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Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Hydrogen Production from Thermocatalytic Hydrogen Sulfide Decomposition  

Science Journals Connector (OSTI)

Experimental data on hydrogen production from hydrogen sulfide decomposition over various solid catalysts at ... The possibilities given by surface modification by vacuum methods (electron beam evaporation and ma...

O. K. Alexeeva

2002-01-01T23:59:59.000Z

2

CODE OF PRACTICE HYDROGEN SULFIDE  

E-Print Network [OSTI]

. The Immediately Dangerous to Life and Health concentration of 100 ppm has been established by the National Institute for Occupational Safety and Health (NIOSH). Table 1: Health Affects from Short-Term Exposure to Hydrogen Sulfide (reproduced from: Hydrogen Sulphide at the Work Site, Alberta Workplace Health & Safety

Machel, Hans

3

REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN  

E-Print Network [OSTI]

REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM TEXAS A&M UNIVERSITY;PREFACE Attached is the "REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN" that will be used for ODP coring and drilling operations on legs where hydrogen sulfide is likely to be encountered. Prior

4

CODE OF PRACTICE HYDROGEN SULFIDE  

E-Print Network [OSTI]

.E.L) is 10 parts per million (ppm) for 8 hours and 15 ppm as a ceiling limit. The Immediately Dangerous to Life and Health concentration of 100 ppm has been established by the National Institute for Occupational Safety and Health (NIOSH). Table 1: Health Affects from Short-Term Exposure to Hydrogen Sulfide

Machel, Hans

5

Giant Hydrogen Sulfide Plume in the Oxygen Minimum Zone off Peru Supports Chemolithoautotrophy  

E-Print Network [OSTI]

Giant Hydrogen Sulfide Plume in the Oxygen Minimum Zone off Peru Supports Chemolithoautotrophy sporadically accumulate hydrogen sulfide (H2S), which is toxic to most multicellular organisms and has been feedback loop that could fuel further sulfate reduction and potentially stabilize the sulfidic OMZ waters

Boyer, Edmond

6

Thiophene Hydrogenation to Tetrahydrothiophene over Tungsten Sulfide Catalysts  

Science Journals Connector (OSTI)

Independent reactions of thiophene reduction to tetrahydrothiophene and thiophene hydrogenolysis to form hydrogen sulfide...4...hydrocarbons are shown to occur over supported tungsten sulfide catalysts and unsupp...

A. V. Mashkina

2003-03-01T23:59:59.000Z

7

Hydrogen Production from Hydrogen Sulfide in IGCC Power Plants  

SciTech Connect (OSTI)

IGCC power plants are the cleanest coal-based power generation facilities in the world. Technical improvements are needed to help make them cost competitive. Sulfur recovery is one procedure in which improvement is possible. This project has developed and demonstrated an electrochemical process that could provide such an improvement. IGCC power plants now in operation extract the sulfur from the synthesis gas as hydrogen sulfide. In this project H{sub 2}S has been electrolyzed to yield sulfur and hydrogen (instead of sulfur and water as is the present practice). The value of the byproduct hydrogen makes this process more cost effective. The electrolysis has exploited some recent developments in solid state electrolytes. The proof of principal for the project concept has been accomplished.

Elias Stefanakos; Burton Krakow; Jonathan Mbah

2007-07-31T23:59:59.000Z

8

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network [OSTI]

HYDROGEN AND SULFUR PRODUCTION FROM HYDROGEN SULFIDE WASTES? John B.L. Harkness and Richard D. Doctor, Argonne National Laboratory, Argonne. IL ABSTRACT A new hydrogen sulfide waste-treatment process that uses microwave plasma... to be economically competitive. In addition, the experiments show-that. typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology. BACKGROUND In 1987, Argonne staff found the first...

Harkness, J.; Doctor, R. D.

9

Electrodeposited Cobalt-Sulfide Catalyst for Electrochemical and Photoelectrochemical Hydrogen Generation from Water  

E-Print Network [OSTI]

the use of strong acids and bases, thus reducing their environmental impact and increasing Generation from Water Yujie Sun,,,, Chong Liu,, David C. Grauer,, Junko Yano, Jeffrey R. Long,*,, Peidong, and long-term aqueous stability, offer promising features for potential use in solar energy applications

10

Kinetic study of hydrogen sulfide absorption in aqueous chlorine solution  

E-Print Network [OSTI]

). This technique involves H2S mass transfer in an aqueous phase using a gas-liquid contactor. Since H2S is poorly. This scrubbing liquid is just drained when the salt accumulation due to H2S oxidation into sulfate anions becomes Hydrogen sulfide (H2S) is currently removed from gaseous effluents by chemical scrubbing using water

Paris-Sud XI, Université de

11

The selective adsorption of hydrogen sulfide from natural gas streams  

E-Print Network [OSTI]

, and Mr. Ovid Baker of Magnolia Petroleum Company. The author also wishes to thank the Linde Company for ths Molecular Sieve type adsorbents and technical information on the same. He also wishes to thank Mr. R. D. Henley and We Magnolia Petroleum... Effect of Water Vapor on Adsorptive Capacity of Bed. 31 Table VI Abbreviated Comparison of Adsorbents. 32 INTRODUCTIOM INTRODUC TION The separation of mercaptans and hydrogen sulfide from natural gas produced from sour reservoirs is a problem which...

Fails, James Clayton

2012-06-07T23:59:59.000Z

12

Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Chloride and Hydrogen Sulfide Hydrogen Chloride and Hydrogen Sulfide Removal Sorbents for High Temperature Gas Streams Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,767,000 entitled "Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams." Disclosed in this patent is the invention of a unique regenerable sorbent process that can remove contaminants from gas produced by the gasification of fossil fuels. Specifically, the process removes hydrogen chloride by using the regenerable sorbent and simultaneously extracts hydrogen chloride compounds and hydrogen

13

Gas-Phase Thiophene Hydrogenation to Tetrahydrothiophene over Sulfide Catalysts  

Science Journals Connector (OSTI)

Thiophene hydrogenation to tetrahydrothiophene over supported transition metal sulfides is studied....T = 240°C and P...= 2 MPa showed that aluminosilicate-supported PdS is one to two orders of magnitude more act...

A. V. Mashkina; L. G. Sakhaltueva

2002-01-01T23:59:59.000Z

14

A study of the reactions of arsinic and arsonic acids with hydrogen sulfide and hydrogen selenide  

E-Print Network [OSTI]

A STUDY OF THE REACTIONS OF ARSINIC AND ARSONIC ACIDS WITH HYDROGEN SULFIDE AND HYDROGEN SELENIDE by CYNTHIA ANNETTE APPLEGATE Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1986 Major Subject: Chemistry A STUDY OF THE REACTIONS OF ARSINIC AND ARSONIC ACIDS WITH HYDROGEN SULFIDE AND HYDROGEN SELENIDE A Thesis by CYNTHIA ANNETTE APPLEGATE Approved as to style and content by: Ralph A. ngaro...

Applegate, Cynthia Annette

2012-06-07T23:59:59.000Z

15

Quantitative evaluation of hydrogen sulfide at 0.3 M and 1.0 M-hydrogen-ion concentration  

E-Print Network [OSTI]

. In the present study, cobalt sulfide was quantitatively re? covered from a solution whose hydrogen-ion concentration -12was calculated to be 6.95 x 10 M. As in the case of zinc sulfide, this was to be expected, since a decreased hydrogen-ion concentration... quantitatively to an electrolysis beaker with distilled water. The copper 28 was deposited on a platinum gauze cathode in 9 hours from a solution containing a 5 ml. excess of 18 M sulfuric acid in 125 ml., and a current of 0.5 ampere. 12. Copper (II) - Zinc...

Machel, Albert R.

1958-01-01T23:59:59.000Z

16

ARTICLE IN PRESS Modeling hydrogen sulfide emissions across the gas liquid interface  

E-Print Network [OSTI]

production methods in the US have led to the emergence of large- scale commeARTICLE IN PRESS Modeling hydrogen sulfide emissions across the gas­ liquid interface-film theory Hydrogen sulfide Process-based model Lagoon flux Mass transfer a b s t r a c t Hydrogen sulfide (H

Aneja, Viney P.

17

Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst  

SciTech Connect (OSTI)

Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

McGuiggan, M.F.; Kuch, P.L.

1984-05-08T23:59:59.000Z

18

Toxic sulfide concentrations in the sediments and water column of the Suwannee River estuary and its influence on hard clam survival  

E-Print Network [OSTI]

Toxic sulfide concentrations in the sediments and water column of the Suwannee River estuary that is grown to market size in estuarine sediments. Hydrogen sulfide, a natural metabolic poison known of hard clams used in field aquaculture areas in the Suwannee River estuary. Sulfide was found in sediment

Florida, University of

19

The HYSULF{sup SM} process: A valuable hydrogen resource from hydrogen sulfide  

SciTech Connect (OSTI)

The increasing demand for hydrogen to reduce the sulfur content in standard refinery fuels is a very familiar problem to everyone in the industry. This problem could be partially offset by the continuous recycling of the hydrogen portion of hydrogen sulfide. In this regard, Marathon has been developing the HYSULF process. This process uses Redox chemistry under mild operating conditions to convert hydrogen sulfide into hydrogen and sulfur. The process employs two basic steps, i.e., a sulfur production and recovery step and a hydrogen production step. All chemicals and the catalyst used in the HYSULF process are either commercially available or are slight modifications of available materials. Also, the chemistry used in the HYSULF process is similar to that used in commercial desulfurization and gas sweetening processes.

Plummer, M.A. [Marathon Oil Co., Littleton, CO (United States)

1995-09-01T23:59:59.000Z

20

Atmospheric Environment 42 (2008) 33153331 Measurement and analysis of ammonia and hydrogen sulfide  

E-Print Network [OSTI]

; Hydrogen sulfide; Swine barns; CAFOs 1. Introduction Changes in livestock production methods in the USAtmospheric Environment 42 (2008) 3315­3331 Measurement and analysis of ammonia and hydrogen, where NH3­N ¼ (14 17)NH3) and hydrogen sulfide (H2S) were measured from a finishing swine confinement

Aneja, Viney P.

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Hydrogen sulfide spatial distribution and exposure in deep-pit swine housing.  

E-Print Network [OSTI]

??The objectives of this research focus on investigating spatial distribution of hydrogen sulfide gas associated with manure removal and agitation events in deep-pit swine production… (more)

Swestka, Randy John

2010-01-01T23:59:59.000Z

22

Removal of Hydrogen Sulfide from Landfill Gas Using a Solar Regenerable Adsorbent.  

E-Print Network [OSTI]

??Landfill gas is a complex mix of gases, containing methane, carbon dioxide, nitrogen and hydrogen sulfide, created by the action of microorganisms within the landfill.… (more)

Kalapala, Sreevani

2014-01-01T23:59:59.000Z

23

Photoelectrochemical Hydrogen Production on InP Nanowire Arrays with Molybdenum Sulfide Electrocatalysts  

Science Journals Connector (OSTI)

Photoelectrochemical Hydrogen Production on InP Nanowire Arrays with Molybdenum Sulfide Electrocatalysts ... Several semiconductor nanowire systems, synthesized by different methods, have been investigated by photoelectrochemistry. ... power available from the hydrogen produced and the power supplied by an external source. ...

Lu Gao; Yingchao Cui; Jia Wang; Alessandro Cavalli; Anthony Standing; Thuy T. T. Vu; Marcel A. Verheijen; Jos E. M. Haverkort; Erik P. A. M. Bakkers; Peter H. L. Notten

2014-05-29T23:59:59.000Z

24

HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana  

E-Print Network [OSTI]

HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana , L. A. Wiseb , S for the poisoning kinetics of hydrogen sulfide (H2S) on composite solid polymer electrolyte Pt (SPE-Pt) electrode) fuel cells, there is much less in the literature on H2S poisoning. Uribe et al showed

Sethuraman, Vijay A.

25

Turning Sun and Water Into Hydrogen Fuel | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel May 5, 2011 - 1:27pm Addthis Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D. Damsgaard, Thomas Pedersen and Ole Hansen, Technical University of Denmark Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D.

26

Turning Sun and Water Into Hydrogen Fuel | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel May 5, 2011 - 1:27pm Addthis Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D. Damsgaard, Thomas Pedersen and Ole Hansen, Technical University of Denmark Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D.

27

Modeling of Syngas Reactions and Hydrogen Generation Over Sulfides  

SciTech Connect (OSTI)

The objective of the research is to analyze pathways of reactions of hydrogen with oxides of carbon over sulfides, and to predict which characteristics of the sulfide catalyst (nature of metal, defect structure) give rise to the lowest barriers toward oxygenated hydrocarbon product. Reversal of these pathways entails the generation of hydrogen, which is also proposed for study. In this first year of study, adsorption reactions of H atoms and H{sub 2} molecules with MoS{sub 2}, both in molecular and solid form, have been modeled using high-level density functional theory. The geometries and strengths of the adsorption sites are described and the methods used in the study are described. An exposed MO{sup IV} species modeled as a bent MoS{sub 2} molecule is capable of homopolar dissociative chemisorption of H{sub 2} into a dihydride S{sub 2}MoH{sub 2}. Among the periodic edge structures of hexagonal MoS{sub 2}, the (1{bar 2}11) edge is most stable but still capable of dissociating H{sub 2}, while the basal plane (0001) is not. A challenging task of theoretically accounting for weak bonding of MoS{sub 2} sheets across the Van der Waals gap has been addressed, resulting in a weak attraction of 0.028 eV/MoS{sub 2} unit, compared to the experimental value of 0.013 eV/MoS{sub 2} unit.

Kamil Klier; Jeffery A. Spirko; Michael L. Neiman

2002-09-17T23:59:59.000Z

28

Methods for producing hydrogen (BI) sulfide and/or removing metals  

DOE Patents [OSTI]

The present invention is a process wherein sulfide production by bacteria is efficiently turned on and off, using pH adjustment. The adjustment of pH impacts sulfide production by bacteria by altering the relative amounts of H.sub.2 S and HS-- in solution and thereby control the inhibition of the bacterial metabolism that produces sulfide. This process can be used to make a bioreactor produce sulfide "on-demand" so that the production of sulfide can be matched to its use as a metal precipitation reagent. The present invention is of significance because it enables the use of a biological reactor, a cost effective sulfide production system, by making the biological reactor produce hydrogen sulfide "on demand", and therefore responsive to production schedules, waste stream generation rate, and health and safety requirements/goals.

Truex, Michael J [Richland, WA; Peyton, Brent M [Pullman, WA; Toth, James J [Kennewick, WA

2002-05-14T23:59:59.000Z

29

Metal?organic frameworks for the storage and delivery of biologically active hydrogen sulfide  

SciTech Connect (OSTI)

Hydrogen sulfide is an extremely toxic gas that is also of great interest for biological applications when delivered in the correct amount and at the desired rate. Here we show that the highly porous metal-organic frameworks with the CPO-27 structure can bind the hydrogen sulfide relatively strongly, allowing the storage of the gas for at least several months. Delivered gas is biologically active in preliminary vasodilation studies of porcine arteries, and the structure of the hydrogen sulfide molecules inside the framework has been elucidated using a combination of powder X-ray diffraction and pair distribution function analysis.

Allan, Phoebe K.; Wheatley, Paul S.; Aldous, David; Mohideen, M. Infas; Tang, Chiu; Hriljac, Joseph A.; Megson, Ian L.; Chapman, Karena W.; De Weireld, Guy; Vaesen, Sebastian; Morris, Russell E. (St Andrews)

2012-04-02T23:59:59.000Z

30

Corrosion of iron in acid solutions with hydrogen sulfide  

SciTech Connect (OSTI)

The influence of pH and the concentration of hydrogen sulfide (H{sub 2}S) on corrosion of iron in acid solutions was studied using a potentiostatic polarization method. The alternating current (AC) impedance technique also was used to characterize the active dissolution process of iron. Results showed the dissolution process was accelerated by H{sub 2}S. The anodic dissolution current (i{sub a}) increased with pH and H{sub 2}S concentration with reaction orders of about n{sub pH} = n{sub H{sub 2}s} = 0.25 when the ratio of H{sub 2}S concentration and hydrogen ion (H{sub 3}O{sup +}) concentration was <10{sup 1.5} i{sub a} reached a maximum and became independent of pH and [H{sub 2}S] when [H{sub 2}S]/H{sub 3}O{sup +} > 10{sup 1.5}. The Nyquist diagram corresponding to the active dissolution process in the Tafel range exhibited two capacitive loops in addition to the well-known, high-frequency capacitive loop. A mechanism was proposed to explain the results in which H{sub 2}S chemisorbed first on the electrode surface and then catalyzed the anodic dissolution of iron in two discharging steps.

Cheng, X.L.; Ma, H.Y.; Zhang, J.P.; Chen, X.; Chen, S.H. [Shandong Univ., Jinan (China). Dept. of Chemistry; Yang, H.Q. [Peking Univ. (China). Dept. of Chemistry

1998-05-01T23:59:59.000Z

31

Water's Hydrogen Bond Strength  

E-Print Network [OSTI]

Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

Martin Chaplin

2007-06-10T23:59:59.000Z

32

Journal of Power Sources 135 (2004) 184191 A solid oxide fuel cell system fed with hydrogen sulfide  

E-Print Network [OSTI]

Journal of Power Sources 135 (2004) 184­191 A solid oxide fuel cell system fed with hydrogen for a solid oxide fuel cell (SOFC). This paper presents an examination of a simple hydrogen sulfide and natural gas-fed solid oxide fuel cell system. The possibility of utilization of hydrogen sulfide

33

Single Membrane Reactor Configuration for Separation of Hydrogen, Carbon Dioxide and Hydrogen Sulfide  

SciTech Connect (OSTI)

The objective of the project was to develop a novel complementary membrane reactor process that can consolidate two or more downstream unit operations of a coal gasification system into a single module for production of a pure stream of hydrogen and a pure stream of carbon dioxide. The overall goals were to achieve higher hydrogen production efficiencies, lower capital costs and a smaller overall footprint than what could be achieved by utilizing separate components for each required unit process/operation in conventional coal-to-hydrogen systems. Specifically, this project was to develop a novel membrane reactor process that combines hydrogen sulfide removal, hydrogen separation, carbon dioxide separation and water-gas shift reaction into a single membrane configuration. The carbon monoxide conversion of the water-gas-shift reaction from the coal-derived syngas stream is enhanced by the complementary use of two membranes within a single reactor to separate hydrogen and carbon dioxide. Consequently, hydrogen production efficiency is increased. The single membrane reactor configuration produces a pure H{sub 2} product and a pure CO{sub 2} permeate stream that is ready for sequestration. This project focused on developing a new class of CO{sub 2}-selective membranes for this new process concept. Several approaches to make CO{sub 2}-selective membranes for high-temperature applications have been tested. Membrane disks using the technique of powder pressing and high temperature sintering were successfully fabricated. The powders were either metal oxide or metal carbonate materials. Experiments on CO{sub 2} permeation testing were also performed in the temperature range of 790 to 940 C for the metal carbonate membrane disks. However, no CO{sub 2} permeation rate could be measured, probably due to very slow CO{sub 2} diffusion in the solid state carbonates. To improve the permeation of CO{sub 2}, one approach is to make membranes containing liquid or molten carbonates. Several different types of dual-phase membranes were fabricated and tested for their CO{sub 2} permeation in reducing conditions without the presence of oxygen. Although the flux was quite low, on the order of 0.01-0.001 cc STP/cm{sup 2}/min, the selectivity of CO{sub 2}/He was almost infinite at temperatures of about 800 C. A different type of dual-phase membrane prepared by Arizona State University (ASU) was also tested at GTI for CO{sub 2} permeation. The measured CO{sub 2} fluxes were 0.015 and 0.02 cc STP/cm{sup 2}/min at 750 and 830 C, respectively. These fluxes were higher than the previous flux obtained ({approx}0.01 cc STP/cm{sup 2}/min) using the dual-phase membranes prepared by GTI. Further development in membrane development should be conducted to improve the CO{sub 2} flux. ASU has also focused on high temperature permeation/separation experiments to confirm the carbon dioxide separation capabilities of the dual-phase membranes with La{sup 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF6482) supports infiltrated with a Li/Na/K molten carbonate mixture (42.5/32.5/25.0 mole %). The permeation experiments indicated that the addition of O{sub 2} does improve the permeance of CO{sub 2} through the membrane. A simplified membrane reactor model was developed to evaluate the performance of the process. However, the simplified model did not allow the estimation of membrane transport area, an important parameter for evaluating the feasibility of the proposed membrane reactor technology. As a result, an improved model was developed. Results of the improved membrane reactor model show that the membrane shift reaction has promise as a means to simplify the production of a clean stream of hydrogen and a clean stream of carbon dioxide. The focus of additional development work should address the large area required for the CO{sub 2} membrane as identified in the modeling calculations. Also, a more detailed process flow diagram should be developed that includes integration of cooling and preheating feed streams as well as particulate removal so that stea

Micheal Roberts; Robert Zabransky; Shain Doong; Jerry Lin

2008-05-31T23:59:59.000Z

34

Hydrogen Cars and Water Vapor  

E-Print Network [OSTI]

. This cycle is currently under way with hydrogen fuel cells. As fuel cell cars are suggested as a solutionHydrogen Cars and Water Vapor D.W.KEITHANDA.E.FARRELL'S POLICY FORUM "Rethinking hydrogen cars" (18 misidentified as "zero-emissions vehicles." Fuel cell vehicles emit water vapor. A global fleet could have

Colorado at Boulder, University of

35

High-Temperature Nano-Derived Micro-Hydrogen Sulfide Sensors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Temperature Nano-Derived Micro- Temperature Nano-Derived Micro- Hydrogen and -Hydrogen Sulfide Sensors Background The Department of Energy (DOE) National Energy Technology Laboratory (NETL) seeks applications for the University Coal Research (UCR) Program to further develop the understanding of coal utilization. Since the program's inception in 1979, its primary objectives have been to (1) improve our understanding of the chemical and physical processes involved in the conversion and utilization of coal in an environmentally

36

Turing Water into Hydrogen Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

so, coat with water, and add sunshine. What do you get? In theory, energy-rich hydrogen produced by photolysis-a process by which water molecules placed on a catalytic surface...

37

Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1997-01-01T23:59:59.000Z

38

Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1999-01-01T23:59:59.000Z

39

Turing Water into Hydrogen Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Turning Water into Turning Water into Hydrogen Fuel Turning Water into Hydrogen Fuel New method creates highly reactive catalytic surface, packed with hydroxyl species May 15, 2012 | Tags: Franklin, Materials Science NERSC Contact: Linda Vu, lvu@lbl.gov, +1 510 495 2402 PNNL Contacts: Loel Kathmann, Loel.Kathmann@pnnl.gov, +1 509 371 6068 Artwork from this catalysis research graced the cover of Physical Chemistry Chemical Physics. Image reproduced by permission of Dr Igor Lyubinetsky and the PCCP Owner Societies from Phys. Chem. Chem. Phys. 2012. Build a surface of titanium and oxygen atoms arranged just so, coat with water, and add sunshine. What do you get? In theory, energy-rich hydrogen produced by photolysis-a process by which water molecules placed on a catalytic surface and exposed to sunlight (electromagnetic radiation) are

40

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant  

E-Print Network [OSTI]

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

Gates, Kent. S.

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases  

SciTech Connect (OSTI)

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

2001-11-06T23:59:59.000Z

42

Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors  

SciTech Connect (OSTI)

A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

2014-10-14T23:59:59.000Z

43

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-11-25T23:59:59.000Z

44

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-01-21T23:59:59.000Z

45

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

46

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

47

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

48

Water Electrolysis and Solar Hydrogen Demonstration Projects  

Science Journals Connector (OSTI)

In this chapter, nearly all conventional and newly developed processes for water electrolysis will be considered, and an overview of ... After a brief historical description of hydrogen, water electrolysis, and s...

Gerd Sandstede; Reinhold Wurster

1995-01-01T23:59:59.000Z

49

Supercritical Water Desulfurization of Organic Sulfides Is Consistent with Free-Radical Kinetics  

Science Journals Connector (OSTI)

Pushkaraj R. Patwardhan †, Michael T. Timko †, Caleb A. Class †, Robin E. Bonomi †, Yuko Kida †, Hector H. Hernandez ‡, Jefferson W. Tester §, and William H. Green *† ... In contrast to sulfides and disulfides, they observed that ionic reactions dominated mercaptan decomposition and resulted in greater conversions in aqueous medium. ... Model compounds were selected to represent the various classes of sulfur compounds present in crude oil: an alkyl sulfide (hexyl sulfide), a cyclic sulfide (tetrahydrothiophene), an alkyl aryl sulfide (isopropyl phenyl sulfide), three aromatic sulfides (dibenzyl sulfide, benzyl phenyl sulfide, and diphenyl sulfides), and two thiophenic compounds (thiophene and dibenzothiophene). ...

Pushkaraj R. Patwardhan; Michael T. Timko; Caleb A. Class; Robin E. Bonomi; Yuko Kida; Hector H. Hernandez; Jefferson W. Tester; William H. Green

2013-09-20T23:59:59.000Z

50

Sulfide catalysts for reducing SO2 to elemental sulfur  

DOE Patents [OSTI]

A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

2001-01-01T23:59:59.000Z

51

Nanomaterials for Extracting Hydrogen from Water  

E-Print Network [OSTI]

to catalyze water oxidation. K E Y A C C O M P L I S H M E N T S Produced highly active iron oxide (hematiteNanomaterials for Extracting Hydrogen from Water P R O J E C T L E A D E R : Veronika Szalai (NIST water. R E F E R E N C E Effect of tin doping on -Fe2 O3 photoanodes for water splitting, C. D. Bohn, A

52

E-Print Network 3.0 - anaerobic hydrogen producing Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a small percentage of hydrogen sulfide, water vapor, carbon... Technology Biomethane (biogas) is an alternative and renewable energy source produced through the anaerobic... are...

53

6 - Hydrogen production by water electrolysis  

Science Journals Connector (OSTI)

Abstract: An electrolyzer combines an oxidation and a reduction reaction, driven by electricity, to produce separate streams of hydrogen gas and oxygen gas by a process called electrolysis. The hydrogen contains a portion of the electrical energy, and it can be used to generate electricity in a fuel cell by a process that is the reverse of electrolysis. If water electrolysis is driven by renewable electricity, it can be used in fuel-cell electric vehicles to displace petroleum, increase vehicle efficiency, and reduce the environmental impact of vehicles. The fundamental aspects of electrolytic hydrogen and its use as energy carrier are discussed.

N.A. Kelly

2014-01-01T23:59:59.000Z

54

Fuel from Water: The Photochemical Generation of Hydrogen from Water  

Science Journals Connector (OSTI)

Fuel from Water: The Photochemical Generation of Hydrogen from Water ... Hydrogen can be generated from fossil fuels using well established industrial scale chem.; while this is clearly not green, it can provide the transitional capacity as infrastructure is developed and alternate ways of generating hydrogen using solar, nuclear, hydro, wind, or wave energy come to the fore. ... Our renewed interest in alternative energy has fuelled research in understanding this simplest, in terms of active site organization, of the known hydrogenases over the last two decades. ...

Zhiji Han; Richard Eisenberg

2014-06-26T23:59:59.000Z

55

NETL: Releases & Briefs - Producing hydrogen from water, without  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Producing Hydrogen from Water, without Electrolysis Producing Hydrogen from Water, without Electrolysis Electrochemical potential difference drives the reaction Electrochemical potential difference drives the reaction Researchers at DOE's National Energy Technology Laboratory and Argonne National Laboratory have patented a "Method of Generating Hydrogen by Catalytic Decomposition of Water." The invention potentially leapfrogs current capital and energy intensive processes that produce hydrogen from fossil fuels or through the electrolysis of water. According to co-inventor Arun Bose, "Hydrogen can be produced by electrolysis, but the high voltage requirements are a commercial barrier. The invention provides a new route for producing hydrogen from water by using mixed proton-electron conducting membranes." Water is

56

Kinetic studies of the water gas shift reaction on a sulfided cobalt/molybdena/alumina catalyst  

SciTech Connect (OSTI)

In this study, the applicability of low temperature oxygen chemisorption (LTOC) to measure the specific surface area of several rare-earth oxides (La, Ce, Pr, Nd, Tb) and the kinetics of the water-gas shift reaction over a sulfided cobalt-molybdena-alumina (AMOCAT 1A) catalyst are investigated. The LTOC results indicate that oxygen is possibly adsorbed in the molecular form, O/sub 2//sup -/, as observed by others after heat treatment of these oxides in vacuum. Lanthana and ceria were found to have ratios of total surface area to LTOC similar to those of chromia and molybdena respectively, after a comparable pretreatment. Furthermore, ceria is deduced to exist as a monolayer on the alumina support at loadings below 12%. An additional hour of reduction after the 6 hours of reduction shows a significant increase in LTOC on lanthana, neodymia and terbia which may be due to phase changes exhibited by these polymorphic oxides. The kinetics of the water-gas shift reaction has been extensively studied on iron oxide (high temperature shift) and copper oxide (low temperature shift) based catalysts. This investigation establishes the kinetics over a sulfided cobalt-molybdena-alumina (AMOCAT 1A) catalyst in the medium temperature shift range, 250-300/sup 0/C. The catalyst was sulfided in-situ in a high pressure integrated Berty reactor system. Reaction rates were measured for different CO/H/sub 2/O feed ratios in the range 0.3-3.0, with and without CO/sub 2/ in the feed. The reaction was carried out at several pressures in the range 5-27 atm. and GHSV's in the range 4800-2400 hr/sup 1/.

Srivatsa, N.R.

1987-01-01T23:59:59.000Z

57

Synthesis of cadmium sulfide Q particles in water-in-CO{sub 2} microemulsions  

SciTech Connect (OSTI)

Semiconductor nanoparticles of cadmium sulfide were synthesized in ammonium perfluoropolyether (PFPE-NH{sub 4}) stabilized water-in-CO{sub 2} microemulsions. The particle size was tuned by varying the water-to-surfactant molar ratio ({omega}{sub 0}): {omega}{sub 0} ratios of 5 and 10 yielded nanocrystals with exciton energies of 3.86 and 3.09 eV, corresponding to mean particle radii of 0.9 and 1.8 nm, respectively. These exciton energies are significantly higher than the bulk band gap energy for CdS (2.45 eV) due to quantum confinement effects. Effectively, {omega}{sub 0} controls the size of the compartmentalized water droplets in which the particles grow.

Holmes, J.D.; Bhargava, P.A.; Korgel, B.A.; Johnston, K.P.

1999-09-28T23:59:59.000Z

58

Hydrogen production by the decomposition of water  

DOE Patents [OSTI]

How to produce hydrogen from water was a problem addressed by this invention. The solution employs a combined electrolytical-thermochemical sulfuric acid process. Additionally, high purity sulfuric acid can be produced in the process. Water and SO.sub.2 react in electrolyzer (12) so that hydrogen is produced at the cathode and sulfuric acid is produced at the anode. Then the sulfuric acid is reacted with a particular compound M.sub.r X.sub.s so as to form at least one water insoluble sulfate and at least one water insoluble oxide of molybdenum, tungsten, or boron. Water is removed by filtration; and the sulfate is decomposed in the presence of the oxide in sulfate decomposition zone (21), thus forming SO.sub.3 and reforming M.sub.r X.sub.s. The M.sub.r X.sub.s is recycled to sulfate formation zone (16). If desired, the SO.sub.3 can be decomposed to SO.sub.2 and O.sub.2 ; and the SO.sub.2 can be recycled to electrolyzer (12) to provide a cycle for producing hydrogen.

Hollabaugh, Charles M. (Los Alamos, NM); Bowman, Melvin G. (Los Alamos, NM)

1981-01-01T23:59:59.000Z

59

Electrokinetic Hydrogen Generation from Liquid Water Microjets  

E-Print Network [OSTI]

Electrochemical hydrogen production methods are quiteonly causative hydrogen production method. Although the massa method for the production of molecular hydrogen from

Duffin, Andrew M.; Saykally, Richard J.

2007-01-01T23:59:59.000Z

60

Electrokinetic Hydrogen Generation from Liquid Water Microjets  

E-Print Network [OSTI]

currents and hydrogen production rates are shown to followmolecules. The hydrogen production efficiency is currentlycurrently available hydrogen production routes that can be

Duffin, Andrew M.; Saykally, Richard J.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Vibrational Signature of Water Molecules in Asymmetric Hydrogen Bonding Environments  

E-Print Network [OSTI]

Vibrational Signature of Water Molecules in Asymmetric Hydrogen Bonding Environments Chao Zhang contributions of each of the two hydrogen atoms to the vibrational modes 1 and 3 of water molecules the early works on the molecular structure of water, it has been accepted that a water molecule

Guidoni, Leonardo

62

Author's personal copy Photoelectrochemical hydrogen production from water/  

E-Print Network [OSTI]

coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resourcesAuthor's personal copy Photoelectrochemical hydrogen production from water/ methanol decomposition

Wood, Thomas K.

63

Materials for Hydrogen Generation via Water Electrolysis  

SciTech Connect (OSTI)

A review is presented of materials that could be utilized as electrolytes (and their associated electrodes and interconnect materials) in solid-state electrolysis cells to convert water (or steam) into hydrogen and oxygen. Electrolytes that function as oxygen ion conductors or proton conductors are considered for various operating temperatures from approximately 80 °C to 1000 °C. The fundamental electrochemical reactions are reviewed with some discussion of special sources of steam and DC electricity (advanced nuclear) to drive the reactions at the higher temperatures.

Paul A. Lessing

2007-05-01T23:59:59.000Z

64

Effect of hydrogen sulfide on chemical looping of coal-derived synthesis gas over bentonite-supported metal---oxide oxygen carriers  

SciTech Connect (OSTI)

The effect of hydrogen sulfide (H2S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxidesssuch as iron oxide, nickel oxide, manganese oxide, and copper oxideswas investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H2S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H2S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H2S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H2S for all four metal oxides.

Tian, H.; Simonyi, T.; Poston, J.; Siriwardane, R.

2009-01-01T23:59:59.000Z

65

Effect of hydrogen sulfide on chemical looping combustion of coal-derived synthesis gas over bentonite-supported metal-oxide oxygen carriers  

SciTech Connect (OSTI)

The effect of hydrogen sulfide (H{sub 2}S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxides - such as iron oxide, nickel oxide, manganese oxide, and copper oxide - was investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H{sub 2}S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H{sub 2}S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H{sub 2}S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H{sub 2}S for all four metal oxides.

Tian, H.J.; Simonyi, T.; Poston, J.; Siriwardane, R. [US DOE, Morgantown, WV (United States). National Energy Technology Laboratory

2009-09-15T23:59:59.000Z

66

Process for the production of hydrogen from water  

DOE Patents [OSTI]

A method and device for the production of hydrogen from water and electricity using an active metal alloy. The active metal alloy reacts with water producing hydrogen and a metal hydroxide. The metal hydroxide is consumed, restoring the active metal alloy, by applying a voltage between the active metal alloy and the metal hydroxide. As the process is sustainable, only water and electricity is required to sustain the reaction generating hydrogen.

Miller, William E. (Naperville, IL); Maroni, Victor A. (Naperville, IL); Willit, James L. (Batavia, IL)

2010-05-25T23:59:59.000Z

67

Carbon promoted water electrolysis to produce hydrogen at room temperature.  

E-Print Network [OSTI]

??The objective of the work was to conduct water electrolysis at room temperature with reduced energy costs for hydrogen production. The electrochemical gasification of carbons… (more)

Ranganathan, Sukanya.

2007-01-01T23:59:59.000Z

68

Sonoelectrochemical production of hydrogen via alkaline water electrolysis.  

E-Print Network [OSTI]

??Alkaline water electrolysis is a promising technology to produce clean and pure hydrogen. This technology coupled with the ultrasound results in an enhanced rate of… (more)

Hassan Zadeh, Salman

2014-01-01T23:59:59.000Z

69

Hydrogen and Water: An Engineering, Economic and Environmental Analysis  

SciTech Connect (OSTI)

The multi-year program plan for the Department of Energy's Hydrogen and Fuel Cells Technology Program (USDOE, 2007a) calls for the development of system models to determine economic, environmental and cross-cutting impacts of the transition to a hydrogen economy. One component of the hydrogen production and delivery chain is water; water's use and disposal can incur costs and environmental consequences for almost any industrial product. It has become increasingly clear that due to factors such as competing water demands and climate change, the potential for a water-constrained world is real. Thus, any future hydrogen economy will need to be constructed so that any associated water impacts are minimized. This, in turn, requires the analysis and comparison of specific hydrogen production schemes in terms of their water use. Broadly speaking, two types of water are used in hydrogen production: process water and cooling water. In the production plant, process water is used as a direct input for the conversion processes (e.g. steam for Steam Methane Reforming {l_brace}SMR{r_brace}, water for electrolysis). Cooling water, by distinction, is used indirectly to cool related fluids or equipment, and is an important factor in making plant processes efficient and reliable. Hydrogen production further relies on water used indirectly to generate other feedstocks required by a hydrogen plant. This second order indirect water is referred to here as 'embedded' water. For example, electricity production uses significant quantities of water; this 'thermoelectric cooling' contributes significantly to the total water footprint of the hydrogen production chain. A comprehensive systems analysis of the hydrogen economy includes the aggregate of the water intensities from every step in the production chain including direct, indirect, and embedded water. Process and cooling waters have distinct technical quality requirements. Process water, which is typically high purity (limited dissolved solids) is used inside boilers, reactors or electrolyzers because as it changes phase or is consumed, it leaves very little residue behind. Pre-treatment of 'raw' source water to remove impurities not only enables efficient hydrogen production, but also reduces maintenance costs associated with component degradation due to those impurities. Cooling water has lower overall quality specifications, though it is required in larger volumes. Cooling water has distinct quality requirements aimed at preserving the cooling equipment by reducing scaling and fouling from untreated water. At least as important as the quantity, quality and cost of water inputs to a process are the quantity, quality and cost of water discharge. In many parts of the world, contamination from wastewater streams is a far greater threat to water supply than scarcity or drought (Brooks, 2002). Wastewater can be produced during the pre-treatment processes for process and cooling water, and is also sometimes generated during the hydrogen production and cooling operations themselves. Wastewater is, by definition, lower quality than supply water. Municipal wastewater treatment facilities can handle some industrial wastewaters; others must be treated on-site or recycled. Any of these options can incur additional cost and/or complexity. DOE's 'H2A' studies have developed cost and energy intensity estimates for a variety of hydrogen production pathways. These assessments, however, have not focused on the details of water use, treatment and disposal. As a result, relatively coarse consumption numbers have been used to estimate water intensities. The water intensity for hydrogen production ranges between 1.5-40 gallons per kilogram of hydrogen, including the embedded water due to electricity consumption and considering the wide variety of hydrogen production, water treatment, and cooling options. Understanding the consequences of water management choices enables stakeholders to make informed decisions regarding water use. Water is a fundamentally regional commodity. Water resources vary in quality and qu

Simon, A J; Daily, W; White, R G

2010-01-06T23:59:59.000Z

70

Heat Transfer Characteristics of Sulfur and Sulfur Diluted with Hydrogen Sulfide Flowing Through Circular Tubes  

E-Print Network [OSTI]

is called the pumping-power advantage factor, and has the value 2. 5 x 10 for sodium. The only metals having a higher value of H are 13 lithium 7 and bismuth. Lithium 7 comprises 92. 5% of natural lithium, but the cost of separating it from lithium 6...-section for thermal neutrons being 0. 130 barns. For comparison, water has an absorption cross-section of 0. 58 barns for thermal neutrons (2) . Sulfur is not activated by exposure to neutron flux in such a way as to produce a radioactive isotope which...

