Powered by Deep Web Technologies
Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California  

E-Print Network [OSTI]

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California Gunnar W. Schade,* Gabrielle B. Dreyfus, and Allen H. Goldstein ABSTRACT (CARB) measured MTBE in urban regions in 1995­ 1996, reporting a range of 0.4 to 13.2 ppbv in the LosMethyl tertiary butyl ether (MTBE

Cohen, Ronald C.

2

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network [OSTI]

Environmental Microbiology (2001) 3(6), 407±416 Methyl tert-butyl ether (MTBE) degradation of California, Riverside, Riverside, CA 92521, USA. Summary The widespread use of methyl tert-butyl ether (MTBE is often proposed as the most promising alter- native after treatment. However, MTBE biodegradation appears

3

Measurement of methyl-tert-butyl-ether (MTBE) in raw drinking water  

SciTech Connect (OSTI)

In order to assess the pathways for human exposure to methyl-tert-butyl-ether (MTBE) and to understand the extent of MTBE contamination in watersheds, a purge and trap gas chromatographic mass spectrometric method to measure part-per-trillion (ppt) concentrations of MTBE in environmental waters was developed. A variety of California's raw drinking waters were analyzed. No detectable MTBE was found in deep groundwater (>1000 feet). However shallow groundwater ({approx}250 feet) contained MTBE concentrations of non-detect to 1300 ppt. MTBE concentrations measured in rivers and lakes ranged from non-detect to 3500 ppt. East (San Francisco) Bay area rain water contained approximately 80 ppt MTBE.

Davisson, M L; Koester, C J; Moran, J E

1999-10-14T23:59:59.000Z

4

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Methyl Tert-Butyl Ether (MTBE) in Groundwater P.I. names,Methyl tert-butyl ether (MTBE) is a contaminant of concernsubsurface environments. MTBE appears to be degraded readily

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

5

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis of their pyrolyses by  

E-Print Network [OSTI]

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis 1999; accepted 20 July 1999 Abstract The pyrolysis products of neutral methyl-d3 t-butyl ether (MTBE-d3 from thermal cracking patterns. MTBE and TOME both exhibit base peaks at m/z 73 (which shifts to m/z 76

Morton, Thomas Hellman

6

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network [OSTI]

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

7

Determination of methyl tert. butyl ether (MTBE) in gasoline  

SciTech Connect (OSTI)

A GLC-acid extraction method is described for the determination of MTBE in gasolines. The method consists of a programmed GLC analysis starting at about room temperature conducted before and after extraction with cold 85% phosphoric acid. This treatment results in the preferential solubility of ethers and other oxygenated compounds while minimizing the reaction of olefins and aromatics which may be present in the gasolines. Plotting various known concentrations of MTBE in gasolines against the concentrations determined in the same samples by the authors methodology results in a straight line relationship. The concentration of MTBE in any sample of gasoline may thus be determined using their GLC-extraction procedure and the calibration line. The analysis can accommodate a wide choice of standard GLC columns and programs. 2 refs., 1 fig., 1 tab.

Feldman, J.; Orchin, M. (Univ. of Cincinnati, OH (United States))

1993-02-01T23:59:59.000Z

8

Acute toxicity of methyl-tertiary-butyl ether (MTBE) to aquatic organisms  

SciTech Connect (OSTI)

Due to the recent amendment of the Clean Air Act, oxygenates are now being added to gasolines to boost octane and reduce air pollution from combustion in heavily populated areas. Oxygenates such as alcohols (i.e. methanol) and ethers (methyl-tertiary-butyl ether, MTBE) are commonly being used. A series of bioassay studies have been conducted with MTBE, one of the most commonly used octane-enhancing additives. Freshwater and marine studies were conducted with fish, invertebrates and algae to determine the impact of this material on the environment following accidental spills. Static-renewal studies were run to ensure maintenance of MTBE, a highly volatile material in the test containers. Chemical confirmation of exposure concentrations demonstrated the adequacy of the exposure system. Mysid shrimp were highly sensitive to MTBE, with significantly less effect observed with the other species evaluated. These data have implications for spill response, particularly since MTBE is slow to biodegrade and will rapidly move through groundwater. Comparative data for other oxygenates will also be discussed.

BenKinney, M.T.; Barbieri, J.F.; Gross, J.S.; Naro, P.A. [Stonybrook Labs. Inc., Princeton, NJ (United States)

1994-12-31T23:59:59.000Z

9

Manipulation of the HIFVegf pathway rescues methyl tert-butyl ether (MTBE)-induced vascular lesions  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) has been shown to be specifically anti-angiogenic in piscine and mammalian model systems at concentrations that appear non-toxic in other organ systems. The mechanism by which MTBE targets developing vascular structures is unknown. A global transcriptome analysis of zebrafish embryos developmentally exposed to 0.006255 mM MTBE suggested that hypoxia inducible factor (HIF)-regulated pathways were affected. HIF-driven angiogenesis via vascular endothelial growth factor (vegf) is essential to the developing vasculature of an embryo. Three rescue studies were designed to rescue MTBE-induced vascular lesions: pooled blood in the common cardinal vein (CCV), cranial hemorrhages (CH), and abnormal intersegmental vessels (ISV), and test the hypothesis that MTBE toxicity was HIFVegf dependent. First, zebrafish vegf-a over-expression via plasmid injection, resulted in significantly fewer CH and ISV lesions, 46 and 35% respectively, in embryos exposed to 10 mM MTBE. Then HIF degradation was inhibited in two ways. Chemical rescue by N-oxaloylglycine significantly reduced CCV and CH lesions by 30 and 32% in 10 mM exposed embryos, and ISV lesions were reduced 24% in 5 mM exposed zebrafish. Finally, a morpholino designed to knock-down ubiquitin associated von HippelLindau protein, significantly reduced CCV lesions by 35% in 10 mM exposed embryos. In addition, expression of some angiogenesis related genes altered by MTBE exposure were rescued. These studies demonstrated that MTBE vascular toxicity is mediated by a down regulation of HIFVegf driven angiogenesis. The selective toxicity of MTBE toward developing vasculature makes it a potentially useful chemical in the designing of new drugs or in elucidating roles for specific angiogenic proteins in future studies of vascular development. - Highlights: Global gene expression of MTBE exposed zebrafish suggested altered HIF1 signaling. Over expression of zebrafish vegf-a rescues MTBE-induced vascular lesions. Inhibiting PHD or knocking down VHL rescues MTBE-induced vascular lesions. HIF1-Vegf driven angiogenesis is a target for MTBE vascular toxicity.

Bonventre, Josephine A., E-mail: josephine.bonventre@oregonstate.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Oregon State University, Department of Environmental and Molecular Toxicology, 1011 Agricultural and Life Sciences Bldg, Corvallis, OR 97331 (United States); Kung, Tiffany S., E-mail: tiffany.kung@rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); White, Lori A., E-mail: lawhite@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Cooper, Keith R., E-mail: cooper@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States)

2013-12-15T23:59:59.000Z

10

Alveolar breath sampling and analysis to assess exposures to methyl tertiary butyl ether (MTBE) during motor vehicle refueling  

SciTech Connect (OSTI)

In this study we present a sampling and analytical methodology that can be used to assess consumers` exposures to methyl tertiary butyl ether (MTBE) that may result from routine vehicle refueling operations. The method is based on the collection of alveolar breath samples using evacuated one-liter stainless steel canisters and analysis using a gas chromatograph-mass spectrometer equipped with a patented `valveless` cryogenic preconcentrator. To demonstrate the utility of this approach, a series of breath samples was collected from two individuals (the person pumping the fuel and a nearby observer) immediately before and for 64 min after a vehicle was refueled with premium grade gasoline. Results demonstrate low levels of MTBE in both subjects` breaths before refueling, and levels that increased by a factor of 35 to 100 after the exposure. Breath elimination models fitted to the post exposure measurements indicate that the half-life of MTBE in the first physiological compartment was between 1.3 and 2.9 min. Analysis of the resulting models suggests that breath elimination of MTBE during the 64 min monitoring period was approximately 155 {mu}g for the refueling subject while it was only 30 {mu}g for the nearby observer. This analysis also shows that the post exposure breath elimination of other gasoline constituents was consistent with previously published observations. 20 refs., 3 figs., 4 tabs.

Lindstrom, A.B.; Pleil, J.D. [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States)

1996-07-01T23:59:59.000Z

11

Canada could get three MTBE plants  

SciTech Connect (OSTI)

This article reports on the proposed development of three methyl tert-butyl ether (MTBE) plants in Canada. MTBE is used as an oxygenated fuel additive. The author discusses how demand for MTBE is increasing due to the regulation of leaded gasoline by the U.S. and Canadian governments. The exportation of MTBE from Canada to the U.S. is highlighted.

Anderson, E

1990-03-01T23:59:59.000Z

12

Factors influencing biological treatment of MTBE contaminated ground water  

E-Print Network [OSTI]

Methyl tertiary-butyl ether (MTBE) biodegradation in batchCometabolic degradation of MTBE by a cyclohexane-oxidizingof 49 Biological Treatment of MTBE Fortin, N. Y. , and M. A.

Stringfellow, William T.; Hines Jr., Robert D.; Cockrum, Dirk K.; Kilkenny, Scott T.

2001-01-01T23:59:59.000Z

13

Biodegradation of methyl tertiary butyl ether (MTBE) using a granular activated carbon trickling filter  

SciTech Connect (OSTI)

A pilot scale trickling filter was constructed using granular activated carbon (GAC) as the packing medium and inoculated with a microbial culture known to degrade MTBE. The packing dimensions were 0.076 m in diameter and 0.22 m deep. The unit operated with recycling flow for two months before a biofilm was observed on the GAC. After two additional months the biofilm had visibly spread throughout the packing. A few pieces of GAC were placed in a sealed bottle with MTBE-contaminated water and nutrients. Headspace analysis performed over 14 days confirmed that MTBE degradation was occurring. The trickling filter was converted to continuous flow and operated for one month at a nominal flow rate of 0.1 L/min and a hydraulic loading rate of 32 m{sup 3}/m{sup 2}-d. Samples were collected for analysis at the spray nozzle and at the bottom of the trickling filter. Fractional removal varied with influent MTBE concentration, temperature and liquid flow rate. Percent MTBE removal was as high as 85%. A mechanical failure resulted in the trickling filter bed drying and percent removal dropping to less than 1 percent. However, the system recovered within five days.

Converse, B.M.; Schroeder, E.D.; Chang, D.P.Y.

1999-07-01T23:59:59.000Z

14

Oxidation of methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by ozone and combined ozone/hydrogen peroxide  

SciTech Connect (OSTI)

The aim of this work was to study the reaction of ozone and combined ozone/hydrogen peroxide on oxygenated additives such as methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) in dilute aqueous solution using controlled experimental conditions. Experiments conducted in a semi-continuous reactor with MTBE and ETBE in combination (initial concentration: 2 mmol/L of each) showed that ETBE was better eliminated than MTBE with both ozone and combined O[sub 3]/H[sub 2]O[sub 2]. batch experiments led to the determination of the ratio of the kinetic constants for the reaction of OH[degree]-radical with MTBE and ETBE (k[sub OH[degree]/ETBE]/k[sub OH[degree]//MTBE] = 1.7). Tert-butyl formate and tert-butyl acetate were identified as the ozonation byproducts of MTBE an ETBE, respectively, while tert-butyl alcohol was found to be produced during the ozonation of both compounds. 10 refs., 10 figs., 1 tab.

Leitner, N.K.V.; Papailhou, A.L.; Croue, J.P.; Dore, M. (Univ. de Poitiers (France)); Peyrot, J. (British Petroleum, Harfleur (France))

1994-01-01T23:59:59.000Z

15

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

16

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

17

Evaluating nonmetallic materials` compatibility with MTBE and MTBE + gasoline service  

SciTech Connect (OSTI)

Methyl-tertiary-butyl-ether (MTBE) has become the leading oxygenate in use in the petroleum industry. Since its introduction several years ago there has been premature deterioration of nonmetallic materials in both neat MTBE and MTBE + gasoline. This degradation is costly in several ways: maintenance, replacement, environmental, and product-loss. Identifying nonmetallic materials compatible with MTBE and MTBE + gasoline is important to the petroleum industry -- all the way from the refinery to the retail sale. Exposure tests have been conducted with different types of nonmetallics in neat MTBE, neat MTBE vapor, and 5% MTBE + 95% gasoline. As in previously reported tests, Teflon{reg_sign} laminates were the top performers, experiencing very little change in any of the properties tested. An ester and ether-based urethane laminate also exhibited only small property changes. Most materials displayed significant deterioration of one or more of the measured properties, even in MTBE condensing vapor and the 5% MTBE + 95% gasoline. The specific effects on each material need to be individually evaluated to determine the effect on service life.

Hotaling, A.C.

1995-12-31T23:59:59.000Z

18

{gamma}-aminobutyric acid{sub A} (GABA{sub A}) receptor regulates ERK1/2 phosphorylation in rat hippocampus in high doses of Methyl Tert-Butyl Ether (MTBE)-induced impairment of spatial memory  

SciTech Connect (OSTI)

Experimental and occupational exposure to Methyl Tert-Butyl Ether (MTBE) has been reported to induce neurotoxicological and neurobehavioral effects, such as headache, nausea, dizziness, and disorientation, etc. However, the molecular mechanisms involved in MTBE-induced neurotoxicity are still not well understood. In the present study, we investigated the effects of MTBE on spatial memory and the expression and function of GABA{sub A} receptor in the hippocampus. Our results demonstrated that intraventricular injection of MTBE impaired the performance of the rats in a Morris water maze task, and significantly increased the expression of GABA{sub A} receptor {alpha}1 subunit in the hippocampus. The phosphorylation of ERK1/2 decreased after the MTBE injection. Furthermore, the decreased ability of learning and the reduction of phosphorylated ERK1/2 level of the MTBE-treated rats was partly reversed by bicuculline injected 30 min before the training. These results suggested that MTBE exposure could result in impaired spatial memory. GABA{sub A} receptor may play an important role in the MTBE-induced impairment of learning and memory by regulating the phosphorylation of ERK in the hippocampus.

Zheng Gang; Zhang Wenbin [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China); Zhang Yun [465 Hospital, Jilin Medical College, Jilin 132001 (China); Chen Yaoming; Liu Mingchao; Yao Ting; Yang Yanxia; Zhao Fang [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China); Li Jingxia; Huang Chuanshu [Nelson Institute of Environmental Medicine, New York University School of Medicine, Tuxedo, New York 10987 (United States); Luo Wenjing [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China)], E-mail: luowenj@fmmu.edu.cn; Chen Jingyuan [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China)], E-mail: jy_chen@fmmu.edu.cn

2009-04-15T23:59:59.000Z

19

Review of potential technologies for the treatment of Methyl tertiary butyl Ether (MtBE) in drinking water  

SciTech Connect (OSTI)

At present, the state of knowledge on effective treatment technologies for MtBE in drinking water, and groundwater in general, is limited. Research by others is focusing on the remediation of MtBE close to the point of release. The City of Santa Monica, MWD, Komex and USC are currently conducting research into different technologies that could be used to remove MtBE from drinking water supplies. The objectives of the research are to evaluate different treatment technologies to identify cost-effective and technically feasible alternatives for the removal of MtBE from drinking water. The evaluation is considering moderate to high water flow rates (100 to 2,000+ gpm) and low to moderate MtBE concentrations (<2,000 {mu}g/l). The research program includes four phases: (1) Literature Review; (2) Bench Scale Study; (3) Field Scale Pre-pilot Study; and (4) Summary Evaluation. This paper presents some preliminary information and findings from the first phase of this research - the literature review. The review discusses the chemical properties of MtBE and how they affect remediation and thus, an evaluation of alternative treatment technologies. The review of available literature, and the applicability and limitations of the following technologies are presented in detail.

Brown, A.; Browne, T.E. [Komex H2O Science, Huntington Beach, CA (United States); Devinny, J.S. [Univ. of Southern California, Los Angeles, CA (United States)] [and others

1997-12-31T23:59:59.000Z

20

A review of treatment technologies for MTBE  

SciTech Connect (OSTI)

Available treatment technologies for methyl tertiary butyl ether (MTBE) contamination in soil, groundwater, and recovered groundwater are reviewed and assessed. MTBE contamination is becoming an important issue due to the increasing prevalence and regulation of this gasoline additive. In addition, MTBE is more soluble and more mobile in groundwater than most hydrocarbons, so it is usually the first gasoline constituent to reach sensitive receptors. Treatment of MTBE is complicated by its Henry`s constant, which is lower than most other gasoline constituents. Furthermore, evidence of biodegradability of MTBE is mixed, and MTBE does not degrade rapidly abiotically. Groundwater pumping is usually employed to contain and collect MTBE-contaminated groundwater, often successfully because of its high aqueous solubility. Air sparging/soil vapor extraction is also successfully employed to treat MTBE, but its effectiveness is reduced by the low Henry`s constant of MTBE. Sparging and other aerobic bioremediation approaches are hampered by the poor biodegradability of MTBE. Oxidation technologies, such as ozone injection, hold promise for rapid in situ remediation of MTBE. Treatment of recovered groundwater contaminated with MTBE is also problematic. MTBE adsorbs poorly to granular activated carbon; advanced oxidation processes are effective on MTBE, but entail high capital and operating costs; bioreactors are of questionable effectiveness on MTBE. Air stripping is usually the most cost-effective treatment technology for MTBE so long as the off gas from the air stripper can be discharged without treatment. However, off gas treatment is expensive, so groundwater is sometimes heated to reduce the requirement for stripping air.

Bass, D. [Groundwater Technology, Inc., Norwood, MA (United States)

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Methyl tertiary butyl ether (MtBE) contamination of the City of Santa Monica drinking water supply  

SciTech Connect (OSTI)

In the summer of 1996, the City of Santa Monica ceased pumping groundwater from two Well Fields (Charnock and Arcadia) used for public drinking water supply due to persistent and increasing concentrations of MtBE in all seven municipal water supply wells. This lost production accounted for 50% of the City`s total drinking water supply. In late 1996, the City, in cooperation with State and Federal agencies, initiated an investigation of MtBE contamination at the two well fields. The objectives of the investigation were as follows: (1) Review available data on the production, use, chemical characteristics, fate and transport, toxicology, and remediation of MtBE; (2) Identify locations of potential sources of MtBE groundwater contamination at the well fields; (3) Develop an understanding of the hydrologic pathways from the potential sources to the drinking water wells; and (4) Evaluate alternative treatment technologies for the removal of MtBE from drinking water. In addition to a review of available information about MtBE, the investigation included an extensive review of literature and available data relevant to the well fields, including well field production histories, site and regional hydrogeology, all well logs and production in the groundwater basins, general groundwater quality, and the record of MtBE detection. Based upon the review of background information, conceptual hydrogeologic models were developed. A detailed review of agency files for over 45 potential source sites was conducted. The information from this review was summarized, and source site screening and ranking criteria were developed. A field program was conducted at the major well field (Charnock), including soil gas surveys, CPTs, soil borings and well installations, geophysics, and aquifer testing. The field program provided site data which allowed the conceptual hydrogeologic model to be refitted to actual site conditions.

Brown, A.; Farrow, J.R.C. [Komex H2O Science, Huntington Beach, CA (United States); Rodriguez, R.A. [City of Santa Monica, CA (United States)] [and others

1997-12-31T23:59:59.000Z

22

Economics of new MTBE design  

SciTech Connect (OSTI)

Methyl Tertiary Butyl Ether (MTBE) is produced industrially by catalytic reaction between methanol and isobutene. The catalyst that is widely used is an acidic ion exchange resin. This article explores design and economics when sulfuric acid is the catalyst. The profitability of MTBE production depends mainly on the cost of butenes and methhanol. Thus, the example shows MTBE made with a catalyst of sulfuric acid was profitable at a Saudi Arabian location, even though it was not profitable at a U.S. Gulf Coast location.

Al-Jarallah, A.M.; Lee, A.K.K.

1988-07-01T23:59:59.000Z

23

Statoil outlines MTBE development program  

SciTech Connect (OSTI)

This paper reports that Norway's state oil company Den Norkse state Oljeselskap AS has outlined plans to become one of the major European producers of methyl tertiary butyl ether in the 1990s. Statoil predicts European demand for MTBE will jump to 4.5 million metric tons/year by 2000 from 2.5 million tons in 1990. Europe currently is a net importer of MTBE, with a productive capacity of 2.2 million tons/year.

Not Available

1991-11-25T23:59:59.000Z

24

Factors influencing biological treatment of MTBE contaminated ground water  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) contamination has complicated the remediation of gasoline contaminated sites. Many sites are using biological processes for ground water treatment and would like to apply the same technology to MTBE. However, the efficiency and reliability of MTBE biological treatment is not well documented. The objective of this study was to examine the operational and environmental variables influencing MTBE biotreatment. A fluidized bed reactor was installed at a fuel transfer station and used to treat ground water contaminated with MTBE and gasoline hydrocarbons. A complete set of chemical and operational data was collected during this study and a statistical approach was used to determine what variables were influencing MTBE treatment efficiency. It was found that MTBE treatment was more sensitive to up-set than gasoline hydrocarbon treatment. Events, such as excess iron accumulation, inhibited MTBE treatment, but not hydrocarbon treatment. Multiple regression analysis identified biomass accumulation and temperature as the most important variables controlling the efficiency of MTBE treatment. The influent concentration and loading of hydrocarbons, but not MTBE, also impacted MTBE treatment efficiency. The results of this study suggest guidelines for improving MTBE treatment. Long cell retention times in the reactor are necessary for maintaining MTBE treatment. The onset of nitrification only occurs when long cell retention times have been reached and can be used as an indicator in fixed film reactors that conditions favorable to MTBE treatment exist. Conversely, if the reactor can not nitrify, it is unlikely to have stable MTBE treatment.

Stringfellow, William T.; Hines Jr., Robert D.; Cockrum, Dirk K.; Kilkenny, Scott T.

2001-09-14T23:59:59.000Z

25

Evaluation and Optimization of MTBE Biodegradation in Aquifers, Final Report  

SciTech Connect (OSTI)

This study was focused on meeting the following objectives concerning the process of methyl tertiary butyl ether (MTBE) biodegradation, with the goal of optimizing this process in situ: 1. Assess whether intrinsic bioattenuation of MTBE is feasible under aerobic conditions across several contaminated sites. 2. Determine the effect of co-contaminants, specifically water-soluble gasoline components (most notably benzene, toluene, ethylbenzene and xylenes [BTEX]) on MTBE biodegradation. 3. Determine whether microbial and/or chemical factors contribute to different MTBE degradative activities. 4. Isolate and characterize MTBE-degrading microorganisms from sediments in which MTBE biodegradation was observed.

Legler, T; Balser, L; Koester, C; Wilson, W

2004-02-13T23:59:59.000Z

26

UMass builds bugs to eat MTBE ByAuriaCimino  

E-Print Network [OSTI]

UMass builds bugs to eat MTBE ByAuriaCimino STAfFWRITER An area university's process to destroy with methyl tertiary butyl ether (MTBE), which is found in gasoline. Once the first field trial is complete in particular has suffered from MTBE contamination because of the abundance of groundwater in the state, said

Lovley, Derek

27

Saudi MTBE project revived  

SciTech Connect (OSTI)

Alujain Corp., a member of the Xenel group of Saudi Arabia, is going ahead with plans to build an 800,000-m.t./year methyl tert-butyl ether (MTBE) plant. Bechtel has been appointed project manager for the plant, which will be owned by a new company, National Fuel Additives (Tahseen). Bechtel will help evaluate proposals already submitted for the lump sum turnkey job.

NONE

1996-01-17T23:59:59.000Z

28

MTBE, methanol prices rise  

SciTech Connect (OSTI)

After several months of drifting lower in line with declining autumn gasoline prices, tabs for methyl tert-butyl ether (MTBE) have turned around. There has been no big demand surge, but consumers and traders are beginning to build up inventories in advance of a series of midwinter shutdowns and turnarounds by producers. Spot prices, which dropped as low as 75 cts/gal, have rebounded to 90 cts/gal fob. Eager for a positive glimmer, methanol producers posted a 3-cts/gal increase in contract prices this month. It marks the first upward idea since February. In that time contract prices have dropped 75% from $1.55/gal to 39 cts/gal. A hard winter has hit early in much of the US sending natural gas prices up sharply. At the same time, formaldehyde and acetic acid markets remain firm, and with MTBE rebounding, methanol producers feel entitled to a piece of the action. {open_quotes}I don`t buy into this claim that MTBE demand is up and I don`t think producers can justify even a 3-cts/gal increase,{close_quotes} says one. {open_quotes}There is nothing in the economy to warrant a run-up. Housing starts are weaker, and demand is down at least 80,000 bbl/day with the MTBE shutdown.{close_quotes}

Morris, G.D.L.; Cornitius, T.

1995-12-20T23:59:59.000Z

29

MTBE -- A global perspective  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is a major and familiar component of Reformulated and Oxygenated gasoline in the US. As such, it is essential to the success of the Clean Air Act programs now reaching a crescendo in major urban areas. In less than ten years, US MTBE capacity has grown from about 4,000 B/D to more than 200,000 B/D. Outside of the USA, its role is less widely understood. Although MTBE markets elsewhere are much less driven by legislation, they have seen the same spectacular growth prospects. Overall, about as much MTBE is used today overseas as in the US. To date, this has to be one of the petrochemical industry`s major success stories. Yet today, the MTBE industry stands at a crossroads, with the direction of future development uncertain at best. DeWitt`s gasoline and oxygenates team has closely observed the ups and downs of this market during most of its turbulent history. In this paper, the authors shall try to set down the major developments and prospects, with the personal familiarity of having been there when things changed. The story begins with a brief historical sketch, leading up to the identification of four critical periods in which major changes took place. The causes of today`s uncertainty lie in all of these stages, and are in a very real sense an example of the ``Law of Unintended consequences.`` Having set the stage, a cautious set of predictions will be put forth. These are neither as promising as proponents would like, nor as unpromising as some would tend to believe.

Ludlow, W.I.; Miller, K.D. Jr.; Liew, R.E. van [DeWitt and Co., Inc., Houston, TX (United States)

1995-09-01T23:59:59.000Z

30

Snamprogetti signs MTBE contracts  

SciTech Connect (OSTI)

Snamprogetti (Milan) will use a Russian-developed dehydrogenation process in a world-scale methyl tert-butyl ether (MTBE) plant it is to build at Arzew, Algeria for a previously announced joint venture of Sonatrach (Algiers), Total (Paris), and Ecofuel (Milan). The 600,000-m.t./year plant will be the first in the West to use the improved Snamprogetti-Yarsintez fluidized-bed dehydrogenation (FBD) technology proven on a demonstration plant at Yaroslavl, Russia. The process has also been selected for use in Oxyfuel Corp.`s 500,000-m.t./year MTBE plant near Beaumont, TX. Although the environmental permit is already in place, final agreement for this project has not yet been signed.

Alperowicz, N.

1992-04-15T23:59:59.000Z

31

Analysis of dissolved benzene plumes and methyl tertiary butyl ether (MTBE) plumes in ground water at leaking underground fuel tank (LUFT) sites  

SciTech Connect (OSTI)

The 1990 Clean Air Act Amendments mandate the addition of oxygenates to gasoline products to abate air pollution. Currently, many areas of the country utilize oxygenated or reformulated fuel containing 15- percent and I I-percent MTBE by volume, respectively. This increased use of MTBE in gasoline products has resulted in accidental point source releases of MTBE containing gasoline products to ground water. Recent studies have shown MTBE to be frequently detected in samples of shallow ground water from urban areas throughout the United States (Squillace et al., 1995). Knowledge of the subsurface fate and transport of MTBE in ground water at leaking underground fuel tank (LUFT) sites and the spatial extent of MTBE plumes is needed to address these releases. The goal of this research is to utilize data from a large number of LUFT sites to gain insights into the fate, transport, and spatial extent of MTBE plumes. Specific goals include defining the spatial configuration of dissolved MTBE plumes, evaluating plume stability or degradation over time, evaluating the impact of point source releases of MTBE to ground water, and attempting to identify the controlling factors influencing the magnitude and extent of the MTBE plumes. We are examining the relationships between dissolved TPH, BTEX, and MTBE plumes at LUFT sites using parallel approaches of best professional judgment and a computer-aided plume model fitting procedure to determine plume parameters. Here we present our initial results comparing dissolved benzene and MTBE plumes lengths, the statistical significance of these results, and configuration of benzene and MTBE plumes at individual LUFT sites.

Happel, A.M.; Rice, D. [Lawrence Livermore National Lab., CA (United States); Beckenbach, E. [California Univ., Berkeley, CA (United States); Savalin, L.; Temko, H.; Rempel, R. [California State Water Resources Control Board, Sacramento, CA (United States); Dooher, B. [California Univ., Los Angeles, CA (United States)

1996-11-01T23:59:59.000Z

32

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

33

EPA proposal sets MTBE back  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) producers were looking for a boost from the official New Year`s start of EPA`s reformulated gasoline (RFG) program. But that prospect has been dimmed by an EPA-proposal-in reaction to concerns about RFG prices-to allow states to withdraw from the program. The states that have opted to out make up 5%-6% of the total RFG pool says Arthur Zadronzy, director/government outreach for MTBE producer Arco Chemical. {open_quotes}This is not a major hit, but it is one we have felt,{close_quotes} he says. Despite the state and EPA actions, MTBE producers are not worried about long-term consequences.

Lucas, A.

1995-01-04T23:59:59.000Z

34

Petrochem industry expands North American MTBE capacity  

SciTech Connect (OSTI)

This paper reports that petrochemical manufacturers continue to increase methyl tertiary butyl ether (MTBE) capacity in North America. The action reflects refiners' reformulation of gasoline to help reduce auto emissions. Demand for gasoline blending oxygenates such as MTBE is expected to increase as U.S. refiners reconfigure processing trains to produce fuels meeting requirements of the Clean Air Act amendments of 1990. Recent progress includes plans to build an MTBE plant in Mexico and start-ups of plants on the U.S. Gulf Coast and in Canada.

Not Available

1992-10-05T23:59:59.000Z

35

MTBE: Wild card in groundwater cleanup  

SciTech Connect (OSTI)

Subsurface releases of the gasoline oxygenate, methyl tertiary butyl ether (MTBE) seriously compromise the remediation and closure of properties that have ground water contaminated with BTEX and other conventional fuel hydrocarbon components. Although a manageable protocal for BTEX remediation is being set up, the MTBE problem continues to be difficult. This article discusses a new magnesium peroxide compound which could be part of the solution. Covered topics include oxygen release compound (ORC) enhance bioremediation and the role of oxygen and ORC in MTBE remediation. 1 fig.

Koenigsberg, S. [Regenesis Bioremediation Products, San Juan Capistrano, CA (United States)

1997-11-01T23:59:59.000Z

36

MTBE from butadiene-rich C/sub 4/s  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE), is made by reacting methanol with isobutylene. The preferred source of isobutylene is a steam cracker C/sub 4/ cut from which butadiene has been removed. However, moving the MTBE synthesis upstream of the butadiene extraction will improve the extraction step. The following is a review of conditions imposed on the MTBE unit's design and operation when placed in this new location.

Ancillotti, F.; Pescarollo, E.; Szatmari, E.; Lazar, L.

1987-12-01T23:59:59.000Z

37

MTBE still in poor health, despite the Clean Air Act  

SciTech Connect (OSTI)

After the second winter oxygenated fuels program of the 1990 Clean Air Act, producers of methyl tert-butyl ether (MTBE) are still feeling the chill of poor profitability. Despite the strong demand growth for MTBE to meet oxygen requirements in reformulated gasoline (RFG), oversupply still dogs the market. That, combined with a run-up in feedstock prices, has seen margins for MTBE markers all but evaporate. And it seems matters are likely to get worse before they get better. This week, Belvieu Environmental Fuels (BEF; Houston) expects to startup its 15,000-bbl/day MTBE plant at Mont Belvieu, TX. In late July, Texaco will start up its 15,000-bbl/day MTBE/propylene oxide (PO) plant at Port Neches, TX. In addition, a rash of refinery-based MTBE and tert-amyl methyl ether projects are nearing completion. {open_quotes}Profitability in MTBE has been extremely poor,{close_quotes} says Marvin O. Schlanger, president of Arco Chemical Americas, the largest MTBE producer. There has, however, been some recent recovery on the spot market, with MTBE moving from less than 60 cts/gal to near cash-cost levels of 70 cts/gal. But contract prices remain depressed, and strength in butane and methanol pricing have all buy wiped out any gains in MTBE.

Wood, A.

1994-05-25T23:59:59.000Z

38

Author's personal copy Automobile proximity and indoor residential concentrations of BTEX and MTBE  

E-Print Network [OSTI]

Author's personal copy Automobile proximity and indoor residential concentrations of BTEX and MTBE to indoor benzene and MTBE concentrations appeared to have been dominated by car exhaust concentrations of other BTEX components and methyl tert-butyl ether (MTBE) have been reported [5,6]. Up until

Siegel, Jeffrey

39

Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co-contaminants  

E-Print Network [OSTI]

Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co November 2005 Key words: aerobic, biodegradation, BTEX, co-contaminant, MTBE, TBA Abstract Contamination of groundwater with the gasoline additive methyl tert-butyl ether (MTBE) is often accompanied by many aromatic

40

MTBE still facing pressure from ethanol under latest fuel proposal  

SciTech Connect (OSTI)

The US EPA's finalized reformulated gasoline rule, part of Phase II of the 1990 Clean Air Act, signals a possible turnaround for the sluggish methyl tert-butyl ether (MTBE) market. But if a 30% renewable fuels proposal favoring ethanol passes, pressure could continue for MTBE.

Lucas, A.

1994-01-26T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

MTBE: Capacity boosts on hold amid demand concerns  

SciTech Connect (OSTI)

Uncertainty reigns in the methyl tert-butyl ether (MTBE) market. {open_quotes}We have no choice but to put our expansion plans on the back burner,{close_quotes} says one producer. {open_quotes}Because of government actions, there are no MTBE plants being built or expanded.{close_quotes} Spot MTBE prices have risen ti 82 cts- 83 cts/gal from 76 cts-78 cts/gal earlier this month as the demand for octane enhancement increases for the summer driving season. Some observers say EPA may relax different oxygen requirements for gasoline in different seasons. That would simplify production and supply for MTBE makers.

NONE

1995-05-03T23:59:59.000Z

42

MTBE: The headache of cleaner air  

SciTech Connect (OSTI)

Gasoline with methyl tertiary butyl ether (MTBE) has been sold in the United States since 1979, when it was added to fuels as an octane enhancer after lead was phased out of motor fuels. Recently it has been introduced as a means of reducing carbon monoxide emissions during the winter months in targeted US cities. However, there is concern over health complaints including headaches, dizziness and nausea from residents of some areas. These reports have launched an era of assidious research by scientists and public health officials across the country to learn more about MTBE`s short-term and long-term, and possibly carcinogenic, health effects. New research should help weigh the risk of MTBE as a possible carcinogen and the effectiveness of MTBE-blended fuels in reducing carbon monoxide levels. The question is whether, in minimizing one risk, is another risk - however small - being introduced?

Kneiss, J.

1995-07-01T23:59:59.000Z

43

Global developments in MTBE  

SciTech Connect (OSTI)

This paper is intended to provide an overview of some of the recent developments in MTBE demand growth worldwide and the impact of these developments on MTBE demand in the future. It provides a perspective of the influence of developments in the US on the worldwide MTBE markets. The public`s outcry regarding oxygenates in gasoline, and specifically MTBE, that has been evolving in the US during the past several months is in response to a politically mandated requirement for a fuel that contains oxygen that is provided by MTBE or ethanol. This public unrest had negatively impacted the market price for MTBE at the time this paper was being prepared. However, the author believes that MTBE, because of its clean octane capabilities, will continue to be used as an octane blendstock for gasoline in increasing quantities worldwide as we move through lead phasedown in West Europe and other countries that are experiencing pollution problems relating to exhaust emissions from internal combustion engines. The objectives of this paper are as follows: review developments in MTBE demand 1990--2000; identify regions where MTBE demand growth will occur; review production growth for MTBE, both historical and forecast; examine world trade patterns during the period; assess methanol demand growth during the period; analyze MTBE`s regional price bias; and provide a forecast of future MTBE price trends.

Feller, L.W. [CMAI, Houston, TX (United States)

1995-12-31T23:59:59.000Z

44

Experimental Pathology Laboratories, Inc. Methyl-Tertiary-Butyl Ether  

E-Print Network [OSTI]

COORDINATOR'S REPORT FOR LIFETIME CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE-DAWLEY RATS CONDUCTED AT THE CANCER

Baker, Chris I.

45

Falling MTBE demand bursts the methanol bubble  

SciTech Connect (OSTI)

Methanol spot markets in Europe and the US have been hit hard by weakening demand from methyl tert-butyl ether (MTBE) producers. In Europe, spot prices for domestic T2 product have dropped to DM620-DM630/m.t. fob from early-January prices above DM800/m.t. and US spot prices have slipped to $1.05/gal fob from $1.35/gal. While chemical applications for methanol show sustained demand, sharp methanol hikes during 1994 have priced MTBE out of the gasoline-additive market. {open_quotes}We`ve learned an important lesson. We killed [MTBE] applications in the rest of the world,{close_quotes} says one European methanol producer. Even with methanol currently at DM620/m.t., another manufacturer points out, MTBE production costs still total $300/m.t., $30/m.t. more than MTBE spot prices. Since late 1994, Europe`s 3.3-million m.t./year MTBE production has been cut back 30%.

Wiesmann, G.; Cornitius, T.

