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Sample records for water vapor clouds

  1. Temperature, Water Vapor, and Clouds"

    Office of Scientific and Technical Information (OSTI)

    Radiometric Studies of Temperature, Water Vapor, and Clouds" Project ID: 0011106 ... measurements of column amounts of water vapor and cloud liquid has been well ...

  2. Monitoring of Precipitable Water Vapor and Cloud Liquid Path...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave ... used to measure atmospheric precipitable water vapor (PWV) and cloud liquid path (CLP). ...

  3. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    2004-02-19

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  4. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  5. COLD WATER VAPOR IN THE BARNARD 5 MOLECULAR CLOUD

    SciTech Connect (OSTI)

    Wirstrm, E. S.; Persson, C. M.; Charnley, S. B.; Cordiner, M. A.; Buckle, J. V.; Takakuwa, S.

    2014-06-20

    After more than 30yr of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds; however, there is only one region where cold (?10K) water vapor has been detectedL1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at worklikely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H{sub 2}O (J = 1{sub 10}-1{sub 01}) at 556.9360GHz toward two positions in the cold molecular cloud, Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

  6. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  7. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  8. Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds

    SciTech Connect (OSTI)

    Westwater, Edgeworth

    2011-05-06

    The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement (ARM) Program. At the North Slope of Alaska (NSA), both microwave radiometers (MWR) and the MWRProfiler (MWRP), been used operationally by ARM for passive retrievals of the quantities: Precipitable Water Vapor (PWV) and Liquid Water Path (LWP). However, it has been convincingly shown that these instruments are inadequate to measure low amounts of PWV and LWP. In the case of water vapor, this is especially important during the Arctic winter, when PWV is frequently less than 2 mm. For low amounts of LWP (< 50 g/m{sup 2}), the MWR and MWRP retrievals have an accuracy that is also not acceptable. To address some of these needs, in March-April 2004, NOAA and ARM conducted the NSA Arctic Winter Radiometric Experiment - Water Vapor Intensive Operational Period at the ARM NSA/Adjacent Arctic Ocean (NSA/AAO) site. After this experiment, the radiometer group at NOAA moved to the Center for Environmental Technology (CET) of the Department of Electrical and Computer Engineering of the University of Colorado at Boulder. During this 2004 experiment, a total of 220 radiosondes were launched, and radiometric data from 22.235 to 380 GHz were obtained. Primary instruments included the ARM MWR and MWRP, a Global Positioning System (GPS), as well as the CET Ground-based Scanning Radiometer (GSR). We have analyzed data from these instruments to answer several questions of importance to ARM, including: (a) techniques for improved water vapor measurements; (b) improved calibration techniques during cloudy conditions; (c) the spectral response of radiometers to a variety of conditions: clear, liquid, ice, and mixed phase clouds; and (d) forward modeling of microwave and millimeter wave brightness temperatures from 22 to 380 GHz. Many of these results have been published in the open literature. During the third year of

  9. PROGRESS REPORT OF FY 2004 ACTIVITIES: IMPROVED WATER VAPOR AND CLOUD RETRIEVALS AT THE NSA/AAO

    SciTech Connect (OSTI)

    E. R. Westwater; V. V. Leuskiy; M. Klein; A. J. Gasiewski; and J. A. Shaw

    2004-11-01

    The basic goals of the research are to develop and test algorithms and deploy instruments that improve measurements of water vapor, cloud liquid, and cloud coverage, with a focus on the Arctic conditions of cold temperatures and low concentrations of water vapor. The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement Program. Although several technologies have been investigated to measure these column amounts, microwave radiometers (MWR) have been used operationally by the ARM program for passive retrievals of these quantities: precipitable water vapor (PWV) and integrated water liquid (IWL). The technology of PWV and IWL retrievals has advanced steadily since the basic 2-channel MWR was first deployed at ARM CART sites Important advances are the development and refinement of the tipcal calibration method [1,2], and improvement of forward model radiative transfer algorithms [3,4]. However, the concern still remains that current instruments deployed by ARM may be inadequate to measure low amounts of PWV and IWL. In the case of water vapor, this is especially important because of the possibility of scaling and/or quality control of radiosondes by the water amount. Extremely dry conditions, with PWV less than 3 mm, commonly occur in Polar Regions during the winter months. Accurate measurements of the PWV during such dry conditions are needed to improve our understanding of the regional radiation energy budgets. The results of a 1999 experiment conducted at the ARM North Slope of Alaska/Adjacent Arctic Ocean (NSA/AAO) site during March of 1999 [5] have shown that the strength associated with the 183 GHz water vapor absorption line makes radiometry in this frequency regime suitable for measuring low amounts of PWV. As a portion of our research, we conducted another millimeter wave radiometric experiment at the NSA/AAO in March-April 2004. This

  10. Water Vapor Experiment Concludes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Water Vapor Experiment Concludes The AIRS (atmospheric infrared sounder) Water Vapor Experiment - Ground (AWEX-G) intensive operations period (IOP) at the SGP central facility ...

  11. ARM Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Water Vapor IOP The SGP CART site will host the third ARM water vapor IOP on September 18-October 8, 2000. The CART site is home to a powerful array of instruments capable of ...

  12. ARM - Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, ... FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Water ...

  13. G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value...

    Office of Scientific and Technical Information (OSTI)

    G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product Citation Details In-Document Search Title: G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) ...

  14. ARM - Evaluation Product - MWR Retrievals of Cloud Liquid Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file...

  15. ARM - Measurement - Total cloud water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud water ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total cloud water The total concentration (mass/vol) of ice and liquid water particles in a cloud; this includes condensed water content (CWC). Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a

  16. ARM - PI Product - MWR Retrievals of Cloud Liquid Water and Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govDataPI Data ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us...

  17. Observed Increase of TTL Temperature and Water Vapor in Polluted Couds over Asia

    SciTech Connect (OSTI)

    Su, Hui; Jiang, Jonathan; Liu, Xiaohong; Penner, J.; Read, William G.; Massie, Steven T.; Schoeberl, Mark R.; Colarco, Peter; Livesey, Nathaniel J.; Santee, Michelle L.

    2011-06-01

    Aerosols can affect cloud particle size and lifetime, which impacts precipitation, radiation and climate. Previous studies1-4 suggested that reduced ice cloud particle size and fall speed due to the influence of aerosols may increase evaporation of ice crystals and/or cloud radiative heating in the tropical tropopause layer (TTL), leading to higher water vapor abundance in air entering the stratosphere. Observational substantiation of such processes is still lacking. Here, we analyze new observations from multiple NASA satellites to show the imprint of pollution influence on stratospheric water vapor. We focus our analysis on the highly-polluted South and East Asia region during boreal summer. We find that "polluted" ice clouds have smaller ice effective radius than "clean" clouds. In the TTL, the polluted clouds are associated with warmer temperature and higher specific humidity than the clean clouds. The water vapor difference between the polluted and clean clouds cannot be explained by other meteorological factors, such as updraft and detrainment strength. Therefore, the observed higher water vapor entry value into the stratosphere in the polluted clouds than in the clean clouds is likely a manifestation of aerosol pollution influence on stratospheric water vapor. Given the radiative and chemical importance of stratospheric water vapor, the increasing emission of aerosols over Asia may have profound impacts on stratospheric chemistry and global energy balance and water cycle.

  18. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Water Vapor IOP ... Responses to Site Operations Questionnaires for Water Vapor IOP Instrument Name Instrument ...

  19. An optical water vapor sensor for unmanned aerial vehicles (Technical...

    Office of Scientific and Technical Information (OSTI)

    An optical water vapor sensor for unmanned aerial vehicles Citation Details In-Document Search Title: An optical water vapor sensor for unmanned aerial vehicles The water vapor ...

  20. ARM: Microwave Water Radiometer (MWR): water liq. and vapor along...

    Office of Scientific and Technical Information (OSTI)

    Microwave Water Radiometer (MWR): water liq. and vapor along line of sight (LOS) path Title: ARM: Microwave Water Radiometer (MWR): water liq. and vapor along line of sight (LOS) ...

  1. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsWater Vapor IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Water Vapor IOP 2000.09.18 - 2000.10.08 Lead Scientist : Henry Revercomb For data sets, see below. Abstract Scientific hypothesis: 1. Microwave radiometer (MWR) observations of the 22 GHz water vapor line can accurately constrain the total column amount of water vapor (assuming a calibration accuracy of 0.5 degC or better, which

  2. Feasibility of tropospheric water vapor profiling using infrared heterodyne differential absorption lidar

    SciTech Connect (OSTI)

    Grund, C.J.; Hardesty, R.M.; Rye, B.J.

    1996-04-01

    The development and verification of realistic climate model parameterizations for clouds and net radiation balance and the correction of other site sensor observations for interferences due to the presence of water vapor are critically dependent on water vapor profile measurements. In this study, we develop system performance models and examine the potential of infrared differential absoroption lidar (DIAL) to determine the concentration of water vapor.

  3. Tower Water-Vapor Mixing Ratio

    SciTech Connect (OSTI)

    Guastad, Krista; Riihimaki, Laura; none,

    2013-04-01

    The purpose of the Tower Water-Vapor Mixing Ratio (TWRMR) value-added product (VAP) is to calculate water-vapor mixing ratio at the 25-meter and 60-meter levels of the meteorological tower at the Southern Great Plains (SGP) Central Facility.

  4. Raman lidar measurements of water vapor and aerosols during the atmospheric radiation measurement (ARM) remote clouds sensing (RCS) intensive observation period (IOP)

    SciTech Connect (OSTI)

    Melfi, S.H.; Starr, D.O`C.; Whiteman, D.

    1996-04-01

    The first Atmospheric Radiation Measurement (ARM) remote Cloud Study (RCS) Intensive Operations Period (IOP) was held during April 1994 at the Southern Great Plains (SGP) site. This experiment was conducted to evaluate and calibrate state-of-the-art, ground based remote sensing instruments and to use the data acquired by these instruments to validate retrieval algorithms developed under the ARM program.

  5. Water vapor distribution in protoplanetary disks

    SciTech Connect (OSTI)

    Du, Fujun; Bergin, Edwin A.

    2014-09-01

    Water vapor has been detected in protoplanetary disks. In this work, we model the distribution of water vapor in protoplanetary disks with a thermo-chemical code. For a set of parameterized disk models, we calculate the distribution of dust temperature and radiation field of the disk with a Monte Carlo method, and then solve the gas temperature distribution and chemical composition. The radiative transfer includes detailed treatment of scattering by atomic hydrogen and absorption by water of Lyα photons, since the Lyα line dominates the UV spectrum of accreting young stars. In a fiducial model, we find that warm water vapor with temperature around 300 K is mainly distributed in a small and well-confined region in the inner disk. The inner boundary of the warm water region is where the shielding of UV field due to dust and water itself become significant. The outer boundary is where the dust temperature drops below the water condensation temperature. A more luminous central star leads to a more extended distribution of warm water vapor, while dust growth and settling tends to reduce the amount of warm water vapor. Based on typical assumptions regarding the elemental oxygen abundance and the water chemistry, the column density of warm water vapor can be as high as 10{sup 22} cm{sup –2}. A small amount of hot water vapor with temperature higher than ∼300 K exists in a more extended region in the upper atmosphere of the disk. Cold water vapor with temperature lower than 100 K is distributed over the entire disk, produced by photodesorption of the water ice.

  6. Synthesis of platinum single-crystal nanoparticles in water vapor...

    Office of Scientific and Technical Information (OSTI)

    of platinum single-crystal nanoparticles in water vapor Citation Details In-Document Search Title: Synthesis of platinum single-crystal nanoparticles in water vapor Authors: ...

  7. GPS Water Vapor Projects Within the ARM Southern Great Plains...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GPS Water Vapor Projects Within the ARM Southern Great Plains Region J. Braun, T. Van ... and characterize the four-dimensional distribution of water vapor within the atmosphere. ...

  8. Vertical Variability of Aerosols and Water Vapor Over the Southern...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vertical Variability of Aerosols and Water Vapor Over the Southern Great Plains R. A. ... Abstract We use Raman lidar profiles of water vapor mixing ratio, relative humidity, ...

  9. Raman Lidar Measurements of Aerosols and Water Vapor During the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Raman Lidar Measurements of Aerosols and Water Vapor During the May 2003 Aerosol IOP R. A. ... Marina, California Abstract Raman lidar water vapor and aerosol extinction profiles ...

  10. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, Paul

    1998-01-01

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma.

  11. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, P.

    1998-06-02

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma. 5 figs.

  12. Final Report for ARM Project Measuring 4-D Water Vapor Fields with GPS

    SciTech Connect (OSTI)

    Braun, John

    2006-02-06

    Water vapor is a primary element in the Earth’s climate system. Atmospheric water vapor is central to cloud processes, radiation transfer, and the hydrological cycle. Using funding from Department of Energy (DOE) grant DE-FG03-02ER63327, the University Corporation for Atmospheric Research (UCAR) developed new observational techniques to measure atmospheric water vapor and applied these techniques to measure four dimensional water vapor fields throughout the United States Southern Great Plains region. This report summarizes the development of a new observation from ground based Global Positioning System (GPS) stations called Slant Water Vapor (SW) and it’s utilization in retrieving four dimensional water vapor fields. The SW observation represents the integrated amount of water vapor between a GPS station and a transmitting satellite. SW observations provide improved temporal and spatial sampling of the atmosphere when compared to column-integrated quantities such as preciptitable water vapor (PW). Under funding from the DOE Atmospheric Radiation Measurement (ARM) program, GPS networks in the Southern Great Plains (SGP) region were deployed to retrieve SW to improve the characterization of water vapor throughout the region. These observations were used to estimate four dimensional water vapor fields using tomographic approaches and through assimilation into the MM5 numerical weather model.

  13. Improved Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer J. C. Liljegren Environmental Research Division Argonne National Laboratory Argonne, Illinois Introduction Radiometrics Corporation has developed a twelve-channel microwave radiometer capable of providing continuous, real-time vertical profiles of temperature, water vapor, and limited-resolution cloud liquid water from the surface to 10 km in nearly all weather conditions (Solheim et al. 1998a). Since

  14. ARM: Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid...

    Office of Scientific and Technical Information (OSTI)

    Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid Water and Precipitable Water Vapor Title: ARM: Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid Water and ...

  15. Scanning ARM Cloud Radar Handbook (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Because RF attenuation increases with atmospheric water vapor content, ARM's Tropical ... Subject: 54 ENVIRONMENTAL SCIENCES; ATTENUATION; CLOUDS; MANUALS; RADAR; WATER VAPOR Word ...

  16. G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product

    SciTech Connect (OSTI)

    Koontz, A; Cadeddu, M

    2012-12-05

    The G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) value-added product (VAP) computes precipitable water vapor using neural network techniques from data measured by the GVR. The GVR reports time-series measurements of brightness temperatures for four channels located at 183.3 ± 1, 3, 7, and 14 GHz.

  17. Determination of Large-Scale Cloud Ice Water Concentration by...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Determination of Large-Scale Cloud Ice Water Concentration by Combining ... Title: Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface ...

  18. Thin Liquid Water Clouds: Their Importance and Our Challenge...

    Office of Scientific and Technical Information (OSTI)

    Thin Liquid Water Clouds: Their Importance and Our Challenge Citation Details In-Document Search Title: Thin Liquid Water Clouds: Their Importance and Our Challenge Many of the ...

  19. Determining Cloud Ice Water Path from High-Frequency Microwave...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining Cloud Ice Water Path from High-Frequency Microwave Measurements G. Liu ... A better understanding of cloud water content and its large-scale distribution ...

  20. Numerical modeling of water injection into vapor-dominatedgeothermal...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Numerical modeling of water injection into vapor-dominatedgeothermal reservoirs Citation Details In-Document Search Title: Numerical modeling of water injection ...

  1. Overview of the ARM/FIRE Water Vapor Experiment (AFWEX)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor Experiment (AFWEX) D. C. Tobin, H. E. Revercomb, and D. D. Turner University of Wisconsin-Madison Madison, Wisconsin Introduction An overview of the ARMFIRE Water ...

  2. Posters Toward an Operational Water Vapor Remote Sensing System...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Posters Toward an Operational Water Vapor Remote Sensing System Using the Global ... T. Van Hove and C. Rocken University Navstar Consortium Boulder, Colorado Background Water ...

  3. Validation of TES Temperature and Water Vapor Retrievals with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The primary objective of the TES (Tropospheric Emission Spectrometer) instrument on the Aura spacecraft is the retrieval of trace gases, especially water vapor and ozone. The TES...

  4. Tropical Cloud Properties and Radiative Heating Profiles (Dataset...

    Office of Scientific and Technical Information (OSTI)

    Tropical Cloud Properties and Radiative Heating Profiles Title: Tropical Cloud Properties ... in that it uses the microwave radiometer to scale the radiosonde column water vapor. ...

  5. Operating a radio-frequency plasma source on water vapor

    SciTech Connect (OSTI)

    Nguyen, Sonca V. T.; Gallimore, Alec D.; Foster, John E.

    2009-08-15

    A magnetically enhanced radio-frequency (rf) plasma source operating on water vapor has an extensive list of potential applications. In this work, the use of a rf plasma source to dissociate water vapor for hydrogen production is investigated. This paper describes a rf plasma source operated on water vapor and characterizes its plasma properties using a Langmuir probe, a residual gas analyzer, and a spectrometer. The plasma source operated first on argon and then on water vapor at operating pressures just over 300 mtorr. Argon and water vapor plasma number densities differ significantly. In the electropositive argon plasma, quasineutrality requires n{sub i}{approx_equal}n{sub e}, where n{sub i} is the positive ion density. But in the electronegative water plasma, quasineutrality requires n{sub i+}=n{sub i-}+n{sub e}. The positive ion density and electron density of the water vapor plasma are approximately one and two orders of magnitude lower, respectively, than those of argon plasma. These results suggest that attachment and dissociative attachment are present in electronegative water vapor plasma. The electron temperature for this water vapor plasma source is between 1.5 and 4 eV. Without an applied axial magnetic field, hydrogen production increases linearly with rf power. With an axial magnetic field, hydrogen production jumps to a maximum value at 500 W and then saturates with rf power. The presence of the applied axial magnetic field is therefore shown to enhance hydrogen production.

  6. Water clouds in Y dwarfs and exoplanets

    SciTech Connect (OSTI)

    Morley, Caroline V.; Fortney, Jonathan J.; Marley, Mark S.; Lupu, Roxana; Greene, Tom; Saumon, Didier; Lodders, Katharina

    2014-05-20

    The formation of clouds affects brown dwarf and planetary atmospheres of nearly all effective temperatures. Iron and silicate condense in L dwarf atmospheres and dissipate at the L/T transition. Minor species such as sulfides and salts condense in mid- to late T dwarfs. For brown dwarfs below T {sub eff} ∼ 450 K, water condenses in the upper atmosphere to form ice clouds. Currently, over a dozen objects in this temperature range have been discovered, and few previous theoretical studies have addressed the effect of water clouds on brown dwarf or exoplanetary spectra. Here we present a new grid of models that include the effect of water cloud opacity. We find that they become optically thick in objects below T {sub eff} ∼ 350-375 K. Unlike refractory cloud materials, water-ice particles are significantly nongray absorbers; they predominantly scatter at optical wavelengths through the J band and absorb in the infrared with prominent features, the strongest of which is at 2.8 μm. H{sub 2}O, NH{sub 3}, CH{sub 4}, and H{sub 2} CIA are dominant opacity sources; less abundant species may also be detectable, including the alkalis, H{sub 2}S, and PH{sub 3}. PH{sub 3}, which has been detected in Jupiter, is expected to have a strong signature in the mid-infrared at 4.3 μm in Y dwarfs around T {sub eff} = 450 K; if disequilibrium chemistry increases the abundance of PH{sub 3}, it may be detectable over a wider effective temperature range than models predict. We show results incorporating disequilibrium nitrogen and carbon chemistry and predict signatures of low gravity in planetary mass objects. Finally, we make predictions for the observability of Y dwarfs and planets with existing and future instruments, including the James Webb Space Telescope and Gemini Planet Imager.