Stone, Porter Walwyn

1960-01-01T23:59:59.000Z

71

Biological Water Gas Shift DOE Hydrogen, Fuel Cell, and Infrastructure  

E-Print Network [OSTI]

Biological Water Gas Shift DOE Hydrogen, Fuel Cell, and Infrastructure Technologies Program Review was produced from water in a linked cyanobacterial- hydrogenase hybrid system Isolated mutants and cloned 2

72

Simulating Geologic Co-sequestration of Carbon Dioxide and Hydrogen Sulfide in a Basalt Formation  

SciTech Connect (OSTI)

Co-sequestered CO2 with H2S impurities could affect geologic storage, causing changes in pH and oxidation state that affect mineral dissolution and precipitation reactions and the mobility of metals present in the reservoir rocks. We have developed a variable component, non-isothermal simulator, STOMP-COMP (Water, Multiple Components, Salt and Energy), which simulates multiphase flow gas mixtures in deep saline reservoirs, and the resulting reactions with reservoir minerals. We use this simulator to model the co-injection of CO2 and H2S into brecciated basalt flow top. A 1000 metric ton injection of these supercritical fluids, with 99% CO2 and 1% H2S, is sequestered rapidly by solubility and mineral trapping. CO2 is trapped mainly as calcite within a few decades and H2S is trapped as pyrite within several years.

Bacon, Diana H.; Ramanathan, Ramya; Schaef, Herbert T.; McGrail, B. Peter

2014-01-15T23:59:59.000Z

73

Parametric study of solar hydrogen production from saline water electrolysis  

Science Journals Connector (OSTI)

The purpose of this work is to study the electrolysis of water for the production of hydrogen. A number of parameters, including salinity, voltage, current density and quantity of electricity, were investigated, and their effect on hydrogen production using a modified simple Hoffman electrolysis cell is reported.

S.M. El-Haggar; M. Khalil

1997-01-01T23:59:59.000Z

74

Reaction of Aluminum with Water to Produce Hydrogen  

E-Print Network [OSTI]

Reaction of Aluminum with Water to Produce Hydrogen A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage U.S. Department of Energy Version 1.0 - 2008 Page 1 Promoters Oxide Promoters Salt Promoters Combined Oxide and Salt Promoters Aluminum Pretreatment Molten

75

Reaction of Aluminum with Water to Produce Hydrogen  

E-Print Network [OSTI]

Reaction of Aluminum with Water to Produce Hydrogen A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage U.S. Department of Energy Version 2 - 2010 1 #12 Promoters Oxide Promoters Salt Promoters Combined Oxide and Salt Promoters Aluminum Pretreatment Molten

76

Zinc sulfide liquefaction catalyst  

DOE Patents [OSTI]

A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

Garg, Diwakar (Macungie, PA)

1984-01-01T23:59:59.000Z

77

Water inertial reorientation: Hydrogen bond strength and the angular potential  

E-Print Network [OSTI]

Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

Fayer, Michael D.

78

Ultrafast structural fluctuations and rearrangements of water's hydrogen bonded network  

E-Print Network [OSTI]

Aqueous chemistry is strongly influenced by water's ability to form an extended network of hydrogen bonds. It is the fluctuations and rearrangements of this network that stabilize reaction products and drive the transport ...

Loparo, Joseph J. (Joseph John)

2007-01-01T23:59:59.000Z

79

Production of hydrogen from water using biophotolytic methods  

Science Journals Connector (OSTI)

Hydrogen gas has been produced on a continuous basis using two immobilized microorganisms. One organism, the cyanobacteria it(Anacystis nidulans), oxidizes water, producing molecular oxygen, and reduces exogen...

Howard H. Weetall; Lester O. Krampitz

1980-06-01T23:59:59.000Z

80

Hydrogen peroxide production by water electrolysis: Application to disinfection  

Science Journals Connector (OSTI)

Hydrogen peroxide was produced by direct current electrolysis using only two electrodes, a carbon felt...2...coated titanium anode. The required oxygen was supplied by oxidation of water and by transfer from the ...

P. Drogui; S. Elmaleh; M. Rumeau; C. Bernard…

2001-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Hydrogen production from water: Recent advances in photosynthesis research  

SciTech Connect (OSTI)

The great potential of hydrogen production by microalgal water splitting is predicated on quantitative measurement of the algae`s hydrogen-producing capability, which is based on the following: (1) the photosynthetic unit size of hydrogen production; (2) the turnover time of photosynthetic hydrogen production; (3) thermodynamic efficiencies of conversion of light energy into the Gibbs free energy of molecular hydrogen; (4) photosynthetic hydrogen production from sea water using marine algae; (5) the potential for research advances using modern methods of molecular biology and genetic engineering to maximize hydrogen production. ORNL has shown that sustained simultaneous photoevolution of molecular hydrogen and oxygen can be performed with mutants of the green alga Chlamydomonas reinhardtii that lack a detectable level of the Photosystem I light reaction. This result is surprising in view of the standard two-light reaction model of photosynthesis and has interesting scientific and technological implications. This ORNL discovery also has potentially important implications for maximum thermodynamic conversion efficiency of light energy into chemical energy by green plant photosynthesis. Hydrogen production performed by a single light reaction, as opposed to two, implies a doubling of the theoretically maximum thermodynamic conversion efficiency from {approx}10% to {approx}20%.

Greenbaum, E.; Lee, J.W. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.

1997-12-31T23:59:59.000Z

82

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

83

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

84

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

85

Formation of Hydrogen, Oxygen, and Hydrogen Peroxide in Electron Irradiated Crystalline Water Ice  

E-Print Network [OSTI]

Water ice is abundant both astrophysically, for example in molecular clouds, and in planetary systems. The Kuiper belt objects, many satellites of the outer solar system, the nuclei of comets and some planetary rings are all known to be water-rich. Processing of water ice by energetic particles and ultraviolet photons plays an important role in astrochemistry. To explore the detailed nature of this processing, we have conducted a systematic laboratory study of the irradiation of crystalline water ice in an ultrahigh vacuum setup by energetic electrons holding a linear energy transfer of 4.3 +/- 0.1 keV mm-1. The irradiated samples were monitored during the experiment both on line and in situ via mass spectrometry (gas phase) and Fourier transform infrared spectroscopy (solid state). We observed the production of hydrogen and oxygen, both molecular and atomic, and of hydrogen peroxide. The likely reaction mechanisms responsible for these species are discussed. Additional formation routes were derived from the sublimation profiles of molecular hydrogen (90-140 K), molecular oxygen (147 -151 K) and hydrogen peroxide (170 K). We also present evidence on the involvement of hydroxyl radicals and possibly oxygen atoms as building blocks to yield hydrogen peroxide at low temperatures (12 K) and via a diffusion-controlled mechanism in the warming up phase of the irradiated sample.

Weijun Zheng; David Jewitt; Ralf I. Kaiser

2005-11-18T23:59:59.000Z

86

Hydrogen Generation through Static Feed Water Electrolysis  

Science Journals Connector (OSTI)

Life Systems’ Static Feed Water Electrolysis System (SFWES) concept, developed under NASA...2...) production. The SFWES concept uses (1) an alkaline electrolyte to minimize power requirements and materials compat...

F. C. Jensen; F. H. Schubert

1975-01-01T23:59:59.000Z

87

HYDROGEN ISOTOPE RECOVERY USING PROTON EXCHANGE MEMBRANE ELECTROLYSIS OF WATER  

SciTech Connect (OSTI)

A critical component of tritium glovebox operations is the recovery of high value tritium from the water vapor in the glove box atmosphere. One proposed method to improve existing tritium recovery systems is to replace the disposable hot magnesium beds used to separate the hydrogen and oxygen in water with continuous use Proton Exchange Membrane Electrolyzers (PEMEs). This study examines radiation exposure to the membrane of a PEME and examines the sizing difference that would be needed if the electrolyzer were operated with a cathode water vapor feed instead of an anode liquid water feed.

Fox, E; Scott Greenway, S; Amy Ekechukwu, A

2007-08-27T23:59:59.000Z

88

Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)  

SciTech Connect (OSTI)

Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70°C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H{sub 2}S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

Solehudin, Agus, E-mail: asolehudin@upi.edu [Department of Mechanical Engineering Education, Indonesia University of Education (UPI), Bandung, West Java (Indonesia); Nurdin, Isdiriayani [Department of Chemical Engineering, Bandung Institute of Technology, Bandung, West Java (Indonesia)

2014-03-24T23:59:59.000Z

89

Cedar Key Aquaculture Workshop Sulfide Concentrations in Sediments  

E-Print Network [OSTI]

Cedar Key Aquaculture Workshop Sulfide Concentrations in Sediments and Water: Influence on Hard;ObjectivesObjectives Examine sediment sulfide levels in the SuwanneeExamine sediment sulfide levels of sulfide on hard clam survivalsurvival #12;MethodsMethods SedimentSediment porewaterporewater samples

Florida, University of

90

Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis: Independent Review  

SciTech Connect (OSTI)

This independent review examines DOE cost targets for state-of-the art hydrogen production using water electrolysis.

Not Available

2009-09-01T23:59:59.000Z

91

Hydrogen Production by Noncatalytic Autothermal Reformation of Aviation Fuel Using Supercritical Water  

Science Journals Connector (OSTI)

Hydrogen Production by Noncatalytic Autothermal Reformation of Aviation Fuel Using Supercritical Water ... Energy Fuels, 2009, 23 (12), ...

Jason W. Picou; Jonathan E. Wenzel; H. Brian Lanterman; Sunggyu Lee

2009-10-07T23:59:59.000Z

92

DOE Hydrogen and Fuel Cells Program Record 5040: 2005 Hydrogen Cost from Water Electrolysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

40 Date: December 12, 2008 40 Date: December 12, 2008 Title: 2005 Hydrogen Cost from Water Electrolysis Originator: Roxanne Garland Approved by: Sunita Satyapal Date: December 19, 2008 Item: The 2005 cost status for hydrogen produced from distributed water electrolysis is $5.90 / gge. Assumptions and References: The H2A analysis used to determine the projected cost of $5.88/gge (rounded up to $5.90/gge) was performed by Directed Technologies, Inc. and can be found in Record 5040a. The increase in cost compared to the 2004 analysis ($5.45/gge) is due to two assumptions changed in the model: (a) an increase in the industrial electricity price from 5¢/kWh to 5.5¢/kWh from the EIA Annual Energy Outlook, and (b) an increase in the capital cost estimate of the electrolyzer. The other assumptions in the analysis used standard values

93

Effect of Sulfide on Nitrogen Fixation in a Stream Sediment-Water System  

Science Journals Connector (OSTI)

...Portions (0.2 ml) of the gas phase from each flask...C2H4, and C2H2 by gas chromatography. All gas chromatographic data are corrected for leakage and solubility and are expressed in...milliliter of stream water. All significant differences...

Tat-Yee Tam; Colin I. Mayfield; William E. Inniss; Roger Knowles

1982-05-01T23:59:59.000Z

94

Hydrogen-on-Demand Using Metallic Alloy Nanoparticles in Water Kohei Shimamura,,,,,  

E-Print Network [OSTI]

energy to regenerate metal fuel.1-3 One potential application of this technology is on-board hydrogenHydrogen-on-Demand Using Metallic Alloy Nanoparticles in Water Kohei Shimamura,,,�,, Fuyuki Shimojo Supporting Information ABSTRACT: Hydrogen production from water using Al particles could provide a renewable

Southern California, University of

95

Rapid hydrogen production from water using aluminum nanoclusters: A quantum molecular dynamics simulation study  

E-Print Network [OSTI]

Rapid hydrogen production from water using aluminum nanoclusters: A quantum molecular dynamics Available online 31 December 2013 Keywords: Hydrogen production Water Aluminum nanoclusters Quantum molecular dynamics simulation It is hoped that a hydrogen-on-demand generator may one day start with just

Southern California, University of

96

WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION PROCESS  

SciTech Connect (OSTI)

Optimization of the water-gas shift (WGS) reaction system for hydrogen production for fuel cells is of particular interest to the energy industry. To this end, it is desirable to couple the WGS reaction to hydrogen separation using a semi-permeable membrane, with both processes carried out at high temperatures to improve reaction kinetics and permeation. Reduced equilibrium conversion of the WGS reaction at high temperatures is overcome by product H{sub 2} removal via the membrane. This project involves fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H{sub 2}-separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams will be examined in the project. The first-year screening studies of WGS catalysts identified Cu-ceria as the most promising high-temperature shift catalyst for integration with H{sub 2}-selective membranes. Formulations containing iron oxide were found to deactivate in the presence of CO{sub 2}, and were thus eliminated from further consideration. Cu-containing ceria catalysts, on the other hand, showed high stability in CO{sub 2}-rich gases. This type gas will be present over much of the catalyst, as the membrane removes the hydrogen produced from the shift reaction. Several catalyst formulations were prepared, characterized and tested in the first year of study. Details from the catalyst development and testing work were given in our first annual technical report. Hydrogen permeation through Pd and Pd-alloy foils was investigated in a small membrane reactor constructed during the first year of the project. The effect of temperature on the hydrogen flux through pure Pd, Pd{sub 60}Cu{sub 40} and Pd{sub 75}Ag{sub 25} alloy membranes, each 25 {micro}m thick, was evaluated in the temperature range from 250 C to 500 C at upstream pressure of 4.4 atm and permeate hydrogen pressure of 1 atm. Flux decay was observed for the Pd-Cu membrane above 500 C. From 350-450 C, an average hydrogen flux value of 0.2 mol H{sub 2}/m{sup 2}/s was measured over this Pd-alloy membrane. These results are in good agreement with literature data. In this year's report, we discuss reaction rate measurements, optimization of catalyst kinetics by proper choice of dopant oxide (lanthana) in ceria, long-term stability studies, and H{sub 2} permeation data collected with unsupported flat, 10 {micro}m-thick Pd-Cu membranes over a wide temperature window and in various gas mixtures. The high-temperature shift catalyst composition was further improved, by proper selection of dopant type and amount. The formulation 10 at%Cu-Ce(30 at%La)Ox was the best; this was selected for further kinetic studies. WGS reaction rates were measured in a simulated coal-gas mixture. The stability of catalyst performance was examined in 40-hr long tests. A series of hydrogen permeation tests were conducted in a small flat-membrane reactor using the 10 m{micro}-thick Pd-Cu membranes. Small inhibitory effects of CO and CO{sub 2} were found at temperatures above 350 C, while H{sub 2}O vapor had no effect on hydrogen permeation. No carbon deposition took place during many hours of membrane operation. The reaction extent on the blank (catalyst-free) membrane was also negligible. A larger flat-membrane reactor will be used next year with the catalyst wash coated on screens close coupled with the Pd-Cu membrane.

Maria Flytzani-Stephanopoulos, PI; Jerry Meldon, Co-PI; Xiaomei Qi

2002-12-01T23:59:59.000Z

97

Potential effects of hydrogen sulfide gas from geothermal energy conversion on two plant species native to northern New Mexico  

SciTech Connect (OSTI)

Dry weight of topgrowth, water content of topgrowth, leaf nitrogen content, and leaf chlorophyll content were measured in well-watered, field-exposed little bluestem (Schizachyrium scoparium Nash.) and mountain brome (Bromus marginatus Nees.) plants fumigated with various mean levels of H/sub 2/S ranging from 0.05 to 3.58 ppM. The youngest fully expanded leaves were sampled for chlorophyll content after 60, 80, 100, and 140 and 60, 80, 120, and 140 h total of fumigation for little bluestem and mountain brome, respectively. All other responses were measured after 140 h total of fumigation. The plants received a 7-day fumigation-free period prior to the seventh week (140 h) of fumigations. Dry weight of little bluestem plants which received low concentrations of H/sub 2/S (0.11 ppM) increased by 94% of the control. Dry weight of little bluestem plants which received higher concentrations of H/sub 2/S (0.12 to 0.48 ppM) was reduced to the control level. At the highest H/sub 2/S concentration (2.39 ppM) dry weight of little bluestem was reduced by 44% of the control. Mountain brome was relatively unaffected at the different concentrations of H/sub 2/S until 3.58 ppM H/sub 2/S was received where dry weight was reduced by 37% of the control.

Gonzales, G.J.

1984-02-01T23:59:59.000Z

98

Method for simultaneous recovery of hydrogen from water and from hydrocarbons  

DOE Patents [OSTI]

Method for simultaneous recovery of hydrogen and hydrogen isotopes from water and from hydrocarbons. A palladium membrane, when utilized in cooperation with a nickel catalyst in a reactor, has been found to drive reactions such as water gas shift, steam reforming and methane cracking to substantial completion by removing the product hydrogen from the reacting mixture. In addition, ultrapure hydrogen is produced, thereby eliminating the need for an additional processing step.

Willms, R. Scott (Los Alamos, NM)

1996-01-01T23:59:59.000Z

99

Hydrogen production by water dissociation using ceramic membranes - annual report for FY 2010.  

SciTech Connect (OSTI)

The objective of this project is to develop dense ceramic membranes that can produce hydrogen via coal/coal gas-assisted water dissociation without using an external power supply or circuitry. This project grew from an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen production by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen using OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J. (Energy Systems)

2011-03-14T23:59:59.000Z

100

Hydrogen production by water dissociation using ceramic membranes - annual report for FY 2008.  

SciTech Connect (OSTI)

The objective of this project is to develop dense ceramic membranes that, without using an external power supply or circuitry, can produce hydrogen via coal/coal gas-assisted water dissociation. This project grew from an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen production by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen by means of OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J.; Energy Systems

2009-03-25T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Hydrogen production via carbon-assisted water electrolysis at room temperature.  

E-Print Network [OSTI]

??The objective of the work was to conduct carbon-assisted water electrolysis at room temperature with reduced energy costs for hydrogen production and to improve upon… (more)

Bollineni, Shilpa

2008-01-01T23:59:59.000Z

102

Isotopic Effects of Hydrogen During the Decomposition of Water in Electrolysis with a Solid Polymer Electrolyte  

Science Journals Connector (OSTI)

The partition coefficients of hydrogen isotopes in the decomposition of water in electrolyzers with a solid polymer electrolyte are measured in a wide range of deuterium content in the initial water (from the ...

O. M. Ivanchuk; V. G. Goryanina; M. B. Rozenkevich

2000-09-01T23:59:59.000Z

103

Process for producing cadmium sulfide on a cadmium telluride surface  

DOE Patents [OSTI]

A process is described for producing a layer of cadmium sulfide on a cadmium telluride surface to be employed in a photovoltaic device. The process comprises providing a cadmium telluride surface which is exposed to a hydrogen sulfide plasma at an exposure flow rate, an exposure time and an exposure temperature sufficient to permit reaction between the hydrogen sulfide and cadmium telluride to thereby form a cadmium sulfide layer on the cadmium telluride surface and accomplish passivation. In addition to passivation, a heterojunction at the interface of the cadmium sulfide and the cadmium telluride can be formed when the layer of cadmium sulfide formed on the cadmium telluride is of sufficient thickness. 12 figs.

Levi, D.H.; Nelson, A.J.; Ahrenkiel, R.K.

1996-07-30T23:59:59.000Z

104

WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION PROCESS  

SciTech Connect (OSTI)

This project involved fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H{sub 2} -separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams were examined in the project. Cu-cerium oxide was identified as the most promising high-temperature water-gas shift catalyst for integration with H{sub 2}-selective membranes. Formulations containing iron oxide were found to deactivate in the presence of CO{sub 2}. Cu-containing ceria catalysts, on the other hand, showed high stability in CO{sub 2}-rich gases. This type gas will be present over much of the catalyst, as the membrane removes the hydrogen produced from the shift reaction. The high-temperature shift catalyst composition was optimized by proper selection of dopant type and amount in ceria. The formulation 10at%Cu-Ce(30at%La)O{sub x} showed the best performance, and was selected for further kinetic studies. WGS reaction rates were measured in a simulated coal-gas mixture. The apparent activation energy, measured over aged catalysts, was equal to 70.2 kJ/mol. Reaction orders in CO, H{sub 2}O, CO{sub 2} and H{sub 2} were found to be 0.8, 0.2, -0.3, and -0.3, respectively. This shows that H{sub 2}O has very little effect on the reaction rate, and that both CO{sub 2} and H{sub 2} weakly inhibit the reaction. Good stability of catalyst performance was found in 40-hr long tests. A flat (38 cm{sup 2}) Pd-Cu alloy membrane reactor was used with the catalyst washcoated on oxidized aluminum screens close coupled with the membrane. To achieve higher loadings, catalyst granules were layered on the membrane itself to test the combined HTS activity/ H{sub 2} -separation efficiency of the composite. Simulated coal gas mixtures were used and the effect of membrane on the conversion of CO over the catalyst was evidenced at high space velocities. Equilibrium CO conversion at 400 C was measured at a space velocity of 30,000 h{sup -1} with the 10{micro}m- thick Pd{sub 60}Cu{sub 40} membrane operating under a pressure differential of 100 psi. No carbon deposition took place during operation. The performance of the coupled Cu-ceria catalyst/membrane system at 400 C was stable in {approx} 30 h of continuous operation. The overall conclusion from this project is that Cu-doped ceria catalysts are suitable for use in high-temperature water-gas shift membrane reactors. CO{sub 2}-rich operation does not affect the catalyst activity or stability; neither does it affect hydrogen permeation through the Pd-Cu membrane. Operation in the temperature range of 400-430 C is recommended.

Maria Flytzani-Stephanopoulos; Xiaomei Qi; Scott Kronewitter

2004-02-01T23:59:59.000Z

105

Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy  

SciTech Connect (OSTI)

We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

2010-05-01T23:59:59.000Z

106

Spectroscopic and thermodynamic properties of molecular hydrogen dissolved in water at pressures up to 200 MPa  

SciTech Connect (OSTI)

We have measured the Raman Q-branch of hydrogen in a solution with water at a temperature of about 280 K and at pressures from 20 to 200 MPa. From a least-mean-square fitting analysis of the broad Raman Q-branch, we isolated the contributions from the four lowest individual roto-vibrational lines. The vibrational lines were narrower than the pure rotational Raman lines of hydrogen dissolved in water measured previously, but significantly larger than in the gas. The separations between these lines were found to be significantly smaller than in gaseous hydrogen and their widths were slightly increasing with pressure. The lines were narrowing with increasing rotational quantum number. The Raman frequencies of all roto-vibrational lines were approaching the values of gas phase hydrogen with increasing pressure. Additionally, from the comparison of the integrated intensity signal of Q-branch of hydrogen to the integrated Raman signal of the water bending mode, we have obtained the concentration of hydrogen in a solution with water along the 280 K isotherm. Hydrogen solubility increases slowly with pressure, and no deviation from a smooth behaviour was observed, even reaching thermodynamic conditions very close to the transition to the stable hydrogen hydrate. The analysis of the relative hydrogen concentration in solution on the basis of a simple thermodynamic model has allowed us to obtain the molar volume for the hydrogen gas/water solution. Interestingly, the volume relative to one hydrogen molecule in solution does not decrease with pressure and, at high pressure, is larger than the volume pertinent to one molecule of water. This is in favour of the theory of hydrophobic solvation, for which a larger and more stable structure of the water molecules is expected around a solute molecule.

Borysow, Jacek, E-mail: jborysow@mtu.edu; Rosso, Leonardo del; Celli, Milva; Ulivi, Lorenzo, E-mail: lorenzo.ulivi@isc.cnr.it [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Via Madonna del piano 10, I-50019 Sesto Fiorentino (Italy)] [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Via Madonna del piano 10, I-50019 Sesto Fiorentino (Italy); Moraldi, Massimo [Dipartimento di Fisica e Astronomia, Università degli Studi di Firenze, Via Sansone 1, I-50019 Sesto Fiorentino (Italy)] [Dipartimento di Fisica e Astronomia, Università degli Studi di Firenze, Via Sansone 1, I-50019 Sesto Fiorentino (Italy)

2014-04-28T23:59:59.000Z

107

Hydrogen Ingress in Steels During High-Temperature Oxidation in Water Vapor  

SciTech Connect (OSTI)

It is well established that hydrogen derived from water vapour can penetrate oxidizing alloys with detrimental effect. However, the complexities of tracking hydrogen in these materials have prevented the direct profiling of hydrogen ingress needed to understand these phenomena. Here we report hydrogen profiles in industrially-relevant alumina- and chromia- forming steels correlated with the local oxide-metal nano/microstructure by use of SIMS D2O tracer studies and experimental protocols to optimize D retention. The D profiles unexpectedly varied markedly among the alloys examined, which indicates mechanistic complexity but also the potential to mitigate detrimental water vapour effects by manipulation of alloy chemistry.

Brady, Michael P [ORNL; Fayek, Mostafa [ORNL; Keiser, James R [ORNL; Meyer III, Harry M [ORNL; More, Karren Leslie [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Wesolowski, David J [ORNL; Cole, David R [ORNL

2011-01-01T23:59:59.000Z

108

Hydrogen production by water dissociation using ceramic membranes. Annual report for FY 2007.  

SciTech Connect (OSTI)

The objective of this project is to develop dense ceramic membranes that, without using an external power supply or circuitry, can produce hydrogen via coal/coal gas-assisted water dissociation. This project grew out of an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions [1]. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen to be produced by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting [1, 2]. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen by means of OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

Balachandran, U.; Chen, L.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Park, C. Y.; Picciolo, J. J.; Song, S. J.; Energy Systems

2008-03-04T23:59:59.000Z

109

Depletion of heavy isotopes of oxygen and hydrogen in tissue water of intertidal plants: implications for water economy  

Science Journals Connector (OSTI)

Stable oxygen and hydrogen isotope ratios of leaf and thallus water of the intertidal seagrasses Phyllospadix scouleri and P. torreyi and the marine algae Egregia menziesii, Gelidium coulteri, and Corallina vanco...

L. W. Cooper; M. J. DeNiro

1989-05-01T23:59:59.000Z

110

Improvements and optimisation of water electrolysis for hydrogen production.  

E-Print Network [OSTI]

??[Truncated abstract] Hydrogen as an important energy carrier has wide applications and great potentials. With ever increasing energy costs and concerns with climate change associated… (more)

Zeng, Kai

2012-01-01T23:59:59.000Z

111

Hydrogen from Water in a Novel Recombinant Cyanobacterial System  

SciTech Connect (OSTI)

Photobiological processes are attractive routes to renewable H2 production. With the input of solar energy, photosynthetic microbes such as cyanobacteria and green algae carry out oxygenic photosynthesis, using sunlight energy to extract protons and high energy electrons from water. These protons and high energy electrons can be fed to a hydrogenase system yielding H2. However, most hydrogen-evolving hydrogenases are inhibited by O2, which is an inherent byproduct of oxygenic photosynthesis. The rate of H2 production is thus limited. Certain photosynthetic bacteria are reported to have an O2-tolerant evolving hydrogenase, yet these microbes do not split water, and require other more expensive feedstocks. To overcome these difficulties, the goal of this work has been to construct novel microbial hybrids by genetically transferring O2-tolerant hydrogenases from other bacteria into a class of photosynthetic bacteria called cyanobacteria. These hybrid organisms will use the photosynthetic machinery of the cyanobacterial hosts to perform the water-oxidation reaction with the input of solar energy, and couple the resulting protons and high energy electrons to the O2-tolerant bacterial hydrogenase, all within the same microbe (Fig. 1). The ultimate goal of this work has been to overcome the sensitivity of the hydrogenase enzyme to O2 and address one of the key technological hurdles to cost-effective photobiological H2 production which currently limits the production of hydrogen in algal systems. In pursuit of this goal, work on this project has successfully completed many subtasks leading to a greatly increased understanding of the complicated [NiFe]-hydrogenase enzymes. At the beginning of this project, [NiFe] hydrogenases had never been successfully moved across wide species barriers and had never been heterologously expressed in cyanobacteria. Furthermore, the idea that whole, functional genes could be extracted from complicated, mixed-sequence meta-genomes was not established. In the course of this work, we identified a new hydrogenase from environmental DNA sequence and successfully expressed it in a variety of hosts including cyanobacteria. This was one of the first examples of these complicated enzymes being moved across vastly different bacterial species and is the first example of a hydrogenase being “brought to life” from no other information than a DNA sequence from metagenomic data. The hydrogenase we identified had the molecular signature of other O2-tolerant hydrogenases, and we discovered that the resulting enzyme had exceptionally high oxygen- and thermo-tolerance. The new enzyme retained 80% of its activity after incubation at 80° C for 2 hours and retained 20% activity in 1% O2. We performed detailed analysis on the maturation genes required for construction of a functional enzyme of this class of hydrogenase, and found that seven additional maturation genes were required for minimal activity and a total of nine genes besides the hydrogenase were required for optimal maturation efficiency. Furthermore, we demonstrated that the maturation genes are functional on closely-related hydrogenase enzymes such as those from Alteromonas macleodii and Thiocapsa roseopersicina. Finally, we have extensively modified the hydrogenase to engineer new traits including higher H2 production and better interaction with electron donors. For example, combining two strategies increased hydrogenase activity in cyanobacteria by at least 20-fold over our initial expression level. The activity of this combined strain is almost twice that of the native hydrogenase activity in S. elongatus. This work validates the idea that these enzymes are broadly tolerant to modifications that may help integrate them into a successful photobiological H2 production system. While we did not achieve our ultimate goal of integrating the functional hydrogenase with the cyanobacterial photosynthetic apparatus, the work on this project has led to significant advances in the understanding of these complicated enzymes. This work will greatly benefit future

Weyman, Philip D [J. Craig Venter Institute; Smith, Hamillton O.

2014-12-03T23:59:59.000Z

112

DOE NSF Partnership to Address Critical Challenges in Hydrogen Production from Solar Water Splitting  

Broader source: Energy.gov [DOE]

EERE and the National Science Foundation (NSF) announce a funding opportunity in the area of renewable hydrogen technology research and development, specifically addressing discovery and development of advanced materials systems and chemical proceesses for direct photochemical and/or thermochemical water splitting for application in the solar production of hydrogen fuel.

113

Hydrogen production from the reaction of solvated electrons with benzene in water-ammonia mixtures  

SciTech Connect (OSTI)

Product analysis data for the reaction of the ammoniated electron with benzene-water mixtures in liquid ammonia show that the dominant product is evolved hydrogen and not 1,4-cyclohexadiene.

Dewald, R.R.; Jones, S.R.; Schwartz, B.S.

1980-11-27T23:59:59.000Z

114

Collective Hydrogen Bond Reorganization in Water Studied with Temperature-Dependent Ultrafast Infrared Spectroscopy  

E-Print Network [OSTI]

We use temperature-dependent ultrafast infrared spectroscopy of dilute HOD in H2O to study the picosecond reorganization of the hydrogen bond network of liquid water. Temperature-dependent two-dimensional infrared (2D IR), ...

Nicodemus, Rebecca A.

115

Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR  

E-Print Network [OSTI]

We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

Nicodemus, Rebecca A.

116

Water Dynamics in Nafion Fuel Cell Membranes: The Effects of Confinement and Structural Changes on the Hydrogen Bond Network  

E-Print Network [OSTI]

emissions energy source is hydrogen. Hydrogen powered vehicles using polymer electrolyte membrane fuel cells and hydrophilic aggregates.1-4 Hydrogen fuel cells operate through the oxidation of hydrogen gas at the anodeWater Dynamics in Nafion Fuel Cell Membranes: The Effects of Confinement and Structural Changes

Fayer, Michael D.

117

Hydrogen  

Science Journals Connector (OSTI)

Hydrogen energy is a clean or inexhaustible energy like renewable energy and nuclear energy. Today’s energy supply has a considerable impact on the environment. Hydrogen energy is a promising alternative solut...

2009-01-01T23:59:59.000Z

118

Hydrogen Bonds, Water Rotation and Proton Mobility Liaisons Hydrog`ene, Rotation de l'eau et Mobilit'e du  

E-Print Network [OSTI]

Hydrogen Bonds, Water Rotation and Proton Mobility Liaisons Hydrog`ene, Rotation de l'eau et H 3 O + est presque immo­ bilis'e par des liaisons hydrog`ene extrâ??emement fortes. Ces derni liaisons hydrog`ene de l'eau pure. Dans l'eau en dessous de 20 0 C, la rotation des mol'ecules est plus

Agmon, Noam

119

Solar-Powered Production of Molecular Hydrogen from Water  

Science Journals Connector (OSTI)

At the present time, the majority of industrial-scale hydrogen is produced by steam?methane reformation (SMR), even though the high-temperature conversion of methane to hydrogen results in the concomitant production of carbon monoxide and carbon dioxide. ... 7-9 The PV arrays are used to convert solar light to electricity in order to power alkaline (e.g., 27% KOH at pH 14.7) electrolyzers for producing hydrogen gas. ... Narayanan et al. describe a DC-powered hybrid system that drives a methanol fuel cell in reverse,10 while Soler et al. report on a solar-powered photo-Fenton process that produces hydrogen noncatalytically under severe conditions with a limited number of organic substrates. ...

Hyunwoong Park; Chad D. Vecitis; Wonyong Choi; Oleh Weres; Michael R. Hoffmann

2008-01-04T23:59:59.000Z

120

Mpemba paradox: Hydrogen bond memory and water-skin supersolidity  

E-Print Network [OSTI]

Numerical reproduction of measurements, experimental evidence for skin super-solidity and hydrogen-bond memory clarified that Mpemba paradox integrates the heat emission-conduction-dissipation dynamics in the source-path-drain cycle system.

Chang Q Sun

2015-01-05T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Aluminum hydroxide and hydrogen produced by water electrolysis  

Science Journals Connector (OSTI)

Thermodynamic and kinetic peculiarities of the water electrolysis in a reactor with aluminum electrodes are...

R. R. Salem

2009-11-01T23:59:59.000Z

122

Study of four new, field-based, microbiological tests : verification of the hydrogen sulfide (H?S), Easygel®, Colilert and Petrifilm(tm) tests  

E-Print Network [OSTI]

Currently, the U.N. defines water sources as "improved" (e.g. public taps, protected dug wells and springs, rainwater collection) and "unimproved" (e.g. surface waters, unprotected dug well and spring, and vended water). ...

Trottier, Stephanie (Stephanie Marie Gisele)

2010-01-01T23:59:59.000Z

123

Electrolysis of Water and Recombination of Oxygen and Hydrogen Lecture-Demonstration Equipment  

Science Journals Connector (OSTI)

Electrolysis of water takes place in an ordinary Hoffman type apparatus. Hydrogen and oxygen are collected in an explosion chamber where the mixture is detonated using a high-voltage spark coil. The whole equipment operates under the water contained in a large tank.

V. Acosta; D. L. Nordling; K. V. Freed; C. L. Cowan

1967-01-01T23:59:59.000Z

124

DOE Hydrogen Analysis Repository: Water Use for Power Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Use for Power Production Water Use for Power Production Project Summary Full Title: Consumptive Water Use for U.S. Power Production Project ID: 205 Principal Investigator: Paul Torcellini Keywords: Water, energy use, electricity generation Purpose Estimate the water consumption at power plants to provide a metric for determining water efficiency in building cooling systems. Performer Principal Investigator: Paul Torcellini Organization: National Renewable Energy Laboratory (NREL) Address: 1617 Cole Blvd. Golden, CO 80401 Telephone: 303-384-7528 Email: paul_torcellini@nrel.gov Additional Performers: R. Judkoff, National Renewable Energy Laboratory; N. Long, National Renewable Energy Laboratory Period of Performance End: December 2003 Project Description Type of Project: Analysis

125

High Efficiency Generation of Hydrogen Fuels Using Solar Thermochemical Splitting of Water  

SciTech Connect (OSTI)

The objective of this work is to identify economically feasible concepts for the production of hydrogen from water using solar energy. The ultimate project objective was to select one or more competitive concepts for pilot-scale demonstration using concentrated solar energy. Results of pilot scale plant performance would be used as foundation for seeking public and private resources for full-scale plant development and testing. Economical success in this venture would afford the public with a renewable and limitless source of energy carrier for use in electric power load-leveling and as a carbon-free transportation fuel. The Solar Hydrogen Generation Research (SHGR) project embraces technologies relevant to hydrogen research under the Office of Hydrogen Fuel Cells and Infrastructure Technology (HFCIT) as well as concentrated solar power under the Office of Solar Energy Technologies (SET). Although the photoelectrochemical work is aligned with HFCIT, some of the technologies in this effort are also consistent with the skills and technologies found in concentrated solar power and photovoltaic technology under the Office of Solar Energy Technologies (SET). Hydrogen production by thermo-chemical water-splitting is a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or a combination of heat and electrolysis instead of pure electrolysis and meets the goals for hydrogen production using only water and renewable solar energy as feed-stocks. Photoelectrochemical hydrogen production also meets these goals by implementing photo-electrolysis at the surface of a semiconductor in contact with an electrolyte with bias provided by a photovoltaic source. Here, water splitting is a photo-electrolytic process in which hydrogen is produced using only solar photons and water as feed-stocks. The thermochemical hydrogen task engendered formal collaborations among two universities, three national laboratories and two private sector entities. The photoelectrochemical hydrogen task included formal collaborations with three universities and one national laboratory. The formal participants in these two tasks are listed above. Informal collaborations in both projects included one additional university (the University of Nevada, Reno) and two additional national laboratories (Lawrence Livermore National Laboratory and Lawrence Berkeley National Laboratory).

Heske, Clemens; Moujaes, Samir; Weimer, Alan; Wong, Bunsen; Siegal, Nathan; McFarland, Eric; Miller, Eric; Lewis, Michele; Bingham, Carl; Roth, Kurth; Sabacky, Bruce; Steinfeld, Aldo

2011-09-29T23:59:59.000Z

126

DOE Hydrogen Analysis Repository: Water Implications of Biofuels Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Implications of Biofuels Production Water Implications of Biofuels Production Project Summary Full Title: Water Implications of Biofuels Production in the United States Project ID: 227 Principal Investigator: William S. Logan Brief Description: The National Research Council conducted a workshop and wrote a report examining the potential effects of biofuels production in the U.S. on water and related land resources. Purpose Examine the possible effects of biofuel development on water and related land resources. The central questions are how water use and water quality are expected to change as the U.S. agricultural portfolio shifts to include more energy crops and as overall agricultural production potentially increases. Such questions are considered within the context of U.S. policy and also the expected advances in technology and agricultural practices

127

Experimental Study of Solar Hydrogen Production Performance by Water Electrolysis in the South of Algeria  

Science Journals Connector (OSTI)

Current environment problems require the uses of clean process and durable sources in industrial activities. Hydrogen, produced by water electrolysis, represents high clean energy source. In this process, a high electrical energy rate is needed which led to costly product. In order to remedy this issue, the uses of renewable energies are required. In this work, an experimental study of solar hydrogen production system by alkaline water electrolysis in Ouargla (Algeria) city is presented. The alkaline water electrolysis, with different NaOH concentrations, is feed by photovoltaic panels. The system is tested at different input conditions of voltages and currents. Effects of temperature and NaOH electrolyte concentration on hydrogen production are examined

N. Chennouf; N. Settou; B. Negrou; K. Bouziane; B. Dokkar

2012-01-01T23:59:59.000Z

128

Crossed beam reaction of atomic carbon C ( 3 P j ) with hydrogen sulfide, H 2 S (X 1 A 1 ): Observation of the thioformyl radical, HCS (X 2 A?)  

