National Library of Energy BETA

Sample records for water vapor clouds

  1. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    2004-02-19

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  2. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  3. COLD WATER VAPOR IN THE BARNARD 5 MOLECULAR CLOUD

    SciTech Connect (OSTI)

    Wirstrm, E. S.; Persson, C. M.; Charnley, S. B.; Cordiner, M. A.; Buckle, J. V.; Takakuwa, S.

    2014-06-20

    After more than 30yr of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds; however, there is only one region where cold (?10K) water vapor has been detectedL1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at worklikely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H{sub 2}O (J = 1{sub 10}-1{sub 01}) at 556.9360GHz toward two positions in the cold molecular cloud, Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

  4. Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates V. Mattioli and P. Basili Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado Introduction In recent years the Global

  5. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  6. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  7. Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds

    SciTech Connect (OSTI)

    Westwater, Edgeworth

    2011-05-06

    The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement (ARM) Program. At the North Slope of Alaska (NSA), both microwave radiometers (MWR) and the MWRProfiler (MWRP), been used operationally by ARM for passive retrievals of the quantities: Precipitable Water Vapor (PWV) and Liquid Water Path (LWP). However, it has been convincingly shown that these instruments are inadequate to measure low amounts of PWV and LWP. In the case of water vapor, this is especially important during the Arctic winter, when PWV is frequently less than 2 mm. For low amounts of LWP (< 50 g/m{sup 2}), the MWR and MWRP retrievals have an accuracy that is also not acceptable. To address some of these needs, in March-April 2004, NOAA and ARM conducted the NSA Arctic Winter Radiometric Experiment - Water Vapor Intensive Operational Period at the ARM NSA/Adjacent Arctic Ocean (NSA/AAO) site. After this experiment, the radiometer group at NOAA moved to the Center for Environmental Technology (CET) of the Department of Electrical and Computer Engineering of the University of Colorado at Boulder. During this 2004 experiment, a total of 220 radiosondes were launched, and radiometric data from 22.235 to 380 GHz were obtained. Primary instruments included the ARM MWR and MWRP, a Global Positioning System (GPS), as well as the CET Ground-based Scanning Radiometer (GSR). We have analyzed data from these instruments to answer several questions of importance to ARM, including: (a) techniques for improved water vapor measurements; (b) improved calibration techniques during cloudy conditions; (c) the spectral response of radiometers to a variety of conditions: clear, liquid, ice, and mixed phase clouds; and (d) forward modeling of microwave and millimeter wave brightness temperatures from 22 to 380 GHz. Many of these results have been published in the open literature. During the third year of this contract, we participated in another ARM-sponsored experiment at the NSA during February-March 2007. This experiment is called the Radiative Heating in Underexplored Bands Campaign (RHUBC) and the GSR was operated successfully for the duration of the campaign. One of the principal goals of the experiment was to provide retrievals of water vapor during PWV amounts less than 2 mm and to compare GSR data with ARM radiometers and radiosondes. A secondary goal was to compare the radiometric response of the microwave and millimeter wavelength radiometers to water and ice clouds. In this final report, we will include the separate progress reports for each of the three years of the project and follow with a section on major accomplishments of the project.

  8. PROGRESS REPORT OF FY 2004 ACTIVITIES: IMPROVED WATER VAPOR AND CLOUD RETRIEVALS AT THE NSA/AAO

    SciTech Connect (OSTI)

    E. R. Westwater; V. V. Leuskiy; M. Klein; A. J. Gasiewski; and J. A. Shaw

    2004-11-01

    The basic goals of the research are to develop and test algorithms and deploy instruments that improve measurements of water vapor, cloud liquid, and cloud coverage, with a focus on the Arctic conditions of cold temperatures and low concentrations of water vapor. The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement Program. Although several technologies have been investigated to measure these column amounts, microwave radiometers (MWR) have been used operationally by the ARM program for passive retrievals of these quantities: precipitable water vapor (PWV) and integrated water liquid (IWL). The technology of PWV and IWL retrievals has advanced steadily since the basic 2-channel MWR was first deployed at ARM CART sites Important advances are the development and refinement of the tipcal calibration method [1,2], and improvement of forward model radiative transfer algorithms [3,4]. However, the concern still remains that current instruments deployed by ARM may be inadequate to measure low amounts of PWV and IWL. In the case of water vapor, this is especially important because of the possibility of scaling and/or quality control of radiosondes by the water amount. Extremely dry conditions, with PWV less than 3 mm, commonly occur in Polar Regions during the winter months. Accurate measurements of the PWV during such dry conditions are needed to improve our understanding of the regional radiation energy budgets. The results of a 1999 experiment conducted at the ARM North Slope of Alaska/Adjacent Arctic Ocean (NSA/AAO) site during March of 1999 [5] have shown that the strength associated with the 183 GHz water vapor absorption line makes radiometry in this frequency regime suitable for measuring low amounts of PWV. As a portion of our research, we conducted another millimeter wave radiometric experiment at the NSA/AAO in March-April 2004. This experiment relied heavily on our experiences of the 1999 experiment. Particular attention was paid to issues of radiometric calibration and radiosonde intercomparisons. Our theoretical and experimental work also supplements efforts by industry (F. Solheim, Private Communication) to develop sub-millimeter radiometers for ARM deployment. In addition to quantitative improvement of water vapor measurements at cold temperature, the impact of adding millimeter-wave window channels to improve the sensitivity to arctic clouds was studied. We also deployed an Infrared Cloud Imager (ICI) during this experiment, both for measuring continuous day-night statistics of the study of cloud coverage and identifying conditions suitable for tipcal analysis. This system provided the first capability of determining spatial cloud statistics continuously in both day and night at the NSA site and has been used to demonstrate that biases exist in inferring cloud statistics from either zenith-pointing active sensors (lidars or radars) or sky imagers that rely on scattered sunlight in daytime and star maps at night [6].

  9. ARM Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Water Vapor IOP The SGP CART site will host the third ARM water vapor IOP on September 18-October 8, 2000. The CART site is home to a powerful array of instruments capable of measuring water vapor, making it a prime location for research of this type. The first water vapor IOP, conducted in September 1996, focused on using instruments to measure water vapor and determining the accuracy and calibration of each instrument. The second water vapor IOP, held in September and October of 1997,

  10. Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment V. Mattioli Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado V. Morris Pacific Northwest National

  11. ARM - Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Water Vapor Water vapor is the most effective, fastest changing, and least understood of the greenhouse gases. Water vapor is a powerful greenhouse gas; as a matter of fact, it is the dominant greenhouse gas. But scientists don't

  12. Water Vapor Experiment Concludes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Water Vapor Experiment Concludes The AIRS (atmospheric infrared sounder) Water Vapor Experiment - Ground (AWEX-G) intensive operations period (IOP) at the SGP central facility began on October 27 and ended on November 16, 2003. Researchers David Whiteman and Francis Schmidlin of the National Aeronautics and Space Administration (NASA), Holger Voemel of the National Oceanic and Atmospheric Administration (NOAA), Larry Miloshevich of the National Center for Atmospheric Research, and Barry Lesht

  13. ARM - Measurement - Total cloud water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud water ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total cloud water The total concentration (mass/vol) of ice and liquid water particles in a cloud; this includes condensed water content (CWC). Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a

  14. ARM - Evaluation Product - MWR Retrievals of Cloud Liquid Water and Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vapor ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file level. Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : MWR Retrievals of Cloud Liquid Water and Water Vapor A new algorithm is being developed for the ARM Program to derive liquid water path (LWP) and precipitable water vapor (PWV) from the

  15. ARM - PI Product - MWR Retrievals of Cloud Liquid Water and Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govDataPI Data ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us...

  16. Observed Increase of TTL Temperature and Water Vapor in Polluted Couds over Asia

    SciTech Connect (OSTI)

    Su, Hui; Jiang, Jonathan; Liu, Xiaohong; Penner, J.; Read, William G.; Massie, Steven T.; Schoeberl, Mark R.; Colarco, Peter; Livesey, Nathaniel J.; Santee, Michelle L.

    2011-06-01

    Aerosols can affect cloud particle size and lifetime, which impacts precipitation, radiation and climate. Previous studies1-4 suggested that reduced ice cloud particle size and fall speed due to the influence of aerosols may increase evaporation of ice crystals and/or cloud radiative heating in the tropical tropopause layer (TTL), leading to higher water vapor abundance in air entering the stratosphere. Observational substantiation of such processes is still lacking. Here, we analyze new observations from multiple NASA satellites to show the imprint of pollution influence on stratospheric water vapor. We focus our analysis on the highly-polluted South and East Asia region during boreal summer. We find that "polluted" ice clouds have smaller ice effective radius than "clean" clouds. In the TTL, the polluted clouds are associated with warmer temperature and higher specific humidity than the clean clouds. The water vapor difference between the polluted and clean clouds cannot be explained by other meteorological factors, such as updraft and detrainment strength. Therefore, the observed higher water vapor entry value into the stratosphere in the polluted clouds than in the clean clouds is likely a manifestation of aerosol pollution influence on stratospheric water vapor. Given the radiative and chemical importance of stratospheric water vapor, the increasing emission of aerosols over Asia may have profound impacts on stratospheric chemistry and global energy balance and water cycle.

  17. Tower Water-Vapor Mixing Ratio

    SciTech Connect (OSTI)

    Guastad, Krista; Riihimaki, Laura; none,

    2013-04-01

    The purpose of the Tower Water-Vapor Mixing Ratio (TWRMR) value-added product (VAP) is to calculate water-vapor mixing ratio at the 25-meter and 60-meter levels of the meteorological tower at the Southern Great Plains (SGP) Central Facility.

  18. Water vapor distribution in protoplanetary disks

    SciTech Connect (OSTI)

    Du, Fujun; Bergin, Edwin A.

    2014-09-01

    Water vapor has been detected in protoplanetary disks. In this work, we model the distribution of water vapor in protoplanetary disks with a thermo-chemical code. For a set of parameterized disk models, we calculate the distribution of dust temperature and radiation field of the disk with a Monte Carlo method, and then solve the gas temperature distribution and chemical composition. The radiative transfer includes detailed treatment of scattering by atomic hydrogen and absorption by water of Ly? photons, since the Ly? line dominates the UV spectrum of accreting young stars. In a fiducial model, we find that warm water vapor with temperature around 300 K is mainly distributed in a small and well-confined region in the inner disk. The inner boundary of the warm water region is where the shielding of UV field due to dust and water itself become significant. The outer boundary is where the dust temperature drops below the water condensation temperature. A more luminous central star leads to a more extended distribution of warm water vapor, while dust growth and settling tends to reduce the amount of warm water vapor. Based on typical assumptions regarding the elemental oxygen abundance and the water chemistry, the column density of warm water vapor can be as high as 10{sup 22} cm{sup 2}. A small amount of hot water vapor with temperature higher than ?300 K exists in a more extended region in the upper atmosphere of the disk. Cold water vapor with temperature lower than 100 K is distributed over the entire disk, produced by photodesorption of the water ice.

  19. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, P.

    1998-06-02

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma. 5 figs.

  20. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, Paul

    1998-01-01

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma.

  1. Final Report for ARM Project Measuring 4-D Water Vapor Fields with GPS

    SciTech Connect (OSTI)

    Braun, John

    2006-02-06

    Water vapor is a primary element in the Earth’s climate system. Atmospheric water vapor is central to cloud processes, radiation transfer, and the hydrological cycle. Using funding from Department of Energy (DOE) grant DE-FG03-02ER63327, the University Corporation for Atmospheric Research (UCAR) developed new observational techniques to measure atmospheric water vapor and applied these techniques to measure four dimensional water vapor fields throughout the United States Southern Great Plains region. This report summarizes the development of a new observation from ground based Global Positioning System (GPS) stations called Slant Water Vapor (SW) and it’s utilization in retrieving four dimensional water vapor fields. The SW observation represents the integrated amount of water vapor between a GPS station and a transmitting satellite. SW observations provide improved temporal and spatial sampling of the atmosphere when compared to column-integrated quantities such as preciptitable water vapor (PW). Under funding from the DOE Atmospheric Radiation Measurement (ARM) program, GPS networks in the Southern Great Plains (SGP) region were deployed to retrieve SW to improve the characterization of water vapor throughout the region. These observations were used to estimate four dimensional water vapor fields using tomographic approaches and through assimilation into the MM5 numerical weather model.

  2. Improved Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer J. C. Liljegren Environmental Research Division Argonne National Laboratory Argonne, Illinois Introduction Radiometrics Corporation has developed a twelve-channel microwave radiometer capable of providing continuous, real-time vertical profiles of temperature, water vapor, and limited-resolution cloud liquid water from the surface to 10 km in nearly all weather conditions (Solheim et al. 1998a). Since

  3. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsWater Vapor IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Water Vapor IOP 1996.09.10 - 1996.09.30 Lead Scientist : Henry Revercomb For data sets, see below. Summary SCHEDULE This IOP will be conducted from September 10 - 30, 1996 (coincident with the Fall ARM-UAV IOP). Instruments that do not require supervision will be operated continuously during this period. Instruments that do

  4. G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product

    SciTech Connect (OSTI)

    Koontz, A; Cadeddu, M

    2012-12-05

    The G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) value-added product (VAP) computes precipitable water vapor using neural network techniques from data measured by the GVR. The GVR reports time-series measurements of brightness temperatures for four channels located at 183.3 ± 1, 3, 7, and 14 GHz.

  5. Validation of TES Temperature and Water Vapor Retrievals with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The primary objective of the TES (Tropospheric Emission Spectrometer) instrument on the Aura spacecraft is the retrieval of trace gases, especially water vapor and ozone. The TES...

  6. ARM - Field Campaign - Fall 1997 Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Fall 1997 Water Vapor IOP 1997.09.15 - 1997.10.05 Lead Scientist : Henry Revercomb For data sets, see below. Summary The Water Vapor IOP was conducted as a follow-up to a predecessor IOP on water vapor held in September 1996. This IOP relied heavily on both ground-based guest and CART instrumentation and in-situ aircraft and tethered

  7. Evaluating Water Vapor in the NCAR CAM3 Climate Model with RRTMG/McICA using Modeled and Observed AIRS Spectral Radiances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor in the NCAR CAM3 Climate Model with RRTMG/McICA using Modeled and Observed AIRS Spectral Radiances Michael J. Iacono, Atmospheric and Environmental Research, Inc., 131 Hartwell Avenue, Lexington, MA 02421 USA 1. Overview Objectives: * Evaluate water vapor and temperature simulation in two versions of CAM3 by comparing modeled and observed cloud-cleared AIRS spectral radiances. * Use spectral differences to verify comparisons between modeled water vapor and temperature and observed

  8. Water clouds in Y dwarfs and exoplanets

    SciTech Connect (OSTI)

    Morley, Caroline V.; Fortney, Jonathan J.; Marley, Mark S.; Lupu, Roxana; Greene, Tom; Saumon, Didier; Lodders, Katharina

    2014-05-20

    The formation of clouds affects brown dwarf and planetary atmospheres of nearly all effective temperatures. Iron and silicate condense in L dwarf atmospheres and dissipate at the L/T transition. Minor species such as sulfides and salts condense in mid- to late T dwarfs. For brown dwarfs below T {sub eff} ? 450 K, water condenses in the upper atmosphere to form ice clouds. Currently, over a dozen objects in this temperature range have been discovered, and few previous theoretical studies have addressed the effect of water clouds on brown dwarf or exoplanetary spectra. Here we present a new grid of models that include the effect of water cloud opacity. We find that they become optically thick in objects below T {sub eff} ? 350-375 K. Unlike refractory cloud materials, water-ice particles are significantly nongray absorbers; they predominantly scatter at optical wavelengths through the J band and absorb in the infrared with prominent features, the strongest of which is at 2.8 ?m. H{sub 2}O, NH{sub 3}, CH{sub 4}, and H{sub 2} CIA are dominant opacity sources; less abundant species may also be detectable, including the alkalis, H{sub 2}S, and PH{sub 3}. PH{sub 3}, which has been detected in Jupiter, is expected to have a strong signature in the mid-infrared at 4.3 ?m in Y dwarfs around T {sub eff} = 450 K; if disequilibrium chemistry increases the abundance of PH{sub 3}, it may be detectable over a wider effective temperature range than models predict. We show results incorporating disequilibrium nitrogen and carbon chemistry and predict signatures of low gravity in planetary mass objects. Finally, we make predictions for the observability of Y dwarfs and planets with existing and future instruments, including the James Webb Space Telescope and Gemini Planet Imager.

  9. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Vignola, F.; Andreas, A.

    2013-08-22

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  10. ARM - Field Campaign - ARM-FIRE Water Vapor Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    were the airborne NASA LaRC LASE water vapor lidar and Diode Laser Hygrometer (DLH), the ground-based Vaisala RS-80H (after application of corrections for time-lag, temperature...

  11. ARM - Field Campaign - AIRS Water Vapor Experiment - Ground ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsAIRS Water Vapor Experiment - Ground (AWEX-G) ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at...

  12. ARM - Field Campaign - Single Frequency GPS Water Vapor Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsSingle Frequency GPS Water Vapor Network ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA....

  13. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Vignola, F.; Andreas, A.

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  14. Overview of the ARM/FIRE Water Vapor Experiment (AFWEX)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview of the ARM/FIRE Water Vapor Experiment (AFWEX) D. C. Tobin, H. E. Revercomb, and D. D. Turner University of Wisconsin-Madison Madison, Wisconsin Introduction An overview of the ARM/FIRE Water Vapor Experiment (AFWEX) is given. This field experiment was conducted during November-December 2000 near the central ground-based Atmospheric Radiation Measurement (ARM) site in north central Oklahoma, and was sponsored jointly by the ARM, the National Aeronautics and Space Administration (NASA)

  15. Removal of Sarin Aerosol and Vapor by Water Sprays

    SciTech Connect (OSTI)

    Brockmann, John E.

    1998-09-01

    Falling water drops can collect particles and soluble or reactive vapor from the gas through which they fall. Rain is known to remove particles and vapors by the process of rainout. Water sprays can be used to remove radioactive aerosol from the atmosphere of a nuclear reactor containment building. There is a potential for water sprays to be used as a mitigation technique to remove chemical or bio- logical agents from the air. This paper is a quick-look at water spray removal. It is not definitive but rather provides a reasonable basic model for particle and gas removal and presents an example calcu- lation of sarin removal from a BART station. This work ~ a starting point and the results indicate that further modeling and exploration of additional mechanisms for particle and vapor removal may prove beneficial.

  16. Liquid Water the Key to Arctic Cloud Radiative Closure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water the Key to Arctic Cloud Radiative Closure For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights Research Highlight...

  17. Effect of higher water vapor content on TBC performance

    SciTech Connect (OSTI)

    Pint, Bruce A; Haynes, James A

    2012-01-01

    Coal gasification, or IGCC (integrated gasification combined cycle), is one pathway toward cleaner use of coal for power generation with lower emissions. However, when coal-derived synthesis gas (i.e., syngas) is burned in turbines designed for natural gas, turbine manufacturers recommend 'derating,' or lowering the maximum temperature, which lowers the efficiency of the turbine, making electricity from IGCC more expensive. One possible reason for the derating is the higher water vapor contents in the exhaust gas. Water vapor has a detrimental effect on many oxidation-resistant high-temperature materials. In a turbine hot section, Ni-base superalloys are coated with a thermal barrier coating (TBC) allowing the gas temperature to be higher than the superalloy solidus temperature. TBCs have a low thermal conductivity ceramic top coating (typically Y{sub 2}O{sub 3}-stabilized ZrO{sub 2}, or YSZ) and an oxidation-resistant metallic bond coating. For land-based gas turbines, the industry standard is air plasma sprayed (APS) YSZ and high velocity oxygen fuel (HVOF) sprayed NiCoCrAlY bond coatings. To investigate the role of higher water vapor content on TBC performance and possible mitigation strategies, furnace cycling experiments were conducted in dry O{sub 2} and air with 10% (typical with natural gas or jet fuel) or 50 vol% water vapor. Cycle frequency and temperature were accelerated to one hour at 1100 C (with 10 minute cooling to {approx}30 C between each thermal cycle) to induce early failures in coatings that are expected to operate for several years with a metal temperature of {approx}900 C. Coupons (16 mm diameter x 2 mm thick) of commercial second-generation single crystal superalloy CMSX4 were HVOF coated on both sides with {approx}125 {micro}m of Ni-22wt%Co-17Cr-12Al either with 0.7Y or 0.7Y-0.3Hf-0.4Si. One side was then coated with 190-240 {micro}m of APS YSZ. Coatings were cycled until the YSZ top coating spalled. Figure 2 shows the results of the initial phase of experiments. Compared to dry O{sub 2}, the addition of 10% water vapor decreased the lifetime of MCrAlY by {approx}30% for the conventional CMSX4 substrates. Higher average lifetimes were observed with Hf in the bond coating, but a similar decrease in lifetime was observed when water vapor was added. The addition of Y and La to the superalloy substrate did not change the YSZ lifetime with 10% water vapor. However, increasing water vapor content from 10 to 50% did not further decrease the lifetime of either bond coating with the doped superalloy substrate. Thus, these results suggest that higher water vapor contents cannot explain the derating of syngas-fired turbines, and other factors such as sulfur and ash from imperfect syngas cleanup (or upset conditions) need to be explored. Researchers continue to study effects of water vapor on thermally grown alumina scale adhesion and growth rate, and are looking for bond coating compositions more resistant to oxidation in the presence of water vapor.

  18. Intercomparison of the Cloud Water Phase among Global Climate Models

    SciTech Connect (OSTI)

    Komurcu, Muge; Storelvmo, Trude; Tan, Ivy; Lohmann, U.; Yun, Yuxing; Penner, Joyce E.; Wang, Yong; Liu, Xiaohong; Takemura, T.

    2014-03-27

    Mixed-phase clouds (clouds that consist of both cloud droplets and ice crystals) are frequently present in the Earths atmosphere and influence the Earths energy budget through their radiative properties, which are highly dependent on the cloud water phase. In this study, the phase partitioning of cloud water is compared among six global climate models (GCMs) and with Cloud and Aerosol Lidar with Orthogonal Polarization retrievals. It is found that the GCMs predict vastly different distributions of cloud phase for a given temperature, and none of them are capable of reproducing the spatial distribution or magnitude of the observed phase partitioning. While some GCMs produced liquid water paths comparable to satellite observations, they all failed to preserve sufficient liquid water at mixed-phase cloud temperatures. Our results suggest that validating GCMs using only the vertically integrated water contents could lead to amplified differences in cloud radiative feedback. The sensitivity of the simulated cloud phase in GCMs to the choice of heterogeneous ice nucleation parameterization is also investigated. The response to a change in ice nucleation is quite different for each GCM, and the implementation of the same ice nucleation parameterization in all models does not reduce the spread in simulated phase among GCMs. The results suggest that processes subsequent to ice nucleation are at least as important in determining phase and should be the focus of future studies aimed at understanding and reducing differences among the models.

  19. ARM - Cloud and Rain

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ListCloud and Rain Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Cloud and Rain Water vapor is an invisible gas that is always present in the troposphere. However, the amount of water vapor which the air can hold depends directly on the air temperature. Warm air can hold much more water

  20. Fixation of nitrogen in the presence of water vapor

    DOE Patents [OSTI]

    Harteck, Paul (Santa Barbara, CA)

    1984-01-01

    A process for the fixation of nitrogen is disclosed which comprises combining a mixture of nitrogen, oxygen, metal oxide and water vapor, initially heating the combination to initiate a reaction which forms nitrate, but at a temperature and pressure range below the dissociation pressure of the nitrate. With or without the water component, the yield of fixed nitrogen is increased by the use of a Linde Molecular Sieve Catalyst.

  1. Heterogeneous nucleation of naphthalene vapor on water surface

    SciTech Connect (OSTI)

    Smolik, J.; Schwarz, J.

    1997-01-15

    Transfer processes between drops and gas play an important role in many natural and industrial processes, as absorption of gaseous pollutants by water drops in the atmosphere, combustion of fuel droplets, spray drying, synthesis of nanopowders, wet-dry desulfurization or extinguishing of hot combustion gases. The evaporation of a water drop into a ternary gaseous mixture of air, steam, and naphthalene vapor was investigated. The experimental results were compared with a theoretical prediction based on a numerical solution of coupled boundary layer equations for heat and mass transfer from a drop moving in ternary gas. In the experiments the naphthalene vapor condensed on the water drop as a supercooled liquid even at temperatures far below the melting point of naphthalene. The condensation on drop surface is discussed in terms of classical theory of heterogeneous nucleation on smooth surfaces.

  2. DOE/SC-ARM/TR-122 G-Band Vapor Radiometer Precipitable Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    state or reflect those of the U.S. Government or any agency thereof. DOESC-ARMTR-122 G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product A...

  3. An optical water vapor sensor for unmanned aerial vehicles

    SciTech Connect (OSTI)

    Timothy A. Berkoff; Paul L. Kebabian; Robert A. McClatchy; Charles E. Kolb; Andrew Freedman

    1998-12-01

    The water vapor sensor developed by Aerodyne Research, based on the optical absorption of light at {approximately}935 nm, has been successfully demonstrated on board the Pacific Northwest National Laboratory's Gulfstream-1 research aircraft during the Department of Energy's ARM Intensive Operations Period in August 1998. Data taken during this field campaign show excellent agreement with a chilled mirror and Lyman-alpha hygrometers and measurements confirm the ability to measure rapid, absolute water vapor fluctuations with a high degree of instrument stability and accuracy, with a noise level as low 10 ppmv (1 Hz measurement bandwidth). The construction of this small, lightweight sensor contains several unique elements which result in several significant advantages when compared to other techniques. First, the low power consumption Argon discharge lamp provides an optical beam at a fixed wavelength without a need for temperature or precision current control. The multi-pass absorption cell developed for this instrument provides a compact, low cost method that can survive deployment in the field. Fiber-optic cables, which are used to convey to light between the absorption cell, light source, and detection modules enable remote placement of the absorption cell from the opto-electronics module. Finally, the sensor does not use any moving parts which removes a significant source of potential malfunction. The result is an instrument which maintained its calibration throughout the field measurement campaign, and was not affected by high vibration and large uncontrolled temperature excursions. We believe that the development of an accurate, fast response water vapor monitor described in this report will open up new avenues of aerial-vehicle-based atmospheric research which have been relatively unexplored due to the lack of suitable low-cost, light-weight instrumentation.

  4. Posters Radar/Radiometer Retrievals of Cloud Liquid Water and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Posters Radar/Radiometer Retrievals of Cloud Liquid Water and Drizzle: Analysis Using Data from a Three-Dimensional Large Eddy Simulation of Marine Stratocumulus Clouds G. Feingold Cooperative Institute for Research in Environmental Sciences University of Colorado Boulder, Colorado A. S. Frisch National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado B. Stevens and W. R. Cotton Colorado State University Fort Collins, Colorado Introduction Marine

  5. Detecting and Evaluating the Effect of Overlaying Thin Cirrus Cloud on MODIS Retrieved Water-Cloud Droplet Effective Radius

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detecting and Evaluating the Effect of Overlaying Thin Cirrus Cloud on MODIS Retrieved Water-Cloud Droplet Effective Radius F.-L Chang and Z. Li Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland Z. Li Department of Meteorology University of Maryland College Park, Maryland Introduction Cirrus clouds can largely modify the solar reflected and terrestrial emitted radiances. The ubiquitous presence of cirrus clouds has a global coverage of about 20% to30%

  6. Water vapor in the spectrum of the extrasolar planet HD 189733b. II. The eclipse

    SciTech Connect (OSTI)

    Crouzet, Nicolas; McCullough, Peter R.; Deming, Drake; Madhusudhan, Nikku

    2014-11-10

    Spectroscopic observations of exoplanets are crucial to infer the composition and properties of their atmospheres. HD 189733b is one of the most extensively studied exoplanets and is a cornerstone for hot Jupiter models. In this paper, we report the dayside emission spectrum of HD 189733b in the wavelength range 1.1-1.7 ?m obtained with the Hubble Space Telescope Wide Field Camera 3 (WFC3) in spatial scan mode. The quality of the data is such that even a straightforward analysis yields a high-precision Poisson noise-limited spectrum: the median 1? uncertainty is 57 ppm per 0.02 ?m bin. We also build a white-light curve correcting for systematic effects and derive an absolute eclipse depth of 96 39 ppm. The resulting spectrum shows marginal evidence for water vapor absorption, but can also be well explained by a blackbody spectrum. However, the combination of these WFC3 data with previous Spitzer photometric observations is best explained by a dayside atmosphere of HD 189733b with no thermal inversion and a nearly solar or subsolar H{sub 2}O abundance in a cloud-free atmosphere. Alternatively, this apparent subsolar abundance may be the result of clouds or hazes that future studies need to investigate.

  7. MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    THE ARCTIC MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN THE ARCTIC Cadeddu, Maria Argonne National Laboratory Category: Instruments A new G-band (183 GHz) vapor radiometer (GVR), developed and built by Prosensing Inc. (http://www.prosensing.com), was deployed in Barrow, Alaska, in April 2005. The radiometer was deployed as part of the ongoing Atmospheric Radiation Measurement (ARM) program's effort to improve water vapor retrievals in the cold, dry Arctic

  8. Using information about small-scale variability in water vapor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Category: Modeling Deep convection is the process that most strongly affects the transport of energy and moisture in the atmosphere, and it produces clouds which have...

  9. Radiative Importance of ThinŽ Liquid Water Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Accomplishments of the Instantaneous Radiative Flux (IRF) Working Group August 2006 AERI Observations at Southern Great Plains Improve Infrared Radiative Transfer Models Turner et al., JAS, 2004 * AERI observations used to evaluate clear sky IR radiative transfer models * Long-term comparisons have improved - Spectral line database parameters - Water vapor continuum absorption models * Reduced errors in computation of downwelling radiative IR flux by approx 4; current uncertainty is on

  10. Determining Cloud Ice Water Path from High-Frequency Microwave Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining Cloud Ice Water Path from High-Frequency Microwave Measurements G. Liu Department of Meteorology Florida State University Tallahassee, Florida Introduction A better understanding of cloud water content and its large-scale distribution is important to climate research for improving our ability to parameterize and validate cloud/precipitation processes in global climate models. The goal of this study is to determine the distribution and large-scale advection of cloud ice/liquid water

  11. The role of water vapor feedback in unperturbed climate variability and global warming

    SciTech Connect (OSTI)

    Hall, A.; Manabe, Syukuro

    1999-08-01

    To understand the role of water vapor feedback in unperturbed surface temperature variability, a version of the Geophysical Fluid Dynamics Laboratory coupled ocean-atmosphere model is integrated for 1,000 yr in two configurations, one with water vapor feedback and one without. To understand the role of water vapor feedback in global warming, two 500-yr integrations were also performed in which CO{sub 2} was doubled in both model configurations. The final surface global warming in the model with water vapor feedback is 3.38 C, while in the one without it is only 1.05 C. However, the model`s water vapor feedback has a larger impact on surface warming in response to a doubling of CO{sub 2} than it does on internally generated, low-frequency, global-mean surface temperature anomalies. Water vapor feedback`s strength therefore depends on the type of temperature anomaly it affects. Finally, the authors compare the local and global-mean surface temperature time series from both unperturbed variability experiments to the observed record. The experiment without water vapor feedback does not have enough global-scale variability to reproduce the magnitude of the variability in the observed global-mean record, whether or not one removes the warming trend observed over the past century. In contrast, the amount of variability in the experiment with water vapor feedback is comparable to that of the global-mean record, provided the observed warming trend is removed. Thus, the authors are unable to simulate the observed levels of variability without water vapor feedback.

  12. Latitudinal survey of middle atmospheric water vapor revealed by shipboard microwave spectroscopy. Master's thesis

    SciTech Connect (OSTI)

    Schrader, M.L.

    1994-05-01

    Water vapor is one of the most important greenhouse gases and is an important tracer of atmospheric motions in the middle atmosphere. It also plays an important role in the chemistry of the middle atmosphere and through its photodissociation by solar radiation, it is the major source of hydrogen escaping to space. Ground-based microwave measurements conducted in the 1980s have provided a fair understanding of the seasonal variation of mesospheric water vapor in the northern hemisphere mid-latitudes, but the global distribution of water vapor in the middle atmosphere is only beginning to be revealed by space-based measurements.

  13. Water Vapor Turbulence Profiles in Stationary Continental Convective Mixed Layers

    SciTech Connect (OSTI)

    Turner, D. D.; Wulfmeyer, Volker; Berg, Larry K.; Schween, Jan

    2014-10-08

    The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program’s Raman lidar at the ARM Southern Great Plains (SGP) site in north-central Oklahoma has collected water vapor mixing ratio (q) profile data more than 90% of the time since October 2004. Three hundred (300) cases were identified where the convective boundary layer was quasi-stationary and well-mixed for a 2-hour period, and q mean, variance, third order moment, and skewness profiles were derived from the 10-s, 75-m resolution data. These cases span the entire calendar year, and demonstrate that the q variance profiles at the mixed layer (ML) top changes seasonally, but is more related to the gradient of q across the interfacial layer. The q variance at the top of the ML shows only weak correlations (r < 0.3) with sensible heat flux, Deardorff convective velocity scale, and turbulence kinetic energy measured at the surface. The median q skewness profile is most negative at 0.85 zi, zero at approximately zi, and positive above zi, where zi is the depth of the convective ML. The spread in the q skewness profiles is smallest between 0.95 zi and zi. The q skewness at altitudes between 0.6 zi and 1.2 zi is correlated with the magnitude of the q variance at zi, with increasingly negative values of skewness observed lower down in the ML as the variance at zi increases, suggesting that in cases with larger variance at zi there is deeper penetration of the warm, dry free tropospheric air into the ML.

  14. Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface Radar and Satellite Data in Support of ARM SCM Activities

    SciTech Connect (OSTI)

    Liu, Guosheng

    2013-03-15

    Single-column modeling (SCM) is one of the key elements of Atmospheric Radiation Measurement (ARM) research initiatives for the development and testing of various physical parameterizations to be used in general circulation models (GCMs). The data required for use with an SCM include observed vertical profiles of temperature, water vapor, and condensed water, as well as the large-scale vertical motion and tendencies of temperature, water vapor, and condensed water due to horizontal advection. Surface-based measurements operated at ARM sites and upper-air sounding networks supply most of the required variables for model inputs, but do not provide the horizontal advection term of condensed water. Since surface cloud radar and microwave radiometer observations at ARM sites are single-point measurements, they can provide the amount of condensed water at the location of observation sites, but not a horizontal distribution of condensed water contents. Consequently, observational data for the large-scale advection tendencies of condensed water have not been available to the ARM cloud modeling community based on surface observations alone. This lack of advection data of water condensate could cause large uncertainties in SCM simulations. Additionally, to evaluate GCMs’ cloud physical parameterization, we need to compare GCM results with observed cloud water amounts over a scale that is large enough to be comparable to what a GCM grid represents. To this end, the point-measurements at ARM surface sites are again not adequate. Therefore, cloud water observations over a large area are needed. The main goal of this project is to retrieve ice water contents over an area of 10 x 10 deg. surrounding the ARM sites by combining surface and satellite observations. Built on the progress made during previous ARM research, we have conducted the retrievals of 3-dimensional ice water content by combining surface radar/radiometer and satellite measurements, and have produced 3-D cloud ice water contents in support of cloud modeling activities. The approach of the study is to expand a (surface) point measurement to an (satellite) area measurement. That is, the study takes the advantage of the high quality cloud measurements (particularly cloud radar and microwave radiometer measurements) at the point of the ARM sites. We use the cloud ice water characteristics derived from the point measurement to guide/constrain a satellite retrieval algorithm, then use the satellite algorithm to derive the 3-D cloud ice water distributions within an 10° (latitude) x 10° (longitude) area. During the research period, we have developed, validated and improved our cloud ice water retrievals, and have produced and archived at ARM website as a PI-product of the 3-D cloud ice water contents using combined satellite high-frequency microwave and surface radar observations for SGP March 2000 IOP and TWP-ICE 2006 IOP over 10 deg. x 10 deg. area centered at ARM SGP central facility and Darwin sites. We have also worked on validation of the 3-D ice water product by CloudSat data, synergy with visible/infrared cloud ice water retrievals for better results at low ice water conditions, and created a long-term (several years) of ice water climatology in 10 x 10 deg. area of ARM SGP and TWP sites and then compared it with GCMs.

  15. Measurements of the Infrared SpectraLines of Water Vapor at Atmospheri...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sensing studies and their dependence upon temperature have also been measured by using lean mixtures of water vapor and air. For the sake of brevity they have not been presented...

  16. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu; Ly, Jennifer; Aldajani, Tiem; Baker, Richard W.

    2011-08-23

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  17. Reaction kinetics for the high temperature oxidation of Pu--1wt%Ga in water vapor

    SciTech Connect (OSTI)

    Stakebake, J L; Saba, M A

    1988-01-01

    Oxidation of plutonium metal is greatly accelerated by the presence of water vapor. The magnitude of the effect of water vapor on oxidation kinetics is determined by temperature, water concentration, and oxygen concentration. Most of the previous work has been directed toward evaluating the effect of moisture on the atmospheric oxidation of plutonium. Work on the isolation and characterization of the water reaction with plutonium has been very limited. The present work was undertaken to determine the kinetics of the plutonium--water reaction over a wide range of temperature and pressure. Reaction kinetics were measured using a vacuum microbalance system. The temperature range investigated was 100--500/degree/C. The effect of water vapor pressure on reaction kinetics was determined at 300/degree/C by varying the water pressure from 0.1 to 15 Torr. 2 figs.

  18. Posters Toward an Operational Water Vapor Remote Sensing System Using the Global Positioning System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Posters Toward an Operational Water Vapor Remote Sensing System Using the Global Positioning System S. I. Gutman, (a) R. B. Chadwick, (b) and D. W. Wolf (c) National Oceanic and Atmospheric Administration Boulder, Colorado A. Simon Cooperative Institute for Research in Environmental Science Boulder, Colorado T. Van Hove and C. Rocken University Navstar Consortium Boulder, Colorado Background Water vapor is one of the most important constituents of the free atmosphere since it is the principal

  19. GPS Water Vapor Projects Within the ARM Southern Great Plains Region

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GPS Water Vapor Projects Within the ARM Southern Great Plains Region J. Braun, T. Van Hove, S. Y. Ha, and C. Rocken GPS Science and Technology Program University Corporation for Atmospheric Research Boulder, Colorado Abstract The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Program has a need for an improved capability to measure and characterize the four-dimensional distribution of water vapor within the atmosphere. Applications for this type of data include their use

  20. BALTEX BRIDGE cloud liquid water network project: CLIWA-NET

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud types 432008 ARM-08 (Simplified) Working Strategy of GCSS Large Eddy Simulation (LES) Models Cloud Resolving Models (CRM) Single Column Model Versions of Climate Models...

  1. Determination of 3-D Cloud Ice Water Contents by Combining Multiple Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sources from Satellite, Ground Radar, and a Numerical Model Determination of 3-D Cloud Ice Water Contents by Combining Multiple Data Sources from Satellite, Ground Radar, and a Numerical Model Liu, Guosheng Florida State University Seo, Eun-Kyoung Florida State University Category: Cloud Properties This study aims at determining the 3-dimensional distribution of ice water content over a broad area near the Atmospheric Radiation Measurement Southern Great Plain site, where cloud radar and

  2. Materials, methods and devices to detect and quantify water vapor concentrations in an atmosphere

    DOE Patents [OSTI]

    Allendorf, Mark D; Robinson, Alex L

    2014-12-09

    We have demonstrated that a surface acoustic wave (SAW) sensor coated with a nanoporous framework material (NFM) film can perform ultrasensitive water vapor detection at concentrations in air from 0.05 to 12,000 ppmv at 1 atmosphere pressure. The method is extendable to other MEMS-based sensors, such as microcantilevers, or to quartz crystal microbalance sensors. We identify a specific NFM that provides high sensitivity and selectivity to water vapor. However, our approach is generalizable to detection of other species using NFM to provide sensitivity and selectivity.

