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Sample records for water quality surface

  1. Water Quality Surface and Ground | Open Energy Information

    Open Energy Info (EERE)

    Water Quality Surface and Ground Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleWaterQualitySurfaceandGround&oldid612197" Feedback...

  2. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface...

  3. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface ...

  4. Texas Surface Water Quality Standards Webpage | Open Energy Informatio...

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Texas Surface Water Quality Standards Webpage Citation Texas Commission on...

  5. New Mexico Surface Water Quality Bureau Federal Dredge and Fill...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: New Mexico Surface Water Quality Bureau Federal Dredge and Fill Permits webpage Author New Mexico...

  6. WAC - 173-210A Water Quality Standards for Surface Waters of...

    Open Energy Info (EERE)

    0A Water Quality Standards for Surface Waters of the State of Washington Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation:...

  7. UMTRA project technical assistance contractor quality assurance implementation plan for surface and ground water

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The Uranium Mill Tailings Remedial Action (UMTRA) Project Technical Assistance Contractor (TAC) Quality Assurance Implementation Plan (QAIP) outlines the primary requirements for integrating quality functions for TAC technical activities applied to the surface and ground water phases of the UMTRA Project. The QAIP is subordinate to the latest issue of the UMTRA Project TAC Quality Assurance Program Plan (QAPP). The QAIP addresses technical aspects of the TAC UMTRA Project surface and ground water programs. The QAIP is authorized and approved by the TAC Project Manager and QA manager. The QA program is designed to use monitoring, audit, and surveillance functions as management tools to ensure that all Project organization activities are carried out in a manner that will protect public health and safety, promote the success of the UMTRA Project and meet or exceed contract requirements.

  8. UMTRA project technical assistance contractor quality assurance implementation plan for surface and ground water, Revision 2

    SciTech Connect (OSTI)

    1995-11-01

    This document contains the Technical Assistance Contractor (TAC) Quality Assurance Implementation Plan (QAIP) for the Uranium Mill Tailings Remedial Action (UMTRA) Project. The QAIP outlines the primary requirements for integrating quality functions for TAC technical activities applied to the surface and ground water phases of the UMTRA Project. The QA program is designed to use monitoring, audit, and surveillance activities as management tools to ensure that UMTRA Project activities are carried out in amanner to protect public health and safety, promote the success of the UMTRA Project, and meet or exceed contract requirements.

  9. Forecasting Water Quality & Biodiversity

    Broader source: Energy.gov (indexed) [DOE]

    Forecasting Water Quality & Biodiversity March 25, 2015 Cross-cutting Sustainability ... that measure feedstock production, water quality, water quantity, and biodiversity. ...

  10. Purified water quality study

    SciTech Connect (OSTI)

    Spinka, H.; Jackowski, P.

    2000-04-03

    Argonne National Laboratory (HEP) is examining the use of purified water for the detection medium in cosmic ray sensors. These sensors are to be deployed in a remote location in Argentina. The purpose of this study is to provide information and preliminary analysis of available water treatment options and associated costs. This information, along with the technical requirements of the sensors, will allow the project team to determine the required water quality to meet the overall project goals.

  11. Vermont Section 401 Water Quality Certification Application ...

    Open Energy Info (EERE)

    Abstract Application required for Section 401 water quality certification under the Clean Water Act. Form Type ApplicationNotice Form Topic Section 401 Water Quality...

  12. Clean Water Act Section 401 Water Quality Certification: A Water...

    Open Energy Info (EERE)

    Certification: A Water Quality Protection Tool for States and Tribes Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Guide...

  13. Clean Water Act Section 401 Water Quality Certification A Water...

    Open Energy Info (EERE)

    Certification A Water Quality Protection Tool for States and Tribes Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Guide...

  14. Vermont Water Quality Certification Application for Hydroelectric...

    Open Energy Info (EERE)

    Water Quality Certification Application for Hydroelectric Facilities Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Vermont Water Quality Certification...

  15. Vermont Water Quality Standards | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library General: Vermont Water Quality Standards Abstract Vermont 401 Water Quality Certification Policy Guidance for...

  16. Alaska Water Quality Standards | Open Energy Information

    Open Energy Info (EERE)

    Water Quality Standards Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: Alaska Water Quality...

  17. California State Water Resources Control Board 401 Water Quality...

    Open Energy Info (EERE)

    401 Water Quality Certification Website Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: California State Water Resources Control Board 401 Water...

  18. SWQM: Source Water Quality Modeling Software

    Energy Science and Technology Software Center (OSTI)

    2008-01-08

    The Source Water Quality Modeling software (SWQM) simulates the water quality conditions that reflect properties of water generated by water treatment facilities. SWQM consists of a set of Matlab scripts that model the statistical variation that is expected in a water treatment facility’s water, such as pH and chlorine levels.

  19. Appendix D Surface Water and Ground Water Time-Concentration...

    Office of Legacy Management (LM)

    Surface Water and Ground Water Time-Concentration Plots, Stream Discharge Measurements, Ground Water Level Data, and Ground Water Well Hydrographs This page intentionally left ...

  20. ADEQ Water Quality Forms | Open Energy Information

    Open Energy Info (EERE)

    ADEQ Water Quality Forms Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: ADEQ Water Quality FormsLegal Abstract The Arizona...

  1. Colorado Water Quality Certification General Information | Open...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Colorado Water Quality Certification General InformationLegal Abstract The Colorado Department of...

  2. Montana Water Quality Permit Application, Nondegradation Authorization...

    Open Energy Info (EERE)

    Water Quality Permit Application, Nondegradation Authorization, and Permit Fees Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance -...

  3. Oregon Water Quality Permit Program (Stormwater - Industrial...

    Open Energy Info (EERE)

    Activities) Website Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Oregon Water Quality Permit Program (Stormwater - Industrial Activities) Website...

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data ...

  5. Industry disagrees with water quality recommendations

    SciTech Connect (OSTI)

    Begley, R.

    1992-11-25

    Industry groups are distancing themselves from recommendations on cleaning up the nation's waters issued by Water Quality 2000, a coalition of more than 80 organizations representing industry, environmental groups, government, academia, and professional and scientific societies. The report, [open quotes]A National Water Agenda for the 21st Century[close quotes], is a result of work begun in 1989. It recommends an approach to water quality that emphasizes pollution prevention, increased individual and collective responsibility for protecting water resources, and reorienting water resource programs and institutions along natural, rather than political, watershed boundaries. It includes 85 specific recommendations, many of which are to be implemented locally. The Natural Resources Defense Council (NRDC; Washington) [open quotes]wholeheartedly endorses not only the specific solutions offered today but the process by which these proposals were reached,[close quotes] says Robert W. Adler, NRDC senior attorney and vice chairman of Water Quality 2000. John B. Coleman, corporate environmental affairs manager for Du Pont and a member of the groups's steering committee, says [open quotes]Du Pont and the other industry members of Water Quality 2000 are committed[close quotes] to working to make continuous improvements.

  6. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........9 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Static Water Level Data ...

  7. Water quality assessment in Ecuador

    SciTech Connect (OSTI)

    Chudy, J.P.; Arniella, E.; Gil, E.

    1993-02-01

    The El Tor cholera pandemic arrived in Ecuador in March 1991, and through the course of the year caused 46,320 cases, of which 692 resulted in death. Most of the cases were confined to cities along Ecuador's coast. The Water and Sanitation for Health Project (WASH), which was asked to participate in the review of this request, suggested that a more comprehensive approach should be taken to cholera control and prevention. The approach was accepted, and a multidisciplinary team consisting of a sanitary engineer, a hygiene education specialist, and an institutional specialist was scheduled to carry out the assessment in late 1992 following the national elections.

  8. WC 26 - Water Quality Control Administrative Provisions | Open...

    Open Energy Info (EERE)

    26 - Water Quality Control Administrative Provisions Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: WC 26 - Water Quality...

  9. RAPID/Geothermal/Water Quality/Alaska | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalWater QualityAlaska < RAPID | Geothermal | Water Quality Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About...

  10. Washington 401 Water Quality Certification JARPA Process | Open...

    Open Energy Info (EERE)

    401 Water Quality Certification JARPA Process Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Washington 401 Water Quality...

  11. Microsoft Word - S05072_WaterQualityComplStrategy.doc

    Office of Legacy Management (LM)

    Water Quality Compliance Strategy December 2009 LMSMNTS05072 This page intentionally left blank LMSMNTS05072 Monticello Mill Tailings Site Operable Unit III Water Quality ...

  12. EPA Section 401 Water Quality Certification Manual | Open Energy...

    Open Energy Info (EERE)

    Section 401 Water Quality Certification Manual Jump to: navigation, search OpenEI Reference LibraryAdd to library Reference: EPA Section 401 Water Quality Certification Manual...

  13. Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Details Activities (3) Areas (2) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Field...

  14. Impacts of Water Quality on Residential Water Heating Equipment

    SciTech Connect (OSTI)

    Widder, Sarah H.; Baechler, Michael C.

    2013-11-01

    Water heating is a ubiquitous energy use in all residential housing, accounting for 17.7% of residential energy use (EIA 2012). Today, there are many efficient water heating options available for every fuel type, from electric and gas to more unconventional fuel types like propane, solar, and fuel oil. Which water heating option is the best choice for a given household will depend on a number of factors, including average daily hot water use (total gallons per day), hot water draw patterns (close together or spread out), the hot water distribution system (compact or distributed), installation constraints (such as space, electrical service, or venting accommodations) and fuel-type availability and cost. While in general more efficient water heaters are more expensive than conventional water heating technologies, the savings in energy use and, thus, utility bills can recoup the additional upfront investment and make an efficient water heater a good investment over time in most situations, although the specific payback period for a given installation will vary widely. However, the expected lifetime of a water heater in a given installation can dramatically influence the cost effectiveness and savings potential of a water heater and should be considered, along with water use characteristics, fuel availability and cost, and specific home characteristics when selecting the optimum water heating equipment for a particular installation. This report provides recommendations for selecting and maintaining water heating equipment based on local water quality characteristics.

  15. Paraho environmental data. Part I. Process characterization. Par II. Air quality. Part III. Water quality

    SciTech Connect (OSTI)

    Heistand, R.N.; Atwood, R.A.; Richardson, K.L.

    1980-06-01

    From 1973 to 1978, Development Engineering, Inc. (DEI), a subsidiary of Paraho Development Corporation, demostrated the Paraho technology for surface oil shale retorting at Anvil Points, Colorado. A considerable amount of environmentally-related research was also conducted. This body of data represents the most comprehensive environmental data base relating to surface retorting that is currently available. In order to make this information available, the DOE Office of Environment has undertaken to compile, assemble, and publish this environmental data. The compilation has been prepared by DEI. This report includes the process characterization, air quality, and water quality categories.

  16. Utah Water Quality Standards Workgroup Website | Open Energy...

    Open Energy Info (EERE)

    Quality Standards Workgroup Website Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Utah Water Quality Standards Workgroup Website Abstract This...

  17. Vermont Agency of Natural Resources Section 401 Water Quality...

    Open Energy Info (EERE)

    document outlines the Agency of Natural Resources coordination process with respect to Clean Water Act Section 401 water quality certification decisions. Author Vermont...

  18. Porter-Cologne Water Quality Control Act | Open Energy Information

    Open Energy Info (EERE)

    Porter-Cologne Water Quality Control Act Jump to: navigation, search OpenEI Reference LibraryAdd to library Reference: Porter-Cologne Water Quality Control Act Published Publisher...

  19. Hawaii Water Quality Certification Form | Open Energy Information

    Open Energy Info (EERE)

    Water Quality Certification Form Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Hawaii Water Quality Certification Form Form Type ApplicationNotice Form...

  20. Colorado Water Quality Control Act | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Colorado Water Quality Control ActLegal Abstract Statute setting forth laws for water quality control...

  1. Regional Water Quality Control Boards | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Regional Water Quality Control BoardsLegal Abstract California Regional Water Quality Control Boards,...

  2. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........3 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Natural Gas Analysis Data ...

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Time-Concentration Graph ...

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........3 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Time-Concentration Graphs ...

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........7 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data Static ...

  6. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data Static ...

  7. Geothermal Power Plants — Meeting Water Quality and Conservation Standards

    Office of Energy Efficiency and Renewable Energy (EERE)

    U.S. geothermal power plants can easily meet federal, state, and local water quality and conservation standards.

  8. Effects on the Physical Environment (Hydrodynamics, and Water Quality Food

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Web) | Department of Energy and Water Quality Food Web) Effects on the Physical Environment (Hydrodynamics, and Water Quality Food Web) Effects on the Physical Environment (Hydrodynamics, and Water Quality Food Web) 57_mhk_modeling.ppt (7.28 MB) More Documents & Publications Effects on the Physical Environment (Hydrodynamics, Sediment Transport, and Water Quality) Free Flow Energy (TRL 1 2 3 Component) - Design and Development of a Cross-Platform Submersible Generator Optimized for the

  9. RAPID/BulkTransmission/Water Quality | Open Energy Information

    Open Energy Info (EERE)

    Water Quality across multiple states Permitting Location State Nonpoint Source Pollution Process Nonpoint Source Pollution Agency State Discharge Elimination System...

  10. RAPID/Geothermal/Water Quality | Open Energy Information

    Open Energy Info (EERE)

    Water Quality across multiple states Permitting Location State Nonpoint Source Pollution Process Nonpoint Source Pollution Agency State Discharge Elimination System...

  11. Preliminary Analysis of Surface Radiation Measurement Data Quality...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Radiation Measurement Data Quality at the SGP Extended Facilities Y. Shi and C. N. ... Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Program operates ...

  12. Category:Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Surface Water Sampling page? For detailed information on...

  13. Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions...

    Office of Science (SC) Website

    Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions that Store Sunlight as ... Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions that Store Sunlight as ...

  14. Improved Design Tools for Surface Water and Standing Column Well...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems This project ...

  15. Ecological Screening Values for Surface Water, Sediment, and...

    Office of Scientific and Technical Information (OSTI)

    Ecological Screening Values for Surface Water, Sediment, and Soil Friday, G. P. 54 ENVIRONMENTAL SCIENCES; SOILS; SURFACE WATERS; SEDIMENTS; ECOLOGICAL CONCENTRATION; ENVIRONMENTAL...

  16. Ecological Screening Values for Surface Water, Sediment, and...

    Office of Scientific and Technical Information (OSTI)

    Ecological Screening Values for Surface Water, Sediment, and Soil Citation Details In-Document Search Title: Ecological Screening Values for Surface Water, Sediment, and Soil ...

  17. ARM: Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shi, Yan; Riihimaki, Laura

    1994-01-07

    Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

  18. August 2015 Groundwater and Surface Water Sampling at the Tuba...

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2015 LMSTUB.........7 Water Sampling Field Activities Verification ...

  19. February 2016 Groundwater and Surface Water Sampling at the Tuba...

    Office of Legacy Management (LM)

    6 Groundwater and Surface Water Sampling at the Tuba City, Arizona, Disposal Site April .........5 Water Sampling Field Activities Verification ...

  20. WDEQ-Water Quality Division | Open Energy Information

    Open Energy Info (EERE)

    Quality Division Jump to: navigation, search Name: WDEQ-Water Quality Division Abbreviation: WDEQ WQD Address: 122 West 25th Street 3W Place: Cheyenne, Wyoming Zip: 82002 Phone...

  1. EPA 401 Water Quality Certification website | Open Energy Information

    Open Energy Info (EERE)

    OtherOther: EPA 401 Water Quality Certification websiteLegal Abstract The United States Environmental Protection Agency (EPA) provides various information and resources related...

  2. EPA Handbook on 401 Water Quality Certifications | Open Energy...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: EPA Handbook on 401 Water Quality CertificationsPermittingRegulatory...

  3. Utah Division of Water Quality | Open Energy Information

    Open Energy Info (EERE)

    Ground Water Quality Protection Permitting Contact 2 Contacts.png Woody Campbell http:www.waterquality.utah.gov Retrieved from "http:en.openei.orgw...

  4. Montana 401 Water Quality Certification Webpage | Open Energy...

    Open Energy Info (EERE)

    Certification Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana 401 Water Quality Certification Webpage Abstract Contains information on...

  5. Oregon Water Quality Permit Program (Stormwater Discharge Permits...

    Open Energy Info (EERE)

    Permits) Website Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Oregon Water Quality Permit Program (Stormwater Discharge Permits) Website...

  6. Vermont Section 401 Water Quality Certification Program | Open...

    Open Energy Info (EERE)

    navigation, search OpenEI Reference LibraryAdd to library Web Site: Vermont Section 401 Water Quality Certification Program Abstract Vermont Agency of Natural Resource's...

  7. Vermont Application for Individual Section 401 Water Quality...

    Open Energy Info (EERE)

    Application for Individual Section 401 Water Quality Certification Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Vermont Application for Individual...

  8. WSDE 401 Water Quality Certification webpage | Open Energy Information

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for WSDE 401 Water Quality Certification webpage Citation Washington State...

  9. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE...

    Office of Scientific and Technical Information (OSTI)

    data, and corrosion information, (2) a web site capable of displaying produced water ... New Mexico. (2) Creation of a web-based data entry system for the water quality database. ...

  10. Water quality assessment of the Rio Conchos, Chihuahua, Mexico

    SciTech Connect (OSTI)

    Gutierrez, M.; Borrego, P.

    1999-07-01

    A baseline study was conducted to evaluate the overall quality of the Rio Conchos (Chihuahua, Mexico) and to identify those chemical parameters that can best represent the water quality in different segments of the river. Chemical analyses included the measurement of 62 elements at more than 100 sampling stations along the river, in addition to conventional field analyses (e.g., pH, conductivity). Concentrations of these elements are reported and water quality indicators were identified. Based on the element concentration patterns, the segment of the river in which the water quality is most endangered corresponds to that receiving irrigation drain returns near the confluence of the Rio San Pedro. Self-cleaning and dilution processes account for the improvement in water quality observed as the Rio Conchos approaches the Rio Grande.

  11. 23 CCR 3855 et seq. - Water Quality Certification | Open Energy...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 23 CCR 3855 et seq. - Water Quality CertificationLegal Published NA Year Signed or Took...

  12. Montana 2012 Final Water Quality Integrated Report: Appendix...

    Open Energy Info (EERE)

    Appendix A Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Montana 2012 Final Water Quality Integrated Report: Appendix A Abstract Index for impaired...

  13. Montana 2012 Final Water Quality Integrated Report | Open Energy...

    Open Energy Info (EERE)

    Report Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Montana 2012 Final Water Quality Integrated Report Abstract Provides an overview of sources of...

  14. ADEQ 401 Water Quality Forms | Open Energy Information

    Open Energy Info (EERE)

    ADEQ 401 Water Quality FormsLegal Published NA Year Signed or Took Effect 2012 Legal Citation Not provided DOI Not Provided Check for DOI availability: http:crossref.org Online...

  15. ARM 17-30 - Water Quality | Open Energy Information

    Open Energy Info (EERE)

    Water quality regulations. Published NA Year Signed or Took Effect 1980 Legal Citation ARM 17.30 (1980) DOI Not Provided Check for DOI availability: http:crossref.org...

  16. Title 18 Alaska Administrative Code Chapter 70 Water Quality...

    Open Energy Info (EERE)

    0 Water Quality Standards Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: Title 18 Alaska Administrative Code Chapter 70...

  17. Geothermal Direct-Use — Meeting Water Quality Standards

    Broader source: Energy.gov [DOE]

    Geothermal direct-use applications—such as greenhouses, district and space heating, and aquaculture—can easily meet local and federal water quality standards, which help protect our environment.

  18. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........9 Water Sampling Field Activities Verification ... Data Durango Processing Site Surface Water Quality Data Equipment Blank Data Static ...

