Sample records for x-ray diffraction imaging

  1. Biological imaging by soft x-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shapiro, D. [Stony Brook Univ., Stony Brook, NY (United States); Thibault, P. [Cornell Univ., Ithaca, NY (United States); Beetz, T. [Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab., Upton, NY (United States). Center for Functional Nanomaterials; Elser, V. [Cornell Univ., Ithaca, NY (United States); Howells, M. [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source; Jacobsen, C. [Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab., Upton, NY (United States). Center for Functional Nanomaterials; Kirz, J. [Stony Brook Univ., Stony Brook, NY (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source; Lima, E. [Stony Brook Univ., Stony Brook, NY (United States); Miao, H. [Stony Brook Univ., Stony Brook, NY (United States); Neiman, A. M. [State Univ. of New York at Stony Brook, NY (United States); Sayre, D. [Stony Brook Univ., Stony Brook, NY (United States)

    2005-10-25T23:59:59.000Z

    We have used the method of x-ray diffraction microscopy to image the complex-valued exit wave of an intact and unstained yeast cell. The images of the freeze-dried cell, obtained by using 750-eV x-rays from different angular orientations, portray several of the cell's major internal components to 30-nm resolution. The good agreement among the independently recovered structures demonstrates the accuracy of the imaging technique. To obtain the best possible reconstructions, we have implemented procedures for handling noisy and incomplete diffraction data, and we propose a method for determining the reconstructed resolution. This work represents a previously uncharacterized application of x-ray diffraction microscopy to a specimen of this complexity and provides confidence in the feasibility of the ultimate goal of imaging biological specimens at 10-nm resolution in three dimensions.

  2. Biological Imaging by Soft X-ray Diffraction Microscopy

    SciTech Connect (OSTI)

    Shapiro,D.; Thibault, P.; Beetz, T.; Elser, V.; Howells, M.; Jacobsen, C.; Kirz, J.; Lima, E.; Miao, H.; et al.

    2005-01-01T23:59:59.000Z

    We have used the method of x-ray diffraction microscopy to image the complex-valued exit wave of an intact and unstained yeast cell. The images of the freeze-dried cell, obtained by using 750-eV x-rays from different angular orientations, portray several of the cell's major internal components to 30-nm resolution. The good agreement among the independently recovered structures demonstrates the accuracy of the imaging technique. To obtain the best possible reconstructions, we have implemented procedures for handling noisy and incomplete diffraction data, and we propose a method for determining the reconstructed resolution. This work represents a previously uncharacterized application of x-ray diffraction microscopy to a specimen of this complexity and provides confidence in the feasibility of the ultimate goal of imaging biological specimens at 10-nm resolution in three dimensions.

  3. High spatial resolution X-ray and gamma ray imaging system using diffraction crystals

    DOE Patents [OSTI]

    Smither, Robert K. (Hinsdale, IL)

    2011-05-17T23:59:59.000Z

    A method and a device for high spatial resolution imaging of a plurality of sources of x-ray and gamma-ray radiation are provided. The device comprises a plurality of arrays, with each array comprising a plurality of elements comprising a first collimator, a diffracting crystal, a second collimator, and a detector.

  4. Method for characterizing mask defects using image reconstruction from X-ray diffraction patterns

    DOE Patents [OSTI]

    Hau-Riege, Stefan Peter (Fremont, CA)

    2007-05-01T23:59:59.000Z

    The invention applies techniques for image reconstruction from X-ray diffraction patterns on the three-dimensional imaging of defects in EUVL multilayer films. The reconstructed image gives information about the out-of-plane position and the diffraction strength of the defect. The positional information can be used to select the correct defect repair technique. This invention enables the fabrication of defect-free (since repaired) X-ray Mo--Si multilayer mirrors. Repairing Mo--Si multilayer-film defects on mask blanks is a key for the commercial success of EUVL. It is known that particles are added to the Mo--Si multilayer film during the fabrication process. There is a large effort to reduce this contamination, but results are not sufficient, and defects continue to be a major mask yield limiter. All suggested repair strategies need to know the out-of-plane position of the defects in the multilayer.

  5. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  6. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  7. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  8. Protein crystallography: From X-ray diffraction spots to a three dimensional image

    SciTech Connect (OSTI)

    Terwilliger, T.C.; Berendzen, J.

    1998-02-25T23:59:59.000Z

    Proteins are remarkable molecular machines that are essential for life. They can do many things ranging from the precise control of blood clotting to synthesizing complex organic compounds. Pictures of protein molecules are in high demand in biotechnology because they are important for applications such as drug discovery and for engineering enzymes for commercial use. X-ray crystallography is the most common method for determining the three-dimensional structures of protein molecules. When a crystal of a protein is placed in an X-ray beam, scattering of X-rays off the ordered molecules produces a diffraction pattern that can be measured on a position-sensitive CCD or image-plate detector. Protein crystals typically contain thousands of atoms and the diffraction data are generally measured to relatively low resolution. Consequently the direct methods approaches generally cannot be applied. Instead, if the crystal is modified by adding metal atoms at specific sites or by tuning the wavelength of the X-rays to cross an absorption edge of a metal atom in the crystal, then the information from these additional measurements is sufficient to first identify the /locations of the metal atoms. This information is then used along with the diffraction data to make a three-dimensional picture of electron densities. This picture can be used to determine the position of most or all of the atoms in the protein.

  9. High resolution x-ray and gamma ray imaging using diffraction lenses with mechanically bent crystals

    DOE Patents [OSTI]

    Smither, Robert K. (Hinsdale, IL)

    2008-12-23T23:59:59.000Z

    A method for high spatial resolution imaging of a plurality of sources of x-ray and gamma-ray radiation is provided. High quality mechanically bent diffracting crystals of 0.1 mm radial width are used for focusing the radiation and directing the radiation to an array of detectors which is used for analyzing their addition to collect data as to the location of the source of radiation. A computer is used for converting the data to an image. The invention also provides for the use of a multi-component high resolution detector array and for narrow source and detector apertures.

  10. Development of an adaptable coherent x-ray diffraction microscope with the emphasis on imaging hydrated specimens

    SciTech Connect (OSTI)

    Nam, Daewoong [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan) [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan); Department of Physics, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of); Park, Jaehyun; Shimada, Hiroki; Kim, Sangsoo; Kim, Sunam; Kohmura, Yoshiki; Ishikawa, Tetsuya; Song, Changyong [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan)] [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan); Gallagher-Jones, Marcus [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan) [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan); Institute of Integrative Biology, University of Liverpool, Liverpool L69 7ZB (United Kingdom)

    2013-11-15T23:59:59.000Z

    This paper describes the development of a versatile coherent x-ray diffraction microscope capable of imaging biological specimens in solution. The microscope is a flexible platform accommodating various conditions, from low vacuum (10{sup ?2} Pa) to helium gas filled ambient pressure. This flexibility greatly expands the application area, from in situ materials science to biology systems in their native state, by significantly relaxing restrictions to the sample environment. The coherent diffraction microscope has been used successfully to image a yeast cell immersed in buffer solution. We believe that the design of this coherent diffraction microscope can be directly adapted to various platforms such as table top soft x-ray laser, synchrotron x-ray sources, and x-ray free electron laser with minor relevant adjustments.

  11. Diffraction imaging for in-situ characterization of double-crystal x-ray monochromators

    E-Print Network [OSTI]

    Stoupin, Stanislav; Heald, Steve M; Brewe, Dale; Meron, Mati

    2015-01-01T23:59:59.000Z

    Imaging of the Bragg reflected x-ray beam is proposed and validated as an in-situ method for characterization of performance of double-crystal monochromators under the heat load of intense synchrotron radiation. A sequence of images is collected at different angular positions on the reflectivity curve of the second crystal and analyzed. The method provides rapid evaluation of the wavefront of the exit beam, which relates to local misorientation of the crystal planes along the beam footprint on the thermally distorted first crystal. The measured misorientation can be directly compared to results of finite element analysis. The imaging method offers an additional insight on the local intrinsic crystal quality over the footprint of the incident x-ray beam.

  12. Design and imaging performance of achromatic diffractive/refractive X-ray and Gamma-ray Fresnel lenses

    E-Print Network [OSTI]

    Gerald K. Skinner

    2004-07-21T23:59:59.000Z

    Achromatic combinations of a diffractive Phase Fresnel Lens and a refractive correcting element have been proposed for X-ray and gamma-ray astronomy and for microlithography, but considerations of absorption often dictate that the refractive component be given a stepped profile, resulting in a double Fresnel lens. The imaging performance of corrected Fresnel lenses, with and without `stepping' is investigated and the trade-off between resolution and useful bandwidth in different circumstances is discussed. Provided the focal ratio is large, correction lenses made of low atomic number materials can be used with X-rays in the range approximately 10--100 keV without stepping. The use of stepping extends the possibility of correction to higher aperture systems, to energies as low as a few kilo electron volts and to gamma-rays of $\\sim$ mega electron volt energy.

  13. Progress in Three-Dimensional Coherent X-Ray Diffraction Imaging

    SciTech Connect (OSTI)

    Marchesini, S; Chapman, H N; Barty, A; Howells, M R; Cui, C; Spence, J H; Weierstall, U; Noy, A; Hau-Riege, S P; Kinney, J M; Shapiro, D; Beetz, T; Jacobsen, C; Lima, E; Minor, A M; He, H

    2005-09-30T23:59:59.000Z

    The Fourier inversion of phased coherent diffraction patterns offers images without the resolution and depth-of-focus limitations of lens-based tomographic systems. We report on our recent experimental images inverted using recent developments in phase retrieval algorithms, and summarize efforts that led to these accomplishments. These include ab-initio reconstruction of a two-dimensional test pattern, infinite depth of focus image of a thick object, and its high-resolution ({approx}10 nm resolution) three-dimensional image. Developments on the structural imaging of low density aerogel samples are discussed.

  14. X-ray Diffraction and Multi-Frame Phase Contrast Imaging Diagnostics for IMPULSE at the Advanced Photon Source

    SciTech Connect (OSTI)

    Iverson, Adam [National Security Technologies, LLC; Carlson, Carl [National Security Technologies, LLC; Young, Jason [National Security Technologies, LLC; Curtis, Alden [National Security Technologies, LLC; Jensen, Brian [Los Alamos National Laboratory; Ramos, Kyle [Los Alamos National Laboratory; Yeager, John [Los Alamos National Laboratory; Montgomery, David [Los Alamos National Laboratory; Fezza, Kamel [Argonne National Laboratory

    2013-07-08T23:59:59.000Z

    The diagnostic needs of any dynamic loading platform present unique technical challenges that must be addressed in order to accurately measure in situ material properties in an extreme environment. The IMPULSE platform (IMPact system for Ultrafast Synchrotron Experiments) at the Advanced Photon Source (APS) is no exception and, in fact, may be more challenging, as the imaging diagnostics must be synchronized to both the experiment and the 60 ps wide x-ray bunches produced at APS. The technical challenges of time-resolved x-ray diffraction imaging and high-resolution multi-frame phase contrast imaging (PCI) are described in this paper. Example data from recent IMPULSE experiments are shown to illustrate the advances and evolution of these diagnostics with a focus on comparing the performance of two intensified CCD cameras and their suitability for multi-frame PCI. The continued development of these diagnostics is fundamentally important to IMPULSE and many other loading platforms and will benefit future facilities such as the Dynamic Compression Sector at APS and MaRIE at Los Alamos National Laboratory.

  15. Femtosecond diffractive imaging with a soft-X-ray free-electron laser (CXIDB ID 3)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chapman, H. N.

    The diffraction pattern of this entry corresponds to the one shown in **figure 2a** of the corresponding citation.

  16. Femtosecond diffractive imaging with a soft-X-ray free-electron laser

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist. CategoryFebruaryFebruary 17,Time-Delay X-ray Holography

  17. X-Ray Diffraction Microscopy of Magnetic Structures

    SciTech Connect (OSTI)

    Turner, J.; Lima, E.; Huang, X.; Krupin, O.; Seu, K.; Parks, D.; Kevan, S.; Kisslinger, K.; McNulty, I.; Gambino, R.; Mangin, S.; Roy, S. and Fischer, P.

    2011-07-14T23:59:59.000Z

    We report the first proof-of-principle experiment of iterative phase retrieval from magnetic x-ray diffraction. By using the resonant x-ray excitation process and coherent x-ray scattering, we show that linearly polarized soft x rays can be used to image both the amplitude and the phase of magnetic domain structures. We recovered the magnetic structure of an amorphous terbium-cobalt thin film with a spatial resolution of about 75 nm at the Co L{sub 3} edge at 778 eV. In comparison with soft x-ray microscopy images recorded with Fresnel zone plate optics at better than 25 nm spatial resolution, we find qualitative agreement in the observed magnetic structure.

  18. A Super-high Angular Resolution Principle for Coded-mask X-ray Imaging Beyond the Diffraction Limit of Single Pinhole

    E-Print Network [OSTI]

    Chen Zhang; Shuang Nan Zhang

    2008-06-25T23:59:59.000Z

    High angular resolution X-ray imaging is always demanded by astrophysics and solar physics, which can be realized by coded-mask imaging with very long mask-detector distance in principle. Previously the diffraction-interference effect has been thought to degrade coded-mask imaging performance dramatically at low energy end with very long mask-detector distance. In this work the diffraction-interference effect is described with numerical calculations, and the diffraction-interference cross correlation reconstruction method (DICC) is developed in order to overcome the imaging performance degradation. Based on the DICC, a super-high angular resolution principle (SHARP) for coded-mask X-ray imaging is proposed. The feasibility of coded mask imaging beyond the diffraction limit of single pinhole is demonstrated with simulations. With the specification that the mask element size of 50* 50 square micrometers and the mask-detector distance of 50 m, the achieved angular resolution is 0.32 arcsec above about 10 keV, and 0.36 arcsec at 1.24 keV where diffraction can not be neglected. The on-axis source location accuracy is better than 0.02 arcsec. Potential applications for solar observations and wide-field X-ray monitors are also shortly discussed.

  19. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells with Soft X-Rays Lensless Imaging of Whole Biological Cells with Soft X-Rays Print Wednesday, 26 May 2010 00:00 A team of scientists has used x-ray diffraction...

  20. Nanofabrication of Diffractive X-ray Optics for Synchrotrons...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the soft x-ray range and down to 15 nm in the multi keV range. For use at x-ray free-electron laser (XFEL) sources, diffractive optics must be capable of withstanding extreme...

  1. Soft X-Ray Diffraction Microscopy of a Frozen Hydrated Yeast Cell

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Xiaojing; Nelson, Johanna; Kirz, Janos; Lima, Enju; Marchesini, Stefano; Miao, Huijie; Neiman, Aaron; Shapiro, David; Steinbrener, Jan; Stewart, Andrew; Turner, Joshua; Jacobsen, Chris

    2009-11-01T23:59:59.000Z

    We report the first image of an intact, frozen hydrated eukaryotic cell using x-ray diffraction microscopy, or coherent x-ray diffraction imaging. By plunge freezing the specimen in liquid ethane and maintaining it below -170 degrees C, artifacts due to dehydration, ice crystallization, and radiation damage are greatly reduced. In this example, coherent diffraction data using 520 eV x rays were recorded and reconstructed to reveal a budding yeast cell at a resolution better than 25 nm. This demonstration represents an important step towards high resolution imaging of cells in their natural, hydrated state, without limitations imposed by x-ray optics.

  2. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X-Ray Imaging in Reflection Print The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs...

  3. Transient x-ray diffraction and its application to materials science and x-ray optics

    SciTech Connect (OSTI)

    Hauer, A.A.; Kopp, R.; Cobble, J.; Kyrala, G.; Springer, R. [and others

    1997-12-01T23:59:59.000Z

    Time resolved x-ray diffraction and scattering have been applied to the measurement of a wide variety of physical phenomena from chemical reactions to shock wave physics. Interest in this method has heightened in recent years with the advent of versatile, high power, pulsed x-ray sources utilizing laser plasmas, electron beams and other methods. In this article, we will describe some of the fundamentals involved in time resolved x-ray diffraction, review some of the history of its development, and describe some recent progress in the field. In this article we will emphasize the use of laser-plasmas as the x-ray source for transient diffraction.

  4. A camera for coherent diffractive imaging and holography with a soft-X-ray free electron laser

    SciTech Connect (OSTI)

    Bajt, S; Chapman, H N; Spiller, E; Alameda, J; Woods, B; Frank, M; Bogan, M J; Barty, A; Boutet, S; Marchesini, S; Hau-Riege, S P; Hajdu, J; Shapiro, D

    2007-09-24T23:59:59.000Z

    We describe a camera to record coherent scattering patterns with a soft-X-ray free-electron laser. The camera consists of a laterally-graded multilayer mirror which reflects the diffraction pattern onto a CCD detector. The mirror acts as a bandpass filter both for wavelength and angle, which isolates the desired scattering pattern from non-sample scattering or incoherent emission from the sample. The mirror also solves the particular problem of the extreme intensity of the FEL pulses, which are focused to greater than 10{sup 14} W/cm{sup 2}. The strong undiffracted pulse passes through a hole in the mirror and propagates on to a beam dump at a distance behind the instrument rather than interacting with a beamstop placed near the CCD. The camera concept is extendable for the full range of the fundamental wavelength of the FLASH FEL (i.e. between 6 nm and 60 nm) and into the water window. We have fabricated and tested various multilayer mirrors for wavelengths of 32 nm, 16 nm, 13.5 nm, and 4.5 nm. At the shorter wavelengths mirror roughness must be minimized to reduce scattering from the mirror. We have recorded over 30,000 diffraction patterns at the FLASH free-electron laser with no observable mirror damage or degradation of performance.

  5. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lensless Imaging of Whole Biological Cells with Soft X-Rays Print A team of scientists has used x-ray diffraction microscopy at ALS Beamline 9.0.1 to make images of whole yeast...

  6. Residual stress measurement using X-ray diffraction 

    E-Print Network [OSTI]

    Anderoglu, Osman

    2005-02-17T23:59:59.000Z

    .3.6.2. Synchrotron Diffraction.........................................................................9 II. FUNDAMENTAL CONCEPTS IN X-RAY DIFFRACTION.....................................12 2.1. X-ray Source... radiations ...................................................................16 Table 2.2 Structure factors and reflection conditions ...................................................20 Table 4.1 Chemical composition of SS316...

  7. In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries Johanna Information ABSTRACT: Rechargeable lithium-sulfur (Li-S) batteries hold great potential for high of these batteries for commercial use. The two primary obstacles are the solubility of long chain lithium

  8. X-ray imaging crystal spectrometer for extended X-ray sources

    DOE Patents [OSTI]

    Bitter, Manfred L. (Princeton, NJ); Fraenkel, Ben (Jerusalem, IL); Gorman, James L. (Bordentown, NJ); Hill, Kenneth W. (Lawrenceville, NJ); Roquemore, A. Lane (Cranbury, NJ); Stodiek, Wolfgang (Princeton, NJ); von Goeler, Schweickhard E. (Princeton, NJ)

    2001-01-01T23:59:59.000Z

    Spherically or toroidally curved, double focusing crystals are used in a spectrometer for X-ray diagnostics of an extended X-ray source such as a hot plasma produced in a tokomak fusion experiment to provide spatially and temporally resolved data on plasma parameters using the imaging properties for Bragg angles near 45. For a Bragg angle of 45.degree., the spherical crystal focuses a bundle of near parallel X-rays (the cross section of which is determined by the cross section of the crystal) from the plasma to a point on a detector, with parallel rays inclined to the main plain of diffraction focused to different points on the detector. Thus, it is possible to radially image the plasma X-ray emission in different wavelengths simultaneously with a single crystal.

  9. High-resolution ab initio three-dimensional x-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chapman, Henry N.; Barty, Anton; Marchesini, Stefano; Noy, Aleksandr; Hau-Riege, Stefan P.; Cui, Congwu; Howells, Malcolm R.; Rosen, Rachel; He, Haifeng; Spence, John C.; et al

    2006-01-01T23:59:59.000Z

    Coherent x-ray diffraction microscopy is a method of imaging nonperiodic isolated objects at resolutions limited, in principle, by only the wavelength and largest scattering angles recorded. We demonstrate x-ray diffraction imaging with high resolution in all three dimensions, as determined by a quantitative analysis of the reconstructed volume images. These images are retrieved from the three-dimensional diffraction data using no a priori knowledge about the shape or composition of the object, which has never before been demonstrated on a nonperiodic object. We also construct two-dimensional images of thick objects with greatly increased depth of focus (without loss of transverse spatialmore »resolution). These methods can be used to image biological and materials science samples at high resolution with x-ray undulator radiation and establishes the techniques to be used in atomic-resolution ultrafast imaging at x-ray free-electron laser sources.« less

  10. High-resolution ab initio Three-dimensional X-ray Diffraction Microscopy

    SciTech Connect (OSTI)

    Chapman, H N; Barty, A; Marchesini, S; Noy, A; Cui, C; Howells, M R; Rosen, R; He, H; Spence, J H; Weierstall, U; Beetz, T; Jacobsen, C; Shapiro, D

    2005-08-19T23:59:59.000Z

    Coherent X-ray diffraction microscopy is a method of imaging non-periodic isolated objects at resolutions only limited, in principle, by the largest scattering angles recorded. We demonstrate X-ray diffraction imaging with high resolution in all three dimensions, as determined by a quantitative analysis of the reconstructed volume images. These images are retrieved from the 3D diffraction data using no a priori knowledge about the shape or composition of the object, which has never before been demonstrated on a non-periodic object. We also construct 2D images of thick objects with infinite depth of focus (without loss of transverse spatial resolution). These methods can be used to image biological and materials science samples at high resolution using X-ray undulator radiation, and establishes the techniques to be used in atomic-resolution ultrafast imaging at X-ray free-electron laser sources.

  11. High-resolution ab initio three-dimensional x-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chapman, Henry N.; Barty, Anton; Marchesini, Stefano; Noy, Aleksandr; Hau-Riege, Stefan P.; Cui, Congwu; Howells, Malcolm R.; Rosen, Rachel; He, Haifeng; Spence, John C.; Weierstall, Uwe; Beetz, Tobias; Jacobsen, Chris; Shapiro, David

    2006-01-01T23:59:59.000Z

    Coherent x-ray diffraction microscopy is a method of imaging nonperiodic isolated objects at resolutions limited, in principle, by only the wavelength and largest scattering angles recorded. We demonstrate x-ray diffraction imaging with high resolution in all three dimensions, as determined by a quantitative analysis of the reconstructed volume images. These images are retrieved from the three-dimensional diffraction data using no a priori knowledge about the shape or composition of the object, which has never before been demonstrated on a nonperiodic object. We also construct two-dimensional images of thick objects with greatly increased depth of focus (without loss of transverse spatial resolution). These methods can be used to image biological and materials science samples at high resolution with x-ray undulator radiation and establishes the techniques to be used in atomic-resolution ultrafast imaging at x-ray free-electron laser sources.

  12. X-Ray Diffraction Microscopy of Magnetic Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12.0.2.2 Citation: J.J. Turner et al., "X-Ray Diffraction Microscopy of Magnetic Structures," Phys. Rev. Lett. 107, 033904 (2011). Web: http:prl.aps.orgpdfPRLv107i3e033904...

  13. In-situ mechanical testing during X-ray diffraction

    SciTech Connect (OSTI)

    Van Swygenhoven, Helena, E-mail: helena.vanswygenhoven@psi.ch; Van Petegem, Steven

    2013-04-15T23:59:59.000Z

    Deforming metals during recording X-ray diffraction patterns is a useful tool to get a deeper understanding of the coupling between microstructure and mechanical behaviour. With the advances in flux, detector speed and focussing techniques at synchrotron facilities, in-situ mechanical testing is now possible during powder diffraction and Laue diffraction. The basic principle is explained together with illustrative examples.

  14. Phased Contrast X-Ray Imaging

    ScienceCinema (OSTI)

    Erin Miller

    2012-12-31T23:59:59.000Z

    The Pacific Northwest National Laboratory is developing a range of technologies to broaden the field of explosives detection. Phased contrast X-ray imaging, which uses silicon gratings to detect distortions in the X-ray wave front, may be applicable to mail or luggage scanning for explosives; it can also be used in detecting other contraband, small-parts inspection, or materials characterization.

  15. Lensless imaging of nanoporous glass with soft X-rays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Turner, Joshua J.; Nelson, Johanna; Huang, Xiaojing; Steinbrener, Jan; Jacobsen, Chris

    2013-06-01T23:59:59.000Z

    Coherent soft X-ray diffraction has been used to image nanoporous glass structure in two dimensions using different methods. The merit of the reconstructions was judged using a new method of Fourier phase correlation with a final, refined image. The porous structure was found to have a much larger average size then previously believed.

  16. High-resolution x-ray diffraction microscopy of specifically labeled yeast cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nelson, Johanna; Huang, Xiaojing; Steinbrener, Jan; Shapiro, David; Kirz, Janos; Marchesini, Stephano; Neiman, Aaron M.; Turner, Joshua J.; Jacobsen, Chris

    2010-04-20T23:59:59.000Z

    X-ray diffraction microscopy complements other x-ray microscopy methods by being free of lens-imposed radiation dose and resolution limits, and it allows for high-resolution imaging of biological specimens too thick to be viewed by electron microscopy. We report here the highest resolution (11-13 nm) x-ray diffraction micrograph of biological specimens, and a demonstration of molecular-specific gold labeling at different depths within cells via through-focus propagation of the reconstructed wavefield. The lectin concanavalin A conjugated to colloidal gold particles was used to label the ?-mannan sugar in the cell wall of the yeast Saccharomyces cerevisiae. Cells were plunge-frozen in liquid ethane andmore »freeze-dried, after which they were imaged whole using x-ray diffraction microscopy at 750 eV photon energy.« less

  17. High-resolution x-ray diffraction microscopy of specifically labeled yeast cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nelson, Johanna [Stony Brook Univ., Stony Brook, NY (United States); Huang, Xiaojing [Stony Brook Univ., Stony Brook, NY (United States); Steinbrener, Jan [Stony Brook Univ., Stony Brook, NY (United States); Shapiro, David [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source; Kirz, Janos [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source; Marchesini, Stephano [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source; Neiman, Aaron M. [Northwestern Univ., Evanston, IL (United States); Turner, Joshua J. [Stony Brook Univ., Stony Brook, NY (United States); Jacobsen, Chris [Stony Brook Univ., Stony Brook, NY (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source; Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source

    2010-04-20T23:59:59.000Z

    X-ray diffraction microscopy complements other x-ray microscopy methods by being free of lens-imposed radiation dose and resolution limits, and it allows for high-resolution imaging of biological specimens too thick to be viewed by electron microscopy. We report here the highest resolution (11-13 nm) x-ray diffraction micrograph of biological specimens, and a demonstration of molecular-specific gold labeling at different depths within cells via through-focus propagation of the reconstructed wavefield. The lectin concanavalin A conjugated to colloidal gold particles was used to label the ?-mannan sugar in the cell wall of the yeast Saccharomyces cerevisiae. Cells were plunge-frozen in liquid ethane and freeze-dried, after which they were imaged whole using x-ray diffraction microscopy at 750 eV photon energy.

  18. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging in Reflection Print Wednesday, 26 October 2011 00:00 The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field...

  19. Signal-to-noise and radiation exposure considerations in conventional and diffraction x-ray microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Xiaojing; Miao, Huijie; Steinbrener, Jan; Nelson, Johanna; Shapiro, David; Stewart, Andrew; Turner, Joshua; Jacobsen, Chris

    2009-01-01T23:59:59.000Z

    Using a signal-to-noise ratio estimation based on correlations between multiple simulated images, we compare the dose efficiency of two soft x-ray imaging systems: incoherent brightfield imaging using zone plate optics in a transmission x-ray microscope (TXM), and x-ray diffraction microscopy (XDM) where an image is reconstructed from the far-field coherent diffraction pattern. In XDM one must computationally phase weak diffraction signals; in TXM one suffers signal losses due to the finite numerical aperture and efficiency of the optics. In simulations with objects representing isolated cells such as yeast, we find that XDM has the potential for delivering equivalent resolution images using fewer photons. This can be an important advantage for studying radiation-sensitive biological and soft matter specimens.

  20. X-ray imaging and diffraction from surface phonons on GaAs W. Sauer,a)

    E-Print Network [OSTI]

    Ludwig-Maximilians-Universität, München

    , the driver frequency of the synchrotron was multiplied 102 times by a phase-locked loop PLL , ampli- fied are excited on the GaAs 001 surface by using interdigital transducers, designed for frequencies of up to 900 to measured diffraction profiles at different excitation voltages, the SAW amplitudes were calculated

  1. X-ray server : an outline resource for simulations of x-ray diffraction and scattering.

    SciTech Connect (OSTI)

    Stepanov, S.; Biosciences Division

    2004-01-01T23:59:59.000Z

    X-ray Server is a public project operational at the APS since 1997 with the goals to explore novel network technologies for providing wide scientific community with access to personal research results, establishing scientific collaborations, and refining scientific software. The Server provides Web-based access to a number of programs developed by the author in the field of X-ray diffraction and scattering. The software code operates directly on the Server available for use without downloading. Currently seven programs are accessible that have been used more than 85,000 times. This report discusses the Server philosophy, provides an overview of the physical models and algorithms beneath the codes and demonstrates some applications of the programs. It is shown with examples and statistics how the Server goals are achieved. The plans for further X-ray Server development are outlined.

  2. Signal-to-noise and radiation exposure considerations in conventional and diffraction x-ray microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Xiaojing; Miao, Huijie; Steinbrener, Jan; Nelson, Johanna; Shapiro, David; Stewart, Andrew; Turner, Joshua; Jacobsen, Chris

    2009-01-01T23:59:59.000Z

    Using a signal-to-noise ratio estimation based on correlations between multiple simulated images, we compare the dose efficiency of two soft x-ray imaging systems: incoherent brightfield imaging using zone plate optics in a transmission x-ray microscope (TXM), and x-ray diffraction microscopy (XDM) where an image is reconstructed from the far-field coherent diffraction pattern. In XDM one must computationally phase weak diffraction signals; in TXM one suffers signal losses due to the finite numerical aperture and efficiency of the optics. In simulations with objects representing isolated cells such as yeast, we find that XDM has the potential for delivering equivalent resolution imagesmore »using fewer photons. This can be an important advantage for studying radiation-sensitive biological and soft matter specimens.« less

  3. X-ray lithography using holographic images

    DOE Patents [OSTI]

    Howells, Malcolm S. (Berkeley, CA); Jacobsen, Chris (Sound Beach, NY)

    1997-01-01T23:59:59.000Z

    Methods for forming X-ray images having 0.25 .mu.m minimum line widths on X-ray sensitive material are presented. A holgraphic image of a desired circuit pattern is projected onto a wafer or other image-receiving substrate to allow recording of the desired image in photoresist material. In one embodiment, the method uses on-axis transmission and provides a high flux X-ray source having modest monochromaticity and coherence requirements. A layer of light-sensitive photoresist material on a wafer with a selected surface is provided to receive the image(s). The hologram has variable optical thickness and variable associated optical phase angle and amplitude attenuation for transmission of the X-rays. A second embodiment uses off-axis holography. The wafer receives the holographic image by grazing incidence reflection from a hologram printed on a flat metal or other highly reflecting surface or substrate. In this second embodiment, an X-ray beam with a high degree of monochromaticity and spatial coherence is required.

  4. X-ray lithography using holographic images

    DOE Patents [OSTI]

    Howells, M.S.; Jacobsen, C.

    1997-03-18T23:59:59.000Z

    Methods for forming X-ray images having 0.25 {micro}m minimum line widths on X-ray sensitive material are presented. A holographic image of a desired circuit pattern is projected onto a wafer or other image-receiving substrate to allow recording of the desired image in photoresist material. In one embodiment, the method uses on-axis transmission and provides a high flux X-ray source having modest monochromaticity and coherence requirements. A layer of light-sensitive photoresist material on a wafer with a selected surface is provided to receive the image(s). The hologram has variable optical thickness and variable associated optical phase angle and amplitude attenuation for transmission of the X-rays. A second embodiment uses off-axis holography. The wafer receives the holographic image by grazing incidence reflection from a hologram printed on a flat metal or other highly reflecting surface or substrate. In this second embodiment, an X-ray beam with a high degree of monochromaticity and spatial coherence is required. 15 figs.

  5. Single photon energy dispersive x-ray diffraction

    SciTech Connect (OSTI)

    Higginbotham, Andrew; Patel, Shamim; Ciricosta, Orlando; Suggit, Matthew J.; Wark, Justin S. [Department of Physics, Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU (United Kingdom)] [Department of Physics, Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU (United Kingdom); Hawreliak, James A.; Collins, Gilbert W.; Coppari, Federica; Eggert, Jon H. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Tang, Henry [Department of Earth and Planetary Science, University of California Berkeley, Berkeley, California 94720 (United States)] [Department of Earth and Planetary Science, University of California Berkeley, Berkeley, California 94720 (United States)

    2014-03-15T23:59:59.000Z

    With the pressure range accessible to laser driven compression experiments on solid material rising rapidly, new challenges in the diagnosis of samples in harsh laser environments are emerging. When driving to TPa pressures (conditions highly relevant to planetary interiors), traditional x-ray diffraction techniques are plagued by increased sources of background and noise, as well as a potential reduction in signal. In this paper we present a new diffraction diagnostic designed to record x-ray diffraction in low signal-to-noise environments. By utilising single photon counting techniques we demonstrate the ability to record diffraction patterns on nanosecond timescales, and subsequently separate, photon-by-photon, signal from background. In doing this, we mitigate many of the issues surrounding the use of high intensity lasers to drive samples to extremes of pressure, allowing for structural information to be obtained in a regime which is currently largely unexplored.

  6. Fourier analysis of X-ray micro-diffraction profiles to characterize laser shock peened metals

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    .L., 1950. The effect of cold-work distortion on X-ray pat- terns. Journal of Applied Physics 21, 595LSP need to be further studied from the measured X-ray micro-diffraction profile. Broadening of X-rayFourier analysis of X-ray micro-diffraction profiles to characterize laser shock peened metals

  7. Imaging X-ray Thomson Scattering Spectrometer Design and Demonstration

    SciTech Connect (OSTI)

    Gamboa, E.J. [University of Michigan; Huntington, C.M. [University of Michigan; Trantham, M.R. [University of Michigan; Keiter, P.A [University of Michigan; Drake, R.P. [University of Michigan; Montgomery, David [Los Alamos National Laboratory; Benage, John F. [Los Alamos National Laboratory; Letzring, Samuel A. [Los Alamos National Laboratory

    2012-05-04T23:59:59.000Z

    In many laboratory astrophysics experiments, intense laser irradiation creates novel material conditions with large, one-dimensional gradients in the temperature, density, and ionization state. X-ray Thomson scattering is a powerful technique for measuring these plasma parameters. However, the scattered signal has previously been measured with little or no spatial resolution, which limits the ability to diagnose inhomogeneous plasmas. We report on the development of a new imaging x-ray Thomson spectrometer (IXTS) for the Omega laser facility. The diffraction of x-rays from a toroidally-curved crystal creates high-resolution images that are spatially resolved along a one-dimensional profile while spectrally dispersing the radiation. This focusing geometry allows for high brightness while localizing noise sources and improving the linearity of the dispersion. Preliminary results are presented from a scattering experiment that used the IXTS to measure the temperature profile of a shocked carbon foam.

  8. Soft X-Ray Diffraction Microscopy of a Frozen Hydrated Yeast Cell Xiaojing Huang,1

    E-Print Network [OSTI]

    Mohseni, Hooman

    crystallization, and radiation damage are greatly reduced. In this example, coherent diffraction data using 520 e of biological electron microscopy [1­3]. Radiation damage precludes repeated imaging of live specimens [4 in their natural, hydrated state, without limitations imposed by x-ray optics. DOI: 10.1103/PhysRevLett.103

  9. Differential phase contrast X-ray imaging system and components

    DOE Patents [OSTI]

    Stutman, Daniel; Finkenthal, Michael

    2014-07-01T23:59:59.000Z

    A differential phase contrast X-ray imaging system includes an X-ray illumination system, a beam splitter arranged in an optical path of the X-ray illumination system, and a detection system arranged in an optical path to detect X-rays after passing through the beam splitter.

  10. Borman effect in resonant diffraction of X-rays

    SciTech Connect (OSTI)

    Oreshko, A. P., E-mail: ap.oreshko@physics.msu.ru [Moscow State University (Russian Federation)

    2013-08-15T23:59:59.000Z

    A dynamic theory of resonant diffraction (occurring when the energy of incident radiation is close to the energy of the absorption edge of an element in the composition of a given substance) of synchronous X-rays is developed in the two-wave approximation in the coplanar Laue geometry for large grazing angles in perfect crystals. A sharp decrease in the absorption coefficient in the substance with simultaneously satisfied diffraction conditions (Borman effect) is demonstrated, and the theoretical and first experimental results are compared. The calculations reveal the possibility of applying this approach in analyzing the quadrupole-quadrupole contribution to the absorption coefficient.

  11. Apparatus for X-ray diffraction microscopy and tomography of cryo specimens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beetz, T.; Howells, M. R.; Jacobsen, C.; Kao, C. -C.; Kirz, J.; Lima, E.; Mentes, T. O.; Miao, H.; Sanchez-Hanke, C.; Sayre, D.; et al

    2005-06-01T23:59:59.000Z

    An apparatus for diffraction microscopy of biological and materials science specimens is described. In this system, a coherent soft X-ray beam is selected with a pinhole, and the illuminated specimen is followed by an adjustable beamstop and CCD camera to record diffraction data from non-crystalline specimens. In addition, a Fresnel zone plate can be inserted to allow for direct imaging. The system makes use of a cryogenic specimen holder with cryotransfer capabilities to allow frozen hydrated specimens to be loaded. The specimen can be tilted over a range of ± 80 ° degrees for three-dimensional imaging; this is done bymore »computer-controlled motors, enabling automated alignment of the specimen through a tilt series. The system is now in use for experiments in soft X-ray diffraction microscopy.« less

  12. Apparatus for X-ray diffraction microscopy and tomography of cryo specimens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beetz, T.; Howells, M.R.; Jacobsen, C.; Kao, C.-C.; Kirz, J.; Lima, E.; Mentes, T.O.; Miao, H.; Sanchez-Hanke, C.; Sayre, D.; Shapiro, D.

    2005-06-01T23:59:59.000Z

    An apparatus for diffraction microscopy of biological and materials science specimens is described. In this system, a coherent soft X-ray beam is selected with a pinhole, and the illuminated specimen is followed by an adjustable beamstop and CCD camera to record diffraction data from non-crystalline specimens. In addition, a Fresnel zone plate can be inserted to allow for direct imaging. The system makes use of a cryogenic specimen holder with cryotransfer capabilities to allow frozen hydrated specimens to be loaded. The specimen can be tilted over a range of +/- 80 degrees for three-dimensional imaging; this is done by computer-controlled motors, enabling automated alignment of the specimen through a tilt series. The system is now in use for experiments in soft X-ray diffraction microscopy.

  13. Apparatus for X-ray diffraction microscopy and tomography of cryo specimens

    SciTech Connect (OSTI)

    Beetz, T. [Stony Brook Univ., Stony Brook, NY (United States); Howells, M. R. [Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source; Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials; Jacobsen, C. [Stony Brook Univ., Stony Brook, NY (United States); Kao, C. -C. [Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source; Kirz, J. [Stony Brook Univ., Stony Brook, NY (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source; Lima, E. [Stony Brook Univ., Stony Brook, NY (United States); Mentes, T. O. [Stony Brook Univ., Stony Brook, NY (United States); TASC-INFM National Lab, Trieste (Italy); Miao, H. [Stony Brook Univ., Stony Brook, NY (United States); Sanchez-Hanke, C. [Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source; Sayre, D. [Stony Brook Univ., Stony Brook, NY (United States); Shapiro, D. [Stony Brook Univ., Stony Brook, NY (United States)

    2005-06-01T23:59:59.000Z

    An apparatus for diffraction microscopy of biological and materials science specimens is described. In this system, a coherent soft X-ray beam is selected with a pinhole, and the illuminated specimen is followed by an adjustable beamstop and CCD camera to record diffraction data from non-crystalline specimens. In addition, a Fresnel zone plate can be inserted to allow for direct imaging. The system makes use of a cryogenic specimen holder with cryotransfer capabilities to allow frozen hydrated specimens to be loaded. The specimen can be tilted over a range of ± 80 ° degrees for three-dimensional imaging; this is done by computer-controlled motors, enabling automated alignment of the specimen through a tilt series. The system is now in use for experiments in soft X-ray diffraction microscopy.

  14. Characterization of Microstructure of Severely Deformed Titanium by X-ray Diffraction Profile Analysis

    E-Print Network [OSTI]

    Gubicza, Jenõ

    Characterization of Microstructure of Severely Deformed Titanium by X-ray Diffraction Profile deformation, X-ray peak profile analysis. Abstract. Nanocrystalline titanium was produced by equal channel of the measured X-ray diffraction peak profiles. The peak profile analysis provided the median and the variance

  15. Anomalous X-ray Diffraction Studies for Photovoltaic Applications

    SciTech Connect (OSTI)

    Not Available

    2011-06-22T23:59:59.000Z

    Anomalous X-ray Diffraction (AXRD) has become a useful technique in characterizing bulk and nanomaterials as it provides specific information about the crystal structure of materials. In this project we present the results of AXRD applied to materials for photovoltaic applications: ZnO loaded with Ga and ZnCo{sub 2}O{sub 4} spinel. The X-ray diffraction data collected for various energies were plotted in Origin software. The peaks were fitted using different functions including Pseudo Voigt, Gaussian, and Lorentzian. This fitting provided the integrated intensity data (peaks area values), which when plotted as a function of X-ray energies determined the material structure. For the first analyzed sample, Ga was not incorporated into the ZnO crystal structure. For the ZnCo{sub 2}O{sub 4} spinel Co was found in one or both tetrahedral and octahedral sites. The use of anomalous X-ray diffraction (AXRD) provides element and site specific information for the crystal structure of a material. This technique lets us correlate the structure to the electronic properties of the materials as it allows us to probe precise locations of cations in the spinel structure. What makes it possible is that in AXRD the diffraction pattern is measured at a number of energies near an X-ray absorption edge of an element of interest. The atomic scattering strength of an element varies near its absorption edge and hence the total intensity of the diffraction peak changes by changing the X-ray energy. Thus AXRD provides element specific structural information. This method can be applied to both crystalline and liquid materials. One of the advantages of AXRD in crystallography experiments is its sensitivity to neighboring elements in the periodic tables. This method is also sensitive to specific crystallographic phases and to a specific site in a phase. The main use of AXRD in this study is for transparent conductors (TCs) analysis. TCs are considered to be important materials because of their efficiency and low risk of environmental pollution. These materials are important to solar cells as a result of their remarkable combination of optical and electrical properties, including high electrical conductivity and high optical transparency in the spectrum of visible light. TCs provide a transparent window, which allows sunlight to pass through while also allowing electricity to conduct out of the cell. Spinel materials have the chemical form AB{sub 2}O{sub 4}, and are made of a face-centered cubic (FCC) lattice of oxygen anions and cations in specific interstitial sites. A normal spinel has all A cations on tetrahedral sites and B cations on octahedral sites. In contrast; an inverse spinel has the A and half of the B cations on octahedral sites and the other half of the B cations on tetrahedral sites; a mixed spinel lies between. In the spinel structure, 8 of 64 possible tetrahedral sites and 16 of 32 possible octahedral sites are filled. Normal spinels have particularly high conduction as the linear octahedral chains of B cations likely serve as conduction paths. In this paper we present how the data obtained with AXRD is used to analyze TCs properties as they apply to photovoltaic applications. One of the materials used for this analysis is zinc oxide. It has been loaded with 5% and 10% of Ga, which has an absorption edge of 10367 eV. The peak (100) was measured for the zinc oxide loaded with 10% Ga. In the case of 5% Ga, we measured peaks (100) and (101). With the information provided by the AXRD we can identify if Ga is being incorporated in the ZnO crystal structure. The analysis of 311 plane in the ZnCo{sub 2}O{sub 4} spinel shows if Co is in tetrahedral or octahedral site.

  16. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your HomeLatest News ReleasesDepartmentLendingX-Ray Imaging in

  17. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your HomeLatest News ReleasesDepartmentLendingX-Ray Imaging

  18. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless ImagingLensless X-Ray

  19. Coded Aperture Imaging for Fluorescent X-rays-Biomedical Applications

    SciTech Connect (OSTI)

    Haboub, Abdel; MacDowell, Alastair; Marchesini, Stefano; Parkinson, Dilworth

    2013-06-01T23:59:59.000Z

    Employing a coded aperture pattern in front of a charge couple device pixilated detector (CCD) allows for imaging of fluorescent x-rays (6-25KeV) being emitted from samples irradiated with x-rays. Coded apertures encode the angular direction of x-rays and allow for a large Numerical Aperture x- ray imaging system. The algorithm to develop the self-supported coded aperture pattern of the Non Two Holes Touching (NTHT) pattern was developed. The algorithms to reconstruct the x-ray image from the encoded pattern recorded were developed by means of modeling and confirmed by experiments. Samples were irradiated by monochromatic synchrotron x-ray radiation, and fluorescent x-rays from several different test metal samples were imaged through the newly developed coded aperture imaging system. By choice of the exciting energy the different metals were speciated.

  20. Phase-sensitive X-ray imager

    DOE Patents [OSTI]

    Baker, Kevin Louis

    2013-01-08T23:59:59.000Z

    X-ray phase sensitive wave-front sensor techniques are detailed that are capable of measuring the entire two-dimensional x-ray electric field, both the amplitude and phase, with a single measurement. These Hartmann sensing and 2-D Shear interferometry wave-front sensors do not require a temporally coherent source and are therefore compatible with x-ray tubes and also with laser-produced or x-pinch x-ray sources.

  1. Realizing in-plane surface diffraction by x-ray multiple-beam diffraction with large incidence angle

    SciTech Connect (OSTI)

    Huang, Xian-Rong, E-mail: xiahuang@aps.anl.gov; Gog, Thomas; Assoufid, Lahsen [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Peng, Ru-Wen, E-mail: rwpeng@nju.edu.cn [National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093 (China); Siddons, D. P. [National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973 (United States)

    2014-11-03T23:59:59.000Z

    Based on rigorous dynamical-theory calculations, we demonstrate the principle of an x-ray multiple-beam diffraction (MBD) scheme that overcomes the long-lasting difficulties of high-resolution in-plane diffraction from crystal surfaces. This scheme only utilizes symmetric reflection geometry with large incident angles but activates the out-of-plane and in-plane diffraction processes simultaneously and separately in the continuous MBD planes. The in-plane diffraction is realized by detoured MBD, where the intermediate diffracted waves propagate parallel to the surface, which corresponds to an absolute Bragg surface diffraction configuration that is extremely sensitive to surface structures. A series of MBD diffraction and imaging techniques may be developed from this principle to study surface/interface (misfit) strains, lateral nanostructures, and phase transitions of a wide range of (pseudo)cubic crystal structures, including ultrathin epitaxial films and multilayers, quantum dots, strain-engineered semiconductor or (multi)ferroic materials, etc.

  2. Quantification of thin film crystallographic orientation using X-ray diffraction with an area detector

    E-Print Network [OSTI]

    Baker, Jessica L

    2010-01-01T23:59:59.000Z

    elastic  properties of Au thin films by X?ray diffraction interface in  polythiophene thin?film transistors.  Nat copper  phthalocyanine thin films evaporated on amorphous 

  3. Calibrating X-ray Imaging Devices for Accurate Intensity Measurement

    SciTech Connect (OSTI)

    Haugh, M. J.

    2011-07-28T23:59:59.000Z

    The purpose of the project presented is to develop methods to accurately calibrate X-ray imaging devices. The approach was to develop X-ray source systems suitable for this endeavor and to develop methods to calibrate solid state detectors to measure source intensity. NSTec X-ray sources used for the absolute calibration of cameras are described, as well as the method of calibrating the source by calibrating the detectors. The work resulted in calibration measurements for several types of X-ray cameras. X-ray camera calibration measured efficiency and efficiency variation over the CCD. Camera types calibrated include: CCD, CID, back thinned (back illuminated), front illuminated.

  4. Advances in X-Ray Chemical Analysis, Japan, 41 (2010) ISSN 0911-7806 Theoretical Analysis of X-Ray Waveguide Using Fresnel Diffraction

    E-Print Network [OSTI]

    Jun, Kawai

    2010-01-01T23:59:59.000Z

    -Ray Waveguide Using Fresnel Diffraction Yusuke MORIKAWA and Jun KAWAI #12;#12;41 145 X Adv. X-Ray. Chem. Anal., Japan 41, pp.145-150 (2010) 606-8501 X Theoretical Analysis of X-Ray Waveguide Using Fresnel Diffraction symmetrical pattern. We regard it as a slit and calculated the Fresnel diffraction. We find

  5. Residual stress measurement using X-ray diffraction

    E-Print Network [OSTI]

    Anderoglu, Osman

    2005-02-17T23:59:59.000Z

    -rays..............................................................................................16 2.4. Bragg's Law ..........................................................................................................18 2.5. Diffractometer Geometry... Figure 2.2 Schematic showing the basic components of a modern x-ray tube. Beryllium window is highly transparent to x-rays...............................15 Figure 2.3 Coherent scattering from an electron to a point P...

  6. X-ray Diffraction from Membrane Protein Nanocrystals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-RayX-ray

  7. Real-time X-ray Diffraction Measurements of Shocked Polycrystalline Tin and Aluminum

    SciTech Connect (OSTI)

    Dane V. Morgan, Don Macy, Gerald Stevens

    2008-11-22T23:59:59.000Z

    A new, fast, single-pulse x-ray diffraction (XRD) diagnostic for determining phase transitions in shocked polycrystalline materials has been developed. The diagnostic consists of a 37-stage Marx bank high-voltage pulse generator coupled to a needle-and-washer electron beam diode via coaxial cable, producing line and bremsstrahlung x-ray emission in a 35-ns pulse. The characteristic K? lines from the selected anodes of silver and molybdenum are used to produce the diffraction patterns, with thin foil filters employed to remove the characteristic K? line emission. The x-ray beam passes through a pinhole collimator and is incident on the sample with an approximately 3-mm by 6-mm spot and 1° full-width-half-maximum (FWHM) angular divergence in a Bragg-reflecting geometry. For the experiments described in this report, the angle between the incident beam and the sample surface was 8.5°. A Debye-Scherrer diffraction image was produced on a phosphor located 76 mm from the polycrystalline sample surface. The phosphor image was coupled to a charge-coupled device (CCD) camera through a coherent fiberoptic bundle. Dynamic single-pulse XRD experiments were conducted with thin foil samples of tin, shock loaded with a 1-mm vitreous carbon back window. Detasheet high explosive with a 2-mm-thick aluminum buffer was used to shock the sample. Analysis of the dynamic shock-loaded tin XRD images revealed a phase transformation of the tin beta phase into an amorphous or liquid state. Identical experiments with shock-loaded aluminum indicated compression of the face-centered-cubic (fcc) aluminum lattice with no phase transformation.

  8. Anti-contamination device for cryogenic soft X-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Xiaojing; Miao, Huijie; Nelson, Johanna; Turner, Joshua; Steinbrener, Jan; Shapiro, David; Kirz, Janos; Jacobsen, Chris

    2011-05-01T23:59:59.000Z

    Cryogenic microscopy allows one to view frozen hydrated biological and soft matter specimens with good structural preservation and a high degree of stability against radiation damage. We describe a liquid nitrogen-cooled anti-contamination device for cryogenic X-ray diffraction microscopy. The anti-contaminator greatly reduces the buildup of ice layers on the specimen due to condensation of residual water vapor in the experimental vacuum chamber. We show by coherent X-ray diffraction measurements that this leads to fivefold reduction of background scattering, which is important for far-field X-ray diffraction microscopy of biological specimens.

  9. Single mimivirus particles intercepted and imaged with an X-ray laser (CXIDB ID 2)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Seibert, M. Marvin; Ekeberg, Tomas

    These are the files used to reconstruct the images in the paper "Single Mimivirus particles intercepted and imaged with an X-ray laser". Besides the diffracted intensities, the Hawk configuration files used for the reconstructions are also provided. The files from CXIDB ID 2 are the pattern and configuration files for the pattern showed in Figure 2b in the paper.

  10. Single mimivirus particles intercepted and imaged with an X-ray laser (CXIDB ID 1)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Seibert, M. Marvin; Ekeberg, Tomas; Maia, Filipe R.N.C.

    These are the files used to reconstruct the images in the paper "Single Mimivirus particles intercepted and imaged with an X-ray laser". Besides the diffracted intensities, the Hawk configuration files used for the reconstructions are also provided. The files from CXIDB ID 1 are the pattern and configuration files for the pattern showed in Figure 2a in the paper.

  11. Imaging Quantum States with X-ray Compton Scattering | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging Quantum States with X-ray Compton Scattering Wednesday, April 8, 2015 - 3:00pm SLAC, Redtail Hawk Conference Room 108A Speaker: Yoshiharu Sakurai (Japan Synchrotron...

  12. Method for improve x-ray diffraction determinations of residual stress in nickel-base alloys

    DOE Patents [OSTI]

    Berman, Robert M. (Pittsburgh, PA); Cohen, Isadore (Pittsburgh, PA)

    1990-01-01T23:59:59.000Z

    A process for improving the technique of measuring residual stress by x-ray diffraction in pieces of nickel-base alloys which comprises covering part of a predetermined area of the surface of a nickel-base alloy with a dispersion, exposing the covered and uncovered portions of the surface of the alloy to x-rays by way of an x-ray diffractometry apparatus, making x-ray diffraction determinations of the exposed surface, and measuring the residual stress in the alloy based on these determinations. The dispersion is opaque to x-rays and serves a dual purpose since it masks off unsatisfactory signals such that only a small portion of the surface is measured, and it supplies an internal standard by providing diffractogram peaks comparable to the peaks of the nickel alloy so that the alloy peaks can be very accurately located regardless of any sources of error external to the sample.

  13. Dynamical x-ray diffraction from an icosahedral Al-Pd-Mn quasicrystal

    SciTech Connect (OSTI)

    Kycia, S.

    1996-04-23T23:59:59.000Z

    Primary extinction effects in diffraction from single grains of Al-Pd- Mn, and presumably many other FCI alloys, may be significant and should be corrected for prior to use of diffraction data in structural determinations. Probes based on dynamical diffraction effects, such as x-ray standing wave fluorescence, multiple beam interference, and x-ray transmission topographs, may now be used to study the bulk and surface structure of some quasicrystals. The observation of dynamical diffraction from icosahedral Al-Pd-Mn is a striking confirmation of the fact that quasicrystals can present a degree of structural perfection comparable to that found in the best periodic intermetallic crystals.

  14. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your HomeLatest News ReleasesDepartmentLendingX-Ray

  15. Femtosecond X-ray Diffraction From Two-Dimensional Protein Crystals

    SciTech Connect (OSTI)

    Frank, Matthias; Carlson, David B.; Hunter, Mark; Williams, Garth J.; Messerschmidt, Marc; Zatsepin, Nadia A.; Barty, Anton; Benner, Henry; Chu, Kaiqin; Graf, Alexander; Hau-Riege, Stefan; Kirian, Rick; Padeste, Celestino; Pardini, Tommaso; Pedrini, Bill; Segelke, Brent; Seibert, M. M.; Spence , John C.; Tsai, Ching-Ju; Lane, Steve M.; Li, Xiao-Dan; Schertler, Gebhard; Boutet, Sebastien; Coleman, Matthew A.; Evans, James E.

    2014-02-28T23:59:59.000Z

    Here we present femtosecond x-ray diffraction patterns from two-dimensional (2-D) protein crystals using an x-ray free electron laser (XFEL). To date it has not been possible to acquire x-ray diffraction from individual 2-D protein crystals due to radiation damage. However, the intense and ultrafast pulses generated by an XFEL permits a new method of collecting diffraction data before the sample is destroyed. Utilizing a diffract-before-destroy methodology at the Linac Coherent Light Source, we observed Bragg diffraction to better than 8.5 Å resolution for two different 2-D protein crystal samples that were maintained at room temperature. These proof-of-principle results show promise for structural analysis of both soluble and membrane proteins arranged as 2-D crystals without requiring cryogenic conditions or the formation of three-dimensional crystals.

  16. X-Ray Diffraction Microscopy of Magnetic Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat isJoin theanniversaryI 1 0 3 P 0 d d X O O lX-Ray

  17. Imaging single cells in a beam of live cyanobacteria with an X-ray laser

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schot, Gijs, vander

    This entry contains ten diffraction patterns, and reconstructions images, of individual living Cyanobium gracile cells, imaged using 517 eV X-rays from the LCLS XFEL. The Hawk software package was used for phasing. The Uppsala aerosol injector was used for sample injection, assuring very low noise levels. The cells come from various stages of the cell cycle, and were imaged in random orientations.

  18. Quantitative determination of mineral composition by powder x-ray diffraction

    DOE Patents [OSTI]

    Pawloski, G.A.

    1984-08-10T23:59:59.000Z

    An external standard intensity ratio method is used for quantitatively determining mineralogic compositions of samples by x-ray diffraction. The method uses ratios of x-ray intensity peaks from a single run. Constants are previously determined for each mineral which is to be quantitatively measured. Ratios of the highest intensity peak of each mineral to be quantified in the sample and the highest intensity peak of a reference mineral contained in the sample are used to calculate sample composition.

  19. X-ray diffraction and EXAFS analysis of materials for lithium-based rechargeable batteries

    SciTech Connect (OSTI)

    Sharkov, M. D., E-mail: mischar@mail.ioffe.ru; Boiko, M. E.; Bobyl, A. V.; Ershenko, E. M.; Terukov, E. I. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Zubavichus, Y. V. [National Research Centre “Kurchatov Institute” (Russian Federation)

    2013-12-15T23:59:59.000Z

    Lithium iron phosphate LiFePO{sub 4} (triphylite) and lithium titanate Li{sub 4}Ti{sub 5}O{sub 12} are used as components of a number of active materials in modern rechargeable batteries. Samples of these materials are studied by X-ray diffraction and extended X-ray absorption fine structure (EXAFS) spectroscopy. Hypotheses about the phase composition of the analyzed samples are formulated.

  20. Quality experimental and calculated powder x-ray diffraction

    SciTech Connect (OSTI)

    Sullenger, D.B.; Cantrell, J.S.; Beiter, T.A.; Tomlin, D.W.

    1996-08-01T23:59:59.000Z

    For several years, we have submitted quality powder XRD patterns to the International Centre for Diffraction Data for inclusion as reference standards in their Powder Diffraction File. The procedure followed is described; examples used are {beta}-UH{sub 3}, {alpha}- BaT{sub 2}, alpha-lithium disilicate ({alpha}-Li{sub 2}Si{sub 2}O{sub 5}), and 2,2`,4,4`,6,6`hexanitroazobenzene-III (HNAB-III).

  1. Note: Application of a pixel-array area detector to simultaneous single crystal x-ray diffraction and x-ray absorption spectroscopy measurements

    SciTech Connect (OSTI)

    Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov; Brewe, Dale L.; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Chen, Jing-Sheng; Chow, G. M. [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore)] [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore) [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Department of Physics, National University of Singapore, 117542 Singapore (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, 117575 Singapore (Singapore)

    2014-04-15T23:59:59.000Z

    X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are two main x-ray techniques in synchrotron radiation facilities. In this Note, we present an experimental setup capable of performing simultaneous XRD and XAS measurements by the application of a pixel-array area detector. For XRD, the momentum transfer in specular diffraction was measured by scanning the X-ray energy with fixed incoming and outgoing x-ray angles. By selecting a small fixed region of the detector to collect the XRD signal, the rest of the area was available for collecting the x-ray fluorescence for XAS measurements. The simultaneous measurement of XRD and X-ray absorption near edge structure for Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film was demonstrated as a proof of principle for future time-resolved pump-probe measurements. A static sample makes it easy to maintain an accurate overlap of the X-ray spot and laser pump beam.

