National Library of Energy BETA

Sample records for wet flue gas

  1. Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system

    SciTech Connect (OSTI)

    Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

    1991-01-01

    Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

  2. System of treating flue gas

    DOE Patents [OSTI]

    Ziegler, D.L.

    1975-12-01

    A system is described for treating or cleaning incinerator flue gas containing acid gases and radioactive and fissionable contaminants. Flue gas and a quench solution are fed into a venturi and then tangentially into the lower portion of a receptacle for restricting volumetric content of the solution. The upper portion of the receptacle contains a scrub bed to further treat or clean the flue gas.

  3. Flue gas desulfurization wastewater treatment primer

    SciTech Connect (OSTI)

    Higgins, T.E.; Sandy, A.T.; Givens, S.W.

    2009-03-15

    Purge water from a typical wet flue gas desulfurization system contains myriad chemical constituents and heavy metals whose mixture is determined by the fuel source and combustion products as well as the stack gas treatment process. A well-designed water treatment system can tolerate upstream fuel and sorbent arranged in just the right order to produce wastewater acceptable for discharge. This article presents state-of-the-art technologies for treating the waste water that is generated by wet FGD systems. 11 figs., 3 tabs.

  4. Flue gas conditioning today

    SciTech Connect (OSTI)

    Southam, B.J.; Coe, E.L. Jr.

    1995-12-01

    Many relatively small electrostatic precipitators (ESP`s) exist which collect fly ash at remarkably high efficiencies and have been tested consistently at correspondingly high migration velocities. But the majority of the world`s coal supplies produce ashes which are collected at much lower migration velocities for a given efficiency and therefore require correspondingly large specific collection areas to achieve acceptable results. Early trials of flue gas conditioning (FGC) showed benefits in maximizing ESP performance and minimizing expense which justified continued experimentation. Trials of several dozen ways of doing it wrong eventually developed a set of reliable rules for doing it right. One result is that the use of sulfur trioxide (SO{sub 3}) for adjustment of the resistivity of fly ash from low sulfur coal has been widely applied and has become an automatically accepted part of the option of burning low sulfur coal for compliance with the Clean Air Act of l990 in the U.S.A. Currently, over 100,000 MW of generating capacity is using FGC, and it is estimated that approximately 45,800 MW will utilize coal-switching with FGC for Clean Air Act emission compliance. Guarantees that this equipment will be available to operate at least 98 percent of the time it is called upon are routinely fulfilled.

  5. Mercury sorbent delivery system for flue gas

    DOE Patents [OSTI]

    Klunder; ,Edgar B.

    2009-02-24

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  6. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  7. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, Kwan H.; Ahluwalia, Rajesh K.

    1985-01-01

    A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

  8. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  9. Flue gas desulfurization: Physicochemical and biotechnological approaches

    SciTech Connect (OSTI)

    Pandey, R.A.; Biswas, R.; Chakrabarti, T.; Devotta, S.

    2005-07-01

    Various flue gas desulfurization processes - physicochemical, biological, and chemobiological - for the reduction of emission of SO{sub 2} with recovery of an economic by-product have been reviewed. The physicochemical processes have been categorized as 'once-through' and 'regenerable.' The prominent once-through technologies include wet and dry scrubbing. The wet scrubbing technologies include wet limestone, lime-inhibited oxidation, limestone forced oxidation, and magnesium-enhanced lime and sodium scrubbing. The dry scrubbing constitutes lime spray drying, furnace sorbent injection, economizer sorbent injection, duct sorbent injection, HYPAS sorbent injection, and circulating fluidized bed treatment process. The regenerable wet and dry processes include the Wellman Lord's process, citrate process, sodium carbonate eutectic process, magnesium oxide process, amine process, aqueous ammonia process, Berglau Forchung's process, and Shell's process. Besides these, the recently developed technologies such as the COBRA process, the OSCAR process, and the emerging biotechnological and chemobiological processes are also discussed. A detailed outline of the chemistry, the advantages and disadvantages, and the future research and development needs for each of these commercially viable processes is also discussed.

  10. Flue gas injection control of silica in cooling towers. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Flue gas injection control of silica in cooling towers. Citation Details In-Document Search Title: Flue gas injection control of silica in cooling towers. ...

  11. Recovery of Water from Boiler Flue Gas Using Condensing Heat...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers Citation Details In-Document Search Title: Recovery of Water from Boiler Flue Gas Using ...

  12. Sorbents for mercury removal from flue gas (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Fossil Energy Country of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; Flue Gas; Flue Gas; Mercury; Mercury; ...

  13. Kinetics of combined SO/sub 2//NO in flue gas clean-up

    SciTech Connect (OSTI)

    Chang, S.G.; Littlejohn, D.

    1985-03-01

    The kinetics of reactions involving SO/sub 2/, NO, and ferrous chelate additives in wet flue gas simultaneous desulfurization and denitrification scrubbers are discussed. The relative importance of these reactions are assessed. The relevance of these reactions to spray dryer processes for combined SO/sub 2//NO flue gas clean-up is addressed. 37 refs., 7 figs.

  14. natural gas+ condensing flue gas heat recovery+ water creation...

    Open Energy Info (EERE)

    natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

  15. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  16. BUILDING MATERIALS MADE FROM FLUE GAS DESULFURIZATION BY-PRODUCTS

    SciTech Connect (OSTI)

    Michael W. Grutzeck; Maria DiCola; Paul Brenner

    2006-03-30

    Flue gas desulphurization (FGD) materials are produced in abundant quantities by coal burning utilities. Due to environmental restrains, flue gases must be ''cleaned'' prior to release to the atmosphere. They are two general methods to ''scrub'' flue gas: wet and dry. The choice of scrubbing material is often defined by the type of coal being burned, i.e. its composition. Scrubbing is traditionally carried out using a slurry of calcium containing material (slaked lime or calcium carbonate) that is made to contact exiting flue gas as either a spay injected into the gas or in a bubble tower. The calcium combined with the SO{sub 2} in the gas to form insoluble precipitates. Some plants have been using dry injection of these same materials or their own Class C fly ash to scrub. In either case the end product contains primarily hannebachite (CaSO{sub 3} {center_dot} 1/2H{sub 2}O) with smaller amounts of gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O). These materials have little commercial use. Experiments were carried out that were meant to explore the feasibility of using blends of hannebachite and fly ash mixed with concentrated sodium hydroxide to make masonry products. The results suggest that some of these mixtures could be used in place of conventional Portland cement based products such as retaining wall bricks and pavers.

  17. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  18. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  19. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  20. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  1. Flue gas injection control of silica in cooling towers. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Flue gas injection control of silica in cooling towers. Citation Details In-Document Search Title: Flue gas injection control of silica in cooling towers. You are accessing a ...

  2. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Bush, P.V.; Snyder, T.R.

    1992-01-09

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ask properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  3. Cement Kiln Flue Gas Recovery Scrubber Project

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2001-11-30

    The Cement Kiln Flue Gas Recovery Scrubber Project was a technical success and demonstrated the following: CKD can be used successfully as the sole reagent for removing SO2 from cement kiln flue gas, with removal efficiencies of 90 percent or greater; Removal efficiencies for HCl and VOCs were approximately 98 percent and 70 percent, respectively; Particulate emissions were low, in the range of 0.005 to 0.007 grains/standard cubic foot; The treated CKD sorbent can be recycled to the kiln after its potassium content has been reduced in the scrubber, thereby avoiding the need for landfilling; The process can yield fertilizer-grade K2SO4, a saleable by-product; and Waste heat in the flue gas can provide the energy required for evaporation and crystallization in the by-product recovery operation. The demonstration program established the feasibility of using the Recovery Scrubber{trademark} for desulfurization of flue gas from cement kilns, with generally favorable economics, assuming tipping fees are available for disposal of ash from biomass combustion. The process appears to be suitable for commercial use on any type of cement kiln. EPA has ruled that CKD is a nonhazardous waste, provided the facility meets Performance Standards for the Management of CKD (U.S. Environmental Protection Agency 1999d). Therefore, regulatory drivers for the technology focus more on reduction of air pollutants and pollution prevention, rather than on treating CKD as a hazardous waste. Application of the Recovery Scrubbe{trademark} concept to other waste-disposal operations, where pollution and waste reductions are needed, appears promising.

  4. Characterization of suspended flue gas particle systems with...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; CASCADE IMPACTORS; PERFORMANCE TESTING; FLUE GAS; PARTICLE SIZE; FLUIDIZED-BED COMBUSTION; AIR FILTERS; DISTRIBUTION; MEASURING INSTRUMENTS; ...

  5. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power...

    Office of Scientific and Technical Information (OSTI)

    Flue Gas Purification - Power Plant Performance Citation Details In-Document Search Title: Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance A ...

  6. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler's outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  7. Utility flue gas mercury control via sorbent injection

    SciTech Connect (OSTI)

    Chang, R.; Carey, T.; Hargrove, B.

    1996-12-31

    The potential for power plant mercury control under Title III of the 1990 Clean Air Act Amendments generated significant interest in assessing whether cost effective technologies are available for removing the mercury present in fossil-fired power plant flue gas. One promising approach is the direct injection of mercury sorbents such as activated carbon into flue gas. This approach has been shown to be effective for mercury control from municipal waste incinerators. However, tests conducted to date on utility fossil-fired boilers show that it is much more difficult to remove the trace species of mercury present in flue gas. EPRI is conducting research in sorbent mercury control including bench-scale evaluation of mercury sorbent activity and capacity with simulated flue gas, pilot testing under actual flue gas conditions, evaluation of sorbent regeneration and recycle options, and the development of novel sorbents. A theoretical model that predicts maximum mercury removals achievable with sorbent injection under different operating conditions is also being developed. This paper presents initial bench-scale and model results. The results to date show that very fine and large amounts of sorbents are needed for mercury control unless long residence times are available for sorbent-mercury contact. Also, sorbent activity and capacity are highly dependent on flue gas composition, temperature, mercury species, and sorbent properties. 10 refs., 4 figs., 2 tabs.

  8. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

    1985-08-05

    A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

  9. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, John B. L.; Doctor, Richard D.; Wingender, Ronald J.

    1986-01-01

    A method of simultaneously removing SO.sub.2 and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO.sub.2 and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled.

  10. Separation of flue-gas scrubber sludge into marketable products

    SciTech Connect (OSTI)

    Kawatra, S.K.; Eisele, T.C.

    1997-08-31

    A tremendous amount of wet flue-gas desulfurization scrubber sludge (estimated 20 million metric tons per year in the US) is currently being landfilled at a huge cost to utility companies. Scrubber sludge is the solid precipitate produced during desulfurization of flue-gas from burning high sulfur coal. The amount of this sludge is expected to increase in the near future due to ever increasing governmental regulation concerning the amount of sulfur emissions. Scrubber sludge is a fine, grey colored powder that contains calcium sulfite hemihydrate (CaSO{sub 3} {center_dot} 1/2H{sub 2}), calcium sulfate dihydrate (CaSO{sub 4} {center_dot} 2H{sub 2}O), limestone (CaCO{sub 3}), silicates, and iron oxides. This material can continue to be landfilled at a steadily increasing cost, or an alternative for utilizing this material can be developed. This study explores the characteristics of a naturally oxidized wet flue-gas desulfurization scrubber sludge and uses these characteristics to develop alternatives for recycling this material. In order for scrubber sludge to be used as a feed material for various markets, it was necessary to process it to meet the specifications of these markets. A physical separation process was therefore needed to separate the components of this sludge into useful products at a low cost. There are several physical separation techniques available to separate fine particulates. These techniques can be divided into four major groups: magnetic separation, electrostatic separation, physico-chemical separation, and density-based separation. The properties of this material indicated that two methods of separation were feasible: water-only cycloning (density-based separation), and froth flotation (physico-chemical separation). These processes could be used either separately, or in combination. The goal of this study was to reduce the limestone impurity in this scrubber sludge from 5.6% by weight to below 2.0% by weight. The resulting clean calcium

  11. Dry FGD (flue-gas desulfurization) at Argonne National Laboratory

    SciTech Connect (OSTI)

    Livengood, C.D.

    1990-01-01

    Flue-gas desulfurization (FGD) systems based on spray drying are a relatively recent addition to the spectrum of sulfur dioxide (SO{sub 2}) control options available to utility and industrial boiler operators. Such systems appear to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. These advantages have promoted rapid acceptance of dry scrubbers for applications using western low-sulfur coal, but uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. At Argonne National Laboratory (ANL) we have had more than eight years of operating experience with an industrial-scale dry scrubber used with a boiler firing high-sulfur (3.5%) midwestern coal. This paper describes our operating experience with that system and summarizes several research programs that have utilized it. 7 refs., 15 figs., 6 tabs.

  12. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Ya Liang; Tyler Moore; Douglas P. Harrison

    2003-08-01

    This report describes research conducted between April 1, 2003 and June 30, 2003 on the use of dry regenerable sorbents for concentration of carbon dioxide from flue gas. Grade 1 sodium bicarbonate performed similarly to grade 5 sodium bicarbonate in fixed bed testing in that activity improved after the first carbonation cycle and did not decline over the course of 5 cycles. Thermogravimetric analysis indicated that sodium bicarbonate sorbents produced by calcination of sodium bicarbonate are superior to either soda ash or calcined trona. Energy requirements for regeneration of carbon dioxide sorbents (either wet or dry) is of primary importance in establishing the economic feasibility of carbon dioxide capture processes. Recent studies of liquid amine sorption processes were reviewed and found to incorporate conflicting assumptions of energy requirements. Dry sodium based processes have the potential to be less energy intensive and thus less expensive than oxygen inhibited amine based systems. For dry supported sorbents, maximizing the active fraction of the sorbent is of primary importance in developing an economically feasible process.

  13. Separation of Flue-Gas Scrubber Sludge into Marketable Products

    SciTech Connect (OSTI)

    1998-02-28

    The reduction of sulfur oxides from high sulfur coal burning utility companies has resulted in the production of huge quantities of wet flue-gas desulfurization scrubber sludge. A typical 400 MW power station burning a coal containing 3.5% sulfur by weight and using a limestone absorbent would produce approximately 177,000 tons (dry weight) of scrubber sludge per year. This brownish colored, finely divided material contains calcium sulfite (CaSO{sub 3} {center_dot} 1/2 H{sub 2}O), calcium sulfate (CaSO{sub 4} {center_dot} 2H{sub 2}O), unreacted limestone (CaCO{sub 3}), and various other impurities such as fly-ash and iron oxide particles. The physical separation of the components of scrubber sludge would result in the re-use of this material. The primary use would be conversion to a highly pure synthetic gypsum. This technical report concentrates on the effect of baffle configuration on the separation of calcium sulfite/sulfate from limestone. The position of the baffles as they related to the feed inlet, and the quantity of the baffles were examined. A clean calcium sulfite/sulfate (less than 2.0% limestone by weight) was achieved with the combination of water-only cyclone and horizontally baffled column.

  14. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; John DuPoint

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

  15. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Levy, Edward; Bilirgen, Harun; DuPont, John

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

  16. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Joseph Helble; Balaji Krishnakumar

    2006-07-31

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 3 results for the experimental and modeling tasks. Experiments have been completed on the effects of chlorine. However, the experiments with sulfur dioxide and NO, in the presence of water, suggest that the wet-chemistry analysis system, namely the impingers, is possibly giving erroneous results. Future work will investigate this further and determine the role of reactions in the impingers on the oxidation results. The solid-phase experiments have not been completed and it is anticipated that only preliminary work will be accomplished during this study.

  17. Analysis of Halogen-Mercury Reactions in Flue Gas

    SciTech Connect (OSTI)

    Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

    2010-01-01

    Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation

  18. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  19. Separation of Carbon Dioxide from Flue Gas Using Ion Pumping

    SciTech Connect (OSTI)

    Aines, R; Bourcier, W L; Johnson, M R

    2006-04-21

    We are developing a new way of separating carbon dioxide from flue gas based on ionic pumping of carbonate ions dissolved in water. Instead of relying on large temperature or pressure changes to remove carbon dioxide from solvent used to absorb it from flue gas, the ion pump increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, which can be removed from the downstream side of the ion pump as a nearly pure gas. This novel approach to increasing the concentration of the extracted gas permits new approaches to treating flue gas. The slightly basic water used as the extraction medium is impervious to trace acid gases that destroy existing solvents, and no pre-separation is necessary. The simple, robust nature of the process lends itself to small separation plants. Although the energy cost of the ion pump is significant, we anticipate that it will be compete favorably with the current 35% energy penalty of chemical stripping systems in use at power plants. There is the distinct possibility that this simple method could be significantly more efficient than existing processes.

  20. Direct fired absorption machine flue gas recuperator

    DOE Patents [OSTI]

    Reimann, Robert C.; Root, Richard A.

    1985-01-01

    A recuperator which recovers heat from a gas, generally the combustion gas of a direct-fired generator of an absorption machine. The recuperator includes a housing with liquid flowing therethrough, the liquid being in direct contact with the combustion gas for increasing the effectiveness of the heat transfer between the gas and the liquid.

  1. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Thomas Nelson; Raghubir P. Gupta

    2005-01-01

    This report describes research conducted between October 1, 2004 and December 31, 2004 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Two supported sorbents were tested in a bench scale fluidized bed reactor system. The sorbents were prepared by impregnation of sodium carbonate on to an inert support at a commercial catalyst manufacturing facility. One sorbent, tested through five cycles of carbon dioxide sorption in an atmosphere of 3% water vapor and 0.8 to 3% carbon dioxide showed consistent reactivity with sodium carbonate utilization of 7 to 14%. A second, similarly prepared material, showed comparable reactivity in one cycle of testing. Batches of 5 other materials were prepared in laboratory scale quantities (primarily by spray drying). These materials generally have significantly greater surface areas than calcined sodium bicarbonate. Small scale testing showed no significant adsorption of mercury on representative carbon dioxide sorbent materials under expected flue gas conditions.

  2. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

    2006-09-30

    This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

  3. Dry scrubber reduces SO sub 2 in calciner flue gas

    SciTech Connect (OSTI)

    Brown, G.W. ); Roderick, D. ); Nastri, A. )

    1991-02-18

    This paper discusses the installation of a dry sulfur dioxide scrubber for an existing petroleum coke calciner at its Fruita, Colo., refinery. The dry scrubbing process was developed by the power industry to help cope with the acid rain problem. It is the first application of the process in an oil refinery. The process could also remove SO{sub 2} from the flue gas of a fluid catalytic cracker, fluid coker, or other refinery sources.

  4. Thief process for the removal of mercury from flue gas

    DOE Patents [OSTI]

    Pennline, Henry W.; Granite, Evan J.; Freeman, Mark C.; Hargis, Richard A.; O'Dowd, William J.

    2003-02-18

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  5. Flue gas desulfurization gypsum and fly ash

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

  6. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or

  7. New Mexico Associated-Dissolved Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    New Mexico Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves ... Wet After Lease Separation, as of Dec. 31 New Mexico Associated-Dissolved Natural Gas ...

  8. New Mexico Nonassociated Natural Gas, Wet After Lease Separation...

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    Proved Reserves (Billion Cubic Feet) New Mexico Nonassociated Natural Gas, Wet After ... Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New ...

  9. New Mexico Natural Gas, Wet After Lease Separation Proved Reserves...

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    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico Natural ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New Mexico Natural ...

  10. New York Nonassociated Natural Gas, Wet After Lease Separation...

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves (Billion Cubic Feet) New York Nonassociated Natural Gas, Wet After ... Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New ...

  11. ,"West Virginia Associated-Dissolved Natural Gas, Wet After Lease...

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    Data for" ,"Data 1","West Virginia Associated-Dissolved Natural Gas, Wet ... PM" "Back to Contents","Data 1: West Virginia Associated-Dissolved Natural Gas, Wet ...

  12. ,"Louisiana State Offshore Nonassociated Natural Gas, Wet After...

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    Louisiana State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 LA, State Offshore ...

  14. ,"Texas State Offshore Natural Gas, Wet After Lease Separation...

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  15. Texas State Offshore Natural Gas, Wet After Lease Separation...

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    Texas State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 TX, State Offshore ...

  16. ,"Louisiana State Offshore Natural Gas, Wet After Lease Separation...

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  17. ,"Texas State Offshore Nonassociated Natural Gas, Wet After Lease...

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  18. ,"Texas State Offshore Associated-Dissolved Natural Gas, Wet...

