National Library of Energy BETA

Sample records for xylene btx asphalt

  1. BTX Holdings Inc | Open Energy Information

    Open Energy Info (EERE)

    Product: BTX Holdings acquires, develops, and deploys technologies to process plant derived biomass waste, extract the usable fractions, and utilise or sell the extractions in...

  2. Cool Asphalt Shingles | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cool Asphalt Shingles Cool Asphalt Shingles Berkeley Lab Heat Island Group research assistant Sharon Chen prepares a prototype of high-performance cool shingle roofing. Credit: Heat Island Group, Lawrence Berkeley National Laboratory Berkeley Lab Heat Island Group research assistant Sharon Chen prepares a prototype of high-performance cool shingle roofing. Credit: Heat Island Group, Lawrence Berkeley National Laboratory Lead Performer: Lawrence Berkeley National Laboratory - Berkeley, CA

  3. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organicsmore » present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.« less

  4. Rapid determination of actinides in asphalt samples

    SciTech Connect (OSTI)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organics present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.

  5. New Cool Roof Coatings and Affordable Cool Color Asphalt

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Cool Roof Coatings and Affordable Cool Color Asphalt Shingles Meng-Dawn Cheng Oak ... roof coatings and asphalt shingles to reduce energy consumption of new and existing roofs. ...

  6. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Production Capacity of Operable Petroleum Refineries Definitions Key Terms Definition Alkylate The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Aromatics Hydrocarbons characterized by unsaturated ring structures of carbon atoms. Commercial petroleum aromatics are benzene, toluene, and xylene (BTX). Asphalt A dark-brown-to-black cement-like material containing bitumens as the

  7. Surface roughness effects on the solar reflectance of cool asphalt...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Surface roughness effects on the solar reflectance of cool asphalt shingles Citation Details In-Document Search Title: Surface roughness effects on the solar ...

  8. Methods for the synthesis and polymerization of .alpha.,.alpha.'-dihalo-p-xylenes

    DOE Patents [OSTI]

    Ferraris, John P.; Neef, Charles J.

    2002-07-30

    The present invention describes an improved method for the polymerization of .alpha.,.alpha.-dihalo-p-xylene's such as the .alpha.,.alpha.'-dihalo-2-methoxy-5-(2-ethylhexyloxy)-xylene's. The procedure for synthesis is based on the specific order of addition of reagents and the use of an anionic initiator that allows control of the molecular weight of the polymer. The molecular weight control allows processability of the polymer which is important for its utility in applications including in light-emitting-diodes, field effect transistors and photovoltaic devices.

  9. Asphalt Roofing Shingles Into Energy Project Summary Report

    SciTech Connect (OSTI)

    Jameson, Rex, PE

    2008-04-28

    Based on a widely cited September, 1999 report by the Vermont Agency of Natural Resources, nearly 11 million tons of asphalt roofing shingle wastes are produced in the United States each year. Recent data suggests that the total is made up of about 9.4 million tons from roofing tear-offs and about 1.6 million tons from manufacturing scrap. Developing beneficial uses for these materials would conserve natural resources, promote protection of the environment and strengthen the economy. This project explored the feasibility of using chipped asphalt shingle materials in cement manufacturing kilns and circulating fluidized bed (CFB) boilers. A method of enhancing the value of chipped shingle materials for use as fuel by removing certain fractions for use as substitute raw materials for the manufacture of new shingles was also explored. Procedures were developed to prevent asbestos containing materials from being processed at the chipping facilities, and the frequency of the occurrence of asbestos in residential roofing tear-off materials was evaluated. The economic feasibility of each potential use was evaluated based on experience gained during the project and on a review of the well established use of shingle materials in hot mix asphalt. This project demonstrated that chipped asphalt shingle materials can be suitable for use as fuel in circulating fluidized boilers and cement kilns. More experience would be necessary to determine the full benefits that could be derived and to discover long term effects, but no technical barriers to full scale commercial use of chipped asphalt shingle materials in these applications were discovered. While the technical feasibility of various options was demonstrated, only the use of asphalt shingle materials in hot mix asphalt applications is currently viable economically.

  10. Recovery and reuse of asphalt roofing waste. Final report

    SciTech Connect (OSTI)

    Desai, S.; Graziano, G.; Shepherd, P.

    1984-02-02

    Burning of asphalt roofing waste as a fuel and incorporating asphalt roofing waste in bituminous paving were identified as the two outstanding resource recovery concepts out of ten studied. Four additional concepts might be worth considering under different market or technical circumstances. Another four concepts were rated as worth no further consideration at this time. This study of the recovery of the resource represented in asphalt roofing waste has identified the sources and quantities of roofing waste. About six million cubic yards of scrap roofing are generated annually in the United States, about 94% from removal of old roofing at the job site and the remainder from roofing material production at factories. Waste disposal is a growing problem for manufacturers and contractors. Nearly all roofing waste is hauled to landfills at a considerable expense to roofing contractors and manufacturers. Recovery of the roofing waste resource should require only a modest economic incentive. The asphalt contained in roofing waste represents an energy resource of more than 7 x 10/sup 13/ Btu/year. Another 1 x 10/sup 13/ Btu/year may be contained in field-applied asphalt on commercial building roofs. The two concepts recommended by this study appear to offer the broadest applicability, the most favorable economics, and the highest potential for near-term implementation to reuse this resource.

  11. Asphalt emulsion sealing of uranium mill tailings. 1979 annual report

    SciTech Connect (OSTI)

    Hartley, J.N.; Koehmstedt, P.L.; Esterl, D.J.; Freeman, H.D.

    1980-06-01

    Uranium mill tailings are a source of low-level radiation and radioactive materials that may be released into the environment. Stabilization or disposal of these tailings in a safe and environmentally sound way is necessary to minimize radon exhalation and other radioactive releases. One of the most promising concepts for stabilizing uranium tailings is being investigated at the Pacific Northwest Laboratory: the use of asphalt emulsion to contain radon and other potentially hazardous materials in uranium tailings. Results of these studies indicate that radon flux from uranium tailings can be reduced by greater than 99% by covering the tailings with an asphalt emulsion that is poured on or sprayed on (3.0 to 7.0 mm thick), or mixed with some of the tailings and compacted to form an admixture seal (2.5 to 15.2 cm) containing 18 wt % residual asphalt.

  12. Investigation of Asphalt Mixture Creep Behavior Using Thin Beam Specimens

    SciTech Connect (OSTI)

    Zofka, Adam; Marasteanu, Mihai; Turos, Mugur

    2008-02-15

    The asphalt pavement layer consists of two or more lifts of compacted asphalt mixture; the top of the layer is also exposed to aging, a factor that significantly affects the mixture properties. The current testing specifications use rather thick specimens that cannot be used to investigate the gradual change in properties with pavement depth. This paper investigates the feasibility of using the 3-point bending test with thin asphalt mixture beams (127x12.7x6.35 mm) to determine the low-temperature creep compliance of the mixtures. Several theoretical and semi-empirical models, from the theory of composites, are reviewed and evaluated using numerical and experimental data. Preliminary results show that this method can be used for low-temperature mixture characterization but several crucial factors need further inspection and interpretation.

  13. Evaluation of products recovered from scrap tires for use as asphalt modifiers

    SciTech Connect (OSTI)

    McKay, J.

    1992-05-01

    Western Research Institute performed rheological tests and water sensitivity tests on asphalt cements that had been modified with carbonous residues obtained from the pyrolysis of scrap tires and waste motor oil. These tests are part of an ongoing program at the University of Wyoming Chemical Engineering Department to evaluate, as asphalt additives, solid carbonous products recovered from the scrap tire and waste motor oil pyrolysis experiments conducted at the University. The tests showed that carbonous residues increased the viscosity and decreased the elasticity of AC-10 and AC-20 asphalts. The tests also indicatedthat asphalt cements modified with carbonous residues were less sensitive to water damage and age embrittlement than unmodified asphalt cements.

  14. Automated titration method for use on blended asphalts

    DOE Patents [OSTI]

    Pauli, Adam T.; Robertson, Raymond E.; Branthaver, Jan F.; Schabron, John F.

    2012-08-07

    A system for determining parameters and compatibility of a substance such as an asphalt or other petroleum substance uses titration to highly accurately determine one or more flocculation occurrences and is especially applicable to the determination or use of Heithaus parameters and optimal mixing of various asphalt stocks. In a preferred embodiment, automated titration in an oxygen gas exclusive system and further using spectrophotometric analysis (2-8) of solution turbidity is presented. A reversible titration technique enabling in-situ titration measurement of various solution concentrations is also presented.

  15. Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures

    DOE Patents [OSTI]

    Plancher, Henry; Petersen, Joseph C.

    1982-01-01

    Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

  16. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y.

    1991-01-01

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  17. Remedial investigation/feasibility study analysis asphalt storage area, Elmendorf AFB, Alaska. Master's thesis

    SciTech Connect (OSTI)

    Miller, N.S.

    1993-01-01

    This report is focused on an abandoned material storage area located on Elmendorf Air Force Base (EAFB), Alaska. The site is located approximately 2000 feet from the east end of the east/west runway and includes approximately 25 acres. The site was used for asphalt storage and preparation activities during the 1940s and 1950s. Approximately 4,500 drums of asphalt and 29 drums of unknown materials have been abandoned at the site. The drums are located in 32 areas throughout the 25-acre site. Following several decades of exposure to the elements, many of the drums have corroded and leaked to the ground surface. Several acres of soil are inundated with liquid asphalt that has leaked from the drums. Depths of the asphalt range from 6 to 10 inches in areas where surface anomalies have created depressions, and thus a collection point for the asphalt. A 14-x 18-x 4 foot wood frame pit used to support previous asphalt operations is located at the north end of the site. The pit contains approximately 2300 gallons of asphalt. There are also locations where the soil appears to be contaminated by petroleum products other than asphalt.

  18. Genotoxicity and apoptosis in Drosophila melanogaster exposed to benzene, toluene and xylene: Attenuation by quercetin and curcumin

    SciTech Connect (OSTI)

    Singh, Mahendra P.; Mishra, M.; Sharma, A.; Shukla, A.K.; Mudiam, M.K.R.; Patel, D.K.; Ram, K. Ravi; Chowdhuri, D. Kar

    2011-05-15

    Monocyclic aromatic hydrocarbons (MAHs) such as benzene, toluene and xylene are being extensively used for various industrial and household purposes. Exposure to these hydrocarbons, occupationally or non-occupationally, is harmful to organisms including human. Several studies tested for toxicity of benzene, toluene and xylene, and interestingly, only a few studies looked into the attenuation. We used Drosophila model to test the genotoxic and apoptotic potential of these compounds and subsequently evaluated the efficiency of two phytochemicals, namely, quercetin and curcumin in attenuating test chemical induced toxicity. We exposed third instar larvae of wild type Drosophila melanogaster (Oregon R{sup +}) to 1.0-100.0 mM benzene, toluene or xylene, individually, for 12, 24 and 48 h and examined their apoptotic and genotoxic potential. We observed significantly (P < 0.001) increased apoptotic markers and genotoxicity in a concentration- and time-dependent manner in organisms exposed to benzene, toluene or xylene. We also observed significantly (P < 0.001) increased cytochrome P450 activity in larvae exposed to test chemicals and this was significantly reduced in the presence of 3',4'-dimethoxyflavone, a known Aryl hydrocarbon receptor (AhR) blocker. Interestingly, we observed a significant reduction in cytochrome P450 activity, GST levels, oxidative stress parameters, genotoxic and apoptotic endpoints when organisms were exposed simultaneously to test chemical along with quercetin or curcumin. The study further suggests the suitability of D. melanogaster as an alternate animal model for toxicological studies involving benzene, toluene and xylene and its potential in studying the protective role(s) of phytochemicals.

  19. Hanford Permanent Isolation Barrier Program: Asphalt technology data and status report - FY 1994

    SciTech Connect (OSTI)

    Freeman, H.D.; Romine, R.A.; Zacher, A.H.

    1994-09-01

    The asphalt layer within the Hanford Permanent Isolation Barrier (HPIB) is an important component of the overall design. This layer provides a RCRA equivalent backup to the overlying earthen layers in the unlikely event that these layers are not able to reduce the infiltration rate to less than 0.05 cm/yr. There is only limited amount of information on using asphalt for a moisture infiltration barrier over the long times required by the HPIB. Therefore, a number of activities are under way, as part of the Barrier Development Program, to obtain data on the performance of asphalt as a moisture barrier in a buried environment over a 1000-year period. These activities include (1) determining RCRA equivalency, (2) measurement of physical properties, (3) measurement of aging characteristics, and (4) relationship to ancient asphalt analogs. During FY 1994 progress was made on all of these activities. Studies were conducted both in the laboratory and on the prototype barrier constructed over the 216-B-57 crib in the 200 East Area on the Hanford Site. This report presents results obtained from the asphalt technology tasks during FY 1994. Also included are updates to planned activities for asphalt analogs and monitoring the asphalt test pad near the prototype barrier. Measurements of hydraulic conductivity on the HMAC portion of the prototype barrier show that the asphalt layers easily meet the RCRA standard of 1 {times} 10{sup -7} cm/s. In-place measurements using a new field falling head technique show an average of 3.66 {times} 10{sup -8} cm/s, while cores taken from the north end of the prototype and measured in a laboratory setup averaged 1.29 {times} 10{sup -9} cm/s. Measurements made on the fluid applied asphalt membrane (polymer-modified asphalt) show an extremely low permeability of less than 1 {times} 10{sup -11} cm/s.

  20. Y-12's rough roads smoothed over with 23,000 tons of recycled asphalt |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) 's rough roads smoothed over with 23,000 tons of recycled asphalt Tuesday, December 29, 2015 - 12:00am NNSA Blog Some 23,000 tons of asphalt removed during this summer's UPF site work have been put to use throughout the site. Potholes and gravel roads are now "paved" with the recycled asphalt that has been ground into a material called base course. Unlike gravel, the material tends to rebind into a solid form as it is packed down,

  1. Development of superior asphalt recycling agency: Phase 1, Technical feasibility. Technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Glover, C.J.; Davison, R.R.; Lin, Moon-Sun; Chaffin, J.; Liu, Meng; Eckhardt, C.

    1996-04-01

    About every 12 years, asphalt roads must be reworked, and this is usually done by placing thick layers (hot-mix overlays) of new material on top of failed material, resulting in considerable waste of material and use of new asphalt binder. A good recycling agent is needed, not only to reduce the viscosity of the aged material but also to restore compatibility. Objective is to establish the technical feasibility (Phase I) of determining the specifications and operating parameters for producing high quality recycling agents which will allow most/all the old asphalt-based road material to be recycled. It is expected that supercritical fractionation can be used. The advanced road aging simulation procedure will be used to study aging of blends of old asphalt and recycling agents.

  2. New Cool Roof Coatings and Affordable Cool Color Asphalt | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy New Cool Roof Coatings and Affordable Cool Color Asphalt New Cool Roof Coatings and Affordable Cool Color Asphalt Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review emrgtech25_cheng_040413.pdf (1.35 MB) More Documents & Publications Accelerated Aging of Roofing Materials - 2013 BTO Peer Review Berkeley Lab Heat Island Group research assistant Sharon Chen prepares a prototype of high-performance cool shingle roofing. Credit: Heat Island

  3. Asphalt emulsion radon barrier systems for uranium mill tailings: an overview of the technology

    SciTech Connect (OSTI)

    Baker, E.G.; Hartley, J.N.; Freeman, H.D.; Gates, T.E.; Nelson, D.A.; Dunning, R.L.

    1984-03-01

    Pacific Northwest Laboratory (PNL), under contract to the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) office, has developed an asphalt emulsion cover system to reduce the release of radon from uranium mill tailings. The system has been field tested at Grand Junction, Colorado. Results from laboratory and field tests indicate that this system is effective in reducing radon release to near-background levels (<2.5 pCi m/sup -2/s/sup -1/) and has the properties required for long-term effectiveness and stability. Engineering specifications have been developed, and analysis indicates that asphalt emulsion covers are cost-competitive with other cover systems. This report summarizes the technology for asphalt emulsion radon barrier systems. 59 references, 45 figures, 36 tables.

  4. Computerized economic and statistical investigation of the Alabama liquid asphalt market for public entities

    SciTech Connect (OSTI)

    Morgan, J.E. Jr.

    1986-01-01

    This study outlines the development of an economic data base and techniques utilized in identifying noncompetitive practices in the sealed bid market for liquid asphalt products purchased by public entities in the State of Alabama. It describes the organization of data and methods for displaying salient characteristics of market conduct and performance. Likely areas of anticompetitive activity are identified from an examination of conditional factors influencing collusion in a market and of circumstantial evidence of collusive behavior of the vendors. Methods of detecting and analyzing suspicious behavior are indicated and applied to selected data. The conclusion reached was that collusion was present in the Alabama liquid asphalt market during 1971-1978. An antitrust action was initiated by the State. Damages were calculated from the data base using a GLM regression model. An out-of-court settlement was negotiated by the defendant vendors.

  5. Development of asphalts and pavements using recycled tire rubber. Phase 1, Technical feasibility. Technical progress report, September 1, 1994--August 31, 1995

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J.

    1996-06-01

    About 285 million tires are discarded every year; less than 100 million are currently being recycled, with the rest being placed in landfills and other waste sites. A solution to reduce the littering of the environment is to use ground tire rubber in road construction. Currently, about 27 million tons of asphalt are used each year in road construction and maintenance of the country`s 2 million miles of roads. If all of the waste tire rubber could be combined with asphalt in road construction, it would displace less than 6% of the total asphalt used each year, yet could save about 60 trillion Btus annually. Purpose of this project is to provide data needed to optimize the performance of rubber-asphalt concretes. The first phase is to develop asphalts and recycling agents tailored for compatibility with ground tire rubber. Chapter 2 presents results on Laboratory Testing and Evaluation: fractionate asphalt material, reblending for aromatic asphalts, verifying optimal curing parameters, aging of blends, and measuring ductilities of asphalt-rubber binders. Chapter 3 focuses on Evaluating Mixture Characteristics (modified binders). Chapter 4 covers Adhesion Test Development (water susceptibility is also covered). The final chapter focuses on the Performance/Economic Update and Commercialization Plan.

  6. Recycling spent sandblasting grit and similar wastes as aggregate in asphaltic concrete. Technical data sheet

    SciTech Connect (OSTI)

    Heath, J.C.; Nelson, B.

    1998-12-01

    The Naval Facilities Engineering Service Center (NFESC), Port Hueneme, California, and Naval Facilities Engineering Command Engineering Field Activity, West, San Bruno, California, took overall leadership in identifying and testing methods to manage waste generated from a machine shop located at Hunters Point Annex, at Naval Station, Treasure Island, California. Ship cleaning and equipment maintenance resulted in the accumulation of 4,665 tons of spent sandblasting grit at the site. The spent grit, consisting of silica sand plus a small amount of slag-derived grit, had the physical characteristics of coarse-grained beach sand and also contained fragments of coatings. The spent grit had the potential for exhibiting hazardous characteristics since the coatings included lead-based primers, copper, and butyltin-containing antifouling topcoats. The most beneficial application of reusing the spent grit was to use it as a replacement for some of the fine aggregate in asphaltic concrete. A test program was established that included characterization, bench-scale testing, long-term pilot scale testing, and a full-scale demonstration. Full-scale asphalt production provided samples which proved both the chemical leaching resistance and physical performance characteristics were acceptable.

  7. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Pauul J. Tikalsky

    2004-10-31

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: (1) a statistically sound evaluation of the characterization of foundry sand, (2) a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and (3) the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at N{sub ini}, N{sub des}, and N{sub max}. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  8. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Tikalsky, Paul J.; Bahia, Hussain U.; Deng, An; Snyder, Thomas

    2004-10-15

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: a statistically sound evaluation of the characterization of foundry sand, a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at Nini, Ndes, and Nmax. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  9. Intercalation of p-methycinnamic acid anion into Zn-Al layered double hydroxide to improve UV aging resistance of asphalt

    SciTech Connect (OSTI)

    Peng, Chao; Dai, Jing; Yu, Jianying; Yin, Jian

    2015-02-15

    A UV absorber, p-methycinnamic acid (PMCA), was intercalated into Zn-Al layered double hydroxide (LDH) by calcination recovery. Fourier transform infrared spectroscopy showed that the PMCA anions completely replaced the CO{sub 3}{sup 2−} anions in the interlayer galleries of Zn-Al-LDH containing PMCA anions (Zn-Al-PMCA-LDH). X-ray diffraction and transmission electron microscopy showed that the interlayer distance increased from 0.78 nm to 1.82 nm after the substitution of PMCA anions for CO{sub 3}{sup 2−} anions. The similar diffraction angles of the CO{sub 3}{sup 2−} anion-containing Zn-Al-LDH (Zn-Al-CO{sub 3}{sup 2−}-LDH) and the Zn-Al-CO{sub 3}{sup 2−}-LDH/styrene–butadiene–styrene (SBS) modified asphalt implied that the asphalt molecules do not enter into the LDH interlayer galleries to form separated-phase structures. The different diffraction angles of Zn-Al-PMCA-LDH and Zn-Al-PMCA-LDH/SBS modified asphalt indicated that the asphalt molecules penetrated into the LDH interlayer galleries to form an expanded-phase structure. UV-Vis absorbance analyses showed that Zn-Al-PMCA-LDH was better able to block UV light due to the synergistic effects of PMCA and Zn-Al-LDH. Conventional physical tests and atomic force microscopy images of the SBS modified asphalt, Zn-Al-CO{sub 3}{sup 2−}-LDH/SBS modified asphalt and Zn-Al-PMCA-LDH/SBS modified asphalt before and after UV aging indicated that Zn-Al-PMCA-LDH improved the UV aging resistance of SBS modified asphalts.

