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1

SOLOX coke-oven gas desulfurization ppm levels -- No toxic waste  

SciTech Connect

For sulfur removal from coke-oven gas, the reduction/oxidation processes such as Stretford are the most effective, capable of removing the H[sub 2]S down to ppm levels. However, these processes have, in the past, suffered from ecological problems with secondary pollutant formation resulting from side reactions with HCN and O[sub 2]. The SOLOX gas desulfurization system is a development of the Stretford process in which the toxic effluent problems are eliminated by installing a salt decomposition process operating according to the liquid-phase hydrolysis principle. In this process, the gaseous hydrolysis products H[sub 2]S, NH[sub 3] and CO[sub 2] are returned to the untreated gas, and the regenerated solution is recycled to the absorption process. The blowdown from the absorption circuit is fed into a tube reactor where the hydrolysis process takes place. The toxic salts react with water, producing as reaction products the gases H[sub 2]S, NH[sub 3] and CO[sub 2], and the nontoxic salt Na[sub 2]SO[sub 4]. From the hydrolysis reactor the liquid stream flows into a fractionating crystallization plant. This plant produces a recycle stream of regenerated absorption solution and a second stream containing most of the Na[sub 2]SO[sub 4]. This second stream comprises the net plant waste and can be disposed of with the excess ammonia liquor or sprayed onto the coal.

Platts, M. (Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)); Tippmer, K. (Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany))

1994-09-01T23:59:59.000Z

2

Coke oven gas desulfurization: at Republic Steel's New Coking Facility, Warren, OH  

SciTech Connect

Our performance test indicates that the Sulfiban process is an effective method for removing H/sub 2/S from coke-oven gas. The process is able to handle variations in coke-oven gas flow and composition. Continuing efforts are underway to maintain optimum desulfurization conditions while trying to reduce waste production and MEA consumption. The problems which have prevented us from operating continuously have given us a better understanding of the process. This has contributed to better plant operations and greater equipment reliability for us to obtain continuous coke-oven gas desulfurization. 2 figures, 1 table.

Boak, S.C.; Prucha, D.G.; Turic, H.L.

1981-01-01T23:59:59.000Z

3

New process for coke-oven gas desulfurization  

SciTech Connect

With the EPA reclassifying spent iron oxide as a hazardous waste material in 1990, an alternative technology was sought for desulfurizing coke-oven gas. Vacasulf technology was adopted for reasons that included: producing of coke battery heating gas without further polishing and high-quality elemental sulfur; lowest operating cost in comparison with other methods; no waste products; and integrates with existing ammonia destruction facility. Vacasulf requires a single purchased material, potassium hydroxide, that reacts with carbon dioxide in coke-oven gas to form potassium carbonate which, in turn, absorbs hydrogen sulfide. Operation of the system has been successful following the resolution of relatively minor start-up problems.

Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

1995-10-01T23:59:59.000Z

4

Method for processing coke oven gas  

SciTech Connect

Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO2-containing gas, with a steam reforming catalyst.

Flockenhaus, C.; Meckel, J.F.; Wagener, D.

1980-11-25T23:59:59.000Z

5

Process for the elimination of waste water produced upon the desulfurization of coking oven gas by means of wash solution containing organic oxygen-carrier, with simultaneous recovery of elemental sulfur  

Science Conference Proceedings (OSTI)

A process is disclosed for the elimination of waste water falling out with the desulfurization of coking oven gas by means of an organic oxygen carrier-containing washing solution with simultaneous recovery of elemental sulfur. The waste water is decomposed in a combustion chamber in a reducing atmosphere at temperatures between about 1000/sup 0/ and 1100/sup 0/ C. under such conditions that the mole ratio of H/sub 2/S:SO/sub 2/ in the exhaust gas of the combustion chamber amounts to at least 2:1. Sulfur falling out is separated and the sensible heat of the exhaust gas is utilized for steam generation. The cooled and desulfurized exhaust gas is added to the coking oven gas before the pre-cooling. Sulfur falling out from the washing solution in the oxidizer is separated out and lead into the combustion chamber together with the part of the washing solution discharged as waste water from the washing solution circulation. Preferred embodiments include that the sulfur loading of the waste water can amount to up to about 370 kg sulfur per m/sup 3/ waste water; having the cooling of sulfur-containing exhaust gas leaving the combustion chamber follow in a waste heat boiler and a sulfur condenser heated by pre-heated boiler feed water, from which condenser sulfur is discharged in liquid state.

Diemer, P.; Brake, W.; Dittmer, R.

1985-04-16T23:59:59.000Z

6

Desulphurization of coke oven gas by the Stretford Process  

SciTech Connect

The Stretford process is probably the most effective means available for removing hydrogen sulphide from gas streams. For streams which do not contain hydrogen cyanide or excessive oxygen it should be nearly ideal. However, the large volume of waste liquor generated by fixation of hydrogen cyanide has prevented its widespread adoption for coke oven gas treatment. Investigations of various proposals for treating the waste liquor indicate that the only practicable way of dealing with it is by reductive incineration. Although attempts to apply the Peabody-Holmes reductive incineration process have been disappointing, significant progress in overcoming some of its deficiencies has been made. The Zimpro wet oxidation process will provide a convenient method of treating the HCN scrubber effluent at No. 1 Plant. However, it will not treat the sodium based liquor from the Stretford plant. Its application to Stretford waste treatment is limited to situations where ammonium liquors and ammonium sulphate recovery facilities are available. Commissioning of this plant has been delayed while a defect in the air compressor supplied for the plant is being remedied. When the problem of liquid effluent disposal has been overcome, and if reagent chemicals continue to be available at reasonable prices, the Stretford process will be a good choice for coke oven gas desulphurization. 8 figures.

Plenderleith, J.