1995-03-01T23:59:59.000Z

46

Add MTBE unit ahead of alkylation  

SciTech Connect (OSTI)

Approximately three years ago, the people at Diamond Shamrock's Sunray, Texas, refinery recognized a growing demand for high octane super premium unleaded gasoline in their regional marketing area. It was apparent that they would need to change their processing scheme to meet this growing demand. After investigating several options, they decided to install an MTBE (methyl tert-butyl ether) unit upstream of their existing sulfuric acid (H/sub 2/SO/sub 4/) aklylation unit. The new unit would process olefin feed before it entered the alkylation unit. The MTBE unit was expected to improve Diamond Shamrock's gasoline pool in two ways. First, the MTBE would be an additional high octane blending stock for the gasoline pool. Second, the MTBE unit would improve the quality of the olefin stream going to the alkylation unit. Diamond Shamrock brought their MTBE unit onstream in December, 1985. The results of the combined operation exceeded expectations, producing alkylate in excess of 98 RON (Research octane number) and MTBE of 118 RON. These components significantly upgraded the refinery's capability to produce a super premium unleaded gasoline.

Masters, K.R.; Prohaska, E.A.

1988-08-01T23:59:59.000Z

47

The MTBE solution: Octanes, technology, and refinery profitability  

SciTech Connect (OSTI)

This paper has been developed to provide refiners with business decision insight regarding the production of methyl tertiary butyl ether (MTBE) from refinery - (FCC) produced isobutylene. The driving forces making MTBE an attractive investment are examined with regard to the increasing demand for higher octane unleaded gasolines. The decision to proceed with MTBE production depends on the profitability of such an investment and the refiner's ability to meet market demands using available processing equipment, refinery produced streams and external feedstocks. The factors affecting this decision are analyzed in this paper and include: industry ability to meet rising octane demand; profit potential realized by diverting isobutylene to MTBE; availability of technology for producing MTBE; and investment and operating costs required to produce MTBE. Chemical Research and Licensing and NEOCHEM have developed a simple, low cost process to produce MTBE, reducing the excessive equipment and high operating costs that were associated with conventional MTBE designs. The economics and process benefits of installing a CRandL/NEOCHEM MTBE process are examined within the framework of a generalized medium-sized refinery configuration.

Lander, E.P.; Hubbard, J.N.; Smith, L.A.

1983-03-01T23:59:59.000Z

48

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

49

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

50

Veba in MTBE project, cutting aromatics  

SciTech Connect (OSTI)

The new owners of the refinery and petrochemical complex at Schwedt in eastern Germany-RWE-DEA (Hamburg), Veba Oel (Gelsenkirchen), Agip (Rome), Total (Paris), and Elf-Aquitaine (Paris)-plan to build a 60,000-m.t./year methyl tert-butyl ether (MTBE) plant at the site for 1994-1995 completion. The MTBE project forms part of the consortium`s announced DM1.5-billion ($500 million) investment program for the complex that aims to raise refinery throughput from 8 million m.t./year to 12 million m.t./year by 1994 and hike production of naphtha and benzene.

Young, I.; Roberts, M.

1992-04-15T23:59:59.000Z

51

Methanex considers methanol, MTBE in Qatar  

SciTech Connect (OSTI)

CW has learned that Methanex Corp. is considering entering one of two methanol and methyl tert-butyl ether (MTBE) projects in Qatar. Executive v.p. Michael Wilson says that part of the company`s New Zealand plant could be moved to a site in Qatar, which would lower capital costs for the possible project by $75 million-$100 million. Both Qatar General Petroleum Corp. and Qatar Fuel Additives are developing methanol and MTBE projects at Umm Said, Qatar. Methanex says its goal is to ensure low-cost feedstocks.

NONE

1995-12-13T23:59:59.000Z

52

Total to withdraw from Qatar methanol - MTBE?  

SciTech Connect (OSTI)

Total is rumored to be withdrawing from the $700-million methanol and methyl tert-butyl ether (MTBE) Qatar Fuel Additives Co., (Qafac) project. The French company has a 12.5% stake in the project. Similar equity is held by three other foreign investors: Canada`s International Octane, Taiwan`s Chinese Petroleum Corp., and Lee Change Yung Chemical Industrial Corp. Total is said to want Qafac to concentrate on methanol only. The project involves plant unit sizes of 610,000 m.t./year of MTBE and 825,000 m.t./year of methanol. Total declines to comment.

NONE

1996-05-01T23:59:59.000Z

53

Drinking Water Problems: MTBE  

E-Print Network [OSTI]

. This compound belongs to a chemical family of fuel oxygenates that enhance gaso- line combustion by increasing oxygen available for the process. Added to gasoline, MTBE has reduced carbon monoxide and ozone emissions by promoting more complete burning.... Texas follows the EPA drinking water advisory of 20 to 40 micrograms per liter. How can MTBE be Removed from Well Water? MTBE requires a specific treatment process for removal from water. Well owners can use granular activated carbon or charcoal...

Dozier, Monty; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

54

Ecological hazards of MTBE exposure: A research agenda  

SciTech Connect (OSTI)

Fuel oxygenates are used in metropolitan areas across the United States in order to reduce the amount of carbon monoxide released into the atmosphere during the winter. The most commonly used fuel oxygenate is Methyl tert-butyl ether (MTBE). Its widespread use has resulted in releases into the environment. To date there has been only minimal effort to investigate ecological impacts caused by exposure to concentrations of MTBE typically found in environmental media. Research into the potential for MTBE to adversely affect ecological receptors is essential. Acquisition of such baselines data is especially critical in light of continuing inputs and potential accumulation of MTBE in environmental media. A research Agenda is included in this report and addresses: Assessing Ecological Impacts, Potential Ecological Impacts of MTBE (aquatic organisms, terrestrial organisms), Potential Ecological Endpoints, and A Summary of Research Needs.

Carlsen, T.; Hall, L.; Rice, D.

1997-03-01T23:59:59.000Z

55

Korean oxygenates rule sparks MTBE capacity plans  

SciTech Connect (OSTI)

The Korean government`s strict standard for gasoline sold domestically is expected to have a significant impact on the methyl tert-butyl ether (MTBE) market. The mandate-requiring gasoline oxygen content of 0.5% this year, 0.75% by 1996, and 1.0% by 1998-has sparked a rush by Korean refineries to build new MTBE plants. If expansion plans are carried out, Korea`s MTBE capacity will increase from 280,000 m.t./year to 650,000 m.t./year by 1996, far surpassing predicted demand. Honam Oil, part of the Lucky Group, plans startup of a 100,000-m.t./year unit at Yeochon by early 1996. In addition, by the end of 1996 Ssangyong Oil will bring a 100,000-m.t./year unit onstream.

Kim, Hyung-Jin

1994-06-15T23:59:59.000Z

56

Ecofuel plans MTBE plant in Italy  

SciTech Connect (OSTI)

Ecofuel (Milan), an ENI company, is evaluating construction of a new methyl tert-butyl ether (MTBE) plant in Italy, but has shelved plans for a world-scale MTBE unit in Mexico. The Italian unit is tied to ethylene expansion now under way. Later this year EniChem (Milan), a sister company, is due to complete construction of a 360,000-m.t./year cracker at Brindisi. The C{sub 4} stream available there and from the existing cracker at Priolo in Sicily should provide enough feed for a unit of up to 100,000 m.t./year of MTBE capacity. Some of the feedstock could also come from the Ravenna cracker.

Alperowicz, N.

1992-04-29T23:59:59.000Z

57

Health studies indicate MTBE is safe gasoline additive  

SciTech Connect (OSTI)

Implementation of the oxygenated fuels program by EPA in 39 metropolitan areas, including Fairbanks and Anchorage, Alaska, in the winter of 1992, encountered some unexpected difficulties. Complaints of headaches, dizziness, nausea, and irritated eyes started in Fairbanks, jumped to Anchorage, and popped up in various locations in the lower 48 states. The suspected culprit behind these complaints was the main additive for oxygenation of gasoline is methyl tert-butyl ether (MTBE). A test program, hastily organized in response to these complaints, has indicated that MTBE is a safe gasoline additive. However, official certification of the safety of MTBE is still awaited.

Anderson, E.V.

1993-09-01T23:59:59.000Z

58

MTBE growth limited despite lead phasedown in gasoline  

SciTech Connect (OSTI)

This month's legislated reduction of the allowable amount of lead additives in gasoline will increase demand strongly for methyl-tert-butyl ether (MTBE) as an octane enhancer, but the economics of the refinery business and the likelihood of rapidly increasing high-octane gasoline imports probably will limit the size of the business in coming years. MTBE will be used to fill the octane gap now, but economics and imports of gasoline later on could hold down demand. The limited growth in sales of MTBE is discussed.

Storck, W.

1985-07-15T23:59:59.000Z

59

Trichloroethene Removal From Waste Gases in Anaerobic Biotrickling Filters Through Reductive Dechlorination  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE) vapors into water was used.MTBE is highly soluble in water (dimensionless Henrysgas stream was laden with MTBE vapors (200-300 mg m -3 )

Popat, Sudeep Chandrakant

2010-01-01T23:59:59.000Z

60

Mercury Methylation in Mine Wastes Collected from Abandoned Mercury Mines in the USA  

SciTech Connect (OSTI)

Mercury mines contain highly elevated Hg contents, but more problematic environmentally are elemental Hg and soluble Hg salts produced during ore retorting that remain in wastes at mine sites. Under certain conditions, these inorganic Hg compounds convert to bioavailable, highly toxic organic Hg forms. Speciation and transformation of Hg was studied in wastes collected from abandoned Hg mines at McDermitt, NV, and Terlingua, TX, which are moderate size on an international scale and produced about 10,000 and 5,000 t of elemental Hg, respectively. In waste samples, we measured total Hg and methyl-Hg contents, identified various Hg compounds using Hg-thermo-desorption pyrolysis, and determined rates of Hg methylation and methyl-Hg demethylation using isotopic-tracer methods. Pyrolysis analysis of mine wastes showed variable amounts of cinnabar, metacinnabar, Hg salts, elemental Hg, and elemental Hg sorbed onto particulates such as clay and Fe-oxides. Mine wastes with the highest methyl-Hg contents correspond to those with elemental Hg and particulate-sorbed elemental Hg, and also produced the highest laboratory-estimated potential Hg methylation rates, as much as 4.8%/day. Samples containing dominantly cinnabar showed little or no Hg methylation. Mine wastes with high methyl-Hg contents generally showed low methyl-Hg demethylation, suggesting that Hg methylation was dominant. Both mines are located in semiarid climates, and during this study, streambeds below the mines were dry. Total Hg contents in stream sediment collected below the mines show significant dilution, and methyl-Hg contents were typically below the limit of determination. Methylation of Hg downstream from Hg mines is probably lower in arid climates due to lack of mine-water runoff and lower microbial activity. The correspondence of mine wastes containing elemental Hg and high methyl-Hg contents suggests that Hg0 oxidizes to Hg2+, which is subsequently bioavailable for microbial Hg methylation.

Gray, John E. (U.S. Geological Survey); Hines, Mark E. (Massachusetts, Univ Of); Biester, Harald (Heidelberg College); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

2003-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

MTBE, ethanol rules come under fire  

SciTech Connect (OSTI)

EPA is facing stiff challenges to the mandates for methyl tert-butyl ether (MTBE) and ethanol in its reformulated gasoline (RFG) program. Wisconsin officials are receiving hundreds of complaints about the alleged health effects and other problems with MTBE added to gasoline, and Gov. Tommy Thompson is demanding that EPA suspend the RFG program until April 1. Rep. James Sensenbrenner (R., WI) is threatening to introduce a bill to repeal the program in Wisconsin if EPA does not comply. However, EPA administrator Carol Browner says the agency will {open_quotes}defer any decision{close_quotes} on the request. EPA has sent technical experts to Milwaukee to respond to and monitor citizens` complaints.

Begley, R.

1995-03-01T23:59:59.000Z

62

Modeling the atmospheric inputs of MTBE to groundwater systems  

SciTech Connect (OSTI)

A numerical transport model was used to calculate the movement of methyl-t-butyl ether (MTBE) and several other volatile organic compounds (VOCs) from the atmosphere downward through the unsaturated zone and into shallow groundwater. Simulations were carried out for periods as long as 10 years to investigate whether a gaseous atmospheric MTBE source at typical ambient concentrations could account for the presence of MTBE in shallow groundwater at the types of low ug/L levels that have been found during the National Water Quality Assessment Program currently being conducted by the US Geological Survey. The simulations indicate that downward movement of MTBE to shallow groundwater will be very slow when there is no net downward movement of water through the vadose zone. For example, for a vadose zone composed of fine sand, and assuming tens of cm of infiltration, then only a few years will be required for water at a water table that is 5.0 m below ground surface to attain MTBE levels that correspond to saturation with respect to the atmospheric source gaseous concentration. An on/off atmospheric source, as might occur in the seasonal use of MTBE, will lead to concentrations in shallow groundwater that correspond to saturation with the time-averaging atmospheric source concentration.

Pankow, J.F.; Johnson, R.L. [Oregon Graduate Inst., Portland, OR (United States). Dept. of Environmental Science and Engineering; Thomson, N.R. [Univ. of Waterloo, Ontario (Canada). Dept. of Civil Engineering

1995-12-31T23:59:59.000Z

63

Remediation of MTBE in groundwater: A case where pump-and-treat works  

SciTech Connect (OSTI)

Two case studies are discussed in which groundwater pumping reduced levels of dissolved methyl tertiary butyl ether (MTBE) in groundwater by more than two orders of magnitude, in some cases to below detection limits. MTBE contamination in groundwater is becoming an important issue due to the increasing prevalence and regulation of this gasoline additive. In addition, MTBE is more mobile in groundwater than most hydrocarbons, so it is usually the first gasoline constituent to reach sensitive receptors. Since its Henry`s constant is low, in situ removal of MTBE from groundwater by air sparging is slow, and MTBE does not rapidly degrade, either biologically or abiotically. Therefore, groundwater pumping is usually employed to contain and collect MTBE-contaminated groundwater. Pumping groundwater can reduce MME levels to below detection limits within a few years, because MTBE in the subsurface is found mostly dissolved in groundwater. In contrast, the more hydrophobic gasoline hydrocarbons exist mostly in pockets of separate phase material and adsorbed to soil particles and dissolve slowly in groundwater. Hydrocarbon concentrations are rarely reduced to closure levels within a reasonable time frame by pumping. Sites in eastern Massachusetts and southern New Jersey, where groundwater was contaminated with MTBE due to releases of unleaded gasoline from underground storage tanks, are discussed. At these sites, average MTBE levels were reduced by two to three orders of magnitude, from several ppm or more to less than 10 ppb within three years by pumping groundwater at 10 to 30 gpm.

Bass, D.H.; Riley, B. [Groundwater Technology, Inc., Norwood, MA (United States); Farrell, T. [Groundwater Technology, Inc., Trenton, NJ (United States)

1994-12-31T23:59:59.000Z

64

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 2.  

E-Print Network [OSTI]

vapors of methyl tert-butyl ether (MTBE), a gasoline additive of great environmental concern MTBE treatment are discussed. Introduction The rapidly rising number of reports of groundwater con- taminated with the gasoline additive methyl tert-butyl ether (MTBE) has raised concerns about its

65

Health risks associated with exposure to gasoline additives-methyl tertiary butyl ether [MTBE]. Hearing before a Subcommittee of the Committee on Appropriations, United States Senate, One Hundred Third Congress, First Session, Special Hearing  

SciTech Connect (OSTI)

This hearing focuses on an Alaskan study by the Centers for Disease Control which examines possible health risks associated with exposure to gasoline additive know as MTBE. Testimony is given by Dr. William Roper, Director, CDC.

Not Available

1993-01-01T23:59:59.000Z

66

Race to license new MTBE and TAME routes heats up  

SciTech Connect (OSTI)

With refineries and petrochemical manufacturers continuing to gear up production of oxygenates for use in reformulated fuels, new routes to methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME) are clearly hot items in the licensing market. And probably nowhere has the competition become as intense as in offerings for skeletal isomerization technologies to boost ethers production from fluid catalytic cracking and steam cracking.

Rotman, D.

1993-01-06T23:59:59.000Z

67

Meeting the challenge of MTBE biodegradation  

SciTech Connect (OSTI)

Oxygenated and reformulated gasolines have been developed in response to air pollution control regulations targeted at reducing carbon monoxide emissions and photochemical air pollution. The 1990 Clean Air Act Amendments required the addition of fuel oxygenates to gasoline in areas where the level of carbon monoxide exceeded national ambient air quality standards. In the South Coast Air Basin gasoline containing oxygenated compounds has been in use since the late 1980`s. One oxygenated fuel additive most often selected by producers to meet the requirements is methyl tert-butyl ether (MTBE). However, large production numbers associated with MTBE production, combined with the compound`s high water solubility, chemical stability, and toxicity, make it a potentially important groundwater pollutant. The County Sanitation District of Los Angeles, Joint Water Pollution Control Plant in Carson, California is one of the few wastewater treatment plants in the nation that receives refinery wastewater discharge. It has operated several pilot-scale compost-based biofilters for control of various volatile organic contaminants throughout the plant since a 1991 joint study with the University of California, Davis. After one year of operation, one of the biofilters spontaneously developed the ability to degrade MTBE. The paper describes the collaborative efforts to determine the feasibility of transferring the degrading microbial population from the solid to liquid phase, without loss of activity, and to determine some of the environmental requirements necessary for survival of the microbial culture.

Eweis, J.B.; Chang, D.P.Y.; Schroeder, E.D.; Scow, K.M. [Univ. of California, Davis, CA (United States); Morton, R.L.; Caballero, R.C. [Los Angeles County Sanitation Districts, Carson, CA (United States). Joint Water Pollution Control Plant

1997-12-31T23:59:59.000Z

68

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

69

US refiners choose variety of routes to MTBE  

SciTech Connect (OSTI)

This paper reports that refiners and merchant manufacturers in the U.S. are gearing up to produce the large volumes of methyl tertiary butyl ether (MTBE) needed to comply with oxygenated gasoline requirements. The 1990 U.S. Clean Air Act Amendments specify that, as of the first of this coming November, gasoline containing a minimum of 2.7 wt % oxygen must be sold in 39 CO-nonattainment cities. Refiners and others are scurrying to bring MTBE capacity on line in time to meet this requirement. Many U.S. refiners already have some operating MTBE capacity, but this will not be nearly enough to meet the looming increase in demand. As a result, additional capacity is being constructed worldwide.

Rhodes, A.K.

1992-09-07T23:59:59.000Z

70

Effect of lower feedstock prices on economics of MTBE complex  

SciTech Connect (OSTI)

Economic evaluation of the methyl tertiary butyl ether (MTBE) complex was carried out starting from n-butane and by captive production of methanol from natural gas. The processing steps consist of isomerization of n-butane to isobutane, dehydrogenation of isobutane to make isobutene, and finally, the reaction of isobutene with methanol to produce MTBE. Two different plant sizes were considered, and the effect of 30% lower feedback prices on profitability was studied. It was found that the raw materials cost is a dominant component, composing about 55% of the total production cost. An internal rate of return of 19% could be realized for 500,000 tons per annum MTBE complex based on economic data in mid-1993. The payback period estimated at this capacity was 3.8 years, and the break-even capacity was 36.6%.

Rahman, F.; Hamid, S.H.; Ali, M.A. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia)

1996-01-01T23:59:59.000Z

71

Treatment of methyl tert-butyl ether vapors in biotrickling filters. 1. Reactor startup, steady-state performance, and culture characteristics  

SciTech Connect (OSTI)

An aerobic microbial consortium able to biodegrade methyl tert-butyl ether (MTBE) was enriched in two waste air biotrickling filters after continuous operation for 6 months. After this acclimation phase, the two laboratory-scale biotrickling filters were able to degrade up to 50 g of MTBE per cubic meter of reactor per hour, a value comparable to other gasoline constituents. Such high performance could be sustained for at least 4--6 weeks. After the acclimation phase, the MTBE degrading biotrickling filters were characterized by their almost full conversion of MTBE to carbon dioxide and the absence of any degradation byproducts in either the gas or the liquid phase. They also exhibited a very high specific degradation activity per amount of biomass, and a low rate of biomass accumulation. An observed biomass yield of 0.1 g g{sup {minus}1} and a specific growth rate of 0.025 day{sup {minus}1} were determined for the biotrickling filter process culture. Further data on MTBE mass transfer and on the dynamic behavior of the biotrickling filter are presented in part 2 of this paper. Overall, the results demonstrate that MTBE can be effectively biodegraded under carefully controlled environmental conditions.

Fortin, N.Y.; Deshusses, M.A. [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering] [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering

1999-09-01T23:59:59.000Z

72

A near infrared regression model for octane measurements in gasolines which contain MTBE  

SciTech Connect (OSTI)

Near infrared (NIR) spectroscopy has emerged as a superior technique for the on-line determination of octane during the blending of gasoline. This results from the numerous advantages that NIR spectroscopy has over conventional on-line instrumentation. Methyl t-butyl ether (MTBE) is currently the oxygenated blending component of choice. MTBE is advantageous because it has a high blending octane, a low Reid vapor pressure, is relatively cheap, and does not form peroxides (1). The goal of this project was to develop a NIR regression model that could be used to predict pump octanes regardless of whether they contained MTBE.

Maggard, S.M. (Ashland Petroleum Co., KY (USA))

1990-01-01T23:59:59.000Z

73

Oxygenates du`jour...MTBE? Ethanol? ETBE?  

SciTech Connect (OSTI)

There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

Wolfe, R.

1995-12-31T23:59:59.000Z

74

Detections of MTBE in surficial and bedrock aquifers in New England  

SciTech Connect (OSTI)

The gasoline additive methyl tert-butyl ether (MTBE) was detected in 24% of water samples collected from surficial and bedrock aquifers in areas of New England. MTBE was the most frequently detected volatile organic compound among the 60 volatile chemicals analyzed and was present in 33 of 133 wells sampled from July 1993 through September 1995. The median MTBE concentration measured in ground-water samples was 0.45 microgram per liter and concentrations ranged from 0.2 to 5.8 microgram per liter. The network of wells sampled for MTBE consisted of 103 monitoring wells screened in surficial sand-and-gravel aquifers and 30 domestic-supply wells in fractured crystalline bedrock aquifers. Seventy-seven percent of all MTBE detections were from 26 shallow monitoring wells screened in surficial aquifers. MTBE was detected in42% of monitoring wells in urban areas. In agricultural areas, MTBE was detected i 8% (2 of 24) of wells and was not detected in undeveloped areas. Sixty-two percent of the MTBE detections in surficial aquifers were from wells within 0.25 mile of gasoline stations or underground gasoline storage tanks; all but one of these wells were in Connecticut and Massachusetts, where reformulated gasoline is used. MTBE was detected in 23% of deep domestic-supply wells that tapped fractured bedrock aquifers. MTBE was detected in bedrock wells only in Connecticut and Massachusetts; land use near the wells was suburban to rural, and none of the sampled bedrock wells were within 0.25 mile of a gasoline station.

Grady, S.J. [Geological Survey, Hartford, CT (United States)

1995-12-31T23:59:59.000Z

75

Remediation of overlapping benzene/MTBE and MTBE-only plumes: A case study  

SciTech Connect (OSTI)

Two overlapping dissolved hydrocarbon plumes were identified in the shallow water-bearing zone at a commercial vehicle service and fueling facility. Plume 1 originated from a pre-1993 gasoline product line/dispenser leak. This plume contained a relatively common mix of benzene, toluene, ethylbenzene, xylenes (BTEX), and methyl tert-butyl ether (MTBE); benzene and MTBE were identified as the Plume 1 contaminants of concern based on their detection at approximately 200 {mu}g/l each, which exceeded regulatory guidance. Plume 2, which was detected in the tank cavity during UST removal, resulted from gasoline line leaks/underground storage tank overfills. Although the majority of impacted soils in both the dispenser and tank cavity areas were removed during UST excavation, rainfall during impacted soil removal mobilized the MTBE contained in the soils to groundwater. As a result, Plume 2 contained approximately 900 {mu}g/l MTBE while BTEX compounds were non-detect. Although the impacted zone sustained an approximate yield of only 0.3 gallon per minute, Pennsylvania regulations dictate that this zone must be treated as an aquifer. The failure of remediating gasoline plumes using pump-and-treat has been predominantly due to BTEX`s tendency to adsorb onto soil, creating a residual-phase product layer which acts as a continuing source of dissolved-phase BTEX. Based on this experience, most groundwater and remediation professionals reject pump-and-treat as a viable remedial option, except in situations where controlling groundwater movement is the predominant goal.

Carpenter, P.L. [TolTest, Inc., Pittsburgh, PA (United States); Vinch, C.A. [Ryder Transportation Services, Lawrenceville, NJ (United States)

1997-12-31T23:59:59.000Z

76

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network [OSTI]

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

77

Lyondell`s new isobutylene route could fuel an MTBE capacity boost  

SciTech Connect (OSTI)

Driven by the hot growth prospects for methyl tert-butyl ether (MTBE), Lyondell Petrochemical (Houston) has developed a route to isobutylene it claims can produce the MTBE feedstock at half the capital cost of alternative synthesis technology. If proved, the process will be used in a new 7500-10,000 bbl/day MTBE plant at Channelview, TX. Lyondell also hopes to license the technology. {open_quotes}With expanding MTBE capacity, we will have to have new routes to isobutylene,{close_quotes} says Bob G. Gower, president and CEO of Lyondell. {open_quotes}We think this is a good fit within Lyondell, but also that it is important technology.{close_quotes} Gower declines to detail its specifics, but says it is a one-step isomerization of n-butenes to isobutylene. The firm has tested the process at a pilot unit and plans a demonstration unit in 1992.

Rotman, D.; Wood, A.

1992-03-25T23:59:59.000Z

78

Synthesis of MTBE during CO hydrogenation: Reaction sites required  

SciTech Connect (OSTI)

Synthesis of methyl tert-butyl ether (MTBE) during carbon monoxide (CO) hydrogenation has been studied with the following reaction schemes: (1) the addition of isobutylene during CO hydrogenation over metal catalysts active for methanol synthesis (Pd/SiO{sub 2} and Li-Pd/SiO{sub 2}) and (2) the addition of isobutylene during CO hydrogenation over a dual bed configuration consisting of Li-Pd/SiO{sub 2} and a zeolite (H-ZSM-5 or HY). The addition of isobutylene during methanol synthesis over the supported Pd catalysts indicated that MTBE cannot be formed on metal sites from a reaction of isobutylene with methanol precursors. However, addition of isobutylene to the syngas feed over a dual bed consisting of a methanol synthesis catalyst and an acid zeolite downstream of the methanol synthesis catalyst showed that MTBE can be synthesized during CO hydrogenation provided acid sites are available. In order to get higher conversions of methanol to MTBE, optimization of the acid catalyst and/or reaction conditions would be required to minimize formation of byproduct hydrocarbons.

Kazi, A.M.; Goodwin, J.G. Jr.; Marcelin, G.; Oukaci, R. [Univ. of Pittsburgh, PA (United States). Dept. of Chemical and Petroleum Engineering

1995-03-01T23:59:59.000Z

79

Iran plans huge private sector MTBE plant  

SciTech Connect (OSTI)

An export-oriented 1-million m.t./year methyl tert-butyl ether (MTBE) plant is planned as one of Iran`s private sector investment projects. State-owned National Petrochemical Co (NPC; Tehran) and the Dubai-based Iranian businessman Abdul Wahab Galadari have signed a letter of intent allowing Galadari to develop the venture. Colt Engineering (Calgary, AL) is assisting Galadari with costs, planning and technology selection for the estimated $300-million plus venture. An important meeting with NPC is scheduled end of this month, says Galadari, and a financial package should be put together by end of March or April. The facility will most likely be wholly-owned by the Galadari family, roughly 50% by members resident in Iran and the remainder by the Dubai-based concern A.W. Galadari Sons. NPC says it may take a token shareholding in the venture.

Alperowicz, N.

1992-01-15T23:59:59.000Z

80

Treatment of methyl t-butyl ether contaminated water using a dense medium plasma reactor, a mechanistic and kinetic investigation  

E-Print Network [OSTI]

and oxidation mechanisms of methyl t-butyl ether (MTBE) in a dense medium plasma (DMP) reactor utilizing gas for the removal of MTBE from an aqueous solution in the DMP reactor. Rate constants are also derived for three reactor configurations and two pin array spin rates. The oxidation products from the treatment of MTBE

Dandy, David

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

MTBE will be a boon to U. S. gas processors  

SciTech Connect (OSTI)

This paper reports that the advent of methyl tertiary butyl ether (MTBE) as the primary oxygenate blending component for oxygenated and reformulated motor fuels promises significant benefits for the U.S. gas-processing industry. Increased demand for isobutane as MTBE-plant feedstock will buoy both normal butane and isobutane pricing in U.S. gulf Coast during the 1990s. Elimination of the need to crack normal butane in U.S. olefin plants will also strengthen competitive feedstocks somewhat, including ethane and propane. And increased use of normal butane as isomerization feedstock will result in wider recognition of the premium quality of gas plant normal butane production compared to most refinery C[sub 4] production.

Otto, K.W. (Purvin and Gertz, Inc. Dallas, TX (United States))

1993-01-11T23:59:59.000Z

82

MTBE movements between Texas Gulf Coast plants to be enhanced  

SciTech Connect (OSTI)

This paper reports that Texas Eastern Products Pipeline Co. (Teppco), Houston, has begun construction of its shuttle pipeline, a 10-mile, 6 and 8-in. line to move methyl tertiary butyl ether (MTBE) between producers and refiners along the Houston Ship Channel. Funding for the project has been approved, rights-of-way are secured, and procurement of materials is under way, according to Teppco. The line will flow from the western edge of Shell's refinery eastward to storage facilities of Teppco's Baytown terminal. The shuttle pipeline anticipates the US requirement for oxygenated gasolines that takes effect Nov. 1. Approximately 70% of the available US merchant capacity for MTBE is located along the shuttle's path, Teppco says.

Not Available

1992-07-27T23:59:59.000Z

83

The Social Costs of an MTBE Ban in California  

E-Print Network [OSTI]

349 The Social Costs of an MTBE Ban in California REFERENCESD.E. Rolston. Impacts of MTBE on California Groundwater. Environmental Assessment of MTBE, Vol. 4. A. Keller et al. ,

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

84

Effects of temperature and acidic pre-treatment on Fenton-driven oxidation of MTBE-spent granular activated carbon  

SciTech Connect (OSTI)

The effects of temperature and acidic pretreatment on Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC, derived from bituminous coal) were investigated. Limiting factors in MTBE removal in GAC include the heterogeneous distribution of amended Fe, and slow intraparticle diffusive transport of MTBE and hydrogen peroxide (H{sub 2}O{sub 2}) into the 'reactive zone'. Acid pretreatment of GAC before Fe amendment altered the surface chemistry of the GAC, lowered the pH point of zero charge, and resulted in greater penetration and more uniform distribution of Fe in GAC. This led to a condition where Fe, MTBE, and H{sub 2}O{sub 2} coexisted over a larger volume of the GAC contributing to greater MTBE oxidation and removal. H{sub 2}O{sub 2} reaction and MTBE removal in GAC increased with temperature. Modeling H{sub 2}O{sub 2} transport and reaction in GAC indicated that H{sub 2}O{sub 2} penetration was inversely proportional with temperature and tortuosity, and occurred over a larger fraction of the total volume of small GAC particles (0.3 mm diameter) relative to large particles (1.2 mm diameter). Acidic pretreatment of GAC, Fe-amendment, elevated reaction temperature, and use of small GAC particles are operational parameters that improve Fenton-driven oxidation of MTBE in GAC. 29 refs., 6 figs., 1 tab.

Kan, E.; Huling, S.G. [Robert S. Kerr Environmental Research Center, Ada, OK (United States)

2009-03-01T23:59:59.000Z

85

MTBE catalyst shows increased conversion in commercial unit  

SciTech Connect (OSTI)

Rising demand for methyl tertiary butyl ether (MTBE) has spawned interest in finding a cost-effective means of increasing production from existing units. A commercial trial of an improved MTBE catalyst was conducted recently at Lyondell Petrochemical Co.'s Channelview, Tex., plant. The new catalyst called Amberlyst 35 Wet, enhanced oxygenate production in the Lyondell trial. The new catalyst changes the activity coefficients of at least one of the components of the MTBE reaction, resulting in higher equilibrium conversion relative to its first-generation counterpart. Key catalyst properties are: particle size, 0.4--1.25 mm; Apparent density, 0.82 g/ml; Surface area, 44 sq m/g; Moisture content, 56%; Concentration of acid sites, 1.9 meq/ml (5.4 meq/g); Porosity, 0.35 cc/g; and Average pore diameter, 300 [angstrom]. Suggested operating conditions are: maximum temperature, 284 F (140 C); minimum bed depth, 24 in. (0.61 m); and liquid hourly space velocity (LHSV), 1--5 hr[sup [minus]1].

Not Available

1994-10-10T23:59:59.000Z

86

Review of the environmental behavior and fate of methyl tert-butyl ether  

SciTech Connect (OSTI)

A review of pertinent equations and current research indicates that when gasoline oxygenated with methyl tert-butyl ether (MTBE) comes into contact with water, large amounts of MTBe can dissolve. At 25 C, the water solubility of MTBE is about 5,000 mg/L for a gasoline that is 10% MTBE by weight, whereas for a nonoxygenated gasoline, the total hydrocarbon solubility in water is typically about 120 mg/L. Methyl tert-butyl ether sorbs only weakly to subsurface solids; therefore, sorption does not substantially retard the transport of MTBE by ground water. In addition, MTBE generally resists biodegradation in ground water. The half-life of MTBE in the atmosphere can be as short as 3 d in a regional airshed. In the air, MTBE tends to partition into atmospheric water, including precipitation. However, the washing out of gas-phase MTBE by precipitation will not, by itself, greatly alter the gas-phase concentration of the compound in the air. The partitioning of MTBE to precipitation can nevertheless result in concentrations as high as 3 {micro}g/L or more in urban precipitation and can contribute to the presence of MTBE in surface and ground water.

Squillace, P.J.; Zogorski, J.S. [Geological Survey, Rapid City, SD (United States); Pankow, J.F. [Oregon Graduate Inst. of Science and Technology, Beaverton, OR (United States). Dept. of Environmental Science and Engineering; Korte, N.E. [Oak Ridge National Lab., TN (United States). Environmental Science Div.

1997-09-01T23:59:59.000Z

87

energy savings by the use of mtbe to replace alkylate in automotive gasolines  

SciTech Connect (OSTI)

This paper presents data on the differences in energy consumption in the production of leaded and unleaded AI-93 gasolines with various blend components. The authors investigate as high-octane components certain products that are more effective in use and less energy-consuming in production in comparison with alkylate. In particular, methyl tert-butyl ether (MTBE) is discussed; it is not poisonous, it has a high heat of combustion, and it does not attack materials of construction. The addition of 11% MTBE to gasoline lowers the cold start temperature of engines by 10-12 degrees. Moreover, no adjustment of the carburetor is required for the changeover to gasoline with 11% MTBE.

Englin, B.A.; Emel'yanov, V.E.; Terent'ev, G.A.; Vinogradov, A.M.

1986-07-01T23:59:59.000Z

88

Removal of MTBE and other organic contaminants from water by sorption to high silica zeolites  

SciTech Connect (OSTI)

Select zeolites with high SiO{sub 2}/Al{sub 2}O{sub 3} ratios were shown to effectively remove methyl tert-butyl ether (MTBE), chloroform, and trichloroethylene (TCE) from water. In laboratory studies using batch sorption equilibria, high Si large-port mordenite and ZSM-5 (silicalite) were found to have sorption properties for MTBE and TCE superior to activated carbon. for example, at an equilibrium solution concentration of 100 {micro}g/L, high Si mordenite retained 8--12x more MTBE than either of two powdered activated carbons used as reference sorbents. Sorption results also highlight the importance of pore size and SiO{sub 2}/Al{sub 2}O{sub 3} ration on contaminant removal efficiencies by zeolites.

Anderson, M.A.

2000-02-15T23:59:59.000Z

89

Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms  

SciTech Connect (OSTI)

Microorganisms indigenous to the stream-bed sediments at two gasoline-contaminated groundwater sites demonstrated significant mineralization of the fuel oxygenates, methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA). Up to 73% of [U-{sup 14}C]-MTBE and 84% of [U-{sup 14}C]-TBA were degraded to {sup 14}CO{sub 2} under mixed aerobic/anaerobic conditions. No significant mineralization was observed under strictly anaerobic conditions. The results indicate that, under the mixed aerobic/anaerobic conditions characteristic of stream-bed sediments, microbial processes may provide a significant environmental sink for MTBE and TBA delivered to surface water bodies by contaminated groundwater or by other sources.

Bradley, P.M.; Landmeyer, J.E.; Chapelle, F.H. [Geological Survey, Columbia, SC (United States)] [Geological Survey, Columbia, SC (United States)

1999-06-01T23:59:59.000Z

90

The social costs of an MTBE ban in California (Condensed version)  

E-Print Network [OSTI]

in Focus: Phasing Out MTBE in Gasoline," Annual Energyand P. J. Bartholomae, "MTBE and Benzene Plume Behavior: ASoil Sediment & Groundwater MTBE Special Issue, March, 43-

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2002-01-01T23:59:59.000Z

91

MTBE demand as a oxygenated fuel additive  

SciTech Connect (OSTI)

The MTBE markets are in the state of flux. In the U.S. the demand has reached a plateau while in other parts of the world, it is increasing. The various factors why MTBE is experiencing a global shift will be examined and future volumes projected.

