Sample records for water vapor clouds

  1. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cadeddu, Maria

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  2. Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from MODIS

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from such as cloud mask, atmos- pheric profiles, aerosol properties, total precipitable water, and cloud properties vapor amount, aerosol particles, and the subsequently formed clouds [9]. Barnes et al. [2] provide

  3. Cold Water Vapor in the Barnard 5 Molecular Cloud

    E-Print Network [OSTI]

    Wirström, E S; Persson, C M; Buckle, J V; Cordiner, M A; Takakuwa, S

    2014-01-01T23:59:59.000Z

    After more than 30 years of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds, however, there is only one region where cold (~10 K) water vapor has been detected - L1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at work -- likely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H2O (J = 1_10 - 1_01) at 556.9360 GHz toward two positions in the cold molecular cloud Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

  4. Tropical Water Vapor and Cloud Feedbacks in Climate Models: A Further Assessment Using Coupled Simulations

    E-Print Network [OSTI]

    Sun, Dezheng

    ). A small change in these radiative effects of water vapor and clouds can either offset or greatly amplify global warming, we find no significant correlation between the inter-model variations in the cloud albedo feedback during ENSO and the inter-model variations in the cloud albedo feedback during global warming

  5. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06T23:59:59.000Z

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  6. Energy and water vapor transport across a simplified cloud-clear air interface

    E-Print Network [OSTI]

    Gallana, Luca; De Santi, Francesca; Iovieno, Michele; Tordella, Daniela

    2015-01-01T23:59:59.000Z

    We consider a simplified physics of the could interface where condensation, evaporation and radiation are neglected and momentum, thermal energy and water vapor transport is represented in terms of the Boussinesq model coupled to a passive scalar transport equation for the vapor. The interface is modeled as a layer separating two isotropic turbulent regions with different kinetic energy and vapor concentration. In particular, we focus on the small scale part of the inertial range as well as on the dissipative range of scales which are important to the micro-physics of warm clouds. We have numerically investigated stably stratified interfaces by locally perturbing at an initial instant the standard temperature lapse rate at the cloud interface and then observing the temporal evolution of the system. When the buoyancy term becomes of the same order of the inertial one, we observe a spatial redistribution of the kinetic energy which produce a concomitant pit of kinetic energy within the mixing layer. In this sit...

  7. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01T23:59:59.000Z

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  8. Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds

    SciTech Connect (OSTI)

    Westwater, Edgeworth

    2011-05-06T23:59:59.000Z

    The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement (ARM) Program. At the North Slope of Alaska (NSA), both microwave radiometers (MWR) and the MWRProfiler (MWRP), been used operationally by ARM for passive retrievals of the quantities: Precipitable Water Vapor (PWV) and Liquid Water Path (LWP). However, it has been convincingly shown that these instruments are inadequate to measure low amounts of PWV and LWP. In the case of water vapor, this is especially important during the Arctic winter, when PWV is frequently less than 2 mm. For low amounts of LWP (< 50 g/m{sup 2}), the MWR and MWRP retrievals have an accuracy that is also not acceptable. To address some of these needs, in March-April 2004, NOAA and ARM conducted the NSA Arctic Winter Radiometric Experiment - Water Vapor Intensive Operational Period at the ARM NSA/Adjacent Arctic Ocean (NSA/AAO) site. After this experiment, the radiometer group at NOAA moved to the Center for Environmental Technology (CET) of the Department of Electrical and Computer Engineering of the University of Colorado at Boulder. During this 2004 experiment, a total of 220 radiosondes were launched, and radiometric data from 22.235 to 380 GHz were obtained. Primary instruments included the ARM MWR and MWRP, a Global Positioning System (GPS), as well as the CET Ground-based Scanning Radiometer (GSR). We have analyzed data from these instruments to answer several questions of importance to ARM, including: (a) techniques for improved water vapor measurements; (b) improved calibration techniques during cloudy conditions; (c) the spectral response of radiometers to a variety of conditions: clear, liquid, ice, and mixed phase clouds; and (d) forward modeling of microwave and millimeter wave brightness temperatures from 22 to 380 GHz. Many of these results have been published in the open literature. During the third year of this contract, we participated in another ARM-sponsored experiment at the NSA during February-March 2007. This experiment is called the Radiative Heating in Underexplored Bands Campaign (RHUBC) and the GSR was operated successfully for the duration of the campaign. One of the principal goals of the experiment was to provide retrievals of water vapor during PWV amounts less than 2 mm and to compare GSR data with ARM radiometers and radiosondes. A secondary goal was to compare the radiometric response of the microwave and millimeter wavelength radiometers to water and ice clouds. In this final report, we will include the separate progress reports for each of the three years of the project and follow with a section on major accomplishments of the project.

  9. Remote sensing of total integrated water vapor, wind speed, and cloud liquid water over the ocean using the Special Sensor Microwave/Imager (SSM/I)

    E-Print Network [OSTI]

    Manning, Norman Willis William

    1997-01-01T23:59:59.000Z

    A modified D-matrix retrieval method is the basis of the refined total integrated water vapor (TIWV), total integrated cloud liquid water (CLW), and surface wind speed (WS) retrieval methods that are developed. The 85 GHZ polarization difference...

  10. Collaborative Research: The Influence of Cloud Microphysics and Radiation on the Response of Water Vapor and Clouds to Climate Change

    SciTech Connect (OSTI)

    Dr. Kerry Emanuel; Michael J. Iacono

    2011-06-28T23:59:59.000Z

    Uncertainties in representing the atmospheric water cycle are major obstacles to an accurate prediction of future climate. This project focused on addressing some of these uncertainties by implementing new physics for convection and radiation into the NCAR climate model. To better understand and eventually better represent these processes, we modified CAM3.5 to use the convection and cloud schemes developed by the Massachusetts Institute of Technology (MIT) and the RRTMG rapid radiation code for global models developed by Atmospheric and Environmental Research, Inc. (AER). The impact of the new physics on the CAM3.5 simulation of convection on diurnal and intra-seasonal scales, intra-seasonal oscillations and the distribution of water vapor has been investigated. The effect of the MIT and AER physics also has been tested in the Weather Research and Forecasting (WRF) regional forecast model. It has been found that the application of the AER radiation and MIT convection produces significant improvements in the modeled diurnal cycle of convection, especially over land, in the NCAR climate model. However, both the standard CAM3.5 (hereinafter STD) and the modified CAM3.5 with the new physics (hereinafter MOD) are still unable to capture the proper spectrum and propagating characteristics of the intra-seasonal oscillations (ISOs). The new physics methods modify, but do not substantially improve, the distribution of upper tropospheric water vapor relative to satellite measurements.

  11. The Influence of Cloud Microphysics and Radiation on the Response of Water Vapor and Clouds to Climate Change

    SciTech Connect (OSTI)

    Emanuel, Kerry; Iacono, Michael J.

    2010-11-11T23:59:59.000Z

    Uncertainties in representing the atmospheric water cycle are major obstacles to the accurate prediction of future climate. This project focused on addressing some of these uncertainties by implementing new physics for convection and radiation into the NCAR Community Atmosphere Model (CAM). To better understand and eventually better represent these processes in this major national climate model, we modified CAM3.5 to use the convection and cloud schemes developed by the Massachusetts Institute of Technology (MIT) and the RRTMG rapid radiation code for global climate models developed by Atmospheric and Environmental Research, Inc. (AER). The impact of the new physics on the CAM3.5 simulation of convection on diurnal and intra-seasonal scales, on intra-seasonal oscillations and on the distribution of water vapor has been investigated. In addition, the MIT and AER physics packages have been incorporated and tested in combination within the Weather Research and Forecasting (WRF) regional forecast model for the purpose of evaluating and improving convective and radiative processes on time scales appropriate to weather simulations. It has been found that the application of the AER radiation and MIT convection produces significant improvements in the modeled diurnal cycle of convection, especially over land, in the NCAR climate model. However, both the standard CAM3.5 and the modified CAM3.5 with the new physics are unable to capture the proper spectrum and propagating characteristics of dynamical intra-seasonal oscillations such as the Madden-Julian Oscillation. In addition, it has been shown that the new physics methods modify, but do not substantially improve, the distribution of upper tropospheric water vapor in CAM as established through the comparison of modeled and observed satellite radiances. This suggests that continuing regional discrepancies in water vapor amounts in the climate model may not be solely related to convective or radiative processes. The major results of this project have been described in more detail in a journal article titled â??The Impacts of AER Radiation and MIT Convection on the Water Cycle Simulated by CAM3.5â?ť that will be submitted for publication during Fall 2010.

  12. An Analysis of Cloud Cover and Water Vapor for the ALMA Project

    E-Print Network [OSTI]

    (Chile), Chalviri (Bolivia) and Five Sites in Argentina using Satellite Data and a Verification and water vapor at Chajnantor (Chile), Chalviri (Bolivia) and four sites in Argentina. Since time

  13. PROGRESS REPORT OF FY 2004 ACTIVITIES: IMPROVED WATER VAPOR AND CLOUD RETRIEVALS AT THE NSA/AAO

    SciTech Connect (OSTI)

    E. R. Westwater; V. V. Leuskiy; M. Klein; A. J. Gasiewski; and J. A. Shaw

    2004-11-01T23:59:59.000Z

    The basic goals of the research are to develop and test algorithms and deploy instruments that improve measurements of water vapor, cloud liquid, and cloud coverage, with a focus on the Arctic conditions of cold temperatures and low concentrations of water vapor. The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement Program. Although several technologies have been investigated to measure these column amounts, microwave radiometers (MWR) have been used operationally by the ARM program for passive retrievals of these quantities: precipitable water vapor (PWV) and integrated water liquid (IWL). The technology of PWV and IWL retrievals has advanced steadily since the basic 2-channel MWR was first deployed at ARM CART sites Important advances are the development and refinement of the tipcal calibration method [1,2], and improvement of forward model radiative transfer algorithms [3,4]. However, the concern still remains that current instruments deployed by ARM may be inadequate to measure low amounts of PWV and IWL. In the case of water vapor, this is especially important because of the possibility of scaling and/or quality control of radiosondes by the water amount. Extremely dry conditions, with PWV less than 3 mm, commonly occur in Polar Regions during the winter months. Accurate measurements of the PWV during such dry conditions are needed to improve our understanding of the regional radiation energy budgets. The results of a 1999 experiment conducted at the ARM North Slope of Alaska/Adjacent Arctic Ocean (NSA/AAO) site during March of 1999 [5] have shown that the strength associated with the 183 GHz water vapor absorption line makes radiometry in this frequency regime suitable for measuring low amounts of PWV. As a portion of our research, we conducted another millimeter wave radiometric experiment at the NSA/AAO in March-April 2004. This experiment relied heavily on our experiences of the 1999 experiment. Particular attention was paid to issues of radiometric calibration and radiosonde intercomparisons. Our theoretical and experimental work also supplements efforts by industry (F. Solheim, Private Communication) to develop sub-millimeter radiometers for ARM deployment. In addition to quantitative improvement of water vapor measurements at cold temperature, the impact of adding millimeter-wave window channels to improve the sensitivity to arctic clouds was studied. We also deployed an Infrared Cloud Imager (ICI) during this experiment, both for measuring continuous day-night statistics of the study of cloud coverage and identifying conditions suitable for tipcal analysis. This system provided the first capability of determining spatial cloud statistics continuously in both day and night at the NSA site and has been used to demonstrate that biases exist in inferring cloud statistics from either zenith-pointing active sensors (lidars or radars) or sky imagers that rely on scattered sunlight in daytime and star maps at night [6].

  14. Water vapor, cloud liquid water paths, and rain rates over northern high latitude open seas

    E-Print Network [OSTI]

    Zuidema, Paquita

    longwave radiation caused by differences in cloud cover can produce an JOURNAL OF GEOPHYSICAL RESEARCH, VOL-level stratus con- tribute the most to the total Arctic cloud cover of any cloud type according to surface presence during summertime but otherwise the Wentz internal sea-ice screening appears effective

  15. Forced Dispersion of Liquefied Natural Gas Vapor Clouds with Water Spray Curtain Application

    E-Print Network [OSTI]

    Rana, Morshed A.

    2011-02-22T23:59:59.000Z

    .............................................................................................................................. 211 xv LIST OF FIGURES Page Fig. 1. Densities of methane (vapor) and air at different temperatures. .......................... 2 Fig. 2. Temperature and specific gravity of methane, air and methane-air mixture at atmospheric... on methane concentration downwind of the LNG pool ..................................................................................................... 37 Fig. 10. Methane concentrations downwind of the LNG pool, with and without water spray...

  16. ARM - PI Product - MWR Retrievals of Cloud Liquid Water and Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa- PolarizationgovCampaignsSummergovFieldgovDataPI Data ProductsMWR Retrievals of Cloud

  17. Tropospheric water vapor and climate sensitivity

    SciTech Connect (OSTI)

    Schneider, E.K.; Kirtman, B.P.; Lindzen, R.S. [Center for Ocean-Land-Atmosphere Studies, Calverton, MD (United States)] [Center for Ocean-Land-Atmosphere Studies, Calverton, MD (United States)

    1999-06-01T23:59:59.000Z

    Estimates are made of the effect of changes in tropospheric water vapor on the climate sensitivity to doubled carbon dioxide (CO{sub 2}) using a coarse resolution atmospheric general circulation model coupled to a slab mixed layer ocean. The sensitivity of the model to doubled CO{sub 2} is found as the difference between the equilibrium responses for control and doubled CO{sub 2} cases. Clouds are specified to isolate the water vapor feedback. Experiments in which the water vapor distribution is specified rather than internally calculated are used to find the contribution of water vapor in various layers and latitude belts to the sensitivity. The contribution of water vapor in layers of equal mass to the climate sensitivity varies by about a factor of 2 with height, with the largest contribution coming from layers between 450 and 750 mb, and the smallest from layers above 230 mb. The positive feedback on the global mean surface temperature response to doubled CO{sub 2} from water vapor above 750 mb is about 2.6 times as large as that from water vapor below 750 mb. The feedback on global mean surface temperature due to water vapor in the extratropical free troposphere is about 50% larger than the feedback due to the lower-latitude free troposphere water vapor. Several important sources of nonlinearity of the radiative heating rates were identified in the process of constructing the specified cloud and water vapor fields. These are (1) the interaction of clouds and solar radiation, which produces much more reflection of solar radiation for time mean clouds than for the instantaneous clouds; (2) the correlation of clouds and water vapor, which produces less downward longwave radiation at the ground for correlated clouds and water vapor than when these fields are independent; and (3) the interaction of water vapor with long wave radiation, which produces less downward longwave radiation at the ground of the average over instantaneous water vapor distributions than of the time mean water vapor distribution.

  18. Turn-key Raman lidar for profiling atmospheric water vapor, clouds, and aerosols at the US Southern Great Plains Climate Study Site

    SciTech Connect (OSTI)

    Goldsmith, J.E.M.; Blair, F.H.; Bisson, S.E.

    1997-12-31T23:59:59.000Z

    There are clearly identified scientific requirements for continuous profiling of atmospheric water vapor at the Department of Energy, Atmospheric Radiation Measurement program, Southern Great Plains CART (Cloud and Radiation Testbed) site in northern Oklahoma. Research conducted at several laboratories has demonstrated the suitability of Raman lidar for providing measurements that are an excellent match to those requirements. We have developed and installed a ruggedized Raman lidar system that resides permanently at the CART site, and that is computer automated to eliminate the requirements for operator interaction. In addition to the design goal of profiling water vapor through most of the troposphere during nighttime and through the boundary layer during daytime, the lidar provides quantitative characterizations of aerosols and clouds, including depolarization measurements for particle phase studies.

  19. Ocean Water Vapor and Cloud Burden Trends Derived from the Topex Microwave Radiometer

    E-Print Network [OSTI]

    Ruf, Christopher

    algorithm is a log-linear regression algorithm with coefficients that are stratified by wind speed and water. TMR OBSERVATIONS The TMR flew in a 10-day non-sun-synchronous exact repeat orbit with an inclination

  20. Water Vapor Experiment Concludes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  1. ARM Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP Update Information on new,Scanning Radar323ARM Water Vapor IOP

  2. Application of Computational Fluid Dynamics in the Forced Dispersion Modeling of LNG Vapor Clouds

    E-Print Network [OSTI]

    Kim, Byung-Kyu

    2013-05-31T23:59:59.000Z

    The safety and security of liquefied natural gas (LNG) facilities has prompted the need for continued study of LNG mitigation systems. Water spray systems are widely recognized as an effective measure for dispersing LNG vapor clouds. Currently...

  3. A Low-order Model of Water Vapor, Clouds, and Thermal Emission for Tidally Locked Terrestrial Planets

    E-Print Network [OSTI]

    Yang, Jun

    2014-01-01T23:59:59.000Z

    In the spirit of minimal modeling of complex systems, we develop an idealized two-column model to investigate the climate of tidally locked terrestrial planets with Earth-like atmospheres in the habitable zone of M-dwarf stars. The model is able to approximate the fundamental features of the climate obtained from three-dimensional (3D) atmospheric general circulation model (GCM) simulations. One important reason for the two-column model's success is that it reproduces the high cloud albedo of the GCM simulations, which reduces the planet's temperature and delays the onset of a runaway greenhouse state. The two-column model also clearly illustrates a secondary mechanism for determining the climate: the nightside acts as a ``radiator fin'' through which infrared energy can be lost to space easily. This radiator fin is maintained by a temperature inversion and dry air on the nightside, and plays a similar role to the subtropics on modern Earth. Since 1D radiative-convective models cannot capture the effects of t...

  4. Hydrogen Cars and Water Vapor

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    misidentified as "zero-emissions vehicles." Fuel cell vehicles emit water vapor. A global fleet could have, with discernible effects on people and ecosystems. The broad environmental effects of fuel cell vehicles. This cycle is currently under way with hydrogen fuel cells. As fuel cell cars are suggested as a solution

  5. ARM - Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP Related Links Facilities and Instruments Manus Island NauruWater

  6. 6, 80698095, 2006 Water vapor in Asian

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of Sciences, Beijing, China 2 National Center for Atmospheric Research, Boulder, CO, USA Received: 23 May 2006 vapor from European Center for Medium-Range Weather20 Forecasts (ECMWF) analyses. 1 Introduction Upper Tropospheric Water Vapor (UTWV) is a key greenhouse gas which exerts a major influence on the energy balance

  7. Global Climate Modeling of the Martian water cycle with improved microphysics and radiatively active water ice clouds

    E-Print Network [OSTI]

    Navarro, Thomas; Forget, François; Spiga, Aymeric; Millour, Ehouarn; Montmessin, Franck

    2013-01-01T23:59:59.000Z

    Radiative effects of water ice clouds have noteworthy consequences on the Martian atmosphere, its thermal structure and circulation. Accordingly, the inclusion of such effects in the LMD Mars Global Climate Model (GCM) greatly modifies the simulated Martian water cycle. The intent of this paper is to address the impact of radiatively active clouds on atmospheric water vapor and ice in the GCM and improve its representation. We propose a new enhanced modeling of the water cycle, consisting of detailed cloud microphysics with dynamic condensation nuclei and a better implementation of perennial surface water ice. This physical modeling is based on tunable parameters. This new version of the GCM is compared to the Thermal Emission Spectrometer observations of the water cycle. Satisfying results are reached for both vapor and cloud opacities. However, simulations yield a lack of water vapor in the tropics after Ls=180{\\deg} which is persistent in simulations compared to observations, as a consequence of aphelion c...

  8. Near-Global Survey of Effective Droplet Radii in Liquid Water Clouds Using ISCCP Data 1 . Introduction

    E-Print Network [OSTI]

    Han, Quingyuan

    VOLUME 7 Near-Global Survey of Effective Droplet Radii in Liquid Water Clouds Using ISCCP Data 1 indicate the magnitude ofaerosol effects on clouds. A method, based on a complete radiative transfer model the radiative effects ofwater vapor and clouds and the hydrological cycle, and create several important cloud

  9. Adsorption of water vapor on reservoir rocks

    SciTech Connect (OSTI)

    Not Available

    1993-07-01T23:59:59.000Z

    Progress is reported on: adsorption of water vapor on reservoir rocks; theoretical investigation of adsorption; estimation of adsorption parameters from transient experiments; transient adsorption experiment -- salinity and noncondensible gas effects; the physics of injection of water into, transport and storage of fluids within, and production of vapor from geothermal reservoirs; injection optimization at the Geysers Geothermal Field; a model to test multiwell data interpretation for heterogeneous reservoirs; earth tide effects on downhole pressure measurements; and a finite-difference model for free surface gravity drainage well test analysis.

  10. Global cloud liquid water path simulations

    SciTech Connect (OSTI)

    Lemus, L. [Southern Hemisphere Meteorology, Clayton, Victoria (Australia)] [Southern Hemisphere Meteorology, Clayton, Victoria (Australia); Rikus, L. [Bureau of Meteorology Research Centre, Melbourne, Victoria (Australia)] [Bureau of Meteorology Research Centre, Melbourne, Victoria (Australia); Martin, C.; Platt, R. [CSIRO, Aspendale, Victoria (Australia)] [CSIRO, Aspendale, Victoria (Australia)

    1997-01-01T23:59:59.000Z

    A new parameterization of cloud liquid water and ice content has been included in the Bureau of Meteorology Global Assimilation and Prediction System. The cloud liquid water content is derived from the mean cloud temperatures in the model using an empirical relationship based on observations. The results from perpetual January and July simulations are presented and show that the total cloud water path steadily decreases toward high latitudes, with two relative maxima at midlatitudes and a peak at low latitudes. To validate the scheme, the simulated fields need to be processed to produce liquid water paths that can be directly compared with the corresponding field derived from Special Sensor Microwave/Imager (SSM/I) data. This requires the identification of cloud ice water content within the parameterization and a prescription to account for the treatment of strongly precipitating subgrid-scale cloud. The resultant cloud liquid water paths agree qualitatively with the SSM/I data but show some systematic errors that are attributed to corresponding errors in the model`s simulation of cloud amounts. Given that a more quantitative validation requires substantial improvement in the model`s diagnostic cloud scheme, the comparison with the SSM/I data indicates that the cloud water path, derived from the cloud liquid water content parameterization introduced in this paper, is consistent with the observations and can be usefully incorporated in the prediction system. 40 refs., 11 figs., 1 tab.

  11. Ice Heating Up Cold Clouds | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ice Heating Up Cold Clouds Ice Heating Up Cold Clouds Released: October 04, 2011 In a heated battle, ice crystals win the competition for cloud water vapor The mighty cloud ice...

  12. atmospheric water vapor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    greenhouse gas, contributing to approximately two-thirds of the Earth's greenhouse effect Mitchell, 1989; IntergovernmentalA meta-analysis of water vapor...

  13. FIRST DETECTION OF WATER VAPOR IN A PRE-STELLAR CORE

    SciTech Connect (OSTI)

    Caselli, Paola; Douglas, Thomas [School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT (United Kingdom); Keto, Eric [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Bergin, Edwin A. [Department of Astronomy, The University of Michigan, 500 Church Street, Ann Arbor, MI 48109-1042 (United States); Tafalla, Mario [Observatorio Astronomico Nacional (IGN), Calle Alfonso XII, 3, E-28014 Madrid (Spain); Aikawa, Yuri [Department of Earth and Planetary Sciences, Kobe University, Nada, 657-8501 Kobe (Japan); Pagani, Laurent [LERMA and UMR 8112 du CNRS, Observatoire de Paris, 61 Av. de l'Observatoire, F-75014 Paris (France); Yildiz, Umut A.; Kristensen, Lars E.; Van Dishoeck, Ewine F. [Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA Leiden (Netherlands); Van der Tak, Floris F. S. [SRON Netherlands Institute for Space Research, P.O. Box 800, 9700 AV, Groningen (Netherlands); Walmsley, C. Malcolm; Codella, Claudio [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Firenze (Italy); Nisini, Brunella, E-mail: p.caselli@leeds.ac.uk [INAF-Osservatorio Astronomico di Roma, I-00040 Monte Porzio Catone (Italy)

    2012-11-10T23:59:59.000Z

    Water is a crucial molecule in molecular astrophysics as it controls much of the gas/grain chemistry, including the formation and evolution of more complex organic molecules in ices. Pre-stellar cores provide the original reservoir of material from which future planetary systems are built, but few observational constraints exist on the formation of water and its partitioning between gas and ice in the densest cores. Thanks to the high sensitivity of the Herschel Space Observatory, we report on the first detection of water vapor at high spectral resolution toward a dense cloud on the verge of star formation, the pre-stellar core L1544. The line shows an inverse P-Cygni profile, characteristic of gravitational contraction. To reproduce the observations, water vapor has to be present in the cold and dense central few thousand AU of L1544, where species heavier than helium are expected to freeze out onto dust grains, and the ortho:para H{sub 2} ratio has to be around 1:1 or larger. The observed amount of water vapor within the core (about 1.5 Multiplication-Sign 10{sup -6} M{sub Sun }) can be maintained by far-UV photons locally produced by the impact of galactic cosmic rays with H{sub 2} molecules. Such FUV photons irradiate the icy mantles, liberating water vapor in the core center. Our Herschel data, combined with radiative transfer and chemical/dynamical models, shed light on the interplay between gas and solids in dense interstellar clouds and provide the first measurement of the water vapor abundance profile across the parent cloud of a future solar-type star and its potential planetary system.

  14. Decomposing aerosol cloud radiative effects into cloud cover, liquid water path and Twomey components

    E-Print Network [OSTI]

    Daniel, Rosenfeld

    Decomposing aerosol cloud radiative effects into cloud cover, liquid water path and Twomey interactions radiative effects, i.e., the cloud cover, liquid water path (LWP) and cloud drop radius (Twomey negative radiative forcing on the global scale, mainly due to the cloud cover effect. © 2013 Elsevier B

  15. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Vignola, F.; Andreas, A.

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  16. Apparent Temperature Dependence on Localized Atmospheric Water Vapor

    E-Print Network [OSTI]

    Salvaggio, Carl

    Apparent Temperature Dependence on Localized Atmospheric Water Vapor Matthew Montanaroa, Carl temperature of the target if not properly accounted for. The temperature error is defined as the difference between the target leaving apparent temperature and observed apparent temperature. The effects

  17. VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM

    E-Print Network [OSTI]

    ) and their binary mixtures (between 348 and 393 K). The properties of supercritical carbon dioxide were determinedVAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE the vapor-liquid equilibrium of water (between 323 and 573 K), carbon dioxide (between 230 and 290 K

  18. Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

    1995-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  19. Experimental Study of Water Vapor Adsorption on Geothermal

    E-Print Network [OSTI]

    Stanford University

    SGP-TR-148 Experimental Study of Water Vapor Adsorption on Geothermal Reservoir Rocks Shubo Shang Geothermal Program under Department of Energy Grant No. DE-FG07-90IDI2934,and by the Department of Petroleum Engineering, Stanford University Stanford Geothermal Program Interdisciplinary Research in Engineering

  20. Surface Science in the Richmond Lab: Vapor/Water Studies

    E-Print Network [OSTI]

    Richmond, Geraldine L.

    Surface Science in the Richmond Lab: Vapor/Water Studies Many of the Earth's important atmospheric recovery, and emulsion stabilization. We are studying the behavior of species at the carbon tetrachloride.2 3100300029002800 pH~ 2 pH~ 4.5 pH ~ 5.5 Wavenumbers / cm-1 SFGAmp/arb.units COOH COOH COOH Emulsion Studies

  1. Evaluation of tropospheric water vapor profiling using eye-safe, infrared differential absorption lidar

    SciTech Connect (OSTI)

    Rye, B.J. [Colorado Univ., Boulder, CO (United States). Cooperative Inst. for Research in Environmental Sciences]|[National Oceanic and Atmospheric Administration, Boulder, CO (United States). Environmental Technology Lab.; Machol, J.L.; Grund, C.J.; Hardesty, R.M. [National Oceanic and Atmospheric Administration, Boulder, CO (United States). Environmental Technology Lab.

    1996-05-14T23:59:59.000Z

    Continuous, high quality profiles of water vapor, free of systematic bias, and of moderate temporal and spatial resolution are fundamental to the success of the ARM CART program. In addition, these should be acquired over long periods at low operational and maintenance cost. The development and verification of realistic climate model parameterizations for clouds and net radiation balance, and the correction of other CART site sensor observations for interferences due to the presence of water vapor are critically dependent on water vapor profile measurements. To date, application of profiles have been limited by vertical resolution and uniqueness and high operating cost, or diminished daytime performance, lack of eye-safety, and high maintenance cost. Recent developments in infrared laser and detector technology make possible compact IR differential absorption lidar (DIAL) systems at eye-safe wavelengths. In the studies reported here, we develop DIAL system performance models and examine the potential of solving some of the shortcomings of previous methods using parameters representative of current technologies. These simulations are also applied to determine the strengths and weaknesses unique to the DIAL method for this application.

  2. Fixation of nitrogen in the presence of water vapor

    DOE Patents [OSTI]

    Harteck, Paul (Santa Barbara, CA)

    1984-01-01T23:59:59.000Z

    A process for the fixation of nitrogen is disclosed which comprises combining a mixture of nitrogen, oxygen, metal oxide and water vapor, initially heating the combination to initiate a reaction which forms nitrate, but at a temperature and pressure range below the dissociation pressure of the nitrate. With or without the water component, the yield of fixed nitrogen is increased by the use of a Linde Molecular Sieve Catalyst.

  3. Balance of atmospheric water vapor over the Gulf of Mexico

    E-Print Network [OSTI]

    Hughes, Ralph Morgan

    1967-01-01T23:59:59.000Z

    / / / / I / o. i + B CAP C BBJ V S TPA PZA EHA Fig. 5. Vertical distribution of the average water-vapor flux normal to the perimeter of the Gulf of Nexico during Oct-Kov-Dec 1959. Plus values are inflow in kgm/sec-mb-. m. -o-I Pi C4 I / ~-o, i...BALANCE OF ATMOSPHERIC HATER VAPOR OVER THE GULF OF MEXICO A Thesis By RALPH MORGAN HUGHES Captain, USAF Submitted to the Graduate College of the Texas A&M University in partial fulf-'llment of the rec;uirements for the degree of MASTER...

  4. LETTER The incidence and implications of clouds for cloud forest plant water relations

    E-Print Network [OSTI]

    Goldsmith, Greg

    , the montane forest experienced higher precipi- tation, cloud cover and leaf wetting events of longer duration for an improved understanding of clouds and their effects on cloud forest plant functioning. As summarised below (VPD) and photosynthetically active radiation. In turn, this decreases plant water demand. The suppres

  5. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa- PolarizationgovCampaignsSummer Single ColumngovCampaignsWater Cycle Pilot

  6. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa- PolarizationgovCampaignsSummer Single ColumngovCampaignsWater Cycle

  7. Water vapor and the dynamics of climate changes

    E-Print Network [OSTI]

    Schneider, Tapio; Levine, Xavier

    2009-01-01T23:59:59.000Z

    Water vapor is not only Earth's dominant greenhouse gas. Through the release of latent heat when it condenses, it also plays an active role in dynamic processes that shape the global circulation of the atmosphere and thus climate. Here we present an overview of how latent heat release affects atmosphere dynamics in a broad range of climates, ranging from extremely cold to extremely warm. Contrary to widely held beliefs, atmospheric circulation statistics can change non-monotonically with global-mean surface temperature, in part because of dynamic effects of water vapor. For example, the strengths of the tropical Hadley circulation and of zonally asymmetric tropical circulations, as well as the kinetic energy of extratropical baroclinic eddies, can be lower than they presently are both in much warmer climates and in much colder climates. We discuss how latent heat release is implicated in such circulation changes, particularly through its effect on the atmospheric static stability, and we illustrate the circul...

  8. Cloud water contents and hydrometeor sizes during the FIRE Arctic Clouds Experiment

    E-Print Network [OSTI]

    Shupe, Matthew

    of radiometers at an ice station frozen into the drifting ice pack of the Arctic Ocean. The NASA/FIRE Arctic- dependent water contents and hydrometeor sizes for all-ice and all-liquid clouds. For the spring and early summer period, all-ice cloud retrievals showed a mean particle diameter of about 60 m and ice water

  9. On water ice formation in interstellar clouds

    E-Print Network [OSTI]

    Renaud Papoular

    2005-07-06T23:59:59.000Z

    A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The model predicts the existence of a threshold in interstellar light extinction, A(v), which is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal/mole, which sets the visible exctinction threshold at a few magnitudes, as observed. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, forming an ice mantle, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The model also predicts that the thickness of the mantle, and, hence, the optical thickness at 3 mu, grow linearly with A(v), as observed, with a slope which depends upon the total amount of water in the gas. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons, and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances of sticking in situ.

  10. Atmospheric cloud water contains a diverse bacterial community

    SciTech Connect (OSTI)

    Kourtev, P. S.; Hill, Kimberly A.; Shepson, Paul B.; Konopka, Allan

    2011-06-15T23:59:59.000Z

    Atmospheric cloud water contains an active microbial community which can impact climate, human health and ecosystem processes in terrestrial and aquatic systems. Most studies on the composition of microbial communities in clouds have been performed with orographic clouds that are typically in direct contact with the ground. We collected water samples from cumulus clouds above the upper U.S. Midwest. The cloud water was analyzed for the diversity of bacterial phylotypes by denaturing gradient gel electrophoresis (DGGE) and sequencing of 16S rRNA gene amplicons. DGGE analyses of bacterial communities detected 17e21 bands per sample. Sequencing confirmed the presence of a diverse bacterial community; sequences from seven bacterial phyla were retrieved. Cloud water bacterial communities appeared to be dominated by members of the cyanobacteria, proteobacteria, actinobacteria and firmicutes.

  11. Intercomparison of the Cloud Water Phase among Global Climate Models

    SciTech Connect (OSTI)

    Komurcu, Muge; Storelvmo, Trude; Tan, Ivy; Lohmann, U.; Yun, Yuxing; Penner, Joyce E.; Wang, Yong; Liu, Xiaohong; Takemura, T.

    2014-03-27T23:59:59.000Z

    Mixed-phase clouds (clouds that consist of both cloud droplets and ice crystals) are frequently present in the Earth’s atmosphere and influence the Earth’s energy budget through their radiative properties, which are highly dependent on the cloud water phase. In this study, the phase partitioning of cloud water is compared among six global climate models (GCMs) and with Cloud and Aerosol Lidar with Orthogonal Polarization retrievals. It is found that the GCMs predict vastly different distributions of cloud phase for a given temperature, and none of them are capable of reproducing the spatial distribution or magnitude of the observed phase partitioning. While some GCMs produced liquid water paths comparable to satellite observations, they all failed to preserve sufficient liquid water at mixed-phase cloud temperatures. Our results suggest that validating GCMs using only the vertically integrated water contents could lead to amplified differences in cloud radiative feedback. The sensitivity of the simulated cloud phase in GCMs to the choice of heterogeneous ice nucleation parameterization is also investigated. The response to a change in ice nucleation is quite different for each GCM, and the implementation of the same ice nucleation parameterization in all models does not reduce the spread in simulated phase among GCMs. The results suggest that processes subsequent to ice nucleation are at least as important in determining phase and should be the focus of future studies aimed at understanding and reducing differences among the models.

  12. An optical water vapor sensor for unmanned aerial vehicles

    SciTech Connect (OSTI)

    Timothy A. Berkoff; Paul L. Kebabian; Robert A. McClatchy; Charles E. Kolb; Andrew Freedman

    1998-12-01T23:59:59.000Z

    The water vapor sensor developed by Aerodyne Research, based on the optical absorption of light at {approximately}935 nm, has been successfully demonstrated on board the Pacific Northwest National Laboratory's Gulfstream-1 research aircraft during the Department of Energy's ARM Intensive Operations Period in August 1998. Data taken during this field campaign show excellent agreement with a chilled mirror and Lyman-alpha hygrometers and measurements confirm the ability to measure rapid, absolute water vapor fluctuations with a high degree of instrument stability and accuracy, with a noise level as low 10 ppmv (1 Hz measurement bandwidth). The construction of this small, lightweight sensor contains several unique elements which result in several significant advantages when compared to other techniques. First, the low power consumption Argon discharge lamp provides an optical beam at a fixed wavelength without a need for temperature or precision current control. The multi-pass absorption cell developed for this instrument provides a compact, low cost method that can survive deployment in the field. Fiber-optic cables, which are used to convey to light between the absorption cell, light source, and detection modules enable remote placement of the absorption cell from the opto-electronics module. Finally, the sensor does not use any moving parts which removes a significant source of potential malfunction. The result is an instrument which maintained its calibration throughout the field measurement campaign, and was not affected by high vibration and large uncontrolled temperature excursions. We believe that the development of an accurate, fast response water vapor monitor described in this report will open up new avenues of aerial-vehicle-based atmospheric research which have been relatively unexplored due to the lack of suitable low-cost, light-weight instrumentation.

  13. enhanced) in water vapor. The distribution of water ice throughout the solar nebula may

    E-Print Network [OSTI]

    Utrecht, Universiteit

    enhanced) in water vapor. The distribution of water ice throughout the solar nebula may have varied Solar System (Univ. of Arizona Press, Tucson, AZ, 1988), p. 348. The time scale for settling of solids that are a few hundred times greater than that of the canonical solar nebula (14). Turbulent

  14. Moisture burst structure in satellite water vapor imagery

    E-Print Network [OSTI]

    Ulsh, David Joel

    1988-01-01T23:59:59.000Z

    The moisture burst is a tropical synoptic-scale weather event that typically originates along the ITCZ and has been defined previously in window-channel infrared imagery. This research uses 6. 7-micrometer water vapor absorption band imagery to composite 35... moisture burst events during the North Pacific cool season of 1983-1984. Composite maps are constructed at four times, each 24 h apart, during the life cycle of the moisture burst. A comparative baseline is provided by an additional composite of 35 dates...

  15. ARM - Field Campaign - ARM-FIRE Water Vapor Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76)ARM2, 2006Observations ofgovCampaignsARM-FIRE Water Vapor

  16. The Water Vapor Abundance in Orion KL Outflows

    E-Print Network [OSTI]

    J. Cernicharo; J. R. Goicoechea; F. Daniel; M. R. Lerate; M. J. Barlow; B. M. Swinyard; E. van Dishoeck; T. L. Lim; S. Viti; J. Yates

    2006-08-16T23:59:59.000Z

    We present the detection and modeling of more than 70 far-IR pure rotational lines of water vapor, including the 18O and 17O isotopologues, towards Orion KL. Observations were performed with the Long Wavelength Spectrometer Fabry-Perot (LWS/FP; R~6800-9700) on board the Infrared Space Observatory (ISO) between ~43 and ~197 um. The water line profiles evolve from P-Cygni type profiles (even for the H2O18 lines) to pure emission at wavelengths above ~100 um. We find that most of the water emission/absorption arises from an extended flow of gas expanding at 25+-5 kms^-1. Non-local radiative transfer models show that much of the water excitation and line profile formation is driven by the dust continuum emission. The derived beam averaged water abundance is 2-3x10^-5. The inferred gas temperature Tk=80-100 K suggests that: (i) water could have been formed in the "plateau" by gas phase neutral-neutral reactions with activation barriers if the gas was previously heated (e.g. by shocks) to >500 K and/or (ii) H2O formation in the outflow is dominated by in-situ evaporation of grain water-ice mantles and/or (iii) H2O was formed in the innermost and warmer regions (e.g. the hot core) and was swept up in ~1000 yr, the dynamical timescale of the outflow.

  17. MODELLING RADIATIVELY ACTIVE WATER-ICE CLOUDS: IMPACT ON THE THERMAL STRUCTURE AND WATER CYCLE.

    E-Print Network [OSTI]

    Madeleine, Jean-Baptiste

    MODELLING RADIATIVELY ACTIVE WATER-ICE CLOUDS: IMPACT ON THE THERMAL STRUCTURE AND WATER CYCLE. J. The essential role of water-ice clouds in shaping the thermal structure of the martian atmosphere has been long presumed [1] but neglected in GCMs because of the lack of observations and difficulty to predict

  18. Analysis and Calibration of CRF Raman Lidar Cloud Liquid Water Measurements

    SciTech Connect (OSTI)

    Turner, D.D.

    2007-10-31T23:59:59.000Z

    The Atmospheric Radiation Measurement (ARM) Raman lidar (RL), located at the Southern Great Plains (SGP) Climate Research Facility (CRF), is a unique state-of-the-art active remote sensor that is able to measure profiles of water vapor, aerosol, and cloud properties at high temporal and vertical resolution throughout the diurnal cycle. In October 2005, the capability of the RL was extended by the addition of a new detection channel that is sensitive to the Raman scattering of liquid water. This new channel permits the system, in theory, to measure profiles of liquid water content (LWC) by the RL. To our knowledge, the ARM RL is the only operation lidar with this capability. The liquid water Raman backscattering cross-section is a relatively weak and spectrally broad feature, relative to the water vapor Raman backscatter signal. The wide bandpass required to achieve reasonable signal-to-noise in the liquid water channel essentially eliminates the ability to measure LWC profiles during the daytime in the presence of large solar background, and thus all LWC observations are nighttime only. Additionally, the wide bandpass increases the probability that other undesirable signals, such as fluorescence from aerosols, may contaminate the observation. The liquid water Raman cross-section has a small amount of overlap with the water vapor Raman cross-section, and thus there will be a small amount of ‘cross-talk’ between the two signals, with water vapor contributing a small amount of signal to the LWC observation. And finally, there is significant uncertainty in the actual strength of the liquid water Raman cross-section in the literature. The calibrated LWC profiles, together with the coincident cloud backscatter observations also made by the RL, can be used to derive profiles of cloud droplet effective radius. By combining these profiles of effective radius in the lower portion of the cloud with the aerosol extinction measurements made below the cloud by the RL, the first aerosol indirect effect can be investigated using a single instrument, thereby reducing the uncertainty associated with aligning the different sampling periods and fields of view of multiple instruments. We have applied a “first principles” calibration to the LWC profiles. This approach requires that the relative differences in optical efficiency between the water vapor and liquid water channels be known; this relative difference is easily computed using the efficiency values of the beam splitters and interference filters in the lidar that were provided by the vendors of these components. The first principles approach then transfers the calibration from the water vapor mixing ratio to the LWC using the difference in the optical efficiency and an interpolated value of the liquid water Raman cross section from the literature, and the better established water vapor Raman cross section. After accounting for all known error sources, the vertical integral of LWC was compared against a similar value retrieved from a co-located ground-based infrared radiometer. The RL and infrared radiometer have significantly different fields of view; thus to compare the two sensors the data were averaged to 5 min intervals where only cloudy samples were included in the average of each. While there is fair scatter in the data (r=0.47), there is also a clear indication of a positive correlation between the infrared and the RL values. The value of the slope of the regression is 0.49, which indicates a tendency of the RL measurements to underestimate the total liquid amount with respect to the infrared retrieval. Research continues to investigate the source of the bias, but the most likely candidate is the large uncertainty in the liquid water Raman cross-section as there have been no direct measurements made of this parameter at the lidar’s laser wavelength of 355 nm. The calibrated LWC profile was then used together with the cloud backscatter coefficient profile from the RL to derive profiles of cloud droplet effective radius and cloud droplet number density. These profiles o

  19. Water, Vapor, and Salt Dynamics in a Hot Repository

    SciTech Connect (OSTI)

    Bahrami, Davood; Danko, George [Department of Mining Engineering, University of Nevada, Reno, 1664 N. Virginia St., Reno, NV, 89557 (United States); Walton, John [Department of Civil Engineering, University of Texas at El Paso, 500 W. University, El Paso, TX, 79968 (United States)

    2007-07-01T23:59:59.000Z

    The purpose of this paper is to report the results of a new model study examining the high temperature nuclear waste disposal concept at Yucca Mountain using MULTIFLUX, an integrated in-drift- and mountain-scale thermal-hydrologic model. The results show that a large amount of vapor flow into the drift is expected during the period of above-boiling temperatures. This phenomenon makes the emplacement drift a water/moisture attractor during the above-boiling temperature operation. The evaporation of the percolation water into the drift gives rise to salt accumulation in the rock wall, especially in the crown of the drift for about 1500 years in the example. The deposited salts over the drift footprint, almost entirely present in the fractures, may enter the drift either by rock fall or by water drippage. During the high temperature operation mode, the barometric pressure variation creates fluctuating relative humidity in the emplacement drift with a time period of approximately 10 days. Potentially wet and dry conditions and condensation on salt-laden drift wall sections may adversely affect the storage environment. Salt accumulations during the above-boiling temperature operation must be sufficiently addressed to fully understand the waste package environment during the thermal period. Until the questions are resolved, a below-boiling repository design is favored where the Alloy-22 will be less susceptible to localized corrosion. (authors)

  20. Desalination-of water by vapor-phase transport through hydrophobic nanopores

    E-Print Network [OSTI]

    Lee, Jongho

    We propose a new approach to desalination of water whereby a pressure difference across a vapor-trapping nanopore induces selective transport of water by isothermal evaporation and condensation across the pore. Transport ...