1981-01-01T23:59:59.000Z

7

Innovative coke oven gas cleaning system for retrofit applications  

DOE Green Energy (OSTI)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

Not Available

1992-08-24T23:59:59.000Z

8

Problem of improving coke oven gas purification systems  

Science Conference Proceedings (OSTI)

A discussion of the problems of improving desulfurization processes of coke oven gas was presented. Of particular interest were control systems and increasing capacity of the coke ovens. Included in the discussion were the vacuum-carbonate and arsenic-soda sulfur removal systems. Problems involved with these systems were the number of treatment operations, the volume of the reagents used, and the operation of equipment for naphthalene and cyanide removal.

Goldin, I.A.

1982-01-01T23:59:59.000Z

9

Fuel gas main replacement at Acme Steel's coke plant  

SciTech Connect

ACME Steel's Chicago coke plant consists of two 4-meter, 50-oven Wilputte underjet coke-oven batteries. These batteries were constructed in 1956--1957. The use of blast furnace gas was discontinued in the late 1960's. In 1977--1978, the oven walls in both batteries were reconstructed. Reconstruction of the underfire system was limited to rebuilding the coke-oven gas reversing cocks and meter in orifices. By the early 1980's, the 24-in. diameter underfire fuel gas mains of both batteries developed leaks at the Dresser expansion joints. These leaks were a result of pipe loss due to corrosion. Leaks also developed along the bottoms and sides of both mains. A method is described that permitted pushing temperatures to be maintained during replacement of underfire fuel gas mains. Each of Acme's two, 50-oven, 4-metric Wilputte coke-oven, gas-fired batteries were heated by converting 10-in. diameter decarbonizing air mains into temporary fuel gas mains. Replacement was made one battery at a time, with the temporary 10-in. mains in service for five to eight weeks.

Trevino, O. (Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant)

1994-09-01T23:59:59.000Z

10

New packing in absorption systems for trapping benzene from coke-oven gas  

SciTech Connect

The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

11

Coke oven gas desulphurization by the Carl Still process  

SciTech Connect

The Steubenville East Coke Plant need a desulfurization process that would desulfurize an eventual 95 million standard cubic feet per day of coke oven gas from an inlet of 450 gr/DSCF to an outlet of 45 gr/DSCF of hydrogen sulfide. The Dravo/Still plant process was selected, due to the use of ammonia which was available in the gas, as the absorbing agent. It was also a proven process. Dravo/Still also was capable of building a sulfuric acid plant. The desulfurization efficiency of the plant has consistently provided an average final gas sulfur loading below the guaranteed 45 gr/DSCF. This removal efficiency has enabled production of an average of 4615 tons per day of 66/sup 0/Be acid. Also SO/sub 2/ to SO/sub 3/ conversion has averaged 98%. 3 figures. (DP)

Knight, R.E.

1981-01-01T23:59:59.000Z

12

Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas  

SciTech Connect

The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

13

Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process  

DOE Patents (OSTI)

In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

DeGeorge, Charles W. (Chester, NJ)

1981-01-01T23:59:59.000Z

14

Cogeneration Waste Heat Recovery at a Coke Calcining Facility  

E-Print Network (OSTI)

PSE Inc. recently completed the design, construction and start-up of a cogeneration plant in which waste heat in the high temperature flue gases of three existing coke calcining kilns is recovered to produce process steam and electrical energy. The heat previously exhausted to the atmosphere is now converted to steam by waste heat recovery boilers. Eighty percent of the steam produced is metered for sale to a major oil refinery, while the remainder passes through a steam turbine generator and is used for deaeration and feedwater heating. The electricity produced is used for the plant auxiliaries and sold to the local utility. Many design concepts were incorporated into the plant which provided for high plant availability, reliability and energy efficiency. This paper will show how these concepts were implemented and incorporated into the detailed design of the plant while making cogeneration a cost effective way to save conventional fuels. Operating data since plant start-up will also be presented.

Coles, R. L.

1986-06-01T23:59:59.000Z

15

Takahax-Hirohax process for coke oven gas desulfurization  

SciTech Connect

This paper describes the Takahax-Hirohax process to desulfurize coke oven gas and to produce an ammonium sulfate end product. A review is also made of current operating experience and recent technical developments. The Takahax-Hirohax process is extremely useful when the COG contains a suitable ammonia to sulfur ratio and when ammonium sulfate is a desirable end product. No contaminated effluent streams are emitted from the process. The process is simple, reliable, flexible, and responds easily to COG variations. 4 figures, 3 tables. (DP)

Gastwirth, H.; Miner, R.; Stengle, W.

1981-01-01T23:59:59.000Z

16

Method for removing hydrogen sulfide from coke oven gas  

Science Conference Proceedings (OSTI)

An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

Ritter, H.

1982-08-03T23:59:59.000Z

17

Organic Sulphur Transfers in Coke Oven Gas via Noncatalytic Partial Oxidation  

Science Conference Proceedings (OSTI)

The organic sulfur transformation was studied during coke oven gas to produce syngas via noncatalytic partial oxidation. The concentration of CS2 and thiophene was examined in syngas by sulfide detector. For comparison, the sulfur transfer was also studied ... Keywords: Organic sulfur transfer, Coke oven gas, CS2, thiophene

Guojie Zhang; Yongfa Zhang; Xianglan Li; Hongcheng Cao

2009-10-01T23:59:59.000Z

18

A new technology for producing hydrogen and adjustable ratio syngas from coke oven gas  

Science Conference Proceedings (OSTI)

About 15 billion Nm{sup 3} coke oven gas (COG) is emitted into the air in Shanxi Province in China as air pollutants. It is also a waste of precious chemical resources. In this study, COG was purified respectively by four methods including refrigeration, fiberglass, silica gel, and molecular sieve. Purified COG was separated by a prism membrane into two gas products. One consists mainly of H{sub 2} ({gt}90 vol %) and the other is rich in CH{sub 4} ({gt}60 vol %) with their exact compositions to vary with the membrane separation pressure and outlet gas flow ratio. The gas rich in CH{sub 4} was partially oxidized with oxygen in a high-temperature fixed-bed quartz reactor charged with coke particles of 10 mm size. At 1200-1300{sup o}C, a CH{sub 4} conversion of {gt}99% could be obtained. The H{sub 2}/CO ratio in the synthesis product gas can be adjusted in the range 0.3-1.4, very favorable for further C1 synthesis. 10 refs., 17 figs., 1t ab.