NONE

1996-10-01T23:59:59.000Z

92

Interdisciplinary investigation of subsurface contaminant transport and fate at point-source releases of gasoline containing MTBE  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is commonly found at concentrations above the current U.S. Environmental Protection Agency draft lifetime health advisory for drinking water (20 to 200 micrograms per liter) at many point-source gasoline release sites. MTBE is significantly more persistent than benzene, toluene, ethyl-benzene and xylenes (BTEX) in the subsurface. Therefore, evaluation of the implications of its presence in gasoline to monitored natural attenuation and engineered bioremediation alternatives is warranted. An interdisciplinary, field-based investigation of the subsurface transport and fate of MTBE and petroleum hydrocarbons is being conducted by the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program at the site of an underground gasoline storage-tank release near Beaufort, South Carolina. The objective of the investigation is to provide a systematic evaluation of natural attenuation of MTBE compared to BTEX. Results of the field and laboratory studies at this site will be generalized to a broader range of hydrogeochemical conditions through experiments at other sites. Furthermore, newly developed methods of analysis can be applied to sites across the Nation. This investigation of MTBE at point-source release sites is coordinated with investigations of the occurrence of MTBE in shallow ground water, surface water, precipitation, and the atmosphere being conducted by the USGS National Water-Quality Assessment Program.

Buxton, H.T.; Baehr, A.L. [Geological Survey, West Trenton, NJ (United States); Landmeyer, J.E. [Geological Survey, Columbia, SC (United States)] [and others

1997-12-31T23:59:59.000Z

93

Multiple steady states during reactive distillation of methyl tert-butyl ether  

SciTech Connect (OSTI)

This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

1993-11-01T23:59:59.000Z

94

Location of MTBE and toluene in the channel system of the zeolite mordenite: Adsorption and host-guest interactions  

SciTech Connect (OSTI)

This paper reports a study of the location of Methyl Tertiary Butyl Ether (MTBE) and toluene molecules adsorbed in the pores of the organophylic zeolite mordenite from an aqueous solution. The presence of these organic molecules in the zeolite channels was revealed by structure refinement performed by the Rietveld method. About 3 molecules of MTBE and 3.6 molecules of toluene per unit cell were incorporated into the cavities of mordenite, representing 75% and 80% of the total absorption capacity of this zeolite. In both cases a water molecule was localized inside the side pocket of mordenite. The saturation capacity determined by the adsorption isotherms, obtained by batch experiments, and the weight loss given by thermogravimetric (TG) analyses were in very good agreement with these values. The interatomic distances obtained after the structural refinements suggest MTBE could be connected to the framework through a water molecule, while toluene could be bonded to framework oxygen atoms. The rapid and high adsorption of these hydrocarbons into the organophylic mordenite zeolite makes this cheap and environmental friendly material a suitable candidate for the removal of these pollutants from water. - graphical abstract: Location of MTBE (a) and toluene (b) in mordenite channels (projection along the [001] direction). Highlights: Black-Right-Pointing-Pointer We investigated the MTBE and toluene adsorption process into an organophilic zeolite mordenite. Black-Right-Pointing-Pointer The presence of MTBE and toluene in mordenite was determined by X-ray diffraction studies. Black-Right-Pointing-Pointer About 3 molecules of MTBE and 3.6 molecules of toluene per unit cell were incorporated into the zeolite cavities. Black-Right-Pointing-Pointer MTBE is connected to the framework through a water molecule. Black-Right-Pointing-Pointer Toluene is directly bonded to framework oxygen atoms.

Arletti, Rossella, E-mail: rossella.arletti@unito.it [Department of Earth Sciences, University of Torino Via Valperga Caluso 35, I-10125, Torino (Italy)] [Department of Earth Sciences, University of Torino Via Valperga Caluso 35, I-10125, Torino (Italy); Martucci, Annalisa; Alberti, Alberto [Department of Earth Sciences, University of Ferrara, Via G. Saragat 1, I-44100, Ferrara (Italy)] [Department of Earth Sciences, University of Ferrara, Via G. Saragat 1, I-44100, Ferrara (Italy); Pasti, Luisa; Nassi, Marianna [Department of Chemistry, University of Ferrara, Via L. Borsari 26, I-44100 Ferrara (Italy)] [Department of Chemistry, University of Ferrara, Via L. Borsari 26, I-44100 Ferrara (Italy); Bagatin, Roberto [Research Centre for Non-Conventional Energy-Istituto ENI Donegani, Environmental Technologies, Via Fauser 4, I-28100 Novara (Italy)] [Research Centre for Non-Conventional Energy-Istituto ENI Donegani, Environmental Technologies, Via Fauser 4, I-28100 Novara (Italy)

2012-10-15T23:59:59.000Z

95

MTBE, Oxygenates, and Motor Gasoline  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997EnvironmentElectricityrgy81 §98 3.241MTBE,

96

Two US markets, or one? How the MTBE-gasoline relationship is evolving  

SciTech Connect (OSTI)

This issue of Energy Detente features the price sensitivity of Methyl Tertiary Butyl Ether. Data is presented for US wholesale gasoline prices vs. MTBE for the 20-month period beginning in June 1994 and ending in January 1996, and the data is discussed. Also contained in this issue is the refining netback data and the fuel price/tax data for the period ending January 5, 1996.

NONE

1996-01-26T23:59:59.000Z

97

Disposition, metabolism, and toxicity of methyl tertiary butyl ether, an oxygenate for reformulated gasoline  

SciTech Connect (OSTI)

Studies of the toxicology of methyl tertiary butyl ether (MTBE) were reviewed as a possible information base for evaluating the health effects of evaporative emissions from reformulated gasoline (RFG). Perirenal fat/blood MTBE concentration ratios ranged from 9.7 to 11.6 after 15 wk of intermittent exposure. During an oxyfuels program in Fairbanks, AK, blood levels of occupationally exposed workers were 0.2-31.5 {mu}g/L MTBE and 1.6 to 72.2 {mu}g/L TBA with a mean TBA:MTBE blood concentration ratio of 4.2. In patients who received MTBE by percutaneous, transhepatic puncture for the dissolution of cholesterol gallstones, concentrations of MTBE in fat tissue reached 60 and 300 {mu}g/g at a treatment time when mean blood MTBE was less than 20 {mu}g/ml. The results of laboratory and clinical studies indicate that metabolites of MTBE may contribute to the nephropathy, neoplasms, and other pathological changes associated with repeated exposure to MTBE in experimental animals. It is concluded that such studies can provide a well-defined database for quantitatitive safety comparisons and health risk-benefit analyses of MTBE and other oxygenates in RFG. 39 refs., 1 tab.

Hutcheon, D.E.; Hove, W. ten; Boyle, J. III [UMDNJ, New Jersey Medical Schook, Newark, NJ (United States)] [UMDNJ, New Jersey Medical Schook, Newark, NJ (United States); Arnold, J.D. [Arnold & Arnold, Inc., Kansas City, MO (United States)] [Arnold & Arnold, Inc., Kansas City, MO (United States)

1996-04-05T23:59:59.000Z

98

A screening model for evaluating the degradation and transport of MTBE and other fuel oxygenates in the subsurface  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) has received high attention as it contributed to cleaner air and contaminated thousands of underground storage tank sites. Because MTBE is very water soluble, it is more difficult to remove from water by conventional remediation techniques. Therefore, biodegradation of MTBE has become a remediation alternative. In order to understand the transport and transformation processes, they present a closed form solution as a screening tool in this paper. The possible reaction pathways of first-order reactions are described as a reaction matrix. The singular value decomposition is conducted analytically to decouple the partial differential equations of the multi-species transport system coupled by the reaction matrix into multiple independent subsystems. Therefore, the complexity of mathematical description for the reactive transport system is significantly reduced and analytical solutions may be previously available or easily derived.

Sun, Y; Lu, X

2004-04-20T23:59:59.000Z

99

The Social Costs of an MTBE Ban in California  

E-Print Network [OSTI]

85 MTBE is more soluble in water than BTEX, which means thatlong as BTEX plumes; and California Regional Water QualityMTBE than BTEX dissolves in a given quantity of water. This

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

100

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling. Revision 1  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

1991-12-01T23:59:59.000Z

102

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

1991-12-31T23:59:59.000Z

103

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

1991-12-01T23:59:59.000Z

104

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network [OSTI]

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

105

Iron optimization for Fenton-driven oxidation of MTBE-spent granular activated carbon  

SciTech Connect (OSTI)

Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) was accomplished through the addition of iron (Fe) and hydrogen peroxide (H{sub 2}O{sub 2}) (15.9 g/L; pH 3). The GAC used was URV, a bituminous-coal based carbon. The Fe concentration in GAC was incrementally varied (1020-25 660 mg/kg) by the addition of increasing concentrations of Fe solution (FeSO4{center_dot}7H{sub 2}O). MTBE degradation in Fe-amended GAC increased by an order of magnitude over Fe-unamended GAC and H{sub 2}O{sub 2} reaction was predominantly (99%) attributed to GAC-bound Fe within the porous structure of the GAC. Imaging and microanalysis of GAC particles indicated limited penetration of Fe into GAC. The optimal Fe concentration was 6710 mg/kg (1020 mg/kg background; 5690 mg/kg amended Fe) and resulted in the greatest MTBE removal and maximum Fe loading oxidation efficiency (MTBE oxidized (g)/Fe loaded to GAC(mg/Kg)). At lower Fe concentrations, the H{sub 2}O{sub 2} reaction was Fe limited. At higher Fe concentrations, the H{sub 2}O{sub 2} reaction was not entirely Fe limited, and reductions in GAC surface area, GAC pore volume, MTBE adsorption, and Fe loading oxidation efficiency were measured. Results are consistent with nonuniform distribution of Fe, pore blockage in H{sub 2}O{sub 2} transport, unavailable Fe, and limitations in H{sub 2}O{sub 2} diffusive transport, and emphasize the importance of optimal Fe loading. 22 refs., 6 figs., 2 tabs.

Scott G. Huling; Patrick K. Jones; Tony R. Lee [U.S. Environmental Protection Agency, Ada, OK (United States). Office of Research and Development, National Risk Management Research Laboratory

2007-06-01T23:59:59.000Z

106

Multivariable controller increased MTBE complex capacity  

SciTech Connect (OSTI)

Capacity increased by more than 4.6% when one dynamic matrix multivariable controller began operating in Valero Refining Company`s MTBE production complex in Corpus Christi, Texas. This was on a plant that was already running well above design capacity due to previously made process changes. A single controller was developed to cover an isobutane dehydrogenation (ID) unit and an MTBE reaction and fractionation plant with the intermediate isobutylene surge drum. The overall benefit is realized by a comprehensive constrained multivariable predictive controller that properly handles all sets of limits experienced by the complex, whether limited by the front-end ID or back-end MTBE units. The controller has 20 manipulated, 6 disturbance and 44 controlled variables, and covers widely varying dynamics with settling times ranging from twenty minutes to six hours. The controller executes each minute with a six hour time horizon. A unique achievement is intelligent surge drum level handling by the controller for higher average daily complex capacity as a whole. The ID unit often operates at simultaneous limits on reactor effluent compressor capacity, cold box temperature and hydrogen/hydrocarbon ratio, and the MTBE unit at impurity in butene column overhead as well as impurity in MTBE product. The paper discusses ether production, isobutane dehydrogenation, maximizing production, controller design, and controller performance.

Robertson, D.; Peterson, T.J.; O`Connor, D. [DMC Corp., Houston, TX (United States); Payne, D.; Adams, V. [Valero Refining Co., Corpus Christi, TX (United States)

1997-03-01T23:59:59.000Z

107

active methyl tert-butyl: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

108

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

109

Texas plant will use new process to coproduce propylene oxide, MTBE  

SciTech Connect (OSTI)

Texaco Chemical Co. is building a $400 + million facility to produce 1.2 billion lb/year (14,000 b/d) methyl tertiary butyl ether (MTBE) and 400 million lb/year (about 500 metric tons/day) propylene oxide (PO). The facility-under construction at Port Neches, Tex.-will utilize a newly developed Texaco process that coproduces the two chemicals. The process produces propylene oxide and tertiary butyl alcohol (TBA) from the reaction of isobutane with oxygen in one step, then in a second step with propylene. The TBA is then reacted with methanol in a one-step process that synthesizes MTBE. The paper describes the Port Neches facilities, construction schedule, feedstocks, product uses, and auxiliary equipment.

Rhodes, A.K.

1993-08-30T23:59:59.000Z

110

Gas phase synthesis of MTBE on triflic-acid-modified zeolites  

SciTech Connect (OSTI)

The gas phase synthesis of MTBE (methyl tert-butyl ether) was studied using three series of triflic acid (TFA)-modified zeolites, the parent materials being HY, H-mordenite, and HZSM-5. Impregnation with TFA was found to enhance MTBE synthesis activity only for the large-pore zeolite Y and only up to a certain extent of modification. A high level of TFA modification caused a reduction in activity, apparently due to blockage of the active sites by TFA molecules and extra-lattice Al formed during the modification process. The mechanism of activity enhancement by TFA modification appears to be related to the formation of extra-lattice Al rather than the direct presence of TFA. 20 refs., 6 figs., 1 tab.

Nikolopoulos, A.A.; Kogelbauer, A.; Goodwin, J.G. Jr. [Univ. of Pittsburgh, PA (United States)] [and others] [Univ. of Pittsburgh, PA (United States); and others

1996-01-01T23:59:59.000Z

111

Toxicity of methyl tertiary butyl ether to Daphnia magna and photobacterium phosphoreum  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is a liquid organic compound added to gasoline to increase its oxygen content and to reduce the emission of carbon monoxide during combustion in many urban areas. In order to meet the 1990 Clean Air Act amendments, gasoline must contain 2.7% oxygen (by weight) or 15% (by volume) of MTBE in gasoline to meet the regulations for the control of carbon monoxide emissions. Health effects caused by inhalation of MTBE include headaches, dizziness, irritated eyes and nausea; MTBE is one of cancer--causing chemicals. Intracaval injection of MTBE (0.2 mg/kg) caused the highest mortality (100%) in rats. General anesthetic effect induced by MTBE was found at or above 1200 mg/kg body weight; Rosenkranz and Klopman (1991) predicted that MTBE is neither a genotoxicant nor a carcinogen. Nevertheless, the safety of using MTBE in oxygenated fuels is now being questioned from its potential as groundwater pollutant. This study measures the toxicity of MTBE to Daphnia magna and Photobacterium phosphoreum. 13 refs.

Gupta, G.; Lin, Y.J. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States)

1995-10-01T23:59:59.000Z

112

Observation on the biodegradation and bioremediation potential of methyl t-butyl ether  

SciTech Connect (OSTI)

There have been few reports documenting evidence for the biodegradation of the fuel oxygenate alkyl ether, methyl t-butyl ether (MTBE) in groundwater, soils, and biosludges. Partial (or complete) microbial breakdown of MTBE has been observed in an anaerobic subsoil, a river sediment under methanogenic conditions, a cyclohexane-degrading bacterial consortium and a pure culture of the methylotroph, Methylisnus trichosporium OB3b. An aerobic bacterial enrichment (BC-1) isolated from an industrial transient (non-accumulating) metabolic intermediate. The studies suggest that MTBE is cleaved by BC-1 to TBA which is then metabolized via isopropanol and acetone. There is little information on the occurrence of indigenous MTBE-degraders in groundwater, soils and activated sludges. Preliminary evidence has been obtained, however, from a marketing terminal groundwater site that naturally-occurring MTBE-degraders are present in some monitoring wells. Microcosm experiments with groundwater from this aquifer show that MTBE is aerobically degraded (no TBA formed) with a first-order decay rate (0.31/day) similar to BTEX. Also, MTBE did not inhibit the intrinsic biodegradation potential of BTEX in groundwater microcosms. In summary, the data presented indicate that MTBE biodegradation has been observed in some environmental media. Further work is needed to assess the feasibility of using indigenous or derived aerobic and anaerobic MTBE-degrading cultures for treating fuel ethers in groundwaters or wastewater with in-situ or ex-situ bioremediation technologies.

Salanitro, J.; Wisniewski, H.; McAllister, P. [Shell Development Co., Houston, TX (United States)

1995-12-31T23:59:59.000Z

113

Biodegradation of methyl tert-butyl ether by a bacterial pure culture  

SciTech Connect (OSTI)

A bacterial strain, PM1, which is able to utilize methyl tert-butyl ether (MTBE) as its sole carbon and energy source, was isolated from a mixed microbial consortium in a compost biofilter capable of degrading MTBE. Initial linear rates of MTBE degradation by 2 x 10{sup 6} cells ml{sup {minus}1} were 0.07, 1.17, and 3.56 {mu}g ml{sup {minus}1} h{sup {minus}1} for initial concentrations of 5, 50, and 500 {mu}g MTBE ml{sup {minus}1}, respectively. When incubated with 20 {mu}g of uniformly labeled [{sup 14}C]MTBE ml{sup {minus}1}, strain PM1 converted 46% to {sup 14}CO{sub 2} and 19% to {sup 14}C-labeled cells within 120 h. This yield is consistent with the measurement of protein accumulation at different MTBE concentrations from which was estimated a biomass yield of 0.18 of cells mg MTBE{sup {minus}1}. Strain PM1 was inoculated into sediment core material collected from a contaminated groundwater plume at Port Hueneme, California, in which there was no evidence of MTBE degradation. Strain PM1 readily degraded 20 {micro}g of MTBE ml{sup {minus}1} added to the core material. The rate of MTBE removal increased with additional inputs of 20 {micro}g of MTBE ml{sup {minus}1}. These results suggest that PM1 has potential for use in the remediation of MTBE-contaminated environments.

Hanson, J.R.; Ackerman, C.E.; Scow, K.M.

1999-11-01T23:59:59.000Z

114

Remediation of a fractured clay soil contaminated with gasoline containing MTBE  

SciTech Connect (OSTI)

Gasoline and other light non-aqueous phase liquids (LNAPLs) released into fractured clay soils initially move by advection of the LNAPL through the fractures. Once advective movement of the LNAPL ceases, dissolution of the gasoline components into the pore water and diffusion into the intact blocks of clay becomes an important transport process. The aqueous-phase flux of each compound in the mixture depends in large part upon its aqueous solubility. For example, a low-solubility compound like isooctane remains primarily in the fracture in the LNAPL. A high-solubility compound, like methyl-tert-butyl ether (MTBE), dissolves readily and may move almost entirely into the clay matrix. The distribution of compounds between the matrix and the fractures will have an important impact on the rate at which the gasoline contaminated soil can be remediated. In this context, the presence of soluble additives like MTBE can significantly impact the risk and remediation time for the, soil. Beginning in 1993 a field study to examine the applicability of air flushing for remediation of low-permeability soils was sponsored by API. The study focused on a variety of soil vapor extraction (SVE) and in situ air sparging (IAS) approaches for mass removal and risk reduction. The source of gasoline contamination in this study was a release of 50 liters of a mixture containing 14 gasoline hydrocarbons ranging from pentane to naphthalene, and including MTBE. The mixture was released into the shallow subsurface and allowed to redistribute for 10 months prior to air flushing startup. Numerical modeling indicated that essentially all of the MTBE should have dissolved into the matrix. In contrast, essentially all of the isooctane should have remained in the LNAPL in the fractures.

Johnson, R.L.; Grady, D.E. [Oregon Graduate Institute, Portland, OR (United States); Walden, T. [BP Oil Europe, Brussels (Belgium)

1997-12-31T23:59:59.000Z

115

Kinetics and mechanism of the sonolytic destruction of methyl tert-butyl ether by ultrasonic irradiation in the presence of ozone  

SciTech Connect (OSTI)

The kinetics and mechanism of the sonolytic degradation of methyl tert-butyl ether (MTBE) have been investigated at an ultrasonic frequency of 205 kHz and power of 200 W L{sup {minus}1}. The observed first-order degradation rate constant for the loss of MTBE increased from 4.1 {times} 10{sup {minus}4} s{sup {minus}1} to 8.5 {times} 10{sup {minus}4} s{sup {minus}1} as the concentration of MTBE decreased from 1.0 to 0.01 mM. In the presence of O{sub 3}, the sonolytic rate of destruction of MTBE was accelerated substantially. The rate of MTBE sonolysis with ozone was enhanced by a factor of 1.5--3.9 depending on the initial concentration of MTBE. tert-Butyl formate, tert-butyl alcohol, methyl acetate, and acetone were found to be the primary intermediates and byproducts of the degradation reaction with yields of 8, 5, 3, and 12%, respectively. A reaction mechanism involving three parallel pathways that include the direct pyrolytic decomposition of MTBE, the direct reaction of MTBE with ozone, and the reaction of MTBE with hydroxyl radical is proposed.

Kang, J.W. [Yonsei Univ., Wonju (Korea, Republic of). Dept. of Industrial Environment and Health] [Yonsei Univ., Wonju (Korea, Republic of). Dept. of Industrial Environment and Health; Hoffmann, M.R. [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.] [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.

1998-10-15T23:59:59.000Z

116

Recovery of methanol in an MTBE process  

SciTech Connect (OSTI)

In a process for the manufacture of methyltertiarybutylether (MTBE) in which methanol and a mixture of C/sub 4/ hydrocarbons containing isobutylene are contacted in a reaction zone containing an ion-exchange resin catalyst under suitable conditions to effect the reaction of methanol and isobutylene to produce a reaction product containing MTBE, unreacted methanol, unreacted isobutylene and other C/sub 4/ hydrocarbons, the reaction product is introduced to a fractionation zone wherein it is separated into a bottoms product comprising essentially MTBE and an overhead product containing unreacted methanol, unreacted isobutylene, and other C/sub 4/ hydrocarbons, and the overhead product is introduced to an absorption zone wherein the methanol is absorbed; the improvement is described which comprises utilizing silica gel as adsorbent and regenerating the silica gel adsorbent in a closed loop by contacting the silica gel absorbent with a desorption gas stream at an elevated temperature for a sufficient period of time to remove absorbed methanol, cooling the effluent from the adsorption zone to condense desorbed methanol removing desorbed methanol from the system and recycling the desorption gas to the adsorption zone.

Whisenhunt, D.E.; Byers, G.L.; Hattiangadi, U.S.

1988-05-31T23:59:59.000Z

117

Eliminating MTBE in Gasoline in 2006  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96Nebraska NuclearDecade Year-08/03)1 Eliminating MTBE in

118

Feasibility of using bioaugmentation with bacterial strain PM1 for bioremediation of MTBE-contaminated vadose and groundwater environments  

E-Print Network [OSTI]

2000. "In Situ Treatment of MTBE by Biostimulation of NativeAmerican Petroleum Institute MTBE Biodegradation Workshop,Detection and Quantification of MTBE-degrading Strain PM1 by

Scow, Kate M; Hristova, Krassimira

2001-01-01T23:59:59.000Z

119

The Social Costs of an MTBE Ban in California  

E-Print Network [OSTI]

in Gasoline. Annual Energy Outlook 2000. DOE/EIA-0383,in Gaso- line. Annual Energy Outlook 2000. DOE/EIA-0383,MTBE in Gasoline, Annual Energy Outlook 2000, 2001a. Mazur,

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

120

Fast photoreactions of ethanol and MTBE on tropospheric metal oxide particles  

SciTech Connect (OSTI)

Ethanol (EtOH) and tert-Butyl methyl ether (MTBE) are both finding increased use as oxygenated additives to fuels. However, the environmental fate in the troposphere of these species is unclear when they escape as fugitive emissions. In several locations there are reports of human illness in response to MTBE in particular. Volatile organic compounds (VOC`s) such as these are generally thought to react by a variety of homogeneous free-radical mechanisms, usually beginning with attack by OH radical. However, we show by laboratory kinetic studies that the heterogeneous photoreaction on solid suspended metal-oxide particulates such as fly ash proceeds with a comparable rate, especially in urban environments. EtOH reacts to form acetaldehyde, and EtOH forms isobutene, methanol, and formaldehyde. Our work appears to be the first-ever demonstration that VOC`s can react as fast by a heterogeneous mechanism as by a homogeneous one in the atmosphere. Experiments by various optical and kinetic techniques show that the active phases in fly ash are Fe oxides, which are fairly abundant in other atmospheric particulates as well.

Idriss, H.; Seebauer, E.G. [Univ. of Illinois, Urbana, IL (United States)

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Intrinsic bioremediation of a BTEX and MTBE plume under mixed aerobic/denitrifying conditions  

SciTech Connect (OSTI)

A shallow Coastal Plain aquifer in rural Sampson Country, North Carolina, has been contaminated with petroleum hydrocarbon from a leaking underground storage tank containing gasoline.An extensive field characterization has been performed to define the horizontal and vertical distribution of soluble gasoline components and indicator parameters. A plume of dissolved methyl tert-butyl ether (MTBE) and the aromatic hydrocarbons benzene, toluene, ethylbenzene, and xylene isomers (BTEX) is present in the aquifer and has migrated over 600 ft from the source area. Background dissolved oxygen concentrations range from 7 to 8 mg/L, and nitrate concentrations range from 5 to 22 mg/L as N due to extensive fertilization of fields surrounding the spill. In the center of the BTEX plume, oxygen concentrations decline to less than 1 mg/L while nitrate concentrations remain high. The total mass flux of MTBE and all BTEX components decline with distance downgradient relative to a conservative tracer (chloride). At the source, the total BTEX concentration exceeds 75 mg/L while 130 ft downgradient, total BTEX concentrations are less than 4.9 mg/L, a 15-fold reduction. Toluene and ethylbenzene decline most rapidly followed by m-p-xylene, o-xylene and finally benzene. Biodegradation of TEX appears to be enhanced by the excess nitrate present in the aquifer while benzene biodegradation appears to be due to strictly aerobic processes.

Borden, R.C.; Daniel, R.A. [North Carolina State Univ., Raleigh, NC (United States). Civil Engineering Dept.

1995-09-01T23:59:59.000Z

122

Heterogeneous models of tubular reactors packed with ion-exchange resins: Simulation of the MTBE synthesis  

SciTech Connect (OSTI)

The study of behavior of fixed-bed reactors using ion-exchange resins as catalysts was carried out by making use of a complete bidimensional heterogeneous model for the reactor, which included the resistances inside the ion-exchange resin particles, considered with a macroreticular structure. The active sites were located inside the gel phase of the resin, represented by microspheres, and on the macropores walls. The overall efficiency of such heterogeneous catalyst particles was defined by the macroeffectiveness and microeffectiveness factors accounting for the process behavior on the macropores and inside the microspheres. The synthesis of methyl tert-butyl ether, MTBE, a liquid-phase reversible exothermic reaction between methanol and isobutene, was considered as a reference case. This system was studied in the temperature range of 313--338 K, and the effect of the thermodynamic equilibrium conditions was examined. The results predicted by the complete heterogeneous model were compared with those obtained with the simple pseudohomogeneous model, which revealed higher hot spots. Moreover, a comparison between bidimensional and unidimensional models was also performed. The orthogonal collocation method was used for the discretization of the differential equations inside the catalyst particles, which were reduced from three (corresponding to the three mass balances for the three compounds, isobutene, methanol, and MTBE) to only one differential equation, by using the concept of the generalized variable.

Quinta Ferreira, R.M.; Almeida-Costa, C.A. [Univ. of Coimbra (Portugal). Dept. of Chemical Engineering; Rodrigues, A.E. [Univ. of Porto (Portugal). Dept. of Chemical Engineering

1996-11-01T23:59:59.000Z

123

The social costs of an MTBE ban in California (Long version)  

E-Print Network [OSTI]

Ethanol, Non-oxy Case D'( p) MTBE Case D(p) U.S. Supply S(p)NO. 932 THE SOCIAL COSTS OF AN MTBE BAN IN CALIFORNIA (LONGMTBE .

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2002-01-01T23:59:59.000Z

124

Atmosphere-Water Interaction of Chloroform, Toluene, and MTBE in Small Perennial Urban Streams  

E-Print Network [OSTI]

Atmosphere-Water Interaction of Chloroform, Toluene, and MTBE in Small Perennial Urban Streams-butyl ether (MTBE) are frequently detected VOCs in the atmosphere, surface water, and ground water in urban not be the predominant source of chloroform and toluene in the two urban streams. In contrast, MTBE may be coming from

125

Kinetics and modeling of mixture effects during complete catalytic oxidation of benzene and methyl tert-butyl ether  

SciTech Connect (OSTI)

The performance of a catalytic incinerator depends on the nature of the compounds being oxidized and cannot be predicted simply by knowing the performance of the incinerator with pure-component model compounds. Considering the importance of mixture effects, an attempt was made to develop a combined model to predict the conversion when benzene and methyl tert-butyl ether (MTBE) are simultaneously oxidized. Complete catalytic oxidation of benzene and MTBE, singly and in mixtures, was investigated over a platinum catalyst. No inhibition effects were seen with benzene, but MTBE conversion was distinctly inhibited by benzene. A Mars-van Krevelen rate model was used to explain the results. Model parameters were obtained from pure-component experiments and then incorporated into a multicomponent model without any adjustment or additional rate parameters. The multicomponent model was able to predict the conversion of benzene and MTBE oxidation in the binary mixture using the pure-component data without adjustable parameters.

Dangi, S.; Abraham, M.A. [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering] [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering

1997-06-01T23:59:59.000Z

126

The current status of the U.S. MTBE industry  

SciTech Connect (OSTI)

This paper reviews the status of the MTBE industry from its beginnings as a result of the Clean Air Act Amendments and the need for the use of oxygenates in non-attainment areas. During 1990--93 three world scale merchant plants were constructed and in 1994 two more were brought on stream. The paper tabulates reasons why MTBE gained the lion`s share of the oxygenates market. Finally the paper discusses the problems that now plague the industry and their causes.

Rose, G.M. [Global Octanes Corp., Houston, TX (United States)

1995-12-31T23:59:59.000Z

127

he increasing frequency of detection of the widely used gasoline additive methyl tert-  

E-Print Network [OSTI]

T he increasing frequency of detection of the widely used gasoline additive methyl tert- butyl, the September 15, 1999, Report of the Blue Ribbon Panel on Oxygenates in Gasoline (1) states that between 5 with large releases (e.g., LUFTs). Unprecedented growth in use Use of MTBE as a gasoline additive began

128

Reactant adsorption and its impact upon MTBE synthesis on zeolites  

SciTech Connect (OSTI)

Zeolites show interesting properties as catalysts for MTBE synthesis from methanol and isobutene such as a high selectivity to MTBE even at a low methanol/isobutene feed ratio. In order to explain this high selectivity, the adsorption behaviors of HY and HZSM-5 zeolites and their impact on activity and selectivity for MTBE synthesis were studied. Adsorption experiments, carried out under conditions similar to those used for reaction, showed that ca. 2.5 molecules of methanol were adsorbed per acid site on HZSM-5 and HY zeolites, whereas isobutene was found to form a 1:1 adsorption complex. The excess methanol adsorbed was found to be only weakly bonded, probably via hydrogen bonds. On a commercially used resin catalyst (Amberlyst-15) equal amounts of methanol and isobutene were adsorbed. The higher methanol uptake of the zeolites was paralleled by a higher selectivity to MTBE as compared to the resin catalyst. The increased adsorption of methanol on the zeolites was concluded to play a key role in suppressing the formation of by-products due to isobutene dimerization or oligomerization by decreasing the adsorption of isobutene on the active sites and thereby keeping these sites available for reaction. 40 refs., 5 figs., 3 tabs.

Kogelbauer, A.; Nikolopoulos, A.A.; Goodwin, J.G. Jr.; Marcelin, G. [Univ. of Pittsburgh, PA (United States)] [Univ. of Pittsburgh, PA (United States)

1995-03-01T23:59:59.000Z

129

New low energy process for MTBE and TAME  

SciTech Connect (OSTI)

Considered as new bulk petrochemicals of limited feedstocks MTBE (methyltertbutylether) and TAME (tertamylmethylether) need cheap and simple, minimum-cost production processes. The problems in optimizing the etherification are set by specifications for ether products and hydrocarbon raffinates. Working up reaction products from etherification processes containing hydrocarbons, methanol and ether to secure the pure main and side products is difficult because of azeotrope formation of methanol with ethers or hydrocarbons. At EC Erdolchemie GmbH, Cologne, a semicommercial unit with a capacity of 2,500 metric t/y has now been successfully operated for nearly one year producing high purity MTBE (> 99 wt.%) and a raffinate II with methanol content of < 0.05 wt.%. The TAME process has successfully been tested in a 3,000 kg/y TAME pilot plant for almost two years. Based on the operating experience, EC has prepared the engineering for a commercial multiproduct plant, including the production of 30,000 metric t/y MTBE, 15,000 metric t/y TAME and 6,000 metric t/y methylbutenes (TAME cracking product) in the first stage. EC has made application to the authorities for a construction permit. The process for MTBE and TAME will be licensed by EC Erdolchemie GmbH, Postfach 75 20 02, 5000 Cologne 71, West Germany or by Lurgi Kohle und Mineraloltechnik GmbH, Postfach 11 12 31, 6000 Frankfurt Main 2, West Germany.

Herwig, J.; Schleppinghoff, B.; Schulwitz, S.

1984-06-01T23:59:59.000Z

130

Cytotoxic and DNA-damaging effects of methyl tert-butyl ether and its metabolites on HL-60 cells in vitro  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is a widely used oxygenate in unleaded gasoline; however, few studies have been conducted on the toxicity of this compound. This study evaluates the cytotoxic and DNA-damaging effects of MTBE and its metabolites in a human haemopoietic cell line, HL-60. The metabolites of MTBE studied include tertiary butyl alcohol (TBA), {alpha}-hydroxyisobutyric acid (HIBA), and formaldehyde. Comet assay is used to assess DNA damage, and the cytotoxicity is investigated by lactate dehydrogenease (LDH) release. The results show no significant cytotoxic effects of MTBE, TBA, and HIBA over a concentration ranging from 1 to 30 mM. Formaldehyde, in contrast, causes a substantial LDH release at a concentration of 5 {mu}M. Hydrogen peroxide, a known oxidative agent, at concentrations ranging from 10 to 100 {mu}M, produces a significant dose-related increase in DNA damage, whereas a much higher concentration of MTBE (1 to 30 mM) is required to produce a similar observation. The genotoxic effects of TBA and HIBA appear to be identical to that of MTBE. Conversely, DNA damage is observed for formaldehyde at a relatively low concentration range (5 to 100 {mu}M). These findings suggest that MTBE and its metabolites, except formaldehyde, have relatively low cytotoxic and genotoxic effects. 16 refs., 4 figs.

Tang, G.H. [Xian Medical Univ. (China); Shen, Y.; Shen, H.M. [National Univ. of Singapore (Singapore)] [and others

1996-12-31T23:59:59.000Z

131

E-Print Network 3.0 - aerobic mtbe biodegradation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

27 ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT Summary: capable of MTBE biodegradation. 12;Effective treatment of a mixture...

132

Determination of Methyl tert-Butyl Ether and tert-Butyl Alcohol in Water by Solid-Phase Microextraction/Head Space Analysis in Comparison to EPA Method 5030/8260B  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is now one of the most common groundwater contaminants in the United States. Groundwater contaminated with MTBE is also likely to be contaminated with tert-butyl alcohol (TBA), because TBA is a component of commercial grade MTBE, TBA can also be used as a fuel oxygenate, and TBA is a biodegradation product of MTBE. In California, MTBE is subject to reporting at concentrations greater than 3 {micro}g/L. TBA is classified as a ''contaminant of current interest'' and has a drinking water action level of 12 {micro}g/L. In this paper, we describe the development and optimization of a simple, automated solid phase microextraction (SPME) method for the analysis of MTBE and TBA in water and demonstrate the applicability of this method for monitoring MTBE and TBA contamination in groundwater, drinking water, and surface water. In this method, the headspace (HS) of a water sample is extracted with a carboxen/polydimethylsiloxane SPME fiber, the MTBE and TBA are desorbed into a gas chromatograph (GC), and detected using mass spectrometry (MS). The method is optimized for the routine analysis of MTBE and TBA with a level of quantitation of 0.3 {micro}g/L and 4 {micro}g/L, respectively, in water. MTBE quantitation was linear for over two orders of concentration (0.3 {micro}g/L -80 {micro}g/L). TBA was found to be linear within the range of 4 {micro}g/L-7,900 {micro}g/L. The lower level of detection for MTBE is 0.03 {micro}g/L using this method. This SPME method using headspace extraction was found to be advantageous over SPME methods requiring immersion of the fiber into the water samples, because it prolonged the life of the fiber by up to 400 sample analyses. This is the first time headspace extraction SPME has been shown to be applicable to the measurement of both MTBE and TBA at concentrations below regulatory action levels. This method was compared with the certified EPA Method 5030/8260B (purge-and-trap/GC/MS) using split samples from laboratory bioreactors treating MTBE contaminated water and applied to environmental samples collected throughout the East Bay area of California. Results from the SPME-HS/GC/MS method were directly comparable to the EPA Method 5030/8260B. This method provides an simple, inexpensive, accurate, and sensitive alternative to EPA Method 5030/8260B for the analysis of MTBE and TBA in water samples.

Oh, Keun-Chan; Stringfellow, William T.

2003-10-02T23:59:59.000Z

133

The evolution of fuel: A dissertation on MTBE and elastomers  

SciTech Connect (OSTI)

This paper begins with a history of the development of the internal combustion engine and the need for a fuel octane booster that would also be non-polluting. The use of ethers as fuel additives cause a compatibility problem with valve sealing materials. The main purpose of this presentation is to address this compatibility problem. The paper makes specific recommendations for the author`s General Twin Seal, describing the seal components (slip seal, bonnet and lower plate O-rings, gland O-rings, bearing retainer O-rings, and pressure relief device seals) and which materials these components should be manufactured from to be compatible with the following fuel additives: toluene, MTBE, and various mixtures of toluene and MTBE.