  2. An instrument for 3D x-ray nano-imaging

    SciTech Connect (OSTI)

    Holler, M.; Raabe, J.; Diaz, A.; Guizar-Sicairos, M.; Quitmann, C.; Menzel, A.; Bunk, O. [Paul Scherrer Institut, 5232 Villigen PSI (Switzerland)

    2012-07-15T23:59:59.000Z

    We present an instrument dedicated to 3D scanning x-ray microscopy, allowing a sample to be precisely scanned through a beam while the angle of x-ray incidence can be changed. The position of the sample is controlled with respect to the beam-defining optics by laser interferometry. The instrument achieves a position stability better than 10 nm standard deviation. The instrument performance is assessed using scanning x-ray diffraction microscopy and we demonstrate a resolution of 18 nm in 2D imaging of a lithographic test pattern while the beam was defined by a pinhole of 3 {mu}m in diameter. In 3D on a test object of copper interconnects of a microprocessor, a resolution of 53 nm is achieved.

  3. 2D and 3D Refraction Based X-ray Imaging Suitable for Clinical and Pathological Diagnosis

    SciTech Connect (OSTI)

    Ando, Masami [Institute of Science and Technology, Tokyo Univ. of Science, Yamasaki 2641, Noda, Chiba 278-8510 (Japan); Photon Factory, IMSS, KEK, Oho 1-1, Tsukuba, Ibaraki 305-0801 (Japan); Dept. of Photo-Science, GUAS, Shonan, Hayama, Kanagawa 240-0193 (Japan); Bando, Hiroko; Ueno, Ei [Dept. of Breast-Thyroid-Endocrine Surgery, Univ. of Tsukuba, Ibaraki 305-8573 (Japan)] (and others)

    2007-01-19T23:59:59.000Z

    The first observation of micro papillary (MP) breast cancer by x-ray dark-field imaging (XDFI) and the first observation of the 3D x-ray internal structure of another breast cancer, ductal carcinoma in-situ (DCIS), are reported. The specimen size for the sheet-shaped MP was 26 mm x 22 mm x 2.8 mm, and that for the rod-shaped DCIS was 3.6 mm in diameter and 4.7 mm in height. The experiment was performed at the Photon Factory, KEK: High Energy Accelerator Research Organization. We achieved a high-contrast x-ray image by adopting a thickness-controlled transmission-type angular analyzer that allows only refraction components from the object for 2D imaging. This provides a high-contrast image of cancer-cell nests, cancer cells and stroma. For x-ray 3D imaging, a new algorithm due to the refraction for x-ray CT was created. The angular information was acquired by x-ray optics diffraction-enhanced imaging (DEI). The number of data was 900 for each reconstruction. A reconstructed CT image may include ductus lactiferi, micro calcification and the breast gland. This modality has the possibility to open up a new clinical and pathological diagnosis using x-ray, offering more precise inspection and detection of early signs of breast cancer.

  4. Segmentation of x-ray images using Probabilistic Relaxation Labeling

    SciTech Connect (OSTI)

    Thai, T.Q.

    1991-01-01T23:59:59.000Z

    Segmentation is a process of separating objects of interest from their background or from other objects in an image. Without a suitable segmentation scheme, it is very difficult to detect contraband in X-rays images. In this paper, a Probabilistic Relaxation Labeling (PRL) segmentation scheme is presented and compared with other segmentation methods. PRL segmentation is an interative algorithm that labels each pixel in an image by cooperative use of two information sources: the pixel probability and the degree of certainty of its probability supported by the neighboring pixels. The practical implementation and results of the PRL segmentation on X-ray baggage images are also discussed and compared with other segmentation methods. 13 refs., 12 figs.

  5. Phase Effects on Mesoscale Object X-ray Absorption Images

    SciTech Connect (OSTI)

    Martz, Jr., H E; Aufderheide, M B; Barty, A; Lehman, S K; Kozioziemski, B J; Schneberk, D J

    2004-09-24T23:59:59.000Z

    At Lawrence Livermore National Laboratory particular emphasis is being placed on the nondestructive characterization (NDC) of 'mesoscale' objects.[Martz and Albrecht 2003] We define mesoscale objects as objects that have mm extent with {micro}m features. Here we confine our discussions to x-ray imaging methods applicable to mesoscale object characterization. The goal is object recovery algorithms including phase to enable emerging high-spatial resolution x-ray imaging methods to ''see'' inside or image mesoscale-size materials and objects. To be successful our imaging characterization effort must be able to recover the object function to one micrometer or better spatial resolution over a few millimeters field-of-view with very high contrast.

  6. Methodology for Optimal In Situ Alignment and Setting of Bendable Optics for Diffraction-Limited Focusing of Soft X-Rays

    E-Print Network [OSTI]

    Merthe, Daniel

    2013-01-01T23:59:59.000Z

    mirrors, x-rays, x-ray optics, synchrotron radiation,beamline, Kirkpatrick-Baez, metrology of x-ray opticsand Setting of Bendable Optics for Diffraction-Limited

  7. Impulsive solvent heating probed by picosecond x-ray diffraction M. Cammarata

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    Impulsive solvent heating probed by picosecond x-ray diffraction M. Cammarata European Synchrotron and J. H. Lee Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea Q. Y. Kong European Synchrotron

  8. Radial x-ray diffraction of tungsten tetraboride to 86 GPa under nonhydrostatic compression

    E-Print Network [OSTI]

    Lin, Jung-Fu "Afu"

    Radial x-ray diffraction of tungsten tetraboride to 86 GPa under nonhydrostatic compression Lun December 2012; published online 16 January 2013) Investigations of the equation of state of tungsten moduli and hardness exceed- ing or closing that of diamond. Tungsten tetraboride (WB4) is a candidate

  9. Diffraction crystals for sagittally focusing x-rays

    DOE Patents [OSTI]

    Ice, G.E.; Sparks, C.J. Jr.

    1982-06-07T23:59:59.000Z

    The invention is a new type of diffraction crystal designed for sagittally focusing photons of various energies. The invention is based on the discovery that such focusing is not obtainable with conventional crystals because of distortion resulting from anticlastic curvature. The new crystal comprises a monocrystalline base having a front face contoured for sagittally focusing photons and a back face provided with rigid, upstanding, stiffening ribs restricting anticlastic curvature. When mounted in a suitable bending device, the reflecting face of the crystal can be adjusted to focus photons having any one of a range of energies.

  10. Diffraction crystal for sagittally focusing x-rays

    DOE Patents [OSTI]

    Ice, Gene E. (Oak Ridge, TN); Sparks, Jr., Cullie J. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    The invention is a new type of diffraction crystal designed for sagittally focusing photons of various energies. The invention is based on the discovery that such focusing is not obtainable with conventional crystals because of distortion resulting from anticlastic curvature. The new crystal comprises a monocrystalline base having a front face contoured for sagittally focusing photons and a back face provided with rigid, upstanding, stiffening ribs restricting anticlastic curvature. When mounted in a suitable bending device, the reflecting face of the crystal can be adjusted to focus photons having any one of a range of energies.

  11. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging

  12. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless ImagingLensless

  13. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless ImagingLenslessLensless

  14. X-ray diffraction study of the static strength of tungsten to 69 GPa Duanwei He* and Thomas S. Duffy

    E-Print Network [OSTI]

    Duffy, Thomas S.

    X-ray diffraction study of the static strength of tungsten to 69 GPa Duanwei He* and Thomas S of tungsten was determined under static high pressures to 69 GPa using x-ray diffraction techniques strength of tungsten increases with compression, reaching a value of 5.3 GPa at the highest pressure

  15. Capture and X-ray diffraction studies of protein microcrystals in a microfluidic trap array

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lyubimov, Artem Y.; Murray, Thomas D.; Koehl, Antoine; Araci, Ismail Emre; Uervirojnangkoorn, Monarin; Zeldin, Oliver B.; Cohen, Aina E.; Soltis, S. Michael; Baxter, Elizabeth L.; Brewster, Aaron S.; et al

    2015-04-01T23:59:59.000Z

    X-ray free-electron lasers (XFELs) promise to enable the collection of interpretable diffraction data from samples that are refractory to data collection at synchrotron sources. At present, however, more efficient sample-delivery methods that minimize the consumption of microcrystalline material are needed to allow the application of XFEL sources to a wide range of challenging structural targets of biological importance. Here, a microfluidic chip is presented in which microcrystals can be captured at fixed, addressable points in a trap array from a small volume (more »conducting diffraction experiments at room temperature without the need for flash-cooling. Proof-of-principle tests with a model system (hen egg-white lysozyme) demonstrated the high efficiency of the microfluidic approach for crystal harvesting, permitting the collection of sufficient data from only 265 single-crystal still images to permit determination and refinement of the structure of the protein. This work shows that microfluidic capture devices can be readily used to facilitate data collection from protein microcrystals grown in traditional laboratory formats, enabling analysis when cryopreservation is problematic or when only small numbers of crystals are available. Such microfluidic capture devices may also be useful for data collection at synchrotron sources.« less

  16. Final report: high resolution lensless 3D imaging of nanostructures with coherent x-rays

    SciTech Connect (OSTI)

    Jacobsen, Chris

    2014-12-07T23:59:59.000Z

    Final report on the project "High resolution lensless 3D imaging of nanostructures with coherent x-rays"

  17. Cyclic olefin homopolymer-based microfluidics for protein crystallization and in situ X-ray diffraction

    SciTech Connect (OSTI)

    Emamzadah, Soheila [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Petty, Tom J. [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Biomedical Graduate Studies Genomics and Computational Biology Group, University of Pennsylvania, Philadelphia, PA 19104 (United States); De Almeida, Victor [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Nishimura, Taisuke [Department of Plant Biology, University of Geneva, CH-1205 Geneva (Switzerland); Joly, Jacques; Ferrer, Jean-Luc [Institut de Biologie Structurale J.-P. Ebel, CEA-CNRS-University J. Fourier, 38027 Grenoble CEDEX 1 (France); Halazonetis, Thanos D., E-mail: thanos.halazonetis@unige.ch [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland)

    2009-09-01T23:59:59.000Z

    A cyclic olefin homopolymer-based microfluidics system has been established for protein crystallization and in situ X-ray diffraction. Microfluidics is a promising technology for the rapid identification of protein crystallization conditions. However, most of the existing systems utilize silicone elastomers as the chip material which, despite its many benefits, is highly permeable to water vapour. This limits the time available for protein crystallization to less than a week. Here, the use of a cyclic olefin homopolymer-based microfluidics system for protein crystallization and in situ X-ray diffraction is described. Liquid handling in this system is performed in 2 mm thin transparent cards which contain 500 chambers, each with a volume of 320 nl. Microbatch, vapour-diffusion and free-interface diffusion protocols for protein crystallization were implemented and crystals were obtained of a number of proteins, including chicken lysozyme, bovine trypsin, a human p53 protein containing both the DNA-binding and oligomerization domains bound to DNA and a functionally important domain of Arabidopsis Morpheus’ molecule 1 (MOM1). The latter two polypeptides have not been crystallized previously. For X-ray diffraction analysis, either the cards were opened to allow mounting of the crystals on loops or the crystals were exposed to X-rays in situ. For lysozyme, an entire X-ray diffraction data set at 1.5 Å resolution was collected without removing the crystal from the card. Thus, cyclic olefin homopolymer-based microfluidics systems have the potential to further automate protein crystallization and structural genomics efforts.

  18. An assessment of the resolution limitation due to radiation-damage in X-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Howells, M.R.; Beetz, T.; Chapman, H.N.; Cui, C.; Holton, J.M.; Jacobsen, C.J.; Kirz, J.; Lima, E.; Marchesini, S.; Miao, H.; et al

    2009-03-01T23:59:59.000Z

    X-ray diffraction microscopy (XDM) is a new form of x-ray imaging that is being practiced at several third-generation synchrotron-radiation x-ray facilities. Nine years have elapsed since the technique was first introduced and it has made rapid progress in demonstrating high-resolution three-dimensional imaging and promises few-nm resolution with much larger samples than can be imaged in the transmission electron microscope. Both life- and materials-science applications of XDM are intended, and it is expected that the principal limitation to resolution will be radiation damage for life science and the coherent power of available x-ray sources for material science. In this paper wemore »address the question of the role of radiation damage. We use a statistical analysis based on the so-called "dose fractionation theorem" of Hegerl and Hoppe to calculate the dose needed to make an image of a single life-science sample by XDM with a given resolution. We find that for simply-shaped objects the needed dose scales with the inverse fourth power of the resolution and present experimental evidence to support this finding. To determine the maximum tolerable dose we have assembled a number of data taken from the literature plus some measurements of our own which cover ranges of resolution that are not well covered otherwise. The conclusion of this study is that, based on the natural contrast between protein and water and "Rose-criterion" image quality, one should be able to image a frozen-hydrated biological sample using XDM at a resolution of about 10 nm.« less

  19. An assessment of the resolution limitation due to radiation-damage in X-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Howells, M.R.; Beetz, T.; Chapman, H.N.; Cui, C.; Holton, J.M.; Jacobsen, C.J.; Kirz, J.; Lima, E.; Marchesini, S.; Miao, H.; Sayre, D.; Shapiro, D.A.; Spence, J.C.H.; Starodub, D.

    2009-03-01T23:59:59.000Z

    X-ray diffraction microscopy (XDM) is a new form of x-ray imaging that is being practiced at several third-generation synchrotron-radiation x-ray facilities. Nine years have elapsed since the technique was first introduced and it has made rapid progress in demonstrating high-resolution three-dimensional imaging and promises few-nm resolution with much larger samples than can be imaged in the transmission electron microscope. Both life- and materials-science applications of XDM are intended, and it is expected that the principal limitation to resolution will be radiation damage for life science and the coherent power of available x-ray sources for material science. In this paper we address the question of the role of radiation damage. We use a statistical analysis based on the so-called "dose fractionation theorem" of Hegerl and Hoppe to calculate the dose needed to make an image of a single life-science sample by XDM with a given resolution. We find that for simply-shaped objects the needed dose scales with the inverse fourth power of the resolution and present experimental evidence to support this finding. To determine the maximum tolerable dose we have assembled a number of data taken from the literature plus some measurements of our own which cover ranges of resolution that are not well covered otherwise. The conclusion of this study is that, based on the natural contrast between protein and water and "Rose-criterion" image quality, one should be able to image a frozen-hydrated biological sample using XDM at a resolution of about 10 nm.

  20. Continuous motion scan ptychography: Characterization for increased speed in coherent x-ray imaging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deng, Junjing; Nashed, Youssef S. G.; Chen, Si; Phillips, Nicholas W.; Peterka, Tom; Ross, Rob; Vogt, Stefan; Jacobsen, Chris; Vine, David J.

    2015-01-01T23:59:59.000Z

    Ptychography is a coherent diffraction imaging (CDI) method for extended objects in which diffraction patterns are acquired sequentially from overlapping coherent illumination spots. The object’s complex transmission function can be reconstructed from those diffraction patterns at a spatial resolution limited only by the scattering strength of the object and the detector geometry. Most experiments to date have positioned the illumination spots on the sample using a move-settle-measure sequence in which the move and settle steps can take longer to complete than the measure step. We describe here the use of a continuous “fly-scan” mode for ptychographic data collection in whichmore »the sample is moved continuously, so that the experiment resembles one of integrating the diffraction patterns from multiple probe positions. This allows one to use multiple probe mode reconstruction methods to obtain an image of the object and also of the illumination function. We show in simulations, and in x-ray imaging experiments, some of the characteristics of fly-scan ptychography, including a factor of 25 reduction in the data acquisition time. This approach will become increasingly important as brighter x-ray sources are developed, such as diffraction limited storage rings.« less

  1. Fiber fed x-ray/gamma ray imaging apparatus

    DOE Patents [OSTI]

    Hailey, C.J.; Ziock, K.P.

    1992-06-02T23:59:59.000Z

    X-ray/gamma ray imaging apparatus is disclosed for detecting the position, energy, and intensity of x-ray/gamma ray radiation comprising scintillation means disposed in the path of such radiation and capable of generating photons in response to such radiation; first photodetection means optically bonded to the scintillation means and capable of generating an electrical signal indicative of the intensity, and energy of the radiation detected by the scintillation means; second photodetection means capable of generating an electrical signal indicative of the position of the radiation in the radiation pattern; and means for optically coupling the scintillation means to the second photodetection means. The photodetection means are electrically connected to control and storage means which may also be used to screen out noise by rejecting a signal from one photodetection means not synchronized to a signal from the other photodetection means; and also to screen out signals from scattered radiation. 6 figs.

  2. X-Ray Diffraction Study of Elemental Erbium to 65 GPa

    SciTech Connect (OSTI)

    Pravica, M.G.; Lipinska-Kalita, K.; Quine, Z.; Romano, E.; Nicol, M.F. (UNLV)

    2006-02-02T23:59:59.000Z

    We have investigated phase transitions in elemental erbium in a diamond anvil cell up to 65 GPa using x-ray powder diffraction methods. We present preliminary evidence of a series of phase transitions that appear to follow the expected hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc sequence. In particular, we believe that we have evidence for the predicted dhcp {yields} distorted fcc transition between 43 GPa and 65 GPa.

  3. Measuring the x-ray resolving power of bent potassium acid phthalate diffraction crystals

    SciTech Connect (OSTI)

    Haugh, M. J., E-mail: haughmj@nv.doe.gov; Jacoby, K. D. [National Security Technologies, LLC, Livermore, California 94550 (United States); Wu, M.; Loisel, G. P. [Sandia National Laboratories, Albuquerque, New Mexico 87123 (United States)

    2014-11-15T23:59:59.000Z

    This report presents the results from measuring the X-ray resolving power of a curved potassium acid phthalate (KAP(001)) spectrometer crystal using two independent methods. It is part of a continuing effort to measure the fundamental diffraction properties of bent crystals that are used to study various characteristics of high temperature plasmas. Bent crystals like KAP(001) do not usually have the same diffraction properties as corresponding flat crystals. Models that do exist to calculate the effect of bending the crystal on the diffraction properties have simplifying assumptions and their accuracy limits have not been adequately determined. The type of crystals that we measured is being used in a spectrometer on the Z machine at Sandia National Laboratories in Albuquerque, New Mexico. The first technique for measuring the crystal resolving power measures the X-ray spectral line width of the characteristic lines from several metal anodes. The second method uses a diode X-ray source and a double crystal diffractometer arrangement to measure the reflectivity curve of the KAP(001) crystal. The width of that curve is inversely proportional to the crystal resolving power. The measurement results are analyzed and discussed.

  4. Time-resolved x-ray diffraction techniques for bulk polycrystalline materials under dynamic loading

    SciTech Connect (OSTI)

    Lambert, P. K.; Hustedt, C. J.; Zhao, M.; Ananiadis, A. G.; Hufnagel, T. C. [Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Vecchio, K. S. [Department of NanoEngineering, University of California San Diego, La Jolla, California 92093 (United States); Huskins, E. L. [Oak Ridge Institute for Science and Education, Oak Ridge, Tennessee 37830 (United States); US Army Research Laboratory, Aberdeen Proving Ground, Aberdeen, Maryland 21005 (United States); Casem, D. T. [US Army Research Laboratory, Aberdeen Proving Ground, Aberdeen, Maryland 21005 (United States); Gruner, S. M. [Department of Physics, Cornell University, Ithaca, New York 14853 (United States); Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Cornell University, Ithaca, New York 14853 (United States); Tate, M. W.; Philipp, H. T.; Purohit, P.; Weiss, J. T. [Department of Physics, Cornell University, Ithaca, New York 14853 (United States); Woll, A. R. [Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, New York 14853 (United States); Kannan, V.; Ramesh, K. T. [Department of Mechanical Engineering, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Kenesei, P.; Okasinski, J. S.; Almer, J. [X-ray Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

    2014-09-15T23:59:59.000Z

    We have developed two techniques for time-resolved x-ray diffraction from bulk polycrystalline materials during dynamic loading. In the first technique, we synchronize a fast detector with loading of samples at strain rates of ?10{sup 3}–10{sup 4} s{sup ?1} in a compression Kolsky bar (split Hopkinson pressure bar) apparatus to obtain in situ diffraction patterns with exposures as short as 70 ns. This approach employs moderate x-ray energies (10–20 keV) and is well suited to weakly absorbing materials such as magnesium alloys. The second technique is useful for more strongly absorbing materials, and uses high-energy x-rays (86 keV) and a fast shutter synchronized with the Kolsky bar to produce short (?40??s) pulses timed with the arrival of the strain pulse at the specimen, recording the diffraction pattern on a large-format amorphous silicon detector. For both techniques we present sample data demonstrating the ability of these techniques to characterize elastic strains and polycrystalline texture as a function of time during high-rate deformation.

  5. Absolute x-ray energy calibration over a wide energy range using a diffraction-based iterative method

    E-Print Network [OSTI]

    Duffy, Thomas S.

    Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794, USA 2 DepartmentAbsolute x-ray energy calibration over a wide energy range using a diffraction-based iterative;REVIEW OF SCIENTIFIC INSTRUMENTS 83, 063901 (2012) Absolute x-ray energy calibration over a wide energy

  6. 7 Å Resolution in Protein 2-Dimentional-Crystal X-Ray Diffraction at Linac Coherent Light Source

    SciTech Connect (OSTI)

    Pedrini, Bill; Tsai, Ching-Ju; Capitani, Guido; Padeste, Celestino; Hunter, Mark; Zatsepin, Nadia A.; Barty, Anton; Benner, Henry; Boutet, Sebastien; Feld, Geoffrey K.; Hau-Riege, Stefan; Kirian, Rick; Kupitz, Christopher; Messerschmidt, Marc; Ogren, John I.; Pardini, Tommaso; Segelke, Brent; Williams, Garth J.; Spence , John C.; Abela, Rafael; Coleman, Matthew A.; Evans, James E.; Schertler, Gebhard; Frank, Matthias; Li, Xiao-Dan

    2014-06-09T23:59:59.000Z

    Membrane proteins arranged as two-dimensional (2D) crystals in the lipid en- vironment provide close-to-physiological structural information, which is essential for understanding the molecular mechanisms of protein function. X-ray diffraction from individual 2D crystals did not represent a suitable investigation tool because of radiation damage. The recent availability of ultrashort pulses from X-ray Free Electron Lasers (X-FELs) has now provided a mean to outrun the damage. Here we report on measurements performed at the LCLS X-FEL on bacteriorhodopsin 2D crystals mounted on a solid support and kept at room temperature. By merg- ing data from about a dozen of single crystal diffraction images, we unambiguously identified the diffraction peaks to a resolution of 7 °A, thus improving the observable resolution with respect to that achievable from a single pattern alone. This indicates that a larger dataset will allow for reliable quantification of peak intensities, and in turn a corresponding increase of resolution. The presented results pave the way to further X-FEL studies on 2D crystals, which may include pump-probe experiments at subpicosecond time resolution.

  7. Data preparation and evaluation techniques for x-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Steinbrener, Jan; Nelson, Johanna; Huang, Xiaojing; Marchesini, Stefano; Shapiro, David; Turner, Joshua J.; Jacobsen, Chris

    2010-01-01T23:59:59.000Z

    The post-experiment processing of X-ray Diffraction Microscopy data is often time-consuming and difficult. This is mostly due to the fact that even if a preliminary result has been reconstructed, there is no definitive answer as to whether or not a better result with more consistently retrieved phases can still be obtained. We show here that the first step in data analysis, the assembly of two-dimensional diffraction patterns from a large set of raw diffraction data, is crucial to obtaining reconstructions of highest possible consistency. We have developed software that automates this process and results in consistently accurate diffraction patterns. Wemore »have furthermore derived some criteria of validity for a tool commonly used to assess the consistency of reconstructions, the phase retrieval transfer function, and suggest a modified version that has improved utility for judging reconstruction quality.« less

  8. Data preparation and evaluation techniques for x-ray diffraction microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Steinbrener, Jan; Nelson, Johanna; Huang, Xiaojing; Marchesini, Stefano; Shapiro, David; Turner, Joshua J.; Jacobsen, Chris

    2010-01-01T23:59:59.000Z

    The post-experiment processing of X-ray Diffraction Microscopy data is often time-consuming and difficult. This is mostly due to the fact that even if a preliminary result has been reconstructed, there is no definitive answer as to whether or not a better result with more consistently retrieved phases can still be obtained. We show here that the first step in data analysis, the assembly of two-dimensional diffraction patterns from a large set of raw diffraction data, is crucial to obtaining reconstructions of highest possible consistency. We have developed software that automates this process and results in consistently accurate diffraction patterns. We have furthermore derived some criteria of validity for a tool commonly used to assess the consistency of reconstructions, the phase retrieval transfer function, and suggest a modified version that has improved utility for judging reconstruction quality.

  9. Automated high pressure cell for pressure jump x-ray diffraction

    SciTech Connect (OSTI)

    Brooks, Nicholas J.; Gauthe, Beatrice L. L. E.; Templer, Richard H.; Ces, Oscar; Seddon, John M. [Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Terrill, Nick J. [Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE (United Kingdom); Rogers, Sarah E. [ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom)

    2010-06-15T23:59:59.000Z

    A high pressure cell for small and wide-angle x-ray diffraction measurements of soft condensed matter samples has been developed, incorporating a fully automated pressure generating network. The system allows both static and pressure jump measurements in the range of 0.1-500 MPa. Pressure jumps can be performed as quickly as 5 ms, both with increasing and decreasing pressures. Pressure is generated by a motorized high pressure pump, and the system is controlled remotely via a graphical user interface to allow operation by a broad user base, many of whom may have little previous experience of high pressure technology. Samples are loaded through a dedicated port allowing the x-ray windows to remain in place throughout an experiment; this facilitates accurate subtraction of background scattering. The system has been designed specifically for use at beamline I22 at the Diamond Light Source, United Kingdom, and has been fully integrated with the I22 beamline control systems.

  10. Time-, frequency-, and wavevector-resolved x-ray diffraction from single molecules

    SciTech Connect (OSTI)

    Bennett, Kochise, E-mail: kcbennet@uci.edu; Biggs, Jason D.; Zhang, Yu; Dorfman, Konstantin E.; Mukamel, Shaul, E-mail: smukamel@uci.edu [University of California, Irvine, California 92697-2025 (United States)

    2014-05-28T23:59:59.000Z

    Using a quantum electrodynamic framework, we calculate the off-resonant scattering of a broadband X-ray pulse from a sample initially prepared in an arbitrary superposition of electronic states. The signal consists of single-particle (incoherent) and two-particle (coherent) contributions that carry different particle form factors that involve different material transitions. Single-molecule experiments involving incoherent scattering are more influenced by inelastic processes compared to bulk measurements. The conditions under which the technique directly measures charge densities (and can be considered as diffraction) as opposed to correlation functions of the charge-density are specified. The results are illustrated with time- and wavevector-resolved signals from a single amino acid molecule (cysteine) following an impulsive excitation by a stimulated X-ray Raman process resonant with the sulfur K-edge. Our theory and simulations can guide future experimental studies on the structures of nano-particles and proteins.

  11. High-Angular-Resolution Microbeam X-Ray Diffraction with CCD Detector

    SciTech Connect (OSTI)

    Imai, Yasuhiko; Kimura, Shigeru; Sakaia, Akira [Japan Synchrotron Radiation Research Institute, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Sakata, Osami [Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama-cho, Toyonaka, Osaka 670-8531 (Japan)

    2010-04-06T23:59:59.000Z

    We have introduced a CCD-type two-dimensional X-ray detector for a microbeam X-ray diffraction system using synchrotron radiation, so that we can measure local reciprocal space maps (RSM) of samples rapidly. A local RSM of a strain-relaxed SiGe 004 grown on a Si (001) substrate was measured in higher-angular-resolution and faster than a conventional way. The measurement was achieved in 1 h 40 min. with the 2theta resolution of 80 murad and the spatial resolution of 1.4(h)x0.5(v) {mu}m{sup 2}. The introduction of the CCD enabled us to measure RSMs at many points in a sample, that is, the distribution of strain fields and lattice tilts can be revealed in high-angular- and high-spatial-resolution.

  12. Dimensionality and noise in energy selective x-ray imaging

    SciTech Connect (OSTI)

    Alvarez, Robert E. [Aprend Technology, Mountain View, California 94043 (United States)] [Aprend Technology, Mountain View, California 94043 (United States)

    2013-11-15T23:59:59.000Z

    Purpose: To develop and test a method to quantify the effect of dimensionality on the noise in energy selective x-ray imaging.Methods: The Cramèr-Rao lower bound (CRLB), a universal lower limit of the covariance of any unbiased estimator, is used to quantify the noise. It is shown that increasing dimensionality always increases, or at best leaves the same, the variance. An analytic formula for the increase in variance in an energy selective x-ray system is derived. The formula is used to gain insight into the dependence of the increase in variance on the properties of the additional basis functions, the measurement noise covariance, and the source spectrum. The formula is also used with computer simulations to quantify the dependence of the additional variance on these factors. Simulated images of an object with three materials are used to demonstrate the trade-off of increased information with dimensionality and noise. The images are computed from energy selective data with a maximum likelihood estimator.Results: The increase in variance depends most importantly on the dimension and on the properties of the additional basis functions. With the attenuation coefficients of cortical bone, soft tissue, and adipose tissue as the basis functions, the increase in variance of the bone component from two to three dimensions is 1.4 × 10{sup 3}. With the soft tissue component, it is 2.7 × 10{sup 4}. If the attenuation coefficient of a high atomic number contrast agent is used as the third basis function, there is only a slight increase in the variance from two to three basis functions, 1.03 and 7.4 for the bone and soft tissue components, respectively. The changes in spectrum shape with beam hardening also have a substantial effect. They increase the variance by a factor of approximately 200 for the bone component and 220 for the soft tissue component as the soft tissue object thickness increases from 1 to 30 cm. Decreasing the energy resolution of the detectors increases the variance of the bone component markedly with three dimension processing, approximately a factor of 25 as the resolution decreases from 100 to 3 bins. The increase with two dimension processing for adipose tissue is a factor of two and with the contrast agent as the third material for two or three dimensions is also a factor of two for both components. The simulated images show that a maximum likelihood estimator can be used to process energy selective x-ray data to produce images with noise close to the CRLB.Conclusions: The method presented can be used to compute the effects of the object attenuation coefficients and the x-ray system properties on the relationship of dimensionality and noise in energy selective x-ray imaging systems.

  13. The Coherent X-ray Imaging (CXI) Instrument at the Linac Coherent Light Source (LCLS)

    SciTech Connect (OSTI)

    Boutet, Sebastien; Williams, Garth J.; /SLAC; ,

    2011-08-16T23:59:59.000Z

    The Linac Coherent Light Source (LCLS) has become the first ever operational hard X-ray Free Electron Laser in 2009. It will operate as a user facility capable of delivering unique research opportunities in multiple fields of science. The LCLS and the LCLS Ultrafast Science Instruments (LUSI) construction projects are developing instruments designed to make full use of the capabilities afforded by the LCLS beam. One such instrument is being designed to utilize the LCLS coherent beam to image with high resolution any sub-micron object. This instrument is called the Coherent X-ray Imaging (CXI) instrument. This instrument will provide a flexible optical system capable of tailoring key beam parameters for the users. A suite of shot-to-shot diagnostics will also be provided to characterize the beam on every pulse. The provided instrumentation will include multi-purpose sample environments, sample delivery and a custom detector capable of collecting 2D data at 120 Hz. In this article, the LCLS will be briefly introduced along with the technique of Coherent X-ray Diffractive Imaging (CXDI). A few examples of scientific opportunities using the CXI instrument will be described. Finally, the conceptual layout of the instrument will be presented along with a description of the key requirements for the overall system and specific devices required.

  14. Fixture for supporting and aligning a sample to be analyzed in an x-ray diffraction apparatus

    DOE Patents [OSTI]

    Green, L.A.; Heck, J.L. Jr.

    1985-04-23T23:59:59.000Z

    A fixture is provided for supporting and aligning small samples of material on a goniometer for x-ray diffraction analysis. A sample-containing capillary is accurately positioned for rotation in the x-ray beam by selectively adjusting the fixture to position the capillary relative to the x and y axes thereof to prevent wobble and position the sample along the z axis or the axis of rotation. By employing the subject fixture relatively small samples of materials can be analyzed in an x-ray diffraction apparatus previously limited to the analysis of much larger samples.

  15. Imaging Nonequilibrium Atomic Vibrations with X-ray Diffuse Scattering

    SciTech Connect (OSTI)

    Trigo, M.; Chen, J.; Vishwanath, V.H.; /SLAC; Sheu, Y.M.; /Michigan U.; Graber, T.; Henning, R.; /U. Chicago; Reis, D; /SLAC /Stanford U., Appl. Phys. Dept.; ,

    2011-03-03T23:59:59.000Z

    We use picosecond x-ray diffuse scattering to image the nonequilibrium vibrations of the lattice following ultrafast laser excitation. We present images of nonequilibrium phonons in InP and InSb throughout the Brillouin-zone which remain out of equilibrium up to nanoseconds. The results are analyzed using a Born model that helps identify the phonon branches contributing to the observed features in the time-resolved diffuse scattering. In InP this analysis shows a delayed increase in the transverse acoustic (TA) phonon population along high-symmetry directions accompanied by a decrease in the longitudinal acoustic (LA) phonons. In InSb the increase in TA phonon population is less directional.

  16. Investigation of the hard x-ray background in backlit pinhole imagers

    SciTech Connect (OSTI)

    Fein, J. R., E-mail: jrfein@umich.edu; Holloway, J. P. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109-2143 (United States); Peebles, J. L. [Center for Energy Research, University of California, San Diego, La Jolla, California 92093 (United States); Keiter, P. A.; Klein, S. R.; Kuranz, C. C.; Manuel, M. J.-E.; Drake, R. P. [Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, Ann Arbor, Michigan 48109-2143 (United States)

    2014-11-15T23:59:59.000Z

    Hard x-rays from laser-produced hot electrons (>10 keV) in backlit pinhole imagers can give rise to a background signal that decreases signal dynamic range in radiographs. Consequently, significant uncertainties are introduced to the measured optical depth of imaged plasmas. Past experiments have demonstrated that hard x-rays are produced when hot electrons interact with the high-Z pinhole substrate used to collimate the softer He-? x-ray source. Results are presented from recent experiments performed on the OMEGA-60 laser to further study the production of hard x-rays in the pinhole substrate and how these x-rays contribute to the background signal in radiographs. Radiographic image plates measured hard x-rays from pinhole imagers with Mo, Sn, and Ta pinhole substrates. The variation in background signal between pinhole substrates provides evidence that much of this background comes from x-rays produced in the pinhole substrate itself. A Monte Carlo electron transport code was used to model x-ray production from hot electrons interacting in the pinhole substrate, as well as to model measurements of x-rays from the irradiated side of the targets, recorded by a bremsstrahlung x-ray spectrometer. Inconsistencies in inferred hot electron distributions between the different pinhole substrate materials demonstrate that additional sources of hot electrons beyond those modeled may produce hard x-rays in the pinhole substrate.

  17. High Pressure X-ray Diffraction Study on Icosahedral Boron Arsenide (B12As2)

    SciTech Connect (OSTI)

    J Wu; H Zhu; D Hou; C Ji; C Whiteley; J Edgar; Y Ma

    2011-12-31T23:59:59.000Z

    The high pressure properties of icosahedral boron arsenide (B12As2) were studied by in situ X-ray diffraction measurements at pressures up to 25.5 GPa at room temperature. B12As2 retains its rhombohedral structure; no phase transition was observed in the pressure range. The bulk modulus was determined to be 216 GPa with the pressure derivative 2.2. Anisotropy was observed in the compressibility of B12As2-c-axis was 16.2% more compressible than a-axis. The boron icosahedron plays a dominant role in the compressibility of boron-rich compounds.

  18. An X-ray Imaging Study of the Stellar Population in RCW49

    E-Print Network [OSTI]

    M. Tsujimoto; E. D. Feigelson; L. K. Townsley; P. S. Broos; K. V. Getman; J. Wang; G. P. Garmire; D. Baba; T. Nagayama; M. Tamura; E. B. Churchwell

    2007-05-04T23:59:59.000Z

    We present the results of a high-resolution X-ray imaging study of the stellar population in the Galactic massive star-forming region RCW49 and its central OB association Westerlund 2. We obtained a 40 ks X-ray image of a 17'x17' field using the Chandra X-ray Observatory and deep NIR images using the Infrared Survey Facility in a concentric 8'3x8'3 region. We detected 468 X-ray sources and identified optical, NIR, and Spitzer Space Telescope MIR counterparts for 379 of them. The unprecedented spatial resolution and sensitivity of the X-ray image, enhanced by optical and infrared imaging data, yielded the following results: (1) The central OB association Westerlund 2 is resolved for the first time in the X-ray band. X-ray emission is detected from all spectroscopically-identified early-type stars in this region. (2) Most (86%) X-ray sources with optical or infrared identifications are cluster members in comparison with a control field in the Galactic Plane. (3) A loose constraint (2--5 kpc) for the distance to RCW49 is derived from the mean X-ray luminosity of T Tauri stars. (4) The cluster X-ray population consists of low-mass pre--main-sequence and early-type stars as obtained from X-ray and NIR photometry. About 30 new OB star candidates are identified. (5) We estimate a cluster radius of 6'--7' based on the X-ray surface number density profiles. (6) A large fraction (90%) of cluster members are identified individually using complimentary X-ray and MIR excess emission. (7) The brightest five X-ray sources, two Wolf-Rayet stars and three O stars, have hard thermal spectra.

  19. Hard X-ray Microscopic Images of the Human Hair

    SciTech Connect (OSTI)

    Goo, Jawoong; Jeon, Soo Young; Oh, Tak Heon; Hong, Seung Phil; Lee, Won-Soo [Department of Dermatology and Institute of Hair and Cosmetic Medicine, Yonsei University Wonju College of Medicine, Wonju (Korea, Republic of); Yon, Hwa Shik [Pohang Accelerator Laboratory, Pohang University of Science and Technology, Pohang (Korea, Republic of)

    2007-01-19T23:59:59.000Z

    The better visualization of the human organs or internal structure is challenging to the physicist and physicians. It can lead to more understanding of the morphology, pathophysiology and the diagnosis. Conventionally used methods to investigate cells or architectures, show limited value due to sample processing procedures and lower resolution. In this respect, Zernike type phase contrast hard x-ray microscopy using 6.95keV photon energy has advantages. We investigated hair fibers of the normal healthy persons. Coherence based phase contrast images revealed three distinct structures of hair, medulla, cortex, and cuticular layer. Some different detailed characters of each sample were noted. And further details would be shown and these results would be utilized as basic data of morphologic study of human hair.

  20. Automatic Extraction of Femur Contours from Hip X-ray Images

    E-Print Network [OSTI]

    Leow, Wee Kheng

    for large and complex bones in x-ray images. For instance, in a femur x-ray image (Fig. 1), the femoral head interior within solid bony walls (Fig. 1a). Moreover, the femoral head overlaps with the pelvis bone. In this case, the extraction of bone contours becomes a more complex problem than classical image segmentation

  1. Mechanics of Microelectronics Structures as Revealed by X-ray Diffraction

    SciTech Connect (OSTI)

    Murray,C.; Yan, H.; Noyan, I.

    2007-01-01T23:59:59.000Z

    The presence of strain distributions within semiconductor features influences many aspects of their behavior. For example, microelectronic technology that incorporates strained silicon improves device performance by increasing carrier mobility in the Si channels. Because current semiconductor fabrication contains multiple levels of metallic and dielectric structures, an understanding of the mechanical response of the constituent elements is critical to the prediction of the overall device performance. In addition, the interaction of strain fields between adjacent structures becomes greater as feature sizes decrease and the corresponding feature density increases. The use of synchrotron-based X-ray methods allows one to determine the interaction between strained features and their environment at a submicron resolution. Real-space mapping of strain distributions in pseudomorphically strained, raised SiGe structures revealed that elastic relaxation extends approximately 20 times the feature thickness from their edges. X-ray topographic methods were also applied to map the substrate deformation induced by overlying SiGe features. A formulation based on the classical Ewald-von Laue theory of dynamical diffraction was derived to match the measured diffraction profiles.

  2. High-pressure powder x-ray diffraction study of EuVO4

    E-Print Network [OSTI]

    Garg, Alka B

    2015-01-01T23:59:59.000Z

    The high-pressure structural behavior of europium orthovanadate has been studied using in-situ, synchrotron based, high-pressure x-ray powder diffraction technique. Angle-dispersive x-ray diffraction measurements were carried out at room temperature up to 34.7 GPa using a diamond-anvil cell, extending the pressure range reported in previous experiments. We confirmed the occurrence of zircon-scheelite phase transition at 6.8 GPa and the coexistence of low- and high-pressure phases up to 10.1 GPa. In addition, clear evidence of a scheelite-fregusonite transition is found at 23.4 GPa. The fergusonite structure remains stable up to 34.7 GPa, the highest pressure reached in the present measurements. A partial decomposition of EuVO4 was also observed from 8.1 to 12.8 GPa, however, this fact did not preclude the identification of the different crystal structures of EuVO4. The crystal structures of the different phases have been Rietveld refined and their equations of state (EOS) have been determined. The results are...

  3. First results from a next-generation off-plane X-ray diffraction grating

    E-Print Network [OSTI]

    McEntaffer, Randall; Schultz, Ted; Gantner, Brennan; Tutt, James; Holland, Andrew; O'Dell, Stephen; Gaskin, Jessica; Kolodziejczak, Jeffrey; Zhang, William W; Chan, Kai-Wing; Biskach, Michael; McClelland, Ryan; Iazikov, Dmitri; Wang, Xinpeng; Koecher, Larry

    2013-01-01T23:59:59.000Z

    Future NASA X-ray spectroscopy missions will require high throughput, high resolution grating spectrometers. Off-plane reflection gratings are capable of meeting the performance requirements needed to realize the scientific goals of these missions. We have identified a novel grating fabrication method that utilizes common lithographic and microfabrication techniques to produce the high fidelity groove profile necessary to achieve this performance. Application of this process has produced an initial pre-master that exhibits a radial (variable line spacing along the groove dimension), high density (>6000 grooves/mm), laminar profile. This pre-master has been tested for diffraction efficiency at the BESSY II synchrotron light facility and diffracts up to 55% of incident light into usable spectral orders. Furthermore, tests of spectral resolving power show that these gratings are capable of obtaining resolutions well above 1300 ($\\lambda/\\Delta\\lambda$) with limitations due to the test apparatus, not the gratings...

  4. High-pressure X-ray diffraction and X-ray emission studies on iron-bearing silicate perovskite under high pressures

    SciTech Connect (OSTI)

    Lin, Jung-Fu; Speciale, Sergio; Prakapenka, Vitali B.; Dera, Przemek; Lavina, Babara; Watson, Heather C. (NIU); (UC); (Texas); (GFZ)

    2010-06-22T23:59:59.000Z

    Iron-bearing silicate perovskite is believed to be the most abundant mineral of the Earth's lower mantle. Recent studies have shown that Fe{sup 2+} exists predominantly in the intermediate-spin state with a total spin number of 1 in silicate perovskite in the lower part of the lower mantle. Here we have measured the spin states of iron and the pressure-volume relation in silicate perovskite [(Mg{sub 0.6},Fe{sub 0.4})SiO{sub 3}] at pressure conditions relevant to the lowermost mantle using in situ X-ray emission and X-ray diffraction in a diamond cell. Our results showed that the intermediate-spin Fe{sup 2+} is stable in the silicate perovskite up to {approx} 125 GPa but starts to transition to the low-spin state at approximately 135 GPa. Concurrent X-ray diffraction measurements showed a decrease of approximately 1% in the unit cell volume in the silicate perovskite [(Mg{sub 0.6},Fe{sub 0.4})SiO{sub 3}], which is attributed to the intermediate-spin to the low-spin transition. The transition pressure coincides with the pressure conditions of the lowermost mantle, raising the possibility of the existence of the silicate perovskite phase with the low-spin Fe{sup 2+} across the transition from the post-perovskite to the perovskite phases in the bottom of the D{double_prime} layer.

  5. SIMULATION OF ENERGY SELECTIVE X-RAY IMAGES FOR MATERIAL DIS-CRIMINATION

    E-Print Network [OSTI]

    Hickman, Mark

    SIMULATION OF ENERGY SELECTIVE X-RAY IMAGES FOR MATERIAL DIS- CRIMINATION Rune S Thing1 , Syen J Carlo model is presented to evaluate the clinical benefits of optimal energy bins in spectral X-ray imaging, using the BEAMnrc code system. While energy resolving photon counting detectors have been

  6. In-orbit performance of the XMM-Newton X-ray telescopes: images and spectra

    E-Print Network [OSTI]

    B. Aschenbach

    2001-09-21T23:59:59.000Z

    The performance of the three X-ray telescopes on-board of XMM-Newton is evaluated addressing imaging characteristics and effective collecting area. The agreement with ground calibration data is excellent. The analysis of images and spectra of cosmic X-ray sources, emphazising supernova and supernova remnants, prooves that the telescopes are even better than originally required.

  7. Crystal structures of N sub 2 O to 12 GPa by x-ray diffraction

    SciTech Connect (OSTI)

    Mills, R.L.; Olinger, B.; Cromer, D.T.; LeSar, R. (University of California, Los Alamos National Laboratory, Los Alamos, New Mexico (USA))

    1991-10-01T23:59:59.000Z

    The structures and phase transitions of N{sub 2}O were studied by powder x-ray diffraction in a tungsten--carbide anvil device from about 100 to 300 K and 2 to 12 GPa. Two solid phases, {alpha}-N{sub 2}O and {beta}-N{sub 2}O, were observed. The {alpha} pattern is consistent with the known low-pressure low-temperature ordered cubic form, space group Pa3, up to 4.8 GPa where transition to a new {beta} solid occurs. From refinements using photographic x-ray intensities, the {beta}-N{sub 2}O structure was determined to be orthorhombic Cmca. There are four molecules in a unit cell with {ital a}=4.954 A, {ital b}=4.497 A, and {ital c}=6.201 A at 5.81 GPa and 298 K. The molecular axes lie parallel to the {ital bc} plane and are tipped at an angle of 37.2{degree} to the {ital b} axis. Random head-to-tail orientation is probable in both solids. The phase diagram and values of the molar volume for N{sub 2}O are compared with published data for the isoelectronic molecule CO{sub 2}. Recent theoretical calculations correctly predict the {beta}-N{sub 2}O structure.

  8. An in-vacuum x-ray diffraction microscope for use in the 0.7-2.9 keV range

    SciTech Connect (OSTI)

    Vine, D. J. [Australian Research Council Centre of Excellence for Coherent X-ray Science (Australia); School of Physics, University of Melbourne, Victoria 3010 (Australia); Argonne National Laboratory, Argonne, Illinois 60439 (United States); Williams, G. J. [Australian Research Council Centre of Excellence for Coherent X-ray Science (Australia); SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Clark, J. N. [Australian Research Council Centre of Excellence for Coherent X-ray Science (Australia); Department of Physics, La Trobe University, Bundoora, Victoria 3086 (Australia); London Centre for Nanotechnology, University College, London WC1E 6BT (United Kingdom); Putkunz, C. T.; Abbey, B.; Nugent, K. A. [Australian Research Council Centre of Excellence for Coherent X-ray Science (Australia); School of Physics, University of Melbourne, Victoria 3010 (Australia); Pfeifer, M. A. [Australian Research Council Centre of Excellence for Coherent X-ray Science (Australia); Cornell High Energy Synchrotron Source, Cornell University, Ithaca, New York 14850 (United States); Legnini, D.; Roehrig, C.; Wrobel, E.; McNulty, I. [Argonne National Laboratory, Argonne, Illinois 60439 (United States); Huwald, E. [Department of Physics, La Trobe University, Bundoora, Victoria 3086 (Australia); Riessen, G. van; Peele, A. G. [Australian Research Council Centre of Excellence for Coherent X-ray Science (Australia); Department of Physics, La Trobe University, Bundoora, Victoria 3086 (Australia); Beetz, T.; Irwin, J.; Feser, M.; Hornberger, B. [Xradia, Inc., 4385 Hopyard Road, Pleasanton, California 94588 (United States)

    2012-03-15T23:59:59.000Z

    A dedicated in-vacuum coherent x-ray diffraction microscope was installed at the 2-ID-B beamline of the Advanced Photon Source for use with 0.7-2.9 keV x-rays. The instrument can accommodate three common implementations of diffractive imaging; plane wave illumination; defocused-probe (Fresnel diffractive imaging) and scanning (ptychography) using either a pinhole, focused or defocused probe. The microscope design includes active feedback to limit motion of the optics with respect to the sample. Upper bounds on the relative optics-to-sample displacement have been measured to be 5.8 nm(v) and 4.4 nm(h) rms/h using capacitance micrometry and 27 nm/h using x-ray point projection imaging. The stability of the measurement platform and in-vacuum operation allows for long exposure times, high signal-to-noise and large dynamic range two-dimensional intensity measurements to be acquired. Finally, we illustrate the microscope's stability with a recent experimental result.

  9. X-ray backscatter imaging of nuclear materials

    DOE Patents [OSTI]

    Chapman, Jeffrey Allen; Gunning, John E; Hollenbach, Daniel F; Ott, Larry J; Shedlock, Daniel

    2014-09-30T23:59:59.000Z

    The energy of an X-ray beam and critical depth are selected to detect structural discontinuities in a material having an atomic number Z of 57 or greater. The critical depth is selected by adjusting the geometry of a collimator that blocks backscattered radiation so that backscattered X-ray originating from a depth less than the critical depth is not detected. Structures of Lanthanides and Actinides, including nuclear fuel rod materials, can be inspected for structural discontinuities such as gaps, cracks, and chipping employing the backscattered X-ray.

  10. High-temperature/high-pressure x-ray diffraction: Recent developments

    SciTech Connect (OSTI)

    Schiferl, D.; Johnson, S.W.; Zinn, A.S.

    1989-01-01T23:59:59.000Z

    We have developed two Merrill-Bassett diamond-anvil cells for specialized high-temperature uses. The first is constructed largely of rhenium to provide uniform, constant P and T on the order of 20 GPa at 1200 K for extended periods. The second is for single-crystal x-ray diffraction, but can be heated to 630 K at 20 GPa to grow single-crystal samples which cannot be produced at room temperature. With this cell, the crystal structure of /var epsilon/-O/sub 2/ was shown to be monoclinic with a = 3.649 A, b = 5.493 A, c = 7.701 A, and /Beta/ = 116.11/degree/ at 19.7 GPa. 15 refs.

  11. Kinetics of Methane Hydrate Decomposition Studied via in Situ Low Temperature X-ray Powder Diffraction

    SciTech Connect (OSTI)

    Everett, Susan M [ORNL; Rawn, Claudia J [ORNL; Keffer, David J. [University of Tennessee, Knoxville (UTK); Mull, Derek L [ORNL; Payzant, E Andrew [ORNL; Phelps, Tommy Joe [ORNL

    2013-01-01T23:59:59.000Z

    Gas hydrates are known to have a slowed decomposition rate at ambient pressure and temperatures below the melting point of ice termed self-preservation or anomalous preservation. As hydrate exothermically decomposes, gas is released and water of the clathrate cages transforms into ice. Two regions of slowed decomposition for methane hydrate, 180 200 K and 230 260 K, were observed, and the kinetics were studied by in situ low temperature x-ray powder diffraction. The kinetic constants for ice formation from methane hydrate were determined by the Avrami model within each region and activation energies, Ea, were determined by the Arrhenius plot. Ea determined from the data for 180 200 K was 42 kJ/mol and for 230 260 K was 22 kJ/mol. The higher Ea in the colder temperature range was attributed to a difference in the microstructure of ice between the two regions.

  12. Development of Hard X-ray Imaging Optics with Two Pairs of Elliptical and Hyperbolic Mirrors

    SciTech Connect (OSTI)

    Matsuyama, S.; Fujii, M.; Wakioka, T.; Mimura, H.; Handa, S.; Kimura, T. [Department of Precision Science and Technology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan); Nishino, Y.; Tamasaku, K.; Makina, Y.; Ishikawa, T. [SPring-8/RIKEN, 1-1-1 Kouto, Sayoucho, Sayogun, Hyogo 679-5148 (Japan); Yamauchi, K. [Department of Precision Science and Technology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan); Research Center for Ultra-Precision Science and Technology, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan)

    2010-06-23T23:59:59.000Z

    To form a magnified hard X-ray image with a 50 nm resolution, we have studied total reflection mirror optics with two pairs of elliptical and hyperbolic mirrors, which is called 'Advanced Kirkpatrick-Baez system'. A designed optical system has 200x and 300x magnifications in vertical and horizontal directions. Also diffraction limit size in the optical system is 40 nmx45 nm. We fabricated a pair of elliptical and hyperbolic mirrors for horizontal imaging with a figure accuracy of 2 nm using elastic emission machining (EEM), microstitching interferometry (MSI) and relative-angle-determinable stitching interferometry (RADSI). One-dimensional tests for forming a demagnified image of a slit were carried out at an X-ray energy of 11.5 keV at BL29XUL (EH2) of SPring-8. As a result, a shape beam with a FWHM of 78 nm was observed. This demonstrates that we realized one-dimensional Wolter optics that has a spatial resolution of 78 nm.

  13. Systems and methods for detecting an image of an object by use of an X-ray beam having a polychromatic distribution

    DOE Patents [OSTI]

    Parham, Christopher; Zhong, Zhong; Pisano, Etta; Connor, Dean; Chapman, Leroy D.

    2010-06-22T23:59:59.000Z

    Systems and methods for detecting an image of an object using an X-ray beam having a polychromatic energy distribution are disclosed. According to one aspect, a method can include detecting an image of an object. The method can include generating a first X-ray beam having a polychromatic energy distribution. Further, the method can include positioning a single monochromator crystal in a predetermined position to directly intercept the first X-ray beam such that a second X-ray beam having a predetermined energy level is produced. Further, an object can be positioned in the path of the second X-ray beam for transmission of the second X-ray beam through the object and emission from the object as a transmitted X-ray beam. The transmitted X-ray beam can be directed at an angle of incidence upon a crystal analyzer. Further, an image of the object can be detected from a beam diffracted from the analyzer crystal.

  14. A wavelet transform algorithm for peak detection and application to powder x-ray diffraction data

    SciTech Connect (OSTI)

    Gregoire, John M.; Dale, Darren; van Dover, R. Bruce

    2011-01-01T23:59:59.000Z

    Peak detection is ubiquitous in the analysis of spectral data. While many noise-filtering algorithms and peak identification algorithms have been developed, recent work [P. Du, W. Kibbe, and S. Lin, Bioinformatics 22, 2059 (2006); A. Wee, D. Grayden, Y. Zhu, K. Petkovic-Duran, and D. Smith, Electrophoresis 29, 4215 (2008)] has demonstrated that both of these tasks are efficiently performed through analysis of the wavelet transform of the data. In this paper, we present a wavelet-based peak detection algorithm with user-defined parameters that can be readily applied to the application of any spectral data. Particular attention is given to the algorithm's resolution of overlapping peaks. The algorithm is implemented for the analysis of powder diffraction data, and successful detection of Bragg peaks is demonstrated for both low signal-to-noise data from theta–theta diffraction of nanoparticles and combinatorial x-ray diffraction data from a composition spread thin film. These datasets have different types of background signals which are effectively removed in the wavelet-based method, and the results demonstrate that the algorithm provides a robust method for automated peak detection.

  15. ZnTe:O phosphor development for x-ray imaging applications

    SciTech Connect (OSTI)

    Kang, Z.T.; Summers, C.J.; Menkara, H.; Wagner, B.K.; Durst, R.; Diawara, Y.; Mednikova, G.; Thorson, T. [Phosphor Technology Center of Excellence, School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245 (United States); Georgia Tech Research Institute, Georgia Institute of Technology, Atlanta, Georgia 30332-0826 (United States); Bruker AXS 5465 East Cheryl Parkway, Madison Wisconson 53711 (United States)

    2006-03-13T23:59:59.000Z

    An efficient ZnTe:O x-ray powder phosphor was prepared by a dry synthesis process using gaseous doping and etching medias. The x-ray luminescent properties were evaluated and compared to standard commercial phosphors exhibited an x-ray luminescent efficiency equivalent to 76% of Gd{sub 2}O{sub 2}S:Tb and an equal resolution of 2.5 lines/mm. In addition, the fast decay time, low afterglow, and superior spectral match to conventional charge-coupled devices-indicate that ZnTe:O is a very promising phosphor candidate for x-ray imaging applications.

  16. X-ray Image Bank Open for Business - NERSC Center News, Feb 22, 2011

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-RayX-rayX-ray Image

  17. Reactive sputter magnetron reactor for preparation of thin films and simultaneous in situ structural study by X-ray diffraction

    SciTech Connect (OSTI)

    Buergi, J.; Molleja, J. Garcia; Feugeas, J. [Instituto de Fisica Rosario (CONICET-UNR), Bv. 27 de Febrero 210 bis, S2000EZP Rosario (Argentina); Neuenschwander, R. [Laboratorio Nacional Luz Sincrotron (LNLS), Caixa Postal 6192, CEP13083-970 Campinas (Brazil); Kellermann, G. [Departamento de Fisica (Universidade Federal do Parana), Caixa Postal 19044, CEP81531-990 Curitiba (Brazil); Craievich, A. F. [Instituto de Fisica (Universidade de Sao Paulo), Rua do Matao Travessa R 187, CEP05508-090 Sao Paulo (Brazil)

    2013-01-15T23:59:59.000Z

    The purpose of the designed reactor is (i) to obtain polycrystalline and/or amorphous thin films by controlled deposition induced by a reactive sputtering magnetron and (ii) to perform a parallel in situ structural study of the deposited thin films by X-ray diffraction, in real time, during the whole growth process. The designed reactor allows for the control and precise variation of the relevant processing parameters, namely, magnetron target-to-sample distance, dc magnetron voltage, and nature of the gas mixture, gas pressure and temperature of the substrate. On the other hand, the chamber can be used in different X-ray diffraction scanning modes, namely, {theta}-2{theta} scanning, fixed {alpha}-2{theta} scanning, and also low angle techniques such as grazing incidence small angle X-ray scattering and X-ray reflectivity. The chamber was mounted on a standard four-circle diffractometer located in a synchrotron beam line and first used for a preliminary X-ray diffraction analysis of AlN thin films during their growth on the surface of a (100) silicon wafer.

  18. Imaging Performance of the XMM-Newton X-ray telescopes

    E-Print Network [OSTI]

    B. Aschenbach; U. Briel; F. Haberl; H. Braeuninger; W. Burkert; A. Oppitz; P. Gondoin; D. Lumb

    2000-07-18T23:59:59.000Z

    The in-orbit imaging performance of the three X-ray telescopes on board of the X-ray astronomy observatory XMM-Newton is presented and compared with the performance measured on ground at the MPE PANTER test facility. The comparison shows an excellent agreement between the on ground and in-orbit performance.

  19. Characterization of Diffraction-Enhanced Imaging

    SciTech Connect (OSTI)

    Kao, T.; Connor, D; Dilmanian, F; Faulconer, L; Liu, T; Parham, C; Pisano, E; Zhong, Z

    2009-01-01T23:59:59.000Z

    Diffraction-enhanced imaging (DEI) is a new x-ray imaging modality that has been shown to enhance contrast between normal and cancerous breast tissues. In this study, diffraction-enhanced imaging in computed tomography (DEI-CT) mode was used to quantitatively characterize the refraction contrasts of the organized structures associated with invasive human breast cancer. Using a high-sensitivity Si (3 3 3) reflection, the individual features of breast cancer, including masses, calcifications and spiculations, were observed. DEI-CT yields 14, 5 and 7 times higher CT numbers and 10, 9 and 6 times higher signal-to-noise ratios (SNR) for masses, calcifications and spiculations, respectively, as compared to conventional CT of the same specimen performed using the same detector, x-ray energy and dose. Furthermore, DEI-CT at ten times lower dose yields better SNR than conventional CT. In light of the recent development of a compact DEI prototype using an x-ray tube as its source, these results, acquired at a clinically relevant x-ray energy for which a pre-clinical DEI prototype currently exists, suggest the potential of clinical implementation of mammography with DEI-CT to provide high-contrast, high-resolution images of breast cancer (Parham 2006 PhD Dissertation University of North Carolina at Chapel Hill).

  20. Mossbauer spectroscopic and x-ray diffraction studies of FeSiO2 nanocomposite soft magnetic materials

    E-Print Network [OSTI]

    Yang, De-Ping

    Mo¨ssbauer spectroscopic and x-ray diffraction studies of FeÕSiO2 nanocomposite soft magnetic. The compositions of the precursor and the successive heat-treated samples have been investigated by 57 Fe Mo¨ssbauer a synthesis of Fe/SiO2 nanocomposites and a study of their magnetic and structural properties using Mo¨ssbauer

  1. X-ray diffraction studies and equation of state of methane at 202 GPa Liling Sun a,*, Wei Yi a

    E-Print Network [OSTI]

    Shen, Guoyin

    X-ray diffraction studies and equation of state of methane at 202 GPa Liling Sun a,*, Wei Yi that at room temperature compressed CH4 remains an insulator with cubic structure to 202 GPa. Ó 2009 Elsevier B of planetary interiors and the origin of their magnetic field distribution. CH4 has a very rich phase diagram

  2. High temperature x ray diffraction determination of the body-centered-cubicface-centered-cubic transformation temperature in

    E-Print Network [OSTI]

    McHenry, Michael E.