  10. Headspace solid-phase microextraction (HS-SPME) for the determination of benzene, toluene, ethylbenzene, and xylenes (BTEX) in foundry molding sand

    SciTech Connect (OSTI)

    Dungan, R.S. [USDA ARS, Beltsville, MD (United States). Environmental Management & Byproducts Utilization Laboratory

    2005-07-01

    The use of headspace solid-phase microextraction (HS-SPME) to determine benzene, toluene, ethylbenzene, and xylenes (BTEX) in foundry molding sand, specifically a 'green sand' (clay-bonded sand) was investigated. The BTEX extraction was conducted using a 75 {mu} M carboxen-polydimethylsiloxane (CAR-PDMS) fiber, which was suspended above 10 g of sample. The SPME fiber was desorbed in a gas chromatograph injector port (280{sup o}C for 1 min) and the analytes were characterized by mass spectrometry. The effects of extraction time and temperature, water content, and clay and bituminous coal percentage on HS-SPME of BTEX were investigated. Because green sands contain bentonite clay and carbonaceous material such as crushed bituminous coal, a matrix effect was observed. The detection limits for BTEX were determined to be {lt}= 0.18 ng g{sup -1} of green sand.

  11. Investigation of the proposed solar-driven moisture phenomenon in asphalt shingle roofs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boudreaux, Philip; Pallin, Simon; Jackson, Roderick

    2016-01-19

    We report that unvented, sealed or conditioned attics are an energy efficiency measure to reduce the thermal load of the home and decrease the space conditioning energy consumption. This retrofit is usually done by using spray polyurethane foam underneath the roof sheathing and on the gables and soffits of an attic to provide a thermal and air barrier. Unvented attics perform well from this perspective but from a moisture perspective sometimes the unvented attic homes have high interior humidity or moisture damage to the roof. As homes become more air tight and energy efficient, an understanding of the hygrothermal dynamicsmore » of the home become more important. One proposed reason for high unvented attic humidity has been that moisture can come through the asphalt shingle roof system and increase the moisture content of the roof sheathing and attic air. This has been called solar driven moisture. Oak Ridge National Laboratory (ORNL) investigated this proposed phenomenon by examining the physical properties of a roof and the physics required for the phenomenon. Results showed that there are not favorable conditions for solar driven moisture to occur. ORNL also conducted an experimental study on an unvented attic home and compared the humidity below the roof sheathing before and after a vapor impermeable underlayment was installed. There was no statistically significant difference in absolute humidity before and after the vapor barrier was installed. Finally, the outcome of the theoretical and experimental study both suggest that solar driven moisture does not occur in any significant amount.« less

  12. Utilize Cementitious High Carbon Fly Ash (CHCFA) to Stabilize Cold In-Place Recycled (CIR) Asphalt Pavement as Base Coarse

    SciTech Connect (OSTI)

    Wen, Haifang; Li, Xiaojun; Edil, Tuncer; O'Donnell, Jonathan; Danda, Swapna

    2011-02-05

    The purpose of this study was to evaluate the performance of cementitious high carbon fly ash (CHCFA) stabilized recycled asphalt pavement as a base course material in a real world setting. Three test road cells were built at MnROAD facility in Minnesota. These cells have the same asphalt surface layers, subbases, and subgrades, but three different base courses: conventional crushed aggregates, untreated recycled pavement materials (RPM), and CHCFA stabilized RPM materials. During and after the construction of the three cells, laboratory and field tests were carried out to characterize the material properties. The test results were used in the mechanistic-empirical pavement design guide (MEPDG) to predict the pavement performance. Based on the performance prediction, the life cycle analyses of cost, energy consumption, and greenhouse gasses were performed. The leaching impacts of these three types of base materials were compared. The laboratory and field tests showed that fly ash stabilized RPM had higher modulus than crushed aggregate and RPM did. Based on the MEPDG performance prediction, the service life of the Cell 79 containing fly ash stabilized RPM, is 23.5 years, which is about twice the service life (11 years) of the Cell 77 with RPM base, and about three times the service life (7.5 years) of the Cell 78 with crushed aggregate base. The life cycle analysis indicated that the usage of the fly ash stabilized RPM as the base of the flexible pavement can significantly reduce the life cycle cost, the energy consumption, the greenhouse gases emission. Concentrations of many trace elements, particularly those with relatively low water quality standards, diminish over time as water flows through the pavement profile. For many elements, concentrations below US water drinking water quality standards are attained at the bottom of the pavement profile within 2-4 pore volumes of flow.

  13. Initial site characterization, environmental assessment, and corrective actions for underground storage tank 2315-U, Pine Ridge East Repeater Station, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Eaton, J.M.; Ingram, E.M. )

    1991-02-01

    This document presents the Initial Site Characterization Report and information to date regarding environmental assessment and corrective actions for Underground Storage Tank (UST) 2315-U at the Pine Ridge East Repeater Station, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. This document was prepared following guidance in US Environmental Protection Agency (EPA) regulations promulgated under 40 CFR 280. The Pine Ridge East Repeater Station is located on Pine Ridge, which borders the Y-12 Plant to the north. One 64-gallon, asphalt-coated steel tank was located adjacent to the Repeater Station. This tank was used to store gasoline for the station's emergency power generator. Tank 2315-U was exempted from regulation under 40 CFR 280 and Tennessee Department of Health and Environment (TDHE) Rules 1200-1-15.-01 through 1200-1-15-.07 due to size and emergency generator exemptions. Because of an identified release discovered during initial corrective actions, TDHE requirements in revised Rule 1200-1-15-.06, promulgated April 15, 1990, regarding release response and corrective actions, apply to the site (TDHE, 1990). This report documents all activities, including initial abatement, initial site characterization, environmental assessment sampling, and corrective actions conducted to comply with TDHE regulations. Initial site characterization sampling data revealed that benzene, toluene, and xylene (BTX) concentrations exceeded applicable regulatory guidelines and lead values were elevated above levels expected for clean soils. 17 refs., 10 figs., 8 tabs.

  14. SOLAR HEATING OF TANK BOTTOMS Application of Solar Heating to Asphaltic and Parrafinic Oils Reducing Fuel Costs and Greenhouse Gases Due to Use of Natural Gas and Propane

    SciTech Connect (OSTI)

    Eugene A. Fritzler

    2005-09-01

    The sale of crude oil requires that the crude meet product specifications for BS&W, temperature, pour point and API gravity. The physical characteristics of the crude such as pour point and viscosity effect the efficient loading, transport, and unloading of the crude oil. In many cases, the crude oil has either a very high paraffin content or asphalt content which will require either hot oiling or the addition of diluents to the crude oil to reduce the viscosity and the pour point of the oil allowing the crude oil to be readily loaded on to the transport. Marginal wells are significantly impacted by the cost of preheating the oil to an appropriate temperature to allow for ease of transport. Highly paraffinic and asphaltic oils exist throughout the D-J basin and generally require pretreatment during cold months prior to sales. The current study addresses the use of solar energy to heat tank bottoms and improves the overall efficiency and operational reliability of stripper wells.

  15. Selective aromatization of C[sub 3] and C[sub 4] paraffins over modified encilite catalysts. 1. Qualitative study

    SciTech Connect (OSTI)

    Jana, A.K.; Rao, M.S. . Department of Chemical Engineering)

    1993-06-01

    The catalytic activity of Zn-encilite in the aromatization of propane and n-butane has been studied by a comparative study of the yields of benzene, toluene, and xylenes (BTX) using propane and n-butane as feeds. The results showed that n-butane had better activity and selectivity to BTX than propane. The effects of reaction temperature, contact time, inlet concentration, poisoning with ammonia on H-encilite, and different degrees of ion exchange with Zn[sup 2+] ion were studied in detail in order to obtain information on the reaction mechanism. The results indicated that the activity and the selectivity were dictated by the acidity and Zn loading on the catalyst.

  16. Make aromatics from LPG

    SciTech Connect (OSTI)

    Doolan, P.C. ); Pujado, P.R. )

    1989-09-01

    Liquefied petroleum gas (LPG) consists mainly of the propane and butane fraction recovered from gas fields, associated petroleum gas and refinery operations. Apart from its use in steam cracking and stream reforming, LPG has few petrochemical applications. The relative abundance of LPG and the strong demand for aromatics - benzene, toluene and xylenes (BTX) - make it economically attractive to produce aromatics via the aromatization of propane and butanes. This paper describes the Cyclar process, which is based on a catalyst formulation developed by BP and which uses UOP's CCR catalyst regeneration technology, converts propane, butanes or mixtures thereof to petrochemical-quality aromatics in a single step.

  17. Surface roughness effects on the solar reflectance of cool asphalt...

    Office of Scientific and Technical Information (OSTI)

    The model is then used to compute the reflectance of shingles with a mixture of different colored granules, when the reflectances of the corresponding mono-color shingles are ...

  18. A novel plug-flow digester for biogasification of conventional and hazardous organics

    SciTech Connect (OSTI)

    Ghosh, S.; Kato, Y.; Liu, T.; Fukushi, K.

    1996-12-31

    A novel plug-flow digestion system of simple construction was designed, fabricated and operated for several years with a synthetic mixture of solid and liquid wastes simulating conditions south of the US-Mexican border and other developing countries. Benzene, toluene, and o-xylene (BTX) were mixed with the synthetic feed in several phases of this research to simulate field conditions where these solvents are discharged to public sewers and mixed with non-hazardous pollutants. The mesophilic plug-flow digester exhibited a high gas yield of 0.46 SCM /kg VS added, a methane content of 77 mol%, and a VS reduction of 75% at an HRT of 13 days with a 96% biodegradation of the feed toluene. At a feed concentration of 50 mg/l, toluene did not inhibit anaerobic fermentation. Gas and methane yields, and VS and COD conversion efficiencies were about the same with or without toluene present in the feed. At a reduced HRT of 8 days, a high feed COD concentration of 50,000 mg/l, and a loading rate of 0.48 kg VS/m{sup 3}-day, the digester afforded a gas yield of 3.1 SCM /kg VS added, and a methane content of 67 mol%. Benzene, toluene, and o-xylene were biodegraded at efficiencies of 94%, 90%, and 88%, respectively. The degradation kinetics of the xenobiotic compound could be described by a model based on cometabolic degradation of these secondary substrates.

  19. Flash methanolysis of wood for the production of fuels and chemicals

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1983-01-01

    Biomass in the form of less than 1000 micron oven dried fir wood particles was flash pyrolyzed in the presence of methane (methanolysis) in a downflow 1 in. I.D. tubular reactor at pressures of 20 to 200 psi and temperatures between 800/sup 0/ and 1050/sup 0/C. The major products were benzene, toluene and xylene (BTX), a heavy oily liquid (greater than or equal to C/sub 9/), ethylene and carbon monoxide. As much as 12% of the available carbon in the wood was converted to BTX, 21% to ethylene and 48% to carbon monoxide at 50 psi and 1000/sup 0/C. The maximum heavier oil yield of 11% was observed at 50 psi and 800/sup 0/C. Wood particle residence times for all experiments were calculated to be less than 1 second at 20 and 50 psi and up to 2.8 sec at 200 psi. The yelds were found to be greatly influenced by the methane to wood feed ratio. Experiments were conducted to insure the results to be that produced from the wood and methane and not a catalytic effect of the reactor wall of foreign matter. Material balance, including char analyses, indicate approximately 75 to 80% of the available carbon in the feed wood reacted. Methane balances were within the margin of error of the measuring equipment showing that there is no significant net production or consumption of methane. A preliminary economic evaluation of a 2000 ton/day wood processing plant producing ethylene, benzene and methanol showed a reasonably cmpetitive plant investment of $29,000/barrel fuel oil equivalent/day assuming 15% return on investment and present market values for the products.

  20. Field-usable portable analyzer for chlorinated organic compounds

    SciTech Connect (OSTI)

    Buttner, W.J.; Penrose, W.R.; Stetter, J.R.

    1995-10-01

    Transducer Research, Inc. (TRI) has been working with the DOE Morgantown Energy Technology Center to develop a new chemical monitor based on a unique sensor which responds selectively to vapors of chlorinated solvents. We are also developing field applications for the monitor in actual DOE cleanup operations. During the initial phase, prototype instruments were built and field tested. Because of the high degree of selectivity that is obtained, no response was observed with common hydrocarbon organic compounds such as BTX (benzene, toluene, xylene) or POLs (petroleum, oil, lubricants), and in fact, no non-halogen-containing chemical has been identified which induces a measurable response. By the end of the Phase I effort, a finished instrument system was developed and test marketed. This instrument, called the RCL MONITOR, was designed to analyze individual samples or monitor an area with automated repetitive analyses. Vapor levels between 0 and 500 ppm can be determined in 90 s with a lower detection limit of 0.2 ppm using the handportable instrument. In addition to the development of the RCL MONITOR, advanced sampler systems are being developed to: (1) extend the dynamic range of the instrument through autodilution of the vapor and (2) allow chemical analyses to be performed on aqueous samples. When interfaced to the samplers, the RCL MONITOR is capable of measuring chlorinated solvent contamination in the vapor phase up to 5000 ppm and in water and other condensed media from 10 to over 10,000 ppb(wt)--without hydrocarbon and other organic interferences.

  1. Field Testing Unvented Roofs with Asphalt Shingles in Cold and Hot-Humid Climates

    SciTech Connect (OSTI)

    Ueno, Kohta; Lstiburek, Joseph W.

    2015-09-01

    Insulating roofs with dense-pack cellulose (instead of spray foam) has moisture risks, but is a lower cost approach. If moisture risks could be addressed, buildings could benefit from retrofit options, and the ability to bring HVAC systems within the conditioned space. Test houses with unvented roof assemblies were built to measure long-term moisture performance, in the Chicago area (5A) and the Houston area (2A). The Chicago-area test bed had seven experimental rafter bays, including a control vented compact roof, and six unvented roof variants with cellulose or fiberglass insulation. The interior was run at 50% RH. All roofs except the vented cathedral assembly experienced wood moisture contents and RH levels high enough to constitute failure. Disassembly at the end of the experiment showed that the unvented fiberglass roofs had wet sheathing and mold growth. In contrast, the cellulose roofs only had slight issues, such as rusted fasteners and sheathing grain raise. The Houston-area roof was an unvented attic insulated with spray-applied fiberglass. Most ridges and hips were built with a diffusion vent detail, capped with vapor permeable roof membrane. Some ridge sections were built as a conventional unvented roof, as a control. In the control unvented roofs, roof peak RHs reached high levels in the first winter; as exterior conditions warmed, RHs quickly fell. In contrast, the diffusion vent roofs had drier conditions at the roof peak in wintertime, but during the summer, RHs and MCs were higher than the unvented roof (albeit in the safe range).

  2. Y-12's rough roads smoothed over with recycled asphalt | Y-12 National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NNSA's systems administrators keep the computers running For Systems Administrator (SysAdmin) Day, meet some of the men & women keeping NNSA going. Thanks for all you do! Michelle Swinkels, Senior Systems and Network Technologist at NNSA's Lawrence Livermore National Laboratory What excites you about your work for NNSA? I'... NNSA innovation fuels space exploration Today, in accordance with a 1971 Presidential proclamation, the United States commemorates the first human setting foot on the

  3. Technology Solutions Case Study: Field Testing an Unvented Roof with Asphalt Shingles in a Cold Climate

    SciTech Connect (OSTI)

    K. Ueno and J. Lstiburek

    2015-09-01

    Test houses with unvented roof assemblies were built to measure long-term moisture performance, in the Chicago area (5A) and the Houston area (2A). The Chicago-area test bed had seven experimental rafter bays, including a "control" vented compact roof, and six unvented roof variants with cellulose or fiberglass insulation. The interior was run at 50% RH. All roofs except the vented cathedral assembly experienced wood moisture contents and RH levels high enough to constitute failure. Disassembly at the end of the experiment showed that the unvented fiberglass roofs had wet sheathing and mold growth. In contrast, the cellulose roofs only had slight issues, such as rusted fasteners and sheathing grain raise.

  4. Field Testing Unvented Roofs with Asphalt Shingles in Cold and Hot-Humid Climates

    SciTech Connect (OSTI)

    Ueno, Kohta; Lstiburek, Joseph W.

    2015-09-01

    Test houses with unvented roof assemblies were built to measure long-term moisture performance, in the Chicago area (5A) and the Houston area (2A). The Chicago-area test bed had seven experimental rafter bays, including a control vented compact roof, and six unvented roof variants with cellulose or fiberglass insulation. The interior was run at 50% RH. The Houston-area roof was an unvented attic insulated with spray-applied fiberglass. Most ridges and hips were built with a diffusion vent detail, capped with vapor permeable roof membrane. In contrast, the diffusion vent roofs had drier conditions at the roof peak in wintertime, but during the summer, RHs and MCs were higher than the unvented roof (albeit in the safe range).

  5. Broward County, Florida: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    in Broward County, Florida Advanced Green Technologies Apollo Energy Systems Inc Atlas Solar Innovations BTX Holdings Inc Cyclone Power Technologies Inc Ener1 Inc EnerFuel...

  6. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Products Supplied Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per

  7. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Exports Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

  8. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Exports by Destination Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels

  9. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Area of Entry Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short

  10. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    U.S. Imports by Country of Origin Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is

  11. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Imports by Destination Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels

  12. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Tanker and Barge Between PADDs Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5

  13. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Yield Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

  14. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Production Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short

  15. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    & Blender Net Production Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5

  16. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Refinery Stocks Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per

  17. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Supply and Disposition Balance Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5

  18. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    : Asphalt and road oil consumption, price, and expenditure estimates, 2014 State Asphalt and road oil a Consumption Prices Expenditures Thousand barrels Trillion Btu Dollars per ...

  19. U.S. Energy Information Administration | State Energy Data 2014: Prices and Expenditures

    Gasoline and Diesel Fuel Update (EIA)

    7 Asphalt: A dark brown-to-black cement-like material obtained by petroleum processing and containing bitumens as the predominant component; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. ASTM: The American Society for Testing and Materials. Aviation gasoline (finished): A complex mixture of

  20. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    PAD District Imports by Country of Origin Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for

  1. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Receipts by Pipeline, Tanker, and Barge Between PAD Districts Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The

  2. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Pipeline, Tanker, and Barge Between PADDs Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for

  3. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Shell Storage Capacity at Operable Refineries Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for

  4. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Working Storage Capacity at Operable Refineries Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor

  5. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy

    2011-04-30

    This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, p

  6. U.S. Energy Information Administration | State Energy Data 2014: Consumption

    Gasoline and Diesel Fuel Update (EIA)

    5 Glossary G L O S S A R Y Asphalt: A dark brown-to-black cement-like material obtained by petro- leum processing and containing bitumens as the predominant component; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton. ASTM:

  7. 1

    Office of Environmental Management (EM)

    Tetrachloroethylene, Trichloroethylene, Trichloroflouromethane, Acetone, Ethyl ether, Methanol, Methyl isobutyl ketone, n-Butyl alcohol, Xylene, Cresols, Cresylic acid,...

  8. An NMR (Nuclear Magnetic Resonance) Investigation of the Chemical Association and Molecular Dynamics in Asphalt Ridge Tar Sand Ore and Bitumen

    DOE R&D Accomplishments [OSTI]

    Netzel, D. A.; Coover, P. T.

    1987-09-01

    Preliminary studies on tar sand bitumen given in this report have shown that the reassociation of tar sand bitumen to its original molecular configuration after thermal stressing is a first-order process requiring nearly a week to establish equilibrium. Studies were also conducted on the dissolution of tar sand bitumen in solvents of varying polarity. At a high-weight fraction of solute to solvent the apparent molecular weight of the bitumen molecules was greater than that of the original bitumen when dissolved in chloroform-d{sub 1} and benzene-d{sub 6}. This increase in the apparent molecular weight may be due to micellar formation or a weak solute-solvent molecular complex. Upon further dilution with any of the solvents studied, the apparent molecular weight of the tar sand bitumen decreased because of reduced van der Waals forces of interaction and/or hydrogen bonding. To define the exact nature of the interactions, it will be necessary to have viscosity measurements of the solutions.

  9. 1

    Office of Environmental Management (EM)

    Xylene, Ethyl acetate, Ethyl benzene, Ethyl ether, n-Butyl alcohol, Cyclohexanone, Methanol, Cresols, Cresylic acid, Nitroobenzene, Carbon disulfide, Isobutanol, Pyridine, 2-...

  10. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemicals and transportation fuels from lignocellulosic biomass. DMF has a high octane number and is the precursor to green para-xylene. CTH enables selective...

  11. ITP Chemicals: Energy and Environmental Profile of the U.S. Chemical Industry, May 2000

    Office of Energy Efficiency and Renewable Energy (EERE)

    Profiles about the ethylene chain, propylene chain, benzene-toulene-xylene chain, agricultural chemicals chain, chlor-alkali industry, and supporting processes

  12. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kinetic Regimes in the Production of Renewable p-Xylene Work was performed at the Universities of Minnesota, Massachusetts and Delaware by the group of Dauenhauer, Fan, Caratzoulas ...

  13. Upgrading of heavy oils by asphaltenic bottom cracking

    SciTech Connect (OSTI)

    Sudoh, j.; Shiroto, Y.; Fukui, Y.; Takeuchi, C.