Smith, G.M. [General Valve Co., Brookshire, TX (United States)

1995-12-31T23:59:59.000Z

134

Why methyl tert-butyl ether production by reactive distillation may yield multiple solutions  

SciTech Connect (OSTI)

This paper presents an explanation of why methyl tert-butyl ether (MTBE) production by reactive distillation may yield multiple solutions. Widely different composition profiles and conversions may, as already reported by Krishna and others, results with identical column specifications, depending on the initial estimates provided. A hypothesis yielding a qualitative understanding of this phenomenon has been developed. The inert n-butene plays a key role in the proposed explanation: As the reaction mixture is diluted with n-butene, the activity coefficient of methanol increases substantially and the temperature decreases. This dilution has a profound effect on the equilibrium conversion, enabling MTBE to escape from the reactive zone without decomposition. When methanol is fed below or in the lower part of the reactive zone of the column, the ``lifting capacity`` of the minimum boiling point MTBE-methanol azeotrope will also be important.

Hauan, S.; Hertzberg, T.; Lien, K.M. [Univ. of Trondheim (Norway)

1995-03-01T23:59:59.000Z

135

Exposure to methyl tert-butyl ether and benzene among service station attendants and operators  

SciTech Connect (OSTI)

Concerns for atmospheric pollution from auto exhaust have led to the blending of {open_quotes}oxygenates{close_quotes} with motor fuels. The most common oxygenate, methyl tert-butyl ether (MTBE) is currently required within several metropolitan areas (Denver and Phoenix) in the range of 12% of the motor fuel. Amendments to the Clean Air Act may expand this requirement to as many as 44 other areas of the United States in the near future. In consideration of the magnitude of potential uncontrolled exposures from its extensive use and a related concern involving the potential influence of MTBE blending on exposures to other constituents of gasoline (particularly benzene), an evaluation of exposures among service station attendants and operators was undertaken at the request, and in cooperation with, the American Petroleum Institute during the latter part of 1990. For application of the survey results to a broad audience, three categories or types of service stations were identified with regard to MTBE use and exposure potential: (a) service stations that do not use MTBE or use it only as an octane enhancer, (b) service stations with seasonal requirements to use 12-15% MTBE (the Denver, Colorado, and Phoenix, Arizona, metropolitan areas), and (c) service stations equipped with stage II (active) vapor recovery systems (several coastal areas, most notably Southern California). 4 refs., 4 tabs.

Hartle, R. [National Inst. for Occupational Safety and Health, Cincinnati, OH (United States)

1993-12-01T23:59:59.000Z

136

Reaction calorimetry study of the liquid-phase synthesis of tert-butyl methyl ether  

SciTech Connect (OSTI)

The liquid-phase addition of methanol to isobutene to give tert-butyl methyl ether (MTBE) on the ion-exchange resin Lewatit K2631 has been studied in a calorimetric reactor. Heat capacity of MTBE and enthalpy of the MTBE synthesis reaction in the temperature range 312--333 K have been determined. MTBE heat capacity in the liquid phase has been found to obey the equation c[sub P] (J/mol[center dot]K) = 472.34 [minus] 2.468(T/K) + 0.005071(T/K)[sup 2]. At 298 K the standard molar reaction enthalpy is [Delta]H[degree] = [minus]33.8 kJ/mol. A method to estimate apparent activation energies from heat flow rate in a given reaction has been developed and proved to be valid for the MTBE synthesis. Using this method, an apparent activation energy of 91.1--95.2 kJ/mol is calculated. A [minus]3.8 kJ/mol value has been found for the adsorption enthalpy of methanol on the ion-exchange resin Lewatit K2631 by a combination of reaction calorimetry and thermogravimetry. This allows the calculation of an activation energy on the gel phase of the resin of 91 kJ/mol.

Sola, L.; Pericas, M.A.; Cunill, F.; Iborra, M. (Univ. de Barcelona (Spain). Dept. d'Enginyeria Quimica)

1994-11-01T23:59:59.000Z

137

Pilot-scale evaluation of chemical oxidation for MTBE-contaminated soil  

SciTech Connect (OSTI)

The US Environmental Protection Agency (USEPA) has tentatively classified MTBE as a possible human carcinogen, thus further emphasizing the importance for study of fate, transport, and environmental effects of MTBE. The treatment of subsurface contaminants (e.g., MTBE) from leaking underground storage tank (LUST) sites presents many complex challenges. Many techniques have been employed for the remediation of contaminants in soil and groundwater at LUST sites. Under sponsorship of US EPA's National Risk Management Research Laboratory, IT Corporation has conducted evaluations of chemical oxidation of MTBE contaminated soil using Fenton's Reagent (hydrogen peroxide catalyzed by ferrous sulfate), simulating both ex-situ and in-situ soil remediation. Bench-scale ex-situ tests have shown up to 90% degradation of MTBE within 12 hours. Pilot-scale MTBE oxidation tests were conducted in a stainless paddle-type mixer with a 10 cubic foot mixing volume. The reactor was designed with a heavy duty mixer shaft assembly to homogenize soil and included provisions for contaminant and reagent addition, mixing, and sample acquisition. The tests were performed by placing 400 pounds of a synthetic soil matrix (consisting of a mixture of top soil, sand, gravel and clay) in the reactor, spiking with 20 ppm of MTBE, and mixing thoroughly. The variables evaluated in the pilot-scale tests included reaction time, amount of hydrogen peroxide, and amount of ferrous sulfate. After 8 hours of reaction, using 4 times the stoichiometric quantity of hydrogen peroxide and a 10:1 hydrogen peroxide: ferrous iron weight ratio, approximately 60% MTBE degradation was observed. When 10 times the stoichiometric quantity of hydrogen peroxide was used (with the same ratio of hydrogen peroxide to ferrous iron), 90% MTBE degradation was observed. When the same test was performed without any ferrous iron addition, 75% MTBE degradation was observed.

Rahman, M.; Schupp, D.A.; Krishnan, E.R.; Tafuri, A.N.; Chen, C.T.

1999-07-01T23:59:59.000Z

138

New processes to recovery methanol and remove oxygenates from Valero MTBE unit  

SciTech Connect (OSTI)

The refiner today has to evaluate every available option to increase octane in the gasoline pool to make up for the loss in octane created by lead phase down. Production of MTBE is one of the most attractive options. MTBE is produced by selectivity reacting isobutylene with methanol. Valero Refining's refinery at Corpus Christie, Texas (formerly Saber Refining) is one of the most modern refineries built in the last decade to upgrade resids. As part of the gasoline upgrading Valero had built a Butamer Unit to convert normal butane to isobutane upstream of their HF Alkylation Unit. In 1984 as an ongoing optimization of its operations, Valero Refining evaluated various processes to enable it to increase the octane output, and decided to build an MTBE unit. Valero selected the MTBE process licensed by Arco Technology, Inc. and contracted with Jacobs Engineering Group, Inc., Houston, Texas to provide detailed engineering and procurement services.

Hillen, P.; Clemmons, J.

1987-01-01T23:59:59.000Z

139

Traitement biologique in situ au sein d'un aquifre de polluants de type ETBE et MTBE  

E-Print Network [OSTI]

Traitement biologique in situ au sein d'un aquifère de polluants de type ETBE et MTBE Yves Benoit Villeurbanne (6) CNRS, UMR5557, Ecologie Microbienne ­ 69100 Villeurbanne Résumé Le MtBE et l' EtBE sont des : Traçabilité, Innocuité, Efficacité: Application aux polluants pétroliers type MTBE, ETBE), financé par le pôle

Paris-Sud XI, Université de

140

Automobile proximity and indoor residential concentrations of BTEX and MTBE  

SciTech Connect (OSTI)

Attached garages have been identified as important sources of indoor residential air pollution. However, the literature lacks information on how the proximity of cars to the living area affects indoor concentrations of gasoline-related compounds, and the origin of these pollutants. We analyzed data from the Relationships of Indoor, Outdoor, and Personal Air (RIOPA) study and evaluated 114 residences with cars in an attached garage, detached garage or carport, or without cars. Results indicate that homes with cars in attached garages were affected the most. Concentrations in homes with cars in detached garages and residences without cars were similar. The contribution from gasoline-related sources to indoor benzene and MTBE concentrations appeared to be dominated by car exhaust, or a combination of tailpipe and gasoline vapor emissions. Residing in a home with an attached garage could lead to benzene exposures ten times higher than exposures from commuting in heavy traffic.

Corsi, Dr. Richard [University of Texas, Austin; Morandi, Dr. Maria [University of Texas Health Science Center, Houston; Siegel, Dr. Jeffrey [University of Texas, Austin; Hun, Diana E [ORNL

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network [OSTI]

D. J. Slomczynski. 2003. BTEX/MTBE bioremediation: BionetsScow, and L. Alvarez-Cohen. MTBE and benzene biodegradationinteractions in BTEX and MTBE mixtures by an MTBE-degrading

2007-01-01T23:59:59.000Z

142

Whole-genorne analysis of the methyl tert-butyl ether-degrading beta-proteobacterium Methylibium petroleiphilum PM1  

SciTech Connect (OSTI)

Methylibium petroleiphilum PM1 is a methylotroph distinguished by its ability to completely metabolize the fuel oxygenate methyl tert-butyl ether (MTBE). Strain PM1 also degrades aromatic (benzene, toluene, and xylene) and straight-chain (C, to C,,) hydrocarbons present in petroleum products. Whole-genome analysis of PM1 revealed an similar to 4-Mb circular chromosome and an similar to 600-kb megaplasmid, containing 3,831 and 646 genes, respectively. Aromatic hydrocarbon and alkane degradation, metal resistance, and methylotrophy are encoded on the chromosome. The megaplasmid contains an unusual t-RNA island, numerous insertion sequences, and large repeated elements, including a 40-kb region also present on the chromosome and a 29-kb tandem repeat encoding phosphonate transport and cobalamin biosynthesis. The megaplasmid also codes for alkane degradation and was shown to play an essential role in MTBE degradation through plasmid-curing experiments. Discrepancies between the insertion sequence element distribution patterns, the distributions of best BLASTP hits among major phylogenetic groups, and the G+C contents of the chromosome (69.2%) and plasmid (66%), together with comparative genome hybridization experiments, suggest that the plasmid was recently acquired and apparently carries the genetic information responsible for PM1's ability to degrade MTBE. Comparative genomic hybridization analysis with two PM1-like MTBE-degrading environmental isolates (similar to 99% identical 16S rRNA gene sequences) showed that the plasmid was highly conserved (ca. 99% identical), whereas the chromosomes were too diverse to conduct resequencing analysis. PM1's genome sequence provides a foundation for investigating MTBE biodegradation and exploring the genetic regulation of multiple biodegradation pathways in M. petroleiphilum and other MTBE-degrading beta-proteobacteria.

Kane, Staci R. [Lawrence Livermore National Laboratory (LLNL); Chakicherla, Anu Y. [Lawrence Livermore National Laboratory (LLNL); Chain, Patrick S. G. [Lawrence Livermore National Laboratory (LLNL); Schmidt, Radomir [University of California, Davis; Shin, M [U.S. Department of Energy, Joint Genome Institute; Legler, Tina C. [Lawrence Livermore National Laboratory (LLNL); Scow, Kate M. [University of California, Davis; Larimer, Frank W [ORNL; Lucas, Susan [Joint Genome Institute, Walnut Creek, California; Richardson, P M [U.S. Department of Energy, Joint Genome Institute; Hristova, Krassimira R. [University of California, Davis

2007-03-01T23:59:59.000Z

143

One multivariable controller increased capacity of an Oleflex{trademark}/MTBE complex  

SciTech Connect (OSTI)

Capacity increased by more than 4.6% when one dynamic matrix controller began operating in Valero Refining Company`s MTBE production complex in Corpus Christi, Texas. This was on a plant that was already running well above design capacity due to process changes previously made on the plant. A single controller was developed to cover an Oleflex{trademark} isobutane dehydrogenation unit and an MTBe reaction and fractionation plant with the intermediate isobutylene surge drum. The overall benefit is realized by a comprehensive constrained multivariable predictive controller which properly handles all sets of limits experienced by the complex, whether limited by the front-end Oleflex{trademark} or back-end MTBE unit. The controller has 20 manipulated, 6 disturbance and 44 controlled variables, and covers widely varying dynamics with settling times ranging from twenty minutes to six hours. The controller executes each minute with a six hour time horizon. A unique achievement is intelligent handling of the surge drum level by the controller for higher average daily capacity of the complex as a whole. The Oleflex{trademark} often operates at simultaneous limits on reactor effluent compressor capacity, cold box temperature and hydrogen/hydrocarbon ratio and the MTBE at impurity in butene column overhead as well as impurity in MTBE product.

Robertson, D.; Peterson, T.J.; O`Connor, D. [Dynamic Matrix Control Corp., Houston, TX (United States); Adams, V.; Payne, D. [Valero Refining Co., Corpus Christi, TX (United States)

1996-12-01T23:59:59.000Z

144

Relationship between MTBE-blended gasoline properties and warm-up driveability  

SciTech Connect (OSTI)

The relationship between MBE-blended gasoline properties and warm-up driveability is investigated by focusing on the transient combustion air-fuel ratio that strongly relates to the combustion state of the engine. As a result, although warm-up driveability of MTBE-free gasoline has a high correlation with 50% distillation temperature (T50) and a high correlation with 100 C distillation volume (E100), the correlation is found to be low when blended with MTBE. Various formulas that improve correlation with peak excess air ratio ({lambda}) by correcting T50 and E100 for the amount of MTBE blended are examined. The formula for which the highest determination coefficient is obtained is proposed as a new driveability index (DI) that can also be applied to MTBE-blended gasoline. In addition, the effect on driveability by gasoline base materials using this new DI also is investigated. The results indicate that the new DI worsen when heavy reformate containing large amounts of aromatics or MTBE, an oxygen-containing compound, is used for the octane improver, leaving the balance of the volatility out of consideration.

Suzawa, Takumi; Yamaguchi, Kazunori; Kashiwabara, Kimito [Mitsubishi Motors Corp., Tokyo (Japan); Fujisawa, Norihiro; Matsubara, Michiro

1995-12-31T23:59:59.000Z

146

Isobaric vapor-liquid equilibria in the systems methyl 1,1-dimethylethyl ether + hexane and + heptane  

SciTech Connect (OSTI)

The vapor-liquid equilibrium at 94 kPa has been determined for the binary systems of methyl 1,1-dimethylethyl ether (MTBE) with hexane and with heptane. Both systems deviate slightly from ideal behavior, can be described as regular solutions, and do not present an azeotrope. The activity coefficients and boiling point of the solutions were correlated with its composition by the Redlich-Kister, Wohl, Wilson, UNIQUAC, NRTL, and Wisniak-Tamir equations.

Wisniak, J.; Magen, E.; Shachar, M.; Zeroni, I.; Segura, H. [Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Chemical Engineering] [Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Chemical Engineering; Reich, R. [Univ. de Concepcion (Chile). Dept. of Chemical Engineering] [Univ. de Concepcion (Chile). Dept. of Chemical Engineering

1997-03-01T23:59:59.000Z

147

Four: Evaluating Reforms in the Implementation of Hazardous Waste Policies in California  

E-Print Network [OSTI]

the increasing extent of MTBE contamination from USTs. Onlyof groundwater supplies with MTBE, a gasoline additive.contamination, especially by MTBE, have grown in importance.

Cutter, W. Bowman; DeShazo, J.R.

2006-01-01T23:59:59.000Z

148

Exposure to methyl tert-butyl ether, benzene, and total hydrocarbons at the Singapore-Malaysia causeway immigration checkpoint  

SciTech Connect (OSTI)

The primary aim of this study was to determine the extent and levels of exposure to volatile organic compounds (VOCs) from automobile emissions in a group of immigration officers at a busy cross-border checkpoint. A majority (80%) of the workers monitored were exposed to benzene at levels between 0.01 and 0.5 ppm, with only 1.2% exceeding the current Occupational Safety and Health Administration occupational exposure limit of 1 ppm. The geometric mean (GM) concentrations of 8-hr time-weighted average exposure were 0.03 ppm, 0.9 ppm, and 2.46 ppm for methyl-tert-butyl ether (MTBE), benzene, and total hydrocarbons (THC), respectively. The highest time-weighted average concentrations measured were 1.05 ppm for MTBE, 2.01 ppm for benzene, and 34 ppm for THC. It was found that motorbikes emitted a more significant amount of pollutants compared with motor cars. On average, officers at the motorcycle booths were exposed to four to five times higher levels of VOCs (GMs of 0.07 ppm, 0.23 ppm, and 4.7 ppm for MTBE, benzene, and THC) than their counterparts at the motor car booths (GMs of 0.01 ppm, 0.05 ppm, and 1.5 ppm). The airborne concentrations of all three pollutants correlated with the flow of vehicle traffic. Close correlations were also noted for the concentrations in ambient air for the three pollutants measured. Benzene and MTBE had a correlation coefficient of 0.97. The overall findings showed that the concentrations of various VOCs were closely related to the traffic density, suggesting that they were from a common source, such as exhaust emissions from the vehicles. The results also indicated that although benzene, MTBE, and THC are known to be volatile, a significant amount could still be detected in the ambient environment, thus contributing to our exposure to these compounds. 4 refs., 6 figs.

Tan, C.; Ong, H.Y.; Kok, P.W. [and others

1996-12-31T23:59:59.000Z

149

LIDEM unit for the production of methyl tert-butyl ether from butanes  

SciTech Connect (OSTI)

One of the basic problems in the production of motor fuels is how to obtain high-octane unleaded gasolines that will meet today`s ecological requirements. The term {open_quotes}reformulated gasolines{close_quotes} has come into general use throughout the world to denote fuels with a certain chemical composition. These gasolines consist of preselected components; as shown by worldwide experience, they must include oxygen-containing compounds that are distinguished by high octane numbers and low reactivities. Standards in effect in the United States, Japan, and certain Western European countries require that automotive gasolines must contain at least 2-4% by weight of oxygen-containing compounds (calculated as oxygen). In the last 15 years, in order to meet these requirements, production has been set up in various countries for the manufacture of high-octane oxygen-containing components known as oxygenates. The most common of these is methyl tert-butyl ether (MTBE), obtained by etherification of isobutene by methanol. Process technology developed by this last organization was used as the basis for constructing a unit in the Nizhnekamskneftekhim Production Association and at the Mazheikyai Petroleum Refinery in Lithuania. MTBE production has been held back mainly by a shortage of isobutene, which is obtained mainly from butane-butene cuts produced in cat crackers. In order to alleviate this shortage, it has been proposed that MTBE should be obtained from saturated C{sub 4} hydrocarbons that are recovered in processing oilfield associated gas, and also in the refinery from primary distillation units, catalytic reformers, and hydrocrackers. A working design was developed in 1991-1992 by Lengiproneftekhim for a basically new combination unit designed for the processing of saturated C{sub 4} hydrocarbons, which has been termed the LIDEM unit (Leningrad - isomerization - dehydrogenation - MTBE).

Rudin, M.G.; Zadvornov, M.A.

1994-09-01T23:59:59.000Z

150

Gas phase synthesis of MTBE from methanol and isobutene over dealuminated zeolites  

SciTech Connect (OSTI)

Gas phase synthesis of MTBE from methanol and isobutene has been investigated over different zeolites. It is shown that bulk Si/Al ratio has a marked influence on the formation of MTBE. H-beta zeolite was found to be as active as acid Amberlyst-15 (reference catalyst), and noticeably superior to non- and dealuminated forms of H-Y, H-ZSM-5, zeolite omega, and H-mordenites. Screening test results obtained over other catalysts (SAPOs and pillared clays) are briefly commented. The contribution of the external surface of the zeolites to the reaction is discussed. In the case of H-Y zeolites, it is shown that extra framework Al species ({sup 27}Al NMR signal at 30 ppm) have a detrimental effect on the reaction. 64 refs., 12 figs., 3 tabs.

Collignon, F.; Mariani, M.; Moreno, S.; Remy, M.; Poncelet, G. [Universite Catholique de Louvain (Belgium)] [Universite Catholique de Louvain (Belgium)

1997-02-01T23:59:59.000Z

151

Rates and products of degradation for MTBE and other oxygenate fuel additives in the subsurface environment  

SciTech Connect (OSTI)

The recent realization that oxygenated fuel additives such as MTBE are becoming widely distributed groundwater contaminants has created a sudden and pressing demand for data on the processes that control their environmental fate. Explaining and predicting the subsequent environmental fate of these compounds is going to require extrapolations over long time frames that will be very sensitive to the quality of input data on each compound. To provide such data, they have initiated a systematic study of the pathways and kinetics of fuel oxygenate degradation under subsurface conditions. Batch experiments in simplified model systems are being performed to isolate specific processes that may contribute to MTBE degradation. A variety of degradation pathways can be envisioned that lead to t-butyl alcohol (TBA) as the primary or secondary product. However, experiments to date with a facultative iron reducing bacteria showed no evidence for TBA formation. Continuing experiments include mixed cultures from a range of aquifer materials representative of NAWQA study sites.

Tratnyek, P.G.; Church, C.D.; Pankow, J.F. [Oregon Graduate Inst., Portland, OR (United States). Dept. of Environmental Science and Engineering

1995-12-31T23:59:59.000Z

152

Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story  

E-Print Network [OSTI]

as methyl-tert-butyl ether (MTBE), lubricating oil and itsthe environment. Use of the MTBE additive in gasoline wasof gasoline laced with MTBE into groundwater resulted in

2013-01-01T23:59:59.000Z

153

Energy Efficiency Improvement and Cost Saving Opportunities for the Petrochemical Industry - An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network [OSTI]

Ethylene dichloride 1 MTBE 2 Vinylchloride 3 Ethylbenzene 1Methyl- Tertiary-Butyl-Ether (MTBE) or Ethyl-Tertiary-Butyl-Styrene Vinylchloride MTBE Benzene, Toluene, Xylene Acetone

Neelis, Maarten

2008-01-01T23:59:59.000Z

154

Cometabolic bioremediation  

E-Print Network [OSTI]

Intrinsic bioremediation of MTBE-contaminated groundwater atcontaminants, e.g. PCE, TCE, MTBE, TNT, dioxane, atrazine,Methyl tert-butyl ether (MTBE) has also been remediated

Hazen, Terry C.

2010-01-01T23:59:59.000Z

155

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. [801Methyl tert-butyl ether  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

Marcelin, G.

1992-06-24T23:59:59.000Z

156

Treatment of methyl tert-butyl ether vapors in a biotrickling filters. 2. Analysis of the rate-limiting step and behavior under transient conditions  

SciTech Connect (OSTI)

Detailed experiments were performed with gas phase biotrickling filters treating vapors of methyl tert-butyl ether (MTBE), a gasoline additive of great environmental concern. A particular emphasis was placed on the analysis of the rate-limiting step, and it was found that the process was mostly limited by the biological reaction rather than by mass transfer. Further experiments involved the study of the dynamic behavior of the biotrickling filters under simulated field conditions. In all cases, the biotrickling filters adapted rapidly to the new conditions, and new steady states were obtained within hours. The relevance of the results and the implications as far as implementation of biotrickling filters for field MTBE treatment are discussed.

Fortin, N.Y.; Deshusses, M.A. [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering] [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering

1999-09-01T23:59:59.000Z

157

VOL. 32, No.4 UNL WATER CENTER AUGUST 2000 New Method For Detecting Trace Amounts of MTBE  

E-Print Network [OSTI]

water their use to help curb growing prob- at spill sites. lems with air pollution. MTBE is the most emis-by Steve Ress sions, are considered small. Gasoline additives that help keep our air clean can- "Most of the information available on oxygenates 10 mine the extent of their environmental impacts

Nebraska-Lincoln, University of

158

Sonolytic destruction of methyl tert-butyl ether by ultrasonic irradiation: The role of O{sub 3}, H{sub 2}O{sub 2}, frequency, and power density  

SciTech Connect (OSTI)

The kinetics of degradation of methyl tert-butyl ether (MTBE) by ultrasonic irradiation in the presence of ozone as functions of applied frequencies and applied power are investigated. Experiments are performed over the frequency range of 205--1,078 kHz. The higher overall reaction rates are observed at 358 and 618 kHz and then at 205 and 1,078 kHz. The observed pseudo-first-order rate constant, k{sub 0}, for MTBE degradation increases with increasing power density up to 250 W L{sup {minus}1}. A linear dependence of the first-order rate constant, k{sub O{sub 3}}, for the simultaneous degradation of O{sub 3} on power density is also observed. Naturally occurring organic matter (NOM) is shown to have a negligible effect on observed reaction rates.

Kang, J.W.; Hung, H.M.; Lin, A.; Hoffmann, M.R. [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.] [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.

1999-09-15T23:59:59.000Z

159

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity  

E-Print Network [OSTI]

methyl-tertiary-butyl- ether (MTBE) and the biomass burningfrom all source categories. MTBE is a gasoline additive andwith the fuel tracer MTBE (e.g. 0.82 for MTBE/benzene).

Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

2009-01-01T23:59:59.000Z

160

Radioactive Waste Radioactive Waste  

E-Print Network [OSTI]

#12;Radioactive Waste at UF Bldg 831 392-8400 #12;Radioactive Waste · Program is designed to;Radioactive Waste · Program requires · Generator support · Proper segregation · Packaging · labeling #12;Radioactive Waste · What is radioactive waste? · Anything that · Contains · or is contaminated

Slatton, Clint

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense  

E-Print Network [OSTI]

-butyl ether (MTBE) in a dense medium plasma (DMP) reactor utilizing gas chromatog- raphy-massspectrometryandgaschromatography-thermal conductivity techniques. A rate law is developed for the removal of MTBE from an aqueous solution in the DMP. The oxidation products from the treatment of MTBE-contaminated water in the DMP reactor were found

Dandy, David

162

Pyrolysis of Organic Molecules Relevant to Combustion as Monitored by Photoionization Time-of-Flight Mass Spectrometry  

E-Print Network [OSTI]

is observed, which is similar to MTBE in this system whichisobutene formed from MTBE, is found to occur. REFERENCES [methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (

Weber, Kevin Howard

2010-01-01T23:59:59.000Z

163

Life-cycle Environmental Inventory of Passenger Transportation in the United States  

E-Print Network [OSTI]

Methyltert?ButylEther(MTBE);http://www.atsdr.cdc.gov/MethylTertiaryButyl Ether (MTBE), which was easilyaccountingwasnotperformedonMTBEandtheresult of

Chester, Mikhail V

2008-01-01T23:59:59.000Z

164

(distillation) (Le Chatelier  

E-Print Network [OSTI]

acetate(methyl-, ethyl-, butyl-) , methanol isobutene MTBE , ethanol isobutene ETBE , methanol 2-methyl-1% MTBE 3 DMC . 2% 1990 MTBE 1999 3 2002 MTBE . [ 1-1 ] Phosgene process polycarbonate(PC) 50/ . DMC DMC MTBE / . ( : Amoco, "Review of DMC Manufacture and its

Hong, Deog Ki

165

he U.S. Geological Survey's (USGS) National Water-Quality Assess-  

E-Print Network [OSTI]

of the wells included methyl tert-butyl ether (MTBE), tetrachloroethene (PCE), dichlorodifluoromethane, 1

166

Multiple Objective Stormwater Management For the Coliseum Complex  

E-Print Network [OSTI]

methyl tertiary butyl ether (MTBE) remain in the soil around5.2 ppb xylenes, and 160 ppb MTBE remain in the groundwater

Jones, Jesse; Kraai, Rachel

2009-01-01T23:59:59.000Z

167

Effects of water chemistry on NF/RO membrane structure and performance  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE), benzene, ethylbenzene,TCE** Industrial C 2 HCl 3 MTBE** [48] Industrial C 5 H 12 O

Mo, Yibing

2013-01-01T23:59:59.000Z

168

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network [OSTI]

methyl-tertiary butyl ether (MTBE), from gasoline by 2004.MTBE was used to meet a requirement for gasoline to containbeginning in 2002, replacing MTBE with ethanol. According to

2007-01-01T23:59:59.000Z

169

The Scientific Basis for the Regulation of Nanoparticles: Challenging Paracelsus and Pare  

E-Print Network [OSTI]

NANOTECHNOILOGY 402 (2007). 20. MTBE unquestionably causesTertiary-Butyl Ether (MTBE)-a Gasoline Additive-CausesMethyl Tertiary-butyl Ether (MTBE) in CD-I Mice and F-344

Goldstein, Bernard D.

2010-01-01T23:59:59.000Z

170

Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area  

E-Print Network [OSTI]

Methanol Ethanol Acetone MEK MTBE CO Methane UCI UCI TOGA/methyl tertiary butyl ether (MTBE), and toluene all ratioedthe observed decay. For MTBE, also a species that is not

2010-01-01T23:59:59.000Z

171

Soil type, crop and irrigation technique affect nitrogen leaching to groundwater  

E-Print Network [OSTI]

water contamination with MTBE (methyl tertiary-butyl ether,that areas vulnerable to MTBE are also vulner- able tothat affect the movement of MTBE. If only a small amount of

Letey, John; Vaughan, Peter

2013-01-01T23:59:59.000Z

172

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE) at 57 amu has been previouslyby a fragment of MTBE (62%) with minor contributions fromFortner and Knighton, 2008). MTBE also in- terfered (16%)

2011-01-01T23:59:59.000Z

173

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3and SO2  

E-Print Network [OSTI]

methyl tertiary- butyl ether (MTBE) and its effect on plasmaand three VOCs (propyne, furan, MTBE) remained below their 3Ethanol Acetone MEK MAC MVK MTBE Furan CH 3 OH C 2 H 5 OH C

2010-01-01T23:59:59.000Z

174

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network [OSTI]

methyl-tertiary butyl ether (MTBE), from gasoline by 2004.MTBE was used to meet a requirement for gasoline to containbeginning in 2002, replacing MTBE with ethanol. According to

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

175

Finding the missing stratospheric Bry: a global modeling study of CHBr3 and CH2Br2  

E-Print Network [OSTI]

Methanol Ethanol Acetone MEK MTBE CO Methane UCI UCI TOGA/methyl tertiary butyl ether (MTBE), and toluene all ratioedthe observed decay. For MTBE, also a species that is not

2010-01-01T23:59:59.000Z

176

QUANTIFYING NON-POINT SOURCES OF VOLATILE ORGANIC COMPOUNDS IN STORMWATER FROM A PARKING LOT  

E-Print Network [OSTI]

-butyl ether (MTBE) on urban particles indicates a site- specific interaction between MTBE and a particulate is a possible source only for the gasoline oxygenate methyl tert-butyl ether (MTBE). Lopes and Bender (1998

177

Assessing the Effectiveness of California's Underground Storage Tank Annual Inspection Rate Requirements  

E-Print Network [OSTI]

Methyl Tert-Butyl Ether (MTBE), a gasoline additive. Thefor the lions share of MTBE contamination, as well asIn response to the MTBE crisis, California increased the

Cutter, W. Bowman

2008-01-01T23:59:59.000Z

178

Life-Cycle Water Impacts of U.S. Transportation Fuels  

E-Print Network [OSTI]

Drinking Water: Methyl Tertiary Butyl Ether (MTBE).http://www.epa.gov/mtbe/water.htm (11/30/10), Chiu, Y. W. ;LCFS LCI LP LPG MED MRO MSF MTBE MWD MWDOC NAICS NERC NETL

Scown, Corinne Donahue

2010-01-01T23:59:59.000Z

179

Comparison of SPME headspace analysis to U.S. EPA method5030/8260B for MTBE monitoring  

SciTech Connect (OSTI)

A novel method for analysis of methyl tert-butyl ether andtert-butyl alcohol using solid phase microextraction is described andcompared to a standard method.

Stringfellow, William T.; Oh, Kuen-Chan

2005-02-01T23:59:59.000Z

180

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network [OSTI]

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste  

E-Print Network [OSTI]

waste (i.e, mixture of biohazardous and chemical or radioactive waste), call Environment, Health2/2009 Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste Description Biohazard symbol Address: UCSD 200 West Arbor Dr. San Diego, CA 92103 (619

Tsien, Roger Y.

182

Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste  

E-Print Network [OSTI]

Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste Description Biohazard symbol Address: UCSD 9500 Gilman Drive La Jolla, CA 92093 (858) 534) and identity of liquid waste Biohazard symbol Address: UCSD 9500 Gilman Drive La Jolla, CA 92093 (858) 534

Tsien, Roger Y.

183

Hazardous Waste Program (Alabama)  

Broader source: Energy.gov [DOE]

This rule states criteria for identifying the characteristics of hazardous waste and for listing hazardous waste, lists of hazardous wastes, standards for the management of hazardous waste and...

184

Effect of Ethanol and Methyl-tert-Butyl Ether on Monoaromatic Hydrocarbon Biodegradation: Response Variability for Different Aquifer Materials Under Various Electron-Accepting Conditions  

SciTech Connect (OSTI)

Aquifer microcosms were used to determine how ethanol and methyl-tert-butyl ether (MtBE) affect monoaromatic hydrocarbon degradation under different electron-accepting conditions commonly found in contaminated sites experiencing natural attenuation. Response variability was investigated by using aquifer material from four sites with different exposure history. The lag phase prior to BTEX (benzene, toluene, ethylbenzene, and xylenes) and ethanol degradation was typically shorter in microcosms with previously contaminated aquifer material, although previous exposure did not always result in high degradation activity. Toluene was degraded in all aquifer materials and generally under a broader range of electron-accepting conditions compared to benzene, which was degraded only under aerobic conditions. MtBE was not degraded within 100 days under any condition, and it did not affect BTEX or ethanol degradation patterns. Ethanol was often degraded before BTEX compounds, and had a variable effect on BTEX degradation as a function of electron-accepting conditions and aquifer material source. An occasional enhancement of toluene degradation by ethanol occurred in denitrifying microcosms with unlimited nitrate; this may be attributable to the fortuitous growth of toluene-degrading bacteria during ethanol degradation. Nevertheless, experiments with flow-through aquifer columns showed that this beneficial effect could be eclipsed by an ethanol-driven depletion of electron acceptors, which significantly inhibited BTEX degradation and is probably the most important mechanism by which ethanol could hinder BTEX natural attenuation. A decrease in natural attenuation could increase the likelihood that BTEX compounds reach a receptor as well as the potential duration of exposure.

Ruiz-Aguilar, G L; Fernandez-Sanchez, J M; Kane, S R; Kim, D; Alvarez, P J

2003-10-06T23:59:59.000Z

185

Detailed chemical kinetic reaction mechanism for biodiesel components methyl stearate and methyl oleate  

E-Print Network [OSTI]

Detailed chemical kinetic reaction mechanism for biodiesel components methyl stearate and methyl are developed for two of the five major components of biodiesel fuel, methyl stearate and methyl oleate renewable sources, can reduce net emissions of greenhouse gases. An important class of biodiesel fuels

Paris-Sud XI, Université de

186

Bioelectrochemical Integration of Waste Heat Recovery, Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

MHRC System Concept ADVANCED MANUFACTURING OFFICE Bioelectrochemical Integration of Waste Heat Recovery, Waste-to-Energy Conversion, and Waste-to-Chemical Conversion with...

187

MUSHROOM WASTE MANAGEMENT PROJECT LIQUID WASTE MANAGEMENT  

E-Print Network [OSTI]

of solid and liquid wastes generated at mushroom producing facilities. Environmental guidelines#12;MUSHROOM WASTE MANAGEMENT PROJECT LIQUID WASTE MANAGEMENT PHASE I: AUDIT OF CURRENT PRACTICE The Mushroom Waste Management Project (MWMP) was initiated by Environment Canada, the BC Ministry

188

Wasted Wind  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

why turbulent airflows are causing power losses and turbine failures in America's wind farms-and what to do about it April 1, 2014 Wasted Wind This aerial photo of Denmark's Horns...

189

MTBE Production Economics  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997EnvironmentElectricityrgy81 §98 3.241

190

Detailed Chemical Kinetic Reaction Mechanism for Biodiesel Components Methyl Stearate and Methyl Oleate  

SciTech Connect (OSTI)

New chemical kinetic reaction mechanisms are developed for two of the five major components of biodiesel fuel, methyl stearate and methyl oleate. The mechanisms are produced using existing reaction classes and rules for reaction rates, with additional reaction classes to describe other reactions unique to methyl ester species. Mechanism capabilities were examined by computing fuel/air autoignition delay times and comparing the results with more conventional hydrocarbon fuels for which experimental results are available. Additional comparisons were carried out with measured results taken from jet-stirred reactor experiments for rapeseed methyl ester fuels. In both sets of computational tests, methyl oleate was found to be slightly less reactive than methyl stearate, and an explanation of this observation is made showing that the double bond in methyl oleate inhibits certain low temperature chain branching reaction pathways important in methyl stearate. The resulting detailed chemical kinetic reaction mechanism includes more approximately 3500 chemical species and more than 17,000 chemical reactions.

Naik, C; Westbrook, C K; Herbinet, O; Pitz, W J; Mehl, M

2010-01-22T23:59:59.000Z

191

alkyl-tert alkyl ethers: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TREAT METHYL- TERT-BUTYL ETHER CONTAMINATED CiteSeer Summary: Methyl-tert-butyl ether (MTBE) is a commonly used gasoline additive. Leaking underground storage tank systems,...

192

Waste processing air cleaning  

SciTech Connect (OSTI)

Waste processing and preparing waste to support waste processing relies heavily on ventilation. Ventilation is used at the Hanford Site on the waste storage tanks to provide confinement, cooling, and removal of flammable gases.

Kriskovich, J.R.

1998-07-27T23:59:59.000Z

193

Waste Disposal (Illinois)  

Broader source: Energy.gov [DOE]

This article lays an outline of waste disposal regulations, permits and fees, hazardous waste management and underground storage tank requirements.