    , generators, transformers, sensors,1 and, more recently, for magnetic refrigeration.4­6 Recently 16 February 2012) In situ high-temperature x ray diffraction and magnetization measurements were.1063/1.3675990] INTRODUCTION Fe-Ni alloys have been extensively studied, due to their technologically important magnetic

  3. Tamper to delay motion and decrease ionization of a sample during short pulse x-ray imaging

    DOE Patents [OSTI]

    London, Richard A. (Orinda, CA); Szoke; Abraham (Fremont, CA), Hau-Riege; Stefan P. (Fremont, CA), Chapman; Henry N. (Livermore, CA)

    2007-06-26T23:59:59.000Z

    A system for x-ray imaging of a small sample comprising positioning a tamper so that it is operatively connected to the sample, directing short intense x-ray pulses onto the tamper and the sample, and detecting an image from the sample. The tamper delays the explosive motion of the sample during irradiation by the short intense x-ray pulses, thereby extending the time to obtain an x-ray image of the original structure of the sample.

  4. In-line x-ray phase-contrast tomography and diffraction-contrast tomography study of the ferrite-cementite microstructure in steel

    E-Print Network [OSTI]

    van Vliet, Lucas J.

    In-line x-ray phase-contrast tomography and diffraction-contrast tomography study of the ferrite;In-line X-ray phase-contrast tomography and diffraction-contrast tomography study of the ferrite embedded in a ferrite matrix of medium-carbon steel. The measurements were carried out at the material

  5. Blazed high-efficiency x-ray diffraction via transmission through arrays of

    E-Print Network [OSTI]

    with the x-ray microscope at BESSY," Rev. Sci. Instrum. 66, 1282-1286 (1995). 12. A. G. Klein and S. A

  6. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation Print Magnetic thin-film nanostructures can exhibit a magnetic vortex state in which the magnetization vectors lie in...

  7. A Combinational Approach to the Fusion, De-noising and Enhancement of Dual-Energy X-Ray Luggage Images

    E-Print Network [OSTI]

    Abidi, Mongi A.

    dual-energy X-ray images for better object classification and threat detection. The fusion stepA Combinational Approach to the Fusion, De-noising and Enhancement of Dual-Energy X-Ray Luggage-based noise reduction technique which is very efficient in removing background noise from fused X-ray images

  8. Analysis of X-Ray Diffraction as a Probe of Interdiffusion in Si/SiGe Heterostructures

    SciTech Connect (OSTI)

    Brennan, Sean M

    2003-08-20T23:59:59.000Z

    We investigate numerical simulations that utilize a non-linear interdiffusion solver and dynamical x-ray diffraction calculations to predict the local composition evolution in low Ge concentration Si/SiGe superlattices and their diffraction patterns during annealing. Superlattice satellite peak decay rates are compared with experimentally measured values and simulated diffraction patterns are matched directly to data with good success. The simulations are used to test the sensitivity of x-ray diffraction to various uncertainties commonly encountered when measuring interdiffusion at Si/SiGe interfaces. It is found that the most serious errors result from variations in the Ge content across the surface of the wafer. For example, the resolution limit of most experimental techniques used to measure Ge concentration in a SiGe film is -1 at.%, for a film with 11% mean Ge concentration annealed for 5 hours at 870 C, this level of error will cause the observed interdiffusivity values to deviate by -25% or +50%. The simulations are further used to show that for Si/SiGe interdiffusion, superlattice diffraction produces valid measurements when applied to 004 superlattice satellite peaks and square wave composition modulations even though it is only exactly applicable to satellite peaks about 000 reflection and to sinusoidal composition modulations. Finally, we show that proper interpretation of x-ray scattering data to extract Si/SiGe interdiffusivity values must account for the strong dependence of the interdiffusivity on Ge concentration.

  9. Probing Martensitic Transition in Nitinol Wire: A Comparison of X-ray Diffraction and Other Techniques

    SciTech Connect (OSTI)

    Butler, J.; Tiernan, P.; Tofail, S. A. M.; Ghandi, A. A. [Materials and Surface Science Institute, University of Limerick, Limerick (Ireland)

    2011-01-17T23:59:59.000Z

    Martensitic to austenite transformation in Nitinol wire can be measured by a number of techniques such as XRD (X-Ray Diffraction), DSC (Differential Scanning Calorimetry), BFR (Bend and Free Recovery) and Vickers indentation recovery. A comparison of results from these varied characterisation techniques is reported here to obtain a greater understanding of the thermal-elastic-structural changes associated with martensitic transformation. The transformation temperatures measured by DSC were found to correspond well with the structural and mechanical information obtained from XRD, BFR and Vickers indent recovery methods. Indent recovery is a relatively new and accurate method of monitoring stress induced martensitic transformations in NiTi and is one of only a few methods of stress inducing martensitic transformation in large scale samples. It is especially useful for NiTi in the as-cast billet form, where tensile testing is impossible. BFR is uniquely popular in the NiTi wire manufacturing sector and is recognised as the most accurate method of measuring the transformation temperature. Here the material is stressed to a representative in-service stress level during the test. No other test uses the shape memory effect for measuring the transformation temperature of NiTi. The results show that the DSC thermogram and XRD diffractogram have a peak overlap which is a common occurrence in NiTi that has been extensively processed. The XRD method further explains the observations in the DSC thermogram and in combination they confirm the transformation temperature.

  10. X-ray tomographic image magnification process, system and apparatus therefor

    DOE Patents [OSTI]

    Kinney, J.H.; Bonse, U.K.; Johnson, Q.C.; Nichols, M.C.; Saroyan, R.A.; Massey, W.N.; Nusshardt, R.

    1993-09-14T23:59:59.000Z

    A computerized three-dimensional x-ray tomographic microscopy system is disclosed, comprising: (a) source means for providing a source of parallel x-ray beams, (b) staging means for staging and sequentially rotating a sample to be positioned in the path of the (c) x-ray image magnifier means positioned in the path of the beams downstream from the sample, (d) detecting means for detecting the beams after being passed through and magnified by the image magnifier means, and (e) computing means for analyzing values received from the detecting means, and converting the values into three-dimensional representations. Also disclosed is a process for magnifying an x-ray image, and apparatus therefor. 25 figures.

  11. X-ray tomographic image magnification process, system and apparatus therefor

    DOE Patents [OSTI]

    Kinney, John H. (Danville, CA); Bonse, Ulrich K. (Dortmund, DE); Johnson, Quintin C. (Livermore, CA); Nichols, Monte C. (Livermore, CA); Saroyan, Ralph A. (Livermore, CA); Massey, Warren N. (Livermore, CA); Nusshardt, Rudolph (Waltrop, DE)

    1993-01-01T23:59:59.000Z

    A computerized three-dimensional x-ray tomographic microscopy system is disclosed, comprising: a) source means for providing a source of parallel x-ray beams, b) staging means for staging and sequentially rotating a sample to be positioned in the path of the c) x-ray image magnifier means positioned in the path of the beams downstream from the sample, d) detecting means for detecting the beams after being passed through and magnified by the image magnifier means, and e) computing means for analyzing values received from the detecting means, and converting the values into three-dimensional representations. Also disclosed is a process for magnifying an x-ray image, and apparatus therefor.

  12. Note: Dynamic strain field mapping with synchrotron X-ray digital image correlation

    SciTech Connect (OSTI)

    Lu, L. [CAS Key Laboratory of Mechanical Behavior and Design of Materials, Department of Modern Mechanics, University of Science and Technology of China, Hefei, Anhui 230027 (China); The Peac Institute of Multiscale Sciences, Chengdu, Sichuan 610207 (China); Fan, D.; Luo, S. N., E-mail: sluo@pims.ac.cn [The Peac Institute of Multiscale Sciences, Chengdu, Sichuan 610207 (China); Bie, B. X. [The Peac Institute of Multiscale Sciences, Chengdu, Sichuan 610207 (China); School of Science, Wuhan University of Technology, Wuhan, Hubei 430070 (China); Ran, X. X.; Qi, M. L., E-mail: qiml@whut.edu.cn [School of Science, Wuhan University of Technology, Wuhan, Hubei 430070 (China); Parab, N.; Sun, J. Z.; Liao, H. J.; Hudspeth, M. C.; Claus, B. [School of Aeronautics and Astronautics, Purdue University, West Lafayette, Indiana 47907 (United States); Fezzaa, K.; Sun, T. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Chen, W. [School of Aeronautics and Astronautics, Purdue University, West Lafayette, Indiana 47907 (United States); School of Material Science Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); Gong, X. L., E-mail: gongxl@ustc.edu.cn [CAS Key Laboratory of Mechanical Behavior and Design of Materials, Department of Modern Mechanics, University of Science and Technology of China, Hefei, Anhui 230027 (China)

    2014-07-15T23:59:59.000Z

    We present a dynamic strain field mapping method based on synchrotron X-ray digital image correlation (XDIC). Synchrotron X-ray sources are advantageous for imaging with exceptional spatial and temporal resolutions, and X-ray speckles can be produced either from surface roughness or internal inhomogeneities. Combining speckled X-ray imaging with DIC allows one to map strain fields with high resolutions. Based on experiments on void growth in Al and deformation of a granular material during Kolsky bar/gas gun loading at the Advanced Photon Source beamline 32ID, we demonstrate the feasibility of dynamic XDIC. XDIC is particularly useful for dynamic, in-volume, measurements on opaque materials under high strain-rate, large, deformation.

  13. Imaging of lateral spin valves with soft x-ray microscopy

    SciTech Connect (OSTI)

    Mosendz, O.; Mihajlovic, G.; Pearson, J. E.; Fischer, P.; Im, M.-Y.; Bader, S. D.; Hoffmann, A.

    2009-05-01T23:59:59.000Z

    We investigated Co/Cu lateral spin valves by means of high-resolution transmission soft x-ray microscopy with magnetic contrast that utilizes x-ray magnetic circular dichroism (XMCD). No magnetic XMCD contrast was observed at the Cu L{sub 3} absorption edge, which should directly image the spin accumulation in Cu. Although electrical transport measurements in a non-local geometry clearly detected the spin accumulation in Cu, which remained unchanged during illumination with circular polarized x-rays at the Co and Cu L{sub 3} absorption edges.

  14. Imaging of lateral spin valves with soft x-ray microscopy.

    SciTech Connect (OSTI)

    Mosendz, O.; Mihajlovic, G.; Pearson, J. E.; Fischer, P.; Im, M.-Y.; Bader, S. D.; Hoffmann, A.; LBNL

    2009-01-01T23:59:59.000Z

    We investigated Co/Cu lateral spin valves by means of high-resolution transmission soft x-ray microscopy with magnetic contrast that utilizes x-ray magnetic circular dichroism (XMCD). No magnetic XMCD contrast was observed at the Cu L{sub 3} absorption edge, which should directly image the spin accumulation in Cu, although electrical transport measurements in a nonlocal geometry clearly detected the spin accumulation in Cu, which remained unchanged during illumination with circular polarized x rays at the Co and Cu L{sub 3} absorption edges.

  15. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-Ray Imaging ofX-Ray

  16. Image plates as x-ray detectors in plasma physics experiments

    SciTech Connect (OSTI)

    Gales, S.G.; Bentley, C.D. [AWE Aldermaston, Reading RG7 4PR (United Kingdom)

    2004-10-01T23:59:59.000Z

    The performance of image plates based on the photostimulable phosphor BaF(Br,l):Eu{sup 2+} has been investigated and compared with x-ray film. Evaluation of detective quantum efficiency (DQE), sensitivity, dynamic range, and linearity was carried out for several types of commercially available image plate, using the Excalibur soft x-ray calibration facility at AWE. Image plate response was found to be linear over a dynamic range of 5 orders of magnitude. One type of image plate was found to have a number of advantages for soft x-ray detection, with a measured sensitivity 1 order of magnitude greater than that of Kodak Industrex CX and DEF-5 x-ray film. The DQE of this plate was found to be superior to that of film at low [less than 10{sup 3} photons/(50 {mu}m){sup 2}] and high fluxes [greater than 10{sup 4} photons/(50 {mu}m){sup 2}]. The spatial resolution of image plates, scanned with several models of commercial image plate readers, has been evaluated using a USAF resolution test target. The highest spatial resolution measured is 35 {mu}m. Though this is significantly lower than the resolution possible with film, it is sufficient for many applications. Image plates were fielded in a refractive x-ray lens imaging diagnostic on the 1 TW Helen laser and these results are discussed.

  17. X-ray tests of a two-dimensional stigmatic imaging scheme with variable magnifications

    SciTech Connect (OSTI)

    Lu, J., E-mail: jlu@pppl.gov [Key Laboratory of Optoelectronic Technology and System of Ministry of Education, Chongqing University, Chongqing 400030 (China); Bitter, M.; Hill, K. W.; Delgado-Aparicio, L. F.; Efthimion, P. C.; Pablant, N. A. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Beiersdorfer, P. [Physics Division, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Caughey, T. A.; Brunner, J. [Inrad Optics, 181 Legrand Avenue, Northvale, New Jersey 07647 (United States)

    2014-11-15T23:59:59.000Z

    A two-dimensional stigmatic x-ray imaging scheme, consisting of two spherically bent crystals, one concave and one convex, was recently proposed [M. Bitter et al., Rev. Sci. Instrum. 83, 10E527 (2012)]. The Bragg angles and the radii of curvature of the two crystals of this imaging scheme are matched to eliminate the astigmatism and to satisfy the Bragg condition across both crystal surfaces for a given x-ray energy. In this paper, we consider more general configurations of this imaging scheme, which allow us to vary the magnification for a given pair of crystals and x-ray energy. The stigmatic imaging scheme has been validated for the first time by imaging x-rays generated by a micro-focus x-ray source with source size of 8.4 ?m validated by knife-edge measurements. Results are presented from imaging the tungsten L?1 emission at 8.3976 keV, using a convex Si-422 crystal and a concave Si-533 crystal with 2d-spacings of 2.21707 Å and 1.65635 Å and radii of curvature of 500 ± 1 mm and 823 ± 1 mm, respectively, showing a spatial resolution of 54.9 ?m. This imaging scheme is expected to be of interest for the two-dimensional imaging of laser produced plasmas.

  18. The Coherent X-ray Imaging instrument at the Linac Coherent Light Source

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liang, Mengning; Williams, Garth J.; Messerschmidt, Marc; Seibert, M. Marvin; Montanez, Paul A.; Hayes, Matt; Milathianaki, Despina; Aquila, Andrew; Hunter, Mark S.; Koglin, Jason E.; et al

    2015-05-01T23:59:59.000Z

    The Coherent X-ray Imaging (CXI) instrument specializes in hard X-ray, in-vacuum, high power density experiments in all areas of science. Two main sample chambers, one containing a 100 nm focus and one a 1 µm focus, are available, each with multiple diagnostics, sample injection, pump–probe and detector capabilities. The flexibility of CXI has enabled it to host a diverse range of experiments, from biological to extreme matter.

  19. SCANNING ELECTRON MICROSCOPY AND X-RAY DIFFRACTION ANALYSIS OF TANK 18 SAMPLES

    SciTech Connect (OSTI)

    Hay, M.; O'Rourke, P.; Ajo, H.

    2012-03-08T23:59:59.000Z

    The F-Area Tank Farm (FTF) Performance Assessment (PA) utilizes waste speciation in the waste release model used in the FTF fate and transport modeling. The waste release modeling associated with the residual plutonium in Tank 18 has been identified as a primary contributor to the Tank 18 dose uncertainty. In order to reduce the uncertainty related to plutonium in Tank 18, a better understanding of the plutonium speciation in the Tank 18 waste (including the oxidation state and stoichiometry) is desired. Savannah River National Laboratory (SRNL) utilized Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD) to analyze Tank 18 samples to provide information on the speciation of plutonium in the waste material. XRD analysis of the Tank 18 samples did not identify any plutonium mineral phases in the samples. These indicates the crystalline mineral phases of plutonium are below the detection limits of the XRD method or that the plutonium phase(s) lack long range order and are present as amorphous or microcrystalline solids. SEM analysis of the Tank 18 samples did locate particles containing plutonium. The plutonium was found as small particles, usually <1 {micro}m but ranging up to several micrometers in diameter, associated with particles of an iron matrix and at low concentration in other elemental matrices. This suggests the plutonium has an affinity for the iron matrix. Qualitatively, the particles of plutonium found in the SEM analysis do not appear to account for all of the plutonium in the sample based on concentrations determined from the chemical analysis of the Tank 18 samples. This suggests that plutonium is also distributed throughout the solids in low concentrations.

  20. Investigating high speed phenomena in laser plasma interactions using dilation x-ray imager (invited)

    SciTech Connect (OSTI)

    Nagel, S. R., E-mail: nagel7@llnl.gov; Bell, P. M.; Bradley, D. K.; Ayers, M. J.; Piston, K.; Felker, B. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Hilsabeck, T. J.; Kilkenny, J. D.; Chung, T.; Sammuli, B. [General Atomics, P.O. Box 85608, San Diego, California 92186-5608 (United States); Hares, J. D.; Dymoke-Bradshaw, A. K. L. [Kentech Instruments Ltd., Wallingford, Oxfordshire OX10 (United Kingdom)

    2014-11-15T23:59:59.000Z

    The DIlation X-ray Imager (DIXI) is a new, high-speed x-ray framing camera at the National Ignition Facility (NIF) sensitive to x-rays in the range of ?2–17 keV. DIXI uses the pulse-dilation technique to achieve a temporal resolution of less than 10 ps, a ?10× improvement over conventional framing cameras currently employed on the NIF (?100 ps resolution), and otherwise only attainable with 1D streaked imaging. The pulse-dilation technique utilizes a voltage ramp to impart a velocity gradient on the signal-bearing electrons. The temporal response, spatial resolution, and x-ray sensitivity of DIXI are characterized with a short x-ray impulse generated using the COMET laser facility at Lawrence Livermore National Laboratory. At the NIF a pinhole array at 10 cm from target chamber center (tcc) projects images onto the photocathode situated outside the NIF chamber wall with a magnification of ?64×. DIXI will provide important capabilities for warm-dense-matter physics, high-energy-density science, and inertial confinement fusion, adding important capabilities to temporally resolve hot-spot formation, x-ray emission, fuel motion, and mix levels in the hot-spot at neutron yields of up to 10{sup 17}. We present characterization data as well as first results on electron-transport phenomena in buried-layer foil experiments.

  1. Rietveld X-ray diffraction analysis of nanostructured rutile films of titania prepared by pulsed laser deposition

    SciTech Connect (OSTI)

    Murugesan, S. [Physical Metallurgy Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu (India)] [Physical Metallurgy Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu (India); Kuppusami, P., E-mail: pk@igcar.gov.in [Physical Metallurgy Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu (India); Mohandas, E. [Physical Metallurgy Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu (India)] [Physical Metallurgy Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu (India)

    2010-01-15T23:59:59.000Z

    Rietveld powder X-ray diffraction analysis of the rutile films of titanium oxide prepared by pulsed laser deposition was carried out. The crystallite size increased with increase of substrate temperature, while the strain showed a reverse trend. The films synthesized at temperature {>=}573 K showed that the crystal structure was almost close to that of bulk rutile structure. The influence of the substrate temperature on the lattice parameters and oxygen coordinates were also studied in the present work.

  2. anomalous x-ray diffraction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the soft X-rays emitted by the neutron-star surface. The relation between these heating rates and measured near-infrared fluxes in the K and Ks bands places severe...

  3. X-ray Diffraction Laboratory: Department of Chemistry Texas A & M University

    E-Print Network [OSTI]

    Meagher, Mary

    and the data containing computers will not be connected by wired or wireless internet networks to the Word Wide Web. RESPONSIBILITY: The X-ray Laboratory personell will be responsible for security issues. MATERIALS

  4. Characterization of montmorillonite doped PVA/SA blends using X-ray diffraction

    SciTech Connect (OSTI)

    Hemalatha, K.; Somashekarappa, H. [Department of Physics, Yuvaraja's College, University of Mysore, Manasagangotri, Mysore-570005 (India); Mahadevaiah,; Somashekar, R., E-mail: rs@physics.uni-mysore.ac.in [Department of Studies in Physics, University of Mysore, Manasagangotri, Mysore-570006 (India)

    2014-04-24T23:59:59.000Z

    PVA films doped with Montmorillonite was prepared by slow evaporation technique. These films have been used to record X-ray patterns at room temperature. Correlation lengths and microstructural parameters were computed using in-house program employing X-ray data. Results show that correlation lengths as well as crystallite size increases with increase in the concentration of Montmorillonite which is inconformity with the conductivity studies.

  5. High-throughput imaging of heterogeneous cell organelles with an X-ray laser

    SciTech Connect (OSTI)

    Hantke, Max, F.

    2014-11-17T23:59:59.000Z

    Preprocessed detector images that were used for the paper "High-throughput imaging of heterogeneous cell organelles with an X-ray laser". The CXI file contains the entire recorded data - including both hits and blanks. It also includes down-sampled images and LCLS machine parameters. Additionally, the Cheetah configuration file is attached that was used to create the pre-processed data.

  6. High-throughput imaging of heterogeneous cell organelles with an X-ray laser

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hantke, Max, F.

    Preprocessed detector images that were used for the paper "High-throughput imaging of heterogeneous cell organelles with an X-ray laser". The CXI file contains the entire recorded data - including both hits and blanks. It also includes down-sampled images and LCLS machine parameters. Additionally, the Cheetah configuration file is attached that was used to create the pre-processed data.

  7. Integration of a broad beam ion source with a high-temperature x-ray diffraction vacuum chamber

    SciTech Connect (OSTI)

    Manova, D.; Bergmann, A.; Maendl, S.; Neumann, H.; Rauschenbach, B. [Leibniz-Institut fuer Oberflaechenmodifizierung e. V., Permoserstr. 15, 04318 Leipzig (Germany)

    2012-11-15T23:59:59.000Z

    Here, the integration of a low energy, linearly variable ion beam current density, mechanically in situ adjustable broad beam ion source with a high-temperature x-ray diffraction (XRD) vacuum chamber is reported. This allows in situ XRD investigation of phase formation and evolution processes induced by low energy ion implantation. Special care has been taken to an independent adjustment of the ion beam for geometrical directing towards the substrate, a 15 mm small ion source exit aperture to avoid a secondary sputter process of the chamber walls, linearly variable ion current density by using a pulse length modulation (PLM) for the accelerating voltages without changing the ion beam density profile, nearly homogeneous ion beam distribution over the x-ray footprint, together with easily replaceable Kapton{sup Registered-Sign} windows for x-rays entry and exit. By combining a position sensitive x-ray detector with this PLM-modulated ion beam, a fast and efficient time resolved investigation of low energy implantation processes is obtained in a compact experimental setup.

  8. Single-particle structure determination by correlations of snapshot X-ray diffraction patterns (CXIDB ID 20)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Starodub, D.

    This deposition includes the diffraction images generated by the paired polystyrene spheres in random orientations. These images were used to determine and phase the single particle diffraction volume from their autocorrelation functions.

  9. X-ray photon-in/photon-out methods for chemical imaging

    SciTech Connect (OSTI)

    Marcus, Matthew A.

    2010-03-24T23:59:59.000Z

    Most interesting materials in nature are heterogeneous, so it is useful to have analytical techniques with spatial resolution sufficient to resolve these heterogeneities.This article presents the basics of X-ray photon-in/photon-out chemical imaging. This family of methods allows one to derive images reflectingthe chemical state of a given element in a complex sample, at micron or deep sub-micron scale. X-ray chemical imaging is relatively non-destructiveand element-selective, and requires minimal sample preparation. The article presents the basic concepts and some considerations of data takingand data analysis, along with some examples.

  10. Mirrors for X-ray telescopes: Fresnel diffraction-based computation of Point Spread Functions from metrology

    E-Print Network [OSTI]

    Raimondi, Lorenzo

    2014-01-01T23:59:59.000Z

    The imaging sharpness of an X-ray telescope is chiefly determined by the optical quality of its focusing optics, which in turn mostly depends on the shape accuracy and the surface finishing of the grazing incidence X-ray mirrors that compose the optical modules. In order to ensure the imaging performance during the mirror manufacturing, a fundamental step is represented by the prediction of the mirror Point Spread Function (PSF) from the metrology of its surface. Traditionally, the PSF computation in X-rays is assumed to be different depending on whether the surface defects are classified as figure errors or roughness [...] The aim of this work is to overcome this limit, providing analytical formulae, valid at any light wavelength, to compute the PSF of an X-ray mirror shell from the measured longitudinal profiles and the roughness Power Spectral Density (PSD), without distinguishing spectral ranges with different treatments. The method we adopted is based on the Huygens-Fresnel principle to compute the diffr...

  11. PERTURBATION-BASED ERROR ANALYSIS OF ITERATIVE IMAGE RECONSTRUCTION ALGORITHM FOR X-RAY COMPUTED TOMOGRAPHY

    E-Print Network [OSTI]

    Fessler, Jeffrey A.

    -ray computed tomography. The effects of the quantization error in forward-projection, back computed tomography (CT) have been proposed to improve image quality and reduce dose [1]. These methodsPERTURBATION-BASED ERROR ANALYSIS OF ITERATIVE IMAGE RECONSTRUCTION ALGORITHM FOR X-RAY COMPUTED

  12. Optimization of X-ray Radiographic Imaging Birsen Yazici, Il-Young Son, An Jin

    E-Print Network [OSTI]

    Yazici, Birsen

    while minimizing the patient dose. Digital phantoms are generated using the virtual photographic Synopsis This chapter presents x-ray image quality optimization techniques using digital phantom images quality analysis. Absorbed doses in organs and tissues of the segmented VIP-Man phantom are obtained from

  13. Formation of delta ferrite in 9 wt.% Cr steel investigated by in-situ X-ray diffraction using synchrotron radiation

    E-Print Network [OSTI]

    Mayr, P.

    In-situ X-ray diffraction (XRD) measurements using high energy synchrotron radiation were performed to monitor in real time the formation of delta ferrite in a martensitic 9 wt pct chromium steel under simulated weld thermal ...

  14. Investigation of the spontaneous lateral modulation in short-period superlattices by grazing-incidence x-ray diffraction.

    SciTech Connect (OSTI)

    Moss, Simon C. (University of Houston, Houston, TX); Holy, Vaclav (Charles University, Prague, Czech Republic); Reno, John Louis; Krause, B. (ESRF, Grenoble, France); Norman, Andrew G. (National Renewable Energy Laboratory, Golden, CO); Mikulik, P. (Masaryk University, Brno, Czech Republic); Caha, O. (Masaryk University, Brno, Czech Republic); Mascarenhas, Angelo (National Renewable Energy Laboratory, Golden, CO)

    2005-03-01T23:59:59.000Z

    The process of spontaneous lateral composition modulation in short-period InAs/AlAs superlattices has been investigated by grazing-incidence x-ray diffraction. We have developed a theoretical description of x-ray scattering from laterally modulated structures that makes it possible to determine the lateral composition modulation directly without assuming any structure model. From experimental intensity distributions in reciprocal space we have determined the amplitudes of the modulation and its degree of periodicity and their dependence on the number of superlattice periods. From the data it follows that the modulation process cannot be explained by bunching of monolayer steps and most likely, it is caused by stress-driven morphological instabilities of the growing surface.

  15. Structures and transitions in solid O/sub 2/ to 13 GPa at 298 K by x-ray diffraction

    SciTech Connect (OSTI)

    Olinger, B.; Mills, R.L.; Roof R.B. Jr.

    1984-12-01T23:59:59.000Z

    The structures and phase transitions in solid O/sub 2/ were studied at 298 K from 6 to 13 GPa using powder x-ray diffraction in an anvil cell. Pressures were determined from the compression of in situ NaF. X-ray photographs at various pressures showed patterns from five different phases of O/sub 2/, two of which were previously unreported. Values of the bulk modulus and volume were derived up to 11 GPa where transition to epsilon-O/sub 2/ occurs. A compromise fit to all available data indicates that epsilon-O/sub 2/ may be an orthorhombic distortion of delta-O/sub 2/.

  16. X-ray diffraction, spectroscopic and DFT studies of 1-(4-bromophenyl)-3,5-diphenylformazan

    SciTech Connect (OSTI)

    Tezcan, H., E-mail: habibe@gazi.edu.tr [Gazi University, Department of Chemistry, Faculty of Education (Turkey); Tokay, N. [Hacettepe University, Department of Chemistry, Faculty of Science (Turkey); Alpaslan, G. [Giresun University, Department of Medical Services and Techniques, Vocational School of Health Services (Turkey); Erdönmez, A. [Ondokuz May?s University, Department of Physics, Faculty of Science and Art (Turkey)

    2013-12-15T23:59:59.000Z

    The crystal structure of 1-(4-bromophenyl)-3,5-diphenylformazan was determined by X-ray single crystal diffraction technique. The crystals are orthorhombic, a = 23.0788(9), b = 7.9606(3), c = 18.6340(12) Å, Z = 8, sp. gr. Pbca, R{sub 1} = 0.074. The structure was also examined using the density-functional theory. Its structure stability, and frontier molecular orbital components were discussed and the results were compared with X-ray and spectral results. The maximum absorbtion peaks of the UV-vis spectrum of the compound have been calculated using the time-dependent density-functional theory. It was found a good agreement between the calculated and experimental maximum absorption wavelength.

  17. Ultrafast X-ray Diffraction Theory Jianshu Cao* and Kent R. Wilson

    E-Print Network [OSTI]

    Cao, Jianshu

    notablely using ultrafast optical pump-probe pulses. Unfortunately, except for a few favorable cases of a sample is initiated by an ultrafast optical laser pulse and then probed by an ultrafast X-ray pulse initiated by the optical pump pulse in real time and real space.9-11 From a simple viewpoint, ultrafast X

  18. Diffraction line-profile shape by synchrotron and laboratory x-ray sources* Davor Balzar `Jo,Peter W. Stephens 2,and Hassel Ledbetter 1

    E-Print Network [OSTI]

    Balzar, Davor

    Diffraction line-profile shape by synchrotron and laboratory x-ray sources* Davor Balzar `Jo-line profiles obtained at the X3Bl NSLS powder-diffraction beamline and with a standard CuKa,,, sealed source) divergence but also on the character of diffraction-line profiles at high angles. A theoretical expression

  19. To the Graduate Council: I am submitting herewith a thesis written by Yue Zheng entitled "X-Ray Image

    E-Print Network [OSTI]

    Abidi, Mongi A.

    -ray imaging for airport luggage inspection and the characteristics of single-energy and dual-energy x-ray data single energy and dual energy x-ray images, are then presented in four categories: (1) gray based color-coding approaches and dual-energy image fusion algorithms --spatial information- based

  20. Demonstration of x-ray fluorescence imaging of a high-energy-density plasma

    SciTech Connect (OSTI)

    MacDonald, M. J., E-mail: macdonm@umich.edu; Gamboa, E. J. [Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor, Michigan 48109 (United States); SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Keiter, P. A.; Fein, J. R.; Klein, S. R.; Kuranz, C. C.; LeFevre, H. J.; Manuel, M. J.-E.; Wan, W. C.; Drake, R. P. [Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor, Michigan 48109 (United States); Montgomery, D. S. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Biener, M. M.; Fournier, K. B. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Streit, J. [Schafer Corporation, Livermore, California 94551 (United States)

    2014-11-15T23:59:59.000Z

    Experiments at the Trident Laser Facility have successfully demonstrated the use of x-ray fluorescence imaging (XRFI) to diagnose shocked carbonized resorcinol formaldehyde (CRF) foams doped with Ti. One laser beam created a shock wave in the doped foam. A second laser beam produced a flux of vanadium He-? x-rays, which in turn induced Ti K-shell fluorescence within the foam. Spectrally resolved 1D imaging of the x-ray fluorescence provided shock location and compression measurements. Additionally, experiments using a collimator demonstrated that one can probe specific regions within a target. These results show that XRFI is a capable alternative to path-integrated measurements for diagnosing hydrodynamic experiments at high energy density.

  1. High resolution x-ray lensless imaging by differential holographic encoding

    SciTech Connect (OSTI)

    Zhu, D.; Guizar-Sicairos, M.; Wu, B.; Scherz, A.; Acremann, Y.; Tylisczcak, T.; Fischer, P.; Friedenberger, N.; Ollefs, K.; Farle, M.; Fienup, J. R.; Stohr, J.

    2009-11-02T23:59:59.000Z

    X-ray free electron lasers (X-FEL{sub s}) will soon offer femtosecond pulses of laterally coherent x-rays with sufficient intensity to record single-shot coherent scattering patterns for nanoscale imaging. Pulse trains created by splitand-delay techniques even open the door for cinematography on unprecedented nanometer length and femtosecond time scales. A key to real space ultrafast motion pictures is fast and reliable inversion of the recorded reciprocal space scattering patterns. Here we for the first time demonstrate in the x-ray regime the power of a novel technique for lensless high resolution imaging, previously suggested by Guizar-Sicairos and Fienup termed holography with extended reference by autocorrelation linear differential operation, HERALD0. We have achieved superior resolution over conventional x-ray Fourier transform holography (FTH) without sacrifices in SNR or significant increase in algorithmic complexity. By combining images obtained from individual sharp features on an extended reference, we further show that the resolution can be even extended beyond the reference fabrication limits. Direct comparison to iterative phase retrieval image reconstruction and images recorded with stateof- the-art zone plate microscopes is presented. Our results demonstrate the power of HERALDO as a favorable candidate for robust inversion of single-shot coherent scattering patterns.

  2. Performance of CID camera X-ray imagers at NIF in a harsh neutron environment

    SciTech Connect (OSTI)

    Palmer, N. E. [LLNL; Schneider, M. B. [LLNL; Bell, P. M. [LLNL; Piston, K. W. [LLNL; Moody, J. D. [LLNL; James, D. L. [LLNL; Ness, R. A. [LLNL; Haugh, M. J. [NSTec; Lee, J. J. [NSTec; Romano, E. D. [NSTec

    2013-09-01T23:59:59.000Z

    Charge-injection devices (CIDs) are solid-state 2D imaging sensors similar to CCDs, but their distinct architecture makes CIDs more resistant to ionizing radiation.1–3 CID cameras have been used extensively for X-ray imaging at the OMEGA Laser Facility4,5 with neutron fluences at the sensor approaching 109 n/cm2 (DT, 14 MeV). A CID Camera X-ray Imager (CCXI) system has been designed and implemented at NIF that can be used as a rad-hard electronic-readout alternative for time-integrated X-ray imaging. This paper describes the design and implementation of the system, calibration of the sensor for X-rays in the 3 – 14 keV energy range, and preliminary data acquired on NIF shots over a range of neutron yields. The upper limit of neutron fluence at which CCXI can acquire useable images is ~ 108 n/cm2 and there are noise problems that need further improvement, but the sensor has proven to be very robust in surviving high yield shots (~ 1014 DT neutrons) with minimal damage.

  3. In-situ stoichiometry determination using x-ray fluorescence generated by reflection-high-energy-electron-diffraction

    SciTech Connect (OSTI)

    Keenan, Cameron; Chandril, Sandeep; Lederman, David [Department of Physics and Multifunctional Materials Laboratory, West Virginia University, Morgantown, West Virginia 26506 (United States); Myers, T. H. [Department of Physics and Multifunctional Materials Laboratory, West Virginia University, Morgantown, West Virginia 26506 (United States); Materials Science, Engineering, and Commercialization Program, Texas State University-San Marcos, San Marcos, Texas 78666 (United States)

    2011-06-01T23:59:59.000Z

    A major challenge in the stoichiometric growth of complex oxide compounds is the control of the relative compositions of the constituent materials. A potential avenue for compositional analysis during growth is the use of x-ray fluorescence generated during reflection high energy electron diffraction measurements. Using this technique, relative compositions of Y and Mn in molecular beam epitaxy grown YMnO{sub 3} samples were studied. Comparing the results with Rutherford back scattering spectroscopy suggests that the technique has the potential for real-time analysis of elemental fluxes and stoichiometry control during sample growth.

  4. Variable growth modes of CaF[sub 2] on Si(111) determined by x-ray photoelectron diffraction

    SciTech Connect (OSTI)

    Denlinger, J.D.; Rotenberg, E. (Department of Physics, University of California, Berkeley, California 94720 (United States) Materials Sciences Division, Lawrence Berkeley Laboratory, Berkeley, California 94720 (United States)); Hessinger, U.; Leskovar, M. (Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States)); Olmstead, M.A. (Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States) Materials Sciences Division, Lawrence Berkeley Laboratory, Berkeley, California 94720 (United States))

    1993-04-26T23:59:59.000Z

    Chemical discrimination of bulk and interface Ca 2[ital p] x-ray photoelectron diffraction modulations is used to identify three growth regimes during the initial stages of CaF[sub 2] epitaxy on Si(111). Low flux, high temperature conditions produce island growth atop a nonwetting, chemically reacted Ca-F interface layer. Changing the growth kinetics by increasing the flux produces more laminar growth. Lowering the substrate temperature produces a more stoichiometric CaF[sub 2] interface layer that results in immediate wetting and laminar growth.

  5. Installation of soft X-ray array diagnostics and its application to tomography reconstruction using synthetic KSTAR X-ray images

    SciTech Connect (OSTI)

    Lee, Seung Hun; Jang, Juhyeok; Hong, Joohwan; Jang, Siwon; Choe, Wonho, E-mail: wchoe@kaist.ac.kr [Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of); Impurity and Edge Research Center, Daejeon 305-701 (Korea, Republic of); Pacella, D.; Romano, A.; Gabellieri, L. [Associazione Euratom-ENEA sulla Fusione, C.R. Frascati 00044 (Italy); Kim, Junghee [National Fusion Research Institute, Daejeon 305-806 (Korea, Republic of); Major of Nuclear Fusion and Plasma Science Department, Korea University of Science and Technology, Daejeon 305-350 (Korea, Republic of)

    2014-11-15T23:59:59.000Z

    Four-array system of soft X-ray diagnostics was installed on KSTAR tokamak. Each array has 32 viewing chords of two photo-diode array detectors with spatial resolution of 2 cm. To estimate signals from the soft X-ray radiation power, typical n{sub e}, T{sub e}, and argon impurity line radiation profiles in KSTAR are chosen. The photo-diodes were absolutely calibrated as a function of the incident photon energy in 2–40 keV range with a portable X-ray tube. Two-dimensional T{sub e} image properties by multi-energy method were simulated and visualized with six combinations of beryllium filter sets within the dynamic range of signal ratio.

  6. Wavelength calibration of x-ray imaging crystal spectrometer on Joint Texas Experimental Tokamak

    SciTech Connect (OSTI)

    Yan, W.; Chen, Z. Y., E-mail: zychen@hust.edu.cn; Jin, W.; Huang, D. W.; Ding, Y. H.; Li, J. C.; Zhang, X. Q.; Zhuang, G. [School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan (China); Lee, S. G.; Shi, Y. J. [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of)

    2014-11-15T23:59:59.000Z

    The wavelength calibration of x-ray imaging crystal spectrometer is a key issue for the measurements of plasma rotation. For the lack of available standard radiation source near 3.95 Å and there is no other diagnostics to measure the core rotation for inter-calibration, an indirect method by using tokamak plasma itself has been applied on joint Texas experimental tokamak. It is found that the core toroidal rotation velocity is not zero during locked mode phase. This is consistent with the observation of small oscillations on soft x-ray signals and electron cyclotron emission during locked-mode phase.

  7. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-Ray Imaging of the

  8. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-Ray Imaging of

  9. 3D Reconstruction of the Femoral Bone using two X-ray Images from Orthogonal Views

    E-Print Network [OSTI]

    3D Reconstruction of the Femoral Bone using two X-ray Images from Orthogonal Views B. Nikkhahe of the femur and 97 % of the model femur shaft less than 2 mm from the CT scan. Also the femoral head visualization of the femur including the femoral collumn and condyles is important for the clinician in a number

  10. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D. Sayre (Stony Brook University); P. Thibault and V. Elser (Cornell University); T. Beetz and C. Jacobsen (Stony Brook University and Brookhaven National Laboratory); M....

  11. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find Find More LikeAndreasHelp Table ofBiological

  12. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find Find More LikeAndreasHelp Table

  13. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find Find More LikeAndreasHelp TableBiological

  14. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find Find More LikeAndreasHelp TableBiologicalBiological

  15. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplexMaterialProduction PetraBiologicalBiological

  16. Biological Imaging by Soft X-Ray Diffraction Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplexMaterialProduction

  17. X-ray absorption spectroscopy by full-field X-ray microscopy of a thin graphite flake: Imaging and

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    .bittencourt@ua.ac.be * Corresponding author Keywords: carbon; graphene; nanostructure; NEXAFS; X-ray microscopy Beilstein J structure of graphite flakes consisting of a few graphene layers. The flake was produced by exfoli- ation of the remarkable transport properties of graphene in 2004 by Geim and Novoselov triggered intense interest in its

  18. Reconstruction of a yeast cell from X-ray diffraction data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thibault, Pierre; Elser, Veit; Jacobsen, Chris; Shapiro, David; Sayre, David

    2006-06-21T23:59:59.000Z

    Details are provided of the algorithm used for the reconstruction of yeast cell images in the recent demonstration of diffraction microscopy by Shapiro, Thibault, Beetz, Elser, Howells, Jacobsen, Kirz, Lima, Miao, Nieman & Sayre [Proc. Natl Acad. Sci. USA (2005), 102, 15343-15346]. Two refinements of the iterative constraint-based scheme are developed to address the current experimental realities of this imaging technique, which include missing central data and noise. A constrained power operator is defined whose eigenmodes allow the identification of a small number of degrees of freedom in the reconstruction that are negligibly constrained as a result of the missing data. To achieve reproducibility in the algorithm's output, a special intervention is required for these modes. Weak incompatibility of the constraints caused by noise in both direct and Fourier space leads to residual phase fluctuations. This problem is addressed by supplementing the algorithm with an averaging method. The effect of averaging may be interpreted in terms of an effective modulation transfer function, as used in optics, to quantify the resolution. The reconstruction details are prefaced with simulations of wave propagation through a model yeast cell. These show that the yeast cell is a strong-phase-contrast object for the conditions in the experiment.

  19. Reconstruction of a yeast cell from X-ray diffraction data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thibault, Pierre; Elser, Veit; Jacobsen, Chris; Shapiro, David; Sayre, David

    2006-06-21T23:59:59.000Z

    Details are provided of the algorithm used for the reconstruction of yeast cell images in the recent demonstration of diffraction microscopy by Shapiro, Thibault, Beetz, Elser, Howells, Jacobsen, Kirz, Lima, Miao, Nieman & Sayre [Proc. Natl Acad. Sci. USA (2005), 102, 15343-15346]. Two refinements of the iterative constraint-based scheme are developed to address the current experimental realities of this imaging technique, which include missing central data and noise. A constrained power operator is defined whose eigenmodes allow the identification of a small number of degrees of freedom in the reconstruction that are negligibly constrained as a result of the missingmore »data. To achieve reproducibility in the algorithm's output, a special intervention is required for these modes. Weak incompatibility of the constraints caused by noise in both direct and Fourier space leads to residual phase fluctuations. This problem is addressed by supplementing the algorithm with an averaging method. The effect of averaging may be interpreted in terms of an effective modulation transfer function, as used in optics, to quantify the resolution. The reconstruction details are prefaced with simulations of wave propagation through a model yeast cell. These show that the yeast cell is a strong-phase-contrast object for the conditions in the experiment.« less

  20. The use of X-ray diffraction, microscopy, and magnetic measurements for analysing microstructural features of a duplex stainless steel

    SciTech Connect (OSTI)

    Ribeiro Miranda, M.A. [Instituto de Fisica, Universidade Federal do Ceara, Campus do Pici, Caixa Postal 6030, CEP 60455-760 Fortaleza/CE (Brazil)]. E-mail: marcus@fisica.ufc.br; Sasaki, J.M. [Instituto de Fisica, Universidade Federal do Ceara, Campus do Pici, Caixa Postal 6030, CEP 60455-760 Fortaleza/CE (Brazil); Tavares, S.S.M. [PGMEC/TEM, Universidade Federal Fluminense, Rua Passo da Patria, 156, CEP 24210-240, Niteroi/RJ (Brazil); de Abreu, H.F.G. [Depto. Engenharia Meca-hat nica, Universidade Federal do Ceara (Brazil); Neto, J.M. [Instituto de Fisica, Universidade Federal do Rio de Janeiro (Brazil)

    2005-05-15T23:59:59.000Z

    X-ray diffraction, light optical microscopy, and magnetization saturation measurements were employed to analyse the microstructural features of a UNS S31803 duplex stainless steel modified by high-temperature treatments. The samples were heated to 1300 deg. C and cooled by different ways to produce five different microstructures. Solution treatments at 1000 deg. C were also employed to produce another five conditions. Three methods were employed to determine the austenite/ferrite proportions. X-ray diffraction gave higher austenite values than the other methods, due to the influence of texture, but can be successfully used to determine the microstrain level in each phase. Magnetic saturation measurement is a very simple and precise method for quantification of austenite and ferrite volume fractions in samples that were fast-cooled and slow-cooled. Light microscopy can give a fast and precise measurement of the phase proportions and reveals important features related to the morphology of the phases, but in the samples where the austenite content is low, quantification becomes difficult and imprecise.

  1. LOW TEMPERATURE X-RAY DIFFRACTION STUDIES OF NATURAL GAS HYDRATE SAMPLES FROM THE GULF OF MEXICO

    SciTech Connect (OSTI)

    Rawn, Claudia J [ORNL; Sassen, Roger [Texas A& M University; Ulrich, Shannon M [ORNL; Phelps, Tommy Joe [ORNL; Chakoumakos, Bryan C [ORNL; Payzant, E Andrew [ORNL

    2008-01-01T23:59:59.000Z

    Clathrate hydrates of methane and other small alkanes occur widespread terrestrially in marine sediments of the continental margins and in permafrost sediments of the arctic. Quantitative study of natural clathrate hydrates is hampered by the difficulty in obtaining pristine samples, particularly from submarine environments. Bringing samples of clathrate hydrate from the seafloor at depths without compromising their integrity is not trivial. Most physical property measurements are based on studies of laboratory-synthesized samples. Here we report X-ray powder diffraction measurements of a natural gas hydrate sample from the Green Canyon, Gulf of Mexico. The first data were collected in 2002 and revealed ice and structure II gas hydrate. In the subsequent time the sample has been stored in liquid nitrogen. More recent X-ray powder diffraction data have been collected as functions of temperature and time. This new data indicates that the larger sample is heterogeneous in ice content and shows that the amount of sII hydrate decreases with increasing temperature and time as expected. However, the dissociation rate is higher at lower temperatures and earlier in the experiment.

  2. A 31?T split-pair pulsed magnet for single crystal x-ray diffraction at low temperature

    SciTech Connect (OSTI)

    Duc, F.; Frings, P.; Nardone, M.; Billette, J.; Zitouni, A.; Delescluse, P.; Béard, J.; Nicolin, J. P.; Rikken, G. L. J. A. [Laboratoire National des Champs Magnétiques Intenses, CNRS-INSA-UJF-UPS, 143, avenue de Rangueil, F-31400 Toulouse (France); Fabrèges, X. [Laboratoire National des Champs Magnétiques Intenses, CNRS-INSA-UJF-UPS, 143, avenue de Rangueil, F-31400 Toulouse (France); Laboratoire Léon Brillouin, UMR12 CEA-CNRS Bât 563 CEA Saclay, 91191 Gif sur Yvette Cedex (France); Roth, T. [European Synchrotron Radiation Facility, Boîte Postale 220, F-38043 Grenoble Cedex (France); European XFEL GmbH, Albert-Einstein-Ring 19, D-22761 Hamburg (Germany); Detlefs, C.; Lesourd, M.; Zhang, L. [European Synchrotron Radiation Facility, Boîte Postale 220, F-38043 Grenoble Cedex (France)

    2014-05-15T23:59:59.000Z

    We have developed a pulsed magnet system with panoramic access for synchrotron x-ray diffraction in magnetic fields up to 31?T and at low temperature down to 1.5?K. The apparatus consists of a split-pair magnet, a liquid nitrogen bath to cool the pulsed coil, and a helium cryostat allowing sample temperatures from 1.5 up to 250?K. Using a 1.15?MJ mobile generator, magnetic field pulses of 60?ms length were generated in the magnet, with a rise time of 16.5?ms and a repetition rate of 2 pulses/h at 31?T. The setup was validated for single crystal diffraction on the ESRF beamline ID06.

  3. Performance of a static-anode/flat-panel x-ray fluoroscopy system in a diagnostic strength magnetic field: A truly hybrid x-ray/MR imaging system

    SciTech Connect (OSTI)

    Fahrig, R.; Wen, Z.; Ganguly, A.; DeCrescenzo, G.; Rowlands, J.A.; Stevens, G.M.; Saunders, R.F.; Pelc, N.J. [Department of Radiology, Stanford University, Stanford, California 94305 (United States); Department of Radiology and Department of Physics, Stanford University, Stanford, California 94305 (United States); Department of Radiology, Stanford University, Stanford, California 94305 (United States); Sunnybrook and Women's Health Sciences Center and Medical Biophysics, University of Toronto, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5 (Canada); GE Healthcare, Schenectady, Wisconsin (United States); Department of Radiology, Stanford University, Stanford, California 94305 (United States)

    2005-06-15T23:59:59.000Z

    Minimally invasive procedures are increasing in variety and frequency, facilitated by advances in imaging technology. Our hybrid imaging system (GE Apollo{sup TM} flat panel, custom Brand x-ray static anode x-ray tube, GE Lunar high-frequency power supply and 0.5 T Signa SP{sup TM}) provides both x-ray and MR imaging capability to guide complex procedures without requiring motion of the patient between two distant gantries. The performance of the x-ray tube in this closely integrated system was evaluated by modeling and measuring both the response of the filament to an externally applied field and the behavior of the electron beam for field strengths and geometries of interest. The performance of the detector was assessed by measuring the slanted-edge modulation transfer function (MTF) and when placed at zero field and at 0.5 T. Measured resonant frequencies of filaments can be approximated using a modified vibrating beam model, and were at frequencies well below the 25 kHz frequency of our generator for our filament geometry. The amplitude of vibration was not sufficient to cause shorting of the filament during operation within the magnetic field. A simple model of electrons in uniform electric and magnetic fields can be used to estimate the deflection of the electron beam on the anode for the fields of interest between 0.2 and 0.5 T. The MTF measured at the detector and the DQE showed no significant difference inside and outside of the magnetic field. With the proper modifications, an x-ray system can be fully integrated with a MR system, with minimal loss of image quality. Any x-ray tube can be assessed for compatibility when placed at a particular location within the field using the models. We have also concluded that a-Si electronics are robust against magnetic fields. Detailed knowledge of the x-ray system installation is required to provide estimates of system operation.

  4. Proceedings of the workshop on X-ray computed microtomography

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    This report consists of vugraphs from the nine presentations at the conference. Titles of the presentations are: CMT: Applications and Techniques; Computer Microtomography Using X-rays from Third Generation Synchrotron X-ray; Approaches to Soft-X-ray Nanotomography; Diffraction Enhanced Tomography; X-ray Computed Microtomography Applications at the NSLS; XCMT Applications in Forestry and Forest Products; 3DMA: Investigating Three Dimensional Pore Geometry from High Resolution Images; X-ray Computed Microtomography Studies of Volcanic Rock; and 3-D Visualization of Tomographic Volumes.

  5. Oxygen diffusivity in silicon derived from dynamical X-ray diffraction

    SciTech Connect (OSTI)

    Will, J.; Groeschel, A.; Bergmann, C.; Steinrueck, H.-G.; Magerl, A. [Crystallography and Structural Physics, University of Erlangen-Nuernberg, Staudtstr. 3, 91058 Erlangen (Germany); Kot, D.; Schubert, M. A.; Kissinger, G. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany)

    2013-02-21T23:59:59.000Z

    Thickness dependent Pendelloesung oscillations are highly sensitive to strain fields from defects in a host crystal. Based on this, we present a novel technique to measure the precipitation kinetics of oxygen in silicon already at its early stage of clustering at high temperatures. At 900 Degree-Sign C, precipitates with a radius smaller than 4 nm and with a density of 1 {+-} 0.5 Multiplication-Sign 10{sup 13} 1/cm{sup 3} were observed. The technique was calibrated by complementary scanning transmission electron microscope and energy dispersive X-ray measurements in the range of normal diffusivity yielding a diffusion constant of 1.7 {+-} 0.1 Multiplication-Sign 10{sup -12}cm{sup 2}/s, which is close to the literature value of 2.074 Multiplication-Sign 10{sup -12}cm{sup 2}/s. The measurements have been made with the characteristic K{sub {alpha}1}-line of a high voltage tungsten X-ray tube at 59.31 keV, which provides the opportunity to illuminate through complex sample environments like high temperature scattering furnaces.

  6. A concept to collect neutron and x-ray images on the same line of sight at NIF

    SciTech Connect (OSTI)

    Merrill, F. E., E-mail: fmerrill@lanl.gov; Danly, C. R.; Grim, G. P.; Volegov, P. L.; Wilde, C. H. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Izumi, N.; Jedlovec, D.; Fittinghoff, D. N.; Pak, A.; Park, H.-S. [Livermore National Laboratory, Livermore, California 94551 (United States)

    2014-11-15T23:59:59.000Z

    Neutron and x-ray images are collected at the National Ignition Facility (NIF) to measure the size and shape of inertial confinement fusion implosions. The x-ray images provide a measure of the size and shape of the hot region of the deuterium-tritium fuel while the neutron images provide a measure of the size and shape of the burning plasma. Although these two types of images are collected simultaneously, they are not collected along the same line of sight (LOS). One 14 MeV neutron image is collected on the NIF equator, and two x-ray images are collected along the polar axis and nearly perpendicular to the neutron imaging line of sight on the equator. Both measurements use pinhole apertures to form the images, but existing x-ray imaging provides time-resolved measurements while the neutron images are time-integrated. Detailed comparisons of the x-ray and neutron images can provide information on the fuel assembly, but these studies have been limited because the implosions are not azimuthally symmetric and the images are collected along different LOS. We have developed a conceptual design of a time-integrated x-ray imaging system that could be added to the existing neutron imaging LOS. This new system would allow these detailed studies, providing important information on the fuel assembly of future implosions. Here we present this conceptual design and the expected performance characteristics.

  7. Analyzer-based phase-contrast imaging system using a micro focus x-ray source

    SciTech Connect (OSTI)

    Zhou, Wei [BME Department, Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Majidi, Keivan; Brankov, Jovan G., E-mail: brankov@iit.edu [ECE Department, Illinois Institute of Technology, Chicago, Illinois 60616 (United States)

    2014-08-15T23:59:59.000Z

    Here we describe a new in-laboratory analyzer based phase contrast-imaging (ABI) instrument using a conventional X-ray tube source (CXS) aimed at bio-medical imaging applications. Phase contrast-imaging allows visualization of soft tissue details usually obscured in conventional X-ray imaging. The ABI system design and major features are described in detail. The key advantage of the presented system, over the few existing CXS ABI systems, is that it does not require high precision components, i.e., CXS, X-ray detector, and electro-mechanical components. To overcome a main problem introduced by these components, identified as temperature stability, the system components are kept at a constant temperature inside of three enclosures, thus minimizing the electrical and mechanical thermal drifts. This is achieved by using thermoelectric (Peltier) cooling/heating modules that are easy to control precisely. For CXS we utilized a microfocus X-ray source with tungsten (W) anode material. In addition the proposed system eliminates tungsten's multiple spectral lines by selecting monochromator crystal size appropriately therefore eliminating need for the costly mismatched, two-crystal monochromator. The system imaging was fine-tuned for tungsten K?{sub 1} line with the energy of 59.3 keV since it has been shown to be of great clinical significance by a number of researchers at synchrotron facilities. In this way a laboratory system that can be used for evaluating and quantifying tissue properties, initially explored at synchrotron facilities, would be of great interest to a larger research community. To demonstrate the imaging capability of our instrument we use a chicken thigh tissue sample.

  8. Structures and phase diagrams of N2 and CO to 13 GPa by x-ray diffraction

    SciTech Connect (OSTI)

    Mills, R.L.; Olinger, B.; Cromer, D.T.

    1986-03-01T23:59:59.000Z

    The structures and phase transitions of N2 and CO were studied by powder x-ray diffraction from 100 to 300 K and 4 to 13 GPa. Three solid phases, US , delta, and epsilon, were observed in each material. The known US and delta solids were confirmed to have hexagonal space group P63/mmc and cubic space group Pm3n, respectively. From refinements using photographic x-ray intensities, the new epsilon-N2 and epsilon-CO structures were determined to be rhombohedral R3c. There are eight ordered molecules in the epsilon-N2 unit cell with a = 5.928 A and = 85.14 at 110 K and 7.8 GPa, and eight ordered molecules in the epsilon-CO unit cell with a = 6.059 A and = 85.73 at 100 K and 5.5 GPa. The CO molecules are randomly oriented head to tail. The delta--epsilon transition takes place through an ordering and small displacement of the N2 and CO molecules, accompanied by a slight extension of the lattice along a cube diagonal. Molar volumes are presented over an expanded P-T region. Recent theoretical calculations using lattice energies, molecular dynamics, and symmetry correlations correctly predict features in the N2 and CO phase diagrams.

  9. In-situ stress analysis with X-Ray diffraction for yield locus characterization of sheet metals

    SciTech Connect (OSTI)

    Güner, A.; Tekkaya, A. E. [Institute of Forming Technology and Lightweight Construction, TU Dortmund University, Baroper Str. 301, 44227 Dortmund (Germany); Zillmann, B.; Lampke, T. [Institute of Materials Science and Engineering, Chemnitz University of Technology, Erfenschlager Strasse 73 D-09125 Chemnitz (Germany)

    2013-12-16T23:59:59.000Z

    A main problem in the field of sheet metal characterization is the inhomogeneous plastic deformation in the gauge regions of specimens which causes the analytically calculated stresses to differ from the sought state of stress acting in the middle of the gauge region. To overcome this problem, application of X-Ray diffraction is analyzed. For that purpose a mobile X-ray diffractometer and an optical strain measurement system are mounted on a universal tensile testing machine. This enables the recording of the whole strain and stress history of a material point. The method is applied to uniaxial tension tests, plane strain tension tests and shear tests to characterize the interstitial free steel alloy DC06. The applicability of the concepts of stress factors is verified by uniaxial tension tests. The experimentally obtained values are compared with the theoretical values calculated with crystal elasticity models utilizing the orientation distribution functions (ODF). The relaxation problem is addressed which shows itself as drops in the stress values with the strain kept at a constant level. This drop is analyzed with elasto-viscoplastic material models to correct the measured stresses. Results show that the XRD is applicable to measure the stresses in sheet metals with preferred orientation. The obtained yield locus is expressed with the Yld2000–2D material model and an industry oriented workpiece is analyzed numerically. The comparison of the strain distribution on the workpiece verifies the identified material parameters.

  10. Tuning of colossal dielectric constant in gold-polypyrrole composite nanotubes using in-situ x-ray diffraction techniques

    SciTech Connect (OSTI)

    Sarma, Abhisakh; Sanyal, Milan K., E-mail: milank.sanyal@saha.ac.in [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India)

    2014-09-15T23:59:59.000Z

    In-situ x-ray diffraction technique has been used to study the growth process of gold incorporated polypyrrole nanotubes that exhibit colossal dielectric constant due to existence of quasi-one-dimensional charge density wave state. These composite nanotubes were formed within nanopores of a polycarbonate membrane by flowing pyrrole monomer from one side and mixture of ferric chloride and chloroauric acid from other side in a sample cell that allows collection of x-ray data during the reaction. The size of the gold nanoparticle embedded in the walls of the nanotubes was found to be dependent on chloroauric acid concentration for nanowires having diameter more than 100 nm. For lower diameter nanotubes the nanoparticle size become independent of chloroauric acid concentration and depends on the diameter of nanotubes only. The result of this study also shows that for 50 nm gold-polypyrrole composite nanotubes obtained with 5.3 mM chloroauric acid gives colossal dielectric constant of about 10{sup 7}. This value remain almost constant over a frequency range from 1Hz to 10{sup 6} Hz even at 80 K temperature.