  19. Surface engineering of the quality factor of metal coated microcantilevers

    SciTech Connect (OSTI)

    Ergincan, O.; Kooi, B. J.; Palasantzas, G.

    2014-12-14

    We performed noise measurements to obtain the quality factor (Q) and frequency shift of gold coated microcantilevers before and after surface modification using focused ion beam. As a result of our studies, it is demonstrated that surface engineering offers a promising method to control and increase the Q factor up to 50% for operation in vacuum. Surface modification could also lead to deviations from the known Q ∼ P{sup −1} behavior at low vacuum pressures P within the molecular regime. Finally, at higher pressures within the continuum regime, where Q is less sensitive to surface changes, a power scaling Q ∼ P{sup c} with c ≈ 0.3 was found instead of c = 0.5. The latter is explained via a semi-empirical formulation to account for continuum dissipation mechanisms at significant Reynolds numbers Re ∼ 1.

  20. Surface Water Sampling At Raft River Geothermal Area (1973) ...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Raft River Geothermal Area (1973) Exploration Activity Details Location...

  1. Surface Water Sampling At Chena Geothermal Area (Holdmann, Et...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Chena Geothermal Area (Holdmann, Et Al., 2006) Exploration Activity...

  2. Montana Surface Water Application for Beneficial Use (DNRC Form...

    Open Energy Info (EERE)

    for Beneficial Use (DNRC Form 600 GW) Citation Montana Department of Natural Resources & Conservation. Form: Montana Surface Water Application for Beneficial Use (DNRC Form 600...

  3. Montana Surface Water Application for Beneficial Use (DNRC Form...

    Open Energy Info (EERE)

    Beneficial Use (DNRC Form 600 SW) Citation Montana Department of Natural Resources and Conservation. Form: Montana Surface Water Application for Beneficial Use (DNRC Form 600...

  4. Structure of water adsorbed on a mica surface

    SciTech Connect (OSTI)

    Park, Sung-Ho; Sposito, Garrison

    2002-01-29

    Monte Carlo simulations of hydration water on the mica (001) surface under ambient conditions revealed water molecules bound closely to the ditrigonal cavities in the surface, with a lateral distribution of approximately one per cavity, and water molecules interposed between K{sup +} counter ions in a layer situated about 2.5 {angstrom} from a surface O along a direction normal to the (001) plane. The calculated water O density profile was in quantitative agreement with recent X-ray reflectivity measurements indicating strong lateral ordering of the hydration water but liquid-like disorder otherwise.

  5. Role of surface characteristics in urban meteorology and air quality

    SciTech Connect (OSTI)

    Sailor, D.J.

    1993-08-01

    Urbanization results in a landscape with significantly modified surface characteristics. The lower values of reflectivity to solar radiation, surface moisture availability, and vegetative cover, along with the higher values of anthropogenic heat release and surface roughness combine to result higher air temperatures in urban areas relative to their rural counterparts. Through their role in the surface energy balance and surface exchange processes, these surface characteristics are capable of modifying the local meteorology. The impacts on wind speeds, air temperatures, and mixing heights are of particular importance, as they have significant implications in terms of urban energy use and air quality. This research presents several major improvements to the meteorological modeling methodology for highly heterogeneous terrain. A land-use data-base is implemented to provide accurate specification of surface characteristic variability in simulations of the Los Angeles Basin. Several vegetation parameterizations are developed and implemented, and a method for including anthropogenic heat release into the model physics is presented. These modeling advancements are then used in a series of three-dimensional simulations which were developed to investigate the potential meteorological impact of several mitigation strategies. Results indicate that application of moderate tree-planting and urban-lightening programs in Los Angeles may produce summertime air temperature reductions on the order of 4{degree}C with a concomitant reduction in air pollution. The analysis also reveals several mechanisms whereby the application of these mitigation strategies may potentially increase pollutant concentrations. The pollution and energy use consequences are discussed in detail.

  6. Method for quantifying the prediction uncertainties associated with water quality models

    SciTech Connect (OSTI)

    Summers, J.K.; Wilson, H.T.; Kou, J.

    1993-01-01

    Many environmental regulatory agencies depend on models to organize, understand, and utilize the information for regulatory decision making. A general analytical protocol was developed to quantify prediction error associated with commonly used surface water quality models. Its application is demonstrated by comparing water quality models configured to represent different levels of spatial, temporal, and mechanistic complexity. This comparison can be accomplished by fitting the models to a benchmark data set. Once the models are successfully fitted to the benchmark data, the prediction errors associated with each application can be quantified using the Monte Carlo simulation techniques.

  7. South Asia transboundary water quality monitoring workshop summary report.

    SciTech Connect (OSTI)

    Betsill, Jeffrey David; Littlefield, Adriane C.; Luetters, Frederick O.; Rajen, Gaurav

    2003-04-01

    The Cooperative Monitoring Center (CMC) promotes collaborations among scientists and researchers in several regions as a means of achieving common regional security objectives. To promote cooperation in South Asia on environmental research, an international working group made up of participants from Bangladesh, India, Nepal, Pakistan, and the United States convened in Kathmandu, Nepal, from February 17-23,2002. The workshop was held to further develop the South Asia Transboundary Water Quality Monitoring (SATWQM) project. The project is sponsored in part by the CMC located at Sandia National Laboratories in Albuquerque, New Mexico through funding provided by the US. Department of State, Regional Environmental Affairs Office, American Embassy, Kathmandu, Nepal, and the National Nuclear Security Administration's (NNSA) Office of Nonproliferation and National Security. This report summarizes the SATWQM project, the workshop objectives, process and results. The long-term interests of the participants are to develop systems for sharing regional environmental information as a means of building confidence and improving relations among South Asian countries. The more immediate interests of the group are focused on activities that foster regional sharing of water quality data in the Ganges and Indus River basins. Issues of concern to the SATWQM network participants include studying the impacts from untreated sewage and industrial effluents, agricultural run-off, salinity increases in fresh waters, the siltation and shifting of river channels, and the environmental degradation of critical habitats such as wetlands, protected forests, and endangered aquatic species conservation areas. The workshop focused on five objectives: (1) a deepened understanding of the partner organizations involved; (2) garnering the support of additional regional and national government and non-government organizations in South Asia involved in river water quality monitoring; (3) identification of

  8. Integration of remote sensing and geographic information systems for Great Lakes water quality monitoring

    SciTech Connect (OSTI)

    Lathrop, R.G. Jr.

    1988-01-01

    The utility of three operational satellite remote sensing systems, namely, the Landsat Thematic Mapper (TM), the SPOT High Resolution Visible (HRV) sensors and the NOAA Advanced Very High Resolution Radiometer (AVHRR), were evaluated as a means of estimating water quality and surface temperature. Empirical calibration through linear regression techniques was used to relate near-simultaneously acquired satellite radiance/reflectance data and water quality observations obtained in Green Bay and the nearshore waters of Lake Michigan. Four dates of TM and one date each of SPOT and AVHRR imagery/surface reference data were acquired and analyzed. Highly significant relationships were identified between the TM and SPOT data and secchi disk depth, nephelometric turbidity, chlorophyll a, total suspended solids (TSS), absorbance, and surface temperature (TM only). The AVHRR data were not analyzed independently but were used for comparison with the TM data. Calibrated water quality image maps were input to a PC-based raster GIS package, EPPL7. Pattern interpretation and spatial analysis techniques were used to document the circulation dynamics and model mixing processes in Green Bay. A GIS facilitates the retrieval, query and spatial analysis of mapped information and provides the framework for an integrated operational monitoring system for the Great Lakes.

  9. Surface water supply for the Clearlake, California Hot Dry Rock Geothermal Project

    SciTech Connect (OSTI)

    Jager, A.R.

    1996-03-01

    It is proposed to construct a demonstration Hot Dry Rock (HDR) geothermal plant in the vicinity of the City of Clearlake. An interim evaluation has been made of the availability of surface water to supply the plant. The evaluation has required consideration of the likely water consumption of such a plant. It has also required consideration of population, land, and water uses in the drainage basins adjacent to Clear Lake, where the HDR demonstration project is likely to be located. Five sources were identified that appear to be able to supply water of suitable quality in adequate quantity for initial filling of the reservoir, and on a continuing basis, as makeup for water losses during operation. Those sources are California Cities Water Company, a municipal supplier to the City of Clearlake; Clear Lake, controlled by Yolo County Flood Control and Water Conservation District; Borax Lake, controlled by a local developer; Southeast Regional Wastewater Treatment Plant, controlled by Lake County; and wells, ponds, and streams on private land. The evaluation involved the water uses, water rights, stream flows, precipitation, evaporation, a water balance, and water quality. In spite of California`s prolonged drought, the interim conclusion is that adequate water is available at a reasonable cost to supply the proposed HDR demonstration project.

  10. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    SciTech Connect (OSTI)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung; Naomi Davidson; Ajeet Kumar Reddy; Mingzhen Wei

    2003-04-01

    The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information, (2) a web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries, (3) a fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water, and (4) a corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project has been focused on creating the water quality databases for produced water and surface water, along with collection of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 4000 entries for southeast New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the

  11. Relationship of regional water quality to aquifer thermal energy storage

    SciTech Connect (OSTI)

    Allen, R.D.

    1983-11-01

    Ground-water quality and associated geologic characteristics may affect the feasibility of aquifer thermal energy storage (ATES) system development in any hydrologic region. This study sought to determine the relationship between ground-water quality parameters and the regional potential for ATES system development. Information was collected from available literature to identify chemical and physical mechanisms that could adversely affect an ATES system. Appropriate beneficiation techniques to counter these potential geochemical and lithologic problems were also identified through the literature search. Regional hydrology summaries and other sources were used in reviewing aquifers of 19 drainage regions in the US to determine generic geochemical characteristics for analysis. Numerical modeling techniques were used to perform geochemical analyses of water quality from 67 selected aquifers. Candidate water resources regions were then identified for exploration and development of ATES. This study identified six principal mechanisms by which ATES reservoir permeability may be impaired: (1) particulate plugging, (2) chemical precipitation, (3) liquid-solid reactions, (4) formation disaggregation, (5) oxidation reactions, and (6) biological activity. Specific proven countermeasures to reduce or eliminate these effects were found. Of the hydrologic regions reviewed, 10 were identified as having the characteristics necessary for ATES development: (1) Mid-Atlantic, (2) South-Atlantic Gulf, (3) Ohio, (4) Upper Mississippi, (5) Lower Mississippi, (6) Souris-Red-Rainy, (7) Missouri Basin, (8) Arkansas-White-Red, (9) Texas-Gulf, and (10) California.

  12. EA-1093: Surface Water Drainage System, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to correct deficiencies in, and then to maintain, the surface water drainage system serving the U.S. Department of Energy's Rocky Flats...

  13. Nano-Cone Textures Generate Extremely "Robust" Water- Repellant Surfaces

    SciTech Connect (OSTI)

    2013-10-30

    High-speed video of water droplets bouncing off a surface textured with nanocones.The scientists filmed the droplets using a camera capable of capturing 30,000 frames per second.

  14. Hawaii Application for Surface Water Use Permit for Proposed...

    Open Energy Info (EERE)

    for Proposed New Use in a Designated Surface Water Management Area (DLNR Form SWUPA-N) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Hawaii...

  15. Fermilab | Tritium at Fermilab | Tritium in Surface Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Water Fermilab map Fermilab has conducted an environmental monitoring program on site for roughly 40 years. In November of 2005, for the first time, we detected low levels of tritium in Indian Creek, one of three creeks that travel through the Fermilab site. Low but measurable levels of tritium continue to be detected in Indian Creek. All tritium levels found on site are well below any federal health and environmental standards. The Department of Energy standard for surface water is

  16. Coastal water quality from remote sensing and GIS. A case study on South West Sardinia (Italy)

    SciTech Connect (OSTI)

    Poli, U.; Ippoliti, M.; Venturini, C.; Falcone, P.; Marino, A.

    1997-08-01

    In this paper the application of remote sensing image processing and GIS techniques in monitoring and managing coastal areas is proposed. The methodology has been applied to South-West Sardinia Coast where the environment is endangered by industrial plants and other human activities. The area is characterized by the presence of many submarine springs aligned along coastal cliffs. Water quality parameters (chlorophyll, suspended sediments and temperature) spatial and temporal variations, have been studied using Landsat TM images. Particularly, in this paper are reported the results referred to sea surface thermal gradients, considered as one of the main water quality index. Thermal gradients have been mapped in order to outline water circulation, thermal pollution and presence and distribution of submarine springs. Furthermore, a GIS approach of relating mono and multitemporal TM data with ground referenced information on industrial plants characteristics and distribution has been applied.

  17. An alternative approach to achieving water quality-based limits

    SciTech Connect (OSTI)

    Hart, C.M.; Graeser, W.C.

    1995-12-01

    Since May 1982, members of the Iron and Steel Industry have been required to meet effluent limits based on Best Available Technology (BAT) for a process water discharge to receiving stream. US Steel Clairton Works has been successful in meeting these limits in the last three years; however, the current regulatory thrust is toward more stringent limits based on water quality. In cases of smaller streams such as the receiving stream for Clairton Works` process outfall, these limits can be very rigid. This paper will discuss the alternative approaches investigated to meet the new more stringent limits including the solution chosen.

  18. Approaches to verification of two-dimensional water quality models

    SciTech Connect (OSTI)

    Butkus, S.R. . Water Quality Dept.)

    1990-11-01

    The verification of a water quality model is the one procedure most needed by decision making evaluating a model predictions, but is often not adequate or done at all. The results of a properly conducted verification provide the decision makers with an estimate of the uncertainty associated with model predictions. Several statistical tests are available for quantifying of the performance of a model. Six methods of verification were evaluated using an application of the BETTER two-dimensional water quality model for Chickamauga reservoir. Model predictions for ten state variables were compared to observed conditions from 1989. Spatial distributions of the verification measures showed the model predictions were generally adequate, except at a few specific locations in the reservoir. The most useful statistics were the mean standard error of the residuals. Quantifiable measures of model performance should be calculated during calibration and verification of future applications of the BETTER model. 25 refs., 5 figs., 7 tabs.

  19. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    SciTech Connect (OSTI)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung

    2003-09-24

    The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) Databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information. (2) A web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries. (3) A fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water. (4) A corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project was focused on creating the water quality databases for produced water and surface water, along with collecting of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 7000 entries for New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the accuracy and speed

  20. An Ontology Design Pattern for Surface Water Features

    SciTech Connect (OSTI)

    Sinha, Gaurav; Mark, David; Kolas, Dave; Varanka, Dalia; Romero, Boleslo E; Feng, Chen-Chieh; Usery, Lynn; Liebermann, Joshua; Sorokine, Alexandre

    2014-01-01

    Surface water is a primary concept of human experience but concepts are captured in cultures and languages in many different ways. Still, many commonalities can be found due to the physical basis of many of the properties and categories. An abstract ontology of surface water features based only on those physical properties of landscape features has the best potential for serving as a foundational domain ontology. It can then be used to systematically incor-porate concepts that are specific to a culture, language, or scientific domain. The Surface Water ontology design pattern was developed both for domain knowledge distillation and to serve as a conceptual building-block for more complex surface water ontologies. A fundamental distinction is made in this on-tology between landscape features that act as containers (e.g., stream channels, basins) and the bodies of water (e.g., rivers, lakes) that occupy those containers. Concave (container) landforms semantics are specified in a Dry module and the semantics of contained bodies of water in a Wet module. The pattern is imple-mented in OWL, but Description Logic axioms and a detailed explanation is provided. The OWL ontology will be an important contribution to Semantic Web vocabulary for annotating surface water feature datasets. A discussion about why there is a need to complement the pattern with other ontologies, es-pecially the previously developed Surface Network pattern is also provided. Fi-nally, the practical value of the pattern in semantic querying of surface water datasets is illustrated through a few queries and annotated geospatial datasets.

  1. Real-Time Water Quality Management in the Grassland Water District

    SciTech Connect (OSTI)

    Quinn, Nigel W.T.; Hanna, W. Mark; Hanlon, Jeremy S.; Burns, Josphine R.; Taylor, Christophe M.; Marciochi, Don; Lower, Scott; Woodruff, Veronica; Wright, Diane; Poole, Tim

    2004-12-10

    The purpose of the research project was to advance the concept of real-time water quality management in the San Joaquin Basin by developing an application to drainage of seasonal wetlands in the Grassland Water District. Real-time water quality management is defined as the coordination of reservoir releases, return flows and river diversions to improve water quality conditions in the San Joaquin River and ensure compliance with State water quality objectives. Real-time water quality management is achieved through information exchange and cooperation between shakeholders who contribute or withdraw flow and salt load to or from the San Joaquin River. This project complements a larger scale project that was undertaken by members of the Water Quality Subcommittee of the San Joaquin River Management Program (SJRMP) and which produced forecasts of flow, salt load and San Joaquin River assimilative capacity between 1999 and 2003. These forecasts can help those entities exporting salt load to the River to develop salt load targets as a mechanism for improving compliance with salinity objectives. The mass balance model developed by this project is the decision support tool that helps to establish these salt load targets. A second important outcome of this project was the development and application of a methodology for assessing potential impacts of real-time wetland salinity management. Drawdown schedules are typically tied to weather conditions and are optimized in traditional practices to maximize food sources for over-wintering wildfowl as well as providing a biological control (through germination temperature) of undesirable weeds that compete with the more proteinaceous moist soil plants such as swamp timothy, watergrass and smartweed. This methodology combines high resolution remote sensing, ground-truthing vegetation surveys using established survey protocols and soil salinity mapping using rapid, automated electromagnetic sensor technology. This survey methodology

  2. Properties of water surface discharge at different pulse repetition rates

    SciTech Connect (OSTI)

    Ruma,; Yoshihara, K.; Hosseini, S. H. R. Sakugawa, T.; Akiyama, H.; Akiyama, M.; Lukeš, P.

    2014-09-28

    The properties of water surface discharge plasma for variety of pulse repetition rates are investigated. A magnetic pulse compression (MPC) pulsed power modulator able to deliver pulse repetition rates up to 1000 Hz, with 0.5 J per pulse energy output at 25 kV, was used as the pulsed power source. Positive pulse with a point-to-plane electrode configuration was used for the experiments. The concentration and production yield of hydrogen peroxide (H₂O₂) were quantitatively measured and orange II organic dye was treated, to evaluate the chemical properties of the discharge reactor. Experimental results show that the physical and chemical properties of water surface discharge are not influenced by pulse repetition rate, very different from those observed for under water discharge. The production yield of H₂O₂ and degradation rate per pulse of the dye did not significantly vary at different pulse repetition rates under a constant discharge mode on water surface. In addition, the solution temperature, pH, and conductivity for both water surface and underwater discharge reactors were measured to compare their plasma properties for different pulse repetition rates. The results confirm that surface discharge can be employed at high pulse repetition rates as a reliable and advantageous method for industrial and environmental decontamination applications.

  3. File:06MTFShortTermWaterQualityStandardForTurbidity318Authorization...

    Open Energy Info (EERE)

    MTFShortTermWaterQualityStandardForTurbidity318Authorization.pdf Jump to: navigation, search File File history File usage Metadata File:06MTFShortTermWaterQualityStandardForTurbidi...

  4. File:Colorado Water Quality Control Act.pdf | Open Energy Information

    Open Energy Info (EERE)

    Colorado Water Quality Control Act.pdf Jump to: navigation, search File File history File usage Metadata File:Colorado Water Quality Control Act.pdf Size of this preview: 463 ...

