Sample records for x-ray absorption spectroscopy

  1. SMB, X-ray Absorption Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection245C Unlimited ReleaseWelcome to theAbsorption Spectroscopy X-ray

  2. Transient x-ray absorption spectroscopy of hydrated halogen atom

    E-Print Network [OSTI]

    Elles, Christopher G.; Shkrob, Ilya A.; Crowell, Robert A.; Arms, Dohn A.; Landahl, Eric C.

    2008-02-11T23:59:59.000Z

    Time-resolved x-ray absorption spectroscopy has been used to observe the transient species generated by one-photon detachment of an electron from aqueous bromide. The K-edge spectrum of the short-lived Br(0) atom exhibits a resonant 1s-4p transition...

  3. Simulating Ru L3-edge X-ray Absorption Spectroscopy with Time...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ru L3-edge X-ray Absorption Spectroscopy with Time-Dependent Density Functional Theory: Model Complexes and Electron Simulating Ru L3-edge X-ray Absorption Spectroscopy with...

  4. ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING CONFIGURATIONS OF

    E-Print Network [OSTI]

    Sparks, Donald L.

    ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING Rights Reserved #12;ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE

  5. X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films

    E-Print Network [OSTI]

    X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large of magnesium hydride. Keywords: A. hydrogen storage materials, thin films; C. EXAFS, NEXAFS, X-ray diffraction

  6. X-ray absorption spectroscopy of biomimetic dye molecules for solar cells Peter L. Cook,1

    E-Print Network [OSTI]

    Himpsel, Franz J.

    X-ray absorption spectroscopy of biomimetic dye molecules for solar cells Peter L. Cook,1 Xiaosong November 2009 Dye-sensitized solar cells are potentially inexpensive alternatives to traditional semiconductor solar cells. In order to optimize dyes for solar cells we systematically investigate

  7. A new endstation at the Swiss Light Source for ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy measurements of liquid solutions

    SciTech Connect (OSTI)

    Brown, Matthew A.; Redondo, Amaia Beloqui; Duyckaerts, Nicolas; Mächler, Jean-Pierre [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland)] [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland); Jordan, Inga; Wörner, Hans Jakob [Laboratory of Physical Chemistry, ETH Zürich, CH-8093 Zürich (Switzerland)] [Laboratory of Physical Chemistry, ETH Zürich, CH-8093 Zürich (Switzerland); Lee, Ming-Tao; Ammann, Markus; Nolting, Frithjof; Kleibert, Armin; Huthwelker, Thomas; Birrer, Mario; Honegger, Juri; Wetter, Reto [Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland)] [Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland); Bokhoven, Jeroen A. van [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland) [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland); Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland)

    2013-07-15T23:59:59.000Z

    A new liquid microjet endstation designed for ultraviolet (UPS) and X-ray (XPS) photoelectron, and partial electron yield X-ray absorption (XAS) spectroscopies at the Swiss Light Source is presented. The new endstation, which is based on a Scienta HiPP-2 R4000 electron spectrometer, is the first liquid microjet endstation capable of operating in vacuum and in ambient pressures up to the equilibrium vapor pressure of liquid water at room temperature. In addition, the Scienta HiPP-2 R4000 energy analyzer of this new endstation allows for XPS measurements up to 7000 eV electron kinetic energy that will enable electronic structure measurements of bulk solutions and buried interfaces from liquid microjet samples. The endstation is designed to operate at the soft X-ray SIM beamline and at the tender X-ray Phoenix beamline. The endstation can also be operated using a Scienta 5 K ultraviolet helium lamp for dedicated UPS measurements at the vapor-liquid interface using either He I or He II ? lines. The design concept, first results from UPS, soft X-ray XPS, and partial electron yield XAS measurements, and an outlook to the potential of this endstation are presented.

  8. Use of X-ray Absorption Spectroscopy to Distinguish Between Inner And Outer-sphere Pb Adsorption Complexes on Montmorillonite

    E-Print Network [OSTI]

    Sparks, Donald L.

    Use of X-ray Absorption Spectroscopy to Distinguish Between Inner And Outer-sphere Pb Adsorption on the functional groups at the edges of the montmorillonite. At I = 0.002 M Pb absorption was less dependent

  9. Gas cell for in situ soft X-ray transmission-absorption spectroscopy of materials

    SciTech Connect (OSTI)

    Drisdell, W. S.; Kortright, J. B. [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    2014-07-15T23:59:59.000Z

    A simple gas cell design, constructed primarily from commercially available components, enables in situ soft X-ray transmission-absorption spectroscopy of materials in contact with gas at ambient temperature. The cell has a minimum X-ray path length of 1 mm and can hold gas pressures up to ?300 Torr, and could support higher pressures with simple modifications. The design enables cycling between vacuum and gas environments without interrupting the X-ray beam, and can be fully sealed to allow for measurements of air-sensitive samples. The cell can attach to the downstream port of any appropriate synchrotron beamline, and offers a robust and versatile method for in situ measurements of certain materials. The construction and operation of the cell are discussed, as well as sample preparation and proper spectral analysis, illustrated by examples of spectral measurements. Potential areas for improvement and modification for specialized applications are also mentioned.

  10. Electrochemical flowcell for in-situ investigations by soft x-ray absorption and emission spectroscopy

    SciTech Connect (OSTI)

    Schwanke, C.; Lange, K. M., E-mail: Kathrin.lange@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Solar Fuels, Albert-Einstein-Straße 15, 12489 Berlin (Germany); Golnak, R.; Xiao, J. [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Methods for Material Development, Albert-Einstein-Straße 15, 12489 Berlin (Germany)

    2014-10-15T23:59:59.000Z

    A new liquid flow-cell designed for electronic structure investigations at the liquid-solid interface by soft X-ray absorption and emission spectroscopy is presented. A thin membrane serves simultaneously as a substrate for the working electrode and solid state samples as well as for separating the liquid from the surrounding vacuum conditions. In combination with counter and reference electrodes this approach allows in-situ studies of electrochemical deposition processes and catalytic reactions at the liquid-solid interface in combination with potentiostatic measurements. As model system in-situ monitoring of the deposition process of Co metal from a 10 mM CoCl{sub 2} aqueous solution by X-ray absorption and emission spectroscopy is presented.

  11. Atomic structure of machined semiconducting chips: An x-ray absorption spectroscopy study

    SciTech Connect (OSTI)

    Paesler, M.; Sayers, D.

    1988-12-01T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) has been used to examine the atomic structure of chips of germanium that were produced by single point diamond machining. It is demonstrated that although the local (nearest neighbor) atomic structure is experimentally quite similar to that of single crystal specimens information from more distant atoms indicates the presence of considerable stress. An outline of the technique is given and the strength of XAS in studying the machining process is demonstrated.

  12. Note: Application of a pixel-array area detector to simultaneous single crystal x-ray diffraction and x-ray absorption spectroscopy measurements

    SciTech Connect (OSTI)

    Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov; Brewe, Dale L.; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Chen, Jing-Sheng; Chow, G. M. [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore)] [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore) [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Department of Physics, National University of Singapore, 117542 Singapore (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, 117575 Singapore (Singapore)

    2014-04-15T23:59:59.000Z

    X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are two main x-ray techniques in synchrotron radiation facilities. In this Note, we present an experimental setup capable of performing simultaneous XRD and XAS measurements by the application of a pixel-array area detector. For XRD, the momentum transfer in specular diffraction was measured by scanning the X-ray energy with fixed incoming and outgoing x-ray angles. By selecting a small fixed region of the detector to collect the XRD signal, the rest of the area was available for collecting the x-ray fluorescence for XAS measurements. The simultaneous measurement of XRD and X-ray absorption near edge structure for Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film was demonstrated as a proof of principle for future time-resolved pump-probe measurements. A static sample makes it easy to maintain an accurate overlap of the X-ray spot and laser pump beam.

  13. GEOC Thursday, March 25, 2010 192 -In situ characterization of environmental redox reactions using quick-scanning X-ray absorption spectroscopy

    E-Print Network [OSTI]

    Sparks, Donald L.

    quick-scanning X-ray absorption spectroscopy (Q-XAS) Donald L Sparks, Dr. Matthew Ginder-Vogel, Dr. In this presentation, we will describe the use of quick X-ray absorption spectroscopy (Q-XAS), at a subsecond time by calculated rate constants that do not change with concentration. In addition to using X-ray absorption near

  14. Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions at the Soil/Water Interface

    E-Print Network [OSTI]

    Sparks, Donald L.

    Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions on the surface coordination environment of Ni sorbed onto clays and aluminum oxides using X-ray absorption fine

  15. X-ray absorption spectroscopy studies of electrochemically deposited thin oxide films.

    SciTech Connect (OSTI)

    Balasubramanian, M.

    1998-06-02T23:59:59.000Z

    We have utilized ''in situ'' X-ray Absorption Fine Structure Spectroscopy to investigate the structure and composition of thin oxide films of nickel and iron that have been prepared by electrodeposition on a graphite substrate from aqueous solutions. The films are generally disordered. Structural information has been obtained from the analysis of the data. We also present initial findings on the local structure of heavy metal ions, e.g. Sr and Ce, incorporated into the electrodeposited nickel oxide films. Our results are of importance in a number of technological applications, among them, batteries, fuel cells, electrochromic and ferroelectric materials, corrosion protection, as well as environmental speciation and remediation.

  16. Americium characterization by X-ray fluorescence and absorption spectroscopy in plutonium uranium mixed oxide

    SciTech Connect (OSTI)

    Degueldre, Claude, E-mail: claude.degueldre@psi.ch; Cozzo, Cedric; Martin, Matthias; Grolimund, Daniel; Mieszczynski, Cyprian

    2013-06-01T23:59:59.000Z

    Plutonium uranium mixed oxide (MOX) fuels are currently used in nuclear reactors. The actinides in these fuels need to be analyzed after irradiation for assessing their behaviour with regard to their environment and the coolant. In this work the study of the atomic structure and next-neighbour environment of Am in the (Pu,U)O? lattice in an irradiated (60 MW d kg?¹) MOX sample was performed employing micro-X-ray fluorescence (µ-XRF) and micro-X-ray absorption fine structure (µ-XAFS) spectroscopy. The chemical bonds, valences and stoichiometry of Am (~0.66 wt%) are determined from the experimental data gained for the irradiated fuel material examined in its peripheral zone (rim) of the fuel. In the irradiated sample Am builds up as Am³? species within an [AmO?]¹³? coordination environment (e.g. >90%) and no (<10%) Am(IV) or (V) can be detected in the rim zone. The occurrence of americium dioxide is avoided by the redox buffering activity of the uranium dioxide matrix. - Graphical abstract: Americium LIII XAFS spectra recorded for the irradiated MOX sub-sample in the rim zone for a 300 ?m×300 ?m beam size area investigated over six scans of 4 h. The records remain constant during multi-scan. The analysis of the XAFS signal shows that Am is found as trivalent in the UO? matrix. This analytical work shall open the door of very challenging analysis (speciation of fission product and actinides) in irradiated nuclear fuels. - Highlights: • Americium was characterized by microX-ray absorption spectroscopy in irradiated MOX fuel. • The americium redox state as determined from XAS data of irradiated fuel material was Am(III). • In the sample, the Am³? face an AmO?¹³?coordination environment in the (Pu,U)O? matrix. • The americium dioxide is reduced by the uranium dioxide matrix.

  17. New Homogeneous Standards by Atomic Layer Deposition for Synchrotron X-ray Fluorescence and Absorption Spectroscopies.

    SciTech Connect (OSTI)

    Butterworth, A.L.; Becker, N.; Gainsforth, Z.; Lanzirotti, A.; Newville, M.; Proslier, T.; Stodolna, J.; Sutton, S.; Tyliszczak, T.; Westphal, A.J.; Zasadzinski, J. (UCB)

    2012-03-13T23:59:59.000Z

    Quantification of synchrotron XRF analyses is typically done through comparisons with measurements on the NIST SRM 1832/1833 thin film standards. Unfortunately, these standards are inhomogeneous on small scales at the tens of percent level. We are synthesizing new homogeneous multilayer standards using the Atomic Layer Deposition technique and characterizing them using multiple analytical methods, including ellipsometry, Rutherford Back Scattering at Evans Analytical, Synchrotron X-ray Fluorescence (SXRF) at Advanced Photon Source (APS) Beamline 13-ID, Synchrotron X-ray Absorption Spectroscopy (XAS) at Advanced Light Source (ALS) Beamlines 11.0.2 and 5.3.2.1 and by electron microscopy techniques. Our motivation for developing much-needed cross-calibration of synchrotron techniques is borne from coordinated analyses of particles captured in the aerogel of the NASA Stardust Interstellar Dust Collector (SIDC). The Stardust Interstellar Dust Preliminary Examination (ISPE) team have characterized three sub-nanogram, {approx}1{micro}m-sized fragments considered as candidates to be the first contemporary interstellar dust ever collected, based on their chemistries and trajectories. The candidates were analyzed in small wedges of aerogel in which they were extracted from the larger collector, using high sensitivity, high spatial resolution >3 keV synchrotron x-ray fluorescence spectroscopy (SXRF) and <2 keV synchrotron x-ray transmission microscopy (STXM) during Stardust ISPE. The ISPE synchrotron techniques have complementary capabilities. Hard X-ray SXRF is sensitive to sub-fg mass of elements Z {ge} 20 (calcium) and has a spatial resolution as low as 90nm. X-ray Diffraction data were collected simultaneously with SXRF data. Soft X-ray STXM at ALS beamline 11.0.2 can detect fg-mass of most elements, including cosmochemically important oxygen, magnesium, aluminum and silicon, which are invisible to SXRF in this application. ALS beamline 11.0.2 has spatial resolution better than 25 nm. Limiting factors for Stardust STXM analyses were self-imposed limits of photon dose due to radiation damage concerns, and significant attenuation of <1500 eV X-rays by {approx}80{micro}m thick, {approx}25 mg/cm{sup 3} density silica aerogel capture medium. In practice, the ISPE team characterized the major, light elements using STXM (O, Mg, Al, Si) and the heavier minor and trace elements using SXRF. The two data sets overlapped only with minor Fe and Ni ({approx}1% mass abundance), providing few quantitative cross-checks. New improved standards for cross calibration are essential for consortium-based analyses of Stardust interstellar and cometary particles, IDPs. Indeed, they have far reaching application across the whole synchrotron-based analytical community. We have synthesized three ALD multilayers simultaneously on silicon nitride membranes and silicon and characterized them using RBS (on Si), XRF (on Si{sub 3}N{sub 4}) and STXM/XAS (holey Si{sub 3}N{sub 4}). The systems we have started to work with are Al-Zn-Fe and Y-Mg-Er. We have found these ALD multi-layers to be uniform at {micro}m- to nm scales, and have found excellent consistency between four analytical techniques so far. The ALD films can also be used as a standard for e-beam instruments, eg., TEM EELS or EDX. After some early issues with the consistency of coatings to the back-side of the membrane windows, we are confident to be able to show multi-analytical agreement to within 10%. As the precision improves, we can use the new standards to verify or improve the tabulated cross-sections.

  18. Millisecond Kinetics of Nanocrystal Cation Exchange UsingMicrofluidic X-ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Chan, Emory M.; Marcus, Matthew A.; Fakra, Sirine; Elnaggar,Mariam S.; Mathies, Richard A.; Alivisatos, A. Paul

    2007-05-07T23:59:59.000Z

    We describe the use of a flow-focusing microfluidic reactorto measure the kinetics of theCdSe-to-Ag2Se nanocrystal cation exchangereaction using micro-X-ray absorption spectroscopy (mu XAS). The smallmicroreactor dimensions facilitate the millisecond mixing of CdSenanocrystal and Ag+ reactant solutions, and the transposition of thereaction time onto spatial coordinates enables the in situ observation ofthe millisecond reaction with mu XAS. XAS spectra show the progression ofCdSe nanocrystals to Ag2Se over the course of 100 ms without the presenceof long-lived intermediates. These results, along with supporting stoppedflow absorption experiments, suggest that this nanocrystal cationexchange reaction is highly efficient and provide insight into how thereaction progresses in individual particles. This experiment illustratesthe value and potential of in situ microfluidic X-ray synchrotrontechniques for detailed studies of the millisecond structuraltransformations of nanoparticles and other solution-phase reactions inwhich diffusive mixing initiates changes in local bond structures oroxidation states.

  19. Electronic Structure of Transition Metal-Cysteine Complexes From X-Ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Leung, B.O.; Jalilehvand, F.; Szilagyi, R.K.

    2009-05-19T23:59:59.000Z

    The electronic structures of Hg{sup II}, Ni{sup II}, Cr{sup III}, and Mo{sup V} complexes with cysteine were investigated by sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy and density functional theory. The covalency in the metal-sulfur bond was determined by analyzing the intensities of the electric-dipole allowed pre-edge features appearing in the XANES spectra below the ionization threshold. Because of the well-defined structures of the selected cysteine complexes, the current work provides a reference set for further sulfur K-edge XAS studies of bioinorganic active sites with transition metal-sulfur bonds from cysteine residues as well as more complex coordination compounds with thiolate ligands.

  20. Tin Valence and Local Environments in Silicate Glasses as Determined From X-ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    McKeown,D.; Buechele, A.; Gan, H.; Pegg, I.

    2008-01-01T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) was used to characterize the tin (Sn) environments in four borosilicate glass nuclear waste formulations, two silicate float glasses, and three potassium aluminosilicate glasses. Sn K-edge XAS data of most glasses investigated indicate Sn4+O6 units with average Sn-O distances near 2.03 Angstroms. XAS data for a float glass fabricated under reducing conditions show a mixture of Sn4+O6 and Sn2+O4 sites. XAS data for three glasses indicate Sn-Sn distances ranging from 3.43 to 3.53 Angstroms, that suggest Sn4+O6 units linking with each other, while the 4.96 Angstroms Sn-Sn distance for one waste glass suggests clustering of unlinked Sn4+O6 units.

  1. Dissimilar behavior of technetium and rhenium in borosilicate waste glass as determined by X-ray absorption spectroscopy

    E-Print Network [OSTI]

    Lukens, Wayne W.; McKeown, David A.; Buechele, Andrew C.; Muller, Isabelle S.; Shuh, David K.; Pegg, Ian L.

    2006-01-01T23:59:59.000Z

    by X-ray fluorescence (XRF) spectroscopy with a relativeuncertainty of 4%. XRF analyses utilized an ARL 9400X-ray fluorescence spectrometer with XRF composition values

  2. Design and operation of an in situ high pressure reaction cell for x-ray absorption spectroscopy.

    SciTech Connect (OSTI)

    Bare, S. R.; Yang, N.; Kelly, S. D.; Mickelson, G. E.; Modica, F. S.; UOP LLC; EXAFS Analysis

    2007-01-01T23:59:59.000Z

    The design and initial operation of an in situ catalysis reaction cell for x-ray absorption spectroscopy measurements at high pressure is described. The design is based on an x-ray transparent tube fabricated from beryllium. This forms a true plug flow reactor for catalysis studies. The reactor is coupled to a portable microprocessor-controlled versatile feed system, and incorporates on-line analysis of reaction products. XAFS data recorded during the reduction of a NiRe/carbon catalyst at 4 bar are used to illustrate the performance of the reactor.

  3. Design and Operation of an In Situ High Pressure Reaction Cell for X-Ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Bare, Simon R.; Mickelson, G. E.; Modica, F. S. [UOP LLC, Des Plaines, IL, 60016 (United States); Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 6044 (United States)

    2007-02-02T23:59:59.000Z

    The design and initial operation of an in situ catalysis reaction cell for x-ray absorption spectroscopy measurements at high pressure is described. The design is based on an x-ray transparent tube fabricated from beryllium. This forms a true plug flow reactor for catalysis studies. The reactor is coupled to a portable microprocessor-controlled versatile feed system, and incorporates on-line analysis of reaction products. XAFS data recorded during the reduction of a NiRe/carbon catalyst at 4 bar are used to illustrate the performance of the reactor.

  4. Identification of lead chemical form in mine waste materials by X-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Taga, Raijeli L.; Ng, Jack [University of Queensland, National Research Centre for Environmental Toxicology (EnTox), Brisbane, 4108 (Australia); Zheng Jiajia; Huynh, Trang; Noller, Barry [University of Queensland, Centre for Mined Land Rehabilitation, Brisbane, 4072 (Australia); Harris, Hugh H. [School of Chemistry and Physics, University of Adelaide, Adelaide, 5005 (Australia)

    2010-06-23T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) provides a direct means for measuring lead chemical forms in complex samples. In this study, XAS was used to identify the presence of plumbojarosite (PbFe{sub 6}(SO{sub 4}){sub 4}(OH){sub 12}) by lead L{sub 3}-edge XANES spectra in mine waste from a small gold mining operation in Fiji. The presence of plumbojarosite in tailings was confirmed by XRD but XANES gave better resolution. The potential for human uptake of Pb from tailings was measured using a physiologically based extract test (PBET), an in-vitro bioaccessibility (BAc) method. The BAc of Pb was 55%. Particle size distribution of tailings indicated that 40% of PM{sub 10} particulates exist which could be a potential risk for respiratory effects via the inhalation route. Food items collected in the proximity of the mine site had lead concentrations which exceed food standard guidelines. Lead within the mining lease exceeded sediment guidelines. The results from this study are used to investigate exposure pathways via ingestion and inhalation for potential risk exposure pathways of Pb in that locality. The highest Pb concentration in soil and tailings was 25,839 mg/kg, exceeding the Australian National Environment Protection Measure (NEPM) soil health investigation levels.

  5. Speciation of selenium in stream insects using X-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Ruwandi Andrahennadi; Mark Wayland; Ingrid J. Pickering [University of Saskatchewan, Saskatoon, SK (Canada). Department of Geological Sciences

    2007-11-15T23:59:59.000Z

    Selenium contamination in the environment is a widespread problem affecting insects and other wildlife. Insects occupy a critical middle link and aid in trophic transfer of selenium in many terrestrial and freshwater food chains, but the mechanisms of selenium uptake through the food chain are poorly understood. In particular, biotransformation of selenium by insects into different chemical forms will greatly influence how toxic or benign the selenium is to that organism or to its predators. We have used X-ray absorption spectroscopy (XAS) to identify the chemical form of selenium in insects inhabiting selenium contaminated streams near Hinton, Alberta (Canada). Selenium K near-edge spectra indicate a variability of selenium speciation among the insects that included mayflies (Ephemeroptera), stoneflies (Plecoptera), caddisflies (Trichoptera), and craneflies (Diptera). Higher percentages of inorganic selenium were observed in primary consumers, detritivores, and filter feeders than in predatory insects. Among the organic forms of selenium, organic selenides constituted a major fraction in most organisms. A species modeled as trimethylselenonium was observed during the pupal stage of caddisflies. These results provide insights into how the insects cope with their toxic cargo, including how the selenium is biotransformed into less toxic forms and how it can be eliminated from the insects. More broadly, this study demonstrates the strengths of XAS to probe the effects of heavy elements at trace levels in insects from the field.

  6. X-ray absorption spectroscopy by full-field X-ray microscopy of a thin graphite flake: Imaging and

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    .bittencourt@ua.ac.be * Corresponding author Keywords: carbon; graphene; nanostructure; NEXAFS; X-ray microscopy Beilstein J structure of graphite flakes consisting of a few graphene layers. The flake was produced by exfoli- ation of the remarkable transport properties of graphene in 2004 by Geim and Novoselov triggered intense interest in its

  7. X-ray Absorption Spectroscopy of the Multi-phase Interstellar Medium: Oxygen and Neon Abundances

    E-Print Network [OSTI]

    Yangsen Yao; Q. Daniel Wang

    2005-12-19T23:59:59.000Z

    X-ray absorption spectroscopy provides a potentially powerful tool in determining the metal abundances in various phases of the interstellar medium (ISM). We present a case study of the sight line toward 4U 1820-303 (Galactic coordinates l, b=2.79, -7.91 and distance = 7.6 kpc), based on Chandra Grating observations. The detection of OI, OII, OIII, OVII, OVIII, and NeIX Kalpha absorption lines allows us to measure the atomic column densities of the neutral, warm ionized, and hot phases of the ISM through much of the Galactic disk. By comparing these measurements with the 21 cm hydrogen emission and with the pulsar dispersion measure along the same sight line, we estimate the mean oxygen abundances in the neutral and total ionized phases as 0.3(0.2, 0.6) and 2.2(1.1, 3.5) in units of Anders & Grevesse (1989) solar value. This significant oxygen abundance difference is apparently a result of molecule/dust grain destruction and recent metal enrichment in the warm ionized and hot phases. We also measure the column density of neon from its absorption edge and obtain the Ne/O ratio of the neutral plus warm ionized gas as 2.1(1.3, 3.5) solar. Accounting for the expected oxygen contained in molecules and dust grains would reduce the Ne/O ratio by a factor of ~1.5. From a joint-analysis of the OVII, OVIII, and NeIX lines, we obtain the Ne/O abundance ratio of the hot phase as 1.4(0.9, 2.1) solar, which is not sensitive to the exact temperature distribution assumed in the absorption line modeling. These comparable ISM Ne/O ratios for the hot and cooler gas are thus considerably less than the value (2.85+-0.07; 1sigma) recently inferred from corona emission of solar-like stars (Drake & Testa 2005). (abridged)

  8. How Can X-ray Transient Absorption Spectroscopy Aide Solar Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are from optimized on structural, energetic and dynamic parameters. Intense X-ray pulses from synchrotrons and X-ray free electrons lasers coupled with ultrafast lasers...

  9. Towards simultaneous measurements of electronic and structural properties in ultra-fast x-ray free electron laser absorption spectroscopy experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaudin, J.; Fourment, C.; Cho, B. I.; Engelhorn, K.; Galtier, E.; Harmand, M.; Leguay, P. M.; Lee, H. J.; Nagler, B.; Nakatsutsumi, M.; et al

    2014-04-17T23:59:59.000Z

    The rapidly growing ultrafast science with X-ray lasers unveils atomic scale processes with unprecedented time resolution bringing the so called “molecular movie” within reach. X-ray absorption spectroscopy is one of the most powerful x-ray techniques providing both local atomic order and electronic structure when coupled with ad-hoc theory. Collecting absorption spectra within few x-ray pulses is possible only in a dispersive setup. We demonstrate ultrafast time-resolved measurements of the LIII-edge x-ray absorption near-edge spectra of irreversibly laser excited Molybdenum using an average of only few x-ray pulses with a signal to noise ratio limited only by the saturation level ofmore »the detector. The simplicity of the experimental set-up makes this technique versatile and applicable for a wide range of pump-probe experiments, particularly in the case of non-reversible processes.« less

  10. Auto-oligomerization and hydration of pyrrole revealed by x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Advanced Light Source; Schwartz, Craig P.; Uejio, Janel S.; Duffin, Andrew M.; England, Alice H.; Prendergast, David; Saykally, Richard J

    2009-05-29T23:59:59.000Z

    Near edge x-ray absorption fine structure (NEXAFS) spectra have been measured at the carbon and nitrogen K-edges of the prototypical aromatic molecule, pyrrole, both in the gas phase and when solvated in water, and compared with spectra simulated using a combination of classical molecular dynamics and first principles density functional theory in the excited state core hole approximation. The excellent agreement enabled detailed assignments. Pyrrole is highly reactive, particularly in water, and reaction products formed by the auto-oligomerization of pyrrole are identified. The solvated spectra have been measured at two different temperatures, indicating that the final states remain largely unaffected by both hydration and temperature. This is somewhat unexpected, since the nitrogen in pyrrole can donate a hydrogen bond to water.

  11. Ligand-field symmetry effects in Fe(II) polypyridyl compounds probed by transient X-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Cho, Hana; Strader, Matthew L.; Hong, Kiryong; Jamula, Lindsey; Kim, Tae Kyu; Groot, Frank M. F. de; McCusker, James K.; Schoenlein, Robert W.; Huse, Nils

    2012-02-28T23:59:59.000Z

    Ultrafast excited-state evolution in polypyridyl FeII complexes are of fundamental interest for understanding the origins of the sub-ps spin-state changes that occur upon photoexcitation of this class of compounds as well as for the potential impact such ultrafast dynamics have on incorporation of these compounds in solar energy conversion schemes or switchable optical storage technologies. We have demonstrated that ground-state and, more importantly, ultrafast time-resolved x-ray absorption methods can offer unique insights into the interplay between electronic and geometric structure that underpin the photo-induced dynamics of this class of compounds. The present contribution examines in greater detail how the symmetry of the ligand field surrounding the metal ion can be probed using these x-ray techniques. In particular, we show that steady-state K-edge spectroscopy of the nearest-neighbour nitrogen atoms reveals the characteristic chemical environment of the respective ligands and suggests an interesting target for future charge-transfer femtosecond and attosecond spectroscopy in the x-ray water window.

  12. Quantification of rapid environmental redox processes with quick-scanning x-ray absorption

    E-Print Network [OSTI]

    Sparks, Donald L.

    Quantification of rapid environmental redox processes with quick-scanning x-ray absorption. Here we apply quick-scanning x-ray absorption spectroscopy (Q-XAS), at sub-second time that can be measured using x-ray absorption spectroscopy. arsenic extended x-ray absorption fine structure

  13. Atomic resolution mapping of the excited-state electronic structure of Cu2O with time-resolved x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Hillyard, P. W.; Kuchibhatla, S. V. N. T.; Glover, T. E.; Hertlein, M. P.; Huse, Nils; Nachimuthu, P.; Saraf, L. V.; Thevuthasan, S.; Gaffney, K. J.

    2010-05-02T23:59:59.000Z

    We have used time-resolved soft x-ray spectroscopy to investigate the electronic structure of optically excited cuprous oxide at the O K-edge and the Cu L3-edge. The 400 nm optical excitation shifts the Cu and O absorptions to lower energy, but does not change the integrated x-ray absorption significantly for either edge. The constant integrated x-ray absorption cross-section indicates that the conduction-band and valence-band edges have very similar Cu 3d and O 2p orbital contributions. The 2.1 eV optical band gap of Cu2O significantly exceeds the one eV shift in the Cu L3- and O K-edges absorption edges induced by optical excitation, demonstrating the importance of core-hole excitonic effects and valence electron screening in the x-ray absorption process.

  14. High Resolution Spectroscopy of X-ray Quasars: Searching for the X-ray Absorption from the Warm-Hot Intergalactic Medium

    E-Print Network [OSTI]

    Fang, Taotao

    We present a survey of six low- to moderate-redshift quasars with Chandra and XMM-Newton. The primary goal is to search for the narrow X-ray absorption lines produced by highly ionized metals in the warm-hot intergalactic ...

  15. X-ray absorption spectroscopy at the Ni-K edge in Stackhousia tryonii Bailey hyperaccumulator

    E-Print Network [OSTI]

    Kachenko, A.

    2009-01-01T23:59:59.000Z

    Micro x-ray ?uorescence ( -XRF) mapping was performed using15 RESULTS AND DISCUSSION -XRF imaging was used to determinelocalisation in planta. Typical -XRF maps obtained of stem,

  16. Iron near absorption edge X-ray spectroscopy at aqueous-membrane interfaces

    SciTech Connect (OSTI)

    Wang, Wenjie; Kuzmenko, Ivan; Vaknin, David

    2014-01-01T23:59:59.000Z

    Employing synchrotron X-ray scattering, we systematically determine the absorption near-edge spectra (XANES) of iron in its ferrous (Fe2+) and ferric (Fe3+) states both as ions in aqueous solutions and as they bind to form a single layer to anionic templates that consist of carboxyl or phosphate groups at aqueous/vapor interfaces. While the XANES of bulk iron ions show that the electronic state and coordination of iron complexes in the bulk are isotropic, the interfacial bound ions show a signature of a broken inversion-symmetry environment. The XANES of Fe2+ and Fe3+ in the bulk possess distinct profiles however, upon binding they practically exhibit similar patterns. This indicates that both bound ions settle into a stable electronic and coordination configuration with an effective fractional valence (for example, Fe[2+nu]+, 0 < nu < 1) at charged organic templates. Such two dimensional properties may render interfacial iron, abundant in living organisms, a more efficient and versatile catalytic behavior.

  17. Coupling MD Simulations and X-ray Absorption Spectroscopy to Study Ions in Solution

    SciTech Connect (OSTI)

    Marcos, E. Sanchez; Beret, E. C.; Martinez, J. M.; Pappalardo, R. R. [University of Seville, Dept. of Physical Chemistry (Spain); Ayala, R.; Munoz-Paez, A. [University of Seville, CSIC-ICMSE. Dept. of Inorganic Chemistry (Spain)

    2007-11-29T23:59:59.000Z

    The structure of ionic solutions is a key-point in understanding physicochemical properties of electrolyte solutions. Among the reduced number of experimental techniques which can supply direct information on the ion environment, X-ray Absorption techniques (XAS) have gained importance during the last decades although they are not free of difficulties associated to the data analysis leading to provide reliable structures. Computer simulations of ions in solution is a theoretical alternative to provide information on the solvation structure. Thus, the use of computational chemistry can increase the understanding of these systems although an accurate description of ionic solvation phenomena represents nowadays a significant challenge to theoretical chemistry. We present: (a) the assignment of features in the XANES spectrum to well defined structural motif in the ion environment, (b) MD-based evaluation of EXAFS parameters used in the fitting procedure to make easier the structural resolution, and (c) the use of the agreement between experimental and simulated XANES spectra to help in the choice of a given intermolecular potential for Computer Simulations. Chemical problems examined are: (a) the identification of the second hydration shell in dilute aqueous solutions of highly-charged cations, such as Cr{sup 3+}, Rh{sup 3+}, Ir{sup 3+}, (b) the invisibility by XAS of certain structures characterized by Computer Simulations but exhibiting high dynamical behavior and (c) the solvation of Br{sup -} in acetonitrile.

  18. Local versus global electronic properties of chalcopyrite alloys: X-ray absorption spectroscopy and ab initio calculations

    SciTech Connect (OSTI)

    Sarmiento-Pérez, Rafael; Botti, Silvana, E-mail: silvana.botti@univ-lyon1.fr [Institut Lumière Matière and ETSF, UMR5306 Université Lyon 1-CNRS, Université de Lyon, F-69622 Villeurbanne Cedex (France); Schnohr, Claudia S., E-mail: c.schnohr@uni-jena.de [Institut für Festkörperphysik, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Lauermann, Iver [Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner Platz 1, 14109 Berlin (Germany); Rubio, Angel [Nano-Bio Spectroscopy Group and ETSF Scientific Development Centre, Departamento de Física de Materiales, Centro de Física de Materiales CSIC-MPC and DIPC, Universidad del País Vasco UPV/EHU, Avenida de Tolosa 72, E-20018 San Sebastián (Spain); Fritz Haber Institute, Max Planck Society, Faradayweg 4-6, 14195 Berlin (Germany); Johnson, Benjamin, E-mail: benjamin.johnson@alumni.tu-berlin.de [Fritz Haber Institute, Max Planck Society, Faradayweg 4-6, 14195 Berlin (Germany)

    2014-09-07T23:59:59.000Z

    Element-specific unoccupied electronic states of Cu(In, Ga)S{sub 2} were studied as a function of the In/Ga ratio by combining X-ray absorption spectroscopy with density functional theory calculations. The S absorption edge shifts with changing In/Ga ratio as expected from the variation of the band gap. In contrast, the cation edge positions are largely independent of composition despite the changing band gap. This unexpected behavior is well reproduced by our calculations and originates from the dependence of the electronic states on the local atomic environment. The changing band gap arises from a changing spatial average of these localized states with changing alloy composition.

  19. In operando observation system for electrochemical reaction by soft X-ray absorption spectroscopy with potential modulation method

    SciTech Connect (OSTI)

    Nagasaka, Masanari, E-mail: nagasaka@ims.ac.jp; Kosugi, Nobuhiro [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan); The Graduate University for Advanced Studies, Myodaiji, Okazaki 444-8585 (Japan); Yuzawa, Hayato; Horigome, Toshio [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan)

    2014-10-15T23:59:59.000Z

    In order to investigate local structures of electrolytes in electrochemical reactions under the same scan rate as a typical value 100 mV/s in cyclic voltammetry (CV), we have developed an in operando observation system for electrochemical reactions by soft X-ray absorption spectroscopy (XAS) with a potential modulation method. XAS spectra of electrolytes are measured by using a transmission-type liquid flow cell with built-in electrodes. The electrode potential is swept with a scan rate of 100 mV/s at a fixed photon energy, and soft X-ray absorption coefficients at different potentials are measured at the same time. By repeating the potential modulation at each fixed photon energy, it is possible to measure XAS of electrochemical reaction at the same scan rate as in CV. We have demonstrated successful measurement of the Fe L-edge XAS spectra of aqueous iron sulfate solutions and of the change in valence of Fe ions at different potentials in the Fe redox reaction. The mechanism of these Fe redox processes is discussed by correlating the XAS results with those at different scan rates.

  20. Speciation of Lead in a Mixed Soil Component System Using X-ray Absorption Fine Structure Spectroscopy

    E-Print Network [OSTI]

    Sparks, Donald L.

    Speciation of Lead in a Mixed Soil Component System Using X-ray Absorption Fine Structure (XAFS). Lead concentrations of 6000, 18000, and 29000 µg Pb/g solid were reacted with soil components

  1. Influence of the cobalt particle size in the CO hydrogenation reaction studied by in situ X-ray absorption spectroscopy

    E-Print Network [OSTI]

    Herranz, Tirma

    2010-01-01T23:59:59.000Z

    Cobalt, nanoparticles, Fischer-Tropsch, X-ray absorption (oxides [5] and Fischer-Tropsch (FT) synthesis [6,7]. Itswhich is inactive for Fischer-Tropsch synthesis. This oxide

  2. Theoretical standards in x-ray spectroscopies

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    We propose to extend our state-of-the-art, ab initio XAFS (X-ray absorption fine structure) codes, FEFF. Our current work has been highly successful in achieving accurate, user-friendly XAFS standards, exceeding the performance of both tabulated standards and other codes by a considerable margin. We now propose to add the capability to treat more complex materials. This includes multiple-scattering, polarization dependence, an approximate treatment of XANES (x-ray absorption near edge structure), and other improvements. We also plan to adapt FEFF to other spectroscopies, e.g. photoelectron diffraction (PD) and diffraction anomalous fine structure (DAFS).

  3. Sulfur K-edge X-ray absorption spectroscopy as an experimental probe for S-nitroso proteins

    SciTech Connect (OSTI)

    Szilagyi, Robert K. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)]. E-mail: Szilagyi@Montana.EDU; Schwab, David E. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)

    2005-04-29T23:59:59.000Z

    X-ray absorption spectroscopy at the sulfur K-edge (2.4-2.6 keV) provides a sensitive and specific technique to identify S-nitroso compounds, which have significance in nitric oxide-based cell signaling. Unique spectral features clearly distinguish the S-nitroso-form of a cysteine residue from the sulfhydryl-form or from a methionine thioether. Comparison of the sulfur K-edge spectra of thiolate, thiol, thioether, and S-nitroso thiolate compounds indicates high sensitivity of energy positions and intensities of XAS pre-edge features as determined by the electronic environment of the sulfur absorber. A new experimental setup is being developed for reaching the in vivo concentration range of S-nitroso thiol levels in biological samples.

  4. In-situ X-ray absorption spectroscopy analysis of capacity fade in nanoscale-LiCoO{sub 2}

    SciTech Connect (OSTI)

    Patridge, Christopher J. [NRC/NRL Cooperative Research Associate, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Love, Corey T., E-mail: corey.love@nrl.navy.mil [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Swider-Lyons, Karen E. [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Twigg, Mark E. [Electronics Science and Technology Division, Code 6812, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Ramaker, David E. [Chemistry Division, Code 6189, U.S. Naval Research laboratory, Washington, DC 20375 (United States)

    2013-07-15T23:59:59.000Z

    The local structure of nanoscale (?10–40 nm) LiCoO{sub 2} is monitored during electrochemical cycling utilizing in-situ X-ray absorption spectroscopy (XAS). The high surface area of the LiCoO{sub 2} nanoparticles not only enhances capacity fade, but also provides a large signal from the particle surface relative to the bulk. Changes in the nanoscale LiCoO{sub 2} metal-oxide bond lengths, structural disorder, and chemical state are tracked during cycling by adapting the delta mu (??) technique in complement with comprehensive extended X-ray absorption fine structure (EXAFS) modeling. For the first time, we use a ?? EXAFS method, and by comparison of the difference EXAFS spectra, extrapolate significant coordination changes and reduction of cobalt species with cycling. This combined approach suggests Li–Co site exchange at the surface of the nanoscale LiCoO{sub 2} as a likely factor in the capacity fade and irreversible losses in practical, microscale LiCoO{sub 2}. - Graphical abstract: Electrochemical cycling of Li-ion batteries has strong impact on the structure and integrity of the cathode active material particularly near the surface/electrolyte interface. In developing a new method, we have used in-situ X-ray absorption spectroscopy during electrochemical cycling of nanoscale LiCoO{sub 2} to track changes during charge and discharge and between subsequent cycles. Using difference spectra, several small changes in Co-O bond length, Co-O and Co-Co coordination, and site exchange between Co and Li sites can be tracked. These methods show promise as a new technique to better understand processes which lead to capacity fade and loss in Li-ion batteries. - Highlights: • A new method is developed to understand capacity fade in Li-ion battery cathodes. • Structural changes are tracked during Li intercalation/deintercalation of LiCoO{sub 2}. • Surface structural changes are emphasized using nanoscale-LiCoO{sub 2} and difference spectra. • Full multiple scattering calculations are used to support ?? analysis.

  5. X-ray absorption spectroscopy elucidates the impact of structural disorder on electron mobility in amorphous zinc-tin-oxide thin films

    SciTech Connect (OSTI)

    Siah, Sin Cheng, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu; Lee, Yun Seog; Buonassisi, Tonio, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Lee, Sang Woon; Gordon, Roy G. [Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138 (United States); Heo, Jaeyeong [Department of Materials Science and Engineering, Chonnam National University, Gwangju 500-757 (Korea, Republic of); Shibata, Tomohiro; Segre, Carlo U. [Physics Department and CSRRI, Illinois Institute of Technology, Chicago, Illinois 606016 (United States)

    2014-06-16T23:59:59.000Z

    We investigate the correlation between the atomic structures of amorphous zinc-tin-oxide (a-ZTO) thin films grown by atomic layer deposition (ALD) and their electronic transport properties. We perform synchrotron-based X-ray absorption spectroscopy at the K-edges of Zn and Sn with varying [Zn]/[Sn] compositions in a-ZTO thin films. In extended X-ray absorption fine structure (EXAFS) measurements, signal attenuation from higher-order shells confirms the amorphous structure of a-ZTO thin films. Both quantitative EXAFS modeling and X-ray absorption near edge spectroscopy (XANES) reveal that structural disorder around Zn atoms increases with increasing [Sn]. Field- and Hall-effect mobilities are observed to decrease with increasing structural disorder around Zn atoms, suggesting that the degradation in electron mobility may be correlated with structural changes.

  6. Soft X-Ray and Vacuum Ultraviolet Based Spectroscopy of the Actinides

    SciTech Connect (OSTI)

    Tobin, J G

    2011-03-17T23:59:59.000Z

    The subjects of discussion included: VUV photoelectron spectroscopy, X-ray photoelectron spectroscopy, Synchrotron-radiation-based photoelectron spectroscopy, Soft x-ray absorption spectroscopy, Soft x-ray emission spectroscopy, Inverse photoelectron spectroscopy, Bremstrahlung Isochromat Spectroscopy, Low energy IPES, Resonant inverse photoelectron spectroscopy.

  7. Near-edge X-ray absorption fine-structure spectroscopy of naphthalene diimide-thiophene co-polymers

    SciTech Connect (OSTI)

    Gann, Eliot; McNeill, Christopher R., E-mail: christopher.mcneill@monash.edu [Department of Materials Engineering, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Szumilo, Monika; Sirringhaus, Henning [Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE (United Kingdom)] [Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Sommer, Michael [Institute of Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. 31, 79104 Freiburg (Germany)] [Institute of Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. 31, 79104 Freiburg (Germany); Maniam, Subashani; Langford, Steven J. [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia)] [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Thomsen, Lars [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)] [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2014-04-28T23:59:59.000Z

    Near-edge X-ray absorption fine-structure (NEXAFS) spectroscopy is an important tool for probing the structure of conjugated polymer films used in organic electronic devices. High-performance conjugated polymers are often donor-acceptor co-polymers which feature a repeat unit with multiple functional groups. To facilitate better application of NEXAFS spectroscopy to the study of such materials, improved understanding of the observed NEXAFS spectral features is required. In order to examine how the NEXAFS spectrum of a donor-acceptor co-polymer relates to the properties of the sub-units, a series of naphthalene diimide-thiophene-based co-polymers have been studied where the nature and length of the donor co-monomer has been systematically varied. The spectra of these materials are compared with that of a thiophene homopolymer and naphthalene diimide monomer enabling peak assignment and the influence of inter-unit electronic coupling to be assessed. We find that while it is possible to attribute peaks within the ?* manifold as arising primarily due to the naphthalene diimide or thiophene sub-units, very similar dichroism of these peaks is observed indicating that it may not be possible to separately probe the molecular orientation of the separate sub-units with carbon K-edge NEXAFS spectroscopy.

  8. Near-infrared photoluminescence and ligand K-edge x-ray absorption spectroscopies of AnO2Cl42-(An:u, NP, Pu)

    SciTech Connect (OSTI)

    Wilkerson, Marianne P [Los Alamos National Laboratory; Berg, John M [Los Alamos National Laboratory; Clark, David L [Los Alamos National Laboratory; Conradson, Steven D [Los Alamos National Laboratory; Hobart, David E [Los Alamos National Laboratory; Kozimor, Stosh A [Los Alamos National Laboratory; Scott, Brian L [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    We have used photoluminescence and X-ray absorption spectroscopies to investigate electronic structures and metal-ligand bonding of a series of An02CI/ ' (An = U, Np, Pu) compounds. Specifically, we will discuss time-resolved near-infrared emission spectra of crystalline Cs2U(An)02C14 (An = Np and Pu) both at 23 K and 75 K, as well as chlorine Kedge X-ray absorption spectra ofCs2An02CI4 (An = U, Np).

  9. Start | View At a Glance | Author Index 220-1 Kinetics of Rapid Redox Processes at the Mineral/Water Interface Using Quick-Scanning X-Ray Absorption Spectroscopy

    E-Print Network [OSTI]

    Sparks, Donald L.

    at the Mineral/Water Interface Using Quick-Scanning X-Ray Absorption Spectroscopy (Q-XAS). See more from-situ synchrotron-based technique, quick scanning X-ray absorption spectroscopy (Q-XAS), at sub-second time scales

  10. Distinct local structure of nanoparticles and nanowires of V{sub 2}O{sub 5} probed by x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Joseph, B.; Maugeri, L.; Bendele, M.; Saini, N. L., E-mail: Naurang.Saini@roma1.infn.it [Dipartimento di Fisica, Universitá di Roma “La Sapienza” - P. le Aldo Moro 2, 00185 Roma (Italy); Iadecola, A. [Dipartimento di Fisica, Universitá di Roma “La Sapienza” - P. le Aldo Moro 2, 00185 Roma (Italy) [Dipartimento di Fisica, Universitá di Roma “La Sapienza” - P. le Aldo Moro 2, 00185 Roma (Italy); Elettra, Sincrotrone Trieste, Strada Statale 14, Km 163.5, Basovizza, Trieste (Italy); Okubo, M.; Li, H.; Zhou, H. [National Institute of Advanced Industrial Science and Technology (AIST), Umezono 1-1-1, Tsukuba 305-8568 (Japan)] [National Institute of Advanced Industrial Science and Technology (AIST), Umezono 1-1-1, Tsukuba 305-8568 (Japan); Mizokawa, T. [Department of Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan) [Department of Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan); Department of Complexity Science and Engineering, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan)

    2013-12-16T23:59:59.000Z

    We have used V K-edge x-ray absorption spectroscopy to study local structures of bulk, nanoparticles and nanowires of V{sub 2}O{sub 5}. The extended x-ray absorption fine structure measurements show different local displacements in the three morphologically different V{sub 2}O{sub 5} samples. It is found that the nanowires have a significantly ordered chain structure in comparison to the V{sub 2}O{sub 5} bulk. In contrast, nanoparticles have larger interlayer disorder. The x-ray absorption near-edge structure spectra show different electronic structure that appears to be related with the local atomic disorder in the three V{sub 2}O{sub 5} samples.

  11. X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films

    SciTech Connect (OSTI)

    Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

    1999-02-01T23:59:59.000Z

    The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

  12. Time-resolved x-ray absorption spectroscopy of photoinduced insulator-metal transition in a colossal magnetoresistive manganite

    SciTech Connect (OSTI)

    Rini, M.; Tobey, R.; Wall, S.; Zhu, Y.; Tomioka, Y.; Tokura, Y.; Cavalleri, A.; Schoenlein, R.W.

    2008-08-01T23:59:59.000Z

    We studied the ultrafast insulator-metal transition in a manganite by means of picosecond X-ray absorption at the O K- and Mn L-edges, probing photoinduced changes in O-2p and Mn-3d electronic states near the Fermi level.

  13. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    SciTech Connect (OSTI)

    Tokunaga, Tetsu; Tokunaga, T.K.; Wan, J.; Kim, Y.; Sutton, S.R.; Newville, M.; Lanzirotti, A.; Rao, W.

    2008-01-15T23:59:59.000Z

    The oxidation status of uranium in sediments is important because the solubility of this toxic and radioactive element is much greater for U(VI) than for U(IV) species. Thus, redox manipulation to promote precipitation of UO{sub 2} is receiving interest as a method to remediate U-contaminated sediments. Presence of Fe and Mn oxides in sediments at much higher concentrations than U requires understanding of their redox status as well. This study was conducted to determine changes in oxidation states of U, Fe, and Mn in U-contaminated sediments from Oak Ridge National Laboratory. Oxidation states of these elements were measured in real-time and nondestructively using X-ray absorption spectroscopy, on sediment columns supplied with synthetic groundwater containing organic carbon (OC, 0, 3, 10, 30 and 100 mM OC as lactate) for over 400 days. In sediments supplied with OC {ge} 30 mM, 80% of the U was reduced to U(IV), with transient reoxidation at about 150 days. Mn(III,IV) oxides were completely reduced to Mn(II) in sediments infused with OC {ge} 3 mM. However, Fe remained largely unreduced in all sediment columns, showing that Fe(III) can persist as an electron acceptor in reducing sediments over long times. This result in combination with the complete reduction of all other potential electron acceptors supports the hypothesis that the reactive Fe(III) fraction was responsible for reoxidizing U(IV).

  14. An x-ray absorption near-edge spectroscopy study of the oxidation state of chromium in electrodeposited oxide films.

    SciTech Connect (OSTI)

    Balasubramanian, M.; Melendres, C. A.; Chemical Engineering

    1999-01-01T23:59:59.000Z

    The oxidation state of chromium incorporated into simulated corrosion films of nickel has been investigated using the technique of 'in situ' X-ray Absorption Near-Edge Spectroscopy (XANES). The films were prepared by electrochemical deposition of the appropriate oxide (hydroxide) onto a graphite substrate. Cathodic deposition from a 0.01 M Cr(NO{sub 3}){sub 3} solution at constant current results in a Cr{sup 3+} oxide (hydroxide) film. Deposition from a 0.01 M K{sub 2}CrO{sub 4} solution produces a film which is predominantly Cr{sup 3+} but with some Cr{sup 6+}. This material is air-sensitive and the ratio of Cr{sup 6+} to Cr{sup 3+} increases with time of exposure to ambient. Cathodic codeposition of Cr{sup 3+} with nickel hydroxide from Cr(NO{sub 3}){sub 3} solution results in a film with chromium in the 3+ oxidation state. On the other hand, cathodic codeposition from a Cr{sup 6+} solution of K{sub 2}CrO{sub 4} with nickel hydroxide leads to a film containing Cr{sup 6+}.

  15. Development of Palladium L-Edge X-Ray Absorption Spectroscopy And Its Application for Chloropalladium Complexes

    SciTech Connect (OSTI)

    Boysen, R.B.; Szilagyi, R.K.

    2009-05-12T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) is a synchrotron-based experimental technique that provides information about geometric and electronic structures of transition metal complexes. Combination of metal L-edge and ligand K-edge XAS has the potential to define the complete experimental ground state electronic structures for metal complexes with unoccupied d manifolds. We developed a quantitative treatment for Pd L-edge spectroscopy on the basis of the well-established chlorine K-edge XAS for a series of chloropalladium complexes that are pre-catalysts in various organic transformations. We found that Pd-Cl bonds are highly covalent, such as 24 {+-} 2%, 34 {+-} 3%, and 48 {+-} 4% chloride 3p character for each Pd-Cl bond in [PdCl{sub 4}]{sup 2-}, [PdCl{sub 6}]{sup 2-}, and PdCl{sub 2}, respectively. Pd(2p {yields} 4d) transition dipole integrals of 20.8 (SSRL)/16.9 (ALS) eV and 14.1 (SSRL)/11.9 (ALS) eV were determined using various combinations of L-edges for Pd(II) and Pd(IV), respectively. Application of metal-ligand covalency and transition dipole integrals were demonstrated for the example of bridging chloride ligands in PdCl{sub 2}. Our work lays the foundation for extending the quantitative treatment to other catalytically important ligands, such as phosphine, phosphite, olefin, amine, and alkyl in order to correlate the electronic structures of palladium complexes with their catalytic activity.

  16. Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications

    E-Print Network [OSTI]

    Sparks, Donald L.

    Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized of quick extended x-ray absorption fine structure QEXAFS and quick x-ray absorption near edge structure- tion spectroscopy XAS was developed in energy dispersive and quick extended x-ray absorption fine

  17. Conduction-band electronic states of YbInCu{sub 4} studied by photoemission and soft x-ray absorption spectroscopies

    SciTech Connect (OSTI)

    Utsumi, Yuki; Kurihara, Hidenao; Maso, Hiroyuki; Tobimatsu, Komei [Graduate School of Science, Hiroshima University, Higashi-Hiroshima 739-8526 (Japan); Sato, Hitoshi; Shimada, Kenya; Namatame, Hirofumi [Hiroshima Synchrotron Radiation Center, Hiroshima University, Higashi-Hiroshima 739-0046 (Japan); Hiraoka, Koichi [Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577 (Japan); Kojima, Kenichi [Graduate School of Integrated Arts and Sciences, Hiroshima University, Higashi-Hiroshima 739-8521 (Japan); Ohkochi, Takuo; Fujimori, Shin-ichi; Takeda, Yukiharu; Saitoh, Yuji [Synchrotron Radiation Research Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Mimura, Kojiro [Graduate School of Engineering, Osaka Prefecture University, Sakai 599-8531 (Japan); Ueda, Shigenori; Yamashita, Yoshiyuki; Yoshikawa, Hideki; Kobayashi, Keisuke [NIMS Beamline Station at SPring-8, National Institute for Materials Science, Hyogo 679-5148 (Japan); Oguchi, Tamio [ISIR, Osaka University, Ibaraki 567-0047 (Japan); Taniguchi, Masaki [Graduate School of Science, Hiroshima University, Higashi-Hiroshima 739-8526 (Japan); Hiroshima Synchrotron Radiation Center, Hiroshima University, Higashi-Hiroshima 739-0046 (Japan)

    2011-09-15T23:59:59.000Z

    We have studied conduction-band (CB) electronic states of a typical valence-transition compound YbInCu{sub 4} by means of temperature-dependent hard x-ray photoemission spectroscopy (HX-PES) of the Cu 2p{sub 3/2} and In 3d{sub 5/2} core states taken at h{nu}=5.95 keV, soft x-ray absorption spectroscopy (XAS) of the Cu 2p{sub 3/2} core absorption region around h{nu}{approx}935 eV, and soft x-ray photoemission spectroscopy (SX-PES) of the valence band at the Cu 2p{sub 3/2} absorption edge of h{nu}=933.0 eV. With decreasing temperature below the valence transition at T{sub V}=42 K, we have found that (1) the Cu 2p{sub 3/2} and In 3d{sub 5/2} peaks in the HX-PES spectra exhibit the energy shift toward the lower binding-energy side by {approx}40 and {approx}30 meV, respectively, (2) an energy position of the Cu 2p{sub 3/2} main absorption peak in the XAS spectrum is shifted toward higher photon-energy side by {approx}100 meV, with an appearance of a shoulder structure below the Cu 2p{sub 3/2} main absorption peak, and (3) an intensity of the Cu L{sub 3}VV Auger spectrum is abruptly enhanced. These experimental results suggest that the Fermi level of the CB-derived density of states is shifted toward the lower binding-energy side. We have described the valence transition in YbInCu{sub 4} in terms of the charge transfer from the CB to Yb 4f states.

  18. Ultrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations

    E-Print Network [OSTI]

    Cao, Jianshu

    13­20 to generate ultrafast x-ray pulses, however, the prospect of ultrafast EXAFS seems encouragingUltrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations Frank L by the recent experimental demonstration of ultrafast x-ray absorption spectroscopy, we present a framework

  19. Soft-x-ray spectroscopy study of nanoscale materials

    SciTech Connect (OSTI)

    Guo, J.-H.

    2005-07-30T23:59:59.000Z

    The ability to control the particle size and morphology of nanoparticles is of crucial importance nowadays both from a fundamental and industrial point of view considering the tremendous amount of high-tech applications. Controlling the crystallographic structure and the arrangement of atoms along the surface of nanostructured material will determine most of its physical properties. In general, electronic structure ultimately determines the properties of matter. Soft X-ray spectroscopy has some basic features that are important to consider. X-ray is originating from an electronic transition between a localized core state and a valence state. As a core state is involved, elemental selectivity is obtained because the core levels of different elements are well separated in energy, meaning that the involvement of the inner level makes this probe localized to one specific atomic site around which the electronic structure is reflected as a partial density-of-states contribution. The participation of valence electrons gives the method chemical state sensitivity and further, the dipole nature of the transitions gives particular symmetry information. The new generation synchrotron radiation sources producing intensive tunable monochromatized soft X-ray beams have opened up new possibilities for soft X-ray spectroscopy. The introduction of selectively excited soft X-ray emission has opened a new field of study by disclosing many new possibilities of soft X-ray resonant inelastic scattering. In this paper, some recent findings regarding soft X-ray absorption and emission studies of various nanostructured systems are presented.

  20. X-ray spectroscopy of low-mass X-ray binaries

    E-Print Network [OSTI]

    Juett, Adrienne Marie, 1976-

    2004-01-01T23:59:59.000Z

    I present high-resolution X-ray grating spectroscopy of neutron stars in low-mass X-ray binaries (LMXBs) using instruments onboard the Chandra X-ray Observatory and the X-ray Multi-Mirror Mission (XMM-Newton). The first ...

  1. Setup for in situ investigation of gases and gas/solid interfaces by soft x-ray emission and absorption spectroscopy

    SciTech Connect (OSTI)

    Benkert, A., E-mail: andreas.benkert@kit.edu, E-mail: l.weinhardt@kit.edu [Institute for Photon Science and Synchrotron Radiation, Karlsruhe Institute of Technology (KIT), Hermann-v.-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Gemeinschaftslabor für Nanoanalytik, Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe (Germany); Blum, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Meyer, F. [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany)] [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Wilks, R. G. [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany)] [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Yang, W. [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)] [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Bär, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Insitut für Physik und Chemie, Brandenburgische Technische Universität Cottbus-Senftenberg, Konrad-Wachsmann-Allee 1, 03046 Cottbus (Germany); and others

    2014-01-15T23:59:59.000Z

    We present a novel gas cell designed to study the electronic structure of gases and gas/solid interfaces using soft x-ray emission and absorption spectroscopies. In this cell, the sample gas is separated from the vacuum of the analysis chamber by a thin window membrane, allowing in situ measurements under atmospheric pressure. The temperature of the gas can be regulated from room temperature up to approximately 600?°C. To avoid beam damage, a constant mass flow can be maintained to continuously refresh the gaseous sample. Furthermore, the gas cell provides space for solid-state samples, allowing to study the gas/solid interface for surface catalytic reactions at elevated temperatures. To demonstrate the capabilities of the cell, we have investigated a TiO{sub 2} sample behind a mixture of N{sub 2} and He gas at atmospheric pressure.