  7. Tower Water-Vapor Mixing Ratio (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Tower Water-Vapor Mixing Ratio Citation Details In-Document Search Title: Tower Water-Vapor Mixing Ratio The purpose of the Tower Water-Vapor Mixing Ratio (TWRMR) value-added ...

  8. A Comparison of Water Vapor Quantities from Model Short-Range...

    Office of Scientific and Technical Information (OSTI)

    Comparison of Water Vapor Quantities from Model Short-Range Forecasts and ARM Observations Citation Details In-Document Search Title: A Comparison of Water Vapor Quantities from ...

  9. ARM - Field Campaign - Single Frequency GPS Water Vapor Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsSingle Frequency GPS Water Vapor Network ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA....

  10. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Vignola, F.; Andreas, A.

    2013-08-22

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  11. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Vignola, F.; Andreas, A.

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  12. Numerical simulation of water injection into vapor-dominated reservoirs

    SciTech Connect (OSTI)

    Pruess, K.

    1995-01-01

    Water injection into vapor-dominated reservoirs is a means of condensate disposal, as well as a reservoir management tool for enhancing energy recovery and reservoir life. We review different approaches to modeling the complex fluid and heat flow processes during injection into vapor-dominated systems. Vapor pressure lowering, grid orientation effects, and physical dispersion of injection plumes from reservoir heterogeneity are important considerations for a realistic modeling of injection effects. An example of detailed three-dimensional modeling of injection experiments at The Geysers is given.

  13. Removal of Sarin Aerosol and Vapor by Water Sprays

    SciTech Connect (OSTI)

    Brockmann, John E.

    1998-09-01

    Falling water drops can collect particles and soluble or reactive vapor from the gas through which they fall. Rain is known to remove particles and vapors by the process of rainout. Water sprays can be used to remove radioactive aerosol from the atmosphere of a nuclear reactor containment building. There is a potential for water sprays to be used as a mitigation technique to remove chemical or bio- logical agents from the air. This paper is a quick-look at water spray removal. It is not definitive but rather provides a reasonable basic model for particle and gas removal and presents an example calcu- lation of sarin removal from a BART station. This work ~ a starting point and the results indicate that further modeling and exploration of additional mechanisms for particle and vapor removal may prove beneficial.

  14. ARM - Field Campaign - ARM-FIRE Water Vapor Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsARM-FIRE Water Vapor Experiment ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : ARM-FIRE Water Vapor Experiment 2000.11.01 - 2000.12.31 Lead Scientist : Henry Revercomb Data Availability Yes For data sets, see below. Summary This field mission experience indicated that it is possible for several sensors to be used in a coordinated fashion over a period of several weeks to achieve a mean water

  15. Posters Radar/Radiometer Retrievals of Cloud Liquid Water and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for retrieving cloud liquid water content and drizzle characteristics using a K -band Doppler radar (Kropfli et al. 1990) and microwave radiometer (Hogg et al. 1983). The...

  16. Liquid Water the Key to Arctic Cloud Radiative Closure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water the Key to Arctic Cloud Radiative Closure For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights Research Highlight...

  17. ARM - Field Campaign - Arctic Winter Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsArctic Winter Water Vapor IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Arctic Winter Water Vapor IOP 2004.03.09 - 2004.04.09 Lead Scientist : Ed Westwater Data Availability http://www.etl.noaa.gov/programs/2004/wviop/data will contain quicklooks of all of the data. For data sets, see below. Summary During the IOP, the Ground-based Scanning Radiometer of NOAA/ETL, and the ARM MicroWave

  18. Intercomparison of the Cloud Water Phase among Global Climate Models

    SciTech Connect (OSTI)

    Komurcu, Muge; Storelvmo, Trude; Tan, Ivy; Lohmann, U.; Yun, Yuxing; Penner, Joyce E.; Wang, Yong; Liu, Xiaohong; Takemura, T.

    2014-03-27

    Mixed-phase clouds (clouds that consist of both cloud droplets and ice crystals) are frequently present in the Earths atmosphere and influence the Earths energy budget through their radiative properties, which are highly dependent on the cloud water phase. In this study, the phase partitioning of cloud water is compared among six global climate models (GCMs) and with Cloud and Aerosol Lidar with Orthogonal Polarization retrievals. It is found that the GCMs predict vastly different distributions of cloud phase for a given temperature, and none of them are capable of reproducing the spatial distribution or magnitude of the observed phase partitioning. While some GCMs produced liquid water paths comparable to satellite observations, they all failed to preserve sufficient liquid water at mixed-phase cloud temperatures. Our results suggest that validating GCMs using only the vertically integrated water contents could lead to amplified differences in cloud radiative feedback. The sensitivity of the simulated cloud phase in GCMs to the choice of heterogeneous ice nucleation parameterization is also investigated. The response to a change in ice nucleation is quite different for each GCM, and the implementation of the same ice nucleation parameterization in all models does not reduce the spread in simulated phase among GCMs. The results suggest that processes subsequent to ice nucleation are at least as important in determining phase and should be the focus of future studies aimed at understanding and reducing differences among the models.

  19. Effect of higher water vapor content on TBC performance

    SciTech Connect (OSTI)

    Pint, Bruce A; Haynes, James A

    2012-01-01

    Coal gasification, or IGCC (integrated gasification combined cycle), is one pathway toward cleaner use of coal for power generation with lower emissions. However, when coal-derived synthesis gas (i.e., syngas) is burned in turbines designed for natural gas, turbine manufacturers recommend 'derating,' or lowering the maximum temperature, which lowers the efficiency of the turbine, making electricity from IGCC more expensive. One possible reason for the derating is the higher water vapor contents in the exhaust gas. Water vapor has a detrimental effect on many oxidation-resistant high-temperature materials. In a turbine hot section, Ni-base superalloys are coated with a thermal barrier coating (TBC) allowing the gas temperature to be higher than the superalloy solidus temperature. TBCs have a low thermal conductivity ceramic top coating (typically Y{sub 2}O{sub 3}-stabilized ZrO{sub 2}, or YSZ) and an oxidation-resistant metallic bond coating. For land-based gas turbines, the industry standard is air plasma sprayed (APS) YSZ and high velocity oxygen fuel (HVOF) sprayed NiCoCrAlY bond coatings. To investigate the role of higher water vapor content on TBC performance and possible mitigation strategies, furnace cycling experiments were conducted in dry O{sub 2} and air with 10% (typical with natural gas or jet fuel) or 50 vol% water vapor. Cycle frequency and temperature were accelerated to one hour at 1100 C (with 10 minute cooling to {approx}30 C between each thermal cycle) to induce early failures in coatings that are expected to operate for several years with a metal temperature of {approx}900 C. Coupons (16 mm diameter x 2 mm thick) of commercial second-generation single crystal superalloy CMSX4 were HVOF coated on both sides with {approx}125 {micro}m of Ni-22wt%Co-17Cr-12Al either with 0.7Y or 0.7Y-0.3Hf-0.4Si. One side was then coated with 190-240 {micro}m of APS YSZ. Coatings were cycled until the YSZ top coating spalled. Figure 2 shows the results of the

  20. Fixation of nitrogen in the presence of water vapor

    DOE Patents [OSTI]

    Harteck, Paul

    1984-01-01

    A process for the fixation of nitrogen is disclosed which comprises combining a mixture of nitrogen, oxygen, metal oxide and water vapor, initially heating the combination to initiate a reaction which forms nitrate, but at a temperature and pressure range below the dissociation pressure of the nitrate. With or without the water component, the yield of fixed nitrogen is increased by the use of a Linde Molecular Sieve Catalyst.

  1. Heterogeneous nucleation of naphthalene vapor on water surface

    SciTech Connect (OSTI)

    Smolik, J.; Schwarz, J.

    1997-01-15

    Transfer processes between drops and gas play an important role in many natural and industrial processes, as absorption of gaseous pollutants by water drops in the atmosphere, combustion of fuel droplets, spray drying, synthesis of nanopowders, wet-dry desulfurization or extinguishing of hot combustion gases. The evaporation of a water drop into a ternary gaseous mixture of air, steam, and naphthalene vapor was investigated. The experimental results were compared with a theoretical prediction based on a numerical solution of coupled boundary layer equations for heat and mass transfer from a drop moving in ternary gas. In the experiments the naphthalene vapor condensed on the water drop as a supercooled liquid even at temperatures far below the melting point of naphthalene. The condensation on drop surface is discussed in terms of classical theory of heterogeneous nucleation on smooth surfaces.

  2. Evaluating Water Vapor in the NCAR CAM3 Climate Model with RRTMG...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor in the NCAR CAM3 Climate Model with RRTMGMcICA using Modeled and Observed ... Objectives: * Evaluate water vapor and temperature simulation in two versions of CAM3 by ...

  3. Comparison of Cloud Fraction and Liquid Water Path between ECMWF...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Comparison of Cloud Fraction and Liquid Water Path between ECMWF Simulations and ARM Long-term Observations at the NSA Site Ming Zhao (mzhao@uwyo.edu) and Zhien Wang ...

  4. Water vapor in the spectrum of the extrasolar planet HD 189733b. II. The eclipse

    SciTech Connect (OSTI)

    Crouzet, Nicolas; McCullough, Peter R.; Deming, Drake; Madhusudhan, Nikku

    2014-11-10

    Spectroscopic observations of exoplanets are crucial to infer the composition and properties of their atmospheres. HD 189733b is one of the most extensively studied exoplanets and is a cornerstone for hot Jupiter models. In this paper, we report the dayside emission spectrum of HD 189733b in the wavelength range 1.1-1.7 μm obtained with the Hubble Space Telescope Wide Field Camera 3 (WFC3) in spatial scan mode. The quality of the data is such that even a straightforward analysis yields a high-precision Poisson noise-limited spectrum: the median 1σ uncertainty is 57 ppm per 0.02 μm bin. We also build a white-light curve correcting for systematic effects and derive an absolute eclipse depth of 96 ± 39 ppm. The resulting spectrum shows marginal evidence for water vapor absorption, but can also be well explained by a blackbody spectrum. However, the combination of these WFC3 data with previous Spitzer photometric observations is best explained by a dayside atmosphere of HD 189733b with no thermal inversion and a nearly solar or subsolar H{sub 2}O abundance in a cloud-free atmosphere. Alternatively, this apparent subsolar abundance may be the result of clouds or hazes that future studies need to investigate.

  5. MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    THE ARCTIC MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN THE ARCTIC Cadeddu, Maria Argonne National Laboratory Category: Instruments A new G-band (183 GHz) vapor radiometer (GVR), developed and built by Prosensing Inc. (http://www.prosensing.com), was deployed in Barrow, Alaska, in April 2005. The radiometer was deployed as part of the ongoing Atmospheric Radiation Measurement (ARM) program's effort to improve water vapor retrievals in the cold, dry Arctic

  6. Measurements of water vapor adsorption on the Geysers rocks

    SciTech Connect (OSTI)

    Gruszkiewicz, Miroslaw S.; Horita, Juske; Simonson, John M.; Mesmer, Robert E.

    1996-01-24

    The ORNL high temperature isopiestic apparatus was adapted for adsorption measurements. The quantity of water retained by rock samples taken from three different wells of The Geysers was measured at 150 °C and at 200 °C as a function of pressure in the range 0.00 ≤ p/p0 ≤ 0.98, where p0 is the saturated water vapor pressure. The rocks were crushed and sieved into three fractions of different grain sizes (with different specific surface areas). Both adsorption (increasing pressure) and desorption (decreasing pressure) runs were made in order to investigate the nature and extent of the hysteresis. Additionally, BET surface area analyses were performed by Porous Materials Inc. on the same rock samples using nitrogen or krypton adsorption measurements at 77 K. Specific surface areas and pore volumes were determined. These parameters are important in estimating water retention capability of a porous material. The same laboratory also determined the densities of the samples by helium pycnometry. Their results were then compared with our own density values obtained by measuring the effect of buoyancy in compressed argon. One of the goals of this project is to determine the dependence of the water retention capacity of the rocks as a function of temperature. The results show a significant dependence of the adsorption and desorption isotherms on the grain size of the sample. The increase in the amount of water retained with temperature observed previously (Shang et al., 1994a, 1994b, 1995) between 90 and 130°C for various reservoir rocks from The Geysers may be due to the contribution of slow chemical adsorption and may be dependent on the time allowed for equilibration. In contrast with the results of Shang et al. (1994a, 1994b, 1995), some closed and nearly closed hysteresis loops on the water adsorption/desorption isotherms (with closing points at p/p0 ≈ 0.6) were obtained in this study. In these cases the effects of activated

  7. Using information about small-scale variability in water vapor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Category: Modeling Deep convection is the process that most strongly affects the transport of energy and moisture in the atmosphere, and it produces clouds which have...

  8. Radiative Importance of ThinŽ Liquid Water Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Accomplishments of the Instantaneous Radiative Flux (IRF) Working Group August 2006 AERI Observations at Southern Great Plains Improve Infrared Radiative Transfer Models Turner et al., JAS, 2004 * AERI observations used to evaluate clear sky IR radiative transfer models * Long-term comparisons have improved - Spectral line database parameters - Water vapor continuum absorption models * Reduced errors in computation of downwelling radiative IR flux by approx 4; current uncertainty is on

  9. The role of water vapor feedback in unperturbed climate variability and global warming

    SciTech Connect (OSTI)

    Hall, A.; Manabe, Syukuro

    1999-08-01

    To understand the role of water vapor feedback in unperturbed surface temperature variability, a version of the Geophysical Fluid Dynamics Laboratory coupled ocean-atmosphere model is integrated for 1,000 yr in two configurations, one with water vapor feedback and one without. To understand the role of water vapor feedback in global warming, two 500-yr integrations were also performed in which CO{sub 2} was doubled in both model configurations. The final surface global warming in the model with water vapor feedback is 3.38 C, while in the one without it is only 1.05 C. However, the model`s water vapor feedback has a larger impact on surface warming in response to a doubling of CO{sub 2} than it does on internally generated, low-frequency, global-mean surface temperature anomalies. Water vapor feedback`s strength therefore depends on the type of temperature anomaly it affects. Finally, the authors compare the local and global-mean surface temperature time series from both unperturbed variability experiments to the observed record. The experiment without water vapor feedback does not have enough global-scale variability to reproduce the magnitude of the variability in the observed global-mean record, whether or not one removes the warming trend observed over the past century. In contrast, the amount of variability in the experiment with water vapor feedback is comparable to that of the global-mean record, provided the observed warming trend is removed. Thus, the authors are unable to simulate the observed levels of variability without water vapor feedback.

  10. Latitudinal survey of middle atmospheric water vapor revealed by shipboard microwave spectroscopy. Master's thesis

    SciTech Connect (OSTI)

    Schrader, M.L.

    1994-05-01

    Water vapor is one of the most important greenhouse gases and is an important tracer of atmospheric motions in the middle atmosphere. It also plays an important role in the chemistry of the middle atmosphere and through its photodissociation by solar radiation, it is the major source of hydrogen escaping to space. Ground-based microwave measurements conducted in the 1980s have provided a fair understanding of the seasonal variation of mesospheric water vapor in the northern hemisphere mid-latitudes, but the global distribution of water vapor in the middle atmosphere is only beginning to be revealed by space-based measurements.

  11. Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface Radar and Satellite Data in Support of ARM SCM Activities

    SciTech Connect (OSTI)

    Liu, Guosheng

    2013-03-15

    Single-column modeling (SCM) is one of the key elements of Atmospheric Radiation Measurement (ARM) research initiatives for the development and testing of various physical parameterizations to be used in general circulation models (GCMs). The data required for use with an SCM include observed vertical profiles of temperature, water vapor, and condensed water, as well as the large-scale vertical motion and tendencies of temperature, water vapor, and condensed water due to horizontal advection. Surface-based measurements operated at ARM sites and upper-air sounding networks supply most of the required variables for model inputs, but do not provide the horizontal advection term of condensed water. Since surface cloud radar and microwave radiometer observations at ARM sites are single-point measurements, they can provide the amount of condensed water at the location of observation sites, but not a horizontal distribution of condensed water contents. Consequently, observational data for the large-scale advection tendencies of condensed water have not been available to the ARM cloud modeling community based on surface observations alone. This lack of advection data of water condensate could cause large uncertainties in SCM simulations. Additionally, to evaluate GCMs’ cloud physical parameterization, we need to compare GCM results with observed cloud water amounts over a scale that is large enough to be comparable to what a GCM grid represents. To this end, the point-measurements at ARM surface sites are again not adequate. Therefore, cloud water observations over a large area are needed. The main goal of this project is to retrieve ice water contents over an area of 10 x 10 deg. surrounding the ARM sites by combining surface and satellite observations. Built on the progress made during previous ARM research, we have conducted the retrievals of 3-dimensional ice water content by combining surface radar/radiometer and satellite measurements, and have produced 3

  12. Water Vapor Turbulence Profiles in Stationary Continental Convective Mixed Layers

    SciTech Connect (OSTI)

    Turner, D. D.; Wulfmeyer, Volker; Berg, Larry K.; Schween, Jan

    2014-10-08

    The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program’s Raman lidar at the ARM Southern Great Plains (SGP) site in north-central Oklahoma has collected water vapor mixing ratio (q) profile data more than 90% of the time since October 2004. Three hundred (300) cases were identified where the convective boundary layer was quasi-stationary and well-mixed for a 2-hour period, and q mean, variance, third order moment, and skewness profiles were derived from the 10-s, 75-m resolution data. These cases span the entire calendar year, and demonstrate that the q variance profiles at the mixed layer (ML) top changes seasonally, but is more related to the gradient of q across the interfacial layer. The q variance at the top of the ML shows only weak correlations (r < 0.3) with sensible heat flux, Deardorff convective velocity scale, and turbulence kinetic energy measured at the surface. The median q skewness profile is most negative at 0.85 zi, zero at approximately zi, and positive above zi, where zi is the depth of the convective ML. The spread in the q skewness profiles is smallest between 0.95 zi and zi. The q skewness at altitudes between 0.6 zi and 1.2 zi is correlated with the magnitude of the q variance at zi, with increasingly negative values of skewness observed lower down in the ML as the variance at zi increases, suggesting that in cases with larger variance at zi there is deeper penetration of the warm, dry free tropospheric air into the ML.

  13. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu; Ly, Jennifer; Aldajani, Tiem; Baker, Richard W.

    2011-08-23

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  14. Reaction kinetics for the high temperature oxidation of Pu--1wt%Ga in water vapor

    SciTech Connect (OSTI)

    Stakebake, J L; Saba, M A

    1988-01-01

    Oxidation of plutonium metal is greatly accelerated by the presence of water vapor. The magnitude of the effect of water vapor on oxidation kinetics is determined by temperature, water concentration, and oxygen concentration. Most of the previous work has been directed toward evaluating the effect of moisture on the atmospheric oxidation of plutonium. Work on the isolation and characterization of the water reaction with plutonium has been very limited. The present work was undertaken to determine the kinetics of the plutonium--water reaction over a wide range of temperature and pressure. Reaction kinetics were measured using a vacuum microbalance system. The temperature range investigated was 100--500/degree/C. The effect of water vapor pressure on reaction kinetics was determined at 300/degree/C by varying the water pressure from 0.1 to 15 Torr. 2 figs.