  5. ARS Title 49-200 Water Quality Control | Open Energy Information

    Open Energy Info (EERE)

    -200 Water Quality Control Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS Title 49-200 Water Quality ControlLegal Abstract...

  6. ARM 17-30-101 - Water Quality: 401 Certification | Open Energy...

    Open Energy Info (EERE)

    30-101 - Water Quality: 401 Certification Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: ARM 17-30-101 - Water Quality:...

  7. U.A.C. R317-6: Ground Water Quality Protection | Open Energy...

    Open Energy Info (EERE)

    6: Ground Water Quality Protection Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: U.A.C. R317-6: Ground Water Quality...

  8. A.A.C. R18-11: Water Quality Standards | Open Energy Information

    Open Energy Info (EERE)

    C. R18-11: Water Quality Standards Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: A.A.C. R18-11: Water Quality...

  9. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small moleculesilica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (?hads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 3.1 kJ/mol water) and ethanol (-78.0 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing watersilica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  10. Puget Sound Dissolved Oxygen Modeling Study: Development of an Intermediate Scale Water Quality Model

    SciTech Connect (OSTI)

    Khangaonkar, Tarang; Sackmann, Brandon S.; Long, Wen; Mohamedali, Teizeen; Roberts, Mindy

    2012-10-01

    The Salish Sea, including Puget Sound, is a large estuarine system bounded by over seven thousand miles of complex shorelines, consists of several subbasins and many large inlets with distinct properties of their own. Pacific Ocean water enters Puget Sound through the Strait of Juan de Fuca at depth over the Admiralty Inlet sill. Ocean water mixed with freshwater discharges from runoff, rivers, and wastewater outfalls exits Puget Sound through the brackish surface outflow layer. Nutrient pollution is considered one of the largest threats to Puget Sound. There is considerable interest in understanding the effect of nutrient loads on the water quality and ecological health of Puget Sound in particular and the Salish Sea as a whole. The Washington State Department of Ecology (Ecology) contracted with Pacific Northwest National Laboratory (PNNL) to develop a coupled hydrodynamic and water quality model. The water quality model simulates algae growth, dissolved oxygen, (DO) and nutrient dynamics in Puget Sound to inform potential Puget Sound-wide nutrient management strategies. Specifically, the project is expected to help determine 1) if current and potential future nitrogen loadings from point and non-point sources are significantly impairing water quality at a large scale and 2) what level of nutrient reductions are necessary to reduce or control human impacts to DO levels in the sensitive areas. The project did not include any additional data collection but instead relied on currently available information. This report describes model development effort conducted during the period 2009 to 2012 under a U.S. Environmental Protection Agency (EPA) cooperative agreement with PNNL, Ecology, and the University of Washington awarded under the National Estuary Program

  11. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  12. Energy Landscape of Water and Ethanol on Silica Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reachingmore » its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.« less

  13. Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer

    SciTech Connect (OSTI)

    Jurss, Jonah W.; Concepcion, Javier C.; Norris, Michael R.; Templeton, Joseph L.; Meyer, Thomas J.

    2010-04-08

    Single-electron activation of multielectron catalysis has been shown to be viable in catalytic water oxidation with stepwise proton-coupled electron transfer, leading to high-energy catalytic precursors. For the blue dimer, cis,cis-[(bpy)2(H2O)RuIIIORuIII(H2O)(bpy)2]4+, the first well-defined molecular catalyst for water oxidation, stepwise 4e-/4H+ oxidation occurs to give the reactive precursor [(O)RuVORuV(O)]4+. This key intermediate is kinetically inaccessible at an unmodified metal oxide surface, where the only available redox pathway is electron transfer. We report here a remarkable surface activation of indium-tin oxide (In2O3:Sn) electrodes toward catalytic water oxidation by the blue dimer at electrodes derivatized by surface phosphonate binding of [Ru(4,4'-((HO)2P(O)CH2)2bpy)2(bpy)]2+. Surface binding dramatically improves the rate of surface oxidation of the blue dimer and induces water oxidation catalysis.

  14. Concentrations of 23 trace elements in ground water and surface water at and near the Idaho National Engineering Laboratory, Idaho, 1988--91

    SciTech Connect (OSTI)

    Liszewski, M.J.; Mann, L.J.

    1993-12-31

    Analytical data for 23 trace elements are reported for ground- and surface-water samples collected at and near the Idaho National Engineering Laboratory during 1988--91. Water samples were collected from 148 wells completed in the Snake River Plain aquifer, 18 wells completed in discontinuous deep perched-water zones, and 1 well completed in an alluvial aquifer. Surface-water samples also were collected from three streams, two springs, two ponds, and one lake. Data are categorized by concentrations of total recoverable of dissolved trace elements. Concentrations of total recoverable trace elements are reported for unfiltered water samples and include results for one or more of the following: aluminum, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel, selenium, silver, and zinc. Concentrations of dissolved trace elements are reported for water samples filtered through a nominal 0.45-micron filter and may also include bromide, fluoride, lithium, molybdenum, strontium, thallium, and vanadium. Concentrations of dissolved hexavalent chromium also are reported for many samples. The water samples were analyzed at the US Geological Survey`s National Water Quality Laboratory in Arvada, Colorado. Methods used to collect the water samples and quality assurance instituted for the sampling program are described. Concentrations of chromium equaled or exceeded the maximum contaminant level at 12 ground-water quality monitoring wells. Other trace elements did not exceed their respective maximum contaminant levels.

  15. Radiolysis Concerns for Water Shielding in Fission Surface Power Applications

    SciTech Connect (OSTI)

    Schoenfeld, Michael P.; Anghaie, Samim

    2008-01-21

    This paper presents an overview of radiolysis concerns with regard to water shields for fission surface power. A review of the radiolysis process is presented and key parameters and trends are identified. From this understanding of the radiolytic decomposition of water, shield pressurization and corrosion are identified as the primary concerns. Existing experimental and modeling data addressing concerns are summarized. It was found that radiolysis of pure water in a closed volume results in minimal, if any net decomposition, and therefore reduces the potential for shield pressurization and corrosion.

  16. Water and Carbon Dioxide Adsorption at Olivine Surfaces

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Bylaska, Eric J.; Felmy, Andrew R.

    2013-11-14

    Plane-wave density functional theory (DFT) calculations were performed to simulate water and carbon dioxide adsorption at the (010) surface of five olivine minerals, namely, forsterite (Mg2SiO4), calcio-olivine (Ca2SiO4), tephroite (Mn2SiO4), fayalite (Fe2SiO4), and Co-olivine (Co2SiO4). Adsorption energies per water molecule obtained from energy minimizations varied from -78 kJ mol-1 for fayalite to -128 kJ mol-1 for calcio-olivine at sub-monolayer coverage and became less exothermic as coverage increased. In contrast, carbon dioxide adsorption energies at sub-monolayer coverage ranged from -20 kJ mol-1 for fayalite to -59 kJ mol-1 for calcio-olivine. Therefore, the DFT calculations show a strong driving force for carbon dioxide displacement by water at the surface of all olivine minerals in a competitive adsorption scenario. Additionally, adsorption energies for both water and carbon dioxide were found to be more exothermic for the alkaline-earth (AE) olivines than for the transition-metal (TM) olivines and to not correlate with the solvation enthalpies of the corresponding divalent cations. However, a correlation was obtained with the charge of the surface divalent cation indicating that the more ionic character of the AE cations in the olivine structure relative to the TM cations leads to greater interactions with adsorbed water and carbon dioxide molecules at the surface and thus more exothermic adsorption energies for the AE olivines. For calcio-olivine, which exhibits the highest divalent cation charge of the five olivines, ab initio molecular dynamics simulations showed that this effect leads both water and carbon dioxide to react with the surface and form hydroxyl groups and a carbonate-like species, respectively.

  17. Surface Water Data at Los Alamos National Laboratory 1998 Water Year

    SciTech Connect (OSTI)

    D. A. Shaull; M. R. Alexander; R. P. Reynolds; C. T. McLean; R. P. Romero

    1999-02-01

    The principal investigators collected and computed surface water discharge data from 19 stream-gaging stations that cover most of Los Alamos National Laboratory. Also included are discharge data from three springs that flow into Caiion de Vane.

  18. Uranium in US surface, ground, and domestic waters. Volume 2

    SciTech Connect (OSTI)

    Drury, J.S.; Reynolds, S.; Owen, P.T.; Ross, R.H.; Ensminger, J.T.

    1981-04-01

    The report Uranium in US Surface, Ground, and Domestic Waters comprises four volumes. Volumes 2, 3, and 4 contain data characterizing the location, sampling date, type, use, and uranium conentrations of 89,994 individual samples presented in tabular form. The tabular data in volumes 2, 3, and 4 are summarized in volume 1 in narrative form and with maps and histograms.

  19. The effect of carbon on surface quality of solid-state-sintered...

    Office of Scientific and Technical Information (OSTI)

    The effect of carbon on surface quality of solid-state-sintered silicon carbide as optical materials Citation Details In-Document Search Title: The effect of carbon on surface ...

  20. Water quality: Historic values and impact of drilling activities during FY 1988 at the reference repository location in southeastern Washington

    SciTech Connect (OSTI)

    Eddy, P.A.; Teel, S.S.; Raymond, J.R.; Bierschenk, W.H.

    1988-03-01

    The purpose of the Environmental Monitoring Program was to monitor the characterization activities related to the Basalt Waste Isolation Project (BWIP) at boreholes DC-24CX and DC-25CX and document any environmental impacts as a result of these activities including contamination and/or degradation of the aquifer water quality from the invasion of drilling fluids into the formation and surface contamination from the disposal of drilling fluid at the land surface. The first phase of this program involved describing the baseline water quality at the Reference Repository Location (RRL) including data for spring and surface waters, and both the unconfined and confined aquifers. The second phase involved the collection and analysis of samples collected during drilling operations at wells DC-24CX and DC-25CX. Five surface water and 25 spring sampling sites were designated for chemical and radiological background data collection for BWIP. Chemical and radiological background data from 61 wells that obtain water from the unconfined aquifers indicate that the chemistry of these aquifers is similar to the spring and surface water samples. However, some of the wells show contamination from existing operations and past operations of various facilities on the Hanford Site. These contaminants are both chemical and radiological in nature with nitrate as the primary chemical constituent and tritium as the major radiological constituent. 20 refs., 9 figs., 8 tabs.

  1. Heterogeneous nucleation of naphthalene vapor on water surface

    SciTech Connect (OSTI)

    Smolik, J.; Schwarz, J.

    1997-01-15

    Transfer processes between drops and gas play an important role in many natural and industrial processes, as absorption of gaseous pollutants by water drops in the atmosphere, combustion of fuel droplets, spray drying, synthesis of nanopowders, wet-dry desulfurization or extinguishing of hot combustion gases. The evaporation of a water drop into a ternary gaseous mixture of air, steam, and naphthalene vapor was investigated. The experimental results were compared with a theoretical prediction based on a numerical solution of coupled boundary layer equations for heat and mass transfer from a drop moving in ternary gas. In the experiments the naphthalene vapor condensed on the water drop as a supercooled liquid even at temperatures far below the melting point of naphthalene. The condensation on drop surface is discussed in terms of classical theory of heterogeneous nucleation on smooth surfaces.

  2. Surface water data at Los Alamos National Laboratory: 2009 water year

    SciTech Connect (OSTI)

    Ortiz, David; McCullough, Betsy

    2010-05-01

    The principal investigators collected and computed surface water discharge data from 73 stream-gage stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs two that flow into Caon de Valle and one that flows into Water Canyon.

  3. Surface water data at Los Alamos National Laboratory: 2008 water year

    SciTech Connect (OSTI)

    Ortiz, David; Cata, Betsy; Kuyumjian, Gregory

    2009-09-01

    The principal investigators collected and computed surface water discharge data from 69 stream-gage stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs two that flow into Caon de Valle and one that flows into Water Canyon.

  4. Surface Water Data at Los Alamos National Laboratory: 1999 Water Year

    SciTech Connect (OSTI)

    D. A. Shaull; M. R. Alexander; R. P. Reynolds; C. T. McLean; R. P. Romero

    2000-04-01

    The principal investigators collected and computed surface water discharge data from 22 stream-gaging stations that cover most of Los Alamos National Laboratory with one at Bandelier National Monument. Also included are discharge data from three springs that flow into Canon de Valle and nine partial-record storm water stations.

  5. Surface Water Data at Los Alamos National Laboratory 2006 Water Year

    SciTech Connect (OSTI)

    R.P. Romero, D. Ortiz, G. Kuyumjian

    2007-08-01

    The principal investigators collected and computed surface water discharge data from 44 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data for 44 stations.

  6. Surface Water Data at Los Alamos National Laboratory: 2002 Water Year

    SciTech Connect (OSTI)

    D.A. Shaull; D. Ortiz; M.R. Alexander; R.P. Romero

    2003-03-03

    The principal investigators collected and computed surface water discharge data from 34 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data from 16 stations.

  7. Surface Water Data at Los Alamos National Laboratory 2000 Water Year

    SciTech Connect (OSTI)

    D.A.Shaull; M.R.Alexander; R.P.Reynolds; R.P.Romero; E.T.Riebsomer; C.T.McLean

    2001-06-02

    The principal investigators collected and computed surface water discharge data from 23 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs, two that flow into Canon del Valle and one that flows into Water Canyon.

  8. Observation of dynamic water microadsorption on Au surface

    SciTech Connect (OSTI)

    Huang, Xiaokang, E-mail: xiaokang.huang@tqs.com; Gupta, Gaurav; Gao, Weixiang; Tran, Van; Nguyen, Bang; McCormick, Eric; Cui, Yongjie; Yang, Yinbao; Hall, Craig; Isom, Harold [TriQuint Semiconductor, Inc., 500 W Renner Road, Richardson, Texas 75080 (United States)

    2014-05-15

    Experimental and theoretical research on water wettability, adsorption, and condensation on solid surfaces has been ongoing for many decades because of the availability of new materials, new detection and measurement techniques, novel applications, and different scales of dimensions. Au is a metal of special interest because it is chemically inert, has a high surface energy, is highly conductive, and has a relatively high melting point. It has wide applications in semiconductor integrated circuitry, microelectromechanical systems, microfluidics, biochips, jewelry, coinage, and even dental restoration. Therefore, its surface condition, wettability, wear resistance, lubrication, and friction attract a lot of attention from both scientists and engineers. In this paper, the authors experimentally investigated Au{sub 2}O{sub 3} growth, wettability, roughness, and adsorption utilizing atomic force microscopy, scanning electron microscopy, reflectance spectrometry, and contact angle measurement. Samples were made using a GaAs substrate. Utilizing a super-hydrophilic Au surface and the proper surface conditions of the surrounding GaAs, dynamic microadsorption of water on the Au surface was observed in a clean room environment. The Au surface area can be as small as 12??m{sup 2}. The adsorbed water was collected by the GaAs groove structure and then redistributed around the structure. A model was developed to qualitatively describe the dynamic microadsorption process. The effective adsorption rate was estimated by modeling and experimental data. Devices for moisture collection and a liquid channel can be made by properly arranging the wettabilities or contact angles of different materials. These novel devices will be very useful in microfluid applications or biochips.

  9. Water quality investigation of Kingston Fossil Plant dry ash stacking

    SciTech Connect (OSTI)

    Bohac, C.E.

    1990-04-01

    Changing to a dry ash disposal systems at Kingston Fossil Plant (KFP) raises several water quality issues. The first is that removing the fly ash from the ash pond could alter the characteristics of the ash pond discharge to the river. The second concerns proper disposal of the runoff and possibly leachate from the dry ash stack. The third is that dry ash stacking might change the potential for groundwater contamination at the KFP. This report addresses each of these issues. The effects on the ash pond and its discharge are described first. The report is intended to provide reference material to TVA staff in preparation of environmental review documents for new ash disposal areas at Kingston. Although the investigation was directed toward analysis of dry stacking, considerations for other disposal options are also discussed. This report was reviewed in draft form under the title Assessment of Kingston Fossil Plant Dry Ash Stacking on the Ash Pond and Groundwater Quality.'' 11 refs., 3 figs., 18 tabs.

  10. Performance of a selective surfaced water wall retrofit

    SciTech Connect (OSTI)

    Arasteh, D.; Harrje, D.T.; Nall, D.H.; Settles, G.S.

    1980-01-01

    The results of a successful passive water wall design and implementation in a suburban central New Jersey home are presented. The unique aspects of this work include the use of a selective surface coating on the exterior face of the thermal mass, the use of low-cost materials, and detailed performance measurements of the wall and home. The overall approach was to evaluate the retrofit possibilities of such a passive solar addition. Material costs of approximately $650 make this water wall design an attractive candidate for the do-it-yourself home retrofit. The wall performed well in supplying almost 20% of the winter heating requrements for the entire house. Compared to night insulation, the selective surface proved to be slightly less effective but much more economical.

  11. 2009-12 "Hold a Planned DOE-EM Meeting on LANL Water Quality...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Programs in a Northern New Mexico Location" 2009-12 "Hold a Planned DOE-EM Meeting on LANL Water Quality Programs in a Northern New Mexico Location" The NNMCAB recommends ...

  12. WAC - 173-200 Water Quality Standards for Groundwaters of the...

    Open Energy Info (EERE)

    These rules establish ground water quality standards to protect the environment and human health and protection of existing and future beneficial uses of groundwaters in...

  13. 5 CCR 1002-42 Site Specific Water Quality Standards for Ground...

    Open Energy Info (EERE)

    to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: 5 CCR 1002-42 Site Specific Water Quality Standards for Ground WaterLegal Abstract...

  14. MCA 75-5-101 et seq. - Water Quality | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: MCA 75-5-101 et seq. - Water QualityLegal Abstract Title 75, Chapter 5, MCA governs water...

  15. Shallow ground-water flow, water levels, and quality of water, 1980-84, Cowles Unit, Indiana Dunes National Lakeshore

    SciTech Connect (OSTI)

    Cohen, D.A.; Shedlock, R.J.

    1986-01-01

    The Cowles Unit of Indiana Dunes National Lakeshore in Porter County, northwest Indiana, contains a broad dune-beach complex along the southern shoreline of Lake Michigan and a large wetland, called the Great Marsh, that occupies the lowland between the shoreline dunes and an older dune-beach complex farther inland. Water levels and water quality in the surficial aquifer were monitored from 1977 to 1984 near settling ponds on adjacent industrial property at the western end of the Cowles Unit. Since 1980, when the settling pond bottoms were sealed, these intradunal lowlands contained standing water only during periods of high snowmelt or rainfall. Water level declines following the cessation of seepage ranged from 6 feet at the eastern-most settling pond to nearly 14 feet at the western-most pond. No general pattern of water table decline was observed in the Great Marsh or in the shoreline dune complex at distances > 3,000 ft east or north of the settling ponds. Since the settling ponds were sealed, the concentration of boron has decreased while concentrations of cadmium, arsenic, zinc, and molybdenum in shallow ground-water downgradient of the ponds show no definite trends in time. Arsenic, boron and molybdenum have remained at concentrations above those of shallow groundwater in areas unaffected by settling pond seepage. 11 refs., 10 figs., 1 tab.

  16. Oil spreading in surface waters with an ice cover

    SciTech Connect (OSTI)

    Yapa, P.D.; Weerasuriya, S.A.; Belaskas, D.P.; Chowdhury, T.