  1. Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

    1993-07-01T23:59:59.000Z

    Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

  2. Millimeter-wave Radiometer for High Sensitivity Water Vapor Profiling in Arid Regions

    SciTech Connect (OSTI)

    Pazmany, Andrew

    2006-11-09T23:59:59.000Z

    Abstract - ProSensing Inc. has developed a G-band (183 GHz) water Vapor Radiometer (GVR) for long-term, unattended measurements of low concentrations of atmospheric water vapor and liquid water. Precipitable water vapor and liquid water path are estimated from zenith brightness temperatures measured from four double-sideband receiver channels, centered at 183.31 1, 3 and 7, and 14 GHz. A prototype ground-based version of the instrument was deployed at the DOE ARM program?s North Slope of Alaska site near Barrow AK in April 2005, where it collected data continuously for one year. A compact, airborne version of this instrument, packaged to operate from a standard 2-D PMS probe canister, has been tested on the ground and is scheduled for test flights in the summer of 2006. This paper presents design details, laboratory test results and examples of retrieved precipitable water vapor and liquid water path from measured brightness temperature data.

  3. VALIDATION OF CLOUD LIQUID WATER PATH RETRIEVALS FROM SEVIRI ON METEOSAT-8 USING CLOUDNET OBSERVATIONS

    E-Print Network [OSTI]

    Haak, Hein

    on global cloud statistics and radiation budget #12;(Feijt et al., 2003). With the launch of Meteosat Second effective radius and Cloud Liquid Water Path (CLWP) over Europe. The CloudNET research project, supported forecast models. The radiative behavior of clouds depends predominantly on cloud properties

  4. Cloud Condensation Nuclei (CCN) Analysis of Biogenic Secondary Organic Aerosol

    E-Print Network [OSTI]

    Collins, Gary S.

    Cloud Condensation Nuclei (CCN) Analysis of Biogenic Secondary Organic Aerosol Rachel L. Atlas1' gas-phase emissions and the aerosols they form (figure 6), including a cloud condensation nuclei Cloud condensation nuclei (CCN) are particles which water vapor condenses onto to form cloud droplets

  5. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu (Palo Alto, CA); Ly, Jennifer (San Jose, CA); Aldajani, Tiem (San Jose, CA); Baker, Richard W. (Palo Alto, CA)

    2011-08-23T23:59:59.000Z

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  6. Water Vapor Turbulence Profiles in Stationary Continental Convective Mixed Layers

    SciTech Connect (OSTI)

    Turner, D. D.; Wulfmeyer, Volker; Berg, Larry K.; Schween, Jan

    2014-10-08T23:59:59.000Z

    The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program’s Raman lidar at the ARM Southern Great Plains (SGP) site in north-central Oklahoma has collected water vapor mixing ratio (q) profile data more than 90% of the time since October 2004. Three hundred (300) cases were identified where the convective boundary layer was quasi-stationary and well-mixed for a 2-hour period, and q mean, variance, third order moment, and skewness profiles were derived from the 10-s, 75-m resolution data. These cases span the entire calendar year, and demonstrate that the q variance profiles at the mixed layer (ML) top changes seasonally, but is more related to the gradient of q across the interfacial layer. The q variance at the top of the ML shows only weak correlations (r < 0.3) with sensible heat flux, Deardorff convective velocity scale, and turbulence kinetic energy measured at the surface. The median q skewness profile is most negative at 0.85 zi, zero at approximately zi, and positive above zi, where zi is the depth of the convective ML. The spread in the q skewness profiles is smallest between 0.95 zi and zi. The q skewness at altitudes between 0.6 zi and 1.2 zi is correlated with the magnitude of the q variance at zi, with increasingly negative values of skewness observed lower down in the ML as the variance at zi increases, suggesting that in cases with larger variance at zi there is deeper penetration of the warm, dry free tropospheric air into the ML.

  7. Models of the atmospheric water vapor budget for the Texas HIPLEX area: by Steven Francis Williams.

    E-Print Network [OSTI]

    Williams, Steven Francis

    1979-01-01T23:59:59.000Z

    co:erage cf. convective activ' ty, Thus, the em&unt of convection seems to be more important than the type oz pr"se. . ce of convective activi!y. An increased tran:port of water vapor near ti e surface is -hown to be an important factor... of watc-. z vapor tnrough each later, l boundary shown in Fig. 1 can be comput d by substituting Eqs. (16) ? (19), reaper tively, into Eq. (14) . Th ' net transport of water vapor 'nt the volume through la+eral oouccdaries or t?:e net horizontal tran:;port...

  8. Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface Radar and Satellite Data in Support of ARM SCM Activities

    SciTech Connect (OSTI)

    Liu, Guosheng

    2013-03-15T23:59:59.000Z

    Single-column modeling (SCM) is one of the key elements of Atmospheric Radiation Measurement (ARM) research initiatives for the development and testing of various physical parameterizations to be used in general circulation models (GCMs). The data required for use with an SCM include observed vertical profiles of temperature, water vapor, and condensed water, as well as the large-scale vertical motion and tendencies of temperature, water vapor, and condensed water due to horizontal advection. Surface-based measurements operated at ARM sites and upper-air sounding networks supply most of the required variables for model inputs, but do not provide the horizontal advection term of condensed water. Since surface cloud radar and microwave radiometer observations at ARM sites are single-point measurements, they can provide the amount of condensed water at the location of observation sites, but not a horizontal distribution of condensed water contents. Consequently, observational data for the large-scale advection tendencies of condensed water have not been available to the ARM cloud modeling community based on surface observations alone. This lack of advection data of water condensate could cause large uncertainties in SCM simulations. Additionally, to evaluate GCMsâ�� cloud physical parameterization, we need to compare GCM results with observed cloud water amounts over a scale that is large enough to be comparable to what a GCM grid represents. To this end, the point-measurements at ARM surface sites are again not adequate. Therefore, cloud water observations over a large area are needed. The main goal of this project is to retrieve ice water contents over an area of 10 x 10 deg. surrounding the ARM sites by combining surface and satellite observations. Built on the progress made during previous ARM research, we have conducted the retrievals of 3-dimensional ice water content by combining surface radar/radiometer and satellite measurements, and have produced 3-D cloud ice water contents in support of cloud modeling activities. The approach of the study is to expand a (surface) point measurement to an (satellite) area measurement. That is, the study takes the advantage of the high quality cloud measurements (particularly cloud radar and microwave radiometer measurements) at the point of the ARM sites. We use the cloud ice water characteristics derived from the point measurement to guide/constrain a satellite retrieval algorithm, then use the satellite algorithm to derive the 3-D cloud ice water distributions within an 10�° (latitude) x 10�° (longitude) area. During the research period, we have developed, validated and improved our cloud ice water retrievals, and have produced and archived at ARM website as a PI-product of the 3-D cloud ice water contents using combined satellite high-frequency microwave and surface radar observations for SGP March 2000 IOP and TWP-ICE 2006 IOP over 10 deg. x 10 deg. area centered at ARM SGP central facility and Darwin sites. We have also worked on validation of the 3-D ice water product by CloudSat data, synergy with visible/infrared cloud ice water retrievals for better results at low ice water conditions, and created a long-term (several years) of ice water climatology in 10 x 10 deg. area of ARM SGP and TWP sites and then compared it with GCMs.

  9. Application of Computational Fluid Dynamics in the Forced Dispersion Modeling of LNG Vapor Clouds 

    E-Print Network [OSTI]

    Kim, Byung-Kyu

    2013-05-31T23:59:59.000Z

    droplet-LNG vapor system, which will serve in developing guidelines and establishing engineering criteria for a site-specific LNG mitigation system. Finally, the potentials of applying CFD modeling in providing guidance for setting up the design criteria...

  10. HYDROLOGY, HYDROCHEMISTRY AND IMPLICATIONS FOR WATER SUPPLY OF A CLOUD FOREST IN CENTRAL AMERICA

    E-Print Network [OSTI]

    Walter, M.Todd

    HYDROLOGY, HYDROCHEMISTRY AND IMPLICATIONS FOR WATER SUPPLY OF A CLOUD FOREST IN CENTRAL AMERICA Alonso Caballero #12;HYDROLOGY, HYDROCHEMISTRY AND IMPLICATIONS FOR WATER SUPPLY OF A CLOUD FOREST and dry periods. Consequently, the tropical hydrology of cloud-forest watersheds is not well studied

  11. 1 DECEMBER 1995 Validation of Satellite Retrievals of Cloud Microphysics and Liquid Water Path

    E-Print Network [OSTI]

    Han, Quingyuan

    1 DECEMBER 1995 Validation of Satellite Retrievals of Cloud Microphysics and Liquid Water Path Using Observations from FIRE 1, Introduction Q. HAN, * W. Rossow, t R. WELCH, * A. WHITE, * * AND J Cloud effective radii (r) and cloud liquid water path (LWP) are derived from ISCCP spatially sampled

  12. Estimate of the global distribution of stratiform supercooled liquid water clouds using the LITE lidar

    E-Print Network [OSTI]

    Hogan, Robin

    them to generally have a greater effect on the net radiative fluxes than any ice clouds in the profileEstimate of the global distribution of stratiform supercooled liquid water clouds using the LITE layers that have a much larger radiative impact than ice clouds of the same water content because

  13. Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated

    E-Print Network [OSTI]

    Cal, Mark P.

    Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated Activated Carbon treated cloths exhibit high adsorption capacities for water (0.5-0.67 m u g of fiber) and 100% desorption upon heating to 100 "C. The untreated and treated ACCBO samples exhibited no degradation upon heating

  14. Water Vapor and Mechanical Work: A Comparison of Carnot and Steam Cycles OLIVIER PAULUIS

    E-Print Network [OSTI]

    Pauluis, Olivier M.

    Water Vapor and Mechanical Work: A Comparison of Carnot and Steam Cycles OLIVIER PAULUIS Center in the atmosphere is discussed here by comparing two idealized heat engines: the Carnot cycle and the steam cycle. A steam cycle transports water from a warm moist source to a colder dryer sink. It acts as a heat engine

  15. Water absorption in Galactic translucent clouds: conditions and history of the gas derived from Herschel/HIFI PRISMAS observations

    E-Print Network [OSTI]

    Flagey, N; Lis, D C; Gerin, M; Neufeld, D; Sonnentrucker, P; De Luca, M; Godard, B; Goicoechea, J R; Monje, R; Phillips, T G

    2012-01-01T23:59:59.000Z

    We present Herschel/HIFI observations of nine transitions of \\hho and \\hheo towards six high-mass star-forming regions, obtained as part of the PRISMAS Key Program. Water vapor in translucent clouds is detected in absorption along every sightline. We derive the column density of \\hho or \\hheo for the lower energy level of each transition observed. The total water column density is about a few $10^{13} \\rm{cm^{-2}}$. We find that the abundance of water relative to hydrogen nuclei is $1\\times10^{-8}$ in agreement with models for oxygen chemistry with high cosmic ray ionization rates. Relative to \\hh, the abundance of water is remarkably constant at $5\\times10^{-8}$. The abundance of water in excited levels is at most 15%, implying that the excitation temperature $T_{ex}$ in the ground state transitions is below 10 K. The column densities derived from the two ortho ground state transitions indicates that $T_{ex}\\simeq5$ K and that the density $n($\\hh$)$ in the clouds is $\\le10^4 \\rm{cm^{-3}}$. For most clouds we...

  16. Adsorption of water vapor on reservoir rocks. First quarterly report, January--March 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-01T23:59:59.000Z

    Progress is reported on: adsorption of water vapor on reservoir rocks; theoretical investigation of adsorption; estimation of adsorption parameters from transient experiments; transient adsorption experiment -- salinity and noncondensible gas effects; the physics of injection of water into, transport and storage of fluids within, and production of vapor from geothermal reservoirs; injection optimization at the Geysers Geothermal Field; a model to test multiwell data interpretation for heterogeneous reservoirs; earth tide effects on downhole pressure measurements; and a finite-difference model for free surface gravity drainage well test analysis.

  17. Materials, methods and devices to detect and quantify water vapor concentrations in an atmosphere

    DOE Patents [OSTI]

    Allendorf, Mark D; Robinson, Alex L

    2014-12-09T23:59:59.000Z

    We have demonstrated that a surface acoustic wave (SAW) sensor coated with a nanoporous framework material (NFM) film can perform ultrasensitive water vapor detection at concentrations in air from 0.05 to 12,000 ppmv at 1 atmosphere pressure. The method is extendable to other MEMS-based sensors, such as microcantilevers, or to quartz crystal microbalance sensors. We identify a specific NFM that provides high sensitivity and selectivity to water vapor. However, our approach is generalizable to detection of other species using NFM to provide sensitivity and selectivity.

  18. airs water vapor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dissertations Summary: ??Soils are complex environments comprising various biological (roots, water, air etc) and physical constituents (minerals, aggregates, etc). Synchrotron...

  19. ARM - Field Campaign - Fall 1997 Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8LigovCampaignsCLEX-5govCampaignsFall 1997 Cloud IOP

  20. Validation of TES Temperature and Water Vapor Retrievals with ARM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsing Maps toValidatingCloud PropertiesObservations

  1. A NORMETEX MODEL 15 M3/HR WATER VAPOR PUMPING TEST

    SciTech Connect (OSTI)

    Klein, J.; Fowley, M.; Steeper, T.

    2010-12-20T23:59:59.000Z

    Tests were performed using a Model 15 m{sup 3}/hr Normetex vacuum pump to determine if pump performance degraded after pumping a humid gas stream. An air feed stream containing 30% water vapor was introduced into the pump for 365 hours with the outlet pressure of the pump near the condensation conditions of the water. Performance of the pump was tested before and after the water vapor pumping test and indicated no loss in performance of the pump. The pump also appeared to tolerate small amounts of condensed water of short duration without increased noise, vibration, or other adverse indications. The Normetex pump was backed by a dual-head diaphragm pump which was affected by the condensation of water and produced some drift in operating conditions during the test.

  2. Time domain measurement of the THz refractivity of water vapor

    E-Print Network [OSTI]

    Oklahoma State University

    region," Metrologia 18(2), 49­52 (1982). 7. R. J. Hill and R. S. Lawrence, "Refractive index of water

  3. Orbital apocenter is not a sufficient condition for HST/STIS detection of Europa's water vapor aurora

    E-Print Network [OSTI]

    Nimmo, Francis

    aurora Lorenz Rotha,b,1 , Kurt D. Retherforda , Joachim Saurc , Darrell F. Strobeld,e , Paul D. Feldmane that the discovery of a water vapor aurora in Decem- ber 2012 by local hydrogen (H) and oxygen (O) emissions by our 2014 STIS observations. Europa | Hubble Space Telescope | aurora | water vapor plumes | Jupiter

  4. IUPAC critical evaluation of the rotationalvibrational spectra of water vapor. Part I--Energy levels and transition wavenumbers

    E-Print Network [OSTI]

    Chance, Kelly

    Keywords: Water vapor Transition wavenumbers Atmospheric physics Energy levels MARVEL Information systemIUPAC critical evaluation of the rotational­vibrational spectra of water vapor. Part I--Energy levels and transition wavenumbers for H2 17 O and H2 18 O Jonathan Tennyson a,Ă, Peter F. Bernath b

  5. The role of water vapor and solar radiation in determining temperature changes and trends measured at Armagh, 18812000

    E-Print Network [OSTI]

    The role of water vapor and solar radiation in determining temperature changes and trends measured in atmospheric circulation, are discussed. Citation: Stanhill, G. (2011), The role of water vapor and solar radiation in determining temperature changes and trends measured at Armagh, 1881­2000, J. Geophys. Res., 116

  6. Water vapor on supergiants. The 12 micron TEXES spectra of mu Cephei

    E-Print Network [OSTI]

    N. Ryde; M. J. Richter; G. M. Harper; K. Eriksson; D. L. Lambert

    2006-03-15T23:59:59.000Z

    Several recent papers have argued for warm, semi-detached, molecular layers surrounding red giant and supergiant stars, a concept known as a MOLsphere. Spectroscopic and interferometric analyses have often corroborated this general picture. Here, we present high-resolution spectroscopic data of pure rotational lines of water vapor at 12 microns for the supergiant mu Cephei. This star has often been used to test the concept of molecular layers around supergiants. Given the prediction of an isothermal, optically thick water-vapor layer in Local Thermodynamic Equilibrium around the star (MOLsphere), we expected the 12 micron lines to be in emission or at least in absorption but filled in by emission from the molecular layer around the star. Our data, however, show the contrary; we find definite absorption. Thus, our data do not easily fit into the suggested isothermal MOLsphere scenario. The 12 micron lines, therefore, put new, strong constraints on the MOLsphere concept and on the nature of water seen in signatures across the spectra of early M supergiants. We also find that the absorption is even stronger than that calculated from a standard, spherically symmetric model photosphere without any surrounding layers. A cool model photosphere, representing cool outer layers is, however, able to reproduce the lines, but this model does not account for water vapor emission at 6 microns. Thus, a unified model for water vapor on mu Cephei appears to be lacking. It does seem necessary to model the underlying photospheres of these supergiants in their whole complexity. The strong water vapor lines clearly reveal inadequacies of classical model atmospheres.

  7. Water vapor transport in the vicinity of imbibing saline plumes: Homogeneous and layered unsaturated porous media

    E-Print Network [OSTI]

    Weisbrod, Noam

    solutions (brines) were applied as point sources to the surface of homogenous packs of prewetted silica sand vapor transport from the residually saturated sand into the imbibing brine was observed in all sand grades and geometries. Pure water applied to sand prewetted with brine migrated into the surrounding

  8. IUPAC critical evaluation of the rotationalvibrational spectra of water vapor, Part III: Energy levels and transition

    E-Print Network [OSTI]

    Chance, Kelly

    rotational­ vibrational line positions, transition intensities, and energy levels, with associated critically. These transitions give rise to 18 486 validated energy levels, of which 10 446 and 8040 belong to o-H2 16 O and p-H2IUPAC critical evaluation of the rotational­vibrational spectra of water vapor, Part III: Energy

  9. IUPAC Critical Evaluation of the Rotational-Vibrational Spectra of Water Vapor. Part II.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , transition wavenumbers, atmospheric physics, energy levels, MARVEL, information system, database, WIUPAC Critical Evaluation of the Rotational-Vibrational Spectra of Water Vapor. Part II. Energy Kingdom c Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, U.S.A. d Universit

  10. IUPAC critical evaluation of the rotationalvibrational spectra of water vapor. Part II

    E-Print Network [OSTI]

    Chance, Kelly

    Atmospheric physics Energy levels MARVEL Information system Database W@DIS Infrared spectra Microwave spectraIUPAC critical evaluation of the rotational­vibrational spectra of water vapor. Part II Energy, York, UK c Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA d

  11. Water vapor variability in the tropics and its links to dynamics and precipitation

    E-Print Network [OSTI]

    Allan, Richard P.

    dioxide doubling [e.g., Intergovernmental Panel on Climate Change (IPCC), 2001]. This uncertainty stems P. P. Shirshov Institute of Oceanology, Russian Academy of Sciences, Moscow, Russia Richard P. Allan to understanding feedbacks and processes operating within the climate system. Column-integrated water vapor (CWV

  12. investigating the source, transport, and isotope fractionation of water vapor in the atmospheric boundary layer

    E-Print Network [OSTI]

    Minnesota, University of

    investigating the source, transport, and isotope fractionation of water vapor in the atmospheric-portable mixing ratio generator and Rayleigh distillation device, Agricultural and Forest Meteorology, 150, 1607 ratio generator. Incom- ing dry air passes through a molecular sieve and then a stainless steel frit (a

  13. GEOSTAR-II: A PROTOTYPE WATER VAPOR IMAGER/SOUNDER FOR THE PATH Todd Gaier1

    E-Print Network [OSTI]

    Ruf, Christopher

    GEOSTAR-II: A PROTOTYPE WATER VAPOR IMAGER/SOUNDER FOR THE PATH MISSION Todd Gaier1 , Bjorn the as yet undefined mission requirements. By far the most stringent "requirement" is the recovery. The IF signals are routed to a correlator unit on coaxial cables. The system is not designed to provide full

  14. Summary Weusedthreemethodstomeasureboundarylayer conductance to heat transfer (gbH) and water vapor transfer

    E-Print Network [OSTI]

    Martin, Timothy

    Summary Weusedthreemethodstomeasureboundarylayer conductance to heat transfer (gbH) and water vapor of transpiration). The boundary layer conductance to heat transfer is small enough that leaf temperature can become diffusion, the boundary layer around a leaf also provides resistance to the transfer of heat between a leaf

  15. Measurement of Water Vapor Concentration using Tunable Diode Laser Absorption Spectroscopy

    E-Print Network [OSTI]

    Barrett, Alexander B.

    2010-07-14T23:59:59.000Z

    Tunable diode laser spectroscopy and the Beer-Lambert relation has been used to measure the absorption of water vapor both in an absorption cell and in a shock tube. The purpose of this thesis is to develop a laser diagnostic capable of determining...

  16. Clarifying the Dominant Sources and Mechanisms of Cirrus Cloud Formation

    E-Print Network [OSTI]

    Cziczo, Daniel James

    Formation of cirrus clouds depends on the availability of ice nuclei to begin condensation of atmospheric water vapor. Although it is known that only a small fraction of atmospheric aerosols are efficient ice nuclei, the ...

  17. Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn Other NewsSpin andInterim DataCooling -INTEGRATINGIntegration

  18. Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement

    E-Print Network [OSTI]

    Tong, Yunwei

    2013-11-08T23:59:59.000Z

    aggregate contact due to dust particles on the aggregate surface. The rupture may occur because of the construction loads and operating traffic during construction, or could be environmentally induced by freeze-thaw cycling. Once a break in the film... design, environment and traffic, can be defined as progressive degradation of asphalt mixture material due to the presence of water. The occurrence of moisture damage in asphalt material is a rather complex phenomenon, which involves chemical, physical...

  19. Vapor-liquid equilibria of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems

    SciTech Connect (OSTI)

    Mun, S.Y.; Lee, H.

    1999-12-01T23:59:59.000Z

    Vapor-liquid equilibrium data of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems were measured at 60, 160, 300, and 760 mmHg at temperatures ranging from 315 to 488 K. The apparatus used in this work is a modified still especially designed for the measurement of low-pressure VLE, in which both liquid and vapor are continuously recirculated. For the analysis of salt-containing solutions, a method incorporating refractometry and gravimetry was used. From the experimental measurements, the effect of lithium bromide on the VLE behavior of water + 1,3-propanediol was investigated. The experimental data of the salt-free system were successfully correlated using the Wilson, NRTL, and UNIQUAC models. In addition, the extended UNIQUAC model of Sander et al. was applied to the VLE calculation of salt-containing mixtures.

  20. Calculation of the Dimer Equilibrium Constant of Heavy Water Saturated Vapor

    E-Print Network [OSTI]

    L. A. Bulavin; S. V. Khrapatiy; V. N. Makhlaichuk

    2015-03-13T23:59:59.000Z

    Water is the most common substance on Earth.The discovery of heavy water and its further study have shown that the change of hydrogen for deuterium leads to the significant differences in their properties.The triple point temperature of heavy water is higher,at the same time the critical temperature is lower.Experimental values of the second virial coefficient of the EOS for the vapor of normal and heavy water differ at all temperatures.This fact can influence the values of the dimerization constant for the heavy water vapor.The equilibrium properties of the dimerization process are described with the methods of chemical thermodynamics.The chemical potentials for monomers (m) and dimers (d)are the functions of their concentrations.The interactions of monomer-dimer and dimer-dimer types are taken into account within the solution of equation for chemical potentials.The obtained expression for the dimerization constant contains the contributions of these types.The averaged potentials are modeled by the Sutherland potential.Theoretical values of the dimerization constant for the heavy water vapor at different temperatures are compared to those for normal water.We see the exceeding of the values for the heavy water at all temperatures.This fact is in good agreement with all experimental data that is available.The excess is related to the differences in the character of the heat excitations of the dimers of normal and heavy water,their rotational constants and energy of their vibrational excitations.Significant role is also played by the monomer-dimer and dimer-dimer interactions.

  1. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single Family Homes (Revised)

    SciTech Connect (OSTI)

    Cummings, J.; Withers, C.; Martin, E.; Moyer, N.

    2012-10-01T23:59:59.000Z

    This document focuses on managing the driving forces which move air and moisture across the building envelope. While other previously published Measure Guidelines focus on elimination of air pathways, the ultimate goal of this Measure Guideline is to manage drivers which cause air flow and water vapor transport across the building envelope (and also within the home), control air infiltration, keep relative humidity (RH) within acceptable limits, avoid combustion safety problems, improve occupant comfort, and reduce house energy use.

  2. Response of water vapor to interannual variations of SST: Results from NCAR Community Climate Model (CCM2)

    SciTech Connect (OSTI)

    Sun, De-Zheng [National Center For Atmospheric Research, Boulder, CO (United States)

    1997-11-01T23:59:59.000Z

    This paper very briefly documents the response of water vapor to interannual changes in sea surface temperature (SST) in two of the most frequently used climate models: the National Center for Atmospheric Research (NCAR) community climate model (CCM2) and the GFDL spectral model (R30). The corresponding results from radiosonde data are also presented for reference. A simple linear regression model is used to quantify the response of water vapor to changes in SST in the two simulations. Except for the negative response of water vapor over Australia, CCM2 simulates the major characteristics in the horizontal structure of the water vapor response shown in the radiosonde data. The negative response of water over Australia is also not well simulated by GFDL R30. In addition, GFDL R30 significantly underestimates the positive response over the Indian Ocean. The horizontal contrasts between the negative response over the western Pacific and the positive response over the central and eastern Pacific in the model simulations are larger than in the radiosonde data. The negative response in the subtropical region in CCM2 is more pronounced than in R30. Averaged over the tropics, CCM2 has a larger water vapor response in both the boundary layer and the upper troposphere than R30. The correlations between variations of water vapor in the upper troposphere and those at the surface level are also stronger in CCM2 than in R30. 2 refs., 5 figs.

  3. Orographic Precipitation and Water Vapor Fractionation over the Southern Andes RONALD B. SMITH AND JASON P. EVANS

    E-Print Network [OSTI]

    Evans, Jason

    Orographic Precipitation and Water Vapor Fractionation over the Southern Andes RONALD B. SMITH (Smith and Barstad 2004) to predict the patterns of orographic pre- Corresponding author address: Ronald B. Smith, Depa

  4. Calculation of the Dimer Equilibrium Constant of Heavy Water Saturated Vapor

    E-Print Network [OSTI]

    Bulavin, L A; Makhlaichuk, V N

    2015-01-01T23:59:59.000Z

    Water is the most common substance on Earth.The discovery of heavy water and its further study have shown that the change of hydrogen for deuterium leads to the significant differences in their properties.The triple point temperature of heavy water is higher,at the same time the critical temperature is lower.Experimental values of the second virial coefficient of the EOS for the vapor of normal and heavy water differ at all temperatures.This fact can influence the values of the dimerization constant for the heavy water vapor.The equilibrium properties of the dimerization process are described with the methods of chemical thermodynamics.The chemical potentials for monomers (m) and dimers (d)are the functions of their concentrations.The interactions of monomer-dimer and dimer-dimer types are taken into account within the solution of equation for chemical potentials.The obtained expression for the dimerization constant contains the contributions of these types.The averaged potentials are modeled by the Sutherlan...

  5. Effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water

    SciTech Connect (OSTI)

    Polka, H.M.; Gmehling, J. (Univ. of Oldenburg (Germany). Chair of Industrial Chemistry)

    1994-07-01T23:59:59.000Z

    The effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water was studied using a Swietoslawski ebulliometer. The measurements were performed for two constant salt molalities (1 and 2 mol[center dot]kg[sup [minus]1]) under isobaric conditions at 50.66 kPa. Strong salting-out of the alcohol was observed in all cases, leading to a complete elimination of the azeotropic point at relatively low salt concentrations. The results were correlated using an extension of the NRTL equation for mixed solvent electrolyte systems proposed by Mock, Evans, and Chen.

  6. Evaluating specific error characteristics of microwave-derived cloud liquid water products

    E-Print Network [OSTI]

    Christopher, Sundar A.

    of cloud LWP products globally using concurrent data from visible/ infrared satellite sensors. The approachEvaluating specific error characteristics of microwave-derived cloud liquid water products Thomas J microwave satellite measurements. Using coincident visible/infrared satellite data, errors are isolated

  7. Use of airs and modis thermal infrared channels to retrieve ice cloud properties

    E-Print Network [OSTI]

    Yost, Christopher Rogers

    2007-04-25T23:59:59.000Z

    In this study, we use thermal infrared channels to retrieve the optical thickness and effective particle radius of ice clouds. A physical model is used in conjunction with Atmospheric Infrared Sounder (AIRS) temperature and water vapor profiles...

  8. Use of airs and modis thermal infrared channels to retrieve ice cloud properties 

    E-Print Network [OSTI]

    Yost, Christopher Rogers

    2007-04-25T23:59:59.000Z

    In this study, we use thermal infrared channels to retrieve the optical thickness and effective particle radius of ice clouds. A physical model is used in conjunction with Atmospheric Infrared Sounder (AIRS) temperature and water vapor profiles...

  9. New Mexico cloud super cooled liquid water survey final report 2009.

    SciTech Connect (OSTI)

    Beavis, Nick; Roskovensky, John K.; Ivey, Mark D.

    2010-02-01T23:59:59.000Z

    Los Alamos and Sandia National Laboratories are partners in an effort to survey the super-cooled liquid water in clouds over the state of New Mexico in a project sponsored by the New Mexico Small Business Assistance Program. This report summarizes the scientific work performed at Sandia National Laboratories during the 2009. In this second year of the project a practical methodology for estimating cloud super-cooled liquid water was created. This was accomplished through the analysis of certain MODIS sensor satellite derived cloud products and vetted parameterizations techniques. A software code was developed to analyze multiple cases automatically. The eighty-one storm events identified in the previous year effort from 2006-2007 were again the focus. Six derived MODIS products were obtained first through careful MODIS image evaluation. Both cloud and clear-sky properties from this dataset were determined over New Mexico. Sensitivity studies were performed that identified the parameters which most influenced the estimation of cloud super-cooled liquid water. Limited validation was undertaken to ensure the soundness of the cloud super-cooled estimates. Finally, a path forward was formulized to insure the successful completion of the initial scientific goals which include analyzing different of annual datasets, validation of the developed algorithm, and the creation of a user-friendly and interactive tool for estimating cloud super-cooled liquid water.

  10. Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-11-01T23:59:59.000Z

    A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

  11. Trace water vapor determination in nitrogen and corrosive gases using infrared spectroscopy

    SciTech Connect (OSTI)

    Espinoza, L.H.; Niemczyk, T.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry; Stallard, B.R.; Garcia, M.J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-06-01T23:59:59.000Z

    The generation of particles in gas handling systems as a result of corrosion is a major concern in the microelectronics industry. The corrosion can be caused by the presence of trace quantities of water in corrosive gases such as HCl or HBr. FTIR spectroscopy has been shown to be a method that can be made compatible with corrosive gases and is capable of detecting low ppb levels of water vapor. In this report, the application of FTIR spectroscopy combined with classical least squares multivariate calibration to detect trace H{sub 2}O in N{sub 2}, HCl and HBr is discussed. Chapter 2 discusses the gas handling system and instrumentation required to handle corrosive gases. A method of generating a background spectrum useful to the measurements discussed in this report, as well as in other application areas such as gas phase environmental monitoring, is discussed in Chapter 3. Experimental results obtained with the first system are presented in Chapter 4. Those results made it possible to optimize the design options for the construction of a dedicate system for low ppb water vapor determination. These designs options are discussed in Chapter 5. An FTIR prototype accessory was built. In addition, a commercially available evacuable FTIR system was obtained for evaluation. Test results obtained with both systems are discussed in Chapter 6. Experiments dealing with the interaction between H{sub 2}O-HCl and potential improvements to the detection system are discussed in Chapter 7.

  12. In-reactor oxidation of zircaloy-4 under low water vapor pressures

    SciTech Connect (OSTI)

    Walter G. Luscher; David J. Senor; Keven K. Clayton; Glen R. Longhurst

    2015-01-01T23:59:59.000Z

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370 C). Data from these tests will be used to support the fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr- 4 over the specified range of test conditions. Comparisons between in- and ex-reactor test results were performed to evaluate the influence of irradiation.

  13. In-Reactor Oxidation of Zircaloy-4 Under Low Water Vapor Pressures

    SciTech Connect (OSTI)

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin; Longhurst, Glen

    2015-01-01T23:59:59.000Z

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330° and 370°C). Data from these tests will be used to support fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr-4 over the specified range of test conditions. Comparisons between in- and ex- reactor test results were performed to evaluate the influence of irradiation.

  14. Method of condensing vaporized water in situ to treat tar sands formations

    DOE Patents [OSTI]

    Hsu, Chia-Fu (Rijswijk, NL)

    2010-03-16T23:59:59.000Z

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  15. An Assessment of the Parameterization of Subgrid-Scale Cloud Effects on Radiative Transfer. Part II: Horizontal Inhomogeneity

    E-Print Network [OSTI]

    Stephens, Graeme L.

    in downwelling radiative fluxes at the surface induced by changes in cloud cover and water vapor distributions. 1An Assessment of the Parameterization of Subgrid-Scale Cloud Effects on Radiative Transfer. Part II form 5 January 2005) ABSTRACT The role of horizontal inhomogeneity in radiative transfer through cloud

  16. Indian Summer Monsoon Drought 2009: Role of Aerosol and Cloud Microphysics

    SciTech Connect (OSTI)

    Hazra, Anupam; Taraphdar, Sourav; Halder, Madhuparna; Pokhrel, S.; Chaudhari, H. S.; Salunke, K.; Mukhopadhyay, P.; Rao, S. A.

    2013-07-01T23:59:59.000Z

    Cloud dynamics played a fundamental role in defining Indian summer monsoon (ISM) rainfall during drought in 2009. The anomalously negative precipitation was consistent with cloud properties. Although, aerosols inhibited the growth of cloud effective radius in the background of sparse water vapor, their role is secondary. The primary role, however, is played by the interactive feedback between cloud microphysics and dynamics owing to reduced efficient cloud droplet growth, lesser latent heating release and shortage of water content. Cloud microphysical processes were instrumental for the occurrence of ISM drought 2009.

  17. Electrical, optical, and material characterizations of blue InGaN light emitting diodes submitted to reverse-bias stress in water vapor condition

    SciTech Connect (OSTI)

    Chen, Hsiang, E-mail: hchen@ncnu.edu.tw; Chu, Yu-Cheng; Chen, Yun-Ti; Chen, Chian-You [Department of Applied Materials and Optoelectronic Engineering, National Chi Nan University, No. 1, University Road, Puli, Nantou County 54561, Taiwan (China); Shei, Shih-Chang [Department of Electrical Engineering, National University of Tainan, No.33, Sec. 2, Shulin St., West Central Dist., Tainan City 70005, Taiwan (China)

    2014-09-07T23:59:59.000Z

    In this paper, we investigate degradation of InGaN/GaN light emitting diodes (LEDs) under reverse-bias operations in water vapor and dry air. To examine failure origins, electrical characterizations including current-voltage, breakdown current profiles, optical measurement, and multiple material analyses were performed. Our findings indicate that the diffusion of indium atoms in water vapor can expedite degradation. Investigation of reverse-bias stress can help provide insight into the effects of water vapor on LEDs.

  18. Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle

    SciTech Connect (OSTI)

    Hosni, Mohammad H.

    2014-03-30T23:59:59.000Z

    Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerant’s pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development of the cycle and have gained an in-depth understanding of the governing fundamental knowledge, based on the laws of physics and thermodynamics and verified with our testing results. Through this research, we are identifying optimal working fluid and operating conditions to eventually demonstrate the core technology for space cooling or other applications.

  19. Microphysical Properties of Clouds with Low Liquid Water Paths: An Update from Clouds with Low Optical (Water) Depth

    SciTech Connect (OSTI)

    Turner, D.D.; Flynn, C.; Long, C.; McFarlane, S.; Vogelmann, A.; Johnson, K.; Miller, M.; Chiu, C.; Marshak, A.; Wiscombe, W.; Clough, S.A.; Heck, P.; Minnis, P.; Liljegren, J.; Min, Q.; O'Hirok, W.; Wang, Z.

    2005-03-18T23:59:59.000Z

    Clouds play a critical role in the modulation of the radiative transfer in the atmosphere, and how clouds interact with radiation is one of the primary uncertainties in global climate models (GCMs). To reduce this uncertainty, the U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) program collects an immense amount of data from its Climate Research Facilities (CRFs); these data include observations of radiative fluxes, cloud properties from active and passive remote sensors, upper atmospheric soundings, and other observations. The program's goal is to use these coincident, longterm observations to improve the parameterization of radiative transfer in clear and cloudy atmospheres in GCMs.

  20. A model of vapor-liquid equilibria for acid gas-alkanolamine-water systems

    SciTech Connect (OSTI)

    Austgen, D.M. Jr.

    1989-01-01T23:59:59.000Z

    A physico-chemical model was developed for representing liquid phase chemical equilibria and vapor-liquid (phase) equilibria of H{sub 2}SCO{sub 2}-alkanolamine-water systems. The equilibrium composition of the liquid phase is determined by minimization of the Gibbs free energy. Activity coefficients are represented with the Electrolyte-NRTL equation treating both long-range electrostatic interactions and short-range binary interactions between liquid phase species. Vapor phase fugacity coefficients are calculated using the Redlich-Kwong-Soave Equation of State. Adjustable parameters of the model, binary interaction parameters and carbamate stability constants, were fitted on published binary system alkanolamine-water and ternary system (H{sub 2}S-alkanolamine-water, CO{sub 2}-alkanolamine-water) VLE data. The Data Regression System of ASPEN PLUS, based upon the Maximum Likelihood Principle, was used to estimate adjustable parameters. Ternary system measurements used in parameter estimation ranged in temperature from 25 to 120{degree}C in alkanolamine concentration from 1 to 5 M, in acid gas loading from 0 to 1.5 moles per mole alkanolamine, and in acid gas partial pressure from 0.1 to 1,000 kPa. Maximum likelihood estimates of ternary system H{sub 2} or CO{sub 2} equilibrium partial pressures and liquid phase concentrations were found to be in good agreement with measurements for aqueous solutions of monoethanolamine (MEA), diethanolamine (DEA), diglycolamine (DGA), and methyldiethanolamine (MDEA) indicating that the model successfully represents ternary system data. The model was extended to represent CO{sub 2} solubility in aqueous mixtures of MDEA with MEA or DEA. The solubility was measured at 40 and 80{degree}C over a wide range of CO{sub 2} partial pressures. These measurements were used to estimate additional binary parameters of the mixed solvent systems.

  1. Moisture effects in low-slope roofs: Drying rates after water addition with various vapor retarders

    SciTech Connect (OSTI)

    Pedersen, C.R. [Technical Univ. of Denmark, Lyngby (Denmark); Petrie, T.W. [Marquette Univ., Milwaukee, WI (United States). Dept. of Mechanical Engineering; Courville, G.E.; Desjarlais, A.O.; Childs, P.W.; Wilkes, K.E. [Oak Ridge National Lab., TN (United States)

    1992-10-01T23:59:59.000Z

    Tests have been conducted in the Large Scale Climate Simulator (LSCS) of the US. Building Envelope Research Center at the Oak Ridge National Laboratory (ORNL) to investigate downward drying rates of various unvented, low-slope roof systems. A secondary objective was to study heat flow patterns so as to understand how to control latent heat effects on impermeable heat flux transducers. Nine test sections were tested simultaneously. The sections had a p deck above fibrous-glass insulation and were examples of cold-deck systems. These five sections had various vapor retarder systems on a gypsum board ceiling below the insulation. The other four sections had a lightweight insulating concrete deck below expanded polystyrene insulation and the same vapor retarder systems, and were examples of warm-deck systems. The cold-deck systems had materials that were relatively permeable to water vapor, while the materials in the warm-deck systems were less permeable. All test sections were topped by an impermeable roofing membrane. The test sections were instrumented with thermocouples between all layers and with small heat flux transducers at the bottom and top of the fibrous-glass insulation and in the middle of the expanded polystyrene insulation. Two different kinds of moisture probes were used to qualitatively monitor the movement of the moisture. The heat flux measurements showed that heat conduction dominates the system using impermeable insulation materials, with only a slight increase due to increased thermal conductivity of wet expanded polystyrene. There was significant transfer of latent heat in the test sections with permeable insulation, causing the peak heat fluxes to increase by as much as a factor of two. With temperatures imposed that are typical of summer days, latent heat transfer associated with condensation and evaporation of moisture in the test sections was measured to be as important as the heat transfer by conduction.

  2. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01T23:59:59.000Z

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR�¢����s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument�¢����s robustness in a real-world situation.

  3. THE INFLUENCE OF CLOUD PROCESSES ON THE DISTRIBUTION OF CHEMICAL SPECIES FOR THE 10 JULY 1996 STERAO/DEEP CONVECTION STORM

    E-Print Network [OSTI]

    Stuart, Amy L.