Science Journals Connector (OSTI)

One of the simplest organosulfur reactions that between ground statecarbon atoms C ( 3 P j ) and hydrogen sulfide H 2 S (X 1 A 1 ) was studied at an average collision energy of 21.0 kJ? mol ?1 using the crossed molecular beams technique. The product angular distribution and time-of-flight spectra of m/e=45 ( HC 32 S ) were monitored. Forward-convolution fitting of our data yields an almost isotropic center-of-mass angular flux-distribution whereas the center-of-mass translational energy flux distribution peaks at about 50 kJ? mol ?1 indicating a tight exit transition state from the decomposing thiohydroxycarbene HCSH complex to the reaction products. The high energy cut-off of the translational energy flux distribution is consistent with the formation of the thioformyl radical HCS in its X 2 A electronic ground state. The first experimental verification of an existing thiohydroxycarbene intermediate and the rigorous assignment of the HCS radical product under single collision conditions explicitly suggest inclusion of the title reaction in chemical reaction networks of molecular clouds TMC-1 and OMC-1 the outflow of the carbon star IRC+10216 Shoemaker/Levy 9 impact-induced nonequilibrium sulfur chemistry in the Jovian atmosphere as well as combustion of sulfur containing coal.

R. I. Kaiser; W. Sun; A. G. Suits

1997-01-01T23:59:59.000Z

129

CdSe-MoS2: A Quantum Size-Confined Photocatalyst for Hydrogen Evolution from Water under Visible Light  

E-Print Network [OSTI]

and for the conversion of carbon dioxides into methanol and hydrocarbons. Metal chalcogenides1­9 are promisingCdSe-MoS2: A Quantum Size-Confined Photocatalyst for Hydrogen Evolution from Water under Visible driven pathway to hydrogen. Hydrogen is not only an environmentally benign fuel for the generation

Osterloh, Frank

130

The combined system for fuel supply of fuel cells on the basis of the aluminum-water hydrogen generator and the metal hybride hydrogen storage  

Science Journals Connector (OSTI)

The system for fuel supply of a hydrogen-air fuel cell on the basis of the aluminum-water hydrogen generator and hydride-forming alloy as an intermediate gas storage has been developed. For a series of...4.5 ? x ...

I. V. Yanilkin; Ye. I. Shkol’nikov; S. N. Klyamkin; M. S. Vlaskin…

2010-12-01T23:59:59.000Z

131

Reaction of Aluminum with Water to Produce Hydrogen: A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010.  

Broader source: Energy.gov [DOE]

Produced in 2008 by DOE and updated in 2010, this report focuses on the key issues as well as advantages and disadvantages associated with using the reaction between aluminum metal and water for on-board vehicular hydrogen storage.

132

Hydrogen Generation by Solid Polymer Electrolyte Water Electrolysis  

Science Journals Connector (OSTI)

The General Electric Company -water electrolysis technology, which is based on a solid ... The inherent system advantages of the acid SPE electrolysis technology are explained. System performance predictions are....

L. J. Nuttall; A. P. Fickett; W. A. Titterington

1975-01-01T23:59:59.000Z

133

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

134

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Extracellular Proteins Promote Zinc Sulfide Aggregation Extracellular Proteins Promote Zinc Sulfide Aggregation Print Wednesday, 26 September 2007 00:00 Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

135

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

136

Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines  

E-Print Network [OSTI]

Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines Zhenhao, 2007 A thermodynamic model calculating the solubility of hydrogen sulfide (H2S) in pure water phase. With this specific interaction approach, this model is able to predict H2S solubility in other

Zhu, Chen

137

Hydrogen production from inexhaustible supplies of fresh and salt water using microbial  

E-Print Network [OSTI]

Hydrogen production from inexhaustible supplies of fresh and salt water using microbial reverse-electrodialysis, containing exoelectrogenic bacteria, and a cathode, forming a microbial reverse-electrodialysis electrolysis overpotential, while the reverse electrodialysis stack contributed 0.5­0.6 V at a salinity ratio (seawater

138

Hydrogen Evolution at Activated Nisx-Cathodes in Water Electrolysis  

Science Journals Connector (OSTI)

NiSx-coated nickel cathodes are used for commercial water electrolysis in concentrated KOH solutions. Such electrodes have ... to 5 mol% during 16 days of electrolysis and to about 0.7 mol% after...1.00–1.03. The...

B. Børresen; A. Bjørgum; G. Hagen; R. Tunold…

1998-01-01T23:59:59.000Z

139

Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury, Junrong Zheng, and M. D. Fayer*  

E-Print Network [OSTI]

Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury of picoseconds, observe hydrogen bond breaking and monitor the equilibration of the hydrogen bond network in water. In addition, the vibrational lifetime, the time constant for hydrogen bond breaking, and the rate

Fayer, Michael D.

140

Solar photocatalytic hydrogen production from water using a dual bed photosystem. Task 2 report; Annual report  

SciTech Connect (OSTI)

This work is an investigation into the use of photocatalytic particles in a dual bed configuration, so as to effect the solar-driven decomposition of water to its constituent elements, particularly hydrogen. The system envisioned would consist of two modules, each consisting of a shallow, flat, sealed container, in which micron-sized photocatalytic particles are immobilized. An aqueous solution containing a redox mediator is pumped between the two chambers. Different photoparticles and catalysts are chosen for their respective modules so as to effect oxidative water-splitting in one vessel to evolve oxygen gas, and reductive water-splitting in the other to evolve hydrogen. This is a direct photoconversion scheme that breaks down the energetic requirement for water decomposition into a 2-photon process, and enables separate production of hydrogen and oxygen. Titanium dioxide, TiO{sub 2}, and indium phosphide, InP, were employed as photoparticles in the O{sub 2}- and H{sub 2}-evolving beds, respectively. Platinum catalysts were evaluated to prompt H{sub 2}-evolution. Calculations on the energy band structure of free and immobilized particles provided guidance as to how the microstructure of the particles should be configured. A series of redox mediators, spanning a range of redox potentials, were tested. While many electron donors facilitated H{sub 2}-evolution, only the most oxidizing ones enabled O{sub 2}-evolution. A single redox couple, capable of charge exchange in both modules, is desirable to avoid system design complexity.

Linkous, C.A.; McKaige, G.T.; Slattery, D.K.; Ouellette, A.J.A.; Austin, B.C.N.

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Effect of water vapor/hydrogen environments on niobium, B-66 niobium alloy, tantalum, and Ta-10W alloy  

SciTech Connect (OSTI)

In this paper, the results of an experimental investigation of the effect of water vapor/hydrogen environments on the mechanical properties of niobium, B-66 niobium alloy, tantalum, and Ta-10W alloy are presented. Tensile tests were conducted on specimens of these materials in water vapor/hydrogen mixture ratios of 1 and 3. The water vapor/hydrogen environment caused strength reductions on tantalum and Ta-10W and ductility reductions on all four materials. The degree and causes of embrittlement were a complex function of temperature.

Walter, R.J.; Bentle, G.G.; Chandler, W.T. (Rockwell International Corp., Canoga Park, CA (United States). Rocketdyne Div.)

1991-04-01T23:59:59.000Z

142

To build a photoelectrochemical (PEC) system that produces hydrogen fuel directly from water using sunlight as the energy source.  

E-Print Network [OSTI]

1 SS H2 O2 metaloxide GoalGoal To build a photoelectrochemical (PEC) system that produces hydrogen fuel directly from water using sunlight as the energy source. Approach: development of a multi provides voltage assist using lower-energy photons catalyst surface optimized for hydrogen evolution UH

143

Temperature and water vapor pressure effects on the friction coefficient of hydrogenated diamondlike carbon films.  

SciTech Connect (OSTI)

Microtribological measurements of a hydrogenated diamondlike carbon film in controlled gaseous environments show that water vapor plays a significant role in the friction coefficient. These experiments reveal an initial high friction transient behavior that does not reoccur even after extended periods of exposure to low partial pressures of H{sub 2}O and O{sub 2}. Experiments varying both water vapor pressure and sample temperature show trends of a decreasing friction coefficient as a function of both the decreasing water vapor pressure and the increasing substrate temperature. Theses trends are examined with regard to first order gas-surface interactions. Model fits give activation energies on the order of 40 kJ/mol, which is consistent with water vapor desorption.

Dickrell, P. L.; Sawyer, W. G.; Eryilmaz, O. L.; Erdemir, A.; Energy Technology; Univ. of Florida

2009-07-01T23:59:59.000Z

144

Solar Thermal Energy Cycle Based on Sulfur and Sulfide Oxidizing Bacteria  

Science Journals Connector (OSTI)

New solar energy technologies for the production of biomass for the purpose of synthesizing methane, hydrogen and proteins could be based on the solar generation of the inorganic energy source (Fe2+, metal sulfid...

C. C. Bärtels; H. Tributsch

1991-01-01T23:59:59.000Z

145

Hydrogen bond rearrangements and the motion of charge defects in water viewed using multidimensional ultrafast infrared spectroscopy  

E-Print Network [OSTI]

Compared with other molecular liquids, water is highly structured due to its ability to form up to four hydrogen bonds to its nearest neighbors, resulting in a tetrahedral network of molecules. However, this network is ...

Roberts, Sean T. (Sean Thomas)

2010-01-01T23:59:59.000Z

146

Hydrogen isotopic fractionation factor between brucite and water in the temperature range from 100° to 510° C  

Science Journals Connector (OSTI)

The hydrogen isotopic fractionation factor between brucite and water has been determined in the temperature range of 100°–510° C. Brucite is always depleted in deuterium relative to...3In?=8.72×106 ...

Hiroshi Satake; Sadao Matsuo

147

Effect of hydrogen bridge geometry on the vibrational spectra of water: Three-parameter potential of H bond  

Science Journals Connector (OSTI)

The ability of water molecules to form a three-dimensional network of hydrogen bonds basically determines both the intrinsic structure and unique properties of this liquid and also a character of interactions wit...

Yu. Ya. Efimov

2010-06-01T23:59:59.000Z

148

A novel method of hydrogen generation by water electrolysis using an ultra-short-pulse power supply  

Science Journals Connector (OSTI)

A novel method of hydrogen generation by water electrolysis using ultra-short-pulse power supply is ... pulse with the width of 300 ns, electrolysis takes place with a mechanism dominated by ... from the conventi...

Naohiro Shimizu; Souzaburo Hotta; Takayuki Sekiya…

2006-04-01T23:59:59.000Z

149

Hydordesulfurization of dibenzothiophene using hydrogen generated in situ by the water-gas shift reaction in a trickle bed reactor  

E-Print Network [OSTI]

HYDRODESULFURIZATION OF DIBENZOTHIOPHENE USING HYDROGEN GENERATED IN SITU BY THE WATER ? GAS SHIFT REACTION IN A TRICKLE BED REACTOR A Thesis BRUCE DAVID HOOK Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1984 Major Subject: Chemical Engineering HYDRODESULFURIZATION OF DIBENZOTHIOPHENE USING HYDROGEN GENERATED IN SITU BY THE WATER ? GAS SHIFT REACTION IN A TRICKLE BED REACTOR A Thesis by BRUCE...

Hook, Bruce David

2012-06-07T23:59:59.000Z

150

Metal-and hydrogen-bonding competition during water absorption on Pd(111) and Ru(0001)  

SciTech Connect (OSTI)

The initial stages of water adsorption on the Pd(111) and Ru(0001) surfaces have been investigated experimentally by Scanning Tunneling Microscopy in the temperature range between 40 K and 130 K, and theoretically with Density Functional Theory (DFT) total energy calculations and STM image simulations. Below 125 K water dissociation does not occur at any appreciable rate and only molecular films are formed. Film growth starts by the formation of flat hexamer clusters where the molecules bind to the metal substrate through the O-lone pair while making H-bonds with neighboring molecules. As coverage increases, larger networks of linked hexagons are formed with a honeycomb structure, which requires a fraction of the water molecules to have their molecular plane perpendicular to the metal surface with reduced water-metal interaction. Energy minimization favors the growth of networks with limited width. As additional water molecules adsorb on the surface they attach to the periphery of existing islands, where they interact only weakly with the metal substrate. These molecules hop along the periphery of the clusters at intermediate temperatures. At higher temperatures they bind to the metal to continue the honeycomb growth. The water-Ru interaction is significantly stronger than the water-Pd interaction, which is consistent with the greater degree of hydrogen-bonded network formation and reduced water-metal bonding observed on Pd relative to Ru.

Tatarkhanov, Mouslim; Ogletree, D. Frank; Rose, Franck; Mitsui, Toshiyuki; Fomin, Evgeny; Rose, Mark; Cerda, Jorge I.; Salmeron, Miquel

2009-09-03T23:59:59.000Z

151

Mitigation of Hydrogen Gas Generation from the Reaction of Water with Uranium Metal in K Basins Sludge  

SciTech Connect (OSTI)

Means to decrease the rate of hydrogen gas generation from the chemical reaction of uranium metal with water were identified by surveying the technical literature. The underlying chemistry and potential side reactions were explored by conducting 61 principal experiments. Several methods achieved significant hydrogen gas generation rate mitigation. Gas-generating side reactions from interactions of organics or sludge constituents with mitigating agents were observed. Further testing is recommended to develop deeper knowledge of the underlying chemistry and to advance the technology aturation level. Uranium metal reacts with water in K Basin sludge to form uranium hydride (UH3), uranium dioxide or uraninite (UO2), and diatomic hydrogen (H2). Mechanistic studies show that hydrogen radicals (H·) and UH3 serve as intermediates in the reaction of uranium metal with water to produce H2 and UO2. Because H2 is flammable, its release into the gas phase above K Basin sludge during sludge storage, processing, immobilization, shipment, and disposal is a concern to the safety of those operations. Findings from the technical literature and from experimental investigations with simple chemical systems (including uranium metal in water), in the presence of individual sludge simulant components, with complete sludge simulants, and with actual K Basin sludge are presented in this report. Based on the literature review and intermediate lab test results, sodium nitrate, sodium nitrite, Nochar Acid Bond N960, disodium hydrogen phosphate, and hexavalent uranium [U(VI)] were tested for their effects in decreasing the rate of hydrogen generation from the reaction of uranium metal with water. Nitrate and nitrite each were effective, decreasing hydrogen generation rates in actual sludge by factors of about 100 to 1000 when used at 0.5 molar (M) concentrations. Higher attenuation factors were achieved in tests with aqueous solutions alone. Nochar N960, a water sorbent, decreased hydrogen generation by no more than a factor of three while disodium phosphate increased the corrosion and hydrogen generation rates slightly. U(VI) showed some promise in attenuating hydrogen but only initial testing was completed. Uranium metal corrosion rates also were measured. Under many conditions showing high hydrogen gas attenuation, uranium metal continued to corrode at rates approaching those observed without additives. This combination of high hydrogen attenuation with relatively unabated uranium metal corrosion is significant as it provides a means to eliminate uranium metal by its corrosion in water without the accompanying hazards otherwise presented by hydrogen generation.

Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

2010-01-29T23:59:59.000Z

152

The Integration of a Structural Water-Gas-Shift Catalyst with a Vanadium Alloy Hydrogen Transport Device  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9 9 The InTegraTIon of a STrucTural WaTer- gaS-ShIfT caTalyST WITh a VanadIum alloy hydrogen TranSporT deVIce Description The purpose of this project is to produce a scalable device that simultaneously performs both water-gas-shift (WGS) and hydrogen separation from a coal-derived synthesis gas stream. The justification of such a system is the improved efficiency for the overall production of hydrogen. Removing hydrogen from the synthesis gas (syngas) stream allows the WGS reaction to convert more carbon monoxide (CO) to carbon dioxide (CO 2 ) and maximizes the total hydrogen produced. An additional benefit is the reduction in capital cost of plant construction due to the removal of one step in the process by integrating WGS with the membrane separation device.

153

Evolution of Water Reservoirs on Mars: Constraints from Hydrogen Isotopes in Martian Meteorites  

E-Print Network [OSTI]

Martian surface morphology implies that Mars was once warm enough to maintain persistent liquid water on its surface. While the high D/H ratios (~6 times the Earth's ocean water) of the current martian atmosphere suggest that significant water has been lost from the surface during martian history, the timing, processes, and the amount of the water loss have been poorly constrained. Recent technical developments of ion-microprobe analysis of martian meteorites have provided accurate estimation of hydrogen isotope compositions (D/H) of martian water reservoirs at the time when the meteorites formed. Based on the D/H data from the meteorites, this study demonstrates that the water loss during the pre-Noachian (>41-99 m global equivalent layers, GEL) was more significant than in the rest of martian history (>10-53 m GEL). Combining our results with geological and geomorphological evidence for ancient oceans, we propose that undetected subsurface water/ice (~100-1000 m GEL) should have existed, and it exceeds the ...

Kurokawa, Hiroyuki; Ushioda, Masashi; Matsuyama, Takeshi; Moriwaki, Ryota; Dohm, James M; Usui, Tomohiro

2014-01-01T23:59:59.000Z

154

Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal  

SciTech Connect (OSTI)

The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

Barton, Tom

2013-06-30T23:59:59.000Z

155

Hierarchically Ordered Cadmium Sulfide Nanowires Dispersed in Aqueous Solution  

Science Journals Connector (OSTI)

The paper reports on the preparation, characterization, and dispersion of cadmium sulfide (CdS) nanowires using ordered mesoporous silica, SBA-15, as a template. A homogeneous and stable dispersion of hierarchically ordered CdS nanowires in water ...This work demonstrates the formation of cadmium sulfide (CdS) nanowires. These nanowires are templated by mesoporous SBA-15 and their connectivity is tuned by the number of nanoconnectors (templated by micropores). They form stable dispersions in aqueous sodium dodecyl sulfate (SDS) solutions.

Rajagopalan Thiruvengadathan; Oren Regev

2005-05-17T23:59:59.000Z

156

Apparatus and method for simultaneous recovery of hydrogen from water and from hydrocarbons  

DOE Patents [OSTI]

Apparatus and method for simultaneous recovery of hydrogen from water and from hydrocarbon feed material. The feed material is caused to flow over a heated catalyst which fosters the water-gas shift reaction (H.sub.2 O+COH.sub.2 +CO.sub.2) and the methane steam reforming reaction (CH.sub.4 +H.sub.2 O3 H.sub.2 +CO). Both of these reactions proceed only to partial completion. However, by use of a Pd/Ag membrane which is exclusively permeable to hydrogen isotopes in the vicinity of the above reactions and by maintaining a vacuum on the permeate side of the membrane, product hydrogen isotopes are removed and the reactions are caused to proceed further toward completion. A two-stage palladium membrane reactor was tested with a feed composition of 28% CQ.sub.4, 35% Q.sub.2 O (where Q=H, D, or T), and 31% Ar in 31 hours of continuous operation during which 4.5 g of tritium were processed. Decontamination factors were found to increase with decreasing inlet rate. The first stage was observed to have a decontamination factor of approximately 200, while the second stage had a decontamination factor of 2.9.times.10.sup.6. The overall decontamination factor was 5.8.times.10.sup.8. When a Pt/.alpha.-Al.sub.2 O.sub.3 catalyst is employed, decoking could be performed without catalyst degradation. However, by adjusting the carbon to oxygen ratio of the feed material with the addition of oxygen, coking could be altogether avoided.

Willms, R. Scott (Los Alamos, NM); Birdsell, Stephen A. (Los Alamos, NM)

2000-01-01T23:59:59.000Z

157

Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process)  

SciTech Connect (OSTI)

The CAMERE process (carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction) was developed and evaluated. The reverse-water-gas-shift reactor and the methanol synthesis reactor were serially aligned to form methanol from CO{sub 2} hydrogenation. Carbon dioxide was converted to CO and water by the reverse-water-gas-shift reaction (RWReaction) to remove water before methanol was synthesized. With the elimination of water by RWReaction, the purge gas volume was minimized as the recycle gas volume decreased. Because of the minimum purge gas loss by the pretreatment of RWReactor, the overall methanol yield increased up to 89% from 69%. An active and stable catalyst with the composition of Cu/ZnO/ZrO{sub 2}/Ga{sub 2}O{sub 3} (5:3:1:1) was developed. The system was optimized and compared with the commercial methanol synthesis processes from natural gas and coal.

Joo, O.S.; Jung, K.D.; Han, S.H.; Uhm, S.J. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.] [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.; Moon, I. [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering] [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering; Rozovskii, A.Y.; Lin, G.I. [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)] [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)

1999-05-01T23:59:59.000Z

158

Hydrogen Energy Technology Geoff Dutton  

E-Print Network [OSTI]

Integrated gasification combined cycle (IGCC) Pyrolysis Water electrolysis Reversible fuel cell Hydrogen Hydrogen-fuelled internal combustion engines Hydrogen-fuelled turbines Fuel cells Hydrogen systems Overall expensive. Intermediate paths, employing hydrogen derived from fossil fuel sources, are already used

Watson, Andrew

159

Efficient, sustainable production of molecular hydrogen -a promising alternative to batteries in terms of energy storage -is still an unsolved problem. Implementation of direct water splitting  

E-Print Network [OSTI]

in terms of energy storage - is still an unsolved problem. Implementation of direct water splitting usingEfficient, sustainable production of molecular hydrogen - a promising alternative to batteries

KuÂ?el, Petr

160

X-ray Photoelectron Spectroscopy of GaP{1-x}N(x) Photocorroded as a Result of Hydrogen Production through Water Electrolysis  

E-Print Network [OSTI]

X-ray Photoelectron Spectroscopy of GaP{1-x}N(x) Photocorroded as a Result of Hydrogen Production through Water Electrolysis

Mayer, Marie A

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Oxidative Remobilization of Technetium Sequestered by Sulfide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron. Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent...

162

Purification of sulfide oxidase from rat liver  

E-Print Network [OSTI]

of sulfide oxidase, provided an initial precipitation of sulfide oxidase, and after chromatographic procedures a 21 fold purification of the enzyme was obtained....

Pu, Lixia

1994-01-01T23:59:59.000Z

163

Using of produced water associated with oil and gas production as a source of hydrogen: solar electrolysis cell application  

E-Print Network [OSTI]

Abstract In frame of the growing global concerns regarding to the high extent of environmental pollution and its serious consequences on the future of the planet. The seek out for a proper source of clean energy is considered to be a top priority. Where a substantial reduction in a present reliance on fossil fuels is achieved. This objective can not be factual without intensive efforts to find out the appropriate alternative, which are the sustainable and environmentally friendly energy alternatives. The use of hydrogen as an alternative fuel is gaining more and more acceptance as the environmental impact of hydrocarbons becomes more evident. The using of enormous amount of a polluted produced water associated oil and gas production activities to generate the hydrogen by solar hydrolysis cell, is considered to be a multi advantages alternative, where the volume of polluted and environmentally risky water been reduced and a significant volume of hydrogen been gained. This work is an attempt to design of a hydrogen generating station by water electrolysis whose energy resources are solar. The electricity supply is done by photovoltaic cells. The novelty of this work is the using of produced water to generate a clean energy (hydrogen), and in the same time reducing the threats caused by the disposal pits of the vast volume of the produced water at oilfields, which is the biggest challenge to the oil industry and the environment. In this work, the produced water has been electrolyzed by using solar energy. Standard chemical analyses methods have followed to determine the pollutants constitutes in this water. A pilot plant of

Maher A. R; Sadiq Al-baghdadi; Hashim R. Abdolhamid B; Omar A. Mkhatresh B

164

Water vapour and hydrogen in the terrestrial-planet-forming region of a protoplanetary disk  

E-Print Network [OSTI]

Planetary systems, ours included, are formed in disks of dust and gas around young stars. Disks are an integral part of the star and planet formation process, and knowledge of the distribution and temperature of inner disk material is crucial for understanding terrestrial planet formation, giant planet migration, and accretion onto the central star. While the inner regions of protoplanetary disks in nearby star forming regions subtend only a few nano-radians, near-IR interferometry has recently enabled the spatial resolution of these terrestrial zones. Most observations have probed only dust, which typically dominates the near-IR emission. Here I report spectrally dispersed near-IR interferometric observations that probe gas (which dominates the mass and dynamics of the inner disk), in addition to dust, within one astronomical unit of the young star MWC 480. I resolve gas, including water vapor and atomic hydrogen, interior to the edge of the dust disk; this contrasts with results of previous spectrally dispersed interferometry observations. Interactions of this accreting gas with migrating planets may lead to short-period exoplanets like those detected around main-sequence stars. The observed water vapor is likely produced by the sublimation of migrating icy bodies, and provides a potential reservoir of water for terrestrial planets.

J. A. Eisner

2007-06-08T23:59:59.000Z

165

UNCORRECTEDPROOF The effect of temperature on the adsorption rate of hydrogen  

E-Print Network [OSTI]

size, and low operating temperatures. In a ``hydrogen challenged'' economy, the fuel for the PEMFCsUNCORRECTEDPROOF DTD 5 The effect of temperature on the adsorption rate of hydrogen sulfide on Pt adsorbed at lower temperatures. A value of the activation energy of hydrogen sulfide adsorption on Pt

Van Zee, John W.

166

Pt loaded carbon aerogel catalyst for catalytic exchange reactions between water and hydrogen gas  

Science Journals Connector (OSTI)

We report development and characterization of platinum doped carbon aerogel catalyst for catalytic exchange reactions between water and hydrogen gas. The carbon aerogel with uniformly dispersed platinum nanoparticles was prepared by adding platinum precursor during the sol-gel process. Thereafter colloidal PTFE was mixed with the platinum doped carbon aerogel powder and coated on Dixon rings to obtain hydrophobic catalyst with required mechanical strength. Detailed studies have been carried out to observe the effect of physical characteristics of the catalyst powder (surface area and pore size of aerogels Pt cluster size and its valence state etc) and the different coating parameters (PTFE to Pt-CA ratio and Pt loading on Dixon ring) on volume transfer rate (Ky.a) for H/D reaction. Ky.a values of ?0.8 m3 (STP).s?1. m?3 were obtained for Pt loading of 7% and Pt cluster size of 3 nm at atmospheric pressure.

P. K. Gupta

2013-01-01T23:59:59.000Z

167

PRODUCTION OF HYDROGEN BY SUPERADIABATIC DECOMPOSITION OF HYDROGEN SULFIDE  

E-Print Network [OSTI]

in a cylindrical vessel packed with a porous ceramic medium with a high thermal capacity. The intensive heat internal surfaces permits the accumulation of combustion energy in the solid matrix. As a result, flame hydrocarbons via the superadiabatic partial oxidation have shown the high potential of this approach. It has

168

Experimental investigation of the effects of water electrolysis parameters on the amount of hydrogen damage in Pb(Zr,Ti)O3  

Science Journals Connector (OSTI)

Water electrolysis technique has been used in this work...3 (PZT), and the effects of water electrolysis parameters on the amount of hydrogen damage ... investigations show that increasing the current density dur...

A. Shafiei; A. Alfantazi

2014-01-01T23:59:59.000Z

169

Ab initio Equation of State data for hydrogen, helium, and water and the internal structure of Jupiter  

E-Print Network [OSTI]

The equation of state of hydrogen, helium, and water effects interior structure models of giant planets significantly. We present a new equation of state data table, LM-REOS, generated by large scale quantum molecular dynamics simulations for hydrogen, helium, and water in the warm dense matter regime, i.e.for megabar pressures and temperatures of several thousand Kelvin, and by advanced chemical methods in the complementary regions. The influence of LM-REOS on the structure of Jupiter is investigated and compared with state-of-the-art results within a standard three-layer model consistent with astrophysical observations of Jupiter. Our new Jupiter models predict an important impact of mixing effects of helium in hydrogen with respect to an altered compressibility and immiscibility.

N. Nettelmann; B. Holst; A. Kietzmann; M. French; R. Redmer; D. Blaschke

2007-12-06T23:59:59.000Z

170

Stable isotopes of hydrogen and oxygen in surface water and ground water at selected sites on or near the Idaho National Engineering Laboratory, Idaho  

SciTech Connect (OSTI)

Relative stable isotopic ratios for hydrogen and oxygen compared to standard mean ocean water are presented for water from 4 surface-water sites and 38 ground-water sites on or near the Idaho National Engineering Laboratory (INEL). The surface-water samples were collected monthly from March 1991 through April 1992 and after a storm event on June 18, 1992. The ground-water samples either were collected during 1991 or 1992. These data were collected as part of the US Geological Survey`s continuing hydrogeological investigations at the INEL. The relative isotopic ratios of hydrogen and oxygen are reported as delta {sup 2}H ({delta}{sup 2}H) and as delta {sup 18}O ({delta}{sup 18}O), respectively. The values of {delta}{sup 2}H and {delta}{sup 18}O in water from the four surface-water sites ranged from -143.0 to -122 and from -18.75 to -15.55, respectively. The values of {delta}{sup 2}H and {delta}{sup 18}O in water from the 38 ground-water sites ranged from -141.0 to -120.0 and from -18.55 to -14.95, respectively.

Ott, D.S.; Cecil, L.D.; Knobel, L.L.

1994-11-01T23:59:59.000Z

171

Membrane contactor assisted water extraction system for separating hydrogen peroxide from a working solution, and method thereof  

DOE Patents [OSTI]

The present invention relates to a membrane contactor assisted extraction system and method for extracting a single phase species from multi-phase working solutions. More specifically one preferred embodiment of the invention relates to a method and system for membrane contactor assisted water (MCAWE) extraction of hydrogen peroxide (H.sub.2O.sub.2) from a working solution.

Snyder, Seth W. (Lincolnwood, IL); Lin, Yupo J. (Naperville, IL); Hestekin' Jamie A. (Fayetteville, AR); Henry, Michael P. (Batavia, IL); Pujado, Peter (Kildeer, IL); Oroskar, Anil (Oak Brook, IL); Kulprathipanja, Santi (Inverness, IL); Randhava, Sarabjit (Evanston, IL)

2010-09-21T23:59:59.000Z

172

Sunlight-Driven Hydrogen Formation by Membrane-Supported Photoelectrochemical Water Splitting  

SciTech Connect (OSTI)

This report describes the significant advances in the development of the polymer-supported photoelectrochemical water-splitting system that was proposed under DOE grant number DE-FG02-05ER15754. We developed Si microwire-array photoelectrodes, demonstrated control over the material and light-absorption properties of the microwire-array photoelectrodes, developed inexpensive processes for synthesizing the arrays, and doped the arrays p-type for use as photocathodes. We also developed techniques for depositing metal-nanoparticle catalysts of the hydrogen-evolution reaction (HER) on the wire arrays, investigated the stability and catalytic performance of the nanoparticles, and demonstrated that Ni-Mo alloys are promising earth-abundant catalysts of the HER. We also developed methods that allow reuse of the single-crystalline Si substrates used for microwire growth and methods of embedding the microwire photocathodes in plastic to enable large-scale processing and deployment of the technology. Furthermore we developed techniques for controlling the structure of WO3 films, and demonstrated that structural control can improve the quantum yield of photoanodes. Thus, by the conclusion of this project, we demonstrated significant advances in the development of all components of a sunlight-driven membrane-supported photoelectrochemical water-splitting system. This final report provides descriptions of some of the scientific accomplishments that were achieved under the support of this project and also provides references to the peer-reviewed publications that resulted from this effort.

Lewis, Nathan S. [California Institute of Technology] [California Institute of Technology

2014-03-26T23:59:59.000Z

173

Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting  

Science Journals Connector (OSTI)

...electacta.2007.11.027 37 Gahleitner G. , Hydrogen from renewable electricity: An international review of power-to-gas pilot plants for stationary applications . Int. J. Hydrogen Energy 38 , 2039 – 2061 ( 2013 ). 10.1016/j.ijhydene...

Benjamin Rausch; Mark D. Symes; Greig Chisholm; Leroy Cronin

2014-09-12T23:59:59.000Z

174

Oxygen tolerance of an in silico-designed bioinspired hydrogen-evolving catalyst in water  

Science Journals Connector (OSTI)

...32 Zipoli F Car R Cohen MH...A ( 2009 ) Hydrogen production...reduction at a fuel-cell cathode . J Phys...current for hydrogen evolution...Reduction at a Fuel-Cell cathode...Current for Hydrogen Evolution...Zipoli, F., Car, R., Cohen...

Patrick H.-L. Sit; Roberto Car; Morrel H. Cohen; Annabella Selloni

2013-01-01T23:59:59.000Z

175

Elemental and isotopic compositions of the hydrothermal sulfide on the East Pacific Rise near 13°N  

Science Journals Connector (OSTI)

The mineralogical, elemental, and isotopic characteristics of a hydrothermal sulfide sample from one dredge station (12°42.30?N, 103°54.48?W, water depth 2655 m) on the East Pacific Rise near 13°N were analyze...

ZhiGang Zeng; DaiGeng Chen; XueBo Yin; XiaoYuan Wang…

2010-02-01T23:59:59.000Z

176

Effect of Water Transport on the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer  

E-Print Network [OSTI]

be developed that provides efficient production of clean hydrogen. The methods existing today for large-scale produc- tion of hydrogen typically involve hydrocarbon reforming of natural gas or coal gasification% , the overall efficiency is 40%.7 Two issues remain, however, that make the future of this technology un

Weidner, John W.

177

Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting  

Science Journals Connector (OSTI)

...system that uses a carbon cathode to reduce protons and a...SiW 12 O 40 ] at a carbon cathode. Alternatively, starting from the fully oxidized...Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction . J...electrocatalysis to stack development . Int. J. Hydrogen Energy...

Benjamin Rausch; Mark D. Symes; Greig Chisholm; Leroy Cronin

2014-09-12T23:59:59.000Z

178

Water molecules insert into N-HCl-M hydrogen bonds while M-ClX-C halogen bonds remain intact in dihydrates of halopyridinium hexachloroplatinates  

Science Journals Connector (OSTI)

Crystals of the dihydrates of three halopyridinium hexachloroplatinate salts form networks that are propagated via N-HO and O-HCl-Pt hydrogen bonds and Pt-ClX-C halogen bonds. The water molecules can be considered to have been inserted into N-HCl-Pt hydrogen bonds anticipated in the anyhdrous form of such salts.

Zordan, F.

2004-09-15T23:59:59.000Z

179

Characterization of a new magnesium hydrogen orthophosphate salt, Mg3.5H2(PO4)3, synthesized in supercritical water  

E-Print Network [OSTI]

Characterization of a new magnesium hydrogen orthophosphate salt, Mg3.5H2(PO4)3, synthesized 2007 Available online 31 March 2007 Abstract Beige crystals of a new magnesium hydrogen orthophosphate water; IR and Raman spectra; Magnesium; Orthophosphate; Nanomaterial 1. Introduction Inorganic

Ryan, Dominic

180

Synthesis and Optical Properties of Sulfide Nanoparticles Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optical Properties of Sulfide Nanoparticles Prepared in Dimethylsulfoxide. Synthesis and Optical Properties of Sulfide Nanoparticles Prepared in Dimethylsulfoxide. Abstract: Many...

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Solar energy: Hydrogen and oxygen  

Science Journals Connector (OSTI)

Solar energy: Hydrogen and oxygen ... Demonstrating the electrolysis of water with solar energy. ...

John J. Farrell

1982-01-01T23:59:59.000Z

182

Corrosion Behavior of 304 Stainless Steel in High Temperature, Hydrogenated Water  

SciTech Connect (OSTI)

The corrosion behavior of an austenitic stainless steel (UNS S30400) has been characterized in a 10,000 hour test conducted in hydrogenated, ammoniated water at 260 C. The corrosion kinetics were observed to follow a parabolic rate dependency, the parabolic rate constant being determined by chemical descaling to be 1.16 mg dm{sup -2} hr{sup -1/2}. X-ray photoelectron spectroscopy, in combination with argon ion milling and target factor analysis, was applied to provide an independent estimate of the rate constant that agreed with the gravimetric result. Based on the distribution of the three oxidized alloying constituents (Fe, Cr, Ni) with respect to depth and elemental state, it was found that: (a) corrosion occurs in a non-selective manner, and (b) the corrosion film consists of two spinel oxide layers--a ferrite-based outer layer (Ni{sub 0.2}Fe{sub 0.8})(Fe{sub 0.95}Cr{sub 0.05}){sub 2}O{sub 4} on top of a chromite-based inner layer (Ni{sub 0.2}Fe{sub 0.8})(Cr{sub 0.7}Fe{sub 0.3}){sub 2}O{sub 4}. These compositions agree closely with the solvi phases created by immiscibility in the Fe{sub 3}O{sub 4}-FeCr{sub 2}O{sub 4} binary, implying that immiscibility plays an important role in the phase separation process.

S.E. Ziemniak; M. Hanson

2001-05-04T23:59:59.000Z

183

Water Molecules Hydrogen Bonding to Aromatic Acceptors of Amino Acids: the Structure of Tyr-Tyr-Phe Dihydrate and a Crystallographic Database Study on Peptides  

Science Journals Connector (OSTI)

In the crystal structure of Tyr-Tyr-Phe dihydrate, one of the water molecules forms a hydrogen bond with the Phe side chain. In a database study four related examples in peptides are found.

Steiner, T.

1998-01-01T23:59:59.000Z

184

The Behaviour of Electrolytes in Mixed Solvents. Part I. The Free Energies and Heat Contents of Hydrogen Chloride in Water-Ethyl Alcohol Solutions  

Science Journals Connector (OSTI)

1 November 1929 research-article The Behaviour of Electrolytes in Mixed Solvents. Part I. The Free Energies and Heat Contents of Hydrogen Chloride in Water-Ethyl Alcohol Solutions J. A. V. Butler C. M. Robertson The Royal Society...

1929-01-01T23:59:59.000Z

185

Zinc Treatment Effects on Corrosion Behavior of 304 Stainless Steel in High Temperature, Hydrogenated Water  

SciTech Connect (OSTI)

Trace levels of soluble zinc(II) ions (30 ppb) maintained in mildly alkaline, hydrogenated water at 260 C were found to lower the corrosion rate of austenitic stainless steel (UNS S30400) by about a factor of five, relative to a non-zinc baseline test after 10,000 hr. Characterizations of the corrosion oxide layer via grazing incidence X-ray diffraction and X-ray photoelectron spectroscopy in combination with argon ion milling and target factor analysis, confirmed the presence of two spinel oxide phases and minor amounts of recrystallized nickel. Based on the distribution of the three oxidized alloying constituents (Fe, Cr, Ni) with respect to depth and oxidation state, it was concluded that: (a) corrosion occurs in a non-selective manner, but approximately 30% of the oxidized iron is released to the water, and (b) the two spinel oxides exist as a ferrite-based outer layer (Ni{sub 0.1}Zn{sub 0.6}Fe{sub 0.3})(Fe{sub 0.95}Cr{sub 0.05}){sub 2}O{sub 4} on top of a chromite-based inner layer (Ni{sub 0.1}Zn{sub 0.2}Fe{sub 0.7})(Fe{sub 0.4}Cr{sub 0.6}){sub 2}O{sub 4}. These results suggest that immiscibility in the Fe{sub 3}O{sub 4}-ZnFe{sub 2}O{sub 4} binary may play a role in controlling the zinc content of the outer layer. On the other hand, the lower corrosion rate caused by zinc additions is believed to be a consequence of corrosion oxide film stabilization due to the substitution reaction equilibrium: z Zn{sup 2+}(aq) + FeCr{sub 2}O{sub 4}(s) {approx} z Fe{sup 2+}(aq) + (Zn{sub z}Fe{sub 1-z})Cr{sub 2}O{sub 4}(s). The liquid-solid distribution coefficient for the reaction, defined by the ratio of total zinc to iron ion concentrations in solution divided by the Zn(II)/Fe(II) ratio in the solid, z/(1-z), was found to be 0.184. This interpretation is consistent with the benefits of zinc treatment being concentration dependent.