Jun Shen; Zhi-zhong Wang; Huai-wang Yang; Run-sheng Yao [Taiyuan University of Technology, Taiyuan (China). Department of Chemical Engineering

2007-12-15T23:59:59.000Z

19

Innovative coke oven gas cleaning system for retrofit applications  

Science Conference Proceedings (OSTI)

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

Not Available

1992-10-16T23:59:59.000Z

20

Dale Coke: Coke Farm  

E-Print Network (OSTI)

Dale Coke Photo by Benjamin J. Myers.2009. Coke FarmDale Coke grew up on an apricot orchard in California’s

Farmer, Ellen

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Innovative coke oven gas cleaning system for retrofit applications: Environmental Monitoring Program. Volume 3, Appendix sections 8--14: Baseline Sampling Program report  

Science Conference Proceedings (OSTI)

This report contains no text. It consists entirely of numerical data: Coke oven wastewater treatment performance; Ammonia still effluents to equalization tank; Stack gas analysis of coke oven batteries; CoaL consumption; Coke production; Supplemental OSHA employee exposure monitoring(hydrocarbons,ammonia, hydrogen sulfide); operating data; chemical products and coke oven gas production.

Stuart, L.M.

1994-05-27T23:59:59.000Z

22

The use of ethylenediamine to remove hydrogen sulfide from coke oven gas  

Science Conference Proceedings (OSTI)

The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution showed the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be used in the form of ethylenethiourea - a marketable byproduct.

Marakhovskii, L.F.; Rezunenko, Y.I.; Popov, A.A.

1983-01-01T23:59:59.000Z

23

Use of ethylenediamine to remove hydrogen sulfide from coke oven gas  

SciTech Connect

The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution which show that the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be recovered in the form of ethylenethiourea - a marketable byproduct.

Marakhovskii, L.F.; Popov, A.A.; Rezunenko, Yu.I.

1983-01-01T23:59:59.000Z

24

Utilizing secondary heat to heat wash oil in the coke-oven gas desulfurization division  

SciTech Connect

Removal of hydrogen sulfide from the coke-oven gas by the vacuum-carbonate method involves significant energy costs, comprising about 47% of the total costs of the process. This is explained by the significant demand of steam for regeneration of the wash oil, the cost of which exceeds 30% of the total operating costs. The boiling point of the saturated wash oil under vacuum does not exceed 70/sup 0/C, thus the wash oil entering the regenerator can be heated either by the direct coke-oven gas or by the tar supernatant from the gas collection cycle. Utilizing the secondary heat of the direct coke-oven gas and the tar supernatant liquor (the thermal effect is approximately the same) to heat the wash oil from the gas desulfurization shops significantly improves the industrial economic indices. Heating the wash oil from gas desulfurization shops using the vacuum-carbonate method by the heat of the tar supernatant liquor may be adopted at a number of coking plants which have a scarcity of thermal resources and which have primary coolers with vertical tubes.

Volkov, E.L.

1981-01-01T23:59:59.000Z

25

Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report  

SciTech Connect

This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

Not Available

1994-05-24T23:59:59.000Z

26

Final environmental information volume for the coke oven gas cleaning project at the Bethlehem Steel Corporation Sparrows Point Plant  

Science Conference Proceedings (OSTI)

Bethelehem Steel Corporation (BSC) is planning to conduct a demonstration project involving an integrated system that can be retrofitted into coke oven gas handling systems to address a variety of environmental and operational factors in a more cost-effective manner. Successful application of this technology to existing US coke plants could: (1) reduce emissions of sulfur dioxide, cyanide, and volatile organic compounds (including benzene) (2) reduce the cost and handling of processing feed chemicals, (3) disposal costs of nuisance by-products and (4) increase reliability and reduce operation/maintenance requirements for coke oven gas desulfurization systems. The proposed system will remove sulfur from the coke oven gas in the form of hydrogen sulfide using the ammonia indigenous to the gas as the primary reactive chemical. Ammonia and hydrogen cyanide are also removed in this process. The hydrogen sulfide removed from the coke oven gas in routed to a modified Claus plant for conversion to a saleable sulfur by-product. Ammonia and hydrogen cyanide will be catalytically converted to hydrogen, nitrogen, carbon dioxide, and carbon monoxide. The tail gas from the sulfur recovery unit is recycled to the coke oven gas stream, upstream of the new gas cleaning system. The proposed demonstration project will be installed at the existing coke oven facilities at BSC's Sparrows Point Plant. This volume describes the proposed actions and the resulting environmental impacts. 21 refs., 19 figs., 9 tabs.

Not Available

1990-04-24T23:59:59.000Z

27

Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine  

SciTech Connect

The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

2007-03-15T23:59:59.000Z

28

Choosing a coke-oven gas desulfurization system: a review of current technology  

SciTech Connect

Installation of coke-oven gas desulphurizing systems is primarily the result of air pollution control regulations. Although not currently profitable, operating costs can be minimized by choosing the technology most suited to the particular application. The Stretford Holmes, Takahax/Hirohax, Koppers Vacuum Carbonate, Sulfiban and Dravo/Still processes are discussed, together with criteria for economic analysis based on technical and by-product market evaluations.

Lynch, P.A.