  15. Investigating the source, transport, and isotope composition of water vapor in the planetary boundary layer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Griffis, Timothy J.; Wood, Jeffrey D.; Baker, John M.; Lee, Xuhui; Xiao, Ke; Chen, Zichong; Welp, Lisa R.; Schultz, Natalie M.; Gorski, Galen; Chen, Ming; et al

    2016-04-25

    Increasing atmospheric humidity and convective precipitation over land provide evidence of intensification of the hydrologic cycle – an expected response to surface warming. The extent to which terrestrial ecosystems modulate these hydrologic factors is important to understand feedbacks in the climate system. We measured the oxygen and hydrogen isotope composition of water vapor at a very tall tower (185 m) in the upper Midwest, United States, to diagnose the sources, transport, and fractionation of water vapor in the planetary boundary layer (PBL) over a 3-year period (2010 to 2012). These measurements represent the first set of annual water vapor isotopemore » observations for this region. Several simple isotope models and cross-wavelet analyses were used to assess the importance of the Rayleigh distillation process, evaporation, and PBL entrainment processes on the isotope composition of water vapor. The vapor isotope composition at this tall tower site showed a large seasonal amplitude (mean monthly δ18Ov ranged from –40.2 to –15.9 ‰ and δ2Hv ranged from –278.7 to –113.0 ‰) and followed the familiar Rayleigh distillation relation with water vapor mixing ratio when considering the entire hourly data set. However, this relation was strongly modulated by evaporation and PBL entrainment processes at timescales ranging from hours to several days. The wavelet coherence spectra indicate that the oxygen isotope ratio and the deuterium excess (dv) of water vapor are sensitive to synoptic and PBL processes. According to the phase of the coherence analyses, we show that evaporation often leads changes in dv, confirming that it is a potential tracer of regional evaporation. Isotope mixing models indicate that on average about 31 % of the growing season PBL water vapor is derived from regional evaporation. However, isoforcing calculations and mixing model analyses for high PBL water vapor mixing ratio events ( > 25 mmol mol–1) indicate that regional

  16. Observed and simulated temperature dependence of the liquid water path of low clouds

    SciTech Connect (OSTI)

    Del Genio, A.D.; Wolf, A.B.

    1996-04-01

    Data being acquired at the Atmospheric Radiation Measurement (ARM) Southern great Plains (SGP) Cloud and Radiation Testbed (CART) site can be used to examine the factors determining the temperature dependence of cloud optical thickness. We focus on cloud liquid water and physical thickness variations which can be derived from existing ARM measurements.

  17. Determination of 3-D Cloud Ice Water Contents by Combining Multiple...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determination of 3-D Cloud Ice Water Contents by Combining Multiple Data Sources from Satellite, Ground Radar, and a Numerical Model Liu, Guosheng Florida State University Seo,...

  18. Geodesic-dome tank roof cuts water contamination, vapor losses

    SciTech Connect (OSTI)

    Barrett, A.E. )

    1989-07-10

    Colonial Pipeline Co. has established an ongoing program for using geodesic-dome roofs on tanks in liquid petroleum-product service. As its standard, Colonial adopted geodesicodone roofs, in conjunction with internal floating decks, to replace worn external floating roofs on existing tanks used in gasoline service and for use on new tanks in all types of product service. Geodesic domes are clear-span structures requiring no internal-support columns. This feature allows the associated use of a floating deck that is as vapor tight as is possible to construct. Further, geodesic domes can practically eliminate rainwater contamination, eliminate wind-generated vapor losses, and greatly reduce filling losses associated with conventional external floating roofs.

  19. DOE/SC-ARM/TR-122 G-Band Vapor Radiometer Precipitable Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product A Koontz M Cadeddu December 2012 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that

  20. MoSi 2 Oxidation in 670-1498 K Water Vapor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sooby Wood, Elizabeth; Parker, Stephen S.; Nelson, Andrew T.; Maloy, Stuart A.; Butt, D.

    2016-03-08

    Molybdenum disilicide (MoSi2) has well documented oxidation resistance at high temperature (T > 1273 K) in dry O2 containing atmospheres due to the formation of a passive SiO2 surface layer. But, its behavior under atmospheres where water vapor is the dominant species has received far less attention. Oxidation testing of MoSi2 was performed at temperatures ranging from 670–1498 K in both 75% water vapor and synthetic air (Ar-O2, 80%–20%) containing atmospheres. Here the thermogravimetric and microscopy data describing these phenomena are presented. Over the temperature range investigated, MoSi2 displays more mass gain in water vapor than in air. The oxidationmore » kinetics observed in water vapor differ from that of the air samples. Two volatile oxides, MoO2(OH)2 and Si(OH)4, are thought to be the species responsible for the varied kinetics, at 670–877 K and at 1498 K, respectively. Finally, we observed an increase in oxidation (140–300 mg/cm2) from 980–1084 K in water vapor, where passivation is observed in air.« less

  1. Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Integrating the Production of Biofuels and Bioproducts Integrating the Production of Biofuels and Bioproducts April 28, 2016 - 11:25am Addthis Non-food biomass such as the crop residue (the leftover material from crops like stalks, leaves, and husks of corn plants following harvest) pictured above can be converted to biofuels as well as high-value products such as plastics, chemicals, and fertilizers. Non-food biomass such as the crop residue (the leftover material from crops like

  2. Tracer study of oxygen and hydrogen uptake by Mg alloys in air with water vapor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brady, M. P.; Fayek, M.; Meyer, H. M.; Leonard, D. N.; Elsentriecy, H. H.; Unocic, K. A.; Anovitz, L. M.; Cakmak, E.; Keiser, J. R.; Song, G. L.; et al

    2015-05-15

    We studied the pure oxidation of Mg, Mg–3Al–1Zn (AZ31B), and Mg–1Zn–0.25Zr–<0.5Nd (ZE10A) at 85 °C in humid air using sequential exposures with H218O and D216O for water vapor. Incorporation of 18O in the hydroxide/oxide films indicated that oxygen from water vapor participated in the reaction. Moreover, penetration of hydrogen into the underlying metal was observed, particularly for the Zr- and Nd-containing ZE10A. Isotopic tracer profiles suggested a complex mixed inward/outward film growth mechanism.

  3. Continuous Water Vapor Profiles for the Fixed Atmospheric Radiation Measurement Sites

    SciTech Connect (OSTI)

    Jensen, M; Troyan, D

    2006-01-09

    The Atmospheric Radiation Measurement (ARM) Program defined a specific metric for the first quarter of Fiscal Year 2006 to complete a continuous time series of the vertical profile of water vapor for selected 30-day periods from each of the fixed ARM sites. In order to accomplish this metric, a new technique devised to incorporate radiosonde data, microwave radiometer data and analysis information from numerical weather forecast models has been developed. The product of this analysis, referred to as the merged sounding value-added product, includes vertical profiles of atmospheric water vapor concentration and several other important thermodynamic state variables at 1-minute time intervals and 266 vertical levels.

  4. Materials, methods and devices to detect and quantify water vapor concentrations in an atmosphere

    DOE Patents [OSTI]

    Allendorf, Mark D; Robinson, Alex L

    2014-12-09

    We have demonstrated that a surface acoustic wave (SAW) sensor coated with a nanoporous framework material (NFM) film can perform ultrasensitive water vapor detection at concentrations in air from 0.05 to 12,000 ppmv at 1 atmosphere pressure. The method is extendable to other MEMS-based sensors, such as microcantilevers, or to quartz crystal microbalance sensors. We identify a specific NFM that provides high sensitivity and selectivity to water vapor. However, our approach is generalizable to detection of other species using NFM to provide sensitivity and selectivity.

  5. A NORMETEX MODEL 15 M3/HR WATER VAPOR PUMPING TEST

    SciTech Connect (OSTI)

    Klein, J.; Fowley, M.; Steeper, T.

    2010-12-20

    Tests were performed using a Model 15 m{sup 3}/hr Normetex vacuum pump to determine if pump performance degraded after pumping a humid gas stream. An air feed stream containing 30% water vapor was introduced into the pump for 365 hours with the outlet pressure of the pump near the condensation conditions of the water. Performance of the pump was tested before and after the water vapor pumping test and indicated no loss in performance of the pump. The pump also appeared to tolerate small amounts of condensed water of short duration without increased noise, vibration, or other adverse indications. The Normetex pump was backed by a dual-head diaphragm pump which was affected by the condensation of water and produced some drift in operating conditions during the test.

  6. Radiative Importance of ThinŽ Liquid Water Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Accomplishments of the Cloud Properties Working Group (CPWG) August 2006 Cloud Radiative Forcing at the ARM Climate Research Facility: Using ARM Data to Establish Testable Metrics for GCM Predictions of Cloud Feedback Gerald Mace University of Utah, Salt Lake City, Utah The scientific underpinning of the Atmospheric Radiation Measurement (ARM) Program is largely based on the premise that long term ground-based measurements of certain quantities provide information sufficient to test the

  7. Measurements of water vapor adsorption on The Geysers rocks

    SciTech Connect (OSTI)

    Gruszkiewicz, M.S.; Horita, J.; Simonson, J.M.; Mesmer, R.E.

    1996-04-01

    One of the goals of this project is to determine the dependence of the water retention capacity of the rocks as a function of temperature. The results show a significant dependence of the adsorption and desorption isotherms on the grain size of the sample. The increase in the amount of water retained with temperature observed previously between 90 and 30{degrees}C for various reservoir rocks from The Geysers may be due to the contribution of slow chemical adsorption and may be dependent on the time allowed for equilibration. In contrast with the results of Shang, some closed and nearly closed hysteresis loops on the water adsorption/desorption isotherms were obtained in this study. In these cases the effects of activated processes were not present, and no increase in water adsorption with temperature was observed.

  8. Detecting Cirrus-Overlapping-Water Clouds and Retrieving their...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clouds and Retrieving their Optical Properties Using MODIS Data F.-L. Chang and Z. Li Earth System Science Interdisciplinary Center University of Maryland College...

  9. ARM - Routine AAF Clouds with Low Optical Water Depths (CLOWD...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Discovery Channel Earth Live Blog News & Press RACORO Backgrounder (PDF, 528K) ... will obtain representative statistics of cloud microphysical, aerosol, and ...

  10. Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling

    SciTech Connect (OSTI)

    Boone, Eric J.; Laskin, Alexander; Laskin, Julia; Wirth, Christopher; Shepson, Paul B.; Stirm, Brian H.; Pratt, Kerri A.

    2015-07-21

    Cloud water and below-cloud atmospheric particle samples were collected onboard a research aircraft during the Southern Oxidant and Aerosol Study (SOAS) over a forested region of Alabama in June 2013. The organic molecular composition of the samples was studied to gain insights into the aqueous-phase processing of organic compounds within cloud droplets. High resolution mass spectrometry with nanospray desorption electrospray ionization and direct infusion electrospray ionization were utilized to compare the organic composition of the particle and cloud water samples, respectively. Isoprene and monoterpene-derived organosulfates and oligomers were identified in both the particles and cloud water, showing the significant influence of biogenic volatile organic compound oxidation above the forested region. While the average O:C ratios of the organic compounds were similar between the atmospheric particle and cloud water samples, the chemical composition of these samples was quite different. Specifically, hydrolysis of organosulfates and formation of nitrogen-containing compounds were observed for the cloud water when compared to the atmospheric particle samples, demonstrating that cloud processing changes the composition of organic aerosol.

  11. Functionalization of multi-walled carbon nanotubes using water-assisted chemical vapor deposition

    SciTech Connect (OSTI)

    Ran Maofei; Sun Wenjing; Liu Yan; Chu Wei; Jiang Chengfa

    2013-01-15

    A simple and novel method, water-assisted chemical vapor deposition (CVD) was developed to functionalize multi-walled carbon nanotubes (MWCNTs) during the synthesis process. The functionalized MWCNTs were characterized using Raman spectroscopy, XPS, TGA, NH{sub 3}-TPD, SEM and HR-TEM. It was found that new defects are introduced and the amount of acidic groups is increased on the MWCNT surface during the water-assisted CVD process. The amount of C-OH and C-O group on the MWCNT surface is found to be increased from 21.1% to 42% with water vapor assistance. Density functional theory (DFT) was employed to study the chemical behavior of water vapor molecule on the catalyst particle surface of Ni(1 1 1) cluster. Based on the experimental and DFT simulation results, a mechanism for functionalization of MWCNTs by water-assisted CVD is proposed. - Graphical abstract: Water is adsorbed and activated on Ni surface, then dissociated into OH and O species, followed by part of OH and O species desorbed from the surface. Finally, the desorbed OH and O species oxidize the unsaturated carbon atoms of carbon nanotubes, form defects and oxygen-containing groups. Highlights: Black-Right-Pointing-Pointer MWCNTs were functionalized by water-assisted CVD method. Black-Right-Pointing-Pointer Defects and weak-medium acidic sites were created on the MWCNT sidewalls. Black-Right-Pointing-Pointer Oxygen-containing groups in functionalized MWCNT were increased from 21.1% to 42%. Black-Right-Pointing-Pointer A mechanism for the influence of water vapor on MWCNTs was proposed.

  12. Remote Spectroscopic Sounding of Liquid Water Path in Thick Clouds in Winter Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remote Spectroscopic Sounding of Liquid Water Path in Thick Clouds in Winter Conditions S. V. Dvoryashin and G. S. Golitsyn A. M. Obukhov Institute of Atmospheric Physics Russian Academy of Sciences Moscow, Russia The liquid water path (LWP) in mixed clouds is restored based on remote measurements of spectral brightness of a cloudy layer in the spectral range 2.15-2.35µm. The results of spectroscopic sounding of dense clouds sounding are presented. Introduction Since the 1980s, in A. M. Obukhov

  13. New Mexico cloud super cooled liquid water survey final report 2009.

    SciTech Connect (OSTI)

    Beavis, Nick; Roskovensky, John K.; Ivey, Mark D.

    2010-02-01

    Los Alamos and Sandia National Laboratories are partners in an effort to survey the super-cooled liquid water in clouds over the state of New Mexico in a project sponsored by the New Mexico Small Business Assistance Program. This report summarizes the scientific work performed at Sandia National Laboratories during the 2009. In this second year of the project a practical methodology for estimating cloud super-cooled liquid water was created. This was accomplished through the analysis of certain MODIS sensor satellite derived cloud products and vetted parameterizations techniques. A software code was developed to analyze multiple cases automatically. The eighty-one storm events identified in the previous year effort from 2006-2007 were again the focus. Six derived MODIS products were obtained first through careful MODIS image evaluation. Both cloud and clear-sky properties from this dataset were determined over New Mexico. Sensitivity studies were performed that identified the parameters which most influenced the estimation of cloud super-cooled liquid water. Limited validation was undertaken to ensure the soundness of the cloud super-cooled estimates. Finally, a path forward was formulized to insure the successful completion of the initial scientific goals which include analyzing different of annual datasets, validation of the developed algorithm, and the creation of a user-friendly and interactive tool for estimating cloud super-cooled liquid water.

  14. Water vapor and ozone profiles with a CO{sub 2} DIAL system in south Italy

    SciTech Connect (OSTI)

    Bellecci, C.; Caputi, G.; De Donato, F.; Gaudio, P.; Valentini, M.

    1996-12-31

    In this paper the authors present the work carried out at the University of Calabria regarding a prototype of a DIAL system. This has been realized for remote pollution monitoring. Most of the efforts have been done to perform several measurements on an horizontal path in order to scan the wide surrounding area. The concentrations of ozone and water vapor have been carried out using two different methods both related with the DIAL technique. With the integrated technique, average concentrations have been evaluated up to 5 km using topographical targets. In the range resolution technique, profiles of ozone and water vapor have been performed up to 700 m with a spatial resolution of about 30 m. Although the system needs a revision in several subsystems of its set-up, the experimentation has pointed out the performance available and the necessary improvements.

  15. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single Family Homes (Revised)

    SciTech Connect (OSTI)

    Cummings, J.; Withers, C.; Martin, E.; Moyer, N.

    2012-10-01

    This document focuses on managing the driving forces which move air and moisture across the building envelope. While other previously published Measure Guidelines focus on elimination of air pathways, the ultimate goal of this Measure Guideline is to manage drivers which cause air flow and water vapor transport across the building envelope (and also within the home), control air infiltration, keep relative humidity (RH) within acceptable limits, avoid combustion safety problems, improve occupant comfort, and reduce house energy use.

  16. Posters Scanning Raman Lidar Measurements of Atmospheric Water Vapor and Aerosols

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 Posters Scanning Raman Lidar Measurements of Atmospheric Water Vapor and Aerosols R. A. Ferrare and K. D. Evans (a) Hughes STX Corporation Lanham, Maryland S. H. Melfi and D. N. Whiteman NASA/Goddard Space Flight Center Greenbelt, Maryland The principal objective of the Department of Energy's (DOE) Atmospheric Radiation Measurement Program (ARM) is to develop a better understanding of the atmospheric radiative balance in order to improve the parameterization of radiative processes in general

  17. The Effects of Water Vapor and Hydrogen on the High-Temperature Oxidation of Alloys

    SciTech Connect (OSTI)

    Mu, N.; Jung, K.; Yanar, N. M.; Pettit, F. S; Holcomb, G. R.; Howard, B. H.; Meier, G. H.

    2013-06-01

    Essentially all alloys and coatings that are resistant to corrosion at high temperature require the formation of a protective (slowly-growing and adherent) oxide layer by a process known as selective oxidation. The fundamental understanding of this process has been developed over the years for exposure in pure oxygen or air. However, the atmospheres in most applications contain significant amounts of water vapor which can greatly modify the behavior of protective oxides. The development of oxy-fuel combustion systems in which fossil fuels are burned in a mixture of recirculated flue gas and oxygen, rather than in air, has caused renewed interest in the effects of water vapor and steam on alloy oxidation. The focus of this paper is on the ways the presence of water vapor can directly alter the selective oxidation process. The paper begins with a brief review of the fundamentals of selective oxidation followed by a description of recent experimental results regarding the effect of water vapor on the oxidation of a variety of chromia-forming alloys (Fe- and Ni-base) in the temperature range 600 to 700 °C. The atmospheres include air, air-H{sub 2}O, Ar-H{sub 2}O and Ar-H{sub 2}O-O{sub 2}. Then the behavior of alumina-forming alloys in H{sub 2}O-containing atmospheres is briefly described. As hydrogen is produced during oxidation of alloys in H{sub 2}O, it can be released back into the gas phase or injected into the metal (where it can diffuse through to the other side). Experiments in which hydrogen concentrations have been measured on both sides of thin specimens during oxidation by H{sub 2}O on only one side are described. Finally, it is attempted to catalogue the various experimental observations under a few general principles.

  18. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes

    SciTech Connect (OSTI)

    Cummings, James; Withers, Charles; Martin, Eric; Moyer, Neil

    2012-10-01

    This report is a revision of an earlier report titled: Measure Guideline: Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes. Revisions include: Information in the text box on page 1 was revised to reflect the most accurate information regarding classifications as referenced in the 2012 International Residential Code. “Measure Guideline” was dropped from the title of the report. An addition was made to the reference list.

  19. Fractionation of soil gases by diffusion of water vapor, gravitational settling, and thermal diffusion

    SciTech Connect (OSTI)

    Severinghaus, J.P.; Bender, M.L. [Univ. of Rhode Island, RI (United States)] [Univ. of Rhode Island, RI (United States); Keeling, R.F. [Scripps Institution of Oceanography, LaJolla, CA (United States)] [Scripps Institution of Oceanography, LaJolla, CA (United States); Broecker, W.S. [Lamont-Doherty Earth Observatory, Palisades, NY (United States)] [Lamont-Doherty Earth Observatory, Palisades, NY (United States)

    1996-03-01

    Air sampled from the moist unsaturated zone in a sand dune exhibits depletion in the heavy isotopes of N{sub 2} and O{sub 2}. We propose that the depletion is caused by a diffusive flux of water vapor out of the dune, which sweeps out the other gases, forcing them to diffuse back into the dune. The heavy isotopes of N{sub 2} and O{sub 2} diffuse back more slowly, resulting in a steady-state depletion of the heavy isotopesin the dune interior. We predict the effect`s magnitude with molecular diffusion theory and reproduce it in a laboratory simulation, finding good agreement between field, theory, and lab. The magnitude of the effect is governed by the ratio of the binary diffusivities against water vapor of a pair of gases, and increases {approximately} linearly with the difference between the water vapor mole fraction of the site and the advectively mixed reservoir with which it is in diffusive contact (in most cases the atmosphere). 32 refs., 1 fig., 3 tabs.