    1983-03-01

    Results of the pilot plant study of the conversion of heavy petroleum residues (Khafji VR) to lighter feedstocks deasphalted oil (DAO) by a combination process involving asphaltenic bottom cracking (ABC) and solvent deasphalting (SDA) are reported. In addition to correlations between DAO and asphalt yield under various hydrotreating conditions, a mathematical model describing quantitative relationships between recycle rate of SDA asphalt and ABC in extinction and recycle operations are described. Effects of process variations on product (DAO, asphalt) quality are also discussed.

  14. Building America Technology Solutions Case Study: Field Testing an Unvented

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Roof with Asphalt Shingles in a Cold Climate | Department of Energy Testing an Unvented Roof with Asphalt Shingles in a Cold Climate Building America Technology Solutions Case Study: Field Testing an Unvented Roof with Asphalt Shingles in a Cold Climate In this project, Building America team Building Science Corporation devised an experiment to build and instrument unvented test roofs using air-permeable insulation (dense-pack cellulose and fiberglass) in a cold climate (Chicago, Illinois

  15. Microsoft Word - DOE-ID-11-021 - North Wind EC.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 SECTION A. Project Title: Idaho National Laboratory Asphalt Repair Project - North Wind Services, LLC SECTION B. Project Description The deterioration of asphalt roads, pads and parking areas at Idaho National Laboratory (INL) facilities necessitates the repair and or replacement in selected areas. Repair and/or replacement of sections of asphalt roads, pads, walkways, and parking areas will be conducted at Advanced Mixed Waste Treatment Facility (AMWTP), Idaho Nuclear Technology and

  16. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Stocks by Type Definitions Key Terms Definition Alaskan in Transit Alaskan crude oil stocks in transit by water between Alaska and the other States, the District of Columbia, Puerto Rico, and the Virgin Islands. Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of

  17. Annual Site Environmental Report Summary Pamphlet Sandia National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... within a strict temperature band of 70 to 76 degrees ... Sandia continues installation of "Cool Roofs" at buildings ... Concrete, asphalt, wood, metal, insulation, and other C&D ...

  18. A novel technique for the production of cool colored concrete...

    Office of Scientific and Technical Information (OSTI)

    for the production of cool colored concrete tile and asphalt shingle roofing products Citation Details In-Document Search Title: A novel technique for the production of cool ...

  19. Recycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    recycle LANL innovates recycling paths for various materials. Aerosol cans Asphalt Batteries Cardboard Concrete Light bulbs Metal Pallets Paper Tires Toner cartridges Vegetation...

  20. EIA-800

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Residual Fuel Oil 511 Asphalt and Road Oil 931 * Includes propane, propylene, ethane, ethylene, normal butane, butylene, isobutane, isobutylene, and pentanes plus. Quantities ...

  1. EIA-801

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Residual Fuel Oil 511 Asphalt and Road Oil 931 Product Code PADD 1 Item Description * Includes ethane, ethylene, propane, propylene, normal butane, butylene, isobutane, ...

  2. Te

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refineras Refineries Refinera Raffinerie Asphalt ... Usine de valorisation United States Estados Unidos ... Ltd 71 Marathon Petroleum Co LP 106 Silver Eagle ...

  3. In situ BTEX biotransformation under enhanced nitrate- and sulfate-reducing conditions

    SciTech Connect (OSTI)

    Reinhard, M.; Shang, S.; Kitanidis, P.K.; Orwin, E.; Hopkins, G.D.; LeBron, C.A.

    1997-01-01

    In situ anaerobic biotransformation of BTEX (benzene, toluene, ethylbenzene, o-xylene, and m-xylene) was investigated under enhanced nitrate- and sulfate-reducing conditions. Controlled amounts of BTEX compounds added to slugs of treated groundwater were released into a gasoline-contaminated aquifer at Seal Beach, CA. In a series of studies, the slugs, 470-1700 L in volume, were released into the aquifer through a multi-port injection/extraction well and were subsequently withdrawn over a 2-3 month period. To evaluate unamended in situ conditions, the injectate was treated with granular activated carbon (GAC) and augmented with bromide as a tracer. To evaluate nitrate- and sulfate-reducing conditions, the injectate was also deionized and augmented with 200-300 {mu}g/L BTEX, nitrate or sulfate, and background electrolytes. Under unamended conditions, transformation appeared to be limited to the slow removal of toluene and m,p-xylene (i.e. sum of m+p-xylene). Under nitrate-reducing conditions, toluene, ethylbenzene, and m-xylene were transformed without a lag phase in less than 10 days, and o-xylene was transformed in 72 days. Under sulfate-reducing conditions, toluene, m-xylene and o-xylene were completely transformed in less then 50 days, and ethylbenzene was removed in 60 days. Benzene appeared to be removed under sulfate-reducing conditions, but the trend was pronounced only at some levels. 47 refs., 11 figs., 2 tabs.

  4. China shows increasing interest in heavy oil and oil sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    China and Canadian and US groups are cooperating in several areas to develop the heavy oil, asphalt, and oil sand deposits of China. The agreements dealing with exploration and upgrading are briefly described. The majority of the paper describes the occurrences of heavy oil, asphalt, and oil sands in China. 1 figure.

  5. Flash pyrolysis of biomass with reactive and nonreactive gases

    SciTech Connect (OSTI)

    Sundaram, M.S.; Steinberg, M.; Fallon, P.

    1982-10-01

    Studies were done on the flash pyrolysis of Douglas fir wood in the presence of reactive and nonreactive gases including hydrogen, methane, and helium. Pyrolysis and gasification of the wood particles was done in one step, without catalysts. Almost complete (98%) gasification of the carbon in Douglas fir wood was achieved at 1000/sup 0/C and 500-psi hydrogen pressure. The reaction products were methane, ethane, ethylene, carbon monoxide, BTX, and water. Flash hydropyrolysis produced a large yield of hydrocarbon gases (up to 78% C) comprising methane and ethane. High yields of ethylene (up to 21% C) and BTX (up to 12% C) were obtained via methane pyrolysis of fir wood; a free-radical mechanism is proposed to explain the enhanced yield of ethylene in a methane atmosphere.

  6. CX-009107: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Xylene Measurement for Saltstone Antifoams CX(s) Applied: B3.6 Date: 08/27/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office

  7. Method for making thin polypropylene film

    DOE Patents [OSTI]

    Behymer, R.D.; Scholten, J.A.

    1985-11-21

    An economical method is provided for making uniform thickness polypropylene film as thin as 100 Angstroms. A solution of polypropylene dissolved in xylene is formed by mixing granular polypropylene and xylene together in a flask at an elevated temperature. A substrate, such as a glass plate or microscope slide is immersed in the solution. When the glass plate is withdrawn from the solution at a uniform rate, a thin polypropylene film forms on a flat surface area of the glass plate as the result of xylene evaporation. The actual thickness of the polypropylene film is functional of the polypropylene in xylene solution concentration, and the particular withdrawal rate of the glass plate from the solution. After formation, the thin polypropylene film is floated from the glass plate onto the surface of water, from which it is picked up with a wire hoop.

  8. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    The relationship between the turnover number of the catalyst and the reaction time was obtained. Other aromatic compounds such as toluene, n-butylbenzene, tetralin, o-xylene all ...

  9. University of Delaware | CCEI Patents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Patents and Patent Applications Production of Para-xylene by Catalytically Reacting 2,5-Dimethylfuran and Ethylene in a Solvent Dauenhauer, P. J.; Williams, C. L.; Vlachos, D. G.; ...

  10. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lewis acid zeolites (Zr-, Sn- and Ti-BEA) were developed for tandem Diels-Alder cycloaddition and dehydration of 2,5-dimethylfuran (DMF) and ethylene to p-xylene achieving the highest selectivity of 80% at 99% conversion of DMF, with improved recalcitrance to deactivation. Lewis Acid Zeolites for Production of Biorenewable p-xylene Work performed in CCEI at the Universities of Massachusetts, Minnesota and Pennsylvania CATALYSIS CENTER FOR ENERGY INNOVATION - http://www.efrc.udel.edu/ Research

  11. DOE Tour of Zero: Reclaimed Modern by Dwell Development | Department...

    Energy Savers [EERE]

    a fluid-applied asphalt weather-resistant barrier that was also used for window flashing. ... house, serving as a continuous drainage plane and flashing for window and door openings

  12. CX-009091: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Montrose Operations Center Asphalt Overlay Project CX(s) Applied: B1.3 Date: 07/30/2012 Location(s): Colorado Offices(s): Western Area Power Administration-Rocky Mountain Region

  13. DOE Tour of Zero: The Vista Palm Drive by Southeast Volusia Habitat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    single-story structure, hip-roof design, and bottom course of asphalt shingles are tar glued as well as nailed to the CDX plywood sheathing to make for a wind- and...

  14. Task

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Noise exposure d) Application of cold coal tar coating to asphalt * Dermal contact ... up of high concentrations of carbon monoxide gas CO andor other by-products of combustion. ...

  15. CX-012613: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Repair/Reseals Concrete and Asphalt Covers at R- Reactor Seepage Basin CX(s) Applied: B1.3Date: 41801 Location(s): South CarolinaOffices(s): Savannah River Operations Office

  16. Bioadhesive Alliance

    Broader source: Energy.gov [DOE]

    Bioadhesive Alliance Inc. is a developer and manufacturer of “PiGrid”, bio-based adhesive that is green, low cost, and durable and can be utilized as a substitute to petroleum-based asphalt binder.

  17. Final Report Northeast Site Area B NAPL Remediation Project

    Office of Legacy Management (LM)

    ... In order to seal the "gap" between the edge of asphalt and top of the geomembrane, a 1-inch thick cement- slurry "plug" was placed on top of the membrane. 2.4.4 Abandonment After ...

  18. Green Button Applications | OpenEI Community

    Open Energy Info (EERE)

    Gazette We have the right of way when the light is green and we have the green turn signal VDOT needs to paint yellow stripes on the asphalt on either .... Press the menu...

  19. Fact #763: January 21, 2013 Eighty-four Percent of Scrapped Tires...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ground rubber, which is used for sports surfacing, asphalt, playgrounds, and other molded ... U.S. Scrap Tire Uses, 2009 Market Tons (Thousands) Tire-derived Fuel 2,084.8 Ground Rubber ...

  20. CX-008904: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Asphalt Sealing of Parking Areas and Roadways at National Energy Technology Laboratory, Pittsburgh CX(s) Applied: B1.3 Date: 08/29/2012 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory

  1. Microsoft Word - DOE-ID-INL-16-012.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Approximately 30,000 sq. ft. of asphalt will be removed, the existing road base will be ... Field Representative and the Cultural Resource Management Office as soon as possible. ...

  2. Microsoft Word - DOE-ID-INL-16-012 R1.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Approximately 150,000 sq. ft. of asphalt will be removed, the road base will be re-graded to ... Field Representative and the Cultural Resource Management Office as soon as possible. ...

  3. CX-007772: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Idaho National Laboratory Asphalt Repair Project - North Wind Services, LLC CX(s) Applied: B1.3 Date: 11/28/2011 Location(s): Idaho Offices(s): Nuclear Energy, Idaho Operations Office

  4. U.S. Total Shell Storage Capacity at Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Greater than 500 ppm Sulfur 16,847 -- -- -- -- -- 2004-2015 Residual Fuel Oil 26,815 -- -- -- -- -- 1982-2015 Lubricants 15,024 -- -- -- -- -- 1982-2015 Asphalt and Road Oil 26,932 ...

  5. U.S. Working Storage Capacity at Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Greater than 500 ppm Sulfur 15,284 -- -- -- -- -- 2004-2015 Residual Fuel Oil 22,769 -- -- -- -- -- 1982-2015 Lubricants 13,858 -- -- -- -- -- 1982-2015 Asphalt and Road Oil 24,515 ...

  6. ,"U.S. Production Capacity of Operable Petroleum Refineries"

    U.S. Energy Information Administration (EIA) Indexed Site

    Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Aromatics Production Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Asphalt and Road Oil ...

  7. Site-specific variability in BTEX biodegradation under denitrifying conditions

    SciTech Connect (OSTI)

    Kao, C.M.; Borden, R.C.

    1997-03-01

    Laboratory microcosm experiments were conducted to evaluate the feasibility of benzene, toluene, ethylbenzene, m-xylene, and o-xylene (BTEX) biodegradation under denitrifying conditions. Nine different sources of inocula, including contaminated and uncontaminated soil cores from four different sites and activated sludge, were used to establish microcosms. BTEX was not degraded under denitrifying conditions in microcosms inoculated with aquifer material from Rocky Point and Traverse City. However, rapid depletion of glucose under denitrifying conditions was observed in microcosms containing Rocky Point aquifer material. TEX degradation was observed in microcosms containing Rocky Point aquifer material. TEX degradation was observed in microcosms containing aquifer material from Fort Bragg and Sleeping Bear Dunes and sewage sludge. Benzene was recalcitrant in all microcosms tested. The degradation of o-xylene ceased after toluene, ethylbenzene, and m-xylene were depleted in the Fort Bragg and sludge microcosms, but o-xylene continued to degrade in microcosms with contaminated Sleeping Bear Dunes soil. The most probable number (MPN) of denitrifiers in these nine different inocula were measured using a microtiter technique. There was no correlation between the MPN of denitrifiers and the TEX degradation rate under denitrifying conditions. Experimental results indicate that the degradation sequence and TEX degradation rate under denitrifying conditions may differ among sites. Results also indicate that denitrification alone may not be a suitable bioremediation technology for gasoline-contaminated aquifers because of the inability of denitrifiers to degrade benzene.

  8. Flash hydropyrolysis of coal. Quarterly report No. 11, October 1-December 31, 1979

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.; Bhatt, B.L.

    1980-02-01

    The following conclusions can be drawn from this work: (1) when the caking bituminous coals are used with diluents, only 20% Pittsburgh No. 8 coal can be added to the diluent swhile 40% Illinois No. 6 could be added due to the higher free swelling index of the Pittsburgh No. 8; (2) When limestone is used as a diluent, considerably more sulfur is retained in the char than when using sand; (3) when the char from an experiment using limestone is recycled as the diluent for another experiment, the char continually retains additional sulfur through at least three recycles; (4) decomposition of the limestone and reduction is indicated by the high concentrations of CO observed at 900/sup 0/C; (5) increasing the coal feed rate by a factor of 4 from 2.4 to 10.7 lb/hr at low H/sub 2//Coal ratios (approx. = 0.6) results in no appreciable change in gaseous HC yields (approx. = 27%) or concentration (approx. = 45%) but higher BTX yields (1.1% vs. 5.4%); (6) although only one experiment was conducted, it appears that hydrogasification of untreated New Mexico sub-bituminous coal at 950/sup 0/C does not give an increase in yield over hydrogasification at 900/sup 0/C; (7) the hydrogasification of Wyodak lignite gives approximately the same gaseous HC yields as that obtained from North Dakota lignite but higher BTX yields particularly at 900/sup 0/C and 1000 psi (9% vs. 2%); (8) treating New Mexico sub-bituminous coal with NaCO/sub 3/ does not increase its hydrogasification qualities between 600/sup 0/C and 900/sup 0/C at 1000 psi but does decrease the BTX yield.

  9. Solubilities and other physical parameters of aromatic hydrocarbons in water and aqueous sodium chloride solutions as determined by headspace analysis

    SciTech Connect (OSTI)

    Lowry, M.A.H.

    1991-12-31

    The solubility, Henry`s law constant, aqueous-vapor partition coefficients, and oil-aqueous distribution coefficients of benzene, toluene, ethylbenzene, o-xylene,m-xylene and p-xylene were determined in water and aqueous sodium chloride solutions at 25C. Values are in agreement with using gas chromatography of headspace literature. The salting-out effect of sodium chloride on the solute properties measured was illustrated using the empirical relationship deduced by Setschenow (1889). The empirical relationship predicts that the logarithm of solubility will be a function of ionic strength. The solubility data obtained in this work obeys this relationship. It was also found that the logarithm of the Henry`s law constant, partition coefficient, and distribution coefficient are linear functions of ionic strength. 10 tabs, 6 figs.

  10. Market and environmental protection forces threaten smooth transition to heavy crude: race against time

    SciTech Connect (OSTI)

    Not Available

    1986-05-28

    Two constructive forces are laying the foundation for a destructive situation: (1) lower oil prices for now-abundant conventional crude have shrunk the light-heavy oil price differential to destroy the incentive to invest in refinery upgrading with deep conversion facilities, while (2) the powerful movement to environmental protection will require massive investments by refiners for compliance with emerging regulations. It is the process technology sector that is left holding the bag, as this issue, continuing coverage of two refining meetings, shows. This issue also includes: (1) ED asphalt export prices to USA (1986 to date); (2) ED US posted asphalt price series, May 1986; and (3) US asphalt imports by country of origin, Jan., Feb., March, 1986. The ED Refining Netback Data Series is being reformatted and does not appear in this issue. Neither does the Fuel Price/Tax Series appear, but the Western and Eastern hemisphere formats are being updated and will appear alternately in future issues.

  11. Process for upgrading heavy oils

    SciTech Connect (OSTI)

    LePage, J.F.; Marlino, G.

    1983-07-05

    The viscosity of heavy oils is reduced in order to facilitate pipe line transportation thereof. A fraction of the heavy oil is deasphalted in the presence of C/sub 5/-C/sub 7/ hydrocarbons, a portion of the separated asphalt is converted to synthesis gas, at least a portion of said gas is used to manufacture an alcohol mixture including methanol and C/sub 2/ to C/sub 10/ alcohols, which mixture is admixed with the heavy oil before transportation thereof. This procedure is more beneficial to the transported heavy oil than the prior processes which do not comprise the conversion of the asphalt fraction of the heavy oil.

  12. Materials that Improve the Cost-Effectiveness of Air Barrier Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Materials that Improve the Cost-Effectiveness of Air Barrier Systems Materials that Improve the Cost-Effectiveness of Air Barrier Systems 1 of 3 3M has developed a primer-less self-adhered membrane that serves as an air, liquid water, and water vapor barrier. This technology installs in up to half the time of asphalt-based membranes, which will lead to installed costs that are similar or lower than that of asphalt-based membranes. Image: 3M 2 of 3 3M has developed a

  13. Biocatalytic conversion of ethylene to ethylene oxide using an engineered toluene monooxygenase

    SciTech Connect (OSTI)

    Carlin, DA; Bertolani, SJ; Siegel, JB

    2015-01-01

    Mutants of toluene o-xylene monooxygenase are demonstrated to oxidize ethylene to ethylene oxide in vivo at yields of >99%. The best mutant increases ethylene oxidation activity by >5500-fold relative to the native enzyme. This is the first report of a recombinant enzyme capable of carrying out this industrially significant chemical conversion.

  14. PRODUCTION OF SLIP CAST CALCIA HOLLOWWARE

    DOE Patents [OSTI]

    Stoddard, S.D.; Nuckolls, D.E.; Cowan, R.E.

    1963-12-31

    A method for producing slip cast calcia hollow ware in which a dense calcia grain is suspended in isobutyl acetate or a mixture of tertiary amyl alcohol and o-xylene is presented. A minor amount of triethanolamine and oleic acid is added to the suspension vehicle as viscosity adjusting agents and the suspension is cast in a plaster mold, dried, and fired. (AEC)

  15. Density and viscosity for mixtures of propanoic acid with aromatic hydrocarbons at 298.15 K

    SciTech Connect (OSTI)

    Singh, M.; Gupta, P.C.; Kesharwani, R.N.

    1995-03-01

    The density and viscosity of binary mixtures of propanic acid + benzene, + toluene, and + o-, + m-, and + p-xylenes have been measured at 298.15 K. Excess volumes have been calculated. The interactions existing between the components have been discussed. The results are used to theoretically justify the validity of the viscosity models.

  16. A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications

    SciTech Connect (OSTI)

    Pei, Yuanjiang; Mehl, Marco; Liu, Wei; Lu, Tianfeng; Pitz, William J.; Som, Sibendu

    2015-05-12

    A mixture of n-dodecane and m-xylene is investigated as a diesel fuel surrogate for compression ignition engine applications. Compared to neat n-dodecane, this binary mixture is more representative of diesel fuel because it contains an alkyl-benzene which represents an important chemical class present in diesel fuels. A detailed multi-component mechanism for n-dodecane and m-xylene was developed by combining a previously developed n-dodecane mechanism with a recently developed mechanism for xylenes. The xylene mechanism is shown to reproduce experimental ignition data from a rapid compression machine and shock tube, speciation data from the jet stirred reactor and flame speed data. This combined mechanism was validated by comparing predictions from the model with experimental data for ignition in shock tubes and for reactivity in a flow reactor. The combined mechanism, consisting of 2885 species and 11754 reactions, was reduced to a skeletal mechanism consisting 163 species and 887 reactions for 3D diesel engine simulations. The mechanism reduction was performed using directed relation graph (DRG) with expert knowledge (DRG-X) and DRG-aided sensitivity analysis (DRGASA) at a fixed fuel composition of 77% of n-dodecane and 23% m-xylene by volume. The sample space for the reduction covered pressure of 1 – 80 bar, equivalence ratio of 0.5 – 2.0, and initial temperature of 700 – 1600 K for ignition. The skeletal mechanism was compared with the detailed mechanism for ignition and flow reactor predictions. Finally, the skeletal mechanism was validated against a spray flame dataset under diesel engine conditions documented on the Engine Combustion Network (ECN) website. These multi-dimensional simulations were performed using a Representative Interactive Flame (RIF) turbulent combustion model. Encouraging results were obtained compared to the experiments with regards to the predictions of ignition delay and lift-off length at different ambient temperatures.