1982-12-01T23:59:59.000Z

29

Method of washing hydrogen sulfide from coke oven gas by the ammonium sulfide method  

Science Conference Proceedings (OSTI)

An improved coke oven gas washing process for removing hydrogen sulfide is proposed wherein the coke oven gas is treated in a hydrogen sulfide scrubber by counterflow with an aqueous ammonia wash water. A stream of aqueous weak ammonia liquor is cooled and sprayed through nozzles in the mid-region of the hydrogen sulfide scrubber. A quantity of aqueous ammonia liquor, corresponding to the quantity which is sprayed through the said nozzles, is withdrawn from the hydrogen sulfide scrubber at a level below the nozzles and is introduced into the top of the said hydrogen sulfide scrubber. Ammonia vapor released at the nozzles has a higher partial pressure than the ammonia partial pressure of the coke oven gas in the region of the nozzle. The aqueous ammonia liquor from the deacidifier is the source of the cooled aqueous ammonia liquor which is introduced through the nozzles. A portion of the aqueous ammonia liquor from the deacidifier is introduced directly into the top of the hydrogen sulfide scrubber as a portion of the required aqueous ammonia wash water.

Ritter, H.

1985-05-21T23:59:59.000Z

30

Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel  

Science Conference Proceedings (OSTI)

The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

1996-02-01T23:59:59.000Z

31

Innovative coke oven gas cleaning system for retrofit applications  

SciTech Connect

The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental Monitoring includes sampling of 27 additional streams that are important to measure operational or environmental performance and impacts of the installation of the new COG treatment facilities.

Not Available

1992-09-21T23:59:59.000Z

32

Reduction of NO[sub x] emissions coke oven gas combustion process  

SciTech Connect

The paper describes by-product processing at Clairton Works which uses a unique cryogenic technology. Modifications to the desulfurization facility, nitrogen oxide formation in combustion processes (both thermal and fuel NO[sub x]), and the boilers plants are described. Boilers were used to study the contribution of fuel NO[sub x] formation during the combustion of coke oven gas. Results are summarized. The modifications made to the desulfurization facility resulted in the overall H[sub 2]S emission being reduced by 2-4 grains/100scf and the NO[sub x] emission being reduced by 21-42% in the boiler stacks.

Terza, R.R. (USS Clairton Works, PA (United States)); Sardesai, U.V. (Westfield Engineering and Services, Inc., Houston, TX (United States))

1993-01-01T23:59:59.000Z

33

Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz  

Science Conference Proceedings (OSTI)

The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2008-03-15T23:59:59.000Z

34

Problem of sludge formation in benzol division solar oil and ''carbonization'' in coke oven gas compressor systems  

Science Conference Proceedings (OSTI)

A discussion is presented on the problem and possible causes of sludge formation in the return solar oil in benzene recovery units and on the problem of deposits in the pipe systems after coke oven gas compressors. The possible entrainment of fine particles of coal charge in the solar oil was also discussed. Sedimentation of the sludge was recommended with daily removal of the settled sludge. A chemical analysis of the deposits in the piping system of the coke oven gas and the coal charge revealed that the deposits were not caused by entrained coal particles. (JMT)

Rezunenko, Y.I.

1982-01-01T23:59:59.000Z

35

Summing up of discussion on improvement trends in coke-oven gas purification flowsheets  

SciTech Connect

Reference is made to a previously published article that included flowsheets for purification of coke-oven gas. It is concluded that the flowsheets for a process using arsenic-soda and vacuum-carbonate methods of sulfur removal in which the gas is cooled to 303-308/sup 0/K are seriously in error. Schemes involving minor refrigeration, sulfur removal by the circulating ammonia method and ammonia recovery as ammonia liquor are seen as promising but in need of further improvement. One scheme discussed (the VUKhIN scheme) involves ammonia recovery by the circulating phosphate method and sulfur removal by the circulating ammonia method is seen as a replacement for the minor refrigeration method. Since liquid ammonia consumption in agriculture is continually increasing, schemes that result in production of liquid ammonia rather than ammonia liquor should be seriously considered.

Zemblevskii, K.K.

1983-01-01T23:59:59.000Z

36

Hydrogen production from simulated hot coke oven gas by using oxygen-permeable ceramics  

SciTech Connect

Hydrogen production from simulated hot coke oven gas (HCOG) was investigated in a BaCo{sub 0.7}Fe{sub 0.2}Nb{sub 0.1}O{sub 3-{delta}} (BCFNO) membrane reactor combined with a Ni/Mg(Al)O catalyst by the partial oxidation with toluene as a model tar compound under atmospheric pressure. The reaction results indicated that toluene was completely converted to H{sub 2} and CO in the catalytic reforming of the simulated HCOG in the temperature range from 825 to 875{sup o}C. Both thermodynamically predicated values and experimental data showed that the selective oxidation of toluene took precedence over that of CH{sub 4} in the reforming reaction. At optimized reaction conditions, the dense oxygen-permeable membrane has an oxygen permeation flux around 12.3 mL cm{sup -2} min{sup -1}, and a CH{sub 4} conversion of 86%, a CO{sub 2} conversion of 99%, a H{sub 2} yield of 88%, and a CO yield of 87% have been achieved. When the toluene and methane were reformed, the amount of H{sub 2} in the reaction effluent gas was about 2 times more than that of original H{sub 2} in simulated HCOG. The results reveal that it is feasible for hydrogen production from HCOG by reforming hydrocarbon compounds in a ceramic oxygen-permeable membrane reactor. 27 refs., 10 figs., 3 abs.

Hongwei Cheng; Yuwen Zhang; Xionggang Lu; Weizhong Ding; Qian Li [Shanghai University, Shanghai (China). Shanghai Key Laboratory of Modern Metallurgy and Materials Processing

2009-01-15T23:59:59.000Z

37

Kansas refinery starts up coke gasification unit  

SciTech Connect

Texaco Refining and Marketing Inc. has started up a gasification unit at its El Dorado, Kan., refinery. The unit gasifies delayed coke and other refinery waste products. This is the first refinery to install a coke-fueled gasification unit for power generation. Start-up of the $80-million gasification-based power plant was completed in mid-June. The gasifier produces syngas which, along with natural gas, fuels a combustion turbine. The turbine produces virtually 100% of the refinery`s electricity needs and enough heat to generate 40% of its steam requirements.