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    Data for" ,"Data 1","Texas State Offshore Associated-Dissolved Natural Gas, Wet ... "Back to Contents","Data 1: Texas State Offshore Associated-Dissolved Natural Gas, Wet ...

  19. ,"West Virginia Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  20. ,"Montana Associated-Dissolved Natural Gas, Wet After Lease Separation...

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    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  1. ,"Oklahoma Nonassociated Natural Gas, Wet After Lease Separation...

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    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  2. ,"Kentucky Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  3. ,"Louisiana Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  4. ,"Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  5. ,"Ohio Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  6. ,"Mississippi Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  7. ,"Mississippi Nonassociated Natural Gas, Wet After Lease Separation...

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    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  8. ,"Ohio Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  9. ,"Michigan Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  10. ,"Lower 48 States Natural Gas, Wet After Lease Separation Proved...

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    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 48 States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  11. ,"Virginia Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  12. ,"Wyoming Nonassociated Natural Gas, Wet After Lease Separation...

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    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  13. ,"Kansas Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  14. ,"Pennsylvania Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  15. ,"Montana Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  16. ,"Mississippi Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  17. ,"Texas Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  18. ,"Kansas Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  19. ,"Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  20. ,"Michigan Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  1. ,"Miscellaneous States Natural Gas, Wet After Lease Separation...

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    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  2. ,"Ohio Nonassociated Natural Gas, Wet After Lease Separation...

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  3. ,"Utah Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  4. ,"Kentucky Associated-Dissolved Natural Gas, Wet After Lease...

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    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  5. ,"Montana Nonassociated Natural Gas, Wet After Lease Separation...

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    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  6. ,"Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  7. ,"Utah Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","Utah Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  8. ,"Virginia Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  9. ,"Louisiana - South Onshore Natural Gas, Wet After Lease Separation...

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    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click ... Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  10. ,"Kentucky Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  11. ,"Virginia Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  12. ,"Miscellaneous States Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  13. ,"Wyoming Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  14. ,"Michigan Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  15. ,"Louisiana Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  16. ,"Oklahoma Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  17. ,"Utah Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  18. ,"West Virginia Nonassociated Natural Gas, Wet After Lease Separation...

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    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  19. ,"Texas Nonassociated Natural Gas, Wet After Lease Separation...

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    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  20. ,"Texas Natural Gas, Wet After Lease Separation Proved Reserves...

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  1. ,"Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  2. ,"Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

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  3. ,"Louisiana Nonassociated Natural Gas, Wet After Lease Separation...

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    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  4. ,"U.S. Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  5. New Mexico - East Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico - East Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade ...

  6. New Mexico - West Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    West Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - West Associated-Dissolved Natural Gas, Wet After Lease ...

  7. New Mexico - East Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    East Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - East Nonassociated Natural Gas, Wet After Lease Separation, Proved ...

  8. New Mexico - East Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - East Associated-Dissolved Natural Gas, Wet After Lease Separation, ...

  9. New Mexico - West Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico - West Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade ...

  10. Louisiana - North Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    North Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - North Nonassociated Natural Gas, Wet After Lease Separation, Proved ...

  11. ,"North Dakota Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Dakota Nonassociated Natural Gas, Wet ... 9:32:06 AM" "Back to Contents","Data 1: North Dakota Nonassociated Natural Gas, Wet ...

  12. Louisiana - North Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Louisiana - North Associated-Dissolved Natural Gas, Wet ... Wet After Lease Separation, as of Dec. 31 North Louisiana Associated-Dissolved Natural Gas ...

  13. ,"Louisiana - North Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana - North Nonassociated Natural Gas, Wet After Lease ... "Back to Contents","Data 1: Louisiana - North Nonassociated Natural Gas, Wet After Lease ...

  14. North Dakota Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    North Dakota Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves ... Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 North ...

  15. ,"Louisiana - North Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana - North Natural Gas, Wet After Lease Separation ... "Back to Contents","Data 1: Louisiana - North Natural Gas, Wet After Lease Separation ...

  16. North Dakota Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) North Dakota Natural ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 North Dakota ...

  17. ,"Louisiana - North Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana - North Associated-Dissolved Natural Gas, Wet ... "Back to Contents","Data 1: Louisiana - North Associated-Dissolved Natural Gas, Wet ...

  18. North Dakota Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    North Dakota Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves ... Wet After Lease Separation, as of Dec. 31 North Dakota Associated-Dissolved Natural Gas ...

  19. Louisiana - North Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Louisiana - North Natural Gas, Wet After Lease Separation ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 North Louisiana ...

  20. Transport Membrane Condenser for Water and Energy Recovery from Power Plant Flue Gas

    SciTech Connect (OSTI)

    Dexin Wang

    2012-03-31

    The new waste heat and water recovery technology based on a nanoporous ceramic membrane vapor separation mechanism has been developed for power plant flue gas application. The recovered water vapor and its latent heat from the flue gas can increase the power plant boiler efficiency and reduce water consumption. This report describes the development of the Transport Membrane Condenser (TMC) technology in details for power plant flue gas application. The two-stage TMC design can achieve maximum heat and water recovery based on practical power plant flue gas and cooling water stream conditions. And the report includes: Two-stage TMC water and heat recovery system design based on potential host power plant coal fired flue gas conditions; Membrane performance optimization process based on the flue gas conditions, heat sink conditions, and water and heat transport rate requirement; Pilot-Scale Unit design, fabrication and performance validation test results. Laboratory test results showed the TMC system can exact significant amount of vapor and heat from the flue gases. The recovered water has been tested and proved of good quality, and the impact of SO{sub 2} in the flue gas on the membrane has been evaluated. The TMC pilot-scale system has been field tested with a slip stream of flue gas in a power plant to prove its long term real world operation performance. A TMC scale-up design approach has been investigated and an economic analysis of applying the technology has been performed.

  1. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases

  2. Model for flue-gas desulfurization in a circulating dry scrubber

    SciTech Connect (OSTI)

    Neathery, J.K.

    1996-01-01

    A simple model was developed to describe the absorption of SO{sub 2} in a circulating dry scrubbing (CDS) process, which is a semi dry, lime-based, flue-gas desulfurization (FGD) process that utilizes a circulating fluidized bed arrangement for contacting a sorbent with SO{sub 2}-laden flue gas under coolside conditions. The reaction chemistry is thought to be similar to that of spray-drying absorption. The liquid-phase mass-transfer coefficient was successfully modeled as a function of the sorbent particle spacing on the wetted surfaces. Gas-phase mass-transfer resistances were assumed to be insignificant. Due to the high surface area available in a CDS reactor, the evaporation rate of water from the slurry was modeled as constant-rate drying according to classic spray-dryer theory. However, the falling-rate and diffusion evaporation stages were negligible in CDS since sorbent particle bunching at the surface of the slurry is nonexistent.

  3. Wet powder seal for gas containment

    DOE Patents [OSTI]

    Stang, L.G.

    1979-08-29

    A gas seal is formed by a compact layer of an insoluble powder and liquid filling the fine interstices of that layer. The smaller the particle size of the selected powder, such as sand or talc, the finer will be the interstices or capillary spaces in the layer and the greater will be the resulting sealing capacity, i.e., the gas pressure differential which the wet powder layer can withstand. Such wet powder seal is useful in constructing underground gas reservoirs or storage cavities for nuclear wastes as well as stopping leaks in gas mains buried under ground or situated under water. The sealing capacity of the wet powder seal can be augmented by the hydrostatic head of a liquid body established over the seal.

  4. Wet powder seal for gas containment

    DOE Patents [OSTI]

    Stang, Louis G.

    1982-01-01

    A gas seal is formed by a compact layer of an insoluble powder and liquid filling the fine interstices of that layer. The smaller the particle size of the selected powder, such as sand or talc, the finer will be the interstices or capillary spaces in the layer and the greater will be the resulting sealing capacity, i.e., the gas pressure differential which the wet powder layer can withstand. Such wet powder seal is useful in constructing underground gas reservoirs or storage cavities for nuclear wastes as well as stopping leaks in gas mains buried under ground or situated under water. The sealing capacity of the wet powder seal can be augmented by the hydrostatic head of a liquid body established over the seal.

  5. State-of-the-art review of materials-related problems in flue gas desulfurization systems

    SciTech Connect (OSTI)

    Maiya, P. S.

    1980-10-01

    This report characterizes the chemical and mechanical environments to which the structural components used in flue-gas desulfurization (FGD) are exposed. It summarizes the necessary background information pertinent to various FGD processes currently in use, with particular emphasis on lime/limestone scrubbing technology, so that the materials problems and processing variables encountered in FGD systems can be better defined and appreciated. The report also describes the materials currently used and their performance to date in existing wet scrubbers. There is little doubt that with more extensive use of coal and flue-gas scrubbers by utilities and other segments of private industry, a better understanding of the material failure mechanisms, performance limitations, and potential problem areas is required for the design of more reliable and cost-effective FGD systems. To meet the above objectives, a materials evaluation program is proposed. The important experimental variables and the number of tests required to evaluate a given material are discussed. 55 references, 9 figures, 6 tables.

  6. New York Natural Gas, Wet After Lease Separation Proved Reserves...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New York Natural Gas, ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New York Natural ...

  7. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    SciTech Connect (OSTI)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co

  8. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson

    2004-07-01

    This report describes research conducted between April 1, 2004 and June 30, 2004 on the preparation and use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Support materials and supported sorbents were prepared by spray drying. Sorbents consisting of 20 to 50% sodium carbonate on a ceramic support were prepared by spray drying in batches of approximately 300 grams. The supported sorbents exhibited greater carbon dioxide capture rates than unsupported calcined sodium bicarbonate in laboratory tests. Preliminary process design and cost estimation for a retrofit application suggested that costs of a dry regenerable sodium carbonate-based process could be lower than those of a monoethanolamine absorption system. In both cases, the greatest part of the process costs come from power plant output reductions due to parasitic consumption of steam for recovery of carbon dioxide from the capture medium.

  9. Investigation of a mercury speciation technique for flue gas desulfurization materials

    SciTech Connect (OSTI)

    Lee, J.Y.; Cho K.; Cheng L.; Keener, T.C.; Jegadeesan G.; Al-Abed, S.R.

    2009-08-15

    Most of the synthetic gypsum generated from wet flue gas desulfurization (FGD) scrubbers is currently being used for wallboard production. Because oxidized mercury is readily captured by the wet FGD scrubber, and coal-fired power plants equipped with wet scrubbers desire to benefit from the partial mercury control that these systems provide, some mercury is likely to be bound in with the FGD gypsum and wallboard. In this study, the feasibility of identifying mercury species in the FGD gypsum and wallboard samples was investigated using a large sample size thermal desorption method and samples from power plants in Pennsylvania. Potential candidates of pure mercury standards including mercuric chloride, mercurous chloride, mercury oxide, mercury sulfide, and mercuric sulfate were analyzed to compare their results with those obtained from FGD gypsum and dry wallboard samples. Although any of the thermal evolutionary curves obtained from these pure mercury standards did not exactly match with those of the FGD gypsum and wallboard samples, it was identified that Hg{sub 2}Cl{sub 2} and HgCl{sub 2} could be candidates. An additional chlorine analysis from the gypsum and wallboard samples indicated that the chlorine concentrations were approximately 2 orders of magnitude higher than the mercury concentrations, suggesting possible chlorine association with mercury. 21 refs., 5 figs., 3 tabs.

  10. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  11. Hybrid heat exchange for the compression capture of CO2 from recirculated flue gas

    SciTech Connect (OSTI)

    Oryshchyn, Danylo B.; Ochs, Thomas L.; Summers, Cathy A.

    2004-01-01

    An approach proposed for removal of CO2 from flue gas cools and compresses a portion of a recirculated flue-gas stream, condensing its volatile materials for capture. Recirculating the flue gas concentrates SOx, H2O and CO2 while dramatically reducing N2 and NOx, enabling this approach, which uses readily available industrial components. A hybrid system of indirect and direct-contact heat exchange performs heat and mass transfer for pollutant removal and energy recovery. Computer modeling and experimentation combine to investigate the thermodynamics, heat and mass transfer, chemistry and engineering design of this integrated pollutant removal (IPR) system.

  12. Multi-component removal in flue gas by aqua ammonia

    DOE Patents [OSTI]

    Yeh, James T.; Pennline, Henry W.

    2007-08-14

    A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

  13. Biomimetic Membrane for CO2 Capture from Flue Gas

    SciTech Connect (OSTI)

    Michael C. Trachtenberg

    2007-05-31

    These Phase III experiments successfully addressed several issues needed to characterize a permeator system for application to a pulverized coal (PC) burning furnace/boiler assuming typical post-combustion cleanup devices in place. We completed key laboratory stage optimization and modeling efforts needed to move towards larger scale testing. The SOPO addressed six areas. Task 1--Post-Combustion Particle Cleanup--The first object was to determine if the Carbozyme permeator performance was likely to be reduced by particles (materials) in the flue gas stream that would either obstruct the mouth of the hollow fibers (HF) or stick to the HF bore wall surface. The second, based on the Acceptance Standards (see below), was to determine whether it would be preferable to clean the inlet gas stream (removing acid gases and particulates) or to develop methods to clean the Carbozyme permeator if performance declined due to HF block. We concluded that condensation of particle and particulate emissions, in the heat exchanger, could result in the formation of very sticky sulfate aerosols with a strong likelihood of obtruding the HF. These must be managed carefully and minimized to near-zero status before entering the permeator inlet stream. More extensive post-combustion cleanup is expected to be a necessary expense, independent of CO{sub 2} capture technology This finding is in agreement with views now emerging in the literature for a variety of CO{sub 2} capture methods. Task 2--Water Condensation--The key goal was to monitor and control temperature distributions within the permeator and between the permeator and its surroundings to determine whether water condensation in the pores or the HF bore would block flow, decreasing performance. A heat transfer fluid and delivery system were developed and employed. The result was near isothermal performance that avoided all instances of flow block. Direct thermocouple measurements provided the basis for developing a heat transfer

  14. Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-09-27

    The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

  15. ,"New Mexico - West Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico - West Natural Gas, Wet After Lease ... 8:56:27 AM" "Back to Contents","Data 1: New Mexico - West Natural Gas, Wet After Lease ...

  16. ,"New Mexico Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico Nonassociated Natural Gas, Wet After ... 8:57:57 AM" "Back to Contents","Data 1: New Mexico Nonassociated Natural Gas, Wet After ...

  17. ,"New York Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New York Nonassociated Natural Gas, Wet After ... 8:57:57 AM" "Back to Contents","Data 1: New York Nonassociated Natural Gas, Wet After ...

  18. ,"New York Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New York Natural Gas, Wet After Lease ... 8:56:32 AM" "Back to Contents","Data 1: New York Natural Gas, Wet After Lease ...

  19. ,"New York Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New York Associated-Dissolved Natural Gas, Wet ... 8:59:18 AM" "Back to Contents","Data 1: New York Associated-Dissolved Natural Gas, Wet ...

  20. ,"New Mexico Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico Natural Gas, Wet After Lease ... 8:56:31 AM" "Back to Contents","Data 1: New Mexico Natural Gas, Wet After Lease ...

  1. ,"New Mexico - East Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico - East Natural Gas, Wet After Lease ... 8:56:26 AM" "Back to Contents","Data 1: New Mexico - East Natural Gas, Wet After Lease ...

  2. ,"U.S. Federal Offshore Nonassociated Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Federal Offshore Nonassociated Natural Gas, Wet After ... "Back to Contents","Data 1: U.S. Federal Offshore Nonassociated Natural Gas, Wet After ...

  3. ,"Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet ... AM" "Back to Contents","Data 1: Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet ...

  4. ,"North Dakota Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Dakota Natural Gas, Wet After Lease ... 9:30:28 AM" "Back to Contents","Data 1: North Dakota Natural Gas, Wet After Lease ...

  5. ,"Texas - RRC District 6 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 6 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 6 Natural Gas, Wet After ...

  6. ,"Texas - RRC District 5 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 5 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 5 Natural Gas, Wet After ...

  7. ,"Texas - RRC District 2 Onshore Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 2 Onshore Natural Gas, Wet ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 2 Onshore Natural Gas, Wet ...

  8. ,"Texas - RRC District 10 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 10 Natural Gas, Wet After ... 7:19:08 AM" "Back to Contents","Data 1: Texas - RRC District 10 Natural Gas, Wet After ...

  9. ,"Texas - RRC District 4 Onshore Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 4 Onshore Natural Gas, Wet ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 4 Onshore Natural Gas, Wet ...

  10. ,"Texas - RRC District 8 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 8 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 8 Natural Gas, Wet After ...

  11. ,"Texas - RRC District 9 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 9 Natural Gas, Wet After ... 7:19:08 AM" "Back to Contents","Data 1: Texas - RRC District 9 Natural Gas, Wet After ...

  12. ,"Texas - RRC District 1 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 1 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 1 Natural Gas, Wet After ...

  13. ,"Texas - RRC District 3 Onshore Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 3 Onshore Natural Gas, Wet ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 3 Onshore Natural Gas, Wet ...

  14. Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic Framework mmen-Mg2(dobpdc) Previous Next List Thomas M. McDonald, Woo Ram Lee, Jarad A. ...

  15. Catalysts for Oxidation of Mercury in Flue Gas - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Catalysts for Oxidation of Mercury in Flue Gas National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 7776780.pdf (365 KB) Technology Marketing Summary Disclosed in this patent are catalysts for the oxidation of elemental mercury in flue gas. These novel catalysts include iridium (Ir), platinum/iridium (Pt/Ir), and Thief carbons. The catalyst materials will adsorb

  16. Method for removing heavy metal and nitrogen oxides from flue gas, device for removing heavy metal and nitrogen oxides from flue gas

    SciTech Connect (OSTI)

    Huang, Hann-Sheng; Livengood, Charles David

    1997-12-01

    A method for the simultaneous removal of oxides and heavy metals from a fluid is provided comprising combining the fluid with compounds containing alkali and sulfur to create a mixture; spray drying the mixture to create a vapor phase and a solid phase; and isolating the vapor phase from the solid phase. A device is also provided comprising a means for spray-drying flue gas with alkali-sulfide containing liquor at a temperature sufficient to cause the flue gas to react with the compounds so as to create a gaseous fraction and a solid fraction and a means for directing the gaseous fraction to a fabric filter.

  17. Texas State Offshore Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved ... Separation, as of Dec. 31 TX, State Offshore Nonassociated Natural Gas Proved ...

  18. Texas State Offshore Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved ... Separation, as of Dec. 31 TX, State Offshore Associated-Dissolved Natural Gas Proved ...

  19. Louisiana State Offshore Nonassociated Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Louisiana State Offshore Nonassociated Natural Gas, Wet After ... Separation, as of Dec. 31 LA, State Offshore Nonassociated Natural Gas Proved ...

  20. Louisiana State Offshore Associated-Dissolved Natural Gas, Wet...

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Louisiana State Offshore Associated-Dissolved Natural Gas, Wet ... Separation, as of Dec. 31 LA, State Offshore Associated-Dissolved Natural Gas Proved ...

  1. Economic assessment of advanced flue gas desulfurization processes. Final report

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final reprot, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluations, was completed in October 1980. A slightly modified and condensed version of that report appears as appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  2. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  3. CO₂ Capture Membrane Process for Power Plant Flue Gas

    SciTech Connect (OSTI)

    Toy, Lora; Kataria, Atish; Gupta, Raghubir

    2012-04-01

    Because the fleet of coal-fired power plants is of such importance to the nation's energy production while also being the single largest emitter of CO₂, the development of retrofit, post-combustion CO₂ capture technologies for existing and new, upcoming coal power plants will allow coal to remain a major component of the U.S. energy mix while mitigating global warming. Post-combustion carbon capture technologies are an attractive option for coal-fired power plants as they do not require modification of major power-plant infrastructures, such as fuel processing, boiler, and steam-turbine subsystems. In this project, the overall objective was to develop an advanced, hollow-fiber, polymeric membrane process that could be cost-effectively retrofitted into current pulverized coal-fired power plants to capture at least 90% of the CO₂ from plant flue gas with 95% captured CO₂ purity. The approach for this project tackled the technology development on three different fronts in parallel: membrane materials R&D, hollow-fiber membrane module development, and process development and engineering. The project team consisted of RTI (prime) and two industrial partners, Arkema, Inc. and Generon IGS, Inc. Two CO₂-selective membrane polymer platforms were targeted for development in this project. For the near term, a next-generation, high-flux polycarbonate membrane platform was spun into hollow-fiber membranes that were fabricated into both lab-scale and larger prototype (~2,200 ft²) membrane modules. For the long term, a new fluoropolymer membrane platform based on poly(vinylidene fluoride) [PVDF] chemistry was developed using a copolymer approach as improved capture membrane materials with superior chemical resistance to flue-gas contaminants (moisture, SO₂, NOx, etc.). Specific objectives were: - Development of new, highly chemically resistant, fluorinated polymers as membrane materials with minimum selectivity of 30 for CO₂ over N₂ and CO₂ permeance

  4. Fluid/particle separation and coal cleaning: Progress, potential advances, and their effects on FGD (flue-gas desulfurization)

    SciTech Connect (OSTI)

    Livengood, C.D.; Doctor, R.D.