  17. Characterization of a combined release of LNAPLs and DNAPLs

    SciTech Connect (OSTI)

    Holt, W. )

    1993-10-01

    The subject of this investigation concerns a large quantity, subsurface release of an asphalt paint. The asphalt paint consisted of a mixture of asphalt (cut-back) and a commercial solvent that is 1,1,1-trichloroethane (TCA) based. The TCA appeared in the aquifer as a dense, nonaqueous phase liquid (DNAPL), and the balance of the material in the asphalt paint mixture appeared as light, nonaqueous phase liquids (LNAPLs). The site is located within a manufacturing facility which has been in operation since the late 1900s. There has been extensive development at the site, with attendant renovations and demolition of prior structures and placement of fill material, which has changed the natural surface soil conditions and complicated the local ground-water flow patterns. The complexity of the geology and hydrogeology of the site as well as the extent of the contaminant plume migration further complicated the site investigation. The investigation consisted of several elements: (A) Soil/Gas/Vapor Survey; (B) Surface-Water Sampling; (C) Deep and Shallow Cluster Drilling, Ground-Water Monitoring Well Installation, and Sampling; and (D) Ground-Water Flow and Transport Modeling.

  18. Conversion of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Chen, N.Y.; Pelrine, B.P.; Yan, T.Y.

    1982-12-14

    This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products. The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

  19. Lignite pellets and methods of agglomerating or pelletizing

    DOE Patents [OSTI]

    Baker, Albert F.; Blaustein, Eric W.; Deurbrouck, Albert W.; Garvin, John P.; McKeever, Robert E.

    1981-01-01

    The specification discloses lignite pellets which are relatively hard, dust resistant, of generally uniform size and free from spontaneous ignition and general degradation. Also disclosed are methods for making such pellets which involve crushing as mined lignite, mixing said lignite with a binder such as asphalt, forming the lignite binder mixture into pellets, and drying the pellets.

  20. Short-Term Energy Outlook Model Documentation: Other Petroleum Products Consumption Model

    Reports and Publications (EIA)

    2011-01-01

    The other petroleum product consumption module of the Short-Term Energy Outlook (STEO) model is designed to provide U.S. consumption forecasts for 6 petroleum product categories: asphalt and road oil, petrochemical feedstocks, petroleum coke, refinery still gas, unfinished oils, and other miscvellaneous products

  1. recycling

    National Nuclear Security Administration (NNSA)

    6%2A en Y-12's rough roads smoothed over with 23,000 tons of recycled asphalt http:nnsa.energy.govblogy%E2%80%9112%E2%80%99s-rough-roads-smoothed-over-23000-tons-recycled-asph...

  2. Recycle plastics into feedstocks

    SciTech Connect (OSTI)

    Kastner, H.; Kaminsky, W.

    1995-05-01

    Thermal cracking of mixed-plastics wastes with a fluidized-bed reactor can be a viable and cost-effective means to meet mandatory recycling laws. Strict worldwide environmental statutes require the hydrocarbon processing industry (HPI) to develop and implement product applications and technologies that reuse post-consumer mixed-plastics waste. Recycling or reuse of plastics waste has a broad definition. Recycling entails more than mechanical regranulation and remelting of polymers for film and molding applications. A European consortium of academia and refiners have investigated if it is possible and profitable to thermally crack plastics into feedstocks for refining and petrochemical applications. Development and demonstration of pyrolysis methods show promising possibilities of converting landfill garbage into valuable feedstocks such as ethylene, propylene, BTX, etc. Fluidized-bed reactor technologies offer HPI operators a possible avenue to meet recycling laws, conserve raw materials and yield a profit. The paper describes thermal cracking for feedstocks and pyrolysis of polyolefins.

  3. Ecological Interactions Between Metals and Microbes

    SciTech Connect (OSTI)

    Konopka, Allan E.

    2004-06-01

    Analyses of chromium resistant microbes. Culturable xylene-degrading and chromate-resistant microbes were obtained from chronically cocontaminated soil using a microcosm enrichment technique, and shown to correlate to dominant soil populations using culture independent techniques. The soil microbial community proved able to mount a respiratory response to addition of xylene in the presence of chromate. The majority of isolates belonged to the ubiquitous but poorly studied high %G+C Gram positive genus Arthrobacter, and exhibited considerable genotypic and phenotypic variability. Phenotypic assays uncovered a wide variation in the levels of chromate resistance, even between very closely related strains. Primers designed against conserved motifs in the known chrA chromate efflux gene failed to detect similar sequences among the chromate resistant Arthrobacter isolates obtained through enrichment.

  4. Variations in the structure of aromatic solvents under the influence of microadditives of the C{sub 60} fullerene

    SciTech Connect (OSTI)

    Ginzburg, B. M. Tuichiev, Sh.

    2007-02-15

    The structural ordering of aromatic solvents is investigated using wide-angle X-ray diffraction. It is shown that the degree of structural ordering of aromatic solvents at room temperature decreases in the following sequence: benzene, toluene, and n-xylene. The introduction of the C{sub 60} fullerene ({approx}0.001%) into these solvents leads to an increase in the degree of their ordering. Upon introduction of the fullerene, the degree of structural ordering increases significantly in n-xylene and only slightly in toluene and remains virtually unchanged in benzene. An analysis of the small-angle X-ray diffraction patterns of C{sub 60} fullerene solutions in benzene likewise demonstrates that the introduction of the fullerene into benzene leads to an insignificant change in the degree of structural ordering of this solvent. The specific features of the structure and behavior of benzene upon interaction with C{sub 60} fullerene additives are discussed.

  5. Process for hydrocracking carbonaceous material to provide fuels or chemical feed stock

    DOE Patents [OSTI]

    Duncan, Dennis A.

    1980-01-01

    A process is disclosed for hydrocracking coal or other carbonaceous material to produce various aromatic hydrocarbons including benzene, toluene, xylene, ethylbenzene, phenol and cresols in variable relative concentrations while maintaining a near constant maximum temperature. Variations in relative aromatic concentrations are achieved by changing the kinetic severity of the hydrocracking reaction by altering the temperature profile up to and quenching from the final hydrocracking temperature. The relative concentration of benzene to the alkyl and hydroxyl aromatics is increased by imposing increased kinetic severity above that corresponding to constant heating rate followed by immediate quenching at about the same rate to below the temperature at which dehydroxylation and dealkylation reactions appreciably occur. Similarly phenols, cresols and xylenes are produced in enhanced concentrations by adjusting the temperature profile to provide a reduced kinetic severity relative to that employed when high benzene concentrations are desired. These variations in concentrations can be used to produce desired materials for chemical feed stocks or for fuels.

  6. Analysis of low molecular weight hydrocarbons including 1,3-butadiene in engine exhaust gases using an aluminum oxide porous-layer open-tubular fused-silica column

    SciTech Connect (OSTI)

    Pelz, N.; Dempster, N.M.; Shore, P.R. )

    1990-05-01

    A method for the quantitative analysis of individual hydrocarbons in the C1-C8 range emitted in engine exhaust gases is described. The procedure provides base-line or near base-line resolution of C4 components including 1,3-butadiene. With a run time of less than 50 min, the light aromatics (benzene, toluene, ethyl benzene, p- and m-xylene, and o-xylene) are resolved during the same analysis as aliphatic hydrocarbons in the C1-C8 range. It is shown that typical 1,3-butadiene levels in engine exhaust are about 5 ppm at each of two engine conditions. Aromatic hydrocarbon levels show a dependence on engine operating conditions, benzene being about 20 ppm at high speed and about 40 ppm at idle.

  7. Crosslinked Polybenzimidazole Membrane For Gas Separation

    DOE Patents [OSTI]

    Jorgensen, Betty S.; Young, Jennifer S.; Espinoza, Brent F.

    2005-09-20

    A cross-linked, supported polybenzimidazole membrane for gas separation is prepared by layering a solution of polybenzimidazole (PBI) and a,a'dibromo-p-xylene onto a porous support and evaporating solvent. A supported membrane of cross-linked poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole unexpectedly exhibits an enhanced gas permeability compared to the non-cross linked analog at temperatures over 265° C.

  8. Crosslinked Polybenzimidazole Membrane For Gas Separation

    DOE Patents [OSTI]

    Jorgensen, Betty S. (Jemez Springs, NM); Young, Jennifer S. (Los Alamos, NM); Espinoza, Brent F. (Los Alamos, NM)

    2005-09-20

    A cross-linked, supported polybenzimidazole membrane for gas separation is prepared by layering a solution of polybenzimidazole (PBI) and a,a'dibromo-p-xylene onto a porous support and evaporating solvent. A supported membrane of cross-linked poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole unexpectedly exhibits an enhanced gas permeability compared to the non-cross linked analog at temperatures over 265 C.

  9. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MOFs can tune the critical point of gases Scientific Achievement Molecular simulations and NMR relaxometry experiments demonstrate that pure benzene or xylene confined in isoreticular metal-organic frameworks (IRMOFs) exhibit vapor-liquid phase equilibria where the critical point may be reduced by tuning the structure of the MOF. Significance and Impact The potential for tuning the critical point of a pure fluid necessitates revisiting pure and multicomponent phase behavior in nanoporous

  10. DOE - Office of Legacy Management -- Hooker Chemical Co - NY 05

    Office of Legacy Management (LM)

    Hooker Chemical Co - NY 05 FUSRAP Considered Sites Site: Hooker Chemical Co. (NY.05) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Occidental Chemical Corporation Hooker Electrochemical Corporation NY.05-1 NY.05-2 Location: Niagara Falls , New York NY.05-3 Evaluation Year: 1985 NY.05-1 NY.05-2 Site Operations: Design, engineering, construction, equipping and operation of a plant for the manufacture of Product 45 (xylene hexachloride); MFL (Miller's

  11. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Processing Area Definitions Key Terms Definition Aviation Gasoline Blending Components Naphthas which will be used for blending or compounding into finished aviation gasoline (e.g., straight-run gasoline, alkylate, reformate, benzene, toluene, and xylene). Excludes oxygenates (alcohols, ethers), butane, and pentanes plus. Oxygenates are reported as other hydrocarbons, hydrogen, and oxygenates. Barrel A unit of volume equal to 42 U.S. gallons. Conventional Blendstock for Oxygenate Blending (CBOB)

  12. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Imports & Exports Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether),

  13. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Input Definitions Key Terms Definition Aviation Gasoline Blending Components Naphthas which will be used for blending or compounding into finished aviation gasoline (e.g., straight-run gasoline, alkylate, reformate, benzene, toluene, and xylene). Excludes oxygenates (alcohols, ethers), butane, and pentanes plus. Oxygenates are reported as other hydrocarbons, hydrogen, and oxygenates. Barrel A unit of volume equal to 42 U.S. gallons. Conventional Blendstock for Oxygenate Blending (CBOB) Motor

  14. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    and Blender Net Inputs Definitions Key Terms Definition Aviation Gasoline Blending Components Naphthas which will be used for blending or compounding into finished aviation gasoline (e.g., straight-run gasoline, alkylate, reformate, benzene, toluene, and xylene). Excludes oxygenates (alcohols, ethers), butane, and pentanes plus. Oxygenates are reported as other hydrocarbons, hydrogen, and oxygenates. Barrel A unit of volume equal to 42 U.S. gallons. Blending Plant A facility which has no

  15. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Inputs & Utilization Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether),

  16. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Total Stocks Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and

  17. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Weekly Supply Estimates Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether),

  18. Studies of thin films and surfaces with optical harmonic generation and electron spectroscopy

    SciTech Connect (OSTI)

    Wilk, D.E.

    1996-01-01

    Optical second harmonic generation (SHG) and sum frequency generation (SFG) were used to study C{sup 60} thin solid films (low energy ED forbidden electronic excitations), and electron spectroscopy was used to study organic overlayers (xylenes) on Pt(111). Theory of SHG from a thin film is described in terms of surface and bulk contributions as well as local and nonlocal contributions to the optical nonlinearities. (1)In situ SHG data on C{sub 60} films during UHV film growth can be described in terms of only nonlocal contributions to both surface and bulk nonlinear susceptibilities. Microscopic origin of SHG response is discussed in terms of electric quadrupole and ED transitions of C{sub 60}. (2)Adsorption and thermal decomposition of ortho- and para-xylene on Pt(111) is studied using HREELS, LEED, AES, and thermal desorption spectroscopy. We have observed preferential decomposition of the methyl groups which leads to distinct decomposition pathways for ortho- and para-xylene on Pt(111).

  19. Grounding electrode and method of reducing the electrical resistance of soils

    DOE Patents [OSTI]

    Koehmstedt, Paul L.

    1980-01-01

    A first solution of an electrolyte is injected underground into a volume of soil having negative surface charges on its particles. A cationic surfactant suspended in this solution neutralizes these surface charges of the soil particles within the volume. Following the first solution, a cationic asphalt emulsion suspended in a second solution is injected into the volume. The asphalt emulsion diffuses through the volume and electrostatically bonds with additional soil surrounding the volume such that an electrically conductive water repellant shell enclosing the volume is formed. This shell prevents the leaching of electrolyte from the volume into the additional soil. The second solution also contains a dissolved deliquescent salt which draws water into the volume prior to the formation of the shell. When electrically connected to an electrical installation such as a power line tower, the volume constitutes a grounding electrode for the tower.

  20. Use of bioassays in assessing health hazards from complex mixtures: A RASH analysis

    SciTech Connect (OSTI)

    Jones, T.D.

    1993-10-14

    The Finney harmonic mean model for joint toxicity of ingredients in mixtures can be used to estimate the toxicity of the neat compound if one component can be substituted in potency-adjusted-doses for each of the other components. Chemical analysis data and relative potency values (computed according to the Rapid Screening of Hazard (RASH) method) were used to compare the toxicities as predicted from ingredients of cigarette smoke, PAHs in diesel exhaust, asphalt, coal tar, pitch, and creosote with the measured toxicities of the neat mixtures. Accuracy for cigarette smoke condensate, coal tar, pitch, and creosote were within a factor of three; asphalt within a factor of 18; but the PAC content of diesel particulate was inadequate to accurately describe the toxicity of diesel emissions.

  1. Cost of radon-barrier systems for uranium mill tailings

    SciTech Connect (OSTI)

    Baker, E.G.; Hartley, J.N.

    1982-08-01

    This report deals specifically with the cost of three types of radon barrier systems, earthen covers, asphalt emulsion covers, and multilayer covers, which could meet standards proposed by the Environmental Protection Agency to stabilize uranium mill tailings located primarily in the western US. In addition, the report includes a sensitivity analysis of various factors which significantly effect the overall cost of the three systems. These analyses were based on a generic disposal site. Four different 3m thick earthen covers were tested and cost an average of $27/m/sup 2/. The least expensive earthen cover cost was about $21/m/sup 2/. The asphalt cover system (6 to 7 cm of asphalt topped with 0.6m of overburden) cost about $28/m/sup 2/. The four multilayer covers averaged $57/m/sup 2/, but materials handling problems encountered during the test inflated this cost above what was anticipated and significant cost reductions should be possible. The least expensive multilayer cover cost $43/m/sup 2/. Based on the results of the Grand Junction field test we estimated the cost of covering the tailings from three high priority sites, Durango, Shiprock, and Salt Lake City (Vitro). The cost of a 3m earthen cover ranged from $18 to 33/m/sup 2/ for the seven disposal sites (two or three at each location) studied. The cost of asphalt cover systems were $23 to 28/m/sup 2/ and the multilayer cover costs were between $31 to 36/m/sup 2/. The earthen cover costs are less than the Grand Junction field test cost primarily because cover material is available at or near most of the disposal sites selected. Earthen material was imported from 6 to 10 miles for the field test. Assuming more efficienct utilization of materials significantly reduced the cost of the multilayer covers.

  2. Geothermal Energy Retrofit

    SciTech Connect (OSTI)

    Bachman, Gary

    2015-07-28

    The Cleary University Geothermal Energy Retrofit project involved: 1. A thermal conductivity test; 2. Assessment of alternative horizontal and vertical ground heat exchanger options; 3. System design; 4. Asphalt was stripped from adjacent parking areas and a vertical geothermal ground heat exchanger system installed; 5. the ground heat exchanger was connected to building; 6. a system including 18 heat pumps, control systems, a manifold and pumps, piping for fluid transfer and ductwork for conditioned air were installed throughout the building.

  3. Utilization of ash from municipal solid waste combustion

    SciTech Connect (OSTI)

    Jones, C.; Hahn, J.; Magee, B.; Yuen, N.; Sandefur, K.; Tom, J.; Yap, C.

    1999-09-01

    This ash study investigated the beneficial use of municipal waste combustion combined ash from the H-POWER facility in Oahu. These uses were grouped into intermediate cover for final closure of the Waipahu landfill, daily cover at the Waimanalo Gulch Landfill, and partial replacement for aggregate in asphalt for road paving. All proposed uses examine combined fly and bottom ash from a modern waste-to-energy facility that meets requirements of the Clean Air Act Amendments for Maximum Achievable Control Technology.

  4. Word Pro - A

    U.S. Energy Information Administration (EIA) Indexed Site

    Thermal Conversion Factor Source Documentation Approximate Heat Content of Petro- leum and Natural Gas Plant Liquids Asphalt. The U.S. Energy Information Administration (EIA) adopted the thermal conversion factor of 6.636 million British thermal units (Btu) per barrel as estimated by the Bureau of Mines and first published in the Petro- leum Statement, Annual, 1956. Aviation Gasoline Blending Components. Assumed by EIA to be 5.048 million Btu per barrel or equal to the thermal conversion factor

  5. U.S. Energy Information Administration | State Energy Data 2014: Prices and Expenditures

    Gasoline and Diesel Fuel Update (EIA)

    1 Petroleum Overview The 25 petroleum products included in the State Energy Data System (SEDS) are explained in this section. For 10 of these products, the method of estimating their prices by state is described in individual sections. The 10 petroleum products are: * Asphalt and road oil (AR) * Aviation gasoline (AV) * Distillate fuel oil (DF) * Jet fuel (JF) * Kerosene (KS) * Liquefied petroleum gases (LG) * Lubricants (LU) * Motor gasoline (MG) * Petroleum coke (PC) * Residual fuel oil (RF)

  6. Word Pro - Untitled1

    U.S. Energy Information Administration (EIA) Indexed Site

    Approximate Heat Content of Petroleum and Natural Gas Plant Liquids Asphalt. The U.S. Energy Information Administration (EIA) adopted the thermal conversion factor of 6.636 million British thermal units (Btu) per barrel as estimated by the Bureau of Mines and first published in the Petroleum Statement, Annual, 1956. Aviation Gasoline. EIA adopted the thermal conversion factor of 5.048 million Btu per barrel as adopted by the Bureau of Mines from the Texas Eastern Transmission Corporation

  7. Accelerated Aging of Roofing Materials - 2013 BTO Peer Review | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Accelerated Aging of Roofing Materials - 2013 BTO Peer Review Accelerated Aging of Roofing Materials - 2013 BTO Peer Review Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review emrgtech24_destaillats_040413.pdf (1.02 MB) More Documents & Publications Accelerated Aging of Roofing Materials Stay-Clean and Durable White Elastomeric Roof Coatings New Cool Roof Coatings and Affordable Cool Color Asphalt

  8. U.S. Refineries Competitive Positions

    U.S. Energy Information Administration (EIA) Indexed Site

    Refineries Competitive Positions 2014 EIA Energy Conference July 14, 2014 Joanne Shore American Fuel & Petrochemical Manufacturers Refiners competitive positions Function of optimizing feedstock costs, operating costs, and revenues through mix of products sold 2 Propane/butane Chemicals Gasoline Jet Fuel Diesel/heating oil Lubes Fuel for ships Asphalt FEEDSTOCKS Qualities: - Heavy/Light - Sweet/Sour Location (Distance) - Domestic - International PROCESSING Size Complexity Treating (sulfur)

  9. Buildings Energy Data Book: 1.4 Environmental Data

    Buildings Energy Data Book [EERE]

    5 Disposal and Recovery of Construction and Demolition (C&D) Materials in 2003 Reporting State (2) (1) (3) Florida 27% Maryland 54% Massachusetts 82% New Jersey 79% North Carolina 1% Utah 4% Virginia 3% Washington 60% Total 48% Note(s): Source(s): 1) Only eight states reported recovery and disposal amounts 2003, representing approximately 21% of the US population. 2) State definitions vary regarding what constitutes C&D materials. Some states may include concrete, asphalt pavement, and

  10. Techniques and Technologies for Field Detection of Asbestos Containing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials | Department of Energy Techniques and Technologies for Field Detection of Asbestos Containing Materials Techniques and Technologies for Field Detection of Asbestos Containing Materials Asbestos has been used in numerous applications at DOE sites including sprayed-on fireproofing, asphalt and vinyl floor tile, and asbestos-cement (transite) siding. Techniques and Technologies for Field Detection of Asbestos Containing Materials (290.26 KB) More Documents & Publications Chemical

  11. Refinery Yield of Liquefied Refinery Gases

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Liquefied Refinery Gases Finished Motor Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Residual Fuel Oil Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Still Gas Miscellaneous Products Processing Gain(-) or Loss(+) Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources

  12. Petroleum Refining Sector (NAICS 324110) Energy and GHG Combustion Emissions Profile, November 2012

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    69 2.4 PETROLEUM REFINING SECTOR (NAICS 324110) 2.4.1. Overview of the Petroleum Refining Manufacturing Sector Petroleum refining is a complex industry that generates a diverse slate of fuel products and petrochemicals, from gasoline to asphalt. Refining requires a range of processing steps, including distillation, cracking, reforming, and treating. Most of these processes are highly reliant on process heating and steam energy. Petroleum refineries are an essential part of the U.S. economy.