Rhodes, A.K.

1996-08-05T23:59:59.000Z

38

Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report  

Science Conference Proceedings (OSTI)

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

Stuart, L.M.

1994-05-27T23:59:59.000Z

39

Coke briquettes  

SciTech Connect

This patent describes a briquette suitable for use as an auxiliary fuel in a shaft furnace for melting of mineral in the manufacture of mineral wool which comprises: 30-75% by weight, based on the dry weight of the briquettes, of particles of coke fines or coal fines or both, the fines consisting essentially of particles having a particle size of from 2 to 25 mm; at least 7% by weight, based on the dry weight of the briquette, of a hydraulic binder; and at least 15% by weight, based on the dry weight of the briquette, of a fine grain oxidic mineral component selected from the group consisting of sand, slag, stone powder, fly ash, limestone powder, dolomite powder, silicon dioxide, and waste material from mineral wool manufacturer, the fine grain oxidic mineral component having a particle size of less than 2 mm.

Anderson, D.B.; Juhlin, N.J.W.; Gillenium, C.I.; Kjell-Berger, O.; Brinck, O.R.

1987-04-28T23:59:59.000Z

40

Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 1, January 1, 1991--June 30, 1991  

DOE Green Energy (OSTI)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

Not Available

1992-08-24T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"  

U.S. Energy Information Administration (EIA) Indexed Site

2 Relative Standard Errors for Table 7.2;" 2 Relative Standard Errors for Table 7.2;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,,,,,"Natural Gas",,,"Steam",,,," ",,,"and","Wood-Related","All"

42

,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"  

U.S. Energy Information Administration (EIA) Indexed Site

Relative Standard Errors for Table 7.1;" Relative Standard Errors for Table 7.1;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,,,,,"Natural Gas",,,"Steam",,,," ",,,"and","Wood-Related","All"

43

Influence of technological factors on statics of hydrogen sulfide absorption from coke-oven gas by the ammonia process  

SciTech Connect

The basic technological factors that determine the effectiveness of hydrogen sulfide absorption from coke-oven gas by the cyclic ammonia process are the initial H/sub 2/S content of the gas, the degree of purification, the absorption temperature and the NH/sub 3/ and CO/sub 2/ contents of the absorbent solution. The effects of these factors on the statics of hydrogen sulfide absorption are studied. The investigation is based on the phase-equilibrium distributions of components in the absorption-desorption gas-cleaning cycle. The mathematical model is presented which includes the solution of a system of chemical equilibrium equations for reactions in the solution, material balances, and electrical neutrality. 4 references, 5 figures, 1 table.

Nazarov, V.G.; Kamennykh, B.M.; Rus'yanov, N.D.

1983-01-01T23:59:59.000Z

44

Trends in the automation of coke production  

SciTech Connect

Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

45

Financial Analysis for Developing CDM Project in the Coke Plant  

Science Conference Proceedings (OSTI)

In the coke plant, the traditional coke wet quenching method is to be used to cool down the red hot coke and waste heat is released to the atmosphere in China. There are a lot of smog, particles, cyanide, sulphide and etc. mixtures within the waste heat. ... Keywords: CDQ technology, CO2 emission reductions, financial analysis, potential calculation, recycle sustainable development

Ma Xiuqin; Huang Chao; Wu Guoning

2009-05-01T23:59:59.000Z

46

Coke | OpenEI  

Open Energy Info (EERE)

18 18 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142278418 Varnish cache server Coke Dataset Summary Description UK National coal (and solid fuels and gases derived from processing coal) are published in Chapter 2 (Solid Fuels and Derived Gases) of the Digest of UK Energy Statistics (DUKES). Included here are the datasets for commodity balances (1998 - 2009); supply and consumption (2005 - 2009) of coal and other fuels (e.g. coke oven gas, blast furnace gas, benzole and tars, etc). Chapter 2 of the report is available: http://www.decc.gov.uk/assets/decc/Statistics/publications/dukes/308-dukes-2010-ch2.pdf Source UK Department of Energy and Climate Change (DECC)

47

Clean Production of Coke from Carbonaceous Fines  

Science Conference Proceedings (OSTI)

In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

Craig N. Eatough

2004-11-16T23:59:59.000Z

48

Determination of electrical resistivity of dry coke beds  

SciTech Connect

The electrical resistivity of the coke bed is of great importance when producing FeMn, SiMn, and FeCr in a submerged arc furnace. In these processes, a coke bed is situated below and around the electrode tip and consists of metallurgical coke, slag, gas, and metal droplets. Since the basic mechanisms determining the electrical resistivity of a coke bed is not yet fully understood, this investigation is focused on the resistivity of dry coke beds consisting of different carbonaceous materials, i.e., coke beds containing no slag or metal. A method that reliably compares the electrical bulk resistivity of different metallurgical cokes at 1500{sup o} C to 1600{sup o}C is developed. The apparatus is dimensioned for industrial sized materials, and the electrical resistivity of anthracite, charcoal, petroleum coke, and metallurgical coke has been measured. The resistivity at high temperatures of the Magnitogorsk coke, which has the highest resistivity of the metallurgical cokes investigated, is twice the resistivity of the Corus coke, which has the lowest electrical resistivity. Zdzieszowice and SSAB coke sort in between with decreasing resistivities in the respective order. The electrical resistivity of anthracite, charcoal, and petroleum coke is generally higher than the resistivity of the metallurgical cokes, ranging from about two to about eight times the resistivity of the Corus coke at 1450{sup o}C. The general trend is that the bulk resistivity of carbon materials decreases with increasing temperature and increasing particle size.