    1989-01-01

    Argonne National Laboratory (ANL) has been investigating several approaches to SO{sub 2} and NO{sub x} control that could play significant roles in future emission-control strategies. These techniques include greater application of an existing technology, physical coal cleaning (PCC), as a precombustion complement to FGD, and the combined removal of NO{sub x} and SO{sub 2} in flue-gas cleanup (FGC) systems based on spray drying (a wet/dry process) or in-duct injection of dry sorbents. This paper discusses the results of some of that research with particular attention to the beneficial role of fabric filtration in the dry and wet/dry FGC processes. 7 refs., 5 figs.

  5. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature

  6. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    SciTech Connect (OSTI)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by

  7. In the field. Pilot project uses innovative process to capture CO{sub 2} from flue gas

    SciTech Connect (OSTI)

    2008-04-01

    A pilot project at We Energies' Pleasant Prairie Power Plant uses chilled ammonia to capture CO{sub 2} from flue gas. 3 photos.

  8. Critical review of mercury chemistry in flue gas.

    SciTech Connect (OSTI)

    Mendelsohn, M. H.; Livengood, C. D.

    2006-11-27

    Mercury (Hg) and its compounds have long been recognized as potentially hazardous to human health and the environment. Many man-made sources of mercury have been reduced in recent years through process changes and control measures. However, emissions of mercury from coal-fired power plants, while exceedingly dilute by the usual pollution standards, still constitute a major source when considered in the aggregate. Concerns over those emissions and the prospect of impending emissions regulations have led to a wide range of research projects dealing with the measurement and control of mercury in flue gas. This work has made considerable progress in improving the understanding of mercury emissions and their behavior, but inconsistencies and unexpected results have also shown that a better understanding of mercury chemistry is needed. To develop a more complete understanding of where additional research on mercury chemistry is needed, the U.S. Department of Energy (DOE) asked Argonne National Laboratory (Argonne) to conduct a critical review of the available information as reported in the technical literature. The objectives were to summarize the current state of the art of chemistry knowledge, identify significant knowledge gaps, and recommend future research to resolve those gaps. An initial evaluation of potential review topics indicated that the scope of the review would need to be limited and focused on the most important topics relative to mercury control. To aid in this process, Argonne developed a brief survey that was circulated to researchers in the field who could help identify and prioritize the many aspects of the problem. The results of the survey were then used to design and guide a highly focused literature search that identified key papers for analysis. Each paper was reviewed, summarized, and evaluated for the relevance and quality of the information presented. The results of that work provided the basis for conclusions regarding the state of knowledge

  9. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    SciTech Connect (OSTI)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates Units 1 and 2 to evaluate

  10. New Mexico Natural Gas Wet After Lease Separation, Reserves in...

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) New Mexico Natural Gas Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion...

  11. ,"New Mexico Nonassociated Natural Gas Proved Reserves, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation",10,"Annual",201...

  12. Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet...

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves from Greater than 200 Meters Deep (Percent) Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet After Lease Separation, Proved Reserves from Greater than...

  13. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Less than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production from Less than 200 Meters Deep (Billion Cubic...

  14. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Greater than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production from Greater than 200 Meters Deep (Billion...

  15. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    Less than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves from Less than 200 Meters Deep (Billion...

  16. Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet...

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  17. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    Greater than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves from Greater than 200 Meters Deep...

  18. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  19. Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet ... as of Dec. 31 Federal Offshore, Gulf of Mexico, Texas Natural Gas Reserves Summary as of ...

  20. Carbon dioxide absorber and regeneration assemblies useful for power plant flue gas

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2012-11-06

    Disclosed are apparatus and method to treat large amounts of flue gas from a pulverized coal combustion power plant. The flue gas is contacted with solid sorbents to selectively absorb CO.sub.2, which is then released as a nearly pure CO.sub.2 gas stream upon regeneration at higher temperature. The method is capable of handling the necessary sorbent circulation rates of tens of millions of lbs/hr to separate CO.sub.2 from a power plant's flue gas stream. Because pressurizing large amounts of flue gas is cost prohibitive, the method of this invention minimizes the overall pressure drop in the absorption section to less than 25 inches of water column. The internal circulation of sorbent within the absorber assembly in the proposed method not only minimizes temperature increases in the absorber to less than 25.degree. F., but also increases the CO.sub.2 concentration in the sorbent to near saturation levels. Saturating the sorbent with CO.sub.2 in the absorber section minimizes the heat energy needed for sorbent regeneration. The commercial embodiments of the proposed method can be optimized for sorbents with slower or faster absorption kinetics, low or high heat release rates, low or high saturation capacities and slower or faster regeneration kinetics.

  1. The Clean Coal Technology Program 100 MWe demonstration of gas suspension absorption for flue gas desulfurization

    SciTech Connect (OSTI)

    Hsu, F.E.; Hedenhag, J.G.; Marchant, S.K.; Pukanic, G.W.; Norwood, V.M.; Burnett, T.A.

    1997-12-31

    AirPol Inc., with the cooperation of the Tennessee Valley Authority (TVA) under a Cooperative Agreement with the United States Department of Energy, installed and tested a 10 MWe Gas Suspension Absorption (GSA) Demonstration system at TVA`s Shawnee Fossil Plant near Paducah, Kentucky. This low-cost retrofit project demonstrated that the GSA system can remove more than 90% of the sulfur dioxide from high-sulfur coal-fired flue gas, while achieving a relatively high utilization of reagent lime. This paper presents a detailed technical description of the Clean Coal Technology demonstration project. Test results and data analysis from the preliminary testing, factorial tests, air toxics texts, 28-day continuous demonstration run of GSA/electrostatic precipitator (ESP), and 14-day continuous demonstration run of GSA/pulse jet baghouse (PJBH) are also discussed within this paper.

  2. Novel Application of Carbonate Fuel Cell for Capturing Carbon Dioxide from Flue Gas Streams

    SciTech Connect (OSTI)

    Jolly, Stephen; Ghezel-Ayagh, Hossein; Willman, Carl; Patel, Dilip; DiNitto, M.; Marina, Olga A.; Pederson, Larry R.; Steen, William A.

    2015-09-30

    To address concerns about climate change resulting from emission of CO2 by coal-fueled power plants, FuelCell Energy, Inc. has developed the Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept. The CEPACS system utilizes Electrochemical Membrane (ECM) technology derived from the Company’s Direct FuelCell® products. The system separates the CO2 from the flue gas of other plants and produces electric power using a supplementary fuel. FCE is currently evaluating the use of ECM to cost effectively separate CO2 from the flue gas of Pulverized Coal (PC) power plants under a U.S. Department of Energy contract. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from the flue gas with no more than 35% increase in the cost of electricity. The project activities include: 1) laboratory scale operational and performance tests of a membrane assembly, 2) performance tests of the membrane to evaluate the effects of impurities present in the coal plant flue gas, in collaboration with Pacific Northwest National Laboratory, 3) techno-economic analysis for an ECM-based CO2 capture system applied to a 550 MW existing PC plant, in partnership with URS Corporation, and 4) bench scale (11.7 m2 area) testing of an ECM-based CO2 separation and purification system.

  3. High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents

    SciTech Connect (OSTI)

    Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

    2002-09-20

    The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

  4. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard

    2003-12-01

    ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

  5. Nebraska Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Nebraska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) No Data Available For This Series - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Nonassociated Natural Gas Proved Reserves,

  6. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    SciTech Connect (OSTI)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  7. ,"Crude Oil and Lease Condensate","Wet Natural Gas"

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    U.S. proved reserves, and reserves changes, 2013-2014" ,"Crude Oil and Lease Condensate","Wet Natural Gas" ,"billion barrels","trillion cubic feet" "U.S. proved reserves at...

  8. New Mexico - West Nonassociated Natural Gas, Wet After Lease...

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    New Mexico - West Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 ...

  9. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  10. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  11. New York Associated-Dissolved Natural Gas, Wet After Lease Separation...

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    New York Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves ... Wet After Lease Separation, as of Dec. 31 New York Associated-Dissolved Natural Gas ...

  12. ,"U.S. Nonassociated Natural Gas Proved Reserves, Wet After Lease...

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    Gas Proved Reserves, Wet After Lease Separation" ,"Click worksheet name or tab at bottom ... Gas Proved Reserves, Wet After Lease Separation",10,"Annual",2014,"06301979" ...

  13. ,"U.S. Natural Gas, Wet After Lease Separation Proved Reserves...

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    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","U.S. Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  14. Nebraska Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) No Data Available For This Series - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Associated-Dissolved Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 Nebraska Associated-Dissolved Natural

  15. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2014-06-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

  16. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  17. The use of flue gas for the growth of microalgal biomass

    SciTech Connect (OSTI)

    Zeiler, K.G.; Kadam, K.L.; Heacox, D.A.

    1995-11-01

    Capture and utilization of carbon dioxide (CO{sub 2}) by microalgae is a promising technology to help reduce emissions from fossil fuel-fired power plants. Microalgae are of particular interest because of their rapid growth rates and tolerance to varying environmental conditions. Laboratory work is directed toward investigating the effects of simulated flue gas on microalgae, while engineering studies have focused on the economics of the technology. One strain of a green algae, Monoraphidium minutum, has shown excellent tolerance and growth when exposed to simulated flue gas which meets the requirements of the 1990 Clean Air Act Amendments (1990 CAAA). Biomass concentrations of {similar_to}2g/L have been measured in batch culture. Several other microalgae have also shown tolerance to simulated flue gas; however, the growth of these strains is not equivalent to that observed for M. minutum. Coupling the production of biodiesel or other microalgae-derived commodity chemicals with the use of flue gas carbon dioxide is potentially a zero-cost method of reducing the amount of carbon dioxide contributed to the atmosphere by fossil fuel-fired power plants. We have identified two major biological performance parameters which can provide sufficient improvement in this technology to render it cost-competitive with other existing CO{sub x} mitigation technologies. These are algal growth rate and lipid content. An updated economic analysis shows that growth rate is the more important of the two, and should be the focus of near term research activities. The long term goal of achieving zero cost will require other, non-biological, improvements in the process.

  18. pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (801 KB) Technology Marketing SummaryIncreased recycling of power plant cooling water calls for low-cost means of preventing the formation of calcium carbonate and silicate scale. Hardness (Ca and Mg) and silica are two of

  19. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  20. Influence factors on the flue gas desulfurization in the circulating fluidized bed reactor

    SciTech Connect (OSTI)

    Gao, J.; Tang, D.; Liu, H.; Suzuki, Yoshizo; Kito, Nobo

    1997-12-31

    This paper describes a dry SO{sub 2} removal method -- the absorbent (Ca(OH){sub 2}) was injected into the Circulating Fluidized Bed (CFB) reactor at the coolside of the duct to abate SO{sub 2} in the flue gas -- with the potential to significantly enhance desulfurization performance over that of existing dry/semi-dry Flue Gas Desulfurization (FGD) technology such as Spray Drying. A patent for coolside Flue Gas Desulfurization in the Circulating Fluidized Bed reactor (CFB-FGD) was approved by the China Patent Bureau in September of 1995 and the additional laboratory experiment was carried out in an electrically heated bench scale quartz circulating fluidized bed reactor of 2350mm in height and 23mm in diameter in January, 1996. The influences of steam, ratio of calcium and sulfur, reactor temperature, and absorbent utilization efficiency were invested. The results show that: (1) Water steam plays a key role in the reaction of Ca(OH){sub 2} and SO{sub 2} in the CFB reactor; (2) There is a positive effect of Ca/S on SO{sub 2} removal efficiency; (3) The temperature is an another key factor for SO{sub 2} removal efficiency for the CFB-FGD process; (4) The absorbent can be enhanced in the CFB reactor; (5) The CFB reactor is better than the dry/semi-dry FDG technology. SO{sub 2} removal efficiency can be as high as 84.8%.

  1. Recovery of Water from Boiler Flue Gas Using Condensing Heat...

    Office of Scientific and Technical Information (OSTI)

    DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water ...

  2. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the

  3. Hot waste-to-energy flue gas treatment using an integrated fluidised bed reactor

    SciTech Connect (OSTI)

    Bianchini, A.; Pellegrini, M.; Saccani, C.

    2009-04-15

    This paper describes an innovative process to increase superheated steam temperatures in waste-to-energy (WTE) plants. This solution is mainly characterised by a fluidised bed reactor in which hot flue gas is treated both chemically and mechanically. This approach, together with gas recirculation, increases the energy conversion efficiency, and raises the superheated steam temperature without decreasing the useful life of the superheater. This paper presents new experimental data obtained from the test facility installed at the Hera S.p.A. WTE plant in Forli, Italy; discusses changes that can be implemented to increase the duration of experimental testing; offers suggestions for the design of an industrial solution.

  4. Catalysts for oxidation of mercury in flue gas

    DOE Patents [OSTI]

    Granite, Evan J.; Pennline, Henry W.

    2010-08-17

    Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

  5. Testing in flue gas cleaning systems of waste incineration plants

    SciTech Connect (OSTI)

    Wallen, B.; Bergquist, A.; Nordstroem, J.

    1995-07-01

    Test racks containing creviced, welded coupons of stainless steels (SS), nickel-based alloys, and titanium were exposed in gas cleaning systems in municipal waste incineration plants. The environments in the cleaning systems were very corrosive. The best corrosion resistance was shown by the superaustenitic SS UNS S32654 and the nickel-based alloys UNS N10276 (C-276) and N06022 (C-22). Titanium performed poorly and was attacked by excessive uniform corrosion.

  6. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no

  7. Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 13 1980's 23 25 1990's 25 23 30 46 56 44 38 30 28 27 2000's 29 26 31 32 32 29 18 20 19 29 2010's 38 48 100 46 141 - = No Data Reported; -- = Not Applicable; NA = Not

  8. Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 166 1980's 194 184 174 194 189 157 150 145 157 145 1990's 67 136 133 93 85 104 89 56 38 41 2000's 39 30 38 37 40 46 44 37 12 20 2010's 29 46 82 135 189 - = No Data

  9. California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 307 1980's 265 265 325 344 256 254 261 243 220 233 1990's 228 220 196 135 145 109 120 129 116 233 2000's 244 185 197

  10. California - Coastal Region Onshore Natural Gas, Wet After Lease Separation

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 395 1980's 330 325 384 405 284 277 275 255 232 238 1990's 232 231 215 201 205 163 168 176 118 233 2000's 244 185 197 174 196 277 214 212 151 169 2010's 180 173 305 284 277 - = No Data

  11. California - Coastal Region Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 88 1980's 65 60 59 61 28 23 14 12 12 5 1990's 4 11 19 66 60 54 48 47 2 0 2000's 0 0 0 1 8 8 6 1 1 1 2010's 2 1 2 2 8 - = No Data

  12. California - Los Angeles Basin Onshore Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - Los Angeles Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 176 1980's 207 163 104 115 163 188 149 155 158 141 1990's 110 120 103 108 108 115 112 146 154 174 2000's 204 195 218 196 184 186 161 154 81 91 2010's 92 102 98 90 84 - =

  13. California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1 1980's 0 1 1 1 1 3 0 0 0 0 1990's 0 0 3 0 0 0 0 3 1 0 2000's 1 1 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not

  14. California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,784 1980's 1,721 1,566 1,593 1,556 1,538 1,642 1,398 1,196 1,086 972 1990's 901 885 773 749 744 679 560 518 445 336 2000's 748 836

  15. California Federal Offshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 249 1980's 307 1,110 1,249 1,312 1,252 1990's 1,229 995 987 976 1,077 1,195 1,151 498 437 488 2000's 500 490 459 456 412 776 756

  16. California Federal Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 73 1980's 107 227 217 258 267 1990's 240 179 149 147 110 94 115 58 52 48 2000's 76 50 56 55 47 49 55 53 3 9 2010's 3 0 0 0 0 - = No Data Reported; -- =

  17. California Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,881 1980's 1,792 1,424 1,230 1,120 1,006 1990's 911 901 799 817 808 736 610 570 453 355 2000's 754 842 796 759 767 799 780 686 621 612 2010's 503 510 272 247 273 - = No Data Reported;

  18. California State Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 234 1980's 166 256 254 243 235 1990's 194 60 63 65 63 59 49 56 44 77 2000's 91 85 91 83 87 90 90 83 57 57 2010's 66 82 66 75 76 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  19. California State Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8 1980's 6 12 22 22 29 1990's 6 5 4 2 4 3 2 2 5 19 2000's 5 5 6 7 2 1 5 4 3 4 2010's 3 3 1 0 0 - = No Data Reported; -- = Not Applicable; NA = Not

  20. Florida Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Florida Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 108 1980's 122 99 86 64 90 81 69 62 69 57 1990's 53 45 55 59 117 110 119 112 106 100 2000's 93 96 102 92 88 87 50 110 1 7 2010's 30 2 0 1 0 - = No Data Reported; -- =

  1. Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 108 1980's 122 99 86 64 90 81 69 62 69 57 1990's 53 45 55 59 117 110 119 112 106 100 2000's 93 96 102 92 88 87 50 110 1 7 2010's 56 6 16 15 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  2. Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 26 4 16 14 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  3. Kentucky Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kentucky Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2 1980's 11 14 12 19 17 13 17 19 19 22 1990's 8 10 8 6 47 27 24 26 20 29 2000's 27 25 25 25 19 30 36 34 34 32 2010's 111 98 93 44 49 - = No Data Reported; -- = Not

  4. Texas - RRC District 9 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 9 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 633 1980's 502 796 965 845 786 753 761 717 686 617 1990's 703 674 613 636 715 730 749 785 665 1,180 2000's 1,645 2,428 3,070 3,514 4,445 4,608 6,660 7,846

  5. Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,038 1980's 1,374 1,228 1,060 959 867 710 691 691 616 581 1990's 573 572 624 502 611 879 824 850 794 713 2000's 652 488 561 450 362 384 347 365 223 362 2010's 334 318

  6. Michigan Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Michigan Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 733 1980's 883 758 719 824 774 689 577 569 491 432 1990's 408 437 352 328 357 326 347 281 228 227 2000's 214 159 214 269 193 153 192 179 148 77 2010's 72 77 94 125 108

  7. Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14 1980's 34 12 27 31 14 25 41 13 28 39 1990's 22 14 11 9 11 32 28 31 17 54 2000's 19 19 20 14 12 14 19 15 9 78 2010's 10 104 7 19 18 - = No

  8. Miscellaneous States Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Miscellaneous States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 156 1980's 180 193 74 81 77 77 136 66 84 87 1990's 72 76 93 96 67 69 68 44 39 67 2000's 42 83 100 134 110 132 139 241 272 349 2010's 363 393 233 188 185 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  9. Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 142 1980's 146 181 47 50 63 52 95 53 56 48 1990's 50 62 82 87 56 37 40 13 22 13 2000's 23 64 80 120 98 118 120 226 263 271 2010's 353 270 219 169 167 - = No Data

  10. Mississippi Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Mississippi Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 67 1980's 73 66 74 80 114 105 66 61 71 105 1990's 126 108 85 53 43 27 47 51 47 31 2000's 35 26 33 27 20 20 21 30 45 38 2010's 36 62 62 43 58 - = No Data Reported; --

  11. Montana Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Montana Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 51 1980's 122 89 81 108 77 91 98 97 101 68 1990's 86 66 61 53 55 53 51 42 52 67 2000's 70 85 94 112 130 161 195 219 197 312 2010's 302 270 289 304 325 - = No Data

  12. Montana Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Montana Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 786 1980's 1,186 1,247 789 813 748 793 725 704 733 821 1990's 834 782 814 631 672 739 755 727 737 784 2000's 822 822 820 956 872 837 874 848 817 681 2010's 657 522 327 286 361 - = No Data

  13. Ohio Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Ohio Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 432 1980's 282 165 158 396 364 395 522 477 749 686 1990's 844 805 780 763 780 699 715 594 548 777 2000's 717 631 772 823 767 714 801 926 886 799 2010's 742 684 1,012 2,887 6,985 - = No Data Reported; --

  14. Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 9 1980's 11 14 14 21 78 67 22 21 8 19 1990's 23 20 10 8 9 36 47 92 79 96 2000's 157 168 137 164 125 134 151 130 127 133 2010's 144 134 125 269 299 - = No Data

  15. ,"U.S. Natural Gas Proved Reserves, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves, Wet After Lease Separation" ,"Click worksheet name or tab at bottom for ... Gas Proved Reserves, Wet After Lease Separation",10,"Annual",2014,"06301979" ...