  3. Continuous Water Vapor Profiles for the Fixed Atmospheric Radiation Measurement Sites

    SciTech Connect (OSTI)

    Jensen, M; Troyan, D

    2006-01-09

    The Atmospheric Radiation Measurement (ARM) Program defined a specific metric for the first quarter of Fiscal Year 2006 to complete a continuous time series of the vertical profile of water vapor for selected 30-day periods from each of the fixed ARM sites. In order to accomplish this metric, a new technique devised to incorporate radiosonde data, microwave radiometer data and analysis information from numerical weather forecast models has been developed. The product of this analysis, referred to as the merged sounding value-added product, includes vertical profiles of atmospheric water vapor concentration and several other important thermodynamic state variables at 1-minute time intervals and 266 vertical levels.

  4. A NORMETEX MODEL 15 M3/HR WATER VAPOR PUMPING TEST

    SciTech Connect (OSTI)

    Klein, J.; Fowley, M.; Steeper, T.

    2010-12-20

    Tests were performed using a Model 15 m{sup 3}/hr Normetex vacuum pump to determine if pump performance degraded after pumping a humid gas stream. An air feed stream containing 30% water vapor was introduced into the pump for 365 hours with the outlet pressure of the pump near the condensation conditions of the water. Performance of the pump was tested before and after the water vapor pumping test and indicated no loss in performance of the pump. The pump also appeared to tolerate small amounts of condensed water of short duration without increased noise, vibration, or other adverse indications. The Normetex pump was backed by a dual-head diaphragm pump which was affected by the condensation of water and produced some drift in operating conditions during the test.

  5. Modification and Application of a New Method for Retrieving Water-Cloud Microphysics Vertical Profile

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modification and Application of a New Method for Retrieving Water-Cloud Microphysics Vertical Profile F.-L Chang and Z. Li Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland Z. Li Department of Meteorology University of Maryland College Park, Maryland X. Dong Department of Atmospheric Sciences University of North Dakota Grand Forks, North Dakota Introduction Low- level boundary layer clouds have the most significant influence on cloud radiative forcing

  6. Remote Spectroscopic Sounding of Liquid Water Path in Thick Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences, the original methodology of sounding of dense clouds has been under development 1-3. The methodology...

  7. Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling

    SciTech Connect (OSTI)

    Boone, Eric J.; Laskin, Alexander; Laskin, Julia; Wirth, Christopher; Shepson, Paul B.; Stirm, Brian H.; Pratt, Kerri A.

    2015-07-21

    Cloud water and below-cloud atmospheric particle samples were collected onboard a research aircraft during the Southern Oxidant and Aerosol Study (SOAS) over a forested region of Alabama in June 2013. The organic molecular composition of the samples was studied to gain insights into the aqueous-phase processing of organic compounds within cloud droplets. High resolution mass spectrometry with nanospray desorption electrospray ionization and direct infusion electrospray ionization were utilized to compare the organic composition of the particle and cloud water samples, respectively. Isoprene and monoterpene-derived organosulfates and oligomers were identified in both the particles and cloud water, showing the significant influence of biogenic volatile organic compound oxidation above the forested region. While the average O:C ratios of the organic compounds were similar between the atmospheric particle and cloud water samples, the chemical composition of these samples was quite different. Specifically, hydrolysis of organosulfates and formation of nitrogen-containing compounds were observed for the cloud water when compared to the atmospheric particle samples, demonstrating that cloud processing changes the composition of organic aerosol.

  8. New Mexico cloud super cooled liquid water survey final report 2009.

    SciTech Connect (OSTI)

    Beavis, Nick; Roskovensky, John K.; Ivey, Mark D.

    2010-02-01

    Los Alamos and Sandia National Laboratories are partners in an effort to survey the super-cooled liquid water in clouds over the state of New Mexico in a project sponsored by the New Mexico Small Business Assistance Program. This report summarizes the scientific work performed at Sandia National Laboratories during the 2009. In this second year of the project a practical methodology for estimating cloud super-cooled liquid water was created. This was accomplished through the analysis of certain MODIS sensor satellite derived cloud products and vetted parameterizations techniques. A software code was developed to analyze multiple cases automatically. The eighty-one storm events identified in the previous year effort from 2006-2007 were again the focus. Six derived MODIS products were obtained first through careful MODIS image evaluation. Both cloud and clear-sky properties from this dataset were determined over New Mexico. Sensitivity studies were performed that identified the parameters which most influenced the estimation of cloud super-cooled liquid water. Limited validation was undertaken to ensure the soundness of the cloud super-cooled estimates. Finally, a path forward was formulized to insure the successful completion of the initial scientific goals which include analyzing different of annual datasets, validation of the developed algorithm, and the creation of a user-friendly and interactive tool for estimating cloud super-cooled liquid water.

  9. Water vapor and ozone profiles with a CO{sub 2} DIAL system in south Italy

    SciTech Connect (OSTI)

    Bellecci, C.; Caputi, G.; De Donato, F.; Gaudio, P.; Valentini, M.

    1996-12-31

    In this paper the authors present the work carried out at the University of Calabria regarding a prototype of a DIAL system. This has been realized for remote pollution monitoring. Most of the efforts have been done to perform several measurements on an horizontal path in order to scan the wide surrounding area. The concentrations of ozone and water vapor have been carried out using two different methods both related with the DIAL technique. With the integrated technique, average concentrations have been evaluated up to 5 km using topographical targets. In the range resolution technique, profiles of ozone and water vapor have been performed up to 700 m with a spatial resolution of about 30 m. Although the system needs a revision in several subsystems of its set-up, the experimentation has pointed out the performance available and the necessary improvements.

  10. Raman Lidar Measurements of Aerosols and Water Vapor During the May 2003 Aerosol IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Raman Lidar Measurements of Aerosols and Water Vapor During the May 2003 Aerosol IOP R. A. Ferrare National Aeronautics and Space Administration Langley Research Center Hampton, Virginia D. D. Turner Pacific Northwest National Laboratory Richland, Washington M. Clayton Science Applications International Corporation National Aeronautics and Space Administration Langley Research Center Hampton, Virginia B. S. Schmid and J. Redemann BAER/NASA Ames Research Institute Moffett Field, California D.

  11. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single Family Homes (Revised)

    SciTech Connect (OSTI)

    Cummings, J.; Withers, C.; Martin, E.; Moyer, N.

    2012-10-01

    This document focuses on managing the driving forces which move air and moisture across the building envelope. While other previously published Measure Guidelines focus on elimination of air pathways, the ultimate goal of this Measure Guideline is to manage drivers which cause air flow and water vapor transport across the building envelope (and also within the home), control air infiltration, keep relative humidity (RH) within acceptable limits, avoid combustion safety problems, improve occupant comfort, and reduce house energy use.

  12. Vertical Variability of Aerosols and Water Vapor Over the Southern Great Plains

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vertical Variability of Aerosols and Water Vapor Over the Southern Great Plains R. A. Ferrare National Aeronautics and Space Administration Langley Research Center Hampton, Virginia D. D. Turner Pacific Northwest National Laboratory Richland, Washington M. Clayton and V. Brackett Science Applications International Corporation National Aeronautics and Space Administration Langley Research Center Hampton, Virginia T. P. Tooman and J. E. M. Goldsmith Sandia National Laboratories Livermore,

  13. DOE/SC-ARM/TR-128 Tower Water-Vapor Mixing Ratio Value-Added

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 Tower Water-Vapor Mixing Ratio Value-Added Product April 2013 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights.

  14. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes

    SciTech Connect (OSTI)

    Cummings, James; Withers, Charles; Martin, Eric; Moyer, Neil

    2012-10-01

    This report is a revision of an earlier report titled: Measure Guideline: Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes. Revisions include: Information in the text box on page 1 was revised to reflect the most accurate information regarding classifications as referenced in the 2012 International Residential Code. “Measure Guideline” was dropped from the title of the report. An addition was made to the reference list.

  15. Fractionation of soil gases by diffusion of water vapor, gravitational settling, and thermal diffusion

    SciTech Connect (OSTI)

    Severinghaus, J.P.; Bender, M.L. [Univ. of Rhode Island, RI (United States)] [Univ. of Rhode Island, RI (United States); Keeling, R.F. [Scripps Institution of Oceanography, LaJolla, CA (United States)] [Scripps Institution of Oceanography, LaJolla, CA (United States); Broecker, W.S. [Lamont-Doherty Earth Observatory, Palisades, NY (United States)] [Lamont-Doherty Earth Observatory, Palisades, NY (United States)

    1996-03-01

    Air sampled from the moist unsaturated zone in a sand dune exhibits depletion in the heavy isotopes of N{sub 2} and O{sub 2}. We propose that the depletion is caused by a diffusive flux of water vapor out of the dune, which sweeps out the other gases, forcing them to diffuse back into the dune. The heavy isotopes of N{sub 2} and O{sub 2} diffuse back more slowly, resulting in a steady-state depletion of the heavy isotopesin the dune interior. We predict the effect`s magnitude with molecular diffusion theory and reproduce it in a laboratory simulation, finding good agreement between field, theory, and lab. The magnitude of the effect is governed by the ratio of the binary diffusivities against water vapor of a pair of gases, and increases {approximately} linearly with the difference between the water vapor mole fraction of the site and the advectively mixed reservoir with which it is in diffusive contact (in most cases the atmosphere). 32 refs., 1 fig., 3 tabs.

  16. Molecular dynamics study of two-dimensional sum frequency generation spectra at vapor/water interface

    SciTech Connect (OSTI)

    Ishiyama, Tatsuya; Morita, Akihiro; Tahara, Tahei

    2015-06-07

    Two-dimensional heterodyne-detected vibrational sum frequency generation (2D HD-VSFG) spectra at vapor/water interface were studied by molecular dynamics (MD) simulation with a classical flexible and nonpolarizable model. The present model well describes the spectral diffusion of 2D infrared spectrum of bulk water as well as 2D HD-VSFG at the interface. The effect of isotopic dilution on the 2D HD-VSFG was elucidated by comparing the normal (H{sub 2}O) water and HOD water. We further performed decomposition analysis of 2D HD-VSFG into the hydrogen-bonding and the dangling (or free) OH vibrations, and thereby disentangled the different spectral responses and spectral diffusion in the 2D HD-VSFG. The present MD simulation demonstrated the role of anharmonic coupling between these modes on the cross peak in the 2D HD-VSFG spectrum.

  17. Detecting Cirrus-Overlapping-Water Clouds and Retrieving their Optical Properties Using MODIS Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cirrus-Overlapping-Water Clouds and Retrieving their Optical Properties Using MODIS Data F.-L. Chang and Z. Li Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland Z. Li Department of Meteorology University of Maryland College Park, Maryland Introduction Different methods have been proposed to detect multilayer clouds using passive remote sensing data. Baum et al. (1995) used the CO 2 -slicing technique applied to the High Resolution Infrared Radiation

  18. Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-11-01

    A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

  19. Kinetics of Chronic Oxidation of NBG-17 Nuclear Graphite by Water Vapor

    SciTech Connect (OSTI)

    Contescu, Cristian I; Burchell, Timothy D; Mee, Robert

    2015-05-01

    This report presents the results of kinetic measurements during accelerated oxidation tests of NBG-17 nuclear graphite by low concentration of water vapor and hydrogen in ultra-high purity helium. The objective is to determine the parameters in the Langmuir-Hinshelwood (L-H) equation describing the oxidation kinetics of nuclear graphite in the helium coolant of high temperature gas-cooled reactors (HTGR). Although the helium coolant chemistry is strictly controlled during normal operating conditions, trace amounts of moisture (predictably < 0.2 ppm) cannot be avoided. Prolonged exposure of graphite components to water vapor at high temperature will cause very slow (chronic) oxidation over the lifetime of graphite components. This behavior must be understood and predicted for the design and safe operation of gas-cooled nuclear reactors. The results reported here show that, in general, oxidation by water of graphite NBG-17 obeys the L-H mechanism, previously documented for other graphite grades. However, the characteristic kinetic parameters that best describe oxidation rates measured for graphite NBG-17 are different than those reported previously for grades H-451 (General Atomics, 1978) and PCEA (ORNL, 2013). In some specific conditions, certain deviations from the generally accepted L-H model were observed for graphite NBG-17. This graphite is manufactured in Germany by SGL Carbon Group and is a possible candidate for the fuel elements and reflector blocks of HTGR.

  20. In-Reactor Oxidation of Zircaloy-4 Under Low Water Vapor Pressures

    SciTech Connect (OSTI)

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin; Longhurst, Glen

    2015-01-01

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370C). Data from these tests will be used to support fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr-4 over the specified range of test conditions. Comparisons between in- and ex- reactor test results were performed to evaluate the influence of irradiation.

  1. In-reactor oxidation of zircaloy-4 under low water vapor pressures

    SciTech Connect (OSTI)

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin K.; Longhurst, Glen R.

    2015-01-01

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370 C). Data from these tests will be used to support the fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr- 4 over the specified range of test conditions. Comparisons between in- and ex-reactor test results were performed to evaluate the influence of irradiation.

  2. Method of condensing vaporized water in situ to treat tar sands formations

    DOE Patents [OSTI]

    Hsu, Chia-Fu

    2010-03-16

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  3. Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle

    SciTech Connect (OSTI)

    Hosni, Mohammad H.

    2014-03-30

    Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerant’s pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development of the cycle and have gained an in-depth understanding of the governing fundamental knowledge, based on the laws of physics and thermodynamics and verified with our testing results. Through this research, we are identifying optimal working fluid and operating conditions to eventually demonstrate the core technology for space cooling or other applications.

  4. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR?¢????s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument?¢????s robustness in a real-world situation.

  5. Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds K. Ivanova Pennsylvania State University University Park, Pennsylvania T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington M. Ausloos University of Liège B-4000 Liège, Belgium Abstract We present a method on how to derive an underlying mathematical (statistical or model free) equation for a liquid water path (LWP) signal directly from empirical data. The evolution of the probability density

  6. A comparison of water vapor quantities from model short-range forecasts and ARM observations

    SciTech Connect (OSTI)

    Hnilo, J J

    2006-03-17

    Model evolution and improvement is complicated by the lack of high quality observational data. To address a major limitation of these measurements the Atmospheric Radiation Measurement (ARM) program was formed. For the second quarter ARM metric we will make use of new water vapor data that has become available, and called the 'Merged-sounding' value added product (referred to as OBS, within the text) at three sites: the North Slope of Alaska (NSA), Darwin Australia (DAR) and the Southern Great Plains (SGP) and compare these observations to model forecast data. Two time periods will be analyzed March 2000 for the SGP and October 2004 for both DAR and NSA. The merged-sounding data have been interpolated to 37 pressure levels (e.g., from 1000hPa to 100hPa at 25hPa increments) and time averaged to 3 hourly data for direct comparison to our model output.

  7. Treatment of Produced Water Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Lynn E. Katz; Kerry A. Kinney; Robert S. Bowman; Enid J. Sullivan; Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Craig R. Altare

    2006-01-31

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. Produced waters typically contain a high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component as well as chemicals added during the oil-production process. It has been estimated that a total of 14 billion barrels of produced water were generated in 2002 from onshore operations (Veil, 2004). Although much of this produced water is disposed via reinjection, environmental and cost considerations can make surface discharge of this water a more practical means of disposal. In addition, reinjection is not always a feasible option because of geographic, economic, or regulatory considerations. In these situations, it may be desirable, and often necessary from a regulatory viewpoint, to treat produced water before discharge. It may also be feasible to treat waters that slightly exceed regulatory limits for re-use in arid or drought-prone areas, rather than losing them to reinjection. A previous project conducted under DOE Contract DE-AC26-99BC15221 demonstrated that surfactant modified zeolite (SMZ) represents a potential treatment technology for produced water containing BTEX. Laboratory and field experiments suggest that: (1) sorption of benzene, toluene, ethylbenzene and xylenes (BTEX) to SMZ follows linear isotherms in which sorption increases with increasing solute hydrophobicity; (2) the presence of high salt concentrations substantially increases the capacity of the SMZ for BTEX; (3) competitive sorption among the BTEX compounds is negligible; and, (4) complete recovery of the SMZ sorption capacity for BTEX can be achieved by air sparging the SMZ. This report summarizes research for a follow on project to optimize the regeneration process for multiple sorption/regeneration cycles, and to develop and incorporate a vapor phase bioreactor (VPB) system for treatment of the off-gas generated during air sparging. To this end, we conducted batch and column laboratory SMZ and VPB experiments with synthetic and actual produced waters. Based on the results of the laboratory testing, a pilot scale study was designed and conducted to evaluate the combined SMZ/VPB process. An economic and regulatory feasibility analysis was also completed as part of the current study to assess the viability of the process for various water re-use options.

  8. TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM

    SciTech Connect (OSTI)

    LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

    2003-10-01

    Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and assembled to treat the off-gas from the SMZ regeneration process. These columns will be used both in the laboratory and in the proposed field testing to be conducted next year. Innocula for the columns that degrade all of the BTEX columns have been developed.

  9. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W.

    2014-05-14

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 away from the surface.

  10. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  11. Biophysical controls on carbon and water vapor fluxes across a grassland climatic gradient in the United States

    SciTech Connect (OSTI)

    Wagle, Pradeep; Xiao, Xiangming; Scott, Russell L.; Kolb, Thomas E.; Cook, David R.; Brunsell, Nathaniel; Baldocchi, Dennis D.; Basara, Jeffrey; Matamala, Roser; Zhou, Yuting; Bajgain, Rajen

    2015-12-01

    Understanding of the underlying causes of spatial variation in exchange of carbon and water vapor fluxes between grasslands and the atmosphere is crucial for accurate estimates of regional and global carbon and water budgets, and for predicting the impact of climate change on biosphereatmosphere feedbacks of grasslands. We used ground-based eddy flux and meteorological data, and the Moderate Resolution Imaging Spectroradiometer (MODIS) enhanced vegetation index (EVI) from 12 grasslands across the United States to examine the spatial variability in carbon and water vapor fluxes and to evaluate the biophysical controls on the spatial patterns of fluxes. Precipitation was strongly associated with spatial and temporal variability in carbon and water vapor fluxes and vegetation productivity. Grasslands with annual average precipitation <600 mm generally had neutral annual carbon balance or emitted small amount of carbon to the atmosphere. Despite strong coupling between gross primary production (GPP)and evapotranspiration (ET) across study sites, GPP showed larger spatial variation than ET, and EVI had a greater effect on GPP than on ET. Consequently, large spatial variation in ecosystem water use efficiency (EWUE = annual GPP/ET; varying from 0.67 0.55 to 2.52 0.52 g C mm?ET) was observed. Greater reduction in GPP than ET at high air temperature and vapor pressure deficit caused a reduction in EWUE in dry years, indicating a response which is opposite than what has been reported for forests. Our results show that spatial and temporal variations in ecosystem carbon uptake, ET, and water use efficiency of grasslands were strongly associated with canopy greenness and coverage, as indicated by EVI.

  12. A Compact, Backscattering Deplolarization Cloud Spectrometer for Ice and Water Discrimination

    SciTech Connect (OSTI)

    Thomson, David

    2014-05-15

    This project was to develop a compact optical particle spectrometer, small enough for operation on UAVS, that measures the optical diameter of cloud hydrometeors and differentiates their water phase (liquid or solid). To reach this goal, a work plan was laid out that would complete three objectives: 1) Evaluation of designs for an optical particle spectrometer that measures the component of light backscattered at two polarization angles. 2) Testing of selected designs on an optical bench. 3) Construction and preliminary testing of a prototype instrument based on the selected, optimum design. A protoype instrument was developed and tested in an icing wind tunnel where the results showed good measurement of cloud droplets and ice particles.

  13. Method and apparatus for simulating atomospheric absorption of solar energy due to water vapor and CO.sub.2

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Denver, CO)

    1995-01-01

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth's surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO.sub.2 and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO.sub.2 and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO.sub.2 and moisture.

  14. Method and apparatus for simulating atmospheric absorption of solar energy due to water vapor and CO{sub 2}

    DOE Patents [OSTI]

    Sopori, B.L.

    1995-06-20

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.

  15. Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations

    SciTech Connect (OSTI)

    Turner, David D.

    2003-06-01

    A novel new approach to retrieve cloud microphysical properties from mixed-phase clouds is presented. This algorithm retrieves cloud optical depth, ice fraction, and the effective size of the water and ice particles from ground-based, high-resolution infrared radiance observations. The theoretical basis is that the absorption coefficient of ice is stronger than that of liquid water from 10-13 mm, whereas liquid water is more absorbing than ice from 16-25 um. However, due to strong absorption in the rotational water vapor absorption band, the 16-25 um spectral region becomes opaque for significant water vapor burdens (i.e., for precipitable water vapor amounts over approximately 1 cm). The Arctic is characterized by its dry and cold atmosphere, as well as a preponderance of mixed-phase clouds, and thus this approach is applicable to Arctic clouds. Since this approach uses infrared observations, cloud properties are retrieved at night and during the long polar wintertime period. The analysis of the cloud properties retrieved during a 7 month period during the Surface Heat Budget of the Arctic (SHEBA) experiment demonstrates many interesting features. These results show a dependence of the optical depth on cloud phase, differences in the mode radius of the water droplets in liquid-only and mid-phase clouds, a lack of temperature dependence in the ice fraction for temperatures above 240 K, seasonal trends in the optical depth with the clouds being thinner in winter and becoming more optically thick in the late spring, and a seasonal trend in the effective size of the water droplets in liquid-only and mixed-phase clouds that is most likely related to aerosol concentration.

  16. Evaluation of an ambient air sampling system for tritium (as tritiated water vapor) using silica gel adsorbent columns

    SciTech Connect (OSTI)

    Patton, G.W.; Cooper, A.T.; Tinker, M.R.

    1995-08-01

    Ambient air samples for tritium analysis (as the tritiated water vapor [HTO] content of atmospheric moisture) are collected for the Hanford Site Surface Environmental Surveillance Project (SESP) using the solid adsorbent silica gel. The silica gel has a moisture sensitive indicator which allows for visual observation of moisture movement through a column. Despite using an established method, some silica gel columns showed a complete change in the color indicator for summertime samples suggesting that breakthrough had occurred; thus a series of tests was conducted on the sampling system in an environmental chamber. The purpose of this study was to determine the maximum practical sampling volume and overall collection efficiency for water vapor collected on silica gel columns. Another purpose was to demonstrate the use of an impinger-based system to load water vapor onto silica gel columns to provide realistic analytical spikes and blanks for the Hanford Site SESP. Breakthrough volumes (V{sub b}) were measured and the chromatographic efficiency (expressed as the number of theoretical plates [N]) was calculated for a range of environmental conditions. Tests involved visual observations of the change in the silica gel`s color indicator as a moist air stream was drawn through the column, measurement of the amount of a tritium tracer retained and then recovered from the silica gel, and gravimetric analysis for silica gel columns exposed in the environmental chamber.

  17. Detection of water masers toward young stellar objects in the Large Magellanic Cloud

    SciTech Connect (OSTI)

    Johanson, A. K.; Migenes, V.; Breen, S. L.

    2014-02-01

    We present results from a search for water maser emission toward N4A, N190, and N206, three regions of massive star formation in the Large Magellanic Cloud (LMC). Four water masers were detected; two toward N4A, and two toward N190. In the latter region, no previously known maser emission has been reported. Future studies of maser proper motion to determine the galactic dynamics of the LMC will benefit from the independent data points the new masers in N190 provide. Two of these masers are associated with previously identified massive young stellar objects (YSOs), which strongly supports the authenticity of the classification. We argue that the other two masers identify previously unknown YSOs. No masers were detected toward N206, but it does host a newly discovered 22 GHz continuum source, also associated with a massive YSO. We suggest that future surveys for water maser emission in the LMC be targeted toward the more luminous, massive YSOs.

  18. Treatment of Produced Waters Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Lynn E. Katz; Kerry A. Kinney; R. S. Bowman; E. J. Sullivan

    2005-03-11

    This report summarizes work performed on this project from October 2004 through March 2005. In previous work, a surfactant modified zeolite (SMZ) was shown to be an effective system for removing BTEX contaminants from produced water. Additional work on this project demonstrated that a compost-based biofilter could biodegrade the BTEX contaminants found in the SMZ regeneration waste gas stream. However, it was also determined that the BTEX concentrations in the waste gas stream varied significantly during the regeneration period and the initial BTEX concentrations were too high for the biofilter to handle effectively. A series of experiments were conducted to determine the feasibility of using a passive adsorption column placed upstream of the biofilter to attenuate the peak gas-phase VOC concentrations delivered to the biofilter during the SMZ regeneration process. In preparation for the field test of the SMZ/VPB treatment system in New Mexico, a pilot-scale SMZ system was also designed and constructed during this reporting period. Finally, a cost and feasibility analysis was also completed. To investigate the merits of the passive buffering system during SMZ regeneration, two adsorbents, SMZ and granular activated carbon (GAC) were investigated in flow-through laboratory-scale columns to determine their capacity to handle steady and unsteady VOC feed conditions. When subjected to a toluene-contaminated air stream, the column containing SMZ reduced the peak inlet 1000 ppmv toluene concentration to 630 ppmv at a 10 second contact time. This level of buffering was insufficient to ensure complete removal in the downstream biofilter and the contact time was longer than desired. For this reason, using SMZ as a passive buffering system for the gas phase contaminants was not pursued further. In contrast to the SMZ results, GAC was found to be an effective adsorbent to handle the peak contaminant concentrations that occur early during the SMZ regeneration process. At a one second residence time, the GAC bed reduced peak contaminant concentrations by 97%. After the initial peak, the inlet VOC concentration in the SMZ regeneration gas stream drops exponentially with time. During this period, the contaminants on the GAC subsequently desorbed at a nearly steady rate over the next 45 hours resulting in a relatively steady effluent concentration of approximately 25 ppm{sub v}. This lower concentration is readily degradable by a downstream vapor phase biofilter (VPB) and the steady nature of the feed stream will prevent the biomass in the VPB from enduring starvation conditions between SMZ regeneration cycles. Repetitive sorption and desorption cycles that would be expected in the field were also investigated. It was determined that although the GAC initially lost some VOC sorption capacity, the adsorption and desorption profiles stabilized after approximately 6 cycles indicating that a GAC bed should be suitable for continuous operation. In preparation for the pilot field testing of the SMZ/VPB system, design, ''in-house'' construction and testing of the field system were completed during this project period. The design of the SMZ system for the pilot test was based on previous investigations by the PI's in Wyoming, 2002 and on analyses of the produced water at the field site in New Mexico. The field tests are scheduled for summer, 2005. A cost survey, feasibility of application and cost analyses were completed to investigate the long term effectiveness of the SMZ/VPB system as a method of treating produced water for re-use. Several factors were investigated, including: current costs to treat and dispose of produced water, end-use water quality requirements, and state and federal permitting requirements.

  19. Water injection as a means for reducing non-condensible andcorrosive gases in steam produced from vapor-dominated reservoirs

    SciTech Connect (OSTI)

    Pruess, Karsten; Spycher, Nicolas; Kneafsey, Timothy J.

    2007-01-08

    Large-scale water injection at The Geysers, California, hasgenerated substantial benefits in terms of sustaining reservoir pressuresand production rates, as well as improving steam composition by reducingthe content of non-condensible gases (NCGs). Two effects have beenrecognized and discussed in the literature as contributing to improvedsteam composition, (1) boiling of injectate provides a source of "clean"steam to production wells, and (2) pressurization effects induced byboiling of injected water reduce upflow of native steam with large NCGconcentrations from depth. In this paper we focus on a possibleadditional effect that could reduce NCGs in produced steam by dissolutionin a condensed aqueous phase.Boiling of injectate causes pressurizationeffects that will fairly rapidly migrate outward, away from the injectionpoint. Pressure increases will cause an increase in the saturation ofcondensed phase due to vapor adsorption on mineral surfaces, andcapillary condensation in small pores. NCGs will dissolve in theadditional condensed phase which, depending upon their solubility, mayreduce NCG concentrations in residual steam.We have analyzed thepartitioning of HCl between vapor and aqueous phases, and have performednumerical simulations of injection into superheated vapor zones. Oursimulations provide evidence that dissolution in the condensed phase canindeed reduce NCG concentrations in produced steam.

  20. A unified parameterization of clouds and turbulence using CLUBB and subcolumns in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thayer-Calder, K.; Gettelman, A.; Craig, C.; Goldhaber, S.; Bogenschutz, P. A.; Chen, C.-C.; Morrison, H.; Höft, J.; Raut, E.; Griffin, B. M.; et al

    2015-06-30

    Most global climate models parameterize separate cloud types using separate parameterizations. This approach has several disadvantages, including obscure interactions between parameterizations and inaccurate triggering of cumulus parameterizations. Alternatively, a unified cloud parameterization uses one equation set to represent all cloud types. Such cloud types include stratiform liquid and ice cloud, shallow convective cloud, and deep convective cloud. Vital to the success of a unified parameterization is a general interface between clouds and microphysics. One such interface involves drawing Monte Carlo samples of subgrid variability of temperature, water vapor, cloud liquid, and cloud ice, and feeding the sample points into amore » microphysics scheme. This study evaluates a unified cloud parameterization and a Monte Carlo microphysics interface that has been implemented in the Community Atmosphere Model (CAM) version 5.3. Results describing the mean climate and tropical variability from global simulations are presented. The new model shows a degradation in precipitation skill but improvements in short-wave cloud forcing, liquid water path, long-wave cloud forcing, precipitable water, and tropical wave simulation. Also presented are estimations of computational expense and investigation of sensitivity to number of subcolumns.« less

  1. A unified parameterization of clouds and turbulence using CLUBB and subcolumns in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thayer-Calder, K.; Gettelman, A.; Craig, C.; Goldhaber, S.; Bogenschutz, P. A.; Chen, C.-C.; Morrison, H.; Höft, J.; Raut, E.; Griffin, B. M.; et al

    2015-12-01

    Most global climate models parameterize separate cloud types using separate parameterizations. This approach has several disadvantages, including obscure interactions between parameterizations and inaccurate triggering of cumulus parameterizations. Alternatively, a unified cloud parameterization uses one equation set to represent all cloud types. Such cloud types include stratiform liquid and ice cloud, shallow convective cloud, and deep convective cloud. Vital to the success of a unified parameterization is a general interface between clouds and microphysics. One such interface involves drawing Monte Carlo samples of subgrid variability of temperature, water vapor, cloud liquid, and cloud ice, and feeding the sample points into amore » microphysics scheme. This study evaluates a unified cloud parameterization and a Monte Carlo microphysics interface that has been implemented in the Community Atmosphere Model (CAM) version 5.3. Model computational expense is estimated, and sensitivity to the number of subcolumns is investigated. Results describing the mean climate and tropical variability from global simulations are presented. The new model shows a degradation in precipitation skill but improvements in shortwave cloud forcing, liquid water path, long-wave cloud forcing, precipitable water, and tropical wave simulation.« less

  2. Active probing of cloud multiple scattering, optical depth, vertical thickness, and liquid water content using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Tellier, L. L.; Ho, Cheng,

    2002-01-01

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60-degree full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer, and, from there, estimate the volume-averaged liquid water content. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Here we present recent WAIL data oti various clouds and discuss the extension of WAIL to full diurnal monitoring by means of an ultra-narrow magneto-optic atomic line filter for daytime measurements.

  3. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

    1985-01-01

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  4. ARM - PI Product - AERIoe Thermodynamic Profile and Cloud Retrieval for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MC3E Lamont X-band site (I6) Lamont X-band site (I6) ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : AERIoe Thermodynamic Profile and Cloud Retrieval for MC3E Lamont X-band site (I6) [ ARM research ] The AERIoe algorithm retrieves profiles of temperature and water vapor mixing ratio, together with cloud properties for a single-layer cloud (i.e., LWP, effective radius), from AERI-observed infrared

  5. Pollution Changes Clouds' Ice Crystal Genesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pollution Changes Clouds' Ice Crystal Genesis For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Suspended high in the atmosphere, plentiful dust particles are fertile turf for growing ice. But, what are the optimal conditions for this crop? Researchers at Pacific Northwest National Laboratory (PNNL) found that miniscule particles of airborne dust, thought to be a perfect landing site for water vapor, are altered by the

  6. Water vapor and temperature inversions near the 0 deg C level over the tropical western Pacific. Master's thesis

    SciTech Connect (OSTI)

    Hart, K.A.

    1994-01-01

    During the Intensive Observation Period (IOP), several periods of water vapor and temperature inversions near the 0 deg C level were observed. Satellite and radiosonde data from TOGA COARE are used to document the large-scale conditions and thermodynamic and kinematic structures present during three extended periods in which moisture and temperature inversions near the freezing level were very pronounced. Observations from each case are synthesized into schematics which represent typical structures of the inversion phenomena. Frequency distributions of the inversion phenomena along with climatological humidity and temperature profiles are calculated for the four-month IOP.

  7. MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2)

    SciTech Connect (OSTI)

    Gaustad, KL; Turner, DD; McFarlane, SA

    2011-07-25

    This report provides a short description of the Atmospheric Radiation Measurement (ARM) Climate Research Facility microwave radiometer (MWR) Retrieval (MWRRET) value-added product (VAP) algorithm. This algorithm utilizes a complementary physical retrieval method and applies brightness temperature offsets to reduce spurious liquid water path (LWP) bias in clear skies resulting in significantly improved precipitable water vapor (PWV) and LWP retrievals. We present a general overview of the technique, input parameters, output products, and describe data quality checks. A more complete discussion of the theory and results is given in Turner et al. (2007b).

  8. Arctic Mixed-Phase Cloud Properties from AERI Lidar Observations: Algorithm and Results from SHEBA

    SciTech Connect (OSTI)

    Turner, David D.

    2005-04-01

    A new approach to retrieve microphysical properties from mixed-phase Arctic clouds is presented. This mixed-phase cloud property retrieval algorithm (MIXCRA) retrieves cloud optical depth, ice fraction, and the effective radius of the water and ice particles from ground-based, high-resolution infrared radiance and lidar cloud boundary observations. The theoretical basis for this technique is that the absorption coefficient of ice is greater than that of liquid water from 10 to 13 ?m, whereas liquid water is more absorbing than ice from 16 to 25 ?m. MIXCRA retrievals are only valid for optically thin (?visible < 6) single-layer clouds when the precipitable water vapor is less than 1 cm. MIXCRA was applied to the Atmospheric Emitted Radiance Interferometer (AERI) data that were collected during the Surface Heat Budget of the Arctic Ocean (SHEBA) experiment from November 1997 to May 1998, where 63% of all of the cloudy scenes above the SHEBA site met this specification. The retrieval determined that approximately 48% of these clouds were mixed phase and that a significant number of clouds (during all 7 months) contained liquid water, even for cloud temperatures as low as 240 K. The retrieved distributions of effective radii for water and ice particles in single-phase clouds are shown to be different than the effective radii in mixed-phase clouds.

  9. Effect of Water Vapor on the 1100oC Oxidation Behavior of Plasma-Sprayed TBCs with HVOF NiCoCrAlX Bond Coatings

    SciTech Connect (OSTI)

    Haynes, James A; Unocic, Kinga A; Pint, Bruce A

    2013-01-01

    With the goal of investigating the reported detrimental effect of water vapor on thermal barrier coating (TBC) performance, furnace cycle experiments were conducted in dry O2 and air with 10 and 50% water vapor at 1100 C. The TBC systems evaluated were air plasma-sprayed (APS), yttria-stabilized zirconia (YSZ) top coatings with high velocity oxy fuel (HVOF)-deposited NiCoCrAlY or NiCoCrAlYHfSi bond coating. Average TBC lifetime was reduced by ~30% in air with 10% water vapor compared to cycling in dry O2, using 1h cycle durations. Superalloy substrates with Y and La additions also were investigated but showed no statistical change in the average TBC lifetime compared to the base CMSX4 superalloy. In all cases, the bond coating with Hf and Si additions increased YSZ lifetime by 20% or more. Experiments that increased water vapor to 50% showed no further decrease in TBC lifetime. Increasing the cycle frequency to 100h resulted in a large increase in TBC lifetime, especially for the NiCoCrAlYHfSi bond coatings. Co-doping the NiCoCrAl bond coat with Y and Hf was beneficial to TBC lifetime, but did not mitigate the detrimental impact of water vapor.

  10. The Use of Water Vapor as a Refrigerant: Impact of Cycle Modifications on Commercial Viability

    SciTech Connect (OSTI)

    Brandon F. Lachner, Jr.; Gregory F. Nellis; Douglas T. Reindl

    2004-08-30

    This project investigated the economic viability of using water as the refrigerant in a 1000-ton chiller application. The most attractive water cycle configuration was found to be a flash-intercooled, two-stage cycle using centrifugal compressors and direct contact heat exchangers. Component level models were developed that could be used to predict the size and performance of the compressors and heat exchangers in this cycle as well as in a baseline, R-134a refrigeration cycle consistent with chillers in use today. A survey of several chiller manufacturers provided information that was used to validate and refine these component models. The component models were integrated into cycle models that were subsequently used to investigate the life-cycle costs of both an R-134a and water refrigeration cycle. It was found that the first cost associated with the water as a refrigerant cycle greatly exceeded the savings in operating costs associated with its somewhat higher COP. Therefore, the water refrigeration cycle is not an economically attractive option to today's R-134a refrigeration system. There are a number of other issues, most notably the requirements associated with purging non-condensable gases that accumulate in a direct contact heat exchanger, which will further reduce the economic viability of the water cycle.

  11. Microphysical Consequences of the Spatial Distribution of Ice Nucleation in Mixed-Phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, Fan; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2014-07-28

    Mixed-phase stratiform clouds can persist even with steady ice precipitation fluxes, and the origin and microphysical properties of the ice crystals are of interest. Vapor deposition growth and sedimentation of ice particles along with a uniform volume source of ice nucleation, leads to a power law relation between ice water content wi and ice number concentration ni with exponent 2.5. The result is independent of assumptions about the vertical velocity structure of the cloud and is therefore more general than the related expression of Yang et al. [2013]. The sensitivity of the wi-ni relationship to the spatial distribution of ice nucleation is confirmed by Lagrangian tracking and ice growth with cloud-volume, cloud-top, and cloud-base sources of ice particles through a time-dependent cloud field. Based on observed wi and ni from ISDAC, a lower bound of 0.006 m^3/s is obtained for the ice crystal formation rate.

  12. Minimalist Model of Ice Microphysics in Mixed-phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, F.; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2013-07-28

    The question of whether persistent ice crystal precipitation from super cooled layer clouds can be explained by time-dependent, stochastic ice nucleation is explored using an approximate, analytical model, and a large-eddy simulation (LES) cloud model. The updraft velocity in the cloud defines an accumulation zone, where small ice particles cannot fall out until they are large enough, which will increase the residence time of ice particles in the cloud. Ice particles reach a quasi-steady state between growth by vapor deposition and fall speed at cloud base. The analytical model predicts that ice water content (wi) has a 2.5 power law relationship with ice number concentration ni. wi and ni from a LES cloud model with stochastic ice nucleation also confirm the 2.5 power law relationship. The prefactor of the power law is proportional to the ice nucleation rate, and therefore provides a quantitative link to observations of ice microphysical properties.

