Sample records for weight sulfur pounds

  1. Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are nowTotal" (Percent) Type: Sulfur Content API Gravity Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions,

  2. WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,

    E-Print Network [OSTI]

    Minimization/ Volume Reduction 0 Solid Radioactive Waste $2,168 $0 $2,168 Vial Crusher for glass vialsWASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED, REUSED, RECYCLED OR CONSERVED IN 2004 WASTE TYPE DESCRIPTION DETAILS * Automotive Waste Substitution 510 Hazardous Waste $1,020 $1,000 $1,000 Aqueous Solvent

  3. WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,

    E-Print Network [OSTI]

    labeled chemicals Waste Minimization/ Volume Reduction 0 Solid Radioactive Waste $2,168 $3,795 $2,168 VialWASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED, REUSED, RECYCLED OR CONSERVED IN 2003 WASTE TYPE DESCRIPTION DETAILS * Radioactive Waste Source Reduction 1,500 Radioactive Waste $6,000 $2,500 $6,000 Waste

  4. Weed Busters: How to Pound Threadleaf Groundsel

    E-Print Network [OSTI]

    McGinty, Allan; Hart, Charles R.; Cadenhead, J. F.

    2005-10-05T23:59:59.000Z

    L-5470 9/05 How to Pound Threadleaf Groundsel (Senecio) Safe and effective three-step ways to control threadleaf groundsel Weed Treatment Series Allan McGinty, Charles Hart and J. F. Cadenhead Extension Range Specialists The Texas A&M University...

  5. An analysis of Ezra Pound's attitudes in the Pisan Cantos

    E-Print Network [OSTI]

    Mackin, Samuel Jack

    1967-01-01T23:59:59.000Z

    United SCates coaman4 post, at Javsgna and thence co genoa for interrogation, lS after being held under house arrest at Genoa for several weeks, he was transferred to Che kary Disciplinary Training Center at Pisa, Italy, where he was held from Ney... Cent in the medical compound, where he recovered. It was here at the Pisa GTC that Che first draft of the ~L C~gg@g was written. The ~@~CQgQg are a record of Pound~a life and mind during the time Chat he wae imprisoned at Pisai 17?~era pound ac...

  6. Potential Supply Impacts of Removal of 1-Pound RVP Waiver

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    trends, and current laws and regulations. The EIA's Annual Energy Outlook 2002 (AEO2002) is usedPotential Supply Impacts of Removal of 1-Pound RVP Waiver September 2002 #12;ii Energy Information by the Office of Oil and Gas of the Energy Information Administration. General questions concerning the report

  7. Pounding and impact of base isolated buildings due to earthquakes

    E-Print Network [OSTI]

    Agarwal, Vivek Kumar

    2005-08-29T23:59:59.000Z

    ...............................................................................12 1.2.1. Fixed base buildings.....................................................................12 1.2.2. Base isolated buildings.................................................................12 1.3. Study objective.........................................................................24 2.2.1. Single degree of freedom system..................................................24 2.2.2. Two degree of freedom system ....................................................28 2.3. Base isolation with building pounding...

  8. Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams

    SciTech Connect (OSTI)

    Siriwardane, Ranjan

    1999-09-30T23:59:59.000Z

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  9. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01T23:59:59.000Z

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  10. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H. (LaJolla, CA)

    1983-12-20T23:59:59.000Z

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  11. Pound Ridge, New York: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal PwerPerkins County, Nebraska: EnergyPiratiniEdwards,PoseyPoudre Valley R E A, Inc JumpPound

  12. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    None

    2010-10-01T23:59:59.000Z

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key parts—a positive and negative electrode and an electrolyte—that exchange ions to store and release electricity. Using different materials for these components changes a battery’s chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  13. Pound-Rebka experiment and torsion in the Schwarzschild spacetime

    SciTech Connect (OSTI)

    Maluf, J. W.; Ulhoa, S. C.; Faria, F. F. [Instituto de Fisica, Universidade de Brasilia, C. P. 04385, 70.919-970 Brasilia DF (Brazil)

    2009-08-15T23:59:59.000Z

    We develop some ideas discussed by E. Schucking [arXiv:0803.4128] concerning the geometry of the gravitational field. First, we address the concept according to which the gravitational acceleration is a manifestation of the space-time torsion, not of the curvature tensor. It is possible to show that there are situations in which the geodesic acceleration of a particle may acquire arbitrary values, whereas the curvature tensor approaches zero. We conclude that the space-time curvature does not affect the geodesic acceleration. Then we consider the Pound-Rebka experiment, which relates the time interval {delta}{tau}{sub 1} of two light signals emitted at a position r{sub 1}, to the time interval {delta}{tau}{sub 2} of the signals received at a position r{sub 2}, in a Schwarzschild type gravitational field. The experiment is determined by four space-time events. The infinitesimal vectors formed by these events do not form a parallelogram in the (t,r) plane. The failure in the closure of the parallelogram implies that the space-time has torsion. We find the explicit form of the torsion tensor that explains the nonclosure of the parallelogram.

  14. Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations set limits on the sulfur content of allowable fuels (1.0% by weight, dry basis) for combustion, as well as for the heat input of any fuel burning equipment (250,000 Btu/hour)....

  15. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01T23:59:59.000Z

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  16. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01T23:59:59.000Z

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  17. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07T23:59:59.000Z

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  18. DSRP, direct sulfur production

    SciTech Connect (OSTI)

    McMichael, W.J.; Agarwal, S.K.; Jang, B.L.; Howe, G.B. [Research Triangle Institute, Research Triangle Park, NC (United States); Chen, D.H.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1993-06-01T23:59:59.000Z

    The objective of this work is to demonstrate on a bench-scale the Direct Sulfur Recovery Process (DSRP) for up to 99 percent or higher recovery of sulfur (as elemental sulfur) from regeneration off-gases and coal-gas produced in integrated gasification combined cycle (IGCC) power generating systems. Fundamental kinetic and thermodynamic studies will also be conducted to enable development of a model to predict DSRP performance in large-scale reactors and to shed light on the mechanism of DSRP reactions. The ultimate goal of the project is to advance the DSRP technology to the point where industry is willing to support its further development.

  19. Sulfur Dioxide Regulations (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

  20. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

    1981-01-01T23:59:59.000Z

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  1. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

    1996-01-01T23:59:59.000Z

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

  2. Understanding Pound-Drever-Hall locking using voltage controlled radio-frequency oscillators: An undergraduate experiment

    E-Print Network [OSTI]

    Le Roy, Robert J.

    Understanding Pound-Drever-Hall locking using voltage controlled radio-frequency oscillators. The three main pieces of equipment are a commercial voltage controlled oscillator, a resonating cavity of the voltage controlled oscillator. The cavity resonance is then observed by scanning the frequency

  3. Why should I recycle? The average American generates 4.5 pounds of waste daily.

    E-Print Network [OSTI]

    Tsien, Roger Y.

    Why should I recycle? The average American generates 4.5 pounds of waste daily. Instead of throwing paper and containers in the trash,recycle them in single-stream receptacles conveniently located throughout campus.These guidelines will help you recycle more and waste less. What's recyclable? · Mixed

  4. 37The Oldest Lunar Rocks Apollo astronauts recovered over 840 pounds of lunar rocks, and during

    E-Print Network [OSTI]

    37The Oldest Lunar Rocks Apollo astronauts recovered over 840 pounds of lunar rocks, and during applied to the different rock samples. Location Mission Rock Type Age (Myr) Mare Tranquillitatis Apollo-11 Basalt 3,500 Oceanus Procellarum Apollo-12 Basalt 3,200 Fra Mauro Formation Apollo-14 Basalt 4,150 Apollo

  5. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27T23:59:59.000Z

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  6. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08T23:59:59.000Z

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  7. Problems #3, Math 204, Dr. M. Bohner. Sep 10, 2003. Due Sep 15, 11 am. 12. A tank has ten gallons of water in which two pounds of salt has been dissolved. Brine with

    E-Print Network [OSTI]

    Bohner, Martin

    of water in which two pounds of salt has been dissolved. Brine with 1.5 pound of salt per gallon enters

  8. Precision vertical mixer processes 30,000 pound batch of solid rocket propellants

    SciTech Connect (OSTI)

    Not Available

    1986-11-01T23:59:59.000Z

    The world's largest solid rocket propellant mixer has been singled out for Honors in the mixers and blenders category of the 1986 Chemical Processing Vaaler Awards competition. The mixer, which is four times larger than any heretofore used, was specially designed and built for one of the nations' foremost manufacturers of rocket propellants. Developments in the fields of metallurgy, material handling, computerization and electronics permitted the giant step of manufacturing propellants in batch sizes up to 30,000 pounds. Until this time, 7000 pounds was considered the maximum size batch within the scope of hazards analysis. The vertical design of the mixer lends itself to an effective fire protection system. Infra-red detectors are used to sense a sudden heat rise. Should an emergency situation arise once the bowl is in the mix position and under vacuum, the protection system will activate within twelve seconds, deluge the product zone with water, rapidly drop the bowl and simultaneously disconnect the electric power. The design encompasses remote operation and emphasizes safety and reliability. The mixer permits propellant manufacturers to safely produce more uniform, even burning products. Its large batch size simplifies the problems with multiple batches within a simple engine. By reducing labor costs and affording other manufacturing economies, it increases productivity while cutting costs.

  9. Sugar yields from dilute sulfuric acid and sulfur dioxide pretreatments and subsequent enzymatic hydrolysis of switchgrass

    E-Print Network [OSTI]

    California at Riverside, University of

    Sugar yields from dilute sulfuric acid and sulfur dioxide pretreatments and subsequent enzymatic Dilute sulfuric acid Sulfur dioxide Biofuels Switchgrass a b s t r a c t Dacotah switchgrass was pretreated with sulfuric acid concentrations of 0.5, 1.0, and 2.0 wt.% at 140, 160, and 180 °C and with 1

  10. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    SciTech Connect (OSTI)

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

    2014-06-17T23:59:59.000Z

    Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

  11. Sulfur-Free Selective Pulping

    E-Print Network [OSTI]

    Dimmel, D. R.; Bozell, J. J.

    A joint research effort is being conducted on ways to produce cost-effective pulping catalysts from lignin. This project addresses improving selectivities and reducing the levels of sulfur chemicals used in pulping. Improved selectivity means...

  12. Understanding Pound-Drever-Hall locking using voltage controlled radio-frequency oscillators: An undergraduate experiment

    E-Print Network [OSTI]

    Liekhus-Schmaltz, C E

    2011-01-01T23:59:59.000Z

    A senior undergraduate experiment has been developed for learning about frequency stabilization techniques using radio-frequency electronics. The primary objective is to frequency stabilize a voltage controlled oscillator to a cavity resonance at 800 MHz using the Pound-Drever-Hall scheme. This technique is commonly applied to stabilize lasers at optical frequencies, but by using radio-frequency equipment exclusively it is possible to systematically study various aspects of the technique more thoroughly, inexpensively, and free from eye hazards. Students also learn about modular radio-frequency electronics and basic feedback control loops. By varying the temperature of the resonator, the students may determine the thermal expansion coefficients of copper, aluminum, and super invar.

  13. Selective catalytic reduction of sulfur dioxide to elemental sulfur

    SciTech Connect (OSTI)

    Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

    1992-01-01T23:59:59.000Z

    Elemental sulfur recovery from SO[sub 2]-containing gas streams is highly attractive as it produces a saleable. Product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO[sub 2] with coke) and Claus plants(reaction of SO[sub 2] with H[sub 2]S over catalyst). This project win investigate a cerium oxide catalyst for the single-stage selective reduction SO[sub 2] to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified as a superior catalyst for SO[sub 2] reduction by CO to elemental sulfur because of its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650C). Kinetic and parametric studies of SO[sub 2] reduction planned over various CeO[sub 2]-formulations will provide the necessary basis for development of a simplified process, a single-stage elemental sulfur recovery scheme from variable concentration gas streams. A first apparent application is treatment of regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought Claus-alternative'' for coal-fired power plant applications.

  14. analyzing organic sulfur: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fiord sulfur deposits were best modeled as containing two sub-populations: sulfur on ice and sulfur on rock; 2) as expected, classifiers using Gaussian kernels outperformed...

  15. On the Origin of Sulfur

    E-Print Network [OSTI]

    Nils Ryde; David L. Lambert

    2005-10-05T23:59:59.000Z

    We present our work on the halo evolution of sulfur, based on observations of the S I lines around 9220 A for ten stars for which the S abundance was obtained previously from much weaker S I lines at 8694 A. We cannot confirm the rise and the high [S/Fe] abundances for low [Fe/H], as claimed in the literature from analysis of the 8694 A lines. The reasons for claims of an increase in [S/Fe] with decreasing [Fe/H] are probably twofold: uncertainties in the measurements of the weak 8694 A lines, and systematic errors in metallicity determinations from Fe I lines. The near-infrared sulfur triplet at 9212.9, 9228.1, and 9237.5 A are preferred for an abundance analysis of sulfur for metal-poor stars. Our work was presented in full by Ryde & Lambert (2004).

  16. Energy savings can be communicated in terms of kilowatt hours (energy), carbon (climate change) or pounds (cost).

    E-Print Network [OSTI]

    McAuley, Derek

    AIM Energy savings can be communicated in terms of kilowatt hours (energy), carbon (climate change) or pounds (cost). We want to know if these different communication units prime different motivations more broadly. This implies that considering carbon may result in wider changes in sustainable behaviour

  17. Molecular Structures of Polymer/Sulfur Composites for Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

  18. LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.

    SciTech Connect (OSTI)

    BATEY, J.E.; MCDONALD, R.J.

    2005-06-01T23:59:59.000Z

    This project was funded by NYSERDA and has clearly demonstrated many advantages of using low sulfur content heating oil to provide thermal comfort in homes. Prior laboratory research in the United States and Canada had indicated a number of potential benefits of using lower sulfur (0.05%) heating oil. However, this prior research has not resulted in the widespread use of low sulfur fuel oil in the marketplace. The research project described in this report was conducted with the assistance of a well-established fuel oil marketer in New York State (NYS) and has provided clear proof of the many real-world advantages of marketing and using low sulfur content No. 2 fuel oil. The very positive experience of the participating marketer over the past three years has already helped to establish low sulfur heating oil as a viable option for many other fuel marketers. In large part, based on the initial findings of this project and the experience of the participating NYS oilheat marketer, the National Oilheat Research Alliance (NORA) has already fully supported a resolution calling for the voluntary use of low sulfur (0.05 percent) home heating oil nationwide. The NORA resolution has the goal of converting eighty percent of all oil-heated homes to the lower sulfur fuel (0.05 percent by weight) by the year 2007. The Oilheat Manufacturers Association (OMA) has also passed a resolution fully supporting the use of lower sulfur home heating oil in the equipment they manufacture. These are important endorsements by prominent national oil heat associations. Using lower sulfur heating oil substantially lowers boiler and furnace fouling rates. Laboratory studies had indicated an almost linear relationship between sulfur content in the oil and fouling rates. The completed NYSERDA project has verified past laboratory studies in over 1,000 occupied residential homes over the course of three heating seasons. In fact, the reduction in fouling rates so clearly demonstrated by this project is almost the same as predicted by past laboratory studies. Fouling deposition rates are reduced by a factor of two to three by using lower sulfur oil. This translates to a potential for substantial service cost savings by extending the interval between labor-intensive cleanings of the internal surfaces of the heating systems in these homes. In addition, the time required for annual service calls can be lowered, reducing service costs and customer inconvenience. The analyses conducted as part of this field demonstration project indicates that service costs can be reduced by up to $200 million a year nationwide by using lower sulfur oil and extending vacuum cleaning intervals depending on the labor costs and existing cleaning intervals. The ratio of cost savings to added fuel costs is economically attractive based on past fuel price differentials for the lower sulfur product. The ratio of cost savings to added costs vary widely as a function of hourly service rates and the additional cost for lower sulfur oil. For typical values, the expected benefit is a factor of two to four higher than the added fuel cost. This means that for every dollar spent on higher fuel cost, two to four dollars can be saved by lowered vacuum cleaning costs when the cleaning intervals are extended. Information contained in this report can be used by individual oil marketers to estimate the benefit to cost ratio for their specific applications. Sulfur oxide and nitrogen oxide air emissions are reduced substantially by using lower sulfur fuel oil in homes. Sulfur oxides emissions are lowered by 75 percent by switching from fuel 0.20 percent to 0.05 percent sulfur oil. This is a reduction of 63,000 tons a year nationwide. In New York State, sulfur oxide emissions are reduced by 13,000 tons a year. This translates to a total value of $12 million a year in Sulfur Oxide Emission Reduction Credits for an emission credit cost of $195 a ton. While this ''environmental cost'' dollar savings is smaller than the potential service costs reduction, it is very significant. It represents an important red

  19. New insights into Archean sulfur cycle from mass-independent sulfur isotope records from the

    E-Print Network [OSTI]

    of Archean sulfur reservoirs and to trace pathways in the Archean sulfur cycle. Our data are explained S/33 S/32 S) for sulfide sulfur in shale and carbonate lithofacies from the Hamersley Basin, Western of the lower Mount McRae Shale (V2.5 Ga). Likewise, sulfide sulfur analyses of the Jeerinah Formation (V2.7 Ga

  20. Fermentation, Hydrogen, and Sulfur Metabolism in Multiple Uncultivated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fermentation, Hydrogen, and Sulfur Metabolism in Multiple Uncultivated Bacterial Phyla. Fermentation, Hydrogen, and Sulfur Metabolism in Multiple Uncultivated Bacterial Phyla....

  1. Sulfur hexafluoride as a surrogate

    SciTech Connect (OSTI)

    Taylor, P.H.; Chadbourne, J.F.

    1987-06-01T23:59:59.000Z

    A viable chemical surrogate for monitoring the effectiveness of hazardous waste incinerators must include high thermal stability and low toxicity among its characteristics. The relationship between sulfur hexafluoride (SF6) and hazardous constituent thermal stability for a mixture of chlorinated hydrocarbons indicates that SF6 has the potential to satisfy the basic requirements of a chemical surrogate for hazardous waste incineration.

  2. Recovering sulfur from gas streams

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    Linde AG (Hoellriegeiskreuth, Germany) has developed ClinSulf-SDP process, a two-reactor system that offers better than 99.5% sulfur recovery at low capital and operating costs. In a traditional Claus plant, sulfur-recovery rates of 99.3% can be achieved by combining a two- or three-stage Claus plant with a separate tail-gas cleanup unit (TGCU). Common TGCU methods include H{sub 2}S scrubbing, subdewpoint condensation and direct oxidation. Such combined units are not only costly and complicated to build and maintain, but many of today`s operators require higher sulfur-recovery rates--on the order of 99.3%--99.8%. The Clin-Sulf-SDP combines several catalytic stages of a Claus plant with a subdewpoint, tailgas-treatment system, and the process uses only two reactors. At the heart of the process are two identical, internally cooled reactors. Two four-way valves periodically reverse the sequence of the matching reactors, allowing them to alternate between sulfur-adsorption and catalyst-regeneration modes.

  3. Green Weight 

    E-Print Network [OSTI]

    Al-Haji, A.; Al-Omair, A.

    2010-01-01T23:59:59.000Z

    Green-weight is a novel system designed to supply a high-rise building with all its needs of electricity using wind energy and to supplement its lighting needs with natural sunlight. David Fisher has proposed an ingenious method to harness the wind...

  4. Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Gregory F.; Kruger, Albert A.

    2014-10-01T23:59:59.000Z

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis). If the amount of sulfur exceeds its tolerance level a molten salt will accumulate and upset melter operations and potentially shorten melter useful life. Therefore relatively conservative limits have been placed on sulfur loading in melter feed which in-turn significantly impacts the amount of glass that will be produced, in particular at the Hanford site. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 312 individual glass compositions. This model was shown to well represent the data, accounting for over 80% of the variation in data and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed based on 19 scaled melter tests. The model is appropriate for control of waste glass processing which includes uncertainty quantification. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5 ? TiO2 < CaO < P2O5 ? ZnO. The components that most decrease sulfur solubility are Cl > Cr2O3 > SiO2 ? ZrO2 > Al2O3.

  5. Toward Understanding the Effect of Nuclear Waste Glass Composition on Sulfur Solubility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D.; Kim, Dong-Sang; Muller, I. S.; Kruger, Albert A.; Piepel, Gregory F.

    2014-10-01T23:59:59.000Z

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which inmore »turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.« less

  6. Toward Understanding the Effect of Nuclear Waste Glass Composition on Sulfur Solubility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D. [Pacific Northwest National Laboratory; Kim, Dong-Sang [Pacific Northwest National Laboratory; Muller, I. S. [The Catholic University National Laboratory; Kruger, Albert A. [Department of Energy -- Ofice of River Protection; Piepel, Gregory F. [Pacific Northwest National Laboratory

    2014-10-01T23:59:59.000Z

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

  7. Pounds That Kill: The External Costs of Vehicle MICHAEL L. ANDERSON

    E-Print Network [OSTI]

    Auffhammer, Maximilian

    ), likely in response to rising gasoline prices and the passage of the Corporate Average Fuel Efficiency (CAFE) standard. As gasoline prices fell in the late-1980s, however, average vehicle weight began of research examines the effects of CAFE and gasoline prices on consumers' vehicle choices (Portney, Parry

  8. Magneto-optical conductivity in graphene including electron-phonon coupling Adam Pound1

    E-Print Network [OSTI]

    Ahlers, Guenter

    8S 4M1 3 The Canadian Institute for Advanced Research, Toronto, Ontario, Canada, M5G 1Z8 and 4 of spectral weight in each Landau level (LL) into phonon-assisted peaks in the spectral function. Other new, upright cone forming the conduction band and the lower, inverted cone forming the valence band

  9. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01T23:59:59.000Z

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  10. Natural Gas Processing Plant- Sulfur (New Mexico)

    Broader source: Energy.gov [DOE]

    This regulation establishes sulfur emission standards for natural gas processing plants. Standards are stated for both existing and new plants. There are also rules for stack height requirements,...

  11. Transition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget

    E-Print Network [OSTI]

    Alexander, Becky

    processes, volca- noes) or produced within the atmosphere by oxidation of re- duced sulfur speciesTransition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur importance of sulfate production by Fe(III)- and Mn(II)-catalyzed oxidation of S(IV) by O2. We scale

  12. Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake

    E-Print Network [OSTI]

    Borguet, Eric

    promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

  13. Massive atmospheric sulfur loading of the AD 1600 Huaynaputina eruption and implications for petrologic sulfur estimates

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    for petrologic sulfur estimates Fidel Costa1 and Bruno Scaillet Institut des Sciences de la Terre d'Orle´ans, UMR petrological, analytical, and thermodyna- mical data to constrain the sulfur yield of the AD 1600 Huaynaputina loading of the AD 1600 Huaynaputina eruption and implications for petrologic sulfur estimates, Geophys

  14. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26T23:59:59.000Z

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  15. atmospheric sulfur deposition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    desert dust Paytan, Adina 8 Effects of sulfuric acid and nitrogen deposition on mineral nutrition of Picea abies (L.) Karst. Physics Websites Summary: Effects of sulfuric...

  16. Manipulating the Surface Reactions in Lithium Sulfur Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode...

  17. Method for Determining Performance of Sulfur Oxide Adsorbents...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Method for Determining Performance of Sulfur Oxide Adsorbents for Diesel Emission Control Using Online Measurement of SO2 and Method for Determining Performance of Sulfur Oxide...

  18. Comparative Study on the Sulfur Tolerance and Carbon Resistance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Comparative Study on the Sulfur Tolerance and Carbon Resistance of...

  19. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01T23:59:59.000Z

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  20. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24T23:59:59.000Z

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  1. Mining Weighted Association Rules without Preassigned Weights

    E-Print Network [OSTI]

    Bai, Fengshan

    Mining Weighted Association Rules without Preassigned Weights Ke Sun and Fengshan Bai Abstract--Association rule mining is a key issue in data mining. However, the classical models ignore the difference between the transactions, and the weighted association rule mining does not work on databases with only binary attributes

  2. Heat Transfer Characteristics of Sulfur and Sulfur Diluted with Hydrogen Sulfide Flowing Through Circular Tubes

    E-Print Network [OSTI]

    Stone, Porter Walwyn

    1960-01-01T23:59:59.000Z

    concentrations of hydrogen sulfide, using water as a basis of comparison. For identical tube sizes and the same fluid velocity, both pure and dilute sulfur were found to have a film conductance ~- I less than ten percent that of water over most... the v x d curves for each concentration of diluent. Sulfur is diluted with H2S, added as persulfide Sulfur is diluted with H S, added as liquid 34 35 10. A Ratio of film conductance of pure sulfur to that of water versus temperature. The flow...

  3. Definition of Non-Conventional Sulfur Utilization in Western Kazakhstan for Sulfur Concrete (Phase 1)

    SciTech Connect (OSTI)

    Kalb, Paul

    2007-05-31T23:59:59.000Z

    Battelle received a contract from Agip-KCO, on behalf a consortium of international oil and gas companies with exploration rights in the North Caspian Sea, Kazakhstan. The objective of the work was to identify and help develop new techniques for sulfur concrete products from waste, by-product sulfur that will be generated in large quantitites as drilling operations begin in the near future. BNL has significant expertise in the development and use of sulfur concrete products and has direct experience collaborating with the Russian and Kazakh partners that participated. Feasibility testing was successfully conducted for a new process to produce cost-effective sulfur polymer cement that has broad commerical applications.

  4. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    DOE Patents [OSTI]

    Mahajan, Devinder

    2004-12-28T23:59:59.000Z

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  5. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, Tetsuo (Ames, IA); Squires, Thomas G. (Gilbert, IA); Venier, Clifford G. (Ames, IA)

    1985-02-05T23:59:59.000Z

    A process for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  6. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11T23:59:59.000Z

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  7. World copper smelter sulfur balance-1988

    SciTech Connect (OSTI)

    Towle, S.W. (Bureau of Mines, Denver, CO (United States))

    1993-01-01T23:59:59.000Z

    In 1989, the US Bureau of Mines initiated a contract to gather engineering, operating, and environmental cost data for 1988 for 30 major foreign primary copper smelters in market economy countries. Data were collected for 29 of the designated smelters together with information on applicable environmental regulations. Materials balance data obtained were used with available data for the eight US smelters to determine the approximate extent of copper smelter sulfur emission control in 1988. A broad characterization of the status of sulfur emission control regulation was made. The 37 US and foreign smelters represented roughly 73.2% of world and 89.3% of market economy primary copper production in 1988. The 29 non-US smelters attained 55.3% control of their input sulfur in 1988. Combined with the 90.4% control of US smelters, an aggregate 63.4% sulfur control existed. Roughly 1,951,100 mt of sulfur was emitted from the 37 market economy smelters in 1988. Identifiable SO[sub 2] control regulations covered 72.4% of the 29 foreign smelters, representing 65.5% of smelting capacity. Including US smelters, 78.4% of the major market economy smelters were regulated, representing 73.1% of smelting capacity. Significant changes since 1988 that may increase sulfur emission control are noted.

  8. Toward Understanding the Effect of Nuclear Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D. [Pacific Northwest National Laboratory; Kim, Dong-Sang [Pacific Northwest National Laboratory; Muller, I. S. [The Catholic University National Laboratory; Kruger, Albert A. [Department of Energy -- Ofice of River Protection; Piepel, Gregory F. [Pacific Northwest National Laboratory

    2014-10-01T23:59:59.000Z

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

  9. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zheng, Jianming [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Walter, Eric [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pan, Huilin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Lv, Dongping [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zuo, Pengjian [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Chen, Honghao [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Deng, Z. D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liaw, Bor Y. [School of Ocean and Earth Science and Technology, Hawaii Natural Energy Institute, (United States); Yu, Xiqian [Brookhaven National Laboratory, Upton, NY (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Upton, NY (United States); Zhang, Ji-Guang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liu, Jun [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Xiao, Jie [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

    2014-12-09T23:59:59.000Z

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  10. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09T23:59:59.000Z

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  11. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2014-12-09T23:59:59.000Z

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore »cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  12. Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-

    E-Print Network [OSTI]

    Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

  13. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Vehicle...

  14. An Aerosol Condensation Model for Sulfur Trioxide

    SciTech Connect (OSTI)

    Grant, K E

    2008-02-07T23:59:59.000Z

    This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

  15. Multispecies weighted Hurwitz numbers

    E-Print Network [OSTI]

    Harnad, J

    2015-01-01T23:59:59.000Z

    The construction of hypergeometric 2D Toda $\\tau$-functions as generating functions for weighted Hurwitz numbers is extended to multispecies families. Both the enumerative geometrical significance of multispecies weighted Hurwitz numbers as weighted enumerations of branched coverings of the Riemann sphere and their combinatorial significance in terms of weighted paths in the Cayley graph of $S_n$ are derived. The particular case of multispecies quantum weighted Hurwitz numbers is studied in detail.

  16. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22T23:59:59.000Z

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  17. Development of High Energy Density Lithium-Sulfur Cells

    Broader source: Energy.gov (indexed) [DOE]

    for increased sulfur loading Cathode Anode Investigatingoptimizing Li and Si composite anodes Exploring polymer electrolytes Electrolyte Determining new...

  18. Waste Description Pounds Reduced,

    E-Print Network [OSTI]

    -labeled oligonucleotides Waste minimization 3,144 Radiological waste (396 ft3 ); Mixed waste (35 gallons); Hazardous Waste of radioactivity, thus avoiding radiological waste generation. This process won a 2008 DOE P2 Star Award environmentally friendly manor. BNL pays shipping fees to the recycling facility. Building demolition recycling

  19. Posting type Advisory update Subject Inconstant bias in XRF sulfur

    E-Print Network [OSTI]

    Fischer, Emily V.

    Posting type Advisory update Subject Inconstant bias in XRF sulfur Module/Species A/ S Sites entire attention to observable discontinuities in XRF sulfur data. Shifts in the sulfur/sulfate ratio during 2003-4 were shown to coincide with recalibrations of the XRF system and to correlate with other XRF biases

  20. On the galactic chemical evolution of sulfur

    E-Print Network [OSTI]

    N. Ryde; D. L. Lambert

    2003-12-02T23:59:59.000Z

    Sulfur abundances have been determined for ten stars to resolve a debate in the literature on the Galactic chemical evolution of sulfur in the halo phase of the Milky Way. Our analysis is based on observations of the S I lines at 9212.9, 9228.1, and 9237.5 A for stars for which the S abundance was obtained previously from much weaker S I lines at 8694.0 and 8694.6 A. In contrast to the previous results showing [S/Fe] to rise steadily with decreasing [Fe/H], our results show that [S/Fe] is approximately constant for metal-poor stars ([Fe/H] < -1) at [S/Fe] = +0.3. Thus, sulfur behaves in a similar way to the other alpha elements, with an approximately constant [S/Fe] for metallicities lower than [Fe/H] = -1. We suggest that the reason for the earlier claims of a rise of [S/Fe] is partly due to the use of the weak S I 8694.0 and 8694.6 A lines and partly uncertainties in the determination of the metallicity when using Fe I lines. The S I 9212.9, 9228.1, and 9237.5 A lines are preferred for an abundance analysis of sulfur for metal-poor stars.

  1. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

    1991-01-01T23:59:59.000Z

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  2. Safety considerations for the use of sulfur in sulfur-modified pavement materials

    E-Print Network [OSTI]

    Jacobs, Carolyn Yuriko

    1980-01-01T23:59:59.000Z

    when equipped with accessories for remote multipoint (choice of sequential or simultaneous systems) sampling systems, 3) General Monitors Hydrogen Sulfide Monitors Model Z150, a single channel system, and Model 2200, either 2 or 4 channel systems... situations are gaseous emissions of hydrogen sulfide (H2S) and sulfur dioxide (S02), as well as airborne particulate sulfur. These hazards can usually be gauged in terms of temperature, time duration of temperature, and dispersion factors. Hydrogen...

  3. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-01-01T23:59:59.000Z

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  4. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29T23:59:59.000Z

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  5. Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof

    SciTech Connect (OSTI)

    Oswald, A.A.; Bhatia, R.N.; Mozeleski, E.J.; Glivicky, A.P.; Brueggeman, B.G.; Hooten, J.R.; Smith, C.M.; Hsu, C.S.

    1991-07-09T23:59:59.000Z

    This patent describes a hydroformylation-hydrogenation process comprising reacting an olefinic cracked petroleum distillate feed, produced from petroleum residue by high temperature thermal cracking, and containing C{sub 5} to C{sub 35}-1-n-alkyl olefins as the major type of olefin components, and organic sulfur compounds in concentrations exceeding 0.1% sulfur. It comprises at first with carbon monoxide and hydrogen at temperatures between about 50 and 250{degrees} C and pressures in the range of 50 to 6000 psi; in the presence of a Group VIII transition metal carbonyl complex catalyst in effective amounts to produce aldehydes of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule.

  6. Sulfur capture in an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Baars, D.M.; Hunter, C.A.; Keitelman, E.N.

    1981-06-01T23:59:59.000Z

    Sulfur capture in an atmospheric fluidized-bed combustor (AFBC) both with and without recycle of fines elutriated from the bed was studied. Two empirical correlations, one by Babcock and Wilcox and the other by Westinghouse, correlate sulfur capture as a function of the calcium-to-sulfur mole ratio and gas residence time. Both correlations fit the experimental no-recycle results quite well. Of the limestones tested with no recycle, Vulcan Materials exhibits the best sulfur-capture performance. Data collected with Reed limestone indicates that recycle improves sulfur-capture compared with once-through performance. However, there is a decreasing effect on sulfur capture as the recycle rate is increased to large values. At 90% sulfur capture, the fractional reduction of fresh limestone feed attributable to recycle is 24 to 35% over a gas-residence time range of 0.7 to 0.4 s.

  7. Costs to reduce sulfur dioxide emissions

    SciTech Connect (OSTI)

    None

    1982-03-01T23:59:59.000Z

    Central to the resolution of the acid rain issue are debates about the costs and benefits of controlling man-made emissions of chemicals that may cause acid rain. In this briefing, the position of those who are calling for immediate action and implicating coal-fired powerplants as the cause of the problem is examined. The costs of controlling sulfur dioxide emissions using alternative control methods available today are presented. No attempt is made to calculate the benefits of reducing these emissions since insufficient information is available to provide even a rough estimate. Information is presented in two steps. First, costs are presented as obtained through straightforward calculations based upon simplifying but realistic assumptions. Next, the costs of sulfur dioxide control obtained through several large-scale analyses are presented, and these results are compared with those obtained through the first method.

  8. Development of the Hybrid Sulfur Thermochemical Cycle

    SciTech Connect (OSTI)

    Summers, William A.; Steimke, John L

    2005-09-23T23:59:59.000Z

    The production of hydrogen via the thermochemical splitting of water is being considered as a primary means for utilizing the heat from advanced nuclear reactors to provide fuel for a hydrogen economy. The Hybrid Sulfur (HyS) Process is one of the baseline candidates identified by the U.S. Department of Energy [1] for this purpose. The HyS Process is a two-step hybrid thermochemical cycle that only involves sulfur, oxygen and hydrogen compounds. Recent work has resulted in an improved process design with a calculated overall thermal efficiency (nuclear heat to hydrogen, higher heating value basis) approaching 50%. Economic analyses indicate that a nuclear hydrogen plant employing the HyS Process in conjunction with an advanced gas-cooled nuclear reactor system can produce hydrogen at competitive prices. Experimental work has begun on the sulfur dioxide depolarized electrolyzer, the major developmental component in the cycle. Proof-of-concept tests have established proton-exchange-membrane cells (a state-of-the-art technology) as a viable approach for conducting this reaction. This is expected to lead to more efficient and economical cell designs than were previously available. Considerable development and scale-up issues remain to be resolved, but the development of a viable commercial-scale HyS Process should be feasible in time to meet the commercialization schedule for Generation IV gas-cooled nuclear reactors.

  9. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Liu, Wei (Cambridge, MA)

    1995-01-01T23:59:59.000Z

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  10. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05T23:59:59.000Z

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  11. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

    1989-01-01T23:59:59.000Z

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  12. Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions

    E-Print Network [OSTI]

    Denver, University of

    with sulfuric and nitric acids formed from at- mospheric oxidations of sulfur dioxide SO2 and nitrogen oxides mobile sources comes from the combustion of sulfur compounds in fuel. The U.S. is in the process of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

  13. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources andPlant Liquids,+ LeasePrice Sold to Electric Power

  14. alum rock sulfur: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -resolution carbon and sulfur isotope profiles from Early to Middle Ordovician carbonate rocks from the Argentine Investigation of isotopic compositions recorded in...

  15. aromatic sulfur heterocycles: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alkylating agent Skin MMP inhibitor MMP Matrix metalloproteinase Sulfur mustard (HD, SM), is a chemical warfare agent that within hours causes extensive blistering Androulakis,...

  16. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Broader source: Energy.gov (indexed) [DOE]

    of long cycle-life in half cells and expand the synthesis of sulfurcarbon composite materials of various sulfur loadings 2. Compare the performance for different...

  17. Sulfur Isotopes as Indicators of Amended Bacterial Sulfate Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Amended Bacterial Sulfate Reduction Processes Influencing Field Scale Uranium Bioremediation. Sulfur Isotopes as Indicators of Amended Bacterial Sulfate Reduction Processes...

  18. Fundamental Studies of Lithium-Sulfur Cell Chemistry

    Broader source: Energy.gov (indexed) [DOE]

    Studies of Lithium-Sulfur Cell Chemistry PI: Nitash Balsara LBNL June 17, 2014 Project ID ESS224 This presentation does not contain any proprietary, confidential, or otherwise...

  19. LARGE-SCALE MEASUREMENT OF AIRBORNE PARTICULATE SULFUR

    E-Print Network [OSTI]

    Loo, B.W.