194

International Journal of Mass Spectrometry 249250 (2006) 303310 Pyrolysis of 2-methoxy-2,3,3-trimethylbutane (MTMB) monitored by  

E-Print Network [OSTI]

used fuel oxygenates MTBE and TAME), the predominance of bond homolysis at temperatures >900 K suggests homologues ­ methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME) ­ present a new set of problems discussed as alternatives to MTBE and TAME, because they are expected to be much less soluble in water. More

Morton, Thomas Hellman

195

UNIVERSITY OF CALIFORNIA Santa Barbara  

E-Print Network [OSTI]

, B. Dooher, and D. Rice, Analysis of dissolved benzene plumes and methyl tertiary butyl ether (MTBE, An evaluation of MTBE impacts to California groundwater resources, pp. 68 p., Lawrence Livermore National, Temporal Analysis of Methyl Tertiary Butyl Ether (MTBE) Plumes at California Leaking Underground Fuel tank

California at Santa Barbara, University of

196

WASTE TO WATTS Waste is a Resource!  

E-Print Network [OSTI]

to Climate protection in light of the· Waste Framework Directive. The "energy package", e.g. the RenewablesWASTE TO WATTS Waste is a Resource! energy forum Case Studies from Estonia, Switzerland, Germany Bossart,· ABB Waste-to-Energy Plants Edmund Fleck,· ESWET Marcel van Berlo,· Afval Energie Bedrijf From

Columbia University

197

EINLADUNG INFOTAG 2001 Eine Forschungsanstalt  

E-Print Network [OSTI]

durch den Benzinzusatz MTBE. Methyl-tert-butylether gehört weltweit zu den meistproduzierten orga- nischen Chemikalien. Weil MTBE im Grundwasser auftritt, soll es in den USA als Benzinzusatz verboten

Wehrli, Bernhard

198

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Aug. 2004, p. 47204726 Vol. 70, No. 8 0099-2240/04/$08.00 0 DOI: 10.1128/AEM.70.8.47204726.2004  

E-Print Network [OSTI]

contamination of surface and groundwater resources by the gasoline oxygenate methyl tert-butyl ether (MTBE) is leading to its phaseout. Ethanol, a likely candidate to substitute MTBE, is increasingly being used

Alvarez, Pedro J.

199

Isothermal vapor-liquid equilibria for 2-methyl-2-butanol + 2-methyl-1-butanol + 1-pentanol  

SciTech Connect (OSTI)

Vapor-liquid equilibria (VLE) for 2-methyl-2-butanol + 2-methyl-1-butanol and 2-methyl-2-butanol + 2-methyl-1-butanol + 1-pentanol have been measured at 373.15 K. The binary VLE results have been correlated by different liquid-phase activity coefficient models. The binary interaction parameters obtained from Wilson, NRTL, and UNIQUAC models in this and a previously study are used to predict the VLE data for the ternary system. Vapor-liquid equilibrium (VLE) data are necessary for the design of distillation processes.

Aucejo, A.; Burguet, M.C.; Monton, J.B.; Munoz, R.; Sanchotello, M.; Vazquez, M.I. (Univ. of Valencia (Spain). Dept. de Ingenieria Quimica)

1994-07-01T23:59:59.000Z

200

Hanford Site annual dangerous waste report: Volume 1, Part 1, Generator dangerous waste report, dangerous waste  

SciTech Connect (OSTI)

This report contains information on hazardous wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, waste number, weight, and waste designation.

NONE

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Central Waste Complex (CWC) Waste Analysis Plan  

SciTech Connect (OSTI)

The purpose of this waste analysis plan (WAP) is to document the waste acceptance process, sampling methodologies, analytical techniques, and overall processes that are undertaken for waste accepted for storage at the Central Waste Complex (CWC), which is located in the 200 West Area of the Hanford Facility, Richland, Washington. Because dangerous waste does not include the source, special nuclear, and by-product material components of mixed waste, radionuclides are not within the scope of this documentation. The information on radionuclides is provided only for general knowledge.

ELLEFSON, M.D.

1999-12-01T23:59:59.000Z

202

Radioactive Waste Management (Minnesota)  

Broader source: Energy.gov [DOE]

This section regulates the transportation and disposal of high-level radioactive waste in Minnesota, and establishes a Nuclear Waste Council to monitor the federal high-level radioactive waste...

203

Waste Management  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500IIVasudhaSurface.Laboratory30,WP-073.99 4.22PrimaryWaste

204

Hazardous Wastes Management (Alabama)  

Broader source: Energy.gov [DOE]

This legislation gives regulatory authority to the Department of Environmental Management to monitor commercial sites for hazardous wastes; fees on waste received at such sites; hearings and...

205

Waste Treatment Plant Overview  

Office of Environmental Management (EM)

contracted Bechtel National, Inc., to design and build the world's largest radioactive waste treatment plant. The Waste Treatment and Immobilization Plant (WTP), also known as the...

206

Salt Waste Processing Initiatives  

Office of Environmental Management (EM)

1 Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives...

207

Solid Waste (New Mexico)  

Broader source: Energy.gov [DOE]

The New Mexico Environment Department's Solid Waste Bureau manages solid waste in the state. The Bureau implements and enforces the rules established by the Environmental Improvement Board.

208

Nuclear Waste Reduction  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nuclear Waste Reduction Pyroprocessing is a promising technology for recycling used nuclear fuel and improving the associated waste management options. The process...

209

Radioactive Waste Management  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

To establish policies and guidelines by which the Department of Energy (DOE) manages tis radioactive waste, waste byproducts, and radioactively contaminated surplus facilities.

1984-02-06T23:59:59.000Z

210

Transuranic Waste Requirements  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The guide provides criteria for determining if a waste is to be managed in accordance with DOE M 435.1-1, Chapter III, Transuranic Waste Requirements.

1999-07-09T23:59:59.000Z

211

Radioactive and chemotoxic wastes: Only radioactive wastes?  

SciTech Connect (OSTI)

Radioactive waste arising from Italian Nuclear Power Plants and Research Centers, classified as 1st and 2nd Category wastes, are managed only as radioactive wastes following the Technical Guide No. 26 issued by the Italian Regulatory Body: ENEA DISP on 1987. A very important Regulatory Regime revision for Italian Nuclear Activities started at the end of 1991. This paper considers the need to develop a new strategy dedicated to mixed waste in line with current international trends.

Eletti, G.F.; Tocci, M. [ENEA DISP, Rome (Italy)

1993-12-31T23:59:59.000Z

212

Solid Waste and Infectious Waste Regulations (Ohio)  

Broader source: Energy.gov [DOE]

This chapter of the law that establishes the Ohio Environmental Protection Agency establishes the rules and regulations regarding solid waste.

213

WasteTraining Booklet Waste & Recycling Impacts  

E-Print Network [OSTI]

WasteTraining Booklet #12;Waste & Recycling Impacts Environment: The majority of our municipal jobs while recycling 10,000 tons of waste creates 36 jobs. Environment: Recycling conserves resources. It takes 95% less energy to make aluminum from recycled aluminum than from virgin materials, 60% less

Saldin, Dilano

214

Hanford Site annual dangerous waste report: Volume 4, Waste Management Facility report, Radioactive mixed waste  

SciTech Connect (OSTI)

This report contains information on radioactive mixed wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, handling method and containment vessel, waste number, waste designation and amount of waste.

NONE

1994-12-31T23:59:59.000Z

215

Hanford Site annual dangerous waste report: Volume 2, Generator dangerous waste report, radioactive mixed waste  

SciTech Connect (OSTI)

This report contains information on radioactive mixed wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, waste number, waste designation, weight, and waste designation.

NONE

1994-12-31T23:59:59.000Z

216

Central Waste Complex (CWC) Waste Analysis Plan  

SciTech Connect (OSTI)

The purpose of this waste analysis plan (WAP) is to document the waste acceptance process, sampling methodologies, analytical techniques, and overall processes that are undertaken for waste accepted for storage at the Central Waste Complex (CWC), which is located in the 200 West Area of the Hanford Facility, Richland, Washington. Because dangerous waste does not include the source special nuclear and by-product material components of mixed waste, radionuclides are not within the scope of this document. The information on radionuclides is provided only for general knowledge. This document has been revised to meet the interim status waste analysis plan requirements of Washington Administrative Code (WAC) 173 303-300(5). When the final status permit is issued, permit conditions will be incorporated and this document will be revised accordingly.

ELLEFSON, M.D.

2000-01-06T23:59:59.000Z

217

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network [OSTI]

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

218

Aluminum Waste Reaction Indicators in a Municipal Solid Waste Landfill  

E-Print Network [OSTI]

Aluminum Waste Reaction Indicators in a Municipal Solid Waste Landfill Timothy D. Stark, F.ASCE1 landfills may contain aluminum from residential and commercial solid waste, industrial waste, and aluminum pro- duction wastes. Some aluminum-bearing waste materials, particularly aluminum production wastes

219

Radioactive mixed waste disposal  

SciTech Connect (OSTI)

Various types of waste have been generated during the 50-year history of the Hanford Site. Regulatory changes in the last 20 years have provided the emphasis for better management of these wastes. Interpretations of the Atomic Energy Act of 1954 (AEA), the Resource Conservation and Recovery Act of 1976 (RCRA), and the Hazardous and Solid Waste Amendments (HSWA) have led to the definition of radioactive mixed wastes (RMW). The radioactive and hazardous properties of these wastes have resulted in the initiation of special projects for the management of these wastes. Other solid wastes at the Hanford Site include low-level wastes, transuranic (TRU), and nonradioactive hazardous wastes. This paper describes a system for the treatment, storage, and disposal (TSD) of solid radioactive waste.

Jasen, W.G.; Erpenbeck, E.G.

1993-02-01T23:59:59.000Z

220

Understanding radioactive waste  

SciTech Connect (OSTI)

This document contains information on all aspects of radioactive wastes. Facts are presented about radioactive wastes simply, clearly and in an unbiased manner which makes the information readily accessible to the interested public. The contents are as follows: questions and concerns about wastes; atoms and chemistry; radioactivity; kinds of radiation; biological effects of radiation; radiation standards and protection; fission and fission products; the Manhattan Project; defense and development; uses of isotopes and radiation; classification of wastes; spent fuels from nuclear reactors; storage of spent fuel; reprocessing, recycling, and resources; uranium mill tailings; low-level wastes; transportation; methods of handling high-level nuclear wastes; project salt vault; multiple barrier approach; research on waste isolation; legal requiremnts; the national waste management program; societal aspects of radioactive wastes; perspectives; glossary; appendix A (scientific American articles); appendix B (reference material on wastes). (ATT)

Murray, R.L.

1981-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Radioactive Waste Management Manual  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

This Manual further describes the requirements and establishes specific responsibilities for implementing DOE O 435.1, Radioactive Waste Management, for the management of DOE high-level waste, transuranic waste, low-level waste, and the radioactive component of mixed waste. Change 1 dated 6/19/01 removes the requirement that Headquarters is to be notified and the Office of Environment, Safety and Health consulted for exemptions for use of non-DOE treatment facilities. Certified 1-9-07.

1999-07-09T23:59:59.000Z

222

Determination of Total Lipids as Fatty Acid Methyl Esters (FAME...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

will be replaced by an ester bond between the fatty acid and a methyl group, producing methyl esters of the fatty acids (FAME) and free glycerol. 1.4 The FAME are then...

223

Comparative Dynamics of Leucine Methyl Groups in FMOC-Leucine...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dynamics of Leucine Methyl Groups in FMOC-Leucine and in a ProteinHydrophobic Core Probed by Solid-State Deuteron Comparative Dynamics of Leucine Methyl Groups in FMOC-Leucine and...

224

Sub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments  

E-Print Network [OSTI]

-dependent, sphero-symmetric droplet combustion simulation that includes detailed gas phase chemical kineticsSub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments and detailed 2012 Abstract Combustion characteristics of isolated sub-millimeter sized methyl butanoate (MB

Walter, M.Todd

225

Mercury Methylation at Mercury Mines In The Humboldt River Basin, Nevada, USA  

SciTech Connect (OSTI)

Total Hg and methylmercury concentrations were measured in mine-waste calcines (retorted ore), sediment, and water samples collected in and around abandoned mercury mines in western Nevada to evaluate Hg methylation at the mines and in the Humboldt River basin. Mine-waste calcines contain total Hg concentrations as high as 14 000?g/g. Stream-sediment samples collected within 1 km of the mercury mines contain total Hg concentrations as high as 170?g/g, whereas stream sediments collected>5 km from the mines, and those collected from the Humboldt River and regional baseline sites, contain total Hg concentrations<0.5?g/g. Similarly, methylmercury concentrations in mine-waste calcines are locally as high as 96 ng/g, but methylmercury contents in stream-sediments collected downstream from the mines and from the Humboldt River are lower, ranging from<0.05 to 0.95 ng/g. Stream-water samples collected below two mines studied contain total Hg concentrations ranging from 6 to 2000 ng/L, whereas total Hg in Humboldt River water was generally lower ranging from 2.1 to 9.0 ng/L. Methylmercury concentrations in the Humboldt River water were the lowest in this study (<0.02-0.27 ng/L). Although total Hg and methylmercury concentrations are locally high in mine-waste calcines, there is significant dilution of Hg and lower Hg methylation down gradient from the mines, especially in the sediments and water collected from the Humboldt River, which is> 8 km from any mercury mines. Our data indicate little transference of Hg and methylmercury from the sediment to the water column due to the lack of mine runoff in this desert climate.

Gray, John E. (U.S. Geological Survey); Crock, James G. (U.S. Geological Survey); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

2002-12-01T23:59:59.000Z

226

Vapor-liquid equilibria for systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data were measured for binary systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa. The experimental data obtained in this work are thermodynamically consistent according to a point-to-point consistency test, and deviation from ideal behavior is small in all cases. They can be equally well correlated with the Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations.

Aucejo, A.; Burguet, M.C.; Monton, J.B.; Munoz, R.; Sanchotello, M.; Vazquez, M.I. (Univ. de Valencia (Spain). Dept. de Ingenieria Quimica)

1994-04-01T23:59:59.000Z

227

Georgia Hazardous Waste Management Act  

Broader source: Energy.gov [DOE]

The Georgia Hazardous Waste Management Act (HWMA) describes a comprehensive, Statewide program to manage hazardous wastes through regulating hazardous waste generation, transportation, storage,...

228

Waste Management Quality Assurance Plan  

E-Print Network [OSTI]

Revision 6 Waste Management Quality Assurance Plan Waste6 WM QA Plan Waste Management Quality Assurance Plan LBNL/4 Management Quality Assurance

Waste Management Group

2006-01-01T23:59:59.000Z

229

Hazardous Waste Act (New Mexico)  

Broader source: Energy.gov [DOE]

"Hazardous waste" means any solid waste or combination of solid wastes that because of their quantity, concentration or physical, chemical or infectious characteristics may: cause or significantly...

230

E-Print Network 3.0 - amplified methylation polymorphism Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 2 Infraspecific DNA Methylation Polymorphism in Cotton (Gossypium Summary: Infraspecific DNA Methylation Polymorphism in Cotton (Gossypium...

231

Waste-to-Energy: Waste Management and Energy Production Opportunities...  

Office of Environmental Management (EM)

Waste-to-Energy: Waste Management and Energy Production Opportunities Waste-to-Energy: Waste Management and Energy Production Opportunities July 24, 2014 9:00AM to 3:30PM EDT U.S....

232

Bioelectrochemical Integration of Waste Heat Recovery, Waste...  

Broader source: Energy.gov (indexed) [DOE]

and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes Air Products and Chemicals, Inc. - Allentown, PA A microbial reverse electrodialysis...

233

WASTE DISPOSAL WORKSHOPS: ANTHRAX CONTAMINATED WASTE  

E-Print Network [OSTI]

Demonstration LLNL Lawrence Livermore National Laboratory MSW Municipal Solid Waste OSHA Occupational Safety and Health Administration PPE Personal Protective Equipment POTW Publicly Owned Treatment Works RCRA Resource

234

Radioactive Waste Management Manual  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

This Manual further describes the requirements and establishes specific responsibilities for implementing DOE O 435.1, Radioactive Waste Management, for the management of DOE high-level waste, transuranic waste, low-level waste, and the radioactive component of mixed waste. The purpose of the Manual is to catalog those procedural requirements and existing practices that ensure that all DOE elements and contractors continue to manage DOE's radioactive waste in a manner that is protective of worker and public health and safety, and the environment. Does not cancel other directives.

1999-07-09T23:59:59.000Z

235

PROOF COPY [023113] 008209QEE [023113]008209QEE  

E-Print Network [OSTI]

as a replacement for the gasoline oxygenate, methyl tert-butyl ether MTBE , may lead to indirect impacts related facilitate the migration of pre-existing contamination. MTBE 25 mg/L influent was not degraded inlet by one order of magnitude relative to columns fed BTEX alone or with MTBE. However, 16S

Alvarez, Pedro J.

236

Environmental Toxicology and Chemistry, Vol. 21, No. 12, pp. 26312639, 2002 Printed in the USA  

E-Print Network [OSTI]

--Aquifer microcosms were used to determine how ethanol and methyl-tert-butyl ether (MtBE) affect monoaromatic compared to benzene, which was degraded only under aerobic conditions. The MtBE was not degraded within 100 to phase out MtBE as a gasoline oxy- genate is likely to significantly increase the use of ethanol

Alvarez, Pedro J.

237

90% of new cars have engines specially designed to run on hydrous ethanol. This avoids the expense of remov-  

E-Print Network [OSTI]

competes with gasoline (petrol), diesel and MTBE (methyl tert-butyl ether, added to gasoline to MTBE, however, ethanol is comparable regarding price per energy unit and has considerable environmental advantages. MTBE is added to gasoline as an octane booster, replac- ing the lead formerly used

238

Physico-chemical and biological characterization of an aquifer polluted with Yves Benoit (1)  

E-Print Network [OSTI]

to in order to meet specific requirements. Oxygenates such as methyl tert-butyl ether (MTBE) or ethyl tert on groundwater was not estimated prior to their utilization and the actual level of MTBE and ETBE contamination of MTBE- and ETBE-biodegradation is quite poor. Two directives have been adopted in the EU to promote

Paris-Sud XI, Université de

239

Critical Reviews in Environmental Science and Technology, 00(0):000000 (2001) 1064-3389/01/$.50  

E-Print Network [OSTI]

water contamination by methyl tert-butyl ether (MTBE) have made policymakers more cognizant of the need reformulated gasoline (RFG) (2% oxygen) year-round to reduce emissions that contribute to ozone formation. MTBE-making process that lead to the widespread use of MTBE over the last decade is now quite controversial (BRP, 1999

Alvarez, Pedro J.

240

Monitoring synaptic protein dynamics with higher temporal, spatial, and molecular resolution  

E-Print Network [OSTI]

Spectrometry mSOG MiniSOG MTBE Methyl tert-butyl ether mTORMethyl tert-butyl ether (MTBE, 1.4 mL) was then added for1,000 g, 5 min). The MTBE layer was collected into a 1.5-mL

Butko, Margaret

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

I. Pt-Catalyzed Tandem Epoxide Fragmentation/Pentannulation of Propargylic Esters II. Progress Toward the Kopsia Family of Indole Alkaloids  

E-Print Network [OSTI]

methyl t-butyl ether (MTBE), a much more environmentallyPhMe, reflux POCl 3 , Et 3 N CN MTBE Scheme 3.3: OptimizedO H NH POCl 3 , Et 3 N CN MTBE 1-Isocyanocyclohex-1-ene (

Pujanauski, Brian Gerard

2010-01-01T23:59:59.000Z

242

Effects of oxygenate concentration on species mole fractions in premixed n-heptane flames  

E-Print Network [OSTI]

-heptane/oxygenate mixtures were 2.7 and 3.4. Three different fuel oxygenates (i.e. MTBE, methanol, and ethanol) were tested tertiary-butyl ether (MTBE), ethyl tertiary-butyl ether (ETBE), and tertiary amyl methyl ether (TAME)) were considered as possible fuel oxygenates. MTBE and ethanol are the most common oxygenates currently used

Senkan, Selim M.

243

Fourier Transform Infrared Spectroscopy  

E-Print Network [OSTI]

FTIR - 1 Fourier Transform Infrared Spectroscopy FTIR DETERMINATION OF MTBE IN GASOLINE AND ETHANOL FTIR DETERMINATION OF MTBE IN GASOLINE AND ETHANOL IN VODKA AND MOUTHWASH INTRODUCTION As a part has contained MTBE (methyl tert­butyl ether) as its primary oxygenate. However, there has been

Nizkorodov, Sergey

244

Oxidation and methylation of dissolved elemental mercury by anaerobic bacteria  

SciTech Connect (OSTI)

Methylmercury is a neurotoxin that poses significant health risks to humans. Some anaerobic sulphate- and iron-reducing bacteria can methylate oxidized forms of mercury, generating methylmercury1-4. One strain of sulphate-reducing bacteria (Desulfovibrio desulfuricans ND132) can also methylate elemental mercury5. The prevalence of this trait among different bacterial strains and species remains unclear, however. Here, we compare the ability of two strains of the sulphate-reducing bacterium Desulfovibrio and one strain of the iron-reducing bacterium Geobacter to oxidise and methylate elemental mercury in a series of laboratory incubations. Experiments were carried out under dark, anaerobic conditions, in the presence of environmentally-relevant concentrations of elemental mercury. We report differences in the ability of these organisms to oxidise and methylate elemental mercury. In line with recent findings5, we show that Desulfovibrio desulfuricans ND132 can both oxidise and methylate elemental mercury. However, the rate of methylation of elemental mercury is only about one third the rate of methylation of oxidized mercury. We also show that Desulfovibrio alaskensis G20 can oxidise, but not methylate, elemental mercury. Geobacter sulfurreducens PCA is able to oxidise and methylate elemental mercury in the presence of cysteine. We suggest that the activity of methylating and non-methylating bacteria may together enhance the formation of methylmercury in anaerobic environments.

Hu, Haiyan [ORNL] [ORNL; Lin, Hui [ORNL] [ORNL; Zheng, Wang [ORNL] [ORNL; Tomanicek, Stephen J [ORNL] [ORNL; Johs, Alexander [ORNL] [ORNL; Feng, Xinbin [ORNL] [ORNL; Elias, Dwayne A [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Gu, Baohua [ORNL] [ORNL

2013-01-01T23:59:59.000Z

245

Solid Waste Management Written Program  

E-Print Network [OSTI]

Solid Waste Management Program Written Program Cornell University 8/28/2012 #12;Solid Waste.................................................................... 4 4.2.1 Compost Solid Waste Treatment Facility.................................................................... 4 4.2.2 Pathological Solid Waste Treatment Facility

Pawlowski, Wojtek

246

Radioactive Waste: 1. Radioactive waste from your lab is  

E-Print Network [OSTI]

Radioactive Waste: 1. Radioactive waste from your lab is collected by the RSO. 2. Dry radioactive waste must be segregated by isotope. 3. Liquid radioactive waste must be separated by isotope. 4. Liquid frequently and change them if contaminated. 5. Use radioactive waste container to collect the waste. 6. Check

Jia, Songtao

247

www.d-waste.com info@d-waste.com  

E-Print Network [OSTI]

, the International Solid Waste Association, GIZ/SWEEP-Net, the Waste to Energy Research Council (WTERT) and the Solidwww.d-waste.com info@d-waste.com Acharnon 141 10446 ATHENS GREECE T: +30 2155302449 F: +30 2155302447 For Release November 13, 2013 Waste Atlas shows how the world handles its refuse D-Waste

248

Hazardous Waste Management (Arkansas)  

Broader source: Energy.gov [DOE]

The Hazardous Waste Program is carried out by the Arkansas Department of Environmental Quality which administers its' program under the Hazardous Waste management Act (Arkansas Code Annotated 8-7...

249

Hazardous Waste Management (Delaware)  

Broader source: Energy.gov [DOE]

The act authorizes the Delaware Department of Natural Resources and Environment Control (DNREC) to regulate hazardous waste and create a program to manage sources of hazardous waste. The act...

250

Hazardous Waste Management (Oklahoma)  

Broader source: Energy.gov [DOE]

This article states regulations for the disposal of hazardous waste. It also provides information about permit requirements for the transport, treatment and storage of such waste. It also mentions...

251

Pet Waste Management  

E-Print Network [OSTI]

About 1 million pounds of dog waste is deposited daily in North Texas alone. That's why proper disposal of pet waste can make a big difference in the environment. 5 photos, 2 pages...

Mechell, Justin; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

252

Waste Management and WasteWaste Management and Waste--toto--EnergyEnergy Status in SingaporeStatus in Singapore  

E-Print Network [OSTI]

Waste Management and WasteWaste Management and Waste--toto--EnergyEnergy Status in Singapore #12;Singapore's Waste Management · In 2003, 6877 tonnes/day (2.51 M tonnes/year) of MSW collected plants · 8% (non-incinerable waste) and incineration ash goes to the offshore Semakau Landfill · To reach

Columbia University

253

Waste disposal package  

DOE Patents [OSTI]

This is a claim for a waste disposal package including an inner or primary canister for containing hazardous and/or radioactive wastes. The primary canister is encapsulated by an outer or secondary barrier formed of a porous ceramic material to control ingress of water to the canister and the release rate of wastes upon breach on the canister. 4 figs.

Smith, M.J.

1985-06-19T23:59:59.000Z

254

Rethinking the Waste Hierarchy  

E-Print Network [OSTI]

principles of EU waste policies. The environmental damage caused by waste depends on which type of manage, Environmental Assessment Institute For further information please contact: Environmental Assessment Institute.imv.dk #12;Environmental Assessment Institute Rethinking the Waste Hierarchy March 2005 Recommendations

255

Biodiesel production using waste frying oil  

SciTech Connect (OSTI)

Research highlights: {yields} Waste sunflower frying oil is successfully converted to biodiesel using lipase as catalyst. {yields} Various process parameters that affects the conversion of transesterification reaction such as temperature, enzyme concentration, methanol: oil ratio and solvent are optimized. {yields} Inhibitory effect of methanol on lipase is reduced by adding methanol in three stages. {yields} Polar solvents like n-hexane and n-heptane increases the conversion of tranesterification reaction. - Abstract: Waste sunflower frying oil is used in biodiesel production by transesterification using an enzyme as a catalyst in a batch reactor. Various microbial lipases have been used in transesterification reaction to select an optimum lipase. The effects of various parameters such as temperature, methanol:oil ratio, enzyme concentration and solvent on the conversion of methyl ester have been studied. The Pseudomonas fluorescens enzyme yielded the highest conversion. Using the P. fluorescens enzyme, the optimum conditions included a temperature of 45 deg. C, an enzyme concentration of 5% and a methanol:oil molar ratio 3:1. To avoid an inhibitory effect, the addition of methanol was performed in three stages. The conversion obtained after 24 h of reaction increased from 55.8% to 63.84% because of the stage-wise addition of methanol. The addition of a non-polar solvent result in a higher conversion compared to polar solvents. Transesterification of waste sunflower frying oil under the optimum conditions and single-stage methanol addition was compared to the refined sunflower oil.

Charpe, Trupti W. [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India); Rathod, Virendra K., E-mail: vk.rathod@ictmumbai.edu.in [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India)

2011-01-15T23:59:59.000Z

256

Identifying Mixed Chemical and Radioactive Waste Mixed waste is: any waste material containing both radioactive materials  

E-Print Network [OSTI]

Identifying Mixed Chemical and Radioactive Waste Mixed waste is: any waste material containing both as noted on the list, you do not have a mixed waste and it may be managed as a normal radioactive waste radioactive waste after initially dating the container, the hold for decay time is extended, but you cannot

Straight, Aaron

257

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which can lead to public health problems. * MtBE (Methyl tert Butyl Ether), a gasoline additive, has begun to contaminate ground water supplies. * Similarly, perchlorate has...

258

Municipal waste processing apparatus  

DOE Patents [OSTI]

This invention relates to apparatus for processing municipal waste, and more particularly to vibrating mesh screen conveyor systems for removing grit, glass, and other noncombustible materials from dry municipal waste. Municipal waste must be properly processed and disposed of so that it does not create health risks to the community. Generally, municipal waste, which may be collected in garbage trucks, dumpsters, or the like, is deposited in processing areas such as landfills. Land and environmental controls imposed on landfill operators by governmental bodies have increased in recent years, however, making landfill disposal of solid waste materials more expensive. 6 figs.

Mayberry, J.L.

1988-04-13T23:59:59.000Z

259

Radioactive Waste Management Basis  

SciTech Connect (OSTI)

The purpose of this Radioactive Waste Management Basis is to describe the systematic approach for planning, executing, and evaluating the management of radioactive waste at LLNL. The implementation of this document will ensure that waste management activities at LLNL are conducted in compliance with the requirements of DOE Order 435.1, Radioactive Waste Management, and the Implementation Guide for DOE Manual 435.1-1, Radioactive Waste Management Manual. Technical justification is provided where methods for meeting the requirements of DOE Order 435.1 deviate from the DOE Manual 435.1-1 and Implementation Guide.

Perkins, B K

2009-06-03T23:59:59.000Z

260

Radioactive Waste Management Manual  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

This Manual further describes the requirements and establishes specific responsibilities for implementing DOE O 435.1, Radioactive Waste Management, for the management of DOE high-level waste, transuranic waste, low-level waste, and the radioactive component of mixed waste. Change 1 dated 6/19/01 removes the requirement that Headquarters is to be notified and the Office of Environment, Safety and Health consulted for exemptions for use of non-DOE treatment facilities. Certified 1-9-07. Admin Chg 2, dated 6-8-11, cancels DOE M 435.1-1 Chg 1.

1999-07-09T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Mixed waste: Proceedings  

SciTech Connect (OSTI)

This volume contains the peer-reviewed and edited versions of papers submitted for presentation a the Second International Mixed Waste Symposium. Following the tradition of the First International Mixed Waste Symposium, these proceedings were prepared in advance of the meeting for distribution to participants. The symposium was organized by the Mixed Waste Committee of the American Society of Mechanical Engineers. The topics discussed at the symposium include: stabilization technologies, alternative treatment technologies, regulatory issues, vitrification technologies, characterization of wastes, thermal technologies, laboratory and analytical issues, waste storage and disposal, organic treatment technologies, waste minimization, packaging and transportation, treatment of mercury contaminated wastes and bioprocessing, and environmental restoration. Individual abstracts are catalogued separately for the data base.

Moghissi, A.A.; Blauvelt, R.K.; Benda, G.A.; Rothermich, N.E. [eds.] [Temple Univ., Philadelphia, PA (United States). Dept. of Environmental Safety and Health

1993-12-31T23:59:59.000Z

262

An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion  

SciTech Connect (OSTI)

Biodiesel is typically a mixture of long chain fatty acid methyl esters for use in compression ignition engines. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This research study presents new combustion data for methyl decanoate in an opposed-flow diffusion flame. An improved detailed chemical kinetic model for methyl decanoate combustion is developed, which serves as the basis for deriving a skeletal mechanism via the direct relation graph method. The novel skeletal mechanism consists of 648 species and 2998 reactions. This mechanism well predicts the methyl decanoate opposed-flow diffusion flame data. The results from the flame simulations indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

2010-02-19T23:59:59.000Z

263

Bioelectrochemical Integration of Waste Heat Recovery, Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

electrolytic cell, designed to integrate waste heat recovery (i.e a microbial heat recovery cell or MHRC), can operate as a fuel cell and convert effluent streams into...

264

New Waste Calcining Facility (NWCF) Waste Streams  

SciTech Connect (OSTI)

This report addresses the issues of conducting debris treatment in the New Waste Calcine Facility (NWCF) decontamination area and the methods currently being used to decontaminate material at the NWCF.

K. E. Archibald

1999-08-01T23:59:59.000Z

265

Transuranic (TRU) Waste | Department of Energy  

Office of Environmental Management (EM)

Transuranic (TRU) Waste Transuranic (TRU) Waste Transuranic (TRU) Waste Defined by the WIPP Land Withdrawal Act as "waste containing more than 100 nanocuries of alpha-emitting...

266

Solid Waste Management Plan. Revision 4  

SciTech Connect (OSTI)

The waste types discussed in this Solid Waste Management Plan are Municipal Solid Waste, Hazardous Waste, Low-Level Mixed Waste, Low-Level Radioactive Waste, and Transuranic Waste. The plan describes for each type of solid waste, the existing waste management facilities, the issues, and the assumptions used to develop the current management plan.

NONE

1995-04-26T23:59:59.000Z

267

Ferrocyanide tank waste stability  

SciTech Connect (OSTI)

Ferrocyanide wastes were generated at the Hanford Site during the mid to late 1950s as a result of efforts to create more tank space for the storage of high-level nuclear waste. The ferrocyanide process was developed to remove [sup 137]CS from existing waste and newly generated waste that resulted from the recovery of valuable uranium in Hanford Site waste tanks. During the course of research associated with the ferrocyanide process, it was recognized that ferrocyanide materials, when mixed with sodium nitrate and/or sodium nitrite, were capable of violent exothermic reaction. This chemical reactivity became an issue in the 1980s, when safety issues associated with the storage of ferrocyanide wastes in Hanford Site tanks became prominent. These safety issues heightened in the late 1980s and led to the current scrutiny of the safety issues associated with these wastes, as well as current research and waste management programs. Testing to provide information on the nature of possible tank reactions is ongoing. This document supplements the information presented in Summary of Single-Shell Tank Waste Stability, WHC-EP-0347, March 1991 (Borsheim and Kirch 1991), which evaluated several issues. This supplement only considers information particular to ferrocyanide wastes.

Fowler, K.D.

1993-01-01T23:59:59.000Z

268

Energy from Waste UK Joint Statement on Energy from Waste  

E-Print Network [OSTI]

Energy from Waste UK Joint Statement on Energy from Waste Read more overleaf Introduction Energy from waste provides us with an opportunity for a waste solution and a local source of energy rolled,itcan onlyaddressaportionofthewastestream andisnotsufficientonitsown. Energy obtained from the combustion of residual waste (Energy from

269

Hanford Tank Waste Information Enclosure 1 Hanford Tank Waste Information  

E-Print Network [OSTI]

Hanford Tank Waste Information Enclosure 1 1 Hanford Tank Waste Information 1.0 Summary This information demonstrates the wastes in the twelve Hanford Site tanks meet the definition of transuranic (TRU. The wastes in these twelve (12) tanks are not high-level waste (HLW), and contain more than 100 nanocuries

270

Stabilization of compactible waste  

SciTech Connect (OSTI)

This report summarizes the results of series of experiments performed to determine the feasibility of stabilizing compacted or compactible waste with polymers. The need for this work arose from problems encountered at disposal sites attributed to the instability of this waste in disposal. These studies are part of an experimental program conducted at Brookhaven National Laboratory (BNL) investigating methods for the improved solidification/stabilization of DOE low-level wastes. The approach taken in this study was to perform a series of survey type experiments using various polymerization systems to find the most economical and practical method for further in-depth studies. Compactible dry bulk waste was stabilized with two different monomer systems: styrene-trimethylolpropane trimethacrylate (TMPTMA) and polyester-styrene, in laboratory-scale experiments. Stabilization was accomplished by wetting or soaking compactible waste (before or after compaction) with monomers, which were subsequently polymerized. Three stabilization methods are described. One involves the in-situ treatment of compacted waste with monomers in which a vacuum technique is used to introduce the binder into the waste. The second method involves the alternate placement and compaction of waste and binder into a disposal container. In the third method, the waste is treated before compaction by wetting the waste with the binder using a spraying technique. A series of samples stabilized at various binder-to-waste ratios were evaluated through water immersion and compression testing. Full-scale studies were conducted by stabilizing two 55-gallon drums of real compacted waste. The results of this preliminary study indicate that the integrity of compacted waste forms can be readily improved to ensure their long-term durability in disposal environments. 9 refs., 10 figs., 2 tabs.

Franz, E.M.; Heiser, J.H. III; Colombo, P.

1990-09-01T23:59:59.000Z

271

Methyl viologen radical reactions with several oxidizing agents. [Gamma Radiation  

SciTech Connect (OSTI)

The rates of oxidation of the methyl viologen radical by peroxodisulfate and hydrogen peroxide has been investigated. The methyl viologen free radical was produced by pulse radiolysis. The reaction of the peroxodisulfate radical with the methyl viologen radical was first order in both species, and the reaction rate constant is reported. A el-radiation study revealed a chain decomposition of the peroxodisulfate radical involving the methyl viologen radical when methanol, ethanol, or 2-propanol was present. Loss of the methyl viologen radical was then no longer observed to be a simple first-order reaction. The reaction of hydrogen peroxide with the methyl viologen radical was very slow in the presence of 1 M methanol. A much faster reaction in the absence of methanol was interpreted to be a reaction of the methyl viologen radical with the peroxy radicals. Hydrogen peroxide, in contrast to the chain decomposition of peroxodisulfate radicals, does not participate in a chain reaction involving the methyl viologen radical and methanol. Rate constants for the reaction of methyl viologen radical with dichromate radical, iodate radical, and ferricyanide radical are reported.

Levey, G.; Ebbesen, T.W.

1983-01-01T23:59:59.000Z

272

Underground waste barrier structure  

DOE Patents [OSTI]

Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.

Saha, Anuj J. (Hamburg, NY); Grant, David C. (Gibsonia, PA)

1988-01-01T23:59:59.000Z

273

Guidelines for mixed waste minimization  

SciTech Connect (OSTI)

Currently, there is no commercial mixed waste disposal available in the United States. Storage and treatment for commercial mixed waste is limited. Host States and compacts region officials are encouraging their mixed waste generators to minimize their mixed wastes because of management limitations. This document provides a guide to mixed waste minimization.

Owens, C.