  2. Cation distribution in Ni{sub 1?x}Zn{sub x}Fe{sub 2}O{sub 4} using X-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Yadav, A. K., E-mail: akyadav@barc.gov.in; Jha, S. N.; Bhattacharyya, D.; Sahoo, N. K. [Atomic and Molecular Physics Division, Bhabha Atomic Research Centre, Mumbai - 400094 (India); Jadhav, J.; Biswas, S. [Department of Physics, The LNM Institute of Information Technology, Jaipur-302031 (India)

    2014-04-24T23:59:59.000Z

    Spinel ferrite samples of Ni{sub 1?x}Zn{sub x}Fe{sub 2}O{sub 4} (for x=0.2, 0.4, 0.5, 0.6 and 0.8) nanoparticles prepared by a novel chemical synthesis method have been characterized by X-ray Absorption Spectroscopy (XAS) technique to investigate the distribution of cations in the unit cell. XANES region clearly shows that as Ni concentration increases, the pre-edge feature, which is a characteristic of tetrahedral coordination of Fe, is enhanced. A quantitative determination of the relative occupancy of iron cation in the octahedral and tetrahedral sites of the spinel structure was obtained from EXAFS data analysis. It has been found that as atomic fraction of Ni is increased from 0.2 to 0.8, Fe occupancy at tetrahedral to octahedral sites is increased from 13:87 and to 39:61.

  3. HIGH-RESOLUTION X-RAY SPECTROSCOPY OF THE MULTIPHASE INTERSTELLAR MEDIUM TOWARD Cyg X-2

    E-Print Network [OSTI]

    Schulz, Norbert S.

    High-resolution X-ray absorption spectroscopy is a powerful diagnostic tool for probing chemical and physical properties of the interstellar medium (ISM) at various phases. We present detections of K transition absorption ...

  4. Sum rules for polarization-dependent x-ray absorption

    SciTech Connect (OSTI)

    Ankudinov, A.; Rehr, J.J. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1995-01-01T23:59:59.000Z

    A complete set of sum rules is obtained for polarization-dependent x-ray-absorption fine structure and x-ray circular magnetic dichroism (CMD), analogous to those for CMD derived by Thole [ital et] [ital al]. These sum rules relate x-ray-absorption coefficients to the ground-state expectation values of various operators. Problems with applying these sum rules are discussed.

  5. Radial distribution function in x-ray-absorption fine structure

    SciTech Connect (OSTI)

    Stern, E.A.; Ma, Y.; Hanske-Petitpierre, O. (Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States)); Bouldin, C.E. (National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States))

    1992-07-01T23:59:59.000Z

    It has been argued that, in systems that have disorder too large to be described by a Gaussian, x-ray-absorption fine-structure (XAFS) spectroscopy alone cannot define the radial distribution function (RDF) because of the lack of low-{ital k} data. We show that the low-{ital k} data can, under certain conditions, be reconstructed using cumulant expansions, which give the correct functional form. This allows XAFS to determine unbiased single-shell RDF's in cases of moderate disorder, without assuming a particular model for the RDF. Some examples are given to illustrate the technique and its limitations.

  6. Performance and characteristics of a high pressure, high temperature capillary cell with facile construction for operando x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Bansode, Atul; Urakawa, Atsushi, E-mail: aurakawa@iciq.es [Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona (Spain); Guilera, Gemma; Simonelli, Laura; Avila, Marta [ALBA Synchrotron Light Source, Crta. BP 1413, Km. 3.3, 08290 Cerdanyola del Vallès, Barcelona (Spain); Cuartero, Vera [ALBA Synchrotron Light Source, Crta. BP 1413, Km. 3.3, 08290 Cerdanyola del Vallès, Barcelona (Spain); European Synchrotron Radiation Facility (ESRF), CS40220, F-38043, Grenoble Cedex (France)

    2014-08-15T23:59:59.000Z

    We demonstrate the use of commercially available fused silica capillary and fittings to construct a cell for operando X-ray absorption spectroscopy (XAS) for the study of heterogeneously catalyzed reactions under high pressure (up to 200 bars) and high temperature (up to 280?°C) conditions. As the first demonstration, the cell was used for CO{sub 2} hydrogenation reaction to examine the state of copper in a conventional Cu/ZnO/Al{sub 2}O{sub 3} methanol synthesis catalyst. The active copper component of the catalyst was shown to remain in the metallic state under supercritical reaction conditions, at 200 bars and up to 260?°C. With the coiled heating system around the capillary, one can easily change the length of the capillary and control the amount of catalyst under investigation. With precise control of reactant(s) flow, the cell can mimic and serve as a conventional fixed-bed micro-reactor system to obtain reliable catalytic data. This high comparability of the reaction performance of the cell and laboratory reactors is crucial to gain insights into the nature of actual active sites under technologically relevant reaction conditions. The large length of the capillary can cause its bending upon heating when it is only fixed at both ends because of the thermal expansion. The degree of the bending can vary depending on the heating mode, and solutions to this problem are also presented. Furthermore, the cell is suitable for Raman studies, nowadays available at several beamlines for combined measurements. A concise study of CO{sub 2} phase behavior by Raman spectroscopy is presented to demonstrate a potential of the cell for combined XAS-Raman studies.

  7. Role of defects in BiFeO{sub 3} multiferroic films and their local electronic structure by x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Ravalia, Ashish; Vagadia, Megha; Solanki, P. S.; Shah, N. A.; Kuberkar, D. G., E-mail: dgkuberkar@rediffmail.com [Department of Physics, Saurashtra University, Rajkot 360 005 (India); Gautam, S.; Chae, K. H. [Nano Material Analysis Centre, Korean Institute of Science and Technology, Seoul 136-79 (Korea, Republic of); Asokan, K. [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

    2014-10-21T23:59:59.000Z

    Present study reports the role of defects in the electrical transport in BiFeO{sub 3} (BFO) multiferroic films and its local electronic structure investigated by near-edge X-ray absorption fine structure. Defects created by high energy 200?MeV Ag{sup +15} ion irradiation with a fluence of ?5?×?10{sup 11} ions/cm{sup 2} results in the increase in structural strain and reduction in the mobility of charge carriers and enhancement in resistive (I-V) and polarization (P-E) switching behaviour. At higher fluence of ?5?×?10{sup 12} ions/cm{sup 2}, there is a release in the structural strain due to local annealing effect, resulting in an increase in the mobility of charge carriers, which are released from oxygen vacancies and hence suppression in resistive and polarization switching. Near-edge X-ray absorption fine structure studies at Fe L{sub 3,2}- and O K-edges show a significant change in the spectral features suggesting the modifications in the local electronic structure responsible for changes in the intrinsic magnetic moment and electrical transport properties of BFO.

  8. SMB, X-ray Emission Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection245C Unlimited ReleaseWelcome to theAbsorption Spectroscopy

  9. GEOC Sunday, March 21, 2010 47 -Speciation and release kinetics of cadmium and zinc in paddy soils: Application of X-ray absorption

    E-Print Network [OSTI]

    Sparks, Donald L.

    : Application of X-ray absorption spectroscopy (XAS) Saengdao Khaokaew, Rufus L Chaney, PhD Matt Ginder kinetics, which is the aim of this research. X-ray absorption spectroscopy (XAS) was used to investigate Cd-ray absorption fine structure (EXAFS) spectroscopic data indicates that CdCO3 and Cd-humic complexes

  10. X-ray absorption in distant type II QSOs

    E-Print Network [OSTI]

    M. Krumpe; G. Lamer; A. Corral; A. D. Schwope; F. J. Carrera; X. Barcons; M. Page; S. Mateos; J. A. Tedds; M. G. Watson

    2008-03-10T23:59:59.000Z

    We present the results of the X-ray spectral analysis of an XMM-Newton-selected type II QSO sample with z>0.5 and 0.5-10 keV flux of 0.3-33 x 10^{-14} erg/s/cm^2. The distribution of absorbing column densities in type II QSOs is investigated and the dependence of absorption on X-ray luminosity and redshift is studied. We inspected 51 spectroscopically classified type II QSO candidates from the XMM-Newton Marano field survey, the XMM-Newton-2dF wide angle survey (XWAS), and the AXIS survey to set-up a well-defined sample with secure optical type II identifications. Fourteen type II QSOs were classified and an X-ray spectral analysis performed. Since most of our sources have only ~40 X-ray counts (PN-detector), we carefully studied the fit results of the simulated X-ray spectra as a function of fit statistic and binning method. We determined that fitting the spectra with the Cash-statistic and a binning of minimum one count per bin recovers the input values of the simulated X-ray spectra best. Above 100 PN counts, the free fits of the spectrum's slope and absorbing hydrogen column density are reliable. We find only moderate absorption (N_H=(2-10) x 10^22 cm^-2) and no obvious trends with redshift and intrinsic X-ray luminosity. In a few cases a Compton-thick absorber cannot be excluded. Two type II objects with no X-ray absorption were discovered. We find no evidence for an intrinsic separation between type II AGN and high X-ray luminosity type II QSO in terms of absorption. The stacked X-ray spectrum of our 14 type II QSOs shows no iron K-alpha line. In contrast, the stack of the 8 type II AGN reveals a very prominent iron K-alpha line at an energy of ~ 6.6 keV and an EW ~ 2 keV.

  11. Soft X-Ray Microscopy and Spectroscopy at the Molecular Environmental...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soft X-Ray Microscopy and Spectroscopy at the Molecular Environmental Science Beamline at the Advanced Light Source. Soft X-Ray Microscopy and Spectroscopy at the Molecular...

  12. X-ray absorption in distant type II QSOs

    E-Print Network [OSTI]

    Krumpe, M; Corral, A; Schwope, A D; Carrera, F J; Barcons, X; Page, M; Mateos, S; Tedds, J A; Watson, M G

    2008-01-01T23:59:59.000Z

    We present the results of the X-ray spectral analysis of an XMM-Newton-selected type II QSO sample with z>0.5 and 0.5-10 keV flux of 0.3-33 x 10^{-14} erg/s/cm^2. The distribution of absorbing column densities in type II QSOs is investigated and the dependence of absorption on X-ray luminosity and redshift is studied. We inspected 51 spectroscopically classified type II QSO candidates from the XMM-Newton Marano field survey, the XMM-Newton-2dF wide angle survey (XWAS), and the AXIS survey to set-up a well-defined sample with secure optical type II identifications. Fourteen type II QSOs were classified and an X-ray spectral analysis performed. Since most of our sources have only ~40 X-ray counts (PN-detector), we carefully studied the fit results of the simulated X-ray spectra as a function of fit statistic and binning method. We determined that fitting the spectra with the Cash-statistic and a binning of minimum one count per bin recovers the input values of the simulated X-ray spectra best. Above 100 PN coun...

  13. Mn Occupations in Ga1-xMnxN Dilute Magnetic Semiconductors Probed by X-Ray Absorption Near-Edge Structure Spectroscopy

    SciTech Connect (OSTI)

    Wei Shiqiang; Yan Wensheng; Sun Zhihu; Liu Qinghua; Zhong Wenjie [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Zhang Xinyi [Department of Physics, Surface Physics Laboratory (National Key Laboratory), Fudan University, 220 Handan Road, Shanghai 200433 (China); Synchrotron Radiation Research Center, Fudan University, 220 Handan Road, Shanghai 200433 (China); Oyanagi, H. [Photonics Research Institute, National Institute of Advanced Industrial Science and Technology 1-1-1 Umezono Tsukuba, Ibaraki 305-8568 (Japan); Wu Ziyu [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 (China)

    2007-02-02T23:59:59.000Z

    X-ray absorption near-edge structure (XANES) is used to study the characteristics of different sites of Mn in the Ga1-xMnxN dilute magnetic semiconductor (DMS) with zinc-blende structure. The XANES spectra of representative Mn occupation sites (substitutional MnGa, interstitial MnI, MnGa-MnI dimer and Mn cluster) in GaN lattice are theoretically calculated and compared with experimental results. The substitutional Mn in GaN is characterized by a pre-edge peak at 2.0 eV and a post-edge multiple-scattering peak at 29.1 eV. The peaks shift in position and drop in intensity dramatically for the interstitial MnI and MnGa-MnI dimmer, and disappear completely for Mn clusters. We propose that the distinct characteristics of Mn K-edge XANES spectra for different Mn sites favor to discriminate Mn occupations in GaMnN DMS.

  14. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    SciTech Connect (OSTI)

    Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

    2010-05-01T23:59:59.000Z

    We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

  15. Cu K-edge X-ray Absorption Spectroscopy Reveals Differential Copper Coordimation Within Amyloid-beta Oligomers Compared to Amyloid-beta Monomers

    SciTech Connect (OSTI)

    J Shearer; P Callan; T Tran; V Szalai

    2011-12-31T23:59:59.000Z

    The fatal neurodegenerative disorder Alzheimer's disease (AD) has been linked to the formation of soluble neurotoxic oligomers of amyloid-{beta} (A{beta}) peptides. These peptides have high affinities for copper cations. Despite their potential importance in AD neurodegeneration few studies have focused on probing the Cu{sup 2+/1+} coordination environment within A{beta} oligomers. Herein we present a Cu K-edge X-ray absorption spectroscopic study probing the copper-coordination environment within oligomers of A{beta}(42) (sequence: DAEFRHDSGYEVHHQKLVFFAEDVGSNKGAIIGLMVGGVVIA). We find that the Cu{sup 2+} cation is contained within a square planar mixed N/O ligand environment within A{beta}(42) oligomers, which is similar to the copper coordination environment of the monomeric forms of {l_brace}Cu{sup II}A{beta}(40){r_brace} and {l_brace}Cu{sup II}A{beta}(16){r_brace}. Reduction of the Cu{sup 2+} cation within the A{beta}(42) oligomers to Cu{sup 1+} yields a highly dioxygen sensitive copper-species that contains Cu{sup 1+} in a tetrahedral coordination geometry. This can be contrasted with monomers of {l_brace}Cu{sup I}A{beta}(40){r_brace} and {l_brace}Cu{sup I}A{beta}(16){r_brace}, which contain copper in a dioxygen inert linear bis-histidine ligand environment [Shearer and Szalai, J. Am. Chem. Soc., 2008, 130, 17826]. The biological implications of these findings are discussed.

  16. Theoretical standards in x-ray spectroscopies. Annual progress report, 1991--1992

    SciTech Connect (OSTI)

    Not Available

    1992-09-01T23:59:59.000Z

    We propose to extend our state-of-the-art, ab initio XAFS (X-ray absorption fine structure) codes, FEFF. Our current work has been highly successful in achieving accurate, user-friendly XAFS standards, exceeding the performance of both tabulated standards and other codes by a considerable margin. We now propose to add the capability to treat more complex materials. This includes multiple-scattering, polarization dependence, an approximate treatment of XANES (x-ray absorption near edge structure), and other improvements. We also plan to adapt FEFF to other spectroscopies, e.g. photoelectron diffraction (PD) and diffraction anomalous fine structure (DAFS).

  17. NSLS (National Synchrotron Light Source) X-19A beamline performance for x-ray absorption measurements

    SciTech Connect (OSTI)

    Yang, C.Y.; Penner-Hahn, J.E.; Stefan, P.M. (Michigan Univ., Ann Arbor, MI (USA). Dept. of Chemistry; Brookhaven National Lab., Upton, NY (USA))

    1989-01-01T23:59:59.000Z

    Characterization of the X-19A beamline at the National Synchrotron Light Source (NSLS) is described. The beamline is designed for high resolution x-ray absorption spectroscopy over a wide energy range. All of the beamline optical components are compatible with ultrahigh vacuum (UHV) operation. This permits measurements to be made in a window-less mode, thereby facilitating lower energy (<4 KeV) studies. To upgrade the beamline performance, several possible improvements in instrumentation and practice are discussed to increase photon statistics with an optimum energy resolution, while decreasing the harmonic contamination and noise level. A special effort has been made to improve the stability and UHV compatibility of the monochromator system. Initial x-ray absorption results demonstrate the capabilities of this beamline for x-ray absorption studies of low Z elements (e.g. S) in highly dilute systems. The future use of this beamline for carrying out various x-ray absorption experiments is presented. 10 refs., 4 figs.

  18. X-RAY ABSORPTION OF HIGH-REDSHIFT QUASARS

    SciTech Connect (OSTI)

    Eitan, Assaf; Behar, Ehud, E-mail: sassafe@tx.technion.ac.il, E-mail: behar@physics.technion.ac.il [Physics Department, Technion, Haifa 32000 (Israel)

    2013-09-01T23:59:59.000Z

    The soft X-ray photoelectric absorption of high-z quasars has been known for two decades, but has no unambiguous astrophysical context. We construct the largest sample to date of 58 high-redshift quasars (z > 0.45) selected from the XMM-Newton archive based on a high photon count criterion (>1800). We measure the optical depth {tau} at 0.5 keV and find that 43% of the quasars show significant absorption. We aim to find which physical parameters of the quasars, e.g., redshift, radio luminosity, radio loudness, or X-ray luminosity, drive their observed absorption. We compare the absorption behavior with redshift with the pattern expected if the diffuse intergalactic medium (IGM) is responsible for the observed absorption. We also compare the absorption with a comparison sample of gamma-ray burst (GRB) X-ray afterglows. Although the z > 2 quasar opacity is consistent with diffuse IGM absorption, many intermediate-z (0.45 < z < 2) quasars are not sufficiently absorbed for this scenario, and are appreciably less absorbed than GRBs. Only 10/37 quasars at z < 2 are absorbed, and only 5/30 radio-quiet quasars are absorbed. We find a weak correlation between {tau} and z, and an even weaker correlation between {tau} and radio luminosity. These findings lead to the conclusion that although a diffuse IGM origin for the quasar absorption is unlikely, the optical depth does seem to increase with redshift, roughly as (1 + z){sup 2.2{+-}0.6}, tending to {tau} Almost-Equal-To 0.4 at high redshifts, similar to the high-z GRBs. This result can be explained by an ionized and clumpy IGM at z < 2, and a cold, diffuse IGM at higher redshift. If, conversely, the absorption occurs at the quasar, and owing to the steep L{sub x} {proportional_to}(1 + z){sup 7.1{+-}0.5} correlation in the present sample, the host column density scales as N{sub H}{proportional_to}L{sub x}{sup 0.7{+-}0.1}.

  19. State-Dependent Electron Delocalization Dynamics at the Solute-Solvent Interface: Soft X-ray Absorption Spectroscopy and Ab Initio Calculations

    E-Print Network [OSTI]

    Bokarev, Sergey I; Suljoti, Edlira; Kühn, Oliver; Aziz, Emad F

    2013-01-01T23:59:59.000Z

    Non-radiative decay channels in the L-edge fluorescence spectra from transition metal-aqueous solutions give rise to spectral dips in X-ray transmission spectra. Their origin is unraveled here using partial and inverse partial fluorescence yields on the micro-jet combined with multi-reference ab initio electronic structure calculations. Comparing Fe2+, Fe3+, and Co2+ systems we demonstrate unequivocally that spectral dips are due to a state-dependent electron delocalization within the manifold of d-orbitals.

  20. High-resolution X-ray spectroscopy of Theta Car

    E-Print Network [OSTI]

    Yael Naze; Gregor Rauw

    2008-08-25T23:59:59.000Z

    Context : The peculiar hot star Theta Car in the open cluster IC2602 is a blue straggler as well as a single-line binary of short period (2.2d). Aims : Its high-energy properties are not well known, though X-rays can provide useful constraints on the energetic processes at work in binaries as well as in peculiar, single objects. Methods : We present the analysis of a 50ks exposure taken with the XMM-Newton observatory. It provides medium as well as high-resolution spectroscopy. Results : Our high-resolution spectroscopy analysis reveals a very soft spectrum with multiple temperature components (1--6MK) and an X-ray flux slightly below the `canonical' value (log[L_X(0.1-10.)/L_{BOL}] ~ -7). The X-ray lines appear surprisingly narrow and unshifted, reminiscent of those of beta Cru and tau Sco. Their relative intensities confirm the anomalous abundances detected in the optical domain (C strongly depleted, N strongly enriched, O slightly depleted). In addition, the X-ray data favor a slight depletion in neon and iron, but they are less conclusive for the magnesium abundance (solar-like?). While no significant changes occur during the XMM-Newton observation, variability in the X-ray domain is detected on the long-term range. The formation radius of the X-ray emission is loosely constrained to <5 R_sol, which allows for a range of models (wind-shock, corona, magnetic confinement,...) though not all of them can be reconciled with the softness of the spectrum and the narrowness of the lines.

  1. Three-dimensional mapping of nickel oxidation states using full field x-ray absorption near edge structure nanotomography

    SciTech Connect (OSTI)

    Nelson, George J.; Harris, William M.; Izzo, John R. Jr.; Grew, Kyle N.; Chiu, Wilson K. S. [HeteroFoaM Center, a DOE Energy Frontier Research Center, Department of Mechanical Engineering, University of Connecticut, 191 Auditorium Rd., Storrs, Connecticut 06269-3139 (United States); Chu, Yong S. [National Synchrotron Light Source II, Brookhaven National Laboratory, Bldg. 703 Upton, New York 11973-5000 (United States); Yi, Jaemock [Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Ave., Bldg. 438-B007 Argonne, Illinois 60439 (United States); Andrews, Joy C.; Liu Yijin; Pianetta, Piero [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, 2575 Sand Hill Rd., MS 69 Menlo Park, California 94025 (United States)

    2011-04-25T23:59:59.000Z

    The reduction-oxidation cycling of the nickel-based oxides in composite solid oxide fuel cells and battery electrodes is directly related to cell performance. A greater understanding of nickel redox mechanisms at the microstructural level can be achieved in part using transmission x-ray microscopy (TXM) to explore material oxidation states. X-ray nanotomography combined with x-ray absorption near edge structure (XANES) spectroscopy has been applied to study samples containing distinct regions of nickel and nickel oxide (NiO) compositions. Digitally processed images obtained using TXM demonstrate the three-dimensional chemical mapping and microstructural distribution capabilities of full-field XANES nanotomography.

  2. C-C bond unsaturation degree in monosubstituted ferrocenes for molecular electronics investigated by a combined near-edge x-ray absorption fine structure, x-ray photoemission spectroscopy, and density functional theory approach

    SciTech Connect (OSTI)

    Boccia, A.; Lanzilotto, V.; Marrani, A. G.; Zanoni, R. [Dipartimento di Chimica, Universita degli Studi di Roma ''La Sapienza'', piazzale Aldo Moro 5, I-00185 Rome (Italy); Stranges, S. [Dipartimento di Chimica, Universita degli Studi di Roma ''La Sapienza'', piazzale Aldo Moro 5, I-00185 Rome (Italy); IOM-CNR, Laboratorio TASC, I-34149 Basovizza, Trieste (Italy); Alagia, M. [IOM-CNR, Laboratorio TASC, I-34149 Basovizza, Trieste (Italy); Fronzoni, G.; Decleva, P. [Dipartimento di Scienze Chimiche, Universita di Trieste, Via L. Giorgieri 1, I-34127 Trieste, Italy and IOM-CNR Democritos, Trieste (Italy)

    2012-04-07T23:59:59.000Z

    We present the results of an experimental and theoretical investigation of monosubstituted ethyl-, vinyl-, and ethynyl-ferrocene (EtFC, VFC, and EFC) free molecules, obtained by means of synchrotron-radiation based C 1s photoabsorption (NEXAFS) and photoemission (C 1s XPS) spectroscopies, and density functional theory (DFT) calculations. Such a combined study is aimed at elucidating the role played by the C-C bond unsaturation degree of the substituent on the electronic structure of the ferrocene derivatives. Such substituents are required for molecular chemical anchoring onto relevant surfaces when ferrocenes are used for molecular electronics hybrid devices. The high resolution C 1s NEXAFS spectra exhibit distinctive features that depend on the degree of unsaturation of the hydrocarbon substituent. The theoretical approach to consider the NEXAFS spectrum made of three parts allowed to disentangle the specific contribution of the substituent group to the experimental spectrum as a function of its unsaturation degree. C 1s IEs were derived from the experimental data analysis based on the DFT calculated IE values for the different carbon atoms of the substituent and cyclopentadienyl (Cp) rings. Distinctive trends of chemical shifts were observed for the substituent carbon atoms and the substituted atom of the Cp ring along the series of ferrocenes. The calculated IE pattern was rationalized in terms of initial and final state effects influencing the IE value, with special regard to the different mechanism of electron conjugation between the Cp ring and the substituent, namely the {sigma}/{pi} hyperconjugation in EtFC and the {pi}-conjugation in VFC and EFC.

  3. X-ray absorption spectroscopic studies of mononuclear non-heme iron enzymes

    SciTech Connect (OSTI)

    Westre, T.E.

    1996-01-01T23:59:59.000Z

    Fe-K-edge X-ray absorption spectroscopy (XAS) has been used to investigate the electronic and geometric structure of the iron active site in non-heme iron enzymes. A new theoretical extended X-ray absorption fine structure (EXAFS) analysis approach, called GNXAS, has been tested on data for iron model complexes to evaluate the utility and reliability of this new technique, especially with respect to the effects of multiple-scattering. In addition, a detailed analysis of the 1s{yields}3d pre-edge feature has been developed as a tool for investigating the oxidation state, spin state, and geometry of iron sites. Edge and EXAFS analyses have then been applied to the study of non-heme iron enzyme active sites.

  4. X-ray spectroscopy of neutron star low-mass X-ray binaries

    E-Print Network [OSTI]

    Krauss, Miriam Ilana

    2007-01-01T23:59:59.000Z

    In this thesis, I present work spanning a variety of topics relating to neutron star lowmass X-ray binaries (LMXBs) and utilize spectral information from X-ray observations to further our understanding of these sources. ...

  5. SURFACE SEGREGATION STUDIES OF SOFC CATHODES: COMBINING SOFT X-RAYS AND ELECTROCHEMICAL IMPEDENCE SPECTROSCOPY

    SciTech Connect (OSTI)

    Miara, Lincoln J.; Piper, L.F.J.; Davis, Jacob N.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Basu, Soumendra; Smith, K. E.; Pal, Uday B.; Gopalan, Srikanth

    2010-12-01T23:59:59.000Z

    A system to grow heteroepitaxial thin-films of solid oxide fuel cell (SOFC) cathodes on single crystal substrates was developed. The cathode composition investigated was 20% strontium-doped lanthanum manganite (LSM) grown by pulsed laser deposition (PLD) on single crystal (111) yttria-stabilized zirconia (YSZ) substrates. By combining electrochemical impedance spectroscopy (EIS) with x-ray photoemission spectroscopy (XPS) and x-ray absorption spectroscopy XAS measurements, we conclude that electrically driven cation migration away from the two-phase gas-cathode interface results in improved electrochemical performance. Our results provide support to the premise that the removal of surface passivating phases containing Sr2+ and Mn2+, which readily form at elevated temperatures even in O2 atmospheric pressures, is responsible for the improved cathodic performance upon application of a bias.

  6. A doubly curved elliptical crystal spectrometer for the study of localized x-ray absorption in hot plasmas

    SciTech Connect (OSTI)

    Cahill, Adam D., E-mail: adc87@cornell.edu; Hoyt, Cad L.; Pikuz, Sergei A.; Shelkovenko, Tania; Hammer, David A. [Cornell University, Electrical and Computer Engineering, Ithaca, NY 14853 (United States)

    2014-10-15T23:59:59.000Z

    X-ray absorption spectroscopy is a powerful tool for the diagnosis of plasmas over a wide range of both temperature and density. However, such a measurement is often limited to probing plasmas with temperatures well below that of the x-ray source in order to avoid object plasma emission lines from obscuring important features of the absorption spectrum. This has excluded many plasmas from being investigated by this technique. We have developed an x-ray spectrometer that provides the ability to record absorption spectra from higher temperature plasmas than the usual approach allows without the risk of data contamination by line radiation emitted by the plasma under study. This is accomplished using a doubly curved mica crystal which is bent both elliptically and cylindrically. We present here the foundational work in the design and development of this spectrometer along with initial results obtained with an aluminum x-pinch as the object plasma.

  7. First results from the high-brightness x-ray spectroscopy beamline 9. 3.1 at ALS

    SciTech Connect (OSTI)

    Ng, W.; Jones, G.; Perera, R.C.C.

    1995-10-01T23:59:59.000Z

    Beamline 9.3.1 at the Advanced Light Source (ALS) is a windowless beamline, covering the 1-6 keV photon-energy range. This beamline is designed to achieve the goal of high brightness at the sample for use in the X-ray Atomic and Molecular Spectroscopy (XAMS) science, surface and interface science, biology, and x-ray optical development programs at ALS. X-ray absorption and time of flight photoemission measurements in 2 - 5 keV photon energy along with the flux, resolution, spot size and stability of the beamline will be discussed. Prospects for future XAMS measurements will also be presented.

  8. Core and Valence Excitations in Resonant X-ray Spectroscopy using Restricted Excitation Window Time-dependent Density Functional Theory

    SciTech Connect (OSTI)

    Zhang, Yu; Biggs, Jason D.; Healion, Daniel; Govind, Niranjan; Mukamel, Shaul

    2012-11-21T23:59:59.000Z

    We report simulations of X-ray absorption near edge structure (XANES), resonant inelastic X-ray scattering (RIXS) and 1D stimulated X-ray Raman spectroscopy (SXRS) signals of cysteine at the oxygen, nitrogen and sulfur K and L2,3 edges. The simulated XANES signals from the restricted window time-dependent density functional theory (REW-TDDFT) and the static exchange (STEX) method are compared with experiments, showing that REW-TDDFT is more accurate and computationally less expensive than STEX. Simulated RIXS and 1D SXRS signals from REW-TDDFT give some insights on the correlation of different excitations in the molecule.

  9. angle x-ray absorption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    angle x-ray absorption First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Time Resolved X-Ray Absorption...

  10. X-ray Absorption Spectroscopy and Density Functional Theory Studies of [(H3buea)FeIII-X]n1 (X= S2-, O2-,OH-): Comparison of Bonding and Hydrogen Bonding in Oxo and Sulfido Complexes

    SciTech Connect (OSTI)

    Dey, Abhishek; Hocking, Rosalie K.; /Stanford U., Chem. Dept.; Larsen, Peter; Borovik, Andrew S.; /Kansas U.; Hodgson, Keith O.; Hedman, Britt; Solomon, Edward I.; /SLAC,

    2006-09-27T23:59:59.000Z

    Iron L-edge, iron K-edge, and sulfur K-edge X-ray absorption spectroscopy was performed on a series of compounds [Fe{sup III}H{sub 3}buea(X)]{sup n-} (X = S{sup 2-}, O{sup 2-}, OH{sup -}). The experimentally determined electronic structures were used to correlate to density functional theory calculations. Calculations supported by the data were then used to compare the metal-ligand bonding and to evaluate the effects of H-bonding in Fe{sup III}-O vs Fe{sup III-}S complexes. It was found that the Fe{sup III-}O bond, while less covalent, is stronger than the FeIII-S bond. This dominantly reflects the larger ionic contribution to the Fe{sup III-}O bond. The H-bonding energy (for three H-bonds) was estimated to be -25 kcal/mol for the oxo as compared to -12 kcal/mol for the sulfide ligand. This difference is attributed to the larger charge density on the oxo ligand resulting from the lower covalency of the Fe-O bond. These results were extended to consider an Fe{sup IV-}O complex with the same ligand environment. It was found that hydrogen bonding to Fe{sup IV-}O is less energetically favorable than that to Fe{sup III-}O, which reflects the highly covalent nature of the Fe{sup IV-}O bond.

  11. Time-resolved soft x-ray absorption setup using multi-bunch operation modes at synchrotrons

    SciTech Connect (OSTI)

    Stebel, L.; Sigalotti, P.; Ressel, B.; Cautero, G. [Sincrotrone Trieste, S.S. 14 km 163.5, Area Science Park, 34149 Basovizza (Italy); Malvestuto, M.; Capogrosso, V. [Sincrotrone Trieste, S.S. 14 km 163.5, Area Science Park, 34149 Basovizza (Italy); Department of Physics, University of Trieste, via A. Valerio 2, 34127, Trieste (Italy); Bondino, F.; Magnano, E. [IOM-CNR, TASC laboratory, S.S. 14 km 163.5, Area Science Park, 34149 Basovizza (Italy); Parmigiani, F. [Sincrotrone Trieste, S.S. 14 km 163.5, Area Science Park, 34149 Basovizza (Italy); Department of Physics, University of Trieste, via A. Valerio 2, 34127, Trieste (Italy); IOM-CNR, TASC laboratory, S.S. 14 km 163.5, Area Science Park, 34149 Basovizza (Italy)

    2011-12-15T23:59:59.000Z

    Here, we report on a novel experimental apparatus for performing time-resolved soft x-ray absorption spectroscopy in the sub-ns time scale using non-hybrid multi-bunch mode synchrotron radiation. The present setup is based on a variable repetition rate Ti:sapphire laser (pump pulse) synchronized with the {approx}500 MHz x-ray synchrotron radiation bunches and on a detection system that discriminates and singles out the significant x-ray photon pulses by means of a custom made photon counting unit. The whole setup has been validated by measuring the time evolution of the L{sub 3} absorption edge during the melting and the solidification of a Ge single crystal irradiated by an intense ultrafast laser pulse. These results pave the way for performing synchrotron time-resolved experiments in the sub-ns time domain with variable repetition rate exploiting the full flux of the synchrotron radiation.

  12. ON RELATIVISTIC DISK SPECTROSCOPY IN COMPACT OBJECTS WITH X-RAY CCD CAMERAS

    SciTech Connect (OSTI)

    Miller, J. M.; Cackett, E. M. [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); D'Ai, A. [Dipartimento di Scienze Fisiche ed Astronomiche, Universita di Palermo, Palermo (Italy); Bautz, M. W.; Nowak, M. A. [Kavli Institute for Astrophysics and Space Research, MIT, 77 Massachusetts Avenue, Cambridge, MA 02139 (United States); Bhattacharyya, S. [Department of Astronomy and Astrophysics, Tata Institute of Fundamental Research, Mumbai 400005 (India); Burrows, D. N.; Kennea, J. [Department of Astronomy and Astrophysics, Pennsylvania State University, 525 Davey Lab, College Park, PA 16802 (United States); Fabian, A. C.; Reis, R. C. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CB3 OHA (United Kingdom); Freyberg, M. J.; Haberl, F. [Max-Planck-Institut fuer extraterrestrische Physik, Giessenbachstrasse, 85748 Garching (Germany); Strohmayer, T. E. [Astrophysics Science Division, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Tsujimoto, M., E-mail: jonmm@umich.ed [Japan Aerospace Exploration Agency, Institute of Space and Astronomical Sciences, 3-1-1 Yoshino-dai, Sagamihara, Kanagawa 229-8510 (Japan)

    2010-12-01T23:59:59.000Z

    X-ray charge-coupled devices (CCDs) are the workhorse detectors of modern X-ray astronomy. Typically covering the 0.3-10.0 keV energy range, CCDs are able to detect photoelectric absorption edges and K shell lines from most abundant metals. New CCDs also offer resolutions of 30-50 (E/{Delta}E), which is sufficient to detect lines in hot plasmas and to resolve many lines shaped by dynamical processes in accretion flows. The spectral capabilities of X-ray CCDs have been particularly important in detecting relativistic emission lines from the inner disks around accreting neutron stars and black holes. One drawback of X-ray CCDs is that spectra can be distorted by photon 'pile-up', wherein two or more photons may be registered as a single event during one frame time. We have conducted a large number of simulations using a statistical model of photon pile-up to assess its impacts on relativistic disk line and continuum spectra from stellar-mass black holes and neutron stars. The simulations cover the range of current X-ray CCD spectrometers and operational modes typically used to observe neutron stars and black holes in X-ray binaries. Our results suggest that severe photon pile-up acts to falsely narrow emission lines, leading to falsely large disk radii and falsely low spin values. In contrast, our simulations suggest that disk continua affected by severe pile-up are measured to have falsely low flux values, leading to falsely small radii and falsely high spin values. The results of these simulations and existing data appear to suggest that relativistic disk spectroscopy is generally robust against pile-up when this effect is modest.

  13. On Relativistic Disk Spectroscopy in Compact Objects with X-ray CCD Cameras

    E-Print Network [OSTI]

    J. M. Miller; A. D'Ai; M. W. Bautz; S. Bhattacharyya; D. N. Burrows; E. M. Cackett; A. C. Fabian; M. J. Freyberg; F. Haberl; J. Kennea; M. A Nowak; R. C. Reis; T. E. Strohmayer; M. Tsujimoto

    2010-09-22T23:59:59.000Z

    X-ray charge-coupled devices (CCDs) are the workhorse detectors of modern X-ray astronomy. Typically covering the 0.3-10.0 keV energy range, CCDs are able to detect photoelectric absorption edges and K shell lines from most abundant metals. New CCDs also offer resolutions of 30-50 (E/dE), which is sufficient to detect lines in hot plasmas and to resolve many lines shaped by dynamical processes in accretion flows. The spectral capabilities of X-ray CCDs have been particularly important in detecting relativistic emission lines from the inner disks around accreting neutron stars and black holes. One drawback of X-ray CCDs is that spectra can be distorted by photon "pile-up", wherein two or more photons may be registered as a single event during one frame time. We have conducted a large number of simulations using a statistical model of photon pile-up to assess its impacts on relativistic disk line and continuum spectra from stellar-mass black holes and neutron stars. The simulations cover the range of current X-ray CCD spectrometers and operational modes typically used to observe neutron stars and black holes in X-ray binaries. Our results suggest that severe photon pile-up acts to falsely narrow emission lines, leading to falsely large disk radii and falsely low spin values. In contrast, our simulations suggest that disk continua affected by severe pile-up are measured to have falsely low flux values, leading to falsely small radii and falsely high spin values. The results of these simulations and existing data appear to suggest that relativistic disk spectroscopy is generally robust against pile-up when this effect is modest.

  14. X-Ray Absorption Spectroscopy of Metallobiomolecules

    E-Print Network [OSTI]

    Scott, Robert A.

    by the Center for Metalloenzyme Studies (CMS) at the University of Georgia, Athens. Reference Material: Shulman information at the supramolecular to macromolecular level, One-dimensional (1°) molecular level information

  15. X-Ray Absorption Spectroscopy of Metallobiomolecules

    E-Print Network [OSTI]

    Scott, Robert A.

    by the Center for Metalloenzyme Studies (CMS) at the University of Georgia, Athens. Reference Material: Shulman at the supramolecular to macromolecular level, One-dimensional (1°) molecular level information is available through

  16. 3D Imaging of Nickel Oxidation States using Full Field X-ray Absorption Near Edge Structure Nanotomography

    SciTech Connect (OSTI)

    Nelson, George; Harris, William; Izzo, John; Grew, Kyle N. (Connecticut); (USARL)

    2012-01-20T23:59:59.000Z

    Reduction-oxidation (redox) cycling of the nickel electrocatalyst phase in the solid oxide fuel cell (SOFC) anode can lead to performance degradation and cell failure. A greater understanding of nickel redox mechanisms at the microstructural level is vital to future SOFC development. Transmission x-ray microscopy (TXM) provides several key techniques for exploring oxidation states within SOFC electrode microstructure. Specifically, x-ray nanotomography and x-ray absorption near edge structure (XANES) spectroscopy have been applied to study samples of varying nickel (Ni) and nickel oxide (NiO) compositions. The imaged samples are treated as mock SOFC anodes containing distinct regions of the materials in question. XANES spectra presented for the individual materials provide a basis for the further processing and analysis of mixed samples. Images of composite samples obtained are segmented, and the distinct nickel and nickel oxide phases are uniquely identified using full field XANES spectroscopy. Applications to SOFC analysis are discussed.

  17. Ultrafast X-Ray Spectroscopy as a Probe of Nonequilibrium Dynamics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dynamic broadenings, and changes in the branching ratio. The authors demonstrate that ultrafast x-ray spectroscopy is a suitable probe to deliver detailed new insights or...

  18. Chandra High Resolution X-ray Spectroscopy of AM Her

    E-Print Network [OSTI]

    V. Girish; V. R. Rana; K. P. Singh

    2007-02-14T23:59:59.000Z

    We present the results of high resolution spectroscopy of the prototype polar AM Herculis observed with Chandra High Energy Transmission Grating. The X-ray spectrum contains hydrogen-like and helium-like lines of Fe, S, Si, Mg, Ne and O with several Fe L-shell emission lines. The forbidden lines in the spectrum are generally weak whereas the hydrogen-like lines are stronger suggesting that emission from a multi-temperature, collisionally ionized plasma dominates. The helium-like line flux ratios yield a plasma temperature of 2 MK and a plasma density 1 - 9 x10^12 cm^-3, whereas the line flux ratio of Fe XXVI to Fe XXV gives an ionization temperature of 12.4 +1.1 -1.4 keV. We present the differential emission measure distribution of AM Her whose shape is consistent with the volume emission measure obtained by multi-temperature APEC model. The multi-temperature plasma model fit to the average X-ray spectrum indicates the mass of the white dwarf to be ~1.15 M_sun. From phase resolved spectroscopy, we find the line centers of Mg XII, S XVI, resonance line of Fe XXV, and Fe XXVI emission modulated by a few hundred to 1000 km/s from the theoretically expected values indicating bulk motion of ionized matter in the accretion column of AM Her. The observed velocities of Fe XXVI ions are close to the expected shock velocity for a 0.6 M_sun white dwarf. The observed velocity modulation is consistent with that expected from a single pole accreting binary system.

  19. Number of relevant independent points in x-ray-absorption fine-structure spectra

    SciTech Connect (OSTI)

    Stern, E.A. (Physics Department FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-10-01T23:59:59.000Z

    A discussion is given of the amount of information present in x-ray-absorption fine-structure spectra. It is shown that the usual formulations underestimate the degrees of freedom by at least one.

  20. Nuclear resonant inelastic X-ray scattering and synchrotron Mossbauer spectroscopy

    E-Print Network [OSTI]

    Lin, Jung-Fu "Afu"

    Chapter 19 Nuclear resonant inelastic X-ray scattering and synchrotron Mo¨ssbauer spectroscopy with nuclear resonant inelastic X-ray scattering and synchrotron Mo¨ssbauer spectroscopy for studying magnetic to the Planck radiation function. Synchrotron Mo¨ssbauer spectra and partial phonon density of states (PDOS

  1. X-ray absorption spectroscopic studies of the active sites of nickel- and copper-containing metalloproteins

    SciTech Connect (OSTI)

    Tan, G.O.

    1993-06-01T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) is a useful tool for obtaining structural and chemical information about the active sites of metalloproteins and metalloenzymes. Information may be obtained from both the edge region and the extended X-ray absorption fine structure (EXAFS) or post-edge region of the K-edge X-ray absorption spectrum of a metal center in a compound. The edge contains information about the valence electronic structure of the atom that absorbs the X-rays. It is possible in some systems to infer the redox state of the metal atom in question, as well as the geometry and nature of ligands connected to it, from the features in the edge in a straightforward manner. The EXAFS modulations, being produced by the backscattering of the ejected photoelectron from the atoms surrounding the metal atom, provide, when analyzed, information about the number and type of neighbouring atoms, and the distances at which they occur. In this thesis, analysis of both the edge and EXAFS regions has been used to gain information about the active sites of various metalloproteins. The metalloproteins studied were plastocyanin (Pc), laccase and nickel carbon monoxide dehydrogenase (Ni CODH). Studies of Cu(I)-imidazole compounds, related to the protein hemocyanin, are also reported here.

  2. Phase Effects on Mesoscale Object X-ray Absorption Images

    SciTech Connect (OSTI)

    Martz, Jr., H E; Aufderheide, M B; Barty, A; Lehman, S K; Kozioziemski, B J; Schneberk, D J

    2004-09-24T23:59:59.000Z

    At Lawrence Livermore National Laboratory particular emphasis is being placed on the nondestructive characterization (NDC) of 'mesoscale' objects.[Martz and Albrecht 2003] We define mesoscale objects as objects that have mm extent with {micro}m features. Here we confine our discussions to x-ray imaging methods applicable to mesoscale object characterization. The goal is object recovery algorithms including phase to enable emerging high-spatial resolution x-ray imaging methods to ''see'' inside or image mesoscale-size materials and objects. To be successful our imaging characterization effort must be able to recover the object function to one micrometer or better spatial resolution over a few millimeters field-of-view with very high contrast.

  3. Characterization of the Electronic Structure of Silicon Nanoparticles Using X-ray Absorption and Emission

    SciTech Connect (OSTI)

    Vaverka, A M

    2008-07-15T23:59:59.000Z

    Resolving open questions regarding transport in nanostructures can have a huge impact on a broad range of future technologies such as light harvesting for energy. Silicon has potential to be used in many of these applications. Understanding how the band edges of nanostructures move as a function of size, surface termination and assembly is of fundamental importance in understanding the transport properties of these materials. In this thesis work I have investigated the change in the electronic structure of silicon nanoparticle assemblies as the surface termination is changed. Nanoparticles are synthesized using a thermal evaporation technique and sizes are determined using atomic force microscopy (AFM). By passivating the particles with molecules containing alcohol groups we are able to modify the size dependent band edge shifts. Both the valence and conduction bands are measured using synchrotron based x-ray absorption spectroscopy (XAS) and soft x-ray fluorescence (SXF) techniques. Particles synthesized via recrystallization of amorphous silicon/SiO{sub 2} multilayers of thicknesses below 10 nm are also investigated using the synchrotron techniques. These samples also show quantum confinement effects but the electronic structure is different from those synthesized via evaporation methods. The total bandgap is determined for all samples measured. The origins of these differences in the electronic structures are discussed.

  4. Soft X-ray Spectroscopy Study of the Electronic Structure of Oxidized and Partially Oxidized Magnetite Nanoparticles

    SciTech Connect (OSTI)

    Gilbert, Benjamin; Katz, Jordan E.; Denlinger, Jonathan D.; Yin, Yadong; Falcone, Roger; Waychunas, Glenn A.

    2010-10-24T23:59:59.000Z

    The crystal structure of magnetite nanoparticles may be transformed to maghemite by complete oxidation, but under many relevant conditions the oxidation is partial, creating a mixed-valence material with structural and electronic properties that are poorly characterized. We used X-ray diffraction, Fe K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy, and soft X-ray absorption and emission spectroscopy to characterize the products of oxidizing uncoated and oleic acid-coated magnetite nanoparticles in air. The oxidization of uncoated magnetite nanoparticles creates a material that is structurally and electronically indistinguishable from maghemite. By contrast, while oxidized oleic acid-coated nanoparticles are also structurally indistinguishable from maghemite, Fe L-edge spectroscopy revealed the presence of interior reduced iron sites even after a 2-year period. We used X-ray emission spectroscopy at the O K-edge to study the valence bands (VB) of the iron oxide nanoparticles, using resonant excitation to remove the contributions from oxygen atoms in the ligands and from low-energy excitations that obscured the VB edge. The bonding in all nanoparticles was typical of maghemite, with no detectable VB states introduced by the long-lived, reduced-iron sites in the oleic acid-coated sample. However, O K-edge absorption spectroscopy observed a 0.2 eV shift in the position of the lowest unoccupied states in the coated sample, indicating an increase in the semiconductor band gap relative to bulk stoichiometric maghemite that was also observed by optical absorption spectroscopy. The results show that the ferrous iron sites within ferric iron oxide nanoparticles coated by an organic ligand can persist under ambient conditions with no evidence of a distinct interior phase and can exert an effect on the global electronic and optical properties of the material. This phenomenon resembles the band gap enlargement caused by electron accumulation in the conduction band of TiO2.

  5. ON RELATIVISTIC DISK SPECTROSCOPY IN COMPACT OBJECTS WITH X-RAY CCD CAMERAS

    E-Print Network [OSTI]

    Miller, J. M.

    X-ray charge-coupled devices (CCDs) are the workhorse detectors of modern X-ray astronomy. Typically covering the 0.3-10.0 keV energy range, CCDs are able to detect photoelectric absorption edges and K shell lines from ...

  6. Novel Approaches to Soft X-ray Spectroscopy: Scanning TransmissionX-ray Microscopy and Ambient Pressure X-Ray PhotoelectronSpectroscopy

    SciTech Connect (OSTI)

    Bluhm, Hendrik; Gilles, Mary K.; Mun, Simon B.; Tyliszczak, Tolek

    2006-02-01T23:59:59.000Z

    This workshop focused on novel spectroscopies at Beamlines 11.0.2, 5.3.2 and 9.3.2 at the ALS. The workshop brought together users from a wide range of fields to highlight recent experimental and technical developments both in scanning transmission X-ray spectroscopy (STXM) and ambient pressure photoelectron spectroscopy (APPES). The morning session featured talks on experiments involving new developments at the STXM, while the afternoon session was devoted to those using APXPS. In the morning session, Tolek Tyliszczak discussed the improved detector developments at the STXM, such as an avalanche photodiode detector and fluorescence and electron detection, as well as the continued development of in situ cells for heating, gas flow, and electrochemical cells. Of these, only the avalanche photodiode in combination with a novel multichannel photon-counting system is in routine use in time-resolved studies. Bartel Van Waeyenberge (Ghent University) presented results of magnetic imaging with a time resolution of 70-100 ps combined with a lateral resolution of 20-40 nm performed with the STXM (Beamline 11.0.2). As a complement to the time-domain ''pump-and-probe'' measurements, they developed a frequency-domain ''sine-excitation'' technique in order to study specific eigenmodes of these ferromagnetic patterns with high spatial resolution. This new approach was used to study the gyrotropic vortex motions in micron-sized ferromagnetic patterns. Adam Hitchcock (McMaster University) presented the development, in collaboration with Daniel Guay (INRS, Varennes) and Sherry Zhang, of the apparatus and techniques for applying STXM to in-situ studies of electrochemistry, in particular electrochromism in polyaniline. In addition, substantial progress was reported on a joint project to develop substrates and methods for chemically selective lithography of multilayer polymer systems. Selective patterns, such as that displayed in the figure, can now be written efficiently with the bend magnet STXM on Beamline 5.3.2. Yves Acremann (SSRL) discussed time and spatially resolved X-ray magnetic circular dichroism (XMCD) experiments on spin transfer devices at the STXM (Beamline 11.0.2). These elegant experiments explore time resolved measurements of the magnetization dynamics within a 100 x 150 nm sample influenced by a spin-polarized current. This experiment shows that the magnetization in these magnetic nanostructures are not uniform, as they are influenced by the Oersted field of the charge current needed to generate the spin current. The implementation of a novel multichannel photon counting system in combination with an avalanche photon detector decreased the data-acquisition time by a factor of 10, owing to its ability to resolve the structure of multi bunch mode. Gordon E. Brown, Jr. (Stanford University and SSRL) described ''Applications of STXM to Microbial Bioweathering and Biomineralization''. In the interaction of bacteria with ferrihydrite nanoparticles, microenvironments that were very different than the bulk material were observed, showing that bulk thermodynamics may not be useful for predicting micro phases. Gordon also presented work showing that iron nanoparticles are attracted to the negatively charged bacteria and form a coating that reduces iron oxide minerals. The afternoon session started with presentations by Simon Mun and Hendrik Bluhm, who discussed the current status and the future plans for the two APPES end-stations at the ALS, which are located at Beamlines 9.3.2 and 11.0.2, respectively. In both end-stations, samples can be measured in gaseous environments at pressures of up to several Torr, which makes possible the investigation of numerous phenomena, in particular in the fields of atmospheric and environmental science as well as heterogeneous catalysis. Specific examples of the application of APPES were shown in the following presentations. John Hemminger (University of California, Irvine) reported on APPES investigations at Beamlines 9.3.2 and 11.0.2 of the interaction of alkali halide surfaces with water. The m

  7. Finite temperature effects on the X-ray absorption spectra of lithium compounds: First-principles interpretation of X-ray Raman measurements

    SciTech Connect (OSTI)

    Pascal, Tod A.; Prendergast, David, E-mail: dgprendergast@lbl.gov [The Molecular Foundry, Materials Science Division, Lawrence Berkeley National Laboratory (LBNL), Berkeley, California 94720 (United States)] [The Molecular Foundry, Materials Science Division, Lawrence Berkeley National Laboratory (LBNL), Berkeley, California 94720 (United States); Boesenberg, Ulrike; Kostecki, Robert; Richardson, Thomas J. [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States)] [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States); Weng, Tsu-Chien; Sokaras, Dimosthenis; Nordlund, Dennis [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford, California 94720 (United States)] [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford, California 94720 (United States); McDermott, Eamon; Moewes, Alexander [University of Saskatchewan, Department of Physics and Engineering Physics, Saskatoon, Saskatchewan S7N 5E2 (Canada)] [University of Saskatchewan, Department of Physics and Engineering Physics, Saskatoon, Saskatchewan S7N 5E2 (Canada); Cabana, Jordi [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States) [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States); Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60605 (United States)

    2014-01-21T23:59:59.000Z

    We elucidate the role of room-temperature-induced instantaneous structural distortions in the Li K-edge X-ray absorption spectra (XAS) of crystalline LiF, Li{sub 2}SO{sub 4}, Li{sub 2}O, Li{sub 3}N, and Li{sub 2}CO{sub 3} using high resolution X-ray Raman spectroscopy (XRS) measurements and first-principles density functional theory calculations within the eXcited electron and Core Hole approach. Based on thermodynamic sampling via ab initio molecular dynamics simulations, we find calculated XAS in much better agreement with experiment than those computed using the rigid crystal structure alone. We show that local instantaneous distortion of the atomic lattice perturbs the symmetry of the Li 1s core-excited-state electronic structure, broadening spectral line-shapes and, in some cases, producing additional spectral features. The excellent agreement with high-resolution XRS measurements validates the accuracy of our first-principles approach to simulating XAS, and provides both accurate benchmarks for model compounds and a predictive theoretical capability for identification and characterization of multi-component systems, such as lithium-ion batteries, under working conditions.

  8. In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial Photosynthesis Monday, June 30, 2014 Plants and other organisms use a process called photosynthesis to produce...

  9. Precision X-ray spectroscopy of 3C 273 jet knots

    E-Print Network [OSTI]

    Avara, Mark J

    2008-01-01T23:59:59.000Z

    We present results from precision X-ray spectroscopy using high-resolution ([delta lambda] = 0.01A) spectra of 3C 273 jet knots extracted from eight observations made using Chandra in conjunction with the HETGS. Using these ...

  10. Soft x-ray emission spectroscopy studies of the electronic structure of silicon supersaturated with sulfur

    E-Print Network [OSTI]

    Sullivan, Joseph Timothy

    We apply soft x-ray emission spectroscopy (XES) to measure the electronic structure of crystalline silicon supersaturated with sulfur (up to 0.7 at. %), a candidate intermediate-band solar cell material. Si L[subscript ...

  11. THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED BY MO K-EDGE X-RAY ABSORPTION

    E-Print Network [OSTI]

    Sheffield, University of

    THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED of molybdenum in model UK high level nuclear waste glasses was investigated by X-ray Absorption Spectroscopy (XAS). Molybdenum K-edge XAS data were acquired from several inactive simulant high level nuclear waste

  12. A microsecond time resolved x-ray absorption near edge structure synchrotron study of phase transitions in Fe undergoing ramp heating at high pressure

    SciTech Connect (OSTI)

    Marini, C.; Mathon, O.; Pascarelli, S. [European Synchrotron Radiation Facility, 6 Rue Jules Horowitz, BP220, 38043 Grenoble Cedex (France); Occelli, F.; Torchio, R.; Recoules, V.; Loubeyre, P. [CEA, Bruyeres le Chatel, 91297 Arpajon Cedex (France)

    2014-03-07T23:59:59.000Z

    We report a microsecond time-resolved x-ray absorption near edge structure study using synchrotron radiation to dynamically detect structural phase transitions in Fe undergoing rapid heating along a quasi-isochoric path. Within a few ms, we observed two structural phase transitions, which transform the ambient bcc phase of Fe into the fcc phase, and then into the liquid phase. This example illustrates the opportunities offered by energy dispersive x-ray absorption spectroscopy in the study of matter under extreme dynamic conditions. Advanced simulations are compared to these data.

  13. Using in situ X-ray absorption spectroscopy to study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}}

    SciTech Connect (OSTI)

    Itoh, Takanori, E-mail: tknitoh@seimichemical.co.jp [AGC SeimiChemical Co., Ltd., 3-2-10 Chigasaki, Chigasaki City, Kanagawa 253-8585 (Japan); Nakayama, Masanobu [Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya-city, Aichi 466-8555 (Japan)

    2012-08-15T23:59:59.000Z

    To study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF) as a function of the oxygen partial pressure (P(O{sub 2})), in situ the Co and Fe K-edge X-ray absorption spectroscopy (XAS) was measured at elevated temperatures of 900 and 1000 K. The reduction of the Co and Fe valence, i.e., the oxygen content (3-{delta}) in LSCF, followed the change of P(O{sub 2}) from 1 to 10{sup -4} atm during{approx}4000 s. The quantitative analysis of the X-ray absorption near edge structure (XANES) and the extended X-ray absorption fine structure (EXAFS) indicated that the Fe valence was higher than the Co valence at oxidative condition ({delta} Almost-Equal-To 0) in LSCF. Whereas the Co valence decreased more than the Fe valence after reduction of P(O{sub 2}) at both 900 and 1000 K. From the relaxation plots of the valence and the oxygen content (3-{delta}) for Co and Fe after changing P(O{sub 2}), we successfully determined D{sub chem} and E{sub a} of an oxygen ion migration around Co and Fe in LSCF. A structural model with and without oxygen vacancies and an oxygen ion conduction mechanism for LSCF are proposed based on these results. - Graphical abstract: A structural model with and without oxygen vacancies, and the oxygen ion conduction mechanism of LSCF were speculated. In other words, oxygen vacancies would form more preferentially around Co than Fe from the results of in situ XAS analysis during reduction, and oxygen ions needs to pass through at the vicinity of Fe from the results of D{sub chem} and E{sub a}. Highlights: Black-Right-Pointing-Pointer Study of the oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF). Black-Right-Pointing-Pointer Using in situ X-ray absorption for study of valence and oxygen diffusion coefficient. Black-Right-Pointing-Pointer The oxygen vacancies should be preferentially localized around Co in LSCF. Black-Right-Pointing-Pointer The values of the dynamics parameters for Co and Fe are close to each other.

  14. Double core-hole spectroscopy of transient plasmas produced in the interaction of ultraintense x-ray pulses with neon

    E-Print Network [OSTI]

    Gao, Cheng; Yuan, Jianmin

    2015-01-01T23:59:59.000Z

    Double core-hole (DCH) spectroscopy is investigated systematically for neon atomic system in the interaction with ultraintense x-ray pulses with photon energy from 937 eV to 2000 eV. A time-dependent rate equation, implemented in the detailed level accounting approximation, is utilized to study the dynamical evolution of the level population and emission properties of the highly transient plasmas. For x-ray pulses with photon energy in the range of 937-1030 eV, where $1s\\rightarrow 2p$ resonance absorption from single core-hole (SCH) states of neon charge states exist, inner-shell resonant absorption (IRA) effects play important roles in the time evolution of population and DCH spectroscopy. Such IRA physical effects are illustrated in detail by investigating the interaction of x-ray pulses at a photon energy of 944 eV, which corresponds to the $1s\\rightarrow 2p$ resonant absorption from the SCH states ($1s2s^22p^4$, $1s2s2p^5$ and $1s2p^6$) of Ne$^{3+}$. After averaging over the space and time distribution o...

  15. Confirmation of X-ray Absorption by Warm-hot Intergalactic Medium in the Sculptor Wall

    E-Print Network [OSTI]

    Fang, Taotao

    In a previous paper, we reported a 3? detection of an absorption line from the warm-hot intergalactic medium (WHIM) using the Chandra and XMM X-ray grating spectra of the blazar H2356-309, the sight line of which intercepts ...