    2010-01-01T23:59:59.000Z

    dispersive x-ray fluorescence (XRF) analysis. Concentrationsvalida- tion studies of XRF measurements have establishedelemental sulfur measurement by XRF can be closely related

  20. anaerobic green sulfur: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Carbon Flow of Heliobacteria Is Related More to Clostridia than to the Green Sulfur Bacteria, Chemistry, and Energy, Environment, and Chemical...

  1. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

    1988-01-01T23:59:59.000Z

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

  2. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, N.K.; Ruether, J.A.; Smith, D.N.

    1987-10-07T23:59:59.000Z

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

  3. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02T23:59:59.000Z

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  4. Chemistry of Sulfur Oxides on Transition Metals. II. Thermodynamics of Sulfur Oxides on Platinum(111)

    E-Print Network [OSTI]

    Lin, Xi

    J/mol from temperature-programmed desorption (TPD) experiments.4 Having some energetic data or, moreover, having substantial data on the thermodynamics of adsorption and interconversion of sulfur oxide species obtained several new vibrational features by pretreating the Pt(111) surface with the gas-phase oxygen

  5. Sulfurization of carbon surface for vapor phase mercury removal I: Effect of temperature and sulfurization protocol

    E-Print Network [OSTI]

    Borguet, Eric

    with the decomposition of surface functionalities, which creates active sites for sulfur bonding. The presence of H2S2S adsorption, and that surface chemistry played a significant role in the uptake of H2S. Mikhalovsky and Zaitsev [9] showed that H2S adsorption from an inert atmosphere on activated carbons resulted

  6. SYNTHESIS OF SULFUR-BASED WATER TREATMENT AGENT FROM SULFUR DIOXIDE WASTE STREAMS

    SciTech Connect (OSTI)

    Robert C. Brown; Maohong Fan

    2001-12-01T23:59:59.000Z

    We propose a process that uses sulfur dioxide from coal combustion as a raw material to synthesize polymeric ferric sulfate (PFS), a water treatment agent. The process uses sodium chlorate as an oxidant and ferrous sulfate as an absorbent. The major chemical mechanisms in this reaction system include oxidation, hydrolysis, and polymerization. Oxidation determines sulfur conversion efficiency while hydrolysis and polymerization control the quality of product. Many factors, including SO{sub 2} inlet concentration, flow rate of simulated flue gas, reaction temperature, addition rate of oxidant and stirring rate, may affect the efficiencies of SO{sub 2} removal. Currently, the effects of SO{sub 2} inlet concentration, the flow rate of simulated flue gas and addition rate of flue gas on removal efficiencies of SO{sub 2}, are being investigated. Experiments shown in this report have demonstrated that the conversion efficiencies of sulfur dioxide with ferrous sulfate as an absorbent are in the range of 60-80% under the adopted process conditions. However, the conversion efficiency of sulfur dioxide may be improved by optimizing reaction conditions to be investigated. Partial quality indices of the synthesized products, including Fe{sup 2+} concentration and total iron concentration, have been evaluated.

  7. Correlation for the total sulfur content in char after devolatilization

    SciTech Connect (OSTI)

    Vasilije Manovic; Borislav Grubor [University of Belgrade, Belgrade (Serbia & Montenegro)

    2006-02-01T23:59:59.000Z

    The overall process of coal combustion takes place in two successive steps: devolatilization and char combustion. The fate of sulfur during the devolatilization of coal of different rank was investigated. The significance of the investigation is in fact that a major part of sulfur release occurs during devolatilization of coal, (i.e., emission of sulfur oxides during combustion of coal largely depends on sulfur release during devolatilization). The experimental investigations were conducted to obtain the data about the quantitative relation between sulfur content in the coal and sulfur content in the char. Standard procedures were used for obtaining the chars in a laboratory oven and determining the sulfur forms in the coal and char samples. The experiments were done with ground coal samples ({lt}0.2 mm), at the temperatures in the range of 500-1000{sup o}C. We showed that the amount of sulfur remaining in the char decreases, but not significantly in the temperature range 600-900{sup o}C. On the basis of the theoretical consideration of behavior of sulfur forms during devolatilization, certain simplifying assumptions, and obtained experimental data, we propose two correlations to associate the content of sulfur in the coal and in the char. The correlations are based on the results of the proximate analysis and sulfur forms in coal. Good agreement was found when the proposed correlations were compared with the experimental results obtained for investigated coals. Moreover, the correlations were verified by results found in the literature for numerous Polish, Albanian, and Turkish coals. Significant correlations (P {lt}0.05) between observed and calculated data with correlation coefficient, R {gt}0.9, were noticed in the case of all coals. 25 refs., 3 figs., 2 tabs.

  8. Sulfuric acid deposition from stratospheric geoengineering with sulfate aerosols

    E-Print Network [OSTI]

    Robock, Alan

    aerosols can potentially result in an increase in acid deposition. [4] Acid rain has been studiedSulfuric acid deposition from stratospheric geoengineering with sulfate aerosols Ben Kravitz,1 Alan limit of hydration of all sulfate aerosols into sulfuric acid. For annual injection of 5 Tg of SO2

  9. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    E-Print Network [OSTI]

    Hultman, Nathan E.

    PNNL-14537 Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results S.J. Smith E;PNNL-14537 Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results PNNL Research Report Joint Global Change Research Institute 8400 Baltimore Avenue College Park, Maryland 20740 #12;PNNL-14537

  10. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01T23:59:59.000Z

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  11. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

    2010-01-12T23:59:59.000Z

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  12. SUSCEPTIBILIT MAGNTIQUE DE QUELQUES SULFURES ET OXYDES DE PLUTONIUM

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    261. SUSCEPTIBILITÉ MAGNÉTIQUE DE QUELQUES SULFURES ET OXYDES DE PLUTONIUM Par GEORGES RAPHAEL et CHARLES DE NOVION, S.E.C.P.E.R., Section d'Études des Céramiques à base de Plutonium, Centre d susceptibilite magnétique des sulfures de plutonium : PuS, Pu3S4, PU2S3CXI PuS2. Ces composes non conduc- teurs

  13. High-sulfur coals in the eastern Kentucky coal field

    SciTech Connect (OSTI)

    Hower, J.C.; Graham, U.M. (Univ. of Kentucky Center for Applied Energy Research, Lexington, KY (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington, KY (United States))

    1993-08-01T23:59:59.000Z

    The Eastern Kentucky coal field is notable for relatively low-sulfur, [open quotes]compliance[close quotes] coals. Virtually all of the major coals in this area do have regions in which higher sulfur lithotypes are common, if not dominant, within the lithologic profile. Three Middle Pennsylvanian coals, each representing a major resource, exemplify this. The Clintwood coal bed is the stratigraphically lowest coal bed mined throughout the coal field. In Whitley County, the sulfur content increase from 0.6% at the base to nearly 12% in the top lithotype. Pyrite in the high-sulfur lithotype is a complex mixture of sub- to few-micron syngenetic forms and massive epigenetic growths. The stratigraphically higher Pond Creek coal bed is extensively mined in portions of the coal field. Although generally low in sulfur, in northern Pike and southern Martin counties the top one-third can have up to 6% sulfur. Uniformly low-sulfur profiles can occur within a few hundred meters of high-sulfur coal. Pyrite occurs as 10-50 [mu]m euhedra and coarser massive forms. In this case, sulfur distribution may have been controlled by sandstone channels in the overlying sediments. High-sulfur zones in the lower bench of the Fire Clay coal bed, the stratigraphically highest coal bed considered here, are more problematical. The lower bench, which is of highly variable thickness and quality, generally is overlain by a kaolinitic flint clay, the consequence of a volcanic ash fall into the peat swamp. In southern Perry and Letcher counties, a black, illite-chlorite clay directly overlies the lower bench. General lack of lateral continuity of lithotypes in the lower bench suggests that the precursor swamp consisted of discontinuous peat-forming environments that were spatially variable and regularly inundated by sediments. Some of the peat-forming areas may have been marshlike in character.

  14. Light weight phosphate cements

    DOE Patents [OSTI]

    Wagh, Arun S. (Naperville, IL); Natarajan, Ramkumar, (Woodridge, IL); Kahn, David (Miami, FL)

    2010-03-09T23:59:59.000Z

    A sealant having a specific gravity in the range of from about 0.7 to about 1.6 for heavy oil and/or coal bed methane fields is disclosed. The sealant has a binder including an oxide or hydroxide of Al or of Fe and a phosphoric acid solution. The binder may have MgO or an oxide of Fe and/or an acid phosphate. The binder is present from about 20 to about 50% by weight of the sealant with a lightweight additive present in the range of from about 1 to about 10% by weight of said sealant, a filler, and water sufficient to provide chemically bound water present in the range of from about 9 to about 36% by weight of the sealant when set. A porous ceramic is also disclosed.

  15. Weighted control systems

    E-Print Network [OSTI]

    Al-Radhi, Adhi Omar

    1974-01-01T23:59:59.000Z

    ) 50 3-10 Defects per Unit Control Charts (Sudden Increase in Number of Defects) 51 3-11 Defects per Unit Control Charts (Slow Increase in Number of Defects) 52 3-12 O. C. Curves of Fraction Defectives Control Charts. 54 3-13 O. C. Curves.... The exponential smoothing principle was introduced to quality control field in 1959. It was first adapted in the mean control chart [25]. Through this control system, the most recent information is weighted and combined with the weighted past observations. 10...

  16. Molecular Structures of Polymer/Sulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life

    SciTech Connect (OSTI)

    Xiao, Lifen; Cao, Yuliang; Xiao, Jie; Schwenzer, Birgit; Engelhard, Mark H.; Saraf, Laxmikant V.; Nie, Zimin; Exarhos, Gregory J.; Liu, Jun

    2013-04-26T23:59:59.000Z

    Vulcanizedpolyaniline/sulfur (SPANI/S) nanostructures were investigated for Li-S battery applications, but the detailed molecular structures of such composites have not been fully illustrated. In this paper, we synthesize SPANI/S composites with different S content in a nanorod configuration. FTIR, Raman, XPS, XRD, SEM and elemental analysis methods are used to characterize the molecular structure of the materials. We provide clear evidence that a portion of S was grafted on PANI during heating and connected the PANI chains with disulfide bonds to form a crosslinked network and the rest of S was encapsulated within it.. Polysulfides and elementary sulfur nanoparticles are physically trapped inside the polymer network and are not chemically bound to the polymer. The performance of the composites is further improved by reducing the particle size. Even after 500 cycles a capacity retention rate of 68.8% is observed in the SPANI/S composite with 55% S content.

  17. Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids

    SciTech Connect (OSTI)

    Not Available

    1981-10-01T23:59:59.000Z

    The mechanisms by which various fuel component hydrocarbons related to both heavy petroleum and coal-derived liquids are converted to hydrogen without forming carbon were investigated. Reactive differences between paraffins and aromatics in autothermal reforming (ATR) were shown to be responsible for the observed fuel-specific carbon formation characteristics. The types of carbon formed in the reformer were identified by SEM and XRD analyses of catalyst samples and carbon deposits. From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation. The effects of propylene addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics, synergistic effects on conversion characteristics were identified. Indications that the sulfur content of the fuel may be the limiting factor for efficient ATR operation were found. The conversion and degradation effects of the sulfur additive (thiophene) were examined.

  18. High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.

    SciTech Connect (OSTI)

    Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

    2005-09-01T23:59:59.000Z

    A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

  19. Effects of fine particulate matter and its constituents on low birth weight among full-term infants in California

    SciTech Connect (OSTI)

    Basu, Rupa, E-mail: Rupa.Basu@oehha.ca.gov [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States)] [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States); Harris, Maria [School of Public Health, Boston University, Boston, MA (United States)] [School of Public Health, Boston University, Boston, MA (United States); Sie, Lillian [School of Public Health, University of California, Berkeley, CA (United States)] [School of Public Health, University of California, Berkeley, CA (United States); Malig, Brian; Broadwin, Rachel; Green, Rochelle [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States)] [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States)

    2014-01-15T23:59:59.000Z

    Relationships between prenatal exposure to fine particles (PM{sub 2.5}) and birth weight have been observed previously. Few studies have investigated specific constituents of PM{sub 2.5}, which may identify sources and major contributors of risk. We examined the effects of trimester and full gestational prenatal exposures to PM{sub 2.5} mass and 23 PM{sub 2.5} constituents on birth weight among 646,296 term births in California between 2000 and 2006. We used linear and logistic regression models to assess associations between exposures and birth weight and risk of low birth weight (LBW; <2500 g), respectively. Models were adjusted for individual demographic characteristics, apparent temperature, month and year of birth, region, and socioeconomic indicators. Higher full gestational exposures to PM{sub 2.5} mass and several PM{sub 2.5} constituents were significantly associated with reductions in term birth weight. The largest reductions in birth weight were associated with exposure to vanadium, sulfur, sulfate, iron, elemental carbon, titanium, manganese, bromine, ammonium, zinc, and copper. Several of these PM{sub 2.5} constituents were associated with increased risk of term LBW. Reductions in birth weight were generally larger among younger mothers and varied by race/ethnicity. Exposure to specific constituents of PM{sub 2.5}, especially traffic-related particles, sulfur constituents, and metals, were associated with decreased birth weight in California. -- Highlights: • Examine full gestational and trimester fine particle and its constituents on term birth weight. • Fine particles and several of its constituents associated with birth weight reductions. • Largest reductions for traffic-related particles, sulfur constituents, and metals. • Greater birth weight reductions for younger mothers, and varied by race/ethnicity.

  20. Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3

    SciTech Connect (OSTI)

    Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

    1995-09-01T23:59:59.000Z

    The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

  1. Weight 1. Leadership

    E-Print Network [OSTI]

    Prodiæ, Aleksandar

    Weight 0 1 2 3 1. Leadership 33% Has not demonstrated impact through a leadership role Has held a leadership role in one or more organizations and demonstrated impact Has held an organization-wide leadership role in one or more

  2. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13T23:59:59.000Z

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  3. Sulfur Dioxide Treatment from Flue Gases Using a Biotrickling

    E-Print Network [OSTI]

    ), and several episodes in London (1). All fuels used by humans such as coal, oil, natural gas, peat, wood of absorbing sulfur dioxide either in water or in aqueous slurries

  4. Sulfurized olefin lubricant additives and compositions containing same

    SciTech Connect (OSTI)

    Braid, M.

    1980-03-25T23:59:59.000Z

    Lubricant additives having substantially improved extreme pressure characteristics are provided by modifying certain sulfurized olefins by reacting said olefins with a cyclic polydisulfide under controlled reaction conditions and at a temperature of at least about 130/sup 0/ C.

  5. aqueous organic sulfur: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kaufman, Alan Jay 352 Using ISC & GIS to predict sulfur deposition from coal-fired power plants Texas A&M University - TxSpace Summary: positioning system was also used...

  6. adenylation sulfur transfer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chatterjee, A. 264 SO2 impacts on forage and soil sulfur concentrations near coal-fired power plants Texas A&M University - TxSpace Summary: The goal of this research was to...

  7. Physiology of multiple sulfur isotope fractionation during microbial sulfate reduction

    E-Print Network [OSTI]

    Sim, Min Sub

    2012-01-01T23:59:59.000Z

    Microbial sulfate reduction (MSR) utilizes sulfate as an electron acceptor and produces sulfide that is depleted in heavy isotopes of sulfur relative to starting sulfate. The fractionation of S-isotopes is commonly used ...

  8. Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes

    E-Print Network [OSTI]

    Harkness, J.; Doctor, R. D.

    A new hydrogen sulfide waste-treatment process that uses microwave plasma-chemical technology is currently under development in the Soviet Union and in the United States. Whereas the present waste treatment process only recovers sulfur at best...

  9. Novel Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Lei Yang; Meilin Liu

    2008-12-31T23:59:59.000Z

    One of the unique advantages of SOFCs over other types of fuel cells is the potential for direct utilization of hydrocarbon fuels (it may involve internal reforming). Unfortunately, most hydrocarbon fuels contain sulfur, which would dramatically degrade SOFC performance at parts-per-million (ppm) levels. Low concentration of sulfur (ppm or below) is difficult to remove efficiently and cost-effectively. Therefore, knowing the exact poisoning process for state-of-the-art anode-supported SOFCs with Ni-YSZ cermet anodes, understanding the detailed anode poisoning mechanism, and developing new sulfur-tolerant anodes are essential to the promotion of SOFCs that run on hydrocarbon fuels. The effect of cell operating conditions (including temperature, H{sub 2}S concentration, cell voltage/current density, etc.) on sulfur poisoning and recovery of nickel-based anode in SOFCs was investigated. It was found that sulfur poisoning is more severe at lower temperature, higher H{sub 2}S concentration or lower cell current density (higher cell voltage). In-situ Raman spectroscopy identified the nickel sulfide formation process on the surface of a Ni-YSZ electrode and the corresponding morphology change as the sample was cooled in H{sub 2}S-containing fuel. Quantum chemical calculations predicted a new S-Ni phase diagram with a region of sulfur adsorption on Ni surfaces, corresponding to sulfur poisoning of Ni-YSZ anodes under typical SOFC operating conditions. Further, quantum chemical calculations were used to predict the adsorption energy and bond length for sulfur and hydrogen atoms on various metal surfaces. Surface modification of Ni-YSZ anode by thin Nb{sub 2}O{sub 5} coating was utilized to enhance the sulfur tolerance. A multi-cell testing system was designed and constructed which is capable of simultaneously performing electrochemical tests of 12 button cells in fuels with four different concentrations of H{sub 2}S. Through systematical study of state-of-the-art anode-supported SOFC button cells, it is seen that the long-term sulfur poisoning behavior of those cells indicate that there might be a second-stage slower degradation due to sulfur poisoning, which would last for a thousand hour or even longer. However, when using G-18 sealant from PNNL, the 2nd stage poisoning was effectively prohibited.

  10. An electrochemical Claus process for sulfur recovery

    SciTech Connect (OSTI)

    Pujare, N.U.; Tsai, K.J.; Sammuells, A.F. (Eltron Research, Inc., Aurora, IL (US))

    1989-12-01T23:59:59.000Z

    Electrochemical oxidation of H{sub 2}S to give sulfur and water was achieved at 900{degrees}C using fuel cells possessing the general configuration where anode electrocatalysts experimentally investigated for promoting the subject oxidation reaction included WS{sub 2} and the thiospinels CuNi{sub 2}S{sub 4}, CuCo{sub 2}S{sub 4}, CuFe{sub 2}S{sub 4}, and NiFe{sub 2}S{sub 4}. The predominant oxidizable electroactive species present in the fuel cell anode compartment was suggested to be hydrogen originating from the initial thermal dissociation of H{sub 2}S (H{sub 2}S {r reversible} H{sub 2} + 1/2 S{sub 2}) at fuel cell operating temperatures. Rapid anode kinetics were found for the anodic reaction with the empirical trend for exchange currents (i{sub o}) per geometric area being found to be NiFe{sub 2}S{sub 4}{gt}WS{sub 2}{gt}CuCo{sub 2}S{sub 4}{gt}CuFe{sub 2}S{sub 4}{approx equal}NiCo{sub 2}S{sub 4}{gt}CuNi{sub 2}S{sub 4}.

  11. The weighted words collector

    E-Print Network [OSTI]

    Boisberranger, Jérémie Du; Ponty, Yann

    2012-01-01T23:59:59.000Z

    Motivated by applications in bioinformatics, we consider the word collector problem, i.e. the expected number of calls to a random weighted generator of words of length $n$ before the full collection is obtained. The originality of this instance of the non-uniform coupon collector lies in the, potentially large, multiplicity of the words/coupons of a given probability/composition. We obtain a general theorem that gives an asymptotic equivalent for the expected waiting time of a general version of the Coupon Collector. This theorem is especially well-suited for classes of coupons featuring high multiplicities. Its application to a given language essentially necessitates some knowledge on the number of words of a given composition/probability. We illustrate the application of our theorem, in a step-by-step fashion, on three exemplary languages, revealing asymptotic regimes in $\\Theta(\\mu(n)\\cdot n)$ and $\\Theta(\\mu(n)\\cdot \\log n)$, where $\\mu(n)$ is the sum of weights over words of length $n$.

  12. Cleaning method for removing sulfur containing deposits from coke oven gas lines

    SciTech Connect (OSTI)

    Sumansky, L.W.

    1985-04-09T23:59:59.000Z

    Process for removing hard to remove deposits containing elemental sulfur and multivalent compounds from a surface comprising contacting the deposits with a cleaning composition comprising (a) a major portion of aliphatic amine, (b) water, and (c) an oxidizing or reducing agent, allowing the cleaning composition to remain in contact with the deposits for sufficient time to allow sufficient dissolution of said solid to take place to allow removal of the deposits to take place, and applying such force as is necessary to remove these partially dissolved deposits from the surface. A preferred cleaning composition comprises from about 60 to about 90 volume percent aliphatic amine, from about 10 to about 40 volume percent water, and from about 1 to about 3 weight percent of a moderate oxidizing or reducing agent, such percentages based on the total composition.

  13. Hybrid Sulfur Thermochemical Process Development Annual Report

    SciTech Connect (OSTI)

    Summers, William A.; Buckner, Melvin R.

    2005-07-21T23:59:59.000Z

    The Hybrid Sulfur (HyS) Thermochemical Process is a means of producing hydrogen via water-splitting through a combination of chemical reactions and electrochemistry. Energy is supplied to the system as high temperature heat (approximately 900 C) and electricity. Advanced nuclear reactors (Generation IV) or central solar receivers can be the source of the primary energy. Large-scale hydrogen production based on this process could be a major contributor to meeting the needs of a hydrogen economy. This project's objectives include optimization of the HyS process design, analysis of technical issues and concerns, creation of a development plan, and laboratory-scale proof-of-concept testing. The key component of the HyS Process is the SO2-depolarized electrolyzer (SDE). Studies were performed that showed that an electrolyzer operating in the range of 500-600 mV per cell can lead to an overall HyS cycle efficiency in excess of 50%, which is superior to all other currently proposed thermochemical cycles. Economic analysis indicated hydrogen production costs of approximately $1.60 per kilogram for a mature nuclear hydrogen production plant. However, in order to meet commercialization goals, the electrolyzer should be capable of operating at high current density, have a long operating lifetime , and have an acceptable capital cost. The use of proton-exchange-membrane (PEM) technology, which leverages work for the development of PEM fuel cells, was selected as the most promising route to meeting these goals. The major accomplishments of this project were the design and construction of a suitable electrolyzer test facility and the proof-of-concept testing of a PEM-based SDE.

  14. Use of zinc and copper (I) salts to reduce sulfur and nitrogen impurities during the pyrolysis of plastic and rubber waste to hydrocarbons

    DOE Patents [OSTI]

    Wingfield, Jr., Robert C. (Southfield, MI); Braslaw, Jacob (Southfield, MI); Gealer, Roy L. (West Bloomfield, MI)

    1984-01-01T23:59:59.000Z

    An improvement in a process for the pyrolytic conversion of rubber and plastic waste to hydrocarbon products which results in reduced levels of nitrogen and sulfur impurities in these products. The improvement comprises pyrolyzing the waste in the presence of at least about 1 weight percent of salts, based on the weight of the waste, preferably chloride or carbonate salts, of zinc or copper (I). This invention was made under contract with or subcontract thereunder of the Department of Energy Contract #DE-AC02-78-ER10049.

  15. Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,

    E-Print Network [OSTI]

    Guo, John Zhanhu

    a maximum value of 15 ppm sulfur content in diesel fuel, and this ultra-low-sulfur fuel is expectedSulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Catalyst Qiang Wang,*, Jiahua of sulfur has not been investigated. In this article, the sulfur poisoning of the NOx storage

  16. CLOSEOUT REPORT FOR HYBRID SULFUR PRESSURIZED BUTTON CELL TEST FACILITY

    SciTech Connect (OSTI)

    Steeper, T.

    2010-09-15T23:59:59.000Z

    This document is the Close-Out Report for design and partial fabrication of the Pressurized Button Cell Test Facility at Savannah River National Laboratory (SRNL). This facility was planned to help develop the sulfur dioxide depolarized electrolyzer (SDE) that is a key component of the Hybrid Sulfur Cycle for generating hydrogen. The purpose of this report is to provide as much information as possible in case the decision is made to resume research. This report satisfies DOE Milestone M3GSR10VH030107.0. The HyS Cycle is a hybrid thermochemical cycle that may be used in conjunction with advanced nuclear reactors or centralized solar receivers to produce hydrogen by watersplitting. The HyS Cycle utilizes the high temperature (>800 C) thermal decomposition of sulfuric acid to produce oxygen and regenerate sulfur dioxide. The unique aspect of HyS is the generation of hydrogen in a water electrolyzer that is operated under conditions where dissolved sulfur dioxide depolarizes the anodic reaction, resulting in substantial voltage reduction. Low cell voltage is essential for both high thermodynamic efficiency and low hydrogen cost. Sulfur dioxide is oxidized at the anode, producing sulfuric acid that is sent to the high temperature acid decomposition portion of the cycle. Sulfur dioxide from the decomposer is cycled back to electrolyzers. The electrolyzer cell uses the membrane electrode assembly (MEA) concept. Anode and cathode are formed by spraying a catalyst, typically platinized carbon, on both sides of a Proton Exchange Membrane (PEM). SRNL has been testing SDEs for several years including an atmospheric pressure Button Cell electrolyzer (2 cm{sup 2} active area) and an elevated temperature/pressure Single Cell electrolyzer (54.8 cm{sup 2} active area). SRNL tested 37 MEAs in the Single Cell electrolyzer facility from June 2005 until June 2009, when funding was discontinued. An important result of the final months of testing was the development of a method that prevents the formation of a sulfur layer previously observed in MEAs used in the Hybrid Sulfur Cycle electrolyzer. This result is very important because the sulfur layer increased cell voltage and eventually destroyed the MEA that is the heart of the cell. Steimke and Steeper [2005, 2006, 2007, 2008] reported on testing in the Single Cell Electrolyzer test facility in several periodic reports. Steimke et. al [2010] issued a final facility close-out report summarizing all the testing in the Single Cell Electrolyzer test facility. During early tests, significant deterioration of the membrane occurred in 10 hours or less; the latest tests ran for at least 200 hours with no sign of deterioration. Ironically, the success with the Single Cell electrolyzer meant that it became dedicated to long runs and not available for quick membrane evaluations. Early in this research period, the ambient pressure Button Cell Electrolyzer test facility was constructed to quickly evaluate membrane materials. Its small size allowed testing of newly developed membranes that typically were not available in sizes large enough to test in the Single Cell electrolyzer. The most promising membranes were tested in the Single Cell Electrolyzer as soon as sufficient large membranes could be obtained. However, since the concentration of SO{sub 2} gas in sulfuric acid decreases rapidly with increasing temperature, the ambient pressure Button Cell was no longer able to achieve the operating conditions needed to evaluate the newer improved high temperature membranes. Significantly higher pressure operation was required to force SO{sub 2} into the sulfuric acid to obtain meaningful concentrations at increased temperatures. A high pressure (200 psig), high temperature (120 C) Button Cell was designed and partially fabricated just before funding was discontinued in June 2009. SRNL completed the majority of the design of the test facility, including preparation of a process and instrument drawing (P&ID) and preliminary designs for the major components. SRNL intended to complete the designs and procu

  17. Toxicology Studies on Lewisite and Sulfur Mustard Agents: Modified Dominant Lethal Study of Sulfur Mustard in Rats Final Report

    SciTech Connect (OSTI)

    Sasser, L. B.; Cushing, J. A.; Kalkwarf, D. R.; Buschbom, R. L.

    1989-05-01T23:59:59.000Z

    Occupational health standards have not been established for sulfur mustard (HD) [bis{2-chloroethyl)-sulfide) ' a strong alkylating agent with known mutagenic properties. Little, however, is known about the mutagenic activity of HD in mammalian species and data regarding the dominant lethal effects of HD are ambiguous. The purpose of this study was to determine the dominant lethal effect in male and female rats orally exposed to HD. The study was conducted in two phases; a female dominant lethal phase and a male dominant lethal phase. Sprague-Dawley rats of each sex were administered 0.08, 0.20, or 0.50 mg/kg HD in sesame oil 5 days/week for 10 weeks. For the female phase, treated or untreated males were mated with treated females and their fetuses were evaluated at approximately 14 days after copulation. For the male dominant lethal phase, treated males cohabited with untreated femal (during 5 days of each week for 10 weeks) and females were sacrificed for fetal evaluation 14 days after the midweek of cohabitation during each of the 10 weeks. The appearance and behavior of the rats were unremarkable throughout the experiment and there were no treatment-related deaths. Growth rates were reduced in both female and male rats treated with 0.50 mg/kg HD. Indicators of reproductive performance did not demonstrate significant female dominant lethal effects, although significant male dominant lethal effects were observed at 2 and 3 week post-exposure. These effects included increases of early fetal resorptions and preimplantation losses and decreases of total live embryo implants. These effects were most consistently observed at a dose of 0.50 mg/kg, but frequently occurred at the lower doses. Although no treatment-related effects on male reproductive organ weights or sperm motility were found, a significant increase in the percentage of abnormal sperm was detected in males exposed to 0. 50 mg/kg HD. The timing of these effects is consistent with an effect during the postmeiotic stages of spermatogenesis, possibly involving the generally sensitive spermatids.

  18. International Global Atmospheric Chemistry Programme global emissions inventory activity: Sulfur emissions from volcanoes, current status

    SciTech Connect (OSTI)

    Benkovitz, C.M.

    1995-07-01T23:59:59.000Z

    Sulfur emissions from volcanoes are located in areas of volcanic activity, are extremely variable in time, and can be released anywhere from ground level to the stratosphere. Previous estimates of global sulfur emissions from all sources by various authors have included estimates for emissions from volcanic activity. In general, these global estimates of sulfur emissions from volcanoes are given as global totals for an ``average`` year. A project has been initiated at Brookhaven National Laboratory to compile inventories of sulfur emissions from volcanoes. In order to complement the GEIA inventories of anthropogenic sulfur emissions, which represent conditions circa specific years, sulfur emissions from volcanoes are being estimated for the years 1985 and 1990.

  19. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

    2012-08-14T23:59:59.000Z

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  20. Preliminary Investigation of Sulfur Loading in Hanford LAW Glass

    SciTech Connect (OSTI)

    Vienna, John D.; Hrma, Pavel R.; Buchmiller, William C.; Ricklefs, Joel S.

    2004-04-01T23:59:59.000Z

    A preliminary estimate was developed for loading limits for high-sulfur low-activity waste (LAW) feeds that will be vitrified into borosilicate glass at the Hanford Site in the waste-cleanup effort. Previous studies reported in the literature were consulted to provide a basis for the estimate. The examination of previous studies led to questions about sulfur loading in Hanford LAW glass, and scoping tests were performed to help answer these questions. These results of these tests indicated that a formulation approach developed by Vienna and colleagues shows promise for maximizing LAW loading in glass. However, there is a clear need for follow-on work. The potential for significantly lowering the amount of LAW glass produced at Hanford (after the initial phase of processing) because of higher sulfur tolerances may outweigh the cost and effort required to perform the necessary testing.

  1. Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report

    SciTech Connect (OSTI)

    NONE

    1997-01-01T23:59:59.000Z

    The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

  2. Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 2, October--December 1992

    SciTech Connect (OSTI)

    Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

    1992-12-31T23:59:59.000Z

    Elemental sulfur recovery from SO{sub 2}-containing gas streams is highly attractive as it produces a saleable. Product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plants(reaction of SO{sub 2} with H{sub 2}S over catalyst). This project win investigate a cerium oxide catalyst for the single-stage selective reduction SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because of its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650C). Kinetic and parametric studies of SO{sub 2} reduction planned over various CeO{sub 2}-formulations will provide the necessary basis for development of a simplified process, a single-stage elemental sulfur recovery scheme from variable concentration gas streams. A first apparent application is treatment of regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

  3. Sulfur gas geochemical detection of hydrothermal systems. Final report

    SciTech Connect (OSTI)

    Rouse, G.E.

    1984-01-01T23:59:59.000Z

    The purpose of this investigation was to determine whether a system of exploration using sulfur gases was capable of detecting convecting hydrothermal systems. Three surveying techniques were used at the Roosevelt Hot Springs KGRA in Utah. These were (a) a sniffing technique, capable of instantaneous determinations of sulfur gas concentration, (b) an accumulator technique, capable of integrating the sulfur gas emanations over a 30 day interval, and (c) a method of analyzing the soils for vaporous sulfur compounds. Because of limitations in the sniffer technique, only a limited amount of surveying was done with this method. The accumulator and soil sampling techniques were conducted on a 1000 foot grid at Roosevelt Hot Springs, and each sample site was visited three times during the spring of 1980. Thus, three soil samples and two accumulator samples were collected at each site. The results are shown as averages of three soil and two accumulator determinations of sulfur gas concentrations at each site. Soil surveys and accumulator surveys were conducted at two additional KGRA's which were chosen based on the state of knowledge of these hydrothermal systems and upon their differences from Roosevelt Hot Springs in an effort to show that the exploration methods would be effective in detecting geothermal reservoirs in general. The results at Roosevelt Hot Springs, Utah show that each of the three surveying methods was capable of detecting sulfur gas anomalies which can be interpreted to be related to the source at depth, based on resistivity mapping of that source, and also correlatable with major structural features of the area which are thought to be controlling the geometry of the geothermal reservoir. The results of the surveys at Roosevelt did not indicate that either the soil sampling technique or the accumulator technique was superior to the other.

  4. Direct sulfur recovery during sorbent regeneration. Final report

    SciTech Connect (OSTI)

    Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

    1993-08-01T23:59:59.000Z

    The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

  5. Improving fractionation lowers butane sulfur level at Saudi gas plant

    SciTech Connect (OSTI)

    Harruff, L.G.; Martinie, G.D.; Rahman, A. [Saudi Arabian Oil Co., Dhahran (Saudi Arabia)

    1998-10-12T23:59:59.000Z

    Increasing the debutanizer reflux/feed ratio to improve fractionation at an eastern Saudi Arabian NGL plant reduced high sulfur in the butane product. The sulfur resulted from dimethyl sulfide (DMS) contamination in the feed stream from an offshore crude-oil reservoir in the northern Arabian Gulf. The contamination is limited to two northeastern offshore gas-oil separation plants operated by Saudi Arabian Oil Co. (Saudi Aramco) and, therefore, cannot be transported to facilities outside the Eastern Province. Two technically acceptable solutions for removing this contaminant were investigated: 13X molecular-sieve adsorption of the DMS and increased fractionation efficiency. The latter would force DMS into the debutanizer bottoms.

  6. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

    1993-01-01T23:59:59.000Z

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  7. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18T23:59:59.000Z

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  8. The Quantitation of Sulfur Mustard By-Products, Sulfur-Containing Herbicides, and Organophosphonates in Soil and Concrete

    SciTech Connect (OSTI)

    Tomkins, B.A., Sega, G.A. [Oak Ridge National Lab., TN (United States)], Macnaughton, S.J. [Microbial Insights, Inc., Rockford, TN (United States)

    1997-12-31T23:59:59.000Z

    Over the past fifty years, the facilities at Rocky Mountain Arsenal have been used for the manufacturing, bottling, and shipping sulfur- containing herbicides, sulfur mustard, and Sarin. There is a need for analytical methods capable of determining these constituents quickly to determine exactly how specific waste structural materials should be handled, treated, and landfilled.These species are extracted rapidly from heated samples of soil or crushed concrete using acetonitrile at elevated pressure, then analyzed using a gas chromatograph equipped with a flame photometric detector. Thiodiglycol, the major hydrolysis product of sulfur mustard, must be converted to a silylated derivative prior to quantitation. Detection limits, calculated using two statistically-unbiased protocols, ranged between 2-13 micrograms analyte/g soil or concrete.

  9. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

    2012-03-06T23:59:59.000Z

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  10. A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts

    E-Print Network [OSTI]

    Tang, Hairong

    2005-01-01T23:59:59.000Z

    Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

  11. Revisit Carbon/Sulfur Composite for Li-S Batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Revisit CarbonSulfur Composite for Li-S Batteries. Revisit CarbonSulfur Composite for Li-S Batteries. Abstract: To correlate the carbon properties e.g. surface area and porous...

  12. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review and Peer Evaluation es105liang2011o.pdf More Documents & Publications CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives...

  13. Chromium modified nickel-iron aluminide useful in sulfur bearing environments

    DOE Patents [OSTI]

    Cathcart, John V. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

    1989-06-13T23:59:59.000Z

    An improved nickel-iron aluminide containing chromium and molybdenum additions to improve resistance to sulfur attack.

  14. 'R. S. Pound, M. A. Saifi, W. C. Hahn, Jr., Solid-State Electron. 17, 245 2S. Margalit, D. Fekete, D. M. Pepper, c.-P. Lee, and A. Yariv, Appl.

    E-Print Network [OSTI]

    Woodall, Jerry M.