  11. Atomic data for the ITER Core Imaging X-ray Spectrometer

    SciTech Connect (OSTI)

    Clementson, J; Beiersdorfer, P; Biedermann, C; Bitter, M; Delgado-Aparicio, L F; Graf, A; Gu, M F; Hill, K W; Barnsley, R

    2012-06-15T23:59:59.000Z

    The parameters of the ITER core plasmas will be measured using the Core Imaging X-ray Spectrometer (CIXS), a high-resolution crystal spectrometer focusing on the L-shell spectra of highly ionized tungsten atoms. In order to correctly infer the plasma properties accurate atomic data are required. Here, some aspects of the underlying physics are discussed using experimental data and theoretical predictions from modeling.

  12. Radiation exposure in X-ray-based imaging techniques used in osteoporosis

    E-Print Network [OSTI]

    Damilakis, John; Adams, Judith E.; Guglielmi, Giuseppe; Link, Thomas M.

    2010-01-01T23:59:59.000Z

    and nonradiologists in dual-energy X-ray absorptiometrymorphometry studies using dual-energy X-ray absorptiometry.dose measurements in dual energy X-ray absorptiometry (DXA).

  13. Beyond 3-D X-ray Imaging: Methodology Development and Applications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the availability of the new generation of X-ray sources and the advanced X-ray optics. The advanced X-ray Optics along with novel methodology has made it possible to...

  14. Femtosecond Single-Shot Imaging of Nanoscale Ferromagnetic Order in Co/Pd Multilayers using Resonant X-ray Holography

    SciTech Connect (OSTI)

    Wang, Tianhan; Zhu, Diling; Benny Wu,; Graves, Catherine; Schaffert, Stefan; Rander, Torbjorn; Muller, leonard; Vodungbo, Boris; Baumier, Cedric; Bernstein, David P.; Brauer, Bjorn; Cros, Vincent; Jong, Sanne de; Delaunay, Renaud; Fognini, Andreas; Kukreja, Roopali; Lee, Sooheyong; Lopez-Flores, Victor; Mohanty, Jyoti; Pfau, Bastian; Popescu, 5 Horia

    2012-05-15T23:59:59.000Z

    We present the first single-shot images of ferromagnetic, nanoscale spin order taken with femtosecond x-ray pulses. X-ray-induced electron and spin dynamics can be outrun with pulses shorter than 80 fs in the investigated fluence regime, and no permanent aftereffects in the samples are observed below a fluence of 25 mJ/cm{sup 2}. Employing resonant spatially-muliplexed x-ray holography results in a low imaging threshold of 5 mJ/cm{sup 2}. Our results open new ways to combine ultrafast laser spectroscopy with sequential snapshot imaging on a single sample, generating a movie of excited state dynamics.

  15. Taheri-Saramad x-ray detector (TSXD): A novel high spatial resolution x-ray imager based on ZnO nano scintillator wires in polycarbonate membrane

    SciTech Connect (OSTI)

    Taheri, A., E-mail: at1361@aut.ac.ir; Saramad, S.; Ghalenoei, S.; Setayeshi, S. [Department of Energy Engineering and Physics, Amirkabir University of Technology, Tehran 15875-4413 (Iran, Islamic Republic of)] [Department of Energy Engineering and Physics, Amirkabir University of Technology, Tehran 15875-4413 (Iran, Islamic Republic of)

    2014-01-15T23:59:59.000Z

    A novel x-ray imager based on ZnO nanowires is designed and fabricated. The proposed architecture is based on scintillation properties of ZnO nanostructures in a polycarbonate track-etched membrane. Because of higher refractive index of ZnO nanowire compared to the membrane, the nanowire acts as an optical fiber that prevents the generated optical photons to spread inside the detector. This effect improves the spatial resolution of the imager. The detection quantum efficiency and spatial resolution of the fabricated imager are 11% and <6.8 ?m, respectively.

  16. Thermoelastic study of nanolayered structures using time-resolved X-ray diffraction at high repetition rate

    SciTech Connect (OSTI)

    Navirian, H. A.; Schick, D., E-mail: daniel.schick@uni-potsdam.de; Leitenberger, W.; Bargheer, M. [Institut für Physik und Astronomie, Universität Potsdam, Karl-Liebknecht-Str. 24-25, 14476 Potsdam (Germany); Gaal, P.; Shayduk, R. [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Wilhelm-Conrad-Röntgen Campus, BESSY II, Albert-Einstein-Str. 15, 12489 Berlin (Germany)

    2014-01-13T23:59:59.000Z

    We investigate the thermoelastic response of a nanolayered sample composed of a metallic SrRuO{sub 3} electrode sandwiched between a ferroelectric Pb(Zr{sub 0.2}Ti{sub 0.8})O{sub 3} film with negative thermal expansion and a SrTiO{sub 3} substrate. SrRuO{sub 3} is rapidly heated by fs-laser pulses with 208?kHz repetition rate. Diffraction of X-ray pulses derived from a synchrotron measures the transient out-of-plane lattice constant c of all three materials simultaneously from 120?ps to 5??s with a relative accuracy up to ?c/c?=?10{sup ?6}. The in-plane propagation of sound is essential for understanding the delayed out-of-plane compression of Pb(Zr{sub 0.2}Ti{sub 0.8})O{sub 3}.

  17. Time-resolved X-ray diffraction studies of laser-induced acoustic wave propagation in bilayer metallic thin crystals

    SciTech Connect (OSTI)

    Er, Ali Oguz [Department of Physics and Astronomy, Western Kentucky University, Bowling Green, Kentucky 42101 (United States); Tang, Jau, E-mail: jautang@gate.sinica.edu.tw, E-mail: prentzepis@ece.tamu.edu [Research Center for Applied Sciences Academia Sinica, Taipei, Taiwan (China); Chen, Jie [Key Laboratory for Laser Plasmas (Ministry of Education) and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China); Rentzepis, Peter M., E-mail: jautang@gate.sinica.edu.tw, E-mail: prentzepis@ece.tamu.edu [Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843 (United States)

    2014-09-07T23:59:59.000Z

    Phonon propagation across the interface of a Cu/Ag(111) bilayer and transient lattice disorder, induced by a femtosecond 267?nm pulse, in Ag(111) crystal have been measured by means of time resolved X-ray diffraction. A “blast” force due to thermal stress induced by suddenly heated electrons is formed within two picoseconds after excitation and its “blast wave” propagation through the interface and Ag (111) crystal was monitored by the shift and broadening of the rocking curve, I vs. ?, as a function of time after excitation. Lattice disorder, contraction and expansion as well as thermal strain formation and wave propagation have also been measured. The experimental data and mechanism proposed are supported by theoretical simulations.

  18. X-ray diffraction, optical microscopy, and microhardness studies of gas nitrided titanium alloys and titanium aluminide

    SciTech Connect (OSTI)

    Sha, W. [Metals Research Group, School of Planning, Architecture and Civil Engineering, The Queen's University of Belfast, Belfast BT7 1NN (United Kingdom)], E-mail: w.sha@qub.ac.uk; Haji Mat Don, M.A.; Mohamed, A.; Wu, X.; Siliang, B. [Metals Research Group, School of Planning, Architecture and Civil Engineering, The Queen's University of Belfast, Belfast BT7 1NN (United Kingdom); Zhecheva, A. [Sifco Applied Surface Concepts (UK) Ltd., Division of Sifco Industries, Inc., European Headquarters, 38 Walkers Road, Moons Moat North, Redditch, Worcestershire B98 9HD (United Kingdom)

    2008-03-15T23:59:59.000Z

    Thermochemical surface gas nitriding of {beta}21s, Timetal 205 and a Ti-Al alloy was conducted using differential scanning calorimeter equipment, in nominally pure nitrogen at 850 deg. C and 950 deg. C ({beta}21s), 730 deg. C and 830 deg. C (Timetal 205), and 950 deg. C and 1050 deg. C (Ti-Al) for 1 h, 3 h and 5 h. X-ray diffraction analyses showed new phases formed in the nitrided layer, depending on the alloy and the time and the temperature of nitriding. Microstructures were analyzed using optical microscopy. Cross-sectional microhardness profiles of cross-sectional samples after nitriding were obtained using a Knoop indenter.

  19. Diffusion-driven precipitate growth and ripening of oxygen precipitates in boron doped silicon by dynamical x-ray diffraction

    SciTech Connect (OSTI)

    Will, J., E-mail: will@krist.uni-erlangen.de; Gröschel, A.; Bergmann, C.; Magerl, A. [Crystallography and Structural Physics, University of Erlangen-Nürnberg, Staudtstr. 3, 91058 Erlangen (Germany); Spiecker, E. [Center for Nanoanalysis and Electron Microscopy, University of Erlangen-Nürnberg, Cauerstr. 6, 91058 Erlangen (Germany)

    2014-03-28T23:59:59.000Z

    X-ray Pendellösung fringes from three silicon single crystals measured at 900?°C are analyzed with respect to density and size of oxygen precipitates within a diffusion-driven growth model and compared with TEM investigations. It appears that boron doped (p+) material shows a higher precipitate density and a higher strain than moderately (p-) boron crystals. In-situ diffraction reveals a diffusion-driven precipitate growth followed by a second growth regime in both materials. An interpretation of the second growth regime in terms of Ostwald ripening yields surface energy values (around 70?erg/cm{sup 2}) similar to published data. Further, an increased nucleation rate by a factor of ?13 is found in the p+ sample as compared to a p- sample at a nucleation temperature of 450?°C.

  20. Observation of localized heating phenomena during microwave heating of mixed powders using in situ x-ray diffraction technique

    SciTech Connect (OSTI)

    Sabelström, N., E-mail: sabelstrom.n.aa@m.titech.ac.jp; Hayashi, M. [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, Tokyo 152-8552 (Japan); Watanabe, T. [Department of Chemistry and Materials Science, Tokyo Institute of Technology, Tokyo 152-8552 (Japan); Nagata, K. [Department of Conservation Science, Tokyo University of the Arts, 12-8 Ueno Park, Taito-ku, Tokyo (Japan)

    2014-10-28T23:59:59.000Z

    In materials processing research using microwave heating, there have been several observations of various phenomena occurring known as microwave effects. One significant example of such a phenomenon is increased reaction kinetics. It is believed that there is a possibility that this might be caused by localized heating, were some reactants would attain a higher than apparent temperature. To examine whether such thermal gradients are indeed possible, mixed powders of two microwave non-absorbers, alumina and magnesia, were mixed with graphite, a known absorber, and heated in a microwave furnace. During microwave irradiation, the local temperatures of the respective sample constituents were measured using an in situ x-ray diffraction technique. In the case of the alumina and graphite sample, a temperature difference of around 100?°C could be observed.

  1. Synthesis and single crystal x-ray diffraction study of a Schiff base derived from 4-acylpyrazolone and 2-aminophenol

    SciTech Connect (OSTI)

    Sharma, Naresh; Kant, Rajni, E-mail: vivek-gupta2k2@hotmail.com; Gupta, Vivek K., E-mail: vivek-gupta2k2@hotmail.com [Department of Physics and Electronics, University of Jammu, Jammu Tawi - 180006 (India); Jadeja, R. N. [Department of Chemistry, Faculty of Science, The M. S. University of Baroda, Vadodara-390002 (India)

    2014-04-24T23:59:59.000Z

    The title compound, (Z)-1-(3-chlorophenyl)-4[1((2hydroxyphenyl)amino)propylidene] -3-methyl-1H-pyrazol-5(4H)-one was synthesized by refluxing compound 1-(m-chlorophenyl)-3-methyl-4-propionyl-5-pyrazolone, with 2-aminophenol in ethanol. The compound crystallizes in the orthorhombic crystal system with space group Pca2{sub 1} having unit cell parameters: a = 26.2993(8), b = 7.0724(2) and c = 18.7170(5)Å. The structure contains two crystallographically independent molecules, A, and, B, in the asymmetric unit cell. The crystal structure was solved by direct method using single crystal X-ray diffraction data collected at room temperature and refined by full-matrix least-squares procedures to a final R- value of 0.049 for 5207 observed reflections.

  2. Beam hardening effects in grating-based x-ray phase-contrast imaging

    SciTech Connect (OSTI)

    Chabior, Michael; Donath, Tilman; David, Christian; Bunk, Oliver; Schuster, Manfred; Schroer, Christian; Pfeiffer, Franz [Siemens AG Corporate Technology, 80200 Muenchen (Germany); Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Siemens AG Corporate Technology, 80200 Muenchen (Germany); Technische Universitaet Dresden, 01062 Dresden (Germany); Technische Universitaet Muenchen, 85748 Garching (Germany)

    2011-03-15T23:59:59.000Z

    Purpose: In this work, the authors investigate how beam hardening affects the image formation in x-ray phase-contrast imaging and consecutively develop a correction algorithm based on the results of the analysis. Methods: The authors' approach utilizes a recently developed x-ray imaging technique using a grating interferometer capable of visualizing the differential phase shift of a wave front traversing an object. An analytical description of beam hardening is given, highlighting differences between attenuation and phase-contrast imaging. The authors present exemplary beam hardening artifacts for a number of well-defined samples in measurements at a compact laboratory setup using a polychromatic source. Results: Despite the differences in image formation, the authors show that beam hardening leads to a similar reduction of image quality in phase-contrast imaging as in conventional attenuation-contrast imaging. Additionally, the authors demonstrate that for homogeneous objects, beam hardening artifacts can be corrected by a linearization technique, applicable to all kinds of phase-contrast methods using polychromatic sources. Conclusions: The evaluated correction algorithm is shown to yield good results for a number of simple test objects and can thus be advocated in medical imaging and nondestructive testing.

  3. Feasibility Study of Gas Electron Multiplier Detector as an X-Ray Image Sensor

    E-Print Network [OSTI]

    Shin, Sukyoung; Lee, Soonhyouk

    2015-01-01T23:59:59.000Z

    For its ease manufacturing, flexible geometry, and cheap manufacturing cost, the gas electron multiplier (GEM) detector can be used as an x-ray image sensor. For this purpose, we acquired relative detection efficiencies and suggested a method to increase the detection efficiency in order to study the possibility of GEM detector as an x-ray image sensor. The GEM detector system is composed of GEM foils, the instrument system, the gas system, and the negative power supply. The instrument system consists of the A225 charge sensitive preamp, A206 discriminator, and MCA8000D multichannel analyzer. For the gas system, Argon gas was mixed with CO2 to the ratio of 8:2, and for the negative 2,000 volts, the 3106D power supply was used. The CsI-coated GEM foil was used to increase the detection efficiency. Fe-55 was used as an x-ray source and the relative efficiency was acquired by using the ratio of GEM detector to the CdTe detector. The total count method and the energy spectrum method were used to calculate the rel...

  4. Regularization of soft-X-ray imaging in the DIII-D tokamak

    SciTech Connect (OSTI)

    Wingen, Andreas [ORNL; Shafer, Morgan W [ORNL; Unterberg, Ezekial A [ORNL; Hill, Judith C [ORNL; Hillis, Donald Lee [ORNL

    2015-01-01T23:59:59.000Z

    An image inversion scheme for the soft X-ray imaging system (SXRIS) diagnostic at the DIII-D tokamak is developed to obtain the local soft X-ray emission at a poloidal cross-section from the spatially line-integrated image taken by the SXRIS camera. The scheme uses the Tikhonov regularization method since the inversion problem is generally ill-posed. The regularization technique uses the generalized singular value decomposition to determine a solution that depends on a free regularization parameter. The latter has to be chosen carefully, and the so called {\\it L-curve} method to find the optimum regularization parameter is outlined. A representative test image is used to study the properties of the inversion scheme with respect to inversion accuracy, amount/strength of regularization, image noise and image resolution. The optimum inversion parameters are identified, while the L-curve method successfully computes the optimum regularization parameter. Noise is found to be the most limiting issue, but sufficient regularization is still possible at noise to signal ratios up to 10%-15%. Finally, the inversion scheme is applied to measured SXRIS data and the line-integrated SXRIS image is successfully inverted.

  5. Pore level imaging of fluid transport using synchrotron x-ray microtomography

    SciTech Connect (OSTI)

    Coles, M.E.; Hazlett, R.D.; Muegge, E.L. [Mobil Exploration and Producing Technical Center, Dallas, TX (United States); Spanne, P. [European Synchrotron Radiation Facility, 38 - Grenoble (France); Soll, W.E. [Los Alamos National Lab., NM (United States); Jones, K.W. [Brookhaven National Lab., Upton, NY (United States)

    1996-12-31T23:59:59.000Z

    Recently developed high resolution computed microtomography (CMI) using synchrotron X-ray sources is analogous to conventional medical Cr scanning and provides the ability to obtain three-dimensional images of specimens with a spatial resolution on the order of micrometers. Application of this technique to the study of core samples has previously been shown to provide excellent two- and three-dimensional high resolution descriptions of pore structure and mineral distributions of core material. Recently, computed microtomographic endpoint saturation images of a fluid filled sandstone core sample were obtained using a microtomographic apparatus and a high energy X-ray beam produced by a superconducting wiggler at the National Synchrotron Light Source at Brookhaven National Laboratory. Images of a 6 mm subsection of the one inch diameter core sample were obtained prior and subsequent to flooding to residual oil. Both oil and brine phases were observable within the imaged rock matrix. The rock matrix image data was used as input to a fluid transport simulator and the results compared with the end point saturation images and data. These high resolution images of the fluid filled pore space have not been previously available to researchers and will provide valuable insight to fluid flow, and provide data as input into and validation of high resolution porous media flow simulators, such as percolation-network and Lattice Boltzmann models.

  6. High-resolution ab initio three-dimensional X-ray diffraction microscopy (CXIDB ID 15)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chapman, Henry N.

    The file contains 125 images corresponding to different tilts of the sample around the y axis at 1 degree intervals. Each image is the result of 4 exposures merged together. For more details see the citation.

  7. Cs-Exchange in Birnessite: Raction Mechanisms Inferred from Time-Resolved X-ray Diffraction and Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Lopano, C.; Heaney, P; Post, J

    2009-01-01T23:59:59.000Z

    We have explored the exchange of Cs for interlayer Na in birnessite using several techniques, including transmission electron microscopy (TEM) and time-resolved synchrotron X-ray diffraction (XRD). Our goal was to test which of two possible exchange mechanisms is operative during the reaction: (1) diffusion of cations in and out of the interlayer or (2) dissolution of Na-birnessite and reprecipitation of Cs-birnessite. The appearance of distinct XRD peaks for Na- and Cs-rich phases in partially exchanged samples offered support for a simple diffusion model, but it was inconsistent with the compositional and crystallographic homogeneity of (Na,Cs)-birnessite platelets from core to rim as ascertained by TEM. Time-resolved XRD revealed systematic changes in the structure of the emergent Cs-rich birnessite phase during exchange, in conflict with a dissolution and reprecipitation model. Instead, we propose that exchange occurred by sequential delamination of Mn oxide octahedral sheets. Exfoliation of a given interlayer region allowed for wholesale replacement of Na by Cs and was rapidly followed by reassembly. This model accounts for the rapidity of metal exchange in birnessite, the co-existence of distinct Na- and Cs-birnessite phases during the process of exchange, and the uniformly mixed Na- and Cs-compositions ascertained from point analyses by selected area electron diffraction and energy dispersive spectroscopy of partially exchanged grains.

  8. The SF6 monolayer on graphite by X-ray diffraction C. Marti, T. Ceva, B. Croset, C. De Beauvais and A. Thomy (*)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1517 The SF6 monolayer on graphite by X-ray diffraction C. Marti, T. Ceva, B. Croset, C. De) Résumé. 2014 La structure du film de SF6 adsorbé sur graphite a été étudiée entre 35 et 180 K par du cristal 3D, ce qui explique le mouillage imparfait du graphite par SF6. Dans le domaine où la

  9. Characterization of Chain Molecular Assemblies in Long-Chain, Layered Silver Thiolates: A Joint Infrared Spectroscopy and X-ray Diffraction Study

    E-Print Network [OSTI]

    Parikh, Atul N.

    , and Theoretical DiVisions, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 ReceiVed: October 1, 1998 of infrared transmission spectroscopy and powder X-ray diffraction. The structural attributes elucidated. The three-dimensional network of 1D channels alternates between the chain layers. All the chain structural

  10. Amyloid Treatment and Research Program key research findings: Definition of the electron microscopic structure and x-ray diffraction pattern of amyloid

    E-Print Network [OSTI]

    Finzi, Adrien

    , which for the first time defined the biochemical nature and source of the amyloid fibril in this form microscopic structure and x-ray diffraction pattern of amyloid fibrils in 1967, providing key insight of amyloidosis. Characterization of the protein deposits in dialysis-associated amyloidosis as 2- microglobulin

  11. Intrafacet migration effects in InGaN/GaN structures grown on triangular GaN ridges studied by submicron beam x-ray diffraction

    E-Print Network [OSTI]

    Sirenko, Andrei

    Intrafacet migration effects in InGaN/GaN structures grown on triangular GaN ridges studied for x-ray diffraction and reciprocal space mapping of InGaN/GaN multiple-quantum-well MQW structures grown on the sidewalls of 10- m-wide triangular GaN ridges with 1-1.1 facets. Samples were produced

  12. Synchrotron X-ray diffraction studies of phase transitions and mechanical properties of nanocrystalline materials at high pressure

    SciTech Connect (OSTI)

    Prilliman, Gerald Stephen

    2003-09-01T23:59:59.000Z

    The behavior of nanocrystals under extreme pressure was investigated using synchrotron x-ray diffraction. A major part of this investigation was the testing of a prototype synchrotron endstation on a bend magnet beamline at the Advanced Light Source for high pressure work using a diamond anvil cell. The experiments conducted and documented here helped to determine issues of efficiency and accuracy that had to be resolved before the construction of a dedicated ''super-bend'' beamline and endstation. The major conclusions were the need for a cryo-cooled monochromator and a fully remote-controllable pressurization system which would decrease the time to change pressure and greatly reduce the error created by the re-placement of the diamond anvil cell after each pressure change. Two very different types of nanocrystal systems were studied, colloidal iron oxide (Fe{sub 2}O{sub 3}) and thin film TiN/BN. Iron oxide nanocrystals were found to have a transition from the {gamma} to the {alpha} structure at a pressure strongly dependent on the size of the nanocrystals, ranging from 26 GPa for 7.2 nm nanocrystals to 37 GPa for 3.6 nm nanocrystals. All nanocrystals were found to remain in the {alpha} structure even after release of pressure. The transition pressure was also found, for a constant size (5.7 nm) to be strongly dependent on the degree of aggregation of the nanocrystals, increasing from 30 GPa for completely dissolved nanocrystals to 45 GPa for strongly aggregated nanocrystals. Furthermore, the x-ray diffraction pattern of the pressure induced {alpha} phase demonstrated a decrease in intensity for certain select peaks. Together, these observations were used to make a complete picture of the phase transition in nanocrystalline systems. The size dependence of the transition was interpreted as resulting from the extremely high surface energy of the {alpha} phase which would increase the thermodynamic offset and thereby increase the kinetic barrier to transition that must be overridden with pressure. The anomalous intensities in the x-ray diffraction patterns were interpreted as being the result of stacking faults, indicating that the mechanism of transition proceeds by the sliding of {gamma}(111) planes to form {alpha}(001) planes. The increasing transition pressure for more aggregated samples may be due to a positive activation volume, retarding the transition for nanocrystals with less excess (organic) volume available to them. The lack of a reverse transition upon decompression makes this interpretation more difficult because of the lack of an observable hysteresis, and it is therefore difficult to ascertain kinetic effects for certain. In the case TiN/BN nanocomposite systems, it was found that the bulk modulus (B{sub 0}) of the TiN nanoparticles was not correlated to the observed hardness or Young's modulus of the macroscopic thin film. This indicates that the origin of the observed super-hard nature of these materials is not due to any change in the Ti-N interatomic potential. Rather, the enhanced hardness must be due to nano-structural effects. It was also found that during pressurization the TiN nanoparticles developed a great deal of strain. This strain can be related to defects induced in individual nanoparticles which generates strain in adjacent particles due to the highly coupled nature of the system.

  13. Soft x-ray backlighting of cryogenic implosions using a narrowband crystal imaging system (invited)

    SciTech Connect (OSTI)

    Stoeckl, C., E-mail: csto@lle.rochester.edu; Bedzyk, M.; Brent, G.; Epstein, R.; Fiksel, G.; Guy, D.; Goncharov, V. N.; Hu, S. X.; Ingraham, S.; Jacobs-Perkins, D. W.; Jungquist, R. K.; Marshall, F. J.; Mileham, C.; Nilson, P. M.; Sangster, T. C.; Shoup, M. J.; Theobald, W. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

    2014-11-15T23:59:59.000Z

    A high-performance cryogenic DT inertial confinement fusion implosion experiment is an especially challenging backlighting configuration because of the high self-emission of the core at stagnation and the low opacity of the DT shell. High-energy petawatt lasers such as OMEGA EP promise significantly improved backlighting capabilities by generating high x-ray intensities and short emission times. A narrowband x-ray imager with an astigmatism-corrected bent quartz crystal for the Si He{sub ?} line at ?1.86 keV was developed to record backlit images of cryogenic direct-drive implosions. A time-gated recording system minimized the self-emission of the imploding target. A fast target-insertion system capable of moving the backlighter target ?7 cm in ?100 ms was developed to avoid interference with the cryogenic shroud system. With backlighter laser energies of ?1.25 kJ at a 10-ps pulse duration, the radiographic images show a high signal-to-background ratio of >100:1 and a spatial resolution of the order of 10 ?m. The backlit images can be used to assess the symmetry of the implosions close to stagnation and the mix of ablator material into the dense shell.

  14. Growth and nucleation regimes in boron doped silicon by dynamical x-ray diffraction

    SciTech Connect (OSTI)

    Will, J., E-mail: johannes.will@fau.de; Gröschel, A.; Bergmann, C.; Weißer, M.; Magerl, A. [Crystallography and Structural Physics, University of Erlangen-Nürnberg, Staudtstr. 3, 91058 Erlangen (Germany)

    2014-09-15T23:59:59.000Z

    The oxygen precipitation of highly (17.5 m? cm) and moderately (4.5 ? cm) boron (B) doped silicon (Si) crystals at 780?°C is investigated by following in-situ the evolution of diffraction Pendellösung oscillations. All samples show an initial diffusion-driven growth process which may change over into Ostwald ripening. For the highly doped sample and involving a nucleation step at 450?°C for 30?h, the precipitate density ? is enhanced by a factor of 8 as compared to the moderately doped sample. The influence of a high B concentration on ? is dramatically higher for the samples directly heated to 780?°C, where an enhancement factor of 80 is found. Considering Ostwald ripening as a second growth regime reveals consistent ripening rates and surface energies ? with those found at 900?°C in a previous publication.

  15. Soft x-ray reduction camera for submicron lithography

    DOE Patents [OSTI]

    Hawryluk, Andrew M. (2708 Rembrandt Pl., Modesto, CA 95356); Seppala, Lynn G. (7911 Mines Rd., Livermore, CA 94550)

    1991-01-01T23:59:59.000Z

    Soft x-ray projection lithography can be performed using x-ray optical components and spherical imaging lenses (mirrors), which form an x-ray reduction camera. The x-ray reduction is capable of projecting a 5x demagnified image of a mask onto a resist coated wafer using 4.5 nm radiation. The diffraction limited resolution of this design is about 135 nm with a depth of field of about 2.8 microns and a field of view of 0.2 cm.sup.2. X-ray reflecting masks (patterned x-ray multilayer mirrors) which are fabricated on thick substrates and can be made relatively distortion free are used, with a laser produced plasma for the source. Higher resolution and/or larger areas are possible by varying the optic figures of the components and source characteristics.

  16. Soft x-ray reduction camera for submicron lithography

    DOE Patents [OSTI]

    Hawryluk, A.M.; Seppala, L.G.

    1991-03-26T23:59:59.000Z

    Soft x-ray projection lithography can be performed using x-ray optical components and spherical imaging lenses (mirrors), which form an x-ray reduction camera. The x-ray reduction is capable of projecting a 5x demagnified image of a mask onto a resist coated wafer using 4.5 nm radiation. The diffraction limited resolution of this design is about 135 nm with a depth of field of about 2.8 microns and a field of view of 0.2 cm[sup 2]. X-ray reflecting masks (patterned x-ray multilayer mirrors) which are fabricated on thick substrates and can be made relatively distortion free are used, with a laser produced plasma for the source. Higher resolution and/or larger areas are possible by varying the optic figures of the components and source characteristics. 9 figures.

  17. X-ray imaging of extended magnetic domain walls in Ni80Fe20 wires

    SciTech Connect (OSTI)

    Basu, S.; Fry, P. W.; Allwood, D. A.; Bryan, M. T.; Gibbs, M. R. J.; Schrefl, T.; Im, M.-Y.; Fischer, P.

    2009-06-20T23:59:59.000Z

    We have used magnetic transmission X-ray microscopy to image magnetization configurations in 700 nm wide Ni{sub 80}Fe{sub 20} planar wires attached to 'nucleation' pads Domain walls were observed to inject only across half of the wire width but extend to several micrometers in length. Magnetostatic interactions with adjacent wires caused further unusual domain wall behavior. Micromagnetic modeling suggests the extended walls have Neel-like structure along their length and indicates weaker exchange coupling than is often assumed. These observations explain previous measurements of domain wall injection and demonstrate that magnetic domain walls in larger nanowires cannot always be considered as localized entities.

  18. A monochromatic x-ray imaging system for characterizing low-density foams

    SciTech Connect (OSTI)

    Lanier, Nicholas E. [Los Alamos National Laboratory; Taccetti, Jose M. [Los Alamos National Laboratory; Hamilton, Christopher E. [Los Alamos National Laboratory

    2012-05-04T23:59:59.000Z

    In High Energy Density (HED) laser experiments, targets often require small, low-density, foam components. However, their limited size can preclude single component characterization, forcing one to rely solely on less accurate bulk measurements. We have developed a monochromatic imaging a system to characterize both the density and uniformity of single component low-mass foams. This x-ray assembly is capable of determining line-averaged density variations near the 1% level, and provides statistically identical results to those obtained at the Brookhaven's NSLS. This system has the added benefit of providing two-dimensional density data, allowing an assessment of density uniformity.

  19. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat isJoin theanniversaryI 1 0 3 P 0 d dX-Ray Imaging

  20. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat isJoin theanniversaryI 1 0 3 P 0 dX-Ray Imaging

  1. 2D electron temperature diagnostic using soft x-ray imaging technique

    SciTech Connect (OSTI)

    Nishimura, K., E-mail: nishim11@nuclear.es.kit.ac.jp; Sanpei, A., E-mail: sanpei@kit.ac.jp; Tanaka, H.; Ishii, G.; Kodera, R.; Ueba, R.; Himura, H.; Masamune, S. [Department of Electronics, Kyoto Institute of Technology, Kyoto 606-8585 (Japan)] [Department of Electronics, Kyoto Institute of Technology, Kyoto 606-8585 (Japan); Ohdachi, S.; Mizuguchi, N. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan)] [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan)

    2014-03-15T23:59:59.000Z

    We have developed a two-dimensional (2D) electron temperature (T{sub e}) diagnostic system for thermal structure studies in a low-aspect-ratio reversed field pinch (RFP). The system consists of a soft x-ray (SXR) camera with two pin holes for two-kinds of absorber foils, combined with a high-speed camera. Two SXR images with almost the same viewing area are formed through different absorber foils on a single micro-channel plate (MCP). A 2D T{sub e} image can then be obtained by calculating the intensity ratio for each element of the images. We have succeeded in distinguishing T{sub e} image in quasi-single helicity (QSH) from that in multi-helicity (MH) RFP states, where the former is characterized by concentrated magnetic fluctuation spectrum and the latter, by broad spectrum of edge magnetic fluctuations.

  2. Generalized Uncertainty Quantification for Linear Inverse Problems in X-ray Imaging

    SciTech Connect (OSTI)

    Fowler, Michael James

    2014-04-25T23:59:59.000Z

    In industrial and engineering applications, X-ray radiography has attained wide use as a data collection protocol for the assessment of material properties in cases where direct observation is not possible. The direct measurement of nuclear materials, particularly when they are under explosive or implosive loading, is not feasible, and radiography can serve as a useful tool for obtaining indirect measurements. In such experiments, high energy X-rays are pulsed through a scene containing material of interest, and a detector records a radiograph by measuring the radiation that is not attenuated in the scene. One approach to the analysis of these radiographs is to model the imaging system as an operator that acts upon the object being imaged to produce a radiograph. In this model, the goal is to solve an inverse problem to reconstruct the values of interest in the object, which are typically material properties such as density or areal density. The primary objective in this work is to provide quantitative solutions with uncertainty estimates for three separate applications in X-ray radiography: deconvolution, Abel inversion, and radiation spot shape reconstruction. For each problem, we introduce a new hierarchical Bayesian model for determining a posterior distribution on the unknowns and develop efficient Markov chain Monte Carlo (MCMC) methods for sampling from the posterior. A Poisson likelihood, based on a noise model for photon counts at the detector, is combined with a prior tailored to each application: an edge-localizing prior for deconvolution; a smoothing prior with non-negativity constraints for spot reconstruction; and a full covariance sampling prior based on a Wishart hyperprior for Abel inversion. After developing our methods in a general setting, we demonstrate each model on both synthetically generated datasets, including those from a well known radiation transport code, and real high energy radiographs taken at two U. S. Department of Energy laboratories.

  3. 3-dimensional imaging system using crystal diffraction lenses

    DOE Patents [OSTI]

    Smither, R.K.

    1999-02-09T23:59:59.000Z

    A device for imaging a plurality of sources of x-ray and gamma-ray radiation is provided. Diffracting crystals are used for focusing the radiation and directing the radiation to a detector which is used for analyzing their addition to collect data as to the location of the source of radiation. A computer is used for converting the data to an image. The invention also provides for a method for imaging x-ray and gamma radiation by supplying a plurality of sources of radiation; focusing the radiation onto a detector; analyzing the focused radiation to collect data as to the type and location of the radiation; and producing an image using the data. 18 figs.

  4. 3-dimensional imaging system using crystal diffraction lenses

    DOE Patents [OSTI]

    Smither, Robert K. (Hinsdale, IL)

    1999-01-01T23:59:59.000Z

    A device for imaging a plurality of sources of x-ray and gamma-ray radiation is provided. Diffracting crystals are used for focussing the radiation and directing the radiation to a detector which is used for analyzing their addition to collect data as to the location of the source of radiation. A computer is used for converting the data to an image. The invention also provides for a method for imaging x-ray and gamma radiation by supplying a plurality of sources of radiation; focussing the radiation onto a detector; analyzing the focused radiation to collect data as to the type and location of the radiation; and producing an image using the data.

  5. Atomic Resolution Coherent Diffractive Imaging and Ultrafast Science

    SciTech Connect (OSTI)

    Zuo, Jian-min (University of Illinois) [University of Illinois

    2011-01-12T23:59:59.000Z

    A major scientific challenge is determining the 3-D atomic structure of small nanostructures, including single molecules. Coherent diffractive imaging (CDI) is a promising approach. Recent progress has demonstrated coherent diffraction patterns can be recorded from individual nanostructures and phased to reconstruct their structure. However, overcoming the dose limit imposed by radiation damage is a major obstacle toward the full potential of CDI. One approach is to use ultrafast x-ray or electron pulses. In electron diffraction, amplitudes recorded in a diffraction pattern are unperturbed by lens aberrations, defocus, and other microscope resolution-limiting factors. Sub-A signals are available beyond the information limit of direct imaging. Significant contrast improvement is obtained compared to high-resolution electron micrographs. progress has also been made in developing time-resolved electron diffraction and imaging for the study of ultrafast dynamic processes in materials. This talk will cover these crosscutting issues and the convergence of electron and x-ray diffraction techniques toward structure determination of single molecules.

  6. Structure of a zeolite ZSM-5-Bithiophene complex as determined by high-resolution synchrotron X-ray powder diffraction

    SciTech Connect (OSTI)

    Eylem, C.; Hriljac, J.A. [Brookhaven National Laboratory, Upton, NY (United States)] [Brookhaven National Laboratory, Upton, NY (United States); Ramamurthy, V.; Corbin, D.R. [Du Pont Co., Wilmington, DE (United States)] [Du Pont Co., Wilmington, DE (United States); Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States)

    1996-04-01T23:59:59.000Z

    The structure of a zeolite ZSM-5 complex with ca. 4 molecules/unit cell of bithiophene was determined by high-resolution synchrotron X-ray powder diffraction. In adopts monoclinic symmetry in space group P2{sub 1}/n ({alpha} unique) between room temperature and 25 K, with refined lattice parameters at 25 K of a = 20.0614(4), b = 19.8251(4), c = 13.3623(4) {Angstrom}, and a = 90.848(2){degrees}. Structural modeling and Rietveld refinements showed that there are two crystallographically unique bithiophene molecules, each with an occupancy factor of ca. 0.5. One bithiophene is localized at the center of the straight channels with one of the rings residing at the intersection with the sinusoidal channels. The other molecule lies in the sinusoidal channels and projects partially into the straight channels. The relationship between polythiophene chain length and the formation of conducting polythiophene molecular wires in the ZSM-5 framework is discussed. 32 refs., 4 figs., 3 tabs.

  7. Purification, crystallization and preliminary X-ray diffraction analysis of the human mismatch repair protein MutS[beta

    SciTech Connect (OSTI)

    Tseng, Quincy; Orans, Jillian; Hast, Michael A.; Iyer, Ravi R.; Changela, Anita; Modrich, Paul L.; Beese, Lorena S. (Duke)

    2012-03-16T23:59:59.000Z

    MutS{beta} is a eukaryotic mismatch repair protein that preferentially targets extrahelical unpaired nucleotides and shares partial functional redundancy with MutS{alpha} (MSH2-MSH6). Although mismatch recognition by MutS{alpha} has been shown to involve a conserved Phe-X-Glu motif, little is known about the lesion-binding mechanism of MutS{beta}. Combined MSH3/MSH6 deficiency triggers a strong predisposition to cancer in mice and defects in msh2 and msh6 account for roughly half of hereditary nonpolyposis colorectal cancer mutations. These three MutS homologs are also believed to play a role in trinucleotide repeat instability, which is a hallmark of many neurodegenerative disorders. The baculovirus overexpression and purification of recombinant human MutS{beta} and three truncation mutants are presented here. Binding assays with heteroduplex DNA were carried out for biochemical characterization. Crystallization and preliminary X-ray diffraction analysis of the protein bound to a heteroduplex DNA substrate are also reported.

  8. Study of microstress state of P91 steel using complementary mechanical Barkhausen, magnetoacoustic emission, and X-ray diffraction techniques

    SciTech Connect (OSTI)

    Augustyniak, Boles?aw, E-mail: bolek@mif.pg.gda.pl; Piotrowski, Leszek; Maciakowski, Pawe?; Chmielewski, Marek [Faculty of Applied Physics and Mathematics, Gdansk University of Technology, 80-233 Gdansk (Poland); Lech-Grega, Marzena; ?elechowski, Janusz [The Institute of Non-Ferrous Metals, 32-050 Skawina (Poland)

    2014-05-07T23:59:59.000Z

    The paper deals with assessment of microstress state of martensite P91 steel using three complementary techniques: mechanical Barkhausen emission, magnetoacoustic emission (MAE), and X-ray diffraction (XRD) profile analysis. Magnetic coercivity Hc and microstructure were investigated with inductive magnetometry and magnetic force microscopy (MFM), respectively. Internal stress level of P91 steel was modified by heat treatment. Steel samples were austenitized, quenched, and then tempered at three temperatures (720?°C, 750?°C, and 780?°C) during increasing time (from 15?min up to 240?min). The microstrain level ?{sub i} was evaluated using Williamson–Hall method. It was revealed that during tempering microstrain systematically decreases from ?{sub i}?=?2.5 × 10{sup ?3} for as quenched state down to ?{sub i}?=?0.3?×?10{sup ?3} for well tempered samples. Both mechanical hardness (Vicker's HV) and magnetic hardness (coercivity) decrease almost linearly with decreasing microstrain while the MAE and MBE intensities strongly increase. Tempering leads to evident shift of the MeBN intensity maximum recorded for the first load towards lower applied strain values and to increase of MAE intensity. This indicates that the microstress state deduced by magnetic techniques is correlated with microstrains evaluated with XRD technique.

  9. X-ray diffraction analysis of InGaP/GaAs heterointerfaces grown by metalorganic chemical vapor deposition

    SciTech Connect (OSTI)

    Nittono, T.; Hyuga, F. [NTT System Electronics Laboratories 3-1, Morinosato Wakamiya, Atsugi-shi, Kanagawa, 243-01 (Japan)] [NTT System Electronics Laboratories 3-1, Morinosato Wakamiya, Atsugi-shi, Kanagawa, 243-01 (Japan)

    1997-03-01T23:59:59.000Z

    InGaP/GaAs heterointerfaces grown by metalorganic chemical vapor deposition have been characterized by a high-resolution x-ray diffraction analysis of multiple quantum well structures. The flow of AsH{sub 3} to InGaP surface produces an InGaAs-like interfacial layer at the GaAs-on-InGaP interface, indicating P atoms of the InGaP surface are easily replaced by As atoms. The flow of PH{sub 3} to GaAs surface, on the other hand, does not make any detectable interfacial layer, indicating that almost no As atoms of the GaAs surface are replaced by P atoms. It is also found that the flow of trimethylgallium (TMG) to the InGaP surface produces a GaP-like interfacial layer. This interfacial layer is probably formed by the reaction between TMG and excessive P atoms on the InGaP surface or residual PH{sub 3} in the growth chamber. {copyright} {ital 1997 American Institute of Physics.}

  10. Growth kinetics of CaF[sub 2]/Si(111) heteroepitaxy: An x-ray photoelectron diffraction study

    SciTech Connect (OSTI)

    Denlinger, J.D.; Rotenberg, E. (Department of Physics and Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720 (United States)); Hessinger, U.; Leskovar, M.; Olmstead, M.A. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1995-02-15T23:59:59.000Z

    Kinetic variations of the initial stages of CaF[sub 2] growth on Si(111) by molecular-beam epitaxy are studied with the [ital in] [ital situ] combination of x-ray photoelectron spectroscopy and diffraction. After the formation of a chemically reacted interface layer, the morphology of the subsequent bulk layers is found to be dependent on the substrate temperature and incident flux rate, as well as the initial interface structure. For substrate temperatures above [similar to]600 [degree]C, subsequent layers do not easily wet the interface layer, and a transition is observed from a three-dimensional island formation at low flux to a laminar growth following the coalescence of bilayer islands at higher flux. At lower substrate temperatures ([similar to]450 [degree]C), a different stoichiometry and structure of the interface layer leads to laminar growth at all fluxes, but with a different bulk nucleation behavior. Crystalline heteroepitaxy is not observed when growth initiates at room temperature, but homoepitaxy does proceed at room temperature if the first few layers are deposited at a high temperature. The different growth regimes are discussed in terms of a kinetic model separating step and terrace nucleation where, contrary to homoepitaxy, step nucleation leads to islanded growth.

  11. all-sky x-ray image: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sky coverage each orbit, and full sky coverage each 50 days, hard x-ray studies of gamma-ray bursts, AGN, galactic transients, x-ray binaries and accretion-powered pulsars can be...

  12. Design and characterization of electron beam focusing for X-ray generation in novel medical imaging architecture

    SciTech Connect (OSTI)

    Bogdan Neculaes, V., E-mail: neculaes@research.ge.com; Zou, Yun; Zavodszky, Peter; Inzinna, Louis; Zhang, Xi; Conway, Kenneth; Caiafa, Antonio; Frutschy, Kristopher; Waters, William; De Man, Bruno [GE Global Research, Niskayuna, New York 12309 (United States)] [GE Global Research, Niskayuna, New York 12309 (United States)

    2014-05-15T23:59:59.000Z

    A novel electron beam focusing scheme for medical X-ray sources is described in this paper. Most vacuum based medical X-ray sources today employ a tungsten filament operated in temperature limited regime, with electrostatic focusing tabs for limited range beam optics. This paper presents the electron beam optics designed for the first distributed X-ray source in the world for Computed Tomography (CT) applications. This distributed source includes 32 electron beamlets in a common vacuum chamber, with 32 circular dispenser cathodes operated in space charge limited regime, where the initial circular beam is transformed into an elliptical beam before being collected at the anode. The electron beam optics designed and validated here are at the heart of the first Inverse Geometry CT system, with potential benefits in terms of improved image quality and dramatic X-ray dose reduction for the patient.

  13. Study of calcium-containing orthophosphates of NaZr{sub 2}(PO{sub 4}){sub 3} structural type by high-temperature X-ray diffraction

    SciTech Connect (OSTI)

    Orlova, A. I.; Kanunov, A. E., E-mail: a.kanunov@mail.ru [Nizhni Novgorod State University (Russian Federation); Samoilov, S. G.; Kazakova, A. Yu.; Kazantsev, G. N. [Leipunsky Institute of Physics and Power Engineering (Russian Federation)] [Leipunsky Institute of Physics and Power Engineering (Russian Federation)

    2013-03-15T23:59:59.000Z

    Orthophosphates Ca{sub 0.5}Ti{sub 2}(PO{sub 4}){sub 3}, Ca{sub 0.5}Zr{sub 2}(PO{sub 4}){sub 3}, Ca{sub 0.75}Zr{sub 2}(SiO{sub 4}){sub 0.5}(PO{sub 4}){sub 2.5}, and CaMg{sub 0.5}Zr{sub 1.5}(PO{sub 4}){sub 3} (structural type NaZr{sub 2}(PO{sub 4}){sub 3}), having different occupancies of interframework positions by calcium, have been prepared by the sol-gel method with the subsequent thermal treatment of dried gels and investigated by IR spectroscopy and X-ray diffraction. The analytical indexing of X-ray diffraction patterns is performed within the sp. gr. R3{sup -}. High-temperature X-ray diffraction was used to investigate the behavior of the orthophosphates upon heating: thermal expansion in the temperature range of 20-610 Degree-Sign C (up to 500 Degree-Sign C for Ca{sub 0.5}Zr{sub 2}(PO{sub 4}){sub 3}). The coefficients of thermal expansion are calculated from the shift of diffraction peaks. The unit-cell parameters of crystals at different temperatures are determined. The dependences of thermal expansion and its anisotropy on the occupancy of cation M positions by calcium are revealed.

  14. Imaging design of the wide field x-ray monitor onboard the HETE satellite

    SciTech Connect (OSTI)

    Zand, J.J.M. In`T; Fenimore, E.E. [Los Alamos National Lab., NM (United States); Kawai, N.; Yoshida, A.; Matsuoka, M. [Institute of Physical and Chemical Research (RIKEN), Saitama (Japan); Yamauchi, M. [Miyazaki Univ. (Japan)

    1994-11-01T23:59:59.000Z

    The High Energy Transient Experiment (HETE), to be launched in 1995, will study Gamma-Ray Bursts in an unprecendented wide wavelength range from Gamma- and X-ray to UV wavelengths. The X-ray range (2 to 25 keV) will be covered by 2 perpendicularly oriented 1-dimensional coded aperture cameras. These instruments cover a wide field of view of 2 sr and thus have a relatively large potential to locate GRBs to a fraction of a degree, which is an order of magnitude better than BATSE. The imaging design of these coded aperture cameras relates to the design of the coded apertures and the decoding algorithm. The aperture pattern is to a large extent determined by the high background in this wide field application and the low number of pattern elements ({approximately}100) in each direction. The result is a random pattern with an open fraction of 33%. The onboard decoding algorithm is dedicated to the localization of a single point source.

  15. Simultaneous measurements of several state variables in shocked carbon by imaging x-ray scattering

    SciTech Connect (OSTI)

    Gamboa, E. J., E-mail: eliseo@umich.edu; Drake, R. P.; Keiter, P. A.; Trantham, M. R. [University of Michigan, Ann Arbor, Michigan 48109 (United States)] [University of Michigan, Ann Arbor, Michigan 48109 (United States); Falk, K.; Montgomery, D. S.; Benage, J. F. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2014-04-15T23:59:59.000Z

    We apply the novel experimental technique of imaging x-ray Thomson scattering to measure the spatial profiles of the temperature, ionization state, relative material density, and the shock speed in a high-energy density system. A blast wave driven in a low-density foam is probed with 90? scattering of 7.8?keV helium-like nickel x-rays, which are spectrally dispersed and resolved in one spatial dimension by a doubly curved crystal. The inferred properties of the shock are shown to be self-consistent with 1D analytical estimates. These high-resolution measurements enable a direct comparison of the observed temperature with the results from hydrodynamic simulations. We find good agreement with the simulations for the temperature at the shock front but discrepancies in the modeling of the spatial temperature profile and shock speed. These results indicate the challenges in modeling the shock dynamics of structured materials like foams, commonly used in many high-energy density and laboratory astrophysics experiments.

  16. X-ray imaging crystal spectroscopy for use in plasma transport research

    SciTech Connect (OSTI)

    Reinke, M. L.; Podpaly, Y. A.; Hutchinson, I. H.; Rice, J. E.; Gao, C.; Greenwald, M.; Howard, N. T.; Hubbard, A.; Hughes, J. W.; White, A. E.; Wolfe, S. M. [MIT-Plasma Science and Fusion Center, Cambridge, Massachusetts 02139 (United States); Bitter, M.; Delgado-Aparicio, L.; Hill, K.; Pablant, N. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

    2012-11-15T23:59:59.000Z

    This research describes advancements in the spectral analysis and error propagation techniques associated with x-ray imaging crystal spectroscopy (XICS) that have enabled this diagnostic to be used to accurately constrain particle, momentum, and heat transport studies in a tokamak for the first time. Doppler tomography techniques have been extended to include propagation of statistical uncertainty due to photon noise, the effect of non-uniform instrumental broadening as well as flux surface variations in impurity density. These methods have been deployed as a suite of modeling and analysis tools, written in interactive data language (IDL) and designed for general use on tokamaks. Its application to the Alcator C-Mod XICS is discussed, along with novel spectral and spatial calibration techniques. Example ion temperature and radial electric field profiles from recent I-mode plasmas are shown, and the impact of poloidally asymmetric impurity density and natural line broadening is discussed in the context of the planned ITER x-ray crystal spectrometer.

  17. Hydrostatic Compression Curve for Triamino-Trinitrobenzene Determined to 13.0 GPa with Powder X-Ray Diffraction

    SciTech Connect (OSTI)

    Stevens, Lewis L.; Velisavljevic, Nenad; Hooks, Daniel E.; Dattelbaum, Dana M. (LANL)

    2008-08-22T23:59:59.000Z

    Using powder X-ray diffraction in conjunction with a diamond anvil cell (DAC), the unit cell volume of triamino-trinitrobenzene (TATB) has been measured from ambient pressure to 13 GPa. The resultant isotherm is compared with previous theoretical (Byrd and Rice and Pastine and Bernecker) and experimental (Olinger and Cady) works. While all reports are consistent to approximately 2 GPa, our measurements reveal a slightly stiffer TATB material than reported by Olinger and Cady and an intermediate compressibility compared with the isotherms predicted by the two theoretical works. Analysis of the room temperature isotherm using the semi-empirical, Murnaghan, Birch-Murnaghan, and Vinet equations of state (EOS) provided a determination of the isothermal bulk modulus (K{sub 0}) and its pressure-derivative (K{sub 0}') for TATB. From these fits to our P-V isotherm, from ambient pressure to 8 GPa, the average results for the zero-pressure bulk modulus and its pressure derivative were found to be 14.7 GPa and 10.1, respectively. For comparison to shock experiments on pressed TATB powder and its plastic-bonded formulation PBX 9502 (95% TATB, 5% Kel-F 800), the isotherm was transformed to the pseudo-velocity U{sub s}-u{sub p} plane using the Rankine-Hugoniot jump conditions. This analysis provides an extrapolated bulk sound speed, c{sub 0}=1.70 km s{sup -1}, for TATB and its agreement with a previous determination (c{sub 0}=1.43 km s{sup -1}) is discussed. Furthermore, our P-V and corresponding U{sub s}-u{sub p} curves reveal a subtle cusp at approximately 8 GPa. This cusp is discussed in relation to similar observations made for the aromatic hydrocarbons anthracene, benzene and toluene, graphite, and trinitrotoluene (TNT).

  18. High-pressure single-crystal X-ray diffraction of Tl{sub 2}SeO{sub 4}

    SciTech Connect (OSTI)

    Grzechnik, Andrzej [Departamento de Fisica de la Materia Condensada, Universidad del Pais Vasco, E-48080 Bilbao (Spain)], E-mail: andrzej.grzechnik@ehu.es; Breczewski, Tomasz; Friese, Karen [Departamento de Fisica de la Materia Condensada, Universidad del Pais Vasco, E-48080 Bilbao (Spain)

    2008-11-15T23:59:59.000Z

    The effect of pressure on the crystal structure of thallium selenate (Tl{sub 2}SeO{sub 4}) (Pmcn, Z=4), containing the Tl{sup +} cations with electron lone pairs, has been studied with single-crystal X-ray diffraction in a diamond anvil cell up to 3.64 GPa at room temperature. No phase transition has been observed. The compressibility data are fitted by a Murnaghan equation of state with the zero-pressure bulk modulus B{sub 0}=29(1) GPa and the unit-cell volume at ambient pressure V{sub 0}=529.6(8) A{sup 3} (B'=4.00). Tl{sub 2}SeO{sub 4} is the least compressible in the c direction, while the pressure-induced changes of the a and b lattice parameters are quite similar. These observations can be explained by different pressure effects on the nine- and 11-fold coordination polyhedra around the two non-equivalent Tl atoms. The SeO{sub 4}{sup 2-} tetrahedra are not rigid units and become more distorted. Their contribution to the compressibility is small. The effect of pressure on the isotypical oxide materials A{sub 2}TO{sub 4} with the {beta}-K{sub 2}SO{sub 4} structure is discussed. It appears that the presence of electron lone pairs on the Tl{sup +} cation does not seem to influence the compressibility of Tl{sub 2}SeO{sub 4}. - Graphical abstract: Pressure dependence of normalized lattice parameters and unit-cell volumes in Tl{sub 2}SeO{sub 4} (Pmcn, Z=4). The solid line is the Murnaghan equation of state.

  19. High-pressure behavior and thermoelastic properties of niobium studied by in situ x-ray diffraction

    SciTech Connect (OSTI)

    Zou, Yongtao, E-mail: yongtao.zou@stonybrook.edu, E-mail: yongtaozou6@gmail.com; Li, Baosheng [Mineral Physics Institute, State University of New York, Stony Brook, New York 11794 (United States); Qi, Xintong [Department of Materials Science and Engineering, State University of New York, Stony Brook, New York 11794 (United States); Wang, Xuebing; Chen, Ting [Department of Geosciences, State University of New York, Stony Brook, New York 11794 (United States); Li, Xuefei [Mineral Physics Institute, State University of New York, Stony Brook, New York 11794 (United States); Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000 (China); Welch, David [Department of Materials Science and Engineering, State University of New York, Stony Brook, New York 11794 (United States); Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973 (United States)

    2014-07-07T23:59:59.000Z

    In situ synchrotron energy dispersive x-ray diffraction (XRD) experiments on Nb have been conducted at pressures up to 6.4 GPa and temperatures up to 1073 K. From the pressure-volume-temperature measurements, thermoelastic parameters were derived for the first time for Nb based on the thermal pressure (?P{sub th}) equation of state (EOS), modified high-T Birch-Murnaghan EOS, and Mie-Grüneisen-Debye EOS. With the pressure derivative of the bulk modulus K{sub T}{sup ´} fixed at 4.0, we obtained the ambient isothermal bulk modulus K{sub T0}=174(5) GPa, the temperature derivative of bulk modulus at constant pressure (?K{sub T}/?T){sub P}=-0.060(8) GPa K?¹ and at constant volume (?K{sub T}/?T){sub V}=-0.046(8) GPa K?¹, the volumetric thermal expansivity ?{sub T}(T)=2.3(3)×10??+0.3(2)×10??T (K?¹), as well as the pressure dependence of thermal expansion (??/?P){sub T}=(?2.0±0.4)×10?? K?¹ GPa?¹. Fitting the present data to the Mie-Grüneisen-Debye EOS with Debye temperature ??=276.6 K gives ??=1.27(8) and K{sub T0}=171(3) GPa at a fixed value of q=3.0. The ambient isothermal bulk modulus and Grüneisen parameter derived from this work are comparable to previously reported values from both experimental and theoretical studies. An in situ high-resolution, angle dispersive XRD study on Nb did not indicate any anomalous behavior related to pressure-induced electronic topological transitions at ~5 GPa as has been reported previously.

  20. Phases of underpotentially deposited Hg on Au(111): An in situ surface X-ray diffraction study

    SciTech Connect (OSTI)

    Li, J.; Abruna, H.D. [Cornell Univ., Ithaca, NY (United States)] [Cornell Univ., Ithaca, NY (United States)

    1997-04-10T23:59:59.000Z

    We report on an in situ surface X-ray diffraction study of the underpotential deposition (UPD) of mercury on Au(111). We have observed three UPD phases present at potentials prior to bulk mercury deposition. These phases consist of two well-ordered intermediate states and what appears to be either a fully discharged two-dimensional liquid Hg layer or a monolayer of an amorphous Hg-Au alloy. Both ordered intermediate phases have hexagonal structures with lattice vectors that are rotated 30{degree} from those of the Au(111) substrate. The first phase (phase I), present at a potential of +0.68 V, was only observed on fresh flame-annealed Au(111) electrodes and appears to be an open incommensurate structure with a lattice constant of 3.86 {+-} 0.03 A. This phase appears to be metastable since it changes to a second ordered phase (phase II) after a certain time. The second phase has a more compact lattice with a = 3.34 {+-} 0.01 A and appears to be a commensurate 2x2 structure with 2/3 of the Hg atoms at threefold hollow sites and 1/3 on atop sites. Similar to the first one, this phase is also metastable and can be transformed to a final, fully discharged, state of a two-dimensional liquid Hg layer or an amorphous Hg-Au alloy. The entire Hg UPD process, from Hg{sup 2+} to the fully discharged metallic Hg layer, agrees well with a multistep mechanism based on previous electrochemical kinetic studies on polycrystalline Au electrodes. 31 refs., 10 figs., 2 tabs.

  1. The growth of epitaxial iron oxides on platinum (111) as studied by X-ray photoelectron diffraction, scanning tunneling microscopy, and low energy electron diffraction

    SciTech Connect (OSTI)

    Kim, Y.J.

    1995-05-01T23:59:59.000Z

    Three complementary surface structure probes, x-ray photoelectron diffraction (XPD), scanning tunneling microscopy (STM), and low-energy electron diffraction (LEED) have been combined in a single instrument. This experimental system has been utilized to study the structure and growth mechanisms of iron oxide films on Pt(111); these films were formed by first depositing a single overlayer of Fe with a certain coverage in monolayers (ML`s), and then thermally oxidizing it in an oxygen atmosphere. For films up to {approximately}1 ML in thickness, a bilayer of Fe and O similar to those in FeO(111) is found to form. In agreement with prior studies, STM and LEED show this to be an incommensurate oxide film forming a lateral superlattice with short- and long-range periodicities of {approximately}3.1 {Angstrom} and {approximately}26.0 {Angstrom}. XPD in addition shows a topmost oxygen layer to be relaxed inward by -0.6 {Angstrom} compared to bulk FeO(111), and these are new structural conclusions. The oxygen stacking in the FeO(111) bilayer is dominated by one of two possible binding sites. For thicker iron oxide films from 1.25 ML to 3.0 ML, the growth mode is essentially Stranski-Krastanov: iron oxide islands form on top of the FeO(111) bilayer mentioned above. For iron oxide films of 3.0 ML thickness, x-ray photoelectron spectroscopy (XPS) yields an Fe 2p{sub 3/2} binding energy and an Fe:O stoichiometry consistent with the presence of Fe{sub 3}O{sub 4}. Our XPD data further prove this overlayer to be Fe{sub 3}O{sub 4}(111)-magnetite in two almost equally populated domains with a 180{degrees} rotation between them. The structural parameters for this Fe{sub 3}O{sub 4} overlayer generally agree with those of a previous LEED study, except that we find a significant difference in the first Fe-O interplanar spacing. This work demonstrates the considerable benefits to be derived by using this set of complementary surface structure probes in such epitaxial growth studies.