  13. ARM - PI Product - AERIoe Thermodynamic Profile and Cloud Retrieval for SGP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CF during LABLE-2012 2 ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : AERIoe Thermodynamic Profile and Cloud Retrieval for SGP CF during LABLE-2012 [ ARM research ] The AERIoe algorithm retrieves profiles of temperature and water vapor mixing ratio, together with cloud properties for a single-layer cloud (i.e., LWP, effective radius), from AERI-observed infrared radiance spectrum. The method is a

  14. ARM - PI Product - AERIoe Thermodynamic Profile and Cloud Retrieval for SGP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CF during LABLE-2013 3 ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : AERIoe Thermodynamic Profile and Cloud Retrieval for SGP CF during LABLE-2013 [ ARM research ] The AERIoe algorithm retrieves profiles of temperature and water vapor mixing ratio, together with cloud properties for a single-layer cloud (i.e., LWP, effective radius), from AERI-observed infrared radiance spectrum. The method is a

  15. Scanning ARM Cloud Radars Part I: Operational Sampling Strategies

    SciTech Connect (OSTI)

    Kollias, Pavlos; Bharadwaj, Nitin; Widener, Kevin B.; Jo, Ieng; Johnson, Karen

    2014-03-01

    Probing clouds in three-dimensions has never been done with scanning millimeter-wavelength (cloud) radars in a continuous operating environment. The acquisition of scanning cloud radars by the Atmospheric Radiation Measurement (ARM) program and research institutions around the world generate the need for developing operational scan strategies for cloud radars. Here, the first generation of sampling strategies for the Scanning ARM Cloud Radars (SACRs) is discussed. These scan strategies are designed to address the scientific objectives of the ARM program, however, they introduce an initial framework for operational scanning cloud radars. While the weather community uses scan strategies that are based on a sequence of scans at constant elevations, the SACRs scan strategies are based on a sequence of scans at constant azimuth. This is attributed to the cloud properties that are vastly different for rain and snow shafts that are the primary target of precipitation radars. A cloud surveillance scan strategy is introduced (HS-RHI) based on a sequence of horizon-to-horizon Range Height Indicator (RHI) scans that sample the hemispherical sky (HS). The HS-RHI scan strategy is repeated every 30 min to provide a static view of the cloud conditions around the SACR location. Between HS-RHI scan strategies other scan strategies are introduced depending on the cloud conditions. The SACRs are pointing vertically in the case of measurable precipitation at the ground. The radar reflectivities are corrected for water vapor attenuation and non-meteorological detection are removed. A hydrometeor detection mask is introduced based on the difference of cloud and noise statistics is discussed.

  16. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    2008-01-15

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  17. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  18. Testing a New Cirrus Cloud Parameterizaton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Institute of Oceanography La Jolla, California Introduction Cirrus cloud cover and ice water content (IWC) are the two most important properties of cirrus clouds. However, in...

  19. Tropical Cloud Properties and Radiative Heating Profiles

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mather, James

    2008-01-15

    We have generated a suite of products that includes merged soundings, cloud microphysics, and radiative fluxes and heating profiles. The cloud microphysics is strongly based on the ARM Microbase value added product (Miller et al., 2003). We have made a few changes to the microbase parameterizations to address issues we observed in our initial analysis of the tropical data. The merged sounding product is not directly related to the product developed by ARM but is similar in that it uses the microwave radiometer to scale the radiosonde column water vapor. The radiative fluxes also differ from the ARM BBHRP (Broadband Heating Rate Profile) product in terms of the radiative transfer model and the sampling interval.

  20. Tropical Cloud Properties and Radiative Heating Profiles

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mather, James

    We have generated a suite of products that includes merged soundings, cloud microphysics, and radiative fluxes and heating profiles. The cloud microphysics is strongly based on the ARM Microbase value added product (Miller et al., 2003). We have made a few changes to the microbase parameterizations to address issues we observed in our initial analysis of the tropical data. The merged sounding product is not directly related to the product developed by ARM but is similar in that it uses the microwave radiometer to scale the radiosonde column water vapor. The radiative fluxes also differ from the ARM BBHRP (Broadband Heating Rate Profile) product in terms of the radiative transfer model and the sampling interval.

  1. Scanning ARM Cloud Radar Handbook

    SciTech Connect (OSTI)

    Widener, K; Bharadwaj, N; Johnson, K

    2012-06-18

    The scanning ARM cloud radar (SACR) is a polarimetric Doppler radar consisting of three different radar designs based on operating frequency. These are designated as follows: (1) X-band SACR (X-SACR); (2) Ka-band SACR (Ka-SACR); and (3) W-band SACR (W-SACR). There are two SACRs on a single pedestal at each site where SACRs are deployed. The selection of the operating frequencies at each deployed site is predominantly determined by atmospheric attenuation at the site. Because RF attenuation increases with atmospheric water vapor content, ARM's Tropical Western Pacific (TWP) sites use the X-/Ka-band frequency pair. The Southern Great Plains (SGP) and North Slope of Alaska (NSA) sites field the Ka-/W-band frequency pair. One ARM Mobile Facility (AMF1) has a Ka/W-SACR and the other (AMF2) has a X/Ka-SACR.

  2. Cirrus clouds in a global climate model with a statistical cirrus cloud scheme

    SciTech Connect (OSTI)

    Wang, Minghuai; Penner, Joyce E.

    2010-06-21

    A statistical cirrus cloud scheme that accounts for mesoscale temperature perturbations is implemented in a coupled aerosol and atmospheric circulation model to better represent both subgrid-scale supersaturation and cloud formation. This new scheme treats the effects of aerosol on cloud formation and ice freezing in an improved manner, and both homogeneous freezing and heterogeneous freezing are included. The scheme is able to better simulate the observed probability distribution of relative humidity compared to the scheme that was implemented in an older version of the model. Heterogeneous ice nuclei (IN) are shown to decrease the frequency of occurrence of supersaturation, and improve the comparison with observations at 192 hPa. Homogeneous freezing alone can not reproduce observed ice crystal number concentrations at low temperatures (<205 K), but the addition of heterogeneous IN improves the comparison somewhat. Increases in heterogeneous IN affect both high level cirrus clouds and low level liquid clouds. Increases in cirrus clouds lead to a more cloudy and moist lower troposphere with less precipitation, effects which we associate with the decreased convective activity. The change in the net cloud forcing is not very sensitive to the change in ice crystal concentrations, but the change in the net radiative flux at the top of the atmosphere is still large because of changes in water vapor. Changes in the magnitude of the assumed mesoscale temperature perturbations by 25% alter the ice crystal number concentrations and the net radiative fluxes by an amount that is comparable to that from a factor of 10 change in the heterogeneous IN number concentrations. Further improvements on the representation of mesoscale temperature perturbations, heterogeneous IN and the competition between homogeneous freezing and heterogeneous freezing are needed.

  3. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    SciTech Connect (OSTI)

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, Allen B.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-01-03

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for assessing aerosol effects on cold season precipitation in California.

  4. ARM Cloud Aerosol Precipitation Experiment (ACAPEX) Science Plan

    SciTech Connect (OSTI)

    Leung, L. R.; Prather, K.; Ralph, R.; Rosenfeld, D.; Spackman, R.; DeMott, P.; Fairall, C.; Fan, J.; Hagos, S.; Hughes, M.; Long, C.; Rutledge, S.; Waliser, D.; Wang, H.

    2014-09-01

    The western U.S. receives precipitation predominantly during the cold season when storms approach from the Pacific Ocean. The snowpack that accumulates during winter storms provides about 70-90% of water supply for the region. Understanding and modeling the fundamental processes that govern the large precipitation variability and extremes in the western U.S. is a critical test for the ability of climate models to predict the regional water cycle, including floods and droughts. Two elements of significant importance in predicting precipitation variability in the western U.S. are atmospheric rivers and aerosols. Atmospheric rivers (ARs) are narrow bands of enhanced water vapor associated with the warm sector of extratropical cyclones over the Pacific and Atlantic oceans. Because of the large lower-tropospheric water vapor content, strong atmospheric winds and neutral moist static stability, some ARs can produce heavy precipitation by orographic enhancement during landfall on the U.S. West Coast. While ARs are responsible for a large fraction of heavy precipitation in that region during winter, much of the rest of the orographic precipitation occurs in post-frontal clouds, which are typically quite shallow, with tops just high enough to pass the mountain barrier. Such clouds are inherently quite susceptible to aerosol effects on both warm rain and ice precipitation-forming processes.

  5. The influence of ice nucleation mode and ice vapor growth on simulation of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    arctic mixed-phase clouds The influence of ice nucleation mode and ice vapor growth on simulation of arctic mixed-phase clouds Avramov, Alexander The Pennsylvania State University Category: Modeling Mixed-phase arctic stratus clouds are the predominant cloud type in the Arctic . Perhaps one of the most intriguing of their features is that they tend to have liquid tops that precipitate ice. Despite the fact that this situation is colloidally unstable, these cloud systems are quite long lived

  6. Multiwavelength observations of a devleoping cloud system: The FIRE II 26 November 1991 case study

    SciTech Connect (OSTI)

    Intrieri, J.M.; Eberhard, W.L.; Uttal, T.

    1995-12-01

    Simultaneous multiwavelength measurements of a developing cloud system were obtained by NOAA Doppler lidar, Doppler radar, Fourier transform infrared interferometer, and microwave and infrared radiometers on 26 November 1991. The evolution of the cloud system is described in terms of lidar backscatter, radar reflectivity and velocity, interferometer atmospheric spectra, and radiometer brightness temperature, integrated liquid water, and water vapor paths. Utilizing the difference in wavelength between the radar and lidar, and therefore their independent sensitivity to different regions of the same cloud, the cloud top, base, depth, and multiple layer heights can be determined with better accuracy than with either instrument alone. Combining the radar, lidar, and radiometer measurements using two different techniques allows an estimation of the vertical profile of cloud microphysical properties such as particle sizes. Enhancement of lidar backscatter near zenith revealed when highly oriented ice crystals were present. The authors demonstrate that no single instrument is sufficient to accurately describe cirrus clouds and that measurements in combination can provide important details on their geometric, radiative, and microphysical properties.

  7. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  8. Understanding Ice Supersaturation, Particle Growth, and Number Concentration in Cirrus Clouds

    SciTech Connect (OSTI)

    Comstock, Jennifer M.; Lin, Ruei-Fong; Starr, David O.; Yang, P.

    2008-12-10

    Many factors control the ice supersaturation and microphysical properties in cirrus clouds. We explore the effects of dynamic forcing, ice nucleation mechanisms, and ice crystal growth rate on the evolution and distribution of water vapor and cloud properties in cirrus clouds using a detailed microphysical model and remote sensing measurements obtained at the Department of Energys Atmospheric Radiation Measurement (ARM) Climate Research Facility located near Lamont, OK. To help understand dynamic scales important in cirrus formation, we force the model using both large-scale forcing derived using ARM variational analysis, and mean mesoscale velocity derived from radar Doppler velocity measurements. Both heterogeneous and homogeneous nucleation processes are explored, where we have implemented a rigorous classical theory heterogeneous nucleation scheme to compare with empirical representations. We evaluate model simulations by examining both bulk cloud properties and distributions of measured radar reflectivity, lidar extinction, and water vapor profiles, as well as retrieved cloud microphysical properties. This approach allows for independent verification of both the large and small particle modes of the particle size distribution. Our results suggest that mesoscale variability is the primary mechanism needed to reproduce observed quantities, while nucleation mechanism is secondary. Slow ice crystal growth tends to overestimate the number of small ice crystals, but does not seem to influence bulk properties such as ice water path and cloud thickness. The most realistic simulations as compared with observations are forced using mesoscale waves, include fast ice crystal growth, and initiate ice by either homogeneous or heterogeneous nucleation. Ice crystal number concentrations on the order of 10-100 L-1 produce results consistent with both lidar and radar observations during a cirrus event observed on 7 December 1999, which has an optical depth range typical of midlatitude cirrus.

  9. The Role of Shallow Cloud Moistening in MJO and Non-MJO Convective...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to quantify bulk shallow cloud moistening through evaporation of condensed water using a simple method based on observations of liquid water path, cloud depth and temporal...

  10. Vapor spill pipe monitor

    DOE Patents [OSTI]

    Bianchini, G.M.; McRae, T.G.

    1983-06-23

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

  11. Long Term Field Development of a Surfactant Modified Zeolite/Vapor Phase Bioreactor System for Treatment of Produced Waters for Power Generation

    SciTech Connect (OSTI)

    Lynn Katz; Kerry Kinney; Robert Bowman; Enid Sullivan; Soondong Kwon; Elaine Darby; Li-Jung Chen; Craig Altare

    2007-12-31

    The main goal of this research was to investigate the feasibility of using a combined physicochemical/biological treatment system to remove the organic constituents present in saline produced water. In order to meet this objective, a physical/chemical adsorption process was developed and two separate biological treatment techniques were investigated. Two previous research projects focused on the development of the surfactant modified zeolite adsorption process (DE-AC26-99BC15221) and development of a vapor phase biofilter (VPB) to treat the regeneration off-gas from the surfactant modified zeolite (SMZ) adsorption system (DE-FC26-02NT15461). In this research, the SMZ/VPB was modified to more effectively attenuate peak loads and to maintain stable biodegradation of the BTEX constituents from the produced water. Specifically, a load equalization system was incorporated into the regeneration flow stream. In addition, a membrane bioreactor (MBR) system was tested for its ability to simultaneously remove the aromatic hydrocarbon and carboxylate components from produced water. The specific objectives related to these efforts included the following: (1) Optimize the performance VPBs treating the transient loading expected during SMZ regeneration: (a) Evaluate the impact of biofilter operating parameters on process performance under stable operating conditions. (b) Investigate how transient loads affect biofilter performance, and identify an appropriate technology to improve biological treatment performance during the transient regeneration period of an SMZ adsorption system. (c) Examine the merits of a load equalization technology to attenuate peak VOC loads prior to a VPB system. (d) Evaluate the capability of an SMZ/VPB to remove BTEX from produced water in a field trial. (2) Investigate the feasibility of MBR treatment of produced water: (a) Evaluate the biodegradation of carboxylates and BTEX constituents from synthetic produced water in a laboratory-scale MBR. (b) Evaluate the capability of an SMZ/MBR system to remove carboxylates and BTEX from produced water in a field trial. Laboratory experiments were conducted to provide a better understanding of each component of the SMZ/VPB and SMZ/MBR process. Laboratory VPB studies were designed to address the issue of influent variability and periodic operation (see DE-FC26-02NT15461). These experiments examined multiple influent loading cycles and variable concentration loadings that simulate air sparging as the regeneration option for the SMZ system. Two pilot studies were conducted at a produced water processing facility near Farmington, New Mexico. The first field test evaluated SMZ adsorption, SMZ regeneration, VPB buffering, and VPB performance, and the second test focused on MBR and SMZ/MBR operation. The design of the field studies were based on the results from the previous field tests and laboratory studies. Both of the biological treatment systems were capable of removing the BTEX constituents in the laboratory and in the field over a range of operating conditions. For the VPB, separation of the BTEX constituents from the saline aqueous phase yielded high removal efficiencies. However, carboxylates remained in the aqueous phase and were not removed in the combined VPB/SMZ system. In contrast, the MBR was capable of directly treating the saline produced water and simultaneously removing the BTEX and carboxylate constituents. The major limitation of the MBR system is the potential for membrane fouling, particularly when the system is treating produced water under field conditions. The combined process was able to effectively pretreat water for reverse osmosis treatment and subsequent downstream reuse options including utilization in power generation facilities. The specific conclusions that can be drawn from this study are summarized.

  12. ARM - Measurement - Cloud size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measurements as cloud thickness, cloud area, and cloud aspect ratio. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  13. Comparison of Cloud Fraction and Liquid Water Path between ECMWF simulations and ARM long-term Observations at the NSA Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    poster, seasonal and annual variations of cloudiness and liquid water path (LWP) from European Center for Medium-Range Weather Forecasts (ECMWF) model were compared with surface measurement from the ARM Climate Research Facility (ARCF) North Slope of Alaska ( N S A ) s i t e b e t we e n J a n u a r y 1 9 9 9 and December 2004. ● Model simulated large scale features match well with observations. ● There are significant differences in cloud vertical and temporal distributions and in the

  14. G-Band Vapor Radiometer Profiler (GVRP) Handbook

    SciTech Connect (OSTI)

    Caddeau, MP

    2010-06-23

    The G-Band Vapor Radiometer Profiler (GVRP) provides time-series measurements of brightness temperatures from 15 channels between 170 and 183.310 GHz. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. Channels between 170.0 and 176.0 GHz are particularly sensitive to the presence of liquid water. The sensitivity to water vapor of the 183.31-GHz line is approximately 30 times higher than at the frequencies of the two-channel microwave radiometer (MWR) for a precipitable water vapor (PWV) amount of less than 2.5 mm. Measurements from the GVRP instrument are therefore especially useful during low-humidity conditions (PWV < 5 mm). In addition to integrated water vapor and liquid water, the GVRP can provide low-resolution vertical profiles of water vapor in very dry conditions.

  15. Precipitating clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    processes, especially related ice. * Very large differences between observed IN number concentration and ice concentration in a given clouds. * Many ice nucleation modes are...

  16. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

    1995-09-26

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

  17. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, John P. (Idaho Falls, ID); Larson, Ronald A. (Idaho Falls, ID); Goodrich, Lorenzo D. (Shelley, ID); Hall, Harold J. (Idaho Falls, ID); Stoddard, Billy D. (Idaho Falls, ID); Davis, Sean G. (Idaho Falls, ID); Kaser, Timothy G. (Idaho Falls, ID); Conrad, Frank J. (Albuquerque, NM)

    1995-01-01

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet.

  18. Vapor Barriers or Vapor Diffusion Retarders

    Broader source: Energy.gov [DOE]

    In most U.S. climates, vapor diffusion retarders can help prevent moisture problems, increase energy efficiency, and improve comfort in homes.

  19. Radiative Effects of Cloud Inhomogeneity and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative Effects of Cloud Inhomogeneity and Geometric Association Over the Tropical Western Pacific Warm Pool X. Wu National Center for Atmospheric Research (a) Boulder, Colorado X. -Z. Liang Illinois State Water Survey Champaign, Illinois Introduction The representation of cloud systems and cloud-radiation interaction is considered to be one of major uncertainties in general circulation models (GCMs). This arises because (1) complete observations of cloud systems are impossible and available

  20. ARM - Field Campaign - Spring Cloud IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    respectively. From these measurements, cloud condensed water content (CVIcwc) and number concentration (CVInum) are determined. CVInum may be artificially enhanced due to breakup...

  1. ARM - Measurement - Cloud type

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement : Cloud type Cloud type such as cirrus, stratus, cumulus etc Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  2. LNG fire and vapor control system technologies

    SciTech Connect (OSTI)

    Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

    1982-06-01

    This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

  3. Validation of Cloud Properties Derived from GOES-9 Over the ARM...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud phase, effective temperature, effective height, optical depth, effective particle size, and liquid or ice water path. Cloud-top height and thickness are also derived...

  4. Dispelling Clouds of Uncertainty

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lewis, Ernie; Teixeira, João

    2015-06-15

    How do you build a climate model that accounts for cloud physics and the transitions between cloud regimes? Use MAGIC.

  5. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperaturemore » and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.« less

  6. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    SciTech Connect (OSTI)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperature and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.

  7. Month-Long 2D Cloud-Resolving Model Simulation and Resultant Statistics of Cloud Systems Over the ARM SGP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Month-Long 2D Cloud-Resolving Model Simulation and Resultant Statistics of Cloud Systems Over the ARM SGP X. Wu Department of Geological and Atmospheric Sciences Iowa State University Ames, Iowa X.-Z. Liang Illinois State Water Survey University of Illinois Urbana-Champaign, Illinois Introduction The cloud-resolving model (CRM) has recently emerged as a useful tool to develop improved representations of convections, clouds, and cloud-radiation interactions in general circulation models (GCMs).

  8. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  9. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  10. Near-field thermal radiative transfer and thermoacoustic effects from vapor plumes produced by pulsed CO{sub 2} laser ablation of bulk water

    SciTech Connect (OSTI)

    Kudryashov, S. I.; Lyon, Kevin; Allen, S. D.

    2006-12-15

    Submillimeter deep heating of bulk water by thermal radiation from ablative water plumes produced by a 10.6 {mu}m transversely excited atmospheric CO{sub 2} laser and the related acoustic generation has been studied using a contact time-resolved photoacoustic technique. Effective penetration depths of thermal radiation in water were measured as a function of incident laser fluence and the corresponding plume temperatures were estimated. The near-field thermal and thermoacoustic effects of thermal radiation in laser-ablated bulk water and their potential near-field implications are discussed.

  11. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1986-08-15

    The atomic vapor laser isotope separation (AVLIS) process for the enrichment of uranium is evaluated. (AIP)

  12. ARM - Measurement - Cloud location

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    point in space and time, typically expressed as a binary cloud mask. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  13. ARM - Measurement - Cloud extinction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an incident beam by the process of cloud absorption andor scattering. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  14. Dispelling Clouds of Uncertainty

    SciTech Connect (OSTI)

    Lewis, Ernie; Teixeira, João

    2015-06-15

    How do you build a climate model that accounts for cloud physics and the transitions between cloud regimes? Use MAGIC.

  15. Developing and Evaluating Ice Cloud Parameterizations by

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by remote sensing is that the transfer functions which relate the observables (e. g., radar Doppler spectrum) to cloud properties (e. g., ice water content, or IWC) are not...

  16. ARSCL Cloud Statistics - A Value-Added Product

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARSCL Cloud Statistics - A Value-Added Product Y. Shi Pacific Northwest National Laboratory Richland, Washington M. A. Miller Brookhaven National Laboratory Upton, New York Introduction The active remote sensing of cloud layers (ARSCLs) value-added product (VAP) combines data from active remote sensors to produce an objective determination of cloud location, radar reflectivity, vertical velocity, and Doppler spectral width. Information about the liquid water path (LWP) in these clouds and the

  17. Limiting Factors for Convective Cloud Top Height in the Tropics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Limiting Factors for Convective Cloud Top Height in the Tropics M. P. Jensen and A. D. Del Genio National Aeronautics and Space Administration Goddard Institute for Space Studies Columbia University New York, New York Introduction Populations of tropical convective clouds are mainly comprised of three types: shallow trade cumulus, mid-level cumulus congestus and deep convective clouds (Johnson et al. 1999). Each of these cloud types has different impacts on the local radiation and water budgets.

  18. Posters Ship-Based Measurements of Cloud Optical Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the optical properties of MBL clouds using measurements taken on the NOAA research vessel Malcom Baldrige. We seek the relationship between optical depth and liquid water because...

  19. Fundamental to the Cloud Land Surface Interaction Campaign (CLASIC...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in agriculture ranging from more accurate weather forecasting to improved water management decisions and crop yield estimation. CLASIC CLASIC - - LAND LAND Cloud and Land...

  20. RACORO continental boundary layer cloud investigations. 2. Large...

    Office of Scientific and Technical Information (OSTI)

    The case is based on observations obtained during the RACORO Campaign (Routine AtmosphericRadiation Measurement ARM Aerial Facility AAF Clouds with Low Optical Water Depths ...

  1. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, Terry W. (Tracy, CA); Ault, Earl R. (Dublin, CA); Moses, Edward I. (Castro Valley, CA)

    1992-01-01

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

  2. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, T.W.; Ault, E.R.; Moses, E.I.

    1992-12-01

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment. 2 figs.

  3. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  4. ARM - Cloud Memory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Memory Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Cloud Memory Now you can make your own cloud memory game to practice recognizing clouds at home or share with your class. Example (not to scale) of cloud memory card available for download. Example (not to scale) of cloud memory card

  5. In-well vapor stripping drilling and characterization work plan

    SciTech Connect (OSTI)

    Koegler, K.J.

    1994-03-13

    This work plan provides the information necessary for drilling, sampling, and hydrologic testing of wells to be completed in support of a demonstration of the in-well vapor stripping system. The in-well vapor stripping system is a remediation technology designed to preferentially extract volatile organic compounds (VOCs) from contaminated groundwater by converting them to a vapor phase. Air-lift pumping is used to lift and aerate groundwater within the well. The volatiles escaping the aerated water are drawn off by a slight vacuum and treated at the surface while the water is allowed to infiltrate the vadose zone back to the watertable.

  6. Category:Mercury Vapor | Open Energy Information

    Open Energy Info (EERE)

    Mercury Vapor Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Mercury Vapor page? For detailed information on Mercury Vapor as...

  7. Parameterizing Size Distribution in Ice Clouds

    SciTech Connect (OSTI)

    DeSlover, Daniel; Mitchell, David L.

    2009-09-25

    PARAMETERIZING SIZE DISTRIBUTIONS IN ICE CLOUDS David L. Mitchell and Daniel H. DeSlover ABSTRACT An outstanding problem that contributes considerable uncertainty to Global Climate Model (GCM) predictions of future climate is the characterization of ice particle sizes in cirrus clouds. Recent parameterizations of ice cloud effective diameter differ by a factor of three, which, for overcast conditions, often translate to changes in outgoing longwave radiation (OLR) of 55 W m-2 or more. Much of this uncertainty in cirrus particle sizes is related to the problem of ice particle shattering during in situ sampling of the ice particle size distribution (PSD). Ice particles often shatter into many smaller ice fragments upon collision with the rim of the probe inlet tube. These small ice artifacts are counted as real ice crystals, resulting in anomalously high concentrations of small ice crystals (D < 100 m) and underestimates of the mean and effective size of the PSD. Half of the cirrus cloud optical depth calculated from these in situ measurements can be due to this shattering phenomenon. Another challenge is the determination of ice and liquid water amounts in mixed phase clouds. Mixed phase clouds in the Arctic contain mostly liquid water, and the presence of ice is important for determining their lifecycle. Colder high clouds between -20 and -36 oC may also be mixed phase but in this case their condensate is mostly ice with low levels of liquid water. Rather than affecting their lifecycle, the presence of liquid dramatically affects the cloud optical properties, which affects cloud-climate feedback processes in GCMs. This project has made advancements in solving both of these problems. Regarding the first problem, PSD in ice clouds are uncertain due to the inability to reliably measure the concentrations of the smallest crystals (D < 100 m), known as the small mode. Rather than using in situ probe measurements aboard aircraft, we employed a treatment of ice cloud optical properties formulated in terms of PSD parameters in combination with remote measurements of thermal radiances to characterize the small mode. This is possible since the absorption efficiency (Qabs) of small mode crystals is larger at 12 m wavelength relative to 11 m wavelength due to the process of wave resonance or photon tunneling more active at 12 m. This makes the 12/11 m absorption optical depth ratio (or equivalently the 12/11 m Qabs ratio) a means for detecting the relative concentration of small ice particles in cirrus. Using this principle, this project tested and developed PSD schemes that can help characterize cirrus clouds at each of the three ARM sites: SGP, NSA and TWP. This was the main effort of this project. These PSD schemes and ice sedimentation velocities predicted from them have been used to test the new cirrus microphysics parameterization in the GCM known as the Community Climate Systems Model (CCSM) as part of an ongoing collaboration with NCAR. Regarding the second problem, we developed and did preliminary testing on a passive thermal method for retrieving the total water path (TWP) of Arctic mixed phase clouds where TWPs are often in the range of 20 to 130 g m-2 (difficult for microwave radiometers to accurately measure). We also developed a new radar method for retrieving the cloud ice water content (IWC), which can be vertically integrated to yield the ice water path (IWP). These techniques were combined to determine the IWP and liquid water path (LWP) in Arctic clouds, and hence the fraction of ice and liquid water. We have tested this approach using a case study from the ARM field campaign called M-PACE (Mixed-Phase Arctic Cloud Experiment). This research led to a new satellite remote sensing method that appears promising for detecting low levels of liquid water in high clouds typically between -20 and -36 oC. We hope to develop this method in future research.

  8. Scanning ARM Cloud Radars. Part II: Data Quality Control and Processing

    SciTech Connect (OSTI)

    Kollias, Pavlos; Jo, Ieng; Borque, Paloma; Tatarevic, Aleksandra; Lamer, Katia; Bharadwaj, Nitin; Widener, Kevin B.; Johnson, Karen L.; Clothiaux, Eugene E.

    2014-03-01

    The Scanning ARM Cloud Radars (SACRs) are the primary instruments for documenting the four-dimensional structure and evolution of clouds within a 20-30 km radius from the ARM fixed and mobile sites. Here, the post-processing of the calibrated SACR measurements is discussed. First, a feature mask algorithm that objectively determines the presence of significant radar returns is described. The feature mask algorithm is based on the statistical properties of radar receiver noise. It accounts for atmospheric emission and is applicable even for SACR profiles with few or no signal-free range gates. Using the nearest-in-time atmospheric sounding, the SACR radar reflectivities are corrected for gaseous attenuation (water vapor and oxygen) using a line-by-line absorption model. Despite having a high pulse repetition frequency, the SACR has a narrow Nyquist velocity limit and thus Doppler velocity folding is commonly observed. An unfolding algorithm that makes use of a first guess for the true Doppler velocity using horizontal wind measurements from the nearest sounding is described. The retrieval of the horizontal wind profile from the HS-RHI SACR scan observations and/or nearest sounding is described. The retrieved horizontal wind profile can be used to adaptively configure SACR scan strategies that depend on wind direction. Several remaining challenges are discussed, including the removal of insect and second-trip echoes. The described algorithms significantly enhance SACR data quality and constitute an important step towards the utilization of SACR measurements for cloud research.

  9. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  10. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1985-11-08

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power reactor fuel has been under development for over 10 years. In June 1985 the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for the internationally competitive production of uranium separative work. The economic basis for this decision is considered, with an indicated of the constraints placed on the process figures of merit and the process laser system. We then trace an atom through a generic AVLIS separator and give examples of the physical steps encountered, the models used to describe the process physics, the fundamental parameters involved, and the role of diagnostic laser measurements.

  11. Stratified vapor generator

    DOE Patents [OSTI]

    Bharathan, Desikan (Lakewood, CO); Hassani, Vahab (Golden, CO)

    2008-05-20

    A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

  12. Intercomparison of Large-eddy Simulations of Arctic Mixed-phase Clouds: Importance of Ice Size Distribution Assumptions

    SciTech Connect (OSTI)

    Ovchinnikov, Mikhail; Ackerman, Andrew; Avramov, Alex; Cheng, Anning; Fan, Jiwen; Fridlind, Ann; Ghan, Steven J.; Harrington, Jerry Y.; Hoose, Corinna; Korolev, Alexei; McFarquhar, Greg; Morrison, H.; Paukert, Marco; Savre, Julien; Shipway, Ben; Shupe, Matthew D.; Solomon, Amy; Sulia, Kara

    2014-03-14

    Large-eddy simulations of mixed-phase Arctic clouds by 11 different models are analyzed with the goal of improving understanding and model representation of processes controlling the evolution of these clouds. In a case based on observations from the Indirect and Semi-Direct Aerosol Campaign (ISDAC), it is found that ice number concentration, Ni, exerts significant influence on the cloud structure. Increasing Ni leads to a substantial reduction in liquid water path (LWP) and potential cloud dissipation, in agreement with earlier studies. By comparing simulations with the same microphysics coupled to different dynamical cores as well as the same dynamics coupled to different microphysics schemes, it is found that the ice water path (IWP) is mainly controlled by ice microphysics, while the inter-model differences in LWP are largely driven by physics and numerics of the dynamical cores. In contrast to previous intercomparisons, all models here use the same ice particle properties (i.e., mass-size, mass-fall speed, and mass-capacitance relationships) and a common radiation parameterization. The constrained setup exposes the importance of ice particle size distributions (PSD) in influencing cloud evolution. A clear separation in LWP and IWP predicted by models with bin and bulk microphysical treatments is documented and attributed primarily to the assumed shape of ice PSD used in bulk schemes. Compared to the bin schemes that explicitly predict the PSD, schemes assuming exponential ice PSD underestimate ice growth by vapor deposition and overestimate mass-weighted fall speed leading to an underprediction of IWP by a factor of two in the considered case.

  13. The vapor pressures of explosives

    SciTech Connect (OSTI)

    Ewing, Robert G.; Waltman, Melanie J.; Atkinson, David A.; Grate, Jay W.; Hotchkiss, Peter

    2013-01-05

    The vapor pressures of many explosive compounds are extremely low and thus determining accurate values proves difficult. Many researchers, using a variety of methods, have measured and reported the vapor pressures of explosives compounds at single temperatures, or as a function of temperature using vapor pressure equations. There are large variations in reported vapor pressures for many of these compounds, and some errors exist within individual papers. This article provides a review of explosive vapor pressures and describes the methods used to determine them. We have compiled primary vapor pressure relationships traceable to the original citations and include the temperature ranges for which they have been determined. Corrected values are reported as needed and described in the text. In addition, after critically examining the available data, we calculate and tabulate vapor pressures at 25 C.

  14. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect (OSTI)

    Eric M. Suuberg; Vahur Oja

    1997-07-01

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  15. ARM Cloud Aerosol Precipitation Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Precipitation Experiment a NOAA ship in the Pacific Ocean and on a DOE- sponsored plane over land and sea. These researchers will study: (1) water sources, evolution and structure of atmospheric rivers over the Pacific Ocean (2) long range transport of aerosols over the Pacific Ocean between Hawaii and the U.S. West Coast, and how aerosols interact with atmospheric rivers (3) the point where atmospheric rivers make landfall on the U.S. West Coast, especially how clouds form where

  16. Using Radar, Lidar, and Radiometer measurements to Classify Cloud Type and Study Middle-Level Cloud Properties

    SciTech Connect (OSTI)

    Wang, Zhien

    2010-06-29

    The project is mainly focused on the characterization of cloud macrophysical and microphysical properties, especially for mixed-phased clouds and middle level ice clouds by combining radar, lidar, and radiometer measurements available from the ACRF sites. First, an advanced mixed-phase cloud retrieval algorithm will be developed to cover all mixed-phase clouds observed at the ACRF NSA site. The algorithm will be applied to the ACRF NSA observations to generate a long-term arctic mixed-phase cloud product for model validations and arctic mixed-phase cloud processes studies. To improve the representation of arctic mixed-phase clouds in GCMs, an advanced understanding of mixed-phase cloud processes is needed. By combining retrieved mixed-phase cloud microphysical properties with in situ data and large-scale meteorological data, the project aim to better understand the generations of ice crystals in supercooled water clouds, the maintenance mechanisms of the arctic mixed-phase clouds, and their connections with large-scale dynamics. The project will try to develop a new retrieval algorithm to study more complex mixed-phase clouds observed at the ACRF SGP site. Compared with optically thin ice clouds, optically thick middle level ice clouds are less studied because of limited available tools. The project will develop a new two wavelength radar technique for optically thick ice cloud study at SGP site by combining the MMCR with the W-band radar measurements. With this new algorithm, the SGP site will have a better capability to study all ice clouds. Another area of the proposal is to generate long-term cloud type classification product for the multiple ACRF sites. The cloud type classification product will not only facilitates the generation of the integrated cloud product by applying different retrieval algorithms to different types of clouds operationally, but will also support other research to better understand cloud properties and to validate model simulations. The ultimate goal is to improve our cloud classification algorithm into a VAP.

  17. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  18. Supercooled liquid water Estimation Tool

    Energy Science and Technology Software Center (OSTI)

    2012-05-04

    The Cloud Supercooled liquid water Estimation Tool (SEET) is a user driven Graphical User Interface (GUI) that estimates cloud supercooled liquid water (SLW) content in terms of vertical column and total mass from Moderate resolution Imaging Supercooled liquid water Estimation Tool Spectroradiometer (MODIS) spatially derived cloud products and realistic vertical cloud parameterizations that are user defined. It also contains functions for post-processing of the resulting data in tabular and graphical form.

  19. Vapor Barriers or Vapor Diffusion Retarders | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    called "structural" vapor diffusion retarders. Materials such as rigid foam insulation, reinforced plastics, aluminum, and stainless steel are relatively resistant to...

  20. Transport diffusion of liquid water and methanol through membranes...

    Office of Scientific and Technical Information (OSTI)

    DIFFUSION; MEMBRANES; METHANOL; TRANSPORT; WATER; GOLD; SURFACES; COMPUTER CALCULATIONS DIFFUSION; WATER; METHANOL; GOLD; MEMBRANES; SURFACES; COMPUTER CALCULATIONS Word Cloud ...

  1. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J.

    1996-12-31

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  2. MAGIC Cloud Properties from Zenith Radiance Data Final Campaign Summary

    SciTech Connect (OSTI)

    Chiu, J. -Y.C.; Gregory, L.; Wagener, R.

    2016-01-01

    Cloud droplet size and optical depth are the most fundamental properties for understanding cloud formation, dissipation and interactions with aerosol and drizzle. They are also a crucial determinant of Earth’s radiative and water-energy balances. However, these properties are poorly predicted in climate models. As a result, the response of clouds to climate change is one of the major sources of uncertainty in climate prediction.

  3. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CART RL Order Data Westwater ETL MWR Order Data Whiteman GSFC RL Order Data GallagherWeber Dataplane Order Data Gutman GPS Order Data Lesht BBSS Order Data Morris CART MWR Order...

  4. ARM - Measurement - Cloud fraction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fraction ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud fraction Fraction of sky covered by clouds. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance

  5. Finance Idol Word Cloud

    Broader source: Energy.gov [DOE]

    This word cloud represents the topics discussed during the Big and Small Ideas: How to Lower Solar Financing Costs breakout session at the SunShot Grand Challenge.

  6. ARM - Measurement - Cloud phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that involves property descriptors such as stratus, cumulus, and cirrus. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  7. Ice Nucleation of Bare and Sulfuric Acid-coated Mineral Dust Particles and Implication for Cloud Properties

    SciTech Connect (OSTI)

    Kulkarni, Gourihar R.; Sanders, Cassandra N.; Zhang, Kai; Liu, Xiaohong; Zhao, Chun

    2014-08-27

    Ice nucleation properties of different dust species coated with soluble material are not well understood. We determined the ice nucleation ability of bare and sulfuric acid coated mineral dust particles as a function of temperature (-25 to -35 deg C) and relative humidity with respect to water (RHw). Five different mineral dust species: Arizona test dust (ATD), illite, montmorillonite, quartz and kaolinite were dry dispersed and size-selected at 150 nm and exposed to sulfuric acid vapors in the coating apparatus. The condensed sulfuric acid soluble mass fraction per particle was estimated from the cloud condensation nuclei activated fraction measurements. The fraction of dust particles nucleating ice at various temperatures and RHw was determined using a compact ice chamber. In water-subsaturated conditions, compared to bare dust particles, we found that only coated ATD particles showed suppression of ice nucleation ability while other four dust species did not showed the effect of coating on the fraction of particles nucleating ice. The results suggest that interactions between the dust surface and sulfuric acid vapor are important, such that interactions may or may not modify the surface via chemical reactions with sulfuric acid. At water-supersaturated conditions we did not observed the effect of coating, i.e. the bare and coated dust particles had similar ice nucleation behavior.

  8. Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fielding, M. D.; Chiu, J. C.; Hogan, R. J.; Feingold, G.; Eloranta, E.; O'Connor, E. J.; Cadeddu, M. P.