    - tenuation of solar radiation. The cloud hydromete- ors may serve as locations for aqueous and ice-phase be captured by the precipitating ice particles. Photolysis rates are altered by the scattering and at vapor, cloud water, rain, cloud ice, snow, grau- pel or hail, and scalars. A second order Runge

  4. A comparison of water vapor quantities from model short-range forecasts and ARM observations

    SciTech Connect (OSTI)

    Hnilo, J J

    2006-03-17T23:59:59.000Z

    Model evolution and improvement is complicated by the lack of high quality observational data. To address a major limitation of these measurements the Atmospheric Radiation Measurement (ARM) program was formed. For the second quarter ARM metric we will make use of new water vapor data that has become available, and called the 'Merged-sounding' value added product (referred to as OBS, within the text) at three sites: the North Slope of Alaska (NSA), Darwin Australia (DAR) and the Southern Great Plains (SGP) and compare these observations to model forecast data. Two time periods will be analyzed March 2000 for the SGP and October 2004 for both DAR and NSA. The merged-sounding data have been interpolated to 37 pressure levels (e.g., from 1000hPa to 100hPa at 25hPa increments) and time averaged to 3 hourly data for direct comparison to our model output.

  5. The Effect of Water Vapor on Cr Depletion in Advanced Recuperator Alloys

    SciTech Connect (OSTI)

    Pint, Bruce A [ORNL

    2005-01-01T23:59:59.000Z

    Durable alloy foils are needed for gas turbine recuperators operating at 650--700 C. It has been established that water vapor in the exhaust gas causes more rapid consumption of Cr in austenitic stainless steels leading to a reduction in operating lifetime of these thin-walled components. Laboratory testing at 650--800 C of commercial and model alloys is being used to develop a better understanding of the long-term rate of Cr consumption in these environments. Results are presented for commercial alloys 709, 120 and 625. After 10,000h exposures at 650 C and 700 C in humid air, grain boundary Cr depletion was observed near the surface of all these materials. In the Fe-base alloys, 709 and 120, this depletion led to localized Fe-rich nodule formation. This information then can be used to develop low-cost alternatives to currently available candidate materials.

  6. Treatment of Produced Water Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Lynn E. Katz; Kerry A. Kinney; Robert S. Bowman; Enid J. Sullivan; Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Craig R. Altare

    2006-01-31T23:59:59.000Z

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. Produced waters typically contain a high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component as well as chemicals added during the oil-production process. It has been estimated that a total of 14 billion barrels of produced water were generated in 2002 from onshore operations (Veil, 2004). Although much of this produced water is disposed via reinjection, environmental and cost considerations can make surface discharge of this water a more practical means of disposal. In addition, reinjection is not always a feasible option because of geographic, economic, or regulatory considerations. In these situations, it may be desirable, and often necessary from a regulatory viewpoint, to treat produced water before discharge. It may also be feasible to treat waters that slightly exceed regulatory limits for re-use in arid or drought-prone areas, rather than losing them to reinjection. A previous project conducted under DOE Contract DE-AC26-99BC15221 demonstrated that surfactant modified zeolite (SMZ) represents a potential treatment technology for produced water containing BTEX. Laboratory and field experiments suggest that: (1) sorption of benzene, toluene, ethylbenzene and xylenes (BTEX) to SMZ follows linear isotherms in which sorption increases with increasing solute hydrophobicity; (2) the presence of high salt concentrations substantially increases the capacity of the SMZ for BTEX; (3) competitive sorption among the BTEX compounds is negligible; and, (4) complete recovery of the SMZ sorption capacity for BTEX can be achieved by air sparging the SMZ. This report summarizes research for a follow on project to optimize the regeneration process for multiple sorption/regeneration cycles, and to develop and incorporate a vapor phase bioreactor (VPB) system for treatment of the off-gas generated during air sparging. To this end, we conducted batch and column laboratory SMZ and VPB experiments with synthetic and actual produced waters. Based on the results of the laboratory testing, a pilot scale study was designed and conducted to evaluate the combined SMZ/VPB process. An economic and regulatory feasibility analysis was also completed as part of the current study to assess the viability of the process for various water re-use options.

  7. The influence of midlatitude and tropical overturning circulation on the isotopic composition of atmospheric water vapor and

    E-Print Network [OSTI]

    Noone, David

    coordinates. In this depiction, poleward transport of air and water vapor is non-diffusive, in a way for an open distillation. Model experiments that simulate a wide range of circulation strengths show to the polar region exceeds the rate at which surface sources replenish the poleward moving air stream. Across

  8. Isothermal vapor-liquid equilibria for water + 2-aminoethanol + dimethyl sulfoxide and its constituent three binary systems

    SciTech Connect (OSTI)

    Tochigi, Katsumi; Akimoto, Kentarou; Ochi, Kenji [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry] [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Liu, Fangyhi; Kawase, Yasuhito [Nippon Refine Co., Ltd., Tokyo (Japan)] [Nippon Refine Co., Ltd., Tokyo (Japan)

    1999-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system water + 2-aminoethanol + dimethyl sulfoxide and its three constituent binary mixtures at 363.15 K. The apparatus used was a modified Rogalski-Malanoski equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  9. Nature of the Mesoscale Boundary Layer Height and Water Vapor Variability Observed 14 June 2002 during the IHOP_2002 Campaign

    E-Print Network [OSTI]

    Guichard, Francoise

    Nature of the Mesoscale Boundary Layer Height and Water Vapor Variability Observed 14 June 2002, Boulder, Colorado (Manuscript received 4 September 2007, in final form 23 June 2008) ABSTRACT Mesoscale at the mesoscale, with the spatial pattern and the magnitude of the variability changing from day to day. On 14

  10. TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM

    SciTech Connect (OSTI)

    LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

    2003-10-01T23:59:59.000Z

    Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and assembled to treat the off-gas from the SMZ regeneration process. These columns will be used both in the laboratory and in the proposed field testing to be conducted next year. Innocula for the columns that degrade all of the BTEX columns have been developed.

  11. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria, E-mail: Valeria.Molinero@utah.edu [Department of Chemistry, The University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)

    2014-11-14T23:59:59.000Z

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  12. Two Stage Vapor Compression Heat Pump with Solution Circuits: Catering to Simultaneous Chilling and Water Heating Needs

    E-Print Network [OSTI]

    Rane, M. V.; Radermacher, R.

    results indicate that the two stage VCHSC can achiev~ cooling coefficient of performances as high as 1.04 while pumping heat through a lift of 194?F (10S0C). Comparison is made with a system consisting of a vapor compressor chiller and a gas fired... conditioning and hot water for various uses will be assessed. comparison is made with a system consisting of a vapor compressor chiller and a gas fired furnace (option 2). The basis for comparison being: a) the total primary energy usage, b) the cost...

  13. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W., E-mail: srick@uno.edu [Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148 (United States)

    2014-05-14T23:59:59.000Z

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 Ĺ away from the surface.

  14. Forced Dispersion of Liquefied Natural Gas Vapor Clouds with Water Spray Curtain Application 

    E-Print Network [OSTI]

    Rana, Morshed A.

    2011-02-22T23:59:59.000Z

    concerns have been expressed regarding the safety of this fuel. In addition, regulatory authorities in the U.S. as well as all over the world expect the implementation of consequence mitigation measures for LNG spills. For the effective and safer use any...

  15. 3708 IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 47, NO. 11, NOVEMBER 2009 Retrieval of Atmospheric Water Vapor Density With

    E-Print Network [OSTI]

    Reising, Steven C.

    3708 IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 47, NO. 11, NOVEMBER 2009 Retrieval, remote sensing, water vapor. Manuscript received November 1, 2008; revised May 2, 2009 and August 8, 2009 the latent heat of vaporization is a principal mechanism for the transport of energy from the equatorial

  16. Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave radiometer data are systematically compared to models to quantify and

    E-Print Network [OSTI]

    Hogan, Robin

    Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave a systematic evaluation of clouds in forecast models. Clouds and their associated microphysical processes for end users of weather forecasts, who may be interested not only in cloud cover, but in other variables

  17. Retrieval of water vapor profiles over ocean using SSM/I and SSM/T-2

    E-Print Network [OSTI]

    Blankenship, Clay Bruce

    1997-01-01T23:59:59.000Z

    surface. Intrsred retrievals also suffer because clouds are opaque at these fiequencies, making retrievals impossible below cloud layers. Since clouds are largely transparent to microwaves, microwave radiance measurements are well-suited to global...B footprint size, along-track by cross-track CHAPTER IH PHYSICS OF MICROWAVE RADIATIVE TRANSFER 3. 1 Microwave Radiative Transfer in the Atmosphere The radiance at a given wavelength X of a blackbody (perfect emitter) of temperature T is given...

  18. Glass softening, crystallization, and vaporization of nano-aggregates of Amorphous Solid Water: Fast Scanning Calorimetry studies

    E-Print Network [OSTI]

    Deepanjan Bhattacharya; Liam OReilly; Vlad Sadtchenko

    2014-10-31T23:59:59.000Z

    Fast scanning calorimetry (FSC) was employed to investigate glass softening dynamics in amorphous solid water (ASW) nano-aggregates with thicknesses ranging from 2 to 20 nm. ASW nano-aggregates were prepared by vapor-deposition on the surface of a tungsten filament near 141 K and then heated at a rate of 100 kK/s. The resulting thermogram complex endo- and exothermal features were analyzed using a simple model. The results of the analysis show that glass softening of ASW nano-aggregates takes place at 160 K and vaporization of ASW nano-aggregates can take place at temperatures as low as 185 K. The results of these studies are discussed in conjunction with results of past studies of glass softening dynamics in water in various confining geometries.

  19. Method and apparatus for simulating atmospheric absorption of solar energy due to water vapor and CO{sub 2}

    DOE Patents [OSTI]

    Sopori, B.L.

    1995-06-20T23:59:59.000Z

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.

  20. Method and apparatus for simulating atomospheric absorption of solar energy due to water vapor and CO.sub.2

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Denver, CO)

    1995-01-01T23:59:59.000Z

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth's surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO.sub.2 and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO.sub.2 and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO.sub.2 and moisture.

  1. Isobaric vapor-liquid equilibria of the water + 1-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-09-01T23:59:59.000Z

    Isobaric vapor-liquid equilibria for the water + 1-propanol system are reported at 30, 60, and 100 kPa. The results were found to be thermodynamically consistent according to Van Ness-Byer-Gibbs, Kojima, and Wisniak methods. The system shows a minimum boiling azeotrope, and the azeotropic composition is scarcely shifted with pressure. Results were compared with literature values. The data were correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC liquid-phase activity coefficient models.

  2. Oval BA (and the Great Red Spot) extend down to a supersolar water cloud layer in Jupiter's atmosphere

    E-Print Network [OSTI]

    Marcus, Philip S.

    Oval BA (and the Great Red Spot) extend down to a supersolar water cloud layer in Jupiter in Jupiter's troposphere, with stable layers near cloud bases [4,6,7]. We use these two results to determine horizontal band in Fig. 2 shows that vortex- model derived static stability (white bars) is consistent

  3. Plasma Kinetics in Electrical Discharge in Mixture of Air, Water and Ethanol Vapors for Hydrogen Enriched Syngas Production

    E-Print Network [OSTI]

    Shchedrin, A I; Ryabtsev, A V; Chernyak, V Ya; Yukhymenko, V V; Olszewski, S V; Naumov, V V; Prysiazhnevych, I V; Solomenko, E V; Demchina, V P; Kudryavtsev, V S

    2008-01-01T23:59:59.000Z

    The complex theoretical and experimental investigation of plasma kinetics of the electric discharge in the mixture of air and ethanol-water vapors is carried out. The discharge was burning in the cavity, formed by air jets pumping between electrodes, placed in aqueous ethanol solution. It is found out that the hydrogen yield from the discharge is maximal in the case when ethanol and water in the solution are in equal amounts. It is shown that the hydrogen production increases with the discharge power and reaches the saturation at high value. The concentrations of the main stable gas-phase components, measured experimentally and calculated numerically, agree well in the most cases.

  4. Structure and Dynamics of the Instantaneous Water/Vapor Interface Revisited by Path-Integral and Ab-Initio Molecular Dynamics Simulations

    E-Print Network [OSTI]

    Kessler, Jan; Spura, Thomas; Karhan, Kristof; Partovi-Azar, Pouya; Hassanali, Ali A; Kühne, Thomas D

    2015-01-01T23:59:59.000Z

    The structure and dynamics of the water/vapor interface is revisited by means of path-integral and second-generation Car-Parrinello ab-initio molecular dynamics simulations in conjunction with an instantaneous surface definition [A. P. Willard and D. Chandler, J. Phys. Chem. B 114, 1954 (2010)]. In agreement with previous studies, we find that one of the OH bonds of the water molecules in the topmost layer is pointing out of the water into the vapor phase, while the orientation of the underlying layer is reversed. Therebetween, an additional water layer is detected, where the molecules are aligned parallel to the instantaneous water surface.

  5. Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations

    SciTech Connect (OSTI)

    Turner, David D.

    2003-06-01T23:59:59.000Z

    A novel new approach to retrieve cloud microphysical properties from mixed-phase clouds is presented. This algorithm retrieves cloud optical depth, ice fraction, and the effective size of the water and ice particles from ground-based, high-resolution infrared radiance observations. The theoretical basis is that the absorption coefficient of ice is stronger than that of liquid water from 10-13 mm, whereas liquid water is more absorbing than ice from 16-25 um. However, due to strong absorption in the rotational water vapor absorption band, the 16-25 um spectral region becomes opaque for significant water vapor burdens (i.e., for precipitable water vapor amounts over approximately 1 cm). The Arctic is characterized by its dry and cold atmosphere, as well as a preponderance of mixed-phase clouds, and thus this approach is applicable to Arctic clouds. Since this approach uses infrared observations, cloud properties are retrieved at night and during the long polar wintertime period. The analysis of the cloud properties retrieved during a 7 month period during the Surface Heat Budget of the Arctic (SHEBA) experiment demonstrates many interesting features. These results show a dependence of the optical depth on cloud phase, differences in the mode radius of the water droplets in liquid-only and mid-phase clouds, a lack of temperature dependence in the ice fraction for temperatures above 240 K, seasonal trends in the optical depth with the clouds being thinner in winter and becoming more optically thick in the late spring, and a seasonal trend in the effective size of the water droplets in liquid-only and mixed-phase clouds that is most likely related to aerosol concentration.

  6. Isobaric vapor-liquid equilibria of the water + 2-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica] [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica

    1996-05-01T23:59:59.000Z

    Distillation is perhaps the separation process most widely used in the chemical processing industry. The correct design of distillation columns requires the availability of accurate and, if possible, thermodynamically consistent vapor-liquid equilibria (VLE) data. The present work is part of a project studying the effect of pressure on the behavior of the azeotropic point in mixtures in which at least one component is an alcohol. Isobaric vapor-liquid equilibria were obtained for the water + 2-propanol system at 30, 60, and 100 kPa. The activity coefficients were found to be thermodynamically consistent by the methods of Van Ness-Byer-Gibbs, Kojima, and Wisniak. The data were correlated with five liquid phase activity coefficient models (Margules, Van Laar, Wilson, NRTL, and UNIQUAC).

  7. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  8. A Compact, Backscattering Deplolarization Cloud Spectrometer for Ice and Water Discrimination

    SciTech Connect (OSTI)

    Thomson, David

    2014-05-15T23:59:59.000Z

    This project was to develop a compact optical particle spectrometer, small enough for operation on UAVS, that measures the optical diameter of cloud hydrometeors and differentiates their water phase (liquid or solid). To reach this goal, a work plan was laid out that would complete three objectives: 1) Evaluation of designs for an optical particle spectrometer that measures the component of light backscattered at two polarization angles. 2) Testing of selected designs on an optical bench. 3) Construction and preliminary testing of a prototype instrument based on the selected, optimum design. A protoype instrument was developed and tested in an icing wind tunnel where the results showed good measurement of cloud droplets and ice particles.

  9. MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2)

    SciTech Connect (OSTI)

    Gaustad, KL; Turner, DD; McFarlane, SA

    2011-07-25T23:59:59.000Z

    This report provides a short description of the Atmospheric Radiation Measurement (ARM) Climate Research Facility microwave radiometer (MWR) Retrieval (MWRRET) value-added product (VAP) algorithm. This algorithm utilizes a complementary physical retrieval method and applies brightness temperature offsets to reduce spurious liquid water path (LWP) bias in clear skies resulting in significantly improved precipitable water vapor (PWV) and LWP retrievals. We present a general overview of the technique, input parameters, output products, and describe data quality checks. A more complete discussion of the theory and results is given in Turner et al. (2007b).

  10. A Fixed Point Charge Model for Water Optimized to the Vapor-Liquid Coexistence Properties

    E-Print Network [OSTI]

    the temperature range of the liquid. Results were compared to the SPC, SPC/E, and MSPC/E models, vapor pressures, critical parameters, and the second virial coefficient. It is inferior to the SPC interactions. Models of this type include the Bernal-Fowler1 , ST22 , TIPS23 , TIP4P4 , SPC5 , SPC/E6

  11. A Test of the Simulation of Tropical Convective Cloudiness by a Cloud-Resolving Model MARIO A. LOPEZ, DENNIS L. HARTMANN, PETER N. BLOSSEY, ROBERT WOOD,

    E-Print Network [OSTI]

    Hartmann, Dennis

    effects are investigated. The simulation of anvil cloud can be improved while maintaining a good and water vapor have a strong influence on the radiation budget of the earth, and it is unclear how cloud solar radiation, although their effect on the net energy balance is often much less than

  12. The Hydrated Proton at the Water Liquid/Vapor Interface Matt K. Petersen, Srinivasan S. Iyengar, Tyler J. F. Day, and Gregory A. Voth*,

    E-Print Network [OSTI]

    Iyengar, Srinivasan S.

    The Hydrated Proton at the Water Liquid/Vapor Interface Matt K. Petersen, Srinivasan S. Iyengar ReceiVed: July 23, 2004; In Final Form: August 22, 2004 The hydrated proton was studied at the water the migration of the excess proton to and about the interface through the fluctuating bond topology described

  13. Detecting Cirrus-Overlapping-Water Clouds and Retrieving their Optical Properties Using MODIS Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration wouldDECOMPOSITIONPortalToDepthandCirrus-Overlapping-Water Clouds and

  14. Development of advanced cloud parameterizations to examine air quality, cloud properties, and cloud-radiation feedback in mesoscale models

    SciTech Connect (OSTI)

    Lee, In Young

    1993-09-01T23:59:59.000Z

    The distribution of atmospheric pollutants is governed by dynamic processes that create the general conditions for transport and mixing, by microphysical processes that control the evolution of aerosol and cloud particles, and by chemical processes that transform chemical species and form aerosols. Pollutants emitted into the air can undergo homogeneous gas reactions to create a suitable environment for the production by heterogeneous nucleation of embryos composed of a few molecules. The physicochemical properties of preexisting aerosols interact with newly produced embryos to evolve by heteromolecular diffusion and coagulation. Hygroscopic particles wig serve as effective cloud condensation nuclei (CCN), while hydrophobic particles will serve as effective ice-forming nuclei. Clouds form initially by condensation of water vapor on CCN and evolve in a vapor-liquid-solid system by deposition, sublimation, freezing, melting, coagulation, and breakup. Gases and aerosols that enter the clouds undergo aqueous chemical processes and may acidity hydrometer particles. Calculations for solar and longwave radiation fluxes depend on how the respective spectra are modified by absorbers such as H{sub 2}O, CO{sub 2}, O{sub 3}, CH{sub 4}, N{sub 2}O, chlorofruorocarbons, and aerosols. However, the flux calculations are more complicated for cloudy skies, because the cloud optical properties are not well defined. In this paper, key processes such as tropospheric chemistry, cloud microphysics parameterizations, and radiation schemes are reviewed in terms of physicochemical processes occurring, and recommendations are made for the development of advanced modules applicable to mesoscale models.

  15. Cloud Services Cloud Services

    E-Print Network [OSTI]

    Cloud Services Cloud Services In 2012 UCD IT Services launched an exciting new set of cloud solutions called CloudEdu, which includes cloud servers, cloud storage, cloud hosting and cloud network. The CloudEdu package includes a consultancy service in design, deployment, management and utilisation

  16. Active probing of cloud multiple scattering, optical depth, vertical thickness, and liquid water content using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B. (Anthony B.); Rohde, C. A. (Charles A.); Tellier, L. L. (Larry L.); Ho, Cheng,

    2002-01-01T23:59:59.000Z

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60-degree full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer, and, from there, estimate the volume-averaged liquid water content. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Here we present recent WAIL data oti various clouds and discuss the extension of WAIL to full diurnal monitoring by means of an ultra-narrow magneto-optic atomic line filter for daytime measurements.

  17. Vapor Transport in Dry Soils

    SciTech Connect (OSTI)

    Gee, Glendon W.; Ward, Anderson L.

    2001-11-16T23:59:59.000Z

    Water-vapor movement in soils is a complex process, controlled by both diffusion and advection and influenced by pressure and thermal gradients acting across tortuous flow paths. Wide-ranging interest in water-vapor transport includes both theoretical and practical aspects. Just how pressure and thermal gradients enhance water-vapor flow is still not completely understood and subject to ongoing research. Practical aspects include dryland farming (surface mulching), water harvesting (aerial wells), fertilizer placement, and migration of contaminants at waste-sites. The following article describes the processes and practical applications of water-vapor transport, with emphasis on unsaturated (dry) soil systems.

  18. Experimental evidence for interaction of water vapor and platinum crucibles at high temperatures : Implications for volatiles

    E-Print Network [OSTI]

    Cartigny, Pierre

    The extraction of water from igneous rocks and minerals is classically achieved by induction heating or foils, to extract water from rocks or minerals should be avoided. The interaction high- lighted : Implications for volatiles from igneous rocks and minerals Matthieu Clog , Pierre Cartigny, Cyril Aubaud

  19. Interaction of wide-band-gap single crystals with 248-nm excimer laser radiation. XI. The effect of water vapor and temperature on laser desorption

    E-Print Network [OSTI]

    Dickinson, J. Thomas

    . Significantly, introducing water vapor lowers the particle velocities and thus the effective surface temperature systems, simultaneous electronic excitation and exposure to aggressive chemicals can acceler- ate etching-induced neutral particle desorption and surface erosion on single- crystal sodium chloride in the presence of low

  20. The Use of Water Vapor as a Refrigerant: Impact of Cycle Modifications on Commercial Viability

    SciTech Connect (OSTI)

    Brandon F. Lachner, Jr.; Gregory F. Nellis; Douglas T. Reindl

    2004-08-30T23:59:59.000Z

    This project investigated the economic viability of using water as the refrigerant in a 1000-ton chiller application. The most attractive water cycle configuration was found to be a flash-intercooled, two-stage cycle using centrifugal compressors and direct contact heat exchangers. Component level models were developed that could be used to predict the size and performance of the compressors and heat exchangers in this cycle as well as in a baseline, R-134a refrigeration cycle consistent with chillers in use today. A survey of several chiller manufacturers provided information that was used to validate and refine these component models. The component models were integrated into cycle models that were subsequently used to investigate the life-cycle costs of both an R-134a and water refrigeration cycle. It was found that the first cost associated with the water as a refrigerant cycle greatly exceeded the savings in operating costs associated with its somewhat higher COP. Therefore, the water refrigeration cycle is not an economically attractive option to today's R-134a refrigeration system. There are a number of other issues, most notably the requirements associated with purging non-condensable gases that accumulate in a direct contact heat exchanger, which will further reduce the economic viability of the water cycle.

  1. Isobaric vapor-liquid equilibria for binary and ternary systems composed of water, 1-propanol, and 2-propanol at 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-11-01T23:59:59.000Z

    Isobaric vapor-liquid equilibria data were obtained for the 2-propanol + 1-propanol binary system and the water + 1-propanol + 2-propanol ternary system at 100 kPa. The data were found to be thermodynamically consistent according to the Van Ness-Byer-Gibbs method for the binary system and according to the McDermott-Ellis method for the ternary one. The binary system is well represented by assuming ideal behavior. The binary interaction parameters obtained from this and previous work are used to predict the vapor-liquid equilibrium for the ternary system using the UNIQUAC, NRTL, and Wilson models. The ternary system is well predicted from binary data.

  2. NORIA - a finite element computer program for analyzing water, vapor, air, and energy transport in porous media

    SciTech Connect (OSTI)

    Bixler, N.E.

    1985-08-01T23:59:59.000Z

    NORIA is a finite element computer program that solves four nonlinear, parabolic, partial differential equations simultaneously. The four equations describe the transport of water, water vapor, air, and energy through partially saturated porous media. The numerical procedure uses the standard Galerkin finite element method to handle spatial discretization of two-dimensional domains with either planar symmetry or axisymmetry. Time integration is performed by a third-order predictor-corrector scheme that uses error estimates to automatically adjust time-step size so as to maintain uniform local time truncation error throughout the calculation. Thus, the user is not required to select time-step size except at the first time step. Nearly all material properties, such as permeability, can either be set to constant values or can be defined as functions of the dependent and independent variables by user-supplied subroutines. The gas phase is taken to be ideal. This report is intended primarily as a user`s manual but also includes discussions of the theory of two-phase transport in porous media and the numerical procedure used in NORIA. 33 refs., 10 figs., 1 tab.

  3. Extremely Luminous Water Vapor Emission from a Type 2 Quasar at Redshift z = 0.66

    E-Print Network [OSTI]

    Richard Barvainis; Robert Antonucci

    2005-06-10T23:59:59.000Z

    A search for water masers in 47 Sloan Digital Sky Survey Type 2 quasars using the Green Bank Telescope has yielded a detection at a redshift of z = 0.660. This maser is more than an order of magnitude higher in redshift than any previously known and, with a total isotropic luminosity of 23,000 L_sun, also the most powerful. The presence and detectability of water masers in quasars at z ~ 0.3-0.8 may provide a better understanding of quasar molecular tori and disks, as well as fundamental quasar and galaxy properties such as black hole masses. Water masers at cosmologically interesting distances may also eventually provide, via direct distance determinations, a new cosmological observable for testing the reality and properties of dark energy, currently inferred primarily through Type 1a supernova measurements.

  4. Evaluation of a New Mixed-Phase Cloud Microphysics Parameterization with CAM3 Single-Column Model and M-PACE Observations

    SciTech Connect (OSTI)

    Liu, Xiaohong; Xie, Shaocheng; Ghan, Steven J.

    2007-12-14T23:59:59.000Z

    Most global climate models generally prescribe the partitioning of condensed water into liquid droplets and ice crystals in mixed-phase clouds according to a temperature-dependent function, which affects modeled cloud phase, cloud lifetime and radiative properties. This study evaluates a new mixed-phase cloud microphysics parameterization (for ice nucleation and water vapor deposition) against the Atmospheric Radiation Measurement (ARM) Mixed-phase Arctic Cloud Experiment (M-PACE) observations using the NCAR Community Atmospheric Model Version 3 (CAM3) single column model (SCAM). It is shown that SCAM with the new scheme produces a more realistic simulation of the cloud phase structure and the partitioning of condensed waterinto liquid droplets against observations during the M-PACE than the standard CAM. Sensitivity test indicates that ice number concentration could play an important role in the simulated mixed-phase cloud microphysics, and thereby needs to be realistically represented in global climate models.

  5. Evaluation of the Daylight Cycle of Model-Predicted Cloud Amount and Condensed Water Path over Europe with Observations from MSG SEVIRI

    E-Print Network [OSTI]

    Stoffelen, Ad

    Evaluation of the Daylight Cycle of Model-Predicted Cloud Amount and Condensed Water Path over accurate information on diurnal cycles during daylight hours of cloud properties over land and ocean surfaces. This paper evaluates the daylight cycle of CA and CWP as predicted by the Regional Atmospheric

  6. Comments on ''Accuracy of Raman lidar water vapor calibration and its applicability to long-term measurements''

    SciTech Connect (OSTI)

    Whiteman, David N.; Venable, Demetrius; Landulfo, Eduardo

    2011-05-20T23:59:59.000Z

    In a recent publication, Leblanc and McDermid [Appl. Opt., 47, 5592 (2008)]APOPAI0003-693510.1364/AO.47.005592 proposed a hybrid calibration technique for Raman water vapor lidar involving a tungsten lamp and radiosondes. Measurements made with the lidar telescope viewing the calibration lamp were used to stabilize the lidar calibration determined by comparison with radiosonde. The technique provided a significantly more stable calibration constant than radiosondes used alone. The technique involves the use of a calibration lamp in a fixed position in front of the lidar receiver aperture. We examine this configuration and find that such a configuration likely does not properly sample the full lidar system optical efficiency. While the technique is a useful addition to the use of radiosondes alone for lidar calibration, it is important to understand the scenarios under which it will not provide an accurate quantification of system optical efficiency changes. We offer examples of these scenarios. Scanning of the full telescope aperture with the calibration lamp can circumvent most of these limitations. Based on the work done to date, it seems likely that the use of multiple calibration lamps in different fixed positions in front of the telescope may provide sufficient redundancy for long-term calibration needs. Further full-aperture scanning experiments, performed over an extended period of time, are needed to determine a ''best practice'' for the use of multiple calibration lamps in the hybrid technique.

  7. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  8. Distribution of volatile organic compounds in soil vapor in the vicinity of a defense fuel supply point, Hanahan, South Carolina. Water resources investigations report

    SciTech Connect (OSTI)

    Robertson, J.F.; Aelion, C.M.; Vroblesky, D.A.

    1993-12-31T23:59:59.000Z

    The report describes the results of a reconnaissance study to identify areas of potential contamination of the water table aquifer by volatile organic compounds (VOC`s) beneath a Defense Fuel Supply Point and adjacent properties near Hanahan, S.C. Six areas in and around the DFSP facility were investigated with soil-vapor techniques. The northern boundary area has been studied extensively and was, therefore, not included in the investigation.

  9. VALIDATION OF CLOUD LIQUID WATER PATH RETRIEVALS FROM SEVIRI USING ONE YEAR OF

    E-Print Network [OSTI]

    Haak, Hein

    from microwave radiometer (MWR) measurements of two CloudNET stations in Northern Europe. The MWR retrievals from SEVIRI. The daily median LWP values from SEVIRI and MWR are highly correlated (corr. > 0 winter. 1. Introduction Clouds strongly modulate the energy balance of the Earth and its atmosphere

  10. Expected magnitude of the aerosol shortwave indirect effect in springtime Arctic liquid water clouds

    E-Print Network [OSTI]

    reflection of photons between the snow or sea ice surface and cloud base, the shortwave first indirect effect of high quality longwave spectral radiation measurements in the Arctic from which the indirect effect can clouds both absorb and scatter radiation. We therefore do not yet have a comparable spectral capability

  11. Simulations of Arctic Mixed-Phase Clouds in Forecasts with CAM3 and AM2 for M-PACE

    SciTech Connect (OSTI)

    Xie, Shaocheng; Boyle, James; Klein, Stephen A.; Liu, Xiaohong; Ghan, Steven J.

    2008-02-29T23:59:59.000Z

    Simulations of mixed-phase clouds in short-range forecasts with the National Center for Atmospheric Research Community Atmosphere Model version 3 (CAM3) and the Geophysical Fluid Dynamics Laboratory (GFDL) climate model (AM2) for the Mixed-Phase Arctic Cloud Experiment (M-PACE) are performed under the DOE CCPP-ARM Parameterization Testbed (CAPT), which initializes the climate models with analysis data produced from numerical weather prediction (NWP) centers. It is shown that CAM3 significantly underestimates the observed boundary layer mixed-phase clouds and cannot realistically simulate the variations with temperature and cloud height of liquid water fraction in the total cloud condensate based an oversimplified cloud microphysical scheme. In contrast, AM2 reasonably reproduces the observed boundary layer clouds while its clouds contain much less cloud condensate than CAM3 and the observations. Both models underestimate the observed cloud top and base for the boundary layer clouds. The simulation of the boundary layer mixed-phase clouds and their microphysical properties is considerably improved in CAM3 when a new physically based cloud microphysical scheme is used. The new scheme also leads to an improved simulation of the surface and top of the atmosphere longwave radiative fluxes in CAM3. It is shown that the Bergeron-Findeisen process, i.e., the ice crystal growth by vapor deposition at the expense of coexisting liquid water, is important for the models to correctly simulate the characteristics of the observed microphysical properties in mixed-phase clouds. Sensitivity tests show that these results are not sensitive to the analysis data used for model initializations. Increasing model horizontal resolution helps capture the subgrid-scale features in Arctic frontal clouds but does not help improve the simulation of the single-layer boundary layer clouds. Ice crystal number density has large impact on the model simulated mixed-phase clouds and their microphysical properties and needs to be accurately represented in climate models.

  12. Retrieval of Cloud Ice Water Content Profiles from Advanced Microwave Sounding Unit-B Brightness Temperatures Near the Atmospheric Radiation Measurement Southern Great Plains Site

    SciTech Connect (OSTI)

    Seo, E-K.; Liu, G.

    2005-03-18T23:59:59.000Z

    One of the Atmospheric Radiation Measurement (ARM) Program important goals is to develop and test radiation and cloud parameterizations of climate models using single column modeling (SCMs) (Randall et al. 1996). As forcing terms, SCMs need advection tendency of cloud condensates besides the tendencies of temperature, moisture and momentum. To compute the tendency terms of cloud condensates, 3D distribution of cloud condensates over a scale much larger than the climate model's grid scale is needed. Since they can cover a large area within a short time period, satellite measurements are useful utilities to provide advection tendency of cloud condensates for SCMs. However, so far, most satellite retrieval algorithms only retrieve vertically integrated quantities, for example, in the case of cloud ice, ice water path (IWP). To fulfill the requirement of 3D ice water content field for computing ice water advection, in this study, we develop an ice water content profile retrieval algorithm by combining the vertical distribution characteristics obtained from long-term surface radar observations and satellite high-frequency microwave observations that cover a large area. The algorithm is based on the Bayesian theorem using a priori database derived from analyzing cloud radar observations at the Southern Great Plains (SGP) site. The end product of the algorithm is a 3D ice water content covering 10{sup o} x 10{sup o} surrounding the SGP site during the passage of the satellite. This 3D ice water content, together with wind field analysis, can be used to compute the advection tendency of ice water for SCMs.

  13. Plant-Water Relations in Seasonally Dry Tropical Montane Cloud Forests

    E-Print Network [OSTI]

    Goldsmith, Gregory Rubin

    2012-01-01T23:59:59.000Z

    treatment. Figure 3. Leaf water potential measured over timeecosystems, including soil water use generally between 20 cmboth deep roots and deep water use by plants have also been

  14. Evaluation of A New Mixed-Phase Cloud Microphysics Parameterization with the NCAR Climate Atmospheric Model (CAM3) and ARM Observations Fourth Quarter 2007 ARM Metric Report

    SciTech Connect (OSTI)

    X Liu; SJ Ghan; S Xie; J Boyle; SA Klein

    2007-09-30T23:59:59.000Z

    Mixed-phase clouds are composed of a mixture of cloud droplets and ice crystals. The cloud microphysics in mixed-phase clouds can significantly impact cloud optical depth, cloud radiative forcing, and cloud coverage. However, the treatment of mixed-phase clouds in most current climate models is crude and the partitioning of condensed water into liquid droplets and ice crystals is prescribed as temperature dependent functions. In our previous 2007 ARM metric reports a new mixed-phase cloud microphysics parameterization (for ice nucleation and water vapor deposition) was documented and implemented in the NCAR Community Atmospheric Model Version 3 (CAM3). The new scheme was tested against the Atmospheric Radiation Measurement (ARM) Mixed-phase Arctic Cloud Experiment (M-PACE) observations using the single column modeling and short-range weather forecast approaches. In this report this new parameterization is further tested with CAM3 in its climate simulations. It is shown that the predicted ice water content from CAM3 with the new parameterization is in better agreement with the ARM measurements at the Southern Great Plain (SGP) site for the mixed-phase clouds.

  15. Quantification of cloud water interception along the windward slope of Santa Cruz Island, Galapagos

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    (Ecuador) Alexandre Pryeta, , Christian Dominguezb , Pilar Fuente Tomaia,c , C´edric Chaumontd , No´emi d, Quito, Ecuador c Department of Silviculture and Pastures, Forest Engineering School, University conditions of low vapor pressure deficits and weak solar radiation and is therefore associated with limited

  16. Effect of Mo Dispersion Size and Water Vapor on Oxidation of Two-Phase Directionally Solidified NiAl-9Mo In-Situ Composites

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Meisner, Roberta Ann [ORNL] [ORNL; Lance, Michael J [ORNL] [ORNL; Tortorelli, Peter F [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Oxidation of two-phase NiAl-9Mo eutectics with 3 different growth rates/2nd phase Mo dispersion sizes were investigated at 900 C in air and air with 10% water vapor. Good oxidation resistance via alumina formation was observed in dry air, with Mo volatilization loss minimized by fine submicron Mo dispersions. However, extensive Mo volatilization and in-place internal oxidation of prior Mo phase regions was observed in wet air oxidation. Ramifications of this phenomenon for the development of multi-phase high-temperature alloys are discussed

  17. Tropical Cloud Properties and Radiative Heating Profiles

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mather, James

    We have generated a suite of products that includes merged soundings, cloud microphysics, and radiative fluxes and heating profiles. The cloud microphysics is strongly based on the ARM Microbase value added product (Miller et al., 2003). We have made a few changes to the microbase parameterizations to address issues we observed in our initial analysis of the tropical data. The merged sounding product is not directly related to the product developed by ARM but is similar in that it uses the microwave radiometer to scale the radiosonde column water vapor. The radiative fluxes also differ from the ARM BBHRP (Broadband Heating Rate Profile) product in terms of the radiative transfer model and the sampling interval.

  18. Broken and inhomogeneous cloud impact on satellite cloud particle effective radius and cloudphase retrievals

    E-Print Network [OSTI]

    Stoffelen, Ad

    on the particle size distribution, height, and thermo- dynamic phase of clouds. Water and ice clouds have parameterizations is the global dis- tribution of cloud thermodynamic phase, i.e., whether a cloud is composed on satellitederived cloud particle effective radius (re) and cloud phase (CPH) for broken and overcast inhomogeneous

  19. Measurements of heat and mass transfer coefficients during absorption of water vapor by lithium bromide and (Li,K,Na)NO sub 3 mixtures

    SciTech Connect (OSTI)

    Zaltash, A.; Ally, M.R.; Linkous, R.L.; Klatt, L.N.

    1991-01-01T23:59:59.000Z

    A knowledge of heat and mass transfer coefficients in heat pump fluids, plays an important role in the design of absorption machines. Heat and mass transfer coefficients as well as subcooling are measured for absorption of water vapor in (Li, K, Na)No{sub 3} and Lithium Bromide (LiBr) mixtures.The rate of absorption of water vapor is obtained from the difference in concentration of mixtures between inlet and outlet streams across the absorber. In situ concentrations of aqueous salt mixtures over temperature ranges between 80 to 135 {degrees}C were calculated from density measurements. This technique of measurement is a reliable and convenient but not a very accurate ({plus minus}0.8 wt% salt) method of measuring the in situ salt concentration. Results show that the subcooling at the absorber exit is not only a property of the fluid, but depends strongly on the process conditions. The subcooling in LiBr mixtures without additive is shown to vary between 2.2 and 24.3 {degrees}C and the film heat transfer coefficient between 1365.2 and 801.1 W/m{sup 2}.K respectively, depending upon process conditions. These empirical results will prove to be of value to heat pump manufacturers because they have a strong bearing on costs and performance. Heat and mass transfer coefficients in aqueous salt solutions ate presented as a function of dimensionless numbers. 12 refs., 3 figs., 4 tabs.

  20. A new (W,Mo)C electrocatalyst synthesized by a carbonyl process: activity enhancement resulting from water vapor treatment in the synthesizing process

    SciTech Connect (OSTI)

    Kudo, T.; Ishikawa, A.; Kawamura, G.; Okamoto, H.

    1985-08-01T23:59:59.000Z

    It has been revealed that electrocatalytic activity of tungsten and molybdenum mixed carbides formed on a carbon fiber substrate using a process in which metallic film formed by CVD at 450/sup 0/C from W(CO)/sub 6/ an Mo(CO)/sub 6/ is carburized with CO at 820/sup 0/C is enhanced by exposure to water vapor ( about 20 torr) at its synthesizing stage before the carburization. Activity tests in relation to electro-oxidation of H/sub 2/ and CH/sub 3/OH conducted in 1M H/sub 2/SO/sub 4/ at 50/sup 0/C show that the potentiostatic current generated by reactants per real surface area of the catalyst thus obtained is 0.27 A-m/sup -2/ (at 0.2V vs. RHE) and 0.0037 A-m/sup -2/ (at 0.5V), respectively. The activity enhancement resulting from water vapor treatment is discussed in the light of surface analyses using Auger electron spectroscopy.

  1. CloudSat Overview CloudSat will provide, from space, the first global survey of cloud profiles and

    E-Print Network [OSTI]

    on the radiative and water budgets of clouds are broadly referred to as indirect aerosol effects. The aerosol processes and their accumulated effects on the global scale. 2. Mission Description CloudSat is plannedCloudSat Overview CloudSat will provide, from space, the first global survey of cloud profiles

  2. Cirrus clouds in a global climate model with a statistical cirrus cloud scheme

    SciTech Connect (OSTI)

    Wang, Minghuai; Penner, Joyce E.

    2010-06-21T23:59:59.000Z

    A statistical cirrus cloud scheme that accounts for mesoscale temperature perturbations is implemented in a coupled aerosol and atmospheric circulation model to better represent both subgrid-scale supersaturation and cloud formation. This new scheme treats the effects of aerosol on cloud formation and ice freezing in an improved manner, and both homogeneous freezing and heterogeneous freezing are included. The scheme is able to better simulate the observed probability distribution of relative humidity compared to the scheme that was implemented in an older version of the model. Heterogeneous ice nuclei (IN) are shown to decrease the frequency of occurrence of supersaturation, and improve the comparison with observations at 192 hPa. Homogeneous freezing alone can not reproduce observed ice crystal number concentrations at low temperatures (<205 K), but the addition of heterogeneous IN improves the comparison somewhat. Increases in heterogeneous IN affect both high level cirrus clouds and low level liquid clouds. Increases in cirrus clouds lead to a more cloudy and moist lower troposphere with less precipitation, effects which we associate with the decreased convective activity. The change in the net cloud forcing is not very sensitive to the change in ice crystal concentrations, but the change in the net radiative flux at the top of the atmosphere is still large because of changes in water vapor. Changes in the magnitude of the assumed mesoscale temperature perturbations by 25% alter the ice crystal number concentrations and the net radiative fluxes by an amount that is comparable to that from a factor of 10 change in the heterogeneous IN number concentrations. Further improvements on the representation of mesoscale temperature perturbations, heterogeneous IN and the competition between homogeneous freezing and heterogeneous freezing are needed.