    . Fekete, D. M. Pepper, c.-P. Lee, and A. Yariv, Appl. Phys. Lett. 33, 346 (1978). 'R. B. Gold, R. A'R. S. Pound, M. A. Saifi, W. C. Hahn, Jr., Solid-State Electron. 17, 245 (1974). 2S. Margalit, D. D. Hess, C. F. Krum, Ref. 3, p. 641. 5p. A. Barnes, H. J. Leamy, J. M. Poate, and G. K. Celler

  15. Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase

    E-Print Network [OSTI]

    Borguet, Eric

    surface in a fixed-bed reactor. By changing the temperature and duration of the sulfur impregnation mercury adsorption experiments were carried out in a fixed-bed reactor. Sulfur was impregnated mainly a fixed-bed adsorber at room temperature decreased with an increase in sulfur content. Such behavior

  16. Transport Properties and Performance of Polymer Electrolyte Membranes for the Hybrid Sulfur Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    to the cathode.4 However, increased water transport also results in more dilute sulfuric acid, which affectsTransport Properties and Performance of Polymer Electrolyte Membranes for the Hybrid Sulfur and SO2 crossover in the hybrid sulfur cycle electrolyzer were quantified for a poly phenylene -based

  17. Effect of Water Transport on the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Effect of Water Transport on the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer, large-scale production of hydrogen. A key step in the process is the oxidation of sulfur dioxide determines the product sulfuric acid concentration, iii affects SO2 crossover rate, and iv serves to hydrate

  18. REGULAR PAPER Photoproduction of hydrogen by sulfur-deprived C. reinhardtii

    E-Print Network [OSTI]

    Meier, Iris

    dramatic was the effect of sulfur deprivation on the H2-production process, which depends both on the presREGULAR PAPER Photoproduction of hydrogen by sulfur-deprived C. reinhardtii mutants with impaired+Business Media B.V. 2007 Abstract Photoproduction of H2 was examined in a series of sulfur-deprived Chlamydomonas

  19. Dissociation of Import of the Rieske Iron-Sulfur Protein into Saccharomyces cerevisiae Mitochondria from Proteolytic

    E-Print Network [OSTI]

    Trumpower, Bernard L.

    processing peptidase was investigated using high concentrations of metal chelators and iron-sulfur protein- sulfur protein into the mitochondrial matrix is inde- pendent of proteolytic processing first removes a 22-amino acid peptide from the prese- quence of the precursor iron-sulfur protein (p

  20. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08T23:59:59.000Z

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  1. Paper 2008-01-0434 Effects of Sulfur Level and Anisotropy of Sulfide Inclusions on

    E-Print Network [OSTI]

    Fatemi, Ali

    to fatigue strength, the high sulfur material had up to 25% lower fatigue strength than the ultra low sulfur, monotonic tensile and CVN impact behavior of SAE 4140 steel with high (0.077% S), low (0.012% S) and ultra low (0.004% S) sulfur contents at two hardness levels (40 HRC and 50 HRC). The longitudinally oriented

  2. Global Anthropogenic Sulfur Emissions for 1985 and 1990 Carmen M. Benkovitz

    E-Print Network [OSTI]

    the refining process, most of the sulfur i n the crude o i l may be recovered; what i s not #12;recovered remains mainly in the residual sulfur-containing materials (e.g., roast oil fraction. ing of ores), and the use of sulfur compounds to produce other industrial goods (e.g., cellulose production) generate large

  3. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J. (Naperville, IL)

    1990-01-01T23:59:59.000Z

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  4. The Hybrid Sulfur Cycle for Nuclear Hydrogen Production

    SciTech Connect (OSTI)

    Summers, William A.; Gorensek, Maximilian B.; Buckner, Melvin R.

    2005-09-08T23:59:59.000Z

    Two Sulfur-based cycles--the Sulfur-Iodine (SI) and the Hybrid Sulfur (HyS)--have emerged as the leading thermochemical water-splitting processes for producing hydrogen utilizing the heat from advanced nuclear reactors. Numerous international efforts have been underway for several years to develop the SI Cycle, but development of the HyS Cycle has lagged. The purpose of this paper is to discuss the background, current status, recent development results, and the future potential for this thermochemical process. Savannah River National Laboratory (SRNL) has been supported by the U.S. Department of Energy Office of Nuclear Energy, Science, and Technology since 2004 to evaluate and to conduct research and development for the HyS Cycle. Process design studies and flowsheet optimization have shown that an overall plant efficiency (based on nuclear heat converted to hydrogen product, higher heating value basis) of over 50% is possible with this cycle. Economic studies indicate that a nuclear hydrogen plant based on this process can be economically competitive, assuming that the key component, the sulfur dioxide-depolarized electrolyzer, can be successfully developed. SRNL has recently demonstrated the use of a proton-exchange-membrane electrochemical cell to perform this function, thus holding promise for economical and efficient hydrogen production.

  5. Revisit Carbon/Sulfur Composite for Li-S Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wagner, Michael J.; Hays, Kevin; Li, Xiaohong S.; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-07-23T23:59:59.000Z

    To correlate the carbon properties e.g. surface area and porous structure, with the electrochemical behaviors of carbon/sulfur (C/S) composite cathodes for lithium-sulfur (Li-S) batteries, four different carbon frameworks including Ketjen Black (KB, high surface area and porous), Graphene (high surface area and nonporous), Acetylene Black (AB, low surface area and nonporous) and Hollow Carbon Nano Sphere (HCNS, low surface area and porous) are employed to immobilize sulfur (80 wt.%). It has been revealed that high surface area of carbon improves the utilization rate of active sulfur and decreases the real current density during the electrochemical reactions. Accordingly, increased reversible capacities and reduced polarization are observed for high surface area carbon hosts such as KB/S and graphene/S composites. The porous structure of KB or HCNS matrix promotes the long-term cycling stability of C/S composites but only at relatively low rate (0.2 C). Once the current density increases, the pore effect completely disappears and all Li-S batteries show similar trend of capacity degradation regardless of the different carbon hosts used in the cathodes. The reason has been assigned to the formation of reduced amount of irreversible Li2S on the cathode as well as shortened time for polysulfides to transport towards lithium anode at elevated current densities. This work provides valuable information for predictive selection on carbon materials to construct C/S composite for practical applications from the electrochemical point of view.

  6. Sodium and sulfur release and recapture during black liquor burning

    SciTech Connect (OSTI)

    Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

    1995-08-01T23:59:59.000Z

    The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

  7. Argonne Electrochemical Technology Program Sulfur removal from reformate

    E-Print Network [OSTI]

    Argonne Electrochemical Technology Program Sulfur removal from reformate Xiaoping Wang, Theodore Krause, and Romesh Kumar Chemical Engineering Division Argonne National Laboratory Hydrogen, Fuel Cells, and Infrastructure Technologies 2003 Merit Review Berkeley, CA May 19-22, 2003 #12;Argonne Electrochemical Technology

  8. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01T23:59:59.000Z

    This document summarizes progress on the Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2000 through September 30, 2000. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid will also be determined, as will the removal of arsenic, a known poison for NOX selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), First Energy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the second reporting period for the subject Cooperative Agreement. During this period, the first of four short-term sorbent injection tests were conducted at the First Energy Bruce Mansfield Plant. This test determined the effectiveness of dolomite injection through out-of-service burners as a means of controlling sulfuric acid emissions from this unit. The tests showed that dolomite injection could achieve up to 95% sulfuric acid removal. Balance of plant impacts on furnace slagging and fouling, air heater fouling, ash loss-on-ignition, and the flue gas desulfurization system were also determined. These results are presented and discussed in this report.

  9. Sulfur controls edge closer in acid-rain debate

    SciTech Connect (OSTI)

    Not Available

    1984-10-04T23:59:59.000Z

    The role of airborne sulfur emissions from midwestern and southern coal-fired power plants in exacerbating the acid rain problem is discussed. This problem is discussed from the standpoint of legislation, compliance costs, scrubber performance and cost, and chemistry of acid rains.

  10. Auction design and the market for sulfur dioxide emissions

    E-Print Network [OSTI]

    Joskow, Paul L.

    1996-01-01T23:59:59.000Z

    Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

  11. ADVANCED SULFUR CONTROL CONCEPTS FOR HOT-GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect (OSTI)

    A. LOPEZ ORTIZ; D.P. HARRISON; F.R. GROVES; J.D. WHITE; S. ZHANG; W.-N. HUANG; Y. ZENG

    1998-10-31T23:59:59.000Z

    This research project examined the feasibility of a second generation high-temperature coal gas desulfurization process in which elemental sulfur is produced directly during the sorbent regeneration phase. Two concepts were evaluated experimentally. In the first, FeS was regenerated in a H2O-O2 mixture. Large fractions of the sulfur were liberated in elemental form when the H2O-O2 ratio was large. However, the mole percent of elemental sulfur in the product was always quite small (<<1%) and a process based on this concept was judged to be impractical because of the low temperature and high energy requirements associated with condensing the sulfur. The second concept involved desulfurization using CeO2 and regeneration of the sulfided sorbent, Ce2O2S, using SO2 to produce elemental sulfur directly. No significant side reactions were observed and the reaction was found to be quite rapid over the temperature range of 500°C to 700°C. Elemental sulfur concentrations (as S2) as large as 20 mol% were produced. Limitations associated with the cerium sorbent process are concentrated in the desulfurization phase. High temperature and highly reducing coal gas such as produced in the Shell gasification process are required if high sulfur removal efficiencies are to be achieved. For example, the equilibrium H2S concentration at 800°C from a Shell gas in contact with CeO2 is about 300 ppmv, well above the allowable IGCC specification. In this case, a two-stage desulfurization process using CeO2 for bulk H2S removal following by a zinc sorbent polishing step would be required. Under appropriate conditions, however, CeO2 can be reduced to non-stoichiometric CeOn (n<2) which has significantly greater affinity for H2S. Pre-breakthrough H2S concentrations in the range of 1 ppmv to 5 ppmv were measured in sulfidation tests using CeOn at 700°C in highly reducing gases, as measured by equilibrium O2 concentration, comparable to the Shell gas. Good sorbent durability was indicated in a twenty-five-cycle test. The sorbent was exposed for 58 consecutive days to temperatures between 600°C and 800°C and gas atmospheres from highly reducing to highly oxidizing without measurable loss of sulfur capacity or reactivity. In the process analysis phase of this study, a two-stage desulfurization process using cerium sorbent with SO2 regeneration followed by zinc sorbent with dilute O2 regeneration was compared to a single-stage process using zinc sorbent and O2 regeneration with SO2 in the regeneration product gas converted to elemental sulfur using the direct sulfur recovery process (DSRP). Material and energy balances were calculated using the process simulation package PRO/II. Major process equipment was sized and a preliminary economic analysis completed. Sorbent replacement rate, which is determined by the multicycle sorbent durability, was found to be the most significant factor in both processes. For large replacement rates corresponding to average sorbent lifetimes of 250 cycles or less, the single-stage zinc sorbent process with DSRP was estimated to be less costly. However, the cost of the two-stage cerium sorbent process was more sensitive to sorbent replacement rate, and, as the required replacement rate decreased, the economics of the two-stage process improved. For small sorbent replacement rates corresponding to average sorbent lifetimes of 1000 cycles or more, the two-stage cerium process was estimated to be less costly. In the relatively wide middle range of sorbent replacement rates, the relative economics of the two processes depends on other factors such as the unit cost of sorbents, oxygen, nitrogen, and the relative capital costs.

  12. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M; Lytle, J.M.; Ruch, R.R.; Kruse, C.W.; Chaven, C.; Hackley, K.C.; Hughes, R.E.; Harvey, R.D.; Frost, J.K. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States); Huffman, G.; Huggins, F.E. [Kentucky Univ., Lexington, KY (United States)

    1992-09-01T23:59:59.000Z

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal preoxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation.

  13. Emission of volatile sulfur compounds during composting of municipal solid waste (MSW)

    SciTech Connect (OSTI)

    Zhang, Hongyu [Beijing Building Materials Academy of Science Research/State Key Laboratory of Solid Waste Reuse for Building Material, Beijing 100041 (China); College of Resources and Environment Sciences, China Agricultural University, Beijing 100094 (China); Schuchardt, Frank [Johann Heinrich von Thuenen-Institute, Institute of Agricultural Technology and Biosystems Engineering, Bundesallee 50, 38116 Braunschweig (Germany); Li, Guoxue, E-mail: ligx@cau.edu.cn [College of Resources and Environment Sciences, China Agricultural University, Beijing 100094 (China); Yang, Jinbing; Yang, Qingyuan [College of Resources and Environment Sciences, China Agricultural University, Beijing 100094 (China)

    2013-04-15T23:59:59.000Z

    Highlights: ? We compare the volatile sulfur compounds (VSCs) emissions during three types of municipal solid wastes (MSWs) composting. ? The VSCs released from the kitchen waste composting was significantly higher than that from 15–80 mm fraction of MSW. ? Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. ? Addition of 20% cornstalks could significantly reduce the VSCs emissions during kitchen waste composting. - Abstract: Volatile sulfur compounds (VSCs) are the main source for malodor from composting plants. In this study, the VSCs generated from composting of 15–80 mm municipal solid waste (T0), kitchen waste (T1) and kitchen waste mixed dry cornstalks (T2) were measured in 60 L reactors with forced aeration for a period of 30 days. The VSCs detected in all treatments were hydrogen sulfide (H{sub 2}S), methyl mercaptan (MM), dimethyl sulfide (DMS), carbon bisulfide (CS{sub 2}) and dimethyl disulfide (DMDS). Over 90% of the VSCs emissions occurred during the first 15 days, and reached their peak values at days 4–7. The emission profiles of five VSCs species were significantly correlated with internal materials temperature and outlet O{sub 2} concentration (p < 0.05). Total emissions of the VSCs were 216.1, 379.3 and 126.0 mg kg{sup ?1} (dry matter) for T0, T1 and T2, respectively. Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. Composting of kitchen waste from separate collection posed a negative influence on the VSC and leachate production because of its high moisture content. An addition of dry cornstalks at a mixing ratio of 4:1 (wet weight) could significantly reduce the VSCs emissions and avoid leachate. Compared to pure kitchen waste, VSCs were reduced 66.8%.

  14. Mass-dependent fractionation of quadruple stable sulfur isotope system as a new tracer of sulfur biogeochemical cycles

    E-Print Network [OSTI]

    Long, Bernard

    - ing rare isotopes for Earth materials was the discovery of anomalous 17 O abundance in a wide variety, USA b Department of Geology and Earth System Science Interdisciplinary Center, University of Maryland and extraterrestrial materials. Ã? 2006 Elsevier Inc. All rights reserved. 1. Introduction Sulfur (32 S, 33 S, 34 S

  15. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20T23:59:59.000Z

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  16. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01T23:59:59.000Z

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  17. Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

  18. Method of making sulfur-resistant composite metal membranes

    DOE Patents [OSTI]

    Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

    2012-01-24T23:59:59.000Z

    The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

  19. Molecular weight and molecular weight distribution of kraft lignins

    SciTech Connect (OSTI)

    Schmidl, W.; Dong, D.; Fricke, A.L. (Univ. of Florida, Gainesville, FL (United States))

    1990-01-01T23:59:59.000Z

    Kraft lignins are the lignin degradation products from kraft pulping. They are complex, heterogeneous polymers with some polar character. The molecular weight of kraft lignins greatly affect the physical properties of black liquors, and are of primary importance in separation from black liquor and in evaluating potential uses. Several purified kraft lignins from slash pine were analyzed for number average molecular weight by vapor pressure osmometry (VPO), for weight average molecular weight by low angle laser light scattering (LALLS), and for the molecular weight distribution by high temperature size exclusion chromatography (SEC). The lignins were run in tetrahydrofuran (THF), N,N-dimethyl formamide (DMF), DMF with 0.1M LiBr, and pyridine at conditions above the Theta temperature. Experimental methods are discussed. The results show that VPO may be used to determine M[sub n] for kraft lignins if the purity of the lignins and the identity of the impurities are known. LALLS can be used to determine M[sub w] for kraft lignins if measurements are made at or above the Theta temperature of the lignin-solvent pair. SEC should be used at temperatures at, or above, the Theta temperature of the lignin-solvent pair. Size separation is highly dependent on the solvent used, and DMF is a much better solvent than THF for high temperature SEC. Future work using moment resolution procedures to derive an accurate calibration curve are also discussed.

  20. ADVANCED SULFUR CONTROL CONCEPTS FOR HOT GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect (OSTI)

    Unknown

    1999-04-01T23:59:59.000Z

    The objective of this project is to develop a hot-gas desulfurization process scheme for control of H{sub 2}S in HTHP coal gas that can be more simply and economically integrated with known regenerable sorbents in DOE/METC-sponsored work than current leading hot-gas desulfurization technologies. In addition to being more economical, the process scheme to be developed must yield an elemental sulfur byproduct.

  1. Sulfur Isotopes as Indicators of Amended Bacterial Sulfate

    E-Print Network [OSTI]

    Hubbard, Susan

    Scale Uranium Bioremediation J E N N I F E R L . D R U H A N , * , M A R K E . C O N R A D , K E N N E September 5, 2008. Accepted September 8, 2008. Aqueous uranium (U(VI)) concentrations in a contaminated(II), sulfate, sulfide, acetate, U(VI), and 34S of sulfate and sulfide to explore the utility of sulfur isotopes

  2. Intensities of electronic transitions in sulfur dioxide vapor

    E-Print Network [OSTI]

    McCray, James Arthur

    1955-01-01T23:59:59.000Z

    . Relation between Oscillator Strength and Probability Coefficient of Absorption . . . . . . . . . . . . . . . . 20 V. The Ultraviolet Spectrum of Sulfur Dioxide Gas . . . . . . 22 ) VI. Experimental Procedure and Computations . . . . . . . . . 23 U A... where )(e is defined as the dielectric constant of the medium. This equation holds for radiation which has a frequency sufficiently dif- ferent from that of the resonant frequencies of'the molecules of the medium, The polarizability o( of a molecule...

  3. Posting type Informational Subject Changed reporting of XRF sulfur

    E-Print Network [OSTI]

    Fischer, Emily V.

    Posting type Informational Subject Changed reporting of XRF sulfur Module/Species A/ S Sites entire network Period Starting 1/1/05 Submitter W.H. White, white@crocker.ucdavis.edu Supporting information XRF and 2005 seen in Figure 1. 0.9 1 1.1 1.2 1.3 1.4 12/1/04 1/1/05 2/1/05 3S/SO4 = ADJUSTMENT REPORTED XRF

  4. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01T23:59:59.000Z

    A test program is being sponsored by the US Department of Energy (DOE), EPRI, FirstEnergy, and TVA to investigate furnace injection of alkaline sorbents as a means of reducing sulfuric acid concentrations in the flue gas from coal-fired boilers. This test program is being conducted at the FirstEnergy Bruce Mansfield Plant (BMP), although later testing will be conducted at a TVA plant. A sorbent injection test was conducted the week of April 18, 2000. The test was the first of several short-term (one- to two-week duration) tests to investigate the effectiveness of various alkaline sorbents for sulfuric acid control and the effects of these sorbents on boiler equipment performance. This first short-term test investigated the effect of injecting dry dolomite powder (CaCO{sub 3} {center_dot} MgCO{sub 3}), a mineral similar to limestone, into the furnace of Unit 2. During the test program, various analytical techniques were used to assess the effects of sorbent injection. These primarily included sampling with the controlled condensation system (CCS) for determining flue gas SO{sub 3} content and an acid dew-point (ADP) meter for determining the sulfuric acid dew point (and, indirectly, the concentration of sulfuric acid) of the flue gas. EPA Reference Method 26a was used for determining hydrochloric acid (HCl) and hydrofluoric acid (HF), as well and chlorine (Cl{sub 2}) and fluorine (F{sub 2}) concentrations in the flue gas. Fly ash resistivity was measured using a Southern Research Institute (SRI) point-to-plane resistivity probe, and unburned carbon in fly ash was determined by loss on ignition (LOI). Coal samples were also collected and analyzed for a variety of parameters. Finally, visual observations were made of boiler furnace and convective pass surfaces prior to and during sorbent injection.

  5. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01T23:59:59.000Z

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  6. How to Obtain Reproducible Results for Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Lu, Dongping; Gu, Meng; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-01-01T23:59:59.000Z

    The basic requirements for getting reliable Li-S battery data have been discussed in this work. Unlike Li-ion batteries, electrolyte-rich environment significantly affects the cycling stability of Li-S batteries prepared and tested under the same conditions. The reason has been assigned to the different concentrations of polysulfide-containing electrolytes in the cells, which have profound influences on both sulfur cathode and lithium anode. At optimized S/E ratio of 50 g L-1, a good balance among electrolyte viscosity, wetting ability, diffusion rate dissolved polysulfide and nucleation/growth of short-chain Li2S/Li2S2 has been built along with largely reduced contamination on the lithium anode side. Accordingly, good cyclability, high reversible capacity and Coulombic efficiency are achieved in Li-S cell with controlled S/E ratio without any additive. Other factors such as sulfur content in the composite and sulfur loading on the electrode also need careful concern in Li-S system in order to generate reproducible results and gauge the various methods used to improve Li-S battery technology.

  7. Removal of nitrogen and sulfur from oil-shale

    SciTech Connect (OSTI)

    Olmstead, W.N.

    1986-01-28T23:59:59.000Z

    This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

  8. Sibley station low-sulfur coal conversion program

    SciTech Connect (OSTI)

    Rupinskas, R.L. [Sargent & Lundy LLC, Chicago, IL (United States); Rembold, D.F. [Missouri Public Service, Kansas City, MO (United States)

    1995-03-01T23:59:59.000Z

    After embarking on an upgrade project in 1986 that was designed to allow efficient and reliable operation of its coal-fired Sibley station through 2010, Missouri Public Service (MPS) faced the uncertainty of impending acid-rain legislation. To protect its investment in the Sibley Rebuild Program, the utility evaluated compliance options based on the emerging legislation and concluded that switching to low-sulfur coal offered the least-cost compliance approach. Compared to installing a scrubber, switching to a low-sulfur coal was also more straightforward, although not without challenges and complications. This paper reviews the Sibley low-sulfur coal conversion program. At Sibley, fuel switching was chosen only after numerous internal and external studies; it withstood late challenges from natural gas and allowance trading. Switching demanded additional equipment to blend Power River Basin coals and other coals, and demanded additional and upgraded protective equipment in the areas of fire protection, dust collection, and explosion prevention. In the year since the coal conversion project was completed the facility has operated reliably, the economic benefits of the lower cost Powder River Basin coals have been realized, and the station has also met the requirements of both phases of the acid rain legislation. Fuel switching at Sibley required a team approach and careful analysis. The coal conversion project also required attention and dedication by team members in order to minimize fuel costs while maintaining optimum plant efficiency and availability.

  9. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22T23:59:59.000Z

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  10. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Yang, Xiao-Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Zhang, Xuran [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Li, Chao [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; McKinnon, Meaghan E. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Sadok, Rachel G. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Qu, Deyu [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Yu, Xiqian [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry

    2014-11-01T23:59:59.000Z

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  11. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-11-01T23:59:59.000Z

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore »the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  12. Abundances of sulfur, chlorine, and trace elements in Illinois Basin coals, USA

    SciTech Connect (OSTI)

    Chou, C.L. [Illinois State Geological Survey, Champaign, IL (United States)

    1997-12-31T23:59:59.000Z

    Abundances of sulfur, chlorine and 52 trace elements in 220 channel and drill-core samples of high volatile bituminous coals (Pennsylvanian age) from the Illinois Basin, USA, are evaluated for the purpose of better understanding geologic processes affecting trace element variation in the coal seams. Mean elemental abundances in Illinois Basin coals are listed in a table. Most Illinois Basin coals are high-sulfur (> 3% total sulfur). Peat was influenced by seawater during early diagenesis. However, low-medium sulfur coal (<3% total sulfur) occurs in restricted areas along the Walshville Channel, which is a contemporaneous river in the peat swamp. A comparison of trace element abundances between high-sulfur and low-medium sulfur coals showed that only seven elements (boron, sulfur, iron, molybdenum, mercury, thallium, and uranium) are clearly more abundant in high-sulfur coal than in low-medium sulfur coal. Apparently, boron, sulfur, molybdenum, and uranium in high-sulfur coals were derived from seawater that inundated the peat swamp and terminated peat accumulation. Iron, mercury, and thallium had a terrestrial source and were incorporated in pyrite during diagenesis. Their enrichment in high-sulfur coal is related to pyrite formation in a reducing environment. The chlorine content in Illinois Basin coals, including channel and drill core samples, varies from 0.01% to 0.8% (on a dry basis). Coal samples from surface mines (< 50 meter depth) are usually low in chlorine content (<0.1%). Samples from underground mines (> 50 meter depth) have a chlorine content ranging between 0.1% to 0.5%. Variation of chlorine content in each of the two coal seams shows that chlorine content increases with depth because the chloride in coal is in equilibrium with the chloride in the groundwater, which is also depth dependent. A low chlorine content in shallow regions of a coal seam is a result of leaching by fresh groundwater.

  13. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15T23:59:59.000Z

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  14. Weighted Watson-Crick automata

    SciTech Connect (OSTI)

    Tamrin, Mohd Izzuddin Mohd [Department of Information System, Kulliyyah of Information and Communication Technology, International Islamic University Malaysia, 50728 Gombak, Selangor (Malaysia); Turaev, Sherzod; Sembok, Tengku Mohd Tengku [Department of Computer Science, Kulliyyah of Information and Communication Technology, International Islamic University Malaysia, 50728 Gombak, Selangor (Malaysia)

    2014-07-10T23:59:59.000Z

    There are tremendous works in biotechnology especially in area of DNA molecules. The computer society is attempting to develop smaller computing devices through computational models which are based on the operations performed on the DNA molecules. A Watson-Crick automaton, a theoretical model for DNA based computation, has two reading heads, and works on double-stranded sequences of the input related by a complementarity relation similar with the Watson-Crick complementarity of DNA nucleotides. Over the time, several variants of Watson-Crick automata have been introduced and investigated. However, they cannot be used as suitable DNA based computational models for molecular stochastic processes and fuzzy processes that are related to important practical problems such as molecular parsing, gene disease detection, and food authentication. In this paper we define new variants of Watson-Crick automata, called weighted Watson-Crick automata, developing theoretical models for molecular stochastic and fuzzy processes. We define weighted Watson-Crick automata adapting weight restriction mechanisms associated with formal grammars and automata. We also study the generative capacities of weighted Watson-Crick automata, including probabilistic and fuzzy variants. We show that weighted variants of Watson-Crick automata increase their generative power.

  15. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-04-29T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub X} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub X} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the previous semi-annual technical progress report (April 1, 2001 through September 30, 2001). During the current reporting period, additional balance of plant impact information was determined for one of the two tests. These additional balance-of-plant results are presented and discussed in this report. There was no other technical progress to report, because all planned testing as part of this project has been completed.

  16. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2001-11-06T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

  17. ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Gorensek, M.; Edwards, T.

    2009-06-11T23:59:59.000Z

    A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

  18. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Knight, R.A. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-12-31T23:59:59.000Z

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In this project, two approaches to sulfur reduction are being explored in conjunction with thermocracking: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to thermocracking. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation of the scrubbing solvent and light-to-middle oils to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization is the same material previously studied, which was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous either as live cultures or in the form of concentrated biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous flash thermocracker (FTC) constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches. This quarter, 45 kg of IBC-109 coal was obtained and sized to 40 x 80 mesh for mild gasification. Laboratory experiments were conducted to identify means of dispersing or emulsifying pitch in water to render is accessible to biocatalysts, and exploratory desulfurization tests on one-gram pitch samples were begun.

  19. Molecular Weight & Energy Transport 7 September 2011

    E-Print Network [OSTI]

    Militzer, Burkhard

    't transport the bulk of the energy in the sun. #12;Molecular Weight & Energy Transport 7 September 2011 Goals · Review mean molecular weight this intuitively before looking back at your quantitative results. #12;molecular weight & energy transport 2 Energy

  20. Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Lin, Zhan [ORNL] [ORNL; Liu, Zengcai [ORNL] [ORNL; Fu, Wujun [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Given the great potential for improving the energy density of state-of-the-art lithium-ion batteries by a factor of 5, a breakthrough in lithium-sulfur (Li-S) batteries will have a dramatic impact in a broad scope of energy related fields. Conventional Li-S batteries that use liquid electrolytes are intrinsically short-lived with low energy efficiency. The challenges stem from the poor electronic and ionic conductivities of elemental sulfur and its discharge products. We report herein lithium polysulfidophosphates (LPSP), a family of sulfur-rich compounds, as the enabler of long-lasting and energy-efficient Li-S batteries. LPSP have ionic conductivities of 3.0 10-5 S cm-1 at 25 oC, which is 8 orders of magnitude higher than that of Li2S (~10-13 S cm-1). The high Li-ion conductivity of LPSP is the salient characteristic of these compounds that impart the excellent cycling performance to Li-S batteries. In addition, the batteries are configured in an all-solid state that promises the safe cycling of high-energy batteries with metallic lithium anodes.

  1. Standard test method for conducting drop-weight test to determine nil-ductility transition temperature of ferritic steels

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2006-01-01T23:59:59.000Z

    1.1 This test method covers the determination of the nil-ductility transition (NDT) temperature of ferritic steels, 5/8 in. (15.9 mm) and thicker. 1.2 This test method may be used whenever the inquiry, contract, order, or specification states that the steels are subject to fracture toughness requirements as determined by the drop-weight test. 1.3 The values stated in inch-pound units are to be regarded as the standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  2. Portable instrument and method for detecting reduced sulfur compounds in a gas

    DOE Patents [OSTI]

    Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

    1983-06-01T23:59:59.000Z

    A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

  3. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    200 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

  4. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    200 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

  5. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    of long cycle life in half cells and expand the synthesis of sulfurcarbon composite materials of various sulfur loading 2. Compare the performance for different...

  6. Sulfur barrier for use with in situ processes for treating formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Christensen, Del Scot (Friendswood, TX)

    2009-12-15T23:59:59.000Z

    Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

  7. SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-03-04T23:59:59.000Z

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NOX control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

  8. SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-02-04T23:59:59.000Z

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NO{sub x} control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two First Energy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

  9. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-10-01T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2003 through September, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the eighth reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the report for the time period April 1, 2002 through September 30, 2002. During the current period, process economic estimates were developed, comparing the costs of the furnace magnesium hydroxide slurry injection process tested as part of this project to a number of other candidate SO{sub 3}/sulfuric acid control technologies for coal-fired power plants. The results of this economic evaluation are included in this progress report.

  10. SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-07-03T23:59:59.000Z

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

  11. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States)] [and others

    1992-12-31T23:59:59.000Z

    The purposes of this Testing and Materials (ASTM) forms of sulfur analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation. Problem that limits commercial application of the PCE process is the high chlorine content in the PCE-treated coals. Hence, to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal is an additional goal of this investigation. MWOPC`s results have been repeated on fresh IBC-104 coal. Oxidation of coals was found to affect subsequent PCE desulfurization. Elemental sulfur is more amenable to removal by PCE. Ohio 5/6 coal appears to produce elemental sulfur more readily than Illinois coal during oxidation. Data from X-Ray Diffraction spectroscopy indicate that sulfate in the oxidized Illinois IBC-104 coal is mainly in gypsum form, whereas, sulfate in oxidized Ohio 5/6 sample is mainly in szomolnokite form. These data suggest that the oxidation reaction for Ohio 5/6 coal might occur under catalytic conditions which readily convert pyrite to produce FeSO{sub 4} and elemental sulfur. The higher elemental sulfur content in that coal results in higher ASTM organic sulfur removal by PCE extraction. From mass balance calculation, 96% of the total sulfur and greater than 95% of total iron were accounted for during our PCE tests with both long-term ambient-oxidized IBC-104 coal and ambient-oxidized Ohio 516 coal.

  12. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01T23:59:59.000Z

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  13. Investigation of Sulfur Removal by Direct Limestone Injection

    E-Print Network [OSTI]

    Colaluca, M. A.; Maloney, D. J.

    Stream Cleanup Systems Contractors Review Meeting, DOE/METC 88/6094, Contract DE-AC21-86MC23262, 295-304. Chase, et al, 1985, JANAF Thermochemical Tables, J. Phys. Chern. Ref. Data, 14, Suppl. 1. Cole, J. A., Kramlich, J. C., Seeker, W. R...-IE-90-06-05 Proceedings from the 12th National Industrial Energy Technology Conference, Houston, TX, June 19-20, 1990 Newton, G. H., Chen, S. L., and Kramlich, J. D., 1989, Role of Porosity Less in Limiting Sulfur Dioxide Capture by Calcium...

  14. Effects of dairy intake on weight maintenance

    E-Print Network [OSTI]

    Zemel, Michael B.; Donnelly, Joseph E.; Smith, Bryan K.; Sullivan, Debra K.; Richards, Joanna; Morgan-Hanusa, Danielle; Mayo, Matthew S.; Sun, Xiaocun; Cook-Wiens, Galen; Bailey, Bruce W.; Van Walleghen, Emily L.; Washburn, Richard A.

    2008-10-24T23:59:59.000Z

    . However, weight maintenance following successful weight loss is a critical component to the successful management of obesity, and although there are animal data to support the concept of calcium and dairy attenuation of weight and fat regain [23... or components of body composition. The premise of this investigation was that correction of dietary calcium and dairy insufficiency may attenuate weight regain following successful weight loss. Accord- ingly, it was important to have a clear comparison of inad...

  15. ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP

    SciTech Connect (OSTI)

    Ron Rohrbach; Gary Zulauf; Tim Gavin

    2003-04-01T23:59:59.000Z

    Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-duty as well. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consists of four phases. Phase I will focus on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II we will concentrate on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III will study life cycle and regeneration options for the spent filter. Phase IV will focus on efficacy and life testing and component integration. The project team will include a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Mack Trucks Inc.), a filter recycler (American Wastes Industries), and a low-sulfur fuel supplier (Equilon, a joint venture between Shell and Texaco).

  16. Investigation of a sulfur reduction technique for mild gasification char

    SciTech Connect (OSTI)

    Knight, R.A.

    1991-01-01T23:59:59.000Z

    The object of this program is to investigate the desulfurization of mild gasification char using hydrogen/methane mixtures in a laboratory-scale experimental study. In the first year of the two- year program, char is being treated with mixtures of H{sub 2} and CH{sub 4} at temperatures of 1100{degrees}C to 1550{degrees}F and pressures of 50 to 100 psig. The effects of temperature, pressure, residence time, gas velocity, and gas composition on sulfur removal and carbon gasification are being determined. The batch experiments are being performed in a nominal 2-inch-ID stainless-steel, batch, fluidized-bed reactor. The char to be desulfurized was produced by the IGT mild gasification process research unit (PRU) in a recently completed DOE/METC-sponsored technology development program. The parent coal was Illinois No. 6 from a preparation plant, and the char from the selected test contains 4.58 wt% sulfur. In the first quarter, we have obtained and prepared a char for the desulfurization tests. Ultimate and proximate analyses were performed on this char, and its pore size distribution and surface area were determined. Also this quarter, the fluidized-bed reactor system was constructed and equipped with high pressure mass flow controllers and a high pressure sintered metal filter to remove fines from the effluent gas stream.

  17. Catalysts for the selective oxidation of hydrogen sulfide to sulfur

    DOE Patents [OSTI]

    Srinivas, Girish (Thornton, CO); Bai, Chuansheng (Baton Rouge, LA)

    2000-08-08T23:59:59.000Z

    This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

  18. A novel coal feeder for production of low sulfur fuel

    SciTech Connect (OSTI)

    Khang, S.J.; Lin, L.; Keener, T.C.; Yeh, P.

    1991-01-01T23:59:59.000Z

    A dual-screw feeder was designed for desulfurization of coal. This reactor contains two screw tubes, the inner tube acting as a coal pyrolizer and the outer tube acting as a desulfurizer with hot calcined lime pellets or other renewable sorbent pellets. The objectives of this project is to study the feasibility of an advanced concept of desulfurization and possibly some denitrification in this coal feeder. In this year, two basic studies have been performed: (1) the desulfurization and (2) the denitrification due to mild pyrolysis. Specifically, the following tasks have been performed: (1) Setting up the Dual-Screw reactor, (2) Determination of the pyrolysis product and the sulfur distribution in char, tar and gas based on experimental data, (3) Study of the devolatilization, the desulfurization kinetics and the denitrification kinetics and obtaining the basic kinetic parameters, (4) Study of the sulfur removal efficiency of lime pellets fed into the outer tube of the dual-feeder reactor, (5) Study of the effect of the coal particle size on pyrolysis and desulfurization, (6) Study of the coal pyrolysis and desulfurization using a TGA(Thermal Gravimetric Analyzer).

  19. Crystal structure studies on sulfur oxygenase reductase from Acidianus tengchongensis

    SciTech Connect (OSTI)

    Li Mei [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Chen Zhiwei [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); Zhang Pingfeng; Pan Xiaowei [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Jiang Chengying [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); An Xiaomin [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Liu Shuangjiang [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); Chang Wenrui [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China)], E-mail: wrchang@sun5.ibp.ac.cn

    2008-05-09T23:59:59.000Z

    Sulfur oxygenase reductase (SOR) simultaneously catalyzes oxidation and reduction of elemental sulfur to produce sulfite, thiosulfate, and sulfide in the presence of molecular oxygen. In this study, crystal structures of wild type and mutants of SOR from Acidianus tengchongensis (SOR-AT) in two different crystal forms were determined and it was observed that 24 identical SOR monomers form a hollow sphere. Within the icosatetramer sphere, the tetramer and trimer channels were proposed as the paths for the substrate and products, respectively. Moreover, a comparison of SOR-AT with SOR-AA (SOR from Acidianus ambivalens) structures showed that significant differences existed at the active site. Firstly, Cys31 is not persulfurated in SOR-AT structures. Secondly, the iron atom is five-coordinated rather than six-coordinated, since one of the water molecules ligated to the iron atom in the SOR-AA structure is lost. Consequently, the binding sites of substrates and a hypothetical catalytic process of SOR were proposed.

  20. Weight and volume relationships in fluid dairy products

    E-Print Network [OSTI]

    Wilson, Robert Ray

    1962-01-01T23:59:59.000Z

    regxession equations xelating pounds per gallon at given temperatures to the fat percentage and the specific gravity at 102o/'102oP determined with the Watson lactometer in 50 samples of xaw hexd milk . . . . . . . 50 vi LIST 0F TABLES (Cont. ) Table... relating specific gravity by the Babcock bottle method and pounds per gallon to the fat percentage, solids-not-fat percentage, and temperature (op) in 35 samples of fortified and non-fortified skim- milk ~ o ~ e a ~ ~ ~ a ~ o ~ o ~ ~ ~ ~ ~ ~ ~ 70...

  1. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2004-01-01T23:59:59.000Z

    The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

  2. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-06-01T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2002 through March 31, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the seventh reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO3 removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the previous report (April 1, 2002 through September 30, 2002). During the current period, there was no technical progress to report, because all planned testing as part of this project has been completed. The project period of performance was extended to allow the conduct of testing of another SO{sub 3} control technology, the sodium bisulfite injection process. However, these additional tests have not yet been conducted.