  16. Femtosecond Xray Absorption Spectroscopy at a Hard Xray Free Electron Laser: Application to Spin Crossover Dynamics

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    Femtosecond Xray Absorption Spectroscopy at a Hard Xray Free Electron Laser: Application to Spin Rennes 1, F35042, Rennes, France ABSTRACT: X-ray free electron lasers (XFELs) deliver short ( operated in femtosecond laser slicing mode15 ). The development of new X-ray facilities such as X-ray free

  17. Probing reaction dynamics of transition-metal complexes in solution via time-resolved soft x-ray spectroscopy

    SciTech Connect (OSTI)

    Huse, N.; Kim, T.-K.; Khalil, M.; Jamula, L.; McCusker, J.K.; Schoenlein, R.W.

    2008-08-01T23:59:59.000Z

    We report the first time-resolved soft x-ray measurements of solvated transition-metal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding. We report the first time-resolved soft x-ray spectroscopy of solution-phase molecular dynamics. Changes in ligand-field splitting and spin-state populations in 3d orbitals of the Fe{sup II} complex are directly probed via transient absorption changes of the Fe L{sub 2} and L{sub 3} edges following photo-induced metal-to-ligand charge transfer. With the emergence of high-flux ultrafast soft x-ray sources, details on interplay between atomic structure, electronic states, and spin contributions will be revealed. Our experimental approach opens the door to femtosecond soft x-ray investigations of liquid phase chemistry that have previously been inaccessible.

  18. Observing heme doming in myoglobin with femtosecond X-ray absorption spectroscopya)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Levantino, M.; Lemke, H. T.; Schirò, G.; Glownia, M.; Cupane, A.; Cammarata, M.

    2015-07-01T23:59:59.000Z

    We report time-resolved X-ray absorption measurements after photolysis of carbonmonoxy myoglobin performed at the LCLS X-ray free electron laser with nearly 100 fs (FWHM) time resolution. Data at the Fe K-edge reveal that the photoinduced structural changes at the heme occur in two steps, with a faster (~70 fs) relaxation preceding a slower (~400 fs) one. We tentatively attribute the first relaxation to a structural rearrangement induced by photolysis involving essentially only the heme chromophore and the second relaxation to a residual Fe motion out of the heme plane that is coupled to the displacement of myoglobin F-helix.

  19. X-ray absorption in GaGdN: A study of local structure

    SciTech Connect (OSTI)

    Martinez-Criado, G.; Sans, J. A.; Susini, J. [Experiments Division, European Synchrotron Radiation Facility, 38043-Grenoble (France); Sancho-Juan, O.; Cantarero, A. [Institut de Ciencia dels Materials, Universitat de Valencia, P.O. Box 22085, 46071-Valencia (Spain); Garro, N. [Institut de Ciencia dels Materials, Universitat de Valencia, P.O. Box 22085, 46071-Valencia (Spain); Fundacio General de la Universitat de Valencia, P.O. Box 22085, 46071-Valencia (Spain); Roever, M.; Mai, D.-D.; Bedoya-Pinto, A.; Malindretos, J.; Rizzi, A. [IV. Physikalisches Institut and Virtual Institute of Spin Electronics (VISel), Georg-August Universitaet Goettingen, D-37077 Goettingen (Germany)

    2008-07-14T23:59:59.000Z

    In this study, we report on the incorporation of dilute Gd amounts into GaN films grown by molecular beam epitaxy. A combination of x-ray fluorescence with x-ray absorption spectroscopic techniques enabled us to examine not only the distribution of rare earth atoms in the GaN matrix but also the short-range structural order. Our results show Gd atoms in a trivalent state with tetrahedral coordination, thus substituting Ga in the wurtzite GaN structure.

  20. X-RAY EMISSION AND ABSORPTION FEATURES DURING AN ENERGETIC THERMONUCLEAR X-RAY BURST FROM IGR J17062-6143

    SciTech Connect (OSTI)

    Degenaar, N.; Miller, J. M. [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); Wijnands, R.; Altamirano, D. [Astronomical Institute ''Anton Pannekoek'', University of Amsterdam, Postbus 94249, 1090 GE Amsterdam (Netherlands); Fabian, A. C., E-mail: degenaar@umich.edu [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 OHA (United Kingdom)

    2013-04-20T23:59:59.000Z

    Type-I X-ray bursts are thermonuclear explosions occurring in the surface layers of accreting neutron stars. These events are powerful probes of the physics of neutron stars and their surrounding accretion flow. We analyze a very energetic type-I X-ray burst from the neutron star low-mass X-ray binary IGR J17062-6143 that was detected with Swift on 2012 June 25. The light curve of the {approx_equal}18 minute long X-ray burst tail shows an episode of {approx_equal}10 minutes during which the intensity is strongly fluctuating by a factor of {approx_equal}3 above and below the underlying decay trend on a timescale of seconds. The X-ray spectrum reveals a highly significant emission line around {approx_equal}1 keV, which can be interpreted as an Fe-L shell line caused by the irradiation of cold gas. We also detect significant absorption lines and edges in the Fe-K band, which are strongly suggestive of the presence of hot, highly ionized gas along the line of sight. None of these features are present in the persistent X-ray spectrum of the source. The timescale of the strong intensity variations, the velocity width of the Fe-L emission line (assuming Keplerian motion), and photoionization modeling of the Fe-K absorption features each independently point to gas at a radius of {approx_equal} 10{sup 3} km as the source of these features. The unusual X-ray light curve and spectral properties could have plausibly been caused by a disruption of the accretion disk due to the super-Eddington fluxes reached during the X-ray burst.

  1. Dynamics in shear flow studied by X-ray Photon Correlation Spectroscopy

    E-Print Network [OSTI]

    Sebastian Busch; Torben Haugaard Jensen; Yuriy Chushkin; Andrei Fluerasu

    2008-03-19T23:59:59.000Z

    X-ray photon correlation spectroscopy was used to measure the diffusive dynamics of colloidal particles in a shear flow. The results presented here show how the intensity autocorrelation functions measure both the diffusive dynamics of the particles and their flow-induced, convective motion. However, in the limit of low flow/shear rates, it is possible to obtain the diffusive component of the dynamics, which makes the method suitable for the study of the dynamical properties of a large class of complex soft-matter and biological fluids. An important benefit of this experimental strategy over more traditional X-ray methods is the minimization of X-ray induced beam damage. While the method can be applied also for photon correlation spectroscopy in the visible domain, our analysis shows that the experimental conditions under which it is possible to measure the diffusive dynamics are easier to achieve at higher q values (with X-rays).

  2. Ultraviolet/X-ray variability and the extended X-ray emission of the radio-loud broad absorption line quasar PG 1004+130

    E-Print Network [OSTI]

    Scott, A E; Miller, B P; Luo, B; Gallagher, S C

    2015-01-01T23:59:59.000Z

    We present the results of recent Chandra, XMM-Newton, and Hubble Space Telescope observations of the radio-loud (RL), broad absorption line (BAL) quasar PG 1004+130. We compare our new observations to archival X-ray and UV data, creating the most comprehensive, high signal-to-noise, multi-epoch, spectral monitoring campaign of a RL BAL quasar to date. We probe for variability of the X-ray absorption, the UV BAL, and the X-ray jet, on month-year timescales. The X-ray absorber has a low column density of $N_{H}=8\\times10^{20}-4\\times10^{21}$ cm$^{-2}$ when it is assumed to be fully covering the X-ray emitting region, and its properties do not vary significantly between the 4 observations. This suggests the observed absorption is not related to the typical "shielding gas" commonly invoked in BAL quasar models, but is likely due to material further from the central black hole. In contrast, the CIV BAL shows strong variability. The equivalent width (EW) in 2014 is EW=11.24$\\pm$0.56 \\AA, showing a fractional increa...

  3. X-ray absorption fine structure spectroscopic study of uranium nitrides

    SciTech Connect (OSTI)

    Poineau, Frederic [University of Nevada, Las Vegas; Yeamans, Charles B. [University of California, Berkeley; Cerefice, Gary S. [University of Nevada, Las Vegas; Sattelberger, Alfred P [Argonne National Laboratory (ANL); Czerwinski, Ken R. [University of Nevada, Las Vegas

    2012-01-01T23:59:59.000Z

    Uranium mononitride (UN), sesquinitride (U2N3) and dinitride (UN2) were characterized by extended X-Ray absorption fine structure spectroscopy. Analysis on UN indicate the presence of three uranium shells at distances of 3.46(3), 4.89(5) and 6.01(6) A and a nitrogen shell at a distance of 2.46(2) A . For U2N3, two absorbing uranium atoms at different crystallographic positions are present in the structure. One of the uranium atoms is surrounded by nitrogen atoms at 2.28(2) A and by uranium atoms at 3.66(4) and 3.95(4) A . The second type of uranium atom is surrounded by nitrogen atoms at 2.33(2) and 2.64(3) A and by uranium atoms at 3.66(4), 3.95(4) and 5.31(5) A . Results on UN2 indicate two uranium shells at 3.71(4) and 5.32(5) A and two nitrogen shells at 2.28(2).

  4. X-ray spectroscopy of gamma-ray bursts: the path to the progenitor

    E-Print Network [OSTI]

    Davide Lazzati; Rosalba Perna; Gabriele Ghisellini

    2002-01-17T23:59:59.000Z

    Despite great observational and theoretical effort, the burst progenitor is still a mysterious object. It is generally accepted that one of the best ways to unveil its nature is the study of the properties of the close environment in which the explosion takes place. We discuss the potentiality and feasibility of time resolved X-ray spectroscopy, focusing on the prompt gamma-ray phase. We show that the study of absorption features (or continuum absorption) can reveal the radial structure of the close environment, unaccessible with different techniques. We discuss the detection of absorption in the prompt and afterglow spectra of several bursts, showing how these are consistent with gamma-ray bursts taking place in dense regions. In particular, we show that the radius and density of the surrounding cloud can be measured through the evolution of the column density in the prompt burst phase. The derived cloud properties are similar to those of the star forming cocoons and globules within molecular clouds. We conclude that the burst are likely associated with the final evolutionary stages of massive stars.

  5. THE CHANDRA MULTI-WAVELENGTH PROJECT: OPTICAL SPECTROSCOPY AND THE BROADBAND SPECTRAL ENERGY DISTRIBUTIONS OF X-RAY-SELECTED AGNs

    SciTech Connect (OSTI)

    Trichas, Markos; Green, Paul J.; Aldcroft, Tom; Kim, Dong-Woo; Mossman, Amy [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138 (United States); Silverman, John D. [Institute for the Physics and Mathematics of the Universe (IPMU), University of Tokyo, Kashiwanoha 5-1-5, Kashiwa-shi, Chiba 277-8568 (Japan); Barkhouse, Wayne [Department of Physics and Astrophysics, University of North Dakota, Grand Forks, ND 58202 (United States); Cameron, Robert A. [W. W. Hansen Experimental Physics Laboratory, Kavli Institute for Particle Astrophysics and Cosmology, Department of Physics and SLAC National Accelerator Laboratory, Stanford University, Stanford, CA 94305 (United States); Constantin, Anca [Department of Physics and Astronomy, James Madison University, PHCH, Harrisonburg, VA 22807 (United States); Ellison, Sara L. [Department of Physics and Astronomy, University of Victoria, Victoria, BC V8P 1A1 (Canada); Foltz, Craig [Division of Astronomical Sciences, National Science Foundation, 4201 Wilson Blvd., Arlington, VA 22230 (United States); Haggard, Daryl [Center for Interdisciplinary Exploration and Research in Astrophysics, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (United States); Jannuzi, Buell T. [NOAO, Kitt Peak National Observatory, Tucson, AZ 85726 (United States); Marshall, Herman L. [Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139 (United States); Perez, Laura M. [Department of Astronomy, California Institute of Technology, 1200 East California Blvd, Pasadena, CA 91125 (United States); Romero-Colmenero, Encarni [South African Astronomical Observatory, P.O. Box 9, Observatory, 7935 (South Africa); Ruiz, Angel [Osservatorio Astronomico di Brera-INAF, Milan (Italy); Smith, Malcolm G., E-mail: mtrichas@cfa.harvard.edu [Cerro Tololo Interamerican Observatory, La Serena (Chile); and others

    2012-06-01T23:59:59.000Z

    From optical spectroscopy of X-ray sources observed as part of the Chandra Multi-wavelength Project (ChaMP), we present redshifts and classifications for a total of 1569 Chandra sources from our targeted spectroscopic follow-up using the FLWO/1.5 m, SAAO/1.9 m, WIYN 3.5 m, CTIO/4 m, KPNO/4 m, Magellan/6.5 m, MMT/6.5 m, and Gemini/8 m telescopes, and from archival Sloan Digital Sky Survey (SDSS) spectroscopy. We classify the optical counterparts as 50% broad-line active galactic nuclei (AGNs), 16% emission line galaxies, 14% absorption line galaxies, and 20% stars. We detect QSOs out to z {approx} 5.5 and galaxies out to z {approx} 3. We have compiled extensive photometry, including X-ray (ChaMP), ultraviolet (GALEX), optical (SDSS and ChaMP-NOAO/MOSAIC follow-up), near-infrared (UKIDSS, Two Micron All Sky Survey, and ChaMP-CTIO/ISPI follow-up), mid-infrared (WISE), and radio (FIRST and NVSS) bands. Together with our spectroscopic information, this enables us to derive detailed spectral energy distributions (SEDs) for our extragalactic sources. We fit a variety of template SEDs to determine bolometric luminosities, and to constrain AGNs and starburst components where both are present. While {approx}58% of X-ray Seyferts (10{sup 42} erg s{sup -1} < L{sub 2-10keV} <10{sup 44} erg s{sup -1}) require a starburst event (>5% starburst contribution to bolometric luminosity) to fit observed photometry only 26% of the X-ray QSO (L{sub 2-10keV} >10{sup 44} erg s{sup -1}) population appear to have some kind of star formation contribution. This is significantly lower than for the Seyferts, especially if we take into account torus contamination at z > 1 where the majority of our X-ray QSOs lie. In addition, we observe a rapid drop of the percentage of starburst contribution as X-ray luminosity increases. This is consistent with the quenching of star formation by powerful QSOs, as predicted by the merger model, or with a time lag between the peak of star formation and QSO activity. We have tested the hypothesis that there should be a strong connection between X-ray obscuration and star formation but we do not find any association between X-ray column density and star formation rate both in the general population or the star-forming X-ray Seyferts. Our large compilation also allows us to report here the identification of 81 X-ray Bright Optically inactive Galaxies, 78 z > 3 X-ray sources, and eight Type-2 QSO candidates. Also, we have identified the highest redshift (z = 5.4135) X-ray-selected QSO with optical spectroscopy.

  6. X-ray spectroscopy of the supernova remnant RCW 86

    E-Print Network [OSTI]

    Jacco Vink; Jelle Kaastra; Johan Bleeker

    1997-09-12T23:59:59.000Z

    We present an analysis of ASCA X-ray data of SNR RCW 86. There appears to be a remarkable spectral variation over the remnant, indicating temperatures varying from 0.8 keV to > 3 keV. We have fitted these spectra with non-equilibrium ionization models and found that all regions are best fitted by emission from a hot plasma underabundant in metals (<0.25 solar), but in some cases fluorescent emission indicates overabundances of Ar and Fe. The ionization stage of the metals appears to be far from equilibrium, at some spots as low as log(n_e t) 15.3 (SI units). We discuss the physical reality of the abundances and suggest an electron distribution with a supra-thermal tail to alleviate the strong depletion factors observed. We argue that RCW 86 is the result of a cavity explosion.

  7. X-ray Spectroscopy for Quality Control of Chemotherapy Drugs

    SciTech Connect (OSTI)

    Greaves, E. D.; Barros, H.; Bermudez, J.; Sajo-Bohus, L. [Universidad Simon Bolivar, Apartado 89000, Caracas 1080A (Venezuela); Angeli-Greaves, M. [Universidad Central de Venezuela, Apartado 90373 Caracas 1083A (Venezuela)

    2007-10-26T23:59:59.000Z

    We develop a method, employing Compton peak standardization and the use of matrix-matched spiked samples with Total Reflection X-ray Fluorescence (TXRF), for the determination of platinum plasma concentrations of patients undergoing chemotherapy with Pt-bearing drugs. Direct blood plasma analysis attains Pt detection limits of 70 ng/ml. Measurement results of prescribed drug doses are compared to achieved blood Pt concentrations indicating a lack of expected correlations. Direct analysis of Pt-containing infused drugs from a variety of suppliers indicates cases of abnormal concentrations which raises quality control issues. We demonstrate the potential usefulness of the method for pharmacokinetic studies or for routine optimization and quality control of Pt chemotherapy treatments.

  8. Solution spectroelectrochemical cell for in situ X-ray absorption fine structure

    SciTech Connect (OSTI)

    Antonio, M.R.; Soderholm, L. [Argonne National Lab., IL (United States). Chemistry Div.; Song, I. [Case Western Reserve Univ., Cleveland, OH (United States)

    1995-06-12T23:59:59.000Z

    A purpose-built spectroelectrochemical cell for in situ fluorescence XAFS (X-ray Absorption Fine Structure) measurements of bulk solution species during constant-potential electrolysis is described. The cell performance was demonstrated by the collection of europium L{sub 3}-edge XANES (X-ray Absorption Near Edge Structure) throughout the course of electrolysis of an aqueous solution of EuCl{sub 3}{center_dot}6H{sub 2}O in 1 M H{sub 2}SO{sub 4}. The europium L{sub 3}-edge resonances reported here for the Eu{sup III} and Eu{sup II} ions demonstrate that their 2p{sub 3/2} {yields} 5d electronic transition probabilities are not the same.

  9. X-ray absorption fine structure spectroscopic determination of plutonium speciation at the Rocky Flats environmental technology

    SciTech Connect (OSTI)

    Lezama-pacheco, Juan S [Los Alamos National Laboratory; Conradson, Steven D [Los Alamos National Laboratory; Clark, David L [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    X-ray Absorption Fine Structure spectroscopy was used to probe the speciation of the ppm level Pu in thirteen soil and concrete samples from the Rocky Flats Environmental Technology Site in support of the site remediation effort that has been successfully completed since these measurements. In addition to X-ray Absorption Near Edge Spectra, two of the samples yielded Extended X-ray Absorption Fine Structure spectra that could be analyzed by curve-fits. Most of these spectra exhibited features consistent with PU(IV), and more specificaJly, PuO{sub 2+x}-type speciation. Two were ambiguous, possibly indicating that Pu that was originally present in a different form was transforming into PuO{sub 2+x}, and one was interpreted as demonstrating the presence of an unusual Pu(VI) compound, consistent with its source being spills from a PUREX purification line onto a concrete floor and the resultant extreme conditions. These experimental results therefore validated models that predicted that insoluble PuO{sub 2+x} would be the most stable form of Pu in equilibrium with air and water even when the source terms were most likely Pu metal with organic compounds or a Pu fire. A corollary of these models' predictions and other in situ observations is therefore that the minimal transport of Pu that occurred on the site was via the resuspension and mobilization of colloidal particles. Under these conditions, the small amounts of diffusely distributed Pu that were left on the site after its remediation pose only a negligible hazard.

  10. Mode-Locked Multichromatic X-Rays in a Seeded Free-Electron Laser for Single-Shot X-Ray Spectroscopy

    SciTech Connect (OSTI)

    Xiang, Dao; Ding, Yuantao; Raubenheimer, Tor; Wu, Juhao; /SLAC

    2012-05-10T23:59:59.000Z

    We present the promise of generating gigawatt mode-locked multichromatic x rays in a seeded free-electron laser (FEL). We show that, by using a laser to imprint periodic modulation in electron beam phase space, a single-frequency coherent seed can be amplified and further translated to a mode-locked multichromatic output in an FEL. With this configuration the FEL output consists of a train of mode-locked ultrashort pulses which span a wide frequency gap with a series of equally spaced sharp lines. These gigawatt multichromatic x rays may potentially allow one to explore the structure and dynamics of a large number of atomic states simultaneously. The feasibility of generating mode-locked x rays ranging from carbon K edge ({approx}284 eV) to copper L{sub 3} edge ({approx}931 eV) is confirmed with numerical simulation using the realistic parameters of the linac coherent light source (LCLS) and LCLS-II. We anticipate that the mode-locked multichromatic x rays in FELs may open up new opportunities in x-ray spectroscopy (i.e. resonant inelastic x-ray scattering, time-resolved scattering and spectroscopy, etc.).

  11. Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications

    SciTech Connect (OSTI)

    Khalid, S.; Caliebe, W.; Siddons, P.; So, I.; Clay, b.; Hanson, J.; Wang, Q.; Frenkel, A.; Marinkovicl, N.; Hould, N.; ginder-Vogel, M.; Landrot, G.L.; Sparks, D.L.; Ganjoo, A.

    2010-01-19T23:59:59.000Z

    In order to learn about in situ structural changes in materials at subseconds time scale, we have further refined the techniques of quick extended x-ray absorption fine structure (QEXAFS) and quick x-ray absorption near edge structure (XANES) spectroscopies at beamline X18B at the National Synchrotron Light Source. The channel cut Si (111) monochromator oscillation is driven through a tangential arm at 5 Hz, using a cam, dc motor, pulley, and belt system. The rubber belt between the motor and the cam damps the mechanical noise. EXAFS scan taken in 100 ms is comparable to standard data. The angle and the angular range of the monochromator can be changed to collect a full EXAFS or XANES spectrum in the energy range 4.7-40.0 KeV. The data are recorded in ascending and descending order of energy, on the fly, without any loss of beam time. The QEXAFS mechanical system is outside the vacuum system, and therefore changing the mode of operation from conventional to QEXAFS takes only a few minutes. This instrument allows the acquisition of time resolved data in a variety of systems relevant to electrochemical, photochemical, catalytic, materials, and environmental sciences.

  12. Missing cosmic metals revealed by X-ray absorption towards distant sources

    E-Print Network [OSTI]

    Campana, S; Ferrara, A; Pallottini, A

    2015-01-01T23:59:59.000Z

    The census of heavy elements (metals) produced by all stars through cosmic times up to present-day is limited to ~50%; of these only half are still found within their parent galaxy. The majority of metals is expelled from galaxies into the circumgalactic (or even more distant, intergalactic) space by powerful galactic winds, leaving unpleasant uncertainty on the amount, thermal properties and distribution of these key chemical species. These dispersed metals unavoidably absorb soft X-ray photons from distant sources. We show that their integrated contribution can be detected in the form of increasing X-ray absorption with distance, for all kinds of high-energy cosmic sources. Based on extensive cosmological simulations, we assess that $\\sim$ 10\\% of all cosmic metals reside in the intergalactic medium. Most of the X-ray absorption arises instead from a few discrete structures along the line of sight. These extended structures, possibly pin-pointing galaxy groups, contain million degree, metal-enriched gas, 10...

  13. Atmospheric Corrosion of Silver Investigated by X-ray Photoelectron Spectroscopy Dissertation

    E-Print Network [OSTI]

    Atmospheric Corrosion of Silver Investigated by X-ray Photoelectron Spectroscopy Dissertation Atmospheric corrosion is a costly problem. Accelerated laboratory tests, such as the salt fog chamber, have been created to predict corrosion of materials without the need to expose them over long periods

  14. In Situ Synchrotron X-ray Spectroscopy of Lanthanum Manganite Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Yildiz, Bilge

    . Introduction The solid oxide fuel cell (SOFC) has potential to produce energy with high efficiency, especiallyIn Situ Synchrotron X-ray Spectroscopy of Lanthanum Manganite Solid Oxide Fuel Cell Electrodes Kee fuel cells (SOFC) under long term cathodic or anodic polarization, termed `current conditioning

  15. Science Highlight March 2010 Schematic drawing of the setup for x-ray emission spectroscopy

    E-Print Network [OSTI]

    Wechsler, Risa H.

    foodstuffs for nutrition while recycling CO2 from the atmosphere and replacing it with O2. By utilizingScience Highlight ­ March 2010 Schematic drawing of the setup for x-ray emission spectroscopy of complex aerobic life. Coupled to the reduction of carbon dioxide, biological photosynthesis contrib- utes

  16. HIV-1 Tat membrane interactions probed using X-ray and neutron scattering, CD spectroscopy and MD simulations

    E-Print Network [OSTI]

    Nagle, John F.

    HIV-1 Tat membrane interactions probed using X-ray and neutron scattering, CD spectroscopy and MD translocation, were provided by wide-angle X-ray scattering (WAXS) and neutron scattering. CD spectroscopy for Neutron Research, 100 Bureau Drive, Stop 6102, Gaithersburg, MD 20899, United States d CHESS, Cornell

  17. Two-dimensional stimulated resonance Raman spectroscopy of molecules with broadband x-ray pulses

    SciTech Connect (OSTI)

    Biggs, Jason D.; Zhang Yu; Healion, Daniel; Mukamel, Shaul [Department of Chemistry, University of California, Irvine, California 92697-2025 (United States)

    2012-05-07T23:59:59.000Z

    Expressions for the two-dimensional stimulated x-ray Raman spectroscopy (2D-SXRS) signal obtained using attosecond x-ray pulses are derived. The 1D- and 2D-SXRS signals are calculated for trans-N-methyl acetamide (NMA) with broad bandwidth (181 as, 14.2 eV FWHM) pulses tuned to the oxygen and nitrogen K-edges. Crosspeaks in 2D signals reveal electronic Franck-Condon overlaps between valence orbitals and relaxed orbitals in the presence of the core-hole.

  18. X-RAY ABSORPTION ANALYSIS OF NGC 3516: APPEARANCE OF FAST COMPONENTS WITH INCREASED SOURCE FLUX

    SciTech Connect (OSTI)

    Holczer, Tomer; Behar, Ehud, E-mail: tomer@physics.technion.ac.il, E-mail: behar@physics.technion.ac.il [Department of Physics, Technion, Haifa 32000 (Israel)

    2012-03-01T23:59:59.000Z

    By analyzing the X-ray spectra of NGC 3516 from 2001 and 2006 obtained with the HETGS spectrometer on board the Chandra X-ray Observatory, we find that the kinematic structure of the outflow can be well represented by four outflow components intrinsic to NGC 3516: -350 {+-} 100 km s{sup -1}, -1500 {+-} 150 km s{sup -1}, -2600 {+-} 200 km s{sup -1}, and -4000 {+-} 400 km s{sup -1}. A local component at z = 0 could be confused in the spectrum with intrinsic component 3. Components 1 and 2 have a broad range of ionization manifested by absorption from 23 different charge states of Fe. Components 3 and 4 are more highly ionized and show absorption from only nine different charge states of Fe. However, we were able to reconstruct the absorption measure distribution for all four. The total column density of each component is N{sub H} = (1.8 {+-} 0.5) Multiplication-Sign 10{sup 22} cm{sup -2}, (2.5 {+-} 0.3) Multiplication-Sign 10{sup 22} cm{sup -2}, (6.9 {+-} 4.3) Multiplication-Sign 10{sup 22} cm{sup -2}, and (5.4 {+-} 1.2) Multiplication-Sign 10{sup 22} cm{sup -2}, respectively. The fast components 3 and 4 appear only in the high state of 2006 and not in 2001, while the slower components persist during both epochs. On the other hand, there is no significant absorption variability within days during 2001 or 2006. We find that the covering factor plays a minor role for the line absorption.

  19. A wavelet analysis for the X-ray absorption spectra of molecules

    SciTech Connect (OSTI)

    Penfold, T. J. [Ecole polytechnique Federale de Lausanne, Laboratoire de spectroscopie ultrarapide, ISIC, FSB-BSP, CH-1015 Lausanne (Switzerland); Ecole polytechnique Federale de Lausanne, Laboratoire de chimie et biochimie computationnelles, ISIC, FSB-BCH, CH-1015 Lausanne (Switzerland); SwissFEL, Paul Scherrer Inst, CH-5232 Villigen (Switzerland); Tavernelli, I.; Rothlisberger, U. [Ecole polytechnique Federale de Lausanne, Laboratoire de chimie et biochimie computationnelles, ISIC, FSB-BCH, CH-1015 Lausanne (Switzerland); Milne, C. J.; Abela, R. [SwissFEL, Paul Scherrer Inst, CH-5232 Villigen (Switzerland); Reinhard, M.; Nahhas, A. El; Chergui, M. [Ecole polytechnique Federale de Lausanne, Laboratoire de spectroscopie ultrarapide, ISIC, FSB-BSP, CH-1015 Lausanne (Switzerland)

    2013-01-07T23:59:59.000Z

    We present a Wavelet transform analysis for the X-ray absorption spectra of molecules. In contrast to the traditionally used Fourier transform approach, this analysis yields a 2D correlation plot in both R- and k-space. As a consequence, it is possible to distinguish between different scattering pathways at the same distance from the absorbing atom and between the contributions of single and multiple scattering events, making an unambiguous assignment of the fine structure oscillations for complex systems possible. We apply this to two previously studied transition metal complexes, namely iron hexacyanide in both its ferric and ferrous form, and a rhenium diimine complex, [ReX(CO){sub 3}(bpy)], where X = Br, Cl, or ethyl pyridine (Etpy). Our results demonstrate the potential advantages of using this approach and they highlight the importance of multiple scattering, and specifically the focusing phenomenon to the extended X-ray absorption fine structure (EXAFS) spectra of these complexes. We also shed light on the low sensitivity of the EXAFS spectrum to the Re-X scattering pathway.

  20. Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy

    SciTech Connect (OSTI)

    Huse, Nils; Wen, Haidan; Nordlund, Dennis; Szilagyi, Erzsi; Daranciang, Dan; Miller, Timothy A.; Nilsson, Anders; Schoenlein, Robert W.; Lindenberg, Aaron M.

    2009-04-24T23:59:59.000Z

    We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O-H stretch mode at 3 mu m, probed via soft x-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft x-ray spectroscopy in liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8MPa, is manifest by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

  1. THE CHANDRA MULTI-WAVELENGTH PROJECT: OPTICAL SPECTROSCOPY AND THE BROADBAND SPECTRAL ENERGY DISTRIBUTIONS OF X-RAY-SELECTED AGNs

    E-Print Network [OSTI]

    Trichas, Markos

    From optical spectroscopy of X-ray sources observed as part of the Chandra Multi-wavelength Project (ChaMP), we present redshifts and classifications for a total of 1569 Chandra sources from our targeted spectroscopic ...

  2. Double-core excitations in formamide can be probed by X-ray double-quantum-coherence spectroscopy

    E-Print Network [OSTI]

    Mukamel, Shaul

    Yu Zhang, Daniel Healion, Jason D. Biggs, and Shaul Mukamel Citation: J. Chem. Phys. 138, 144301 be probed by X-ray double-quantum-coherence spectroscopy Yu Zhang, Daniel Healion, Jason D. Biggs, and Shaul

  3. X-ray photon correlation spectroscopy studies of the dynamics of self-assembling block copolymer structures

    E-Print Network [OSTI]

    Falus, Péter, 1972-

    2004-01-01T23:59:59.000Z

    Several improvements presented to the emerging technique of X-ray Photon Correlation Spectroscopy. These improvements enabled the study of polymer structures, in particular isotropic sponge phases of homo-polymer block ...

  4. absorption spectroscopy xas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy xas First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Time Resolved X-Ray...

  5. atomic absorption spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atomic absorption spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Transient x-ray...

  6. In situ synchrotron based x-ray techniques as monitoring tools for atomic layer deposition

    SciTech Connect (OSTI)

    Devloo-Casier, Kilian, E-mail: Kilian.DevlooCasier@Ugent.be; Detavernier, Christophe; Dendooven, Jolien [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Ghent (Belgium); Ludwig, Karl F. [Physics Department, Boston University, 590 Commonwealth Avenue, Boston, Massachusetts 02215 (United States)

    2014-01-15T23:59:59.000Z

    Atomic layer deposition (ALD) is a thin film deposition technique that has been studied with a variety of in situ techniques. By exploiting the high photon flux and energy tunability of synchrotron based x-rays, a variety of new in situ techniques become available. X-ray reflectivity, grazing incidence small angle x-ray scattering, x-ray diffraction, x-ray fluorescence, x-ray absorption spectroscopy, and x-ray photoelectron spectroscopy are reviewed as possible in situ techniques during ALD. All these techniques are especially sensitive to changes on the (sub-)nanometer scale, allowing a unique insight into different aspects of the ALD growth mechanisms.

  7. Stratified Quasar Winds: Integrating X-ray and Infrared Views of Broad Absorption Line Quasars

    E-Print Network [OSTI]

    S. C. Gallagher; J. E. Everett

    2007-02-07T23:59:59.000Z

    Quasars are notable for the luminous power they emit across decades in frequency from the far-infrared through hard X-rays; emission at different frequencies emerges from physical scales ranging from AUs to parsecs. Each wavelength regime thus offers a different line of sight into the central engine and a separate probe of outflowing material. Therefore, obtaining a complete accounting of the physical characteristics and kinetic power of quasar winds requires a panchromatic approach. X-ray and infrared studies are particularly powerful for covering the range of interesting physical scales and ionization states of the outflow. We present a stratified wind picture based on a synthesis of multiwavelength research programs designed to constrain the nature of mass ejection from radio-quiet quasars. This wind comprises three zones: the highly ionized shielding gas, the UV broad absorption line wind, and the cold dusty outflow. The primary launching mechanism for the wind likely varies in each zone. While radiative acceleration on resonance lines dominates for the UV absorbing wind, the shielding gas may instead be driven by magnetic forces. Ultraviolet continuum radiative pressure, perhaps coupled with magnetic launching, accelerates a dusty outflow that obscures the inner broad line region in unification schemes.

  8. In situ x-ray photoelectron spectroscopy for electrochemical reactions in ordinary solvents

    SciTech Connect (OSTI)

    Masuda, Takuya [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan) [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan); PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 333-0012 (Japan); Yoshikawa, Hideki; Kobata, Masaaki; Kobayashi, Keisuke [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), Sayo, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), Sayo, Hyogo 679-5148 (Japan); Noguchi, Hidenori [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan) [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan); PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 333-0012 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044 (Japan); Kawasaki, Tadahiro [Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603 (Japan)] [Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603 (Japan); Uosaki, Kohei [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan) [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044 (Japan)

    2013-09-09T23:59:59.000Z

    In situ electrochemical X-ray photoelectron spectroscopy (XPS) apparatus, which allows XPS at solid/liquid interfaces under potential control, was constructed utilizing a microcell with an ultra-thin Si membrane, which separates vacuum and a solution. Hard X-rays from a synchrotron source penetrate into the Si membrane surface exposed to the solution. Electrons emitted at the Si/solution interface can pass through the membrane and be analyzed by an analyzer placed in vacuum. Its operation was demonstrated for potential-induced Si oxide growth in water. Effect of potential and time on the thickness of Si and Si oxide layers was quantitatively determined at sub-nanometer resolution.

  9. X-ray photoelectron spectroscopy of gallium nitride films grown by radical-beam gettering epitaxy

    SciTech Connect (OSTI)

    Rogozin, I. V. [Berdyansk State Pedagogical University (Ukraine)], E-mail: rogozin@bdpu.org; Kotlyarevsky, M. B. [Academy of Management and Information Technology (Ukraine)

    2007-05-15T23:59:59.000Z

    Thin GaN films were grown on GaAs(111) substrates by radical-beam gettering epitaxy. The structural quality of the films was studied by high-resolution x-ray diffraction. The chemical composition of the GaAs surface and GaN film was studied by x-ray photoelectron spectroscopy. It is shown that Ga-N and As-N bonds are formed on the GaAs surface at initial growth stages at low temperatures. The state of the film-substrate interface was studied. It was found that prolonged annealing of GaN films in nitrogen radicals shifts the composition to nitrogen excess.

  10. Electronic Properties of Hydrogen Storage Materials with Photon-in/Photon-out Soft-X-Ray Spectroscopy

    SciTech Connect (OSTI)

    Guo, Jinghua

    2008-09-22T23:59:59.000Z

    The applications of resonant soft X-ray emission spectroscopy on a variety of carbon systems have yielded characteristic fingerprints. With high-resolution monochromatized synchrotron radiation excitation, resonant inelastic X-ray scattering has emerged as a new source of information about electronic structure and excitation dynamics. Photon-in/photon-out soft-X-ray spectroscopy is used to study the electronic properties of fundamental materials, nanostructure, and complex hydrides and will offer potential in-depth understanding of chemisorption and/or physisorption mechanisms of hydrogen adsorption/desorption capacity and kinetics.

  11. X-ray absorption signatures of the molecular environment in water and ice

    E-Print Network [OSTI]

    Wei Chen; Xifan Wu; Roberto Car

    2009-09-21T23:59:59.000Z

    The x-ray absorption spectra of water and ice are calculated with a many-body approach for electron-hole excitations. The experimental features, including the small effects of temperature change in the liquid, are quantitatively reproduced from molecular configurations generated by ab-initio molecular dynamics. The spectral difference between the solid and the liquid is due to two major short range order effects. One, due to breaking of hydrogen bonds, enhances the pre-edge intensity in the liquid. The other, due to a non-bonded molecular fraction in the first coordination shell, affects the main spectral edge in the conversion of ice to water. This effect may not involve hydrogen bond breaking as shown by experiment in high-density amorphous ice.

  12. HELIUM IN NATAL H II REGIONS: THE ORIGIN OF THE X-RAY ABSORPTION IN GAMMA-RAY BURST AFTERGLOWS

    SciTech Connect (OSTI)

    Watson, Darach; Andersen, Anja C.; Fynbo, Johan P. U.; Hjorth, Jens; Kruehler, Thomas; Laursen, Peter; Leloudas, Giorgos; Malesani, Daniele [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen O (Denmark); Zafar, Tayyaba [Laboratoire d'Astrophysique de Marseille - LAM, Universite Aix-Marseille and CNRS, UMR 7326, 38 rue F. Joliot-Curie, F-13388, Marseille Cedex 13 (France); Gorosabel, Javier [Instituto de Astrofisica de Andalucia (IAA-CSIC), Glorieta de la Astronomia s/n, E-18008, Granada (Spain); Jakobsson, Pall, E-mail: darach@dark-cosmology.dk [Centre for Astrophysics and Cosmology, Science Institute, University of Iceland, Dunhagi 5, 107 Reykjavik (Iceland)

    2013-05-01T23:59:59.000Z

    Soft X-ray absorption in excess of Galactic is observed in the afterglows of most gamma-ray bursts (GRBs), but the correct solution to its origin has not been arrived at after more than a decade of work, preventing its use as a powerful diagnostic tool. We resolve this long-standing problem and find that absorption by He in the GRB's host H II region is responsible for most of the absorption. We show that the X-ray absorbing column density (N{sub H{sub X}}) is correlated with both the neutral gas column density and with the optical afterglow's dust extinction (A{sub V} ). This correlation explains the connection between dark bursts and bursts with high N{sub H{sub X}} values. From these correlations, we exclude an origin of the X-ray absorption which is not related to the host galaxy, i.e., the intergalactic medium or intervening absorbers are not responsible. We find that the correlation with the dust column has a strong redshift evolution, whereas the correlation with the neutral gas does not. From this, we conclude that the column density of the X-ray absorption is correlated with the total gas column density in the host galaxy rather than the metal column density, in spite of the fact that X-ray absorption is typically dominated by metals. The strong redshift evolution of N{sub H{sub X}}/A{sub V} is thus a reflection of the cosmic metallicity evolution of star-forming galaxies and we find it to be consistent with measurements of the redshift evolution of metallicities for GRB host galaxies. We conclude that the absorption of X-rays in GRB afterglows is caused by He in the H II region hosting the GRB. While dust is destroyed and metals are stripped of all of their electrons by the GRB to great distances, the abundance of He saturates the He-ionizing UV continuum much closer to the GRB, allowing it to remain in the neutral or singly-ionized state. Helium X-ray absorption explains the correlation with total gas, the lack of strong evolution with redshift, as well as the absence of dust, metal or hydrogen absorption features in the optical-UV spectra.

  13. Probing X-ray Absorption and Optical Extinction in the Interstellar Medium Using Chandra Observations of Supernova Remnants

    E-Print Network [OSTI]

    Foight, Dillon; Ozel, Feryal; Slane, Patrick

    2015-01-01T23:59:59.000Z

    We present a comprehensive study of interstellar X-ray extinction using the extensive Chandra supernova remnant archive and use our results to refine the empirical relation between the hydrogen column density and optical extinction. In our analysis, we make use of the large, uniform data sample to assess various systematic uncertainties in the measurement of the interstellar X-ray absorption. Specifically, we address systematic uncertainties that originate from (i) the emission models used to fit supernova remnant spectra, (ii) the spatial variations within individual remnants, (iii) the physical conditions of the remnant such as composition, temperature, and non-equilibrium regions, and (iv) the model used for the absorption of X-rays in the interstellar medium. Using a Bayesian framework to quantify these systematic uncertainties, and combining the resulting hydrogen column density measurements with the measurements of optical extinction toward the same remnants, we find the empirical relation NH = (2.87+/-...

  14. Hard x-ray emission spectroscopy: a powerful tool for the characterization of magnetic semiconductors

    E-Print Network [OSTI]

    Rovezzi, Mauro

    2014-01-01T23:59:59.000Z

    This review aims to introduce the x-ray emission spectroscopy (XES) and resonant inelastic x-ray scattering (RIXS) techniques to the materials scientist working with magnetic semiconductors (e.g. semiconductors doped with 3d transition metals) for applications in the field of spin-electronics. We focus our attention on the hard part of the x-ray spectrum (above 3 keV) in order to demonstrate a powerful element- and orbital-selective characterization tool in the study of bulk electronic structure. XES and RIXS are photon-in/photon-out second order optical processes described by the Kramers-Heisenberg formula. Nowadays, the availability of third generation synchrotron radiation sources permits to apply such techniques also to dilute materials, opening the way for a detailed atomic characterization of impurity-driven materials. We present the K{\\ss} XES as a tool to study the occupied valence states (directly, via valence-to-core transitions) and to probe the local spin angular momentum (indirectly, via intra-at...

  15. Slow dynamics of nanocomposite polymer aerogels as revealed by X-ray photocorrelation spectroscopy (XPCS)

    SciTech Connect (OSTI)

    Hernández, Rebeca, E-mail: rhernandez@ictp.csic.es, E-mail: aurora.nogales@csic.es; Mijangos, Carmen [Instituto de Ciencia y Tecnología de Polímeros, ICTP-CSIC, Juan de la Cierva, 3, 28006 Madrid (Spain)] [Instituto de Ciencia y Tecnología de Polímeros, ICTP-CSIC, Juan de la Cierva, 3, 28006 Madrid (Spain); Nogales, Aurora, E-mail: rhernandez@ictp.csic.es, E-mail: aurora.nogales@csic.es; Ezquerra, Tiberio A. [Instituto de Estructura de la Materia, IEM-CSIC, Serrano 121, 28006 Madrid (Spain)] [Instituto de Estructura de la Materia, IEM-CSIC, Serrano 121, 28006 Madrid (Spain); Sprung, Michael [Petra III at DESY, Notkestr. 85, 22607 Hamburg (Germany)] [Petra III at DESY, Notkestr. 85, 22607 Hamburg (Germany)

    2014-01-14T23:59:59.000Z

    We report on a novel slow dynamics of polymer xerogels, aerogels, and nanocomposite aerogels with iron oxide nanoparticles, as revealed by X-ray photon correlation spectroscopy. The polymer aerogel and its nanocomposite aerogels, which are porous in nature, exhibit hyper-diffusive dynamics at room temperature. In contrast, non-porous polymer xerogels exhibit an absence of this peculiar dynamics. This slow dynamical process has been assigned to a relaxation of the characteristic porous structure of these materials and not to the presence of nanoparticles.

  16. High-pressure X-ray absorption fine structure in the diamond anvil cell and its applications in geological materials

    E-Print Network [OSTI]

    Duffy, Thomas S.

    nano- polycrystalline diamond instead of single crystal anvils, the influence of diamond diffractionHigh-pressure X-ray absorption fine structure in the diamond anvil cell and its applications fine structure in the diamond anvil cell and its applications in geological materials Xinguo Hong1

  17. Morphology of gold nanoparticles determined by full-curve fitting of the light absorption spectrum. Comparison with X-ray scattering and electron microscopy data

    E-Print Network [OSTI]

    Kostyantyn Slyusarenko; Benjamin Abécassis; Patrick Davidson; Doru Constantin

    2015-04-04T23:59:59.000Z

    UV-Vis absorption spectroscopy is frequently used to characterize the size and shape of gold nanoparticles. We present a full-spectrum model that yields reliable results for the commonly encountered case of mixtures of spheres and rods in varying proportions. We determine the volume fractions of the two populations, the aspect ratio distribution of the nanorods (average value and variance) and the interface damping parameter. We validate the model by checking the fit results against small-angle X-ray scattering and transmission electron microscopy data and show that correctly accounting for the polydispersity in aspect ratio is essential for a quantitative description of the longitudinal plasmon peak.

  18. X-ray Absorption Spectroscopy of Biologically Relevant Systems

    E-Print Network [OSTI]

    Uejio, Janel Sunayo

    2010-01-01T23:59:59.000Z

    of the interaction of the carboxylate with lithium; this isinteractions of carboxylate with the monovalent cations lithium,lithium acetate revealing distinct shifts between the cations, indicative of preferential interactions.

  19. X-ray Absorption Spectroscopy: a Powerful Tool for Investigating

    E-Print Network [OSTI]

    Morante, Silvia

    LURE D 2.15 2.6 ESRF Grenoble D 6. 0.6, 1.3 5. GERMANY BESSY I BESSY D 0.8 19.4 DELTA Dortmund 1.5 5.5 BESSY II BESSY D 1.7 5.0 ANKA Karlsruhe D 2.5 2 ELSA Bonn 3.5 1.4 DORIS DESY 5. 0.55 6. INDIA INDUS I

  20. X-ray Absorption Spectroscopy: a Powerful Tool for Investigating

    E-Print Network [OSTI]

    Morante, Silvia

    ) accelerated particles relativistic (E = mc2) radial acceleration (e.g. deflected by a magnet) Lorentz force F Synchrotronstrahlung (BESSY), Berlin 8. Canadian Light Source (CLS), Saskatoon, Saskatchewan 9. Center for Advanced

  1. TENDER ENERGY X-RAY ABSORPTION SPECTROSCOPY (TES)

    E-Print Network [OSTI]

    Ohta, Shigemi

    productivity at the earliest possible date. · Strategy combines in-house and external aspects to create world IMPACT: · Energy Materials: Photovoltaic, fuel-cell, battery and superconducting (nano

  2. X-ray Transient Absorption of Transition Metal Complex Excited States and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-RayX-rayX-ray

  3. Versatile plug flow catalytic cell for in situ transmission/fluorescence x-ray absorption fine structure measurements

    SciTech Connect (OSTI)

    Centomo, P.; Zecca, M. [Dipartimento di Scienze Chimiche, via Marzolo 1, Universita degli Studi di Padova, 35131 Padova (Italy); Meneghini, C. [Dipartimento di Scienze, via della Vasca Navale 84, Universita di Roma TRE, 00146 Roma (Italy)

    2013-05-15T23:59:59.000Z

    A novel flow-through catalytic cell has been developed for in situ x-ray absorption spectroscopy (XAS) experiments on heterogeneous catalysts under working conditions and in the presence of a liquid and a gas phase. The apparatus allows to carry out XAS measurements in both the transmission and fluorescence modes, at moderate temperature (from RT to 50-80 Degree-Sign C) and low-medium gas pressure (up to 7-8 bars). The materials employed are compatible with several chemicals such as those involved in the direct synthesis of hydrogen peroxide (O{sub 2}, H{sub 2}, H{sub 2}O{sub 2}, methanol). The versatile design of the cell allows to fit it to different experimental setups in synchrotron radiation beamlines. It was used successfully for the first time to test nanostructured Pd catalysts during the direct synthesis of hydrogen peroxide (H{sub 2}O{sub 2}) in methanol solution from dihydrogen and dioxygen.

  4. Ab initio curved-wave x-ray-absorption fine structure

    SciTech Connect (OSTI)

    Mustre de Leon, J.; Rehr, J.J.; Zabinsky, S.I. (Department of Physics, FM-15, University of Washington, Seattle, Washington (USA)); Albers, R.C. (Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico (USA))

    1991-09-01T23:59:59.000Z

    The most important elements of {ital ab} {ital initio} calculations of x-ray-absorption fine structure (XAFS) are studied. To obtain accurate results without {ital ad} {ital hoc} adjustable parameters, we find it essential to include (i) curved-wave effects, (ii) a complex, energy-dependent self-energy, (iii) an approximate molecular potential, and (iv) a fixed energy reference for the photoelectron wave number. Based on these findings, an automated code has been developed for {ital ab} {ital initio} calculations of single-scattering XAFS, in which curved-wave effects are treated exactly in terms of effective backscattering amplitudes, inelastic losses and self-energy shifts are incorporated with use of a Hedin-Lundqvist self-energy, an automated relativistic overlapping-atom muffin-tin potential is used, and the energy threshold is estimated from electron-gas theory. The efficiency of the code is made possible by analytic expressions for the Hedin-Lundqvist self-energy. This code replaces existing tables of XAFS phases and scattering amplitudes and yields reliable theoretical XAFS standards for arbitrary pairs of atoms throughout the Periodic Table ({ital Z}{le}94). These results are comparable to those from self-consistent calculations and are valid to within about 20 eV of the absorption edge. Comparisons with experiment are presented for Cu, Ge, Pt, Br{sub 2}, and GeCl{sub 4}. The calculated XAFS amplitudes are found to be accurate to within 15%; XAFS phases are accurate to within 0.2 rad; and nearest-neighbor distances are typically accurate to within 0.02 A.

  5. Suzaku X-Ray Spectroscopy of a Peculiar Hot Star in the Galactic Center Region

    E-Print Network [OSTI]

    Yoshiaki Hyodo; Masahiro Tsujimoto; Katsuji Koyama; Shogo Nishiyama; Tetsuya Nagata; Itsuki Sakon; Hiroshi Murakami; Hironori Matsumoto

    2007-12-03T23:59:59.000Z

    We present the results of a Suzaku study of a bright point-like source in the 6.7 keV intensity map of the Galactic center region. We detected an intense FeXXV 6.7 keV line with an equivalent width of ~1 keV as well as emission lines of highly ionized Ar and Ca from a spectrum obtained by the X-ray Imaging Spectrometer. The overall spectrum is described very well by a heavily absorbed (~2x10^{23}cm^{-2}) thin thermal plasma model with a temperature of 3.8+/-0.6 keV and a luminosity of ~3x10^{34} erg s^{-1} (2.0--8.0 keV) at 8 kpc. The absorption, temperature, luminosity, and the 6.7 keV line intensity were confirmed with the archived XMM-Newton data. The source has a very red (J-Ks=8.2 mag) infrared spectral energy distribution (SED), which was fitted by a blackbody emission of ~1000 K attenuated by a visual extinction of ~31 mag. The high plasma temperature and the large X-ray luminosity are consistent with a wind-wind colliding Wolf-Rayet binary. The similarity of the SED to those of the eponymous Quintuplet cluster members suggests that the source is a WC-type source.

  6. X-ray imaging crystal spectroscopy for use in plasma transport research

    SciTech Connect (OSTI)

    Reinke, M. L.; Podpaly, Y. A.; Hutchinson, I. H.; Rice, J. E.; Gao, C.; Greenwald, M.; Howard, N. T.; Hubbard, A.; Hughes, J. W.; White, A. E.; Wolfe, S. M. [MIT-Plasma Science and Fusion Center, Cambridge, Massachusetts 02139 (United States); Bitter, M.; Delgado-Aparicio, L.; Hill, K.; Pablant, N. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

    2012-11-15T23:59:59.000Z

    This research describes advancements in the spectral analysis and error propagation techniques associated with x-ray imaging crystal spectroscopy (XICS) that have enabled this diagnostic to be used to accurately constrain particle, momentum, and heat transport studies in a tokamak for the first time. Doppler tomography techniques have been extended to include propagation of statistical uncertainty due to photon noise, the effect of non-uniform instrumental broadening as well as flux surface variations in impurity density. These methods have been deployed as a suite of modeling and analysis tools, written in interactive data language (IDL) and designed for general use on tokamaks. Its application to the Alcator C-Mod XICS is discussed, along with novel spectral and spatial calibration techniques. Example ion temperature and radial electric field profiles from recent I-mode plasmas are shown, and the impact of poloidally asymmetric impurity density and natural line broadening is discussed in the context of the planned ITER x-ray crystal spectrometer.

  7. High-rate x-ray spectroscopy in mammography with a CdTe detector: A digital pulse processing approach

    SciTech Connect (OSTI)

    Abbene, L.; Gerardi, G.; Principato, F.; Del Sordo, S.; Ienzi, R.; Raso, G. [Dipartimento di Fisica e Tecnologie Relative, Universita di Palermo, Viale delle Scienze, Edificio 18, Palermo 90128 (Italy) and INAF/IASF Palermo, Via Ugo La Malfa 153, 90146 Palermo (Italy); Dipartimento di Fisica e Tecnologie Relative, Universita di Palermo, Viale delle Scienze, Edificio 18, Palermo 90128 (Italy); INAF/IASF Palermo, Via Ugo La Malfa 153, 90146 Palermo (Italy); Istituto di Radiologia, Policlinico, 90100 Palermo (Italy); Dipartimento di Fisica e Tecnologie Relative, Universita di Palermo, Viale delle Scienze, Edificio 18, Palermo 90128 (Italy)

    2010-12-15T23:59:59.000Z

    Purpose:Direct measurement of mammographic x-ray spectra under clinical conditions is a difficult task due to the high fluence rate of the x-ray beams as well as the limits in the development of high resolution detection systems in a high counting rate environment. In this work we present a detection system, based on a CdTe detector and an innovative digital pulse processing (DPP) system, for high-rate x-ray spectroscopy in mammography. Methods: The DPP system performs a digital pile-up inspection and a digital pulse height analysis of the detector signals, digitized through a 14-bit, 100 MHz digitizer, for x-ray spectroscopy even at high photon counting rates. We investigated on the response of the digital detection system both at low (150 cps) and at high photon counting rates (up to 500 kcps) by using monoenergetic x-ray sources and a nonclinical molybdenum anode x-ray tube. Clinical molybdenum x-ray spectrum measurements were also performed by using a pinhole collimator and a custom alignment device. Results: The detection system shows excellent performance up to 512 kcps with an energy resolution of 4.08% FWHM at 22.1 keV. Despite the high photon counting rate (up to 453 kcps), the molybdenum x-ray spectra, measured under clinical conditions, are characterized by a low number of pile-up events. The agreement between the attenuation curves and the half value layer values, obtained from the measured spectra, simulated spectra, and from the exposure values directly measured with an ionization chamber, also shows the accuracy of the measurements. Conclusions: These results make the proposed detection system a very attractive tool for both laboratory research and advanced quality controls in mammography.

  8. Delocalization and occupancy effects of 5f orbitals in plutonium intermetallics using L3-edge resonant X-ray emission spectroscopy

    SciTech Connect (OSTI)

    Booth, C. H.; Medling, S. A.; Jiang, Yu; Bauer, E. D.; Tobash, P. H.; Mitchell, J. N.; Veirs, D. K.; Wall, M. A.; Allen, P. G.; Kas, J. J.; Sokaras, D.; Nordlund, D.; Weng, T.-C.

    2014-06-24T23:59:59.000Z

    Although actinide (An) L3 -edge X-ray absorption near-edge structure (XANES) spectroscopy has been very effective in determining An oxidation states in insulating, ionically bonded materials, such as in certain coordination compounds and mineral systems, the technique fails in systems featuring more delocalized 5f orbitals, especially in metals. Recently, actinide L3-edge resonant X-ray emission spec- troscopy (RXES) has been shown to be an effective alternative. This technique is further demonstrated here using a parameterized partial unoccupied density of states method to quantify both occupancy and delocalization of the 5f orbital in ?-Pu, ?-Pu, PuCoGa5 , PuCoIn5 , and PuSb2. These new results, supported by FEFF calculations, highlight the effects of strong correlations on RXES spectra and the technique?s ability to differentiate between f-orbital occupation and delocalization.

  9. Masked-backlighter technique used to simultaneously image x-ray absorption and x-ray emission from an inertial confinement fusion plasma

    SciTech Connect (OSTI)

    Marshall, F. J., E-mail: fredm@lle.rochester.edu; Radha, P. B. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

    2014-11-15T23:59:59.000Z

    A method to simultaneously image both the absorption and the self-emission of an imploding inertial confinement fusion plasma has been demonstrated on the OMEGA Laser System. The technique involves the use of a high-Z backlighter, half of which is covered with a low-Z material, and a high-speed x-ray framing camera aligned to capture images backlit by this masked backlighter. Two strips of the four-strip framing camera record images backlit by the high-Z portion of the backlighter, while the other two strips record images aligned with the low-Z portion of the backlighter. The emission from the low-Z material is effectively eliminated by a high-Z filter positioned in front of the framing camera, limiting the detected backlighter emission to that of the principal emission line of the high-Z material. As a result, half of the images are of self-emission from the plasma and the other half are of self-emission plus the backlighter. The advantage of this technique is that the self-emission simultaneous with backlighter absorption is independently measured from a nearby direction. The absorption occurs only in the high-Z backlit frames and is either spatially separated from the emission or the self-emission is suppressed by filtering, or by using a backlighter much brighter than the self-emission, or by subtraction. The masked-backlighter technique has been used on the OMEGA Laser System to simultaneously measure the emission profiles and the absorption profiles of polar-driven implosions.

  10. Broadband spectroscopy of the eclipsing high mass X-ray binary 4U 1700-37 with Suzaku

    E-Print Network [OSTI]

    Jaisawal, Gaurava K

    2015-01-01T23:59:59.000Z

    We present the results obtained from broadband spectroscopy of the high mass X-ray binary 4U 1700-37 using data from a Suzaku observation in 2006 September 13-14 covering 0.29-0.72 orbital phase range. The light curves showed significant and rapid variation in source flux during entire observation. We did not find any signature of pulsations in the light curves. However, a quasi-periodic oscillation at ~20 mHz was detected in the power density spectrum of the source. The 1-70 keV spectrum was fitted with various continuum models. However, we found that the partially absorbed high energy cutoff power-law and Negative and Positive power-law with Exponential cutoff (NPEX) models described the source spectrum well. Iron emission lines at 6.4 keV and 7.1 keV were detected in the source spectrum. An absorption like feature at ~39 keV was detected in the residuals while fitting the data with NPEX model. Considering the feature as cyclotron absorption line, the surface magnetic field of the neutron star was estimated...

  11. First-Principles Calculation of Principal Hugoniot and K-Shell X-ray Absorption Spectra for Warm Dense KCl

    E-Print Network [OSTI]

    Zhao, Shijun; Kang, Wei; Li, Zi; Zhang, Ping; He, Xian-Tu

    2015-01-01T23:59:59.000Z

    Principal Hugoniot and K-shell X-ray absorption spectra of warm dense KCl are calculated using the first-principles molecular dynamics method. Evolution of electronic structures as well as the influence of the approximate description of ionization on pressure (caused by the underestimation of the energy gap between conduction bands and valence bands) in the first-principles method are illustrated by the calculation. Pressure ionization and thermal smearing are shown as the major factors to prevent the deviation of pressure from global accumulation along the Hugoniot. In addition, cancellation between electronic kinetic pressure and virial pressure further reduces the deviation. The calculation of X-ray absorption spectra shows that the band gap of KCl persists after the pressure ionization of the $3p$ electrons of Cl and K taking place at lower energy, which provides a detailed understanding to the evolution of electronic structures of warm dense matter.

  12. In situ x-ray absorption fine structure and optical reflectance studies of electrodeposited nickel hydrous oxide films in alkaline electrolytes.