    1993-02-01

    A study of oil spreading in surface waters in the presence of a floating ice cover is presented. The ice can be solid or fragmented. Both axi-symmetrical and uni-directional spreading are studied. The report describes the analytical and numerical model development, the experimental set-up, results from the laboratory experiments, and their comparison with the derived theory and the numerical simulation. To analyze the spreading of oil under solid ice, new equations are derived. These equations consider gravity (buoyancy) - inertia phase, gravity (buoyancy) - viscous phase, and the termination of spreading during the buoyancy - surface tension phase. The derivation considers both the constant discharge mode and the constant volume mode. Therefore, a complete description of the spreading phenomena from the time of initial spill to termination of spreading is presented. The emphasis of the study is on the dominant spreading mechanism for oil under ice, which is the buoyancy-viscous phase.

  17. Novel Americium Treatment Process for Surface Water and Dust Suppression Water

    SciTech Connect (OSTI)

    Tiepel, E.W.; Pigeon, P.; Nesta, S.; Anderson, J.

    2006-07-01

    The Rocky Flats Environmental Technology Site (RFETS), a former nuclear weapons production plant, has been remediated under CERCLA and decommissioned to become a National Wildlife Refuge. The site conducted this cleanup effort under the Rocky Flats Cleanup Agreement (RFCA) that established limits for the discharge of surface and process waters from the site. At the end of 2004, while a number of process buildings were undergoing decommissioning, routine monitoring of a discharge pond (Pond A-4) containing approximately 28 million gallons of water was discovered to have been contaminated with a trace amount of Americium-241 (Am-241). While the amount of Am-241 in the pond waters was very low (0.5 - 0.7 pCi/l), it was above the established Colorado stream standard of 0.15 pCi/l for release to off site drainage waters. The rapid successful treatment of these waters to the regulatory limit was important to the site for two reasons. The first was that the pond was approaching its hold-up limit. Without rapid treatment and release of the Pond A-4 water, typical spring run-off would require water management actions to other drainages onsite or a mass shuttling of water for disposal. The second reason was that this type of contaminated water had not been treated to the stringent stream standard at Rocky Flats before. Technical challenges in treatment could translate to impacts on water and secondary waste management, and ultimately, cost impacts. All of the technical challenges and specific site criteria led to the conclusion that a different approach to the treatment of this problem was necessary and a crash treatability program to identify applicable treatment techniques was undertaken. The goal of this program was to develop treatment options that could be implemented very quickly and would result in the generation of no high volume secondary waste that would be costly to dispose. A novel chemical treatment system was developed and implemented at the RFETS to treat Am

  18. CONSTRUCTED WETLAND TREATMENT SYSTEMS FOR WATER QUALITY IMPROVEMENT

    SciTech Connect (OSTI)

    Nelson, E.

    2010-07-19

    The Savannah River National Laboratory implemented a constructed wetland treatment system (CWTS) in 2000 to treat industrial discharge and stormwater from the Laboratory area. The industrial discharge volume is 3,030 m{sup 3} per day with elevated toxicity and metals (copper, zinc and mercury). The CWTS was identified as the best treatment option based on performance, capital and continuing cost, and schedule. A key factor for this natural system approach was the long-term binding capacity of heavy metals (especially copper, lead, and zinc) in the organic matter and sediments. The design required that the wetland treat the average daily discharge volume and be able to handle 83,280 m{sup 3} of stormwater runoff in a 24 hour period. The design allowed all water flow within the system to be driven entirely by gravity. The CWTS for A-01 outfall is composed of eight one-acre wetland cells connected in pairs and planted with giant bulrush to provide continuous organic matter input to the system. The retention basin was designed to hold stormwater flow and to allow controlled discharge to the wetland. The system became operational in October of 2000 and is the first wetland treatment system permitted by South Carolina DHEC for removal of metals. Because of the exceptional performance of the A-01 CWTS, the same strategy was used to improve water quality of the H-02 outfall that receives discharge and stormwater from the Tritium Area of SRS. The primary contaminants in this outfall were also copper and zinc. The design for this second system required that the wetland treat the average discharge volume of 415 m{sup 3} per day, and be able to handle 9,690 m{sup 3} of stormwater runoff in a 24 hour period. This allowed the building of a system much smaller than the A-01 CWTS. The system became operational in July 2007. Metal removal has been excellent since water flow through the treatment systems began, and performance improved with the maturation of the vegetation during

  19. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2014

    SciTech Connect (OSTI)

    2013-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2014 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring is performed by the GWPP during CY 2014 to achieve the following goals: 􀁸 to protect the worker, the public, and the environment; 􀁸 to maintain surveillance of existing and potential groundwater contamination sources; 􀁸 to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; 􀁸 to identify and characterize long-term trends in groundwater quality at Y-12; and 􀁸 to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12.

  20. Surface Chemistry of GaP(001) and InP(001) in Contact with Water...

    Office of Scientific and Technical Information (OSTI)

    Surface Chemistry of GaP(001) and InP(001) in Contact with Water Citation Details In-Document Search Title: Surface Chemistry of GaP(001) and InP(001) in Contact with Water ...

  1. AISI/DOE Technology Roadmap Program: Improved Surface Quality of Exposed Automotive Sheet Steels

    SciTech Connect (OSTI)

    John G. Speer; David K. Matlock; Noel Meyers; Young-Min Choi

    2002-10-10

    Surface quality of sheet steels is an important economic and technical issue for applications such as critical automotive surfaces. This project was therefore initiated to develop a more quantitative methodology for measuring surface imperfections, and to assess their response to forming and painting, particularly with respect to their visibility or invisibility after painting. The objectives were met, and included evaluation of a variety of imperfections present on commercial sheet surfaces or simulated using methods developed in the laboratory. The results are expected to have significant implications with respect to the methodology for assessing surface imperfections, development of quantitative criteria for surface inspection, and understanding and improving key painting process characteristics that influence the perceived quality of sheet steel surfaces.

  2. Diagnosis of Solar Water Heaters Using Solar Storage Tank Surface Temperature Data: Preprint

    SciTech Connect (OSTI)

    Burch, J.; Magnuson, L.; Barker, G.; Bullwinkel, M.

    2009-04-01

    Study of solar water heaters by using surface temperature data of solar storage tanks to diagnose proper operations.

  3. AGENDA ADEP Surface Water Protection Project NPDES Storm Water Individual Permit Bi-Annual Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AGENDA ADEP Surface Water Protection Project NPDES Storm Water Individual Permit Bi-Annual Update Public Meeting January 22, 2014 5:30-7:30 p.m. Cities of Gold Conference Center Pojoaque, New Mexico 5:30 p.m. Poster Session 5:50 p.m. Welcome Steve Veenis 6:00 p.m. Flooding Events Fall 2013 Armand Groffman 6:15 p.m. IP Compliance for 2013 Jeff Walterscheid Kate Lynnes 6:35 p.m. IP Corrective Action Screening Process Thaddeus Kostrubala 6:45 p.m. Permit Renewal Kate Lynnes 7:00 p.m. Communities

  4. Water-quality data for aquifers, streams, and lakes in the vicinity of Keechi, Mount Sylvan, Oakwood, and Palestine salt domes, northeast Texas salt-dome basin

    SciTech Connect (OSTI)

    Carr, J.E.; Halasz, S.J.; Liscum, F.

    1980-11-01

    This report contains water-quality data for aquifers, streams, and lakes in the vicinity of Keechi, Mount Sylvan, Oakwood, and Palestine Salt Domes in the northeast Texas salt-dome basin. Water-quality data were compiled for aquifers in the Wilcox Group, the Carrizo Sand, and the Queen City Sand. The data include analyses for dissolved solids, pH, temperature, hardness, calcium, magnesium, sodium, bicarbonate, chloride, and sulfate. Water-quality and streamflow data were obtained from 63 surface-water sites in the vicinity of the domes. These data include water discharge, specific conductance, pH, water temperature, and dissolved oxygen. Samples were collected at selected sites for analysis of principal and selected minor dissolved constituents.

  5. Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

    SciTech Connect (OSTI)

    Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

    2005-10-31

    Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

  6. Linear relationship between water wetting behavior and microscopic interactions of super-hydrophilic surfaces

    SciTech Connect (OSTI)

    Liu, Jian; Guo, Pan; University of Chinese Academy of Sciences, Beijing 100049 ; Wang, Chunlei; Shi, Guosheng Fang, Haiping

    2013-12-21

    Using molecular dynamics simulations, we show a fine linear relationship between surface energies and microscopic Lennard-Jones parameters of super-hydrophilic surfaces. The linear slope of the super-hydrophilic surfaces is consistent with the linear slope of the super-hydrophobic, hydrophobic, and hydrophilic surfaces where stable water droplets can stand, indicating that there is a universal linear behavior of the surface energies with the water-surface van der Waals interaction that extends from the super-hydrophobic to super-hydrophilic surfaces. Moreover, we find that the linear relationship exists for various substrate types, and the linear slopes of these different types of substrates are dependent on the surface atom density, i.e., higher surface atom densities correspond to larger linear slopes. These results enrich our understanding of water behavior on solid surfaces, especially the water wetting behaviors on uncharged super-hydrophilic metal surfaces.

  7. South Asia Water Resources Workshop: An effort to promote water quality data sharing in South Asia

    SciTech Connect (OSTI)

    RAJEN,GAURAV; BIRINGER,KENT L.; BETSILL,J. DAVID

    2000-04-01

    To promote cooperation in South Asia on environmental research, an international working group comprised of participants from Bangladesh, India, Nepal, Pakistan, Sri Lanka, and the US convened at the Soaltee Hotel in Kathmandu, Nepal, September 12 to 14, 1999. The workshop was sponsored in part by the Cooperative Monitoring Center (CMC) at Sandia National Laboratories in Albuquerque, New Mexico, through funding provided by the Department of Energy (DOE) Office of Nonproliferation and National Security. The CMC promotes collaborations among scientists and researchers in regions throughout the world as a means of achieving common regional security objectives. In the long term, the workshop organizers and participants are interested in the significance of regional information sharing as a means to build confidence and reduce conflict. The intermediate interests of the group focus on activities that might eventually foster regional management of some aspects of water resources utilization. The immediate purpose of the workshop was to begin the implementation phase of a project to collect and share water quality information at a number of river and coastal estuary locations throughout the region. The workshop participants achieved four objectives: (1) gaining a better understanding of the partner organizations involved; (2) garnering the support of existing regional organizations promoting environmental cooperation in South Asia; (3) identifying sites within the region at which data is to be collected; and (4) instituting a data and information collection and sharing process.

  8. OAR 340-048 - Certification of Compliance with Water Quality...

    Open Energy Info (EERE)

    Procedures for processing applications for certification pursuant to Section 401 of the Clean Water Act. Published NA Year Signed or Took Effect 1985 Legal Citation OAR 340-048...

  9. 16 TAC, part 1, chapter 3, rule 3.93 Water Quality Certification...

    Open Energy Info (EERE)

    93 Water Quality Certification Definitions Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 16 TAC, part 1, chapter 3, rule...

  10. MCA 75-5-401 - Water Quality Permits: Board Rules for Permits...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: MCA 75-5-401 - Water Quality Permits: Board Rules for PermitsLegal Abstract Sets forth board...

  11. H.A.R. 11-54 - Water Quality Standards | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: H.A.R. 11-54 - Water Quality StandardsLegal Abstract The State of Hawaii Department of Health...

  12. 49 A.R.S. 321 et seq.: Water Quality Appeals | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 49 A.R.S. 321 et seq.: Water Quality AppealsLegal Abstract This section governs appeals to the...

  13. NMS 74-6-4 Duties and Powers of the Water Quality Control Commission...

    Open Energy Info (EERE)

    -4 Duties and Powers of the Water Quality Control Commission Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: NMS 74-6-4 Duties...

  14. NMS 74-6 Environmental Improvement of Water Quality | Open Energy...

    Open Energy Info (EERE)

    Environmental Improvement of Water Quality Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: NMS 74-6 Environmental Improvement of...

  15. U.A.C. R317-2: Standards of Quality for Waters of the State ...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: U.A.C. R317-2: Standards of Quality for Waters of the StateLegal Abstract This regulation...

  16. U.A.C. R317-15: Water Quality Certification | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: U.A.C. R317-15: Water Quality CertificationLegal Abstract This rule establishes procedures for...

  17. I.C. 39-3602 - Water Quality--Definitions | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: I.C. 39-3602 - Water Quality--DefinitionsLegal Abstract This statutory section provides...

  18. Effect of Surface Oxidation on Interfacial Water Structure at a Pyrite (100) Surface as Studied by Molecular Dynamics Simulation

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.; Wick, Collin D.

    2015-06-01

    In the first part of this paper, a Scanning Electron Microscopy and contact angle study of a pyrite surface (100) is reported describing the relationship between surface oxidation and the hydrophilic surface state. In addition to these experimental results, the following simulated surface states were examined using Molecular Dynamics Simulation (MDS): fresh unoxidized (100) surface; polysulfide at the (100) surface; elemental sulfur at the (100) surface. Crystal structures for the polysulfide and elemental sulfur at the (100) surface were simulated using Density Functional Theory (DFT) quantum chemical calculations. The well known oxidation mechanism which involves formation of a metal deficient layer was also described with DFT. Our MDS results of the behavior of interfacial water at the fresh and oxidized pyrite (100) surfaces without/with the presence of ferric hydroxide include simulated contact angles, number density distribution for water, water dipole orientation, water residence time, and hydrogen-bonding considerations. The significance of the formation of ferric hydroxide islands in accounting for the corresponding hydrophilic surface state is revealed not only from experimental contact angle measurements but also from simulated contact angle measurements using MDS. The hydrophilic surface state developed at oxidized pyrite surfaces has been described by MDS, on which basis the surface state is explained based on interfacial water structure. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the DOE funded work performed by Liem X. Dang. Battelle operates the Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES.

  19. Stormwater runoff water quality evaluation and management program for hazardous chemical sites: Development issues

    SciTech Connect (OSTI)

    Lee, G.F.; Jones-Lee, A.

    1998-12-31

    The deficiencies in the typical stormwater runoff water quality monitoring from hazardous chemical sites and an alternative approach (Evaluation Monitoring) for monitoring that shifts the monitoring program from periodic sampling and analysis of stormwater runoff for a suite of chemical parameters to examining the receiving waters to determine what, if any, water quality use impairments are occurring due to the runoff-associated constituents is presented in this paper. Rather than measuring potentially toxic constituents such as heavy metals in runoff, the monitoring program determines whether there is aquatic life toxicity in the receiving waters associated with the stormwater runoff. If toxicity is found, its cause is determined and the source of the constituents causing the toxicity is identified through forensic analysis. Based on this information, site-specific, technically valid stormwater runoff management programs can be developed that will control real water quality impacts caused by stormwater runoff-associated constituents.

  20. A modeling study of the potential water quality impacts from in-stream tidal energy extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Taiping; Yang, Zhaoqing; Copping, Andrea E.

    2013-11-09

    To assess the effects of tidal energy extraction on water quality in a simplified estuarine system, which consists of a tidal bay connected to the coastal ocean through a narrow channel where energy is extracted using in-stream tidal turbines, a three-dimensional coastal ocean model with built-in tidal turbine and water quality modules was applied. The effects of tidal energy extraction on water quality were examined for two energy extraction scenarios as compared with the baseline condition. It was found, in general, that the environmental impacts associated with energy extraction depend highly on the amount of power extracted from the system.more » Model results indicate that, as a result of energy extraction from the channel, the competition between decreased flushing rates in the bay and increased vertical mixing in the channel directly affects water quality responses in the bay. The decreased flushing rates tend to cause a stronger but negative impact on water quality. On the other hand, the increase of vertical mixing could lead to higher bottom dissolved oxygen at times. As the first modeling effort directly aimed at examining the impacts of tidal energy extraction on estuarine water quality, this study demonstrates that numerical models can serve as a very useful tool for this purpose. Furthermore, more careful efforts are warranted to address system-specific environmental issues in real-world, complex estuarine systems.« less

  1. Lake Whitney Comprehensive Water Quality Assessment, Phase 1B- Physical and Biological Assessment (USDOE)

    SciTech Connect (OSTI)

    Doyle, Robert D; Byars, Bruce W

    2009-11-24

    Baylor University Center for Reservoir and Aquatic Systems Research (CRASR) has conducted a phased, comprehensive evaluation of Lake Whitney to determine its suitability for use as a regional water supply reservoir. The area along the Interstate 35 corridor between Dallas / Fort Worth Metroplex and the Waco / Temple Centroplex represents one of the fastest growth areas in the State of Texas and reliable water supplies are critical to sustainable growth. Lake Whitney is situated midway between these two metropolitan areas. Currently, the City of Whitney as well as all of Bosque and Hill counties obtain their potable water from the Trinity Sands aquifer. Additionally, parts of the adjoining McLennan and Burleson counties utilize the Trinity sands aquifer system as a supplement to their surface water supplies. Population growth coupled with increasing demands on this aquifer system in both the Metroplex and Centroplex have resulted in a rapid depletion of groundwater in these rural areas. The Lake Whitney reservoir represents both a potentially local and regional solution for an area experiencing high levels of growth. Because of the large scope of this project as well as the local, regional and national implications, we have designed a multifaceted approach that will lead to the solution of numerous issues related to the feasibility of using Lake Whitney as a water resource to the region. Phase IA (USEPA, QAPP Study Elements 1-4) of this research focused on the physical limnology of the reservoir (bathymetry and fine scale salinity determination) and develops hydrodynamic watershed and reservoir models to evaluate how salinity would be expected to change with varying hydrologic and climatic factors. To this end, we implemented a basic water quality modeling program in collaboration with the Texas Parks and Wildlife Department and the Texas Commission on Environmental Quality to add to the developing long-term database on Lake Whitney. Finally, we conducted an initial

  2. Waste stream recycling: Its effect on water quality

    SciTech Connect (OSTI)

    Cornwell, D.A. ); Lee, R.G. )

    1994-11-01

    Waste streams recycled to the influent of a water treatment plant typically contain contaminants at concentrations that are of concern. These contaminants may include giardia and Cryptosporidium, trihalomethanes, manganese, and assimilable organic carbon. This research shows that proper management--treatment, equalization, and monitoring--of the waste streams can render them suitable for recycling in many situations.

  3. NMAC 20.6.2 Ground and Surface Water Protection | Open Energy...

    Open Energy Info (EERE)

    6.2 Ground and Surface Water Protection Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: NMAC 20.6.2 Ground and Surface...

  4. Quality problems in waters used for drinking purposes in Italy

    SciTech Connect (OSTI)

    Funari, E.; Bastone, A.; Bottoni, P.; De Donno, D.; Donati, L. )

    1991-12-01

    With a grant from the Italian Ministry of the Environment, the National Institute of Health (Istituto Superiore di Sanita) promoted and coordinated some activities aimed at determining the extent and the intensity of contamination of waters used for human consumption by some chemical agents, and describing causes and modalities of contamination and human health implications. The chemical agents examined were herbicides, nitrates, trihalomethanes, asbestos, manganese and fluoride. In this paper a first nationwide picture of these problems is reported.

  5. Tissue-based water quality biosensors for detecting chemical warfare agents

    DOE Patents [OSTI]

    Greenbaum, Elias; Sanders, Charlene A.

    2003-05-27

    A water quality sensor for detecting the presence of at least one chemical or biological warfare agent includes: a cell; apparatus for introducing water into the cell and discharging water from the cell adapted for analyzing photosynthetic activity of naturally occurring, free-living, indigenous photosynthetic organisms in water; a fluorometer for measuring photosynthetic activity of naturally occurring, free-living, indigenous photosynthetic organisms drawn into the cell; and an electronics package that analyzes raw data from the fluorometer and emits a signal indicating the presence of at least one chemical or biological warfare agent in the water.

  6. Evaluation of Water Quality Conditions Near Proposed Fish Production Sites Associated with the Yakima Fisheries Project, 1991-1993 Final Report.