    2015-02-16

    Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar reflectivity. We present a new method to simultaneously retrieve cloud and drizzle vertical profiles in drizzling boundary-layer cloud using surface-based observations of radar reflectivity, lidar attenuated backscatter, and zenith radiances. Specifically, the vertical structure of droplet size and water content of both cloud and drizzle is characterised throughout the cloud. An ensemble optimal estimation approach provides full error statistics given the uncertainty in the observations. To evaluate the new method, we first perform retrievals using synthetic measurements from large-eddy simulation snapshots of cumulusmore » under stratocumulus, where cloud water path is retrieved with an error of 31 g m−2. The method also performs well in non-drizzling clouds where no assumption of the cloud profile is required. We then apply the method to observations of marine stratocumulus obtained during the Atmospheric Radiation Measurement MAGIC deployment in the northeast Pacific. Here, retrieved cloud water path agrees well with independent 3-channel microwave radiometer retrievals, with a root mean square difference of 10–20 g m−2.« less

  9. Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fielding, M. D.; Chiu, J. C.; Hogan, R. J.; Feingold, G.; Eloranta, E.; O'Connor, E. J.; Cadeddu, M. P.

    2015-07-02

    Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar reflectivity. We present a new method to simultaneously retrieve cloud and drizzle vertical profiles in drizzling boundary-layer clouds using surface-based observations of radar reflectivity, lidar attenuated backscatter, and zenith radiances under conditions when precipitation does not reach the surface. Specifically, the vertical structure of droplet size and water content of both cloud and drizzle is characterised throughout the cloud. An ensemble optimal estimation approach provides full error statistics given the uncertainty in the observations. To evaluate the new method, we first perform retrievalsmore » using synthetic measurements from large-eddy simulation snapshots of cumulus under stratocumulus, where cloud water path is retrieved with an error of 31 g m-2. The method also performs well in non-drizzling clouds where no assumption of the cloud profile is required. We then apply the method to observations of marine stratocumulus obtained during the Atmospheric Radiation Measurement MAGIC deployment in the Northeast Pacific. Here, retrieved cloud water path agrees well with independent three-channel microwave radiometer retrievals, with a root mean square difference of 10–20 g m-2.« less

  10. Promising Technology: Condensing Gas Water Heaters

    Broader source: Energy.gov [DOE]

    Condensing water heaters achieve higher efficiencies than conventional water heaters by capturing the latent heat from water vapor contained in the flue gases. Combustion gases are exhausted through a secondary heat exchanger where the latent heat of water vapor in the exhaust gas is transferred to the stored water. This technology enables the water heater to achieve thermal efficiencies up to 99%.

  11. Overview of the COPS Aerosol and Cloud Microphysics (ACM) Subgroup...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at the AMF for Jun-Aug 2007 - Multi-wavelength aerosol and water vapor lidar (BERTHA) - Doppler wind lidar * Mainly in vertical-pointing mode * Operated primarily in the daytime,...

  12. Boundary Layer Cloud Turbulence Characteristics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (10) Modeling Need (10) Cloud Boundaries 9 9 Cloud Fraction Variance Skewness UpDowndraft coverage Dominant Freq. signal Dissipation rate ??? Observation-Modeling Interface...

  13. TC_CLOUD_REGIME.cdr

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    intensity (e.g. May and Ballinger, 2007) Resulting Cloud Properties Examine rain DSD using polarimetric radar Examine ice cloud properties using MMCR and MPL Expect...

  14. ARM - Measurement - Cloud droplet size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    droplet size Linear size (e.g. radius or diameter) of a cloud particle Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  15. ARM - Measurement - Cloud effective radius

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the number size distribution of cloud particles, whether liquid or ice. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  16. Cloud computing security.

    SciTech Connect (OSTI)

    Shin, Dongwan; Claycomb, William R.; Urias, Vincent E.

    2010-10-01

    Cloud computing is a paradigm rapidly being embraced by government and industry as a solution for cost-savings, scalability, and collaboration. While a multitude of applications and services are available commercially for cloud-based solutions, research in this area has yet to fully embrace the full spectrum of potential challenges facing cloud computing. This tutorial aims to provide researchers with a fundamental understanding of cloud computing, with the goals of identifying a broad range of potential research topics, and inspiring a new surge in research to address current issues. We will also discuss real implementations of research-oriented cloud computing systems for both academia and government, including configuration options, hardware issues, challenges, and solutions.

  17. Parameterizations of Cloud Microphysics and Indirect Aerosol Effects

    SciTech Connect (OSTI)

    Tao, Wei-Kuo

    2014-05-19

    1. OVERVIEW Aerosols and especially their effect on clouds are one of the key components of the climate system and the hydrological cycle [Ramanathan et al., 2001]. Yet, the aerosol effect on clouds remains largely unknown and the processes involved not well understood. A recent report published by the National Academy of Science states "The greatest uncertainty about the aerosol climate forcing - indeed, the largest of all the uncertainties about global climate forcing - is probably the indirect effect of aerosols on clouds [NRC, 2001]." The aerosol effect on clouds is often categorized into the traditional "first indirect (i.e., Twomey)" effect on the cloud droplet sizes for a constant liquid water path [Twomey, 1977] and the "semi-direct" effect on cloud coverage [e.g., Ackerman et al., 2000]. Enhanced aerosol concentrations can also suppress warm rain processes by producing a narrow droplet spectrum that inhibits collision and coalescence processes [e.g., Squires and Twomey, 1961; Warner and Twomey, 1967; Warner, 1968; Rosenfeld, 1999]. The aerosol effect on precipitation processes, also known as the second type of aerosol indirect effect [Albrecht, 1989], is even more complex, especially for mixed-phase convective clouds. Table 1 summarizes the key observational studies identifying the microphysical properties, cloud characteristics, thermodynamics and dynamics associated with cloud systems from high-aerosol continental environments. For example, atmospheric aerosol concentrations can influence cloud droplet size distributions, warm-rain process, cold-rain process, cloud-top height, the depth of the mixed phase region, and occurrence of lightning. In addition, high aerosol concentrations in urban environments could affect precipitation variability by providing an enhanced source of cloud condensation nuclei (CCN). Hypotheses have been developed to explain the effect of urban regions on convection and precipitation [van den Heever and Cotton, 2007 and Shepherd, 2005]. Recently, a detailed spectral-bin microphysical scheme was implemented into the Goddard Cumulus Ensemble (GCE) model. Atmospheric aerosols are also described using number density size-distribution functions. A spectral-bin microphysical model is very expensive from a computational point of view and has only been implemented into the 2D version of the GCE at the present time. The model is tested by studying the evolution of deep tropical clouds in the west Pacific warm pool region and summertime convection over a mid-latitude continent with different concentrations of CCN: a low "clean" concentration and a high "dirty" concentration. The impact of atmospheric aerosol concentration on cloud and precipitation will be investigated. 2. MODEL DESCRIPTION AND CASE STUDIES 2.1 GCE MODEL The model used in this study is the 2D version of the GCE model. Modeled flow is anelastic. Second- or higher-order advection schemes can produce negative values in the solution. Thus, a Multi-dimensional Positive Definite Advection Transport Algorithm (MPDATA) has been implemented into the model. All scalar variables (potential temperature, water vapor, turbulent coefficient and all five hydrometeor classes) use forward time differencing and the MPDATA for advection. Dynamic variables, u, v and w, use a second-order accurate advection scheme and a leapfrog time integration (kinetic energy semi-conserving method). Short-wave (solar) and long-wave radiation as well as a subgrid-scale TKE turbulence scheme are also included in the model. Details of the model can be found in Tao and Simpson (1993) and Tao et al. (2003). 2.2 Microphysics (Bin Model) The formulation of the explicit spectral-bin microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (cloud droplets and raindrops), and six types of ice particles: pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail. Each type is described by a special size distribution function containing 33 categories (bins). Atmospheric aerosols are also described using number density size-distribution functions (containing 33 bins). Droplet nucleation (activation) is derived from the analytical calculation of super-saturation, which is used to determine the sizes of aerosol particles to be activated and the corresponding sizes of nucleated droplets. Primary nucleation of each type of ice crystal takes place within certain temperature ranges. A detailed description of these explicitly parameterized processes can be found in Khain and Sednev (1996) and Khain et al. (1999, 2001). 2.3 Case Studies Three cases, a tropical oceanic squall system observed during TOGA COARE (Tropical Ocean and Global Atmosphere Coupled Ocean-Atmosphere Response Experiment, which occurred over the Pacific Ocean warm pool from November 1992 to February 1993), a midlatitude continental squall system observed during PRESTORM (Preliminary Regional Experiment for STORM-Central, which occurred in Kansas and Oklahoma during May-June 1985), and mid-afternoon convection observed during CRYSTAL-FACE (Cirrus Regional Study of Tropical Anvils and Cirrus Layers – Florida Area Cumulus Experiment, which occurred in Florida during July 2002), will be used to examine the impact of aerosols on deep, precipitating systems. 3. SUMMARY of RESULTS • For all three cases, higher CCN produces smaller cloud droplets and a narrower spectrum. Dirty conditions delay rain formation, increase latent heat release above the freezing level, and enhance vertical velocities at higher altitude for all cases. Stronger updrafts, deeper mixed-phase regions, and more ice particles are simulated with higher CCN in good agreement with observations. • In all cases, rain reaches the ground early with lower CCN. Rain suppression is also evident in all three cases with high CCN in good agreement with observations (Rosenfeld, 1999, 2000 and others). Rain suppression, however, only occurs during the first hour of simulation. This result suggests that microphysical processes dominate the impact of aerosols on precipitation in the early stage of precipitation development. • During the mature stage of the simulations, the effect of increasing aerosol concentration ranges from rain suppression in the PRESTORM case to little effect on surface rainfall in the CRYSTAL-FACE case to rain enhancement in the TOGA COARE case. • The model results suggest that evaporative cooling is a key process in determining whether higher CCN reduces or enhances precipitation. Cold pool strength can be enhanced by stronger evaporation. When cold pool interacts with the near surface wind shear, the low-level convergence can be stronger, facilitating secondary cloud formation and more vigorous precipitation processes. Evaporative cooling is more than two times stronger at low levels with higher CCN for the TOGA COARE case during the early stages of precipitation development. However, evaporative cooling is slightly stronger at lower levels with lower CCN for the PRESTORM case. The early formation of rain in the clean environment could allow for the formation of an earlier and stronger cold pool compared to a dirty environment. PRESTORM has a very dry environment and both large and small rain droplets can evaporate. Consequently, the cold pool is relatively weaker, and the system is relatively less intense with higher CCN. • Sensitivity tests are conducted to determine the impact of ice processes on aerosol-precipitation interaction. The results suggested that ice processes are crucial for suppressing precipitation due to high CCN for the PRESTORM case. More and smaller ice particles are generated in the dirty case and transported to the trailing stratiform region. This reduces the heavy convective rain and contributes to the weakening of the cold pool. Warm rain processes dominate the TOGA COARE case. Therefore, ice processes only play a secondary role in terms of aerosol-precipitation interaction. • Two of the three cloud systems presented in this paper formed a line structure (squall system). A 2D simulation, therefore, gives a good approximation to such a line of convective clouds. Since the real atmosphere is 3D, further 3D cloud-resolving simulations are needed to address aerosol-precipitation interactions. 4. REFERENCES Tao, W.-K., X. Li, A. Khain, T. Matsui, S. Lang, and J. Simpson, 2007: The role of atmospheric aerosol concentration on deep convective precipitation: Cloud-resolving model simulations. J. Geophy. Res., 112, D24S18, doi:10.1029/2007JD008728. All other references can be found in above paper. 5. Acknowledgements The GCE model is mainly supported by the NASA Headquarters Atmospheric Dynamics and Thermodynamics Program and the NASA Tropical Rainfall Measuring Mission (TRMM). The research was also supported by the Office of Science (BER), U. S. Department of Energy/Atmospheric Radiation Measurement (DOE/ARM) Interagency. The authors acknowledge NASA Goddard Space Flight Center for computer time used in this research.

  18. Portable vapor diffusion coefficient meter

    DOE Patents [OSTI]

    Ho, Clifford K.

    2007-06-12

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  19. Vapor deposition of hardened niobium

    DOE Patents [OSTI]

    Blocher, Jr., John M.; Veigel, Neil D.; Landrigan, Richard B.

    1983-04-19

    A method of coating ceramic nuclear fuel particles containing a major amount of an actinide ceramic in which the particles are placed in a fluidized bed maintained at ca. 800.degree. to ca. 900.degree. C., and niobium pentachloride vapor and carbon tetrachloride vapor are led into the bed, whereby niobium metal is deposited on the particles and carbon is deposited interstitially within the niobium. Coating apparatus used in the method is also disclosed.

  20. Posters Parameterization of Thin Mid-Level Stratiform Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thickness or its tendency within a GCM layer from the large-scale fields. 5. Develop and test a parameterization of altocumulus cloud layer optical properties (liquid water path...

  1. Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations D. D. Turner University of Wisconsin-Madison Madison, Wisconsin and Pacific Northwest National Laboratory Richland, Washington Abstract A novel new approach to retrieve cloud microphysical properties from mixed-phase clouds is presented. This algorithm retrieves cloud optical depth, ice fraction, and the effective size of the water and ice particles from ground-based, high-resolution infrared radiance

  2. Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud

    SciTech Connect (OSTI)

    Klein, S A; McCoy, R B; Morrison, H; Ackerman, A; Avramov, A; deBoer, G; Chen, M; Cole, J; DelGenio, A; Golaz, J; Hashino, T; Harrington, J; Hoose, C; Khairoutdinov, M; Larson, V; Liu, X; Luo, Y; McFarquhar, G; Menon, S; Neggers, R; Park, S; Poellot, M; von Salzen, K; Schmidt, J; Sednev, I; Shipway, B; Shupe, M; Spangenberg, D; Sud, Y; Turner, D; Veron, D; Falk, M; Foster, M; Fridlind, A; Walker, G; Wang, Z; Wolf, A; Xie, S; Xu, K; Yang, F; Zhang, G

    2008-02-27

    Results are presented from an intercomparison of single-column and cloud-resolving model simulations of a cold-air outbreak mixed-phase stratocumulus cloud observed during the Atmospheric Radiation Measurement (ARM) program's Mixed-Phase Arctic Cloud Experiment. The observed cloud occurred in a well-mixed boundary layer with a cloud top temperature of -15 C. The observed liquid water path of around 160 g m{sup -2} was about two-thirds of the adiabatic value and much greater than the mass of ice crystal precipitation which when integrated from the surface to cloud top was around 15 g m{sup -2}. The simulations were performed by seventeen single-column models (SCMs) and nine cloud-resolving models (CRMs). While the simulated ice water path is generally consistent with the observed values, the median SCM and CRM liquid water path is a factor of three smaller than observed. Results from a sensitivity study in which models removed ice microphysics indicate that in many models the interaction between liquid and ice-phase microphysics is responsible for the large model underestimate of liquid water path. Despite this general underestimate, the simulated liquid and ice water paths of several models are consistent with the observed values. Furthermore, there is some evidence that models with more sophisticated microphysics simulate liquid and ice water paths that are in better agreement with the observed values, although considerable scatter is also present. Although no single factor guarantees a good simulation, these results emphasize the need for improvement in the model representation of mixed-phase microphysics. This case study, which has been well observed from both aircraft and ground-based remote sensors, could be a benchmark for model simulations of mixed-phase clouds.

  3. Automated detection of cloud and cloud-shadow in single-date Landsat imagery using neural networks and spatial post-processing

    SciTech Connect (OSTI)

    Hughes, Michael J. [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Hayes, Daniel J [ORNL] [ORNL

    2014-01-01

    Use of Landsat data to answer ecological questions is contingent on the effective removal of cloud and cloud shadow from satellite images. We develop a novel algorithm to identify and classify clouds and cloud shadow, \\textsc{sparcs}: Spacial Procedures for Automated Removal of Cloud and Shadow. The method uses neural networks to determine cloud, cloud-shadow, water, snow/ice, and clear-sky membership of each pixel in a Landsat scene, and then applies a set of procedures to enforce spatial rules. In a comparison to FMask, a high-quality cloud and cloud-shadow classification algorithm currently available, \\textsc{sparcs} performs favorably, with similar omission errors for clouds (0.8% and 0.9%, respectively), substantially lower omission error for cloud-shadow (8.3% and 1.1%), and fewer errors of commission (7.8% and 5.0%). Additionally, textsc{sparcs} provides a measure of uncertainty in its classification that can be exploited by other processes that use the cloud and cloud-shadow detection. To illustrate this, we present an application that constructs obstruction-free composites of images acquired on different dates in support of algorithms detecting vegetation change.

  4. Scanning ARM Cloud Radars Part II: Data Quality Control and Processing

    SciTech Connect (OSTI)

    Kollias, Pavlos; Jo, Ieng; Borque, Paloma; Tatarevic, Aleksandra; Lamer, Katia; Bharadwaj, Nitin; Widener, Kevin B.; Johnson, Karen; Clothiaux, Eugene E.

    2014-03-01

    The Scanning ARM Cloud Radars (SACRs) are the primary instruments for documenting the four-dimensional structure and evolution of clouds within a 20-30 km radius from the ARM fixed and mobile sites. Here, the post-processing of the calibrated SACR measurements is discussed. First, a feature mask algorithm that objectively determines the presence of significant radar returns is described. The feature mask algorithm is based on the statistical properties of radar receiver noise. It accounts for atmospheric emission and is applicable even for SACR profiles with few or no signal-free range gates. Using the nearest-in-time atmospheric sounding, the SACR radar reflectivities are corrected for gaseous attenuation (water vapor and oxygen) using a line-by-line absorption model. Despite having a high pulse repetition frequency, the SACR has a narrow Nyquist velocity limit and thus Doppler velocity folding is commonly observed. An unfolding algorithm that makes use of a first guess for the true Doppler velocity using horizontal wind measurements from the nearest sounding is described. The retrieval of the horizontal wind profile from the Hemispherical Sky Range Height Indicator SACR scan observations and/or nearest sounding is described. The retrieved horizontal wind profile can be used to adaptively configure SACR scan strategies that depend on wind direction. Several remaining challenges are discussed, including the removal of insect and second-trip echoes. The described algorithms significantly enhance SACR data quality and constitute an important step towards the utilization of SACR measurements for cloud research.

  5. A 10 Year Climatology of Arctic Cloud Fraction and Radiative Forcing at Barrow, Alaska

    SciTech Connect (OSTI)

    Dong, Xiquan; Xi, Baike; Crosby, Kathryn; Long, Charles N.; Stone, R. S.; Shupe, Matthew D.

    2010-09-15

    A 10-yr record of Arctic cloud fraction and surface radiation budget has been generated using data collected from June 1998 to May 2008 at the Atmospheric Radiation Measurement (ARM) North Slope of Alaska (NSA) site and the nearby NOAA Barrow Observatory (BRW). The record includes the seasonal variations of cloud fraction (CF), cloud liquid water path (LWP), precipitable water vapor (PWV), surface albedo, shortwave (SW) and longwave (LW) fluxes and cloud radative forcings (CRFs), as well as their decadal variations. Values of CF derived from different instruments and methods agree well, having an annual average of ~0.74. Cloudiness increases from March to May, remains high (~0.8-0.9) from May to October, and then decreases over winter. More clouds and higher LWP and PWV occurred during the warm season (May-October) than the cold season (November-April). These results are strongly associated with southerly flow which transports warm, moist air masses to Barrow from the North Pacific and over area of Alaska already free of snow during the warm season and with a dipole pattern of pressure in which a high is centered over the Beaufort Sea and low over the Aleutians during the cold season. The monthly means of estimated clear-sky and measured allsky SW-down and LW-down fluxes at the two facilities are almost identical with the annual mean differences less than 1.6 W m-2. The downwelling and upwelling LW fluxes remain almost constant from January to March, then increase from March and peak during July-August. SW-down fluxes are primarily determined by seasonal changes in the intensity and duration of insolation over Northern Alaska, and are also strongly dependent on cloud fraction and optical depth, and surface albedo. The monthly variations of NET CRF generally follow the cycle of SW CRF, modulated by LW effects. On annual average, the negative SW CRF and positive LW CRF tend to cancel, resulting in annual average NET CRF of 2-4.5 Wm-2. Arctic clouds have a 3 net warming effect on the surface throughout the year, with exception of the snow-free period from middle June to middle September when there tends to be a cooling effect. The daily average surface albedos agree well at the two sites remaining high (>0.8) until late May, dropping below 0.2 after the snow melts around June and increasing during autumn once snow begins to accumulate. On the basis of long-term regression analyses CF has decreased by about 0.048 while temperature has risen by ?1.1 K over the 10-yr period, which can be characterized by tendencies of warming mainly during December and April. With regard to the 2007 record minimum Arctic ice extent, this study provides additional empirical evidence that decreased cloud cover and increased SW-down flux during summer contributed to anomalous ice melt in the region north of Barrow. At Barrow, average June-August CF decreased by 0.062 in 2007 from the 10-yr mean, while SW-down and NET fluxes increased by 28.4 Wm-2 and 11.3 Wm-2, respectively. The increase in the NET radiative flux during summer 2007 most likely contributed to an increase in surface air temperature of 1.6 K.

  6. Cloud Properties and Radiative Heating Rates for TWP

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Comstock, Jennifer

    2013-11-07

    A cloud properties and radiative heating rates dataset is presented where cloud properties retrieved using lidar and radar observations are input into a radiative transfer model to compute radiative fluxes and heating rates at three ARM sites located in the Tropical Western Pacific (TWP) region. The cloud properties retrieval is a conditional retrieval that applies various retrieval techniques depending on the available data, that is if lidar, radar or both instruments detect cloud. This Combined Remote Sensor Retrieval Algorithm (CombRet) produces vertical profiles of liquid or ice water content (LWC or IWC), droplet effective radius (re), ice crystal generalized effective size (Dge), cloud phase, and cloud boundaries. The algorithm was compared with 3 other independent algorithms to help estimate the uncertainty in the cloud properties, fluxes, and heating rates (Comstock et al. 2013). The dataset is provided at 2 min temporal and 90 m vertical resolution. The current dataset is applied to time periods when the MMCR (Millimeter Cloud Radar) version of the ARSCL (Active Remotely-Sensed Cloud Locations) Value Added Product (VAP) is available. The MERGESONDE VAP is utilized where temperature and humidity profiles are required. Future additions to this dataset will utilize the new KAZR instrument and its associated VAPs.

  7. Cloud Properties and Radiative Heating Rates for TWP

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Comstock, Jennifer

    A cloud properties and radiative heating rates dataset is presented where cloud properties retrieved using lidar and radar observations are input into a radiative transfer model to compute radiative fluxes and heating rates at three ARM sites located in the Tropical Western Pacific (TWP) region. The cloud properties retrieval is a conditional retrieval that applies various retrieval techniques depending on the available data, that is if lidar, radar or both instruments detect cloud. This Combined Remote Sensor Retrieval Algorithm (CombRet) produces vertical profiles of liquid or ice water content (LWC or IWC), droplet effective radius (re), ice crystal generalized effective size (Dge), cloud phase, and cloud boundaries. The algorithm was compared with 3 other independent algorithms to help estimate the uncertainty in the cloud properties, fluxes, and heating rates (Comstock et al. 2013). The dataset is provided at 2 min temporal and 90 m vertical resolution. The current dataset is applied to time periods when the MMCR (Millimeter Cloud Radar) version of the ARSCL (Active Remotely-Sensed Cloud Locations) Value Added Product (VAP) is available. The MERGESONDE VAP is utilized where temperature and humidity profiles are required. Future additions to this dataset will utilize the new KAZR instrument and its associated VAPs.

  8. Magellan: A Cloud Computing Testbed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magellan News & Announcements Archive Petascale Initiative Exascale Computing APEX Home » R & D » Archive » Magellan: A Cloud Computing Testbed Magellan: A Cloud Computing Testbed Cloud computing is gaining a foothold in the business world, but can clouds meet the specialized needs of scientists? That was one of the questions NERSC's Magellan cloud computing testbed explored between 2009 and 2011. The goal of Magellan, a project funded through the U.S. Department of Energy (DOE) Oce

  9. ARM - Measurement - Cloud base height

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    base height ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud base height For a given cloud or cloud layer, the lowest level of the atmosphere where cloud properties are detectable. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  10. ARM - Measurement - Cloud top height

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    top height ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud top height For a given cloud or cloud layer, the highest level of the atmosphere where cloud properties are detectable. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  11. Vapor Pressures and Heats of Vaporization of Primary Coal Tars

    Office of Scientific and Technical Information (OSTI)

    / PC92544-18 VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS FINAL REPORT Grant Dates: August, 1992 - November, 1996 Principal Authors: Eric M. Suuberg (PI) and Vahur Oja Report Submitted: April, 1997 Revised: July, 1997 Grant Number: DE-FG22-92PC92544 Report Submitted by: ERIC M. SUUBERG DIVISION OF ENGINEERING BROWN UNIVERSITY PROVIDENCE, RI 02912 TEL. (401) 863-1420 Prepared For: U. S. DEPT. OF ENERGY FEDERAL ENERGY TECHNOLOGY CENTER P.O. BOX 10940 PITTSBURGH, PA 15236 DR.

  12. First observations of tracking clouds using scanning ARM cloud radars

    SciTech Connect (OSTI)

    Borque, Paloma; Giangrande, Scott; Kollias, Pavlos

    2014-12-01

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (first echo). These measurements complement cloud and precipitation tracking using geostationary satellites and weather radars. Here, two-dimensional (2-D) Along-Wind Range Height Indicator (AW-RHI) observations of a population of shallow cumuli (with and without precipitation) from the 35-GHz scanning ARM cloud radar (SACR) at the DOE Atmospheric Radiation Measurements (ARM) program Southern Great Plains (SGP) site are presented. Observations from the ARM SGP network of scanning precipitation radars are used to provide the larger scale context of the cloud field and to highlight the advantages of the SACR to detect the numerous, small, non-precipitating cloud elements. A new Cloud Identification and Tracking Algorithm (CITA) is developed to track cloud elements. In CITA, a cloud element is identified as a region having a contiguous set of pixels exceeding a preset reflectivity and size threshold. The high temporal resolution of the SACR 2-D observations (30 sec) allows for an area superposition criteria algorithm to match cloud elements at consecutive times. Following CITA, the temporal evolution of cloud element properties (number, size, and maximum reflectivity) is presented. The vast majority of the designated elements during this cumulus event were short-lived non-precipitating clouds having an apparent life cycle shorter than 15 minutes. The advantages and disadvantages of cloud tracking using an SACR are discussed.

  13. First observations of tracking clouds using scanning ARM cloud radars

    SciTech Connect (OSTI)

    Borque, Paloma; Giangrande, Scott; Kollias, Pavlos

    2014-12-01

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (‘‘first echo’’). These measurements complement cloud and precipitation tracking using geostationary satellites and weather radars. Here, two-dimensional (2-D) Along-Wind Range Height Indicator (AW-RHI) observations of a population of shallow cumuli (with and without precipitation) from the 35-GHz scanning ARM cloud radar (SACR) at the DOE Atmospheric Radiation Measurements (ARM) program Southern Great Plains (SGP) site are presented. Observations from the ARM SGP network of scanning precipitation radars are used to provide the larger scale context of the cloud field and to highlight the advantages of the SACR to detect the numerous, small, non-precipitating cloud elements. A new Cloud Identification and Tracking Algorithm (CITA) is developed to track cloud elements. In CITA, a cloud element is identified as a region having a contiguous set of pixels exceeding a preset reflectivity and size threshold. The high temporal resolution of the SACR 2-D observations (30 sec) allows for an area superposition criteria algorithm to match cloud elements at consecutive times. Following CITA, the temporal evolution of cloud element properties (number, size, and maximum reflectivity) is presented. The vast majority of the designated elements during this cumulus event were short-lived non-precipitating clouds having an apparent life cycle shorter than 15 minutes. The advantages and disadvantages of cloud tracking using an SACR are discussed.

  14. Cloud microphysical relationships and their implication on entrainment and mixing mechanism for the stratocumulus clouds measured during the VOCALS project

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yum, Seong Soo; Wang, Jian; Liu, Yangang; Senum, Gunnar; Springston, Stephen; McGraw, Robert; Yeom, Jae Min

    2015-05-27

    Cloud microphysical data obtained from G-1 aircraft flights over the southeastern pacific during the VOCALS-Rex field campaign were analyzed for evidence of entrainment mixing of dry air from above cloud top. Mixing diagram analysis was made for the horizontal flight data recorded at 1 Hz and 40 Hz. The dominant observed feature, a positive relationship between cloud droplet mean volume (V) and liquid water content (L), suggested occurrence of homogeneous mixing. On the other hand, estimation of the relevant scale parameters (i.e., transition length scale and transition scale number) consistently indicated inhomogeneous mixing. Importantly, the flight altitudes of the measurementsmore » were significantly below cloud top. We speculate that mixing of the entrained air near the cloud top may have indeed been inhomogeneous; but due to vertical circulation mixing, the correlation between V and L became positive at the measurement altitudes in mid-level of clouds, because during their descent, cloud droplets evaporate, faster in more diluted cloud parcels, leading to a positive correlation between V and L regardless of the mixing mechanism near the cloud top.« less

  15. Vapor deposition of thin films

    SciTech Connect (OSTI)

    Smith, D.C.; Pattillo, S.G.; Laia, J.R. Jr.; Sattelberger, A.P.

    1990-10-05

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl){sub 3}, iridium(allyl){sub 3}, molybdenum(allyl){sub 4}, tungsten(allyl){sub 4}, rhenium (allyl){sub 4}, platinum(allyl){sub 2}, or palladium(allyl){sub 2} are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  16. Vapor deposition of thin films

    DOE Patents [OSTI]

    Smith, David C. (Los Alamos, NM); Pattillo, Stevan G. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Sattelberger, Alfred P. (Los Alamos, NM)

    1992-01-01

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl).sub.3, iridium(allyl).sub.3, molybdenum(allyl).sub.4, tungsten(allyl).sub.4, rhenium(allyl).sub.4, platinum(allyl).sub.2, or palladium(allyl).sub.2 are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  17. Sensitivity of CAM5-Simulated Arctic Clouds and Radiation to Ice Nucleation Parameterization

    SciTech Connect (OSTI)

    Xie, Shaocheng; Liu, Xiaohong; Zhao, Chuanfeng; Zhang, Yuying

    2013-08-01

    Sensitivity of Arctic clouds and radiation in the Community Atmospheric Model version 5 to the ice nucleation process is examined by testing a new physically based ice nucleation scheme that links the variation of ice nuclei (IN) number concentration to aerosol properties. The default scheme parameterizes the IN concentration simply as a function of ice supersaturation. The new scheme leads to a significant reduction in simulated IN number concentrations at all latitudes while changes in cloud amount and cloud properties are mainly seen in high latitudes and middle latitude storm tracks. In the Arctic, there is a considerable increase in mid-level clouds and a decrease in low clouds, which result from the complex interaction among the cloud macrophysics, microphysics, and the large-scale environment. The smaller IN concentrations result in an increase in liquid water path and a decrease in ice water path due to the slow-down of the Bergeron-Findeisen process in mixed-phase clouds. Overall, there is an increase in the optical depth of Arctic clouds, which leads to a stronger cloud radiative forcing (net cooling) at the top of the atmosphere. The comparison with satellite data shows that the new scheme slightly improves low cloud simulations over most of the Arctic, but produces too many mid-level clouds. Considerable improvements are seen in the simulated low clouds and their properties when compared to Arctic ground-based measurements. Issues with the observations and the model-observation comparison in the Arctic region are discussed.

  18. Microbase Cloud Products and Associated Heating Rates in the Tropical Western Pacific

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microbase Cloud Products and Associated Heating Rates in the Tropical Western Pacific J. H. Mather and S. A. McFarlane Pacific Northwest National Laboratory Richland, Washington Introduction The microbase value added product (Miller et al. 2003) provides a standardized framework for calculating and storing continuous retrievals of cloud microphysical properties including liquid water content (LWC), ice water content (IWC), and cloud droplet size. Microbase is part of the larger broadband heating

  19. Process-model Simulations of Cloud Albedo Enhancement by Aerosols in the Arctic

    SciTech Connect (OSTI)

    Kravitz, Benjamin S.; Wang, Hailong; Rasch, Philip J.; Morrison, H.; Solomon, Amy

    2014-11-17

    A cloud-resolving model is used to simulate the effectiveness of Arctic marine cloud brightening via injection of cloud condensation nuclei (CCN). An updated cloud microphysical scheme is employed, with prognostic CCN and cloud particle numbers in both liquid and mixed-phase marine low clouds. Injection of CCN into the marine boundary layer can delay the collapse of the boundary layer and increase low-cloud albedo. Because nearly all of the albedo effects are in the liquid phase due to the removal of ice water by snowfall when ice processes are involved, albedo increases are stronger for pure liquid clouds than mixed-phase clouds. Liquid precipitation can be suppressed by CCN injection, whereas ice precipitation (snow) is affected less; thus the effectiveness of brightening mixed-phase clouds is lower than for liquid-only clouds. CCN injection into a clean regime results in a greater albedo increase than injection into a polluted regime, consistent with current knowledge about aerosol-cloud interactions. Unlike previous studies investigating warm clouds, dynamical changes in circulation due to precipitation changes are small.

  20. Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

    DOE Patents [OSTI]

    Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

    2014-12-02

    The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

  1. Evaluating and Constraining Ice Cloud Parameterizations in CAM5 using Aircraft Measurements from the SPARTICUS Campaign

    SciTech Connect (OSTI)

    Zhang, Kai; Liu, Xiaohong; Wang, Minghuai; Comstock, Jennifer M.; Mitchell, David; Mishra, Subhashree; Mace, Gerald G.

    2013-01-01

    This study uses aircraft measurements of relative humidity and ice crystal size distribution collected in synoptic cirrus during the SPARTICUS (Small PARTicles In CirrUS) field campaign to evaluate and constrain ice cloud parameterizations in the Community Atmosphere Model version 5. The probability density function (PDF) of ice crystal number concentration (Ni) derived from high frequency (1 Hz) measurements features a strong dependence on ambient temperature. As temperature decreases from -35C to -62C, the peak in the PDF shifts from 10-20 L-1 to 200-1000 L-1, while the ice crystal number concentration shows a factor of 6-7 increase. Model simulations are performed with two different insitu ice nucleation schemes. One of the schemes can reproduce a clear increase of Ni with decreasing temperature, by using either an observation based ice nuclei spectrum or a classical theory based spectrum with a relatively low (5%-10%) maximum freezing ratio for dust aerosols. The simulation with the other scheme, which assumes a high maximum freezing ratio (100%), shows much weaker temperature dependence of Ni. Simulations are also performed to test empirical parameters related to water vapor deposition and the auto-conversion of ice crystals to snow. Results show that a value between 0.05 and 0.1 for the water vapor deposition coefficient and 250 um for the critical ice crystal size can produce good agreements between model simulation and the SPARTICUS measurements in terms of ice crystal number concentration and effective radius. The climate impact of perturbing these parameters is also discussed.

  2. Vapor generation methods for explosives detection research

    SciTech Connect (OSTI)

    Grate, Jay W.; Ewing, Robert G.; Atkinson, David A.

    2012-12-01

    The generation of calibrated vapor samples of explosives compounds remains a challenge due to the low vapor pressures of the explosives, adsorption of explosives on container and tubing walls, and the requirement to manage (typically) multiple temperature zones as the vapor is generated, diluted, and delivered. Methods that have been described to generate vapors can be classified as continuous or pulsed flow vapor generators. Vapor sources for continuous flow generators are typically explosives compounds supported on a solid support, or compounds contained in a permeation or diffusion device. Sources are held at elevated isothermal temperatures. Similar sources can be used for pulsed vapor generators; however, pulsed systems may also use injection of solutions onto heated surfaces with generation of both solvent and explosives vapors, transient peaks from a gas chromatograph, or vapors generated by s programmed thermal desorption. This article reviews vapor generator approaches with emphasis on the method of generating the vapors and on practical aspects of vapor dilution and handling. In addition, a gas chromatographic system with two ovens that is configurable with up to four heating ropes is proposed that could serve as a single integrated platform for explosives vapor generation and device testing. Issues related to standards, calibration, and safety are also discussed.

  3. Vacuum vapor deposition gun assembly

    DOE Patents [OSTI]

    Zeren, Joseph D. (Boulder, CO)

    1985-01-01

    A vapor deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, a hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

  4. Testing cloud microphysics parameterizations in NCAR CAM5 with ISDAC and M-PACE observations

    SciTech Connect (OSTI)

    Liu X.; Lin W.; Xie, S.; Boyle, J.; Klein, S. A.; Shi, X.; Wang, Z.; Ghan, S. J.; Earle, M.; Liu, P. S. K.; Zelenyuk, A.

    2011-12-24

    Arctic clouds simulated by the National Center for Atmospheric Research (NCAR) Community Atmospheric Model version 5 (CAM5) are evaluated with observations from the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Indirect and Semi-Direct Aerosol Campaign (ISDAC) and Mixed-Phase Arctic Cloud Experiment (M-PACE), which were conducted at its North Slope of Alaska site in April 2008 and October 2004, respectively. Model forecasts for the Arctic spring and fall seasons performed under the Cloud-Associated Parameterizations Testbed framework generally reproduce the spatial distributions of cloud fraction for single-layer boundary-layer mixed-phase stratocumulus and multilayer or deep frontal clouds. However, for low-level stratocumulus, the model significantly underestimates the observed cloud liquid water content in both seasons. As a result, CAM5 significantly underestimates the surface downward longwave radiative fluxes by 20-40 W m{sup -2}. Introducing a new ice nucleation parameterization slightly improves the model performance for low-level mixed-phase clouds by increasing cloud liquid water content through the reduction of the conversion rate from cloud liquid to ice by the Wegener-Bergeron-Findeisen process. The CAM5 single-column model testing shows that changing the instantaneous freezing temperature of rain to form snow from -5 C to -40 C causes a large increase in modeled cloud liquid water content through the slowing down of cloud liquid and rain-related processes (e.g., autoconversion of cloud liquid to rain). The underestimation of aerosol concentrations in CAM5 in the Arctic also plays an important role in the low bias of cloud liquid water in the single-layer mixed-phase clouds. In addition, numerical issues related to the coupling of model physics and time stepping in CAM5 are responsible for the model biases and will be explored in future studies.

  5. Opaque cloud detection

    DOE Patents [OSTI]

    Roskovensky, John K. (Albuquerque, NM)

    2009-01-20

    A method of detecting clouds in a digital image comprising, for an area of the digital image, determining a reflectance value in at least three discrete electromagnetic spectrum bands, computing a first ratio of one reflectance value minus another reflectance value and the same two values added together, computing a second ratio of one reflectance value and another reflectance value, choosing one of the reflectance values, and concluding that an opaque cloud exists in the area if the results of each of the two computing steps and the choosing step fall within three corresponding predetermined ranges.

  6. Bringing Clouds into Focus

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bringing Clouds into Focus Bringing Clouds into Focus A New Global Climate Model May Reduce the Uncertainty of Climate Forecasting May 11, 2010 Contact: John Hules, JAHules@lbl.gov , +1 510 486 6008 Randall-fig4.png The large data sets generated by the GCRM require new analysis and visualization capabilities. This 3D plot of vorticity isosurfaces was developed using VisIt, a 3D visualization tool with a parallel distributed architecture, which is being extended to support the geodesic grid used

  7. ARM - Cloud Twist

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Twist Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Cloud Twist Want to make your own version of Cloud Twist? Here are the files you will need. Floor Mat A low resolution image (7.3 MB) and high resolution image (53.2 MB) are available. Spinner Board A low resolution image (992.6 KB) and

  8. Cloud Based Applications and Platforms (Presentation)

    SciTech Connect (OSTI)

    Brodt-Giles, D.