    SciTech Connect (OSTI)

    Hu, Y.; Bae, I. T.; Mo, Y.; Antonio, M. R.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

    1997-01-01T23:59:59.000Z

    X-ray absorption fine structure (XAFS) and optical reflectance spectroscopy (RS) have been used to examine in situ electronic and structural aspects of nickel hydrous oxide, a-Ni(OH)2(hyd), electrodes supported on gold in alkaline electrolytes as a function of their state of charge. The extended X-ray absorption fine structure (EXAFS) of a-Ni(OH)2(hyd) electrodes in the uncharged (UC, or discharged) and overcharged (OC, or fully charged) states yielded, in each case, a single set of two distinct nearest-neighbor shells, with distances, d(Ni-O)1 = 2.05 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 3.11 {+-} 0.02 {angstrom} for UC, and d(Ni-O)1 = 1.87 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 2.83 {+-} 0.02 {angstrom} for OC. The in situ EXAFS of films allowed to self-discharge following overcharge could be fit with contributions from both sets of shells, suggesting that only two types of nickel sites are sufficient to account for the redox chemistry of this material. These data, in addition to information derived both from quantitative X-ray absorption near-edge structure (XANES) and optical RS in the visible range, indicate that the excess anodic charge, i.e., beyond the one-electron oxidation of Ni2+ sites, observed during the first oxidation of freshly prepared a-Ni(OH)2(hyd) electrodes may not be related to oxidation state changes involving nickel sites in the lattice, and, therefore, do not support the existence of nickel sites with a formal oxidation state higher than three for charged or overcharged electrodes in this media.

  13. Optically Detected Extended X-Ray Absorption Fine Structure Study of InGaN/GaN Single Quantum Wells

    SciTech Connect (OSTI)

    Rigopoulos, N.; Hamilton, B.; Davies, G. J.; Towlson, B. M. [School of Electrical and Electronic Engineering, University of Manchester, Manchester M60 1QD (United Kingdom); Poolton, N. R. J. [Synchrotron Radiation Department, Daresbury Laboratory, Daresbury, Warrington WA4 4AD (United Kingdom); Dawson, P.; Graham, D. M. [School of Physics and Astronomy, University of Manchester, Manchester M60 1QD (United Kingdom); Kappers, M. J.; Humphreys, C. J. [Dept. of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom); Carlson, S. [MAX-lab, Lund University, P.O. Box 118, SE- 221 00 Lund (Sweden)

    2007-04-10T23:59:59.000Z

    We have investigated the local atomic environment of the Ga atoms in an InxGa1-xN single quantum well structure using Optically Detected Extended X-ray Absorption Fine Structure (OD-EXAFS). A comparison of the OD-EXAFS data with a theoretical model shows the technique to be site selective for this particular structure and reveals that the quantum well emission originates from regions with x=0.15.

  14. Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy

    SciTech Connect (OSTI)

    Huse, Nils; Kim, Tae Kyu; Khalil, Munira; Jamula, Lindsey; McCusker, James K.; Schoenlein, Robert W.

    2010-05-02T23:59:59.000Z

    We report the first time-resolved soft x-ray measurements of solvated transition-metal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.

  15. First-principles core-level X-ray photoelectron spectroscopy calculation on arsenic defects in silicon crystal

    SciTech Connect (OSTI)

    Kishi, Hiroki; Miyazawa, Miki; Matsushima, Naoki; Yamauchi, Jun [Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama-shi, Kanagawa-ken 223-8522 (Japan)

    2014-02-21T23:59:59.000Z

    We investigate the X-ray photoelectron spectroscopy (XPS) binding energies of As 3d in Si for various defects in neutral and charged states by first-principles calculation. It is found that the complexes of a substitutional As and a vacancy in charged and neutral states explain the experimentally observed unknown peak very well.

  16. An x-ray absorption spectroscopic study of the electronic structure and bonding of rare-earth orthoferrites

    SciTech Connect (OSTI)

    Hayes, J.R.; Grosvenor, A.P. (Saskatchewan)

    2011-11-07T23:59:59.000Z

    Rare-earth orthoferrites, REFeO{sub 3} (RE=rare earth; Y), are tremendously adaptable compounds that are being investigated for use in a wide variety of applications including gas sensors, vehicle catalytic converters, and solid-oxide fuel cells. They also exhibit interesting magnetic properties such as high-temperature antiferromagnetism, making them useful for data storage applications. The compounds adopt a distorted perovskite-type structure where the tilt angle of the octahedra increases (Fe-O-Fe bond angle decreases) as the size of the rare-earth atom decreases. Despite intensive study of the physical properties of these compounds, very few studies have investigated how the bonding and electronic structure of these systems change with substitution of the RE. X-ray absorption near-edge spectroscopy (XANES) is a technique well-suited for such a study, and, in view of this, Fe L-, Fe K- and O K-edge spectra from a series of REFeO{sub 3} compounds (RE=La, Pr, Nd, Sm, Eu, Gd, Ho, Yb, Y) have been collected, and are presented here. Fe L-edge spectra show that Fe is octahedrally coordinated and that the Fe-centered octahedra do not appear to distort with changes in the identity of the RE. The Fe K-edge spectra contain an intersite hybrid peak, which is an ill-studied feature that is attributed to non-local transitions of 1s electrons to 3d states on the next-nearest-neighbor atom that are hybridized with 4p states on the absorbing atom through O 2p states. In this study, it is shown that the intensity of this feature is strongly dependent on the Fe-O-Fe bond angle; the lower the Fe-O-Fe bond angle, the less intense the intersite hybrid peak is.

  17. THREE NEW GALACTIC CENTER X-RAY SOURCES IDENTIFIED WITH NEAR-INFRARED SPECTROSCOPY

    SciTech Connect (OSTI)

    DeWitt, Curtis [Department of Physics, University of California, Davis, CA 95616 (United States); Bandyopadhyay, Reba M.; Eikenberry, Stephen S.; Sarajedini, Ata [Department of Astronomy, University of Florida, 211 Bryant Space Center, P.O. Box 112055, Gainesville, FL 32611 (United States); Sellgren, Kris [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Blum, Robert; Olsen, Knut [National Optical Astronomy Observatories, Tucson, AZ 85719 (United States); Bauer, Franz E., E-mail: curtis.n.dewitt@nasa.gov [Departamento de Astronomía y Astrofísica, Pontificia Universidad Católica de Chile, Casilla 306, Santiago 22 (Chile)

    2013-11-01T23:59:59.000Z

    We have conducted a near-infrared spectroscopic survey of 47 candidate counterparts to X-ray sources discovered by the Chandra X-Ray Observatory near the Galactic center (GC). Though a significant number of these astrometric matches are likely to be spurious, we sought out spectral characteristics of active stars and interacting binaries, such as hot, massive spectral types or emission lines, in order to corroborate the X-ray activity and certify the authenticity of the match. We present three new spectroscopic identifications, including a Be high-mass X-ray binary (HMXB) or a ? Cassiopeiae (Cas) system, a symbiotic X-ray binary, and an O-type star of unknown luminosity class. The Be HMXB/? Cas system and the symbiotic X-ray binary are the first of their classes to be spectroscopically identified in the GC region.

  18. Monitoring Long-Range Electron Transfer Pathways in Proteins by Stimulated Attosecond Broadband X-ray Raman Spectroscopy

    SciTech Connect (OSTI)

    Zhang, Yu; Biggs, Jason; Govind, Niranjan; Mukamel, Shaul

    2014-10-09T23:59:59.000Z

    Long-range electron transfer (ET) plays a key role in many biological energy conversion and synthesis processes. We show that nonlinear spectroscopy with attosecond X-ray pulses provides a real time movie of the evolving oxidation states and electron densities around atoms, and can probe these processes with high spatial and temporal resolution. This is demonstrated in a simulation study of the stimulated X-ray Raman (SXRS) signals in Re-modified azurin, which had long served as a benchmark for long-range ET in proteins. Nonlinear SXRS signals are sensitive to the local electronic structure and should offer a novel window for long-range ET.

  19. Effect of Residence Time on Ni-Sorption Mechanisms on Clay and Oxide Minerals: An X-ray Absorption Fine Structure (XAFS) Study

    E-Print Network [OSTI]

    Sparks, Donald L.

    Effect of Residence Time on Ni-Sorption Mechanisms on Clay and Oxide Minerals: An X-ray Absorption minerals is typically fast initially, then the rates gradually diminish. In the literature the decline

  20. Oxygen Abundances in the Milky Way Using X-ray Absorption Measurements Towards Galaxy Clusters

    E-Print Network [OSTI]

    Wayne H. Baumgartner; Richard F. Mushotzky

    2005-09-21T23:59:59.000Z

    We present measurements of the oxygen abundance of the Milky Way's ISM by observing the K-shell X-ray photoionization edge towards galaxy clusters. This effect is most easily observed towards objects with galactic columns (n_H) of a few times 1e21 cm^-2. We measure X-ray column densities towards 11 clusters and find that at high galactic columns above approximately 1e21 cm^-2 the X-ray columns are generally 1.5--3.0 times greater than the 21 cm H II columns, indicating that molecular clouds become an important contributor to n_H at higher columns. We find the average ISM oxygen abundance to be (O/H) = (4.85 +/- 0.06) x 10^-4, or 0.99 solar when using the most recent solar photospheric values. Since X-ray observations are sensitive to the total amount of oxygen present (gas + dust), these results indicate a high gas to dust ratio. Also, the oxygen abundances along lines of sight through high galactic columns (n_H) are the same as abundances through low columns, suggesting that the composition of denser clouds is similar to that of the more diffuse ISM.

  1. Reactive ZnO/Ti/ZnO interfaces studied by hard x-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Knut, Ronny, E-mail: Ronny.Knut@physics.gu.se; Lindblad, Rebecka; Rensmo, Håkan; Karis, Olof [Department of Physics and Astronomy, Uppsala University, Box 516, 75120 Uppsala (Sweden); Grachev, Sergey; Faou, Jean-Yvon; Søndergård, Elin [Unité Mixte CNRS/Sain-Gobain Recherche, 39 Quai Lucien Lefranc, 93303 Aubervilliers (France); Gorgoi, Mihaela [Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Str. 15, D-12489 Berlin (Germany)

    2014-01-28T23:59:59.000Z

    The chemistry and intermixing at buried interfaces in sputter deposited ZnO/Ti/ZnO thin layers were studied by hard x-ray photoelectron spectroscopy. The long mean free path of the photoelectrons allowed for detailed studies of the oxidation state, band bending effects, and intrinsic doping of the buried interfaces. Oxidation of the Ti layer was observed when ZnO was deposited on top. When Ti is deposited onto ZnO, Zn Auger peaks acquire a metallic character indicating a strong reduction of ZnO at the interface. Annealing of the stack at 200?°C results in further reduction of ZnO and oxidation of Ti. Above 300?°C, oxygen transport from the bulk of the ZnO layer takes place, leading to re-oxidation of ZnO at the interface and further oxidation of Ti layer. Heating above 500?°C leads to an intermixing of the layers and the formation of a Zn{sub x}TiO{sub y} compound.

  2. X-ray absorption spectroscopic studies of the dinuclear iron center in methane monooxygenase and the sulfure and chlorine centers in photographic materials

    SciTech Connect (OSTI)

    DeWitt, J.G.

    1992-12-01T23:59:59.000Z

    The dinuclear iron center of the hydroxylase component of soluble methane monooxygenase (MMO) from Methylococcus capsulatus and Methylosinus trichosporiwn has been studied by X-ray absorption spectroscopy. Analysis of the Fe K-edge EXAFS revealed that the first shell coordination of the Fe(HI)Fe(IH) oxidized state of the hydroxylase from M. capsulatus consists of approximately 6 N and 0 atoms at an average distance of 2.04 [Angstrom]. The Fe-Fe distance was determined to be 3.4 [Angstrom]. No evidence for the presence of a short oxo bridge in the iron center of the oxidized hydroxylase was found, suggesting that the active site of MMO is significantly different from the active sites of the dinuclear iron proteins hemery and ribonucleotide reductase. In addition, the results of the first shell fits suggest that there are more oxygen than nitrogen donor ligands.

  3. X-ray absorption spectroscopic studies of the dinuclear iron center in methane monooxygenase and the sulfure and chlorine centers in photographic materials

    SciTech Connect (OSTI)

    DeWitt, J.G.

    1992-12-01T23:59:59.000Z

    The dinuclear iron center of the hydroxylase component of soluble methane monooxygenase (MMO) from Methylococcus capsulatus and Methylosinus trichosporiwn has been studied by X-ray absorption spectroscopy. Analysis of the Fe K-edge EXAFS revealed that the first shell coordination of the Fe(HI)Fe(IH) oxidized state of the hydroxylase from M. capsulatus consists of approximately 6 N and 0 atoms at an average distance of 2.04 {Angstrom}. The Fe-Fe distance was determined to be 3.4 {Angstrom}. No evidence for the presence of a short oxo bridge in the iron center of the oxidized hydroxylase was found, suggesting that the active site of MMO is significantly different from the active sites of the dinuclear iron proteins hemery and ribonucleotide reductase. In addition, the results of the first shell fits suggest that there are more oxygen than nitrogen donor ligands.

  4. Picosecond soft X-ray absorption measurement of the photo-inducedinsulator-to-metal transition in VO2.

    SciTech Connect (OSTI)

    Cavalleri, Andrea; Chong, Henry H.W.; Fourmaux, Sylvain; Glover,Thornton E.; Heimann, Phil A.; Kieffer, Jean Claude; Mun, B. Simon; Padmore, Howard A.; Schoenlein, Robert W.

    2004-02-01T23:59:59.000Z

    We directly measure the photoinduced insulator-to-metal transition in VO2 using time-resolved near-edge x-ray absorption. Picosecond pulses of synchrotron radiation are used to detect the redshift in the vanadium L3edge at 516 eV, which is associated with the transient collapse of the low-temperature band gap. We identify a two-component temporal response, corresponding to an ultrafast transformation over a 50 nm surface layer, followed by 40 m/s thermal growth of the metallic phase into the bulk.

  5. ON THE PROSPECT OF CONSTRAINING BLACK HOLE SPIN THROUGH X-RAY SPECTROSCOPY OF HOTSPOTS

    E-Print Network [OSTI]

    Yaqoob, Tahir

    Future X-ray instrumentation is expected to allow us to significantly improve the constraints derived from the Fe?K lines in active galactic nuclei, such as the black hole angular momentum (spin) and the inclination angle ...

  6. X-ray afterglows and spectroscopy of Gamma-Ray Bursts

    E-Print Network [OSTI]

    Luigi Piro

    2004-02-26T23:59:59.000Z

    I will review the constraints set by X-ray measurements of afterglows on several issues of GRB, with particular regard to the fireball model, the environment, the progenitor and dark GRB.

  7. Imaging X-ray spectroscopy with micro-X and Chandra

    E-Print Network [OSTI]

    Rutherford, John (John Morton)

    2013-01-01T23:59:59.000Z

    High spectral resolution observations of X-ray phenomena have the potential to uncover new physics. Currently, only point sources can be probed with high resolution spectra, using gratings. Extended objects like supernova ...

  8. Sub-nanosecond time-resolved ambient-pressure X-ray photoelectron spectroscopy setup for pulsed and constant wave X-ray light sources

    SciTech Connect (OSTI)

    Shavorskiy, Andrey; Slaughter, Daniel S.; Zegkinoglou, Ioannis; Rude, Bruce S.; Bluhm, Hendrik [Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Neppl, Stefan; Cryan, James P.; Siefermann, Katrin R.; Weise, Fabian; Lin, Ming-Fu; Bacellar, Camila; Ziemkiewicz, Michael P.; Fraund, Matthew W.; Khurmi, Champak; Wright, Travis W.; Schoenlein, Robert W.; Gessner, Oliver, E-mail: ogessner@lbl.gov [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Hertlein, Marcus P.; Tyliszczak, Tolek [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Huse, Nils [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Physics Department, University of Hamburg and Max-Planck Institute for Structure and Dynamics of Matter, 22761 Hamburg (Germany); and others

    2014-09-15T23:59:59.000Z

    An apparatus for sub-nanosecond time-resolved ambient-pressure X-ray photoelectron spectroscopy studies with pulsed and constant wave X-ray light sources is presented. A differentially pumped hemispherical electron analyzer is equipped with a delay-line detector that simultaneously records the position and arrival time of every single electron at the exit aperture of the hemisphere with ?0.1 mm spatial resolution and ?150 ps temporal accuracy. The kinetic energies of the photoelectrons are encoded in the hit positions along the dispersive axis of the two-dimensional detector. Pump-probe time-delays are provided by the electron arrival times relative to the pump pulse timing. An average time-resolution of (780 ± 20) ps (FWHM) is demonstrated for a hemisphere pass energy E{sub p} = 150 eV and an electron kinetic energy range KE = 503–508 eV. The time-resolution of the setup is limited by the electron time-of-flight (TOF) spread related to the electron trajectory distribution within the analyzer hemisphere and within the electrostatic lens system that images the interaction volume onto the hemisphere entrance slit. The TOF spread for electrons with KE = 430 eV varies between ?9 ns at a pass energy of 50 eV and ?1 ns at pass energies between 200 eV and 400 eV. The correlation between the retarding ratio and the TOF spread is evaluated by means of both analytical descriptions of the electron trajectories within the analyzer hemisphere and computer simulations of the entire trajectories including the electrostatic lens system. In agreement with previous studies, we find that the by far dominant contribution to the TOF spread is acquired within the hemisphere. However, both experiment and computer simulations show that the lens system indirectly affects the time resolution of the setup to a significant extent by inducing a strong dependence of the angular spread of electron trajectories entering the hemisphere on the retarding ratio. The scaling of the angular spread with the retarding ratio can be well approximated by applying Liouville's theorem of constant emittance to the electron trajectories inside the lens system. The performance of the setup is demonstrated by characterizing the laser fluence-dependent transient surface photovoltage response of a laser-excited Si(100) sample.

  9. Multidimensional x-ray spectroscopy of valence and core excitations in Jason D. Biggs, Yu Zhang, Daniel Healion, and Shaul Mukamel

    E-Print Network [OSTI]

    Mukamel, Shaul

    Multidimensional x-ray spectroscopy of valence and core excitations in cysteine Jason D. Biggs, Yu and core excitations in cysteine Jason D. Biggs, Yu Zhang, Daniel Healion, and Shaul Mukamela) Department

  10. X-Ray Spectroscopy of the Classical Nova V458 Vulpeculae with Suzaku

    E-Print Network [OSTI]

    Masahiro Tsujimoto; Dai Takei; Jeremy J. Drake; Jan-Uwe Ness; Shunji Kitamoto

    2008-10-17T23:59:59.000Z

    We conducted a target of opportunity X-ray observation of the classical nova V458 Vulpeculae 88 days after the explosion using the Suzaku satellite. With a 20 ks exposure, the X-ray Imaging Spectrometer detected X-ray emission significantly harder than typical super-soft source emission. The X-ray spectrum shows K lines from N, Ne, Mg, Si, and S, and L-series emission from Fe in highly ionized states. The spectrum can be described by a single temperature (0.64 keV) thin thermal plasma model in collisional equilibrium with a hydrogen-equivalent extinction column density of ~3e21/cm2, a flux of ~1e-12 erg/s/cm2, and a luminosity of ~6e34 erg/s in the 0.3-3.0 keV band at an assumed distance of 13 kpc. We found a hint of an enhancement of N and deficiencies of O and Fe relative to other metals. The observed X-ray properties can be interpreted as the emission arising from shocks of ejecta from an ONe-type nova.

  11. X-Ray Spectroscopy of the Classical Nova V458 Vulpeculae with Suzaku

    E-Print Network [OSTI]

    Tsujimoto, Masahiro; Drake, Jeremy J; Ness, Jan-Uwe; Kitamoto, Shunji

    2008-01-01T23:59:59.000Z

    We conducted a target of opportunity X-ray observation of the classical nova V458 Vulpeculae 88 days after the explosion using the Suzaku satellite. With a 20 ks exposure, the X-ray Imaging Spectrometer detected X-ray emission significantly harder than typical super-soft source emission. The X-ray spectrum shows K lines from N, Ne, Mg, Si, and S, and L-series emission from Fe in highly ionized states. The spectrum can be described by a single temperature (0.64 keV) thin thermal plasma model in collisional equilibrium with a hydrogen-equivalent extinction column density of ~3e21/cm2, a flux of ~1e-12 erg/s/cm2, and a luminosity of ~6e34 erg/s in the 0.3-3.0 keV band at an assumed distance of 13 kpc. We found a hint of an enhancement of N and deficiencies of O and Fe relative to other metals. The observed X-ray properties can be interpreted as the emission arising from shocks of ejecta from an ONe-type nova.

  12. In situ Ru K-edge x-ray absorption fine structure studies of electroprecipitated ruthenium dioxide films with relevance to supercapacitor applications.

    SciTech Connect (OSTI)

    Mo, Y.; Antonio, M. R.; Stefan, I. C.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

    2000-10-26T23:59:59.000Z

    Modifications in electronic and structural aspects of RuO{sub 2} films electroprecipitated onto Au electrodes induced by changes in the applied potential have been examined in situ in aqueous 0.50 M H{sub 2}SO{sub 4} by Ru K-edge X-ray absorption spectroscopy (XAS). The Fourier transform of the k{sup 3}-weighted extended X-ray absorption fine structure (EXAFS), k{sup 3}x(k), for the film polarized at +1.20V vs RHE is characterized by two shells attributed to Ru-O and Ru-Ru interactions with average distances of 1.94(1) and 3.12(2) {angstrom}, respectively, in agreement with results obtained ex situ for Ru{sup 4+} in hydrous RuO{sub 2} by other groups. In contrast, films in the reduced state, i.e., +0.40 V vs RHE, yielded only a single shell ascribed to a Ru-O interaction at 2.02(1) {angstrom} with no evidence for a distant Ru-Ru shell. The long Ru-O distance is in agreement with that reported earlier for the hydrous Ru{sup 3+} ion [Ru-(OH{sub 2}){sub 6}]{sup 3+} in the solid state. Moreover, the difference between the average Ru-O bond lengths for the reduced and oxidized films is consistent with the difference in the ionic radii of Ru{sup 3+} and Ru{sup 4+}. On this basis it has been suggested that films in the reduced state contain Ru{sup 3+} sites, consistent with the electrochemical results, in a phase with apparently less order beyond the Ru-O coordination sphere than for hydrous RuO{sub 2}.

  13. Femtosecond soft x-ray spectroscopy of solvated transition metal complexes: Deciphering the interplay of electronic and structural dynamics

    SciTech Connect (OSTI)

    Huse, Nils; Cho, Hana; Hong, Kiryong; Jamula, Lindsey; de Groot, Frank M. F.; Kim, Tae Kyu; McCusker, James K.; Schoenlein, Robert W.

    2011-03-09T23:59:59.000Z

    We present the first implementation of femtosecond soft X-ray spectroscopy as an ultrafast direct probe of the excited-state valence orbitals in solution-phase molecules. This method is applied to photoinduced spin crossover of [Fe(tren(py)3)]2+, where the ultrafast spinstate conversion of the metal ion, initiated by metal-to-ligand charge-transfer excitation, is directly measured using the intrinsic spin-state selectivity of the soft X-ray L-edge transitions. Our results provide important experimental data concerning the mechanism of ultrafast spin-state conversion and subsequent electronic and structural dynamics, highlighting the potential of this technique to study ultrafast phenomena in the solution phase.

  14. ELECTRON SPECTROSCOPY OF SURFACES Elemental and Chemical Analysis with X-ray

    E-Print Network [OSTI]

    of the experiment is to make the students familiar with the fundamental principles and basic methodology of XPS be of relevance for a vast range of systems not only in condensed matter physics, chemistry, and materials science simple process. When a solid surface is irradiated with soft X-ray photons (Fig. 1a), an incident photon

  15. Suzaku Spectroscopy of the Extended X-Ray Emission in M17

    E-Print Network [OSTI]

    Yoshiaki Hyodo; Masahiro Tsujimoto; Kenji Hamaguchi; Katsuji Koyama; Shunji Kitamoto; Yoshitomo Maeda; Yohko Tsuboi; Yuichiro Ezoe

    2007-07-27T23:59:59.000Z

    We present the results of a Suzaku spectroscopic study of the soft extended X-ray emission in the HII region M17. The spectrum of the extended emission was obtained with a high signal-to-noise ratio in a spatially-resolved manner using the X-ray Imaging Spectrometer (XIS). We established that the contamination by unresolved point sources, the Galactic Ridge X-ray emission, the cosmic X-ray background, and the local hot bubble emission is negligible in the background-subtracted XIS spectrum of the diffuse emission. Half a dozen of emission lines were resolved clearly for the first time, including K lines of highly ionized O, Ne, and Mg as well as L series complex of Fe at 0.5--1.5 keV. Based on the diagnosis of these lines, we obtained the following results: (1) the extended emission is an optically-thin thermal plasma represented well by a single temperature of 3.0 +/- 0.4 MK, (2) the abundances of elements with emission lines in the diffuse spectrum are 0.1--0.3 solar, while those of bright discrete sources are 0.3--1.5 solar, (3) the metal abundances relative to each other in the diffuse emission are consistent with solar except for a Ne enhancement of a factor of 2, (4) both the plasma temperature and the chemical composition of the diffuse emission show no spatial variation across the studied spatial scale of about 5 pc.

  16. X-Ray Spectroscopy of II Pegasi: Coronal Temperature Structure, Abundances, and Variability

    E-Print Network [OSTI]

    Huenemoerder, David P.

    We have obtained high-resolution X-ray spectra of the coronally active binary II Pegasi (HD 224085), covering the wavelength range of 1.5-25 Å. For the first half of our 44 ks observation, the source was in a quiescent ...

  17. Vibronic fine structure in high-resolution x-ray absorption spectra from ion-bombarded boron nitride nanotubes

    SciTech Connect (OSTI)

    Petravic, Mladen; Peter, Robert; Varasanec, Marijana [Department of Physics and Center for Micro and Nano Sciences and Technologies, University of Rijeka, 51000 Rijeka (Croatia); Li Luhua; Chen Ying [Institute for Technology Research and Innovation, Deakin University, Geelong Waurn Ponds Campus, 3217 (Australia); Cowie, Bruce C. C. [Australian Synchrotron, Clayton VIC 3168 (Australia)

    2013-05-15T23:59:59.000Z

    The authors have applied high-resolution near-edge x-ray absorption fine structure measurements around the nitrogen K-edge to study the effects of ion-bombardment on near-surface properties of boron nitride nanotubes. A notable difference has been observed between surface sensitive partial electron yield (PEY) and bulk sensitive total electron yield (TEY) fine-structure measurements. The authors assign the PEY fine structure to the coupling of excited molecular vibrational modes to electronic transitions in NO molecules trapped just below the surface. Oxidation resistance of the boron nitride nanotubes is significantly reduced by low energy ion bombardment, as broken B-N bonds are replaced by N-O bonds involving oxygen present in the surface region. In contrast to the PEY spectra, the bulk sensitive TEY measurements on as-grown samples do not exhibit any fine structure while the ion-bombarded samples show a clear vibronic signature of molecular nitrogen.

  18. Center for X-Ray Optics, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-08-01T23:59:59.000Z

    This report discusses the following topics: Center for X-Ray Optics; Soft X-Ray Imaging wit Zone Plate Lenses; Biological X-Ray microscopy; Extreme Ultraviolet Lithography for Nanoelectronic Pattern Transfer; Multilayer Reflective Optics; EUV/Soft X-ray Reflectometer; Photoemission Microscopy with Reflective Optics; Spectroscopy with Soft X-Rays; Hard X-Ray Microprobe; Coronary Angiography; and Atomic Scattering Factors.

  19. NuSTAR and Suzaku X-ray Spectroscopy of NGC 4151: Evidence for Reflection from the Inner Accretion Disk

    E-Print Network [OSTI]

    Keck, M L; Ballantyne, D R; Bauer, F; Boggs, S E; Christensen, F E; Craig, W W; Dauser, T; Elvis, M; Fabian, A C; Fuerst, F; García, J; Grefenstette, B W; Hailey, C J; Harrison, F A; Madejski, G; Marinucci, A; Matt, G; Reynolds, C S; Stern, D; Walton, D J; Zoghbi, A

    2015-01-01T23:59:59.000Z

    We present X-ray timing and spectral analyses of simultaneous 150 ks Nuclear Spectroscopic Telescope Array (NuSTAR) and Suzaku X-ray observations of the Seyfert 1.5 galaxy NGC 4151. We disentangle the continuum emission, absorption, and reflection properties of the active galactic nucleus (AGN) by applying inner accretion disk reflection and absorption-dominated models. With a time-averaged spectral analysis, we find strong evidence for relativistic reflection from the inner accretion disk. We find that relativistic emission arises from a highly ionized inner accretion disk with a steep emissivity profile, which suggests an intense, compact illuminating source. We find a preliminary, near-maximal black hole spin a>0.9 accounting for statistical and systematic modeling errors. We find a relatively moderate reflection fraction with respect to predictions for the lamp post geometry, in which the illuminating corona is modeled as a point source. Through a time-resolved spectral analysis, we find that modest coron...

  20. Near-edge x-ray-absorption fine structure of Pb: A comparison of theory and experiment

    SciTech Connect (OSTI)

    Newville, M.; Livins, P. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States)); Yacoby, Y. (Racah Institute of Physics, Hebrew University, Jerusalem (Israel)); Rehr, J.J.; Stern, E.A. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-06-01T23:59:59.000Z

    Two independent techniques are used to obtain the background function for the x-ray-absorption fine structure (XAFS) of pure Pb at energies that are normally inaccessible because they are in the edge. The results of the two techniques are shown to give the same [chi]([ital k]) above a threshold energy in the absorption edge, where the background is 70% of the edge step. The reliability of the XAFS starting at unprecedentedly low [ital k] values (1.5 A[sup [minus]1] above the Fermi energy) allows sensitive tests of several details of theoretical XAFS calculations. Electron-hole-excitation losses in addition to the plasmon-pole loss term are shown to be important, and the Hedin-Lundqvist many-body self-energy is found to be superior to that of Dirac-Hara for pure Pb. One of the presented methods of background removal can be employed for general XAFS analysis, and is easily automated.

  1. X-ray continuum emission spectroscopy from hot dense matter at Gbar pressures

    SciTech Connect (OSTI)

    Kraus, D., E-mail: dominik.kraus@berkeley.edu; Falcone, R. W. [Department of Physics, University of California, Berkeley, California 94720 (United States); Döppner, T.; Kritcher, A. L.; Bachmann, B.; Collins, G. W.; Hawreliak, J. A.; Landen, O. L.; Ma, T.; Le Pape, S.; Swift, D. C. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Chapman, D. A. [Plasma Physics Group, Radiation Physics Department, AWE plc, Reading RG7 4PR, United Kingdom and Centre for Fusion, Space and Astrophysics, University of Warwick, Coventry CV4 7AL (United Kingdom); Glenzer, S. H. [SLAC National Accelerator Laboratory, Menlo Park, California 94309 (United States); Neumayer, P. [GSI Helmholtzzentrum für Schwerionenforschung, 64291 Darmstadt (Germany)

    2014-11-15T23:59:59.000Z

    We have measured the time-resolved x-ray continuum emission spectrum of ?30 times compressed polystyrene created at stagnation of spherically convergent shock waves within the Gbar fundamental science campaign at the National Ignition Facility. From an exponential emission slope between 7.7 keV and 8.1 keV photon energy and using an emission model which accounts for reabsorption, we infer an average electron temperature of 375 ± 21 eV, which is in good agreement with HYDRA-1D simulations.

  2. Photo-Induced Spin-State Conversion in Solvated Transition Metal Complexes Probed via Time-Resolved Soft X-ray Spectroscopy

    SciTech Connect (OSTI)

    Huse, Nils; Kim, Tae Kyu; Jamula, Lindsey; McCusker, James K.; de Groot, Frank M. F.; Schoenlein, Robert W.

    2010-04-30T23:59:59.000Z

    Solution-phase photoinduced low-spin to high-spin conversion in the FeII polypyridyl complex [Fe(tren(py)3)]2+ (where tren(py)3 is tris(2-pyridylmethyliminoethyl)amine) has been studied via picosecond soft X-ray spectroscopy. Following 1A1 --> 1MLCT (metal-to-ligand charge transfer) excitation at 560 nm, changes in the iron L2- and L3-edges were observed concomitant with formation of the transient high-spin 5T2 state. Charge-transfer multiplet calculations coupled with data acquired on low-spin and high-spin model complexes revealed a reduction in ligand field splitting of 1 eV in the high-spin state relative to the singlet ground state. A significant reduction in orbital overlap between the central Fe-3d and the ligand N-2p orbitals was directly observed, consistent with the expected ca. 0.2 Angstrom increase in Fe-N bond length upon formation of the high-spin state. The overall occupancy of the Fe-3d orbitals remains constant upon spin crossover, suggesting that the reduction in sigma-donation is compensated by significant attenuation of pi-back-bonding in the metal-ligand interactions. These results demonstrate the feasibility and unique potential of time-resolved soft X-ray absorption spectroscopy to study ultrafast reactions in the liquid phase by directly probing the valence orbitals of first-row metals as well as lighter elements during the course of photochemical transformations.

  3. In situ X-ray absorption fine structure studies of foreign metal ions in nickel hydrous oxide electrodes in alkaline electrolytes

    SciTech Connect (OSTI)

    Kim, Sunghyun; Tryk, D.A.; Scherson, D. (Case Western Reserve Univ., Cleveland, OH (United States)); Antonio, M.R. (Argonne National Lab., IL (United States)); Carr, R. (Stanford Synchrotron Radiation Lab., CA (United States))

    1994-10-06T23:59:59.000Z

    Aspects of the structural and electronic properties of hydrous oxide films of composite (9:1) Ni/Co and (9:1) Ni/Fe, prepared by electrodeposition, have been examined in alkaline electrolytes using in situ X-ray absorption fine structure (XAFS). An analysis of the X-ray absorption near the edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) for the Co and Fe K-edges of these composite hydrous oxides revealed that, regardless of the oxidation state of nickel sites in the films, the guest metal ions are present as Co[sup 3+] and Fe[sup 3+] and that the cobalt-oxygen distance d(Co-O) = 1.9 [+-] 0.02 [angstrom] and d(Fe-O) = 1.92 [+-] 0.02 [angstrom]. The latter values are in excellent agreement with d(Me-O) (Me = Co or Fe) in CoOOH and [beta]- and [gamma]-FeOOH, respectively, determined by conventional X-ray diffraction. Two clearly defined Me-Ni first coordination shells could be observed in the Fourier transforms (FT) of the K-edge EXAFS of the guest metal recorded at a potential at which both Ni[sup 2+] and Ni[sup 3+] sites are expected to be present. 28 refs., 10 figs., 3 tabs.

  4. SOFT X-RAY SPECTROSCOPY OF THE CYGNUS LOOP SUPERNOVA REMNANT

    SciTech Connect (OSTI)

    Oakley, Phil [Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, 77 Massachusetts Ave., 37-582F, Cambridge, MA 02139 (United States)] [Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, 77 Massachusetts Ave., 37-582F, Cambridge, MA 02139 (United States); McEntaffer, Randall [Department of Physics and Astronomy, Van Allen Hall, University of Iowa, Iowa City, IA 52242 (United States)] [Department of Physics and Astronomy, Van Allen Hall, University of Iowa, Iowa City, IA 52242 (United States); Cash, Webster, E-mail: Oakley@mit.edu [Center for Astrophysics and Space Astronomy, University of Colorado, Boulder, CO 80309 (United States)] [Center for Astrophysics and Space Astronomy, University of Colorado, Boulder, CO 80309 (United States)

    2013-03-20T23:59:59.000Z

    We present the results of a suborbital rocket flight whose scientific target was the Cygnus Loop Supernova Remnant. The payload consists of wire grid collimators, off-plane grating arrays, and gaseous electron multiplier (GEM) detectors. The system is designed for spectral measurements in the 17-107 A bandpass with a resolution up to {approx}60 ({lambda}/{Delta}{lambda}). The Extended X-ray Off-plane Spectrometer (EXOS) was launched on a Terrier-Black Brant rocket on 2009 November 13 from White Sands Missile Range and obtained 340 s of useable scientific data. The X-ray emission is dominated by O VII and O VIII, including the He-like O VII triplet at {approx}22 A. Another emission feature at {approx}45 A is composed primarily of Si XI and Si XII. The best-fit model to this spectrum is an equilibrium plasma model at a temperature of log(T) = 6.4 (0.23 keV).

  5. PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL

    SciTech Connect (OSTI)

    Phelan, B.T.; Myers, D.J.; Smith, M.C.

    2009-01-01T23:59:59.000Z

    State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratory’s Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

  6. Proceedings of the eighth international colloquium on ultraviolet and x-ray spectroscopy of astrophysical and laboratory plasmas (IAU colloquium 86)

    SciTech Connect (OSTI)

    Not Available

    1984-01-01T23:59:59.000Z

    This volume represents the Proceedings of the Eighth International Colloquium on Ultraviolet and X-Ray Spectroscopy of Astrophysical and Laboratory Plasmas. The aim of this series of colloquia has been to bring together workers in the fields of astrophysical spectroscopy, laboratory spectroscopy and atomic physics in order to exchange ideas and results on problems which are common to these different disciplines. In addition to the presented papers there was a poster paper session. (WRF)

  7. Non-matrix corrected organic sulfur determination by energy dispersive X-ray spectroscopy for western Kentucky coals and residues

    SciTech Connect (OSTI)

    Clark, C.P.; Freeman, G.B.; Hower, J.C.

    1984-01-01T23:59:59.000Z

    A method for non-matrix corrected organic sulfur analysis by energy dispersive X-ray spectroscopy has been developed using petroleum coke standards. Typically, electron beam microanalysis is a rapid, nondestructive analytical technique to quantitatively measure organic sulfur in coal. The results show good correlation to ASTM values for numerous well characterized coals with a wide range in total and pyritic sulfur content. This direct analysis is capable of reducing error commonly associated with the present ASTM method which relies on an indirect measure of organic sulfur by difference. The precision of the organic sulfur values determined in the present study is comparable to that obtained by ZAF matrix corrected microanalysis. The energy dispersive microanalysis is capable of measuring micro as well as bulk organic sulfur levels.

  8. X-ray photoelectron spectroscopy study of para-substituted benzoic acids chemisorbed to aluminum oxide thin films

    SciTech Connect (OSTI)

    Kreil, Justin; Ellingsworth, Edward; Szulczewski, Greg [Department of Chemistry, The University of Alabama, Shelby Hall, 250 Hackberry Lane, Tuscaloosa, Alabama 35487 (United States)] [Department of Chemistry, The University of Alabama, Shelby Hall, 250 Hackberry Lane, Tuscaloosa, Alabama 35487 (United States)

    2013-11-15T23:59:59.000Z

    A series of para-substituted, halogenated (F, Cl, Br, and I) benzoic acid monolayers were prepared on the native oxide of aluminum surfaces by solution self-assembly and spin-coating techniques. The monolayers were characterized by x-ray photoelectron spectroscopy (XPS) and water contact angles. Several general trends are apparent. First, the polarity of the solvent is critical to monolayer formation. Protic polar solvents produced low coverage monolayers; in contrast, nonpolar solvents produced higher coverage monolayers. Second, solution deposition yields a higher surface coverage than spin coating. Third, the thickness of the monolayers determined from XPS suggests the plane of the aromatic ring is perpendicular to the surface with the carboxylate functional group most likely binding in a bidentate chelating geometry. Fourth, the saturation coverage (?2.7 × 10{sup 14} molecules cm{sup ?2}) is independent of the para-substituent.

  9. Electronic structure of Al- and Ga-doped ZnO films studied by hard X-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Gabás, M.; Ramos Barrado, José R. [Lab. de Materiales and Superficies, Dpto. de Física Aplicada I, Universidad de Málaga, 29071 Málaga (Spain); Torelli, P. [Laboratorio TASC, IOM-CNR, S.S. 14 km 163.5, Basovizza, I-34149 Trieste (Italy); Barrett, N. T. [CEA, DSM/IRAMIS/SPCSI, F-91191 Gif-sur-Yvette Cedex (France); Sacchi, M. [Synchrotron SOLEIL, BP 48, 91192 Gif-sur-Yvette, France and Institut des NanoSciences de Paris, UPMC Paris 06, CNRS UMR 7588, 4 Place Jussieu, 75005 Paris (France)

    2014-01-01T23:59:59.000Z

    Al- and Ga-doped sputtered ZnO films (AZO, GZO) are semiconducting and metallic, respectively, despite the same electronic valence structure of the dopants. Using hard X-ray photoelectron spectroscopy we observe that both dopants induce a band in the electronic structure near the Fermi level, accompanied by a narrowing of the Zn 3d/O 2p gap in the valence band and, in the case of GZO, a substantial shift in the Zn 3d. Ga occupies substitutional sites, whereas Al dopants are in both substitutional and interstitial sites. The latter could induce O and Zn defects, which act as acceptors explaining the semiconducting character of AZO and the lack of variation in the optical gap. By contrast, mainly substitutional doping is consistent with the metallic-like behavior of GZO.

  10. Fuel Injection and Spray Research Using X-Ray Diagnostics

    Broader source: Energy.gov (indexed) [DOE]

    temperature ambient (plastic windows) 5 Radiography - Monochromatic x-rays - Absorption of x-rays by the fuel - Ensemble averaged (flux limited) - Room temperature ambient...

  11. Fuel Injection and Spray Research Using X-Ray Diagnostics

    Broader source: Energy.gov (indexed) [DOE]

    by ECN using several different techniques - Silicone molds (Valencia) - X-ray absorption tomography (CAT) - X-Ray phase contrast imaging (Argonne) - Microscopy (Sandia) ...

  12. Combining Feedback Absorption Spectroscopy, Amplified Resonance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compounds in Automotive Emissions Discusses a novel combination of multi-component scanning direct absorption spectroscopy, resonant cavity and low-pressure sampling to...

  13. X-ray and EUV Spectroscopy of the Boundary Layer Emission of Nonmagnetic Cataclysmic Variables

    E-Print Network [OSTI]

    Christopher W. Mauche

    1997-09-11T23:59:59.000Z

    EUVE, ROSAT, and ASCA observations of the boundary layer emission of nonmagnetic cataclysmic variables (CVs) are reviewed. EUVE spectra reveal that the effective temperature of the soft component of high-Mdot nonmagnetic CVs is kT ~ 10-20 eV and that its luminosity is ~ 0.1-0.5 times the accretion disk luminosity. Although the EUV spectra are very complex and belie simple interpretation, the physical conditions of the boundary layer gas are constrained by emission lines of highly ionized Ne, Mg, Si, and Fe. ROSAT and ASCA spectra of the hard component of nonmagnetic CVs are satisfactorily but only phenomenologically described by multi-temperature thermal plasmas, and the constraints imposed on the physical conditions of this gas are limited by the relatively weak and blended lines. It is argued that significant progress in our understanding of the X-ray spectra of nonmagnetic CVs will come with future observations with XMM, AXAF, and Astro-E.

  14. Suzaku Spectroscopy Study of Hard X-Ray Emission in the Arches Cluster

    E-Print Network [OSTI]

    M. Tsujimoto; Y. Hyodo; K. Koyama

    2006-11-03T23:59:59.000Z

    We present the results of a Suzaku study of the Arches cluster. A high S/N spectrum in the 3-12 keV band was obtained with the XIS. We found that the spectrum consists of a thermal plasma, a hard power-law tail, and two Gaussian lines. The plasma component (kT~2.2 keV) is established from the presence of CaXIX and FeXXV K alpha lines as well as the absence of FeXXVI K alpha line. The two Gaussian lines represent the K alpha and beta lines from iron at lower ionization stages. Both the line centers and the intensity ratio of these two lines are consistent with the neutral iron. The hard power-law tail (index~0.7) was found to have no pronounced iron K edge feature. In comparison with the published Chandra spectra, we conclude that the thermal component is from the ensemble of point-like sources plus thermal diffuse emission concentrated at the cluster center, while the Gaussian and the hard tail components are from the non-thermal diffuse emission extended in a larger scale. In the band-limited XIS images, the distribution of the 7.5-10.0 keV emission resembles that of the 6.4 keV emission. This strongly suggests that the power-law emission is related to the 6.4 and 7.1 keV lines in the underlying physics. We discuss two ideas to explain both the hard continuum and the lines: (1) X-ray photoionization that produces fluorescence lines and the Thomson scattering continuum and (2) non-thermal electron impact ionization of iron atoms and bremsstrahlung continuum. But whichever scenario is adopted, the photon or particle flux from the Arches cluster is too low to account for the observed line and continuum intensity.

  15. X-ray diffraction and extended X-ray absorption fine structure study of epitaxial mixed ternary bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} (x = 0-2) films on Si (111)

    SciTech Connect (OSTI)

    Niu, G.; Zoellner, M. H.; Zaumseil, P. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Pouliopoulos, A. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); D'Acapito, F. [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, F. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France)

    2013-01-28T23:59:59.000Z

    Ternary single crystalline bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} films over the full stoichiometry range (x = 0-2) have been epitaxially grown on Si (111) with tailored electronic and crystallographic structure. In this work, we present a detailed study of their local atomic environment by extended X-ray absorption fine structure at both Y K and Pr L{sub III} edges, in combination with complementary high resolution x-ray diffraction measurements. The local structure exhibits systematic variations as a function of the film composition. The cation coordination in the second and third coordination shells changes with composition and is equal to the average concentration, implying that the Pr{sub x}Y{sub 2-x}O{sub 3} films are indeed fully mixed and have a local bixbyite structure with random atomic-scale ordering. A clear deviation from the virtual crystal approximation for the cation-oxygen bond lengths is detected. This demonstrates that the observed Vegard's law for the lattice variation as a function of composition is based microscopically on a more complex scheme related to local structural distortions which accommodate the different cation-oxygen bond lengths.

  16. Characterization of Chain Molecular Assemblies in Long-Chain, Layered Silver Thiolates: A Joint Infrared Spectroscopy and X-ray Diffraction Study

    E-Print Network [OSTI]

    Parikh, Atul N.

    , and Theoretical DiVisions, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 ReceiVed: October 1, 1998 of infrared transmission spectroscopy and powder X-ray diffraction. The structural attributes elucidated. The three-dimensional network of 1D channels alternates between the chain layers. All the chain structural

  17. Broadband X-ray Imaging and Spectroscopy of the Crab Nebula and Pulsar with NuSTAR

    E-Print Network [OSTI]

    Madsen, Kristin K; Harrison, Fiona; An, Hongjun; Boggs, Steven; Christensen, Finn E; Craig, William W; Fryer, Chris L; Grefenstette, Brian W; Hailey, Charles J; Markwardt, Craig; Nynka, Melania; Stern, Daniel; Zoglauer, Andreas; Zhang, William

    2015-01-01T23:59:59.000Z

    We present broadband (3 -- 78 keV) NuSTAR X-ray imaging and spectroscopy of the Crab nebula and pulsar. We show that while the phase-averaged and spatially integrated nebula + pulsar spectrum is a power-law in this energy band, spatially resolved spectroscopy of the nebula finds a break at $\\sim$9 keV in the spectral photon index of the torus structure with a steepening characterized by $\\Delta\\Gamma\\sim0.25$. We also confirm a previously reported steepening in the pulsed spectrum, and quantify it with a broken power-law with break energy at $\\sim$12 keV and $\\Delta\\Gamma\\sim0.27$. We present spectral maps of the inner 100\\as\\ of the remnant and measure the size of the nebula as a function of energy in seven bands. These results find that the rate of shrinkage with energy of the torus size can be fitted by a power-law with an index of $\\gamma = 0.094\\pm 0.018$, consistent with the predictions of Kennel and Coroniti (1984). The change in size is more rapid in the NW direction, coinciding with the counter-jet w...

  18. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Axnanda, Stephanus [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Crumlin, Ethan J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Mao, Baohua [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Rani, Sana [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chang, Rui [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Karlsson, Patrik G. [VG Scienta,Uppsala (Sweden); Edwards, Mårten O. M. [VG Scienta,Uppsala (Sweden); Lundqvist, Måns [VG Scienta,Uppsala (Sweden); Moberg, Robert [VG Scienta,Uppsala (Sweden); Ross, Phil [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Hussain, Zahid [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Liu, Zhi [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Shanghai Tech Univ., Shanghai (China)

    2015-05-07T23:59:59.000Z

    We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²? and Pt?? interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.

  19. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Axnanda, Stephanus; Crumlin, Ethan J.; Mao, Baohua; Rani, Sana; Chang, Rui; Karlsson, Patrik G.; Edwards, Mårten O. M.; Lundqvist, Måns; Moberg, Robert; Ross, Phil; et al

    2015-05-07T23:59:59.000Z

    We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquidmore »and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²? and Pt?? interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.« less

  20. Elemental content of enamel and dentin after bleaching of teeth (a comparative study between laser-induced breakdown spectroscopy and x-ray photoelectron spectroscopy)

    SciTech Connect (OSTI)

    Imam, H. [National Institute of Laser Enhanced Sciences, NILES, Cairo University, Giza (Egypt)] [National Institute of Laser Enhanced Sciences, NILES, Cairo University, Giza (Egypt); Ahmed, Doaa [Department of Restorative Sciences, Faculty of Dentistry, Alexandria University, Alexandria (Egypt)] [Department of Restorative Sciences, Faculty of Dentistry, Alexandria University, Alexandria (Egypt); Eldakrouri, Ashraf [National Institute of Laser Enhanced Sciences, NILES, Cairo University, Giza (Egypt) [National Institute of Laser Enhanced Sciences, NILES, Cairo University, Giza (Egypt); Department of Optometry and Vision Science, College of Applied Medical Science, King Saud University, Riyadh (Saudi Arabia)

    2013-06-21T23:59:59.000Z

    The elemental content of the superficial and inner enamel as well as that of dentin was analyzed using laser-induced breakdown spectroscopy (LIBS) and x-ray photoelectron spectroscopy (XPS) of bleached and unbleached tooth specimens. It is thus clear from the spectral analysis using both the LIBS and XPS technique that elemental changes (though insignificant within the scopes of this study) of variable intensities do occur on the surface of the enamel and extend deeper to reach dentin. The results of the LIBS revealed a slight reduction in the calcium levels in the bleached compared to the control specimens in all the different bleaching groups and in both enamel and dentin. The good correlation found between the LIBS and XPS results demonstrates the possibility of LIBS technique for detection of minor loss in calcium and phosphorus in enamel and dentin.

  1. Percolative superconductivity in La{sub 2}CuO{sub 4.06} by lattice granularity patterns with scanning micro x-ray absorption near edge structure

    SciTech Connect (OSTI)

    Poccia, Nicola [MESA Institute for Nanotechnology, University of Twente, P. O. Box 217, 7500AE Enschede (Netherlands); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Chorro, Matthieu [Synchrotron SOLEIL L'Orme des Merisiers, 91190 Paris S.Aubin (France); Ricci, Alessandro [Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, D-22607 Hamburg (Germany); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Xu, Wei [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Marcelli, Augusto [Istituto Nazionale di Fisica Nucleare - Laboratori Nazionali di Frascati, 00044 Frascati, Rome (Italy); NSRL, University of Science and Technology of China, Hefei 230026 (China); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Campi, Gaetano [Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Bianconi, Antonio [RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy)

    2014-06-02T23:59:59.000Z

    The simplest cuprate superconductor La{sub 2}CuO{sub 4+y} with mobile oxygen interstitials exhibits a clear phase separation. It is known that oxygen interstitials enter into the rocksalt La{sub 2}O{sub 2+y} spacer layers forming oxygen interstitials rich puddles and poor puddles but only recently a bulk multiscale structural phase separation has been observed by using scanning micro X-ray diffraction. Here we get further information on their spatial distribution, using scanning La L{sub 3}-edge micro X-ray absorption near edge structure. Percolating networks of oxygen rich puddles are observed in different micrometer size portions of the crystals. Moreover, the complex surface resistivity shows two jumps associated to the onset of intra-puddle and inter-puddles percolative superconductivity. The similarity of oxygen doped La{sub 2}CuO{sub 4+y}, with the well established phase separation in iron selenide superconductors is also discussed.

  2. X-ray Absorption Measurements on Nickel Cathode of Sodium-beta Alumina batteries: Fe-Ni-CI Chemical Associations

    SciTech Connect (OSTI)

    Bowden, Mark E.; Alvine, Kyle J.; Fulton, John L.; Lemmon, John P.; Lu, Xiaochuan; Webb-Robertson, Bobbie-Jo M.; Heald, Steve M.; Balasubramanian, Mahalingam; Mortensen, Devon R.; Seidler, Gerald T.; Hess, Nancy J.

    2014-02-01T23:59:59.000Z

    Sections of Na-Al-NiCl2 cathodes from sodium-beta alumina ZEBRA batteries have been characterized with X-ray fluorescence mapping, and XANES measurements to probe the microstructure, elemental correlation, and chemical speciation after voltage cycling. Cycling was performed under identical load conditions at either 240 or 280 °C operating temperature and subsequently quenched in either the charged or discharged state. X-ray fluorescence mapping and XANES measurements were made adjacent to the current collector and ?"-Al2O3 solid electrolyte interfaces to detect possible gradients in chemical properties across the cathode. An FeS additive, introduced during battery synthesis, was found to be present as either Fe metal or an Fe(II) chloride in all cathode samples. X-ray fluorescence mapping reveals an operating temperature and charge-state dependent spatial correlation between Fe, Ni, and Cl concentration. XANES measurements indicate that both Ni and Fe are chemically reactive and shift between metallic and chloride phases in the charged and discharged states, respectively. However the percentage of chemically active Ni and Fe is significantly less in the cell operated at lower temperature. Additionally, the cathode appeared chemically homogeneous at the scale of our X-ray measurements.

  3. Band offsets of TiZnSnO/Si heterojunction determined by x-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Sun, R. J.; Jiang, Q. J.; Yan, W. C.; Feng, L. S.; Lu, B.; Ye, Z. Z. [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Li, X. F. [Key Laboratory of Advanced Display and System Application, Ministry of Education, Shanghai University, Shanghai 200072 (China); Li, X. D. [Xinyi PV Products (Anhui) Holdings LTD, Xinyi PV Glass Industrial Zone, No. 2 Xinyi Road, ETDZ, Wuhu 241009 (China); Lu, J. G., E-mail: lujianguo@zju.edu.cn [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Key Laboratory of Advanced Display and System Application, Ministry of Education, Shanghai University, Shanghai 200072 (China)

    2014-09-28T23:59:59.000Z

    X-ray photoelectron spectroscopy (XPS) was utilized to measure the valence band offset (?E{sub V}) of the TiZnSnO (TZTO)/Si heterojunction. TZTO films were deposited on Si (100) substrates using magnetron sputtering at room temperature. By using the Zn 2p{sub 3/2} and Sn 3d{sub 5/2} energy levels as references, the value of ?E{sub V} was calculated to be 2.69 ± 0.1 eV. Combining with the experimental optical energy band gap of 3.98 eV for TZTO extracted from the UV-vis transmittance spectrum, the conduction band offset (?E{sub C}) was deduced to be 0.17 ± 0.1 eV at the interface. Hence, the energy band alignment of the heterojunction was determined accurately, showing a type-I form. This will be beneficial for the design and application of TZTO/Si hybrid devices.

  4. In-situ X-ray photoelectron spectroscopy studies of water on metals and oxides at ambient conditions

    SciTech Connect (OSTI)

    Salmeron, Miquel; Yamamoto, S.; Bluhm, H.; Andersson, K.; Ketteler, G.; Ogasawara, H.; Salmeron, M.; Nilsson, A.

    2007-10-29T23:59:59.000Z

    X-ray photoelectron spectroscopy (XPS) is a powerful tool for surface and interface analysis, providing the elemental composition of surfaces and the local chemical environment of adsorbed species. Conventional XPS experiments have been limited to ultrahigh vacuum (UHV) conditions due to a short mean free path of electrons in a gas phase. The recent advances in instrumentation coupled with third-generation synchrotron radiation sources enables in-situ XPS measurements at pressures above 5 Torr. In this review, we describe the basic design of the ambient pressure XPS setup that combines differential pumping with an electrostatic focusing. We present examples of the application of in-situ XPS to studies of water adsorption on the surface of metals and oxides including Cu(110), Cu(111), TiO2(110) under environmental conditions of water vapor pressure. On all these surfaces we observe a general trend where hydroxyl groups form first, followed by molecular water adsorption. The importance of surface OH groups and their hydrogen bonding to water molecules in water adsorption on surfaces is discussed in detail.

  5. Analysis of the surface of tricalcium silicate during the induction period by X-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Bellmann, F., E-mail: frank.bellmann@uni-weimar.de [Institute for Building Materials Science, Bauhaus University Weimar, 99423 Weimar (Germany); Sowoidnich, T.; Ludwig, H.-M. [Institute for Building Materials Science, Bauhaus University Weimar, 99423 Weimar (Germany)] [Institute for Building Materials Science, Bauhaus University Weimar, 99423 Weimar (Germany); Damidot, D. [Ecole des Mines de Douai, Civil and Environmental Engineering Department, 941 rue Charles Bourseul, BP 10838, 59508 Doua cedex (France)] [Ecole des Mines de Douai, Civil and Environmental Engineering Department, 941 rue Charles Bourseul, BP 10838, 59508 Doua cedex (France)

    2012-09-15T23:59:59.000Z

    X-ray photoelectron spectroscopy allows the analysis of surface layers with a thickness of a few nanometers. The method is sensitive to the chemical environment of the atoms since the binding energy of the electrons depends on the chemical bonds to neighboring atoms. It has been applied to the hydration of tricalcium silicate (Ca{sub 3}SiO{sub 5}, C{sub 3}S) by analyzing a sample after 30 min of hydration. Also two references have been investigated namely anhydrous C{sub 3}S and intermediate phase in order to enable a quantitative evaluation of the experimental data. In the hydrated C{sub 3}S sample, the analyzed volume (0.2 mm{sup 2} surface by 13 nm depth) contained approximately 44 wt.% of C{sub 3}S and 56 wt.% of intermediate phase whereas C-S-H was not detected. Scanning Electron Microscopy data and geometric considerations indicate that the intermediate phase forms a thin layer having a thickness of approximately 2 nm and covers the complete surface instead of forming isolated clusters.

  6. Atomic-Scale Chemical Imaging and Quantification of Metallic Alloy Structures by Energy-Dispersive X-Ray Spectroscopy

    SciTech Connect (OSTI)

    Lu, Ping [Sandia National Laboratories; Zhou, Lin [Ames Laboratory; Kramer, Matthew J. [Ames Laboratory; Smith, David J. [Arizona State University

    2014-02-04T23:59:59.000Z

    Determination of atomic-scale crystal structure for nanostructured intermetallic alloys, such as magnetic alloys containing Al, Ni, Co (alnico) and Fe, is crucial for understanding physical properties such as magnetism, but technically challenging due to the small interatomic distances and the similar atomic numbers. By applying energy-dispersive X-ray spectroscopy (EDS) mapping to the study of two intermetallic phases of an alnico alloy resulting from spinodal decomposition, we have determined atomic-scale chemical composition at individual lattice sites for the two phases: one is the B2 phase with Fe0.76Co0.24 -Fe0.40Co0.60 ordering and the other is the L21 phase with Ni0.48Co0.52 at A-sites, Al at B?-sites and Fe0.20Ti0.80 at B??-sites, respectively. The technique developed through this study represents a powerful real-space approach to investigate structure chemically at the atomic scale for a wide range of materials systems.