  16. Improved Recovery from Gulf of Mexico Reservoirs, Volume 4, Comparison of Methane, Nitrogen and Flue Gas for Attic Oil. February 14, 1995 - October 13, 1996. Final Report

    SciTech Connect (OSTI)

    Wolcott, Joanne; Shayegi, Sara

    1997-01-13

    Gas injection for attic oil recovery was modeled in vertical sandpacks to compare the process performance characteristics of three gases, namely methane, nitrogen and flue gas. All of the gases tested recovered the same amount of oil over two cycles of gas injection. Nitrogen and flue gas recovered oil more rapidly than methane because a large portion of the methane slug dissolved in the oil phase and less free gas was available for oil displacement. The total gas utilization for two cycles of gas injection was somewhat better for nitrogen as compared to methane and flue gas. The lower nitrogen utilization was ascribed to the lower compressibility of nitrogen.

  17. Compression stripping of flue gas with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; O'Connor, William K.

    2005-05-31

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SO.sub.X and NO.sub.X and CO.sub.2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO.sub.2, SO.sub.2, and H.sub.2 O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  18. Compression Stripping of Flue Gas with Energy Recovery

    SciTech Connect (OSTI)

    Ochs, Thomas L.; O'Connor, William K.

    2005-05-31

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SOX and NOX and CO2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO2, SO2, and H2O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  19. Corrosion testing in the flue gas cleaning and condensation systems in Swedish waste incineration plants

    SciTech Connect (OSTI)

    Wallen, B.; Bergqvist, A.; Nordstroem, J.

    1994-12-31

    Test racks containing creviced, welded coupons of stainless steels, nickel base alloys and titanium have been exposed in various parts of the gas cleaning systems in three municipal waste incineration plants. The flue gases were rich in hydrogen halides and the environments in the cleaning systems were very corrosive causing mainly crevice and pitting corrosion. The best corrosion resistance was shown by the superaustenitic stainless steel S32654 and the nickel base alloys N10276 and N06022. Titanium performed badly and was attacked by excessive uniform corrosion.

  20. An experimental study of flue gas desulfurization in a pilot spray dryer

    SciTech Connect (OSTI)

    Ollero, P.; Salvador, L.; Canadas, L.

    1997-12-31

    More than 45 experimental tests have been conducted on a 10,000 Nm{sup 3}/h spray-drying desulfurization pilot plant. The effects of SO{sub 2} and fly ash concentration, Ca/S ratio, approach to saturation temperature, unit load changes, and the utilization of seawater as make-up water on both spray dryer behavior and treated flue gas properties were analyzed. This experimental study allows us to reach some conclusions about how to achieve optimum operating conditions and to assess the impact of spray drying on a downstream ESP. 5 refs., 14 figs., 2 tabs.

  1. Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks

    SciTech Connect (OSTI)

    Lesch, David A

    2010-06-30

    UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary

  2. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  3. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2013-08-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

  4. Sodium-based dry regenerable sorbent for carbon dioxide capture from power plant flue gas

    SciTech Connect (OSTI)

    Lee, J.B.; Ryu, C.K.; Baek, J.I.; Lee, J.H.; Eom, T.H.; Kim, S.H.

    2008-07-15

    Dry regenerable sorbent technology is one of the emerging technologies as a cost-effective and energy-efficient technology for CO{sub 2} capture from flue gas. Six sodium-based dry regenerable sorbents were prepared by spray-drying techniques. Their physical properties and reactivities were tested to evaluate their applicability to a fluidized-bed or fast transport-bed CO{sub 2} capture process. Each sorbents contained 20-50 wt% of Na{sub 2}CO{sub 3} or NaHCO{sub 3}. All sorbents except for Sorb NX30 were insufficient with either attrition resistance or reactivity, or both properties. Sorb NX30 sorbent satisfied most of the physical requirements for a commercial fluidized-bed reactor process along with good chemical reactivity. Sorb NX30 sorbent had a spherical shape, an average size of 89 {mu}m, a size distribution of 38-250 {mu}m, and a bulk density of approximately 0.87 g/mL. The attrition index (AI) of Sorb NX30 reached below 5% compared to about 20% for commercial fluidized catalytic cracking (FCC) catalysts. CO{sub 2} sorption capacity of Sorb NX30 was approximately 10 wt% (>80% sorbent utilization) in the simulated flue gas condition compared with 6 of 30 wt% MEA solution (33% sorbent utilization). All sorbents showed almost-complete regeneration at temperatures less than 120{sup o}C.

  5. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  6. PH adjustment of power plant cooling water with flue gas/fly...

    Office of Scientific and Technical Information (OSTI)

    PH adjustment of power plant cooling water with flue gasfly ash Citation Details In-Document Search Title: PH adjustment of power plant cooling water with flue gasfly ash A...

  7. ,"U.S. Federal Offshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Federal Offshore Natural Gas, Wet After Lease Separation ... "Back to Contents","Data 1: U.S. Federal Offshore Natural Gas, Wet After Lease Separation ...

  8. ,"U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet ... "Back to Contents","Data 1: U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet ...

  9. ,"Texas - RRC District 7B Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 7B Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 7B Natural Gas, Wet After ...

  10. ,"Texas - RRC District 7C Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 7C Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 7C Natural Gas, Wet After ...

  11. ,"Texas - RRC District 8A Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 8A Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 8A Natural Gas, Wet After ...

  12. Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 693 1980's 682 683 1990's 4,184 5,460 5,870 5,212 4,898 4,930 5,100 5,013 4,643 4,365 2000's 4,269 3,958 3,922 4,345 4,159 4,006 3,963 4,036 3,379 2,948 2010's 2,724 2,570 2,304 1,670 2,121 - = No Data Reported; -- = Not Applicable; NA = Not

  13. Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 680 1980's 659 658 1990's 4,159 5,437 5,840 5,166 4,842 4,886 5,062 4,983 4,615 4,338 2000's 4,241 3,931 3,891 4,313 4,127 3,977 3,945 4,016 3,360 2,919 2010's 2,686 2,522 2,204 1,624 1,980

  14. Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 32,275 1980's 33,395 33,049 35,002 34,291 34,476 34,223 33,355 33,715 9,179 9,019 1990's 9,393 9,653 9,725 9,986 9,813 9,575 9,296 10,673 10,043 9,855 2000's 9,331 8,901 8,533 8,348 8,473 8,237 10,333 12,022 7,766 9,183 2010's 8,917 9,511 9,667

  15. Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 5,058 1980's 4,828 4,373 4,188 3,883 4,120 3,131 2,462 2,983 2,910 2,821 1990's 2,466 2,924 3,002 3,492 3,326 3,310 3,216 2,957 2,768 2,646 2000's 2,564 2,309 2,157 2,081 2,004 1,875 1,447

  16. Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,725 1980's 1,796 1,821 1,974 2,081 2,240 2,032 2,011 2,018 2,000 1,782 1990's 1,739 1,672 1,752 1,555 1,610 1,566 1,472 1,479 1,332 1,546 2000's 1,584 1,619 1,654 1,666 1,837 1,967 2,271 3,306 5,628 10,872 2010's 14,181 16,374 11,039 13,524

  17. Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,559 1980's 1,602 1,637 1,800 1,887 2,051 1,875 1,861 1,873 1,843 1,637 1990's 1,672 1,536 1,619 1,462 1,525 1,462 1,383 1,423 1,294 1,505 2000's 1,545 1,589 1,616 1,629 1,797 1,921 2,227

  18. California - San Joaquin Basin Onshore Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - San Joaquin Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,037 1980's 4,434 4,230 4,058 3,964 3,808 3,716 3,404 3,229 3,033 2,899 1990's 2,775 2,703 2,511 2,425 2,130 2,018 1,864 2,012 2,016 2,021 2000's 2,413 2,298 2,190 2,116

  19. California Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,961 1980's 3,345 2,660 2,663 2,546 2,507 1990's 2,400 2,213 2,093 1,982 1,698 1,619 1,583 1,820 1,879 2,150 2000's 2,198 1,922 1,900 1,810 2,006 2,585 2,155 2,193

  20. California Federal Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California Federal Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 322 1980's 414 1,337 1,466 1,570 1,519 1990's 1,469 1,174 1,136 1,123 1,187 1,289 1,266 556 489 536 2000's 576 540 515 511 459 825 811 805 705 740 2010's 725 711 652 264 243 - = No Data Reported; -- =

  1. California Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,842 1980's 5,137 4,084 3,893 3,666 3,513 1990's 3,311 3,114 2,892 2,799 2,506 2,355 2,193 2,390 2,332 2,505 2000's 2,952 2,763 2,696 2,569 2,773 3,384 2,935 2,879 2,538 2,926 2010's 2,785 3,042 2,119 2,023 2,260 - = No Data Reported; -- =

  2. Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 181 1980's 200 259 206 173 208 167 190 219 177 236 1990's 510 682 762 1,162 1,088 1,072 1,055 533 772 781 2000's 960 1,025 1,097 1,186 1,293 1,326 1,541 1,838 2,010

  3. Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,838 1980's 3,170 3,228 3,551 3,373 3,140 3,095 3,198 3,131 3,749 4,526 1990's 4,759 6,011 6,463 6,979 7,036 7,592 8,064 7,160 8,208 9,372 2000's 10,837 12,949 14,348 15,893 15,249 17,122 17,682 22,480 24,169 24,081 2010's 25,372 26,151 21,674

  4. Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,657 1980's 2,970 2,969 3,345 3,200 2,932 2,928 3,008 2,912 3,572 4,290 1990's 4,249 5,329 5,701 5,817 5,948 6,520 7,009 6,627 7,436 8,591 2000's 9,877 11,924 13,251 14,707 13,956 15,796

  5. Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,824 1980's 10,065 10,443 10,128 10,183 9,981 9,844 11,093 11,089 10,530 10,509 1990's 10,004 9,946 10,302 9,872 9,705 9,093 8,145 7,328 6,862 6,248 2000's 5,682 5,460 5,329 5,143 5,003 4,598 4,197 4,248 3,795 3,500 2010's 3,937 3,747 3,557

  6. Kansas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,657 1980's 9,880 10,304 10,016 10,051 9,871 9,729 10,961 10,974 10,427 10,408 1990's 9,890 9,831 10,208 9,779 9,630 9,026 8,063 7,277 6,802 6,196 2000's 5,641 5,355 5,263 5,058 4,923 4,515

  7. Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 504 1980's 536 561 592 600 647 806 883 940 957 1,015 1990's 1,047 1,187 1,126 1,036 1,025 1,102 1,046 1,429 1,295 1,530 2000's 1,837 1,950 1,999 1,971 1,982 2,240 2,369 2,588 2,846 2,919 2010's 2,785 2,128 1,515 1,794 1,753 - = No Data Reported;

  8. Kentucky Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kentucky Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 502 1980's 525 547 580 581 630 793 866 921 938 993 1990's 1,039 1,177 1,118 1,030 978 1,075 1,022 1,403 1,275 1,501 2000's 1,810 1,925 1,974 1,946 1,963 2,210 2,333 2,554 2,812 2,887 2010's

  9. Texas - RRC District 1 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 732 1980's 683 870 708 960 714 754 716 639 1,002 1,037 1990's 744 660 606 540 586 498 523 950 1,101 1,165 2000's 1,037 1,024 1,047 1,047 1,184 1,148 1,048

  10. Texas - RRC District 10 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 10 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 6,805 1980's 6,381 6,264 6,242 5,948 5,443 5,484 5,320 5,030 4,876 4,849 1990's 4,608 4,763 4,463 4,214 4,405 4,656 4,592 4,386 4,510 4,447 2000's 4,143

  11. Texas - RRC District 5 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 5 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 5 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,127 1980's 1,117 1,265 1,322 1,477 1,911 2,100 2,169 2,106 1,989 1,789 1990's 1,835 1,841 1,692 1,790 1,926 1,876 2,088 1,681 1,906 2,301 2000's 3,089

  12. Texas - RRC District 6 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 6 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 6 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,710 1980's 3,622 3,653 3,749 4,279 4,087 4,274 4,324 4,151 4,506 5,201 1990's 5,345 4,856 4,987 5,170 5,131 5,425 5,690 5,616 5,691 5,562 2000's 5,901

  13. Texas - RRC District 8 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8,073 1980's 7,216 6,620 6,084 6,064 5,362 5,246 5,254 4,973 4,738 4,403 1990's 4,323 4,023 3,792 3,569 3,267 3,218 3,069 2,886 2,727 2,947 2000's 3,345

  14. Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 46,803 46,620 44,319 42,192 41,404 41,554 1990's 41,411 39,288 38,141 37,847 39,020 39,736 41,592 41,108 40,793 43,350 2000's 45,419 46,462 47,491 48,717 53,275 60,178 65,805 76,357 81,843 85,034 2010's 94,287 104,454 93,475 97,921 105,955 - = No

  15. Texas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 35,971 35,867 34,584 32,852 32,309 32,349 1990's 32,412 30,729 29,474 29,967 31,071 31,949 33,432 33,322 33,429 35,470 2000's 38,585 40,376 41,104 42,280 46,728 53,175 58,736 68,827 74,284

  16. Utah Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Utah Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 650 1980's 870 1,722 1,928 2,112 1,984 1,897 1,795 1,870 1,509 1,498 1990's 1,432 1,532 1,709 1,909 1,631 1,424 1,446 1,695 2,293 3,050 2000's 4,125 4,450 3,915 3,318 3,661 4,051 4,894 6,095 6,393 6,810

  17. Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 122 175 216 235 253 248 230 217 1990's 138 225 904 1,322 1,833 1,836 1,930 2,446 1,973 2,017 2000's 1,704 1,752 1,673 1,717 1,742 2,018 2,302 2,529 2,378 3,091 2010's 3,215 2,832 2,579 2,373 2,800 - = No Data Reported; -- = Not Applicable; NA =

  18. Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 122 175 216 235 253 248 230 217 1990's 138 225 904 1,322 1,833 1,836 1,930 1,923 1,973 2,017 2000's 1,704 1,752 1,673 1,717 1,742 2,018 2,302 2,529 2,378 3,091 2010's 3,215 2,832 2,579

  19. West Virginia Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) West Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,669 1980's 2,559 1,944 2,252 2,324 2,246 2,177 2,272 2,360 2,440 2,342 1990's 2,329 2,672 2,491 2,598 2,702 2,588 2,793 2,946 2,968 3,040 2000's 3,062 2,825 3,498 3,399 3,509 4,572 4,654 4,881 5,266 6,090 2010's 7,163 10,532

  20. West Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) West Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,593 1980's 2,437 1,881 2,169 2,238 2,173 2,104 2,207 2,210 2,299 2,244 1990's 2,243 2,513 2,293 2,408 2,569 2,514 2,722 2,887 2,925 2,952 2000's 2,929 2,777 3,477 3,376 3,489 4,553

  1. Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 7,834 1980's 9,413 9,659 10,155 10,728 11,014 11,229 10,393 10,572 10,903 11,276 1990's 10,433 10,433 11,305 11,387 11,351 12,712 13,084 14,321 14,371 14,809 2000's 17,211 19,399 21,531 22,716 23,640 24,722 24,463 30,896 32,399 36,748 2010's

  2. Wyoming Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Wyoming Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 6,796 1980's 8,039 8,431 9,095 9,769 10,147 10,519 9,702 9,881 10,287 10,695 1990's 9,860 9,861 10,681 10,885 10,740 11,833 12,260 13,471 13,577 14,096 2000's 16,559 18,911 20,970 22,266

  3. Louisiana - South Onshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14,580 1980's 13,407 13,049 12,153 11,553 10,650 10,120 9,416 9,024 8,969 8,934 1990's 8,492 7,846 7,019 6,219 6,558 6,166 6,105 6,137 5,966 5,858 2000's 5,447 5,341 4,395 3,874 3,557 3,478 3,473 3,463

  4. Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,276 1980's 11,273 11,178 10,364 9,971 9,162 8,328 7,843 7,644 7,631 7,661 1990's 7,386 6,851 6,166 5,570 5,880 5,446 5,478 5,538 5,336 5,259 2000's

  5. Louisiana Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,360 2,391 2,128 1,794 1,741 1990's 1,554 1,394 1,167 926 980 1,001 1,039 1,016 911 979 2000's 807 796 670 586 557 588 561 641 1,235 1,072 2010's 679 639 773 870 908

  6. Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 19,676 13,334 12,852 12,620 12,912 1990's 12,151 11,363 10,227 9,541 10,145 9,891 10,077 10,036 9,480 9,646 2000's 9,512 10,040 9,190 9,538 9,792 10,679 10,710 10,292 11,816 20,970 2010's 29,517 30,545 22,135 20,389 23,258 - = No Data Reported;

  7. Louisiana Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 16,316 10,943 10,724 10,826 11,171 1990's 10,597 9,969 9,060 8,615 9,165 8,890 9,038 9,020 8,569 8,667 2000's 8,704 9,245 8,520 8,952 9,235 10,091 10,149 9,651 10,581 19,898 2010's 28,838

  8. Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 143,852 1980's 139,421 143,515 142,984 143,469 141,226 138,464 139,070 135,256 141,211 139,798 1990's 141,941 140,584 138,883 136,953 138,213 139,369 141,136 140,382 139,015

  9. Michigan Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Michigan Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 601 1980's 668 494 481 529 419 375 665 1,002 943 1,011 1990's 922 967 938 890 1,022 1,018 1,778 1,975 2,158 2,086 2000's 2,558 2,873 3,097 3,219 2,961 2,808 2,925 3,512 3,105 2,728 2010's

  10. Mississippi Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Mississippi Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,511 1980's 1,776 2,042 1,803 1,603 1,496 1,364 1,304 1,223 1,146 1,108 1990's 1,129 1,061 873 800 653 667 634 583 662 681 2000's 620 663 746 748 692 758 816 958 1,035 922 2010's 858 868 612 600 563 - = No Data Reported; -- = Not

  11. Mississippi Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Mississippi Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,444 1980's 1,703 1,976 1,729 1,523 1,382 1,259 1,238 1,162 1,075 1,003 1990's 1,003 953 788 747 610 640 587 532 615 650 2000's 585 637 713 721 672 738 795 928 990 884 2010's 822 806

  12. Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 837 1980's 1,308 1,336 870 921 825 884 823 801 834 889 1990's 920 848 875 684 727 792 806 769 789 851 2000's 892 907 914 1,068 1,002 998 1,069 1,067 1,014 993 2010's 959 792 616 590 686 - = No Data Reported; -- = Not Applicable; NA = Not

  13. Oklahoma Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Oklahoma Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,246 1980's 2,252 2,441 2,426 2,269 2,244 2,149 2,191 2,017 1,894 1,785 1990's 1,820 1,406 1,483 1,550 1,342 1,228 1,023 1,015 1,196 1,238 2000's 1,113 1,109 1,177

  14. Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14,545 1980's 13,908 15,507 17,140 17,261 17,102 17,078 17,779 17,703 17,450 16,733 1990's 16,967 15,518 14,732 14,099 14,323 14,295 13,952 14,311 14,517 13,490 2000's 14,543 14,366 15,753 16,231 17,200 18,146 18,535 20,184 22,113 24,207 2010's

  15. Oklahoma Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Oklahoma Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,299 1980's 11,656 13,066 14,714 14,992 14,858 14,929 15,588 15,686 15,556 14,948 1990's 15,147 14,112 13,249 12,549 12,981 13,067 12,929 13,296 13,321 12,252 2000's 13,430 13,256 14,576

  16. Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,516 1980's 951 1,265 1,430 1,882 1,576 1,618 1,562 1,650 2,074 1,644 1990's 1,722 1,631 1,533 1,722 1,806 1,488 1,702 1,861 1,848 1,780 2000's 1,740 1,782 2,225 2,497 2,371 2,793 3,064 3,377 3,594 7,018 2010's 14,068 26,719 36,543

  17. Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,507 1980's 940 1,251 1,416 1,861 1,498 1,551 1,540 1,629 2,066 1,625 1990's 1,699 1,611 1,523 1,714 1,797 1,452 1,655 1,769 1,769 1,684 2000's 1,583 1,614 2,088 2,333 2,246 2,659

  18. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    1995-09-01

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  19. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2002-05-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

  20. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect (OSTI)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  1. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect (OSTI)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  2. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect (OSTI)

    1996-04-30

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  3. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    1995-09-01

    The SNRB{trademark} Flue Gas Cleanup Demonstration Project was cooperatively funded by the U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B&W, the Electric Power Research Institute (EPRI), Ohio Edison, Norton Chemical Process Products Company and the 3M Company. The SNRB{trademark} technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. Development of the SNRB{trademark} process at B&W began with pilot testing of high-temperature dry sorbent injection for SO{sub 2} removal in the 1960`s. Integration of NO{sub x} reduction was evaluated in the 1970`s. Pilot work in the 1980`s focused on evaluation of various NO{sub x} reduction catalysts, SO{sub 2} sorbents and integration of the catalyst with the baghouse. This early development work led to the issuance of two US process patents to B&W - No. 4,309,386 and No. 4,793,981. An additional patent application for improvements to the process is pending. The OCDO was instrumental in working with B&W to develop the process to the point where a larger scale demonstration of the technology was feasible. This report represents the completion of Milestone M14 as specified in the Work Plan. B&W tested the SNRB{trademark} pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R. E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B&W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB{trademark} process. The SNRB{trademark} facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993.