  3. Evaluation of the aerosol indirect effect in marine stratocumulus clouds: Droplet number, size, liquid water path, and radiative impact

    E-Print Network [OSTI]

    Russell, Lynn

    Evaluation of the aerosol indirect effect in marine stratocumulus clouds: Droplet number, size stratocumulus clouds in the northeastern Pacific Ocean were analyzed to determine the effect of aerosol particles on cloud microphysical and radiative properties. Seven nighttime and two daytime cases were

  4. Ozone, water vapor, and temperature in the upper tropical troposphere: Variations over a decade of MOZAIC measurements

    E-Print Network [OSTI]

    Bortz, Sarah E; Prather, Michael J; Cammas, Jean-Pierre; Thouret, Valérie; Smit, Herman

    2006-01-01T23:59:59.000Z

    An extension of the measurement of ozone and water vapour byin-service Aircraft (MOZAIC) ozone climatologies usingcomparison with SHADOZ ozone and MODIS aerosol, J. Geophys.

  5. Dynamics of particle clouds in ambient currents with application to open-water sediment disposal

    E-Print Network [OSTI]

    Gensheimer, Robert James, III

    2010-01-01T23:59:59.000Z

    Open-water sediment disposal is used in many applications around the world, including land reclamation, dredging, and contaminated sediment isolation. Timely examples include the land reclamation campaign currently underway ...

  6. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    SciTech Connect (OSTI)

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, Allen B.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-01-03T23:59:59.000Z

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for assessing aerosol effects on cold season precipitation in California.

  7. Detection of Far-Infrared Water Vapor, Hydroxyl, and Carbon Monoxide Emissions from the Supernova Remnant 3C 391

    E-Print Network [OSTI]

    William T. Reach; Jeonghee Rho

    1998-09-01T23:59:59.000Z

    We report the detection of shock-excited far-infrared emission of H2O, OH, and CO from the supernova remnant 3C 391, using the ISO Long-Wavelength Spectrometer. This is the first detection of thermal H2O and OH emission from a supernova remnant. For two other remnants, W~28 and W~44, CO emission was detected but OH was only detected in absorption. The observed H2O and OH emission lines arise from levels within ~400 K of the ground state, consistent with collisional excitation in warm, dense gas created after the passage of the shock front through the dense clumps in the pre-shock cloud. The post-shock gas we observe has a density ~2x10^5 cm^{-3} and temperature 100-1000 K, and the relative abundances of CO:OH:H2O in the emitting region are 100:1:7 for a temperature of 200 K. The presence of a significant column of warm H2O suggests that the chemistry has been significantly changed by the shock. The existence of significant column densities of both OH and H2O, which is at odds with models for non-dissociative shocks into dense gas, could be due to photodissociation of H2O or a mix of fast and slow shocks through regions with different pre-shock density.

  8. G-Band Vapor Radiometer Profiler (GVRP) Handbook

    SciTech Connect (OSTI)

    Caddeau, MP

    2010-06-23T23:59:59.000Z

    The G-Band Vapor Radiometer Profiler (GVRP) provides time-series measurements of brightness temperatures from 15 channels between 170 and 183.310 GHz. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. Channels between 170.0 and 176.0 GHz are particularly sensitive to the presence of liquid water. The sensitivity to water vapor of the 183.31-GHz line is approximately 30 times higher than at the frequencies of the two-channel microwave radiometer (MWR) for a precipitable water vapor (PWV) amount of less than 2.5 mm. Measurements from the GVRP instrument are therefore especially useful during low-humidity conditions (PWV < 5 mm). In addition to integrated water vapor and liquid water, the GVRP can provide low-resolution vertical profiles of water vapor in very dry conditions.

  9. Effect of atmospheric water vapor on modification of stable isotopes in near-surface snow on ice sheets

    E-Print Network [OSTI]

    Walden, Von P.

    in the near-surface snow of East Antarctica. The processes of forced ventilation, pore-space diffusion to forced ventilation for several annual cycles. Postdepositional modification during the Last Glacial. Introduction [2] Stable isotopes of water in polar snow and ice have long been regarded as proxies for local

  10. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07T23:59:59.000Z

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  11. Estimation of precipitable water from surface observations

    E-Print Network [OSTI]

    Kahan, Archie Marion

    1959-01-01T23:59:59.000Z

    for estimating the precipitable water at Lake Charles, Louisiana. P red ic tors employed were surface vapor p re s ? sure, ceiling, cloud cover , cloud type, wind, pressure change and iv season. E rrors of estimate averaged approximately one tenth o f... of the photocells and the intense radiation of the noon sun leads one to accept the reality of a ce ll temperature greater than the ambient air temperature. The ce lls are, in effect, miniature green ? houses, The epoxy resin cylinder encasing the crysta l...

  12. Long Term Field Development of a Surfactant Modified Zeolite/Vapor Phase Bioreactor System for Treatment of Produced Waters for Power Generation

    SciTech Connect (OSTI)

    Lynn Katz; Kerry Kinney; Robert Bowman; Enid Sullivan; Soondong Kwon; Elaine Darby; Li-Jung Chen; Craig Altare

    2007-12-31T23:59:59.000Z

    The main goal of this research was to investigate the feasibility of using a combined physicochemical/biological treatment system to remove the organic constituents present in saline produced water. In order to meet this objective, a physical/chemical adsorption process was developed and two separate biological treatment techniques were investigated. Two previous research projects focused on the development of the surfactant modified zeolite adsorption process (DE-AC26-99BC15221) and development of a vapor phase biofilter (VPB) to treat the regeneration off-gas from the surfactant modified zeolite (SMZ) adsorption system (DE-FC26-02NT15461). In this research, the SMZ/VPB was modified to more effectively attenuate peak loads and to maintain stable biodegradation of the BTEX constituents from the produced water. Specifically, a load equalization system was incorporated into the regeneration flow stream. In addition, a membrane bioreactor (MBR) system was tested for its ability to simultaneously remove the aromatic hydrocarbon and carboxylate components from produced water. The specific objectives related to these efforts included the following: (1) Optimize the performance VPBs treating the transient loading expected during SMZ regeneration: (a) Evaluate the impact of biofilter operating parameters on process performance under stable operating conditions. (b) Investigate how transient loads affect biofilter performance, and identify an appropriate technology to improve biological treatment performance during the transient regeneration period of an SMZ adsorption system. (c) Examine the merits of a load equalization technology to attenuate peak VOC loads prior to a VPB system. (d) Evaluate the capability of an SMZ/VPB to remove BTEX from produced water in a field trial. (2) Investigate the feasibility of MBR treatment of produced water: (a) Evaluate the biodegradation of carboxylates and BTEX constituents from synthetic produced water in a laboratory-scale MBR. (b) Evaluate the capability of an SMZ/MBR system to remove carboxylates and BTEX from produced water in a field trial. Laboratory experiments were conducted to provide a better understanding of each component of the SMZ/VPB and SMZ/MBR process. Laboratory VPB studies were designed to address the issue of influent variability and periodic operation (see DE-FC26-02NT15461). These experiments examined multiple influent loading cycles and variable concentration loadings that simulate air sparging as the regeneration option for the SMZ system. Two pilot studies were conducted at a produced water processing facility near Farmington, New Mexico. The first field test evaluated SMZ adsorption, SMZ regeneration, VPB buffering, and VPB performance, and the second test focused on MBR and SMZ/MBR operation. The design of the field studies were based on the results from the previous field tests and laboratory studies. Both of the biological treatment systems were capable of removing the BTEX constituents in the laboratory and in the field over a range of operating conditions. For the VPB, separation of the BTEX constituents from the saline aqueous phase yielded high removal efficiencies. However, carboxylates remained in the aqueous phase and were not removed in the combined VPB/SMZ system. In contrast, the MBR was capable of directly treating the saline produced water and simultaneously removing the BTEX and carboxylate constituents. The major limitation of the MBR system is the potential for membrane fouling, particularly when the system is treating produced water under field conditions. The combined process was able to effectively pretreat water for reverse osmosis treatment and subsequent downstream reuse options including utilization in power generation facilities. The specific conclusions that can be drawn from this study are summarized.

  13. ON THE FORMATION OF INTERSTELLAR WATER ICE: CONSTRAINTS FROM A SEARCH FOR HYDROGEN PEROXIDE ICE IN MOLECULAR CLOUDS

    SciTech Connect (OSTI)

    Smith, R. G.; Wright, C. M.; Robinson, G. [School of Physical, Environmental and Mathematical Sciences, University of New South Wales, Australian Defence Force Academy, Canberra, ACT 2600 (Australia); Charnley, S. B. [Astrochemistry Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Pendleton, Y. J. [NASA Lunar Science Institute, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Maldoni, M. M., E-mail: r.smith@adfa.edu.au, E-mail: c.wright@adfa.edu.au, E-mail: g.robinson@adfa.edu.au, E-mail: Steven.B.Charnley@nasa.gov, E-mail: yvonne.pendleton@nasa.gov [Geoscience Australia, Canberra, ACT 2601 (Australia)

    2011-12-20T23:59:59.000Z

    Recent surface chemistry experiments have shown that the hydrogenation of molecular oxygen on interstellar dust grains is a plausible formation mechanism, via hydrogen peroxide (H{sub 2}O{sub 2}), for the production of water (H{sub 2}O) ice mantles in the dense interstellar medium. Theoretical chemistry models also predict the formation of a significant abundance of H{sub 2}O{sub 2} ice in grain mantles by this route. At their upper limits, the predicted and experimental abundances are sufficiently high that H{sub 2}O{sub 2} should be detectable in molecular cloud ice spectra. To investigate this further, laboratory spectra have been obtained for H{sub 2}O{sub 2}/H{sub 2}O ice films between 2.5 and 200 {mu}m, from 10 to 180 K, containing 3%, 30%, and 97% H{sub 2}O{sub 2} ice. Integrated absorbances for all the absorption features in low-temperature H{sub 2}O{sub 2} ice have been derived from these spectra. For identifying H{sub 2}O{sub 2} ice, the key results are the presence of unique features near 3.5, 7.0, and 11.3 {mu}m. Comparing the laboratory spectra with the spectra of a group of 24 protostars and field stars, all of which have strong H{sub 2}O ice absorption bands, no absorption features are found that can definitely be identified with H{sub 2}O{sub 2} ice. In the absence of definite H{sub 2}O{sub 2} features, the H{sub 2}O{sub 2} abundance is constrained by its possible contribution to the weak absorption feature near 3.47 {mu}m found on the long-wavelength wing of the 3 {mu}m H{sub 2}O ice band. This gives an average upper limit for H{sub 2}O{sub 2}, as a percentage of H{sub 2}O, of 9% {+-} 4%. This is a strong constraint on parameters for surface chemistry experiments and dense cloud chemistry models.

  14. Vapor spill pipe monitor

    DOE Patents [OSTI]

    Bianchini, G.M.; McRae, T.G.

    1983-06-23T23:59:59.000Z

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

  15. Evaluation of Mixed-Phase Cloud Microphysics Parameterizations with the NCAR Single Column Climate Model (SCAM) and ARM Observations

    SciTech Connect (OSTI)

    Liu, X; Ghan, SJ; Xie, S

    2007-04-01T23:59:59.000Z

    Mixed-phase stratus clouds are ubiquitous in the Arctic and play an important role in climate in this region. However, climate models have generally proven unsuccessful at simulating the partitioning of condensed water into liquid droplets and ice crystals in these Arctic clouds, which affect modeled cloud phase, cloud lifetime and radiative properties. An ice nucleation parameterization and a vapor deposition scheme were developed that together provide a physically-consistent treatment of mixed-phase clouds in global climate models. These schemes have been implemented in the National Center for Atmospheric Research (NCAR) Community Atmospheric Model Version 3 (CAM3). This report documents the performance of these schemes against ARM Mixed-phase Arctic Cloud Experiment (M-PACE) observations using the CAM single column model version (SCAM). SCAM with our new schemes has a more realistic simulation of the cloud phase structure and the partitioning of condensed water into liquid droplets against observations during the M-PACE than the standard CAM simulations.

  16. Rapid Migration of Radionuclides Leaked from High-Level Water Tanks; A Study of Salinity Gradients, Wetted Path Geometry and Water Vapor Transport

    SciTech Connect (OSTI)

    Anderson l. Ward; Glendon W. Gee; John S. Selker; Clay Cooper

    2002-04-24T23:59:59.000Z

    The basis of this study was the hypothesis that the physical and chemical properties of hypersaline tank waste could lead to wetting from instability and fingered flow following a tank leak. Thus, the goal of this project was to develop an understanding of the impacts of the properties of hypersaline fluids on transport through the unsaturated zone beneath Hanford's Tank Farms. There were three specific objectives (i) to develop an improved conceptualization of hypersaline fluid transport in laboratory (ii) to identify the degree to which field conditions mimic the flow processes observed in the laboratory and (iii) to provide a validation data set to establish the degree to which the conceptual models, embodied in a numerical simulator, could explain the observed field behavior. As hypothesized, high ionic strength solutions entering homogeneous pre-wetted porous media formed unstable wetting fronts atypical of low ionic strength infiltration. In the field, this mechanism could for ce flow in vertical flow paths, 5-15 cm in width, bypassing much of the media and leading to waste penetration to greater depths than would be predicted by current conceptual models. Preferential flow may lead to highly accelerated transport through large homogeneous units, and must be included in any conservative analysis of tank waste losses through coarse-textured units. However, numerical description of fingered flow using current techniques has been unreliable, thereby precluding tank-scale 3-D simulation of these processes. A new approach based on nonzero, hysteretic contract angles and fluid-dependent liquid entry has been developed for the continuum scale modeling of fingered flow. This approach has been coupled with and adaptive-grid finite-difference solver to permit the prediction of finger formation and persistence form sub centimeter scales to the filed scale using both scalar and vector processors. Although laboratory experiments demonstrated that elevated surface tens ion of imbibing solutions can enhance vertical fingered flow, this phenomenon was not observed in the field. Field tests showed that the fingered flow behavior was overwhelmed by the variability in texture resulting from differences in the depositional environment. Field plumes were characterized by lateral spreading with an average width to depth aspect ratio of 4. For both vertical fingers and lateral flow, the high ionic strength contributed to the vapor phase dilution of the waste, which increased waste volume and pushed the wetting from well beyond what would have occurred if the volume of material had remained unchanged from that initially released into the system. It was also observed that following significant vapor-phase dilution of this waste simulants that streams of colloids were ejected from the sediment surfaces. It was shown that due to the high-sodium content of the tank wastes the colloids were deflocculated below a critical salt concentration in Hanford sediments. Th e released colloids, which at the site would be expected to carry the bulk of the sorbed heavy metals and radioisotopes, were mobile though coarse Hanford sediments, but clogged finer layers. The developments resulting from this study are already being applied at Hanford in the nonisothermal prediction of the hypersaline, high pH waste migration in tank farms and in the development of inverse methods for history matching under DOE's Groundwater/Vadose Zone Integration Project at Hanford.

  17. Rapid Migration of Radionuclides Leaked from High-Level Water Tanks: A Study of Salinity Gradients, Wetted Path Geometry and Water Vapor Transport

    SciTech Connect (OSTI)

    Anderson L. Ward; Glendon W. Gee; John S. Selker; Caly Cooper

    2002-04-24T23:59:59.000Z

    The basis of this study was the hypothesis that the physical and chemical properties of hypersaline tank waste could lead to wetting from instability and fingered flow following a tank leak. Thus, the goal of this project was to develop an understanding of the impacts of the properties of hypersaline fluids on transport through the unsaturated zone beneath Hanford's Tank Farms. There were three specific objectives (i) to develop an improved conceptualization of hypersaline fluid transport in laboratory (ii) to identify the degree to which field conditions mimic the flow processes observed in the laboratory and (iii) to provide a validation data set to establish the degree to which the conceptual models, embodied in a numerical simulator, could explain the observed field behavior. As hypothesized, high ionic strength solutions entering homogeneous pre-wetted porous media formed unstable wetting fronts a typical of low ionic strength infiltration. In the field, this mechanism could force flow in vertical flow paths, 5-15 cm in width, bypassing much of the media and leading to waste penetration to greater depths than would be predicted by current conceptual models. Preferential flow may lead to highly accelerated transport through large homogeneous units, and must be included in any conservative analysis of tank waste losses through coarse-textured units. However, numerical description of fingered flow using current techniques has been unreliable, thereby precluding tank-scale 3-D simulation of these processes. A new approach based on nonzero, hysteretic contact angles and fluid-dependent liquid entry has been developed for the continuum scale modeling of fingered flow. This approach has been coupled with and adaptive-grid finite-difference solver to permit the prediction of finger formation and persistence form sub centimeter scales to the filed scale using both scalar and vector processors. Although laboratory experiments demonstrated that elevated surface tension of imbibing solutions can enhance vertical fingered flow, this phenomenon was not observed in the field. Field tests of showed that the fingered flow behavior was overwhelmed by the variability in texture resulting from differences in the depositional environment. Field plumes were characterized by lateral spreading with an average width to depth aspect ratio of 4. For both vertical fingers and lateral flow, the high ionic strength contributed to the vapor phase dilution of the waste, which increased waste volume and pushed the wetting from well beyond what would have occurred if the volume of material had remained unchanged from that initially released into the system. It was also observed that following significant vapor-phase dilution of the waste simulants that streams of colloids were ejected from the sediment surfaces. It was shown that due to the high-sodium content of the tank wastes the colloids were deflocculated below a critical salt concentration in Hanford sediment s. The released colloids, which at the site would be expected to carry the bulk of the sorbed heavy metals and radioisotopes, were mobile though coarse Hanford sediments, but clogged finer layers. The developments resulting from this study are already being applied at Hanford in the nonisothermal prediction of the hypersaline, high pH waste migration in tank farms and in the development of inverse methods for history matching under DOE's Groundwater/Vadose Zone Integration Project at Hanford.

  18. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

    1995-09-26T23:59:59.000Z

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

  19. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, John P. (Idaho Falls, ID); Larson, Ronald A. (Idaho Falls, ID); Goodrich, Lorenzo D. (Shelley, ID); Hall, Harold J. (Idaho Falls, ID); Stoddard, Billy D. (Idaho Falls, ID); Davis, Sean G. (Idaho Falls, ID); Kaser, Timothy G. (Idaho Falls, ID); Conrad, Frank J. (Albuquerque, NM)

    1995-01-01T23:59:59.000Z

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet.

  20. acetone vapor sensing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    XI, Universit de 7 ATMOSPHERIC WATER VAPOR PROFILES DERIVED FROM REMOTE-SENSING RADIOMETER MEASUREMENTS CiteSeer Summary: The feasibility and preliminary testing of a low...

  1. Parameterizations of Cloud Microphysics and Indirect Aerosol Effects

    SciTech Connect (OSTI)

    Tao, Wei-Kuo [NASA/GSFC] [NASA/GSFC

    2014-05-19T23:59:59.000Z

    1. OVERVIEW Aerosols and especially their effect on clouds are one of the key components of the climate system and the hydrological cycle [Ramanathan et al., 2001]. Yet, the aerosol effect on clouds remains largely unknown and the processes involved not well understood. A recent report published by the National Academy of Science states "The greatest uncertainty about the aerosol climate forcing - indeed, the largest of all the uncertainties about global climate forcing - is probably the indirect effect of aerosols on clouds [NRC, 2001]." The aerosol effect on clouds is often categorized into the traditional "first indirect (i.e., Twomey)" effect on the cloud droplet sizes for a constant liquid water path [Twomey, 1977] and the "semi-direct" effect on cloud coverage [e.g., Ackerman et al., 2000]. Enhanced aerosol concentrations can also suppress warm rain processes by producing a narrow droplet spectrum that inhibits collision and coalescence processes [e.g., Squires and Twomey, 1961; Warner and Twomey, 1967; Warner, 1968; Rosenfeld, 1999]. The aerosol effect on precipitation processes, also known as the second type of aerosol indirect effect [Albrecht, 1989], is even more complex, especially for mixed-phase convective clouds. Table 1 summarizes the key observational studies identifying the microphysical properties, cloud characteristics, thermodynamics and dynamics associated with cloud systems from high-aerosol continental environments. For example, atmospheric aerosol concentrations can influence cloud droplet size distributions, warm-rain process, cold-rain process, cloud-top height, the depth of the mixed phase region, and occurrence of lightning. In addition, high aerosol concentrations in urban environments could affect precipitation variability by providing an enhanced source of cloud condensation nuclei (CCN). Hypotheses have been developed to explain the effect of urban regions on convection and precipitation [van den Heever and Cotton, 2007 and Shepherd, 2005]. Recently, a detailed spectral-bin microphysical scheme was implemented into the Goddard Cumulus Ensemble (GCE) model. Atmospheric aerosols are also described using number density size-distribution functions. A spectral-bin microphysical model is very expensive from a computational point of view and has only been implemented into the 2D version of the GCE at the present time. The model is tested by studying the evolution of deep tropical clouds in the west Pacific warm pool region and summertime convection over a mid-latitude continent with different concentrations of CCN: a low "clean" concentration and a high "dirty" concentration. The impact of atmospheric aerosol concentration on cloud and precipitation will be investigated. 2. MODEL DESCRIPTION AND CASE STUDIES 2.1 GCE MODEL The model used in this study is the 2D version of the GCE model. Modeled flow is anelastic. Second- or higher-order advection schemes can produce negative values in the solution. Thus, a Multi-dimensional Positive Definite Advection Transport Algorithm (MPDATA) has been implemented into the model. All scalar variables (potential temperature, water vapor, turbulent coefficient and all five hydrometeor classes) use forward time differencing and the MPDATA for advection. Dynamic variables, u, v and w, use a second-order accurate advection scheme and a leapfrog time integration (kinetic energy semi-conserving method). Short-wave (solar) and long-wave radiation as well as a subgrid-scale TKE turbulence scheme are also included in the model. Details of the model can be found in Tao and Simpson (1993) and Tao et al. (2003). 2.2 Microphysics (Bin Model) The formulation of the explicit spectral-bin microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (cloud droplets and raindrops), and six types of ice particles: pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail. Each type is described by a special size distribution function containing 33 categories (bin

  2. Simulating mixed-phase Arctic stratus clouds: Sensitivity to ice initiationmechanisms

    SciTech Connect (OSTI)

    Sednev, I.; Menon, S.; McFarquhar, G.

    2009-04-10T23:59:59.000Z

    The importance of Arctic mixed-phase clouds on radiation and the Arctic climate is well known. However, the development of mixed-phase cloud parameterization for use in large scale models is limited by lack of both related observations and numerical studies using multidimensional models with advanced microphysics that provide the basis for understanding the relative importance of different microphysical processes that take place in mixed-phase clouds. To improve the representation of mixed-phase cloud processes in the GISS GCM we use the GISS single-column model coupled to a bin resolved microphysics (BRM) scheme that was specially designed to simulate mixed-phase clouds and aerosol-cloud interactions. Using this model with the microphysical measurements obtained from the DOE ARM Mixed-Phase Arctic Cloud Experiment (MPACE) campaign in October 2004 at the North Slope of Alaska, we investigate the effect of ice initiation processes and Bergeron-Findeisen process (BFP) on glaciation time and longevity of single-layer stratiform mixed-phase clouds. We focus on observations taken during October 9th-10th, which indicated the presence of a single-layer mixed-phase clouds. We performed several sets of 12-hour simulations to examine model sensitivity to different ice initiation mechanisms and evaluate model output (hydrometeors concentrations, contents, effective radii, precipitation fluxes, and radar reflectivity) against measurements from the MPACE Intensive Observing Period. Overall, the model qualitatively simulates ice crystal concentration and hydrometeors content, but it fails to predict quantitatively the effective radii of ice particles and their vertical profiles. In particular, the ice effective radii are overestimated by at least 50%. However, using the same definition as used for observations, the effective radii simulated and that observed were more comparable. We find that for the single-layer stratiform mixed-phase clouds simulated, process of ice phase initiation due to freezing of supercooled water in both saturated and subsaturated (w.r.t. water) environments is as important as primary ice crystal origination from water vapor. We also find that the BFP is a process mainly responsible for the rates of glaciation of simulated clouds. These glaciation rates cannot be adequately represented by a water-ice saturation adjustment scheme that only depends on temperature and liquid and solid hydrometeors contents as is widely used in bulk microphysics schemes and are better represented by processes that also account for supersaturation changes as the hydrometeors grow.

  3. Simulating mixed-phase Arctic stratus clouds: sensitivity to ice initiation mechanisms

    SciTech Connect (OSTI)

    Sednev, Igor; Sednev, I.; Menon, S.; McFarquhar, G.

    2008-02-18T23:59:59.000Z

    The importance of Arctic mixed-phase clouds on radiation and the Arctic climate is well known. However, the development of mixed-phase cloud parameterization for use in large scale models is limited by lack of both related observations and numerical studies using multidimensional models with advanced microphysics that provide the basis for understanding the relative importance of different microphysical processes that take place in mixed-phase clouds. To improve the representation of mixed-phase cloud processes in the GISS GCM we use the GISS single-column model coupled to a bin resolved microphysics (BRM) scheme that was specially designed to simulate mixed-phase clouds and aerosol-cloud interactions. Using this model with the microphysical measurements obtained from the DOE ARM Mixed-Phase Arctic Cloud Experiment (MPACE) campaign in October 2004 at the North Slope of Alaska, we investigate the effect of ice initiation processes and Bergeron-Findeisen process (BFP) on glaciation time and longevity of single-layer stratiform mixed-phase clouds. We focus on observations taken during 9th-10th October, which indicated the presence of a single-layer mixed-phase clouds. We performed several sets of 12-h simulations to examine model sensitivity to different ice initiation mechanisms and evaluate model output (hydrometeors concentrations, contents, effective radii, precipitation fluxes, and radar reflectivity) against measurements from the MPACE Intensive Observing Period. Overall, the model qualitatively simulates ice crystal concentration and hydrometeors content, but it fails to predict quantitatively the effective radii of ice particles and their vertical profiles. In particular, the ice effective radii are overestimated by at least 50%. However, using the same definition as used for observations, the effective radii simulated and that observed were more comparable. We find that for the single-layer stratiform mixed-phase clouds simulated, process of ice phase initiation due to freezing of supercooled water in both saturated and undersaturated (w.r.t. water) environments is as important as primary ice crystal origination from water vapor. We also find that the BFP is a process mainly responsible for the rates of glaciation of simulated clouds. These glaciation rates cannot be adequately represented by a water-ice saturation adjustment scheme that only depends on temperature and liquid and solid hydrometeors contents as is widely used in bulk microphysics schemes and are better represented by processes that also account for supersaturation changes as the hydrometeors grow.

  4. Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighandSWPA / SPRA /Ml'.Solar Thermal Solar ThermalJul 13 1 2 3

  5. Cloud Computing

    SciTech Connect (OSTI)

    Pete Beckman and Ian Foster

    2009-12-04T23:59:59.000Z

    Chicago Matters: Beyond Burnham (WTTW). Chicago has become a world center of "cloud computing." Argonne experts Pete Beckman and Ian Foster explain what "cloud computing" is and how you probably already use it on a daily basis.

  6. Clouds are integral to the climate system. They are a crucial component of the global water cycle, vital

    E-Print Network [OSTI]

    Allan, Richard P.

    gives a value of 61.6% cloud cover over the period January 2001 to December 2010). These estimates were with the Earth's radiative energy balance. They cool the surface by shading it from the direct solar beam but almost as strongly enhance the greenhouse effect of the atmosphere by reducing the efficiency by which

  7. Liquefied Natural Gas (LNG) Vapor Dispersion Modeling with Computational Fluid Dynamics Codes

    E-Print Network [OSTI]

    Qi, Ruifeng

    2012-10-19T23:59:59.000Z

    Federal regulation 49 CFR 193 and standard NFPA 59A require the use of validated consequence models to determine the vapor cloud dispersion exclusion zones for accidental liquefied natural gas (LNG) releases. For modeling purposes, the physical...

  8. LNG fire and vapor control system technologies

    SciTech Connect (OSTI)

    Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

    1982-06-01T23:59:59.000Z

    This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

  9. Warm water vapor envelope in the supergiants alf Ori and alf Her and its effects on the apparent size from the near-infrared to the mid-infrared

    E-Print Network [OSTI]

    Keiichi Ohnaka

    2004-06-02T23:59:59.000Z

    We present a possible interpretation for the increase of the angular diameter of the supergiants alf Ori (M1-2 Ia-Ibe) and alf Her (M5 Ib-II) from the K band to the 11 micron region and the high-resolution 11 micron spectra without any salient spectral features revealed by Weiner et al. (2003). The angular diameters as well as the high-resolution spectra of alf Ori and alf Her obtained in the 11 micron region can be reproduced by a warm water vapor envelope, whose presence in alf Ori was revealed by Tsuji (2000) based on the reanalysis of the near-infrared data obtained with the Stratoscope II. While prominent absorption due to H2O can be expected from such a dense, warm water vapor envelope, the absorption lines can be filled in by emission from the extended part of the envelope. This effect leads to a significant weakening of the H2O lines in the 11 micron region, and makes the observed spectra appear to be rather featureless and continuum-like. However, the emission due to H2O lines from the extended envelope leads to an increase of the apparent size in this spectral region. The observed angular diameter and the high resolution spectra of alf Ori and alf Her in the 11 micron region can be best interpreted by the water vapor envelope extending to 1.4--1.5 Rstar, with a temperature of about 2000 K and a column density of H2O of the order of 10^20 cm^-2.

  10. Vapor scavenging by atmospheric aerosol particles

    SciTech Connect (OSTI)

    Andrews, E.

    1996-05-01T23:59:59.000Z

    Particle growth due to vapor scavenging was studied using both experimental and computational techniques. Vapor scavenging by particles is an important physical process in the atmosphere because it can result in changes to particle properties (e.g., size, shape, composition, and activity) and, thus, influence atmospheric phenomena in which particles play a role, such as cloud formation and long range transport. The influence of organic vapor on the evolution of a particle mass size distribution was investigated using a modified version of MAEROS (a multicomponent aerosol dynamics code). The modeling study attempted to identify the sources of organic aerosol observed by Novakov and Penner (1993) in a field study in Puerto Rico. Experimentally, vapor scavenging and particle growth were investigated using two techniques. The influence of the presence of organic vapor on the particle`s hydroscopicity was investigated using an electrodynamic balance. The charge on a particle was investigated theoretically and experimentally. A prototype apparatus--the refractive index thermal diffusion chamber (RITDC)--was developed to study multiple particles in the same environment at the same time.

  11. Mixed phase clouds, cloud electrification and remote sensing.

    SciTech Connect (OSTI)

    Chylek, P. (Petr); Borel, C. C. (Christoph C.); Klett, James

    2004-01-01T23:59:59.000Z

    Most of hypothesis trying to explain charge separation in thunderstorm clouds require presence of ice and supercooled water. Thus the existence of ice or at least mixed phase regions near cloud tops should be a necessary (but not a sufficient) condition for development of lightning. We show that multispectral satellite based instruments, like the DOE MTI (Multispectral Thermal Imager) or NASA MODIS (Moderate Resolution Imaging Spectroradiometer), using the near infrared and visible spectral bands are able to distinguish between water, ice and mixed phase cloud regions. An analysis of the MTI images of mixed phase clouds - with spatial resolution of about 20 m - shows regions of pure water, pure ice as well as regions of water/ice mixtures. We suggest that multispectral satellite instruments may be useful for a short time forecast of lightning probabilities.

  12. Christopher RUF EXTERNAL SPONSORED RESEARCH FUNDING HISTORY 06/30/1992 to 04/30/1996; "GEOSAT Follow-On water vapor radiometer engineering support,"

    E-Print Network [OSTI]

    Ruf, Christopher

    Calibration Standard for Interferometric and Polarimetric Microwave Radiometers," EMAG Technologies, Inc., Ann Cloud Radar Studies," Dept. of Energy; $500,000 ($75,000/yr to Ruf); Co-I (PI is T. Ackermann, PSU Dept/30/2000; "Conical-Scanning Microwave Imager/Sounder Development Program," Ball Aerospace and Technology Corporation

  13. Corrigendum to Aerosol impacts on California winter clouds and precipitation during CalWater 2011: local pollution versus long-range transported dust published in Atmos. Chem. Phys., 14, 81–101, 2014

    SciTech Connect (OSTI)

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, A.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-05-01T23:59:59.000Z

    In the paper “Aerosol impacts on California winter clouds and precipitation during CalWater 2011: local pollution versus long-range transported dust” by J. Fan et al., wrong versions of Fig. 8 and Fig. 12 were published. Please find the correct figures below.

  14. The influence of stratus, stratocumulus, and altocumulus clouds on the spectral distribution of solar radiation over Antarctic waters

    E-Print Network [OSTI]

    Pettett, James Eugene

    1973-01-01T23:59:59.000Z

    CLOUD WAVEBANDS (per cent) Q s 0 COVER B G-R I (eel/cm day) 458/115E Nov 27 Nov 27-28 Nov 28 508/115E Dec 1 Nov 29-Dec 2 Nov 29 508/78E Jan 9 Jan 7-12 Jan 12 558/115E Dec 4 Dec 3-5 Dec 5 558/72E Jan 6 Jan 5-6 Jan 5 U X Sc(Brkn) A... DATES CLOUD WAVEBANDS(per cent) Q C COVER B G-R I (cal/cm day) 60S/1148 Dec 8 Dec 6-8 Dec 6 608/81E Dec 26 Dec 23-26 Dec 23 60S/74E Jan 2 Jan 2-4 Jan 3 65S/94E Dec 21 Dec 10-22 Dec 11 65S/75E Dec 30 Dec 27-31 Dec 27 U 23 X Ac...

  15. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  16. Kinematical relations among radar-observed water concentrations, vertical motions, and liquid-water drop-size spectra in convective clouds

    E-Print Network [OSTI]

    Runnels, Robert Clayton

    1962-01-01T23:59:59.000Z

    of return settling are often cloudless or consist of cumulus clouds which have had their growth impeded. If conditions in the atmosphere are favorable, convection cells form and the updraft areas associated with these cells develop into cumulonimbus... and time, M & M(x, y, z, t). The x- and y-directions are horizontal and z-direction is positive toward the zenith. If the quantity M is conservative, the local rate of change at a fixed locality (the local change) can be represented by the following...

  17. Remote Sensing: Cloud Properties P Yang, Texas A&M University, College Station, TX, USA

    E-Print Network [OSTI]

    Baum, Bryan A.

    and the effective particle size. Global cloud observations based on satellite measurements serve many uses of supercooled water and ice particles. Water and ice clouds interact with solar radiation differently and have are analyzed routinely for global cloud macrophysical properties such as cloud height, phase (water, ice

  18. Investigating the Radiative Impact Clouds Using Retrieved Properties to Classify Cloud Type

    E-Print Network [OSTI]

    Hogan, Robin

    of Reading, RG6 6AL, UK Abstract. Active remote sensing allows cloud properties such as ice and liquid water remote sensing, Cloud categorization, Cloud properties, Radiative impact. PACS: 92.60. Vb. INTRODUCTION in a radiation scheme which can simulate the radiation budget and heating rates throughout the atmospheric

  19. A Cloud Detection Algorithm using the Downwelling Infrared Radiance Measured by an Infrared Pyrometer of the Ground-based Microwave Radiometer

    SciTech Connect (OSTI)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-01-01T23:59:59.000Z

    For a better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear sky Tb obtained by an empirical formula as a function of surface air temperature and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of the clear sky condition. It is designated as cloud free data only when both the spectral and temporal tests confirm a cloud free data. Overall, most of the thick and uniform clouds are successfully screened out by the spectral test, while the broken and fast-varying clouds are screened out by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for 6 months, from January 2013 to June 2013. The overall proportion correct is about 88.3% and the probability of detection is 90.8 %, which are comparable with or better than those of previous similar approaches. Two thirds of failures occur when the new algorithm detects clouds while the ceilometer does not detect, resulting in different values of the probability of detection with different cloud base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.

  20. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ahn, M.-H.; Han, D.; Won, H. Y.; Morris, V.

    2015-01-01T23:59:59.000Z

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperaturemore »and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.« less

  1. 1-Dimensional Numerical Model of Thermal Conduction and Vapor Diffusion

    E-Print Network [OSTI]

    Schörghofer, Norbert

    developed by Samar Khatiwala, 2001 extended to variable thermal properties and irregular grid by Norbert Sch for c. Upper boundary condition: a) Radiation Q + k T z z=0 = T4 z=0 Q is the incoming solar flux of Water Vapor with Phase Transitions developed by Norbert Sch¨orghofer, 2003­2004 3 phases: vapor, free

  2. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  3. An annual cycle of Arctic cloud characteristics observed by radar and lidar at SHEBA

    E-Print Network [OSTI]

    Shupe, Matthew

    distribution of cloud boundary heights, and occurrence of liquid phase in clouds are determined from radar-observed clouds containing liquid was 73% for the year. The least amount of liquid water phase was observed during-detected clouds. Liquid was distributed in a combination of all-liquid and mixed phase clouds, and was detected

  4. In-well vapor stripping drilling and characterization work plan

    SciTech Connect (OSTI)

    Koegler, K.J.

    1994-03-13T23:59:59.000Z

    This work plan provides the information necessary for drilling, sampling, and hydrologic testing of wells to be completed in support of a demonstration of the in-well vapor stripping system. The in-well vapor stripping system is a remediation technology designed to preferentially extract volatile organic compounds (VOCs) from contaminated groundwater by converting them to a vapor phase. Air-lift pumping is used to lift and aerate groundwater within the well. The volatiles escaping the aerated water are drawn off by a slight vacuum and treated at the surface while the water is allowed to infiltrate the vadose zone back to the watertable.

  5. Effects of capillarity and vapor adsorption in the depletion of vapor-dominated geothermal reservoirs

    SciTech Connect (OSTI)

    Pruess, Karsten; O'Sullivan, Michael

    1992-01-01T23:59:59.000Z

    Vapor-dominated geothermal reservoirs in natural (undisturbed) conditions contain water as both vapor and liquid phases. The most compelling evidence for the presence of distributed liquid water is the observation that vapor pressures in these systems are close to saturated vapor pressure for measured reservoir temperatures (White et al., 1971; Truesdell and White, 1973). Analysis of natural heat flow conditions provides additional, indirect evidence for the ubiquitous presence of liquid. From an analysis of the heat pipe process (vapor-liquid counterflow) Preuss (1985) inferred that effective vertical permeability to liquid phase in vapor-dominated reservoirs is approximately 10{sup 17} m{sup 2}, for a heat flux of 1 W/m{sup 2}. This value appears to be at the high end of matrix permeabilities of unfractured rocks at The Geysers, suggesting that at least the smaller fractures contribute to liquid permeability. For liquid to be mobile in fractures, the rock matrix must be essentially completely liquid-saturated, because otherwise liquid phase would be sucked from the fractures into the matrix by capillary force. Large water saturation in the matrix, well above the irreducible saturation of perhaps 30%, has been shown to be compatible with production of superheated steam (Pruess and Narasimhan, 1982). In response to fluid production the liquid phase will boil, with heat of vaporization supplied by the reservoir rocks. As reservoir temperatures decline reservoir pressures will decline also. For depletion of ''bulk'' liquid, the pressure would decline along the saturated vapor pressure curve, while for liquid held by capillary and adsorptive forces inside porous media, an additional decline will arise from ''vapor pressure lowering''. Capillary pressure and vapor adsorption effects, and associated vapor pressure lowering phenomena, have received considerable attention in the geothermal literature, and also in studies related to geologic disposal of heat generating nuclear wastes, and in the drying of porous materials. Geothermally oriented studies were presented by Chicoine et al. (1977), Hsieh and Ramey (1978, 1981), Herkelrath et al. (1983), and Nghiem and Ramey (1991). Nuclear waste-related work includes papers by Herkelrath and O'Neal (1985), Pollock (1986), Eaton and Bixler (1987), Pruess et al. (1990), Nitao (1990), and Doughty and E'ruess (1991). Applications to industrial drying of porous materials have been discussed by Hamiathy (1969) arid Whitaker (1977). This paper is primarily concerned with evaluating the impact of vapor pressure lowering (VPL) effects on the depletion behavior of vapor-dominated reservoirs. We have examined experimental data on vapor adsorption and capillary pressures in an effort to identify constitutive relationships that would be applicable to the tight matrix rocks of vapor-dominated systems. Numerical simulations have been performed to evaluate the impact of these effects on the depletion of vapor-dominated reservoirs.

  6. Cloud Computing Adam Barker

    E-Print Network [OSTI]

    St Andrews, University of

    Cloud Computing 1 Adam Barker #12;Overview · Introduction to Cloud computing · Enabling technologies · Di erent types of cloud: IaaS, PaaS and SaaS · Cloud terminology · Interacting with a cloud: management consoles · Launching an instance · Connecting to an instance · Running your application · Clouds

  7. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11T23:59:59.000Z

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  8. Vapor generation methods for explosives detection research. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vapor generation methods for explosives detection research. Vapor generation methods for explosives detection research. Abstract: The generation of calibrated vapor samples of...

  9. Lecture Ch. 8 Cloud Classification

    E-Print Network [OSTI]

    Russell, Lynn

    clouds Middle clouds Grayish, block the sun, sometimes patchy Sharp outlines, rising, bright white1 Lecture Ch. 8 · Cloud Classification ­ Descriptive approach to clouds · Drop Growth and Precipitation Processes ­ Microphysical characterization of clouds · Complex (i.e. Real) Clouds ­ Examples

  10. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08T23:59:59.000Z

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  11. atmospheric water transport: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stenzel, Oliver J 2009-01-01 2 Atmospheric Water Vapor Transport and the Water Balance of North America: Part I CiteSeer Summary: The atmospheric water vapor flux divergence and...

  12. Cloud Controlling Factors --Low Clouds BJORN STEVENS,

    E-Print Network [OSTI]

    Stevens, Bjorn

    Cloud Controlling Factors -- Low Clouds BJORN STEVENS, Department of Atmospheric and Oceanic) clouds is reviewed, with an emphasis on factors that may be expected to change in a changing climate of low-cloud control- ling processes are offered: these include renewing our focus on theory, model

  13. Cloud Controlling Factors --Low Clouds BJORN STEVENS,

    E-Print Network [OSTI]

    Stevens, Bjorn

    Cloud Controlling Factors -- Low Clouds BJORN STEVENS, Department of Atmospheric and Oceanic conspire to determine the statistics and cli- matology of layers of shallow (boundary layer) clouds of low-cloud control- ling processes are offered: these include renewing our focus on theory, model

  14. Cloud Tracking in Cloud-Resolving Models

    E-Print Network [OSTI]

    Plant, Robert

    Cloud Tracking in Cloud-Resolving Models RMetS Conference 4th September 2007 Bob Plant Department of Meteorology, University of Reading, UK #12;Introduction Obtain life cycle statistics for clouds in CRM simulations What is the distribution of cloud lifetimes? What factors determine the lifetime of an individual

  15. Temperature dependent vapor pressures of chlorinated catechols, syringols, and syringaldehydes

    SciTech Connect (OSTI)

    Lei, Y.D.; Shiu, W.Y.; Boocock, D.G.B. [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry] [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry; Wania, F. [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)] [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)

    1999-03-01T23:59:59.000Z

    The vapor pressures of nine chlorinated catechols, syringols, and syringaldehydes were determined as a function of temperature with a gas chromatographic retention time technique. The vapor pressures at 298.15 K were in the range of 0.02--1 Pa, and the enthalpies of vaporization, between 68 and 82 kJ/mol. The validity of the technique was established by a calibration involving four chlorinated phenols with well-known vapor pressures. Using these data and previously reported solubility data, Henry`s law constants for these substances and some chlorinated guaiacols and veratrols were estimated. The vapor pressure of these substances tends to decrease with increasing polarity and an increasing number of chlorine atoms. Henry`s law constants decrease sharply with increasing polarity, suggesting that methylation can result in a significant increase in a chemical`s potential for volatilization from water.

