Sample records for xylene excludes oxygenates

  1. Xylenes Reactions and Diffusions in ZSM-5 Zeolite based Catalyst S. Al-Khattaf*

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    isomers followed by o-xylene and m-xylene was found to be least reactive. The order of reactivity increases to 500°C, m-xylene reaction will be more selective to disproportionation than other xylene isomers the literature. Generally m-xylene effectiveness factor was estimated to be less than 0.1 indicating to a high

  2. Isobaric vapor-liquid equilibria of p-xylene + o-xylene and m-xylene + o-xylene systems at 6. 66 and 26. 66 kPa

    SciTech Connect (OSTI)

    Llopis, F.J.; Monton, J.B. (Univ. de Valencia (Spain). Dept. de Ingenieria Quimica)

    1994-01-01T23:59:59.000Z

    Vapor-liquid equilibrium data were obtained for systems of o-xylene with p- and m-xylenes at 6.66 and 26.66 kPa. The activity coefficients were found to be thermodynamically consistent. They were equally well correlated with the Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations. The parameters of these equations are given.

  3. National Environmental Policy Act (NEPA) Categorically Excluded...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Management System NEPA National Environmental Policy Act (NEPA) Categorically Excluded Actions National Environmental Policy Act (NEPA) Categorically Excluded...

  4. Baytown Xylene Fractionation Energy Reduction using Dynamic Matrix Control (DMC)

    E-Print Network [OSTI]

    Hokanson, D.

    2014-01-01T23:59:59.000Z

    Baytown Xylene Fractionation Energy Reduction using Dynamic Matrix Control (DMC) IETC 2014 New Orleans, Louisiana David Hokanson ExxonMobil Research and Engineering May 22, 2014 ESL-IE-14-05-33 Proceedings of the Thrity-Sixth Industrial Energy... Conference New Orleans, LA. May 20-23, 2014 3Baytown Chemical / Refining Complex ExxonMobil Baytown Refining & Chemical Complex • One of world’s largest integrated, most technologically advanced petroleum/petrochemical complexes, in operation since 1919...

  5. COMPUTING EXCLUDED MINORS Isolde Adler

    E-Print Network [OSTI]

    Adler, Isolde

    , · linklessly/knotlessly embeddable graphs · C, D minor ideals C D, C D minor ideals · C minor ideal Capex minor ideal Capex := {G | v V(G) such that G \\ v C} ISOLDE ADLER COMPUTING EXCLUDED MINORS 5/18 #12 graphs · C, D minor ideals C D, C D minor ideals · C minor ideal Capex minor ideal Capex := {G | v

  6. Modeling Xylene Reactions over ZSM-5 Zeolite in a Riser Simulator: 1,3 versus 1,2-Methyl Shift

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    -xylene p-xylene). The rate constants and activation energies are obtained from simplified kinetic models include solvent use, manufacture of di- paraxylene and herbicides. Total U.S. consumption of p

  7. Isobaric vapor-liquid equilibria of ethylbenzene + m-xylene and ethylbenzene + o-xylene systems at 6. 66 and 26. 66 kPa

    SciTech Connect (OSTI)

    Monton, J.B.; Llopis, F.J. (Univ. de Valencia (Spain). Dept. de Ingenieria Quimica)

    1994-01-01T23:59:59.000Z

    Vapor-liquid equilibrium data were obtained for systems of ethylbenzene with m- and o-xylenes at 6.66 and 26.66 kPa. The activity coefficients were found to be thermodynamically consistent. They were equally well correlated with the Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations. The parameters of these equations are given.

  8. Detection of Benzene, Toluene, Ethyl Benzene, and Xylenes (BTEX) Using Toluene Dioxygenase-Peroxidase Coupling Reactions

    E-Print Network [OSTI]

    Chen, Wilfred

    bioassay may be suitable for field monitoring of BTEX to identify and track contaminated water and follow in contaminated water because of their accuracy and sensitivity. Although very sensitive, the cost associatedDetection of Benzene, Toluene, Ethyl Benzene, and Xylenes (BTEX) Using Toluene Dioxygenase

  9. Quaternary liquid-liquid equilibrium of n-heptane-toluene-o-xylene-propylene carbonate

    SciTech Connect (OSTI)

    Salem, A.B.S.H.; Hamad, E.Z.; Al-Naafa, M.A. (King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Chemical Engineering Dept.)

    1994-03-01T23:59:59.000Z

    Liquid-liquid equilibrium data for the system n-heptane/toluene/o-xylene/propylene carbonate were obtained at 25 OC. Experimental tie line data were measured by gas chromatographic analysis. The UNIQUAC and NRTL models were used to predict the quaternary data from the corresponding ternary data. Agreement between the predictions and the experimental data was satisfactory.

  10. Clean Water Act (excluding Section 404)

    SciTech Connect (OSTI)

    Not Available

    1993-01-15T23:59:59.000Z

    This Reference Book contains a current copy of the Clean Water Act (excluding Section 404) and those regulations that implement the statutes and appear to be most relevant to US Department of Energy (DOE) activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Updates that include important new requirements will be provided periodically. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

  11. Experimental and theoretical STM imaging of xylene isomers on Pd,,111... D. N. Futaba, J. P. Landry, A. Loui, and S. Chiang*

    E-Print Network [OSTI]

    Chiang, Shirley

    and experimental study of the three isomers of xylene, C6H4 CH3 2, adsorbed on Pd 111 . Using scanning tunneling as well investigated.3­5 The scanning tunneling microscope STM affords the ability to obtain a highly and STM, the chamber was backfilled with 99 %- purity xylene using a variable-leak valve. The xylene

  12. Mechanistic Studies of Reactions of Peroxodiiron(III) Intermediates in T201 Variants of Toluene/o-Xylene Monooxygenase Hydroxylase

    E-Print Network [OSTI]

    Lippard, Stephen J.

    Site-directed mutagenesis studies of a strictly conserved T201 residue in the active site of toluene/o-xylene monooxygenase hydroxylase (ToMOH) revealed that a single mutation can facilitate kinetic isolation of two ...

  13. The influence of initial soil moisture content on the fate of xylene applies to soil

    E-Print Network [OSTI]

    Aurelius, Marcus William

    2012-06-07T23:59:59.000Z

    of -1 0. 15, 0. 20, and 0. 26 kg kg correspond to moisture potentials of -100, -68, and -33 kPa. It was initially of interest to investigate the mobility of xylene at a loading rate equivalent to 9. 52 of the total pore volume. The loading rate... in experimental design. Treat- ment Number Lysimeter Numbers Moisture Water Loading Content Potential Rate (kg kg ) (kPa) (%%d PV) Equivalent Depth of Application (m) 1 2 3 4 5 12, 15, 18 7, 10, 11 3, 4, 5 1, 2, 9 8, 14, 17 0. 15 0. 20 0...

  14. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) Year Month...

  15. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H. (Danville, CA)

    1986-01-01T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  16. Urine Test Strips to Exclude Cerebral Spinal Fluid Blood

    E-Print Network [OSTI]

    Marshall, Robin A; Hejamanowski, Chris

    2011-01-01T23:59:59.000Z

    two Pearson Chi-Square tests. The first compared samplesO riginal R esearch Urine Test Strips to Exclude CerebralBayer Multistix ® urine test strips are designed to test

  17. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  18. Correlation of the phase equilibrium data for the heptane-toluene-sulfolane and heptane-xylene-sulfolane systems

    SciTech Connect (OSTI)

    Cassell, G.W.; Hassan, M.M.; Hines, A.L. (Univ. of Missouri, Dept. of Chemical Engineering, Columbia, MO (US))

    1989-10-01T23:59:59.000Z

    Liquid-liquid equilibrium data were measured for the heptane-toluene-sulfolane system at 25{sup 0}C and for the heptane-xylene-sulfolane system at 17, 25, and 50{sup 0}C. The NRTL and UNIQUAC equations are used to correlate the experimental data and to predict the phase compositions of the ternary systems. The agreement between the predicted and the experimental results was equally good with both equations.

  19. Thermodynamical Consistency of Excluded Volume Hadron Gas Models

    E-Print Network [OSTI]

    M. I. Gorenstein

    2012-05-08T23:59:59.000Z

    The new excluded volume hadron gas model by Singh et al. [1-7] is critically discussed. We demonstrate that in this model the results obtained from relations between thermodynamical quantities disagree with the corresponding results obtained by statistical ensemble averaging. Thus, the model does not satisfy the requirements of thermodynamical consistency.

  20. Acute toxicity of toluene, hexane, xylene, and benzene to the rotifers Brachionus calyciflorus and Brachionus plicatilis

    SciTech Connect (OSTI)

    Ferrando, M.D.; Andreu-Moliner, E. (Univ. of Valencia (Spain))

    1992-08-01T23:59:59.000Z

    A large number of studies on the biological effects of oil pollution in the aquatic environment deal with the effects of whole crude or refined oils or their water-soluble fractions. However, low boiling, aromatic hydrocarbons, which are probably the most toxic constituents of oil, have until now not been examined in sufficient detail. Toluene, benzene and xylene, constitute a major component of various oils. They may be readily lost by weathering but are toxic in waters that are relatively stagnant and are chronically polluted. Korn et al. have stated that toluene is more toxic than many other hydrocarbons such as benzene, though the latter are more water-soluble. Report of the effects of exposure to organic solvents like hexane or toluene are still limited although organic solvents are a well-known group of neurointoxicants. Various benzene derivates continue to be used as chemical intermediates, solvents, pesticides, so on, in spite of incomplete knowledge of their chronic toxicity. The majority of toxicity studies about the effects of pollution on aquatic organisms under controlled conditions have used either fish or the cladoceran Daphnia magna and there are few studies reported using rotifers. The effects of herbicides on population variables of laboratory rotifer cultures have been investigated. Rotifers are one of the main sources of zooplankton production and they have an important ecological significance in the aquatic environment. The present work was designed to investigate the effect of short-term exposure to some petroleum derivates which might be expected to occur immediately under an oil-slick, on freshwater and brackish environment rotifers. 18 refs., 1 tab.

  1. Liquid-liquid equilibria for the ternary systems sulfolane + octane + benzene, sulfolane + octane + toluene and sulfolane + octane + p-xylene

    SciTech Connect (OSTI)

    Lee, S.; Kim, H. [Seoul National Univ. (Korea, Republic of). Dept. of Chemical Engineering

    1995-03-01T23:59:59.000Z

    Sulfolane is widely used as a solvent for the extraction of aromatic hydrocarbons. Ternary phase equilibrium data are essential for the proper understanding of the solvent extraction process. Liquid-liquid equilibrium data for the systems sulfolane + octane + benzene, sulfolane + octane + toluene and sulfolane + octane + p-xylene were determined at 298.15, 308.15, and 318.15 K. Tie line data were satisfactorily correlated by the Othmer and Tobias method. The experimental data were compared with the values calculated by the UNIQUAC and NRTL models. Good quantitative agreement was obtained with these models. However, the calculated values based on the NRTL model were found to be better than those based on the UNIQUAC model.

  2. Characterization of a Peroxodiiron(III) Intermediate in the T201S Variant of Toluene/o-Xylene Monooxygenase Hydroxylase from Pseudomonas sp. OX1

    E-Print Network [OSTI]

    Song, Woon Ju

    We report the observation of a novel intermediate in the reaction of a reduced toluene/o-xylene monooxygenase hydroxylase (ToMOH[subscript red]) T201S variant, in the presence of a regulatory protein (ToMOD), with dioxygen. ...

  3. E-Print Network 3.0 - advanced cancer excluding Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: advanced cancer excluding Page: << < 1 2 3 4 5 > >> 1 Eur J Cancer. Author manuscript Social...

  4. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30T23:59:59.000Z

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  5. GL069 Financial Summary (Including Multi-Year Funds And Excluding Agency Funds)

    E-Print Network [OSTI]

    Shull, Kenneth R.

    GL069 Financial Summary (Including Multi-Year Funds And Excluding Agency Funds) GL069 Cognos Report, or click . Legacy Name/Type - This report is an enhancement to the GL013 report. #12;GL069 Financial Summary (Including Multi-Year Funds And Excluding Agency Funds) GL069 Cognos Report Job Aid ­ cdm 7

  6. GL071 Financial Summary Historical Comparison (Excluding Agency and Multi-Year Funds)

    E-Print Network [OSTI]

    Shull, Kenneth R.

    GL071 Financial Summary ­ Historical Comparison (Excluding Agency and Multi-Year Funds) GL071 into the Entries box, or click . Legacy Name/Type ­ Similar to MCFITS reports. #12;GL071 Financial Summary ­ Historical Comparison (Excluding Agency and Multi-Year Funds) GL071 Cognos Report Job Aid - cdm 7

  7. GL070 Financial Summary with Project Purpose (Excluding Agency and Multi-Year Funds)

    E-Print Network [OSTI]

    Shull, Kenneth R.

    GL070 Financial Summary with Project Purpose (Excluding Agency and Multi-Year Funds) GL070 Cognos is an enhancement to the Cognos GL013 report. #12;GL070 Financial Summary with Project Purpose (Excluding Agency and Multi-Year Funds) GL070 Cognos Report Job Aid - cdm 7/23/2010 © 2009 Northwestern University Page 2 of 4

  8. UC Davis Student Services Fee (excludes Mental Health funds) Student Services and Fees Administrative Advisory Committee

    E-Print Network [OSTI]

    Pasternack, Gregory B.

    UC Davis Student Services Fee (excludes Mental Health funds) Student Services and Fees Management Capital Projects 2 943,666.00$ (2,807.79)$ (946,473.79)$ -$ Child Care 45,325.16$ 144,957.08$ 99 and Institutional Analysis #12;UC Davis Student Services Fee (excludes Mental Health funds) Student Services

  9. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  10. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

  11. Oxygen enriched fireflooding

    SciTech Connect (OSTI)

    Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

    1995-02-01T23:59:59.000Z

    Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

  12. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06T23:59:59.000Z

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  13. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17T23:59:59.000Z

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  14. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  15. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  16. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  17. Particle number fluctuations in nuclear collisions within excluded volume hadron gas model

    E-Print Network [OSTI]

    M. I. Gorenstein; M. Hauer; D. O. Nikolajenko

    2007-02-26T23:59:59.000Z

    The multiplicity fluctuations are studied in the van der Waals excluded volume hadron-resonance gas model. The calculations are done in the grand canonical ensemble within the Boltzmann statistics approximation. The scaled variances for positive, negative and all charged hadrons are calculated along the chemical freeze-out line of nucleus-nucleus collisions at different collision energies. The multiplicity fluctuations are found to be suppressed in the van der Waals gas. The numerical calculations are presented for two values of hard-core hadron radius, $r=0.3$ fm and 0.5 fm, as well as for the upper limit of the excluded volume suppression effects.

  18. *Excludes capital investment for P&R facility EFFECTS OF MAP-21 ON SEAMLESS TRANSIT FROM

    E-Print Network [OSTI]

    *Excludes capital investment for P&R facility EFFECTS OF MAP-21 ON SEAMLESS TRANSIT FROM FORT BEND is not available for residents making the commute from FBC to Downtown Houston. · Researchers estimate latent demand for 1,700+ P&R one-way passenger trips per day. SEAMLESS TRANSIT COST · Federal funds may

  19. GL074 Financial Summary with Management Level & Project Purpose (Excluding Agency and Multi-Year Funds)

    E-Print Network [OSTI]

    Shull, Kenneth R.

    GL074 Financial Summary with Management Level & Project Purpose (Excluding Agency and Multi-Year Funds) (notes on running the report) Reporting Cognos 12/13/2010-vlr GL074 Financial Summary of the new filters found in the Cognos report GL074 Financial Summary with Management Level & Project Purpose

  20. GL068 Financial Summary (Excluding Agency and Multi-Year Funds)

    E-Print Network [OSTI]

    Shull, Kenneth R.

    GL068 Financial Summary (Excluding Agency and Multi-Year Funds) GL068 Cognos Report Job Aid - cdm 9/21/2009 © 2009 Northwestern University Page 1 of 5 General Information about the GL068 Report Description to see more. Legacy Name/Type This report is an enhancement to the Cognos GL013 report. #12;GL068

  1. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2002-07-01T23:59:59.000Z

    In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

  2. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15T23:59:59.000Z

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  3. Clean Water Act (excluding Section 404). Environmental guidance program reference book: Revision 6

    SciTech Connect (OSTI)

    Not Available

    1993-01-15T23:59:59.000Z

    This Reference Book contains a current copy of the Clean Water Act (excluding Section 404) and those regulations that implement the statutes and appear to be most relevant to US Department of Energy (DOE) activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Updates that include important new requirements will be provided periodically. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

  4. Facts and Figures January 2007 INCOME AND EXPENDITURE (Excluding Press, CA & Trusts) 2005-06

    E-Print Network [OSTI]

    Travis, Adrian

    Facts and Figures January 2007 INCOME AND EXPENDITURE (Excluding Press, CA & Trusts) 2005-06 2004,928 Breakdown of Research Grant Income 2005-06 £'000 % £'000 Total staff 8602 8570 8,623 Research Councils 89,095 Total 203,886 188,711 Total respondents 2,890 100.0% 3,227 100.0 Breakdown of HEFCE/TDA Income 2005-06

  5. Ionic Asymmetry and Solvent Excluded Volume Effects on Spherical Electric Double Layers: A Density Functional Approach

    SciTech Connect (OSTI)

    Medasani, Bharat; Ovanesyan, Zaven; Thomas, Dennis G.; Sushko, Maria L.; Marucho, Marcelo

    2014-05-29T23:59:59.000Z

    In this article we present a classical density functional theory for electrical double layers of spherical macroions that extends the capabilities of conventional approaches by accounting for electrostatic ion correlations, size asymmetry and excluded volume effects. The approach is based on a recent approximation introduced by Hansen-Goos and Roth for the hard sphere excess free energy of inhomogeneous fluids (J. Chem. Phys. 124, 154506). It accounts for the proper and efficient description of the effects of ionic asymmetry and solvent excluded volume, especially at high ion concentrations and size asymmetry ratios including those observed in experimental studies. Additionally, we utilize a leading functional Taylor expansion approximation of the ion density profiles. In addition, we use the Mean Spherical Approximation for multi-component charged hard sphere fluids to account for the electrostatic ion correlation effects. These approximations are implemented in our theoretical formulation into a suitable decomposition of the excess free energy which plays a key role in capturing the complex interplay between charge correlations and excluded volume effects. We perform Monte Carlo simulations in various scenarios to validate the proposed approach, obtaining a good compromise between accuracy and computational cost. We use the proposed computational approach to study the effects of ion size, ion size asymmetry and solvent excluded volume on the ion profiles, integrated charge, mean electrostatic potential, and ionic coordination number around spherical macroions in various electrolyte mixtures. Our results show that both solvent hard sphere diameter and density play a dominant role in the distribution of ions around spherical macroions, mainly for experimental water molarity and size values where the counterion distribution is characterized by a tight binding to the macroion, similar to that predicted by the Stern model.

  6. Transport study of hafnium(IV) and zirconium(IV) ions mutual separation by using Tri-n-butyl phosphate-xylene-based supported liquid membranes

    SciTech Connect (OSTI)

    Chaudry, M.A.; Ahmed, B. (Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan))

    1992-02-01T23:59:59.000Z

    A Hf transport study through supported liquid membranes has been carried out to determine flux and permeability data for this metal ion. Tri-n-butyl phosphate (TBP)-xylene-based liquid membranes supported in polypropylene hydrophobic microporous film have been used. These data for hafnium and the previous data for zirconium have furnished the Zr to Hf flux ratio (S) as a function of nitric acid and TBP concentrations of the order of 12 in a single stage at room temperature. Optimum conditions for the separation of these two metal ions appear to 5-6 TBP mol/dm{sup 3} HNO{sub 3}, concentrations {le} 2.93 mol/dm{sup 3}, and 10C. The value of S from an aqueous solution containing 2.4% Hf with respect to Zr has been found to be >125 at 10C and 1.78 mol/dm{sup 3} TBP concentration in the membrane. The technique appears to be feasible for purification of Zr respect to Hf or vice versa.

  7. Description of Hot and Dense Hadron Gas Properties in a New Excluded-Volume model

    E-Print Network [OSTI]

    S. K. Tiwari; P. K. Srivastava; C. P. Singh

    2011-11-10T23:59:59.000Z

    A new equation of state for a hot and dense hadron gas (HG) is obtained where the finite hard-core size of baryons has been incorporated in a thermodynamically consistent formulation of excluded volume correction. Our model differs from other existing approaches on the following points. We assign a hard-core volume only to each baryon and mesons though possess a small volume but they can fuse and interpenetrate into one another. Use of the full quantum statistics is made in obtaining the grand canonical partition function where excluded-volume correction has been incorporated by explicitly integrating over volume. We thus find that the new model works even for the cases of extreme temperatures and/or densities where most of other approaches fail. The model does not violate causality even at extreme densities. The temperature and density dependence of various thermodynamical quantities, e.g. pressure, baryon density, entropy and energy density compare well with the results of other microscopic HG models. After suitable parametrization of the centre-of-mass energy in terms of temperature and baryon chemical potential, we explore some new freeze-out criteria which exhibit full independence of the collision energy and of the structures of the colliding nuclei. We further demonstrate the suitability of our model in explaining various experimental results of the multiplicity-ratios of various particles and their antiparticles. Finally, we use our excluded-volume model to obtain the transport behaviour of the hot and/or dense HG such as shear viscosity to entropy ratio, speed of sound etc. and compare the results with earlier calculations.

  8. Method for excluding salt and other soluble materials from produced water

    DOE Patents [OSTI]

    Phelps, Tommy J. (Knoxville, TN) [Knoxville, TN; Tsouris, Costas (Oak Ridge, TN) [Oak Ridge, TN; Palumbo, Anthony V. (Oak Ridge, TN) [Oak Ridge, TN; Riestenberg, David E. (Knoxville, TN) [Knoxville, TN; McCallum, Scott D. (Knoxville, TN) [Knoxville, TN

    2009-08-04T23:59:59.000Z

    A method for reducing the salinity, as well as the hydrocarbon concentration of produced water to levels sufficient to meet surface water discharge standards. Pressure vessel and coflow injection technology developed at the Oak Ridge National Laboratory is used to mix produced water and a gas hydrate forming fluid to form a solid or semi-solid gas hydrate mixture. Salts and solids are excluded from the water that becomes a part of the hydrate cage. A three-step process of dissociation of the hydrate results in purified water suitable for irrigation.

  9. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2003-01-01T23:59:59.000Z

    In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

  10. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1997-01-01T23:59:59.000Z

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  11. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

  12. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1992-01-01T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  13. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  14. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-08-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

  15. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

  16. Oxygen abundances in the most oxygen-rich spiral galaxies

    E-Print Network [OSTI]

    L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

    2006-01-06T23:59:59.000Z

    Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

  17. Oxygen Concentration Microgradients for Cell Culture

    E-Print Network [OSTI]

    Park, Jaehyun

    2010-01-01T23:59:59.000Z

    The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

  18. Oxygen Transport Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay

    2008-08-30T23:59:59.000Z

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

  19. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  20. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham

    2006-12-31T23:59:59.000Z

    Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

  1. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

  2. Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

  3. Composite oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05T23:59:59.000Z

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  4. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2000-10-01T23:59:59.000Z

    This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  5. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas

    2005-09-30T23:59:59.000Z

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

  6. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

  7. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

    2011-03-22T23:59:59.000Z

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  8. Electrochemical studies of quinone oxygen

    SciTech Connect (OSTI)

    Deanhardt, M.L. (Lander College, Greenwood, SC (US)); Mushrush, G.W.; Stalick, W.M. (Chemistry Dept., George mason Univ., Fairfax, VA (US)); Watkins, J.M. Jr. (Naval Research Lab., Fuels Section, Code 6180, Washington, DC (US))

    1990-02-01T23:59:59.000Z

    Asphaltenes are a chemically complex mixture of aromatic and heteroaromatic compounds. This material contains oxygen in various functional groups. The distribution includes esters, carboxylic acids, phenolic and most probably quinone type oxygen functionalities. The present work details the complete electrochemical behaviour of quinone type oxygen. The method is quinone specific. A condensed aromatic quinone, 9,10-anthraquinone, was selected as representative of complex quinones. By this method quinones can be determined in the presence of other oxygen functional groups, alcohols, carboxylic acids, ethers, and other carbonyls.

  9. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2002-04-01T23:59:59.000Z

    This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  10. Pool octanes via oxygenates

    SciTech Connect (OSTI)

    Prezelj, M.

    1987-09-01T23:59:59.000Z

    Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

  11. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2001-12-01T23:59:59.000Z

    Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  12. Excluded Volume Effects in Polymer Solutions: II. Comparison of Experimental Results with Numerical Simulation Data

    SciTech Connect (OSTI)

    Graessley, W.W.; Grest, G.S.; Hayward, R.C.

    1999-03-23T23:59:59.000Z

    The effect of excluded volume on the coil size of dilute linear polymers was investigated by off-lattice Monte Carlo simulations. The radius of gyration R{sub g} was evaluated for a wide range of chain lengths at several temperatures and at the athermal condition. The theta temperature and the corresponding theta chain dimensions were established for the system, and the dependence of the size expansion factor, a{sub s} = R{sub g} /(R{sub g}){sub {theta}}, on chain length N and temperature T was examined. For long chains and at high temperatures, a{sub s} is a function of N/N{sub s}{sup 2} alone, where the length scale N{sub s}{sup 2} depends only on T. The form of this simulations-based master function compares favorably with {alpha}{sub s}(M/M{sub s}{sup 2}), an experimental master curve for linear polymers in good solvents, where M{sub s}{sup 2} depends only on polymer-solvent system. Comparisons when N{sub s}{sup 2}(T) and M{sub s}{sup 2}(system) are reduced to common units, numbers of Kuhn steps, strongly indicate that coil expansion in even the best of good solvents is small relative to that expected for truly athermal solutions. An explanation for this behavior is proposed, based on what would appear to be an inherent difference in the equation of state properties for polymeric and monomeric liquids.