S.E. Ziemniak; M. Hanson

2001-03-20T23:59:59.000Z

186

Catalytic reduction of CO with hydrogen sulfide. 3. Study of adsorption of O/sub 2/, CO, and CO coadsorbed with H/sub 2/S on anatase and rutile using Auger electron spectroscopy and temperature-programmed desorption  

SciTech Connect (OSTI)

In O/sub 2/ and CO adsorption on anatase, only one weakly bound molecular desorption state was observed. For CO on rutile, there was a strongly bound and a weakly bound state. For O/sub 2/ rutile, a weakly bound state and two strongly chemisorbed states were observed. These strongly bound states are associated with the surface lattice anion vacancies produced on rutile (110). The amount of chemisorption in one of the strongly bound oxygen desorption states is correlated with the initial rate of irreversible adsorption of H/sub 2/S on rutile. Coadsorption of CO and H/sub 2/S indicates that strongly chemisorbed CO interacts with strongly chemisorbed H/sub 2/S to yield intermediates which desorb as CH/sub 3/SH and CH/sub 4/ at T approx. 800 K. At higher temperatures the surface sulfide concentration dominates the -SH concentration, explaining the dominance of COS in the product mixture. Implications of commercial hydrodesulfurization catalysts are discussed.

Beck, D.D.; White, J.M.; Ratcliffe, C.T.

1986-07-03T23:59:59.000Z

187

Biosynthesis and urinary excretion of methyl sulfonium derivatives of the sulfur mustard analog, 2-chloroethyl ethyl sulfide, and other thioethers  

SciTech Connect (OSTI)

Thioether methyltransferase was previously shown to catalyze the S-adenosylmethionine-dependent methylation of diemthyl selenide, dimethyl telluride, and various thioethers to produce the corresponding methyl onium ions. In this paper we show that the following thioethers are also substrates for this enzyme in vitro: 2-hydroxyethyl ethyl sulfide, 2-chloroethyl ethyl sulfide, thiodiglycol, t-butyl sulfide, and isopropyl sulfide. To demonstrate thioether methylation in vivo, mice were injected with (methyl-{sup 3}H)methionine plus different thioethers, and extracts of lungs, livers, kidneys, and urine were analyzed by high-performance liquid chromatography for the presence of ({sup 3}H)methyl sulfonium ions. The following thioethers were tested, and all were found to be methylated in vivo: dimethyl sulfide, diethyl sulfide, methyl n-propyl sulfide, tetrahydrothiophene, 2-(methylthio)ethylamine, 2-hydroxyethyl ethyl sulfide, and 2-chloroethyl ethyl sulfide. This supports our hypothesis that the physiological role of thioether methyltransferase is to methylate seleno-, telluro-, and thioethers to more water-soluble onium ions suitable for urinary excretion. Conversion of the mustard gas analog, 2-chloroethyl ethyl sulfide, to the methyl sulfonium derivative represents a newly discovered mechanism for biochemical detoxification of sulfur mustards, as this conversion blocks formation of the reactive episulfonium ion that is the ultimate alkylating agent for this class of compounds.

Mozier, N.M.; Hoffman, J.L. (Univ. of Louisville, KY (USA))

1990-12-01T23:59:59.000Z

188

Strategic Directions for Hydrogen Delivery Workshop Proceedings  

Broader source: Energy.gov (indexed) [DOE]

including water or oil pipelines for hydrogen transport Assess viability of natural gas safety systems when hydrogen is introduced Conduct field demonstra- tion of hydrogen...

189

On Methods for the Large-Scale Production of Hydrogen from Water  

Science Journals Connector (OSTI)

Off-peak power would give sufficiently cheap hydrogen with classical electrolyzers. Emerging technology could produce it at between $0.85 and $2.90 (106 Btu)-1 for electricity costs (bulk purchase) between 2 and ...

J. O’M. Bockris

1975-01-01T23:59:59.000Z

190

NREL: Hydrogen and Fuel Cells Research - Hydrogen Production and Delivery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production and Delivery Hydrogen Production and Delivery Most of the hydrogen in the United States is produced by steam reforming of natural gas. For the near term, this production method will continue to dominate. Researchers at NREL are developing advanced processes to produce hydrogen economically from sustainable resources. NREL's hydrogen production and delivery R&D efforts, which are led by Huyen Dinh, focus on the following topics: Biological Water Splitting Fermentation Conversion of Biomass and Wastes Photoelectrochemical Water Splitting Solar Thermal Water Splitting Renewable Electrolysis Hydrogen Dispenser Hose Reliability Hydrogen Production and Delivery Pathway Analysis. Biological Water Splitting Certain photosynthetic microbes use light energy to produce hydrogen from

191

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS  

E-Print Network [OSTI]

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS S.W. Banovic, J.N. Du (Received January 5, 1998) (Accepted March 23, 1998) Introduction Iron-aluminum weld overlay coatings, the application of iron-aluminum alloys is currently limited due to hydrogen cracking susceptibility subsequent

DuPont, John N.

192

Stable catalyst layers for hydrogen permeable composite membranes  

DOE Patents [OSTI]

The present invention provides a hydrogen separation membrane based on nanoporous, composite metal carbide or metal sulfide coated membranes capable of high flux and permselectivity for hydrogen without platinum group metals. The present invention is capable of being operated over a broad temperature range, including at elevated temperatures, while maintaining hydrogen selectivity.

Way, J. Douglas; Wolden, Colin A

2014-01-07T23:59:59.000Z

193

The role of hydrogen in methane formation from carbon and water over metal catalysts  

E-Print Network [OSTI]

in air at 300 C for 2 h and at 400 C for 2 h. Calcination was followed by reduction under hydrogen at 300oC for 2 h, then at 425oC for 2 h. Before the catalyst was used, it was crushed using a mortar and pestle, and sieved to between 10 and 20 mesh... OR Figure 1. Diagram of On-line Gas Chromatograph 11 Rt the termination of an analysis, both hydrogen and carbon containing products of each reaction were compared to assure reproducibility. The detector unit for the on-line gas chromatograph...

Moore, Stanley Edwin

2012-06-07T23:59:59.000Z

194

C. Plennevaux et al., Electrochemistry Communications 26 (2013) 1720 Contribution of CO2 on hydrogen evolution and hydrogen permeation in low  

E-Print Network [OSTI]

Introduction The risk of hydrogen embrittlement of steels is a primary concern for material selection in oil the risk of hydrogen embrittlement. Sulfide stress cracking (SSC) is one of the main risks of steel on hydrogen evolution and hydrogen permeation in low alloy steels exposed to H2S environment C. Plennevauxa

Paris-Sud XI, Université de

195

Formation of Hydrogen Peroxide in Water Irradiated with X- and Alpha-Rays  

Science Journals Connector (OSTI)

... of very different ionic density, namely, 0·9 A. X-rays and polonium or radon?-rays. Methods. The irradiation with X-rays and the titration of hydrogen peroxide ... x-rays. The ionic yield, in the case of X-rays, suggests that the radon (3-rays probably account for less than 5 per cent of the total effect ...

P. BONET-MAURY; M. LEFORT

1948-09-04T23:59:59.000Z

196

Redox cycle stability of mixed oxides used for hydrogen generation in the cyclic water gas shift process  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Fe{sub 2}O{sub 3} modified with CaO, SiO{sub 2} and Al{sub 2}O{sub 3} was studied in cyclic water gas shift reactor. • For the first time stability of such oxides were tested for 100 redox cycles. • Optimally added oxides significantly improved the activity and the stability of Fe{sub 2}O{sub 3}. • Increased stability was attributed to the impediment of neck formation. - Abstract: Repeated cycles of the reduction of Fe{sub 3}O{sub 4} with reductive gas, e.g. hydrogen and subsequent oxidation of the reduced iron material with water vapor can be harnessed as a process for the production of pure hydrogen. The redox behavior of iron oxide modified with various amounts of SiO{sub 2}, CaO and Al{sub 2}O{sub 3} was investigated in the present study. The total amount of the additional metal oxides was always below 15 wt%. The samples were prepared by co-precipitation using urea hydrolysis method. The influence of various metal oxides on the hydrogen production capacity and the material stability was studied in detail in terms of temperature-programmed reduction (TPR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET analysis. Furthermore, the activity and the stability of the samples were tested in repeated reduction with diluted H{sub 2} and re-oxidation cycles with H{sub 2}O. The results indicate that combination of several oxides as promoter increases the stability of the iron oxide material by mitigating the sintering process. The positive influence of the oxides in stabilizing the iron oxide material is attributed to the impediment of neck formation responsible for sintering.

Datta, Pradyot, E-mail: pradyot.datta@gmail.com

2013-10-15T23:59:59.000Z

197

Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy  

SciTech Connect (OSTI)

We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O-H stretch mode at 3 mu m, probed via soft x-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft x-ray spectroscopy in liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8MPa, is manifest by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

Huse, Nils; Wen, Haidan; Nordlund, Dennis; Szilagyi, Erzsi; Daranciang, Dan; Miller, Timothy A.; Nilsson, Anders; Schoenlein, Robert W.; Lindenberg, Aaron M.

2009-04-24T23:59:59.000Z

198

Hydrogen production by supercritical water gasification of biomass. Phase 1 -- Technical and business feasibility study, technical progress report  

SciTech Connect (OSTI)

The nine-month Phase 1 feasibility study was directed toward the application of supercritical water gasification (SCWG) for the economical production and end use of hydrogen from renewable energy sources such as sewage sludge, pulp waste, agricultural wastes, and ultimately the combustible portion of municipal solid waste. Unique in comparison to other gasifier systems, the properties of supercritical water (SCW) are ideal for processing biowastes with high moisture content or contain toxic or hazardous contaminants. During Phase I, an end-to-end SCWG system was evaluated. A range of process options was initially considered for each of the key subsystems. This was followed by tests of sewage sludge feed preparation, pumping and gasification in the SCW pilot plant facility. Based on the initial process review and successful pilot-scale testing, engineering evaluations were performed that defined a baseline system for the production, storage and end use of hydrogen. The results compare favorably with alternative biomass gasifiers currently being developed. The results were then discussed with regional wastewater treatment facility operators to gain their perspective on the proposed commercial SCWG systems and to help define the potential market. Finally, the technical and business plans were developed based on perceived market needs and the projected capital and operating costs of SCWG units. The result is a three-year plan for further development, culminating in a follow-on demonstration test of a 5 MT/day system at a local wastewater treatment plant.

NONE

1997-12-01T23:59:59.000Z

199

Coproduction of sulphuric acid and hydrogen by sulphur-assisted water electrolysis process  

Science Journals Connector (OSTI)

The addition of sulphur powder to the anode compartment of the sulphuric acid-water electrolysis cell resulted in the suppression of oxygen... 4 2? ...) by the ...

Y. S. Shih; M. J. Jong

1983-01-01T23:59:59.000Z

200

Sulfidation of coal gasifier heat exchanger alloys  

Science Journals Connector (OSTI)

Three steels, viz., INCOLOY* 800H, Fecralloy,† and AlSI 310, were exposed to a simulated low Btu coal gasifier product gas at 450 °C. Sulfidation...

S. R. J. Saunders; S. Schlierer

1986-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Ion Hydration and Associated Defects in Hydrogen Bond Network of Water: Observation of Reorientationally Slow Water Molecules Beyond First Hydration Shell in Aqueous Solutions of MgCl$_2$  

E-Print Network [OSTI]

Effects of presence of ions, at moderate to high concentrations, on dynamical properties of water molecules are investigated through classical molecular dynamics simulations using two well known non-polarizable water models. Simulations reveal that the presence of magnesium chloride (MgCl$_2$) induces perturbations in the hydrogen bond network of water leading to the formation of bulk-like domains with \\textquoteleft defect sites\\textquoteright~on boundaries of such domains: water molecules at such defect sites have less number of hydrogen bonds than those in bulk water. Reorientational autocorrelation functions for dipole vectors of such defect water molecules are computed at different concentrations of ions and compared with system of pure water. Earlier experimental and simulation studies indicate significant differences in reorientational dynamics for water molecules in the first hydration shell of many dissolved ions. Results of this study suggest that defect water molecules, which are beyond the first hydration shells of ions, also experience significant slowing down of reorientation times as a function of concentration in the case of MgCl$_2$. However, addition of cesium chloride(CsCl) to water does not perturb the hydrogen bond network of water significantly even at higher concentrations. This difference in behavior between MgCl$_2$ and CsCl is consistent with the well-known Hofmeister series.

Upayan Baul; Satyavani Vemparala

2014-12-18T23:59:59.000Z

202

Influence of physisorbed water on the conductivity of hydrogen terminated silicon-on-insulator surfaces  

E-Print Network [OSTI]

the water layer is displaced by inert gas purging, heating, or pumping. The observed conductivity changes active defects as the surface oxidizes. Surprisingly, physisorbed water via adsorption from ambient.1063/1.2822417 On semiconductor surfaces adsorption or reaction events which result in charge redistribution give rise to changes

203

A Near-term Economic Analysis of Hydrogen Fueling Stations  

E-Print Network [OSTI]

hydrogen dispenser Reverse osmosis and deionizer waterAlkaline Electrolyzer Reverse osmosis and deionizer water

Weinert, Jonathan X.

2005-01-01T23:59:59.000Z

204

A Near-Term Economic Analysis of Hydrogen Fueling Stations  

E-Print Network [OSTI]

hydrogen dispenser Reverse osmosis and deionizer waterAlkaline Electrolyzer Reverse osmosis and deionizer water

Weinert, Jonathan X.

2005-01-01T23:59:59.000Z

205

Proceedings of the workshop on the impact of hydrogen on water reactor safety. Volume II of IV  

SciTech Connect (OSTI)

Separate abstracts were prepared for the papers presented in the subject area: hydrogen sources and detection.

Berman, M. (ed.)

1981-01-26T23:59:59.000Z

206

Soluble Hydrogen-bonding Interpolymer Complexes in Water: A Small-Angle Neutron Scattering Study  

E-Print Network [OSTI]

The hydrogen-bonding interpolymer complexation between poly(acrylic acid) (PAA) and the poly(N,N-dimethylacrylamide) (PDMAM) side chains of the negatively charged graft copolymer poly(acrylic acid-co-2-acrylamido-2-methyl-1-propane sulfonic acid)-graft-poly(N, N dimethylacrylamide) (P(AA-co-AMPSA)-g-PDMAM), containing 48 wt % of PDMAM, and shortly designated as G48, has been studied by small-angle neutron scattering in aqueous solution. Complexation occurs at low pH (pH < 3.75), resulting in the formation of negatively charged colloidal particles, consisting of PAA/PDMAM hydrogen-bonding interpolymer complexes, whose radius is estimated to be around 165 A. As these particles involve more than five graft copolymer chains, they act as stickers between the anionic chains of the graft copolymer backbone. This can explain the characteristic thickening observed in past rheological measurements with these mixtures in the semidilute solution, with decreasing pH. We have also examined the influence of pH and PAA molecular weight on the formation of these nanoparticles.

Maria Sotiropoulou; Julian Oberdisse; Georgios Staikos

2006-04-03T23:59:59.000Z

207

An Assessment of the Near-Term Costs of Hydrogen Refueling Stations and Station Components  

E-Print Network [OSTI]

hydrogen dispenser Water Reverse osmosis and deionizer waterAlkaline Electrolyzer Reverse osmosis and deionizer water

Weinert, Jonathan X.; Lipman, Timothy

2006-01-01T23:59:59.000Z

208

Biogenic formation of photoactive arsenic-sulfide nanotubes by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

formation of photoactive arsenic-sulfide nanotubes by Shewanella sp. strain HN-41 . Biogenic formation of photoactive arsenic-sulfide nanotubes by Shewanella sp. strain HN-41 ....

209

Hydrogen Economy: The Role of Nano-scaled Support Material for Electrocatalysts Aimed for Water Electrolysis  

Science Journals Connector (OSTI)

The role and importance of support materials for electrocatalysts aimed for water electrolysis is given. Besides their superior support characteristics...2, (iii) multiwalled carbon nanotubes (MWCNTs) and (iv) Ma...

Perica Paunovi?; Orce Popovski…

2011-01-01T23:59:59.000Z

210

The Potential Cardioprotective Effects of Hydrogen in Irradiated Mice  

Science Journals Connector (OSTI)

......we investigated whether hydrogen-rich water exerted cardiopro...We demonstrated here that hydrogen treatment has a cardioprotective effect. MATERIALS AND METHODS Hydrogen-rich water production Hydrogen was dissolved in......

Liren Qian; Fei Cao; Jianguo Cui; Yicun Wang; Yuecheng Huang; Yunhai Chuai; Luqian Zaho; Hao Jiang; Jianming Cai

2010-11-01T23:59:59.000Z

211

Oxygen- and Hydrogen-Isotopic Ratios of Water in Precipitation: Beyond Paleothermometry  

Science Journals Connector (OSTI)

...of water can be used to test Earth-system models focused on the hydrologic cycle...of the hydrologic cycles of Earth-system models that include appropriate isotopic...testing hydrologic cycles in Earth system models; this direction will be most...

Richard B. Alley; Kurt M. Cuffey

212

Kinetics and mechanism of thiophene hydrodesulfurization over carbon-supported transition metal sulfides  

SciTech Connect (OSTI)

Results of a detailed kinetic study on the thiophene hydrodesulfurization reaction at atmospheric pressure over a set of carbon-supported transition metal sulfides, i.e., the sulfides of Co, Mo, Rh, and the mixed CoMo sulfide, are presented. It is found that (partially) hydrogenated thiophenes, i.e., 2,3-dihydrothiophene, 2,5-dihydrothiophene, and tetrahydrothiophene, are important intermediates in the reaction mechanism. The reaction orders of thiophene suggest that carbon-sulfur bond cleavage is rate limiting for most of the catalysts. The CoMo catalyst may have hydrogenative sulfur removal as the rate limiting step. This catalyst shows a strong decrease in apparent activation energy with temperature to be ascribed to a large change in steady state surface coverage by thiophene (or H{sub 2}S) as a function of temperature. This is consistent with a strong interaction between catalyst and thiophene. The Rh catalyst most probably shows a phase transition leading to different kinetic parameters. A strong interaction between the metal sulfide and thiophene is important for a high HDS activity. 38 refs., 4 figs., 5 tabs.

Hensen, E.J.M.; Vissenberg, M.J.; Beer, V.H.J. de [Eindhoven Univ. of Technology (Netherlands)] [and others] [Eindhoven Univ. of Technology (Netherlands); and others

1996-10-01T23:59:59.000Z

213

Coadsorption as a probe of mechanism: cyclic sulfides and straight chain thiols on Mo(110)  

SciTech Connect (OSTI)

The authors reported that tetrahydrothiophene and trimethylene sulfide undergo desulfurization on Mo(110) to form gaseous alkanes and alkenes in a temperature-programmed reaction experiment. In both cases, straight chain alkane evolution preceded alkene evolution. They proposed that the intermediate leading to straight chain alkanes and alkenes from these two cyclic sulfides is a surface thiolate. The thiolate undergoes competitive C/sub 1/-hydrogenation to alkane and C/sub 2/-dehydrogenation to alkene, depending on the surface hydrogenation concentration. They report here that coadsorbed cyclic sulfides C/sub n/H/sub 2n/S (n = 3, 4) and linear thiols C/sub m/H/sub 2m+1/SH(m = 2, 3, 4) react during a temperature-programmed reaction experiment to form alkanes C/sub n/H/sub 2n+2/ and C/sub m/H/sub 2m+2/ at exactly the same temperature. These experiments lend powerful support to their proposal that cyclic sulfides and straight chain thiols react on Mo(110) by way of a thiolate intermediate.

Roberts, J.T.; Friend, C.M.

1987-07-08T23:59:59.000Z

214

Adsorption of Water Dimer on Platinum(111): Identification of the ?OH···Pt Hydrogen Bond  

Science Journals Connector (OSTI)

‡ Department of Advanced Materials Science, The University of Tokyo, Kashiwa 277-8561, Japan ... ? Faculty of Physical Sciences, VR-III, University of Iceland, 107 Reykjavík, Iceland ... In the decade and a half, the increased capability of surface scientists to probe at the mol.-level has resulted in more detailed information of the properties of water on progressively more complicated materials and under more stringent conditions. ...

Kenta Motobayashi; Líney Árnadóttir; Chikako Matsumoto; Eric M. Stuve; Hannes Jónsson; Yousoo Kim; Maki Kawai

2014-10-22T23:59:59.000Z

215

Neutron structure of human carbonic anhydrase II: A hydrogen bonded water network switch is observed between pH 7.8 and 10.0.  

SciTech Connect (OSTI)

The neutron structure of wild type human carbonic anhydrase II at pH 7.8 has been determined to 2.0 resolution. Detailed analysis and comparison to the previous determined structure at pH 10.0 shows important differences in protonation of key catalytic residues in the active site as well as a rearrangement of the hydrogen bonded water network. For the first time, a completed hydrogen bonded network stretching from the Zn-bound solvent to the proton shuttling residue His64 has been directed observed.

Fisher, Zoe [Los Alamos National Laboratory (LANL); Langan, Paul [ORNL; Mustyakimov, Marat [Los Alamos National Laboratory (LANL); Kovalevsky, Andrey [Los Alamos National Laboratory (LANL)

2011-01-01T23:59:59.000Z

216

Solar Photo Catalytic Hydrogen Production from water using a dual bed photosystem  

SciTech Connect (OSTI)

A body of work was performed in which the feasibility of photocatalytically decomposing water into its constituent elements using a dual bed, or modular photosystem, under solar radiation was investigated. The system envisioned consists of two modules, each consisting of a shallow, flat, sealed container, in which microscopic photocatalytic particles are immobilized. The photocatalysts absorb light, generating free electrons and lattice vacancy holes, which are capable of performing reductive and oxidative chemistry, respectively. The photocatalysts would be chosen as to whether they specifically promote H{sub 2} or O{sub 2} evolution in their respective containers. An aqueous solution containing a redox mediator is pumped between the two chambers in order to transfer electron equivalents from one reaction to the other.

Florida Solar Energy Center

2003-03-30T23:59:59.000Z

217

Hydrogen Sulfide Combustion:? Relevant Issues under Claus Furnace Conditions  

Science Journals Connector (OSTI)

Their mechanisms include the chemistry that leads to the formation of SO, SO2, SO3, and S2, as well as other chemical paths for the destruction of H2S. Another important source of chemistry and kinetics data that is more recent can be found in the University of Leeds, U.K. Sulfur Mechanism (which can be found on the Internet at www.chem.leeds.ac.uk/Combustion/Combustion.html). ... The databank contains the ideal gas heat capacity, free energy of formation, and enthalpy of formation for many species, and these values are accurate at the high temperatures that are typical of combustion for more than 59 stable and radical species. ... Clark et al.4 noted in their study of Claus chemistry that H2S combusts more quickly than the hydrocarbons that were present in the initial gas mixture. ...

Ivan A. Gargurevich

2005-08-23T23:59:59.000Z

218

Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of  

E-Print Network [OSTI]

. These processes include natural gas processing, petroleum refining, petrochemical plants, Kraft mills, coke ovens, and coal gasifiers. H2S concentrations in these processes vary from 0 to 60 vol % (6). The Claus process

Borguet, Eric

219

Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor  

E-Print Network [OSTI]

monitoring, solid-oxide fuel cells, and coal gasification, require operation at much higher temperatures thanSulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor Yung Ho to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20­600 times greater

Tobin, Roger G.

220

Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants  

E-Print Network [OSTI]

,2 operated by fuel cells. Unfortunately, the lack of infrastructure, such as a network of hydrogen refueling of hydrogen sulfide (H2S), which poisons the anode in the fuel cell stack, leading to low SOFC efficiencyPerformance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel

Azad, Abdul-Majeed

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Mitigation of Hydrogen Gas Generation from the Reaction of Uranium Metal with Water in K Basin Sludge and Sludge Waste Forms  

SciTech Connect (OSTI)

Prior laboratory testing identified sodium nitrate and nitrite to be the most promising agents to minimize hydrogen generation from uranium metal aqueous corrosion in Hanford Site K Basin sludge. Of the two, nitrate was determined to be better because of higher chemical capacity, lower toxicity, more reliable efficacy, and fewer side reactions than nitrite. The present lab tests were run to determine if nitrate’s beneficial effects to lower H2 generation in simulated and genuine sludge continued for simulated sludge mixed with agents to immobilize water to help meet the Waste Isolation Pilot Plant (WIPP) waste acceptance drainable liquid criterion. Tests were run at ~60°C, 80°C, and 95°C using near spherical high-purity uranium metal beads and simulated sludge to emulate uranium-rich KW containerized sludge currently residing in engineered containers KW-210 and KW-220. Immobilization agents tested were Portland cement (PC), a commercial blend of PC with sepiolite clay (Aquaset II H), granulated sepiolite clay (Aquaset II G), and sepiolite clay powder (Aquaset II). In all cases except tests with Aquaset II G, the simulated sludge was mixed intimately with the immobilization agent before testing commenced. For the granulated Aquaset II G clay was added to the top of the settled sludge/solution mixture according to manufacturer application directions. The gas volumes and compositions, uranium metal corrosion mass losses, and nitrite, ammonia, and hydroxide concentrations in the interstitial solutions were measured. Uranium metal corrosion rates were compared with rates forecast from the known uranium metal anoxic water corrosion rate law. The ratios of the forecast to the observed rates were calculated to find the corrosion rate attenuation factors. Hydrogen quantities also were measured and compared with quantities expected based on non-attenuated H2 generation at the full forecast anoxic corrosion rate to arrive at H2 attenuation factors. The uranium metal corrosion rates in water alone and in simulated sludge were near or slightly below the metal-in-water rate while nitrate-free sludge/Aquaset II decreased rates by about a factor of 3. Addition of 1 M nitrate to simulated sludge decreased the corrosion rate by a factor of ~5 while 1 M nitrate in sludge/Aquaset II mixtures decreased the corrosion rate by ~2.5 compared with the nitrate-free analogues. Mixtures of simulated sludge with Aquaset II treated with 1 M nitrate had uranium corrosion rates about a factor of 8 to 10 lower than the water-only rate law. Nitrate was found to provide substantial hydrogen mitigation for immobilized simulant sludge waste forms containing Aquaset II or Aquaset II G clay. Hydrogen attenuation factors of 1000 or greater were determined at 60°C for sludge-clay mixtures at 1 M nitrate. Hydrogen mitigation for tests with PC and Aquaset II H (which contains PC) were inconclusive because of suspected failure to overcome induction times and fully enter into anoxic corrosion. Lessening of hydrogen attenuation at ~80°C and ~95°C for simulated sludge and Aquaset II was observed with attenuation factors around 100 to 200 at 1 M nitrate. Valuable additional information has been obtained on the ability of nitrate to attenuate hydrogen gas generation from solution, simulant K Basin sludge, and simulant sludge with immobilization agents. Details on characteristics of the associated reactions were also obtained. The present testing confirms prior work which indicates that nitrate is an effective agent to attenuate hydrogen from uranium metal corrosion in water and simulated K Basin sludge to show that it is also effective in potential candidate solidified K Basin waste forms for WIPP disposal. The hydrogen mitigation afforded by nitrate appears to be sufficient to meet the hydrogen generation limits for shipping various sludge waste streams based on uranium metal concentrations and assumed waste form loadings.

Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

2011-06-08T23:59:59.000Z

222

DOE Hydrogen and Fuel Cells Program: Hydrogen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production Hydrogen Production Hydrogen Delivery Hydrogen Storage Hydrogen Manufacturing Fuel Cells Applications/Technology Validation Safety Codes and Standards Education Basic Research Systems Analysis Systems Integration U.S. Department of Energy Search help Home > Hydrogen Production Printable Version Hydrogen Production Hydrogen can be produced from diverse domestic feedstocks using a variety of process technologies. Hydrogen-containing compounds such as fossil fuels, biomass or even water can be a source of hydrogen. Thermochemical processes can be used to produce hydrogen from biomass and from fossil fuels such as coal, natural gas and petroleum. Power generated from sunlight, wind and nuclear sources can be used to produce hydrogen electrolytically. Sunlight alone can also drive photolytic production of

223

Design of a photochemical water electrolysis system based on a W-typed dye-sensitized serial solar module for high hydrogen production  

Science Journals Connector (OSTI)

Abstract A W-typed dye-sensitized serial solar module (W-typed DSSM) was designed for hydrogen production from water electrolysis. The optimal thickness and width of the TiO2 electrode film were 12 ?m and 5 mm, and the optimal thickness of Pt counter electrode film was 4 nm, respectively. The photocurrent density, open circuit voltage, and fill factor were 2.13 mA cm?2, 3.51 V, and 0.61, respectively, for a serial module assembled from five unit cells, which resulted in an overall conversion efficiency of 4.56%. The obtained voltage increased with increasing number of unit cells connected, and was 3.51 V in the five column fabricated W-typed DSSM. 2.1 mL h?1 of hydrogen gas was emitted when a W-typed DSSM assembled from five columns was connected to carbon electrodes in a water electrolysis system. The rate of hydrogen evolution in the five columned W-typed DSSM was 0.00213 L h?1. Therefore, the actual light-hydrogen conversion was calculated to be 2.02%.

Byeong Sub Kwak; Jinho Chae; Misook Kang

2014-01-01T23:59:59.000Z

224

Energetics of Hydrogen Bond Network Rearrangements in Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Wednesday, 25 May 2005 00:00 The unique...

225

Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants  

SciTech Connect (OSTI)

Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

2001-11-06T23:59:59.000Z

226

Optimized Hydrogen and Electricity Generation from Wind  

Broader source: Energy.gov [DOE]

Several optimizations can be employed to create hydrogen and electricity from a wind energy source. The key element in hydrogen production from an electrical source is an electrolyzer to convert water and electricity into hydrogen and oxygen.

227

Hydrogen Highways  

E-Print Network [OSTI]

adequate on-board hydrogen storage is essential, and remainsjustify their costs. Hydrogen storage remains an importantto 10,000 psi, liquid hydrogen storage, and other solid and

Lipman, Timothy

2005-01-01T23:59:59.000Z

228

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

SciTech Connect (OSTI)

Hydrogen production from coal gasification can be enhanced by driving the equilibrium limited Water Gas Shift reaction forward by incessantly removing the CO{sub 2} by-product via the carbonation of calcium oxide. This project aims at using the OSU patented high-reactivity mesoporous precipitated calcium carbonate sorbent for removing the CO{sub 2} product. Preliminary experiments demonstrate the show the superior performance of the PCC sorbent over other naturally occurring calcium sorbents. Gas composition analyses show the formation of 100% pure hydrogen. Novel calcination techniques could lead to smaller reactor footprint and single-stage reactors that can achieve maximum theoretical H{sub 2} production for multicyclic applications. Sub-atmospheric calcination studies reveal the effect of vacuum level, diluent gas flow rate, thermal properties of the diluent gas and the sorbent loading on the calcination kinetics which play an important role on the sorbent morphology. Steam, which can be easily separated from CO{sub 2}, is envisioned to be a potential diluent gas due to its enhanced thermal properties. Steam calcination studies at 700-850 C reveal improved sorbent morphology over regular nitrogen calcination. A mixture of 80% steam and 20% CO{sub 2} at ambient pressure was used to calcine the spent sorbent at 820 C thus lowering the calcination temperature. Regeneration of calcium sulfide to calcium carbonate was achieved by carbonating the calcium sulfide slurry by bubbling CO{sub 2} gas at room temperature.

Mahesh Iyer; Himanshu Gupta; Danny Wong; Liang-Shih Fan

2005-09-30T23:59:59.000Z

229

An Assessment of the Near-Term Costs of Hydrogen Refueling Stations and Station Components  

E-Print Network [OSTI]

hydrogen dispenser Reverse osmosis and deionizer waterAlkaline Electrolyzer Reverse osmosis and deionizer water

Lipman, T E; Weinert, Jonathan X.

2006-01-01T23:59:59.000Z

230

Hydrogen from Water in a Novel Recombinant Oxygen-Tolerant Cyanobacterial System - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Philip D. Weyman (Primary Contact), Isaac T. Yonemoto, Hamilton O. Smith J. Craig Venter Institute 10355 Science Center Dr. San Diego, CA 92121 Phone: (858) 200-1815 Email: pweyman@jcvi.org DOE Managers HQ: Eric Miller Phone: (202) 287-5829 Email: Eric.Miller@hq.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FC36-05GO15027 National Laboratory Collaborators: * Karen Wawrousek, Scott Noble, Jianping Yu, and Pin-Ching Maness * National Renewable Energy Laboratory (NREL), Golden, CO Project Start Date: May 1, 2005 Project End Date: January 30, 2014

231

Effect of the hydrogen bridge geometry on the vibrational spectra of water: Two-parameter H-bonding potentials  

Science Journals Connector (OSTI)

A principle to design the multi-parameter potentials of hydrogen bonding is proposed and developed. Based on fluctuation theory, they provide the description of temperature evolution of the shape of OH vibrati...

Yu. Ya. Efimov

2009-08-01T23:59:59.000Z

232

Hydrogen Storage Technologies Hydrogen Delivery  

E-Print Network [OSTI]

Hydrogen Storage Technologies Roadmap Hydrogen Delivery Technical Team Roadmap June 2013 #12;This.................................................................................. 13 6. Hydrogen Storage). The Hydrogen Delivery Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose mission

233

Hydrogen, Fuel Infrastructure  

E-Print Network [OSTI]

results of using hydrogen power, of course, will be energy independence for this nation... think about between hydrogen and oxygen generates energy, which can be used to power a car producing only water to taking these cars from laboratory to showroom so that the first car driven by a child born today could

234

Hydrogen Delivery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mark Paster Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technology Program Hydrogen Production and Delivery Team Hydrogen Delivery Goal Hydrogen Delivery Goal Liquid H 2 & Chem. Carriers Gaseous Pipeline Truck Hydrides Liquid H 2 - Truck - Rail Other Carriers Onsite reforming Develop Develop hydrogen fuel hydrogen fuel delivery delivery technologies that technologies that enable the introduction and enable the introduction and long long - - term viability of term viability of hydrogen as an energy hydrogen as an energy carrier for transportation carrier for transportation and stationary power. and stationary power. Delivery Options * End Game - Pipelines - Other as needed * Breakthrough Hydrogen Carriers * Truck: HP Gas & Liquid Hydrogen

235

Hydrogen separation process  

DOE Patents [OSTI]

A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

2011-05-24T23:59:59.000Z

236

Water Electrolysis  

Science Journals Connector (OSTI)

Production of ammonium sulfate fertilizer via synthetic ammonia was a national project in Japan just after World War II, and water electrolysis as the source of hydrogen was active....3 of hydrogen and 700 Nm3 of...

Fumio Hine

1985-01-01T23:59:59.000Z

237

Grain boundary depletion and migration during selective oxidation of Cr in a Ni-5Cr binary alloy exposed to high-temperature hydrogenated water  

SciTech Connect (OSTI)

High-resolution microscopy of a high-purity Ni-5Cr alloy exposed to 360°C hydrogenated water reveals intergranular selective oxidation of Cr accompanied by local Cr depletion and diffusion-induced grain boundary migration (DIGM). The corrosion-product oxide consists of a porous, interconnected network of Cr2O3 platelets with no further O ingress into the metal ahead. Extensive grain boundary depletion of Cr (to <0.05at.%) is observed typically 20–100 nm wide as a result of DIGM and reaching depths of many micrometers beyond the oxidation front.

Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

2014-10-15T23:59:59.000Z

238

Angular and energy dependence of cross sections for ejection of electrons from water vapor. III. 20–150-keV neutral-hydrogen impact  

Science Journals Connector (OSTI)

Absolute values of cross sections for electron production in collisions of neutral hydrogen atoms of 20–150 keV energy with water vapor molecules have been measured as a function of the ejection energy and angle. The range of angles was 10° to 160° and the electron energy range was 1–300 eV. The doubly differential cross sections were integrated over angle and/or energy to obtain singly differential cross sections, total electron production cross sections, and average energies of ejection. The angular distribution of the electron loss peak was found to have some features in common with the cross section for elastic scattering of electrons.

M. A. Bolorizadeh and M. E. Rudd

1986-02-01T23:59:59.000Z

239

Water Electrolysis  

Science Journals Connector (OSTI)

In this chapter, water electrolysis technology and its applications for nuclear hydrogen ... of the chapter, a general classification of water electrolysis systems is given, the fundamentals of water electrolysis

Greg F. Naterer; Ibrahim Dincer…

2013-01-01T23:59:59.000Z

240

Cost Analysis of Hydrogen Storage Systems  

Broader source: Energy.gov (indexed) [DOE]

In 2004, DOE has selected TIAX to evaluate the lifecycle cost and WTW energy use and GHG emissions of various hydrogen storage options. Water Electrolyzer Water Electrolyzer...

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Hydrogen Isotope Fractionation in the System Brucite-Water at 3 GPa Dept of Geological Science,University of Michigan; * now at Dept of Geology & Geophysics,University of Minnesota.Email:anthony.c.withers-1@umn.edu  

E-Print Network [OSTI]

Hydrogen Isotope Fractionation in the System Brucite-Water at 3 GPa Dept of Geological Science apparatus, we have made measurements in the chemically simple brucite-water system, which has beenCl pressure medium Experiments quenched at >200 °C/s Starting material:fine grained brucite (D = -100

Chikamoto, Megumi

242

Hydrogen’s Potential  

Science Journals Connector (OSTI)

Estimates of future demand for non-fossil produced hydrogen and of its potential are oriented toward ... to the environment as the present fossil energy economy [10.4, 10.9].

J. Nitsch; C. Voigt

1988-01-01T23:59:59.000Z

243

Photochemical generation of carbon monoxide and hydrogen by reduction of carbon dioxide and water under visible light irradiation  

Science Journals Connector (OSTI)

...energy conversion with consumption of a pollutant, CO2...energy conversion with consumption of a pollutant, CO...energy conversion with consumption of a pollutant, CO2...energy by producing fuels (hydrogen, carbon...M) in the reaction vessel; the gas contained...

Jean-Marie Lehn; Raymond Ziessel

1982-01-01T23:59:59.000Z

244

Hydrogen production from inexhaustible supplies of fresh and salt water using microbial reverse-electrodialysis electrolysis cells  

Science Journals Connector (OSTI)

...renewable source of energy, such as solar (5), wind, or waste organic...collection for MREC operation. The pump and effluent reservoirs...9] where {delta}H is the heat of combustion (J/mol...BE ( 2005 ) Electrochemically assisted microbial production of hydrogen...

Younggy Kim; Bruce E. Logan

2011-01-01T23:59:59.000Z

245

First demonstration of CdSe as a photocatalyst for hydrogen evolution from water under UV and visible lightw  

E-Print Network [OSTI]

­10 but can produce H2 from aqueous solutions containing sacrificial electrons donors, such as Na2S and Na2SO3% aqueous methanol, a known sacrificial electron donor,21 the hydrogen evolution rate was about three to four times higher, producing a total H2 amount of 18.4 mmol after 5 h. The increase in the H2 rate

Osterloh, Frank

246

Hydrogenation of carbonaceous materials  

DOE Patents [OSTI]

A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000.degree. C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

1980-01-01T23:59:59.000Z

247

Kinetic Studies on the Hydrogen Peroxide-Enhanced In Situ Biodegradation of Hydrocarbons in Water-Saturated Ground Zone  

Science Journals Connector (OSTI)

Techniques are rapidly developing for aerobic biodegradation of hydrocarbons in lower water-bearing formations. It is well known that...