  3. Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis

    E-Print Network [OSTI]

    Harris, E.

    The oxidation of SO[subscript 2] to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to ...

  4. Production of low sulfur binder pitich from high-sulfur Illinois coals. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect (OSTI)

    Knight, R.A.

    1995-12-31T23:59:59.000Z

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. Previously, flash thermocracking (FTC) was used to successfully upgrade the properties of mild gasification pitch, yielding a suitable blending stock for use as a binder in the production of carbon electrodes for the aluminum industry. However, in pitches from high-sulfur (4%) Illinois coal, the pitch sulfur content (2%) was still higher than preferred. In this project two approaches to sulfur reduction are being explored in conjunction with FTC: (1) the use of a moderate-sulfur (1.2%) Illinois coal as mild gasification feedstock, and (2) direct biodesulfurization of the liquids from high-sulfur coal prior to FTC. In Case 1, the liquids are being produced by mild gasification of IBC-109 coal in a bench-scale fluidized-bed reactor, followed by distillation to isolate the crude pitch. In Case 2, biodesulfurization with Rhodococcus Rhodochrous IGTS8 biocatalyst is being performed on crude pitch obtained from Illinois No. 6 coal tests conducted in the IGT MILDGAS PRU in 1990. Following preparation of the crude pitches, pitch upgrading experiments are being conducted in a continuous FTC reactor constructed in previous ICCI-sponsored studies. This quarter, mild gasification of IBC-109 coal was completed, producing 450 g of coal liquids, which were then distilled to recover 329 g of Case 1 crude pitch. Next month, the pitch will be subjected to FTC treatment and evaluated. Biodesulfurization experiments were performed on Case 2 pitch dispersed in l-undecanol, resulting in sulfur reductions of 15.1 to 21.4%. This was marginally lower than the 24.8% desulfurization obtained in l-dodecanol, but separation of pitch from the dispersant was facilitated by the greater volatility of l-undecanol.

  5. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-12-31T23:59:59.000Z

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  6. STERN 978-0-12-370875-5 00005 Sulfur: From Acquisition

    E-Print Network [OSTI]

    159 STERN 978-0-12-370875-5 00005 Sulfur: From Acquisition to Assimilation David Gonzalez 5 INTRODUCTION Sulfur (S) is an essential element present in proteins, lipids, and important productivity s0010s0010 p0010p0010 CHAPTER CONTENTS Introduction 159 I. SO4 2 Acquisition and assimilation 160

  7. Modeling of Water-rock interaction in the Mackenzie Basin: competition between sulfuric and carbonic acids

    E-Print Network [OSTI]

    sulfuric and carbonic acids E. Beaulieu, Y. Godd´eris, D. Labat, C. Roelandt, D. Calmels, J. Gail- lardet of the resulting proof before it is published in its final form. Please note that during the production process in the Mackenzie Basin: competition between sulfuric and carbonic acids. E. Beaulieu1 , Y. Goddéris1 , D. Labat1

  8. The impact of dilute sulfuric acid on the selectivity of xylooligomer depolymerization to monomers

    E-Print Network [OSTI]

    California at Riverside, University of

    The impact of dilute sulfuric acid on the selectivity of xylooligomer depolymerization to monomers of polymerization (DP) ranging from 2 to 5 was followed at 160 °C with sulfuric acid added to adjust the pH from acid is low in cost itself, the over- all process is still quite expensive due to the combined costs

  9. Activation of Sulfur-and Nitrogen-Containing Heterocycles by a Dinuclear Iridium Complex

    E-Print Network [OSTI]

    Jones, William D.

    in Scheme 1, which show the sulfur and nitrogen atoms being removed as H2S and NH3. Because of new structurally characterized. Introduction The removal of heteroatom impurities is an essential component pressures of hydrogen (150-2250 psi) over a hot heterogeneous catalyst (320-440 °C) to remove sulfur

  10. Surface Science 415 (1998) 2936 Structural studies of sulfur-passivated GaAs (100)

    E-Print Network [OSTI]

    Zhang, Yanchao

    1998-01-01T23:59:59.000Z

    . Keywords: Atomic force microscopy; Gallium arsenide; Low-energy electron diffraction; Roughness; SulfurSurface Science 415 (1998) 29­36 Structural studies of sulfur-passivated GaAs (100) surfaces Abstract We present the results of Auger electron spectroscopy (AES), low-energy electron diffraction (LEED

  11. Understanding the Role of Different Conductive Polymers in Improving the Nanostructured Sulfur Cathode Performance

    E-Print Network [OSTI]

    Cui, Yi

    structural configurations of conductive polymer-sulfur composites employed in previous studies. In this workUnderstanding the Role of Different Conductive Polymers in Improving the Nanostructured Sulfur for the confinement of lithium polysulfides. However, the roles of different conductive polymers

  12. Sulfur accumulation and atmospherically deposited sulfate in the Lake states. Forest Service research paper

    SciTech Connect (OSTI)

    David, M.B.; Gertner, G.Z.; Grigal, D.F.; Ohmann, L.F.

    1989-01-01T23:59:59.000Z

    This report characterizes the mass of soil sulfur (adjusted for nitrogen), and atmospherically deposited sulfate along an acid-precipitation gradient from Minnesota to Michigan. The relationship of these variables, presented graphically through contour mapping, suggests that patterns of atmospheric wet sulfate deposition are reflected in soil-sulfur pools.

  13. Effect of Environmental Factors on Sulfur Gas Emissions from Problem Drywall

    E-Print Network [OSTI]

    Effect of Environmental Factors on Sulfur Gas Emissions from Problem Drywall Randy Maddalena on Sulfur Gas Emissions from Problem Drywall Randy Maddalena Indoor Environment Department Environmental humidity (RH) and with an area-specific ventilation rate of ~1.5 cubic meters per square meter of emitting

  14. Equilibrium Segregation of Sulfur to the Free Surface of Single Crystalline Titanium

    E-Print Network [OSTI]

    Zexian, Cao

    1 Equilibrium Segregation of Sulfur to the Free Surface of Single Crystalline Titanium Z crystalline titanium from 560°C to 800°C was investigated using Auger electron spectroscopy (AES) measurements decaying distribution of sulfur beneath the titanium surface at equilibrium was revealed by sputter depth

  15. In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries Johanna Information ABSTRACT: Rechargeable lithium-sulfur (Li-S) batteries hold great potential for high of these batteries for commercial use. The two primary obstacles are the solubility of long chain lithium

  16. Molecular and atomic emission during single-bubble cavitation in concentrated sulfuric acid

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    Molecular and atomic emission during single- bubble cavitation in concentrated sulfuric acid David during cavitation. Single-bubble sonoluminescence (SBSL) from sulfuric acid (H2SO4) is much brighter than occurring during single- bubble cavitation. In fact, SBSL spectra from organic liquids8,9 have been

  17. Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    than the conventional lithium ion batteries based on metal oxide cathodes and graphite anodes Sulfur Batteries Guangyuan Zheng, Qianfan Zhang, Judy J. Cha, Yuan Yang, Weiyang Li, Zhi Wei Seh, and Yi lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent

  18. Assessing historical global sulfur emission patterns for the period 1850--1990

    SciTech Connect (OSTI)

    Lefohn, A.S. [A.S.L. and Associates, Helena, MT (United States); Husar, J.D.; Husar, R.B. [Washington Univ., St. Louis, MO (United States). Center for Air Pollution Impact and Trend Analysis; Brimblecombe, P. [Univ. of East Anglia, Norwich (United Kingdom)

    1996-07-19T23:59:59.000Z

    Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

  19. Fractionation of sulfur isotopes by Desulfovibrio vulgaris mutants lacking hydrogenases or type I tetraheme cytochrome c[subscript 3

    E-Print Network [OSTI]

    Sim, Min Sub

    The sulfur isotope effect produced by sulfate reducing microbes is commonly used to trace biogeochemical cycles of sulfur and carbon in aquatic and sedimentary environments. To test the contribution of intracellular coupling ...

  20. Stable isotope geochemistry of sulfur bearing minerals and clay mineralogy of some soils and sediments in Loot Desert, central Iran

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Stable isotope geochemistry of sulfur bearing minerals and clay mineralogy of some soils Keywords: Sulfur geochemistry Gypsum crystallization water Clay mineralogy Palygorskite Iranian soils Loot technique and clay mineralogy were studied in different landforms in Loot Desert, central Iran. Four

  1. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, December 1, 1994--February 28, 1995

    SciTech Connect (OSTI)

    Knight, R.A.

    1996-03-01T23:59:59.000Z

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In previous ICCI projects at IGT, flash thermocracking (FTC) was used to successfully upgrade the properties of mild gasification pitch, yielding a suitable blending stock for use as a binder in the production of carbon electrodes for the aluminum industry. However, in pitches from high-sulfur (4%) Illinois coal, the pitch sulfur content is still unacceptably high at 2%. In this project, two approaches to sulfur reduction are being explored in conjunction with FTC: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to FTC. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous IGTS8 biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous FTC reactor constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches.

  2. Investigation of the sulfur and lithium to sulfur ratio threshold in stress corrosion cracking of sensitized alloy 600 in borated thiosulfate solution

    SciTech Connect (OSTI)

    Bandy, R.; Kelly, K.

    1984-07-01T23:59:59.000Z

    The stress corrosion cracking of sensitized Alloy 600 was investigated in aerated solutions of sodium thiosulfate generally containing 1.3% boric acid. The aim of the investigation, among others, was to determine the existence, if any, of a threshold level of sulfur, and lithium to sulfur ratio governing the SCC. Specimens were first solution annealed at 1135/sup 0/C for 45 minutes, water quenched, and then sensitized at 621/sup 0/C for 18 hours. Reverse U-bends were tested at room temperature, whereas slow strain rate and constant load tests were performed at 80/sup 0/C. All tests were performed in solutions open to the atmosphere. The results indicate that in the borated thiosulfate solution containing 7 ppM sulfur, 5 ppM lithium as lithium hydroxide is sufficient to inhibit SCC in U-bends. The occurrence of inhibition seems to correlate to the rapid increase of pH and conductivity of the solution as a result of the lithium hydroxide addition. In the slow strain rate tests in the borated solution containing 0.7 ppM lithium as lithium hydroxide, significant stress corrosion cracking is observed at a sulfur level of 30 ppb, i.e., a lithium to sulfur ratio of 23. In a parallel test in 30 ppb sulfur level but without any lithium hydroxide, the stress corrosion cracking is more severe than that in the lithiated environment, thus implying that lithium hydroxide plays some role in the stress corrosion cracking inhibition.

  3. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect (OSTI)

    Chou, M.I.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States)

    1993-09-01T23:59:59.000Z

    The purposes of this project are: to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE process developed by the Midwest Ore Processing Co. (MWOPC), to verify the forms-of-sulfur determination using the ASTM method for evaluation of the PCE process, and to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal. The objectives for the second year are: to verify the possible effects of PCE treatment on coal-derived FeS{sub 2}, FeSO{sub 4}, and Fe{sub 2}(SO{sub 4}){sub 3} on ASTM coal analysis, to investigate the behavior of sulfur during oxidation and PCE desulfurization using the isotopically signatured coal sample, to investigate the effects of conditions and/or reagents on the oxidation of the organic-sulfur-model compounds, to evaluate the extended oxidation condition on the organic sulfur removal by PCE desulfurization, and to study other innovative pretreatment processes for the removal of organic sulfur from coal under mild conditions.

  4. Comparative analysis of polycyclic aromatic sulfur heterocycles isolated from four shale oils. [Polycyclic aromatic sulfur heterocycles; thiophenes

    SciTech Connect (OSTI)

    Willey, C.; Pelroy, R.; Stewart, D.

    1981-12-01T23:59:59.000Z

    This report describes the isolation of sulfur heterocycle fractions from four shale oils (Paraho, Geokinetics, Occidental, and Rio Blanco), the use of capillary column gas chromatography and mass spectrometry for the identification of individual mixture components, and a reverse (Ames) and forward mutation assay with Salmonella typhimurium to screen for possible health hazards. The major components of the Polycyclic Aromatic Sulfur Heterocycles (PASH) fractions for all four shale oils were found to be two- to three-ringed parent and alkylated thiophene compounds. In all cases the PASH fractions showed no more specific mutagenic response than the neutral PAC fractions from which they were isolated. The only mutagenic response which was detected in the PASH fractions was for the Rio Blanco shale oil and showed specific mutagenic response similar to the neutral PAC fraction from which it was isolated. Finally, the forward mutation 8-azaguanine test was apparently more sensitive than the Ames histidine reversion test in detecting mutagenic activity for the chemical fractions from the shale oils.

  5. Petrography and chemistry of sized fly ash from low-sulfur and high-sulfur coal sources

    SciTech Connect (OSTI)

    Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Trimble, A.S. [Franklin County High School, Frankfort, KY (United States); Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Palmer, C. [Geological Survey, Reston, VA (United States)

    1996-12-31T23:59:59.000Z

    Fly ash samples were collected in November and December, 1994, from two units representing high- and low-sulfur feed coals at a Kentucky power station. The ashes were wet screened at 100, 200, 325, and 500 mesh. The dried ({approximately}40 C) fractions were then weighed, split for petrographic and chemical analysis, mounted in epoxy and prepared as polished pellets, and analyzed for ash yield and carbon content. The November ashes had a similar size distribution in the +325 mesh fractions. The low-sulfur hot side and cool side ashes had a similar size distribution in the November ashes. In contrast, the December fly ashes showed the typical trend, the cool-side ash being finer (over 20% more ash in the {minus}500 mesh fraction) than the hot-side ash. Carbon tends to be relatively concentrated in the coarse fractions. The dominance of the {minus}325 mesh fractions in the overall size analysis implies, though, that carbon in the fine sizes is an important consideration in the utilization potential of the fly ash.

  6. Sampling, preservation, and analytical methods research plan - liquid redox sulfur recovery technologies: Stretford process. Topical report

    SciTech Connect (OSTI)

    Trofe, T.W.

    1986-11-01T23:59:59.000Z

    GRI has developed a sampling, preservation, and analytical (SPandA) methods research plan for developing and validating analytical methodologies for liquid redox sulfur recovery processes (e.g., Stretford process). The document describes the technical approach which will be used to direct research activities to develop SPandA methodologies to analyze gaseous, aqueous, and solid process streams from the Stretford sulfur recovery process. The primary emphasis is on developing and validating methodologies for analyzing vanadium (IV) and vanadium (V), anthraquinone disulphonic acids (ADA), polysulfide-sulfur, sulfide-sulfur, thiosulfate, sulfate, thiocyanate, total soluble sulfur, alkalinity, pH, total dissolved solids, total suspended solids, and dissolved oxygen in aqueous process streams. The document includes descriptions of the process streams and chemical species, selection of candidate analytical methods, and technical approach for methods development and validation.

  7. Weighted Guidelines | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2, 2015Visiting Strong, Smart,Department of EnergyEnergyWeighted

  8. Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon and Heather C. Allen*

    E-Print Network [OSTI]

    Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon 43210 ReceiVed: May 27, 2004; In Final Form: August 19, 2004 The reaction between methanol and sulfuric peak in the 800 cm-1 region, not present in either the neat methanol or concentrated sulfuric acid

  9. Population, Economy and Energy Use’s Influence on Sulfur Emissions in the United States Since 1900

    E-Print Network [OSTI]

    Kissock, J. K.; Husar, R. B.

    and the transition from coal to less sulfur intensive fuels have reduced sulfur emissions. The net effect of all drivers has been moderate growth in sulfur emissions from 1900 to present. Since 1973, increased energy efficiency and the shift from an industrial to a...

  10. ALTERNATIVE FLOWSHEETS FOR THE SULFUR-IODINE THERMOCHEMICAL HYDROGEN CYCLE

    SciTech Connect (OSTI)

    BROWN,LC; LENTSCH,RD; BESENBRUCH,GE; SCHULTZ,KR; FUNK,JE

    2003-02-01T23:59:59.000Z

    OAK-B135 A hydrogen economy will need significant new sources of hydrogen. Unless large-scale carbon sequestration can be economically implemented, use of hydrogen reduces greenhouse gases only if the hydrogen is produced with non-fossil energy sources. Nuclear energy is one of the limited options available. One of the promising approaches to produce large quantities of hydrogen from nuclear energy efficiently is the Sulfur-Iodine (S-I) thermochemical water-splitting cycle, driven by high temperature heat from a helium Gas-Cooled Reactor. They have completed a study of nuclear-driven thermochemical water-splitting processes. The final task of this study was the development of a flowsheet for a prototype S-I production plant. An important element of this effort was the evaluation of alternative flowsheets and selection of the reference design.

  11. Sulfur-Iodine Integrated Lab Scale Experiment Development

    SciTech Connect (OSTI)

    Russ, Ben

    2011-05-27T23:59:59.000Z

    The sulfur-iodine (SI) cycle was deermined to be the best cycle for coupling to a high temperature reactor (HTR) because of its high efficiency and potential for further improvement. The Japanese Atomic Energy Agency (JAEA) has also selected the SI process for further development and has successfully completed bench-scale demonstrations of the SI process at atmospheric pressure. JEA also plans to proceed with pilot-scale demonstrations of the SI process and eventually plans to couple an SI demonstration plant to its High Temperature Test Reactor (HHTR). As part of an international NERI project, GA, SNL, and the Frech Commissariat L'Energie Atomique performed laboratory-scale demonstrations of the SI process at prototypical temperatures and pressures. This demonstration was performed at GA in San Diego, CA and concluded in April 2009.

  12. Phosphate Glasses for Vitrification of Waste with High Sulfur Content

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.; Hrma, Pavel R.; Cassingham, Nathan J.

    2002-10-31T23:59:59.000Z

    The low solubility of sulfate in silicate-based glasses, approximately 1 mass% as SO3, limits the loading of high-level waste (HLW) and low-activity waste (LAW) containing high concentrations of sulfur. Based on crucible melting studies, we have shown that the phosphate glasses may incorporate more than 5 mass% SO3; hence, the waste loading can be increased until another constraint is met, such as glass durability. A high-sulfate HLW glass has been formulated and tested to demonstrate the advantages of phosphate glasses. The effect of waste loading on the chemical durability of quenched and slow-cooled phosphate glasses was determined using the Product Consistency Test.

  13. Energy Aware Scheduling for Weighted Completion Time and Weighted Tardiness

    E-Print Network [OSTI]

    Carrasco, Rodrigo A; Stein, Cliff

    2011-01-01T23:59:59.000Z

    The ever increasing adoption of mobile devices with limited energy storage capacity, on the one hand, and more awareness of the environmental impact of massive data centres and server pools, on the other hand, have both led to an increased interest in energy management algorithms. The main contribution of this paper is to present several new constant factor approximation algorithms for energy aware scheduling problems where the objective is to minimize weighted completion time plus the cost of the energy consumed, in the one machine non-preemptive setting, while allowing release dates and deadlines.Unlike previous known algorithms these new algorithms can handle general job-dependent energy cost functions, extending the application of these algorithms to settings outside the typical CPU-energy one. These new settings include problems where in addition, or instead, of energy costs we also have maintenance costs, wear and tear, replacement costs, etc., which in general depend on the speed at which the machine r...

  14. Ultra-low Sulfur Reduction Emission Control Device/Development of an On-board Fuel Sulfur Trap

    SciTech Connect (OSTI)

    Rohrbach, Ron; Barron, Ann

    2008-07-31T23:59:59.000Z

    Honeywell has completed working on a multiyear program to develop and demonstrate proof-of-concept for an 'on-vehicle' desulfurization fuel filter for both light duty and heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NOx adsorbers. The NOx adsorber may be required to meet the proposed new EPA Tier II and '2007-Rule' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters was also examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. In the second phase of the program a light duty diesel engine test was also demonstrated. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consisted of four phases. Phase I focused on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II concentrated on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III studied life cycle and regeneration options for the spent filter. Phase IV focused on efficacy and benefits in the desulfation steps of a NOx adsorber on both a heavy and light duty engine. The project team included a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Navistar Inc. (formerly International Truck & Engine Corporation) and Mack Trucks Inc.), and filter recycler (American Wastes Industries).

  15. Weighted Marshall-Olkin Bivariate Exponential Distribution

    E-Print Network [OSTI]

    Kundu, Debasis

    Weighted Marshall-Olkin Bivariate Exponential Distribution Ahad Jamalizadeh§ & Debasis Kundu of weighted Marshall-Olkin bivariate exponential distribu- tions. This new singular distribution has of this paper is to introduce a weighted Marshall-Olkin bivariate exponential (WMOBE) distribution, using

  16. Tribological behavior of near-frictionless carbon coatings in high- and low-sulfur diesel fuels.

    SciTech Connect (OSTI)

    Alzoubi, M. F.; Ajayi, O. O.; Eryilmaz, O. L.; Ozturk, O.; Erdemir, A.; Fenske, G.

    2000-01-19T23:59:59.000Z

    The sulfur content in diesel fuel has a significant effect on diesel engine emissions, which are currently subject to environmental regulations. It has been observed that engine particulate and gaseous emissions are directly proportional to fuel sulfur content. With the introduction of low-sulfur fuels, significant reductions in emissions are expected. The process of sulfur reduction in petroleum-based diesel fuels also reduces the lubricity of the fuel, resulting in premature failure of fuel injectors. Thus, another means of preventing injector failures is needed for engines operating with low-sulfur diesel fuels. In this study, the authors evaluated a near-frictionless carbon (NFC) coating (developed at Argonne National Laboratory) as a possible solution to the problems associated with fuel injector failures in low-lubricity fuels. Tribological tests were conducted with NFC-coated and uncoated H13 and 52100 steels lubricated with high- and low- sulfur diesel fuels in a high-frequency reciprocating test machine. The test results showed that the NFC coatings reduced wear rates by a factor of 10 over those of uncoated steel surfaces. In low-sulfur diesel fuel, the reduction in wear rate was even greater (i.e., by a factor of 12 compared to that of uncoated test pairs), indicating that the NFC coating holds promise as a potential solution to wear problems associated with the use of low-lubricity diesel fuels.

  17. Geologic controls on sulfur content of the Blue Gem coal seam, southeastern Kentucky

    SciTech Connect (OSTI)

    Rimmer, S.M.; Moore, T.A.; Esterle, J.S.; Hower, J.C.

    1985-01-01T23:59:59.000Z

    Detailed petrographic and lithologic data on the Blue Gem coal seam for a local area in Knox County, Kentucky, suggest that a relationship may exist between overlying roof lithology, petrographic composition of the coal, and sulfur content. In the western part of the area, where thick (20-40 feet) shale sequences overlie the coal, sulfur contents are low (less than 1%). In isolated areas where discontinuous sandstones occur within 6 feet of the coal, sulfur contents range from 1% to over 3%. In the east, a sandstone body usually overlies and frequently scours out the coal, yet sulfur content varies independently of roof lithology. Towards the east, there is an increase in abundance, thickness and variability of fusain bands within the coal and an increase in pyrite and siderite either as cell fillings in fusinite or as masses within vitrinite; early emplacement of these minerals is indicated by compaction features. Data suggest the importance of depositional environment of the peat and overlying sediments as a control on sulfur occurrence. High sulfur contents in the west are related to sandstone bodies which may have allowed sulfate-bearing waters to permeate into the peat. In the east, where increases in pyrite, siderite and fusain content of the coal and coarsening of the overlying sediments suggest a change in environment, the presence or absence of pyrite-containing fusain bands may account for sulfur variability. Siderite occurrence may reflect local fluctuations in sulfate supply to the peat swamp.

  18. Is Dark Energy Abnormally Weighting?

    E-Print Network [OSTI]

    A. Fuzfa; J. -M. Alimi

    2006-09-05T23:59:59.000Z

    We present a new interpretation of dark energy in terms of an \\textit{Abnormally Weighting Energy} (AWE). This means that dark energy does not couple to gravitation in the same way as ordinary matter, yielding a violation of the weak and strong equivalence principles on cosmological scales. The resulting cosmological mechanism accounts for the Hubble diagram of type Ia supernovae in terms of both cosmic acceleration and variation of the gravitational constant while still accounting for the present tests of general relativity. This explanation allows to build dark energy models (i) without violation of the strong energy condition $p<-\\rho c^2/3$ (ii) with non-negligible direct couplings to gravitation and (iii) natural convergence mechanism toward general relativity.

  19. The vibrational and rotational structure of the 2400 to 1950 A? absorption spectrum of sulfur dioxide

    E-Print Network [OSTI]

    Riggs, James Willborn

    1958-01-01T23:59:59.000Z

    -l ap pi ng Or de rs 26 Ex te rn al Op ti cs As so ci at ed wi th Ab so rp ti on Tu be 27 28 Sulfur Dioxide Gas System.-The sulfur dioxide gas system associated with the absorption tube is pictured in Figure 3... fulfillment of' %hm r*tuir??Mi*s f?r %ift ??' m m m m m m & m s t Major Sttfejoott Rupeio* THE VIBRATIONAL AND ROTATIONAL STRUCTURE OP THE 2400 TO 1950 A ABSORPTION SPECTRUM OP SULFUR DIOXIDE A Dissertation 37 James Willborn Riggs, Jr. Approved...

  20. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

    1984-01-01T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  1. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

    1987-03-10T23:59:59.000Z

    This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

  2. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  3. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, Ragnar P. (Birmingham, MI); Winterbottom, Walter L. (Farmington Hills, MI); Wroblowa, Halina S. (West Bloomfield, MI)

    1987-01-01T23:59:59.000Z

    This specification is directed to a method of making a current collector (14) for a sodium/sulfur battery (10). The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material (16) formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500-1000 angstroms.

  4. Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

  5. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  6. World copper smelter sulfur balance, 1988. (Information circular, 1993). Information circular/1993

    SciTech Connect (OSTI)

    Towle, S.W.

    1993-01-01T23:59:59.000Z

    In 1989, the US Bureau of Mines initiated a contract to gather engineering, operating, and environmental cost data for 1988 for 30 major foreign primary copper smelters in market economy countries. Data were collected for 29 of the designated smelters together with information on applicable environmental regulations. Materials balance data obtained were used with available data for the eight US smelters to determine the approximate extent of copper smelter sulfur emission control in 1988. A broad characterization of the status of sulfur emission control regulation was made. Significant changes since 1988 that may increase sulfur emission control are noted.

  7. Influences of clouds and rain on the large-scale transport and deposition of sulfur

    SciTech Connect (OSTI)

    Luecken, D.J.; Berkowitz, C.M.; Easter, R.C.

    1991-07-01T23:59:59.000Z

    This paper describes the application of a three-dimensional, global-scale Eulerian model with an explicit description of cloud and chemical processes. Simulation results describing the transport of sulfur from North America and Europe across the north Atlantic Ocean during a climatological July are presented. Wet deposition was found to contribute slightly more to total sulfur deposition than dry deposition, a feature explained by the large amounts of precipitation during this month. The wet deposition patterns did not always correspond to the emissions patterns. The precipitation rate and spatial distribution had a large effect on the calculated concentrations of soluble sulfur species. 10 refs., 7 figs., 1 tab.

  8. Influence of fuel sulfur on the selective reduction of NO by NH/sub 3/

    SciTech Connect (OSTI)

    Lucas, D.; Brown, N.J.

    1981-10-01T23:59:59.000Z

    The selective reduction of NO by NH/sub 3/ addition has been studied in a lean-burning oil fired laboratory combustion tunnel with pyridine and thiophene added to the fuel oil. Two distinct, but interrelated effects were observed. The conversion of a fixed amount of fuel nitrogen to NO in the flame increased as the fuel sulfur concentration increased. In the post-combustion gases, there was a shift in the temperature dependence of the reduction process when the sulfur combustion products were present. The extent of the NO reduction was not significantly altered, but the optimum temperature for reduction shifted to higher values as the sulfur concentration increased.

  9. Sulfur by-product formation in the Stretford process. Topical report

    SciTech Connect (OSTI)

    Trofe, T.W.; DeBerry, D.W.

    1993-09-01T23:59:59.000Z

    Liquid redox sulfur recovery processes remove H2S from sour gas streams and produce elemental sulfur for sale or disposal. The Stretford Process is one of the oldest commercial liquid redox processes and it is based on a vanadium and anthraquinone redox system. Improvements in the operability and reliability of the Stretford process would be beneficial to the process user. The report presents results of research focused on developing an understanding of the process parameters and factors that impact sulfur by-product formation (e.g., sodium thiosulfate and sodium sulfate) in the Stretford process. The information in the report can help current Stretford plant process users better understand the operations of their plants, especially with regards to sulfur by-product formation and control strategies.

  10. Did the Clean Air Act cause the remarkable decline in sulfur dioxide concentrations?

    E-Print Network [OSTI]

    Greenstone, Michael

    2003-01-01T23:59:59.000Z

    Over the last three decades, ambient concentrations of sulfur dioxide (SO2) air pollution have declined by approximately 80%. This paper tests whether the 1970 Clean Air Act and its subsequent amendments caused this decline. ...

  11. Explaining low sulfur dioxide allowance prices : the effect of expectation errors and irreversibility

    E-Print Network [OSTI]

    Montero, Juan-Pablo

    1998-01-01T23:59:59.000Z

    The low price of allowances has been a frequently noted featured of the implementation of the sulfur dioxide emissions market of the U.S. Acid Rain Program. This paper presents theoretical and numerical analyses that explain ...

  12. Effect of Sulfur and Hydrocarbon Fuels on Titanate/Ceria SOFC Anodes

    SciTech Connect (OSTI)

    Marina, O.A.; Pedersen, L.R.; Stevenson, J.W.

    2005-01-27T23:59:59.000Z

    The purpose of the project is to develop low-cost, high-performance anodes that offer low polarization resistance as well as improved tolerance for nonidealities in anode environment such as redox cycles, sulfur and other poisons, and hydrocarbons.

  13. Sulfur isotopes as indicators of amended bacterial sulfate reduction processes influencing field scale uranium bioremediation

    E-Print Network [OSTI]

    Druhan, J.L.

    2009-01-01T23:59:59.000Z

    results in enrichment of S, the heavier isotope of sulfur,isotope data from M-24 were observed, although the degree of enrichmentisotopes as indicators of in situ acetate amended sulfate and uranium bioreduction processes. Enrichment

  14. The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India

    E-Print Network [OSTI]

    Chatterjee, A.

    High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

  15. New method of regenerating spent vacuum-carbonate sulfur removal liquor

    SciTech Connect (OSTI)

    Popov, A.A.; Dovgopol, A.P.; Goncharova, Z.S.; Belitskii, A.N,.; Gorokhov, N.N.; Grigorash, A.S.; Yaroshenko, A.K.

    1980-01-01T23:59:59.000Z

    A three-stage method is proposed for processing the ballast salts in the wash liquor from vacuum-carbonate removal of sulfur from coke-oven gas. The method is based on successive treatment of the liquor with sulfur dioxide, hydrogen sulfide and 95% sulfuric acid in the presence of hydrogen sulfide. The products of the process are thiosulfate, sulfate and elemental sulfur, at yields of 99.8%, 99.5% and 99.7% respectively. These investigations of a waste-free vacuum-carbonate method of removing hydrogen sulfide from coke-oven gas convincingly show that it is possible in principle to efficiently utilize the spent liquors both as a feedstock and as an absorbent and to obtain commercial products as a result.

  16. Frataxin (FXN) Based Regulation of the Iron-Sulfur Cluster Assembly Complex

    E-Print Network [OSTI]

    Rabb, Jennifer

    2012-07-16T23:59:59.000Z

    Iron-sulfur clusters are protein cofactors that are critical for all life forms. Elaborate multi-component systems have evolved for the biosynthesis of these cofactors to protect organisms from the toxic effects of free iron and sulfide ions...

  17. E-Print Network 3.0 - aromatic sulfur compounds Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale Summary: . It has been also shown that most of the sulfur compounds in oil shale are...

  18. EVALUATION OF A SULFUR OXIDE CHEMICAL HEAT STORAGE PROCESS FOR A STEAM SOLAR ELECTRIC PLANT

    E-Print Network [OSTI]

    Dayan, J.

    2011-01-01T23:59:59.000Z

    central receiver of a solar plant, that absorbs heat duringper kW-hr produced by the solar plant and the sulfur-oxideis essential if solar power plants are ever to supply a

  19. Excellent Sulfur Resistance of Pt/BaO/CeO2 Lean NOx Trap Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and CHF Peden.2008."Excellent Sulfur Resistance of PtBaOCeO2 Lean NOx Trap Catalysts."Applied Catalysis. B, Environmental 84(3-4):545-551. doi:10.1016j.apcatb.2008.05.009...

  20. Cost-benefit analysis of ultra-low sulfur jet fuel

    E-Print Network [OSTI]

    Kuhn, Stephen (Stephen Richard)

    2010-01-01T23:59:59.000Z

    The growth of aviation has spurred increased study of its environmental impacts and the possible mitigation thereof. One emissions reduction option is the introduction of an Ultra Low Sulfur (ULS) jet fuel standard for ...

  1. Sulfur-rich carbon cryogels for supercapacitors with improved conductivity and wettability

    E-Print Network [OSTI]

    Cao, Guozhong

    Sulfur-rich carbon cryogels for supercapacitors with improved conductivity and wettability Yao Zhou electrolytes. 1 Introduction Supercapacitors have been extensively investigated for decades due as backup energy devices to batteries due to their higher power density. Generally, supercapacitors can

  2. Soft x-ray emission spectroscopy studies of the electronic structure of silicon supersaturated with sulfur

    E-Print Network [OSTI]

    Sullivan, Joseph Timothy

    We apply soft x-ray emission spectroscopy (XES) to measure the electronic structure of crystalline silicon supersaturated with sulfur (up to 0.7 at. %), a candidate intermediate-band solar cell material. Si L[subscript ...

  3. Effective hydrogen generation and resource circulation based on sulfur cycle system

    SciTech Connect (OSTI)

    Takahashi, Hideyuki; Mabuchi, Takashi; Hayashi, Tsugumi; Yokoyama, Shun; Tohji, Kazuyuki [Graduate School of Environmental Studies, Tohoku University 6-6-20, Aramaki, Aoba-ku, Sendai, 980-8579 (Japan)

    2013-12-10T23:59:59.000Z

    For the effective hydrogen generation from H{sub 2}S, it should be compatible that the increscent of the photocatalytic (or electrochemical) activities and the development of effective utilization method of by-products (poly sulfide ion). In this study, “system integration” to construct the sulfur cycle system, which is compatible with the increscent of the hydrogen and or electron energy generation ratio and resource circulation, is investigated. Photocatalytic hydrogen generation rate can be enhanced by using stratified photocatalysts. Photo excited electron can be transpired to electrode to convert the electron energy to hydrogen energy. Poly sulfide ion as the by-products can be transferred into elemental sulfur and/or industrial materials such as rubber. Moreover, elemental sulfur can be transferred into H{sub 2}S which is the original materials for hydrogen generation. By using this “system integration”, the sulfur cycle system for the new energy generation can be constructed.

  4. Application of gas chromatography with open tubular columns and chemiluminescent detection to the determination of sulfur-containing substances in oil pollutions of sea water

    SciTech Connect (OSTI)

    Savchuk, S.A.; Rudenko, B.A. [Vernadsky Inst. of Geochemical and Analytical Chemistry, Moscow (Russian Federation); Brodskii, E.S. [Severtzov Inst. of Evolution Morphology and Ecology of Animals, Moscow (Russian Federation)

    1995-11-01T23:59:59.000Z

    Sulfur in the free state and in the form of sulfur-containing organic substances, such as thiols, alkylsulfides, thiacycloalkanes, and thiophenes, are permanently present in oils and in the organic matter of bottom sediments. There are three classes of crude oils that are categorized by the sulfur concentration. Low-sulfur oils contain up to 0.5% of sulfur, sulfurous oils contain from 0.51 to 2%, and high-sulfur oils contain more than 2% of sulfur. The substances of thiophene series are considered to be the most stable sulfur compounds in oils. They are formed at the diagenesis stage via the aromatization of thiacycloalkanes during the thermal maturing of petroleum. Therefore, the determination of the composition of sulfur-containing aromatic substances is very important for studying oil-formation processes.

  5. Facile synthesis, spectral properties and formation mechanism of sulfur nanorods in PEG-200

    SciTech Connect (OSTI)

    Xie, Xin-yuan; Li, Li-yun; Zheng, Pu-sheng [Department of Chemistry, Jinan University, Guangzhou 510632 (China)] [Department of Chemistry, Jinan University, Guangzhou 510632 (China); Zheng, Wen-jie, E-mail: tzhwj@jnu.edu.cn [Department of Chemistry, Jinan University, Guangzhou 510632 (China)] [Department of Chemistry, Jinan University, Guangzhou 510632 (China); Bai, Yan; Cheng, Tian-feng; Liu, Jie [Department of Chemistry, Jinan University, Guangzhou 510632 (China)] [Department of Chemistry, Jinan University, Guangzhou 510632 (China)

    2012-11-15T23:59:59.000Z

    Graphical abstract: Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of about 6–8 was obtained. The sulfur nanoparticles could self-assemble from spherical particles to nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift which was due to the production of nanorods. Highlights: ? A novel, facile and greener method to synthesize sulfur nanorods by the solubilizing and templating effect of PEG-200 was reported. ? S{sup 0} nanoparticles could self assemble in PEG-200 and finally form monodisperse and homogeneous rod-like structure with an average diameter of about 80 nm, the length ca. 600 nm. ? The absorption band showed a red shift and the RRS intensity enhanced continuously during the self-assembling process. ? PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. -- Abstract: The synthesis of nano-sulfur sol by dissolving sublimed sulfur in a green solvent-PEG-200 was studied. Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of 6–8 was obtained. The structure, morphology, size, and stability of the products were investigated by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering (DLS) measurements. The spectral properties of the products were investigated by ultraviolet-visible (UV–vis) absorption and resonance Rayleigh scattering spectroscopy (RRS). The results showed that the spherical sulfur nanoparticles could self-assemble into nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift and the RRS intensity enhanced continuously. There was physical cross-linking between PEG and sulfur nanoparticles. PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. This research provides a greener and more environment-friendly synthetic method for the production of sulfur nanorods.