    SciTech Connect (OSTI)

    Dauble, Dennis D.

    1994-05-01

    In 1991, the Pacific Northwest Laboratory (PNL) began studying water quality at several sites in the Yakima River Basin for the Bonneville Power Administration. These sites were being proposed as locations for fish culture facilities as part of the Yakima Fisheries Project (YFP). Surface water quality parameters near the proposed fish culture facilities are currently suitable for fish production. Water quality conditions in the mainstream Yakima River and its tributaries are generally excellent in the upper part of the watershed (i.e., near Cle Elum), but they are only fair to poor for the river downstream of Union Gap (river mile 107). Water quality of the Naches River near Oak Flats is also suitable for fish production. Groundwater supplies near the proposed fish production facilities typically have elevated concentrations of metals and dissolved gases. These conditions can be mitigated using best engineering practices such as precipitation and degasification. Additionally, mixing with surface water may improve these conditions. Depending on the location and depth of the well, groundwater temperatures may be warmer than optimum for acclimating and holding juvenile and adult fish. Water quality parameters measured in the Yakima River and tributaries sometimes exceed the range of values described as acceptable for culture of salmonids and for the protection of other aquatic life. However, constituent concentrations are within ranges that exist in many northwest fish hatcheries. Additionally, site-specific tests conducted by PNL (i.e., live box exposures and egg incubation studies) indicate that fish can be successfully reared in surface and well water near the proposed facility sites. Thus, there appear to be no constraints to artificial production for the YFP.

  7. Surface Water Sampling At Chena Geothermal Area (Waring, Et Al...

    Open Energy Info (EERE)

    calcium and magnesium concentrations were measured, with elevated levels of silica and sulfate. Surface fumarole gases were tested with a flame to indicate carbon dioxide...

  8. Water adsorption induced in-plane domain switching on BaTiO{sub 3} surface

    SciTech Connect (OSTI)

    Li, X.; Bai, Y.; Su, Y. J.; Wang, B. C.

    2015-09-07

    In this study, the influences of the adsorption of water molecules on the changes in the atomic and electric structures of BaTiO{sub 3} surface were investigated using ab initio calculation. Water molecules are molecularly and dissociatively adsorbed on the BaTiO{sub 3} surface, which makes electrons transfer from water molecules to the BaTiO{sub 3} surface. The redistribution of electrons in the BaTiO{sub 3} surface layers weakens the Ba-O interactions and strengthens the Ti-O interactions, so that the Ti atom shifts in TiO{sub 2} plane, i.e., an in-plane domain switching. The adsorption of water molecules on BaTiO{sub 3} surfaces also results in a reduction in the surface rumpling.

  9. Two-dimensional water quality modeling of Town Creek embayment on Guntersville Reservoir

    SciTech Connect (OSTI)

    Bender, M.D.; Shiao, Ming C.; Hauser, G.E. . Engineering Lab.); Butkus, S.R. . Water Quality Dept.)

    1990-09-01

    TVA investigated water quality of Town Creek embayment using a branched two-dimensional model of Guntersville Reservoir. Simulation results were compared in terms of algal biomass, nutrient concentrations, and volume of embayment with depleted dissolved oxygen. Stratification and flushing play a significant role in the embayment water quality. Storms introduce large loadings of organics, nutrients, and suspended solids. Dissolved oxygen depletion is most severe after storms followed by low flow that fails to flush the embayment. Embayment water quality responses to potential animal waste and erosion controls were explored. Modeling indicated animal waste controls were much more cost-effective than erosion controls. Erosion controls will decrease embayment suspended solids and thereby increase algal biomass due to greater light penetration. 29 refs., 16 figs., 4 tabs.

  10. Dispersal Limitations on Fish Community Recovery Following Long-term Water Quality Remediation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McManamay, Ryan A.; Jett, Robert T.; Ryon, Michael G.; Gregory, Scott M.; Stratton, Sally H.; Peterson, Mark J.

    2016-02-22

    Holistic restoration approaches, such as water quality remediation, are likely to meet conservation objectives because they are typically implemented at watershed scales, as opposed to individual stream reaches. However, habitat fragmentation may impose constraints on the ecological effectiveness of holistic restoration strategies by limiting colonization following remediation. We questioned the importance of dispersal limitations to fish community recovery following long-term water quality remediation and species reintroductions across the White Oak Creek (WOC) watershed near Oak Ridge, Tennessee (USA). Long-term (26 years) responses in fish species richness and biomass to water quality remediation were evaluated in light of habitat fragmentation andmore » population isolation from instream barriers, which varied in their passage potential. In addition, ordination techniques were used to determine the relative importance of habitat connectivity and water quality, in explaining variation fish communities relative to environmental fluctuations, i.e. streamflow. Ecological recovery (changes in richness) at each site was negatively related to barrier index, a measure of community isolation by barriers relative to stream distance. Following species reintroductions, dispersal by fish species was consistently in the downstream direction and upstream passage above barriers was non-existent. The importance of barrier index in explaining variation in fish communities was stronger during higher flow conditions, but decreased over time an indication of increasing community stability and loss of seasonal migrants. Compared to habitat fragmentation, existing water quality concerns (i.e., outfalls, point source discharges) were unrelated to ecological recovery, but explained relatively high variation in community dynamics. Our results suggest that habitat fragmentation limited the ecological effectiveness of intensive water quality remediation efforts and fish reintroduction

  11. Farm operator perceptions of water quality protective pest management practices: Selected survey findings

    SciTech Connect (OSTI)

    Zimmerman, R.; Blair, J.; Webb, B.

    1995-12-01

    The use of pesticides in agriculture often poses a tension between water quality and environmental protection goals on the one hand and the viability of food supplies on the other hand. Pesticides used for field crops (e.g., corn, soy beans and wheat) have been detected in waterbodies, and according to some studies, are apparently finding their way into water supplies. A considerable amount of discretion is allowed in farm operator`s choice of pest management practices, and voluntary behavior becomes an important factor in promoting environmentally protective practices. Thus, it is important to know the attitudes of farmers who make pest management decisions including pesticide choices, toward the use of various water quality protective pest management practices. A number of studies show that more general environmental attitudes reflect a general world view that shapes attitudes toward particular environmental issues. This paper addresses the relationship between the more general environmental attitudes of farmers to their attitudes toward water quality issues and pest management practices which are protective of water quality. Some of the personal tradeoffs farmers are willing to make to enhance environmental controls on pesticides are also explored. Results are based on preliminary findings from a survey of farm operators who grow corn, soybeans and other field crops in three eastern states. The survey was conducted via a mail questionnaire to 2,700 farmers with telephone follow-up during the Fall of 1994. Implications of the findings for pest management in general are discussed.

  12. Method of and device for detecting oil pollutions on water surfaces

    DOE Patents [OSTI]

    Belov, Michael Leonidovich; Gorodnichev, Victor Aleksandrovich; Kozintsev, Valentin Ivanovich; Smimova, Olga Alekseevna; Fedotov, Yurii Victorovich; Khroustaleva, Anastasiva Michailovnan

    2008-08-26

    Detection of oil pollution on water surfaces includes providing echo signals obtained from optical radiation of a clean water area at two wavelengths, optically radiating an investigated water area at two wavelengths and obtaining echo signals from the optical radiation of the investigated water area at the two wavelengths, comparing the echo signals obtained from the radiation of the investigated area at two wavelengths with the echo signals obtained from the radiation of the clean water area, and based on the comparison, determining presence or absence of oil pollution in the investigated water area.

  13. Improved Design Tools for Surface Water and Standing Column Well Heat Pump

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems | Department of Energy Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems This project will improve the capability of engineers to design heat pump systems that utilize surface water or standing column wells (SCW) as their heat sources and sinks. gshp_spitler_design_tools.html_.pdf (286.01 KB) More Documents & Publications City of Eagan …Civic Ice Arena Renovation

  14. Water quality criteria for colored smokes: Solvent Yellow 33, Final report. [Contains glossary

    SciTech Connect (OSTI)

    Davidson, K.A.; Hovatter, P.S.

    1987-11-01

    The available data on the environmental fate, aquatic toxicity, and mammalian toxicity of Solvent Yellow 33, a quinoline dye used in colored smoke grenades, were reviewed. The US Environmental Protection Agency (USEPA) guidelines were used in an attempt to generate water quality criteria for the protection of aquatic life and its use and of human health. 87 refs., 2 figs., 13 tabs.

  15. EM Completes Project to Maintain Water Quality of Spent Nuclear Fuel Basin at Idaho Site

    Broader source: Energy.gov [DOE]

    IDAHO FALLS, Idaho – EM and its main cleanup contractor at DOE’s Idaho Site recently reached a major project milestone necessary to maintain water quality and continued, safe operations within the site’s spent nuclear fuel storage basin.

  16. Technical assistance contractor management plan: Surface and ground water

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    This report presents the general management structure of the Technical Assistance Contractor (TAC) for the Uranium Mill Tailings Remedial Action (UMTRA) Project. This team is a partnership of four major private subcontractors, which teamed together, are striving to be the leader in environmental restoration of uranium mining and milling operations. It will provide a pool of experts in various aspects of the technologies necessary to accomplish this goal, available to DOE to deal with mission concerns. The report expands on goals from TAC`s mission statement, which include management concerns, environment, safety, and health, quality, technical support, communications, and personnel.

  17. 5 CCR 1002-31 Basic Standards and Methodologies for Surface Water...

    Open Energy Info (EERE)

    to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: 5 CCR 1002-31 Basic Standards and Methodologies for Surface Water RegulationLegal Abstract...

  18. NMSA 72-5 Appropriation and Use of Surface Water | Open Energy...

    Open Energy Info (EERE)

    5 Appropriation and Use of Surface Water Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: NMSA 72-5 Appropriation and Use of...

  19. Clean Boiler Water-side Heat Transfer Surfaces - Steam Tip Sheet #7

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  20. "Nanoengineered Surfaces for Efficiency Enhancements in Energy and Water",

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Professor Kripa Varansi, Massachusetts Institute of Technology | Princeton Plasma Physics Lab October 24, 2012, 4:15pm Colloquia MBG Auditorium "Nanoengineered Surfaces for Efficiency Enhancements in Energy and Water", Professor Kripa Varansi, Massachusetts Institute of Technology Thermal-fluid-surface interactions are ubiquitous in multiple industries including Energy, Water, Agriculture, Transportation, Electronics Cooling, Buildings, etc. Over the years, these systems have been

  1. Water Quality Trends in the Entiat River Subbasin: Final 2008 Annual Report.

    SciTech Connect (OSTI)

    Woodsmith, Richard; Bookter, Andy

    2009-03-30

    The ISEMP program monitors the status and trend of water quality elements that may affect restoration project effectiveness in the Entiat subbasin. As part of this effort, the PNW Research Station (PNW) measures, analyzes and interprets temporal trends in natural stream water pH, dissolved oxygen, specific conductivity and temperature. The Entiat River is currently on the Clean Water Act 303(d) list for pH exceedence, and there is insufficient information to determine the spatial and temporal extent or potential causes of this exceedence. In the spring 2008, PNW redeployed data-logging, multiparameter probes at four locations in the Entiat subbasin to measure water quality parameters, focusing on pH. This resumed previous data collection that was interrupted by river ice in early December 2007. Instruments were again removed from the river in early December 2008. This annual report covers the period from December 2007 through December 2008. The highest pH values occurred during the low-flow period from midsummer through the following midspring then dropped sharply during the annual snowmelt runoff period from late spring through early summer. Water temperature began rapidly increasing during the receding limb of the annual snowmelt hydrograph. Highest mean monthly temperatures occurred in July and August, while instantaneous maxima occurred during the period July-September. Dissolved oxygen reached its lowest levels during the period of highest water temperature in July-September. Specific conductivity remained very low at all sites throughout the year.

  2. Critical review: Radionuclide transport, sediment transport, and water quality mathematical modeling; and radionuclide adsorption/desorption mechanisms

    SciTech Connect (OSTI)

    Onishi, Y.; Serne, R.J.; Arnold, E.M.; Cowan, C.E.; Thompson, F.L.

    1981-01-01

    This report describes the results of a detailed literature review of radionuclide transport models applicable to rivers, estuaries, coastal waters, the Great Lakes, and impoundments. Some representatives sediment transport and water quality models were also reviewed to evaluate if they can be readily adapted to radionuclide transport modeling. The review showed that most available transport models were developed for dissolved radionuclide in rivers. These models include the mechanisms of advection, dispersion, and radionuclide decay. Since the models do not include sediment and radionuclide interactions, they are best suited for simulating short-term radionuclide migration where: (1) radionuclides have small distribution coefficients; (2) sediment concentrations in receiving water bodies are very low. Only 5 of the reviewed models include full sediment and radionuclide interactions: CHMSED developed by Fields; FETRA SERATRA, and TODAM developed by Onishi et al, and a model developed by Shull and Gloyna. The 5 models are applicable to cases where: (1) the distribution coefficient is large; (2) sediment concentrations are high; or (3) long-term migration and accumulation are under consideration. The report also discusses radionuclide absorption/desorption distribution ratios and addresses adsorption/desorption mechanisms and their controlling processes for 25 elements under surface water conditions. These elements are: Am, Sb, C, Ce, Cm, Co, Cr, Cs, Eu, I, Fe, Mn, Np, P, Pu, Pm, Ra, Ru, Sr, Tc, Th, {sup 3}H, U, Zn and Zr.

  3. Molecular Dynamics Simulation and Analysis of Interfacial Water at Selected Sulfide Mineral Surfaces under Anaerobic Conditions

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.

    2014-04-10

    In this paper, we report on a molecular dynamics simulation (MDS) study of the behavior of interfacial water at selected sulfide mineral surfaces under anaerobic conditions. The study revealed the interfacial water structure and wetting characteristics of the pyrite (100) surface, galena (100) surface, chalcopyrite (012) surface, sphalerite (110) surface, and molybdenite surfaces (i.e., the face, armchair-edge, and zigzag-edge surfaces), including simulated contact angles, relative number density profiles, water dipole orientations, hydrogen-bonding, and residence times. For force fields of the metal and sulfur atoms in selected sulfide minerals used in the MDS, we used the universal force field (UFF) and another set of force fields optimized by quantum chemical calculations for interactions with interfacial water molecules at selected sulfide mineral surfaces. Simulation results for the structural and dynamic properties of interfacial water molecules indicate the natural hydrophobic character for the selected sulfide mineral surfaces under anaerobic conditions as well as the relatively weak hydrophobicity for the sphalerite (110) surface and two molybdenite edge surfaces. Part of the financial support for this study was provided by the U.S. Department of Energy (DOE) under Basic Science Grant No. DE-FG-03-93ER14315. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the DOE, funded work performed by Liem X. Dang. Battelle operates Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES. The authors are grateful to Professor Tsun-Mei Chang for valuable discussions.

  4. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  5. Water quality in the shingle creek basin, Florida, before and after wastewater diversion

    SciTech Connect (OSTI)

    O`Dell, K.M.

    1994-05-01

    Shingle Creek is a major inflow to Lake Tohopekaliga, Florida. Water quality and the trophic status of Lake Tohopekaliga are affected strongly by the water quality of Shingle Creek. This report documents 10 yr of water quality data in Shingle Creek at the lake outfall; for a pre- (October 1981-December 1986) and a post-wastewater discharge (January 1987-September 1991) removal period. Nutrient budgets for the subbasins were calculated from an intense research program (January 1983-December 1985) to document instream impacts attributable to wastewater, determine the role of the cypress swamp in the middle subbasin, and document relationships between water quality and land uses. Rapid urbanization converted forested uplands and agricultural lands to housing and commercial land use during the study. Stormwater runoff in Florida has been identified as a major pollution source. Treatment of stormwater pollution, through Best Management Practices (BMPs), has been regulated by the State of Florida in this area since 1982. By 1988, 84% of the urban landuse in the upper basin was subject to stormwater treatment prior to being discharged to the creek. Potential increases in urban derived nutrient inputs were offset by stormwater management, and alum treatment and diversion of municipal wastewater. Nitrogen loading and P loads and variance decreased significantly during the 10-yr period, despite rapid urbanization in the northern and central subbasins. Nutrient export from the subbasins was influenced by the dominant land use. The middle subbasin contains a swamp that contributed the greatest P and Cl{sup -} loads because of the increase in discharge to the swamp from sources other than the canal. The northern urban subbasin received the wastewater discharges and served as a net sink for N and P exported from the subbasin. 24 refs., 9 figs., 1 tab.

  6. Reconnaissance of ground-water quality in the Papio-Missouri river natural resources district, Eastern Nebraska, July through September 1992. Water resources investigation

    SciTech Connect (OSTI)

    Verstraeten, I.M.; Ellis, M.J.

    1995-12-31

    The purpose of this report is to describe the water quality of the principal aquifers in the study area. Wells representative of the geology and land use in the study area were selected for water-quality sampling. Variations in constituent concentration among aquifers are discussed. The report describes the spatial distributions of dissolved nitrite plus-nitrate as nitrogen and triazine and other acetanilide herbicides and evaluates the effects of cropland application of nitrogen and herbicides on the ground-water quality within the study area. The report also summarizes the concentrations of dissolved major and trace constituents including radionuclide activity and concentration.

  7. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2012

    SciTech Connect (OSTI)

    Elvado Environmental, LLC

    2011-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2012 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2012 is in accordance with the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge along the boundary of the Oak Ridge Reservation. Modifications to the CY 2012 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. Each modification to the monitoring program will be approved by the Y-12 GWPP manager and documented as an addendum to this sampling and analysis plan. The following sections of this report provide details regarding

  8. Evaluation of Phytoremediation of Coal Bed Methane Product Water and Waters of Quality Similar to that Associated with Coal Bed Methane Reserves of the Powder River Basin, Montana and Wyoming

    SciTech Connect (OSTI)

    James Bauder

    2008-09-30

    U.S. emphasis on domestic energy independence, along with advances in knowledge of vast biogenically sourced coalbed methane reserves at relatively shallow sub-surface depths with the Powder River Basin, has resulted in rapid expansion of the coalbed methane industry in Wyoming and Montana. Techniques have recently been developed which constitute relatively efficient drilling and methane gas recovery and extraction techniques. However, this relatively efficient recovery requires aggressive reduction of hydrostatic pressure within water-saturated coal formations where the methane is trapped. Water removed from the coal formation during pumping is typically moderately saline and sodium-bicarbonate rich, and managed as an industrial waste product. Current approaches to coalbed methane product water management include: surface spreading on rangeland landscapes, managed irrigation of agricultural crop lands, direct discharge to ephermeral channels, permitted discharge of treated and untreated water to perennial streams, evaporation, subsurface injection at either shallow or deep depths. A Department of Energy-National Energy Technology Laboratory funded research award involved the investigation and assessment of: (1) phytoremediation as a water management technique for waste water produced in association with coalbed methane gas extraction; (2) feasibility of commercial-scale, low-impact industrial water treatment technologies for the reduction of salinity and sodicity in coalbed methane gas extraction by-product water; and (3) interactions of coalbed methane extraction by-product water with landscapes, vegetation, and water resources of the Powder River Basin. Prospective, greenhouse studies of salt tolerance and water use potential of indigenous, riparian vegetation species in saline-sodic environments confirmed the hypothesis that species such as Prairie cordgrass, Baltic rush, American bulrush, and Nuttall's alkaligrass will thrive in saline-sodic environments when

  9. Use of Remote Technology in the Surface Water Environmental Monitoring Program at SRS Reducing Measurements in the Field - 13336

    SciTech Connect (OSTI)

    Eddy, T.; Terry, B.; Meyer, A.; Hall, J.; Allen, P.; Hughey, D.; Hartley, T.