  2. Aerosol Imaging with a Soft X-ray Free Electron Laser

    SciTech Connect (OSTI)

    Bogan, Michael J.; /SLAC /LLNL, Livermore; Boutet, Sebastien; /SLAC; Chapman, Henry N.; /DESY /Hamburg U.; Marchesini, Stefano; /LBL, Berkeley; Barty, Anton; Benner, W.Henry /LLNL, Livermore; Rohner, Urs; /LLNL, Livermore /TOFWERK AG; Frank, Matthias; Hau-Riege, Stefan P.; /LLNL, Livermore; Bajt, Sasa; /DESY; Woods, Bruce; /LLNL, Livermore; Seibert, M.M.; Iwan, Bianca; Timneanu, Nicusor; Hajdu, Janos; /Uppsala U.; Schulz, Joachim; /DESY

    2011-08-22T23:59:59.000Z

    Lasers have long played a critical role in the advancement of aerosol science. A new regime of ultrafast laser technology has recently be realized, the world's first soft xray free electron laser. The Free electron LASer in Hamburg, FLASH, user facility produces a steady source of 10 femtosecond pulses of 7-32 nm x-rays with 10{sub 12} photons per pulse. The high brightness, short wavelength, and high repetition rate (>500 pulses per second) of this laser offers unique capabilities for aerosol characterization. Here we use FLASH to perform the highest resolution imaging of single PM2.5 aerosol particles in flight to date. We resolve to 35 nm the morphology of fibrous and aggregated spherical carbonaceous nanoparticles that existed for less than two milliseconds in vacuum. Our result opens the possibility for high spatialand time-resolved single particle aerosol dynamics studies, filling a critical technological need in aerosol science.

  3. Maximum Entropy Method and Charge Flipping, a Powerful Combination to Visualize the True Nature of Structural Disorder from in situ X-ray Powder Diffraction Data

    SciTech Connect (OSTI)

    Samy, A.; Dinnebier, R; van Smaalen, S; Jansen, M

    2010-01-01T23:59:59.000Z

    In a systematic approach, the ability of the Maximum Entropy Method (MEM) to reconstruct the most probable electron density of highly disordered crystal structures from X-ray powder diffraction data was evaluated. As a case study, the ambient temperature crystal structures of disordered {alpha}-Rb{sub 2}[C{sub 2}O{sub 4}] and {alpha}-Rb{sub 2}[CO{sub 3}] and ordered {delta}-K{sub 2}[C{sub 2}O{sub 4}] were investigated in detail with the aim of revealing the 'true' nature of the apparent disorder. Different combinations of F (based on phased structure factors) and G constraints (based on structure-factor amplitudes) from different sources were applied in MEM calculations. In particular, a new combination of the MEM with the recently developed charge-flipping algorithm with histogram matching for powder diffraction data (pCF) was successfully introduced to avoid the inevitable bias of the phases of the structure-factor amplitudes by the Rietveld model. Completely ab initio electron-density distributions have been obtained with the MEM applied to a combination of structure-factor amplitudes from Le Bail fits with phases derived from pCF. All features of the crystal structures, in particular the disorder of the oxalate and carbonate anions, and the displacements of the cations, are clearly obtained. This approach bears the potential of a fast method of electron-density determination, even for highly disordered materials. All the MEM maps obtained in this work were compared with the MEM map derived from the best Rietveld refined model. In general, the phased observed structure factors obtained from Rietveld refinement (applying F and G constraints) were found to give the closest description of the experimental data and thus lead to the most accurate image of the actual disorder.

  4. 3D Imaging of Nickel Oxidation States using Full Field X-ray Absorption Near Edge Structure Nanotomography

    SciTech Connect (OSTI)

    Nelson, George; Harris, William; Izzo, John; Grew, Kyle N. (Connecticut); (USARL)

    2012-01-20T23:59:59.000Z

    Reduction-oxidation (redox) cycling of the nickel electrocatalyst phase in the solid oxide fuel cell (SOFC) anode can lead to performance degradation and cell failure. A greater understanding of nickel redox mechanisms at the microstructural level is vital to future SOFC development. Transmission x-ray microscopy (TXM) provides several key techniques for exploring oxidation states within SOFC electrode microstructure. Specifically, x-ray nanotomography and x-ray absorption near edge structure (XANES) spectroscopy have been applied to study samples of varying nickel (Ni) and nickel oxide (NiO) compositions. The imaged samples are treated as mock SOFC anodes containing distinct regions of the materials in question. XANES spectra presented for the individual materials provide a basis for the further processing and analysis of mixed samples. Images of composite samples obtained are segmented, and the distinct nickel and nickel oxide phases are uniquely identified using full field XANES spectroscopy. Applications to SOFC analysis are discussed.

  5. Simultaneous High-Resolution 2-Dimensional Spatial and 1-Dimensional Picosecond Streaked X-ray Pinhole Imaging

    SciTech Connect (OSTI)

    Steel, A B; Nagel, S R; Dunn, J; Baldis, H A

    2012-05-03T23:59:59.000Z

    A Kentech x-ray streak camera was run at the LLNL Compact Multipulse Terawatt (COMET) laser to record simultaneous space- and time-resolved measurements of picosecond laser-produced plasmas. Four different x-ray energy channels were monitored using broad-band filters to record the time history of Cu targets heated at irradiances of 10{sup 16} - 10{sup 19} W/cm{sup 2}. Through the Cu filter channel, a time-resolution below 3ps was obtained. Additionally, an array of 10 {micro}m diameter pinholes was placed in front of the camera to produce multiple time-resolved x-ray images on the photocathode and time-integrated images on the phosphor with 10 and 15 times magnification, respectively, with spatial resolution of <13 {micro}m.

  6. Performance assessment of CsI(Tl) screens on various substrates for X-ray imaging

    E-Print Network [OSTI]

    Feng, Zhaodong; Zhang, Hongkai; Zhao, Bozhen; Qin, Xiubo; Wei, Cunfeng; Liu, Yu; Wei, Long

    2015-01-01T23:59:59.000Z

    Thallium-doped cesium iodide (CsI(Tl)) screens are widely used in X-ray imaging devices because of the columnar structure of CsI(Tl) layer, but few reports focus on the optical role of the substrate in the screen system. In this paper, four substrates including fused silica (SiO2), silver-film coated SiO2, graphite (C) and fiber optic plate (FOP) are used to fabricate CsI(Tl) screens by thermal evaporation. Their imaging performance is evaluated by relative light output (RLO), modulation transfer function (MTF), normalized noise power spectrum (NNPS) and noise equivalent quanta (NEQ). The results reveal that although CsI(Tl) film on graphite plate yields images with the lowest light output, it presents relatively higher spatial resolution and better signal-to-noise characteristics. However, films on SiO2 plate obtain low MTF but high NNPS curves, whether or not coated with silver film. Furthermore, scintillation screens on FOP have bright images with low NNPS and high NEQ, but have the lowest MTF. By controll...

  7. X-ray diffraction and extended X-ray absorption fine structure study of epitaxial mixed ternary bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} (x = 0-2) films on Si (111)

    SciTech Connect (OSTI)

    Niu, G.; Zoellner, M. H.; Zaumseil, P. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Pouliopoulos, A. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); D'Acapito, F. [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, F. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France)

    2013-01-28T23:59:59.000Z

    Ternary single crystalline bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} films over the full stoichiometry range (x = 0-2) have been epitaxially grown on Si (111) with tailored electronic and crystallographic structure. In this work, we present a detailed study of their local atomic environment by extended X-ray absorption fine structure at both Y K and Pr L{sub III} edges, in combination with complementary high resolution x-ray diffraction measurements. The local structure exhibits systematic variations as a function of the film composition. The cation coordination in the second and third coordination shells changes with composition and is equal to the average concentration, implying that the Pr{sub x}Y{sub 2-x}O{sub 3} films are indeed fully mixed and have a local bixbyite structure with random atomic-scale ordering. A clear deviation from the virtual crystal approximation for the cation-oxygen bond lengths is detected. This demonstrates that the observed Vegard's law for the lattice variation as a function of composition is based microscopically on a more complex scheme related to local structural distortions which accommodate the different cation-oxygen bond lengths.

  8. Relationship of brain imaging with radionuclides and with x-ray computed tomography

    SciTech Connect (OSTI)

    Kuhl, D.E.

    1981-03-03T23:59:59.000Z

    Because of high sensitivity and specificity for altered local cerebral structure, x-ray computed tomography (CT) is the preferred initial diagnostic imaging study under most circumstances when cerebral disease is suspected. CT has no competitor for detecting fresh intracerebral hemorrhage. Radionuclide imaging (RN) scan is preferred when relative perfusion is to be assessed, in patients allergic to contrast media, and when an adequate CT study is not technically possible. (RN) plays an important complementary role to CT, especially for patients suspected of subacute or chronic subdura hematoma, cerebral infarction, arteriovenous malformations, meningitis, encephalitis, normal pressure hydrocephalus, or when CT findings are inconclusive. When CT is not available, RN serves as a good screening study for suspected cerebral tumor, infection, recent infarction, arteriovenous malformation, and chronic subdural hematoma. Future improvement in radionuclide imaging by means of emission composition potential. The compound plating approacl threshold for all the investigated transistors and fast neutron spectra lies within the raal. The value of the potential slightly changes with the coordinate change in this region, i.e. the charge on a collecting electrode is not practically guided up to a certain moment of time during the movement of nonequilibrium carriers.

  9. Quantitative Mapping of Structured Polymeric Systems Using Singular Value Decomposition Analysis of Soft X-ray Images

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    Quantitative Mapping of Structured Polymeric Systems Using Singular Value Decomposition Analysis of Soft X-ray Images I. N. Koprinarov, A. P. Hitchcock,* C. T. McCrory, and R. F. Childs Department of this system. The sample was studied fully hydrated in order to perform the quantitative mapping when

  10. High-resolution x-ray diffraction investigation of relaxation and dislocations in SiGe layers grown on (001), (011), and (111) Si substrates

    SciTech Connect (OSTI)

    Zhylik, A.; Benediktovich, A. [Department of Theoretical Physics, Belarusian State University, 4 Fr. Nezavisimosti Avenue, 220030 Minsk, Republic of Belarus (Belarus); Ulyanenkov, A.; Guerault, H. [Bruker AXS GmbH, Oestliche Rheinbrueckenstrasse 49, 76187 Karlsruhe (Germany); Myronov, M.; Dobbie, A.; Leadley, D. R. [Department of Physics, The University of Warwick, Coventry CV4 7AL (United Kingdom); Ulyanenkova, T. [Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany)

    2011-06-15T23:59:59.000Z

    This work presents a detailed characterization, using high-resolution x-ray diffraction, of multilayered Si{sub 1-x}Ge{sub x} heterostructures grown on (001), (011), and (111) Si substrates by reduced pressure chemical vapor deposition. Reciprocal space mapping has been used to determine both the strain and Ge concentration depth profiles within each layer of the heterostructures after initially determining the crystallographic tilt of all the layers. Both symmetric and asymmetric reciprocal space maps were measured on each sample, and the evaluation was performed simultaneously for the whole data set. The ratio of misfit to threading dislocation densities has been estimated for each individual layer based on an analysis of diffuse x-ray scattering from the defects.

  11. Center for X-Ray Optics, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-08-01T23:59:59.000Z

    This report discusses the following topics: Center for X-Ray Optics; Soft X-Ray Imaging wit Zone Plate Lenses; Biological X-Ray microscopy; Extreme Ultraviolet Lithography for Nanoelectronic Pattern Transfer; Multilayer Reflective Optics; EUV/Soft X-ray Reflectometer; Photoemission Microscopy with Reflective Optics; Spectroscopy with Soft X-Rays; Hard X-Ray Microprobe; Coronary Angiography; and Atomic Scattering Factors.

  12. Synchrotron-based imaging and tomography with hard X-rays C. Rau a,b,c,e,*, V. Crecea a,d

    E-Print Network [OSTI]

    Braun, Paul

    Synchrotron-based imaging and tomography with hard X-rays C. Rau a,b,c,e,*, V. Crecea a,d , W. Liu, 33501 Bielefeld, Germany h BESSY GmbH, Albert-Einstein-Str.15, 12489 Berlin, Germany i Department Hard X-ray imaging with synchrotron radiation is a powerful tool to study opaque materials on the micro

  13. The Focusing Optics x-ray Solar Imager: FOXSI Sam Kruckera,b, Steven Christec, Lindsay Glesenera,d, Shin-nosuke Ishikawaa, Stephen

    E-Print Network [OSTI]

    California at Berkeley, University of

    University, Furo-cho, Chikusa-ku, Nagoya 464-8601, Japan ABSTRACT The Focusing Optics x-ray Solar Imager. Today's leading solar HXR instrument, the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI, solar physics, solar flares, silicon strip detectors, grazing-incidence optics, high-energy x-ray optics

  14. Masked-backlighter technique used to simultaneously image x-ray absorption and x-ray emission from an inertial confinement fusion plasma

    SciTech Connect (OSTI)

    Marshall, F. J., E-mail: fredm@lle.rochester.edu; Radha, P. B. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

    2014-11-15T23:59:59.000Z

    A method to simultaneously image both the absorption and the self-emission of an imploding inertial confinement fusion plasma has been demonstrated on the OMEGA Laser System. The technique involves the use of a high-Z backlighter, half of which is covered with a low-Z material, and a high-speed x-ray framing camera aligned to capture images backlit by this masked backlighter. Two strips of the four-strip framing camera record images backlit by the high-Z portion of the backlighter, while the other two strips record images aligned with the low-Z portion of the backlighter. The emission from the low-Z material is effectively eliminated by a high-Z filter positioned in front of the framing camera, limiting the detected backlighter emission to that of the principal emission line of the high-Z material. As a result, half of the images are of self-emission from the plasma and the other half are of self-emission plus the backlighter. The advantage of this technique is that the self-emission simultaneous with backlighter absorption is independently measured from a nearby direction. The absorption occurs only in the high-Z backlit frames and is either spatially separated from the emission or the self-emission is suppressed by filtering, or by using a backlighter much brighter than the self-emission, or by subtraction. The masked-backlighter technique has been used on the OMEGA Laser System to simultaneously measure the emission profiles and the absorption profiles of polar-driven implosions.

  15. Hard X-ray polarimetry with Caliste, a high performance CdTe based imaging spectrometer

    E-Print Network [OSTI]

    Antier, S; Limousin, O; Caroli, E; da Silva, R M Curado; Blondel, C; Chipaux, R; Honkimaki, V; Horeau, B; Laurent, P; Maia, J M; Meuris, A; Del Sordo, S; Stephen, J B

    2015-01-01T23:59:59.000Z

    Since the initial exploration of soft gamma-ray sky in the 60's, high-energy celestial sources have been mainly characterized through imaging, spectroscopy and timing analysis. Despite tremendous progress in the field, the radiation mechanisms at work in sources such as neutrons stars and black holes are still unclear. The polarization state of the radiation is an observational parameter which brings key additional information about the physical process. This is why most of the projects for the next generation of space missions covering the tens of keV to the MeV region require a polarization measurement capability. A key element enabling this capability is a detector system allowing the identification and characterization of Compton interactions as they are the main process at play. The hard X-ray imaging spectrometer module, developed in CEA with the generic name of Caliste module, is such a detector. In this paper, we present experimental results for two types of Caliste-256 modules, one based on a CdTe cr...

  16. Attenuation Correction of L-shell X-ray Fluorescence Computed Tomography Imaging

    E-Print Network [OSTI]

    Long, Liu; Bo, Ma; Qing, Xu; Lingtong, Yan; Li, Li; Songlin, Feng; Xiangqian, Feng

    2014-01-01T23:59:59.000Z

    X-ray Fluorescence Computed Tomography(XFCT) is a prevalent experimental technique which is utilized to investigate the spatial distribution of elements in sample. The sensitivity of L-shell XFCT of some elements is lower than that of K-shell XFCT. However, the image reconstruction for this technique has much more problems than that of transmission tomography, one of which is self-absorption. In the present work, a novel strategy was developed to deal with such problems. But few researches are concerned on attenuation correction of L-shell XFCT that are essential to get accurate reconstructed image. We make use of the known quantities and the unknown elemental concentration of interest to express the unknown attenuation maps. And then the attenuation maps are added in the contribution value of the pixel in MLEM reconstruction method. Results indicate that the relative error is less than 14.1%, which is proved this method can correct L-shell XFCT very well.

  17. X-ray imaging with monochromatic and small focal spot size sources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of x-ray energy and intensity (under investigation) Measurements at the Elettra (Trieste) synchrotron Edge Response Function at ATF * Spot size * He Pipe added * 10 7 10 8...

  18. Imaging X-ray spectroscopy with micro-X and Chandra

    E-Print Network [OSTI]

    Rutherford, John (John Morton)

    2013-01-01T23:59:59.000Z

    High spectral resolution observations of X-ray phenomena have the potential to uncover new physics. Currently, only point sources can be probed with high resolution spectra, using gratings. Extended objects like supernova ...

  19. Study of strain propagation in laser irradiated silicon crystal by time-resolved diffraction of K-{alpha} x-ray probe of different photon energies

    SciTech Connect (OSTI)

    Arora, V.; Bagchi, S.; Chakera, J. A.; Naik, P. A.; Gupta, P. D. [Laser Plasma Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013 (India); Gupta, M.; Gupta, A.; Chaddah, P. [UGC-DAE Consortium for Scientific Research, University Campus, Indore 452 001 (India)

    2013-07-14T23:59:59.000Z

    An experimental study on the time resolved x-ray diffraction from laser shocked silicon crystal, carried out using a 10 TW Ti:sapphire laser system, is presented. The characteristic K{sub {alpha}} x-ray line radiation generated by 45 fs laser produced plasmas of two different target materials (iron and copper) is used as the probe, whereas the stretched pulse of sub-nanosecond duration (pump), derived from the same laser, is used to compress the sample. The use of x-ray probe of different photon energies yields information about the strain over a greater crystal depth. The dynamics of the strain propagation is inferred by monitoring the evolution of rocking curve width of the shocked sample at different time delays between the pump and the probe pulse. The shock velocity deduced from these measurements is {approx}10{sup 6} cm/s, consistent with the sound velocity in bulk silicon. The maximum elastic compression observed is 0.4%, indicating a pressure of 0.8 GPa.

  20. High-Pressure Synchtron Radiation X-Ray Diffraction Studies of Pentaerythritol Tetranitrate C(CH[subscript 2]ONO[subscript 2 ])[subscript 4

    SciTech Connect (OSTI)

    Lipinska-Kalita, K.E.; Pravica, M.; Nicol, M. (UNLV)

    2006-02-02T23:59:59.000Z

    A high-pressure x-ray diffraction study of nanocrystalline pentaerythritol tetranitrate, C(CH{sub 2}ONO{sub 2}){sub 4}, (PETN), has been performed in a diamond-anvil cell at ambient temperature using synchrotron radiation. Pressure-induced alterations in the profiles of the diffraction lines, including their positions, widths and intensities were followed up to 30 GPa in a compressino cycle. The spectral changes in the diffraction patterns at low pressures indicated continuous densification of the tetragonal structure (space group P{bar 4}2{sub 1}c). The diffraction patterns confirmed that PETN compressed from ambient pressure to 7.4 GPa by 17%. At 8.2 GPa and above, several new diffraction lines appeared in the patterns. These lines suggest that the lattice undergoes an incomplete stress-induced structural transformation from the tetragonal to an orthorhombic structure (most probably space group P2{sub 1}22{sub 1}). The mixture of both structures appeared to persist to 30 GPa. The progressive broadening of the diffraction lines as the pressure increased beyond 10 GPa is attributed to the combined diffraction lines of a mixture of two coexisting PETN phases and inhomogeneous pressure distribution within the sample.

  1. Reflection nebulae in the Galactic Center: the case for soft X-ray imaging polarimetry

    E-Print Network [OSTI]

    Marin, F; Soffitta, P; Karas, V; Kunneriath, D

    2015-01-01T23:59:59.000Z

    The origin of irradiation and fluorescence of the 6.4 keV bright giant molecular clouds surrounding Sgr A*, the central supermassive black hole of our Galaxy, remains enigmatic. Testing the theory of a past active period of Sgr A* requires X-ray polarimetry. In this paper, we show how modern imaging polarimeters could revolutionize our understanding of the Galactic Center. Through Monte Carlo modeling, we produce a 4-8 keV polarization map of the Galactic Center, focusing on the polarimetric signature produced by Sgr B1, Sgr B2, G0.11-0.11, Bridge E, Bridge D, Bridge B2, MC2, MC1, Sgr C3, Sgr C2, and Sgr C1. We estimate the resulting polarization, include polarized flux dilution by the diffuse plasma emission detected toward the GC, and simulate the polarization map that modern polarimetric detectors would obtain assuming the performances of a mission prototype. The eleven reflection nebulae investigated in this paper present a variety of polarization signatures, ranging from nearly unpolarized to highly pola...

  2. Concept to diagnose mix with imaging x-ray Thomson scattering

    SciTech Connect (OSTI)

    Keiter, Paul A.; Gamboa, Eliseo J.; Huntington, Channing M.; Kuranz, Carolyn C. [Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, Ann Arbor, Michigan 48103 (United States)

    2012-10-15T23:59:59.000Z

    Turbulent mixing of two fluid species is a ubiquitous problem, prevalent in systems such as inertial confinement fusion (ICF) capsule implosions, supernova remnants, and other astrophysical systems. In complex, high Reynolds number compressible high energy density (HED) flows such as these, hydrodynamic instabilities initiate the turbulent mixing process, which can then feedback and alter the mean hydrodynamic motion through nonlinear processes. In order to predict how these systems evolve under turbulent conditions, models are used. However, these models require detailed quantitative data to validate and constrain their detailed physics models as well as improve them. Providing this much needed data is currently at the forefront of HED research but is proving elusive due to a lack of available diagnostics capable of directly measuring detailed flow variables. Thomson scattering is a promising technique in this regard as it provides fundamental conditions of the flow ({rho}, T, Zbar) due to its direct interaction with the small scales of the fluid or plasma and was recently considered as a possible mix diagnostic. With the development of imaging x-ray Thomson scattering (IXRTS) obtaining spatial profiles of these variables is within reach. We propose a novel use of the IXRTS technique that will provide more detailed quantitative data required for model validation in mix experiments.

  3. Upgrades of the high resolution imaging x-ray crystal spectrometers on experimental advanced superconducting tokamak

    SciTech Connect (OSTI)

    Lu, B.; Wang, F.; Fu, J.; Li, Y.; Wan, B. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui (China); Shi, Y. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui (China); National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon (Korea, Republic of); Bitter, M.; Hill, K. W. [Princeton Plasma Physics Laboratory, MS37-B332, Princeton, New Jersey 08543-0451 (United States); Lee, S. G. [National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    Two imaging x-ray crystal spectrometers, the so-called 'poloidal' and 'tangential' spectrometers, were recently implemented on experimental advanced superconducting tokamak (EAST) to provide spatially and temporally resolved impurity ion temperature (T{sub i}), electron temperature (T{sub e}) and rotation velocity profiles. They are derived from Doppler width of W line for Ti, the intensity ratio of Li-like satellites to W line for Te, and Doppler shift of W line for rotation. Each spectrometer originally consisted of a spherically curved crystal and a two-dimensional multi-wire proportional counter (MWPC) detector. Both spectrometers have now been upgraded. The layout of the tangential spectrometer was modified, since it had to be moved to a different port, and the spectrometer was equipped with two high count rate Pilatus detectors (Model 100 K) to overcome the count rate limitation of the MWPC and to improve its time resolution. The poloidal spectrometer was equipped with two spherically bent crystals to record the spectra of He-like and H-like argon simultaneously and side by side on the original MWPC. These upgrades are described, and new results from the latest EAST experimental campaign are presented.

  4. X-ray diffraction study of the binding of the antisickling agent 12C79 to human hemoglobin

    SciTech Connect (OSTI)

    Wireko, R.C.; Abraham, D.J. (Virginia Commonwealth Univ., Richmond (United States))

    1991-03-15T23:59:59.000Z

    The hemoglobin binding site of the antisickling agent 12C79 has been determined by x-ray crystallography. 12C79 is recognized as one of the first molecules to reach clinical trials that was designed, de novo, from x-ray-determined atomic coordinates of a protein. Several previous attempts to verify the proposed Hb binding sites via crystallographic studies have failed. Using revised experimental procedures, the authors obtained 12C79-deoxhemoglobin crystals grown after reaction with oxyhemoglobin and cyanoborohydride reduction to stabilize the Schiff base linkage. The difference electron-density Fourier maps show that two 12C79 molecules bind covalently to both symmetry-related N-terminal amino groups of the hemoglobin {alpha} chains. This is in contrast to the original design that proposed the binding of one drug molecule that spans the molecular dyad to interact with both N-terminal {alpha}-amino groups.

  5. Hard X-ray polarimetry with Caliste, a high performance CdTe based imaging spectrometer

    E-Print Network [OSTI]

    S. Antier; P. Ferrando; O. Limousin; E. Caroli; R. M. Curado da Silva; C. Blondel; R. Chipaux; V. Honkimaki; B. Horeau; P. Laurent; J. M. Maia; A. Meuris; S. Del Sordo; J. B. Stephen

    2015-05-05T23:59:59.000Z

    Since the initial exploration of soft gamma-ray sky in the 60's, high-energy celestial sources have been mainly characterized through imaging, spectroscopy and timing analysis. Despite tremendous progress in the field, the radiation mechanisms at work in sources such as neutrons stars and black holes are still unclear. The polarization state of the radiation is an observational parameter which brings key additional information about the physical process. This is why most of the projects for the next generation of space missions covering the tens of keV to the MeV region require a polarization measurement capability. A key element enabling this capability is a detector system allowing the identification and characterization of Compton interactions as they are the main process at play. The hard X-ray imaging spectrometer module, developed in CEA with the generic name of Caliste module, is such a detector. In this paper, we present experimental results for two types of Caliste-256 modules, one based on a CdTe crystal, the other one on a CdZnTe crystal, which have been exposed to linearly polarized beams at the European Synchrotron Radiation Facility. These results, obtained at 200-300 keV, demonstrate their capability to give an accurate determination of the polarization parameters (polarization angle and fraction) of the incoming beam. Applying a selection to our data set, equivalent to select 90 degrees Compton scattered interactions in the detector plane, we find a modulation factor Q of 0.78. The polarization angle and fraction are derived with accuracies of approximately 1 degree and 5%. The modulation factor remains larger than 0.4 when essentially no selection is made at all on the data. These results prove that the Caliste-256 modules have performances allowing them to be excellent candidates as detectors with polarimetric capabilities, in particular for future space missions.

  6. Pressurized subsampling system for pressured gas-hydrate-bearing sediment: Microscale imaging using X-ray computed tomography

    SciTech Connect (OSTI)

    Jin, Yusuke, E-mail: u-jin@aist.go.jp; Konno, Yoshihiro; Nagao, Jiro [Production Technology Team, Methane Hydrate Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Sapporo 062-8517 (Japan)

    2014-09-01T23:59:59.000Z

    A pressurized subsampling system was developed for pressured gas hydrate (GH)-bearing sediments, which have been stored under pressure. The system subsamples small amounts of GH sediments from cores (approximately 50 mm in diameter and 300 mm in height) without pressure release to atmospheric conditions. The maximum size of the subsamples is 12.5 mm in diameter and 20 mm in height. Moreover, our system transfers the subsample into a pressure vessel, and seals the pressure vessel by screwing in a plug under hydraulic pressure conditions. In this study, we demonstrated pressurized subsampling from artificial xenon-hydrate sediments and nondestructive microscale imaging of the subsample, using a microfocus X-ray computed tomography (CT) system. In addition, we estimated porosity and hydrate saturation from two-dimensional X-ray CT images of the subsamples.

  7. Time resolved, 2-D hard X-ray imaging of relativistic electron-beam target interactions on ETA-II

    SciTech Connect (OSTI)

    Crist, C.E. [Sandia National Labs., Albuquerque, NM (United States); Sampayan, S.; Westenskow, G.; Caporaso, G.; Houck, T.; Weir, J.; Trimble, D. [Lawrence Livermore National Lab., CA (United States); Krogh, M. [AlliedSignal FM and T, Kansas City, MO (United States)

    1998-11-01T23:59:59.000Z

    Advanced radiographic applications require a constant source size less than 1 mm. To study the time history of a relativistic electron beam as it interacts with a bremsstrahlung converter, one of the diagnostics they use is a multi-frame time-resolved hard x-ray camera. They are performing experiments on the ETA-II accelerator at Lawrence Livermore National Laboratory to investigate details of the electron beam/converter interactions. The camera they are using contains 6 time-resolved images, each image is a 5 ns frame. By starting each successive frame 10 ns after the previous frame, they create a 6-frame movie from the hard x-rays produced from the interaction of the 50-ns electron beam pulse.

  8. Relationship between dislocations and residual stresses in cold-drawn pearlitic steel analyzed by energy-dispersive X-ray diffraction

    SciTech Connect (OSTI)

    Sato, Shigeo, E-mail: s.sato@imr.tohoku.ac.jp [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Wagatsuma, Kazuaki [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Suzuki, Shigeru [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan); Kumagai, Masayoshi; Imafuku, Muneyuki [Faculty of Engineering, Tokyo City University, Tokyo 158-8557 (Japan); Tashiro, Hitoshi [Gyoda 361-0011 (Japan); Kajiwara, Kentaro [Japan Synchrotron Radiation Research Institute, Sayo 679-5198 (Japan); Shobu, Takahiasa [Japan Atomic Energy Agency, Sayo 679-5184 (Japan)

    2013-09-15T23:59:59.000Z

    We analyzed the dislocation distribution of cold-drawn pearlitic-steel wire by using the line-profile analysis based on the energy dispersive X-ray diffraction (EDXD). Although this line-profile analysis requires a high resolution in reciprocal space, the resolution for EDXD is generally poor due to the energy resolution of the detector. Our analysis demonstrated that the resolution in the reciprocal space can be maximized at small scattering angles. Using the line-profile analysis based on the EDXD, the microstructural parameters such as the crystallite size and the dislocation density of the ferrite phase in the pearlitic steel were successfully analyzed. In addition, the distribution of the residual stress of the ferrite phase of a pearlitic steel wire was also analyzed using the EDXD measurement. - Highlights: • Energy dispersive X-ray diffraction is applied to the line-profile analysis. • Distribution of dislocations in ferrite in the pearlitic steel wire is analyzed. • Relationship between dislocations and residual stress is discussed.

  9. In situ apparatus for the study of clathrate hydrates relevant to solar system bodies using synchrotron X-ray diffraction and Raman spectroscopy

    E-Print Network [OSTI]

    Day, Sarah J; Evans, Aneurin; Parker, Julia E

    2015-01-01T23:59:59.000Z

    Clathrate hydrates are believed to play a significant role in various solar system environments, e.g. comets, and the surfaces and interiors of icy satellites, however the structural factors governing their formation and dissociation are poorly understood. We demonstrate the use of a high pressure gas cell, combined with variable temperature cooling and time-resolved data collection, to the in situ study of clathrate hydrates under conditions relevant to solar system environments. Clathrates formed and processed within the cell are monitored in situ using synchrotron X-ray powder diffraction and Raman spectroscopy. X-ray diffraction allows the formation of clathrate hydrates to be observed as CO2 gas is applied to ice formed within the cell. Complete conversion is obtained by annealing at temperatures just below the ice melting point. A subsequent rise in the quantity of clathrate is observed as the cell is thermally cycled. Four regions between 100-5000cm-1 are present in the Raman spectra that carry feature...

  10. Imaging of high-energy x-ray emission from cryogenic thermonuclear fuel implosions on the NIF

    SciTech Connect (OSTI)

    Ma, T.; Izumi, N.; Tommasini, R.; Bradley, D. K.; Bell, P.; Cerjan, C. J.; Dixit, S.; Doeppner, T.; Jones, O.; Landen, O. L.; LePape, S.; Mackinnon, A. J.; Park, H.-S.; Patel, P. K.; Prasad, R. R.; Ralph, J.; Smalyuk, V. A.; Springer, P. T.; Suter, L.; Town, R. P. J. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); and others

    2012-10-15T23:59:59.000Z

    Accurately assessing and optimizing the implosion performance of inertial confinement fusion capsules is a crucial step to achieving ignition on the NIF. We have applied differential filtering (matched Ross filter pairs) to provide broadband time-integrated absolute x-ray self-emission images of the imploded core of cryogenic layered implosions. This diagnostic measures the temperature- and density-sensitive bremsstrahlung emission and provides estimates of hot spot mass, mix mass, and pressure.

  11. Distribution of unresolvable anisotropic microstructures revealed in visibility-contrast images using x-ray Talbot interferometry

    SciTech Connect (OSTI)

    Yashiro, Wataru; Harasse, Sebastien; Kawabata, Katsuyuki; Kuwabara, Hiroaki; Yamazaki, Takashi; Momose, Atsushi [Department of Advanced Materials Science, Graduate School of Frontier Sciences, the University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan)

    2011-09-01T23:59:59.000Z

    X-ray Talbot interferometry has been widely used as a technique for x-ray phase imaging and tomography. We propose a method using this interferometry for mapping distribution of parameters characterizing anisotropic microstructures, which are typically of the order of {mu}m in size and cannot be resolved by the imaging system, in a sample. The method uses reduction in fringe visibility, which is caused by such unresolvable microstructures, in moire images obtained using an interferometer. We applied the method to a chloroprene rubber sponge sample, which exhibited uniaxial anisotropy of reduced visibility. We measured the dependencies of reduced visibility on both the Talbot order and the orientation of the sample and obtained maps of three parameters and their anisotropies that characterize the unresolvable anisotropic microstructures in the sample. The maps indicated that the anisotropy of the sample's visibility contrast mainly originated from the anisotropy of the microstructure elements' average size. Our method directly provides structural information on unresolvable microstructures in real space, which is only accessible through the ultra-small-angle x-ray scattering measurements in reciprocal space, and is expected to be broadly applied to material, biological, and medical sciences.

  12. Application of Image And X-Ray Microtomography Technique To Quantify Filler Distribution In Thermoplastic-Natural Rubber Blend Composites

    SciTech Connect (OSTI)

    Ahmad, Sahrim; Rasid, Rozaidi; Mouad, A. T. [Faculty of Applied Science and Technology, Universiti Kebangsaan Malaysia (UKM), Bandar Baru Bangi, 43000 Kajang (Malaysia); Aziz Mohamed, A.; Abdullah, Jaafar; Dahlan, M.; Mohamad, Mahathir; Jamro, Rafhayudi; Hamzah Harun, M. [Malaysian Nuclear Agency, Bangi, 43000 Kajang (Malaysia); Yazid, Hafizal [Faculty of Applied Science and Technology, Universiti Kebangsaan Malaysia (UKM), Bandar Baru Bangi, 43000 Kajang (Malaysia); Hafizal Yazid, Faculty of Applied Science and Technology, Universiti Kebangsaan Malaysia (UKM), Bandar Baru Bangi, 43000 Kajang (Malaysia); Abdullah, W. Saffiey W.

    2010-01-05T23:59:59.000Z

    X-ray microtomography and ImageJ 1.39 u is used as a tool to quantify volume percentage of B{sub 4}C as fillers in thermoplastic-natural rubber blend composites. The use of percentage of area occupied by fillers as obtain from ImageJ from the microtomography sliced images enables the proposed technique to easily obtain the amount volume percentage of B{sub 4}C in the composite non-destructively. Comparison with other technique such as density measurement and chemical analysis proves the proposed technique as one of the promising approach.

  13. X-Ray Imaging Current-Driven Magnetic Domain-Wall Motion in Nanowires

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-Ray DiagnosticsX-Ray

  14. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat isJoin theanniversaryI 1 0 3 P 0 d dX-RayX-Ray

  15. High-resolution chemical imaging of gold nanoparticles using hard x-ray ptychography

    SciTech Connect (OSTI)

    Hoppe, R.; Patommel, J.; Schroer, C. G. [Institute of Structural Physics, Technische Universitaet Dresden, D-01062 Dresden (Germany)] [Institute of Structural Physics, Technische Universitaet Dresden, D-01062 Dresden (Germany); Reinhardt, J. [Institute of Structural Physics, Technische Universitaet Dresden, D-01062 Dresden (Germany) [Institute of Structural Physics, Technische Universitaet Dresden, D-01062 Dresden (Germany); Deutsches Elektronen-Synchrotron DESY, D-22607 Hamburg (Germany)] [Germany; Hofmann, G.; Grunwaldt, J.-D. [Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology, D-76131 Karlsruhe (Germany)] [Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology, D-76131 Karlsruhe (Germany); Damsgaard, C. D. [Center for Electron Nanoscopy and Department of Physics, Technical University of Denmark, DK-2800 Lyngby (Denmark)] [Center for Electron Nanoscopy and Department of Physics, Technical University of Denmark, DK-2800 Lyngby (Denmark); Wellenreuther, G.; Falkenberg, G. [Deutsches Elektronen-Synchrotron DESY, D-22607 Hamburg (Germany)] [Deutsches Elektronen-Synchrotron DESY, D-22607 Hamburg (Germany)

    2013-05-20T23:59:59.000Z

    We combine resonant scattering with (ptychographic) scanning coherent diffraction microscopy to determine the chemical state of gold nanoparticles with high spatial resolution. Ptychographic images of the sample are recorded for a series of energies around the gold L{sub 3} absorption edge. From these data, chemical information in the form of absorption and resonant scattering spectra is reconstructed at each location in the sample. For gold nanoparticles of about 100 nm diameter, a spatial resolution of about 20-30 nm is obtained. In the future, this microscopy approach will open the way to operando studies of heterogeneous catalysts on the nanometer scale.

  16. Imaging single cells in a beam of live cyanobacteria with an X-ray laser

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schot, Gijs, vander

    Diffraction pattern of a micron-sized S. elongatus cell at 1,100 eV photon energy (1.13 nm wavelength) with ~10^11 photons per square micron on the sample in ~70 fs. The signal to noise ratio at 4 nm resolution is 3.7 with 0.24 photons per Nyquist pixel. The cell was alive at the time of the exposure. The central region of the pattern (dark red) is saturated and this prevented reliable image reconstruction.

  17. Mapping the Ionization State of Laser-Irradiated Ar Gas Jets With Multi-Wavelength Monochromatic X-Ray Imaging

    SciTech Connect (OSTI)

    Kugland, N L; Doppner, T; Kemp, A; Schaeffer, D; Glenzer, S H; Niemann, C

    2010-04-08T23:59:59.000Z

    Two-dimensional monochromatic images of fast-electron stimulated Ar K{alpha} and He-{alpha} x-ray self-emission have recorded a time-integrated map of the extent of Ar{sup {approx}6+} and Ar{sup 16+} ions, respectively, within a high density (10{sup 20} cm{sup -3} atomic density) Ar plasma. This plasma was produced by irradiating a 2 mm wide clustering Ar gas jet with an ultra-high intensity (10{sup 19} W/cm{sup 2}, 200 fs) Ti:Sapphire laser operating at 800 nm. Spherically bent quartz crystals in the 200 (for K{alpha}) and 201 (for He-{alpha}) planes were used as near-normal incidence reflective x-ray optics. We see that a large (830 {micro}m long) region of plasma emits K{alpha} primarily along the laser axis, while the He-{alpha} emission is confined to smaller hot spot (230 {micro}m long) region that likely corresponds to the focal volume of the f/8 laser beam. X-ray spectra from a Bragg spectrometer operating in the von Hamos geometry, which images in one dimension, indicate that the centroids of the K{alpha} and He-{alpha} emission regions are separated by approximately 330 {micro}m along the laser axis.

  18. Fundamental x-ray interaction limits in diagnostic imaging detectors: Spatial resolution

    E-Print Network [OSTI]

    Cunningham, Ian

    , London, Ontario N6A 5K8, Canada, Departments of Diagnostic Radiology and Nuclear Medicine, London Health transformed with the emergence of digital detector technology. Although digital systems offer many practical of future digital x-ray detectors. © 2008 American Association of Physicists in Medicine. DOI: 10

  19. Upgrades of imaging x-ray crystal spectrometers for high-resolution and high-temperature plasma diagnostics on EAST

    SciTech Connect (OSTI)

    Lyu, B., E-mail: blu@ipp.ac.cn; Wang, F. D.; Fu, J.; Li, Y. Y. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui 230031 (China); Pan, X. Y.; Chen, J.; Wan, B. N. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui 230031 (China); School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026 (China); Bitter, M.; Hill, K. W.; Delgado-Aparicio, L. F.; Pablant, N. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, New Jersey 08543-0451 (United States); Lee, S. G. [National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon 305-333 (Korea, Republic of); Shi, Y. J. [School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026 (China); WCI for Fusion Theory, National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon 305-333 (Korea, Republic of); Ye, M. Y. [School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2014-11-15T23:59:59.000Z

    Upgrade of the imaging X-ray crystal spectrometers continues in order to fulfill the high-performance diagnostics requirements on EAST. For the tangential spectrometer, a new large pixelated two-dimensional detector was deployed on tokamaks for time-resolved X-ray imaging. This vacuum-compatible detector has an area of 83.8 × 325.3 mm{sup 2}, a framing rate over 150 Hz, and water-cooling capability for long-pulse discharges. To effectively extend the temperature limit, a double-crystal assembly was designed to replace the previous single crystals for He-like argon line measurement. The tangential spectrometer employed two crystal slices attached to a common substrate and part of He- and H-like Ar spectra could be recorded on the same detector when crystals were chosen to have similar Bragg angles. This setup cannot only extend the measurable Te up to 10 keV in the core region, but also extend the spatial coverage since He-like argon ions will be present in the outer plasma region. Similarly, crystal slices for He-like iron and argon spectra were adopted on the poloidal spectrometer. Wavelength calibration for absolute rotation velocity measurement will be studied using cadmium characteristic L-shell X-ray lines excited by plasma radiation. A Cd foil is placed before the crystal and can be inserted and retracted for in situ wavelength calibration. The Geant4 code was used to estimate X-ray fluorescence yield and optimize the thickness of the foil.

  20. Coadsorption of sulfate/bisulfate anions with Hg cations during Hg underpotential deposition on Au(111): An in situ x-ray diffraction study

    SciTech Connect (OSTI)

    Li, J.; Abruna, H.D. [Cornell Univ., Ithaca, NY (United States)] [Cornell Univ., Ithaca, NY (United States)

    1997-01-09T23:59:59.000Z

    The first stage of mercury underpotential deposition on Au(111) electrodes in 0.10 M H{sub 2}SO{sub 4} containing 1.0 mM Hg{sup 2+} has been studied by synchrotron X-ray scattering techniques including grazing incidence X-ray diffraction and specular crystal truncation rod measurements. An ordered coadsorbed structure of sulfate/bisulfate anions and Hg cations was found at potentials between the first and second Hg UPD peaks (+0.80 V > E > +0.88 V vs Ag/AgCl(3 M KCl)). The coadsorption structure was found to consist of a compressed Hg honeycomb lattice with the honeycomb centers occupied by sulfate or bisulfate anions. The compression of the lattice is likely due to the formation of mercurous (Hg{sub 2}{sup 2+}) ions which have a much shorter Hg-Hg distance than that in frozen bulk Hg crystals. The net charge transferred under the first Hg UPD peak suggests that the chemical state of the species in the coadsorbed structure is likely Hg{sub 2}SO{sub 4}. Our results indicate that both the chemical state of the mercury cations and the nature of the anions are important in the resulting electrodeposited structures. 38 refs., 8 figs., 1 tab.

  1. The process of data formation for the Spectrometer/Telescope for Imaging X-rays (STIX) in Solar Orbiter

    E-Print Network [OSTI]

    Giordano, Sara; Piana, Michele; Massone, Anna Maria

    2014-01-01T23:59:59.000Z

    The Spectrometer/Telescope for Imaging X-rays (STIX) is a hard X-ray imaging spectroscopy device to be mounted in the Solar Orbiter cluster with the aim of providing images and spectra of solar flaring regions at different photon energies in the range from a few keV to around 150 keV. The imaging modality of this telescope is based on the Moire pattern concept and utilizes 30 sub-collimators, each one containing a pair of co-axial grids. This paper applies Fourier analysis to provide the first rigorous description of the data formation process in STIX. Specifically, we show that, under first harmonic approximation, the integrated counts measured by STIX sub-collimators can be interpreted as specific spatial Fourier components of the incoming photon flux, named visibilities. Fourier analysis also allows the quantitative assessment of the reliability of such interpretation. The description of STIX data in terms of visibilities has a notable impact on the image reconstruction process, since it fosters the applic...

  2. Fabrication of high aspect grating using bonded substrate for X-ray refraction imaging by Talbot-Lau interferometer

    SciTech Connect (OSTI)

    Tada, Takuji; Murakoshi, Dai; Ishii, Hiroyasu; Hashimoto, Atsushi; Kaneko, Yasuhisa; Ito, Wataru; Agano, Toshitaka [Medical Systems Research and Development Center, R and D Management Headquarters, FUJIFILM Corp., 798, Miyanodai, Kaisei-machi, Ashigarakami-gun, Kanagawa 258-8538 (Japan); Imaging Technology Center, R and D Management Headquarters, FUJIFILM Corp., 798, Miyanodai, Kaisei-machi, Ashigarakami-gun, Kanagawa 258-8538 (Japan)

    2012-07-31T23:59:59.000Z

    In order to improve the image quality of X-ray refraction images using a Talbot-Lau interferometer, we have been attempting to fabricate gratings with high aspect ratio. In our attempt, deep grooves of grating structure were channeled on a Si substrate bonded by Au diffusion bonding method, and the grooves were filled with Au where the Au layer used for the bonding Si substrate was acting as a seed layer of Au electroplating. From the results of a visibility measurement and a cross sectional SEM image, it was confirmed that the grooves with a pitch of 5.8 {mu}m and a depth of 100 {mu}m could be successfully filled with Au over a large area of 72 Multiplication-Sign 80 mm{sup 2}. Using this grating, the X-ray refraction images for the cartilage of a knee joint of a livestock pig could be obtained where SPS method was employed for the single-shot image acquisition.

  3. A soft x-ray transmission grating imaging-spectrometer for the National Ignition Facility

    SciTech Connect (OSTI)

    Moore, A S; Guymer, T M; Kline, J L; Morton, J; Taccetti, M; Lanier, N E; Bentley, C; Workman, J; Peterson, B; Mussack, K; Cowan, J; Prasad, R; Richardson, M; Burns, S; Kalantar, D H; Benedetti, L R; Bell, P; Bradley, D; Hsing, W; Stevenson, M

    2012-05-01T23:59:59.000Z

    A soft x-ray transmission grating spectrometer has been designed for use on high energy-density physics experiments at the National Ignition Facility (NIF); coupled to one of the NIF gated x-ray detectors (GXD) it records sixteen time-gated spectra between 250 and 1000eV with 100ps temporal resolution. The trade-off between spectral and spatial resolution leads to an optimized design for measurement of emission around the peak of a 100-300eV blackbody spectrum. Performance qualification results from the NIF, the Trident Laser Facility and VUV beamline at the National Synchrotron Light Source (NSLS), evidence a <100{micro}m spatial resolution in combination with a source-size limited spectral resolution that is <10eV at photon energies of 300eV.

  4. Vacancy-induced nanoscale phase separation in KxFe2–ySe? single crystals evidenced by Raman scattering and powder x-ray diffraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lazarevi?, N.; Abeykoon, M.; Stephens, P. W.; Lei, Hechang; Bozin, E. S.; Petrovic, C.; Popovi?, Z. V.

    2012-08-01T23:59:59.000Z

    Polarized Raman scattering spectra of KxFe2–ySe? were analyzed in terms of peculiarities of both I4/m and I4/mmm space group symmetries. The presence of the Raman active modes from both space group symmetries (16 Raman-active modes of the I4/m phase and two Raman-active modes of the I4/mmm phase) confirmed the existence of two crystallographic domains with different space group symmetry in a KxFe2–ySe? sample. High-resolution synchrotron powder x-ray diffraction structural refinement of the same sample confirmed the two-phase description, and determined the atomic positions and occupancies for both domains.

  5. Identification of an incommensurate FeAl{sub 2} overlayer on FeAl(110) using x-ray diffraction and reflectivity

    SciTech Connect (OSTI)

    Baddorf, A.P. [Oak Ridge National Lab., TN (United States); Chandavarkar, S.S. [Tennessee Univ., Knoxville, TN (United States). Dept. of Physics and Astronomy

    1995-06-30T23:59:59.000Z

    FeAl, like NiAl, crystallizes in the CsCl structure. Consequently the (110) planes contain equal amounts of Fe and Al distributed as interlocking rectangles. Unlike the NiAI(110) surface, which retains the (1{times}l) in-plane symmetry of the bulk, FeAl(l10) reconstructs to form an ordered, incommensurate overlayer. The reconstructed layer introduces x-ray diffraction rods at half-order positions along the [1{bar 1}0] direction, and displaced {plus_minus}0.2905 from integer positions along the [001] direction. Peak widths reveal excellent long range order. Specular reflectivity measurements above and below the Fe K{alpha} edge can be reproduced using a model containing a single reconstructed overlayer with an Fe:Al ratio of 1:2, consistent with FeA{sub I}2.

  6. New Insights into the Relationship Between Network Structure and Strain Induced Crystallization in Unvolcanized Natural Rubber by Synchrotron X-ray Diffraction

    SciTech Connect (OSTI)

    Toki, S.; Hsiao, B; Amnuaypornsri, S; Sakdapipanich, J

    2009-01-01T23:59:59.000Z

    The relationship between the network structure and strain-induced crystallization in un-vulcanized as well as vulcanized natural rubbers (NR) and synthetic poly-isoprene rubbers (IR) was investigated via synchrotron wide-angle X-ray diffraction (WAXD) technique. It was found that the presence of a naturally occurring network structure formed by natural components in un-vulcanized NR significantly facilitates strain-induced crystallization and enhances modulus and tensile strength. The stress-strain relation in vulcanized NR is due to the combined effect of chemical and naturally occurring networks. The weakness of naturally occurring network against stress and temperature suggests that vulcanized NR has additional relaxation mechanism due to naturally occurring network. The superior mechanical properties in NR compared with IR are mainly due to the existence of naturally occurring network structure.

  7. X-ray ?-Laue diffraction analysis of Cu through-silicon vias: A two-dimensional and three-dimensional study

    SciTech Connect (OSTI)

    Sanchez, Dario Ferreira; Weleguela, Monica Larissa Djomeni; Audoit, Guillaume; Grenier, Adeline; Gergaud, Patrice; Bleuet, Pierre [Univ. Grenoble Alpes, F-38000 Grenoble (France); CEA/LETI, MINATEC Campus, F-38054 Grenoble (France); Laloum, David [Univ. Grenoble Alpes, F-38000 Grenoble (France); CEA/LETI, MINATEC Campus, F-38054 Grenoble (France); ST Microelectronics, 850 Rue Jean Monnet, F-38920 Crolles (France); Ulrich, Olivier; Micha, Jean-Sébastien; Robach, Odile [Univ. Grenoble Alpes, F-38000 Grenoble (France); CEA/INAC and CNRS, SPrAM, 17 rue des Martyrs, F-38054 Grenoble (France); Lorut, Frédéric [ST Microelectronics, 850 Rue Jean Monnet, F-38920 Crolles (France)

    2014-10-28T23:59:59.000Z

    Here, white X-ray ?-beam Laue diffraction is developed and applied to investigate elastic strain distributions in three-dimensional (3D) materials, more specifically, for the study of strain in Cu 10??m diameter–80??m deep through-silicon vias (TSVs). Two different approaches have been applied: (i) two-dimensional ?-Laue scanning and (ii) ?-beam Laue tomography. 2D ?-Laue scans provided the maps of the deviatoric strain tensor integrated along the via length over an array of TSVs in a 100??m thick sample prepared by Focused Ion Beam. The ?-beam Laue tomography analysis enabled to obtain the 3D grain and elemental distribution of both Cu and Si. The position, size (about 3??m), shape, and orientation of Cu grains were obtained. Radial profiles of the equivalent deviatoric strain around the TSVs have been derived through both approaches. The results from both methods are compared and discussed.

  8. Polarity of semipolar wurtzite crystals: X-ray photoelectron diffraction from GaN(101?1) and GaN(202?1) surfaces

    SciTech Connect (OSTI)

    Romanyuk, O., E-mail: romanyuk@fzu.cz; Ji?í?ek, P.; Bartoš, I. [Institute of Physics, Academy of Sciences of the Czech Republic, Cukrovarnická 10, 162 53 Prague (Czech Republic); Paskova, T. [Department of Electrical and Computer Engineering, North Carolina State University, Raleigh, North Carolina 27606 (United States)

    2014-09-14T23:59:59.000Z

    Polarity of semipolar GaN(101?1) (101?1?) and GaN(202?1) (202?1?) surfaces was determined with X-ray photoelectron diffraction (XPD) using a standard MgK? source. The photoelectron emission from N 1s core level measured in the a-plane of the crystals shows significant differences for the two crystal orientations within the polar angle range of 80–100° from the (0001) normal. It was demonstrated that XPD polar plots recorded in the a-plane are similar for each polarity of the GaN(101?1) and GaN(202?1) crystals if referred to (0001) crystal axes. For polarity determinations of all important GaN(h0h?l) semipolar surfaces, the above given polar angle range is suitable.

  9. X-ray diffraction study on pressure-induced phase transformations and the equation of state of ZnGa{sub 2}Te{sub 4}

    SciTech Connect (OSTI)

    Errandonea, D., E-mail: daniel.errandonea@uv.es [Departamento de Física Aplicada-ICMUV, MALTA Consolider Team, Universidad de Valencia, Edificio de Investigación, C/Dr. Moliner 50, Burjassot, 46100 Valencia (Spain); Kumar, R. S. [High Pressure Science and Engineering Center, Department of Physics and Astronomy, University of Nevada Las Vegas, 4505 Maryland Parkway, Las Vegas, Nevada 89154-4002 (United States); Gomis, O. [Centro de Tecnologías Físicas: Acústica, Materiales y Astrofísica, MALTA Consolider Team, Universitat Politècnica de València, 46022 València (Spain); Manjón, F. J. [Instituto de Diseño para la Fabricación y Producción Automatizada, MALTA Consolider Team, Universitat Politècnica de València, 46022 València (Spain); Ursaki, V. V.; Tiginyanu, I. M. [Institute of Applied Physics, Academy of Sciences of Moldova, 2028 Chisinau (Moldova, Republic of)

    2013-12-21T23:59:59.000Z

    We report on high-pressure x-ray diffraction measurements up to 19.8?GPa in zinc digallium telluride (ZnGa{sub 2}Te{sub 4}) at room temperature. An irreversible structural phase transition takes place at pressures above 12.1?GPa and upon decompression a third polymorph of ZnGa{sub 2}Te{sub 4} was recovered as a metastable phase at pressures below 2.9?GPa. Rietveld refinements were carried out for the three detected polymorphs, being their possible crystal structures reported. The axial compressibilities for the low-pressure phase of ZnGa{sub 2}Te{sub 4} have been determined as well as the equation of state of the low- and high-pressure phases. The reported results are compared with those available in the literature for related compounds. Pressure-induced coordination changes and transition mechanisms are also discussed.

  10. The application of soft x-ray imaging techniques to auroral research. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-06-01T23:59:59.000Z

    The feasibility of building and operating a grazing incidence X-ray telescope for auroral zone studies from the Polar Plasma Laboratory (PPL) is discussed. A detailed structural analysis of the preferred design, an array of seven nested Wolter mirrors, is presented. An engineering evaluation of the requirements for the instrumental configuration, power, weight and telemetry is included. The problems of radiation hardening and thermal control are discussed. The resulting strawman instrument is presented.

  11. High-pressure X-ray diffraction study of SrMoO{sub 4} and pressure-induced structural changes

    SciTech Connect (OSTI)

    Errandonea, Daniel [MALTA Consolider Team-Departamento de Fisica Aplicada-ICMUV, Universitat de Valencia, Edificio de Investigacion, c/Dr. Moliner 50, 46100 Burjassot, Valencia (Spain)], E-mail: daniel.errandonea@uv.es; Kumar, Ravhi S. [Department of Physics and Astronomy, High Pressure Science and Engineering Center, University of Nevada, 4505 Maryland Parkway, Las Vegas, NV 89154-4002 (United States); Ma Xinghua; Tu Chaoyang [Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Graduated School of Chinese Academy of Science, 100039 Beijing (China)

    2008-02-15T23:59:59.000Z

    SrMoO{sub 4} was studied under compression up to 25 GPa by angle-dispersive X-ray diffraction. A phase transition was observed from the scheelite-structured ambient phase (space group I4{sub 1}/a) to a monoclinic fergusonite phase (space group I2/a) at 12.2(9) GPa. The unit-cell parameters of the high-pressure phase are a=5.265(9) A, b=11.191(9) A, c=5.195 (5) A, and {beta}=90.9(1){sup o}, Z=4 at 13.1 GPa. There is no significant volume collapse at the phase transition. No additional phase transitions were observed and on release of pressure the initial phase is recovered, implying that the observed structural modifications are reversible. The reported transition appeared to be a ferroelastic second-order transformation producing a structure that is a monoclinic distortion of the low-pressure phase and was previously observed in compounds isostructural to SrMoO{sub 4}. A possible mechanism for the transition is proposed and its character is discussed in terms of the present data and the Landau theory. Finally, the room temperature equation of states is reported and the anisotropic compressibility of the studied crystal is discussed in terms of the compression of the Sr-O and Mo-O bonds. - Graphical abstract: The evolution of the structure of SrMoO{sub 4} upon compression was established using synchrotron X-ray diffraction and a diamond-anvil cell. A pressure-induced phase transition was found involving a symmetry decrease from tetragonal to monoclinic. A transition mechanism is proposed and its ferroelastic character is discussed in terms of the Landau theory.

  12. Simultaneous probing of phase transformations in Ni-Ti thin film shape memory alloy by synchrotron radiation-based X-ray diffraction and electrical resistivity

    SciTech Connect (OSTI)

    Braz Fernandes, F.M. [CENIMAT/I3N, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Mahesh, K.K., E-mail: kkmahesh@rediffmail.com [CENIMAT/I3N, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Martins, R.M.S. [CENIMAT/I3N, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), P.O. Box 510119, 01314 Dresden (Germany); IST/Instituto Tecnológico e Nuclear (IST/ITN), Universidade Técnica de Lisboa, EN10, 2696-953 Sacavém (Portugal); Centro de Física Nuclear da Universidade de Lisboa (CFNUL), Av. Prof. Gama Pinto 2, 1649-003 Lisboa (Portugal); Silva, R.J.C. [CENIMAT/I3N, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Baehtz, C.; Borany, J. von [Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), P.O. Box 510119, 01314 Dresden (Germany)

    2013-02-15T23:59:59.000Z

    Nickel–Titanium (Ni–Ti) thin film shape memory alloys (SMAs) have been widely projected as novel materials which can be utilized in microdevices. Characterization of their physical properties and its correlation with phase transformations has been a challenging issue. In the present study, X-ray beam diffraction has been utilized to obtain the structural information at different temperatures while cooling. Simultaneously, electrical resistivity (ER) was measured in the phase transformation temperature range. The variation of ER and integral area of the individual diffraction peaks of the different phases as a function of temperature have been compared. A mismatch between the conventional interpretation of ER variation and the results of the XRD data has been clearly identified. - Highlights: ? Phase transformation characterization of Ni–Ti thin film SMA has been carried out. ? Simultaneous monitoring of the XRD and ER with temperature is performed. ? The variation of ER and integral area of the diffraction peaks have been compared. ? A shift of the transformation temperatures obtained by two techniques is discussed.

  13. Design of the high-resolution soft X-ray imaging system on the Joint Texas Experimental Tokamak

    SciTech Connect (OSTI)

    Li, Jianchao; Ding, Yonghua, E-mail: yhding@mail.hust.edu.cn; Zhang, Xiaoqing; Xiao, Zhengyu; Zhuang, Ge [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electric and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2014-11-15T23:59:59.000Z

    A new soft X-ray diagnostic system has been designed on the Joint Texas Experimental Tokamak (J-TEXT) aiming to observe and survey the magnetohydrodynamic (MHD) activities. The system consists of five cameras located at the same toroidal position. Each camera has 16 photodiode elements. Three imaging cameras view the internal plasma region (r/a < 0.7) with a spatial resolution about 2 cm. By tomographic method, heat transport outside from the 1/1 mode X-point during the sawtooth collapse is found. The other two cameras with a higher spatial resolution 1 cm are designed for monitoring local MHD activities respectively in plasma core and boundary.