  6. Minimizing sulfur contamination and rinse water volume required following a sulfuric acid/hydrogen peroxide clean by performing a chemically basic rinse

    SciTech Connect (OSTI)

    Clews, P.J.; Nelson, G.C.; Resnick, P.J.; Matlock, C.A.; Adkins, C.L.J.

    1997-08-01T23:59:59.000Z

    Sulfuric acid hydrogen peroxide mixtures (SPM) are commonly used in the semiconductor industry to remove organic contaminants from wafer surfaces. This viscous solution is very difficult to rinse off wafer surfaces. Various rinsing conditions were tested and the resulting residual contamination on the wafer surface was measured. The addition of small amounts of a chemical base such as ammonium hydroxide to the rinse water has been found to be effective in reducing the surface concentration of sulfur and also mitigates the particle growth that occurs on SPM cleaned wafers. The volume of room temperature water required to rinse these wafers is also significantly reduced.

  7. Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2011-03-15T23:59:59.000Z

    Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

  8. Animal performance on small grain pastures with and without sulfur fertilizer

    E-Print Network [OSTI]

    Hardt, Paul Frederick

    1990-01-01T23:59:59.000Z

    prevalent in nature, S is present in the geosphere as sulfate. Sulfur may assume a number of oxidation states ranging from sulfide at -2 to sulfate at +6 and can therefore participate in many biological reactions. Sulfur is an essential mineral... for the synthesis of the amino acids methionine, cysteine and cystine (Tarver and Schmidt, 1939; Huovinen and Gustafsson, 1967), for maintaining the integrity of protein structure (Lehninger, 1982), is a component of mucopolysaccharides associated with structural...

  9. Development of Efficient Flowsheet and Transient Modeling for Nuclear Heat Coupled Sulfur Iodine Cyclefor Hydrogen Production

    SciTech Connect (OSTI)

    Shripad T. Revankar; Nicholas R. Brown; Cheikhou Kane; Seungmin Oh

    2010-05-01T23:59:59.000Z

    The realization of the hydrogen as an energy carrier for future power sources relies on a practical method of producing hydrogen in large scale with no emission of green house gases. Hydrogen is an energy carrier which can be produced by a thermochemical water splitting process. The Sulfur-Iodine (SI) process is an example of a water splitting method using iodine and sulfur as recycling agents.

  10. New ZnO-Based Regenerable Sulfur Sorbents for Fluid-Bed/Transport Reactor Applications

    SciTech Connect (OSTI)

    Slimane, R.B.; Lau, F.S.; Abbasian, J.; Ho, K.H.

    2002-09-19T23:59:59.000Z

    The overall objective of the ongoing sorbent development work at GTI is the advancement to the demonstration stage of a promising ZnO-TiO2 sulfur sorbent that has been developed under DCCA/ICCI and DOE/NETL sponsorship. This regenerable sorbent has been shown to possess an exceptional combination of excellent chemical reactivity, high effective capacity for sulfur absorption, high resistance to attrition, and regenerability at temperatures lower than required by typical zinc titanates.

  11. The solubility of elemental sulfur in methane, carbon dioxide and hydrogen sulfide gas

    E-Print Network [OSTI]

    Wieland, Denton R.

    1958-01-01T23:59:59.000Z

    ABSTRACT The object of the work reported In this dissertation was to determine the solubility of sulfur in gaseous methane carbon dioxide, and hydrogen sulfide and in mixtures of these gases, at various pressures and temperatures* Sulfur solubility... of methane and propane (which has a critical pressure of approximately the same value of hydrogen sulfide) is 1500 psia. To have liquid in this system at 1500 psia, however, would require a maximum temperature of 20?F which is well below the minimum...

  12. atomic weights table: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stability, atomic weights and molecular weights V. Paar, Bijeniccka 32, 10000 Zagreb, Croatia Accepted 15 January 2002 Abstract A power law is introduced weights. The power law...

  13. apparent molecular weight: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stability, atomic weights and molecular weights V. Paar, Bijeniccka 32, 10000 Zagreb, Croatia Accepted 15 January 2002 Abstract A power law is introduced weights. The power law...

  14. atomic weights tables: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stability, atomic weights and molecular weights V. Paar, Bijeniccka 32, 10000 Zagreb, Croatia Accepted 15 January 2002 Abstract A power law is introduced weights. The power law...

  15. assigning individual weights: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    understeer, and cornering shifts weight to the opposite side, unloading the inside tires. But why does weight shift during these maneuvers? How can weight shift when...

  16. Measurement of the diffusion coefficient of sulfur hexafluoride in water

    SciTech Connect (OSTI)

    King. D.B.; Saltzman, E.S. [Univ. of Miami, FL (United States)] [Univ. of Miami, FL (United States)

    1995-04-15T23:59:59.000Z

    Sulfur hexafluoride has been widely used in field studies and laboratory experiments to develop a relationship between gas transfer and wind speed. The interpretation of the data from such studies requires the diffusion coefficient of SF{sub 6} (D{sub SF6}), which has not previously been measured. In this study, D{sub SF6} has been determined in pure water and in 35%NaCl over a temperature range of 5-25{degrees}C. The measurements were made using a continuous-flow diffusion cell where SF{sub 6} flows beneath an agar gel membrane while helium flows above the gel. The experimental data for pure water yielded the following equation: D{sub SF6}=0.029 exp ({minus}19.3/RT, where R is the gas constant and T is temperature in kelvins). Measurements of D{sub SF6} in 35% NaCl were not significantly different from the pure water values. On the basis of this data, the authors estimate the Schmidt numbers for seawater over the temperature range 5-25{degrees}C to be Sc=3016.1{minus}172.00t+4.4996t{sup 2}{minus}0.047965t{sup 3}, where t is temperature in degrees Celsius. 31 refs., 3 figs., 2 tabs.

  17. Longitudinal study of children exposed to sulfur oxides

    SciTech Connect (OSTI)

    Dodge, R.; Solomon, P.; Moyers, J.; Hayes, C.

    1985-05-01T23:59:59.000Z

    This study is a longitudinal comparison of the health of children exposed to markedly different concentrations of sulfur dioxide and moderately different concentrations of particulate sulfate. The four groups of subjects lived in two areas of one smelter town and in two other towns, one of which was also a smelter town. In the area of highest pollution, children were intermittently exposed to high SO/sub 2/ levels (peak three-hour average concentration exceeded 2,500 micrograms/m3) and moderate particulate SO/sub 4/= levels (average concentration was 10.1 micrograms/m3). When the children were grouped by the four gradients of pollution observed, the prevalence of cough (measured by questionnaire) correlated significantly with pollution levels (trend chi-square = 5.6, p = 0.02). No significant differences in the incidence of cough or other symptoms occurred among the groups of subjects over three years, and pulmonary function and lung function growth over the study were roughly equal among all the groups. These results suggest that intermittent elevations in SO/sub 2/ concentration, in the presence of moderate particulate SO/sub 4/= concentration, produced evidence of bronchial irritation in the subjects, but no chronic effect on lung function or lung function growth was detected.

  18. Sulfur dioxide-induced chronic bronchitis in beagle dogs

    SciTech Connect (OSTI)

    Greene, S.A.; Wolff, R.K.; Hahn, F.F.; Henderson, R.F.; Mauderly, J.L.; Lundgren, D.L.

    1984-01-01T23:59:59.000Z

    This study was done to produce a model of chronic bronchitis. Twelve beagle dogs were exposed to 500 ppm sulfur dioxide (SO/sub 2/) for 2 h/d, 5d/wk for 21 wk and 4 dogs were sham-exposed to filtered ambient air for the same period. Exposure effects were evaluated by periodically examining the dogs using chest radiographs, pulmonary function, tracheal mucous clearance, and the cellular and soluble components of bronchopulmonary lavage fluids. Dogs were serially sacrificed after 13 and 21 wk of exposure and after 6 and 14 wk of recovery. Clinical signs produced in the SO/sub 2/-exposed dogs included mucoid nasal discharge, productive cough, moist rales on auscultation, tonsilitis, and conjunctivitis. Chest radiographs revealed mild peribronchiolar thickening. Histopathology, tracheal mucous clearance measurements, and lavage cytology were consistent with a diagnosis of chronic bronchitis. It is concluded that repeated exposure to 500 ppm SO/sub 2/ for 21 wk produced chronic bronchitis in the beagle dog. Complete recovery occurred within 5 wk following cessation of SO/sub 2/ exposure. 43 references, 2 figures, 2 tables.

  19. Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel

    SciTech Connect (OSTI)

    Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

    1996-02-01T23:59:59.000Z

    The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

  20. "EIA-914 Production Weighted Response Rates, Percent"

    U.S. Energy Information Administration (EIA) Indexed Site

    EIA-914 Production Weighted Response Rates, Percent" "Areas",38353,38384,38412,38443,38473,38504,38534,38565,38596,38626,38657,38687,38718,38749,38777,"application...

  1. Chapter 11Chapter 11 Estimating the Weighted

    E-Print Network [OSTI]

    Schubart, Christoph

    Chapter 11Chapter 11 Estimating the Weighted Average Cost of Capital DES Chapter 11 1 #12;U i th C.xls for shortfor short. DES Chapter 11 2 #12;S i l i hSteps to estimate value using the Corporate Valuation stockholders DES Chapter 11 7 #12;Estimating Target Weights Page 223: To calculate WACC, we need to estimate

  2. Semiring Artificial Neural Networks and Weighted Automata

    E-Print Network [OSTI]

    Hoelldobler, Steffen

    Semiring Artificial Neural Networks and Weighted Automata And an Application to Digital Image neural networks and weighted automata. For this task, we introduce semiring artificial neural networks, that is, artificial neural networks which implement the addition and the multiplication of semirings. We

  3. Observation of neutral sulfuric acid-amine containing clusters in laboratory and ambient measurements

    SciTech Connect (OSTI)

    Kuang C.; Zhao, J.; Smith, J. N.; Eisele, F. L.; Chen, M.; McMurry, P. H.

    2011-11-02T23:59:59.000Z

    Recent ab initio calculations showed that amines can enhance atmospheric sulfuric acid-water nucleation more effectively than ammonia, and this prediction has been substantiated in laboratory measurements. Laboratory studies have also shown that amines can effectively displace ammonia in several types of ammonium clusters. However, the roles of amines in cluster formation and growth at a microscopic molecular scale (from molecular sizes up to 2 nm) have not yet been well understood. Processes that must be understood include the incorporation of amines into sulfuric acid clusters and the formation of organic salts in freshly nucleated particles, which contributes significantly to particle growth rates. We report the first laboratory and ambient measurements of neutral sulfuric acid-amine clusters using the Cluster CIMS, a recently-developed mass spectrometer designed for measuring neutral clusters formed in the atmosphere during nucleation. An experimental technique, which we refer to as Semi-Ambient Signal Amplification (SASA), was employed. Sulfuric acid was added to ambient air, and the concentrations and composition of clusters in this mixture were analyzed by the Cluster CIMS. This experimental approach led to significantly higher cluster concentrations than are normally found in ambient air, thereby increasing signal-to-noise levels and allowing us to study reactions between gas phase species in ambient air and sulfuric acid containing clusters. Mass peaks corresponding to clusters containing four H{sub 2}SO{sub 4} molecules and one amine molecule were clearly observed, with the most abundant sulfuric acid-amine clusters being those containing a C2- or C4-amine (i.e. amines with masses of 45 and 73 amu). Evidence for C3- and C5-amines (i.e. amines with masses of 59 and 87 amu) was also found, but their correlation with sulfuric acid tetramer was not as strong as was observed for the C2- and C4-amines. The formation mechanisms for those sulfuric acid-amine clusters were investigated by varying the residence time in the inlet. It was concluded that the amines react directly with neutral clusters and that ion-induced clustering of sulfuric acid cluster ions with amines was not a dominant process. Results from ambient measurements using the Cluster CIMS without addition of sulfuric acid have shown that the sulfuric acid-amine clusters were reasonably well correlated with sulfuric acid tetramer and consistent with the SASA experiments at the same Boulder sampling site. Also, clusters that contain C2- or C4-amines were more abundant and better correlated with sulfuric acid tetramer than other types of amine containing clusters. However, ambient measurements of sulfuric acid-amine clusters remain difficult and highly uncertain because their concentrations are only slightly above background levels, even during nucleation events.

  4. Non-matrix corrected organic sulfur determination by energy dispersive X-ray spectroscopy for western Kentucky coals and residues

    SciTech Connect (OSTI)

    Clark, C.P.; Freeman, G.B.; Hower, J.C.

    1984-01-01T23:59:59.000Z

    A method for non-matrix corrected organic sulfur analysis by energy dispersive X-ray spectroscopy has been developed using petroleum coke standards. Typically, electron beam microanalysis is a rapid, nondestructive analytical technique to quantitatively measure organic sulfur in coal. The results show good correlation to ASTM values for numerous well characterized coals with a wide range in total and pyritic sulfur content. This direct analysis is capable of reducing error commonly associated with the present ASTM method which relies on an indirect measure of organic sulfur by difference. The precision of the organic sulfur values determined in the present study is comparable to that obtained by ZAF matrix corrected microanalysis. The energy dispersive microanalysis is capable of measuring micro as well as bulk organic sulfur levels.

  5. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    SciTech Connect (OSTI)

    Elmore, B.B.

    1993-08-01T23:59:59.000Z

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  6. The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992; Revision

    SciTech Connect (OSTI)

    Savage, R.L.; Lazarov, L.K.; Prudich, M.E.; Lange, C.A.; Kumar, N.

    1994-03-10T23:59:59.000Z

    The initial technical goal in the project was to develop a chemical method for the cost effective removal of both inorganic and organic sulfur from Ohio coals. Verifying and using a process of reacting ethanol vapors with coal under conditions disclosed in U.S. Patent 4,888,029, the immediate technical objectives were to convert a small scale laborative batch process to a larger scale continuous process which can serve as the basis for commercial development of the technology. This involved getting as much information as possible from small scale batch autoclave or fluid bed laboratory reactors for use in pilot plant studies. The laboratory data included material balances on the coal and sulfur, temperature and pressure ranges for the reaction, minimum reaction times at different conditions, the effectiveness of different activators such as oxygen and nitric oxide, the amount and nature of by-products such as sulfur dioxide, hydrogen sulfide and acetaldehyde, the effect of coal particle size on the speed and completeness of the reaction, and the effectiveness of the reaction on different Ohio coals. Because the laboratory experiments using the method disclosed in U.S. 4,888,029 were not successful, the objective for the project was changed to develop a new laboratory process to use ethanol to remove sulfur from coal. Using copper as a catalyst and as an H{sub 2}S scavenger, a new laboratory procedure to use ethanol to remove sulfur from coal has been developed at Ohio University and a patent application covering this process was filed in March, 1993. The process is based on the use of copper as a catalyst for the dehydrogenation of ethanol to produce nascent hydrogen to remove sulfur from the coal and the use of copper as a scavenger to capture the hydrogen sulfide formed from the sulfur removed from coal.

  7. Using Brain Weight to Predict Gestation in Mammals Bivariate Fit of Gestation By Brain Weight

    E-Print Network [OSTI]

    Carriquiry, Alicia

    1 Using Brain Weight to Predict Gestation in Mammals Bivariate Fit of Gestation By Brain Weight 0 100 200 300 400 500 Gestation 0 500 1000 1500 BrainWgt Linear Fit (All 50 mammals) Predicted Gestation = 85.248543 + 0.299867 Brain Weight Summary of Fit RSquare 0.372483 RSquare Adj 0.35941 Root Mean

  8. National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China

    E-Print Network [OSTI]

    Zhou, Nan

    2013-01-01T23:59:59.000Z

    and Price 2008). In addition, this scenario assumes that the share of biomassand Price 2008). Substitution of fossil fuels in cement kilns with low-sulfur biomass

  9. Nuclear Hydrogen Initiative, Results of the Phase II Testing of Sulfur-Iodine Integrated Lab Scale Experiments

    SciTech Connect (OSTI)

    Benjamin Russ; G. Naranjo; R. Moore; W. Sweet; M. Hele; N. Pons

    2009-10-30T23:59:59.000Z

    International collaborative effort to construct a laboratory-scale Sulfur-Iodine process capable of producing 100-200 L/hr of hydrogen.

  10. The effect of nitrogen supply and form on the absorption and assimilation of sulfur by the cotton plant

    E-Print Network [OSTI]

    Lane, Harry Cleburne

    1951-01-01T23:59:59.000Z

    of the first basic studies on the ef- fect of sulfur deficiency on the metabolism of the tomato by grosing the plants on a sul~ficient nutrient solution, He found in sulfur-de ficient plants a high level of carbohydrates and soluble organic nitrogen at all... elongation of the internodesX (c) high sulfbr plants were mare succulent than deficient sul- fur pXantsi (d) nitx'ates accumulated in deficient sulfur plants~ and (e) soluble orgazd. c nitrogenous fractions were higher in the sulfur de ficient plants...

  11. THE EFFECT OF ANOLYTE PRODUCT ACID CONCENTRATION ON HYBRID SULFUR CYCLE PERFORMANCE

    SciTech Connect (OSTI)

    Gorensek, M.; Summers, W.

    2010-03-24T23:59:59.000Z

    The Hybrid Sulfur (HyS) cycle (Fig. 1) is one of the simplest, all-fluids thermochemical cycles that has been devised for splitting water with a high-temperature nuclear or solar heat source. It was originally patented by Brecher and Wu in 1975 and extensively developed by Westinghouse in the late 1970s and early 1980s. As its name suggests, the only element used besides hydrogen and oxygen is sulfur, which is cycled between the +4 and +6 oxidation states. HyS comprises two steps. One is the thermochemical (>800 C) decomposition of sulfuric acid (H{sub 2}SO{sub 4}) to sulfur dioxide (SO{sub 2}), oxygen (O{sub 2}), and water. H{sub 2}SO{sub 4} = SO{sub 2} + 1/2 O{sub 2} + H{sub 2}O. The other is the SO{sub 2}-depolarized electrolysis of water to H{sub 2}SO{sub 4} and hydrogen (H{sub 2}), SO{sub 2} + 2 H{sub 2}O = H{sub 2}SO{sub 4} + H{sub 2}, E{sup o} = -0.156 V, explaining the 'hybrid' designation. These two steps taken together split water into H{sub 2} and O{sub 2} using heat and electricity. Researchers at the Savannah River National Laboratory (SRNL) and at the University of South Carolina (USC) have successfully demonstrated the use of proton exchange membrane (PEM) electrolyzers (Fig. 2) for the SO{sub 2}-depolarized electrolysis (sulfur oxidation) step, while Sandia National Laboratories (SNL) successfully demonstrated the high-temperature sulfuric acid decomposition (sulfur reduction) step using a bayonet-type reactor (Fig. 3). This latter work was performed as part of the Sulfur-Iodine (SI) cycle Integrated Laboratory Scale demonstration at General Atomics (GA). The combination of these two operations results in a simple process that will be more efficient and cost-effective for the massive production of hydrogen than alkaline electrolysis. Recent developments suggest that the use of PEMs other than Nafion will allow sulfuric acid to be produced at higher concentrations (>60 wt%), offering the possibility of net thermal efficiencies around 50% (HHV basis). The effect of operation at higher anolyte concentrations on the flowsheet, and on the net thermal efficiency for a nuclear-heated HyS process, is examined and quantified.

  12. Queer As a Three Pound Note #1

    E-Print Network [OSTI]

    Multiple Contributors

    1991-01-01T23:59:59.000Z

    of homosexuality by those after money or power or secret informa- tion.? He sat at his desk, sloughing jacket and loosening tie, slapping a new file on the desk top in front of himself, his voice never once paus- ing, but becoming sonorous, a minister deliver...

  13. WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,

    E-Print Network [OSTI]

    re-distills the solvent when dirty. The removed grit and sludge is mixed in with the waste oil Fuel oil and Turkey Based Biofuel Energy Rocovery 12,000 Industrial Waste $30,000 $500 $29,500 1500 gallons of #6 fuel oil and biofuels accepted from EENS as fuel stock for the Steam Facility Electronic

  14. WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,

    E-Print Network [OSTI]

    . Removed grit and sludge are mixed with the waste oil. Photon-counting spectrofluorimeter Substitution 54 or composted at the stump dump. Plant Engineering grounds vehicle wash system * Waste minimization 8,000 Oils and eliminates the potential of oil and grease being released to soil. Organic solvents Substitution 678

  15. WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,

    E-Print Network [OSTI]

    to the manufacturer . Replaced with energy efficient light emitting diode (LED) signs. Project reduced risk of tritium

  16. Queer As a Three Pound Note #1 

    E-Print Network [OSTI]

    Multiple Contributors

    1991-01-01T23:59:59.000Z

    -Type text/plain; charset=ISO-8859-1 ?AS A ?3 N O TE ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 Issue Number One in the BENT COPPERS Series A slash... upon or conflict with other holders of copyrights. No reprints of any type are permitted without express, written permission of the publisher and individual contributors involved. 2 ?3?3?3 ?3?3?3 ?As a ?3 Note?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3...

  17. Queer as 2 Three Pound Notes #2

    E-Print Network [OSTI]

    Multiple Contributors

    1991-01-01T23:59:59.000Z

    ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 TWO ?3 NOTES ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 Issue Number Two in the BENT COPPERS Series ?3?3?3...?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 ?AS ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3 ?3?3?3 ?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?3?AS TWO ?3 NOTES?3?3?3...

  18. Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin

    SciTech Connect (OSTI)

    Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

    2011-02-28T23:59:59.000Z

    Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

  19. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. (Institute of Gas Technology, Chicago, IL (United States)); Gidaspow, D.; Gupta, R.; Wasan, D.T. (Illinois Inst. of Tech., Chicago, IL (United States)); Pfister, R.M.: Krieger, E.J. (Ohio State Univ., Columbus, OH (United States))

    1992-05-01T23:59:59.000Z

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  20. Region-based Dynamic Weighting Probabilistic Geocoding

    E-Print Network [OSTI]

    Li, Zhongxia

    2014-07-30T23:59:59.000Z

    it extremely important that geocoding results be as accurate as possible. Existing global-weighting approaches to geocoding assume spatial stationarity of addressing systems and address data characteristic distributions across space, resulting in heuristics...

  1. A Library for Locally Weighted Projection Regression 

    E-Print Network [OSTI]

    Klanke, Stefan; Vijayakumar, Sethu; Schaal, Stefan

    2008-01-01T23:59:59.000Z

    In this paper we introduce an improved implementation of locally weighted projection regression (LWPR), a supervised learning algorithm that is capable of handling high-dimensional input data. As the key features, our ...

  2. Weight Perception Discrepancy Among Ethnically Diverse Youth

    E-Print Network [OSTI]

    Cromwell, Kate Duncan

    2012-10-19T23:59:59.000Z

    not feel they are, may be at risk for negative health conditions. Social Comparison Theory may provide a tool for evaluating identified discrepancies. Given that minorities have higher obesity rates, it is hypothesized that weight perception discrepancy...

  3. Method for removing sulfur compounds from C/sub 6/ and lower alkanes

    SciTech Connect (OSTI)

    Keyworth, D.A.

    1989-03-28T23:59:59.000Z

    A process is described for recovering a low sulfur content hydrocarbon fraction having a boiling point of n-hexane or less from a hydrocarbon stream containing hydrocarbons boiling at or below the boiling point of hexane and organic sulfur compounds comprising monosulfides boiling at or below the boiling point of n-hexane. It consists of contacting the hydrocarbon stream with a dilute aqueous solution of sodium hypochlorite for a time sufficient to convert a selected amount of monosulfide compounds present to compounds having boiling points above the boiling point of n-hexane, separating an aqueous phase and a hydrocarbon phase and fractionally distilling the hydrocarbon phase to recover a hydrocarbon fraction having a boiling point of n-hexane or less, and having a reduced amount of the organic sulfur compounds.

  4. The East Penn process for recycling sulfuric acid from lead-acid batteries

    SciTech Connect (OSTI)

    Leiby, R.; Bricker, M. [East Penn Manufacturing Co., Inc., Lyon Station, PA (United States); Spitz, R. [Spitz (R.), Holbrook, MA (United States)

    1995-12-31T23:59:59.000Z

    Prior to March 1992, the only component of the lead-acid battery that was not recycled by East Penn Manufacturing Company was the sulfuric acid electrolyte. This acid was unusable in new batteries because the iron level was found to exceed new product specifications. The development of a liquid ion exchange process to remove the iron from the acid allows East Penn to currently recover over three million gallons of sulfuric acid annually. The process is based upon the use of an iron selective liquid ion exchange material or solvent to extract iron from the sulfuric acid electrolyte followed by regeneration of the solvent. Equilibrium and kinetic data for the extraction and regeneration steps were collected in order to scale up the process to commercial scale. An electrochemical process for the treatment of the acid used in the regeneration step was also developed which significantly reduces the volume of strip acid required in the process.

  5. Configuring the thermochemical hydrogen sulfuric acid process step for the Tandem Mirror Reactor

    SciTech Connect (OSTI)

    Galloway, T.R.

    1981-05-01T23:59:59.000Z

    This paper identifies the sulfuric acid step as the critical part of the thermochemical cycle in dictating the thermal demands and temperature requirements of the heat source. The General Atomic Sulfur-Iodine Cycle is coupled to a Tandem Mirror. The sulfuric acid decomposition process step is focused on specifically since this step can use the high efficiency electrical power of the direct converter together with the other thermal-produced electricity to Joule-heat a non-catalytic SO/sub 3/ decomposer to approximately 1250/sup 0/K. This approach uses concepts originally suggested by Dick Werner and Oscar Krikorian. The blanket temperature can be lowered to about 900/sup 0/K, greatly alleviating materials problems, the level of technology required, safety problems, and costs. A moderate degree of heat has been integrated to keep the cycle efficiency around 48%, but the number of heat exchangers has been limited in order to keep hydrogen production costs within reasonable bounds.

  6. Electrochemical separation and concentration of sulfur containing gases from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

    1981-01-01T23:59:59.000Z

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  7. Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming

    SciTech Connect (OSTI)

    Gunther Dieckmann

    2006-06-30T23:59:59.000Z

    In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic reforming is that the level of sulfur found in low sulfur diesel can poison most catalysts. This report shows that a proprietary low cost Ni-based reforming catalyst can be used to reform a 7 and 50 ppm sulfur containing diesel fuel for over 500 hours of operation. Coking, which appears to be route of catalyst deactivation due to metal stripping, can be controlled by catalyst modifications, introduction of turbulence, and/or by application of an electromagnetic field with a frequency from {approx}50 kHz to 13.56 MHz with field strength greater than about 100 V/cm and more preferably greater about 500 V/cm.

  8. Sulfur dioxide emissions from primary nonferrous smelters in the Western United States

    SciTech Connect (OSTI)

    Mangeng, C.; Mead, R.

    1980-08-01T23:59:59.000Z

    The greatest source of sulfur dioxide emissions in the West has been the pyrometallurgical processing of copper, lead, and zinc ores. Until the early 1970s, the emissions from most nonferrous metal smelters were released without control into the environment. However, recent Federal and State legislation has mandated the need for large reductions of emissions, a task that will require the introduction of highly efficient sulfur dioxide control technology. The particular processes at each smelter, the smelter location, the capital and operating costs including the cost of energy, the resolution of currently litigated issues, and the metal market prices will be major influences on the choice of technology and on the schedule for implementation of smelter control plans. These parameters are examined, and the problems and issues associated with them are described. The future impact of smelter sulfur dioxide emissions is discussed within the framework of the relevant economic, technologial, and legal issues.

  9. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion

    SciTech Connect (OSTI)

    Chou, C.L.

    1991-01-01T23:59:59.000Z

    The purpose of this project is to conduct laboratory experiments to clarify the mechanism of boiler corrosion, which may lead to solving the corrosion problem associated with the utilization of Illinois' high-sulfur and high-chlorine coal. The kinetics of the release of sulfur and chlorine species during coal combustion is being determined in the laboratories using temperature-programmed pyrolysis coupled with quadrupole gas analysis (QGA) and thermogravimetric analysis in conjunction with Fourier transform infrared spectroscopy (FTIR). Samples of boiler deposits and ashes from different locations in boilers using Illinois coal will be analyzed for mineralogical and chemical compositions to understand the relations among deposit compositions, coal compositions, and the gaseous species in combustion gases. The relationship between the level of chlorine in Illinois coal and boiler corrosion will be studied by experiments with simulated combustion gases under combustion conditions. Reduction of sulfur and chloride concentrations in the flue gas using additives will also be evaluated.

  10. Bimodal Distribution of Sulfuric Acid Aerosols in the Upper Haze of Venus

    E-Print Network [OSTI]

    Gao, Peter; Crisp, David; Bardeen, Charles G; Yung, Yuk L

    2013-01-01T23:59:59.000Z

    The upper haze (UH) of Venus is variable on the order of days and it is populated by two particle modes. We use a 1D microphysics and vertical transport model based on the Community Aerosol and Radiation Model for Atmospheres to evaluate whether interaction of upwelled cloud particles and sulfuric acid particles nucleated in situ on meteoric dust are able to generate the two size modes and whether their observed variability are due to cloud top vertical transient winds. Nucleation of photochemically produced sulfuric acid onto polysulfur condensation nuclei generates mode 1 cloud droplets that then diffuse upwards into the UH. Droplets generated in the UH from nucleation of sulfuric acid onto meteoric dust coagulate with the upwelled cloud particles and cannot reproduce the observed bimodal size distribution. The mass transport enabled by cloud top transient winds are able to generate a bimodal size distribution in a time scale consistent with observations. Sedimentation and convection in the middle and lower...

  11. Sonic Enhanced Ash Agglomeration and Sulfur Capture. Technical progress report, July 1993--September 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    A major concern with the utilization of coal in directly fired gas turbines is the control of particulate emissions and reduction of sulfur dioxide, and alkali vapor from combustion of coal, upstream of the gas turbine. Much research and development has been sponsored on methods for particulate emissions control and the direct injection of calcium-based sorbents to reduce SO{sub 2} emission levels. The results of this research and development indicate that both acoustic agglomeration of particulates and direct injection of sorbents have the potential to become a significant emissions control strategy. The Sonic Enhanced Ash Agglomeration and Sulfur Capture program focuses upon the application of an MTCI proprietary invention (Patent No. 5,197,399) for simultaneously enhancing sulfur capture and particulate agglomeration of the combustor effluent. This application can be adapted as either a ``hot flue gas cleanup`` subsystem for the current concepts for combustor islands or as an alternative primary pulse combustor island in which slagging, sulfur capture, particulate agglomeration and control, and alkali gettering as well as NO{sub x} control processes become an integral part of the pulse combustion process. The goal of the program is to support the DOE mission in developing coal-fired combustion gas turbines. In particular, the MTCI proprietary process for bimodal ash agglomeration and simultaneous sulfur capture will be evaluated and developed. The technology embodiment of the invention provides for the use of standard grind, moderately beneficiated coal and WEM for firing the gas turbine with efficient sulfur capture and particulate emission control upstream of the turbine. The process also accommodates injection of alkali gettering material if necessary.

  12. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31T23:59:59.000Z

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  13. The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-04-15T23:59:59.000Z

    In developing the new Ohio University procedure the thermodynamic limitations of the reactions for removal of both pyritic and organic sulfur from coal at 400--600{degrees}C were studied using copper as a very strong H{sub 2}S-acceptor. Copper serves as a catalyst for ethanol dehydrogenation to form nascent hydrogen. Copper also serves as a scavenger to form copper sulfide from the hydrogen sulfide evolved during the reaction. Copper sulfide in turn serves as a catalyst for organic sulfur hydrodesulfurization reactions. If the coal to be desulfurized contains pyrite (FeS{sub 2}) or FeS, the copper scavenger effect reduces any back reaction of hydrogen sulfide with the iron and increases the removal of sulfur from the carbonaceous material. The desired effect of using copper can be achieved by using copper or copper containing alloys as materials of construction or as liners for a regenerable reactor. During the time period that Ohio Coal Development Office supported this work, small scale (560 grams) laboratory experiments with coals containing about 3.5% sulfur have achieved up to 90% desulfurization at temperatures of 500{degrees}C when using a copper reactor. Results from the autoclave experiments have identified the nature of the chemical reactions taking place. Because the process removes both pyritic and organic sulfur in coal, the successful scale up of the process would have important economic significance to the coal industry. Even though this and other chemical processes may be relatively expensive and far from being commercial, the reason for further development is that this process may hold the promise of achieving much greater sulfur reduction and of producing a cleaner coal than other methods. This would be especially important for small or older power plants and industrial boilers.

  14. Bioprocessing of High-sulfur Crudes Via Appliaction of Critical Fluid Biocatalysis

    SciTech Connect (OSTI)

    Ginosar, Daniel Michael; Bala, Greg Alan; Anderson, Raymond Paul; Fox, Sandra Lynn; Stanescue, Marina A.

    2002-05-01T23:59:59.000Z

    This experimental research project investigated protein-based biocatalysis in supercritical fluid solvents as an integrated process approach to catalyze the removal of sulfur atoms from crude oils and fuels. The work focused on the oxidation of model sulfur-containing compounds in supercritical reaction media and included three major tasks: microbiological induction experiments, proteincatalyzed biooxidation in supercritical solvents, and a work-in-kind cooperative research and development agreement (CRADA). This work demonstrated that the biooxidation reaction could be improved by an order-of-magnitude by carrying out the reaction in emulsions in supercritical fluids.

  15. Sulfur determination in blood from inhabitants of Brazil using neutron activation analysis

    SciTech Connect (OSTI)

    Oliveira, Laura C.; Zamboni, Cibele B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN-CNEN/SP) Av. Professor Lineu Prestes 2242 05508-000 Sao Paulo, SP (Brazil)

    2013-05-06T23:59:59.000Z

    In this study the NAA technique was applied to analyze sulfur in blood from inhabitants of Brazil for the proposition of an indicative interval. The measurements were performed considering lifestyle factors (non-smokers, non-drinkers and no history of toxicological exposure) of Brazilian inhabitants. The influence of gender was also investigated considering several age ranges (18-29, 30-39, 40-49, >50 years). These data are useful in clinical investigations, to identify or prevent diseases caused by inadequate sulfur ingestion and for nutritional evaluation of Brazilian population.

  16. Morbidity And Sulfur Dioxide: Evidence From French Strikes At Oil Refineries

    E-Print Network [OSTI]

    Matthew Neidell; Emmanuelle Lavaine

    2012-01-01T23:59:59.000Z

    This paper examines the impact of sulfur dioxide (SO2) in France on health outcomes at a census track level. To do so, we use recent strikes affecting oil refineries in France, in October 2010, as a natural experiment. Our work offers several contributions. We first show that a temporal shut down in the refining process leads to a reduction in sulfur dioxide concentration. We then use this narrow time frame exogenous shock to assess the impact of a change in air pollution concentration on respiratory outcomes. Our estimates suggest that daily variation in SO2 air pollution has economically significant health effects at levels below the current standard. 0

  17. Cathodic reduction of sulfur dioxide at porous, phthalocyanine-containing electrodes in nonaqueous electrolytes

    SciTech Connect (OSTI)

    Shembel', E.M.; Ksenzhek, O.S.; Danilova, N.P.; Shustov, V.A.

    1988-03-01T23:59:59.000Z

    Electrodes containing catalysts, particularly electrodes containing metal chelate compounds, were studied for their effect on reducing cathodic sulfur dioxide. The electrodes were prepared with an iron phthalocyanine polymer deposited onto activated carbon. Fluoropolymer dispersions was used as the binder and electrochemical studies were performed in a glove box under dry argon. Lithium perchlorate solution in propylene carbonate was used as the electrolyte solution. The results indicate that materials with high catalytic activity show promise in raising the discharge voltage in power sources of the lithium-sulfur dioxide system.

  18. Selective trace determination of sulfur and aluminum using charged particle activation analysis 

    E-Print Network [OSTI]

    Burton, Terrence Dale

    1974-01-01T23:59:59.000Z

    for the characterization of ultra-pure materials. In a previous study ( 26) we had analyzed crude oil samples for their sulfur content using the reaction 3 S(p, oc ) P. P is a positron emitter with a half- 29 29 life of 4. . 2 seconds. The 0. 511 MeV gamma... gammas which tended to overload the detector, a lead absorber ( 2" thick) was used. A focused beam of 20 MeV protons was used for irradiating a pure sulfur pellet at very low beam currents (1 nano ampere) and the prompt 2. 23 MeV gamma ray...

  19. NO[sub x] reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1992-09-15T23:59:59.000Z

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter. 7 figs.

  20. NOx reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1993-08-31T23:59:59.000Z

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  1. Preliminary analysis of patent trends for sodium/sulfur battery technology

    SciTech Connect (OSTI)

    Triplett, M.B.; Winter, C.; Ashton, W.B.

    1985-07-01T23:59:59.000Z

    This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.

  2. Monte Carlo Simulations of Small Sulfuric Acid-Water Clusters S. M. Kathmann,* and B. N. Hale,*

    E-Print Network [OSTI]

    Hale, Barbara N.