    2014-05-15

    Presentation to the Cloud Computing East 2014 Conference, where we are highlighting our cloud computing strategy, describing the platforms on the cloud (including Smartgrid.gov), and defining our process for implementing cloud based applications.

  9. Atomic vapor laser isotope separation process

    DOE Patents [OSTI]

    Wyeth, R.W.; Paisner, J.A.; Story, T.

    1990-08-21

    A laser spectroscopy system is utilized in an atomic vapor laser isotope separation process. The system determines spectral components of an atomic vapor utilizing a laser heterodyne technique. 23 figs.

  10. High-expansion foam for LNG vapor mitigation. Topical report, September 1987-December 1989

    SciTech Connect (OSTI)

    Atallah, S.; Shah, J.N.; Peterlinz, M.E.

    1990-05-01

    One of the purposes of these high expansion foam systems is to reduce the extent of the hazardous vapor cloud generated during an accidental LNG release. Should the LNG ignite, these systems serve the additional function of controlling the LNG fire and minimizing its radiation to the surroundings. Foam generators have been installed along the tops of dike walls surrounding some LNG storage tanks, and around other fenced containment areas where LNG may be accidentally released, such as LNG pump pits and pipe rack trenches. To date there are no technically justifiable guidelines for the design and installation of these systems. Furthermore, there are no models that may be used describe the vapor source so as to be able to predict the reduction in the hazardous vapor cloud zone when high expansion foam is applied to an LNG spill. Information is essential not only for the optimal design of high expansion foam systems, but also for comparing the cost effectiveness of alternative LNG vapor mitigation measures.

  11. Macquarie Island Cloud and Radiation Experiment (MICRE) Science Plan

    SciTech Connect (OSTI)

    Marchand, RT; Protat, A; Alexander, SP

    2015-12-01

    Clouds over the Southern Ocean are poorly represented in present day reanalysis products and global climate model simulations. Errors in top-of-atmosphere (TOA) broadband radiative fluxes in this region are among the largest globally, with large implications for modeling both regional and global scale climate responses (e.g., Trenberth and Fasullo 2010, Ceppi et al. 2012). Recent analyses of model simulations suggest that model radiative errors in the Southern Ocean are due to a lack of low-level postfrontal clouds (including clouds well behind the front) and perhaps a lack of supercooled liquid water that contribute most to the model biases (Bodas-Salcedo et al. 2013, Huang et al. 2014). These assessments of model performance, as well as our knowledge of cloud and aerosol properties over the Southern Ocean, rely heavily on satellite data sets. Satellite data sets are incomplete in that the observations are not continuous (i.e., they are acquired only when the satellite passes nearby), generally do not sample the diurnal cycle, and view primarily the tops of cloud systems (especially for the passive instruments). This is especially problematic for retrievals of aerosol, low-cloud properties, and layers of supercooled water embedded within (rather than at the top of) clouds, as well as estimates of surface shortwave and longwave fluxes based on these properties.

  12. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  13. Vapor Retarder Classification - Building America Top Innovation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Vapor Retarder Classification - Building America Top Innovation Vapor Retarder Classification - Building America Top Innovation Photo of a vapor retarder classification. Air-tight and well-insulated homes have little or no tolerance for drying if they get wet; moisture control is critical. This Top Innovation profile describes Building America research that established vapor retarder classifications and appropriate applications that has been instrumental in the market

  14. ARM - Measurement - Images of Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsImages of Clouds ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Images of Clouds Digital images of cloud scenes (various formats) from satellite, aircraft, and ground-based platforms. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a

  15. ARM - Measurement - Precipitable water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsPrecipitable water ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Precipitable water Total amount of water vapor in a vertical column of air, often expressed as the depth of the layer of water that would be formed if all the water vapor were condensed to liquid water. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following

  16. Wind speed response of marine non-precipitating stratocumulus clouds over a diurnal cycle in cloud-system resolving simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kazil, J.; Feingold, G.; Yamaguchi, T.

    2015-10-21

    Observed and projected trends in large scale wind speed over the oceans prompt the question: how might marine stratocumulus clouds and their radiative properties respond to future changes in large scale wind speed? Wind speed drives the surface fluxes of sensible heat, moisture, and momentum, and thereby acts on cloud liquid water path (LWP) and cloud radiative properties. We present an investigation of the dynamical response of non-precipitating, overcast marine stratocumulus clouds to different wind speeds, all else equal. In cloud-system resolving simulations, we find that higher wind speed leads to faster boundary layer growth and stronger entrainment. The dynamicalmoredriver is enhanced buoyant production of turbulence kinetic energy (TKE) from latent heat release in cloud updrafts. LWP is enhanced during the night and in the morning at higher wind speed, and more strongly suppressed later in the day. Wind speed hence accentuates the diurnal LWP cycle by expanding the morning afternoon contrast. The higher LWP at higher wind speed does not, however, enhance cloud top cooling because in clouds with LWP ⪆ 50 g m?2, long wave emissions are very insensitive to LWP. This leads to the more general conclusion that in sufficiently thick stratocumulus clouds, additional boundary layer growth and entrainment due to a boundary layer moistening arises by stronger production of TKE from latent heat release in cloud updrafts, rather than from enhanced longwave cooling. We find furthermore that large scale wind modulates boundary layer decoupling. At nighttime and at low wind speed during daytime, it enhances decoupling in part by faster boundary layer growth and stronger entrainment, and in part because circulation driven by shear from large scale wind in the sub-cloud layer hinders vertical moisture transport between the surface and cloud base. With increasing wind speed, however, in decoupled daytime conditions, shear-driven circulation due to large scale wind takes over from buoyancy-driven circulation in transporting moisture from the surface to cloud base, and thereby reduces decoupling and helps maintain LWP. The cloud radiative effect (CRE) responds to changes in LWP and cloud fraction, and higher wind speed translates to a stronger diurnally averaged CRE. However, the sensitivity of the diurnally averaged CRE to wind speed decreases with increasing wind speed.less

  17. ARM - Cloud Word Seek

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Word Seek Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Cloud Word Seek

  18. Underwater vapor phase burning of aluminum particles and on aluminum ignition during steam explosions

    SciTech Connect (OSTI)

    Epstein, M. )

    1991-09-01

    Recently reported experimental studies on aluminum-water steam explosions indicate that there may be a critical metal temperature at which the process changes over from a physical explosion to one which is very violent and involves the rapid liberation of chemical energy. In this report we examine the hypothesis that vapor-phase burning of aluminum is a necessary condition for the occurrence of such ignition-type'' steam explosions. An available two-phase stagnation flow film-boiling model is used to calculate the steam flux to the vaporizing aluminum surface. Combining this calculation with the notion that there is an upper limit to the magnitude of the metal vaporization rate at which the reaction regime must change from vapor phase to surface burning, leads to prediction of the critical metal surface temperature below which vapor phase burning is impossible. The critical temperature is predicted for both the aluminum-water pre-mixture configuration in which coarse drops of aluminum are falling freely through water and for the finely-fragmented aluminum drops in the wake of the pressure shock that triggers'' the explosion. Vapor phase burning is predicted to be possible during the pre-mixture phase but not very likely during the trigger phase of a steam explosion. The implications of these findings in terms of the validity of the hypothesis that ignition may begin with the vapor phase burning of aluminum is discussed. Recently postulated, alternative mechanisms of underwater aluminum ignition are also discussed.

  19. Underwater vapor phase burning of aluminum particles and on aluminum ignition during steam explosions

    SciTech Connect (OSTI)

    Epstein, M.

    1991-09-01

    Recently reported experimental studies on aluminum-water steam explosions indicate that there may be a critical metal temperature at which the process changes over from a physical explosion to one which is very violent and involves the rapid liberation of chemical energy. In this report we examine the hypothesis that vapor-phase burning of aluminum is a necessary condition for the occurrence of such ``ignition-type`` steam explosions. An available two-phase stagnation flow film-boiling model is used to calculate the steam flux to the vaporizing aluminum surface. Combining this calculation with the notion that there is an upper limit to the magnitude of the metal vaporization rate at which the reaction regime must change from vapor phase to surface burning, leads to prediction of the critical metal surface temperature below which vapor phase burning is impossible. The critical temperature is predicted for both the aluminum-water pre-mixture configuration in which coarse drops of aluminum are falling freely through water and for the finely-fragmented aluminum drops in the wake of the pressure shock that ``triggers`` the explosion. Vapor phase burning is predicted to be possible during the pre-mixture phase but not very likely during the trigger phase of a steam explosion. The implications of these findings in terms of the validity of the hypothesis that ignition may begin with the vapor phase burning of aluminum is discussed. Recently postulated, alternative mechanisms of underwater aluminum ignition are also discussed.

  20. Testing Cloud Microphysics Parameterizations in NCAR CAM5 with ISDAC and M-PACE Observations

    SciTech Connect (OSTI)

    Liu, Xiaohong; Xie, Shaocheng; Boyle, James; Klein, Stephen A.; Shi, Xiangjun; Wang, Zhien; Lin, Wuyin; Ghan, Steven J.; Earle, Michael; Liu, Peter; Zelenyuk, Alla

    2011-12-24

    Arctic clouds simulated by the NCAR Community Atmospheric Model version 5 (CAM5) are evaluated with observations from the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Indirect and Semi-Direct Aerosol Campaign (ISDAC) and Mixed-Phase Arctic Cloud Experiment (M-PACE), which were conducted at its North Slope of Alaska site in April 2008 and October 2004, respectively. Model forecasts for the Arctic Spring and Fall seasons performed under the Cloud- Associated Parameterizations Testbed (CAPT) framework generally reproduce the spatial distributions of cloud fraction for single-layer boundary layer mixed-phase stratocumulus, and multilayer or deep frontal clouds. However, for low-level clouds, the model significantly underestimates the observed cloud liquid water content in both seasons and cloud fraction in the Spring season. As a result, CAM5 significantly underestimates the surface downward longwave (LW) radiative fluxes by 20-40 W m-2. The model with a new ice nucleation parameterization moderately improves the model simulations by increasing cloud liquid water content in mixed-phase clouds through the reduction of the conversion rate from cloud liquid to ice by the Wegener-Bergeron- Findeisen (WBF) process. The CAM5 single column model testing shows that change in the homogeneous freezing temperature of rain to form snow from -5 C to -40 C has a substantial impact on the modeled liquid water content through the slowing-down of liquid and rain-related processes. In contrast, collections of cloud ice by snow and cloud liquid by rain are of minor importance for single-layer boundary layer mixed-phase clouds in the Arctic.

  1. Two Electron Holes in Hematite Facilitate Water Splitting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Two Electron Holes in Hematite Facilitate Water Splitting Print Hydrogen is an attractive form of fuel because its only by-product is nonpolluting water vapor. The problem,...

  2. An Evaluation of MWR Retrievals of Liquid Water Path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    retrievals of precipitable water vapor (PWV) and liquid water path (LWP). The paper shows case study comparisons between the standard "statistical" approach and those obtained...

  3. First observations of tracking clouds using scanning ARM cloud radars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Borque, Paloma; Giangrande, Scott; Kollias, Pavlos

    2014-12-01

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (‘‘first echo’’). These measurements complement cloud and precipitation tracking using geostationary satellites and weather radars. Here, two-dimensional (2-D) Along-Wind Range Height Indicator (AW-RHI) observations of a population of shallow cumuli (with and without precipitation) from the 35-GHz scanning ARM cloud radar (SACR) at the DOE Atmospheric Radiation Measurements (ARM) program Southern Great Plains (SGP) site are presented. Observations from the ARM SGP network of scanning precipitation radars are used to provide the larger scale context of the cloud fieldmore » and to highlight the advantages of the SACR to detect the numerous, small, non-precipitating cloud elements. A new Cloud Identification and Tracking Algorithm (CITA) is developed to track cloud elements. In CITA, a cloud element is identified as a region having a contiguous set of pixels exceeding a preset reflectivity and size threshold. The high temporal resolution of the SACR 2-D observations (30 sec) allows for an area superposition criteria algorithm to match cloud elements at consecutive times. Following CITA, the temporal evolution of cloud element properties (number, size, and maximum reflectivity) is presented. The vast majority of the designated elements during this cumulus event were short-lived non-precipitating clouds having an apparent life cycle shorter than 15 minutes. The advantages and disadvantages of cloud tracking using an SACR are discussed.« less

  4. Means and method for vapor generation

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1984-01-01

    A liquid, in heat transfer contact with a surface heated to a temperature well above the vaporization temperature of the liquid, will undergo a multiphase (liquid-vapor) transformation from 0% vapor to 100% vapor. During this transition, the temperature driving force or heat flux and the coefficients of heat transfer across the fluid-solid interface, and the vapor percentage influence the type of heating of the fluid--starting as "feedwater" heating where no vapors are present, progressing to "nucleate" heating where vaporization begins and some vapors are present, and concluding with "film" heating where only vapors are present. Unstable heating between nucleate and film heating can occur, accompanied by possibly large and rapid temperature shifts in the structures. This invention provides for injecting into the region of potential unstable heating and proximate the heated surface superheated vapors in sufficient quantities operable to rapidly increase the vapor percentage of the multiphase mixture by perhaps 10-30% and thereby effectively shift the multiphase mixture beyond the unstable heating region and up to the stable film heating region.

  5. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, Loren D. (Morrison, CO); Cerni, Todd A. (Littleton, CO)

    1989-01-01

    Apparatus and method determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavlength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to: ##EQU1## where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4)+K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation.

  6. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, L.D.; Cerni, T.A.

    1989-10-17

    Apparatus and method are disclosed which determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavelength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to an equation given in the patent where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4) + K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation. 11 figs.

  7. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Test of In-Cloud Water Vapor Parameterizations Using SHEBA/FIRE-ACE Observations Fu, Q. and Hollars, S., University of Washington Thirteenth Atmospheric Radiation Measurement (ARM) Science Team Meeting Cloud schemes in numerical models require specification of saturated water vapor pressure. The in-cloud water vapor is often assumed to be saturated with respect to liquid water and ice, respectively, for pure water and ice clouds. There is an ambiguity, however, in defining the water vapor

  8. Process for recovering organic vapors from air

    DOE Patents [OSTI]

    Baker, Richard W. (Mountain View, CA)

    1985-01-01

    A process for recovering and concentrating organic vapor from a feed stream of air having an organic vapor content of no more than 20,000 ppm by volume. A thin semipermeable membrane is provided which has a feed side and a permeate side, a selectivity for organic vapor over air of at least 50, as measured by the ratio of organic vapor permeability to nitrogen permeability, and a permeability of organic vapor of at least 3.times.10.sup.-7 cm.sup.3 (STP) cm/cm.sup.2 sec.cm Hg. The feed stream is passed across the feed side of the thin semipermeable membrane while providing a pressure on the permeate side which is lower than the feed side by creating a partial vacuum on the permeate side so that organic vapor passes preferentially through the membrane to form an organic vapor depleted air stream on the feed side and an organic vapor enriched stream on the permeate side. The organic vapor which has passed through the membrane is compressed and condensed to recover the vapor as a liquid.

  9. The carbon inventory in a quiescent, filamentary molecular cloud in G328

    SciTech Connect (OSTI)

    Burton, Michael G.; Ashley, Michael C. B.; Braiding, Catherine; Storey, John W. V.; Kulesa, Craig; Hollenbach, David J.; Wolfire, Mark; Glck, Christian; Rowell, Gavin

    2014-02-20

    We present spectral line images of [C I] 809 GHz, CO J = 1-0 115 GHz and H I 1.4 GHz line emission, and calculate the corresponding C, CO and H column densities, for a sinuous, quiescent giant molecular cloud about 5 kpc distant along the l = 328 sightline (hereafter G328) in our Galaxy. The [C I] data comes from the High Elevation Antarctic Terahertz telescope, a new facility on the summit of the Antarctic plateau where the precipitable water vapor falls to the lowest values found on the surface of the Earth. The CO and H I data sets come from the Mopra and Parkes/ATCA telescopes, respectively. We identify a filamentary molecular cloud, ?75 5 pc long with mass ?4 10{sup 4} M {sub ?} and a narrow velocity emission range of just 4 km s{sup 1}. The morphology and kinematics of this filament are similar in CO, [C I], and H I, though in the latter appears as self-absorption. We calculate line fluxes and column densities for the three emitting species, which are broadly consistent with a photodissociation region model for a GMC exposed to the average interstellar radiation field. The [C/CO] abundance ratio averaged through the filament is found to be approximately unity. The G328 filament is constrained to be cold (T {sub Dust} < 20 K) by the lack of far-IR emission, to show no clear signs of star formation, and to only be mildly turbulent from the narrow line width. We suggest that it may represent a GMC shortly after formation, or perhaps still in the process of formation.

  10. A High Resolution Hydrometer Phase Classifier Based on Analysis of Cloud Radar Doppler Spectra.

    SciTech Connect (OSTI)

    Luke,E.; Kollias, P.

    2007-08-06

    The lifecycle and radiative properties of clouds are highly sensitive to the phase of their hydrometeors (i.e., liquid or ice). Knowledge of cloud phase is essential for specifying the optical properties of clouds, or else, large errors can be introduced in the calculation of the cloud radiative fluxes. Current parameterizations of cloud water partition in liquid and ice based on temperature are characterized by large uncertainty (Curry et al., 1996; Hobbs and Rangno, 1998; Intriery et al., 2002). This is particularly important in high geographical latitudes and temperature ranges where both liquid droplets and ice crystal phases can exist (mixed-phase cloud). The mixture of phases has a large effect on cloud radiative properties, and the parameterization of mixed-phase clouds has a large impact on climate simulations (e.g., Gregory and Morris, 1996). Furthermore, the presence of both ice and liquid affects the macroscopic properties of clouds, including their propensity to precipitate. Despite their importance, mixed-phase clouds are severely understudied compared to the arguably simpler single-phase clouds. In-situ measurements in mixed-phase clouds are hindered due to aircraft icing, difficulties distinguishing hydrometeor phase, and discrepancies in methods for deriving physical quantities (Wendisch et al. 1996, Lawson et al. 2001). Satellite-based retrievals of cloud phase in high latitudes are often hindered by the highly reflecting ice-covered ground and persistent temperature inversions. From the ground, the retrieval of mixed-phase cloud properties has been the subject of extensive research over the past 20 years using polarization lidars (e.g., Sassen et al. 1990), dual radar wavelengths (e.g., Gosset and Sauvageot 1992; Sekelsky and McIntosh, 1996), and recently radar Doppler spectra (Shupe et al. 2004). Millimeter-wavelength radars have substantially improved our ability to observe non-precipitating clouds (Kollias et al., 2007) due to their excellent sensitivity that enables the detection of thin cloud layers and their ability to penetrate several non-precipitating cloud layers. However, in mixed-phase clouds conditions, the observed Doppler moments are dominated by the highly reflecting ice crystals and thus can not be used to identify the cloud phase. This limits our ability to identify the spatial distribution of cloud phase and our ability to identify the conditions under which mixed-phase clouds form.

  11. METHANE GAS STABILIZES SUPERCOOLED ETHANE DROPLETS IN TITAN'S CLOUDS

    SciTech Connect (OSTI)

    Wang, Chia C.; Lang, E. Kathrin; Signorell, Ruth

    2010-03-20

    Strong evidence for ethane clouds in various regions of Titan's atmosphere has recently been found. Ethane is usually assumed to exist as ice particles in these clouds, although the possible role of liquid and supercooled liquid ethane droplets has been recognized. Here, we report on infrared spectroscopic measurements of ethane aerosols performed in the laboratory under conditions mimicking Titan's lower atmosphere. The results clearly show that liquid ethane droplets are significantly stabilized by methane gas which is ubiquitous in Titan's nitrogen atmosphere-a phenomenon that does not have a counterpart for water droplets in Earth's atmosphere. Our data imply that supercooled ethane droplets are much more abundant in Titan's clouds than previously anticipated. Possibly, these liquid droplets are even more important for cloud processes and the formation of lakes than ethane ice particles.

  12. Cloud/Aerosol Parameterizations: Application and Improvement of General Circulation Models

    SciTech Connect (OSTI)

    Penner, Joyce

    2012-06-30

    One of the biggest uncertainties associated with climate models and climate forcing is the treatment of aerosols and their effects on clouds. The effect of aerosols on clouds can be divided into two components: The first indirect effect is the forcing associated with increases in droplet concentrations; the second indirect effect is the forcing associated with changes in liquid water path, cloud morphology, and cloud lifetime. Both are highly uncertain. This project applied a cloud-resolving model to understand the response of clouds under a variety of conditions to changes in aerosols. These responses are categorized according to the large-scale meteorological conditions that lead to the response. Meteorological conditions were sampled from various fields, which, together with a global aerosol model determination of the change in aerosols from present day to pre-industrial conditions, was used to determine a first order estimate of the response of global cloud fields to changes in aerosols. The response of the clouds in the NCAR CAM3 GCM coupled to our global aerosol model were tested by examining whether the response is similar to that of the cloud resolving model and methods for improving the representation of clouds and cloud/aerosol interactions were examined.

  13. TURBULENCE DECAY AND CLOUD CORE RELAXATION IN MOLECULAR CLOUDS

    SciTech Connect (OSTI)

    Gao, Yang; Law, Chung K.; Xu, Haitao

    2015-02-01

    The turbulent motion within molecular clouds is a key factor controlling star formation. Turbulence supports molecular cloud cores from evolving to gravitational collapse and hence sets a lower bound on the size of molecular cloud cores in which star formation can occur. On the other hand, without a continuous external energy source maintaining the turbulence, such as in molecular clouds, the turbulence decays with an energy dissipation time comparable to the dynamic timescale of clouds, which could change the size limits obtained from Jean's criterion by assuming constant turbulence intensities. Here we adopt scaling relations of physical variables in decaying turbulence to analyze its specific effects on the formation of stars. We find that the decay of turbulence provides an additional approach for Jeans' criterion to be achieved, after which gravitational infall governs the motion of the cloud core. This epoch of turbulence decay is defined as cloud core relaxation. The existence of cloud core relaxation provides a more complete understanding of the effect of the competition between turbulence and gravity on the dynamics of molecular cloud cores and star formation.

  14. Chemical vapor deposition of sialon

    DOE Patents [OSTI]

    Landingham, Richard L. (Livermore, CA); Casey, Alton W. (Livermore, CA)

    1982-01-01

    A laminated composite and a method for forming the composite by chemical vapor deposition. The composite includes a layer of sialon and a material to which the layer is bonded. The method includes the steps of exposing a surface of the material to an ammonia containing atmosphere; heating the surface to at least about 1200.degree. C.; and impinging a gas containing in a flowing atmosphere of air N.sub.2, SiCl.sub.4, and AlCl.sub.3 on the surface.

  15. Control of flow through a vapor generator

    DOE Patents [OSTI]

    Radcliff, Thomas D.

    2005-11-08

    In a Rankine cycle system wherein a vapor generator receives heat from exhaust gases, provision is made to avoid overheating of the refrigerant during ORC system shut down while at the same time preventing condensation of those gases within the vapor generator when its temperature drops below a threshold temperature by diverting the flow of hot gases to ambient and to thereby draw ambient air through the vapor generator in the process. In one embodiment, a bistable ejector is adjustable between one position, in which the hot gases flow through the vapor generator, to another position wherein the gases are diverted away from the vapor generator. Another embodiment provides for a fixed valve ejector with a bias towards discharging to ambient, but with a fan on the downstream side of said vapor generator for overcoming this bias.

  16. Clouds' Role in Sunlight Stopping

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clouds' Role in Sunlight Stopping For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Clouds are energy traffic cops, controlling how much sunlight reaches Earth. Pacific Northwest National Laboratory (PNNL) researchers used long-term observations to show that the sunlight stopping power of each type of typical tropical cloud, and how frequently they occur, must be accurately simulated in climate models. Otherwise,

  17. ARM - Measurement - Cloud ice particle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ice particle ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud ice particle Particles made of ice found in clouds. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or

  18. ARM - Measurement - Cloud optical depth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    optical depth ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud optical depth Amount of light cloud droplets or ice particles prevent from passing through a column of atmosphere. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  19. Novel methods of copper vapor laser excitation

    SciTech Connect (OSTI)

    McColl, W.B.; Ching, H.; Bosch, R.; Brake, M.; Gilgenbach, R.

    1990-12-31

    Microwave and intense electron beam excitation of copper vapor are being investigated to be used in copper vapor lasers for isotope separation. Both methods use copper chloride vapor by heating copper chloride. Helium was used as the buffer gas at 2 to 100 torr. In the microwave system, intense copperlines at 510 nm and 578 nm were observed. Initial electron beam results indicate that light emission follows the beam current.

  20. Coupling apparatus for a metal vapor laser

    DOE Patents [OSTI]

    Ball, D.G.; Miller, J.L.

    1993-02-23

    Coupling apparatus for a large bore metal vapor laser is disclosed. The coupling apparatus provides for coupling high voltage pulses (approximately 40 KV) to a metal vapor laser with a high repetition rate (approximately 5 KHz). The coupling apparatus utilizes existing thyratron circuits and provides suitable power input to a large bore metal vapor laser while maintaining satisfactory operating lifetimes for the existing thyratron circuits.

  1. Coupling apparatus for a metal vapor laser

    DOE Patents [OSTI]

    Ball, Don G. (Livermore, CA); Miller, John L. (Dublin, CA)

    1993-01-01

    Coupling apparatus for a large bore metal vapor laser is disclosed. The coupling apparatus provides for coupling high voltage pulses (approximately 40 KV) to a metal vapor laser with a high repetition rate (approximately 5 KHz). The coupling apparatus utilizes existing thyratron circuits and provides suitable power input to a large bore metal vapor laser while maintaining satisfactory operating lifetimes for the existing thyratron circuits.

  2. MEMS Lubrication by In-Situ Tribochemical Reactions From the Vapor Phase.

    SciTech Connect (OSTI)

    Dugger, Michael T.; Asay, David B.; Kim, Seong H.

    2008-01-01

    Vapor Phase Lubrication (VPL) of silicon surfaces with pentanol has been demonstrated. Two potential show stoppers with respect to application of this approach to real MEMS devices have been investigated. Water vapor was found to reduce the effectiveness of VPL with alcohol for a given alcohol concentration, but the basic reaction mechanism observed in water-free environments is still active, and devices operated much longer in mixed alcohol and water vapor environments than with chemisorbed monolayer lubricants alone. Complex MEMS gear trains were successfully lubricated with alcohol vapors, resulting in a factor of 104 improvement in operating life without failure. Complex devices could be made to fail if operated at much higher frequencies than previously used, and there is some evidence that the observed failure is due to accumulation of reaction products at deeply buried interfaces. However, if hypothetical reaction mechanisms involving heated surfaces are valid, then the failures observed at high frequency may not be relevant to operation at normal frequencies. Therefore, this work demonstrates that VPL is a viable approach for complex MEMS devices in conventional packages. Further study of the VPL reaction mechanisms are recommended so that the vapor composition may be optimized for low friction and for different substrate materials with potential application to conventionally fabricated, metal alloy parts in weapons systems. Reaction kinetics should be studied to define effective lubrication regimes as a function of the partial pressure of the vapor phase constituent, interfacial shear rate, substrate composition, and temperature.

  3. TWP Island Cloud Trail Studies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a key to understanding boundary layer cloud formation in the tropics. Except during El Nio periods, Nauru represents a divergent region of the ocean upwind from the...

  4. ARM - Measurement - Cloud condensation nuclei

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AOS : Aerosol Observing System CCN : Cloud Condensation Nuclei Particle Counter TDMA : Tandem Differential Mobility Analyzer Field Campaign Instruments AMT : Aerosol Modeling...

  5. Vapor Retarder Classification - Building America Top Innovation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This Top Innovation profile describes Building America research that established vapor ... Find other case studies of Building America projects across the country that utilizes ...

  6. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  7. FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS

    Office of Scientific and Technical Information (OSTI)

    give a higher lower limit value than the completely vaporized sample. Conversely, the heavy fractions or residue give a smaller lower limit value. For this reason, there is...

  8. Study of Mechanisms of Aerosol Indirect Effects on Glaciated Clouds: Progress during the Project Final Technical Report

    SciTech Connect (OSTI)

    2013-10-18

    This 3-year project has studied how aerosol pollution influences glaciated clouds. The tool applied has been an 'aerosol-cloud model'. It is a type of Cloud-System Resolving Model (CSRM) modified to include 2-moment bulk microphysics and 7 aerosol species, as described by Phillips et al. (2009, 2013). The study has been done by, first, improving the model and then performing sensitivity studies with validated simulations of a couple of observed cases from ARM. These are namely the Tropical Warm Pool International Cloud Experiment (TWP-ICE) over the tropical west Pacific and the Cloud and Land Surface Interaction Campaign (CLASIC) over Oklahoma. During the project, sensitivity tests with the model showed that in continental clouds, extra liquid aerosols (soluble aerosol material) from pollution inhibited warm rain processes for precipitation production. This promoted homogeneous freezing of cloud droplets and aerosols. Mass and number concentrations of cloud-ice particles were boosted. The mean sizes of cloud-ice particles were reduced by the pollution. Hence, the lifetime of glaciated clouds, especially ice-only clouds, was augmented due to inhibition of sedimentation and ice-ice aggregation. Latent heat released from extra homogeneous freezing invigorated convective updrafts, and raised their maximum cloud-tops, when aerosol pollution was included. In the particular cases simulated in the project, the aerosol indirect effect of glaciated clouds was twice than of (warm) water clouds. This was because glaciated clouds are higher in the troposphere than water clouds and have the first interaction with incoming solar radiation. Ice-only clouds caused solar cooling by becoming more extensive as a result of aerosol pollution. This 'lifetime indirect effect' of ice-only clouds was due to higher numbers of homogeneously nucleated ice crystals causing a reduction in their mean size, slowing the ice-crystal process of snow production and slowing sedimentation. In addition to the known indirect effects (glaciation, riming and thermodynamic), new indirect effects were discovered and quantified due to responses of sedimentation, aggregation and coalescence in glaciated clouds to changing aerosol conditions. In summary, the change in horizontal extent of the glaciated clouds ('lifetime indirect effects'), especially of ice-only clouds, was seen to be of higher importance in regulating aerosol indirect effects than changes in cloud properties ('cloud albedo indirect effects').

  9. Efficacy of Aerosol-Cloud Interactions Under Varying Meteorological Conditions: Southern Great Plains Vs. Pt. Reyes

    SciTech Connect (OSTI)

    Dunn, M.; Schwartz, S.; Kim, B.-G.; Miller, M.; Liu, Y.; Min, Q.

    2008-03-10

    Several studies have demonstrated that cloud dynamical processes such as entrainment mixing may be the primary modulator of cloud optical properties in certain situations. For example, entrainment of dry air alters the cloud drop size distribution by enhancing drop evaporation. However, the effect of entrainment mixing and other forms or turbulence is still quite uncertain. Although these factors and aerosol-cloud interactions should be considered together when evaluating the efficacy of aerosol indirect effects, the underlying mechanisms appear to be dependent upon each other. In addition, accounting for them is impossible with the current understanding of aerosol indirect effect. Therefore, careful objective screening and analysis of observations are needed to determine the extent to which mixing related properties affect cloud optical properties, apart from the aerosol first indirect effect. This study addresses the role of aerosol-cloud interactions in the context of varying meteorological conditions based on ARM data obtained at the Southern Great Plains (SGP) site in Oklahoma and at Pt. Reyes, California. Previous analyses of the continental stratiform clouds at the SGP site have shown that the thicker clouds of high liquid water path (LWP) tend to contain sub adiabatic LWPs. These sub adiabatic LWPs, which result from active mixing processes, correspond to a lower susceptibility of the clouds to aerosol-cloud interactions, and, hence, to reduced aerosol indirect effects. In contrast, the consistently steady and thin maritime stratus clouds observed at Pt. Reyes are much closer to adiabatic. These clouds provide an excellent benchmark for the study of the aerosol influence on modified marine clouds relative to continental clouds, since they form in a much more homogeneous meteorological environment than those at the continental site.

  10. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, V.J.; Johnson, S.A.

    1999-08-03

    A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

  11. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, Vincent J. (Downers Grove, IL); Johnson, Stanley A. (Countryside, IL)

    1999-01-01

    A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

  12. Widget:LogoCloud | Open Energy Information

    Open Energy Info (EERE)

    LogoCloud Jump to: navigation, search This widget adds css selectors and javascript for the Template:LogoCloud. For example: Widget:LogoCloud Retrieved from "http:...

  13. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  14. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  15. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  16. Zenith Radiance Retrieval of Cloud Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    retrievals of cloud properties from the AMF/COPS campaign Preliminary retrievals of cloud properties from the AMF/COPS campaign Christine Chiu, UMBC/JCET Alexander Marshak, GSFC Yuri Knyazikhin, Boston University Warren Wiscombe, GSFC Christine Chiu, UMBC/JCET Alexander Marshak, GSFC Yuri Knyazikhin, Boston University Warren Wiscombe, GSFC The cloud optical properties of interest are: The cloud optical properties of interest are: * Cloud optical depth τ - the great unknown * Radiative cloud

  17. Stacked vapor fed amtec modules

    DOE Patents [OSTI]

    Sievers, Robert K. (North Huntingdon, PA)

    1989-01-01

    The present invention pertains to a stacked AMTEC module. The invention includes a tubular member which has an interior. The member is comprised of a ion conductor that substantially conducts ions relative to electrons, preferably a beta"-alumina solid electrolyte, positioned about the interior. A porous electrode for conducting electrons and allowing sodium ions to pass therethrough, and wherein electrons and sodium ions recombine to form sodium is positioned about the beta"-alumina solid electrolyte. The electrode is operated at a temperature and a pressure that allows the recombined sodium to vaporize. Additionally, an outer current collector grid for distributing electrons throughout the porous electrode is positioned about and contacts the porous electrode. Also included in the invention is transporting means for transporting liquid sodium to the beta"-alumina solid electrolyte of the tubular member. A transition piece is positioned about the interior of the member and contacts the transporting means. The transition piece divides the member into a first cell and a second cell such that each first and second cell has a beta"-alumina solid electrolyte, a first and second porous electrode and a grid. The transition piece conducts electrons from the interior of the tubular member. There is supply means for supplying sodium to the transporting means. Preferably the supply means is a shell which surrounds the tubular member and is operated at a temperature such that the vaporized sodium condenses thereon. Returning means for returning the condensed sodium from the shell to the transporting means provides a continuous supply of liquid sodium to the transporting means. Also, there are first conducting means for conducting electric current from the transition piece which extends through the shell, and second conducting means for conducting electric current to the grid of the first cell which extends through the shell.

  18. Quantitative organic vapor-particle sampler

    DOE Patents [OSTI]

    Gundel, Lara; Daisey, Joan M.; Stevens, Robert K.

    1998-01-01

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  19. High bandwidth vapor density diagnostic system

    DOE Patents [OSTI]

    Globig, Michael A. (Antioch, CA); Story, Thomas W. (Oakley, CA)

    1992-01-01

    A high bandwidth vapor density diagnostic system for measuring the density of an atomic vapor during one or more photoionization events. The system translates the measurements from a low frequency region to a high frequency, relatively noise-free region in the spectrum to provide improved signal to noise ratio.

  20. Dynamics of Molecular Clouds: Observations, Simulations, and...

    Office of Scientific and Technical Information (OSTI)

    Conference: Dynamics of Molecular Clouds: Observations, Simulations, and NIF Experiments Citation Details In-Document Search Title: Dynamics of Molecular Clouds: Observations,...

  1. Clouds Environmental Ltd | Open Energy Information

    Open Energy Info (EERE)

    Clouds Environmental Ltd Jump to: navigation, search Name: Clouds Environmental Ltd Place: Portsmouth, United Kingdom Zip: PO3 5EG Product: Independent consultancy specialising in...

  2. Cloud Properties Working Group Break Out Session

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    relation to fall speeds, implications for previous measurements. (Mitchell) Q8: Geoengineering of cirrus clouds (Mitchell) Q9: Cold cloud phase partitioning: Roles of...

  3. A simple grand canonical approach to compute the vapor pressure of bulk and finite size systems

    SciTech Connect (OSTI)

    Factorovich, Matas H.; Scherlis, Damin A.

    2014-02-14

    In this article we introduce a simple grand canonical screening (GCS) approach to accurately compute vapor pressures from molecular dynamics or Monte Carlo simulations. This procedure entails a screening of chemical potentials using a conventional grand canonical scheme, and therefore it is straightforward to implement for any kind of interface. The scheme is validated against data obtained from Gibbs ensemble simulations for water and argon. Then, it is applied to obtain the vapor pressure of the coarse-grained mW water model, and it is shown that the computed value is in excellent accord with the one formally deduced using statistical thermodynamics arguments. Finally, this methodology is used to calculate the vapor pressure of a water nanodroplet of 94 molecules. Interestingly, the result is in perfect agreement with the one predicted by the Kelvin equation for a homogeneous droplet of that size.

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observational Evidence of Changes in Water Vapor, Clouds, and Radiation Submitter: Dong, X., University of North Dakota Area of Research: Cloud DistributionsCharacterizations...

  5. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  6. Polluting of Winter Convective Clouds upon Transition from Ocean Inland Over Central California: Contrasting Case Studies

    SciTech Connect (OSTI)

    Rosenfeld, Daniel; Chemke, Rei; Prather, Kimberly; Suski, Kaitlyn; Comstock, Jennifer M.; Schmid, Beat; Tomlinson, Jason M.; Jonsson, Haf

    2014-01-01

    In-situ aircraft measurements of aerosol chemical and cloud microphysical properties were conducted during the CalWater campaign in February and March 2011 over the Sierra Nevada Mountains and the coastal waters of central California. The main objective was to elucidate the impacts of aerosol properties on clouds and precipitation forming processes. In order to accomplish this, we compared contrasting cases of clouds that ingested aerosols from different sources. The results showed that clouds containing pristine oceanic air had low cloud drop concentrations and started to develop rain 500 m above their base. This occurred both over the ocean and over the Sierra Nevada, mainly in the early morning when the radiatively cooled stable continental boundary layer was decoupled from the cloud base. Supercooled rain dominated the precipitation that formed in growing convective clouds in the pristine air, up to the -21C isotherm level. A contrasting situation was documented in the afternoon over the foothills of the Sierra Nevada, when the clouds ingested high pollution aerosol concentrations produced in the Central Valley. This led to slow growth of the cloud drop effective radius with height and suppressed and even prevented the initiation of warm rain while contributing to the development of ice hydrometeors in the form of graupel. Our results show that cloud condensation and ice nuclei were the limiting factors that controlled warm rain and ice processes, respectively, while the unpolluted clouds in the same air mass produced precipitation quite efficiently. These findings provide the motivation for deeper investigations into the nature of the aerosols seeding clouds.

  7. Influence of Arctic cloud thermodynamic phase on surface shortwave flux

    SciTech Connect (OSTI)

    Lubin, D.; Vogelmann, A.

    2010-03-15

    As part of the Indirect and Semi-Direct Aerosol Campaign (ISDAC) an Analytical Spectral Devices (ASD, Inc.) spectroradiometer was deployed at the Barrow NSA site during April and May of 2008, and in April-October of 2009. This instrument recorded one-minute averages of surface downwelling spectral flux in the wavelength interval 350-2200 nm, thus sampling the two major near infrared windows (1.6 and 2.2 microns) in which the flux is influenced by cloud microphysical properties including thermodynamic phase and effective particle size. Aircraft in situ measurements of cloud properties show mostly mixed-phase clouds over Barrow during the campaign, but with wide variability in relative liquid versus ice water content. At fixed total optical depth, this variability in phase composition can yield of order 5-10 Watts per square meter in surface flux variability, with greater cloud attenuation of the surface flux usually occurring under higher ice water content. Thus our data show that changes in cloud phase properties, even within the 'mixed-phase' category, can affect the surface energy balance at the same order of magnitude as greenhouse gas increases. Analysis of this spectral radiometric data provides suggestions for testing new mixed-phase parameterizations in climate models.