  20. Performance of a Cross-Flow Humidifier with a High Flux Water Vapor Transport Membrane

    SciTech Connect (OSTI)

    Ahluwalia, R. K.; Wang, X.; Johnson, W. B.; Berg, F.; Kadylak, D.

    2015-09-30

    Water vapor transport (WVT) flux across a composite membrane that consists of a very thin perfluorosulfonic acid (PFSA) ionomer layer sandwiched between two expanded polytetrafluoroethylene (PTFE) microporous layers is investigated. Static and dynamic tests are conducted to measure WVT flux for different composite structures; a transport model shows that the underlying individual resistances for water diffusion in the gas phase and microporous and ionomer layers and for interfacial kinetics of water uptake at the ionomer surface are equally important under different conditions. A finite-difference model is formulated to determine water transport in a full-scale (2-m2 active membrane area) planar cross-flow humidifier module assembled using pleats of the optimized composite membrane. In agreement with the experimental data, the modeled WVT flux in the module increases at higher inlet relative humidity (RH) of the wet stream and at lower pressures, but the mass transfer effectiveness is higher at higher pressures. The model indicates that the WVT flux is highest under conditions that maintain the wet stream at close to 100% RH while preventing the dry stream from becoming saturated. The overall water transport is determined by the gradient in RH of the wet and dry streams but is also affected by vapor diffusion in the gas layer and the microporous layer.

  1. Molecular dynamics study of two-dimensional sum frequency generation spectra at vapor/water interface

    SciTech Connect (OSTI)

    Ishiyama, Tatsuya; Morita, Akihiro; Tahara, Tahei

    2015-06-07

    Two-dimensional heterodyne-detected vibrational sum frequency generation (2D HD-VSFG) spectra at vapor/water interface were studied by molecular dynamics (MD) simulation with a classical flexible and nonpolarizable model. The present model well describes the spectral diffusion of 2D infrared spectrum of bulk water as well as 2D HD-VSFG at the interface. The effect of isotopic dilution on the 2D HD-VSFG was elucidated by comparing the normal (H{sub 2}O) water and HOD water. We further performed decomposition analysis of 2D HD-VSFG into the hydrogen-bonding and the dangling (or free) OH vibrations, and thereby disentangled the different spectral responses and spectral diffusion in the 2D HD-VSFG. The present MD simulation demonstrated the role of anharmonic coupling between these modes on the cross peak in the 2D HD-VSFG spectrum.

  2. Cloud&Proper+es:& How&much&water&is&in&a&cloud?&

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summer Training 2015 How much water is in a cloud? ! Cloud&Proper+es:& How&much&water&is&in&a&cloud?& ! ! ! ! presented&by&& Sonja&Drueke&(McGill&University)& Mallory&Row&(University&of&Oklahoma)& &Zhiyuan&Jiang&(Penn&State&University)& &Fabian&Hoffmann&(Leibniz&Universität&Hannover)& & with&guidance&from&!

  3. Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-11-01

    A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

  4. Kinetics of Chronic Oxidation of NBG-17 Nuclear Graphite by Water Vapor

    SciTech Connect (OSTI)

    Contescu, Cristian I; Burchell, Timothy D; Mee, Robert

    2015-05-01

    This report presents the results of kinetic measurements during accelerated oxidation tests of NBG-17 nuclear graphite by low concentration of water vapor and hydrogen in ultra-high purity helium. The objective is to determine the parameters in the Langmuir-Hinshelwood (L-H) equation describing the oxidation kinetics of nuclear graphite in the helium coolant of high temperature gas-cooled reactors (HTGR). Although the helium coolant chemistry is strictly controlled during normal operating conditions, trace amounts of moisture (predictably < 0.2 ppm) cannot be avoided. Prolonged exposure of graphite components to water vapor at high temperature will cause very slow (chronic) oxidation over the lifetime of graphite components. This behavior must be understood and predicted for the design and safe operation of gas-cooled nuclear reactors. The results reported here show that, in general, oxidation by water of graphite NBG-17 obeys the L-H mechanism, previously documented for other graphite grades. However, the characteristic kinetic parameters that best describe oxidation rates measured for graphite NBG-17 are different than those reported previously for grades H-451 (General Atomics, 1978) and PCEA (ORNL, 2013). In some specific conditions, certain deviations from the generally accepted L-H model were observed for graphite NBG-17. This graphite is manufactured in Germany by SGL Carbon Group and is a possible candidate for the fuel elements and reflector blocks of HTGR.

  5. In-Reactor Oxidation of Zircaloy-4 Under Low Water Vapor Pressures

    SciTech Connect (OSTI)

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin; Longhurst, Glen

    2015-01-01

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370C). Data from these tests will be used to support fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr-4 over the specified range of test conditions. Comparisons between in- and ex- reactor test results were performed to evaluate the influence of irradiation.

  6. In-reactor oxidation of zircaloy-4 under low water vapor pressures

    SciTech Connect (OSTI)

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin K.; Longhurst, Glen R.

    2015-01-01

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370 C). Data from these tests will be used to support the fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr- 4 over the specified range of test conditions. Comparisons between in- and ex-reactor test results were performed to evaluate the influence of irradiation.

  7. Method of condensing vaporized water in situ to treat tar sands formations

    DOE Patents [OSTI]

    Hsu, Chia-Fu

    2010-03-16

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  8. Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle

    SciTech Connect (OSTI)

    Hosni, Mohammad H.

    2014-03-30

    Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerant’s pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development

  9. Precipitating clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A suggestion for a new focus on cloud microphysical process study in the ARM program 1. Retrieving precipitating mixed- phase cloud properties Zhien Wang University of Wyoming zwang@uwyo.edu Retrieving Precipitating Mixed-phase Cloud Properties Global distribution of supercooled water topped stratiform clouds (top > 1 km and length> 14km) Most of them are mixed-phase with precipitation or virga An multiple sensor based approach to provide water phase as well as ice phase properties

  10. Acidity dependence on cloud drop sizes, enhancement of sulfate production in clouds and its climatic implications from cloud water collected at a remote eastern US site. Master`s thesis

    SciTech Connect (OSTI)

    Logie, B.D.

    1995-09-10

    Two different cloud water collectors were operated simultaneously on a mountain-top platform in Mt. Mitchell State Park, North Carolina (35 deg 44` 05 N 82 deg 17` 15W) to assess differences, if any, in measured acidity, ionic concentrations, and liquid water collection efficiencies during the summer, 1994. The cloud water collectors used were the Daube California Institute of Technology active-string collector (CALTECH) and the non-rotating passive Atmospheric Sciences Research Center string collector. Both collectors transfer cloud water into their sampling bottles by a process analogous to the collision-coalescence process in precipitation initiation by which cloud droplets accumulate on the collector strings and are then transferred to collection bottles as the droplets become large enough to fall. These large drops, in turn, acquire smaller droplets along their path.

  11. Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds K. Ivanova Pennsylvania State University University Park, Pennsylvania T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington M. Ausloos University of Liège B-4000 Liège, Belgium Abstract We present a method on how to derive an underlying mathematical (statistical or model free) equation for a liquid water path (LWP) signal directly from empirical data. The evolution of the probability density

  12. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Xu, Liukang; McDermitt, Dayle; Anderson, Tyler; Riensche, Brad; Komissarov, Anatoly; Howe, Julie

    2012-02-01

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been

  13. The effects of water vapor on the oxidation behavior of alumina forming austenitic stainless steels

    SciTech Connect (OSTI)

    Yanar, N. M.; Lutz, B. S.; Garcia-Fresnillo, L.; Brady, Michael P.; Meier, G. H.

    2015-08-19

    The isothermal oxidation behavior of three alumina forming austenitic (AFA) stainless steels with varying composition was studied at 650 and 800 °C in dry air and gases which contained water vapor. The AFA alloys exhibited better oxidation resistance than a “good chromia former” at 650 °C, particularly in H2O-containing atmospheres by virtue of alumina-scale formation. Although the AFA alloys were more resistant than chromia formers, their oxidation resistance was degraded at 650 °C in the presence of water vapor. In dry air the AFA alloys formed, thin continuous alumina scales, whereas in Ar–4%H2–3%H2O the areas of continuous alumina were reduced and Fe oxide-rich nodules and regions of Cr, Mn-rich oxides formed. In some regions internal oxidation of the aluminum occurred in the H2O-containing gas. The alloy OC8 had slightly better resistance than OC4 or OC5 in this atmosphere. The alumina-forming capability of the AFA alloys decreases with increasing temperature and, at 800 °C, they are borderline alumina formers, even in dry air. The oxidation resistance of all three alloys was degraded at 800 °C in atmospheres, which contained water vapor (Air–10%H2O, Ar–3%H2O and Ar–4%H2–3%H2O). The areas, which formed continuous alumina, were reduced in these atmospheres and areas of internal oxidation occurred. However, as a result of the borderline alumina-forming capability of the AFA alloys it was not possible to determine which of the H2O-containing atmospheres was more severe or to rank the alloys in terms of their performance. The experimental results indicate that the initial microstructure of the AFA alloys also plays a role in their oxidation performance. Less protective oxides formed at 800 °C when alloy OC8 was equilibrated before exposure rather than being exposed in the as-processed condition. As a result, the reason for this is the presence of different

  14. The effects of water vapor on the oxidation behavior of alumina forming austenitic stainless steels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yanar, N. M.; Lutz, B. S.; Garcia-Fresnillo, L.; Brady, Michael P.; Meier, G. H.

    2015-08-19

    The isothermal oxidation behavior of three alumina forming austenitic (AFA) stainless steels with varying composition was studied at 650 and 800 °C in dry air and gases which contained water vapor. The AFA alloys exhibited better oxidation resistance than a “good chromia former” at 650 °C, particularly in H2O-containing atmospheres by virtue of alumina-scale formation. Although the AFA alloys were more resistant than chromia formers, their oxidation resistance was degraded at 650 °C in the presence of water vapor. In dry air the AFA alloys formed, thin continuous alumina scales, whereas in Ar–4%H2–3%H2O the areas of continuous alumina were reducedmore » and Fe oxide-rich nodules and regions of Cr, Mn-rich oxides formed. In some regions internal oxidation of the aluminum occurred in the H2O-containing gas. The alloy OC8 had slightly better resistance than OC4 or OC5 in this atmosphere. The alumina-forming capability of the AFA alloys decreases with increasing temperature and, at 800 °C, they are borderline alumina formers, even in dry air. The oxidation resistance of all three alloys was degraded at 800 °C in atmospheres, which contained water vapor (Air–10%H2O, Ar–3%H2O and Ar–4%H2–3%H2O). The areas, which formed continuous alumina, were reduced in these atmospheres and areas of internal oxidation occurred. However, as a result of the borderline alumina-forming capability of the AFA alloys it was not possible to determine which of the H2O-containing atmospheres was more severe or to rank the alloys in terms of their performance. The experimental results indicate that the initial microstructure of the AFA alloys also plays a role in their oxidation performance. Less protective oxides formed at 800 °C when alloy OC8 was equilibrated before exposure rather than being exposed in the as-processed condition. As a result, the reason for this is the presence of different phases in the bulk of the two specimens.« less

  15. A comparison of water vapor quantities from model short-range forecasts and ARM observations

    SciTech Connect (OSTI)

    Hnilo, J J

    2006-03-17

    Model evolution and improvement is complicated by the lack of high quality observational data. To address a major limitation of these measurements the Atmospheric Radiation Measurement (ARM) program was formed. For the second quarter ARM metric we will make use of new water vapor data that has become available, and called the 'Merged-sounding' value added product (referred to as OBS, within the text) at three sites: the North Slope of Alaska (NSA), Darwin Australia (DAR) and the Southern Great Plains (SGP) and compare these observations to model forecast data. Two time periods will be analyzed March 2000 for the SGP and October 2004 for both DAR and NSA. The merged-sounding data have been interpolated to 37 pressure levels (e.g., from 1000hPa to 100hPa at 25hPa increments) and time averaged to 3 hourly data for direct comparison to our model output.

  16. A Comparison of Water Vapor Quantities from Model Short-Range Forecasts and ARM Observations

    SciTech Connect (OSTI)

    Hnilo, J.

    2006-03-17

    Model evolution and improvement is complicated by the lack of high quality observational data. To address a major limitation of these measurements the Atmospheric Radiation Measurement (ARM) program was formed. For the second quarter ARM metric we will make use of new water vapor data that has become available, and called the “Mergedsounding” value added product (referred to as OBS, within the text) at three sites: the North Slope of Alaska (NSA), Darwin Australia (DAR) and the Southern Great Plains (SGP) and compare these observations to model forecast data. Two time periods will be analyzed March 2000 for the SGP and October 2004 for both DAR and NSA. The merged-sounding data have been interpolated to 37 pressure levels (e.g., from 1000hPa to 100hPa at 25hPa increments) and time averaged to 3 hourly data for direct comparison to our model output.

  17. Treatment of Produced Water Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Lynn E. Katz; Kerry A. Kinney; Robert S. Bowman; Enid J. Sullivan; Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Craig R. Altare

    2006-01-31

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. Produced waters typically contain a high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component as well as chemicals added during the oil-production process. It has been estimated that a total of 14 billion barrels of produced water were generated in 2002 from onshore operations (Veil, 2004). Although much of this produced water is disposed via reinjection, environmental and cost considerations can make surface discharge of this water a more practical means of disposal. In addition, reinjection is not always a feasible option because of geographic, economic, or regulatory considerations. In these situations, it may be desirable, and often necessary from a regulatory viewpoint, to treat produced water before discharge. It may also be feasible to treat waters that slightly exceed regulatory limits for re-use in arid or drought-prone areas, rather than losing them to reinjection. A previous project conducted under DOE Contract DE-AC26-99BC15221 demonstrated that surfactant modified zeolite (SMZ) represents a potential treatment technology for produced water containing BTEX. Laboratory and field experiments suggest that: (1) sorption of benzene, toluene, ethylbenzene and xylenes (BTEX) to SMZ follows linear isotherms in which sorption increases with increasing solute hydrophobicity; (2) the presence of high salt concentrations substantially increases the capacity of the SMZ for BTEX; (3) competitive sorption among the BTEX compounds is negligible; and, (4) complete recovery of the SMZ sorption capacity for BTEX can be achieved by air sparging the SMZ. This report summarizes research for a follow on project to optimize the regeneration process for multiple sorption/regeneration cycles, and to develop and incorporate a vapor phase bioreactor (VPB) system for treatment of the off-gas generated during

  18. TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM

    SciTech Connect (OSTI)

    LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

    2003-10-01

    Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and

  19. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W.

    2014-05-14

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 away from the surface.

  20. Dependence of Tritium Release from Stainless Steel on Temperature and Water Vapor

    SciTech Connect (OSTI)

    Shmayda, W. T.; Sharpe, M.; Boyce, A. M.; Shea, R.; Petroski, B.; Schroeder, W. U.

    2015-09-15

    The impact of water vapor and temperature on the release of tritium from stainless steel was studied. Degreased stainless steel samples loaded with tritium at room temperature following a 24-h degassing in vacuum at room temperature were subjected to increasing temperatures or humidity. In general, increasing either the sample temperature or the humidity causes an increased quantity of tritium to be removed. Increasing the temperature to 300°C in a dry gas stream results in a significant release of tritium and is therefore an effective means for reducing the tritium inventory in steel. For humid purges at 30°C, a sixfold increase in humidity results in a tenfold increase in the peak outgassing rate. Increasing the humidity from 4 parts per million (ppm) to 1000 ppm when the sample temperature is 100°C causes a significant increase in the tritium outgassing rate. Finally, a simple calculation shows that only 15% of the activity present in the sample was removed in these experiments, suggesting that the surface layer of adsorbed water participates in regulating tritium desorption from the surface.

  1. Dependence of Tritium Release from Stainless Steel on Temperature and Water Vapor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shmayda, W. T.; Sharpe, M.; Boyce, A. M.; Shea, R.; Petroski, B.; Schroeder, W. U.

    2015-09-15

    The impact of water vapor and temperature on the release of tritium from stainless steel was studied. Degreased stainless steel samples loaded with tritium at room temperature following a 24-h degassing in vacuum at room temperature were subjected to increasing temperatures or humidity. In general, increasing either the sample temperature or the humidity causes an increased quantity of tritium to be removed. Increasing the temperature to 300°C in a dry gas stream results in a significant release of tritium and is therefore an effective means for reducing the tritium inventory in steel. For humid purges at 30°C, a sixfold increasemore » in humidity results in a tenfold increase in the peak outgassing rate. Increasing the humidity from 4 parts per million (ppm) to 1000 ppm when the sample temperature is 100°C causes a significant increase in the tritium outgassing rate. Finally, a simple calculation shows that only 15% of the activity present in the sample was removed in these experiments, suggesting that the surface layer of adsorbed water participates in regulating tritium desorption from the surface.« less

  2. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  3. Long-term stable water vapor permeation barrier properties of SiN/SiCN/SiN nanolaminated multilayers grown by plasma-enhanced chemical vapor deposition at extremely low pressures

    SciTech Connect (OSTI)

    Choi, Bum Ho Lee, Jong Ho

    2014-08-04

    We investigated the water vapor permeation barrier properties of 30-nm-thick SiN/SiCN/SiN nanolaminated multilayer structures grown by plasma enhanced chemical vapor deposition at 7 mTorr. The derived water vapor transmission rate was 1.12 × 10{sup −6} g/(m{sup 2} day) at 85 °C and 85% relative humidity, and this value was maintained up to 15 000 h of aging time. The X-ray diffraction patterns revealed that the nanolaminated film was composed of an amorphous phase. A mixed phase was observed upon performing high resolution transmission electron microscope analysis, which indicated that a thermodynamically stable structure was formed. It was revealed amorphous SiN/SiCN/SiN multilayer structures that are free from intermixed interface defects effectively block water vapor permeation into active layer.

  4. A Compact, Backscattering Deplolarization Cloud Spectrometer for Ice and Water Discrimination

    SciTech Connect (OSTI)

    Thomson, David

    2014-05-15

    This project was to develop a compact optical particle spectrometer, small enough for operation on UAVS, that measures the optical diameter of cloud hydrometeors and differentiates their water phase (liquid or solid). To reach this goal, a work plan was laid out that would complete three objectives: 1) Evaluation of designs for an optical particle spectrometer that measures the component of light backscattered at two polarization angles. 2) Testing of selected designs on an optical bench. 3) Construction and preliminary testing of a prototype instrument based on the selected, optimum design. A protoype instrument was developed and tested in an icing wind tunnel where the results showed good measurement of cloud droplets and ice particles.