Dr. E. R. Barenschee; Dr. O. Helmling; S. Dahmer; B. Del Grosso…

1990-01-01T23:59:59.000Z

248

Applicability of Henry's law to hydrogen, helium, and nitrogen solubilities in water and olive oil at 37 °C and pressures up to 300 atmospheres  

Science Journals Connector (OSTI)

The solubilities of pure hydrogen, helium, and nitrogen in water and olive oil were measured at 37 °C at gas-saturation pressures from 25 to 300 atmospheres. Rigorous thermodynamic criteria were used to assess the applicability of Henry's law to the pressure dependence of the gas solubility in each system. The solubilities of the three gases in water and helium in olive oil followed Henry's law as given by the Krichevsky-Kasarnovsky equation. In contrast, hydrogen and nitrogen in olive oil each attained concentrations high enough to cause significant concentration-dependent variations of the dissolved gas activity coefficient and/or partial molal volume. The consequent deviations from Henry's law were greatest in the nitrogen-oil system, where mole fraction nitrogen solubilities calculated from the Krichevsky-Kasarnovsky equation exceeded measured values by 8, 14, and 23% at 50, 100, and 250 atm, respectively. Incorporation of results into the critical volume model of nitrogen anesthesia, using olive oil as a model of the physiological anesthetic site and literature data for the anesthetic potency of nitrogen in mice breathing high-pressure He-N2-O2 atmospheres, shows that nonideal solution behavior may become important for gases dissolved in physiological hydrophobic regions at biologically active concentrations, even if dissolved gas binding to proteins or other macromolecules is not involved.

Wayne A. Gerth

1985-01-01T23:59:59.000Z

249

Stabilization of Lead Sulfide Nanoparticles by Polyamines in Aqueous Solutions. A Structural Study of the Dispersions  

Science Journals Connector (OSTI)

† Department of Chemistry, University of Cyprus, P.O. ... (1, 42-45) Excluding some older aqueous procedures, based on sulfur sources such as hydrogen sulfide gas or thioacetamide,(23, 24) optimal size and polydispersity control is currently provided in organic solvents either at high temperatures, using variants of the TOP/TOPO method,(21) or closer to room temperature with oleylamine as a coordinating solvent. ... The pH was equal to 6 in the cases of PAH and PDDA and equal to 10 in the case of PEI, these being the “natural” pH values of the dispersions, obtained immediately upon mixing their components. ...

Elena Koupanou; Silvia Ahualli; Otto Glatter; Angel Delgado; Frank Krumeich; Epameinondas Leontidis

2010-10-14T23:59:59.000Z

250

Hydrogen sensor  

DOE Patents [OSTI]

A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

Duan, Yixiang (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Cao, Wenqing (Katy, TX)

2010-11-23T23:59:59.000Z

251

Nuclear Hydrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Error Error Nuclear Hydrogen - RCC cannot be displayed due to a timeout error. We recommend: * Refresh Nuclear Hydrogen - RCC * Increasing your portlet timeout setting. *...

252

Organusulfur Catalysis With Reduced Molybdenum Sulfides Containing the Mo6S8 Cluster  

SciTech Connect (OSTI)

Industrial synthesis of sulfur-containing organic chemicals basically focuses on the broad categories of mercaptans (thiols), alkylsulfides (thioethers), polysulfides, and thiophenes. Of the organo-sulfur compounds produced, by far the most important in terms of quantities produced is methyl mercaptan (methanethiol or MeSH), which is produced mainly for the downstream production of methionine and methanesulfonyl chloride. Higher thiols are also used in the manufacture of rubber and plastics as polymerization regulators, chain transfer agents, or initiators. Other important organosulfur chemicals are dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), both of which are used extensively for presulfiding of industrial hydroprocessing catalysts, and substituted thiophenes which are used as intermediates for production of agrochemicals, dyes, and pharmaceuticals. Thiols are produced commercially at the rate of about 10{sup 4} ton/yr from hydrogen sulfide (H{sub 2}S) and alcohols or olefins, using homogeneous free-radical synthesis, or heterogeneous catalysts based on solid acids or supported metal oxides and/or sulfides. Despite this large production rate, and the industrial importance of the organosulfur compounds, only limited research has been devoted to the development of new catalytic materials for their synthesis. Additionally, for most organosulfur catalytic reactions, only limited information exists about reaction mechanisms, active sites, adsorbed surface species, and especially the nature of the catalysts under reaction conditions.

Thomas Jay Paskach

2002-08-27T23:59:59.000Z

253

Characterization and activity of ferric-sulfide-based catalyst in model reactions of direct coal liquefaction: Effect of preparation conditions  

SciTech Connect (OSTI)

The authors studied the activity of various ferric-sulfide-based catalysts in model hydrogenation and cracking reactions under conditions typical of direct coal liquefaction (DCL). The catalysts used were mixtures of FeS{sub 2} (pyrite, PY) and nonstoichiometric FeS{sub x} (pyrrhotite, PH) obtained by high-temperature disproportionation of ferric sulfide in a nitrogen atmosphere or a hydrogen atmosphere. The structural changes in the catalyst were also examined, both before and after the model reactions. The cracking functionality of the catalysts was studied by using cumene, and the hydrocracking functionality was studied by using diphenylmethane. Phenanthrene was used as a model compound for hydrogenation and hydrogen shuttling. Phenanthrene hydrogenation was studied in the presence of H{sub 2}(g), and hydrogen shuttling was studied when a hydrogen donor (tetralin) was present in the absence of H{sub 2}(g). All the model reactions were performed under conditions typical of DCL: 400 C and 1,000 psig for 30 min. The surface and bulk of the catalysts were characterized by Auger electron spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and atomic absorption spectroscopy. The performance of the catalysts was found to vary with the type of reaction, the initial ratio of FeS{sub x} to FeS{sub 2} (PH/PY) found in the catalyst, and the catalyst age. Catalysts freshly prepared in a nitrogen atmosphere were most active for model hydrogenation and hydrocracking runs. Catalysts freshly prepared in hydrogen were most active in shuttling. A simple model was developed to explain changes in the surface and bulk of the catalysts.

Chadha, A.; Stinespring, C.D.; Stiller, A.H.; Zondlo, J.W.; Dadyburjor, D.B. [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering] [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering

1997-02-01T23:59:59.000Z

254

Development and Parametric Testing of Alkaline Water Electrolysis Cells for Hydrogen Production Based on Inorganic-Membrane-Electrolyte Technology  

Science Journals Connector (OSTI)

A research programme aiming at the development of a new advanced concept in alkaline water electrolysis has been demonstrated at S.C.K....

H. Vandenborre; L. H. Baetsle; W. Hebel; R. Leysen…

1980-01-01T23:59:59.000Z

255

Hydrogen Storage Workshop Argonne National Laboratory  

E-Print Network [OSTI]

hydrogen, fuel cells, and distribution..." #12;1. Hydrogen Storage 2. Hydrogen Production 3. Fuel Cell Cost Energy & Water Appropriations #12;FY 2002 Budget = $47.425M Transportation Fuel Cell Stack Subsystem Rossmeissl Hydrogen, Fuel Cells & Infrastructure Technologies Program Energy Efficiency and Renewable Energy

256

Chemical Hydrogen Storage Center Center of Excellence  

E-Print Network [OSTI]

alternatives and assess economics and life cycle analysis of borohydride/water to hydrogen · Millennium CellChemical Hydrogen Storage Center Center of Excellence for Chemical Hydrogen Storage William Tumas proprietary or confidential information #12;2 Chemical Hydrogen Storage Center Overview Project Start Date: FY

Carver, Jeffrey C.

257

Hydrogen & Fuel Cells - Hydrogen - Hydrogen Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Quality Issues for Fuel Cell Vehicles Hydrogen Quality Issues for Fuel Cell Vehicles Introduction Developing and implementing fuel quality specifications for hydrogen are prerequisites to the widespread deployment of hydrogen-fueled fuel cell vehicles. Several organizations are addressing this fuel quality issue, including the International Standards Organization (ISO), the Society of Automotive Engineers (SAE), the California Fuel Cell Partnership (CaFCP), and the New Energy and Industrial Technology Development Organization (NEDO)/Japan Automobile Research Institute (JARI). All of their activities, however, have focused on the deleterious effects of specific contaminants on the automotive fuel cell or on-board hydrogen storage systems. While it is possible for the energy industry to provide extremely pure hydrogen, such hydrogen could entail excessive costs. The objective of our task is to develop a process whereby the hydrogen quality requirements may be determined based on life-cycle costs of the complete hydrogen fuel cell vehicle "system." To accomplish this objective, the influence of different contaminants and their concentrations in fuel hydrogen on the life-cycle costs of hydrogen production, purification, use in fuel cells, and hydrogen analysis and quality verification are being assessed.

258

Relationship of Hydrogen Bioavailability to Chromate Reduction in Aquifer Sediments  

Science Journals Connector (OSTI)

...Media Ecosystem Fresh Water microbiology Geologic...Oxidation-Reduction Water Supply georef;2010007932...studies geochemistry ground water hydrogen laboratory studies...Oklahoma pollution reduction remediation sediments United States...

Tamara L. Marsh; Michael J. McInerney

2001-04-01T23:59:59.000Z

259

Comparative studies of hydrodenitrogenation by mixed metal sulfide catalysts  

E-Print Network [OSTI]

. , Sanchez, K. M. , and Reibenspies, J. , "Synthesis and characterization of [Et4N][M(CO)5SR] and [Et4N]2[M2 (CO) 8 (SR) 2] complexes (M = Cr, Mo, W) . Ligand substitution... to mimic the commercial catalyst (ie. no sulfide bridges prior to activation) l a Ni/Mo sulfide catalyst which consisted of Ni and Mo atoms brought in intimate contact by sulfide bridges; Ni/Mo and Co/Mo organometallic catalysts whose central metal had...

Luchsinger, Mary Margaret

1990-01-01T23:59:59.000Z

260

Polymer system for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Whinnery, LeRoy L. (4929 Julie St., Livermore, Alameda County, CA 94550)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (Livermore, CA); Whinnery, LeRoy L. (Livermore, CA)

1998-11-17T23:59:59.000Z

262

A paradox resolved: Sulfide acquisition by roots of seep tubeworms sustains net chemoautotrophy  

Science Journals Connector (OSTI)

...numbers indicate consumption and negative numbers...require sulfide to fuel autotrophic carbon...In the split-vessel respiration experiments...production to consumption) when sulfide...animal biomass to vessel volume necessitated...sulfide and oxygen consumption rates...

John K. Freytag; Peter R. Girguis; Derk C. Bergquist; Jason P. Andras; James J. Childress; Charles R. Fisher

2001-01-01T23:59:59.000Z

263

E-Print Network 3.0 - antimony sulfide colloid Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

separates, B:33 sulfides, B:37, 39 sulfides and sediments, B:45... -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

264

E-Print Network 3.0 - antimony sulfides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

separates, B:33 sulfides, B:37, 39 sulfides and sediments, B:45... -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

265

NREL: Learning - Hydrogen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production Production The simplest and most common element, hydrogen is all around us, but always as a compound with other elements. To make it usable in fuel cells or otherwise provide energy, we must expend energy or modify another energy source to extract it from the fossil fuel, biomass, water, or other compound in which it is found. Nearly all hydrogen production in the United States today is by steam reformation of natural gas. This, however, releases carbon dioxide in the process and trades one relatively clean fuel for another, with associated energy loss, so it does little to meet national energy needs. Hydrogen can also be produced by electrolysis-passing an electrical current through water to break it into hydrogen and oxygen-but electrolysis is inefficient and is only as clean

266

Experimental and theoretical study of pressure effects on hydrogen isotope fractionation in the system brucite-water at elevated temperatures  

Science Journals Connector (OSTI)

A detailed, systematic experimental and theoretical study was conducted to investigate the effect of pressure on equilibrium D/H fractionation between brucite (Mg(OH)2) and water at temperatures from 200 to 600°C and pressures up to 800 MPa. A fine-grained brucite was isotopically exchanged with excess amounts of water, and equilibrium D/H fractionation factors were calculated by means of the partial isotope exchange method. Our experiments unambiguously demonstrated that the D/H fractionation factor between brucite and water increased by 4.4 to 12.4‰ with increasing pressure to 300 or 800 \\{MPa\\} at all the temperatures investigated. The observed increases are linear with the density of water under experimental conditions. We calculated the pressure effects on the reduced partition function ratios (?-factor) of brucite (300–800 K and P ? 800 MPa) and water (400–600°C and P ? 100 MPa), employing a statistical-mechanical method similar to that developed by Kieffer (1982) and a simple thermodynamic method based on the molar volumes of normal and heavy waters, respectively. Our theoretical calculations showed that the reduced partition function ratio of brucite increases linearly with pressure at a given temperature (as much as 12.6‰ at 300 K and 800 MPa). The magnitude of the pressure effects rapidly decreases with increasing temperature. On the other hand, the ?-factor of water decreases 4 to 5‰ with increasing pressure to 100 \\{MPa\\} at 400 to 600°C. Overall D/H isotope pressure effects combined from the separate calculations on brucite and water are in excellent agreement with the experimental results under the same temperature-pressure range. Our calculations also suggest that under the current experimental conditions, the magnitude of the isotope pressure effects is much larger on water than brucite. Thus, the observed pressure effects on D/H fractionation are common to other systems involving water. It is very likely that under some geologic conditions, pressure is an important variable in controlling D/H partitioning.

Juske Horita; David R. Cole; Veniamin B. Polyakov; Thomas Driesner

2002-01-01T23:59:59.000Z

267

A Continuous Solar Thermochemical Hydrogen Production Plant Design  

E-Print Network [OSTI]

11]. One method for hydrogen production is a water-splittingof various methods of hydrogen production, the Department ofOne method of reducing the cost of hydrogen production is to

Luc, Wesley Wai

268

Electrolysis of Sea Water  

Science Journals Connector (OSTI)

In implementation of the hydrogen economy, the electrolysis of sea water as the source of hydrogen has been ... . Two options exist for performance of this electrolysis. The first option is to subject the water t...

L. O. Williams

1975-01-01T23:59:59.000Z

269

Transport and reduction of sulfate and immobilization of sulfide in marine black shales  

SciTech Connect (OSTI)

In fine-grained sediments in which the amount of reduced sulfur retained in stable phases substantially exceeds that present initially in pore waters, rates of sulfate reduction may have equaled or exceeded rates of sulfate transport, resulting in enrichment of [sup 34]S in pore waters and reduction products. Abundance and isotopic compositions of reduced sulfur compounds can be used to calculate the extent of sulfide retention and improve reconstructions of carbon-sulfur oxidation-reduction (redox) budgets. The Miocene Monterey Formation and Upper Devonian New Albany Shale represent distinct types of black shales that accumulated under different conditions of sulfate reduction. Our results suggest that the rate of sulfate reduction was controlled largely by mass transport in the Monterey and by the reduction process itself in the New Albany. Sulfide was more efficiently retained in the Monterey; thus each mole of sulfide in the New Albany represents a greater amount of sedimented organic carbon removed during sulfate reduction. 30 refs., 4 figs., 1 tab.

Zaback, D.A.; Pratt, L.M.; Hayes, J.M. (Indiana Univ., Bloomington (United States))

1993-02-01T23:59:59.000Z

270

Reduced ternary molybdenum and tungsten sulfides and hydroprocessing catalysis therewith  

DOE Patents [OSTI]

New amorphous molybdenum/tungsten sulfides with the general formula M.sup.n+.sub.2x/n (L.sub.6 S.sub.8)S.sub.x, where L is molybdenum or tungsten and M is a ternary metal, has been developed. Characterization of these amorphous materials by chemical and spectroscopic methods (IR, Raman, PES) shows that the (M.sub.6 S.sub.8).sup.0 cluster units are present. Vacuum thermolysis of the amorphous Na.sub.2x (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH first produces poorly crystalline NaMo.sub.6 S.sub.8 by disproportionation at 800.degree. C. and well-crystallized NaMo.sub.6 S.sub.8 at .gtoreq. 900.degree. C. Ion-exchange of the sodium material in methanol with soluble M.sup.2+ and M.sup.3+ salts (M=Sn, Co, Ni, Pb, La, Ho) produces the M.sup.n+.sub.2x/n (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH compounds. Additionally, the new reduced ternary molybdenum sulfides with the general formula M.sup.n+.sub.2x/n Mo.sub.6 S.sub.8+x (MeOH).sub.y ›MMOS! (M=Sn, Co, Ni) is an effective hydrodesulfurization (HDS) catalyst both as-prepared and after a variety of pretreatment conditions. Under specified pretreatment conditions with flowing hydrogen gas, the SnMoS type catalyst can be stabilized, and while still amorphous, can be considered as "Chevrel phase-like" in that both contain Mo.sub.6 S.sub.8 cluster units. Furthermore, the small cation NiMoS and CoMoS type pretreated catalyst showed to be very active HDS catalysts with rates that exceeded the model unpromoted and cobalt-promoted MoS.sub.2 catalysts.

Hilsenbeck, Shane J. (Ames, IA); McCarley, Robert E. (Ames, IA); Schrader, Glenn L. (Ames, IA); Xie, Xiaobing (College Station, TX)

1999-02-16T23:59:59.000Z

271

Process analysis and economics of biophotolysis of water. IEA technical report from the IEA Agreement on the Production and Utilization of Hydrogen  

SciTech Connect (OSTI)

This report is a preliminary cost analysis of the biophotolysis of water and was prepared as part of the work of Annex 10 of the IEA Hydrogen agreement. Biophotolysis is the conversion of water and solar energy to hydrogen and oxygen using microalgae. In laboratory experiments at low light intensities, algal photosynthesis and some biophotolysis reactions exhibit highlight conversion efficiencies that could be extrapolated to about 10% solar efficiencies if photosynthesis were to saturate at full sunlight intensities. The most promising approach to achieving the critical goal of high conversion efficiencies at full sunlight intensities, one that appears within the capabilities of modern biotechnology, is to genetically control the pigment content of algal cells such that the photosynthetic apparatus does not capture more photons than it can utilize. A two-stage indirect biophotolysis system was conceptualized and general design parameters extrapolated. The process comprises open ponds for the CO{sub 2}fixation stage, an algal concentration step, a dark adaptation and fermentation stage, and a closed tubular photobioreactor in which hydrogen production would take place. A preliminary cost analysis for a 200 hectare (ha) system, including 140 ha of open algal ponds and 14 ha of photobioreactors was carried out. The cost analysis was based on prior studies for algal mass cultures for fuels production and a conceptual analysis of a hypothetical photochemical processes, as well as the assumption that the photobioreactors would cost about $100/m(sup 2). Assuming a very favorable location, with 21 megajoules (MJ)/m{sup 2} total insolation, and a solar conversion efficiency of 10% based on CO{sub 2} fixation in the large algal ponds, an overall cost of $10/gigajoule (GJ) is projected. Of this, almost half is due to the photobioreactors, one fourth to the open pond system, and the remainder to the H{sub 2} handling and general support systems. It must be cautioned that these are highly preliminary, incomplete, and optimistic estimates. Biophotolysis processes, indirect or direct, clearly require considerable basic and applied R and D before a more detailed evaluation of their potential and plausible economics can be carried out. For example, it is not yet clear which type of algae, green algae, or cyanobacteria, would be preferred in biophotolysis. If lower-cost photobioreactors can be developed, then small-scale (<1 ha) single-stage biophotolysis processes may become economically feasible. A major basic and applied R and D effort will be required to develop such biophotolysis processes.

Benemann, J.R.

1998-03-31T23:59:59.000Z

272

Renewable Hydrogen: Integration, Validation, and Demonstration  

SciTech Connect (OSTI)

This paper is about producing hydrogen through the electrolysis of water and using the hydrogen in a fuel cell or internal combustion engine generator to produce electricity during times of peak demand, or as a transportation fuel.

Harrison, K. W.; Martin, G. D.

2008-07-01T23:59:59.000Z

273

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...  

Broader source: Energy.gov (indexed) [DOE]

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

274

An Overview of Hydrogen Production Technologies  

SciTech Connect (OSTI)

Currently, hydrogen is primarily used in the chemical industry, but in the near future it will become a significant fuel. There are many processes for hydrogen production. This paper reviews reforming (steam, partial oxidation, autothermal, plasma, and aqueous phase), pyrolysis, hydrogen from biomass, electrolysis and other methods for generating hydrogen from water, and hydrogen storage. In addition, desulfurization, water-gas-shift, and hydrogen purification methods are discussed. Basics of these processes are presented with a large number of references for the interested reader to learn more.

Holladay, Jamie D.; Hu, Jianli; King, David L.; Wang, Yong

2009-01-30T23:59:59.000Z

275

Hydrogen Analysis  

Broader source: Energy.gov [DOE]

Presentation on Hydrogen Analysis to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of systems analysis in DOE Hydrogen Program.

276

Hydrogen Storage  

Broader source: Energy.gov [DOE]

On-board hydrogen storage for transportation applications continues to be one of the most technically challenging barriers to the widespread commercialization of hydrogen-fueled vehicles. The EERE...

277

Hydrogen Safety  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

278

Hydrogen Cryomagnetics  

E-Print Network [OSTI]

% cryogenics (inc. MRI) 29% pressurisation and purging 11%controlled atmospheres (inc. breathing) 6% 4     Figure 5. Simplified price-cost, supply-demand relationship that is central to the helium market model developed during the Helium Resources... of hydrogen large amounts of hydrogen must be available for liquefaction. This poses problems for the production of liquid hydrogen via intermittent wind energy and via microwave plasma reactors that are not scalable as a result of low hydrogen production...

Glowacki, B. A.; Hanely, E.; Nuttall, W. J.

2014-01-01T23:59:59.000Z

279

Effective hydrogen generation and resource circulation based on sulfur cycle system  

SciTech Connect (OSTI)

For the effective hydrogen generation from H{sub 2}S, it should be compatible that the increscent of the photocatalytic (or electrochemical) activities and the development of effective utilization method of by-products (poly sulfide ion). In this study, “system integration” to construct the sulfur cycle system, which is compatible with the increscent of the hydrogen and or electron energy generation ratio and resource circulation, is investigated. Photocatalytic hydrogen generation rate can be enhanced by using stratified photocatalysts. Photo excited electron can be transpired to electrode to convert the electron energy to hydrogen energy. Poly sulfide ion as the by-products can be transferred into elemental sulfur and/or industrial materials such as rubber. Moreover, elemental sulfur can be transferred into H{sub 2}S which is the original materials for hydrogen generation. By using this “system integration”, the sulfur cycle system for the new energy generation can be constructed.

Takahashi, Hideyuki; Mabuchi, Takashi; Hayashi, Tsugumi; Yokoyama, Shun; Tohji, Kazuyuki [Graduate School of Environmental Studies, Tohoku University 6-6-20, Aramaki, Aoba-ku, Sendai, 980-8579 (Japan)

2013-12-10T23:59:59.000Z

280

DOE HydrogenDOE Hydrogen Fuel CellsFuel Cells  

E-Print Network [OSTI]

between hydrogen and oxygen generates energy, which can be used to power a car producing only water that America can lead the world in developing clean, hydrogen-powered automobiles. "A simple chemical reaction to taking these cars from laboratory to showroom so that the first car driven by a child born today could

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Hydrogenation apparatus  

DOE Patents [OSTI]

Hydrogenation reaction apparatus is described comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1,100 to 1,900 C, while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products. 2 figs.

Friedman, J.; Oberg, C. L.; Russell, L. H.

1981-06-23T23:59:59.000Z

282

Photoelectrochemical Hydrogen Production  

SciTech Connect (OSTI)

The objectives of this project, covering two phases and an additional extension phase, were the development of thin film-based hybrid photovoltaic (PV)/photoelectrochemical (PEC) devices for solar-powered water splitting. The hybrid device, comprising a low-cost photoactive material integrated with amorphous silicon (a-Si:H or a-Si in short)-based solar cells as a driver, should be able to produce hydrogen with a 5% solar-to-hydrogen conversion efficiency (STH) and be durable for at least 500 hours. Three thin film material classes were studied and developed under this program: silicon-based compounds, copper chalcopyrite-based compounds, and metal oxides. With the silicon-based compounds, more specifically the amorphous silicon carbide (a-SiC), we achieved a STH efficiency of 3.7% when the photoelectrode was coupled to an a-Si tandem solar cell, and a STH efficiency of 6.1% when using a crystalline Si PV driver. The hybrid PV/a-SiC device tested under a current bias of -3~4 mA/cm{sup 2}, exhibited a durability of up to ~800 hours in 0.25 M H{sub 2}SO{sub 4} electrolyte. Other than the PV driver, the most critical element affecting the photocurrent (and hence the STH efficiency) of the hybrid PV/a-SiC device was the surface energetics at the a-SiC/electrolyte interface. Without surface modification, the photocurrent of the hybrid PEC device was ~1 mA/cm{sup 2} or lower due to a surface barrier that limits the extraction of photogenerated carriers. We conducted an extensive search for suitable surface modification techniques/materials, of which the deposition of low work function metal nanoparticles was the most successful. Metal nanoparticles of ruthenium (Ru), tungsten (W) or titanium (Ti) led to an anodic shift in the onset potential. We have also been able to develop hybrid devices of various configurations in a monolithic fashion and optimized the current matching via altering the energy bandgap and thickness of each constituent cell. As a result, the short-circuit photocurrent density of the hybrid device (measured in a 2-electrode configuration) increased significantly without assistance of any external bias, i.e. from ?1 mA/cm{sup 2} to ~5 mA/cm{sup 2}. With the copper chalcopyrite compounds, we have achieved a STH efficiency of 3.7% in a coplanar configuration with 3 a-Si solar cells and one CuGaSe{sub 2} photocathode. This material class exhibited good durability at a photocurrent density level of -4 mA/cm{sup 2} (“5% STH” equivalent) at a fixed potential (-0.45 VRHE). A poor band-edge alignment with the hydrogen evolution reaction (HER) potential was identified as the main limitation for high STH efficiency. Three new pathways have been identified to solve this issue. First, PV driver with bandgap lower than that of amorphous silicon were investigated. Crystalline silicon was identified as possible bottom cell. Mechanical stacks made with one Si solar cell and one CuGaSe{sub 2} photocathode were built. A 400 mV anodic shift was observed with the Si cell, leading to photocurrent density of -5 mA/cm{sup 2} at 0VRHE (compared to 0 mA/cm{sup 2} at the same potential without PV driver). We also investigated the use of p-n junctions to shift CuGaSe{sub 2} flatband potential anodically. Reactively sputtered zinc oxy-sulfide thin films was evaluated as n-type buffer and deposited on CuGaSe{sub 2}. Ruthenium nanoparticles were then added as HER catalyst. A 250 mV anodic shift was observed with the p-n junction, leading to photocurrent density at 0VRHE of -1.5 mA/cm{sup 2}. Combining this device with a Si solar cell in a mechanical stack configuration shifted the onset potential further (+400 mV anodically), leading to photocurrent density of -7 mA/cm{sup 2} at 0VRHE. Finally, we developed wide bandgap copper chalcopyrite thin film materials. We demonstrated that Se can be substituted with S using a simple annealing step. Photocurrent densities in the 5-6 mA/cm{sub 2} range were obtained with red 2.0eV CuInGaS{sub 2} photocathodes. With the metal oxide compounds, we have demonstrated that a WO{sub 3}-based hybrid p

Hu, Jian

2013-12-23T23:59:59.000Z

283

STILL CHASING THE HYDROGEN ECONOMY  

Science Journals Connector (OSTI)

Water electrolysis firm aims to help meet 2015 global target for first commercial FUEL-CELL CARS ... IN HIS 2003 State of the Union address, President George W. Bush proclaimed that the time was ripe for the hydrogen economy, a world in which hydrogen is the primary energy currency instead of fossil fuels. ...

STEPHEN K. RITTER

2011-11-07T23:59:59.000Z

284

Hydrogen,Fuel Cells & Infrastructure  

E-Print Network [OSTI]

chemical reaction between hydrogen and oxygen generates energy, which can be used to power a car producing funding so that America can lead the world in developing clean, hydrogen-powered automobiles." "A simple only water, not exhaust fumes. With a new national commitment, our scientists and engineers

285

Toward a quantitative model for the formation of gravitational magmatic sulfide deposits  

E-Print Network [OSTI]

concentration at sulfide saturation (referred to as sulfur solubility for simplicity) decreases. As the melt of sulfide liquid from a silicate melt, and the coupled growth kinetics and settling dynamics of sulfide liquid layer at the bottom of a magma chamber are referred to as the necessary criteria for sulfide ore

Zhang, Youxue

286

An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California  

E-Print Network [OSTI]

hydrogen via electrolysis using water as a feedstock. Forhydrogen via electrolysis using water as a feedstock. For

Nicholas, Michael A; Ogden, J

2010-01-01T23:59:59.000Z

287

Hydrogen Fuel Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Fuel Basics Hydrogen Fuel Basics Hydrogen Fuel Basics August 14, 2013 - 2:06pm Addthis Hydrogen is a clean fuel that, when consumed, produces only water. Hydrogen can be produced from a variety of domestic sources, such as coal, natural gas, nuclear power, and renewable power. These qualities make it an attractive fuel option for transportation and electricity generation applications. Hydrogen is an energy carrier that can be used to store, move, and deliver energy produced from other sources. The energy in hydrogen fuel is derived from the fuels and processes used to produce the hydrogen. Today, hydrogen fuel can be produced through several methods. The most common methods are thermal, electrolytic, and photolytic processes. Thermal Processes Thermal processes for hydrogen production typically involve steam

288

Hydrogen Fuel Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Fuel Basics Hydrogen Fuel Basics Hydrogen Fuel Basics August 14, 2013 - 2:06pm Addthis Hydrogen is a clean fuel that, when consumed, produces only water. Hydrogen can be produced from a variety of domestic sources, such as coal, natural gas, nuclear power, and renewable power. These qualities make it an attractive fuel option for transportation and electricity generation applications. Hydrogen is an energy carrier that can be used to store, move, and deliver energy produced from other sources. The energy in hydrogen fuel is derived from the fuels and processes used to produce the hydrogen. Today, hydrogen fuel can be produced through several methods. The most common methods are thermal, electrolytic, and photolytic processes. Thermal Processes Thermal processes for hydrogen production typically involve steam

289

Transportation Fuel Basics - Hydrogen | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Transportation Fuel Basics - Hydrogen Transportation Fuel Basics - Hydrogen Transportation Fuel Basics - Hydrogen August 19, 2013 - 5:45pm Addthis Hydrogen (H2) is a potentially emissions-free alternative fuel that can be produced from domestic resources. Although not widely used today as a transportation fuel, government and industry research and development are working toward the goal of clean, economical, and safe hydrogen production and hydrogen-powered fuel cell vehicles. Hydrogen is the simplest and most abundant element in the universe. However, it is rarely found alone in nature. Hydrogen is locked up in enormous quantities in water (H2O), hydrocarbons (such as methane, CH4), and other organic matter. Efficiently producing hydrogen from these compounds is one of the challenges of using hydrogen as a fuel. Currently,

290

Transportation Fuel Basics - Hydrogen | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Transportation Fuel Basics - Hydrogen Transportation Fuel Basics - Hydrogen Transportation Fuel Basics - Hydrogen August 19, 2013 - 5:45pm Addthis Hydrogen (H2) is a potentially emissions-free alternative fuel that can be produced from domestic resources. Although not widely used today as a transportation fuel, government and industry research and development are working toward the goal of clean, economical, and safe hydrogen production and hydrogen-powered fuel cell vehicles. Hydrogen is the simplest and most abundant element in the universe. However, it is rarely found alone in nature. Hydrogen is locked up in enormous quantities in water (H2O), hydrocarbons (such as methane, CH4), and other organic matter. Efficiently producing hydrogen from these compounds is one of the challenges of using hydrogen as a fuel. Currently,

291

Potential Carriers and Approaches for Hydrogen Delivery  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Carriers Calculation Tools Truck Transport Available H 2 Carrier Solution (Oil or water) Additional Reactant H 2 Carrier 16 Storage and forecourt tabs have been...

292

DOE Hydrogen Analysis Repository: Hydrogen Analysis Projects by Principal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Principal Investigator Principal Investigator Below are hydrogen analyses and analytical models grouped by principal investigator. | A | B | C | D | E | F | G | H | J | K | L | M | N | O | P | R | S | T | U | V | W A Portfolio of Power-Trains for Europe Review of FreedomCAR and Fuel Partnership Ahluwalia, Rajesh Fuel Cell Systems Analysis GCtool-ENG Ahluwalia, Rajesh K. Hydrogen Storage Systems Analysis Ahmed, Shabbir Cost Implications of Hydrogen Quality Requirements Fuel Quality Effects on Stationary Fuel Cell Systems Fuel Quality in Fuel Cell Systems Quick Starting Fuel Processors - A Feasibility Study Amos, Wade Biological Water-Gas Shift Costs of Storing and Transporting Hydrogen Photobiological Hydrogen Production from Green Algae Cost Analysis Arif, Muhammad Fuel Cell Water Transport Mechanism

293

Study of electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten as hydrogen electrodes in alkaline water electrolysis  

SciTech Connect (OSTI)

Electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten were characterized for the hydrogen evolution reaction (HER) in the electrolysis of 30 w/o KOH alkaline water at 25 C. The rate-determining step (rds) of the HER was suggested based on the Tafel slope of polarization and the capacitance of electrode-solution interface determined by ac impedance measurement. The HER on the nickel- and cobalt-based codeposits was enhanced significantly compared with that o the electrolytic nickel and cobalt with comparable deposit loadings. The decrease in the HER overpotential was more pronounced on the molybdenum-containing codeposits, particularly on cobalt-molybdenum which also showed a high stability. The enhancement of the HER was attributed to both the synergetic composition and the increased active surface of the codeposits. The real electrocatalytic activity of te electrodes and the effect of their and the increased active surface of the codeposits. The real electrocatalytic activity of the electrodes and the effect of their surface increase were distinguished quantitatively. The linear relations between HER overpotential and surface roughness factor of the electrodes on a Y-log(X) plot were obtained experimentally and interpreted based on the Tafel law.

Fan, C.; Piron, D.L.; Sleb, A.; Paradis, P. (Ecole Polytechnique de Montreal, Quebec (Canada). Dept. de Metallurgie et de Genie des Materiaux)

1994-02-01T23:59:59.000Z

294

AC03CH05-Levinger ARI 11 February 2010 22:19 Analysis of Water in Confined  

E-Print Network [OSTI]

of hydrogen fuel cells. Water's unique properties can be traced to its formation of an extended hydrogen micelles, nanoscopically confined water, hydrogen bond dynamics, orientational dynamics Abstract The properties of water depend on its extended hydrogen bond network and thecontinualpicosecond

Fayer, Michael D.

295

FUEL CELL TECHNOLOGIES PROGRAM Hydrogen and Fuel  

E-Print Network [OSTI]

Hydrogen is a versatile energy carrier that can be used to power nearly every end-use energy need. The fuel cell -- an energy conversion device that can efficiently capture and use the power of hydrogen the chemical energy in hydrogen to electricity, with pure water and potentially useful heat as the only

296

Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transition Metal Sulfide Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells Hua Zhang 1 , Ysmael Verde-Gómez 1 and Allan J. Jacobson 1 Alejandra Ramirez 2 and Russell R. Chianelli 2 1 Department of Chemistry, University of Houston Houston, TX 77204 2 Materials Research and Technology Institute, University of Texas at El Paso, El Paso, TX 79968 Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells Hua Zhang 1 , Ysmael Verde-Gómez 1 and Allan J. Jacobson 1 Alejandra Ramirez 2 and Russell R. Chianelli 2 1 Department of Chemistry, University of Houston Houston, TX 77204 2 Materials Research and Technology Institute, University of Texas at El Paso, El Paso, TX 79968 March 21, 2003 Objectives ¾ Investigate non-platinum electro-catalysts with CO tolerance ¾ Focus on transition metal sulfides as electro-catalysts

297

Design and fabrication of a tin-sulfide annealing furnace  

E-Print Network [OSTI]

A furnace was designed and its heat transfer properties were analyzed for use in annealing thin-film tins-ulfide solar cells. Tin sulfide has been explored as an earth abundant solar cell material, and the furnace was ...

Lewis, Raymond (Raymond A.)

2011-01-01T23:59:59.000Z

298

Utilization of Dimethyl Sulfide as a Sulfur Source with the Aid of Light by Marinobacterium sp. Strain DMS-S1  

Science Journals Connector (OSTI)

...sulfone, methanesulfonate, diethyl sulfide, tetrahydrothiophene, diethyl sulfone, ethanesulfonate, methionine...Methylphenyl sulfide (, TK) Diphenyl sulfide (, TK) Tetrahydrothiophene (, TK) Tetramethylene sulfoxide (, TK) Sulfolane...

Hiroyuki Fuse; Osamu Takimura; Katsuji Murakami; Yukiho Yamaoka; Toshio Omori

2000-12-01T23:59:59.000Z

299

Producing hydrogen using nuclear energy  

Science Journals Connector (OSTI)

The earliest means of separating hydrogen from water was by electrolysis using electrical energy that usually had been produced by low-efficiency thermodynamic processes. Substitution of thermal energy for electrical energy in high-temperature electrolysis gives a somewhat higher overall efficiency, but significantly complicates the process. Today, the vast majority of hydrogen is produced by steam methane reforming (SMR) followed by a water-shift reaction. A well-designed SMR plant will yield hydrogen having 75â??80% of the energy of the methane used. Recent work in Japan has demonstrated the feasibility of substituting high-temperature heat from a gas-cooled nuclear reactor to replace the heat supplied in SMR by the combustion of methane. Using high-temperature heat from nuclear plants to drive thermochemical processes for producing hydrogen has been studied extensively. Bench-scale tests have been carried out in Japan demonstrating the sulphur-iodine (SI) process to produce hydrogen.

Robert E. Uhrig

2008-01-01T23:59:59.000Z

300

Process for thin film deposition of cadmium sulfide  

DOE Patents [OSTI]

The present invention teaches a process for depositing layers of cadmium sulfide. The process includes depositing a layer of cadmium oxide by spray pyrolysis of a cadmium salt in an aqueous or organic solvent. The oxide film is then converted into cadmium sulfide by thermal ion exchange of the O.sup.-2 for S.sup.-2 by annealing the oxide layer in gaseous sulfur at elevated temperatures.

Muruska, H. Paul (East Windsor, NJ); Sansregret, Joseph L. (Scotch Plains, NJ); Young, Archie R. (Montclair, NJ)

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Water-splitting using photocatalytic porphyrin-nanotube composite devices  

DOE Patents [OSTI]

A method for generating hydrogen by photocatalytic decomposition of water using porphyrin nanotube composites. In some embodiments, both hydrogen and oxygen are generated by photocatalytic decomposition of water.

Shelnutt, John A. (Tijeras, NM); Miller, James E. (Albuquerque, NM); Wang, Zhongchun (Albuquerque, NM); Medforth, Craig J. (Winters, CA)

2008-03-04T23:59:59.000Z

302

Hydrogen from renewable resources research  

SciTech Connect (OSTI)

In 1986 the Hawaii Natural Energy Institute (HNEI) and the Florida Solar Energy Center (FSEC) were contracted by the Solar Energy Research Institute (SERI) to conduct an assessment of hydrogen production technologies and economic feasibilities of the production and use of hydrogen from renewable resources. In the 1989/90 period all monies were directed toward research and development with an emphasis on integration of tasks, focusing on two important issues, production and storage. The current year's efforts consisted of four tasks, one task containing three subtasks: Hydrogen Production by Gasification of Glucose and Wet Biomass in Supercritical Water; Photoelectrochemical Production of Hydrogen; Photoemission and Photoluminescence Studies of Catalyzed Photoelectrode Surfaces for Hydrogen Production; Solar Energy Chemical Conversion by Means of Photoelectrochemical (PEC) Methods Using Coated Silicon Electrodes; Assessment of Impedance Spectroscopy Methods for Evaluation of Semiconductor-Electrolyte Interfaces; Solar Energy Conversion with Cyanobacteria; Nonclassical Polyhydride Metal Complexes as Hydrogen Storage Materials. 61 refs., 22 figs., 11 tabs.