    2013-07-01

    There are a wide range of sensor and remote technology applications available for use in environmental monitoring programs. Each application has its own set of limitations and can be challenging when attempting to utilize it under diverse environmental field conditions. The Savannah River Site Environmental Monitoring Program has implemented several remote sensing and surface water flow technologies that have increased the quality of the data while reducing the number of field measurements. Implementation of this technology reduced the field time for personnel that commute across the Savannah River Site (SRS) over a span of 310 square miles. The wireless surface water flow technology allows for immediate notification of changing field conditions or equipment failure thus reducing data-loss or erroneous field data and improving data-quality. This wireless flow technology uses the stage-to-flow methodology coupled with implementation of a robust highly accurate Acoustic Doppler Profiler system for measuring discharge under various field conditions. Savings for implementation of the wireless flow application and Flowlink{sup R} technology equates to approximately 1175 hours annually for the radiological liquid effluent and surveillance programs. The SonTek River Suveyor and Flowtracker technologies are utilized for calibration of the wireless flow monitoring devices in the site streams and validation of effluent flows at the SRS. Implementation of similar wireless devices is also planned in the National Pollutant Discharge Elimination System (NPDES) Storm-water Monitoring Program. SRS personnel have been developing a unique flow actuator device. This device activates an ISCO{sup TM} automated sampler under flowing conditions at storm-water outfall locations across the site. This technology is unique in that it was designed to be used under field conditions with rapid changes in flow and sedimentation where traditional actuators have been unsuccessful in tripping the

  10. The effect of plutonium dioxide water surface coverage on the generation of hydrogen and oxygen

    SciTech Connect (OSTI)

    Veirs, Douglas K.; Berg, John M.; Crowder, Mark L.

    2012-06-20

    The conditions for the production of oxygen during radiolysis of water adsorbed onto plutonium dioxide powder are discussed. Studies in the literature investigating the radiolysis of water show that both oxygen and hydrogen can be generated from water adsorbed on high-purity plutonium dioxide powder. These studies indicate that there is a threshold in the amount of water below which oxygen is not generated. The threshold is associated with the number of monolayers of adsorbed water and is shown to occur at approximately two monolayers of molecularly adsorbed water. Material in equilibrium with 50% relative humidity (RH) will be at the threshold for oxygen generation. Using two monolayers of molecularly adsorbed water as the threshold for oxygen production, the total pressure under various conditions is calculated assuming stoichiometric production of hydrogen and oxygen. The specific surface area of the oxide has a strong effect on the final partial pressure. The specific surface areas resulting in the highest pressures within a 3013 container are evaluated. The potential for oxygen generation is mitigated by reduced relative humidity, and hence moisture adsorption, at the oxide surface which occurs if the oxide is warmer than the ambient air. The potential for oxygen generation approaches zero as the temperature difference between the ambient air and the material approaches 6 C.

  11. Studies of the viscoelastic properties of water confined between surfaces of specified chemical nature.

    SciTech Connect (OSTI)

    Houston, Jack E.; Grest, Gary Stephen; Moore, Nathan W.; Feibelman, Peter J.

    2010-09-01

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.

  12. Aquatic macroinvertebrates and water quality of Sandia Canyon, Los Alamos National Laboratory, 1995

    SciTech Connect (OSTI)

    Cross, S.; Nottelman, H.

    1997-01-01

    The Biology Team of ESH-20 (the Ecology Group) at Los Alamos National Laboratory (LANL) has collected samples from the stream within Sandia Canyon since the summer of 1990. These field studies measure water quality parameters and collect aquatic macroinvertebrates from sampling sites within the upper canyon stream. Reports by Bennett and Cross discuss previous aquatic studies in Sandia Canyon. This report updates and expands the previous findings. The Biology Team collected water quality data and aquatic macroinvertebrates monthly at three sampling stations within Sandia Canyon in 1995. The two upstream stations occur near a cattail (Typha latifolia) dominated marsh downstream from outfalls that discharge industrial and sanitary waste effluent into the stream, thereby maintaining year-round flow. The third station is approximately 1.5 miles downstream from the outfalls within a mixed conifer forest. All water chemistry parameters measured in Sandia Canyon during 1995 fell within acceptable State limits and scored in the {open_quotes}good{close_quotes} or {open_quotes}excellent{close_quotes} ranges when compared to an Environmental Quality Index. However, aquatic macroinvertebrates habitats have been degraded by widespread erosion, channelization, loss of wetlands due to deposition and stream lowering, scour, limited acceptable substrates, LANL releases and spills, and other stressors. Macroinvertebrate communities at all the stations had low diversities, low densities, and erratic numbers of individuals. These results indicate that although the stream possesses acceptable water chemistry, it has reduced biotic potential. The best developed aquatic community occurs at the sampling station with the best habitat and whose downstream location partially mitigates the effects of upstream impairments.

  13. Bio-energy feedstock yields and their water quality benefits in Mississippi

    SciTech Connect (OSTI)

    Parajuli, Prem B.

    2011-08-10

    Cellulosic and agricultural bio-energy crops can, under careful management, be harvested as feedstock for bio-fuels production and provide environmental benefits. However, it is required to quantify their relative advantages in feedstock production and water quality. The primary objective of this research was to evaluate potential feedstock yield and water quality benefit scenarios of bioenergy crops: Miscanthus (Miscanthus-giganteus), Switchgrass (Panicum virgatum), Johnsongrass (Sorghum halepense), Alfalfa (Medicago sativa L.), Soybean {Glycine max (L.) Merr.}, and Corn (Lea mays) in the Upper Pearl River watershed (UPRW), Mississippi using a Soil and Water Assessment Tool (SWAT). The SWAT model was calibrated (January 1981 to December 1994) and validated (January 1995 to September 2008) using monthly measured stream flow data. The calibrated and validated model determined good to very good performance for stream flow prediction (R2 and E from 0.60 to 0.86). The RMSE values (from 14 m3 s-1 to 37 m3 s-1) were estimated at similar levels of errors during model calibration and validation. The long-term average annual potential feedstock yield as an alternative energy source was determined the greatest when growing Miscanthus grass (373,849 Mg) as followed by Alfalfa (206,077 Mg), Switchgrass (132,077 Mg), Johnsongrass (47,576 Mg), Soybean (37,814 Mg), and Corn (22,069 Mg) in the pastureland and cropland of the watershed. Model results determined that average annual sediment yield from the Miscanthus grass scenario determined the least (1.16 Mg/ha) and corn scenario the greatest (12.04 Mg/ha). The SWAT model simulated results suggested that growing Miscanthus grass in the UPRW would have the greatest potential feedstock yield and water quality benefits.

  14. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-01-01

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  15. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-12-31

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  16. Electric double layer at metal oxide surfaces: Static properties of the cassiterite - Water Interface

    SciTech Connect (OSTI)

    Vlcek, Lukas; Zhang, Zhan; Machesky, Michael L.; Wesolowski, David J

    2007-04-01

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn

  17. Electric double layer at metal oxide surfaces:static properties of the cassiterite-water interface.

    SciTech Connect (OSTI)

    Vlcek, L.; Zhang, Z.; Machesky, M .L.; Fenter, P.; Rosenqvist, J.; Wesolowski, D. J.; Anovitz, L. M.; Predota, M.; Cummings, P. T.; Vanderbilt Univ.; ORNL; Univ. of South Bohimia; Illinois State Water Survey

    2007-03-24

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn

  18. Water Quality Sampling Locations Along the Shoreline of the Columbia River, Hanford Site, Washington

    SciTech Connect (OSTI)

    Peterson, Robert E.; Patton, Gregory W.

    2009-12-14

    As environmental monitoring evolved on the Hanford Site, several different conventions were used to name or describe location information for various sampling sites along the Hanford Reach of the Columbia River. These methods range from handwritten descriptions in field notebooks to the use of modern electronic surveying equipment, such as Global Positioning System receivers. These diverse methods resulted in inconsistent archiving of analytical results in various electronic databases and published reports because of multiple names being used for the same site and inaccurate position data. This document provides listings of sampling sites that are associated with groundwater and river water sampling. The report identifies names and locations for sites associated with sampling: (a) near-river groundwater using aquifer sampling tubes; (b) riverbank springs and springs areas; (c) pore water collected from riverbed sediment; and (d) Columbia River water. Included in the listings are historical names used for a particular site and the best available geographic coordinates for the site, as of 2009. In an effort to create more consistency in the descriptive names used for water quality sampling sites, a naming convention is proposed in this document. The convention assumes that a unique identifier is assigned to each site that is monitored and that this identifier serves electronic database management requirements. The descriptive name is assigned for the convenience of the subsequent data user. As the historical database is used more intensively, this document may be revised as a consequence of discovering potential errors and also because of a need to gain consensus on the proposed naming convention for some water quality monitoring sites.

  19. Development of An Empirical Water Quality Model for Stormwater Based on Watershed Land Use in Puget Sound

    SciTech Connect (OSTI)

    Cullinan, Valerie I.; May, Christopher W.; Brandenberger, Jill M.; Judd, Chaeli; Johnston, Robert K.

    2007-03-29

    The Sinclair and Dyes Inlet watershed is located on the west side of Puget Sound in Kitsap County, Washington, U.S.A. (Figure 1). The Puget Sound Naval Shipyard (PSNS), U.S Environmental Protection Agency (USEPA), the Washington State Department of Ecology (WA-DOE), Kitsap County, City of Bremerton, City of Bainbridge Island, City of Port Orchard, and the Suquamish Tribe have joined in a cooperative effort to evaluate water-quality conditions in the Sinclair-Dyes Inlet watershed and correct identified problems. A major focus of this project, known as Project ENVVEST, is to develop Water Clean-up (TMDL) Plans for constituents listed on the 303(d) list within the Sinclair and Dyes Inlet watershed. Segments within the Sinclair and Dyes Inlet watershed were listed on the State of Washington’s 1998 303(d) because of fecal coliform contamination in marine water, metals in sediment and fish tissue, and organics in sediment and fish tissue (WA-DOE 2003). Stormwater loading was identified by ENVVEST as one potential source of sediment contamination, which lacked sufficient data for a contaminant mass balance calculation for the watershed. This paper summarizes the development of an empirical model for estimating contaminant concentrations in all streams discharging into Sinclair and Dyes Inlets based on watershed land use, 18 storm events, and wet/dry season baseflow conditions between November 2002 and May 2005. Stream pollutant concentrations along with estimates for outfalls and surface runoff will be used in estimating the loading and ultimately in establishing a Water Cleanup Plan (TMDL) for the Sinclair-Dyes Inlet watershed.

  20. Clean Water Act and Regulations (EPA)

    Broader source: Energy.gov [DOE]

    The Clean Water Act (CWA; 33 U.S.C. §1251 et seq.) establishes the basic structure for regulating discharges of pollutants into the waters of the United States and regulating quality standards for surface waters.

  1. 2009-10 "Convene a Panel of Water Quality Experts" | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 "Convene a Panel of Water Quality Experts" 2009-10 "Convene a Panel of Water Quality Experts" The intent of this recommendation is to help the DOE and LANL to maintain good relations with oversight agencies, such as the EPA, and to keep the general public fully informed of the ongoing cleanup of legacy wastes at LANL. Rec 2009-10 - September 30, 2009 (145.42

  2. Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface Radar and Satellite Data in Support of ARM SCM Activities

    SciTech Connect (OSTI)

    Liu, Guosheng

    2013-03-15

    -D cloud ice water contents in support of cloud modeling activities. The approach of the study is to expand a (surface) point measurement to an (satellite) area measurement. That is, the study takes the advantage of the high quality cloud measurements (particularly cloud radar and microwave radiometer measurements) at the point of the ARM sites. We use the cloud ice water characteristics derived from the point measurement to guide/constrain a satellite retrieval algorithm, then use the satellite algorithm to derive the 3-D cloud ice water distributions within an 10° (latitude) x 10° (longitude) area. During the research period, we have developed, validated and improved our cloud ice water retrievals, and have produced and archived at ARM website as a PI-product of the 3-D cloud ice water contents using combined satellite high-frequency microwave and surface radar observations for SGP March 2000 IOP and TWP-ICE 2006 IOP over 10 deg. x 10 deg. area centered at ARM SGP central facility and Darwin sites. We have also worked on validation of the 3-D ice water product by CloudSat data, synergy with visible/infrared cloud ice water retrievals for better results at low ice water conditions, and created a long-term (several years) of ice water climatology in 10 x 10 deg. area of ARM SGP and TWP sites and then compared it with GCMs.

  3. September 2015 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site

    Office of Legacy Management (LM)

    Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site February 2016 LMS/SHP/S00915 This page intentionally left blank U.S. Department of Energy DVP-September 2015, Shiprock, New Mexico February 2016 RINs 15097348 and 15097349 Page i Contents Sampling Event Summary ...............................................................................................................1 Planned Sampling Map Shiprock, New Mexico, Disposal Site

  4. January 2016 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Processing Site

    Office of Legacy Management (LM)

    6 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Processing Site March 2016 LMS/GJT/S00116 This page intentionally left blank U.S. Department of Energy DVP-January 2016, Grand Junction, Colorado March 2016 RIN 15127576 Page i Contents Sampling Event Summary ...............................................................................................................1 Grand Junction, Colorado, Processing Site, Sample Location Map

  5. July 2015 Groundwater and Surface Water Sampling at the Naturita, Colorado, Processing Site

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Naturita, Colorado, Processing Site October 2015 LMS/NAP/S00715 This page intentionally left blank U.S. Department of Energy DVP-July 2015, Naturita, Colorado October 2015 RIN 15077222 Page i Contents Sampling Event Summary ...............................................................................................................1 Data Assessment Summary

  6. November 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites February 2016 LMS/RFN/RFO/S01115 This page intentionally left blank U.S. Department of Energy DVP-November 2015, Rifle, Colorado February 2016 RINs 15107463 and 15107464 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Planned Sampling Map

  7. West Village Community: Quality Management Processes and Preliminary Heat Pump Water Heater Performance

    SciTech Connect (OSTI)

    Dakin, B.; Backman, C.; Hoeschele, M.; German, A.

    2012-11-01

    West Village, a multi-use project underway at the University of California Davis, represents a ground-breaking sustainable community incorporating energy efficiency measures and on-site renewable generation to achieve community-level Zero Net Energy (ZNE) goals. The project when complete will provide housing for students, faculty, and staff with a vision to minimize the community's impact on energy use by reducing building energy use, providing on-site generation, and encouraging alternative forms of transportation. This focus of this research is on the 192 student apartments that were completed in 2011 under Phase I of the West Village multi-year project. The numerous aggressive energy efficiency measures implemented result in estimated source energy savings of 37% over the B10 Benchmark. There are two primary objectives of this research. The first is to evaluate performance and efficiency of the central heat pump water heaters as a strategy to provide efficient electric water heating for net-zero all-electric buildings and where natural gas is not available on site. In addition, effectiveness of the quality assurance and quality control processes implemented to ensure proper system commissioning and to meet program participation requirements is evaluated. Recommendations for improvements that could improve successful implementation for large-scale, high performance communities are identified.

  8. West Village Community. Quality Management Processes and Preliminary Heat Pump Water Heater Performance

    SciTech Connect (OSTI)

    Dakin, B.; Backman, C.; Hoeschele, M.; German, A.

    2012-11-01

    West Village, a multi-use project underway at the University of California Davis, represents a ground-breaking sustainable community incorporating energy efficiency measures and on-site renewable generation to achieve community-level Zero Net Energy (ZNE) goals. When complete, the project will provide housing for students, faculty, and staff with a vision to minimize the community’s impact on energy use by reducing building energy use, providing on-site generation, and encouraging alternative forms of transportation. This focus of this research is on the 192 student apartments that were completed in 2011 under Phase I of the West Village multi-year project. The numerous aggressive energy efficiency measures implemented result in estimated source energy savings of 37% over the B10 Benchmark. There are two primary objectives of this research. The first is to evaluate performance and efficiency of the central heat pump water heaters as a strategy to provide efficient electric water heating for net-zero all-electric buildings and where natural gas is not available on site. In addition, effectiveness of the quality assurance and quality control processes implemented to ensure proper system commissioning and to meet program participation requirements is evaluated. Recommendations for improvements that could improve successful implementation for large-scale, high performance communities are identified.

  9. Water balance in the Amazon basin from a land surface model ensemble

    SciTech Connect (OSTI)

    Getirana, Augusto; Dutra, Emanuel; Guimberteau, Matthieu; Kam, Jonghun; Li, Hongyi; Decharme, Bertrand; Zhang, Zhengqiu J.; Ducharne, Agnes; Boone, Aaron; Balsamo, Gianpaolo; Rodell, Matthew; Mounirou Toure, Ally; Xue, Yongkang; Peters-Lidard, Christa D.; Kumar, Sujay V.; Arsenault, Kristi Rae; Drapeau, Guillaume; Leung, Lai-Yung R.; Ronchail, Josyane; Sheffield, Justin

    2014-12-06

    Despite recent advances in modeling and remote sensing of land surfaces, estimates of the global water budget are still fairly uncertain. The objective of this study is to evaluate the water budget of the Amazon basin based on several state-of-the-art land surface model (LSM) outputs. Water budget variables [total water storage (TWS), evapotranspiration (ET), surface runoff (R) and baseflow (B)] are evaluated at the basin scale using both remote sensing and in situ data. Fourteen LSMs were run using meteorological forcings at a 3-hourly time step and 1-degree spatial resolution. Three experiments are performed using precipitation which has been rescaled to match monthly global GPCP and GPCC datasets and the daily HYBAM dataset for the Amazon basin. R and B are used to force the Hydrological Modeling and Analysis Platform (HyMAP) river routing scheme and simulated discharges are compared against observations at 165 gauges. Simulated ET and TWS are compared against FLUXNET and MOD16A2 evapotranspiration, and GRACE TWS estimates in different catchments. At the basin scale, simulated ET ranges from 2.39mm.d-1 to 3.26mm.d-1 and a low spatial correlation between ET and P indicates that evapotranspiration does not depend on water availability over most of the basin. Results also show that other simulated water budget variables vary significantly as a function of both the LSM and precipitation used, but simulated TWS generally agree at the basin scale. The best water budget simulations resulted from experiments using the HYBAM dataset, mostly explained by a denser rainfall gauge network the daily rescaling.

  10. River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zachara, John M.; Chen, Xingyuan; Murray, Chris; Hammond, Glenn

    2016-03-04

    A well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. As a result of water tablemore » elevation fluctuations, river water intrusion, and changes in groundwater flow directions, time series trends for Uaq and SpC were found to be complex and displayed large temporal and well-to-well variability. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in Uaq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized Uaq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. Moreover, while Uaq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

  11. River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zachara, John M.; Chen, Xingyuan; Murray, Chris; Hammond, Glenn

    2016-03-04

    In this study, a well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time series trendsmore » for Uaq and SpC were complex and displayed large temporal and well-to-well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in Uaq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized Uaq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While Uaq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

  12. Tuning the interaction between propagating and localized surface plasmons for surface enhanced Raman scattering in water for biomedical and environmental applications

    SciTech Connect (OSTI)

    Shioi, Masahiko; Jans, Hilde; Lodewijks, Kristof; Van Dorpe, Pol; Lagae, Liesbet; Kawamura, Tatsuro

    2014-06-16

    With a view to biomedical and environmental applications, we investigate the plasmonic properties of a rectangular gold nanodisk array in water to boost surface enhanced Raman scattering (SERS) effects. To control the resonance wavelengths of the surface plasmon polariton and the localized surface plasmon, their dependence on the array period and diameter in water is studied in detail using a finite difference time domain method. A good agreement is obtained between calculated resonant wavelengths and those of gold nanodisk arrays fabricated using electron beam lithography. For the optimized structure, a SERS enhancement factor of 7.8 × 10{sup 7} is achieved in water experimentally.