  5. Biophysical controls on carbon and water vapor fluxes across a grassland climatic gradient in the United States

    SciTech Connect (OSTI)

    Wagle, Pradeep; Xiao, Xiangming; Scott, Russell L.; Kolb, Thomas E.; Cook, David R.; Brunsell, Nathaniel; Baldocchi, Dennis D.; Basara, Jeffrey; Matamala, Roser; Zhou, Yuting; Bajgain, Rajen

    2015-12-01

    Understanding of the underlying causes of spatial variation in exchange of carbon and water vapor fluxes between grasslands and the atmosphere is crucial for accurate estimates of regional and global carbon and water budgets, and for predicting the impact of climate change on biosphere–atmosphere feedbacks of grasslands. We used ground-based eddy flux and meteorological data, and the Moderate Resolution Imaging Spectroradiometer (MODIS) enhanced vegetation index (EVI) from 12 grasslands across the United States to examine the spatial variability in carbon and water vapor fluxes and to evaluate the biophysical controls on the spatial patterns of fluxes. Precipitation was strongly associated with spatial and temporal variability in carbon and water vapor fluxes and vegetation productivity. Grasslands with annual average precipitation <600 mm generally had neutral annual carbon balance or emitted small amount of carbon to the atmosphere. Despite strong coupling between gross primary production (GPP)and evapotranspiration (ET) across study sites, GPP showed larger spatial variation than ET, and EVI had a greater effect on GPP than on ET. Consequently, large spatial variation in ecosystem water use efficiency (EWUE = annual GPP/ET; varying from 0.67 ± 0.55 to 2.52 ± 0.52 g C mm⁻¹ET) was observed. Greater reduction in GPP than ET at high air temperature and vapor pressure deficit caused a reduction in EWUE in dry years, indicating a response which is opposite than what has been reported for forests. Our results show that spatial and temporal variations in ecosystem carbon uptake, ET, and water use efficiency of grasslands were strongly associated with canopy greenness and coverage, as indicated by EVI.

  6. Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations

    SciTech Connect (OSTI)

    Turner, David D.

    2003-06-01

    A novel new approach to retrieve cloud microphysical properties from mixed-phase clouds is presented. This algorithm retrieves cloud optical depth, ice fraction, and the effective size of the water and ice particles from ground-based, high-resolution infrared radiance observations. The theoretical basis is that the absorption coefficient of ice is stronger than that of liquid water from 10-13 mm, whereas liquid water is more absorbing than ice from 16-25 um. However, due to strong absorption in the rotational water vapor absorption band, the 16-25 um spectral region becomes opaque for significant water vapor burdens (i.e., for precipitable water vapor amounts over approximately 1 cm). The Arctic is characterized by its dry and cold atmosphere, as well as a preponderance of mixed-phase clouds, and thus this approach is applicable to Arctic clouds. Since this approach uses infrared observations, cloud properties are retrieved at night and during the long polar wintertime period. The analysis of the cloud properties retrieved during a 7 month period during the Surface Heat Budget of the Arctic (SHEBA) experiment demonstrates many interesting features. These results show a dependence of the optical depth on cloud phase, differences in the mode radius of the water droplets in liquid-only and mid-phase clouds, a lack of temperature dependence in the ice fraction for temperatures above 240 K, seasonal trends in the optical depth with the clouds being thinner in winter and becoming more optically thick in the late spring, and a seasonal trend in the effective size of the water droplets in liquid-only and mixed-phase clouds that is most likely related to aerosol concentration.

  7. Method and apparatus for simulating atmospheric absorption of solar energy due to water vapor and CO{sub 2}

    DOE Patents [OSTI]

    Sopori, B.L.

    1995-06-20

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.

  8. Method and apparatus for simulating atomospheric absorption of solar energy due to water vapor and CO.sub.2

    DOE Patents [OSTI]

    Sopori, Bhushan L.

    1995-01-01

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth's surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO.sub.2 and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO.sub.2 and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO.sub.2 and moisture.

  9. Detection of water masers toward young stellar objects in the Large Magellanic Cloud

    SciTech Connect (OSTI)

    Johanson, A. K.; Migenes, V.; Breen, S. L.

    2014-02-01

    We present results from a search for water maser emission toward N4A, N190, and N206, three regions of massive star formation in the Large Magellanic Cloud (LMC). Four water masers were detected; two toward N4A, and two toward N190. In the latter region, no previously known maser emission has been reported. Future studies of maser proper motion to determine the galactic dynamics of the LMC will benefit from the independent data points the new masers in N190 provide. Two of these masers are associated with previously identified massive young stellar objects (YSOs), which strongly supports the authenticity of the classification. We argue that the other two masers identify previously unknown YSOs. No masers were detected toward N206, but it does host a newly discovered 22 GHz continuum source, also associated with a massive YSO. We suggest that future surveys for water maser emission in the LMC be targeted toward the more luminous, massive YSOs.

  10. Evaluation of an ambient air sampling system for tritium (as tritiated water vapor) using silica gel adsorbent columns

    SciTech Connect (OSTI)

    Patton, G.W.; Cooper, A.T.; Tinker, M.R.

    1995-08-01

    Ambient air samples for tritium analysis (as the tritiated water vapor [HTO] content of atmospheric moisture) are collected for the Hanford Site Surface Environmental Surveillance Project (SESP) using the solid adsorbent silica gel. The silica gel has a moisture sensitive indicator which allows for visual observation of moisture movement through a column. Despite using an established method, some silica gel columns showed a complete change in the color indicator for summertime samples suggesting that breakthrough had occurred; thus a series of tests was conducted on the sampling system in an environmental chamber. The purpose of this study was to determine the maximum practical sampling volume and overall collection efficiency for water vapor collected on silica gel columns. Another purpose was to demonstrate the use of an impinger-based system to load water vapor onto silica gel columns to provide realistic analytical spikes and blanks for the Hanford Site SESP. Breakthrough volumes (V{sub b}) were measured and the chromatographic efficiency (expressed as the number of theoretical plates [N]) was calculated for a range of environmental conditions. Tests involved visual observations of the change in the silica gel`s color indicator as a moist air stream was drawn through the column, measurement of the amount of a tritium tracer retained and then recovered from the silica gel, and gravimetric analysis for silica gel columns exposed in the environmental chamber.

  11. Treatment of Produced Waters Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Lynn E. Katz; Kerry A. Kinney; R. S. Bowman; E. J. Sullivan

    2005-03-11

    second residence time, the GAC bed reduced peak contaminant concentrations by 97%. After the initial peak, the inlet VOC concentration in the SMZ regeneration gas stream drops exponentially with time. During this period, the contaminants on the GAC subsequently desorbed at a nearly steady rate over the next 45 hours resulting in a relatively steady effluent concentration of approximately 25 ppm{sub v}. This lower concentration is readily degradable by a downstream vapor phase biofilter (VPB) and the steady nature of the feed stream will prevent the biomass in the VPB from enduring starvation conditions between SMZ regeneration cycles. Repetitive sorption and desorption cycles that would be expected in the field were also investigated. It was determined that although the GAC initially lost some VOC sorption capacity, the adsorption and desorption profiles stabilized after approximately 6 cycles indicating that a GAC bed should be suitable for continuous operation. In preparation for the pilot field testing of the SMZ/VPB system, design, ''in-house'' construction and testing of the field system were completed during this project period. The design of the SMZ system for the pilot test was based on previous investigations by the PI's in Wyoming, 2002 and on analyses of the produced water at the field site in New Mexico. The field tests are scheduled for summer, 2005. A cost survey, feasibility of application and cost analyses were completed to investigate the long term effectiveness of the SMZ/VPB system as a method of treating produced water for re-use. Several factors were investigated, including: current costs to treat and dispose of produced water, end-use water quality requirements, and state and federal permitting requirements.

  12. A unified parameterization of clouds and turbulence using CLUBB and subcolumns in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thayer-Calder, K.; Gettelman, A.; Craig, C.; Goldhaber, S.; Bogenschutz, P. A.; Chen, C.-C.; Morrison, H.; Höft, J.; Raut, E.; Griffin, B. M.; et al

    2015-06-30

    Most global climate models parameterize separate cloud types using separate parameterizations. This approach has several disadvantages, including obscure interactions between parameterizations and inaccurate triggering of cumulus parameterizations. Alternatively, a unified cloud parameterization uses one equation set to represent all cloud types. Such cloud types include stratiform liquid and ice cloud, shallow convective cloud, and deep convective cloud. Vital to the success of a unified parameterization is a general interface between clouds and microphysics. One such interface involves drawing Monte Carlo samples of subgrid variability of temperature, water vapor, cloud liquid, and cloud ice, and feeding the sample points into amore » microphysics scheme. This study evaluates a unified cloud parameterization and a Monte Carlo microphysics interface that has been implemented in the Community Atmosphere Model (CAM) version 5.3. Results describing the mean climate and tropical variability from global simulations are presented. The new model shows a degradation in precipitation skill but improvements in short-wave cloud forcing, liquid water path, long-wave cloud forcing, precipitable water, and tropical wave simulation. Also presented are estimations of computational expense and investigation of sensitivity to number of subcolumns.« less

  13. A unified parameterization of clouds and turbulence using CLUBB and subcolumns in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thayer-Calder, K.; Gettelman, A.; Craig, C.; Goldhaber, S.; Bogenschutz, P. A.; Chen, C.-C.; Morrison, H.; Höft, J.; Raut, E.; Griffin, B. M.; et al

    2015-12-01

    Most global climate models parameterize separate cloud types using separate parameterizations. This approach has several disadvantages, including obscure interactions between parameterizations and inaccurate triggering of cumulus parameterizations. Alternatively, a unified cloud parameterization uses one equation set to represent all cloud types. Such cloud types include stratiform liquid and ice cloud, shallow convective cloud, and deep convective cloud. Vital to the success of a unified parameterization is a general interface between clouds and microphysics. One such interface involves drawing Monte Carlo samples of subgrid variability of temperature, water vapor, cloud liquid, and cloud ice, and feeding the sample points into amore » microphysics scheme. This study evaluates a unified cloud parameterization and a Monte Carlo microphysics interface that has been implemented in the Community Atmosphere Model (CAM) version 5.3. Model computational expense is estimated, and sensitivity to the number of subcolumns is investigated. Results describing the mean climate and tropical variability from global simulations are presented. The new model shows a degradation in precipitation skill but improvements in shortwave cloud forcing, liquid water path, long-wave cloud forcing, precipitable water, and tropical wave simulation.« less

  14. Active probing of cloud multiple scattering, optical depth, vertical thickness, and liquid water content using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Tellier, L. L.; Ho, Cheng,

    2002-01-01

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60-degree full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer, and, from there, estimate the volume-averaged liquid water content. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Here we present recent WAIL data oti various clouds and discuss the extension of WAIL to full diurnal monitoring by means of an ultra-narrow magneto-optic atomic line filter for daytime measurements.

  15. Emission from water vapor and absorption from other gases at 5-7.5 μm in Spitzer-IRS Spectra Of Protoplanetary Disks

    SciTech Connect (OSTI)

    Sargent, B. A.; Forrest, W.; Watson, Dan M.; Kim, K. H.; Richter, I.; Tayrien, C.; D'Alessio, P.; Calvet, N.; Furlan, E.; Green, J.; Pontoppidan, K.

    2014-09-10

    We present spectra of 13 T Tauri stars in the Taurus-Auriga star-forming region showing emission in Spitzer Space Telescope Infrared Spectrograph 5-7.5 μm spectra from water vapor and absorption from other gases in these stars' protoplanetary disks. Seven stars' spectra show an emission feature at 6.6 μm due to the ν{sub 2} = 1-0 bending mode of water vapor, with the shape of the spectrum suggesting water vapor temperatures >500 K, though some of these spectra also show indications of an absorption band, likely from another molecule. This water vapor emission contrasts with the absorption from warm water vapor seen in the spectrum of the FU Orionis star V1057 Cyg. The other 6 of the 13 stars have spectra showing a strong absorption band, peaking in strength at 5.6-5.7 μm, which for some is consistent with gaseous formaldehyde (H{sub 2}CO) and for others is consistent with gaseous formic acid (HCOOH). There are indications that some of these six stars may also have weak water vapor emission. Modeling of these stars' spectra suggests these gases are present in the inner few AU of their host disks, consistent with recent studies of infrared spectra showing gas in protoplanetary disks.

  16. ARM - PI Product - AERIoe Thermodynamic Profile and Cloud Retrieval for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MC3E Garber X-band site (I5) Garber X-band site (I5) ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : AERIoe Thermodynamic Profile and Cloud Retrieval for MC3E Garber X-band site (I5) [ ARM research ] The AERIoe algorithm retrieves profiles of temperature and water vapor mixing ratio, together with cloud properties for a single-layer cloud (i.e., LWP, effective radius), from AERI-observed infrared

  17. ARM - PI Product - AERIoe Thermodynamic Profile and Cloud Retrieval for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MC3E Lamont X-band site (I6) Lamont X-band site (I6) ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : AERIoe Thermodynamic Profile and Cloud Retrieval for MC3E Lamont X-band site (I6) [ ARM research ] The AERIoe algorithm retrieves profiles of temperature and water vapor mixing ratio, together with cloud properties for a single-layer cloud (i.e., LWP, effective radius), from AERI-observed infrared

  18. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M.; McRae, Thomas G.

    1985-01-01

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  19. Water vapor and temperature inversions near the 0 deg C level over the tropical western Pacific. Master's thesis

    SciTech Connect (OSTI)

    Hart, K.A.

    1994-01-01

    During the Intensive Observation Period (IOP), several periods of water vapor and temperature inversions near the 0 deg C level were observed. Satellite and radiosonde data from TOGA COARE are used to document the large-scale conditions and thermodynamic and kinematic structures present during three extended periods in which moisture and temperature inversions near the freezing level were very pronounced. Observations from each case are synthesized into schematics which represent typical structures of the inversion phenomena. Frequency distributions of the inversion phenomena along with climatological humidity and temperature profiles are calculated for the four-month IOP.

  20. Arctic Mixed-Phase Cloud Properties from AERI Lidar Observations: Algorithm and Results from SHEBA

    SciTech Connect (OSTI)

    Turner, David D.

    2005-04-01

    A new approach to retrieve microphysical properties from mixed-phase Arctic clouds is presented. This mixed-phase cloud property retrieval algorithm (MIXCRA) retrieves cloud optical depth, ice fraction, and the effective radius of the water and ice particles from ground-based, high-resolution infrared radiance and lidar cloud boundary observations. The theoretical basis for this technique is that the absorption coefficient of ice is greater than that of liquid water from 10 to 13 ?m, whereas liquid water is more absorbing than ice from 16 to 25 ?m. MIXCRA retrievals are only valid for optically thin (?visible < 6) single-layer clouds when the precipitable water vapor is less than 1 cm. MIXCRA was applied to the Atmospheric Emitted Radiance Interferometer (AERI) data that were collected during the Surface Heat Budget of the Arctic Ocean (SHEBA) experiment from November 1997 to May 1998, where 63% of all of the cloudy scenes above the SHEBA site met this specification. The retrieval determined that approximately 48% of these clouds were mixed phase and that a significant number of clouds (during all 7 months) contained liquid water, even for cloud temperatures as low as 240 K. The retrieved distributions of effective radii for water and ice particles in single-phase clouds are shown to be different than the effective radii in mixed-phase clouds.

  1. Effect of Water Vapor on the 1100oC Oxidation Behavior of Plasma-Sprayed TBCs with HVOF NiCoCrAlX Bond Coatings

    SciTech Connect (OSTI)

    Haynes, James A; Unocic, Kinga A; Pint, Bruce A

    2013-01-01

    With the goal of investigating the reported detrimental effect of water vapor on thermal barrier coating (TBC) performance, furnace cycle experiments were conducted in dry O2 and air with 10 and 50% water vapor at 1100 C. The TBC systems evaluated were air plasma-sprayed (APS), yttria-stabilized zirconia (YSZ) top coatings with high velocity oxy fuel (HVOF)-deposited NiCoCrAlY or NiCoCrAlYHfSi bond coating. Average TBC lifetime was reduced by ~30% in air with 10% water vapor compared to cycling in dry O2, using 1h cycle durations. Superalloy substrates with Y and La additions also were investigated but showed no statistical change in the average TBC lifetime compared to the base CMSX4 superalloy. In all cases, the bond coating with Hf and Si additions increased YSZ lifetime by 20% or more. Experiments that increased water vapor to 50% showed no further decrease in TBC lifetime. Increasing the cycle frequency to 100h resulted in a large increase in TBC lifetime, especially for the NiCoCrAlYHfSi bond coatings. Co-doping the NiCoCrAl bond coat with Y and Hf was beneficial to TBC lifetime, but did not mitigate the detrimental impact of water vapor.

  2. Comparison of Cirrus Cloud Radiative Properties and Dynamical Processes at Two Atmospheric Radiation Measurement (ARM) Si...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cirrus Cloud Radiative Properties and Dynamical Processes at Two Atmospheric Radiation Measurement Sites in the Tropical Western Pacific J. M. Comstock, J. H. Mather, and T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington Introduction Upper tropospheric humidity plays an important role in the formation and maintenance of tropical cirrus clouds. Deep convection is crucial for the transport of water vapor from the boundary layer to the upper troposphere and is

  3. Satellite determination of stratus cloud microphysical properties...

    Office of Scientific and Technical Information (OSTI)

    of liquid water path from SSMI, broadband albedo from ERBE, and cloud characteristics from ISCCP are used to study stratus regions. An average cloud liquid water path of ...

  4. Observation of hydroxymethyl hydroperoxide in a reaction system containing CH{sub 2}OO and water vapor through pure rotational spectroscopy

    SciTech Connect (OSTI)

    Nakajima, Masakazu; Endo, Yasuki

    2015-10-28

    Pure rotational transitions of hydroxymethyl hydroperoxide (HMHP) were observed in the discharged plasma of a CH{sub 2}I{sub 2}/O{sub 2}/water gas mixture, where the water complex with the simplest Criegee intermediate CH{sub 2}OO has been identified [M. Nakajima and Y. Endo, J. Chem. Phys. 140, 134302 (2014)]. Isotope experiments using heavy water support that the currently observed HMHP molecule was produced by the reaction of CH{sub 2}OO with water vapor. The observed species was identified as the most stable conformer with the help of quantum chemical calculations. We also clarified that productions of formic acid and dioxirane are promoted by the existence of water vapor in the discharged reaction system.

  5. The Use of Water Vapor as a Refrigerant: Impact of Cycle Modifications on Commercial Viability

    SciTech Connect (OSTI)

    Brandon F. Lachner, Jr.; Gregory F. Nellis; Douglas T. Reindl

    2004-08-30

    This project investigated the economic viability of using water as the refrigerant in a 1000-ton chiller application. The most attractive water cycle configuration was found to be a flash-intercooled, two-stage cycle using centrifugal compressors and direct contact heat exchangers. Component level models were developed that could be used to predict the size and performance of the compressors and heat exchangers in this cycle as well as in a baseline, R-134a refrigeration cycle consistent with chillers in use today. A survey of several chiller manufacturers provided information that was used to validate and refine these component models. The component models were integrated into cycle models that were subsequently used to investigate the life-cycle costs of both an R-134a and water refrigeration cycle. It was found that the first cost associated with the water as a refrigerant cycle greatly exceeded the savings in operating costs associated with its somewhat higher COP. Therefore, the water refrigeration cycle is not an economically attractive option to today's R-134a refrigeration system. There are a number of other issues, most notably the requirements associated with purging non-condensable gases that accumulate in a direct contact heat exchanger, which will further reduce the economic viability of the water cycle.

  6. Microphysical Consequences of the Spatial Distribution of Ice Nucleation in Mixed-Phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, Fan; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2014-07-28

    Mixed-phase stratiform clouds can persist even with steady ice precipitation fluxes, and the origin and microphysical properties of the ice crystals are of interest. Vapor deposition growth and sedimentation of ice particles along with a uniform volume source of ice nucleation, leads to a power law relation between ice water content wi and ice number concentration ni with exponent 2.5. The result is independent of assumptions about the vertical velocity structure of the cloud and is therefore more general than the related expression of Yang et al. [2013]. The sensitivity of the wi-ni relationship to the spatial distribution of ice nucleation is confirmed by Lagrangian tracking and ice growth with cloud-volume, cloud-top, and cloud-base sources of ice particles through a time-dependent cloud field. Based on observed wi and ni from ISDAC, a lower bound of 0.006 m^3/s is obtained for the ice crystal formation rate.