  13. Microsoft PowerPoint - 300 Area Perspective.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area Perspective 300 Area Perspective River and Plateau Committee February 15, 2012 February 15, 2012 John B. Price Business/Research Park in N Richland h d l h High Density Residential is the norm MSA Bldg and Townhouses "Smartpark" includes Townhouses High Density Residential Infiltration from Impervious Areas & Irrigation Townhouses Grass Townhouse Townhouses Grass Bare Ground from Construction Storm Sewer Asphalt Grass Grate p Remediated 1100 Area -Industrial Area f h l ff

  14. U.S. States - SEDS - U.S. Energy Information Administration (EIA)

    Gasoline and Diesel Fuel Update (EIA)

    Refineries Competitive Positions 2014 EIA Energy Conference July 14, 2014 Joanne Shore American Fuel & Petrochemical Manufacturers Refiners competitive positions Function of optimizing feedstock costs, operating costs, and revenues through mix of products sold 2 Propane/butane Chemicals Gasoline Jet Fuel Diesel/heating oil Lubes Fuel for ships Asphalt FEEDSTOCKS Qualities: - Heavy/Light - Sweet/Sour Location (Distance) - Domestic - International PROCESSING Size Complexity Treating (sulfur)

  15. Construction Update Rattley Rd Closure | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Construction Update Rattley Rd Closure Lawrence Dr. Construction Update; Rattley Rd. Closure Heads up Reconfiguration of the Lawrence Drive entrance to Jefferson Lab is progressing toward completion of the base asphalt layer. This is scheduled for completion early in the week of June 13, 2016. The final pavement layer on the entire length of Lawrence Dr. will occur in late June or early July. The road will be opened to traffic after the base layer is completed to accommodate the imminent closure

  16. The Effects of Infrared-Blocking Pigments and Deck Venting on Stone-Coated Metal Residential Roofs

    SciTech Connect (OSTI)

    Miller, William A

    2006-01-01

    Field data show that stone-coated metal shakes and S-mission tile, which exploit the use of infraredblocking color pigments (IrBCPs), along with underside venting reduce the heat flow penetrating the conditioned space of a residence by 70% compared with the amount of heat flow penetrating roofs with conventional asphalt shingles. Stone-coated metal roof products are typically placed on battens and counter-battens and nailed through the battens to the roof deck. The design provides venting on the underside of the metal roof that reduces the heat flow penetrating a home. The Metal Construction Association (MCA) and its affiliate members installed stone-coated metal roofs with shake and S-mission tile profiles and a painted metal shake roof on a fully instrumented attic test assembly at Oak Ridge National Laboratory (ORNL). Measurements of roof, deck, attic, and ceiling temperatures; heat flows; solar reflectance; thermal emittance; and ambient weather were recorded for each of the test roofs and also for an adjacent attic cavity covered with a conventional pigmented and direct nailed asphalt shingle roof. All attic assemblies had ridge and soffit venting; the ridge was open to the underside of the stone-coated metal roofs. A control assembly with a conventional asphalt shingle roof was used for comparing deck and ceiling heat transfer rates.

  17. Steep-Slope Assembly Testing of Clay and Concrete Tile With and Without Cool Pigmented Colors

    SciTech Connect (OSTI)

    Miller, William A

    2005-11-01

    Cool color pigments and sub-tile venting of clay and concrete tile roofs significantly impact the heat flow crossing the roof deck of a steep-slope roof. Field measures for the tile roofs revealed a 70% drop in the peak heat flow crossing the deck as compared to a direct-nailed asphalt shingle roof. The Tile Roofing Institute (TRI) and its affiliate members are keenly interested in documenting the magnitude of the drop for obtaining solar reflectance credits with state and federal "cool roof" building efficiency standards. Tile roofs are direct-nailed or are attached to a deck with batten or batten and counter-batten construction. S-Misson clay and concrete tile roofs, a medium-profile concrete tile roof, and a flat slate tile roof were installed on fully nstrumented attic test assemblies. Temperature measures of the roof, deck, attic, and ceiling, heat flows, solar reflectance, thermal emittance, and the ambient weather were recorded for each of the tile roofs and also on an adjacent attic cavity covered with a conventional pigmented and directnailed asphalt shingle roof. ORNL measured the tile's underside temperature and the bulk air temperature and heat flows just underneath the tile for batten and counter-batten tile systems and compared the results to the conventional asphalt shingle.

  18. Charge Transfer Fluorescence and 34 nm Exciton Diffusion Length in Polymers with Electron Acceptor End Traps

    SciTech Connect (OSTI)

    Zaikowski, L.; Mauro, G.; Bird, M.; Karten, B.; Asaoka, S.; Wu, Q.; Cook, A. R.; Miller, J.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are as large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. The efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.

  19. Charge transfer fluorescence and 34 nm exciton diffusion length in polymers with electron acceptor end traps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zaikowski, Lori; Mauro, Gina; Bird, Matthew; Karten, Brianne; Asaoka, Sadayuki; Wu, Qin; Cook, Andrew R.; Miller, John R.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are asmore » large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. As a result, the efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.« less

  20. CASTING SLIPS FOR FABRICATION OF REFRACTORY METAL WARE

    DOE Patents [OSTI]

    Stoddard, S.D.; Nuckolls, D.E.; Cowan, R.E.

    1962-09-01

    A composition is given for slip casting tungsten metal. The composition consists essentially of tungsten metal with an average particle size of 0.9 micron, an organic vehicle such as methyl chloroform, o-xylene, n-butyl acetate, isobutyl acetate, and 1, 1, 2, 2-tetrachlorethane, and a suspending agent such as ethyl cellulose, with the approximate ratio of said vehicle to the tungsten metal being 12 cc of a solution containing from 5 to about 20 grams of said ethyl cellulose in 400 cc of said organic vehicle per 100 grams of metal. (AEC)

  1. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, D.S.

    1984-02-16

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  2. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, David S.; Yao, Neng-Ping

    1985-01-01

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  3. Superfund Record of Decision (EPA Region 2): Love Canal (93rd Street School), Niagara County, City of Niagara Falls, NY. (Third remedial action), (amendment), May 1991. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-05-15

    The Love Canal (93rd Street) site is an inactive hazardous waste site located in Niagara Falls, New York. The 19-acre 93rd Street School site, one of several operable units for the Love Canal Superfund site, is the focus of the Record of Decision (ROD). The fill material is reported to contain fly ash and BHC (a pesticide) waste. The ROD amends the 1988 ROD, and addresses final remediation of onsite contaminated soil through excavation and offsite disposal. The primary contaminants of concern affecting the soil are VOCs including toluene and xylenes; other organics including PAHs and pesticides; and metals including arsenic, chromium, and lead.

  4. Anaerobic biodegradation of BTEX in aquifer material. Environmental research brief

    SciTech Connect (OSTI)

    Borden, R.C.; Hunt, M.J.; Shafer, M.B.; Barlaz, M.A.

    1997-08-01

    Laboratory and field experiments were conducted in two petroleum-contaminated aquifers to examine the anaerobic biodegradation of benzene, toluene, ethylbenzene and xylene isomers (BTEX) under ambient conditions. Aquifer material was collected from locations at the source, mid-plume and end-plume at both sites, incubated under ambient conditions, and monitored for disappearance of the test compounds. In the mid-plume location at the second site, in-situ column experiments were also conducted for comparison with the laboratory microscosm and field-scale results. In the end-plume microcosms, biodegradation was variable with extensive biodegradation in some microcosms and little or no biodegradation in others.

  5. Zeolite catalysis: technology

    SciTech Connect (OSTI)

    Heinemann, H.

    1980-07-01

    Zeolites have been used as catalysts in industry since the early nineteen sixties. The great majority of commercial applications employ one of three zeolite types: zeolite Y; Mordenite; ZSM-5. By far the largest use of zeolites is in catalytic cracking, and to a lesser extent in hydrocracking. This paper reviews the rapid development of zeolite catalysis and its application in industries such as: the production of gasoline by catalytic cracking of petroleum; isomerization of C/sub 5/ and C/sub 6/ paraffin hydrocarbons; alkylation of aromatics with olefins; xylene isomerization; and conversion of methanol to gasoline.

  6. Characterizing a fast-response, low-afterglow liquid scintillator for neutron time-of-flight diagnostics in fast ignition experiments

    SciTech Connect (OSTI)

    Abe, Y. Hosoda, H.; Arikawa, Y.; Nagai, T.; Kojima, S.; Sakata, S.; Inoue, H.; Iwasa, Y.; Iwano, K.; Yamanoi, K.; Fujioka, S.; Nakai, M.; Sarukura, N.; Shiraga, H.; Norimatsu, T.; Azechi, H.

    2014-11-15

    The characteristics of oxygen-enriched liquid scintillators with very low afterglow are investigated and optimized for application to a single-hit neutron spectrometer for fast ignition experiments. It is found that 1,2,4-trimethylbenzene has better characteristics as a liquid scintillator solvent than the conventional solvent, p-xylene. In addition, a benzophenon-doped BBQ liquid scintillator is shown to demonstrate very rapid time response, and therefore has potential for further use in neutron diagnostics with fast time resolution.

  7. Long period grating refractive-index sensor: optimal design for single wavelength interrogation

    SciTech Connect (OSTI)

    Kapoor, Amita; Sharma, Enakshi K.

    2009-11-01

    We report the design criteria for the use of long period gratings (LPGs) as refractive-index sensors with output power at a single interrogating wavelength as the measurement parameter. The design gives maximum sensitivity in a given refractive-index range when the interrogating wavelength is fixed. Use of the design criteria is illustrated by the design of refractive-index sensors for specific application to refractive-index variation of a sugar solution with a concentration and detection of mole fraction of xylene in heptane (paraffin).

  8. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J.; Daniels, Edward J.; Bonsignore, Patrick V.

    2001-01-01

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  9. Testing a new NIF neutron time-of-flight detector with a bibenzyl scintillator on OMEGA

    SciTech Connect (OSTI)

    Glebov, V. Yu.; Forrest, C.; Knauer, J. P.; Pruyne, A.; Romanofsky, M.; Sangster, T. C.; Shoup, M. J. III; Stoeckl, C.; Caggiano, J. A.; Carman, M. L.; Clancy, T. J.; Hatarik, R.; McNaney, J.; Zaitseva, N. P.

    2012-10-15

    A new neutron time-of-flight (nTOF) detector with a bibenzyl crystal as a scintillator has been designed and manufactured for the National Ignition Facility (NIF). This detector will replace a nTOF20-Spec detector with an oxygenated xylene scintillator currently operational on the NIF to improve the areal-density measurements. In addition to areal density, the bibenzyl detector will measure the D-D and D-T neutron yield and the ion temperature of indirect- and direct-drive-implosion experiments. The design of the bibenzyl detector and results of tests on the OMEGA Laser System are presented.

  10. Heterobimetallic zeolite, InV-ZSM-5, enables efficient conversion of biomass derived ethanol to renewable hydrocarbons

    SciTech Connect (OSTI)

    Narula, Chaitanya K.; Li, Zhenglong; Casbeer, Erik M.; Geiger, Robert A.; Moses-Debusk, Melanie; Keller, Martin; Buchanan, Michelle V.; Davison, Brian H.

    2015-11-03

    Here, direct catalytic conversion of ethanol to hydrocarbon blend-stock can increase biofuels use in current vehicles beyond the ethanol blend-wall of 10–15%. Literature reports describe quantitative conversion of ethanol over zeolite catalysts but high C2 hydrocarbon formation renders this approach unsuitable for commercialization. Furthermore, the prior mechanistic studies suggested that ethanol conversion involves endothermic dehydration step. Here, we report the complete conversion of ethanol to hydrocarbons over InV-ZSM-5 without added hydrogen and which produces lower C2 (<13%) as compared to that over H-ZSM-5. Experiments with C2H5OD and in situ DRIFT suggest that most of the products come from the hydrocarbon pool type mechanism and dehydration step is not necessary. Thus, our method of direct conversion of ethanol offers a pathway to produce suitable hydrocarbon blend-stock that may be blended at a refinery to produce fuels such as gasoline, diesel, JP-8, and jet fuel, or produce commodity chemicals such as BTX.

  11. Heterobimetallic zeolite, InV-ZSM-5, enables efficient conversion of biomass derived ethanol to renewable hydrocarbons

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Narula, Chaitanya K.; Li, Zhenglong; Casbeer, Erik M.; Geiger, Robert A.; Moses-Debusk, Melanie; Keller, Martin; Buchanan, Michelle V.; Davison, Brian H.

    2015-11-03

    Here, direct catalytic conversion of ethanol to hydrocarbon blend-stock can increase biofuels use in current vehicles beyond the ethanol blend-wall of 10–15%. Literature reports describe quantitative conversion of ethanol over zeolite catalysts but high C2 hydrocarbon formation renders this approach unsuitable for commercialization. Furthermore, the prior mechanistic studies suggested that ethanol conversion involves endothermic dehydration step. Here, we report the complete conversion of ethanol to hydrocarbons over InV-ZSM-5 without added hydrogen and which produces lower C2 (<13%) as compared to that over H-ZSM-5. Experiments with C2H5OD and in situ DRIFT suggest that most of the products come from the hydrocarbonmore » pool type mechanism and dehydration step is not necessary. Thus, our method of direct conversion of ethanol offers a pathway to produce suitable hydrocarbon blend-stock that may be blended at a refinery to produce fuels such as gasoline, diesel, JP-8, and jet fuel, or produce commodity chemicals such as BTX.« less

  12. Kinetics of flash hydrogenation of lignite and subbituminous coal

    SciTech Connect (OSTI)

    Bhatt, B; Fallon, P T; Steinberg, M

    1980-01-01

    A reaction model, based on a single coal particle surrounded by H/sub 2/ gas, is developed for the hydrogenation of lignite and subbituminous coal. Conversion data from experiments conducted at various pressures, temperatures, particle residence times and gas residence times are correlated to calculate activation energies and to obtain one set of kinetic parameters. A single object function formulated from the weighted errors for the four dependent process variables, CH/sub 4/, C/sub 2/H/sub 6/, BTX, and oil yields, was minimized using a program containing three independent iterative techniques. The results of the nonlinear regression analysis for lignite show that a first-order chemical reaction model with respect to C conversion, satisfactorily describes the dilute phase hydrogenation. The conversion data obtained from hydrogenation experiments using subbituminous coal are correlated using similar techniques. The results obtained from data analysis of the two types of coals are compared. The mechanism, the rate expressions, and the design curves developed can be used for scale-up and reactor design.

  13. Implementation of solar-reflective surfaces: Materials and utility programs

    SciTech Connect (OSTI)

    Bretz, S.; Akbari, H.; Rosenfeld, A.; Taha, H.

    1992-06-01

    This report focuses on implementation issues for using solar-reflective surfaces to cool urban heat islands, with specific examples for Sacramento, California. Advantages of solar-reflective surfaces for reducing energy use are: (1) they are cost-effective if albedo is increased during routine maintenance; (2) the energy savings coincide with peak demand for power; (3) there are positive effects on environmental quality; and (4) the white materials have a long service life. Important considerations when choosing materials for mitigating heat islands are identified as albedo, emissivity, durability, cost, pollution and appearance. There is a potential for increasing urban albedo in Sacramento by an additional 18%. Of residential roofs, we estimate that asphalt shingle and modified bitumen cover the largest area, and that built-up roofing and modified bitumen cover the largest area of commercial buildings. For all of these roof types, albedo may be increased at the time of re-roofing without any additional cost. When a roof is repaired, a solar-reflective roof coating may be applied to significantly increase albedo and extend the life of the root Although a coating may be cost-effective if applied to a new roof following installation or to an older roof following repair, it is not cost-effective if the coating is applied only to save energy. Solar-reflective pavement may be cost-effective if the albedo change is included in the routine resurfacing schedule. Cost-effective options for producing light-colored pavement may include: (1) asphalt concrete, if white aggregate is locally available; (2) concrete overlays; and (3) newly developed white binders and aggregate. Another option may be hot-rolled asphalt, with white chippings. Utilities could promote solar-reflective surfaces through advertisement, educational programs and cost-sharing of road resurfacing.

  14. csv.cfm

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    State Energy Data System (SEDS): 2015 (updates by energy source) Schedule of new releases of energy consumption, price, and expenditure estimates by energy source. See the 2014 version of this page. + EXPAND ALL Petroleum and fuel ethanol 2015 Release date Jet fuel Planned 10/21/2016 Lubricants Planned 10/21/2016 Asphalt and road oil Planned 10/21/2016 Motor gasoline Planned 12/16/2016 Fuel ethanol Planned 12/16/2016 Aviation gasoline Planned 12/16/2016 Distillate fuel oil consumption Planned

  15. Technology meets aggregate

    SciTech Connect (OSTI)

    Wilson, C.; Swan, C.

    2007-07-01

    New technology carried out at Tufts University and the University of Massachusetts on synthetic lightweight aggregate has created material from various qualities of fly ash from coal-fired power plants for use in different engineered applications. In pilot scale manufacturing tests an 'SLA' containing 80% fly ash and 20% mixed plastic waste from packaging was produced by 'dry blending' mixed plastic with high carbon fly ash. A trial run was completed to produce concrete masonry unit (CMU) blocks at a full-scale facility. It has been shown that SLA can be used as a partial substitution of a traditional stone aggregate in hot asphalt mix. 1 fig., 2 photos.

  16. U.S. Department of Energy Office of Legacy Management

    Office of Legacy Management (LM)

    March 12, 2013 Inspector SM Stoller, Ohio EPA, ODH Area Former Production Area and Waste Pits Area Sub-Area Type of Finding Follow Up No. Location (Use Map Whenever Possible) GPS? Unauthorized Use Disturbance Vegetation Other Description Photo? (File No.) Corrected Maintenance Req'd Cont. Observation 1 North of Bio-wetland NO X Concrete debris X 2 North of Bio-wetland NO X Asphalt debris X 3 North of Bio-wetland NO X Concrete debris X 4 A4B NO X Concrete debris X 5 Main drainage corridor NO X

  17. The extraction of bitumen from western tar sands. Annual report, July 1990--July 1991

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-04-01

    Contents of this report include the following: executive summary; characterization of the native bitumen from the Whiterocks oil sand deposit; influence of carboxylic acid content on bitumen viscosity; water based oil sand separation technology; extraction of bitumen from western oil sands by an energy-efficient thermal method; large- diameter fluidized bed reactor studies; rotary kiln pyrolysis of oil sand; catalytic upgrading of bitumen and bitumen derived liquids; ebullieted bed hydrotreating and hydrocracking; super critical fluid extraction; bitumen upgrading; 232 references; Appendix A--Whiterocks tar sand deposit bibliography; Appendix B--Asphalt Ridge tar sand deposit bibliography; and Appendix C--University of Utah tar sands bibliography.

  18. U.S. Energy Information Administration | State Energy Data 2014: Consumption

    Gasoline and Diesel Fuel Update (EIA)

    3 Appendix F. Data and Methodology Changes A P P E N D I X F Tables and data files in the State Energy Data System (SEDS) supply a new year of data each production cycle. The latest data may be preliminary and, therefore, revised the following cycle. Changes made to consumption and price source data for historical years are also regularly incorporated into SEDS. Listed below are changes in SEDS contents beyond the standard updates. Petroleum Asphalt and road oil For 2009 forward, state-level

  19. Table 1.15 Non-Combustion Use of Fossil Fuels, 1980-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Non-Combustion Use of Fossil Fuels, 1980-2011 Year Petroleum Products Natural Gas 4 Coal Total Percent of Total Energy Consumption Asphalt and Road Oil Liquefied Petroleum Gases 1 Lubricants Petro- chemical Feedstocks 2 Petroleum Coke Special Naphthas Other 3 Total Physical Units 5<//td> 1980 145 230 58 253 14 [R] 37 58 795 [R] 639 2.4 [ – –] [ – –] 1981 125 229 56 216 15 [R] 27 54 722 [R] 518 [R] 2.1 [ – –] [ – –] 1982 125 256 51 157 15 [R] 25 48 678 [R] 448 [R] 1.4 [ – –] [

  20. Word Pro - Untitled1

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 1.15 Non-Combustion Use of Fossil Fuels, Selected Years, 1980-2011 Year Petroleum Products Natural Gas 4 Coal Total Percent of Total Energy Consumption Asphalt and Road Oil Liquefied Petroleum Gases 1 Lubricants Petro- chemical Feedstocks 2 Petroleum Coke Special Naphthas Other 3 Total Physical Units 5 1980 145 230 58 253 R 14 37 58 R 795 639 2.4 - - - - 1985 156 R 278 53 144 R 16 30 41 R 719 500 1.1 - - - - 1990 176 R 373 60 199 20 20 39 R 887 R 567 .6 - - - - 1991 162 R 426 53 203 17 17

  1. War against water

    SciTech Connect (OSTI)

    Fitz-Hugh, S.