1992-02-01T23:59:59.000Z

274

Operational Waste Volume Projection  

SciTech Connect (OSTI)

Waste receipts to the double-shell tank system are analyzed and wastes through the year 2015 are projected based on generation trends of the past 12 months. A computer simulation of site operations is performed, which results in projections of tank fill schedules, tank transfers, evaporator operations, tank retrieval, and aging waste tank usage. This projection incorporates current budget planning and the clean-up schedule of the Tri-Party Agreement. Assumptions were current as of June. 2000.

STRODE, J.N.

2000-08-28T23:59:59.000Z

275

Operational waste volume projection  

SciTech Connect (OSTI)

Waste receipts to the double-shell tank system are analyzed and wastes through the year 2015 are projected based on generation trends of the past 12 months. A computer simulation of site operations is performed, which results in projections of tank fill schedules, tank transfers, evaporator operations, tank retrieval, and aging waste tank usage. This projection incorporates current budget planning and the clean-up schedule of the Tri-Party Agreement. Assumptions were current as of June 1996.

Koreski, G.M.

1996-09-20T23:59:59.000Z

276

Hazardous Waste Management (Indiana)  

Broader source: Energy.gov [DOE]

The state supports the implementation of source reduction, recycling, and other alternative solid waste management practices over incineration and land disposal. The Department of Environmental...

277

Waste Heat Recovery  

Office of Environmental Management (EM)

DRAFT - PRE-DECISIONAL - DRAFT 1 Waste Heat Recovery 1 Technology Assessment 2 Contents 3 1. Introduction to the TechnologySystem ......

278

Norcal Waste Systems, Inc.  

SciTech Connect (OSTI)

Fact sheet describes the LNG long-haul heavy-duty trucks at Norcal Waste Systems Inc.'s Sanitary Fill Company.

Not Available

2002-12-01T23:59:59.000Z

279

Solid Waste Management (Connecticut)  

Broader source: Energy.gov [DOE]

Solid waste facilities operating in Connecticut must abide by these regulations, which describe requirements and procedures for issuing construction and operating permits; environmental...

280

Solid Waste Policies (Iowa)  

Broader source: Energy.gov [DOE]

This statute establishes the support of the state for alternative waste management practices that reduce the reliance upon land disposal and incorporate resource recovery. Cities and counties are...

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Solid Waste Management (Indiana)  

Broader source: Energy.gov [DOE]

The state supports the implementation of source reduction, recycling, and other alternative solid waste management practices over incineration and land disposal. The Indiana Department of...

282

Avoidable waste management costs  

SciTech Connect (OSTI)

This report describes the activity based costing method used to acquire variable (volume dependent or avoidable) waste management cost data for routine operations at Department of Energy (DOE) facilities. Waste volumes from environmental restoration, facility stabilization activities, and legacy waste were specifically excluded from this effort. A core team consisting of Idaho National Engineering Laboratory, Los Alamos National Laboratory, Rocky Flats Environmental Technology Site, and Oak Ridge Reservation developed and piloted the methodology, which can be used to determine avoidable waste management costs. The method developed to gather information was based on activity based costing, which is a common industrial engineering technique. Sites submitted separate flow diagrams that showed the progression of work from activity to activity for each waste type or treatability group. Each activity on a flow diagram was described in a narrative, which detailed the scope of the activity. Labor and material costs based on a unit quantity of waste being processed were then summed to generate a total cost for that flow diagram. Cross-complex values were calculated by determining a weighted average for each waste type or treatability group based on the volume generated. This study will provide DOE and contractors with a better understanding of waste management processes and their associated costs. Other potential benefits include providing cost data for sites to perform consistent cost/benefit analysis of waste minimization and pollution prevention (WMIN/PP) options identified during pollution prevention opportunity assessments and providing a means for prioritizing and allocating limited resources for WMIN/PP.

Hsu, K.; Burns, M.; Priebe, S.; Robinson, P.

1995-01-01T23:59:59.000Z

283

Solid Waste Permits (Louisiana)  

Broader source: Energy.gov [DOE]

The Louisiana Department of Environmental Quality administers the rules and regulations governing the storage, collection, processing, recovery, and reuse of solid waste protect the air,...

284

Solid Waste Management (Michigan)  

Broader source: Energy.gov [DOE]

This Act encourages the Department of Environmental Quality and Health Department representatives to develop and encourage methods for disposing solid waste that are environmentally sound, that...

285

Vitrification of waste  

DOE Patents [OSTI]

A method for encapsulating and immobilizing waste for disposal. Waste, preferably, biologically, chemically and radioactively hazardous, and especially electronic wastes, such as circuit boards, are placed in a crucible and heated by microwaves to a temperature in the range of approximately 300.degree. C. to 800.degree. C. to incinerate organic materials, then heated further to a temperature in the range of approximately 1100.degree. C. to 1400.degree. C. at which temperature glass formers present in the waste will cause it to vitrify. Glass formers, such as borosilicate glass, quartz or fiberglass can be added at the start of the process to increase the silicate concentration sufficiently for vitrification.

Wicks, George G. (Aiken, SC)

1999-01-01T23:59:59.000Z

286

Vitrification of waste  

DOE Patents [OSTI]

A method is described for encapsulating and immobilizing waste for disposal. Waste, preferably, biologically, chemically and radioactively hazardous, and especially electronic wastes, such as circuit boards, are placed in a crucible and heated by microwaves to a temperature in the range of approximately 300 C to 800 C to incinerate organic materials, then heated further to a temperature in the range of approximately 1100 C to 1400 C at which temperature glass formers present in the waste will cause it to vitrify. Glass formers, such as borosilicate glass, quartz or fiberglass can be added at the start of the process to increase the silicate concentration sufficiently for vitrification.

Wicks, G.G.

1999-04-06T23:59:59.000Z

287

Waste minimization assessment procedure  

SciTech Connect (OSTI)

Perry Nuclear Power Plant began developing a waste minimization plan early in 1991. In March of 1991 the plan was documented following a similar format to that described in the EPA Waste Minimization Opportunity Assessment Manual. Initial implementation involved obtaining management's commitment to support a waste minimization effort. The primary assessment goal was to identify all hazardous waste streams and to evaluate those streams for minimization opportunities. As implementation of the plan proceeded, non-hazardous waste streams routinely generated in large volumes were also evaluated for minimization opportunities. The next step included collection of process and facility data which would be useful in helping the facility accomplish its assessment goals. This paper describes the resources that were used and which were most valuable in identifying both the hazardous and non-hazardous waste streams that existed on site. For each material identified as a waste stream, additional information regarding the materials use, manufacturer, EPA hazardous waste number and DOT hazard class was also gathered. Once waste streams were evaluated for potential source reduction, recycling, re-use, re-sale, or burning for heat recovery, with disposal as the last viable alternative.

Kellythorne, L.L. (Centerior Energy, Cleveland, OH (United States))

1993-01-01T23:59:59.000Z

288

Secondary Waste Cast Stone Waste Form Qualification Testing Plan  

SciTech Connect (OSTI)

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the 56 million gallons of radioactive waste stored in 177 underground tanks at the Hanford Site. The WTP includes a pretreatment facility to separate the wastes into high-level waste (HLW) and low-activity waste (LAW) fractions for vitrification and disposal. The LAW will be converted to glass for final disposal at the Integrated Disposal Facility (IDF). Cast Stone a cementitious waste form, has been selected for solidification of this secondary waste stream after treatment in the ETF. The secondary-waste Cast Stone waste form must be acceptable for disposal in the IDF. This secondary waste Cast Stone waste form qualification testing plan outlines the testing of the waste form and immobilization process to demonstrate that the Cast Stone waste form can comply with the disposal requirements. Specifications for the secondary-waste Cast Stone waste form have not been established. For this testing plan, Cast Stone specifications are derived from specifications for the immobilized LAW glass in the WTP contract, the waste acceptance criteria for the IDF, and the waste acceptance criteria in the IDF Permit issued by the State of Washington. This testing plan outlines the testing needed to demonstrate that the waste form can comply with these waste form specifications and acceptance criteria. The testing program must also demonstrate that the immobilization process can be controlled to consistently provide an acceptable waste form product. This testing plan also outlines the testing needed to provide the technical basis for understanding the long-term performance of the waste form in the disposal environment. These waste form performance data are needed to support performance assessment analyses of the long-term environmental impact of the secondary-waste Cast Stone waste form in the IDF

Westsik, Joseph H.; Serne, R. Jeffrey

2012-09-26T23:59:59.000Z

289

Waste Treatment and Immobilation Plant HLW Waste Vitrification...  

Office of Environmental Management (EM)

6 Technology Readiness Assessment for the Waste Treatment and Immobilization Plant (WTP) HLW Waste Vitrification Facility L. Holton D. Alexander C. Babel H. Sutter J. Young August...

290

Municipal Waste Planning, Recycling and Waste Reduction Act (Pennsylvania)  

Broader source: Energy.gov [DOE]

This act provides for planning for the processing and disposal of municipal waste; requires counties to submit plans for municipal waste management systems within their boundaries; authorizes...

291

ORTH/VIM proteins that regulate DNA methylation are functional ubiquitin E3 ligases  

E-Print Network [OSTI]

ORTH/VIM proteins that regulate DNA methylation are functional ubiquitin E3 ligases Edward Kraft1 methylation status in vivo. Keywords: RING, E3 ligase, DNA methylation, ubiquitylation, ORTH/VIM, SRA

Jacobsen, Steve

292

Hazardous Waste Management (North Carolina)  

Broader source: Energy.gov [DOE]

These rules identify and list hazardous waste and set standards for the generators and operators of such waste as well as owners or operators of waste facilities. They also stats standards for...

293

Virginia Waste Management Act (Virginia)  

Broader source: Energy.gov [DOE]

Solid waste and hazardous waste are regulated under a number of programs at the Department of Environmental Quality. These programs are designed to encourage the reuse and recycling of solid waste...

294

Solid Waste Disposal Act (Texas)  

Broader source: Energy.gov [DOE]

The Texas Commission on Environmental Quality is responsible for the regulation and management of municipal solid waste and hazardous waste. A fee is applied to all solid waste disposed in the...

295

Solid Waste Act (New Mexico)  

Broader source: Energy.gov [DOE]

The main purpose of the Solid Waste Act is to authorize and direct the establishment of a comprehensive solid waste management program. The act states details about specific waste management...

296

Georgia Waste Control Law (Georgia)  

Broader source: Energy.gov [DOE]

The Waste Control Law makes it unlawful to dump waste in any lakes, streams or surfaces waters of the State or on any private property without consent of the property owner. Waste is very broadly...

297

Host cells and methods for producing 3-methyl-2-buten-1-ol, 3-methyl-3-buten-1-ol, and 3-methyl-butan-1-ol  

DOE Patents [OSTI]

The invention provides for a method for producing a 5-carbon alcohol in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses a first enzyme capable of catalyzing the dephosphorylation of an isopentenyl pyrophosphate (IPP) or dimethylallyl diphosphate (DMAPP), such as a Bacillus subtilis phosphatase (YhfR), under a suitable condition so that 5-carbon alcohol is 3-methyl-2-buten-1-ol and/or 3-methyl-3-buten-1-ol is produced. Optionally, the host cell may further comprise a second enzyme capable of reducing a 3-methyl-2-buten-1-ol to 3-methyl-butan-1-ol, such as a reductase.

Chou, Howard H. (Berkeley, CA); Keasling, Jay D. (Berkeley, CA)

2011-07-26T23:59:59.000Z

298

WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,  

E-Print Network [OSTI]

DESCRIPTION DETAILS * Radioactive Waste Source Reduction 1,500 Radioactive Waste $6,000 $2,500 $6,000 Waste Yard Sorting Table surveying to sort clean waste from radioactive waste Radioactive Emissions Emission lives. Radioactive Waste generated through wet chemistry Waste Minimization 30 Mixed waste / Liquid

299

Solid Waste Paul Woodson, East Central University  

E-Print Network [OSTI]

of groundwater contamination, air pollution, and odor. Solid wastes may be displeasing to the public either, industrial and medical wastes, food wastes, mineral waste, and nonhazardous wastes. In addition/reservoirs, special wastes, such as medical wastes, low level radioactive wastes, construction/demolition debris

300

Animal Waste Technology Fund (Maryland)  

Broader source: Energy.gov [DOE]

A bill passed in 2012 transferred responsibility for animal waste management technology projects to the Maryland Department of Agriculture. The Department will maintain the Animal Waste Technology...

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Nebraska Hazardous Waste Regulations (Nebraska)  

Broader source: Energy.gov [DOE]

These regulations, promulgated by the Department of Environmental Quality, contain provisions pertaining to hazardous waste management, waste standards, permitting requirements, and land disposal...

302

RADIOACTIVE WASTE DISPOSAL IN GRANITE  

E-Print Network [OSTI]

RADIOACTIVE WASTE DISPOSAL IN GRANITE Paul A. WitherspoonRADIOACTIVE WASTE DISPOSAL IN GRANITE Paul A. Wither spoona repository site in granite are to evaluate the suitability

Witherspoon, P.A.

2010-01-01T23:59:59.000Z

303

Solid Waste Management Act (Oklahoma)  

Broader source: Energy.gov [DOE]

This Act establishes rules for the permitting, posting of security, construction, operation, closure, maintenance and remediation of solid waste disposal sites; disposal of solid waste in ways that...

304

Solid Waste Management (South Dakota)  

Broader source: Energy.gov [DOE]

This statute contains provisions for solid waste management systems, groundwater monitoring, liability for pollution, permitting, inspections, and provisions for waste reduction and recycling...

305

Hazardous Waste Management (New Mexico)  

Broader source: Energy.gov [DOE]

The New Mexico Environment Department's Hazardous Waste Bureau is responsible for the management of hazardous waste in the state. The Bureau enforces the rules established by the Environmental...

306

Solid Waste Rules (New Hampshire)  

Broader source: Energy.gov [DOE]

The solid waste statute applies to construction and demolition debris, appliances, recyclables, and the facilities that collect, process, and dispose of solid waste. DES oversees the management of...

307

Solid Waste Management (North Carolina)  

Broader source: Energy.gov [DOE]

The Solid Waste Program regulates safe management of solid waste through guidance, technical assistance, regulations, permitting, environmental monitoring, compliance evaluation and enforcement....

308

Radioactive waste disposal package  

DOE Patents [OSTI]

A radioactive waste disposal package comprising a canister for containing vitrified radioactive waste material and a sealed outer shell encapsulating the canister. A solid block of filler material is supported in said shell and convertible into a liquid state for flow into the space between the canister and outer shell and subsequently hardened to form a solid, impervious layer occupying such space.

Lampe, Robert F. (Bethel Park, PA)

1986-01-01T23:59:59.000Z

309

Hazardous Waste Management Training  

E-Print Network [OSTI]

Hazardous Waste Management Training Persons (including faculty, staff and students) working with hazardous materials should receive annual training that addresses storage, use, and disposal of hazardous before handling hazardous waste. Departments are re- quired to keep records of training for as long

Dai, Pengcheng

310

Nuclear waste solutions  

DOE Patents [OSTI]

High efficiency removal of technetium values from a nuclear waste stream is achieved by addition to the waste stream of a precipitant contributing tetraphenylphosphonium cation, such that a substantial portion of the technetium values are precipitated as an insoluble pertechnetate salt.

Walker, Darrel D. (1684 Partridge Dr., Aiken, SC 29801); Ebra, Martha A. (129 Hasty Rd., Aiken, SC 29801)

1987-01-01T23:59:59.000Z

311

Waste classification sampling plan  

SciTech Connect (OSTI)

The purpose of this sampling is to explain the method used to collect and analyze data necessary to verify and/or determine the radionuclide content of the B-Cell decontamination and decommissioning waste stream so that the correct waste classification for the waste stream can be made, and to collect samples for studies of decontamination methods that could be used to remove fixed contamination present on the waste. The scope of this plan is to establish the technical basis for collecting samples and compiling quantitative data on the radioactive constituents present in waste generated during deactivation activities in B-Cell. Sampling and radioisotopic analysis will be performed on the fixed layers of contamination present on structural material and internal surfaces of process piping and tanks. In addition, dose rate measurements on existing waste material will be performed to determine the fraction of dose rate attributable to both removable and fixed contamination. Samples will also be collected to support studies of decontamination methods that are effective in removing the fixed contamination present on the waste. Sampling performed under this plan will meet criteria established in BNF-2596, Data Quality Objectives for the B-Cell Waste Stream Classification Sampling, J. M. Barnett, May 1998.

Landsman, S.D.

1998-05-27T23:59:59.000Z

312

E-Print Network 3.0 - arsenic methylation profiles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: , urinary arsenic methylation profiles, and urothelial carcinoma susceptibility. Food Chem. Toxicol. 46, 929... and in vitro studies suggest that methylated arsenic...

313

Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container  

E-Print Network [OSTI]

of Energy (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees Isolation Plan (Plan) for identified nitrate salt bearing waste disposed in the Waste Isolation Pilot Plant detailed proposal for the expedited closure of underground Hazardous Waste Disposal Unit (HWDU) Panel 6, so

Napp, Nils

314

TRU Waste Sampling Program: Volume I. Waste characterization  

SciTech Connect (OSTI)

Volume I of the TRU Waste Sampling Program report presents the waste characterization information obtained from sampling and characterizing various aged transuranic waste retrieved from storage at the Idaho National Engineering Laboratory and the Los Alamos National Laboratory. The data contained in this report include the results of gas sampling and gas generation, radiographic examinations, waste visual examination results, and waste compliance with the Waste Isolation Pilot Plant-Waste Acceptance Criteria (WIPP-WAC). A separate report, Volume II, contains data from the gas generation studies.

Clements, T.L. Jr.; Kudera, D.E.

1985-09-01T23:59:59.000Z

315

Radioactive waste material disposal  

DOE Patents [OSTI]

The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide. 3 figs.

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

1995-10-24T23:59:59.000Z

316

Radioactive waste material disposal  

DOE Patents [OSTI]

The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide.

Forsberg, Charles W. (155 Newport Dr., Oak Ridge, TN 37830); Beahm, Edward C. (106 Cooper Cir., Oak Ridge, TN 37830); Parker, George W. (321 Dominion Cir., Knoxville, TN 37922)

1995-01-01T23:59:59.000Z

317

Hazardous Waste Disposal Sites (Iowa)  

Broader source: Energy.gov [DOE]

These sections contain information on fees and monitoring relevant to operators of hazardous waste disposal sites.

318

Waste incineration and the community -  

E-Print Network [OSTI]

strategy followed by the operator of Amsterdam's waste-to- energy plant has convinced the public and other growing amounts of waste In 1992, the City of Amsterdam created Afval Energie Bedrijf (AEB), a waste-to-energy as much energy and materials as possible from municipal waste while protecting the environment. It seeks

Columbia University

319

Waste to Energy Time Activities  

E-Print Network [OSTI]

SEMINAR Waste to Energy Time Activities 9:30-9:40 Brief introduction of participants 9:40-10:10 Presentation of Dr. Kalogirou, "Waste to Energy: An Integral Part of Worldwide Sustainable Waste Management" 10. Sofia Bethanis, "Production of synthetic aggregates for use in structural concrete from waste to energy

320

Copenhagen Waste Management and Incineration  

E-Print Network [OSTI]

Copenhagen Waste Management and Incineration Florence, April 24 2009 Julie B. Svendsen incentives · Waste Management plan 2012 · Incineration plants #12;Florence, April 24 20093 Copenhagen Waste ownership of treatment facilities · Incineration plants · Land fill · Disposal of hazardous waste · Source

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Generating power with waste wood  

SciTech Connect (OSTI)

Among the biomass renewables, waste wood has great potential with environmental and economic benefits highlighting its resume. The topics of this article include alternate waste wood fuel streams; combustion benefits; waste wood comparisons; waste wood ash; pilot scale tests; full-scale test data; permitting difficulties; and future needs.

Atkins, R.S.

1995-02-01T23:59:59.000Z

322

Methane generation from waste materials  

DOE Patents [OSTI]

An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

Samani, Zohrab A. (Las Cruces, NM); Hanson, Adrian T. (Las Cruces, NM); Macias-Corral, Maritza (Las Cruces, NM)

2010-03-23T23:59:59.000Z

323

Certification Plan, low-level waste Hazardous Waste Handling Facility  

SciTech Connect (OSTI)

The purpose of this plan is to describe the organization and methodology for the certification of low-level radioactive waste (LLW) handled in the Hazardous Waste Handling Facility (HWHF) at Lawrence Berkeley Laboratory (LBL). This plan also incorporates the applicable elements of waste reduction, which include both up-front minimization and end-product treatment to reduce the volume and toxicity of the waste; segregation of the waste as it applies to certification; an executive summary of the Waste Management Quality Assurance Implementing Management Plan (QAIMP) for the HWHF and a list of the current and planned implementing procedures used in waste certification. This plan provides guidance from the HWHF to waste generators, waste handlers, and the Waste Certification Specialist to enable them to conduct their activities and carry out their responsibilities in a manner that complies with the requirements of WHC-WAC. Waste generators have the primary responsibility for the proper characterization of LLW. The Waste Certification Specialist verifies and certifies that LBL LLW is characterized, handled, and shipped in accordance with the requirements of WHC-WAC. Certification is the governing process in which LBL personnel conduct their waste generating and waste handling activities in such a manner that the Waste Certification Specialist can verify that the requirements of WHC-WAC are met.

Albert, R.

1992-06-30T23:59:59.000Z

324

Hazardous Waste Management (Michigan)  

Broader source: Energy.gov [DOE]

A person shall not generate, dispose, store, treat, or transport hazardous waste in this state without complying with the requirements of this article. The department, in the conduct of its duties...

325

Waste and Recycling  

ScienceCinema (OSTI)

Nuclear engineer Dr. Kathy McCarthy talks about nuclear energy, the challenge of nuclear waste and the research aimed at solutions. For more information about nuclear energy research, visit http://www.facebook.com/idahonationallaboratory.

McCarthy, Kathy

2013-05-28T23:59:59.000Z

326

Solid Waste Management (Kansas)  

Broader source: Energy.gov [DOE]

This act aims to establish and maintain a cooperative state and local program of planning and technical and financial assistance for comprehensive solid waste management. No person shall construct,...

327

UMC Construction Waste (4493)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

collect all Construction waste identified in 2006 and excess through plant sales, recycle through plant scrap metal recycle program, dispose in Y-12 on-site landfill, or ship to...

328

Citrus Waste Biomass Program  

SciTech Connect (OSTI)

Renewable Spirits is developing an innovative pilot plant bio-refinery to establish the commercial viability of ehtanol production utilizing a processing waste from citrus juice production. A novel process based on enzymatic hydrolysis of citrus processing waste and fermentation of resulting sugars to ethanol by yeasts was successfully developed in collaboration with a CRADA partner, USDA/ARS Citrus and Subtropical Products Laboratory. The process was also successfully scaled up from laboratory scale to 10,000 gal fermentor level.

Karel Grohman; Scott Stevenson

2007-01-30T23:59:59.000Z

329

Methyl bromide emissions to the atmosphere from temperate woodland ecosystems  

E-Print Network [OSTI]

The environmental importance of methyl bromide (CH3Br) arises from its contribution to stratospheric ozone loss processes and, as a consequence, its emissions from anthropogenic sources are subject to the Montreal Protocol. A better understanding...

Drewer, Julia; Heal, Kate V; Smith, Keith A; Heal, Mathew R

2008-01-01T23:59:59.000Z

330

The Genetics of de novo Methylation in Arabidopsis thaliana  

E-Print Network [OSTI]

domains akin to UHRF1 and the VIM proteins. These proteinsthe VARIANT IN METHYLATION (VIM) family. In higher orderUHRF1 in mammal or the VIM proteins in plants. UHRF1/VIM

Greenberg, Maxim Van Cleef

2012-01-01T23:59:59.000Z

331

Regulation of yeast development by mRNA methylation  

E-Print Network [OSTI]

The internal methylation of mRNA post-transcriptionally is an essential component of the mRNA editing machinery in virtually every eukaryotic system. Despite this ubiquity, little is known about the relevance, consequences ...

Agarwala, Sudeep D

2012-01-01T23:59:59.000Z

332

akap12 promoter methylation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(MEK) with hydrogen peroxide (H2O2), is widely used in industry as a radicalThermal Hazard Analysis of Methyl Ethyl Ketone Peroxide Ron-Hsin Chang, Chi-Min Shu and Po-Yin Yeh...

333

Control of mercury methylation in wetlands through iron addition  

E-Print Network [OSTI]

Mason, R. P. ; Flegal, A. R. , Mercury speciation in the SanP. ; Flegal, A. R. , Decadal mercury trends in San FranciscoP. G. ; Nelson, D. C. , Mercury methylation from unexpected

Sedlak, David L; Ulrich, Patrick D

2009-01-01T23:59:59.000Z

334

Hanford Site annual dangerous waste report. Volume 1, Part 2, Generator dangerous waste report dangerous waste: Calendar Year 1993  

SciTech Connect (OSTI)

This report contains information on hazardous wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, weight, waste description, and waste designation.

Not Available

1993-12-31T23:59:59.000Z

335

Hanford Site annual dangerous waste report. Volume 1, Part 1, Generator dangerous waste report dangerous waste: Calendar Year 1993  

SciTech Connect (OSTI)

This report contains information on hazardous wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, weight, waste description, and waste designation.

Not Available

1993-12-31T23:59:59.000Z

336

Methyl arsenic adsorption and desorption behavior on iron oxides  

E-Print Network [OSTI]

METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 2004 Major Subject: Soil Science METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to Texas A&M University...

Lafferty, Brandon James

2005-08-29T23:59:59.000Z

337

The synthesis of some N-methylated aminoalkylphosphonic acids  

E-Print Network [OSTI]

(XLIII) were o heated with diethyl hydrogenphosphonate (XVI) at approximately 100 until the evolution of dimethylarnine (XXX) ceased. The 1-dimethyl- amino 1-alkenes (XLIV) reacted exothermically with diethyl hydro- genphosphonate (XVI) once... exothermically with methyl iodide at room temperature whereas the other eaters, which contained more bulky (R) substituents, did not. Secondly, the betaine obtained m the highest yield, N, N, N-trimethyl-N-(phosphono- methyl)ammonium hydroxide, mner salt...

Eikenberry, Jon Nathan

1966-01-01T23:59:59.000Z

338

Idaho Waste Vitrification Facilities Project Vitrified Waste Interim Storage Facility  

SciTech Connect (OSTI)

This feasibility study report presents a draft design of the Vitrified Waste Interim Storage Facility (VWISF), which is one of three subprojects of the Idaho Waste Vitrification Facilities (IWVF) project. The primary goal of the IWVF project is to design and construct a treatment process system that will vitrify the sodium-bearing waste (SBW) to a final waste form. The project will consist of three subprojects that include the Waste Collection Tanks Facility, the Waste Vitrification Facility (WVF), and the VWISF. The Waste Collection Tanks Facility will provide for waste collection, feed mixing, and surge storage for SBW and newly generated liquid waste from ongoing operations at the Idaho Nuclear Technology and Engineering Center. The WVF will contain the vitrification process that will mix the waste with glass-forming chemicals or frit and turn the waste into glass. The VWISF will provide a shielded storage facility for the glass until the waste can be disposed at either the Waste Isolation Pilot Plant as mixed transuranic waste or at the future national geological repository as high-level waste glass, pending the outcome of a Waste Incidental to Reprocessing determination, which is currently in progress. A secondary goal is to provide a facility that can be easily modified later to accommodate storage of the vitrified high-level waste calcine. The objective of this study was to determine the feasibility of the VWISF, which would be constructed in compliance with applicable federal, state, and local laws. This project supports the Department of Energys Environmental Management missions of safely storing and treating radioactive wastes as well as meeting Federal Facility Compliance commitments made to the State of Idaho.

Bonnema, Bruce Edward

2001-09-01T23:59:59.000Z

339

Solid Waste Management Program (South Dakota)  

Broader source: Energy.gov [DOE]

South Dakota's Solid Waste Management Program offers loans and grants for solid waste disposal, recycling, and waste tire projects. Funds are available for private or public projects, and...

340

Independent Oversight Review, Waste Treatment and Immobilization...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Waste Treatment and Immobilization Plant - December 2012 December 2012 Review of the Hanford Site Waste Treatment and Immobilization Plant Low Activity Waste Melter Process...

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

SECONDARY WASTE MANAGEMENT STRATEGY FOR EARLY LOW ACTIVITY WASTE TREATMENT  

SciTech Connect (OSTI)

This study evaluates parameters relevant to River Protection Project secondary waste streams generated during Early Low Activity Waste operations and recommends a strategy for secondary waste management that considers groundwater impact, cost, and programmatic risk. The recommended strategy for managing River Protection Project secondary waste is focused on improvements in the Effiuent Treatment Facility. Baseline plans to build a Solidification Treatment Unit adjacent to Effluent Treatment Facility should be enhanced to improve solid waste performance and mitigate corrosion of tanks and piping supporting the Effiuent Treatment Facility evaporator. This approach provides a life-cycle benefit to solid waste performance and reduction of groundwater contaminants.

CRAWFORD TW

2008-07-17T23:59:59.000Z

342

Waste Treatment Plant - 12508  

SciTech Connect (OSTI)

The Waste Treatment Plant (WTP) will immobilize millions of gallons of Hanford's tank waste into solid glass using a proven technology called vitrification. The vitrification process will turn the waste into a stable glass form that is safe for long-term storage. Our discussion of the WTP will include a description of the ongoing design and construction of this large, complex, first-of-a-kind project. The concept for the operation of the WTP is to separate high-level and low-activity waste fractions, and immobilize those fractions in glass using vitrification. The WTP includes four major nuclear facilities and various support facilities. Waste from the Tank Farms is first pumped to the Pretreatment Facility at the WTP through an underground pipe-in-pipe system. When construction is complete, the Pretreatment Facility will be 12 stories high, 540 feet long and 215 feet wide, making it the largest of the four major nuclear facilities that compose the WTP. The total size of this facility will be more than 490,000 square feet. More than 8.2 million craft hours are required to construct this facility. Currently, the Pretreatment Facility is 51 percent complete. At the Pretreatment Facility the waste is pumped to the interior waste feed receipt vessels. Each of these four vessels is 55-feet tall and has a 375,000 gallon capacity, which makes them the largest vessels inside the Pretreatment Facility. These vessels contain a series of internal pulse-jet mixers to keep incoming waste properly mixed. The vessels are inside the black-cell areas, completely enclosed behind thick steel-laced, high strength concrete walls. The black cells are designed to be maintenance free with no moving parts. Once hot operations commence the black-cell area will be inaccessible. Surrounded by black cells, is the 'hot cell canyon'. The hot cell contains all the moving and replaceable components to remove solids and extract liquids. In this area, there is ultrafiltration equipment, cesium-ion exchange columns, evaporator boilers and recirculation pumps, and various mechanical process pumps for transferring process fluids. During the first phase of pretreatment, the waste will be concentrated using an evaporation process. Solids will be filtered out, and the remaining soluble, highly radioactive isotopes will be removed using an ion-exchange process. The high-level solids will be sent to the High-Level Waste (HLW) Vitrification Facility, and the low activity liquids will be sent to the Low-Activity Waste (LAW) Vitrification Facility for further processing. The high-level waste will be transferred via underground pipes to the HLW Facility from the Pretreatment Facility. The waste first arrives at the wet cell, which rests inside a black-cell area. The pretreated waste is transferred through shielded pipes into a series of melter preparation and feed vessels before reaching the melters. Liquids from various facility processes also return to the wet cell for interim storage before recycling back to the Pretreatment Facility. (authors)

Harp, Benton; Olds, Erik [US DOE (United States)

2012-07-01T23:59:59.000Z

343

Mixed waste characterization reference document  

SciTech Connect (OSTI)

Waste characterization and monitoring are major activities in the management of waste from generation through storage and treatment to disposal. Adequate waste characterization is necessary to ensure safe storage, selection of appropriate and effective treatment, and adherence to disposal standards. For some wastes characterization objectives can be difficult and costly to achieve. The purpose of this document is to evaluate costs of characterizing one such waste type, mixed (hazardous and radioactive) waste. For the purpose of this document, waste characterization includes treatment system monitoring, where monitoring is a supplement or substitute for waste characterization. This document establishes a cost baseline for mixed waste characterization and treatment system monitoring requirements from which to evaluate alternatives. The cost baseline established as part of this work includes costs for a thermal treatment technology (i.e., a rotary kiln incinerator), a nonthermal treatment process (i.e., waste sorting, macronencapsulation, and catalytic wet oxidation), and no treatment (i.e., disposal of waste at the Waste Isolation Pilot Plant (WIPP)). The analysis of improvement over the baseline includes assessment of promising areas for technology development in front-end waste characterization, process equipment, off gas controls, and monitoring. Based on this assessment, an ideal characterization and monitoring configuration is described that minimizes costs and optimizes resources required for waste characterization.

NONE

1997-09-01T23:59:59.000Z

344

Hazardous Waste/Mixed Waste Treatment Building throughput study  

SciTech Connect (OSTI)

The hazardous waste/mixed waste HW/MW Treatment Building (TB) is the specified treatment location for solid hazardous waste/mixed waste at SRS. This report provides throughput information on the facility based on known and projected waste generation rates. The HW/MW TB will have an annual waste input for the first four years of approximately 38,000 ft{sup 3} and have an annual treated waste output of approximately 50,000 ft{sup 3}. After the first four years of operation it will have an annual waste input of approximately 16,000 ft{sup 3} and an annual waste output of approximately 18,000 ft. There are several waste streams that cannot be accurately predicted (e.g. environmental restoration, decommissioning, and decontamination). The equipment and process area sizing for the initial four years should allow excess processing capability for these poorly defined waste streams. A treatment process description and process flow of the waste is included to aid in understanding the computations of the throughput. A description of the treated wastes is also included.

England, J.L.; Kanzleiter, J.P.

1991-12-18T23:59:59.000Z

345

Waste segregation procedures and benefits  

SciTech Connect (OSTI)

Segregation is a critical first step in handling hazardous and radioactive materials to minimize the generation of regulated wastes. In addition, segregation can significantly reduce the complexity and the total cost of managing waste. Procedures at Sandia National Laboratories, Albuquerque require that wastes be segregated, first, by waste type (acids, solvents, low level radioactive, mixed, classified, etc.). Higher level segregation requirements, currently under development, are aimed at enhancing the possibilities for recovery, recycle and reapplication; reducing waste volumes; reducing waste disposal costs, and facilitating packaging storage, shipping and disposal. 2 tabs.

Fish, J.D.; Massey, C.D.; Ward, S.J.

1990-01-01T23:59:59.000Z

346

ZERO WASTE STANFORD WASTE REDUCTION, RECYCLING AND COMPOSTING GUIDELINES  

E-Print Network [OSTI]

ZERO WASTE STANFORD WASTE REDUCTION, RECYCLING AND COMPOSTING GUIDELINES PLASTICS, METALS & GLASS pleaseemptyandflatten COMPOSTABLES kitchenandyardwasteonly LANDFILL ONLY ifallelsefails All Plastic Containers Metal Material All Food Paper Plates & Napkins *including pizza & donut boxes Compostable & Biodegradable

Gerdes, J. Christian

347

RECYCLING AND GENERAL WASTE MANAGEMENT OPERATIONAL PROCEDURE  

E-Print Network [OSTI]

RECYCLING AND GENERAL WASTE MANAGEMENT OPERATIONAL PROCEDURE Swansea University Estates Services.6.1/1 Recycling & General Waste Management Department: Estates & Facilities Management Site: Swansea University recycling and waste management facilities in Swansea university To ensure that Waste Management Objectives

Harman, Neal.A.

348

FROM WASTE TO WORTH: THE ROLE OF WASTE DIVERSION IN  

E-Print Network [OSTI]

;Canadian Energy-From-Waste Coalition (CEFWC) 1 There is considerable merit to the ideas outlined commitment to foster a green and sustainable economy. The Canadian Energy-From-Waste Coalition (CEFWC sign that the system is failing. #12;Canadian Energy-From-Waste Coalition (CEFWC) 2 Like you, the CEFWC

Columbia University

349

Waste IncIneratIon and Waste PreventIon  

E-Print Network [OSTI]

disposing of waste, it also makes consider- able amounts of energy available in the form of electricity emissions annu- ally. About 50 percent of the energy contained in residual municipal waste comes from- sions from the fossil waste fraction and the fos- sil energy purchased from external sources

350

Waste Management & Research172 Waste Manage Res 2003: 21: 172177  

E-Print Network [OSTI]

. Keywords: Waste incineration, PVC (polyvinylchloride), energy recovery, material recycling, HCLWaste Management & Research172 Waste Manage Res 2003: 21: 172­177 Printed in UK ­ all rights reserved Copyright © ISWA 2003 Waste Management & Research ISSN 0734­242X In many market segments

Columbia University

351

Swedish nuclear waste efforts  

SciTech Connect (OSTI)

After the introduction of a law prohibiting the start-up of any new nuclear power plant until the utility had shown that the waste produced by the plant could be taken care of in an absolutely safe way, the Swedish nuclear utilities in December 1976 embarked on the Nuclear Fuel Safety Project, which in November 1977 presented a first report, Handling of Spent Nuclear Fuel and Final Storage of Vitrified Waste (KBS-I), and in November 1978 a second report, Handling and Final Storage of Unreprocessed Spent Nuclear Fuel (KBS II). These summary reports were supported by 120 technical reports prepared by 450 experts. The project engaged 70 private and governmental institutions at a total cost of US $15 million. The KBS-I and KBS-II reports are summarized in this document, as are also continued waste research efforts carried out by KBS, SKBF, PRAV, ASEA and other Swedish organizations. The KBS reports describe all steps (except reprocessing) in handling chain from removal from a reactor of spent fuel elements until their radioactive waste products are finally disposed of, in canisters, in an underground granite depository. The KBS concept relies on engineered multibarrier systems in combination with final storage in thoroughly investigated stable geologic formations. This report also briefly describes other activities carried out by the nuclear industry, namely, the construction of a central storage facility for spent fuel elements (to be in operation by 1985), a repository for reactor waste (to be in operation by 1988), and an intermediate storage facility for vitrified high-level waste (to be in operation by 1990). The R and D activities are updated to September 1981.