  7. Minimalist Model of Ice Microphysics in Mixed-phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, F.; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2013-07-28

    The question of whether persistent ice crystal precipitation from super cooled layer clouds can be explained by time-dependent, stochastic ice nucleation is explored using an approximate, analytical model, and a large-eddy simulation (LES) cloud model. The updraft velocity in the cloud defines an accumulation zone, where small ice particles cannot fall out until they are large enough, which will increase the residence time of ice particles in the cloud. Ice particles reach a quasi-steady state between growth by vapor deposition and fall speed at cloud base. The analytical model predicts that ice water content (wi) has a 2.5 power law relationship with ice number concentration ni. wi and ni from a LES cloud model with stochastic ice nucleation also confirm the 2.5 power law relationship. The prefactor of the power law is proportional to the ice nucleation rate, and therefore provides a quantitative link to observations of ice microphysical properties.

  8. ARM - PI Product - AERIoe Thermodynamic Profile and Cloud Retrieval for SGP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CF during LABLE-2012 2 ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : AERIoe Thermodynamic Profile and Cloud Retrieval for SGP CF during LABLE-2012 [ ARM research ] The AERIoe algorithm retrieves profiles of temperature and water vapor mixing ratio, together with cloud properties for a single-layer cloud (i.e., LWP, effective radius), from AERI-observed infrared radiance spectrum. The method is a

  9. ARM - PI Product - AERIoe Thermodynamic Profile and Cloud Retrieval for SGP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CF during LABLE-2013 3 ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : AERIoe Thermodynamic Profile and Cloud Retrieval for SGP CF during LABLE-2013 [ ARM research ] The AERIoe algorithm retrieves profiles of temperature and water vapor mixing ratio, together with cloud properties for a single-layer cloud (i.e., LWP, effective radius), from AERI-observed infrared radiance spectrum. The method is a

  10. Evaluation of Mixed-Phase Cloud Microphysics Parameterizations...

    Office of Scientific and Technical Information (OSTI)

    the partitioning of condensed water into liquid droplets and ice crystals in these Arctic clouds, which affect modeled cloud phase, cloud lifetime and radiative properties. ...

  11. IR and SFG vibrational spectroscopy of the water bend in the bulk liquid and at the liquid-vapor interface, respectively

    SciTech Connect (OSTI)

    Ni, Yicun; Skinner, J. L.

    2015-07-07

    Vibrational spectroscopy of the water bending mode has been investigated experimentally to study the structure of water in condensed phases. In the present work, we calculate the theoretical infrared (IR) and sum-frequency generation (SFG) spectra of the HOH bend in liquid water and at the water liquid/vapor interface using a mixed quantum/classical approach. Classical molecular dynamics simulation is performed by using a recently developed water model that explicitly includes three-body interactions and yields a better description of the water surface. Ab-initio-based transition frequency, dipole, polarizability, and intermolecular coupling maps are developed for the spectral calculations. The calculated IR and SFG spectra show good agreement with the experimental measurements. In the theoretical imaginary part of the SFG susceptibility for the water liquid/vapor interface, we find two features: a negative band centered at 1615 cm{sup −1} and a positive band centered at 1670 cm{sup −1}. We analyze this spectrum in terms of the contributions from molecules in different hydrogen-bond classes to the SFG spectral density and also compare to SFG results for the OH stretch. SFG of the water bending mode provides a complementary picture of the heterogeneous hydrogen-bond configurations at the water surface.

  12. “Lidar Investigations of Aerosol, Cloud, and Boundary Layer Properties Over the ARM ACRF Sites”

    SciTech Connect (OSTI)

    Ferrare, Richard; Turner, David

    2015-01-13

    Project goals; Characterize the aerosol and ice vertical distributions over the ARM NSA site, and in particular to discriminate between elevated aerosol layers and ice clouds in optically thin scattering layers; Characterize the water vapor and aerosol vertical distributions over the ARM Darwin site, how these distributions vary seasonally, and quantify the amount of water vapor and aerosol that is above the boundary layer; Use the high temporal resolution Raman lidar data to examine how aerosol properties vary near clouds; Use the high temporal resolution Raman lidar and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds; and Use the high temporal Raman lidar data to continue to characterize the turbulence within the convective boundary layer and how the turbulence statistics (e.g., variance, skewness) is correlated with larger scale variables predicted by models.

  13. Scanning ARM Cloud Radars Part I: Operational Sampling Strategies

    SciTech Connect (OSTI)

    Kollias, Pavlos; Bharadwaj, Nitin; Widener, Kevin B.; Jo, Ieng; Johnson, Karen

    2014-03-01

    Probing clouds in three-dimensions has never been done with scanning millimeter-wavelength (cloud) radars in a continuous operating environment. The acquisition of scanning cloud radars by the Atmospheric Radiation Measurement (ARM) program and research institutions around the world generate the need for developing operational scan strategies for cloud radars. Here, the first generation of sampling strategies for the Scanning ARM Cloud Radars (SACRs) is discussed. These scan strategies are designed to address the scientific objectives of the ARM program, however, they introduce an initial framework for operational scanning cloud radars. While the weather community uses scan strategies that are based on a sequence of scans at constant elevations, the SACRs scan strategies are based on a sequence of scans at constant azimuth. This is attributed to the cloud properties that are vastly different for rain and snow shafts that are the primary target of precipitation radars. A cloud surveillance scan strategy is introduced (HS-RHI) based on a sequence of horizon-to-horizon Range Height Indicator (RHI) scans that sample the hemispherical sky (HS). The HS-RHI scan strategy is repeated every 30 min to provide a static view of the cloud conditions around the SACR location. Between HS-RHI scan strategies other scan strategies are introduced depending on the cloud conditions. The SACRs are pointing vertically in the case of measurable precipitation at the ground. The radar reflectivities are corrected for water vapor attenuation and non-meteorological detection are removed. A hydrometeor detection mask is introduced based on the difference of cloud and noise statistics is discussed.

  14. A comparison of cloud properties at a coastal and inland site...

    Office of Scientific and Technical Information (OSTI)

    have examined differences in cloud liquid water paths (LWPs) at a coastal (Barrow) and an ... KEYWORDS: arctic clouds, cloud liquid water, microwave radiometer, ECMWF model, ...

  15. Adsorption characteristics of water vapor on gear-pellet and honeycomb-pellet types of adsorbents containing A-type zeolite

    SciTech Connect (OSTI)

    Nakamura, A.; Munakata, K.; Hara, K.; Narita, S.; Sugiyama, T.; Kotoh, K.; Tanaka, M.; Uda, T.

    2015-03-15

    It is necessary to recover or process tritiated species that are extensively coexistent in nuclear fusion installations. A conventional way to recover tritium release to atmosphere is catalytic oxidation of tritiated species and adsorption of tritiated water vapor on adsorbents with high surface areas. Therefore, new adsorbents with low pressure loss and high surface areas need to be developed and utilized for such large-scale adsorption systems. In this study, attention was focused on new adsorbents, which are gear-type pellet MS5A adsorbent, gear-type pellet MS4A adsorbent and honeycomb-type pellet MS5A adsorbent. The adsorption characteristics of the new adsorbent were comparatively studied with conventional type of adsorbents (pellet-type MS5A adsorbent and pebble-type MS5A adsorbent), in terms of adsorption capacity, pressure loss and adsorption rate. It was found that the adsorption capacity of water vapor on the gear-type adsorbents is higher than that on a honeycomb-type adsorbent. The experimental breakthrough curves indicate that the adsorption rates of water vapor on gear-type and honeycomb-type adsorbents are smaller than that on conventional type adsorbents. Various adsorption models were also tested to correlate the experimental isotherms. It was found that the Langmuir-Freundlich model could properly correlate the experimental adsorption isotherms.

  16. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    2008-01-15

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  17. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  18. Tropical Cloud Properties and Radiative Heating Profiles

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mather, James

    2008-01-15

    We have generated a suite of products that includes merged soundings, cloud microphysics, and radiative fluxes and heating profiles. The cloud microphysics is strongly based on the ARM Microbase value added product (Miller et al., 2003). We have made a few changes to the microbase parameterizations to address issues we observed in our initial analysis of the tropical data. The merged sounding product is not directly related to the product developed by ARM but is similar in that it uses the microwave radiometer to scale the radiosonde column water vapor. The radiative fluxes also differ from the ARM BBHRP (Broadband Heating Rate Profile) product in terms of the radiative transfer model and the sampling interval.

  19. Tropical Cloud Properties and Radiative Heating Profiles

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mather, James

    We have generated a suite of products that includes merged soundings, cloud microphysics, and radiative fluxes and heating profiles. The cloud microphysics is strongly based on the ARM Microbase value added product (Miller et al., 2003). We have made a few changes to the microbase parameterizations to address issues we observed in our initial analysis of the tropical data. The merged sounding product is not directly related to the product developed by ARM but is similar in that it uses the microwave radiometer to scale the radiosonde column water vapor. The radiative fluxes also differ from the ARM BBHRP (Broadband Heating Rate Profile) product in terms of the radiative transfer model and the sampling interval.

  20. Scanning ARM Cloud Radar Handbook

    SciTech Connect (OSTI)

    Widener, K; Bharadwaj, N; Johnson, K

    2012-06-18

    The scanning ARM cloud radar (SACR) is a polarimetric Doppler radar consisting of three different radar designs based on operating frequency. These are designated as follows: (1) X-band SACR (X-SACR); (2) Ka-band SACR (Ka-SACR); and (3) W-band SACR (W-SACR). There are two SACRs on a single pedestal at each site where SACRs are deployed. The selection of the operating frequencies at each deployed site is predominantly determined by atmospheric attenuation at the site. Because RF attenuation increases with atmospheric water vapor content, ARM's Tropical Western Pacific (TWP) sites use the X-/Ka-band frequency pair. The Southern Great Plains (SGP) and North Slope of Alaska (NSA) sites field the Ka-/W-band frequency pair. One ARM Mobile Facility (AMF1) has a Ka/W-SACR and the other (AMF2) has a X/Ka-SACR.

  1. Final Report on the Development of an Improved Cloud Microphysical...

    Office of Scientific and Technical Information (OSTI)

    Facilities (AAF) Clouds with Low Optical Water Depths (CLOWD) Optical Radiative ... integrated over all bin sizes, liquid water content LWC, extinction of liquid clouds ...

  2. Cirrus clouds in a global climate model with a statistical cirrus cloud scheme

    SciTech Connect (OSTI)

    Wang, Minghuai; Penner, Joyce E.

    2010-06-21

    A statistical cirrus cloud scheme that accounts for mesoscale temperature perturbations is implemented in a coupled aerosol and atmospheric circulation model to better represent both subgrid-scale supersaturation and cloud formation. This new scheme treats the effects of aerosol on cloud formation and ice freezing in an improved manner, and both homogeneous freezing and heterogeneous freezing are included. The scheme is able to better simulate the observed probability distribution of relative humidity compared to the scheme that was implemented in an older version of the model. Heterogeneous ice nuclei (IN) are shown to decrease the frequency of occurrence of supersaturation, and improve the comparison with observations at 192 hPa. Homogeneous freezing alone can not reproduce observed ice crystal number concentrations at low temperatures (<205 K), but the addition of heterogeneous IN improves the comparison somewhat. Increases in heterogeneous IN affect both high level cirrus clouds and low level liquid clouds. Increases in cirrus clouds lead to a more cloudy and moist lower troposphere with less precipitation, effects which we associate with the decreased convective activity. The change in the net cloud forcing is not very sensitive to the change in ice crystal concentrations, but the change in the net radiative flux at the top of the atmosphere is still large because of changes in water vapor. Changes in the magnitude of the assumed mesoscale temperature perturbations by 25% alter the ice crystal number concentrations and the net radiative fluxes by an amount that is comparable to that from a factor of 10 change in the heterogeneous IN number concentrations. Further improvements on the representation of mesoscale temperature perturbations, heterogeneous IN and the competition between homogeneous freezing and heterogeneous freezing are needed.

  3. Vapor-liquid Equilibria and Polarization Behavior of the GCP Water Model: Gaussian Charge-on-spring versus Dipole Self-consistent Field approaches to induced polarization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chialvo, Ariel A; Moucka, Filip; Vlcek, Lukas; Nezbeda, Ivo

    2015-01-01

    We implemented the Gaussian charge-on-spring (GCOS) version of the original self-consistent field implementation of the Gaussian Charge Polarizable water model and test its accuracy to represent the polarization behavior of the original model involving smeared charges and induced dipole moments. For that purpose we adapted the recently developed multiple-particle-move (MPM) within the Gibbs and isochoric-isothermal ensembles Monte Carlo methods for the efficient simulation of polarizable fluids. We assessed the accuracy of the GCOS representation by a direct comparison of the resulting vapor-liquid phase envelope, microstructure, and relevant microscopic descriptors of water polarization along the orthobaric curve against the corresponding quantitiesmore » from the actual GCP water model.« less

  4. Vapor concentration monitor

    DOE Patents [OSTI]

    Bayly, John G.; Booth, Ronald J.

    1977-01-01

    An apparatus for monitoring the concentration of a vapor, such as heavy water, having at least one narrow bandwidth in its absorption spectrum, in a sample gas such as air. The air is drawn into a chamber in which the vapor content is measured by means of its radiation absorption spectrum. High sensitivity is obtained by modulating the wavelength at a relatively high frequency without changing its optical path, while high stability against zero drift is obtained by the low frequency interchange of the sample gas to be monitored and of a reference sample. The variable HDO background due to natural humidity is automatically corrected.

  5. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    SciTech Connect (OSTI)

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, Allen B.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-01-03

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for

  6. Aircraft-measured indirect cloud effects from biomass burning smoke in the Arctic and subarctic

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zamora, L. M.; Kahn, R. A.; Cubison, M. J.; Diskin, G. S.; Jimenez, J. L.; Kondo, Y.; McFarquhar, G. M.; Nenes, A.; Thornhill, K. L.; Wisthaler, A.; et al

    2016-01-21

    The incidence of wildfires in the Arctic and subarctic is increasing; in boreal North America, for example, the burned area is expected to increase by 200–300% over the next 50–100 years, which previous studies suggest could have a large effect on cloud microphysics, lifetime, albedo, and precipitation. However, the interactions between smoke particles and clouds remain poorly quantified due to confounding meteorological influences and remote sensing limitations. Here, we use data from several aircraft campaigns in the Arctic and subarctic to explore cloud microphysics in liquid-phase clouds influenced by biomass burning. Median cloud droplet radii in smoky clouds were ~40–60% smallermore » than in background clouds. Based on the relationship between cloud droplet number (Nliq) and various biomass burning tracers (BBt) across the multi-campaign data set, we calculated the magnitude of subarctic and Arctic smoke aerosol–cloud interactions (ACIs, where ACI = (1/3) × dln(Nliq)/dln(BBt)) to be ~0.16 out of a maximum possible value of 0.33 that would be obtained if all aerosols were to nucleate cloud droplets. Interestingly, in a separate subarctic case study with low liquid water content (~0.02gm–3) and very high aerosol concentrations (2000–3000 cm–3) in the most polluted clouds, the estimated ACI value was only 0.05. In this case, competition for water vapor by the high concentration of cloud condensation nuclei (CCN) strongly limited the formation of droplets and reduced the cloud albedo effect, which highlights the importance of cloud feedbacks across scales. Using our calculated ACI values, we estimate that the smoke-driven cloud albedo effect may decrease local summertime short-wave radiative flux by between 2 and 4 Wm–2 or more under some low and homogeneous cloud cover conditions in the subarctic, although the changes should be smaller in high surface albedo regions of the Arctic. Furthermore, we lastly explore evidence suggesting that

  7. Observed correlations between aerosol and cloud properties in an Indian Ocean trade cumulus regime

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pistone, Kristina; Praveen, Puppala S.; Thomas, Rick M.; Ramanathan, Veerabhadran; Wilcox, Eric M.; Bender, Frida A.-M.

    2016-04-27

    There are many contributing factors which determine the micro- and macrophysical properties of clouds, including atmospheric vertical structure, dominant meteorological conditions, and aerosol concentration, all of which may be coupled to one another. In the quest to determine aerosol effects on clouds, these potential relationships must be understood. Here we describe several observed correlations between aerosol conditions and cloud and atmospheric properties in the Indian Ocean winter monsoon season.In the CARDEX (Cloud, Aerosol, Radiative forcing, Dynamics EXperiment) field campaign conducted in February and March 2012 in the northern Indian Ocean, continuous measurements were made of atmospheric precipitable water vapor (PWV)more » and the liquid water path (LWP) of trade cumulus clouds, concurrent with measurements of water vapor flux, cloud and aerosol vertical profiles, meteorological data, and surface and total-column aerosol from instrumentation at a ground observatory and on small unmanned aircraft. We present observations which indicate a positive correlation between aerosol and cloud LWP only when considering cases with low atmospheric water vapor (PWV < 40 kg m–2), a criterion which acts to filter the data to control for the natural meteorological variability in the region.We then use the aircraft and ground-based measurements to explore possible mechanisms behind this observed aerosol–LWP correlation. The increase in cloud liquid water is found to coincide with a lowering of the cloud base, which is itself attributable to increased boundary layer humidity in polluted conditions. High pollution is found to correlate with both higher temperatures and higher humidity measured throughout the boundary layer. A large-scale analysis, using satellite observations and meteorological reanalysis, corroborates these covariations: high-pollution cases are shown to originate as a highly polluted boundary layer air mass approaching the observatory from a

  8. IMPROVED MAGNUS' FORM OF SATURATION VAPOR PRESSURE Oleg A. Alduchov...

    Office of Scientific and Technical Information (OSTI)

    We will show that two of the new formulations of vapor pressure over water and ice are ... The most precise formulation of vapor pressure over a plane surface of water was given by ...

  9. ARM Cloud Aerosol Precipitation Experiment (ACAPEX) Science Plan

    SciTech Connect (OSTI)

    Leung, L. R.; Prather, K.; Ralph, R.; Rosenfeld, D.; Spackman, R.; DeMott, P.; Fairall, C.; Fan, J.; Hagos, S.; Hughes, M.; Long, C.; Rutledge, S.; Waliser, D.; Wang, H.

    2014-09-01

    The western U.S. receives precipitation predominantly during the cold season when storms approach from the Pacific Ocean. The snowpack that accumulates during winter storms provides about 70-90% of water supply for the region. Understanding and modeling the fundamental processes that govern the large precipitation variability and extremes in the western U.S. is a critical test for the ability of climate models to predict the regional water cycle, including floods and droughts. Two elements of significant importance in predicting precipitation variability in the western U.S. are atmospheric rivers and aerosols. Atmospheric rivers (ARs) are narrow bands of enhanced water vapor associated with the warm sector of extratropical cyclones over the Pacific and Atlantic oceans. Because of the large lower-tropospheric water vapor content, strong atmospheric winds and neutral moist static stability, some ARs can produce heavy precipitation by orographic enhancement during landfall on the U.S. West Coast. While ARs are responsible for a large fraction of heavy precipitation in that region during winter, much of the rest of the orographic precipitation occurs in post-frontal clouds, which are typically quite shallow, with tops just high enough to pass the mountain barrier. Such clouds are inherently quite susceptible to aerosol effects on both warm rain and ice precipitation-forming processes.

  10. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ...

  11. Understanding and Improving CRM and GCM Simulations of Cloud...

    Office of Scientific and Technical Information (OSTI)

    of convection, clouds and radiative heating rate and fluxes using the ARM ... as well as cloud water contents in producing net radiative fluxes closer to observations. ...

  12. Multiwavelength observations of a devleoping cloud system: The FIRE II 26 November 1991 case study

    SciTech Connect (OSTI)

    Intrieri, J.M.; Eberhard, W.L.; Uttal, T.