    -to-liquid nucleation1-5 to acid rain formation6-8 and ozone depletion mechanisms.9-11 Doyle's early work2 predictedMonte Carlo Simulations of Small Sulfuric Acid-Water Clusters S. M. Kathmann,* and B. N. Hale§,* En Form: August 7, 2001 Effective atom-atom potentials are developed for binary sulfuric acid

  3. Uptake and Surface Reaction of Methanol by Sulfuric Acid Solutions Investigated by Vibrational Sum Frequency Generation and Raman Spectroscopies

    E-Print Network [OSTI]

    Uptake and Surface Reaction of Methanol by Sulfuric Acid Solutions Investigated by Vibrational SumVised Manuscript ReceiVed: June 4, 2008 The uptake of methanol at the air-liquid interface of 0-96.5 wt % sulfuric methanol and H2SO4 to form methyl hydrogen sulfate. The surface is saturated with the methyl species after

  4. Metal-dependent Fermi-level movement in the metal/sulfur-passivated InGaP contact

    E-Print Network [OSTI]

    Kim, Sehun

    Metal-dependent Fermi-level movement in the metal/sulfur-passivated InGaP contact Y. K. Kim formed on S-passivated n-InGaP 100 surface reveals that the species produced by the chemical reaction. The initial sulfur passivation of n-InGaP 100 surface efficiently reduced the gap states within the band gap

  5. HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS

    SciTech Connect (OSTI)

    Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

    2009-05-12T23:59:59.000Z

    This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

  6. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 4: Diesel Particulate Filters -- Final Report

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    2000-01-15T23:59:59.000Z

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This is the fourth and final report for the DPF test program and covers the effect of diesel sulfur level on: a catalyzed diesel particulate filter (CDPF), and a continuously regenerating diesel particulate filter (CR-DPF).

  7. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect (OSTI)

    Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-08-25T23:59:59.000Z

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  8. A novel mechanism and kinetic model to explain enhanced xylose yields from dilute sulfuric acid compared to hydrothermal pretreatment of corn stover

    E-Print Network [OSTI]

    California at Riverside, University of

    A novel mechanism and kinetic model to explain enhanced xylose yields from dilute sulfuric acid stover Dilute sulfuric acid Hydrothermal pretreatment Kinetic model Xylose a b s t r a c t Pretreatment of corn stover in 0.5% sulfuric acid at 160 °C for 40 min realized a maximum monomeric plus oligomeric

  9. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 105, NO. Dl, PAGES 1387-1415, JANUARY 20,2000 Sulfur chelllistry in the National Center for

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    Understanding the tropospheric sulfur cycle is impor- tant because of its contribution to acid rain and its effect on the Earth's radiation balance. The role of sulfuric acid in acid rain has been recognizedJOURNAL OF GEOPHYSICAL RESEARCH, VOL. 105, NO. Dl, PAGES 1387-1415, JANUARY 20,2000 Sulfur

  10. New Model to Predict Formation Damage due to Sulfur Deposition in Sour M.A. Mahmoud and A.A. Al-Majed, KFUPM, all SPE

    E-Print Network [OSTI]

    Al-Majed, Abdulaziz Abdullah

    in the reservoir will help in better management of sour gas reservoirs with potential sulfur deposition problems as a dissolved species in virtually all deep sour gas reservoirs. Sulfur precipitation is induced by a reductionSPE 149535 New Model to Predict Formation Damage due to Sulfur Deposition in Sour Gas Wells M

  11. Far-infrared spectroelectrochemistry: a study of linear molybdenum/iron/sulfur clusters

    E-Print Network [OSTI]

    Reid, Scott A.

    Far-infrared spectroelectrochemistry: a study of linear molybdenum/iron/sulfur clusters Michael D Received 7 June 2003; accepted 29 November 2003 Abstract The far-infrared spectroelectrochemistry of linear identical electro- chemical properties, allows one to observe solute bands in the 450-cmÃ?1 region. The far-infrared

  12. Effects of sulfuric acid and nitrogen deposition on mineral nutrition of Picea abies (L.) Karst.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ecosystems, saplings have been sprayed with artificial acid rain, structured soil samples have been extractedEffects of sulfuric acid and nitrogen deposition on mineral nutrition of Picea abies (L.) Karst. B sites in the Fichtel- gebirge, and low fogwater pH (Trautner, 1989) of 2.2 indicate a high acid stress

  13. Sulfur Cycling in the Terrestrial Subsurface: Commensal Interactions, Spatial Scales, and Microbial Heterogeneity

    E-Print Network [OSTI]

    Grossman, Ethan L.

    Sulfur Cycling in the Terrestrial Subsurface: Commensal Interactions, Spatial Scales, and Microbial microbial processes in the terrestrial subsurface. Previous geochemical studies suggested that sulfide environment in shallow sediments (5 m), and produces acidic waters (pH 3.8) that are rich in sulfate (28 m

  14. Influence of transport and ocean ice extent on biogenic aerosol sulfur in the Arctic atmosphere

    E-Print Network [OSTI]

    Influence of transport and ocean ice extent on biogenic aerosol sulfur in the Arctic atmosphere S, such as methanesulfonic acid (MSA). This study examines relationships between changes in total sea ice extent north of 70. These results suggest that a decrease in seasonal ice cover influencing other mechanisms of DMS production could

  15. The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India*

    E-Print Network [OSTI]

    The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India* A.L. Ganesan Program on the Science and Policy of Global Change combines cutting-edge scientific research with independent policy analysis to provide a solid foundation for the public and private decisions needed

  16. Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

    DOE Patents [OSTI]

    Way, J. Douglas; Hatlevik, Oyvind

    2014-07-15T23:59:59.000Z

    The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.

  17. Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light

    E-Print Network [OSTI]

    Denver, University of

    ) or directly through adsorbed nitrogen and hydrogen atoms (11, 12). Ammonia emissions from tunnel studies have mea- surements than all other data combined. Sulfur compounds in gasoline combust in the engine to help facilitate the stringent 2007 diesel engine emission requirements. These reductions

  18. The influence of sulfur supplementation (methionine and sulfate) on the zinc availability

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    availability of a poor diet in sheep M Lamand, C Lab, M Mignon, JC Tressol INRA, Laboratoire des Maladies availability in lambs. Increasing the sulfur level with methionine and sulfate, of such a diet, enhances zinc absorption. However, sul- fur is not the only factor limiting zinc availability in a hypoproteic diet. zinc

  19. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents and methods of use thereof

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2006-06-27T23:59:59.000Z

    Reduced sulfur gas species (e.g., H.sub.2S, COS and CS.sub.2) are removed from a gas stream by compositions wherein a zinc titanate ingredient is associated with a metal oxide-aluminate phase material in the same particle species. Nonlimiting examples of metal oxides comprising the compositions include magnesium oxide, zinc oxide, calcium oxide, nickel oxide, etc.

  20. Co-firing high sulfur coal with refuse derived fuels. Final report

    SciTech Connect (OSTI)

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1997-11-30T23:59:59.000Z

    This project was designed to evaluate the combustion performance of and emissions from a fluidized bed combustor during the combustion of mixtures of high sulfur and/or high chlorine coals and municipal solid waste (MSW). The project included four major tasks, which were as follows: (1) Selection, acquisition, and characterization of raw materials for fuels and the determination of combustion profiles of combination fuels using thermal analytical techniques; (2) Studies of the mechanisms for the formation of chlorinated organics during the combustion of MSW using a tube furnace; (3) Investigation of the effect of sulfur species on the formation of chlorinated organics; and (4) Examination of the combustion performance of combination fuels in a laboratory scale fluidized bed combustor. Several kinds of coals and the major combustible components of the MSW, including PVC, newspaper, and cellulose were tested in this project. Coals with a wide range of sulfur and chlorine contents were used. TGA/MS/FTIR analyses were performed on the raw materials and their blends. The possible mechanism for the formation of chlorinated organics during combustion was investigated by conducting a series of experiments in a tube furnace. The effect of sulfur dioxide on the formation of molecular chlorine during combustion processes was examined in this study.

  1. Posting type Advisory Subject Varying bias of XRF sulfur relative to IC sulfate

    E-Print Network [OSTI]

    Fischer, Emily V.

    Posting type Advisory Subject Varying bias of XRF sulfur relative to IC sulfate Module/Species A of evidence point to XRF measurement bias as the source of most of the observed variation. Figure 1 shows that was offset by two abrupt increases, each coming at the start of a new sample month. The XRF analyses, unlike

  2. Sorbent utilization prediction methodology: sulfur control in fluidized-bed combustors

    SciTech Connect (OSTI)

    Fee, D.C.; Wilson, W.I.; Shearer, J.A.; Smith, G.W.; Lenc, J.F.; Fan, L.S.; Myles, K.M.; Johnson, I.

    1980-09-01T23:59:59.000Z

    The United States Government has embarked on an ambitious program to develop and commercialize technologies to efficiently extract energy from coal in an environmentally acceptable manner. One of the more promising new technologies for steam and power generation is the fluidized-bed combustion of coal. In this process, coal is burned in a fluidized bed composed mainly of calcined limestone sorbent. The calcium oxide reacts chemically to capture the sulfur dioxide formed during the combustion and to maintain the stack gas sulfur emissions at acceptable levels. The spent sulfur sorbent, containing calcium sulfate, is a dry solid that can be disposed of along with coal ash or potentially used. Other major advantages of fluidized-bed combustion are the reduction in nitrogen oxide emissions because of the relatively low combustion temperatures, the capability of burning wide varieties of fuel, the high carbon combustion efficiencies, and the high heat-transfer coefficients. A key to the widespread commercialization of fluidized-bed technology is the ability to accurately predict the amount of sulfur that will be captured by a given sorbent. This handbook meets this need by providing a simple, yet reliable, user-oriented methodology (the ANL method) that allows performance of a sorbent to be predicted. The methodology is based on only three essential sorbent parameters, each of which can be readily obtained from standardized laboratory tests. These standard tests and the subsequent method of data reduction are described in detail.

  3. Structural and Functional Studies on Human Mitochondrial Iron-Sulfur Cluster Biosynthesis

    E-Print Network [OSTI]

    Tsai, Chi-Lin

    2012-07-16T23:59:59.000Z

    Iron-sulfur (Fe-S) clusters are critical protein cofactors found in all life forms. In eukaryotes, a well-conserved biosynthetic pathway located in the mitochondria is used to assemble Fe-S clusters. Although proteins required for Fe-S cluster...

  4. Rare sulfur and triple oxygen isotope geochemistry of volcanogenic sulfate aerosols

    E-Print Network [OSTI]

    Bindeman, Ilya N.

    Rare sulfur and triple oxygen isotope geochemistry of volcanogenic sulfate aerosols I.N. Bindeman a of Technology, Pasadena, CA, USA c Department of Earth and Planetary Sciences, McGill University, Montreal, Que., Canada d Department of Geology and Earth System Science Interdisciplinary Center, University of Maryland

  5. PART I: JOB DESCRIPTION Weighted Job Questionnaire (WJQ) Custom

    E-Print Network [OSTI]

    PART I: JOB DESCRIPTION Weighted Job Questionnaire (WJQ) Custom Department Name: Position Number WEIGHTED JOB QUESTIONNAIRE (WJQ) CUSTOM PARTI: JOB DESCRIPTION 1. POSITION IDENTIFICATION Department

  6. Obesity & Weight Loss Therapy Krakauer and Krakauer, J Obes Weight Loss Ther 2014, 4:2

    E-Print Network [OSTI]

    Krakauer, Nir Y.

    Obesity & Weight Loss Therapy Krakauer and Krakauer, J Obes Weight Loss Ther 2014, 4:2 http the original author and source are credited. Keywords: Waist circumference; Body shape index; Obesity Introduction Obesity has historically been a sign of good health, except at the greatestexcess[1

  7. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06T23:59:59.000Z

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  8. Analyzing organic sulfur in coal/char: Integrated mild gasification/XANES methods. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes; Huffman, G.P. [Kentucky Univ., Lexington, KY (United States)

    1994-09-01T23:59:59.000Z

    The overall goal of this study is to improve the understanding of sulfur in coals/chars via the use of combined advanced non-destructive and advanced destructive methods of sulfur analysis. This study combines selective oxidation, analytical pyrolysis, and sulfur X-ray Absorption Near Edge Structure Spectroscopy (XANES) analysis. Samples with a wide variety of sulfur contents, (0.63% to 4.40%) have been prepared for use in this study. This includes steam gasification chars, oxidized coals and desulfurized coals as well of the original unaltered coals. Mild pyrolysis and preliminary XANES data shows that the sulfur chemistry of gasification chars is significantly different from that of the original coals. Mild pyrolysis of the samples that were oxidized with peroxyacetic acid showed that the level of simple thiophene structures observed in the pyrolysis products declines with increasing levels of oxidation. Sulfur XANES spectra of treated samples showed various effects depending on the treatment severity. For the less severely treated samples (demineralization and solvent extraction), the XANES spectra were similar, although not identical, to the untreated coal spectra, whereas the more severe treatments (steam at 450 C; peroxyacetic acid at 25 C) showed preferential oxidation of one or more sulfur-bearing phases in the original coal. Additional samples have recently been examined by XANES and W-band EPR and the data is currently being processed and evaluated.

  9. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13T23:59:59.000Z

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  10. Weighted median of the data in solving least absolute

    E-Print Network [OSTI]

    Scitovski, Rudolf

    is illustrated by an example of hourly natural gas consumption forecast. Key words. median, weighted median

  11. Manipulation of Weighted Voting Games and the Effect of Quota

    E-Print Network [OSTI]

    Allan, Vicki H.

    for measuring voters' power in weighted voting games. We consider two methods of manipulating weighted voting of manipulators to have more power over the outcomes of the games. We evaluate the extent of susceptibility, Weighted voting games, Manipulation, Annexation, Merging, Power indices. 1 Introduction Weighted voting

  12. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    SciTech Connect (OSTI)

    Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

    2008-07-02T23:59:59.000Z

    Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

  13. Exploring Weight Identity: An Examination of the Cognitive, Affective, and Behavioral Components of Weight

    E-Print Network [OSTI]

    Asbury, Mary Elizabeth

    2011-04-20T23:59:59.000Z

    The current study sought to expand social identity theory (Tajfel, 1978; Tajfel & Turner, 1979) to include the concept of weight. Previous research has shown that individuals have social identities associated with age ...

  14. Replication regulates volume weighting in quantum cosmology

    SciTech Connect (OSTI)

    Hartle, James [Department of Physics, University of California, Santa Barbara, California 93106 (United States); Hertog, Thomas [APC, UMR 7164 (CNRS, Universite Paris 7), 10 rue A.Domon et L.Duquet, 75205 Paris (France) and Intl Solvay Institutes, Boulevard du Triomphe, ULB-C.P. 231, 1050 Brussels (Belgium)

    2009-09-15T23:59:59.000Z

    Probabilities for observations in cosmology are conditioned both on the Universe's quantum state and on local data specifying the observational situation. We show the quantum state defines a measure for prediction through such conditional probabilities that is well-behaved for spatially large or infinite universes when the probabilities that our data are replicated are taken into account. In histories where our data are rare volume weighting connects top-down probabilities conditioned on both the data and the quantum state to the bottom-up probabilities conditioned on the quantum state alone. We apply these principles to a calculation of the number of inflationary e-folds in a homogeneous, isotropic minisuperspace model with a single scalar field moving in a quadratic potential. We find that volume weighting is justified and the top-down probabilities favor a large number of e-folds, hereby predicting the curvature of our Universe at the present time to be approximately zero.

  15. Information weights of nucleotides in DNA sequences

    E-Print Network [OSTI]

    M. R. Dudek; S. Cebrat; M. Kowalczuk; P. Mackiewicz; A. Nowicka; D. Mackiewicz; M. Dudkiewicz

    2003-01-21T23:59:59.000Z

    The coding sequence in DNA molecule is considered as a message to be transferred to receiver, the proteins, through a noisy information channel and each nucleotide is assigned a respective information weight. With the help of the nucleotide substitution matrix we estimated the lower bound of the amount of information carried out by nucleotides which is not subject of mutations. We used the calculated weights to reconstruct k-oligomers of genes from the Borrelia burgdorferi genome. We showed, that to this aim there is sufficient a simple rule, that the number of bits of the carried information cannot exceed some threshold value. The method introduced by us is general and applies to every genome.

  16. Lubricant oil consumption effects on diesel exhaust ash emissions using a sulfur dioxide trace technique and thermogravimetry

    E-Print Network [OSTI]

    Plumley, Michael J

    2005-01-01T23:59:59.000Z

    A detailed experimental study was conducted targeting lubricant consumption effects on ,diesel exhaust ash levels using a model year 2002 5.9L diesel engine, high and low Sulfur commercial lubricants, and clean diesel ...

  17. The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification

    E-Print Network [OSTI]

    Luo, Qian

    2012-01-01T23:59:59.000Z

    S.P Chan, J. M Norbeck, Steam hydrogasification of coal-woodet al. , Sulfur-deactivated steam reforming of gasifiedPark, S.P. Singh, J.M. Norbeck, Steam hydrogasification of

  18. Refined understanding of sulfur amino acid nutrition in hybrid striped bass, Morone chrysops (male symbol) x M. saxatilis (female symbol)

    E-Print Network [OSTI]

    Kelly, Mark Christopher

    2005-08-29T23:59:59.000Z

    Previous studies have indicated the level of total sulfur amino acids (TSAA) (methionine + cystine) is most limiting in practical diet formulations for hybrid striped bass (HSB), especially if animal feedstuffs are replaced with plant feedstuffs...

  19. The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen

    E-Print Network [OSTI]

    Miu, Kevin (Kevin K.)

    2006-01-01T23:59:59.000Z

    The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming - the most prevalent method of hydrogen ...

  20. SO[subscript 2] photolysis as a source for sulfur mass-independent isotope signatures in stratospehric aerosols

    E-Print Network [OSTI]

    Jiang, B.

    Signatures of sulfur isotope mass-independent fractionation (S-MIF) have been observed in stratospheric sulfate aerosols deposited in polar ice. The S-MIF signatures are thought to be associated with stratospheric ...

  1. 1300 Federal Register / Vol. 67, No. 7 / Thursday, January 10, 2002 / Rules and Regulations determining sulfur content in fuel for

    E-Print Network [OSTI]

    1300 Federal Register / Vol. 67, No. 7 / Thursday, January 10, 2002 / Rules and Regulations sampling and analysis for sulfur content under subpart GG for stationary gas turbines that combust pipeline; Atlantic Large Whale Take Reduction Plan Regulation

  2. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01T23:59:59.000Z

    firn and ice at Summit, Greenland, J. Geophys. Res. , 98,AL. : TRACE GASES IN GREENLAND ICE CORE ¨ . Andreae Kettle,and sulfur gases from Greenland ice cores M. Aydin, 1 M. B.

  3. Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants 

    E-Print Network [OSTI]

    Schwartz, M. H.

    1979-01-01T23:59:59.000Z

    pulverized coal-fired boiler equipment. These are: (1) coal cleaning to remove pyritic sulfur, (2) conventional wet, nonregenerable scrubbing with alkaline slurry and solution processes, and (3) dry processes which involve direct introduction of lime...

  4. An In-Situ Photometric and Energy Analysis of a Sulfur LampLighting System

    SciTech Connect (OSTI)

    Crawford, Doug; Gould, Carl; Packer, Michael; Rubinstein,Francis; Siminovitch, Michael

    1995-06-01T23:59:59.000Z

    This paper describes the results of a photometric and energy analysis that was conducted on a new light guide and sulfur lamp system recently installed at the U.S. Department of Energy's Forrestal Building. This novel system couples two high lumen output, high efficiency sulfur lamps to a single 73 m (240 ft.) hollow light guide lined with a reflective prismatic film. The system lights a large roadway and plaza area that lies beneath a section of the building. It has been designed to completely replace the grid of 280 mercury vapor lamps formerly used to light the space. This paper details the results of a field study that characterizes the significant energy savings and increased illumination levels that have been achieved. Comparisons to modeled HID lighting scenarios are also included.

  5. Iron distribution among phases in high- and low-sulfur coal fly ash

    SciTech Connect (OSTI)

    Hower, J.C.; Graham, U.M.; Rathbone, R.F. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Dyar, M.D.; Taylor, M.E. [West Chester Univ., PA (United States). Dept. of Geology and Astronomy

    1995-12-31T23:59:59.000Z

    Moessbauer spectroscopy, reflected-light optical microscopy, scanning-electron microscopy, wet chemical, and X-ray diffraction studies were conducted on six fly ash samples. The fly ashes, representing the combustion by-products of coals with total sulfur contents of less than 2% to greater than 4%, ranged from 17.6 to 32.0% Fe{sub 2}O{sub 3} by XRF analysis. Wet chemical analysis was used to determine the Fe{sup 3+}/{summation}Fe content of the ashes, which ranged from 72% to 83%. Optical analysis of the ashes indicated that the spinel, encompassing iron oxides of various compositions, ranges from 4.0 to 12.6% (vol.). Moessbauer analyses confirmed the presence of three Fe-bearing phases: magnetite, hematite (possibly of two different compositions), and glass. The variation in the Fe-oxidation state follows the variation in the sulfur, consequently pyrite, content of the feed coal.

  6. Sodium/sulfur battery engineering for stationary energy storage. Final report

    SciTech Connect (OSTI)

    Koenig, A.; Rasmussen, J. [Silent Power, Inc., Salt Lake City, UT (United States)

    1996-04-01T23:59:59.000Z

    The use of modular systems to distribute power using batteries to store off-peak energy and a state of the art power inverter is envisioned to offer important national benefits. A 4-year, cost- shared contract was performed to design and develop a modular, 300kVA/300-kWh system for utility and customer applications. Called Nas-P{sub AC}, this system uses advanced sodium/sulfur batteries and requires only about 20% of the space of a lead-acid-based system with a smaller energy content. Ten, 300-VDC, 40-kWh sodium/sulfur battery packs are accommodated behind a power conversion system envelope with integrated digital control. The resulting design facilities transportation, site selection, and deployment because the system is quiet and non-polluting, and can be located in proximity to the load. This report contains a detailed description of the design and supporting hardware development performed under this contract.

  7. ZnO-based regenerable sulfur sorbents for fluid-bed/transport reactor applications

    DOE Patents [OSTI]

    Slimane, Rachid B.; Abbasian, Javad; Williams, Brett E.

    2004-09-21T23:59:59.000Z

    A method for producing regenerable sulfur sorbents in which a support material precursor is mixed with isopropanol and a first portion of deionized water at an elevated temperature to form a sol mixture. A metal oxide precursor comprising a metal suitable for use as a sulfur sorbent is dissolved in a second portion of deionized water, forming a metal salt solution. The metal salt solution and the sol mixture are mixed with a sol peptizing agent while heating and stirring, resulting in formation of a peptized sol mixture. The metal oxide precursor is dispersed substantially throughout the peptized sol mixture, which is then dried, forming a dry peptized sol mixture. The dry peptized sol mixture is then calcined and the resulting calcined material is then converted to particles.

  8. Update on sulfur compound distribution in NGL: Plant test data GPA Section A committee, plant design

    SciTech Connect (OSTI)

    Harryman, J.M. [Shell Oil Co., Houston, TX (United States); Smith, B. [Texaco E and P Inc., Tulsa, OK (United States)

    1996-12-31T23:59:59.000Z

    The mystery of why sulfur compounds could never be balanced from analyses of the product streams of NGL fractionation towers was solved by analyzing the data collected during testing completed by GPA Technical Section A in November and December of 1993 at Texaco`s Eunice, New Mexico fractionation plant. Decomposition of dimethyl disulfide (DMDS) to form methyl mercaptan within the towers is the cause of the sulfur balance discrepancies explained in the paper. The results of testing were reported to the 1994 convention, but at the time, a few weeks after completion of testing, the chemistry was not understood, i.e., what is the source of the hydrogen required to complete the formation of methyl mercaptan. This paper is an update of the previous paper and it includes the DMDS decomposition chemistry. It is essentially the body of a report completed in early 1995, excluding the Appendix of data. The 66-page Appendix may be obtained from the GPA, Tulsa.

  9. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01T23:59:59.000Z

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  10. Controls on the sulfur cycle in estuarine sediments on the Central Texas coast

    E-Print Network [OSTI]

    Thomson, Heather

    2009-06-02T23:59:59.000Z

    volatile sulfides (AVS). TRS does not include elemental sulfur and organic sulfur which are usually at minor concentrations compared to TRS. AVS is part of TRS and has been often considered to be simply solid FeS (mackinawite). However, AVS may also....80 28.49 29.61 92 0.853 Fall Summer 1.00 41.80 30.52 83 0.887 Fall 1.12 35.48 21.57 67 0.724 Summer 1.13 36.81 29.83 15 0.494 Fall 0.91 37.21 22.76 28 0.589 Summer 1.65 0.94 28.15 61 0.634 Fall 0.7 1.51 21.84 23 0.455 Summer 1.18 7.6 27.72 90 0.787 Fall...

  11. Chromatic acclimation and population dynamics of green sulfur bacteria grown with spectrally tailored light

    E-Print Network [OSTI]

    Saikin, Semion K; Huh, Joonsuk; Hannout, Moataz; Wang, Yaya; Zare, Farrokh; Aspuru-Guzik, Alan; Tang, Joseph Kuo-Hsiang

    2014-01-01T23:59:59.000Z

    Living organisms have to adjust to their surrounding in order to survive in stressful conditions. We study this mechanism in one of most primitive creatures - photosynthetic green sulfur bacteria. These bacteria absorb photons very efficiently using the chlorosome antenna complexes and perform photosynthesis in extreme low-light environments. How the chlorosomes in green sulfur bacteria are acclimated to the stressful light conditions, for instance, if the spectrum of light is not optimal for absorption, is unknown. Studying Chlorobaculum tepidum cultures with far-red to near-infrared light-emitting diodes, we found that these bacteria react to changes in energy flow by regulating the amount of light-absorbing pigments and the size of the chlorosomes. Surprisingly, our results indicate that the bacteria can survive in near-infrared lights capturing low-frequency photons by the intermediate units of the light-harvesting complex. The latter strategy may be used by the species recently found near hydrothermal ve...

  12. Near-frictionless carbon coatings for use in fuel injectors and pump systems operating with low-sulfur diesel fuels

    SciTech Connect (OSTI)

    Erdemir, A.; Ozturk, O.; Alzoubi, M.; Woodford, J.; Ajayi, L.; Fenske, G.

    2000-01-19T23:59:59.000Z

    While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO{sub 2} emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. This research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems. The lubricity of various diesel fuels (i.e., high-sulfur, 500 ppm; low sulfur, 140 ppm; ultra-clean, 3 ppm; and synthetic diesel or Fischer-Tropsch, zero sulfur) were tested by using both uncoated and NFC-coated 52100 steel specimens in a ball-on-three-disks and a high-frequency reciprocating wear-test rig. The test program was expanded to include some gasoline fuels as well (i.e., regular gasoline and indolene) to further substantiate the usefulness of the NFC coatings in low-sulfur gasoline environments. The results showed that the NFC coating was extremely effective in reducing wear and providing lubricity in low-sulfur or sulfur-free diesel and gasoline fuels. Specifically, depending on the wear test rig, test pair, and test media, the NFC films were able to reduce wear rates of balls and flats by factors of 8 to 83. These remarkable reductions in wear rates raise the prospect for using the ultra slick carbon coatings to alleviate problems that will be caused by the use of low sulfur diesel and gasoline fuels. Surfaces of the wear scars and tracks were characterized by optical and scanning electron microscopy, and by Raman spectroscopy.

  13. Sulfur Iodine Process Summary for the Hydrogen Technology Down-Selection

    SciTech Connect (OSTI)

    Benjamin Russ

    2009-05-01T23:59:59.000Z

    This report summarizes the sulfur-iodine (SI) thermochemical water splitting process for the purpose of supporting the process for evaluating and recommending a hydrogen production technology to deploy with the Next Generation Nuclear Plant (NGNP). This package provides the baseline process description as well as a comparison with the process as it was implemented in the Integrated Lab Scale (ILS) experiment conducted at General Atomics from 2006-2009.

  14. EVALUATION OF PROTON-CONDUCTING MEMBRANES FOR USE IN A SULFUR-DIOXIDE DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D.; Elvington, M.; Colon-Mercado, H.

    2009-11-11T23:59:59.000Z

    The chemical stability, sulfur dioxide transport, ionic conductivity, and electrolyzer performance have been measured for several commercially available and experimental proton exchange membranes (PEMs) for use in a sulfur dioxide depolarized electrolyzer (SDE). The SDE's function is to produce hydrogen by using the Hybrid Sulfur (HyS) Process, a sulfur based electrochemical/thermochemical hybrid cycle. Membrane stability was evaluated using a screening process where each candidate PEM was heated at 80 C in 60 wt. % H{sub 2}SO{sub 4} for 24 hours. Following acid exposure, chemical stability for each membrane was evaluated by FTIR using the ATR sampling technique. Membrane SO{sub 2} transport was evaluated using a two-chamber permeation cell. SO{sub 2} was introduced into one chamber whereupon SO{sub 2} transported across the membrane into the other chamber and oxidized to H{sub 2}SO{sub 4} at an anode positioned immediately adjacent to the membrane. The resulting current was used to determine the SO{sub 2} flux and SO{sub 2} transport. Additionally, membrane electrode assemblies (MEAs) were prepared from candidate membranes to evaluate ionic conductivity and selectivity (ionic conductivity vs. SO{sub 2} transport) which can serve as a tool for selecting membranes. MEAs were also performance tested in a HyS electrolyzer measuring current density versus a constant cell voltage (1V, 80 C in SO{sub 2} saturated 30 wt% H2SO{sub 4}). Finally, candidate membranes were evaluated considering all measured parameters including SO{sub 2} flux, SO{sub 2} transport, ionic conductivity, HyS electrolyzer performance, and membrane stability. Candidate membranes included both PFSA and non-PFSA polymers and polymer blends of which the non-PFSA polymers, BPVE-6F and PBI, showed the best selectivity.

  15. Evaluation of an enhanced gravity-based fine-coal circuit for high-sulfur coal

    SciTech Connect (OSTI)

    Mohanty, M.K.; Samal, A.R.; Palit, A. [South Illinois University, Carbondale, IL (United States). Dept. of Mining & Mineral Resources Engineering

    2008-02-15T23:59:59.000Z

    One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m{sup 2}, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The 'linear screen + enhanced gravity separator + screen-bowl circuit' provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61 %, respectively.

  16. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  17. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, Krishnamurti (Naperville, IL)

    1992-01-01T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

  18. Industrial recovery capability. Final report. [Claus alumina catalyst for sulfur production

    SciTech Connect (OSTI)

    Gregg, D.W.

    1984-12-01T23:59:59.000Z

    This report provides an evaluation of the vulnerability - to a nuclear strike, terrorist attack, or natural disaster - of our national capacity to produce chlorine, beryllium, and a particular specialty alumina catalyst required for the production of sulfur. All of these industries are of critical importance to the United States economy. Other industries that were examined and found not to be particularly vulnerable are medicinal drugs and silicon wafers for electronics. Thus, only the three more vulnerable industries are addressed in this report.

  19. The effect of sulfur, magnesium, and various rates of potassium on forage production in some sandy soils of East Texas 

    E-Print Network [OSTI]

    Landua, Dennis Paul

    1969-01-01T23:59:59.000Z

    THE EFFECT OF SULFUR, MAGNESIUM, AND VARIOUS RATES OF POTASSIUM ON FORAGE PRODUCTION IN SOME SANDy SOILS OF EAST TEXAS A Thesis by DENNIS PAUL LANDUA Submitted to the Graduate Collccje of Texas AFM Unive, sity in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE Ma 1969 Major Subject Soil Chemistr THE EFFECT OF SULFUR, MAGNESIUM, AND VARIOUS RATES OF POTASSIUM ON FORAGE PRODUCTION IN SOME SANDY SOILS OF EAST TEXAS A Thesis by DENNIS PAUL LANDUA Approved...

  20. NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance

    SciTech Connect (OSTI)

    Rangan, M.; Yung, M. M.; Medlin, J. W.

    2012-06-01T23:59:59.000Z

    Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

  1. Sulfur, Chlorine, and Argon Abundances in Planetary Nebulae. III: Observations and Results for a Final Sample

    E-Print Network [OSTI]

    K. B. Kwitter; R. B. C. Henry; J. B. Milingo

    2002-09-25T23:59:59.000Z

    This paper is the fourth in a series whose purpose is to study the interstellar abundances of sulfur, chlorine, and argon in the Galaxy using a sample of 86 planetary nebulae. Here we present new high-quality spectrophotometric observations of 20 Galactic planetary nebulae with spectral coverage from 3700-9600 Angstroms. A major feature of our observations throughout the entire study has been the inclusion of the near-infrared lines of [S III] 9069,9532, which allows us to calculate accurate S+2 abundances and to either improve upon or convincingly confirm results of earlier sulfur abundance studies. For each of the 20 objects here we calculate ratios of S/O, Cl/O, and Ar/O and find average values of S/O=1.1E-2+/-1.1E-2, Cl/O=4.2E-4+/-5.3E-4, and Ar/O=5.7E-3+/-4.3E-3. For six objects we are able to compare abundances of S+3 calculated directly from available [S IV] 10.5 micron measurements with those inferred indirectly from the values of the ionization correction factors for sulfur. In the final paper of the series, we will compile results from all 86 objects, search for and evaluate trends, and use chemical evolution models to interpret our results.

  2. Activated carbon cleanup of the acid gas feed to Claus sulfur plants

    SciTech Connect (OSTI)

    Harruff, L.G.; Bushkuhl, S.J. [Saudi Aramco, Dhahran (Saudi Arabia)

    1996-12-31T23:59:59.000Z

    This paper presents the details of a recently developed novel process using activated carbon to remove hydrocarbon contaminants from the acid gas feed to Claus sulfur recovery units. Heavy hydrocarbons, particularly benzene, toluene and xylene (BTX) have been linked to coke formation and catalyst deactivation in Claus converters. This deactivation results in reduced sulfur recovery and increased sulfur emissions from these plants. This effect is especially evident in split flow Claus plants which bypass some of the acid gas feed stream around the initial combustion step because of a low hydrogen sulfide concentration. This new clean-up process was proven to be capable of removing 95% of the BTX and other C{sub 6}{sup +} hydrocarbons from acid gas over a wide range of actual plant conditions. Following the adsorption step, the activated carbon was easily regenerated using low pressure steam. A post regeneration drying step using plant fuel gas also proved beneficial. This technology was extensively pilot tested in Saudi Aramco`s facilities in Saudi Arabia. Full scale commercial units are planned for two plants in the near future with the first coming on-line in 1997. The process described here represents the first application of activated carbon in this service, and a patent has been applied for. The paper will discuss the pilot plant results and the issues involved in scale-up to commercial size.

  3. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1999-06-22T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  4. Vacuum carbonate desulfurization and claus sulfur recovery system at No. 11 battery

    SciTech Connect (OSTI)

    Ellis, A.

    1981-01-01T23:59:59.000Z

    The vacuum carbonate process functions above 90% efficiency and satisfactorily removes the HCN and sulfur compounds from the coke oven gas generated at No. 11 Battery. It has been noted that a large quantity of energy is required for the operation of the vacuum carbonate system. Normally 544,617 kg (1.2 million lbs of steam) and 5.4 thousand kWh of electricity are used per day to maintain the system's temperatures and pressures. The processed coke oven gases from the system satisfy industrial and environmental standards as a combustible fuel. The HCN destruction unit reduces the corrosive HCN to concentrations below .07% of the acid gas stream and offers the necessary protection to the downstream modified Claus unit. The Claus unit at No. 11 Battery operates at 98% efficiency and produces 5896 kg (6.5 tons) of sulfur per day. The liquid sulfur generated in the Claus unit is a high quality product of 99% purity. 7 figures, 3 tables.

  5. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, George (820 Skywood Rd., Lafayette, CA 94549); Orr, Thomas Robert (2285 Vestal, Castro Valley, CA 94546); Greene, Charles Maurice (6450 Regent St., Oakland, CA 94618); Crawford, Douglas Gordon (33 Longridge Rd., Orinda, CA 94563); Berman, Samuel Maurice (2832 Union St., San Francisco, CA 94123)

    1998-01-01T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  6. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, George (Lafayette, CA); Orr, Thomas Robert (Castro Valley, CA); Greene, Charles Maurice (Oakland, CA); Crawford, Douglas Gordon (Orinda, CA); Berman, Samuel Maurice (San Francisco, CA)

    1999-01-01T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  7. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1998-10-20T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  8. HYBRID SULFUR FLOWSHEETS USING PEM ELECTROLYSIS AND A BAYONET DECOMPOSITION REACTOR

    SciTech Connect (OSTI)

    Gorensek, M; William Summers, W

    2008-05-30T23:59:59.000Z

    A conceptual design is presented for a Hybrid Sulfur process for the production of hydrogen using a high-temperature nuclear heat source to split water. The process combines proton exchange membrane-based SO{sub 2}-depolarized electrolyzer technology being developed at Savannah River National Laboratory with silicon carbide bayonet decomposition reactor technology being developed at Sandia National Laboratories. Both are part of the US DOE Nuclear Hydrogen Initiative. The flowsheet otherwise uses only proven chemical process components. Electrolyzer product is concentrated from 50 wt% sulfuric acid to 75 wt% via recuperative vacuum distillation. Pinch analysis is used to predict the high-temperature heat requirement for sulfuric acid decomposition. An Aspen Plus{trademark} model of the flowsheet indicates 340.3 kJ high-temperature heat, 75.5 kJ low-temperature heat, 1.31 kJ low-pressure steam, and 120.9 kJ electric power are consumed per mole of H{sub 2} product, giving an LHV efficiency of 35.3% (41.7% HHV efficiency) if electric power is available at a conversion efficiency of 45%.

  9. Resistance of biofilm-covered mortars to microbiologically influenced deterioration simulated by sulfuric acid exposure

    SciTech Connect (OSTI)

    Soleimani, Sahar, E-mail: ssoleima@connect.carleton.ca; Isgor, O. Burkan, E-mail: burkan_isgor@carleton.ca; Ormeci, Banu, E-mail: banu_ormeci@carleton.ca

    2013-11-15T23:59:59.000Z

    Following the reported success of biofilm applications on metal surfaces to inhibit microbiologically influenced corrosion, effectiveness and sustainability of E. coli DH5? biofilm on mortar surface to prevent microbiologically influenced concrete deterioration (MICD) are investigated. Experiments simulating microbial attack were carried out by exposing incrementally biofilm-covered mortar specimens to sulfuric acid solutions with pH ranging from 3 to 6. Results showed that calcium concentration in control reactors without biofilm was 23–47% higher than the reactors with biofilm-covered mortar. Formation of amorphous silica gel as an indication of early stages of acid attack was observed only on the control mortar specimens without biofilm. During acidification, the biofilm continued to grow and its thickness almost doubled from ? 30 ?m before acidification to ? 60 ?m after acidification. These results demonstrated that E. coli DH5? biofilm was able to provide a protective and sustainable barrier on mortar surfaces against medium to strong sulfuric acid attack. -- Highlights: •Effectiveness of E.coli DH5? biofilm to prevent MICD was studied. •Conditions that lead to MICD were simulated by chemical acidification. •Biofilm-covered mortar specimens were exposed to sulfuric acid solutions. •The presence of biofilm helped reduce the chemically-induced mortar deterioration. •Biofilm remained alive and continued to grow during the acidification process.