Eidem, P.A.; Tangstad, M.; Bakken, J.A. [NTNU, Trondheim (Norway)

2008-02-15T23:59:59.000Z

49

Petroleum Coke VBD  

Science Conference Proceedings (OSTI)

Mar 1, 2011 ... Electrode Technology for Aluminium Production: Petroleum Coke VBD ... of Calcined Petroleum Coke: Jignesh Panchal1; Mark Wyborney1; ...

50

Sectoral trends in global energy use and greenhouse gas emissions  

E-Print Network (OSTI)

factors for production of coal products -- patent fuel, cokeoven coke,coke oven gas, blast furnace gas and briquettes (BKB) --

2006-01-01T23:59:59.000Z

51

Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs  

E-Print Network (OSTI)

United States crude slate is becoming heavier and generally higher in sulfur. At the same time demand of distillate products is increasing. Refiners are reworking their plans to include resid conversion via coking and approximately 230,000 BPD of new coking capacity is either under construction or announced. Even if 50 percent of the coke produced is exported, there will be an excess capacity of coke selling at less than $30/ton depending upon the sulfur content. This coke can be gasified effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per million Btu in 1990. The paper will discuss three gasifiers - Gesellschaft fur Kohle-Technologie Gmbh (GKT), Texaco and Westinghouse which may be used for the production of medium-Btu gas from coke. The design parameters, which for coke gasification may be different from coal gasification because of the difference in physical and chemical characteristics of coke and coal, will be evaluated. Conceptual design will be performed based upon normal fuel requirements of about 20 billion Btu per day for a typical 50,000 BPD refinery. Adaptability of coke derived gas to refinery fuel systems will be discussed in terms of flame temperatures, flue gas volumes, derating and required furnace modifications. Estimates of capital and operating costs will be obtained to calculate the gas cost using the new tax laws. Finally, the GKT gasifier will be compared to the developing Texaco and Westinghouse gasifiers to assess the effect of second generation gasifiers on the economics of coke gasification.

Patel, S. S.

1982-01-01T23:59:59.000Z

52

Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 3, January 1, 1991--December 31, 1991  

Science Conference Proceedings (OSTI)

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

Not Available

1992-10-16T23:59:59.000Z

53

Greenhouse gas emissions, waste and recycling policy Kaylee Acuff  

E-Print Network (OSTI)

Greenhouse gas emissions, waste and recycling policy Kaylee Acuff and Daniel T. Kaffine We thank@mines.edu.) 1 #12;Greenhouse gas emissions, waste and recycling policy Abstract This paper examines least-cost policies for waste reduction, incorporating upstream greenhouse gas externalities associated

54

Fundamentals of Delayed Coking Joint Industry Project  

Science Conference Proceedings (OSTI)

The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

2003-02-07T23:59:59.000Z

55

Economical Desulfurization of Petroleum Coke  

Science Conference Proceedings (OSTI)

Presentation Title, Economical Desulfurization of Petroleum Coke ... " Desulfurization of Petroleum Coke Beyond 1600'C" by Christopher A. Paul of Great Lakes ...

56

GTZ-Greenhouse Gas Calculator for Waste Management | Open Energy  

Open Energy Info (EERE)

GTZ-Greenhouse Gas Calculator for Waste Management GTZ-Greenhouse Gas Calculator for Waste Management Jump to: navigation, search Tool Summary Name: GTZ-Greenhouse Gas Calculator for Waste Management Agency/Company /Organization: GTZ Sector: Energy Website: www.gtz.de/en/themen/umwelt-infrastruktur/abfall/30026.htm References: GHG Calculator for Waste Management[1] Waste Management - GTZ Website[2] Logo: GTZ-Greenhouse Gas Calculator for Waste Management The necessity to reduce greenhouse gases and thus mitigate climate change is accepted worldwide. Especially in low- and middle-income countries, waste management causes a great part of the national greenhouse gas production, because landfills produce methane which has a particularly strong effect on climate change. Therefore, it is essential to minimize

57

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect

Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

Michael Volk; Keith Wisecarver

2003-09-26T23:59:59.000Z

58

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect

Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

Michael Volk; Keith Wisecarver

2004-09-26T23:59:59.000Z

59

Gas generation results and venting study for transuranic waste drums  

DOE Green Energy (OSTI)

Sixteen waste drums, containing six categories of plutonium-contaminated waste, were monitored for venting and gas generation for six months. The venting devices tested appeared adequate to relieve pressure and prevent hydrogen accumulation. Most of the gas generation, primarily H2 and CO2, was due to radiolytic decomposition of the hydrogenous wastes. Comparison of the gas yields with those obtained previously in laboratory tests showed very reasonable agreement with few exceptions.

Kazanjian, A.R.; Arnold, P.M.; Simmons, W.C.; D'Amico, E.L.

1985-09-23T23:59:59.000Z

60

Development Of Reclamation Substrates For Alberta Oil Sands Using Mature Fine Tailings And Coke.  

E-Print Network (OSTI)

??Mature fine tailings and coke are waste products of the oil sands industry with potential for reclamation. A greenhouse study assessed whether substrates of various… (more)

Luna-Wolter, Gabriela L.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Water-Gas Shift Membrane Reactor Studies  

E-Print Network (OSTI)

Coal, Petroleum coke, Biomass, Waste, etc. Gasifier Particulate Removal Air Separator Oxygen Air Steam

62

"Code(a)","End Use","Electricity(b)","Fuel Oil","Diesel Fuel(c)"," Gas(d)","NGL(e)","Coke and Breeze)"  