  13. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-10-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  14. Oxygen detection using evanescent fields

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

    2007-08-28T23:59:59.000Z

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  15. Mixed oxygen ion/electron-conducting ceramics for oxygen separation

    SciTech Connect (OSTI)

    Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

    1995-05-01T23:59:59.000Z

    Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

  16. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

  17. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2002-01-01T23:59:59.000Z

    Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

  18. Low Oxygen Environments in Chesapeake Bay

    E-Print Network [OSTI]

    Boynton, Walter R.

    Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

  19. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-11-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

  20. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07T23:59:59.000Z

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  1. Oxygen transfer in the implant environment

    E-Print Network [OSTI]

    Goor, Jared Braden

    2007-01-01T23:59:59.000Z

    Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

  2. OXYGEN DIFFUSION IN UO2-x

    E-Print Network [OSTI]

    Kim, K.C.

    2013-01-01T23:59:59.000Z

    ~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

  3. PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux

    E-Print Network [OSTI]

    Mallin, Michael

    PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

  4. Electrocatalytic Reactivity for Oxygen Reduction of Palladium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

  5. Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

    E-Print Network [OSTI]

    VanVeller, Brett

    The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

  6. Extracorporeal membrane oxygenation promotes long chain fatty...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

  7. OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE

    E-Print Network [OSTI]

    Kim, Kee Chul

    2010-01-01T23:59:59.000Z

    Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

  8. Formation, characterization and reactivity of adsorbed oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

  9. Oxygen Concentration Microgradients for Cell Culture

    E-Print Network [OSTI]

    Park, Jaehyun

    2010-01-01T23:59:59.000Z

    for technology that can control microscale oxygen gradientstechnology is the ability to rapidly generate and alter oxygentechnology should enable numerous studies in the field of biology where oxygen

  10. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

    2003-11-01T23:59:59.000Z

    The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

  11. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  12. OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES

    E-Print Network [OSTI]

    Truong, Thanh N.

    OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

  13. Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

  14. Oxygen uptake of benthic systems

    E-Print Network [OSTI]

    Priebe, William Franklin

    1972-01-01T23:59:59.000Z

    mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

  15. Quantifying the areal extent and dissolved oxygen concentrations of Archean oxygen oases.

    E-Print Network [OSTI]

    Olson, Stephanie

    2013-01-01T23:59:59.000Z

    ??Several lines of evidence indicate that the advent of oxygenic photosynthesis preceded the oxygenation of the atmosphere—perhaps by as much as 300 million years. The… (more)

  16. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal (excluding semiconductor-and solar-

    E-Print Network [OSTI]

    Production and Use: Estimated value of silicon alloys and metal (excluding semiconductor- and solar- grade and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips China, 49%; Russia, 20

  17. Oxygen reduction on platinum : an EIS study

    E-Print Network [OSTI]

    Golfinopoulos, Theodore

    2009-01-01T23:59:59.000Z

    The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

  18. Microchemical systems for singlet oxygen generation

    E-Print Network [OSTI]

    Hill, Tyrone F. (Tyrone Frank), 1980-

    2008-01-01T23:59:59.000Z

    Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

  19. The Role of Oxygen in Coal Gasification

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

  20. Mitochondrial reactive oxygen species and cancer

    E-Print Network [OSTI]

    Chandel, Navdeep S

    Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

  1. Composite oxygen ion transport element

    SciTech Connect (OSTI)

    Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

    2007-06-12T23:59:59.000Z

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  2. Catalyst containing oxygen transport membrane

    SciTech Connect (OSTI)

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04T23:59:59.000Z

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  3. AN ELECTRICAL OXYGEN-TEMPERATURE METER

    E-Print Network [OSTI]

    426 AN ELECTRICAL OXYGEN-TEMPERATURE METER FOR FISHERY BIOLOGISTS SEP 2 1196: vuUiJo HIM. . SPECIAL and Wildlife, Daniel H. Janzen, Director AN ELECTRICAL OXYGEN-TEMPERATURE METER FOR FISHERY BIOLOGISTS -temperature meter 11 Maintenance and trouble -shooting 12 #12;AN ELECTRICAL OXYGEN-TEMPERATURE METER

  4. Effects of oxygen on fracturing fluids

    SciTech Connect (OSTI)

    Walker, M.L.; Shuchart, C.E.; Yaritz, J.G.; Norman, L.R.

    1995-11-01T23:59:59.000Z

    The stability of polysaccharide gels at high temperature is limited by such factors as pH, mechanical degradation, and oxidants. Oxygen is unavoidably placed in fracturing fluids through dissolution of air. To prevent premature degradation of the fracturing fluid by this oxidant, oxygen scavengers are commonly used. In this paper, the effects of oxygen and various oxygen scavengers on gel stability will be presented. Mechanical removal of oxygen resulted in surprisingly stable fracturing gels at 275 F. However, chemical removal of oxygen gave mixed results. Test data from sodium thiosulfate, sodium sulfite, and sodium erythorbate used as oxygen scavengers/gel stabilizers showed that the efficiency of oxygen removal from gels did not directly coincide with the viscosity retention of the gel, and large excesses of additives were necessary to provide optimum gel stabilization. The inability of some oxygen scavengers to stabilize the gel was the result of products created from the interaction of oxygen with the oxygen scavenger, which in turn, produced species that degraded the gel. The ideal oxygen scavenger should provide superior gel stabilization without creating detrimental side reaction products. Of the materials tested, sodium thiosulfate appeared to be the most beneficial.

  5. Oxygen Detection via Nanoscale Optical Indicators

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

  6. 8, 22252248, 2008 Detection of oxygen

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

  7. The Mechanisms of Oxygen Reduction and Evolution Reactions in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

  8. Oxygen consumption of bovine granulosa cells in vitro.

    E-Print Network [OSTI]

    Li, Dongxing

    2012-01-01T23:59:59.000Z

    ??The oxygen consumption rate of granulosa cells is considered to be a key determinant of oocyte oxygenation in follicles. The oxygen status of the oocyte… (more)

  9. Lycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic

    E-Print Network [OSTI]

    Wurtzel, Eleanore

    , quenching singlet oxygen generated during the water-splitting process of photo- synthesis (10, 11). VariousLycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic photosynthetic cyclase. Instead, we show that CruP aids in preventing accumulation of reactive oxygen species (ROS

  10. Experimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine Laser

    E-Print Network [OSTI]

    Carroll, David L.

    state I. Conventionally, a two-phase (gas-liquid) chemistry singlet oxygen generator (SOG) producesExperimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine of the electric discharge iodine laser continues, the role of oxygen atoms downstream of the discharge region

  11. Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

  12. Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

  13. OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

    E-Print Network [OSTI]

    Byrn, Marianne; Calvin, Melvin

    1965-01-01T23:59:59.000Z

    OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES TWO-eng-48 OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

  14. Dynamics of pulled desorption with effects of excluded volume interaction: The p-Laplacian diffusion equation and its exact solution

    E-Print Network [OSTI]

    K. L. Sebastian; V. G. Rostiashvili; T. A. Vilgis

    2011-08-31T23:59:59.000Z

    We analyze the dynamics of desorption of a polymer molecule which is pulled at one of its ends with force $f$, trying to desorb it. We assume a monomer to desorb when the pulling force on it exceeds a critical value $f_{c}$. We formulate an equation for the average position of the $n^{th}$ monomer, which takes into account excluded volume interaction through the blob-picture of a polymer under external constraints. The approach leads to a diffusion equation with a $p$-Laplacian for the propagation of the stretching along the chain. This has to be solved subject to a moving boundary condition. Interestingly, within this approach, the problem can be solved exactly in the trumpet, stem-flower and stem regimes. In the trumpet regime, we get $\\tau=\\tau_{0}n_d^{2}$ where $n_d$ is the number of monomers that have desorbed at the time $\\tau$. $\\tau_{0}$ is known only numerically, but for $f$ close to $f_{c}$, it is found to be $\\tau_{0}\\sim f_c/(f^{2/3}-f_{c}^{2/3})$. If one used simple Rouse dynamics, this result changes to {\

  15. Direct constraints on diffusion models from cosmic-ray positron data: Excluding the Minimal model for dark matter searches

    E-Print Network [OSTI]

    Julien Lavalle; David Maurin; Antje Putze

    2015-01-22T23:59:59.000Z

    Galactic Cosmic-ray (CR) transport parameters are usually constrained by the boron-to-carbon ratio. This procedure is generically plagued with degeneracies between the diffusion coefficient and the vertical extent of the Galactic magnetic halo. The latter is of paramount importance for indirect dark matter (DM) searches, because it fixes the amount of DM annihilation or decay that contributes to the local antimatter CR flux. These degeneracies could be broken by using secondary radioactive species, but the current data still have large error bars, and this method is extremely sensitive to the very local interstellar medium (ISM) properties. Here, we propose to use the low-energy CR positrons in the GeV range as another direct constraint on diffusion models. We show that the PAMELA data disfavor small diffusion halo ($L\\lesssim 3$ kpc) and large diffusion slope models, and exclude the minimal ({\\em min}) configuration (Maurin et al. 2001, Donato et al. 2004) widely used in the literature to bracket the uncertainties in the DM signal predictions. This is complementary to indirect constraints (diffuse radio and gamma-ray emissions) and has strong impact on DM searches. Indeed this makes the antiproton constraints more robust while enhancing the discovery/exclusion potential of current and future experiments, like AMS-02 and GAPS, especially in the antiproton and antideuteron channels.

  16. Identification of an Archean marine oxygen oasis

    SciTech Connect (OSTI)

    Riding, Dr Robert E [University of Tennessee (UT); Fralick, Dr Philip [Lakehead University, Canada; Liang, Liyuan [ORNL

    2014-01-01T23:59:59.000Z

    The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

  17. Myocardial Reloading after Extracorporeal Membrane Oxygenation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protein Synthesis. Abstract: Extracorporeal membrane oxygenation (ECMO) unloads the heart providing a bridge to recovery in children after myocardial stunning. Mortality after...

  18. Oxygen Concentration Microgradients for Cell Culture.

    E-Print Network [OSTI]

    Park, Jaehyun

    2010-01-01T23:59:59.000Z

    ??There is a growing need for technology that can control microscale oxygen gradients onto a tissue or culture sample in vitro. This dissertation introduces the… (more)

  19. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO)

    1991-01-01T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

  20. Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system

    E-Print Network [OSTI]

    Low, Clarke Alan

    2008-01-01T23:59:59.000Z

    Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

  1. High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen

    E-Print Network [OSTI]

    Sibener, Steven

    High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

  2. New Oxygen-Production Technology Proving Successful

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

  3. Oxygen and Nitrogen Contamination During Arc Welding

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, shielded metal arc, self-shielded metal arc, and submerged arc welding are reviewed. Calcu- lations upon heating is also discussed. Introduction Oxygen and nitrogen ~ontamination of weld metal

  4. Phytoremediation of hydrocarbon-contaminated soils: principles and applications

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Toluene Ethylbenzene CH2CH3 ii) Common Oxygenates MTBE O C CH3CH3 CH3 m-Xylene CH3 CH3 p-Xylene CH3 CH3 CH Ethylbenzene CH2CH3CH2CH3CH2CH3 ii) Common Oxygenates MTBE O C CH3CH3 CH3 m-Xylene CH3 CH3 CH3 CH3 p-Xylene CH3 Ethylbenzene CH2CH3 ii) Common Oxygenates MTBE O C CH3CH3 CH3 m-Xylene CH3 CH3 p-Xylene CH3 CH3 CH3CH2OH

  5. Faculty of Law Number of students who has finished (with a degree) and early leavers (excluding transferred students) by AY (As of May 1, 2012)

    E-Print Network [OSTI]

    Banbara, Mutsunori

    Holdover H OthersI) Total + early admission Total GraduatesC) over-term within designated term Rate outside school Reasons to leaveF) Leaving RateG) Holdover H within designated term over-term GraduatesCFaculty of Law Number of students who has finished (with a degree) and early leavers (excluding

  6. rule'' to reduce the monetary penalty by 50 to 75 percent right off the top. Citizens are often excluded from EPA

    E-Print Network [OSTI]

    Peterson, M. Nils

    environmental projects (SEPs), begun in the late 1990s, so that convicted polluters can mitigate the damage excluded from EPA decision making, even when it affects them. For example, in a federal environmental-impact statement, citizens are not given notice of a preliminary environmental assessment of their neighborhood

  7. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect (OSTI)

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01T23:59:59.000Z

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  8. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  9. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

    1997-01-01T23:59:59.000Z

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  10. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

    1996-01-01T23:59:59.000Z

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  11. Selective photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

    1998-01-01T23:59:59.000Z

    A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

  12. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01T23:59:59.000Z

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  13. Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)

    E-Print Network [OSTI]

    Levin, Lisa

    Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen increased animal activity associated with increasing bottom-water oxygen concentration. We examined faunal community responses to oxygen and organic matter gradients across the lower oxygen minimum zone (OMZ

  14. Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen-Iodine Laser System

    E-Print Network [OSTI]

    Carroll, David L.

    Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen a low-pressure oxygen/helium/nitric oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic oxygen, ozone, and other excited species adds levels

  15. Characterization of an oxygen suspension used for intravenous infusion

    E-Print Network [OSTI]

    Peña, Kristen Helen

    2012-01-01T23:59:59.000Z

    Oxygenated fluid mixture can be used to treat critically ill patients suffering from asphyxia, lung injury, and cardiac arrest. This oxygenated fluid delivered intravenously re-oxygenates the bloodstream, allowing for more ...

  16. Reactive oxygen species: a breath of life or death?

    E-Print Network [OSTI]

    Fruehauf, John P; Meyskens, Frank L Jr

    2007-01-01T23:59:59.000Z

    AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

  17. Blood oxygen transport and depletion : the key of consummate divers

    E-Print Network [OSTI]

    Meir, Jessica Ulrika

    2009-01-01T23:59:59.000Z

    and Dill, D. B. (1935). Oxygen dissociation curves of birdE. (1964). A venous blood oxygen reservoir in the divingand Torrance, J. D. (1977). Oxygen-Affinity of Avian Blood.

  18. Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

  19. Oxygen Tension Modulates Neurite Outgrowth in PC12 Cells Through A Mechanism Involving HIF and VEGF

    E-Print Network [OSTI]

    Genetos, Damian C.; Cheung, Whitney K.; Decaris, Martin L.; Leach, J. Kent

    2010-01-01T23:59:59.000Z

    neural repair. Keywords Oxygen tension . Neurite extension .respective physiological oxygen microenvironments (Chen etet al. 2008). For example, oxygen tension differentially

  20. Long-term oxygen sensor implantation in the porcine subcutaneous environment

    E-Print Network [OSTI]

    Kumosa, Lucas Stefan

    2011-01-01T23:59:59.000Z

    Membrane-­?Covered  Oxygen  Electrode.   Analytical  Microvascular  and  tissue  oxygen   distribution.  vitro  stability  of  an  oxygen  sensor.   Anal  Chem,  

  1. On the maximum value of the cosmic abundance of oxygen and the oxygen yield

    E-Print Network [OSTI]

    L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

    2007-01-11T23:59:59.000Z

    We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centers of the most luminous galaxies, we have constructed the luminosity - central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of HII regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities (-22.3 oxygen abundance 12+log(O/H) ~ 8.87. This provides strong evidence that the oxygen abundance in the centers of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas+dust oxygen abundance in spiral galaxies is 12+log(O/H) ~ 8.95. This value is a factor of ~ 2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.

  2. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

  3. Density Functional Theory Study of Oxygen Reduction Activity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Abstract: The...

  4. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments...

  5. Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

  6. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

  7. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

  8. Effects of Oxygen-Containing Functional Groups on Supercapacitor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen-Containing Functional Groups on Supercapacitor Performance. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Abstract: Molecular dynamics (MD)...

  9. Testing Oxygen Reduction Reaction Activity with the Rotating...

    Broader source: Energy.gov (indexed) [DOE]

    Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

  10. Isolation, Characterization of an Intermediate in an Oxygen Atom...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer...

  11. Fractionation of Oxygen Isotopes in Phosphate during its Interactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides. Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides....

  12. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

  13. Density Functional Study of the Structure, Stability and Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Study of the Structure, Stability and Oxygen Reduction Activity of Ultrathin Platinum Nanowires. Density Functional Study of the Structure, Stability and Oxygen Reduction Activity...

  14. Electron-Stimulated Production of Molecular Oxygen in Amorphous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water. Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water. Abstract: The low-energy, electron-stimulated production of molecular oxygen from pure amorphous...

  15. Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

  16. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

  17. Reactive Gliosis Reactive Oxygen Species: Superoxide

    E-Print Network [OSTI]

    . By sensing the electric signals generated by other 3368 Reactive Gliosis #12;individuals, mormyrids are alsoReactive Gliosis Glial Scar Reactive Oxygen Species: Superoxide Anions Neuroinflammation motor output. Reafferent Control in Electric Communication Reafferent Control in Electric Communication

  18. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-08-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  19. Design optimization of oxygenated fluid pump

    E-Print Network [OSTI]

    Piazzarolo, Bruno Aiala

    2012-01-01T23:59:59.000Z

    In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

  20. Electron-impact excitation of neutral oxygen

    E-Print Network [OSTI]

    P. S. Barklem

    2006-09-25T23:59:59.000Z

    Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

  1. Injectable polymer for in vivo oxygen sensing

    E-Print Network [OSTI]

    Imaad, Syed M. (Syed Muhammad)

    2013-01-01T23:59:59.000Z

    This thesis documents the synthesis and characterization of an elastomeric polymer that is oxygen sensitive and can be interrogated using Magnetic Resonance Imaging (MRI) or Magnetic Resonance (MR) technology to report the ...

  2. Oxygen Enriched Combustion System Performance Study

    E-Print Network [OSTI]

    Chen, S. L.; Kwan, Y.; Abele, A. R.; Silver, L. S.; Kobayashi, H.

    }ched combustlon systems are technically, envlronmentally and economically feasible and offer significant energy savings and/or productivity improvement, and then to verify the performance of selected systems in research furnaces. Tests of several commercial... for 35 - 100 percent oxygen. The absolute levels of the NO x emissions also depended on the furnace temperature. INTRODUCTION Oxygen enriched combustion has been found to have significant energy saving potential in industrial furnace applications...

  3. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-01-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

  4. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

  5. Magnetism in Lithium–Oxygen Discharge Product

    SciTech Connect (OSTI)

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13T23:59:59.000Z

    Nonaqueous lithium–oxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithium–oxygen batteries. We demonstrate that the major discharge product formed in the lithium–oxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium– oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  6. Atomic Oxygen in the Comae of Comets

    E-Print Network [OSTI]

    Anita L. Cochran

    2008-07-03T23:59:59.000Z

    We report on the detection of atomic oxygen lines in the spectra of 8 comets. These forbidden lines are a result of the photodissociation of the parent oxygen-bearing species directly into an excited state. We used high resolution spectra obtained at the McDonald Observatory 2.7m telescope to resolve the cometary oxygen lines from the telluric oxygen lines and from other cometary emissions. We find that the relative intensities of the two red lines (6300.304 and 6363.776A) are consistent with theory. The green line (5577.339A) has an intensity which is about 10% of the sum of the intensities of the two red lines. We show that collisional quenching may be important in the inner coma. If we assume the relative excitation rates of potential parents which have appeared in the literature, then H2O would be the parent of the cometary green oxygen line. However, those rates have been questioned. We measured the width of the three oxygen lines and find that the green line is wider than either of the two red lines. The finding of a wider line could imply a different parent for the green and red lines. However, the constancy of the green to red line flux ratio suggests the parent is the same for these lines but that the exciting photons have different energies.

  7. Faculty of Law Number of students who has finished (with a degree) and early leavers (excluding transferred students) by AY (As of May 1, 2011)

    E-Print Network [OSTI]

    Banbara, Mutsunori

    Faculty of Law Number of students who has finished (with a degree) and early leavers (excluding or less more than 1 year Law 180 227 227 155 65 220 68% 29% 97% 5 2% 0 2 Total 180 227 227 155 65 220 68% 29% 97% 5 2% 0 2 Law 180 184 184 139 37 176 76% 20% 96% 6 3% 2 0 Total 180 184 184 139 37 176 76% 20

  8. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-07-01T23:59:59.000Z

    Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

  9. Oxygen generator for medical applications (USIC)

    SciTech Connect (OSTI)

    Staiger, C. L.

    2012-03-01T23:59:59.000Z

    The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

  10. Carbon-Oxygen Bond Activation in Esters by Platinum(0): Cleavage of the Less Reactive Bond

    E-Print Network [OSTI]

    Jones, William D.

    esters in the presence of trialkylphosphines to give -allyl addition products.2 Acetate and benzoate-O oxidative addition to give -allyl products. Vinyl esters (acetate and benzoate) were also reported of the solution. Reaction with Allyl Acetate. Treatment of 1 with 10 equiv of allyl acetate in p-xylene-d10 at 160

  11. Dissecting Oxygenic Photosynthesis: The Evolution of the "Z"-Scheme

    E-Print Network [OSTI]

    Govindjee

    of the "period four oxygen clock" and the structure of the oxygen-evolving center. After a brief mention the maximum quantum yield, i.e., the number of oxygen molecules evolved per photon of light absorbed11CHAPTER Dissecting Oxygenic Photosynthesis: The Evolution of the "Z"-Scheme for Thylakoid

  12. Oxygen Toxicity Calculations by Erik C. Baker, P.E.

    E-Print Network [OSTI]

    Read, Charles

    1 Oxygen Toxicity Calculations by Erik C. Baker, P.E. Management of exposure to oxygen toxicity myself using the good ole' FORTRAN programming language, I found that incorporating oxygen toxicity for others. Background Two oxygen toxicity parameters are typically "tracked" in technical diving

  13. Energetic neutral atoms at Mars 4. Imaging of planetary oxygen

    E-Print Network [OSTI]

    Lukyanov, Alex

    Energetic neutral atoms at Mars 4. Imaging of planetary oxygen S. Barabash and M. Holmstro of the Martian oxygen exosphere/corona results in the production of planetary oxygen ions. The newborn ions start. The oxygen ions can then charge exchange with the neutral gases (H, H2, and O) of the Martian exosphere

  14. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-02-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

  15. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  16. Oxygenates du`jour...MTBE? Ethanol? ETBE?

    SciTech Connect (OSTI)

    Wolfe, R.

    1995-12-31T23:59:59.000Z

    There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

  17. Oxygen abundance of open cluster dwarfs

    E-Print Network [OSTI]

    Z. -X. Shen; X. -W. Liu; H. -W. Zhang; B. Jones; D. N. C. Lin

    2007-03-30T23:59:59.000Z

    We present oxygen abundances of dwarfs in the young open cluster IC 4665 deduced from the OI $\\lambda$7774 triplet lines and of dwarfs in the open cluster Pleiades derived from the [OI] $\\lambda$6300 forbidden line. Stellar parameters and oxygen abundances were derived using the spectroscopic synthesis tool SME (Spectroscopy Made Easy). We find a dramatic increase in the upper boundary of the OI triplet abundances with decreasing temperature in the dwarfs of IC 4665, consistent with the trend found by Schuler et al. in the open clusters Pleiades and M 34, and to a less extent in the cool dwarfs of Hyades (Schuler et al. 2006a) and UMa (King & Schuler 2005). By contrast, oxygen abundances derived from the [OI] $\\lambda$6300 forbidden line for stars in Pleiades and Hyades (Schuler et al. 2006b) are constant within the errors. Possible mechanisms that may lead a varying oxygen triplet line abundance are examined, including systematic errors in the stellar parameter determinations, the NLTE effects, surface activities and granulation. The age-related effects stellar surface activities (especially the chromospheric activities) are suggested by our analysis to blame for the large spreads of oxygen triplet line abundances.

  18. Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells

    E-Print Network [OSTI]

    Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells Xue Xia, Justin C. Tokash, Fang Zhang, Peng Liang, Xia Huang,*, and Bruce E. Logan*,, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, P

  19. Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully influence organisms living in near

    E-Print Network [OSTI]

    Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully to the winter of 2014. Their scholarly work is presented in this collection. #12;1 Oxygen: From Environment", 2013, 2014 Table of contents Page 2. Laura Lilly - Low-oxygen formation along the California current. 6

  20. Interaction of light with the ZnO surface: Photon induced oxygen "breathing," oxygen vacancies, persistent photoconductivity,

    E-Print Network [OSTI]

    Shalish, Ilan

    Interaction of light with the ZnO surface: Photon induced oxygen "breathing," oxygen vacancies donation of oxygen vacancies. Our findings suggest that the observed decomposition of the ZnO lattice may. The formation of oxygen-vacancy rich surface is suggested to induce surface delta doping, causing accumulation

  1. Photochemical Escape of Oxygen from Early Mars

    E-Print Network [OSTI]

    Zhao, Jinjin

    2015-01-01T23:59:59.000Z

    Photochemical escape is an important process for oxygen escape from present Mars. In this work, a 1-D Monte-Carlo Model is developed to calculate escape rates of energetic oxygen atoms produced from O2+ dissociative recombination reactions (DR) under 1, 3, 10, and 20 times present solar XUV fluxes. We found that although the overall DR rates increase with solar XUV flux almost linearly, oxygen escape rate increases from 1 to 10 times present solar XUV conditions but decreases when increasing solar XUV flux further. Analysis shows that atomic species in the upper thermosphere of early Mars increases more rapidly than O2+ when increasing XUV fluxes. While the latter is the source of energetic O atoms, the former increases the collision probability and thus decreases the escape probability of energetic O. Our results suggest that photochemical escape be a less important escape mechanism than previously thought for the loss of water and/or CO2 from early Mars.