  13. Effects of uranium-mining releases on ground-water quality in the Puerco River Basin, Arizona and New Mexico

    SciTech Connect (OSTI)

    Van Metre, P.C.; Wirt, L.; Lopes, T.J.; Ferguson, S.A.

    1997-12-31

    The purpose of this report is to describe: (1) the water quality of the Puerco River alluvial aquifer, (2) the movement of water between the Puerco River and underlying alluvial aquifer, and (3) changes in the water quality of the alluvial and bedrock aquifers related to releases of contaminants by uranium-mining activities. This report focuses on the alluvial aquifer near the reach of the Puerco River that was subjected to continuous flow containing mine-dewatering effluents and to flow containing mine-dewatering effluents and to flow from the tailings-pond spill.

  14. Surface modification of cellulose acetate membrane using thermal annealing to enhance produced water treatment

    SciTech Connect (OSTI)

    Kusworo, T. D. Aryanti, N. Firdaus, M. M. H.; Sukmawati, H.

    2015-12-29

    This study is performed primarily to investigate the effect of surface modification of cellulose acetate using thermal annealing on the enhancement of membrane performance for produced water treatment. In this study, Cellulose Acetate membranes were casted using dry/wet phase inversion technique. The effect of additive and post-treatment using thermal annealing on the membrane surface were examined for produced water treatment. Therma annealing was subjected to membrane surface at 60 and 70 °C for 5, 10 and 15 second, respectively. Membrane characterizations were done using membrane flux and rejection with produced water as a feed, Scanning Electron Microscopy (SEM) and Fourier Transform Infra Red (FTIR) analysis. Experimental results showed that asymmetric cellulose acetate membrane can be made by dry/wet phase inversion technique. The results from the Scanning Electron Microscopy (FESEM) analysis was also confirmed that polyethylene glycol as additivie in dope solution and thermal annealing was affected the morphology and membrane performance for produced water treatment, respectively. Scanning electron microscopy micrographs showed that the selective layer and the substructure of membrane became denser and more compact after the thermal annealing processes. Therefore, membrane rejection was significantly increased while the flux was slighty decreased, respectively. The best membrane performance is obtained on the composition of 18 wt % cellulose acetate, poly ethylene glycol 5 wt% with thermal annealing at 70° C for 15 second.

  15. Surface Quality of Ti-6%Al-4%V ELI When Machined Using CVD-Carbide Tools at High Cutting Speed

    SciTech Connect (OSTI)

    Gusri, A. I.; Che Hassan, C. H.; Jaharah, A. G.; Yasir, A.; Zaid, Y.; Yanuar, B.

    2011-01-17

    Machining of Ti-6Al-4V ELI becomes more interested topic due to extremely weight-to-strength ratio and resistance to corrosion at elevated temperature. Quality of machined surface is presented by surface roughness, surface texture and damages of microstructure of titanium alloys. The turning parameters evaluated are cutting speed of 55-95 m/min, feed rate of 0.15-0.35 mm/rev, depth of cut of 0.10-0.20 mm and tool grade of CVD carbide tools. The results show the trend lines of surface roughness value are higher at the initial machining and the surface texture profile has a strong correlation with the feed rate. At the machining condition of cutting speed of 95 m/min, feed rate of 0.35 mm/rev and depth of cut of 0.10 mm produced the with layer with thickness of 2.0 {mu}m.

  16. May 2012 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2012-12-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 9-10, 2012, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the site boundaries have not been affected by project-related contaminants.

  17. May 2011 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2011-12-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 16-17, 2011, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed by the U.S. Environmental Protection Agency (EPA) Radiation&Indoor Environments National Laboratory in Las Vegas, Nevada. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry, and for tritium using the conventional method. Tritium was not measured using the enrichment method because the EPA laboratory no longer offers that service. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the boundaries have not been affected by project-related contaminants.

  18. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river drainage, USA

    SciTech Connect (OSTI)

    Jager, Henriette I.; Baskaran, Latha M.; Schweizer, Peter E.; Turhollow, Anthony F.; Brandt, Craig C.; Srinivasan, Raghavan

    2014-05-15

    We study that the mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remain a significant concern for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.

  19. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river basin, USA

    SciTech Connect (OSTI)

    Jager, Yetta; Brandt, Craig C; Baskaran, Latha Malar; Srinivasan, Raghavan; Turhollow Jr, Anthony F; Schweizer, Peter E

    2015-01-01

    The mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remain a significant concern for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.

  20. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river drainage, USA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jager, Henriette I.; Baskaran, Latha M.; Schweizer, Peter E.; Turhollow, Anthony F.; Brandt, Craig C.; Srinivasan, Raghavan

    2014-05-15

    We study that the mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remainmore » a significant concern for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.« less

  1. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river basin, USA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jager, Yetta; Brandt, Craig C; Baskaran, Latha Malar; Srinivasan, Raghavan; Turhollow Jr, Anthony F; Schweizer, Peter E

    2015-01-01

    The mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remain a significant concernmore » for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.« less

  2. Elements of an environmental decision support system for seasonal wetland salt management in a river basin subjected to water quality regulation

    SciTech Connect (OSTI)

    Quinn, N.W.T.

    2009-06-01

    Seasonally managed wetlands in the Grasslands Basin on the west-side of California's San Joaquin Valley provide food and shelter for migratory wildfowl during winter months and sport for waterfowl hunters during the annual duck season. Surface water supply to these wetlands contain salt which, when drained to the San Joaquin River during the annual drawdown period, can negatively impact water quality and cause concern to downstream agricultural riparian water diverters. Recent environmental regulation, limiting discharges salinity to the San Joaquin River and primarily targeting agricultural non-point sources, now also targets return flows from seasonally managed wetlands. Real-time water quality management has been advocated as a means of continuously matching salt loads discharged from agricultural, wetland and municipal operations to the assimilative capacity of the San Joaquin River. Past attempts to build environmental monitoring and decision support systems (EDSS's) to implement this concept have enjoyed limited success for reasons that are discussed in this paper. These reasons are discussed in the context of more general challenges facing the successful implementation of a comprehensive environmental monitoring, modelling and decision support system for the San Joaquin River Basin.

  3. Raman spectroscopy of solutions and interfaces containing nitrogen dioxide, water, and 1,4 dioxane: Evidence for repulsion of surface water by NO{sub 2} gas

    SciTech Connect (OSTI)

    Murdachaew, Garold; Varner, Mychel E.; Veer, Wytze E. van der; Gerber, R. Benny; Phillips, Leon F.

    2014-05-14

    The interaction of water, 1,4 dioxane, and gaseous nitrogen dioxide, has been studied as a function of distance measured through the liquid-vapour interface by Raman spectroscopy with a narrow (<0.1 mm) laser beam directed parallel to the interface. The Raman spectra show that water is present at the surface of a dioxane-water mixture when gaseous NO{sub 2} is absent, but is virtually absent from the surface of a dioxane-water mixture when gaseous NO{sub 2} is present. This is consistent with recent theoretical calculations that show NO{sub 2} to be mildly hydrophobic.

  4. Application of Hotelling’s T{sup 2} charts in monitoring quality parameters in a drinking water supply system

    SciTech Connect (OSTI)

    Costa, Mafalda T.; Carolino, Elisabete; Oliveira, Teresa A.

    2015-03-10

    In water supply systems with distribution networkthe most critical aspects of control and Monitoring of water quality, which generates crises system, are the effects of cross-contamination originated by the network typology. The classics of control of quality systems through the application of Shewhart charts are generally difficult to manage in real time due to the high number of charts that must be completed and evaluated. As an alternative to the traditional control systems with Shewhart charts, this study aimed to apply a simplified methodology of a monitoring plan quality parameters in a drinking water distribution, by applying Hotelling’s T{sup 2} charts and supplemented with Shewhart charts with Bonferroni limits system, whenever instabilities with processes were detected.

  5. The ecological evaluation of surface water outfalls at a manufacturing plant in New Jersey

    SciTech Connect (OSTI)

    Harman, C.R.; Gilchrist, W.

    1995-12-31

    Historic metal machining operations at a manufacturing plant in northern New Jersey had resulted in the contamination of three surface water outfalls leading from the plant to a second-order stream used for trout fishing. The outfalls were fed by a combination of non-contact cooling water, stormwater runoff and groundwater infiltration. The outfalls ranged in length from 180 meters to 600 meters. All three of the outfalls pass through forested wetland areas and contained emergent wetland pockets. The ecological evaluation consisted of the collection of sediment samples to evaluate the extent of chemical contamination and the evaluation of the biological integrity of a portion of the surface water outfalls. Additionally, an ecological characterization of the surrounding habitat was prepared. Sediment sampling indicated elevated concentrations of antimony, cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc. Nickel concentrations were the most significant, with concentrations ranging up to 9,850 mg/kg. PCB concentrations ranged between 0.45 mg/kg and 6.4 mg/kg. Elevated concentrations of metals and PCBs were detected to a sediment depth of 45 centimeters. To evaluate the potential for biological impacts from the metals in the sediments, a modified Rapid Bioassessment Protocol 1 evaluation was conducted on the macroinvertebrate population. The results of the evaluation indicated a very sparse macroinvertebrate community. Those organisms that were identified were typical of highly contaminated surface water system. The surrounding wetland systems appeared to be unaffected by the outfall contamination. Based on the results of the first phase of the ecological evaluation, a program of additional sediment sampling and further biological evaluation was prepared.

  6. 2009-12 "Hold a Planned DOE-EM Meeting on LANL Water Quality Programs in a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Northern New Mexico Location" | Department of Energy 2 "Hold a Planned DOE-EM Meeting on LANL Water Quality Programs in a Northern New Mexico Location" 2009-12 "Hold a Planned DOE-EM Meeting on LANL Water Quality Programs in a Northern New Mexico Location" The NNMCAB recommends that DOE-EM open the special meeting with Mr. Gilkeson to the public and change the location for the meeting to one of the Northern New Mexico communities, such as Los Alamos or Espanola. Rec

  7. Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems (DE-EE0002961)

    SciTech Connect (OSTI)

    Spitler, J. D.; Culling, J. R.; Conjeevaram, K.; Ramesh, M.; Selvakumar, M.

    2012-11-30

    Ground-source heat pump (GSHP) systems are perhaps the most widely used “sustainable” heating and cooling systems, with an estimated 1.7 million installed units with total installed heating capacity on the order of 18 GW. They are widely used in residential, commercial, and institutional buildings. Standing column wells (SCW) are one form of ground heat exchanger that, under the right geological conditions, can provide excellent energy efficiency at a relatively low capital cost. Closed-loop surface water heat pump (SWHP) systems utilize surface water heat exchangers (SWHE) to reject or extract heat from nearby surface water bodies. For building near surface water bodies, these systems also offer a high degree of energy efficiency at a low capital cost. However, there have been few design tools available for properly sizing standing column wells or surface water heat exchangers. Nor have tools for analyzing the energy consumption and supporting economics-based design decisions been available. The main contributions of this project lie in providing new tools that support design and energy analysis. These include a design tool for sizing surface water heat exchangers, a design tool for sizing standing column wells, a new model of surface water heat pump systems implemented in EnergyPlus and a new model of standing column wells implemented in EnergyPlus. These tools will better help engineers design these systems and determine the economic and technical feasibility.

  8. Apparatus and procedure to characterize the surface quality of conductors by measuring the rate of cathode emission as a function of surface electric field strength

    DOE Patents [OSTI]

    Mestayer, Mac; Christo, Steve; Taylor, Mark

    2014-10-21

    A device and method for characterizing quality of a conducting surface. The device including a gaseous ionizing chamber having centrally located inside the chamber a conducting sample to be tested to which a negative potential is applied, a plurality of anode or "sense" wires spaced regularly about the central test wire, a plurality of "field wires" at a negative potential are spaced regularly around the sense, and a plurality of "guard wires" at a positive potential are spaced regularly around the field wires in the chamber. The method utilizing the device to measure emission currents from the conductor.

  9. Surface Water Transport for the F/H Area Seepage Basins Groundwater Program

    SciTech Connect (OSTI)

    Chen, Kuo-Fu

    1995-08-29

    The contribution of the F- and H-Area Seepage Basins (FHSBs) tritium releases to the tritium concentration in the Savannah River are presented in this report. WASP5 was used to simulate surface water transport for tritium releases from the FHSBs. The WASP5 model was qualified with the 1993 tritium measurements at US Highway 301. The tritium concentrations in Fourmile Branch and the Savannah River were calculated for tritium releases from FHSBs. The calculated tritium concentrations above normal environmental background in the Savannah River, resulting from FHSBs releases, drop from 1.25 pCi/ml (<10% of EPA Drinking Water Guide) in 1995 to 0.0056 pCi/ml in 2045.

  10. Influences of Peat, Surface and Subsurface Water, and Snow on Active Layer Thickness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Atchley, Adam; Coon, Ethan T.; Painter, Scott L; Harp, Dylan; Wilson, Cathy

    2016-01-01

    The effect of three environmental conditions: 1) thickness of organic soil, 2) snow depth, and 3) soil moisture content or water table height above and below the soil surface, on active layer thickness (ALT) are investigated using an ensemble of 1D thermal hydrology models. Sensitivity analyses of the ensemble exposed the isolated influence of each environmental condition on ALT and their multivariate interactions. The primary and interactive influences are illustrated in the form of color maps of ALT change. Results show that organic layer acts as a strong insulator, and its thickness is the dominant control of ALT, but themore » strength of the effect of organic layer thickness is dependent on the saturation state. Snow depth, subsurface saturation, and ponded water depth are strongly codependent and positively correlated to ALT.« less

  11. Overview of groundwater and surface water standards pertinent to the Idaho National Engineering Laboratory. Revision 3

    SciTech Connect (OSTI)

    Lundahl, A.L.; Williams, S.; Grizzle, B.J.

    1995-09-01

    This document presents an overview of groundwater- and surface water-related laws, regulations, agreements, guidance documents, Executive Orders, and DOE orders pertinent to the Idaho National Engineering Laboratory. This document is a summary and is intended to help readers understand which regulatory requirements may apply to their particular circumstances. However, the document is not intended to be used in lieu of applicable regulations. Unless otherwise noted, the information in this report reflects a summary and evaluation completed July 1, 1995. This document is considered a Living Document, and updates on changing laws and regulations will be provided.

  12. May 2013 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2013-10-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 14-16, 2013, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location CER #1 Black Sulphur. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods.

  13. Quantifying the impacts of land surface schemes and dynamic vegetation on the model dependency of projected changes in surface energy and water budgets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Miao; Wang, Guiling; Chen, Haishan

    2016-03-01

    Assessing and quantifying the uncertainties in projected future changes of energy and water budgets over land surface are important steps toward improving our confidence in climate change projections. In our study, the contribution of land surface models to the inter-GCM variation of projected future changes in land surface energy and water fluxes are assessed based on output from 19 global climate models (GCMs) and offline Community Land Model version 4 (CLM4) simulations driven by meteorological forcing from the 19 GCMs. Similar offline simulations using CLM4 with its dynamic vegetation submodel are also conducted to investigate how dynamic vegetation feedback, amore » process that is being added to more earth system models, may amplify or moderate the intermodel variations of projected future changes. Projected changes are quantified as the difference between the 2081–2100 period from the Representative Concentration Pathway 8.5 (RCP8.5) future experiment and the 1981–2000 period from the historical simulation. Under RCP8.5, projected changes in surface water and heat fluxes show a high degree of model dependency across the globe. Although precipitation is very likely to increase in the high latitudes of the Northern Hemisphere, a high degree of model-related uncertainty exists for evapotranspiration, soil water content, and surface runoff, suggesting discrepancy among land surface models (LSMs) in simulating the surface hydrological processes and snow-related processes. Large model-related uncertainties for the surface water budget also exist in the Tropics including southeastern South America and Central Africa. Moreover, these uncertainties would be reduced in the hypothetical scenario of a single near-perfect land surface model being used across all GCMs, suggesting the potential to reduce uncertainties through the use of more consistent approaches toward land surface model development. Under such a scenario, the most significant reduction is likely to

  14. Effect of Cu2+ Activation on Interfacial Water Structure at the Sphalerite Surface as Studied by Molecular Dynamics Simulation

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.; Wick, Collin D.

    2015-12-10

    In the first part of this paper, an experimental contact angle study of the fresh and Cu2+ activated sphalerite-ZnS surface as well as the covellite-CuS (001) surface is reported describing the increased hydrophobic character of the surface during Cu2+ activation. In addition to these experimental results, the fresh sphalerite-ZnS (110), copper-zinc sulfide-CuZnS2 (110), villamaninite- CuS2 (100), and covellite-CuS (001) surfaces were examined using Molecular Dynamics Simulation (MDS). Our MDS results on the behavior of interfacial water at the fresh sphalerite-ZnS (110), copper-zinc sulfide-CuZnS2 (110), villamaninite-CuS2 (100), and covellite-CuS (001) surfaces include simulated contact angles, water number density distribution, water dipole orientation, water residence time, and hydrogen-bonding considerations. The copper content at the Cu2+ activated sphalerite surface seems to account for the increased hydrophobicity as revealed by both experimental and MD simulated contact angle measurements. The relatively greater hydrophobic character developed at the Cu2+ activated sphalerite surface and at the copper-zinc sulfide surface has been described by MDS, based on the structure of interfacial water and its dynamic properties. L.X.D. acknowledges funding from the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

  15. Spatiotemporal nonpoint source pollution water quality management framework using bi-directional model-GIS linkage

    SciTech Connect (OSTI)

    Faizullabhoy, M.S.; Yoon, J.

    1999-07-01

    A framework for water quality assessment and management purposes was developed. In this framework, a bilateral linkage was implemented between the distributed model, Agricultural Nonpoint Source Pollution Model (AGNPS) and the Geographic Information System (GIS) to investigate a spatiotemporal nonpoint source pollution problem from a 750-acre watershed in the NSGA (Naval Security Group Activity) Northwest base at the Virginia/North Carolina border. AGNPS is an event-based, distributed parameter model that simulates runoff and the transport of sediment and nutrients (nitrogen and phosphorus) from predominantly agricultural watersheds. In this study rather than manually implementing AGNPS simulation, extracted data are integrated in an automated fashion through a direct bilateral linkage framework between the AGNPS model engine and the GIS. This bilateral linkage framework resulted in a powerful, up-to-date tool that would be capable of monitoring and instantaneously visualizing the transport of any pollutant as well as effectively identifying critical areas of the nonpoint source (NPS) pollution. The framework also allowed the various what if scenarios to support the decision-making processes. Best Management Practices (BMP) for the watershed can be generated in a close loop iterative scheme, until predefined management objectives are achieved. Simulated results showed that the optimal BMP scenario achieved an average reduction of about 41% in soluble and sediment-attached nitrogen and about 62% reduction in soluble and sediment phosphorus from current NPS pollution levels.

  16. Water quality evaluation and geochemical assessment of iron, manganese, and arsenic in a landfill site

    SciTech Connect (OSTI)

    Pisigan, R.A. Jr.