  14. Fuel Injection and Spray Research Using X-Ray Diagnostics

    Broader source: Energy.gov (indexed) [DOE]

    by ECN using several different techniques - Silicone molds (Valencia) - X-ray absorption tomography (CAT) - X-Ray phase contrast imaging (Argonne) - Microscopy (Sandia) ...

  15. X-Ray Imaging Current-Driven Magnetic Domain-Wall Motion in Nanowires

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-Ray Diagnostics

  16. X-Ray Imaging Current-Driven Magnetic Domain-Wall Motion in Nanowires

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-Ray

  17. X-Ray Imaging Current-Driven Magnetic Domain-Wall Motion in Nanowires

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat isJoin theanniversaryI 1 0 3 P 0 d d XX-RayX-Ray

  18. X-Ray Imaging of the Dynamic Magnetic Vortex Core Deformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat isJoin theanniversaryI 1 0 3 P 0 d dX-Ray

  19. Synchrotron-based X-ray fluorescence imaging and elemental mapping from biological samples

    SciTech Connect (OSTI)

    D Rao; M Swapna; R Cesareo; A Brunetti; T Akatsuka; T Yuasa; T Takeda; G Gigante

    2011-12-31T23:59:59.000Z

    The present study utilized the new hard X-ray microspectroscopy beamline facility, X27A, available at NSLS, BNL, USA, for elemental mapping. This facility provided the primary beam in a small spot of the order of {approx}10 {mu}m, for focussing. With this spatial resolution and high flux throughput, the synchrotron-based X-ray fluorescent intensities for Mn, Fe, Zn, Cr, Ti and Cu were measured using a liquid-nitrogen-cooled 13-element energy-dispersive high-purity germanium detector. The sample is scanned in a 'step-and-repeat' mode for fast elemental mapping measurements and generated elemental maps at 8, 10 and 12 keV, from a small animal shell (snail). The accumulated trace elements, from these biological samples, in small areas have been identified. Analysis of the small areas will be better suited to establish the physiology of metals in specific structures like small animal shell and the distribution of other elements.

  20. Statistical models and regularization strategies in statistical image reconstruction of low-dose X-ray computed tomography: a survey

    E-Print Network [OSTI]

    Zhang, Hao; Ma, Jianhua; Lu, Hongbing; Liang, Zhengrong

    2014-01-01T23:59:59.000Z

    Statistical image reconstruction (SIR) methods have shown potential to substantially improve the image quality of low-dose X-ray computed tomography (CT) as compared to the conventional filtered back-projection (FBP) method for various clinical tasks. According to the maximum a posterior (MAP) estimation, the SIR methods can be typically formulated by an objective function consisting of two terms: (1) data-fidelity (or equivalently, data-fitting or data-mismatch) term modeling the statistics of projection measurements, and (2) regularization (or equivalently, prior or penalty) term reflecting prior knowledge or expectation on the characteristics of the image to be reconstructed. Existing SIR methods for low-dose CT can be divided into two groups: (1) those that use calibrated transmitted photon counts (before log-transform) with penalized maximum likelihood (pML) criterion, and (2) those that use calibrated line-integrals (after log-transform) with penalized weighted least-squares (PWLS) criterion. Accurate s...

  1. Structural phase transition and magnetism in hexagonal SrMnO{sub 3} by magnetization measurements and by electron, x-ray, and neutron diffraction studies

    SciTech Connect (OSTI)

    Daoud-Aladine, A.; Chapon, L. C.; Knight, K. S. [ISIS facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Martin, C. [Laboratoire CRISMAT-UMR, 6508 ENSI CAEN, 6, Marechal Juin, 14050 Caen (France); ISIS facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Hervieu, M. [Laboratoire CRISMAT-UMR, 6508 ENSI CAEN, 6, Marechal Juin, 14050 Caen (France); Brunelli, M. [European Synchrotron Radiation Facility, BP220, F-38043 Grenoble Cedex (France); Radaelli, P. G. [ISIS facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

    2007-03-01T23:59:59.000Z

    The structural and magnetic properties of the hexagonal four-layer form of SrMnO{sub 3} have been investigated by combining magnetization measurements, electron diffraction, and high-resolution synchrotron x-ray and neutron powder diffraction. Below 350 K, there is subtle structural phase transition from hexagonal symmetry (space group P6{sub 3}/mmc) to orthorhombic symmetry (space group C222{sub 1}) where the hexagonal metric is preserved. The second-order phase transition involves a slight tilting of the corner-sharing Mn{sub 2}O{sub 9} units composed of two face-sharing MnO{sub 6} octahedra and the associated displacement of Sr{sup 2+} cations. The phase transition is described in terms of symmetry-adapted displacement modes of the high symmetry phase. Upon further cooling, long range magnetic order with propagation vector k=(0,0,0) sets in below 300 K. The antiferromagnetic structure, analyzed using representation theory, shows a considerably reduced magnetic moment indicating the crucial role played by direct exchange between Mn centers of the Mn{sub 2}O{sub 9} units.

  2. X-ray absorption and diffraction studies of the mixed-phase state of (Cr x V 1 ? x ) 2 O 3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pease, D. M.; Frenkel, A. I.; Krayzman, V.; Huang, T.; Shanthakumar, P.; Budnick, J. I.; Metcalf, P.; Chudnovsky, F. A.; Stern, E. A.

    2011-02-01T23:59:59.000Z

    X-ray diffraction and vanadium x-ray absorption near-edge structure (XANES) data have been obtained for (V1-x)?O? samples containing several concentrations of Cr, crossing the metal-insulator transition boundary. For single-phase single-crystal samples our theoretical results are generally in good qualitative agreement with our experimental single-crystal XANES, for both crystal orientations relative to the incident-beam electric vector. However, an anomalous peak occurs for both orientations in the K pre-edge of the single-crystal sample containing 1.2% Cr, a paramagnetic insulator sample that is in the concentration regime corresponding to the room-temperature two-phase (coexistence) region of the phase diagram. Upon increasing the temperature of the 0.4% Cr powdered material to 400 K so that one enters the two-phase region of the phase diagram, a similar peak appears and then diminishes at 600 K. These results, as well as experiments done by others involving room-temperature and low-temperature XANES of a 1.1% Cr sample, suggest that this feature in the V pre-edge structure is associated with the appearance under some circumstances of a small amount of highly distorted VO? octahedra in the interface region between coexisting metal and insulating phases. Finally, we find that, for the two-phase regime, the concentration ratio of the metal-to-insulating phase varies between different regions from a sample batch of uniform composition made by the skull melting method.

  3. Analysis of the KROTOS KFC test by coupling X-Ray image analysis and MC3D calculations

    SciTech Connect (OSTI)

    Brayer, C.; Charton, A.; Grishchenko, D.; Fouquart, P.; Bullado, Y.; Compagnon, F.; Correggio, P.; Cassiaut-Louis, N.; Piluso, P. [Commissariat a l'Energie Atomique et Aux Energies Alternatives, CEA Cadarache, DEN, F-13108 Saint-Paul-Les-Durance (France)

    2012-07-01T23:59:59.000Z

    During a hypothetical severe accident sequence in a Pressurized Water Reactor (PWR), the hot molten materials (corium) issuing from the degraded reactor core may generate a steam explosion if they come in contact with water and may damage the structures and threaten the reactor integrity. The SERENA program is an international OECD project that aims at helping the understanding of this phenomenon also called Fuel Coolant Interaction (FCI) by providing data. CEA takes part in this program by performing tests in its KROTOS facility where steam explosions using prototypic corium can be triggered. Data about the different phases in the premixing are extracted from the KROTOS X-Ray radioscopy images by using KIWI software (KROTOS Image analysis of Water-corium Interaction) currently developed by CEA. The MC3D code, developed by IRSN, is a thermal-hydraulic multiphase code mainly dedicated to FCI studies. It is composed of two applications: premixing and explosion. An overall FCI calculation with MC3D requires a premixing calculation followed by an explosion calculation. The present paper proposes an alternative approach in which all the features of the premixing are extracted from the X-Ray pictures using the KIWI software and transferred to an MC3D dataset for a direct simulation of the explosion. The main hypothesis are discussed as well as the first explosion results obtained with MC3D for the KROTOS KFC test. These results are rather encouraging and are analyzed on the basis of comparisons with the experimental data. (authors)

  4. Mossbauer spectroscopic and x-ray diffraction studies of structural and magnetic properties of heat-treated ,,Ni0.5Zn0.5...Fe2O4 nanoparticles

    E-Print Network [OSTI]

    Yang, De-Ping

    Mo¨ssbauer spectroscopic and x-ray diffraction studies of structural and magnetic properties-temperature and low-temperature 57 Fe Mo¨ssbauer effect experiments allowed us to determine whether the heat-temperature Mo¨ssbauer spectra revealed that the precursor is paramagnetic, while the heat-treated samples have

  5. Broadband diffractive lens or imaging element

    DOE Patents [OSTI]

    Ceglio, Natale M. (Livermore, CA); Hawryluk, Andrew M. (Modesto, CA); London, Richard A. (Oakland, CA); Seppala, Lynn G. (Livermore, CA)

    1991-01-01T23:59:59.000Z

    A broadband diffractive lens or imaging element produces a sharp focus and/or a high resolution image with broad bandwidth illuminating radiation. The diffractive lens is sectored or segmented into regions, each of which focuses or images a distinct narrowband of radiation but all of which have a common focal length. Alternatively, a serial stack of minus filters, each with a diffraction pattern which focuses or images a distinct narrowband of radiation but all of which have a common focal length, is used. The two approaches can be combined. Multifocal broadband diffractive elements can also be formed.

  6. Broadband diffractive lens or imaging element

    DOE Patents [OSTI]

    Ceglio, N.M.; Hawryluk, A.M.; London, R.A.; Seppala, L.G.

    1993-10-26T23:59:59.000Z

    A broadband diffractive lens or imaging element produces a sharp focus and/or a high resolution image with broad bandwidth illuminating radiation. The diffractive lens is sectored or segmented into regions, each of which focuses or images a distinct narrowband of radiation but all of which have a common focal length. Alternatively, a serial stack of minus filters, each with a diffraction pattern which focuses or images a distinct narrowband of radiation but all of which have a common focal length, is used. The two approaches can be combined. Multifocal broadband diffractive elements can also be formed. Thin film embodiments are described. 21 figures.

  7. Broadband diffractive lens or imaging element

    DOE Patents [OSTI]

    Ceglio, Natale M. (Livermore, CA); Hawryluk, Andrew M. (Modesto, CA); London, Richard A. (Oakland, CA); Seppala, Lynn G. (Livermore, CA)

    1993-01-01T23:59:59.000Z

    A broadband diffractive lens or imaging element produces a sharp focus and/or a high resolution image with broad bandwidth illuminating radiation. The diffractive lens is sectored or segmented into regions, each of which focuses or images a distinct narrowband of radiation but all of which have a common focal length. Alternatively, a serial stack of minus filters, each with a diffraction pattern which focuses or images a distinct narrowband of radiation but all of which have a common focal length, is used. The two approaches can be combined. Multifocal broadband diffractive elements can also be formed. Thin film embodiments are described.

  8. Spatial resolution of synchrotron x-ray microtomography in high energy range: Effect of x-ray energy and sample-to-detector distance

    SciTech Connect (OSTI)

    Seo, D.; Tomizato, F.; Toda, H.; Kobayashi, M. [Department of Mechanical Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580 (Japan); Uesugi, K.; Takeuchi, A.; Suzuki, Y. [Japan Synchrotron Radiation Research Institute, Mikazuki, Sayo, Hyogo 679-5198 (Japan)

    2012-12-24T23:59:59.000Z

    Spatial resolution of three-dimensional images obtained by synchrotron X-ray microtomography technique is evaluated using cyclic bar patterns machined on a steel wire. Influences of X-ray energy and the sample-to-detector distance on spatial resolution were investigated. High X-ray energies of 33-78 keV are applied due to the high X-ray absorption of transition metals. Best spatial resolution of about 1.2 {mu}m pitch was observed at the sample-to-detector distance range of 20-110 mm and at the energy range of 68-78 keV. Several factors such as X-ray scattering and diffraction phenomena affecting the degradation of spatial resolution are also discussed.

  9. Direct Observations of Sigma Phase Formation in Duplex Stainless Steels using In Situ Synchrotron X-Ray Diffraction

    SciTech Connect (OSTI)

    Elmer, J W; Palmer, T A; Specht, E D

    2006-07-03T23:59:59.000Z

    The formation and growth of sigma phase in 2205 duplex stainless steel was observed and measured in real time using synchrotron radiation during 10 hr isothermal heat treatments at temperatures between 700 C and 850 C. Sigma formed in near-equilibrium quantities during the isothermal holds, starting from a microstructure which contained a balanced mixture of metastable ferrite and austenite. In situ synchrotron diffraction continuously monitored the transformation, and these results were compared to those predicted by thermodynamic calculations. Differences between the calculated and measured amounts of sigma, ferrite and austenite suggest that the thermodynamic calculations underpredict the sigma dissolution temperature by approximately 50 C. The data were further analyzed using a modified Johnson-Mehl-Avrami (JMA) approach to determine kinetic parameters for sigma formation over this temperature range. The initial JMA exponent, n, at low fractions of sigma was found to be approximately 7.0, however, towards the end of the transformation, n decreased to values of approximately 0.75. The change in the JMA exponent was attributed to a change in the transformation mechanism from discontinuous precipitation with increasing nucleation rate, to growth of the existing sigma phase after nucleation site saturation occurred. Because of this change in mechanism, it was not possible to determine reliable values for the activation energy and pre-exponential terms for the JMA equation. While cooling back to room temperature, the partial transformation of austenite resulted in a substantial increase in the ferrite content, but sigma retained its high temperature value to room temperature.

  10. Direct Observations of Sigma Phase Formation in Duplex Stainless Steels Using In Situ Synchrotron X-Ray Diffraction

    SciTech Connect (OSTI)

    Elmer, J. W. [Lawrence Livermore National Laboratory (LLNL); Palmer, T. A. [Lawrence Livermore National Laboratory (LLNL); Specht, Eliot D [ORNL

    2007-01-01T23:59:59.000Z

    The formation and growth of sigma ( ) phase in 2205 duplex stainless steel (DSS) was observed and measured in real time using synchrotron radiation during 10 hour isothermal heat treatments at temperatures between 700 C and 850 C. Sigma formed in near-equilibrium quantities during the isothermal holds, starting from a microstructure which contained a balanced mixture of metastable ferrite and austenite. In-situ synchrotron diffraction continuously monitored the transformation, and these results were compared to those predicted by thermodynamic calculations. The data were further analyzed using a modified Johnson-Mehl-Avrami-Kolmogrov (JMAK) approach to determine kinetic parameters for sigma formation over this temperature range. The initial JMAK exponent, n, at low fractions of sigma was found to be approximately 7.0; however, toward the end of the transformation, n decreased to values of approximately 0.75. The change in the JMAK exponent was attributed to a change in the transformation mechanism from discontinuous precipitation with increasing nucleation rate, to growth of the existing sigma phase after nucleation site saturation occurred. Because of this change in mechanism, it was not possible to determine reliable values for the activation energy and pre-exponential terms for the JMAK equation. While cooling back to room temperature, the partial transformation of austenite resulted in a substantial increase in the ferrite content, but sigma retained its high-temperature value to room temperature.

  11. Effects of Fresnel fringes on TEM images of interfaces in X-ray multil ayers

    E-Print Network [OSTI]

    Nguyen, Tai D.; O'Keefe, Michael A.; Kilaas, Roar; Gronsky, Ronald; Kortright, Jeffrey B.

    1992-01-01T23:59:59.000Z

    and J.B. Kortright, Fresnel Fringe Effects at Interfaces ofand T.F. Page, A TEM Fresnel Diffraction-Based Method forW/Si Multilayers Using The Fresnel Method, Ultramicroscopy

  12. X-ray holography of biological specimens

    SciTech Connect (OSTI)

    Solem, J.C.

    1984-01-01T23:59:59.000Z

    The author reviews the reasons for x-ray imaging of biological specimens and the techniques presently being used for x-ray microscopy. The author points out the advantages of x-ray holography and the difficulties of obtaining the requisite coherence with conventional sources. The author discusses the problems of radiation damage and the remarkable fact that short pulse x-ray sources circumvent these problems and obtain high-resolution images of specimens in the living state. Finally, the author reviews some of the efforts underway to develop high-intensity coherent x-ray sources for the laboratory. 14 references, 5 figures, 2 tables.

  13. Thermal equation of state of solid naphthalene to 13 GPa and 773 K: In situ X-ray diffraction study and first principles calculations

    SciTech Connect (OSTI)

    Likhacheva, Anna Y., E-mail: alih@igm.nsc.ru [Sobolev Institute of Geology and Mineralogy, SB RAS, Novosibirsk 630090 (Russian Federation); Rashchenko, Sergey V.; Chanyshev, Artem D.; Litasov, Konstantin D. [Sobolev Institute of Geology and Mineralogy, SB RAS, Novosibirsk 630090 (Russian Federation) [Sobolev Institute of Geology and Mineralogy, SB RAS, Novosibirsk 630090 (Russian Federation); Department of Geology and Geophysics, Novosibirsk State University, Novosibirsk 630090 (Russian Federation); Inerbaev, Talgat M. [Department of Physics and Technical Science, Gumilyov Eurasian National University, Astana (Kazakhstan)] [Department of Physics and Technical Science, Gumilyov Eurasian National University, Astana (Kazakhstan); Kilin, Dmitry S. [Department of Chemistry, University of South Dakota, Vermillion, South Dakota 57069 (United States)] [Department of Chemistry, University of South Dakota, Vermillion, South Dakota 57069 (United States)

    2014-04-28T23:59:59.000Z

    In a wide range of P-T conditions, such fundamental characteristics as compressibility and thermoelastic properties remain unknown for most classes of organic compounds. Here we attempt to clarify this issue by the example of naphthalene as a model representative of polycyclic aromatic hydrocarbons (PAHs). The elastic behavior of solid naphthalene was studied by in situ synchrotron powder X-ray diffraction up to 13 GPa and 773 K and first principles computations to 20 GPa and 773 K. Fitting of the P-V experimental data to Vinet equation of state yielded T 0 = 8.4(3) GPa and T' = 7.2 (3) at V0 = 361 Å(3), whereas the thermal expansion coefficient was found to be extremely low at P > 3 GPa (about 10(-5) K(-1)), in agreement with theoretical estimation. Such a diminishing of thermal effects with the pressure increase clearly demonstrates a specific feature of the high-pressure behavior of molecular crystals like PAHs, associated with a low energy of intermolecular interactions.

  14. A combined solid-state NMR and synchrotron x-ray diffraction powder study on the structure of the antioxidant(+)-catechin 4.5 hydrate.

    SciTech Connect (OSTI)

    Harper, J. K.; Doebbler, J. A.; Jaccques, E.; Grant, D. M.; Von Dreele, R. B.; Univ. of Utah

    2010-03-10T23:59:59.000Z

    Analyses combining X-ray powder diffraction (XRD) and solid-state NMR (SSNMR) data can now provide crystal structures in challenging powders that are inaccessible by traditional methods. The flavonoid catechin is an ideal candidate for these methods, as it has eluded crystallographic characterization despite extensive study. Catechin was first described nearly two centuries ago, and its powders exhibit numerous levels of hydration. Here, synchrotron XRD data provide all heavy-atom positions in (+)-catechin 4.5-hydrate and establish the space group as C2. SSNMR data ({sup 13}C tensor and {sup 1}H/{sup 13}C correlation) complete the conformation by providing catechin's five OH hydrogen orientations. Since 1903, this phase has been erroneously identified as a 4.0 hydrate, but XRD and density data establish that this discrepancy is due to the facile loss of the water molecule located at a Wyckoff special position in the unit cell. A final improvement to heavy-atom positions is provided by a geometry optimization of bond lengths and valence angles with XRD torsion angles held constant. The structural enhancement in this final structure is confirmed by the significantly improved fit of computed {sup 13}C tensors to experimental data.

  15. Composition and strain in thin Si{sub 1-x}Ge{sub x} virtual substrates measured by micro-Raman spectroscopy and x-ray diffraction

    SciTech Connect (OSTI)

    Perova, T. S.; Wasyluk, J.; Waldron, A. [Department of Electronic and Electrical Engineering, Trinity College, University of Dublin, Dublin 2 (Ireland); Lyutovich, K.; Kasper, E.; Oehme, M. [Institut fuer Halbleitertechnik, Universitaet Stuttgart, Pfaffenwaldring 47, 70569 Stuttgart (Germany); Rode, K. [School of Physics, CRANN, Trinity College, University of Dublin, Dublin 2 (Ireland)

    2011-02-01T23:59:59.000Z

    Micro-Raman spectroscopy was employed for the determination of the germanium content, x and strain, {epsilon}, in ultrathin SiGe virtual substrates grown directly on Si by molecular beam epitaxy. The growth of highly relaxed SiGe layers was achieved by the introduction of point defects at a very low temperature during the initial stage of growth. SiGe virtual substrates with thicknesses in the range 40-200 nm with a high Ge content (up to 50%) and degree of relaxation, r, in the range 20%-100% were investigated using micro-Raman spectroscopy and x-ray diffraction (XRD) techniques. The Ge content, x, and strain, {epsilon}, were estimated from equations describing Si-Si, Si-Ge, and Ge-Ge Raman vibrational modes, modified in this study for application to thin SiGe layers. The alteration of the experimentally derived equations from previous studies was performed using independent data for x and r obtained from XRD reciprocal space maps. A number of samples consisting of a strained-silicon (s-Si) layer deposited on a SiGe virtual substrate were also analyzed. The stress value for the s-Si varied from 0.54 to 2.75 GPa, depending on the Ge-content in the virtual substrates. These results are in good agreement with theoretically predicted values.

  16. X-ray and neutron powder diffraction studies of Ba(Nd{sub x}Y{sub 2-x})CuO{sub 5}

    SciTech Connect (OSTI)

    Liu, G. [Ceramics Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Huang, Q. [NIST Center for Neutron Research, Naperville, IL 60563 (United States); Kaduk, J.A. [INEOS Technologies, Naperville, IL 60563 (United States); Yang, Z. [Yunnan Normal University, Kunming 650092 (China); Lucas, C. [Chemistry and Biochemistry Department, University of Maryland, College Park, MD 20742 (United States); Wong-Ng, W. [Ceramics Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States)], E-mail: Winnie.wong-ng@nist.gov

    2008-12-15T23:59:59.000Z

    Ba(R,R'){sub 2}CuO{sub 5} (R,R'=lanthanides and Y) plays an important role as a flux-pinning agent in enhancing the superconducting properties of the Ba{sub 2}(R,R')Cu{sub 3}O{sub 6+x} (R,R'=lanthanides and Y) coated conductors. Using X-ray diffraction and neutron diffraction, we found that the Ba(Nd{sub x}Y{sub 2-x})CuO{sub 5} solid solution adopts two structure types. In the Nd-rich region (1.8{<=}x{<=}2.0), the materials are of brown color (commonly referred to as the 'brown phase'), and the structure is tetragonal with space group I4/mbm (no. 127). In the Y-rich region (0.0{<=}x{<=}1.4), the materials are green (commonly referred to as the 'green phase') and the structure is orthorhombic with space group Pnma (no. 62). A two-phase region (1.4

  17. Observations of Ferrite/Austenite Transformations in the Heat Affected Zone of 2205 Duplex Stainless Steel Spot Welds Using Time Resolved X-Ray Diffraction

    SciTech Connect (OSTI)

    Palmer, T; Elmer, J; Babu, S

    2003-10-29T23:59:59.000Z

    Time Resolved X-Ray Diffraction (TRXRD) measurements are made in the Heat Affected Zone (HAZ) of 2205 Duplex Stainless Steel (DSS) spot welds. Both the {gamma} {yields} {delta} and {delta} {yields} {gamma} transformations are monitored as a function of time during the rapid spot weld heating and cooling cycles. These observations are then correlated with calculated thermal cycles. Where the peak temperatures are highest ({approx}1342 C), the {gamma} {yields} {delta} transformation proceeds to completion, leaving a ferritic microstructure at the end of heating. With lower peak temperatures, the {gamma} {yields} {delta} transformation proceeds to only partial completion, resulting in a microstructure containing both transformed and untransformed austenite. Further analyses of the individual diffraction patterns show shifts in the peak positions and peak widths as a function of both time and temperature. In addition, these changes in the peak characteristics are correlated with measured changes in the ferrite volume fraction. Such changes in the peak positions and widths during the {gamma} {yields} {delta} transformation provide an indication of changes occurring in each phase. These changes in peak properties can be correlated with the diffusion of nitrogen and other substitutional alloying elements, which are recognized as the primary mechanisms for this transformation. Upon cooling, the {delta} {yields} {gamma} transformation is observed to proceed from both the completely and partially transformed microstructural regions in the TRXRD data. An examination of the resulting microstructures confirms the TRXRD observation as the evidence shows that austenite both nucleates and grows from the ferritic microstructure at locations closest to the fusion zone boundary and grows from untransformed austenite grains at locations further from this boundary.

  18. Upgraded high time-resolved x-ray imaging crystal spectroscopy system for J-TEXT ohmic plasmas

    SciTech Connect (OSTI)

    Jin, W.; Chen, Z. Y., E-mail: zychen@hust.edu.cn; Huang, D. W.; Li, Q. L.; Yan, W.; Luo, Y. H.; Huang, Y. H.; Tong, R. H.; Yang, Z. J.; Rao, B.; Ding, Y. H.; Zhuang, G. [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)] [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Lee, S. G.; Shi, Y. J. [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of)] [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of)

    2014-02-15T23:59:59.000Z

    This paper presents the upgraded x-ray imaging crystal spectrometer (XICS) system on Joint Texas Experimental Tokamak (J-TEXT) tokamak and the latest experimental results obtained in last campaign. With 500 Hz frame rate of the new Pilatus detector and 5 cm × 10 cm spherically bent crystal, the XICS system can provide core electron temperature (T{sub e}), core ion temperature (T{sub i}), and plasma toroidal rotation (V{sub ?}) with a maximum temporal resolution of 2 ms for J-TEXT pure ohmic plasmas. These parameters with high temporal resolution are very useful in tokamak plasma research, especially for rapidly changed physical processes. The experimental results from the upgraded XICS system are presented.

  19. Biomedical nuclear and X-ray imager using high-energy grazing incidence mirrors

    DOE Patents [OSTI]

    Ziock, Klaus-Peter; Craig, William W.; Hasegawa, Bruce; Pivovaroff, Michael J.

    2005-09-27T23:59:59.000Z

    Imaging of radiation sources located in a subject is explored for medical applications. The approach involves using grazing-incidence optics to form images of the location of radiopharmaceuticals administered to a subject. The optics are "true focusing" optics, meaning that they project a real and inverted image of the radiation source onto a detector possessing spatial and energy resolution.

  20. Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic Sequestration Conditions Using X?ray Computed Microtomography

    SciTech Connect (OSTI)

    Jung, Hun Bok; Jansik, Danielle P.; Um, Wooyong

    2013-01-01T23:59:59.000Z

    ABSTRACT: X-ray microtomography (XMT), a nondestructive three-dimensional imaging technique, was applied to demonstrate its capability to visualize the mineralogical alteration and microstructure changes in hydrated Portland cement exposed to carbon dioxide under geologic sequestration conditions. Steel coupons and basalt fragments were added to the cement paste in order to simulate cement-steel and cement-rock interfaces. XMT image analysis showed the changes of material density and porosity in the degradation front (density: 1.98 g/cm3, porosity: 40%) and the carbonated zone (density: 2.27 g/cm3, porosity: 23%) after reaction with CO2- saturated water for 5 months compared to unaltered cement (density: 2.15 g/cm3, porosity: 30%). Three-dimensional XMT imaging was capable of displaying spatially heterogeneous alteration in cement pores, calcium carbonate precipitation in cement cracks, and preferential cement alteration along the cement-steel and cement-rock interfaces. This result also indicates that the interface between cement and host rock or steel casing is likely more vulnerable to a CO2 attack than the cement matrix in a wellbore environment. It is shown here that XMT imaging can potentially provide a new insight into the physical and chemical degradation of wellbore cement by CO2 leakage.

  1. Automated Patient Identification and Localization Error Detection Using 2-Dimensional to 3-Dimensional Registration of Kilovoltage X-Ray Setup Images

    SciTech Connect (OSTI)

    Lamb, James M., E-mail: jlamb@mednet.ucla.edu; Agazaryan, Nzhde; Low, Daniel A.

    2013-10-01T23:59:59.000Z

    Purpose: To determine whether kilovoltage x-ray projection radiation therapy setup images could be used to perform patient identification and detect gross errors in patient setup using a computer algorithm. Methods and Materials: Three patient cohorts treated using a commercially available image guided radiation therapy (IGRT) system that uses 2-dimensional to 3-dimensional (2D-3D) image registration were retrospectively analyzed: a group of 100 cranial radiation therapy patients, a group of 100 prostate cancer patients, and a group of 83 patients treated for spinal lesions. The setup images were acquired using fixed in-room kilovoltage imaging systems. In the prostate and cranial patient groups, localizations using image registration were performed between computed tomography (CT) simulation images from radiation therapy planning and setup x-ray images corresponding both to the same patient and to different patients. For the spinal patients, localizations were performed to the correct vertebral body, and to an adjacent vertebral body, using planning CTs and setup x-ray images from the same patient. An image similarity measure used by the IGRT system image registration algorithm was extracted from the IGRT system log files and evaluated as a discriminant for error detection. Results: A threshold value of the similarity measure could be chosen to separate correct and incorrect patient matches and correct and incorrect vertebral body localizations with excellent accuracy for these patient cohorts. A 10-fold cross-validation using linear discriminant analysis yielded misclassification probabilities of 0.000, 0.0045, and 0.014 for the cranial, prostate, and spinal cases, respectively. Conclusions: An automated measure of the image similarity between x-ray setup images and corresponding planning CT images could be used to perform automated patient identification and detection of localization errors in radiation therapy treatments.

  2. A theoretical comparison of x-ray angiographic image quality using energy-dependent and conventional subtraction methods

    SciTech Connect (OSTI)

    Tanguay, Jesse; Kim, Ho Kyung; Cunningham, Ian A. [Imaging Research Laboratories, Robarts Research Institute, 100 Perth Drive, London, Ontario N6A 5K8 (Canada) and Department of Medical Biophysics, University of Western Ontario, London, Ontario N6A 5C1 (Canada); School of Mechanical Engineering, Pusan National University, Jangjeon-dong, Geumjeong-gu, Busan 609-735 (Korea, Republic of); Imaging Research Laboratories, Robarts Research Institute, 100 Perth Drive, London, Ontario N6A 5K8 (Canada); Department of Medical Biophysics, University of Western Ontario, London, Ontario N6A 5C1 (Canada); Lawson Health Research Institute, London, Ontario N6A 4V2 (Canada) and London Health Sciences Centre, London, Ontario N6A 5A5 (Canada)

    2012-01-15T23:59:59.000Z

    Purpose: X-ray digital subtraction angiography (DSA) is widely used for vascular imaging. However, the need to subtract a mask image can result in motion artifacts and compromised image quality. The current interest in energy-resolving photon-counting (EPC) detectors offers the promise of eliminating motion artifacts and other advanced applications using a single exposure. The authors describe a method of assessing the iodine signal-to-noise ratio (SNR) that may be achieved with energy-resolved angiography (ERA) to enable a direct comparison with other approaches including DSA and dual-energy angiography for the same patient exposure. Methods: A linearized noise-propagation approach, combined with linear expressions of dual-energy and energy-resolved imaging, is used to describe the iodine SNR. The results were validated by a Monte Carlo calculation for all three approaches and compared visually for dual-energy and DSA imaging using a simple angiographic phantom with a CsI-based flat-panel detector. Results: The linearized SNR calculations show excellent agreement with Monte Carlo results. While dual-energy methods require an increased tube heat load of 2x to 4x compared to DSA, and photon-counting detectors are not yet ready for angiographic imaging, the available iodine SNR for both methods as tested is within 10% of that of conventional DSA for the same patient exposure over a wide range of patient thicknesses and iodine concentrations. Conclusions: While the energy-based methods are not necessarily optimized and further improvements are likely, the linearized noise-propagation analysis provides the theoretical framework of a level playing field for optimization studies and comparison with conventional DSA. It is concluded that both dual-energy and photon-counting approaches have the potential to provide similar angiographic image quality to DSA.

  3. Automatic Annotation of X-ray Images: A Study on Attribute Selection

    E-Print Network [OSTI]

    Ünay, Devrim

    Processing and Analysis Group, Philips Research, The Netherlands Abstract. Advances in the medical imaging, analyzed, classified, stored and retrieved in medical centers. As a result, medical image classification Introduction Storing, archiving and sharing patient information among medical centers has become a crucial task

  4. Structural characterization of the CeO{sub 2}/Gd{sub 2}O{sub 3} mixed system by synchrotron X-ray diffraction

    SciTech Connect (OSTI)

    Artini, Cristina, E-mail: c.artini@ge.ieni.cnr.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Costa, Giorgio A., E-mail: costa@chimica.unige.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); CNR-SPIN Genova, Corso Perrone 24, 16152 Genova (Italy); Pani, Marcella, E-mail: marcella@chimica.unige.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Lausi, Andrea, E-mail: andrea.lausi@elettra.trieste.it [Sincrotrone Trieste S.C.p.A., ss 14, km 163, 5, 34149 Basovizza, Trieste (Italy); Plaisier, Jasper, E-mail: jasper.plaisier@elettra.trieste.it [Sincrotrone Trieste S.C.p.A., ss 14, km 163, 5, 34149 Basovizza, Trieste (Italy)

    2012-06-15T23:59:59.000Z

    The structural determination of the CeO{sub 2}/Gd{sub 2}O{sub 3} mixed system is a non-trivial problem because of the close resemblance between the ionic sizes of Ce{sup 4+} and Gd{sup 3+} and between the crystal structures of CeO{sub 2} and Gd{sub 2}O{sub 3}. (Ce{sub 1-x}Gd{sub x})O{sub 2-x/2} powder samples with x ranging between 0 and 1 have been synthesized by coprecipitation of mixed oxalates and subsequent thermal decomposition in air at 1200 Degree-Sign C followed by slow cooling. Synchrotron powder X-ray diffraction data were collected and refined by the Rietveld method. Lattice parameters do not follow Vegard's law and no peak splitting has been observed for any composition, meaning that no biphasic regions exist over the whole compositional range. The same hybrid structural model - a proper mixture of the structures of the two pure oxides - was used for the refinements, allowing to account for the data observed. - graphical abstract: Substituting Ce{sup 4+} by Gd{sup 3+}, a gradual transition from the F structure (typical of CeO{sub 2}) to the C structure (typical of Gd{sub 2}O{sub 3}) takes place. The lattice parameters do not follow Vegard's law. Highlights: Black-Right-Pointing-Pointer A structural study of Ce-Gd mixed oxides has been performed. Black-Right-Pointing-Pointer In (Ce{sub 1-x}Gd{sub x})O{sub 2-x/2} a solid solution forms for 0{<=}x{<=}0.3. Black-Right-Pointing-Pointer For x>0.3 a gradual transition from the C to the F structure is observed. Black-Right-Pointing-Pointer Lattice parameters do not follow Vegard's law.

  5. Time-resolved synchrotron x-ray diffraction studies of the crystallization of amorphous Co(80-x)FexB??

    SciTech Connect (OSTI)

    Simmons, L. M., E-mail: l.simmons@mmu.ac.uk [Division of Electrical and Electronic Engineering, School of Engineering, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom); Greig, D. [School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT (United Kingdom); Lucas, C. A. [Oliver Lodge Laboratory, Department of Physics, University of Liverpool, Liverpool L69 7ZE (United Kingdom); Kilcoyne, S. H. [School of Applied Sciences, University of Huddersfield, Huddersfield HD1 3DH (United Kingdom)

    2014-09-28T23:59:59.000Z

    This paper addresses the time-dependent crystallization process occurring in “bulk” amorphous Co(80-x)FexB?? (x = 20, 40) metallic ribbons by means of synchrotron x-ray diffraction (SXRD) and transmission electron microscopy. Metallic ribbons, produced via melt-spinning technique, were annealed in-situ, with SXRD patterns collected every 60 s. SXRD reveals that Co??Fe??B?? alloys crystallize from an amorphous structure to a primary bcc ?-(Co,Fe) phase, whereas Co??Fe??B?? initially crystallizes into the same bcc ?-(Co,Fe) but exhibits cooperative growth of both stable and metastable boride phases later into the hold. Johnson-Mehl-Avrami-Kolmogorov statistics was used on post annealed samples to determine the mechanisms of growth and the activation energy (Ea) of the ?-(Co,Fe) phase. Results indicate that the growth mechanisms are similar for both alloy compositions for all annealing temperatures, with the Avrami exponent of n = 1.51(1) and 2.02(6) for x = 20 and 40, respectively, suggesting one-dimensional growth, with a decreasing nucleation rate. Activation energy for ?-(Co,Fe) was determined to be 2.7(1) eV and 2.4(3) eV in x = 20 and 40, respectively, suggesting that those alloys with a lower Co content have a stronger resistance to crystallization. Based on these results, fabrication of CoFeB magnetic tunnel junctions via depositing amorphous layers and subsequently annealing to induce lattice matching presents itself as a viable and efficient method, for increasing the giant magnetoresistance in magnetic tunnel junctions.

  6. Hidden Superlattice in Tl2(SC6H4S) and Tl2(SeC6H4Se) Solved from Powder X-ray Diffraction

    SciTech Connect (OSTI)

    K Stone; D Turner; M Singh; T Vaid; P Stephens

    2011-12-31T23:59:59.000Z

    The crystal structures of the isostructural title compounds poly[({mu}-benzene-1,4-dithiolato)dithallium], Tl{sub 2}(SC{sub 6}H{sub 4}S), and poly[({mu}-benzene-1,4-diselenolato)dithallium], Tl{sub 2}(SeC{sub 6}H{sub 4}Se), were solved by simulated annealing from high-resolution synchrotron X-ray powder diffraction. Rietveld refinements of an initial structure with one formula unit per triclinic cell gave satisfactory agreement with the data, but led to a structure with impossibly close non-bonded contacts. A disordered model was proposed to alleviate this problem, but an alternative supercell structure leads to slightly improved agreement with the data. The isostructural superlattice structures were confirmed for both compounds through additional data collection, with substantially better counting statistics, which revealed the presence of very weak superlattice peaks not previously seen. Overall, each structure contains Tl-S or Tl-Se two-dimensional networks, connected by phenylene bridges. The sulfur (or selenium) coordination sphere around each thallium is a highly distorted square pyramid or a 'see-saw' shape, depending upon how many Tl-S or Tl-Se interactions are considered to be bonds. In addition, the two compounds contain pairs of Tl{sup I} ions that interact through a closed-shell 'thallophilic' interaction: in the sulfur compound there are two inequivalent pairs of Tl atoms with Tl-Tl distances of 3.49 and 3.58 {angstrom}, while in the selenium compound those Tl-Tl interactions are at 3.54 and 3.63 {angstrom}.

  7. X-ray Surveys and Wide-Field Optical/Near-Infrared Imaging with the Joint Dark Energy Mission

    E-Print Network [OSTI]

    W. N. Brandt

    2004-07-22T23:59:59.000Z

    I briefly describe a few important scientific issues that could be addressed effectively via the combination of data from JDEM and X-ray missions. The topics covered are largely focused on active galactic nuclei (AGN) and include (1) the selection of AGN via X-ray emission and optical variability, (2) nuclear outbursts in galaxies due to transient fueling of their supermassive black holes, (3) moderate-luminosity AGN at high redshift (z > 4) found via application of "dropout" techniques to X-ray sources, and (4) the host-galaxy morphologies of X-ray selected AGN. I also describe the substantial challenges to obtaining wide-field X-ray data with sufficient sensitivity to complement JDEM properly.

  8. Spectroscopic and X-ray diffraction investigation of the behavior of hanksite and tychite at high pressures, and a model for the compressibility of sulfate minerals

    E-Print Network [OSTI]

    Palaich, SEM; Manning, CE; Schauble, E; Kavner, A

    2013-01-01T23:59:59.000Z

    Physics and Chemistry of Minerals, 37, 5, 265–282. Chen,and Smith, G.I. (1965) Mineral equilibria in the Searlesstudy of the behavior of mineral barite by X?ray dif-

  9. Capabilities and limitations of Phase Contrast Imaging techniques with X-rays and neutrons

    E-Print Network [OSTI]

    Damato, Antonio Leonardo

    2009-01-01T23:59:59.000Z

    Phase Contrast Imaging (PCI) was studied with the goal of understanding its relevance and its requirements. Current literature does not provide insight on the effect of a relaxation in coherence requirements on the PCI ...

  10. Reflection soft X-ray microscope and method

    DOE Patents [OSTI]

    Suckewer, S.; Skinner, C.H.; Rosser, R.

    1993-01-05T23:59:59.000Z

    A reflection soft X-ray microscope is provided by generating soft X-ray beams, condensing the X-ray beams to strike a surface of an object at a predetermined angle, and focusing the X-ray beams reflected from the surface onto a detector, for recording an image of the surface or near surface features of the object under observation.

  11. Quantitative X-Ray Imaging of Intraplaque Hemorrhage in Aortas of ApoE-/-/LDL-/- Double Knockout Mice

    SciTech Connect (OSTI)

    Langheinrich,A.; Michniewicz, A.; Sedding, D.; Lai, B.; Jorgensen, S.; Bohle, R.; Ritman, E.

    2007-01-01T23:59:59.000Z

    Objectives: To determine if hemorrhage into an arterial wall can be detected in CT images by virtue of the iron content. Materials and Methods: Aortas from male apoE-/-/LDL-/- mice (n = 31) were infused in situ with contrast agent, for micro-CT scanning and histology. Roentgen-opacities within the aortic walls were identified by histology and micro-x-ray fluorescence to be iron or calcium. Dual-energy scanning was performed at 2 energy levels using synchrotron-based micro-CT [(2 {mu}m)3 voxels, 16 and 20 keV] and 64-slice CT (0.4 x 0.4 x 0.6 mm voxels, 80 and 120 kVp). Results: Opacities were identified as hemorrhage-related clusters of multiple punctate deposits, containing both Fe (0.48 x 10-12 g/voxel) and Ca (3.18 x 10-2 g/voxel), or as isolated confluent accumulations of exclusively calcium. Subtraction of the dual-energy CT scans discriminated iron from calcium deposits. Conclusion: Detection and quantification of iron deposits in hemorrhaged atherosclerotic lesions is feasible by dual-energy CT imaging.

  12. Femtosecond diffractive imaging with a soft-X-ray free-electron laser

    E-Print Network [OSTI]

    Loss, Daniel

    Synchrotron Radiation Laboratory, Stanford Linear Accelerator Center, 2575 Sand Hill Road, Menlo Park the sample explodes and turns into a plasma. Here we report the first experimental demonstration-resolution scattering signals for such samples in conventional experiments11,12 . Damage is caused by energy deposited

  13. A high-resolution imaging x-ray crystal spectrometer for high energy density plasmas

    SciTech Connect (OSTI)

    Chen, Hui, E-mail: chen33@llnl.gov, E-mail: bitter@pppl.gov; Magee, E.; Nagel, S. R.; Park, J.; Schneider, M. B.; Stone, G.; Williams, G. J.; Beiersdorfer, P. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550-9234 (United States); Bitter, M., E-mail: chen33@llnl.gov, E-mail: bitter@pppl.gov; Hill, K. W. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Kerr, S. [Department of Applied Science, University of Alberta, Edmonton, Alberta T6G 2R3 (Canada)

    2014-11-15T23:59:59.000Z

    Adapting a concept developed for magnetic confinement fusion experiments, an imaging crystal spectrometer has been designed and tested for HED plasmas. The instrument uses a spherically bent quartz [211] crystal with radius of curvature of 490.8 mm. The instrument was tested at the Titan laser at Lawrence Livermore National Laboratory by irradiating titanium slabs with laser intensities of 10{sup 19}–10{sup 20} W/cm{sup 2}. He-like and Li-like Ti lines were recorded, from which the spectrometer performance was evaluated. This spectrometer provides very high spectral resolving power (E/dE > 7000) while acquiring a one-dimensional image of the source.

  14. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm)Hydrogen StorageITERITERBuilding EnergyImaging PrintImaging

  15. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm)Hydrogen StorageITERITERBuilding EnergyImagingImaging

  16. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging of4Lensless Imaging

  17. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenIT |Hot SpringsemployedImager Spots andImaging

  18. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenIT |Hot SpringsemployedImager SpotsImaging

  19. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenIT |Hot SpringsemployedImagerImaging Antifungal

  20. Multi-Material Decomposition Using Statistical Image Reconstruction in X-Ray CT

    E-Print Network [OSTI]

    Fessler, Jeffrey A.

    and Jeffrey A. Fessler Abstract--Dual-energy (DE) CT scans provide two sets of measurements at two different-mean-square (RMS) errors. Index Terms--Computed tomography, dual energy, multi- material decomposition, statistical image reconstruction I. INTRODUCTION Dual-energy (DE) CT reconstruction methods typically re- construct

  1. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm)Hydrogen StorageITERITERBuilding EnergyImaging

  2. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your HomeLatest News ReleasesDepartmentLending aLensless Imaging

  3. Lensless Imaging of Magnetic Nanostructures by X-ray Spectro-Holography

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging of4 J. Lüning, W.

  4. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging of4 J. Lüning,

  5. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging of4 J.

  6. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging of4 J.Lensless

  7. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging of4

  8. Lensless Imaging of Whole Biological Cells with Soft X-Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless Imaging of4Lensless

  9. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenIT |Hot SpringsemployedImager Spots and

  10. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenIT |Hot SpringsemployedImager Spots

  11. Imaging Antifungal Drug Molecules in Action using Soft X-Ray Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenIT |Hot SpringsemployedImager

  12. A Full-Field KB-FZP Microscope for Hard X-Ray Imaging with Sub-100 nm Resolution

    E-Print Network [OSTI]

    Braun, Paul

    , Germany, 6 BESSY GmbH, Albert-Einstein-Str.15, 12489 Berlin, Germany A full-field hard X-ray microscope was performed at the Advanced Photon Source (APS), a synchrotron radiation source of the third generation

  13. Element-specific imaging of magnetic domains at 25 nm spatial resolution using soft x-ray microscopy

    E-Print Network [OSTI]

    Bayreuther, Günther

    magnetic transmission x-ray microscopy M-TXM . This was first demonstrated at the synchrotron facility BESSY I in Berlin.8­10 In this article experiments with M-TXM obtained at the XM-1 beamline

  14. Comparison of the bubble size distribution in silicate foams using 2-dimensional images and 3-dimensional x-ray microtomography

    SciTech Connect (OSTI)

    Robert, G.; Baker, D.R.; Rivers, M.L.; Allard, E.; Larocque, J. (McGill); (UC)

    2005-02-03T23:59:59.000Z

    Three silicate glasses were hydrated at high pressure and then heated at atmospheric pressure to exsolve the water into bubbles and create foams. The bubble size distribution in these foams was measured by x-ray microtomography on the GSECARS BM-13 beamline at the Advanced Photon Source. The bubble area distributions were measured in two dimensions using the image slices produced from the microtomography and the software ImageJ. The bubble volume distributions were measured from the three-dimensional tomographic images with the BLOB3D software. We found that careful analysis of the microtomography data in both two and three dimensions was necessary to avoid the physically unrealistic, experimental artifact of identifying and counting many small bubbles whose surfaces were not defined by a septum of glass. When this artifact was avoided the foams demonstrated power-law distributions of bubble sizes in both two and three dimensions. Conversion of the power-law exponents for bubble areas measured in two dimensions to exponents for bubble volumes usually agreed with the measured three dimensional volume exponents. Furthermore, the power-law distributions for bubble volumes typically agree with multiple theories of bubble growth, all of which yield an exponent of 1 for the cumulative bubble volume distribution. The measured bubble volume distributions with exponents near 0.3 can be explained by diffusive growth as proposed by other authors, but distributions with exponents near 1.4 remain to be explained and are the subject of continuing research on the effects of water concentration and melt viscosity on foaming behavior.

  15. Broadband X-ray Imaging and Spectroscopy of the Crab Nebula and Pulsar with NuSTAR

    E-Print Network [OSTI]

    Madsen, Kristin K; Harrison, Fiona; An, Hongjun; Boggs, Steven; Christensen, Finn E; Craig, William W; Fryer, Chris L; Grefenstette, Brian W; Hailey, Charles J; Markwardt, Craig; Nynka, Melania; Stern, Daniel; Zoglauer, Andreas; Zhang, William

    2015-01-01T23:59:59.000Z

    We present broadband (3 -- 78 keV) NuSTAR X-ray imaging and spectroscopy of the Crab nebula and pulsar. We show that while the phase-averaged and spatially integrated nebula + pulsar spectrum is a power-law in this energy band, spatially resolved spectroscopy of the nebula finds a break at $\\sim$9 keV in the spectral photon index of the torus structure with a steepening characterized by $\\Delta\\Gamma\\sim0.25$. We also confirm a previously reported steepening in the pulsed spectrum, and quantify it with a broken power-law with break energy at $\\sim$12 keV and $\\Delta\\Gamma\\sim0.27$. We present spectral maps of the inner 100\\as\\ of the remnant and measure the size of the nebula as a function of energy in seven bands. These results find that the rate of shrinkage with energy of the torus size can be fitted by a power-law with an index of $\\gamma = 0.094\\pm 0.018$, consistent with the predictions of Kennel and Coroniti (1984). The change in size is more rapid in the NW direction, coinciding with the counter-jet w...

  16. Development of a High Resolution X-Ray Imaging Crystal Spectrometer for Measurement of Ion-Temperature and Rotation-Velocity Profiles in Fusion Energy Research Plasmas

    SciTech Connect (OSTI)

    Hill, K W; Broennimann, Ch; Eikenberry, E F; Ince-Cushman, A; Lee, S G; Rice, J E; Scott, S

    2008-02-27T23:59:59.000Z

    A new imaging high resolution x-ray crystal spectrometer (XCS) has been developed to measure continuous profiles of ion temperature and rotation velocity in fusion plasmas. Following proof-of-principle tests on the Alcator C-Mod tokamak and the NSTX spherical tokamak, and successful testing of a new silicon, pixilated detector with 1MHz count rate capability per pixel, an imaging XCS is being designed to measure full profiles of Ti and v? on C-Mod. The imaging XCS design has also been adopted for ITER. Ion-temperature uncertainty and minimum measurable rotation velocity are calculated for the C-Mod spectrometer. The affects of x-ray and nuclear-radiation background on the measurement uncertainties are calculated to predict performance on ITER.

  17. Development of a High Resolution X-Ray Imaging Crystal Spectrometer for Measurement of Ion-Temperature and Rotation-Velocity Profiles in Fusion Energy Research Plasmas

    SciTech Connect (OSTI)

    Hill, K W; Broennimann, Ch; Eikenberry, E F; Ince-Cushman, A; Lee, S G; Rice, J E; Scott, S

    2008-01-29T23:59:59.000Z

    A new imaging high resolution x-ray crystal spectrometer (XCS) has been developed to measure continuous profiles of ion temperature and rotation velocity in fusion plasmas. Following proof-of-principle tests on the Alcator C-Mod tokamak and the NSTX spherical tokamak, and successful testing of a new silicon, pixilated detector with 1 MHz count rate capability per pixel, an imaging XCS is being designed to measure full profiles of Ti and v? on C-Mod. The imaging XCS design has also been adopted for ITER. Ion-temperature uncertainty and minimum measurable rotation velocity are calculated for the C-Mod spectrometer. The affects of x-ray and uclear-radiation background on the measurement uncertainties are calculated to predict performance on ITER.

  18. X-ray Observations of Mrk 231

    E-Print Network [OSTI]

    T. J. Turner

    1998-08-10T23:59:59.000Z

    This paper presents new X-ray observations of Mrk 231, an active galaxy of particular interest due to its large infrared luminosity and the presence of several blueshifted broad absorption line (BAL) systems, a phenomenon observed in a small fraction of QSOs. A ROSAT HRI image of Mrk 231 is presented, this shows an extended region of soft X-ray emission, covering several tens of kpc, consistent with the extent of the host galaxy. An ASCA observation of Mrk 231 is also presented. Hard X-rays are detected but the data show no significant variability in X-ray flux. The hard X-ray continuum is heavily attenuated and X-ray column estimates range from ~ 2 x 10^{22} - 10^{23} cm^{-2} depending on whether the material is assumed to be neutral or ionized, and on the model assumed for the extended X-ray component. These ASCA data provide only the second hard X-ray spectrum of a BAL AGN presented to date. The broad-band spectral-energy-distribution of the source is discussed. While Mrk 231 is X-ray weak compared to Seyfert 1 galaxies, it has an optical-to-X-ray spectrum typical of a QSO.

  19. Experimental investigation of bright spots in broadband, gated x-ray images of ignition-scale implosions on the National Ignition Facility

    SciTech Connect (OSTI)

    Barrios, M. A.; Suter, L. J.; Glenn, S.; Benedetti, L. R.; Bradley, D. K.; Collins, G. W.; Hammel, B. A.; Izumi, N.; Ma, T.; Scott, H.; Smalyuk, V. A. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Regan, S. P.; Epstein, R. [Laboratory for Laser Energetics, University of Rochester 250 East River Road, Rochester, New York 14623-199 (United States)] [Laboratory for Laser Energetics, University of Rochester 250 East River Road, Rochester, New York 14623-199 (United States); Kyrala, G. A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2013-07-15T23:59:59.000Z

    Bright spots in the hot spot intensity profile of gated x-ray images of ignition-scale implosions at the National Ignition Facility [G. H. Miller et al., Opt. Eng. 443, (2004)] are observed. X-ray images of cryogenically layered deuterium-tritium (DT) and tritium-hydrogen-deuterium (THD) ice capsules, and gas filled plastic shell capsules (Symcap) were recorded along the hohlraum symmetry axis. Heterogeneous mixing of ablator material and fuel into the hot spot (i.e., hot-spot mix) by hydrodynamic instabilities causes the bright spots. Hot-spot mix increases the radiative cooling of the hot spot. Fourier analysis of the x-ray images is used to quantify the evolution of bright spots in both x- and k-space. Bright spot images were azimuthally binned to characterize bright spot location relative to known isolated defects on the capsule surface. A strong correlation is observed between bright spot location and the fill tube for both Symcap and cryogenically layered DT and THD ice targets, indicating the fill tube is a significant seed for the ablation front instability causing hot-spot mix. The fill tube is the predominant seed for Symcaps, while other capsule non-uniformities are dominant seeds for the cryogenically layered DT and THD ice targets. A comparison of the bright spot power observed for Si- and Ge-doped ablator targets shows heterogeneous mix in Symcap targets is mostly material from the doped ablator layer.

  20. Sensing the wavefront of x-ray free-electron lasers using aerosol spheres

    SciTech Connect (OSTI)

    Loh, N.Duane; Starodub, Dimitri; Lomb, Lukas; Hampton, Christina Y.; Martin, Andrew V.; Sierra, Raymond G.; Barty, Anton; Aquila, Andrew; Schulz, Joachim; Steinbrener, Jan; Shoeman, Robert L.; Kassemeyer, Stephan; Bostedt, Christoph; Bozek, John; Epp, Sascha W.; Erk, Benjamin; Hartmann, Robert; Rolles, Daniel; Rudenko, Artem; Rudek, Benedikt; Foucar, Lutz

    2014-04-22T23:59:59.000Z

    Characterizing intense, focused x-ray free electron laser (FEL) pulses is crucial for their use in diffractive imaging. We describe how the distribution of average phase tilts and intensities on hard x-ray pulses with peak intensities of 10 21 W/m2 can be retrieved from an ensemble of diffraction patterns produced by 70 nm-radius polystyrene spheres, in a manner that mimics wave-front sensors. Besides showing that an adaptive geometric correction may be necessary for diffraction data from randomly injected sample sources, the paper demonstrates the possibility of collecting statistics on structured pulses using only the diffraction patterns they generate and highlights the imperative to study its impact on single-particle diffractive imaging.

  1. X-ray spectrometry

    SciTech Connect (OSTI)

    Markowicz, A.A.; Van Grieken, R.E.

    1986-04-01T23:59:59.000Z

    In the period under review, i.e, through 1984 and 1985, some 600 articles on XRS (X-ray spectrometry) were published; most of these have been scanned and the most fundamental ones are discussed. All references will refer to English-language articles, unless states otherwise. Also general books have appeared on quantitative EPXMA (electron-probe X-ray microanalysis) and analytical electron microscopy (AEM) as well as an extensive review on the application of XRS to trace analysis of environmental samples. In the period under review no radically new developments have been seen in XRS. However, significant improvements have been made. Gain in intensities has been achieved by more efficient excitation, higher reflectivity of dispersing media, and better geometry. Better understanding of the physical process of photon- and electron-specimen interactions led to complex but more accurate equations for correction of various interelement effects. Extensive use of micro- and minicomputers now enables fully automatic operation, including qualitative analysis. However, sample preparation and presentation still put a limit to further progress. Although some authors find XRS in the phase of stabilization or even stagnation, further gradual developments are expected, particularly toward more dedicated equipment, advanced automation, and image analysis systems. Ways are outlined in which XRS has been improved in the 2 last years by excitation, detection, instrumental, methodological, and theoretical advances. 340 references.

  2. E-Print Network 3.0 - aspect ratio x-ray Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0953-89841825S17 Summary: the power ratio of beam splitting. With centralized remote control, heating and x-ray diffraction... for in situ x-ray diffraction at high...

  3. Aberration-corrected X-ray spectrum imaging and Fresnel contrast to differentiate nanoclusters and cavities in helium-irradiated alloy 14YWT

    SciTech Connect (OSTI)

    Miller, Michael K [ORNL] [ORNL; Parish, Chad M [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Helium accumulation negatively impacts structural materials used in neutron-irradiated environments, such as fission and fusion reactors. Next-generation fission and fusion reactors will require structural materials, such as steels, resistant to large neutron doses yet see service temperatures in the range most affected by helium embrittlement. Previous work has indicated the difficulty of experimentally differentiating nanometer-sized helium bubbles from the Ti-Y-O rich nanoclustsers (NCs) in radiation-tolerant nanostructured ferritic alloys (NFAs). Because the NCs are expected to sequester helium away from grain boundaries and reduce embrittlement, experimental methods to study simultaneously the NC and bubble populations are needed. In this study, aberration-corrected scanning transmission electron microscopy (STEM) results combining high-collection-efficiency X-ray spectrum images (SIs), multivariate statistical analysis (MVSA), and Fresnel-contrast bright-field STEM imaging have been used for such a purpose. Results indicate that Fresnel-contrast imaging, with careful attention to TEM-STEM reciprocity, differentiates bubbles from NCs, and MVSA of X-ray SIs unambiguously identifies NCs. Therefore, combined Fresnel-contrast STEM and X-ray SI is an effective STEM-based method to characterize helium-bearing NFAs.

  4. Monte Carlo study for optimal conditions in single-shot imaging with femtosecond x-ray laser pulses

    SciTech Connect (OSTI)

    Park, Jaehyun; Ishikawa, Tetsuya; Song, Changyong [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan)] [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan); Joti, Yasumasa [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan)] [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan)

    2013-12-23T23:59:59.000Z

    Intense x-ray pulses from x-ray free electron lasers (XFELs) enable the unveiling of atomic structure in material and biological specimens via ultrafast single-shot exposures. As the radiation is intense enough to destroy the sample, a new sample must be provided for each x-ray pulse. These single-particle delivery schemes require careful optimization, though systematic study to find such optimal conditions is still lacking. We have investigated two major single-particle delivery methods: particle injection as flying objects and membrane-mount as fixed targets. The optimal experimental parameters were searched for via Monte Carlo simulations to discover that the maximum single-particle hit rate achievable is close to 40%.