  4. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes

    SciTech Connect (OSTI)

    Jozewicz, W. . Environmental Systems Div.); Rochelle, G.T. . Dept. of Chemical Engineering)

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide (Ca(OH){sub 2}) slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  5. Decarb/Desal: Separation of Carbon Dioxide from Flue Gas with Simultaneous Fresh Water Production

    SciTech Connect (OSTI)

    Aines, R; Bourcier, W

    2009-10-21

    If fossil fuels continue to be a major part of the world's energy supply, effective means must be developed to deal with the carbon emissions. Geologic sequestration of supercritical CO{sub 2} is expected to play a major role in mitigating this problem. Separating carbon dioxide from other gases is the most costly aspect of schemes for geologic sequestration. That cost is driven by the complexity and energy intensity of current chemical-stripping methods for separating carbon dioxide. Our experience in water treatment technology indicated that an entirely new approach could be developed, taking advantage of water's propensity to separate gases that ionize in water (like CO{sub 2}) from those that do not (like N{sub 2}). Even though water-based systems might not have the extreme selectivity of chemicals like substituted amines used in industrial systems today, they have the potential to tolerate NO{sub x}, SO{sub x}, and particulates while also producing clean drinking water as a valuable byproduct. Lower capital cost, broader range of applicability, environmental friendliness, and revenue from a second product stream give this approach the potential to significantly expand the worldwide application of carbon separation for geologic sequestration. Here we report results for separation of CO{sub 2} from flue gas by two methods that simultaneously separate carbon dioxide and fresh water: ionic pumping of carbonate ions dissolved in water, and thermal distillation. The ion pumping method dramatically increases dissolved carbonate ion in solution and hence the overlying vapor pressure of CO{sub 2} gas, allowing its removal as a pure gas. We have used two common water treatment methods to drive the ion pumping approach, reverse osmosis and electrodialysis to produce pure CO{sub 2}. This novel approach to increasing the concentration of the extracted gas permits new approaches to treating flue gas, because the slightly basic water used as the extraction medium is

  6. Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016

  7. PH adjustment of power plant cooling water with flue gas/fly ash

    SciTech Connect (OSTI)

    Brady, Patrick V.; Krumhansl, James L.

    2015-09-22

    A system including a vessel including a heat source and a flue; a turbine; a condenser; a fluid conduit circuit disposed between the vessel, the turbine and the condenser; and a diverter coupled to the flue to direct a portion of an exhaust from the flue to contact with a cooling medium for the condenser water. A method including diverting a portion of exhaust from a flue of a vessel; modifying the pH of a cooling medium for a condenser with the portion of exhaust; and condensing heated fluid from the vessel with the pH modified cooling medium.

  8. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance

    SciTech Connect (OSTI)

    Andrew Seltzer; Zhen Fan

    2011-03-01

    A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

  9. OpenEI Community - natural gas+ condensing flue gas heat recovery...

    Open Energy Info (EERE)

    groupincrease-natural-gas-energy-efficiency

  10. Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,334 1980's 1,551 1,252 1,200 1,353 1,193 1,064 1,242 1,571 1,434 1,443 1990's 1,330 1,404 1,290 1,218 1,379 1,344 2,125 2,256 2,386 2,313 2000's 2,772 3,032 3,311 3,488 3,154 2,961 3,117 3,691 3,253 2,805 2010's 2,975 2,549 1,781 1,839 1,873 -

  11. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2015-06-30

    The objective of this project was to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This final report details all development, analysis, design and testing of the project. Also included in the final report are an updated Techno-Economic Analysis and CO2 Lifecycle Analysis. The subsystems included in the pilot demonstration plant are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant was proven to be capable of capturing CO2 from various sources (gas and coal) and mineralizing it into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The final report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. The report also discusses the results of the fully integrated operation of the facility. Fiber cement boards have been produced in this facility exclusively using reactive calcium carbonate from captured CO2 from flue gas. These boards meet all US and China appropriate acceptance standards. Use demonstrations for these boards are now underway.

  12. JV Task 5 - Evaluation of Residual Oil Fly Ash As A Mercury Sorbent For Coal Combustion Flue Gas

    SciTech Connect (OSTI)

    Robert Patton

    2006-12-31

    The mercury adsorption capacity of a residual oil fly ash (ROFA) sample collected form Florida Power and Light Company's Port Everglades Power Plant was evaluated using a bituminous coal combustion flue gas simulator and fixed-bed testing protocol. A size-segregated (>38 {micro}g) fraction of ROFA was ground to a fine powder and brominated to potentially enhance mercury capture. The ROFA and brominated-ROFA were ineffective in capturing or oxidizing the Hg{sup 0} present in a simulated bituminous coal combustion flue gas. In contrast, a commercially available DARCO{reg_sign} FGD initially adsorbed Hg{sup 0} for about an hour and then catalyzed Hg{sup 0} oxidation to produce Hg{sup 2+}. Apparently, the unburned carbon in ROFA needs to be more rigorously activated in order for it to effectively capture and/or oxidize Hg{sup 0}.

  13. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  14. JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas

    SciTech Connect (OSTI)

    Ye Zhuang; Christopher Martin; John Pavlish

    2009-03-31

    This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

  15. Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

    SciTech Connect (OSTI)

    Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

    2011-10-16

    Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

  16. Spare parts program practices for flue gas desulfurization systems: Final report

    SciTech Connect (OSTI)

    Morgan, W.E.; Stresewski, J.E.; Cannell, A.L.

    1987-04-01

    Reliability and availability of a flue gas desulfurization (FGD) system is dependent to some extent on adequate system maintenance. System maintenance must be supported by a well planned spare parts program. The objective of this project was to determine the current practices followed by electric utilities in planning spare parts programs. Utilities with operational FGD systems were surveyed to determine the types of practices and typical inventory levels for spare parts for various items of FGD system equipment. FGD system suppliers and consulting engineering firms were also surveyed to obtain their recommendations regarding system sparing philosophy. The survey results were examined to determine significant trends and identify areas where further work could be beneficial. In general, spare parts problems typically have not been a cause for loss of availability except in some specific cases where a late start in planning the spare parts program contributed to problems during early stages of FGD system operation. Computerized methods for inventory surveillance and reordering are replacing manual methods. Stock levels for spare parts typically have been adjusted to reflect the individual utilities' operating experience. Documentation of spare parts usage rates over an extended time period would provide a data base for utilities planning spare parts programs for their first FGD system installation.

  17. LIFAC flue gas desulfurization process an alternative SO{sub 2} control strategy

    SciTech Connect (OSTI)

    Patel, J.G.; Vilala, J.

    1995-12-01

    This paper discusses the results from two recently completed LIFAC flue gas desulfurization plants - 300 MW Shand lignite powered station owned by Saskatchewan Power Corporation and 60 MW Whitewater Valley high sulfur coal fired station owned by Richmond Powerand Light. LIFACis a dry FGD process in which limestone is injected into the upper regions of the boiler furnace and an activation reactor is used to humidify the unreacted limestone to achieve additional sulfur capture. The performance in both plants indicates that 70 to 80% sulfur is removed at a Ca/S ratio of 2. Cost performance data from these plants has shown that LI FAC both on construction cost and $/ton SO{sub 2} removed basis is very cost competitive compared to other SO{sub 2} control technologies. The Richmond plant has been realized under the auspices of the U.S. Department of Energy`s Clean Coal Technology program. The Shand plant is the first commercial installation in North America. The paper also discusses highlights of operating and maintenance experience, availability and handling of the solid waste product.

  18. Status of spray-dryer flue-gas desulfurization. Final report

    SciTech Connect (OSTI)

    Ireland, P.A.

    1982-01-01

    Utility interest and commitment to spray drying for SO/sub 2/ and particulate control has increased dramatically in response to vendor claims (lower costs, dry wastes, lower energy requirements, and simplicity) and newly promulgated federal emission regulations that allow lower SO/sub 2/ removal requirements (70%) for low-sulfur coals. Unfortunately, limited data are available from which to evaluate vendor claims prior to commercial commitment or to improve the cost and reliability of this potentially important flue gas desulfurization (FGD) option. Accordingly, EPRI is conducting a pilot-scale project (RP1870) to provide a systematic evaluation of the technology unconstrained by specific vendor designs, operating philosophy, or commercial limitation. It will result in guidelines for system design and optimization in order to ensure reliable utility operation at minimum cost. This final report (TPS 80-741) contains a review of the design practices for the full-scale systems ordered and a discussion of the important spray-drying FGD process variables. Other EPRI work in this area includes a cost study with the Tennessee Valley Authority (RP1180-7) and a spray-dryer waste solids characterization (RP1870-2). The EPA has published a similar status document, which, in addition to spray drying, also covers dry injection and burning coal-alkali mixtures. However, the EPA document is not as detailed on either the design of full-scale systems or the technical issues.

  19. U.S. Nonassociated Natural Gas, Wet After Lease Separation, New...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reservoir Discoveries in Old Fields (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, New Reservoir Discoveries in Old Fields (Billion Cubic Feet) ...

  20. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reservoir Discoveries in Old Fields (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, New Reservoir Discoveries in Old Fields (Billion Cubic ...

  1. Crude Oil and Lease Condensate Wet Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. proved reserves, and reserves changes, 2013-2014 Crude Oil and Lease Condensate Wet Natural Gas billion barrels trillion cubic feet U.S. proved reserves at December 31, 2013 36.5 354.0 Total discoveries 5.4 50.5 Net revisions 0.4 1.0 Net Adjustments, Sales, Acquisitions 0.8 11.5 Production -3.2 -28.1 Net additions to U.S. proved reserves 3.4 34.8 U.S. proved reserves at December 31, 2014 39.9 388.8 Percent change in U.S. proved reserves 9.3% 9.8% Percent change calculated from unrounded

  2. PH adjustment of power plant cooling water with flue gas/fly...

    Office of Scientific and Technical Information (OSTI)

    Krumhansl, James L. A system including a vessel including a heat source and a flue; a turbine; a condenser; a fluid conduit circuit disposed between the vessel, the turbine and...

  3. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis

  4. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Zanfir, Monica; Solunke, Rahul; Shah, Minish

    2012-06-01

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbon's catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full

  5. Alkali metal vapor removal from pressurized fluidized-bed combustor flue gas. Quarterly report, April-June 1980

    SciTech Connect (OSTI)

    Johnson, I.; Swift, W.M.; Lee, S.H.D.; Boyd, W.A.

    1980-07-01

    In the application of pressurized fluidized-bed combustors (PFBC) to the generation of electricity, hot corrosion of gas turbine components by alkali metal compounds is a potential problem. The objective of this investigation is to develop a method for removing these gaseous alkali metal compounds from the high-pressure high-temperature gas from a PFBC before the gas enters the gas turbine. A granular-bed filter, using either diatomaceous earth or activated bauxite as the bed material, is the concept currently being studied. Results are presented for the testing of diatomaceous earth for alkali vapor sorption at 800/sup 0/C and 9-atm pressure, using a simulated flue gas. Activated bauxite sorbent can be regenerated by leaching with water, and the kinetics of the leaching is under study.

  6. CO{sub 2} Capture from Flue Gas Using Solid Molecular Basket Sorbents

    SciTech Connect (OSTI)

    Fillerup, Eric; Zhang, Zhonghua; Peduzzi, Emanuela; Wang, Dongxiang; Guo, Jiahua; Ma, Xiaoliang; Wang, Xiaoxing; Song, Chunshan

    2012-08-31

    The objective of this project is to develop a new generation of solid, regenerable polymeric molecular basket sorbent (MBS) for more cost-efficient capture and separation of CO{sub 2} from flue gas of coal-fired power plants. The primary goal is to develop a cost-effective MBS sorbent with better thermal stability. To improve the cost-effectiveness of MBS, we have explored commercially available and inexpensive support to replace the more expensive mesoporous molecular sieves like MCM-41 and SBA- 15. In addition, we have developed some advanced sorbent materials with 3D pore structure such as hexagonal mesoporous silica (HMS) to improve the CO{sub 2} working capacity of MBS, which can also reduce the cost for the whole CO{sub 2} capture process. During the project duration, the concern regarding the desorption rate of MBS sorbents has been raised, because lower desorption rate increases the desorption time for complete regeneration of the sorbent which in turn leads to a lower working capacity if the regeneration time is limited. Thus, the improvement in the thermal stability of MBS became a vital task for later part of this project. The improvement in the thermal stability was performed via increasing the polymer density either using higher molecular weight PEI or PEI cross-linking with an organic compound. Moreover, we have used the computational approach to estimate the interaction of CO{sub 2} with different MBSs for the fundamental understanding of CO{sub 2} sorption, which may benefit the development, design and modification of the sorbents and the process.

  7. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energys National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2

  8. Effects of flue gas components on the reaction of Ca(OH){sub 2} with SO{sub 2}

    SciTech Connect (OSTI)

    Liu, C.F.; Shih, S.M.

    2006-12-20

    A differential fixed-bed reactor was employed to study the effects of the flue gas components, H{sub 2}O, CO{sub 2}, NOx, and O{sub 2}, on the reaction between Ca(OH){sub 2} and SO{sub 2} under conditions similar to those in the bag filters of a spray-drying flue gas desulfurization (FGD) system. The presence of CO{sub 2} with SO{sub 2} in the gas phase enhanced the sulfation of Ca(OH){sub 2} only when NOx was also present. When either NOx (mainly NO) or O{sub 2} was present with SO{sub 2}, the enhancement effect was slight, but became great when both NOx and O{sub 2} were present, and was even greater when CO{sub 2} was also present. The great enhancement effect exerted by the presence of NOx/O{sub 2} resulted from the rise in the NO{sub 2} concentration, which enhanced the oxidation of HSO{sub 3}- and SO{sub 3}{sup 2-} to SO{sub 4}{sup 2-} in the water layer adsorbed on Ca(OH){sub 2} surface and the formation of deliquescent salts of calcium nitrite and nitrate. The enhancement effect due to the presence of NOx/O{sub 2} was more pronounced when the relative humidity was above that at which the salts deliquesced; the extent of sulfation was more than twice that obtained when SO{sub 2} alone was present. The presence of H{sub 2}O, CO{sub 2}, NOx, and O{sub 2} in the flue gas is beneficial to the SO{sub 2} capture in the low-temperature dry and semidry FGD processes. The presence of NOx/O{sub 2} also enhanced CO{sub 2} removal when SO{sub 2} was absent.

  9. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  10. CO[sub 2] capture from the flue gas of conventional fossil-fuel-fired power plants

    SciTech Connect (OSTI)

    Wolsky, A.M.; Daniels, E.J.; Jody, B.J. )

    1994-08-01

    Research has been conducted at Argonne National Laboratory to identify and evaluate the advantages and deficiencies of several technologies, both commercially available and alternative technologies, for capturing CO[sub 2] from the flue gas of utility boilers that use air as an oxidant (the current universal practice). The technologies include chemical solvent, cryogenic, membrane, physical absorption, and physical adsorption methods. In general, technologies for capturing CO[sub 2] are expensive and energy-intensive. Therefore, they result in a substantial overall increase in the cost of power generation. Research to improve the performance and economics of these technologies is discussed. 20 refs., 6 figs., 1 tab.

  11. Separation of flue-gas scrubber sludge into marketable products. Fourth year, first quarterly technical progress report, September 1, 1996--December 31, 1996 (Quarter No. 13)

    SciTech Connect (OSTI)

    Kawatra, S.K.; Eisele, T.C.

    1996-12-01

    To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. It consists of calcium sulfite (CaSO{sub 3}{circ}0.5H{sub 2}O), gypsum (CaSO{sub 4}{circ}2H{sub 2}O), and unreacted limestone (CaCO{sub 3}) or lime (Ca(OH)2), with miscellaneous objectionable impurities such as iron oxides, silicates, and magnesium, sodium, and potassium oxides or salts. These impurities prevent many sludges from being utilized as a replacement for natural gypsum, and as a result they must be disposed of in landfills, which presents a serious disposal problem. Knowledge of scrubber sludge characteristics is necessary for the development of purification technologies which will make it possible to directly utilize scrubber sludges rather than landfilling them. This project is studying the use of minimal-reagent froth flotation as the purification process, using the surface properties of the particles of unreacted limestone to remove them and their associated impurities from the material, leaving a purified calcium sulfite/gypsum product.

  12. Selective CO 2 Capture from Flue Gas Using Metal–Organic Frameworks-A Fixed Bed Study

    SciTech Connect (OSTI)

    Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

    2012-05-03

    It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

  13. ,"New Mexico Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico Associated-Dissolved Natural Gas, ... 8:59:18 AM" "Back to Contents","Data 1: New Mexico Associated-Dissolved Natural Gas, ...

  14. ,"New Mexico - East Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico - East Nonassociated Natural Gas, ... 8:57:52 AM" "Back to Contents","Data 1: New Mexico - East Nonassociated Natural Gas, ...

  15. ,"New Mexico - West Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico - West Nonassociated Natural Gas, ... 8:57:52 AM" "Back to Contents","Data 1: New Mexico - West Nonassociated Natural Gas, ...

  16. ,"North Dakota Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Dakota Associated-Dissolved Natural Gas, ... 9:33:41 AM" "Back to Contents","Data 1: North Dakota Associated-Dissolved Natural Gas, ...

  17. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-10-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues (CCBs) in abandoned coal mines, and will assess the environmental impact of such underground CCB placement. This report describes progress in the following areas: environmental characterization, mix development and geotechnical characterization, material handling and system economics, underground placement, and field demonstration.

  18. System for removing solids from a used lime or limestone slurry scrubbing liquor in flue gas desulfurization

    SciTech Connect (OSTI)

    Randolph, A.D.

    1981-10-13

    The flue gas desulfurization process using a lime or limestone slurry scrubbing solution produces used liquor containing calcium sulfite or sulfate (Typically gypsum). Precipitated particles are removed by feeding the used scrubbing liquor to an agitated crystallization zone to grow crystals and directing part of the used scrubbing liquor from that zone to a quiescent crystallization zone, in which particles are settled back into the agitated zone. An underflow stream from the agitated zone containing large crystals is combined with an overflow stream from the quiescent zone, which combined stream is clarified with the fines being returned to the scrubber and the large crystals being removed as a waste product. Apparatus for performing the above process in which the agitated and quiescent crystallization zones form part of a single crystallization vessel, and the two zones are separated by a baffle.

  19. Study investigates eletron beam scrubbing for removal of (SO{sub 2}) and (NO{sub x}) from flue gas

    SciTech Connect (OSTI)

    1996-03-01

    A beam of high-energy electrons can be used to initiate simultaneous oxidation of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) in flue gas from coal-fired power plants. This process, known as electron beam dry scrubbing (EBDS), has been under development since 1970 and shows great promise as it continues towards commercialization. One obstacle, the high cost and low power of conventional electron beam generator, may be overcome through integration of an advanced electron beam generator being developed by Science Applications International Corporation (SAIC - McLean, Virginia). SAIC was funded to (1) design, construct, and test a prototype of its continuously pulsed, high- average-power electron beam generator; and (2) evaluate the performance and economics of EBDS with the advanced electron beam generator as applied to high-sulfur coal-fired power plants. Results of the EBDS evaluation are reported in this paper. 1 ref., 1 fig., 3 tabs.