  2. Oxygen Transport Ceramic Membranes Quarterly Report

    E-Print Network [OSTI]

    Eagar, Thomas W.

    /Reaction rates in Ion 21 Transport Membranes using Isotope Tracer and Transient Kinetic Techniques CONCLUSIONS 30Oxygen Transport Ceramic Membranes Quarterly Report January 2003 ­ March 2003 Principal Authors on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane

  3. Novel Membranes and Processes for Oxygen Enrichment

    SciTech Connect (OSTI)

    Lin, Haiqing

    2011-11-15T23:59:59.000Z

    The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

  4. Oxygen addition to sulfur of metal thiolates

    E-Print Network [OSTI]

    Soma, Takako

    2012-06-07T23:59:59.000Z

    , and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

  5. Oxygen isotope exchange between water and semiquinones

    SciTech Connect (OSTI)

    Stevenson, G.R.; Wang, Z.Y.; Reiter, R.C.; Peters, S.J.

    1988-09-14T23:59:59.000Z

    A reaction is described that can be utilized to produce /sup 17/O-labeled anion radicals that yield strong well resolved ESR signals exhibiting splitting from the /sup 17/O nucleus. The oxygen anthraquinone has been studied, and the results are reported herein. 7 references, 1 figure.

  6. Oxygen-producing inert anodes for SOM process

    DOE Patents [OSTI]

    Pal, Uday B

    2014-02-25T23:59:59.000Z

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  7. The Economics of Oxygen Enriched Air Production Via Membranes

    E-Print Network [OSTI]

    Gollan, A.; Kleper, M. H.

    1984-01-01T23:59:59.000Z

    Oxygen enriched air combustion is a recognized approach to energy conservation. Conventional methods of producing oxygen enriched air: Pressure Swing Adsorption and Cryogenics, are energy-intensive and expensive. In this paper the economics of using...

  8. Breath is a mixture of nitrogen, oxygen, carbon dioxide, water

    E-Print Network [OSTI]

    12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

  9. OXYGEN TRANSFER IN TRICKLING FILTERS By BruceE. Logan~

    E-Print Network [OSTI]

    OXYGEN TRANSFER IN TRICKLING FILTERS By BruceE. Logan~ ABSTRACT: Insufficientoxygen transfer can result in anaerobic biofilmsand odor generation during biochemicaloxygen demand (BOD) removal plastic media trickling filters occurs by diffusion of oxygen through thin fluid films, previous models

  10. Design, measurement, and analysis of oxygenated fluid pump system

    E-Print Network [OSTI]

    Mason, Alexander M., IV (Alexander Martin)

    2012-01-01T23:59:59.000Z

    The author sought out the opportunity to design and implement a system for pumping oxygenated fluid and mixing it with saline, for the purpose of providing sufficient levels of oxygen for patients undergoing forms of ...

  11. Label-free oxygen-metabolic photoacoustic microscopy in vivo

    E-Print Network [OSTI]

    Wang, Lihong

    tomography (PET) using radioactively labeled oxy- gen. Many other pathological and physiological functions of oxygen consumption instead of the static oxygen concentration.11 If the region of interest has well

  12. Optimization of Oxygen Purity for Coal Conversion Energy Reduction

    E-Print Network [OSTI]

    Baker, C. R.; Pike, R. A.

    1982-01-01T23:59:59.000Z

    The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

  13. Optical Perfusion and Oxygenation Characterization in a Liver Phantom

    E-Print Network [OSTI]

    King, Travis J.

    2012-02-14T23:59:59.000Z

    Continuous monitoring of blood perfusion and oxygenation is essential in assessing the health of a transplanted organ. Particularly, monitoring the perfusion and oxygenation of the organ during the two-week period after the transplant procedure...

  14. Methane Adsorption and Dissociation and Oxygen Adsorption and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

  15. Inhibitive Influence of Oxygen Vacancies for Photoactivity on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Abstract: Scanning tunneling...

  16. Oxygen-induced magnetic properties and metallic behavior of a...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Abstract: In this paper, ab initio...

  17. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

  18. On the reduction of oxygen from dispersed media

    E-Print Network [OSTI]

    Roushdy, Omar H., 1977-

    2007-01-01T23:59:59.000Z

    The reduction of oxygen from an organic phase dispersed in a concentrated electrolyte is investigated. Dispersed organic phases are used to enhance oxygen transport in fermenters and artificial blood substitutes. This work ...

  19. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-10-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

  20. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29T23:59:59.000Z

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  1. A miniature inexpensive, oxygen sensing element

    SciTech Connect (OSTI)

    Arenz, R.W.

    1991-10-07T23:59:59.000Z

    An exhaustive study was conducted to determine the feasibility of Nernst-type oxygen sensors based on ceramics containing Bi{sub 2}O{sub 3}. The basic sensor design consisted of a ceramic sensing module sealed into a metal tube. The module accommodated an internal heater and thermocouple. Thermal-expansion-matched metals, adhesives, and seals were researched and developed, consistent with sequential firings during sensor assembly. Significant effort was devoted to heater design/testing and to materials' compatibility with Pt electrodes. A systematic approach was taken to develop all sensor components which led to several design modifications. Prototype sensors were constructed and exhaustively tested. It is concluded that development of Nerst-type oxygen sensors based on Bi{sub 2}O{sub 3} will require much further effort and application of specialized technologies. However, during the course of this 3-year program much progress was reported in the literature on amperometric-type oxygen sensors, and a minor effort was devoted here to this type of sensor based on Bi{sub 2}O{sub 3}. These studies were made on Bi{sub 2}O{sub 3}-based ceramic samples in a multilayer-capacitor-type geometry and amperometric-type oxygen sensing was demonstrated at very low temperatures ({approximately} 160{degree}C). A central advantage here is that these types of sensors can be mass-produced very inexpensively ({approximately} 20--50 cents per unit). Research is needed, however, to develop an optimum diffusion-limiting barrier coating. In summary, the original goals of this program were not achieved due to unforeseen problems with Bi{sub 2}O{sub 3}-based Nernst sensors. However, a miniature amperometric sensor base on Bi{sub 2}O{sub 3} was demonstrated in this program, and it is now seen that this latter sensor is far superior to the originally proposed Nernst sensor. 6 refs., 24 figs.

  2. Oxygen stabilized zirconium vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  3. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-08-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

  4. DME-to-oxygenates process studies

    SciTech Connect (OSTI)

    Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

    1994-12-31T23:59:59.000Z

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  5. Quasi-Reversible Oxygen Exchange of Amorphous IGZO Thin Films

    E-Print Network [OSTI]

    Shahriar, Selim

    MRSEC Quasi-Reversible Oxygen Exchange of Amorphous IGZO Thin Films NSF Grant # 1121262 A. U. Adler of varying oxygen partial pressure. Oxygen exchange was confirmed by 18O tracer diffusion (time of carrier content vs. pO2) analysis should be applicable for studying the underlying carrier generation

  6. Oxygen Reduction DOI: 10.1002/anie.201403264

    E-Print Network [OSTI]

    Goddard III, William A.

    Oxygen Reduction DOI: 10.1002/anie.201403264 Dramatic Increase in the Oxygen Reduction Reaction solvation) is used to predict how the energies and barriers for the mechanistic steps of the oxygen. In these electro- chemical devices, H2 (generated e.g. from solar energy conversion) reacts with O2 to produce

  7. IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS

    E-Print Network [OSTI]

    Wells, Scott A.

    1 IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS Jacek Makinia*, Scott A in a full-scale activated sludge reactor. The Activated Sludge Model No. 1 was used to describe for dissolved oxygen. KEYWORDS Activated sludge; dispersion; dissolved oxygen dynamics; mass transfer

  8. Oceanic oxygen changes as a bellwether of climate change

    E-Print Network [OSTI]

    Fischlin, Andreas

    Oceanic oxygen changes as a bellwether of climate change Term paper in Biogeochemistry@ethz.ch] Tutor: Prof. Dr. Nicholas Gruber [nicholas.gruber@env.ethz.ch] Abstract The response of oceanic oxygen of climate change. Recent publications indicate that the oceanic oxygen outgassing is substaintially larger

  9. Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear molybdenum chloride clusters. Measurements of the probe operating in a 0%­21% gaseous oxygen environment have

  10. THE OXYGEN REQUIREMENTS OF SHELLFISH By Philip H. Mitchell

    E-Print Network [OSTI]

    THE OXYGEN REQUIREMENTS OF SHELLFISH ~ By Philip H. Mitchell 2°7 #12;Blank page retained for pagination #12;THE OXYGEN REQUIREMENTS OF SHELLFISH. By PHILIP H. MITCHELL. J1, The respiratory exchanges to temperature changes, a smaller utili- zation of oxygen in proportion to the body weight with increase in size

  11. Field test of two high-pressure direct-contact downhole steam generators. Volume II. Oxygen/diesel system

    SciTech Connect (OSTI)

    Moreno, J.B.

    1983-07-01T23:59:59.000Z

    A field test of an oxygen/diesel fuel, direct contact steam generator has been completed. The field test, which was a part of Project DEEP STEAM and was sponsored by the US Department of Energy, involved the thermal stimulation of a well pattern in the Tar Zone of the Wilmington Oil Field. The activity was carried out in cooperation with the City of Long Beach and the Long Beach Oil Development Company. The steam generator was operated at ground level, with the steam and combustion products delivered to the reservoir through 2022 feet of calcium-silicate insulated tubing. The objectives of the test included demonstrations of safety, operational ease, reliability and lifetime; investigations of reservoir response, environmental impact, and economics; and comparison of those points with a second generator that used air rather than oxygen. The test was extensively instrumented to provide the required data. Excluding interruptions not attributable to the oxygen/diesel system, steam was injected 78% of the time. System lifetime was limited by the combustor, which required some parts replacement every 2 to 3 weeks. For the conditions of this particular test, the use of trucked-in LOX resulted in liess expense than did the production of the equivalent amount of high pressure air using on site compressors. No statistically significant production change in the eight-acre oxygen system well pattern occurred during the test, nor were any adverse effects on the reservoir character detected. Gas analyses during the field test showed very low levels of SOX (less than or equal to 1 ppM) in the generator gaseous effluent. The SOX and NOX data did not permit any conclusion to be drawn regarding reservoir scrubbing. Appreciable levels of CO (less than or equal to 5%) were measured at the generator, and in this case produced-gas analyses showed evidence of significant gas scrubbing. 64 figures, 10 tables.

  12. E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

  13. Green fluorescent protein based indicators of dynamic redox changes and reactive oxygen species

    E-Print Network [OSTI]

    Dooley, Colette

    2006-01-01T23:59:59.000Z

    attached a singlet oxygen generator to the C-terminal ofencoded singlet oxygen generators, which is currentlyassays. A. Singlet oxygen generator and sensor are tethered;

  14. E-Print Network 3.0 - acute oxygen sensing Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dissolved oxygen with global warming. In coastal regimes oxygen deficits represent acute ecosystem... Ocean oxygen minima expansions and their biological impacts Lothar Stramma...

  15. Oxygen-driven relaxation processes in pre-irradiated Ar cryocrystals

    E-Print Network [OSTI]

    Savchenko, E. V; Belov, A. G; Gumenchuk, G. B; Ponomaryov, A. N; Bondybey, V. E

    2006-01-01T23:59:59.000Z

    Excitations of Solid Oxygen ?in Russian?, B. I. Verkin andNUMBER 11 NOVEMBER 2006 Oxygen-driven relaxation processes? Relaxation processes in oxygen-containing Ar cryocrystals

  16. OXYGEN REDUCTION WITH CARBON SUPPORTED METALLIC CLUSTER CATALYSTS IN ALKALINE ELECTROLYTE

    E-Print Network [OSTI]

    Ross Jr., Philip N.

    2013-01-01T23:59:59.000Z

    be published in the Proceedings OXYGEN REDUCTION WITH CARBONof California. LBL-11891 Oxygen Reduction with Carbonof Pt interacts with both oxygen and water more strongly

  17. Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.

    E-Print Network [OSTI]

    Chakraborty, Subrata

    2013-01-01T23:59:59.000Z

    Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

  18. E-Print Network 3.0 - active oxygen control Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: active oxygen control Page: << < 1 2 3 4 5 > >> 1 Oxygen Modulation via Microfluidic Devices Oxygen...

  19. I. Excluded Volume Effects in Ising Cluster Distributions and Nuclear Multifragmentation II. Multiple-Chance Effects in Alpha-Particle Evaporation

    SciTech Connect (OSTI)

    Breus, Dimitry E.

    2005-05-16T23:59:59.000Z

    In Part 1, geometric clusters of the Ising model are studied as possible model clusters for nuclear multifragmentation. These clusters may not be considered as non-interacting (ideal gas) due to excluded volume effect which predominantly is the artifact of the cluster's finite size. Interaction significantly complicates the use of clusters in the analysis of thermodynamic systems. Stillinger's theory is used as a basis for the analysis, which within the RFL (Reiss, Frisch, Lebowitz) fluid-of-spheres approximation produces a prediction for cluster concentrations well obeyed by geometric clusters of the Ising model. If thermodynamic condition of phase coexistence is met, these concentrations can be incorporated into a differential equation procedure of moderate complexity to elucidate the liquid-vapor phase diagram of the system with cluster interaction included. The drawback of increased complexity is outweighted by the reward of greater accuracy of the phase diagram, as it is demonstrated by the Ising model. A novel nuclear-cluster analysis procedure is developed by modifying Fisher's model to contain cluster interaction and employing the differential equation procedure to obtain thermodynamic variables. With this procedure applied to geometric clusters, the guidelines are developed to look for excluded volume effect in nuclear multifragmentation. In part 2, an explanation is offered for the recently observed oscillations in the energy spectra of {alpha}-particles emitted from hot compound nuclei. Contrary to what was previously expected, the oscillations are assumed to be caused by the multiple-chance nature of {alpha}-evaporation. In a semi-empirical fashion this assumption is successfully confirmed by a technique of two-spectra decomposition which treats experimental {alpha}-spectra has having contributions from at least two independent emitters. Building upon the success of the multiple-chance explanation of the oscillations, Moretto's single-chance evaporation theory is augmented to include multiple-chance emission and tested on experimental data to yield positive results.

  20. Dilute Oxygen Combustion Phase IV Final Report

    SciTech Connect (OSTI)

    Riley, M.F.

    2003-04-30T23:59:59.000Z

    Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

  1. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect (OSTI)

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltán; Horváth, Attila [Institute of Chemistry, Eötvös Loránd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsár, Zoltán [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27T23:59:59.000Z

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  2. Countries Diesel Prices Excluding Taxes

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOilCompanyexcluding taxes) Date Belgium

  3. Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters the water by diffusion from air, as a by-product of photosynthesis and

    E-Print Network [OSTI]

    Tyler, Christy

    Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters and rapids. There is an inverse relationship between temperature and DO, i.e. colder water holds more oxygen it supplies oxygen to aquatic organisms. Higher DO levels also give the water a better taste. Figure 2. During

  4. FORMATION OF MOLECULAR OXYGEN AND OZONE ON AMORPHOUS SILICATES

    SciTech Connect (OSTI)

    Jing Dapeng; He Jiao; Vidali, Gianfranco [Physics Department, Syracuse University, Syracuse, NY 13244 (United States); Brucato, John Robert; Tozzetti, Lorenzo [Osservatorio Astrofisico di Arcetri, INAF, I-50125 Florence (Italy); De Sio, Antonio [Department of Physics and Astronomy, University of Florence, I-50125 Florence (Italy)

    2012-09-01T23:59:59.000Z

    Oxygen in the interstellar medium is seen in the gas phase, in ices (incorporated in H{sub 2}O, CO, and CO{sub 2}), and in grains such as (Mg{sub x} Fe{sub 1-x} )SiO{sub 3} or (Mg{sub x} Fe{sub 1-x} ){sub 2}SiO{sub 4}, 0 < x < 1. In this investigation, we study the diffusion of oxygen atoms and the formation of oxygen molecules and ozone on the surface of an amorphous silicate film. We find that ozone is formed at low temperature (<30 K), and molecular oxygen forms when the diffusion of oxygen atoms becomes significant, at around 60 K. This experiment, besides being the first determination of the diffusion energy barrier (1785 {+-} 35 K) for oxygen atoms on a silicate surface, suggests bare silicates as a possible storage place for oxygen atoms in low-A{sub v} environments.

  5. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

    2014-09-30T23:59:59.000Z

    The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

  6. How Plants Do It: Light, Oxygen, Action!

    SciTech Connect (OSTI)

    Yachandra, Vittal (University of California, Berkeley) [University of California, Berkeley

    2008-08-26T23:59:59.000Z

    Plants have been doing it with ease for millions of years, and yet science has yet to fully comprehend how: Photosynthesis. It's a fundamental process of all plant life on Earth, using the simple and abundant ingredients of water and light to create food and enrich the planet's atmosphere with life-giving oxygen. In this talk, Professor Yachandra discusses how understanding the process of photosynthesis holds the key to a whole new level of mastery of how energy is produced, with enormous implications for the economy and the environment.

  7. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect (OSTI)

    Timothy L. Ward

    2000-06-30T23:59:59.000Z

    Mixed-conducting membranes have the ability to conduct oxygen with perfect selectivity at elevated temperatures, which makes them an extremely attractive alternative for oxygen separation and membrane reactor applications. The ability to reliably fabricate these membranes in thin or thick films would enable solid-state divisional limitations to be minimized, thus providing higher oxygen flux. Based on that motivation, the overall objective for this project is to develop and demonstrate a strategy for the fabrication of supported Wick film ceramic mixed conducting membranes, and improve the understanding of the fundamental issues associated with reliable fabrication of these membranes. The project has focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} because of its superior permeability and stability in reducing atmospheres. The fabrication strategy employed involves the deposition of SrCo{sub 0.5}FeO{sub x} thick films onto porous supports of the same composition. In the second year of this project, we completed characterization of the sintering and phase behavior of the porous SrCo{sub 0.5}FeO{sub x} supports, leading to a standard support fabrication methodology. Using a doctor blade method, pastes made from aerosol-derived SrCo{sub 0.5}FeO{sub x} powder dispersed with polyethylene glycol were applied to the supports, and the sintering behavior of the thick film membranes was examined in air and nitrogen atmospheres. It has been demonstrated that the desired crystalline phase content can be produced in the membranes, and that the material in the membrane layer can be highly densified without densifying the underlying support. However, considerable cracking and opening of the film occurred when films densified to a high extent. The addition of MgO into the SrCo{sub 0.5}FeO{sub x} supports was shown to inhibit support sintering so that temperatures up to 1300 C, where significant liquid formation occurs, could be used for film sintering. This successfully reduced cracking, however the films retained open porosity. The investigation of this concept will be continued in the final year of the project. Investigation of a metal organic chemical vapor deposition (MOCVD) method for defect mending in dense membranes was also initiated. An appropriate metal organic precursor (iron tetramethylheptanedionate) was identified whose deposition can be controlled by access to oxygen at temperatures in the 280-300 C range. Initial experiments have deposited iron oxide, but only on the membrane surface; thus refinement of this method will continue.

  8. Oxygen stabilized zirconium-vanadium-iron alloy

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  9. Jupiter Oxygen Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429 Throttled (botOpen6 Climate ZoneJeromeCounty isJupiter Oxygen Corporation

  10. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01T23:59:59.000Z

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  11. Oxygen Abundance Measurements of SHIELD Galaxies

    E-Print Network [OSTI]

    Haurberg, Nathalie C; Cannon, John M; Marshall, Melissa V

    2015-01-01T23:59:59.000Z

    We have derived oxygen abundances for 8 galaxies from the Survey of HI in Extremely Low-mass Dwarfs (SHIELD). The SHIELD survey is an ongoing study of very low-mass galaxies, with M$_{\\rm HI}$ between 10$^{6.5}$ and 10$^{7.5}$ M$_{\\odot}$, that were detected by the Arecibo Legacy Fast ALFA (ALFALFA) survey. H$\\alpha$ images from the WIYN 3.5m telescope show that these 8 SHIELD galaxies each possess one or two active star-forming regions which were targeted with long-slit spectral observations using the Mayall 4m telescope at KPNO. We obtained a direct measurement of the electron temperature by detection of the weak [O III] $\\lambda$4363 line in 2 of the HII regions. Oxygen abundances for the other HII regions were estimated using a strong-line method. When the SHIELD galaxies are plotted on a B-band luminosity-metallicity diagram they appear to suggest a slightly shallower slope to the relationship than normally seen. However, that offset is systematically reduced when the near-infrared luminosity is used ins...

  12. OXYGEN DEPLETION IN THE INTERSTELLAR MEDIUM: IMPLICATIONS FOR GRAIN MODELS AND THE DISTRIBUTION OF ELEMENTAL OXYGEN

    SciTech Connect (OSTI)

    Whittet, D. C. B. [New York Center for Astrobiology, and Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, 110 Eighth Street, Troy, NY 12180 (United States)

    2010-02-20T23:59:59.000Z

    This paper assesses the implications of a recent discovery that atomic oxygen is being depleted from diffuse interstellar gas at a rate that cannot be accounted for by its presence in silicate and metallic oxide particles. To place this discovery in context, the uptake of elemental O into dust is considered over a wide range of environments, from the tenuous intercloud gas and diffuse clouds sampled by the depletion observations to dense clouds where ice mantles and gaseous CO become important reservoirs of O. The distribution of O in these contrasting regions is quantified in terms of a common parameter, the mean number density of hydrogen (n{sub H}). At the interface between diffuse and dense phases (just before the onset of ice-mantle growth) as much as {approx}160 ppm of the O abundance is unaccounted for. If this reservoir of depleted oxygen persists to higher densities it has implications for the oxygen budget in molecular clouds, where a shortfall of the same order is observed. Of various potential carriers, the most plausible appears to be a form of O-bearing carbonaceous matter similar to the organics found in cometary particles returned by the Stardust mission. The 'organic refractory' model for interstellar dust is re-examined in the light of these findings, and it is concluded that further observations and laboratory work are needed to determine whether this class of material is present in quantities sufficient to account for a significant fraction of the unidentified depleted oxygen.

  13. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  14. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  15. Dilute oxygen combustion. Phase I report

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  16. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D.

    2009-10-01T23:59:59.000Z

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

  17. The effect of monomolecular films on oxygen transfer across an air-water interface

    E-Print Network [OSTI]

    Mahmoud, Tariq Ahmad

    1967-01-01T23:59:59.000Z

    Rate 8. Effect of Aquasave Monolayer on Oxygen Uptake Rate 9. Effect of Isopropyl Alcohol on Oxygen Uptake Rate 10. Effect of Isopropyl Alcohol on Oxygen Uptake Rate 11. Effect of Isopropyl Alcohol on Oxygen Uptake Rate 12. Effect of Kerosene... on Oxygen Uptake Rate 13. Effect of Kerosene on Oxygen Uptake Rate 14. Effect of n-Pentanol on Oxygen Uptake Rate 15. Effect of n-Pentanol on Oxygen Uptake Rate 16. Effect of Hexane on Oxygen Uptake Rate 17. Effect of Hexane on Oxygen Uptake Rate 18...

  18. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak...

  19. Palladium-Cobalt Particles As Oxygen-Reduction Electrocatalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Palladium-Cobalt Particles As Oxygen-Reduction Electrocatalysts Brookhaven National Laboratory...

  20. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13T23:59:59.000Z

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  1. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the efficiency of solid oxide fuel cells can be improved. Citation: Edmondson PD, WJ Weber, F Namavar, and Y Zhang.2011."Lattice Distortions and Oxygen Vacancies Produced in...

  2. active oxygen probe: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: I present here the results of the first principles studies of the adsorption energetics of the intermediates of the oxygen electro-reduction reaction (ORR)...

  3. Optical dissolved oxygen sensor utilizing molybdenum chloride cluster phosphorescence

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    in oxygen atmospheres 0%­21% were obtained with a signal to noise ratio better than 150. Photobleaching physical principles, electrochemistry or luminescence. Electrochemical devices result in analyte

  4. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    - - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

  5. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  6. Microbial metatranscriptomics in a permanent marine oxygen minimum zone

    E-Print Network [OSTI]

    Stewart, Frank J.

    Simultaneous characterization of taxonomic composition, metabolic gene content and gene expression in marine oxygen minimum zones (OMZs) has potential to broaden perspectives on the microbial and biogeochemical dynamics ...

  7. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Broader source: Energy.gov (indexed) [DOE]

    2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

  8. Modeling Oxygen Transport in Three-Dimensional Capillary Networks.

    E-Print Network [OSTI]

    Fraser, Graham M

    2012-01-01T23:59:59.000Z

    ??The purpose of this thesis was to examine how the use of real 3-dimensional (3D) capillary network geometries affect models of oxygen transport to tissue.… (more)

  9. Electron-Stimulated Production of Molecular Oxygen in Amorphous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precursor Transport Through the Hydrogen Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water on Pt(111): Precursor Transport Through the Hydrogen...