U.S. Energy Information Administration (EIA) Indexed Site

3 Relative Standard Errors for Table 5.3;" 3 Relative Standard Errors for Table 5.3;" " Unit: Percents." " "," " " "," ",," ","Distillate"," "," " " "," ","Net Demand",,"Fuel Oil",,,"Coal" "NAICS"," ","for ","Residual","and","Natural","LPG and","(excluding Coal" "Code(a)","End Use","Electricity(b)","Fuel Oil","Diesel Fuel(c)"," Gas(d)","NGL(e)","Coke and Breeze)" ,,"Total United States" " 311 - 339","ALL MANUFACTURING INDUSTRIES" ,"TOTAL FUEL CONSUMPTION",2,3,6,2,4,9

63

Slurry growth and gas retention in synthetic Hanford waste  

DOE Green Energy (OSTI)

This work seeks to establish chemical and physical processes responsible for the generation and retention of gases within waste from a particular high-level waste tank on the Hanford Site, Tank 101-SY, through the use of synthetic wastes on a laboratory scale. The goal of these activities is to support the development of mitigation/remediation strategies for Tank 101-SY. Laboratory studies of aged synthetic waste have shown that gas generation occurs thermally at a significant level at current tank temperatures. Gas compositions include the same gases produced in actual tank waste, primarily N{sub 2}, N{sub 2}O, and H{sub 2}. Gas stoichiometries have been shown to be greatly influenced by several organic and inorganic constituents within the synthetic waste. Retention of gases in the synthetic waste is in the form of bubble attachment to solid particles.

Bryan, S.A.; Pederson, L.R.; Scheele, R.D.

1992-09-01T23:59:59.000Z

64

Slurry growth and gas retention in synthetic Hanford waste  

DOE Green Energy (OSTI)

This work seeks to establish chemical and physical processes responsible for the generation and retention of gases within waste from a particular high-level waste tank on the Hanford Site, Tank 101-SY, through the use of synthetic wastes on a laboratory scale. The goal of these activities is to support the development of mitigation/remediation strategies for Tank 101-SY. Laboratory studies of aged synthetic waste have shown that gas generation occurs thermally at a significant level at current tank temperatures. Gas compositions include the same gases produced in actual tank waste, primarily N[sub 2], N[sub 2]O, and H[sub 2]. Gas stoichiometries have been shown to be greatly influenced by several organic and inorganic constituents within the synthetic waste. Retention of gases in the synthetic waste is in the form of bubble attachment to solid particles.

Bryan, S.A.; Pederson, L.R.; Scheele, R.D.

1992-09-01T23:59:59.000Z

65

Gas generation from Tank 241-SY-103 waste  

DOE Green Energy (OSTI)

This report summarizes progress made in evaluating mechanisms by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using actual waste from Tank 241-SY-103. The objective of this work is to establish the identity and stoichiometry of degradation products formed in actual tank wastes by thermal and radiolytic processes as a function of temperature. The focus of the gas generation tests on Tank 241-SY-103 samples is first the effect of temperature on gas generation (volume and composition). Secondly, gas generation from irradiation of Tank 241-SY-103 samples at the corresponding temperatures as the thermal-only treatments will be measured in the presence of an external radiation source (using a {sup 137}Cs capsule). The organic content will be measured on a representative sample prior to gas generation experiments and again at the termination of heating and irradiation. The gas generation will be related to the extent of organic species consumption during heating. Described in this report are experimental methods used for producing and measuring gases generated at various temperatures from highly radioactive actual tank waste, and results of gas generation from Tank 241-SY-103 waste taken from its convective layer. The accurate measurement of gas generation rates from actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from the convective layer of Tank 241-SY-103, a waste tank listed on the Flammable Gas Watch List due to its potential for flammable gas accumulation above the flammability limit.

Bryan, S.A.; King, C.M.; Pederson, L.R.; Forbes, S.V.; Sell, R.L.

1996-04-01T23:59:59.000Z

66

Radiolytic gas generation from cement-based waste hosts for DOE low-level radioactive wastes  

DOE Green Energy (OSTI)

Using cement-based immobilization binders with simulated radioactive waste containing sulfate, nitrate, nitrite, phosphate, and fluoride anions, the gamma- and alpha-radiolytic gas generation factors (G/sub t/, molecules/100 eV) and gas compositions were measured on specimens of cured grouts. These tests studied the effects of; (1) waste composition; (2) the sample surface-to-volume ratio; (3) the waste slurry particle size; and (4) the water content of the waste host formula. The radiolysis test vessels were designed to minimize the ''dead'' volume and to simulate the configuration of waste packages.

Dole, L.R.; Friedman, H.A.

1986-01-01T23:59:59.000Z

67

Definition: Coke | Open Energy Information  

Open Energy Info (EERE)

Coke A solid carbonaceous residue derived from low-ash, low-sulfur bituminous coal; used as a fuel and a reducing agent in smelting iron ore in a blast furnace. Coke from...

68

Met coke world summit 2005  

SciTech Connect

Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

NONE

2005-07-01T23:59:59.000Z

69

System for recovering methane gas from liquid waste  

SciTech Connect

A system for and method of recovering methane gas from liquid waste which is stored within a pit is disclosed herein. The methane gas is produced by causing the liquid waste to undergo anaerobic fermentation. Therefore, it is necessary to close the pit in an air tight fashion. This is carried out using a cover sheet which is fixedly disposed over the pit in an air tight but readily disengagable fashion. The liquid waste within this air tight pit is preferably agitated intermittently during its storage therein whereby to increase the amount of methane gas produced.

Grabis, D.W.

1983-07-19T23:59:59.000Z

70

Coking and gasification process  

DOE Patents (OSTI)

An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

1986-01-01T23:59:59.000Z

71

CARBON TECHNOLOGY: I: Petroleum Coke  

Science Conference Proceedings (OSTI)

CARBON TECHNOLOGY: Session I: Petroleum Coke. Sponsored by: LMD Aluminum Committee Program Organizer: Jean-Claude Thomas , Aluminium ...

72

Investigating factors that influence carbon dissolution from Coke into Molten iron.  