Rydberg, J.

1981-09-01T23:59:59.000Z

352

Skutterudite Thermoelectric Generator For Automotive Waste Heat...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Skutterudite TE modules were...

353

Waste Heat Recovery Opportunities for Thermoelectric Generators...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Waste Heat Recovery Opportunities for Thermoelectric Generators Waste Heat Recovery Opportunities for Thermoelectric Generators Thermoelectrics have unique advantages for...

354

Solid Waste Facilities Regulations (Massachusetts)  

Broader source: Energy.gov [DOE]

This chapter of the Massachusetts General Laws governs the operation of solid waste facilities. It seeks to encourage sustainable waste management practices and to mitigate adverse effects, such as...

355

Hazardous Waste Management (North Dakota)  

Broader source: Energy.gov [DOE]

The Department of Health is the designated agency to administer and coordinate a hazardous waste management program to provide for the reduction of hazardous waste generation, reuse, recovery, and...

356

Montana Hazardous Waste Act (Montana)  

Broader source: Energy.gov [DOE]

This Act addresses the safe and proper management of hazardous wastes and used oil, the permitting of hazardous waste facilities, and the siting of facilities. The Department of Environmental...

357

Waste Management Assistance Act (Iowa)  

Broader source: Energy.gov [DOE]

This section promotes the proper and safe storage, treatment, and disposal of solid, hazardous, and low-level radioactive wastes in Iowa, and calls on Iowans to assume responsibility for waste...

358

Solid Waste Management Program (Missouri)  

Broader source: Energy.gov [DOE]

The Solid Waste Management Program in the Department of Natural Resources regulates the management of solid waste in the state of Missouri. A permit is required prior to the construction or...

359

Hydrothermal Processing of Wet Wastes  

Broader source: Energy.gov [DOE]

Breakout Session 3AConversion Technologies III: Energy from Our WasteWill we Be Rich in Fuel or Knee Deep in Trash by 2025? Hydrothermal Processing of Wet Wastes James R. Oyler, President, Genifuel Corporation

360

Zero Waste, Renewable Energy & Environmental  

E-Print Network [OSTI]

· Dioxins & Furans · The `State of Waste' in the US · WTE Technologies · Thermal Recycling ­ Turnkey dangerous wastes in the form of gases and ash, often creating entirely new hazards, like dioxins and furans

Columbia University

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Waste Management | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Cleanup Waste Management Waste Management July 15, 2014 Energy Expos Students work in groups to create hands-on exhibits about the energy sources that power the nation, ways to...

362

High-Level Waste Requirements  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The guide provides the criteria for determining which DOE radioactive wastes are to be managed as high-level waste in accordance with DOE M 435.1-1.

1999-07-09T23:59:59.000Z

363

Low-Level Waste Requirements  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The guide provides criteria for determining which DOE radioactive wastes are to be managed as low-level waste in accordance with DOE M 435.1-1, Chapter IV.

1999-07-09T23:59:59.000Z

364

Delaware Solid Waste Authority (Delaware)  

Broader source: Energy.gov [DOE]

The Delaware Solid Waste Authority (DSWA) runs three landfills, all of which recover methane and generate electricity with a total capacity of 24 MWs. The DSWA Solid Waste Plan includes goals,...

365

Management of Solid Waste (Oklahoma)  

Broader source: Energy.gov [DOE]

The Solid Waste Management Division of the Department of Environmental Quality regulates solid waste disposal or any person who generates, collects, transports, processes, and/or disposes of solid...

366

Heat Recovery From Solid Waste  

E-Print Network [OSTI]

areas of evaluation, including the cost of fuel, cost of solid waste disposal, plant energy requirements, available technology, etc....

Underwood, O. W.

1981-01-01T23:59:59.000Z

367

HAZARDOUS WASTE LABEL DEPAUL UNIVERSITY  

E-Print Network [OSTI]

- Hazardous Ignitable Reactive Toxic Oxidizer Other ( explain ) Generator Building Dept. HAZARDOUS WASTE LABEL: Generator Building Dept. Please fill out the hazardous waste label on line and download labels on to a plainHAZARDOUS WASTE LABEL DEPAUL UNIVERSITY ENVIRONMENTAL HEALTH & SAFETY 5-4170 Corrosive Non

Schaefer, Marcus

368

RETHINKING WASTE, RECYCLING, AND HOUSEKEEPING  

E-Print Network [OSTI]

RETHINKING WASTE, RECYCLING, AND HOUSEKEEPING EFFICIENCY.EFFICIENCY. A l GA leaner Green #12 t R li Management Recycling Staff The Office of Waste Reduction & Recycling started in The Office of Waste Reduction & Recycling started in 1990, we have 14 full time staff positions. ·We collect over 40

Howitt, Ivan

369

Nested methylation-specific polymerase chain reaction cancer detection method  

DOE Patents [OSTI]

A molecular marker-based method for monitoring and detecting cancer in humans. Aberrant methylation of gene promoters is a marker for cancer risk in humans. A two-stage, or "nested" polymerase chain reaction method is disclosed for detecting methylated DNA sequences at sufficiently high levels of sensitivity to permit cancer screening in biological fluid samples, such as sputum, obtained non-invasively. The method is for detecting the aberrant methylation of the p16 gene, O 6-methylguanine-DNA methyltransferase gene, Death-associated protein kinase gene, RAS-associated family 1 gene, or other gene promoters. The method offers a potentially powerful approach to population-based screening for the detection of lung and other cancers.

Belinsky, Steven A. (Albuquerque, NM); Palmisano, William A. (Edgewood, NM)

2007-05-08T23:59:59.000Z

370

Radioactive Waste Management  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The objective of this Order is to ensure that all Department of Energy (DOE) radioactive waste is managed in a manner that is protective of worker and public health and safety and the environment. Cancels DOE O 5820.2A

1999-07-09T23:59:59.000Z

371

Waste Description Pounds Reduced,  

E-Print Network [OSTI]

for toxic solvents, chemical storage, and disposal associated with the cleaning of vacuum parts. Aerosol can liters of solvent and saves approximately 50 labor hours. Propane cylinder de- valver Recycling 75 Hazardous waste $7,500 $0 $7,500 The Collider Accelerator Division bought a propane cylinder de

372

Radioactive Waste Management  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The objective of this Order is to ensure that all Department of Energy (DOE) radioactive waste is managed in a manner that is protective of worker and public health and safety and the environment. Cancels DOE O 5820.2A. Chg 1 dated 8-28-01. Certified 1-9-07.

1999-07-09T23:59:59.000Z

373

WIPP TRANSURANIC WASTE How has the WIPP TRU Waste Inventory Changed  

E-Print Network [OSTI]

of tank waste from the Hanford site that is currently managed as high-level waste. None of this waste has that these Hanford tank wastes will be treated and will eventually be able to meet the WIPP waste acceptance criteria on the Hanford Tank Waste and K-Basin Sludges that were included in the waste inventory for recertifica- tion

374

Hanford Tank Waste - Near Source Treatment of Low Activity Waste  

SciTech Connect (OSTI)

Abstract only. Treatment and disposition of Hanford Site waste as currently planned consists of 100+ waste retrievals, waste delivery through up to 8+ miles of dedicated, in-ground piping, centralized mixing and blending operations- all leading to pre-treatment combination and separation processes followed by vitrification at the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The sequential nature of Tank Farm and WTP operations requires nominally 15-20 years of continuous operations before all waste can be retrieved from many Single Shell Tanks (SSTs). Also, the infrastructure necessary to mobilize and deliver the waste requires significant investment beyond that required for the WTP. Treating waste as closely as possible to individual tanks or groups- as allowed by the waste characteristics- is being investigated to determine the potential to 1) defer, reduce, and/or eliminate infrastructure requirements, and 2) significantly mitigate project risk by reducing the potential and impact of single point failures. The inventory of Hanford waste slated for processing and disposition as LAW is currently managed as high-level waste (HLW), i.e., the separation of fission products and other radionuclides has not commenced. A significant inventory of this waste (over 20M gallons) is in the form of precipitated saltcake maintained in single shell tanks, many of which are identified as potential leaking tanks. Retrieval and transport (as a liquid) must be staged within the waste feed delivery capability established by site infrastructure and WTP. Near Source treatment, if employed, would provide for the separation and stabilization processing necessary for waste located in remote farms (wherein most of the leaking tanks reside) significantly earlier than currently projected. Near Source treatment is intended to address the currently accepted site risk and also provides means to mitigate future issues likely to be faced over the coming decades. This paper describes the potential near source treatment and waste disposition options as well as the impact these options could have on reducing infrastructure requirements, project cost and mission schedule.

Ramsey, William Gene

2013-08-15T23:59:59.000Z

375

Waste acceptance and waste loading for vitrified Oak Ridge tank waste  

SciTech Connect (OSTI)

The Office of Science and Technology of the DOE has funded a joint project between the Oak Ridge National Laboratory (ORNL) and the Savannah River Technology Center (SRTC) to evaluate vitrification and grouting for the immobilization of sludge from ORNL tank farms. The radioactive waste is from the Gunite and Associated Tanks (GAAT), the Melton Valley Storage Tanks (MVST), the Bethel Valley Evaporator Service Tanks (BVEST), and the Old Hydrofractgure Tanks (OHF). Glass formulation development for sludge from these tanks is discussed in an accompanying article for this conference (Andrews and Workman). The sludges contain transuranic radionuclides at levels which will make the glass waste form (at reasonable waste loadings) TRU. Therefore, one of the objectives for this project was to ensure that the vitrified waste form could be disposed of at the Waste Isolation Pilot Plant (WIPP). In order to accomplish this, the waste form must meet the WIPP Waste Acceptance Criteria (WAC). An alternate pathway is to send the glass waste forms for disposal at the Nevada Test Site (NTS). A sludge waste loading in the feed of 6 wt percent will lead to a waste form which is non-TRU and could potentially be disposed of at NTS. The waste forms would then have to meet the requirements of the NTS WAC. This paper presents SRTC`s efforts at demonstrating that the glass waste form produced as a result of vitrification of ORNL sludge will meet all the criteria of the WIPP WAC or NTS WAC.

Harbour, J.R.; Andrews, M.K.

1997-06-06T23:59:59.000Z

376

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J.

2013-01-29T23:59:59.000Z

377

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J

2013-11-26T23:59:59.000Z

378

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J.

2012-09-11T23:59:59.000Z

379

Effects of hydration water on protein methyl group dynamics insolution  

SciTech Connect (OSTI)

Elastic and quasielastic neutron scattering experiments have been used to investigate the dynamics of methyl groups in a protein-model hydrophobic peptide in solution. The results suggest that, when the hydrophobic side chains are hydrated by a single hydration water layer, the only allowed motions are confined and attributed to librational and rotational movement associated with the methyl groups. They provide unique experimental evidence that the structural and dynamical properties of the interfacial water strongly influence the side-chain dynamics and the activation of diffusive motion.

Russo D; Hura GL; Copley JRD

2007-01-01T23:59:59.000Z

380

Waste minimization handbook, Volume 1  

SciTech Connect (OSTI)

This technical guide presents various methods used by industry to minimize low-level radioactive waste (LLW) generated during decommissioning and decontamination (D and D) activities. Such activities generate significant amounts of LLW during their operations. Waste minimization refers to any measure, procedure, or technique that reduces the amount of waste generated during a specific operation or project. Preventive waste minimization techniques implemented when a project is initiated can significantly reduce waste. Techniques implemented during decontamination activities reduce the cost of decommissioning. The application of waste minimization techniques is not limited to D and D activities; it is also useful during any phase of a facility`s life cycle. This compendium will be supplemented with a second volume of abstracts of hundreds of papers related to minimizing low-level nuclear waste. This second volume is expected to be released in late 1996.

Boing, L.E.; Coffey, M.J.

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Quality Services: Solid Wastes, Part 360: Solid Waste Management Facilities (New York)  

Broader source: Energy.gov [DOE]

These regulations apply to all solid wastes with the exception of hazardous or radioactive waste. Proposed solid waste processing facilities are required to obtain permits prior to construction,...

382

Waste Isolation Pilot Plant Transuranic Waste Baseline inventory report. Volume 3. Revision 1  

SciTech Connect (OSTI)

This report consists of information related to the waste forms at the WIPP facility from the waste originators. Data for retrievably stored, projected and total wastes are given.

NONE

1995-02-01T23:59:59.000Z

383

WASTE/BY-PRODUCT HYDROGEN DOE/DOD Workshop  

E-Print Network [OSTI]

; 6 Waste/Byproduct HydrogenWaste/By product Hydrogen Waste H2 sources include: Waste biomass: biogas Waste/Byproduct Hydrogen Waste/By product Hydrogen Fuel FlexibilityFuel Flexibility Biogas: generated

384

Treatment of halogen-containing waste and other waste materials  

DOE Patents [OSTI]

A process for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes.

Forsberg, Charles W. (Oak Ridge, TN); Beahm, Edward C. (Oak Ridge, TN); Parker, George W. (Concord, TN)

1997-01-01T23:59:59.000Z

385

Treatment of halogen-containing waste and other waste materials  

DOE Patents [OSTI]

A process is described for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes. 3 figs.

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

1997-03-18T23:59:59.000Z

386

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

387

Freezing of Dynamics of a Methyl Group in a Protein Hydrophobic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freezing of Dynamics of a Methyl Group in a Protein Hydrophobic Core at Cryogenic Temperatures by Deuteron NMR Spectroscopy. Freezing of Dynamics of a Methyl Group in a Protein...

388

Environmental and age effects on methylation changes in human brain and blood cells  

E-Print Network [OSTI]

Previous studies have shown that DNA methylation may 1 e associated with disease, aging, the rate of aging and genetics. In this thesis, age is accurately predicted from DNA methylation in brain and blood tissues using two ...

Giguzinsky, Orit

2014-01-01T23:59:59.000Z

389

Experimental and Analytical Studies on Pyroelectric Waste Heat Energy Conversion  

E-Print Network [OSTI]

Waste heat Pyroelectric energy3 Pyroelectric Waste Heat Energy Harvesting Using Heat4 Pyroelectric Waste Heat Energy Harvesting Using Relaxor

Lee, Felix

2012-01-01T23:59:59.000Z

390

Ultrafast photochemistry of methyl hydroperoxide on ice particles  

E-Print Network [OSTI]

Ultrafast photochemistry of methyl hydroperoxide on ice particles M. A. Kambouresa , S. AOOH, on water clusters produces a surprisingly wide range of products on a subpicosecond time scale | photodissociation Photoinduced processes at surfaces of water or ice are of interest in atmospheric chemistry

Nizkorodov, Sergey

391

Tritium waste package  

DOE Patents [OSTI]

A containment and waste package system for processing and shipping tritium xide waste received from a process gas includes an outer drum and an inner drum containing a disposable molecular sieve bed (DMSB) seated within outer drum. The DMSB includes an inlet diffuser assembly, an outlet diffuser assembly, and a hydrogen catalytic recombiner. The DMSB absorbs tritium oxide from the process gas and converts it to a solid form so that the tritium is contained during shipment to a disposal site. The DMSB is filled with type 4A molecular sieve pellets capable of adsorbing up to 1000 curies of tritium. The recombiner contains a sufficient amount of catalyst to cause any hydrogen add oxygen present in the process gas to recombine to form water vapor, which is then adsorbed onto the DMSB.

Rossmassler, Rich (Cranbury, NJ); Ciebiera, Lloyd (Titusville, NJ); Tulipano, Francis J. (Teaneck, NJ); Vinson, Sylvester (Ewing, NJ); Walters, R. Thomas (Lawrenceville, NJ)

1995-01-01T23:59:59.000Z

392

Hydraulic waste energy recovery  

SciTech Connect (OSTI)

Water distribution systems are typically a municipality's largest consumer of energy and greatest expense. The water distribution network has varying pressure requirements due to the age of the pipeline and topographical differences. Certain circumstances require installation of pressure reducing devices in the pipeline to lower the water pressure in the system. The consequence of this action is that the hydraulic energy supplied by the high lift or booster pumps is wasted in the process of reducing the pressure. A possible solution to capture the waste hydraulic energy is to install an in-line electricity generating turbine. Energy recovery using in-line turbine systems is an emerging technology. Due to the lack of technical and other relevant information on in-line turbine system installations, questions of constructability and legal issues over the power service contract have yet to be answered. This study seeks to resolve these questions and document the findings so that other communities may utilize this information. 10 figs.

Lederer, C.C.; Thomas, A.H.; McGuire, J.L. (Detroit Buildings and Safety Engineering Dept., MI (USA))

1990-12-01T23:59:59.000Z

393

Tritium waste package  

DOE Patents [OSTI]

A containment and waste package system for processing and shipping tritium oxide waste received from a process gas includes an outer drum and an inner drum containing a disposable molecular sieve bed (DMSB) seated within the outer drum. The DMSB includes an inlet diffuser assembly, an outlet diffuser assembly, and a hydrogen catalytic recombiner. The DMSB absorbs tritium oxide from the process gas and converts it to a solid form so that the tritium is contained during shipment to a disposal site. The DMSB is filled with type 4A molecular sieve pellets capable of adsorbing up to 1000 curies of tritium. The recombiner contains a sufficient amount of catalyst to cause any hydrogen and oxygen present in the process gas to recombine to form water vapor, which is then adsorbed onto the DMSB. 1 fig.

Rossmassler, R.; Ciebiera, L.; Tulipano, F.J.; Vinson, S.; Walters, R.T.

1995-11-07T23:59:59.000Z

394

Nuclear waste management. Semiannual progress report, October 1983-March 1984  

SciTech Connect (OSTI)

Progress in the following studies on radioactive waste management is reported: defense waste technology; Nuclear Waste Materials Characterization Center; waste isolation; and supporting studies. 58 figures, 22 tables.

McElroy, J.L.; Powell, J.A.

1984-06-01T23:59:59.000Z

395

Medical and Biohazardous Waste Generator's Guide (Revision 2)  

E-Print Network [OSTI]

Waste Supplies 8. Solid Medical Waste Disposal ProceduresMedical/Biohazardous Waste Pickup Containers Solid Medical/Security Notice 8. Solid Medical Waste Disposal Procedures

Waste Management Group

2006-01-01T23:59:59.000Z

396

Waste Management in Dsseldorf Combination of separate collection,  

E-Print Network [OSTI]

Waste Management in Düsseldorf Combination of separate collection, recycling and waste-to-energy Biowaste Garden waste Light packaging Paper Glass Wood from bulky waste Bulky waste Rest / mixed waste Bio- Garden- Paper Glass Light Metals Wood Bulky Rest waste waste Card- Pack. waste board Saved CO2

Columbia University

397

Method for processing aqueous wastes  

DOE Patents [OSTI]

A method is presented for treating waste water such as that from an industrial processing facility comprising the separation of the waste water into a dilute waste stream and a concentrated waste stream. The concentrated waste stream is treated chemically to enhance precipitation and then allowed to separate into a sludge and a supernate. The supernate is skimmed or filtered from the sludge and blended with the dilute waste stream to form a second dilute waste stream. The sludge remaining is mixed with cementitious material, rinsed to dissolve soluble components, then pressed to remove excess water and dissolved solids before being allowed to cure. The dilute waste stream is also chemically treated to decompose carbonate complexes and metal ions and then mixed with cationic polymer to cause the precipitated solids to flocculate. Filtration of the flocculant removes sufficient solids to allow the waste water to be discharged to the surface of a stream. The filtered material is added to the sludge of the concentrated waste stream. The method is also applicable to the treatment and removal of soluble uranium from aqueous streams, such that the treated stream may be used as a potable water supply. 4 figures.

Pickett, J.B.; Martin, H.L.; Langton, C.A.; Harley, W.W.

1993-12-28T23:59:59.000Z

398

Method for processing aqueous wastes  

DOE Patents [OSTI]

A method for treating waste water such as that from an industrial processing facility comprising the separation of the waste water into a dilute waste stream and a concentrated waste stream. The concentrated waste stream is treated chemically to enhance precipitation and then allowed to separate into a sludge and a supernate. The supernate is skimmed or filtered from the sludge and blended with the dilute waste stream to form a second dilute waste stream. The sludge remaining is mixed with cementitious material, rinsed to dissolve soluble components, then pressed to remove excess water and dissolved solids before being allowed to cure. The dilute waste stream is also chemically treated to decompose carbonate complexes and metal ions and then mixed with cationic polymer to cause the precipitated solids to flocculate. Filtration of the flocculant removes sufficient solids to allow the waste water to be discharged to the surface of a stream. The filtered material is added to the sludge of the concentrated waste stream. The method is also applicable to the treatment and removal of soluble uranium from aqueous streams, such that the treated stream may be used as a potable water supply.

Pickett, John B. (3922 Wood Valley Dr., Aiken, SC 29803); Martin, Hollis L. (Rt. 1, Box 188KB, McCormick, SC 29835); Langton, Christine A. (455 Sumter St. SE., Aiken, SC 29801); Harley, Willie W. (110 Fairchild St., Batesburg, SC 29006)

1993-01-01T23:59:59.000Z

399

Naval Waste Package Design Report  

SciTech Connect (OSTI)

A design methodology for the waste packages and ancillary components, viz., the emplacement pallets and drip shields, has been developed to provide designs that satisfy the safety and operational requirements of the Yucca Mountain Project. This methodology is described in the ''Waste Package Design Methodology Report'' Mecham 2004 [DIRS 166168]. To demonstrate the practicability of this design methodology, four waste package design configurations have been selected to illustrate the application of the methodology. These four design configurations are the 21-pressurized water reactor (PWR) Absorber Plate waste package, the 44-boiling water reactor (BWR) waste package, the 5-defense high-level waste (DHLW)/United States (U.S.) Department of Energy (DOE) spent nuclear fuel (SNF) Co-disposal Short waste package, and the Naval Canistered SNF Long waste package. Also included in this demonstration is the emplacement pallet and continuous drip shield. The purpose of this report is to document how that design methodology has been applied to the waste package design configurations intended to accommodate naval canistered SNF. This demonstrates that the design methodology can be applied successfully to this waste package design configuration and support the License Application for construction of the repository.

M.M. Lewis

2004-03-15T23:59:59.000Z

400

Phase 1 Methyl Iodide Deep-Bed Adsorption Tests  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products (FPs) and activation products including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Research, demonstrations, and some reprocessing plant experience have indicated that diatomic iodine can be captured with efficiencies high enough to meet regulatory requirements. Research on the capture of organic iodides has also been performed, but to a lesser extent [Jubin 2012b]. Several questions remain open regarding the capture of iodine bound in organic compounds. Deep-bed methyl iodide adsorption testing has progressed according to a multi-laboratory methyl iodide adsorption test plan. This report summarizes the first phase of methyl iodide adsorption work performed according to this test plan using the deep-bed iodine adsorption test system at the Idaho National Laboratory (INL), performed during Fiscal Year (FY) 2013 and early FY-2014. Testing has been performed to address questions posed in the test plan, and followed the testing outline in the test plan. Tests established detection limits, developed procedures for sample analysis with minimal analytical interferences, and confirmed earlier results that show that the methyl iodide reacts when in contact with the AgZ sorbent, and not significantly in the gas flow upstream of the sorbent. The reaction(s) enable separation of the iodine from the organic moiety, so that the iodine can chemisorb onto the sorbent. The organic moiety can form other compounds, some of which are organic compounds that are detected and can be tentatively identified using GC-FID and GCMS. Test results also show that other gas constituents (NOx and/or H2O) can affect the methyl iodide reactions. With NOx and H2O present in the gas stream, the majority of uncaptured iodine exiting iodine-laden sorbent beds is in the form of I2 or HI, species that are soluble in NaOH scrubbing solution for iodine analysis. But when NOx and H2O are not present, then the majority of the uncaptured iodine exiting iodine-laden sorbent is in the form of methyl iodide. Methyl iodide adsorption efficiencies have been high enough so that initial DFs exceed 1,000 to 10,000. The methyl iodide mass transfer zone depths are estimated at 4-8 inches, possibly deeper than mass transfer zone depths estimated for I2 adsorption on AgZ. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption under various conditions specified in the methyl iodide test plan, and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

Nick Soelberg; Tony Watson

2014-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Radioactive waste processing apparatus  

DOE Patents [OSTI]

Apparatus for use in processing radioactive waste materials for shipment and storage in solid form in a container is disclosed. The container includes a top, and an opening in the top which is smaller than the outer circumference of the container. The apparatus includes an enclosure into which the container is placed, solution feed apparatus for adding a solution containing radioactive waste materials into the container through the container opening, and at least one rotatable blade for blending the solution with a fixing agent such as cement or the like as the solution is added into the container. The blade is constructed so that it can pass through the opening in the top of the container. The rotational axis of the blade is displaced from the center of the blade so that after the blade passes through the opening, the blade and container can be adjusted so that one edge of the blade is adjacent the cylindrical wall of the container, to insure thorough mixing. When the blade is inside the container, a substantially sealed chamber is formed to contain vapors created by the chemical action of the waste solution and fixant, and vapors emanating through the opening in the container.

Nelson, Robert E. (Lombard, IL); Ziegler, Anton A. (Darien, IL); Serino, David F. (Maplewood, MN); Basnar, Paul J. (Western Springs, IL)

1987-01-01T23:59:59.000Z

402

RSSC RADIOACTIVE WASTE DISPOSAL 08/2011 7-1 RADIOACTIVE WASTE DISPOSAL  

E-Print Network [OSTI]

RSSC RADIOACTIVE WASTE DISPOSAL 08/2011 7-1 CHAPTER 7 RADIOACTIVE WASTE DISPOSAL PAGE I. Radioactive Waste Disposal ............................................................................................ 7-2 II. Radiation Control Technique #2 Instructions for Preparation of Radioactive Waste

Slatton, Clint

403

Tank Waste and Waste Processing | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

breakthrough immobilization technologies. Currently projects are focusing on: In-tank sludge washing at Hanford Enhanced waste processing at Idaho, Hanford, and Savannah River...

404

WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,  

E-Print Network [OSTI]

/spills and subsequent clean up costs ($20,000) Sewage Sludge Volume Reduction 234,000 Radioactive Waste $910,000 $193,400 $716,600 60,000 gallons of radioactive STP liquid waste could have been disposed of through,000) Digital Imaging System Substitution 282 Hazardous Waste / Radioactive Waste / Industrial Waste $25,000 $25

405

AUSTRIA SHOWCASE WASTE-to-ENERGY  

E-Print Network [OSTI]

1 AUSTRIA SHOWCASE WASTE-to-ENERGY in AUSTRIA AECC Aberdeen Exhibition & Conference Center management in EU countries · Separated collection: Recycling and Waste-to-Energy · Development of emission standards for waste incineration · Examples for Waste-to-Energy projects in Austria · Waste-to-Energy

406

ASU Roadmap to Zero Waste Contact Information  

E-Print Network [OSTI]

zero solid waste across our campus locations by 2015. Over the past decade, the university has made Waste Management relationship and the zero solid waste plan, we are taking our operational sustainability efforts to the next level. ASU defines zero solid waste as a 90-percent reduction in waste to area

Zhang, Junshan

407

Waste Toolkit A-Z Light bulbs  

E-Print Network [OSTI]

Waste Toolkit A-Z Light bulbs Can I recycle light bulbs? It depends what type of bulbs you have of in the normal University waste bins (landfill waste). Energy saving bulbs and fluorescent tubes are classified light bulbs? Standard filament bulbs Put in the waste bin (landfill waste) as these are not classified

Melham, Tom

408

Vitrification of high sulfate wastes  

SciTech Connect (OSTI)

The US Department of Energy (DOE) through the Mixed Waste Integrated Program (MWIP) is investigating the application of vitrification technology to mixed wastes within the DOE system This work involves identifying waste streams, laboratory testing to identify glass formulations and characterize the vitrified product, and demonstration testing with the actual waste in a pilot-scale system. Part of this program is investigating process limits for various waste components, specifically those components that typically create problems for the application of vitrification, such as sulfate, chloride, and phosphate. This work describes results from vitrification testing for a high-sulfate waste, the 183-H Solar Evaporation Basin waste at Hanford. A low melting phosphate glass formulation has been developed for a waste stream high in sodium and sulfate. At melt temperatures in the range of 1,000 C to 1,200 C, sulfate in the waste is decomposed to gaseous oxides and driven off during melting, while the remainder of the oxides stay in the melt. Decomposition of the sulfates eliminates the processing problems typically encountered in vitrification of sulfate-containing wastes, resulting in separation of the sulfate from the remainder of the waste and allowing the sulfate to be collected in the off-gas system and treated as a secondary waste stream. Both the vitreous product and intentionally devitrified samples are durable when compared to reference glasses by TCLP and DI water leach tests. Simple, short tests to evaluate the compatibility of the glasses with potential melter materials found minimal corrosion with most materials.

Merrill, R.A.; Whittington, K.F.; Peters, R.D.

1994-09-01T23:59:59.000Z

409

Focus Sheet | Hazardous Waste Checklist How to be ready for state hazardous waste  

E-Print Network [OSTI]

-hazardous solid chemicals may go in the trash. Have you disposed of "waste-like", legacy and unknown c Manage anyFocus Sheet | Hazardous Waste Checklist How to be ready for state hazardous waste inspectors. See a hazardous waste inspection. ons, rrosive. n hemicals? ical waste. Waste-like chemicals have als Are you

Wilcock, William

410

Waste Isolation Pilot Plant Transuranic Waste Baseline inventory report. Volume 2. Revision 1  

SciTech Connect (OSTI)

This document is the Baseline Inventory Report for the transuranic (alpha-bearing) wastes stored at the Waste Isolation Pilot Plant (WIPP) in New Mexico. Waste stream profiles including origin, applicable EPA codes, typical isotopic composition, typical waste densities, and typical rates of waste generation for each facility are presented for wastes stored at the WIPP.

NONE

1995-02-01T23:59:59.000Z

411

Hazardous Waste Facilities Siting (Connecticut)  

Broader source: Energy.gov [DOE]

These regulations describe the siting and permitting process for hazardous waste facilities and reference rules for construction, operation, closure, and post-closure of these facilities.

412

Hazardous Waste Transporter Permits (Connecticut)  

Broader source: Energy.gov [DOE]

Transportation of hazardous wastes into or through the State of Connecticut requires a permit. Some exceptions apply. The regulations provide information about obtaining permits and other permit...

413

Reporting Fraud, Waste, and Abuse  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

This Notice reminds all DOE employees of their duty to report allegations of fraud, waste, and abuse to the Office of Inspector General. No cancellation.

2004-09-15T23:59:59.000Z

414

Process for preparing liquid wastes  

DOE Patents [OSTI]

A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

1997-01-01T23:59:59.000Z

415

Solid Waste Management Act (Pennsylvania)  

Broader source: Energy.gov [DOE]

This Act provides for the planning and regulation of solid waste storage, collection, transportation, processing, treatment, and disposal. It requires that municipalities submit plans for municipal...

416

Nuclear waste incineration technology status  

SciTech Connect (OSTI)

The incinerators developed and/or used for radioactive waste combustion are discussed and suggestions are made for uses of incineration in radioactive waste management programs and for incinerators best suited for specific applications. Information on the amounts and types of radioactive wastes are included to indicate the scope of combustible wastes being generated and in existence. An analysis of recently developed radwaste incinerators is given to help those interested in choosing incinerators for specific applications. Operating information on US and foreign incinerators is also included to provide additional background information. Development needs are identified for extending incinerator applications and for establishing commercial acceptance.

Ziegler, D.L.; Lehmkuhl, G.D.; Meile, L.J.

1981-07-15T23:59:59.000Z

417

Treatment of mercury containing waste  

DOE Patents [OSTI]

A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

Kalb, Paul D. (Wading River, NY); Melamed, Dan (Gaithersburg, MD); Patel, Bhavesh R (Elmhurst, NY); Fuhrmann, Mark (Babylon, NY)

2002-01-01T23:59:59.000Z

418

Progress Update: TRU Waste Shipping  

SciTech Connect (OSTI)

A progress update at the Savannah River Site. A continued effort on shipping TRU waste to WIPP in Carlsbad, New Mexico.

Cody, Tom

2010-01-01T23:59:59.000Z

419

Chernobyls waste site  

SciTech Connect (OSTI)

An analysis of the prospects for using the Chernobyl exclusion zone for development of a spent fuel store, waste disposal site and other nuclear facilities.

Schmieman, Eric A.; Paskevych, Sergiy; Sizov, Andrey; Batiy, Valeriy

2007-02-15T23:59:59.000Z

420

Progress Update: TRU Waste Shipping  

ScienceCinema (OSTI)

A progress update at the Savannah River Site. A continued effort on shipping TRU waste to WIPP in Carlsbad, New Mexico.

Cody, Tom

2012-06-14T23:59:59.000Z

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Waste gas combustion in a Hanford radioactive waste tank  

SciTech Connect (OSTI)

It has been observed that a high-level radioactive waste tank generates quantities of hydrogen, ammonia, nitrous oxide, and nitrogen that are potentially well within flammability limits. These gases are produced from chemical and nuclear decay reactions in a slurry of radioactive waste materials. Significant amounts of combustible and reactant gases accumulate in the waste over a 110- to 120-d period. The slurry becomes Taylor unstable owing to the buoyancy of the gases trapped in a matrix of sodium nitrate and nitrite salts. As the contents of the tank roll over, the generated waste gases rupture through the waste material surface, allowing the gases to be transported and mixed with air in the cover-gas space in the dome of the tank. An ignition source is postulated in the dome space where the waste gases combust in the presence of air resulting in pressure and temperature loadings on the double-walled waste tank. This analysis is conducted with hydrogen mixing studies HMS, a three-dimensional, time-dependent fluid dynamics code coupled with finite-rate chemical kinetics. The waste tank has a ventilation system designed to maintain a slight negative gage pressure during normal operation. We modeled the ventilation system with the transient reactor analysis code (TRAC), and we coupled these two best-estimate accident analysis computer codes to model the ventilation system response to pressures and temperatures generated by the hydrogen and ammonia combustion.

Travis, J.R.; Fujita, R.K.; Spore, J.W.

1994-07-01T23:59:59.000Z

422

Waste acceptance criteria for the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria (WAC), DOE/WIPP-069, was initially developed by a U.S. Department of Energy (DOE) Steering Committee to provide performance requirements to ensure public health and safety as well as the safe handling of transuranic (TRU) waste at the WIPP. This revision updates the criteria and requirements of previous revisions and deletes those which were applicable only to the test phase. The criteria and requirements in this document must be met by participating DOE TRU Waste Generator/Storage Sites (Sites) prior to shipping contact-handled (CH) and remote-handled (RH) TRU waste forms to the WIPP. The WIPP Project will comply with applicable federal and state regulations and requirements, including those in Titles 10, 40, and 49 of the Code of Federal Regulations (CFR). The WAC, DOE/WIPP-069, serves as the primary directive for assuring the safe handling, transportation, and disposal of TRU wastes in the WIPP and for the certification of these wastes. The WAC identifies strict requirements that must be met by participating Sites before these TRU wastes may be shipped for disposal in the WIPP facility. These criteria and requirements will be reviewed and revised as appropriate, based on new technical or regulatory requirements. The WAC is a controlled document. Revised/changed pages will be supplied to all holders of controlled copies.

NONE

1996-04-01T23:59:59.000Z

423

Biotechnology for environmental control and waste treatment  

SciTech Connect (OSTI)

A slide show is reproduced here to review the technology of anaerobic digestion as a process for cleaning waste waters from municipal and industry wastes. Radioactive wastes are addressed also. (PSB)

Donaldson, T.L.; Harris, M.T.; Lee, D.D.; Walker, J.F.; Strandberg, G.W.

1985-01-01T23:59:59.000Z

424

Hazardous Waste Management Standards and Regulations (Kansas)  

Broader source: Energy.gov [DOE]

This act states the standards and regulations for the management of hazardous waste. No person shall construct, modify or operate a hazardous waste facility or otherwise dispose of hazardous waste...

425

Hazardous Waste Facility Siting Program (Maryland)  

Broader source: Energy.gov [DOE]

The Hazardous Waste Facilities Siting Board is responsible for overseeing the siting of hazardous waste facilities in Maryland, and will treat hazardous waste facilities separately from low-level...

426

Eugene Solid Waste Management Market Analysis  

E-Print Network [OSTI]

Eugene Solid Waste Management Market Analysis Prepared By: Mitchell Johnson Alex Sonnichsen #12;Eugene Solid Waste Management Market Analysis May 2012 Page 1 Summary This study examines the economic impact of the solid waste management system

Oregon, University of

427

Printed on recycled paper. 2013 Cornell Waste  

E-Print Network [OSTI]

management by focusing University resources and capabilities on this pressing economic, environmental of waste generation and composition, waste reduction, risk management, environmental equity and publicPrinted on recycled paper. 2013 Cornell Waste Management Institute CWMI is a program

Chen, Tsuhan

428

Salt Waste Processing Initiatives  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September2-SCORECARD-01-24-13 Page 1 of 1 DepartmentSalt Waste1

429

Waste Isolation Pilot Plant  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption byAbout Printable VersionProtective Actions Actions to30/15Waste

430

Hanford Dangerous Waste Permit  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment and

431

DC Hazardous Waste Management (District of Columbia)  

Broader source: Energy.gov [DOE]

This regulation regulates the generation, storage, transportation, treatment, and disposal of hazardous waste, and wherever feasible, reduces or eliminates waste at the source. It is the policy of...