  10. Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Abstract: In a recent work, we have shown that chemically synthesized...

  11. Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High temperature oxygen sensors are widely used for exhaust gas monitoring in automobiles. This particular study explores the use of thin film single crystalline samaria...

  12. Korean oxygenates rule sparks MTBE capacity plans

    SciTech Connect (OSTI)

    Kim, Hyung-Jin

    1994-06-15T23:59:59.000Z

    The Korean government`s strict standard for gasoline sold domestically is expected to have a significant impact on the methyl tert-butyl ether (MTBE) market. The mandate-requiring gasoline oxygen content of 0.5% this year, 0.75% by 1996, and 1.0% by 1998-has sparked a rush by Korean refineries to build new MTBE plants. If expansion plans are carried out, Korea`s MTBE capacity will increase from 280,000 m.t./year to 650,000 m.t./year by 1996, far surpassing predicted demand. Honam Oil, part of the Lucky Group, plans startup of a 100,000-m.t./year unit at Yeochon by early 1996. In addition, by the end of 1996 Ssangyong Oil will bring a 100,000-m.t./year unit onstream.

  13. Dilute Oxygen Combustion - Phase 3 Report

    SciTech Connect (OSTI)

    Riley, Michael F.

    2000-05-31T23:59:59.000Z

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  14. Dilute Oxygen Combustion Phase 3 Final Report

    SciTech Connect (OSTI)

    Riley, M.F.; Ryan, H.M.

    2000-05-31T23:59:59.000Z

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  15. the International Civil Aviation Organization (ICAO) adopted a resolution that not only accepted a long-term strat-egy for reducing emissions but also excluded language intended to prevent unilateral application of EU legislation

    E-Print Network [OSTI]

    Sibille, Etienne

    of atmospheric pollution, airliners cross many borders and fly through many regula- tory jurisdictions a long-term strat- egy for reducing emissions but also excluded language intended to prevent unilateral-standing disagreement between in- dustrialized and developing countries about preventing climate change. Secondly

  16. Reactive oxygen species deglycosilate glomerular a-dystroglycan

    E-Print Network [OSTI]

    Campbell, Kevin P.

    Reactive oxygen species deglycosilate glomerular a-dystroglycan NPJ Vogtla¨nder1 , WPM Tamboer1 open. Reactive oxygen species (ROS) are known to degrade and depolymerize carbohydrates, and to playDa in skeletal muscle, ranging from 120 kDa in brain to 190 kDa in the Torpedo electric organ.8

  17. Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*,

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*, Lee D. Bryant,, Andreas Matzinger obtained from 11 eutrophic lakes and suggests a model describing the consumption of dissolved oxygen (O2) in the hypolimnia of eutrophic lakes as a result of only two fundamental processes: O2 is consumed (i) by settled

  18. Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age

    E-Print Network [OSTI]

    Macalady, Jenn

    Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age D. T photosynthesis to overall primary production would have influ- enced oceanic redox and the Proterozoic O2 budget time in Earth's history, complete dominance of oxygenic photosynthesis in the oceans. This paved

  19. Unexpected Nondissociative Binding of N2O on Oxygen Vacancies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 . Unexpected Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 ....

  20. Singlet oxygen luminescence detection with a fibre-coupled superconducting

    E-Print Network [OSTI]

    Greenaway, Alan

    Singlet oxygen luminescence detection with a fibre-coupled superconducting nanowire single luminescence detection Fibre-based singlet oxygen luminescence detection References Superconducting Detector, is an intermediate in many biological processes. We employ a superconducting nanowire single-photon detector (SNSPD

  1. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Huang, Tao (Manorville, NY)

    2009-12-15T23:59:59.000Z

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  2. Instructions for use Removal of Oxygen and Nitrogen from Niobium

    E-Print Network [OSTI]

    Tachizawa, Kazuya

    Instructions for use #12;------ Removal of Oxygen and Nitrogen from Niobium by External Gettering of Energy Science and Technology, Kyoto University Yoshida-Honmachi, Sakyo-ku, Kyoto 606-01 Japan Keywords External Gettering, Purification of Niobium, Thermodynamics of Impurities, Oxygen Diffusion, Purity

  3. HERSCHEL MEASUREMENTS OF MOLECULAR OXYGEN IN ORION

    SciTech Connect (OSTI)

    Goldsmith, Paul F.; Chen, Jo-Hsin; Li Di [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Liseau, Rene; Black, John H. [Department of Earth and Space Sciences, Chalmers University of Technology, Onsala Space Observatory, SE-439 92 Onsala (Sweden); Bell, Tom A. [Centro de Astrobiologia, CSIC-INTA, 28850 Madrid (Spain); Hollenbach, David [SETI Institute, Mountain View, CA 94043 (United States); Kaufman, Michael J. [Department of Physics and Astronomy, San Jose State University, San Jose, CA 95192 (United States); Lis, Dariusz C. [California Institute of Technology, Cahill Center for Astronomy and Astrophysics 301-17, Pasadena, CA 91125 (United States); Melnick, Gary [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS 66, Cambridge, MA 02138 (United States); Neufeld, David [Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Pagani, Laurent; Encrenaz, Pierre [LERMA and UMR8112 du CNRS, Observatoire de Paris, 61 Av. de l'Observatoire, 75014 Paris (France); Snell, Ronald [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Benz, Arnold O.; Bruderer, Simon [Institute of Astronomy, ETH Zurich, Zurich (Switzerland); Bergin, Edwin [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); Caselli, Paola [School of Physics and Astronomy, University of Leeds, Leeds (United Kingdom); Caux, Emmanuel [Universite de Toulouse, UPS-OMP, IRAP, Toulouse (France); Falgarone, Edith, E-mail: Paul.F.Goldsmith@jpl.nasa.gov [LRA/LERMA, CNRS, UMR8112, Observatoire de Paris and Ecole Normale Superieure, 24 rue Lhomond, 75231 Paris Cedex 05 (France)

    2011-08-20T23:59:59.000Z

    We report observations of three rotational transitions of molecular oxygen (O{sub 2}) in emission from the H{sub 2} Peak 1 position of vibrationally excited molecular hydrogen in Orion. We observed the 487 GHz, 774 GHz, and 1121 GHz lines using the Heterodyne Instrument for the Far Infrared on the Herschel Space Observatory, having velocities of 11 km s{sup -1} to 12 km s{sup -1} and widths of 3 km s{sup -1}. The beam-averaged column density is N(O{sub 2}) = 6.5 x 10{sup 16} cm{sup -2}, and assuming that the source has an equal beam-filling factor for all transitions (beam widths 44, 28, and 19''), the relative line intensities imply a kinetic temperature between 65 K and 120 K. The fractional abundance of O{sub 2} relative to H{sub 2} is (0.3-7.3) x 10{sup -6}. The unusual velocity suggests an association with a {approx}5'' diameter source, denoted Peak A, the Western Clump, or MF4. The mass of this source is {approx}10 M{sub sun} and the dust temperature is {>=}150 K. Our preferred explanation of the enhanced O{sub 2} abundance is that dust grains in this region are sufficiently warm (T {>=} 100 K) to desorb water ice and thus keep a significant fraction of elemental oxygen in the gas phase, with a significant fraction as O{sub 2}. For this small source, the line ratios require a temperature {>=}180 K. The inferred O{sub 2} column density {approx_equal}5 x 10{sup 18} cm{sup -2} can be produced in Peak A, having N(H{sub 2}) {approx_equal} 4 x 10{sup 24} cm{sup -2}. An alternative mechanism is a low-velocity (10-15 km s{sup -1}) C-shock, which can produce N(O{sub 2}) up to 10{sup 17} cm{sup -2}.

  4. Direct tuyere injection of oxygen for enhanced coal combustion

    SciTech Connect (OSTI)

    Riley, M.F. [Praxair, Inc., Tarrytown, NY (United States)

    1996-12-31T23:59:59.000Z

    Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

  5. Nanoparticulate-catalyzed oxygen transfer processes

    DOE Patents [OSTI]

    Hunt, Andrew T. (Atlanta, GA); Breitkopf, Richard C. (Dunwoody, GA)

    2009-12-01T23:59:59.000Z

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  6. Relaxation behavior of oxygen deficient strontium manganite

    SciTech Connect (OSTI)

    Pandey, Namita, E-mail: namita205@gmail.com; Thakur, Awalendra Kumar, E-mail: namita205@gmail.com [Department of Physics, Indian Institute of Technology-Patna, Patna- 800013 (India)

    2014-04-24T23:59:59.000Z

    Conduction behavior of nanocrystalline oxygen deficient ceramic-SrMnO{sub 3–?}(??0.14) has been studied. The structural analysis of nano-SrMnO{sub 2.86} follows hexagonal unit cell structure with P6{sub 3}/mmc (194) space group belonging to 6/mmm point group with 4H – layered type hexagonal-cubic layers. The system have lattice parameters; a = 5.437(92) Å, c = 9.072(92) Å, c/a?1.66 (85) with ? =90° ?= 120° and cell volume, V= 232.35(18). The relaxation times estimated from complex impedance and modulus relaxation spectrum, show the thermally activated system with corresponding activation energies as 0.66 eV and 0.51 eV The stretching factor ‘?’ from the scaled modulus spectrum shows the poly-dispersive non-Debye nature of the system. The hopping number ‘n’ shows the influence of ionic charge carriers which controls the conduction mechanism of nano-SrMnO{sub 2.86}.

  7. Faraday Discuss., 1997, 108, 115130 Excited state dynamics in clusters of oxygen

    E-Print Network [OSTI]

    Continetti, Robert E.

    Faraday Discuss., 1997, 108, 115�130 Excited state dynamics in clusters of oxygen Runjun Li, Karl A clusters of oxygen. Oxygen clusters and liquid oxygen have a com- plicated chemistry due to numerous low) dynamics of small anionic clusters of oxygen. We Ðnd that the dynamics of the neutral DPD pathway

  8. Oxygen diffusion, surface exchange and oxygen semi-permeation performances of Ln2NiO4+ membranes (Ln = La, Pr and Nd)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oxygen diffusion, surface exchange and oxygen semi-permeation performances of Ln2NiO4+ membranes the rate determining step (rds) in oxygen semi-permeation of dense Ln2NiO4+ membranes (with Ln = La, Pr and Nd), a specific setup has been designed, which allowed measuring the oxygen semi-permeation flux

  9. Oxygen Modulation via Microfluidic Devices Oxygen is a key but under-studied metabolic variable. It influences biological phenomena as diverse as

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    Oxygen Modulation via Microfluidic Devices Oxygen is a key but under-studied metabolic variable methods to modulate oxygen are crude and inefficient. Our lab has developed a suite of devices which can rapidly alter oxygen conditions surrounding cells in both position and time.[1-3]. Moreover, because

  10. Flammability of selected heat resistant alloys in oxygen gas mixtures

    SciTech Connect (OSTI)

    Zawierucha, R.; McIlroy, K.; Million, J.F. [Praxair, Inc., Tonawanda, NY (United States)

    1995-12-31T23:59:59.000Z

    Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

  11. Increased intrapulmonary retention of radiolabeled neutrophils in early oxygen toxicity

    SciTech Connect (OSTI)

    Rinaldo, J.E.; English, D.; Levine, J.; Stiller, R.; Henson, J.

    1988-02-01T23:59:59.000Z

    Sequential lung injuries, such as oxygen toxicity followed by septicemia, are common during the adult respiratory distress syndrome (ARDS). As these forms of vascular injury may be mediated in part by polymorphonuclear leukocytes (PMN), aberrant interactions between PMN and previously injured pulmonary endothelium are of both theoretical interest and clinical importance. The present study was undertaken to test the hypothesis that early oxygen toxicity at a dose that injuries pulmonary endothelium relatively selectively alters intrapulmonary neutrophil kinetics. Unanesthetized rats breathing 1.0 atmospheres oxygen for 36 h showed ultrastructural endothelial damage but no edema, injury, or neutrophilic inflammation by histologic criteria. However, in these oxygen-toxic animals, whereas initial accumulation of radiolabeled PMN in lungs was normal, washout of PMN was abnormal at 120 min after infusion, at which point the pulmonary retention of radiolabeled PMN in the lungs of oxygen-treated animals was significantly higher than in control animals (139% of control, p less than 0.0096). Features of our methodology, including avoidance of osmotic stress and use of paired control animals, appear to have greatly enhanced the sensitivity of radiolabeled neutrophils for detecting a subtle abnormality of neutrophil-endothelial interactions. Our studies in the oxygen toxicity model provide the first demonstration in vivo of abnormal intrapulmonary neutrophil kinetics in early oxygen toxicity prior to the onset of histologic evidence of lung injury or inflammation.

  12. Measuring oxygen reduction/evolution reactions on the nanoscale

    SciTech Connect (OSTI)

    Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL; Kumar, Amit [ORNL; Morozovska, A. N. [National Academy of Science of Ukraine, Kiev, Ukraine; Ciucci, Francesco [Harvard-Smithsonian Center for Astrophysics

    2011-01-01T23:59:59.000Z

    The efficiency of fuel cells and metal-air batteries is significantly limited by the activation of oxygen reduction and evolution reactions (ORR/OER). Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologies, the governing mechanisms remain elusive and until now addressable only by macroscopic studies. This lack of nanoscale understanding precludes optimization of material architecture. Here we report direct measurements of oxygen reduction/evolution reactions and oxygen vacancy diffusion on oxygen-ion conductive solid surfaces with sub-10 nanometer resolution. In electrochemical strain microscopy (ESM), the biased scanning probe microscopy tip acts as a moving, electrocatalytically active probe exploring local electrochemical activity. The probe concentrates an electric field in a nanometer-scale volume of material, and bias-induced, picometer-level surface displacements provide information on local electrochemical processes. Systematic mapping of oxygen activity on bare and Pt-functionalized yttria-stabilized zirconia (YSZ) surfaces is demonstrated. This approach allows directly visualization of ORR/OER activation process at the triple-phase boundary, and can be extended to broad spectrum of oxygen-conductive and electrocatalytic materials.

  13. Influence of geometry on liquid oxygen magnetohydrodynamics

    SciTech Connect (OSTI)

    Boulware, Jeffrey C.; Ban, Heng [Department of Mechanical and Aerospace Engineering, Utah State University, 4130 Old Main Hill, Logan, UT 84322-4130 (United States); Jensen, Scott; Wassom, Steve [Space Dynamics Laboratory, Utah State University Research Foundation, 1695 North Research Park Way, North Logan, UT 84341 (United States)

    2010-11-15T23:59:59.000Z

    Magnetic fluid actuators have performed well in industrial applications, but have a limited temperature range due to the freezing point of the carrier fluid. Liquid oxygen (LOX) presents a pure, paramagnetic fluid suitable for use in a cryogenic magnetic fluid system; therefore, it is a potential solution to increasing the thermal range of magnetic fluid technology without the need for magnetic particles. The current study presents experimental work regarding the influence of geometry on the dynamics of a LOX slug in a 1.9 mm quartz tube when pulsed by a solenoid in a closed volume. A numerical analysis calculated the optimal solenoid geometry and balanced the magnetic, damping, and pressure forces to determine optimal slug lengths. Three configurations comprised the experiment: (1) a 24-gauge wire solenoid with an optimized 2.7 cm length slug, (2) a 30-gauge wire solenoid with an optimized 1.3 cm length slug, and (3) a 30-gauge wire solenoid with a nonoptimized 2.5 cm length slug. Typically, the hydrodynamic breakdown limit is calculated and used to determine the system range; however the experiment showed that the hydrodynamic breakdown limit was never reached by the slug. This implied that, instead, the system range should factor in a probabilistic risk of failure calculated as a function of the induced pressure change from its oscillations. The experimental data were also used to establish a nondimensional relationship between the maximum displacement and initial magnetic pressure on the slug. The average initial velocity of the slug was found to be proportional to the initial magnetic pressure, Mason number, and slug length. The results of this study can be used in the design and optimization of a LOX fluid system for space or low-temperature applications. (author)

  14. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect (OSTI)

    Yi, Min [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Shen, Zhigang, E-mail: shenzhg@buaa.edu.cn [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Zhao, Xiaohu [Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liang, Shuaishuai [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liu, Lei [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China)

    2014-04-07T23:59:59.000Z

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  15. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01T23:59:59.000Z

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  16. Production of Ultra-Cold-Neutrons in Solid ?-Oxygen

    E-Print Network [OSTI]

    E. Gutsmiedl; A. Frei; F. Boehle; A. Maier; S. Paul; H. Schober; A. Orecchini

    2010-07-30T23:59:59.000Z

    Our recent neutron scattering measurements of phonons and magnons in solid \\alpha-oxygen have led us to a new understanding of the production mechanismen of ultra-cold-neutrons (UCN) in this super-thermal converter. The UCN production in solid \\alpha-oxygen is dominated by the excitation of phonons. The contribution of magnons to UCN production becomes only slightly important above E >10 meV and at E >4 meV. Solid \\alpha-oxygen is in comparison to solid deuterium less effcient in the down-scattering of thermal or cold neutrons into the UCN energy regime.

  17. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24T23:59:59.000Z

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  18. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect (OSTI)

    Kojda, Danny [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universität Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14T23:59:59.000Z

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  19. Magnetic resonance imaging of the cerebral metabolic rate of oxygen (CMRO?)

    E-Print Network [OSTI]

    Bolar, Divya Sanam

    2010-01-01T23:59:59.000Z

    Oxygen consumption is an essential process of the functioning brain. The rate at which the brain consumes oxygen is known as the cerebral metabolic rate of oxygen (CMRO?). CMRO? is intimately related to brain health and ...

  20. Seasonal and interannual oxygen variability on the Washington and Oregon continental shelves

    E-Print Network [OSTI]

    2015-01-01T23:59:59.000Z

    A. Pe~ na (2013), Declining oxygen on the British ColumbiaE. , and L. I. Gordon (1992), Oxygen solubility in seawater:10.1002/2014JC010254 Key Points: Oxygen model presented for

  1. Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen flux determined by mixed-phase AgAg2O deposition. Atomic oxygen flux determined by mixed-phase AgAg2O deposition. Abstract: The flux of atomic oxygen generated in a...

  2. Triple Oxygen Isotope Measurement of Nitrate to Analyze Impact of Aircraft Emissions

    E-Print Network [OSTI]

    Chan, Sharleen

    P. ; Craig, H. Atmospheric oxygen: isotopic composition andM.H. 1986. A non-mass-dependent oxygen isotope effect in theof ozone from molecular oxygen: the role of symmetry in

  3. Advances in studying bioinorganic reaction mechanisms: isotopic probes of activated oxygen

    E-Print Network [OSTI]

    Roth, Justine P.

    Advances in studying bioinorganic reaction mechanisms: isotopic probes of activated oxygen intermediates in metalloenzymes Justine P Roth Metalloenzymes catalyze reactions of molecular oxygen and its reduced forms through the controlled formation of metal- bound, activated oxygen intermediates

  4. Oxygen Loss from Venus and the Influence of Extreme Solar Wind Conditions

    E-Print Network [OSTI]

    McEnulty, Tess

    2012-01-01T23:59:59.000Z

    and I. Sillanpää (2009), Oxygen ion escape from Venus in aobservations of atmospheric oxygen escape during the passageI. F. Stewart (1981), Hot oxygen BIBLIOGRAPHY atoms in the

  5. High-Velocity Oxygen Fuel Thermal Spray of Fe-Based Amorphous Alloy: a Numerical and Experimental Study

    E-Print Network [OSTI]

    Ajdelsztajn, L.; Dannenberg, J.; Lopez, J.; Yang, N.; Farmer, J.; Lavernia, E. J.

    2009-01-01T23:59:59.000Z

    High-Velocity Oxygen Fuel Thermal Spray of Fe-Basedusing a high velocity oxygen fuel (HVOF) spray processstructure. [12] High velocity oxygen fuel (HVOF) thermal

  6. Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report

    SciTech Connect (OSTI)

    Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

    1994-08-01T23:59:59.000Z

    The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

  7. A method of determining the dissolved oxygen in the moisture of a porous medium and some oxygen diffusion studies

    E-Print Network [OSTI]

    Runkles, Jack Ralph

    1952-01-01T23:59:59.000Z

    this dissolved oxygen The sample chamber apparatus gives ocnsplcte seal of the bottle from the atmosphere The ohsabor does not require a large ameunt Of nitrogen Sb remove all the oxygen from it, It is easily portable and light in weight The proposed method... METHOD QF DETRHRIUIHO THE DISSOLVED OXmEK IE THE MOISTURE OF A POROUS ERDD% @AD SMfE QXYOEB DKFFUSIOE STUDIES ' INTRO DUO fQRF, I Oxygen, bas been known to be important in plant growth fox maay years There has been a great deal of xesearoh...

  8. E-Print Network 3.0 - activity peak oxygen Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Yttria-stabilized zirconia, a well known oxygen ion... including fuel cells, oxygen pumps, and chemical gas sensors because of a number of superior properties... such as heat...

  9. E-Print Network 3.0 - adjuvant hyperbaric oxygen Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ph.D., Editor Summary: . Hyperbaric oxygen is the definitive treat- ment for carbon monoxide poisoning.47 However, pro- ponents... III, Putnam RW, Dean JB: Hyperbaric oxygen and...

  10. E-Print Network 3.0 - apneic oxygenation combined Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the same day were combined for data analysis. The oxygen concentration gradient in the agar... Oxygen sensation and social feeding mediated by a C. elegans guanylate cyclase...

  11. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  12. Aging Enhances the Production of Reactive Oxygen Species andBactericid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

  13. E-Print Network 3.0 - accumulate reactive oxygen Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reactive oxygen Search Powered by Explorit Topic List Advanced Search Sample search results for: accumulate reactive oxygen Page: << < 1 2 3 4 5 > >> 1 CLINICAL CONCEPTS AND...

  14. Low-Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria. Low-Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria. Abstract: Microarray analysis indicated...

  15. E-Print Network 3.0 - atomic oxygen simulation Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen simulation Page: << < 1 2 3 4 5 > >> 1 Influence of oxygen on the interfacial...

  16. E-Print Network 3.0 - adjunctive hyperbaric oxygen Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hyperbaric oxygen Search Powered by Explorit Topic List Advanced Search Sample search results for: adjunctive hyperbaric oxygen Page: << < 1 2 3 4 5 > >> 1 TO: UMRSMAS Divers FR:...

  17. Microfluidic advantage : novel techniques for protein folding and oxygen control in cell cultures

    E-Print Network [OSTI]

    Polinkovsky, Mark E.; Polinkovsky, Mark E.

    2012-01-01T23:59:59.000Z

    Novel Techniques for Protein Folding and Oxygen Control inTemperature Jump System to Study Fast Protein FoldingNovel Techniques for Protein Folding and Oxygen Control in

  18. Impact of ethanol and butanol as oxygenates on SIDI engine efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and...

  19. E-Print Network 3.0 - achieving fast oxygen Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bulletin Collection: Environmental Sciences and Ecology 51 Oxygen diffusion in titanite: Lattice diffusion and fast-path diffusion in single crystals Summary: Oxygen...

  20. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

  1. In-situ generation of oxygen-releasing metal peroxides

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Denham, Miles E. (Aiken, SC)

    2007-01-09T23:59:59.000Z

    A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

  2. Reaction of adsorption substitution of oxygen on a cracking catalyst

    SciTech Connect (OSTI)

    Vishnetskaya, M.V.; Takhtarova, G.N.; Topchieva, K.V.

    1986-04-01T23:59:59.000Z

    In an investigation of catalysts for methanol synthesis and carbon monoxide conversion, the authors have observed, for the first time, the reaction of adsorption substitution of strongly bound oxygen on catalysts containing zeolites and compounds of lanthanum and cerium.

  3. Nano- sized strontium titanate metal oxide semiconductor oxygen gas sensors.

    E-Print Network [OSTI]

    Hu, Ying.

    2008-01-01T23:59:59.000Z

    ??The project focuses on strontium titanate (SrTiO3> material, a very important material for oxygen sensors. The advantages of the material are low cost and stability… (more)

  4. Phosphorescent semiconductor nanocrystals and proteins for biological oxygen sensing

    E-Print Network [OSTI]

    McLaurin, Emily J. (Emily Jane)

    2011-01-01T23:59:59.000Z

    Oxygen is required for cellular respiration by all complex life making it a key metabolic profiling factor in biological systems. Tumors are defined by hypoxia (low pO2), which has been shown to influence response to ...

  5. Dissolution of oxygen reduction electrocatalysts in acidic environment

    E-Print Network [OSTI]

    Gu, Zhihui

    2009-05-15T23:59:59.000Z

    Platinum (Pt) alloy nanoparticles are used as catalysts in electrochemical cells to reduce oxygen to water and to oxidize hydrogen; the overall reaction converts chemical energy into electrical energy. These nanocatalysts are deposited on a carbon...

  6. A DIGITAL CONTROL SYSTEM FOR OPTIMAL OXYGEN TRANSFER

    E-Print Network [OSTI]

    A DIGITAL CONTROL SYSTEM FOR OPTIMAL OXYGEN TRANSFER EFFICIENCY Arnold Schwarzenegger Governor system ............................. 10 5.2 Types of aeration processes of fine bubble diffusers for sub-surface aeration ............ 13 5.5 Process design considerations

  7. Transient Mobility of Oxygen Adatoms upon O2 Dissociation on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    only at the bridging oxygen vacancies, with one O atom healing a vacancy and other O atom bonding at the neighboring Ti site as an adatom. Majority (81%) of O adatoms are found...