    1995-12-31

    Several monitoring wells at a landfill site were sampled for water quality parameters to determine the nature of groundwater contamination. The landfill, located beneath a limestone and dolomitic bedrock, has been used for about 20 years for trash and garbage disposal. The monitoring parameters include major cations and anions, as well as iron, manganese, arsenic, and other parameters measured in the field to characterize the subsurface conditions. Groundwater samples collected near the landfill and downgradient locations had higher levels of iron, manganese, arsenic, alkalinity, hardness than those samples from an upgradient well. The downgradient and on-site samples were also more acidic and turbid, The dissolved oxygen data tend to suggest reducing conditions in the leachate environment. The elevated groundwater concentrations of the three metals, especially iron, were most probably caused by the acidity generated by carbon dioxide and organic acids released from microbial degradation of organic compounds dumped into the landfill. The acidic pH led to the dissolution of iron, manganese, and arsenic bearing mineral phases. The buffering reactions of limestone and dolomite to neutralize the acidic degradation products increased the hardness cations, Ca{sup +2} and Mg{sup +2}. Inorganic speciation modeling indicates that iron, manganese, and arsenic predominantly exist as Fe {sup +2}, Mn{sup +2}, and H{sub 3}AsO{sub 3}. The possible presence of organic complexes of iron was discussed, but could be modeled due to lack of appropriate equilibrium constant data.

  17. Evaluation of surface water treatment and discharge options for the Weldon Spring Site Remedial Action Project

    SciTech Connect (OSTI)

    Goyette, M.L.; MacDonell, M.M.

    1992-09-01

    The US Department of Energy (DOE), under its Environmental Restoration and Waste Management Program, is responsible for conducting response actions at the Weldon Spring site in St. Charles County, Missouri. The site consists of two noncontiguous areas: (1) the chemical plant area, which includes four raffinate pits and two small ponds, and (2) a 3.6-ha (9-acre) quarry located about 6.4 km (4 mi) southwest of the chemical plant area. Both of these areas became chemically and radioactively contaminated as a result of processing and disposal activities that took place from the 1940s through 1960s. The Weldon Spring site, located about 48 km (30 mi) west of St. Louis, is listed on the National Priorities List of the US Environmental Protection Agency. Nitroaromatic explosives were processed by the Army at the chemical plant area during the 1940s, and radioactive materials were processed by DOE`s predecessor agency (the Atomic Energy Commission) during the 1950s and 1960s. Overall remediation of the Weldon Spring site is being addressed through the Weldon Spring Site Remedial Action Project, and it consists of several components. One component is the management of radioactively and chemically contaminated surface water impoundments at the chemical plant area -- i.e., the four raffinate pits, Frog Pond, and Ash Pond which was addressed under a separate action and documented in an engineering evaluation/cost analysis report. This report discusses the evaluation of surface water treatment at the Weldon Spring site.

  18. TRITIUM UNCERTAINTY ANALYSIS FOR SURFACE WATER SAMPLES AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Atkinson, R.

    2012-07-31

    Radiochemical analyses of surface water samples, in the framework of Environmental Monitoring, have associated uncertainties for the radioisotopic results reported. These uncertainty analyses pertain to the tritium results from surface water samples collected at five locations on the Savannah River near the U.S. Department of Energy's Savannah River Site (SRS). Uncertainties can result from the field-sampling routine, can be incurred during transport due to the physical properties of the sample, from equipment limitations, and from the measurement instrumentation used. The uncertainty reported by the SRS in their Annual Site Environmental Report currently considers only the counting uncertainty in the measurements, which is the standard reporting protocol for radioanalytical chemistry results. The focus of this work is to provide an overview of all uncertainty components associated with SRS tritium measurements, estimate the total uncertainty according to ISO 17025, and to propose additional experiments to verify some of the estimated uncertainties. The main uncertainty components discovered and investigated in this paper are tritium absorption or desorption in the sample container, HTO/H{sub 2}O isotopic effect during distillation, pipette volume, and tritium standard uncertainty. The goal is to quantify these uncertainties and to establish a combined uncertainty in order to increase the scientific depth of the SRS Annual Site Environmental Report.

  19. Surface water drainage system. Environmental assessment and finding of no significant impact

    SciTech Connect (OSTI)

    1996-05-01

    This Environmental Assessment (EA) is written pursuant to the National Environmental Policy Act (NEPA). The document identifies and evaluates the action proposed to correct deficiencies in, and then to maintain, the surface water drainage system serving the Department of Energy`s Rocky Flats Environmental Technology Site (Site), located north of Golden, Colorado. Many of the activities proposed would not normally be subject to this level of NEPA documentation. However, in many cases, maintenance of the system has been deferred to the point that wetlands vegetation has become established in some ditches and culverts, creating wetlands. The proposed activities would damage or remove some of these wetlands in order to return the drainage system to the point that it would be able to fully serve its intended function - stormwater control. The Department of Energy (DOE) regulations require that activities affecting environmentally sensitive areas like wetlands be the subject of an EA. Most portions of the surface water drainage system are presently inadequate to convey the runoff from a 100-year storm event. As a result, such an event would cause flooding across much of the Site and possibly threaten the integrity of the dams at the terminal ponds. Severe flooding would not only cause damage to facilities and equipment, but could also facilitate the transport of contaminants from individual hazardous substance sites (IHSSs). Uncontrolled flow through the A- and B-series ponds could cause contaminated sediments to become suspended and carried downstream. Additionally, high velocity flood flows significantly increase erosion losses.

  20. Projected Changes in Mean and Interannual Variability of Surface Water over Continental China

    SciTech Connect (OSTI)

    Leng, Guoyong; Tang, Qiuhong; Huang, Maoyi; Hong, Yang; Leung, Lai-Yung R.

    2015-05-01

    Five General Circulation Model (GCM) climate projections under the RCP8.5 emission scenario were used to drive the Variable Infiltration Capacity (VIC) hydrologic model to investigate the impacts of climate change on hydrologic cycle over continental China in the 21st century. The bias-corrected climatic variables were generated for the Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR5) by the Inter-Sectoral Impact Model Intercomparison Project (ISI-MIP). Results showed much larger fractional changes of annual mean Evaportranspiration (ET) per unit warming than the corresponding fractional changes of Precipitation (P) per unit warming across the country especially for South China, which led to notable decrease of surface water variability (P-E). Specifically, negative trends for annual mean runoff up to -0.33%/decade and soil moisture trends varying between -0.02 to -0.13%/decade were found for most river basins across China. Coincidentally, interannual variability for both runoff and soil moisture exhibited significant positive trends for almost all river basins across China, implying an increase in extremes relative to the mean conditions. Noticeably, the largest positive trends for runoff variability and soil moisture variability, which were up to 38 0.41%/decade and 0.90%/decade, both occurred in Southwest China. In addition to the regional contrast, intra-seasonal variation was also large for the runoff mean and runoff variability changes, but small for the soil moisture mean and variability changes. Our results suggest that future climate change could further exacerbate existing water-related risks (e.g. floods and droughts) across China as indicated by the marked decrease of surface water amounts combined with steady increase of interannual variability throughout the 21st century. This study highlights the regional contrast and intra-seasonal variations for the projected hydrologic changes and could provide muti

  1. Molecular dynamics study of saltsolution interface: Solubility and surface charge of salt in water

    SciTech Connect (OSTI)

    Kobayashi, Kazuya; Liang, Yunfeng E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Matsuoka, Toshifumi E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Sakka, Tetsuo

    2014-04-14

    The NaCl saltsolution interface often serves as an example of an uncharged surface. However, recent laser-Doppler electrophoresis has shown some evidence that the NaCl crystal is positively charged in its saturated solution. Using molecular dynamics (MD) simulations, we have investigated the NaCl saltsolution interface system, and calculated the solubility of the salt using the direct method and free energy calculations, which are kinetic and thermodynamic approaches, respectively. The direct method calculation uses a saltsolution combined system. When the system is equilibrated, the concentration in the solution area is the solubility. In the free energy calculation, we separately calculate the chemical potential of NaCl in two systems, the solid and the solution, using thermodynamic integration with MD simulations. When the chemical potential of NaCl in the solution phase is equal to the chemical potential of the solid phase, the concentration of the solution system is the solubility. The advantage of using two different methods is that the computational methods can be mutually verified. We found that a relatively good estimate of the solubility of the system can be obtained through comparison of the two methods. Furthermore, we found using microsecond time-scale MD simulations that the positively charged NaCl surface was induced by a combination of a sodium-rich surface and the orientation of the interfacial water molecules.

  2. Method for formation of high quality back contact with screen-printed local back surface field

    DOE Patents [OSTI]

    Rohatgi, Ajeet; Meemongkolkiat, Vichai

    2010-11-30

    A thin silicon solar cell having a back dielectric passivation and rear contact with local back surface field is described. Specifically, the solar cell may be fabricated from a crystalline silicon wafer having a thickness from 50 to 500 micrometers. A barrier layer and a dielectric layer are applied at least to the back surface of the silicon wafer to protect the silicon wafer from deformation when the rear contact is formed. At least one opening is made to the dielectric layer. An aluminum contact that provides a back surface field is formed in the opening and on the dielectric layer. The aluminum contact may be applied by screen printing an aluminum paste having from one to 12 atomic percent silicon and then applying a heat treatment at 750 degrees Celsius.

  3. Correlation of Oil-Water and Air-Water Contact Angles of Diverse Silanized Surfaces and Relationship to Fluid Interfacial Tensions

    SciTech Connect (OSTI)

    Grate, Jay W.; Dehoff, Karl J.; Warner, Marvin G.; Pittman, Jonathan W.; Wietsma, Thomas W.; Zhang, Changyong; Oostrom, Martinus

    2012-02-24

    The use of air-water, {Theta}{sub wa}, or air-liquid contact angles is customary in surface science, while oil-water contact angles {Theta}{sub ow}, are of paramount importance in subsurface multiphase flow phenomena including petroleum reocovery, nonaqueous phase liquid fate and transport, and geological carbon sequestration. In this paper we determine both the air-water and oil-water contact angles of silica surfaces modified with a diverse selection of silanes, using hexadecane as the oil. The silanes included alkylsilanes, alkylarylsilanes, and silanes with alkyl or aryl groups that are functionalized with heteroatoms such as N, O, and S. These silanes yielded surfaces with wettabilities from water-wet to oil wet, including specific silanized surfaces functionalized with heteroatoms that yield intermediate wet surfaces. The oil-water contact angles for clean and silanized surfaces, excluding one partially fluorinated surface, correlate linearly with air-water contact angles with a slope of 1.41 (R = 0.981, n = 13). These data were used to examine a previously untested theoretical treatment relating air-water and oil-water contact angles in terms of fluid interfacial energies. Plotting the cosines of these contact angles against one another, we obtain a linear relationship in excellent agreement with the theoretical treatment; the data fit cos {Theta}{sub ow} = 0.667 cos {Theta}{sub ow} + 0.384 (R = 0.981, n = 13), intercepting cos {Theta}{sub ow} = -1 at -0.284. The theoretical slope, based on the fluid interfacial tensions {Theta}{sub wa}, {Theta}{sub ow}, and {Theta}{sub oa}, is 0.67. We also demonstrate how silanes can be used to alter the wettability of the interior of a pore network micromodel device constructed in silicon/silica with a glass cover plate. Such micromodels are used to study multiphase flow phenomena. The contact angle of the resulting interior was determined in situ. An intermediate wet micromodel gave a contact angle in excellent agreement

  4. Effects of coal fly-ash disposal on water quality in and around the Indiana Dunes National Lakeshore, Indiana. Water-resources investigations (final)

    SciTech Connect (OSTI)

    Hardy, M.A.

    1981-04-01

    Dissolved constituents in seepage from fly-ash settling ponds bordering part of the Indiana Dunes National Lakeshore (the Lakeshore) have increased trace elements, and gross alpha and gross beta radioactivity in ground water and surface water downgradient from the settling ponds. Data suggest that concentrations of some dissolved trace elements may be greater beneath interdunal pond 2 than in the pond. The soil system downgradient from the settling ponds seems to have affected the concentrations of dissolved ions in the settling-pond seepage. Calcium concentrations were greater in ground water downgradient from the settling ponds than in the ponds. Where organic material was present downgradient from the settling ponds, concentrations of arsenic, fluoride, molybdenum, potassium, sulfate, and strontium were greater in the ground water than in the ponds. In contrast, the concentrations of cadmium, copper, nickel, aluminum, cobalt, lead, and zinc were less.

  5. Partial oxidation of landfill leachate in supercritical water: Optimization by response surface methodology

    SciTech Connect (OSTI)

    Gong, Yanmeng; Wang, Shuzhong; Xu, Haidong; Guo, Yang; Tang, Xingying

    2015-09-15

    Highlights: • Partial oxidation of landfill leachate in supercritical water was investigated. • The process was optimized by Box–Behnken design and response surface methodology. • GY{sub H2}, TRE and CR could exhibit up to 14.32 mmol·gTOC{sup −1}, 82.54% and 94.56%. • Small amounts of oxidant can decrease the generation of tar and char. - Abstract: To achieve the maximum H{sub 2} yield (GY{sub H2}), TOC removal rate (TRE) and carbon recovery rate (CR), response surface methodology was applied to optimize the process parameters for supercritical water partial oxidation (SWPO) of landfill leachate in a batch reactor. Quadratic polynomial models for GY{sub H2}, CR and TRE were established with Box–Behnken design. GY{sub H2}, CR and TRE reached up to 14.32 mmol·gTOC{sup −1}, 82.54% and 94.56% under optimum conditions, respectively. TRE was invariably above 91.87%. In contrast, TC removal rate (TR) only changed from 8.76% to 32.98%. Furthermore, carbonate and bicarbonate were the most abundant carbonaceous substances in product, whereas CO{sub 2} and H{sub 2} were the most abundant gaseous products. As a product of nitrogen-containing organics, NH{sub 3} has an important effect on gas composition. The carbon balance cannot be reached duo to the formation of tar and char. CR increased with the increase of temperature and oxidation coefficient.

  6. Real-Time Water Quality Monitoring and Habitat Assessment in theSan Luis National Wildlife Refuge

    SciTech Connect (OSTI)

    Quinn, Nigel W.T.; Hanlon, Jeremy S.; Burns, Josephine R.; Stromayer, Karl A.K.; Jordan, Brandon M.; Ennis, Mike J.; Woolington,Dennis W.

    2005-08-28

    The project report describes a two year experiment to control wetland drainage to the San Joaquin River of California from the San Luis National Wildlife Refuge using a decision support system for real-time water quality management. This system required the installation and operation of one inlet and three drainage flow and water quality monitoring stations which allowed a simple mass balance model to be developed of the seasonally managed wetlands in the study area. Remote sensing methods were developed to document long-term trends in wetland moist soil vegetation and soil salinity in response to management options such as delaying the initiation of seasonal wetland drainage. These environmental management tools provide wetland managers with some of the tools necessary to improve salinity conditions in the San Joaquin River and improve compliance with State mandated salinity objectives without inflicting long-term harm on the wild fowl habitat resource.

  7. Assessment of Dissolved Oxygen Mitigation at Hydropower Dams Using an Integrated Hydrodynamic/Water Quality/Fish Growth Model

    SciTech Connect (OSTI)

    Bevelhimer, Mark S; Coutant, Charles C

    2006-07-01

    Dissolved oxygen (DO) in rivers is a common environmental problem associated with hydropower projects. Approximately 40% of all FERC-licensed projects have requirements to monitor and/or mitigate downstream DO conditions. Most forms of mitigation for increasing DO in dam tailwaters are fairly expensive. One area of research of the Department of Energy's Hydropower Program is the development of advanced turbines that improve downstream water quality and have other environmental benefits. There is great interest in being able to predict the benefits of these modifications prior to committing to the cost of new equipment. In the case of turbine replacement or modification, there is a need for methods that allow us to accurately extrapolate the benefits derived from one or two turbines with better design to the replacement or modification of all turbines at a site. The main objective of our study was to demonstrate a modeling approach that integrates the effects of flow and water quality dynamics with fish bioenergetics to predict DO mitigation effectiveness over long river segments downstream of hydropower dams. We were particularly interested in demonstrating the incremental value of including a fish growth model as a measure of biological response. The models applied are a suite of tools (RMS4 modeling system) originally developed by the Tennessee Valley Authority for simulating hydrodynamics (ADYN model), water quality (RQUAL model), and fish growth (FISH model) as influenced by DO, temperature, and available food base. We parameterized a model for a 26-mile reach of the Caney Fork River (Tennessee) below Center Hill Dam to assess how improvements in DO at the dam discharge would affect water quality and fish growth throughout the river. We simulated different types of mitigation (i.e., at the turbine and in the reservoir forebay) and different levels of improvement. The model application successfully demonstrates how a modeling approach like this one can be used

  8. Polycyclic aromatic hydrocarbons in surface waters of Alessandria District, South Eastern Piedmont (Italy)

    SciTech Connect (OSTI)

    Trova, C.; Cossa, G.; Gandolfo, G.

    1992-10-01

    Polynuclear aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants. Because of the high toxicity of some polycyclic compounds, such as benzopyrenes, the determination of their levels in air, water, soil and aquatic organisms was the object of several papers. Anthropogenic pyrolitic and combustion processes, related to industrial plants, domestic heating, automobile traffic, are the major sources of these compounds; from these sources they enter atmospheric environment where their concentration is reduced by scavenging during precipitation events: rain, snow and fog in urban areas usually show high contents of PAHs. Dry and wet atmospheric polluted depositions effluents transport appreciable amounts of PAHs to aquatic environment, where they are rapidly taken up and accumulated by both fish and shellfish. Alessandria District, in South-Eastern Piedmont (Italy), lies in the middle of Torino-Milano-Genova industrial area: in addition to local sources, a relatively long range transport of polluted air masses may conduct to this region atmospheric contaminants, such as polynuclear compounds, that can enter fluvial environments through meteoric precipitation. The object of this work was to evaluate PAH content in surface waters flowing across the described territory. Samplings were carried on during winter season, when the concentration of these pollutants usually reaches the highest levels. 8 refs., 4 figs., 2 tabs.

  9. System for collecting products dumped on the surface of a mass of water

    SciTech Connect (OSTI)

    Carro, F.J.

    1982-06-01

    A system for collecting products dumped on the surface of a mass of water includes cages to be arranged at the sides of a tanker. Each cage is preferably prismatic in shape. The height of the cages is such that when the tanker is at ballast, the lower parts of the cages will be submerged while the upper parts will be above the maximum loading line of the tanker. The cages are fastened to the sides of the tanker by freely rotating connection points. In the interiors of the cages is housed a series of floating suction pump inlet members or housings, likewise prismatic in shape, having appropriate dimensions to permit a great sensitivity to the least fluctuating movements of the liquid surface. The complete face of each suction pump inlet member, which is oriented in the direction of travel of the tanker, is provided with an opening which has a height such that the lower edge thereof will be positioned below the floating line of the suction pumps at an approximate depth of 0.01 meter.

  10. Surface and bulk crystallization of amorphous solid water films: Confirmation of “top-down” crystallization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yuan, Chunqing; Smith, R. Scott; Kay, Bruce D.

    2016-01-11

    Here, the crystallization kinetics of nanoscale amorphous solid water (ASW) films are investigated using temperature-programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS). TPD measurements are used to probe surface crystallization and RAIRS measurements are used to probe bulk crystallization. Isothermal TPD results show that surface crystallization is independent of the film thickness (from 100 to 1000 ML). Conversely, the RAIRS measurements show that the bulk crystallization time increases linearly with increasing film thickness. These results suggest that nucleation and crystallization begin at the ASW/vacuum interface and then the crystallization growth front propagates linearly into the bulk. This mechanism wasmore » confirmed by selective placement of an isotopic layer (5% D2O in H2O) at various positions in an ASW (H2O) film. In this case, the closer the isotopic layer was to the vacuum interface, the earlier the isotopic layer crystallized. These experiments provide direct evidence to confirm that ASW crystallization in vacuum proceeds by a “top-down” crystallization mechanism.« less