  8. PROJECT PROFILE: Stable Perovskite Solar Cells via Chemical Vapor...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stable Perovskite Solar Cells via Chemical Vapor Deposition PROJECT PROFILE: Stable Perovskite Solar Cells via Chemical Vapor Deposition Funding Opportunity: SuNLaMP SunShot ...

  9. Rotary Vapor Compression Cycle Technology: A Pathway to Ultra...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rotary Vapor Compression Cycle Technology: A Pathway to Ultra-Efficient Air Conditioning, Heating and Refrigeration Rotary Vapor Compression Cycle Technology: A Pathway to...

  10. After More Than 20 Years Operating, Hanford's Soil Vapor Extraction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wise, Juan Aguilar, Doug Rybarski, and Christina Agular. The soil vapor extraction trailer is shown near Hanfords Plutonium Finishing Plant. The soil vapor extraction...

  11. Vapor Extraction Well Performance and Recommendations for Future...

    Office of Scientific and Technical Information (OSTI)

    Well Performance and Recommendations for Future Soil Vapor Extraction Activities at the A-014 Outfall Citation Details In-Document Search Title: Vapor Extraction Well ...

  12. A New Model for Liquid Water Absorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model for Liquid Water Absorption For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Liquid water path (LWP) is a critical measurement for a wide range of atmospheric studies, as the amount of liquid in a cloud is critical to understanding many cloud processes. For example, the radiative impact of the cloud (in both the longwave and shortwave portions of the spectrum) depends heavily on the LWP. Thus, the Atmospheric

  13. Evaluation of high‐level clouds in cloud resolving model...

    Office of Scientific and Technical Information (OSTI)

    ... Res., 104, 24,527-24,545. Rasmussen, R. M., I. Geresdi, G. Thompson, K. Manning, and E. Karplus (2002), Freezing drizzle formation in stably stratified layer clouds: The role of ...

  14. ARM - Field Campaign - Cloud IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsCloud IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Cloud IOP 1998.04.27 - 1998.05.17 Lead Scientist : Gerald Mace For data sets, see below. Summary Monday, April 27, 1998 IOP Opening Activities: Heavy rain (nearly 2.5" since 12Z 4/26/98) at the central facility (CF) dominated the first day of the Cloud Physics/Single Column Model IOP and limited the daily activities. A 1430 GMT

  15. Process for vaporizing a liquid hydrocarbon fuel

    DOE Patents [OSTI]

    Szydlowski, Donald F. (East Hartford, CT); Kuzminskas, Vaidotas (Glastonbury, CT); Bittner, Joseph E. (East Hartford, CT)

    1981-01-01

    The object of the invention is to provide a process for vaporizing liquid hydrocarbon fuels efficiently and without the formation of carbon residue on the apparatus used. The process includes simultaneously passing the liquid fuel and an inert hot gas downwardly through a plurality of vertically spaed apart regions of high surface area packing material. The liquid thinly coats the packing surface, and the sensible heat of the hot gas vaporizes this coating of liquid. Unvaporized liquid passing through one region of packing is uniformly redistributed over the top surface of the next region until all fuel has been vaporized using only the sensible heat of the hot gas stream.

  16. Recovering hydrocarbons from hydrocarbon-containing vapors

    DOE Patents [OSTI]

    Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

    1980-09-30

    Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

  17. Atomic vapor laser isotope separation using resonance ionization

    SciTech Connect (OSTI)

    Comaskey, B.; Crane, J.; Erbert, G.; Haynam, C.; Johnson, M.; Morris, J.; Paisner, J.; Solarz, R.; Worden, E.

    1986-09-01

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power-reactor fuel has been under development for over 10 years. In June 1985, the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for enriched uranium. Resonance photoionization is the heart of the AVLIS process. We discuss those fundamental atomic parameters that are necessary for describing isotope-selective resonant multistep photoionization along with the measurement techniques that we use. We illustrate the methodology adopted with examples of other elements that are under study in our program.

  18. cloud | OpenEI Community

    Open Energy Info (EERE)

    - 13:42 How cleantech-as-a-service will drive renewable energy adoption 2015 adoption Big Data clean tech clean-tech cleantech cleantech forum cleantech-as-a-service cloud...

  19. Chemical vapor infiltration using microwave energy

    DOE Patents [OSTI]

    Devlin, David J. (Los Alamos, NM); Currier, Robert P. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Barbero, Robert S. (Santa Cruz, NM)

    1993-01-01

    A method for producing reinforced ceramic composite articles by means of chemical vapor infiltration and deposition in which an inverted temperature gradient is utilized. Microwave energy is the source of heat for the process.

  20. Vapor purification with self-cleaning filter

    DOE Patents [OSTI]

    Josephson, Gary B.; Heath, William O.; Aardahl, Christopher L.

    2003-12-09

    A vapor filtration device including a first electrode, a second electrode, and a filter between the first and second electrodes is disclosed. The filter is formed of dielectric material and the device is operated by applying a first electric potential between the electrodes to polarize the dielectric material such that upon passing a vapor stream through the filter, particles from the vapor stream are deposited onto the filter. After depositing the particles a second higher voltage is applied between the electrodes to form a nonthermal plasma around the filter to vaporize the collected particles thereby cleaning the filter. The filter can be a packed bed or serpentine filter mat, and an optional upstream corona wire can be utilized to charge airborne particles prior to their deposition on the filter.

  1. Perfluorocarbon vapor tagging of blasting cap detonators

    DOE Patents [OSTI]

    Dietz, Russell N. (Shoreham, NY); Senum, Gunnar I. (Patchogue, NY)

    1981-01-01

    A plug for a blasting cap is made of an elastomer in which is dissolved a perfluorocarbon. The perfluorocarbon is released as a vapor into the ambient over a long period of time to serve as a detectable taggant.

  2. Millimeter Wave Cloud Radar (MMCR) Handbook

    SciTech Connect (OSTI)

    KB Widener; K Johnson

    2005-01-30

    The millimeter cloud radar (MMCR) systems probe the extent and composition of clouds at millimeter wavelengths. The MMCR is a zenith-pointing radar that operates at a frequency of 35 GHz. The main purpose of this radar is to determine cloud boundaries (e.g., cloud bottoms and tops). This radar will also report radar reflectivity (dBZ) of the atmosphere up to 20 km. The radar possesses a doppler capability that will allow the measurement of cloud constituent vertical velocities.

  3. Perturbed Physics Ensemble Simulations of Cirrus on the Cloud System-resolving Scale

    SciTech Connect (OSTI)

    Muhlbauer, Andreas; Berry, Elizabeth; Comstock, Jennifer M.; Mace, Gerald G.

    2014-04-16

    In this study, the effect of uncertainties in the parameterization of ice microphysical processes and initial conditions on the variability of cirrus microphysical and radiative properties are investigated in a series of cloud system-resolving perturbed physics ensemble (PPE) and initial condition ensemble (ICE) simulations. Three cirrus cases representative of mid-latitude, subtropical and tropical cirrus are examined. It is found that the variability in cirrus properties induced by perturbing uncertain parameters in ice microphysics parameterizations outweighs the variability induced by perturbing the initial conditions in midlatitude and subtropical cirrus. However, in tropical anvil cirrus the variability in the PPE and ICE simulations is about the same order of magnitude. The cirrus properties showing the largest sensitivity are ice water content (IWC) and cloud thickness whereas the averaged high cloud cover is only marginally affected. Changes in cirrus ice water path and outgoing longwave radiation are controlled primarily by changes in IWC and cloud thickness but not by changes is the averaged high cloud cover. The change in the vertical distribution of cloud fraction and cloud thickness is caused by changes in cirrus cloud base whereas cloud top is not sensitive to either perturbed physics or perturbed initial conditions. In all cirrus cases, the top three parameters controlling the microphysical variability and radiative impact of cirrus clouds are ice fall speeds, ice autoconversion size thresholds and heterogeneous ice nucleation. Changes in the ice deposition coefficient do not affect the ice water path and outgoing longwave radiation. Similarly, changes in the number concentration of aerosols available for homogeneous freezing have virtually no effect on the microphysical and radiative properties of midlatitude and subtropical cirrus but only little impact on tropical anvil cirrus. Overall, the sensitivity of cirrus microphysical and radiative properties to uncertainties in ice microphysics is largest for midlatitude cirrus and smallest for tropical anvil cirrus.

  4. Evaluation of high-level clouds in cloud resolving model simulations...

    Office of Scientific and Technical Information (OSTI)

    Evaluation of high-level clouds in cloud resolving model simulations with ARM and KWAJEX observations: HIGH CLOUD IN CRM Citation Details In-Document Search This content will ...

  5. Effects of Ocean Ecosystem on Marine Aerosol-Cloud Interaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meskhidze, Nicholas; Nenes, Athanasios

    2010-01-01

    Using smore » atellite data for the surface ocean, aerosol optical depth (AOD), and cloud microphysical parameters, we show that statistically significant positive correlations exist between ocean ecosystem productivity, the abundance of submicron aerosols, and cloud microphysical properties over different parts of the remote oceans. The correlation coefficient for remotely sensed surface chlorophyll a concentration ([Chl- a ]) and liquid cloud effective radii over productive areas of the oceans varies between − 0.2 and − 0.6 . Special attention is given to identifying (and addressing) problems from correlation analysis used in the previous studies that can lead to erroneous conclusions. A new approach (using the difference between retrieved AOD and predicted sea salt aerosol optical depth, AOD diff ) is developed to explore causal links between ocean physical and biological systems and the abundance of cloud condensation nuclei (CCN) in the remote marine atmosphere. We have found that over multiple time periods, 550 nm AOD diff (sensitive to accumulation mode aerosol, which is the prime contributor to CCN) correlates well with [Chl- a ] over the productive waters of the Southern Ocean. Since [Chl- a ] can be used as a proxy of ocean biological productivity, our analysis demonstrates the role of ocean ecology in contributing CCN, thus shaping the microphysical properties of low-level marine clouds.« less

  6. Dispersion of Cloud Droplet Size Distributions, Cloud Parameterizations and Indirect Aerosol Effects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dispersion of Cloud Droplet Size Distributions, Cloud Parameterizations, and Indirect Aerosol Effects P. H. Daum and Y. Liu Brookhaven National Laboratory Upton, New York Introduction Most studies of the effect of aerosols on cloud radiative properties have considered only changes in the cloud droplet concentration, neglecting changes in the spectral shape of the cloud droplet size distribution. However, it has been shown that that the spectral dispersion of the cloud droplet size distribution

  7. Intercomparison of model simulations of mixed-phase clouds observed...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. I: Single layer cloud Citation Details ...

  8. ARM - Measurement - Ice water content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    content ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Ice water content The concentration (mass/vol) of ice water particles in a cloud. Categories Atmospheric State, Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  9. ARM - Measurement - Liquid water content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    content ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water content The concentration (mass/vol) of liquid water droplets in a cloud. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded

  10. Understanding and Improving CRM and GCM Simulations of Cloud Systems with ARM Observations

    SciTech Connect (OSTI)

    Wu, Xiaoqing

    2014-02-25

    The works supported by this ASR project lay the solid foundation for improving the parameterization of convection and clouds in the NCAR CCSM and the climate simulations. We have made a significant use of CRM simulations and ARM observations to produce thermodynamically and dynamically consistent multi-year cloud and radiative properties; improve the GCM simulations of convection, clouds and radiative heating rate and fluxes using the ARM observations and CRM simulations; and understand the seasonal and annual variation of cloud systems and their impacts on climate mean state and variability. We conducted multi-year simulations over the ARM SGP site using the CRM with multi-year ARM forcing data. The statistics of cloud and radiative properties from the long-term CRM simulations were compared and validated with the ARM measurements and value added products (VAP). We evaluated the multi-year climate simulations produced by the GCM with the modified convection scheme. We used multi-year ARM observations and CRM simulations to validate and further improve the trigger condition and revised closure assumption in NCAR GCM simulations that demonstrate the improvement of climate mean state and variability. We combined the improved convection scheme with the mosaic treatment of subgrid cloud distributions in the radiation scheme of the GCM. The mosaic treatment of cloud distributions has been implemented in the GCM with the original convection scheme and enables the use of more realistic cloud amounts as well as cloud water contents in producing net radiative fluxes closer to observations. A physics-based latent heat (LH) retrieval algorithm was developed by parameterizing the physical linkages of observed hydrometeor profiles of cloud and precipitation to the major processes related to the phase change of atmospheric water.

  11. Coupling Between Oceanic Upwelling and Cloud-aerosol Properties at the AMF Point Reyes Site

    SciTech Connect (OSTI)

    Dunn, M.; Jensen, M.; Miller, M.; Kollias, P.; Bartholomew, M. J.; Turner, D.; Andrews, E.; Jefferson, A.; Daum, P.

    2008-03-10

    Cloud microphysical properties measured at the ARM Mobile Facility site located on the northern coast of California near Point Reyes, during the 2005 Marine Stratus Radiation, Aerosol and Drizzle experiment, were analyzed to determine their relationship to the coastal sea surface temperature (SST) which was characterized using measurements acquired from a National Oceanic and Atmospheric Administration offshore buoy. An increase in SST resulting from a relaxation of upwelling, occurring in the eastern Pacific Ocean off the coast of California in summer is observed to strongly correlate with nearby ground measured cloud microphysical properties and cloud condensation nuclei (CCN) concentrations. Correlations between these atmospheric and oceanic features provide insight into the interplay between the ocean and cloud radiative properties. We present evidence of this robust correlation and examine the factors controlling these features. The marine boundary layer is in direct contact with the sea surface and is strongly influenced by SST. Moisture and vertical motion are crucial ingredients for cloud development and so we examine the role of SST in providing these key components to the atmosphere. Although upwelling of cold subsurface waters is conventionally thought to increase aerosols in the region, thus increasing clouds, here we observed a relaxation of upwelling associated with changes in the structure of marine stratus clouds. As upwelling relaxes, the SST get warmer, thick clouds with high liquid water paths are observed and persist for a few days. This cycle is repeated throughout the summer upwelling season. A concomitant cyclic increase and decrease of CCN concentration is also observed. Forcing mechanisms and large-scale atmospheric features are discussed. Marine stratocumulus clouds are a critical component of the earth's radiation budget and this site provides an excellent opportunity to study the influence of SST on these clouds.

  12. RACORO Extended-Term Aircraft Observations of Boundary-Layer Clouds

    SciTech Connect (OSTI)

    Vogelmann, A. M.; McFarquhar, Greg; Ogren, John A.; Turner, David D.; Comstock, Jennifer M.; Feingold, G.; Long, Charles N.; Jonsson, Haf; Bucholtz, Anthony; Collins, Donald R.; Diskin, G. S.; Gerber, H.; Lawson, Paul; Woods, Roy; Andrews, Elizabeth; Yang, Hee-Jung; Chiu, Christine J.; Hartsock, Daniel; Hubbe, John M.; Lo, Chaomei; Marshak, A.; Monroe, Justin; McFarlane, Sally A.; Schmid, Beat; Tomlinson, Jason M.; Toto, Tami

    2012-06-30

    A first-of-a-kind, extended-term cloud aircraft campaign was conducted to obtain an in-situ statistical characterization of boundary-layer clouds needed to investigate cloud processes and refine retrieval algorithms. Coordinated by the Atmospheric Radiation Measurement (ARM) Aerial Facility (AAF), the Routine AAF Clouds with Low Optical Water Depths (CLOWD) Optical Radiative Observations (RACORO) field campaign operated over the ARM Southern Great Plains (SGP) site from 22 January to 30 June 2009, collecting 260 h of data during 59 research flights. A comprehensive payload aboard the Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS) Twin Otter aircraft measured cloud microphysics, solar and thermal radiation, aerosol properties, and atmospheric state parameters. Proximity to the SGP's extensive complement of surface measurements provides ancillary data that supports modeling studies and enables evaluating a variety of surface retrieval algorithms. The five-month duration enabled sampling a range of conditions associated with the seasonal transition from winter to summer. Although about two-thirds of the cloud flights occurred in May and June, boundary-layer cloud fields were sampled under a variety of environmental and aerosol conditions, with about 75% of the flights occurring in cumulus and stratocumulus. Preliminary analyses show how these data are being used to analyze cloud-aerosol relationships, determine the aerosol sizes that are responsible for nucleating cloud drops, characterize the horizontal variability of the cloud radiative impacts, and evaluate air-borne and surface-based cloud property retrievals. We discuss how conducting an extended-term campaign requires a simplified operating paradigm that is different from that used for typical, short-term, intensive aircraft field programs.

  13. Tropical Warm Pool International Cloud Experiment (TWP-ICE): Cloud and Rain Characteristics in the Australian Monsoon

    SciTech Connect (OSTI)

    PT May; C Jakob; JH Mather

    2004-05-30

    The impact of oceanic convection on its environment and the relationship between the characteristics of the convection and the resulting cirrus characteristics is still not understood. An intense airborne measurement campaign combined with an extensive network of ground-based observations is being planned for the region near Darwin, Northern Australia, during January-February, 2006, to address these questions. The Tropical Warm Pool International Cloud Experiment (TWP-ICE) will be the first field program in the tropics that attempts to describe the evolution of tropical convection, including the large scale heat, moisture, and momentum budgets, while at the same time obtaining detailed observations of cloud properties and the impact of the clouds on the environment. The emphasis will be on cirrus for the cloud properties component of the experiment. Cirrus clouds are ubiquitous in the tropics and have a large impact on their environment but the properties of these clouds are poorly understood. A crucial product from this experiment will be a dataset suitable to provide the forcing and testing required by cloud-resolving models and parameterizations in global climate models. This dataset will provide the necessary link between cloud properties and the models that are attempting to simulate them. The experiment is a collaboration between the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Program, the Bureau of Meteorology (BoM), the National Aeronautics and Space Administration (NASA), the European Commission DG RTD-1.2, and several United States, Australian, Canadian, and European Universities. This experiment will be undertaken over a 4-week period in early 2006. January and February corresponds to the wet phase of the Australia monsoon. This season has been selected because, despite Darwins coastal location, the convection that occurs over and near Darwin at this time is largely of maritime origin with a large fetch over water. Based on previous experiments, the convection appears typical of maritime convection with widespread convection that has complex organization, but is not as deep or as intense as continental or coastal convection. Therefore, it is expected that the convection and cloud characteristics will be representative of conditions typical for wide areas of the tropics.

  14. Cloud Computing Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Services - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  15. The influence of mixed and phase clouds on surface shortwave irradiance during the Arctic spring

    SciTech Connect (OSTI)

    Lubin D.; Vogelmann A.

    2011-10-13

    The influence of mixed-phase stratiform clouds on the surface shortwave irradiance is examined using unique spectral shortwave irradiance measurements made during the Indirect and Semi-Direct Aerosol Campaign (ISDAC), supported by the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program. An Analytical Spectral Devices (ASD, Inc.) spectroradiometer measured downwelling spectral irradiance from 350 to 2200 nm in one-minute averages throughout April-May 2008 from the ARM Climate Research Facility's North Slope of Alaska (NSA) site at Barrow. This study examines spectral irradiance measurements made under single-layer, overcast cloud decks having geometric thickness < 3000 m. Cloud optical depth is retrieved from irradiance in the interval 1022-1033 nm. The contrasting surface radiative influences of mixed-phase clouds and liquid-water clouds are discerned using irradiances in the 1.6-{micro}m window. Compared with liquid-water clouds, mixed-phase clouds during the Arctic spring cause a greater reduction of shortwave irradiance at the surface. At fixed conservative-scattering optical depth (constant optical depth for wavelengths {lambda} < 1100 nm), the presence of ice water in cloud reduces the near-IR surface irradiance by an additional several watts-per-meter-squared. This additional reduction, or supplemental ice absorption, is typically {approx}5 W m{sup -2} near solar noon over Barrow, and decreases with increasing solar zenith angle. However, for some cloud decks this additional absorption can be as large as 8-10 W m{sup -2}.

  16. ARM - Field Campaign - Arctic Winter Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Al Gasiewsk, Taneil Uttal, and Duane Hazen, Domenico CiminiM Vinia Mattioli, Bob L. Weber, Sally Dowlatshahi,Joe A. Shaw, Jim Liljegren ,B. M. Lesht, Bernie Zak; The 2004 North...

  17. Tropical Anvil Characteristics and Water Vapor of the Tropical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the nature of solute. 2) Heymsfield and Miloshevich (1993): J r depends on T. Depression of freezing point due to solute and curvature effects is considered but those...

  18. Cloud Optical Properties from the Multifilter Shadowband Radiometer (MFRSRCLDOD): An ARM Value-Added Product

    SciTech Connect (OSTI)

    Turner, DD; McFarlane, SA; Riihimaki, L; Shi, Y; Lo, C; Min, Q

    2014-02-01

    The microphysical properties of clouds play an important role in studies of global climate change. Observations from satellites and surface-based systems have been used to infer cloud optical depth and effective radius. Min and Harrison (1996) developed an inversion method to infer the optical depth of liquid water clouds from narrow band spectral Multifilter Rotating Shadowband Radiometer (MFRSR) measurements (Harrison et al. 1994). Their retrieval also uses the total liquid water path (LWP) measured by a microwave radiometer (MWR) to obtain the effective radius of the warm cloud droplets. Their results were compared with Geostationary Operational Environmental Satellite (GOES) retrieved values at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site (Min and Harrison 1996). Min et al. (2003) also validated the retrieved cloud optical properties against in situ observations, showing that the retrieved cloud effective radius agreed well with the in situ forward scattering spectrometer probe observations. The retrieved cloud optical properties from Min et al. (2003) were used also as inputs to an atmospheric shortwave model, and the computed fluxes were compared with surface pyranometer observations.

  19. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, Terry (Tracy, CA)

    1988-01-01

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself.

  20. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2006-07-26

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  1. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2007-10-23

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  2. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, T.

    1988-03-15

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

  3. What Makes Clouds Form, Grow and Die?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Makes Clouds Form, Grow and Die? What Makes Clouds Form, Grow and Die? Simulations Show Raindrops Physics May Affect Climate Model Accuracy February 19, 2015 thunderstorm Brazil shuttle NASA 1984 540 PNNL scientists used real-world observations to simulate how small clouds are likely to stay shallow, while larger clouds grow deeper because they mix with less dry air. Pictured are small and large thunderstorms growing over southern Brazil, taken from the space shuttle. Image: NASA Johnson Space

  4. Layered Atlantic Smoke Interactions with Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Layered Atlantic Smoke Interactions with Clouds Island in the South Atlantic Ocean. Warm African winds combine with the cool sea surface temperatures and form a large stratocumulus deck, transitioning to year-round trade-wind shallow cumulus at the location of Ascension Island. These clouds and myriad aerosol-cloud-radiation interactions will be studied. Using a portable observatory, or ARM Mobile Facility (AMF), that contains some of most advanced atmospheric research instrumentation for cloud,

  5. RACORO continental boundary layer cloud investigations. 2. Large-eddy simulations of cumulus clouds and evaluation with in-situ and ground-based observations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Endo, Satoshi; Fridlind, Ann M.; Lin, Wuyin; Vogelmann, Andrew M.; Toto, Tami; Ackerman, Andrew S.; McFarquhar, Greg M.; Jackson, Robert C.; Jonsson, Haflidi H.; Liu, Yangang

    2015-06-19

    A 60-hour case study of continental boundary layer cumulus clouds is examined using two large-eddy simulation (LES) models. The case is based on observations obtained during the RACORO Campaign (Routine Atmospheric Radiation Measurement [ARM] Aerial Facility [AAF] Clouds with Low Optical Water Depths [CLOWD] Optical Radiative Observations) at the ARM Climate Research Facility's Southern Great Plains site. The LES models are driven by continuous large-scale and surface forcings, and are constrained by multi-modal and temporally varying aerosol number size distribution profiles derived from aircraft observations. We compare simulated cloud macrophysical and microphysical properties with ground-based remote sensing and aircraft observations.more » The LES simulations capture the observed transitions of the evolving cumulus-topped boundary layers during the three daytime periods, and generally reproduce variations of droplet number concentration with liquid water content (LWC), corresponding to the gradient between the cloud centers and cloud edges at given heights. The observed LWC values fall within the range of simulated values; the observed droplet number concentrations are commonly higher than simulated, but differences remain on par with potential estimation errors in the aircraft measurements. Sensitivity studies examine the influences of bin microphysics versus bulk microphysics, aerosol advection, supersaturation treatment, and aerosol hygroscopicity. Simulated macrophysical cloud properties are found to be insensitive in this non-precipitating case, but microphysical properties are especially sensitive to bulk microphysics supersaturation treatment and aerosol hygroscopicity.« less

  6. RACORO continental boundary layer cloud investigations. 2. Large-eddy simulations of cumulus clouds and evaluation with in-situ and ground-based observations

    SciTech Connect (OSTI)

    Endo, Satoshi; Fridlind, Ann M.; Lin, Wuyin; Vogelmann, Andrew M.; Toto, Tami; Ackerman, Andrew S.; McFarquhar, Greg M.; Jackson, Robert C.; Jonsson, Haflidi H.; Liu, Yangang

    2015-06-19

    A 60-hour case study of continental boundary layer cumulus clouds is examined using two large-eddy simulation (LES) models. The case is based on observations obtained during the RACORO Campaign (Routine Atmospheric Radiation Measurement [ARM] Aerial Facility [AAF] Clouds with Low Optical Water Depths [CLOWD] Optical Radiative Observations) at the ARM Climate Research Facility's Southern Great Plains site. The LES models are driven by continuous large-scale and surface forcings, and are constrained by multi-modal and temporally varying aerosol number size distribution profiles derived from aircraft observations. We compare simulated cloud macrophysical and microphysical properties with ground-based remote sensing and aircraft observations. The LES simulations capture the observed transitions of the evolving cumulus-topped boundary layers during the three daytime periods, and generally reproduce variations of droplet number concentration with liquid water content (LWC), corresponding to the gradient between the cloud centers and cloud edges at given heights. The observed LWC values fall within the range of simulated values; the observed droplet number concentrations are commonly higher than simulated, but differences remain on par with potential estimation errors in the aircraft measurements. Sensitivity studies examine the influences of bin microphysics versus bulk microphysics, aerosol advection, supersaturation treatment, and aerosol hygroscopicity. Simulated macrophysical cloud properties are found to be insensitive in this non-precipitating case, but microphysical properties are especially sensitive to bulk microphysics supersaturation treatment and aerosol hygroscopicity.

  7. Method and Apparatus for Concentrating Vapors for Analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2008-10-07

    An apparatus and method are disclosed for pre-concentrating gaseous vapors for analysis. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable. Vapors sorbed and concentrated within the bed of the apparatus can be thermally desorbed achieving at least partial separation of vapor mixtures. The apparatus is suitable, e.g., for preconcentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than for direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications.

  8. Detecting Drizzle in Marine Warm Clouds Using Visible, Infrared, and Microwave Satellite Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Drizzle in Marine Warm Clouds Using Visible, Infrared, and Microwave Satellite Data H. Shao and G. Liu Florida State University Tallahassee, Florida Introduction Determining the radiative effects of aerosols is one of the most important areas in climate research. There are observational evidences showing that aerosols can affect the radiative balance of the earth indirectly - as the number of aerosols increases, water in the cloud spreads over many more particles. Large concentrations of small

  9. Evolving the Land Information System into a Cloud Computing Service

    SciTech Connect (OSTI)

    Houser, Paul R.

    2015-02-17

    The Land Information System (LIS) was developed to use advanced flexible land surface modeling and data assimilation frameworks to integrate extremely large satellite- and ground-based observations with advanced land surface models to produce continuous high-resolution fields of land surface states and fluxes. The resulting fields are extremely useful for drought and flood assessment, agricultural planning, disaster management, weather and climate forecasting, water resources assessment, and the like. We envisioned transforming the LIS modeling system into a scientific cloud computing-aware web and data service that would allow clients to easily setup and configure for use in addressing large water management issues. The focus of this Phase 1 project was to determine the scientific, technical, commercial merit and feasibility of the proposed LIS-cloud innovations that are currently barriers to broad LIS applicability. We (a) quantified the barriers to broad LIS utility and commercialization (high performance computing, big data, user interface, and licensing issues); (b) designed the proposed LIS-cloud web service, model-data interface, database services, and user interfaces; (c) constructed a prototype LIS user interface including abstractions for simulation control, visualization, and data interaction, (d) used the prototype to conduct a market analysis and survey to determine potential market size and competition, (e) identified LIS software licensing and copyright limitations and developed solutions, and (f) developed a business plan for development and marketing of the LIS-cloud innovation. While some significant feasibility issues were found in the LIS licensing, overall a high degree of LIS-cloud technical feasibility was found.

  10. ARM Data for Cloud Parameterization

    SciTech Connect (OSTI)

    Xu, Kuan-Man

    2006-10-02

    The PI's ARM investigation (DE-IA02-02ER633 18) developed a physically-based subgrid-scale saturation representation that fully considers the direct interactions of the parameterized subgrid-scale motions with subgrid-scale cloud microphysical and radiative processes. Major accomplishments under the support of that interagency agreement are summarized in this paper.

  11. Unlocking the Secrets of Clouds

    Office of Energy Efficiency and Renewable Energy (EERE)

    Clouds may look soft, fluffy and harmless to the untrained eye, but to an expert climate model scientist they represent great challenges. Fortunately the Atmospheric Radiation Measurement (ARM) Climate and Research Facility is kicking off a five-month study which should significantly clear the air.

  12. Advancing Explosives Detection Capabilities: Vapor Detection

    SciTech Connect (OSTI)

    Atkinson, David

    2012-10-15

    A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

  13. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  14. Advancing Explosives Detection Capabilities: Vapor Detection

    ScienceCinema (OSTI)

    Atkinson, David

    2014-07-24

    A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

  15. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Chunsong; Liu, Yangang; Niu, Shengjie; Endo, Satoshi

    2014-12-17

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasingmore » scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.« less

  16. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    SciTech Connect (OSTI)

    Lu, Chunsong; Liu, Yangang; Niu, Shengjie; Endo, Satoshi

    2014-12-17

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasing scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.

  17. Method of physical vapor deposition of metal oxides on semiconductors

    DOE Patents [OSTI]

    Norton, David P. (Knoxville, TN)

    2001-01-01

    A process for growing a metal oxide thin film upon a semiconductor surface with a physical vapor deposition technique in a high-vacuum environment and a structure formed with the process involves the steps of heating the semiconductor surface and introducing hydrogen gas into the high-vacuum environment to develop conditions at the semiconductor surface which are favorable for growing the desired metal oxide upon the semiconductor surface yet is unfavorable for the formation of any native oxides upon the semiconductor. More specifically, the temperature of the semiconductor surface and the ratio of hydrogen partial pressure to water pressure within the vacuum environment are high enough to render the formation of native oxides on the semiconductor surface thermodynamically unstable yet are not so high that the formation of the desired metal oxide on the semiconductor surface is thermodynamically unstable. Having established these conditions, constituent atoms of the metal oxide to be deposited upon the semiconductor surface are directed toward the surface of the semiconductor by a physical vapor deposition technique so that the atoms come to rest upon the semiconductor surface as a thin film of metal oxide with no native oxide at the semiconductor surface/thin film interface. An example of a structure formed by this method includes an epitaxial thin film of (001)-oriented CeO.sub.2 overlying a substrate of (001) Ge.

  18. Water mist injection in oil shale retorting

    DOE Patents [OSTI]

    Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

    1980-07-30

    Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

  19. ARM - Field Campaign - Cloud Radar IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsCloud Radar IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Cloud Radar IOP 1997.04.02 - 1997.04.22 Lead Scientist : Brooks Martner Data Availability MMCR Quick Look Data For data sets, see below. Abstract The objectives of the Cloud Radar IOP are to: support the calibration of the ARM millimeter cloud radar and evaluate the spatial versus temporal variability of cloud properties as seen

  20. Model analysis of the anthropogenic aerosol effect on clouds over East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhang, Meigen; Liu, Xiaohong; Zhao, Chun

    2012-01-16

    A coupled meteorology and aerosol/chemistry model WRF-Chem (Weather Research and Forecast model coupled with Chemistry) was used to conduct a pair of simulations with present-day (PD) and preindustrial (PI) emissions over East Asia to examine the aerosol indirect effect on clouds. As a result of an increase in aerosols in January, the cloud droplet number increased by 650 cm{sup -3} over the ocean and East China, 400 cm{sup -3} over Central and Southwest China, and less than 200 cm{sup -3} over North China. The cloud liquid water path (LWP) increased by 40-60 g m{sup -2} over the ocean and Southeast China and 30 g m{sup -2} over Central China; the LWP increased less than 5 g m{sup -2} or decreased by 5 g m{sup -2} over North China. The effective radius (Re) decreased by more than 4 {mu}m over Southwest, Central, and Southeast China and 2 {mu}m over North China. In July, variations in cloud properties were more uniform; the cloud droplet number increased by approximately 250-400 cm{sup -3}, the LWP increased by approximately 30-50 g m{sup -2}, and Re decreased by approximately 3 {mu}m over most regions of China. In response to cloud property changes from PI to PD, shortwave (SW) cloud radiative forcing strengthened by 30 W m{sup -2} over the ocean and 10 W m{sup -2} over Southeast China, and it weakened slightly by approximately 2-10 W m{sup -2} over Central and Southwest China in January. In July, SW cloud radiative forcing strengthened by 15 W m{sup -2} over Southeast and North China and weakened by 10 W m{sup -2} over Central China. The different responses of SW cloud radiative forcing in different regions was related to cloud feedbacks and natural variability.

  1. Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) Science Plan

    SciTech Connect (OSTI)

    Fast, JD; Berg, LK

    2015-12-01

    Cumulus convection is an important component in the atmospheric radiation budget and hydrologic cycle over the Southern Great Plains and over many regions of the world, particularly during the summertime growing season when intense turbulence induced by surface radiation couples the land surface to clouds. Current convective cloud parameterizations contain uncertainties resulting in part from insufficient coincident data that couples cloud macrophysical and microphysical properties to inhomogeneities in boundary layer and aerosol properties. The Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) campaign is designed to provide a detailed set of measurements that are needed to obtain a more complete understanding of the life cycle of shallow clouds by coupling cloud macrophysical and microphysical properties to land surface properties, ecosystems, and aerosols. HI-SCALE consists of 2, 4-week intensive observational periods, one in the spring and the other in the late summer, to take advantage of different stages and distribution of “greenness” for various types of vegetation in the vicinity of the Atmospheric Radiation and Measurement (ARM) Climate Research Facility’s Southern Great Plains (SGP) site as well as aerosol properties that vary during the growing season. Most of the proposed instrumentation will be deployed on the ARM Aerial Facility (AAF) Gulfstream 1 (G-1) aircraft, including those that measure atmospheric turbulence, cloud water content and drop size distributions, aerosol precursor gases, aerosol chemical composition and size distributions, and cloud condensation nuclei concentrations. Routine ARM aerosol measurements made at the surface will be supplemented with aerosol microphysical properties measurements. The G-1 aircraft will complete transects over the SGP Central Facility at multiple altitudes within the boundary layer, within clouds, and above clouds.

  2. Moisture Durability of Vapor Permeable Insulating Sheathing (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-10-01

    In this project, Building America team Building Science Corporation researched some of the ramifications of using exterior, vapor permeable insulation on retrofit walls with vapor permeable cavity insulation. Retrofit strategies are a key factor in reducing exterior building stock consumption.

  3. Type B Accident Investigation of the Acid Vapor Inhalation on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Acid Vapor Inhalation on June 7, 2005, in TA-48, Building RC-1 Room 402 at the Los Alamos National Laboratory Type B Accident Investigation of the Acid Vapor Inhalation on June 7,...

  4. Non-Vapor Compression HVAC Technologies Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Non-Vapor Compression HVAC Technologies Report Non-Vapor Compression HVAC Technologies Report This thermoelastic system provides a promising alternative to traditional vapor-compression HVAC technologies. Read the full report below to learn more. <em>Credit: University of Maryland</em> This thermoelastic system provides a promising alternative to traditional vapor-compression HVAC technologies. Read the full report below to learn more. Credit: University of Maryland While

  5. Final report on the project entitled "The Effects of Disturbance & Climate on Carbon Storage & the Exchanges of CO2 Water Vapor & Energy Exchange of Evergreen Coniferous Forests in the Pacific Northwest: Integration of Eddy Flux, Plant and Soil Measurements at a Cluster of Supersites"

    SciTech Connect (OSTI)

    Beverly E. Law , Christoph K. Thomas

    2011-09-20

    This is the final technical report containing a summary of all findings with regard to the following objectives of the project: (1) To quantify and understand the effects of wildfire on carbon storage and the exchanges of energy, CO2, and water vapor in a chronosequence of ponderosa pine (disturbance gradient); (2) To investigate the effects of seasonal and interannual variation in climate on carbon storage and the exchanges of energy, CO2, and water vapor in mature conifer forests in two climate zones: mesic 40-yr old Douglas-fir and semi-arid 60-yr old ponderosa pine (climate gradient); (3) To reduce uncertainty in estimates of CO2 feedbacks to the atmosphere by providing an improved model formulation for existing biosphere-atmosphere models; and (4) To provide high quality data for AmeriFlux and the NACP on micrometeorology, meteorology, and biology of these systems. Objective (1): A study integrating satellite remote sensing, AmeriFlux data, and field surveys in a simulation modeling framework estimated that the pyrogenic carbon emissions, tree mortality, and net carbon exchange associated with four large wildfires that burned ~50,000 hectares in 2002-2003 were equivalent to 2.4% of Oregon statewide anthropogenic carbon emissions over the same two-year period. Most emissions were from the combustion of the forest floor and understory vegetation, and only about 1% of live tree mass was combusted on average. Objective (2): A study of multi-year flux records across a chronosequence of ponderosa pine forests yielded that the net carbon uptake is over three times greater at a mature pine forest compared with young pine. The larger leaf area and wetter and cooler soils of the mature forest mainly caused this effect. A study analyzing seven years of carbon and water dynamics showed that interannual and seasonal variability of net carbon exchange was primarily related to variability in growing season length, which was a linear function of plant-available soil moisture in spring and early summer. A multi-year drought (2001-2003) led to a significant reduction of net ecosystem exchange due to carry-over effects in soil moisture and carbohydrate reserves in plant-tissue. In the same forest, the interannual variability in the rate carbon is lost from the soil and forest floor is considerable and related to the variability in tree growth as much as it is to variability in soil climatic conditions. Objective (3): Flux data from the mature ponderosa pine site support a physical basis for filtering nighttime data with friction velocity above the canopy. An analysis of wind fields and heat transport in the subcanopy at the mesic 40-year old Douglas site yielded that the non-linear structure and behavior of spatial temperature gradients and the flow field require enhanced sensor networks to estimate advective fluxes in the subcanopy of forest to close the surface energy balance in forests. Reliable estimates for flux uncertainties are needed to improve model validation and data assimilation in process-based carbon models, inverse modeling studies and model-data synthesis, where the uncertainties may be as important as the fluxes themselves. An analysis of the time scale dependence of the random and flux sampling error yielded that the additional flux obtained by increasing the perturbation timescale beyond about 10 minutes is dominated by random sampling error, and therefore little confidence can be placed in its value. Artificial correlation between gross ecosystem productivity (GEP) and ecosystem respiration (Re) is a consequence of flux partitioning of eddy covariance flux data when GEP is computed as the difference between NEE and computed daytime Re (e.g. using nighttime Re extrapolated into daytime using soil or air temperatures). Tower-data must be adequately spatially averaged before comparison to gridded model output as the time variability of both is inherently different. The eddy-covariance data collected at the mature ponderosa pine site and the mesic Douglas fir site were used to develop and evaluate a new method to extra

  6. Two Electron Holes in Hematite Facilitate Water Splitting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by-product is nonpolluting water vapor. The problem, however, is that the production of hydrogen-via the process of water splitting-currently requires the burning of traditional...