  7. Absorption spectroscopy of a laboratory photoionized plasma experiment at Z

    SciTech Connect (OSTI)

    Hall, I. M.; Durmaz, T.; Mancini, R. C. [Physics Department, University of Nevada, Reno, Nevada 89557 (United States)] [Physics Department, University of Nevada, Reno, Nevada 89557 (United States); Bailey, J. E.; Rochau, G. A. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)] [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); Golovkin, I. E.; MacFarlane, J. J. [Prism Computational Sciences, Madison, Wisconsin 53711 (United States)] [Prism Computational Sciences, Madison, Wisconsin 53711 (United States)

    2014-03-15T23:59:59.000Z

    The Z facility at the Sandia National Laboratories is the most energetic terrestrial source of X-rays and provides an opportunity to produce photoionized plasmas in a relatively well characterised radiation environment. We use detailed atomic-kinetic and spectral simulations to analyze the absorption spectra of a photoionized neon plasma driven by the x-ray flux from a z-pinch. The broadband x-ray flux both photoionizes and backlights the plasma. In particular, we focus on extracting the charge state distribution of the plasma and the characteristics of the radiation field driving the plasma in order to estimate the ionisation parameter.

  8. Separable-spherical-wave approximation: Application to x-ray-absorption fine-structure multiple scattering in ReO sub 3

    SciTech Connect (OSTI)

    Houser, B. (Department of Physics, MS 68, Eastern Washington University, Cheney, Washington 99004 (United States)); Ingalls, R.; Rehr, J.J. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1992-04-01T23:59:59.000Z

    Rehr and Albers have shown that the exact x-ray-absorption fine-structure (XAFS) propagator may be expanded in a separable matrix form, and that the lowest-order term in the expansion yields XAFS formulas that contain spherical-wave corrections, yet retain the simplicity of the plane-wave approximation. This separable-spherical-wave approximation was used to model the multiple-scattering contributions to the XAFS spectrum of rhenium trioxide. We report a modest improvement over the plane-wave approximation.

  9. Resonant soft X-ray emission spectroscopy of vanadium oxides andrelated compounds

    SciTech Connect (OSTI)

    Schmitt, Thorsten

    2004-11-01T23:59:59.000Z

    In today's information world, bits of data are processed by semiconductor chips, and stored in the magnetic disk drives. But tomorrow's information technology may see magnetism (spin) and semiconductivity (charge) combined in one ''spintronic'' device that exploits both charge and ''spin'' to carry data (the best of two worlds). Spintronic devices such as spin valve transistors, spin light emitting diodes, non-volatile memory, logic devices, optical isolators and ultra-fast optical switches are some of the areas of interest for introducing the ferromagnetic properties at room temperature in a semiconductor to make it multifunctional. The potential advantages of such spintronic devices will be higher speed, greater efficiency, and better stability at a reduced power consumption. This Thesis contains two main topics: In-depth understanding of magnetism in Mn doped ZnO, and our search and identification of at least six new above room temperature ferromagnetic semiconductors. Both complex doped ZnO based new materials, as well as a number of nonoxides like phosphides, and sulfides suitably doped with Mn or Cu are shown to give rise to ferromagnetism above room temperature. Some of the highlights of this work are discovery of room temperature ferromagnetism in: (1) ZnO:Mn (paper in Nature Materials, Oct issue, 2003); (2) ZnO doped with Cu (containing no magnetic elements in it); (3) GaP doped with Cu (again containing no magnetic elements in it); (4) Enhancement of Magnetization by Cu co-doping in ZnO:Mn; and (5) CdS doped with Mn, and a few others not reported in this thesis. We discuss in detail the first observation of ferromagnetism above room temperature in the form of powder, bulk pellets, in 2-3 {micro}m thick transparent pulsed laser deposited films of the Mn (< 4 at.%) doped ZnO. High-resolution transmission electron microscopy (HRTEM) and electron energy loss spectroscopy (EELS) spectra recorded from 2 to 200nm areas showed homogeneous distribution of Mn substituting for Zn a 2{sup +} state in the ZnO lattice. Ferromagnetic Resonance (FMR) technique is used to confirm the existence of ferromagnetic ordering at temperatures as high as 425K. The ab initio calculations were found to be consistent with the observation of ferromagnetism arising from fully polarized Mn 2{sup +} state. The key to observed room temperature ferromagnetism in this system is the low temperature processing, which prevents formation of clusters, secondary phases and the host ZnO from becoming n-type. The electronic structure of the same Mn doped ZnO thin films studied using XAS, XES and RIXS. revealed a strong hybridization between Mn 3d and O 2p states, which is an important characteristic of a Dilute magnetic Semiconductor (DMS). It is shown that the various processing conditions like sintering temperature, dopant concentration and the properties of precursors used for making of DMS have a great influence on the final properties. Use of various experimental techniques to verify the physical properties, and to understand the mechanism involved to give rise to ferromagnetism is presented. Methods to improve the magnetic moment in Mn doped ZnO are also described. New promising DMS materials (such as Cu doped ZnO are explored). The demonstrated new capability to fabricate powder, pellets, and thin films of room temperature ferromagnetic semiconductors thus makes possible the realization of a wide range of complex elements for a variety of new multifunctional phenomena related to Spintronic devices as well as magneto-optic components.

  10. Investigating Silicon-Based Photoresists with Coherent Anti-Stokes Raman Scattering and X-ray Micro-spectroscopy

    E-Print Network [OSTI]

    Caster, Allison G.

    2010-01-01T23:59:59.000Z

    LIGHT (X- RAYS , EUV, ULTRAFAST PULSES ), OR HEAT . T HEthe “on” time of an ultrafast pulse is referred to as thepeak-power of the ultrafast pulses, purely electronic four-

  11. Fabrication of high-throughput critical-angle X-ray transmission gratings for wavelength-dispersive spectroscopy

    E-Print Network [OSTI]

    Bruccoleri, Alexander Robert

    2013-01-01T23:59:59.000Z

    The development of the critical-angle transmission (CAT) grating seeks both an order of magnitude improvement in the effective area, and a factor of three increase in the resolving power of future space-based, soft x-ray ...

  12. The determination of interfacial structure and phase transitions in Al/Cu and Al/Ni interfaces by means of surface extended x-ray absorption fine structure

    SciTech Connect (OSTI)

    Barrera, E.V. (Rice Univ., Houston, TX (United States). Dept. of Mechanical Engineering and Materials Science); Heald, S.M. (Brookhaven National Lab., Upton, NY (United States))

    1991-01-01T23:59:59.000Z

    Surface extended x-ray absorption fine structure (SEXAFS) was used to investigate the interfacial conditions of Al/Cu and Al/Ni shallow buried interfaces. Previous studies using glancing angle extended x-ray absorption fine structure, x-ray reflectivity, photoemission, and SEXAFS produced conflicting results as to whether or not the interfaces between Al and Cu and Al and Ni were reacted upon room temperature deposition. In this study polycrystalline bilayers of Al/Cu and Al/Ni and trilayers of Al/Cu/Al and Al/Ni/Al were deposited on tantalum foil at room temperature in ultra high vacuum and analyzed to evaluate the reactivity of these systems on a nanometer scale. It become overwhelming apparent that the interfacial phase reactions were a function of the vacuum conditions. Samples deposited with the optimum vacuum conditions showed reaction products upon deposition at room temperature which were characterized by comparisons to standards and by least squares fitting the be CuAl{sub 2} and NiAl{sub 3} respectively. The results of this study that the reacted zone thicknesses were readily dependent on the deposition parameters. For both Al on Cu and Al on Ni as well as the metal on Al conditions 10{Angstrom} reaction zones were observed. These reaction zones were smaller than that observed for bilayers of Al on Cu (30{Angstrom}) and Al on Ni (60{Angstrom}) where deposition rates were much higher and samples were much thicker. The reaction species are evident by SEXAFS, where the previous photoemission studies only indicated that changes had occurred. Improved vacuum conditions as compared to the earlier experiments is primarily the reason reactions on deposition were seen in this study as compared to the earlier SEXAFS studies.

  13. The determination of interfacial structure and phase transitions in Al/Cu and Al/Ni interfaces by means of surface extended x-ray absorption fine structure

    SciTech Connect (OSTI)

    Barrera, E.V. [Rice Univ., Houston, TX (United States). Dept. of Mechanical Engineering and Materials Science; Heald, S.M. [Brookhaven National Lab., Upton, NY (United States)

    1991-12-31T23:59:59.000Z

    Surface extended x-ray absorption fine structure (SEXAFS) was used to investigate the interfacial conditions of Al/Cu and Al/Ni shallow buried interfaces. Previous studies using glancing angle extended x-ray absorption fine structure, x-ray reflectivity, photoemission, and SEXAFS produced conflicting results as to whether or not the interfaces between Al and Cu and Al and Ni were reacted upon room temperature deposition. In this study polycrystalline bilayers of Al/Cu and Al/Ni and trilayers of Al/Cu/Al and Al/Ni/Al were deposited on tantalum foil at room temperature in ultra high vacuum and analyzed to evaluate the reactivity of these systems on a nanometer scale. It become overwhelming apparent that the interfacial phase reactions were a function of the vacuum conditions. Samples deposited with the optimum vacuum conditions showed reaction products upon deposition at room temperature which were characterized by comparisons to standards and by least squares fitting the be CuAl{sub 2} and NiAl{sub 3} respectively. The results of this study that the reacted zone thicknesses were readily dependent on the deposition parameters. For both Al on Cu and Al on Ni as well as the metal on Al conditions 10{Angstrom} reaction zones were observed. These reaction zones were smaller than that observed for bilayers of Al on Cu (30{Angstrom}) and Al on Ni (60{Angstrom}) where deposition rates were much higher and samples were much thicker. The reaction species are evident by SEXAFS, where the previous photoemission studies only indicated that changes had occurred. Improved vacuum conditions as compared to the earlier experiments is primarily the reason reactions on deposition were seen in this study as compared to the earlier SEXAFS studies.

  14. X-ray diffraction and EXAFS analysis of materials for lithium-based rechargeable batteries

    SciTech Connect (OSTI)

    Sharkov, M. D., E-mail: mischar@mail.ioffe.ru; Boiko, M. E.; Bobyl, A. V.; Ershenko, E. M.; Terukov, E. I. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Zubavichus, Y. V. [National Research Centre “Kurchatov Institute” (Russian Federation)

    2013-12-15T23:59:59.000Z

    Lithium iron phosphate LiFePO{sub 4} (triphylite) and lithium titanate Li{sub 4}Ti{sub 5}O{sub 12} are used as components of a number of active materials in modern rechargeable batteries. Samples of these materials are studied by X-ray diffraction and extended X-ray absorption fine structure (EXAFS) spectroscopy. Hypotheses about the phase composition of the analyzed samples are formulated.

  15. A Fast, Versatile Nanoprobe for Complex Materials: The Sub-micron Resolution X-ray Spectroscopy Beamline at NSLS-II (491st Brookhaven Lecture)

    SciTech Connect (OSTI)

    Thieme, Juergen [BNL Photon Sciences Directorate

    2014-02-06T23:59:59.000Z

    Time is money and for scientists who need to collect data at research facilities like Brookhaven Lab’s National Synchrotron Light Source (NSLS), “beamtime” can be a precious commodity. While scanning a complex material with a specific technique and standard equipment today would take days to complete, researchers preparing to use brighter x-rays and the new sub-micron-resolution x-ray spectroscopy (SRX) beamline at the National Synchrotron Light Source II (NSLS-II) could scan the same sample in greater detail with just a few hours of beamtime. Talk about savings and new opportunities for researchers! Users will rely on these tools for locating trace elements in contaminated soils, developing processes for nanoparticles to deliver medical treatments, and much more. Dr. Thieme explains benefits for next-generation research with spectroscopy and more intense x-rays at NSLS-II. He discusses the instrumentation, features, and uses for the new SRX beamline, highlighting its speed, adjustability, and versatility for probing samples ranging in size from millimeters down to the nanoscale. He will talk about complementary beamlines being developed for additional capabilities at NSLS-II as well.

  16. Spectroscopy of M-shell x-ray transitions in Zn-like through Co-like W

    SciTech Connect (OSTI)

    Clementson, J; Beiersdorfer, P; Brown, G V; Gu, M F

    2009-07-08T23:59:59.000Z

    The M-shell x-ray emission of highly charged tungsten ions has been investigated at the Livermore electron beam ion trap facility. Using the SuperEBIT electron beam ion trap and a NASA x-ray calorimeter array, transitions connecting the ground configurations in the 1500-3600 eV spectral range of zinc-like W{sup 44+} through cobalt-like W{sup 47+} have been measured. The measured spectra are compared with theoretical line positions and emissivities calculated using the FAC code.

  17. NuSTAR STUDY OF HARD X-RAY MORPHOLOGY AND SPECTROSCOPY OF PWN G21.5–0.9

    E-Print Network [OSTI]

    Nynka, Melania

    We present NuSTAR high-energy X-ray observations of the pulsar wind nebula (PWN)/supernova remnant G21.5–0.9. We detect integrated emission from the nebula up to ~40 keV, and resolve individual spatial features over a broad ...

  18. Soft x-ray spectroscopy beam line on the NSLS Xl undulator: Optical design and first performance tests

    E-Print Network [OSTI]

    Homes, Christopher C.

    generationof soft x-ray undulator beam lines which will figure prominently at new synchrotron radiation facilities such as ALS, ELETTRA and BESSY II. During the first performancetestsabsorption spectra of simple-ray region. 1. INTRODUCTION The next generationof synchrotron radiation (SR) fa- cilities servingthe soft x

  19. Journal of Electron Spectroscopy and Related Phenomena 144147 (2005) 259269 Soft X-ray spectromicroscopy of biological

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    in the case of electron beam based techniques; radiation damage in the case of electron microscopy; lack. This requires a source of bright, continu- ouslytunablesoftX-rays(50­2000 eV),andthussynchrotron radiation spatial reso- lution in the case of IR, NMR and optical techniques; inabil- ity to couple to wet specimens

  20. AugEX: AUGER ELECTRON AND X-RAY SPECTROMETER ON CHANDRAYAAN-2 ROVER

    E-Print Network [OSTI]

    Bapat, Bhas

    for determining elemental composition which have a space heritage X-Ray Fluorescence (XRF) Particle-induced X-ray fluorescence (XRF) Expected Advantage: cover low Z elements with higher sensitivity than XRF or PIXE. ACHARYA-ray absorption or charged particle bombardment X-ray emission induced by X-ray absorption: XRF X-ray emission

  1. High-Dispersion Spectroscopy of the X-Ray Transient RXTE J0421+560 (= CI Cam) during Outburst

    E-Print Network [OSTI]

    Edward L. Robinson; Inese I. Ivans; William F. Welsh

    2001-10-04T23:59:59.000Z

    We obtained high dispersion spectra of CI Cam, the optical counterpart of XTE J0421+560, two weeks after the peak of its short outburst in 1998 April. The optical counterpart is a supergiant B[e] star emitting a two-component wind. The cool wind (the source of narrow emission lines of neutral and ionized metals) has a velocity of 32 km/s and a temperature near 8000 K. Dense and roughly spherical, it fills the space around the sgB[e] star, and, based on the size of an infrared-emitting dust shell around the system, extends to a radius between 13 - 50 AU. It carries away mass at a high rate, Mdot > 10^(-6) solar masses per year. The hot wind has a velocity in excess of 2500 km/s and a temperature of 1.7 +/-0.3 x 10^4 K. From UV spectra of CI Cam obtained in 2000 March with Hubble Space Telescope, we derive a differential extinction E(B-V) = 0.85 +/- 0.05. We derive a distance to CI Cam > 5 kpc. Based on this revised distance, the X-ray luminosity at the peak of the outburst was L(2-25 keV) > 3.0 x 10^38 erg/s, making CI Cam one of the most luminous X-ray transients. The ratio of quiescent to peak luminosity in the 2 - 25 keV band is < 1.7 x 10^(-6). The compact star in CI Cam is immersed in the dense circumstellar wind from the sgB[e] star and burrows through the wind producing little X-ray emission except for rare transient outbursts. This picture (a compact star traveling in a wide orbit through the dense circumstellar envelope of a sgB[e] star, occasionally producing transient X-ray outbursts) makes CI Cam unique among the known X-ray binaries. Strong circumstantial evidence suggests that the compact object is a black hole, not a neutron star. We speculate that the X-ray outburst was short because the accretion disk around the compact star is fed from a stellar wind and is smaller than disks fed by Roche-lobe overflow.

  2. Hazards analysis for the E.O. Lawrence Berkeley National Laboratory x-ray absorption experiments to be performed at Stanford Synchrotron Radiation Laboratory

    SciTech Connect (OSTI)

    Edelstein, N.M.; Shuh, D.K.; Bucher, J.B. [Lawrence Berkeley National Lab., CA (United States). Chemical Sciences Div.

    1995-04-01T23:59:59.000Z

    The objective of this experiment is to determine the oxidation state(s) of neptunium (Np) in mouse skeleton and in soft tissue by X-ray Absorption Near Edge Structure (XANES). If Np is present in sufficient concentration, X-ray Absorption Fine Structure (XAFS) data will be obtained in order to further identify the Np species present. These data will be crucial in understanding the metabolic pathway of Np in mammals which will help in the design of reagents which can eliminate Np from mammals in the event of accidental exposure. It is proposed to run these experiments at the Standard Synchrotron Radiation Laboratory (SSRL). This laboratory is a DOE national user facility located at the Stanford Linear Accelerator Center (SLAC). The {sup 237}Np nucleus decays by the emission of an alpha particle and this particle emission is the principal hazard in handling Np samples. This hazard is mitigated by physical containment of the sample which stops the alpha particles within the containment. The total amount of Np material that will be shipped to and be at SSRL at any one time will be less than 1 gram. This limit on the amount of Np will ensure that SLAC remains a low hazard, non-nuclear facility. The Np samples will be solids or Np ions in aqueous solution. The Np samples will be shipped to SSRL/SLAC OHP. SLAC OHP will inventory the samples and swipe the containers holding the triply contained samples, and then bring them to the SSRL Actinide trailer located outside building 131. The QA counting records from the samples, as measured at LBNL, will be provided to SSRL and SLAC OHP prior to the arrival of the samples at SLAC OHP. In addition, strict monitoring of the storage and experimental areas will be performed in accordance with SLAC/OHP radiation protection procedures to ensure against the release of contamination.

  3. X-ray Absorption Spectroscopy Study of the Effects of pH and Ionic

    E-Print Network [OSTI]

    Sparks, Donald L.

    indicated that the mechanism of Pb(II) sorption to the SiO2 surface was pH-dependent. At pH remobilized by competition with other cations, whereas sorbed Pb is expected to become less susceptible

  4. AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS

    E-Print Network [OSTI]

    Kirby, Jon Allan

    2012-01-01T23:59:59.000Z

    dictate the usage of ion chambers for the measurement of rmonitoring front r 0 ion chamber is necessary to correct thebe substituted for the rear ion chamber. How- ever, under

  5. Speciation of arsenic in pyrite by micro-X-ray absorption fine- structure spectroscopy (XAFS)

    SciTech Connect (OSTI)

    Paktunc, D. (CCM)

    2008-09-30T23:59:59.000Z

    Pyrite (FeS2) often contains variable levels of arsenic, regardless of the environment of formation. Arsenian pyrite has been reported in coals, sediments and ore deposits. Arsenian pyrite having As concentrations of up to 10 wt % in sedimentary rocks (Kolker et al. 1997), about 10 wt% in gold deposits (Fleet et al. 1993), 12 wt % in a refractory gold ore (Paktunc et al. 2006) and 20 wt % in a Carlin-type gold deposit in Nevada (Reich et al. 2005) have been reported. Arsenian pyrite is the carrier of gold in hydrothermal Carlin-type gold deposits, and gold concentrations of up to 0.9 wt % have been reported (Reich et al. 2005; Paktunc et al. 2006). In general, high Au concentrations correlate with As-rich zones in pyrite (Paktunc et al. 2006). Pyrite often ends up in mining and metallurgical wastes as an unwanted mineral and consititutes one of the primary sources of As in the wastes. Arsenic can be readily released to the environment due to rapid oxidative dissolution of host pyrite under atmospheric conditions. Pyrite is also the primary source of arsenic in emissions and dust resulting from combustion of bituminous coals. Despite the importance of arsenian pyrite as a primary source of anthropogenic arsenic in the environment and its economic significance as the primary carrier of gold in Carlin-type gold deposits, our understanding of the nature of arsenic in pyrite is limited. There are few papers dealing with the mode of occurrence of arsenic by bulk XAFS in a limited number of pyrite-bearing samples. The present study documents the analysis of pyrite particles displaying different morphologies and a range of arsenic and gold concentrations to determine the nature and speciation of arsenic.

  6. Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy

    E-Print Network [OSTI]

    Cohen, Ronald C.

    spectra measured for aqueous formate and acetate solutions containing lithium, sodium, and potassium 290 eV clearly indicate a preferential interaction of sodium versus potassium, which was less apparent interactions aqueous systems The discovery of the selective interactions between simple ions and proteins dates

  7. X-ray absorption spectroscopy at the Ni-K edge in Stackhousia tryonii Bailey hyperaccumulator

    E-Print Network [OSTI]

    Kachenko, A.

    2009-01-01T23:59:59.000Z

    4 Australian Nuclear Science and Technology Organisation,Australian Nuclear Science and Technology Organisation,

  8. AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS

    E-Print Network [OSTI]

    Kirby, Jon Allan

    2012-01-01T23:59:59.000Z

    SPINACH CHLOROPLASTS Jon Allan Kirby (Ph.D. thesis) May 1981SPINACH CHLOROPLASTS Jon Allan Kirby Ph.D. Thesis May 1981Spinach Chloroplasts Jon Allan Kirby B.S. (Ottawa

  9. Millisecond Kinetics of Nanocrystal Cation Exchange Using Microfluidic X-ray Absorption Spectroscopy

    E-Print Network [OSTI]

    Chan, Emory M.; Marcus, Matthew A.; Fakra, Sirine; Elnaggar, Mariam S.; Mathies, Richard A.; Alivisatos, A. Paul

    2007-01-01T23:59:59.000Z

    S. ; Somorjai, G. A. ; Alivisatos, A. P. Science 2004, 304,S. M. ; Yin, Y. D. ; Alivisatos, A. P. Science 2004, 306,Gygi, F. ; Galli, G. A. ; Alivisatos, A. P. J. Phys. Chem. C

  10. In Situ Electrochemical X-ray Absorption Spectroscopy of Oxygen Reduction Electrocatalysis with High Oxygen Flux

    E-Print Network [OSTI]

    Frenkel, Anatoly

    to the widespread application of fuel cells and air-cathode batteries in automotive and stationary power a progressive evolution of the electronic structure of the metal clusters that is both potential) and the large overpotential (300 mV) in fuel cell cathodes necessitate the use of high loadings of precious-metal

  11. X-ray Absorption Spectroscopy of Liquid Methanol Microjets: Bulk Electronic Structure and Hydrogen Bonding Network

    E-Print Network [OSTI]

    Cohen, Ronald C.

    of ice,15,16 or at the liquid-gas interface.3 As expected, water in its various phases is a natural, Sweden, AdVanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720

  12. X-ray Absorption Spectroscopy Study of Prototype Chemical Systems: Theory vs. Experiment

    E-Print Network [OSTI]

    Schwartz, Craig Philip

    2010-01-01T23:59:59.000Z

    Berlin, 1992). B. Winter, Nuclear Instruments & Methods in80 (12) (2009). B. Winter, Nuclear Instruments & Methods in

  13. Gas cell for in situ soft X-ray transmission-absorption spectroscopy of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMFormsGasReleaseSpeechesHall ATours,Dioxide andNational

  14. Iodine valence and local environments in borosilicate waste glasses using X-ray absorption spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes | NationalCurriculum IntroductionInvestor andPublicTankvalence

  15. A Fern Fatale - X-ray Absorption Spectroscopy Imaging an Arsenic-Loving

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2you aA Deep Dive intoF O

  16. X-ray-induced electronic structure change in CuIr{sub 2}S{sub 4}

    SciTech Connect (OSTI)

    Gretarsson, H.; Kim, Young-June [Department of Physics, University of Toronto, 60 St. George Street, Toronto, Ontario M5S 1A7 (Canada); Kim, Jungho; Casa, D.; Gog, T. [CMC-XOR, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Choi, K. R. [l-PEM, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of); Cheong, S. W. [l-PEM, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of); R-CEM and Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854 (United States)

    2011-09-15T23:59:59.000Z

    The electronic structure of CuIr{sub 2}S{sub 4} is investigated using various bulk-sensitive x-ray spectroscopic methods near the Ir L{sub 3} edge: resonant inelastic x-ray scattering (RIXS), x-ray absorption spectroscopy in the partial fluorescence yield mode, and resonant x-ray emission spectroscopy. A strong RIXS signal (0.75 eV) resulting from a charge-density-wave gap opening is observed below the metal-insulator transition temperature of 230 K. The resultant modification of electronic structure is consistent with the density functional theory prediction. In the spin- and charge-dimer disordered phase induced by x-ray irradiation below 50 K, we find that a broad peak around 0.4 eV appears in the RIXS spectrum.

  17. X-ray/UV Observing Campaign on the Mrk 279 AGN Outflow: A Global Fitting Analysis of the UV Absorption

    E-Print Network [OSTI]

    Jack R. Gabel; Nahum Arav; Jelle S. Kaastra; Gerard A. Kriss; Ehud Behar; Elisa Costantini; C. Martin Gaskell; Kirk T. Korista; Ari Laor; Frits Paerels; Daniel Proga; Jessica Kim Quijano; Masao Sako; Jennifer E. Scott; Katrien C. Steenbrugge

    2005-01-25T23:59:59.000Z

    We present an analysis of the intrinsic UV absorption in the Seyfert 1 galaxy Mrk 279 based on simultaneous long observations with the Hubble Space Telescope (41 ks) and the Far Ultraviolet Spectroscopic Explorer (91 ks). To extract the line-of-sight covering factors and ionic column densities, we separately fit two groups of absorption lines: the Lyman series and the CNO lithium-like doublets. For the CNO doublets we assume that all three ions share the same covering factors. The fitting method applied here overcomes some limitations of the traditional method using individual doublet pairs; it allows for the treatment of more complex, physically realistic scenarios for the absorption-emission geometry and eliminates systematic errors that we show are introduced by spectral noise. We derive velocity-dependent solutions based on two models of geometrical covering -- a single covering factor for all background emission sources, and separate covering factors for the continuum and emission lines. Although both models give good statistical fits to the observed absorption, we favor the model with two covering factors because: (a) the best-fit covering factors for both emission sources are similar for the independent Lyman series and CNO doublet fits; (b) the fits are consistent with full coverage of the continuum source and partial coverage of the emission lines by the absorbers, as expected from the relative sizes of the nuclear emission components; and (c) it provides a natural explanation for variability in the Ly$\\alpha$ absorption detected in an earlier epoch. We also explore physical and geometrical constraints on the outflow from these results.

  18. X-ray absorption and diffraction studies of the mixed-phase state of (Cr x V 1 ? x ) 2 O 3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pease, D. M.; Frenkel, A. I.; Krayzman, V.; Huang, T.; Shanthakumar, P.; Budnick, J. I.; Metcalf, P.; Chudnovsky, F. A.; Stern, E. A.

    2011-02-01T23:59:59.000Z

    X-ray diffraction and vanadium x-ray absorption near-edge structure (XANES) data have been obtained for (V1-x)?O? samples containing several concentrations of Cr, crossing the metal-insulator transition boundary. For single-phase single-crystal samples our theoretical results are generally in good qualitative agreement with our experimental single-crystal XANES, for both crystal orientations relative to the incident-beam electric vector. However, an anomalous peak occurs for both orientations in the K pre-edge of the single-crystal sample containing 1.2% Cr, a paramagnetic insulator sample that is in the concentration regime corresponding to the room-temperature two-phase (coexistence) region of the phase diagram. Upon increasing the temperature of the 0.4% Cr powdered material to 400 K so that one enters the two-phase region of the phase diagram, a similar peak appears and then diminishes at 600 K. These results, as well as experiments done by others involving room-temperature and low-temperature XANES of a 1.1% Cr sample, suggest that this feature in the V pre-edge structure is associated with the appearance under some circumstances of a small amount of highly distorted VO? octahedra in the interface region between coexisting metal and insulating phases. Finally, we find that, for the two-phase regime, the concentration ratio of the metal-to-insulating phase varies between different regions from a sample batch of uniform composition made by the skull melting method.

  19. Double-core excitations in formamide can be probed by X-ray double-quantum-coherence spectroscopy

    SciTech Connect (OSTI)

    Zhang Yu; Healion, Daniel; Biggs, Jason D.; Mukamel, Shaul [Department of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697 (United States)

    2013-04-14T23:59:59.000Z

    The attosecond, time-resolved X-ray double-quantum-coherence four-wave mixing signals of formamide at the nitrogen and oxygen K-edges are simulated using restricted excitation window time-dependent density functional theory and the excited core hole approximation. These signals, induced by core exciton coupling, are particularly sensitive to the level of treatment of electron correlation, thus providing direct experimental signatures of electron and core-hole many-body effects and a test of electronic structure theories.

  20. Controlling X-rays With Light

    SciTech Connect (OSTI)

    Glover, Ernie; Hertlein, Marcus; Southworth, Steve; Allison, Tom; van Tilborg, Jeroen; Kanter, Elliot; Krassig, B.; Varma, H.; Rude, Bruce; Santra, Robin; Belkacem, Ali; Young, Linda

    2010-08-02T23:59:59.000Z

    Ultrafast x-ray science is an exciting frontier that promises the visualization of electronic, atomic and molecular dynamics on atomic time and length scales. A largelyunexplored area of ultrafast x-ray science is the use of light to control how x-rays interact with matter. In order to extend control concepts established for long wavelengthprobes to the x-ray regime, the optical control field must drive a coherent electronic response on a timescale comparable to femtosecond core-hole lifetimes. An intense field is required to achieve this rapid response. Here an intense optical control pulse isobserved to efficiently modulate photoelectric absorption for x-rays and to create an ultrafast transparency window. We demonstrate an application of x-ray transparencyrelevant to ultrafast x-ray sources: an all-photonic temporal cross-correlation measurement of a femtosecond x-ray pulse. The ability to control x-ray/matterinteractions with light will create new opportunities at current and next-generation x-ray light sources.

  1. X-ray Observations of Mrk 231

    E-Print Network [OSTI]

    T. J. Turner

    1998-08-10T23:59:59.000Z

    This paper presents new X-ray observations of Mrk 231, an active galaxy of particular interest due to its large infrared luminosity and the presence of several blueshifted broad absorption line (BAL) systems, a phenomenon observed in a small fraction of QSOs. A ROSAT HRI image of Mrk 231 is presented, this shows an extended region of soft X-ray emission, covering several tens of kpc, consistent with the extent of the host galaxy. An ASCA observation of Mrk 231 is also presented. Hard X-rays are detected but the data show no significant variability in X-ray flux. The hard X-ray continuum is heavily attenuated and X-ray column estimates range from ~ 2 x 10^{22} - 10^{23} cm^{-2} depending on whether the material is assumed to be neutral or ionized, and on the model assumed for the extended X-ray component. These ASCA data provide only the second hard X-ray spectrum of a BAL AGN presented to date. The broad-band spectral-energy-distribution of the source is discussed. While Mrk 231 is X-ray weak compared to Seyfert 1 galaxies, it has an optical-to-X-ray spectrum typical of a QSO.

  2. In situ apparatus for the study of clathrate hydrates relevant to solar system bodies using synchrotron X-ray diffraction and Raman spectroscopy

    E-Print Network [OSTI]

    Day, Sarah J; Evans, Aneurin; Parker, Julia E

    2015-01-01T23:59:59.000Z

    Clathrate hydrates are believed to play a significant role in various solar system environments, e.g. comets, and the surfaces and interiors of icy satellites, however the structural factors governing their formation and dissociation are poorly understood. We demonstrate the use of a high pressure gas cell, combined with variable temperature cooling and time-resolved data collection, to the in situ study of clathrate hydrates under conditions relevant to solar system environments. Clathrates formed and processed within the cell are monitored in situ using synchrotron X-ray powder diffraction and Raman spectroscopy. X-ray diffraction allows the formation of clathrate hydrates to be observed as CO2 gas is applied to ice formed within the cell. Complete conversion is obtained by annealing at temperatures just below the ice melting point. A subsequent rise in the quantity of clathrate is observed as the cell is thermally cycled. Four regions between 100-5000cm-1 are present in the Raman spectra that carry feature...

  3. Upgraded high time-resolved x-ray imaging crystal spectroscopy system for J-TEXT ohmic plasmas

    SciTech Connect (OSTI)

    Jin, W.; Chen, Z. Y., E-mail: zychen@hust.edu.cn; Huang, D. W.; Li, Q. L.; Yan, W.; Luo, Y. H.; Huang, Y. H.; Tong, R. H.; Yang, Z. J.; Rao, B.; Ding, Y. H.; Zhuang, G. [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)] [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Lee, S. G.; Shi, Y. J. [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of)] [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of)

    2014-02-15T23:59:59.000Z

    This paper presents the upgraded x-ray imaging crystal spectrometer (XICS) system on Joint Texas Experimental Tokamak (J-TEXT) tokamak and the latest experimental results obtained in last campaign. With 500 Hz frame rate of the new Pilatus detector and 5 cm × 10 cm spherically bent crystal, the XICS system can provide core electron temperature (T{sub e}), core ion temperature (T{sub i}), and plasma toroidal rotation (V{sub ?}) with a maximum temporal resolution of 2 ms for J-TEXT pure ohmic plasmas. These parameters with high temporal resolution are very useful in tokamak plasma research, especially for rapidly changed physical processes. The experimental results from the upgraded XICS system are presented.

  4. Molecular orientation in soft matter thin films studied by resonant soft X-ray reflectivity

    SciTech Connect (OSTI)

    Mezger, Markus; Jerome, Blandine; Kortright, Jeffrey B.; Valvidares, Manuel; Gullikson, Eric; Giglia, Angelo; Mahne, Nicola; Nannarone, Stefano

    2011-01-12T23:59:59.000Z

    We present a technique to study depth profiles of molecular orientation in soft matter thin films with nanometer resolution. The method is based on dichroism in resonant soft X-ray reflectivity using linear s- and p-polarization. It combines the chemical sensitivity of Near-Edge X-ray Absorption Fine Structure spectroscopy to specific molecular bonds and their orientation relative to the polarization of the incident beam with the precise depth profiling capability of X-ray reflectivity. We demonstrate these capabilities on side chain liquid crystalline polymer thin films with soft X-ray reflectivity data at the carbon K edge. Optical constants of the anisotropic refractive index ellipsoid were obtained from a quantitative analysis using the Berreman formalism. For films up to 50 nm thickness we find that the degree of orientation of the long axis exhibits no depth variation and isindependent of the film thickness.

  5. Photosynthesis and structure of electroless Ni-P films by synchrotron x-ray irradiation

    SciTech Connect (OSTI)

    Hsu, P.-C.; Wang, C.-H.; Yang, T.-Y.; Hwu, Y.-K.; Lin, C.-S.; Chen, C.-H.; Chang, L.-W.; Seol, S.-K.; Je, J.-H.; Margaritondo, G. [Institute of Physics, Academia Sinica, NanKang, Taipei 115, Taiwan and Department of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan (China); Institute of Physics, Academia Sinica, NanKang, Taipei 115, Taiwan (China); Institute of Physics, Academia Sinica, NanKang, Taipei 115, Taiwan (China); Department of Engineering and System Science, National Tsing Hua University, Hsinchu, 300, Taiwan (China) and Institute of Optoelectronic Sciences, National Taiwan Ocean University, Keelung 202, Taiwan (China); Department of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan (China); Kinsus Interconnect Technology Co., Taoyuang 327, Taiwan (China); Department of Materials Science and Optoelectronic Engineering, National Sun Yat-Sen University, Kaoshung 804, Taiwan (China); X-ray Imaging Center, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of) and Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang 790-784 (Korea); Ecole Polytechnique Federale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland)

    2007-05-15T23:59:59.000Z

    The authors describe an electroless deposition method for thin films, based on the irradiation by an x-ray beam emitted by a synchrotron source. Specifically, Ni-P films were deposited at room temperature. This synthesis is a unique combination of photochemical and electrochemical processes. The influence of the pH value on the formation and structural properties of the films was examined by various characterization tools including scanning electron microscopy, x-ray diffraction, and x-ray absorption spectroscopy. Real time monitoring of the deposition process by coherent x-ray microscopy reveals that the formation of hydrogen bubbles leads to a self-catalysis effect without a preexisting catalyst. The mechanisms underlying the deposition process are discussed in details.

  6. On the mechanism of NO selective catalytic reduction by hydrocarbons over Cu-ZSM-5 via X-ray absorption spectroscopic study

    SciTech Connect (OSTI)

    Liu, D.J. [AlliedSignal Inc., Des Plaines, IL (United States)] [AlliedSignal Inc., Des Plaines, IL (United States); Robota, H.J. [ASEC, Tulsa, OK (United States)] [ASEC, Tulsa, OK (United States)

    1999-04-08T23:59:59.000Z

    An understanding of the catalytic mechanism of NO{sub x} reduction is critical for the development of next-generation high-fuel efficiency, low-emission vehicles. This paper compiles the investigations in recent years on the mechanism of NO selective catalytic reduction (SCR) by hydrocarbon over Cu-ZSM-5. The studies were focused on the oxidation state and coordination chemistry of the exchanged Cu as the active site during the catalytic reaction using X-ray absorption spectroscopic (XAS) techniques, mainly XANES and EXAFS. Their experiment demonstrated the existence of a redox mechanism which involves cyclic switching of the oxidation states between Cu(II) and Cu(I) in an oxygen-rich gas mixture under elevated temperature. The authors also observed the coordination structural change of copper ion in ZSM-5 accompanying the change of oxidation state. A correlation between cuprous ion concentration and catalytic activity was found in NO SCR by propene. The impact of another two hydrocarbons, propane and methane, on the copper redox behavior also appears to correlate to catalytic activities in the respective mixtures. Discussions on the nature of the active sites and the mechanism of SCR are presented based on the XAS data analysis. The similarity and difference of the physical properties of copper ion between NO catalytic decomposition and NO SCR are also discussed.

  7. On the Putative Detection of Z>0 X-Ray Absorption Features in the Spectrum of Mrk 421

    SciTech Connect (OSTI)

    Rasmussen, Andrew P.; /SLAC /KIPAC, Menlo Park; Kahn, Steven M.; /SLAC /KIPAC, Menlo Park /Stanford U., Phys. Dept.; Paerels, Frits; /Columbia U., Astron. Astrophys.; Herder, Jan Willem den; Kaastra, Jelle; de Vries, Cor; /SRON, Utrecht

    2006-04-28T23:59:59.000Z

    In a series of papers, Nicastro et al. have claimed the detection of z > 0 O VII absorption features in the spectrum of Mrk 421 obtained with the Chandra Low Energy Transmission Grating Spectrometer (LETGS). We evaluate those claims in the context of a high quality spectrum of the same source obtained with the Reflection Grating Spectrometer (RGS) on XMM-Newton. The data comprise over 955 ksec of usable exposure time and more than 2.6 x 10{sup 4} counts per 50 m{angstrom} at 21.6 {angstrom}. We concentrate on the spectrally clean region (21.3 < {lambda} < 22.5 {angstrom}) where sharp features due to the astrophysically abundant O VII may reveal an intervening, warm-hot intergalactic medium (WHIM). In spite of the fact that the sensitivity of the RGS data is higher than that of the original LETGS data presented by Nicastro et al., we do not confirm detection of any of the intervening systems claimed to date. Rather, we detect only three unsurprising, astrophysically expected features down to the log (N{sub i}) {approx} 14.6 (3{sigma}) sensitivity level. Each of the two purported WHIM features is rejected with a statistical confidence that exceeds that reported for its initial detection. While we can not rule out the existence of fainter, WHIM related features in these spectra, we suggest that previous discovery claims were premature. A more recent paper by Williams et al. claims to have demonstrated that the RGS data we analyze here do not have the resolution or statistical quality required to confirm or deny the LETGS detections. We show that the Williams et al. reduction of the RGS data was highly flawed, leading to an artificial and spurious degradation of the instrument response. We carefully highlight the differences between our analysis presented here and those published by Williams et al.

  8. Angle-resolved environmental X-ray photoelectron spectroscopy: A new laboratory setup for photoemission studies at pressures up to 0.4 Torr

    SciTech Connect (OSTI)

    Mangolini, F.; Wabiszewski, G. E.; Egberts, P. [Department of Mechanical Engineering and Applied Mechanics, University of Pennsylvania, 220 S. 33rd Street, Philadelphia, Pennsylvania 19104 (United States); Ahlund, J.; Backlund, K.; Karlsson, P. G. [VG Scienta AB, Box 15120, SE-750 15 Uppsala (Sweden); Adiga, V. P.; Streller, F. [Department of Materials Science and Engineering, University of Pennsylvania, 3231 Walnut Street, Philadelphia, Pennsylvania 19104 (United States); Wannberg, B. [VG Scienta AB, Box 15120, SE-750 15 Uppsala (Sweden); BW Particle Optics AB, P.O. Box 55, SE-822 22 Alfta (Sweden); Carpick, R. W. [Department of Mechanical Engineering and Applied Mechanics, University of Pennsylvania, 220 S. 33rd Street, Philadelphia, Pennsylvania 19104 (United States); Department of Materials Science and Engineering, University of Pennsylvania, 3231 Walnut Street, Philadelphia, Pennsylvania 19104 (United States)

    2012-09-15T23:59:59.000Z

    The paper presents the development and demonstrates the capabilities of a new laboratory-based environmental X-ray photoelectron spectroscopy system incorporating an electrostatic lens and able to acquire spectra up to 0.4 Torr. The incorporation of a two-dimensional detector provides imaging capabilities and allows the acquisition of angle-resolved data in parallel mode over an angular range of 14 Degree-Sign without tilting the sample. The sensitivity and energy resolution of the spectrometer have been investigated by analyzing a standard Ag foil both under high vacuum (10{sup -8} Torr) conditions and at elevated pressures of N{sub 2} (0.4 Torr). The possibility of acquiring angle-resolved data at different pressures has been demonstrated by analyzing a silicon/silicon dioxide (Si/SiO{sub 2}) sample. The collected angle-resolved spectra could be effectively used for the determination of the thickness of the native silicon oxide layer.

  9. Time-resolved soft-x-ray spectroscopy of a magnetic octupole transition in nickel-like xenon, cesium, and barium ions

    SciTech Connect (OSTI)

    Trabert, E; Beiersdorfer, P; Brown, G V; Boyce, K; Kelley, R L; Kilbourne, C A; Porter, F S; Szymkowiak, A

    2005-11-11T23:59:59.000Z

    A microcalorimeter with event mode capability for time-resolved soft-x-ray spectroscopy, and a high-resolution flat-field EUV spectrometer have been employed at the Livermore EBIT-I electron beam ion trap for observations and wavelength measurements of M1, E2, and M3 decays of long-lived levels in the Ni-like ions Xe{sup 26+}, Cs{sup 27+}, and Ba{sup 28+}. Of particular interest is the lowest excited level, 3d{sup 9}4s {sup 3}D{sub 3}, which can only decay via a magnetic octupole (M3) transition. For this level in Xe an excitation energy of (590.40 {+-} 0.03eV) and a level lifetime of (11.5 {+-} 0.5 ms) have been determined.

  10. Measurement of the valence band-offset in a PbSe/ZnO heterojunction by x-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Li Lin; Qiu Jijun; Weng Binbin; Yuan Zijian; Shi Zhisheng [School of Electrical and Computer Engineering, University of Oklahoma, Norman, Oklahoma 73019 (United States); Li Xiaomin; Gan Xiaoyan [State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Sellers, Ian R. [Deparment of Physics, University of Oklahoma, Norman, Oklahoma 73019 (United States)

    2012-12-24T23:59:59.000Z

    A heterojunction of PbSe/ZnO has been grown by molecular beam epitaxy. X-ray photoelectron spectroscopy was used to directly measure the valence-band offset (VBO) of the heterojunction. The VBO, {Delta}E{sub V}, was determined as 2.51 {+-} 0.05 eV using the Pb 4p{sup 3/2} and Zn 2p{sup 3/2} core levels as a reference. The conduction-band offset, {Delta}E{sub C}, was, therefore, determined to be 0.59 {+-} 0.05 eV based on the above {Delta}E{sub V} value. This analysis indicates that the PbSe/ZnO heterojunction forms a type I (Straddling Gap) heterostructure.

  11. Band alignment study of lattice-matched In{sub 0.49}Ga{sub 0.51}P and Ge using x-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Owen, Man Hon Samuel, E-mail: m.owen.sg@ieee.org, E-mail: yeo@ieee.org; Zhou, Qian; Gong, Xiao; Yeo, Yee-Chia, E-mail: m.owen.sg@ieee.org, E-mail: yeo@ieee.org [Department of Electrical and Computer Engineering, National University of Singapore, Singapore 119260 (Singapore); Zhang, Zheng; Pan, Ji Sheng [Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore); Loke, Wan Khai; Wicaksono, Satrio; Yoon, Soon Fatt [School of Electrical and Electronic Engineering, Nanyang Technological University (NTU), Nanyang Avenue, Singapore 639798 (Singapore); Tok, Eng Soon [Department of Physics, National University of Singapore, Singapore 117551 (Singapore)

    2014-09-08T23:59:59.000Z

    Lattice-matched In{sub 0.49}Ga{sub 0.51}P was grown on a p-type Ge(100) substrate with a 10° off-cut towards the (111) by low temperature molecular beam epitaxy, and the band-alignment of In{sub 0.49}Ga{sub 0.51}P on Ge substrate was obtained by high resolution x-ray photoelectron spectroscopy. The valence band offset for the InGaP/Ge(100) interface was found to be 0.64?±?0.12?eV, with a corresponding conduction band offset of 0.60?±?0.12?eV. The InGaP/Ge interface is found to be of the type I band alignment.

  12. Bright X-ray galaxies in SDSS filaments

    E-Print Network [OSTI]

    Tugay, A V

    2013-01-01T23:59:59.000Z

    Eighteen bright X-ray emitting galaxies were found in nearby filaments within SDSS region. Basic X-ray spectral parameters were estimated for these galaxies using power law model with photoelectric absorption. A close pair of X-ray galaxies was found.

  13. On Estimating the High-Energy Cutoff in the X-ray Spectra of Black Holes via Reflection Spectroscopy

    E-Print Network [OSTI]

    Garcia, Javier A; Steiner, James F; McClintock, Jeffrey E; Keck, Mason L; Wilms, Joern

    2015-01-01T23:59:59.000Z

    The fundamental parameters describing the coronal spectrum of an accreting black hole are the slope $\\Gamma$ of the power-law continuum and the energy $E_{cut}$ at which it rolls over. Remarkably, this parameter can be accurately measured for values as high as 1 MeV by modeling the spectrum of X-rays reflected from a black hole accretion disk at energies below 100 keV. This is possible because the details in the reflection spectrum, rich in fluorescent lines and other atomic features, are very sensitive to the spectral shape of the hardest coronal radiation illuminating the disk. We show that fitting simultaneous NuSTAR (3-79 keV) and low-energy (e.g., Suzaku) data with the most recent version of our reflection model RELXILL, one can obtain reasonable constraints on $E_{cut}$ at energies from tens of keV up to 1 MeV, for a source as faint as 1 mCrab in a 100 ks observation.

  14. X-ray fluorescence spectroscopy for the elemental analysis of plutonium-bearing materials for the materials disposition program

    SciTech Connect (OSTI)

    Voit, S.L.; Boerigter, S.T.; Rising, T.L.

    1997-11-01T23:59:59.000Z

    The US Fissile Materials Disposition (MD) program will disposition about 50 MT of plutonium in the next century. Both of the alternative technologies for disposition, MOX Fuel and Immobilization require knowledge of the incoming composition to 1--5 wt%. Wavelength Dispersive X-Ray Fluorescence (WDXRF) systems, a common elemental analysis technology with a variety of industrial applications and commercial vendors, can readily achieve this level of characterization. Since much of the excess plutonium will be packaged in a long-term storage container as part of the DOE Environmental Management (DOE-EM) program to stabilize plutonium-bearing materials, the characterization system must be implemented during the packaging process. The authors describe a preliminary design for the integration of the WDXRF system into the packaging system to be used at the Rocky Flats site. The Plutonium Stabilization and Packaging System (PuSPS), coupled with the WDXRF characterization system will provide MD with stabilized plutonium-bearing excess material that can be more readily fed to an immobilization facility. The overall added expense to the MD program of obtaining analytical information after materials have been packaged in long-term storage containers could far exceed the expense of implementing XRF analysis during the packaging process.

  15. Composition and strain in thin Si{sub 1-x}Ge{sub x} virtual substrates measured by micro-Raman spectroscopy and x-ray diffraction

    SciTech Connect (OSTI)

    Perova, T. S.; Wasyluk, J.; Waldron, A. [Department of Electronic and Electrical Engineering, Trinity College, University of Dublin, Dublin 2 (Ireland); Lyutovich, K.; Kasper, E.; Oehme, M. [Institut fuer Halbleitertechnik, Universitaet Stuttgart, Pfaffenwaldring 47, 70569 Stuttgart (Germany); Rode, K. [School of Physics, CRANN, Trinity College, University of Dublin, Dublin 2 (Ireland)

    2011-02-01T23:59:59.000Z

    Micro-Raman spectroscopy was employed for the determination of the germanium content, x and strain, {epsilon}, in ultrathin SiGe virtual substrates grown directly on Si by molecular beam epitaxy. The growth of highly relaxed SiGe layers was achieved by the introduction of point defects at a very low temperature during the initial stage of growth. SiGe virtual substrates with thicknesses in the range 40-200 nm with a high Ge content (up to 50%) and degree of relaxation, r, in the range 20%-100% were investigated using micro-Raman spectroscopy and x-ray diffraction (XRD) techniques. The Ge content, x, and strain, {epsilon}, were estimated from equations describing Si-Si, Si-Ge, and Ge-Ge Raman vibrational modes, modified in this study for application to thin SiGe layers. The alteration of the experimentally derived equations from previous studies was performed using independent data for x and r obtained from XRD reciprocal space maps. A number of samples consisting of a strained-silicon (s-Si) layer deposited on a SiGe virtual substrate were also analyzed. The stress value for the s-Si varied from 0.54 to 2.75 GPa, depending on the Ge-content in the virtual substrates. These results are in good agreement with theoretically predicted values.

  16. Scanning Transmission X-ray Microscopy: Applications in Atmospheric Aerosol Research

    SciTech Connect (OSTI)

    Moffet, Ryan C.; Tivanski, Alexei V.; Gilles, Mary K.

    2011-01-20T23:59:59.000Z

    Scanning transmission x-ray microscopy (STXM) combines x-ray microscopy and near edge x-ray absorption fine structure spectroscopy (NEXAFS). This combination provides spatially resolved bonding and oxidation state information. While there are reviews relevant to STXM/NEXAFS applications in other environmental fields (and magnetic materials) this chapter focuses on atmospheric aerosols. It provides an introduction to this technique in a manner approachable to non-experts. It begins with relevant background information on synchrotron radiation sources and a description of NEXAFS spectroscopy. The bulk of the chapter provides a survey of STXM/NEXAFS aerosol studies and is organized according to the type of aerosol investigated. The purpose is to illustrate the current range and recent growth of scientific investigations employing STXM-NEXAFS to probe atmospheric aerosol morphology, surface coatings, mixing states, and atmospheric processing.

  17. Profiling of the SiO2 -SiC Interface Using X-ray Photoelectron Spectroscopy R. N. Ghosh

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    energy loss spectroscopy, have revealed a 1.5-6 nm thick layer with a monotonically decaying C 4 School of Electrical & Computer Engineering, Purdue Univ., W. Lafayette, IN 47907 ABSTRACT techniques have been utilized to study this problem. Atomic H3.7.1 Mat. Res. Soc. Symp. Vol. 640 © 2001

  18. X-ray induced optical reflectivity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Durbin, Stephen M.

    2012-01-01T23:59:59.000Z

    The change in optical reflectivity induced by intense x-ray pulses can now be used to study ultrafast many body responses in solids in the femtosecond time domain. X-ray absorption creates photoelectrons and core level holes subsequently filled by Auger or fluorescence processes, and these excitations ultimately add conduction and valence band carriers that perturb optical reflectivity.Optical absorption associated with band filling and band gap narrowing is shown to explain the basic features found in recent measurements on an insulator (silicon nitride, Si3N4), a semiconductor(gallium arsenide,GaAs), and a metal (gold,Au), obtained with ?100 fs x-ray pulses at 500-2000 eV and probed with 800 nm laser pulses. In particular GaAs exhibits an abrupt drop in reflectivity, persisting only for a time comparable to the x-ray excitation pulse duration, consistent with prompt band gap narrowing.

  19. Chest x-Rays

    Broader source: Energy.gov [DOE]

    The B-reading is a special reading of a standard chest x-ray film performed by a physician certified by the National Institute for Occupational Safety and Health (NIOSH). The reading looks for changes on the chest x-ray that may indicate exposure and disease caused by agents such as asbestos or silica.

  20. Laser Locking with Doppler-free Saturated Absorption Spectroscopy

    E-Print Network [OSTI]

    Novikova, Irina

    - 1 - Laser Locking with Doppler-free Saturated Absorption Spectroscopy Paul L. Stubbs, Advisor the frequency of a 795 nm diode laser using a saturated absorption spectroscopy method. Laser locking in AMO physics is done to stabilize the frequency of lasers used in the laboratory in order to make results more

  1. Bandpass x-ray diode and x-ray multiplier detector

    DOE Patents [OSTI]

    Wang, C.L.

    1982-09-27T23:59:59.000Z

    An absorption-edge of an x-ray absorption filter and a quantum jump of a photocathode determine the bandpass characteristics of an x-ray diode detector. An anode, which collects the photoelectrons emitted by the photocathode, has enhanced amplification provided by photoelectron-multiplying means which include dynodes or a microchannel-plate electron-multiplier. Suppression of undesired high frequency response for a bandpass x-ray diode is provided by subtracting a signal representative of energies above the passband from a signal representative of the overall response of the bandpass diode.

  2. A split imaging spectrometer for temporally and spatially resolved titanium absorption spectroscopy

    SciTech Connect (OSTI)

    Hager, J. D., E-mail: hager@lanl.gov; Lanier, N. E.; Kline, J. L.; Flippo, K. A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Bruns, H. C.; Schneider, M.; Saculla, M.; McCarville, T. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

    2014-11-15T23:59:59.000Z

    We present a temporally and a spatially resolved spectrometer for titanium x-ray absorption spectroscopy along 2 axial symmetric lines-of-sight. Each line-of-sight of the instrument uses an elliptical crystal to acquire both the 2p and 3p Ti absorption lines on a single, time gated channel of the instrument. The 2 axial symmetric lines-of-sight allow the 2p and 3p absorption features to be measured through the same point in space using both channels of the instrument. The spatially dependent material temperature can be inferred by observing the 2p and the 3p Ti absorption features. The data are recorded on a two strip framing camera with each strip collecting data from a single line-of-sight. The design is compatible for use at both the OMEGA laser and the National Ignition Facility. The spectrometer is intended to measure the material temperature behind a Marshak wave in a radiatively driven SiO{sub 2} foam with a Ti foam tracer. In this configuration, a broad band CsI backlighter will be used for a source and the Ti absorption spectrum measured.

  3. A promising concept for using near-surface measuring angles in angle-resolved x-ray photoelectron spectroscopy considering elastic scattering effects

    SciTech Connect (OSTI)

    Oswald, S.; Oswald, F. [IFW Dresden, Postfach 270116, D-01171 Dresden (Germany)

    2011-02-01T23:59:59.000Z

    The increasing number of applications of very thin films requires both reliable thin-layer and interface characterization. A powerful method for characterization in the nanometer thickness range is the angle-resolved x-ray photoelectron spectroscopy (ARXPS). This is a nondestructive depth-profiling method, which can provide elemental content as well as chemical information. Two of the drawbacks of ARXPS are, that it requires dedicated mathematical modeling and that, at least up until now, its use has been restricted away from near-surface angles. In this paper we present a method for the mathematical description of a few, hitherto unaccounted, measurement effects in order to improve the simulations of ARXPS data for complex surface structures. As an immediate application, we propose a simple algorithm to consider the effects of elastic scattering in the standard ARXPS data interpretation, which in principle would allow the use of the whole angular range for the analysis; thus leading to a significant increase in the usable information content from the measurements. The potential of this approach is demonstrated with model calculations for a few thin film examples.

  4. Interfacial chemistry and valence band offset between GaN and Al{sub 2}O{sub 3} studied by X-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Duan, T. L.; Ang, D. S. [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore)] [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore); Pan, J. S. [Institute of Materials Research and Engineering, A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)] [Institute of Materials Research and Engineering, A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)

    2013-05-20T23:59:59.000Z

    The interface region between Ga-face n-type GaN and Al{sub 2}O{sub 3} dielectric (achieved via atomic-layer deposition or ALD) is investigated by X-ray photoelectron spectroscopy (XPS). An increase in the Ga-O to Ga-N bond intensity ratio following Al{sub 2}O{sub 3} deposition implies that the growth of an interfacial gallium sub-oxide (GaO{sub x}) layer occurred during the ALD process. This finding may be ascribed to GaN oxidation, which may still happen following the reduction of a thin native GaO{sub x} by trimethylaluminum (TMA) in the initial TMA-only cycles. The valence band offset between GaN and Al{sub 2}O{sub 3}, obtained using both core-level and valence band spectra, is found to vary with the thickness of the deposited Al{sub 2}O{sub 3}. This observation may be explained by an upward energy band bending at the GaN surface (due to the spontaneous polarization induced negative bound charge on the Ga-face GaN) and the intrinsic limitation of the XPS method for band offset determination.

  5. X-ray laser

    DOE Patents [OSTI]

    Nilsen, Joseph (Livermore, CA)

    1991-01-01T23:59:59.000Z

    An X-ray laser (10) that lases between the K edges of carbon and oxygen, i.e. between 44 and 23 Angstroms, is provided. The laser comprises a silicon (12) and dysprosium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state nickel-like dysprosium ions (34) are resonantly photo-pumped to their upper X-ray laser state by line emission from hydrogen-like silicon ions (32). The novel X-ray laser should prove especially useful for the microscopy of biological specimens.

  6. High resolution soft x-ray spectroscopy of low Z K-shell emission from laser-produced plasmas

    SciTech Connect (OSTI)

    Dunn, J; Magee, E W; Shepherd, R; Chen, H; Hansen, S B; Moon, S J; Brown, G V; Gu, M; Beiersdorfer, P; Purvis, M A

    2008-05-21T23:59:59.000Z

    A large radius, R = 44.3 m, High Resolution Grating Spectrometer (HRGS) with 2400 line/mm variable line spacing has been designed for laser-produced plasma experiments conducted at the Lawrence Livermore National Laboratory Jupiter Laser Facility. The instrument has been run with a low-noise, charge-coupled device detector to record high signal-to-noise spectra in the 10-50 {angstrom} wavelength range. The instrument can be run with a 10-20 {micro}m wide slit to achieve the best spectral resolving power, approaching 1000 and similar to crystal spectrometers at 12-20 {angstrom}, or in slitless operation with a small symmetrical emission source. We describe preliminary spectra emitted from various H-like and He-like low Z ion plasmas heated by 100-500 ps (FWHM), 527 nm wavelength laser pulses. This instrument can be developed as a useful spectroscopy platform relevant to laboratory-based astrophysics as well as high energy density plasma studies.

  7. X-ray Emission from Massive StarsX-ray Emission from Massive Stars David CohenDavid Cohen

    E-Print Network [OSTI]

    Cohen, David

    X-ray Emission from Massive StarsX-ray Emission from Massive Stars David CohenDavid Cohen/s)Velocity (km/s) #12;absorption emission emission occulted emission emission UV telescope side side front back #12;absorption emission emission occulted emission emission UV telescope side side front back #12;The

  8. Transient absorption spectroscopy of laser shocked explosives

    SciTech Connect (OSTI)

    Mcgrane, Shawn D [Los Alamos National Laboratory; Dang, Nhan C [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Bolome, Cindy A [Los Alamos National Laboratory; Moore, D S [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    Transient absorption spectra from 390-890 nm of laser shocked RDX, PETN, sapphire, and polyvinylnitrate (PVN) at sub-nanosecond time scales are reported. RDX shows a nearly linear increase in absorption with time after shock at {approx}23 GPa. PETN is similar, but with smaller total absorption. A broad visible absorption in sapphire begins nearly immediately upon shock loading but does not build over time. PVN exhibits thin film interference in the absorption spectra along with increased absorption with time. The absorptions in RDX and PETN are suggested to originate in chemical reactions happening on picosecond time scales at these shock stresses, although further diagnostics are required to prove this interpretation.