  20. Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 4, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler`s outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  1. California State Offshore Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 226 1980's 160 244 232 221 206 1990's 188 55 59 63 59 56 47 54 39 58 2000's 86 80 85 76 85 89 85 79 54 53 2010's 63 79 65 75 76 - = No Data

  2. Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 167 1980's 185 139 112 132 110 115 132 115 103 101 1990's 114 115 94 93 75 67 82 51 60 52 2000's 40 105 66 85 80 83 82 83 85 83 2010's 79 127 326 433 657 - = No Data Reported;

  3. Texas - RRC District 1 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 209 1980's 172 180 216 175 170 260 241 205 204 251 1990's 333 401 361 191 151 248 446 68 51 67 2000's 69 43 47 48 45 57 61 72 60 67 2010's 267

  4. Texas - RRC District 10 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 0 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 484 1980's 546 456 489 537 617 560 537 482 424 364 1990's 311 298 396 264 264 254 253 227 234 241 2000's 289 255 271 252 249 253 316 436

  5. Texas - RRC District 2 Onshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) 2 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 2 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 955 1980's 921 806 780 747 661 570 517 512 428 430 1990's 407 352 308 288 299 245 252 235 204 202 2000's 115 65 70 81

  6. Texas - RRC District 4 Onshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) 4 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 4 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,416 1980's 1,292 1,005 890 765 702 684 596 451 393 371 1990's 301 243 228 215 191 209 246 368 394 182 2000's 176 140

  7. Texas - RRC District 5 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 5 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 5 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 62 1980's 75 44 47 52 44 40 69 118 101 136 1990's 116 89 126 141 148 47 53 68 89 49 2000's 128 83 65 62 58 51 57 50 40 21 2010's 8 40 53 177

  8. Texas - RRC District 6 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 6 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 6 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 868 1980's 954 869 881 943 938 874 822 811 728 695 1990's 668 638 606 607 547 611 562 578 580 545 2000's 464 412 400 387 402 344 276 247 412

  9. Texas - RRC District 7B Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 7B Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 7B Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 234 1980's 332 292 214 338 292 276 244 282 264 196 1990's 214 157 170 187 181 276 232 260 204 190 2000's 114 88 57 69 76 73 74 62 68 102

  10. Texas - RRC District 7B Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) B Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 7B Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 608 1980's 530 655 733 872 645 574 589 546 576 364 1990's 413 379 380 393 332 263 378 299 306 275 2000's 242 203 237 314 288 859 1,589 2,350 2,682 2,322

  11. Texas - RRC District 7C Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) C Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 7C Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 653 1980's 520 685 704 705 776 780 666 737 727 721 1990's 768 759 748 633 631 640 692 596 557 616 2000's 693 634 737 927 994 1,037 1,196

  12. Texas - RRC District 8A Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 8A Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8A Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 71 1980's 69 59 37 44 43 39 34 30 24 16 1990's 21 21 13 12 15 15 18 41 18 44 2000's 69 82 101 100 95 85 82 88 63 43 2010's 58 31 20 23 24 - = No Data

  13. Texas - RRC District 9 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 9 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 9 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 175 1980's 249 274 299 255 274 290 263 267 241 212 1990's 214 200 184 178 148 138 121 147 199 180 2000's 209 124 140 125 110 126 105 139 158

  14. Utah Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Utah Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 367 1980's 414 335 325 360 341 391 410 471 475 442 1990's 455 469 309 289 286 277 301 310 209 321 2000's 348 303 359 299 290 308 317 368 321 601 2010's 631 909 1,001 895 872 - =

  15. West Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) West Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 76 1980's 122 63 83 86 73 73 65 150 141 98 1990's 86 159 198 190 133 74 71 59 43 88 2000's 98 48 21 23 20 19 16 16 23 24 2010's 29 52 21 70 32 - = No Data

  16. ,"Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  17. ,"Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  18. ,"Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  19. ,"California Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  20. ,"Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  1. ,"Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  2. Louisiana - South Onshore Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) South Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,304 1980's 2,134 1,871 1,789 1,582 1,488 1,792 1,573 1,380 1,338 1,273 1990's 1,106 995 853 649 678 720 627 599 630 599

  3. Ohio Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Ohio Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,047 1980's 1,417 800 984 1,635 1,178 938 898 594 480 589 1990's 371 376 381 343 315 355 399 391 342 402 2000's 469 340 346 304 208 184 174 101 99 97 2010's 90 74 223 314 208 - =

  4. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature range during Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis Smirniotis

    2002-09-17

    A number basic sorbents based on CaO were synthesized, characterized with novel techniques and tested for sorption of CO{sub 2} and selected gas mixtures simulating flue gas from coal fired boilers. Our studies resulted in highly promising sorbents which demonstrated zero affinity for N{sub 2}, O{sub 2}, SO{sub 2}, and NO very low affinity for water, ultrahigh CO{sub 2} sorption capacities, and rapid sorption characteristics, CO{sub 2} sorption at a very wide temperature range, durability, and low synthesis cost. One of the 'key' characteristics of the proposed materials is the fact that we can control very accurately their basicity (optimum number of basic sites of the appropriate strength) which allows for the selective chemisorption of CO{sub 2} at a wide range of temperatures. These unique characteristics of this family of sorbents offer high promise for development of advanced industrial sorbents for the effective CO{sub 2} removal.

  5. Fundamental mechanisms in flue gas conditioning. Topical report No. 2, Literature review and assembly of theories on the interactions of ash and conditioning agents

    SciTech Connect (OSTI)

    Bush, P.V.; Snyder, T.R.

    1992-01-09

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ask properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  6. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping . E-mail: zzhong@seu.edu.cn; Jin Baosheng; Huang Yaji; Zhou Hongcang; Lan Jixiang

    2006-07-01

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  7. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, April 1--June 30, 1996

    SciTech Connect (OSTI)

    1997-05-01

    On September 30, 1993, the US Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate two technologies for the placement of coal combustion residues in abandoned underground coal mines, and will assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement, using virtually dry materials, and (2) hydraulic placement, using a {open_quotes}paste{close_quotes} mixture of materials with about 70% solids. Phase II of the overall program began April 1, 1996. The principal objective of Phase II is to develop and fabricate the equipment for placing the coal combustion by-products underground, and to conduct a demonstration of the technologies on the surface. Therefore, this quarter has been largely devoted to developing specifications for equipment components, visiting fabrication plants throughout Southern Illinois to determine their capability for building the equipment components in compliance with the specifications, and delivering the components in a timely manner.

  8. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October--December 1994

    SciTech Connect (OSTI)

    Chugh, Y.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

    1995-01-01

    On September 30, 1993, the US Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative agreement entitled ``Management of Dry Flue Gas Desulfurization By-Products in Underground Mines`` (DE-FC21-93MC30252). Under the agreement, Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. The major event during the quarter was the demonstration of the SEEC, Inc. technology for loading and transporting coal combustion residues in the SEEC developed Collapsible Intermodal Containers (CIC). The demonstration was held on November 17, 1994, at the Illinois Power Company Baldwin power plant, and was attended by about eighty (80) invited guest. Also during the quarter meetings were held with Peabody Coal Company officials to finalize the area in the Peabody No. 10 mine to be used for the placement of coal combustion residues. Work under the Materials Handling and Systems Economics area continued, particularly in refining the costs and systems configuration and in economic evaluation of various systems using equipment leasing rather than equipment purchases. Likewise, work progressed on residues characterization, with some preparations being made for long-term testing.

  9. Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Kevin Fogash

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  10. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J.

    1998-12-31

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  11. Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Fogash, Kevin

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  12. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    SciTech Connect (OSTI)

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  13. Development of a Novel Gas Pressurized Stripping Process-Based Technology for CO₂ Capture from Post-Combustion Flue Gases

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2015-09-30

    A novel Gas Pressurized Stripping (GPS) post-combustion carbon capture (PCC) process has been developed by Carbon Capture Scientific, LLC, CONSOL Energy Inc., Nexant Inc., and Western Kentucky University in this bench-scale project. The GPS-based process presents a unique approach that uses a gas pressurized technology for CO₂ stripping at an elevated pressure to overcome the energy use and other disadvantages associated with the benchmark monoethanolamine (MEA) process. The project was aimed at performing laboratory- and bench-scale experiments to prove its technical feasibility and generate process engineering and scale-up data, and conducting a techno-economic analysis (TEA) to demonstrate its energy use and cost competitiveness over the MEA process. To meet project goals and objectives, a combination of experimental work, process simulation, and technical and economic analysis studies were applied. The project conducted individual unit lab-scale tests for major process components, including a first absorption column, a GPS column, a second absorption column, and a flasher. Computer simulations were carried out to study the GPS column behavior under different operating conditions, to optimize the column design and operation, and to optimize the GPS process for an existing and a new power plant. The vapor-liquid equilibrium data under high loading and high temperature for the selected amines were also measured. The thermal and oxidative stability of the selected solvents were also tested experimentally and presented. A bench-scale column-based unit capable of achieving at least 90% CO₂ capture from a nominal 500 SLPM coal-derived flue gas slipstream was designed and built. This integrated, continuous, skid-mounted GPS system was tested using real flue gas from a coal-fired boiler at the National Carbon Capture Center (NCCC). The technical challenges of the GPS technology in stability, corrosion, and foaming of selected solvents, and environmental, health and

  14. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  15. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching; Newby, Richard A.; Lippert, Thomas E.

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  16. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-11-01

    There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

  17. Alaska Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alaska Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 27,217 1980's 28,567 28,676 30,814 30,408 30,356 31,092 30,893 30,732 6,269 6,198 1990's 6,927 6,729 6,723 6,494 6,487 6,265 6,080 7,716 7,275 7,209 2000's 6,768 6,592 6,376

  18. Texas - RRC District 1 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 941 1980's 855 1,050 924 1,135 884 1,014 957 844 1,206 1,288 1990's 1,077 1,061 967 731 737 746 969 1,018 1,152 1,232 2000's 1,106 1,066 1,094 1,095 1,229 1,205 1,109 1,101 1,047 1,523 2010's 2,599 6,127

  19. Texas - RRC District 10 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 7,289 1980's 6,927 6,720 6,731 6,485 6,060 6,044 5,857 5,512 5,300 5,213 1990's 4,919 5,061 4,859 4,478 4,669 4,910 4,845 4,613 4,744 4,688 2000's 4,433 4,263 4,299 4,510 5,383 5,430 5,950 6,932 7,601

  20. Texas - RRC District 2 Onshore Natural Gas, Wet After Lease Separation

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 2 Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 3,034 1980's 2,566 2,726 2,565 2,637 2,626 2,465 2,277 2,373 2,131 1,849 1990's 1,825 1,479 1,484 1,425 1,468 1,371 1,430 1,732 1,720 1,974 2000's 2,045 1,863 1,867 1,849 1,934 2,175 2,166

  1. Texas - RRC District 2 Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 2 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 2 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,079 1980's 1,645 1,920 1,785 1,890 1,965 1,895 1,760 1,861 1,703 1,419 1990's 1,418 1,127 1,176 1,137 1,169 1,126 1,178 1,497 1,516

  2. Texas - RRC District 3 Onshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) 3 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 3 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,513 1980's 2,429 2,080 1,881 1,784 1,756 1,537 1,405 1,296 1,226 1,148 1990's 1,056 1,123 1,206 1,159 1,063 960

  3. Texas - RRC District 3 Onshore Natural Gas, Wet After Lease Separation

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 3 Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 6,565 1980's 5,762 5,546 5,048 5,004 5,020 4,477 4,010 3,859 3,626 3,426 1990's 3,080 3,110 2,929 3,251 3,653 4,156 4,652 4,418 4,205 4,132 2000's 4,042 3,943 3,826 3,548 3,400 3,406 3,278

  4. Texas - RRC District 3 Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 3 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 3 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,052 1980's 3,333 3,466 3,167 3,220 3,264 2,940 2,605 2,563 2,400 2,278 1990's 2,024 1,987 1,723 2,092 2,590 3,196 3,612 3,539 3,275

  5. Texas - RRC District 4 Onshore Natural Gas, Wet After Lease Separation

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 4 Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8,559 1980's 8,366 8,256 8,692 8,612 8,796 8,509 8,560 7,768 7,284 7,380 1990's 7,774 7,339 7,041 7,351 7,870 8,021 8,123 8,483 8,824 9,351 2000's 10,118 10,345 9,861 9,055 9,067 9,104 8,474

  6. Texas - RRC District 4 Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 4 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 4 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 7,143 1980's 7,074 7,251 7,802 7,847 8,094 7,825 7,964 7,317 6,891 7,009 1990's 7,473 7,096 6,813 7,136 7,679 7,812 7,877 8,115 8,430

  7. Texas - RRC District 5 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 5 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,189 1980's 1,192 1,309 1,369 1,529 1,955 2,140 2,238 2,224 2,090 1,925 1990's 1,951 1,930 1,818 1,931 2,074 1,923 2,141 1,749 1,995 2,350 2000's 3,217 4,289 4,653 5,460 6,583 9,611 12,648 17,274 20,460

  8. Texas - RRC District 6 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 6 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 3,578 1980's 4,576 4,522 4,630 5,222 5,025 5,148 5,146 4,962 5,234 5,896 1990's 6,013 5,494 5,593 5,777 5,678 6,036 6,252 6,194 6,271 6,107 2000's 6,365 6,429 6,561 6,959 7,966 9,343 9,481 11,715 12,619

  9. Texas - RRC District 7B Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 7B Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 842 1980's 862 947 947 1,210 937 850 833 828 840 560 1990's 627 536 550 580 513 539 610 559 510 465 2000's 356 290 294 383 364 932 1,663 2,412 2,750 2,424 2010's 2,625 3,887 3,363 3,267 2,695 - = No Data

  10. Texas - RRC District 7C Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 7C Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 3,080 1980's 2,543 2,750 2,928 2,855 3,169 3,255 3,039 3,032 3,101 3,497 1990's 3,829 3,592 3,621 3,578 3,660 3,468 4,063 3,843 3,496 3,593 2000's 4,132 3,757 4,167 4,791 5,190 5,702 5,727 6,028 5,529

  11. Texas - RRC District 7C Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 7C Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 7C Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,427 1980's 2,023 2,065 2,224 2,150 2,393 2,475 2,373 2,295 2,374 2,776 1990's 3,061 2,833 2,873 2,945 3,029 2,828 3,371 3,247 2,939 2,977 2000's 3,439

  12. Texas - RRC District 8 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 8 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,645 1980's 2,569 2,630 2,908 3,014 2,932 3,004 3,076 2,898 3,072 3,128 1990's 3,068 2,770 2,742 2,562 2,751 2,834 2,981 3,144 2,820 3,175

  13. Texas - RRC District 8 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 8 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,718 1980's 9,785 9,250 8,992 9,078 8,294 8,250 8,330 7,871 7,810 7,531 1990's 7,391 6,793 6,534 6,131 6,018 6,052 6,050 6,030 5,547 6,122 2000's 6,136 6,007 6,056 5,835 6,002 6,800 6,855 7,303 7,586

  14. Texas - RRC District 8A Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) A Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8A Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,485 1980's 1,396 1,486 1,420 1,301 1,272 1,314 1,275 1,271 1,267 1,534 1990's 1,526 1,521 1,585 1,451 1,572 1,318 1,276 1,206 1,097 1,513

  15. Texas - RRC District 8A Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 8A Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,556 1980's 1,465 1,545 1,457 1,345 1,315 1,353 1,309 1,301 1,291 1,550 1990's 1,547 1,542 1,598 1,463 1,587 1,333 1,294 1,247 1,115 1,557 2000's 1,215 1,190 1,167 1,137 1,281 1,471 1,384 1,531 1,257

  16. Texas - RRC District 9 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 9 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 808 1980's 751 1,070 1,264 1,100 1,060 1,043 1,024 984 927 829 1990's 917 874 797 814 863 868 870 932 864 1,360 2000's 1,854 2,552 3,210 3,639 4,555 4,734 6,765 7,985 9,548 11,522 2010's 13,172 10,920

  17. Texas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10,832 10,753 9,735 9,340 9,095 9,205 1990's 8,999 8,559 8,667 7,880 7,949 7,787 8,160 7,786 7,364 7,880 2000's 6,833 6,089 6,387 6,437 6,547 7,003 7,069 7,530 7,559 8,762 2010's

  18. U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 6,773 6,487 6,315 6,120 6,738 7,471 7,437 7,913 7,495 7,093 2000's 7,010 8,649 8,090 7,417 6,361 5,904 4,835 4,780 5,106 5,223 2010's 5,204

  19. U.S. Federal Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) U.S. Federal Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 31,849 29,914 28,186 27,586 28,813 29,518 29,419 29,011 27,426 26,598 2000's 27,467 27,640 25,862 23,033 19,747 18,252 15,750 14,813 13,892 12,856 2010's 12,120 10,820 9,853 8,567 8,968 - = No Data

  20. U.S. Federal Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) U.S. Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 25,076 23,427 21,871 21,466 22,075 22,047 21,982 21,098 19,931 19,505 2000's 20,456 18,990 17,772 15,616 13,386 12,348 10,915 10,033 8,786 7,633 2010's 6,916

  1. Lower 48 States Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Lower 48 States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 32,208 1980's 33,443 32,870 31,268 31,286 30,282 29,515 28,684 27,457 26,609 26,611 1990's 26,242 25,088 24,701 23,551 23,913 24,532 24,715 24,666

  2. Lower 48 States Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Lower 48 States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 176,060 1980's 172,864 176,385 174,252 174,755 171,508 167,979 167,754 162,713 167,820 166,409 1990's 168,183 165,672 163,584 160,504 162,126 163,901 165,851 165,048 162,400 166,304 2000's 177,179 182,842 187,028 188,797 192,727

  3. Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,479 1980's 1,699 965 1,142 2,031 1,542 1,333 1,420 1,071 1,229 1,275 1990's 1,215 1,181 1,161 1,106 1,095 1,054 1,114 985 890 1,179 2000's 1,186 971 1,118 1,127 975 898 975 1,027 985 896 2010's 832 758 1,235 3,201 7,193 - = No Data Reported; -- = Not

  4. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October 1--December 31, 1995

    SciTech Connect (OSTI)

    1997-05-01

    On September 30, 1993, the U.S. Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SITJC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC-30252). Under the agreement SIUC will develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mine workings, and assess the environmental impact of such underground placements. This report discusses the technical progress achieved during the period October 1 - December 31, 1995. Rapid Aging Test columns were placed in operation during the second quarter of 1995, and some preliminary data were acquired during this quarter. These data indicate that the highly caustic pH is initially generated in the pneumatic mix, but that such pH is short lived. The initial pH rapidly declines to the range of 8 to 9. Leachates in this pH range will have little or no effect on environmental concerns. Dedicated sampling equipment was installed in the groundwater monitoring wells at the proposed placement site at the Peabody Number 10 mine. Also, the groundwater monitoring wells were {open_quotes}developed{close_quotes} during the quarter to remove the fines trapped in the sand pack and screen. A new procedure was used in this process, and proved successful. A series of tests concerning the geotechnical characteristics of the pneumatic mixes were conducted. Results show that both moisture content and curing time have a direct effect on the strength of the mixes. These are, of course, the expected general results. The Christmas holidays and the closing of the University during an extended period affected the progress of the program during the quarter. However, the program is essentially on schedule, both technically and fiscally, and any delays will be overcome during the first quarter of 1996.

  5. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, January--March 1995

    SciTech Connect (OSTI)

    Chugh, Y.; Dutta, D.; Esling, S.

    1995-04-01

    On September 30, 1993, the U.S. Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC 30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, as well as the management plan and the test plan for the overall program, and a discussion of these will not be repeated here. Rather, this report, will set forth the technical progress made during the period January 1 through March 31, 1995. The demonstration of the SEEC, Inc. technology for the transporting of coal combustion residues was completed with the unloading and final disposition of the three Collapsible Intermodal Containers (CIC). The loading and transport by rail of the three CIC`s was quire successful; however some difficulties were encountered in the unloading of the containers. A full topical report on the entire SEEC demonstration is being prepared. As a result of the demonstration some modifications of the SEEC concept may be undertaken. Also during the quarter the location of the injection wells at the Peabody No. 10 mine demonstration site were selected. Peabody Coal Company has developed the specifications for the wells and sought bids for the actual drilling. It is expected that the wells will be drilled early in May.