432

Missouri Hazardous Waste Management Law (Missouri)  

Broader source: Energy.gov [DOE]

The Hazardous Waste Program, administered by the Hazardous Waste Management Commission in the Department of Natural Resources, regulates the processing, transportation, and disposal of hazardous...

433

Enterprise Assessments Operational Awareness Record, Waste Treatment...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the melter handling system (LMH), the melter equipment support handling system (LSH), the radioactive solid waste handling system (RWH), and the radioactive liquid waste disposal...

434

Waste Management Programmatic Environmental Impact Statement...  

Office of Environmental Management (EM)

Waste Management Programmatic Environmental Impact Statement (WM PEIS) Reports and Records of Decision Waste Management Programmatic Environmental Impact Statement (WM PEIS)...

435

Independent Oversight Review, Advanced Mixed Waste Treatment...  

Broader source: Energy.gov (indexed) [DOE]

Review, Advanced Mixed Waste Treatment Project - April 2013 April 2013 Review of Radiation Protection Program Implementation at the Advanced Mixed Waste Treatment Project of...

436

Development of Thermoelectric Technology for Automotive Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermoelectric Technology for Automotive Waste Heat Recovery Development of Thermoelectric Technology for Automotive Waste Heat Recovery Overview and status of project to develop...

437

Development of Thermoelectric Technology for Automotive Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermoelectric Technology for Automotive Waste Heat Recovery Development of Thermoelectric Technology for Automotive Waste Heat Recovery Presentation from the U.S. DOE Office of...

438

Independent Oversight Activity Report, Hanford Waste Treatment...  

Office of Environmental Management (EM)

of River Protection review of the High Level Waste Facility heating, ventilation, and air conditioning systems. Independent Oversight Activity Report, Hanford Waste Treatment...

439

Waste Package Materials Performance Peer Review | Department...  

Broader source: Energy.gov (indexed) [DOE]

Waste Package Materials Performance Peer Review Waste Package Materials Performance Peer Review A consensus peer review of the current technical basis and the planned experimental...

440

Enterprise Assessments Operational Awareness Record, Waste Isolation...  

Energy Savers [EERE]

Operational Awareness Record, Waste Isolation Pilot Plant - March 2015 Enterprise Assessments Operational Awareness Record, Waste Isolation Pilot Plant - March 2015 March 2015...

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Chapter 47 Solid Waste Facilities (Kentucky)  

Broader source: Energy.gov [DOE]

This chapter establishes the permitting standards for solid waste sites or facilities, the standards applicable to all solid waste sites or facilities, and the standards for certification of...

442

Solid Waste Management Policy and Programs (Minnesota)  

Broader source: Energy.gov [DOE]

These statutes encourage the State and local governments to develop waste management strategies to achieve the maximum possible reduction in waste generation, eliminate or reduce adverse...

443

Independent Oversight Activity Report, Hanford Waste Treatment...  

Energy Savers [EERE]

October 2013 Independent Oversight Activity Report, Hanford Waste Treatment and Immobilization Plant - October 2013 October 2013 Observation of Waste Treatment and Immobilization...

444

Independent Oversight Inspection, Waste Isolation Pilot Plant...  

Energy Savers [EERE]

Independent Oversight Inspection, Waste Isolation Pilot Plant, Summary Report - August 2002 Independent Oversight Inspection, Waste Isolation Pilot Plant, Summary Report - August...

445

Independent Oversight Review, Sodium Bearing Waste Treatment...  

Energy Savers [EERE]

Federal - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Federal - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project -...

446

Voluntary Protection Program Onsite Review, Transuranic Waste...  

Energy Savers [EERE]

Transuranic Waste Processing Center - September 2012 Voluntary Protection Program Onsite Review, Transuranic Waste Processing Center - September 2012 September 2012 Evaluation to...

447

Independent Oversight Review, Sodium Bearing Waste Treatment...  

Energy Savers [EERE]

Contractor - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Contractor - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project...

448

Solid Waste Management Act (West Virginia)  

Broader source: Energy.gov [DOE]

In addition to establishing a comprehensive program of controlling all phases of solid waste management and assigning responsibilities for solid waste management to the Secretary of Department of...

449

1993 Solid Waste Reference Forecast Summary  

SciTech Connect (OSTI)

This report, which updates WHC-EP-0567, 1992 Solid Waste Reference Forecast Summary, (WHC 1992) forecasts the volumes of solid wastes to be generated or received at the US Department of Energy Hanford Site during the 30-year period from FY 1993 through FY 2022. The data used in this document were collected from Westinghouse Hanford Company forecasts as well as from surveys of waste generators at other US Department of Energy sites who are now shipping or plan to ship solid wastes to the Hanford Site for disposal. These wastes include low-level and low-level mixed waste, transuranic and transuranic mixed waste, and nonradioactive hazardous waste.

Valero, O.J.; Blackburn, C.L. [Westinghouse Hanford Co., Richland, WA (United States); Kaae, P.S.; Armacost, L.L.; Garrett, S.M.K. [Pacific Northwest Lab., Richland, WA (United States)

1993-08-01T23:59:59.000Z

450

Municipal Solid Waste Resources and Technologies  

Broader source: Energy.gov [DOE]

This page provides a brief overview of municipal solid waste energy resources and technologies supplemented by specific information to apply waste to energy within the Federal sector.

451

Independent Oversight Assessment, Waste Treatment and Immobilization...  

Office of Environmental Management (EM)

Waste Treatment and Immobilization Plant - January 2012 Independent Oversight Assessment, Waste Treatment and Immobilization Plant - January 2012 January 2012 Assessment of the...

452

Integrated Solid Waste Management Act (Nebraska)  

Broader source: Energy.gov [DOE]

This act affirms the state's support for alternative waste management practices, including waste reduction and resource recovery. Each county and municipality is required to file an integrated...

453

Independent Oversight Assessment, Salt Waste Processing Facility...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department...

454

Oversight Reports - Waste Isolation Pilot Plant | Department...  

Broader source: Energy.gov (indexed) [DOE]

Waste Isolation Pilot Plant - December 2007 Inspection of Emergency Management at the Carlsbad Field Office and Waste Isolation Pilot Plant October 2, 2002 Independent Oversight...

455

Independent Oversight Activity Report, Hanford Waste Treatment...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

July 2013 Independent Oversight Activity Report, Hanford Waste Treatment and Immobilization Plant - July 2013 July 2013 Operational Awareness of Waste Treatment and Immobilization...

456

Advanced Membrane Systems: Recovering Wasteful and Hazardous...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the...

457

Reporting Fraud, Waste, and Abuse  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

To notify all Department of Energy (DOE) employees, including National Nuclear Security Administration (NNSA) employees, of their duty to report allegations of fraud, waste, and abuse to the appropriate authorities, including the DOE Office of Inspector General (OIG). Cancels: DOE N 221.12, Reporting Fraud, Waste, and Abuse, dated 10-19-06

2006-12-15T23:59:59.000Z

458

THE ECONOMIST The waste industry  

E-Print Network [OSTI]

of ten feet. Humanity has always produced waste in vast quantities; but more people, more consumption as with toxic chemicals, governments need to persuade people that they should be responsible for the muck into electricity or fuel or fertiliser. Environmentalists dream of a world in which almost nothing is wasted. #12

459

Generating Steam by Waste Incineration  

E-Print Network [OSTI]

Combustible waste is a significant source of steam at the new John Deere Tractor Works assembly plant in Waterloo, Iowa. The incinerators, each rated to consume two tons of solid waste per hour, are expected to provide up to 100 percent of the full...

Williams, D. R.; Darrow, L. A.

1981-01-01T23:59:59.000Z

460

WASTE DISPOSAL SECTION CORNELL UNIVERSITY  

E-Print Network [OSTI]

radioactive products as regular trash. All packages must be free of contamination, radiation symbols2/07 WASTE DISPOSAL SECTION CORNELL UNIVERSITY PROCEDURE for DISPOSAL of RADIOACTIVE MATERIALS This procedure has been developed to ensure the safety of those individuals who handle radioactive waste

Pawlowski, Wojtek

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Waste Management Coordinating Lead Authors  

E-Print Network [OSTI]

-to-energy ..............................................601 10.4.4 Biological treatment including composting, anaerobic digestion, and MBT (Mechanical Biological Treatment) ........................................601 10.4.5 Waste reduction, re-use and recycling ..............602 10.4.6 Wastewater and sludge treatment.....................602 10.4.7 Waste

Columbia University

462

Method of recycling hazardous waste  

SciTech Connect (OSTI)

The production of primary metal from ores has long been a necessary, but environmentally devastating process. Over the past 20 years, in an effort to lessen environmental impacts, the metal processing industry has developed methods for recovering metal values from certain hazardous wastes. However, these processes leave residual molten slag that requires disposal in hazardous waste landfills. A new process recovers valuable metals, metal alloys, and metal oxides from hazardous wastes, such as electric arc furnace (EAF) dust from steel mills, mill scale, spent aluminum pot liners, and wastewater treatment sludge from electroplating. At the same time, the process does not create residual waste for disposal. This new method uses all wastes from metal production processes. These hazardous materials are converted to three valuable products - mineral wool, zinc oxide, and high-grade iron.

NONE

1999-11-11T23:59:59.000Z

463

Solid Waste Management Program Plan  

SciTech Connect (OSTI)

The objective of the Solid Waste Management Program Plan (SWMPP) is to provide a summary level comprehensive approach for the storage, treatment, and disposal of current and future solid waste received at the Hanford Site (from onsite and offsite generators) in a manner compliant with current and evolving regulations and orders (federal, state, and Westinghouse Hanford Company (Westinghouse Hanford)). The Plan also presents activities required for disposal of selected wastes currently in retrievable storage. The SWMPP provides a central focus for the description and control of cost, scope, and schedule of Hanford Site solid waste activities, and provides a vehicle for ready communication of the scope of those activities to onsite and offsite organizations. This Plan represents the most complete description available of Hanford Site Solid Waste Management (SWM) activities and the interfaces between those activities. It will be updated annually to reflect changes in plans due to evolving regulatory requirements and/or the SWM mission. 8 refs., 9 figs., 4 tabs.

Duncan, D.R.

1990-08-01T23:59:59.000Z

464

Characterization of geothermal solid wastes  

SciTech Connect (OSTI)

The compositions of 5 major types of geothermal wastes have been determined, and samples have been subjected to EPA recommended extraction tests to determine if they contain toxic metals that would classify the wastes as hazardous. Of the samples tested, the extracts of geothermal brines clearly contain levels of As, Ba and Pb exceeding the maximum allowed concentrations that characterize wastes as toxic. Only one other waste type, geothermal scale, exhibited EP toxicity. Pb was found in the extract of geothermal scale at a level of 7 mg/l, only 2 mg/l over the maximum limit. All of the other types of geothermal waste samples showed levels of toxic metals in the extracts well below the regulated limits.

Morris, W.F.; Stephens, F.B.

1981-07-01T23:59:59.000Z

465

Radioactive waste material melter apparatus  

DOE Patents [OSTI]

An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another.

Newman, Darrell F. (Richland, WA); Ross, Wayne A. (Richland, WA)

1990-01-01T23:59:59.000Z

466

Radioactive waste material melter apparatus  

DOE Patents [OSTI]

An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another. 8 figs.

Newman, D.F.; Ross, W.A.

1990-04-24T23:59:59.000Z

467

Optimizing High Level Waste Disposal  

SciTech Connect (OSTI)

If society is ever to reap the potential benefits of nuclear energy, technologists must close the fuel-cycle completely. A closed cycle equates to a continued supply of fuel and safe reactors, but also reliable and comprehensive closure of waste issues. High level waste (HLW) disposal in borosilicate glass (BSG) is based on 1970s era evaluations. This host matrix is very adaptable to sequestering a wide variety of radionuclides found in raffinates from spent fuel reprocessing. However, it is now known that the current system is far from optimal for disposal of the diverse HLW streams, and proven alternatives are available to reduce costs by billions of dollars. The basis for HLW disposal should be reassessed to consider extensive waste form and process technology research and development efforts, which have been conducted by the United States Department of Energy (USDOE), international agencies and the private sector. Matching the waste form to the waste chemistry and using currently available technology could increase the waste content in waste forms to 50% or more and double processing rates. Optimization of the HLW disposal system would accelerate HLW disposition and increase repository capacity. This does not necessarily require developing new waste forms, the emphasis should be on qualifying existing matrices to demonstrate protection equal to or better than the baseline glass performance. Also, this proposed effort does not necessarily require developing new technology concepts. The emphasis is on demonstrating existing technology that is clearly better (reliability, productivity, cost) than current technology, and justifying its use in future facilities or retrofitted facilities. Higher waste processing and disposal efficiency can be realized by performing the engineering analyses and trade-studies necessary to select the most efficient methods for processing the full spectrum of wastes across the nuclear complex. This paper will describe technologies being evaluated at Idaho National Laboratory and the facilities weve designed to evaluate options and support optimization.

Dirk Gombert

2005-09-01T23:59:59.000Z

468

Technological enhancements in TRU waste management.  

SciTech Connect (OSTI)

On March 26, 1999, the Waste Isolation Pilot Plant (WIPP) received its first shipment of transuranic (TRU) waste. On November 26, 1999, the Hazardous Waste Facility Permit (HWFP) to receive mixed TRU waste at WIPP became effective. Having achieved these two milestones, facilitating and supporting the characterization, transportation, and disposal of TRU waste became the major challenges for the National TRU Waste Program. After the WIPP began receiving waste, it was evident that, at the rate at which TRU waste was being shipped to and received at WIPP, the facility was not being used to its full potential, nor would it be unless improvements to the TRU waste management system were made. This paper describes some of the efforts to optimize (to make as functional as possible) characterization, transportation, and disposal of TRU waste; some of the technological enhancements necessary to achieve an optimized national transuranic waste system (1); and the interplay between regulatory change and technology development

Elkins, N. Z. (Ned Z.); Moody, D. C. (David C.)

2002-01-01T23:59:59.000Z

469

Los Alamos National Laboratory Waste Management Program  

SciTech Connect (OSTI)

Los Alamos National Laboratory's (LANL) waste management program is responsible for disposition of waste generated by many of the LANL programs and operations. LANL generates liquid and solid waste that can include radioactive, hazardous, and other constituents. Where practical, LANL hazardous and mixed wastes are disposed through commercial vendors; low-level radioactive waste (LLW) and radioactive asbestos-contaminated waste are disposed on site at LANL's Area G disposal cells, transuranic (TRU) waste is disposed at the Waste Isolation Pilot Plant (WIPP), and high-activity mixed wastes are disposed at the Nevada Test Site (NTS) after treatment by commercial vendors. An on-site radioactive liquid waste treatment facility (RLWTF) removes the radioactive constituents from liquid wastes and treated water is released through an NPDES permitted outfall. LANL has a very successful waste minimization program. Routine hazardous waste generation has been reduced over 90% since 1993. LANL has a DOE Order 450.1-compliant environmental management system (EMS) that is ISO 14001 certified; waste minimization is integral to setting annual EMS improvement objectives. Looking forward, under the new LANL management and operating contractor, Los Alamos National Security (LANS) LLC, a Zero Liquid Discharge initiative is being planned that should eliminate flow to the RLWTF NPDES-permitted outfall. The new contractor is also taking action to reduce the number of permitted waste storage areas, to charge generating programs directly for the cost to disposition waste, and to simplify/streamline the waste system. (authors)

Lopez-Escobedo, G.M.; Hargis, K.M.; Douglass, C.R. [Los Alamos National Laboratory, NM (United States)

2007-07-01T23:59:59.000Z

470

Waste characterization at Los Alamos National Laboratory  

SciTech Connect (OSTI)

Most industries generate limited types of solid wastes of a result of their manufacturing processes. The Los Alamos National Laboratory (LANL), a research and development facility, generates a large variety of solid wastes, some exotic. Over 50,000 distinct waste streams are currently generated in the 43 square mile area defining LANL. These wastes include refuse, medical, infectious, hazardous, radioactive, and mixed wastes. LANL is subject to federal and State oversight on matters concerning management of solid wastes. In order to assure regulatory agencies such as the New Mexico Environment Department (NMED) and the US Environmental Protection Agency (EPA) that the Laboratory is properly managing and disposing all solid wastes. LANL has undertaken an extensive waste characterization program to identify sources and ultimate disposition of all solid wastes. Given the number of solid waste streams expected, LANL has taken a two-pronged approach to characterizing wastes: (a) physical identification of all sources of solid wastes including interviews with waste generators; and (b) characterization of wastes from the point of generation. The former approach consists of canvassing all structures within the LANL complex, interviewing waste generators, and identifying sources of waste generation. Data gathered by these interviews are compiled in a database in order to identify the types and rates of waste generation and correct mismanagement of wastes identified during the interviews. The latter approach consists of characterizing all solid wastes which are controlled administratively or subject to stricter controls than municipal solid wastes (i.e., infectious, hazardous, radioactive, and mixed wastes). This characterization forms the basis by which LANL will manage solid waste in accordance to NMED/EPA regulations and US Department of Energy Orders. 8 refs., 3 figs.

Corpion, J.C.; Grieggs, A.R.

1991-01-01T23:59:59.000Z

471

Waste drum refurbishment  

SciTech Connect (OSTI)

Low-carbon steel, radioactive waste containers (55-gallon drums) are experiencing degradation due to moisture and temperature fluctuations. With thousands of these containers currently in use; drum refurbishment becomes a significant issue for the taxpayer and stockholders. This drum refurbishment is a non-intrusive, portable process costing between 1/2 and 1/25 the cost of repackaging, depending on the severity of degradation. At the INEL alone, there are an estimated 9,000 drums earmarked for repackaging. Refurbishing drums rather than repackaging can save up to $45,000,000 at the INEL. Based on current but ever changing WIPP Waste Acceptance Criteria (WAC), this drum refurbishment process will restore drums to a WIPP acceptable condition plus; drums with up to 40% thinning o the wall can be refurbished to meet performance test requirements for DOT 7A Type A packaging. A refurbished drum provides a tough, corrosion resistant, waterproof container with longer storage life and an additional containment barrier. Drums are coated with a high-pressure spray copolymer material approximately .045 inches thick. Increase in internal drum temperature can be held to less than 15 F. Application can be performed hands-on or the equipment is readily adaptable and controllable for remote operations. The material dries to touch in seconds, is fully cured in 48 hours and has a service temperature of {minus}60 to 500 F. Drums can be coated with little or no surface preparation. This research was performed on drums however research results indicate the coating is very versatile and compatible with most any material and geometry. It could be used to provide abrasion resistance, corrosion protection and waterproofing to almost anything.

Whitmill, L.J.

1996-10-18T23:59:59.000Z

472

TRU waste-sampling program  

SciTech Connect (OSTI)

As part of a TRU waste-sampling program, Los Alamos National Laboratory retrieved and examined 44 drums of /sup 238/Pu- and /sup 239/Pu-contaminated waste. The drums ranged in age from 8 months to 9 years. The majority of drums were tested for pressure, and gas samples withdrawn from the drums were analyzed by a mass spectrometer. Real-time radiography and visual examination were used to determine both void volumes and waste content. Drum walls were measured for deterioration, and selected drum contents were reassayed for comparison with original assays and WIPP criteria. Each drum tested at atmospheric pressure. Mass spectrometry revealed no problem with /sup 239/Pu-contaminated waste, but three 8-month-old drums of /sup 238/Pu-contaminated waste contained a potentially hazardous gas mixture. Void volumes fell within the 81 to 97% range. Measurements of drum walls showed no significant corrosion or deterioration. All reassayed contents were within WIPP waste acceptance criteria. Five of the drums opened and examined (15%) could not be certified as packaged. Three contained free liquids, one had corrosive materials, and one had too much unstabilized particulate. Eleven drums had the wrong (or not the most appropriate) waste code. In many cases, disposal volumes had been inefficiently used. 2 refs., 23 figs., 7 tabs.

Warren, J.L.; Zerwekh, A.

1985-08-01T23:59:59.000Z

473

Waste tire recycling by pyrolysis  

SciTech Connect (OSTI)

This project examines the City of New Orleans' waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans' waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city's limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city's waste tire problem. Pending state legislation could improve the city's ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

Not Available

1992-10-01T23:59:59.000Z

474

Tank Waste Disposal Program redefinition  

SciTech Connect (OSTI)

The record of decision (ROD) (DOE 1988) on the Final Environmental Impact Statement, Hanford Defense High-Level, Transuranic and Tank Wastes, Hanford Site, Richland Washington identifies the method for disposal of double-shell tank waste and cesium and strontium capsules at the Hanford Site. The ROD also identifies the need for additional evaluations before a final decision is made on the disposal of single-shell tank waste. This document presents the results of systematic evaluation of the present technical circumstances, alternatives, and regulatory requirements in light of the values of the leaders and constitutents of the program. It recommends a three-phased approach for disposing of tank wastes. This approach allows mature technologies to be applied to the treatment of well-understood waste forms in the near term, while providing time for the development and deployment of successively more advanced pretreatment technologies. The advanced technologies will accelerate disposal by reducing the volume of waste to be vitrified. This document also recommends integration of the double-and single-shell tank waste disposal programs, provides a target schedule for implementation of the selected approach, and describes the essential elements of a program to be baselined in 1992.

Grygiel, M.L.; Augustine, C.A.; Cahill, M.A.; Garfield, J.S.; Johnson, M.E.; Kupfer, M.J.; Meyer, G.A.; Roecker, J.H. [Westinghouse Hanford Co., Richland, WA (United States); Holton, L.K.; Hunter, V.L.; Triplett, M.B. [Pacific Northwest Lab., Richland, WA (United States)

1991-10-01T23:59:59.000Z

475

An approach for sampling solid heterogeneous waste at the Hanford Site waste receiving and processing and solid waste projects  

SciTech Connect (OSTI)

This paper addresses the problem of obtaining meaningful data from samples of solid heterogeneous waste while maintaining sample rates as low as practical. The Waste Receiving and Processing Facility, Module 1, at the Hanford Site in south-central Washington State will process mostly heterogeneous solid wastes. The presence of hazardous materials is documented for some packages and unknown for others. Waste characterization is needed to segregate the waste, meet waste acceptance and shipping requirements, and meet facility permitting requirements. Sampling and analysis are expensive, and no amount of sampling will produce absolute certainty of waste contents. A sampling strategy is proposed that provides acceptable confidence with achievable sampling rates.

Sexton, R.A.

1993-03-01T23:59:59.000Z

476

DuraLith Alkali-Aluminosilicate Geopolymer Waste Form Testing for Hanford Secondary Waste  

SciTech Connect (OSTI)

The primary objective of the work reported here was to develop additional information regarding the DuraLith alkali aluminosilicate geopolymer as a waste form for liquid secondary waste to support selection of a final waste form for the Hanford Tank Waste Treatment and Immobilization Plant secondary liquid wastes to be disposed in the Integrated Disposal Facility on the Hanford Site. Testing focused on optimizing waste loading, improving waste form performance, and evaluating the robustness of the waste form with respect to waste variability.

Gong, W. L.; Lutz, Werner; Pegg, Ian L.

2011-07-21T23:59:59.000Z

477

Waste Disposal Site and Radioactive Waste Management (Iowa)  

Broader source: Energy.gov [DOE]

This section describes the considerations of the Commission in determining whether to approve the establishment and operation of a disposal site for nuclear waste. If a permit is issued, the...

478

Transfer Lines to Connect Liquid Waste Facilities and Salt Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

far will integrate SWPF with current liquid waste facilities, such as the DWPF and the tanks farms." EM is pleased with the spirit of integration. "A key objective for us over the...

479

Waste Examination Assay Facility operations: TRU waste certification  

SciTech Connect (OSTI)

The ORNL Waste Examination Assay Facility (WEAF) was established to nondestructively assay (NDA) transuranic (TRU) waste generated at Oak Ridge National Laboratory (ORNL). The present facility charter encompasses the NDA and nondestructive examination (NDE) of both TRU and low-level wastes (LLW). Presently, equipment includes a Neutron Assay System (NAS), a Segmented Gamma Scanner (SGS), a drum-sized Real-Time Radiography (RTR) system, and a Neutron Slab Detector (NSD). The first three instruments are computer interfaced. Approximately 2300 TRU waste drums have been assayed with the NAS and the SGS. Another 3000 TRU and LLW drums have been examined with the RTR unit. Computer data bases have been developed to collate the large amount of data generated during the assays and examinations. 6 refs., 1 tab.

Schultz, F.J.; Caylor, B.A.; Coffey, D.E.; Phoenix, L.B.

1987-01-01T23:59:59.000Z

480

CRAD, Hazardous Waste Management- December 4, 2007  

Broader source: Energy.gov [DOE]

Hazardous Waste Management Implementation Inspection Criteria, Approach, and Lines of Inquiry (HSS CRAD 64-30)

Note: This page contains sample records for the topic "waste mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Waste Toolkit A-Z Plastic Grundon  

E-Print Network [OSTI]

Waste Toolkit A-Z Plastic ­ Grundon Also see `Swap Shop' and `Office Recycling ­ Grundon' in the Waste Toolkit A-Z How can I recycle plastic? There are lots of different types of plastic. Typically, waste contractors can only recycle PETE plastic and HDPE plastic. The University's preferred waste

Melham, Tom

482

WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,  

E-Print Network [OSTI]

Fuel oil and Turkey Based Biofuel Energy Rocovery 12,000 Industrial Waste $30,000 $500 $29,500 1500WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED, REUSED, RECYCLED OR CONSERVED IN 2006 WASTE TYPE DESCRIPTION DETAILS * Aerosol Can Disposal System Recycling 528 66 pounds of hazardous waste per unit $7

483

Waste disposal options report. Volume 1  

SciTech Connect (OSTI)

This report summarizes the potential options for the processing and disposal of mixed waste generated by reprocessing spent nuclear fuel at the Idaho Chemical Processing Plant. It compares the proposed waste-immobilization processes, quantifies and characterizes the resulting waste forms, identifies potential disposal sites and their primary acceptance criteria, and addresses disposal issues for hazardous waste.

Russell, N.E.; McDonald, T.G.; Banaee, J.; Barnes, C.M.; Fish, L.W.; Losinski, S.J.; Peterson, H.K.; Sterbentz, J.W.; Wenzel, D.R.

1998-02-01T23:59:59.000Z

484

Municipal Solid Waste in The United States  

E-Print Network [OSTI]

2011 Facts and Figures Municipal Solid Waste in The United States #12;United States Environmental Protection Agency Office of Solid Waste (5306P) EPA530-R-13-001 May 2013 www.epa.gov #12;MUNICIPAL SOLID WASTE IN THE UNITED STATES: 2011 FACTS AND FIGURES Table of Contents Chapter Page MUNICIPAL SOLID WASTE

Barlaz, Morton A.

485

Bubblers Speed Nuclear Waste Processing at SRS  

SciTech Connect (OSTI)

At the Department of Energy's Savannah River Site, American Recovery and Reinvestment Act funding has supported installation of bubbler technology and related enhancements in the Defense Waste Processing Facility (DWPF). The improvements will accelerate the processing of radioactive waste into a safe, stable form for storage and permit expedited closure of underground waste tanks holding 37 million gallons of liquid nuclear waste.

None

2010-11-14T23:59:59.000Z

486

Canister arrangement for storing radioactive waste  

DOE Patents [OSTI]

The subject invention relates to a canister arrangement for jointly storing high level radioactive chemical waste and metallic waste resulting from the reprocessing of nuclear reactor fuel elements. A cylindrical steel canister is provided with an elongated centrally disposed billet of the metallic waste and the chemical waste in vitreous form is disposed in the annulus surrounding the billet.

Lorenzo, Donald K. (Knoxville, TN); Van Cleve, Jr., John E. (Kingston, TN)

1982-01-01T23:59:59.000Z

487

Canister arrangement for storing radioactive waste  

DOE Patents [OSTI]

The subject invention relates to a canister arrangement for jointly storing high level radioactive chemical waste and metallic waste resulting from the reprocessing of nuclear reactor fuel elements. A cylindrical steel canister is provided with an elongated centrally disposed billet of the metallic waste and the chemical waste in vitreous form is disposed in the annulus surrounding the billet.

Lorenzo, D.K.; Van Cleve, J.E. Jr.

1980-04-23T23:59:59.000Z

488

UNITED STATES NUCLEAR WASTE TECHNICAL REVIEW BOARD  

E-Print Network [OSTI]

UNITED STATES NUCLEAR WASTE TECHNICAL REVIEW BOARD 2300 Clarendon Boulevard, Suite 1300 Arlington is intended to update Congress and the Secretary of Energy on the U.S. Nuclear Waste Technical Review Board-level radioactive waste (HLW) is evolving. The letter is issued in accordance with provisions of the Nuclear Waste

489

Bubblers Speed Nuclear Waste Processing at SRS  

ScienceCinema (OSTI)

At the Department of Energy's Savannah River Site, American Recovery and Reinvestment Act funding has supported installation of bubbler technology and related enhancements in the Defense Waste Processing Facility (DWPF). The improvements will accelerate the processing of radioactive waste into a safe, stable form for storage and permit expedited closure of underground waste tanks holding 37 million gallons of liquid nuclear waste.

None

2014-08-06T23:59:59.000Z

490

WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED,  

E-Print Network [OSTI]

WASTE DESCRIPTION TYPE OF PROJECT POUNDS REDUCED, REUSED, RECYCLED OR CONSERVED IN 2004 WASTE TYPE Brake Cleaner Recycling System Mercury Utility Devices Substitution 60 Hazardous Waste $1,750 $2,500 $1 of one PCB spill and clean-up event. Organic Solvents Substitution 678 Hazardous Waste $1,355 $36,500 $26

491

Proton NMR analysis of octane number for motor gasoline: Part V  

SciTech Connect (OSTI)

A method to predict the octane number of automobile gasoline containing methyl tert-butyl ether (MTBE) by proton magnetic resonance (PMR) spectrometry was studied. Samples of gasoline whose octane numbers had been identified according to the ASTM standards (commercially available premium gasoline to which MTBE was added at rates of 7 vol % and 14 vol %) were used in this investigation of the effect of MTBE on the octane number. The findings were utilized to introduce a term regarding MTBE into the previously reported linear regression equation for estimating the octane number from the PMR spectrum, and the appropriateness of the linear regression equation was assessed. As a result the MTBE contents in the sample were determined with satisfactory accuracy by using a standard addition method, and a linear regression equation reflecting the effect of MTBE was obtained. These achievements are reported. 11 refs., 3 figs., 5 tabs.

Ichikawa, M.; Nonaka, N.; Amano, H.; Takada, I.; Ishimori, S. [Suzuki Motor Corp., Hamamatsu (Japan); Andoh, H.; Kumamoto, K. [Showa Shell Sikiyu Tokyo (Japan)

1992-10-01T23:59:59.000Z

492

Waste in a land of plenty -Solid waste generation and management  

E-Print Network [OSTI]

of recycling and waste-to- energy, according to the latest in an annual series of national surveys on municipal waste numbers using tonnages only, with any percentages - for recycling, landfilling, waste-to-energyWaste in a land of plenty - Solid waste generation and management in the US The US generates

Columbia University

493

Seventh State of the Environment Report 3.11 Waste Management 3.11 WASTE MANAGEMENT  

E-Print Network [OSTI]

Seventh State of the Environment Report 3.11 Waste Management 211 3.11 WASTE MANAGEMENT 3 on waste management: specific types of waste (end-of-life vehicles, white goods) must be collected materials are available. A small share of hazardous waste is also disposed of abroad, for ex- ample

Columbia University

494

Consolidation process for producing ceramic waste forms  

DOE Patents [OSTI]

A process for the consolidation and containment of solid or semisolid hazardous waste, which process comprises closing an end of a circular hollow cylinder, filling the cylinder with the hazardous waste, and then cold working the cylinder to reduce its diameter while simultaneously compacting the waste. The open end of the cylinder can be sealed prior to or after the cold working process. The preferred method of cold working is to draw the sealed cylinder containing the hazardous waste through a plurality of dies to simultaneously reduce the diameter of the tube while compacting the waste. This process provides a quick continuous process for consolidating hazardous waste, including radioactive waste.

Hash, Harry C. (Joliet, IL); Hash, Mark C. (Shorewood, IL)

2000-01-01T23:59:59.000Z

495

NEVADA TEST SITE WASTE ACCEPTANCE CRITERIA  

SciTech Connect (OSTI)

This document establishes the U. S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site will accept low-level radioactive and mixed waste for disposal. Mixed waste generated within the State of Nevada by NNSA/NSO activities is accepted for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the Nevada Test Site Area 3 and Area 5 Radioactive Waste Management Site for storage or disposal.

U.S. DEPARTMENT OF ENERGY, NATIONAL NUCLEAR SECURITY ADMINISTRATION, NEVADA SITE OFFICE

2005-07-01T23:59:59.000Z

496

Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication  

SciTech Connect (OSTI)

This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea ROK) and United States of America (US) centric in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration between US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.

Steven Frank; Hwan Seo Park; Yung Zun Cho; William Ebert; Brian Riley

2014-12-01T23:59:59.000Z

497

The Hazardous Waste/Mixed Waste Disposal Facility  

SciTech Connect (OSTI)

The Hazardous Waste/Mixed Waste Disposal Facility (HW/MWDF) will provide permanent Resource Conservation and Recovery Act (RCRA) permitted storage, treatment, and disposal for hazardous and mixed waste generated at the Department of Energy's (DOE) Savannah River Site (SRS) that cannot be disposed of in existing or planned SRS facilities. Final design is complete for Phase I of the project, the Disposal Vaults. The Vaults will provide RCRA permitted, above-grade disposal capacity for treated hazardous and mixed waste generated at the SRS. The RCRA Part B Permit application was submitted upon approval of the Permit application, the first Disposal Vault is scheduled to be operational in mid 1994. The technical baseline has been established for Phase II, the Treatment Building, and preliminary design work has been performed. The Treatment Building will provide RCRA permitted treatment processes to handle a variety of hazardous and mixed waste generated at SRS in preparation for disposal. The processes will treat wastes for disposal in accordance with the Environmental Protection Agency's (EPA's) Land Disposal Restrictions (LDR). A RCRA Part B Permit application has not yet been submitted to SCDHEC for this phase of the project. The Treatment Building is currently scheduled to be operational in late 1996.

Bailey, L.L.

1991-01-01T23:59:59.000Z

498

The Hazardous Waste/Mixed Waste Disposal Facility  

SciTech Connect (OSTI)

The Hazardous Waste/Mixed Waste Disposal Facility (HW/MWDF) will provide permanent Resource Conservation and Recovery Act (RCRA) permitted storage, treatment, and disposal for hazardous and mixed waste generated at the Department of Energy`s (DOE) Savannah River Site (SRS) that cannot be disposed of in existing or planned SRS facilities. Final design is complete for Phase I of the project, the Disposal Vaults. The Vaults will provide RCRA permitted, above-grade disposal capacity for treated hazardous and mixed waste generated at the SRS. The RCRA Part B Permit application was submitted upon approval of the Permit application, the first Disposal Vault is scheduled to be operational in mid 1994. The technical baseline has been established for Phase II, the Treatment Building, and preliminary design work has been performed. The Treatment Building will provide RCRA permitted treatment processes to handle a variety of hazardous and mixed waste generated at SRS in preparation for disposal. The processes will treat wastes for disposal in accordance with the Environmental Protection Agency`s (EPA`s) Land Disposal Restrictions (LDR). A RCRA Part B Permit application has not yet been submitted to SCDHEC for this phase of the project. The Treatment Building is currently scheduled to be operational in late 1996.

Bailey, L.L.

1991-12-31T23:59:59.000Z

499

Motor Gasoline Outlook and State MTBE Bans  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil31 E n e

500

Potential microbial impact on transuranic wastes under conditions expected in the Waste Isolation Pilot Plant (WIPP). Annual report, October 1, 1978-September 30, 1979  

SciTech Connect (OSTI)

Previous results were confirmed showing elevated frequencies of radiation-resistant bacteria in microorganisms isolated from shallow transuranic (TRU) burial soil that exhibits nanocurie levels of beta and gamma radioactivity. Research to determine whether plutonium could be methylated by the microbially produced methyl donor, methylcobalamine, was terminated when literature and consulting radiochemists confirmed that other alkylated transuranic elements are extremely short-lived in the presence of oxygen. Emphasis was placed on investigation of the dissolution of plutonium dioxide by complex formation between plutonium and a polyhydroxamate chelate similar to that produced by microorganisms. New chromatographic and spectrophotometric evidence supports previous results showing enhanced dissolution of alpha radioactivity when /sup 239/Pu dioxide was mixed with the chelate Desferol. Microbial degradation studies of citrate, ethylenediamine tetraacetate (EDTA), and nitrilo triacetate (NTA) chelates of europium are in progress. Current results are summarized. All of the chelates were found to degrade. The average half-life for citrate, NTA, and EDTA was 3.2, 8.0, and 28 years, respectively. Microbial CO/sub 2/ generation is also in progress in 72 tests on several waste matrices under potential WIPP isolation conditions. The mean rate of gas generation was 5.97 ..mu..g CO/sub 2//g waste/day. Increasing temperature increased rates of microbial gas generation across treatments of brine, varying water content, nutrient additions, and anaerobic conditions. No microbial growth was detected in experiments to enumerate and identify the microorganisms in rocksalt cores from the proposed WIPP site. This report contains the year's research results and recommendations derived for the design of safe storage of TRU wastes under geologic repository conditions.

Barnhart, B.J.; Campbell, E.W.; Martinez, E.; Caldwell, D.E.; Hallett, R.

1980-07-01T23:59:59.000Z