    1995-12-01

    Simultaneous multiwavelength measurements of a developing cloud system were obtained by NOAA Doppler lidar, Doppler radar, Fourier transform infrared interferometer, and microwave and infrared radiometers on 26 November 1991. The evolution of the cloud system is described in terms of lidar backscatter, radar reflectivity and velocity, interferometer atmospheric spectra, and radiometer brightness temperature, integrated liquid water, and water vapor paths. Utilizing the difference in wavelength between the radar and lidar, and therefore their independent sensitivity to different regions of the same cloud, the cloud top, base, depth, and multiple layer heights can be determined with better accuracy than with either instrument alone. Combining the radar, lidar, and radiometer measurements using two different techniques allows an estimation of the vertical profile of cloud microphysical properties such as particle sizes. Enhancement of lidar backscatter near zenith revealed when highly oriented ice crystals were present. The authors demonstrate that no single instrument is sufficient to accurately describe cirrus clouds and that measurements in combination can provide important details on their geometric, radiative, and microphysical properties.

  13. Vapor Barriers or Vapor Diffusion Retarders | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Moisture Control Vapor Barriers or Vapor Diffusion Retarders Vapor Barriers or Vapor ... can be part of an overall moisture control strategy for your home. | Photo courtesy ...

  14. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS Citation Details In-Document Search Title: VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY ...

  15. Understanding Ice Supersaturation, Particle Growth, and Number Concentration in Cirrus Clouds

    SciTech Connect (OSTI)

    Comstock, Jennifer M.; Lin, Ruei-Fong; Starr, David O.; Yang, P.

    2008-12-10

    Many factors control the ice supersaturation and microphysical properties in cirrus clouds. We explore the effects of dynamic forcing, ice nucleation mechanisms, and ice crystal growth rate on the evolution and distribution of water vapor and cloud properties in cirrus clouds using a detailed microphysical model and remote sensing measurements obtained at the Department of Energys Atmospheric Radiation Measurement (ARM) Climate Research Facility located near Lamont, OK. To help understand dynamic scales important in cirrus formation, we force the model using both large-scale forcing derived using ARM variational analysis, and mean mesoscale velocity derived from radar Doppler velocity measurements. Both heterogeneous and homogeneous nucleation processes are explored, where we have implemented a rigorous classical theory heterogeneous nucleation scheme to compare with empirical representations. We evaluate model simulations by examining both bulk cloud properties and distributions of measured radar reflectivity, lidar extinction, and water vapor profiles, as well as retrieved cloud microphysical properties. This approach allows for independent verification of both the large and small particle modes of the particle size distribution. Our results suggest that mesoscale variability is the primary mechanism needed to reproduce observed quantities, while nucleation mechanism is secondary. Slow ice crystal growth tends to overestimate the number of small ice crystals, but does not seem to influence bulk properties such as ice water path and cloud thickness. The most realistic simulations as compared with observations are forced using mesoscale waves, include fast ice crystal growth, and initiate ice by either homogeneous or heterogeneous nucleation. Ice crystal number concentrations on the order of 10-100 L-1 produce results consistent with both lidar and radar observations during a cirrus event observed on 7 December 1999, which has an optical depth range typical of

  16. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  17. ARM Cloud Properties Working Group: Meeting Logistics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to 1630: J. Comstock - Clouds with Low Optical Water Depth (CLOWD) 1630 to 1645: B. Albrecht - Clouds, Aerosol, and Precipitation in the Marine Boundary Layer (CLAP-MBL) 1645 to ...

  18. The Role of Shallow Cloud Moistening in MJO and Non-MJO Convective...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to quantify bulk shallow cloud moistening through evaporation of condensed water using a simple method based on observations of liquid water path, cloud depth and temporal...

  19. ARM - Measurement - Cloud size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measurements as cloud thickness, cloud area, and cloud aspect ratio. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  20. Vapor spill pipe monitor

    DOE Patents [OSTI]

    Bianchini, G.M.; McRae, T.G.

    1983-06-23

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

  1. Long Term Field Development of a Surfactant Modified Zeolite/Vapor Phase Bioreactor System for Treatment of Produced Waters for Power Generation

    SciTech Connect (OSTI)

    Lynn Katz; Kerry Kinney; Robert Bowman; Enid Sullivan; Soondong Kwon; Elaine Darby; Li-Jung Chen; Craig Altare

    2007-12-31

    The main goal of this research was to investigate the feasibility of using a combined physicochemical/biological treatment system to remove the organic constituents present in saline produced water. In order to meet this objective, a physical/chemical adsorption process was developed and two separate biological treatment techniques were investigated. Two previous research projects focused on the development of the surfactant modified zeolite adsorption process (DE-AC26-99BC15221) and development of a vapor phase biofilter (VPB) to treat the regeneration off-gas from the surfactant modified zeolite (SMZ) adsorption system (DE-FC26-02NT15461). In this research, the SMZ/VPB was modified to more effectively attenuate peak loads and to maintain stable biodegradation of the BTEX constituents from the produced water. Specifically, a load equalization system was incorporated into the regeneration flow stream. In addition, a membrane bioreactor (MBR) system was tested for its ability to simultaneously remove the aromatic hydrocarbon and carboxylate components from produced water. The specific objectives related to these efforts included the following: (1) Optimize the performance VPBs treating the transient loading expected during SMZ regeneration: (a) Evaluate the impact of biofilter operating parameters on process performance under stable operating conditions. (b) Investigate how transient loads affect biofilter performance, and identify an appropriate technology to improve biological treatment performance during the transient regeneration period of an SMZ adsorption system. (c) Examine the merits of a load equalization technology to attenuate peak VOC loads prior to a VPB system. (d) Evaluate the capability of an SMZ/VPB to remove BTEX from produced water in a field trial. (2) Investigate the feasibility of MBR treatment of produced water: (a) Evaluate the biodegradation of carboxylates and BTEX constituents from synthetic produced water in a laboratory-scale MBR. (b

  2. Work function variation of MoS{sub 2} atomic layers grown with chemical vapor deposition: The effects of thickness and the adsorption of water/oxygen molecules

    SciTech Connect (OSTI)

    Kim, Jong Hun; Kim, Jae Hyeon; Park, Jeong Young E-mail: jeongypark@kaist.ac.kr; Lee, Jinhwan; Hwang, C. C.; Lee, Changgu E-mail: jeongypark@kaist.ac.kr

    2015-06-22

    The electrical properties of two-dimensional atomic sheets exhibit remarkable dependences on layer thickness and surface chemistry. Here, we investigated the variation of the work function properties of MoS{sub 2} films prepared with chemical vapor deposition (CVD) on SiO{sub 2} substrates with the number of film layers. Wafer-scale CVD MoS{sub 2} films with 2, 4, and 12 layers were fabricated on SiO{sub 2}, and their properties were evaluated by using Raman and photoluminescence spectroscopies. In accordance with our X-ray photoelectron spectroscopy results, our Kelvin probe force microscopy investigation found that the surface potential of the MoS{sub 2} films increases by ∼0.15 eV when the number of layers is increased from 2 to 12. Photoemission spectroscopy (PES) with in-situ annealing under ultra high vacuum conditions was used to directly demonstrate that this work function shift is associated with the screening effects of oxygen or water molecules adsorbed on the film surface. After annealing, it was found with PES that the surface potential decreases by ∼0.2 eV upon the removal of the adsorbed layers, which confirms that adsorbed species have a role in the variation in the work function.

  3. Dual-wavelength millimeter-wave radar measurements of cirrus clouds

    SciTech Connect (OSTI)

    Sekelsky, S.M.; Firda, J.M.; McIntosh, R.E.

    1996-04-01

    In April 1994, the University of Massachusetts` 33-GHz/95-GHz Cloud Profiling Radar System (CPRS) participated in the multi-sensor Remote Cloud Sensing (RCS) Intensive Operation Period (IOP), which was conducted at the Southern Great Plains Cloud and Radiation Testbed (CART). During the 3-week experiment, CPRS measured a variety of cloud types and severe weather. In the context of global warming, the most significant measurements are dual-frequency observations of cirrus clouds, which may eventually be used to estimate ice crystal size and shape. Much of the cirrus data collected with CPRS show differences between 33-GHz and 95-GHz reflectivity measurements that are correlated with Doppler estimates of fall velocity. Because of the small range of reflectivity differences, a precise calibration of the radar is required and differential attenuation must also be removed from the data. Depolarization, which is an indicator of crystal shape, was also observed in several clouds. In this abstract we present examples of Mie scattering from cirrus and estimates of differential attenuation due to water vapor and oxygen that were derived from CART radiosonde measurements.

  4. G-Band Vapor Radiometer Profiler (GVRP) Handbook

    SciTech Connect (OSTI)

    Caddeau, MP

    2010-06-23

    The G-Band Vapor Radiometer Profiler (GVRP) provides time-series measurements of brightness temperatures from 15 channels between 170 and 183.310 GHz. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. Channels between 170.0 and 176.0 GHz are particularly sensitive to the presence of liquid water. The sensitivity to water vapor of the 183.31-GHz line is approximately 30 times higher than at the frequencies of the two-channel microwave radiometer (MWR) for a precipitable water vapor (PWV) amount of less than 2.5 mm. Measurements from the GVRP instrument are therefore especially useful during low-humidity conditions (PWV < 5 mm). In addition to integrated water vapor and liquid water, the GVRP can provide low-resolution vertical profiles of water vapor in very dry conditions.

  5. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, John P.; Larson, Ronald A.; Goodrich, Lorenzo D.; Hall, Harold J.; Stoddard, Billy D.; Davis, Sean G.; Kaser, Timothy G.; Conrad, Frank J.

    1995-01-01

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet.

  6. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

    1995-09-26

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

  7. Direct Numerical Simulations and Robust Predictions of Cloud Cavitation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collapse | Argonne Leadership Computing Facility cavitating vapor bubbles above a solid wall This image shows cavitating vapor bubbles above a solid wall. The yellow is a visualization of the pressure peak in the center of the bubble cloud. Credit: Computational Science and Engineering Laboratory, ETH Zurich, Switzerland Direct Numerical Simulations and Robust Predictions of Cloud Cavitation Collapse PI Name: Petros Koumoutsakos PI Email: petros@ethz.ch Institution: ETH Zürich Allocation

  8. Lidar Investigations of Aerosol, Cloud, and Boundary Layer Properties Over the ARM ACRF Sites

    SciTech Connect (OSTI)

    Turner, David D.; Ferrare, Richard

    2015-01-13

    The systematic and routine measurements of aerosol, water vapor, and clouds in the vertical column above the Atmospheric Radiation Measurement (ARM) sites from surface-based remote sensing systems provides a unique and comprehensive data source that can be used to characterize the boundary layer (i.e., the lowest 3 km of the atmosphere) and its evolution. New algorithms have been developed to provide critical datasets from ARM instruments, and these datasets have been used in long-term analyses to better understand the climatology of water vapor and aerosol over Darwin, the turbulent structure of the boundary layer and its statistical properties over Oklahoma, and to better determine the distribution of ice and aerosol particles over northern Alaska.

  9. Joint retrievals of cloud and drizzle in marine boundary layer...

    Office of Scientific and Technical Information (OSTI)

    Specifically, the vertical structure of droplet size and water content of both cloud and ... cumulus under stratocumulus, where cloud water path is retrieved with an error of 31 g ...

  10. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS Citation Details In-Document Search Title: VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS You are ...

  11. ARM - Measurement - Cloud type

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement : Cloud type Cloud type such as cirrus, stratus, cumulus etc Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  12. RACORO continental boundary layer cloud investigations. 2. Large...

    Office of Scientific and Technical Information (OSTI)

    Facility AAF Clouds with Low Optical Water Depths CLOWD Optical Radiative ... droplet number concentration with liquid water content (LWC), corresponding to the ...

  13. Characterization of 3D Cirrus Cloud and Radiation Fields Using...

    Office of Scientific and Technical Information (OSTI)

    aerosol number concentration, ice cloud water path, and ice particle number ... effective ice crystal size (De) and ice water content (IWC) by dividing the atmosphere ...

  14. LNG fire and vapor control system technologies

    SciTech Connect (OSTI)

    Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

    1982-06-01

    This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

  15. Dispelling Clouds of Uncertainty

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lewis, Ernie; Teixeira, João

    2015-06-15

    How do you build a climate model that accounts for cloud physics and the transitions between cloud regimes? Use MAGIC.

  16. Vapor Barriers or Vapor Diffusion Retarders | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weatherize » Moisture Control » Vapor Barriers or Vapor Diffusion Retarders Vapor Barriers or Vapor Diffusion Retarders Vapor diffusion retarders installed in a crawlspace can be part of an overall moisture control strategy for your home. | Photo courtesy of Dennis Schroeder, NREL. Vapor diffusion retarders installed in a crawlspace can be part of an overall moisture control strategy for your home. | Photo courtesy of Dennis Schroeder, NREL. In most U.S. climates, vapor barriers, or -- more

  17. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    SciTech Connect (OSTI)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperature and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.

  18. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperaturemore » and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.« less

  19. Testing a New Cirrus Cloud Parameterizaton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing a New Cirrus Cloud Parameterization in NCAR CCM3 D. Zurovac-Jevtic, G. J. Zhang, and V. Ramanathan Center for Atmospheric Sciences Scripps Institute of Oceanography La Jolla, California Introduction Cirrus cloud cover and ice water content (IWC) are the two most important properties of cirrus clouds. However, in general circulation models (GCMs), their treatment is very crude. For example, in the National Center for Atmospheric Research (NCAR) Community Climate Model (CCM3), IWC is

  20. Vapor Pressures and Heats of Vaporization of Primary Coal Tars

    Office of Scientific and Technical Information (OSTI)

    ... Therefore, future research could be directed at measuring the vapor pressures for the ... The results from the current work show that measuring the vapor pressures of complicated ...

  1. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S.; Krajicek, Richard W.

    1981-01-01

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  2. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  3. ARM Cloud Aerosol Precipitation Experiment (ACAPEX) Science Plan...

    Office of Scientific and Technical Information (OSTI)

    Because of the large lower-tropospheric water vapor content, strong atmospheric winds and neutral moist static stability, some ARs can produce heavy precipitation by orographic ...

  4. Dispelling Clouds of Uncertainty

    SciTech Connect (OSTI)

    Lewis, Ernie; Teixeira, João

    2015-06-15

    How do you build a climate model that accounts for cloud physics and the transitions between cloud regimes? Use MAGIC.

  5. ARM - Measurement - Cloud location

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    point in space and time, typically expressed as a binary cloud mask. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  6. Near-field thermal radiative transfer and thermoacoustic effects from vapor plumes produced by pulsed CO{sub 2} laser ablation of bulk water

    SciTech Connect (OSTI)

    Kudryashov, S. I.; Lyon, Kevin; Allen, S. D.

    2006-12-15

    Submillimeter deep heating of bulk water by thermal radiation from ablative water plumes produced by a 10.6 {mu}m transversely excited atmospheric CO{sub 2} laser and the related acoustic generation has been studied using a contact time-resolved photoacoustic technique. Effective penetration depths of thermal radiation in water were measured as a function of incident laser fluence and the corresponding plume temperatures were estimated. The near-field thermal and thermoacoustic effects of thermal radiation in laser-ablated bulk water and their potential near-field implications are discussed.

  7. Effect of canopy structure and open-top chamber techniques on micrometeorological parameters and the gradients and transport of water vapor, carbon dioxide and ozone in the canopies of plum trees (`prunus salicina`) in the San Joaquin valley. Final report

    SciTech Connect (OSTI)

    Grantz, D.A.; Vaughn, D.L.; Metheny, P.A.; Malkus, P.; Wosnik, K.

    1995-03-15

    Plum trees (Prunus salicina cv. Casselman) were exposed to ozone in open-top chambers (OTC) or chamberless plots, and trace gas concentrations and microenvironmental conditions were monitored within tree canopies inside the outside the OTC. Concentrations of ozone, carbon dioxide and water vapor, leaf and air temperature, light intensity, and wind speed were measured at nine positions in the tree canopies. The objectives were to: (1) map the distribution of microenvironmental parameters within the canopies inside and outside the OTC; (2) determine transport parameters for gas exchange, and (3) calculate ozone flux. Significant vertical and horizontal gradients were observed; gradients were diminished and often inverted inside relative to outside the OTC due to air distribution at the bottom of the OCT. Ozone flux was readily modeled from measures of stomatal conductance, nonstomatal conductance and ozone concentration at the leaf surface.

  8. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1986-08-15

    The atomic vapor laser isotope separation (AVLIS) process for the enrichment of uranium is evaluated. (AIP)

  9. Developing and Evaluating Ice Cloud Parameterizations by

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by remote sensing is that the transfer functions which relate the observables (e. g., radar Doppler spectrum) to cloud properties (e. g., ice water content, or IWC) are not...

  10. Prediction of cloud droplet number in a general circulation model

    SciTech Connect (OSTI)

    Ghan, S.J.; Leung, L.R.

    1996-04-01

    We have applied the Colorado State University Regional Atmospheric Modeling System (RAMS) bulk cloud microphysics parameterization to the treatment of stratiform clouds in the National Center for Atmospheric Research Community Climate Model (CCM2). The RAMS predicts mass concentrations of cloud water, cloud ice, rain and snow, and number concnetration of ice. We have introduced the droplet number conservation equation to predict droplet number and it`s dependence on aerosols.

  11. Limiting Factors for Convective Cloud Top Height in the Tropics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Limiting Factors for Convective Cloud Top Height in the Tropics M. P. Jensen and A. D. Del Genio National Aeronautics and Space Administration Goddard Institute for Space Studies Columbia University New York, New York Introduction Populations of tropical convective clouds are mainly comprised of three types: shallow trade cumulus, mid-level cumulus congestus and deep convective clouds (Johnson et al. 1999). Each of these cloud types has different impacts on the local radiation and water budgets.

  12. Fundamental to the Cloud Land Surface Interaction Campaign (CLASIC...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in agriculture ranging from more accurate weather forecasting to improved water management decisions and crop yield estimation. CLASIC CLASIC - - LAND LAND Cloud and Land...

  13. Determining Best Estimates and Uncertainties in Cloud Microphysical...

    Office of Scientific and Technical Information (OSTI)

    Particles in Cirrus (SPARTICUS) Experiment and the Routine AAF Clouds with Low Optical Water Depths (CLOWD) Optical Radiative Observations (RACORO) field campaign, over the North ...

  14. A boundary-layer cloud study using Southern Great Plains Cloud and radiation testbed (CART) data

    SciTech Connect (OSTI)

    Albrecht, B.; Mace, G.; Dong, X.; Syrett, W.

    1996-04-01

    Boundary layer clouds-stratus and fairweather cumulus - are closely coupled involves the radiative impact of the clouds on the surface energy budget and the strong dependence of cloud formation and maintenance on the turbulent fluxes of heat and moisture in the boundary layer. The continuous data collection at the Southern Great Plains (SGP) Cloud and Radiation Testbed (CART) site provides a unique opportunity to study components of the coupling processes associated with boundary layer clouds and to provide descriptions of cloud and boundary layer structure that can be used to test parameterizations used in climate models. But before the CART data can be used for process studies and parameterization testing, it is necessary to evaluate and validate data and to develop techniques for effectively combining the data to provide meaningful descriptions of cloud and boundary layer characteristics. In this study we use measurements made during an intensive observing period we consider a case where low-level stratus were observed at the site for about 18 hours. This case is being used to examine the temporal evolution of cloud base, cloud top, cloud liquid water content, surface radiative fluxes, and boundary layer structure. A method for inferring cloud microphysics from these parameters is currently being evaluated.

  15. Science Cloud 2011

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Cloud 2011 Science Cloud 2011 June 17, 2011 The Magellan teams at NERSC and Argonne recently presented a joint paper detailing their progress and conclusions. At Science Cloud 2011: The Second Workshop on Scientific Cloud Computing, in a paper titled "Magellan: Experiences from a Science Cloud" (PDF, 320KB), lead author Lavanya Ramakrishnan outlined the groups' most recent achievements and conclusions, including a successful run of real-time data analysis for the STAR

  16. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, T.W.; Ault, E.R.; Moses, E.I.