Takahashi, P.K.; McKinley, K.R.

1990-07-01T23:59:59.000Z

303

Support of a pathway to a hydrogen future  

SciTech Connect (OSTI)

This paper consists of viewgraphs which outline the content of the presentation. Subjects addressed include: hydrogen research program vision; electricity industry restructuring -- opportunities and challenges for hydrogen; transportation sector -- opportunities for hydrogen; near-term and mid-term opportunities for hydrogen; and hydrogen production technologies from water. It is concluded that the global climate change challenge is the potential driver for the development of hydrogen systems.

Hoffman, A.R. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

1997-12-31T23:59:59.000Z

304

Iron sulfide catalysts for coal liquefaction prepared using a micellar technique  

SciTech Connect (OSTI)

The authors have recently synthesized nanometer-size iron sulfide catalysts using a reverse micellar system. These particles are 40--70 nm in size and were used in laboratory-scale coal-liquefaction experiments. The catalyst particles were impregnated in situ on coal particles. The catalyst loading was 1.67% with respect to coal. The liquefaction run was carried out at 400 C for 30 min, at a pressure of 1,000 psia H{sub 2}(g) measured at ambient temperature (corresponding to approximately 2,000 psia at reaction conditions), tine absence of any solvent or hydrogen donor. The total conversion, as well as the yields of asphaltene plus preasphaltene and oil plus gas, increased after the run, relative to a thermal (noncatalytic) run. The activity of the micellar catalyst is slightly less than that of a nonmicellar catalyst. However, a slightly higher selectivity to oil plus gas is observed with the micellar catalyst.

Chadha, A.; Sharma, R.K.; Stinespring, C.D.; Dadyburjor, D.B. [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering] [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering

1996-09-01T23:59:59.000Z

305

Historical Doses from Tritiated Water and Tritiated Hydrogen Gas Released to the Atmosphere from Lawrence Livermore National Laboratory (LLNL). Part 5. Accidental Releases  

SciTech Connect (OSTI)

Over the course of fifty-three years, LLNL had six acute releases of tritiated hydrogen gas (HT) and one acute release of tritiated water vapor (HTO) that were too large relative to the annual releases to be included as part of the annual releases from normal operations detailed in Parts 3 and 4 of the Tritium Dose Reconstruction (TDR). Sandia National Laboratories/California (SNL/CA) had one such release of HT and one of HTO. Doses to the maximally exposed individual (MEI) for these accidents have been modeled using an equation derived from the time-dependent tritium model, UFOTRI, and parameter values based on expert judgment. All of these acute releases are described in this report. Doses that could not have been exceeded from the large HT releases of 1965 and 1970 were calculated to be 43 {micro}Sv (4.3 mrem) and 120 {micro}Sv (12 mrem) to an adult, respectively. Two published sets of dose predictions for the accidental HT release in 1970 are compared with the dose predictions of this TDR. The highest predicted dose was for an acute release of HTO in 1954. For this release, the dose that could not have been exceeded was estimated to have been 2 mSv (200 mrem), although, because of the high uncertainty about the predictions, the likely dose may have been as low as 360 {micro}Sv (36 mrem) or less. The estimated maximum exposures from the accidental releases were such that no adverse health effects would be expected. Appendix A lists all accidents and large routine puff releases that have occurred at LLNL and SNL/CA between 1953 and 2005. Appendix B describes the processes unique to tritium that must be modeled after an acute release, some of the time-dependent tritium models being used today, and the results of tests of these models.

Peterson, S

2007-08-15T23:59:59.000Z

306

Experimental Studies in Hydrogen Generation for Fuel Cell Applications using Aluminum Powder.  

E-Print Network [OSTI]

??One method of producing on-demand hydrogen for fuel cells is through the use of aluminum which reacts with water under certain conditions to produce hydrogen.… (more)

Ahmad, Faizan

2010-01-01T23:59:59.000Z

307

Intrinsic Diffusion of Hydrogen on Rutile TiO2(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

images demonstrate a complex behavior of hydrogen formed by water dissociation on BBO vacancies. Different diffusion rates are observed for the two hydrogens in the original...

308

Sulfide, phosphate, and minor element enrichment in the New Albany Shale (Devonian-Mississippian) of southern Indiana  

SciTech Connect (OSTI)

The upper part of the New Albany Shale is divided into three members, which in ascending order are: (1) the Morgan Trail Member, a laminated brownish-black shale; (2) the Camp Run Member, an interbedded brownish-black and greenish-gray shale; and (3) the Clegg Creek Member, also a laminated brownish-black shale. The Morgan Trail and Camp Run Members contain 5 to 6% total organic carbon (TOC) and 2% sulfide sulfur. Isotopic composition of sulfide in these members ranges from -5.0 to -20.0%. C/S plots indicate linear relationships between abundances of these elements characteristic of sediments deposited in a noneuxinic marine environment. The Clegg Creek Member contains 10 to 15% TOC and 2 to 6% sulfide sulfur. Isotopic composition of sulfide ranges from -5.0 to -40.0%. The most negative values are characteristic of syngenetic pyrite formed within an anoxic water column. Abundances of carbon and sulfur are higher and uncorrelated in this member, consistent with deposition in an euxinic environment. Further, DOP (degree of pyritization) values suggest that pyrite formation was generally iron limited throughout Clegg Creek deposition, but sulfur isotopes indicate that syngenetic (water column) pyrite becomes an important component in the sediment only in the upper part of the member. At the top of the Clegg Creek Member a zone of phosphate nodules and trace metal enrichment coincides with maximal TOC values. During euxinic deposition, phosphate and trace metals accumulated below the chemocline due to limited vertical circulation in the water column. Phosphate and trace metals released for organic matter during early diagenesis resulted in precipitation of metal-rich phosphate nodules.

Beier, J.A.

1988-01-01T23:59:59.000Z

309

Hydrogen & Fuel Cells - Hydrogen - Hydrogen Storage  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Storage Systems Modeling and Analysis Hydrogen Storage Systems Modeling and Analysis Several different approaches are being pursued to develop on-board hydrogen storage systems for light-duty vehicle applications. The different approaches have different characteristics, such as: the thermal energy and temperature of charge and discharge kinetics of the physical and chemical process steps involved requirements for the materials and energy interfaces between the storage system and the fuel supply system on one hand, and the fuel user on the other Other storage system design and operating parameters influence the projected system costs as well. Argonne researchers are developing thermodynamic, kinetic, and engineering models of the various hydrogen storage systems to understand the characteristics of storage systems based on these approaches and to evaluate their potential to meet the DOE targets for on-board applications. The DOE targets for 2015 include a system gravimetric capacity of 1.8 kWh/kg (5.5 wt%) and a system volumetric capacity of 1.3 kWh/L (40 g/L). We then use these models to identify significant component and performance issues, and evaluate alternative system configurations and design and operating parameters.

310

FOCUS: HYDROGEN EXCHANGE AND COVALENT MODIFICATION ACCOUNT AND PERSPECTIVE  

E-Print Network [OSTI]

hydrogen exchange behavior, understand the underlying chemistry and structural physics of hydrogen exchange-protected by their H-bonding interactions, they engage in continual ex- change with the hydrogens of solvent water of the underlying chemistry and structural phys- ics of protein HX processes. The study of protein hydrogen exchange

Englander, S. Walter

311

Iowa's first electrodialysis reversal water treatment plant  

Science Journals Connector (OSTI)

In 1979 the City of Washington was notified by the Iowa Department of Natural Resources (IDNR) that the City was in violation of the radium standard for drinking water. The City of Washington authorized an engineering study to determine the most cost-effective and practical way to remove radium and, at the same time, improve overall water quality. Several possible treatment alternatives were evaluated. It was finally decided to utilize electrodialysis reversal (EDR). Washington obtains its water from three deep wells ranging in capacity from 600–780 gpm. The untreated water withdrawn from the wells first passes through the EDR units. There are three EDR units, each able to produce 285 gpm of finished water. In the future, another EDR unit can be easily added to the other three units, since the new plant was built and plumbed for an additional EDR unit if water demand increased. The Jordan aquifer supply is adequate for current and future needs. The average daily water usage in 1993 was 818,000 gal/d. In order to meet peak flows, it is possible to bypass the EDR units with part of the untreated water and then blend treated and untreated water. The treated water meets IDNR standards of 5.0 pC/L. After the EDR units, the water flows through an aerator where odor-causing gases and carbon dioxide are removed. Aeration reduces the amount of caustic soda and chlorine used in the finished water. The hydrogen sulfide gas leaves the water as it passes through the aerator, and this loss of gas creates less chlorine demand. Total and free chlorine residuals are now detected in every water main of the town, whereas before, the residuals would not be detected in certain area of Washington. Phosphates have been cut back from 7 pounds per day to one pound per day. Better water quality is now being achieved with fewer chemicals added to the finished water. Washington's water treatment plant is the first municipal EDR plant in the State of Iowa and one of the largest municipal installations in the United States.

John Hays

2000-01-01T23:59:59.000Z

312

Hydrogen Liquefaction  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Liquid Hydrogen is 0.2% Ortho, 99.8% Para 3 Liquid Supply North America 250+ TPD Capacity Diverse Feedstocks Chlor-Alkali SMR Petro-chem Market...

313

Hydrogen Storage  

Science Journals Connector (OSTI)

Hydrogen is an important energy carrier, and when used as a fuel, can be considered as an alternate to the major fossil fuels, coal, crude oil, and natural gas, and their derivatives. It has the potential to b...

Prof. Dr. Robert A. Huggins

2010-01-01T23:59:59.000Z

314

Hydrogen energy  

Science Journals Connector (OSTI)

...use of hydrogen as an energy carrier will depend significantly...its utilization and conversion to electricity/heat...becomes an alternative energy carrier. However, various...effectively with conventional energy conversion technologies. The...

2007-01-01T23:59:59.000Z

315

Hydrogen Production  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

316

Hydrogen- and Oxygen from Water  

Science Journals Connector (OSTI)

...DUFFIE, J.A., SOLAR ENERGY THERMAL 178 ( 1974 ). FUNK...4, in which the thermal effects of operation...curve, QH, is the net solar heat flow into the...A. Beckman, in Solar Ener-gy Thermal Processes (Wiley...

Edward A. Fletcher; Roger L. Moen

1977-09-09T23:59:59.000Z

317

Extractive distribution of microamounts of europium and americium in the two phase water — HCl — nitrobenzene — N,N,N?,N?-tetraethyl-2,6-dipicolinamide — hydrogen dicarbollylcobaltate system  

Science Journals Connector (OSTI)

Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B?) in the presence of N,N,N?,N?-tetraethyl-2,6-dipicolinamide (TEtDPA, L) has been investigated...

E. Makrlík; P. Va?ura; P. Selucký…

2009-03-01T23:59:59.000Z

318

BOUNDARY LAYER CONTROL IN PIPES THROUGH STRONG INJECTION  

E-Print Network [OSTI]

the environment in a gasifier contains hydrogen, water,compo- nents of the gasifier must be corrosion resistant atis used in existing coal gasifiers. Since hydrogen sulfide

Yeung, William Chor Chun

2014-01-01T23:59:59.000Z

319

Process for removing metals from water  

DOE Patents [OSTI]

A process for removing metals from water including the steps of prefiltering solids from the water, adjusting the pH to between about 2 and 3, reducing the amount of dissolved oxygen in the water, increasing the pH to between about 6 and 8, adding water-soluble sulfide to precipitate insoluble sulfide- and hydroxide-forming metals, adding a containing floc, and postfiltering the resultant solution. The postfiltered solution may optionally be eluted through an ion exchange resin to remove residual metal ions. 2 tabs.

Napier, J.M.; Hancher, C.M.; Hackett, G.D.

1987-06-29T23:59:59.000Z

320

Roles of cocatalysts in semiconductor-based photocatalytic hydrogen production  

Science Journals Connector (OSTI)

...cocatalyst|hydrogen production|water splitting...Photocatalytic hydrogen generation...promising way for H2 production. For water splitting...solid-state reaction method [12]. Y2O3...versus normal hydrogen electrode, negative...of CdS for H2 production could be increased...hydrothermal method through loading...

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Monday, February 23, 2009 Cheap Hydrogen from Scraps  

E-Print Network [OSTI]

because burning it creates only water as a waste product. MECs harness the electrons produced by certainMonday, February 23, 2009 Cheap Hydrogen from Scraps Turning organic waste into hydrogen now works scraps and waste water to generate clean hydrogen fuel. But over the past few years, researchers have

322

Hydrogen Gas Production from Nuclear Power Plant in Relation to Hydrogen Fuel Cell Technologies Nowadays  

Science Journals Connector (OSTI)

Recently world has been confused by issues of energy resourcing including fossil fuel use global warming and sustainable energy generation. Hydrogen may become the choice for future fuel of combustion engine. Hydrogen is an environmentally clean source of energy to end?users particularly in transportation applications because without release of pollutants at the point of end use. Hydrogen may be produced from water using the process of electrolysis. One of the GEN?IV reactors nuclear projects (HTGRs HTR VHTR) is also can produce hydrogen from the process. In the present study hydrogen gas production from nuclear power plant is reviewed in relation to commercialization of hydrogen fuel cell technologies nowadays.

2010-01-01T23:59:59.000Z

323

Coregulated Genes Link Sulfide:Quinone Oxidoreductase and Arsenic Metabolism in Synechocystis sp. Strain PCC6803  

Science Journals Connector (OSTI)

...salt-tolerant chemolithoautotrophic sulfide oxidizers found in hot spring biofilms at Mono...using enrichment cultures of sulfide oxidizers closely related to some Thioalkalivibrio...Reyes (Andalusian Molecular Biology and Regenerative Medicine Centre). There is no conflict...

Csaba I. Nagy; Imre Vass; Gábor Rákhely; István Zoltán Vass; András Tóth; Ágnes Duzs; Loredana Peca; Jerzy Kruk; Péter B. Kós

2014-07-14T23:59:59.000Z

324

CdS nanoparticles sensitization of Al-doped ZnO nanorod array thin film with hydrogen treatment as an ITO/FTO-free photoanode for solar water splitting  

Science Journals Connector (OSTI)

Aluminum-doped zinc oxide (AZO) nanorod array thin ... region, it is sensitized by cadmium sulfide (CdS) nanoparticles which efficiently increase the absorption around 460 nm. The CdS nanoparticles-sensitized AZO...

Chih-Hsiung Hsu; Dong-Hwang Chen

2012-10-01T23:59:59.000Z

325

Biogeochemical cycling in an organic-rich coastal marine basin. 7. Sulfur mass balance, oxygen uptake and sulfide retention  

SciTech Connect (OSTI)

Sulfur and oxygen fluxes were quantified in the seasonally varying anoxic marine sedimentary system of Cape Lookout Bight, N.C., U.S.A. Over the three year study period, 1981-1983, the mean annual sulfate reduction rate was determined to be 18.2 +/- 1.6 moles x m/sup -2/ x y/sup -1/. This value, added to the estimate of the detrital sulfur input of 1.2 +/- 4.4 gave a total sulfur input of 19.4 +/- 4.7 moles x m/sup -1/ x y/sup 2/)/sup 1/. The sulfide flux to the sediment-water interface, measured in anaerobic benthic chambers was 4.6 +/- 0.5 moles x m/sup -2/ x y/sup -1/, and represented 37% of the annual oxygen uptake rate of 25.2 +/- 2.8 moles x m/sup -2/ x y/sup -1/. The sulfide burial rate, determined to be 15.5 +/- 3.1 moles x m/sup -2/ x y/sup -1/, was within 5% of the value predicted by summing the fluxes at the sediment-water interface. The C/S weight ratio of sediment below the depth of diagenetic reaction was determined to be 2.75. The sulfide retention rate in these rapidly accumulating sediments (10 cm/yr) was 77 +/- 19%. Comparison of this result with previous studies shows that rapid sediment accumulation and the lack of bioturbation control this unusually high degree of sulfide retention.

Chanton, J.P.; Martens, C.S.

1987-05-01T23:59:59.000Z

326

10 - Thermochemical production of hydrogen  

Science Journals Connector (OSTI)

Abstract: The growing interest in hydrogen as a chemical reactant and energy carrier requires evaluation of all possible conversion processes for its production. This chapter analyses the different processes currently used for hydrogen production, together with the most promising approaches currently under development. Among the latter are thermochemical water-splitting cycles powered by renewable (sustainable) energy sources. A simplified description of the basic thermodynamic aspects of this process is presented, and some examples are presented.

A. Giaconia

2014-01-01T23:59:59.000Z

327

Hydrogen program overview  

SciTech Connect (OSTI)

This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

1997-12-31T23:59:59.000Z

328

Active Hydrogen  

Science Journals Connector (OSTI)

Dry hydrogen can be activated in an electric discharge if the pressure and voltage are carefully regulated. Active hydrogen reduces metallic sulphides whose heat of formation is 22 000 cal. or less. The active gas is decomposed by 3 cm of well packed glass wool. A quantitative method is given for the determination of active hydrogen. Less of the active gas is formed in a tube coated with stearic acid or phosphoric acid than when no coating is employed. The decay reaction was found to follow the expression for a unimolecular reaction. The rate of decay appears to be independent of the wall surface. The period of half?life at room temperature and 40 mm pressure is 0.2 sec. approximately. The energy of formation of active hydrogen is approximately 18 000 cal. The energy of activation for the decay of the active constituent is approximately 17 800 cal. The properties of active hydrogen are considered in relation to the properties predicted for H3.

A. C. Grubb; A. B. Van Cleave

1935-01-01T23:59:59.000Z

329

Radical cations of sulfides and disulfides: An ESR study  

SciTech Connect (OSTI)

Exposure of dilute solutions of dimethylsulfide, methanethiol, tetrahydrothiophene, terbutyl and diterbutyl-sulfides, dimethyl-disulfide, and diterbutyldisulfide, in freon at 77 K to /sup 60/Co ..gamma.. rays gave the corresponding cations. From the reported ESR spectra, g tensors were obtained. It was found that both sulfide and disulfide cations exhibit the same g tensor: (g/sub max/ = 2.034 +- 0.002, g/sub int/ = 2.017 +- 0.001, g/sub min/ = 2.001 +- 0.005). From this result it has been shown that the disulfide cation is planar. This finding was supported by fully optimized geometry ab initio calculations.

Bonazzola, L.; Michaut, J.P.; Roncin, J.

1985-09-15T23:59:59.000Z

330

Analysis of Ontario's hydrogen economy demands from hydrogen fuel cell vehicles  

Science Journals Connector (OSTI)

The ‘Hydrogen Economy’ is a proposed system where hydrogen is produced from carbon dioxide free energy sources and is used as an alternative fuel for transportation. The utilization of hydrogen to power fuel cell vehicles (FCVs) can significantly decrease air pollutants and greenhouse gases emission from the transportation sector. In order to build the future hydrogen economy, there must be a significant development in the hydrogen infrastructure, and huge investments will be needed for the development of hydrogen production, storage, and distribution technologies. This paper focuses on the analysis of hydrogen demand from hydrogen \\{FCVs\\} in Ontario, Canada, and the related cost of hydrogen. Three potential hydrogen demand scenarios over a long period of time were projected to estimate hydrogen \\{FCVs\\} market penetration, and the costs associated with the hydrogen production, storage and distribution were also calculated. A sensitivity analysis was implemented to investigate the uncertainties of some parameters on the design of the future hydrogen infrastructure. It was found that the cost of hydrogen is very sensitive to electricity price, but other factors such as water price, energy efficiency of electrolysis, and plant life have insignificant impact on the total cost of hydrogen produced.

Hui Liu; Ali Almansoori; Michael Fowler; Ali Elkamel

2012-01-01T23:59:59.000Z

331

Hydrogen Generation Via Fuel Reforming  

Science Journals Connector (OSTI)

Reforming is the conversion of a hydrocarbon based fuel to a gas mixture that contains hydrogen. The H2 that is produced by reforming can then be used to produce electricity via fuel cells. The realization of H2?based power generation via reforming is facilitated by the existence of the liquid fuel and natural gas distribution infrastructures. Coupling these same infrastructures with more portable reforming technology facilitates the realization of fuel cell powered vehicles. The reformer is the first component in a fuel processor. Contaminants in the H2?enriched product stream such as carbon monoxide (CO) and hydrogen sulfide (H2S) can significantly degrade the performance of current polymer electrolyte membrane fuel cells (PEMFC’s). Removal of such contaminants requires extensive processing of the H2?rich product stream prior to utilization by the fuel cell to generate electricity. The remaining components of the fuel processor remove the contaminants in the H2 product stream. For transportation applications the entire fuel processing system must be as small and lightweight as possible to achieve desirable performance requirements. Current efforts at Argonne National Laboratory are focused on catalyst development and reactor engineering of the autothermal processing train for transportation applications.

John F. Krebs

2003-01-01T23:59:59.000Z

332

Zirfon® as Separator Material for Water Electrolysis Under Specific Conditions  

Science Journals Connector (OSTI)

Hydrogen production through alkaline water electrolysis requires improvements to use renewable energy more...

María José Lavorante; Juan Isidro Franco…

2014-01-01T23:59:59.000Z

333

Hydrogen Analysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A A H2A: Hydrogen Analysis Margaret K. Mann DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29, 2004 Washington, D.C. H2A Charter * H2A mission: Improve the transparency and consistency of approach to analysis, improve the understanding of the differences among analyses, and seek better validation from industry. * H2A was supported by the HFCIT Program H2A History * First H2A meeting February 2003 * Primary goal: bring consistency & transparency to hydrogen analysis * Current effort is not designed to pick winners - R&D portfolio analysis - Tool for providing R&D direction * Current stage: production & delivery analysis - consistent cost methodology & critical cost analyses * Possible subsequent stages: transition analysis, end-point

334

Hydrogen Technologies Group  

SciTech Connect (OSTI)

The Hydrogen Technologies Group at the National Renewable Energy Laboratory advances the Hydrogen Technologies and Systems Center's mission by researching a variety of hydrogen technologies.

Not Available

2008-03-01T23:59:59.000Z

335

Hydrogen | Open Energy Information  

Open Energy Info (EERE)

Sector List of Hydrogen Incentives Hydrogen Energy Data Book Retrieved from "http:en.openei.orgwindex.php?titleHydrogen&oldid271963...

336

The Hype About Hydrogen  

E-Print Network [OSTI]

economy based on the hydrogen fuel cell, but this cannot beus to look toward hydrogen. Fuel cell basics, simplifiedthe path to fuel cell commercialization. Hydrogen production

Mirza, Umar Karim

2006-01-01T23:59:59.000Z

337

Hydrogen and Fuel Cell Technology Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen and Fuel Cell Technology Basics Hydrogen and Fuel Cell Technology Basics Hydrogen and Fuel Cell Technology Basics August 14, 2013 - 2:01pm Addthis Photo of a woman scientist using a machine that is purifying biological catalysts for hydrogen production. Hydrogen is the simplest element on Earth. A hydrogen atom consists of only one proton and one electron. It is also the most plentiful element in the universe. Despite its simplicity and abundance, hydrogen doesn't occur naturally as a gas on Earth. It is always combined with other elements. Water, for example, is a combination of hydrogen and oxygen. Hydrogen is also found in many organic compounds, notably the "hydrocarbons" that make up fuels such as gasoline, natural gas, methanol, and propane. To generate electricity using hydrogen, pure hydrogen must first be

338

Hydrogen and Hydrogen-Storage Materials  

Science Journals Connector (OSTI)

Currently, neutron applications in the field of hydrogen and hydrogen-storage materials represent a large and promising research ... relevant topics from this subject area, including hydrogen bulk properties (con...

Milva Celli; Daniele Colognesi; Marco Zoppi

2009-01-01T23:59:59.000Z

339

Adsorption of carbonyl sulfide on nickel and tungsten films  

SciTech Connect (OSTI)

The interaction of carbonyl sulfide with evaporated nickel and tungsten films has been investigated in the temperature range 195-450 K using gas pressures ranging from 1 to 13 N m/sup -2/. Rapid but mainly associative chemisorption of COS occurred on both metals at 195 K. Further adsorption of COS on W at temperatures 293-450 K was extremely slow and accompanied by more CO desorption than COS adsorbed. Sulfidation of Ni film by COS occurred at temperatures greater than or equal to 293 K with the liberation of carbon monoxide. The rate of adsorption increased with temperature but was independent of COS pressure. The activation energy (E/sub x/) increased with extent (X) of sulfidation to a limiting value of 97 kJ mol/sup -1/. A linear relationship was obtained from the plot of E/sub x/ against 1/X, suggesting the applicability of Cabrera-Mott theory to the sulfidation of Ni film by COS. 20 references, 2 figures, 1 table.

Saleh, J.M.; Nasser, F.A.K.

1985-07-18T23:59:59.000Z

340

DOE Hydrogen Program FY 2005 Progress Report IV.F Photoelectrochemical  

E-Print Network [OSTI]

barriers from the Hydrogen Production section of the Hydrogen, Fuel Cells and Infrastructure TechnologiesDOE Hydrogen Program FY 2005 Progress Report 13 IV.F Photoelectrochemical IV.F.1 High-Efficiency Generation of Hydrogen Using Solar Thermochemical Splitting of Water - UNLV: Photoelectrochemical Hydrogen

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

The water-gas shift (WGS) reaction (CO + H2O = CO2+ H2) is an important reaction for hydrogen upgrading during fuel  

E-Print Network [OSTI]

-treatment units in practical low-temperature PEM fuel cell systems, whereby the deleterious CO should be totally for hydrogen upgrading during fuel gas processing. Emerging applications in fuel cells require active, non-pyrophoric, and cost-effective catalysts. Along with a new group of platinum catalysts with atomically dispersed Pt

Napp, Nils

342

Hydrogen Energy System and Hydrogen Production Methods  

Science Journals Connector (OSTI)

Hydrogen is being considered as a synthetic fuel ... . This paper contains an overview of the hydrogen production methods, those being commercially available today as well...

F. Barbir; T. N. Veziro?lu

1992-01-01T23:59:59.000Z

343

Why Hydrogen? Hydrogen from Diverse Domestic Resources  

Broader source: Energy.gov [DOE]

Overview of the U.S. DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program, including technical targets and research and development needs for hydrogen storage and delivery.

344

Heterogeneous Oxidation of Carbonyl Sulfide on Atmospheric Particles and Alumina  

Science Journals Connector (OSTI)

The specifications of gases used in this experiment are as follows without further purification:? OCS (2%, OCS/N2, Scott Specialty Gases Inc.), O2 (99.99% purity, Beijing AP BEIFEN Gases Inc.), H2 (99.999% purity, GCD-300B high purity hydrogen generator, China Bchp Analytical Technology Co. Ltd.). ... To confirm our assignment about the surface SO42- species, 1.0 g of preoxidized Al2O3 sample after exposure to a flow of 500 ppm OCS + 95% O2 at 298 K for 2 h was analyzed by ion chromatography (DIONEX, CA); 2.43 mg/L SO42- can be detected (sample stirred with 100 mL deionized water, and then filtered through a 0.45-?m filter). ... Since the real atmospheric particle sample has relatively high surface area (4.8 m2/g), its influence on the conversion of OCS in atmosphere is not neglectable. ...

Hong He; Junfeng Liu; Yujing Mu; Yunbo Yu; Meixue Chen

2005-11-05T23:59:59.000Z

345

NREL: Hydrogen and Fuel Cells Research - Biological Sciences  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biological Sciences Biological Sciences NREL's biological scientists conduct research on microorganisms-such as photosynthetic bacteria, cyanobacteria, and algae-and are discovering new ways to produce hydrogen and valuable reduced-carbon compounds. We are studying how, through photosynthesis, green algae and cyanobacteria can split water to produce hydrogen, and how, through fermentation, bacteria can produce hydrogen from lignocellulosic biomass feedstocks. Photobiological Water Splitting Image of two green ovals with two yellow strands at the bottom of each oval. Microscopic view of the green alga Chlamydomonas reinhardtii. Microorganisms, like green algae and cyanobacteria, can produce hydrogen by splitting water through a process called "biophotolysis" or "photobiological hydrogen production." This photosynthetic pathway produces

346

Hydrogen Analysis Group  

SciTech Connect (OSTI)

NREL factsheet that describes the general activites of the Hydrogen Analysis Group within NREL's Hydrogen Technologies and Systems Center.

Not Available

2008-03-01T23:59:59.000Z

347

The Hype About Hydrogen  

E-Print Network [OSTI]

another promising solution for hydrogen storage. However,storage and delivery, and there are safety issues as well with hydrogen

Mirza, Umar Karim

2006-01-01T23:59:59.000Z

348

Hydrogen Technology Validation  

Fuel Cell Technologies Publication and Product Library (EERE)

This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

349

DOE Hydrogen Analysis Repository: Centralized Hydrogen Production from Wind  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wind Wind Project Summary Full Title: Well-to-Wheels Case Study: Centralized Hydrogen Production from Wind Project ID: 214 Principal Investigator: Fred Joseck Keywords: Wind; hydrogen production; well-to-wheels (WTW); fuel cell vehicles (FCV); electrolysis Purpose Provide well-to-wheels energy use and emissions data on a potential pathway for producing hydrogen from wind via centralized water electrolysis. This data was used in developing the U.S. Department of Energy Hydrogen Posture Plan. Performer Principal Investigator: Fred Joseck Organization: DOE/EERE/HFCIT Address: 1000 Independence Avenue, SW Washington, DC 20585 Telephone: 202-586-7932 Email: Fred.Joseck@ee.doe.gov Additional Performers: Margaret Mann, National Renewable Energy Laboratory; Michael Wang, Argonne National Laboratory

350

DOE Hydrogen Analysis Repository: Distributed Hydrogen Production from Wind  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

from Wind from Wind Project Summary Full Title: Well-to-Wheels Case Study: Distributed Hydrogen Production from Wind Project ID: 216 Principal Investigator: Fred Joseck Keywords: Wind; hydrogen production; well-to-wheels (WTW); fuel cell vehicles (FCV); electrolysis Purpose Provide well-to-wheels energy use and emissions data on a potential pathway for producing hydrogen from wind via distributed water electrolysis. This data was used in developing the U.S. Department of Energy Hydrogen Posture Plan. Performer Principal Investigator: Fred Joseck Organization: DOE/EERE/HFCIT Address: 1000 Independence Avenue, SW Washington, DC 20585 Telephone: 202-586-7932 Email: Fred.Joseck@ee.doe.gov Additional Performers: Margaret Mann, National Renewable Energy Laboratory; Michael Wang, Argonne National Laboratory

351

New High Performance Water Vapor Membranes to Improve Fuel Cell Balance of Plant Efficiency and Lower Costs (SBIR Phase I) - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0 0 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Earl H. Wagener (Primary Contact), Brad P. Morgan, Jeffrey R. DiMaio Tetramer Technologies L.L.C. 657 S. Mechanic St. Pendleton, SC 29670 Phone: (864) 646-6282 Email: earl.wagener@tetramertechnologies.com DOE Manager HQ: Nancy Garland Phone: (202) 586-5673 Email: Nancy.Garland@ee.doe.gov Contract Number: DE-SC0006172 Project Start Date: June 17, 2011 Project End Date: March 16, 2012 Fiscal Year (FY) 2012 Objectives Demonstrate water vapor transport membrane with * >18,000 gas permeation units (GPU) Water vapor membrane with less than 20% loss in * performance after stress tests Crossover leak rate: <150 GPU * Temperature Durability of 90°C with excursions to * 100°C Cost of <$10/m

352

Evaluating the phase equilibria of liquid water + natural gas mixtures using cubic equations of state with asymmetric mixing rules  

Science Journals Connector (OSTI)

Based on a previously developed liquid–liquid mixing rule we present a modified and robust mixing rule for accurate prediction of water content of natural gas mixtures and the natural gas solubility in liquid water phase. The non-density dependent mixing rule (NDD) and the new mixing rule are incorporated into the Peng–Robinson (PR), Soave–Redlich–Kwong (SRK), and Nasrifar–Bolland (NB) equations of state to investigate their accuracies in estimating the water content of the gas phase as well as the gas solubility in the aqueous phase. For each binary system water + hydrocarbon, water + carbon dioxide, water + hydrogen sulfide, and water + nitrogen, three binary interaction parameters are required to describe the gas–liquid water equilibria. In this work, experimental data from literature were used to tune the parameters. The results are in good agreement with experimental data, demonstrating the reliability of the new mixing rule and the thermodynamic approach used in this work.

P. Reshadi; Kh. Nasrifar; M. Moshfeghian

2011-01-01T23:59:59.000Z

353

8 - Photocatalytic production of hydrogen  

Science Journals Connector (OSTI)

Abstract: The photocatalytic production of hydrogen represents a fascinating way to convert and store solar energy as chemical energy, in the form of renewable hydrogen, the ideal fuel for the future. Hydrogen can be produced either by direct water splitting or by photo-reforming of organics in either liquid or gas phase. Both methods are reviewed in this chapter. Starting with a brief historical background, the most recent achievements in the field of photocatalytic hydrogen production are discussed, concerning both the development of innovative materials able to exploit a larger portion of the solar spectrum compared to traditional photocatalytic materials, and the different set-ups and devices which have been developed and tested.

G.L. Chiarello; E. Selli

2014-01-01T23:59:59.000Z

354

Measurement of gas/water uptake coefficients for trace gases active in the marine environment  

SciTech Connect (OSTI)

Ocean produced reduced sulfur compounds including dimethylsulfide (DMS), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}CH) and carbonyl sulfide (OCS) deliver a sulfur burden to the atmosphere which is roughly equal to sulfur oxides produced by fossil fuel combustion. These species and their oxidation products dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}) and methane sulfonic acid (MSA) dominate aerosol and CCN production in clean marine air. Furthermore, oxidation of reduced sulfur species will be strongly influenced by NO{sub x}/O{sub 3} chemistry in marine atmospheres. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion produced sulfur oxides over the oceans. We have measured the chemical and physical parameters affecting the uptake of reduced sulfur compounds, their oxidation products, ozone, and nitrogen oxides by the ocean's surface, and marine clouds, fogs, and aerosols. These parameters include: gas/surface mass accommodation coefficients; physical and chemically modified (effective) Henry's law constants; and surface and liquid phase reaction constants. These parameters are critical to understanding both the interaction of gaseous trace species with cloud and fog droplets and the deposition of trace gaseous species to dew covered, fresh water and marine surfaces.

Davidovits, P. (Boston Coll., Chestnut Hill, MA (United States). Dept. of Chemistry); Worsnop, D.W.; Zahniser, M.S.; Kolb, C.E. (Aerodyne Research, Inc., Billerica, MA (United States). Center for Chemical and Environmental Physics)

1992-02-01T23:59:59.000Z

355

Hydrogen Delivery Technologies and Systems - Pipeline Transmission...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen Hydrogen Delivery...

356

December 2006 HydrogenHydrogen PPostureosture PlanPlan  

E-Print Network [OSTI]

and improve the environment. The President urged the development of commercially viable fuel cells for cars in a fuel cell, it can power consumer products from computers to cell phones to cars that emit pure water obstacles...so that the first car driven by a child born today could be powered by hydrogen, and pollution

357

Nuclear Hydrogen Initiative  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Nuclear Research Advanced Nuclear Research Office of Nuclear Energy, Science and Technology FY 2003 Programmatic Overview Nuclear Hydrogen Initiative Nuclear Hydrogen Initiative Office of Nuclear Energy, Science and Technology Henderson/2003 Hydrogen Initiative.ppt 2 Nuclear Hydrogen Initiative Nuclear Hydrogen Initiative Program Goal * Demonstrate the economic commercial-scale production of hydrogen using nuclear energy by 2015 Need for Nuclear Hydrogen * Hydrogen offers significant promise for reduced environmental impact of energy use, specifically in the transportation sector * The use of domestic energy sources to produce hydrogen reduces U.S. dependence on foreign oil and enhances national security * Existing hydrogen production methods are either inefficient or produce

358

Mineralogical and chemical assessment of concrete damaged by the oxidation of sulfide-bearing aggregates: Importance of thaumasite formation on reaction mechanisms  

SciTech Connect (OSTI)

Damages in concrete containing sulfide-bearing aggregates were recently observed in the Trois-Rivieres area (Quebec, Canada), characterized by rapid deterioration within 3 to 5 years after construction. A petrographic examination of concrete core samples was carried out using a combination of tools including: stereomicroscopic evaluation, polarized light microscopy, scanning electron microscopy, X-ray diffraction and electron microprobe analysis. The aggregate used to produce concrete was an intrusive igneous rock with different metamorphism degrees and various proportions of sulfide minerals. In the rock, sulfide minerals were often surrounded by a thin layer of carbonate minerals (siderite). Secondary reaction products observed in the damaged concrete include 'rust' mineral forms (e.g. ferric oxyhydroxides such as goethite, limonite (FeO (OH) nH{sub 2}O) and ferrihydrite), gypsum, ettringite and thaumasite. In the presence of water and oxygen, pyrrhotite oxidizes to form iron oxyhydroxides and sulphuric acid. The acid then reacts with the phases of the cement paste/aggregate and provokes the formation of sulfate minerals. Understanding both mechanisms, oxidation and internal sulfate attack, is important to be able to duplicate the damaging reaction in laboratory conditions, thus allowing the development of a performance test for evaluating the potential for deleterious expansion in concrete associated with sulfide-bearing aggregates.

Rodrigues, A. [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada)] [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada); Duchesne, J., E-mail: josee.duchesne@ggl.ulaval.ca [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada); Fournier, B. [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada)] [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada); Durand, B. [Institut de recherche d'Hydro-Quebec (IREQ), 1740 boul. Lionel-Boulet, Varennes, QC, Canada J3X 1S1 (Canada)] [Institut de recherche d'Hydro-Quebec (IREQ), 1740 boul. Lionel-Boulet, Varennes, QC, Canada J3X 1S1 (Canada); Rivard, P. [Universite de Sherbrooke, Sherbrooke, QC, Canada J1K 2R1 (Canada)] [Universite de Sherbrooke, Sherbrooke, QC, Canada J1K 2R1 (Canada); Shehata, M. [Ryerson University, 350 Victoria Street, Toronto, ON, Canada M5B 2K3 (Canada)] [Ryerson University, 350 Victoria Street, Toronto, ON, Canada M5B 2K3 (Canada)

2012-10-15T23:59:59.000Z

359

Increasing Renewable Energy with Hydrogen Storage and Fuel Cell...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Closed loop hydrogen turbine & steam turbine, without atmospheric air, equals zero air pollution Heat Exchanger Electrolyzer produces H 2 & O 2 gases by water electrolysis...

360

Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Barriers: Hydrogen embrittlement of pipelines and remediation (mixing with water vapor?) hpwgwembrittlementsteelssofronis.pdf More Documents & Publications Webinar: I2CNER: An...

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Hydrogenases and Hydrogen Metabolism of Cyanobacteria  

Science Journals Connector (OSTI)

...lowers the potential solar energy conversion efficiencies...molecular hydrogen from solar energy and water by using...several individual projects, two major international...International Energy Agency; http...direct conversion of solar energy (114...