  5. X-ray diffraction on the X-cut of a Ca{sub 3}TaGa{sub 3}Si{sub 2}O{sub 14} single crystal modulated by a surface acoustic wave

    SciTech Connect (OSTI)

    Irzhak, D., E-mail: irzhak@iptm.ru; Roshchupkin, D., E-mail: rochtch@iptm.ru [Institute of Microelectronics Technology and High-Purity Materials Russian Academy of Sciences, Chernogolovka 142432 (Russian Federation)

    2014-06-28T23:59:59.000Z

    The result of X-ray diffraction study on a single crystal of the calcium-gallogermanate family Ca{sub 3}TaGa{sub 3}Si{sub 2}O{sub 14} (CTGS) modulated by a surface acoustic wave (SAW) is presented. The power flow angle for SAW propagating along the X{sub 2} axis of the X-cut in CTGS was measured. The rocking curves for the CTGS crystal were recorded at different amplitudes of an input high frequency electric signal on interdigital transducer used to excite a SAW. Based on the data obtained, intensity dependence of diffraction satellites on the amplitude of electric signal exciting a SAW was built. Numerical simulation of the crystal rocking curves and dependence of diffraction satellite intensities on the SAW amplitude enabled the selection of a set of material constants at which the most complete coincidence of experimental and calculated results is observed.

  6. X-ray microscopy using grazing-incidence reflections optics

    SciTech Connect (OSTI)

    Price, R.H.

    1983-06-30T23:59:59.000Z

    The role of Kirkpatrick-Baez microscopes as the workhorse of the x-ray imaging devices is discussed. This role is being extended with the development of a 22X magnification Kirkpatrick-Baez x-ray microscope with multilayer x-ray mirrors. These mirrors can operate at large angles, high x-ray energies, and have a narrow, well defined x-ray energy bandpass. This will make them useful for numerous experiments. However, where a large solid angle is needed, the Woelter microscope will still be necessary and the technology needed to build them will be useful for many other types of x-ray optics.

  7. X-ray microscopy using grazing-incidence reflection optics

    SciTech Connect (OSTI)

    Price, R.H.

    1981-08-06T23:59:59.000Z

    The Kirkpatrick-Baez microscopes are described along with their role as the workhorse of the x-ray imaging devices. This role is being extended with the development of a 22X magnification Kirkpatrick-Baez x-ray microscope with multilayer x-ray mirrors. These mirrors can operate at large angles, high x-ray energies, and have a narrow, well defined x-ray energy bandpass. This will make them useful for numerous experiments. However, where a large solid angle is needed, the Woelter microscope will still be necessary and the technology needed to build them will be useful for many other types of x-ray optics.

  8. Chest x-Rays

    Broader source: Energy.gov [DOE]

    The B-reading is a special reading of a standard chest x-ray film performed by a physician certified by the National Institute for Occupational Safety and Health (NIOSH). The reading looks for changes on the chest x-ray that may indicate exposure and disease caused by agents such as asbestos or silica.

  9. Quantum Model of Catalysis Based on a Mobile Proton Revealed by Subatomic X-ray and Neutron Diffraction Studies of h-aldose Reductase

    SciTech Connect (OSTI)

    Blakeley, M. P. [European Molecular Biology Laboratory (EMBL), France; Ruiz, Fredrico [Institut de Genetique et de Biologie Moleculaire et Cellulaire, CNRS, ULP, INSER; Cachau, Raul [SAIC-Frederick, Inc., National Cancer Institute at Frederick, Frederick, MD; Hazemann, I. [Institut Laue-Langevin (ILL); Meilleur, Flora [Institut Laue-Langevin (ILL); Mitschler, A. [IGBMC; Ginell, Stephan [Argonne National Laboratory (ANL); Afonine, Pavel [Lawrence Berkeley National Laboratory (LBNL); Ventura, Oscar [Computational Chemical Physics Group, DETEMA, Facultad de Quimica, UdelaR, C.C.1; Cousido-Siah, Alexandra [Institut de Genetique et de Biologie Moleculaire et Cellulaire, CNRS, ULP, INSER; Haertlein, M. [Institut Laue-Langevin (ILL); Joachimiak, Andrzej [Argonne National Laboratory (ANL); Myles, Dean A A [ORNL; Podjarny, A. [IGBMC

    2008-01-01T23:59:59.000Z

    We present results of combined studies of the enzyme human aldose reductase (h-AR, 36 kDa) using single-crystal x-ray data (0.66 Angstroms, 100K; 0.80 Angstroms, 15K; 1.75 Angstroms, 293K), neutron Laue data (2.2 Angstroms, 293K), and quantum mechanical modeling. These complementary techniques unveil the internal organization and mobility of the hydrogen bond network that defines the properties of the catalytic engine, explaining how this promiscuous enzyme overcomes the simultaneous requirements of efficiency and promiscuity offering a general mechanistic view for this class of enzymes.

  10. Note: Design and construction of a multi-scale, high-resolution, tube-generated X-Ray computed-tomography system for three-dimensional (3D) imaging

    SciTech Connect (OSTI)

    Mertens, J. C. E.; Williams, J. J.; Chawla, Nikhilesh [Materials Science and Engineering, Security and Defense Systems Initiative, Arizona State University, 781 E. Terrace Road, ISTB4, Tempe, Arizona 85287-5604 (United States)] [Materials Science and Engineering, Security and Defense Systems Initiative, Arizona State University, 781 E. Terrace Road, ISTB4, Tempe, Arizona 85287-5604 (United States)

    2014-01-15T23:59:59.000Z

    The design and construction of a high resolution modular x-ray computed tomography (XCT) system is described. The approach for meeting a specified set of performance goals tailored toward experimental versatility is highlighted. The instrument is unique in its detector and x-ray source configuration, both of which enable elevated optimization of spatial and temporal resolution. The process for component selection is provided. The selected components are specified, the custom component design discussed, and the integration of both into a fully functional XCT instrument is outlined. The novelty of this design is a new lab-scale detector and imaging optimization through x-ray source and detector modularity.

  11. SU-E-J-83: Ion Imaging to Better Estimate In-Vivo Relative Stopping Powers Using X-Ray CT Prior-Knowledge Information

    SciTech Connect (OSTI)

    Dias, M [Dipartamento di Elettronica, Informazione e Bioingegneria - DEIB, Politecnico di Milano (Italy); Massachusetts General Hospital, Boston, MA (United States); Collins-Fekete, C [Massachusetts General Hospital, Boston, MA (United States); Departement de physique, de genie physique et d'optique et Centre de recherche sur le cancer, Universite Laval, Quebec (Canada); Riboldi, M; Baroni, G [Dipartamento di Elettronica, Informazione e Bioingegneria - DEIB, Politecnico di Milano (Italy); Doolan, P [Massachusetts General Hospital, Boston, MA (United States); University College London, London (United Kingdom); Hansen, D [Experimental Clinical Oncology, Aarhus University, 8000 Aarhus C (Denmark); Seco, J [Massachusetts General Hospital, Boston, MA (United States)

    2014-06-01T23:59:59.000Z

    Purpose: To reduce uncertainties in relative stopping power (RSP) estimates for ions (alpha and carbon) by using Ion radiographic-imaging and X-ray CT prior-knowledge. Methods: A 36×36 phantom matrix composed of 9 materials with different thicknesses and randomly placed is generated. Theoretical RSPs are calculated using stopping power (SP) data from three references (Janni, ICRU49 and Bischel). We introduced an artificial systematic error (1.5%, 2.5% or 3.5%) and a random error (<0.5%) to the SP to simulated patient ion-range errors present in clinic environment. Carbon/alpha final energy for each RSPs set (theoretical and from CT images) is obtained with a ray-tracing algorithm. A gradient descent (GD) method is used to minimize the difference in exit particle energy, between theory and X-ray CT RSP maps, by iteratively correcting the RSP map from X-ray CT. Once a new set of RSPs is obtained for a direction a new optimization is done over other direction using the RSPs from the previous optimization. Theoretical RSPs are compared with experimental RSPs obtained with Gammex Phantom. Results: Preliminary results show that optimized RSP values can be obtained with smaller uncertainties (<1%) than clinical RSPs (1.5% to 3.5%). Theoretical values from three different references show uncertainties, up to 3% from experimental values. Further investigation will consider prior-knowledge from RSP obtained with CT images and ion radiographies from Monte Carlo Simulations. Conclusion: GD and ray-tracing methods have been implemented to reduce RSP uncertainties from values obtained for clinical treatment. Experimental RSPs will be obtained using carbon/alpha beams to consider the existence of material dependent systematic errors. Based on the results, it is hoped to show that using ray-tracing optimization with ion radiography and prior knowledge on RPSs, treatment planning accuracy and cost-effectiveness can be improved.

  12. Theoretical standards in x-ray spectroscopies

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    We propose to extend our state-of-the-art, ab initio XAFS (X-ray absorption fine structure) codes, FEFF. Our current work has been highly successful in achieving accurate, user-friendly XAFS standards, exceeding the performance of both tabulated standards and other codes by a considerable margin. We now propose to add the capability to treat more complex materials. This includes multiple-scattering, polarization dependence, an approximate treatment of XANES (x-ray absorption near edge structure), and other improvements. We also plan to adapt FEFF to other spectroscopies, e.g. photoelectron diffraction (PD) and diffraction anomalous fine structure (DAFS).

  13. Measurement of core plasma temperature and rotation on W7-X made available by the x-ray imaging crystal spectrometer (XICS)

    SciTech Connect (OSTI)

    Pablant, N A; Bitter, M; Burhenn, R; Delgado-Aparicio, L; Ellis, R; Gates, D; Goto, M; Hill, K W; Langenberg, A; Lazerson, S; Mardenfeld, M; Morita, S; Neilson, G H; Oishi, T; Pedersen, T S

    2014-07-01T23:59:59.000Z

    A new x-ray imaging crystal spectrometer diagnostic (XICS) is currently being built for installation on W7-X. This diagnostic will contribute to the study of ion and electron thermal transport and the evolution of the radial electric field by providing high resolution temperature and rotation measurements under many plasma conditions, including ECH heated plasmas. Installation is expected before the first experimental campaign (OP1.1), making an important set of measurements available for the first W7-X plasmas. This diagnostic will also work in concert with the HR-XCS diagnostic to provide an excellent diagnostic set for core impurity transport on W7-X.

  14. X-ray laser

    DOE Patents [OSTI]

    Nilsen, Joseph (Livermore, CA)

    1991-01-01T23:59:59.000Z

    An X-ray laser (10) that lases between the K edges of carbon and oxygen, i.e. between 44 and 23 Angstroms, is provided. The laser comprises a silicon (12) and dysprosium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state nickel-like dysprosium ions (34) are resonantly photo-pumped to their upper X-ray laser state by line emission from hydrogen-like silicon ions (32). The novel X-ray laser should prove especially useful for the microscopy of biological specimens.

  15. Ray tracing flux calculation for the small and wide angle x-ray scattering diffraction station at the SESAME synchrotron radiation facility

    SciTech Connect (OSTI)

    Salah, Wa'el [Synchrotron-light for Experimental Science and Application in the Middle East (SESAME), P.O. Box 7, Allan 19252 (Jordan); Department of Physics, The Hashemite University, Zarqa 13115 (Jordan); Sanchez del Rio, M. [European Synchrotron Radiation Facility, Bp 220, 38043 Grenoble Cedex (France); Hoorani, H. [Synchrotron-light for Experimental Science and Application in the Middle East (SESAME), P.O. Box 7, Allan 19252 (Jordan)

    2009-09-15T23:59:59.000Z

    The calculation for the optics of the synchrotron radiation small and wide angle x-ray scattering beamline, currently under construction at SESAME is described. This beamline is based on a cylindrically bent germanium (111) single crystal with an asymmetric cut of 10.5 deg., followed by a 1.2 m long rhodium coated plane mirror bent into a cylindrical form. The focusing properties of bent asymmetrically cut crystals have not yet been studied in depth. The present paper is devoted to study of a particular application of a bent asymmetrically cut crystal using ray tracing simulations with the SHADOW code. These simulations show that photon fluxes of order of 1.09x10{sup 11} photons/s will be available at the experimental focus at 8.79 keV. The focused beam dimensions will be 2.2 mm horizontal full width at half maximum (FWHM) by 0.12 mm vertical (FWHM).

  16. SU-C-18C-02: Specifcation of X-Ray Projection Angles Which Are Aligned with the Aortic Valve Plane From a Planar Image of a Valvuloplasty Balloon Inflated Across the Aortic Valve

    SciTech Connect (OSTI)

    Fetterly, K; Mathew, V [Mayo Clinic, Rochester, MN (United States)

    2014-06-01T23:59:59.000Z

    Purpose: Transcatheter aortic valve replacement (TAVR) procedures provide a method to implant a prosthetic aortic valve via a minimallyinvasive, catheter-based procedure. TAVR procedures require use of interventional fluoroscopy c-arm projection angles which are aligned with the aortic valve plane to minimize prosthetic valve positioning error due to x-ray imaging parallax. The purpose of this work is to calculate the continuous range of interventional fluoroscopy c-arm projection angles which are aligned with the aortic valve plane from a single planar image of a valvuloplasty balloon inflated across the aortic valve. Methods: Computational methods to measure the 3D angular orientation of the aortic valve were developed. Required inputs include a planar x-ray image of a known valvuloplasty balloon inflated across the aortic valve and specifications of x-ray imaging geometry from the DICOM header of the image. A-priori knowledge of the species-specific typical range of aortic orientation is required to specify the sign of the angle of the long axis of the balloon with respect to the x-ray beam. The methods were validated ex-vivo and in a live pig. Results: Ex-vivo experiments demonstrated that the angular orientation of a stationary inflated valvuloplasty balloon can be measured with precision less than 1 degree. In-vivo pig experiments demonstrated that cardiac motion contributed to measurement variability, with precision less than 3 degrees. Error in specification of x-ray geometry directly influences measurement accuracy. Conclusion: This work demonstrates that the 3D angular orientation of the aortic valve can be calculated precisely from a planar image of a valvuloplasty balloon inflated across the aortic valve and known x-ray geometry. This method could be used to determine appropriate c-arm angular projections during TAVR procedures to minimize x-ray imaging parallax and thereby minimize prosthetic valve positioning errors.

  17. X-Ray Nanoimaging: Instruments and Methods

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-Ray ImagingX-Ray

  18. X-ray phase contrast imaging of biological specimens with femtosecond pulses of betatron radiation from a compact laser plasma wakefield accelerator

    SciTech Connect (OSTI)

    Kneip, S. [Blackett Laboratory, Imperial College London, London SW7 2AZ (United Kingdom); Center for Ultrafast Optical Science, University of Michigan, Ann Arbor 48109 (United States); McGuffey, C.; Dollar, F.; Chvykov, V.; Kalintchenko, G.; Krushelnick, K.; Maksimchuk, A.; Mangles, S. P. D.; Matsuoka, T.; Schumaker, W.; Thomas, A. G. R.; Yanovsky, V. [Center for Ultrafast Optical Science, University of Michigan, Ann Arbor 48109 (United States); Bloom, M. S.; Najmudin, Z.; Palmer, C. A. J.; Schreiber, J. [Blackett Laboratory, Imperial College London, London SW7 2AZ (United Kingdom)

    2011-08-29T23:59:59.000Z

    We show that x-rays from a recently demonstrated table top source of bright, ultrafast, coherent synchrotron radiation [Kneip et al., Nat. Phys. 6, 980 (2010)] can be applied to phase contrast imaging of biological specimens. Our scheme is based on focusing a high power short pulse laser in a tenuous gas jet, setting up a plasma wakefield accelerator that accelerates and wiggles electrons analogously to a conventional synchrotron, but on the centimeter rather than tens of meter scale. We use the scheme to record absorption and phase contrast images of a tetra fish, damselfly and yellow jacket, in particular highlighting the contrast enhancement achievable with the simple propagation technique of phase contrast imaging. Coherence and ultrafast pulse duration will allow for the study of various aspects of biomechanics.

  19. Ultra-short wavelength x-ray system

    DOE Patents [OSTI]

    Umstadter, Donald (Ann Arbor, MI); He, Fei (Ann Arbor, MI); Lau, Yue-Ying (Potomac, MD)

    2008-01-22T23:59:59.000Z

    A method and apparatus to generate a beam of coherent light including x-rays or XUV by colliding a high-intensity laser pulse with an electron beam that is accelerated by a synchronized laser pulse. Applications include x-ray and EUV lithography, protein structural analysis, plasma diagnostics, x-ray diffraction, crack analysis, non-destructive testing, surface science and ultrafast science.

  20. Absence of Structural Impact of Noble Nanoparticles on P3HT: PCBM Blends for Plasmon Enhanced Bulk-Heterojunction Organic Solar Cells Probed by Synchrotron Grazing Incidence X-Ray Diffraction

    E-Print Network [OSTI]

    Samuele Lilliu; Mejd Alsari; Oier Bikondoa; J. Emyr Macdonald; Marcus S. Dahlem

    2014-10-18T23:59:59.000Z

    The incorporation of noble metal nanoparticles, displaying localized surface plasmon resonance, in the active area of donor-acceptor bulk-heterojunction organic photovoltaic devices is an industrially compatible light trapping strategy, able to guarantee better absorption of the incident photons and give an efficiency improvement between 12% and 38%. In the present work, we investigate the effect of Au and Ag nanoparticles blended with P3HT: PCBM on the P3HT crystallization dynamics by synchrotron grazing incidence X-ray diffraction. We conclude that the presence of (1) 80nm Au, (2) mix of 5nm, 50nm, 80nm Au, (3) 40nm Ag, and (4) 10nm, 40nm, 60nm Ag colloidal nanoparticles, at different concentrations below 0.3 wt% in P3HT: PCBM blends, does not affect the behaviour of the blends themselves.

  1. X-Ray diffraction and vibrational spectroscopic study of 2-chloro-N-{l_brace}4-[3-(2,5-dimethylphenyl)-3-methylcyclobutyl] -thiazol-2-yl{r_brace}-acetamide

    SciTech Connect (OSTI)

    Caliskan, Nezihe, E-mail: nezihec@omu.edu.tr; Guentepe, Feyizan [Ondokuz Mayis University, Department of Physics, Faculty of Arts and Sciences (Turkey); Yueksektepe, Cigdem [Cankiri Karatekin University, Department of Physics, Faculty of Science (Turkey); Cukurovali, Alaaddin [Firat University, Department of Chemistry, Faculty of Science (Turkey); Bueyuekguengoer, Orhan [Ondokuz Mayis University, Department of Physics, Faculty of Arts and Sciences (Turkey)

    2010-12-15T23:59:59.000Z

    The title compound C{sub 18}H{sub 21}ClN{sub 2}SO crystallizes with Z = 4 in space group P2{sub 1}/c. The structure of the title compound was characterized by {sup 1}H-NMR, {sup 13}C-NMR, IR and single crystal diffraction. There are an intermolecular N-H-O hydrogen bond and a C-H-{pi} interactions in crystal packing. In addition to the molecular geometry and packing obtained from X-ray experiment, the molecular geometry and vibrational frequencies of the title compound in ground state have been calculated using density functional theory method DFT (B3LYP) with 6-31G (d, p) basis set. Calculated frequencies, bond lengths, angles and dihedral angles are in good agreement with the corresponding experimental data.

  2. In situ X-ray diffraction strain-controlled study of Ti–Nb–Zr and Ti–Nb–Ta shape memory alloys: crystal lattice and transformation features

    SciTech Connect (OSTI)

    Dubinskiy, S. [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Prokoshkin, S. [National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Brailovski, V., E-mail: vladimir.brailovski@etsmtl.ca [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Inaekyan, K. [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Korotitskiy, A. [National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation)

    2014-02-15T23:59:59.000Z

    Phase and structure transformations in biomedical Ti–21.8Nb–6.0Zr (TNZ) and Ti–19.7Nb–5.8Ta (TNT) shape memory alloys (at.%) under and without load in the ? 150 to 100 °S temperature range are studied in situ using an original tensile module for a low-temperature chamber of an X-ray diffractometer. Alpha?- and beta-phase lattice parameters, the crystallographic resource of recovery strain, phase and structure transformation sequences, and microstress appearance and disappearance are examined, compared and discussed. For both alloys, the crystallographic resource of recovery strain decreases with temperature increase to become 4.5% for TNZ and 2.5% for TNT alloy (at RT). Loading at low temperatures leads to additional ??-phase formation and reorientation. Heating under load, as compared to strain-free heating, affects the reverse transformation sequence of both alloys in different ways. For TNZ alloy, strain-free heating results in simultaneous ??? and ???? transformations, whereas during heating under stress, they are sequential: ? + ???? precedes ????. For TNT alloy, strain-free heating results in reverse ???? transformation, whereas during heating under stress, ???? transformation is preceded by ??-phase reorientation. - Highlights: • Comparative in situ XRD analysis of Ti–Nb–Zr(Ta) shape memory alloys is realized. • Lattice parameters of ?- and ??-phases are calculated in the ? 150 to + 100 °C range. • The higher the temperature, the lower the ???? transformation strain. • Loading at low temperatures results in ??-phase formation and reorientation. • Transformation sequences upon heating with and without loading are different.

  3. Development of procedures for refurbishing x-ray optics at the Advanced Light Source

    E-Print Network [OSTI]

    Yashchuk, Valeriy V.

    2013-01-01T23:59:59.000Z

    and Setting of Bendable Optics for Diffraction- Limitedof Soft X-Rays,” Abstract to SPIE Optics and Photonics 2012,Metrology for X-Ray and EUV Optics IV (San Diego, August 12-

  4. Development of at-wavelength metrology for x-ray optics at the ALS

    E-Print Network [OSTI]

    Yashchuk, Valeriy V.

    2010-01-01T23:59:59.000Z

    alignment of bendable x-ray optics to realize diffraction-Bass (Ed. ), Handbook of Optics, third ed. , vol. V, ch. 46,wavelength metrology for x-ray optics at the ALS* Valeriy V.

  5. In situ synchrotron based x-ray techniques as monitoring tools for atomic layer deposition

    SciTech Connect (OSTI)

    Devloo-Casier, Kilian, E-mail: Kilian.DevlooCasier@Ugent.be; Detavernier, Christophe; Dendooven, Jolien [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Ghent (Belgium); Ludwig, Karl F. [Physics Department, Boston University, 590 Commonwealth Avenue, Boston, Massachusetts 02215 (United States)

    2014-01-15T23:59:59.000Z

    Atomic layer deposition (ALD) is a thin film deposition technique that has been studied with a variety of in situ techniques. By exploiting the high photon flux and energy tunability of synchrotron based x-rays, a variety of new in situ techniques become available. X-ray reflectivity, grazing incidence small angle x-ray scattering, x-ray diffraction, x-ray fluorescence, x-ray absorption spectroscopy, and x-ray photoelectron spectroscopy are reviewed as possible in situ techniques during ALD. All these techniques are especially sensitive to changes on the (sub-)nanometer scale, allowing a unique insight into different aspects of the ALD growth mechanisms.

  6. Femtosecond X-ray protein nanocrystallography

    SciTech Connect (OSTI)

    Chapman, Henry N.; Fromme, Petra; Barty, Anton; White, Thomas A.; Kirian, Richard A.; Aquila, Andrew; Hunter, Mark S.; Schulz, Joachim; DePonte, Daniel P.; Weierstall, Uwe; Doak, R. Bruce; Maia, Filipe R. N. C.; Martin, Andrew V.; Schlichting, Ilme; Lomb, Lukas; Coppola, Nicola; Shoeman, Robert L.; Epp, Sascha W.; Hartmann, Robert; Rolles, Daniel; Rudenko, Artem; Foucar, Lutz; Kimmel, Nils; Weidenspointner, Georg; Holl, Peter; Liang, Mengning; Barthelmess, Miriam; Caleman, Carl; Boutet, Sebastien; Bogan, Michael J.; Krzywinski, Jacek; Bostedt, Christoph; Bajt, Sasa; Gumprecht, Lars; Rudek, Benedikt; Erk, Benjamin; Schmidt, Carlo; Homke, Andre; Reich, Christian; Pietschner, Daniel; Struder, Lothar; Hauser, Gunter; Gorke, Hubert; Ullrich, Joachim; Herrmann, Sven; Schaller, Gerhard; Schopper, Florian; Soltau, Heike; Kuhnel, Kai-Uwe; Messerschmidt, Marc; Bozek, John D.; Hau-Riege, Stefan P.; Frank, Matthias; Hampton, Christina Y.; Sierra, Raymond G.; Starodub, Dmitri; Williams, Garth J.; Hajdu, Janos; Timneanu, Nicusor; Seibert, M. Marvin; Andreasson, Jakob; Rocker, Andrea; Jonsson, Olof; Svenda, Martin; Stern, Stephan; Nass, Karol; Andritschke, Robert; Schroter, Claus-Dieter; Krasniqi, Faton; Bott, Mario; Schmidt, Kevin E.; Wang, Xiaoyu; Grotjohann, Ingo; Holton, James M.; Barends, Thomas R. M.; Neutze, Richard; Marchesini, Stefano; Fromme, Raimund; Schorb, Sebastian; Rupp, Daniela; Adolph, Marcus; Gorkhover, Tais; Andersson, Inger; Hirsemann, Helmut; Potdevin, Guillaume; Graafsma, Heinz; Nilsson, Bjorn; Spence, John C. H.

    2011-01-01T23:59:59.000Z

    X-ray crystallography provides the vast majority of macromolecular structures, but the success of the method relies on growing crystals of sufficient size. In conventional measurements, the necessary increase in X-ray dose to record data from crystals that are too small leads to extensive damage before a diffraction signal can be recorded. It is particularly challenging to obtain large, well-diffracting crystals of membrane proteins, for which fewer than 300 unique structures have been determined despite their importance in all living cells. Here we present a method for structure determination where single-crystal X-ray diffraction ‘snapshots’ are collected from a fully hydrated stream of nanocrystals using femtosecond pulses from a hard-X-ray free-electron laser, the Linac Coherent Light Source. We prove this concept with nanocrystals of photosystem I, one of the largest membrane protein complexes. More than 3,000,000 diffraction patterns were collected in this study, and a three-dimensional data set was assembled from individual photosystem I nanocrystals (~200?nm to 2??m in size). We mitigate the problem of radiation damage in crystallography by using pulses briefer than the timescale of most damage processes. This offers a new approach to structure determination of macromolecules that do not yield crystals of sufficient size for studies using conventional radiation sources or are particularly sensitive to radiation damage.

  7. X-ray beam finder

    DOE Patents [OSTI]

    Gilbert, H.W.

    1983-06-16T23:59:59.000Z

    An X-ray beam finder for locating a focal spot of an X-ray tube includes a mass of X-ray opaque material having first and second axially-aligned, parallel-opposed faces connected by a plurality of substantially identical parallel holes perpendicular to the faces and a film holder for holding X-ray sensitive film tightly against one face while the other face is placed in contact with the window of an X-ray head.

  8. X-ray source for mammography

    DOE Patents [OSTI]

    Logan, Clinton M. (Pleasanton, CA)

    1994-01-01T23:59:59.000Z

    An x-ray source utilizing anode material which shifts the output spectrum to higher energy and thereby obtains higher penetrating ability for screening mammography application, than the currently utilized anode material. The currently used anode material (molybdenum) produces an energy x-ray spectrum of 17.5/19.6 keV, which using the anode material of this invention (e.g. silver, rhodium, and tungsten) the x-ray spectrum would be in the 20-35 keV region. Thus, the anode material of this invention provides for imaging of breasts with higher than average x-ray opacity without increase of the radiation dose, and thus reduces the risk of induced breast cancer due to the radiation dose administered for mammograms.

  9. X-ray grid-detector apparatus

    DOE Patents [OSTI]

    Boone, John M. (Folsom, CA); Lane, Stephen M. (Oakland, CA)

    1998-01-27T23:59:59.000Z

    A hybrid grid-detector apparatus for x-ray systems wherein a microchannel plate structure has an air-interspaced grid portion and a phosphor/optical fluid-filled grid portion. The grids are defined by multiple adjacent channels separated by lead-glass septa. X-rays entering the air-interspaced grid portion at an angle of impingement upon the septa are attenuated, while non-impinging x-rays pass through to the phosphor/fluid filled portion. X-ray energy is converted to luminescent energy in the phosphor/fluid filled portion and the resultant beams of light are directed out of the phosphor/optical fluid filled portion to an imaging device.

  10. X-ray source for mammography

    DOE Patents [OSTI]

    Logan, C.M.

    1994-12-20T23:59:59.000Z

    An x-ray source is described utilizing anode material which shifts the output spectrum to higher energy and thereby obtains higher penetrating ability for screening mammography application, than the currently utilized anode material. The currently used anode material (molybdenum) produces an energy x-ray spectrum of 17.5/19.6 keV, which using the anode material of this invention (e.g. silver, rhodium, and tungsten) the x-ray spectrum would be in the 20-35 keV region. Thus, the anode material of this invention provides for imaging of breasts with higher than average x-ray opacity without increase of the radiation dose, and thus reduces the risk of induced breast cancer due to the radiation dose administered for mammograms. 6 figures.

  11. X-Ray Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-Ray Diagnostics X-Ray

  12. Dose, exposure time, and resolution in Serial X-ray Crystallography

    SciTech Connect (OSTI)

    Starodub, D; Rez, P; Hembree, G; Howells, M; Shapiro, D; Chapman, H N; Fromme, P; Schmidt, K; Weierstall, U; Doak, R B; Spence, J C

    2007-03-22T23:59:59.000Z

    Using detailed simulation and analytical models, the exposure time is estimated for serial crystallography, where hydrated laser-aligned proteins are sprayed across a continuous synchrotron beam. The resolution of X-ray diffraction microscopy is limited by the maximum dose that can be delivered prior to sample damage. In the proposed Serial Crystallography method, the damage problem is addressed by distributing the total dose over many identical hydrated macromolecules running continuously in a single-file train across a continuous X-ray beam, and resolution is then limited only by the available fluxes of molecules and X-rays. Orientation of the diffracting molecules is achieved by laser alignment. We evaluate the incident X-ray fluence (energy/area) required to obtain a given resolution from (1) an analytical model, giving the count rate at the maximum scattering angle for a model protein, (2) explicit simulation of diffraction patterns for a GroEL-GroES protein complex, and (3) the frequency cut off of the transfer function following iterative solution of the phase problem, and reconstruction of a density map in the projection approximation. These calculations include counting shot noise and multiple starts of the phasing algorithm. The results indicate the number of proteins needed within the beam at any instant for a given resolution and X-ray flux. We confirm an inverse fourth power dependence of exposure time on resolution, with important implications for all coherent X-ray imaging. We find that multiple single-file protein beams will be needed for sub-nanometer resolution on current third generation synchrotrons, but not on fourth generation designs, where reconstruction of secondary protein structure at a resolution of 7 {angstrom} should be possible with short (below 100 s) exposures.

  13. Crystallization and preliminary X-ray diffraction studies of tetrameric malate dehydrogenase from the novel Antarctic psychrophile Flavobacterium frigidimaris KUC-1

    SciTech Connect (OSTI)

    Fujii, Tomomi [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan); Oikawa, Tadao; Muraoka, Ikuo [Department of Life Science and Biotechnology, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680 (Japan); Soda, Kenji [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan); Department of Life Science and Biotechnology, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680 (Japan); Hata, Yasuo, E-mail: hata@scl.kyoto-u.ac.jp [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan)

    2007-11-01T23:59:59.000Z

    A psychrophilic malate dehydrogenase from the novel Antarctic bacterium F. frigidimaris KUC-1 was crystallized using the hanging-drop vapour-diffusion method. The crystals contained one tetrameric molecule per asymmetric unit. The best crystal diffracted to 1.8 Å resolution. Flavobacterium frigidimaris KUC-1 is a novel psychrotolerant bacterium isolated from Antarctic seawater. Malate dehydrogenase (MDH) is an essential metabolic enzyme in the citric acid cycle and has been cloned, overexpressed and purified from F. frigidimaris KUC-1. In contrast to the already known dimeric form of MDH from the psychrophile Aquaspirillium arcticum, F. frigidimaris MDH exists as a tetramer. It was crystallized at 288 K by the hanging-drop vapour-diffusion method using ammonium sulfate as the precipitating agent. The crystal diffracted to a maximum resolution of 1.80 Å. It contains one tetrameric molecule in the asymmetric unit.

  14. Workshops on Science Enabled by a Coherent, CW, Synchrotron X-ray Source, June 2011

    SciTech Connect (OSTI)

    Brock, Joel

    2012-01-03T23:59:59.000Z

    In June of 2011 we held six two-day workshops called "XDL-2011: Science at the Hard X-ray Diffraction Limit". The six workshops covered (1) Diffraction-based imaging techniques, (2) Biomolecular structure from non-crystalline materials, (3) Ultra-fast science, (4) High-pressure science, (5) Materials research with nano-beams and (6) X-ray photon correlation spectroscopy (XPCS), In each workshop, invited speaker from around the world presented examples of novel experiments that require a CW, diffraction-limited source. During the workshop, each invited speaker provided a one-page description of the experiment and an illustrative graphic. The experiments identified by the workshops demonstrate the broad and deep scientific case for a CW coherent synchrotron x-ray source. The next step is to perform detailed simulations of the best of these ideas to test them quantitatively and to guide detailed x-ray beam-line designs. These designs are the first step toward developing detailed facility designs and cost estimates.

  15. Atomic-Scale Chemical Imaging and Quantification of Metallic Alloy Structures by Energy-Dispersive X-Ray Spectroscopy

    SciTech Connect (OSTI)

    Lu, Ping [Sandia National Laboratories; Zhou, Lin [Ames Laboratory; Kramer, Matthew J. [Ames Laboratory; Smith, David J. [Arizona State University

    2014-02-04T23:59:59.000Z

    Determination of atomic-scale crystal structure for nanostructured intermetallic alloys, such as magnetic alloys containing Al, Ni, Co (alnico) and Fe, is crucial for understanding physical properties such as magnetism, but technically challenging due to the small interatomic distances and the similar atomic numbers. By applying energy-dispersive X-ray spectroscopy (EDS) mapping to the study of two intermetallic phases of an alnico alloy resulting from spinodal decomposition, we have determined atomic-scale chemical composition at individual lattice sites for the two phases: one is the B2 phase with Fe0.76Co0.24 -Fe0.40Co0.60 ordering and the other is the L21 phase with Ni0.48Co0.52 at A-sites, Al at B?-sites and Fe0.20Ti0.80 at B??-sites, respectively. The technique developed through this study represents a powerful real-space approach to investigate structure chemically at the atomic scale for a wide range of materials systems.

  16. ACIS Advanced CCD Imaging Spectrometer: detector on Chandra ASCA Advanced Satellite for Astronomy and Cosmology: X-ray telescope

    E-Print Network [OSTI]

    and ROSAT HRMA High Resolution Mirror Assembly: Chandra mirrors IPC Imaging Proportional Camera: detector

  17. Time-resolved x-ray imaging of high-power laser-irradiated under-dense silica aerogels and agar foams

    SciTech Connect (OSTI)

    Koch, J.A.; Estabrook, K.G.; Bauer, J.D. [and others

    1995-08-01T23:59:59.000Z

    This paper presents the results of experiments in which a high-power laser was used to irradiate low density (4 - 9 mg/cm{sup 3}) silica aerogel and agar foam targets. The laser-solid interaction and energy transport through the material were monitored with time-resolved imaging diagnostics, and the data show the production and propagation of an x-ray emission front in the plasma. The emission-front trajectory data are found to be in significant disagreement with detailed simulations, which predict a much more rapid heating of the cold material, and the data suggest that this discrepancy is not explainable by target inhomogeneities. Evidence suggests that energy transport into the cold material may be dominated by thermal conduction; however, no completely satisfactory explanation for the discrepancies is identified, and further experimental and theoretical research is necessary in order to resolve this important problem in laser-plasma interaction physics.

  18. Scattering of x rays from low-Z materials

    SciTech Connect (OSTI)

    Gaines, J.L.; Kissel, L.D.; Catron, H.C.; Hansen, R.A.

    1980-08-01T23:59:59.000Z

    X rays incident on thin beryllium, boron, carbon, and other low-Z materials undergo both elastic and inelastic scattering as well as diffraction from the crystalline or crystalline-like structure of the material. Unpolarized monoenergetic x rays in the 1.5 to 8.0-keV energy range were used to determine the absolute scattering efficiency of thin beryllium, carbon, and boron foils. These measurements are compared to calculated scattering efficiencies predicted by single-atom theories. In addition, the relative scattering efficiency versus x-ray energy was measured for other low-Z foils using unpolarized bremsstrahlung x rays. In all the low-Z foils examined, we observed Bragg-like x-ray diffraction due to the ordered structure of the materials.

  19. Direct Observations of the (Alpha to Gamma) Transformation at Different Input Powers in the Heat Affected Zone of 1045 C-Mn Steel Arc Welds Observed by Spatially Resolved X-Ray Diffraction

    SciTech Connect (OSTI)

    Palmer, T A; Elmer, J W

    2005-03-16T23:59:59.000Z

    Spatially Resolved X-Ray Diffraction (SRXRD) experiments have been performed during Gas Tungsten Arc (GTA) welding of AISI 1045 C-Mn steel at input powers ranging from 1000 W to 3750 W. In situ diffraction patterns taken at discreet locations across the width of the heat affected zone (HAZ) near the peak of the heating cycle in each weld show regions containing austenite ({gamma}), ferrite and austenite ({alpha}+{gamma}), and ferrite ({alpha}). Changes in input power have a demonstrated effect on the resulting sizes of these regions. The largest effect is on the {gamma} phase region, which nearly triples in width with increasing input power, while the width of the surrounding two phase {alpha}+{gamma} region remains relatively constant. An analysis of the diffraction patterns obtained across this range of locations allows the formation of austenite from the base metal microstructure to be monitored. After the completion of the {alpha} {yields} {gamma} transformation, a splitting of the austenite peaks is observed at temperatures between approximately 860 C and 1290 C. This splitting in the austenite peaks results from the dissolution of cementite laths originally present in the base metal pearlite, which remain after the completion of the {alpha} {yields} {gamma} transformation, and represents the formation of a second more highly alloyed austenite constituent. With increasing temperatures, carbon, originally present in the cementite laths, diffuses from the second newly formed austenite constituent to the original austenite constituent. Eventually, a homogeneous austenitic microstructure is produced at temperatures of approximately 1300 C and above, depending on the weld input power.

  20. Principles of X-ray Navigation

    SciTech Connect (OSTI)

    Hanson, John Eric; /SLAC

    2006-03-17T23:59:59.000Z

    X-ray navigation is a new concept in satellite navigation in which orientation, position and time are measured by observing stellar emissions in x-ray wavelengths. X-ray navigation offers the opportunity for a single instrument to be used to measure these parameters autonomously. Furthermore, this concept is not limited to missions in close proximity to the earth. X-ray navigation can be used on a variety of missions from satellites in low earth orbit to spacecraft on interplanetary missions. In 1997 the Unconventional Stellar Aspect Experiment (USA) will be launched as part of the Advanced Research and Global Observation Satellite (ARGOS). USA will provide the first platform for real-time experimentation in the field of x-ray navigation and also serves as an excellent case study for the design and manufacturing of space qualified systems in small, autonomous groups. Current techniques for determining the orientation of a satellite rely on observations of the earth, sun and stars in infrared, visible or ultraviolet wavelengths. It is possible to use x-ray imaging devices to provide arcsecond level measurement of attitude based on star patterns in the x-ray sky. This technique is explored with a simple simulation. Collimated x-ray detectors can be used on spinning satellites to provide a cheap and reliable measure of orientation. This is demonstrated using observations of the Crab Pulsar taken by the high Energy Astronomy Observatory (HEAO-1) in 1977. A single instrument concept is shown to be effective, but dependent on an a priori estimate of the guide star intensity and thus susceptible to errors in that estimate. A star scanner based on a differential measurement from two x-ray detectors eliminates the need for an a priori estimate of the guide star intensity. A first order model and a second order model of the two star scanner concepts are considered. Many of the stars that emit in the x-ray regime are also x-ray pulsars with frequency stability approaching a part in 10{sup 9}. By observing these pulsations, a satellite can keep accurate time autonomously. They have demonstrated the acquisition and tracking of the Crab nebula pulsar by simulating the operation of a phase-locked loop.

  1. Design and development of a 3D X-ray microscope

    E-Print Network [OSTI]

    Brayanov, Jordan, 1981-

    2006-01-01T23:59:59.000Z

    The rapid development of needle-free injection systems demands better and faster imaging systems, capable of imaging the transient and steady state response of an injection into real tissue. X-ray radiography, x-ray ...

  2. Fluctuation X-Ray Scattering

    SciTech Connect (OSTI)

    Saldin, PI: D. K.; Co-I's: J. C. H. Spence and P. Fromme

    2013-01-25T23:59:59.000Z

    The work supported by the grant was aimed at developing novel methods of finding the structures of biomolecules using x-rays from novel sources such as the x-ray free electron laser and modern synchrotrons

  3. Scintillating Fiber Array Characterization and Alignment for Neutron Imaging using the High Energy X-ray (HEX) Facility

    SciTech Connect (OSTI)

    Buckles, R. A., Ali, Z. A., Cradick, J. R., Traille, A. J., Warthan, W. A.

    2009-09-04T23:59:59.000Z

    The Neutron Imager diagnostic at the National Ignition Facility (NIF) located at Lawrence Livermore National Laboratory (LLNL) will produce high-resolution, gated images of neutron-generating implosions. A similar pinhole imaging experiment (PINEX) diagnostic was recently deployed at the Z facility at Sandia National Laboratories (SNL). Both the SNL and LLNL neutron imagers use similar fiber array scintillators (BCF-99-555). Despite diverse resolution and magnification requirements, both diagnostics put significant onus on the scintillator spatial quality and alignment precision to maintain optimal point spread. Characterization and alignment of the Z-PINEX scintillator and imaging system were done at NSTec/Livermore Operations in 2009, and is currently underway for the NIF Neutron Imager.

  4. Fabrication process for a gradient index x-ray lens

    DOE Patents [OSTI]

    Bionta, Richard M. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Skulina, Kenneth M. (Livermore, CA)

    1995-01-01T23:59:59.000Z

    A process for fabricating high efficiency x-ray lenses that operate in the 0.5-4.0 keV region suitable for use in biological imaging, surface science, and x-ray lithography of integrated circuits. The gradient index x-ray optics fabrication process broadly involves co-sputtering multi-layers of film on a wire, followed by slicing and mounting on block, and then ion beam thinning to a thickness determined by periodic testing for efficiency. The process enables the fabrication of transmissive gradient index x-ray optics for the 0.5-4.0 keV energy range. This process allows the fabrication of optical elements for the next generation of imaging and x-ray lithography instruments m the soft x-ray region.

  5. Fabrication process for a gradient index x-ray lens

    DOE Patents [OSTI]

    Bionta, R.M.; Makowiecki, D.M.; Skulina, K.M.

    1995-01-17T23:59:59.000Z

    A process is disclosed for fabricating high efficiency x-ray lenses that operate in the 0.5-4.0 keV region suitable for use in biological imaging, surface science, and x-ray lithography of integrated circuits. The gradient index x-ray optics fabrication process broadly involves co-sputtering multi-layers of film on a wire, followed by slicing and mounting on block, and then ion beam thinning to a thickness determined by periodic testing for efficiency. The process enables the fabrication of transmissive gradient index x-ray optics for the 0.5-4.0 keV energy range. This process allows the fabrication of optical elements for the next generation of imaging and x-ray lithography instruments in the soft x-ray region. 13 figures.

  6. Soft x-ray microscopy - a powerful analytical tool to image magnetism down to fundamental length and times scales

    E-Print Network [OSTI]

    Fischer, Peter

    2008-01-01T23:59:59.000Z

    analytical tool to image magnetism down to fundamentalmicroscopies Research of magnetism in low dimensions has notnanoscience [3]. Solid state magnetism is also a showcase in

  7. HAWK-I imaging of the X-ray luminous galaxy cluster XMMU J2235.3-2557: The red sequence at z=1.39

    E-Print Network [OSTI]

    C. Lidman; P. Rosati; M. Tanaka; V. Strazzullo; R. Demarco; C. Mullis; N. Ageorges; M. Kissler-Patig; M. G. Petr-Gotzens; F. Selman

    2008-08-20T23:59:59.000Z

    We use HAWK-I, the recently-commissioned near-IR imager on Yepun (VLT-UT4), to obtain wide-field, high-resolution images of the X-ray luminous galaxy cluster XMMU J2235.3-2557 in the J and Ks bands, and we use these images to build a colour-magnitude diagram of cluster galaxies. Galaxies in the core of the cluster form a tight red sequence with a mean J-Ks colour of 1.9 (Vega system). The intrinsic scatter in the colour of galaxies that lie on the red sequence is similar to that measured for galaxies on the red sequence of the Coma cluster. The slope and location of the red sequence can be modelled by passively evolving the red sequence of the Coma cluster backwards in time. Using simple stellar population (SSP) models, we find that galaxies in the core of XMMU J2235.3-2557 are, even at z=1.39, already 3 Gyr old, corresponding to a formation redshift of z ~ 4. Outside the core, the intrinsic scatter and the fraction of galaxies actively forming stars increase substantially. Using SSP models, we find that most of these galaxies will join the red sequence within 1.5 Gyr. The contrast between galaxies in the cluster core and galaxies in the cluster outskirts indicates that the red sequence of XMMU J2235.3-2557 is being built from the dense cluster core outwards.

  8. Tunable X-ray source

    DOE Patents [OSTI]

    Boyce, James R. (Williamsburg, VA)

    2011-02-08T23:59:59.000Z

    A method for the production of X-ray bunches tunable in both time and energy level by generating multiple photon, X-ray, beams through the use of Thomson scattering. The method of the present invention simultaneously produces two X-ray pulses that are tunable in energy and/or time.

  9. FULL FIELD X-RAY IMAGING (FXI) Group Leader: Wah-Keat Lee2 Proposal Team: G. Amatucci1, L. Berman2, L. Butler3, W. Chiu4, Y. Chu2, P. Crane5, D. Dunand6,

    E-Print Network [OSTI]

    Ohta, Shigemi

    -operando studies of energy storage devices · X-ray imaging for biofuels to evaluate biomass breakdown · In situ · Nanostructure of biological armor · Micro and nano physiological networks Micro/nano fluidic devices. K dynamics of freeze-casting for biomaterials · Micro and nanofluidic devices from biomimetics

  10. Phase transition upon K{sup +} ion exchange into Na-low silica X: Combined NMR and synchrotron X-ray powder diffraction study

    SciTech Connect (OSTI)

    Lee, Y.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States); Carr, S.W. [ANSTO, Menai (Australia)] [ANSTO, Menai (Australia)

    1998-09-01T23:59:59.000Z

    The mechanism by which K{sup +} ions exchange into zeolite Na-low silica X (LSX) (Na{sub 96}Al{sub 96}Si{sub 96}O{sub 384}{center_dot}nH{sub 2}O) has ben determined by studying structures of the Na-LSX and K-LSX end members in the Na-K LSX solid solution series as well as samples exchanged at the 20%, 42% and 80% K{sup +} levels. A preliminary investigation using {sup 29}Si MAS NMR spectroscopy revealed a two-phase region in the solid solution near 80% K{sup +} exchange. Rietveld analysis of the powder diffraction data collected from hydrated samples showed that, up to 42% of K{sup +} exchange, K{sup +} ions were located preferentially at site I{prime}, just outside the double 6-ring (D6R) in the sodalite age, and at site II, above the single 6-ring (S6R) in the supercage. Introduction of K{sup +} ions into site I{prime} repositioned Na{sup +} ions into site I, at the center of the D6R. An abrupt change in the cubic lattice parameter from 25.0389(5) to 25.2086(5) {angstrom} marked the formation of a second phase at the 80% K{sup +}-exchange level as K{sup +} ions began to occupy site I. No coexistence of phases was observed for the fully K{sup +}-exchanged sample (a = 25.2486(2) {angstrom}), where sites I and II were fully occupied by K{sup +} ions.

  11. Effect of Network Structure on Characterization and Flow Modeling Using X-ray Micro-Tomography Images of Granular and Fibrous Porous Media

    SciTech Connect (OSTI)

    Bhattad, Pradeep; Willson, Clinton S.; Thompson, Karsten E. (LSU)

    2012-07-31T23:59:59.000Z

    Image-based network modeling has become a powerful tool for modeling transport in real materials that have been imaged using X-ray computed micro-tomography (XCT) or other three-dimensional imaging techniques. Network generation is an essential part of image-based network modeling, but little quantitative work has been done to understand the influence of different network structures on modeling. We use XCT images of three different porous materials (disordered packings of spheres, sand, and cylinders) to create a series of four networks for each material. Despite originating from the same data, the networks can be made to vary over two orders of magnitude in pore density, which in turn affects network properties such as pore-size distribution and pore connectivity. Despite the orders-of-magnitude difference in pore density, single-phase permeability predictions remain remarkably consistent for a given material, even for the simplest throat conductance formulas. Detailed explanations for this beneficial attribute are given in the article; in general, it is a consequence of using physically representative network models. The capillary pressure curve generated from quasi-static drainage is more sensitive to network structure than permeability. However, using the capillary pressure curve to extract pore-size distributions gives reasonably consistent results even though the networks vary significantly. These results provide encouraging evidence that robust network modeling algorithms are not overly sensitive to the specific structure of the underlying physically representative network, which is important given the variety image-based network-generation strategies that have been developed in recent years.

  12. Thermal stability in the blended lithium manganese oxide – Lithium nickel cobalt manganese oxide cathode materials: An in situ time-resolved X-Ray diffraction and mass spectroscopy study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Enyuan; Bak, Seong Min; Senanayake, Sanjaya D.; Yang, Xiao-Qing; Nam, Kyung-Wan; Zhang, Lulu; Shao, Minhua

    2015-03-01T23:59:59.000Z

    Thermal stabilities of a series of blended LiMn2O4(LMO)-LiNi1/3Co1/3Mn1/3O2 (NCM) cathode materials with different weight ratios were studied by in situ time-resolved X-ray diffraction (XRD) combined with mass spectroscopy in the temperature range of 25°C-580°C under helium atmosphere. Upon heating, the electrochemically delithiated LMO changed into Mn3O4 phase at around 250°C. Formation of MnO with rocksalt structure started at 520°C. This observation is in contrast to the previous report for chemically delithiate LMO in air, in which a process of ?-MnO2 transforming to ?-MnO2 was observed. Oxygen peak was not observed in all cases, presumably as a result of either consumptionmore »by the carbon or detection limit. CO2 profile correlates well with the phase transition and indirectly suggests the oxygen release of the cathode. Introducing NCM into LMO has two effects: first, it makes the high temperature rock-salt phase formation more complicated with more peaks in CO2 profile due to different MO (M = Ni, Mn, Co) phases; secondly, the onset temperature of CO2 release is lowered, implying lowered oxygen release temperature. Upon heating, XRD patterns indicate the NCM part reacts first, followed by the LMO part. This confirms the better thermal stability of LMO over NCM.« less

  13. Synthesis and single-crystal X-ray diffraction studies of new framework substituted type II clathrates, Cs{sub 8}Na{sub 16}Ag{sub x}Ge{sub 136-x} (x<7)

    SciTech Connect (OSTI)

    Beekman, M. [Department of Physics, University of South Florida, 4202 East Fowler Ave., PHY 114, Tampa, FL 33620 (United States); Wong-Ng, W. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Kaduk, J.A. [INEOS Technologies, Naperville, IL 60566 (United States); Shapiro, A. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Nolas, G.S. [Department of Physics, University of South Florida, 4202 East Fowler Ave., PHY 114, Tampa, FL 33620 (United States)], E-mail: gnolas@cas.usf.edu

    2007-03-15T23:59:59.000Z

    New inorganic type II clathrates with Ag atoms substituting for framework Ge atoms, Cs{sub 8}Na{sub 16}Ag{sub x}Ge{sub 136-x} (x=0, 5.9, and 6.7), have been synthesized by reaction of the pure elements at high temperature. Structural refinements have been performed using single crystal X-ray diffraction. The materials crystallize with the cubic type II clathrate crystal structure (space group Fd3-barm) with a=15.49262(9)A, 15.51605(6)A, and 15.51618(9) for x=0, 5.9, and 6.7, respectively, and Z=1. The structure is formed by a covalently bonded Ag-Ge framework, in which the Cs and Na atoms are found inside two types of polyhedral cages. Ag substitutes for Ge in the tetrahedrally bonded framework positions, and was found to preferentially occupy the most asymmetric 96g site. The proven ability to substitute atoms for the germanium framework should offer a route to the synthesis of new compositions of type II clathrates, materials that are of interest for potential thermoelectrics applications.

  14. Thermal stability in the blended lithium manganese oxide – Lithium nickel cobalt manganese oxide cathode materials: An in situ time-resolved X-Ray diffraction and mass spectroscopy study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Enyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); Bak, Seong Min [Brookhaven National Lab. (BNL), Upton, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yang, Xiao-Qing [Dongguk Univ., Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering; Nam, Kyung-Wan [Dongguk Univ., Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering] (ORCID:0000000162786369); Zhang, Lulu [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong); Shao, Minhua

    2015-03-01T23:59:59.000Z

    Thermal stabilities of a series of blended LiMn2O4(LMO)-LiNi1/3Co1/3Mn1/3O2 (NCM) cathode materials with different weight ratios were studied by in situ time-resolved X-ray diffraction (XRD) combined with mass spectroscopy in the temperature range of 25°C-580°C under helium atmosphere. Upon heating, the electrochemically delithiated LMO changed into Mn3O4 phase at around 250°C. Formation of MnO with rocksalt structure started at 520°C. This observation is in contrast to the previous report for chemically delithiate LMO in air, in which a process of ?-MnO2 transforming to ?-MnO2 was observed. Oxygen peak was not observed in all cases, presumably as a result of either consumption by the carbon or detection limit. CO2 profile correlates well with the phase transition and indirectly suggests the oxygen release of the cathode. Introducing NCM into LMO has two effects: first, it makes the high temperature rock-salt phase formation more complicated with more peaks in CO2 profile due to different MO (M = Ni, Mn, Co) phases; secondly, the onset temperature of CO2 release is lowered, implying lowered oxygen release temperature. Upon heating, XRD patterns indicate the NCM part reacts first, followed by the LMO part. This confirms the better thermal stability of LMO over NCM.

  15. High-pressure x-ray diffraction study of YBO{sub 3}/Eu{sup 3+}, GdBO{sub 3}, and EuBO{sub 3}: Pressure-induced amorphization in GdBO{sub 3}

    SciTech Connect (OSTI)

    Wang, Pei; Xu, Chao; Ren, Xiangting; Lei, Li; Wang, Shanmin; Peng, Fang; Yan, Xiaozhi; Liu, Dongqiong; Wang, Qiming [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); He, Duanwei, E-mail: duanweihe@scu.edu.cn [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); Institute of Fluid Physics and National Key Laboratory of Shockwave and Detonation Physics, China Academy of Engineering Physics, Mianyang 621900 (China); Xiong, Lun; Liu, Jing [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

    2014-01-28T23:59:59.000Z

    Angle-dispersive synchrotron X-ray diffraction measurements were performed on vaterite-type YBO{sub 3}/Eu{sup 3+}, GdBO{sub 3}, and EuBO{sub 3}, respectively, up to 41?GPa at room temperature using a diamond-anvil cell. Pressure-induced amorphization was observed in hexagonal GdBO{sub 3} with a significant compression along the c-axis. Compared to the ions of the distorted GdBO{sub 3} phase, its anions may lose their long-range order prior to the cations at high pressures. Based on the experimental pressure-volume data, the obtained bulk moduli of YBO{sub 3}/Eu{sup 3+} and GdBO{sub 3} are 329 and 321?GPa, respectively, which are more than 90% larger than that of EuBO{sub 3} (167?GPa) and are presumably attributed to Gd{sup 3+} and Y{sup 3+} with a high density of d valence electrons.

  16. Brighter Screens for Nondestructive Digital X-ray Radiography

    SciTech Connect (OSTI)

    Miller, Jr., A. C.; Bell, Z. W.; Carpenter, D. A.

    2003-09-15T23:59:59.000Z

    Fine resolution, bright X-ray screens are needed for digital radiography and material characterization at the Y-12 National Security Complex (Y-12). Current technology is simply not adequate for transferring high-energy X-ray images to visible light for demanding digital applications. Low energy radiography and especially emerging tomographic technologies are severely hampered for Y-12 nondestructive evaluation (NDE) applications by dim screens with poor resolution. Also, the development of more advanced materials characterization techniques, such as electron backscatter diffraction (EBSD), is driven by a design agency desire for tighter specifications and more uniform materials. Brighter screens would allow us to probe materials on a finer scale, leading to a better understanding of material behavior. A number of X-ray screen materials were studied that would be suitable for direct replacement in existing digital imaging systems. Spectroscopic evaluations were first made for a several candidates and indicated that lutetium orthosilicate (LSO) would be a promising candidate for MeV images. A relative comparison of brightness at various energies was then completed which showed that cesium iodide (CsI) could increase brightness by over an order of magnitude. Since image quality is also important for better screens, the resolving capabilities of candidate materials were measured. Resolution measurements were completed at X-ray peak energies up to 420KeV with magnified optical imaging systems, and indicated that LSO and Industrial Quality Incorporated glass (IQI) exhibited higher resolution than the CsI screen. The results give a choice of materials that can be tailored to the particular test under consideration. If high-speed images are necessary and some resolution can be sacrificed, the CsI screen will be a good choice. The screen can be replaced by an IQI or LSO unit if higher resolution is needed later, for instance to focus in on a region of interest. A number of significant findings were obtained from this study. Most important of the findings was that materials are commercially available that are much brighter than screens currently in use. This finding meets the original objective of the project. Two objectives of the study; however, were not met. We hoped to evaluate a 'quantum dot' (nanometer-sized particles of semiconductor material) wavelength conversion screen, but the manufacturer ceased production of the screen shortly before the project was started. The dot screen could be efficient in converting ultraviolet light to visible light which would have proved important for utilizing a Cherenkov screen. Since this was a very new, cutting-edge technology, an alternative supplier was not found during the study. Also, high-energy testing of a Cherenkov light screen was not performed due to difficulties in obtaining appropriate approvals for locating test equipment in the high-energy X-ray vault at Y-12. The test is still important, and is being pursued through follow-on funding sources. Although many film shots will be eliminated by the availability of high quality digital images, the largest potential gains result from the availability of clearer images that show fine detail in the parts under analysis. Digital radiographic data also offers the possibility of easily sharing data with other sites. This could prove invaluable when critical material, placement, assembly, or quality issues are pressing. Also, increased throughput in the NDE facility allows statistically significant numbers of units to be analyzed. Digital technologies may in fact be needed just to meet minimum requirements of future demands. Increased brightness screens allow for such innovations as 3-D tomographic images to be acquired in a reasonable time. Much of the skill required to interpret 'flattened' X-ray images is not needed to maneuver around the reconstructed tomogram. This study showed that several commercially available materials are much brighter than screens currently in use. The study also showed that materials othe

  17. Chemical imaging at 30 nm spatial resolution in 2-d and 3-d with Scanning Transmission X-ray Microscopy

    E-Print Network [OSTI]

    Fisher, Frank

    sensitive imaging of environmental biofilms; speciation and quantitative mapping of metals in natural river in January 1997, after serving on the editorial board since 1986. He has worked with AFCC since 2008 on fuel

  18. X-ray lithography source

    DOE Patents [OSTI]

    Piestrup, Melvin A. (Woodside, CA); Boyers, David G. (Mountain View, CA); Pincus, Cary (Sunnyvale, CA)

    1991-01-01T23:59:59.000Z

    A high-intensity, inexpensive X-ray source for X-ray lithography for the production of integrated circuits. Foil stacks are bombarded with a high-energy electron beam of 25 to 250 MeV to produce a flux of soft X-rays of 500 eV to 3 keV. Methods of increasing the total X-ray power and making the cross section of the X-ray beam uniform are described. Methods of obtaining the desired X-ray-beam field size, optimum frequency spectrum and elminating the neutron flux are all described. A method of obtaining a plurality of station operation is also described which makes the process more efficient and economical. The satisfying of these issues makes transition radiation an exellent moderate-priced X-ray source for lithography.

  19. X-ray lithography source

    DOE Patents [OSTI]

    Piestrup, M.A.; Boyers, D.G.; Pincus, C.

    1991-12-31T23:59:59.000Z

    A high-intensity, inexpensive X-ray source for X-ray lithography for the production of integrated circuits is disclosed. Foil stacks are bombarded with a high-energy electron beam of 25 to 250 MeV to produce a flux of soft X-rays of 500 eV to 3 keV. Methods of increasing the total X-ray power and making the cross section of the X-ray beam uniform are described. Methods of obtaining the desired X-ray-beam field size, optimum frequency spectrum and eliminating the neutron flux are all described. A method of obtaining a plurality of station operation is also described which makes the process more efficient and economical. The satisfying of these issues makes transition radiation an excellent moderate-priced X-ray source for lithography. 26 figures.