  9. Tools for a Theoretical X-ray Beamline J. J. Rehr*

    E-Print Network [OSTI]

    Botti, Silvana

    Tools for a Theoretical X-ray Beamline J. J. Rehr* Department of Physics University of Washington, France 22 October 2010 #12;X-ray Spectroscopy Beamline #12;Tools for a Theoretical X-ray Beamline · GOAL Theoretical X-ray Beamline: 2. Tools for EXAFS and XANES, EELS, XMCD, ... 3. DFT/MD-TOOLS 4. Next generation

  10. absorption spectroscopy study: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 On Automatic Absorption Detection for Imaging Spectroscopy: A Comparative Study Computer Technologies and...

  11. absorption infrared spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption infrared spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Polarization...

  12. absorption spectroscopy principles: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Saturated Absorption Spectroscopy Experiment SAS CiteSeer Summary: You will use a tunable diode laser to...

  13. Development of soft X-ray polarized light beamline on Indus-2 synchrotron radiation source

    SciTech Connect (OSTI)

    Phase, D. M., E-mail: mgupta@csr.res.in; Gupta, Mukul, E-mail: mgupta@csr.res.in; Potdar, S., E-mail: mgupta@csr.res.in; Behera, L., E-mail: mgupta@csr.res.in; Sah, R., E-mail: mgupta@csr.res.in; Gupta, Ajay, E-mail: mgupta@csr.res.in [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore, 452001 (India)

    2014-04-24T23:59:59.000Z

    This article describes the development of a soft x-ray beamline on a bending magnet source of Indus-2 storage ring (2.5 GeV) and some preliminary results of x-ray absorption spectroscopy (XAS) measurements using the same. The beamline layout is based on a spherical grating monochromator. The beamline is able to accept synchrotron radiation from the bending magnet port BL-1 of the Indus-2 ring with a wide solid angle. The large horizontal and vertical angular acceptance contributes to high photon flux and selective polarization respectively. The complete beamline is tested for ultrahigh vacuum (UHV) ? 10{sup ?10} mbar. First absorption spectrum was obtained on HOPG graphite foil. Our performance test indicates that modest resolving power has been achieved with adequate photon flux to carry out various absorption experiments.

  14. absorption spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino Absorption...

  15. absorption spectroscopy aas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy aas First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino Absorption...

  16. absorption spectroscopy exafs: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy exafs First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Extended Xray Absorption...

  17. absorption spectroscopy studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy studies First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 On Automatic Absorption...

  18. X-ray beam finder

    DOE Patents [OSTI]

    Gilbert, H.W.

    1983-06-16T23:59:59.000Z

    An X-ray beam finder for locating a focal spot of an X-ray tube includes a mass of X-ray opaque material having first and second axially-aligned, parallel-opposed faces connected by a plurality of substantially identical parallel holes perpendicular to the faces and a film holder for holding X-ray sensitive film tightly against one face while the other face is placed in contact with the window of an X-ray head.

  19. Direct and quantitative absorptive spectroscopy of nanowires

    E-Print Network [OSTI]

    Tong, Jonathan Kien-Kwok

    2012-01-01T23:59:59.000Z

    Photonic nanostructures exhibit unique optical properties that are attractive in many different applications. However, measuring the optical properties of individual nanostructures, in particular the absorptive properties, ...

  20. X-ray and synchrotron studies of porous silicon

    SciTech Connect (OSTI)

    Sivkov, V. N., E-mail: svn@dm.komisc.ru [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation); Lomov, A. A. [Russian Academy of Sciences, Physical-Technological Institute (Russian Federation)] [Russian Academy of Sciences, Physical-Technological Institute (Russian Federation); Vasil'ev, A. L. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Nekipelov, S. V. [Komi State Pedagogical Institute (Russian Federation)] [Komi State Pedagogical Institute (Russian Federation); Petrova, O. V. [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation)] [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation)

    2013-08-15T23:59:59.000Z

    The results of comprehensive studies of layers of porous silicon of different conductivity types, grown by anodizing standard Si(111) substrates in an electrolyte based on fluoric acid and ethanol with the addition of 5% of iodine and kept in air for a long time, are discussed. Measurements are performed by scanning electron microscopy, high-resolution X-ray diffraction, and ultrasoft X-ray spectroscopy using synchrotron radiation. The structural parameters of the layers (thickness, strain, and porosity) and atomic and chemical composition of the porous-silicon surface are determined. It is found that an oxide layer 1.5-2.3-nm thick is formed on the surface of the silicon skeleton. The near-edge fine structure of the Si 2p absorption spectrum of this layer corresponds to the fine structure of the 2p spectrum of well coordinated SiO{sub 2}. In this case, the fine structure in the Si 2p-edge absorption region of the silicon skeleton is identical to that of the 2p absorption spectrum of crystalline silicon.

  1. X-Ray Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-Ray Diagnostics X-Ray

  2. Multiplexed absorption tomography with calibration-free wavelength modulation spectroscopy

    SciTech Connect (OSTI)

    Cai, Weiwei; Kaminski, Clemens F., E-mail: cfk23@cam.ac.uk [Department of Chemical Engineering and Biotechnology, University of Cambridge, Cambridge CB2 3RA (United Kingdom)

    2014-04-14T23:59:59.000Z

    We propose a multiplexed absorption tomography technique, which uses calibration-free wavelength modulation spectroscopy with tunable semiconductor lasers for the simultaneous imaging of temperature and species concentration in harsh combustion environments. Compared with the commonly used direct absorption spectroscopy (DAS) counterpart, the present variant enjoys better signal-to-noise ratios and requires no baseline fitting, a particularly desirable feature for high-pressure applications, where adjacent absorption features overlap and interfere severely. We present proof-of-concept numerical demonstrations of the technique using realistic phantom models of harsh combustion environments and prove that the proposed techniques outperform currently available tomography techniques based on DAS.

  3. Silicon drift detector based X-ray spectroscopy diagnostic system for the study of non-thermal electrons at Aditya tokamak

    SciTech Connect (OSTI)

    Purohit, S., E-mail: pshishir@ipr.res.in; Joisa, Y. S.; Raval, J. V.; Ghosh, J.; Tanna, R.; Shukla, B. K.; Bhatt, S. B. [Institute for Plasma Research, Bhat, Gandhinagar 382 428 (India)

    2014-11-15T23:59:59.000Z

    Silicon drift detector based X-ray spectrometer diagnostic was developed to study the non-thermal electron for Aditya tokamak plasma. The diagnostic was mounted on a radial mid plane port at the Aditya. The objective of diagnostic includes the estimation of the non-thermal electron temperature for the ohmically heated plasma. Bi-Maxwellian plasma model was adopted for the temperature estimation. Along with that the study of high Z impurity line radiation from the ECR pre-ionization experiments was also aimed. The performance and first experimental results from the new X-ray spectrometer system are presented.

  4. Soft x-ray generation in gases with an ultrashort pulse laser

    SciTech Connect (OSTI)

    Ditmire, T.R.

    1996-01-08T23:59:59.000Z

    An experimental investigation of soft x-ray production resulting from the interaction of intense near infra-red laser radiation with gases is presented in this thesis. Specifically, soft x-ray generation through high order harmonic generation or exploiting intense inverse bremsstrahlung heating is examined. Most of these studies are conducted with femtosecond, terawatt class Cr:LiSrAlF{sub 6} (LiSAF) laser, though results derived from studies with other laser systems are presented as well. The majority of this work is devoted to experimental investigations, however, theoretical and computational models are developed to interpret the data. These studies are motivated by the possibility of utilizing the physics of intense laser/matter interactions as a potential compact source of bright x-rays. Consequently, the thrust of many of the experiments conducted is aimed at characterizing the x-rays produced for possible use in applications. In general, the studies of this manuscript fall into three categories. First, a unique 130 fs, 8 TW laser that is based on chirped pulse amplification, is described, and its performance is evaluated. The generation of x-rays through high order harmonics is then discussed with emphasis on characterizing and optimizing harmonic generation. Finally, the generation of strong, incoherent x-ray radiation by the intense irradiation of large (>1,000 atom) clusters in gas jets, is explored. The physics of laser energy absorption by clusters illuminated with intensities of 10{sup 15} to 10{sup 17} W/cm{sup 2} is considered in detail. X-ray spectroscopy of the hot plasmas that result from the irradiation of the clusters is conducted, and energy transport and kinetics issues in these plasmas are discussed.

  5. Beam damage of poly(vinyl chloride) [PVC] as observed by x-ray...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    damage of poly(vinyl chloride) PVC as observed by x-ray photoelectron spectroscopy at 143 K, 303 K and 373 K. Beam damage of poly(vinyl chloride) PVC as observed by x-ray...

  6. CHANDRA X-RAY SPECTROSCOPY OF THE FOCUSED WIND IN THE CYGNUS X-1 SYSTEM. I. THE NONDIP SPECTRUM IN THE LOW/HARD STATE

    E-Print Network [OSTI]

    Hanke, Manfred

    We present analyses of a 50 ks observation of the supergiant X-ray binary system Cygnus X-1 (Cyg X-1)/HDE226868 taken with the Chandra High Energy Transmission Grating Spectrometer (HETGS). Cyg X-1 was in its spectrally ...

  7. Absolute absorption spectroscopy based on molecule interferometry

    E-Print Network [OSTI]

    Stefan Nimmrichter; Klaus Hornberger; Hendrik Ulbricht; Markus Arndt

    2008-11-07T23:59:59.000Z

    We propose a new method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photo-induced fragmentation or ionization. The method is based on resolving the recoil resulting from photon absorption by means of near-field matter-wave interference, and it thus applies even to very dilute beams with low optical densities. Our discussion includes the possibility of internal state conversion as well as fluorescence. We assess the influence of various experimental uncertainties and show that the measurement of absolute absorption cross sections is conceivable with high precision and using existing technologies.

  8. Fluctuation X-Ray Scattering

    SciTech Connect (OSTI)

    Saldin, PI: D. K.; Co-I's: J. C. H. Spence and P. Fromme

    2013-01-25T23:59:59.000Z

    The work supported by the grant was aimed at developing novel methods of finding the structures of biomolecules using x-rays from novel sources such as the x-ray free electron laser and modern synchrotrons

  9. Delayed Ultrafast X-ray Auger Probing (DUXAP) of Nucleobase Ultraviolet Photoprotection

    E-Print Network [OSTI]

    McFarland, B K; Miyabe, S; Tarantelli, F; Aguilar, A; Berrah, N; Bostedt, C; Bozek, J; Bucksbaum, P H; Castagna, J C; Coffee, R; Cryan, J; Fang, L; Feifel, R; Gaffney, K; Glownia, J; Martinez, T; Mucke, M; Murphy, B; Natan, A; Osipov, T; Petrovic, V; Schorb, S; Schultz, Th; Spector, L; Swiggers, M; Tenney, I; Wang, S; White, W; White, J; Gühr, M

    2013-01-01T23:59:59.000Z

    We present a new method for ultrafast spectroscopy of molecular photoexcited dynamics. The technique uses a pair of femtosecond pulses: a photoexcitation pulse initiating excited state dynamics followed by a soft x-ray (SXR) probe pulse that core ionizes certain atoms inside the molecule. We observe the Auger decay of the core hole as a function of delay between the photoexcitation and SXR pulses. The core hole decay is particularly sensitive to the local valence electrons near the core and shows new types of propensity rules, compared to dipole selection rules in SXR absorption or emission spectroscopy. We apply the delayed ultrafast x-ray Auger probing (DUXAP) method to the specific problem of nucleobase photoprotection to demonstrate its potential. The ultraviolet photoexcited \\pi\\pi* states of nucleobases are prone to chemical reactions with neighboring bases. To avoid this, the single molecules funnel the \\pi\\pi* population to lower lying electronic states on an ultrafast timescale under violation of the...

  10. Probing the Electronic Structure of a Photoexcited Solar Cell Dye with Transient X-ray Absorption Spectroscopy

    E-Print Network [OSTI]

    Kuiken, Benjamin E. Van

    2014-01-01T23:59:59.000Z

    Pettersson, H.Dye-Sensitized Solar Cells Chem. Rev. 2010,Photo-Sensitizers in Grätzel Solar Cells: Quantum-ChemicalSensitizing Dyes in Solar Cells J. Phys. Chem. C 2008, 113,

  11. Band Gap Energy of Chalcopyrite Thin Film Solar Cell Absorbers Determined by Soft X-Ray Emission and Absorption Spectroscopy

    E-Print Network [OSTI]

    Bar, M.

    2010-01-01T23:59:59.000Z

    8] J.R. Tuttle et al. , Solar Cells 30, 21 (1991). [9] D.OF CHALCOPYRITE THIN FILM SOLAR CELL ABSORBERS DETERMINED BYchalcopyrite thin film solar cell absorbers significantly

  12. X-ray absorption spectroscopy of the cubic and hexagonal polytypes of zinc sulfide B. Gilbert,1,

    E-Print Network [OSTI]

    Haskel, Daniel

    in the zinc-blende and wurtzite modifications of ZnS. We demon- strate that d-like unoccupied bands temperature, while wurtzite, the less dense hexagonal form, is stable above 1020 °C at atmospheric pres- sure cubic or zinc blende phase and wurtzite hexagonal are given in Fig. 1. When the comparison of cubic

  13. Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy of liquid microjets

    E-Print Network [OSTI]

    Uejio, Janel S.

    2008-01-01T23:59:59.000Z

    of the interaction of the carboxylate with lithium; this isinteraction strengths of the monovalent cations of sodium, potassium, and lithiumlithium acetate revealing distinct shifts between the cations, indicative of preferential interactions.

  14. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    E-Print Network [OSTI]

    Tokunaga, T.K.

    2008-01-01T23:59:59.000Z

    National Laboratory, Berkeley, California 94720 University of Chicago, Chicago, Illinois 60637 Savannah River

  15. On the importance of nuclear quantum motions in near edge x-ray absorption fine structure (NEXAFS) spectroscopy of molecules

    E-Print Network [OSTI]

    Schwartz, Craig P.

    2009-01-01T23:59:59.000Z

    improved spectral agreement when nuclear quantum effects areby nuclear motion), and generally improves agreement with

  16. Mn l3,2 x-ray absorption spectroscopy and magnetic circular dichroism in ferromagnetic ga1-xmnxp

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    pulsed-laser melting (II-PLM) [2]. Unlike the holes in thethe magnetic properties of II-PLM films are dominated by the

  17. Revisiting the localization of Zn2+ cations sorbed on pathological apatite calcifications made through X-ray absorption spectroscopy

    E-Print Network [OSTI]

    Bazin, D.

    2010-01-01T23:59:59.000Z

    bones Accepted in Osteoporosis International F. E. Sowrey,to characterise bones Osteoporosis International, in press.such as arthrosis or osteoporosis [3]. Of note, among the

  18. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    E-Print Network [OSTI]

    Tokunaga, T.K.

    2008-01-01T23:59:59.000Z

    to Mn(II) in sediments infused with OC ? 3 mM. However, Fecontaminated sediments were infused with a steady supply ofspectra obtained on sediments infused with 30 and 100 mM OC

  19. Influence of the cobalt particle size in the CO hydrogenation reaction studied by in situ X-ray absorption spectroscopy

    E-Print Network [OSTI]

    Herranz, Tirma

    2010-01-01T23:59:59.000Z

    V.F. , Krishnan, K.M. , Alivisatos, A.P. , Science, 2001,Nordgren, J. , Chang, C. , Alivisatos, A.P. , Thornton, G. ,D.M. , Bastus, N.G. , Alivisatos, A.P. , Nat. Mater. , 2004,

  20. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    E-Print Network [OSTI]

    Tokunaga, T.K.

    2008-01-01T23:59:59.000Z

    precipitation of uranyl on goethite. Environmental Science23 used were hematite and goethite for Fe(III), and fayaliteenergies for hematite and goethite standards were 7,114.9 ±

  1. Soft X-Ray Spectroscopic Study of Dense Strontium-Doped Lanthanum Manganite Cathodes for Solid Oxide Fuel Cell Applications

    SciTech Connect (OSTI)

    L Piper; A Preston; S Cho; A DeMasi; J Laverock; K Smith; L Miara; J Davis; S Basu; et al.

    2011-12-31T23:59:59.000Z

    The evolution of the Mn charge state, chemical composition, and electronic structure of La{sub 0.8}Sr{sub 0.2}MnO{sub 3} (LSMO) cathodes during the catalytic activation of solid oxide fuel cell (SOFC) has been studies using X-ray spectroscopy of as-processed, exposed, and activated dense thin LSMO films. Comparison of O K-edge and Mn L{sub 3,2}-edge X-ray absorption spectra from the different stages of LSMO cathodes revealed that the largest change after the activation occurred in the Mn charge state with little change in the oxygen environment. Core-level X-ray photoemission spectroscopy and Mn L{sub 3} resonant photoemission spectroscopy studies of exposed and as-processed LSMO determined that the SOFC environment (800 C ambient pressure of O{sub 2}) alone results in La deficiency (severest near the surface with Sr doping >0.55) and a stronger Mn{sup 4+} contribution, leading to the increased insulating character of the cathode prior to activation. Meanwhile, O K-edge X-ray absorption measurements support Sr/La enrichment nearer the surface, along with the formation of mixed Sr{sub x}Mn{sub y}O{sub z} and/or passive MnO{sub x} and SrO species.

  2. Tunable X-ray source

    DOE Patents [OSTI]

    Boyce, James R. (Williamsburg, VA)

    2011-02-08T23:59:59.000Z

    A method for the production of X-ray bunches tunable in both time and energy level by generating multiple photon, X-ray, beams through the use of Thomson scattering. The method of the present invention simultaneously produces two X-ray pulses that are tunable in energy and/or time.

  3. Resonant Soft X-Ray Scattering - Combining Structural with Spectroscop...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as well as important L-edges of the 3d transition metals important in magnetic and oxide systems. Measurements of soft x-ray absorption spectra are inherently surface sensitive,...

  4. Broadband high resolution X-ray spectral analyzer

    DOE Patents [OSTI]

    Silver, E.H.; Legros, M.; Madden, N.W.; Goulding, F.; Landis, D.

    1998-07-07T23:59:59.000Z

    A broad bandwidth high resolution X-ray fluorescence spectrometer has a performance that is superior in many ways to those currently available. It consists of an array of 4 large area microcalorimeters with 95% quantum efficiency at 6 keV and it produces X-ray spectra between 0.2 keV and 7 keV with an energy resolution of 7 to 10 eV. The resolution is obtained at input count rates per array element of 10 to 50 Hz in real-time, with analog pulse processing and thermal pile-up rejection. This performance cannot be matched by currently available X-ray spectrometers. The detectors are incorporated into a compact and portable cryogenic refrigerator system that is ready for use in many analytical spectroscopy applications as a tool for X-ray microanalysis or in research applications such as laboratory and astrophysical X-ray and particle spectroscopy. 6 figs.

  5. Broadband high resolution X-ray spectral analyzer

    DOE Patents [OSTI]

    Silver, Eric H. (Berkeley, CA); Legros, Mark (Berkeley, CA); Madden, Norm W. (Livermore, CA); Goulding, Fred (Lafayette, CA); Landis, Don (Pinole, CA)

    1998-01-01T23:59:59.000Z

    A broad bandwidth high resolution x-ray fluorescence spectrometer has a performance that is superior in many ways to those currently available. It consists of an array of 4 large area microcalorimeters with 95% quantum efficiency at 6 keV and it produces x-ray spectra between 0.2 keV and 7 keV with an energy resolution of 7 to 10 eV. The resolution is obtained at input count rates per array element of 10 to 50 Hz in real-time, with analog pulse processing and thermal pile-up rejection. This performance cannot be matched by currently available x-ray spectrometers. The detectors are incorporated into a compact and portable cryogenic refrigerator system that is ready for use in many analytical spectroscopy applications as a tool for x-ray microanalysis or in research applications such as laboratory and astrophysical x-ray and particle spectroscopy.

  6. Valence band density of states of zinc-blende and wurtzite InN from x-ray photoemission spectroscopy and first-principles calculations

    E-Print Network [OSTI]

    As, Donat Josef

    Valence band density of states of zinc-blende and wurtzite InN from x-ray photoemission for wurtzite InN 112¯0 are shown to yield a VB-DOS similar to that of zinc-blende InN, although the nonzero the thermodynamically stable phase is the wurtzite 2H polymorph4 wz-InN , judicious choice of substrate material

  7. Ge L{sub 3}-edge x-ray absorption near-edge structure study of structural changes accompanying conductivity drift in the amorphous phase of Ge{sub 2}Sb{sub 2}Te{sub 5}

    SciTech Connect (OSTI)

    Mitrofanov, K. V. [Nanoelectronics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562 (Japan); Kolobov, A. V., E-mail: a.kolobov@aist.go.jp; Fons, P. [Nanoelectronics Research Institute and Green Nanoelectronics Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562, Japan and Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1, Kouto, Sayo, Hyogo 679-5198 (Japan); Wang, X.; Tominaga, J. [Nanoelectronics Research Institute and Green Nanoelectronics Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562 (Japan); Tamenori, Y.; Uruga, T. [Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1, Kouto, Sayo, Hyogo 679-5198 (Japan); Ciocchini, N.; Ielmini, D. [DEIB - Politecnico di Milano, Piazza L. Da Vinci 32, 20133 Milano (Italy)

    2014-05-07T23:59:59.000Z

    A gradual uncontrollable increase in the resistivity of the amorphous phase of phase-change alloys, such as Ge{sub 2}Sb{sub 2}Te{sub 5}, known as drift, is a serious technological issue for application of phase-change memory. While it has been proposed that drift is related to structural relaxation, no direct structural results have been reported so far. Here, we report the results of Ge L{sub 3}-edge x-ray absorption measurements that suggest that the drift in electrical conductivity is associated with the gradual conversion of tetrahedrally coordinated Ge sites into pyramidal sites, while the system still remains in the amorphous phase. Based on electronic configuration arguments, we propose that during this process, which is governed by the existence of lone-pair electrons, the concentration of free carriers in the system decreases resulting in an increase in resistance despite the structural relaxation towards the crystalline phase.

  8. Effects of {pi}-stacking interactions on the near carbon K-edge x-ray absorption fine structure: A theoretical study of the ethylene pentamer and the phthalocyanine dimer

    SciTech Connect (OSTI)

    Linares, Mathieu; Stafstroem, Sven; Norman, Patrick [Department of Physics, Chemistry and Biology, Linkoeping University, SE-581 83 Linkoeping (Sweden)

    2009-03-14T23:59:59.000Z

    X-ray absorption spectra have been determined for ethylene and free base phthalocyanine at the carbon K-edge with use of the complex polarization propagator method combined with Kohn-Sham density functional theory and the Coulomb attenuated method B3LYP exchange-correlation functional. Apart from isolated molecules, the study includes {pi}-stacked systems of the phthalocyanine dimer and the ethylene dimer, trimer, tetramer, and pentamer. For ethylene, {pi}-stacking involves a reduction in transition energy of the valence {pi}*-band by some 70 meV and large spectral changes (regarding also shape and intensity) of the Rydberg bands. For phthalocyanine, there are large spectral changes in the entire valence {pi}*-part of the spectrum.

  9. A new spectrometer design for the x-ray spectroscopy of laser-produced plasmas with high (sub-ns) time resolution

    SciTech Connect (OSTI)

    Bitter, M., E-mail: bitter@pppl.gov; Hill, K. W.; Efthimion, P. C.; Delgado-Aparicio, L.; Pablant, N. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Lu, Jian [Department of Engineering, Chongqing University, Chongqing 400044 (China); Beiersdorfer, P.; Chen, Hui [Physics Division, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

    2014-11-15T23:59:59.000Z

    This paper describes a new type of x-ray crystal spectrometer, which can be used in combination with gated x-ray detectors to obtain spectra from laser-produced plasmas with a high (sub-ns) time resolution. The spectrometer consists of a convex, spherically bent crystal, which images individual spectral lines as perfectly straight lines across multiple, sequentially gated, strip detectors. Since the Bragg-reflected rays are divergent, the distance between detector and crystal is arbitrary, so that this distance can be appropriately chosen to optimize the experimental arrangement with respect to the detector parameters. The spectrometer concept was verified in proof-of-principle experiments by imaging the L?{sub 1}- and L?{sub 2}-lines of tungsten, at 9.6735 and 9.96150 keV, from a micro-focus x-ray tube with a tungsten target onto a two-dimensional pixilated Pilatus detector, using a convex, spherically bent Si-422 crystal with a radius of curvature of 500 mm.

  10. Molecular shock response of explosives: electronic absorption spectroscopy

    SciTech Connect (OSTI)

    Mcgrne, Shawn D [Los Alamos National Laboratory; Moore, David S [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Bolme, Cindy A [Los Alamos National Laboratory; Eakins, Daniel E [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Electronic absorption spectroscopy in the range 400-800 nm was coupled to ultrafast laser generated shocks to begin addressing the question of the extent to which electronic excitations are involved in shock induced reactions. Data are presented on shocked polymethylmethacrylate (PMMA) thin films and single crystal pentaerythritol tetranitrate (PETN). Shocked PMMA exhibited thin film interference effects from the shock front. Shocked PETN exhibited interference from the shock front as well as broadband increased absorption. Relation to shock initiation hypotheses and the need for time dependent absorption data (future experiments) is briefly discussed.

  11. X-ray lithography source

    DOE Patents [OSTI]

    Piestrup, Melvin A. (Woodside, CA); Boyers, David G. (Mountain View, CA); Pincus, Cary (Sunnyvale, CA)

    1991-01-01T23:59:59.000Z

    A high-intensity, inexpensive X-ray source for X-ray lithography for the production of integrated circuits. Foil stacks are bombarded with a high-energy electron beam of 25 to 250 MeV to produce a flux of soft X-rays of 500 eV to 3 keV. Methods of increasing the total X-ray power and making the cross section of the X-ray beam uniform are described. Methods of obtaining the desired X-ray-beam field size, optimum frequency spectrum and elminating the neutron flux are all described. A method of obtaining a plurality of station operation is also described which makes the process more efficient and economical. The satisfying of these issues makes transition radiation an exellent moderate-priced X-ray source for lithography.

  12. X-ray lithography source

    DOE Patents [OSTI]

    Piestrup, M.A.; Boyers, D.G.; Pincus, C.

    1991-12-31T23:59:59.000Z

    A high-intensity, inexpensive X-ray source for X-ray lithography for the production of integrated circuits is disclosed. Foil stacks are bombarded with a high-energy electron beam of 25 to 250 MeV to produce a flux of soft X-rays of 500 eV to 3 keV. Methods of increasing the total X-ray power and making the cross section of the X-ray beam uniform are described. Methods of obtaining the desired X-ray-beam field size, optimum frequency spectrum and eliminating the neutron flux are all described. A method of obtaining a plurality of station operation is also described which makes the process more efficient and economical. The satisfying of these issues makes transition radiation an excellent moderate-priced X-ray source for lithography. 26 figures.

  13. X-ray compass for determining device orientation

    DOE Patents [OSTI]

    Da Silva, Luiz B. (Danville, CA); Matthews, Dennis L. (Moss Beach, CA); Fitch, Joseph P. (Livermore, CA); Everett, Matthew J. (Pleasanton, CA); Colston, Billy W. (Livermore, CA); Stone, Gary F. (Livermore, CA)

    1999-01-01T23:59:59.000Z

    An apparatus and method for determining the orientation of a device with respect to an x-ray source. In one embodiment, the present invention is coupled to a medical device in order to determine the rotational orientation of the medical device with respect to the x-ray source. In such an embodiment, the present invention is comprised of a scintillator portion which is adapted to emit photons upon the absorption of x-rays emitted from the x-ray source. An x-ray blocking portion is coupled to the scintillator portion. The x-ray blocking portion is disposed so as to vary the quantity of x-rays which penetrate the scintillator portion based upon the particular rotational orientation of the medical device with respect to the x-ray source. A photon transport mechanism is also coupled to the scintillator portion. The photon transport mechanism is adapted to pass the photons emitted from the scintillator portion to an electronics portion. By analyzing the quantity of the photons, the electronics portion determines the rotational orientation of the medical device with respect to the x-ray source.

  14. X-ray compass for determining device orientation

    DOE Patents [OSTI]

    Da Silva, L.B.; Matthews, D.L.; Fitch, J.P.; Everett, M.J.; Colston, B.W.; Stone, G.F.

    1999-06-15T23:59:59.000Z

    An apparatus and method for determining the orientation of a device with respect to an x-ray source are disclosed. In one embodiment, the present invention is coupled to a medical device in order to determine the rotational orientation of the medical device with respect to the x-ray source. In such an embodiment, the present invention is comprised of a scintillator portion which is adapted to emit photons upon the absorption of x-rays emitted from the x-ray source. An x-ray blocking portion is coupled to the scintillator portion. The x-ray blocking portion is disposed so as to vary the quantity of x-rays which penetrate the scintillator portion based upon the particular rotational orientation of the medical device with respect to the x-ray source. A photon transport mechanism is also coupled to the scintillator portion. The photon transport mechanism is adapted to pass the photons emitted from the scintillator portion to an electronics portion. By analyzing the quantity of the photons, the electronics portion determines the rotational orientation of the medical device with respect to the x-ray source. 25 figs.

  15. Time resolved ultraviolet absorption spectroscopy of pulsed fluorocarbon plasmas

    E-Print Network [OSTI]

    Gleason, Karen K.

    Time resolved ultraviolet absorption spectroscopy of pulsed fluorocarbon plasmas Brett A. Cruden.1063/1.1334936 I. INTRODUCTION The study of fluorocarbon plasmas is of great interest for their applications in silicon dioxide etching.1,2 Recently, at- tention has been paid to using fluorocarbon plasmas to pro- duce

  16. absorption spectroscopy establishes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy establishes First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino...

  17. absorption spectroscopy diagnostics: Topics by E-print Network

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    absorption spectroscopy diagnostics First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino...

  18. absorption edge spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption edge spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Communications: Near edge...

  19. absorption spectroscopy characterization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  20. absorption spectroscopy techniques: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy techniques First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 A tomographic...

  1. absorption spectroscopy identifies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  2. absorption spectroscopy method: Topics by E-print Network

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  3. absorption spectroscopy investigation: Topics by E-print Network

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  4. absorption spectroscopies progress: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopies progress First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino...

  5. absorption spectroscopy distance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy distance First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino...

  6. absorption line spectroscopy: Topics by E-print Network

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    absorption line spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Fabry-Perot...

  7. absorption spectroscopy measurements: Topics by E-print Network

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    absorption spectroscopy measurements First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Kinetics and...

  8. Temperature dependent electronic structure of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film probed by X-ray absorption near edge structure

    SciTech Connect (OSTI)

    Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Chen, Jing-Sheng; Moog Chow, Gan, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2014-05-07T23:59:59.000Z

    The Mn K edge X-ray absorption near edge structures (XANES) of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film (100 nm) on (001) LaAlO{sub 3} substrate was measured at different temperatures to probe the MnO{sub 6} octahedron distortion and corresponding electronic structure. The absorption of high temperature paramagnetic-insulator phase differed from that of the low temperature ferromagnetic-metal phase. The temperature-dependent absorption intensity of Mn K edge XANES was correlated with the relaxation of distorted MnO{sub 6} octahedron, which changed the crystal field acting on the Mn site and the related electronic structure and properties. At low temperature, the splitting of Mn majority e{sub g} orbitals decreased and the density of states above the Fermi level increased in the relaxed MnO{sub 6} octahedron, as reflected by a wider separation between two sub-peaks in the pre-edge XANES spectra.

  9. Spectral Modeling of X-rays from Hot Star Winds Emma E. Wollman, Swarthmore College `09

    E-Print Network [OSTI]

    Cohen, David

    and absorption. Consequently, the more luminous a star is, the stronger the wind it can support. This wind-driving1 Spectral Modeling of X-rays from Hot Star Winds Emma E. Wollman, Swarthmore College `09 Prof x-ray spectra from Chandra's archive. Models of x-ray production in hot star winds predict broad

  10. On the nature of the z=0 X-ray absorbers: II. The contrast between local and AGN host galaxy absorption

    E-Print Network [OSTI]

    Rik J. Williams; Smita Mathur; Fabrizio Nicastro

    2007-09-24T23:59:59.000Z

    We search for highly-ionized gas near three AGN host galaxies using the Chandra low-energy transmission grating spectrograph. Strong absorption lines from such gas are seen at z=0, most likely from one or more of the following components: (1) a Galactic corona, (2) the Local Group medium, and (3) an extended warm-hot intergalactic medium (WHIM) filament passing through our local overdensity. Since AGNs reside within host galaxies that are also expected to sit within cosmically overdense regions, similar absorption resulting from these three components should appear at the AGN redshifts as well. However, no such absorption is seen. The lack of strong absorption lines is likely a result of the gas in these host galaxies and surrounding galaxy clusters being much hotter, and hence more highly ionized, than the gas in the Local Group+Galaxy system. We conclude that WHIM filaments produce no measurable absorption lines at the AGN redshifts, and therefore contribute at most a small fraction of the observed z=0 warm-hot gas.

  11. X-ray spectrometry

    SciTech Connect (OSTI)

    Markowicz, A.A.; Van Grieken, R.E.

    1986-04-01T23:59:59.000Z

    In the period under review, i.e, through 1984 and 1985, some 600 articles on XRS (X-ray spectrometry) were published; most of these have been scanned and the most fundamental ones are discussed. All references will refer to English-language articles, unless states otherwise. Also general books have appeared on quantitative EPXMA (electron-probe X-ray microanalysis) and analytical electron microscopy (AEM) as well as an extensive review on the application of XRS to trace analysis of environmental samples. In the period under review no radically new developments have been seen in XRS. However, significant improvements have been made. Gain in intensities has been achieved by more efficient excitation, higher reflectivity of dispersing media, and better geometry. Better understanding of the physical process of photon- and electron-specimen interactions led to complex but more accurate equations for correction of various interelement effects. Extensive use of micro- and minicomputers now enables fully automatic operation, including qualitative analysis. However, sample preparation and presentation still put a limit to further progress. Although some authors find XRS in the phase of stabilization or even stagnation, further gradual developments are expected, particularly toward more dedicated equipment, advanced automation, and image analysis systems. Ways are outlined in which XRS has been improved in the 2 last years by excitation, detection, instrumental, methodological, and theoretical advances. 340 references.

  12. THE HARD X-RAY VIEW OF REFLECTION, ABSORPTION, AND THE DISK-JET CONNECTION IN THE RADIO-LOUD AGN 3C 33

    E-Print Network [OSTI]

    Evans, Daniel A.

    We present results from Suzaku and Swift observations of the nearby radio galaxy 3C 33, and investigate the nature of absorption, reflection, and jet production in this source. We model the 0.5-100 keV nuclear continuum ...

  13. Miniature x-ray source

    DOE Patents [OSTI]

    Trebes, James E. (Livermore, CA); Stone, Gary F. (Livermore, CA); Bell, Perry M. (Tracy, CA); Robinson, Ronald B. (Modesto, CA); Chornenky, Victor I. (Minnetonka, MN)

    2002-01-01T23:59:59.000Z

    A miniature x-ray source capable of producing broad spectrum x-ray emission over a wide range of x-ray energies. The miniature x-ray source comprises a compact vacuum tube assembly containing a cathode, an anode, a high voltage feedthru for delivering high voltage to the anode, a getter for maintaining high vacuum, a connection for an initial vacuum pump down and crimp-off, and a high voltage connection for attaching a compact high voltage cable to the high voltage feedthru. At least a portion of the vacuum tube wall is highly x-ray transparent and made, for example, from boron nitride. The compact size and potential for remote operation allows the x-ray source, for example, to be placed adjacent to a material sample undergoing analysis or in proximity to the region to be treated for medical applications.

  14. A new spectrometer design for the x-ray spectroscopy of laser-produced plasmas with high (sub-ns) time resolutiona)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bitter, M. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543, USA; Hill, K. W. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543, USA; Efthimion, P. C. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543, USA; Delgado-Aparicio, L. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543, USA; Pablant, N. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543, USA; Lu, Jian [Department of Engineering, Chongqing University, Chongqing 400044, China; Beiersdorfer, P. [Physics Division, Lawrence Livermore National Laboratory, Livermore, California 94550, USA; Chen, Hui [Physics Division, Lawrence Livermore National Laboratory, Livermore, California 94550, USA

    2014-11-01T23:59:59.000Z

    This paper describes a new type of x-ray crystal spectrometer, which can be used in combination with gated x-ray detectors to obtain spectra from laser-produced plasmas with a high (sub-ns) time resolution. The spectrometer consists of a convex, spherically bent crystal, which images individual spectral lines as perfectly straight lines across multiple, sequentially gated, strip detectors. Since the Bragg-reflected rays are divergent, the distance between detector and crystal is arbitrary, so that this distance can be appropriately chosen to optimize the experimental arrangement with respect to the detector parameters. The spectrometer concept was verified in proof-of-principle experiments by imaging the L?1- and L?2-lines of tungsten, at 9.6735 and 9.96150 keV, from a micro-focus xray tube with a tungsten target onto a two-dimensional pixilated Pilatus detector, using a convex, spherically bent Si-422 crystal with a radius of curvature of 500 mm.

  15. A new spectrometer design for the x-ray spectroscopy of laser-produced plasmas with high (sub-ns) time resolutiona)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bitter, M.; Hill, K. W.; Efthimion, P. C.; Delgado-Aparicio, L.; Pablant, N.; Lu, Jian; Beiersdorfer, P.; Chen, Hui

    2014-11-01T23:59:59.000Z

    This paper describes a new type of x-ray crystal spectrometer, which can be used in combination with gated x-ray detectors to obtain spectra from laser-produced plasmas with a high (sub-ns) time resolution. The spectrometer consists of a convex, spherically bent crystal, which images individual spectral lines as perfectly straight lines across multiple, sequentially gated, strip detectors. Since the Bragg-reflected rays are divergent, the distance between detector and crystal is arbitrary, so that this distance can be appropriately chosen to optimize the experimental arrangement with respect to the detector parameters. The spectrometer concept was verified in proof-of-principle experiments by imaging themore »L?1- and L?2-lines of tungsten, at 9.6735 and 9.96150 keV, from a micro-focus xray tube with a tungsten target onto a two-dimensional pixilated Pilatus detector, using a convex, spherically bent Si-422 crystal with a radius of curvature of 500 mm.« less

  16. X-ray Fading and Expansion in the "Miniature Supernova Remnant" of GK Persei

    E-Print Network [OSTI]

    Takei, D; Yamaguchi, H; Slane, P; Uchiyama, Y; Katsuda, S

    2015-01-01T23:59:59.000Z

    We report on a second epoch of Chandra X-ray imaging spectroscopy of the spatially-resolved old nova remnant GK Persei. An ACIS-S3 observation of 97.4 ks was conducted in November 2013 after a lapse of 13.8 years from the last visit in 2000. The X-ray emitting nebula appeared more faint and patchy compared with the first epoch. The flux decline was particularly evident in fainter regions and the mean decline was 30-40 % in the 0.5-1.2 keV energy band. A typical expansion of the brightest part of the remnant was 1.9 arcsec, which corresponds to an expansion rate of 0.14 arcsec yr^{-1}. The soft X-ray spectra extracted from both the 2000 and 2013 data can be explained by a non-equilibrium ionization collisional plasma model convolved with interstellar absorption, though do not allow us to constrain the origin of the flux evolution. The plasma temperature has not significantly evolved since the 2000 epoch and we conclude that the fading of the X-ray emission is due largely to expansion. This implies that recent ...

  17. An application of Ti-K X-ray absorption edges and fine structures to the study of substoichiometric titanium carbide TiC1-x

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of substoichiometric titanium carbide TiC1-x V. Moisy-Maurice and C. H. de Novion C.E.A./IRDI/DMECN/DTech, Laboratoire-ray absorption coefficient were made around and up to 1000 eV above the titanium K-edge of TiC1-x samples (0 of titanium deduced from the edge-shift decreases, (ii) the bottom of the titanium 4p bands (situated at 10

  18. Communication: Systematic shifts of the lowest unoccupied molecular orbital peak in x-ray absorption for a series of 3d metal porphyrins

    E-Print Network [OSTI]

    -ray absorption for a series of 3d metal porphyrins J. M. García-Lastra,1,2,a P. L. Cook,3 F. J. Himpsel,3 and A 20 October 2010 Porphyrins are widely used as dye molecules in solar cells. Knowing the energies of their frontier orbitals is crucial for optimizing the energy level structure of solar cells. We use near edge x

  19. Infrared absorption spectroscopy and chemical kinetics of free radicals

    SciTech Connect (OSTI)

    Curl, R.F.; Glass, G.P. [Rice Univ., Houston, TX (United States)

    1993-12-01T23:59:59.000Z

    This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

  20. Reverse engineering the ancient ceramic technology based on X-ray fluorescence spectromicroscopy

    SciTech Connect (OSTI)

    Sciau, Philippe; Leon, Yoanna; Goudeau, Philippe; Fakra, Sirine C.; Webb, Sam; Mehta, Apurva

    2011-07-06T23:59:59.000Z

    We present results of X-ray fluorescence (XRF) microprobe analyses of ancient ceramic cross-sections aiming at deciphering the different firing protocols used for their production. Micro-focused XRF elemental mapping, Fe chemical mapping and Fe K-edge X-ray absorption near edge structure spectroscopy were performed on pre-sigillata ceramics from southern Gaul, and terra Sigillata vessels from Italy and southern Gaul. Pieces from the different workshops and regions showed significant difference in the starting clay material, clay conditioning and kiln firing condition. By contrast, sherds from the same workshop exhibited more subtle differences and possible misfirings. Understanding the precise firing conditions and protocols would allow recreation of kilns for various productions. Furthermore, evolution and modification of kiln design would shed some light on how ancient potters devised solutions to diverse technological problems they encountered.

  1. X-Ray Interactions with Matter from the Center for X-Ray Optics (CXRO)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Henke, B.L.; Gullikson, E.M.; Davis, J.C.

    The primary interactions of low-energy x-rays within condensed matter, viz. photoabsorption and coherent scattering, are described for photon energies outside the absorption threshold regions by using atomic scattering factors. The atomic scattering factors may be accurately determined from the atomic photoabsorption cross sections using modified Kramers-Kronig dispersion relations. From a synthesis of the currently available experimental data and recent theoretical calculations for photoabsorption, the angle-independent, forward-scattering components of the atomic scattering factors have been thus semiempirically determined and tabulated here for 92 elements and for the region 50-30,000 eV. Atomic scattering factors for all angles of coherent scattering and at the higher photon energies are obtained from these tabulated forward-scattering values by adding a simple angle-dependent form-factor correction. The incoherent scattering contributions that become significant for the light elements at the higher photon energies are similarly determined. The basic x-ray interaction relations that are used in applied x-ray physics are presented here in terms of the atomic scattering factors. The bulk optical constants are also related to the atomic scattering factors. These atomic and optical relations are applied to the detailed calculation of the reflectivity characteristics of a series of practical x-ray mirror, multilayer, and crystal monochromators. Comparisons of the results of this semiempirical,"atom-like", description of x-ray interactions for the low-energy region with those of experiment and ab initio theory are presented.

  2. PROBING DYNAMICS OF ELECTRON ACCELERATION WITH RADIO AND X-RAY SPECTROSCOPY, IMAGING, AND TIMING IN THE 2002 APRIL 11 SOLAR FLARE

    SciTech Connect (OSTI)

    Fleishman, Gregory D.; Nita, Gelu M.; Gary, Dale E. [Center for Solar-Terrestrial Research, New Jersey Institute of Technology, Newark, NJ 07102 (United States); Kontar, Eduard P. [Department of Physics and Astronomy, University of Glasgow, Glasgow G12 8QQ (United Kingdom)

    2013-05-10T23:59:59.000Z

    Based on detailed analysis of radio and X-ray observations of a flare on 2002 April 11 augmented by realistic three-dimensional modeling, we have identified a radio emission component produced directly at the flare acceleration region. This acceleration region radio component has distinctly different (1) spectrum, (2) light curves, (3) spatial location, and, thus, (4) physical parameters from those of the separately identified trapped or precipitating electron components. To derive evolution of physical parameters of the radio sources we apply forward fitting of the radio spectrum time sequence with the gyrosynchrotron source function with five to six free parameters. At the stage when the contribution from the acceleration region dominates the radio spectrum, the X-ray- and radio-derived electron energy spectral indices agree well with each other. During this time the maximum energy of the accelerated electron spectrum displays a monotonic increase with time from {approx}300 keV to {approx}2 MeV over roughly one minute duration indicative of an acceleration process in the form of growth of the power-law tail; the fast electron residence time in the acceleration region is about 2-4 s, which is much longer than the time of flight and so requires a strong diffusion mode there to inhibit free-streaming propagation. The acceleration region has a relatively strong magnetic field, B {approx} 120 G, and a low thermal density, n{sub e} {approx}< 2 Multiplication-Sign 10{sup 9} cm{sup -3}. These acceleration region properties are consistent with a stochastic acceleration mechanism.

  3. The XMM-Newton Survey in the Marano Field I. The X-ray data and optical follow-up

    E-Print Network [OSTI]

    M. Krumpe; G. Lamer; A. D. Schwope; S. Wagner; G. Zamorani; M. Mignoli; R. Staubert; L. Wisotzki; G. Hasinger

    2006-12-14T23:59:59.000Z

    We report on a medium deep XMM-Newton survey of the Marano Field and optical follow-up observations. The mosaicked XMM-Newton pointings in this optical quasar survey field cover 0.6 square degree with a total of 120 ksec good observation time. We detected 328 X-ray sources in total. The turnover flux of our sample is f~5x10^(-15) erg/cm^2/s in the 0.2-10 keV band. With VLT FORS1 and FORS2 spectroscopy we classified 96 new X-ray counterparts. The central 0.28 square degree, where detailed optical follow-up observations were performed, contain 170 X-ray sources (detection likelihood ML>10), out of which 48 had already been detected by ROSAT. In this region we recover 23 out of 29 optically selected quasars. With a total of 110 classifications in our core sample we reach a completeness of ~65%. About one third of the XMM-Newton sources is classified as type II AGN with redshifts mostly below 1.0. Furthermore, we detect five high redshift type II AGN (2.2X-ray colors of the core sample indicate that most of the still unidentified X-ray sources are likely to be type II AGN. We calculate absorbing column densities and show that the ratio of absorbed to unabsorbed objects is significantly higher for type II AGN than for type I AGN. Nevertheless, we find a few unabsorbed type II AGN. The X-ray hardness ratios of some high redshift type I AGN also give an indication of heavy absorption. However, none of these type I objects is bright enough for spectral extraction and detailed model fitting. Furthermore, we classified three X-ray bright optically normal galaxies (XBONGs) as counterparts. They show properties similar to type II AGN, probably harbouring an active nucleus.

  4. A SMALL PORTABLE DETECTOR HEAD USING MIS-CONTACTED CdTe FOR X-RAY SPECTROMETRY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    339 A SMALL PORTABLE DETECTOR HEAD USING MIS-CONTACTED CdTe FOR X-RAY SPECTROMETRY P. EICHINGER and the implications of this material for the spectroscopy of gamma rays and X-rays. Instead an arrangement

  5. Opacity of iron, nickel, and copper plasmas in the x-ray wavelength range: Theoretical interpretation of 2p-3d absorption spectra

    SciTech Connect (OSTI)

    Blenski, T.; Loisel, G.; Poirier, M.; Thais, F.; Arnault, P.; Caillaud, T.; Fariaut, J.; Gilleron, F.; Pain, J.-C.; Porcherot, Q.; Reverdin, C.; Silvert, V.; Villette, B.; Bastiani-Ceccotti, S.; Turck-Chieze, S.; Foelsner, W.; Gaufridy de Dortan, F. de [CEA, IRAMIS, Service 'Photons, Atomes et Molecules', Centre d'Etudes de Saclay, F-91191 Gif-sur-Yvette Cedex (France); CEA, DAM, DIF, F-91297 Arpajon (France); LULI, UMR No. 7605 CNRS - Ecole Polytechnique, F-91128 Palaiseau Cedex (France); CEA, IRFU, Service d'Astrophysique, Centre d'Etudes de Saclay, F-91191 Gif-sur-Yvette Cedex (France); Max-Planck-Institut fuer Quantenoptik, D-85748 Garching (Germany); Institute of Nuclear Fusion, Universidad Politecnica de Madrid, Spain and Laboratoire d'Optique Appliquee, ENSTA-Paritech-Polytechnique, Chemin de la Huniere, F-91671 Palaiseau (France)

    2011-09-15T23:59:59.000Z

    This paper deals with theoretical studies on the 2p-3d absorption in iron, nickel, and copper plasmas related to LULI2000 (Laboratoire pour l'Utilisation des Lasers Intenses, 2000J facility) measurements in which target temperatures were of the order of 20 eV and plasma densities were in the range 0.004-0.01 g/cm{sup 3}. The radiatively heated targets were close to local thermodynamic equilibrium (LTE). The structure of 2p-3d transitions has been studied with the help of the statistical superconfiguration opacity code sco and with the fine-structure atomic physics codes hullac and fac. A new mixed version of the sco code allowing one to treat part of the configurations by detailed calculation based on the Cowan's code rcg has been also used in these comparisons. Special attention was paid to comparisons between theory and experiment concerning the term features which cannot be reproduced by sco. The differences in the spin-orbit splitting and the statistical (thermal) broadening of the 2p-3d transitions have been investigated as a function of the atomic number Z. It appears that at the conditions of the experiment the role of the term and configuration broadening was different in the three analyzed elements, this broadening being sensitive to the atomic number. Some effects of the temperature gradients and possible non-LTE effects have been studied with the help of the radiative-collisional code scric. The sensitivity of the 2p-3d structures with respect to temperature and density in medium-Z plasmas may be helpful for diagnostics of LTE plasmas especially in future experiments on the {Delta}n=0 absorption in medium-Z plasmas for astrophysical applications.

  6. Substitution behavior of x(Na{sub 0.5}K{sub 0.5})NbO{sub 3}-(1???x)BaTiO{sub 3} ceramics for multilayer ceramic capacitors by a near edge x-ray absorption fine structure analysis

    SciTech Connect (OSTI)

    Ha, Jooyeon; Ryu, Jiseung; Lee, Heesoo, E-mail: heesoo@pusan.ac.kr [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2014-06-30T23:59:59.000Z

    The doping effect of (Na{sub 0.5}K{sub 0.5})NbO{sub 3} (NKN) as alternatives for rare-earth elements on the electrical properties of BaTiO{sub 3} has been investigated, in terms of their substitution behavior. The dielectric constant of a specimen with x?=?0.05 was about 79% higher than that of pure BaTiO{sub 3}, and the temperature coefficient of capacitance was satisfied by the X7R specification. The specimen with x?=?0.05 showed the lowest tetragonality among the four compositions and had a fine grain size of <2 ?m. Although the addition of NKN decreased the specimen's tetragonality, the electrical properties were enhanced by the formation of defect dipoles and conduction electrons, which resulted from an acceptor and donor substitution behavior. Through O K-edge near edge x-ray absorption fine structure spectroscopy, the practical substitution behavior was defined by the change in Ti 3d orbital states. The energy separation of the Ti 3d orbitals was more apparent with the specimen of x?=?0.05, which is related to the donor level from the donor substitution of Nb{sup 5+} ion for Ti-sites. Therefore, the simultaneous substitution of Na{sup +}/K{sup +} and Nb{sup 5+} ions into BaTiO{sub 3} can improve dielectric properties, based on the charge-transfer process.

  7. Chemical order in Ge{sub x}As{sub y}Se{sub 1-x-y} glasses probed by high resolution X-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Xu, S. W. [Laser Physics Centre, Research School of Physics and Engineering, Australian National University, Canberra, ACT 0200 (Australia); College of Applied Sciences, Beijing University of Technology, Beijing100124 (China); Wang, R. P.; Luther-Davies, B. [Laser Physics Centre, Research School of Physics and Engineering, Australian National University, Canberra, ACT 0200 (Australia); Kovalskiy, A. [Department of Physics and Astronomy, Austin Peay State University, Clarksville, Tennessee 37043 (United States); Miller, A. C.; Jain, H. [Department of Materials Science and Engineering, Lehigh University, 5 East Packer Avenue, Bethlehem, Pennsylvania 18015-3195 (United States)

    2014-02-28T23:59:59.000Z

    We have measured high-resolution x-ray photoelectron spectra of Ge{sub x}As{sub y}Se{sub 1-x-y} glasses with a mean coordination number (MCN) from 2.2 to 2.78. The valence band spectra showed that a number of Se–Se–Se trimers can be found in Se-rich samples, whilst multiband features induced by phase separation can be observed in extremely Se-poor samples. When the Ge, As, and Se 3d spectra were decomposed into several doublets, which correspond, respectively, to different chemical environments, the perfect AsSe{sub 3/2} pyramidal and GeSe{sub 4/2} tetrahedral structures in Se-rich samples gradually evolved into defect structures, including As–As and Ge–Ge homopolar bonds, with increasing Ge and As concentrations. Two transition-like features were found at MCN?=?2.5 and 2.64–2.72 that correspond first to the disappearance of Se-chains in the glass network and, subsequently, destruction of the perfect GeSe{sub 4/2} tetrahedral structures, respectively.

  8. Cryogenic, high-resolution x-ray detector with high count rate capability

    DOE Patents [OSTI]

    Frank, Matthias (Oakland, CA); Mears, Carl A. (Windsor, CA); Labov, Simon E. (Berkeley, CA); Hiller, Larry J. (Livermore, CA); Barfknecht, Andrew T. (Menlo Park, CA)

    2003-03-04T23:59:59.000Z

    A cryogenic, high-resolution X-ray detector with high count rate capability has been invented. The new X-ray detector is based on superconducting tunnel junctions (STJs), and operates without thermal stabilization at or below 500 mK. The X-ray detector exhibits good resolution (.about.5-20 eV FWHM) for soft X-rays in the keV region, and is capable of counting at count rates of more than 20,000 counts per second (cps). Simple, FET-based charge amplifiers, current amplifiers, or conventional spectroscopy shaping amplifiers can provide the electronic readout of this X-ray detector.

  9. Two-dimensional x-ray correlation spectroscopy of remote core states Daniel Healion, Yu Zhang, Jason D. Biggs, Weijie Hua, and Shaul Mukamel

    E-Print Network [OSTI]

    Mukamel, Shaul

    , Jason D. Biggs, Weijie Hua, and Shaul Mukamel Citation: Structural Dynamics 1, 014101 (2014); doi: 10-ray correlation spectroscopy of remote core states Daniel Healion, Yu Zhang, Jason D. Biggs, Weijie Hua, and Shaul

  10. Diagnostic potential of cosmic-neutrino absorption spectroscopy

    SciTech Connect (OSTI)

    Barenboim, Gabriela; /Valencia U.; Mena Requejo, Olga; Quigg, Chris; /Fermilab

    2004-12-01T23:59:59.000Z

    Annihilation of extremely energetic cosmic neutrinos on the relic-neutrino background can give rise to absorption lines at energies corresponding to formation of the electroweak gauge boson Z{sup 0}. The positions of the absorption dips are set by the masses of the relic neutrinos. Suitably intense sources of extremely energetic (10{sup 21} - 10{sup 25}-eV) cosmic neutrinos might therefore enable the determination of the absolute neutrino masses and the flavor composition of the mass eigenstates. Several factors--other than neutrino mass and composition--distort the absorption lines, however. We analyze the influence of the time-evolution of the relic-neutrino density and the consequences of neutrino decay. We consider the sensitivity of the lineshape to the age and character of extremely energetic neutrino sources, and to the thermal history of the Universe, reflected in the expansion rate. We take into account Fermi motion arising from the thermal distribution of the relic-neutrino gas. We also note the implications of Dirac vs. Majorana relics, and briefly consider unconventional neutrino histories. We ask what kinds of external information would enhance the potential of cosmic-neutrino absorption spectroscopy, and estimate the sensitivity required to make the technique a reality.

  11. Diagnostic potential of cosmic-neutrino absorption spectroscopy

    SciTech Connect (OSTI)

    Barenboim, Gabriela; Requejo, Olga Mena; Quigg, Chris [Departament de Fisica Teorica, Universitat de Valencia, Carrer Dr. Moliner 50, E-46100 Burjassot, Valencia (Spain); Theoretical Physics Department, Fermi National Accelerator Laboratory, P.O. Box 500, Batavia, Illinois 60510 (United States)

    2005-04-15T23:59:59.000Z

    Annihilation of extremely energetic cosmic neutrinos on the relic-neutrino background can give rise to absorption lines at energies corresponding to formation of the electroweak gauge boson Z{sup 0}. The positions of the absorption dips are set by the masses of the relic neutrinos. Suitably intense sources of extremely energetic (10{sup 21}-10{sup 25}-eV) cosmic neutrinos might therefore enable the determination of the absolute neutrino masses and the flavor composition of the mass eigenstates. Several factors--other than neutrino mass and composition--distort the absorption lines, however. We analyze the influence of the time evolution of the relic-neutrino density and the consequences of neutrino decay. We consider the sensitivity of the line shape to the age and character of extremely energetic neutrino sources, and to the thermal history of the Universe, reflected in the expansion rate. We take into account Fermi motion arising from the thermal distribution of the relic-neutrino gas. We also note the implications of Dirac vs. Majorana relics, and briefly consider unconventional neutrino histories. We ask what kinds of external information would enhance the potential of cosmic-neutrino absorption spectroscopy, and estimate the sensitivity required to make the technique a reality.

  12. Miniature x-ray source

    DOE Patents [OSTI]

    Trebes, James E. (Livermore, CA); Bell, Perry M. (Tracy, CA); Robinson, Ronald B. (Modesto, CA)

    2000-01-01T23:59:59.000Z

    A miniature x-ray source utilizing a hot filament cathode. The source has a millimeter scale size and is capable of producing broad spectrum x-ray emission over a wide range of x-ray energies. The miniature source consists of a compact vacuum tube assembly containing the hot filament cathode, an anode, a high voltage feedthru for delivering high voltage to the cathode, a getter for maintaining high vacuum, a connector for initial vacuum pump down and crimp-off, and a high voltage connection for attaching a compact high voltage cable to the high voltage feedthru. At least a portion of the vacuum tube wall is fabricated from highly x-ray transparent materials, such as sapphire, diamond, or boron nitride.

  13. Linear accelerator x-ray sources with high duty cycle

    SciTech Connect (OSTI)

    Condron, Cathie; Brown, Craig; Gozani, Tsahi; Langeveld, Willem G. J. [Rapiscan Laboratories, Inc., 520 Almanor Ave. Sunnyvale, CA 94085 (United States); Hernandez, Michael [XScell corp., 2134 Old Middlefield Way, Mountain View, CA 94043 (United States)

    2013-04-19T23:59:59.000Z

    X-ray cargo inspection systems typically use a several-MV pulsed linear accelerator (linac) to produce a bremsstrahlung spectrum of x rays by bombarding a target with electrons. The x rays traverse the cargo and are detected by a detector array. Spectroscopy of the detected x rays is very desirable: if one can determine the spectrum of the transmitted x rays, one can determine the Z of the material they traversed. Even in relatively low-dose modes of operation, thousands of x rays arrive at each detector element during each pulse, unless the x rays are heavily absorbed or scattered by the cargo. For portal or fixed-site systems, dose rates, and therefore x-ray count rates, are even higher. Because of the high x-ray count rate, spectroscopy is impractical in conventional cargo inspection systems, except in certain special cases. For a mobile system, typical pulse durations are a few microseconds, and the number of pulses is on the order of 100 per second, leading to a duty factor of about 0.04%. Clearly, a linear accelerator x-ray source with much higher duty factor would be useful, since then the same number of x rays could be spread out over time, reducing the x-ray count rate. In this paper, we explore the possibility of designing a linear accelerator system, using more or less Conventional Off the Shelf (COTS) components, capable of duty cycles of 1% or greater. A survey was conducted of available linac RF source options and, given the possibilities, calculations were performed for suitable beam centerline designs. Keeping in mind that the size and cost of the accelerator system should be practical for use in a mobile cargo inspection system, only a few options are shown to be reasonably feasible, both requiring the use of klystrons instead of the magnetrons used in conventional systems. An S-Band design appears clearly possible, and there is also a promising X-Band design.