  8. Oxygen Vacancies and Ferromagnetism in CoxTi–x–y...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vacancies and Ferromagnetism in CoxTi–x–y. Oxygen Vacancies and Ferromagnetism in CoxTi–x–y. Abstract: Abstract: Cobalt-doped titanium dioxide, or CTO, has...

  9. Oxygen Enrichment in the Process and Chemical Industries

    E-Print Network [OSTI]

    Milne, R. T.

    1984-01-01T23:59:59.000Z

    The rapid escalation in energy prices during recent years has resulted in a resurgence of interest in the energy-saving aspects of oxygen enrichment techniques available to the process and chemical industries. Important side benefits which may...

  10. Hybrid membrane--PSA system for separating oxygen from air

    DOE Patents [OSTI]

    Staiger, Chad L. (Albuquerque, NM); Vaughn, Mark R. (Albuquerque, NM); Miller, A. Keith (Albuquerque, NM); Cornelius, Christopher J. (Blackburg, VA)

    2011-01-25T23:59:59.000Z

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  11. Enhancing SNCR-aided combustion with oxygen addition

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Wu, Kuang Tsai; Bool III, Lawrence E.

    2004-03-09T23:59:59.000Z

    NOx emissions from combustion are reduced, NOx reduction efficiency by SNCR is improved, and other efficiencies are realized, by injecting oxygen into a fuel-rich combustion zone under controlled conditions.

  12. Oxygen enhanced switching to combustion of lower rank fuels

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02T23:59:59.000Z

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  13. Method for making oxygen-reducing catalyst layers

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; O'Neill, David G.

    2010-06-22T23:59:59.000Z

    Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  14. Oxygenation cost estimates for Cherokee, Douglas, and Norris reservoirs

    SciTech Connect (OSTI)

    Fain, T.G.

    1980-10-01T23:59:59.000Z

    The capital and annual costs associated with reoxygenation of the turbine releases at Cherokee, Douglas and Norris Reservoirs using the small bubble injection technique developed for Ft. Patrick Henry Dam were computed. The weekly average dissolved oxygen (DO) deficits were computed for each reservoir for an average year (based on 16 years of records). The total annual cost of an oxygen supply and injection system for each reservoir is presented. 5 refs., 6 figs., 5 tabs.

  15. Determination of carbon, nitrogen, and oxygen in high purity magnesium

    E-Print Network [OSTI]

    Roche, Neil Gerard

    2012-06-07T23:59:59.000Z

    DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

  16. Oxygen consumption by asphalt films and resulting viscosity changes

    E-Print Network [OSTI]

    Carter, Frank Lee

    2012-06-07T23:59:59.000Z

    OXYGEN CONSUMPTION BY ASPHALT FILNS AND RESULTING VISCOSITY CHANGES A Thesis by FRANK LEE CARTER, JR. Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... Nay 1965 Major Subject: Chemistry OXYGEN CONSUMPTION BY ASPHALT FILMS AND RESULTING VISCOSITY CHANGES A Thesis by FRANK LEE CARTER, JR. Approved as to style and content by: (Chairm of Committee) (H o Depa ( mb ) (Membe May 1965...

  17. Frequency effects on the production of reactive oxygen species in atmospheric radio frequency helium-oxygen discharges

    SciTech Connect (OSTI)

    Zhang, Yuantao T.; He Jin [Shandong Provincial Key Lab of UHV Technology and Gas Discharge Physics, School of Electrical Engineering, Shandong University, Jinan, Shandong Province 250061 (China)

    2013-01-15T23:59:59.000Z

    Several experimental and computational studies have shown that increasing frequency can effectively enhance the discharge stability in atmospheric radio-frequency (rf) discharges, but the frequency effects on the reactivity of rf discharges, represented by the densities of reactive oxygen species (ROS), are still far from fully understood. In this paper, a one-dimensional fluid model with 17 species and 65 reactions taken into account is used to explore the influences of the driving frequency on the production and destruction of ROS in atmospheric rf helium-oxygen discharges. From the computational results, with an increase in the frequency the densities of ROS decrease always at a constant power density, however, in the relatively higher frequency discharges the densities of ROS can be effectively improved by increasing the input power density with an expanded oxygen admixture range, while the discharges operate in the {alpha} mode, and the numerical data also show the optimal oxygen admixture for ground state atomic oxygen, at which the peak atomic oxygen density can be obtained, increases with the driving frequency.

  18. The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

    E-Print Network [OSTI]

    The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

  19. A mathematical simulation of oxygen and lactic acid transport in skeletal muscle subject to periodic ischemia

    E-Print Network [OSTI]

    Artigue, Ronald Stephen

    1974-01-01T23:59:59.000Z

    oxidative processes . However, as Jobis and Chance point out, the 21 22 23 oxygen utilization of respiring cells w111 become oxygen dependent at some critical partial pressure of oxygen (p02) such that as the p02 falls so will the oxygen consumpt1on rate...

  20. Effects of oxygenate concentration on species mole fractions in premixed n-heptane flames

    E-Print Network [OSTI]

    Senkan, Selim M.

    -heptane/oxygenate mixtures were 2.7 and 3.4. Three different fuel oxygenates (i.e. MTBE, methanol, and ethanol) were tested tertiary-butyl ether (MTBE), ethyl tertiary-butyl ether (ETBE), and tertiary amyl methyl ether (TAME)) were considered as possible fuel oxygenates. MTBE and ethanol are the most common oxygenates currently used

  1. E-Print Network 3.0 - atomic oxygen beams Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    beams Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen beams...

  2. Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators Reza Loloee1@msu.edu Abstract--Dissolved oxygen concentration is considered the most important water quality variable in fish culture. Reliable and continuous (24/7) oxygen monitoring of dissolved oxygen (DO) in the 1 ­ 11 mg

  3. Oxygen Consumption by Germinating Seeds Advisor: Dr. Neil Budko (n.v.budko@tudelft.nl)

    E-Print Network [OSTI]

    Vuik, Kees

    Oxygen Consumption by Germinating Seeds Advisor: Dr. Neil Budko (n.v.budko@tudelft.nl) Problem) by the Fytagoras B.V. (Leiden): "Seed germination in most seeds depends on the availability of oxygen. Living seeds commences. The availability of oxygen to the embryo in the seed depends on the oxygen concentration around

  4. Controlled oxygen doping of GaN using plasma assisted molecular-beam epitaxy

    E-Print Network [OSTI]

    Myers, Tom

    Controlled oxygen doping of GaN using plasma assisted molecular-beam epitaxy A. J. Ptak, L. J-assisted molecular-beam epitaxy to study the dependence of oxygen incorporation on polarity and oxygen partial pressure. Oxygen incorporates at a rate ten times faster on nitrogen-polar GaN than on the Ga polarity

  5. E-Print Network 3.0 - atomic oxygen beam Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    beam Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen beam...

  6. E-Print Network 3.0 - atomic oxygen interactions Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interactions Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen interactions...

  7. Ocean oxygen minima expansions and their biological impacts Lothar Stramma a,, Sunke Schmidtko a,b

    E-Print Network [OSTI]

    Levin, Lisa

    Ocean oxygen minima expansions and their biological impacts Lothar Stramma a,Ã?, Sunke Schmidtko a Keywords: Deoxygenation Oxygen minimum zones Ecosystem changes Hypoxia Tropical ocean Tropical Atlantic dissolved oxygen with global warming. In coastal regimes oxygen deficits represent acute ecosystem

  8. E-Print Network 3.0 - atomic oxygen densities Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    densities Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen densities...

  9. Turbulent Oxygen Flames in Type Ia Supernovae A. J. Aspden1

    E-Print Network [OSTI]

    Turbulent Oxygen Flames in Type Ia Supernovae A. J. Aspden1 , J. B. Bell1 , and S. E. Woosley2 oxygen flames. The two aims of the paper are to examine the response of the inductive oxygen flame to intense levels of turbulence, and to explore the possibility of transition to detonation in the oxygen

  10. E-Print Network 3.0 - atomic oxygen interaction Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interaction Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen interaction...

  11. Oxygen sublattice defect in cobalt oxide : formation, migration, charge localization and thermodynamic processes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    643 Oxygen sublattice defect in cobalt oxide : formation, migration, charge localization of oxygen defects in CoO using classical simulations. The charge localization in the oxygen vacancy has]. The defect concentration in the oxygen sublattice is several orders of magnitude smaller, but never- theless

  12. Deep-Sea Research II 47 (2000) 227}257 Variations in bioturbation across the oxygen

    E-Print Network [OSTI]

    Levin, Lisa

    Deep-Sea Research II 47 (2000) 227}257 Variations in bioturbation across the oxygen minimum zone 1999; received in revised form 25 March 1999; accepted 30 March 1999 Abstract Oxygen minimum zones) along a transect across the oxygen minimum zone (OMZ) on the Oman margin. Bottom-water oxygen

  13. E-Print Network 3.0 - atomic oxygen density Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    density Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen density...

  14. Oxygen electrode reaction in molten carbonate fuel cells

    SciTech Connect (OSTI)

    Appleby, A.J.; White, R.E.

    1992-07-07T23:59:59.000Z

    Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

  15. Natural Ores as Oxygen Carriers in Chemical Looping Combustion

    SciTech Connect (OSTI)

    Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

    2013-08-01T23:59:59.000Z

    Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

  16. Oxygen abundance in the Sloan Digital Sky Survey

    E-Print Network [OSTI]

    F. Shi; X. Kong; F. Z. Cheng

    2006-03-10T23:59:59.000Z

    We present two samples of $\\hii$ galaxies from the Sloan Digital Sky Survey (SDSS) spectroscopic observations data release 3. The electron temperatures($T_e$) of 225 galaxies are calculated with the photoionized $\\hii$ model and $T_e$ of 3997 galaxies are calculated with an empirical method. The oxygen abundances from the $T_e$ methods of the two samples are determined reliably. The oxygen abundances from a strong line metallicity indicator, such as $R_{23}$, $P$, $N2$, and $O3N2$, are also calculated. We compared oxygen abundances of $\\hii$ galaxies obtained with the $T_e$ method, $R_{23}$ method, $P$ method, $N2$ method, and $O3N2$method. The oxygen abundances derived with the $T_e$ method are systematically lower by $\\sim$0.2 dex than those derived with the $R_{23}$ method, consistent with previous studies based on $\\hii$ region samples. No clear offset for oxygen abundance was found between $T_e$ metallicity and $P$, $N2$ and $O3N2$ metallicity. When we studied the relation between N/O and O/H, we found that in the metallicity regime of $\\zoh > 7.95$, the large scatter of the relation can be explained by the contribution of small mass stars to the production of nitrogen. In the high metallicity regime, $\\zoh > 8.2$, nitrogen is primarily a secondary element produced by stars of all masses.

  17. The effect of an evaporation suppressant upon the liquid film oxygen transfer coefficient

    E-Print Network [OSTI]

    Amad, Mohamad Towfic

    1967-01-01T23:59:59.000Z

    " ? By Winkler Method 32 Oxygen Transfer Coefficient At 21'C Using Distilled Water Without "Aquasave" ? By Winkler Method 33 Oxygen Transfer Coefficient At 36'C Using Distilled Water With "Aquasave" ? By Winkler Method 34 Oxygen Transfer Coefficient At 36'C... Using Distilled Water Without "Aquasave" ? By Winkler Method 35 Oxygen Transfer Coefficient At 21'C Using Blended Water With "Aquasave" ? By D. O. Meter 37 10. Oxygen Transfer Coefficient At 21'C Using Blended Water Without "Aquasave" ? By D. 0...

  18. CRADA Final Report: Ionically Conductive Membranes Oxygen Separation

    SciTech Connect (OSTI)

    Visco, Steven J.

    2001-10-29T23:59:59.000Z

    Scientists at the Lawrence Berkeley National Laboratory (LBNL) in a collaborative effort with Praxair Corporation developed a bench-top oxygen separation unit capable of producing ultra-high purity oxygen from air. The device is based on thin-film electrolyte technology developed at LBNL as part of a solid oxide fuel cell program. The two teams first demonstrated the concept using planar ceramic disks followed by the development of tubular ceramic structures for the bench-top unit. The highly successful CRADA met all technical milestones on time and on budget. Due to the success of this program the industrial partner and the team at LBNL submitted a grant proposal for further development of the unit to the Advanced Technology Program administered by the National Institute of Standar~s. This proposal was selected for funding, and now the two teams are developing a precommercial oxygen separation unit under a 3-year, $6 million dollar program.

  19. Transition metal-promoted oxygen ion conductors as oxidation catalyst

    SciTech Connect (OSTI)

    Liu, W.; Sarofim, A. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Chemical Engineering; Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering

    1994-12-31T23:59:59.000Z

    A novel metal oxide composite catalyst for the complete oxidation of carbon monoxide and hydrocarbons was prepared by combining oxygen ion conducting materials with active transition metals. The oxygen ion conductors used were typical fluorite-type oxides, such as ceria, zirconia, and others. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of oxygen ion conductors. The intimate contact of the two kinds of materials gave rise to a highly active oxidation catalyst. On Cu-Ce-O composite catalysts, 95% of carbon monoxide was oxidized by air at {approximately} 100 C. Complete methane oxidation on the same catalyst took place at {approximately} 550 C. When the stoichiometric amount of sulfur dioxide was sued to oxidize carbon monoxide, 96% of sulfur dioxide was reduced to elemental sulfur at temperatures above 460 C with 99% of sulfur dioxide conversion. This type of composite catalyst also showed excellent resistance to water poisoning.

  20. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01T23:59:59.000Z

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  1. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-11-22T23:59:59.000Z

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  2. Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?

    E-Print Network [OSTI]

    Grula, J W

    2006-01-01T23:59:59.000Z

    How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not ...

  3. New oxygen radical source using selective sputtering of oxygen atoms for high rate deposition of TiO{sub 2} films

    SciTech Connect (OSTI)

    Yasuda, Yoji; Lei, Hao; Hoshi, Yoichi [Department of Electronics and Information Technology, Tokyo Polytechnic University, Kanagawa 243-0297 (Japan); State Key Laboratory for Corrosion and Protection, Surface Engineering of Materials Division, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Department of Electronics and Information Technology, Tokyo Polytechnic University, Kanagawa 243-0297 (Japan)

    2012-11-15T23:59:59.000Z

    We have developed a new oxygen radical source based on the reactive sputtering phenomena of a titanium target for high rate deposition of TiO{sub 2} films. In this oxygen radical source, oxygen radicals are mainly produced by two mechanisms: selective sputter-emission of oxygen atoms from the target surface covered with a titanium oxide layer, and production of high-density oxygen plasma in the space near the magnetron-sputtering cathode. Compared with molecular oxygen ions, the amount of atomic oxygen radicals increased significantly with an increase in discharge current so that atomic oxygen radicals were mainly produced by this radical source. It should be noted that oxygen atoms were selectively sputtered from the target surface, and titanium atoms sputter-emitted from the target cathode were negligibly small. The amount of oxygen radicals supplied from this radical source increased linearly with increasing discharge current, and oxygen radicals of 1 Multiplication-Sign 10{sup 15} atoms/s/cm{sup 2} were supplied to the substrate surface at a discharge current of 1.2 A. We conclude that our newly developed oxygen radical source can be a good tool to achieve high rate deposition and to control the structure of TiO{sub 2} films for many industrial design applications.

  4. Properties of Reactive Oxygen Species by Quantum Monte Carlo

    E-Print Network [OSTI]

    Andrea Zen; Bernhardt L. Trout; Leonardo Guidoni

    2014-03-11T23:59:59.000Z

    The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of Chemistry, Biology and Atmospheric Science. Nevertheless, the electronic structure of such species is a challenge for ab-initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as $N^3-N^4$, where $N$ is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

  5. Properties of reactive oxygen species by quantum Monte Carlo

    SciTech Connect (OSTI)

    Zen, Andrea [Dipartimento di Fisica, La Sapienza - Università di Roma, Piazzale Aldo Moro 2, 00185 Rome (Italy); Trout, Bernhardt L. [Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Ave, Cambridge, Massachusetts 02139 (United States); Guidoni, Leonardo, E-mail: leonardo.guidoni@univaq.it [Dipartimento di Scienze Fisiche e Chimiche, Università degli studi de L'Aquila, Via Vetoio, 67100 Coppito, L'Aquila (Italy)

    2014-07-07T23:59:59.000Z

    The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of chemistry, biology, and atmospheric science. Nevertheless, the electronic structure of such species is a challenge for ab initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution, and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular, we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as N{sup 3} ? N{sup 4}, where N is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

  6. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    SciTech Connect (OSTI)

    Gerlach, T.M. (Geological Survey, Vancouver, WA (United States))

    1993-02-01T23:59:59.000Z

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO[sub 2]. The CO[sub 2]-poor gases are typical of Type II volcanic gases (GERLACH and GRAEBER, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO[sub 2]-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032[degrees]C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the F[sub o[sub 2

  7. Enhancing P-xylene selectivity during m-xylene transformation using mildly pre-coked ZSM-5 catalyst

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    catalyst S. Al-Khattaf* Department of Chemical Engineering, King Fahd University of Petroleum & Minerals for various processes, like the production of synthetic fibres and plasticizers, efforts are continually been been investigated in detail by several workers [1-12]. Modifications of ZSM-5 by various compounds have

  8. Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum

    SciTech Connect (OSTI)

    Cho, P.; Law, C.K.

    1986-11-01T23:59:59.000Z

    Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

  9. ChemicalChemical StratigraphyStratigraphy Oxygen, Carbon, Strontium,

    E-Print Network [OSTI]

    Miami, University of

    2/25/2009 1 ChemicalChemical StratigraphyStratigraphy Oxygen, Carbon, Strontium, Sulphur Isotopes Change. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department evolves over time, with the geological time line running from right to left in this graph. The increased

  10. Characteristics of Knock in Hydrogen-Oxygen-Argon SI Engine

    SciTech Connect (OSTI)

    Killingsworth, N; Rapp, V; Flowers, D; Aceves, S; Chen, J; Dibble, R

    2010-02-23T23:59:59.000Z

    A promising approach for improving the efficiency of internal combustion engines is to employ a working fluid with a high specific heat ratio such as the noble gas argon. Moreover, all harmful emissions are eliminated when the intake charge is composed of oxygen, nonreactive argon, and hydrogen fuel. Previous research demonstrated indicated thermal efficiencies greater than 45% at 5.5 compression ratio in engines operating with hydrogen, oxygen, and argon. However, knock limits spark advance and increasing the efficiency further. Conditions under which knock occurs in such engines differs from typical gasoline fueled engines. In-cylinder temperatures using hydrogen-oxygen-argon are higher due to the high specific heat ratio and pressures are lower because of the low compression ratio. Better understanding of knock under these conditions can lead to operating strategies that inhibit knock and allow operation closer to the knock limit. In this work we compare knock with a hydrogen, oxygen, and argon mixture to that of air-gasoline mixtures in a variable compression ratio cooperative fuels research (CFR) engine. The focus is on stability of knocking phenomena, as well as, amplitude and frequency of the resulting pressure waves.

  11. High-temperature potentiometric oxygen sensor with internal reference

    DOE Patents [OSTI]

    Routbort, Jules L. (Hinsdale, IL); Singh, Dileep (Naperville, IL); Dutta, Prabir K. (Worthington, OH); Ramasamy, Ramamoorthy (North Royalton, OH); Spirig, John V. (Columbus, OH); Akbar, Sheikh (Hilliard, OH)

    2011-11-15T23:59:59.000Z

    A compact oxygen sensor is provided, comprising a mixture of metal and metal oxide an enclosure containing said mixture, said enclosure capable of isolating said mixture from an environment external of said enclosure, and a first wire having a first end residing within the enclosure and having a second end exposed to the environment. Also provided is a method for the fabrication of an oxygen sensor, the method comprising confining a metal-metal oxide solid mixture to a container which consists of a single material permeable to oxygen ions, supplying an electrical conductor having a first end and a second end, whereby the first end resides inside the container as a reference (PO.sub.2).sup.ref, and the second end resides outside the container in the atmosphere where oxygen partial pressure (PO.sub.2).sup.ext is to be measured, and sealing the container with additional single material such that grain boundary sliding occurs between grains of the single material and grains of the additional single material.

  12. A DIGITAL CONTROL SYSTEM FOR OPTIMAL OXYGEN TRANSFER

    E-Print Network [OSTI]

    A DIGITAL CONTROL SYSTEM FOR OPTIMAL OXYGEN TRANSFER EFFICIENCY Arnold Schwarzenegger Governor operations improvement (i.e., operators training, cleaning frequency and methods, process upgrade, etc audits specialist ­ Henryk Melcer Brown & Caldwell, process designer ­ Rod Reardon Camp, Dresser, and Mc

  13. Atomic oxygen patterning from a biomedical needle-plasma source

    SciTech Connect (OSTI)

    Kelly, Seán; Turner, Miles M. [School of Physical Science and National Centre for Plasma Science and Technology, Dublin City University, Dublin (Ireland)] [School of Physical Science and National Centre for Plasma Science and Technology, Dublin City University, Dublin (Ireland)

    2013-09-28T23:59:59.000Z

    A “plasma needle” is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  14. Oxygen and nitrogen diffusion in ?-hafnium from first principles

    SciTech Connect (OSTI)

    O'Hara, Andrew; Demkov, Alexander A., E-mail: demkov@physics.utexas.edu [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States)

    2014-05-26T23:59:59.000Z

    We use a combination of density functional theory and multistate diffusion formalism to analyze the diffusion of oxygen and nitrogen in technologically important hafnium metal. Comparing the local density approximation and the Perdew-Burke-Ernzerhof version of the generalized gradient approximation, we find that a better description of the hafnium lattice in the latter results in the correct sequence of stable and transition states for oxygen interstitials leading to essentially quantitative agreement with experiment. For oxygen diffusion, we find an isotropic temperature-dependent diffusion coefficient of D=0.082e{sup ?2.04/k{sub B}T}cm{sup 2}s{sup ?1} utilizing interstitial sites with hexahedral and octahedral coordination. For the diffusivity of nitrogen, we find that an additional stable interstitial site, the crowdion site, exists and that the diffusion coefficient is D=0.15e{sup ?2.68/k{sub B}T}cm{sup 2}s{sup ?1}. Our results also reproduce the experimental observation that nitrogen diffusivity is lower than that of oxygen in hafnium.

  15. An oxygen reduction electrocatalyst based on carbon nanotubegraphene complexes

    E-Print Network [OSTI]

    Pennycook, Steve

    such as platinum or its alloys are routinely used in fuel cells because of their high activity. Carbon alloys) for the oxygen reduction reaction (ORR) in acidic media for proton-exchange membrane fuel cells1, and designing catalysts with both optimal activity and stability for ORR in acidic solutions all remain

  16. ORIGINAL PAPER Electrochemical reduction of oxygen with iron phthalocyanine

    E-Print Network [OSTI]

    bio- fuel cells) has been increasing [1­6]. The common point for all the biological systems is need Recent interest in electricity production using microbial fuel cells makes it important to better applications in neutral media. Keywords Microbial fuel cells Á Oxygen reduction Á Iron phthalocyanine Á Redox

  17. Fault Tolerant Oxygen Control of a Diesel Engine Air System

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Fault Tolerant Oxygen Control of a Diesel Engine Air System Rainer Nitsche Matthias Bitzer control problem of a Diesel engine air system having a jammed Exhaust Gas Recirculation (EGR) valve of the air system. Keywords: Fault tolerant control, Diesel engine, Air system, Model-based trajectory

  18. ORIGINAL PAPER Sex differences in circulatory oxygen transport parameters

    E-Print Network [OSTI]

    Hinch, Scott G.

    aerobic energy demands, and suggests that the higher [Hb] of female fish may com- pensate for the smaller has commenced, and so their stored energy reserves must satisfy the energetic demands of the migra rMV. These findings reject the hypothesis that all aspects of the circulatory oxygen trans- port

  19. Process for conversion of lignin to reformulated, partially oxygenated gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    2001-01-09T23:59:59.000Z

    A high-yield process for converting lignin into reformulated, partially oxygenated gasoline compositions of high quality is provided. The process is a two-stage catalytic reaction process that produces a reformulated, partially oxygenated gasoline product with a controlled amount of aromatics. In the first stage of the process, a lignin feed material is subjected to a base-catalyzed depolymerization reaction, followed by a selective hydrocracking reaction which utilizes a superacid catalyst to produce a high oxygen-content depolymerized lignin product mainly composed of alkylated phenols, alkylated alkoxyphenols, and alkylbenzenes. In the second stage of the process, the depolymerized lignin product is subjected to an exhaustive etherification reaction, optionally followed by a partial ring hydrogenation reaction, to produce a reformulated, partially oxygenated/etherified gasoline product, which includes a mixture of substituted phenyl/methyl ethers, cycloalkyl methyl ethers, C.sub.7 -C.sub.10 alkylbenzenes, C.sub.6 -C.sub.10 branched and multibranched paraffins, and alkylated and polyalkylated cycloalkanes.

  20. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01T23:59:59.000Z

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  1. Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands

    E-Print Network [OSTI]

    Goddard III, William A.

    Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands Jason M. Gonzales, Jonas, California 90089 ReceiVed July 31, 2006 Trends in methane activation have been explored for rhenium complexes proceeds with methane activation through a barrier of less than 35 kcal mol-1 . Study

  2. RESPONSE TO OXYGEN DEFICIENCY SENSING EQUIPMENT IN LABORATORIES

    E-Print Network [OSTI]

    Jia, Songtao

    /or lights to warn both the room occupants and those outside the room of the hazard within. 2. Equipment: Vacuum flask that holds liquid air or helium for scientific experiments. Hazardous Atmosphere. Type and location of oxygen deficiency monitoring equipment. When New York Fire Department (FDNY

  3. Subtask 3.12 - Oxygen-Fired CFBC

    SciTech Connect (OSTI)

    Douglas Hajicek; Mark Musich; Ann Henderson

    2007-02-28T23:59:59.000Z

    Traditionally, air is used as the source of oxygen for firing a combustion system. A fully oxygen-fired circulating fluidized-bed combustion (CFBC) system would result in the production of a flue gas stream consisting of mostly carbon dioxide and water. The concentrated carbon dioxide stream would be available for sequestering or other purposes. Temperatures in an oxygen-blown CFBC system would be controlled by a combination of flue gas recycle, solids recirculation, and by appropriately sizing and locating the amount of heat-transfer surface required. Flue gas recycle provides the additional gas required for adequate fluidization and circulation of solids replacing the nitrogen that would be present in an air-blown system. The amount of flue gas recycle will determine how much of the remaining heat from the coal combustion will have to be removed. If the amount of flue gas recycle required by increasing solids recirculation and oxygen staging is limited, introducing the pure oxygen at multiple locations in the combustor to result in a more even temperature profile should result in a more compact system, thus reducing initial capital costs for construction. The overall efficiency of the process should be greater than that of an air-blown system since less fuel is required for the creation of the same amount of energy. The Energy & Environmental Research Center (EERC) is in a unique position to advance this technology. It has a world-class CFBC pilot plant, has experience with firing a wide range of fuels in our air-fired CFBC pilot plant, has prior experience with oxygen-firing a slagging furnace system in a pulverized coal-fired mode with a bituminous coal, and has all of the components required for oxygen-firing right next to the CFBC pilot plant already in place. An engineering study was performed to identify methods, an overall appropriate configuration, and an operating strategy for a fully oxygen-fired CFBC pilot plant by: (1) developing a plan to optimize the amount of flue gas recycle required to control bed temperature; (2) determining how to best utilize the heat-transfer surfaces in a CFBC pilot plant, such as increased external bed surface, to more beneficially use increased solids recycle; (3) identifying appropriate methods for staged addition of the oxygen/recycled flue gas streams to maintain a good temperature profile in the combustor; and (4) determining the level of effort required to convert the EERC CFBC pilot plant to one that is oxygen-blown. The EERC additionally used its experience to consider what would be required for firing a wide range of fuels from biomass to low-rank coals to high-rank coals and petroleum cokes. These proposed modifications will be performed based upon obtaining the required funding.

  4. Electrocatalysis of anodic and cathodic oxygen-transfer reactions

    SciTech Connect (OSTI)

    Wels, B.R.

    1990-09-21T23:59:59.000Z

    The electrocatalysis of oxygen-transfer reactions is discussed in two parts. In Part I, the reduction of iodate (IO{sub 3}{sup {minus}}) is examined as an example of cathodic oxygen transfer. On oxide-covered Pt electrodes (PtO), a large cathodic current is observed in the presence of IO{sub 3}{sup {minus}} to coincide with the reduction of PtO. The total cathodic charge exceeds the amount required for reduction of PtO and IO{sub 3}{sup {minus}} to produce an adsorbed product. An electrocatalytic link between reduction of IO{sub 3}{sup {minus}} and reduction of PtO is indicated. In addition, on oxide-free Pt electrodes, the reduction of IO{sub 3}{sup {minus}} is determined to be sensitive to surface treatment. The electrocatalytic oxidation of CN{sup {minus}} is presented as an example of anodic oxygen transfer in Part II. The voltametric response of CN{sup {minus}} is virtually nonexistent at PbO{sub 2} electrodes. The response is significantly improved by doping PbO{sub 2} with Cu. Cyanide is also oxidized effectively at CuO-film electrodes. Copper is concluded to serve as an adsorption site for CN{sup {minus}}. It is proposed that an oxygen tunneling mechanism comparable to electron tunneling does not occur at the electrode-solution interface. The adsorption of CN{sup {minus}} is therefore considered to be a necessary prerequisite for oxygen transfer. 201 refs., 23 figs., 2 tabs.

  5. Oxygen and Nitrogen in Isolated Dwarf Irregular Galaxies

    E-Print Network [OSTI]

    L. van Zee; M. P. Haynes

    2005-09-22T23:59:59.000Z

    We present long slit optical spectroscopy of 67 HII regions in 21 dwarf irregular galaxies to investigate the enrichment of oxygen, nitrogen, neon, sulfur, and argon in low mass galaxies. Oxygen abundances are obtained via direct detection of the temperature sensitive emission lines for 25 HII regions; for the remainder of the sample, oxygen abundances are estimated from strong line calibrations. The direct abundance determinations are compared to the strong-line abundance calibrations of both McGaugh (1991) and Pilyugin (2000). Global oxygen and nitrogen abundances for this sample of dwarf irregular galaxies are examined in the context of open and closed box chemical evolution models. While several galaxies are consistent with closed box chemical evolution, the majority of this sample have an effective yield ~1/4 of the expected yield for a constant star formation rate and Salpeter IMF, indicating that either outflow of enriched gas or inflow of pristine gas has occurred. The effective yield strongly correlates with M_H/L_B in the sense that gas-rich galaxies are more likely to be closed systems. However, the effective yield does not appear to correlate with other global parameters such as dynamical mass, absolute magnitude, star formation rate or surface brightness. A correlation is found between the observed nitrogen-to-oxygen ratio and the color of the underlying stellar population; redder dwarf irregular galaxies have higher N/O ratios than blue dwarf irregular galaxies. The relative abundance ratios are interpreted in the context of delayed release of nitrogen and varied star formation histories.

  6. Normal muscle oxygen consumption and fatigability in sickle cell patients despite reduced microvascular oxygenation and hemorheological abnormalities

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Normal muscle oxygen consumption and fatigability in sickle cell patients despite reduced hypothesized that muscle metabolism and fatigability could be impaired in sickle cell patients, no study has profile at rest between 16 healthy subjects (AA), 20 sickle cell-hemoglobin C disease (SC) patients and 16

  7. IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS

    SciTech Connect (OSTI)

    Boehman, Andre L.

    2000-08-20T23:59:59.000Z

    As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

  8. OXYGEN CONSUMPTION OF NORMAL AND GREEN OYSTERS 1 PAUL S. GALTSOFF, Ph. D., In Charge, Oyster Fishery Investigations

    E-Print Network [OSTI]

    OXYGEN CONSUMPTION OF NORMAL AND GREEN OYSTERS 1 $ By PAUL S. GALTSOFF, Ph. D., In Charge, Oyster _ ~ethod _ Oxygen consumption of normal oyster _ Effect of oxygen tension on oxygen con- sumption _ Page 489 Increased rate of metabolism _ 490 Experiments with green oysters _ 493 Oxygen consumption

  9. Effects of Hydration and Oxygen Vacancy on CO2 Adsorption and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydration and Oxygen Vacancy on CO2 Adsorption and Activation on ?-Ga2O3(100). Effects of Hydration and Oxygen Vacancy on CO2 Adsorption and Activation on ?-Ga2O3(100)....

  10. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenati...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on...

  11. Electronic structure of perovskite oxide surfaces at elevated temperatures and its correlation with oxygen reduction reactivity

    E-Print Network [OSTI]

    Chen, Yan, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    The objective is to understand the origin of the local oxygen reduction reaction (ORR) activity on the basis of the local electronic structure at the surface of transition metal oxides at elevated temperatures and in oxygen ...

  12. Fundamental studies of heterostructured oxide thin film electrocatalysts for oxygen reduction at high temperatures

    E-Print Network [OSTI]

    Crumlin, Ethan J

    2012-01-01T23:59:59.000Z

    Searching for active and cost-effective catalysts for oxygen electrocatalysis is essential for the development of efficient clean electrochemical energy technologies. Perovskite oxides are active for surface oxygen exchange ...

  13. Direct Electrolysis of Molten Lunar Regolith for the Production of Oxygen and Metals on the Moon

    E-Print Network [OSTI]

    Sirk, Aislinn H.

    The feasibility of producing oxygen by direct electrolysis of the molten lunar regolith at 1600 C was investigated and the generation of usable oxygen gas at the anode and concomitant production of iron and silicon at the ...

  14. E-Print Network 3.0 - atomic oxygen irradiation Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with ground-state atomic oxygen O(3P) has been investigated... It was suggested that the UV dissociates ozone into atomic oxygen, which is responsible for the degradation... be...

  15. Surface structure of ?-Cr2O3(0001) after activated oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface structure of ?-Cr2O3(0001) after activated oxygen exposure. Surface structure of ?-Cr2O3(0001) after activated oxygen exposure. Abstract: The surface structure...

  16. E-Print Network 3.0 - arabian sea oxygen Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen Search Powered by Explorit Topic List Advanced Search Sample search results for: arabian sea oxygen Page: << < 1 2 3 4 5 > >> 1 The origin of summer monsoon rainfall at New...

  17. Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated FeO(111) Surfaces . Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated FeO(111)...

  18. A Mechanism of Photo-Induced Desorption of Oxygen Atoms From...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Photo-Induced Desorption of Oxygen Atoms From MgO Nano-Crystals. A Mechanism of Photo-Induced Desorption of Oxygen Atoms From MgO Nano-Crystals. Abstract: In a series of recent...

  19. Development, testing, and application of quantitative oxygenation imaging from magnetic susceptibility by MRI

    E-Print Network [OSTI]

    Fan, Audrey Peiwen

    2014-01-01T23:59:59.000Z

    The healthy brain consumes 20% of total oxygen used by the body under normal conditions. Continuous oxygen delivery to neural tissue is needed to maintain normal brain function and viability. Reliable measurements of brain ...

  20. Modulation of mixed-phase titania photoluminescence by oxygen adsorption

    SciTech Connect (OSTI)

    Pallotti, D.; Orabona, E.; Amoruso, S.; Maddalena, P. [Dipartimento di Fisica, Universitá degli Studi di Napoli “Federico II,” Via Cintia, I-80126 Napoli (Italy); Institute for Superconductors, Oxides and Innovative Materials and Devices, CNR-SPIN, U.O.S. Napoli, Via Cintia, I-80126 Napoli (Italy); Lettieri, S., E-mail: stefano.lettieri@spin.cnr.it [Institute for Superconductors, Oxides and Innovative Materials and Devices, CNR-SPIN, U.O.S. Napoli, Via Cintia, I-80126 Napoli (Italy)

    2014-07-21T23:59:59.000Z

    We investigate the effect of oxygen (O{sub 2}) adsorption on photoluminescence properties of mixed-phase titania nanoparticle films deposited by femtosecond pulsed laser deposition, aiming to assess preliminary conclusions about the feasibility of opto-chemical sensing based on titania. We evidence that O{sub 2} produces opposite responses in rutile and anatase photoluminescence efficiency, highlighting interesting potentialities for future double-parametric optical sensing based on titania. The results evidence an important role of lattice oxygen atoms, suggesting that the standard Schottky barrier mechanism driving the response toward gas species in most used metal-oxide sensors (e.g., tin dioxide) is not the only active mechanism in titania.

  1. Toxicological and performance aspects of oxygenated motor vehicle fuels

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    At the request of the Environmental Protection Agency, the committee reviewed a draft of a federal report that assesses the effects of oxygenated fuels on public health, air quality, fuel economy, engine performance, and water quality. The committee determined that much of the federal report adequately represents what is known about the effects of methyl tertiary-butyl ether (MTBE) -- the most commonly used additive in the federal oxygenated-fuels program -- on health, the environment, and motor vehicles. MTBE, a chemical added to gasoline to reduce carbon monoxide pollution, appears not to pose a substantial human health risk, but more-definitive data are needed to assess short-term health effects and to determine whether this additive is effective in reducing carbon monoxide pollution in cold environments.

  2. Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion

    SciTech Connect (OSTI)

    Bhavsar, Saurabh; Veser, Goetz

    2013-11-06T23:59:59.000Z

    The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

  3. Evaluation of Advanced PSA and Oxygen Combustion System for Industrial Furnace Applications

    E-Print Network [OSTI]

    Delano, M. A.; Lagree, D.; Kwan, Y.

    M. A. Delano Union Carbide Corp. Tarrytown, NY ABSTRACT EVALUATION OF ADVANCED PSA AND OXYGEN COMBUSTION SYSTEM FOR INDUSTRIAL FURNACE APPLICATIONS D. Lagree Union Carbide Corp. Tonawanda, NY The performance of a pilot scale advanced PSA... oxygen generation system and a low NO x oxygen burner was evaluated for industrial furnace applications. The PSA system employs a two-bed vacuum cycle design with a capacity of 1.3 TPD at 90% O 2 purity. The oxygen generated from the PSA system...

  4. Hydrogen Production from Methane Using Oxygen-permeable Ceramic Membranes

    E-Print Network [OSTI]

    Faraji, Sedigheh

    2010-06-08T23:59:59.000Z

    is the existence of hot spots in the catalyst bed due to the reaction exothermicity [1]. This hydrogen production process could be cost-effective if oxygen is provided by sources other than air separation plant. CO2 reforming (or dry reforming) of methane... information about equilibrium product compositions and equilibrium constants at different temperatures were provided by one of the former students in Dr Susan Williams’ research group [8]. Syngas can also be produced by coal gasification. The syngas...

  5. Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?

    E-Print Network [OSTI]

    John W. Grula

    2006-05-12T23:59:59.000Z

    How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not been preceded by the evolution of nitrogen fixation, and if these organisms had not also acquired the ability to fix nitrogen at the beginning of or very early in their history. The evolution of nitrogen fixation also appears to have been a precondition for the evolution of (bacterio)chlorophyll-based photosynthesis. Given that some form of chlorophyll is obligatory for true photosynthesis, and its light absorption and chemical properties make it a "universal pigment," it may be predicted that the evolution of nitrogen fixation and photosynthesis are also closely linked on other Earth- like planets.

  6. Oxygen abundance methods in the SDSS: view from modern statistics

    E-Print Network [OSTI]

    F. Shi; G. Zhao; James Wicker

    2007-10-24T23:59:59.000Z

    Our purpose is to find which is the most reliable one among various oxygen abundance determination methods. We will test the validity of several different oxygen abundance determination methods using methods of modern statistics. These methods include Bayesian analysis and information scoring. We will analyze a sample of $\\sim$6000 $\\hii$ galaxies from the Sloan Digital Sky Survey (SDSS) spectroscopic observations data release four. All methods that we used drew the same conclusion that the $T_e$ method is a more reliable oxygen abundance determination methods than the Bayesian metallcity method under the existing telescope ability. The ratios of the likelihoods between the different kinds of methods tell us that the $T_e$, $P$, and $O3N2$ methods are consistent with each other because the $P$ and $O3N2$ method are calibrated by $T_e$-method. The Bayesian and $R_{23}$ method are consistent with each other because both are calibrated by a galaxy model. In either case, the $N2$ method is an {\\it unreliable} method.

  7. The solar oxygen crisis: Probably not the last word

    E-Print Network [OSTI]

    H. Socas-Navarro A. A. Norton

    2007-02-06T23:59:59.000Z

    In this work we present support for recent claims that advocate a downward revision of the solar oxygen abundance. Our analysis employs spatially-resolved spectro-polarimetric observations including the \\FeI lines at 6302 \\AA and the \\OI infrared triplet around 7774 \\AA in the quiet Sun. We used the \\FeI lines to reconstruct the three-dimensional thermal and magnetic structure of the atmosphere. The simultaneous \\OI observations were then employed to determine the abundance of oxygen at each pixel, using both LTE and non-LTE (NLTE) approaches to the radiative transfer. In this manner, we obtain values of \\lgEO=8.63 (NLTE) and 8.93 (LTE) dex. We find an unsettling fluctuation of the oxygen abundance over the field of view. This is likely an artifact indicating that, even with this relatively refined strategy, important physical ingredients are still missing in the picture. By examining the spatial distribution of the abundance, we estimate realistic confidence limits of approximately 0.1 dex.

  8. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, Anthony A. (Allentown, PA)

    1985-01-01T23:59:59.000Z

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  9. INTERNATIONAL CONGRESS OF THE AERONAUTICAL SCIENCES Hypersonic flows of argon, nitrogen, oxygen,

    E-Print Network [OSTI]

    Riabov, Vladimir V.

    , nitrogen, oxygen, and carbon dioxide near a toroidal ballute have been investigated numerically using of nitrogen, dissociating oxygen, argon, and carbon dioxide at 8R H 2R and the Knudsen number Kn D from 02G code [12]. Collisions in nitrogen, argon, oxygen, and carbon dioxide are modeled using

  10. Net production of oxygen in the subtropical ocean Stephen C. Riser1

    E-Print Network [OSTI]

    Riser, Stephen C.

    LETTERS Net production of oxygen in the subtropical ocean Stephen C. Riser1 & Kenneth S. Johnson2% of the global ocean surface area, are net producers or consumers of oxygen and fixed carbon is a key uncertainty in the global carbon cycle1,2 . Direct measurements in bottle experiments indicate net oxygen con- sumption

  11. The Effect of Bicarbonate on Photosynthetic Oxygen Evolution in Flashing Light in Chloroplast Fragments

    E-Print Network [OSTI]

    Govindjee

    been resupplied. However, the final oxygen-evolving reac- tion after the accumulation of four positive of HCO3- in the Hill reaction indicates that this ion plays a critical role in the oxygen- evolving mechanism (1-3). Evidence is available that strongly suggests that HC03- acts on the oxygen-evolving side

  12. J. theor. Biol. (1972) 36,427-446 JCinetic Models of Oxygen Evolution in Photosydhesis~

    E-Print Network [OSTI]

    Govindjee

    reaction center, but in it, each oxygen evolving site has two bound reaction centers II. This alternate that involve the accumulation of two or four positive charges before oxygen is evolved. In order to explain models have been proposed here that equally well explain the data. In the 6rst one, oxygen can be evolved

  13. Production of Oxygen Gas and Liquid Metal by Electrochemical Decomposition of Molten Iron Oxide

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    on the moon and on Mars for the generation of oxygen along with the production of structural metalsProduction of Oxygen Gas and Liquid Metal by Electrochemical Decomposition of Molten Iron Oxide) is the electrolytic decomposition of a metal oxide, most preferably into liquid metal and oxygen gas. The successful

  14. Generation of reactive oxygen species by a persulfide (BnSSH) Tonika Chatterji,

    E-Print Network [OSTI]

    Gates, Kent. S.

    Generation of reactive oxygen species by a persulfide (BnSSH) Tonika Chatterji, Kripa Keerthi generate reactive oxygen species under biologically rele- vant conditions via the sequence of reactions by reactive oxygen species generated in this manner may contribute to the cytotoxic properties of leinamycin

  15. MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES A.T. Vai1 , J.; Woburn, MA, 01801, USA Keywords: ISRU, Molten Oxide Electrolysis, Inert Anode, Oxygen Generation Abstract technology for generating oxygen from lunar regolith simulant. Prior to this work, iridium metal was the only

  16. Nitric Oxide Production from Surface Recombination of Oxygen and Nitrogen Atoms

    E-Print Network [OSTI]

    Martín, Pino

    of hypersonic reentry vehicles. In the Earth's atmosphere, oxygen and nitrogen atoms are generated in the shock1 Nitric Oxide Production from Surface Recombination of Oxygen and Nitrogen Atoms Dusan A. Pejakovi from the recombination of oxygen and nitrogen atoms on quartz. The experiments employ two-photon laser

  17. Effects of applied voltages and dissolved oxygen on sustained power generation by microbial fuel cells

    E-Print Network [OSTI]

    Effects of applied voltages and dissolved oxygen on sustained power generation by microbial fuel), Faculty of Advanced Technology, University of Glamorgan, Pontypridd RCT CF37 1DL, UK Oxygen intrusion chamber MFCs at the end of a cycle when the substrate is depleted. A slight increase in dissolved oxygen

  18. Regulation of Singlet Oxygen Generation Using Single-Walled Carbon Zhiwen Tang,

    E-Print Network [OSTI]

    Tan, Weihong

    Regulation of Singlet Oxygen Generation Using Single-Walled Carbon Nanotubes Zhi Zhu, Zhiwen TangDNA aptamer, and single-walled carbon nanotubes (SWNTs) for controllable singlet oxygen (1 O2) generation. 1 O to tissue oxygen to generate highly reactive 1 O2, an aggressive chemical species, which can react rapidly

  19. Direct Electrolysis of Molten Lunar Regolith for the Production of Oxygen and Metals on the Moon

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    regolith at 1600 ºC was investigated. Oxygen gas at the anode was generated concomitantly with productionDirect Electrolysis of Molten Lunar Regolith for the Production of Oxygen and Metals on the Moon A Center, Florida 32899, USA The feasibility of producing oxygen by direct electrolysis of molten lunar

  20. Performance of a Multistream Injection Chemical OxygenIodine Laser with Starlet Ejectors

    E-Print Network [OSTI]

    Carroll, David L.

    and has the potential for higher pressure recovery. Pressures in the singlet-oxygen generator were technology development to date has focused on the singlet-oxygen generator (SOG). The liquid SOG technology- oxygen generation and transport efficiency. The idea of the starlet nozzle concept stems originally from

  1. Geographic variation in phenotypic plasticity in response to dissolved oxygen in an African cichlid fish

    E-Print Network [OSTI]

    Nuismer, Scott L.

    Geographic variation in phenotypic plasticity in response to dissolved oxygen in an African cichlid variation in a population over a number of generations to result in a population that is locally adapted and plastic variation in gill and brain size among swamp (low oxygen; hypoxic) and river (normal oxygen

  2. Microbial Respiration and Its Consequences on Oxygen Availability in Peat Substrate

    E-Print Network [OSTI]

    Boyer, Edmond

    91 Microbial Respiration and Its Consequences on Oxygen Availability in Peat Substrate R. Naasz, J to Horticulture 2, rue Le Nôtre, F-49045 Angers Cedex 01 France Keywords: peat, oxygen uptake, microorganisms (Sphagnum peat) on oxygen transport and availability to the root. This is why, a one-dimensional transfer

  3. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, A.A.

    1985-07-02T23:59:59.000Z

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  4. Oxygen Transport from the Outer Boundary of a Pulsating Arteriole Wall to the

    E-Print Network [OSTI]

    Salamon, Peter

    Oxygen Transport from the Outer Boundary of a Pulsating Arteriole Wall to the Surrounding Tissue In all living organisms, oxygen transport from arterioles to the surrounding tissue is critical for survival. However, the exact nature of the transport of oxygen from the arteriole to the surrounding tissue

  5. The Rise of Oxygen over the Past 205 Million Years and the Evolution

    E-Print Network [OSTI]

    The Rise of Oxygen over the Past 205 Million Years and the Evolution of Large Placental Mammals to the present, we modeled oxygen concentrations over the past 205 million years. Our analysis indicates that atmospheric oxygen approximately doubled over this period, with rela- tively rapid increases in the early

  6. Surface Science 425 (1999) 114 Non-adiabatic charge transfer process of oxygen on

    E-Print Network [OSTI]

    Zeiri, Yehuda

    Surface Science 425 (1999) 1­14 Non-adiabatic charge transfer process of oxygen on metal surfaces November 1998 Abstract The dynamics of charge transfer processes of oxygen on metal surfaces a different charged oxygen species. Empirical universal potential energy functions have been constructed

  7. Chemical oxygen diffusion coefficient measurement by conductivity relaxation--correlation between tracer diffusion

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Chemical oxygen diffusion coefficient measurement by conductivity relaxation--correlation between J. P., Grenier J. C., Loup J. P. ABSTRACT Chemical oxygen diusion coecient ¯(D)was measured the oxygen partial pressure in the surrounding atmosphere of the sample. The consequent evolution

  8. Oxygen diffusion and reactions in Hf-based dielectrics L. V. Goncharova,a

    E-Print Network [OSTI]

    Gustafsson, Torgny

    Oxygen diffusion and reactions in Hf-based dielectrics L. V. Goncharova,a M. Dalponte, D. G Oxygen transport in and reactions with thin hafnium oxide and hafnium silicate films have been. The exchange rate is faster for pure hafnium oxides than for silicates. The amount of exchanged oxygen

  9. INTRODUCTION A general problem for all animals is the supply of oxygen to

    E-Print Network [OSTI]

    Krasnow, Mark A.

    INTRODUCTION A general problem for all animals is the supply of oxygen to internal tissues. The common structural solution is formation of a branched tubular network that transports air or oxygenated (respiratory) system, fine branches ramify on or near the oxygen-requiring tissues, with the extent

  10. Oxygen and Nitroaen Contamination During Submerged Arc Wel ding of Titanium

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ) ) ) ··- -~ Oxygen and Nitroaen Contamination During Submerged Arc Wel ding of Titanium T· \\v· Eagar* The oxygen content of ti tanium submerged arc wel ~ metal is primaril y derendent uron the purity of the fluo1~ ide fluxes, but it is shown here that the oxygen content of the weld metal may be affected

  11. Oxygen: A Fundamental Property Regulating Pelagic Ecosystem Structure in the Coastal Southeastern Tropical

    E-Print Network [OSTI]

    Oxygen: A Fundamental Property Regulating Pelagic Ecosystem Structure in the Coastal Southeastern questions about the role of temperature. Here we investigate the role of oxygen in structuring fish that the distribution of oxygen in the ocean is changing with uncertain consequences. Methodology/Principal Findings

  12. Supplemental Oxygen and Mountaineer Death Rates on Everest and K2

    E-Print Network [OSTI]

    Huey, Raymond B.