  10. Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge

    SciTech Connect (OSTI)

    Wang, Bin [Vanderbilt University, Nashville; Alhassan, Saeed M. [The Petroleum Institute; Pantelides, Sokrates T [ORNL

    2014-01-01T23:59:59.000Z

    Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

  11. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  12. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  13. Encapsulation of mixed radioactive and hazardous waste contaminated incinerator ash in modified sulfur cement

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1990-01-01T23:59:59.000Z

    Some of the process waste streams incinerated at various Department of Energy (DOE) facilities contain traces of both low-level radioactive (LLW) and hazardous constituents, thus yielding ash residues that are classified as mixed waste. Work is currently being performed at Brookhaven National Laboratory (BNL) to develop new and innovative materials for encapsulation of DOE mixed wastes including incinerator ash. One such material under investigation is modified sulfur cement, a thermoplastic developed by the US Bureau of Mines. Monolithic waste forms containing as much as 55 wt % incinerator fly ash from Idaho national Engineering Laboratory (INEL) have been formulated with modified sulfur cement, whereas maximum waste loading for this waste in hydraulic cement is 16 wt %. Compressive strength of these waste forms exceeded 27.6 MPa. Wet chemical and solid phase waste characterization analyses performed on this fly ash revealed high concentrations of soluble metal salts including Pb and Cd, identified by the Environmental Protection Agency (EPA) as toxic metals. Leach testing of the ash according to the EPA Toxicity Characteristic Leaching Procedure (TCLP) resulted in concentrations of Pb and Cd above allowable limits. Encapsulation of INEL fly ash in modified sulfur cement with a small quantity of sodium sulfide added to enhance retention of soluble metal salts reduced TCLP leachate concentrations of Pb and Cd well below EPA concentration criteria for delisting as a toxic hazardous waste. 12 refs., 4 figs., 2 tabs.

  14. Lithium-sulfur batteries based on nitrogen-doped carbon and ionic liquid electrolyte

    SciTech Connect (OSTI)

    Sun, Xiao-Guang [ORNL; Wang, Xiqing [ORNL; Mayes, Richard T [ORNL; Dai, Sheng [ORNL

    2012-01-01T23:59:59.000Z

    Nitrogen-doped mesoporous carbon (NC) and sulfur were used to prepare an NC/S composite cathode, which was evaluated in an ionic liquid electrolyte of 0.5 M lithium bis(trifluoromethane sulfonyl)imide (LiTFSI) in methylpropylpyrrolidinium bis(trifluoromethane sulfonyl)imide (MPPY.TFSI) by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and cycle testing. To facilitate the comparison, a C/S composite based on activated carbon (AC) without nitrogen doping was also fabricated under the same conditions as those for the NC/S composite. Compared with the AC/S composite, the NC/S composite showed enhanced activity toward sulfur reduction, as evidenced by the early onset sulfur reduction potential, higher redox current density in the CV test, and faster charge transfer kinetics as indicated by EIS measurement. At room temperature under a current density of 84 mA g-1 (C/20), the battery based on the NC/S composite exhibited higher discharge potential and an initial capacity of 1420 mAh g-1 whereas that based on the AC/S composite showed lower discharge potential and an initial capacity of 1120 mAh g-1. Both batteries showed similar capacity fading with cycling due to the intrinsic polysulfide solubility and the polysulfide shuttle mechanism; the capacity fading can be improved by further modification of the cathode.

  15. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20T23:59:59.000Z

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  16. Electrochemical and metallurgical aspects of stress corrosion cracking of sensitized Alloy 600 in simulated primary water containing sulfur contamination

    SciTech Connect (OSTI)

    Bandy, R.; Kelly, K.

    1985-01-01T23:59:59.000Z

    The stress corrosion cracking (SCC) of sensitized Alloy 600 was investigated in aerated solutions of sodium thiosulfate containing 1.3% boric acid. Results indicate that in the borated thiosulfate solution containing 7 ppM sulfur, 5 ppM lithium as lithium hydroxide is sufficient to inhibit SCC in U-bends. The occurrence of inhibition seems to correlate to the rapid increase of pH and conductivity of the solution as a result of the lithium hydroxide addition. In the slow strain rate tests in the borated solution containing 0.7 ppM lithium as lithium hydroxide, significant SCC is observed at a sulfur level of 30 ppB, i.e., a lithium to sulfur ratio of 23. In a parallel test in 30 ppB sulfur level but without any lithium hydroxide, the SCC is more severe than that in the lithiated environment. In the constant load test on a specimen held initially at a nominal stress near the yield strength of the material, cracks continue to grow until fracture during controlled, progressive dilution of the bulk solution, leading to final lithium concentration of 1.5 ppM and sulfur concentration (as thiosulfate) of 9.6 ppB i.e., a lithium to sulfur ratio of about 156, although lithium hydroxide retards the rate of crack propagation to some extent. The crack growth rate is strongly influenced by the electrochemical potential which is primarily governed by the local crack tip chemistry.

  17. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

  18. Nutrition, Weight Control and Fast Food.

    E-Print Network [OSTI]

    Sweeten, Mary K.

    1980-01-01T23:59:59.000Z

    Page in Original Bulletin] Nutrition, Weight Control and Fast Food Mary K. Sweeten* The Fast Food Trend More people are eating fewer meals at home and more snack-type meals at fast food ' restaurants. Fast food sales in 1978 in the United States... chain when eating out 60 percent of the time. This trend is a result of more women employed outside the home, a higher per capita disposable income and more leisure time. Although they may cost more than the same meals prepared at home, fast food res...

  19. Light-weight analyzer for odor recognition

    DOE Patents [OSTI]

    Vass, Arpad A; Wise, Marcus B

    2014-05-20T23:59:59.000Z

    The invention provides a light weight analyzer, e.g., detector, capable of locating clandestine graves. The detector utilizes the very specific and unique chemicals identified in the database of human decompositional odor. This detector, based on specific chemical compounds found relevant to human decomposition, is the next step forward in clandestine grave detection and will take the guess-work out of current methods using canines and ground-penetrating radar, which have historically been unreliable. The detector is self contained, portable and built for field use. Both visual and auditory cues are provided to the operator.

  20. atomic weight values: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a sample of 10 100 atoms. Sumei Huang; Girish S. Agarwal 2015-01-10 3 Power laws and fractal behavior in nuclear stability, atomic weights and molecular weights Physics Websites...

  1. atomic weight determinations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Power laws and fractal behavior in nuclear stability, atomic weights and molecular weights Physics Websites...

  2. Written emotional expression: Effects on weight loss and maintenance

    E-Print Network [OSTI]

    Hockemeyer, Jill Renee

    2007-10-16T23:59:59.000Z

    the negative effects of distress on weight loss and maintenance through improved emotional self-regulatory processes. This study examined the effects of expressive writing on weight regain, stress, and emotional eating among individuals who have recently lost...

  3. PARTI: JOB DESCRIPTION Weighted Job Questionnaire (WJQ) Custom

    E-Print Network [OSTI]

    PARTI: JOB DESCRIPTION Weighted Job Questionnaire (WJQ) Custom Meeting, Event and Conference UNIVERSITY & C.U.P.E., Local 3338 WEIGHTED JOB QUESTIONNAIRE (WJQ) CUSTOM PARTI: JOB DESCRIPTION 1. POSITION

  4. A weighted iterative algorithm for neuromagnetic imaging

    SciTech Connect (OSTI)

    Gorodnitsky, I. (Los Alamos National Lab., NM (United States) California Univ., San Diego, La Jolla, CA (United States)); George, J.S.; Schlitt, H.A.; Lewis, P.S. (Los Alamos National Lab., NM (United States))

    1992-01-01T23:59:59.000Z

    The goal of neuromagnetic source reconstruction is high resolution 3-D mapping of the current distribution within the brain. However, the neuromagnetic inverse problem is ill-posed and typically underdetermined. The Moore-Penrose pseudoinverse provides a linear algebraic inverse calculation that simultaneously minimizes chisquare and the Euclidean norm of the component currents. Such minimum norm'' reconstructions tend to produce diffuse and superficial current distributions because voxels nearer the sensor array can account for more power in the data with less current than deeper voxels. We describe an algorithm that overcomes the bias of minimum norm procedures toward superficial solutions by using weights chosen to compensate for the distance dependence of magnetic signal strength. We also apply a Bayesian weighting strategy in an iterative pseudoinverse computation, to address the bias of the linear estimator procedure toward diffuse solutions. This strategy produces a progressively more focal current distribution while accomodating distributed current sources, and appears to effectively reduce the problems associated with the under-determined linear system.

  5. A weighted iterative algorithm for neuromagnetic imaging

    SciTech Connect (OSTI)

    Gorodnitsky, I. [Los Alamos National Lab., NM (United States)]|[California Univ., San Diego, La Jolla, CA (United States); George, J.S.; Schlitt, H.A.; Lewis, P.S. [Los Alamos National Lab., NM (United States)

    1992-09-01T23:59:59.000Z

    The goal of neuromagnetic source reconstruction is high resolution 3-D mapping of the current distribution within the brain. However, the neuromagnetic inverse problem is ill-posed and typically underdetermined. The Moore-Penrose pseudoinverse provides a linear algebraic inverse calculation that simultaneously minimizes chisquare and the Euclidean norm of the component currents. Such ``minimum norm`` reconstructions tend to produce diffuse and superficial current distributions because voxels nearer the sensor array can account for more power in the data with less current than deeper voxels. We describe an algorithm that overcomes the bias of minimum norm procedures toward superficial solutions by using weights chosen to compensate for the distance dependence of magnetic signal strength. We also apply a Bayesian weighting strategy in an iterative pseudoinverse computation, to address the bias of the linear estimator procedure toward diffuse solutions. This strategy produces a progressively more focal current distribution while accomodating distributed current sources, and appears to effectively reduce the problems associated with the under-determined linear system.

  6. Characterization of fly ash from low-sulfur and high-sulfur coal sources: Partitioning of carbon and trace elements with particle size

    SciTech Connect (OSTI)

    Hower, J.C.; Trimble, A.S. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research]|[Franklin County High School, Frankfort, KY (United States); Eble, C.F. [Kentucky Geological survey, Lexington, KY (United States); Palmer, C.A.; Kolker, A. [Geological Survey, Reston, VA (United States)

    1999-07-01T23:59:59.000Z

    Fly ash samples were collected in November and December of 1994, from generating units at a Kentucky power station using high- and low-sulfur feed coals. The samples are part of a two-year study of the coal and coal combustion byproducts from the power station. The ashes were wet screened at 100, 200, 325, and 500 mesh (150, 75, 42, and 25 {micro}m, respectively). The size fractions were then dried, weighed, split for petrographic and chemical analysis, and analyzed for ash yield and carbon content. The low-sulfur heavy side and light side ashes each have a similar size distribution in the November samples. In contrast, the December fly ashes showed the trend observed in later months, the light-side ash being finer (over 20% more ash in the {minus}500 mesh [{minus}25 {micro}m] fraction) than the heavy-side ash. Carbon tended to be concentrated in the coarse fractions in the December samples. The dominance of the {minus}325 mesh ({minus}42 {micro}m) fractions in the overall size analysis implies, though, that carbon in the fine sizes may be an important consideration in the utilization of the fly ash. Element partitioning follows several patterns. Volatile elements, such as Zn and As, are enriched in the finer sizes, particularly in fly ashes collected at cooler, light-side electrostatic precipitator (ESP) temperatures. The latter trend is a function of precipitation at the cooler-ESP temperatures and of increasing concentration with the increased surface area of the finest fraction. Mercury concentrations are higher in high-carbon fly ashes, suggesting Hg adsorption on the fly ash carbon. Ni and Cr are associated, in part, with the spinel minerals in the fly ash.

  7. Advanced sulfur control concepts for hot-gas desulfurization technology. Quarterly report, July 1 - September 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    The primary objective is to determine the feasibility of an alternate concept for the regeneration of high temperature desulfurization sorbents in which elemental sulfur, instead of SO{sub 2} is produced. Iron and cerium-based sorbents were chosen on the basis of thermodynamic analysis to determine the feasibility of elemental sulfur production. Experimental effort on the regeneration of FeS using the partial oxidation concept was completed during the quarter, and attention returned to the sulfidation of CeO{sub 2} and regeneration of Ce{sub 2}O{sub 2}2S. Progress was made in the process simulation effort involving two-step desulfurization using CeO{sub 2} to remove the bulk of the H{sub 2}S followed by a zinc-titanate polishing step. The simulation effort includes regeneration of Ce{sub 2}O{sub 2}S using two concepts - reaction with SO{sub 2} reaction with H{sub 2}O. Elemental sulfur is formed directly in the reaction with SO{sub 2} while H{sub 2}S is the product of the regeneration reaction with steam. Steam regeneration is followed by a Claus process to convert the H{sub 2}S to elemental sulfur. The last test involving partial oxidation regeneration of FeS was completed in early July. Experimental problems were encountered throughout this phase of the program, primarily associated with erratic readings from the total sulfur analyzer. The problems are attributed to variable flow rates through the capillary restrictor, and, in some cases, to steam concentrations which exceeded the capacity of the membrane dryer. Nevertheless, sufficient data was collected to confirm that large fractions of the sulfur in FeS could be liberated in elemental form. Low regeneration temperature ({approximately}600{degrees}C), large steam-to-oxygen ratios, and low space velocities were found to favor elemental sulfur production.

  8. GOALS, EXPECTATIONS, AND SATISFACTION IN THE MAINTENANCE OF WEIGHT LOSS

    E-Print Network [OSTI]

    Chang, Olivia L.

    2009-08-19T23:59:59.000Z

    ......................................................................25 Satisfaction and Weight Loss 37 Measurement of Goals, Expectations, and Satisfaction with Weight Loss...............41 Goals, Expectations, and Satisfaction in the Treatment of Obesity 43 Limitations of Previous Research... of approximately 15-25% of initial weight in 2 to 4 months of treatment, but may also result in substantially greater weight regain than more conventional, calorie-restrictive diets (Wadden & Osei, 2002). Pharmacological interventions have been presented...

  9. Clean coal technology and emissions trading: Is there a future for high-sulfur coal under the Clean Air Act Amendments of 1990?

    SciTech Connect (OSTI)

    Bailey, K.A.; South, D.W. [Argonne National Lab., IL (United States); McDermott, K.A. [Argonne National Lab., IL (United States)]|[Illinois State Univ., Normal, IL (United States)

    1991-12-31T23:59:59.000Z

    The near-term and long-term fate of high-sulfur coal is linked to utility compliance plans, the evolution of emission allowance trading, state and federal regulation, and technological innovation. All of these factors will play an implicit role in the demand for high-sulfur coal. This paper will explore the potential impact that emissions trading will have on high-sulfur coal utilization by electric utilities. 28 refs., 6 figs., 4 tabs.

  10. Clean coal technology and emissions trading: Is there a future for high-sulfur coal under the Clean Air Act Amendments of 1990

    SciTech Connect (OSTI)

    Bailey, K.A.; South, D.W. (Argonne National Lab., IL (United States)); McDermott, K.A. (Argonne National Lab., IL (United States) Illinois State Univ., Normal, IL (United States))

    1991-01-01T23:59:59.000Z

    The near-term and long-term fate of high-sulfur coal is linked to utility compliance plans, the evolution of emission allowance trading, state and federal regulation, and technological innovation. All of these factors will play an implicit role in the demand for high-sulfur coal. This paper will explore the potential impact that emissions trading will have on high-sulfur coal utilization by electric utilities. 28 refs., 6 figs., 4 tabs.

  11. Constrained Clustering with Minkowski Weighted Renato Cordeiro de Amorim

    E-Print Network [OSTI]

    Amorim, Renato Cordeiro de

    Constrained Clustering with Minkowski Weighted K-Means Renato Cordeiro de Amorim Department: renato@dcs.bbk.ac.uk Abstract--In this paper we introduce the Constrained Minkowski Weighted K-Means ratify the general superiority of using feature weighting in K-Means, particularly when applying

  12. The Complexity of Weighted Boolean #CSP , Sangxia Huang2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    The Complexity of Weighted Boolean #CSP Modulo k Heng Guo1 , Sangxia Huang2 , Pinyan Lu3@gmail.com Abstract We prove a complexity dichotomy theorem for counting weighted Boolean CSP modulo k for any similar to the one for the complex weighted Boolean #CSP, found by [Cai, Lu and Xia, STOC 2009]. Then we

  13. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. [Institute of Gas Technology, Chicago, IL (United States); Gidaspow, D.; Gupta, R.; Wasan, D.T. [Illinois Inst. of Tech., Chicago, IL (United States); Pfister, R.M.: Krieger, E.J. [Ohio State Univ., Columbus, OH (United States)

    1992-05-01T23:59:59.000Z

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  14. Abstract--This paper describes an approach for choosing and updating measurement weights used in weighted least squares

    E-Print Network [OSTI]

    -- Auto Tuning; Measurement Weights; Power System State Estimation; Random Error Variances. I is not always true. M is used for estimating measurement e1 Abstract--This paper describes an approach for choosing and updating measurement weights used

  15. Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles

    SciTech Connect (OSTI)

    Hammel, C.J.

    1992-09-01T23:59:59.000Z

    This report examines the shipping regulations that govern the shipment of dangerous goods. Since the elemental sodium contained in both sodium-sulfur and sodium-metal-chloride batteries is classified as a dangerous good, and is listed on both the national and international hazardous materials listings, both national and international regulatory processes are considered in this report The interrelationships as well as the differences between the two processes are highlighted. It is important to note that the transport regulatory processes examined in this report are reviewed within the context of assessing the necessary steps needed to provide for the domestic and international transport of sodium-beta batteries. The need for such an assessment was determined by the Shipping Sub-Working Group (SSWG) of the EV Battery Readiness Working Group (Working Group), created in 1990. The Working Group was created to examine the regulatory issues pertaining to in-vehicle safety, shipping, and recycling of sodium-sulfur batteries, each of which is addressed by a sub-working group. The mission of the SSWG is to establish basic provisions that will ensure the safe and efficient transport of sodium-beta batteries. To support that end, a proposal to the UN Committee of Experts was prepared by the SSWG, with the goal of obtaining a proper shipping name and UN number for sodium-beta batteries and to establish the basic transport requirements for such batteries (see the appendix for the proposal as submitted). It is emphasized that because batteries are large articles containing elemental sodium and, in some cases, sulfur, there is no existing UN entry under which they can be classified and for which modal transport requirements, such as the use of packaging appropriate for such large articles, are provided for. It is for this reason that a specific UN entry for sodium-beta batteries is considered essential.

  16. Synergistic capture mechanisms for alkali and sulfur species from combustion. Final report

    SciTech Connect (OSTI)

    Peterson, T.W.; Shadman, F.; Wendt, J.O.L.; Mwabe, P.O.

    1994-02-01T23:59:59.000Z

    Experimental work was carried out on a 17 kW, 600 cm long, gas laboratory combustor, to investigate the post flame reactive capture of alkali species by kaolinite. Emphasis was on alkali/sorbent interactions occurring in flue gas at temperatures above the alkali dewpoint and on the formation of water insoluble reaction products. Time-temperature studies were carried out by injecting kaolinite at different axial points along the combustor. The effect of chlorine and sulfur on alkali capture was investigated by doping the flame with SO{sub 2} and Cl{sub 2} gases to simulate coal flame environments. Particle time and temperature history was kept as close as possible to that which would ordinarily be found in a practical boiler. Experiments designed to extract apparent initial reaction rates were carried using a narrow range, 1-2 {mu}m modal size sorbent, while, a coarse, multi size sorbent was used to investigate the governing transport mechanisms. The capture reaction has been proposed to be between alkali hydroxide and activated kaolinite, and remains so in the presence of sulfur and chlorine. The presence of sulfur reduces sodium capture by under 10% at 1300{degree}C. Larger reductions at lower temperatures are attributed to the elevated dewpoint of sodium ({approximately}850{degree}C) with subsequent reduction in sorbent residence time in the alkali gas phase domain. Chlorine reduces sodium capture by 30% across the temperature range covered by the present experiments. This result has been linked to thermodynamic equilibria between sodium hydroxide, sodium chloride and water.

  17. Volume-weighted measure for eternal inflation

    SciTech Connect (OSTI)

    Winitzki, Sergei [Department of Physics, Ludwig-Maximilians University, Munich (Germany) and Yukawa Institute of Theoretical Physics, Kyoto University, Kyoto (Japan)

    2008-08-15T23:59:59.000Z

    I propose a new volume-weighted probability measure for cosmological 'multiverse' scenarios involving eternal inflation. The 'reheating-volume (RV) cutoff' calculates the distribution of observable quantities on a portion of the reheating hypersurface that is conditioned to be finite. The RV measure is gauge-invariant, does not suffer from the 'youngness paradox', and is independent of initial conditions at the beginning of inflation. In slow-roll inflationary models with a scalar inflaton, the RV-regulated probability distributions can be obtained by solving nonlinear diffusion equations. I discuss possible applications of the new measure to 'landscape' scenarios with bubble nucleation. As an illustration, I compute the predictions of the RV measure in a simple toy landscape.

  18. VHF EPR quantitation and speciation of organic sulfur in coal. Technical report, September 1, 1993--November 30, 1993

    SciTech Connect (OSTI)

    Clarkson, R.B.; Belford, R.L. [Illinois Univ., Urbana, IL (United States)

    1993-12-31T23:59:59.000Z

    Over the last few years, we have developed a non-destructive technique called Very High Frequency Electron Paramagnetic Resonance (VHF-EPR) that is proving to be a practical and very sensitive analytical method for the organic sulfur in coal. Already, although still under development, the technique rapidly can quantify organic sulfur, and perhaps provide information on organic oxygen and nitrogen, in typical Illinois coals. At this stage, the precision is not well enough calibrated, and specificity for particular species needs more development. This year`s proposal outlined a 12 month work plan designed to improve and extend the utility of VHF-EPR. Two main goals of the work are: (1) refinement and calibration of organic sulfur analysis, in coals of differing rank, over a concentration range from 0.1% to 5%, and (2) better utilization of VHF-EPR coal spectral data for sulfur speciation. This quarter, goal (1) is being pursued; results will be ready to describe in a future report. Meanwhile, work toward goal (2) has produced detailed information about the VHF-EPR spectral behavior of several comparison compounds -- sulfur -- containing thiophenic fused-ring molecules.

  19. Treatability study on the use of by-product sulfur in Kazakhstan for the stabilization of hazardous and radioactive wastes

    SciTech Connect (OSTI)

    Kalb, P.D.; Milian, L.W. [Brookhaven National Lab., Upton, NY (United States). Environmental and Waste Technology Center; Yim, S.P. [Korea Atomic Energy Research Inst. (Korea, Republic of); Dyer, R.S.; Michaud, W.R. [Environmental Protection Agency (United States)

    1997-12-01T23:59:59.000Z

    The Republic of Kazakhstan generates significant quantities of excess elemental sulfur from the production and refining of petroleum reserves. In addition, the country also produces hazardous, and radioactive wastes which require treatment/stabilization. In an effort to find secondary uses for the elemental sulfur, and simultaneously produce a material which could be used to encapsulate, and reduce the dispersion of harmful contaminants into the environment, BNL evaluated the use of the sulfur polymer cement (SPC) produced from by-product sulfur in Kazakhstan. This thermoplastic binder material forms a durable waste form with low leaching properties and is compatible with a wide range of waste types. Several hundred kilograms of Kazakhstan sulfur were shipped to the US and converted to SPC (by reaction with 5 wt% organic modifiers) for use in this study. A phosphogypsum sand waste generated in Kazakhstan during the purification of phosphate fertilizer was selected for treatment. Waste loadings of 40 wt% were easily achieved. Waste form performance testing included compressive strength, water immersion, and Accelerated Leach Testing.

  20. Treatability study on the use of by-product sulfur in Kazakhstan for the stabilization of hazardous and radioactive wastes

    SciTech Connect (OSTI)

    Yim, Sung Paal; Kalb, P.D.; Milian, L.W.

    1997-08-01T23:59:59.000Z

    The Republic of Kazakhstan generates significant quantities of excess sulfur from the production and refining of petroleum reserves. In addition, the country also produces hazardous, and radioactive wastes which require treatment/stabilization. In an effort to find secondary uses for the elemental sulfur, and simultaneously produce a material which could be used to encapsulate, and reduce the dispersion of harmful contaminants into the environment, BNL evaluated the use of the sulfur polymer cement (SPC) produced from by-product sulfur in Kazakhstan. This thermoplastic binder material forms a durable waste form with low leaching properties and is compatible with a wide range of waste types. Several hundred kilograms of Kazakhstan sulfur were shipped to the U.S. and converted to SPC (by reaction with 5 wt% organic modifiers) for use in this study. A phosphogypsum sand waste generated in Kazakhstan during the purification of phosphate fertilizer was selected for treatment. Waste loading of 40 wt% were easily achieved. Waste form performance testing included compressive strength, water immersion, and Accelerated Leach Testing. 14 refs., 7 figs., 6 tabs.

  1. XAFS Studies of Nickel And Sulfur Speciation in Residual Oil Fly-Ash Particulate Matters (ROFA PM)

    SciTech Connect (OSTI)

    Pattanaik, S.; Huggins, F.E.; Huffman, G.P.; Linak, W.P.; Miller, C.A.

    2007-07-12T23:59:59.000Z

    XAFS spectroscopy has been employed to evaluate the effect of fuel compositions and combustion conditions on the amount, form, and distribution of sulfur and nickel in size-fractionated ROFA PM. Analysis of S K-edge XANES establish that sulfate is abundant in all PM. However, depending upon the combustion conditions, lesser amounts of thiophenic sulfur, metal sulfide, and elemental sulfur may also be observed. Least-squares fitting of Ni K-edge XANES reveals that most of the nickel in PM is present as bioavailable NiSO{sub 4}.nH{sub 2}O. The insoluble Ni mainly exists as a minor species, as nickel ferrite in PM{sub 2.5} (PM < 2.5 {micro}m) and nickel sulfide, NixSy in PM{sub 2.5+} (PM > 2.5 {micro}m). The Ni K-edge XANES results are in agreement with the EXAFS data. Such detailed speciation of Ni and S in PM is needed for determining their mobility, bioavailability, and reactivity, and hence, their role in PM toxicity. This information is also important for understanding the mechanism of PM formation, developing effective remediation measures, and providing criteria for identification of potential emission sources. Transition metals complexing with sulfur is ubiquitous in nature. Therefore, this information on metal sulfur complex can be critical to a large body of environmental literature.

  2. A high-efficiency indirect lighting system utilizing the solar 1000 sulfur lamp

    SciTech Connect (OSTI)

    Siminovitch, M.; Gould, C.; Page, E.

    1997-06-01T23:59:59.000Z

    High-lumen light sources represent unique challenges and opportunities for the design of practical and efficient interior lighting systems. High-output sources require a means of large-scale distribution and avoidance of high-luminance glare while providing efficient delivery. An indirect lighting system has been developed for use with a 1,000 Watt sulfur lamp that efficiently utilizes the high-output source to provide quality interior lighting. This paper briefly describes the design and initial testing of this new system.

  3. The effect of sulfate sulfur on the yield and chemical composition of oats, vetch, and turnips

    E-Print Network [OSTI]

    Gipson, Jack Rogers

    1959-01-01T23:59:59.000Z

    agricultural Chemists (28) . Table g. Planting and harvesting dates. o ation ro Planti date arvestin ate Tyler Oats Vetch Greene Ootober il, 1957 October 11, 1957 October 11 1 7 april 19, 1958 May 7, 1958 Not harvested Oats Nacogdoohes Vetch... of sulfur ratea upon tbe production of forage oata at Kirbywille. 3850 3500 3150 2800 2450 1750 4 8 +00 350 Figure g. Effect of looation on ths produotiea of forage oats (average of all 5 treatments). s 1 = Tyler, 2 = Maoogdoohes, 3 = Q...

  4. ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    Robert S. Weber

    1999-05-01T23:59:59.000Z

    Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

  5. Tellurium-Containing Conjugated Materials for Solar Cells: From Sulfur to Tellurium

    SciTech Connect (OSTI)

    Park Y. S.; Kale, T.; Wu, Q.; Ocko, B.M.; Black, C.T., Grubbs, R.B.

    2013-04-03T23:59:59.000Z

    A series of diketopyrrolopyrrole(DPP)-based small molecules have been synthesized by palladium-catalyzed coupling reactions. Electron-donating moieties (benzothiophene, benzoselenophene, and benzotellurophene) are bridged by an electron-withdrawing DPP unit to generate donor-acceptor-donor (D-A-D) type molecules. We observe red-shifts in absorption spectra of these compounds by varying heteroatoms from sulfur to tellurium. In bulk heterojunction solar cells with [6,6]phenyl-C61-butyric acid methyl ester (PC61BM) as acceptor, we obtain power conversion efficiencies of 2.4% (benzothiophene), 4.1% (benzoselenophene), and 3.0% (benzotellurophene), respectively.

  6. Method to improve lubricity of low-sulfur diesel and gasoline fuels

    DOE Patents [OSTI]

    Erdemir, Ali

    2004-08-31T23:59:59.000Z

    A method for providing lubricity in fuels and lubricants includes adding a boron compound to a fuel or lubricant to provide a boron-containing fuel or lubricant. The fuel or lubricant may contain a boron compound at a concentration between about 30 ppm and about 3,000 ppm and a sulfur concentration of less than about 500 ppm. A method of powering an engine to minimize wear, by burning a fuel containing boron compounds. The boron compounds include compound that provide boric acid and/or BO.sub.3 ions or monomers to the fuel or lubricant.

  7. Nonadiabatic calculations of ultraviolet absorption cross section of sulfur monoxide: Isotopic effects on the photodissociation reaction

    SciTech Connect (OSTI)

    Danielache, Sebastian O.; Tomoya, Suzuki; Nanbu, Shinkoh [Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University, Chiyoda Ku, Tokyo 102-8554 (Japan)] [Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University, Chiyoda Ku, Tokyo 102-8554 (Japan); Kondorsky, Alexey [P. N. Lebedev Physical Institute of Russian Academy of Science, Leninsky pr., 53, Moscow, 119991 (Russian Federation) [P. N. Lebedev Physical Institute of Russian Academy of Science, Leninsky pr., 53, Moscow, 119991 (Russian Federation); Moscow Institute of Physics and Technology (State University), Institutsky per., 9, Dolgoprudny Moscow region, 141700 (Russian Federation); Tokue, Ikuo [Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181 (Japan)] [Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181 (Japan)

    2014-01-28T23:59:59.000Z

    Ultraviolet absorption cross sections of the main and substituted sulfur monoxide (SO) isotopologues were calculated using R-Matrix expansion technique. Energies, transition dipole moments, and nonadiabatic coupling matrix elements were calculated at MRCI/AV6Z level. The calculated absorption cross section of {sup 32}S{sup 16}O was compared with experimental spectrum; the spectral feature and the absolute value of photoabsorption cross sections are in good agreement. Our calculation predicts a long lived photoexcited SO* species which causes large non-mass dependent isotopic effects depending on the excitation energy in the ultraviolet region.

  8. Gasoline from natural gas by sulfur processing. Final technical report, June 1993--July 1996

    SciTech Connect (OSTI)

    Erekson, E.J.

    1996-07-01T23:59:59.000Z

    The overall objective of this research project was to develop a catalytic process to convert natural gas to liquid transportation fuels. The process, called the HSM (Hydrogen Sulfide-Methane) Process, consists of two steps that each use catalysts and sulfur-containing intermediates: (1) to convert natural gas to CS{sub 2} and (2) to convert CS{sub 2} to gasoline-range liquids. Experimental data generated in this project were for use in evaluating the commercial potential of the process.

  9. The influence of flowable sulfur on controlled-release of NPK fertilizers

    E-Print Network [OSTI]

    Tammakrut, Somkid

    1983-01-01T23:59:59.000Z

    were determined in the laboratory. Wheat plants were grown in the greenhouse to investigate N and P availability in acid and limed Lufkin soil from the urea and DAP products as well as the effect of S in a rock phosphate sulfur suspension (RP... Page Dry matter yield of wheat plant from two harvests as affected by TSP and DAP fer- tilizers incubated in acid or limed soil 6 weeks before planting. (Bars within an array having the same letters are not significantly different at P = . 05...

  10. Electrochemical deposition of copper on a gold electrode in sulfuric acid: resolution of the interfacial structure

    SciTech Connect (OSTI)

    Toney, M.F.; Howard, J.N.; Richer, J.; Borges, G.L.; Gordon, J.G.; Melroy, O.R. [IBM Research Division, Almaden Research Center, San Jose, California 95120 (United States)] [IBM Research Division, Almaden Research Center, San Jose, California 95120 (United States); Yee, D.; Sorensen, L.B. [Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States)] [Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States)

    1995-12-01T23:59:59.000Z

    The structure of electrochemically deposited submonolayer Cu on Au(111) in sulfuric acid has been extensively investigated but is still poorly known. We report an x-ray scattering determination of this structure that explains existing data. The Cu adatoms form a honeycomb lattice and are adsorbed on threefold hollow sites, while sulfate anions occupy the honeycomb centers. Three oxygens of each sulfate bond to Cu atoms. This stabilizes the structure and illustrates that anion effects can be important in electrodeposited structures. Our results indicate that previous scanning tunneling and atomic force microscopy measurements imaged the sulfate molecules not the Cu atoms. {copyright} {ital 1995 The American Physical Society.}

  11. Sulfur Iodine Process Summary for the Hydrogen Technology Down-Selection: Process Performance Package

    SciTech Connect (OSTI)

    Benjamin Russ

    2009-06-01T23:59:59.000Z

    This document describes the details of implementing a Sulfur-Iodine (S-I) hydrogen production plant to deploy with the Next General Nuclear Power Plant (NGNP). Technical requirements and specifications are included, and a conceptual plant design is presented. The following areas of interest are outlined in particular as a baseline for the various technology comparisons: (1) Performance Criteria - (a) Quantity of hydrogen produced, (b) Purity of hydrogen produced, (c) Flexibility to serve various applications, (d) Waste management; (2) Economic Considerations - (a) Cost of hydrogen, (b) Development costs; and (3) Risk - (a) Technical maturity of the S-I process, (b) Development risk, (c) Scale up options.

  12. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),Energy PetroleumEnergy Lube-oil Phosphorus on DieselFuelSulfur

  13. Nitrogen and Sulfur Requirements for Clostridium thermocellum and Caldicellulosiruptor bescii on Cellulosic Substrates in Minimal Nutrient Media

    SciTech Connect (OSTI)

    Kridelbaugh, Donna M [ORNL; Nelson, Josh C [ORNL; Engle, Nancy L [ORNL; Tschaplinski, Timothy J [ORNL; Graham, David E [ORNL

    2013-01-01T23:59:59.000Z

    Growth media for cellulolytic Clostridium thermocellum and Caldicellulosiruptor bescii bacteria usually contain excess nutrients that would increase costs for consolidated bioprocessing for biofuel production and create a waste stream with nitrogen, sulfur and phosphate. C. thermocellum was grown on crystalline cellulose with varying concentrations of nitrogen and sulfur compounds, and growth rate and alcohol production response curves were determined. Both bacteria assimilated sulfate in the presence of ascorbate reductant, increasing the ratio of oxidized to reduced fermentation products. From these results, a low ionic strength, defined minimal nutrient medium with decreased nitrogen, sulfur, phosphate and vitamin supplements was developed for the fermentation of cellobiose, cellulose and acid-pretreated Populus. Carbon and electron balance calculations indicate the unidentified residual fermentation products must include highly reduced molecules. Both bacterial populations were maintained in co-cultures with substrates containing xylan or hemicellulose in defined medium with sulfate and basal vitamin supplements.

  14. Sulfur K-edge X-ray absorption spectroscopy as an experimental probe for S-nitroso proteins

    SciTech Connect (OSTI)

    Szilagyi, Robert K. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)]. E-mail: Szilagyi@Montana.EDU; Schwab, David E. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)

    2005-04-29T23:59:59.000Z

    X-ray absorption spectroscopy at the sulfur K-edge (2.4-2.6 keV) provides a sensitive and specific technique to identify S-nitroso compounds, which have significance in nitric oxide-based cell signaling. Unique spectral features clearly distinguish the S-nitroso-form of a cysteine residue from the sulfhydryl-form or from a methionine thioether. Comparison of the sulfur K-edge spectra of thiolate, thiol, thioether, and S-nitroso thiolate compounds indicates high sensitivity of energy positions and intensities of XAS pre-edge features as determined by the electronic environment of the sulfur absorber. A new experimental setup is being developed for reaching the in vivo concentration range of S-nitroso thiol levels in biological samples.

  15. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Technical report, September 1--November 31, 1991

    SciTech Connect (OSTI)

    Chou, C.L.

    1991-12-31T23:59:59.000Z

    The purpose of this project is to conduct laboratory experiments to clarify the mechanism of boiler corrosion, which may lead to solving the corrosion problem associated with the utilization of Illinois` high-sulfur and high-chlorine coal. The kinetics of the release of sulfur and chlorine species during coal combustion is being determined in the laboratories using temperature-programmed pyrolysis coupled with quadrupole gas analysis (QGA) and thermogravimetric analysis in conjunction with Fourier transform infrared spectroscopy (FTIR). Samples of boiler deposits and ashes from different locations in boilers using Illinois coal will be analyzed for mineralogical and chemical compositions to understand the relations among deposit compositions, coal compositions, and the gaseous species in combustion gases. The relationship between the level of chlorine in Illinois coal and boiler corrosion will be studied by experiments with simulated combustion gases under combustion conditions. Reduction of sulfur and chloride concentrations in the flue gas using additives will also be evaluated.