  14. Optical re-injection in cavity-enhanced absorption spectroscopy

    SciTech Connect (OSTI)

    Leen, J. Brian, E-mail: b.leen@lgrinc.com; O’Keefe, Anthony [Los Gatos Research, 67 E. Evelyn Avenue, Suite 3, Mountain View, California 94041 (United States)

    2014-09-15T23:59:59.000Z

    Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10{sup ?10} cm{sup ?1}/?(Hz;) an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features.

  15. A short working distance multiple crystal x-ray spectrometer

    SciTech Connect (OSTI)

    Dickinson, B.; Seidler, G. T.; Webb, Z. W.; Bradley, J. A.; Nagle, K. P. [Department of Physics, University of Washington, Seattle, Washington 98195 (United States); Heald, S. M. [Advanced Photon Source, Argonne National Laboratories, Argonne, Illinois 60439 (United States); Gordon, R. A. [Department of Physics, Simon Fraser University, Burnaby, British Columbia V5A 1S6 (Canada); Chou, I. M. [U.S. Geological Survey, Reston, Virginia 20192 (United States)

    2008-12-15T23:59:59.000Z

    For x-ray spot sizes of a few tens of microns or smaller, a millimeter-sized flat analyzer crystal placed {approx}1 cm from the sample will exhibit high energy resolution while subtending a collection solid angle comparable to that of a typical spherically bent crystal analyzer (SBCA) at much larger working distances. Based on this observation and a nonfocusing geometry for the analyzer optic, we have constructed and tested a short working distance (SWD) multicrystal x-ray spectrometer. This prototype instrument has a maximum effective collection solid angle of 0.14 sr, comparable to that of 17 SBCA at 1 m working distance. We find good agreement with prior work for measurements of the Mn K{beta} x-ray emission and resonant inelastic x-ray scattering for MnO, and also for measurements of the x-ray absorption near-edge structure for Dy metal using L{alpha}{sub 2} partial-fluorescence yield detection. We discuss future applications at third- and fourth-generation light sources. For concentrated samples, the extremely large collection angle of SWD spectrometers will permit collection of high-resolution x-ray emission spectra with a single pulse of the Linac Coherent Light Source. The range of applications of SWD spectrometers and traditional multi-SBCA instruments has some overlap, but also is significantly complementary.

  16. Quantum Limits and Robustness of Nonlinear Intracavity Absorption Spectroscopy

    E-Print Network [OSTI]

    John K. Stockton; Ari K. Tuchman

    2008-10-23T23:59:59.000Z

    We investigate the limits of intracavity absorption spectroscopy with nonlinear media. Using a common theoretical framework, we compare the detection of a trace gas within an undriven cavity with gain near and above threshold, a driven cavity with gain kept just below threshold, and a cavity driven close to the saturation point of a saturable absorber. These phase-transition-based metrology methods are typically quantum-limited by spontaneous emission, and we compare them to the empty cavity shotnoise-limited case. Although the fundamental limits achievable with nonlinear media do not surpass the empty cavity limits, we show that nonlinear methods are more robust against certain technical noise models. This recognition may have applications in spectrometer design for devices operating in non-ideal field environments.

  17. Compact x-ray source and panel

    DOE Patents [OSTI]

    Sampayon, Stephen E. (Manteca, CA)

    2008-02-12T23:59:59.000Z

    A compact, self-contained x-ray source, and a compact x-ray source panel having a plurality of such x-ray sources arranged in a preferably broad-area pixelized array. Each x-ray source includes an electron source for producing an electron beam, an x-ray conversion target, and a multilayer insulator separating the electron source and the x-ray conversion target from each other. The multi-layer insulator preferably has a cylindrical configuration with a plurality of alternating insulator and conductor layers surrounding an acceleration channel leading from the electron source to the x-ray conversion target. A power source is connected to each x-ray source of the array to produce an accelerating gradient between the electron source and x-ray conversion target in any one or more of the x-ray sources independent of other x-ray sources in the array, so as to accelerate an electron beam towards the x-ray conversion target. The multilayer insulator enables relatively short separation distances between the electron source and the x-ray conversion target so that a thin panel is possible for compactness. This is due to the ability of the plurality of alternating insulator and conductor layers of the multilayer insulators to resist surface flashover when sufficiently high acceleration energies necessary for x-ray generation are supplied by the power source to the x-ray sources.

  18. Thermal stability in the blended lithium manganese oxide – Lithium nickel cobalt manganese oxide cathode materials: An in situ time-resolved X-Ray diffraction and mass spectroscopy study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Enyuan; Bak, Seong Min; Senanayake, Sanjaya D.; Yang, Xiao-Qing; Nam, Kyung-Wan; Zhang, Lulu; Shao, Minhua

    2015-03-01T23:59:59.000Z

    Thermal stabilities of a series of blended LiMn2O4(LMO)-LiNi1/3Co1/3Mn1/3O2 (NCM) cathode materials with different weight ratios were studied by in situ time-resolved X-ray diffraction (XRD) combined with mass spectroscopy in the temperature range of 25°C-580°C under helium atmosphere. Upon heating, the electrochemically delithiated LMO changed into Mn3O4 phase at around 250°C. Formation of MnO with rocksalt structure started at 520°C. This observation is in contrast to the previous report for chemically delithiate LMO in air, in which a process of ?-MnO2 transforming to ?-MnO2 was observed. Oxygen peak was not observed in all cases, presumably as a result of either consumptionmore »by the carbon or detection limit. CO2 profile correlates well with the phase transition and indirectly suggests the oxygen release of the cathode. Introducing NCM into LMO has two effects: first, it makes the high temperature rock-salt phase formation more complicated with more peaks in CO2 profile due to different MO (M = Ni, Mn, Co) phases; secondly, the onset temperature of CO2 release is lowered, implying lowered oxygen release temperature. Upon heating, XRD patterns indicate the NCM part reacts first, followed by the LMO part. This confirms the better thermal stability of LMO over NCM.« less

  19. Thermal stability in the blended lithium manganese oxide – Lithium nickel cobalt manganese oxide cathode materials: An in situ time-resolved X-Ray diffraction and mass spectroscopy study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Enyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); Bak, Seong Min [Brookhaven National Lab. (BNL), Upton, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yang, Xiao-Qing [Dongguk Univ., Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering; Nam, Kyung-Wan [Dongguk Univ., Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering] (ORCID:0000000162786369); Zhang, Lulu [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong); Shao, Minhua

    2015-03-01T23:59:59.000Z

    Thermal stabilities of a series of blended LiMn2O4(LMO)-LiNi1/3Co1/3Mn1/3O2 (NCM) cathode materials with different weight ratios were studied by in situ time-resolved X-ray diffraction (XRD) combined with mass spectroscopy in the temperature range of 25°C-580°C under helium atmosphere. Upon heating, the electrochemically delithiated LMO changed into Mn3O4 phase at around 250°C. Formation of MnO with rocksalt structure started at 520°C. This observation is in contrast to the previous report for chemically delithiate LMO in air, in which a process of ?-MnO2 transforming to ?-MnO2 was observed. Oxygen peak was not observed in all cases, presumably as a result of either consumption by the carbon or detection limit. CO2 profile correlates well with the phase transition and indirectly suggests the oxygen release of the cathode. Introducing NCM into LMO has two effects: first, it makes the high temperature rock-salt phase formation more complicated with more peaks in CO2 profile due to different MO (M = Ni, Mn, Co) phases; secondly, the onset temperature of CO2 release is lowered, implying lowered oxygen release temperature. Upon heating, XRD patterns indicate the NCM part reacts first, followed by the LMO part. This confirms the better thermal stability of LMO over NCM.

  20. In-operando hard X-ray photoelectron spectroscopy study on the impact of current compliance and switching cycles on oxygen and carbon defects in resistive switching Ti/HfO{sub 2}/TiN cells

    SciTech Connect (OSTI)

    Sowinska, Malgorzata, E-mail: sowinska@ihp-microelectronics.com; Bertaud, Thomas; Walczyk, Damian; Calka, Pauline; Walczyk, Christian [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Thiess, Sebastian [Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg (Germany); Alff, Lambert [Institute of Materials Science, Technische Universität Darmstadt, 64287 Darmstadt (Germany); Schroeder, Thomas [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Brandenburgische Technische Universität, Konrad-Zuse-Strasse 1, 03046 Cottbus (Germany)

    2014-05-28T23:59:59.000Z

    In this study, direct experimental materials science evidence of the important theoretical prediction for resistive random access memory (RRAM) technologies that a critical amount of oxygen vacancies is needed to establish stable resistive switching in metal-oxide-metal samples is presented. In detail, a novel in-operando hard X-ray photoelectron spectroscopy technique is applied to non-destructively investigates the influence of the current compliance and direct current voltage sweep cycles on the Ti/HfO{sub 2} interface chemistry and physics of resistive switching Ti/HfO{sub 2}/TiN cells. These studies indeed confirm that current compliance is a critical parameter to control the amount of oxygen vacancies in the conducting filaments in the oxide layer during the RRAM cell operation to achieve stable switching. Furthermore, clear carbon segregation towards the Ti/HfO{sub 2} interface under electrical stress is visible. Since carbon impurities impact the oxygen vacancy defect population under resistive switching, this dynamic carbon segregation to the Ti/HfO{sub 2} interface is suspected to negatively influence RRAM device endurance. Therefore, these results indicate that the RRAM materials engineering needs to include all impurities in the dielectric layer in order to achieve reliable device performance.

  1. A high pressure cell for supercritical CO{sub 2} on-line chemical reactions studied with x-ray techniques

    SciTech Connect (OSTI)

    Hermida-Merino, Daniel; Portale, Giuseppe; Bras, Wim, E-mail: Wim.Bras@esrf.eu, E-mail: Steve.Howdle@nottingham.ac.uk [DUBBLE@ESRF, Netherlands Organisation for Scientific Research (N.W.O.), CS40220, 38043, Grenoble, Cedex 9 (France); Fields, Peter; Wilson, Richard; Bassett, Simon P.; Jennings, James; Dellar, Martin; Howdle, Steven M., E-mail: Wim.Bras@esrf.eu, E-mail: Steve.Howdle@nottingham.ac.uk [School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom); Gommes, Cedric [Department of Chemical Engineering, University of Liège B6A, allée du 6 Août 3, B-4000 Liège (Belgium); Vrolijk, Benno C. M. [Element Six BV, P.O. Box 119, 5430 AC Cuijk (Netherlands)

    2014-09-15T23:59:59.000Z

    A versatile high pressure X-ray sample cell has been developed for conducting in situ time-resolved X-ray scattering experiments in the pressure and temperature regime required (pressures up to 210 bars and temperatures up to 120 °C) for chemical reactions in supercritical fluids. The large exit opening angle of the cell allows simultaneous performance of SAXS-WAXS experiments. Diamond windows are used in order to benefit from the combination of maximum strength, minimal X-ray absorption and chemical inertia. The sample cell can also be utilised for X-ray spectroscopy experiments over a wide range of photon energies. Results of the online synthesis of a block copolymer, poly(methyl methacrylate-block-poly(benzyl methacrylate), by Reversible Addition-Fragmentation Chain Transfer (RAFT) in a supercritical CO{sub 2} dispersion polymerisation will be discussed. The contribution of the density fluctuations, as function of temperature, to the X-ray scattering signal has been quantified in order to allow appropriate background subtractions.

  2. Sulfur X-Ray Absorption And Vibrational Spectroscopic Study of Sulfur Dioxide, Sulfite, And Sulfonate Solutions And of the Substituted Sulfonate Ions X(3)CSO(3-)(X = H, Cl, F)

    SciTech Connect (OSTI)

    Risberg, E.Damian; Eriksson, L.; Mink, J.; Pettersson, L.G.M.; Skripkin, M.Yu.; Sandstrom, M.

    2009-06-02T23:59:59.000Z

    Sulfur K-edge X-ray absorption near-edge structure (XANES) spectra have been recorded and the S(1s) electron excitations evaluated by means of density functional theory-transition potential (DFT-TP) calculations to provide insight into the coordination, bonding, and electronic structure. The XANES spectra for the various species in sulfur dioxide and aqueous sodium sulfite solutions show considerable differences at different pH values in the environmentally important sulfite(IV) system. In strongly acidic (pH < {approx}1) aqueous sulfite solution the XANES spectra confirm that the hydrated sulfur dioxide molecule, SO{sub 2}(aq), dominates. The theoretical spectra are consistent with an OSO angle of {approx}119{sup o} in gas phase and acetonitrile solution, while in aqueous solution hydrogen bonding reduces the angle to {approx}116{sup o}. The hydration affects the XANES spectra also for the sulfite ion, SO{sub 3}{sup 2-}. At intermediate pH (4) the two coordination isomers, the sulfonate (HSO{sub 3{sup -}}) and hydrogen sulfite (SO{sub 3}H{sup -}) ions with the hydrogen atom coordinated to sulfur and oxygen, respectively, could be distinguished with the ratio HSO{sub 3{sup -}}:SO{sub 3}H{sup -} about 0.28:0.72 at 298 K. The relative amount of HSO{sub 3{sup -}} increased with increasing temperature in the investigated range from 275 to 343 K. XANES spectra of sulfonate, methanesulfonate, trichloromethanesulfonate, and trifluoromethanesulfonate compounds, all with closely similar S-O bond distances in tetrahedral configuration around the sulfur atom, were interpreted by DFT-TP computations. The energy of their main electronic transition from the sulfur K-shell is about 2478 eV. The additional absorption features are similar when a hydrogen atom or an electron-donating methyl group is bonded to the -SO{sub 3} group. Significant changes occur for the electronegative trichloromethyl (Cl{sub 3}C-) and trifluoromethyl (F{sub 3}C-) groups, which strongly affect the distribution especially of the {pi} electrons around the sulfur atom. The S-D bond distance 1.38(2) {angstrom} was obtained for the deuterated sulfonate (DSO{sub 3{sup -}}) ion by Rietveld analysis of neutron powder diffraction data of CsDSO{sub 3}. Raman and infrared absorption spectra of the CsHSO{sub 3}, CsDSO{sub 3}, H{sub 3}CSO{sub 3}Na, and Cl{sub 3}CSO{sub 3}Na{center_dot}H{sub 2}O compounds and Raman spectra of the sulfite solutions have been interpreted by normal coordinate calculations. The C-S stretching force constant for the trichloromethanesulfonate ion obtains an anomalously low value due to steric repulsion between the Cl{sub 3}C- and -SO{sub 3} groups. The S-O stretching force constants were correlated with corresponding S-O bond distances for several oxosulfur species.

  3. Focused X-ray source

    DOE Patents [OSTI]

    Piestrup, M.A.; Boyers, D.G.; Pincus, C.I.; Maccagno, P.

    1990-08-21T23:59:59.000Z

    Disclosed is an intense, relatively inexpensive X-ray source (as compared to a synchrotron emitter) for technological, scientific, and spectroscopic purposes. A conical radiation pattern produced by a single foil or stack of foils is focused by optics to increase the intensity of the radiation at a distance from the conical radiator. 8 figs.

  4. Are Optically-Selected Quasars Universally X-Ray Luminous? X-Ray/UV Relations in Sloan Digital Sky Survey Quasars

    E-Print Network [OSTI]

    Robert R. Gibson; W. N. Brandt; Donald P. Schneider

    2008-08-19T23:59:59.000Z

    We analyze archived Chandra and XMM-Newton X-ray observations of 536 Sloan Digital Sky Survey (SDSS) Data Release 5 (DR5) quasars (QSOs) at 1.7 <= z <= 2.7 in order to characterize the relative UV and X-ray spectral properties of QSOs that do not have broad UV absorption lines (BALs). We constrain the fraction of X-ray weak, non-BAL QSOs and find that such objects are rare; for example, sources underluminous by a factor of 10 comprise $\\la$2% of optically-selected SDSS QSOs. X-ray luminosities vary with respect to UV emission by a factor of $\\la$2 over several years for most sources. UV continuum reddening and the presence of narrow-line absorbing systems are not strongly associated with X-ray weakness in our sample. X-ray brightness is significantly correlated with UV emission line properties, so that relatively X-ray weak, non-BAL QSOs generally have weaker, blueshifted CIV$\\lambda$1549 emission and broader CIII]$\\lambda$1909 lines. The CIV emission line strength depends on both UV and X-ray luminosity, suggesting that the physical mechanism driving the global Baldwin effect is also associated with X-ray emission.

  5. Probing bismuth ferrite nanoparticles by hard x-ray photoemission: Anomalous occurrence of metallic bismuth

    SciTech Connect (OSTI)

    Chaturvedi, Smita; Rajendra, Ranguwar; Ballav, Nirmalya; Kulkarni, Sulabha, E-mail: s.kulkarni@iiserpune.ac.in [Indian Institute of Science Education and Research, Dr. Homi Bhabha Road, Pune 411008 (India); Sarkar, Indranil [DESY Photon Science, Deutsches Elektronen-Synchrotron, 22607 Hamburg (Germany); Shirolkar, Mandar M. [Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026 (China); Jeng, U-Ser; Yeh, Yi-Qi [National Synchrotron Radiation Research Center, 101, Hsin-Ann Road, Science Park, Hsinchu 3007-6, Taiwan (China)

    2014-09-08T23:59:59.000Z

    We have investigated bismuth ferrite nanoparticles (?75?nm and ?155?nm) synthesized by a chemical method, using soft X-ray (1253.6?eV) and hard X-ray (3500, 5500, and 7500?eV) photoelectron spectroscopy. This provided an evidence for the variation of chemical state of bismuth in crystalline, phase pure nanoparticles. X-ray photoelectron spectroscopy analysis using Mg K? (1253.6?eV) source showed that iron and bismuth were present in both Fe{sup 3+} and Bi{sup 3+} valence states as expected for bismuth ferrite. However, hard X-ray photoelectron spectroscopy analysis of the bismuth ferrite nanoparticles using variable photon energies unexpectedly showed the presence of Bi{sup 0} valence state below the surface region, indicating that bismuth ferrite nanoparticles are chemically inhomogeneous in the radial direction. Consistently, small-angle X-ray scattering reveals a core-shell structure for these radial inhomogeneous nanoparticles.

  6. X-ray pump optical probe cross-correlation study of GaAs

    SciTech Connect (OSTI)

    Durbin, S.M.; Clevenger, T.; Graber, T.; Henning, R. (Purdue); (UC)

    2012-09-10T23:59:59.000Z

    Ultrafast dynamics in atomic, molecular and condensed-matter systems are increasingly being studied using optical-pump, X-ray probe techniques where subpicosecond laser pulses excite the system and X-rays detect changes in absorption spectra and local atomic structure. New opportunities are appearing as a result of improved synchrotron capabilities and the advent of X-ray free-electron lasers. These source improvements also allow for the reverse measurement: X-ray pump followed by optical probe. We describe here how an X-ray pump beam transforms a thin GaAs specimen from a strong absorber into a nearly transparent window in less than 100 ps, for laser photon energies just above the bandgap. We find the opposite effect - X-ray induced optical opacity - for photon energies just below the bandgap. This raises interesting questions about the ultrafast many-body response of semiconductors to X-ray absorption, and provides a new approach for an X-ray/optical cross-correlator for synchrotron and X-ray free-electron laser applications.

  7. Eta Car and Its Surroundings: the X-ray Diagnosis

    E-Print Network [OSTI]

    M. F. Corcoran; K. Hamaguchi

    2007-03-02T23:59:59.000Z

    X-ray emission from the supermassive star Eta Carinae (\\ec) originates from hot shocked gas produced by current stellar mass loss as well as ejecta from prior eruptive events. Absorption of this emission by cool material allows the determination of the spatial and temporal distribution of this material. Emission from the shocked gas can provide important information about abundances through the study of thermal X-ray line emission. We discuss how studies of the X-ray emission from Eta Car at a variety of temporal, spatial and spectral scales and resolutions have helped refine our knowledge of both the continuous and discrete mass loss from the system, and its interactions with more extended material around the star.

  8. Producing X-rays at the APS

    ScienceCinema (OSTI)

    None

    2013-04-19T23:59:59.000Z

    An introduction and overview of the Advanced Photon Source at Argonne National Laboratory, the technology that produces the brightest X-ray beams in the Western Hemisphere, and the research carried out by scientists using those X-rays.

  9. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X-Ray Imaging in Reflection Print The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs...

  10. APS X-rays Reveal Picasso's Secret

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | 2003 | 2002 | 2001 2000 Subscribe to APS News rss feed APS X-rays Reveal Picasso's Secret OCTOBER 15, 2012 Bookmark and Share X-rays reveal that Picasso's "Old Guitarist," at...

  11. Spectral analysis of X-ray binaries

    E-Print Network [OSTI]

    Fridriksson, Joel Karl

    2011-01-01T23:59:59.000Z

    In this thesis, I present work from three separate research projects associated with observations of X-ray binaries. Two of those revolve around spectral characteristics of neutron star low-mass X-ray binaries (NS-LMXBs), ...

  12. Microgap x-ray detector

    DOE Patents [OSTI]

    Wuest, C.R.; Bionta, R.M.; Ables, E.

    1994-05-03T23:59:59.000Z

    An x-ray detector is disclosed which provides for the conversion of x-ray photons into photoelectrons and subsequent amplification of these photoelectrons through the generation of electron avalanches in a thin gas-filled region subject to a high electric potential. The detector comprises a cathode (photocathode) and an anode separated by the thin, gas-filled region. The cathode may comprise a substrate, such a beryllium, coated with a layer of high atomic number material, such as gold, while the anode can be a single conducting plane of material, such as gold, or a plane of resistive material, such as chromium/silicon monoxide, or multiple areas of conductive or resistive material, mounted on a substrate composed of glass, plastic or ceramic. The charge collected from each electron avalanche by the anode is passed through processing electronics to a point of use, such as an oscilloscope. 3 figures.

  13. Microgap x-ray detector

    DOE Patents [OSTI]

    Wuest, Craig R. (Danville, CA); Bionta, Richard M. (Livermore, CA); Ables, Elden (Livermore, CA)

    1994-01-01T23:59:59.000Z

    An x-ray detector which provides for the conversion of x-ray photons into photoelectrons and subsequent amplification of these photoelectrons through the generation of electron avalanches in a thin gas-filled region subject to a high electric potential. The detector comprises a cathode (photocathode) and an anode separated by the thin, gas-filled region. The cathode may comprise a substrate, such a beryllium, coated with a layer of high atomic number material, such as gold, while the anode can be a single conducting plane of material, such as gold, or a plane of resistive material, such as chromium/silicon monoxide, or multiple areas of conductive or resistive material, mounted on a substrate composed of glass, plastic or ceramic. The charge collected from each electron avalanche by the anode is passed through processing electronics to a point of use, such as an oscilloscope.

  14. X-ray Properties of Young Stellar Objects in OMC-2 and OMC-3 from the Chandra X-ray Observatory

    E-Print Network [OSTI]

    M. Tsujimoto; K. Koyama; Y. Tsuboi; M. Goto; N. Kobayashi

    2001-10-12T23:59:59.000Z

    We report X-ray results of the Chandra observation of Orion Molecular Cloud 2 and 3. A deep exposure of \\sim 100 ksec detects \\sim 400 X-ray sources in the field of view of the ACIS array, providing one of the largest X-ray catalogs in a star forming region. Coherent studies of the source detection, time variability, and energy spectra are performed. We classify the X-ray sources into class I, class II, and class III+MS based on the J, H, and K-band colors of their near infrared counterparts and discuss the X-ray properties (temperature, absorption, and time variability) along these evolutionary phases.

  15. Spatial resolution of synchrotron x-ray microtomography in high energy range: Effect of x-ray energy and sample-to-detector distance

    SciTech Connect (OSTI)

    Seo, D.; Tomizato, F.; Toda, H.; Kobayashi, M. [Department of Mechanical Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580 (Japan); Uesugi, K.; Takeuchi, A.; Suzuki, Y. [Japan Synchrotron Radiation Research Institute, Mikazuki, Sayo, Hyogo 679-5198 (Japan)

    2012-12-24T23:59:59.000Z

    Spatial resolution of three-dimensional images obtained by synchrotron X-ray microtomography technique is evaluated using cyclic bar patterns machined on a steel wire. Influences of X-ray energy and the sample-to-detector distance on spatial resolution were investigated. High X-ray energies of 33-78 keV are applied due to the high X-ray absorption of transition metals. Best spatial resolution of about 1.2 {mu}m pitch was observed at the sample-to-detector distance range of 20-110 mm and at the energy range of 68-78 keV. Several factors such as X-ray scattering and diffraction phenomena affecting the degradation of spatial resolution are also discussed.

  16. Phase-sensitive X-ray imager

    DOE Patents [OSTI]

    Baker, Kevin Louis

    2013-01-08T23:59:59.000Z

    X-ray phase sensitive wave-front sensor techniques are detailed that are capable of measuring the entire two-dimensional x-ray electric field, both the amplitude and phase, with a single measurement. These Hartmann sensing and 2-D Shear interferometry wave-front sensors do not require a temporally coherent source and are therefore compatible with x-ray tubes and also with laser-produced or x-pinch x-ray sources.

  17. Atomic force microscopy and x-ray photoelectron spectroscopy investigations of the morphology and chemistry of a PdCl{sub 2}/SnCl{sub 2} electroless plating catalysis system adsorbed onto shape memory alloy particles

    SciTech Connect (OSTI)

    Silvain, J.F.; Fouassier, O.; Lescaux, S. [Institut de Chimie de la Matiere Condensee de Bordeaux (ICMCB) - CNRS, Universite de Bordeaux 1, 87 Avenue du Dr A. Schweitzer, F-33608 PESSAC (France); Veeco, Z.I. de la Gaudree, 11 Rue Marie Poussepin, F-91412 Dourdain (France)

    2004-11-01T23:59:59.000Z

    A study of the different stages of the electroless deposition of copper on micronic NiTi shape memory alloy particles activated by one-step and two-step methods has been conducted from both a chemical and a morphological point of view. The combination of x-ray photoelectron spectroscopy (XPS) measurements and atomic force microscopy (AFM) imaging has allowed detection of the distribution of the formed compounds and depth quantification and estimation of the surface topographic parameters. For the two-step method, at the sensitization of the early stages, it is observed by AFM that Sn is absorbed in form of clusters that tend to completely cover the surface and form a continuous film. XPS analysis have shown that Sn and Pd are first absorbed in form of oxide (SnO{sub 2} and PdO) and hydroxide [Sn(OH){sub 4}]. After the entire sensitization step, the NiTi substrate is covered with Sn-based compounds. After the sensitization and the activation steps the powder roughness increases. Behavior of the Sn and Pd growth for the one-step method does not follow the behavior found for the two-step method. Indeed, XPS analysis shows a three-dimensional (3D) growth of Pd clusters on top of a mixture of metallic tin, oxide (SnO) and hydroxide [Sn(OH){sub 2}]. These Pd clusters are covered with a thin layer of Pd-oxide contamination induced by the electroless process. The mean roughness for the one-step and two-step processes are equivalent. After copper deposition, the decrease of mean roughness is attributed to a filling of surface valleys, observed after the Sn-Pd coating step.

  18. Deduction of the chemical state and the electronic structure of Nd{sub 2}Fe{sub 14}B compound from X-ray photoelectron spectroscopy core-level and valence-band spectra

    SciTech Connect (OSTI)

    Wang, Jing; Liang, Le [School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Zhang, Lanting, E-mail: lantingzh@sjtu.edu.cn, E-mail: lmsun@sjtu.edu.cn [School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Hirano Institute for Materials Innovation, Shanghai Jiao Tong University, Shanghai 200240 (China); Sun, Limin, E-mail: lantingzh@sjtu.edu.cn, E-mail: lmsun@sjtu.edu.cn [Instrumental Analysis Center, Shanghai Jiao Tong University, Shanghai 200240 (China); Hirano, Shinichi [Hirano Institute for Materials Innovation, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2014-10-28T23:59:59.000Z

    Characterization of chemical state and electronic structure of the technologically important Nd{sub 2}Fe{sub 14}B compound is attractive for understanding the physical nature of its excellent magnetic properties. X-ray photoelectron spectroscopy (XPS) study of such rare-earth compound is important and also challenging due to the easy oxidation of surface and small photoelectron cross-sections of rare-earth 4f electrons and B 2p electrons, etc. Here, we reported an investigation based on XPS spectra of Nd{sub 2}Fe{sub 14}B compound as a function of Ar ion sputtering time. The chemical state of Fe and that of B in Nd{sub 2}Fe{sub 14}B compound can be clearly determined to be 0 and ?3, respectively. The Nd in Nd{sub 2}Fe{sub 14}B compound is found to have the chemical state of close to +3 instead of +3 as compared with the Nd in Nd{sub 2}O{sub 3}. In addition, by comparing the valence-band spectrum of Nd{sub 2}Fe{sub 14}B compound to that of the pure Fe, the contributions from Nd, Fe, and B to the valence-band structure of Nd{sub 2}Fe{sub 14}B compound is made more clear. The B 2p states and B 2s states are identified to be at ?11.2 eV and ?24.6 eV, respectively, which is reported for the first time. The contribution from Nd 4f states can be identified both in XPS core-level spectrum and XPS valence-band spectrum. Although Nd 4f states partially hybridize with Fe 3d states, Nd 4f states are mainly localized in Nd{sub 2}Fe{sub 14}B compound.

  19. A multi-crystal wavelength dispersive x-ray spectrometer

    SciTech Connect (OSTI)

    Alonso-Mori, Roberto; Montanez, Paul; Delor, James; Bergmann, Uwe [LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Kern, Jan [LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Physical Biosciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720-8099 (United States); Sokaras, Dimosthenis; Weng, Tsu-Chien; Nordlund, Dennis [SSRL, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Tran, Rosalie; Yachandra, Vittal K.; Yano, Junko [Physical Biosciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720-8099 (United States)

    2012-07-15T23:59:59.000Z

    A multi-crystal wavelength dispersive hard x-ray spectrometer with high-energy resolution and large solid angle collection is described. The instrument is specifically designed for time-resolved applications of x-ray emission spectroscopy (XES) and x-ray Raman scattering (XRS) at X-ray Free Electron Lasers (XFEL) and synchrotron radiation facilities. It also simplifies resonant inelastic x-ray scattering (RIXS) studies of the whole 2d RIXS plane. The spectrometer is based on the Von Hamos geometry. This dispersive setup enables an XES or XRS spectrum to be measured in a single-shot mode, overcoming the scanning needs of the Rowland circle spectrometers. In conjunction with the XFEL temporal profile and high-flux, it is a powerful tool for studying the dynamics of time-dependent systems. Photo-induced processes and fast catalytic reaction kinetics, ranging from femtoseconds to milliseconds, will be resolvable in a wide array of systems circumventing radiation damage.

  20. Extending The Methodology Of X-ray Crystallography To Allow X-ray

    E-Print Network [OSTI]

    Miao, Jianwei "John"

    , the radiation damage. While the radiation damage problem can be mitigated somewhat by using cryogenic techniques resolution without serious radiation damage to the specimens. Although X-ray crystallography becomesExtending The Methodology Of X-ray Crystallography To Allow X-ray Microscopy Without X-ray Optics

  1. SMB, X-Ray Spectroscopy & Imaging

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobs RunningSEABRV2/01/12SMB SMB

  2. Synchronization of x-ray pulses to the pump laser in an ultrafast x-ray facility

    E-Print Network [OSTI]

    Corlett, J.N.; Barry, W.; Byrd, J.M.; Schoenlein, R.; Zholents, A.

    2002-01-01T23:59:59.000Z

    Accurate timing of ultrafast x-ray probe pulses emitted fromOF X-RAY PULSES TO THE PUMP LASER IN AN ULTRAFAST X-RAY

  3. High Resolution X-Ray Scattering at Sector 3, Advanced Photon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    about 1 meV resolution; momentum resolved inelastic x-ray scattering with about 1 meV resolution (HERIX); Synchrotron Mossbauer spectroscopy with about 10 neV resolution (SMS)....

  4. SciTech Connect: Validations of Time-Resolved X-Ray Emissions...

    Office of Scientific and Technical Information (OSTI)

    Validations of Time-Resolved X-Ray Emissions Spectroscopy for Analysis of Mn-Based Natural and Artifical Sunlight-to-Energy Assemblies Citation Details In-Document Search Title:...

  5. Evidence Against BALS in the X-ray Bright QSO PG1416-129

    E-Print Network [OSTI]

    Paul J. Green; Thomas L. Aldcroft; Smita Mathur; Norbert Schartel

    1997-02-24T23:59:59.000Z

    Recent results from the ROSAT All Sky Survey, and from deep ROSAT pointings reveal that broad absorption line quasars (BALQSOs) are weak in the soft X-ray bandpass (with optical-to-X-ray spectral slope alpha_{ox}>1.8) in comparison to QSOs with normal OUV spectra (mean alpha_{ox}=1.4). One glaring exception appeared to be the nearby BALQSO PG1416-129, which is a bright ROSAT source showing no evidence for intrinsic soft X-ray absorption. We present here our new HST FOS spectrum of PG1416-129, in which we find no evidence for BALs. We show that the features resulting in the original BAL classification, based on IUE spectra, were probably spurious. On the basis of UV, X-ray and optical evidence, we conclude that PG1416-129, is not now, and has never been a BALQSO. Our result suggests that weak soft X-ray emission is a defining characteristic of true BALQSOs. If BALQSOs indeed harbor normal intrinsic spectral energy distributions, their observed soft X-ray weakness is most likely the result of absorption. The ubiquitous occurrence of weak soft X-ray emission with UV absorption (BALs) thus suggests absorbers in each energy regime that are physically associated, if not identical.

  6. Imaging of lateral spin valves with soft x-ray microscopy

    SciTech Connect (OSTI)

    Mosendz, O.; Mihajlovic, G.; Pearson, J. E.; Fischer, P.; Im, M.-Y.; Bader, S. D.; Hoffmann, A.

    2009-05-01T23:59:59.000Z

    We investigated Co/Cu lateral spin valves by means of high-resolution transmission soft x-ray microscopy with magnetic contrast that utilizes x-ray magnetic circular dichroism (XMCD). No magnetic XMCD contrast was observed at the Cu L{sub 3} absorption edge, which should directly image the spin accumulation in Cu. Although electrical transport measurements in a non-local geometry clearly detected the spin accumulation in Cu, which remained unchanged during illumination with circular polarized x-rays at the Co and Cu L{sub 3} absorption edges.

  7. Imaging of lateral spin valves with soft x-ray microscopy.

    SciTech Connect (OSTI)

    Mosendz, O.; Mihajlovic, G.; Pearson, J. E.; Fischer, P.; Im, M.-Y.; Bader, S. D.; Hoffmann, A.; LBNL

    2009-01-01T23:59:59.000Z

    We investigated Co/Cu lateral spin valves by means of high-resolution transmission soft x-ray microscopy with magnetic contrast that utilizes x-ray magnetic circular dichroism (XMCD). No magnetic XMCD contrast was observed at the Cu L{sub 3} absorption edge, which should directly image the spin accumulation in Cu, although electrical transport measurements in a nonlocal geometry clearly detected the spin accumulation in Cu, which remained unchanged during illumination with circular polarized x rays at the Co and Cu L{sub 3} absorption edges.

  8. X-ray holography of biological specimens

    SciTech Connect (OSTI)

    Solem, J.C.

    1984-01-01T23:59:59.000Z

    The author reviews the reasons for x-ray imaging of biological specimens and the techniques presently being used for x-ray microscopy. The author points out the advantages of x-ray holography and the difficulties of obtaining the requisite coherence with conventional sources. The author discusses the problems of radiation damage and the remarkable fact that short pulse x-ray sources circumvent these problems and obtain high-resolution images of specimens in the living state. Finally, the author reviews some of the efforts underway to develop high-intensity coherent x-ray sources for the laboratory. 14 references, 5 figures, 2 tables.

  9. Borman effect in resonant diffraction of X-rays

    SciTech Connect (OSTI)

    Oreshko, A. P., E-mail: ap.oreshko@physics.msu.ru [Moscow State University (Russian Federation)

    2013-08-15T23:59:59.000Z

    A dynamic theory of resonant diffraction (occurring when the energy of incident radiation is close to the energy of the absorption edge of an element in the composition of a given substance) of synchronous X-rays is developed in the two-wave approximation in the coplanar Laue geometry for large grazing angles in perfect crystals. A sharp decrease in the absorption coefficient in the substance with simultaneously satisfied diffraction conditions (Borman effect) is demonstrated, and the theoretical and first experimental results are compared. The calculations reveal the possibility of applying this approach in analyzing the quadrupole-quadrupole contribution to the absorption coefficient.

  10. Journal of Electron Spectroscopy and Related Phenomena 154 (2007) 6062 Investigation of vanadiumsodium silicate glasses using

    E-Print Network [OSTI]

    Mekki, Abdelkarim

    ­sodium silicate glasses using XANES spectroscopy M. Faiza,, A. Mekkia, B.S. Munb, Z. Hussainb a Surface Science. Keywords: XANES; Vanadium­sodium silicate glasses; V L2,3 edges; O K edge 1. Introduction Studies on oxide vanadium-sodium silicate glasses. X-ray absorption near edge structure (XANES) spectroscopy is a pow- erful

  11. Soft X-ray techniques to study mesoscale magnetism

    E-Print Network [OSTI]

    Kortright, Jeffrey B.

    2003-01-01T23:59:59.000Z

    X-Ray Techniques to Study Mesoscale Magnetism Jeffrey B.X-Ray Techniques to Study Mesoscale Magnetism Jeffrey B.

  12. Measurement of Water Vapor Concentration using Tunable Diode Laser Absorption Spectroscopy

    E-Print Network [OSTI]

    Barrett, Alexander B.

    2010-07-14T23:59:59.000Z

    Tunable diode laser spectroscopy and the Beer-Lambert relation has been used to measure the absorption of water vapor both in an absorption cell and in a shock tube. The purpose of this thesis is to develop a laser diagnostic capable of determining...

  13. absorption spectroscopy q-xas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy q-xas First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino Absorption...

  14. Techniques for synchronization of X-Ray pulses to the pump laser in an ultrafast X-Ray facility

    E-Print Network [OSTI]

    Corlett, J.N.; Doolittle, L.; Schoenlein, R.; Staples, J.; Wilcox, R.; Zholents, A.

    2003-01-01T23:59:59.000Z

    synchronization of ultrafast x-ray pulses produced in theAccurate timing of ultrafast x-ray probe pulses emitted fromOF X-RAY PULSES TO THE PUMP LASER IN AN ULTRAFAST X-RAY

  15. X-ray transmissive debris shield

    DOE Patents [OSTI]

    Spielman, Rick B. (Albuquerque, NM)

    1994-01-01T23:59:59.000Z

    A composite window structure is described for transmitting x-ray radiation and for shielding radiation generated debris. In particular, separate layers of different x-ray transmissive materials are laminated together to form a high strength, x-ray transmissive debris shield which is particularly suited for use in high energy fluences. In one embodiment, the composite window comprises alternating layers of beryllium and a thermoset polymer.

  16. High speed x-ray beam chopper

    DOE Patents [OSTI]

    McPherson, Armon (Oswego, IL); Mills, Dennis M. (Naperville, IL)

    2002-01-01T23:59:59.000Z

    A fast, economical, and compact x-ray beam chopper with a small mass and a small moment of inertia whose rotation can be synchronized and phase locked to an electronic signal from an x-ray source and be monitored by a light beam is disclosed. X-ray bursts shorter than 2.5 microseconds have been produced with a jitter time of less than 3 ns.

  17. An unresolved X-ray source inside the supernova remnant RCW 86

    E-Print Network [OSTI]

    Jacco Vink; Fabrizio Bocchino; Francesco Damiani; Jelle S. Kaastra

    2000-08-29T23:59:59.000Z

    We report on the discovery of an unresolved X-ray source inside the supernova remnant G315.4-2.3 (RCW 86). The source is located 7' to the Southwest of the geometrical centre and may be close to the actual explosion centre of the supernova, which makes this a candidate for the stellar remnant associated with RCW 86. However, the presence of a possible optical counterpart with $V \\sim 14$ at 3" from the X-ray position and evidence for long term variability means that the source is probably an active star. A better X-ray position and better X-ray spectroscopy along with an identification of the optical source are needed to exclude the X-ray source as a neutron star candidate.

  18. X-ray populations in galaxies

    E-Print Network [OSTI]

    G. Fabbiano

    2005-11-09T23:59:59.000Z

    Today's sensistive, high resolution Chandra X-ray observations allow the study of many populations of X-ray sources. The traditional astronomical tools of photometric diagrams and luminosity functions are now applied to these populations, and provide the means for classifying the X-ray sources and probing their evolution. While overall stellar mass drives the amount of X-ray binaries in old stellar population, the amount of sources in star-forming galaxies is related to the star formation rate. Shart-lived, luminous, high mass binaries (HNXBs) dominate these young populations.

  19. X-ray laser microscope apparatus

    DOE Patents [OSTI]

    Suckewer, Szymon (Princeton, NJ); DiCicco, Darrell S. (Plainsboro, NJ); Hirschberg, Joseph G. (Coral Gables, FL); Meixler, Lewis D. (East Windsor, NJ); Sathre, Robert (Princeton, NJ); Skinner, Charles H. (Lawrenceville, NJ)

    1990-01-01T23:59:59.000Z

    A microscope consisting of an x-ray contact microscope and an optical microscope. The optical, phase contrast, microscope is used to align a target with respect to a source of soft x-rays. The source of soft x-rays preferably comprises an x-ray laser but could comprise a synchrotron or other pulse source of x-rays. Transparent resist material is used to support the target. The optical microscope is located on the opposite side of the transparent resist material from the target and is employed to align the target with respect to the anticipated soft x-ray laser beam. After alignment with the use of the optical microscope, the target is exposed to the soft x-ray laser beam. The x-ray sensitive transparent resist material whose chemical bonds are altered by the x-ray beam passing through the target mater GOVERNMENT LICENSE RIGHTS This invention was made with government support under Contract No. De-FG02-86ER13609 awarded by the Department of Energy. The Government has certain rights in this invention.

  20. Investigation of JahnTeller splitting with O 1s x-ray absorption spectroscopy in strained Nd1-xCaxMnO3 thin films

    E-Print Network [OSTI]

    Lin, Minn-Tsong

    of information about the splitting energy of JT distor- tion. Therefore, it is our speculation that the actual JT split- ting energy in CMR system may be smaller than the theoret- ical value, which makes it hard,2 and J. G. Lin1,a 1 Center for Condensed Matter Sciences, National Taiwan University, Taipei 106

  1. Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lukatskaya, Maria R.; Bak, Seong -Min; Yu, Xiqian; Yang, Xiao -Qing; Barsoum, Michel W.; Gogotsi, Yury

    2015-05-01T23:59:59.000Z

    The field of supercapacitors (electrochemical capacitors) is constantly evolving. The global motivation is to create devices that possess a significant energy density without compromising the power density. To achieve this goal, new materials must be discovered and complex electrode architectures developed.

  2. Measuring the Kernel of Time-Dependent Density Functional Theory with X-Ray Absorption Spectroscopy of 3d Transition Metals

    E-Print Network [OSTI]

    Gross, E.K.U.

    of 3d Transition Metals A. Scherz,* E. K. U. Gross, H. Appel, C. Sorg, K. Baberschke, and H. Wende, and a new approximation suggested. But the true value of DFT is in constructing one XC approxi- mation

  3. The use of (micro)-X-ray absorption spectroscopy in cement research A.M. Scheidegger *, M. Vespa, D. Grolimund, E. Wieland, M. Harfouche,

    E-Print Network [OSTI]

    of trace elements in cementitious materials will be outlined presenting two examples relevant for nuclear to determine the local coor- dination environment of Sn(IV) bound to calcium silicate hydrates (C­S­H). Sn K to ensure the safe disposal of these waste forms to minimize their environmental impacts (Levi et al., 1990

  4. X-ray absorption spectroscopy elucidates the impact of structural disorder on electron mobility in amorphous zinc-tin-oxide thin films

    E-Print Network [OSTI]

    to decrease with increasing structural disorder around Zn atoms, suggesting that the degradation in electron for photovoltaic applications by reducing interface recombination and improving device performance.12

  5. Supporting information for Kinetics of Chromium(III) Oxidation by Manganese(IV) Oxides Using Quick Scanning X-Ray Absorption Fine Structure Spectroscopy (Q-XAFS)

    E-Print Network [OSTI]

    Sparks, Donald L.

    H 2.5, 3, and 3.5 Page S-5 to S-7: Figure S5 ­ S5-S1) Effect of Cr concentration S5-S2) Effect of Mn SH 2.5, 3, and 3.5 #12;S-5 Figure S5-S1 #12;S-6 Figure S5-S2 #12;S-7 Figure S5-S3 Figure S5 ­ S5-S1) Effect of Cr concentration ­ pH 2.5; 20 g/L HMO; [Cr(III)]= 100 mM, 80 mM, and 60 mM S5-S2) Effect of Mn

  6. Presented at the NuMat 2012 Conference, 2225 October 2012, Osaka, Japan Microbeam X-ray Absorption Near-Edge Spectroscopy study

    E-Print Network [OSTI]

    Motta, Arthur T.

    Engineering, Penn State University, University Park, PA 16802, USA b Advanced Photon Source, XFD 401 B3194 is investigated by focusing on the chemical state evolution of two alloying elements, Fe and Nb, when incorporated oxide samples. A thin ($12 lm) cross- sectional sample of Zircaloy-4 oxide was also designed

  7. 4f charge-density deformation and magnetostrictive bond strain observed in amorphous TbFe2 by x-ray absorption spectroscopy

    E-Print Network [OSTI]

    Boyer, Edmond

    This can be found, for example, in the elementary rare-earth RE metals which exhibit strains up to l/l 7500 Received 4 December 2009; published 12 January 2010 The giant magnetostriction observed in rare-earth Ref. 5. In the RE-Fe2 structure, the local symmetry at the rare- earth site

  8. Direct and quantitative photothermal absorption spectroscopy of individual particulates

    SciTech Connect (OSTI)

    Tong, Jonathan K.; Hsu, Wei-Chun; Eon Han, Sang; Burg, Brian R.; Chen, Gang, E-mail: gchen2@mit.edu [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Zheng, Ruiting [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China)] [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Shen, Sheng [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)] [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)

    2013-12-23T23:59:59.000Z

    Photonic structures can exhibit significant absorption enhancement when an object's length scale is comparable to or smaller than the wavelength of light. This property has enabled photonic structures to be an integral component in many applications such as solar cells, light emitting diodes, and photothermal therapy. To characterize this enhancement at the single particulate level, conventional methods have consisted of indirect or qualitative approaches which are often limited to certain sample types. To overcome these limitations, we used a bilayer cantilever to directly and quantitatively measure the spectral absorption efficiency of a single silicon microwire in the visible wavelength range. We demonstrate an absorption enhancement on a per unit volume basis compared to a thin film, which shows good agreement with Mie theory calculations. This approach offers a quantitative approach for broadband absorption measurements on a wide range of photonic structures of different geometric and material compositions.

  9. Method and apparatus for aerosol particle absorption spectroscopy

    DOE Patents [OSTI]

    Campillo, Anthony J. (Nesconset, NY); Lin, Horn-Bond (Manorville, NY)

    1983-11-15T23:59:59.000Z

    A method and apparatus for determining the absorption spectra, and other properties, of aerosol particles. A heating beam source provides a beam of electromagnetic energy which is scanned through the region of the spectrum which is of interest. Particles exposed to the heating beam which have absorption bands within the band width of the heating beam absorb energy from the beam. The particles are also illuminated by light of a wave length such that the light is scattered by the particles. The absorption spectra of the particles can thus be determined from an analysis of the scattered light since the absorption of energy by the particles will affect the way the light is scattered. Preferably the heating beam is modulated to simplify the analysis of the scattered light. In one embodiment the heating beam is intensity modulated so that the scattered light will also be intensity modulated when the particles absorb energy. In another embodiment the heating beam passes through an interferometer and the scattered light reflects the Fourier Transform of the absorption spectra.

  10. Phased Contrast X-Ray Imaging

    ScienceCinema (OSTI)

    Erin Miller

    2012-12-31T23:59:59.000Z

    The Pacific Northwest National Laboratory is developing a range of technologies to broaden the field of explosives detection. Phased contrast X-ray imaging, which uses silicon gratings to detect distortions in the X-ray wave front, may be applicable to mail or luggage scanning for explosives; it can also be used in detecting other contraband, small-parts inspection, or materials characterization.

  11. X-ray source populations in galaxies

    E-Print Network [OSTI]

    G. Fabbiano

    2005-11-16T23:59:59.000Z

    Today's sensitive, high-resolution X-ray observations allow the study of populations of X-ray sources, in the luminosity range of Galactic X-ray binaries, in galaxies as distant as 20-30 Mpc. The traditional astronomical tools of photometric diagrams and luminosity functions are now applied to these populations, providing a direct probe of the evolved binary component of different stellar populations. The study of the X-ray populations of E and S0 galaxies has revamped the debate on the formation and evolution of low-mass X-ray binaries (LMXBs) and on the role of globular clusters in these processes. While overall stellar mass drives the amount of X-ray binaries in old stellar populations, the amount of sources in star forming galaxies is related to the star formation rate. Short-lived, luminous, high-mass binaries (HMXBs) dominate these young populations. The most luminous sources in these systems are the debated ULXs, which have been suggested to be ~100-1000 Msol black holes, but could alternatively include a number of binaries with stellar mass black holes. Very soft sources have also been discovered in many galaxies and their nature is currently being debated. Observations of the deep X-ray sky, and comparison with deep optical surveys, are providing the first evidence of the X-ray evolution of galaxies.

  12. Amplification of Gamma Radiation from X-Ray Excited Nuclear States

    E-Print Network [OSTI]

    Silviu Olariu

    1999-07-18T23:59:59.000Z

    In this paper we discuss the possibility of the excitation of nuclear electromagnetic transitions by the absorption of X-ray quanta produced in appropriate inner-shell atomic transitions, and the relevance of this process for the amplification of the gamma radiation from the excited nuclear states. It is concluded that the X-ray pumping technique might provide a useful approach for the development of a gamma ray laser.

  13. Relativistic Effects on Reflection X-ray Spectra of AGN

    SciTech Connect (OSTI)

    Lee, Khee-Gan; /University Coll. London; Fuerst, Steven V.; /KIPAC, Menlo Park; Brandwardi-Raymond, Graziella; Wu, Kinwah; Crowley, Oliver; /University Coll. London

    2007-01-05T23:59:59.000Z

    We have calculated the reflection component of the X-ray spectra of active galactic nuclei (AGN) and shown that they can be significantly modified by the relativistic motion of the accretion flow and various gravitational effects of the central black hole. The absorption edges in the reflection spectra suffer severe energy shifts and smearing. The degree of distortion depends on the system parameters, and the dependence is stronger for some parameters such as the inner radius of the accretion disk and the disk viewing inclination angles. The relativistic effects are significant and are observable. Improper treatment of the reflection component of the X-ray continuum in spectral fittings will give rise to spurious line-like features, which will mimic the fluorescent emission lines and mask the relativistic signatures of the lines.

  14. Rotational Doppler effect in x-ray photoionization

    SciTech Connect (OSTI)

    Sun Yuping; Wang Chuankui [College of Physics and Electronics, Shandong Normal University, 250014 Jinan (China); Theoretical Chemistry, Roslagstullsbacken 15, Royal Institute of Technology, S-106 91 Stockholm (Sweden); Gel'mukhanov, Faris [Theoretical Chemistry, Roslagstullsbacken 15, Royal Institute of Technology, S-106 91 Stockholm (Sweden)

    2010-11-15T23:59:59.000Z

    The energy of the photoelectron experiences a red or blue Doppler shift when the molecule recedes from the detector or approaches him. This results in a broadening of the photoelectron line due to the translational thermal motion. However, the molecules also have rotational degrees of freedom and we show that the translational Doppler effect has its rotational counterpart. This rotational Doppler effect leads to an additional broadening of the spectral line of the same magnitude as the Doppler broadening caused by translational thermal motion. The rotational Doppler broadening as well as the rotational recoil broadening is sensitive to the molecular orbital from which the photoelectron is ejected. This broadening should be taken into account in analysis of x-ray photoemission spectra of super-high resolution and it can be directly observed using x-ray pump-probe spectroscopy.

  15. Maskelynite formation via solid-state transformation: Evidence of infrared and x-ray anisotropy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jaret, Steven J.; Ehm, Lars; Woerner, William R.; Phillips, Brian L.; Nekvasil, Hanna; Wright, Shawn P.; Glotch, Timothy D.

    2015-03-01T23:59:59.000Z

    We present optical microscopy, micro-Raman spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, high-energy X-ray total scattering experiments, and micro-Fourier transform infrared (micro-FTIR) spectroscopy on shocked labradorite from the Lonar Crater, India. We show that maskelynite of shock class 2 is structurally more similar to fused glass than to crystalline plagioclase. However, there are slight but significant differences – preservation of original pre-impact igneous zoning, anisotropy at Infrared wavelengths, X-ray anisotropy, and preservation of some intermediate range order – which are all consistent with a solid-state transformation formation of maskelynite.

  16. X-Ray Nanoimaging: Instruments and Methods

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-Ray ImagingX-Ray

  17. X-ray Modeling of \\eta\\ Carinae and WR140 from SPH Simulations

    E-Print Network [OSTI]

    Russell, Christopher M P; Okazaki, Atsuo T; Madura, Thomas I; Owocki, Stanley P

    2011-01-01T23:59:59.000Z

    The colliding wind binary (CWB) systems \\eta\\ Carinae and WR140 provide unique laboratories for X-ray astrophysics. Their wind-wind collisions produce hard X-rays that have been monitored extensively by several X-ray telescopes, including RXTE. To interpret these RXTE X-ray light curves, we model the wind-wind collision using 3D smoothed particle hydrodynamics (SPH) simulations. Adiabatic simulations that account for the absorption of X-rays from an assumed point source at the apex of the wind-collision shock cone by the distorted winds can closely match the observed 2-10keV RXTE light curves of both \\eta\\ Car and WR140. This point-source model can also explain the early recovery of \\eta\\ Car's X-ray light curve from the 2009.0 minimum by a factor of 2-4 reduction in the mass loss rate of \\eta\\ Car. Our more recent models relax the point-source approximation and account for the spatially extended emission along the wind-wind interaction shock front. For WR140, the computed X-ray light curve again matches the ...

  18. Measurements of benzene concentration by difference-frequency laser absorption spectroscopy

    E-Print Network [OSTI]

    Measurements of benzene concentration by difference-frequency laser absorption spectroscopy Weidong Chen, Fabrice Cazier, Frank Tittel, and Daniel Boucher Measurements of benzene concentration based:sapphire lasers in a GaSe nonlinear optical crystal. A minimum benzene concentration detection of 11.5 parts

  19. absorption near-edge spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption near-edge spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of...

  20. absorption gamma-ray spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption gamma-ray spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 gamma-Ray...

  1. absorption fine-structure spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption fine-structure spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of...

  2. Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell Cathode Materials. Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell...

  3. Using X-Ray Computed Tomography in Pore Structure Characterization...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using X-Ray Computed Tomography in Pore Structure Characterization for a Berea Sandstone: Resolution Effect. Using X-Ray Computed Tomography in Pore Structure Characterization for...

  4. Manipulating X-rays with Tiny Mirrors | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for controlling X-rays. MEMS, or microelectromechanical systems, allow shrinking the optics to the microscale creating ultrafast devices for reflecting X-rays at precise times...

  5. X-ray Lenses Fabricated by LIGA Technology

    SciTech Connect (OSTI)

    Nazmov, Vladimir; Last, Arndt; Saile, Volker [Institut fuer Microstrukturtechnik, Forschungszentrum Karlsruhe GmbH, 76021 Karlsruhe (Germany); Karlsruhe University, 76131 Karlsruhe (Germany); Reznikova, Elena; Mohr, Jurgen [Institut fuer Microstrukturtechnik, Forschungszentrum Karlsruhe GmbH, 76021 Karlsruhe (Germany); Simon, Rolf [Institut fuer Synchrotronstrahlung, Forschungszentrum Karlsruhe GmbH, 76021 Karlsruhe (Germany); DiMichiel, Marco [European Synchrotron Radiation Facility, BP220, 38043, Grenoble (France)

    2007-01-19T23:59:59.000Z

    X-ray refractive optical lens systems have been successfully elaborated, designed, fabricated at the Institute for Microstructure Technology at the Forschungszentrum Karlsruhe (Germany) using LIGA technology in recent years. The lenses are structured in a SU-8 polymer. The capability of the LIGA technique to create an arbitrary profile of the focusing microstructures allow the fabrication of lenses with different curvature radius of parabolic geometry, minimized absorption and a large depth of focus. Also a set of planar lens systems on one substrate can be realized with 17 lenses providing identical focal distances for different X-ray energies from 2 to over 100 keV. Nickel lenses fabricated by electroforming using polymer templates can be applied for energies larger than 80 keV. The parabolic crossed lenses are used for 2D nano focusing of monochromatic beams. The quasi-parabolic crossed lenses with a submicron focus and a focus depth of the centimetre range can be used as an achromatic system. Mosaic truncated parabolic lenses with a focusing aperture up to 1 mm are made to increase the X-ray intensity in the focused spot.

  6. Columbia University X-Ray Measurements

    E-Print Network [OSTI]

    Columbia University X-Ray Measurements of the Levitated Dipole Experiment J. L. Ellsworth, J. Kesner MIT Plasma Science and Fusion Center D.T. Garnier, A.K. Hansen, M.E. Mauel Columbia University

  7. Small Angle X-Ray Scattering Detector

    DOE Patents [OSTI]

    Hessler, Jan P.

    2004-06-15T23:59:59.000Z

    A detector for time-resolved small-angle x-ray scattering includes a nearly constant diameter, evacuated linear tube having an end plate detector with a first fluorescent screen and concentric rings of first fiber optic bundles for low angle scattering detection and an annular detector having a second fluorescent screen and second fiber optic bundles concentrically disposed about the tube for higher angle scattering detection. With the scattering source, i.e., the specimen under investigation, located outside of the evacuated tube on the tube's longitudinal axis, scattered x-rays are detected by the fiber optic bundles, to each of which is coupled a respective photodetector, to provide a measurement resolution, i.e., dq/q, where q is the momentum transferred from an incident x-ray to an x-ray scattering specimen, of 2% over two (2) orders of magnitude in reciprocal space, i.e., qmax/qmin approx=lO0.

  8. Lensless X-Ray Imaging in Reflection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging in Reflection Print Wednesday, 26 October 2011 00:00 The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field...

  9. X-ray source for mammography

    DOE Patents [OSTI]

    Logan, Clinton M. (Pleasanton, CA)

    1994-01-01T23:59:59.000Z

    An x-ray source utilizing anode material which shifts the output spectrum to higher energy and thereby obtains higher penetrating ability for screening mammography application, than the currently utilized anode material. The currently used anode material (molybdenum) produces an energy x-ray spectrum of 17.5/19.6 keV, which using the anode material of this invention (e.g. silver, rhodium, and tungsten) the x-ray spectrum would be in the 20-35 keV region. Thus, the anode material of this invention provides for imaging of breasts with higher than average x-ray opacity without increase of the radiation dose, and thus reduces the risk of induced breast cancer due to the radiation dose administered for mammograms.