  16. Cloud Security by Max Garvey

    E-Print Network [OSTI]

    Tolmach, Andrew

    Cloud Security Survey by Max Garvey #12;Cloudy Cloud is Cloudy What is the cloud? On Demand Service Network access Resource pooling Elasticity of Resources Measured Service #12;Cloud Types/Variants Iaa Cloud Public Cloud Hybrid Cloud combination. Private cloud with overflow going to public cloud. #12

  17. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23T23:59:59.000Z

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  18. Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part II: Multi-layered cloud

    SciTech Connect (OSTI)

    Morrison, H; McCoy, R B; Klein, S A; Xie, S; Luo, Y; Avramov, A; Chen, M; Cole, J; Falk, M; Foster, M; Genio, A D; Harrington, J; Hoose, C; Khairoutdinov, M; Larson, V; Liu, X; McFarquhar, G; Poellot, M; Shipway, B; Shupe, M; Sud, Y; Turner, D; Veron, D; Walker, G; Wang, Z; Wolf, A; Xu, K; Yang, F; Zhang, G

    2008-02-27T23:59:59.000Z

    Results are presented from an intercomparison of single-column and cloud-resolving model simulations of a deep, multi-layered, mixed-phase cloud system observed during the ARM Mixed-Phase Arctic Cloud Experiment. This cloud system was associated with strong surface turbulent sensible and latent heat fluxes as cold air flowed over the open Arctic Ocean, combined with a low pressure system that supplied moisture at mid-level. The simulations, performed by 13 single-column and 4 cloud-resolving models, generally overestimate the liquid water path and strongly underestimate the ice water path, although there is a large spread among the models. This finding is in contrast with results for the single-layer, low-level mixed-phase stratocumulus case in Part I of this study, as well as previous studies of shallow mixed-phase Arctic clouds, that showed an underprediction of liquid water path. The overestimate of liquid water path and underestimate of ice water path occur primarily when deeper mixed-phase clouds extending into the mid-troposphere were observed. These results suggest important differences in the ability of models to simulate Arctic mixed-phase clouds that are deep and multi-layered versus shallow and single-layered. In general, models with a more sophisticated, two-moment treatment of the cloud microphysics produce a somewhat smaller liquid water path that is closer to observations. The cloud-resolving models tend to produce a larger cloud fraction than the single-column models. The liquid water path and especially the cloud fraction have a large impact on the cloud radiative forcing at the surface, which is dominated by the longwave flux for this case.

  19. Vapor-phase heat-transport system

    SciTech Connect (OSTI)

    Hedstrom, J.C.

    1983-01-01T23:59:59.000Z

    A vapor-phase heat-transport system is being tested in one of the passive test cells at Los Alamos. The system consists of one selective-surface collector and a condenser inside a water storage tank. The refrigerant, R-11, can be returned to the collector by gravity or with a pump. Results from several operating configurations are presented, together with a comparison with other passive systems. A new self-pumping concept is presented.

  20. Cloud Seeding By: Julie Walter

    E-Print Network [OSTI]

    Toohey, Darin W.

    , smoke, that then are cooled because of the high altitudes. As the water or condensation nuclei cool more pushed up enough the warm air that is filled with moisture should reach an optimum cooling point-based Western Weather Consultants, whose company supplied Vail Resorts with the cloud seeding generators

  1. Vaporizer design criteria for ethanol fueled internal combustion engines

    E-Print Network [OSTI]

    Ariyaratne, Arachchi Rallage

    1985-01-01T23:59:59.000Z

    Properties of Alcohols, Water and Petroleum Fuels. 2 Results of regression analysis. 3 Effect of various parameters on vaporization length. 51 4 Predicted tube length for different fuel requirements (Ten stainless steel tubes, 4. 7 mm ID. ). 60 ix LIST... with quality with increasing heat flux as parameter. 18 5 Reynolds Number Factor, F. 6 Suppression Factor, S. 27 27 7 Flow chart of the algorithm for vaporization length. 8 The single tube heat exchanger. 33 36 9 Thermocouple arrangement along...

  2. Stratified vapor generator

    DOE Patents [OSTI]

    Bharathan, Desikan (Lakewood, CO); Hassani, Vahab (Golden, CO)

    2008-05-20T23:59:59.000Z

    A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

  3. Vapor-liquid equilibrium of water-acetone-air at ambient temperatures and pressures. An analysis of different VLE-fitting methods

    SciTech Connect (OSTI)

    Lichtenbelt, J.H.; Schram, B.J.

    1985-04-01T23:59:59.000Z

    The availability of accurate equilibrium data is of high importance in chemical engineering practice both for design and research purposes. It appeared that for the gas absorption system water-acetone-air in the range of special interest for absorption and desorption operations, neither literature data nor calculations following UNIFAC gave a sufficient accuracy. An experimental program was set up to determine equilibrium data with an accuracy within 2% for low acetone concentrations (up to 7 wt % gas phase) at ambient temperature (16-30/sup 0/C) and atmospheric pressure (740-860 mmHg). From experiments the activity coefficient at infinite dilution of acetone ..gamma.. is found to be 6.79 (0.01) at 20/sup 0/C and 7.28 (0.01) at 25/sup 0/C, while the total error in ..gamma.. is 1.5%. The equilibrium constant can be calculated from ..gamma.. and shows the same error. The experimental data-fitting with procedures of Margules (two parameters) and Van Laar were successful, but NRTL, Wilson, and UNIQUAC failed, probably because of the small concentration range used.

  4. Cloud Computing og availability

    E-Print Network [OSTI]

    Christensen, Henrik Bćrbak

    Cloud Computing og availability Projekt i pĺlidelighed Henrik Lavdal - 20010210 Sřren Bardino Kaa - 20011654 Gruppe 8 19-03-2010 #12;Cloud Computing og availability Side 2 af 28 Indholdsfortegnelse as a Service (SaaS) ...................................................................9 Availability i cloud

  5. Ad hoc cloud computing 

    E-Print Network [OSTI]

    McGilvary, Gary Andrew

    2014-11-27T23:59:59.000Z

    Commercial and private cloud providers offer virtualized resources via a set of co-located and dedicated hosts that are exclusively reserved for the purpose of offering a cloud service. While both cloud models appeal to ...

  6. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect (OSTI)

    Eric M. Suuberg; Vahur Oja

    1997-07-01T23:59:59.000Z

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  7. ARM - Measurement - Total cloud water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat flux ARM Data Discovery Browseenergy

  8. DRAFT, Revised June 2012 Aerosol cloud-mediated radiative forcing: highly uncertain and

    E-Print Network [OSTI]

    Daniel, Rosenfeld

    drops, adding more cloud water, and increasing the cloud cover. Aerosols affect these components1 DRAFT, Revised June 2012 Aerosol cloud-mediated radiative forcing: highly uncertain and opposite effects from shallow and deep clouds Daniel Rosenfeld1 , Robert Wood2 , Leo Donner3 , Steven Sherwood4 1

  9. Enhancement of cloud cover and suppression of nocturnal drizzle in stratocumulus polluted by haze

    E-Print Network [OSTI]

    to amplify the negative radiative forcing by increasing cloud cover and cloud water [Albrecht, 1989]. [3] We in ship tracks [Ackerman et al., 2000]. Evidence for secondary effects is ambiguous. Cloud cover is seenEnhancement of cloud cover and suppression of nocturnal drizzle in stratocumulus polluted by haze A

  10. On the Relationship between Thermodynamic Structure and Cloud Top, and Its Climate Significance in the Arctic

    E-Print Network [OSTI]

    Shupe, Matthew

    longwave radiation, resulting in a warming at the surface--the cloud ``greenhouse'' effect. The mag. The authors test the longwave radiative impact of cloud liquid above the inversion through hypothetical liquid water distributions. Optically thin CII clouds alter the effective cloud emission temperature and can

  11. On Demand Surveillance Service in Vehicular Cloud

    E-Print Network [OSTI]

    Weng, Jui-Ting

    2013-01-01T23:59:59.000Z

    Toward Vehicular Service Cloud . . . . . . . . . . . . . . .4.2 Open Mobile Cloud Requirement . . . . .3.1 Mobile Cloud

  12. Parameterizing Size Distribution in Ice Clouds

    SciTech Connect (OSTI)

    DeSlover, Daniel; Mitchell, David L.

    2009-09-25T23:59:59.000Z

    PARAMETERIZING SIZE DISTRIBUTIONS IN ICE CLOUDS David L. Mitchell and Daniel H. DeSlover ABSTRACT An outstanding problem that contributes considerable uncertainty to Global Climate Model (GCM) predictions of future climate is the characterization of ice particle sizes in cirrus clouds. Recent parameterizations of ice cloud effective diameter differ by a factor of three, which, for overcast conditions, often translate to changes in outgoing longwave radiation (OLR) of 55 W m-2 or more. Much of this uncertainty in cirrus particle sizes is related to the problem of ice particle shattering during in situ sampling of the ice particle size distribution (PSD). Ice particles often shatter into many smaller ice fragments upon collision with the rim of the probe inlet tube. These small ice artifacts are counted as real ice crystals, resulting in anomalously high concentrations of small ice crystals (D < 100 µm) and underestimates of the mean and effective size of the PSD. Half of the cirrus cloud optical depth calculated from these in situ measurements can be due to this shattering phenomenon. Another challenge is the determination of ice and liquid water amounts in mixed phase clouds. Mixed phase clouds in the Arctic contain mostly liquid water, and the presence of ice is important for determining their lifecycle. Colder high clouds between -20 and -36 oC may also be mixed phase but in this case their condensate is mostly ice with low levels of liquid water. Rather than affecting their lifecycle, the presence of liquid dramatically affects the cloud optical properties, which affects cloud-climate feedback processes in GCMs. This project has made advancements in solving both of these problems. Regarding the first problem, PSD in ice clouds are uncertain due to the inability to reliably measure the concentrations of the smallest crystals (D < 100 µm), known as the “small mode”. Rather than using in situ probe measurements aboard aircraft, we employed a treatment of ice cloud optical properties formulated in terms of PSD parameters in combination with remote measurements of thermal radiances to characterize the small mode. This is possible since the absorption efficiency (Qabs) of small mode crystals is larger at 12 µm wavelength relative to 11 µm wavelength due to the process of wave resonance or photon tunneling more active at 12 µm. This makes the 12/11 µm absorption optical depth ratio (or equivalently the 12/11 µm Qabs ratio) a means for detecting the relative concentration of small ice particles in cirrus. Using this principle, this project tested and developed PSD schemes that can help characterize cirrus clouds at each of the three ARM sites: SGP, NSA and TWP. This was the main effort of this project. These PSD schemes and ice sedimentation velocities predicted from them have been used to test the new cirrus microphysics parameterization in the GCM known as the Community Climate Systems Model (CCSM) as part of an ongoing collaboration with NCAR. Regarding the second problem, we developed and did preliminary testing on a passive thermal method for retrieving the total water path (TWP) of Arctic mixed phase clouds where TWPs are often in the range of 20 to 130 g m-2 (difficult for microwave radiometers to accurately measure). We also developed a new radar method for retrieving the cloud ice water content (IWC), which can be vertically integrated to yield the ice water path (IWP). These techniques were combined to determine the IWP and liquid water path (LWP) in Arctic clouds, and hence the fraction of ice and liquid water. We have tested this approach using a case study from the ARM field campaign called M-PACE (Mixed-Phase Arctic Cloud Experiment). This research led to a new satellite remote sensing method that appears promising for detecting low levels of liquid water in high clouds typically between -20 and -36 oC. We hope to develop this method in future research.

  13. To estimate vapor pressure easily

    SciTech Connect (OSTI)

    Yaws, C.L.; Yang, H.C. (Lamar Univ., Beaumont, TX (USA))

    1989-10-01T23:59:59.000Z

    Vapor pressures as functions of temperature for approximately 700 major organic chemical compounds are given. The tabulation also gives the temperature range for which the data are applicable. Minimum and maximum temperatures are denoted by TMIN and TMAX. The Antoine equation that correlates vapor pressure as a function of temperature is described. A representative comparison of calculated and actual data values for vapor pressure is shown for ethyl alcohol. The coefficient tabulation is based on both literature (experimental data) and estimated values.

  14. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    1996-12-31T23:59:59.000Z

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  15. Cloud Computing For Bioinformatics

    E-Print Network [OSTI]

    Ferrara, Katherine W.

    Cloud Computing For Bioinformatics EC2 and AMIs #12;Quick-starting an EC2 instance (let's get our feet wet!) Cloud Computing #12;Cloud Computing: EC2 instance Quick Start · On EC2 console, we can click on Launch Instance · This will let us get up and going quickly #12;Cloud Computing: EC2 instance

  16. Ice cloud microphysics retrievals from millimeter radar and visible optical depth using an estimation theory approach

    E-Print Network [OSTI]

    Stephens, Graeme L.

    of the planet. These effects occur as a consequence of the way cloud particles scatter and absorb radiation, 0325); 1655 Global Change: Water cycles (1836); KEYWORDS: ice water content retrieval, cirrus cloud), 4335, doi:10.1029/2002JD002693, 2003. 1. Introduction [2] Clouds profoundly affect the radiation budget

  17. Clouds of short-circuited thermionic nanobatteries and promising prospects for development of nanobattery-based aerosol fusion reactors. The preliminary report

    E-Print Network [OSTI]

    Oleg Meshcheryakov

    2012-04-13T23:59:59.000Z

    The physical mechanisms of periodic separation and relaxation of electric charges within aerosol particles possessing the properties the short-circuited batteries can be extremely diverse. With use of appropriate materials and dispersing methods, the electrochemical, thermoelectric, thermionic, pyroelectric, photoelectric, photo electronic emission, or even radionuclide-based emission micro and nano-batteries can be synthesized and be dispersed in the air as clouds self-assembed of the short-circuited aerosol batteries due to the inter-particle electromagnetic dipole-dipole attraction. Intense thermionic emission from ionized hot spots migrating on the relatively cold surface of charged explosive particles, can convert these particles into short-circuited thermionic batteries, turning an aerosol cloud consisting of such unipolar charged, gradually decomposing explosive particles into ball lightning. The slow exothermic decomposition of the highly sensitive explosive aerosol particles, catalyzed by excess ions on their surface, and also ion-catalyzed reactions of slow water vapor induced oxidation of charged combustible aerosol particles underlie two main classes of natural ball lightning. At the same time, the artificially generated clouds consisting of such unipolar charged aerosol nanobatteries, probably, can have some useful applications, not only military ones. In particular, it seems that high-performance pyroelectric fusion reactors could be created on the basis of such ball-shaped aerosol clouds self-assembled of pyroelectric nanocrystals - short-circuited pyroelectric nanobatteries.

  18. Vapor Retarder Classification - Building America Top Innovation...

    Energy Savers [EERE]

    the Top Innovation. See an example of vapor retarder best practices in action. Find other case studies of Building America projects across the country that utilizes vapor retarder...

  19. Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects

    E-Print Network [OSTI]

    Chickos, James S.

    Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid hydrocarbons and their perdeuterated analogues have been determined by correlation-gas chromatography of cyclohexane-d12 and benzene-d6. Other hydrocarbons studied include the perdeuterated forms of hexane, toluene

  20. Water on Earth Source % of Supply

    E-Print Network [OSTI]

    Cochran-Stafira, D. Liane

    of heat. High Heat Capacity · Water absorbs or releases more heat than many substances for each degree is lowered. · spread salt on streets in winter to prevent ice formation. High Heat Capacity · Water vapor in our environment. · On earth, water is found as a liquid, as a solid (ice) or as a gas (water vapor

  1. Using Radar, Lidar, and Radiometer measurements to Classify Cloud Type and Study Middle-Level Cloud Properties

    SciTech Connect (OSTI)

    Wang, Zhien

    2010-06-29T23:59:59.000Z

    The project is mainly focused on the characterization of cloud macrophysical and microphysical properties, especially for mixed-phased clouds and middle level ice clouds by combining radar, lidar, and radiometer measurements available from the ACRF sites. First, an advanced mixed-phase cloud retrieval algorithm will be developed to cover all mixed-phase clouds observed at the ACRF NSA site. The algorithm will be applied to the ACRF NSA observations to generate a long-term arctic mixed-phase cloud product for model validations and arctic mixed-phase cloud processes studies. To improve the representation of arctic mixed-phase clouds in GCMs, an advanced understanding of mixed-phase cloud processes is needed. By combining retrieved mixed-phase cloud microphysical properties with in situ data and large-scale meteorological data, the project aim to better understand the generations of ice crystals in supercooled water clouds, the maintenance mechanisms of the arctic mixed-phase clouds, and their connections with large-scale dynamics. The project will try to develop a new retrieval algorithm to study more complex mixed-phase clouds observed at the ACRF SGP site. Compared with optically thin ice clouds, optically thick middle level ice clouds are less studied because of limited available tools. The project will develop a new two wavelength radar technique for optically thick ice cloud study at SGP site by combining the MMCR with the W-band radar measurements. With this new algorithm, the SGP site will have a better capability to study all ice clouds. Another area of the proposal is to generate long-term cloud type classification product for the multiple ACRF sites. The cloud type classification product will not only facilitates the generation of the integrated cloud product by applying different retrieval algorithms to different types of clouds operationally, but will also support other research to better understand cloud properties and to validate model simulations. The ultimate goal is to improve our cloud classification algorithm into a VAP.

  2. Passive vapor extraction feasibility study

    SciTech Connect (OSTI)

    Rohay, V.J.

    1994-06-30T23:59:59.000Z

    Demonstration of a passive vapor extraction remediation system is planned for sites in the 200 West Area used in the past for the disposal of waste liquids containing carbon tetrachloride. The passive vapor extraction units will consist of a 4-in.-diameter pipe, a check valve, a canister filled with granular activated carbon, and a wind turbine. The check valve will prevent inflow of air that otherwise would dilute the soil gas and make its subsequent extraction less efficient. The granular activated carbon is used to adsorb the carbon tetrachloride from the air. The wind turbine enhances extraction rates on windy days. Passive vapor extraction units will be designed and operated to meet all applicable or relevant and appropriate requirements. Based on a cost analysis, passive vapor extraction was found to be a cost-effective method for remediation of soils containing lower concentrations of volatile contaminants. Passive vapor extraction used on wells that average 10-stdft{sup 3}/min air flow rates was found to be more cost effective than active vapor extraction for concentrations below 500 parts per million by volume (ppm) of carbon tetrachloride. For wells that average 5-stdft{sup 3}/min air flow rates, passive vapor extraction is more cost effective below 100 ppm.

  3. RISK ASSESSMENT CLOUD COMPUTING

    E-Print Network [OSTI]

    Columbia University

    SECURITY RESEARCH PRIVACY RISK ASSESSMENT AMC DATA FISMA CLOUD COMPUTING MOBILE DEVICES OPERATIONS application hosted in the cloud · Alaska DHHS fined $1.7M ­ Portable device stolen from vehicle · Mass Eye

  4. Portable vapor diffusion coefficient meter

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2007-06-12T23:59:59.000Z

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  5. XSEDE Cloud Survey Report

    E-Print Network [OSTI]

    Walter, M.Todd

    XSEDE Cloud Survey Report David Lifka, Cornell Center for Advanced Computing Ian Foster, ANL, ANL and The University of Chicago A National Science Foundation-sponsored cloud user survey was conducted from September 2012 to April 2013 by the XSEDE Cloud Integration Investigation Team to better

  6. Research Cloud Computing Recommendations

    E-Print Network [OSTI]

    Qian, Ning

    Research Cloud Computing Recommendations SRCPAC December 3, 2014 #12;Mandate and Membership SRCPAC convened this committee in Sept 2014 to investigate the role that cloud computing should play in our & Academic Affairs (Social Work) #12;Questions discussed · What cloud resources are available? · Which kinds

  7. Optimization of multi-pressure himidification-dehumidification desalination using thermal vapor compression and hybridization

    E-Print Network [OSTI]

    Mistry, Karan Hemant

    Humidification-dehumidification (HD or HDH) desalination, and specifically HD driven by a thermal vapor compressor (TVC), is a thermal desalination method that has the potential to produce potable water efficiently in order ...

  8. Vapor deposition of hardened niobium

    DOE Patents [OSTI]

    Blocher, Jr., John M. (Columbus, OH); Veigel, Neil D. (Columbus, OH); Landrigan, Richard B. (Columbus, OH)

    1983-04-19T23:59:59.000Z

    A method of coating ceramic nuclear fuel particles containing a major amount of an actinide ceramic in which the particles are placed in a fluidized bed maintained at ca. 800.degree. to ca. 900.degree. C., and niobium pentachloride vapor and carbon tetrachloride vapor are led into the bed, whereby niobium metal is deposited on the particles and carbon is deposited interstitially within the niobium. Coating apparatus used in the method is also disclosed.

  9. Retrieval of Cloud Phase Using the Moderate Resolution Imaging Spectroradiometer Data during the Mixed-Phase Arctic Cloud Experiment

    SciTech Connect (OSTI)

    Spangenberg, D.; Minnis, P.; Shupe, M.; Uttal, T.; Poellot, M.

    2005-03-18T23:59:59.000Z

    Improving climate model predictions over Earth's polar regions requires a comprehensive knowledge of polar cloud microphysics. Over the Arctic, there is minimal contrast between the clouds and background snow surface, making it difficult to detect clouds and retrieve their phase from space. Snow and ice cover, temperature inversions, and the predominance of mixed-phase clouds make it even more difficult to determine cloud phase. Also, since determining cloud phase is the first step toward analyzing cloud optical depth, particle size, and water content, it is vital that the phase be correct in order to obtain accurate microphysical and bulk properties. Changes in these cloud properties will, in turn, affect the Arctic climate since clouds are expected to play a critical role in the sea ice albedo feedback. In this paper, the IR trispectral technique (IRTST) is used as a starting point for a WV and 11-{micro}m brightness temperature (T11) parameterization (WVT11P) of cloud phase using MODIS data. In addition to its ability to detect mixed-phase clouds, the WVT11P also has the capability to identify thin cirrus clouds overlying mixed or liquid phase clouds (multiphase ice). Results from the Atmospheric Radiation Measurement (ARM) MODIS phase model (AMPHM) are compared to the surface-based cloud phase retrievals over the ARM North Slope of Alaska (NSA) Barrow site and to in-situ data taken from University of North Dakota Citation (CIT) aircraft which flew during the Mixed-Phase Arctic Cloud Experiment (MPACE). It will be shown that the IRTST and WVT11P combined to form the AMPHM can achieve a relative high accuracy of phase discrimination compared to the surface-based retrievals. Since it only uses MODIS WV and IR channels, the AMPHM is robust in the sense that it can be applied to daytime, twilight, and nighttime scenes with no discontinuities in the output phase.

  10. Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

    DOE Patents [OSTI]

    Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

    2014-12-02T23:59:59.000Z

    The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

  11. Evaluation and prevention of explosions in soil vapor extraction systems

    SciTech Connect (OSTI)

    Hower, J.W. [Radian Corp., El Segundo, CA (United States)

    1995-12-31T23:59:59.000Z

    Due to the widespread and long term use of petroleum derived fuels and solvents, many areas have subsurface soils contaminated with petroleum derivatives. This contamination can migrate to groundwater, which is frequently used to supply drinking water needs. A common method of cleaning up that contamination is soil vapor extraction (SVE). SVE is a technique where several extraction wells are installed in the contaminated area, with screens in the appropriate vertical locations. The soil vapors re extracted form the wells using a positive displacement blower. To prevent this subsurface contamination from becoming air pollution, the extracted vapors are then sent to some hydrocarbon removal device, such as a carbon adsorption system or a thermal oxidizer. The data used in this investigation were collected as part of a Radian Corporation project for a client. The site is a former petroleum refinery, and the hydrocarbons are primarily gasoline and diesel.

  12. Long-term impacts of aerosols on vertical development of cloud and precipitation

    SciTech Connect (OSTI)

    Li Z.; Liu Y.; Niu, F.; Fan, J.; Rosenfeld, D.; Ding, Y.

    2011-11-13T23:59:59.000Z

    Aerosols alter cloud density and the radiative balance of the atmosphere. This leads to changes in cloud microphysics and atmospheric stability, which can either suppress or foster the development of clouds and precipitation. The net effect is largely unknown, but depends on meteorological conditions and aerosol properties. Here, we examine the long-term impact of aerosols on the vertical development of clouds and rainfall frequencies, using a 10-year dataset of aerosol, cloud and meteorological variables collected in the Southern Great Plains in the United States. We show that cloud-top height and thickness increase with aerosol concentration measured near the ground in mixed-phase clouds-which contain both liquid water and ice-that have a warm, low base. We attribute the effect, which is most significant in summer, to an aerosol-induced invigoration of upward winds. In contrast, we find no change in cloud-top height and precipitation with aerosol concentration in clouds with no ice or cool bases. We further show that precipitation frequency and rain rate are altered by aerosols. Rain increases with aerosol concentration in deep clouds that have a high liquid-water content, but declines in clouds that have a low liquid-water content. Simulations using a cloud-resolving model confirm these observations. Our findings provide unprecedented insights of the long-term net impacts of aerosols on clouds and precipitation.

  13. Cloud tomography: Role of constraints and a new algorithm Dong Huang,1

    E-Print Network [OSTI]

    Cloud tomography: Role of constraints and a new algorithm Dong Huang,1 Yangang Liu,1 and Warren 2008. [1] Retrieving spatial distributions of cloud liquid water content from limited-angle emission data (passive microwave cloud tomography) is ill-posed, and a small inaccuracy in the data and

  14. Aerosol Effects on Cloud Emissivity and Surface Longwave Heating in the Arctic TIMOTHY J. GARRETT1,*

    E-Print Network [OSTI]

    ) studies show that in the Arctic cloud cover generally acts to warm the surface, while coolingAerosol Effects on Cloud Emissivity and Surface Longwave Heating in the Arctic TIMOTHY J. GARRETT1 in the atmosphere tend to increase the reflectance of solar (shortwave) radiation from water clouds, which can lead

  15. Quantifying uncertainties of cloud microphysical property retrievals with a perturbation method

    E-Print Network [OSTI]

    Ohta, Shigemi

    to their modification effects on global radiation balance and atmospheric water cycle. However, representation of clouds Radiation Measurement (ARM) facility, whose primary goal is to carry out long-term observations of cloudsQuantifying uncertainties of cloud microphysical property retrievals with a perturbation method

  16. Working inside the Cloud: Developing a Cloud Computing Infrastructure

    E-Print Network [OSTI]

    Krause, Rolf

    UROP 2012 Working inside the Cloud: Developing a Cloud Computing Infrastructure Cloud computing and live-migration of running VM. USI participates to the development of the first European Cloud computing for a motivated student that will have a chance to improve his/her knowledge on Cloud computing, Java and/or Ruby

  17. Dynamic Cloud Resource Reservation via Cloud Brokerage

    E-Print Network [OSTI]

    Li, Baochun

    Department of Electrical and Computer Engineering, University of Toronto Department of Electrical@eecg.toronto.edu, liang@utoronto.ca Abstract--Infrastructure-as-a-Service clouds offer diverse pric- ing options

  18. Scanning ARM Cloud Radars Part II: Data Quality Control and Processing

    SciTech Connect (OSTI)

    Kollias, Pavlos; Jo, Ieng; Borque, Paloma; Tatarevic, Aleksandra; Lamer, Katia; Bharadwaj, Nitin; Widener, Kevin B.; Johnson, Karen; Clothiaux, Eugene E.

    2014-03-01T23:59:59.000Z

    The Scanning ARM Cloud Radars (SACR’s) are the primary instruments for documenting the four-dimensional structure and evolution of clouds within a 20-30 km radius from the ARM fixed and mobile sites. Here, the post-processing of the calibrated SACR measurements is discussed. First, a feature mask algorithm that objectively determines the presence of significant radar returns is described. The feature mask algorithm is based on the statistical properties of radar receiver noise. It accounts for atmospheric emission and is applicable even for SACR profiles with few or no signal-free range gates. Using the nearest-in-time atmospheric sounding, the SACR radar reflectivities are corrected for gaseous attenuation (water vapor and oxygen) using a line-by-line absorption model. Despite having a high pulse repetition frequency, the SACR has a narrow Nyquist velocity limit and thus Doppler velocity folding is commonly observed. An unfolding algorithm that makes use of a first guess for the true Doppler velocity using horizontal wind measurements from the nearest sounding is described. The retrieval of the horizontal wind profile from the Hemispherical Sky – Range Height Indicator SACR scan observations and/or nearest sounding is described. The retrieved horizontal wind profile can be used to adaptively configure SACR scan strategies that depend on wind direction. Several remaining challenges are discussed, including the removal of insect and second-trip echoes. The described algorithms significantly enhance SACR data quality and constitute an important step towards the utilization of SACR measurements for cloud research.

  19. Beam Measurements of a CLOUD (Cosmics Leaving OUtdoor Droplets) Chamber

    E-Print Network [OSTI]

    Kirkby, Jasper

    2001-01-01T23:59:59.000Z

    A striking correlation has recently been observed between global cloud cover and the flux of incident cosmic rays. The effect of natural variations in the cosmic ray flux is large, causing estimated changes in the Earth's energy radiation balance that are comparable to those attributed to greenhouse gases from the burning of fossil fuels since the Industrial Revolution. However a direct link between cosmic rays and cloud formation has not been unambiguously established. We therefore propose to experimentally measure cloud (water droplet) formation under controlled conditions in a test beam at CERN with a CLOUD chamber, duplicating the conditions prevailing in the troposphere. These data, which have never been previously obtained, will allow a detailed understanding of the possible effects of cosmic rays on clouds and confirm, or otherwise, a direct link between cosmic rays, global cloud cover and the Earth's climate. The measurements will, in turn, allow more reliable calculations to be made of the residual e...

  20. An Autonomous Reliabilit Cloud Comput

    E-Print Network [OSTI]

    Buyya, Rajkumar

    An Autonomous Reliabilit Ami Cloud Comput Department of Computing and Informa Abstract--Cloud computing paradigm allo based access to computing and storages s Internet. Since with advances of Cloud. Keywords- Cloud computing; SLA negotiat I. INTRODUCTION Cloud computing has transferred the services

  1. Shipboard measurements of the cloud-capped marine boundary layer during FIRE/ASTEX

    SciTech Connect (OSTI)

    NONE

    1997-09-01T23:59:59.000Z

    Results are reported on measurements of the cloud-capped marine boundary layer during FIRE/ASTEX. A method was developed from the ASTEX dataset for measuring profiles of liquid water content, droplet size and concentration from cloud radar/microwave radiometer data in marine boundary layer clouds. Profiles were also determined from the first three moments of the Doppler spectrum measured in drizzle with the ETL cloud radar during ASTEX.

  2. Image Storage in Hot Vapors

    E-Print Network [OSTI]

    L. Zhao; T. Wang; Y. Xiao; S. F. Yelin

    2007-10-22T23:59:59.000Z

    We theoretically investigate image propagation and storage in hot atomic vapor. A $4f$ system is adopted for imaging and an atomic vapor cell is placed over the transform plane. The Fraunhofer diffraction pattern of an object in the object plane can thus be transformed into atomic Raman coherence according to the idea of ``light storage''. We investigate how the stored diffraction pattern evolves under diffusion. Our result indicates, under appropriate conditions, that an image can be reconstructed with high fidelity. The main reason for this procedure to work is the fact that diffusion of opposite-phase components of the diffraction pattern interfere destructively.

  3. Vapor deposition of thin films

    DOE Patents [OSTI]

    Smith, David C. (Los Alamos, NM); Pattillo, Stevan G. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Sattelberger, Alfred P. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl).sub.3, iridium(allyl).sub.3, molybdenum(allyl).sub.4, tungsten(allyl).sub.4, rhenium(allyl).sub.4, platinum(allyl).sub.2, or palladium(allyl).sub.2 are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  4. Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud

    SciTech Connect (OSTI)

    Klein, S A; McCoy, R B; Morrison, H; Ackerman, A; Avramov, A; deBoer, G; Chen, M; Cole, J; DelGenio, A; Golaz, J; Hashino, T; Harrington, J; Hoose, C; Khairoutdinov, M; Larson, V; Liu, X; Luo, Y; McFarquhar, G; Menon, S; Neggers, R; Park, S; Poellot, M; von Salzen, K; Schmidt, J; Sednev, I; Shipway, B; Shupe, M; Spangenberg, D; Sud, Y; Turner, D; Veron, D; Falk, M; Foster, M; Fridlind, A; Walker, G; Wang, Z; Wolf, A; Xie, S; Xu, K; Yang, F; Zhang, G

    2008-02-27T23:59:59.000Z

    Results are presented from an intercomparison of single-column and cloud-resolving model simulations of a cold-air outbreak mixed-phase stratocumulus cloud observed during the Atmospheric Radiation Measurement (ARM) program's Mixed-Phase Arctic Cloud Experiment. The observed cloud occurred in a well-mixed boundary layer with a cloud top temperature of -15 C. The observed liquid water path of around 160 g m{sup -2} was about two-thirds of the adiabatic value and much greater than the mass of ice crystal precipitation which when integrated from the surface to cloud top was around 15 g m{sup -2}. The simulations were performed by seventeen single-column models (SCMs) and nine cloud-resolving models (CRMs). While the simulated ice water path is generally consistent with the observed values, the median SCM and CRM liquid water path is a factor of three smaller than observed. Results from a sensitivity study in which models removed ice microphysics indicate that in many models the interaction between liquid and ice-phase microphysics is responsible for the large model underestimate of liquid water path. Despite this general underestimate, the simulated liquid and ice water paths of several models are consistent with the observed values. Furthermore, there is some evidence that models with more sophisticated microphysics simulate liquid and ice water paths that are in better agreement with the observed values, although considerable scatter is also present. Although no single factor guarantees a good simulation, these results emphasize the need for improvement in the model representation of mixed-phase microphysics. This case study, which has been well observed from both aircraft and ground-based remote sensors, could be a benchmark for model simulations of mixed-phase clouds.

  5. Clouds up close | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interactions that affect clouds and thus improve climate projections. Contact Heng Xiao Pacific Northwest National Laboratory 902 Battelle Blvd., PO Box 999 MSIN: K9-30...

  6. Finance Idol Word Cloud

    Broader source: Energy.gov [DOE]

    This word cloud represents the topics discussed during the Big and Small Ideas: How to Lower Solar Financing Costs breakout session at the SunShot Grand Challenge.

  7. SURFACE CLOUD RADIATIVE FORCING, CLOUD FRACTION AND CLOUD ALBEDO: THEIR RELATIONSHIP AND MULTISCALE VARIATION

    E-Print Network [OSTI]

    that have been used to quantify the effect of clouds on radiation budget in both modeling and observationalSURFACE CLOUD RADIATIVE FORCING, CLOUD FRACTION AND CLOUD ALBEDO: THEIR RELATIONSHIP AND MULTISCALE/Atmospheric Sciences Division Brookhaven National Laboratory P.O. Box, Upton, NY www.bnl.gov ABSTRACT Cloud-radiation

  8. Regional terrestrial water storage change and evapotranspiration from terrestrial and atmospheric water balance computations

    E-Print Network [OSTI]

    Yeh, Pat J.-F.; Famiglietti, J. S

    2008-01-01T23:59:59.000Z

    is derived as the residual of precipitation and water vaporThe largest mean water budget residual calculated from theresidual between the two large terms in the combined water

  9. High-expansion foam for LNG vapor mitigation. Topical report, September 1987-December 1989

    SciTech Connect (OSTI)

    Atallah, S.; Shah, J.N.; Peterlinz, M.E.

    1990-05-01T23:59:59.000Z

    One of the purposes of these high expansion foam systems is to reduce the extent of the hazardous vapor cloud generated during an accidental LNG release. Should the LNG ignite, these systems serve the additional function of controlling the LNG fire and minimizing its radiation to the surroundings. Foam generators have been installed along the tops of dike walls surrounding some LNG storage tanks, and around other fenced containment areas where LNG may be accidentally released, such as LNG pump pits and pipe rack trenches. To date there are no technically justifiable guidelines for the design and installation of these systems. Furthermore, there are no models that may be used describe the vapor source so as to be able to predict the reduction in the hazardous vapor cloud zone when high expansion foam is applied to an LNG spill. Information is essential not only for the optimal design of high expansion foam systems, but also for comparing the cost effectiveness of alternative LNG vapor mitigation measures.

  10. Vacuum vapor deposition gun assembly

    DOE Patents [OSTI]

    Zeren, Joseph D. (Boulder, CO)

    1985-01-01T23:59:59.000Z

    A vapor deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, a hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

  11. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  12. Sandia Energy - Cloud Computing Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Computing Services Home Stationary Power Safety, Security & Resilience of Energy Infrastructure Grid Modernization Cyber Security for Electric Infrastructure Cloud Computing...

  13. Profiling clouds' inner life | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    life Released: May 29, 2014 Subgrid modeling pinpoints cloud transformation to uncover true reflective power An accurate understanding of clouds over the ocean is important for...

  14. CONTRIBUTED Green Cloud Computing

    E-Print Network [OSTI]

    Tucker, Rod

    to manage energy consumption across the entire information and communications technology (ICT) sector. While considers both public and private clouds, and includes energy consumption in switching and transmission to energy consumption and cloud computing seems to be an alternative to office-based computing. By Jayant

  15. Toward Securing Sensor Clouds

    E-Print Network [OSTI]

    · 32 GB microSDHC storage 2 Image from http://hothardware.com/News/Leaked-Motorola-DROID-X-2-Daytona Computer Mini Computer External Storage External Storage Router Router Router Router Cloud Computing Cloud: micro surveys, amber alerts 4 #12;Router Router Router Router Mini Computer Mini Computer Mini Computer

  16. July 2012July 2012 Cloud Computing and Virtualization:Cloud Computing and Virtualization

    E-Print Network [OSTI]

    Liu, Jiangchuan (JC)

    July 2012July 2012 Cloud Computing and Virtualization:Cloud Computing and Virtualization/26/2633 Recent: CloudRecent: Cloud The fast growth of cloud computing Cloud file storage/synchronization services Google entries about cloud computing: 184,000,000 #12;July 2012July 2012 44/26/2644 Our CloudOur Cloud 7

  17. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30T23:59:59.000Z

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  18. Cloud Properties and Radiative Heating Rates for TWP

    SciTech Connect (OSTI)

    Comstock, Jennifer

    2013-11-07T23:59:59.000Z

    A cloud properties and radiative heating rates dataset is presented where cloud properties retrieved using lidar and radar observations are input into a radiative transfer model to compute radiative fluxes and heating rates at three ARM sites located in the Tropical Western Pacific (TWP) region. The cloud properties retrieval is a conditional retrieval that applies various retrieval techniques depending on the available data, that is if lidar, radar or both instruments detect cloud. This Combined Remote Sensor Retrieval Algorithm (CombRet) produces vertical profiles of liquid or ice water content (LWC or IWC), droplet effective radius (re), ice crystal generalized effective size (Dge), cloud phase, and cloud boundaries. The algorithm was compared with 3 other independent algorithms to help estimate the uncertainty in the cloud properties, fluxes, and heating rates (Comstock et al. 2013). The dataset is provided at 2 min temporal and 90 m vertical resolution. The current dataset is applied to time periods when the MMCR (Millimeter Cloud Radar) version of the ARSCL (Active Remotely-Sensed Cloud Locations) Value Added Product (VAP) is available. The MERGESONDE VAP is utilized where temperature and humidity profiles are required. Future additions to this dataset will utilize the new KAZR instrument and its associated VAPs.

  19. Cloud Properties and Radiative Heating Rates for TWP

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Comstock, Jennifer

    A cloud properties and radiative heating rates dataset is presented where cloud properties retrieved using lidar and radar observations are input into a radiative transfer model to compute radiative fluxes and heating rates at three ARM sites located in the Tropical Western Pacific (TWP) region. The cloud properties retrieval is a conditional retrieval that applies various retrieval techniques depending on the available data, that is if lidar, radar or both instruments detect cloud. This Combined Remote Sensor Retrieval Algorithm (CombRet) produces vertical profiles of liquid or ice water content (LWC or IWC), droplet effective radius (re), ice crystal generalized effective size (Dge), cloud phase, and cloud boundaries. The algorithm was compared with 3 other independent algorithms to help estimate the uncertainty in the cloud properties, fluxes, and heating rates (Comstock et al. 2013). The dataset is provided at 2 min temporal and 90 m vertical resolution. The current dataset is applied to time periods when the MMCR (Millimeter Cloud Radar) version of the ARSCL (Active Remotely-Sensed Cloud Locations) Value Added Product (VAP) is available. The MERGESONDE VAP is utilized where temperature and humidity profiles are required. Future additions to this dataset will utilize the new KAZR instrument and its associated VAPs.

  20. Vapor canister heater for evaporative emissions systems

    SciTech Connect (OSTI)

    Bishop, R.P.; Berg, P.G.

    1987-01-01T23:59:59.000Z

    Automotive evaporative emissions systems use a charcoal canister to store evaporative hydrocarobn emissions. These stored vapors are later purged and burned during engine operation. Under certain conditions the engine cannot completely purge the canister of the stored fuel vapors, which results in a decreased vapor storage capacity in the canister. A self-regulating PTC (Positive Temperature Coefficient) heater has been developed to warm the purge air as it enters the canister, in order to provide thermal energy for increased release of the vapors from charcoal sites. This paper describes the construction and operation of the vapor canister heater as it relates to improved evaporative emission system performance.

  1. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, L.D.; Cerni, T.A.

    1989-10-17T23:59:59.000Z

    Apparatus and method are disclosed which determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavelength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to an equation given in the patent where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4) + K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation. 11 figs.

  2. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, Loren D. (Morrison, CO); Cerni, Todd A. (Littleton, CO)

    1989-01-01T23:59:59.000Z

    Apparatus and method determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavlength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to: ##EQU1## where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4)+K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation.