    1982-01-01

    It is stressed that waterproofing should be the most important concern in an earth-sheltered home, starting with the design and continuing throughout the construction. Damage which may be caused by water leakage is discussed. Proper site selection is most important and the need for outside professionals and consultants is emphasized. The ideal waterproofing system is discussed and illustrated. Waterproofing agents are discussed in detail. They are: (1) sodium bentonite; (2) elastomers, such as isobutylene isoprene (butyl rubber), EPDM (ethylene propylene diene monomer), and liquid elastomers (polyurethanes); and (3) rubberized asphalt. Availability, sheet sizes and application of these waterproofing agents are discussed. (MJJ)

  2. XANES Identification of Plutonium Speciation in RFETS Samples

    SciTech Connect (OSTI)

    LoPresti, V.; Conradson, S.D.; Clark, D.L.

    2009-06-03

    Using primarily X-ray absorption near edge spectroscopy (XANES) with standards run in tandem with samples, probable plutonium speciation was determined for 13 samples from contaminated soil, acid-splash or fire-deposition building interior surfaces, or asphalt pads from the Rocky Flats Environmental Technology Site (RFETS). Save for extreme oxidizing situations, all other samples were found to be of Pu(IV) speciation, supporting the supposition that such contamination is less likely to show mobility off site. EXAFS analysis conducted on two of the 13 samples supported the validity of the XANES features employed as determinants of the plutonium valence.

  3. CLOSURE REPORT FOR CORRECTIVE ACTION UNIT 204: STORAGE BUNKERS, NEVADA TEST SITE, NEVADA

    SciTech Connect (OSTI)

    2006-04-01

    Corrective Action Unit (CAU) 330 consists of four Corrective Action Sites (CASs) located in Areas 6, 22, and 23 of the Nevada Test Site (NTS). The unit is listed in the Federal Facility Agreement and Consent Order (FFACO, 1996) as CAU 330: Areas 6, 22, and 23 Tanks and Spill Sites. CAU 330 consists of the following CASs: CAS 06-02-04, Underground Storage Tank (UST) and Piping CAS 22-99-06, Fuel Spill CAS 23-01-02, Large Aboveground Storage Tank (AST) Farm CAS 23-25-05, Asphalt Oil Spill/Tar Release

  4. Alkylate

    U.S. Energy Information Administration (EIA) Indexed Site

    Day) Product: Alkylate Aromatics Asphalt & Road Oil Isomers Isobutane Isopentane & Isohexane Isooctane Lubricants Marketable Petroleum Coke Hydrogen Sulfur Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2011 2012 2013 2014 2015 2016 View History U.S. 1,262,443 1,246,875 1,269,361 1,266,352 1,267,246 1,286,012 1982-2016 PAD District 1 108,629 79,429 91,429 83,429

  5. Chemi-microbial processing of waste tire rubber: A project overview

    SciTech Connect (OSTI)

    Romine, R.A.; Snowden-Swan, L.

    1993-12-01

    PNL is developing a method to use thiophillic microorganisms to devulcanize (biodesulfurize) the surface of ground rubber particles, which will improve the bonding and adhesion of the ground tire rubber into the virgin tire rubber matrix. The Chemi-microbial processing approach, introduced in this paper, is targeted at alleviating the waste tire problem in an environmentally conscious manner; it may also be applied to improve asphaltic materials and rubber and polymeric wastes to facilite their recycling. This paper outlines the logic and technical methods that will be used.

  6. DATE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EC Document No.: DOE-ID-INL-09-002 SECTION A. Project Title: Smoking Shelters SECTION B. Project Description. Install up to three prefabricated outdoor shelters for smokers. Design and install a shelter base so that shelters can be movable. The base shall be designed to prevent shelters from moving or tipping over due to high winds. Specific location for shelters is to be determined, but the shelter bases will be placed atop existing concrete or asphalt such that no subsurface soil disturbance

  7. DOE Tour of Zero: Bates Avenue by Sunroc Builders | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bates Avenue by Sunroc Builders DOE Tour of Zero: Bates Avenue by Sunroc Builders 1 of 15 Sunroc Builders built this 1,104-square-foot home in Winter Haven, Florida, to the performance criteria of the U.S. Department of Energy Zero Energy Ready Home (ZERH) program. 2 of 15 ENERGY STAR-rated light-colored asphalt shingles help reflect heat, reducing solar gain during the hot weather in the Florida home. 3 of 15 The energy-efficiency features built into the compact, affordable home are expected to

  8. Putting On the Brakes to Protect America's Natural Treasures - Continuum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magazine | NREL Putting On the Brakes to Protect America's Natural Treasures Putting On the Brakes to Protect America's Natural Treasures National Parks Initiative greens roads and preserves once-in-a-lifetime experiences. A white, four-door car parked on asphalt in front of a marble, multi-columned, dome-roofed building, which is surrounded by evergreen trees and under a slightly cloudy sky. A plug-in electric vehicle charges near the Thomas Jefferson Memorial in Washington, D.C. Photo from

  9. JLab Roads Update: Rattley Rd. Closure Planned to Start Week of July 11

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (updated posted June 23, 2016) | Jefferson Lab Roads Update: Rattley Rd. Closure Planned to Start Week of July 11 (updated posted June 23, 2016) JLab Road Work Update: Status of Work on Lawrence Dr. and Upcoming Closure of Rattley Rd. (update posted July 5, 2016) The final layer of asphalt is scheduled to go on Lawrence Drive this week (week of July 4, 2016). The plan is to complete this portion of the work on Friday, July 8. An announcement will be made when the Lawrence Dr./Jefferson

  10. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    District and State Production Capacity Alkylates Aromatics Asphalt and Road Oil Isomers Lubricants Marketable Petroleum Coke Sulfur (short tons/day) Hydrogen (MMcfd) Table 2. Production Capacity of Operable Petroleum Refineries by PAD District and State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) a 83,429 10,111 26,500 92,765 21,045 21,120 69 1,159 PAD District I Delaware 11,729 5,191 0 6,000 0 13,620 40 596 New Jersey 29,200 0 70,000 4,000 12,000 7,500 26 280 Pennsylvania

  11. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    State/Refiner/Location Alkylates Aromatics Isobutane Lubricants Isomers Isopentane and Isohexane Asphalt and Road Oil Marketable Petroleum Coke Hydrogen (MMcfd) Sulfur (short tons per day) Table 4. Production Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) Isooctane a ..................................................................... Alabama 0 0 15,000 1,150 4,200 0 7,120 40 228 0 Hunt Refining Co 0 0 15,000 0 4,200 0 7,120

  12. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1987 to January 1, 2016 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN 1, 1990 1,030 290 844 456 232 341 2,607 24,202

  13. Hydroprocessing of desalted directly liquefied biomass

    SciTech Connect (OSTI)

    Gevert, B.; Andersson, P.; Jaeras, S.; Sandqvist, S.

    1988-01-01

    Desalted directly liquefied biomass from the PERC process was consecutively extracted with iso-octane and xylene. The hydroprocessing was made in a downflow reactor at a constant hydrogen flow and pressure of 85 normal 1/h and 10.0 MPa, respectively. The catalyst used as a sulfided cobalt + molybdenum catalyst on gamma alumina. At a liquid flow of 180 ml/h, an hourly liquid space velocity of 1.20 and a temperature of 350/degree/C, the oxygen content of the desalted oil was reduced from 15.3 to 2.3% by weight. The effective H/C molar ratio was increased from 1.05 in the starting material to 1.35 and the amount of heavy material with normal atmospheric boiling points above 540/degree/C was reduced from 45.3 to 15.1% by weight. Hydroprocessing at 420/degree/C reduced this heavy material further to 4.5% by weight. The deoxygenation was only to a small degree dependent on whether the feed oil was desalted or extracted with iso-octane or xylene.

  14. Degradative capacities and bioaugmentation potential of an anaerobic benzene-degrading bacterium strain DN11

    SciTech Connect (OSTI)

    Yuki Kasai; Yumiko Kodama; Yoh Takahata; Toshihiro Hoaki; Kazuya Watanabe

    2007-09-15

    Azoarcus sp. strain DN11 is a denitrifying bacterium capable of benzene degradation under anaerobic conditions. The present study evaluated strain DN11 for its application to bioaugmentation of benzene-contaminated underground aquifers. Strain DN11 could grow on benzene, toluene, m-xylene, and benzoate as the sole carbon and energy sources under nitrate-reducing conditions, although o- and p-xylenes were transformed in the presence of toluene. Phenol was not utilized under anaerobic conditions. Kinetic analysis of anaerobic benzene degradation estimated its apparent affinity and inhibition constants to be 0.82 and 11 {mu}M, respectively. Benzene-contaminated groundwater taken from a former coal-distillation plant site in Aichi, Japan was anaerobically incubated in laboratory bottles and supplemented with either inorganic nutrients (nitrogen, phosphorus, and nitrate) alone, or the nutrients plus strain DN11, showing that benzene was significantly degraded only when DN11 was introduced. Denaturing gradient gel electrophoresis of PCR-amplified 16S rRNA gene fragments, and quantitative PCR revealed that DN11 decreased after benzene was degraded. Following the decrease in DN11 16S rRNA gene fragments corresponding to bacteria related to Owenweeksia hongkongensis and Pelotomaculum isophthalicum, appeared as strong bands, suggesting possible metabolic interactions in anaerobic benzene degradation. Results suggest that DN11 is potentially useful for degrading benzene that contaminates underground aquifers at relatively low concentrations. 50 refs., 6 figs., 1 tab.

  15. Source Apportionment of Stack Emissions from Research and Development Facilities Using Positive Matrix Factorization

    SciTech Connect (OSTI)

    Ballinger, Marcel Y.; Larson, Timothy V.

    2014-08-19

    Emissions from research and development (R&D) facilities are difficult to characterize due to the wide variety of processes used, changing nature of research, and large number of chemicals. Positive matrix factorization (PMF) was applied to volatile organic compounds (VOCs) concentrations measured in the main exhaust stacks of four different R&D buildings to identify the number and composition of major contributing sources. PMF identified from 9-11 source-related factors contributing to the stack emissions depending on the building. The factors that were similar between buildings were major contributors to trichloroethylene (TCE), acetone, and ethanol emissions. Several other factors had similar profiles for two or more buildings but not for all four. One factor for each building was a combination of p/m-xylene, o-xylene and ethylbenzene. At least one factor for each building was identified that contained a broad mix of many species and constraints were used in PMF to modify the factors to resemble more closely the off-shift concentration profiles. PMF accepted the constraints with little decrease in model fit. Although the PMF model predicted the profiles of the off-shift samples, the percent of total emissions was under-predicted by the model versus the measured data.

  16. The Hanford Site 1000-Year Cap Design Test

    SciTech Connect (OSTI)

    Gee, Glendon W. ); Ward, Anderson L. ); Wittreich, Curtis D.

    2002-12-27

    Surface barrier or capping technology is needed to isolate buried wastes. A successful cap must prevent the intrusion of plants, animals, and man into the underlying waste, minimize wind and water erosion, require minimal maintenance, and limit water intrusion to near-zero amounts. For some sites where wastes are long-lived, caps should potentially last a thousand years or more. At the U.S. Department of Energy (DOE) Hanford Site in Washington State, a surface cap with a 1000-year design life was constructed and then tested and monitored for performance under wetting conditions that are extreme for the region. The cap was built in 1994 over an existing waste site as a part of a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) treatability test. The above-grade barrier or cap consists of a 2-m-thick silt-loam soil overlying layers (from top down) of sand, gravel, basalt rock (riprap), and a low-permeability asphalt. Two sideslope configurations, a clean-fill gravel on a 10:1 slope and a basalt riprap on a 2:1 slope were part of the overall design and testing. Design considerations included constructability; water-balance monitoring; wind and water erosion control and monitoring; surface revegetation, biointrusion control, subsidence, and sideslope stability; and durability of the asphalt layer.

  17. Liner evaluation for uranium mill tailings. Final report

    SciTech Connect (OSTI)

    Buelt, J.L. (comp.)

    1983-09-01

    The Liner Evaluation for Uranium Mill Tailings Program was conducted to evaluate the need for and performance of prospective lining materials for the long-term management of inactive uranium mill tailings piles. On the basis of program results, two materials have been identified: natural foundation soil amended with 10% sodium bentonite; catalytic airblown asphalt membrane. The study showed that, for most situations, calcareous soils typical of Western US sites adequately buffer tailings leachates and prevent groundwater contamination without additional liner materials or amendments. Although mathematical modeling of disposal sites is recommended on a site-specific basis, there appears to be no reason to expect significant infiltration through the cover for most Western sites. The major water source through the tailings would be groundwater movement at sites with shallow groundwater tables. Even so column leaching studies showed that contaminant source terms were reduced to near maximum contaminant levels (MCL's) for drinking water within one or two pore volumes; thus, a limited source term for groundwater contamination exists. At sites where significant groundwater movement or infiltration is expected and the tailings leachates are alkaline, however, the sodium bentonite or asphalt membrane may be necessary.

  18. CLOSURE REPORT FOR CORRECTIVE ACTION UNIT 390: AREAS 9, 10, AND 12 SPILL SITES, NEVADA TEST SITE, NEVADA

    SciTech Connect (OSTI)

    2005-10-01

    Corrective Action Unit (CAU) 390 consists four Corrective Action Sites (CASs) located in Areas 9, 10, and 12 of the Nevada Test Site. The closure activities performed at the CASs include: (1) CAS 09-99-03, Wax, Paraffin: 2 cubic yards of drilling polymer was removed on June 20,2005, and transported to the Area 9 Landfill for disposal. (2) CAS 10-99-01, Epoxy Tar Spill: 2 cubic feet of asphalt waste was removed on June 20,2005, and transported to the Area 9 Landfill for disposal. (3) CAS 10-99-03, Tar Spills: 3 cubic yards of deteriorated asphalt waste was removed on June 20,2005, and transported to the Area 9 Landfill for disposal. (4) CAS 12-25-03, Oil Stains (2); Container: Approximately 16 ounces of used oil were removed from ventilation equipment on June 28,2005, and recycled. One CAS 10-22-19, Drums, Stains, was originally part of CAU 390 but was transferred out of CAU 390 and into CAU 550, Drums, Batteries, and Lead Materials. The transfer was approved by the Nevada Division of Environmental Protection on August 19,2005, and a copy of the approval letter is included in Appendix D of this report.

  19. Life Cycle Assessment of Pavements: A Critical Review of Existing Literature and Research

    SciTech Connect (OSTI)

    Santero, Nicholas; Masanet, Eric; Horvath, Arpad

    2010-04-20

    This report provides a critical review of existing literature and modeling tools related to life-cycle assessment (LCA) applied to pavements. The review finds that pavement LCA is an expanding but still limited research topic in the literature, and that the existing body of work exhibits methodological deficiencies and incompatibilities that serve as barriers to the widespread utilization of LCA by pavement engineers and policy makers. This review identifies five key issues in the current body of work: inconsistent functional units, improper system boundaries, imbalanced data for asphalt and cement, use of limited inventory and impact assessment categories, and poor overall utility. This review also identifies common data and modeling gaps in pavement LCAs that should be addressed in future work. These gaps include: the use phase (rolling resistance, albedo, carbonation, lighting, leachate, and tire wear and emissions), asphalt fumes, feedstock energy of bitumen, traffic delay, the maintenance phase, and the end-of-life phase. This review concludes with a comprehensive list of recommendations for future research, which shed light on where improvements in knowledge can be made that will benefit the accuracy and comprehensiveness of pavement LCAs moving forward.

  20. ACAA pavement manual. Recommended practice: Coal fly ash in pozzolanic stabilized mixtures for flexible pavement systems

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The purpose of this manual is to guide pavement design engineers, materials engineers, and construction managers in the design and construction of flexible pavement systems in which low- to high-strength Pozzolanic Stabilized Mixtures' ( PSMs') serve as base layers. A PSM incorporates coal fly ash in combination with activators, aggregates and water. Each of three design methods is useful for determining the thickness of a PSM base layer for a flexible pavement system: Method A - American Association of State Highway and Transportation Officials (AASHTO) flexible pavement design procedures, using structural layer coefficients; Method B - Mechanistic pavement design procedures, using resilient modulus values for the pavement layers; and Method C - A combination of Method A and Method B, using mechanistic design concepts for determining pavement layer coefficients. PSMs offer several advantages: PSMs are strong, durable mixtures using locally available materials; PSMs are economically competitive with properly engineered full-depth asphalt or crushed stone base courses; PSMs are suited to stabilizing recycled base mixtures; and PSMs are placed and compacted with conventional construction equipment. To provide the needed guidance for capturing the long-term service and cost-saving features of a PSM design, this manual details the following: a procedure for proportioning PSMs; thickness design procedures which include base layer and asphalt wearing course; and proven techniques for PSM mixing and base layer construction.

  1. Monitoring pavement response and performance using in-situ instrumentation

    SciTech Connect (OSTI)

    Chen, D.H.; Bilyeu, J.; Hugo, F.

    1999-07-01

    The purpose of this paper is to present the effectiveness of in-situ instrumentation on diagnosing the pavement layer conditions under full-scale accelerated traffic loading. The test section is an in-service pavement (US281) in Jacksboro, Texas. Multi-Depth Deflectometers (MDDs) are used to measure both permanent deformations and transient deflections, caused by accelerated traffic loading and Falling Weight Deflectometers (MDDs) are used to measure both permanent deformations and transient deflections, caused by accelerated traffic loading and Falling Weight Deflectometer (FWD) tests. Four different FWD loads of 25, 40, 52, and 67 kN were applied in close proximity to the MDDs at various traffic loading intervals to determine pavement conditions. It was found that the majority of rutting occurred in the newly recycled asphalt mix. The aged ({gt}40 years) underlying base and subgrade layers contributed less than 30% to overall rutting. Only the top recycled Asphalt layer underwent notable deterioration due to traffic loading. Up to 1.5 million axle repetitions, the test pad responded to FWD load almost linearly, not only over the whole pavement system but also within individual layers. However, under higher FWD loads, the percentage of total deflection contributed by the subgrade increased.

  2. Field study plan for alternate barriers

    SciTech Connect (OSTI)

    Freeman, H.D.; Gee, G.W.; Relyea, J.F.

    1989-05-01

    Pacific Northwest Laboratory (PNL) is providing technical assistance in selecting, designing, evaluating, and demonstrating protective barriers. As part of this technical assistance effort, asphalt, clay, and chemical grout will be evaluated for use as alternate barriers. The purpose of the subsurface layer is to reduce the likelihood that extreme events (i.e., 100-year maximum storms, etc.) will cause significant drainage through the barrier. The tests on alternate barriers will include laboratory and field analysis of the subsurface layer performance. This field test plan outlines the activities required to test and design subsurface moisture barriers. The test plan covers activities completed in FY 1988 and planned through FY 1992 and includes a field-scale test of one or more of the alternate barriers to demonstrate full-scale application techniques and to provide performance data on a larger scale. Tests on asphalt, clay, and chemical grout were initiated in FY 1988 in small (30.5 cm diameter) tube-layer lysimeters. The parameters used for testing the materials were different for each one. The tests had to take into account the differences in material characteristics and response to change in conditions, as well as information provided by previous studies. 33 refs., 8 figs., 1 tab.

  3. Summary of the issues with regard to the carcinogenicity, mutagenicity, and exposure of polycyclic organic matter (POM)

    SciTech Connect (OSTI)

    Not Available

    1984-04-01

    Polycyclic organic matter (POM) is emitted from a variety of sources in the environment. Evidence of the carcinogenicity of emissions from coke production, motor vehicles (includes tire wear), asphalt roofing, paving, and air blowing, catalytic cracking residential coal combustion, industrial/utility coal combustion, carbon black, and iron and steel processes is presented. The contribution of the POM fraction to the carcinogenicity of the mixture is evaluated for gasoline engine exhaust condensate and coal combustion effluent and appears to contribute the majority of the carcinogenic potential for those mixtures. Evidence of the mutagenicity of emissions from coke production, motor vehicles (including tire wear), industrial/utility coal combustion, carbon black, iron and steel processes, forest fires and open burning, residential solid fuel (wood) combustion, commercial and other incineration, commercial/industrial oil combustion, residential oil combustion, and asphalt roofing, paving, and air blowing is also presented. The problem in the use of a chemical surrogate to sample for POM-containing emissions is discussed. A discussion of the problems in evaluating the carcinogenic potential of different POM-containing mixtures is also presented.

  4. INTERIM BARRIER AT HANFORDS TY FARM TO PROTECT GROUNDWATER AT THE HANFORD SITE WASHINGTON USA

    SciTech Connect (OSTI)

    PARKER DL; HOLM MJ; HENDERSON JC; LOBER RW

    2011-01-13

    An innovative interim surface barrier was constructed as a demonstration project at the Hanford Site's TY Tank Farm. The purpose of the demonstration barrier is to stop rainwater and snowmelt from entering the soils within the tank farm and driving contamination from past leaks and spills toward the ground water. The interim barrier was constructed using a modified asphalt material with very low permeability developed by MatCon{reg_sign}. Approximately 2,400 cubic yards of fill material were added to the tank farm to create a sloped surface that will gravity drain precipitation to collection points where it will be routed through buried drain lines to an evapotranspiration basin adjacent to the farm. The evapotranspiration basin is a lined basin with a network of perforated drain lines covered with soil and planted with native grasses. The evapotranspiration concept was selected because it prevents the runoff from percolating into the soil column and also avoids potential monitoring and maintenance issues associated with standing water in a traditional evaporation pond. Because of issues associated with using standard excavation and earth moving equipment in the farm a number of alternate construction approaches were utilized to perform excavations and prepare the site for the modified asphalt.