  10. X-ray grid-detector apparatus

    DOE Patents [OSTI]

    Boone, John M. (Folsom, CA); Lane, Stephen M. (Oakland, CA)

    1998-01-27T23:59:59.000Z

    A hybrid grid-detector apparatus for x-ray systems wherein a microchannel plate structure has an air-interspaced grid portion and a phosphor/optical fluid-filled grid portion. The grids are defined by multiple adjacent channels separated by lead-glass septa. X-rays entering the air-interspaced grid portion at an angle of impingement upon the septa are attenuated, while non-impinging x-rays pass through to the phosphor/fluid filled portion. X-ray energy is converted to luminescent energy in the phosphor/fluid filled portion and the resultant beams of light are directed out of the phosphor/optical fluid filled portion to an imaging device.

  11. X-ray source for mammography

    DOE Patents [OSTI]

    Logan, C.M.

    1994-12-20T23:59:59.000Z

    An x-ray source is described utilizing anode material which shifts the output spectrum to higher energy and thereby obtains higher penetrating ability for screening mammography application, than the currently utilized anode material. The currently used anode material (molybdenum) produces an energy x-ray spectrum of 17.5/19.6 keV, which using the anode material of this invention (e.g. silver, rhodium, and tungsten) the x-ray spectrum would be in the 20-35 keV region. Thus, the anode material of this invention provides for imaging of breasts with higher than average x-ray opacity without increase of the radiation dose, and thus reduces the risk of induced breast cancer due to the radiation dose administered for mammograms. 6 figures.

  12. Principles of X-ray Navigation

    SciTech Connect (OSTI)

    Hanson, John Eric; /SLAC

    2006-03-17T23:59:59.000Z

    X-ray navigation is a new concept in satellite navigation in which orientation, position and time are measured by observing stellar emissions in x-ray wavelengths. X-ray navigation offers the opportunity for a single instrument to be used to measure these parameters autonomously. Furthermore, this concept is not limited to missions in close proximity to the earth. X-ray navigation can be used on a variety of missions from satellites in low earth orbit to spacecraft on interplanetary missions. In 1997 the Unconventional Stellar Aspect Experiment (USA) will be launched as part of the Advanced Research and Global Observation Satellite (ARGOS). USA will provide the first platform for real-time experimentation in the field of x-ray navigation and also serves as an excellent case study for the design and manufacturing of space qualified systems in small, autonomous groups. Current techniques for determining the orientation of a satellite rely on observations of the earth, sun and stars in infrared, visible or ultraviolet wavelengths. It is possible to use x-ray imaging devices to provide arcsecond level measurement of attitude based on star patterns in the x-ray sky. This technique is explored with a simple simulation. Collimated x-ray detectors can be used on spinning satellites to provide a cheap and reliable measure of orientation. This is demonstrated using observations of the Crab Pulsar taken by the high Energy Astronomy Observatory (HEAO-1) in 1977. A single instrument concept is shown to be effective, but dependent on an a priori estimate of the guide star intensity and thus susceptible to errors in that estimate. A star scanner based on a differential measurement from two x-ray detectors eliminates the need for an a priori estimate of the guide star intensity. A first order model and a second order model of the two star scanner concepts are considered. Many of the stars that emit in the x-ray regime are also x-ray pulsars with frequency stability approaching a part in 10{sup 9}. By observing these pulsations, a satellite can keep accurate time autonomously. They have demonstrated the acquisition and tracking of the Crab nebula pulsar by simulating the operation of a phase-locked loop.

  13. Compton backscattered collimated x-ray source

    DOE Patents [OSTI]

    Ruth, R.D.; Huang, Z.

    1998-10-20T23:59:59.000Z

    A high-intensity, inexpensive and collimated x-ray source is disclosed for applications such as x-ray lithography is disclosed. An intense pulse from a high power laser, stored in a high-finesse resonator, repetitively collides nearly head-on with and Compton backscatters off a bunched electron beam, having relatively low energy and circulating in a compact storage ring. Both the laser and the electron beams are tightly focused and matched at the interaction region inside the optical resonator. The laser-electron interaction not only gives rise to x-rays at the desired wavelength, but also cools and stabilizes the electrons against intrabeam scattering and Coulomb repulsion with each other in the storage ring. This cooling provides a compact, intense bunch of electrons suitable for many applications. In particular, a sufficient amount of x-rays can be generated by this device to make it an excellent and flexible Compton backscattered x-ray (CBX) source for high throughput x-ray lithography and many other applications. 4 figs.

  14. Compton backscattered collmated X-ray source

    DOE Patents [OSTI]

    Ruth, Ronald D. (Woodside, CA); Huang, Zhirong (Stanford, CA)

    2000-01-01T23:59:59.000Z

    A high-intensity, inexpensive and collimated x-ray source for applications such as x-ray lithography is disclosed. An intense pulse from a high power laser, stored in a high-finesse resonator, repetitively collides nearly head-on with and Compton backscatters off a bunched electron beam, having relatively low energy and circulating in a compact storage ring. Both the laser and the electron beams are tightly focused and matched at the interaction region inside the optical resonator. The laser-electron interaction not only gives rise to x-rays at the desired wavelength, but also cools and stabilizes the electrons against intrabeam scattering and Coulomb repulsion with each other in the storage ring. This cooling provides a compact, intense bunch of electrons suitable for many applications. In particular, a sufficient amount of x-rays can be generated by this device to make it an excellent and flexible Compton backscattered x-ray (CBX) source for high throughput x-ray lithography and many other applications.

  15. Compton backscattered collimated x-ray source

    DOE Patents [OSTI]

    Ruth, Ronald D. (Woodside, CA); Huang, Zhirong (Stanford, CA)

    1998-01-01T23:59:59.000Z

    A high-intensity, inexpensive and collimated x-ray source for applications such as x-ray lithography is disclosed. An intense pulse from a high power laser, stored in a high-finesse resonator, repetitively collides nearly head-on with and Compton backscatters off a bunched electron beam, having relatively low energy and circulating in a compact storage ring. Both the laser and the electron beams are tightly focused and matched at the interaction region inside the optical resonator. The laser-electron interaction not only gives rise to x-rays at the desired wavelength, but also cools and stabilizes the electrons against intrabeam scattering and Coulomb repulsion with each other in the storage ring. This cooling provides a compact, intense bunch of electrons suitable for many applications. In particular, a sufficient amount of x-rays can be generated by this device to make it an excellent and flexible Compton backscattered x-ray (CBX) source for high throughput x-ray lithography and many other applications.

  16. GaN for x-ray detection

    SciTech Connect (OSTI)

    Duboz, Jean-Yves; Lauegt, Marguerite; Schenk, David [CRHEA, CNRS, rue Bernard Gregory, Sophia Antipolis, F-06560 Valbonne (France); Beaumont, Bernard [Lumilog, 2720 chemin de saint Bernard, F-06220 Vallauris (France); Reverchon, Jean-Luc [THALES R and T, route departementale 128, F-91767 Palaiseau Cedex (France); Wieck, Andreas D.; Zimmerling, Tino [Fakultaet fuer Physik und Astronomie, D-44780 Bochum (Germany)

    2008-06-30T23:59:59.000Z

    The potential of GaN based materials for x-ray detection is investigated. The absorption coefficient in GaN is measured as a function of photon energy between 6 and 40 keV. Metal-semiconductor-metal photodetectors are fabricated and characterized. The response dependence on bias, the temporal dynamics, and the response dependence on detector geometry all together point toward a mixing of photovoltaic and photoconductive effects. Thanks to a large photoconductive gain, the detector has a decent responsivity at the expense of a large response time.

  17. The XMM large scale structure survey: optical vs. X-ray classifications of active galactic nuclei and the unified scheme

    E-Print Network [OSTI]

    Garcet, O; Gosset, E; Sprimont, P G; Surdej, J; Borkowski, V; Tajer, M; Pacaud, F; Pierre, M; Chiappetti, L; MacCagni, D; Page, M J; Carrera, F J; Tedds, J A; Mateos, S; Krumpe, M; Contini, T; Corral, A; Ebrero, J; Gavignaud, I; Schwope, A; Le Fèvre, O; Polletta, M; Rosen, S; Lonsdale, C; Watson, M; Borczyk, W; Väisänen, P

    2007-01-01T23:59:59.000Z

    Our goal is to characterize AGN populations by comparing their X-ray and optical classifications. We present a sample of 99 spectroscopically identified X-ray point sources in the XMM-LSS survey which are significantly detected in the [2-10] keV band, and with more than 80 counts. We performed an X-ray spectral analysis for all of these 99 X-ray sources. Introducing the fourfold point correlation coefficient, we find only a mild correlation between the X-ray and the optical classifications, as up to 30% of the sources have differing X-ray and optical classifications: on one hand, 10% of the type 1 sources present broad emission lines in their optical spectra and strong absorption in the X-rays. These objects are highly luminous AGN lying at high redshift and thus dilution effects are totally ruled out, their discrepant nature being an intrinsic property. Their X-ray luminosities and redshifts distributions are consistent with those of the unabsorbed X-ray sources with broad emission lines. On the other hand, ...

  18. Combined Application of QEM-SEM and Hard X-ray Microscopy to Determine Mineralogical Associations and Chemcial Speciation of Trace Metals

    SciTech Connect (OSTI)

    M Grafe; M Landers; R Tappero; P Austin; B Gan; A Grabsch; C Klauber

    2011-12-31T23:59:59.000Z

    We describe the application of quantitative evaluation of mineralogy by scanning electron microscopy in combination with techniques commonly available at hard X-ray microprobes to define the mineralogical environment of a bauxite residue core segment with the more specific aim of determining the speciation of trace metals (e.g., Ti, V, Cr, and Mn) within the mineral matrix. Successful trace metal speciation in heterogeneous matrices, such as those encountered in soils or mineral residues, relies on a combination of techniques including spectroscopy, microscopy, diffraction, and wet chemical and physical experiments. Of substantial interest is the ability to define the mineralogy of a sample to infer redox behavior, pH buffering, and mineral-water interfaces that are likely to interact with trace metals through adsorption, coprecipitation, dissolution, or electron transfer reactions. Quantitative evaluation of mineralogy by scanning electron microscopy coupled with micro-focused X-ray diffraction, micro-X-ray fluorescence, and micro-X-ray absorption near edge structure (mXANES) spectroscopy provided detailed insights into the composition of mineral assemblages and their effect on trace metal speciation during this investigation. In the sample investigated, titanium occurs as poorly ordered ilmenite, as rutile, and is substituted in iron oxides. Manganese's spatial correlation to Ti is closely linked to ilmenite, where it appears to substitute for Fe and Ti in the ilmenite structure based on its mXANES signature. Vanadium is associated with ilmenite and goethite but always assumes the +4 oxidation state, whereas chromium is predominantly in the +3 oxidation state and solely associated with iron oxides (goethite and hematite) and appears to substitute for Fe in the goethite structure.

  19. Transient x-ray diffraction and its application to materials science and x-ray optics

    SciTech Connect (OSTI)

    Hauer, A.A.; Kopp, R.; Cobble, J.; Kyrala, G.; Springer, R. [and others

    1997-12-01T23:59:59.000Z

    Time resolved x-ray diffraction and scattering have been applied to the measurement of a wide variety of physical phenomena from chemical reactions to shock wave physics. Interest in this method has heightened in recent years with the advent of versatile, high power, pulsed x-ray sources utilizing laser plasmas, electron beams and other methods. In this article, we will describe some of the fundamentals involved in time resolved x-ray diffraction, review some of the history of its development, and describe some recent progress in the field. In this article we will emphasize the use of laser-plasmas as the x-ray source for transient diffraction.

  20. Photocarrier dynamics in anatase TiO{sub 2} investigated by pump-probe absorption spectroscopy

    SciTech Connect (OSTI)

    Matsuzaki, H., E-mail: hiroyuki-matsuzaki@aist.go.jp, E-mail: okamotoh@k.u-tokyo.ac.jp; Matsui, Y.; Uchida, R.; Yada, H.; Terashige, T. [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Li, B.-S. [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology (HIT), Harbin City 150080 (China); Sawa, A. [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8562 (Japan); Kawasaki, M. [Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Tokura, Y. [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8562 (Japan); Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Okamoto, H., E-mail: hiroyuki-matsuzaki@aist.go.jp, E-mail: okamotoh@k.u-tokyo.ac.jp [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); CREST, Japan Science and Technology Agency, Chiyoda-ku, Tokyo 102-0075 (Japan)

    2014-02-07T23:59:59.000Z

    The dynamics of photogenerated electrons and holes in undoped anatase TiO{sub 2} were studied by femtosecond absorption spectroscopy from the visible to mid-infrared region (0.1–2.0?eV). The transient absorption spectra exhibited clear metallic responses, which were well reproduced by a simple Drude model. No mid-gap absorptions originating from photocarrier localization were observed. The reduced optical mass of the photocarriers obtained from the Drude-model analysis is comparable to theoretically expected one. These results demonstrate that both photogenerated holes and electrons act as mobile carriers in anatase TiO{sub 2}. We also discuss scattering and recombination dynamics of photogenerated electrons and holes on the basis of the time dependence of absorption changes.

  1. X-ray Detection from Bona-fide and Candidate Brown Dwarfs in the Rho Ophiuchi Cloud with Chandra

    E-Print Network [OSTI]

    Kensuke Imanishi; Masahiro Tsujimoto; Katsuji Koyama

    2001-08-06T23:59:59.000Z

    We present results of an X-ray search from bona-fide and candidate brown dwarfs in the Rho Ophiuchi cloud cores with the Chandra X-ray Observatory. The selected areas are two fields near the cloud center and are observed with the ACIS-I array of a 17'x17' size and a ~100 ks exposure. Among 18 bona-fide and candidate brown dwarfs listed by the infrared spectroscopy, we find X-ray emission from 7 sources above 99.9% confidence level. Therefore ~40% of the infrared-selected brown dwarfs in this cloud emit X-rays. For the brightest 4 sources, the X-ray spectra are made and are fitted with a thin-thermal plasma model of a temperature 1-2.5 keV. The X-rays are also time variable with rapid flares from 2 of the brown dwarfs. Assuming 2 keV temperature and using the empirical relation of Av vs. NH, we estimate the X-ray luminosity or its upper limit of the other faint or non-X-ray sources. The X-ray luminosity (Lx) of the X-ray-detected sources is in the range of 0.3-90x10^28 ergs s^-1, while the luminosity ratio of X-ray to bolometric (Lx/Lbol) is 10^-3 - 10^-5, similar to those of low-mass pre-main-sequence and dMe stars. All these results suggest that the X-ray origin of brown dwarfs is the same as low-mass stars; strong magnetic activity at the stellar surface.

  2. Infrared-laser spectroscopy using a long-pathlength absorption cell

    SciTech Connect (OSTI)

    Kim, K.C.; Briesmeister, R.A.

    1983-01-01T23:59:59.000Z

    The absorption measurements in an ordinary cell may require typically a few torr pressure of sample gas. At these pressures the absorption lines are usually pressure-broadened and, therefore, closely spaced transitions are poorly resolved even at diode-laser resolution. This situation is greatly improved in Doppler-limited spectroscopy at extremely low sample pressures. Two very long-pathlength absorption cells were developed to be used in conjunction with diode lasers. They were designed to operate at controlled temperatures with the optical pathlength variable up to approx. 1.5 km. Not only very low sample pressures are used for studies with such cells but also the spectroscopic sensitivity is enhanced over conventional methods by a factor of 10/sup 3/ to 10/sup 4/, improving the analytical capability of measuring particle densities to the order of 1 x 10'' molecules/cm/sup 3/. This paper presents some analytical aspects of the diode laser spectroscopy using the long-pathlength absorption cells in the areas of absorption line widths, pressure broadening coefficients, isotope composition measurements and trace impurity analysis.

  3. Ultra-sensitive surface absorption spectroscopy using sub-wavelength diameter optical fibers

    E-Print Network [OSTI]

    F. Warken; E. Vetsch; D. Meschede; M. Sokolowski; A. Rauschenbeutel

    2007-06-22T23:59:59.000Z

    The guided modes of sub-wavelength diameter air-clad optical fibers exhibit a pronounced evanescent field. The absorption of particles on the fiber surface is therefore readily detected via the fiber transmission. We show that the resulting absorption for a given surface coverage can be orders of magnitude higher than for conventional surface spectroscopy. As a demonstration, we present measurements on sub-monolayers of 3,4,9,10-perylene-tetracarboxylic dianhydride (PTCDA) molecules at ambient conditions, revealing the agglomeration dynamics on a second to minutes timescale.

  4. Differential phase contrast X-ray imaging system and components

    DOE Patents [OSTI]

    Stutman, Daniel; Finkenthal, Michael

    2014-07-01T23:59:59.000Z

    A differential phase contrast X-ray imaging system includes an X-ray illumination system, a beam splitter arranged in an optical path of the X-ray illumination system, and a detection system arranged in an optical path to detect X-rays after passing through the beam splitter.

  5. Reflection soft X-ray microscope and method

    DOE Patents [OSTI]

    Suckewer, S.; Skinner, C.H.; Rosser, R.

    1993-01-05T23:59:59.000Z

    A reflection soft X-ray microscope is provided by generating soft X-ray beams, condensing the X-ray beams to strike a surface of an object at a predetermined angle, and focusing the X-ray beams reflected from the surface onto a detector, for recording an image of the surface or near surface features of the object under observation.

  6. An alternative scheme of angular-dispersion analyzers for high-resolution medium-energy inelastic X-ray scattering

    E-Print Network [OSTI]

    Huang, Xian-Rong

    2011-01-01T23:59:59.000Z

    The development of medium-energy inelastic X-ray scattering (IXS) optics with meV and sub-meV resolution has attracted considerable efforts in recent years. Meanwhile, there are also concerns or debates about the fundamental and feasibility of the involved schemes. Here the central optical component, the back-reflection angular-dispersion monochromator or analyzer, is analyzed. The results show that the multiple-beam diffraction effect together with transmission-induced absorption can noticeably reduce the diffraction efficiency, although it may not be a fatal threat. In order to improve the efficiency, a simple four-bounce analyzer is proposed that completely avoids these two adverse effects. The new scheme is illustrated to be a feasible alternative approach for developing meV- to sub-meV-resolution IXS spectroscopy.

  7. Nonlinear X-ray Compton Scattering

    E-Print Network [OSTI]

    Fuchs, Matthias; Chen, Jian; Ghimire, Shambhu; Shwartz, Sharon; Kozina, Michael; Jiang, Mason; Henighan, Thomas; Bray, Crystal; Ndabashimiye, Georges; Bucksbaum, P H; Feng, Yiping; Herrmann, Sven; Carini, Gabriella; Pines, Jack; Hart, Philip; Kenney, Christopher; Guillet, Serge; Boutet, Sebastien; Williams, Garth; Messerschmidt, Marc; Seibert, Marvin; Moeller, Stefan; Hastings, Jerome B; Reis, David A

    2015-01-01T23:59:59.000Z

    X-ray scattering is a weak linear probe of matter. It is primarily sensitive to the position of electrons and their momentum distribution. Elastic X-ray scattering forms the basis of atomic structural determination while inelastic Compton scattering is often used as a spectroscopic probe of both single-particle excitations and collective modes. X-ray free-electron lasers (XFELs) are unique tools for studying matter on its natural time and length scales due to their bright and coherent ultrashort pulses. However, in the focus of an XFEL the assumption of a weak linear probe breaks down, and nonlinear light-matter interactions can become ubiquitous. The field can be sufficiently high that even non-resonant multiphoton interactions at hard X-rays wavelengths become relevant. Here we report the observation of one of the most fundamental nonlinear X-ray-matter interactions, the simultaneous Compton scattering of two identical photons producing a single photon at nearly twice the photon energy. We measure scattered...

  8. X-ray lithography using holographic images

    DOE Patents [OSTI]

    Howells, Malcolm S. (Berkeley, CA); Jacobsen, Chris (Sound Beach, NY)

    1997-01-01T23:59:59.000Z

    Methods for forming X-ray images having 0.25 .mu.m minimum line widths on X-ray sensitive material are presented. A holgraphic image of a desired circuit pattern is projected onto a wafer or other image-receiving substrate to allow recording of the desired image in photoresist material. In one embodiment, the method uses on-axis transmission and provides a high flux X-ray source having modest monochromaticity and coherence requirements. A layer of light-sensitive photoresist material on a wafer with a selected surface is provided to receive the image(s). The hologram has variable optical thickness and variable associated optical phase angle and amplitude attenuation for transmission of the X-rays. A second embodiment uses off-axis holography. The wafer receives the holographic image by grazing incidence reflection from a hologram printed on a flat metal or other highly reflecting surface or substrate. In this second embodiment, an X-ray beam with a high degree of monochromaticity and spatial coherence is required.

  9. X-ray lithography using holographic images

    DOE Patents [OSTI]

    Howells, M.S.; Jacobsen, C.

    1997-03-18T23:59:59.000Z

    Methods for forming X-ray images having 0.25 {micro}m minimum line widths on X-ray sensitive material are presented. A holographic image of a desired circuit pattern is projected onto a wafer or other image-receiving substrate to allow recording of the desired image in photoresist material. In one embodiment, the method uses on-axis transmission and provides a high flux X-ray source having modest monochromaticity and coherence requirements. A layer of light-sensitive photoresist material on a wafer with a selected surface is provided to receive the image(s). The hologram has variable optical thickness and variable associated optical phase angle and amplitude attenuation for transmission of the X-rays. A second embodiment uses off-axis holography. The wafer receives the holographic image by grazing incidence reflection from a hologram printed on a flat metal or other highly reflecting surface or substrate. In this second embodiment, an X-ray beam with a high degree of monochromaticity and spatial coherence is required. 15 figs.

  10. Radiographic X-Ray Pulse Jitter

    SciTech Connect (OSTI)

    Mitton, C. V., Good, D. E., Henderson, D. J., Hogge, K. W.

    2011-01-15T23:59:59.000Z

    The Dual Beam Radiographic Facility consists of two identical radiographic sources. Major components of the machines are: Marx generator, water-filled pulse-forming line (PFL), water-filled coaxial transmission line, three-cell inductive voltage adder, and rod-pinch diode. The diode pulse has the following electrical specifications: 2.25-MV, 60-kA, 60-ns. Each source has the following x-ray parameters: 1-mm-diameter spot size, 4-rad at 1 m, 50-ns full width half max. The x-ray pulse is measured with PIN diode detectors. The sources were developed to produce high resolution images on single-shot, high-value experiments. For this application it is desirable to maintain a high level of reproducibility in source output. X-ray pulse jitter is a key metric for analysis of reproducibility. We will give measurements of x-ray jitter for each machine. It is expected that x-ray pulse jitter is predominantly due to PFL switch jitter, and therefore a correlation of the two will be discussed.

  11. Oscillations During Thermonuclear X-ray Bursts

    E-Print Network [OSTI]

    Tod E. Strohmayer

    2001-01-12T23:59:59.000Z

    High amplitude, nearly coherent X-ray brightness oscillations during thermonuclear X-ray bursts were discovered with the Rossi X-ray Timing Explorer (RXTE) in early 1996. Spectral and timing evidence strongly supports the conclusion that these oscillations are caused by rotational modulation of the burst emission and that they reveal the spin frequency of neutron stars in low mass X-ray binaries, a long sought goal of X-ray astronomy. Studies carried out over the past year have led to the discovery of burst oscillations in four new sources, bringing to ten the number with confirmed burst oscillations. I review the status of our knowledge of these oscillations and indicate how they can be used to probe the physics of neutron stars. For a few burst oscillation sources it has been proposed that the strongest and most ubiquitous frequency is actually the first overtone of the spin frequency and hence that two nearly antipodal hot spots are present on the neutron star. This inference has important implications for both the physics of thermonuclear burning as well as the mass - radius relation for neutron stars, so its confirmation is crucial. I discuss recent attempts to confirm this hypothesis for 4U 1636-53, the source for which a signal at the putative fundamental (290 Hz) has been claimed.

  12. X-RAY SPECTROMETRY X-Ray Spectrom. 2007; 36: 336342

    E-Print Network [OSTI]

    Limburg, Karin E.

    , Chicago, IL 60637, USA 3 Cornell High Energy Synchrotron Source and School of Applied and EngineeringX-RAY SPECTROMETRY X-Ray Spectrom. 2007; 36: 336­342 Published online in Wiley InterScience (www to establish a breakthrough in high-resolution, simultaneous area mapping of multiple trace elements

  13. In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries Johanna Information ABSTRACT: Rechargeable lithium-sulfur (Li-S) batteries hold great potential for high of these batteries for commercial use. The two primary obstacles are the solubility of long chain lithium

  14. X-Ray Data from the X-Ray Data Booklet Online

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Thompson, Albert C.; Attwood, David T.; Gullikson, Eric M.; Howells, Malcolm R.; Kortright, Jeffrey B.; Robinson, Arthur L.; Underwood, James H.; Kim, Kwang-Je; Kirz, Janos; Lindau, Ingolf; Pianetta, Piero; Winick, Herman; Williams, Gwyn P.; Scofield, James H.

    The original X-Ray Data Booklet, published in 1985, became a classic reference source. The online version has been significantly revised and updated to reflect today's science. Hundreds of pages of authoritative data provide the x-ray properties of elements, information on synchrotron radiation, scattering processes, optics and detectors, and other related calculations, formulas, and data tables.

  15. Streaked x-ray spectrometer having a discrete selection of Bragg geometries for Omega

    SciTech Connect (OSTI)

    Millecchia, M.; Regan, S. P.; Bahr, R. E.; Romanofsky, M.; Sorce, C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623-1299 (United States)

    2012-10-15T23:59:59.000Z

    The streaked x-ray spectrometer (SXS) is used with streak cameras [D. H. Kalantar, P. M. Bell, R. L. Costa, B. A. Hammel, O. L. Landen, T. J. Orzechowski, J. D. Hares, and A. K. L. Dymoke-Bradshaw, in 22nd International Congress on High-Speed Photography and Photonics, edited by D. L. Paisley and A. M. Frank (SPIE, Bellingham, WA, 1997), Vol. 2869, p. 680] positioned with a ten-inch manipulator on OMEGA [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)] and OMEGA EP [L. J. Waxer et al., Presented at CLEO/QELS 2008, San Jose, CA, 4-9 May 2008 (Paper JThB1)] for time-resolved, x-ray spectroscopy of laser-produced plasmas in the 1.4- to 20-keV photon-energy range. These experiments require measuring a portion of this photon-energy range to monitor a particular emission or absorption feature of interest. The SXS relies on a pinned mechanical reference system to create a discrete set of Bragg reflection geometries for a variety of crystals. A wide selection of spectral windows is achieved accurately and efficiently using this technique. It replaces the previous spectrometer designs that had a continuous Bragg angle adjustment and required a tedious alignment calibration procedure. The number of spectral windows needed for the SXS was determined by studying the spectral ranges selected by OMEGA users over the last decade. These selections are easily configured in the SXS using one of the 25 discrete Bragg reflection geometries and one of the six types of Bragg crystals, including two curved crystals.

  16. Thermal and Nonthermal X-Ray Emission in SNR RCW 86

    E-Print Network [OSTI]

    K. J. Borkowski; J. Rho; S. P. Reynolds; K. K. Dyer

    2000-06-10T23:59:59.000Z

    Supernova remnants may exhibit both thermal and nonthermal X-ray emission. Such remnants can be distinguished by the weakness of their X-ray lines, because of the presence of a strong nonthermal X-ray continuum. RCW 86 is a remnant with weak lines, resulting in low and peculiar abundances when thermal models alone are used to interpret its X-ray spectrum. This indicates the presence of a strong nonthermal synchrotron continuum. We analyze ASCA X-ray spectra of RCW 86 with the help of both nonequilibrium ionization thermal models and nonthermal synchrotron models. A two-temperature thermal model and a simple nonthermal model with an exponential cutoff (plus interstellar absorption) give reasonable results. We obtain blast wave velocity of 800 km/s, the shock ionization age of 1-3x10^11 s/cm^3, and the break in nonthermal spectra at 2-4x10^16 Hz. The strength of nonthermal continuum correlates well with the radio brightness in the bright SW section of the remnant. This is convincing evidence for X-ray synchrotron emission in RCW 86.

  17. Bomb Detection Using Backscattered X-Rays

    SciTech Connect (OSTI)

    Jacobs, J.; Lockwood, G.; Selph, M; Shope, S.; Wehlburg, J.

    1998-10-01T23:59:59.000Z

    Bomb Detection Using Backscattered X-rays* Currently the most common method to determine the contents of a package suspected of containing an explosive device is to use transmission radiography. This technique requires that an x-ray source and film be placed on opposite sides of the package. This poses a problem if the pachge is placed so that only one side is accessible, such as against a wall. There is also a threat to persomel and property since exTlosive devices may be "booby trapped." We have developed a method to x-ray a paclage using backscattered x-rays. This procedure eliminates the use of film behind the target. All of the detection is done from the same side as the source. When an object is subjected to x-rays, some of them iare scattered back towards the source. The backscattenng of x-rays is propordoml to the atomic number (Z) of the material raised to the 4.1 power. This 24"' dependence allows us to easily distinguish between explosives, wires, timer, batteries, and other bomb components. Using transmission radiography-to image the contents of an unknown package poses some undesirable risks. The object must have an x-ray film placed on the side opposite the x-ray source; this cannot be done without moving the package if it has been placed firmly against a wall or pillar. Therefore it would be extremely usefid to be able to image the contents of a package from only one side, without ever having to disturb the package itself. where E is the energy of the incoming x-ray. The volume of x-rays absorbed is important because it is, of course, directly correlated to the intensity of x-mys that will be scattered. Most of the x-rays that scatter will do so in a genemlly forward direction; however, a small percentage do scatter in a backward direction. Figure 1 shows a diagram of the various fates of x-rays directed into an object. The package that was examined in this ex~enment was an attache case made of pressed fiberboardwith a vinyl covering. It was approxirmtely 36 cm wide by 51 cm long by 13 cm deep. The case was placed on an aluminum sheet under the x-ray source. Because of the laborato~ setup, the attache case was rastered in the y-coordinate direction, while the x-ray source mstered in the x-coordinate direction. However, for field use, the x-ray source would of course raster in both the x- and y-coordinate directions, while the object under interrogation would remain stationary and undisturbed. A mobile system for use by law enforcement agencies or bomb disposal squads needs to be portable and somewhat durable. A 300 kV x-ray source should be sufficient for the task requirements and can be mounted on a mobile system. A robotic carriage could be used to transport the x-ray source and the CCD camera to the proximity of the suspect package. The controlling and data analyzing elements of the system' could then be maintained at a &tie distance from the possible explosive. F@re 8 shows a diagram of a conceptual design of a possible system for this type of use. The use of backscattered x-rays for interrogation of packages that may contain explosive devices has been shown to be feasible inthelaboratory. Usinga 150kVx-ray source anddetectors consisting of plastic scintillating material, all bomb components including the wiring were detectable. However, at this time the process requires more time than is desirable for the situations in which it will most likely be needed. Further development of the technology using CCD cameras, rather than the plastic stint illator detectors, shows promise of leading to a much faster system, as well as one with better resolution. Mounting the x- ray source and the CCD camera on a robotic vehicle while keeping the controlling and analyzing components and the opemting personnel a safe distance away from the suspect package will allow such a package to be examined at low risk to human life.

  18. Frontiers in X-Ray Science

    SciTech Connect (OSTI)

    Linda Young

    2011-02-23T23:59:59.000Z

    The year 2010 marked the fiftieth anniversary of the optical laser and the first anniversary of the world's first hard x-ray free-electron laser, the Linac Coherent Light Source (LCLS) at SLAC. This exciting, new accelerator-based source of x-rays provides peak brilliances roughly a billion times greater than currently available from synchrotron sources such as the Advanced Photon Source at Argonne, and thus explores a qualitatively different parameter space. This talk will describe the first experiments at the LCLS aimed at understanding the nature of high intensity x-ray interactions, related applications in ultrafast imaging on the atomic scale and sketch nascent plans for the extension of both linac and storage-ring based photon sources.

  19. The X-ray/submillimetre link

    E-Print Network [OSTI]

    O. Almaini

    2000-01-07T23:59:59.000Z

    It is widely believed that most of the cosmic X-ray background (XRB) is produced by a vast, hitherto undetected population of obscured AGN. Deep X-ray surveys with Chandra and XMM will soon test this hypothesis. Similarly, recent sub-mm surveys with SCUBA have revealed an analogous population of exceptionally luminous, dust-enshrouded {\\em star-forming} galaxies at high redshift. There is now growing evidence for an intimate link between these obscured populations. There are currently large uncertainties in the models, but several independent arguments lead to the conclusion that a significant fraction of the SCUBA sources ($10-30% $) will contain quasars. Recent observational studies of SCUBA survey sources appear to confirm these predictions, although the relative roles of AGN and star-forming activity in heating the dust are unclear. Forthcoming surveys combining X-ray and sub-mm observations will provide a very powerful tool for disentangling these processes.

  20. X-ray atlas of rheumatic diseases

    SciTech Connect (OSTI)

    Dihlmann, W.

    1986-01-01T23:59:59.000Z

    This atlas comprises instructive X-rays of the various inflammatory rheumatic joint diseases in all stages at the extremities and the spinal column. In addition, the complex pattern of the wide range of arthroses, also known as degenerative rheumatic disease is included. Besides the instructive pointers to X-ray diagnosis, the book is also a guide to differential diagnosis. Hence, this book is actually an X-ray atlas of joint diseases in general. Selected Contents: Introduction: What Does ''Rheumatism'' Actually Mean./Radiographic Methodology in Rheumatic Diseases of the Locomotor System/The Mosaic of Arthritis/Adult Rheumatoid Arthritis/Seronegative Spondylarthritis/Classic Collagen Diseases/Enthesiopathies/Gout-Pseudogout

  1. Combined microstructure x-ray optics

    SciTech Connect (OSTI)

    Barbee, T.W. Jr.

    1989-02-01T23:59:59.000Z

    Multilayers are man-made microstructures which vary in depth and are now of sufficient quality to be used as x-ray, soft x-ray and extreme ultraviolet optics. Gratings are man-made in plane microstructures which have been used as optic elements for most of this century. Joining of these two optical microstructures to form combined microstructure optical microstructures to form combined microstructure optical elements has the potential for greatly enhancing both the throughput and the resolution attainable in these spectral ranges. The characteristics of these new optic elements will be presented and compared to experiment with emphasis on the unique properties of these combined microstructures. These results reported are general in nature and not limited to the soft x-ray or extreme ultraviolet spectral domains and also apply to neutrons. 19 refs., 7 figs., 4 tabs.

  2. X-ray reflectivity and surface roughness

    SciTech Connect (OSTI)

    Ocko, B.M.

    1988-01-01T23:59:59.000Z

    Since the advent of high brightness synchrotron radiation sources there has been a phenomenal growth in the use of x-rays as a probe of surface structure. The technique of x-ray reflectivity is particularly relevant to electrochemists since it is capable of probing the structure normal to an electrode surface in situ. In this paper the theoretical framework for x-ray reflectivity is reviewed and the results from previous non-electrochemistry measurements are summarized. These measurements are from the liquid/air interface (CCl/sub 4/), the metal crystal vacuum interface (Au(100)), and from the liquid/solid interface(liquid crystal/silicon). 34 refs., 5 figs.

  3. Anomalous X-ray Diffraction Studies for Photovoltaic Applications

    SciTech Connect (OSTI)

    Not Available

    2011-06-22T23:59:59.000Z

    Anomalous X-ray Diffraction (AXRD) has become a useful technique in characterizing bulk and nanomaterials as it provides specific information about the crystal structure of materials. In this project we present the results of AXRD applied to materials for photovoltaic applications: ZnO loaded with Ga and ZnCo{sub 2}O{sub 4} spinel. The X-ray diffraction data collected for various energies were plotted in Origin software. The peaks were fitted using different functions including Pseudo Voigt, Gaussian, and Lorentzian. This fitting provided the integrated intensity data (peaks area values), which when plotted as a function of X-ray energies determined the material structure. For the first analyzed sample, Ga was not incorporated into the ZnO crystal structure. For the ZnCo{sub 2}O{sub 4} spinel Co was found in one or both tetrahedral and octahedral sites. The use of anomalous X-ray diffraction (AXRD) provides element and site specific information for the crystal structure of a material. This technique lets us correlate the structure to the electronic properties of the materials as it allows us to probe precise locations of cations in the spinel structure. What makes it possible is that in AXRD the diffraction pattern is measured at a number of energies near an X-ray absorption edge of an element of interest. The atomic scattering strength of an element varies near its absorption edge and hence the total intensity of the diffraction peak changes by changing the X-ray energy. Thus AXRD provides element specific structural information. This method can be applied to both crystalline and liquid materials. One of the advantages of AXRD in crystallography experiments is its sensitivity to neighboring elements in the periodic tables. This method is also sensitive to specific crystallographic phases and to a specific site in a phase. The main use of AXRD in this study is for transparent conductors (TCs) analysis. TCs are considered to be important materials because of their efficiency and low risk of environmental pollution. These materials are important to solar cells as a result of their remarkable combination of optical and electrical properties, including high electrical conductivity and high optical transparency in the spectrum of visible light. TCs provide a transparent window, which allows sunlight to pass through while also allowing electricity to conduct out of the cell. Spinel materials have the chemical form AB{sub 2}O{sub 4}, and are made of a face-centered cubic (FCC) lattice of oxygen anions and cations in specific interstitial sites. A normal spinel has all A cations on tetrahedral sites and B cations on octahedral sites. In contrast; an inverse spinel has the A and half of the B cations on octahedral sites and the other half of the B cations on tetrahedral sites; a mixed spinel lies between. In the spinel structure, 8 of 64 possible tetrahedral sites and 16 of 32 possible octahedral sites are filled. Normal spinels have particularly high conduction as the linear octahedral chains of B cations likely serve as conduction paths. In this paper we present how the data obtained with AXRD is used to analyze TCs properties as they apply to photovoltaic applications. One of the materials used for this analysis is zinc oxide. It has been loaded with 5% and 10% of Ga, which has an absorption edge of 10367 eV. The peak (100) was measured for the zinc oxide loaded with 10% Ga. In the case of 5% Ga, we measured peaks (100) and (101). With the information provided by the AXRD we can identify if Ga is being incorporated in the ZnO crystal structure. The analysis of 311 plane in the ZnCo{sub 2}O{sub 4} spinel shows if Co is in tetrahedral or octahedral site.

  4. A method for measuring the rate of reaction by molecular microwave absorption spectroscopy

    E-Print Network [OSTI]

    Brown, Allan Neil

    1954-01-01T23:59:59.000Z

    A METHOD FOR MEASURING THE RATE OF REACTION BT MOLECULAR MICROWAVE ABSORPTION SPECTROSCOPY A Dissertation 9$r Allan Neil Brown Approved as to style and content by: Head of the Departme Chairman of Committee June AM ET LIBRARY A A M COLLEGE... Amplifier ............. ET Figure 8. The Oscilloscope . . . . . . . . . . . . . . . . . 1H Figure 9. The Voltage Integrator.......................... 17 Figure 10. Diagram of Voltage Inte g r a t o r................... 18 Figure 11. The Recording Unit...

  5. Portable total reflection x-ray fluorescence analysis in the identification of unknown laboratory hazards

    SciTech Connect (OSTI)

    Liu, Ying, E-mail: liu.ying.48r@st.kyoto-u.ac.jp; Imashuku, Susumu; Sasaki, Nobuharu; Ze, Long; Kawai, Jun [Department of Materials Science and Engineering, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501 (Japan); Takano, Shotaro; Sohrin, Yoshiki [Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Seki, Hiroko; Miyauchi, Hiroya [Kyoto Prefectural Technology Center for Small and Medium Enterprises, Chudojiminami machi, Shimogyo-ku, Kyoto 600-8813 (Japan)

    2014-05-15T23:59:59.000Z

    In this study, a portable total reflection x-ray fluorescence (TXRF) spectrometer was used to analyze unknown laboratory hazards that precipitated on exterior surfaces of cooling pipes and fume hood pipes in chemical laboratories. With the aim to examine the accuracy of TXRF analysis for the determination of elemental composition, analytical results were compared with those of wavelength-dispersive x-ray fluorescence spectrometry, scanning electron microscope and energy-dispersive x-ray spectrometry, energy-dispersive x-ray fluorescence spectrometry, inductively coupled plasma atomic emission spectrometry, x-ray diffraction spectrometry (XRD), and x-ray photoelectron spectroscopy (XPS). Detailed comparison of data confirmed that the TXRF method itself was not sufficient to determine all the elements (Z?>?11) contained in the samples. In addition, results suggest that XRD should be combined with XPS in order to accurately determine compound composition. This study demonstrates that at least two analytical methods should be used in order to analyze the composition of unknown real samples.

  6. Discovery of Extremely Embedded X-ray Sources in the R Coronae Australis Star Forming Core

    E-Print Network [OSTI]

    Kenji Hamaguchi; Michael F. Corcoran; Rob Petre; Nicholas E. White; Beate Stelzer; Ko Nedachi; Naoto Kobayashi; Alan T. Tokunaga

    2005-03-02T23:59:59.000Z

    With the XMM-Newton and Chandra observatories, we detected two extremely embedded X-ray sources in the R Corona Australis (R CrA) star forming core, near IRS 7. These sources, designated as XB and XA, have X-ray absorption columns of ~3e23 cm-2 equivalent to AV ~180 mag. They are associated with the VLA centimeter radio sources 10E and 10W, respectively. XA is the counterpart of the near-infrared source IRS 7, whereas XB has no K-band counterpart above 19.4 mag. This indicates that XB is younger than typical Class I protostars, probably a Class 0 protostar or in an intermediate phase between Class 0 and Class I. The X-ray luminosity of XB varied between 29X-ray brightness by a factor of two in 30 ksec during an XMM-Newton observation. The XMM-Newton spectra indicate emission from a hot plasma with kT ~3-4 keV and also show fluorescent emission from cold iron. Though the X-ray spectrum from XB is similar to flare spectra from Class I protostars in luminosity and temperature, the light curve does not resemble the lightcurves of magnetically generated X-ray flares because the variability timescale of XB is too long and because variations in X-ray count rate were not accompanied by variations in spectral hardness. The short-term variation of XB may be caused by the partial blocking of the X-ray plasma, while the month-long flux enhancement may be driven by mass accretion.

  7. The XMM large scale structure survey: optical vs. X-ray classifications of active galactic nuclei and the unified scheme

    E-Print Network [OSTI]

    O. Garcet; P. Gandhi; E. Gosset; P. G. Sprimont; J. Surdej; V. Borkowski; M. Tajer; F. Pacaud; M. Pierre; L. Chiappetti; D. Maccagni; M. J. Page; F. J. Carrera; J. A. Tedds; S. Mateos; M. Krumpe; T. Contini; A. Corral; J. Ebrero; I. Gavignaud; A. Schwope; O. Le Fevre; M. Polletta; S. Rosen; C. Lonsdale; M. Watson; W. Borczyk; P. Vaisanen

    2007-09-13T23:59:59.000Z

    Our goal is to characterize AGN populations by comparing their X-ray and optical classifications. We present a sample of 99 spectroscopically identified X-ray point sources in the XMM-LSS survey which are significantly detected in the [2-10] keV band, and with more than 80 counts. We performed an X-ray spectral analysis for all of these 99 X-ray sources. Introducing the fourfold point correlation coefficient, we find only a mild correlation between the X-ray and the optical classifications, as up to 30% of the sources have differing X-ray and optical classifications: on one hand, 10% of the type 1 sources present broad emission lines in their optical spectra and strong absorption in the X-rays. These objects are highly luminous AGN lying at high redshift and thus dilution effects are totally ruled out, their discrepant nature being an intrinsic property. Their X-ray luminosities and redshifts distributions are consistent with those of the unabsorbed X-ray sources with broad emission lines. On the other hand, 25/32 are moderate luminosity AGN, which are both unabsorbed in the X-rays and only present narrow emission lines in their optical spectra. The majority of them have an optical spectrum which is representative of the host galaxy. We finally infer that dilution of the AGN by the host galaxy seems to account for their nature. 5/25 have been defined as Seyfert 2. In conclusion, most of these 32 discrepant cases can be accounted for by the standard AGN unified scheme, as its predictions are not met for only 12% of the 99 X-ray sources. ABRIDGED

  8. Radiobiological studies using gamma and x rays.

    SciTech Connect (OSTI)

    Potter, Charles Augustus; Longley, Susan W.; Scott, Bobby R. [Lovelace Respiratory Research Institute, Albuquerque, NM; Lin, Yong [Lovelace Respiratory Research Institute, Albuquerque, NM; Wilder, Julie [Lovelace Respiratory Research Institute, Albuquerque, NM; Hutt, Julie A. [Lovelace Respiratory Research Institute, Albuquerque, NM; Padilla, Mabel T. [Lovelace Respiratory Research Institute, Albuquerque, NM; Gott, Katherine M. [Lovelace Respiratory Research Institute, Albuquerque, NM

    2013-02-01T23:59:59.000Z

    There are approximately 500 self-shielded research irradiators used in various facilities throughout the U.S. These facilities use radioactive sources containing either 137Cs or 60Co for a variety of biological investigations. A report from the National Academy of Sciences[1] described the issues with security of particular radiation sources and the desire for their replacement. The participants in this effort prepared two peer-reviewed publications to document the results of radiobiological studies performed using photons from 320-kV x rays and 137Cs on cell cultures and mice. The effectiveness of X rays was shown to vary with cell type.

  9. Energy resolved X-ray grating interferometry

    SciTech Connect (OSTI)

    Thuering, T.; Stampanoni, M. [Swiss Light Source, Paul Scherrer Institut, Villigen PSI (Switzerland) [Swiss Light Source, Paul Scherrer Institut, Villigen PSI (Switzerland); Institute for Biomedical Engineering, Swiss Federal Institute of Technology, Zurich (Switzerland); Barber, W. C.; Iwanczyk, J. S. [DxRay, Inc., Northridge, California 91324 (United States)] [DxRay, Inc., Northridge, California 91324 (United States); Seo, Y.; Alhassen, F. [UCSF Physics Research Laboratory, Department of Radiology and Biomedical Imaging, University of California, San Francisco, California 94143 (United States)] [UCSF Physics Research Laboratory, Department of Radiology and Biomedical Imaging, University of California, San Francisco, California 94143 (United States)

    2013-05-13T23:59:59.000Z

    Although compatible with polychromatic radiation, the sensitivity in X-ray phase contrast imaging with a grating interferometer is strongly dependent on the X-ray spectrum. We used an energy resolving detector to quantitatively investigate the dependency of the noise from the spectral bandwidth and to consequently optimize the system-by selecting the best energy band matching the experimental conditions-with respect to sensitivity maximization and, eventually, dose. Further, since theoretical calculations of the spectrum are usually limited due to non-ideal conditions, an energy resolving detector accurately quantifies the spectral changes induced by the interferometer including flux reduction and beam hardening.

  10. X-Ray Nanoimaging: Instruments and Methods

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensusX-RayX-Ray

  11. Discovery of a bright X-ray transient in the Galactic Center with XMM-Newton

    E-Print Network [OSTI]

    D. Porquet; N. Grosso; V. Burwitz; I. L. Andronov; B. Aschenbach; P. Predehl; R. S. Warwick

    2004-12-06T23:59:59.000Z

    We report the discovery of a bright X-ray transient object, XMMU J174554.4-285456, observed in outburst with XMM-Newton on October 3, 2002,and located at 6.3' from SgrA*, the supermassive black hole at the Galactic center.This object exhibits a very large X-ray luminosity variability of a factor of about 1300 between two X-ray observations separated by four months. The X-ray spectrum is best fitted by a power-law with a photon index of 1.6+/-0.2 and absorption column density of 14.1 (+1.6,-1.4) x 10^22 cm^-2. This large absorption suggests this source is located at the distance of the Galactic center, i.e., 8 kpc. The 2-10 keV luminosity is about 1.0 x 10^35(d/8kpc)^2 erg/s. A pulsation period of about 172 s is hinted by the timing analysis. The X-ray properties strongly suggest a binary system with either a black hole or a neutron star for the compact object.

  12. Titanium and germanium lined hohlraums and halfraums as multi-keV x-ray radiators

    SciTech Connect (OSTI)

    Girard, F.; Primout, M.; Villette, B.; Stemmler, Ph.; Jacquet, L.; Babonneau, D. [CEA, DAM, DIF, F-91297 Arpajon (France); Fournier, K. B. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94550 (United States)

    2009-05-15T23:59:59.000Z

    As multi-keV x-ray radiators, hohlraums and halfraums with inner walls coated with metallic materials (called liner) have been tested for the first time with laser as the energy drive. For titanium, conversion efficiencies (CEs) are up to {approx}14% for emission into 4{pi}, integrating between 4.6 and 6.5 keV when a large diameter hohlraum is used. Germanium CE is {approx}0.8% into 4{pi} between 9 and 13 keV. The highest CEs have been obtained with a 1 ns squared pulse and phase plates giving laser absorption near 99%. These high CEs are due to long-lasting, good plasma conditions for multi-keV x-ray production maintained by plasma confinement inside the plastic cylinder and plasma collision leading to a burst of x rays at a time that depends on target size. As photon emitters at 4.7 keV, titanium-lined hohlraums are the most efficient solid targets and data are close to CEs for gas targets, which are considered as the upper limit for x-ray yields since their low density allows good laser absorption and low kinetics losses. As 10.3 keV x-ray emitters, exploded germanium foils give best results one order of magnitude more efficient than thick targets; doped aerogels and lined hohlraums give similar yields, about three times lower than those from exploded foils.

  13. Soft X-Ray Spectroscopic Study of Dense Strontium-Doped Lanthanum Manganite Cathodes for Solid Oxide Fuel Cell Applications

    SciTech Connect (OSTI)

    Piper, L.F.J.; Preston, Andrew R.H.; Cho, Sang Wan; DeMasi, Alexander; Chen, Bin; Laverock, J.; Smith, K. E.; Miara, Lincoln J.; Davis, Jacob N.; Basu, Soumendra; Pal, Uday B.; Gopalan, Srikanth; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Matsuura, A. Y.; Glans, P.A.; Guo, Jianzhong

    2010-12-02T23:59:59.000Z

    The modification of the Mn charge-state, chemical composition and electronic structure of La0.8Sr0.2MnO3 (LSMO) cathodes for solid oxide fuel cell (SOFC) applications remains an area of interest, due to the poorly understood enhanced catalytic activity (often referred to as the "burn-in" phenomenon) observed after many hours of operation. Using a combination of core-level X-ray photoemission spectroscopy (XPS), X-ray emission/absorption spectroscopy (XES/XAS), resonant inelastic X-ray scattering (RIXS) and resonant photoemission spectroscopy (RPES), we have monitored the evolution of these properties in LSMO at various stages of fabrication and operation. By rapidly quenching and sealing in vacuum, we were able to directly compare the pristine (as-fabricated) LSMO with both "heat-treated" (800°C in air, and no bias) and "burnt-in" (800°C in air, -1 V bias) LSMO cathodes i.e. before and after the activation observed in our electrochemical impendence spectroscopy measurements. Comparison between the O K-edge XAS/XES and Mn L3,2-edge XAS of pristine and “burnt-in” LSMO cathodes revealed a severe change in the oxygen environment along with a reduced Mn2+ presence near the surface following activation. The change in the oxygen environment is attributed to SrxMnyOz formation, along with possible passive SrO and Mn3O4 species. We present evidence from our “heat-treated” samples that SrxMnyOz regions form at elevated temperatures in air before the application of a cathodic bias. Our core-level XPS, Mn L3,2-edge RIXS and Mn L3 RPES studies of “heat-treated” and pristine LSMO determined that SOFC environments result in La-deficiency (severest near the surface) and stronger Mn4+ contribution, leading to the increased insulating character of the cathode prior to activation. The passive Mn2+ species near the surface and increased hole-doping (>0.6) of the LSMO upon exposure to the operating environment are considered responsible for the initially poor performance of the SOFC. Meanwhile, the improved oxygen reduction following the application of a cathodic bias is considered to be due to enhanced bulk oxygen-ion diffusion resulting from the migration of Mn2+ ions towards the LSMO/electrolyte interface and the SrxMnyOz regions facilitating enhanced bulk oxygen reduction reaction kinetics.

  14. SLAC All Access: X-ray Microscope

    ScienceCinema (OSTI)

    Nelson, Johanna; Liu, Yijin

    2014-06-13T23:59:59.000Z

    SLAC physicists Johanna Nelson and Yijin Liu give a brief overview of the X-ray microscope at the Stanford Synchrotron Radiation Lightsource (SSRL) that is helping improve rechargeable-battery technology by letting researchers peek into the inner workings of batteries as they operate.

  15. Femtosecond X-ray protein nanocrystallography

    SciTech Connect (OSTI)

    Chapman, Henry N.; Fromme, Petra; Barty, Anton; White, Thomas A.; Kirian, Richard A.; Aquila, Andrew; Hunter, Mark S.; Schulz, Joachim; DePonte, Daniel P.; Weierstall, Uwe; Doak, R. Bruce; Maia, Filipe R. N. C.; Martin, Andrew V.; Schlichting, Ilme; Lomb, Lukas; Coppola, Nicola; Shoeman, Robert L.; Epp, Sascha W.; Hartmann, Robert; Rolles, Daniel; Rudenko, Artem; Foucar, Lutz; Kimmel, Nils; Weidenspointner, Georg; Holl, Peter; Liang, Mengning; Barthelmess, Miriam; Caleman, Carl; Boutet, Sebastien; Bogan, Michael J.; Krzywinski, Jacek; Bostedt, Christoph; Bajt, Sasa; Gumprecht, Lars; Rudek, Benedikt; Erk, Benjamin; Schmidt, Carlo; Homke, Andre; Reich, Christian; Pietschner, Daniel; Struder, Lothar; Hauser, Gunter; Gorke, Hubert; Ullrich, Joachim; Herrmann, Sven; Schaller, Gerhard; Schopper, Florian; Soltau, Heike; Kuhnel, Kai-Uwe; Messerschmidt, Marc; Bozek, John D.; Hau-Riege, Stefan P.; Frank, Matthias; Hampton, Christina Y.; Sierra, Raymond G.; Starodub, Dmitri; Williams, Garth J.; Hajdu, Janos; Timneanu, Nicusor; Seibert, M. Marvin; Andreasson, Jakob; Rocker, Andrea; Jonsson, Olof; Svenda, Martin; Stern, Stephan; Nass, Karol; Andritschke, Robert; Schroter, Claus-Dieter; Krasniqi, Faton; Bott, Mario; Schmidt, Kevin E.; Wang, Xiaoyu; Grotjohann, Ingo; Holton, James M.; Barends, Thomas R. M.; Neutze, Richard; Marchesini, Stefano; Fromme, Raimund; Schorb, Sebastian; Rupp, Daniela; Adolph, Marcus; Gorkhover, Tais; Andersson, Inger; Hirsemann, Helmut; Potdevin, Guillaume; Graafsma, Heinz; Nilsson, Bjorn; Spence, John C. H.

    2011-01-01T23:59:59.000Z

    X-ray crystallography provides the vast majority of macromolecular structures, but the success of the method relies on growing crystals of sufficient size. In conventional measurements, the necessary increase in X-ray dose to record data from crystals that are too small leads to extensive damage before a diffraction signal can be recorded. It is particularly challenging to obtain large, well-diffracting crystals of membrane proteins, for which fewer than 300 unique structures have been determined despite their importance in all living cells. Here we present a method for structure determination where single-crystal X-ray diffraction ‘snapshots’ are collected from a fully hydrated stream of nanocrystals using femtosecond pulses from a hard-X-ray free-electron laser, the Linac Coherent Light Source. We prove this concept with nanocrystals of photosystem I, one of the largest membrane protein complexes. More than 3,000,000 diffraction patterns were collected in this study, and a three-dimensional data set was assembled from individual photosystem I nanocrystals (~200?nm to 2??m in size). We mitigate the problem of radiation damage in crystallography by using pulses briefer than the timescale of most damage processes. This offers a new approach to structure determination of macromolecules that do not yield crystals of sufficient size for studies using conventional radiation sources or are particularly sensitive to radiation damage.

  16. Catalog of supersoft X-ray sources

    E-Print Network [OSTI]

    J. Greiner

    2000-05-11T23:59:59.000Z

    This catalog comprises an up-to-date (December 1999) list of luminous (>10^36 erg/s), binary supersoft X-ray sources. This electronic version (including the accompannying Web-pages) supersedes the printed version of Greiner (1996).

  17. A High Resolution Intergalactic Explorer for the Soft X-ray/FUV

    E-Print Network [OSTI]

    Martin Elvis; Fabrizio Fiore; the CWE Team

    2003-03-19T23:59:59.000Z

    We present a mission concept for high resolution X-ray spectroscopy with a resolving power, R~6000, (c.f. R=Web'. The Cosmic Web is predicted to contain most of the normal matter (baryons) in the nearby Universe.

  18. Femtosecond Single-Shot Imaging of Nanoscale Ferromagnetic Order in Co/Pd Multilayers using Resonant X-ray Holography

    SciTech Connect (OSTI)

    Wang, Tianhan; Zhu, Diling; Benny Wu,; Graves, Catherine; Schaffert, Stefan; Rander, Torbjorn; Muller, leonard; Vodungbo, Boris; Baumier, Cedric; Bernstein, David P.; Brauer, Bjorn; Cros, Vincent; Jong, Sanne de; Delaunay, Renaud; Fognini, Andreas; Kukreja, Roopali; Lee, Sooheyong; Lopez-Flores, Victor; Mohanty, Jyoti; Pfau, Bastian; Popescu, 5 Horia

    2012-05-15T23:59:59.000Z

    We present the first single-shot images of ferromagnetic, nanoscale spin order taken with femtosecond x-ray pulses. X-ray-induced electron and spin dynamics can be outrun with pulses shorter than 80 fs in the investigated fluence regime, and no permanent aftereffects in the samples are observed below a fluence of 25 mJ/cm{sup 2}. Employing resonant spatially-muliplexed x-ray holography results in a low imaging threshold of 5 mJ/cm{sup 2}. Our results open new ways to combine ultrafast laser spectroscopy with sequential snapshot imaging on a single sample, generating a movie of excited state dynamics.

  19. The X-Ray Environment During the Epoch of Terrestrial Planet Formation: Chandra Observations of h Persei

    E-Print Network [OSTI]

    Thayne Currie; Nancy Remage Evans; Brad Spitzbart; Jonathan Irwin; Scott J. Wolk; Jesus Hernandez; Scott J. Kenyon; Jay Pasachoff

    2008-11-11T23:59:59.000Z

    We describe Chandra/ACIS-I observations of the massive ~ 13--14 Myr-old cluster, h Persei, part of the famous Double Cluster (h and chi Persei) in Perseus. Combining the list of Chandra-detected sources with new optical/IR photometry and optical spectroscopy reveals ~ 165 X-ray bright stars with V 1.5 Msun) fall out of X-ray saturation by ~ 10--15 Myr. Changes in stellar structure for > 1.5 Msun stars likely play an important role in this decline of X-ray emission.

  20. Rise time measurement for ultrafast X-ray pulses

    DOE Patents [OSTI]

    Celliers, Peter M. (Berkeley, CA); Weber, Franz A. (Oakland, CA); Moon, Stephen J. (Tracy, CA)

    2005-04-05T23:59:59.000Z

    A pump-probe scheme measures the rise time of ultrafast x-ray pulses. Conventional high speed x-ray diagnostics (x-ray streak cameras, PIN diodes, diamond PCD devices) do not provide sufficient time resolution to resolve rise times of x-ray pulses on the order of 50 fs or less as they are being produced by modern fast x-ray sources. Here, we are describing a pump-probe technique that can be employed to measure events where detector resolution is insufficient to resolve the event. The scheme utilizes a diamond plate as an x-ray transducer and a p-polarized probe beam.