  3. When Clouds become Green: the Green Open Cloud Architecture

    E-Print Network [OSTI]

    Boyer, Edmond

    of a new original energy-efficient Cloud infrastructure called Green Open Cloud. Keywords. Energy with the support of energy-efficient frameworks dedicated to Cloud architectures. Virtualization is a key feature of the energy-aware Cloud infras- tructure that we propose. The conclusion and future works are reviewed

  4. Means and method for vapor generation

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1984-01-01T23:59:59.000Z

    A liquid, in heat transfer contact with a surface heated to a temperature well above the vaporization temperature of the liquid, will undergo a multiphase (liquid-vapor) transformation from 0% vapor to 100% vapor. During this transition, the temperature driving force or heat flux and the coefficients of heat transfer across the fluid-solid interface, and the vapor percentage influence the type of heating of the fluid--starting as "feedwater" heating where no vapors are present, progressing to "nucleate" heating where vaporization begins and some vapors are present, and concluding with "film" heating where only vapors are present. Unstable heating between nucleate and film heating can occur, accompanied by possibly large and rapid temperature shifts in the structures. This invention provides for injecting into the region of potential unstable heating and proximate the heated surface superheated vapors in sufficient quantities operable to rapidly increase the vapor percentage of the multiphase mixture by perhaps 10-30% and thereby effectively shift the multiphase mixture beyond the unstable heating region and up to the stable film heating region.

  5. Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud

    SciTech Connect (OSTI)

    Klein, Stephen A.; McCoy, Renata B.; Morrison, Hugh; Ackerman, Andrew S.; Avramov, Alexander; de Boer, Gijs; Chen, Mingxuan; Cole, Jason N.S.; Del Genio, Anthony D.; Falk, Michael; Foster, Michael J.; Fridlind, Ann; Golaz, Jean-Christophe; Hashino, Tempei; Harrington, Jerry Y.; Hoose, Corinna; Khairoutdinov, Marat F.; Larson, Vincent E.; Liu, Xiaohong; Luo, Yali; McFarquhar, Greg M.; Menon, Surabi; Neggers, Roel A. J.; Park, Sungsu; Poellot, Michael R.; Schmidt, Jerome M.; Sednev, Igor; Shipway, Ben J.; Shupe, Matthew D.; Spangenberg, Douglas A.; Sud, Yogesh C.; Turner, David D.; Veron, Dana E.; von Salzen, Knut; Walker, Gregory K.; Wang, Zhien; Wolf, Audrey B.; Xie, Shaocheng; Xu, Kuan-Man; Yang, Fanglin; Zhang, Gong

    2009-02-02T23:59:59.000Z

    Results are presented from an intercomparison of single-column and cloud-resolving model simulations of a cold-air outbreak mixed-phase stratocumulus cloud observed during the Atmospheric Radiation Measurement (ARM) program's Mixed-Phase Arctic Cloud Experiment. The observed cloud occurred in a well-mixed boundary layer with a cloud top temperature of -15 C. The observed average liquid water path of around 160 g m{sup -2} was about two-thirds of the adiabatic value and much greater than the average mass of ice crystal precipitation which when integrated from the surface to cloud top was around 15 g m{sup -2}. The simulations were performed by seventeen single-column models (SCMs) and nine cloud-resolving models (CRMs). While the simulated ice water path is generally consistent with the observed values, the median SCM and CRM liquid water path is a factor of three smaller than observed. Results from a sensitivity study in which models removed ice microphysics suggest that in many models the interaction between liquid and ice-phase microphysics is responsible for the large model underestimate of liquid water path. Despite this general underestimate, the simulated liquid and ice water paths of several models are consistent with the observed values. Furthermore, there is evidence that models with more sophisticated microphysics simulate liquid and ice water paths that are in better agreement with the observed values, although considerable scatter is also present. Although no single factor guarantees a good simulation, these results emphasize the need for improvement in the model representation of mixed-phase microphysics.

  6. MEMS Lubrication by In-Situ Tribochemical Reactions From the Vapor Phase.

    SciTech Connect (OSTI)

    Dugger, Michael T.; Asay, David B.; Kim, Seong H.

    2008-01-01T23:59:59.000Z

    Vapor Phase Lubrication (VPL) of silicon surfaces with pentanol has been demonstrated. Two potential show stoppers with respect to application of this approach to real MEMS devices have been investigated. Water vapor was found to reduce the effectiveness of VPL with alcohol for a given alcohol concentration, but the basic reaction mechanism observed in water-free environments is still active, and devices operated much longer in mixed alcohol and water vapor environments than with chemisorbed monolayer lubricants alone. Complex MEMS gear trains were successfully lubricated with alcohol vapors, resulting in a factor of 104 improvement in operating life without failure. Complex devices could be made to fail if operated at much higher frequencies than previously used, and there is some evidence that the observed failure is due to accumulation of reaction products at deeply buried interfaces. However, if hypothetical reaction mechanisms involving heated surfaces are valid, then the failures observed at high frequency may not be relevant to operation at normal frequencies. Therefore, this work demonstrates that VPL is a viable approach for complex MEMS devices in conventional packages. Further study of the VPL reaction mechanisms are recommended so that the vapor composition may be optimized for low friction and for different substrate materials with potential application to conventionally fabricated, metal alloy parts in weapons systems. Reaction kinetics should be studied to define effective lubrication regimes as a function of the partial pressure of the vapor phase constituent, interfacial shear rate, substrate composition, and temperature.

  7. Attribution Analysis of Cloud Feedback

    E-Print Network [OSTI]

    Zhou, Chen

    2014-07-15T23:59:59.000Z

    -term global warming. If the EIS-low cloud fraction relationship holds under global warming, it is likely that the tropical low cloud fraction change is non-negative. Climate models without significant negative low cloud fraction change suggest that the cloud...

  8. Convective Cloud Lifecycles Lunchtime seminar

    E-Print Network [OSTI]

    Plant, Robert

    Convective Cloud Lifecycles Lunchtime seminar 19th May 2009 Bob Plant Department of Meteorology, University of Reading, UK #12;Introduction Obtain life cycle statistics for clouds in CRM simulations Why Conclusions Convective Cloud Lifecycles ­ p.1/3 #12;Why bother? Convective Cloud Lifecycles ­ p.2/3 #12;Some

  9. Testing cloud microphysics parameterizations in NCAR CAM5 with ISDAC and M-PACE observations

    SciTech Connect (OSTI)

    Liu X.; Lin W.; Xie, S.; Boyle, J.; Klein, S. A.; Shi, X.; Wang, Z.; Ghan, S. J.; Earle, M.; Liu, P. S. K.; Zelenyuk, A.

    2011-12-24T23:59:59.000Z

    Arctic clouds simulated by the National Center for Atmospheric Research (NCAR) Community Atmospheric Model version 5 (CAM5) are evaluated with observations from the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Indirect and Semi-Direct Aerosol Campaign (ISDAC) and Mixed-Phase Arctic Cloud Experiment (M-PACE), which were conducted at its North Slope of Alaska site in April 2008 and October 2004, respectively. Model forecasts for the Arctic spring and fall seasons performed under the Cloud-Associated Parameterizations Testbed framework generally reproduce the spatial distributions of cloud fraction for single-layer boundary-layer mixed-phase stratocumulus and multilayer or deep frontal clouds. However, for low-level stratocumulus, the model significantly underestimates the observed cloud liquid water content in both seasons. As a result, CAM5 significantly underestimates the surface downward longwave radiative fluxes by 20-40 W m{sup -2}. Introducing a new ice nucleation parameterization slightly improves the model performance for low-level mixed-phase clouds by increasing cloud liquid water content through the reduction of the conversion rate from cloud liquid to ice by the Wegener-Bergeron-Findeisen process. The CAM5 single-column model testing shows that changing the instantaneous freezing temperature of rain to form snow from -5 C to -40 C causes a large increase in modeled cloud liquid water content through the slowing down of cloud liquid and rain-related processes (e.g., autoconversion of cloud liquid to rain). The underestimation of aerosol concentrations in CAM5 in the Arctic also plays an important role in the low bias of cloud liquid water in the single-layer mixed-phase clouds. In addition, numerical issues related to the coupling of model physics and time stepping in CAM5 are responsible for the model biases and will be explored in future studies.

  10. Process-model Simulations of Cloud Albedo Enhancement by Aerosols in the Arctic

    SciTech Connect (OSTI)

    Kravitz, Benjamin S.; Wang, Hailong; Rasch, Philip J.; Morrison, H.; Solomon, Amy

    2014-11-17T23:59:59.000Z

    A cloud-resolving model is used to simulate the effectiveness of Arctic marine cloud brightening via injection of cloud condensation nuclei (CCN). An updated cloud microphysical scheme is employed, with prognostic CCN and cloud particle numbers in both liquid and mixed-phase marine low clouds. Injection of CCN into the marine boundary layer can delay the collapse of the boundary layer and increase low-cloud albedo. Because nearly all of the albedo effects are in the liquid phase due to the removal of ice water by snowfall when ice processes are involved, albedo increases are stronger for pure liquid clouds than mixed-phase clouds. Liquid precipitation can be suppressed by CCN injection, whereas ice precipitation (snow) is affected less; thus the effectiveness of brightening mixed-phase clouds is lower than for liquid-only clouds. CCN injection into a clean regime results in a greater albedo increase than injection into a polluted regime, consistent with current knowledge about aerosol-cloud interactions. Unlike previous studies investigating warm clouds, dynamical changes in circulation due to precipitation changes are small.

  11. Vapor explosion in the RIA-ST-4 experiment. [BWR

    SciTech Connect (OSTI)

    El-Genk, M.S.

    1980-01-01T23:59:59.000Z

    A concern in assuring the safety of commercial light water reactors (LWRs) is whether core overheating, during which molten fuel is produced, can lead to massive vaporization of the coolant and shock pressurization of the system due to an energetic molten fuel-coolant interaction (MFCI). The RIA-ST-4 experiment was one of four scoping tests in the Reactivity Initiated Accident (RIA) Test Series which is being conducted in the Power Burst Facility (PBF) to define an energy deposition failure threshold and to determine modes and consequences of fuel rod failure during a postulated boiling water reactor (BWR) control rod drop accident.

  12. Three-dimensional computer simulations of bioremediation and vapor extraction

    SciTech Connect (OSTI)

    Travis, B.; Trent, B.

    1991-01-01T23:59:59.000Z

    Numerical simulations of two remediation strategies are presented. These calculations are significant in they they will play a major role in the actual field implementation of two very different techniques. The first set of calculations simulates the actual spill event of nearly 60,000 gallons of No. 2 diesel fuel oil and its subsequent flow toward the water table for 13 years. Hydrogen peroxide saturated water flooding is then performed and the bioremediation of the organic material is then calculated. The second set of calculations describes the vacuum extraction of organic vapors and indicates the sensitivity to various assumed formation properties and boundary conditions. 7 refs., 5 figs.

  13. Fresh clouds: A parameterized updraft method for calculating cloud densities in one-dimensional models

    E-Print Network [OSTI]

    Atreya, Sushil

    . Mihalka a a Department of Atmospheric, Oceanic, and Space Science, University of Michigan, Ann Arbor, MI 48109-2143, USA b Astronomy Department, University of California, Berkeley, CA 97420-3411, USA c NASA clouds com- posed of ammonia ice, ammonium hydrosulfide or other com- pounds formed by NH3 and H2S, water

  14. Interannual Variations of Arctic Cloud Types

    E-Print Network [OSTI]

    Hochberg, Michael

    Sciences #12;Changes in Arctic Climate What is the role of cloud cover in Arctic climate change? What is the Cloud Radiative Effect (CRE) in the Arctic? #12;CRE depends on season, cloud type CRE ­ whether clouds specifically chosen to include nighttime obs Total cloud cover and nine cloud types: - High cloud (cirriform

  15. Interannual Variations of Arctic Cloud Types

    E-Print Network [OSTI]

    Hochberg, Michael

    Declining September sea-ice extent #12;Clouds & Changes in Arctic Climate What is the role of cloud cover in Arctic climate change? What is the Cloud Radiative Effect (CRE) in the Arctic? #12;CRE Defined CRE nighttime obs Total cloud cover and nine cloud types: - High cloud (cirriform) - Middle Clouds: Altocumulus

  16. Influence of clouds and diffuse radiation on ecosystem-atmosphere CO 2 and CO 18 O exchanges

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    cover, radiation, meteorological and water isotope data tohere, radiation, cloud property, and aerosol data wereData were obtained from the Atmospheric Radiation

  17. First observations of tracking clouds using scanning ARM cloud radars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Borque, Paloma; Giangrande, Scott; Kollias, Pavlos

    2014-12-01T23:59:59.000Z

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (‘‘first echo’’). These measurements complement cloud and precipitation tracking using geostationary satellites and weather radars. Here, two-dimensional (2-D) Along-Wind Range Height Indicator (AW-RHI) observations of a population of shallow cumuli (with and without precipitation) from the 35-GHz scanning ARM cloud radar (SACR) at the DOE Atmospheric Radiation Measurements (ARM) program Southern Great Plains (SGP) site are presented. Observations from the ARM SGP network of scanning precipitation radars are used to provide the larger scale context of the cloud fieldmore »and to highlight the advantages of the SACR to detect the numerous, small, non-precipitating cloud elements. A new Cloud Identification and Tracking Algorithm (CITA) is developed to track cloud elements. In CITA, a cloud element is identified as a region having a contiguous set of pixels exceeding a preset reflectivity and size threshold. The high temporal resolution of the SACR 2-D observations (30 sec) allows for an area superposition criteria algorithm to match cloud elements at consecutive times. Following CITA, the temporal evolution of cloud element properties (number, size, and maximum reflectivity) is presented. The vast majority of the designated elements during this cumulus event were short-lived non-precipitating clouds having an apparent life cycle shorter than 15 minutes. The advantages and disadvantages of cloud tracking using an SACR are discussed.« less

  18. First observations of tracking clouds using scanning ARM cloud radars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Borque, Paloma [McGill Univ., Montreal, QC (Canada); Giangrande, Scott [Brookhaven National Lab. (BNL), Upton, NY (United States); Kollias, Pavlos [McGill Univ., Montreal, QC (Canada)

    2014-12-01T23:59:59.000Z

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (‘‘first echo’’). These measurements complement cloud and precipitation tracking using geostationary satellites and weather radars. Here, two-dimensional (2-D) Along-Wind Range Height Indicator (AW-RHI) observations of a population of shallow cumuli (with and without precipitation) from the 35-GHz scanning ARM cloud radar (SACR) at the DOE Atmospheric Radiation Measurements (ARM) program Southern Great Plains (SGP) site are presented. Observations from the ARM SGP network of scanning precipitation radars are used to provide the larger scale context of the cloud field and to highlight the advantages of the SACR to detect the numerous, small, non-precipitating cloud elements. A new Cloud Identification and Tracking Algorithm (CITA) is developed to track cloud elements. In CITA, a cloud element is identified as a region having a contiguous set of pixels exceeding a preset reflectivity and size threshold. The high temporal resolution of the SACR 2-D observations (30 sec) allows for an area superposition criteria algorithm to match cloud elements at consecutive times. Following CITA, the temporal evolution of cloud element properties (number, size, and maximum reflectivity) is presented. The vast majority of the designated elements during this cumulus event were short-lived non-precipitating clouds having an apparent life cycle shorter than 15 minutes. The advantages and disadvantages of cloud tracking using an SACR are discussed.

  19. Assessment of radionuclide vapor-phase transport in unsaturated tuff

    SciTech Connect (OSTI)

    Smith, D.M.; Updegraff, C.D.; Bonano, E.J.; Randall, J.D.

    1986-11-01T23:59:59.000Z

    This report describes bounding calculations performed to investigate the possibility of radionuclide migration in a vapor phase associated with the emplacement of high-level waste canister in unsaturated tuff formations. Two potential radionuclide transport mechanisms in the vapor phase were examined: aerosol migration and convection/diffusion of volatile species. The former may have significant impact on the release of radionuclides to the accessible environment as the concentration in the aerosols will be equal to that in the ground water. A conservative analysis of air diffusion in a stagnant liquid film indicated that for all expected repository conditions, aerosol formation is not possible. The migration of volatile species was examined both in the vicinity of a waste canister and outside the thermally disturbed zone. Two-dimensional (radial) and three-dimensional (radial-vertical) coupled heat transfer-gas flow-liquid flow simulations were performed using the TOUGH computer code. The gas flow rate relative to the liquid flow rate predicted from the simulations allowed calculations of mobility ratios due to convection which led to the conclusion that, except for the immediate region near the canister, transport in the liquid phase will be dominant for radionuclides heavier than radon. Near the waste canister, iodine transport may also be important in the vapor phase. Bounding calculations for vertical mobility ratios were carried out as a function of saturation. These calculations are conservative and agree well with the two-dimensional simulations. Based on this analysis, it is clear that vapor-phase transport will not be important for radionuclides such as cesium and heavier species. Vapor transport for iodine may play a role in the overall release scenario depending on the particular repository conditions.

  20. Migrating enterprise storage applications to the cloud

    E-Print Network [OSTI]

    Vrable, Michael Daniel

    2011-01-01T23:59:59.000Z

    2.1 Cloud Providers . . . . . . . . . . . .2.1.1 Cloud Storage . . . . . . . . .2.1.2 Cloud Computation . . . . . . 2.2 Enterprise Storage

  1. A developer's survey on different cloud platforms

    E-Print Network [OSTI]

    Doan, Dzung

    2009-01-01T23:59:59.000Z

    1 Introduction Cloud computing is a computing paradigm inFor this reason, cloud computing has also been describedparallel processing. Cloud computing can be contrasted with

  2. AEROSOL, CLOUDS, AND CLIMATE CHANGE

    SciTech Connect (OSTI)

    SCHWARTZ, S.E.

    2005-09-01T23:59:59.000Z

    Earth's climate is thought to be quite sensitive to changes in radiative fluxes that are quite small in absolute magnitude, a few watts per square meter, and in relation to these fluxes in the natural climate. Atmospheric aerosol particles exert influence on climate directly, by scattering and absorbing radiation, and indirectly by modifying the microphysical properties of clouds and in turn their radiative effects and hydrology. The forcing of climate change by these indirect effects is thought to be quite substantial relative to forcing by incremental concentrations of greenhouse gases, but highly uncertain. Quantification of aerosol indirect forcing by satellite- or ground-based remote sensing has proved quite difficult in view of inherent large variation in the pertinent observables such as cloud optical depth, which is controlled mainly by liquid water path and only secondarily by aerosols. Limited work has shown instances of large magnitude of aerosol indirect forcing, with local instantaneous forcing upwards of 50 W m{sup 66}-2. Ultimately it will be necessary to represent aerosol indirect effects in climate models to accurately identify the anthropogenic forcing at present and over secular time and to assess the influence of this forcing in the context of other forcings of climate change. While the elements of aerosol processes that must be represented in models describing the evolution and properties of aerosol particles that serve as cloud condensation particles are known, many important components of these processes remain to be understood and to be represented in models, and the models evaluated against observation, before such model-based representations can confidently be used to represent aerosol indirect effects in climate models.

  3. Information content and reliability of TOVS estimates of precipitable water

    E-Print Network [OSTI]

    Yin, Min

    1994-01-01T23:59:59.000Z

    of water vapor in the atmosphere has been accomplished by satellite sensors in both the infrared (IR) and microwave spectral regions. The radiance will be high if either the atmospheric temperature is high or the water vapor content is low. Among... hours apart. On board each satellite are channels of High Resolution Infrared Radiation Sounder (HIRS2), Microwave Sounding Unit (MSU) and Stratospheric Sounding Unit (SSU). Two infrared channels are essentially sensitive to water vapor. PW derived...

  4. Control of flow through a vapor generator

    DOE Patents [OSTI]

    Radcliff, Thomas D.

    2005-11-08T23:59:59.000Z

    In a Rankine cycle system wherein a vapor generator receives heat from exhaust gases, provision is made to avoid overheating of the refrigerant during ORC system shut down while at the same time preventing condensation of those gases within the vapor generator when its temperature drops below a threshold temperature by diverting the flow of hot gases to ambient and to thereby draw ambient air through the vapor generator in the process. In one embodiment, a bistable ejector is adjustable between one position, in which the hot gases flow through the vapor generator, to another position wherein the gases are diverted away from the vapor generator. Another embodiment provides for a fixed valve ejector with a bias towards discharging to ambient, but with a fan on the downstream side of said vapor generator for overcoming this bias.

  5. Testing Cloud Microphysics Parameterizations in NCAR CAM5 with ISDAC and M-PACE Observations

    SciTech Connect (OSTI)

    Liu, Xiaohong; Xie, Shaocheng; Boyle, James; Klein, Stephen A.; Shi, Xiangjun; Wang, Zhien; Lin, Wuyin; Ghan, Steven J.; Earle, Michael; Liu, Peter; Zelenyuk, Alla

    2011-12-24T23:59:59.000Z

    Arctic clouds simulated by the NCAR Community Atmospheric Model version 5 (CAM5) are evaluated with observations from the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Indirect and Semi-Direct Aerosol Campaign (ISDAC) and Mixed-Phase Arctic Cloud Experiment (M-PACE), which were conducted at its North Slope of Alaska site in April 2008 and October 2004, respectively. Model forecasts for the Arctic Spring and Fall seasons performed under the Cloud- Associated Parameterizations Testbed (CAPT) framework generally reproduce the spatial distributions of cloud fraction for single-layer boundary layer mixed-phase stratocumulus, and multilayer or deep frontal clouds. However, for low-level clouds, the model significantly underestimates the observed cloud liquid water content in both seasons and cloud fraction in the Spring season. As a result, CAM5 significantly underestimates the surface downward longwave (LW) radiative fluxes by 20-40 W m-2. The model with a new ice nucleation parameterization moderately improves the model simulations by increasing cloud liquid water content in mixed-phase clouds through the reduction of the conversion rate from cloud liquid to ice by the Wegener-Bergeron- Findeisen (WBF) process. The CAM5 single column model testing shows that change in the homogeneous freezing temperature of rain to form snow from -5 C to -40 C has a substantial impact on the modeled liquid water content through the slowing-down of liquid and rain-related processes. In contrast, collections of cloud ice by snow and cloud liquid by rain are of minor importance for single-layer boundary layer mixed-phase clouds in the Arctic.

  6. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  7. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  8. Coupling apparatus for a metal vapor laser

    DOE Patents [OSTI]

    Ball, Don G. (Livermore, CA); Miller, John L. (Dublin, CA)

    1993-01-01T23:59:59.000Z

    Coupling apparatus for a large bore metal vapor laser is disclosed. The coupling apparatus provides for coupling high voltage pulses (approximately 40 KV) to a metal vapor laser with a high repetition rate (approximately 5 KHz). The coupling apparatus utilizes existing thyratron circuits and provides suitable power input to a large bore metal vapor laser while maintaining satisfactory operating lifetimes for the existing thyratron circuits.

  9. Coupling apparatus for a metal vapor laser

    DOE Patents [OSTI]

    Ball, D.G.; Miller, J.L.

    1993-02-23T23:59:59.000Z

    Coupling apparatus for a large bore metal vapor laser is disclosed. The coupling apparatus provides for coupling high voltage pulses (approximately 40 KV) to a metal vapor laser with a high repetition rate (approximately 5 KHz). The coupling apparatus utilizes existing thyratron circuits and provides suitable power input to a large bore metal vapor laser while maintaining satisfactory operating lifetimes for the existing thyratron circuits.

  10. Overview of chemical vapor infiltration

    SciTech Connect (OSTI)

    Besmann, T.M.; Stinton, D.P.; Lowden, R.A.

    1993-06-01T23:59:59.000Z

    Chemical vapor infiltration (CVI) is developing into a commercially important method for the fabrication of continuous filament ceramic composites. Current efforts are focused on the development of an improved understanding of the various processes in CVI and its modeling. New approaches to CVI are being explored, including pressure pulse infiltration and microwave heating. Material development is also proceeding with emphasis on improving the oxidation resistance of the interfacial layer between the fiber and matrix. This paper briefly reviews these subjects, indicating the current state of the science and technology.

  11. Thin Cloud Length Scales Using CALIPSO and CloudSat Data

    E-Print Network [OSTI]

    Solbrig, Jeremy E.

    2010-10-12T23:59:59.000Z

    Thin clouds are the most difficult cloud type to observe. The recent availability of joint cloud products from the active remote sensing instruments aboard CloudSat and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite (CALIPSO) facilitates...

  12. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17T23:59:59.000Z

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  13. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, V.J.; Johnson, S.A.

    1999-08-03T23:59:59.000Z

    A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

  14. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, Vincent J. (Downers Grove, IL); Johnson, Stanley A. (Countryside, IL)

    1999-01-01T23:59:59.000Z

    A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

  15. Using cloud resolving model simulations of deep convection to inform cloud parameterizations in large-scale models

    SciTech Connect (OSTI)

    Klein, Stephen A.; Pincus, Robert; Xu, Kuan-man

    2003-06-23T23:59:59.000Z

    Cloud parameterizations in large-scale models struggle to address the significant non-linear effects of radiation and precipitation that arise from horizontal inhomogeneity in cloud properties at scales smaller than the grid box size of the large-scale models. Statistical cloud schemes provide an attractive framework to self-consistently predict the horizontal inhomogeneity in radiation and microphysics because the probability distribution function (PDF) of total water contained in the scheme can be used to calculate these non-linear effects. Statistical cloud schemes were originally developed for boundary layer studies so extending them to a global model with many different environments is not straightforward. For example, deep convection creates abundant cloudiness and yet little is known about how deep convection alters the PDF of total water or how to parameterize these impacts. These issues are explored with data from a 29 day simulation by a cloud resolving model (CRM) of the July 1997 ARM Intensive Observing Period at the Southern Great Plains site. The simulation is used to answer two questions: (a) how well can the beta distribution represent the PDFs of total water relative to saturation resolved by the CRM? (b) how can the effects of convection on the PDF be parameterized? In addition to answering these questions, additional sections more fully describe the proposed statistical cloud scheme and the CRM simulation and analysis methods.

  16. Cloud Based Applications and Platforms (Presentation)

    SciTech Connect (OSTI)

    Brodt-Giles, D.

    2014-05-15T23:59:59.000Z

    Presentation to the Cloud Computing East 2014 Conference, where we are highlighting our cloud computing strategy, describing the platforms on the cloud (including Smartgrid.gov), and defining our process for implementing cloud based applications.

  17. LES Simulations of Roll Clouds Observed During Mixed- Phase Arctic Cloud Experiment

    SciTech Connect (OSTI)

    Greenberg, S.D.; Harrington, J.Y.; Prenni, A.; DeMott, P.

    2005-03-18T23:59:59.000Z

    Roll clouds, and associated roll convection, are fairly common features of the atmospheric boundary layer. While these organized cumuliform clouds are found over many regions of the planet, they are quite ubiquitous near the edge of the polar ice sheets. In particular, during periods of off-ice flow, when cold polar air flows from the ice pack over the relatively warm ocean water, strong boundary layer convection develops along with frequent rolls. According to Bruemmer and Pohlman (2000), most of the total cloud cover in the Arctic is due to roll clouds. In an effort to examine the influences of mixed-phase microphysics on the boundary layer evolution of roll clouds during off-ice flow, Olsson and Harrington (2000) used a 2D mesoscale model coupled to a bulk microphysical scheme (see Section 2). Their results showed that mixed-phase clouds produced more shallow boundary layers with weaker turbulence than liquid-phase cases. Furthermore, their results showed that because of th e reduced turbulent drag on the atmosphere in the mixed-phase case, regions of mesoscale divergence in the marginal ice-zone were significantly affected. A follow-up 2D study (Harrington and Olsson 2001) showed that the reduced turbulent intensity in mixed-phase cases was due to precipitation. Ice precipitation caused downdraft stabilization which fed back and caused a reduction in the surface heat fluxes. In this work, we extend the work of Olsson and Harrington (2000) and Harrington and Olsson (2001) by examining the impacts of ice microphysics on roll convection. We will present results that illustrate how microphysics alters roll cloud structure and dynamics.

  18. VAPOR PRESSURE ISOTOPE EFFECTS IN THE MEASUREMENT OF ENVIRONMENTAL TRITIUM SAMPLES.

    SciTech Connect (OSTI)

    Kuhne, W.

    2012-12-03T23:59:59.000Z

    Standard procedures for the measurement of tritium in water samples often require distillation of an appropriate sample aliquot. This distillation process may result in a fractionation of tritiated water and regular light water due to the vapor pressure isotope effect, introducing either a bias or an additional contribution to the total tritium measurement uncertainty. The magnitude of the vapor pressure isotope effect is characterized as functions of the amount of water distilled from the sample aliquot and the heat settings for the distillation process. The tritium concentration in the distillate is higher than the tritium concentration in the sample early in the distillation process, it then sharply decreases due to the vapor pressure isotope effect and becomes lower than the tritium concentration in the sample, until the high tritium concentration retained in the boiling flask is evaporated at the end of the process. At that time, the tritium concentration in the distillate again overestimates the sample tritium concentration. The vapor pressure isotope effect is more pronounced the slower the evaporation and distillation process is conducted; a lower heat setting during the evaporation of the sample results in a larger bias in the tritium measurement. The experimental setup used and the fact that the current study allowed for an investigation of the relative change in vapor pressure isotope effect in the course of the distillation process distinguish it from and extend previously published measurements. The separation factor as a quantitative measure of the vapor pressure isotope effect is found to assume values of 1.034 {+-} 0.033, 1.052 {+-} 0.025, and 1.066 {+-} 0.037, depending on the vigor of the boiling process during distillation of the sample. A lower heat setting in the experimental setup, and therefore a less vigorous boiling process, results in a larger value for the separation factor. For a tritium measurement in water samples, this implies that the tritium concentration could be underestimated by 3 - 6%.

  19. Attribution Analysis of Cloud Feedback 

    E-Print Network [OSTI]

    Zhou, Chen

    2014-07-15T23:59:59.000Z

    Uncertainty on cloud feedback is the primary contributor to the large spread of equilibrium climate sensitivity (ECS) in climate models. In this study, we compare the short-term cloud feedback in climate models with observations, and evaluate...

  20. Modeling Incoherent Electron Cloud Effects

    E-Print Network [OSTI]

    Benedetto, E.

    2008-01-01T23:59:59.000Z

    electron-cloud effects and synchrotron radiation can lead toelectron-cloud effects and synchrotron radiation can lead tocloud phenomena in positrons storage rings the effect of syn- chrotron radiation

  1. Quantitative organic vapor-particle sampler

    DOE Patents [OSTI]

    Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

    1998-01-01T23:59:59.000Z

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  2. Secure Cloud Computing With Brokered Trusted

    E-Print Network [OSTI]

    ) ·Audio ·QualComm 7201 528MHZ ·64MB Ram ·MicroSD Slow Storage ·Currently NO SIM CHIPS Monday, March 29 External Storage External Storage Router Router Router Router Cloud Computing Cloud Computing Cloud Storage External Storage Router Router Router Router Cloud Computing Cloud Computing Cloud Computing Tower

  3. Opaque cloud detection

    DOE Patents [OSTI]

    Roskovensky, John K. (Albuquerque, NM)

    2009-01-20T23:59:59.000Z

    A method of detecting clouds in a digital image comprising, for an area of the digital image, determining a reflectance value in at least three discrete electromagnetic spectrum bands, computing a first ratio of one reflectance value minus another reflectance value and the same two values added together, computing a second ratio of one reflectance value and another reflectance value, choosing one of the reflectance values, and concluding that an opaque cloud exists in the area if the results of each of the two computing steps and the choosing step fall within three corresponding predetermined ranges.

  4. Biotic communities and brachiopod paleoecology of the Early Permian McCloud Formation, northern California

    E-Print Network [OSTI]

    Hanger, Rex Alan

    1986-01-01T23:59:59.000Z

    terrene, the shallow water carbonate build-ups are represented by the Early Permian McCloud Formation. Location of Study Area The McCloud Formation crops out discontinuously for about 60 kilometers within Shasta County, California (Figure 2). Effort...BIOTIC COMMUNITIES AND BRACHIOPOD PALEOECOLOGY OF THE EARLY PERMIAN McCLOUD FORMATION, NORTHERN CALIFORNIA. A Thesis by REX ALAN HANGER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements...

  5. Command Line Tools Cloud Computing

    E-Print Network [OSTI]

    Ferrara, Katherine W.

    Command Line Tools Cloud Computing #12;Everybody (or nearly everybody) loves GUI. AWS Command Line of advanced features. After surviving the cloud computing class till now, Your are almost a command line guru! You need AWS command line tools, ec2-api-tools, to maximize the power of AWS cloud computing. Plugging

  6. 8, 96979729, 2008 FRESCO+ cloud

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 9697­9729, 2008 FRESCO+ cloud retrieval algorithm P. Wang et al. Title Page Abstract Chemistry and Physics Discussions FRESCO+: an improved O2 A-band cloud retrieval algorithm for tropospheric on behalf of the European Geosciences Union. 9697 #12;ACPD 8, 9697­9729, 2008 FRESCO+ cloud retrieval

  7. 3, 33013333, 2003 Cirrus cloud

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 3, 3301­3333, 2003 Cirrus cloud occurrence as function of ambient relative humidity J. Str and Physics Discussions Cirrus cloud occurrence as function of ambient relative humidity: A comparison¨om (johan@itm.su.se) 3301 #12;ACPD 3, 3301­3333, 2003 Cirrus cloud occurrence as function of ambient

  8. Cloud Formation, Evolution and Destruction

    E-Print Network [OSTI]

    Estalella, Robert

    Chapter 4 Cloud Formation, Evolution and Destruction We now begin to trace the journey towards a star. How long does this take? The answer is surprisingly short: a good many clouds already contain new stars and these stars tend to be young. The typical cloud cannot spend long, if any time at all

  9. 5, 60136039, 2005 FRESCO cloud

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 6013­6039, 2005 FRESCO cloud algorithm N. Fournier et al. Title Page Abstract Introduction cloud information over deserts from SCIAMACHY O2 A-band N. Fournier 1 , P. Stammes 1 , M. de Graaf 1 , R, 6013­6039, 2005 FRESCO cloud algorithm N. Fournier et al. Title Page Abstract Introduction Conclusions

  10. NIST Cloud Computing Reference Architecture

    E-Print Network [OSTI]

    Perkins, Richard A.

    NIST Cloud Computing Reference Architecture Recommendations of the National Institute of Standards Publication 500-292 #12;i NIST Special Publication 500-292 NIST Cloud Computing Reference Architecture, John Messina, Lee Badger and Dawn Leaf Information Techonology Laboratory Cloud Computing Program

  11. HANFORD CHEMICAL VAPORS WORKER CONCERNS & EXPOSURE EVALUATION

    SciTech Connect (OSTI)

    ANDERSON, T.J.

    2006-12-20T23:59:59.000Z

    Chemical vapor emissions from underground hazardous waste storage tanks on the Hanford site in eastern Washington State are a potential concern because workers enter the tank farms on a regular basis for waste retrievals, equipment maintenance, and surveillance. Tank farm contractors are in the process of retrieving all remaining waste from aging single-shell tanks, some of which date to World War II, and transferring it to newer double-shell tanks. During the waste retrieval process, tank farm workers are potentially exposed to fugitive chemical vapors that can escape from tank headspaces and other emission points. The tanks are known to hold more than 1,500 different species of chemicals, in addition to radionuclides. Exposure assessments have fully characterized the hazards from chemical vapors in half of the tank farms. Extensive sampling and analysis has been done to characterize the chemical properties of hazardous waste and to evaluate potential health hazards of vapors at the ground surface, where workers perform maintenance and waste transfer activities. Worker concerns. risk communication, and exposure assessment are discussed, including evaluation of the potential hazards of complex mixtures of chemical vapors. Concentrations of vapors above occupational exposure limits-(OEL) were detected only at exhaust stacks and passive breather filter outlets. Beyond five feet from the sources, vapors disperse rapidly. No vapors have been measured above 50% of their OELs more than five feet from the source. Vapor controls are focused on limited hazard zones around sources. Further evaluations of vapors include analysis of routes of exposure and thorough analysis of nuisance odors.

  12. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13T23:59:59.000Z

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  13. Stacked vapor fed amtec modules

    DOE Patents [OSTI]

    Sievers, Robert K. (North Huntingdon, PA)

    1989-01-01T23:59:59.000Z

    The present invention pertains to a stacked AMTEC module. The invention includes a tubular member which has an interior. The member is comprised of a ion conductor that substantially conducts ions relative to electrons, preferably a beta"-alumina solid electrolyte, positioned about the interior. A porous electrode for conducting electrons and allowing sodium ions to pass therethrough, and wherein electrons and sodium ions recombine to form sodium is positioned about the beta"-alumina solid electrolyte. The electrode is operated at a temperature and a pressure that allows the recombined sodium to vaporize. Additionally, an outer current collector grid for distributing electrons throughout the porous electrode is positioned about and contacts the porous electrode. Also included in the invention is transporting means for transporting liquid sodium to the beta"-alumina solid electrolyte of the tubular member. A transition piece is positioned about the interior of the member and contacts the transporting means. The transition piece divides the member into a first cell and a second cell such that each first and second cell has a beta"-alumina solid electrolyte, a first and second porous electrode and a grid. The transition piece conducts electrons from the interior of the tubular member. There is supply means for supplying sodium to the transporting means. Preferably the supply means is a shell which surrounds the tubular member and is operated at a temperature such that the vaporized sodium condenses thereon. Returning means for returning the condensed sodium from the shell to the transporting means provides a continuous supply of liquid sodium to the transporting means. Also, there are first conducting means for conducting electric current from the transition piece which extends through the shell, and second conducting means for conducting electric current to the grid of the first cell which extends through the shell.

  14. Experimental investigation of the latent heat of vaporization in aqueous nanofluids

    SciTech Connect (OSTI)

    Lee, Soochan; Phelan, Patrick E., E-mail: phelan@asu.edu; Dai, Lenore; Prasher, Ravi; Gunawan, Andrey [School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287-6106 (United States); Taylor, Robert A. [School of Mechanical and Manufacturing Engineering, University of New South Wales, Sydney 2052 (Australia)

    2014-04-14T23:59:59.000Z

    This paper reports an experimental investigation of the latent heat of vaporization (h{sub fg}) in nanofluids. Two different types of nanoparticles, graphite and silver, suspended in deionized water were exposed to a continuous laser beam (130 mW, 532?nm) to generate boiling. The latent heat of vaporization in the nanofluids was determined by the measured vapor mass generation and the heat input. To ensure that the measured h{sub fg} values are independent of heating method, the experiments were repeated with an electrically heated hot wire as a primary heat input. These experiments show considerable variation in the h{sub fg} of nanofluids. That is, graphite nanofluid exhibits an increased h{sub fg} and silver nanofluid shows a decrease in h{sub fg} compared to the value for pure water. As such, these results indicate that relatively low mass fractions of nanoparticles can apparently create large changes in h{sub fg}.

  15. Quantitative Infrared Intensity Studies of Vapor-PhaseGlyoxal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Intensity Studies of Vapor-Phase Glyoxal,Methylglyoxal, and 2,3-Butanedione (Diacetyl) with Quantitative Infrared Intensity Studies of Vapor-Phase Glyoxal,Methylglyoxal,...

  16. Absolute integrated intensities of vapor-phase hydrogen peroxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Absolute integrated intensities of vapor-phase hydrogen peroxide (H202) in the mid-infrared at atmospheric pressure. Absolute integrated intensities of vapor-phase hydrogen...

  17. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

  18. A High Resolution Hydrometer Phase Classifier Based on Analysis of Cloud Radar Doppler Spectra.

    SciTech Connect (OSTI)

    Luke,E.; Kollias, P.

    2007-08-06T23:59:59.000Z

    The lifecycle and radiative properties of clouds are highly sensitive to the phase of their hydrometeors (i.e., liquid or ice). Knowledge of cloud phase is essential for specifying the optical properties of clouds, or else, large errors can be introduced in the calculation of the cloud radiative fluxes. Current parameterizations of cloud water partition in liquid and ice based on temperature are characterized by large uncertainty (Curry et al., 1996; Hobbs and Rangno, 1998; Intriery et al., 2002). This is particularly important in high geographical latitudes and temperature ranges where both liquid droplets and ice crystal phases can exist (mixed-phase cloud). The mixture of phases has a large effect on cloud radiative properties, and the parameterization of mixed-phase clouds has a large impact on climate simulations (e.g., Gregory and Morris, 1996). Furthermore, the presence of both ice and liquid affects the macroscopic properties of clouds, including their propensity to precipitate. Despite their importance, mixed-phase clouds are severely understudied compared to the arguably simpler single-phase clouds. In-situ measurements in mixed-phase clouds are hindered due to aircraft icing, difficulties distinguishing hydrometeor phase, and discrepancies in methods for deriving physical quantities (Wendisch et al. 1996, Lawson et al. 2001). Satellite-based retrievals of cloud phase in high latitudes are often hindered by the highly reflecting ice-covered ground and persistent temperature inversions. From the ground, the retrieval of mixed-phase cloud properties has been the subject of extensive research over the past 20 years using polarization lidars (e.g., Sassen et al. 1990), dual radar wavelengths (e.g., Gosset and Sauvageot 1992; Sekelsky and McIntosh, 1996), and recently radar Doppler spectra (Shupe et al. 2004). Millimeter-wavelength radars have substantially improved our ability to observe non-precipitating clouds (Kollias et al., 2007) due to their excellent sensitivity that enables the detection of thin cloud layers and their ability to penetrate several non-precipitating cloud layers. However, in mixed-phase clouds conditions, the observed Doppler moments are dominated by the highly reflecting ice crystals and thus can not be used to identify the cloud phase. This limits our ability to identify the spatial distribution of cloud phase and our ability to identify the conditions under which mixed-phase clouds form.

  19. Cloud/Aerosol Parameterizations: Application and Improvement of General Circulation Models

    SciTech Connect (OSTI)

    Penner, Joyce

    2012-06-30T23:59:59.000Z

    One of the biggest uncertainties associated with climate models and climate forcing is the treatment of aerosols and their effects on clouds. The effect of aerosols on clouds can be divided into two components: The first indirect effect is the forcing associated with increases in droplet concentrations; the second indirect effect is the forcing associated with changes in liquid water path, cloud morphology, and cloud lifetime. Both are highly uncertain. This project applied a cloud-resolving model to understand the response of clouds under a variety of conditions to changes in aerosols. These responses are categorized according to the large-scale meteorological conditions that lead to the response. Meteorological conditions were sampled from various fields, which, together with a global aerosol model determination of the change in aerosols from present day to pre-industrial conditions, was used to determine a first order estimate of the response of global cloud fields to changes in aerosols. The response of the clouds in the NCAR CAM3 GCM coupled to our global aerosol model were tested by examining whether the response is similar to that of the cloud resolving model and methods for improving the representation of clouds and cloud/aerosol interactions were examined.

  20. Stratocumulus Clouds ROBERT WOOD

    E-Print Network [OSTI]

    Wood, Robert

    by latent heating in updrafts and cooling in downdrafts. Turbulent eddies and evaporative cooling drives, stratification of the STBL, and in some cases cloud breakup. Feedbacks between radiative cooling, precipitation- way interactions may be a key driver of aerosol concentrations over the remote oceans. Aerosol

  1. Using a cloud resolving model to generate the beam-filling correction for microwave retrieval of oceanic rainfall

    E-Print Network [OSTI]

    Feng, Kai

    2003-01-01T23:59:59.000Z

    ), respectively. They have a parameterized two-class liquid water (cloud water and rain) and a parameterized three-class ice-phase scheme (cloud ice, snow, and graupel). A tropical squall line has been observed on 29 August 1999 during the Kwajalein Experiment...