  5. Biomass Thermochemical Conversion Program. 1983 Annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1984-08-01

    Highlights of progress achieved in the program of thermochemical conversion of biomass into clean fuels during 1983 are summarized. Gasification research projects include: production of a medium-Btu gas without using purified oxygen at Battelle-Columbus Laboratories; high pressure (up to 500 psia) steam-oxygen gasification of biomass in a fluidized bed reactor at IGT; producing synthesis gas via catalytic gasification at PNL; indirect reactor heating methods at the Univ. of Missouri-Rolla and Texas Tech Univ.; improving the reliability, performance, and acceptability of small air-blown gasifiers at Univ. of Florida-Gainesville, Rocky Creek Farm Gasogens, and Cal Recovery Systems. Liquefaction projects include: determination of individual sequential pyrolysis mechanisms at SERI; research at SERI on a unique entrained, ablative fast pyrolysis reactor for supplying the heat fluxes required for fast pyrolysis; work at BNL on rapid pyrolysis of biomass in an atmosphere of methane to increase the yields of olefin and BTX products; research at the Georgia Inst. of Tech. on an entrained rapid pyrolysis reactor to produce higher yields of pyrolysis oil; research on an advanced concept to liquefy very concentrated biomass slurries in an integrated extruder/static mixer reactor at the Univ. of Arizona; and research at PNL on the characterization and upgrading of direct liquefaction oils including research to lower oxygen content and viscosity of the product. Combustion projects include: research on a directly fired wood combustor/gas turbine system at Aerospace Research Corp.; adaptation of Stirling engine external combustion systems to biomass fuels at United Stirling, Inc.; and theoretical modeling and experimental verification of biomass combustion behavior at JPL to increase biomass combustion efficiency and examine the effects of additives on combustion rates. 26 figures, 1 table.

  6. SORGHUM BIOMASS/FEEDSTOCK GENOMICS RESEARCH FOR BIOENERGY

    SciTech Connect (OSTI)

    Rooney, William L.; Mullet, John E.; Klein, Patricia; Kresovich, Steven; Ware, Doreen

    2010-01-01

    Objectives: The specific objectives of this project were to: (1) annotate genes, pathways and regulatory networks identified in the sorghum genome sequence that are important for biomass generation, and (2) identify, map and clarify the function of trait loci that modulate accumulation and quality of biomass in sorghum. Approach: Objective 1: Genes encoding proteins involved in biochemical pathways important for biomass generation and plant composition related to biofuel production (i.e., starch, lignin, sugar, cellulose and hemicellulose) were identified and projected onto biochemical pathways using the database MetaCyc (SorgCyc). The pathway projections provide a baseline of information on sorghum genes involved in biochemical pathways thus aiding our downstream analysis of QTL and traits. In addition, the information on sorghum biochemical pathways in Gramene can be readily compared to information on other cereals and other organisms via Gramene’s comparative mapping tools. This information helped identify gaps in the current knowledge of sorghum biochemistry and identified pathways and genes that may be useful to deploy in sorghum for biomass/bioenergy generation. Objective 2: Grain, biomass, and carbohydrate yields were measured in germplasm and a population consisting of 175 recombinant inbred lines (RILs) (F5:6) from the cross of BTx623 (a high yielding early flowering grain sorghum) × Rio (a high biomass sweet sorghum). Plant growth parameters were analyzed to obtain a baseline for downstream meta-analysis including plant height, flowering time and tillering, traits that likely modulate carbohydrate partitioning in various tissues and total biomass. Traits that affect grain yield, biomass (i.e. the tissue harvest index and distribution of grain, stem, and leaf weight), the composition of structural and non-structural carbohydrates, and the overall energy gain of the plant were evaluated. A genetic map of this population was created and QTL analysis will

  7. Feedstock effects in coal flash pyrolysis

    SciTech Connect (OSTI)

    Tatterson, D.F.; Robinson, K.K.; Guercio, R.; Marker, T.L.

    1990-10-01

    In this paper the impact of lower rank coals on yields and product qualities is examined in a large- scale flash pyrolysis reactor capable of achieving heating rates of 10{sup 6}{degrees}C/s and reactor times of 10 ms. A Montana lignite and a Minnesota peat were pyrolyzed and the results compared to those for Illinois No. 6 bituminous coal. The peat was found to be more reactive than the Illinois No. 6 coal and the lignite less reactive. Relatively high liquid yields were also obtained from the peat. This result demonstrates that high oxygen content in a feedstock does not necessarily correlate with low production of liquids. At high reactor severity, the peat is an excellent source of aromatics (benzene, toulene, and xylenes) and medium Btu gas, which could be converted to other chemical feedstocks.

  8. Chemical vapor deposition of fluorinated polymers

    SciTech Connect (OSTI)

    Moore, J.A.; Lang, C.I.; Lu, T.M.; You, L.

    1993-12-31

    An overview of the authors` work directed toward the deposition of fluorinated polymers by condensation of thermally or photochemically generated intermediates directly from the vapor state will be presented. Previously known materials such as Teflon AF{reg_sign} and Parylene AF{sub 4} have been successfully deposited and are being evaluated for microelectronic application as on-chip dielectrics. A novel, one-step route to Parylene AF{sub 4} will be described which obviates the necessity of multistep organic synthesis to prepare precursors. A new, partially fluorinated parylene obtained from tetrafluoro-p-xylene will be described. It has also been observed that ultraviolet irradiation of the vapor of dimethyl tetrafluorobenzocyclobutene causes the deposition of an insoluble film which contains fluorine.

  9. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOE Patents [OSTI]

    Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

    1998-05-19

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

  10. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOE Patents [OSTI]

    Taylor, Robert T.; Jackson, Kenneth J.; Duba, Alfred G.; Chen, Ching-I

    1998-01-01

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

  11. PREPARATION OF HIGH PURITY UF$sub 4$

    DOE Patents [OSTI]

    Magner, J.E.; Long, R.S.; Ellis, D.A.; Grinstead, R.R.

    1962-04-17

    S>A process for preparing very highly pure uranous tetrafluoride from impure uranium laden solvent extraction strip solutions, ion exchange process and resin-inpulp process eluate solutions which are at least 8M in hydrochloric acid is described. The process first comprises treating any of the above-mentioned solutions with a reducing agent to reduce the uranium to the + 4 oxidation state, and then contacting the reduced solution with an extractant phase comprising about 10 to 70% of tri-butyl phosphate in an organic solvent-diluent selected from benzene, ethyl-benzene, chlorobenzene, xylene, kerosene, or the like. The uranium is extracted into the extractant phase and is subsequently precipitated by treating the extractant with an aqueous fluoride solution. The highly pure uranous tetrafluoride precipitate is separated from the phases and recovered for subsequent utilization. (AEC)

  12. The use of white-rot fungi as active biofilters

    SciTech Connect (OSTI)

    Braun-Luellemann, A.; Johannes, C.; Majcherczyk, A.; Huettermann, A.

    1995-12-31

    White-rot fungi, growing on lignocellulosic substrates, have been successfully used as active organisms in biofilters. Filters using these fungi have a very high biological active surface area, allowing for high degrees of retention, a comparatively low pressure drop, and a high physical stability. The unspecific action of the extracellular enzymes of the white-rot fungi allows for the degradation of a wide variety of substances by the same organism. Degradation of several compounds in the gas phase by the white-rot fungi Trametes versicolor, Pleurotus ostreatus, Bjerkandera adusta, and Phanerochaete chrysosporium was tested. Among the aromatic solvents, styrene was the compound that was most readily degraded, followed by ethylbenzene, xylenes, and toluene. Tetrahydrofuran and dichloromethane were also degraded, whereas dioxane could not be attacked by fungi under the conditions used. Acrylonitrile and aniline were degraded very well, whereas pyridine was resistant to degradation. The process for removing styrene is now in the scaling-up stage.

  13. Eielson Air Force Base Operable Unit 2 baseline risk assessment

    SciTech Connect (OSTI)

    Lewis, R.E.; Jarvis, T.T.; Jarvis, M.R.; Whelan, G.

    1994-10-01

    Operable Unit 2 at Eielson Air Force Base (AFB) near Fairbanks, is one of several operable units characterized by petroleum, oil, and lubricant contamination, and by the presence of organic products floating at the water table, as a result of Air Force operations since the 1940s. The base is approximately 19,270 acres in size, and comprises the areas for military operations and a residential neighborhood for military dependents. Within Operable Unit 2, there are seven source areas. These source areas were grouped together primarily because of the contaminants released and hence are not necessarily in geographical proximity. Source area ST10 includes a surface water body (Hardfill Lake) next to a fuel spill area. The primary constituents of concern for human health include benzene, toluene, ethylbenzene, and xylenes (BTEX). Monitored data showed these volatile constituents to be present in groundwater wells. The data also showed an elevated level of trace metals in groundwater.

  14. Superfund Record of Decision (EPA Region 6): Petro-Chemical (Turtle Bayou), Liberty County, TX. (Second remedial action), September 1991. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-09-06

    The 500-acre Petro-Chemical (Turtle Bayou) site is in Liberty County, Texas. Current land use in the area is divided among cropland, pasture, range, forest, and small rural communities. Since 1971, numerous undocumented disposal activities occurred onsite involving primarily petrochemical wastes. The ROD for OU2 focuses on three areas of contamination at the site affecting soil and ground water contamination, known as the main waste area, the east disposal area, and the Bayou disposal area. The primary contaminants of concern affecting the soil and ground water are VOCs including benzene and xylenes; other organics including PAHs; and metals including lead. The selected remedial action for the site includes treating 302,800 cubic yards of contaminated soil onsite using in-situ vapor extraction to remove VOCs, controlling vertical air infiltration using an engineered soil and synthetic liner cap; consolidating lead-contaminated soil in the Main Waste Area, followed by capping.

  15. Public health assessment for Petro-Chemical, Inc. (Turtle Bayou) Liberty, Liberty County, Texas, Region 6. CERCLIS No. TXD980873350. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-03-30

    The Petro-Chemical Systems, Inc. site, located near Liberty, Texas, is a site where unauthorized disposal of petroleum-based oils has taken place. Although there is evidence of past exposure to site contaminants, the best available evidence does not indicate that humans are currently being exposed to site contaminants at levels that could cause adverse health effects. Contaminated ground water, surface water, soils, and surface water sediments have been found on the site. Although sampling was done for 144 priority pollutants, the primary contaminants of concern are benzene, ethylbenzene, xylene, naphthalene, polycyclic aromatic hydrocarbons, and lead. Because the greatest threat to public health would be contamination of drinking water, the Agency for Toxic Substances and Disease Registry (ATSDR) has recommended that necessary actions are taken to insure that private wells do not become contaminated with site contaminants.

  16. Surfactant-modified zeolites as permeable barriers to organic and inorganic groundwater contaminants

    SciTech Connect (OSTI)

    Bowman, R.S.; Sullivan, E.J.

    1995-10-01

    We have shown in laboratory experiments that natural zeolites treated with hexadecyltrimethylammonium (HDTMA) are effective sorbents for nonpolar organics, inorganic cations, and inorganic anions. Due to their low cost ({approximately}$0.75/kg) and granular nature, HDTMA-zeolites appear ideal candidates for reactive, permeable subsurface barriers. The HDTMA-zeolites are stable over a wide range of pH (3-13), ionic strength (1 M Cs{sup +} or Ca{sup 2+}), and in organic solvents. Surfactant-modified zeolites sorb nonpolar organics (benzene, toluene, xylene, chlorinated aliphatics) via a partitioning mechanism, inorganic cations (Pb{sup 2+}) via ion exchange and surface complexation, and inorganic anions (CrO{sub 4}{sup 2-}, SeO{sub 4}{sup 2-}, SO{sub 4}{sup 2-}) via surface precipitation.The goal of this work is to demonstrate the use of surfactant-modified zeolite as a permeable barrier to ground water contaminants.

  17. Health assessment for Vogel Paint and Wax, Maurice, Sioux County, Iowa, Region 7. CERCLIS No. IAD980630487. Final report

    SciTech Connect (OSTI)

    Not Available

    1989-04-29

    The Vogel Paint and Wax National Priority List site is situated in northwest Iowa in Sioux County. Contaminants found at the site consist of heavy metals (particularly cadmium, chromium, lead, and mercury) and volatile organic compounds (benzene, ethylbenzene, methyl ethyl ketone, toluene, and xylene). Two towns, Maurice and Struble, and the Southern Sioux County Rural Water System well field are located within three miles of the site, and two families live within 1600 feet of the waste-disposal site. Environmental pathways include contaminated soil and ground water, as well as potential surface water and air contamination. Although there does not appear to be any immediate public health threat, the site is of potential health concern because of the possibility for further off-site migration of contaminants into the ground water aquifer and for direct on-site contact.

  18. Industrial hygiene survey report of worker exposures to organotins at Norfolk Naval Shipyard, Portsmouth, Virginia

    SciTech Connect (OSTI)

    Eissler, A.W.; Ferrel, T.W.; Bloom, T.F.; Fajen, J.M.

    1985-06-24

    Breathing-zone samples were analyzed for organotin compounds, copper, and xylene during spray application of organotin containing marine antifouling paint at Norfolk Naval Shipyard, Portsmouth, Virginia, March, 1984. The survey was part of a NIOSH study of occupational exposures to organotin compounds, conducted as a component of an assessment to determine the feasibility of conducting a study of reproductive effects. Company personnel records were reviewed. Work practices were observed. The authors conclude that a potential exists for exposures to organotins and copper. As all employees were wearing respiratory protective equipment, actual exposures may be less than that indicated by the analytical data. The facility could contribute 16 potentially exposed workers to the reproductive effects study.

  19. Aerosol characterization study using multi-spectrum remote sensing measurement techniques.

    SciTech Connect (OSTI)

    Glen, Crystal Chanea; Sanchez, Andres L.; Lucero, Gabriel Anthony; Schmitt, Randal L.; Johnson, Mark S.; Tezak, Matthew Stephen; Servantes, Brandon Lee

    2013-09-01

    A unique aerosol flow chamber coupled with a bistatic LIDAR system was implemented to measure the optical scattering cross sections and depolarization ratio of common atmospheric particulates. Each of seven particle types (ammonium sulfate, ammonium nitrate, sodium chloride, potassium chloride, black carbon and Arizona road dust) was aged by three anthropogenically relevant mechanisms: 1. Sulfuric acid deposition, 2. Toluene ozonolysis reactions, and 3. m-Xylene ozonolysis reactions. The results of pure particle scattering properties were compared with their aged equivalents. Results show that as most particles age under industrial plume conditions, their scattering cross sections are similar to pure black carbon, which has significant impacts to our understanding of aerosol impacts on climate. In addition, evidence emerges that suggest chloride-containing aerosols are chemically altered during the organic aging process. Here we present the direct measured scattering cross section and depolarization ratios for pure and aged atmospheric particulates.

  20. Nanoporous Materials Can Tune the Critical Point of a Pure Substance

    SciTech Connect (OSTI)

    Braun, Efrem; Chen, Joseph J.; Schnell, Sondre K.; Lin, Li-Chiang; Reimer, Jeffrey A.; Smit, Berend

    2015-09-30

    Molecular simulations and NMR relaxometry experiments demonstrate that pure benzene or xylene confined in isoreticular metal–organic frameworks (IRMOFs) exhibit true vapor–liquid phase equilibria where the effective critical point may be reduced by tuning the structure of the MOF. Our results are consistent with vapor and liquid phases extending over many MOF unit cells. These results are counterintuitive since the MOF pore diameters are approximately the same length scale as the adsorbate molecules. Lastly, as applications of these materials in catalysis, separations, and gas storage rely on the ability to tune the properties of adsorbed molecules, we anticipate that the ability to systematically control the critical point, thereby preparing spatially inhomogeneous local adsorbate densities, could add a new design tool for MOF applications.

  1. Nanoporous Materials Can Tune the Critical Point of a Pure Substance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Braun, Efrem; Chen, Joseph J.; Schnell, Sondre K.; Lin, Li-Chiang; Reimer, Jeffrey A.; Smit, Berend

    2015-09-30

    Molecular simulations and NMR relaxometry experiments demonstrate that pure benzene or xylene confined in isoreticular metal–organic frameworks (IRMOFs) exhibit true vapor–liquid phase equilibria where the effective critical point may be reduced by tuning the structure of the MOF. Our results are consistent with vapor and liquid phases extending over many MOF unit cells. These results are counterintuitive since the MOF pore diameters are approximately the same length scale as the adsorbate molecules. Lastly, as applications of these materials in catalysis, separations, and gas storage rely on the ability to tune the properties of adsorbed molecules, we anticipate that the abilitymore » to systematically control the critical point, thereby preparing spatially inhomogeneous local adsorbate densities, could add a new design tool for MOF applications.« less

  2. Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels

    SciTech Connect (OSTI)

    Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

    2013-01-01

    Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

  3. Final alternatives assessment: Other contamination sources: Interim response action, South Tank Farm Plume. Final report

    SciTech Connect (OSTI)

    Not Available

    1990-08-01

    The South Tank Farm Plume (STFP) is located in the southern half of sections 1 and 2. It is a composite plume of C6H6, MEC6H5, XYLEN, DCPD, and BCHPD which is migrating from the area of tank 464A. Recent investigations have shown that the STFP is being biodegraded naturally and will not migrate into either Lake Ladora or Lower Derby Lake prior to implementation of the final remedy. Monitoring with the specific objectives of (1) Verifying the rate of migration and (2) Locating the leading edge of the plume over the time frame of the IRA is proposed as the preferred alternative action. Sections of this assessment provide information on: (1) Site description-history, previous investigations, hydrogeology, LNAPL plume; (2) IRA objectives and evaluation; and (3) Work plan of the IRA-well network, sampling frequency. Appendices include comments and responses.

  4. Natural bioreclamation of alkylbenzenes (BTEX) from a gasoline spill in methanogenic groundwater. Book chapter

    SciTech Connect (OSTI)

    Wilson, J.T.; Kampbell, D.H.; Armstrong, J.

    1994-01-01

    A spill of gasoline from underground storage tanks (USTS) at the Sleeping Bear Dunes National Lakeshore in Benzie County, Michigan, produced a plume of contamination that reached the banks of the Platte River. The plume was short (70 feet) and it had a short residence time (5 to 53 weeks). The plume was in transmissive glacial sands and gravels. The groundwater is cold (10 to 11 C), hard (alkalinity 200 to 350 milligrams/L), and well buffered (pH 6.1 to 7.6). Along the most contaminated flow path, methanogenesis, nitrate reduction, sulfate reduction, iron reduction, and oxygen respiration accepted enough electrons to destroy 30, 14, 4.2, 1.1, and 0.8 milligrams/L of benzene, toluene, ethylbenzene, and xylenes (BTEX compounds) respectively. The actual concentration of BTEX compounds consumed was 42 milligrams/L.

  5. A new neutron time-of-flight detector for fuel-areal-density measurements on OMEGA

    SciTech Connect (OSTI)

    Glebov, V. Yu. Forrest, C. J.; Marshall, K. L.; Romanofsky, M.; Sangster, T. C.; Shoup, M. J.; Stoeckl, C.

    2014-11-15

    A new neutron time-of-flight (nTOF) detector for fuel-areal-density measurements in cryogenic DT implosions was installed on the OMEGA Laser System. The nTOF detector has a cylindrical thin-wall, stainless-steel, 8-in.-diam, 4-in.-thick cavity filled with an oxygenated liquid xylene scintillator. Four gated photomultiplier tubes (PMTs) with different gains are used to measure primary DT and D{sub 2} neutrons, down-scattered neutrons in nT and nD kinematic edge regions, and to study tertiary neutrons in the same detector. The nTOF detector is located 13.4 m from target chamber center in a well-collimated line of sight. The design details of the nTOF detector, PMT optimization, and test results on OMEGA will be presented.

  6. Comparison of advanced distillation control methods. Third annual report

    SciTech Connect (OSTI)

    Riggs, J.B.

    1997-07-01

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls, feedforward from a feed composition analyzer, and decouplers. Auto Tune Variation (ATV) identification with on-line detuning for setpoint changes was used for tuning the diagonal proportional integral (PI) composition controls. In addition, robustness tests were conducted by inducting reboiler duty upsets. For single composition control, the (L, V) configuration was found to be best. For dual composition control, the optimum configuration changes from one column to another. Moreover, the use of analysis tools, such as RGA, appears to be of little value in identifying the optimum configuration for dual composition control. Using feedforward from a feed composition analyzer and using decouplers are shown to offer significant advantages for certain specific cases.

  7. Superfund Record of Decision (EPA Region 2): Sayreville Landfill site, Borough of Sayreville, Middlesex County, New Jersey (first remedial action), September 28, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-09-28

    The 35-acre Sayreville Landfill site is an inactive municipal and industrial landfill in the Borough of Sayreville, Middlesex County, New Jersey. Beginning in 1971, the landfill was used to dispose of municipal and hazardous wastes, including an estimated 50 to 150 drums containing hazardous wastes. The drums were buried in a 20-acre area of the site. In 1977, landfill operations ceased, but subsequent unauthorized dumping of hazardous waste may have occurred. In 1980, a landfill closure plan was implemented by the borough, but was not properly completed. In 1981, the State excavated 30 drums containing benzene, pesticide-, and acid-contaminated liquids. The Record of Decision (ROD) addresses remediation of onsite drummed wastes. A subsequent ROD will address further source remediation (leachate) and remediation of ground and surface waters. The primary contaminants of concern affecting the soil and debris are VOCs including benzene, toluene, and xylenes; other organics including pesticides and phenols; acids; and metals including arsenic, chromium, and lead.