    1992-12-01

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment. 2 figs.

  17. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, Terry W.; Ault, Earl R.; Moses, Edward I.

    1992-01-01

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

  18. Microwave and Millimeter-Wave Radiometric Studies of Temperature...

    Office of Scientific and Technical Information (OSTI)

    of Temperature, Water Vapor and Clouds Citation Details In-Document Search Title: Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds The ...

  19. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Energy Technology Engineering Center (ETEC), Canoga ... cloud, shallow convective cloud, and deep convective cloud. ... of temperature, water vapor, cloud liquid, and ...

  1. Cloud Properties Working Group Low Clouds Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Properties Working Group Low Clouds Update Low Clouds Update Jennifer Comstock Jennifer Comstock Dave Turner Dave Turner Andy Andy Vogelmann Vogelmann Instruments Instruments 90/150 GHz microwave radiometer 90/150 GHz microwave radiometer Deployed during COPS AMF Deployed during COPS AMF Exploring calibration w/ DPR ( Exploring calibration w/ DPR ( Crewell Crewell & & L L ö ö hnert hnert ) ) See COPS Breakout, Wednesday evening See COPS Breakout, Wednesday evening 183 GHz (GVR)

  2. Parameterizing Size Distribution in Ice Clouds

    SciTech Connect (OSTI)

    DeSlover, Daniel; Mitchell, David L.

    2009-09-25

    PARAMETERIZING SIZE DISTRIBUTIONS IN ICE CLOUDS David L. Mitchell and Daniel H. DeSlover ABSTRACT An outstanding problem that contributes considerable uncertainty to Global Climate Model (GCM) predictions of future climate is the characterization of ice particle sizes in cirrus clouds. Recent parameterizations of ice cloud effective diameter differ by a factor of three, which, for overcast conditions, often translate to changes in outgoing longwave radiation (OLR) of 55 W m-2 or more. Much of this uncertainty in cirrus particle sizes is related to the problem of ice particle shattering during in situ sampling of the ice particle size distribution (PSD). Ice particles often shatter into many smaller ice fragments upon collision with the rim of the probe inlet tube. These small ice artifacts are counted as real ice crystals, resulting in anomalously high concentrations of small ice crystals (D < 100 m) and underestimates of the mean and effective size of the PSD. Half of the cirrus cloud optical depth calculated from these in situ measurements can be due to this shattering phenomenon. Another challenge is the determination of ice and liquid water amounts in mixed phase clouds. Mixed phase clouds in the Arctic contain mostly liquid water, and the presence of ice is important for determining their lifecycle. Colder high clouds between -20 and -36 oC may also be mixed phase but in this case their condensate is mostly ice with low levels of liquid water. Rather than affecting their lifecycle, the presence of liquid dramatically affects the cloud optical properties, which affects cloud-climate feedback processes in GCMs. This project has made advancements in solving both of these problems. Regarding the first problem, PSD in ice clouds are uncertain due to the inability to reliably measure the concentrations of the smallest crystals (D < 100 m), known as the small mode. Rather than using in situ probe measurements aboard aircraft, we employed a treatment of ice cloud

  3. In-well vapor stripping drilling and characterization work plan

    SciTech Connect (OSTI)

    Koegler, K.J.

    1994-03-13

    This work plan provides the information necessary for drilling, sampling, and hydrologic testing of wells to be completed in support of a demonstration of the in-well vapor stripping system. The in-well vapor stripping system is a remediation technology designed to preferentially extract volatile organic compounds (VOCs) from contaminated groundwater by converting them to a vapor phase. Air-lift pumping is used to lift and aerate groundwater within the well. The volatiles escaping the aerated water are drawn off by a slight vacuum and treated at the surface while the water is allowed to infiltrate the vadose zone back to the watertable.

  4. Solvent vapor collector

    DOE Patents [OSTI]

    Ellison, Kenneth; Whike, Alan S.

    1979-01-30

    A solvent vapor collector is mounted on the upstream inlet end of an oven having a gas-circulating means and intended for curing a coating applied to a strip sheet metal at a coating station. The strip sheet metal may be hot and solvent vapors are evaporated at the coating station and from the strip as it passes from the coating station to the oven. Upper and lower plenums within a housing of the collector are supplied with oven gases or air from the gas-circulating means and such gases or air are discharged within the collector obliquely in a downstream direction against the strip passing through that collector to establish downstream gas flows along the top and under surfaces of the strip so as, in turn, to induct solvent vapors into the collector at the coating station. A telescopic multi-piece shroud is usefully provided on the housing for movement between an extended position in which it overlies the coating station to collect solvent vapors released thereat and a retracted position permitting ready cleaning and adjustment of that coating station.

  5. Category:Mercury Vapor | Open Energy Information

    Open Energy Info (EERE)

    Mercury Vapor Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Mercury Vapor page? For detailed information on Mercury Vapor as...

  6. Scanning ARM Cloud Radars. Part II: Data Quality Control and Processing

    SciTech Connect (OSTI)

    Kollias, Pavlos; Jo, Ieng; Borque, Paloma; Tatarevic, Aleksandra; Lamer, Katia; Bharadwaj, Nitin; Widener, Kevin B.; Johnson, Karen L.; Clothiaux, Eugene E.

    2014-03-01

    The Scanning ARM Cloud Radars (SACRs) are the primary instruments for documenting the four-dimensional structure and evolution of clouds within a 20-30 km radius from the ARM fixed and mobile sites. Here, the post-processing of the calibrated SACR measurements is discussed. First, a feature mask algorithm that objectively determines the presence of significant radar returns is described. The feature mask algorithm is based on the statistical properties of radar receiver noise. It accounts for atmospheric emission and is applicable even for SACR profiles with few or no signal-free range gates. Using the nearest-in-time atmospheric sounding, the SACR radar reflectivities are corrected for gaseous attenuation (water vapor and oxygen) using a line-by-line absorption model. Despite having a high pulse repetition frequency, the SACR has a narrow Nyquist velocity limit and thus Doppler velocity folding is commonly observed. An unfolding algorithm that makes use of a first guess for the true Doppler velocity using horizontal wind measurements from the nearest sounding is described. The retrieval of the horizontal wind profile from the HS-RHI SACR scan observations and/or nearest sounding is described. The retrieved horizontal wind profile can be used to adaptively configure SACR scan strategies that depend on wind direction. Several remaining challenges are discussed, including the removal of insect and second-trip echoes. The described algorithms significantly enhance SACR data quality and constitute an important step towards the utilization of SACR measurements for cloud research.

  7. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  8. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R.

    2016-05-03

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  9. Microsoft Word - HF_DOE_Clouds_final_report_9-7-2013

    Office of Scientific and Technical Information (OSTI)

    ... In future work such a cloud characterization will be related to water and light use ... However, reducing light intensity also limits water stress, and fluctuating light could ...

  10. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1985-11-08

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power reactor fuel has been under development for over 10 years. In June 1985 the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for the internationally competitive production of uranium separative work. The economic basis for this decision is considered, with an indicated of the constraints placed on the process figures of merit and the process laser system. We then trace an atom through a generic AVLIS separator and give examples of the physical steps encountered, the models used to describe the process physics, the fundamental parameters involved, and the role of diagnostic laser measurements.

  11. ARM - Measurement - Cloud extinction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud extinction The removal of radiant energy from an incident beam by the process of cloud absorption andor ...

  12. Intercomparison of Large-eddy Simulations of Arctic Mixed-phase Clouds: Importance of Ice Size Distribution Assumptions

    SciTech Connect (OSTI)

    Ovchinnikov, Mikhail; Ackerman, Andrew; Avramov, Alex; Cheng, Anning; Fan, Jiwen; Fridlind, Ann; Ghan, Steven J.; Harrington, Jerry Y.; Hoose, Corinna; Korolev, Alexei; McFarquhar, Greg; Morrison, H.; Paukert, Marco; Savre, Julien; Shipway, Ben; Shupe, Matthew D.; Solomon, Amy; Sulia, Kara

    2014-03-14

    Large-eddy simulations of mixed-phase Arctic clouds by 11 different models are analyzed with the goal of improving understanding and model representation of processes controlling the evolution of these clouds. In a case based on observations from the Indirect and Semi-Direct Aerosol Campaign (ISDAC), it is found that ice number concentration, Ni, exerts significant influence on the cloud structure. Increasing Ni leads to a substantial reduction in liquid water path (LWP) and potential cloud dissipation, in agreement with earlier studies. By comparing simulations with the same microphysics coupled to different dynamical cores as well as the same dynamics coupled to different microphysics schemes, it is found that the ice water path (IWP) is mainly controlled by ice microphysics, while the inter-model differences in LWP are largely driven by physics and numerics of the dynamical cores. In contrast to previous intercomparisons, all models here use the same ice particle properties (i.e., mass-size, mass-fall speed, and mass-capacitance relationships) and a common radiation parameterization. The constrained setup exposes the importance of ice particle size distributions (PSD) in influencing cloud evolution. A clear separation in LWP and IWP predicted by models with bin and bulk microphysical treatments is documented and attributed primarily to the assumed shape of ice PSD used in bulk schemes. Compared to the bin schemes that explicitly predict the PSD, schemes assuming exponential ice PSD underestimate ice growth by vapor deposition and overestimate mass-weighted fall speed leading to an underprediction of IWP by a factor of two in the considered case.

  13. Scientific Cloud Computing Misconceptions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientific Cloud Computing Misconceptions Scientific Cloud Computing Misconceptions July 1, 2011 Part of the Magellan project was to understand both the possibilities and the limitations of cloud computing in the pursuit of science. At a recent conference, Magellan investigator Shane Canon outlined some persistent misconceptions about doing science in the cloud - and what Magellan has taught us about them. » Read the ISGTW story. » Download the slides (PDF, 4.1MB

  14. Albedo and transmittance of inhomogeneous stratus clouds

    SciTech Connect (OSTI)

    Zuev, V.E.; Kasyanov, E.I.; Titov, G.A.

    1996-04-01

    A highly important topic is the study of the relationship between the statistical parameters of optical and radiative charactertistics of inhomogeneous stratus clouds. This is important because the radiation codes of general circulation models need improvement, and it is important for geophysical information. A cascade model has been developed at the Goddard Space Flight Center to treat stratocumulus clouds with the simplest geometry and horizontal fluctuations of the liquid water path (optical thickness). The model evaluates the strength with which the stochastic geometry of clouds influences the statistical characteristics of albedo and the trnasmittance of solar radiation.

  15. Stratified vapor generator

    DOE Patents [OSTI]

    Bharathan, Desikan; Hassani, Vahab

    2008-05-20

    A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

  16. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ... and variability in clouds14, water vapour15,16 and surface emission16,17 all ...

  17. Filter vapor trap

    DOE Patents [OSTI]

    Guon, Jerold

    1976-04-13

    A sintered filter trap is adapted for insertion in a gas stream of sodium vapor to condense and deposit sodium thereon. The filter is heated and operated above the melting temperature of sodium, resulting in a more efficient means to remove sodium particulates from the effluent inert gas emanating from the surface of a liquid sodium pool. Preferably the filter leaves are precoated with a natrophobic coating such as tetracosane.

  18. The vapor pressures of explosives

    SciTech Connect (OSTI)

    Ewing, Robert G.; Waltman, Melanie J.; Atkinson, David A.; Grate, Jay W.; Hotchkiss, Peter

    2013-01-05

    The vapor pressures of many explosive compounds are extremely low and thus determining accurate values proves difficult. Many researchers, using a variety of methods, have measured and reported the vapor pressures of explosives compounds at single temperatures, or as a function of temperature using vapor pressure equations. There are large variations in reported vapor pressures for many of these compounds, and some errors exist within individual papers. This article provides a review of explosive vapor pressures and describes the methods used to determine them. We have compiled primary vapor pressure relationships traceable to the original citations and include the temperature ranges for which they have been determined. Corrected values are reported as needed and described in the text. In addition, after critically examining the available data, we calculate and tabulate vapor pressures at 25 C.

  19. Using Radar, Lidar, and Radiometer measurements to Classify Cloud Type and Study Middle-Level Cloud Properties

    SciTech Connect (OSTI)

    Wang, Zhien

    2010-06-29

    The project is mainly focused on the characterization of cloud macrophysical and microphysical properties, especially for mixed-phased clouds and middle level ice clouds by combining radar, lidar, and radiometer measurements available from the ACRF sites. First, an advanced mixed-phase cloud retrieval algorithm will be developed to cover all mixed-phase clouds observed at the ACRF NSA site. The algorithm will be applied to the ACRF NSA observations to generate a long-term arctic mixed-phase cloud product for model validations and arctic mixed-phase cloud processes studies. To improve the representation of arctic mixed-phase clouds in GCMs, an advanced understanding of mixed-phase cloud processes is needed. By combining retrieved mixed-phase cloud microphysical properties with in situ data and large-scale meteorological data, the project aim to better understand the generations of ice crystals in supercooled water clouds, the maintenance mechanisms of the arctic mixed-phase clouds, and their connections with large-scale dynamics. The project will try to develop a new retrieval algorithm to study more complex mixed-phase clouds observed at the ACRF SGP site. Compared with optically thin ice clouds, optically thick middle level ice clouds are less studied because of limited available tools. The project will develop a new two wavelength radar technique for optically thick ice cloud study at SGP site by combining the MMCR with the W-band radar measurements. With this new algorithm, the SGP site will have a better capability to study all ice clouds. Another area of the proposal is to generate long-term cloud type classification product for the multiple ACRF sites. The cloud type classification product will not only facilitates the generation of the integrated cloud product by applying different retrieval algorithms to different types of clouds operationally, but will also support other research to better understand cloud properties and to validate model simulations. The

  20. Using Radar, Lidar, and Radiometer measurements to Classify Cloud Type and Study Middle-Level Cloud Properties

    SciTech Connect (OSTI)

    Wang, Zhien

    2006-01-04

    The project is concerned with the characterization of cloud macrophysical and microphysical properties by combining radar, lidar, and radiometer measurements available from the U.S. Department of Energy's ARM Climate Research Facility (ACRF). To facilitate the production of integrated cloud product by applying different algorithms to the ARM data streams, an advanced cloud classification algorithm was developed to classified clouds into eight types at the SGP site based on ground-based active and passive measurements. Cloud type then can be used as a guidance to select an optimal retrieval algorithm for cloud microphysical property retrieval. The ultimate goal of the effort is to develop an operational cloud classification algorithm for ARM data streams. The vision 1 IDL code of the cloud classification algorithm based on the SGP ACRF site observations was delivered to the ARM cloud translator during 2004 ARM science team meeting. Another goal of the project is to study midlevel clouds, especially mixed-phase clouds, by developing new retrieval algorithms using integrated observations at the ACRF sites. Mixed-phase clouds play a particular role in the Arctic climate system. A multiple remote sensor based algorithm, which can provide ice water content and effective size profiles, liquid water path, and layer-mean effective radius of water droplet, was developed to study arctic mixed-phase clouds. The algorithm is applied to long-term ARM observations at the NSA ACRF site. Based on these retrieval results, we are studying seasonal and interannual variations of arctic mixed-phase cloud macro- and micro-physical properties.

  1. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  2. Supercooled liquid water Estimation Tool

    Energy Science and Technology Software Center (OSTI)

    2012-05-04

    The Cloud Supercooled liquid water Estimation Tool (SEET) is a user driven Graphical User Interface (GUI) that estimates cloud supercooled liquid water (SLW) content in terms of vertical column and total mass from Moderate resolution Imaging Supercooled liquid water Estimation Tool Spectroradiometer (MODIS) spatially derived cloud products and realistic vertical cloud parameterizations that are user defined. It also contains functions for post-processing of the resulting data in tabular and graphical form.

  3. PROJECT PROFILE: Stable Perovskite Solar Cells via Chemical Vapor Deposition

    Broader source: Energy.gov [DOE]

    This project is focused on novel approaches to remove risk related to the development of hybrid perovskite solar cells (HPSCs). Researchers will synthesize a new and chemically stable hybrid organic-inorganic perovskite that eliminates decomposition of the absorber layer upon exposure to water vapor, which is a chief obstacle to widespread use of HPSC technology. They will also demonstrate a unique and industrially-scalable chemical vapor deposition method without halides or iodine, which are the main contributors to perovskite degradation.

  4. MAGIC Cloud Properties from Zenith Radiance Data Final Campaign Summary

    SciTech Connect (OSTI)

    Chiu, J. -Y.C.; Gregory, L.; Wagener, R.

    2016-01-01

    Cloud droplet size and optical depth are the most fundamental properties for understanding cloud formation, dissipation and interactions with aerosol and drizzle. They are also a crucial determinant of Earth’s radiative and water-energy balances. However, these properties are poorly predicted in climate models. As a result, the response of clouds to climate change is one of the major sources of uncertainty in climate prediction.

  5. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J.

    1996-12-31

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  6. ARM - Measurement - Cloud fraction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flux Analysis SWFLUXANAL : Shortwave Flux Analysis TSI : Total Sky Imager UAV-EGRETT : UAV-Egrett WSI : Whole Sky Imager WSICLOUD : Whole Sky Imager Cloud Products ...

  7. ARM - Measurement - Cloud phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that involves property descriptors such as stratus, cumulus, and cirrus. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  8. Finance Idol Word Cloud

    Broader source: Energy.gov [DOE]

    This word cloud represents the topics discussed during the Big and Small Ideas: How to Lower Solar Financing Costs breakout session at the SunShot Grand Challenge.

  9. Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fielding, M. D.; Chiu, J. C.; Hogan, R. J.; Feingold, G.; Eloranta, E.; O'Connor, E. J.; Cadeddu, M. P.

    2015-02-16

    Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar reflectivity. We present a new method to simultaneously retrieve cloud and drizzle vertical profiles in drizzling boundary-layer cloud using surface-based observations of radar reflectivity, lidar attenuated backscatter, and zenith radiances. Specifically, the vertical structure of droplet size and water content of both cloud and drizzle is characterised throughout the cloud. An ensemble optimal estimation approach provides full error statistics given the uncertainty in the observations. To evaluate the new method, we first perform retrievals using synthetic measurements from large-eddy simulation snapshots of cumulusmore » under stratocumulus, where cloud water path is retrieved with an error of 31 g m−2. The method also performs well in non-drizzling clouds where no assumption of the cloud profile is required. We then apply the method to observations of marine stratocumulus obtained during the Atmospheric Radiation Measurement MAGIC deployment in the northeast Pacific. Here, retrieved cloud water path agrees well with independent 3-channel microwave radiometer retrievals, with a root mean square difference of 10–20 g m−2.« less

  10. Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fielding, M. D.; Chiu, J. C.; Hogan, R. J.; Feingold, G.; Eloranta, E.; O'Connor, E. J.; Cadeddu, M. P.

    2015-07-02

    Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar reflectivity. We present a new method to simultaneously retrieve cloud and drizzle vertical profiles in drizzling boundary-layer clouds using surface-based observations of radar reflectivity, lidar attenuated backscatter, and zenith radiances under conditions when precipitation does not reach the surface. Specifically, the vertical structure of droplet size and water content of both cloud and drizzle is characterised throughout the cloud. An ensemble optimal estimation approach provides full error statistics given the uncertainty in the observations. To evaluate the new method, we first perform retrievalsmore » using synthetic measurements from large-eddy simulation snapshots of cumulus under stratocumulus, where cloud water path is retrieved with an error of 31 g m-2. The method also performs well in non-drizzling clouds where no assumption of the cloud profile is required. We then apply the method to observations of marine stratocumulus obtained during the Atmospheric Radiation Measurement MAGIC deployment in the Northeast Pacific. Here, retrieved cloud water path agrees well with independent three-channel microwave radiometer retrievals, with a root mean square difference of 10–20 g m-2.« less