    Supplemental Oxygen and Mountaineer Death Rates on Everest and K2 To the Editor: The use of supplemental oxygen by Hima- layan mountaineers has been debated for more than 8 de- cades.1 Although sometimes viewed as unsporting, supplemen- tal-oxygen use may improve survival rates by increasing performance

  13. Atomic oxygen in solid deuterium A. V. Danilychev and V. A. Apkarian*

    E-Print Network [OSTI]

    Apkarian, V. Ara

    Atomic oxygen in solid deuterium A. V. Danilychev and V. A. Apkarian* Department of Chemistry 113, Japan Submitted June 8, 2000 Fiz. Nizk. Temp. 26, 909­917 September­October 2000 Atomic oxygen is photogenerated in solid D2 by 193 nm irradiation of samples initially doped with molecular oxygen. The atoms

  14. Oxygen as a control on seafloor biological communities and their roles in sedimentary carbon cycling

    E-Print Network [OSTI]

    Oxygen as a control on seafloor biological communities and their roles in sedimentary carbon experiments were conducted at sites spanning the steep oxygen, organic matter, and biological community gradients across the Arabian Sea oxygen minimum zone, in order to quantify the role that fauna play

  15. Dissolved oxygen stratification in two micro-tidal partially-mixed estuaries

    E-Print Network [OSTI]

    Mallin, Michael

    Dissolved oxygen stratification in two micro-tidal partially-mixed estuaries Jing Lin a,*, Lian Xie online 21 August 2006 Abstract The controlling physical factors for vertical oxygen stratification that vertical stratification of dissolved oxygen (DO) concentration can be explained by the extended Hansen

  16. Oxygen driven reconstruction dynamics of Ni,,977... measured by time-lapse scanning tunneling microscopy

    E-Print Network [OSTI]

    Sibener, Steven

    Oxygen driven reconstruction dynamics of Ni,,977... measured by time-lapse scanning tunneling-lapse scanning tunneling microscopy STM has been used to observe the oxygen induced reconstruction behavior of Ni for the merging of steps in the presence of small amounts of adsorbed oxygen, less than 2% of a monolayer. Point

  17. Oxygen chemisorption on Au nanoparticles A. Franceschetti a,b,*, S.J. Pennycook b

    E-Print Network [OSTI]

    Pennycook, Steve

    Oxygen chemisorption on Au nanoparticles A. Franceschetti a,b,*, S.J. Pennycook b , S.T. Pantelides; in final form 11 March 2003 Abstract Oxygen molecules do not adsorb on flat gold surfaces at room temperature, but recent experimental results have demonstrated adsorption of oxygen on small, negatively

  18. Oxygen isotopic disequilibrium in plagioclasecorundumhercynite xenoliths from the Voisey's Bay Intrusion, Labrador, Canada

    E-Print Network [OSTI]

    Oxygen isotopic disequilibrium in plagioclase­corundum­hercynite xenoliths from the Voisey's Bay to skeletal. Ion microprobe analyses indicate that oxygen isotopic equilibrium was neither established during corundum is characterized by 18 O values between 2.5 and 7.6. Oxygen isotopic equilibration with mantle

  19. OXYGEN GAS-PHASE ABUNDANCE REVISITED M. K. Andre,1,2

    E-Print Network [OSTI]

    Howk, Jay Christopher

    OXYGEN GAS-PHASE ABUNDANCE REVISITED M. K. Andre´,1,2 C. M. Oliveira,2 J. C. Howk,2 R. Ferlet,1 J gas-phase oxygen abundance along the sight lines toward 19 early-type Galactic stars at an average mag�1 with a standard deviation of 15% is consistent with previous surveys. The mean oxygen abundance

  20. Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of

    E-Print Network [OSTI]

    Roth, Justine P.

    Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of Activated O2, Maryland 21218 RECEIVED ON JULY 26, 2008 C O N S P E C T U S Competitively determined oxygen (18 O) isotope effects can be power- ful probes of chemical and biological transformations involving molec- ular oxygen

  1. Movement of oxygen vacancies in oxide film during annealing observed by an optical reflectivity difference technique

    E-Print Network [OSTI]

    Zhu, Xiangdong

    Movement of oxygen vacancies in oxide film during annealing observed by an optical reflectivity. The growth and annealing of the film in vacuum and in oxygen ambient are monitored in real time by an oblique tell whether the oxygen vacancies are moving into or moving out of the film during the annealing

  2. Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps

    E-Print Network [OSTI]

    Bennett, Albert F.

    4111 Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps (Weibel et al., 1981). In mammals, maximal rate of oxygen consumption (VOmax) is not limited by any one step of the oxygen cascade; rather limitations to VOmax are distributed across all steps

  3. Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw

    E-Print Network [OSTI]

    Smith, Bradley D.

    Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw Easwaran Arunkumar-rotaxanes to generate singlet oxygen for potential application in photodynamic therapy (PDT). Specifically, we compare-to-face orientations in the solid state. Singlet oxygen generation efficiency was measured by trapping with 1

  4. Molecular H2O as carrier for oxygen diffusion in hydrous silicate melts

    E-Print Network [OSTI]

    Zhang, Youxue

    Molecular H2O as carrier for oxygen diffusion in hydrous silicate melts H. Behrens a,, Y. Zhang b water is known to dramatically enhance oxygen diffusion in silicate melts, glasses and minerals in the diffusion of water and oxygen in silicates, Earth Planet. Sci. Lett., 103 (1991) 228­240.]. Here we report

  5. Oxygen production and carbon sequestration in an upwelling coastal Burke Hales,1

    E-Print Network [OSTI]

    Pierce, Stephen

    Oxygen production and carbon sequestration in an upwelling coastal margin Burke Hales,1 Lee Karp), Oxygen production and carbon sequestration in an upwelling coastal margin, Global Biogeochem. Cycles, 20 of particulate organic carbon (POC) and dissolved O2 during the upwelling season off the Oregon coast. Oxygen

  6. The impact of oxygen on the transcriptome of recombinant S. cerevisiae and P. pastoris - a comparative analysis

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    wise comparisons between oxygen set-points, considering a p-= hypoxic vs. normoxic; HvL = hypoxic vs. oxygen-limited;LvN = oxygen-limited vs. normoxic; Cont = control strain;

  7. Evaluating low oxygen and pH variation and its effects on invertebrate early life stages on upwelling margins /

    E-Print Network [OSTI]

    Frieder, Christina A.

    2013-01-01T23:59:59.000Z

    variability of dissolved oxygen and pH in a nearshoreSAN DIEGO Evaluating low oxygen and pH variation and itsof carbonate chemistry, oxygen saturation, and temperature.

  8. The effects of wavelength, metals, and reactive oxygen species on the sunlight inactivation of microorganisms: observations and applications to the solar disinfection of drinking water

    E-Print Network [OSTI]

    Fisher, Michael Benjamin

    2011-01-01T23:59:59.000Z

    singlet oxygen. Environmental Science & Technology 41(13),Oxygen Mediated Inactivation. Environmental Science & TechnologyOxygen Mediated Inactivation. Environmental Science & Technology

  9. Thermochemical Modeling of the Uranium-Cerium-Oxygen System

    SciTech Connect (OSTI)

    Voit, Stewart L [ORNL; Besmann, Theodore M [ORNL

    2010-10-01T23:59:59.000Z

    The objective of the Fuel Cycle R&D Program, Advanced Fuels campaign is to provide the research and development necessary to develop low loss, high quality nuclear fuels for ultra-high burnup reactor operation. Primary work in this area will be focused on the ceramic and metallic fuel systems. The goal of the current work is to enhance the understanding of ceramic nuclear fuel thermochemistry to support fuel research and development efforts. The thermochemical behavior of oxide nuclear fuel under irradiation is dependent on the oxygen to metal ratio (O:M). In fluorite-structured fuel, the actinide metal cation is bonded with {approx}2 oxygen atoms on a crystal lattice and as the metal atoms fission, fission fragments and free oxygen are created. The resulting fission fragments will contain some oxide forming elements, however these are insufficient to bind to all the liberated oxygen and therefore, there is an average increase in O:M with fuel burnup. Some of the fission products also form species that will migrate to and react with the cladding surface in a phenomenon known as Fuel Clad Chemical Interaction (FCCI). Cladding corrosion is life-limiting so it is desirable to understand influencing factors, such as oxide thermochemistry, which can be used to guide the design and fabrication of higher burn up fuel. A phased oxide fuel thermochemical model development effort is underway within the Advanced Fuels Campaign. First models of binary oxide systems are developed. For nuclear fuel system this means U-O and transuranic systems such as Pu-O, Np-O and Am-O. Next, the binary systems will be combined to form pseudobinary systems such as U-Pu-O, etc. The model development effort requires the use of data to allow optimization based on known thermochemical parameters as a function of composition and temperature. Available data is mined from the literature and supplemented by experimental work as needed. Due to the difficulty of performing fuel fabrication development with actinide materials, fundamental studies with uranium are performed using surrogate materials as stand-ins for transuranic elements. In most cases, cerium can be used as a suitable substitute for plutonium when performing O:M and sintering kinetics studies because of identical valence states. Differences exist between the magnitude of reported thermodynamic data of (U,Pu)O{sub x} and (U,Ce)O{sub x}, however the change in oxygen potential versus O:M follows the same trend for both systems. Cerium is also a major fission product element, and thus understanding its behavior in fuel is an important issue as well.

  10. Oxygen and Nitrogen in Leo A and GR 8

    E-Print Network [OSTI]

    L. van Zee; E. D. Skillman; M. P. Haynes

    2005-09-22T23:59:59.000Z

    We present elemental abundances for multiple HII regions in Leo A and GR 8 obtained from long slit optical spectroscopy of these two nearby low luminosity dwarf irregular galaxies. As expected from their luminosities, and in agreement with previous observations, the derived oxygen abundances are extremely low in both galaxies. High signal-to-noise ratio observations of a planetary nebula in Leo A yield 12 + log(O/H) = 7.30 +/- 0.05; "semi-empirical" calculations of the oxygen abundance in four HII regions in Leo A indicate 12 + log(O/H) = 7.38 +/- 0.10. These results confirm that Leo A has one of the lowest ISM metal abundances of known nearby galaxies. Based on results from two HII regions with high signal-to-noise measurements of the weak [O III] 4363 line, the mean oxygen abundance of GR 8 is 12 + log(O/H) = 7.65 +/- 0.06; using "empirical" and "semi-empirical" methods, similar abundances are derived for 6 other GR 8 HII regions. Similar to previous results in other low metallicity galaxies, the mean log(N/O) = -1.53 +/- 0.09 for Leo A and -1.51 +/- 0.07 for GR 8. There is no evidence of significant variations in either O/H or N/O in the HII regions. The metallicity-luminosity relation for nearby (D oxygen abundances has a mean correlation of 12 + log(O/H) = 5.67 - 0.151 M_B with a dispersion in oxygen about the relationship of 0.21. These observations confirm that gas-rich low luminosity galaxies have extremely low elemental abundances in the ionized gas-phase of their interstellar media. Although Leo A has one of the lowest metal abundances of known nearby galaxies, detection of tracers of an older stellar population indicate that it is not a newly formed galaxy as has been proposed for some other similarly low metallicity star forming galaxies.

  11. The photospheric solar oxygen project: II. Non-concordance of the oxygen abundance derived from two forbidden lines

    E-Print Network [OSTI]

    Caffau, Elisabetta; Malherbe, Jean-M; Bonifacio, Piercarlo; Steffen, Matthias; Monaco, Lorenzo

    2013-01-01T23:59:59.000Z

    In the Sun, the two forbidden [OI] lines at 630 and 636 nm were previously found to provide discrepant oxygen abundances. aims: We investigate whether this discrepancy is peculiar to the Sun or whether it is also observed in other stars. method: We make use of high-resolution, high signal-to-noise ratio spectra of four dwarf to turn-off stars, five giant stars, and one sub-giant star observed with THEMIS, HARPS, and UVES to investigate the coherence of the two lines. results: The two lines provide oxygen abundances that are consistent, within observational errors, in all the giant stars examined by us. On the other hand, for the two dwarf stars for which a measurement was possible, for Procyon, and for the sub-giant star Capella, the 636 nm line provides systematically higher oxygen abundances, as already seen for the Sun. conclusions: The only two possible reasons for the discrepancy are a serious error in the oscillator strength of the NiI line blending the 630 nm line or the presence of an unknown blend in...

  12. National Environmental Policy Act (NEPA) Categorically Excluded...

    Broader source: Energy.gov (indexed) [DOE]

    on Roads Used to Access Groundwater Monitoring Wells South of the Tuba City, Arizona, Uranium Mill Tailing Remedial Action (UMTRA) Title I Ste 05282013 B1.3 LM 01-13 Current...

  13. Guidelines Establishing Criteria for Excluding Buildings from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from the Energy Performance Requirements of Section 543 of the National Energy Conservation Policy Act as Amended by the Energy Policy Act of 2005 Guidelines Establishing...

  14. Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

    DOE Patents [OSTI]

    Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

    2014-01-07T23:59:59.000Z

    A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

  15. The role of oxygen in the uptake of deuterium in lithiated graphite

    SciTech Connect (OSTI)

    C.N. Taylor; J. Dadras; K.E. Luitjohan; J.P. Allain; P.S. Krstic; C.H. Skinner

    2013-12-01T23:59:59.000Z

    We investigate the mechanism of deuterium retention by lithiated graphite and its relationship to the oxygen concentration through surface sensitive experiments and atomistic simulations. Deposition of lithium on graphite yielded 5%–8% oxygen surface concentration and when subsequently irradiated with D ions at energies between 500 and 1000?eV/amu and fluences over 1016?cm-2 the oxygen concentration rose to between 25% and 40%. These enhanced oxygen levels were reached in a few seconds compared to about 300?h when the lithiated graphite was allowed to adsorb oxygen from the ambient environment under equilibrium conditions. Irradiating graphite without lithium deposition, however, resulted in complete removal of oxygen to levels below the detection limit of XPS (e.g., <1%). These findings confirm the predictions of atomistic simulations, which had concluded that oxygen was the primary component for the enhanced hydrogen retention chemistry on the lithiated graphite surface.

  16. Oxygen vacancy ordering within anion-deficient Ceria

    SciTech Connect (OSTI)

    Hull, S., E-mail: stephen.hull@stfc.ac.u [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Norberg, S.T.; Ahmed, I. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Eriksson, S.G. [Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Marrocchelli, D. [School of Chemistry, Edinburgh University, The King's Building, West Mains Road, Edinburgh EH9 3JJ (United Kingdom); Madden, P.A. [School of Chemistry, Edinburgh University, The King's Building, West Mains Road, Edinburgh EH9 3JJ (United Kingdom); Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

    2009-10-15T23:59:59.000Z

    The structural properties of anion deficient ceria, CeO{sub 2-{delta}}, have been studied as a function of oxygen partial pressure, p(O{sub 2}), over the range 0>=log{sub 10p}(O{sub 2})>=-18.9 at 1273(2) K using the neutron powder diffraction technique. Rietveld refinement of the diffraction data collected on decreasing p(O{sub 2}) showed increases in the cubic lattice parameter, a, the oxygen nonstoichiometry, delta, and the isotropic thermal vibration parameters, u{sub Ce} and u{sub O}, starting at log{sub 10p}(O{sub 2}){approx}-11. The increases are continuous, but show a distinct kink at log{sub 10p}(O{sub 2}){approx}-14.5. Analysis of the total scattering (Bragg plus diffuse components) using reverse Monte Carlo (RMC) modelling indicates that the O{sup 2-} vacancies preferentially align as pairs in the <111> cubic directions as the degree of nonstoichiometry increases. This behaviour is discussed with reference to the chemical crystallography of the CeO{sub 2}-Ce{sub 2}O{sub 3} system at ambient temperature and, in particular, to the nature of the long-range ordering of O{sup 2-} vacancies within the crystal structure of Ce{sub 7}O{sub 12}. - Graphical abstract: Partial radial distribution function for oxygen vacancies within CeO{sub 1.710} at 1273 K (solid line) showing the increased tendency for local ordering in <111> directions compared to a random distribution (dashed line).

  17. Thermochemical generation of hydrogen and oxygen from water

    DOE Patents [OSTI]

    Robinson, Paul R. (Knoxville, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1981-01-01T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  18. Thermochemical generation of hydrogen and oxygen from water

    DOE Patents [OSTI]

    Robinson, Paul R. (Knoxville, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1982-01-01T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  19. Method for providing oxygen ion vacancies in lanthanide oxides

    DOE Patents [OSTI]

    Kay, D. Alan R. (4305 Lakeshore Rd., Burlington, CA); Wilson, William G. (820 Harden Dr., Pittsburgh, PA 15229)

    1989-12-05T23:59:59.000Z

    A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

  20. Oxygen-stabilized zirconium-vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1981-10-06T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula Zr/sub x/OV/sub y/ where x = 0.7 to 2.0 and y = 0.18 to 0.33 is described. The compound is capable of reversibly sorbing hydrogen at temperatures from - 196/sup 0/C to 450/sup 0/C at pressures down to 10/sup -6/ Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO/sub 2/.

  1. Organic matter of anoxic and oxygenated marine waters

    E-Print Network [OSTI]

    Gershey, Robert Michael

    1974-01-01T23:59:59.000Z

    that a large percentage of the organic matter found in sea water consists of humic-like material (Skopentsev 1972) formed by condensation of simpler compounds such as carbohydrates and amino acids by plankton life processes (Kalle 1962). This newly... Major Subject: Chemical Oceanography ORGANIC MATTER OF ANOXIC AND OXYGENATED MARINE WATERS A Thesis by ROBERT MICHAEL GERSHEY Approved as to style and content by: Chairman of o tt ) r / ~-' t:u 'fl ~~&"f / 8 ~, g t, i~~ (Head of Department...

  2. Oxygen Transport Studies in Nanocrystalline Ceria Films. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002Optics GroupPlanning Workshopthe MagnetiteOxygen

  3. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratorySpeedingOptimizing I/O performanceOtherOutreachPatents - OwenOxygen

  4. Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 catalyst Formation, stability and CO

    E-Print Network [OSTI]

    Pfeifer, Holger

    1 Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 are the activation of molecular oxygen, the active site for this reaction step, and the nature of the catalytically active oxygen species present under working conditions.[3;9-15] Stiehl et al. had shown that molecularly

  5. IN-SITU STUDY OF OXYGEN ISOTOPES IN GRAPHITE FROM L3 CHONDRITES: INDICATIONS FOR OXYGEN ISOTOPIC HETEROGENEITY. S. Mostefaoui1, FJ. Stadermann2, and A. El Goresy1. !Max-

    E-Print Network [OSTI]

    IN-SITU STUDY OF OXYGEN ISOTOPES IN GRAPHITE FROM L3 CHONDRITES: INDICATIONS FOR OXYGEN ISOTOPIC in-situ measurements of oxygen isotopes in graphite from the Khohar and Mez6-Madaras (L3) chondrites. Oxygen isotopic measurements were conducted with the Washington University ion microprobe (a modified

  6. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31T23:59:59.000Z

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

  7. Oxygen-Diffused Titanium as a Candidate Brake Rotor Material

    SciTech Connect (OSTI)

    Qu, Jun [ORNL; Blau, Peter Julian [ORNL; Jolly, Brian C [ORNL

    2009-01-01T23:59:59.000Z

    Titanium alloys are one of several candidate materials for the next generation of truck disk brake rotors. Despite their advantages of lightweight relative to cast iron and good strength and corrosion resistance, titanium alloys are unlikely to be satisfactory brake rotor materials unless their friction and wear behavior can be significantly improved. In this study, a surface engineering process oxygen diffusion was applied to titanium rotors and has shown very encouraging results. The oxygen diffused Ti-6Al-4V (OD-Ti) was tested on a sub-scale brake tester against a flat block of commercial brake lining material and benchmarked against several other Ti-based materials, including untreated Ti-6Al-4V, ceramic particle-reinforced Ti composites (MMCs), and a thermal-spray-coated Ti alloy. With respect to friction, the OD-Ti outperformed all other candidate materials under the imposed test conditions with the friction coefficient remaining within a desirable range of 0.35-0.50, even under the harshest conditions when the disk surface temperature reached nearly 600 ?C. In addition, the OD-Ti showed significantly improved wear-resistance over the non-treated one and was even better than the Ti-based composite materials.

  8. Donor levels of the divacancy-oxygen defect in silicon

    SciTech Connect (OSTI)

    Markevich, V. P., E-mail: V.Markevich@manchester.ac.uk; Peaker, A. R.; Hamilton, B. [Photon Science Institute, the University of Manchester, Manchester M13 9PL (United Kingdom); Lastovskii, S. B.; Murin, L. I. [Scientific-Practical Materials Research Center of NAS of Belarus, Minsk 220072 (Belarus)

    2014-01-07T23:59:59.000Z

    The elimination of divacancies (V{sub 2}) upon isochronal and isothermal annealing has been studied in oxygen-rich p-type silicon by means of deep level transient spectroscopy (DLTS) and high resolution Laplace DLTS. Divacancies were introduced into the crystals by irradiation with 4 or 6?MeV electrons. The temperature range of the divacancy disappearance was found to be 225-300?°C upon 30 min isochronal annealing in the samples studied. A clear anti-correlation between the disappearance of V{sub 2} and the appearance of two hole traps with activation energies for hole emission of 0.23?eV and 0.08?eV was observed. It is argued that these traps are related to the first and second donor levels of the divacancy-oxygen (V{sub 2}O) complex, respectively. Significant electric field enhancement of the hole emission from the second donor level of the V{sub 2}O center occurred in the diodes studied. It is shown that in the range of electric field from 4?×?10{sup 3} to 1.2?×?10{sup 4}?V/cm the emission enhancement is associated with phonon-assisted tunnelling.

  9. A new approach to oxygen enriched high temperature blast generation

    SciTech Connect (OSTI)

    Queille, P.H.; Macauley, D.

    1996-12-31T23:59:59.000Z

    When increasing fuel injection in a blast furnace in order to reduce coke consumption and/or to increase production, the blast furnace operator tries to keep similar raceway conditions, for instance, an equivalent flame temperature. To compensate for the cooling effect due to the higher injection rate, two solutions can be selected or combined: to raise the temperature of the blast and/or to increase the level of oxygen in the blast. Whatever the choice, the Blast Furnace manager will certainly try to reduce the resulting investment and operating costs to a minimum. Air Liquide and Kvaerner Davy are trying to provide a new way to address these needs by offering a new technology for blast heating. A higher blast temperature will not only allow a higher fuel injection at tuyere level, a lower coke consumption, but also a lower oxygen consumption. Air Liquide and Kvaerner Davy are now able to offer a new heat regenerator with major advantages over conventional stoves. This new device can be used as a permanent substitute for a stove, or as a temporary one during repair, or stove improvement. It can also be added to an existing set of stoves to increase the average blast temperature.

  10. High-resolution NMR process analyzer for oxygenates in gasoline

    SciTech Connect (OSTI)

    Skloss, T.W.; Kim, A.J.; Haw, J.F. (Texas A M Univ., College Station, TX (United States))

    1994-02-15T23:59:59.000Z

    We report a high-resolution 42-MHz[sup 1]HFT-NMR instrument that is suitable for use as a process analyzer and demonstrate its use in the determination of methyl tert-butyl ether (MTBE) in a flowing stream of gasoline. This spectrometer is based on a 55-kg permanent magnet with essentially no fringe field. A spectral resolution of 3 Hz was typically obtained for spinning samples, and this performance was only slightly degraded with flowing samples. We report a procedure for magnet drift compensation using a software procedure rather than a field-frequency lock channel. This procedure allowed signal averaging without loss of resolution. Regulatory changes to be implemented in the near future have created a need for the development of methods for the determination of MTBE and other oxygenates in reformulated gasolines. Existing methods employing gas chromatography are not fast enough for process control of a gasoline blender and suffer from other limitations. This study demonstrates that process analysis NMR is well-suited to the determination of MTBE in a simulated gasoline blender. The detection limit of 0.5 vol % MTBE was obtained with a measurement time of 1 min. The absolute standard deviation of independent determinations was 0.17% when the MTBE concentration was 10%, a nominal value. Preliminary results also suggest that the method may be applicable to gasolines containing mixtures of oxygenate additives as well as the measurement of aromatic and olefinic hydrogens. 33 refs., 9 figs.

  11. Radiation chemistry of alternative fuel oxygenates -- Substituted ethers

    SciTech Connect (OSTI)

    Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.