  8. Permeable sorptive walls for treatment of hydrophobic organic contaminant plumes in groundwater

    SciTech Connect (OSTI)

    Grathwohl, P.; Peschik, G.

    1997-12-31

    Highly hydrophobic contaminants are easily adsorbed from aqueous solutions. Since for many of these compounds sorption increases with increasing organic carbon content natural materials such as bituminous shales and coals may be used in permeable sorptive walls. This, however, only applies if sorption is at equilibrium, which may not always be the case in groundwater treatment using a funnel-and-gate system. In contrast to the natural solids, granular activated carbons (GACs) have very high sorption capacities and reasonably fast sorption kinetics. The laboratory results show that application of GACs (e.g. F100) is economically feasible for in situ removal of polycyclic aromatic hydrocarbons (PAH) from groundwater at a former manufactured gas plant site (MGP). For less sorbing compounds (such as benzene, toluene, xylenes) a combination of adsorption and biodegradation is necessary (i.e. sorptive + reactive treatment).

  9. Pilot-Scale Silicone Process for Low-Cost Carbon Dioxide Capture

    SciTech Connect (OSTI)

    Farnum, Rachel; Perry, Robert; Wood, Benjamin

    2014-12-31

    GE Global Research is developing technology to remove carbon dioxide (CO 2) from the flue gas of coal-fired powerplants. A mixture of 3-aminopropyl end-capped polydimethylsiloxane (GAP-1m) and triethylene glycol (TEG) is the preferred CO2-capture solvent. GE Global Research was contracted by the Department of Energy to test a pilot-scale continuous CO2 absorption/desorption system using a GAP-1m/TEG mixture as the solvent. As part of that effort, an Environmental, Health, and Safety (EH&S) assessment for a CO2-capture system for a 550 MW coal-fired powerplant was conducted. Five components of the solvent, CAS#2469-55-8 (GAP-0), CAS#106214-84-0 (GAP-1-4), TEG, and methanol and xylene (minor contaminants from the aminosilicone) are included in this assessment. One by-product, GAP- 1m/SOX salt, and dodecylbenzenesulfonicacid (DDBSA) were also identified foranalysis. An EH&S assessment was also completed for the manufacturing process for the GAP-1m solvent. The chemicals associated with the manufacturing process include methanol, xylene, allyl chloride, potassium cyanate, sodium hydroxide (NaOH), tetramethyldisiloxane (TMDSO), tetramethyl ammonium hydroxide, Karstedt catalyst, octamethylcyclotetrasiloxane (D4), Aliquat 336, methyl carbamate, potassium chloride, trimethylamine, and (3-aminopropyl) dimethyl silanol. The toxicological effects of each component of both the CO2 capture system and the manufacturing process were defined, and control mechanisms necessary to comply with U.S. EH&S regulations are summarized. Engineering and control systems, including environmental abatement, are described for minimizing exposure and release of the chemical components. Proper handling and storage recommendations are made for each chemical to minimize risk to workers and the surrounding community.

  10. Tracking a defined route for O[subscript 2] migration in a dioxygen-activating diiron enzyme

    SciTech Connect (OSTI)

    Song, Woon Ju; Gucinski, Grant; Sazinsky, Matthew H.; Lippard, Stephen J. (MIT); (Pomona)

    2011-09-08

    For numerous enzymes reactive toward small gaseous compounds, growing evidence indicates that these substrates diffuse into active site pockets through defined pathways in the protein matrix. Toluene/o-xylene monooxygenase hydroxylase is a dioxygen-activating enzyme. Structural analysis suggests two possible pathways for dioxygen access through the {alpha}-subunit to the diiron center: a channel or a series of hydrophobic cavities. To distinguish which is utilized as the O{sub 2} migration pathway, the dimensions of the cavities and the channel were independently varied by site-directed mutagenesis and confirmed by X-ray crystallography. The rate constants for dioxygen access to the diiron center were derived from the formation rates of a peroxodiiron(III) intermediate, generated upon treatment of the diiron(II) enzyme with O2. This reaction depends on the concentration of dioxygen to the first order. Altering the dimensions of the cavities, but not the channel, changed the rate of dioxygen reactivity with the enzyme. These results strongly suggest that voids comprising the cavities in toluene/o-xylene monooxygenase hydroxylase are not artifacts of protein packing/folding, but rather programmed routes for dioxygen migration through the protein matrix. Because the cavities are not fully connected into the diiron active center in the enzyme resting state, conformational changes will be required to facilitate dioxygen access to the diiron center. We propose that such temporary opening and closing of the cavities may occur in all bacterial multicomponent monooxygenases to control O{sub 2} consumption for efficient catalysis. Our findings suggest that other gas-utilizing enzymes may employ similar structural features to effect substrate passage through a protein matrix.

  11. Assessment of cover systems at the Grand Junction, Colorado, uranium mill tailings pile: 1987 field measurements

    SciTech Connect (OSTI)

    Gee, G.W.; Campbell, M.D.; Freeman, H.D.; Cline, J.F.

    1989-02-01

    Four Pacific Northwest Laboratory (PNL) scientists and a technician conducted an onsite evaluation of radon gas exhalation, water content profiles, and plant and animal intrusion for a series of cover systems located on the uranium mill tailings pile at Grand Junction, Colorado. These six plots were sampled extensively down to the radon control layer (e.g., asphalt or wet clay) for soil moisture content and permeability. Radon gas emission through the surface was measured. Soil samples were collected and analyzed in the lab for particle-size distribution, particle density, bulk density, and ambient water content. Prairie dog burrows were excavated to discover the extent to which they penetrated the barriers. Plant type, density, and cover characteristics were measured.

  12. Vaporization, dispersion, and radiant fluxes from LPG spills. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    Both burning and non-burning spills of LPG (primarily propane) were studied. Vaporization rates for propane spills on soil, concrete, insulating concrete, asphalt, sod, wood, and polymer foams were measured. Thermal conductivity, heat transfer coefficients, and steady state vaporization rates were determined. Vapor concentrations were measured downwind of open propane pools 25, 100, 400, and 1600 ft/sup 2/ in area. A Gaussian dispersion model modified for area sources provided a good correlation of measured concentrations. Emitted and incident radiant fluxes from propane fires were measured. Simplified flame radiation models were adequate for predicting radiant fluxes; the maximum effective flux emitted at the flame surface was about 50,000 Btu/h-ft/sup 2/. A few tests in which propane was sprayed into the air showed that at moderately high spray rates all the propane flashed to vapor or atomized; no liquid collected on the ground.

  13. Compilation of air-pollutant emission factors. Volume 1. Stationary-point and area sources, Fourth Edition. Supplement A

    SciTech Connect (OSTI)

    Joyner, W.M.

    1986-10-01

    In the supplement to the Fourth Edition of AP-42, new or revised emissions data are presented for Bituminous and subbituminous coal combustion; Anthracite coal combustion; Fuel oil combustion; Natural gas combustion; Wood waste combustion in boilers; Lignite combustion; Sodium carbonate; Primary aluminum production; Coke production; Primary copper smelting; Ferroalloy production; Iron and steel production; Primary lead smelting; Zinc smelting; Secondary aluminum operations; Gray iron foundries; Secondary lead smelting; Asphaltic concrete plants; Bricks and related clay products; Portland cement manufacturing; Concrete batching; Glass manufacturing; Lime manufacturing; Construction aggregate processing; Taconite ore processing; Western surface coal mining; Chemical wood pulping; Appendix C.1, Particle-size distribution data and sized emission factors for selected sources; and Appendix C.2, Generalized particle size distributions.

  14. Hanford prototype-barrier status report: FY 1997

    SciTech Connect (OSTI)

    Ward, A.L.; Gee, G.W.; Link, S.O.

    1997-12-01

    An above-grade surface barrier consisting of a vegetated soil-cover, surrounded by gravel and rock side slopes, is being tested for the US Department of Energy (DOE). It is part of a treatability study at the 200-BP-1 Operable Unit in the 200 East Area of the Hanford Site, near Richland, Washington. The surface barrier, constructed in 1994, covers 2.5 ha (6.9 acre) of land surface and is situated over an inactive liquid-waste disposal crib. A set of under drains, built into the barrier using curbed asphalt, allows precise measurement of drainage from the soil cover and the side slopes. The treatability test includes measurements of water balance, wind and water erosion, subsidence, plant growth, and plant and animal intrusion. The test compares the performance of the barrier under ambient and simulated climate change (elevated precipitation) conditions. This report documents findings from the third year of testing.

  15. Characterization of Slow Orbit Motion in the SPEAR3

    SciTech Connect (OSTI)

    Sunilkumar, Nikita; Gassner, Georg; Safranek, James; Yan, Yiton; /SLAC

    2012-07-09

    SPEAR3 is a third-generation synchrotron light source storage ring. The beam stability requirements are {approx}10% of the beam size, which is about 1 micron in the vertical plane. Hydrostatic level system (HLS) measurements show that the height of the SPEAR3 tunnel floor varies by tens of microns daily. We present analysis of the HLS data, including accounting for common-mode tidal motion. We discuss the results of experiments done to determine the primary driving source of ground motion. We painted the accelerator tunnel walls white; we temporarily installed Mylar over the asphalt in the center of the accelerator; and we put Mylar over a section of the tunnel walls.

  16. Vaporization, dispersion, and radiant fluxes from LPG spills. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1982-05-01

    Both burning and non-burning spills of LPG (primarily propane) were studied. Vaporization rates for propane spills on soil, concrete, insulating concrete, asphalt, sod, wood, and polymer foams were measured. Thermal conductivity, heat transfer coefficients, and steady state vaporization rates were determined. Vapor concentrations were measured downwind of open propane pools and a Gaussian dispersion model modified for area sources provided a good correlation of measured concentrations. Emitted and incident radiant fluxes from propane fires were measured. Simplified flame radiation models were adequate for predicting radiant fluxes. Tests in which propane was sprayed into the air showed that at moderately high spray rates all the propane flashed to vapor or atomized; no liquid collected on the ground.

  17. Superfund record of decision (EPA Region 1): Fletcher`s Paint Works and Storage, Milford, NH, September 30, 1998

    SciTech Connect (OSTI)

    1999-03-01

    This decision document presents the selected remedial action for the Fletcher`s Paint Works and Storage Facility Superfund Site (Site) located in Milford, New Hampshire. This ROD sets forth the selected remedy for Operable Unit On at the Fletcher`s Paint Site, which involves the excavation and on-site treatment of principal threat wastes which consist of primarily PCB contaminated soils, the replacement of those treated soils at the Site, and placement of a soil and asphalt cover over the residual low level threat wastes. The selected remedy also includes monitored natural attenuation of the contaminated groundwater in the overburdened and bedrock aquifers and institutional controls to prevent future ingestion of contaminated groundwater, as well as restrictions on the use and assess to the subsurface soils at the Elm Street Site.

  18. Nuclear waste management. Quarterly progress report, October through December 1980

    SciTech Connect (OSTI)

    Chikalla, T.D.; Powell, J.A.

    1981-03-01

    Progress reports and summaries are presented under the following headings: high-level waste process development; alternative waste forms; nuclear waste materials characterization center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of radionuclides in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; high level waste form preparation; development of backfill material; development of structural engineered barriers; ONWI disposal charge analysis; spent fuel and fuel component integrity program; analysis of spent fuel policy implementation; analysis of postulated criticality events in a storage array of spent LWR fuel; asphalt emulsion sealing of uranium tailings; liner evaluation for uranium mill tailings; multilayer barriers for sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; revegetation of inactive uranium tailing sites; verification instrument development.

  19. Rockwell International Hot Laboratory decontamination and dismantlement interim progress report 1987-1996

    SciTech Connect (OSTI)

    1997-05-06

    OAK A271 Rockwell International Hot Laboratory decontamination and dismantlement interim progress report 1987-1996. The Rockwell International Hot Laboratory (RIHL) is one of a number of former nuclear facilities undergoing decontamination and decommissioning (D&D) at the Santa Susana Field Laboratory (SSFL). The RIHL facility is in the later stages of dismantlement, with the final objective of returning the site location to its original natural state. This report documents the decontamination and dismantlement activities performed at the facility over the time period 1988 through 1996. At this time, the support buildings, all equipment associated with the facility, and the entire above-ground structure of the primary facility building (Building 020) have been removed. The basement portion of this building and the outside yard areas (primarily asphalt and soil) are scheduled for D&D activities beginning in 1997.

  20. Alternative technologies to optical monitoring systems relating to regulatory compliance (Title V)

    SciTech Connect (OSTI)

    Craney, B.

    1995-12-31

    Due to the development of Title III and Title V of the Clean Air Act Amendments and public awareness of environmentally safe processes, particulate emissions monitoring has become a subject of great importance to the manufacturing sector. An increasing number of monitoring devices are available, and when used in the correct applications, can accurately monitor particulate emissions. This allows identification of a system problem before emissions can reach the stack and trigger non-compliance. This paper focuses on the most widely used technologies for continuous particulate monitoring, specifically the CPM product line, which has been developed to overcome common problems associated with emissions monitoring equipment. Technical data is presented in regard to the CPM operation as well as a case study of a CPM monitor in the asphalt industry.

  1. Unusual superheater tube wastage associated with carburization

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Noreno, A. ); Martinez, L. . Programa de Corrosion del Golfo de Mexico)

    1994-12-01

    The effects of operational power changes on the corrosion of ASTM A 213 type 321H (UNS S32109) stainless steel tubes in a steam superheater were studied. The fuel oil consumed in the plant is high in sulfur, vanadium, and asphalt content. After 107,000 hours of service, the tubes were seriously corroded and developed cracking of the oxide layer. The cracking was associated with frequent temperature changes. Bursts of carbon coke and soot particles deposited on tube surfaces and introduced a carburization process in the steel matrix. Carbon-rich deposits formed in the grain boundaries of the austenitic metal matrix. A carburization-corrosion process caused the intergranular wastage of the steel near the exposed surfaces.

  2. 01-27-05.cdr

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    30/05 - 02/05/05: Hanford - 3 INEEL - 2 LLNL - 3 RFETS - 16 (subject to change) 3,290 total shipments received as of 01/26/05 Disposal Waste disposed as of 01/26/05: 4,242 standard waste boxes 1,285 ten-drum overpacks 59,206 waste drums 26,191 cubic meters Operations: CCP teams make pit stop at INEEL Waste retrieval moves from asphalt to dirt ... TRU TeamWorks is a biweekly e-newsletter for the Waste Isolation Pilot Plant team D E P A R T M E N T O F E N E R G Y U N I T E D S T A T E S O F A M E

  3. The Equivalent Thermal Resistance of Tile Roofs with and without Batten Systems

    SciTech Connect (OSTI)

    Miller, William A

    2013-01-01

    Clay and concrete tile roofs were installed on a fully instrumented attic test facility operating in East Tennessee s climate. Roof, attic and deck temperatures and heat flows were recorded for each of the tile roofs and also on an adjacent attic cavity covered with a conventionally pigmented and direct-nailed asphalt shingle roof. The data were used to benchmark a computer tool for simulation of roofs and attics and the tool used to develop an approach for computing an equivalent seasonal R-value for sub-tile venting. The approach computed equal heat fluxes through the ceilings of roofs having different combinations of surface radiation properties and or building constructions. A direct nailed shingle roof served as a control for estimating the equivalent thermal resistance of the air space. Simulations were benchmarked to data in the ASHRAE Fundamentals for the thermal resistance of inclined and closed air spaces.

  4. Assessment of Radiation Background Variation for Moving Detection Systems

    SciTech Connect (OSTI)

    Miller, James Christopher; Rennie, John Alan; Toevs, James Waldo; Wallace, Darrin J.; Abhold, Mark Edward

    2015-07-13

    The introduction points out that radiation backgrounds fluctuate across very short distances: factors include geology, soil composition, altitude, building structures, topography, and other manmade structures; and asphalt and concrete can vary significantly over short distances. Brief descriptions are given of the detection system, experimental setup, and background variation measurements. It is concluded that positive and negative gradients can greatly reduce the detection sensitivity of an MDS: negative gradients create opportunities for false negatives (nondetection), and positive gradients create a potentially unacceptable FAR (above 1%); the location of use for mobile detection is important to understand; spectroscopic systems provide more information for screening out false alarms and may be preferred for mobile use; and mobile monitor testing at LANL accounts for expected variations in the background.

  5. Nuclear waste management. Quarterly progress report, April-June 1980

    SciTech Connect (OSTI)

    Platt, A.M.; Powell, J.A.

    1980-09-01

    The status of the following programs is reported: high-level waste immobilization; alternative waste forms; Nuclear Waste Materials Characterization Center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of fission products in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; systems study on engineered barriers; criteria for defining waste isolation; spent fuel and fuel pool component integrity program; analysis of spent fuel policy implementation; asphalt emulsion sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; and development of backfill material.

  6. Third-Party Evaluation of Petro Tex Hydrocarbons, LLC, ReGen Lubricating Oil Re-refining Process

    SciTech Connect (OSTI)

    Compere, A L; Griffith, William {Bill} L

    2009-04-01

    This report presents an assessment of market, energy impact, and utility of the PetroTex Hydrocarbons, LLC., ReGen process for re-refining used lubricating oil to produce Group I, II, and III base oils, diesel fuel, and asphalt. PetroTex Hydrocarbons, LLC., has performed extensive pilot scale evaluations, computer simulations, and market studies of this process and is presently evaluating construction of a 23 million gallon per year industrial-scale plant. PetroTex has obtained a 30 acre site in the Texas Industries RailPark in Midlothian Texas. The environmental and civil engineering assessments of the site are completed, and the company has been granted a special use permit from the City of Midlothian and air emissions permits for the Texas Commission on Environmental Quality.

  7. Testing and monitoring plan for the permanent isolation surface barrier prototype

    SciTech Connect (OSTI)

    Gee, G.W.; Cadwell, L.L.; Freeman, H.D.; Ligotke, M.W.; Link, S.O.; Romine, R.A.; Walters, W.H. Jr.

    1993-06-01

    This document is a testing and monitoring plan for a prototype barrier to be constructed at the Hanford Site in 1993. The prototype barrier is an aboveground structure engineered to demonstrate the basic features of an earthen cover system, designed to permanently isolate waste from the biosphere. These features include multiple layers of soil and rock materials and a low-permeability asphalt sublayer. The surface of the barrier consists of silt loam soil, vegetated with plants. The barrier sides are reinforced with rock or coarse earthen-fill to protect against wind and water erosion. The sublayers inhibit plant and animal intrusion and percolation of water. A series of tests will be conducted on the prototype over the next several years to evaluate barrier performance under extreme climatic conditions.

  8. A Texas project illustrates the benefits of integrated gasification

    SciTech Connect (OSTI)

    Philcox, J.; Fenner, G.W.

    1997-07-14

    Gasification can be an attractive option for converting a variety of petroleum feedstocks to chemicals. Natural gas is commonly sued to produce acetic acid, isocyanates, plastics, and fibers. But low-cost, bottom-of-the-barrel feeds, such as vacuum resid, petroleum coke, and asphaltenes, also can be used. In any case, gasification products include synthesis gas, carbon monoxide, hydrogen, steam, carbon dioxide, and power. The more a gasification facility is integrated with utilities and other non-core operations of a production complex, the more economical the products are for all consumers. The paper discusses gasification of natural gas, light hydrocarbons (ethane, propanes, and butanes), and heavy hydrocarbons (distillates, heavy residues, asphalts, coals, petroleum coke). The paper then describes a Texas City Gasification Project, which gasifies methane to produce carbon monoxide, hydrogen, and alcohol. The plant is integrated with a cogeneration plant. Economics are discussed.

  9. Accelerated aging tests of liners for uranium mill tailings disposal

    SciTech Connect (OSTI)

    Barnes, S.M.; Buelt, J.L.; Hale, V.Q.

    1981-11-01

    This document describes the results of accelerated aging tests to determine the long-term effectiveness of selected impoundment liner materials in a uranium mill tailings environment. The study was sponsored by the US Department of Energy under the Uranium Mill Tailings Remedial Action Project. The study was designed to evaluate the need for, and the performance of, several candidate liners for isolating mill tailings leachate in conformance with proposed Environmental Protection Agency and Nuclear Regulatory Commission requirements. The liners were subjected to conditions known to accelerate the degradation mechanisms of the various liners. Also, a test environment was maintained that modeled the expected conditions at a mill tailings impoundment, including ground subsidence and the weight loading of tailings on the liners. A comparison of installation costs was also performed for the candidate liners. The laboratory testing and cost information prompted the selection of a catalytic airblown asphalt membrane and a sodium bentonite-amended soil for fiscal year 1981 field testing.

  10. Buildings Energy Data Book: 5.1 Building Materials/Insulation

    Buildings Energy Data Book [EERE]

    5 Properties of Cool Roofing Materials (1) Asphalt Shingles Shasta White 0.26 0.91 Generic White 0.25 0.91 Generic Grey 0.22 0.91 Light Brown 0.19 0.91 Medium Brown 0.12 0.91 Generic Black 0.05 0.91 White Coatings White Coating (1 coat, 8 mil) 0.80 0.91 White Coating (2 coats, 20 mil) 0.85 0.91 Aluminum Coatings Aluminum 0.61 0.25 Fibered on Black 0.40 0.56 Membranes Gray EPDM (4) 0.23 0.87 White EPDM (4) 0.69 0.87 T-EPDM (4) 0.81 0.92 Light Gravel on Built-Up Roof 0.34 0.90 Metal Roof New, Bare