  2. Computing and Partitioning Cloud Feedbacks Using Cloud Property Histograms. Part I: Cloud Radiative Kernels

    E-Print Network [OSTI]

    Hartmann, Dennis

    radiative forcing. The global and annual mean model-simulated cloud feedback is dominated by contributions to a hypothetical cloudless but other- wise identical planet, the global and annual mean effect of clouds at the top is how cloud radiative effects will change as the planet warms because of long-lived greenhouse gases

  3. Study of Mechanisms of Aerosol Indirect Effects on Glaciated Clouds: Progress during the Project Final Technical Report

    SciTech Connect (OSTI)

    None

    2013-10-18T23:59:59.000Z

    This 3-year project has studied how aerosol pollution influences glaciated clouds. The tool applied has been an 'aerosol-cloud model'. It is a type of Cloud-System Resolving Model (CSRM) modified to include 2-moment bulk microphysics and 7 aerosol species, as described by Phillips et al. (2009, 2013). The study has been done by, first, improving the model and then performing sensitivity studies with validated simulations of a couple of observed cases from ARM. These are namely the Tropical Warm Pool International Cloud Experiment (TWP-ICE) over the tropical west Pacific and the Cloud and Land Surface Interaction Campaign (CLASIC) over Oklahoma. During the project, sensitivity tests with the model showed that in continental clouds, extra liquid aerosols (soluble aerosol material) from pollution inhibited warm rain processes for precipitation production. This promoted homogeneous freezing of cloud droplets and aerosols. Mass and number concentrations of cloud-ice particles were boosted. The mean sizes of cloud-ice particles were reduced by the pollution. Hence, the lifetime of glaciated clouds, especially ice-only clouds, was augmented due to inhibition of sedimentation and ice-ice aggregation. Latent heat released from extra homogeneous freezing invigorated convective updrafts, and raised their maximum cloud-tops, when aerosol pollution was included. In the particular cases simulated in the project, the aerosol indirect effect of glaciated clouds was twice than of (warm) water clouds. This was because glaciated clouds are higher in the troposphere than water clouds and have the first interaction with incoming solar radiation. Ice-only clouds caused solar cooling by becoming more extensive as a result of aerosol pollution. This 'lifetime indirect effect' of ice-only clouds was due to higher numbers of homogeneously nucleated ice crystals causing a reduction in their mean size, slowing the ice-crystal process of snow production and slowing sedimentation. In addition to the known indirect effects (glaciation, riming and thermodynamic), new indirect effects were discovered and quantified due to responses of sedimentation, aggregation and coalescence in glaciated clouds to changing aerosol conditions. In summary, the change in horizontal extent of the glaciated clouds ('lifetime indirect effects'), especially of ice-only clouds, was seen to be of higher importance in regulating aerosol indirect effects than changes in cloud properties ('cloud albedo indirect effects').

  4. Detection of supercooled liquid in mixedphase clouds using radar Doppler spectra

    E-Print Network [OSTI]

    Shupe, Matthew

    in the temperature range from 0 to -40°C, where both liquid and ice hydrometeor phases are sustainable of their hydrometeors (i.e., liquid or ice). Current cloud parameterizations that parti- tion water into liquid and ice 2010; published 1 October 2010. [1] Cloud phase identification from active remote sensors

  5. On the Microphysical Representation of Observed Arctic Mixed-Phase Clouds

    E-Print Network [OSTI]

    Zuidema, Paquita

    On the Microphysical Representation of Observed Arctic Mixed-Phase Clouds Paquita Zuidema, Paul Lawson, Hugh Morrison U of Miami/SPEC, Inc. Boulder CO/NCAR #12;Arctic clouds are often: mixed-phase (ie. both ice + supercooled water) yet long-lasting (despite disequilibrium) #12;why? - are ice nuclei over

  6. Ice nucleation and overseeding of ice in volcanic clouds A. J. Durant,1,2

    E-Print Network [OSTI]

    Rose, William I.

    that such ``overseeded'' volcanic clouds will exhibit enhanced ice crystal concentrations and smaller average ice crystal nucleation in volcanic plumes and clouds affects dynamics [Glaze et al., 1997; Herzog et al., 1998; Mastin- porting water to the stratosphere [Glaze et al., 1997] and these fluxes depend in part on the microphysics

  7. Recovering hydrocarbons from hydrocarbon-containing vapors

    DOE Patents [OSTI]

    Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

    1980-09-30T23:59:59.000Z

    Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

  8. Cobalt Ultrathin Film Catalyzed Ethanol Chemical Vapor Deposition of Single-Walled Carbon Nanotubes

    E-Print Network [OSTI]

    Hone, James

    Cobalt Ultrathin Film Catalyzed Ethanol Chemical Vapor Deposition of Single-Walled Carbon Nanotubes (SWNTs) using a cobalt ultrathin film (1 nm) as the catalyst and ethanol as carbon feedstock flow during the growth. The trace amount of self-contained water (0.2-5 wt %) in ethanol may act

  9. EA-1852: Cloud County Community College Wind Energy Project,...

    Broader source: Energy.gov (indexed) [DOE]

    2: Cloud County Community College Wind Energy Project, Cloud County, Kansas EA-1852: Cloud County Community College Wind Energy Project, Cloud County, Kansas Summary This EA...

  10. Water mist injection in oil shale retorting

    DOE Patents [OSTI]

    Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

    1980-07-30T23:59:59.000Z

    Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

  11. CloudAnalyst: A CloudSim-based Visual Modeller for Analysing Cloud Computing Environments and Applications

    E-Print Network [OSTI]

    Calheiros, Rodrigo N.

    CloudAnalyst: A CloudSim-based Visual Modeller for Analysing Cloud Computing Environments and Applications Bhathiya Wickremasinghe1 , Rodrigo N. Calheiros2 , and Rajkumar Buyya1 1 The Cloud Computing and Distributed Systems (CLOUDS) Laboratory Department of Computer Science and Software Engineering The University

  12. Viscosity of the Aqueous Liquid/Vapor Interfacial Region: 2D Electrochemical Measurements with a Piperidine Nitroxy

    E-Print Network [OSTI]

    Majda, Marcin

    Viscosity of the Aqueous Liquid/Vapor Interfacial Region: 2D Electrochemical Measurements, and that it is coupled to the interfacial water via hydrogen bonding with H2O. In view of this postulate, the viscosity into the dynamic characteristics of aqueous interfaces. Thus, parameters such as the viscosity of water

  13. Chemical vapor infiltration using microwave energy

    DOE Patents [OSTI]

    Devlin, David J. (Los Alamos, NM); Currier, Robert P. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Barbero, Robert S. (Santa Cruz, NM)

    1993-01-01T23:59:59.000Z

    A method for producing reinforced ceramic composite articles by means of chemical vapor infiltration and deposition in which an inverted temperature gradient is utilized. Microwave energy is the source of heat for the process.

  14. Chemical vapor deposition of functionalized isobenzofuran polymers

    E-Print Network [OSTI]

    Olsson, Ylva Kristina

    2007-01-01T23:59:59.000Z

    This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

  15. An advanced vapor-compression desalination system 

    E-Print Network [OSTI]

    Lara Ruiz, Jorge Horacio Juan

    2006-04-12T23:59:59.000Z

    Currently, the two dominant desalination methods are reverse osmosis (RO) and multi-stage flash (MSF). RO requires large capital investment and maintenance, whereas MSF is too energy intensive. An innovative vapor-compression desalination system...

  16. Modeling of LNG Pool Spreading and Vaporization

    E-Print Network [OSTI]

    Basha, Omar 1988-

    2012-11-20T23:59:59.000Z

    In this work, a source term model for estimating the rate of spreading and vaporization of LNG on land and sea is introduced. The model takes into account the composition changes of the boiling mixture, the varying thermodynamic properties due...

  17. Chemical vapor deposition of antimicrobial polymer coatings

    E-Print Network [OSTI]

    Martin, Tyler Philip, 1977-

    2007-01-01T23:59:59.000Z

    There is large and growing interest in making a wide variety of materials and surfaces antimicrobial. Initiated chemical vapor deposition (iCVD), a solventless low-temperature process, is used to form thin films of polymers ...

  18. Hazards to nuclear power plants from large liquefied natural gas (LNG) spills on water

    SciTech Connect (OSTI)

    Kot, C.A.; Eichler, T.V.; Wiedermann, A.H.; Pape, R.; Srinivasan, M.G.

    1981-11-01T23:59:59.000Z

    The hazards to nuclear power plants arising from large spills of liquefied natural gas (LNG) on water transportation routes are treated by deterministic analytical procedures. Global models, which address the salient features of the LNG spill phenomena are used in the analysis. A coupled computational model for the combined LNG spill, spreading, and fire scenario is developed. To predict the air blast environment in the vicinity of vapor clouds with pancake-like geometries, a scalable procedure using both analytical methods and hydrocode calculations is synthesized. Simple response criteria from the fire and weapons effects literature are used to characterize the susceptibility of safety-related power plant systems. The vulnerability of these systems is established either by direct comparison between the LNG threat and the susceptibility criteria or through simple response calculations. Results are analyzed.

  19. Ice Formation in Arctic Mixed-Phase Clouds: Insights from a 3-D Cloud-Resolving Model with Size-Resolved Aerosol and Cloud Microphysics

    SciTech Connect (OSTI)

    Fan, Jiwen; Ovtchinnikov, Mikhail; Comstock, Jennifer M.; McFarlane, Sally A.; Khain, Alexander

    2009-02-27T23:59:59.000Z

    The single-layer mixed-phase clouds observed during the Atmospheric Radiation Measurement (ARM) program’s Mixed-Phase Arctic Cloud Experiment (MPACE) are simulated with a 3-dimensional cloud-resolving model the System for Atmospheric Modeling (SAM) coupled with an explicit bin microphysics scheme and a radar-lidar simulator. Two possible ice enhancement mechanisms – activation of droplet evaporation residues by condensation-followed-by-freezing and droplet freezing by contact freezing inside-out, are scrutinized by extensive comparisons with aircraft and radar and lidar measurements. The locations of ice initiation associated with each mechanism and the role of ice nuclei (IN) in the evolution of mixed-phase clouds are mainly addressed. Simulations with either mechanism agree well with the in-situ and remote sensing measurements on ice microphysical properties but liquid water content is slightly underpredicted. These two mechanisms give very similar cloud microphysical, macrophysical, dynamical, and radiative properties, although the ice nucleation properties (rate, frequency and location) are completely different. Ice nucleation from activation of evaporation nuclei is most efficient near cloud top areas concentrated on the edges of updrafts, while ice initiation from the drop freezing process has no significant location preference (occurs anywhere that droplet evaporation is significant). Both enhanced nucleation mechanisms contribute dramatically to ice formation with ice particle concentration of 10-15 times higher relative to the simulation without either of them. The contribution of ice nuclei (IN) recycling from ice particle evaporation to IN and ice particle concentration is found to be very significant in this case. Cloud can be very sensitive to IN initially and form a nonquilibrium transition condition, but become much less sensitive as cloud evolves to a steady mixed-phase condition. The parameterization of Meyers et al. [1992] with the observed MPACE IN concentration is able to predict the observed mixed-phase clouds reasonably well. This validation may facilitate the application of this parameterization in the cloud and climate models to simulate Arctic clouds.

  20. Solid-Vapor Sorption Refrigeration Systems 

    E-Print Network [OSTI]

    Graebel, W.; Rockenfeller, U.; Kirol, L.

    1991-01-01T23:59:59.000Z

    SOLID-VAPOR SORPTION REFRIGERATION SYSTEMS DR. WILLIAM GRAEBEL DR. UWE ROCKENFELLER MR. LANCE KIROL Engineer President Chief Engineer Rocky Research Rocky Research Rocky Research Boulder city, NV Boulder city, NV Boulder City, NV Abstract.... Complex compounds have a number of advantages as working media, including: 43 SOLID-VAPOR SORPTION REFRIGERATION SYSTEMS DR. WILLIAM GRAEBEL Engineer Rocky Research Boulder city, NV DR. UWE ROCKENFELLER President Rocky Research Boulder city, NV MR...

  1. E-Print Network 3.0 - ad hoc cloud Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    any ad hoc combination of physical processes... . 21. Adding 10% in mass of 10 y m water ice particles to the cloud of Fig 2 ( Y y m, ) reduces... Warming Early Mars with...

  2. Environmental control of cloud-to-ground lightning polarity in severe storms

    E-Print Network [OSTI]

    Buffalo, Kurt Matthew

    2009-05-15T23:59:59.000Z

    directly control cloud electrification and CG flash polarity. A more specific hypothesis, which has been supported by past observational and laboratory charging studies, suggests that broad, strong updrafts and associated large liquid water contents...

  3. A Catalog of HI Clouds in the Large Magellanic Cloud

    E-Print Network [OSTI]

    S. Kim; E. Rosolowsky; Y. Lee; Y. Kim; Y. C. Jung; M. A. Dopita; B. G. Elmegreen; K. C. Freeman; R. J. Sault; M. J. Kesteven; D. McConnell; Y. -H. Chu

    2007-06-28T23:59:59.000Z

    A 21 cm neutral hydrogen interferometric survey of the Large Magellanic Cloud (LMC) combined with the Parkes multi-beam HI single-dish survey clearly shows that the HI gas is distributed in the form of clumps or clouds. The HI clouds and clumps have been identified using a thresholding method with three separate brightness temperature thresholds ($T_b$). Each catalog of HI cloud candidates shows a power law relationship between the sizes and the velocity dispersions of the clouds roughly following the Larson Law scaling $\\sigma_v \\propto R^{0.5}$, with steeper indices associated with dynamically hot regions. The clouds in each catalog have roughly constant virial parameters as a function mass suggesting that that the clouds are all in roughly the same dynamical state, but the values of the virial parameter are significantly larger than unity showing that turbulent motions dominate gravity in these clouds. The mass distribution of the clouds is a power law with differential indices between -1.6 and -2.0 for the three catalogs. In contrast, the distribution of mean surface densities is a log-normal distribution.

  4. amazon state waters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    about a quarter of all global biodiversity. It acts as one of the major flywheels of global climate, transpiring water and generating clouds, affecting atmospheric circulation...

  5. Characterization of melting level clouds over the tropical western pacific warm pool

    SciTech Connect (OSTI)

    Jensen, M.; Johnson, K.; Billings, J.; Troyan, D.; Long, C.; Comstock, J.

    2010-03-15T23:59:59.000Z

    A cursory examination of historical ARSCL data indicates a common cloud feature in the tropics are thin detrainment shelves (Attendant Shelf Clouds, or ASCs) near the melting level (see figure for example). We use the ARSCL product to identify ASCs by defining them as cloud layers with bases above 4 km, a corresponding top below 6 km, and a thickness of less than 1 km. In order to prevent biases in determination of the diurnal cycle of cloud occurrence, we require that both the MMCR and MPL are operating well. In this study we use a total of 55 months of data collected over 14 years of deployments at the Manus, Nauru, and Darwin ARM sites in the Tropical Western Pacific to define the frequency of occurrence (~ 14% of the time) and diurnal cycle of these clouds, along with the atmospheric thermodynamic profile. We further investigate the horizontal extent, cloud radiative forcing, and cloud particle phase through a series of “golden cases” where there is a general absence of additional cloud types in the column and nearby deep convection. These cases indicate that the clouds can cover horizontal areas on the order of a GCM gridbox, have significant (but not always) cloud radiative forcing, and may be composed of liquid or ice water.

  6. Beam Measurements of a CLOUD (Cosmics Leaving OUtdoor Droplets) Chamber

    E-Print Network [OSTI]

    Jasper Kirkby

    2001-04-27T23:59:59.000Z

    A striking correlation has recently been observed between global cloud cover and the flux of incident cosmic rays. The effect of natural variations in the cosmic ray flux is large, causing estimated changes in the Earth's energy radiation balance that are comparable to those attributed to greenhouse gases from the burning of fossil fuels since the Industrial Revolution. However a direct link between cosmic rays and cloud formation has not been unambiguously established. We therefore propose to experimentally measure cloud (water droplet) formation under controlled conditions in a test beam at CERN with a CLOUD chamber, duplicating the conditions prevailing in the troposphere. These data, which have never been previously obtained, will allow a detailed understanding of the possible effects of cosmic rays on clouds and confirm, or otherwise, a direct link between cosmic rays, global cloud cover and the Earth's climate. The measurements will, in turn, allow more reliable calculations to be made of the residual effect on global temperatures of the burning of fossil fuels, an issue of profound importance to society. Furthermore, light radio-isotope records indicate a correlation has existed between global climate and the cosmic ray flux extending back over the present inter-glacial and perhaps earlier. This suggests it may eventually become possible to make long-term (10-1,000 year) predictions of changes in the Earth's climate, provided a deeper understanding can be achieved of the ``geomagnetic climate'' of the Sun and Earth that modulates the cosmic-ray flux.

  7. Polluting of Winter Convective Clouds upon Transition from Ocean Inland Over Central California: Contrasting Case Studies

    SciTech Connect (OSTI)

    Rosenfeld, Daniel; Chemke, Rei; Prather, Kimberly; Suski, Kaitlyn; Comstock, Jennifer M.; Schmid, Beat; Tomlinson, Jason M.; Jonsson, Haf

    2014-01-01T23:59:59.000Z

    In-situ aircraft measurements of aerosol chemical and cloud microphysical properties were conducted during the CalWater campaign in February and March 2011 over the Sierra Nevada Mountains and the coastal waters of central California. The main objective was to elucidate the impacts of aerosol properties on clouds and precipitation forming processes. In order to accomplish this, we compared contrasting cases of clouds that ingested aerosols from different sources. The results showed that clouds containing pristine oceanic air had low cloud drop concentrations and started to develop rain 500 m above their base. This occurred both over the ocean and over the Sierra Nevada, mainly in the early morning when the radiatively cooled stable continental boundary layer was decoupled from the cloud base. Supercooled rain dominated the precipitation that formed in growing convective clouds in the pristine air, up to the -21°C isotherm level. A contrasting situation was documented in the afternoon over the foothills of the Sierra Nevada, when the clouds ingested high pollution aerosol concentrations produced in the Central Valley. This led to slow growth of the cloud drop effective radius with height and suppressed and even prevented the initiation of warm rain while contributing to the development of ice hydrometeors in the form of graupel. Our results show that cloud condensation and ice nuclei were the limiting factors that controlled warm rain and ice processes, respectively, while the unpolluted clouds in the same air mass produced precipitation quite efficiently. These findings provide the motivation for deeper investigations into the nature of the aerosols seeding clouds.

  8. Monday, March 13, 2006 MARS: CORE TO CLOUDS

    E-Print Network [OSTI]

    Rathbun, Julie A.

    with current orbital configurations. We run the model for five years with a northern water ice cap then release Core [#1500] We present new melting data in the system Fe-Ni-S at Martian core pressures, using multi. Clouds, Cap, and Consequences: Outflow Events and Mars Hesperian Climate [#1484] We focus on how outflows

  9. ANNOUNCEMENT Project Atmospheric Brown Cloud (ABC) 2006 TRAINING SCHOOL

    E-Print Network [OSTI]

    Cohen, Ronald C.

    composition, radiative effects and transport of atmospheric aerosols and related atmospheric pollutanANNOUNCEMENT Project Atmospheric Brown Cloud (ABC) 2006 TRAINING SCHOOL Project ABC Science consequences of the haze involve regional and global climate change, impacts on ecosystem, the water cycle

  10. Water Formation in the Early Universe

    E-Print Network [OSTI]

    Bialy, Shmuel; Loeb, Abraham

    2015-01-01T23:59:59.000Z

    We demonstrate that high abundances of water vapor could have existed in extremely low metallicity ($10^{-3}$ solar) partially shielded gas, during the epoch of first metal enrichment of the interstellar medium of galaxies at high redshifts.

  11. A Survey on Cloud Provider Security

    E-Print Network [OSTI]

    A Survey on Cloud Provider Security Measures Alex Pucher, Stratos Dimopoulos Abstract Cloud take advantage of this model already, but security and privacy concerns limit the further adoption agencies and start offering security certifications and separate tightly controlled "government" cloud

  12. Cicada: Predictive Guarantees for Cloud Network Bandwidth

    E-Print Network [OSTI]

    LaCurts, Katrina

    2014-03-24T23:59:59.000Z

    In cloud-computing systems, network-bandwidth guarantees have been shown to improve predictability of application performance and cost. Most previous work on cloud-bandwidth guarantees has assumed that cloud tenants know ...

  13. Electron-Cloud Build-Up: Summary

    E-Print Network [OSTI]

    Furman, M.A.

    2007-01-01T23:59:59.000Z

    Properties In?uencing Electron Cloud Phenomena,” Appl. Surf.Dissipation of the Electron Cloud,” Proc. PAC03 (Portland,is no signi?cant electron-cloud under nominal operating

  14. DIRSIG Cloud Modeling Capabilities; A Parametric Study

    E-Print Network [OSTI]

    Salvaggio, Carl

    1 DIRSIG Cloud Modeling Capabilities; A Parametric Study Kristen Powers powers:................................................................................................................... 13 Calculation of Sensor Reaching Radiance Truth Values for Cloudless & Stratus Cloud Scenes and Atmospheric Database Creation for Stratus Cloud Scene & Calculation of Associated Sensor Reaching Radiance

  15. Magellan: experiences from a Science Cloud

    E-Print Network [OSTI]

    Ramakrishnan, Lavanya

    2013-01-01T23:59:59.000Z

    2010. From Clusters To Clouds: xCAT 2 Is Out Of The Bag.Cost of Doing Science on the Cloud: The Montage Example. Incost of doing science on the cloud: the montage example. In

  16. The Cloud Computing and Other Variables

    E-Print Network [OSTI]

    Borjon-Kubota, Martha Estela

    2011-01-01T23:59:59.000Z

    12. Fragments in Six 13. Cloud Computing 14. Phase 15.Note 48. Devoured vi Cloud Computing and other Variables I.moment. Lasts hours. Cloud Computing Just there Over the

  17. The Magellan Final Report on Cloud Computing

    E-Print Network [OSTI]

    Coghlan, Susan

    2013-01-01T23:59:59.000Z

    4.3.1 Cloud Computing Attractive Features . 4.3.2A berkeley view of cloud computing. Technical Report UCB/matching computations on cloud computing platforms and hpc

  18. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01T23:59:59.000Z

    and transport properties of carbon dioxide for molecularinterfacial properties of binary carbon dioxide – waterCarbon dioxide’s liquid—vapor coexistence curve and critical properties

  19. Sunlight Changes Aerosols in Clouds | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sunlight Changes Aerosols in Clouds Sunlight Changes Aerosols in Clouds Released: October 20, 2011 Scientists show how sunlight alters optical, chemical properties of atmospheric...

  20. 3, 44614488, 2003 Cloud particle

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    effects. On one hand, clouds reflect the incoming solar radiation and thus cool the Earth significant effect on the radiation balance (Wielicki et al, 1996; Mitchell, 1989) due to two competing-Atmosphere system. On the other hand, clouds absorb longwave thermal radiation coming from the surface and then re

  1. Method and Apparatus for Concentrating Vapors for Analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2008-10-07T23:59:59.000Z

    An apparatus and method are disclosed for pre-concentrating gaseous vapors for analysis. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable. Vapors sorbed and concentrated within the bed of the apparatus can be thermally desorbed achieving at least partial separation of vapor mixtures. The apparatus is suitable, e.g., for preconcentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than for direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications.

  2. Desalination of water by vapor transport through hydrophobic nanopores

    E-Print Network [OSTI]

    Lee, Jongho, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Although Reverse osmosis (RO) is the state-of-the-art desalination technology, it still suffers from persistent drawbacks including low permeate flux, low selectivity for non-ionic species, and lack of resistance to chlorine. ...

  3. EXAMINING THE SPECTROSCOPY OF WATER VAPOR IN THE ATMOSPHERE

    E-Print Network [OSTI]

    Petta, Jason

    Used to prove stable flow in C.O. Data Comparison and Analysis Linear Fit Within 3% error #12 and Analysis Plot VCSEL M.R. against Standard Calibrate According to Linear Fit Use Beers Lawł and Ideal Gas Designing Components for the Circuit Insert into steel, airtight container Record Spectra Data Comparison

  4. ARM - Field Campaign - Arctic Winter Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76)ARM2,govCampaignsAircraft Integration

  5. ARM - Field Campaign - Single Frequency GPS Water Vapor Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa- Polarization DiversityPolarization

  6. Overview of the ARM/FIRE Water Vapor Experiment (AFWEX)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomass and BiofuelsOversight Board TheOverview of the ARM/FIRE

  7. Method of physical vapor deposition of metal oxides on semiconductors

    DOE Patents [OSTI]

    Norton, David P. (Knoxville, TN)

    2001-01-01T23:59:59.000Z

    A process for growing a metal oxide thin film upon a semiconductor surface with a physical vapor deposition technique in a high-vacuum environment and a structure formed with the process involves the steps of heating the semiconductor surface and introducing hydrogen gas into the high-vacuum environment to develop conditions at the semiconductor surface which are favorable for growing the desired metal oxide upon the semiconductor surface yet is unfavorable for the formation of any native oxides upon the semiconductor. More specifically, the temperature of the semiconductor surface and the ratio of hydrogen partial pressure to water pressure within the vacuum environment are high enough to render the formation of native oxides on the semiconductor surface thermodynamically unstable yet are not so high that the formation of the desired metal oxide on the semiconductor surface is thermodynamically unstable. Having established these conditions, constituent atoms of the metal oxide to be deposited upon the semiconductor surface are directed toward the surface of the semiconductor by a physical vapor deposition technique so that the atoms come to rest upon the semiconductor surface as a thin film of metal oxide with no native oxide at the semiconductor surface/thin film interface. An example of a structure formed by this method includes an epitaxial thin film of (001)-oriented CeO.sub.2 overlying a substrate of (001) Ge.

  8. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2007-10-23T23:59:59.000Z

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  9. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2006-07-26T23:59:59.000Z

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  10. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, T.

    1988-03-15T23:59:59.000Z

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

  11. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, Terry (Tracy, CA)

    1988-01-01T23:59:59.000Z

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself.

  12. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, Jr., Edward P. (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

  13. Atmos. Chem. Phys., 2, 3137, 2002 www.atmos-chem-phys.org/acp/2/31/ Atmospheric

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    be overestimated due to the as- sumption of constant low cloud cover in the simple radiative- convective model. 1 and Physics Tropical cirrus and water vapor: an effective Earth infrared iris feedback? Q. Fu, M. Baker, and D with upper tropospheric water vapor and cloud ra- diative effects. We argue that the water vapor feedback

  14. Mesoscale Modeling During Mixed-Phase Arctic Cloud Experiment

    SciTech Connect (OSTI)

    Avramov, A.; Harringston, J.Y.; Verlinde, J.

    2005-03-18T23:59:59.000Z

    Mixed-phase arctic stratus clouds are the predominant cloud type in the Arctic (Curry et al. 2000) and through various feedback mechanisms exert a strong influence on the Arctic climate. Perhaps one of the most intriguing of their features is that they tend to have liquid tops that precipitate ice. Despite the fact that this situation is colloidally unstable, these cloud systems are quite long lived - from a few days to over a couple of weeks. It has been hypothesized that mixed-phase clouds are maintained through a balance between liquid water condensation resulting from the cloud-top radiative cooling and ice removal by precipitation (Pinto 1998; Harrington et al. 1999). In their modeling study Harrington et al. (1999) found that the maintenance of this balance depends strongly on the ambient concentration of ice forming nucleus (IFN). In a follow-up study, Jiang et al. (2002), using only 30% of IFN concentration predicted by Meyers et al. (1992) IFN parameterization were able to obtain results similar to the observations reported by Pinto (1998). The IFN concentration measurements collected during the Mixed-Phase Arctic Cloud Experiment (M-PACE), conducted in October 2004 over the North Slope of Alaska and the Beaufort Sea (Verlinde et al. 2005), also showed much lower values then those predicted (Prenne, pers. comm.) by currently accepted ice nucleation parameterizations (e.g. Meyers et al. 1992). The goal of this study is to use the extensive IFN data taken during M-PACE to examine what effects low IFN concentrations have on mesoscale cloud structure and coastal dynamics.

  15. Advanced Chemical Heat Pumps Using Liquid-Vapor Reactions 

    E-Print Network [OSTI]

    Kirol, L.

    1987-01-01T23:59:59.000Z

    Chemical heat pumps utilizing liquid-vapor reactions can be configured in forms analogous to electric drive vapor-compression heat pumps and heat activated absorption heat pumps. Basic thermodynamic considerations eliminate some heat pumps and place...

  16. Moisture Durability of Vapor Permeable Insulating Sheathing (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-10-01T23:59:59.000Z

    In this project, Building America team Building Science Corporation researched some of the ramifications of using exterior, vapor permeable insulation on retrofit walls with vapor permeable cavity insulation. Retrofit strategies are a key factor in reducing exterior building stock consumption.

  17. Vapor intrusion modeling : limitations, improvements, and value of information analyses

    E-Print Network [OSTI]

    Friscia, Jessica M. (Jessica Marie)

    2014-01-01T23:59:59.000Z

    Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

  18. OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL

    E-Print Network [OSTI]

    Stanford University

    OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL RESERVOIRS CONSIDERING ADSORPTION governing the behavior of vapor- dominated geothermal reservoirs. These mechanisms affect both was to determine the most effective injection strategy once these two effects are considered. Geothermal reservoir

  19. Final report on the project entitled "The Effects of Disturbance & Climate on Carbon Storage & the Exchanges of CO2 Water Vapor & Energy Exchange of Evergreen Coniferous Forests in the Pacific Northwest: Integration of Eddy Flux, Plant and Soil Measurements at a Cluster of Supersites"

    SciTech Connect (OSTI)

    Beverly E. Law (PI), Christoph K. Thomas (CoI)

    2011-09-20T23:59:59.000Z

    This is the final technical report containing a summary of all findings with regard to the following objectives of the project: (1) To quantify and understand the effects of wildfire on carbon storage and the exchanges of energy, CO2, and water vapor in a chronosequence of ponderosa pine (disturbance gradient); (2) To investigate the effects of seasonal and interannual variation in climate on carbon storage and the exchanges of energy, CO2, and water vapor in mature conifer forests in two climate zones: mesic 40-yr old Douglas-fir and semi-arid 60-yr old ponderosa pine (climate gradient); (3) To reduce uncertainty in estimates of CO2 feedbacks to the atmosphere by providing an improved model formulation for existing biosphere-atmosphere models; and (4) To provide high quality data for AmeriFlux and the NACP on micrometeorology, meteorology, and biology of these systems. Objective (1): A study integrating satellite remote sensing, AmeriFlux data, and field surveys in a simulation modeling framework estimated that the pyrogenic carbon emissions, tree mortality, and net carbon exchange associated with four large wildfires that burned ~50,000 hectares in 2002-2003 were equivalent to 2.4% of Oregon statewide anthropogenic carbon emissions over the same two-year period. Most emissions were from the combustion of the forest floor and understory vegetation, and only about 1% of live tree mass was combusted on average. Objective (2): A study of multi-year flux records across a chronosequence of ponderosa pine forests yielded that the net carbon uptake is over three times greater at a mature pine forest compared with young pine. The larger leaf area and wetter and cooler soils of the mature forest mainly caused this effect. A study analyzing seven years of carbon and water dynamics showed that interannual and seasonal variability of net carbon exchange was primarily related to variability in growing season length, which was a linear function of plant-available soil moisture in spring and early summer. A multi-year drought (2001-2003) led to a significant reduction of net ecosystem exchange due to carry-over effects in soil moisture and carbohydrate reserves in plant-tissue. In the same forest, the interannual variability in the rate carbon is lost from the soil and forest floor is considerable and related to the variability in tree growth as much as it is to variability in soil climatic conditions. Objective (3): Flux data from the mature ponderosa pine site support a physical basis for filtering nighttime data with friction velocity above the canopy. An analysis of wind fields and heat transport in the subcanopy at the mesic 40-year old Douglas site yielded that the non-linear structure and behavior of spatial temperature gradients and the flow field require enhanced sensor networks to estimate advective fluxes in the subcanopy of forest to close the surface energy balance in forests. Reliable estimates for flux uncertainties are needed to improve model validation and data assimilation in process-based carbon models, inverse modeling studies and model-data synthesis, where the uncertainties may be as important as the fluxes themselves. An analysis of the time scale dependence of the random and flux sampling error yielded that the additional flux obtained by increasing the perturbation timescale beyond about 10 minutes is dominated by random sampling error, and therefore little confidence can be placed in its value. Artificial correlation between gross ecosystem productivity (GEP) and ecosystem respiration (Re) is a consequence of flux partitioning of eddy covariance flux data when GEP is computed as the difference between NEE and computed daytime Re (e.g. using nighttime Re extrapolated into daytime using soil or air temperatures). Tower-data must be adequately spatially averaged before comparison to gridded model output as the time variability of both is inherently different. The eddy-covariance data collected at the mature ponderosa pine site and the mesic Douglas fir site were used to develop and evaluate a new method to extra

  20. Platform for Hybrid Cloud Technical White Paper

    E-Print Network [OSTI]

    Chaudhuri, Surajit

    Platform for Hybrid Cloud Technical White Paper Published: September 2013 (updated) Applies to: SQL Server and Windows Azure Summary: Cloud computing brings a new paradigm shift in computing in the cloud with greater scale and flexibility. Microsoft SQL Server runs very well in the cloud environment

  1. Cloud Computing An enterprise perspective Raghavan Subramanian

    E-Print Network [OSTI]

    Rajamani, Sriram K.

    Cloud Computing ­ An enterprise perspective Raghavan Subramanian Infosys Technologies Limited #12;2Infosys Confidential Overview of cloud computing? Cloud computing* Computing in which dynamically scalable of cloud computing 1. On-demand self-service 2. Ubiquitous network access 3. Location independent resource

  2. IBM Software Solution Brief Safeguarding the cloud

    E-Print Network [OSTI]

    IBM Software Solution Brief Safeguarding the cloud with IBM Security solutions Maintain visibility and control with proven security solutions for public, private and hybrid clouds Highlights Address cloud internal and external users, data, applications and workloads as they move to and from the cloud Regain

  3. 7, 1711717146, 2007 Dependence of cloud

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 7, 17117­17146, 2007 Dependence of cloud fraction and cloud height on temperature T. Wagner et a Creative Commons License. Atmospheric Chemistry and Physics Discussions Dependence of cloud fraction and cloud top height on surface temperature derived from spectrally resolved UV/vis satellite observations T

  4. Draft NISTIR 80061 NIST Cloud Computing2

    E-Print Network [OSTI]

    Draft NISTIR 80061 NIST Cloud Computing2 Forensic Science Challenges NIST Cloud Computing Forensic Computing11 Forensic Science Challenges 12 NIST Cloud Computing Forensic Science Working Group13 Information challenges77 faced by experts when responding to incidents that have occurred in a cloud-computing ecosystem

  5. Cloud Data Management (CDM) Yunpeng Chai

    E-Print Network [OSTI]

    /W performance / Parallelism No/ Simple SQL operations 12 /26 Survey of CDM Cloud Storage: Architecture: Master#12;Cloud Data Management (CDM) Yunpeng Chai 2 /26 Outline Motivation of CDM Survey of CDM IBM SUR Cloud China Mobile National Health Care #12;9 /26 Outline Motivation of CDM Survey of CDM IBM SUR Cloud

  6. 6, 43414373, 2006 Cloud-borne aerosol

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Discussions Impact of cloud-borne aerosol representation on aerosol direct and indirect effects S. J. Ghan of aerosols employ a variety of rep- resentations of such cloud-borne particles. Here we use a global aerosol- ulated aerosol, cloud and radiation fields to various approximations to the representa- tion of cloud

  7. Cloud radar Doppler spectra in drizzling stratiform clouds: 2. Observations and microphysical modeling of drizzle evolution

    E-Print Network [OSTI]

    Cloud radar Doppler spectra in drizzling stratiform clouds: 2. Observations and microphysical I, the influence of cloud microphysics and dynamics on the shape of cloud radar Doppler spectra in warm stratiform clouds was discussed. The traditional analysis of radar Doppler moments was extended

  8. Vision: Cloud-Powered Sight for All Showing the Cloud What You See

    E-Print Network [OSTI]

    Zhong, Lin

    Vision: Cloud-Powered Sight for All Showing the Cloud What You See Paramvir Bahl Matthai Philipose argue that for computers to do more for us, we need to show the cloud what we see and embrace cloud General Terms Algorithms, Design, Human Factors, Languages, Performance, Security Keywords Camera, cloud

  9. CLOUD, DRIZZLE, AND TURBULENCE OBSERVATIONS IN MARINE STRATOCUMULUS CLOUDS IN THE AZORES

    E-Print Network [OSTI]

    CLOUD, DRIZZLE, AND TURBULENCE OBSERVATIONS IN MARINE STRATOCUMULUS CLOUDS IN THE AZORES Jasmine at the Azores provided a unique, long-term record (May 2009 to December 2010) of cloud observations in a regime dominated by low-level stratiform clouds. First, a comprehensive cloud classification scheme that utilizes

  10. Cloud Futures Workshop 2010 Cloud Computing Support for Massively Social Gaming Alexandru Iosup

    E-Print Network [OSTI]

    Iosup, Alexandru

    1 Cloud Futures Workshop 2010 ­ Cloud Computing Support for Massively Social Gaming Alexandru Iosup Pierre (Vrije U.). Cloud Computing Support for Massively Social Gaming (Rain for the Thirsty) #12;Cloud Futures Workshop 2010 ­ Cloud Computing Support for Massively Social Gaming 2 Intermezzo: Tips on how

  11. Changes in Cloud Cover and Cloud Types Over the Ocean from Surface

    E-Print Network [OSTI]

    Hochberg, Michael

    Total cloud cover 54 68 Clear sky (frequency) 22 3 #12;Low Clouds & Solar Radiation Low clouds scatterChanges in Cloud Cover and Cloud Types Over the Ocean from Surface Observations, 1954-2008 Ryan This produces a weak net warming effect in the atmosphere, since more radiation comes in, and less goes out

  12. A Survey of Changes in Cloud Cover and Cloud Types over Land from Surface Observations, 197196

    E-Print Network [OSTI]

    Hochberg, Michael

    of their effects on solar radiation, terrestrial radiation, and precipitation. These effects depend on cloud height, and the season of the year and time of day. The effect of clouds on the earth's radiation budget, the "cloud to be a useful classification in studies of cloud processes (Houze 1993). The climatic effects of clouds further

  13. Advancing Explosives Detection Capabilities: Vapor Detection

    ScienceCinema (OSTI)

    Atkinson, David

    2014-07-24T23:59:59.000Z

    A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

  14. Vaporization of synthetic fuels. Final report. [Thesis

    SciTech Connect (OSTI)

    Sirignano, W.A.; Yao, S.C.; Tong, A.Y.; Talley, D.

    1983-01-01T23:59:59.000Z

    The problem of transient droplet vaporization in a hot convective environment is examined. The main objective of the present study is to develop an algorithm for the droplet vaporization which is simple enough to be feasibly incorporated into a complete spray combustion analysis and yet will also account for the important physics such as liquid-phase internal circulation, unsteady droplet heating and axisymmetric gas-phase convection. A simplified liquid-phase model has been obtained based on the assumption of the existence of a Hill's spherical vortex inside the droplet together with some approximations made in the governing diffusion equation. The use of the simplified model in a spray situation has also been examined. It has been found that droplet heating and vaporization are essentially unsteady and droplet temperature is nonuniform for a significant portion of its lifetime. It has also been found that the droplet vaporization characteristic can be quite sensitive to the particular liquid-phase and gas-phase models. The results of the various models are compared with the existing experimental data. Due to large scattering in the experimental measurements, particularly the droplet diameter, no definite conclusion can be drawn based on the experimental data. Finally, certain research problems which are related to the present study are suggested for future studies.

  15. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01T23:59:59.000Z

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  16. Atomic-vapor-laser isotope separation

    SciTech Connect (OSTI)

    Davis, J.I.

    1982-10-01T23:59:59.000Z

    This paper gives a brief history of the scientific considerations leading to the development of laser isotope separation (LIS) processes. The close relationship of LIS to the broader field of laser-induced chemical processes is evaluated in terms of physical criteria to achieve an efficient production process. Atomic-vapor LIS processes under development at Livermore are reviwed. 8 figures.

  17. Program performs vapor-liquid equilibrium calculations

    SciTech Connect (OSTI)

    Rice, V.L.

    1982-06-28T23:59:59.000Z

    A program designed for the Hewlett-Packard HP-41CV or 41C calculators solves basic vapor-liquid equilibrium problems, including figuring the dewpoint, bubblepoint, and equilibrium flash. The algorithm uses W.C. Edmister's method for predicting ideal-solution K values.

  18. Effects of Ocean Ecosystem on Marine Aerosol-Cloud Interaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meskhidze, Nicholas; Nenes, Athanasios

    2010-01-01T23:59:59.000Z

    Using satellite data for the surface ocean, aerosol optical depth (AOD), and cloud microphysical parameters, we show that statistically significant positive correlations exist between ocean ecosystem productivity, the abundance of submicron aerosols, and cloud microphysical properties over different parts of the remote oceans. The correlation coefficient for remotely sensed surface chlorophyllaconcentration ([Chl-a]) and liquid cloud effective radii over productive areas of the oceans varies between?0.2and?0.6. Special attention is given to identifying (and addressing) problems from correlation analysis used in the previous studies that can lead to erroneous conclusions. A new approach (using the difference between retrieved AOD and predicted seamore »salt aerosol optical depth,AODdiff) is developed to explore causal links between ocean physical and biological systems and the abundance of cloud condensation nuclei (CCN) in the remote marine atmosphere. We have found that over multiple time periods, 550?nmAODdiff(sensitive to accumulation mode aerosol, which is the prime contributor to CCN) correlates well with [Chl-a] over the productive waters of the Southern Ocean. Since [Chl-a] can be used as a proxy of ocean biological productivity, our analysis demonstrates the role of ocean ecology in contributing CCN, thus shaping the microphysical properties of low-level marine clouds.« less

  19. Developmental of a Vapor Cloud Explosion Risk Analysis Tool Using Exceedance Methodology

    E-Print Network [OSTI]

    Alghamdi, Salem

    2012-10-19T23:59:59.000Z

    . ................................................................ 20 4 Chart for blast overpressure according to the multi-energy method .......... 27 5 Chart for blast duration according to the multi-energy method ................. 28 6 The overall methodology of the program... .......................................................................................... 64 21 The wind rose for the case study ................................................................ 65 22 The side-on overpressure exceedance curve at 56 meters distance............ 68 23 The side-on overpressure exceedance curve...