  6. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-07-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, and a discussion of these is not repeated here. Rather, this report discusses the technical progress made during the period April 1 - June 30, 1995. A final topical report on the SEEC, Inc. demonstration of its technology for the transporting of coal combustion residues was completed during the quarter, although final printing of the report was accomplished early in July, 1995. The SEEC technology involves the use of Collapsible Intermodal Containers (CIC`s) developed by SEEC, and the transportation of such containers - filled with fly ash or other coal combustion residues - on rail coal cars or other transportation means. Copies of the final topical report, entitled {open_quotes}The Development and Testing of Collapsible Intermodal Containers for the Handling and Transport of Coal Combustion Residues{close_quotes} were furnished to the Morgantown Energy Technology Center. The Rapid Aging Test colums were placed in operation during the quarter. This test is to determine the long-term reaction of both the pneumatic and hydraulic mixtures to brine as a leaching material, and simulates the conditions that will be encountered in the actual underground placement of the coal combustion residues mixtures. The tests will continue for about one year.

  7. Experimental investigation of a molecular gate membrane for separation of carbon dioxide from flue gas

    SciTech Connect (OSTI)

    Kazama, S.; Kai, T.; Kouketsu, T.; Matsui, S.; Yamada, K.; Hoffman, J.S.; Pennline, H.W.

    2006-09-01

    Commercial-sized modules of the PAMAM dendrimer composite membrane with high CO2/N2 selectivity and CO2 permeance were developed according to the In-situ Modification (IM) method. This method utilizes the interfacial precipitation of membrane materials on the surface of porous, commercially available polysulfone (PSF) ultrafiltration hollow fiber membrane substrates. A thin layer of amphiphilic chitosan, which has a potential affinity for both hydrophobic PSF substrates and hydrophilic PAMAM dendrimers, was employed as a gutter layer directly beneath the inner surface of the substrate by the IM method. PAMAM dendrimers were then impregnated into the chitosan gutter layer to form a hybrid active layer for CO2 separation. Permeation experiments of the PAMAM dendrimer composite membrane were carried out using a humidified mixed CO2 / N2 feed gas at a pressure difference up to 97 kPa at ambient temperature. When conducted with CO2 (5%) / N2 (95%) feed gas at a pressure difference of 97 kPa, the PAMAM composite membrane exhibited an excellent CO2/N2 selectivity of 150 and a CO2 permeance of 1.7×10-7 m3(STP) m-2 s-1 kPa-1. The impact of various process parameters on the permeability and selectivity was also examined.

  8. Simulation of spray drying absorber for removal of HC1 in flue gas from incinerators

    SciTech Connect (OSTI)

    Uchida, S.; Tsuchiga, K.

    1984-04-01

    A theoretical study on the spray drying absorber in an HC1 removal process by lime slurries has been performed with a mathematical model which describes heat and mass transfer and fluid flows in the absorber. From heat and mass balances and a force balance for a moving droplet in the absorber, a set of first-order, nonlinear differential equations relating the amount of water, the gas and droplet temperatures, the drop velocity, the HC1 partial pressure, etc., along the axial direction of the tower was formulated. These relationships were numerically solved to give characteristic profiles in the tower. The results of the simulation based on this model were compared with experimental data and showed satisfactory agreement.

  9. ,"Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  10. ,"California Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  11. ,"California State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  12. U.S. Natural Gas Wet After Lease Separation, Reserves in Nonproducing

    U.S. Energy Information Administration (EIA) Indexed Site

    Reservoirs (Billion Cubic Feet) Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) U.S. Natural Gas Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 33,049 33,157 36,047 36,873 2000's 42,834 52,948 49,974 49,068 51,412 59,658 66,714 78,094 85,543 98,092 2010's 113,439 118,224 110,351 115,915 147,732 - = No Data Reported; -- = Not

  13. U.S. Nonassociated Natural Gas, Reserves in Nonproducing Reservoirs, Wet

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Reserves in Nonproducing Reservoirs, Wet (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Reserves in Nonproducing Reservoirs, Wet (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 27,760 27,526 30,570 31,235 2000's 37,639 46,321 43,401 43,165 45,996 53,387 60,669 71,204 78,863 90,477 2010's 104,340 104,964 90,801 93,697 120,492 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  14. Mercury removal in utility wet scrubber using a chelating agent

    DOE Patents [OSTI]

    Amrhein, Gerald T.

    2001-01-01

    A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

  15. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, New

    U.S. Energy Information Administration (EIA) Indexed Site

    Field Discoveries (Billion Cubic Feet) Field Discoveries (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, New Field Discoveries (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 193 1980's 365 335 161 220 156 143 88 110 67 208 1990's 141 69 13 245 530 248 222 1,360 107 394 2000's 387 1,287 229 447 34 119 40 46 107 263 2010's 102 611 151 63 327 - = No Data Reported; -- = Not Applicable; NA = Not

  16. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Acquisitions (Billion Cubic Feet) Acquisitions (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 6,586 845 908 1,062 987 2,071 1,960 1,350 938 678 2010's 2,469 1,884 2,150 2,843 4,589 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  17. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Adjustments (Billion Cubic Feet) Adjustments (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,925 1980's 1,053 -1,079 843 1,564 -486 695 425 177 437 415 1990's 57 257 567 -302 163 345 164 262 -706 143 2000's -605 499 499 202 -21 126 -54 276 455 877 2010's -482 390 385 -649 1,396 - = No Data Reported; -- = Not Applicable; NA =

  18. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Acquisitions (Billion Cubic Feet) Acquisitions (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 19,051 13,756 10,185 10,638 12,571 10,235 25,122 14,620 7,910 3,477 2010's 10,879 45,989 5,941 8,630 23,705 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release

  19. Influence of CO{sub 2} and O{sub 2} on the reaction of Ca(OH){sub 2} under spray-drying flue gas desulfurization conditions

    SciTech Connect (OSTI)

    Ho, C.S.; Shih, S.M.; Lee, C.D.

    1996-11-01

    The influence of CO{sub 2} and O{sub 2} in the flue gas on the reaction of hydrated lime sorbent with SO{sub 2} was studied using a fixed-bed differential reactor under conditions prevailing in the spray-drying flue gas desulfurization process. With the presence of CO{sub 2}, the sulfation and carbonation reactions of Ca(OH){sub 2} took place simultaneously until Ca(OH){sub 2} ceased to react. The CaCO{sub 3} produced reacted further to form CaSO{sub 3}{center_dot}{1/2}H{sub 2}O. The apparent sulfation rate, total reaction rate, and final total conversion of Ca(OH){sub 2} were greater than those for the case without CO{sub 2}. The final total conversion was about 1.45 times that for the latter case at the conditions of 1,000 ppm SO{sub 2}, 60 C, and 70% relative humidity. The same effect was observed whether CO{sub 2} was present with O{sub 2} or not. Kinetic expressions obtained by assuming chemical reaction control and considering the surface coverage by product crystals best represented the kinetic data.

  20. FULL-SCALE TESTING OF ENHANCED MERCURY CONTROL TECHNOLOGIES FOR WET FGD SYSTEMS

    SciTech Connect (OSTI)

    D.K. McDonald; G.T. Amrhein; G.A. Kudlac; D. Madden Yurchison

    2003-05-07

    Wet flue gas desulfurization (wet FGD) systems are currently installed on about 25% of the coal-fired utility generating capacity in the U.S., representing about 15% of the number of coal-fired units. Depending on the effect of operating parameters such as mercury content of the coal, form of mercury (elemental or oxidized) in the flue gas, scrubber spray tower configuration, liquid-to-gas ratio, and slurry chemistry, FGD systems can provide cost-effective, near-term mercury emissions control options with a proven history of commercial operation. For boilers already equipped with FGD systems, the incremental cost of any vapor phase mercury removal achieved is minimal. To be widely accepted and implemented, technical approaches that improve mercury removal performance for wet FGD systems should also have low incremental costs and have little or no impact on operation and SO{sub 2} removal performance. The ultimate goal of the Full-scale Testing of Enhanced Mercury Control for Wet FGD Systems Program was to commercialize methods for the control of mercury in coal-fired electric utility systems equipped with wet flue gas desulfurization (wet FGD). The program was funded by the U.S. Department of Energy's National Energy Technology Laboratory, the Ohio Coal Development Office within the Ohio Department of Development, and Babcock & Wilcox. Host sites and associated support were provided by Michigan South Central Power Agency (MSCPA) and Cinergy. Field-testing was completed at two commercial coal-fired utilities with wet FGD systems: (1) MSCPA's 55 MW{sub e} Endicott Station and (2) Cinergy's 1300 MW{sub e} Zimmer Station. Testing was conducted at these two locations because of the large differences in size and wet scrubber chemistry. Endicott employs a limestone, forced oxidation (LSFO) wet FGD system, whereas Zimmer uses Thiosorbic{reg_sign} Lime (magnesium enhanced lime) and ex situ oxidation. Both locations burn Ohio bituminous coal.

  1. Utah Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Utah Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,017 1980's 1,284 2,057 2,253 2,472 2,325 2,288 2,205 2,341 1,984 1,940 1990's 1,887 2,001 2,018 2,198 1,917 1,701 1,747 2,005 2,502 3,371 2000's 4,472 4,753 4,274 3,617 3,951 4,359 5,211 6,463 6,714 7,411 2010's 7,146 8,108 7,775 7,057 6,970 - = No Data

  2. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Proved Reserves (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 59,425 1980's 62,010 61,546 62,082 61,694 60,638 60,607 59,577 58,189 32,878 32,809 1990's 33,169 31,817 31,424 30,045 30,400 30,797 30,795 32,382 30,660 31,415 2000's 29,833 29,824 29,541 28,552 27,649 28,236 29,640 32,668 29,023 33,383

  3. U.S. Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Proved Reserves (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 208,335 1980's 206,259 209,434 209,254 209,046 205,984 202,202 201,109 196,428 176,999 175,428 1990's 177,576 175,325 173,309 170,490 171,939 173,476 175,147 175,721 172,443 176,159 2000's 186,510 191,743 195,561 197,145 201,200 213,308 220,416 247,789 255,035 283,879 2010's 317,647

  4. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Proved Reserves (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 148,910 1980's 144,249 147,888 147,172 147,352 145,346 141,595 141,532 138,239 144,121 142,619 1990's 144,407 143,508 141,885 140,445 141,539 142,679 144,352 143,339 141,783 144,744 2000's 156,677 161,921 166,020 168,593 173,551 185,072 190,776 215,121

  5. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Estimated Production from Reserves (Billion Cubic Feet) Estimated Production from Reserves (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Estimated Production from Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 3,405 1980's 3,405 3,316 3,248 3,355 3,518 3,454 3,443 3,351 3,192 3,099 1990's 2,936 2,968 3,031 2,868 2,907 2,886 2,938 3,022 3,136 3,313 2000's 3,299 3,193 2,988 2,855 2,742

  6. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Extensions (Billion Cubic Feet) Extensions (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,139 1980's 1,861 1,537 1,351 977 1,182 1,099 758 542 498 760 1990's 615 737 760 867 850 857 991 1,116 727 586 2000's 2,683 1,194 852 817 907 1,032 810 1,098 1,488 2,669 2010's 2,660 5,957 10,030 9,630 9,962 - = No Data Reported; -- = Not

  7. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Revision Decreases (Billion Cubic Feet) Decreases (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,209 1980's 2,941 2,561 4,516 3,815 2,999 3,163 2,903 2,755 27,612 3,130 1990's 2,571 3,479 1,844 2,723 3,002 2,328 2,013 3,241 3,937 8,705 2000's 4,546 3,232 2,637 2,790 3,170 2,034 2,782 1,804 7,385 2,698 2010's 3,964

  8. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Revision Increases (Billion Cubic Feet) Increases (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,517 1980's 5,283 4,349 5,580 3,695 4,313 4,308 3,856 3,734 4,152 4,603 1990's 4,804 3,698 2,850 3,239 4,519 3,527 3,234 4,925 5,005 11,226 2000's 3,884 3,259 3,587 3,044 4,009 3,281 5,372 5,400 2,943 5,522 2010's 4,983

  9. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales (Billion Cubic Feet) Sales (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Reserves Sales (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 6,921 1,145 1,064 1,040 1,004 1,655 1,726 1,115 662 564 2010's 1,146 1,338 1,131 1,733 4,058 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release

  10. U.S. Natural Gas, Wet After Lease Separation New Reservoir Discoveries in

    U.S. Energy Information Administration (EIA) Indexed Site

    Old Fields (Billion Cubic Feet) New Reservoir Discoveries in Old Fields (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,637 1980's 2,648 3,080 3,520 3,071 2,778 3,053 1,855 1,556 1,979 2,313 1990's 2,492 1,655 1,773 1,930 3,606 2,518 3,209 2,455 2,240 2,265 2000's 2,463 2,898 1,752 1,653 1,244 1,243 1,197 1,244 1,678 2,656 2010's

  11. U.S. Natural Gas, Wet After Lease Separation Reserves Acquisitions (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Acquisitions (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 25,641 14,600 11,093 11,700 13,558 12,306 27,082 15,970 8,848 4,155 2010's 13,348 47,873 8,091 11,473 28,294 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date:

  12. U.S. Natural Gas, Wet After Lease Separation Reserves Adjustments (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Adjustments (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 5,356 1980's 1,253 2,057 2,598 4,363 -2,413 -1,299 2,137 1,199 2,180 2,537 1990's 1,494 3,368 2,543 1,048 1,977 889 4,288 -730 -1,624 1,102 2000's -1,295 1,849 4,006 2,323 170 1,693 946 990 271 5,923 2010's 1,292 2,715 -810 693 4,905 - = No Data Reported; -- = Not Applicable; NA

  13. U.S. Natural Gas, Wet After Lease Separation Reserves Estimated Production

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Estimated Production (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Reserves Estimated Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 20,079 1980's 19,500 19,554 18,292 16,590 18,032 16,798 16,401 16,904 17,466 17,752 1990's 18,003 18,012 18,269 18,641 19,210 18,874 19,783 20,134 19,622 19,856 2000's 20,164 20,642 20,248 20,231 20,017 19,259 19,373 20,318 21,415 22,537 2010's 23,224

  14. U.S. Natural Gas, Wet After Lease Separation Reserves Revision Decreases

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Decreases (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 17,300 1980's 16,531 14,413 20,141 18,385 15,418 17,045 18,557 14,933 39,569 24,624 1990's 14,024 16,189 12,532 12,853 16,509 13,457 13,757 17,655 23,419 33,051 2000's 16,938 21,617 20,202 22,495 27,291 20,647 23,739 17,468 35,195 34,563 2010's 38,339 56,127 88,119

  15. U.S. Natural Gas, Wet After Lease Separation Reserves Revision Increases

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Increases (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 17,077 1980's 17,668 17,156 20,596 18,442 18,751 19,732 22,392 18,455 24,638 27,844 1990's 19,861 20,758 18,906 18,394 22,345 21,548 18,034 22,712 29,401 44,233 2000's 24,394 19,179 21,240 20,780 28,116 23,362 21,640 33,404 31,941 32,664 2010's 42,394 56,015 42,505

  16. U.S. Natural Gas, Wet After Lease Separation Reserves Sales (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Sales (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Reserves Sales (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 21,355 11,885 10,665 10,593 11,583 9,632 23,904 15,518 7,911 4,377 2010's 10,582 44,575 9,950 10,186 21,729 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring

  17. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Estimated

    U.S. Energy Information Administration (EIA) Indexed Site

    Production from Reserves (Billion Cubic Feet) Estimated Production from Reserves (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Estimated Production from Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 16,674 1980's 16,095 16,238 15,044 13,235 14,514 13,344 12,958 13,553 14,274 14,653 1990's 15,067 15,044 15,238 15,773 16,303 15,988 16,845 17,112 16,486 16,543 2000's 16,863 17,451 17,260

  18. U.S. Nonassociated Natural Gas, Wet After Lease Separation, New Field

    U.S. Energy Information Administration (EIA) Indexed Site

    Discoveries (Billion Cubic Feet) New Field Discoveries (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, New Field Discoveries (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 3,086 1980's 2,264 3,535 2,624 1,408 2,428 897 1,034 1,018 1,610 1,280 1990's 1,900 802 655 682 1,411 1,461 1,269 1,387 1,009 1,228 2000's 1,664 2,378 1,145 805 756 854 385 768 1,122 1,160 2010's 793 376 629 200 344 - = No Data

  19. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Adjustments (Billion Cubic Feet) Adjustments (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 3,431 1980's 200 3,136 1,755 2,799 -1,927 -1,994 1,712 1,022 1,743 2,122 1990's 1,437 3,111 1,976 1,350 1,814 544 4,124 -992 -918 959 2000's -671 1,355 3,505 2,121 191 1,567 1,000 714 -184 5,046 2010's 1,774 2,325 -1,195 1,342 3,509 - = No Data

  20. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Extensions (Billion Cubic Feet) Extensions (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8,193 1980's 7,896 9,442 7,403 6,286 7,506 6,436 5,601 4,276 6,634 5,863 1990's 7,672 4,561 4,135 5,509 6,449 6,347 7,198 10,063 7,903 6,815 2000's 12,866 15,987 14,616 16,378 18,161 21,037 22,024 27,157 26,312 40,831 2010's 43,623 41,678 37,023

  1. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Revision Decreases (Billion Cubic Feet) Decreases (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 13,091 1980's 13,590 11,852 15,625 14,570 12,419 13,882 15,654 12,178 11,957 21,494 1990's 11,453 12,710 10,688 10,130 13,507 11,129 11,744 14,414 19,482 24,346 2000's 12,394 18,385 17,565 19,705 24,121 18,613 20,957 15,664 27,810

  2. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    Revision Increases (Billion Cubic Feet) Increases (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,560 1980's 12,385 12,807 15,016 14,747 14,438 15,424 18,536 14,721 20,486 23,241 1990's 15,057 17,060 16,056 15,155 17,826 18,021 14,800 17,787 24,396 33,007 2000's 20,505 15,917 17,653 17,736 24,107 20,081 16,268 28,004 28,998

  3. U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves Sales

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Sales (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, Reserves Sales (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 14,436 10,733 9,601 9,553 10,579 7,977 22,178 14,403 7,249 3,813 2010's 9,436 43,237 8,819 8,453 17,671 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release

  4. ,"Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  5. ,"Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  6. ,"U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  7. ,"Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  8. ,"Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  9. ,"Alaska Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alaska Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  10. ,"Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  11. ,"Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  12. ,"Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  13. ,"California - Coastal Region Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - Coastal Region Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  14. ,"California - Coastal Region Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - Coastal Region Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  15. ,"California - Los Angeles Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - Los Angeles Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  16. ,"California - San Joaquin Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - San Joaquin Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  17. ,"California Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  18. ,"California Federal Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Federal Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next

  19. ,"California Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  20. ,"California State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  1. ,"Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  2. ,"Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  3. ,"Florida Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Florida Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  4. ,"Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015"

  5. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes. Volume 2, Duct spray drying: Final report

    SciTech Connect (OSTI)

    Jozewicz, W.; Rochelle, G.T.

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide [Ca(OH){sub 2}] slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  6. WETTABILITY ALTERATION OF POROUS MEDIA TO GAS-WETTING FOR IMPROVING PRODUCTIVITY AND INJECTIVITY IN GAS-LIQUID FLOWS

    SciTech Connect (OSTI)

    Abbas Firoozabadi

    2002-10-21

    The authors have performed a number of imbibition tests with the treated and untreated cores in nC{sub 10}, nC{sub 14}, and nC{sub 16} and a natural gas condensate liquid. Imbibition tests for nC{sub 14} and nC{sub 16} were also carried out at elevated temperatures of 100 C and 140 C. An experimental polymer synthesized for the purpose of this project was used in core treatment. Imbibition results are very promising and imply liquid condensate mobility enhancement in the treated core. They also performed flow tests to quantify the increase in well deliverability and to simulate flow under realistic field conditions. In the past we have performed extensive testing of wettability alteration in intermediate gas wetting for polymer FC759 at temperatures of 24 C and 90 C. The results were promising for the purpose of gas well deliverability improvement in gas condensate wells. We used FC759 to lower the surface energy of various rocks. The model fluids nC{sub 10}, and nC{sub 14} were used to represent condensate liquid, and air was used as the gas phase. A new (L-16349) polymer, which has been recently synthesized for the purpose of the project, was used in the work to be presented here. L-16349 is a water-soluble fluorochemical polymer, with low order, neutral PH and very low volatile organic compound (VOC < 9.1 g/l). It is light yellow in appearance and density in 25% solution is 1.1 g/cc. Polymer L-16349 is very safe from environmental considerations and it is economical for our purpose. In this work, in addition to nC{sub 10}, and nC{sub 14}, we used two other liquids nC{sub 16}, and a liquid condensate in order to study the effect of wettability alteration with a broader range of fluids.