Paula Tamagnini; Rikard Axelsson; Pia Lindberg; Fredrik Oxelfelt; Röbbe Wünschiers; Peter Lindblad

2002-03-01T23:59:59.000Z

362

Sandia National Laboratories: accelerate hydrogen infrastructure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

have been a major water- and air-pollution source in the U.S.-but remained ... Sandia, SRI International Sign Pact to Advance Hydrogen and Natural Gas Research for...

363

Sandia National Laboratories: hydrogen fuel systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

have been a major water- and air-pollution source in the U.S.-but remained ... Sandia, SRI International Sign Pact to Advance Hydrogen and Natural Gas Research for...

364

Hydrogenases and Hydrogen Metabolism of Cyanobacteria  

Science Journals Connector (OSTI)

...wastes into valuable, energy-rich compounds such...hydrogen from solar energy and water by using a renewable process. The present...IEA (International Energy Agency; http...the European program COST (European Cooperation...

Paula Tamagnini; Rikard Axelsson; Pia Lindberg; Fredrik Oxelfelt; Röbbe Wünschiers; Peter Lindblad

2002-03-01T23:59:59.000Z

365

Generating Potable Water from Fuel Cell Technology Juan E. Tibaquir  

E-Print Network [OSTI]

with hydrogen economy scenario. 4. Research Approach and Results Survey of fuel cell water ASU lab fuel cell Capacity (kW) 5 ­ 150 5 ­ 250 5 50 ­ 1100 100 ­ 2000 100 ­ 250 PEM Fuel cell Oxygen (From air) Hydrogen Implications of Using water from Fuel Cells in a Hydrogen Economy · Hydrogen as an energy and water carrier

Keller, Arturo A.

366

Photoelectrochemical Water Splitting  

Broader source: Energy.gov [DOE]

In this process, hydrogen is produced from water using sunlight and specialized semiconductors called photoelectrochemical materials. In the photoelectrochemical (PEC) system, the semiconductor uses light energy to directly dissociate water molecules into hydrogen and oxygen. Different semiconductor materials work at particular wavelengths of light and energies.

367

Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines...  

Broader source: Energy.gov (indexed) [DOE]

Pipeline Working Group Workshop: Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines Code for Hydrogen Piping and Pipelines. B31...

368

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...  

Broader source: Energy.gov (indexed) [DOE]

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

369

Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bonded Arrays: The Power of Multiple Hydrogen Bonds. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. Abstract: Hydrogen bond interactions in small covalent model...

370

The Role of Carbon in Catalytically Stabilized Transition Metal Sulfides  

SciTech Connect (OSTI)

Since WWII considerable progress has been made in understanding the basis for the activity and the selectivity of molybdenum and tungsten based hydrotreating catalysts. Recently, the focus of investigation has turned to the structure of the catalytically stabilized active catalyst. The surface of the catalytically stabilized MoS2 has been shown to be carbided with the formula MoSxCy under hydrotreating conditions. In this paper we review the basis for this finding and present new data extending the concept to the promoted TMS (transition metal sulfides) systems CoMoC and NiMoC. Freshly sulfided CoMoS and NiMoS catalyst have a strong tendency to form the carbided surface phases from any available carbon source.

Kelty,S.; Berhault, G.; Chianelli, R.

2007-01-01T23:59:59.000Z

371

Adsorption Kinetics of Hydrogen Sulfide and Thiols on GaAs (001) Surfaces in a Vacuum  

Science Journals Connector (OSTI)

For instance, a p(2 × 2) LEED structure, achieved upon repeated exposure to thiol and annealing to 750 K,9 implies that the surface concentration of chemisorbed sulfur could reach 0.25 monolayers. ... Funding for this research was provided by the Canadian Institutes for Health Research and the Canada Research Chair Program. ...

Oleksandr Voznyy; Jan J. Dubowski

2008-02-20T23:59:59.000Z

372

PERGAMON Carbon 38 (2000) 17571765 High temperature hydrogen sulfide adsorption on activated  

E-Print Network [OSTI]

directly, as in a traditional H , 23.1% CO, 5.8% CO , 6.6% H O, 0.5% H S, and2 2 2 2 coal-fired power plant types of activated carbon sorbents were evaluated for their ability to remove H S from a simulated coal temperature was examined as a2 function of carbon surface chemistry (oxidation, thermal desorption, and metal

Cal, Mark P.

373

Crossed beam reaction of atomic carbon C(3 Pj) with hydrogen sulfide,  

E-Print Network [OSTI]

impact-induced nonequilibrium sulfur chemistry in the Jovian atmosphere, as well as combustion of sulfur of the thioformyl radical, HCS(X2 A ) R. I. Kaiser, W. Sun, and A. G. Suits Department of Chemistry, University containing coal. © 1997 American Institute of Physics. S0021-9606 97 03412-0 I. INTRODUCTION The sulfur

Kaiser, Ralf I.

374

Sulfur incorporation into copper indium diselenide single crystals through annealing in hydrogen sulfide  

SciTech Connect (OSTI)

CuInSe{sub 2} crystals were sulfurized in a H{sub 2}S-Ar gas mixture at 575 deg. C. The focus was on the resulting mass transport, in particular, on the interdiffusion of Se and S. Experiments were done for various sulfurization times, and the resulting S distribution was measured by Auger electron spectroscopy sputter depth profiling and analyzed with the Boltzmann-Matano method. A one-dimensional diffusion process had shaped the S distribution in these crystals. The respective diffusion coefficient was on the order of 10{sup -16} cm{sup 2}/s, and it varied only slightly with the S content in CuIn(Se,S){sub 2}.

Titus, Jochen; Birkmire, Robert W.; Hack, Christina; Mueller, Georg; McKeown, Patrick [Institute of Energy Conversion, University of Delaware, Newark, Delaware 19716 (United States); Crystal Growth Laboratory, Department of Materials Science, University of Erlangen-Nuernberg (Germany); Evans East, Princeton, New Jersey 08520 (United States)

2006-02-15T23:59:59.000Z

375

Hydrogen Sulfide Exposure among Oil Refinery Workers at Marathon Petroleum Company in Canton, Ohio.  

E-Print Network [OSTI]

??Air monitoring surveys were conducted during loading operations at three locations inside of Marathon Petroleum Company’s Canton, Ohio oil refinery. These three locations—the sulfur truck… (more)

Beil, Christine A

2012-01-01T23:59:59.000Z

376

Effect of Hydrogen Sulfide in Landfill Gas on Anode Poisoning of Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??The world is facing an energy crisis and there is an immediate need to find a sustainable source of energy. Landfill gas has the potential… (more)

Khan, Feroze

2012-01-01T23:59:59.000Z

377

The effect of hydrogen sulfide on straight-run gasoline during storage  

E-Print Network [OSTI]

AORICULTURAL AND MECHANICAL COLLEOE OF TEXAS COLLEGE STATION. TEXAS DEPARTMENT CP CHEMISTRY ANC CHEMICAL ENOINEERINO k+ fg QLU, er XSS4 l 5, . f ~ t ~ II%& '~ NF14eSC %%Sf, Oa 1S CL+koS4 . '45 gg%444440 %Et ~fv@8&l !a . s Thc~ for ". 4...~ ~y holptvL ~~hices 6mLag %ho e&eaduet of t: ha e~~g, ae6 4a &'~tet &i G~ '~ he &to 'a~lssbis ce%4teieae ts the yesyara@na of this eae~iy4~ X448741NA XOA o ~ o ~ e e o ~ ~ e ~ ~ e ~ ~ ~ o o ~ ~ ~ o ~ o X e %44Clem'4 o e ~ e e ~ e ~ ~ o e e...

Miller, Alvin Junius

2012-06-07T23:59:59.000Z

378

Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation  

E-Print Network [OSTI]

Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation P. Sofronis, I. M. Robertson, D% · Contractor share: 25% · Barriers ­ Hydrogen embrittlement of pipelines and remediation (mixing with water;Objectives · To come up with a mechanistic understanding of hydrogen embrittlement in pipeline steels

379

Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang*  

E-Print Network [OSTI]

Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang* Department of Biochemistry, University of Zurich, Zurich, Switzerland Abstract Ligand binding involves breakage of hydrogen bonds with water molecules and formation of new hydrogen bonds between protein and ligand. In this work, the change

Caflisch, Amedeo

380

Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila  

E-Print Network [OSTI]

Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila Sitindra S Accepted 7 September 2013 Available online 16 September 2013 a b s t r a c t Hydrogen isotope ratio values from recording the hydrogen isotope composition of ambient water, dD values of lipids also depend

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils  

SciTech Connect (OSTI)

Disclosed herein is a method of generating hydrogen from a bio-oil, comprising hydrogenating a water-soluble fraction of the bio-oil with hydrogen in the presence of a hydrogenation catalyst, and reforming the water-soluble fraction by aqueous-phase reforming in the presence of a reforming catalyst, wherein hydrogen is generated by the reforming, and the amount of hydrogen generated is greater than that consumed by the hydrogenating. The method can further comprise hydrocracking or hydrotreating a lignin fraction of the bio-oil with hydrogen in the presence of a hydrocracking catalyst wherein the lignin fraction of bio-oil is obtained as a water-insoluble fraction from aqueous extraction of bio-oil. The hydrogen used in the hydrogenating and in the hydrocracking or hydrotreating can be generated by reforming the water-soluble fraction of bio-oil.

Huber, George W; Vispute, Tushar P; Routray, Kamalakanta

2014-06-03T23:59:59.000Z

382

An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California  

E-Print Network [OSTI]

hydrogen dispenser Reverse osmosis and deionizer waterAlkaline Electrolyzer Reverse osmosis and deionizer waterhydrogen dispenser Reverse osmosis and deionizer water

Nicholas, Michael A; Ogden, J

2010-01-01T23:59:59.000Z

383

Photobiological Water Splitting  

Broader source: Energy.gov [DOE]

In this process, hydrogen is produced from water using sunlight and specialized microorganisms, such as green algae and cyanobacteria. Just as plants produce oxygen during photosynthesis, these microorganisms consume water and produce hydrogen as a byproduct of their natural metabolic processes. Photobiological water splitting is a long-term technology. Currently, the microbes split water much too slowly to be used for efficient, commercial hydrogen production. But scientists are researching ways to modify the microorganisms and to identify other naturally occurring microbes that can produce hydrogen at higher rates. Photobiological water splitting is in the very early stages of research but offers long-term potential for sustainable hydrogen production with low environmental impact.

384

Water Emissions from Fuel Cell Vehicles | Department of Energy  

Energy Savers [EERE]

Water Emissions from Fuel Cell Vehicles Water Emissions from Fuel Cell Vehicles Hydrogen fuel cell vehicles (FCVs) emit approximately the same amount of water per mile as vehicles...

385

Water Emissions from Fuel Cell Vehicles | Department of Energy  

Energy Savers [EERE]

Fuel Cells Water Emissions from Fuel Cell Vehicles Water Emissions from Fuel Cell Vehicles Hydrogen fuel cell vehicles (FCVs) emit approximately the same amount of water per...

386

Hydrogen from Coal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Coal Coal Edward Schmetz Office of Sequestration, Hydrogen and Clean Coal Fuels U.S. Department of Energy DOE Workshop on Hydrogen Separations and Purification Technologies September 8, 2004 Presentation Outline ƒ Hydrogen Initiatives ƒ Hydrogen from Coal Central Production Goal ƒ Why Coal ƒ Why Hydrogen Separation Membranes ƒ Coal-based Synthesis Gas Characteristics ƒ Technical Barriers ƒ Targets ƒ Future Plans 2 3 Hydrogen from Coal Program Hydrogen from Coal Program FutureGen FutureGen Hydrogen Fuel Initiative Hydrogen Fuel Initiative Gasification Fuel Cells Turbines Gasification Fuel Cells Turbines Carbon Capture & Sequestration Carbon Capture & Sequestration The Hydrogen from Coal Program Supports the Hydrogen Fuel Initiative and FutureGen * The Hydrogen Fuel Initiative is a $1.2 billion RD&D program to develop hydrogen

387

Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes &  

E-Print Network [OSTI]

Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure)DescriptionMilestone #12;Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes & Standards #12;Hydrogen Codes & Standards: Goal & Objectives Goal

388

HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM  

E-Print Network [OSTI]

to serve as "go-to" organization to catalyze PA Hydrogen and Fuel Cell Economy development #12;FundingHYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA Melissa Klingenberg, PhDMelissa Klingenberg, PhD #12;Hydrogen ProgramHydrogen Program Air Products

389

Hydrogen Vehicles and Refueling Infrastructure in India  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

HYDROGEN VEHICLES AND FUELLING HYDROGEN VEHICLES AND FUELLING INFRASTRUCTURE IN INDIA Prof. L. M. Das Centre for Energy Studies Indian Institute of Technology Delhi INDIA " The earth was not given to us by our parents , it has been loaned to us by our children" Kenyan Proverb Same feeling exists in all societies Our moral responsibility---to handover a safer earth to future generation IIT Delhi August 18, 2004 -:Hydrogen:- Not a Radically New Concept JULES VERNE Mysterious Island (1876) ...." I believe that water will one day be employed as fuel, that hydrogen and oxygen which constitute it, used singly or together will furnish an inexhaustible source of heat and light of an intensity of which coal is not capable.........water will be coal of the future" IIT Delhi August 18, 2004 Source: T. Nejat Veziroglu , Hydrogen Energy Technologies, UNIDO

390

Ring size and strain as a control of reaction selectivity: ethylene sulfide on Mo(110)  

SciTech Connect (OSTI)

The adsorption and reaction of sulfur-containing organic on single-crystal transition-metal surfaces form a subject of current to the authors and others. The primary focus of their work is an investigation of how thermodynamic properties of adsorbate molecules affect the mechanism(s) by which they react. To this end, they have studied the reactions of two saturated cyclic sulfides-trimethylene sulfide (c-C/sub 3/H/sub 6/S) and tetrahydrothiophene (c-C/sub 4/H/sub 8/S)--on Mo(110). On the basis of these studies they proposed that ring strain in the cyclic sulfide controls reaction selectivity on Mo(110). This work concerns the reactions of a third cyclic sulfide, ethylene sulfide (c-C/sub 2/H/sub 4/S), on Mo(110). The results presented here demonstrate that ring size as well as ring strain determines the reaction selectivity of cyclic sulfides on Mo(110).

Roberts, J.T.; Friend, C.M.

1987-12-09T23:59:59.000Z

391

Hydrogen Storage Experiments for an Undergraduate Laboratory Course—Clean Energy: Hydrogen/Fuel Cells  

Science Journals Connector (OSTI)

Hydrogen Storage Experiments for an Undergraduate Laboratory Course—Clean Energy: Hydrogen/Fuel Cells ... Global interest in both renewable energies and reduction in emission levels has placed increasing attention on hydrogen-based fuel cells that avoid harm to the environment by releasing only water as a byproduct. ... First-Year Undergraduate/General; Green Chemistry; Laboratory Instruction; Environmental Chemistry; Hands-On Learning/Manipulatives; Applications of Chemistry; Electrolytic/Galvanic Cells/Potentials ...

Alla Bailey; Lisa Andrews; Ameya Khot; Lea Rubin; Jun Young; Thomas D. Allston; Gerald A. Takacs

2014-12-09T23:59:59.000Z

392

Solar-hydrogen energy system for Pakistan  

SciTech Connect (OSTI)

A solar-hydrogen energy system has been proposed for Pakistan as the best replacement for the present fossil fuel based energy system. It has been suggested to produce hydrogen via photovoltaic-electrolysis, utilizing the available non-agricultural sunny terrain in Baluchistan region. There will be a desalination plant for sea water desalination. The area under the photovoltaic panels with the availability of water would provide suitable environment for growing some cash crops. This would change the cast useless desert land into green productive farms. In order to show the quantitative benefits of the proposed system, future trends of important energy and economical parameters have been studied with and without hydrogen introduction. The following parameters have been included: population, energy demand (fossil + hydrogen), energy production (fossil + hydrogen), gross national product, fossil energy imports, world energy prices, air pollution, quality of life, environmental savings due to hydrogen introduction, savings due to the higher utilization efficiency of hydrogen, by-product credit, agricultural income, income from hydrogen sale, photovoltaic cell area, total land area, water desalination plant capacity, capital investment, operating and maintenance cost, and total income from the system. The results indicate that adopting the solar-hydrogen energy system would eliminate the import dependency of fossil fuels, increase gross product per capita, reduce pollution, improve quality of life and establish a permanent and clean energy system. The total annual expenditure on the proposed system is less than the total income from the proposed system. The availability of water, the cash crop production, electricity and hydrogen would result in rapid development of Baluchistan, the largest province of Pakistan.

Lutfi, N.

1990-01-01T23:59:59.000Z

393

THE WEATHERING OF A SULFIDE OREBODY: SPECIATION AND FATE OF SOME POTENTIAL CONTAMINANTS  

SciTech Connect (OSTI)

Various potentially toxic trace elements such as As, Cu, Pb and Zn have been remobilized by the weathering of a sulfide orebody that was only partially mined at Leona Heights, California. As a result, this body has both natural and anthropogenically modified weathering profiles only 500 m apart. The orebody is located in a heavily urbanized area in suburban Oakland, and directly affects water quality in at least one stream by producing acidic conditions and relatively high concentrations of dissolved elements (e.g., {approx}500 mg/L Cu, {approx}3700 mg/L Zn). Micrometric-scale mineralogical investigations were performed on the authigenic metal-bearing phases (less than 10 {mu}m in size) using electron-probe micro-analysis (EPMA), micro-Raman, micro X-ray absorption spectroscopy (mXAS), scanning X-ray diffraction (mSXRD) and scanning X-ray fluorescence (mSXRF) mapping techniques. Those measurements were coupled with classical mineralogical laboratory techniques, X-ray diffraction (XRD) and scanning electron microscopy (SEM). Authigenic metal-bearing phases identified are mainly sulfates (jarosite, epsomite, schwertmannite), Fe (oxy-)hydroxides (goethite, hematite and poorly crystalline Fe products) and poorly crystalline Mn (hydr-)oxides. Sulfates and Fe (oxy-)hydroxides are the two main secondary products at both sites, whereas Mn (hydr-) oxides were only observed in the samples from the non-mining site. In these samples, the various trace elements show different affinities for Fe or Mn compounds. Lead is preferentially associated with Mn (hydr-)oxides and As with Fe (oxy-)hydroxides or sulfates. Copper association with Mn and Fe phases is questionable, and the results obtained rather indicate that Cu is present as individual Cu-rich grains (Cu hydroxides). Some ochreous precipitates were found at both sites and correspond to a mixture of schwertmannite, goethite and jarosite containing some potentially toxic trace elements such as Cu, Pb and Zn. According to the trace element distribution and relative abundance of the unweathered sulfides, this orebody still represents a significant reservoir of potential contaminants for the watershed, especially in the non-mining site, as a much greater proportion of sulfides is left to react and because of the lower porosity in this site.

Courtin-Nomade, Alexandra; Grosbois, Cecile; Marcus, Matthew A.; Fakra, Sirine C.; Beny, Jean Michel; Foster, Andrea L.

2010-07-16T23:59:59.000Z

394

Quantum cascade laser spectrometer for trace-gas detection of exhaled Carbonyl Sulfide  

Science Journals Connector (OSTI)

Simultaneous concentration measurements of exhaled carbonyl sulfide and carbon dioxide were demonstrated using a pulsed quantum cascade laser based gas sensor. This sensor has...

Wysocki, Gerard; So, Stephen; McCurdy, Matt; Roller, Chad; Weidmann, Damien; Kosterev, Anatoliy a; Frantz, J Patrick; Curl, Robert F; Tittel, Frank K

395

E-Print Network 3.0 - antimony sulfide thin Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The strata-bound, sulfide- and ... Source: USGS Western Region Coastal and Marine Geology Collection: Geosciences 77 Experimental partitioning of uranium between liquid...

396

Hydrogen Dissociation on Pd4S Surfaces  

SciTech Connect (OSTI)

Exposure of Pd-based hydrogen purification membranes to H,S. a common contaminant in coal gasification streams, can cause membrane performance to deteriorate, either by deactivating surface sites required for dissociative H, adsorption or by forming a low-permeability sulfide scale. In this work. the composition, structure, and catalytic activity of Pd4S, a surface scale commonly observed in Pd-membrane separation of hydrogen from sulfur-containing gas streams, were examined using a combination of experimental characterization and density functional theory (DFT) calculations. A Pd,S sample was prepared by exposing a 100 f1m Pd foil to H2S at 908 K. Both X-ray photoemission depth profiling and low energy ion scattering spectroscopic (LEISS) analysis reveal slight sulfur-enrichment of the top surface of the sample. This view is consistent with the predictions of DFT atomistic thermodynamic calculations. which identified S-terminated Pd,S surfaces as energetically favored over corresponding Pd-terminated surfaces. Activation barriers for H2 dissociation on the Pd,S surfaces were calculated. Although barriers are higher than on Pd(lll). transition state theory analysis identified reaction pathways on the S-terminated surfaces for which hydrogen dissociation rates are high enough to sustain the separation process at conditions relevant to gasification applications.

Miller, J.B.; Alfonso, D.R.; Howard, B.H.; O'Brien, C.P.; Morreale, B.D.

2009-01-01T23:59:59.000Z

397

Hydrogen Production from Nuclear Energy via High Temperature Electrolysis  

SciTech Connect (OSTI)

This paper presents the technical case for high-temperature nuclear hydrogen production. A general thermodynamic analysis of hydrogen production based on high-temperature thermal water splitting processes is presented. Specific details of hydrogen production based on high-temperature electrolysis are also provided, including results of recent experiments performed at the Idaho National Laboratory. Based on these results, high-temperature electrolysis appears to be a promising technology for efficient large-scale hydrogen production.

James E. O'Brien; Carl M. Stoots; J. Stephen Herring; Grant L. Hawkes

2006-04-01T23:59:59.000Z

398

FCT Hydrogen Production: Basics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Basics to someone by E-mail Basics to someone by E-mail Share FCT Hydrogen Production: Basics on Facebook Tweet about FCT Hydrogen Production: Basics on Twitter Bookmark FCT Hydrogen Production: Basics on Google Bookmark FCT Hydrogen Production: Basics on Delicious Rank FCT Hydrogen Production: Basics on Digg Find More places to share FCT Hydrogen Production: Basics on AddThis.com... Home Basics Central Versus Distributed Production Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Basics Photo of hydrogen production in photobioreactor Hydrogen, chemical symbol "H", is the simplest element on earth. An atom of hydrogen has only one proton and one electron. Hydrogen gas is a diatomic

399

The Transition to Hydrogen  

E-Print Network [OSTI]

above, not all hydrogen production methods are equal inrealize hydrogen’s bene- ?ts fully, production methods thathydrogen vary depending on which primary source produces it and which production method

Ogden, Joan M

2005-01-01T23:59:59.000Z

400

The Hydrogen Economy  

Science Journals Connector (OSTI)

The hydrogen economy is a vision for a future in which hydrogen replaces fossil fuels. There are a variety ... of methods for generating, storing and delivering hydrogen since no single method has yet proven supe...

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Hydrogen storage methods  

Science Journals Connector (OSTI)

Hydrogen exhibits the highest heating value per mass of all chemical fuels. Furthermore, hydrogen is regenerative and environmentally friendly. There are two reasons why hydrogen is not the major fuel of today’s ...

Andreas Züttel

2004-04-01T23:59:59.000Z

402

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September byet al. , 1988,1989 HYDROGEN FUEL-CELL VEHICLES: TECHNICALIn the FCEV, the hydrogen fuel cell could supply the "net"

Delucchi, Mark

1992-01-01T23:59:59.000Z

403

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

for the hydrogen refueling station. Compressor cost: inputcost) Compressor power requirement: input data 288.80 Initial temperature of hydrogen (Compressor cost per unit of output ($/hp/million standard ft [SCF] of hydrogen/

Delucchi, Mark

1992-01-01T23:59:59.000Z

404

Measurement of gas/water uptake coefficients for trace gases active in the marine environment. [Annual report  

SciTech Connect (OSTI)

Ocean produced reduced sulfur compounds including dimethylsulfide (DMS), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}CH) and carbonyl sulfide (OCS) deliver a sulfur burden to the atmosphere which is roughly equal to sulfur oxides produced by fossil fuel combustion. These species and their oxidation products dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}) and methane sulfonic acid (MSA) dominate aerosol and CCN production in clean marine air. Furthermore, oxidation of reduced sulfur species will be strongly influenced by NO{sub x}/O{sub 3} chemistry in marine atmospheres. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion produced sulfur oxides over the oceans. We have measured the chemical and physical parameters affecting the uptake of reduced sulfur compounds, their oxidation products, ozone, and nitrogen oxides by the ocean`s surface, and marine clouds, fogs, and aerosols. These parameters include: gas/surface mass accommodation coefficients; physical and chemically modified (effective) Henry`s law constants; and surface and liquid phase reaction constants. These parameters are critical to understanding both the interaction of gaseous trace species with cloud and fog droplets and the deposition of trace gaseous species to dew covered, fresh water and marine surfaces.

Davidovits, P. [Boston Coll., Chestnut Hill, MA (United States). Dept. of Chemistry; Worsnop, D.W.; Zahniser, M.S.; Kolb, C.E. [Aerodyne Research, Inc., Billerica, MA (United States). Center for Chemical and Environmental Physics

1992-02-01T23:59:59.000Z

405

Anti-reflective nanoporous silicon for efficient hydrogen production  

DOE Patents [OSTI]

Exemplary embodiments are disclosed of anti-reflective nanoporous silicon for efficient hydrogen production by photoelectrolysis of water. A nanoporous black Si is disclosed as an efficient photocathode for H.sub.2 production from water splitting half-reaction.

Oh, Jihun; Branz, Howard M

2014-05-20T23:59:59.000Z

406

Solar-Thermal ALD Ferrite-Based Water Splitting Cycle - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 4 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Alan W. Weimer (Primary Contact), Darwin Arifin, Xinhua Liang, Victoria Aston and Paul Lichty University of Colorado Campus Box 596 Boulder, CO 80309-0596 Phone: (303) 492-3759 Email: alan.weimer@colorado.edu DOE Manager HQ: Sara Dillich Phone: (202) 586-7925 Email: Sara.Dillich@ee.doe.gov Contract Number: DE-FC36-05GO15044 Project Start Date: March 31, 2005 Project End Date: Project continuation and direction determined annually by DOE Fiscal Year (FY) 2012 Objectives Demonstrate the "hercynite cycle" feasibility for * carrying out redox. Initiate design, synthesis and testing of a nanostructured * active material for fast kinetics and transport.

407

Hour-by-Hour Cost Modeling of Optimized Central Wind-Based Water Electrolysis Production - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Genevieve Saur (Primary Contact), Chris Ainscough. National Renewable Energy Laboratory (NREL) 15013 Denver West Parkway Golden, CO 80401-3305 Phone: (303) 275-3783 Email: genevieve.saur@nrel.gov DOE Manager HQ: Erika Sutherland Phone: (202) 586-3152 Email: Erika.Sutherland@ee.doe.gov Project Start Date: October 1, 2010 Project End Date: Project continuation and direction determined annually by DOE Fiscal Year (FY) 2012 Objectives Corroborate recent wind electrolysis cost studies using a * more detailed hour-by-hour analysis. Examine consequences of different system configuration * and operation for four scenarios, at 42 sites in five

408

Solar High-Temperature Water Splitting Cycle with Quantum Boost - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9 9 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Robin Taylor (Primary Contact), Roger Davenport, David Genders 1 , Peter Symons 1 , Lloyd Brown 2 , Jan Talbot 3 , Richard Herz 3 Science Applications International, Corp. (SAIC) 10210 Campus Point Drive San Diego, CA 92121 Phone: (858) 826-9124 Email: taylorro@saic.com 1 Electrosynthesis Co., Inc. (ESC) 2 Thermochemical Engineering Solutions (TCHEME) 3 University of California, San Diego (UCSD) DOE Managers HQ: Sara Dillich Phone: (202) 586-7925 Email: Sara.Dillich@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FG36-07GO17002 Subcontractors: * Electrosynthesis Co., Inc., Lancaster, NY * Thermochemical Engineering Solutions, San Diego, CA

409

Hydrogen Permeation Barrier Coatings  

SciTech Connect (OSTI)

Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

Henager, Charles H.

2008-01-01T23:59:59.000Z

410

Technology: Hydrogen and hydrates  

Science Journals Connector (OSTI)

... . 2249–2258 (2004). US Department of Energy Hydrogen Posture Plan http://www.eere.energy.gov/hydrogenandfuelcells/pdfs/hydrogen_posture_plan.pdf Kuhs, W. F. , Genov, ...

Ferdi Schüth

2005-04-06T23:59:59.000Z

411

Hydrogen Pipeline Working Group  

Broader source: Energy.gov [DOE]

The Hydrogen Pipeline Working Group of research and industry experts focuses on issues related to the cost, safety, and reliability of hydrogen pipelines. Participants represent organizations...

412

Hydrogen and fuel taxation.  

E-Print Network [OSTI]

??The competitiveness of hydrogen depends on how it is integrated in the energy tax system in Europe. This paper addresses the competitiveness of hydrogen and… (more)

Hansen, Anders Chr.

2007-01-01T23:59:59.000Z

413

CAN HYDROGEN WIN?: EXPLORING SCENARIOS FOR HYDROGEN  

E-Print Network [OSTI]

such as biofuel plug-in hybrids, but did well when biofuels were removed or priced excessively. Hydrogen fuel cells failed unless costs were assumed to descend independent of demand. However, hydrogen vehicles were; Hydrogen as fuel -- Economic aspects; Technological innovations -- Environmental aspects; Climatic changes

414

Summary of research on hydrogen production from fossil fuels conducted at NETL  

SciTech Connect (OSTI)

In this presentation we will summarize the work performed at NETL on the production of hydrogen via partial oxidation/dry reforming of methane and catalytic decomposition of hydrogen sulfide. We have determined that high pressure resulted in greater carbon formation on the reforming catalysts, lower methane and CO2 conversions, as well as a H2/CO ratio. The results also showed that Rh/alumina catalyst is the most resistant toward carbon deposition both at lower and at higher pressures. We studied the catalytic partial oxidation of methane over Ni-MgO solid solutions supported on metal foams and the results showed that the foam-supported catalysts reach near-equilibrium conversions of methane and H2/CO selectivities. The rates of carbon deposition differ greatly among the catalysts, varying from 0.24 mg C/g cat h for the dipped foams to 7.0 mg C/g cat h for the powder-coated foams, suggesting that the exposed Cr on all of the foam samples may interact with the Ni-MgO catalyst to kinetically limit carbon formation. Effects of sulfur poisoning on reforming catalysts were studies and pulse sulfidation of catalyst appeared to be reversible for some of the catalysts but not for all. Under pulse sulfidation conditions, the 0.5%Rh/alumina and NiMg2Ox-1100ºC (solid solution) catalysts were fully regenerated after reduction with hydrogen. Rh catalyst showed the best overall activity, less carbon deposition, both fresh and when it was exposed to pulses of H2S. Sulfidation under steady state conditions significantly reduced catalyst activity. Decomposition of hydrogen sulfide into hydrogen and sulfur was studied over several supported metal oxides and metal oxide catalysts at a temperature range of 650-850°C. H2S conversions and effective activation energies were estimated using Arrhenius plots. The results of these studies will further our understanding of catalytic reactions and may help in developing better and robust catalysts for the production of hydrogen from fossil fuels

Shamsi, Abolghasem

2008-03-30T23:59:59.000Z

415

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel method for preparing a hydrogenation composition comprising organic polymer molecules having carbon--carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces and particularly from atmospheres within enclosed spaces that contain air, water vapor, oxygen, carbon dioxide or ammonia. The organic polymers molecules containing carbon--carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble noble metal catalyst composition. High molecular weight polymers may be added to the organic polymer/catalyst mixture in order to improve their high temperature performance. The hydrogenation composition is prepared by dispersing the polymers in a suitable solvent, forming thereby a solution suspension, flash-freezing droplets of the solution in a liquid cryogen, freeze-drying the frozen droplets to remove frozen solvent incorporated in the droplets, and recovering the dried powder thus formed.

Shepodd, Timothy J. (330 Thrasher Ave., Livermore, CA 94550); Even, Jr., William R. (4254 Drake Way, Livermore, CA 94550)

2000-01-01T23:59:59.000Z

416

Solar hydrogen production using Ce{sub 1-x}Li{sub x}O{sub 2-{delta}} solid solutions via a thermochemical, two-step water-splitting cycle  

SciTech Connect (OSTI)

The reactivity of Ce{sub 1-x}Li{sub x}O{sub 2-{delta}} (x=0.025, 0.05, 0.075 and 0.1) solid solutions during the redox and two-step water-splitting cycles has been investigated in this work. Thermogravimetric analysis (TGA), X-ray diffraction (XRD) patterns and field-emission scanning electron microscopy (FE-SEM) indicate that there are two reaction mechanisms in the O{sub 2}-releasing step and the shift in the reaction mechanisms occurs in the O{sub 2}-releasing step because of sintering at high temperatures, and a decrease in the concentration of lattice oxygen occurs as the O{sub 2}-releasing step proceeds. The reaction in the O{sub 2}-releasing step follows a second-order mechanism over a temperature range of 1000-1170 Degree-Sign C and a contracting-area model over a temperature range of 1170-1500 Degree-Sign C. According to direct gas mass spectroscopy (DGMS), ceria doped at 5 mol% Li exhibits the highest reactivity in the O{sub 2}-releasing step during both redox cycles in air and two-step water-splitting cycles, whereas ceria doped at 2.5 mol% Li yields the highest amount of hydrogen (4.79 ml/g) in the H{sub 2}-generation step during the two-step water-splitting cycles, which is higher than ceria doped with other metals. DGMS and electrochemical impedance spectroscopy (EIS) suggest that the average reaction rate in the H{sub 2}-generation step is influenced by the concentration of extrinsic oxygen vacancies, and thus, the reactivity in the H{sub 2}-generation step, to some degree, could be tuned by varying the concentration of extrinsic oxygen vacancies (Li content). - Graphical abstract: Average reduction fraction of Ce{sub 1-x}Li{sub x}O{sub 2-{delta}} (x=0.025, 0.05, 0.075 and 0.10) solid solutions versus Li content in the O{sub 2}-releasing step during the redox cycles in air and the two-step water-splitting cycles. Highlights: Black-Right-Pointing-Pointer We have investigated Li-doped ceria for hydrogen production using two-step water-splitting cycles. Black-Right-Pointing-Pointer The sintering effect on the reaction mechanisms was first clarified. Black-Right-Pointing-Pointer The shift of reaction mechanisms occurs during the O{sub 2}-releasing step. Black-Right-Pointing-Pointer The reaction-mechanism shift occurs because of sintering at high temperatures. Black-Right-Pointing-Pointer Doping at 2.5 mol% Li results in the highest H{sub 2} yield and cyclability for hydrogen production.

Meng, Qing-Long; Lee, Chong-il; Shigeta, Satoshi [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)] [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan); Kaneko, Hiroshi [Solutions Research Laboratory, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)] [Solutions Research Laboratory, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan); Tamaura, Yutaka, E-mail: ytamaura@chem.titech.ac.jp [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)] [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)

2012-10-15T23:59:59.000Z

417

Synthesis of Longtime Water/Air-Stable Ni Nanoparticles and Their High Catalytic Activity for Hydrolysis of Ammonia?Borane for Hydrogen Generation  

Science Journals Connector (OSTI)

Soluble starch (amylose), a renewable polymer, is the main component of starch which is the main energy reserve of all higher plants, and can form a dispersion in water. ... The TEM samples were prepared by depositing one or two droplets of the nanoparticle suspensions onto the amorphous carbon coated copper grids, which were dried in argon atmosphere. ... Nitrogen sorption measurements were carried out on an automatic volumetric adsorption equipment (BEL mini, Japan) using the Brunauer?Emmett?Teller (BET) method to test the surface areas of the in situ synthesized catalysts with/without starch after washing with water and vacuum drying at 90 °C. ...

Jun-Min Yan; Xin-Bo Zhang; Song Han; Hiroshi Shioyama; Qiang Xu

2009-07-09T23:59:59.000Z

418

Hydrogen Pipeline Discussion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

praxair.com praxair.com Copyright © 2003, Praxair Technology, Inc. All rights reserved. Hydrogen Pipeline Discussion BY Robert Zawierucha, Kang Xu and Gary Koeppel PRAXAIR TECHNOLOGY CENTER TONAWANDA, NEW YORK DOE Hydrogen Pipeline Workshop Augusta, GA August 2005 2 Introduction Regulatory and technical groups that impact hydrogen and hydrogen systems ASME, DOE, DOT etc, Compressed Gas Association activities ASTM TG G1.06.08 Hydrogen pipelines and CGA-5.6 Selected experience and guidance Summary and recommendations 3 CGA Publications Pertinent to Hydrogen G-5: Hydrogen G-5.3: Commodity Specification for Hydrogen G-5.4: Standard for Hydrogen Piping at Consumer Locations G-5.5: Hydrogen Vent Systems G-5.6: Hydrogen Pipeline Systems (IGC Doc 121/04/E) G-5.7: Carbon Monoxide and Syngas

419

Hydrogen | Open Energy Information  

Open Energy Info (EERE)

<-- Back to Hydrogen Gateway <-- Back to Hydrogen Gateway Technical Reference for Hydrogen Compatibility of Materials KIA FCEV SUNRISE MG 7955 6 7.jpg Guidance on materials selection for hydrogen service is needed to support the deployment of hydrogen as a fuel as well as the development of codes and standards for stationary hydrogen use, hydrogen vehicles, refueling stations, and hydrogen transportation. Materials property measurement is needed on deformation, fracture and fatigue of metals in environments relevant to this hydrogen economy infrastructure. The identification of hydrogen-affected material properties such as strength, fracture resistance and fatigue resistance are high priorities to ensure the safe design of load-bearing structures. To support the needs of the hydrogen community, Sandia National

420

Requirements for low cost electricity and hydrogen fuel production from multi-unit intertial fusion energy plants with a shared driver and target factory  

E-Print Network [OSTI]

hydrogen fuel by electrolysis meeting equal consumer costhydrogen fuel production by water electrolysis to provide lower fuel costFig. 2: Cost hydrogen bywater of (Coil) electrolysis as

Logan, B. Grant; Moir, Ralph; Hoffman, Myron A.

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Overview of interstate hydrogen pipeline systems.  