  7. Uranium accountancy in Atomic Vapor Laser Isotope Separation

    SciTech Connect (OSTI)

    Carver, R.D.

    1986-01-01

    The AVLIS program pioneers the large scale industrial application of lasers to produce low cost enriched uranium fuel for light water reactors. In the process developed at Lawrence Livermore National Laboratory, normal uranium is vaporized by an electron beam, and a precisely tuned laser beam selectively photo-ionizes the uranium-235 isotopes. These ions are moved in an electromagnetic field to be condensed on the product collector. All other uranium isotopes remain uncharged and pass through the collector section to condense as tails. Tracking the three types of uranium through the process presents special problems in accountancy. After demonstration runs, the uranium on the collector was analyzed for isotopic content by Battelle Pacific Northwest Laboratory. Their results were checked at LLNL by analysis of parallel samples. The differences in isotopic composition as reported by the two laboratories were not significant.

  8. Quantifying Diurnal Cloud Radiative Effects by Cloud Type in the Tropical Western Pacific

    SciTech Connect (OSTI)

    Burleyson, Casey D.; Long, Charles N.; Comstock, Jennifer M.

    2015-06-01

    Cloud radiative effects are examined using long-term datasets collected at the three Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facilities in the tropical western Pacific. We quantify the surface radiation budget, cloud populations, and cloud radiative effects by partitioning the data by cloud type, time of day, and as a function of large scale modes of variability such as El Niño Southern Oscillation (ENSO) phase and wet/dry seasons at Darwin. The novel facet of our analysis is that we break aggregate cloud radiative effects down by cloud type across the diurnal cycle. The Nauru cloud populations and subsequently the surface radiation budget are strongly impacted by ENSO variability whereas the cloud populations over Manus only shift slightly in response to changes in ENSO phase. The Darwin site exhibits large seasonal monsoon related variations. We show that while deeper convective clouds have a strong conditional influence on the radiation reaching the surface, their limited frequency reduces their aggregate radiative impact. The largest source of shortwave cloud radiative effects at all three sites comes from low clouds. We use the observations to demonstrate that potential model biases in the amplitude of the diurnal cycle and mean cloud frequency would lead to larger errors in the surface energy budget compared to biases in the timing of the diurnal cycle of cloud frequency. Our results provide solid benchmarks to evaluate model simulations of cloud radiative effects in the tropics.

  9. Clouds, Aerosols and Precipitation in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Marine Boundary Layer (CAP-MBL) Graciosa Island, Azores, NE Atlantic Ocean Graciosa Island, Azores, NE Atlantic Ocean May 2009-December 2010 May 2009-December 2010 Rob Wood, University of Washington Rob Wood, University of Washington AMF Deployment Team Thanks to Mark Miller: AMF Site Scientist Mark Miller: AMF Site Scientist Kim Nitschke: AMF Site Manager CAP-MBL Proposal Team Importance of Low-Clouds for Climate Imperative that we understand the processes controlling the formation,

  10. Ice Concentration Retrieval in Stratiform Mixed-phase Clouds Using Cloud Radar Reflectivity Measurements and 1D Ice Growth Model Simulations

    SciTech Connect (OSTI)

    Zhang, Damao; Wang, Zhien; Heymsfield, Andrew J.; Fan, Jiwen; Luo, Tao

    2014-10-01

    Measurement of ice number concentration in clouds is important but still challenging. Stratiform mixed-phase clouds (SMCs) provide a simple scenario for retrieving ice number concentration from remote sensing measurements. The simple ice generation and growth pattern in SMCs offers opportunities to use cloud radar reflectivity (Ze) measurements and other cloud properties to infer ice number concentration quantitatively. To understand the strong temperature dependency of ice habit and growth rate quantitatively, we develop a 1-D ice growth model to calculate the ice diffusional growth along its falling trajectory in SMCs. The radar reflectivity and fall velocity profiles of ice crystals calculated from the 1-D ice growth model are evaluated with the Atmospheric Radiation Measurements (ARM) Climate Research Facility (ACRF) ground-based high vertical resolution radar measurements. Combining Ze measurements and 1-D ice growth model simulations, we develop a method to retrieve the ice number concentrations in SMCs at given cloud top temperature (CTT) and liquid water path (LWP). The retrieved ice concentrations in SMCs are evaluated with in situ measurements and with a three-dimensional cloud-resolving model simulation with a bin microphysical scheme. These comparisons show that the retrieved ice number concentrations are within an uncertainty of a factor of 2, statistically.

  11. Metal vapor laser including hot electrodes and integral wick

    DOE Patents [OSTI]

    Ault, E.R.; Alger, T.W.

    1995-03-07

    A metal vapor laser, specifically one utilizing copper vapor, is disclosed herein. This laser utilizes a plasma tube assembly including a thermally insulated plasma tube containing a specific metal, e.g., copper, and a buffer gas therein. The laser also utilizes means including hot electrodes located at opposite ends of the plasma tube for electrically exciting the metal vapor and heating its interior to a sufficiently high temperature to cause the metal contained therein to vaporize and for subjecting the vapor to an electrical discharge excitation in order to lase. The laser also utilizes external wicking arrangements, that is, wicking arrangements located outside the plasma tube. 5 figs.

  12. Fine-scale Horizontal Structure of Arctic Mixed-Phase Clouds.

    SciTech Connect (OSTI)

    Rambukkange,M.; Verlinde, J.; Elorante, E.; Luke, E.; Kollias, P.; Shupe, M.

    2006-07-10

    Recent in situ observations in stratiform clouds suggest that mixed phase regimes, here defined as limited cloud volumes containing both liquid and solid water, are constrained to narrow layers (order 100 m) separating all-liquid and fully glaciated volumes (Hallett and Viddaurre, 2005). The Department of Energy Atmospheric Radiation Measurement Program's (DOE-ARM, Ackerman and Stokes, 2003) North Slope of Alaska (NSA) ARM Climate Research Facility (ACRF) recently started collecting routine measurement of radar Doppler velocity power spectra from the Millimeter Cloud Radar (MMCR). Shupe et al. (2004) showed that Doppler spectra has potential to separate the contributions to the total reflectivity of the liquid and solid water in the radar volume, and thus to investigate further Hallett and Viddaurre's findings. The Mixed-Phase Arctic Cloud Experiment (MPACE) was conducted along the NSA to investigate the properties of Arctic mixed phase clouds (Verlinde et al., 2006). We present surface based remote sensing data from MPACE to discuss the fine-scale structure of the mixed-phase clouds observed during this experiment.

  13. Apparatus and method for photochemical vapor deposition

    DOE Patents [OSTI]

    Jackson, Scott C. (Wilmington, DE); Rocheleau, Richard E. (Wilmington, DE)

    1987-03-31

    A photochemical vapor deposition apparatus includes a reactor housing having a window in one wall above a reaction chamber in the housing. A transparent curtain divides the reaction chamber into a reaction zone and a flush zone. At least one substrate is mounted in the reaction zone in light communication with the window so that ultraviolet radiation may penetrate through the window into the reaction zone. The window is kept clear by a gas flowing through the flush zone.

  14. Combined rankine and vapor compression cycles

    DOE Patents [OSTI]

    Radcliff, Thomas D.; Biederman, Bruce P.; Brasz, Joost J.

    2005-04-19

    An organic rankine cycle system is combined with a vapor compression cycle system with the turbine generator of the organic rankine cycle generating the power necessary to operate the motor of the refrigerant compressor. The vapor compression cycle is applied with its evaporator cooling the inlet air into a gas turbine, and the organic rankine cycle is applied to receive heat from a gas turbine exhaust to heat its boiler within one embodiment, a common condenser is used for the organic rankine cycle and the vapor compression cycle, with a common refrigerant, R-245a being circulated within both systems. In another embodiment, the turbine driven generator has a common shaft connected to the compressor to thereby eliminate the need for a separate motor to drive the compressor. In another embodiment, an organic rankine cycle system is applied to an internal combustion engine to cool the fluids thereof, and the turbo charged air is cooled first by the organic rankine cycle system and then by an air conditioner prior to passing into the intake of the engine.

  15. Evaluation of Cloud Type Occurrences and Radiative Forcings Simulated by a Cloud Resolving Model Using Observations from Sa...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Type Occurrences and Radiative Forcings Simulated by a Cloud Resolving Model Using Observations from Satellite and Cloud Radar Y. Luo and S. K. Krueger University of Utah Salt Lake City, Utah Introduction Because of both the various effects clouds exert on the earth-atmospheric system and the cloud feedback, correct representations of clouds in numerical models are critical for accurate climate modeling and weather forecast. Unfortunately, determination of clouds and their radiative

  16. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, Jr., Edward P. (Idaho Falls, ID)

    1999-01-01

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

  17. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, E.P. Jr.

    1999-01-12

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed there between. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock. 2 figs.

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated Water Vapor and Cloud Liquid Water at MCTEX Submitter: Liljegren, J. C., Argonne National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Continuous Dataset of Water Vapor Measurements Throws Water on Assumptions of Cirrus Cloud Formation Submitter: Comstock, J. M., Pacific Northwest National Laboratory Area of...

  20. Storm Clouds Take Rain on Rollercoaster Ride

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clouds Take Rain on Rollercoaster Ride For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Most of us think that when rain forms in a cloud, it will instantly fall down. That's what climate models typically assume, too. But in reality, rising plumes that form turbulent storm clouds can often carry raindrops, snowflakes, and even hailstones upward before they fall out. This lengthened journey prolongs their growth stage and

  1. A Global Cloud Resolving Model Goals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Global Cloud Resolving Model Goals Uniform global horizontal grid spacing of 4 km or better ("cloud permitting") 100 or more layers up to at least the stratopause Parameterizations of microphysics, turbulence (including small clouds), and radiation Execution speed of at least several simulated days per wall-clock day on immediately available systems Annual cycle simulation by end of 2011. Motivations Parameterizations are still problematic. There are no spectral gaps. The equations

  2. Exploring Stratocumulus Cloud-Top Entrainment Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stratocumulus Cloud-Top Entrainment Processes and Parameterizations by Using Doppler For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Stratocumulus clouds are a particularly important component of the Earth's climate system due to their large impact on the radiation budget. But the parameterization of entrainment in these clouds is yet to be fully resolved, which leads to uncertainties in numerical model forecasts ranging

  3. ARM - Measurement - Cloud particle number concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    number concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle number concentration The total number of cloud particles present in any given volume of air. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  4. ARM - Measurement - Cloud particle size distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    size distribution ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle size distribution The number of cloud particles present in any given volume of air within a specified size range, including liquid and ice. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  5. Midlatitude Continental Convective Clouds Experiment Science Objective

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Midlatitude Continental Convective Clouds Experiment Science Objective Despite improvements in computing power, current weather and climate models are unable to accurately reproduce the formation, growth, and decay of clouds and precipitation associated with storm systems. Not only is this due to a lack of data about precipitation, but also about the 3-dimensional environment of the surrounding clouds, winds, and moisture, and how that affects the transfer of energy between the sun and Earth. To

  6. Falcon series data report: 1987 LNG vapor barrier verification field trials

    SciTech Connect (OSTI)

    Brown, T.C.; Cederwall, R.T.; Chan, S.T.; Ermak, D.L.; Koopman, R.P.; Lamson, K.C.; McClure, J.W.; Morris, L.K.

    1990-06-01

    A series of five Liquefied Natural Gas Spills up to 66 m{sup 3} in volume were performed on water within a vapor barrier structure at Frenchman Flat on the Nevada Test Site as a part of a joint government/industry study. This data report presents a description of the tests, the test apparatus, the instrumentation, the meteorological conditions, and the data from the tests. 16 refs., 27 figs., 8 tabs.

  7. ARM - Field Campaign - Fall 1997 Cloud IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsFall 1997 Cloud IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Fall 1997 Cloud IOP 1997.09.15 - 1997.10.05 Lead Scientist : Gerald Mace For data sets, see below. Summary The primary objective of the Cloud IOP was to generate a multi-platform data set that can be used as validation for cloud property retrieval algorithms that are being implemented on the operational MMCR data stream.

  8. Ground-based Microwave Cloud Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microwave Cloud Tomography Experiment, SGP, May 15-June 15, 2009 Lead Scientist Dong Huang, BNL Co-Investigators Al Gasiewski, UC Boulder Maria Cadeddu, ANL Warren Wiscombe, BNL Radiation Processes Working Group March 30, 2009 multiple radiometers All good cloud radiation modelers should close their airplane window shades so as not to be corrupted by the spectacle of real 3D clouds. - Roger Davies In case you forget to do this, you see 3/30/2009 ARM RPWG 2 Effects of cloud structure on radiation

  9. RACORO continental boundary layer cloud investigations. Part...

    Office of Scientific and Technical Information (OSTI)

    RACORO continental boundary layer cloud investigations. Part I: Case study development and ensemble large-scale forcings Citation Details In-Document Search This content will ...

  10. What Makes Clouds Form, Grow and Die?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    were born and grew. Those formulas did not always reflect reality. With more advanced computers came the ability to explicitly simulate large-cloud systems instead of approximating...

  11. Mountain-induced Dynamics Influence Cloud Phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2010-2011 via coordinated projects targeting clouds, precipitation, and dynamics in the Park Range of Colorado. The National Science Foundation sponsored aircraft measurements as...

  12. Fragmentation in rotating isothermal protostellar clouds

    SciTech Connect (OSTI)

    Bodenheimer, P.; Tohline, J.E.; Black, D.C.

    1980-01-01

    Results of an extensive set of 3-D hydrodynamic calculations that have been performed to investigate the susceptibility of rotating clouds to gravitational fragmentation are presented. (GHT)

  13. Characterizing Arctic Mixed-phase Cloud Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    have two distinguished cloud base heights (CBHs) that can be defined by both ceilometer (black dots) and micropulse lidar (MPL; pink dots) measurements (Figure 1). For a...

  14. DOE Research and Development Accomplishments Tag Cloud

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Database Tag Cloud This tag cloud is a specific type of weighted list that provides a quick look at the content of the DOE R&D Accomplishments database. It can be easily browsed because terms are in alphabetical order. With this tag cloud, there is a direct correlation between font size and quantity. The more times a term appears in the bibliographic citations, the larger the font size. This tag cloud is also interactive. Clicking on a term will activate a search for that term. Search

  15. CHARACTERIZATION OF CLOUDS IN TITAN'S TROPICAL ATMOSPHERE

    SciTech Connect (OSTI)

    Griffith, Caitlin A.; Penteado, Paulo; Rodriguez, Sebastien; Baines, Kevin H.; Buratti, Bonnie; Sotin, Christophe; Clark, Roger; Nicholson, Phil; Jaumann, Ralf

    2009-09-10

    Images of Titan's clouds, possible over the past 10 years, indicate primarily discrete convective methane clouds near the south and north poles and an immense stratiform cloud, likely composed of ethane, around the north pole. Here we present spectral images from Cassini's Visual Mapping Infrared Spectrometer that reveal the increasing presence of clouds in Titan's tropical atmosphere. Radiative transfer analyses indicate similarities between summer polar and tropical methane clouds. Like their southern counterparts, tropical clouds consist of particles exceeding 5 {mu}m. They display discrete structures suggestive of convective cumuli. They prevail at a specific latitude band between 8 deg. - 20 deg. S, indicative of a circulation origin and the beginning of a circulation turnover. Yet, unlike the high latitude clouds that often reach 45 km altitude, these discrete tropical clouds, so far, remain capped to altitudes below 26 km. Such low convective clouds are consistent with the highly stable atmospheric conditions measured at the Huygens landing site. Their characteristics suggest that Titan's tropical atmosphere has a dry climate unlike the south polar atmosphere, and despite the numerous washes that carve the tropical landscape.

  16. ARM - Field Campaign - Midlatitude Continental Convective Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experiment (MC3E) Campaign Links Science Plan MC3E Website Field Campaign Report ARM Data Discovery Browse Data Related Campaigns Midlatitude Continental Convective Clouds...

  17. The LANL Cloud-Aerosol Model

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that incorporates two unique aspects in its formulation. First, the model employs a nonlinear solver that requires cloud-aerosol parameterizations be smooth or contain reasonable...

  18. An Analysis of Cloud Absorption During

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Cloud Absorption During ARESE II (Spring 2000) D. M. Powell, R. T. Marchand, and T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington Introduction...

  19. ARM - Evaluation Product - Cloud Classification VAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    properties includes cloud boundaries, thickness, phase, type, and precipitation information, and hence provides a useful tool for evaluation of model simulations and...

  20. Dynamics of Molecular Clouds: Observations, Simulations, and...

    Office of Scientific and Technical Information (OSTI)

    Simulations, and NIF Experiments Citation Details In-Document Search Title: Dynamics of Molecular Clouds: Observations, Simulations, and NIF Experiments Authors: Kane, J ...

  1. Petrology and geochemistry of Alto Peak, a vapor-cored hydrothermal system, Leyte Province, Philippines

    SciTech Connect (OSTI)

    Reyes, A.G.; Giggenbach, W.F.; Saleras, J.R.M.; Salonga, N.D.; Vergara, M.C.

    1993-10-01

    Based on detailed petrological information on secondary mineral assemblages and the composition of fluids trapped in inclusions and discharged from five wells, the Alto Peak geothermal field was found to represent a combined vapor and liquid-dominated system. A central core or chimney, with a diameter of about 1 km, a height of some 3 km and occupied by a high gas vapor (1.1 to 5.6 molal CO{sub 2}), is surrounded by an envelope of intermediate salinity water (7,000 mg/kg Cl) with temperatures between 250 and 350 C. The transition from purely vapor-dominated to liquid-dominated zones takes place via two-phase zones occupied by fluid mixtures of highly variable compositions. Much of the lower temperature, mature neutral pH Cl water is likely to have formed during an earlier stage in the evolution of the system. High temperatures of > 300 C, and associated alteration, are limited to wells AP-1D and the lower parts of AP-2D and are ascribed to re-heating by recent magmatic intrusions. The isotopic composition of the well discharges suggests that they contain some 40 to 50% of magmatic water. Alto Peak is considered a typical example of hydrothermal systems associated with many dormant volcanoes.

  2. Electron Cloud Effects in Accelerators

    SciTech Connect (OSTI)

    Furman, M.A.

    2012-11-30

    Abstract We present a brief summary of various aspects of the electron-cloud effect (ECE) in accelerators. For further details, the reader is encouraged to refer to the proceedings of many prior workshops, either dedicated to EC or with significant EC contents, including the entire ?ECLOUD? series [1?22]. In addition, the proceedings of the various flavors of Particle Accelerator Conferences [23] contain a large number of EC-related publications. The ICFA Beam Dynamics Newsletter series [24] contains one dedicated issue, and several occasional articles, on EC. An extensive reference database is the LHC website on EC [25].

  3. Intercomparison of model simulations of mixed-phase clouds observed...

    Office of Scientific and Technical Information (OSTI)

    Radiation Measurement (ARM) program's Mixed-Phase Arctic Cloud Experiment. The observed cloud occurred in a well-mixed boundary layer with a cloud top temperature of -15 C. The ...

  4. ARM - Field Campaign - Measuring Clouds at SGP with Stereo Photogramme...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the form of the Point Cloud of Cloud Points Product (PCCPP). The PCCPP will: provide context on life-cycle stage and cloud position for vertically pointing radars, lidars, and...

  5. Chemical vapor deposition of epitaxial silicon

    DOE Patents [OSTI]

    Berkman, Samuel (Florham Park, NJ)

    1984-01-01

    A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

  6. New Regenerative Cycle for Vapor Compression Refrigeration

    Office of Scientific and Technical Information (OSTI)

    SCIENTIFIC REPORT Title Page Project Title: New Regenerative Cycle for Vapor Compression Refrigeration DOE Award Number: DE-FG36-04GO14327 Document Title: Final Scientific Report Period Covered by Report: September 30, 2004 to September 30, 2005 Name and Address of Recipient Organization: Magnetic Development, Inc., 68 Winterhill Road, Madison, CT 06443, phone: 203-214-7247, fax: 203-421-7948, e-mail: mjb1000@aol.com Contact Information: Mark J. Bergander, Ph.D., P.E., Principal Investigator,

  7. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, Joel M.; Wylie, Allan H.

    1996-01-01

    A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

  8. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, J.M.; Wylie, A.H.

    1996-01-09

    A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

  9. Copper vapor laser acoustic thermometry system

    DOE Patents [OSTI]

    Galkowski, Joseph J. (Livermore, CA)

    1987-01-01

    A copper vapor laser (CVL) acoustic thermometry system is disclosed. The invention couples an acoustic pulse a predetermined distance into a laser tube by means of a transducer and an alumina rod such that an echo pulse is returned along the alumina rod to the point of entry. The time differential between the point of entry of the acoustic pulse into the laser tube and the exit of the echo pulse is related to the temperature at the predetermined distance within the laser tube. This information is processed and can provide an accurate indication of the average temperature within the laser tube.

  10. Method and apparatus for concentrating vapors for analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2012-06-05

    A pre-concentration device and a method are disclosed for concentrating gaseous vapors for analysis. Vapors sorbed and concentrated within the bed of the pre-concentration device are thermally desorbed, achieving at least partial separation of the vapor mixtures. The pre-concentration device is suitable, e.g., for pre-concentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable.

  11. Propane-induced biodegradation of vapor phase trichloroethylene (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Propane-induced biodegradation of vapor phase trichloroethylene Citation Details In-Document Search Title: Propane-induced biodegradation of vapor phase trichloroethylene Microbial degradation of trichloroethylene (TCE) has been demonstrated under aerobic conditions with propane. The primary objective of this research was to evaluate the feasibility of introducing a vapor phase form of TCE in the presence of propane to batch bioreactors containing a liquid phase

  12. Investigation of odd-order nonlinear susceptibilities in atomic vapors

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Investigation of odd-order nonlinear susceptibilities in atomic vapors Citation Details In-Document Search Title: Investigation of odd-order nonlinear susceptibilities in atomic vapors We theoretically deduce the macroscopic symmetry constraints for arbitrary odd-order nonlinear susceptibilities in homogeneous media including atomic vapors for the first time. After theoretically calculating the expressions

  13. Review of enhanced vapor diffusion in porous media

    SciTech Connect (OSTI)

    Webb, S.W.; Ho, C.K.

    1998-08-01

    Vapor diffusion in porous media in the presence of its own liquid has often been treated similar to gas diffusion. The gas diffusion rate in porous media is much lower than in free space due to the presence of the porous medium and any liquid present. However, enhanced vapor diffusion has also been postulated such that the diffusion rate may approach free-space values. Existing data and models for enhanced vapor diffusion, including those in TOUGH2, are reviewed in this paper.

  14. The Sensitivity of Radiative Fluxes to Parameterized Cloud Microphysic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    these fields include cloud altitude, cloud amount, liquid and ice content, particle size spectra, and radiative fluxes at the surface and the TOA. Comparisons with Atmospheric...

  15. Towards a Characterization of Arctic Mixed-Phase Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    manual classification of cloud phase. Using collocated cloud radar and depolarization lidar observations, it is shown that mixed-phase conditions have a high correlation with a...

  16. An Improved Cloud Classification Algorithm Based on the SGP CART...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the world. The millimeter wave cloud radar (MMCR) provides radar reflectivity and mean Doppler velocity profiles for most of clouds in the troposphere. Raman lidar provide not...

  17. ARM - Field Campaign - Azores: Clouds, Aerosol and Precipitation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaigns Azores: Above-Cloud Radiation Budget near Graciosa Island 2010.04.15, Miller, AMF Azores: Extension to Clouds, Aerosol and Precipitation in the Marine Boundary...

  18. Stratus Cloud Structure from MM-Radar Transects and Satellite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    modeling: * cloud-radiation interaction where correlations can trigger three-dimensional (3D) radiative transfer effects; and * dynamical cloud modeling where the goal is to...

  19. City of Red Cloud, Nebraska (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    Red Cloud, Nebraska (Utility Company) Jump to: navigation, search Name: Red Cloud Municipal Power Place: Nebraska Phone Number: 402-746-2215 Website: www.redcloudnebraska.comgover...

  20. Direct Numerical Simulations and Robust Predictions of Cloud...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud. Credit: Computational Science and Engineering Laboratory, ETH Zurich, Switzerland Direct Numerical Simulations and Robust Predictions of Cloud Cavitation Collapse PI Name:...

  1. ARM - Field Campaign - Marine ARM GPCI Investigation of Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsMarine ARM GPCI Investigation of Clouds (MAGIC) Campaign Links MAGIC Website ARM Data Discovery Browse Data Related Campaigns Marine ARM GPCI Investigation of Clouds...

  2. ARM - Field Campaign - Biogenic Aerosols - Effects on Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    relevant to DOE's goals in understanding the impact of clouds and aerosols on climate change. TWST contributes significantly to the body of data used for extracting cloud...

  3. Can Cloud Computing Address the Scientific Computing Requirements...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    achieve energy efficiency levels comparable to commercial cloud centers. Cloud is a business model and can be applied at DOE supercomputing centers. The progress of the...

  4. Assessing Cloud Spatial and Vertical Distribution with Infrared...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on assessing cloud spatial and vertical distribution with a recently developed infrared (IR) cloud analyzer, named Nephelo. The experiment took place at the ARM's central facility,...

  5. Summary of workshop session F on electron-cloud instabilities...

    Office of Scientific and Technical Information (OSTI)

    Conference: Summary of workshop session F on electron-cloud instabilities Citation Details In-Document Search Title: Summary of workshop session F on electron-cloud instabilities ...

  6. GFDL ARM Project Technical Report: Using ARM Observations to Evaluate Cloud and Convection Parameterizations & Cloud-Convection-Radiation Interactions in the GFDL Atmospheric General Circulation Model

    SciTech Connect (OSTI)

    V. Ramaswamy; L. J. Donner; J-C. Golaz; S. A. Klein

    2010-06-17

    This report briefly summarizes the progress made by ARM postdoctoral fellow, Yanluan Lin, at GFDL during the period from October 2008 to present. Several ARM datasets have been used for GFDL model evaluation, understanding, and improvement. This includes a new ice fall speed parameterization with riming impact and its test in GFDL AM3, evaluation of model cloud and radiation diurnal and seasonal variation using ARM CMBE data, model ice water content evaluation using ARM cirrus data, and coordination of the TWPICE global model intercomparison. The work illustrates the potential and importance of ARM data for GCM evaluation, understanding, and ultimately, improvement of GCM cloud and radiation parameterizations. Future work includes evaluation and improvement of the new dynamicsPDF cloud scheme and aerosol activation in the GFDL model.

  7. Mercury Vapor At Medicine Lake Area (Kooten, 1987) | Open Energy...

    Open Energy Info (EERE)

    Medicine Lake Area (Kooten, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Medicine Lake Area (Kooten, 1987) Exploration...

  8. Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et...

    Open Energy Info (EERE)

    Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et Al., 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey...

  9. Thermodynamic and transport properties of sodium liquid and vapor...

    Office of Scientific and Technical Information (OSTI)

    sodium liquid and vapor. Recently published Russian recommendations and results of equation of state calculations on thermophysical properties of sodium have been included in...

  10. Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) Exploration Activity Details Location...

  11. Mercury Vapor At Lualualei Valley Area (Thomas, 1986) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Exploration Activity Details Location...

  12. Mercury Vapor At Kawaihae Area (Thomas, 1986) | Open Energy Informatio...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Kawaihae Area (Thomas, 1986) Exploration Activity Details Location Kawaihae...

  13. Mercury Vapor At Mauna Loa Northeast Rift Area (Thomas, 1986...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mauna Loa Northeast Rift Area (Thomas, 1986) Exploration Activity Details...

  14. Mercury Vapor At Socorro Mountain Area (Kooten, 1987) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Socorro Mountain Area (Kooten, 1987) Exploration Activity Details Location...

  15. Ground Magnetics At Cove Fort Area - Vapor (Warpinski, Et Al...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Magnetics At Cove Fort Area - Vapor (Warpinski, Et Al., 2002) Exploration Activity Details...

  16. Rotary Vapor Compression Cycle Technology: A Pathway to Ultra...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heating and Refrigeration Rotary Vapor Compression Cycle Technology: A Pathway to Ultra-Efficient Air Conditioning, Heating and Refrigeration Lead Performer: Sandia ...

  17. Direct-Current Resistivity Survey At Cove Fort Area - Vapor ...

    Open Energy Info (EERE)

    2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Direct-Current Resistivity Survey At Cove Fort Area - Vapor (Warpinski, Et Al., 2002)...

  18. Mercury Vapor At Mccoy Geothermal Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Mccoy Geothermal Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mccoy Geothermal Area (DOE GTP) Exploration...

  19. Glenwood Springs Vapor Caves Pool & Spa Low Temperature Geothermal...

    Open Energy Info (EERE)

    & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Glenwood Springs Vapor Caves Pool & Spa Low Temperature Geothermal Facility Facility Glenwood Springs...

  20. IMPROVED MAGNUS' FORM OF SATURATION VAPOR PRESSURE Oleg A. Alduchov...

    Office of Scientific and Technical Information (OSTI)

    ... to convert between temperature and the saturation vapor pressure with minimal error. The requirements of simplicity and minimal error will eliminate many of the approximations. ...

  1. Indirect and Semi-Direct Aerosol Campaign: The Impact of Arctic Aerosols on Clouds

    SciTech Connect (OSTI)

    McFarquhar, Greg; Ghan, Steven J.; Verlinde, J.; Korolev, Alexei; Strapp, J. Walter; Schmid, Beat; Tomlinson, Jason M.; Wolde, Mengistu; Brooks, Sarah D.; Cziczo, Daniel J.; Dubey, Manvendra K.; Fan, Jiwen; Flynn, Connor J.; Gultepe, Ismail; Hubbe, John M.; Gilles, Mary K.; Laskin, Alexander; Lawson, Paul; Leaitch, W. R.; Liu, Peter S.; Liu, Xiaohong; Lubin, Dan; Mazzoleni, Claudio; Macdonald, A. M.; Moffet, Ryan C.; Morrison, H.; Ovchinnikov, Mikhail; Shupe, Matthew D.; Turner, David D.; Xie, Shaocheng; Zelenyuk, Alla; Bae, Kenny; Freer, Matthew; Glen, Andrew

    2011-02-01

    A comprehensive dataset of microphysical and radiative properties of aerosols and clouds in the arctic boundary layer in the vicinity of Barrow, Alaska was collected in April 2008 during the Indirect and Semi-Direct Aerosol Campaign (ISDAC) sponsored by the Department of Energy Atmospheric Radiation Measurement (ARM) and Atmospheric Science Programs. The primary aim of ISDAC was to examine indirect effects of aerosols on clouds that contain both liquid and ice water. The experiment utilized the ARM permanent observational facilities at the North Slope of Alaska (NSA) in Barrow. These include a cloud radar, a polarized micropulse lidar, and an atmospheric emitted radiance interferometer as well as instruments specially deployed for ISDAC measuring aerosol, ice fog, precipitation and spectral shortwave radiation. The National Research Council of Canada Convair-580 flew 27 sorties during ISDAC, collecting data using an unprecedented 42 cloud and aerosol instruments for more than 100 hours on 12 different days. Data were obtained above, below and within single-layer stratus on 8 April and 26 April 2008. These data enable a process-oriented understanding of how aerosols affect the microphysical and radiative properties of arctic clouds influenced by different surface conditions. Observations acquired on a heavily polluted day, 19 April 2008, are enhancing this understanding. Data acquired in cirrus on transit flights between Fairbanks and Barrow are improving our understanding of the performance of cloud probes in ice. Ultimately the ISDAC data will be used to improve the representation of cloud and aerosol processes in models covering a variety of spatial and temporal scales, and to determine the extent to which long-term surface-based measurements can provide retrievals of aerosols, clouds, precipitation and radiative heating in the Arctic.

  2. Vapor and gas sampling of the single-shell tank 241-S-101 using the in situ vapor sampling system

    SciTech Connect (OSTI)

    Lockrem, L.L.

    1997-08-05

    The Vapor Issue Resolution Program tasked the Vapor Team (VT) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-S-101. This document presents In Situ Vapor Sampling System (ISVS) data resulting from the June 6, 1996 sampling of SST 241-S-101. Analytical results will be presented in separate reports issued by the Pacific Northwest National Laboratory (PNNL) which supplied and analyzed the sample media.

  3. Vapor and gas sampling of Single-Shell Tank 241-A-101 using the Vapor Sampling System

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-11-01

    This document presents sampling data resulting from the June 8, 1995, sampling of SST 241-A-101 using the Vapor Sampling System.

  4. ARM - Midlatitude Continental Convective Clouds

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jensen, Mike; Bartholomew, Mary Jane; Genio, Anthony Del; Giangrande, Scott; Kollias, Pavlos

    2012-01-19

    Convective processes play a critical role in the Earth's energy balance through the redistribution of heat and moisture in the atmosphere and their link to the hydrological cycle. Accurate representation of convective processes in numerical models is vital towards improving current and future simulations of Earths climate system. Despite improvements in computing power, current operational weather and global climate models are unable to resolve the natural temporal and spatial scales important to convective processes and therefore must turn to parameterization schemes to represent these processes. In turn, parameterization schemes in cloud-resolving models need to be evaluated for their generality and application to a variety of atmospheric conditions. Data from field campaigns with appropriate forcing descriptors have been traditionally used by modelers for evaluating and improving parameterization schemes.

  5. ARM - Midlatitude Continental Convective Clouds

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jensen, Mike; Bartholomew, Mary Jane; Genio, Anthony Del; Giangrande, Scott; Kollias, Pavlos

    Convective processes play a critical role in the Earth's energy balance through the redistribution of heat and moisture in the atmosphere and their link to the hydrological cycle. Accurate representation of convective processes in numerical models is vital towards improving current and future simulations of Earths climate system. Despite improvements in computing power, current operational weather and global climate models are unable to resolve the natural temporal and spatial scales important to convective processes and therefore must turn to parameterization schemes to represent these processes. In turn, parameterization schemes in cloud-resolving models need to be evaluated for their generality and application to a variety of atmospheric conditions. Data from field campaigns with appropriate forcing descriptors have been traditionally used by modelers for evaluating and improving parameterization schemes.

  6. Modeling Incoherent Electron Cloud Effects

    SciTech Connect (OSTI)

    Vay, Jean-Luc; Benedetto, E.; Fischer, W.; Franchetti, G.; Ohmi, K.; Schulte, D.; Sonnad, K.; Tomas, R.; Vay, J.-L.; Zimmermann, F.; Rumolo, G.; Pivi, M.; Raubenheimer, T.

    2007-06-18

    Incoherent electron effects could seriously limit the beam lifetime in proton or ion storage rings, such as LHC, SPS, or RHIC, or blow up the vertical emittance of positron beams, e.g., at the B factories or in linear-collider damping rings. Different approaches to modeling these effects each have their own merits and drawbacks. We describe several simulation codes which simplify the descriptions of the beam-electron interaction and of the accelerator structure in various different ways, and present results for a toy model of the SPS. In addition, we present evidence that for positron beams the interplay of incoherent electron-cloud effects and synchrotron radiation can lead to a significant increase in vertical equilibrium emittance. The magnitude of a few incoherent e+e- scattering processes is also estimated. Options for future code development are reviewed.

  7. ARM - PI Product - Large Scale Ice Water Path and 3-D Ice Water Content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsLarge Scale Ice Water Path and 3-D Ice Water Content ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Large Scale Ice Water Path and 3-D Ice Water Content Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM

  8. Photolysis rates in correlated overlapping cloud fields: Cloud-J 7.3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Prather, M. J.

    2015-05-27

    A new approach for modeling photolysis rates (J values) in atmospheres with fractional cloud cover has been developed and implemented as Cloud-J – a multi-scattering eight-stream radiative transfer model for solar radiation based on Fast-J. Using observed statistics for the vertical correlation of cloud layers, Cloud-J 7.3 provides a practical and accurate method for modeling atmospheric chemistry. The combination of the new maximum-correlated cloud groups with the integration over all cloud combinations represented by four quadrature atmospheres produces mean J values in an atmospheric column with root-mean-square errors of 4% or less compared with 10–20% errors using simpler approximations. Cloud-Jmore » is practical for chemistry-climate models, requiring only an average of 2.8 Fast-J calls per atmosphere, vs. hundreds of calls with the correlated cloud groups, or 1 call with the simplest cloud approximations. Another improvement in modeling J values, the treatment of volatile organic compounds with pressure-dependent cross sections is also incorporated into Cloud-J.« less

  9. Photolysis rates in correlated overlapping cloud fields: Cloud-J 7.3c

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Prather, M. J.

    2015-08-14

    A new approach for modeling photolysis rates (J values) in atmospheres with fractional cloud cover has been developed and is implemented as Cloud-J – a multi-scattering eight-stream radiative transfer model for solar radiation based on Fast-J. Using observations of the vertical correlation of cloud layers, Cloud-J 7.3c provides a practical and accurate method for modeling atmospheric chemistry. The combination of the new maximum-correlated cloud groups with the integration over all cloud combinations by four quadrature atmospheres produces mean J values in an atmospheric column with root mean square (rms) errors of 4 % or less compared with 10–20 % errorsmore » using simpler approximations. Cloud-J is practical for chemistry–climate models, requiring only an average of 2.8 Fast-J calls per atmosphere vs. hundreds of calls with the correlated cloud groups, or 1 call with the simplest cloud approximations. Another improvement in modeling J values, the treatment of volatile organic compounds with pressure-dependent cross sections, is also incorporated into Cloud-J.« less

  10. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid Water and Precipitable Water Vapor (PI: D. Turner) WACR-ARSCL - Cloud boundaries, radar reflectivity, doppler velocities, and spectral width from 95 GHz W-Band ARM Cloud...

  11. Evaluation of high-level clouds in cloud resolving model simulations with ARM and KWAJEX observations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zheng; Muhlbauer, Andreas; Ackerman, Thomas

    2015-11-05

    In this paper, we evaluate high-level clouds in a cloud resolving model during two convective cases, ARM9707 and KWAJEX. The simulated joint histograms of cloud occurrence and radar reflectivity compare well with cloud radar and satellite observations when using a two-moment microphysics scheme. However, simulations performed with a single moment microphysical scheme exhibit low biases of approximately 20 dB. During convective events, two-moment microphysical overestimate the amount of high-level cloud and one-moment microphysics precipitate too readily and underestimate the amount and height of high-level cloud. For ARM9707, persistent large positive biases in high-level cloud are found, which are not sensitivemore » to changes in ice particle fall velocity and ice nuclei number concentration in the two-moment microphysics. These biases are caused by biases in large-scale forcing and maintained by the periodic lateral boundary conditions. The combined effects include significant biases in high-level cloud amount, radiation, and high sensitivity of cloud amount to nudging time scale in both convective cases. The high sensitivity of high-level cloud amount to the thermodynamic nudging time scale suggests that thermodynamic nudging can be a powerful ‘‘tuning’’ parameter for the simulated cloud and radiation but should be applied with caution. The role of the periodic lateral boundary conditions in reinforcing the biases in cloud and radiation suggests that reducing the uncertainty in the large-scale forcing in high levels is important for similar convective cases and has far reaching implications for simulating high-level clouds in super-parameterized global climate models such as the multiscale modeling framework.« less

  12. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  13. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, A.