    1999-11-15T23:59:59.000Z

    The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

  12. Hydrogen and Oxygen Gas Monitoring System Design and Operation

    SciTech Connect (OSTI)

    Lee C. Cadwallader; Kevin G. DeWall; J. Stephen Herring

    2007-06-01T23:59:59.000Z

    This paper describes pertinent design practices of selecting types of monitors, monitor unit placement, setpoint selection, and maintenance considerations for gas monitors. While hydrogen gas monitors and enriched oxygen atmosphere monitors as they would be needed for hydrogen production experiments are the primary focus of this paper, monitors for carbon monoxide and carbon dioxide are also discussed. The experiences of designing, installing, and calibrating gas monitors for a laboratory where experiments in support of the DOE Nuclear Hydrogen Initiative (NHI) are described along with codes, standards, and regulations for these monitors. Information from the literature about best operating practices is also presented. The NHI program has two types of activities. The first, near-term activity is laboratory and pilot-plant experimentation with different processes in the kilogram per day scale to select the most promising types of processes for future applications of hydrogen production. Prudent design calls for indoor gas monitors to sense any hydrogen leaks within these laboratory rooms. The second, longer-term activity is the prototype, or large-scale plants to produce tons of hydrogen per day. These large, outdoor production plants will require area (or “fencepost”) monitoring of hydrogen gas leaks. Some processes will have oxygen production with hydrogen production, and any oxygen releases are also safety concerns since oxygen gas is the strongest oxidizer. Monitoring of these gases is important for personnel safety of both indoor and outdoor experiments. There is some guidance available about proper placement of monitors. The fixed point, stationary monitor can only function if the intruding gas contacts the monitor. Therefore, monitor placement is vital to proper monitoring of the room or area. Factors in sensor location selection include: indoor or outdoor site, the location and nature of potential vapor/gas sources, chemical and physical data of the gases or vapors, liquids with volatility need sensors near the potential sources of release, nature and concentration of gas releases, natural and mechanical ventilation, detector installation locations not vulnerable to mechanical or water damage from normal operations, and locations that lend themselves to convenient maintenance and calibration. The guidance also states that sensors should be located in all areas where hazardous accumulations of gas may occur. Such areas might not be close to release points but might be areas with restricted air movement. Heavier than air gases are likely to accumulate in pits, trenches, drains, and other low areas. Lighter than air gases are more likely to accumulate in overhead spaces, above drop ceilings, etc. In general, sensors should be located close to any potential sources of major release of gas. The paper gives data on monitor sensitivity and expected lifetimes to support the monitor selection process. Proper selection of indoor and outdoor locations for monitors is described, accounting for the vapor densities of hydrogen and oxygen. The latest information on monitor alarm setpoint selection is presented. Typically, monitors require recalibration at least every six months, or more frequently for inhospitable locations, so ready access to the monitors is an important issue to consider in monitor siting. Gas monitors, depending on their type, can be susceptible to blockages of the detector element (i.e., dus

  13. Declining Oxygen in the Northeast Pacific* STEPHEN D. PIERCE, JOHN A. BARTH, R. KIPP SHEARMAN, AND ANATOLI Y. EROFEEV

    E-Print Network [OSTI]

    Pierce, Stephen

    Declining Oxygen in the Northeast Pacific* STEPHEN D. PIERCE, JOHN A. BARTH, R. KIPP SHEARMAN a decrease in oceanic dissolved oxygen and a thickening of the oxygen minimum zone, associated with global warming. Comprehensive observational analyses of oxygen decline are chal- lenging, given generally sparse

  14. Influence of oxygen on the interfacial stability of Cu on Co,,0001... thin films Hongmei Wen,1 Matthew Neurock,1,

    E-Print Network [OSTI]

    Wadley, Haydn

    Influence of oxygen on the interfacial stability of Cu on Co,,0001... thin films Hongmei Wen,1 of oxygen, which can impact the quality of film and its properties. Previously we found that oxygen to examine the effects of surface atomic oxygen on the stability of the Cu 111 /Co 0001 interface

  15. Origin of deep subgap states in amorphous indium gallium zinc oxide: Chemically disordered coordination of oxygen

    SciTech Connect (OSTI)

    Sallis, S.; Williams, D. S. [Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States); Butler, K. T.; Walsh, A. [Center for Sustainable Technologies and Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY (United Kingdom); Quackenbush, N. F. [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Junda, M.; Podraza, N. J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States); Fischer, D. A.; Woicik, J. C. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); White, B. E.; Piper, L. F. J., E-mail: lpiper@binghamton.edu [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States)

    2014-06-09T23:59:59.000Z

    The origin of the deep subgap states in amorphous indium gallium zinc oxide (a-IGZO), whether intrinsic to the amorphous structure or not, has serious implications for the development of p-type transparent amorphous oxide semiconductors. We report that the deep subgap feature in a-IGZO originates from local variations in the oxygen coordination and not from oxygen vacancies. This is shown by the positive correlation between oxygen composition and subgap intensity as observed with X-ray photoelectron spectroscopy. We also demonstrate that the subgap feature is not intrinsic to the amorphous phase because the deep subgap feature can be removed by low-temperature annealing in a reducing environment. Atomistic calculations of a-IGZO reveal that the subgap state originates from certain oxygen environments associated with the disorder. Specifically, the subgap states originate from oxygen environments with a lower coordination number and/or a larger metal-oxygen separation.

  16. Investigation of oxygen point defects in cubic ZrO2 by density functional theory

    SciTech Connect (OSTI)

    Liu, Bin [ORNL] [ORNL; Xiao, Haiyan [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Zhang, Yanwen [ORNL] [ORNL; Aidhy, Dilpuneet S [ORNL] [ORNL; Weber, William J [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    The energetics of formation and migration of the oxygen vacancy and interstitial in cubic ZrO2 are investigated by density functional theory calculations. In an O-rich environment, the negatively charged oxygen interstitial is the most dominant defect whereas, the positively charged oxygen vacancy is the most dominant defect under O-poor conditions. Oxygen interstitial migration occurs by the interstitialcy and the direct interstitial mechanisms, with calculated migration energy barriers of 2.94 eV and 2.15 eV, respectively. For the oxygen vacancy, diffusion is preferred along the <100> direction, and the calculated energy barriers are 0.26 eV for , 0.27 eV for and 0.54 eV for . These results indicate that oxygen diffusivity is higher through the vacancy-migration mechanism.

  17. Calculation of the degree of utilization of oxygen in the oxidation of bitumen under industrial conditions

    SciTech Connect (OSTI)

    Marakaeva, L.A.; Bereznikov, A.V.; Rozental', D.A.

    1988-09-10T23:59:59.000Z

    The degree of utilization of air oxygen plays an important role in bitumen production. This parameter depends firstly on the capacity of the compressor that could be reduced at a more complete utilization of oxygen; secondly, a high oxygen content of the waste gases can lead to explosions and coke formation. Besides this, the waste gases contain toxic substances at concentrations which are not permitted for discharge into the atmosphere. Thus, the possibility of calculating the oxygen content of waste gases on industrial installation was investigated. The authors have derived an equation which describes the oxygen content of the waste gases as a function of the temperature and depth of oxidation, the oxygen flow rate, and the height of the liquid phase, for a laboratory unit; it was taken as the basis for the transition to the industrial scale.

  18. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOE Patents [OSTI]

    Erickson, D.C.

    1985-06-04T23:59:59.000Z

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power. 1 fig.

  19. In situ global method for measurement of oxygen demand and mass transfer

    SciTech Connect (OSTI)

    Klasson, K.T. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.; Lundbaeck, K.M.O.; Clausen, E.C.; Gaddy, J.L. [Univ. of Arkansas, Fayetteville, AR (United States). Dept. of Chemical Engineering

    1997-05-01T23:59:59.000Z

    Two aerobic microorganisms, Saccharomycopsis lipolytica and Brevibacterium lactofermentum, have been used in a study of mass transfer and oxygen uptake from a global perspective using a closed gas system. Oxygen concentrations in the gas and liquid were followed using oxygen electrodes, and the results allowed for easy calculation of in situ oxygen transport. The cell yields on oxygen for S. lipolytica and B. lactofermentum were 1.01 and 1.53 g/g respectively. The mass transfer coefficient was estimated as 10 h{sup {minus}1} at 500 rpm for both fermentations. The advantages with this method are noticeable since the use of model systems may be avoided, and the in situ measurements of oxygen demand assure reliable data for scale-up.

  20. Flow Metering and Oxygen Trim Control Reduce Dairy Steam Plant Fuel Costs

    E-Print Network [OSTI]

    Foster, E. L.; Nelson, R. L.

    to determine when significant carbon monoxide appeared. This measurement was made by a portable CO analyzer. FIGURE 7 VERILINK LINKAGE INSTALLED ON LARGE B & W BOILER Figure 8 illustrates the data obtained at 60% boiler load. When excess oxygen... is decreased below 1.S percent, significant amounts of carbon monoxide appear. At I percent excess oxygen in the flue gas approximately 300 parts per million CO were present. For this load demand the service engineer selected 2 percent excess oxygen...

  1. Blast furnace injection of massive quantities of coal with enriched air or pure oxygen

    SciTech Connect (OSTI)

    Ponghis, N.; Dufresne, P.; Vidal, R.; Poos, A. (Center de Recherches Metallurgiques, Liege (Belgium))

    1993-01-01T23:59:59.000Z

    An extensive study of the phenomena associated with the blast furnace injection of massive quantities of coal is described. Trials with conventional lances or oxy-coal injectors and hot blast at different oxygen contents - up to 40% - or with cold pure oxygen were realized at coal to oxygen ratios corresponding to a range of 150 to 440 kg. Pilot scale rigs, empty or filled with coke, as well as industrial blast furnaces were utilized.

  2. Oxygen impurity and microalloying effect in a Zr-based bulk metallic glass alloy

    E-Print Network [OSTI]

    Pennycook, Steve

    Oxygen impurity and microalloying effect in a Zr-based bulk metallic glass alloy C.T. Liu*, M composition Zr­10 at.%Al­5% Ti­17.9% Cu­14.6% Ni (BAM-11) was used to study the effects of oxygen impurities and microalloying on the microstructure and mechanical properties. Oxygen impurity at a level of 3000 appm

  3. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    SciTech Connect (OSTI)

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27T23:59:59.000Z

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  4. Oxygen-resistant hydrogenases and methods for designing and making same

    DOE Patents [OSTI]

    King, Paul; Ghirardi, Maria Lucia; Seibert, Michael

    2014-03-04T23:59:59.000Z

    The invention provides oxygen-resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H.sub.2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

  5. Towards forming-free resistive switching in oxygen engineered HfO{sub 2?x}

    SciTech Connect (OSTI)

    Sharath, S. U., E-mail: sharath@oxide.tu-darmstadt.de; Kurian, J.; Hildebrandt, E.; Alff, L. [Institute of Materials Science, Technische Universität Darmstadt, Alarich-Weiss-Strasse 2, 64287 Darmstadt (Germany); Bertaud, T.; Walczyk, C.; Calka, P.; Zaumseil, P.; Sowinska, M.; Walczyk, D. [IHP, Im Technologiepark 25, 15236 Frankfurt Oder (Germany); Gloskovskii, A. [Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg (Germany); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt Oder (Germany); Brandenburgische Technische Universität, Konrad-Zuse-Strasse 1, 03046 Cottbus (Germany)

    2014-02-10T23:59:59.000Z

    We have investigated the resistive switching behavior in stoichiometric HfO{sub 2} and oxygen-deficient HfO{sub 2?x} thin films grown on TiN electrodes using reactive molecular beam epitaxy. Oxygen defect states were controlled by the flow of oxygen radicals during thin film growth. Hard X-ray photoelectron spectroscopy confirmed the presence of sub-stoichiometric hafnium oxide and defect states near the Fermi level. The oxygen deficient HfO{sub 2?x} thin films show bipolar switching with an electroforming occurring at low voltages and low operating currents, paving the way for almost forming-free devices for low-power applications.

  6. Impact of ethanol and butanol as oxygenates on SIDI engine efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Thomas Wallner, Neeraj Shidore, Andrew Ickes Argonne National Laboratory 16...

  7. Effect of different intravenous iron preparations on lymphocyte intracellular reactive oxygen species generation and subpopulation survival.

    E-Print Network [OSTI]

    Gupta, Ajay; Zhuo, Jiaying; Zha, Junli; Reddy, Srinivasa; Olp, Jonathan; Pai, Amy

    2010-01-01T23:59:59.000Z

    IV iron compounds induced greater intracellular ROS generation,IV iron preparations on intracellular reactive oxygen species generationIV iron preparations on intracellular immune cell ROS generation

  8. JOINING ADVANCED MATERIALS BY PLASTIC FLOW PROVIDES SOLUTION FOR OXYGEN SENSOR APPLICATIONS

    E-Print Network [OSTI]

    Kemner, Ken

    JOINING ADVANCED MATERIALS BY PLASTIC FLOW PROVIDES SOLUTION FOR OXYGEN SENSOR APPLICATIONS's unique plastic deformation process. · Abilitytodeploymultipleoxygen sensors (due to their lower cost

  9. Task Technical Plan for Studies of Oxygen Consumption in the Catalyzed Hydrolysis of Tetraphenylborate Ion

    SciTech Connect (OSTI)

    Fink, S.D. [Westinghouse Savannah River Company, AIKEN, SC (United States)

    1996-12-20T23:59:59.000Z

    This document presents the plan for studies of how dissolved oxygen affects the catalytic decomposition of the tetraphenylborate ion in alkaline aqueous solution.

  10. Oxygen-resistant hydrogenases and methods for designing and making same

    DOE Patents [OSTI]

    King, Paul (Golden, CO); Ghirardi, Maria L (Lakewood, CO); Seibert, Michael (Lakewood, CO)

    2009-03-10T23:59:59.000Z

    The invention provides oxygen- resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

  11. Oxygen-Dependent Morphogenesis of Modern Clumped Photosynthetic Mats and Implications for the Archean Stromatolite Record

    E-Print Network [OSTI]

    Sim, Min Sub

    Some modern filamentous oxygenic photosynthetic bacteria (cyanobacteria) form macroscopic tufts, laminated cones and ridges that are very similar to some Archean and Proterozoic stromatolites. However, it remains unclear ...

  12. E-Print Network 3.0 - arterial blood oxygen Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are blood vessels (thick, muscular tubes) that carry oxygen-rich blood from the heart... to the rest of the body. Blood pressure (BP) has two measurements: top...

  13. E-Print Network 3.0 - atmospheric pressure helium-oxygen Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copyright permission to reproduce figures andor text from this article 12;Remote Atmospheric-Pressure... ) were treated with an atmospheric-pressure oxygen and...

  14. Effect of phenylephrine and ephedrine bolus treatment on cerebral oxygenation in anaesthetized patients.

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    Miller RD, ed. Miller’s Anesthesia, 6th Edn. Philadelphia:with oxytocin during spinal anesthesia for elective cesareanlobe oxygenation following anesthesia-induced hypotension.

  15. E-Print Network 3.0 - active oxygen species Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: active oxygen species Page: << < 1 2 3 4 5 > >> 1 Ecological requirements of damselflies in Dutch...

  16. Silicon-on-glass pore network micromodels with oxygen-sensing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silicon-on-glass pore network micromodels with oxygen-sensing fluorophore films for chemical imaging and defined spatial Silicon-on-glass pore network micromodels with...

  17. E-Print Network 3.0 - active oxygen content Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: active oxygen content Page: << < 1 2 3 4 5 > >> 1 Reactivity and coverage of active surface species...

  18. E-Print Network 3.0 - atomic oxygen erosion Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen erosion Page: << < 1 2 3 4 5 > >> 1 J. N. Brooks (M. Ulrickson) Argonne National...

  19. E-Print Network 3.0 - atmospheric oxygenation recorded Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Summary: is that photosynthesising microbes in the surface ocean caused atmospheric oxygen levels to rise significantly around 2... not viable. Researchers have long speculated...

  20. E-Print Network 3.0 - atomic oxygen radical Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen radical Page: << < 1 2 3 4 5 > >> 1 Considering Open Shell Intermediates sfn Radicals...

  1. Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique

    Broader source: Energy.gov [DOE]

    Video recording of the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, originally presented on March 12, 2013.

  2. Oxygen-stabilized zirconium-vanadium-iron alloy

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1981-06-16T23:59:59.000Z

    An oxygen stabilized intermetallic compound is described which has the formula (Zr/sub 1-x/Ti/sub x/)/sub 2-u/(V/sub 1-y/Fe/sub y/)O/sub z/ where x = 0.0 to 0.9, y = 0.01 to 0.9, z = 0.25 to 0.5 and u = 0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196/sup 0/C to 200/sup 0/C at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  3. Photocatalytic reactions of oxygenates on tropospheric oxide particles

    SciTech Connect (OSTI)

    Idriss, H.; Seebauer, E.G.; Miller, A. [Univ. of Illinois, Urbana, IL (United States)

    1996-10-01T23:59:59.000Z

    Oxygenates such as ethanol and tert-butyl methyl ether (MTBE) are finding increased use as additives to fuels. The relative merits of ethanol and MTBE have become the focus of intense debate with their ultimate fate as fugitive emissions representing one aspect of this controversy. Both species are known to react homogeneously with photogenerated OH radicals. Here we show that both can also photoreact on suspended solid particulates in the atmosphere with rates comparable to those of OH reactions. Heterogeneous reactions of ethanol yield acetaldehyde and those of MTBE give isobutene and formaldehyde (carcinogenic). Experiments by spectroscopic and kinetic techniques show that the active phases in fly ash are Fe and Ti oxides. In addition, the effects of humidity and alkali addition on the activity and selectivity of these reactions are also discussed. This work appears to be the first demonstration that volatile organic compounds can react as fast by a heterogeneous mechanism as by a homogeneous one in the atmosphere.

  4. Calorimetric studies of oxygen adsorption on silver powder and of CO and CO/sub 2/ interactions with preadsorbed oxygen on silver

    SciTech Connect (OSTI)

    Vass, M.I.; Budrugeac, P.

    1980-07-01T23:59:59.000Z

    The initial rapid oxygen adsorption on powdered silver ethylene oxidation catalyst had a heat of adsorption that decreased from 70 to 40 kcal/mole as the adsorbed amount increased from 2 to 20 jmole/sq m. The rapid oxygen adsorption covered about one-fourth of the silver surface. Carbon monoxide adsorbed on the oxygen-covered silver with an initial heat of adsorption of 90 kcal/mole which decreased after 0.6 jmole/sq m CO were adsorbed and was approx. 70 kcal/mole at 2 jmole/sq m CO. Carbon dioxide adsorbed on the oxygen-covered surface with 38 kcal/mole heat of adsorption that was independent of coverage. The adsorption study provided evidence for the formation of adsorbed carbonate (CO/sub 3/) surface complexes.

  5. Oxygen at Nanomolar Levels Reversibly Suppresses Process Rates and Gene Expression in Anammox and Denitrification in the Oxygen Minimum Zone off Northern Chile

    E-Print Network [OSTI]

    Dalsgaard, Tage

    A major percentage (20 to 40%) of global marine fixed-nitrogen loss occurs in oxygen minimum zones (OMZs). Concentrations of O[subscript 2] and the sensitivity of the anaerobic N[subscript 2]-producing processes of anammox ...

  6. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory

    SciTech Connect (OSTI)

    Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R.; Boland, Kevin S.; Bradley, Joseph A.; Daly, Scott R.; Kozimor, Stosh A.; Lukens, Wayne W.; Martin, Richard L.; Nordlund, Dennis; Seidler, Gerald T.; Shuh, David K.; Sokaras, Dimosthenis; Tyliszczak, Tolek; Wagner, Gregory L.; Weng, Tsu-Chein; Yang, Ping

    2014-01-01T23:59:59.000Z

    Advancing theories of how metal oxygen bonding influences metal oxo properties can expose new avenues for innovation in materials science, catalysis, and biochemistry. Historically, spectroscopic analyses of the transition metal peroxyanions, MO4x-, have formed the basis for new M O bonding theories. Herein, relative changes in M O orbital mixing in MO42- (M = Cr, Mo, W) and MO41- (M = Mn, Tc, Re) are evaluated for the first time by non-resonant inelastic X-ray scattering, X-ray absorption spectroscopy using fluorescence and transmission (via a scanning transmission X-ray microscope), and linear-response density functional theory. The results suggest that moving from Group 6 to Group 7 or down the triads increases M O e () mixing. Meanwhile, t2 mixing ( + ) remains relatively constant within the same Group. These unexpected changes in frontier orbital energy and composition are evaluated in terms of periodic trends in d orbital energy and radial extension.

  7. Holocene Paleohydrology and Paleoclimate at Treeline, North-Central Russia, Inferred from Oxygen Isotope

    E-Print Network [OSTI]

    Edwards, Thomas W.D.

    Holocene Paleohydrology and Paleoclimate at Treeline, North-Central Russia, Inferred from Oxygen Institute for Geography, Russian Academy of Sciences, Staromonetny Pereulok 29, Moscow 109017, Russia, 1998 Lake-water oxygen-isotope histories for three lakes in northern Russia, derived from the cellulose

  8. Heart Rate and Oxygen Consumption of Northern Elephant Seals during Diving in the Laboratory

    E-Print Network [OSTI]

    Webb, Paul M.

    116 Heart Rate and Oxygen Consumption of Northern Elephant Seals during Diving in the Laboratory Paul M. Webb1 heart rate over the entire dive cycle increased with increasing oxygen consumption in all, which casts some doubt on the usefulness of heart rate as an indicator of metabolicBurney J. Le Boeuf1 1

  9. Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production

    DOE Patents [OSTI]

    Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

    1988-01-01T23:59:59.000Z

    A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

  10. Dissociation of water on oxygen-covered Rh^111 A. Shavorskiy,1

    E-Print Network [OSTI]

    Schnadt, Joachim

    to the somewhat unusual situation that these water layers are actually hydrophobic due to the lack of hydrogenDissociation of water on oxygen-covered Rh^111 A. Shavorskiy,1 T. Eralp,1 E. Ataman,2 C. Isvoranu,2 November 2009; published online 4 December 2009 The adsorption of water and coadsorption with oxygen on Rh

  11. Oxygen affinity and amino acid sequence of myoglobins from endothermic and ectothermic fish

    E-Print Network [OSTI]

    Block, Barbara A.

    that Mb oxygen affinity has evolved such that it is conserved when adjusted for body temperature amongOxygen affinity and amino acid sequence of myoglobins from endothermic and ectothermic fish DAVID J and Conservation Center and Hopkins Marine Station, Stanford University, Pacific Grove, California 93950; 2 Duke

  12. Studies of the Di-iron(VI) Intermediate in Ferrate-Dependent Oxygen Evolution from Water

    E-Print Network [OSTI]

    Roth, Justine P.

    Information ABSTRACT: Molecular oxygen is produced from water via the following reaction of potassium ferrateStudies of the Di-iron(VI) Intermediate in Ferrate-Dependent Oxygen Evolution from Water Rupam consumption of natural abundance water. The derived 18 O KIEs provide insights concerning the identity

  13. Coastal Upwelling Supplies Oxygen-Depleted Water to the Columbia River Estuary

    E-Print Network [OSTI]

    extent and duration of exposure to low DO water. Strong upwelling during neap tides produced the largestCoastal Upwelling Supplies Oxygen-Depleted Water to the Columbia River Estuary G. Curtis Roegner1 States of America Abstract Low dissolved oxygen (DO) is a common feature of many estuarine and shallow-water

  14. Evaluation of novel ceria-supported materials as oxygen carriers for chemical-

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    that was somehow expected according to previous reports on this material. Keywords: carbon dioxide (CO2), chemical-loopingEvaluation of novel ceria-supported materials as oxygen carriers for chemical- looping combustion-supported materials as oxygen carriers for chemical-looping combustion ALI HEDAYATI Department of Energy

  15. Enhanced activity and stability of Pt catalysts on functionalized graphene sheets for electrocatalytic oxygen reduction

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    for electrocatalytic oxygen reduction Rong Kou a , Yuyan Shao a , Donghai Wang a , Mark H. Engelhard a , Ja Hun Kwak a higher electrochemical surface area and oxygen reduction activity with improved stability as compared with the commercial catalyst. Transmission electron microscopy, X-ray photoelectron spectroscopy, and electrochemical

  16. Diffuse Optical Tomography of Cerebral Blood Flow, Oxygenation, and Metabolism in Rat During Focal Ischemia

    E-Print Network [OSTI]

    Yodh, Arjun G.

    of oxygen consumption (CMRO2). Temporary (60-minute) MCAO was performed on five rats. Ischemic changes--Cerebral metabolic rate of oxygen consumption. Diffuse optical tomography (DOT) of the brain is an attractive new complementary to those of magnetic resonance imaging (MRI) and positron emission tomog- raphy (PET), and holds

  17. Stability and Migration of Charged Oxygen Interstitials in ThO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen interstitial mobility in ThO2 than in CeO2. Citation: Xiao HY, Y Zhang, and WJ Weber.2013."Stability and Migration of Charged Oxygen Interstitials in ThO2 and CeO2."Acta...

  18. The Paleoproterozoic snowball Earth: A climate disaster triggered by the evolution of oxygenic photosynthesis

    E-Print Network [OSTI]

    photosynthesis Robert E. Kopp*, Joseph L. Kirschvink, Isaac A. Hilburn, and Cody Z. Nash Division of Geological biomarker, trace element, and isotopic evidence have been used to claim that oxygenic photosynthesis evolved phases. First, oxygenic photosynthesis evolved and brought into the world locally oxic environments

  19. Home Monitoring of Oxygen Saturation and Symptoms for Sickle Cell Disease

    E-Print Network [OSTI]

    Oakley, Jeremy

    Home Monitoring of Oxygen Saturation and Symptoms for Sickle Cell Disease Introduction and Aims There is evidence that the vaso-occlusive crises and other complications associated with sickle cell disease (SCD oxygen levels and the onset of sickle cell crises. A secondary objective of the study is to investigate

  20. Ice-free conditions in Sweden during Marine Oxygen Isotope Stage 3? BARBARA WOHLFARTH

    E-Print Network [OSTI]

    Wohlfarth, Barbara

    Ice-free conditions in Sweden during Marine Oxygen Isotope Stage 3? BARBARA WOHLFARTH BOREAS Wohlfarth, B. 2010 (April): Ice-free conditions in Sweden during Marine Oxygen Isotope Stage 3? Boreas, Vol dates for Sweden older than the Last Glacial Maximum ice advance were eval- uated. Acceptable 14 C dates