  7. Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture

    SciTech Connect (OSTI)

    Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

    2012-04-24

    An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

  8. U.S. Natural Gas, Wet After Lease Separation Reserves Extensions (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Extensions (Billion Cubic Feet) U.S. Natural Gas, Wet After Lease Separation Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 9,332 1980's 9,757 10,979 8,754 7,263 8,688 7,535 6,359 4,818 7,132 6,623 1990's 8,287 5,298 4,895 6,376 7,299 7,204 8,189 11,179 8,630 7,401 2000's 15,550 17,183 15,468 17,195 19,068 22,069 22,834 28,255 27,800 43,500 2010's 46,283 47,635 47,053 51,074 47,071 - = No Data Reported;

  9. Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 12, December 1, 1993--February 28, 1994

    SciTech Connect (OSTI)

    1994-12-31

    The NOXSO process is a dry, post-combustion flue gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from the flue gas of a coal-fired utility boiler. In the process, the SO{sub 2} is reduced to sulfur by-product and the NO{sub x} is reduced to nitrogen and oxygen. It is predicted that the process can economically remove 90% of the acid rain precursor gases from the flue gas stream in a retrofit or new facility. The objective of the NOXSO Demonstration Project is to design, construct, and operate a flue gas treatment system utilizing the NOXSO process. The effectiveness of the process will be demonstrated by achieving significant reductions in emissions of sulfur and nitrogen oxides. In addition, sufficient operating data will be obtained to confirm the process economics and provide a basis to guarantee performance on a commercial scale. The project is presently in the project definition and preliminary design phase. Data obtained during pilot plant testing which was completed on July 30, 1993 is being incorporated in the design of the commercial size plant. A suitable host site to demonstrate the NOXSO process on a commercial scale is presently being sought. The plant general arrangement has been revised to incorporate principles used in the design of fluidized catalytic cracking (FCC) plants. A NOXSO plant availability analysis was prepared using operating experience from the recently completed pilot plant as a basis. The impact of water desorption in the sorbent heater and water adsorption in the sorbent cooler has been quantified and incorporated into the NOXSO process simulator. NOXSO process economics has been updated based on the present design. Capital cost for a 500 MW plant designed to remove 98% of the SO{sub 2} and 85% of the NO{sub x} is estimated at $247/kW.

  10. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-12-31

    This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

  11. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, [October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Thomasson, E.M.; Chugh, Y.P.; Esling, S.; Honaker, R.; Paul, B.; Sevin, H.

    1994-01-01

    The ``Management of Dry Flue Gas Desulfurization By-Products in Underground Mines`` program is one of the largest programs ever undertaken by the Mining Engineering Department of Southern Illinois university, both in terms of complexity and in terms of funding. Total funding over the expected four-year extent of the program, including both Department of Energy, matching Southern Illinois University funds, and contributed funds, this program exceeds three million dollars. The number of cooperating organizations adds to the management complexity of the program. It was believed, therefore, that sound management plan and management base is essential for the efficient and effective conduct of the program. This first quarter period (i.e., October 1--December 31, 1993) was developed to establishing the management base, developing a sound management plan, developing a test plan, and developing sound fiscal management and control. Actual technical operations, such as residue sample acquisition, residue analyses, groundwater sample acquisition and analyses, and material handling studies will get underway early in the next quarter (i.e., January 1--March 31, 1994). Some early results of residue analyses and groundwater analyses should be available by the end of the second quarter. These results will be reported in the next Technical Progress Report.

  12. Table 9. U.S. proved reserves of natural gas, wet after lease separation, 2001-1

    U.S. Energy Information Administration (EIA) Indexed Site

    proved reserves of natural gas, wet after lease separation, 2001-14" "billion cubic feet" ,,,"Revisionsa","Net of Salesb"," "," ","New Reservoir",,,"Provedd","Change" ,,"Net","and","and",,"New Field","Discoveries","Totalc","Estimated","Reserves","from"

  13. Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas

    SciTech Connect (OSTI)

    C. Jean Bustard; Charles Lindsey; Paul Brignac

    2006-05-01

    This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection

  14. Enhanced NO{sub x} removal in wet scrubbers using metal chelates. Final report, Volume 1

    SciTech Connect (OSTI)

    Smith, K.; Lani, B.; Berisko, D.; Schultz, C.; Carlson, W.; Benson, L.B.

    1992-12-01

    Successful pilot plant tests of simultaneous removal of S0{sub 2} and NO{sub x} in a wet lime flue gas desulfurization system were concluded in December. The tests, at up to 1.5 MW(e) capacity, were conducted by the Cincinnati Gas and Electric Company and Dravo Lime Company for the US Department of Energy at a pilot facility at the Miami Fort station of CG&E near Cincinnati, Ohio. The pilot plant scrubbed a slipstream of flue gas from Unit 7, a 530 MW coal-fired electric generating unit. Tests were conducted in three phases between April and December. The technology tested was wet scrubbing with Thiosorbic{reg_sign} magnesium-enhanced lime for S0{sub 2} removal and simultaneous NO scrubbing with ferrous EDTA, a metal chelate. Magnesium-enhanced lime-based wet scrubbing is used at 20 full-scale high-sulfur coal-fired electric generating units with a combined capacity of 8500 NW. Ferrous EDTA reacts with nitric oxide, NO, which comprises about 95% of NO{sub x} from coal-fired boilers. In this report, although not precise, NO and NO{sub x} are used interchangably. A major objective of the tests was to combine NO{sub x} removal using ferrous EDTA, a developing technology, with SO{sub 2} removal using wet lime FGD, already in wide commercial use. If successful, this could allow wide application of this NO{sub x} removal technology.

  15. Evaluation of alkali metal sulfate dew point measurement for detection of hot corrosion conditions in PFBC flue gas

    SciTech Connect (OSTI)

    Helt, J.E.

    1980-11-01

    Hot corrosion in combustion systems is, in general, the accelerated oxidation of nickel, cobalt, and iron-base alloys which occurs in the presence of small amounts of impurities - notably, sodium, sulfur, chlorine, and vanadium. There is no real consensus on which mechanisms are primarily responsible for high-temperature corrosion. One point generally accepted, however, is that corrosion reactions take place at an appreciable rate only in the presence of a liquid phase. When coal is the fuel for combustion, hot corrosion may occur in the form of accelerated sulfidation. It is generally agreed by investigators that molten alkali metal sulfates (Na/sub 2/SO/sub 4/ and K/sub 2/SO/sub 4/) are the principal agents responsible for the occurrence of sulfidation. Although molten sodium sulfate by itself appears to have little or no effect on the corrosion of metal alloys, its presence may increase the accessibility of the bare metal surface to the external atmosphere. If this atmosphere contains either a reductant and/or an oxide such as SiO/sub 2/, SO/sub 3/, or NaOH(Na/sub 2/O), corrosion is likely to occur. Alkali metal sulfate dew point measurement was evaluated as a means of anticipating hot corrosion in the gas turbine of a pressurized fluidized-bed combustion system. The hot corrosion mechanism and deposition rate theory were reviewed. Two methods of dew point measurement, electrical conductivity and remote optical techniques, were identified as having a potential for this application. Both techniques are outlined; practical measurement systems are suggested; and potential problem areas are identified.

  16. Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas

    DOE Patents [OSTI]

    Chang, Shih-Ger; Liu, David K.; Griffiths, Elizabeth A.; Littlejohn, David

    1988-01-01

    described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

  17. Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use

    SciTech Connect (OSTI)

    Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

    2012-07-31

    field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture

  18. Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Pilot-Scale Test Results

    SciTech Connect (OSTI)

    Gary M. Blythe

    2006-03-01

    This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, ''Field Testing of a Wet FGD Additive.'' The objective of the project is to demonstrate the use of a flue gas desulfurization (FGD) additive, Degussa Corporation's TMT-15, to prevent the reemissions of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate that the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine TMT salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project will conduct pilot and full-scale tests of the TMT-15 additive in wet FGD absorbers. The tests are intended to determine required additive dosage requirements to prevent Hg{sup 0} reemissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Power River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, TXU Generation Company LP, Southern Company, and Degussa Corporation. TXU Generation has provided the Texas lignite/PRB co-fired test site for pilot FGD tests, Monticello Steam Electric Station Unit 3. Southern Company is providing the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot and full-scale jet bubbling reactor (JBR) FGD systems to be tested. A third utility, to be named later, will provide the high-sulfur Eastern bituminous coal full-scale FGD test site. Degussa Corporation is providing the TMT-15 additive and technical support to the test program. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing in

  19. ,"Louisiana - South Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana - South Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  20. ,"Lower 48 States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Lower 48 States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  1. ,"California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  2. ,"California - Los Angeles Basin Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - Los Angeles Basin Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014

  3. ,"California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  4. ,"California - San Joaquin Basin Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - San Joaquin Basin Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014

  5. ,"California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  6. ,"California Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  7. ,"California State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  8. Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Task 3 Full-scale Test Results

    SciTech Connect (OSTI)

    Gary Blythe

    2007-05-01

    This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project is to demonstrate the use of a flue gas desulfurization (FGD) additive, Degussa Corporation's TMT-15, to prevent the reemission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate whether the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine TMT salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project is conducting pilot- and full-scale tests of the TMT-15 additive in wet FGD absorbers. The tests are intended to determine required additive dosages to prevent Hg{sup 0} reemissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Power River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, TXU Generation Company LP, Southern Company, and Degussa Corporation. TXU Generation has provided the Texas lignite/PRB cofired test site for pilot FGD tests, Monticello Steam Electric Station Unit 3. Southern Company is providing the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot- and full-scale jet bubbling reactor (JBR) FGD systems to be tested. IPL, an AES company, provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Degussa Corporation is providing the TMT-15 additive and technical support to the test program as cost sharing. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing

  9. Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems

    SciTech Connect (OSTI)

    Gary Blythe; Conor Braman; Katherine Dombrowski; Tom Machalek

    2010-12-31

    This document is the final technical report for Cooperative Agreement DE-FC26-04NT41992, 'Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,' which was conducted over the time-period January 1, 2004 through December 31, 2010. The objective of this project has been to demonstrate at pilot scale the use of solid catalysts and/or fixed-structure mercury sorbents to promote the removal of total mercury and oxidation of elemental mercury in flue gas from coal combustion, followed by wet flue gas desulfurization (FGD) to remove the oxidized mercury at high efficiency. The project was co-funded by the U.S. DOE National Energy Technology Laboratory (DOE-NETL), EPRI, Great River Energy (GRE), TXU Energy (now called Luminant), Southern Company, Salt River Project (SRP) and Duke Energy. URS Group was the prime contractor. The mercury control process under development uses fixed-structure sorbents and/or catalysts to promote the removal of total mercury and/or oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. Oxidized mercury not adsorbed is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The project has tested candidate materials at pilot scale and in a commercial form, to provide engineering data for future full-scale designs. Pilot-scale catalytic oxidation tests have been completed for periods of approximately 14 to19 months at three sites, with an additional round of pilot-scale fixed-structure sorbent tests being conducted at one of those sites. Additionally, pilot-scale wet FGD tests have been conducted downstream of mercury oxidation catalysts at a total of four sites. The sites include the two of three sites from this project and two sites where catalytic oxidation pilot testing was conducted as part of a previous DOE-NETL project. Pilot-scale wet FGD tests were also conducted at a fifth site, but with no catalyst or fixed

  10. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992

    SciTech Connect (OSTI)

    Sublette, K.L.

    1992-12-31

    With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

  11. Field Testing of a Wet FGD Additive for Enhanced Mercury Control

    SciTech Connect (OSTI)

    Gary Blythe; MariJon Owens

    2007-12-31

    This document is the final report for DOE-NETL Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project has been to demonstrate the use of two flue gas desulfurization (FGD) additives, Evonik Degussa Corporation's TMT-15 and Nalco Company's Nalco 8034, to prevent the re-emission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project was intended to demonstrate whether such additives can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project involved pilot- and full-scale tests of the additives in wet FGD absorbers. The tests were intended to determine required additive dosages to prevent Hg{sup 0} re-emissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Powder River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, Luminant Power (was TXU Generation Company LP), Southern Company, IPL (an AES company), Evonik Degussa Corporation and the Nalco Company. Luminant Power provided the Texas lignite/PRB co-fired test site for pilot FGD tests and project cost sharing. Southern Company provided the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, the pilot- and full-scale jet bubbling reactor (JBR) FGD systems tested, and project cost sharing. IPL provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Evonik Degussa Corporation provided the TMT-15 additive, and the Nalco Company provided the Nalco 8034 additive. Both companies also supplied technical support to the test program as in-kind cost sharing. The project was conducted in six tasks. Of the six tasks, Task 1 involved project planning and Task 6 involved

  12. Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Task 5 Full-Scale Test Results

    SciTech Connect (OSTI)

    Gary Blythe; MariJon Owens

    2007-12-01

    This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project is to demonstrate the use of two flue gas desulfurization (FGD) additives, Evonik Degussa Corporation's TMT-15 and Nalco Company's Nalco 8034, to prevent the re-emission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate whether the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project is conducting pilot- and full-scale tests of the additives in wet FGD absorbers. The tests are intended to determine required additive dosages to prevent Hg{sup 0} re-emissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Powder River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, Luminant Power (was TXU Generation Company LP), Southern Company, IPL (an AES company), Evonik Degussa Corporation and the Nalco Company. Luminant Power has provided the Texas lignite/PRB co-fired test site for pilot FGD tests and cost sharing. Southern Company has provided the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot- and full-scale jet bubbling reactor (JBR) FGD systems tested. IPL provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Evonik Degussa Corporation is providing the TMT-15 additive, and the Nalco Company is providing the Nalco 8034 additive. Both companies are also supplying technical support to the test program as in-kind cost sharing. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management

  13. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  14. Development of a Novel Gas Pressurized Process-Based Technology for CO2 Capture from Post-Combustion Flue Gases Preliminary Year 1 Techno-Economic Study Results and Methodology for Gas Pressurized Stripping Process

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2013-03-01

    Under the DOE’s Innovations for Existing Plants (IEP) Program, Carbon Capture Scientific, LLC (CCS) is developing a novel gas pressurized stripping (GPS) process to enable efficient post-combustion carbon capture (PCC) from coal-fired power plants. A technology and economic feasibility study is required as a deliverable in the project Statement of Project Objectives. This study analyzes a fully integrated pulverized coal power plant equipped with GPS technology for PCC, and is carried out, to the maximum extent possible, in accordance to the methodology and data provided in ATTACHMENT 3 – Basis for Technology Feasibility Study of DOE Funding Opportunity Number: DE-FOA-0000403. The DOE/NETL report on “Cost and Performance Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity (Original Issue Date, May 2007), NETL Report No. DOE/NETL-2007/1281, Revision 1, August 2007” was used as the main source of reference to be followed, as per the guidelines of ATTACHMENT 3 of DE-FOA-0000403. The DOE/NETL-2007/1281 study compared the feasibility of various combinations of power plant/CO2 capture process arrangements. The report contained a comprehensive set of design basis and economic evaluation assumptions and criteria, which are used as the main reference points for the purpose of this study. Specifically, Nexant adopted the design and economic evaluation basis from Case 12 of the above-mentioned DOE/NETL report. This case corresponds to a nominal 550 MWe (net), supercritical greenfield PC plant that utilizes an advanced MEAbased absorption system for CO2 capture and compression. For this techno-economic study, CCS’ GPS process replaces the MEA-based CO2 absorption system used in the original case. The objective of this study is to assess the performance of a full-scale GPS-based PCC design that is integrated with a supercritical PC plant similar to Case 12 of the DOE/NETL report, such that it corresponds to a nominal 550 MWe

  15. JV Task-123 Determination of Trace Element Concentrations at an Eastern Bituminous Coal Plant Employing an SCR and Wet FGD

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-05-01

    The Energy & Environmental Research Center (EERC), in partnership with Babcock & Wilcox (B&W) and with funding from U.S. Department of Energy (DOE), conducting tests to prove that a high level of mercury control (>90%) can be achieved at a power plant burning a high-sulfur eastern bituminous coal. With funding from the Electric Power Research Institute (EPRI), DOE, and Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates Program, the EERC completed an additional sampling project to provide data as to the behavior of a number of trace elements across the various pollution control devices, with a special emphasis on the wet flue gas desulfurization (FGD) system. Results showed that the concentrations of almost all the elements of interest leaving the stack were very low, and a high percentage of the trace elements were captured in the electrostatic precipitator (ESP) (for most, >80%). Although, with a few exceptions, the overall mass balances were generally quite good, the mass balances across the wet FGD were more variable. This is most likely a result of some of the concentrations being very low and also the uncertainties in determining flows within a wet FGD.

  16. Increase Natural Gas Energy Efficiency | OpenEI Community

    Open Energy Info (EERE)

    Blog entry Discussion Document Event Poll Question Keywords Author Apply There is no matching content in the group. Group links The technology of Condensing Flue Gas Heat Recovery...

  17. Large-Scale Mercury Control Technology Testing for Lignite-Fired Utilities - Oxidation Systems for Wet FGD

    SciTech Connect (OSTI)

    Steven A. Benson; Michael J. Holmes; Donald P. McCollor; Jill M. Mackenzie; Charlene R. Crocker; Lingbu Kong; Kevin C. Galbreath

    2007-03-31

    Mercury (Hg) control technologies were evaluated at Minnkota Power Cooperative's Milton R. Young (MRY) Station Unit 2, a 450-MW lignite-fired cyclone unit near Center, North Dakota, and TXU Energy's Monticello Steam Electric Station (MoSES) Unit 3, a 793-MW lignite--Powder River Basin (PRB) subbituminous coal-fired unit near Mt. Pleasant, Texas. A cold-side electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber are used at MRY and MoSES for controlling particulate and sulfur dioxide (SO{sub 2}) emissions, respectively. Several approaches for significantly and cost-effectively oxidizing elemental mercury (Hg{sup 0}) in lignite combustion flue gases, followed by capture in an ESP and/or FGD scrubber were evaluated. The project team involved in performing the technical aspects of the project included Babcock & Wilcox, the Energy & Environmental Research Center (EERC), the Electric Power Research Institute, and URS Corporation. Calcium bromide (CaBr{sub 2}), calcium chloride (CaCl{sub 2}), magnesium chloride (MgCl{sub 2}), and a proprietary sorbent enhancement additive (SEA), hereafter referred to as SEA2, were added to the lignite feeds to enhance Hg capture in the ESP and/or wet FGD. In addition, powdered activated carbon (PAC) was injected upstream of the ESP at MRY Unit 2. The work involved establishing Hg concentrations and removal rates across existing ESP and FGD units, determining costs associated with a given Hg removal efficiency, quantifying the balance-of-plant impacts of the control technologies, and facilitating technology commercialization. The primary project goal was to achieve ESP-FGD Hg removal efficiencies of {ge}55% at MRY and MoSES for about a month.

  18. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 3, Product development of gypsum, Phase 1

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    In the way of background information about 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. The first generation process begun in 1973, called the Thiosorbic® Process, was a technical breakthrough that offered significantly improved operating and performance characteristics compared with competing FGD technologies. The process is described as Flow Diagram "A" in Figure 1. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the sludge solids for compunction in a landfill also consumes fly ash that otherwise may be marketable.

  19. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 2, Product development of magnesium hydroxide, Phase 1

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    In the way of background information about 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. The first generation process begun in 1973, called the Thiosorbic® Process, was a technical breakthrough that offered significantly improved operating and performance characteristics compared with competing FGD technologies. The process is described as Flow Diagram "A" in figure 1. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the sludge solids for compaction in a landfill also consumes fly ash that otherwise may be marketable.

  20. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, Chang Y.

    1993-01-01

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO.sub.2 and NO.sub.x.