  16. Lewis Acid-Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Tian, Jian; Wu, Dangxin; Gu, Meng; Xu, Wu; Wang, Chong M.; Gao, Fei; Engelhard, Mark H.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-04-04T23:59:59.000Z

    Lithium-sulfur (Li-S) battery is one of the most promising energy storage systems because of its high specific capacity of 1675 mAh g-1 based on sulfur. However, the rapid capacity degradation, mainly caused by polysulfide dissolution, remains a significant challenge prior to practical applications. Here, we report a novel Ni-based metal organic framework (Ni-MOF), Ni6(BTB)4(BP)3 (BTB = benzene-1,3,5-tribenzoate and BP = 4,4?-bipridyl), that can remarkably immobilize polysulfides within the cathode structure through physical and chemical interactions at the molecular level. The capacity retention achieves up to 89% after 100 cycles at 0.1 C. The interwoven mesopores (~2.8 nm) and micropores (~1.4 nm) of Ni-MOF firstly provide an ideal matrix to confine polysulfides. Additionally, the strong interactions between Lewis acidic Ni(II) center and the polysulfides base significantly slow down the migration of soluble polysulfides out of the pores, which leads to the excellent cycling performance of Ni-MOF/S composite.

  17. Cathodic reduction of sulfur dioxide in nonaqueous electrolytes. polarization curves at porous Electrodes

    SciTech Connect (OSTI)

    Shembel, E.M.; Danilova, N.P.; Ksenzhek, O.S.

    1986-03-01T23:59:59.000Z

    This paper describes some results obtained from studying the poloarization characteristics of cathodic sulfur dioxide reduction at porous electrodes made by applying a mixture of carbon black, graphite, and binder to a metal screen serving as current collector. Solutions of lithium perchlorate in propylene carbonate and in a mixture of propylene carbonate and acetonitrile were used as the electrolytes. Some typical galvanostatic discharge curves are shown for sulfur dioxide reduction at porous electrodes. The discharge capacity increases with increasing electrode porosity and decreasing current density. One can see when comparing the curves that the discharge capacities differ substantially for highly porous electrodes which had practically the same porosity of about 70%. The effect of current density is more important in solutions with a high SO/sub 2/ concentration. The operating efficiency of porous electrodes which serve as cathodes in high power Li-SO/sub 2/ power sources can be predicted on the basis of polorization curves for the porous electrodes which reflect the influence of macrostructure on the cathodic process.

  18. 2008 GRC Iron Sulfur Enzymes-Conference to be held June 8-13, 2008

    SciTech Connect (OSTI)

    Stephen Cramer, Nancy Ryan Gray

    2009-01-01T23:59:59.000Z

    Iron-sulfur proteins are among the most common and ancient enzymes and electron-transfer agents in nature. They play key roles in photosynthesis, respiration, and the metabolism of small molecules such as H2, CO, and N2. The Iron Sulfur Enzyme Gordon Research Conference evolved from an earlier GRC on Nitrogen Fixation that began in 1994. The scope of the current meeting has broadened to include all enzymes or metalloproteins in which Fe-S bonds play a key role. This year's meeting will focus on the biosynthesis of Fe-S clusters, as well as the structure and mechanism of key Fe-S enzymes such as hydrogenase, nitrogenase and its homologues, radical SAM enzymes, and aconitase-related enzymes. Recent progress on the role of Fe-S enzymes in health, disease, DNA/RNA-processing, and alternative bio-energy systems will also be highlighted. This conference will assemble a broad, diverse, and international group of biologists and chemists who are investigating fundamental issues related to Fe-S enzymes, on atomic, molecular, organism, and environmental scales. The topics to be addressed will include: Biosynthesis & Genomics of Fe-S Enzymes; Fundamental Fe-S Chemistry; Hydrogen and Fe-S Enzymes; Nitrogenase & Homologous Fe-S Enzymes; Fe-S Enzymes in Health & Disease; Radical SAM and Aconitase-Related Fe-S Enzymes; Fe-S Enzymes and Synthetic Analogues in BioEnergy; and Fe-S Enzymes in Geochemistry and the Origin of Life.

  19. Non-LTE Abundances of Magnesium, Aluminum and Sulfur in OB Stars Near the Solar Circle

    E-Print Network [OSTI]

    S. Daflon; K. Cunha; V. V. Smith; K. Butler

    2002-12-09T23:59:59.000Z

    Non-LTE abundances of magnesium, aluminum and sulfur are derived for a sample of 23 low-v \\sin i stars belonging to six northern OB associations of the Galactic disk within 1 kpc of the Sun. The abundances are obtained from the fitting of synthetic line profiles to high resolution spectra. A comparison of our results with HII region abundances indicates good agreement for sulfur while the cepheid abundances are higher. The derived abundances of Mg show good overlap with the cepheid results. The aluminum abundances for OB stars are significantly below the cepheid values. But, the OB star results show a dependence with effective temperature and need further investigation. The high Al abundances in the cepheids could be the result of mixing. A discussion of the oxygen abundance in objects near the solar circle suggests that the current mean galactic oxygen abundance in this region is 8.6-8.7 and in agreement with the recently revised oxygen abundance in the solar photosphere. Meaningful comparisons of the absolute S, Al and Mg abundances in OB stars with the Sun must await a reinvestigation of these elements, as well as the meteoritic reference element Si, with 3D hydrodynamical model atmospheres for the Sun. No abundance gradients are found within the limited range in galactocentric distances in the present study. Such variations would be expected only if there were large metallicity gradients in the disk.

  20. Radiative charge transfer in cold and ultracold Sulfur atoms colliding with Protons

    E-Print Network [OSTI]

    G Shen; P C Stancil; J G Wang; J F McCann; B M McLaughlin

    2015-02-25T23:59:59.000Z

    Radiative decay processes at cold and ultra cold temperatures for Sulfur atoms colliding with protons are investigated. The MOLPRO quantum chemistry suite of codes was used to obtain accurate potential energies and transition dipole moments, as a function of internuclear distance, between low-lying states of the SH$^{+}$ molecular cation. A multi-reference configuration-interaction (MRCI) approximation together with the Davidson correction is used to determine the potential energy curves and transition dipole moments, between the states of interest, where the molecular orbitals (MO's) are obtained from state-averaged multi configuration-self-consistent field (MCSCF) calculations. The collision problem is solved approximately using an optical potential method to obtain radiative loss, and a fully two-channel quantum approach for radiative charge transfer. Cross sections and rate coefficients are determined for the first time for temperatures ranging from 10 $\\mu$ K up to 10,000 K. Results are obtained for all isotopes of Sulfur, colliding with H$^{+}$ and D$^{+}$ ions and comparison is made to a number of other collision systems.

  1. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures

    SciTech Connect (OSTI)

    Huang, Cheng; Xiao, Jie; Shao, Yuyan; Zheng, Jianming; Bennett, Wendy D.; Lu, Dongping; Saraf, Laxmikant V.; Engelhard, Mark H.; Ji, Liwen; Zhang, Jiguang; Li, Xiaolin; Graff, Gordon L.; Liu, Jun

    2014-01-09T23:59:59.000Z

    Lithium-sulfur (Li-S) batteries have recently attracted extensive attention due to the high theoretical energy density and potential low cost. Even so, significant challenges prevent widespread adoption, including continuous dissolution and consumption of active sulfur during cycling. Here we present a fundamentally new design using electrically connected graphite and lithium metal as a hybrid anode to control undesirable surface reactions on the anode. The lithiated graphite placed in front of the lithium metal functions as an artificial self-regulated solid electrolyte interface (SEI) layer to actively control the electrochemical reaction while minimizing the deleterious side reactions on the surface and bulk lithium metal. Continuous corrosion and contamination of lithium anode by dissolved polysulfides is largely mitigated. Excellent electrochemical performance has been observed. Li-S cell incorporating the hybrid design retain a capacity of more than 800 mAh g-1 for 400 cycles, corresponding to only 11% fade and a Coulombic efficiency above 99%. This simple hybrid concept may also provide new lessons for protecting metal anodes in other energy storage devices.

  2. Sulfur-Modified Zero-Valent Iron for Remediation Applications at DOE Sites - 13600

    SciTech Connect (OSTI)

    Fogwell, Thomas W. [Fogwell Consulting, P.O. Box 20221, Piedmont, CA 94620 (United States)] [Fogwell Consulting, P.O. Box 20221, Piedmont, CA 94620 (United States); Santina, Pete [SMI-PS, Inc., 2073 Prado Vista, Lincoln, CA 95648 (United States)] [SMI-PS, Inc., 2073 Prado Vista, Lincoln, CA 95648 (United States)

    2013-07-01T23:59:59.000Z

    Many DOE remediation sites have chemicals of concern that are compounds in higher oxidation states, which make them both more mobile and more toxic. The chemical reduction of these compounds both prevents the migration of these chemicals and in some cases reduces the toxicity. It has also been shown that zero-valent iron is a very effective substance to use in reducing oxygenated compounds in various treatment processes. These have included the treatment of halogenated hydrocarbons in the form volatile organic compounds used as solvents and pesticides. Zero-valent iron has also been used to reduce various oxidized metals such as chromium, arsenic, and mercury in order to immobilize them, decrease their toxicity, and prevent further transport. In addition, it has been used to immobilize or break down other non-metallic species such as selenium compounds and nitrates. Of particular interest at several DOE remediation sites is the fact that zero-valent iron is very effective in immobilizing several radioactive metals which are mobile in their oxidized states. These include both technetium and uranium. The main difficulty in using zero-valent iron has been its tendency to become inactive after relatively short periods of time. While it is advantageous to have the zero-valent iron particles as porous as possible in order to provide maximum surface area for reactions to take place, these pores can become clogged when the iron is oxidized. This is due to the fact that ferric oxide has a greater volume for a given mass than metallic iron. When the surfaces of the iron particles oxidize to ferric oxide, the pores become narrower and will eventually shut. In order to minimize the degradation of the chemical activity of the iron due to this process, a modification of zero-valent iron has been developed which prevents or slows this process, which decreases its effectiveness. It is called sulfur-modified iron, and it has been produced in high purity for applications in municipal water treatment applications. Sulfur-modified iron has been found to not only be an extremely economical treatment technology for municipal water supplies, where very large quantities of water must be treated economically, but it has also been demonstrated to immobilize technetium. It has the added benefit of eliminating several other harmful chemicals in water supplies. These include arsenic and selenium. In one large-scale evaluation study an integrated system implemented chemical reduction of nitrate with sulfur-modified iron followed by filtration for arsenic removal. The sulfur-modified iron that was used was an iron-based granular medium that has been commercially developed for the removal of nitrate, co-contaminants including uranium, vanadium and chromium, and other compounds from water. The independent study concluded that 'It is foreseen that the greatest benefit of this technology (sulfur-modified iron) is that it does not produce a costly brine stream as do the currently accepted nitrate removal technologies of ion exchange and reverse osmosis. This investigation confirmed that nitrate reduction via sulfur-modified iron is independent of the hydraulic loading rate. Future sulfur-modified iron treatment systems can be designed without restriction of the reactor vessel dimensions. Future vessels can be adapted to existing site constraints without being limited to height-to-width ratios that would exist if nitrate reduction were to depend on hydraulic loading rate'. Sulfur-modified iron was studied by the Pacific Northwest National Laboratory (PNNL) for its effectiveness in the reduction and permanent sequestration of technetium. The testing was done using Hanford Site groundwater together with sediment. The report stated, 'Under reducing conditions, TcO{sub 4} is readily reduced to TcIV, which forms highly insoluble oxides such at TcO{sub 2}.nH{sub 2}O. However, (re)oxidation of TcIV oxides can lead to remobilization. Under sulfidogenic conditions, most TcIV will be reduced and immobilized as Tc{sub 2}S{sub 7}, which is less readily re-mobilized, ev

  3. Excess carrier generation in femtosecond-laser processed sulfur doped silicon by means of sub-bandgap illumination

    SciTech Connect (OSTI)

    Guenther, Kay-Michael, E-mail: kay-michael.guenther@efzn.de [Clausthal University of Technology, EFZN, Am Stollen 19B, 38640 Goslar (Germany); Gimpel, Thomas; Ruibys, Augustinas; Kontermann, Stefan [Fraunhofer Heinrich Hertz Institute, Am Stollen 19B, 38640 Goslar (Germany); Tomm, Jens W. [Max Born Institut, Max-Born-Straße 2A, 12489 Berlin (Germany); Winter, Stefan [Physikalisch-Technische Bundesanstalt, Bundesallee 100, 38116 Braunschweig (Germany); Schade, Wolfgang [Clausthal University of Technology, EFZN, Am Stollen 19B, 38640 Goslar (Germany); Fraunhofer Heinrich Hertz Institute, Am Stollen 19B, 38640 Goslar (Germany)

    2014-01-27T23:59:59.000Z

    With Fourier-transform photocurrent spectroscopy and spectral response measurements, we show that silicon doped with sulfur by femtosecond laser irradiation generates excess carriers, when illuminated with infrared light above 1100?nm. Three distinct sub-bandgap photocurrent features are observed. Their onset energies are in good agreement with the known sulfur levels S{sup +}, S{sup 0}, and S{sub 2}{sup 0}. The excess carriers are separated by a pn-junction to form a significant photocurrent. Therefore, this material likely demonstrates the impurity band photovoltaic effect.

  4. Weighted power counting and chiral dimensional regularization

    E-Print Network [OSTI]

    Damiano Anselmi

    2014-06-27T23:59:59.000Z

    We define a modified dimensional-regularization technique that overcomes several difficulties of the ordinary technique, and is specially designed to work efficiently in chiral and parity violating quantum field theories, in arbitrary dimensions greater than 2. When the dimension of spacetime is continued to complex values, spinors, vectors and tensors keep the components they have in the physical dimension, therefore the $\\gamma $ matrices are the standard ones. Propagators are regularized with the help of evanescent higher-derivative kinetic terms, which are of the Majorana type in the case of chiral fermions. If the new terms are organized in a clever way, weighted power counting provides an efficient control on the renormalization of the theory, and allows us to show that the resulting chiral dimensional regularization is consistent to all orders. The new technique considerably simplifies the proofs of properties that hold to all orders, and makes them suitable to be generalized to wider classes of models. Typical examples are the renormalizability of chiral gauge theories and the Adler-Bardeen theorem. The difficulty of explicit computations, on the other hand, may increase.

  5. doi:10.1016/j.gca.2005.04.017 A model for oxygen and sulfur isotope fractionation in sulfate during bacterial sulfate

    E-Print Network [OSTI]

    Gilli, Adrian

    describing the fraction- ation relationship between the sulfur and the oxygen isotope composition of residual sulfate ( 34 SSO4_residual, 18 OSO4_residual) and the amount of residual sulfate. The model is based exclusively on oxygen isotope exchange between cell-internal sulfur compounds and ambient water

  6. Weight Distribution of a Class of Binary Linear Block Codes Formed from RCPC Codes

    E-Print Network [OSTI]

    Shen, Yushi Dr.; Cosman, Pamela C; Milstein, Laurence B

    2006-01-01T23:59:59.000Z

    On the weight distribution of terminated convolutionalViterbi, “On the weight distribution of linear block codes9, SEPTEMBER 2005 Weight Distribution of a Class of Binary

  7. 2-D weighted least-squares phase unwrapping

    DOE Patents [OSTI]

    Ghiglia, Dennis C. (Placitas, NM); Romero, Louis A. (Albuquerque, NM)

    1995-01-01T23:59:59.000Z

    Weighted values of interferometric signals are unwrapped by determining the least squares solution of phase unwrapping for unweighted values of the interferometric signals; and then determining the least squares solution of phase unwrapping for weighted values of the interferometric signals by preconditioned conjugate gradient methods using the unweighted solutions as preconditioning values. An output is provided that is representative of the least squares solution of phase unwrapping for weighted values of the interferometric signals.

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Idle Reduction Weight Exemption A vehicle equipped with qualified idle reduction technology may exceed the state's gross weight and axle weight limits by up to 400 pounds to...

  9. affects body weight: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    weight perceptions may be influ- enced by food habits and food environments, nutritional knowledge, cultural norms and expectations and mass media Mikolajczyk, Rafael T; Maxwell,...

  10. FORCE RECONSTRUCTION USING THE SUM OF WEIGHTED ACCELERATIONS

    Office of Scientific and Technical Information (OSTI)

    coordinates. This methodof determiningthe SWAT weights would Now recall the definition of the SWAT dof, equation be equivalentto inverting the mode-shape matrix to...

  11. Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture

    E-Print Network [OSTI]

    Litster, Shawn

    Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture Nicholas S. Siefert Virginia 26507, United States ABSTRACT: We present experimental results of coal gasification. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect

  12. KINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    clarified the role of aqueous-phase production of strong acids in the atmosphere. Oxidation of dissolvedKINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ) are the precursors of the strong acids (i.e., HzS04 and HN03) found in precipitation,! the detailed mechanisms

  13. High precision analysis of all four stable isotopes of sulfur S) at nanomole levels using a laser fluorination

    E-Print Network [OSTI]

    Long, Bernard

    compositions. This methodology increases the spatial resolution of the laser ablation in situ analysis) at nanomole levels using a laser fluorination isotope-ratio-monitoring gas chromatography­mass spectrometry.V. All rights reserved. Keywords: S-33; S-36; Sulfur isotope; Laser; Isotope analysis; Continuous flow

  14. Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost and equipment

    E-Print Network [OSTI]

    by switching to LNG instead of continuing to burn low-sulfur fuel oil and installing new emission controls that stands to benefit if regulators approve LNG shipments to the state. "Beyond payment for this study, FGE will receive no compensation whatsoever whether the state decides to import LNG or not, and no matter under

  15. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Saltzman, Eric

    , and sulfur gases from Greenland ice cores M. Aydin,1 M. B. Williams,1 and E. S. Saltzman1 Received 7-lived atmospheric trace gases were measured in 25 ice core samples from Summit, Greenland. Samples were selected. The CH3Br results are consistent with previous observations of ``excess'' CH3Br in Greenland firn air

  16. Direct Sulfonation of Methane to Methanesulfonic Acid by Sulfur Trioxide Catalyzed by Cerium(IV) Sulfate in the Presence

    E-Print Network [OSTI]

    Bell, Alexis T.

    , methane did not undergo sulfonation to MSA.[4] Hg-based catalysts have been used at elevated temperatureDirect Sulfonation of Methane to Methanesulfonic Acid by Sulfur Trioxide Catalyzed by Cerium(IV) Sulfate in the Presence of Molecular Oxygen Sudip Mukhopadhyay, Alexis T. Bell* Department of Chemical

  17. Enhanced Intersystem Crossing Rate in Polymethine-Like Molecules: Sulfur-Containing Squaraines versus Oxygen-Containing Analogues

    E-Print Network [OSTI]

    Van Stryland, Eric

    characterization includes absorption, fluorescence, quantum yield, anisotropy, and singlet oxygen generation versus Oxygen-Containing Analogues Davorin Peceli, Honghua Hu, Dmitry A. Fishman, Scott Webster, Olga V of new squaraine molecules, where one or two oxygen atoms in a squaraine bridge are replaced with sulfur

  18. Sulfur distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    by the thermal cracking process of the El-Lujjan oil shale showed that the yield of oil was around 12 wt of the boiling point for different distillate fractions. Sulfur in Jordanian oil shale was found to be mainly the dominant phases in these fractions. q 2005 Published by Elsevier Ltd. 1. Introduction Oil shale

  19. Dating groundwater with trifluoromethyl sulfurpentafluoride (SF5CF3), sulfur hexafluoride (SF6), CF3Cl (CFC-13),

    E-Print Network [OSTI]

    Dating groundwater with trifluoromethyl sulfurpentafluoride (SF5CF3), sulfur hexafluoride (SF6), CF; revised 3 October 2007; accepted 30 October 2007; published 22 February 2008. [1] A new groundwater dating and water samples. SF5CF3 and CFC-13 can be used to date groundwaters in some environments where the CFCs

  20. High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances

    SciTech Connect (OSTI)

    K. Coulter

    2010-12-31T23:59:59.000Z

    The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

  1. RELY: A reliability modeling system for analysis of sodium-sulfur battery configurations

    SciTech Connect (OSTI)

    Hostick, C.J.; Huber, H.D.; Doggett, W.H.; Dirks, J.A.; Dovey, J.F.; Grinde, R.B.; Littlefield, J.S.; Cuta, F.M.

    1987-06-01T23:59:59.000Z

    In support of the Office of Energy Storage and Distribution of the US Department of Energy (DOE), Pacific Northwest Laboratory has produced a microcomputer-based software package, called RELY, to assess the impact of sodium-sulfur cell reliability on constant current discharge battery performance. The Fortran-based software operates on IBM microcomputers and IBM-compatibles that have a minimum of 512K of internal memory. The software package has three models that provide the following: (1) a description of the failure distribution parameters used to model cell failure, (2) a Monte Carlo simulation of battery life, and (3) a detailed discharge model for a user-specified battery discharge cycle. 6 refs., 31 figs., 4 tabs.

  2. Manufacture of silicon-based devices having disordered sulfur-doped surface layers

    DOE Patents [OSTI]

    Carey, III; James Edward (Newton, MA); Mazur, Eric (Concord, MA)

    2008-04-08T23:59:59.000Z

    The present invention provides methods of fabricating a radiation-absorbing semiconductor wafer by irradiating at least one surface location of a silicon substrate, e.g., an n-doped crystalline silicon, by a plurality of temporally short laser pulses, e.g., femtosecond pulses, while exposing that location to a substance, e.g., SF.sub.6, having an electron-donating constituent so as to generate a substantially disordered surface layer (i.e., a microstructured layer) that incorporates a concentration of that electron-donating constituent, e.g., sulfur. The substrate is also annealed at an elevated temperature and for a duration selected to enhance the charge carrier density in the surface layer. For example, the substrate can be annealed at a temperature in a range of about 700 K to about 900 K.

  3. Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases

    SciTech Connect (OSTI)

    Laufhutte, D.

    1985-04-30T23:59:59.000Z

    Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

  4. Failure of man-made cavities in salt and surface subsidence due to sulfur mining

    SciTech Connect (OSTI)

    Coates, G.K.; Lee, C.A.; McClain, W.C.; Senseny, P.E.

    1981-01-01T23:59:59.000Z

    An engineering data base relevant to subsidence due to sulfur mining and to structural failure of cavities in salt is established, evaluated and documented. Nineteen failure events are discussed. Based on these documented failure events, capabilities of and inputs to a mathematical model of cavity failure are determined. Two failure events are adequately documented for use in model verification studies. A conclusion of this study that is pertinent to the Strategic Petroleum Reserve is that cavity failures in dome salt are fairly rare, but that as the number of large cavities (especially those having large roof spans) increases, failures will probably be more common unless stability and failure mechanisms of cavities are better understood.

  5. Separation of sulfur and trace elements from high-viscosity petroleums and tar sands

    SciTech Connect (OSTI)

    Nadirov, N.K.; Bychkova, L.V.; Rudenko, N.V.; Dzhakupova, A.N.; Sarsembaeva, B.K.

    1992-07-10T23:59:59.000Z

    Characteristic features of high-viscosity petroleums and tar sands of western Kazakhstan are a great chemical nonuniformity, a diverse combination of proportions of aromatic and heteroatomic structures, and a wide variation in trace-element composition. They contain, moreover, large quantities of aliphatic ethers and esters, sulfo acids, cyclic hydrocarbons, and other valuable components that may be used in the chemical, petrochemical, and other industries. The authors study employed acetylacetone or propanol for organic solvent extraction of a sulfurous concentrate, magnifying the selective separation of organosulfur compounds with the use of ultrasonic phase stratification. Oxidation of organosulfur compounds to sulfoxides, sulfones, and sulfo acids was accomplished with ionizing radiation from Co{sup 60}. 17 refs., 2 tabs.

  6. EFFECT OF ELECTROLYZER CONFIGURATION AND PERFORMANCE ON HYBRID SULFUR PROCESS NET THERMAL EFFICIENCY

    SciTech Connect (OSTI)

    Gorensek, M

    2007-03-16T23:59:59.000Z

    Hybrid Sulfur cycle is gaining popularity as a possible means for massive production of hydrogen from nuclear energy. Several different ways of carrying out the SO{sub 2}-depolarized electrolysis step are being pursued by a number of researchers. These alternatives are evaluated with complete flowsheet simulations and on a common design basis using Aspen Plus{trademark}. Sensitivity analyses are performed to assess the performance potential of each configuration, and the flowsheets are optimized for energy recovery. Net thermal efficiencies are calculated for the best set of operating conditions for each flowsheet and the results compared. This will help focus attention on the most promising electrolysis alternatives. The sensitivity analyses should also help identify those features that offer the greatest potential for improvement.

  7. Electric Power Research Institute, High-Sulfur Test Center report to the Steering Committee, July 1991

    SciTech Connect (OSTI)

    Not Available

    1991-12-31T23:59:59.000Z

    Operation and testing continued this month at the High Sulfur Test Center on the Pilot Wet Scrubber, Mini-Pilot Wet Scrubber and the Spray Dryer Systems. The Pilot continued testing under the High Performance test block program and the Mini-Pilot continued testing under the Formate Forced Oxidation test block. The HSSD testing to investigate the effects that ambient temperature and humidity have on SO{sub 2} removal was completed. Dry alkaline injection testing was started to remove SO{sub 3} and HCl from flue gas which removes visible plumes. Construction upgrades and system shakedown continued on the Cold-Side Selective Catalytic Reduction (SCR) system in preparation for start-up. (VC)

  8. Electric Power Research Institute, High-Sulfur Test Center report to the Steering Committee, July 1991

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    Operation and testing continued this month at the High Sulfur Test Center on the Pilot Wet Scrubber, Mini-Pilot Wet Scrubber and the Spray Dryer Systems. The Pilot continued testing under the High Performance test block program and the Mini-Pilot continued testing under the Formate Forced Oxidation test block. The HSSD testing to investigate the effects that ambient temperature and humidity have on SO{sub 2} removal was completed. Dry alkaline injection testing was started to remove SO{sub 3} and HCl from flue gas which removes visible plumes. Construction upgrades and system shakedown continued on the Cold-Side Selective Catalytic Reduction (SCR) system in preparation for start-up. (VC)

  9. Radiative charge transfer in cold and ultracold Sulfur atoms colliding with Protons

    E-Print Network [OSTI]

    Shen, G; Wang, J G; McCann, J F; McLaughlin, B M

    2015-01-01T23:59:59.000Z

    Radiative decay processes at cold and ultra cold temperatures for Sulfur atoms colliding with protons are investigated. The MOLPRO quantum chemistry suite of codes was used to obtain accurate potential energies and transition dipole moments, as a function of internuclear distance, between low-lying states of the SH$^{+}$ molecular cation. A multi-reference configuration-interaction (MRCI) approximation together with the Davidson correction is used to determine the potential energy curves and transition dipole moments, between the states of interest, where the molecular orbitals (MO's) are obtained from state-averaged multi configuration-self-consistent field (MCSCF) calculations. The collision problem is solved approximately using an optical potential method to obtain radiative loss, and a fully two-channel quantum approach for radiative charge transfer. Cross sections and rate coefficients are determined for the first time for temperatures ranging from 10 $\\mu$ K up to 10,000 K. Results are obtained for all ...

  10. Ultraviolet photosensitivity of sulfur-doped micro- and nano-crystalline diamond

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mendoza, Frank; Makarov, Vladimir; Hidalgo, Arturo; Weiner, Brad; Morell, Gerardo

    2011-06-06T23:59:59.000Z

    The room-temperature photosensitivity of sulfur-doped micro- (MCD), submicro- (SMCD) and nano- (NCD) crystalline diamond films synthesized by hot-filament chemical vapor deposition was studied. The structure and composition of these diamond materials were characterized by Raman spectroscopy, scanning electron microscopy and X-ray diffraction. The UV sensitivity and response time were studied for the three types of diamond materials using a steady state broad UV excitation source and two pulsed UV laser radiations. It was found that they have high sensitivity in the UV region, as high as 109 sec-1mV-1 range, linear response in a broad spectral range below 320 nm, photocurrents around ~10-5 A, and short response time better than 100 ns, which is independent of fluency intensity. A phenomenological model was applied to help understand the role of defects and dopant concentration on the materials’ photosensitivity.

  11. Ultraviolet photosensitivity of sulfur-doped micro- and nano-crystalline diamond

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mendoza, Frank; Makarov, Vladimir; Hidalgo, Arturo; Weiner, Brad; Morell, Gerardo

    2011-06-06T23:59:59.000Z

    The room-temperature photosensitivity of sulfur-doped micro- (MCD), submicro- (SMCD) and nano- (NCD) crystalline diamond films synthesized by hot-filament chemical vapor deposition was studied. The structure and composition of these diamond materials were characterized by Raman spectroscopy, scanning electron microscopy and X-ray diffraction. The UV sensitivity and response time were studied for the three types of diamond materials using a steady state broad UV excitation source and two pulsed UV laser radiations. It was found that they have high sensitivity in the UV region, as high as 109 sec-1mV-1 range, linear response in a broad spectral range below 320 nm, photocurrentsmore »around ~10-5 A, and short response time better than 100 ns, which is independent of fluency intensity. A phenomenological model was applied to help understand the role of defects and dopant concentration on the materials’ photosensitivity.« less

  12. Ultraviolet photosensitivity of sulfur-doped micro- and nano-crystalline diamond

    SciTech Connect (OSTI)

    Mendoza, Frank; Makarov, Vladimir; Hidalgo, Arturo; Weiner, Brad; Morell, Gerardo

    2011-06-06T23:59:59.000Z

    The room-temperature photosensitivity of sulfur-doped micro- (MCD), submicro- (SMCD) and nano- (NCD) crystalline diamond films synthesized by hot-filament chemical vapor deposition was studied. The structure and composition of these diamond materials were characterized by Raman spectroscopy, scanning electron microscopy and X-ray diffraction. The UV sensitivity and response time were studied for the three types of diamond materials using a steady state broad UV excitation source and two pulsed UV laser radiations. It was found that they have high sensitivity in the UV region, as high as 109 sec-1mV-1 range, linear response in a broad spectral range below 320 nm, photocurrents around ~10-5 A, and short response time better than 100 ns, which is independent of fluency intensity. A phenomenological model was applied to help understand the role of defects and dopant concentration on the materials’ photosensitivity.

  13. Effect of {gamma} phase on corrosive wear of duplex stainless steel in sulfuric acid solution

    SciTech Connect (OSTI)

    Lu, X.C. [Tsinghua Univ., Beijing (China). National Tribology Lab.; Li, S.Z.; Jiang, X.X.; Zhang, T.C. [Academia Sinica, Shenyang (China). Inst. of Metal Research

    1995-06-01T23:59:59.000Z

    A modified pin-on-ring device was used to study corrosive wear of a duplex stainless steel (DSS) containing ferrite ({alpha}) and austenite ({gamma}) phases in 1 mol/L sulfuric acid (H{sub 2}SO{sub 4}) at room temperature. Different percentages of {gamma} phase in the matrix ({gamma}{sub p}) were obtained by annealing at different solution temperatures. The corrosive wear resistance of the DSS containing small amounts of {gamma} phase was shown to be greater than that of DSS containing large amounts of {gamma} phase under low loads (< 22 N), but the opposite was true under high loads (> 22 N). The same relationships between corrosive wear rate and load were found under cathodic protection at {minus}600 mV{sub SCE}. The morphologies of wear tracks and debris were observed by scanning electron microscopy (SEM). The influence of the amount of {gamma} phase in the matrix on hardness, corrosion, and corrosive wear resistance was evaluated.

  14. Effects of reactive element additions and sulfur removal on the oxidation behavior of FECRAL alloys

    SciTech Connect (OSTI)

    Stasik, M.C.; Pettit, F.S.; Meier, G.H. (Univ. of Pittsburgh, PA (United States). Dept. of Materials Science and Engineering); Ashary, A. (Praxair, Indianapolis, IN (United States)); Smialek, J.L. (NASA Lewis Research Center, Cleveland, OH (United States))

    1994-12-15T23:59:59.000Z

    The results of this study have shown that desulfurization of FeCrAl alloys by hydrogen annealing can result in improvements in cyclic oxidation comparable to that achieved by doping with reactive elements. Moreover, specimens of substantial thicknesses can be effectively desulfurized because of the high diffusivity of sulfur in bcc iron alloys. The results have also shown that there is less stress generation during the cyclic oxidation of Y-doped FeCrAl compared to Ti-doped or desulfurized FeCrAl. This indicates that the growth mechanism, as well as the strength of the oxide/alloy interface, influences the ultimate oxidation morphology and stress state which will certainly affect the length of time the alumina remains protective.

  15. Influence of fuel sulfur on the selective reduction of NO by NH/sub 3/

    SciTech Connect (OSTI)

    Lucas, D.; Brown, N.J.

    1981-01-01T23:59:59.000Z

    More intensive regulations of the emissions of nitrogen oxides from stationary combustion sources have prompted the innovation and characterization of new control technologies suitable for applications in utilities. One of the more recent and attractive abatement technologies is the Thermal DeNO/sub x/ process which has been described by Lyon and Longwell. This process removes NO by selectively reducing it with NH/sub 3/ added to the post-combustion gases containing excess oxygen. This process is thus independent of the NO formation mechanism and makes no distinction between thermal and fuel NO. The present study is concerned with characterizing the selective reduction process for light distillate oil fuel admixed with variable amounts of pyridene and thiophene in a laboratory scale combustion tunnel under a variety of experimental conditions. This paper reports on those aspects of the study concerned with the investigation of possible synergistic effects between the sulfur and selective reduction chemistry.

  16. The Mechanism of Electropolishing of Niobium in Hydrofluoric-Sulfuric Acid Electrolyte

    SciTech Connect (OSTI)

    Tian, Hui; Corcoran, Sean; Reece, Charles; Kelley, Michael

    2008-07-01T23:59:59.000Z

    Niobium surfaces are commonly electropolished in an effort to obtain optimal smoothness for high-field superconducting radio-frequency cavity applications. We report the use of controlled electrochemical analysis techniques to characterize electropolishing of Nb in a sulfuric and hydrofluoric acid electrolyte. Through the use of a reference electrode, we are able to clearly distinguish the anode and cathode polarization potentials as well as the electrolyte voltage drop, which together sum to the applied power supply voltage. We then identify the temperature and HF concentration dependence of each potential. We also report the use of electrochemical impedance spectroscopy (EIS) on this system. EIS results are consistent with the compact salt film mechanism for niobium electropolishing (EP) in this electrolyte and are not consistent with either the porous salt film or the absorbate-acceptor mechanism. Microscopic understanding of the basic Nb EP mechanism is expected to provide an appro

  17. The south Karelia air pollution study: Effects of low-level expsoure to malodorous sulfur compounds on symptoms

    SciTech Connect (OSTI)

    Partti-Pellinen, K.; Marttila, O. [South Karelia Allergy and Environment Inst., Tiuruniemi (Finland); Vilkka, V. [South Karelia Central Hospital, Lappeenranta (Finland); Jaakkola, J.J. [Univ. of Helsinki (Finland)]|[National Inst. of Public Health, Oslo (Norway)] [and others

    1996-07-01T23:59:59.000Z

    Exposure to very low levels of ambient-air malodorous sulfur compounds and their effect on eye irritation, respiratory-tract symptoms, and central nervous system symptoms in adults were assessed. A cross-sectional self-administered questionnaire (response rate = 77%) was distributed during March and April 1992 to adults (n = 336) who lived in a neighborhood that contained a pulp mill and in a nonpolluted reference community (n = 380). In the exposed community, the measured annual mean concentrations of total reduced sulfur compounds and sulfur dioxide measured in two stations were 2 to 3 {mu}g/m{sup 3} and 1 {mu}g/m{sup 3}, respectively. In the reference community, the annual mean concentration of sulfur dioxide was 1 {mu}g/m{sup 3}. The residents of the community near the pulp mill reported an excess of cough, respiratory infections, and headache during the previous 4 wk, as well as during the preceding 12 mo. The relative risk for headache was increased significantly in the exposed community, compared with the reference area: the adjusted odds ratio (aOR) was 1.83 (95% confidence interval [95% Cl] = 1.06-3.15) during the previous 4 wk and 1.70 (95% Cl = 1.05-2.73) during the preceding 12 mo. The relative risk for cough was also increased during the preceding 12 mo (aOR = 1.64, 95% Cl = 1.01-2.64). These results indicated that adverse health effects of malodorous sulfur compounds occur at lower concentrations than reported previously. 25 refs., 3 tabs.

  18. A Nonempirical Test on the Weight of Pseudorandom Number Generators

    E-Print Network [OSTI]

    Matsumoto, Makoto

    A Nonempirical Test on the Weight of Pseudorandom Number Generators Makoto Matsumoto1 and Takuji introduce a theoretical test, named weight discrepancy test, on pseu- dorandom number generators. This test selected. This test can be performed for most generators based on a linear recursion over the two

  19. Implementing Weighted Abduction in Markov Logic James Blythe

    E-Print Network [OSTI]

    Anderson, Richard

    Implementing Weighted Abduction in Markov Logic James Blythe USC ISI blythe@isi.edu Jerry R. Hobbs@cs.utexas.edu Abstract Abduction is a method for finding the best explanation for observations. Arguably the most advanced approach to abduction, especially for natural language processing, is weighted abduction, which

  20. Weighted Hypothesis Testing Larry Wasserman and Kathryn Roeder1

    E-Print Network [OSTI]

    loss remains nearly constant. specified weights, but minute power loss for poorly specified weights; and (ii) in the non-sparse case, under weak conditions, the worst case power loss for poorly specified the potential power loss. Figure 2 shows the non-sparse case. The plots on the left show the power as a function