  20. Segmented crystalline scintillators: An initial investigation of high quantum efficiency detectors for megavoltage x-ray imaging

    E-Print Network [OSTI]

    Cunningham, Ian

    elements, without loss of spatial resolution due to the spread of optical photons. Radiation damage studies radiotherapy imaging conditions. Results from the radiation damage studies showed that both CsI Tl and BGO Wang, Jin Yamamoto, and Hong Du Department of Radiation Oncology, University of Michigan, Ann Arbor

  1. Energy resolved X-ray grating interferometry

    SciTech Connect (OSTI)

    Thuering, T.; Stampanoni, M. [Swiss Light Source, Paul Scherrer Institut, Villigen PSI (Switzerland) [Swiss Light Source, Paul Scherrer Institut, Villigen PSI (Switzerland); Institute for Biomedical Engineering, Swiss Federal Institute of Technology, Zurich (Switzerland); Barber, W. C.; Iwanczyk, J. S. [DxRay, Inc., Northridge, California 91324 (United States)] [DxRay, Inc., Northridge, California 91324 (United States); Seo, Y.; Alhassen, F. [UCSF Physics Research Laboratory, Department of Radiology and Biomedical Imaging, University of California, San Francisco, California 94143 (United States)] [UCSF Physics Research Laboratory, Department of Radiology and Biomedical Imaging, University of California, San Francisco, California 94143 (United States)

    2013-05-13T23:59:59.000Z

    Although compatible with polychromatic radiation, the sensitivity in X-ray phase contrast imaging with a grating interferometer is strongly dependent on the X-ray spectrum. We used an energy resolving detector to quantitatively investigate the dependency of the noise from the spectral bandwidth and to consequently optimize the system-by selecting the best energy band matching the experimental conditions-with respect to sensitivity maximization and, eventually, dose. Further, since theoretical calculations of the spectrum are usually limited due to non-ideal conditions, an energy resolving detector accurately quantifies the spectral changes induced by the interferometer including flux reduction and beam hardening.

  2. Radiographic X-Ray Pulse Jitter

    SciTech Connect (OSTI)

    Mitton, C. V., Good, D. E., Henderson, D. J., Hogge, K. W.

    2011-01-15T23:59:59.000Z

    The Dual Beam Radiographic Facility consists of two identical radiographic sources. Major components of the machines are: Marx generator, water-filled pulse-forming line (PFL), water-filled coaxial transmission line, three-cell inductive voltage adder, and rod-pinch diode. The diode pulse has the following electrical specifications: 2.25-MV, 60-kA, 60-ns. Each source has the following x-ray parameters: 1-mm-diameter spot size, 4-rad at 1 m, 50-ns full width half max. The x-ray pulse is measured with PIN diode detectors. The sources were developed to produce high resolution images on single-shot, high-value experiments. For this application it is desirable to maintain a high level of reproducibility in source output. X-ray pulse jitter is a key metric for analysis of reproducibility. We will give measurements of x-ray jitter for each machine. It is expected that x-ray pulse jitter is predominantly due to PFL switch jitter, and therefore a correlation of the two will be discussed.

  3. Cryo diffraction microscopy: Ice conditions and finite supports

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miao, H; Downing, K; Huang, X; Kirz, J; Marchesini, S; Nelson, J; Shapiro, D; Steinbrener, J; Stewart, A; Jacobsen, C

    2009-09-01T23:59:59.000Z

    Using a signal-to-noise ratio estimation based on correlations between multiple simulated images, we compare the dose efficiency of two soft x-ray imaging systems: incoherent brightfield imaging using zone plate optics in a transmission x-ray microscope (TXM), and x-ray diffraction microscopy (XDM) where an image is reconstructed from the far-field coherent diffraction pattern. In XDM one must computationally phase weak diffraction signals; in TXM one suffers signal losses due to the finite numerical aperture and efficiency of the optics. In simulations with objects representing isolated cells such as yeast, we find that XDM has the potential for delivering equivalent resolution images using fewer photons. This can be an important advantage for studying radiation-sensitive biological and soft matter specimens.

  4. Frontiers in X-Ray Science

    SciTech Connect (OSTI)

    Linda Young

    2011-02-23T23:59:59.000Z

    The year 2010 marked the fiftieth anniversary of the optical laser and the first anniversary of the world's first hard x-ray free-electron laser, the Linac Coherent Light Source (LCLS) at SLAC. This exciting, new accelerator-based source of x-rays provides peak brilliances roughly a billion times greater than currently available from synchrotron sources such as the Advanced Photon Source at Argonne, and thus explores a qualitatively different parameter space. This talk will describe the first experiments at the LCLS aimed at understanding the nature of high intensity x-ray interactions, related applications in ultrafast imaging on the atomic scale and sketch nascent plans for the extension of both linac and storage-ring based photon sources.

  5. Shad-o-Snap X-Ray Camera Hardware Manual

    E-Print Network [OSTI]

    -o-Snap x-ray camera is a complete, stand-alone x-ray imaging device featuring "smart" microprocessor-controlled camera electronics and a convenient USB interface. The plug- and-play interface allows easy control by the silicon photodiodes. The Shad-o-Snap camera also includes electronics to digitize the video signal

  6. Measurement and characterization of x-ray spot size

    SciTech Connect (OSTI)

    Mueller, K.H.

    1989-01-01T23:59:59.000Z

    In planning an x-ray imaging experiment one must have an accurate model of the imaging system to obtain optimum results. The blurring caused by the finite size of the x-ray source is often the least understood element in the system. We have developed experimental and analytical methods permitting accurate measurement and modeling of the x-ray source. The model offers a simple and accurate way to optimize the radiographic geometry for any given experimental requirement (i.e., resolution and dose at detector). Any text on radiography will mention the effects of the finite size of the x-ray source on image quality and how one can minimize this influence by the choice of a small radiographic magnification. The film blur (independent of the source blur) is often treated as a single number and combined with an effective blur dimension for the x-ray source to give a total blur on the film. In this paper, we will develop a treatment of x-ray sources based on the modulation transfer function (MTF). This approach allows us to infer the spatial distribution function of the electron beam that produces the bremsstrahlung x-rays and to predict the performance of an x-ray imaging system if we know the MTF of the detector. This treatment is much more accurate than a single number characterization. 4 refs., 7 figs.

  7. Electromagnetic Application: X-RAY Alawi H. Ba-Surrah

    E-Print Network [OSTI]

    Masoudi, Husain M.

    , Pulyui published high-quality x-ray images in journals in Paris and London. · Nikola Tesla In April 1887, Nikola Tesla began to investigate X-rays using high voltages and tubes of his own design, as well. The principle behind Tesla's device is called the Bremsstrahlung process, in which a high-energy secondary X

  8. Quantitative electron density characterization of soft tissue substitute plastic materials using grating-based x-ray phase-contrast imaging

    SciTech Connect (OSTI)

    Sarapata, A.; Chabior, M.; Zanette, I.; Pfeiffer, F. [Lehrstuhl für Biomedizinische Physik, Physik-Department and Institut für Medizintechnik, Technische Universität München, 85748 Garching (Germany); Cozzini, C.; Sperl, J. I.; Bequé, D. [GE Global Research, 85748 Garching (Germany); Langner, O.; Coman, J. [QRM GmbH, Möhrendorf (Germany); Ruiz-Yaniz, M. [Lehrstuhl für Biomedizinische Physik, Physik-Department and Institut für Medizintechnik, Technische Universität München, 85748 Garching (Germany); European Synchrotron Radiation Facility, Grenoble (France)

    2014-10-15T23:59:59.000Z

    Many scientific research areas rely on accurate electron density characterization of various materials. For instance in X-ray optics and radiation therapy, there is a need for a fast and reliable technique to quantitatively characterize samples for electron density. We present how a precise measurement of electron density can be performed using an X-ray phase-contrast grating interferometer in a radiographic mode of a homogenous sample in a controlled geometry. A batch of various plastic materials was characterized quantitatively and compared with calculated results. We found that the measured electron densities closely match theoretical values. The technique yields comparable results between a monochromatic and a polychromatic X-ray source. Measured electron densities can be further used to design dedicated X-ray phase contrast phantoms and the additional information on small angle scattering should be taken into account in order to exclude unsuitable materials.

  9. Detection of improvised explosive devices at long-range using coded aperture imaging of backscattered X-rays with dynamic reconstruction

    E-Print Network [OSTI]

    Bell, Jayna T. (Jayna Teresa)

    2009-01-01T23:59:59.000Z

    Standoff detection of improvised explosive devices (IEDs) is a continuing problem for the U.S. military. Current X-ray detection systems cannot detect explosives at distances above a few meters and with a source-detector ...

  10. MULTI-STRANDED AND MULTI-THERMAL SOLAR CORONAL LOOPS: EVIDENCE FROM HINODE X-RAY TELESCOPE AND EUV IMAGING SPECTROMETER DATA

    SciTech Connect (OSTI)

    Schmelz, J. T.; Nasraoui, K. [Physics Department, University of Memphis, Memphis, TN 38152 (United States); Saar, S. H.; Kashyap, V. L.; Weber, M. A.; DeLuca, E. E.; Golub, L., E-mail: jschmelz@memphis.ed [Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138 (United States)

    2010-11-10T23:59:59.000Z

    Data from the X-Ray Telescope (XRT) and the EUV Imaging Spectrometer (EIS) on the Japanese/USA/UK Hinode spacecraft were used to investigate the spatial and thermal properties of an isolated quiescent coronal loop. We constructed differential emission measure (DEM) curves using Monte Carlo based, iterative forward fitting algorithms. We studied the loop as a whole, in segments, in transverse cuts, and point-by-point, always with some form of background subtraction, and find that the loop DEM is neither isothermal nor extremely broad, with approximately 96% of the EM between 6.2 {<=}log T{<=} 6.7, and an EM-weighted temperature of log T = 6.48 {+-} 0.16. We find evidence for a gradual change in temperature along the loop, with log T increasing only by {approx}0.1 from the footpoints to the peak. The combine XRT-EIS data set does a good job of constraining the temperature distribution for coronal loop plasma. Our studies show that the strong constraints at high and low temperatures provided by the combined data set are crucial for obtaining reasonable solutions. These results confirm that the observations of at least some loops are not consistent with isothermal plasma, and therefore cannot be modeled with a single flux tube and must be multi-stranded.

  11. Miniature x-ray source

    DOE Patents [OSTI]

    Trebes, James E. (Livermore, CA); Stone, Gary F. (Livermore, CA); Bell, Perry M. (Tracy, CA); Robinson, Ronald B. (Modesto, CA); Chornenky, Victor I. (Minnetonka, MN)

    2002-01-01T23:59:59.000Z

    A miniature x-ray source capable of producing broad spectrum x-ray emission over a wide range of x-ray energies. The miniature x-ray source comprises a compact vacuum tube assembly containing a cathode, an anode, a high voltage feedthru for delivering high voltage to the anode, a getter for maintaining high vacuum, a connection for an initial vacuum pump down and crimp-off, and a high voltage connection for attaching a compact high voltage cable to the high voltage feedthru. At least a portion of the vacuum tube wall is highly x-ray transparent and made, for example, from boron nitride. The compact size and potential for remote operation allows the x-ray source, for example, to be placed adjacent to a material sample undergoing analysis or in proximity to the region to be treated for medical applications.

  12. Cryo diffraction microscopy: Ice conditions and finite supports

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miao, H; Downing, K; Huang, X; Kirz, J; Marchesini, S; Nelson, J; Shapiro, D; Steinbrener, J; Stewart, A; Jacobsen, C

    2009-09-01T23:59:59.000Z

    Using a signal-to-noise ratio estimation based on correlations between multiple simulated images, we compare the dose efficiency of two soft x-ray imaging systems: incoherent brightfield imaging using zone plate optics in a transmission x-ray microscope (TXM), and x-ray diffraction microscopy (XDM) where an image is reconstructed from the far-field coherent diffraction pattern. In XDM one must computationally phase weak diffraction signals; in TXM one suffers signal losses due to the finite numerical aperture and efficiency of the optics. In simulations with objects representing isolated cells such as yeast, we find that XDM has the potential for delivering equivalent resolution imagesmore »using fewer photons. This can be an important advantage for studying radiation-sensitive biological and soft matter specimens.« less

  13. Gated x-ray detector for the National Ignition Facility

    SciTech Connect (OSTI)

    Oertel, John A.; Aragonez, Robert; Archuleta, Tom; Barnes, Cris; Casper, Larry; Fatherley, Valerie; Heinrichs, Todd; King, Robert; Landers, Doug; Lopez, Frank; Sanchez, Phillip; Sandoval, George; Schrank, Lou; Walsh, Peter; Bell, Perry; Brown, Matt; Costa, Robert; Holder, Joe; Montelongo, Sam; Pederson, Neal [Los Alamos National Laboratory, Los Alamos, New Mexico 87544 (United States); Lawrence Livermore National Laboratory, Livermore, California 94551-0808 (United States); VI Control Systems Ltd., Los Alamos, New Mexico 87544 (United States)

    2006-10-15T23:59:59.000Z

    Two new gated x-ray imaging cameras have recently been designed, constructed, and delivered to the National Ignition Facility in Livermore, CA. These gated x-Ray detectors are each designed to fit within an aluminum airbox with a large capacity cooling plane and are fitted with an array of environmental housekeeping sensors. These instruments are significantly different from earlier generations of gated x-ray images due, in part, to an innovative impedance matching scheme, advanced phosphor screens, pulsed phosphor circuits, precision assembly fixturing, unique system monitoring, and complete remote computer control. Preliminary characterization has shown repeatable uniformity between imaging strips, improved spatial resolution, and no detectable impedance reflections.

  14. Bomb Detection Using Backscattered X-Rays

    SciTech Connect (OSTI)

    Jacobs, J.; Lockwood, G.; Selph, M; Shope, S.; Wehlburg, J.

    1998-10-01T23:59:59.000Z

    Bomb Detection Using Backscattered X-rays* Currently the most common method to determine the contents of a package suspected of containing an explosive device is to use transmission radiography. This technique requires that an x-ray source and film be placed on opposite sides of the package. This poses a problem if the pachge is placed so that only one side is accessible, such as against a wall. There is also a threat to persomel and property since exTlosive devices may be "booby trapped." We have developed a method to x-ray a paclage using backscattered x-rays. This procedure eliminates the use of film behind the target. All of the detection is done from the same side as the source. When an object is subjected to x-rays, some of them iare scattered back towards the source. The backscattenng of x-rays is propordoml to the atomic number (Z) of the material raised to the 4.1 power. This 24"' dependence allows us to easily distinguish between explosives, wires, timer, batteries, and other bomb components. Using transmission radiography-to image the contents of an unknown package poses some undesirable risks. The object must have an x-ray film placed on the side opposite the x-ray source; this cannot be done without moving the package if it has been placed firmly against a wall or pillar. Therefore it would be extremely usefid to be able to image the contents of a package from only one side, without ever having to disturb the package itself. where E is the energy of the incoming x-ray. The volume of x-rays absorbed is important because it is, of course, directly correlated to the intensity of x-mys that will be scattered. Most of the x-rays that scatter will do so in a genemlly forward direction; however, a small percentage do scatter in a backward direction. Figure 1 shows a diagram of the various fates of x-rays directed into an object. The package that was examined in this ex~enment was an attache case made of pressed fiberboardwith a vinyl covering. It was approxirmtely 36 cm wide by 51 cm long by 13 cm deep. The case was placed on an aluminum sheet under the x-ray source. Because of the laborato~ setup, the attache case was rastered in the y-coordinate direction, while the x-ray source mstered in the x-coordinate direction. However, for field use, the x-ray source would of course raster in both the x- and y-coordinate directions, while the object under interrogation would remain stationary and undisturbed. A mobile system for use by law enforcement agencies or bomb disposal squads needs to be portable and somewhat durable. A 300 kV x-ray source should be sufficient for the task requirements and can be mounted on a mobile system. A robotic carriage could be used to transport the x-ray source and the CCD camera to the proximity of the suspect package. The controlling and data analyzing elements of the system' could then be maintained at a &tie distance from the possible explosive. F@re 8 shows a diagram of a conceptual design of a possible system for this type of use. The use of backscattered x-rays for interrogation of packages that may contain explosive devices has been shown to be feasible inthelaboratory. Usinga 150kVx-ray source anddetectors consisting of plastic scintillating material, all bomb components including the wiring were detectable. However, at this time the process requires more time than is desirable for the situations in which it will most likely be needed. Further development of the technology using CCD cameras, rather than the plastic stint illator detectors, shows promise of leading to a much faster system, as well as one with better resolution. Mounting the x- ray source and the CCD camera on a robotic vehicle while keeping the controlling and analyzing components and the opemting personnel a safe distance away from the suspect package will allow such a package to be examined at low risk to human life.

  15. A mirror for lab-based quasi-monochromatic parallel x-rays

    SciTech Connect (OSTI)

    Nguyen, Thanhhai; Lu, Xun; Lee, Chang Jun; Jeon, Insu, E-mail: i-jeon@chonnam.ac.kr [School of Mechanical Engineering, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757 (Korea, Republic of); Jung, Jin-Ho [Pro-optics Co., Ltd., 475 Ami-ri, Bubal-eup, Icheon 467-866 (Korea, Republic of); Jin, Gye-Hwan [Department of Radiology, Nambu University, 76 Chumdan Jungang 1-ro, Gwangsan-gu, Gwangju 506-706 (Korea, Republic of); Kim, Sung Youb [School of Mechanical and Advanced Materials Engineering, Ulsan National Institute of Science and Technology, 100 Banyeon-ri, Eonyang-eup, Ulju-gun, Ulsan 689-798 (Korea, Republic of)

    2014-09-15T23:59:59.000Z

    A multilayered parabolic mirror with six W/Al bilayers was designed and fabricated to generate monochromatic parallel x-rays using a lab-based x-ray source. Using this mirror, curved bright bands were obtained in x-ray images as reflected x-rays. The parallelism of the reflected x-rays was investigated using the shape of the bands. The intensity and monochromatic characteristics of the reflected x-rays were evaluated through measurements of the x-ray spectra in the band. High intensity, nearly monochromatic, and parallel x-rays, which can be used for high resolution x-ray microscopes and local radiation therapy systems, were obtained.

  16. Note: A novel normalization scheme for laser-based plasma x-ray sources

    SciTech Connect (OSTI)

    Zhang, B. B.; Sun, D. R.; Tao, Y., E-mail: taoy@ihep.ac.cn [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Sun, S. S. [Institute of Physics, Chinese Academy of Sciences, Beijing 100090 (China)

    2014-09-15T23:59:59.000Z

    A kHz repetition rate laser pump-X-ray probe system for ultrafast X-ray diffraction is set up based on a laser-driven plasma X-ray source. A simple and reliable normalization approach has been developed to minimize the impact of large X-ray pulse intensity fluctuation on data quality. It utilizes one single X-ray area detector to record both sample and reference signals simultaneously. Performance of this novel normalization method is demonstrated in reflectivity oscillation measurement of a superlattice sample at sub-ps resolution.

  17. X-ray Imaging Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat isJoin theanniversaryI 1 0 3 P

  18. Performance enhancement approaches for a dual energy x-ray

    E-Print Network [OSTI]

    Fu, Kenneth

    2010-01-01T23:59:59.000Z

    Evans, J.P.O. , “Stereoscopic dual energy imaging for targetCrawford, C.R. , “Dual Energy Volumetric X-ray Tomographicimages in 4–10 MeV Dual- energy customs system for material

  19. Chandra X-ray Analysis of Galaxy Cluster A168

    E-Print Network [OSTI]

    Yanbin Yang; Zhiying Huo; Xu Zhou; Suijian Xue; Shude Mao; Jun Ma; Jiansheng Chen

    2004-06-29T23:59:59.000Z

    We present Chandra X-ray observations of galaxy cluster A168 (z=0.045). Two X-ray peaks with a projected distance of 676 kpc are found to be located close to two dominant galaxies, respectively. Both peaks are significantly offset from the peak of the number density distribution of galaxies. This suggests that A168 consists of two subclusters, a northern subcluster (A168N) and a southern subcluster (A168S). Further X-ray imaging analysis reveals that (1) the X-ray isophotes surrounding the two X-ray peaks are heavily distorted, (2) an elongated and ontinuous filament connects the two X-ray peaks. These suggest that strong interactions have occurred between the two subclusters. Spectral analysis shows that A168 has a mean temperature of 2.53 +/- 0.09 keV and a mean metallicity of 0.31 +/- 0.04 Z_{solar}. The metallicity is roughly a constant across the cluster but the temperature shows some systematic variations. Most X-ray, optical and radio properties of A168 are consistent with it being an off-axis merger several Gyrs after a core passage, although detailed numerical simulations are required to see whether the observed properties, in particular the significant offset between the optical and X-ray centers, can be reproduced in such a scenario.

  20. X-ray radiography for container inspection

    DOE Patents [OSTI]

    Katz, Jonathan I. (Clayton, MO); Morris, Christopher L. (Los Alamos, NM)

    2011-06-07T23:59:59.000Z

    Arrangements of X-ray inspection systems are described for inspecting high-z materials in voluminous objects such as containers. Inspection methods may involve generating a radiographic image based on detected attenuation corresponding to a pulsed beams of radiation transmitted through a voluminous object. The pulsed beams of radiation are generated by a high-energy source and transmitted substantially downward along an incident angle, of approximately 1.degree. to 30.degree., to a vertical axis extending through the voluminous object. The generated radiographic image may be analyzed to detect on localized high attenuation representative of high-z materials and to discriminate high-z materials from lower and intermediate-z materials on the basis of the high density and greater attenuation of high-z material for higher energy (3-10 MeV) X-rays, and the compact nature of threatening masses of fissionable materials.

  1. Possibility of corrector plate tuning of x-ray focusing

    SciTech Connect (OSTI)

    Talman, Richard

    2009-05-01T23:59:59.000Z

    Schemes for focusing a hard x-ray beam to a small spot are described. The theoretical minimum spot size, assuming perfect mirror shape, is shown to be 4 nm FWHM, independent of x-ray wavelength. This is less than the 10 nm previously said to be the minimum achievable diffraction-limited x-ray spot size. While providing the penetrating power only possible with x rays, this approaches the resolution needed to image individual atoms or atomic layers. However, the perfect mirror assumption is physically unrealistic. This paper discusses the compensation of mirror shape errors by a corrector plate and shows that the tolerances for corrector plate shape are far looser than are tolerances for mirror shape. The full eventual success of achieving theoretical minimum resolution will require mirror shape precision considerably better than has been achieved at this time, though far looser than would be required for simpleminded paraboloidal focusing. Two variants of the scheme, subject to the same mathematical treatment, are described. (i) The ''corrector plate'' name is copied from the similarly functioning element of the same name in a Schmidt camera. The focusing is achieved using glancing, yet coherent, reflection from a high-Z paraboloidal mirror. The strategy is to obtain dominant focusing from reflection and to compensate with weak refractive focusing. The reflective focusing is strong and achromatic but insufficiently accurate. The refractive focusing is weak and chromatic but highly accurate. The corrector plate improves resolution the way eyeglasses help a person to see. It can, for example, be ''fitted'' the same trial-and-error way an optometrist establishes a prescription for glasses. Dimensional tolerances for the compensator are far looser than would be needed for a mirror to achieve the same resolution. Unlike compound refractive lenses, attenuation will be small, at least for wavelengths longer than 1 A, because the compensation layer is thin. (ii) For this variant, the corrector plate is a washer-shaped refractive or Fresnel lens, and the mirror is (theoretically) a perfect cone. All focusing is provided by the lens. Even though the cone provides no focusing, it improves the resolution by increasing the numerical aperture of the device. Compared to a paraboloidal shape, it is assumed that the conical shape can be more accurately fabricated. Of the two variants, only the first variant is, in principle, capable of achieving the theoretical minimum resolution. Configurations are suggested, in both case (i) and case (ii), that use currently possible construction precisions to produce resolutions better than have been achieved to date. However, both results will remain well above the theoretical minimum until fabrication techniques have been developed that provide greater precision than is possible at this time.

  2. Miniature x-ray source

    DOE Patents [OSTI]

    Trebes, James E. (Livermore, CA); Bell, Perry M. (Tracy, CA); Robinson, Ronald B. (Modesto, CA)

    2000-01-01T23:59:59.000Z

    A miniature x-ray source utilizing a hot filament cathode. The source has a millimeter scale size and is capable of producing broad spectrum x-ray emission over a wide range of x-ray energies. The miniature source consists of a compact vacuum tube assembly containing the hot filament cathode, an anode, a high voltage feedthru for delivering high voltage to the cathode, a getter for maintaining high vacuum, a connector for initial vacuum pump down and crimp-off, and a high voltage connection for attaching a compact high voltage cable to the high voltage feedthru. At least a portion of the vacuum tube wall is fabricated from highly x-ray transparent materials, such as sapphire, diamond, or boron nitride.

  3. Dislocation engineering in SiGe on periodic and aperiodic Si(001) templates studied by fast scanning X-ray nanodiffraction

    SciTech Connect (OSTI)

    Mondiali, Valeria; Cecchi, Stefano; Chrastina, Daniel [L-NESS, Dipartimento di Fisica, Politecnico di Milano, Polo di Como, via Anzani 42, 22100 Como (Italy); Bollani, Monica, E-mail: monica.bollani@ifn.cnr.it [IFN-CNR, L-NESS, via Anzani 42, 22100 Como (Italy); Richard, Marie-Ingrid [ID01/ESRF, BP 220, F-38043 Grenoble Cedex (France); Aix-Marseille Université, CNRS, IM2NP UMR 7334, Campus de St Jérôme, F-13397 Marseille Cedex (France); Schülli, Tobias; Chahine, Gilbert [ID01/ESRF, BP 220, F-38043 Grenoble Cedex (France)

    2014-01-13T23:59:59.000Z

    Fast-scanning X-ray nanodiffraction microscopy is used to directly visualize the misfit dislocation network in a SiGe film deposited on a pit-patterned Si substrate at the beginning of plastic relaxation. X-ray real-space diffracted intensity maps are compared to topographic atomic force microscopy images, in which crosshatch lines can be seen. The change in intensity distribution as a function of the incidence angle shows localized variations in strain within the SiGe film. These variations, which reflect the order imposed by the substrate pattern, are attributed to the presence of both bunches of misfit dislocations and defect-free regions.

  4. Space charge effects in ultrafast electron diffraction and imaging

    SciTech Connect (OSTI)

    Tao Zhensheng; Zhang He; Duxbury, P. M.; Berz, Martin; Ruan, Chong-Yu [Physics and Astronomy Department, Michigan State University, East Lansing, Michigan 48824-2320 (United States)

    2012-02-15T23:59:59.000Z

    Understanding space charge effects is central for the development of high-brightness ultrafast electron diffraction and microscopy techniques for imaging material transformation with atomic scale detail at the fs to ps timescales. We present methods and results for direct ultrafast photoelectron beam characterization employing a shadow projection imaging technique to investigate the generation of ultrafast, non-uniform, intense photoelectron pulses in a dc photo-gun geometry. Combined with N-particle simulations and an analytical Gaussian model, we elucidate three essential space-charge-led features: the pulse lengthening following a power-law scaling, the broadening of the initial energy distribution, and the virtual cathode threshold. The impacts of these space charge effects on the performance of the next generation high-brightness ultrafast electron diffraction and imaging systems are evaluated.

  5. Regularized Equally Sloped Tomography Algorithm for Low Dose X-Ray Computed Tomography

    E-Print Network [OSTI]

    Zhao, Yunzhe

    2012-01-01T23:59:59.000Z

    based imaging computed tomography extraction algorithms and10 2.2. Computed Tomography reconstruction theory andcontrast X-ray computed tomography for observing biological

  6. Regularized Equally Sloped Tomography Algorithm for Low Dose X-Ray Computed Tomography

    E-Print Network [OSTI]

    Zhao, Yunzhe

    2012-01-01T23:59:59.000Z

    based imaging computed tomography extraction algorithms andcontrast X-ray computed tomography for observing biological10 2.2. Computed Tomography reconstruction theory and

  7. X-ray absorption spectroscopy at the Ni-K edge in Stackhousia tryonii Bailey hyperaccumulator

    E-Print Network [OSTI]

    Kachenko, A.

    2009-01-01T23:59:59.000Z

    Micro x-ray ?uorescence ( -XRF) mapping was performed using15 RESULTS AND DISCUSSION -XRF imaging was used to determinelocalisation in planta. Typical -XRF maps obtained of stem,

  8. advanced x-ray techniques: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a new X-ray radiographic technique for measuring density uniformity of silica aerogels used as radiator in proximity-focusing ring-imaging Cherenkov detectors. To obtain...

  9. Design and assembly of a telecentric zoom lens for the Cygnus x-ray source

    SciTech Connect (OSTI)

    Malone, R M; Brown, K K; Curtis, A H; Esquibel, D L; Frayer, D K; Frogget, B C; Garten, J R; Howe, R A; Huerta, J A; Kaufman, M I; Lutz, S S; McGillivray, K D; Smith, S S; Furlanetto, M R; Haines, T J

    2012-08-07T23:59:59.000Z

    Our goal is to collect x-ray images of different sized targets, which are positioned inside a containment vessel, onto different sized CCD cameras.

  10. Laboratory-size three-dimensional x-ray microscope with Wolter type I mirror optics and an electron-impact water window x-ray source

    SciTech Connect (OSTI)

    Ohsuka, Shinji, E-mail: ohsuka@crl.hpk.co.jp [Hamamatsu Photonics K.K., 5000 Hirakuchi, Hamakita-ku, Hamamatsu-City, 434-8601 (Japan); The Graduate School for the Creation of New Photonics Industries, 1955-1 Kurematsu-cho, Nishi-ku, Hamamatsu-City, 431-1202 (Japan); Ohba, Akira; Onoda, Shinobu; Nakamoto, Katsuhiro [Hamamatsu Photonics K.K., 5000 Hirakuchi, Hamakita-ku, Hamamatsu-City, 434-8601 (Japan); Nakano, Tomoyasu [Hamamatsu Photonics K.K., 5000 Hirakuchi, Hamakita-ku, Hamamatsu-City, 434-8601 (Japan); Ray-Focus Co. Ltd., 6009 Shinpara, Hamakita-ku, Hamamatsu-City, 434-0003 (Japan); Miyoshi, Motosuke; Soda, Keita; Hamakubo, Takao [Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904 (Japan)

    2014-09-15T23:59:59.000Z

    We constructed a laboratory-size three-dimensional water window x-ray microscope that combines wide-field transmission x-ray microscopy with tomographic reconstruction techniques, and observed bio-medical samples to evaluate its applicability to life science research fields. It consists of a condenser and an objective grazing incidence Wolter type I mirror, an electron-impact type oxygen K? x-ray source, and a back-illuminated CCD for x-ray imaging. A spatial resolution limit of around 1.0 line pairs per micrometer was obtained for two-dimensional transmission images, and 1-?m scale three-dimensional fine structures were resolved.

  11. X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films

    E-Print Network [OSTI]

    X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large of magnesium hydride. Keywords: A. hydrogen storage materials, thin films; C. EXAFS, NEXAFS, X-ray diffraction

  12. Pixel Array Detector for Time-Resolved X-ray Science, September 1, 1997 - September 14, 2000

    SciTech Connect (OSTI)

    Gruner, Sol M.

    2000-11-07T23:59:59.000Z

    Progress on the design, fabrication, testing and assembly of two-layer Pixel Array Detectors (PADs) is described. The PADs are developed for challenging time-resolved X-ray imaging applications at synchrotron radiation X-ray sources.

  13. Compact x-ray source and panel

    DOE Patents [OSTI]

    Sampayon, Stephen E. (Manteca, CA)

    2008-02-12T23:59:59.000Z

    A compact, self-contained x-ray source, and a compact x-ray source panel having a plurality of such x-ray sources arranged in a preferably broad-area pixelized array. Each x-ray source includes an electron source for producing an electron beam, an x-ray conversion target, and a multilayer insulator separating the electron source and the x-ray conversion target from each other. The multi-layer insulator preferably has a cylindrical configuration with a plurality of alternating insulator and conductor layers surrounding an acceleration channel leading from the electron source to the x-ray conversion target. A power source is connected to each x-ray source of the array to produce an accelerating gradient between the electron source and x-ray conversion target in any one or more of the x-ray sources independent of other x-ray sources in the array, so as to accelerate an electron beam towards the x-ray conversion target. The multilayer insulator enables relatively short separation distances between the electron source and the x-ray conversion target so that a thin panel is possible for compactness. This is due to the ability of the plurality of alternating insulator and conductor layers of the multilayer insulators to resist surface flashover when sufficiently high acceleration energies necessary for x-ray generation are supplied by the power source to the x-ray sources.

  14. High performance x-ray anti-scatter grid

    DOE Patents [OSTI]

    Logan, C.M.

    1995-05-23T23:59:59.000Z

    Disclosed are an x-ray anti-scatter grid for x-ray imaging, particularly for screening mammography, and method for fabricating same, x-rays incident along a direct path pass through a grid composed of a plurality of parallel or crossed openings, microchannels, grooves, or slots etched in a substrate, such as silicon, having the walls of the microchannels or slots coated with a high opacity material, such as gold, while x-rays incident at angels with respect to the slots of the grid, arising from scatter, are blocked. The thickness of the substrate is dependent on the specific application of the grid, whereby a substrate of the grid for mammography would be thinner than one for chest radiology. Instead of coating the walls of the slots, such could be filed with an appropriate liquid, such as mercury. 4 Figs.

  15. High performance x-ray anti-scatter grid

    DOE Patents [OSTI]

    Logan, Clinton M. (Pleasanton, CA)

    1995-01-01T23:59:59.000Z

    An x-ray anti-scatter grid for x-ray imaging, particularly for screening mammography, and method for fabricating same, x-rays incident along a direct path pass through a grid composed of a plurality of parallel or crossed openings, microchannels, grooves, or slots etched in a substrate, such as silicon, having the walls of the microchannels or slots coated with a high opacity material, such as gold, while x-rays incident at angels with respect to the slots of the grid, arising from scatter, are blocked. The thickness of the substrate is dependent on the specific application of the grid, whereby a substrate of the grid for mammography would be thinner than one for chest radiology. Instead of coating the walls of the slots, such could be filed with an appropriate liquid, such as mercury.

  16. Stratigraphic correlation with X-ray powder patterns

    E-Print Network [OSTI]

    Singletary, John B

    1951-01-01T23:59:59.000Z

    pattern of maxima characteristic of all the principal spacings. For instance, if the radiation detector is set so as to observe the secondary diffracted beam at an angle which satisfies Bragg~s Law for some value of d found in the crystal, then a... focusing x-ray spectrometer manufac- tured by the North American Philips Company for commercial use. This instrument, shown in Fig. RB, consists of an x-ray generating unit, a goniometer, and a Geiger counter radiation detector. The patte ns were...

  17. The color of X-rays Spectral X-ray computed tomography using energy sensitive pixel detectors

    E-Print Network [OSTI]

    Schioppa, Enrico Junior

    Energy sensitive X-ray imaging detectors are produced by connecting a semiconductor sensor to a spectroscopic pixel readout chip. In this thesis, the applicability of such detectors to X-ray Computed Tomography (CT) is studied. A prototype Medipix based silicon detector is calibrated using X-ray fluorescence. The charge transport properties of the sensor are characterized using a high energy beam of charged particles at the Super Proton Synchrotron (SPS) at the European Center for Nuclear Research (CERN). Monochromatic X-rays at the European Synchrotron Radiation Facility (ESRF) are used to determined the energy response function. These data are used to implement a physics-based CT projection operator that accounts for the transmission of the source spectrum through the sample and detector effects. Based on this projection operator, an iterative spectral CT reconstruction algorithm is developed by extending an Ordered Subset Expectation Maximization (OSEM) method. Subsequently, a maximum likelihood based algo...

  18. Focused X-ray source

    DOE Patents [OSTI]

    Piestrup, M.A.; Boyers, D.G.; Pincus, C.I.; Maccagno, P.

    1990-08-21T23:59:59.000Z

    Disclosed is an intense, relatively inexpensive X-ray source (as compared to a synchrotron emitter) for technological, scientific, and spectroscopic purposes. A conical radiation pattern produced by a single foil or stack of foils is focused by optics to increase the intensity of the radiation at a distance from the conical radiator. 8 figs.

  19. The BMW X-ray Cluster Survey

    E-Print Network [OSTI]

    Alberto Moretti; Luigi Guzzo; Sergio Campana; Stefano Covino; Davide Lazzati; Marcella Longhetti; Emilio Molinari; Maria Rosa Panzera; Gianpiero Tagliaferri; Ian Dell'Antonio

    2001-03-21T23:59:59.000Z

    We describe the main features of the BMW survey of serendipitous X-ray clusters, based on the still unexploited ROSAT-HRI archival observations. The sky coverage, surface density and first deep optical CCD images of the candidates indicate that this sample can represent an excellent complement to the existing PSPC deep cluster surveys and will provide us with a fully independent probe of the evolution of the cluster abundance, in addition to significantly increasing the number of clusters known at z>0.6.

  20. The BMW X-ray Cluster Survey

    E-Print Network [OSTI]

    Moretti, A; Campana, S; Covino, S; Lazzati, D; Longhetti, M; Molinari, E; Panzera, M R; Tagliaferri, G; Dell'Antonio, I P; Moretti, Alberto; Guzzo, Luigi; Campana, Sergio; Covino, Stefano; Lazzati, Davide; Longhetti, Marcella; Molinari, Emilio; Panzera, Maria Rosa; Tagliaferri, Gianpiero; Antonio, Ian Dell'

    2001-01-01T23:59:59.000Z

    We describe the main features of the BMW survey of serendipitous X-ray clusters, based on the still unexploited ROSAT-HRI archival observations. The sky coverage, surface density and first deep optical CCD images of the candidates indicate that this sample can represent an excellent complement to the existing PSPC deep cluster surveys and will provide us with a fully independent probe of the evolution of the cluster abundance, in addition to significantly increasing the number of clusters known at z>0.6.

  1. Data fusion in neutron and X-ray computed tomography

    SciTech Connect (OSTI)

    Schrapp, Michael J. [Siemens AG, Corporate Technology, Otto-Hahn-Ring 6, 81739 Munich (Germany); Physik Department E21, Technische Universität München, James-Franck-Strasse 1, 85747 Garching (Germany); Goldammer, Matthias [Siemens AG, Corporate Technology, Otto-Hahn-Ring 6, 81739 Munich (Germany); Schulz, Michael [Physik Department E21, Technische Universität München, James-Franck-Strasse 1, 85747 Garching (Germany); Heinz Maier-Leibnitz Zentrum (MLZ), Technische Universität München, Lichtenbergstrasse 1, 85747 Garching (Germany); Issani, Siraj; Bhamidipati, Suryanarayana [Siemens AG, Corporate Technology, Bangalore (India); Böni, Peter [Physik Department E21, Technische Universität München, James-Franck-Strasse 1, 85747 Garching (Germany)

    2014-10-28T23:59:59.000Z

    We present a fusion methodology between neutron and X-ray computed tomography (CT). On the one hand, the inspection by X-ray CT of a wide class of multimaterials in non-destructive testing applications suffers from limited information of object features. On the other hand, neutron imaging can provide complementary data in such a way that the combination of both data sets fully characterizes the object. In this contribution, a novel data fusion procedure, called Fusion Regularized Simultaneous Algebraic Reconstruction Technique, is developed where the X-ray reconstruction is modified to fulfill the available data from the imaging with neutrons. The experiments, which were obtained from an aluminum profile containing a steel screw, and attached carbon fiber plates demonstrate that the image quality in CT can be significantly improved when the proposed fusion method is used.

  2. Inner-Shell Multiple Ionization of Polyatomic Molecules With an Intense X-Ray Free-Electron Laser Studied By Coincident Ion Momentum Imaging

    SciTech Connect (OSTI)

    Erk, B. [Max Planck Advanced Study Group and Deutsches Elektronen-Synchrotron, Hamburg (Germany); Max Planck Inst. for Nuclear Physics, Heidelberg (Germany); Rolles, D. [Max Planck Advanced Study Group and Deutsches Elektronen-Synchrotron, Hamburg (Germany); Max Planck Inst. for Medical Rearch, Heidelburg (Germany); Foucar, L. [Max Planck Society, Hamburg (Germany); Max Planck Inst. for Medical Rearch, Heidelburg (Germany); Rudek, B. [Max Planck Advanced Study Group and Deutsches Elektronen-Synchrotron, Hamburg (Germany); Max Planck Inst. for Nuclear Physics, Heidelberg (Germany); Epp, S. W. [Max Planck Society, Hamburg (Germany). Max Planck Inst. for Nuclear Physics; Max Planck Inst. for Nuclear Physics, Heidelberg (Germany); Cryle, M. [Max Planck Inst. for Medical Rearch, Heidelburg (Germany); Bostedt, C. [SLAC National Accelerator Lab., Menlo Park, CA (United States). Linac Coherent Light Source; Schorb, S. [SLAC National Accelerator Lab., Menlo Park, CA (United States). Linac Coherent Light Source; Technical Univ. Berlin (Germany). Inst. for Optic and Atomic Physics; Bozek, J. [SLAC National Accelerator Lab., Menlo Park, CA (United States). Linac Coherent Light Source; Rouzee, A. [Max Born Inst., Berlin (Germany); Hundertmark, A. [Max Born Inst., Berlin (Germany); Marchenko, T. [Laboratory of Chemical Physics, Paris (France); Simon, M. [Laboratory of Chemical Physics, Paris (France); Filsinger, F. [Fritz Haber Inst. for Max Planck Gesellschaft, Berlin (Germany); Christensen, L. [Aarhus Univ. (Denmark). Dept. of Physics and Astronomy; De, S. [Aarhus Univ. (Denmark). Dept. of Chemistry; Saha Inst. of Nuclear Physics, Kolkata (India); Trippel, S. [Center for Free-Electron Laser Science (CFEL), Hamburg (Germany); Küpper, J. [Center for Free-Electron Laser Science (CFEL) and Univ. of Hamburg, Hamburg (Germany). Dept. of Physics, Center for Ultrafast Imaging; Stapelfeldt, H. [Aarhus Univ. (Denmark). Dept. of Chemistry; Wada, S. [SLAC National Accelerator Lab., Menlo Park, CA (United States). Linac Coherent Light Source; Hiroshima Univ., Higashi-Hiroshima (Japan), Dept. of Physical Science; Ueda, K. [Tohoku Univ., Sendai (Japan). IMRAM; Swiggers, M. [SLAC National Accelerator Lab., Menlo Park, CA (United States). Linac Coherent Light Source; Messerschmidt, M. [SLAC National Accelerator Lab., Menlo Park, CA (United States). Linac Coherent Light Source; Schröter, C. D. [Max Planck Inst. for Nuclear Physics, Heidelberg (Germany); Moshammer, R. [Max Planck Society, Hamburg (Germany). Max Planck Inst. for Nuclear Physics; Max Planck Inst. for Nuclear Physics, Heidelberg (Germany); Schlichting, I. [Max Planck Society, Hamburg (Germany); Max Planck Inst. for Medical Rearch, Heidelburg (Germany); Ullrich, J. [Max Planck Society, Hamburg (Germany). Max Planck Inst. for Nuclear Physics; Max Planck Inst. for Nuclear Physics, Heidelberg (Germany); National Institute for Physics and Technology, Braunschweig (Germany); Rudenko, A. [Max Planck Society, Hamburg (Germany). Max Planck Inst. for Nuclear Physics; Max Planck Inst. for Nuclear Physics, Heidelberg (Germany); Kansas State Univ., Manhattan, KS (United States). Dept. of Physics

    2013-08-28T23:59:59.000Z

    The ionization and fragmentation of two selenium containing hydrocarbon molecules, methylselenol (CH3SeH) and ethylselenol (C2H5SeH), by intense (>1017 W cm-2 ) 5 fs x-ray pulses with photon energies of 1.7 and 2 keV has been studied by means of coincident ion momentum spectroscopy. Measuring charge states and ion kinetic energies, we find signatures of charge redistribution within the molecular environment. Furthermore, by analyzing fragment ion angular correlations, we can determine the laboratory-frame orientation of individual molecules and thus investigate the fragmentation dynamics in the molecular frame. This allows distinguishing protons originating from different molecular sites along with identifying the reaction channels that lead to their emission.

  3. Inner-Shell Multiple Ionization of Polyatomic Molecules With an Intense X-Ray Free-Electron Laser Studied By Coincident Ion Momentum Imaging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Erk, B.; Rolles, D.; Foucar, L.; Rudek, B.; Epp, S. W.; Cryle, M.; Bostedt, C.; Schorb, S.; Bozek, J.; Rouzee, A.; et al

    2013-08-28T23:59:59.000Z

    The ionization and fragmentation of two selenium containing hydrocarbon molecules, methylselenol (CH3SeH) and ethylselenol (C2H5SeH), by intense (>1017 W cm-2 ) 5 fs x-ray pulses with photon energies of 1.7 and 2 keV has been studied by means of coincident ion momentum spectroscopy. Measuring charge states and ion kinetic energies, we find signatures of charge redistribution within the molecular environment. Furthermore, by analyzing fragment ion angular correlations, we can determine the laboratory-frame orientation of individual molecules and thus investigate the fragmentation dynamics in the molecular frame. This allows distinguishing protons originating from different molecular sites along with identifying the reactionmore »channels that lead to their emission.« less

  4. PROBING DYNAMICS OF ELECTRON ACCELERATION WITH RADIO AND X-RAY SPECTROSCOPY, IMAGING, AND TIMING IN THE 2002 APRIL 11 SOLAR FLARE

    SciTech Connect (OSTI)

    Fleishman, Gregory D.; Nita, Gelu M.; Gary, Dale E. [Center for Solar-Terrestrial Research, New Jersey Institute of Technology, Newark, NJ 07102 (United States); Kontar, Eduard P. [Department of Physics and Astronomy, University of Glasgow, Glasgow G12 8QQ (United Kingdom)

    2013-05-10T23:59:59.000Z

    Based on detailed analysis of radio and X-ray observations of a flare on 2002 April 11 augmented by realistic three-dimensional modeling, we have identified a radio emission component produced directly at the flare acceleration region. This acceleration region radio component has distinctly different (1) spectrum, (2) light curves, (3) spatial location, and, thus, (4) physical parameters from those of the separately identified trapped or precipitating electron components. To derive evolution of physical parameters of the radio sources we apply forward fitting of the radio spectrum time sequence with the gyrosynchrotron source function with five to six free parameters. At the stage when the contribution from the acceleration region dominates the radio spectrum, the X-ray- and radio-derived electron energy spectral indices agree well with each other. During this time the maximum energy of the accelerated electron spectrum displays a monotonic increase with time from {approx}300 keV to {approx}2 MeV over roughly one minute duration indicative of an acceleration process in the form of growth of the power-law tail; the fast electron residence time in the acceleration region is about 2-4 s, which is much longer than the time of flight and so requires a strong diffusion mode there to inhibit free-streaming propagation. The acceleration region has a relatively strong magnetic field, B {approx} 120 G, and a low thermal density, n{sub e} {approx}< 2 Multiplication-Sign 10{sup 9} cm{sup -3}. These acceleration region properties are consistent with a stochastic acceleration mechanism.

  5. Producing X-rays at the APS

    ScienceCinema (OSTI)

    None

    2013-04-19T23:59:59.000Z

    An introduction and overview of the Advanced Photon Source at Argonne National Laboratory, the technology that produces the brightest X-ray beams in the Western Hemisphere, and the research carried out by scientists using those X-rays.

  6. APS X-rays Reveal Picasso's Secret

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | 2003 | 2002 | 2001 2000 Subscribe to APS News rss feed APS X-rays Reveal Picasso's Secret OCTOBER 15, 2012 Bookmark and Share X-rays reveal that Picasso's "Old Guitarist," at...

  7. Spectral analysis of X-ray binaries

    E-Print Network [OSTI]

    Fridriksson, Joel Karl

    2011-01-01T23:59:59.000Z

    In this thesis, I present work from three separate research projects associated with observations of X-ray binaries. Two of those revolve around spectral characteristics of neutron star low-mass X-ray binaries (NS-LMXBs), ...

  8. X-ray and Near-infrared Studies of a Star-forming Cloud; L1448

    E-Print Network [OSTI]

    M. Tsujimoto; N. Kobayashi; Y. Tsuboi

    2005-06-27T23:59:59.000Z

    We present the results of X-ray and near-infrared (NIR) observations of L1448, a star-forming region in the Perseus cloud complex using the Chandra X-ray Observatory and the 4 m telescope at the Kitt Peak National Observatory. We detect 72 X-ray sources in a ~17 arcmin x 17 arcmin region with a ~68 ks ACIS exposure, for which we conduct follow-up NIR imaging observations in a concentric ~11 arcmin x 11 arcmin region with FLAMINGOS down to m_Ks ~ 17 mag. Twelve X-ray sources have NIR or optical counterparts. By plotting X-ray mean energy versus NIR to X-ray flux ratio, the X-ray sources are clearly separated into two groups. The X-ray spectral and temporal features as well as NIR magnitudes and colors indicate that one group mainly consists of young stellar objects (YSOs) in the cloud and the other of background extragalactic sources. Ten X-ray-emitting YSO candidates are thus newly identified, which are low-mass or brown dwarf mass sources from their NIR magnitudes. In addition, a possible X-ray signal is found from a mid-infrared protostar L1448 IRS 3(A). The lack of detection of this source in our deep NIR images indicates that this source has a very steep spectral slope of > 3.2 in 2--10 micron.

  9. Microgap x-ray detector

    DOE Patents [OSTI]

    Wuest, C.R.; Bionta, R.M.; Ables, E.

    1994-05-03T23:59:59.000Z

    An x-ray detector is disclosed which provides for the conversion of x-ray photons into photoelectrons and subsequent amplification of these photoelectrons through the generation of electron avalanches in a thin gas-filled region subject to a high electric potential. The detector comprises a cathode (photocathode) and an anode separated by the thin, gas-filled region. The cathode may comprise a substrate, such a beryllium, coated with a layer of high atomic number material, such as gold, while the anode can be a single conducting plane of material, such as gold, or a plane of resistive material, such as chromium/silicon monoxide, or multiple areas of conductive or resistive material, mounted on a substrate composed of glass, plastic or ceramic. The charge collected from each electron avalanche by the anode is passed through processing electronics to a point of use, such as an oscilloscope. 3 figures.

  10. Microgap x-ray detector

    DOE Patents [OSTI]

    Wuest, Craig R. (Danville, CA); Bionta, Richard M. (Livermore, CA); Ables, Elden (Livermore, CA)

    1994-01-01T23:59:59.000Z

    An x-ray detector which provides for the conversion of x-ray photons into photoelectrons and subsequent amplification of these photoelectrons through the generation of electron avalanches in a thin gas-filled region subject to a high electric potential. The detector comprises a cathode (photocathode) and an anode separated by the thin, gas-filled region. The cathode may comprise a substrate, such a beryllium, coated with a layer of high atomic number material, such as gold, while the anode can be a single conducting plane of material, such as gold, or a plane of resistive material, such as chromium/silicon monoxide, or multiple areas of conductive or resistive material, mounted on a substrate composed of glass, plastic or ceramic. The charge collected from each electron avalanche by the anode is passed through processing electronics to a point of use, such as an oscilloscope.

  11. The PICASSO digital detector for Diffraction Enhanced Imaging at ELETTRA

    SciTech Connect (OSTI)

    Arfelli, F.; Longo, R.; Castelli, E. [Physics Department, University of Trieste, Via Valerio 2, 34127 Trieste (Italy); INFN, Sezione di Trieste, Via Valerio 2, 34127 Trieste (Italy); Astolfo, A. [Physics Department, University of Trieste, Via Valerio 2, 34127 Trieste (Italy); Menk, R.-H. [Sincrotrone Trieste SCpA, S.S. 14 km 163.5, 34012 Basovizza, Trieste (Italy); INFN, Sezione di Trieste, Via Valerio 2, 34127 Trieste (Italy); Rigon, L.; Vallazza, E. [INFN, Sezione di Trieste, Via Valerio 2, 34127 Trieste (Italy); Zanconati, F.; De Pellegrin, A. [Department of Pathologic Anatomy, University of Trieste, Strada di Fiume 449, 34149 Trieste (Italy); Chen, R. C. [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); INFN, Sezione di Trieste, Via Valerio 2, 34127 Trieste (Italy); Dreossi, D. [Sincrotrone Trieste SCpA, S.S. 14 km 163.5, 34012 Basovizza, Trieste (Italy)

    2010-07-23T23:59:59.000Z

    A clinical mammography program is in progress at the medical beamline SYRMEP of the Italian synchrotron radiation laboratory ELETTRA in Trieste. A conventional screen-film system is utilized as detector for the examinations on patients. For the next experimental step a digital detector has been designed taking into account the essential requirements for mammography such as high spatial and contrast resolution, high efficiency for low dose examinations and high speed for short acquisition time. A double-layer prototype has already been tested in the frame of the PICASSO project. In addition, an analyzer crystal set-up for Diffraction Enhanced Imaging (DEI) has been available for many years at the SYRMEP beamline. Applying the DEI technique several successful experiments have been carried out in biomedical imaging and in particular in-vitro breast imaging utilizing commercially available detectors. Recently a system upgrade yielded a double-crystal analyzer set-up with improved stability and higher angular resolution. In this study the PICASSO detector has been utilized in combination with the new analyzer set-up for imaging in-vitro breast tissue samples. In order to test the potential of the combined system planar and tomographic images have been acquired and the first results are here presented.

  12. X-ray radiography with highly charged ions

    DOE Patents [OSTI]

    Marrs, Roscoe E. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    An extremely small (1-250 micron FWHM) beam of slow highly charged ions deexciting on an x-ray production target generates x-ray monochromatic radiation that is passed through a specimen and detected for imaging. The resolution of the x-ray radiograms is improved and such detection is achieved with relatively low dosages of radiation passing through the specimen. An apparatus containing an electron beam ion trap (and modifications thereof) equipped with a focusing column serves as a source of ions that generate radiation projected onto an image detector. Electronic and other detectors are able to detect an increased amount of radiation per pixel than achieved by previous methods and apparati.

  13. Crystallization and preliminary X-ray crystallographic analysis of a galactose-specific lectin from Dolichos lablab

    SciTech Connect (OSTI)

    Lavanya Latha, V.; Kulkarni, Kiran A. [Molecular Biophysics Unit, Indian Institute of Science, Bangalore 560 012 (India); Nagender Rao, R.; Siva Kumar, N. [Department of Biochemistry, University of Hyderabad, Hyderabad 500 046 (India); Suguna, K., E-mail: suguna@mbu.iisc.ernet.in [Molecular Biophysics Unit, Indian Institute of Science, Bangalore 560 012 (India)

    2006-02-01T23:59:59.000Z

    The galactose-specific lectin from the seeds of a leguminous plant, D. lablab, has been crystallized. Molecular-replacement solution using 3.0 Å X-ray diffraction data showed the lectin to be a tetramer. The galactose-specific lectin from the seeds of Dolichos lablab has been crystallized using the hanging-drop vapour-diffusion technique. The crystals belong to space group P1, with unit-cell parameters a = 73.99, b = 84.13, c = 93.15 Å, ? = 89.92, ? = 76.01, ? = 76.99°. X-ray diffraction data to a resolution of 3.0 Å have been collected under cryoconditions (100 K) using a MAR imaging-plate detector system mounted on a rotating-anode X-ray generator. Molecular-replacement calculations carried out using the available structures of legume lectins as search models revealed that the galactose-specific lectin from D. lablab forms a tetramer similar to soybean agglutinin; two such tetramers are present in the asymmetric unit.

  14. What are Being Discovered by the Forefront Cosmic X-ray Observations?

    E-Print Network [OSTI]

    Ejiri, Shinji

    ) The launch of Suzaku by the Mu-5 rocket on 2005 July 10, from the JAXA's Uchi- noura Space Center. (right knowledge on the X-ray Universe had to wait the detection of Solar X-rays in 1949 using V-2 rockets [18 MAXI (Monitor of All-sky X-ray Image) [9] which was transported in 2009 July by Space Shuttle onto

  15. Mapping Local Strain in Thin Film/Substrate Systems using X-ray

    SciTech Connect (OSTI)

    Yan,H.; Murray, C.; Noyan, I.

    2007-01-01T23:59:59.000Z

    The authors report experimental data and modeling results for reflection microbeam x-ray topographs from a Si substrate strained by an overlying pseudomorphic SiGe film edge. The diffracted x-ray intensity from the Si substrate is strongly asymmetric as a function of distance from the film edge. A model of the diffracted intensity based on the classical Ewald-von Laue dynamical diffraction theory for an antisymmetric strain distribution indicates that the asymmetry in the diffracted beam profile is only due to the scattering process; individual intensity maxima in the intensity profile cannot be uniquely ascribed to individual features in the local strain distribution.

  16. X-ray spectroscopy of low-mass X-ray binaries

    E-Print Network [OSTI]

    Juett, Adrienne Marie, 1976-

    2004-01-01T23:59:59.000Z

    I present high-resolution X-ray grating spectroscopy of neutron stars in low-mass X-ray binaries (LMXBs) using instruments onboard the Chandra X-ray Observatory and the X-ray Multi-Mirror Mission (XMM-Newton). The first ...

  17. Extending The Methodology Of X-ray Crystallography To Allow X-ray

    E-Print Network [OSTI]

    Miao, Jianwei "John"

    , the radiation damage. While the radiation damage problem can be mitigated somewhat by using cryogenic techniques resolution without serious radiation damage to the specimens. Although X-ray crystallography becomesExtending The Methodology Of X-ray Crystallography To Allow X-ray Microscopy Without X-ray Optics

  18. Synchronization of x-ray pulses to the pump laser in an ultrafast x-ray facility

    E-Print Network [OSTI]

    Corlett, J.N.; Barry, W.; Byrd, J.M.; Schoenlein, R.; Zholents, A.

    2002-01-01T23:59:59.000Z

    Accurate timing of ultrafast x-ray probe pulses emitted fromOF X-RAY PULSES TO THE PUMP LASER IN AN ULTRAFAST X-RAY

  19. X-ray and Near-infrared Studies of a Star-forming Cloud; L1448

    E-Print Network [OSTI]

    Tsujimoto, M; Tsuboi, Y

    2005-01-01T23:59:59.000Z

    We present the results of X-ray and near-infrared (NIR) observations of L1448, a star-forming region in the Perseus cloud complex using the Chandra X-ray Observatory and the 4 m telescope at the Kitt Peak National Observatory. We detect 72 X-ray sources in a ~17 arcmin x 17 arcmin region with a ~68 ks ACIS exposure, for which we conduct follow-up NIR imaging observations in a concentric ~11 arcmin x 11 arcmin region with FLAMINGOS down to m_Ks ~ 17 mag. Twelve X-ray sources have NIR or optical counterparts. By plotting X-ray mean energy versus NIR to X-ray flux ratio, the X-ray sources are clearly separated into two groups. The X-ray spectral and temporal features as well as NIR magnitudes and colors indicate that one group mainly consists of young stellar objects (YSOs) in the cloud and the other of background extragalactic sources. Ten X-ray-emitting YSO candidates are thus newly identified, which are low-mass or brown dwarf mass sources from their NIR magnitudes. In addition, a possible X-ray signal is fou...

  20. Interferometric phase detection at x-ray energies via Fano resonance control

    E-Print Network [OSTI]

    K. P. Heeg; C. Ott; D. Schumacher; H. -C. Wille; R. Röhlsberger; T. Pfeifer; J. Evers

    2014-11-06T23:59:59.000Z

    Modern x-ray light sources promise access to structure and dynamics of matter in largely unexplored spectral regions. However, the desired information is encoded in the light intensity and phase, whereas detectors register only the intensity. This phase problem is ubiquitous in crystallography and imaging, and impedes the exploration of quantum effects at x-ray energies. Here, we demonstrate phase-sensitive measurements characterizing the quantum state of a nuclear two-level system at hard x-ray energies. The nuclei are initially prepared in a superposition state. Subsequently, the relative phase of this superposition is interferometrically reconstructed from the emitted x-rays. Our results form a first step towards x-ray quantum state tomography, and provide new avenues for structure determination and precision metrology via x-ray Fano interference.