SciTech Connect (OSTI)

The use of hydrogen in the energy sector of the United States is projected to increase significantly in the future. Current uses are predominantly in the petroleum refining sector, with hydrogen also being used in the manufacture of chemicals and other specialized products. Growth in hydrogen consumption is likely to appear in the refining sector, where greater quantities of hydrogen will be required as the quality of the raw crude decreases, and in the mining and processing of tar sands and other energy resources that are not currently used at a significant level. Furthermore, the use of hydrogen as a transportation fuel has been proposed both by automobile manufacturers and the federal government. Assuming that the use of hydrogen will significantly increase in the future, there would be a corresponding need to transport this material. A variety of production technologies are available for making hydrogen, and there are equally varied raw materials. Potential raw materials include natural gas, coal, nuclear fuel, and renewables such as solar, wind, or wave energy. As these raw materials are not uniformly distributed throughout the United States, it would be necessary to transport either the raw materials or the hydrogen long distances to the appropriate markets. While hydrogen may be transported in a number of possible forms, pipelines currently appear to be the most economical means of moving it in large quantities over great distances. One means of controlling hydrogen pipeline costs is to use common rights-of-way (ROWs) whenever feasible. For that reason, information on hydrogen pipelines is the focus of this document. Many of the features of hydrogen pipelines are similar to those of natural gas pipelines. Furthermore, as hydrogen pipeline networks expand, many of the same construction and operating features of natural gas networks would be replicated. As a result, the description of hydrogen pipelines will be very similar to that of natural gas pipelines. The following discussion will focus on the similarities and differences between the two pipeline networks. Hydrogen production is currently concentrated in refining centers along the Gulf Coast and in the Farm Belt. These locations have ready access to natural gas, which is used in the steam methane reduction process to make bulk hydrogen in this country. Production centers could possibly change to lie along coastlines, rivers, lakes, or rail lines, should nuclear power or coal become a significant energy source for hydrogen production processes. Should electrolysis become a dominant process for hydrogen production, water availability would be an additional factor in the location of production facilities. Once produced, hydrogen must be transported to markets. A key obstacle to making hydrogen fuel widely available is the scale of expansion needed to serve additional markets. Developing a hydrogen transmission and distribution infrastructure would be one of the challenges to be faced if the United States is to move toward a hydrogen economy. Initial uses of hydrogen are likely to involve a variety of transmission and distribution methods. Smaller users would probably use truck transport, with the hydrogen being in either the liquid or gaseous form. Larger users, however, would likely consider using pipelines. This option would require specially constructed pipelines and the associated infrastructure. Pipeline transmission of hydrogen dates back to late 1930s. These pipelines have generally operated at less than 1,000 pounds per square inch (psi), with a good safety record. Estimates of the existing hydrogen transmission system in the United States range from about 450 to 800 miles. Estimates for Europe range from about 700 to 1,100 miles (Mohipour et al. 2004; Amos 1998). These seemingly large ranges result from using differing criteria in determining pipeline distances. For example, some analysts consider only pipelines above a certain diameter as transmission lines. Others count only those pipelines that transport hydrogen from a producer to a customer (e.g., t

Gillette, J .L.; Kolpa, R. L

2008-02-01T23:59:59.000Z

422

Hydrogen energy  

Science Journals Connector (OSTI)

...present-day petrol-driven car engines. When heat...combined heat and power (CHP) systems...most of their output power range. This scalability...decentralized stationary power generation. Fuel...fuel cells emit only water and have virtually...battery-driven electric cars, because the chemical...

2007-01-01T23:59:59.000Z

423

Theoretical Design by First Principles Molecular Dynamics of a Bioinspired Electrode?Catalyst System for Electrocatalytic Hydrogen Production from Acidified Water  

Science Journals Connector (OSTI)

Our study is based on Car?Parrinello (CP)(26) FPMD simulations of the [FeFe]H cluster in a liquid-water environment with or without hydronium ions. ... To achieve these results, we have employed the first principles molecular dynamics method at an advanced level of system complexity and have illustrated thereby the utility and power of FPMD for molecular design. ...

Federico Zipoli; Roberto Car; Morrel H. Cohen; Annabella Selloni

2010-09-29T23:59:59.000Z

424

Hydrogen production using single-chamber membrane-free microbial electrolysis cells  

E-Print Network [OSTI]

efficiencies of hydrogen fuel cells in converting hydrogen to electricity. The development of advancedHydrogen production using single-chamber membrane-free microbial electrolysis cells Hongqiang Hu., Hydrogen production using single-chamber membrane-free microbial electrol- ysis cells, Water Research (2008

Tullos, Desiree

425

Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents [OSTI]

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

Natesan, K.; Baxter, D.J.

1983-07-26T23:59:59.000Z

426

DOE Permitting Hydrogen Facilities: Hydrogen Fueling Stations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stations Stations Public-use hydrogen fueling stations are very much like gasoline ones. In fact, sometimes, hydrogen and gasoline cars can be fueled at the same station. These stations offer self-service pumps, convenience stores, and other services in high-traffic locations. Photo of a Shell fueling station showing the site convenience store and hydrogen and gasoline fuel pumps. This fueling station in Washington, D.C., provides drivers with both hydrogen and gasoline fuels Many future hydrogen fueling stations will be expansions of existing fueling stations. These facilities will offer hydrogen pumps in addition to gasoline or natural gas pumps. Other hydrogen fueling stations will be "standalone" operations. These stations will be designed and constructed to

427

Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report  

E-Print Network [OSTI]

or hydro-powered water electrolysis. Ammonia as a HydrogenV for conventional water electrolysis (Cooper and Botte,electricity required for water electrolysis under standard

Lipman, Tim; Shah, Nihar

2007-01-01T23:59:59.000Z

428

Hydrogen & Our Energy Future  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Program Hydrogen Program www.hydrogen.energy.gov Hydrogen & Our Energy Future  | HydrOgEn & Our EnErgy FuturE U.S. Department of Energy Hydrogen Program www.hydrogen.energy.gov u.S. department of Energy |  www.hydrogen.energy.gov Hydrogen & Our Energy Future Contents Introduction ................................................... p.1 Hydrogen - An Overview ................................... p.3 Production ..................................................... p.5 Delivery ....................................................... p.15 Storage ........................................................ p.19 Application and Use ........................................ p.25 Safety, Codes and Standards ............................... p.33

429

Sulfur isotope and trace element data from ore sulfides in the Noranda district (Abitibi, Canada): implications for volcanogenic massive sulfide deposit genesis  

Science Journals Connector (OSTI)

We examine models for volcanogenic massive sulfide (VMS) mineralization in the ~2.7-Ga Noranda camp, Abitibi subprovince, Superior Province, Canada, using a combination of multiple sulfur isotope and trace ele...

Elizabeth R. Sharman; Bruce E. Taylor; William G. Minarik…

2014-10-01T23:59:59.000Z

430

Hydrogen Compatibility of Materials  

Broader source: Energy.gov [DOE]

Presentation slides from the Energy Department webinar, Hydrogen Compatibility of Materials, held August 13, 2013.

431

Hydrogen Delivery Liquefaction & Compression  

E-Print Network [OSTI]

Hydrogen Delivery Liquefaction & Compression Raymond Drnevich Praxair - Tonawanda, NY Strategic Initiatives for Hydrogen Delivery Workshop - May 7, 2003 #12;2 Agenda Introduction to Praxair Hydrogen Liquefaction Hydrogen Compression #12;3 Praxair at a Glance The largest industrial gas company in North

432

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

433

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

434

Production of elemental sulfur and ammonium thiosulfate by the oxidation of H2S containing water vapor and ammonia over V/Zr-PILC catalysts  

Science Journals Connector (OSTI)

The catalytic oxidation of hydrogen sulfide in the presence of water and ammonia was studied over V2O5 supported on Zr-pillared clay catalysts (V/Zr-PILCs). The synthesized catalysts were examined using a variety of characterization techniques. A catalytic performance study using V/Zr-PILC catalysts showed that H2S was successfully converted to elemental sulfur and ammonium thiosulfate (ATS) without considerable emission of sulfur dioxide. The H2S conversion over V/Zr-PILCs increased with increasing the content of vanadia up to 6 wt.%. This superior catalytic performance might be related to the uniform dispersion of vanadia species on the Zr-PILC support.

Kanattukara Vijayan Bineesh; Moon-il Kim; Goo-Hwa Lee; Manickam Selvaraj; Kyu Hyun; Dae-Won Park

2012-01-01T23:59:59.000Z

435

Chapter 4 - Hydrogen and Fuel Cell Systems  

Science Journals Connector (OSTI)

Abstract In this chapter, hydrogen and fuel cell systems are introduced. Hydrogen is closely related to fuel cells because fuel cells are very efficient devices for power generation which when supplied with hydrogen generate non-polluting effluents, mainly water or steam. A hydrogen economy is necessary in the context of continuous growth of population and per-capita energy consumption. In this context, renewable energy solutions—especially solar—become more important and their harvesting requires hydrogen as energy carrier. Therefore the role of hydrogen and fuel cell systems in power generation becomes very important. As detailed in the chapter, these systems are useful for converting the fluctuating and intermittent energy of renewable sources and providing power on demand. Hydrogen and fuel cell systems can work either as grid-connected or as independent power generators. Connection to the grid allows for better load leveling and major savings as well as for reduction of pollution associated with power generation. Hydrogen can also be used to power residences and to cogenerate heat or other commodities. In addition, hydrogen and fuel cell technologies are much required for the transportation sector, where they can contribute to pollution and cost reduction and increased efficiency. Hydrogen production methods are reviewed in this chapter with a focus on electrolysis and thermochemical cycles. These systems appear to be leading technologies for the future. Other revised hydrogen production methods are gasification and reforming, which are very relevant for biomass conversion into hydrogen. Photochemical and photo-biochemical hydrogen production methods are also discussed. All types of fuel cells are introduced; these include alkaline, proton-exchange-membrane, phosphoric acid, molten carbonate, solid oxide, direct methanol, and direct ammonia fuel cells. Construction and specific application for power generation are presented for each type. The modeling and optimization aspects of fuel cells and their systems are explained. Several power generation systems with fuel cells are discussed, in which each type of fuel cells has specific system requirements. The overall system must include various types of separators, pumps, and compressors depending on the case. In aqueous systems water must be recycled, e.g., in the case of proton-exchange membrane fuel cells water must be actually fed in excess so that the membrane is wetted. Also for a direct methanol fuel cell water must be recovered and recycled. In molten carbonate fuel cell systems carbon dioxide must be recovered and recycled. In solid oxide fuel cell systems, the fuel must be supplied in excess and is not completely consumed; therefore it is important to couple these systems with gas turbines.

Ibrahim Dincer; Calin Zamfirescu

2014-01-01T23:59:59.000Z

436

Species measurements in a hypersonic, hydrogen-air, combustion wake  

SciTech Connect (OSTI)

A continuously sampling, time-of-flight mass spectrometer has been used to measure relative species concentrations in a two-dimensional, hydrogen-air combustion wake at mainstream Mach numbers exceeding 5. The experiments, in a free piston shock tunnel, yielded distributions of hydrogen, oxygen, nitrogen, water, and nitric oxide at stagnation enthalpies ranging from 5.6 MJ/kg to 12.2 MJ/kg and at a distance of approximately 100s times the thickness of the initial hydrogen jet. The amount of hydrogen mixed in stoichiometric proportions was approximately independent of the stagnation enthalpy, despite the fact that the proportion of hydrogen in the wake was increased with stagnation enthalpy. Roughly 50% of the mixed hydrogen underwent combustion at the highest enthalpy. The proportion of hydrogen reacting to water could be approximately predicted using reaction rates based on mainstream temperatures.

Skinner, K.A.; Stalker, R.J. [Univ. of Queensland, Brisbane, Queensland (Australia)] [Univ. of Queensland, Brisbane, Queensland (Australia)

1996-09-01T23:59:59.000Z

437

Composition for absorbing hydrogen  

DOE Patents [OSTI]

A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

Heung, L.K.; Wicks, G.G.; Enz, G.L.

1995-05-02T23:59:59.000Z

438

Hydrogen Storage - Current Technology | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Current on-board hydrogen storage approaches involve compressed hydrogen gas tanks, liquid hydrogen tanks, cryogenic compressed hydrogen, metal hydrides,...

439

Gaseous Hydrogen Delivery Breakout - Strategic Directions for...  

Broader source: Energy.gov (indexed) [DOE]

Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop...

440

NREL: Hydrogen and Fuel Cells Research - NREL Hydrogen Expert Sees Promise  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NREL Hydrogen Expert Sees Promise in New Discovery NREL Hydrogen Expert Sees Promise in New Discovery Photoelectrochemical pioneer John Turner says nickel film cracks the door for tandem artificial photosynthesis, greater efficiency January 8, 2014 Producing hydrogen directly from the sun -- and in a way that is commercially viable -- is more a reality, less a pipedream, thanks in part to a new discovery, renowned hydrogen water-splitting expert John Turner stated in a commentary in the journal Science. Turner, a research fellow at the Energy Department's National Renewable Energy Laboratory, demonstrated 15 years ago that he could use sunlight in a photoelectrochemical process to extract hydrogen from water at a remarkable 12.4% efficiency. Ever since, researchers have been trying to make that process more stable

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic Reagents  

E-Print Network [OSTI]

Articles Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic for finding carbon-free synthesis methods for metal sulfides. The decomposition of organosulfur, such as manganese sulfide (MnS). Here we report a hydrothermal synthesis method for the formation of MnS in which

442

Current (2009) State-of-the-Art Hydrogen Production Cost Estimate  

E-Print Network [OSTI]

Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis National Cost Estimate Using Water Electrolysis To: Mr. Mark Ruth, NREL, DOE Hydrogen Systems Integration Office. For central production, the hydrogen cost is at the plant gate of an electrolysis facility with a capacity

443

HYDROGEN IGNITION MECHANISM FOR EXPLOSIONS IN NUCLEAR FACILITY PIPE SYSTEMS  

SciTech Connect (OSTI)

Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions exist. Pipe ruptures at nuclear facilities were attributed to hydrogen explosions inside pipelines, in nuclear facilities, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents an ignition source for hydrogen was questionable, but these accidents, demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein.

Leishear, R

2010-05-02T23:59:59.000Z

444

FCT Hydrogen Storage: Hydrogen Storage R&D Activities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Storage R&D Activities Hydrogen Storage R&D Activities to someone by E-mail Share FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Facebook Tweet about FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Twitter Bookmark FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Google Bookmark FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Delicious Rank FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Digg Find More places to share FCT Hydrogen Storage: Hydrogen Storage R&D Activities on AddThis.com... Home Basics Current Technology DOE R&D Activities National Hydrogen Storage Compressed/Liquid Hydrogen Tanks Testing and Analysis Quick Links Hydrogen Production Hydrogen Delivery Fuel Cells Technology Validation Manufacturing Codes & Standards

445

2010 Hydrogen and Fuel Cell Global Commercialization & Development Update  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen is a clean fuel. When used in fuel cells, the Hydrogen is a clean fuel. When used in fuel cells, the only byproducts are water and heat. * Clean hydrogen technology has the potential to strengthen national economies and create high-quali- ty jobs in industries such as fuel cell manufacturing. * Hydrogen can be derived from renewable sources and is fully interchangeable with electricity - hydrogen can be used to generate electricity, while electricity can be used to produce hydrogen. * Over 100 years of safe production, transportation and use of hydrogen shows that it carries no more risk than natural gas or gasoline. * Hydrogen can be produced from diverse domestic sources and processes, freeing it from the political instabilities that affect the world's oil and gas supplies. * Fuel cells have more than double the energy-efficien-

446

Hydrogen pickup and redistribution in alpha-annealed Zircaloy-4  

SciTech Connect (OSTI)

Zircaloy-4, which is widely used as a core structural material in Pressurized-Water Reactors (PWR), picks up hydrogen during service. Hydrogen solubility in Zircaloy-4 is low and hydrides precipitate after the Zircaloy-4 matrix becomes supersaturated with hydrogen. These hydrides embrittle the Zircaloy-4. To study hydrogen pickup and concentration, a postirradiation nondestructive radiographic technique for measuring hydrogen concentration was developed and qualified. Experiments on hydrogen pickup were conducted in the Advanced Test Reactor (ATR). Ex-reactor tests were conducted to determine the conditions for which hydrogen would dissolve, migrate, and precipitate. Finally, a phenomenological model for hydrogen diffusion was indexed to the data. This presentation describes the equipment and the model, presents the results of experiments, and compares the model predictions to experimental results.

Kammenzind, B.F.; Franklin, D.G.; Duffin, W.J. [Bettis Atomic Power Lab., West Mifflin, PA (United States); Peters, H.R. [Martin Marietta Corp., Schenectady, NY (United States). Knolls Atomic Power Lab.

1996-06-01T23:59:59.000Z

447

Hypersonic hydrogen combustion in the thin viscous shock layer  

SciTech Connect (OSTI)

Different models of hypersonic diffusive hydrogen combustion in a thin viscous shock layer (TVSL) at moderate Reynolds numbers have been developed. The study is based on computations of nonequilibrium multicomponent flowfield parameters of air-hydrogen mixture in the TVSL near the blunt probe. The structure of computed combustion zones is analyzed. Under conditions of slot and uniform injections the zone structures are essentially different. Hydrogen injection conditions are discovered at which the nonreacting hydrogen zone and the zone enriched with the hydrogen combustion products appear near the body surface. Hydrogen, water, and OH concentrations identify these zones. More effective cooling of the probe surface occurs at moderate injections compared to strong ones. Under the blowing conditions at moderate Reynolds numbers the most effective cooling of the body surface occurs at moderate uniform hydrogen injection. The results can be helpful for predicting the degree of supersonic hydrogen combustion in hypersonic vehicle engines. 21 refs.

Riabov, V.V.; Botin, A.V. [Worcester Polytechnic Inst, Worcester, MA (United States)

1995-04-01T23:59:59.000Z

448

DOE Hydrogen Analysis Repository: Hydrogen Modeling Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Modeling Projects Modeling Projects Below are models grouped by topic. These models are used to analyze hydrogen technology, infrastructure, and other areas related to the development and use of hydrogen. Cross-Cutting Distributed Energy Resources Customer Adoption Model (DER_CAM) Hydrogen Deployment System (HyDS) Model and Analysis Hydrogen Technology Assessment and Selection Model (HyTASM) Renewable Energy Power System Modular Simulator (RPM-Sim) Stranded Biogas Decision Tool for Fuel Cell Co-Production Energy Infrastructure All Modular Industry Growth Assessment (AMIGA) Model Building Energy Optimization (BEopt) Distributed Energy Resources Customer Adoption Model (DER_CAM) Hydrogen Deployment System (HyDS) Model and Analysis Hydrogen Technology Assessment and Selection Model (HyTASM)

449

Development of an electrochemical hydrogen separator  

SciTech Connect (OSTI)

The EHS is an electrochemical hydrogen separator based on the uniquely reversible nature of hydrogen oxidation-reduction reactions in electrochemical systems. The principle and the hardware concept are shown in Figure 1. Hydrogen from the mixed gas stream is oxidized to H{sup +} ions, transported through a cation transport electrolyte membrane (matrix) under an applied electric field and discharged in a pure hydrogen state on the cathode. The cation transfer electrolyte membrane provides a barrier between the feed and product gases. The EHS design is an offshoot of phosphoric acid fuel cell development. Although any proton transfer electrolyte can be used, the phosphoric acid based system offers a unique advantage because its operating temperature of {approximately}200{degree}C makes it tolerant to trace CO and also closely matches the water-shift reactor exit gas temperature ({approximately}250{degree}C). Hydrogen-containing streams in coal gasification systems have large carbon monoxide contents. For efficient hydrogen recovery, most of the CO must be converted to hydrogen by the low temperature water-shift reaction (Figure 2). Advanced coal gasification and gas separation technologies offer an important pathway to the clean utilization of coal resources.

Abens, S.; Fruchtman, J.; Kush, A.

1993-09-01T23:59:59.000Z

450

DOE Hydrogen and Fuel Cells Program: Hydrogen Analysis Resource Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production Hydrogen Production Hydrogen Delivery Hydrogen Storage Hydrogen Manufacturing Fuel Cells Applications/Technology Validation Safety Codes and Standards Education Basic Research Systems Analysis Analysis Repository H2A Analysis Hydrogen Analysis Resource Center Scenario Analysis Well-to-Wheels Analysis Systems Integration U.S. Department of Energy Search help Home > Systems Analysis > Hydrogen Analysis Resource Center Printable Version Hydrogen Analysis Resource Center The Hydrogen Analysis Resource Center provides consistent and transparent data that can serve as the basis for hydrogen-related calculations, modeling, and other analytical activities. This new site features the Hydrogen Data Book with data pertinent to hydrogen infrastructure analysis; links to external databases related to

451

Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines...  

Broader source: Energy.gov (indexed) [DOE]

of hydrogen permeation behavior and its impact on hydrogen embrittlement of pipeline steels under high gaseous pressures relevant to hydrogen gas transmission pipeline...

452

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...  

Broader source: Energy.gov (indexed) [DOE]

Bulk Hydrogen Storage Strategic Directions for Hydrogen Delivery Workshop May 7-8, 2003 Crystal City, Virginia Breakout Session - Bulk Hydrogen Storage Main ThemesCaveats Bulk...

453

Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping...  

Broader source: Energy.gov (indexed) [DOE]

Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22, 2002-July 22, 2002 Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22,...

454

NREL: Hydrogen and Fuel Cells Research - Hydrogen Storage  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

L. Simpson. (2010) Contact: Thomas Gennett 303-384-6628 Printable Version Hydrogen & Fuel Cells Research Home Projects Fuel Cells Hydrogen Production & Delivery Hydrogen Storage...

455

DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

5037: Hydrogen Storage Materials - 2004 vs. 2006 DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials - 2004 vs. 2006 This program record from the Department...

456

Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

457

Why Hydrogen? Hydrogen from Diverse Domestic Resources  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

produce hydrogen in a centralized coal based operation for .79kg at the plant gate with carbon sequestration. Develop advanced OTM, HTM, technology, advanced reforming and shift...

458

Resource Assessment for Hydrogen Production: Hydrogen Production...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Administration ERR Estimated Recoverable Reserves FCEV fuel cell electric vehicle GHG greenhouse gas GW gigawatt GWh gigawatt-hour GWdt gigawatt-days thermal H2A Hydrogen...

459

The Copper Sulfide Coating on Polyacrylonitrile with Chelating Agents by an Electroless Deposition Method and its EMI Shielding Effectiveness  

SciTech Connect (OSTI)

In this study, a variety of concentrations of chelating agents were added to obtain the anchoring effect and chelating effect in the electroless plating bath. The mechanism of the Cu{sub x(x=1,2)}S growth and the electromagnetic interference shielding effectiveness (EMI SE) of the composite were studied. It was found that the vinyl acetate residued in PAN substrate would be purged due to the swelling effect by chelating agents solution. And then, the anchoring effect occurred due to the hydrogen bonding between the pits of PAN substrate and the chelating agent. Consequently, the copper sulfide layer deposited by the electroless plating reaction with EDTA and TEA. The swelling degree (S{sub d}) was proposed and evaluated from the FT-IR spectra. The relationship between swelling degree of the PAN films and EDTA (C) is expressed as: S{sub d} = 0.13+0.90xe and (-15.15C). And TEA series is expressed as: S{sub d} = 0.07+1.00xe and (-15.15C). On the other hand, the FESEM micrograph showed that the average thickness of copper sulfide increased from 76 nm to 383 nm when the concentration of EDTA increased from 0.00M to 0.20M. Consequently, the EMI SE of the composites increased from 10{approx}12 dB to 25{approx}27 dB. The GIA-XRD analyze indicated that the deposited layer consisted of CuS and Cu{sub 2}S.

Roan, M.-L. [Department of Electro-optical Engineering, Lan-Yan Institute of Technology, Taiwan (China); Chen, Y.-H.; Huang, C.-Y. [Department of Materials Engineering, Tatung University, Taiwan (China)

2008-08-28T23:59:59.000Z

460

Copyright (c) 2000 Water Environment Federation. All Rights Reserved. Odors and VOC Emissions 2000  

E-Print Network [OSTI]

. This paper documents burst releases of H2S recorded with a state-of-the-art field measurement system in two manure collection and storage pits under fully slatted floors. They were mechanically ventilated with pit was continuously pumped from three locations: pit fans, wall fans and pit headspaces. Hydrogen sulfide

Ni, Jiqin "Jee-Chin"

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Hydrogen Generation and Coke Formation over a Diesel Oxidation Catalyst under Fuel Rich Conditions  

Science Journals Connector (OSTI)

Hydrogen Generation and Coke Formation over a Diesel Oxidation Catalyst under Fuel Rich Conditions† ... Hydrogen production via hydrocarbon steam reforming and water gas shift reactions was investigated over a monolith-supported Pt-based diesel oxidation catalyst. ...

Meshari AL-Harbi; Jin-Yong Luo; Robert Hayes; Martin Votsmeier; William S. Epling

2010-12-08T23:59:59.000Z

462

Hydrogen storage gets new hope  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen storage gets new hope Hydrogen storage gets new hope A new method for "recycling" hydrogen-containing fuel materials could open the door to economically viable...

463

The Bumpy Road to Hydrogen  

E-Print Network [OSTI]

will trump hydrogen and fuel cell vehicles. Advocates ofbenefits sooner than hydrogen and fuel cells ever could.emissions from a hydrogen fuel cell vehicle will be about

Sperling, Dan; Ogden, Joan M

2006-01-01T23:59:59.000Z

464

Microbial Fuel Cells for Recycle of Process Water from Cellulosic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to improve ethanol process economics in biorefineries Decreased water consumption Enables wastewater recycling Electricity or hydrogen generation Inexpensive Versatile Applications...

465

Theoretical Studies on Heavy Metal Sulfides in Solution  

SciTech Connect (OSTI)

'Calculating the stabilities, Raman and UV spectra and acidities of As sulfides in aqueous solution', J. A. Tossell, M. D. Zimmermann and G. R. Helz. Some of the Raman spectra obtained by reacting aqueous As(OH)3 with aqueous bisulfide are shown, taken from Wood, et al. (2002). To interpret these spectra we have carried out an extensive series of calculations, detailed for the case of AsS(SH){sub 2}{sup -} in Table 1 below. By employing state of the art quantum chemical techniques to determine gas-phase harmonic and anharmonic frequencies and solution phase corrections we can accurately match features in the experimental spectrum shown in the top figure. The AsS(SH){sub 2}{sup -}...22 H{sub 2}O nanocluster employed is shown in the lower figure. For this species we have calculated the equilibrium structure and the harmonic vibrational spectrum at the CBSB7 B3LYP level. For the free solute species AsS(SH){sub 2}{sup -} we have carried out a whole series of calculations, evaluating harmonic and anharmonic vibrational frequencies at a number of different quantum mechanical levels. In the spectra below, Fig. 3 and Fig. 5 from Wood, et al. (2002), the features around 700-800 cm{sup -1} are attributed to As-O stretches and those around 350-450 cm{sup -1} to As-S stretches. In the nanocluster an isolated vibrational feature is observed at 425 cm{sup -1}, an As=S stretch, close to the value (415 cm{sup -1}) determined by Wood, et al. (2002). Analysis of the calculated frequencies for AsS(SH){sub 2}{sup -} within a polarizable continuum model yields a similar result. Taking the highest level harmonic results, obtained from a CCSD calculation, and adding anharmonic and PCM corrections at the B3LYP level (designated (3) + (5) - (1) in Table 1) gives a frequency for the intense high frequency As=S stretch within 15 cm{sup -1} of experiment. Although there is still interesting work to be done on the stabilities and the Raman and UV spectra of As sulfides, most of the basic concepts have been worked out and we are therefore proposing to move to a new area, that of humic acids (while continuing our studies complexes formed by As oxides and sulfides, now applied to functional groups present in humic acids).

Tossell, John A.

2007-10-31T23:59:59.000Z

466

DEVELOPMENT OF DOPED NANOPOROUS CARBONS FOR HYDROGEN STORAGE  

SciTech Connect (OSTI)

Hydrogen storage materials based on the hydrogen spillover mechanism onto metal-doped nanoporous carbons are studied, in an effort to develop materials that store appreciable hydrogen at ambient temperatures and moderate pressures. We demonstrate that oxidation of the carbon surface can significantly increase the hydrogen uptake of these materials, primarily at low pressure. Trace water present in the system plays a role in the development of active sites, and may further be used as a strategy to increase uptake. Increased surface density of oxygen groups led to a significant enhancement of hydrogen spillover at pressures less than 100 milibar. At 300K, the hydrogen uptake was up to 1.1 wt. % at 100 mbar and increased to 1.4 wt. % at 20 bar. However, only 0.4 wt% of this was desorbable via a pressure reduction at room temperature, and the high lowpressure hydrogen uptake was found only when trace water was present during pretreatment. Although far from DOE hydrogen storage targets, storage at ambient temperature has significant practical advantages oner cryogenic physical adsorbents. The role of trace water in surface modification has significant implications for reproducibility in the field. High-pressure in situ characterization of ideal carbon surfaces in hydrogen suggests re-hybridization is not likely under conditions of practical interest. Advanced characterization is used to probe carbon-hydrogen-metal interactions in a number of systems and new carbon materials have been developed.

Angela D. Lueking; Qixiu Li; John V. Badding; Dania Fonseca; Humerto Gutierrez; Apurba Sakti; Kofi Adu; Michael Schimmel

2010-03-31T23:59:59.000Z

467

Effect of the Protein Denaturants Urea and Guanidinium on Water Structure: A Structural and Thermodynamic Study  

E-Print Network [OSTI]

in the hydrogen bond network of water in the first hydration shell of urea and guanidinium were analyzed in terms of the random network model using Monte Carlo simulations. Bulk water consists of two populations of hydrogen and more bent hydrogen bonds. In the first shell of urea, hydrogen bonds between waters solvating the amino

Sharp, Kim

468

Role of Water States on Water Uptake and Proton Transport in Nafion using Molecular Simulations and Bimodal Network  

E-Print Network [OSTI]

hydrogen permeation properties and water uptake of Nfion 117 membrane and recast film for PEM fuel cell.

Hwang, Gi Suk

2013-01-01T23:59:59.000Z

469

Renewable Hydrogen: Technology Review and Policy Recommendations for State-Level Sustainable Energy Futures  

E-Print Network [OSTI]

Thermal Conversion of Water Wind Electrolysis n.s. (10 MWp)method is the electrolysis of water using a renewableobtain higher Electrolysis of Water Hydrogen can be produced

Lipman, Timothy; Edwards, Jennifer Lynn; Brooks, Cameron

2006-01-01T23:59:59.000Z

470

FCT Hydrogen Production: Hydrogen Production R&D Activities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production R&D Hydrogen Production R&D Activities to someone by E-mail Share FCT Hydrogen Production: Hydrogen Production R&D Activities on Facebook Tweet about FCT Hydrogen Production: Hydrogen Production R&D Activities on Twitter Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Google Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Delicious Rank FCT Hydrogen Production: Hydrogen Production R&D Activities on Digg Find More places to share FCT Hydrogen Production: Hydrogen Production R&D Activities on AddThis.com... Home Basics Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts

471

Lithium sulfide compositions for battery electrolyte and battery electrode coatings  

SciTech Connect (OSTI)

Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

2014-10-28T23:59:59.000Z

472

Changes in Dimethyl Sulfide Oceanic Distribution due to Climate Change  

SciTech Connect (OSTI)

Dimethyl sulfide (DMS) is one of the major precursors for aerosols and cloud condensation nuclei in the marine boundary layer over much of the remote ocean. Here they report on coupled climate simulations with a state-of-the-art global ocean biogeochemical model for DMS distribution and fluxes using present-day and future atmospheric CO{sub 2} concentrations. They find changes in zonal averaged DMS flux to the atmosphere of over 150% in the Southern Ocean. This is due to concurrent sea ice changes and ocean ecosystem composition shifts caused by changes in temperature, mixing, nutrient, and light regimes. The largest changes occur in a region already sensitive to climate change, so any resultant local CLAW/Gaia feedback of DMS on clouds, and thus radiative forcing, will be particularly important. A comparison of these results to prior studies shows that increasing model complexity is associted with reduced DMS emissions at the equator and increased emissions at high latitudes.

Cameron-Smith, P; Elliott, S; Maltrud, M; Erickson, D; Wingenter, O

2011-02-16T23:59:59.000Z

473

Catalyzed Hydrogen Spillover for Hydrogen Storage  

Science Journals Connector (OSTI)

Catalyzed Hydrogen Spillover for Hydrogen Storage ... Storing sufficient H on-board a wide range of vehicle platforms, while meeting all consumer requirements (driving range, cost, safety, performance, etc.), without compromising passenger or cargo space, is a tremendous tech. ... The authors show that for the 1st time significant amts. of H can be stored in MOF-5 and IRMOF-8 at ambient temp. ...

Ralph T. Yang; Yuhe Wang

2009-02-27T23:59:59.000Z

474

Hydrogen Permeability and Integrity of Hydrogen  

E-Print Network [OSTI]

· To develop suitable welding technology for H2 pipeline construction and repair · To develop technical basisHydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Z. Feng*, L.M. Anovitz*, J pressure permeation test · Edison Welding Institute - Pipeline materials · Lincoln Electric Company

475

Investigation of oxides formed in the corrosion of SUS-304 in high-temperature water through the measurement of evolved hydrogen and radiochemical analyses  

SciTech Connect (OSTI)

Corrosion behavior of SUS-304 at 280/sup 0/C in deaerated water has been traced both through measuring H/sub 2/ gas, concomitantly formed with corrosion, and through radiochemical analysis of the corrosion layers. The calculated H/sub 2/ yield based on the reaction, M + x.H/sub 2/O = MO /sub x/ + x.H/sub 2/ (M: iron, chromium, nickel, manganese, and cobalt), agreed reasonably well with the observed H/sub 2/ yields, showing that iron is mainly in a magnetite form and chromium is in a Cr(III) state. More than 85% of the corrosion layers were recovered by repeating ultrasonic cleaning and electrostripping processes. The residual fraction was rich in chromium and dissolved in the subsequent electropolishing process. The total corrosion increases with the reaction time, although the ''inner layer'' tends to stay almost constant at a longer reaction time. In some cases, both neutron irradiated and nonirradiated SUS coexisted. Mutual transfer of the elements from one SUS to the other has been examined.

Tachikawa, E.; Hoshi, M.; Nakashima, M.; Sagawa, C.; Yonezawa, C.

1984-04-01T23:59:59.000Z

476

Gaseous Hydrogen Delivery Breakout- Strategic Directions for Hydrogen Delivery Workshop  

Broader source: Energy.gov [DOE]

Targets, barriers and research and development priorities for gaseous delivery of hydrogen through hydrogen and natural gas pipelines.

477

BP and Hydrogen Pipelines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BP and Hydrogen Pipelines BP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop August 30-31, 2005 Gary P. Yoho, P.E. i l i * Green corporate philosophy and senior management commitment * Reduced greenhouse gas emissions nine years ahead of target * Alternatives to oil are a big part of BP' including natural gas, LNG, solar and hydrogen * Hydrogen Bus Project won Australia' prestigious environmental award * UK partnership opened the first hydrogen demonstration refueling station * Two hydrogen pipelines in Houston area BP Env ronmenta Comm tment s portfolio, s most BP' * li l " li i i * i l pl i i * Li l li l * " i i l i 2 i i ll i i l pl ifi i * 8" ly idl i i l s Hydrogen Pipelines Two nes, on y a brand new 12 ne s act ve Connect Houston area chem ca ant w th a ref nery nes come off a p

478

Hydrogen Production- Current Technology  

Broader source: Energy.gov [DOE]

The development of clean, sustainable, and cost-competitive hydrogen production processes is key to a viable future clean energy economy. Hydrogen production technologies fall into three general...

479

A Hydrogen Economy  

Science Journals Connector (OSTI)

The history of the “hydrogen economy” may be broken down into three parts ... is the history of the founding of the Hydrogen Energy Society which took place in Miami,...

J. O’M. Bockris

1981-01-01T23:59:59.000Z

480

Solar Hydrogen Production  

Science Journals Connector (OSTI)

The common methods of hydrogen production impose many concerns regarding the decline in...2...emission, and ecological impacts. Subsequently, all the downstream industries that consume hydrogen involve the aforem...

Ibrahim Dincer; Anand S. Joshi

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "water hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Hydrogen Fuel Quality (Presentation)  

SciTech Connect (OSTI)

Jim Ohi of NREL's presentation on Hydrogen Fuel Quality at the 2007 DOE Hydrogen Program Annual Merit Review and Peer Evaluation on May 15-18, 2007 in Arlington, Virginia.

Ohi, J.

2007-05-17T23:59:59.000Z

482

Webinar: Hydrogen Refueling Protocols  

Broader source: Energy.gov [DOE]

Video recording and text version of the webinar titled, Hydrogen Refueling Protocols, originally presented on February 22, 2013.

483

The Hydrogen Economy  

Science Journals Connector (OSTI)

Before describing the characteristics of an economy in which hydrogen is the medium of energy, let us...

J. O’M. Bockris; Z. Nagy

1974-01-01T23:59:59.000Z

484

Hydrogen Technologies Safety Guide  

SciTech Connect (OSTI)

The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

Rivkin, C.; Burgess, R.; Buttner, W.

2015-01-01T23:59:59.000Z

485

National Hydrogen Energy Roadmap  

Broader source: Energy.gov [DOE]

This roadmap provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development.

486

Hydrogenation of Magnesium Nickel Boride for Reversible Hydrogen Storage  

Science Journals Connector (OSTI)

Hydrogenation of Magnesium Nickel Boride for Reversible Hydrogen Storage ... Use of hydrogen for transportation applications requires materials that not only store hydrogen at high density but that can operate reversibly at temperatures and pressures below approximately 100 °C and 10 bar, respectively. ... This composition is based on assuming the following complete hydrogenation reaction:which stores 2.6 wt % hydrogen. ...

Wen Li; John J. Vajo; Robert W. Cumberland; Ping Liu; Son-Jong Hwang; Chul Kim; Robert C. Bowman, Jr.

2009-11-06T23:59:59.000Z

487

Direct Water-Cooled Power Electronics Substrate Packaging | Department...  

Broader source: Energy.gov (indexed) [DOE]

Direct Water-Cooled Power Electronics Substrate Packaging Direct Water-Cooled Power Electronics Substrate Packaging 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit...

488

Layered metal sulfides: Exceptionally selective agents for radioactive strontium removal  

Science Journals Connector (OSTI)

...07 mmol, 40 mg) in water (20 ml), an excess...washed several times with water, acetone, and...Complex Environmental Remediation Problems , ed Blacklick...removal from contaminated ground water and wastewater...

Manolis J. Manos; Nan Ding; Mercouri G. Kanatzidis

2008-01-01T23:59:59.000Z

489

Gaseous Hydrogen Delivery Breakout  

E-Print Network [OSTI]

or reduce the likelihood of hydrogen embrittlement Test existing high strength steel alloys for use in largeGaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7 compression. Safety, integrity, reliability: Metal embrittlement, no H2 odorant, low ignition energy

490

2011 DOE Hydrogen and Fuel Cells Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 1 FY 2011 Annual Progress Report DOE Hydrogen and Fuel Cells Program Alabama II.K.14 University of Alabama, Tuscaloosa: Protein-Templated Synthesis and Assembly of Nanostructuctures for Hydrogen Production . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267 V.F.1 CFD Research Corporation: Water Transport in PEM Fuel Cells: Advanced Modeling, Material Selection, Testing, and Design Optimization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .814 V.F.1 ESI US R&D: Water Transport in PEM Fuel Cells: Advanced Modeling, Material Selection, Testing, and Design Optimization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .814 Arizona II.C.1 Arizona State University: Zeolite Membrane Reactor for Water-Gas Shift Reaction for Hydrogen

491

Hydrogen Delivery Liquefaction and Compression  

Broader source: Energy.gov [DOE]

Hydrogen Delivery Liquefaction and Compression - Overview of commercial hydrogen liquefaction and compression and opportunities to improve efficiencies and reduce cost.

492

New Materials for Hydrogen Pipelines  

Broader source: Energy.gov [DOE]

Barriers to Hydrogen Delivery: Existing steel pipelines are subject to hydrogen embrittlement and are inadequate for widespread H2 distribution.

493

Cost Analysis of a Concentrator Photovoltaic Hydrogen Production System  

SciTech Connect (OSTI)

The development of efficient, renewable methods of producing hydrogen