  20. Modeling engine oil vaporization and transport of the oil vapor in the piston ring pack on internal combustion engines

    E-Print Network [OSTI]

    Cho, Yeunwoo, 1973-

    2004-01-01T23:59:59.000Z

    A model was developed to study engine oil vaporization and oil vapor transport in the piston ring pack of internal combustion engines. With the assumption that the multi-grade oil can be modeled as a compound of several ...

  1. The interaction of flow, heat transfer, and free interfaces in an electron-beam vaporization system for metals

    SciTech Connect (OSTI)

    Westerberg, K.W. [Aspen Technology, Inc., Cambridge, MA (United States); McClelland, M.A. [Lawrence Livermore National Lab., CA (United States); Finlayson, B.A. [Univ. of Washington, Seattle, WA (United States)

    1994-11-01T23:59:59.000Z

    A numerical analysis is made of the liquid flow and energy transport in a system to vaporize metals. The energy from an electron beam heats metal confined in a water-cooled crucible. Metal vaporizes from a hot pool of circulating liquid which is surrounded by a shell of its own solid. Flow in the pool is strongly driven by temperature-induced buoyancy and capillary forces and is located in the transition region between laminar and turbulent flow. At high vaporization rates, the thrust of the departing vapor forms a trench at the beam impact site. A modified finite element method is used to calculate the flow and temperature fields coupled with the interface locations. The mesh is structured with spines that stretch and pivot as the interfaces move. The discretized equations are arranged in an {open_quotes}arrow{close_quotes} matrix and solved using the Newton-Raphson method. The electron-beam power and width are varied for cases involving the high-rate vaporization of aluminum. Attention is focused on the interaction of vaporization, liquid flow, and heat transport in the trench area.

  2. Understanding and Improving CRM and GCM Simulations of Cloud Systems with ARM Observations

    SciTech Connect (OSTI)

    Wu, Xiaoqing

    2014-02-25T23:59:59.000Z

    The works supported by this ASR project lay the solid foundation for improving the parameterization of convection and clouds in the NCAR CCSM and the climate simulations. We have made a significant use of CRM simulations and ARM observations to produce thermodynamically and dynamically consistent multi-year cloud and radiative properties; improve the GCM simulations of convection, clouds and radiative heating rate and fluxes using the ARM observations and CRM simulations; and understand the seasonal and annual variation of cloud systems and their impacts on climate mean state and variability. We conducted multi-year simulations over the ARM SGP site using the CRM with multi-year ARM forcing data. The statistics of cloud and radiative properties from the long-term CRM simulations were compared and validated with the ARM measurements and value added products (VAP). We evaluated the multi-year climate simulations produced by the GCM with the modified convection scheme. We used multi-year ARM observations and CRM simulations to validate and further improve the trigger condition and revised closure assumption in NCAR GCM simulations that demonstrate the improvement of climate mean state and variability. We combined the improved convection scheme with the mosaic treatment of subgrid cloud distributions in the radiation scheme of the GCM. The mosaic treatment of cloud distributions has been implemented in the GCM with the original convection scheme and enables the use of more realistic cloud amounts as well as cloud water contents in producing net radiative fluxes closer to observations. A physics-based latent heat (LH) retrieval algorithm was developed by parameterizing the physical linkages of observed hydrometeor profiles of cloud and precipitation to the major processes related to the phase change of atmospheric water.

  3. The Microbase Value-Added Product: A Baseline Retrieval of Cloud Microphysical Properties

    SciTech Connect (OSTI)

    Dunn, M; Johnson, K; Jensen, M

    2011-05-31T23:59:59.000Z

    This report describes the Atmospheric Radiation Measurement (ARM) Climate Research Facility baseline cloud microphysical properties (MICROBASE) value-added product (VAP). MICROBASE uses a combination of millimeter-wavelength cloud radar, microwave radiometer, and radiosonde observations to estimate the vertical profiles of the primary microphysical parameters of clouds including the liquid/ice water content and liquid/ice cloud particle effective radius. MICROBASE is a baseline algorithm designed to apply to most conditions and locations using a single set of parameterizations and a simple determination of water phase based on temperature. This document provides the user of this product with guidelines to assist in determining the accuracy of the product under certain conditions. Quality control flags are designed to identify outliers and indicate instances where the retrieval assumptions may not be met. The overall methodology is described in this report through a detailed description of the input variables, algorithms, and output products.

  4. Cloud Computing and Validation of Expandable In Silico Livers

    E-Print Network [OSTI]

    Ropella, Glen EP; Hunt, C Anthony

    2010-01-01T23:59:59.000Z

    benefit analysis of cloud computing versus desktop grids.as: Ropella and Hunt: Cloud computing and validation ofCloud computing and validation of expandable in silico

  5. Metal vapor laser including hot electrodes and integral wick

    DOE Patents [OSTI]

    Ault, Earl R. (Livermore, CA); Alger, Terry W. (Tracy, CA)

    1995-01-01T23:59:59.000Z

    A metal vapor laser, specifically one utilizing copper vapor, is disclosed herein. This laser utilizes a plasma tube assembly including a thermally insulated plasma tube containing a specific metal, e.g., copper, and a buffer gas therein. The laser also utilizes means including hot electrodes located at opposite ends of the plasma tube for electrically exciting the metal vapor and heating its interior to a sufficiently high temperature to cause the metal contained therein to vaporize and for subjecting the vapor to an electrical discharge excitation in order to lase. The laser also utilizes external wicking arrangements, that is, wicking arrangements located outside the plasma tube.

  6. Metal vapor laser including hot electrodes and integral wick

    DOE Patents [OSTI]

    Ault, E.R.; Alger, T.W.

    1995-03-07T23:59:59.000Z

    A metal vapor laser, specifically one utilizing copper vapor, is disclosed herein. This laser utilizes a plasma tube assembly including a thermally insulated plasma tube containing a specific metal, e.g., copper, and a buffer gas therein. The laser also utilizes means including hot electrodes located at opposite ends of the plasma tube for electrically exciting the metal vapor and heating its interior to a sufficiently high temperature to cause the metal contained therein to vaporize and for subjecting the vapor to an electrical discharge excitation in order to lase. The laser also utilizes external wicking arrangements, that is, wicking arrangements located outside the plasma tube. 5 figs.

  7. Industrial Heat Pumps Using Solid/Vapor Working Fluids

    E-Print Network [OSTI]

    Rockenfeller, U.

    with vapor re-compression recovery systems. The state-of-the-art heat pump equipment employing liquid/vapor working fluids fulfills the requirements only in some applications. The employment of solid/vapor complex compounds leads to 'nore cost effective... allows for firing temperatures much higher than possible with liquid/vapor systems. The high energy density per unit mass and the independence of the vapor pressure from the refrigerant concentration (p = f (T), p "# f( x)) over a wide range leads...

  8. Title: Networking the Cloud: Enabling Enterprise Computing and Storage Cloud computing has been changing how enterprises run and manage their IT systems. Cloud

    E-Print Network [OSTI]

    Title: Networking the Cloud: Enabling Enterprise Computing and Storage Abstract: Cloud computing has been changing how enterprises run and manage their IT systems. Cloud computing platforms provide introduction on Cloud Computing. We propose a Virtual Cloud Pool abstraction to logically unify cloud

  9. Using Surface Remote Sensors to Derive Radiative Characteristics of Mixed-Phase Clouds: An Example from M-PACE

    SciTech Connect (OSTI)

    de Boer, Gijs; Collins, William D.; Menon, Surabi; Long, Charles N.

    2011-12-02T23:59:59.000Z

    Measurements from ground-based cloud radar, high spectral resolution lidar and microwave radiometer are used in conjunction with a column version of the Rapid Radiative Transfer Model (RRTMG) and radiosonde measurements to derive the surface radiative properties under mixed-phase cloud conditions. These clouds were observed during the United States Department of Energy (US DOE) Atmospheric Radiation Measurement (ARM) Mixed-Phase Arctic Clouds Experiment (M-PACE) between September and November of 2004. In total, sixteen half hour time periods are reviewed due to their coincidence with radiosonde launches. Cloud liquid (ice) water paths are found to range between 11.0-366.4 (0.5-114.1) gm-2, and cloud physical thicknesses fall between 286-2075 m. Combined with temperature and hydrometeor size estimates, this information is used to calculate surface radiative flux densities using RRTMG, which are demonstrated to generally agree with measured flux densities from surface-based radiometric instrumentation. Errors in longwave flux density estimates are found to be largest for thin clouds, while shortwave flux density errors are generally largest for thicker clouds. A sensitivity study is performed to understand the impact of retrieval assumptions and uncertainties on derived surface radiation estimates. Cloud radiative forcing is calculated for all profiles, illustrating longwave dominance during this time of year, with net cloud forcing generally between 50 and 90 Wm-2.

  10. Cluster analysis of cloud properties : a method for diagnosing cloud-climate feedbacks

    E-Print Network [OSTI]

    Gordon, Neil D.

    2008-01-01T23:59:59.000Z

    represent cloud effects on gridbox mean visible radiationclouds and the resulting effect on the balance of radiationrepresent cloud effects on grid-box-mean visible radiation

  11. How might a statistical cloud scheme be coupled to a mass-flux convection scheme?

    SciTech Connect (OSTI)

    Klein, Stephen A.; Pincus, Robert; Hannay, Cecile; Xu, Kuan-man

    2004-09-27T23:59:59.000Z

    The coupling of statistical cloud schemes with mass-flux convection schemes is addressed. Source terms representing the impact of convection are derived within the framework of prognostic equations for the width and asymmetry of the probability distribution function of total water mixing ratio. The accuracy of these source terms is quantified by examining output from a cloud resolving model simulation of deep convection. Practical suggestions for inclusion of these source terms in large-scale models are offered.

  12. The Evolution of Cloud Computing in ATLAS

    E-Print Network [OSTI]

    Taylor, Ryan P.; The ATLAS collaboration; Love, Peter; Leblanc, Matthew Edgar; Di Girolamo, Alessandro; Paterson, Michael; Gable, Ian; Sobie, Randall; Field, Laurence

    2015-01-01T23:59:59.000Z

    The ATLAS experiment has successfully incorporated cloud computing technology and cloud resources into its primarily grid-based model of distributed computing. Cloud R&D activities continue to mature and transition into stable production systems, while ongoing evolutionary changes are still needed to adapt and refine the approaches used, in response to changes in prevailing cloud technology. In addition, completely new developments are needed to handle emerging requirements. This work will describe the overall evolution of cloud computing in ATLAS. The current status of the VM management systems used for harnessing IAAS resources will be discussed. Monitoring and accounting systems tailored for clouds are needed to complete the integration of cloud resources within ATLAS' distributed computing framework. We are developing and deploying new solutions to address the challenge of operation in a geographically distributed multi-cloud scenario, including a system for managing VM images across multiple clouds, ...

  13. Precision micro drilling with copper vapor lasers

    SciTech Connect (OSTI)

    Chang, J.J.; Martinez, M.W.; Warner, B.E.; Dragon, E.P.; Huete, G.; Solarski, M.E.

    1994-09-02T23:59:59.000Z

    The authors have developed a copper vapor laser based micro machining system using advanced beam quality control and precision wavefront tilting technologies. Micro drilling has been demonstrated through percussion drilling and trepanning using this system. With a 30 W copper vapor laser running at multi-kHz pulse repetition frequency, straight parallel holes with size varying from 500 microns to less than 25 microns and with aspect ratio up to 1:40 have been consistently drilled on a variety of metals with good quality. For precision trepanned holes, the hole-to-hole size variation is typically within 1% of its diameter. Hole entrance and exit are both well defined with dimension error less than a few microns. Materialography of sectioned holes shows little (sub-micron scale) recast layer and heat affected zone with surface roughness within 1--2 microns.

  14. Atomic vapor spectroscopy in integrated photonic structures

    E-Print Network [OSTI]

    Ritter, Ralf; Pernice, Wolfram; Kübler, Harald; Pfau, Tilman; Löw, Robert

    2015-01-01T23:59:59.000Z

    We investigate an integrated optical chip immersed in atomic vapor providing several waveguide geometries for spectroscopy applications. The narrow-band transmission through a silicon nitride waveguide and interferometer is altered when the guided light is coupled to a vapor of rubidium atoms via the evanescent tail of the waveguide mode. We use grating couplers to couple between the waveguide mode and the radiating wave, which allow for addressing arbitrary coupling positions on the chip surface. The evanescent atom-light interaction can be numerically simulated and shows excellent agreement with our experimental data. This work demonstrates a next step towards miniaturization and integration of alkali atom spectroscopy and provides a platform for further fundamental studies of complex waveguide structures.

  15. Desalination Using Vapor-Compression Distillation 

    E-Print Network [OSTI]

    Lubis, Mirna R.

    2010-07-14T23:59:59.000Z

    The ability to produce potable water economically is the primary purpose of seawater desalination research. Reverse osmosis (RO) and multi-stage flash (MSF) cost more than potable water produced from fresh water resources. As an alternative to RO...

  16. Tropical Warm Pool International Cloud Experiment (TWP-ICE): Cloud and Rain Characteristics in the Australian Monsoon

    SciTech Connect (OSTI)

    PT May; C Jakob; JH Mather

    2004-05-30T23:59:59.000Z

    The impact of oceanic convection on its environment and the relationship between the characteristics of the convection and the resulting cirrus characteristics is still not understood. An intense airborne measurement campaign combined with an extensive network of ground-based observations is being planned for the region near Darwin, Northern Australia, during January-February, 2006, to address these questions. The Tropical Warm Pool – International Cloud Experiment (TWP-ICE) will be the first field program in the tropics that attempts to describe the evolution of tropical convection, including the large scale heat, moisture, and momentum budgets, while at the same time obtaining detailed observations of cloud properties and the impact of the clouds on the environment. The emphasis will be on cirrus for the cloud properties component of the experiment. Cirrus clouds are ubiquitous in the tropics and have a large impact on their environment but the properties of these clouds are poorly understood. A crucial product from this experiment will be a dataset suitable to provide the forcing and testing required by cloud-resolving models and parameterizations in global climate models. This dataset will provide the necessary link between cloud properties and the models that are attempting to simulate them. The experiment is a collaboration between the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Program, the Bureau of Meteorology (BoM), the National Aeronautics and Space Administration (NASA), the European Commission DG RTD-1.2, and several United States, Australian, Canadian, and European Universities. This experiment will be undertaken over a 4-week period in early 2006. January and February corresponds to the wet phase of the Australia monsoon. This season has been selected because, despite Darwin’s coastal location, the convection that occurs over and near Darwin at this time is largely of maritime origin with a large fetch over water. Based on previous experiments, the convection appears typical of maritime convection with widespread convection that has complex organization, but is not as deep or as intense as continental or coastal convection. Therefore, it is expected that the convection and cloud characteristics will be representative of conditions typical for wide areas of the tropics.

  17. Apparatus and method for photochemical vapor deposition

    DOE Patents [OSTI]

    Jackson, Scott C. (Wilmington, DE); Rocheleau, Richard E. (Wilmington, DE)

    1987-03-31T23:59:59.000Z

    A photochemical vapor deposition apparatus includes a reactor housing having a window in one wall above a reaction chamber in the housing. A transparent curtain divides the reaction chamber into a reaction zone and a flush zone. At least one substrate is mounted in the reaction zone in light communication with the window so that ultraviolet radiation may penetrate through the window into the reaction zone. The window is kept clear by a gas flowing through the flush zone.

  18. Solid-Vapor Sorption Refrigeration Systems

    E-Print Network [OSTI]

    Graebel, W.; Rockenfeller, U.; Kirol, L.

    SOLID-VAPOR SORPTION REFRIGERATION SYSTEMS DR. WILLIAM GRAEBEL DR. UWE ROCKENFELLER MR. LANCE KIROL Engineer President Chief Engineer Rocky Research Rocky Research Rocky Research Boulder city, NV Boulder city, NV Boulder City, NV Abstract... Complex compound sorption reactions are ideally suited for use in refrigeration cycles as an economically viable alternative to CFC refrigerants. Complex compound refrigeration provides a number of energy-saving advantages over present refrigeration...

  19. DuPont Chemical Vapor Technical Report

    SciTech Connect (OSTI)

    MOORE, T.L.

    2003-10-03T23:59:59.000Z

    DuPont Safety Resources was tasked with reviewing the current chemical vapor control practices and providing preventive recommendations on best commercial techniques to control worker exposures. The increased focus of the tank closure project to meet the 2024 Tri-Party Agreement (TPA) milestones has surfaced concerns among some CH2MHill employees and other interested parties. CH2MHill is committed to providing a safe working environment for employees and desires to safely manage the tank farm operations using appropriate control measures. To address worker concerns, CH2MHill has chartered a ''Chemical Vapors Project'' to integrate the activities of multiple CH2MHill project teams, and solicit the expertise of external resources, including an independent Industrial Hygiene expert panel, a communications consultant, and DuPont Safety Resources. Over a three-month time period, DuPont worked with CH2MHill ESH&Q, Industrial Hygiene, Engineering, and the independent expert panel to perform the assessment. The process included overview presentations, formal interviews, informal discussions, documentation review, and literature review. DuPont Safety Resources concluded that it is highly unlikely that workers in the tank farms are exposed to chemicals above established standards. Additionally, the conventional and radiological chemistry is understood, the inherent chemical hazards are known, and the risk associated with chemical vapor exposure is properly managed. The assessment highlighted management's commitment to addressing chemical vapor hazards and controlling the associated risks. Additionally, we found the Industrial Hygiene staff to be technically competent and well motivated. The tank characterization data resides in a comprehensive database containing the tank chemical compositions and relevant airborne concentrations.

  20. Combined rankine and vapor compression cycles

    DOE Patents [OSTI]

    Radcliff, Thomas D.; Biederman, Bruce P.; Brasz, Joost J.

    2005-04-19T23:59:59.000Z

    An organic rankine cycle system is combined with a vapor compression cycle system with the turbine generator of the organic rankine cycle generating the power necessary to operate the motor of the refrigerant compressor. The vapor compression cycle is applied with its evaporator cooling the inlet air into a gas turbine, and the organic rankine cycle is applied to receive heat from a gas turbine exhaust to heat its boiler within one embodiment, a common condenser is used for the organic rankine cycle and the vapor compression cycle, with a common refrigerant, R-245a being circulated within both systems. In another embodiment, the turbine driven generator has a common shaft connected to the compressor to thereby eliminate the need for a separate motor to drive the compressor. In another embodiment, an organic rankine cycle system is applied to an internal combustion engine to cool the fluids thereof, and the turbo charged air is cooled first by the organic rankine cycle system and then by an air conditioner prior to passing into the intake of the engine.

  1. High volume fuel vapor release valve

    SciTech Connect (OSTI)

    Gimby, D.R.

    1991-09-03T23:59:59.000Z

    This patent describes a fuel vapor release valve for use in a vehicle fuel system. It comprises a valve housing 10 placed in a specific longitudinal orientation, the valve housing 10 defining an interior cavity 22 having an inlet 20 for admitting fuel vapor and an outlet 14 for discharging such fuel vapor; a valve member 24 positioned in the cavity 22 for movement between an outlet 14 opening position and an outlet 14 closing position, the valve member 24 including a cap member 34 having a seat surface 36 for mating with the outlet 14 and an orifice 42 extending through the cap member 34 providing a passageway from the outlet 14 to the cavity 22, the orifice 42 extending through the cap member 34 providing a passageway from the outlet 14 to the cavity 22, the orifice 42 having a lesser radius than the outlet 14; the valve member 24 further including a plug member 30 engaged with the cap member 34 for movement between an orifice 42 opening position and an orifice 42 closing position; and, a valve housing tilt responsive means for moving the valve member 24 to an outlet 14 and orifice 42 closing position in response to tilting of the valve 10 about its longitudinal axis whereby, upon the return of the valve 10 to its specified longitudinal orientation, the plug member 30 first moves to an orifice 42 opening position and the cap member 34 subsequently moves to an outlet 14 opening position.

  2. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Chunsong; Liu, Yangang; Niu, Shengjie; Endo, Satoshi

    2014-12-27T23:59:59.000Z

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasingmore »scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.« less

  3. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Chunsong [Nanjing Univ. of Information Science and Technology (China). Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters; Chinese Acadamy of Sciences, Beijing (China); Brookhaven National Laboratory (BNL), Upton, NY (United States). Biological, Environmental and Climate Science Dept.; Liu, Yangang [Brookhaven National Laboratory (BNL), Upton, NY (United States). Biological, Environmental and Climate Science Dept.; Niu, Shengjie [Nanjing Univ. of Information Science and Technology (China). Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters; Endo, Satoshi [Brookhaven National Laboratory (BNL), Upton, NY (United States). Biological, Environmental and Climate Science Dept.

    2014-12-27T23:59:59.000Z

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasing scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.

  4. Dust takes detour on ice-cloud journey | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dust takes detour on ice-cloud journey Dust takes detour on ice-cloud journey Pollution-coated particles bypass ice formation, but influence clouds Cirrus clouds are composed of...

  5. Inhomogeneous distribution of droplets in cloud turbulence

    E-Print Network [OSTI]

    Itzhak Fouxon; Yongnam Park; Roei Harduf; Changhoon Lee

    2014-10-30T23:59:59.000Z

    We solve the problem of spatial distribution of inertial particles that sediment in turbulent flow with small ratio of acceleration of fluid particles to acceleration of gravity $g$. The particles are driven by linear drag and have arbitrary inertia. The pair-correlation function of concentration obeys a power-law in distance with negative exponent. Divergence at zero signifies singular distribution of particles in space. Independently of particle size the exponent is ratio of integral of energy spectrum of turbulence times the wavenumber to $g$ times numerical factor. We find Lyapunov exponents and confirm predictions by direct numerical simulations of Navier-Stokes turbulence. The predictions include typical case of water droplets in clouds. This significant progress in the study of turbulent transport is possible because strong gravity makes the particle's velocity at a given point unique.

  6. Model analysis of the anthropogenic aerosol effect on clouds over East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhang, Meigen; Liu, Xiaohong; Zhao, Chun

    2012-01-16T23:59:59.000Z

    A coupled meteorology and aerosol/chemistry model WRF-Chem (Weather Research and Forecast model coupled with Chemistry) was used to conduct a pair of simulations with present-day (PD) and preindustrial (PI) emissions over East Asia to examine the aerosol indirect effect on clouds. As a result of an increase in aerosols in January, the cloud droplet number increased by 650 cm{sup -3} over the ocean and East China, 400 cm{sup -3} over Central and Southwest China, and less than 200 cm{sup -3} over North China. The cloud liquid water path (LWP) increased by 40-60 g m{sup -2} over the ocean and Southeast China and 30 g m{sup -2} over Central China; the LWP increased less than 5 g m{sup -2} or decreased by 5 g m{sup -2} over North China. The effective radius (Re) decreased by more than 4 {mu}m over Southwest, Central, and Southeast China and 2 {mu}m over North China. In July, variations in cloud properties were more uniform; the cloud droplet number increased by approximately 250-400 cm{sup -3}, the LWP increased by approximately 30-50 g m{sup -2}, and Re decreased by approximately 3 {mu}m over most regions of China. In response to cloud property changes from PI to PD, shortwave (SW) cloud radiative forcing strengthened by 30 W m{sup -2} over the ocean and 10 W m{sup -2} over Southeast China, and it weakened slightly by approximately 2-10 W m{sup -2} over Central and Southwest China in January. In July, SW cloud radiative forcing strengthened by 15 W m{sup -2} over Southeast and North China and weakened by 10 W m{sup -2} over Central China. The different responses of SW cloud radiative forcing in different regions was related to cloud feedbacks and natural variability.

  7. Socially Optimal Pricing of Cloud Computing Resources

    E-Print Network [OSTI]

    Menache, Ishai

    The cloud computing paradigm offers easily accessible computing resources of variable size and capabilities. We consider a cloud-computing facility that provides simultaneous service to a heterogeneous, time-varying ...

  8. The Evolution of Cloud Computing in ATLAS

    E-Print Network [OSTI]

    Taylor, Ryan P; The ATLAS collaboration; Brasolin, Franco; Cordeiro, Cristovao; Desmarais, Ron; Field, Laurence; Gable, Ian; Giordano, Domenico; Di Girolamo, Alessandro; Hover, John; Leblanc, Matthew Edgar; Love, Peter; Paterson, Michael; Sobie, Randall; Zaytsev, Alexandr

    2015-01-01T23:59:59.000Z

    The ATLAS experiment has successfully incorporated cloud computing technology and cloud resources into its primarily grid-based model of distributed computing. Cloud R&D activities continue to mature and transition into stable production systems, while ongoing evolutionary changes are still needed to adapt and refine the approaches used, in response to changes in prevailing cloud technology. In addition, completely new developments are needed to handle emerging requirements. This paper describes the overall evolution of cloud computing in ATLAS. The current status of the virtual machine (VM) management systems used for harnessing infrastructure as a service (IaaS) resources are discussed. Monitoring and accounting systems tailored for clouds are needed to complete the integration of cloud resources within ATLAS' distributed computing framework. We are developing and deploying new solutions to address the challenge of operation in a geographically distributed multi-cloud scenario, including a system for ma...

  9. Disruptive technology business models in cloud computing

    E-Print Network [OSTI]

    Krikos, Alexis Christopher

    2010-01-01T23:59:59.000Z

    Cloud computing, a term whose origins have been in existence for more than a decade, has come into fruition due to technological capabilities and marketplace demands. Cloud computing can be defined as a scalable and flexible ...

  10. Simulation of natural corrosion by vapor hydration test: seven-year results

    SciTech Connect (OSTI)

    Luo, J.S.; Ebert, W.L.; Mazer, J.J.; Bates, J.K.

    1996-12-31T23:59:59.000Z

    We have investigated the alteration behavior of synthetic basalt and SRL 165 borosilicate waste glasses that had been reacted in water vapor at 70 {degrees}C for time periods up to seven years. The nature and extent of corrosion of glasses have been determined by characterizing the reacted glass surface with optical microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive x-ray spectroscopy (EDS). Alteration in 70 {degrees}C laboratory tests was compared to that which occurs at 150-200 {degrees}C and also with Hawaiian basaltic glasses of 480 to 750 year old subaerially altered in nature. Synthetic basalt and waste glasses, both containing about 50 percent wt SiO{sub 2} were found to react with water vapor to form an amorphous hydrated gel that contained small amounts of clay, nearly identical to palagonite layers formed on naturally altered basaltic glass. This result implies that the corrosion reaction in nature can be simulated with a vapor hydration test. These tests also provide a means for measuring the corrosion kinetics, which are difficult to determine by studying natural samples because alteration layers have often spelled off the samples and we have only limited knowledge of the conditions under which alteration occurred.

  11. SCANNING CLOUD RADAR OBSERVATIONS AT AZORES: PRELIMINARY 3D CLOUD PRODUCTS

    E-Print Network [OSTI]

    SCANNING CLOUD RADAR OBSERVATIONS AT AZORES: PRELIMINARY 3D CLOUD PRODUCTS P. Kollias, I. Jo, A, NY www.bnl.gov ABSTRACT The deployment of the Scanning W-Band ARM Cloud Radar (SWACR) during the AMF campaign at Azores signals the first deployment of an ARM Facility-owned scanning cloud radar and offers

  12. Cloud-Top Temperatures for Precipitating Winter Clouds JAY W. HANNA

    E-Print Network [OSTI]

    Schultz, David

    1 Cloud-Top Temperatures for Precipitating Winter Clouds JAY W. HANNA NOAA/NESDIS Satellite of satellite-derived cloud-top brightness temperatures from GOES longwave infrared (channel 4) satellite data, rain, freezing rain, and sleet. The distributions of cloud-top brightness temperatures were constructed

  13. Cloud networking and communications Cloud computing is having an important impact on

    E-Print Network [OSTI]

    Boutaba, Raouf

    Editorial Cloud networking and communications Cloud computing is having an important impact attention has been devoted to system aspects of Cloud computing. More recently, however, the focus is shifting towards Cloud net- working and communications with evolutionary and revo- lutionary propositions

  14. Cloud seeding as a technique for studying aerosol-cloud interactions in marine stratocumulus

    E-Print Network [OSTI]

    Miami, University of

    Cloud seeding as a technique for studying aerosol-cloud interactions in marine stratocumulus hygroscopic aerosols were introduced into a solid marine stratocumulus cloud (200 m thick) by burning hygroscopic flares mounted on an aircraft. The cloud microphysical response in two parallel seeding plumes

  15. Cloud radar Doppler spectra in drizzling stratiform clouds: 1. Forward modeling and remote sensing applications

    E-Print Network [OSTI]

    Cloud radar Doppler spectra in drizzling stratiform clouds: 1. Forward modeling and remote sensing broadening and drizzle growth in shallow liquid clouds remain not well understood. Detailed, cloudscale. Profiling, millimeterwavelength (cloud) radars can provide such observations. In particular, the first three

  16. The Cloud Adoption Toolkit: Supporting Cloud Adoption Decisions in the Enterprise

    E-Print Network [OSTI]

    Sommerville, Ian

    1 The Cloud Adoption Toolkit: Supporting Cloud Adoption Decisions in the Enterprise Ali Khajeh-Hosseini, David Greenwood, James W. Smith, Ian Sommerville Cloud Computing Co-laboratory, School of Computer Science University of St Andrews, UK {akh, dsg22, jws7, ifs}@cs.st-andrews.ac.uk Abstract Cloud computing

  17. CLOUD COMPUTING AND INFORMATION POLICY 1 Cloud Computing and Information Policy

    E-Print Network [OSTI]

    Lin, Jimmy

    CLOUD COMPUTING AND INFORMATION POLICY 1 Cloud Computing and Information Policy: Computing in a Policy Cloud? Forthcoming in the Journal of Information Technology and Politics, 5(3). Paul T. Jaeger University of Maryland Jimmy Lin University of Maryland Justin M. Grimes University of Maryland #12;CLOUD

  18. HPI Cloud Symposium ,Operating The Cloud` 25.09.2013, Hasso-Plattner-Institut, Auditorium Building

    E-Print Network [OSTI]

    Weske, Mathias

    Agenda HPI Cloud Symposium ,Operating The Cloud` 25.09.2013, Hasso-Plattner-Institut, Auditorium Building 09:30h Registration 10:00h Opening Prof. Dr. Christoph Meinel, HPI Potsdam 10:30h Cloud-RAID: Eine Methode zur Bereitstellung zuverlässiger Speicherressourcen in Öffentlichen Clouds Maxim Schnajkin, HPI

  19. Cloud Verifier: Verifiable Auditing Service for IaaS Clouds Joshua Schiffman

    E-Print Network [OSTI]

    Jaeger, Trent

    Cloud Verifier: Verifiable Auditing Service for IaaS Clouds Joshua Schiffman Security Architecture University Park, PA, USA yus138,hvijay,tjaeger@cse.psu.edu Abstract--Cloud computing has commoditized compute paradigm, its adoption has been stymied by cloud platform's lack of trans- parency, which leaves customers

  20. Cloud Tracking in Cloud-Resolving Models R. S. Plant1

    E-Print Network [OSTI]

    Plant, Robert

    Cloud Tracking in Cloud-Resolving Models R. S. Plant1 1 Department of Meteorology, University. INTRODUCTION In recent years Cloud Resolving Models (CRMs) have become an increasingly important tool for CRM data, which allows one to investigate statistical prop- erties of the lifecycles of the "clouds

  1. From mini-clouds to Cloud Computing Boris Mejias, Peter Van Roy

    E-Print Network [OSTI]

    Bonaventure, Olivier

    From mini-clouds to Cloud Computing Boris Mej´ias, Peter Van Roy Universit´e catholique de Louvain ­ Belgium {boris.mejias|peter.vanroy}@uclouvain.be Abstract Cloud computing has many definitions with different views within industry and academia, but everybody agrees on that cloud computing is the way

  2. AnonymousCloud: A Data Ownership Privacy Provider Framework in Cloud Computing

    E-Print Network [OSTI]

    Hamlen, Kevin W.

    AnonymousCloud: A Data Ownership Privacy Provider Framework in Cloud Computing Safwan Mahmud Khan their computation results are ultimately delivered. To provide this data ownership privacy, the cloud's distributed-anonymity; authentication; cloud computing; in- formation security; privacy; Tor I. INTRODUCTION Revolutionary advances

  3. Leveraging Platform Basic Services in Cloud Application Platforms for the Development of Cloud

    E-Print Network [OSTI]

    Simons, Anthony J. H.

    Leveraging Platform Basic Services in Cloud Application Platforms for the Development of Cloud.Simons@dcs.shef.ac.uk Abstract-- Cloud application platforms gain popularity and have the potential to alter the way service based cloud applications are developed involving utilisation of platform basic services. A platform

  4. Carbon Chemistry in interstellar clouds

    E-Print Network [OSTI]

    Maryvonne Gerin; David Fosse; Evelyne Roueff

    2002-12-03T23:59:59.000Z

    We discuss new developments of interstellar chemistry, with particular emphasis on the carbon chemistry. We confirm that carbon chains and cycles are ubiquitous in the ISM and closely chemically related to ea ch other, and to carbon. Investigation of the carbon budget in shielded and UV illuminated gas shows that the inventory of interstellar molecules is not complete and more complex molecules with 4 or more carbon atoms must be present. Finally we discuss the consequences for the evolution of clouds and conclude that the ubiquitous presence of carbon chains and cycles is not a necessary consequence of a very young age for interstellar clouds.

  5. Changes in high cloud conditions

    E-Print Network [OSTI]

    Himebrook, Richard Frank

    1974-01-01T23:59:59.000Z

    ). When the effect of unknowns is added to the data (Figs. 3(a) and 3(b), p, 21), the period with most high-cloud cover seems to alter- nate back and forth almost monthly, The average, global, solar radiation (Fig. 3(c), p. 21) depicts a decrease from... radiation, per cent possible sunshine, and average sky cover. The increases in high-cloud cover occurred in areas with the following characteristics: strong upper-air flow; frequent jet ' aircraft traffic; coverage of less than half the sky; late...

  6. Method and apparatus for concentrating vapors for analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2012-06-05T23:59:59.000Z

    A pre-concentration device and a method are disclosed for concentrating gaseous vapors for analysis. Vapors sorbed and concentrated within the bed of the pre-concentration device are thermally desorbed, achieving at least partial separation of the vapor mixtures. The pre-concentration device is suitable, e.g., for pre-concentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable.

  7. A SPITZER SPACE TELESCOPE FAR-INFRARED SPECTRAL ATLAS OF COMPACT SOURCES IN THE MAGELLANIC CLOUDS. I. THE LARGE MAGELLANIC CLOUD

    SciTech Connect (OSTI)

    Van Loon, Jacco Th.; Oliveira, Joana M. [Astrophysics Group, Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG (United Kingdom); Gordon, Karl D.; Meixner, Margaret; Shiao, Bernie; Boyer, Martha L. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Kemper, F.; Woods, Paul M. [Jodrell Bank Centre for Astrophysics, Alan Turing Building, School of Physics and Astronomy, The University of Manchester, Oxford Road, Manchester M13 9PL (United Kingdom); Tielens, A. G. G. M. [Leiden Observatory, P.O. Box 9513, NL-2300 RA Leiden (Netherlands); Marengo, Massimo [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Indebetouw, Remy; Chen, C.-H. Rosie [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); Sloan, G. C. [Department of Astronomy, Cornell University, Ithaca, NY 14853 (United States)], E-mail: jacco@astro.keele.ac.uk

    2010-01-15T23:59:59.000Z

    We present far-infrared spectra, {lambda} = 52-93 {mu}m, obtained with the Spitzer Space Telescope in the spectral energy distribution mode of its MIPS instrument, of a representative sample of the most luminous compact far-infrared sources in the Large Magellanic Cloud (LMC). These include carbon stars, OH/IR asymptotic giant branch (AGB) stars, post-AGB objects and planetary nebulae, the R CrB-type star HV 2671, the OH/IR red supergiants (RSGs) WOH G064 and IRAS 05280 - 6910, the three B[e] stars IRAS 04530 - 6916, R 66 and R 126, the Wolf-Rayet star Brey 3a, the luminous blue variable (LBV) R 71, the supernova remnant N 49, a large number of young stellar objects (YSOs), compact H II regions and molecular cores, and a background galaxy at a redshift z {approx_equal} 0.175. We use the spectra to constrain the presence and temperature of cold dust and the excitation conditions and shocks within the neutral and ionized gas, in the circumstellar environments and interfaces with the surrounding interstellar medium (ISM). First, we introduce a spectral classification scheme. Then, we measure line strengths, dust temperatures, and IR luminosities. Objects associated with star formation are readily distinguished from evolved stars by their cold dust and/or fine-structure lines. Evolved stars, including the LBV R 71, lack cold dust except in some cases where we argue that this is swept-up ISM. This leads to an estimate of the duration of the prolific dust-producing phase ('superwind') of several thousand years for both RSGs and massive AGB stars, with a similar fractional mass loss experienced despite the different masses. We tentatively detect line emission from neutral oxygen in the extreme RSG WOH G064, which suggests a large dust-free cavity with implications for wind driving. In N 49, the shock between the supernova ejecta and ISM is revealed in spectacular fashion by its strong [O I] {lambda}63 {mu}m emission and possibly water vapor; we estimate that 0.2 M {sub sun} of ISM dust was swept up. On the other hand, some of the compact H II regions display pronounced [O III] {lambda}88 {mu}m emission. The efficiency of photoelectric heating in the interfaces of ionized gas and molecular clouds is estimated at 0.1%-0.3%. We confirm earlier indications of a low nitrogen content in the LMC. Evidence for solid state emission features is found in both young and evolved objects, but the carriers of these features remain elusive; some of the YSOs are found to contain crystalline water ice. The spectra constitute a valuable resource for the planning and interpretation of observations with the Herschel Space Observatory and the Stratospheric Observatory For Infrared Astronomy.

  8. Interactive physically-based cloud simulation

    E-Print Network [OSTI]

    Overby, Derek Robert

    2002-01-01T23:59:59.000Z

    of digital artistic media. Previous methods for modeling the growth of clouds do not account for the fluid interactions that are responsible for cloud formation in the physical atmosphere. We propose a model for simulating cloud formation based on a basic...

  9. Dynamics of Clouds Fall Semester 2012

    E-Print Network [OSTI]

    ATS712 Dynamics of Clouds Fall Semester 2012 Meeting Times: T/Th: 9-10:15am Room: ATS 101-2pm Course Description: This class focuses on the general dynamics of cloud systems. Models of fog and other Tools / Skills Cotton, W.R., G.H. Bryan, and S.C. van den Heever, 2010: Storm and Cloud Dynamics

  10. Microsoft Private Cloud Title of document

    E-Print Network [OSTI]

    Chaudhuri, Surajit

    Microsoft Private Cloud Title of document 1 1 Microsoft Private Cloud A Comparative Look at Functionality, Benefits, and Economics November2012 #12;Microsoft Private Cloud Title of document 2 2 Copyright Information © 2012 Microsoft Corporation. All rights reserved. This document is provided "as-is." Information

  11. Performance Engineering for Cloud Computing John Murphy

    E-Print Network [OSTI]

    Murphy, John

    Performance Engineering for Cloud Computing John Murphy Lero ­ The Irish Software Engineering.Murphy@ucd.ie Abstract. Cloud computing potentially solves some of the major challenges in the engineering of large efficient operation. This paper argues that cloud computing is an area where performance engineering must

  12. Level Set Implementations on Unstructured Point Cloud

    E-Print Network [OSTI]

    Duncan, James S.

    Level Set Implementations on Unstructured Point Cloud by HO, Hon Pong A Thesis Submitted;Level Set Implementations on Unstructured Point Cloud by HO, Hon Pong This is to certify that I have implementations on unstructured point cloud 15 3.1 Level set initialization

  13. 6, 93519388, 2006 Aerosol-cloud

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 9351­9388, 2006 Aerosol-cloud interaction inferred from MODIS and models G. Myhre et al Chemistry and Physics Discussions Aerosol-cloud interaction inferred from MODIS satellite data and global 6, 9351­9388, 2006 Aerosol-cloud interaction inferred from MODIS and models G. Myhre et al. Title

  14. Cloud Security: Issues and Concerns Pierangela Samarati*

    E-Print Network [OSTI]

    Samarati, Pierangela

    1 Cloud Security: Issues and Concerns Authors Pierangela Samarati* Universitŕ degli Studi di Milano, Italy sabrina.decapitani@unimi.it Keywords cloud security confidentiality integrity availability secure data storage and processing Summary The cloud has emerged as a successful computing paradigm

  15. Cloud Computing: Centralization and Data Sovereignty

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Cloud Computing: Centralization and Data Sovereignty Primavera De Filippi, Smari McCarthy Abstract: Cloud computing can be defined as the provision of computing resources on-demand over and elasticity of costs, problems arise concerning the collection of personal information in the Cloud

  16. Optimizing Offloading Strategies in Mobile Cloud Computing

    E-Print Network [OSTI]

    Hyytiä, Esa

    Optimizing Offloading Strategies in Mobile Cloud Computing Esa Hyyti¨a Department of Communications Abstract--We consider a dynamic offloading problem arising in the context of mobile cloud computing (MCC consider the task assignment problem arising in the context of the mobile cloud computing (MCC). In MCC

  17. CONTROLLING DATA IN THE CLOUD: OUTSOURCING COMPUTATION

    E-Print Network [OSTI]

    Zou, Cliff C.

    #12;CONTROLLING DATA IN THE CLOUD: OUTSOURCING COMPUTATION WITHOUT OUTSOURCING CONTROL Paper By Laboratories Of America 2009 ACM WORKSHOP ON CLOUD COMPUTING SECURITY (CCSW 2009) Presented By Talal Basaif CAP that will arise later · New directions to solve some issues #12;INTRODUCTION · Cloud computing is one of desirable

  18. Towards a Ubiquitous Cloud Computing Infrastructure

    E-Print Network [OSTI]

    van der Merwe, Kobus

    Towards a Ubiquitous Cloud Computing Infrastructure Jacobus Van der Merwe, K.K. Ramakrishnan of a number of cloud computing use cases. We specifically consider cloudbursting and follow-the-sun and focus that are also network service providers. I. INTRODUCTION Cloud computing is rapidly gaining acceptance

  19. Cloud Computing: Legal Issues in Centralized Architectures

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Cloud Computing: Legal Issues in Centralized Architectures Primavera DE FILIPPI1 , Smari McCARTHY2, Reykjavik, 101, Iceland - Email: smari@gmail.com Abstract: Cloud computing can be defined as the provision they can access their data and the extent to which parties can exploit it. Keywords: Cloud Computing

  20. Heat Recovery in Distillation by Mechanical Vapor Recompression

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    tower energy requirements can be achieved by mechanical vapor recompression. Three design approaches for heating a distillation tower reboiler by mechanical vapor recompression are presented. The advantages of using a screw compressor are discussed... for lowering energy consumption in the distillation process through various heat recovery techniques. (3-8) One such technique utilizes mechanical vapor recompression. (9-12) The principle of this ap proach involves the use of a compressor to recycle...