    1989-11-21

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

  14. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, Ahmet (Atlanta, GA)

    1989-01-01

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula (I) ##STR1## where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula I is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula I and a heat decomposable tellurium compound under nonoxidizing conditions.

  15. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  16. Method and apparatus for conducting variable thickness vapor deposition

    DOE Patents [OSTI]

    Nesslage, G.V.

    1984-08-03

    A method of vapor depositing metal on a substrate in variable thickness comprises conducting the deposition continuously without interruption to avoid formation of grain boundaries. To achieve reduced deposition in specific regions a thin wire or ribbon blocking body is placed between source and substrate to partially block vapors from depositing in the region immediately below.

  17. Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

    2003-06-03

    A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

  18. Hybrid Vapor Compression Adsorption System: Thermal Storage Using Hybrid Vapor Compression Adsorption System

    SciTech Connect (OSTI)

    2012-01-04

    HEATS Project: UTRC is developing a new climate-control system for EVs that uses a hybrid vapor compression adsorption system with thermal energy storage. The targeted, closed system will use energy during the battery-charging step to recharge the thermal storage, and it will use minimal power to provide cooling or heating to the cabin during a drive cycle. The team will use a unique approach of absorbing a refrigerant on a metal salt, which will create a lightweight, high-energy-density refrigerant. This unique working pair can operate indefinitely as a traditional vapor compression heat pump using electrical energy, if desired. The project will deliver a hot-and-cold battery that provides comfort to the passengers using minimal power, substantially extending the driving range of EVs.

  19. Cloud radar Doppler spectra in drizzling stratiform clouds: 1. Forward modeling and remote sensing applications

    SciTech Connect (OSTI)

    Kollias, P.; Luke, E.; Rmillard, J.; Szyrmer, W.

    2011-07-02

    Several aspects of spectral broadening and drizzle growth in shallow liquid clouds remain not well understood. Detailed, cloud-scale observations of microphysics and dynamics are essential to guide and evaluate corresponding modeling efforts. Profiling, millimeter-wavelength (cloud) radars can provide such observations. In particular, the first three moments of the recorded cloud radar Doppler spectra, the radar reflectivity, mean Doppler velocity, and spectrum width, are often used to retrieve cloud microphysical and dynamical properties. Such retrievals are subject to errors introduced by the assumptions made in the inversion process. Here, we introduce two additional morphological parameters of the radar Doppler spectrum, the skewness and kurtosis, in an effort to reduce the retrieval uncertainties. A forward model that emulates observed radar Doppler spectra is constructed and used to investigate these relationships. General, analytical relationships that relate the five radar observables to cloud and drizzle microphysical parameters and cloud turbulence are presented. The relationships are valid for cloud-only, cloud mixed with drizzle, and drizzle-only particles in the radar sampling volume and provide a seamless link between observations and cloud microphysics and dynamics. The sensitivity of the five observed parameters to the radar operational parameters such as signal-to-noise ratio and Doppler spectra velocity resolution are presented. The predicted values of the five observed radar parameters agree well with the output of the forward model. The novel use of the skewness of the radar Doppler spectrum as an early qualitative predictor of drizzle onset in clouds is introduced. It is found that skewness is a parameter very sensitive to early drizzle generation. In addition, the significance of the five parameters of the cloud radar Doppler spectrum for constraining drizzle microphysical retrievals is discussed.

  20. Evaluation of Cloud-Resolving Model Intercomparison Simulations Using TWP-ICE Observations: Precipitation and Cloud Structure

    SciTech Connect (OSTI)

    Varble, Adam C.; Fridlind, Ann; Zipser, Ed; Ackerman, Andrew; Chaboureau, Jean-Pierre; Fan, Jiwen; Hill, Adrian; McFarlane, Sally A.; Pinty, Jean-Pierre; Shipway, Ben

    2011-06-24

    The Tropical Warm Pool - International Cloud Experiment (TWP-ICE) provided high quality model forcing and observational datasets through which detailed model and observational intercomparisons could be performed. In this first of a two part study, precipitation and cloud structures within nine cloud-resolving model simulations are compared with scanning radar reflectivity and satellite infrared brightness temperature observations during an active monsoon period from 19 to 25 January 2006. Most simulations slightly overestimate volumetric convective rainfall. Overestimation of simulated convective area by 50% or more in several simulations is somewhat offset by underestimation of mean convective rain rates. Stratiform volumetric rainfall is underestimated by 13% to 53% despite overestimation of stratiform area by up to 65% because stratiform rain rates in every simulation are much lower than observed. Although simulations match the peaked convective radar reflectivity distribution at low levels, they do not reproduce the peaked distributions observed above the melting level. Simulated radar reflectivity aloft in convective regions is too high in most simulations. 29 In stratiform regions, there is a large spread in model results with none resembling 30 observed distributions. Above the melting level, observed radar reflectivity decreases 31 more gradually with height than simulated radar reflectivity. A few simulations produce 32 unrealistically uniform and cold 10.8-?m infrared brightness temperatures, but several 33 simulations produce distributions close to observed. Assumed ice particle size 34 distributions appear to play a larger role than ice water contents in producing incorrect 35 simulated radar reflectivity distributions aloft despite substantial differences in mean 36 graupel and snow water contents across models. 37

  1. HPC CLOUD APPLIED TO LATTICE OPTIMIZATION

    SciTech Connect (OSTI)

    Sun, Changchun; Nishimura, Hiroshi; James, Susan; Song, Kai; Muriki, Krishna; Qin, Yong

    2011-03-18

    As Cloud services gain in popularity for enterprise use, vendors are now turning their focus towards providing cloud services suitable for scientific computing. Recently, Amazon Elastic Compute Cloud (EC2) introduced the new Cluster Compute Instances (CCI), a new instance type specifically designed for High Performance Computing (HPC) applications. At Berkeley Lab, the physicists at the Advanced Light Source (ALS) have been running Lattice Optimization on a local cluster, but the queue wait time and the flexibility to request compute resources when needed are not ideal for rapid development work. To explore alternatives, for the first time we investigate running the Lattice Optimization application on Amazon's new CCI to demonstrate the feasibility and trade-offs of using public cloud services for science.

  2. QER- Comment of Cloud Peak Energy Inc

    Broader source: Energy.gov [DOE]

    Dear Ms Pickett Please find attached comments from Cloud Peak Energy as input to the Department of Energy’s Quadrennial Energy Review. If possible I would appreciate a confirmation that this email has been received Thank you.

  3. Building a private cloud with Open Nebula

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Short Ryan Glenn Ross Nordeen Mentors: Andree Jacobson ISTI-OFF David Kennel DCS-1 LA-UR 10-05197 Why use Virtualized Cloud Computing for HPC? * Support Legacy Software Stacks *...

  4. Evaluating the MMF Using CloudSat

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its cloud simulations simulations Borrowed from Dave Randall, CSU The big picture The big picture ... ... . . Data ARM A-Train, MISR etc. MMF 4 km runs (CAM) Compare Run CRM...

  5. ARM - Field Campaign - Midlatitude Continental Convective Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Midlatitude Continental Convective Clouds Experiment (MC3E): Multi-Frequency...

  6. ARM - Field Campaign - Boundary Layer Cloud IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsBoundary Layer Cloud IOP Campaign Links Campaign Images ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at...

  7. ARM - Field Campaign - Arctic Cloud Infrared Imaging

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Arctic Cloud Infrared Imaging 2012.07.16 - 2014.07.31 Lead Scientist : Joseph Shaw...

  8. ARM Cloud Retrieval Ensemble Data Set (ACRED)

    SciTech Connect (OSTI)

    Zhao, C; Xie, S; Klein, SA; McCoy, R; Comstock, JM; Delanoë, J; Deng, M; Dunn, M; Hogan, RJ; Jensen, MP; Mace, GG; McFarlane, SA; O’Connor, EJ; Protat, A; Shupe, MD; Turner, D; Wang, Z

    2011-09-12

    This document describes a new Atmospheric Radiation Measurement (ARM) data set, the ARM Cloud Retrieval Ensemble Data Set (ACRED), which is created by assembling nine existing ground-based cloud retrievals of ARM measurements from different cloud retrieval algorithms. The current version of ACRED includes an hourly average of nine ground-based retrievals with vertical resolution of 45 m for 512 layers. The techniques used for the nine cloud retrievals are briefly described in this document. This document also outlines the ACRED data availability, variables, and the nine retrieval products. Technical details about the generation of ACRED, such as the methods used for time average and vertical re-grid, are also provided.

  9. Retrievals of Cloud Fraction and Cloud Albedo from Surface-based Shortwave Radiation Measurements: A Comparison of 16 Year Measurements

    SciTech Connect (OSTI)

    Xie, Yu; Liu, Yangang; Long, Charles N.; Min, Qilong

    2014-07-27

    Ground-based radiation measurements have been widely conducted to gain information on clouds and the surface radiation budget; here several different techniques for retrieving cloud fraction (Long2006, Min2008 and XL2013) and cloud albedo (Min2008, Liu2011 and XL2013) from ground-based shortwave broadband and spectral radiation measurements are examined, and sixteen years of retrievals collected at the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site are compared. The comparison shows overall good agreement between the retrievals of both cloud fraction and cloud albedo, with noted differences however. The Long2006 and Min2008 cloud fractions are greater on average than the XL2013 values. Compared to Min2008 and Liu2011, the XL2013 retrieval of cloud albedo tends to be greater for thin clouds but smaller for thick clouds, with the differences decreasing with increasing cloud fraction. Further analysis reveals that the approaches that retrieve cloud fraction and cloud albedo separately may suffer from mutual contamination of errors in retrieved cloud fraction and cloud albedo. Potential influences of cloud absorption, land-surface albedo, cloud structure, and measurement instruments are explored.

  10. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    2008-01-15

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  11. Electron-Cloud Build-Up: Summary

    SciTech Connect (OSTI)

    Furman, M.A.

    2007-06-18

    I present a summary of topics relevant to the electron-cloud build-up and dissipation that were presented at the International Workshop on Electron-Cloud Effects 'ECLOUD 07' (Daegu, S. Korea, April 9-12, 2007). This summary is not meant to be a comprehensive review of the talks. Rather, I focus on those developments that I found, in my personal opinion, especially interesting. The contributions, all excellent, are posted in http://chep.knu.ac.kr/ecloud07/.

  12. Ignition of Aluminum Particles and Clouds

    SciTech Connect (OSTI)

    Kuhl, A L; Boiko, V M

    2010-04-07

    Here we review experimental data and models of the ignition of aluminum (Al) particles and clouds in explosion fields. The review considers: (i) ignition temperatures measured for single Al particles in torch experiments; (ii) thermal explosion models of the ignition of single Al particles; and (iii) the unsteady ignition Al particles clouds in reflected shock environments. These are used to develop an empirical ignition model appropriate for numerical simulations of Al particle combustion in shock dispersed fuel explosions.

  13. Posters Sensitivity of Cirrus Cloud Radiative

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Posters Sensitivity of Cirrus Cloud Radiative Properties to Ice Crystal Size and Shape in General Circulation Model Simulations D. L. Mitchell Desert Research Institute Reno, Nevada J. E. Kristjánsson Department of Geophysics University of Oslo, Norway M. J. Newman Los Alamos National Laboratory Los Alamos, New Mexico Introduction Recent research (e.g., Mitchell and Arnott 1994) has shown that the radiative properties of cirrus clouds (i.e., optical depth, albedo, emissivity) depend on the

  14. ARM Cloud Properties Working Group: Meeting Logistics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Properties WG Breakout Session 2008 ARM Science Team Meeting Mar. 10, 2008, Norfolk, VA Monday March 10, 2008 1500 to 1515: R. Hogan - A Proposal for ARM support of Cloudnet Activities 1515 to 1530: M. Jensen - Cloud Properties Value- Added Product Development 1530 to 1545: C. Long - Instrument Group Report 1545 to 1600: S. Matrosov - WSR-88D data for ARM science 1600 to 1615: Y. Zhao - A BimodalParticle Distribution Assumption in Cirrus: Comparison of retrieval results with in situ

  15. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  16. Simulating Arctic mixed-phase clouds: Sensitivity to environmental

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions and cloud microphysics processes Simulating Arctic mixed-phase clouds: Sensitivity to environmental conditions and cloud microphysics processes Sednev, Igor Lawrence Berkeley National Laboratory Menon, Surabi Lawrence Berkeley National Laboratory McFarquhar, Greg University of Illinois Category: Field Campaigns The importance of Arctic mixed-phase clouds on radiation and the Arctic climate are evaluated using the NASA GISS single column model (SCM) and cloud microphysics and radar

  17. ARM - Publications: Science Team Meeting Documents: Day and Night cloud

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fraction - Cloud Inter-Compariosn IOP results Day and Night cloud fraction - Cloud Inter-Compariosn IOP results Genkova, Iliana University of Illinois-Champaign Long, Chuck Pacific Northwest National Laboratory Turner, David Pacific Northwest National Laboratory We present results from the CIC IOP from March-may, 2003. Day time and night time cloud fraction retrieval algorithms have been presented and intercompared. Amount of low, middle and high cloud have been estimated and compared to

  18. Icy Cirrus Clouds to Be Studied This Spring

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Icy Cirrus Clouds to Be Studied This Spring Mid-latitude cirrus clouds, which are composed solely of ice crystals, will be the focus of an intensive operational period (IOP) in April and May 2004 at the ARM Climate Research Facility (ACRF) SGP site. Researchers will be probing the clouds with aircraft-based instruments to gather detailed information about the clouds' physical characteristics. To make measurements in cirrus clouds, which generally form in the atmosphere at and above 20,000 feet

  19. Radiative Importance of ThinŽ Liquid Water Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    underpinning of the Atmospheric Radiation Measurement (ARM) Program is largely ... Ackerman, T. P., and G. M. Stokes (2003): The Atmospheric Radiation Measurement Program. ...

  20. Star formation relations in nearby molecular clouds

    SciTech Connect (OSTI)

    Evans, Neal J. II; Heiderman, Amanda; Vutisalchavakul, Nalin

    2014-02-20

    We test some ideas for star formation relations against data on local molecular clouds. On a cloud by cloud basis, the relation between the surface density of star formation rate and surface density of gas divided by a free-fall time, calculated from the mean cloud density, shows no significant correlation. If a crossing time is substituted for the free-fall time, there is even less correlation. Within a cloud, the star formation rate volume and surface densities increase rapidly with the corresponding gas densities, faster than predicted by models using the free-fall time defined from the local density. A model in which the star formation rate depends linearly on the mass of gas above a visual extinction of 8 mag describes the data on these clouds, with very low dispersion. The data on regions of very massive star formation, with improved star formation rates based on free-free emission from ionized gas, also agree with this linear relation.

  1. QUANTITATIVELY ASSESSING THE ROLE OF CLOUDS IN THE TRANSMISSION SPECTRUM OF GJ 1214b

    SciTech Connect (OSTI)

    Morley, Caroline V.; Fortney, Jonathan J.; Kempton, Eliza M.-R.; Marley, Mark S.; Zahnle, Kevin; Vissher, Channon

    2013-09-20

    Recent observations of the super-Earth GJ 1214b show that it has a relatively featureless transmission spectrum. One suggestion is that these observations indicate that the planet's atmosphere is vertically compact, perhaps due to a water-rich composition that yields a large mean molecular weight. Another suggestion is that the atmosphere is hydrogen/helium-rich with clouds that obscure predicted absorption features. Previous models that incorporate clouds have included their effect without a strong physical motivation for their existence. Here, we present model atmospheres of GJ 1214b that include physically motivated clouds of two types. We model the clouds that are present in chemical equilibrium, as has been suggested to occur on brown dwarfs, which include KCl and ZnS for this planet. We also include clouds that form as a result of photochemistry, forming a hydrocarbon haze layer. We use a photochemical kinetics model to understand the vertical distribution and available mass of haze-forming molecules. We model both solar and enhanced-metallicity cloudy models and determine the cloud properties necessary to match observations. In enhanced-metallicity atmospheres, we find that the equilibrium clouds can match the observations of GJ 1214b if they are lofted high into the atmosphere and have a low sedimentation efficiency (f{sub sed} = 0.1). We find that models with a variety of hydrocarbon haze properties can match the observations. Particle sizes from 0.01 to 0.25 ?m can match the transmission spectrum with haze-forming efficiencies as low as 1%-5%.

  2. Chemical analyses and preliminary interpretation of waters collected...

    Open Energy Info (EERE)

    system appears to be a hot water type. The surface expression of fumarole and acid sulfate pools and shallow steam wells gives a false indication of an extensive vapor...

  3. ARM - Lesson Plans: Making Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    about 2 centimeters of water in the bottom of the jar. Hold the black paper upright or prop it up against some books behind the jar. Turn the lid of the jar upside down and fill...

  4. Enhanced Attenuation Technologies: Passive Soil Vapor Extraction

    SciTech Connect (OSTI)

    Vangelas, K.; Looney, B.; Kamath, R.; Adamson, D.; Newell, C.

    2010-03-15

    Passive soil vapor extraction (PSVE) is an enhanced attenuation (EA) approach that removes volatile contaminants from soil. The extraction is driven by natural pressure gradients between the subsurface and atmosphere (Barometric Pumping), or by renewable sources of energy such as wind or solar power (Assisted PSVE). The technology is applicable for remediating sites with low levels of contamination and for transitioning sites from active source technologies such as active soil vapor extraction (ASVE) to natural attenuation. PSVE systems are simple to design and operate and are more cost effective than active systems in many scenarios. Thus, PSVE is often appropriate as an interim-remedial or polishing strategy. Over the past decade, PSVE has been demonstrated in the U.S. and in Europe. These demonstrations provide practical information to assist in selecting, designing and implementing the technology. These demonstrations indicate that the technology can be effective in achieving remedial objectives in a timely fashion. The keys to success include: (1) Application at sites where the residual source quantities, and associated fluxes to groundwater, are relatively low; (2) Selection of the appropriate passive energy source - barometric pumping in cases with a deep vadose zone and barrier (e.g., clay) layers that separate the subsurface from the atmosphere and renewable energy assisted PSVE in other settings and where higher flow rates are required. (3) Provision of sufficient access to the contaminated vadose zones through the spacing and number of extraction wells. This PSVE technology report provides a summary of the relevant technical background, real-world case study performance, key design and cost considerations, and a scenario-based cost evaluation. The key design and cost considerations are organized into a flowchart that dovetails with the Enhanced Attenuation: Chlorinated Organics Guidance of the Interstate Technology and Regulatory Council (ITRC). The PSVE flowchart provides a structured process to determine if the technology is, or is not, reasonable and defensible for a particular site. The central basis for that decision is the expected performance of PSVE under the site specific conditions. Will PSVE have sufficient mass removal rates to reduce the release, or flux, of contamination into the underlying groundwater so that the site can meet it overall remedial objectives? The summary technical information, case study experiences, and structured decision process provided in this 'user guide' should assist environmental decision-makers, regulators, and engineers in selecting and successfully implementing PSVE at appropriate sites.

  5. Monitoring PVD metal vapors using laser absorption spectroscopy

    SciTech Connect (OSTI)

    Braun, D.G.; Anklam, T.M.; Berzins, L.V.; Hagans, K.G.

    1994-04-01

    Laser absorption spectroscopy (LAS) has been used by the Atomic Vapor Laser Isotope Separation (AVLIS) program for over 10 years to monitor the co-vaporization of uranium and iron in its separators. During that time, LAS has proven to be an accurate and reliable method to monitor both the density and composition of the vapor. It has distinct advantages over other rate monitors, in that it is completely non-obtrusive to the vaporization process and its accuracy is unaffected by the duration of the run. Additionally, the LAS diagnostic has been incorporated into a very successful process control system. LAS requires only a line of sight through the vacuum chamber, as all hardware is external to the vessel. The laser is swept in frequency through an absorption line of interest. In the process a baseline is established, and the line integrated density is determined from the absorption profile. The measurement requires no hardware calibration. Through a proper choice of the atomic transition, a wide range of elements and densities have been monitored (e.g. nickel, iron, cerium and gadolinium). A great deal of information about the vapor plume can be obtained from the measured absorption profiles. By monitoring different species at the same location, the composition of the vapor is measured in real time. By measuring the same density at different locations, the spatial profile of the vapor plume is determined. The shape of the absorption profile is used to obtain the flow speed of the vapor. Finally, all of the above information is used evaluate the total vaporization rate.

  6. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Ourmore » findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.« less

  7. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    SciTech Connect (OSTI)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Our findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.

  8. Optimization of Xenon Difluoride Vapor Delivery

    SciTech Connect (OSTI)

    Sweeney, Joseph; Marganski, Paul; Kaim, Robert; Wodjenski, Mike; Gregg, John; Yedave, Sharad; Sergi, Steve; Bishop, Steve; Eldridge, David; Zou Peng [ATMI, Inc., Danbury, Connecticut 06810 (United States)

    2008-11-03

    Xenon difluoride (XeF{sub 2}) has been shown to provide many process benefits when used as a daily maintenance recipe for ion implant. Regularly flowing XeF{sub 2} into the ion source cleans the deposits generated by ion source operation. As a result, significant increases in productivity have been demonstrated. However, XeF{sub 2} is a toxic oxidizer that must be handled appropriately. Furthermore, it is a low vapor pressure solid under standard conditions ({approx}4.5 torr at 25 deg. C). These aspects present unique challenges for designing a package for delivering the chemistry to an ion implanter. To address these challenges, ATMI designed a high-performance, re-usable cylinder for dispensing XeF{sub 2} in an efficient and reliable manner. Data are presented showing specific attributes of the cylinder, such as the importance of internal heat transfer media and the cylinder valve size. The impact of mass flow controller (MFC) selection and ion source tube design on the flow rate of XeF{sub 2} are also discussed. Finally, cylinder release rate data are provided.

  9. Catalytic Reactor For Oxidizing Mercury Vapor

    DOE Patents [OSTI]

    Helfritch, Dennis J.

    1998-07-28

    A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

  10. The Atomic Vapor Laser Isotope Separation Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management`s position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  11. Controlling the vapor pressure of a mercury lamp

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

    1988-01-01

    The invention described herein discloses a method and apparatus for controlling the Hg vapor pressure within a lamp. This is done by establishing and controlling two temperature zones within the lamp. One zone is colder than the other zone. The first zone is called the cold spot. By controlling the temperature of the cold spot, the Hg vapor pressure within the lamp is controlled. Likewise, by controlling the Hg vapor pressure of the lamp, the intensity and linewidth of the radiation emitted from the lamp is controlled.

  12. Controlling the vapor pressure of a mercury lamp

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1988-05-24

    The invention described herein discloses a method and apparatus for controlling the Hg vapor pressure within a lamp. This is done by establishing and controlling two temperature zones within the lamp. One zone is colder than the other zone. The first zone is called the cold spot. By controlling the temperature of the cold spot, the Hg vapor pressure within the lamp is controlled. Likewise, by controlling the Hg vapor pressure of the lamp, the intensity and linewidth of the radiation emitted from the lamp is controlled. 2 figs.

  13. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    retrieval issues. For the algorithm development, database with reliable temperature and water vapor profiles and cloudy assessment is important. Accurate cloud cover assessment...

  14. delamere_swqme_arm08_poster.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cases with a range of precipitable water vapor (PWV) and solar zenith angles. The TSI provides cloud fraction at sonde launch time. RSS Data Processing There are several...

  15. Sandia Energy - ARM Raman Lidar Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the analysis deriving water vapor flux observations using coincident Raman and Doppler lidar measurements and characterizing entrainment in cumulus clouds using Raman...

  16. X:\\ARM_19~1\\P259-271.WPD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    surface Use the above results to develop and validate General Circulation Models (GCM) treatment of clouds, water vapor, radiation fluxes, and the surface heat budget over the...

  17. 8.03 ARM Research Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Way of Looking at Clouds * Climate Controversy Resolved * Water Vapor's Role in Models * International Experiment Reduces Uncertainties CONTENTS CONTENTS New Way of Looking at...

  18. ARM_AVP_SHIS_Taylor_Turner_pdf.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiances for Radiative Transfer Temp & Water Vapor Retrievals Cloud Radiative Prop. Surface Emissivity & T Trace Gas Retrievals Calibration Validation CO 2 CO...

  19. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the formation and dissipation of cirrus clouds. To address this problem, we develop a simple 1-d variational method for directly assimilating satellite observed "water vapor"...

  20. Posters Climate Zones for Maritime Clouds A. B. White and D....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    power (15-m resolution) is analyzed to detect cloud layers using a specified cloud detection limit. In addition to measurements of cloud base, the ceilometer can also provide...

  1. Direct synthesis of large area graphene on insulating substrate by gallium vapor-assisted chemical vapor deposition

    SciTech Connect (OSTI)

    Murakami, Katsuhisa Hiyama, Takaki; Kuwajima, Tomoya; Fujita, Jun-ichi; Tanaka, Shunsuke; Hirukawa, Ayaka; Kano, Emi; Takeguchi, Masaki

    2015-03-02

    A single layer of graphene with dimensions of 20?mm??20?mm was grown directly on an insulating substrate by chemical vapor deposition using Ga vapor catalysts. The graphene layer showed highly homogeneous crystal quality over a large area on the insulating substrate. The crystal quality of the graphene was measured by Raman spectroscopy and was found to improve with increasing Ga vapor density on the reaction area. High-resolution transmission electron microscopy observations showed that the synthesized graphene had a perfect atomic-scale crystal structure within its grains, which ranged in size from 50?nm to 200?nm.

  2. A New Two-Moment Bulk Stratiform Cloud Microphysics Scheme in the Community Atmosphere Model, Version 3 (CAM3). Part II: Single-Column and Global Results

    SciTech Connect (OSTI)

    Gettelman, A.; Morrison, H.; Ghan, Steven J.

    2008-08-11

    The global performance of a new 2-moment cloud microphysics scheme for a General Circulation Model (GCM) is presented and evaluated relative to observations. The scheme produces reasonable representations of cloud particle size and number concentration when compared to observations, and represents expected and observed spatial variations in cloud microphysical quantities. The scheme has smaller particles and higher number concentrations over land than the standard bulk microphysics in the GCM, and is able to balance the radiation budget of the planet with 60% the liquid water of the standard scheme, in better agreement with observations. The new scheme treats both the mixing ratio and number concentration of rain and snow, and is therefore able to differentiate the two key regimes, consisting of drizzle in shallow warm clouds and larger rain drops in deeper cloud systems. The modeled rain and snow size distributions are consistent with observations.

  3. Systems and methods for generation of hydrogen peroxide vapor

    DOE Patents [OSTI]

    Love, Adam H; Eckels, Joel Del; Vu, Alexander K; Alcaraz, Armando; Reynolds, John G

    2014-12-02

    A system according to one embodiment includes a moisture trap for drying air; at least one of a first container and a second container; and a mechanism for at least one of: bubbling dried air from the moisture trap through a hydrogen peroxide solution in the first container for producing a hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above a hydrogen peroxide solution in the second container for producing a hydrogen peroxide vapor. A method according one embodiment includes at least one of bubbling dried air through a hydrogen peroxide solution in a container for producing a first hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above the hydrogen peroxide solution in a container for producing a second hydrogen peroxide vapor. Additional systems and methods are also presented.

  4. Vaporization, dispersion, and radiant fluxes from LPG spills. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    Both burning and non-burning spills of LPG (primarily propane) were studied. Vaporization rates for propane spills on soil, concrete, insulating concrete, asphalt, sod, wood, and polymer foams were measured. Thermal conductivity, heat transfer coefficients, and steady state vaporization rates were determined. Vapor concentrations were measured downwind of open propane pools 25, 100, 400, and 1600 ft/sup 2/ in area. A Gaussian dispersion model modified for area sources provided a good correlation of measured concentrations. Emitted and incident radiant fluxes from propane fires were measured. Simplified flame radiation models were adequate for predicting radiant fluxes; the maximum effective flux emitted at the flame surface was about 50,000 Btu/h-ft/sup 2/. A few tests in which propane was sprayed into the air showed that at moderately high spray rates all the propane flashed to vapor or atomized; no liquid collected on the ground.

  5. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    SciTech Connect (OSTI)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-11-06

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice number is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.

  6. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-11-06

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice numbermore » is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 μm for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.« less

  7. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    SciTech Connect (OSTI)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-12-01

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice number is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.

  8. Mechanistic aspects of vapor phase lubrication of silicon. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Mechanistic aspects of vapor phase lubrication of silicon. Citation Details In-Document Search Title: Mechanistic aspects of vapor phase lubrication of silicon. No abstract prepared. Authors: Dugger, Michael Thomas ; Dirk, Shawn M. ; Ohlhausen, James Anthony Publication Date: 2010-10-01 OSTI Identifier: 1028381 Report Number(s): SAND2010-7362C TRN: US201122%%249 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for

  9. PROJECT PROFILE: Stable Perovskite Solar Cells via Chemical Vapor

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deposition | Department of Energy Stable Perovskite Solar Cells via Chemical Vapor Deposition PROJECT PROFILE: Stable Perovskite Solar Cells via Chemical Vapor Deposition Funding Opportunity: SuNLaMP SunShot Subprogram: Photovoltaics Location: National Renewable Energy Laboratory, Golden, CO SunShot Award Amount: $125,000 This project is focused on novel approaches to remove risk related to the development of hybrid perovskite solar cells (HPSCs). Researchers will synthesize a new and

  10. Flammability characteristics of combustible gases and vapors. [249 refs]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Technical Report) | SciTech Connect Flammability characteristics of combustible gases and vapors. [249 refs] Citation Details In-Document Search Title: Flammability characteristics of combustible gases and vapors. [249 refs] × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in

  11. Injection locked oscillator system for pulsed metal vapor lasers

    DOE Patents [OSTI]

    Warner, Bruce E. (Livermore, CA); Ault, Earl R. (Dublin, CA)

    1988-01-01

    An injection locked oscillator system for pulsed metal vapor lasers is disclosed. The invention includes the combination of a seeding oscillator with an injection locked oscillator (ILO) for improving the quality, particularly the intensity, of an output laser beam pulse. The present invention includes means for matching the first seeder laser pulses from the seeding oscillator to second laser pulses of a metal vapor laser to improve the quality, and particularly the intensity, of the output laser beam pulse.

  12. Thermoelectrically cooled water trap

    DOE Patents [OSTI]

    Micheels, Ronald H.

    2006-02-21

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  13. Magellan: experiences from a Science Cloud

    SciTech Connect (OSTI)

    Ramakrishnan, Lavanya; Zbiegel, Piotr; Campbell, Scott; Bradshaw, Rick; Canon, Richard; Coghlan, Susan; Sakrejda, Iwona; Desai, Narayan; Declerck, Tina; Liu, Anping

    2011-02-02

    Cloud resources promise to be an avenue to address new categories of scientific applications including data-intensive science applications, on-demand/surge computing, and applications that require customized software environments. However, there is a limited understanding on how to operate and use clouds for scientific applications. Magellan, a project funded through the Department of Energy?s (DOE) Advanced Scientific Computing Research (ASCR) program, is investigating the use of cloud computing for science at the Argonne Leadership Computing Facility (ALCF) and the National Energy Research Scientific Computing Facility (NERSC). In this paper, we detail the experiences to date at both sites and identify the gaps and open challenges from both a resource provider as well as application perspective.

  14. Design, demonstration and evaluation of a thermal enhanced vapor extraction system

    SciTech Connect (OSTI)

    Phelan, J.; Reavis, B.; Swanson, J.

    1997-08-01

    The Thermal Enhanced Vapor Extraction System (TEVES), which combines powerline frequency heating (PLF) and radio frequency (RF) heating with vacuum soil vapor extraction, was used to effectively remove volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) from a pit in the chemical waste landfill (CWL) at Sandia National Laboratories (SNL) within a two month heating period. Volume average temperatures of 83{degrees}C and 112{degrees}C were reached for the PLF and RF heating periods, respectively, within the 15 ft x 45 ft x 18.5 ft deep treated volume. This resulted in the removal of 243 lb of measured toxic organic compounds (VOCs and SVOCs), 55 gallons of oil, and 11,000 gallons of water from the site. Reductions of up to 99% in total chromatographic organics (TCO) was achieved in the heated zone. Energy balance calculations for the PLF heating period showed that 36.4% of the heat added went to heating the soil, 38.5% went to evaporating water and organics, 4.2% went to sensible heat in the water, 7.1% went to heating the extracted air, and 6.6% was lost. For the RF heating period went to heating the soil, 23.5% went to evaporating water and organics, 2.4% went to sensible heat in the water, 7.5% went to heating extracted air, and 9.7% went to losses. Energy balance closure was 92.8% for the PLF heating and 98% for the RF heating. The energy input requirement per unit soil volume heated per unit temperature increase was 1.63 kWH/yd{sup 3}-{degrees}C for PLF heating and 0.73 kWH/yd{sup 3}{degrees}C for RF heating.

  15. Cloud-based Architecture Capabilities Summary Report

    SciTech Connect (OSTI)

    Vang, Leng; Prescott, Steven R; Smith, Curtis

    2014-09-01

    In collaborating scientific research arena it is important to have an environment where analysts have access to a shared of information documents, software tools and be able to accurately maintain and track historical changes in models. A new cloud-based environment would be accessible remotely from anywhere regardless of computing platforms given that the platform has available of Internet access and proper browser capabilities. Information stored at this environment would be restricted based on user assigned credentials. This report reviews development of a Cloud-based Architecture Capabilities (CAC) as a web portal for PRA tools.

  16. The Effect Of ZnO Addition On Co/C Catalyst For Vapor And Aqueous Phase Reforming Of Ethanol

    SciTech Connect (OSTI)

    Davidson, Stephen; Sun, Junming; Hong, Yongchun; Karim, Ayman M.; Datye, Abhaya K.; Wang, Yong

    2014-02-05

    The effect of ZnO addition on the oxidation behavior of Co along with catalytic performance in vapor and aqueous phase reforming of ethanol were investigated on Co supported on carbon black (XC-72R). Carbon was selected to minimize the support interactions. Effect of ZnO addition during both vapor and aqueous phase reforming were compared at 250 C. ZnO addition inhibited the reduction of cobalt oxides by H2 and created surface sites for H2O activation. During vapor phase reforming at 450 C the redox of cobalt, driven by steam oxidation and H2 reduction, trended to an equilibrium of Co0/Co2+. ZnO showed no significant effect on cobalt oxidation, inferred from the minor changes of C1 product yield. Surface sites created by ZnO addition enhanced water activation and oxidation of surface carbon species, increasing CO2 selectivity. At 250 C cobalt reduction was minimal, in situ XANES demonstrated that ZnO addition significantly facilitated oxidation of Co0 under vapor phase reforming conditions, demonstrated by lower C1 product yield. Sites introduced by ZnO addition improved the COx selectivity at 250 C. Both Co/C and Co-ZnO/C rapidly oxidized under aqueous phase reaction conditions at 250 C, showing negligible activity in aqueous phase reforming. This work suggests that ZnO affects the activation of H2O for Co catalysts in ethanol reforming.

  17. Transforming the representation of the boundary layer and low clouds for high-resolution regional climate modeling: Final report

    SciTech Connect (OSTI)

    Huang, Hsin-Yuan; Hall, Alex

    2013-07-24

    Stratocumulus and shallow cumulus clouds in subtropical oceanic regions (e.g., Southeast Pacific) cover thousands of square kilometers and play a key role in regulating global climate (e.g., Klein and Hartmann, 1993). Numerical modeling is an essential tool to study these clouds in regional and global systems, but the current generation of climate and weather models has difficulties in representing them in a realistic way (e.g., Siebesma et al., 2004; Stevens et al., 2007; Teixeira et al., 2011). While numerical models resolve the large-scale flow, subgrid-scale parameterizations are needed to estimate small-scale properties (e.g. boundary layer turbulence and convection, clouds, radiation), which have significant influence on the resolved scale due to the complex nonlinear nature of the atmosphere. To represent the contribution of these fine-scale processes to the resolved scale, climate models use various parameterizations, which are the main pieces in the model that contribute to the low clouds dynamics and therefore are the major sources of errors or approximations in their representation. In this project, we aim to 1) improve our understanding of the physical processes in thermal circulation and cloud formation, 2) examine the performance and sensitivity of various parameterizations in the regional weather model (Weather Research and Forecasting model; WRF), and 3) develop, implement, and evaluate the advanced boundary layer parameterization in the regional model to better represent stratocumulus, shallow cumulus, and their transition. Thus, this project includes three major corresponding studies. We find that the mean diurnal cycle is sensitive to model domain in ways that reveal the existence of different contributions originating from the Southeast Pacific land-masses. The experiments suggest that diurnal variations in circulations and thermal structures over this region are influenced by convection over the Peruvian sector of the Andes cordillera, while the mostly dry mountain-breeze circulations force an additional component that results in semi-diurnal variations near the coast. A series of numerical tests, however, reveal sensitivity of the simulations to the choice of vertical grid, limiting the possibility of solid quantitative statements on the amplitudes and phases of the diurnal and semidiurnal components across the domain. According to our experiments, the Mellor-Yamada-Nakanishi-Niino (MYNN) boundary layer scheme and the WSM6 microphysics scheme is the combination of schemes that performs best. For that combination, mean cloud cover, liquid water path, and cloud depth are fairly wellsimulated, while mean cloud top height remains too low in comparison to observations. Both microphysics and boundary layer schemes contribute to the spread in liquid water path and cloud depth, although the microphysics contribution is slightly more prominent. Boundary layer schemes are the primary contributors to cloud top height, degree of adiabaticity, and cloud cover. Cloud top height is closely related to surface fluxes and boundary layer structure. Thus, our study infers that an appropriate tuning of cloud top height would likely improve the low-cloud representation in the model. Finally, we show that entrainment governs the degree of adiabaticity, while boundary layer decoupling is a control on cloud cover. In the intercomparison study using WRF single-column model experiments, most parameterizations show a poor agreement of the vertical boundary layer structure when compared with large-eddy simulation models. We also implement a new Total-Energy/Mass- Flux boundary layer scheme into the WRF model and evaluate its ability to simulate both stratocumulus and shallow cumulus clouds. Result comparisons against large-eddy simulation show that this advanced parameterization based on the new Eddy-Diffusivity/Mass-Flux approach provides a better performance than other boundary layer parameterizations.

  18. ARM - Field Campaign - Thin Cloud Rotating Shadowband Radiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thin Cloud Rotating Shadowband Radiometer 2008.01.08 - 2008.07.18 Lead Scientist : Mary Jane Bartholomew For data sets, see below. Abstract The Thin-Cloud Rotating Shadowband...

  19. E-Cloud Build-up in Grooved Chambers

    SciTech Connect (OSTI)

    Venturini, Marco

    2007-05-01

    We simulate electron cloud build-up in a grooved vacuumchamber including the effect of space charge from the electrons. Weidentify conditions for e-cloud suppression and make contact withprevious estimates of an effective secondary electron yield for groovedsurfaces.

  20. Treatments of Inhomogeneous Clouds in a GCM Column Radiation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of fractal stratocumulus clouds. J. Atmos. Sci., 51, 2434 -2455. Chou, M.-D., M. J. Suarez, C.-H. Ho, M. M.-H. Yan, and K.-T. Lee, 1998: Parameterizations for cloud...