E-Print Network (OSTI)

??The need for more efficient blast furnaces is even greater now that there are stricter environmental regulations on greenhouse gas (GHG) emissions. Coke within the… (more)

Cham, S. Tsuey

2007-01-01T23:59:59.000Z

73

TRU Waste Sampling Program: Volume II. Gas generation studies  

DOE Green Energy (OSTI)

Volume II of the TRU Waste Sampling Program report contains the data generated from evaluating the adequacy of venting/filtering devices for maintaining safe hydrogen levels in plutonium contaminated waste drums. Additional studies reported in this volume include gas generation rates, selected waste form monitoring, and evaluation of hydrogen migration from sealed 90-mil rigid polyethylene drum liners containing /sup 238/Pu-contaminated wastes. All wastes used in the studies were newly-generated, and the waste drums were under controlled, experimental conditions. Studies using /sup 239/Pu-contaminated wastes were conducted at the Rocky Flats Plant. Studies using /sup 238/Pu-contaminated wastes were conducted at the Los Alamos National Laboratory.

Clements, T.L. Jr.; Kudera, D.E.

1985-09-01T23:59:59.000Z

74

Control of waste gas from a thermal EOR operation  

SciTech Connect

This paper summarizes a waste-gas treatment system designed to control emissions from thermal EOR wells. This case study discusses the need, design, installation, and operation of the system.

Peavy, M.A.; Braun, J.E. (Oryx Energy Co. (US))

1991-06-01T23:59:59.000Z

75

Study of physical properties, gas generation and gas retention in simulated Hanford waste  

DOE Green Energy (OSTI)

The purpose of this study was to establish the chemical and physical processes responsible for the generation and retention of gases within high-level waste from Tank 101-SY on the Hanford Site. This research, conducted using simulated waste on a laboratory scale, supports the development of mitigation/remediation strategies for Tank 101-SY. Simulated waste formulations are based on actual waste compositions. Selected physical properties of the simulated waste are compared to properties of actual Tank 101-SY waste samples. Laboratory studies using aged simulated waste show that significant gas generation occurs thermally at current tank temperatures ({approximately}60{degrees}C). Gas compositions include the same gases produced in actual tank waste, primarily N{sub 2}, N{sub 2}O, and H{sub 2}. Gas stoichiometries have been shown to be greatly influenced by several organic and inorganic constituents within the simulated waste. Retention of gases in the simulated waste is in the form of bubble attachment to solid particles. This attachment phenomenon is related to the presence of organic constituents (HEDTA, EDTA, and citrate) of the simulated waste. A mechanism is discussed that relates the gas bubble/particle interactions to the partially hydrophobic surface produced on the solids by the organic constituents.

Bryan, S.A.; Pederson, L.R.; Scheele, R.D.

1993-04-01T23:59:59.000Z

76

Assessment of Fuel Gas Cleanup Systems for Waste Gas Fueled Power Generation  

Science Conference Proceedings (OSTI)

There are many industrial operations that have waste gas streams that are combustible. Chief among these is biogas produced by anaerobic digestion of organic wastes to produce a methane-rich biogas in landfills and anaerobic digesters. These gas streams are increasingly being used to fuel local power generators. The biogas streams, however, contain traces of a wide variety of contaminants. Removal of these contaminants may be required to either meet the manufacturer's requirements for fuel gas quality to...

2006-12-21T23:59:59.000Z

77

Radiogenic gas accumulation in TRU waste storage drums  

DOE Green Energy (OSTI)

A field experiment was conducted over a four-year time span to determine the effect of high-activity transuranic (TRU) waste on the atmosphere within TRU waste storage drums typical of those generated in Savannah River Plant operation. Routine gas composition analyses showed that a significant amount of hydrogen can accumulate in drums that contain high alpha activity, and that flammable gas mixtures could form in such drums in spite of the radiolytic consumption of oxygen. According to this study, gas pressure accumulation does not pose a threat to the integrity of the TRU waste containers that are now being stored at the Savannah River Plant. Therefore, the 20-year storage criterion is still viable. However, the continued avoidance of a perfectly gas-tight drum seal (e.g., epoxy, metal welding) is recommended. The test drums will continue to be monitored.

Ryan, J.P.

1982-01-01T23:59:59.000Z

78

Priorities in the design of chemical shops at coke plants  

SciTech Connect

Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

79

Influence of Coke Calcining Parameters on Petroleum Coke ... - TMS  

Science Conference Proceedings (OSTI)

Jan 1, 1985 ... TMS Student Member price: 0.00. Product In Stock. Description All physical and chemical properties of petroleum coke are determined by three ...

80

Design and construction of coke battery 1A at Radlin coke plant, Poland  

Science Conference Proceedings (OSTI)

In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Integration of stripping of fines slurry in a coking and gasification process  

DOE Patents (OSTI)

In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

DeGeorge, Charles W. (Chester, NJ)

1980-01-01T23:59:59.000Z

82

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect

Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

Michael Volk Jr; Keith Wisecarver

2005-10-01T23:59:59.000Z

83

Radiolytic gas production from concrete containing Savannah River Plant waste  

DOE Green Energy (OSTI)

To determine the extent of gas production from radiolysis of concrete containing radioactive Savannah River Plant waste, samples of concrete and simulated waste were irradiated by /sup 60/Co gamma rays and /sup 244/Cm alpha particles. Gamma radiolysis simulated radiolysis by beta particles from fission products in the waste. Alpha radiolysis indicated the effect of alpha particles from transuranic isotopes in the waste. With gamma radiolysis, hydrogen was the only significant product; hydrogen reached a steady-state pressure that increased with increasing radiation intensity. Hydrogen was produced faster, and a higher steady-state pressure resulted when an organic set retarder was present. Oxygen that was sealed with the wastes was depleted. Gamma radiolysis also produced nitrous oxide gas when nitrate or nitrite was present in the concrete. With alpha radiolysis, hydrogen and oxygen were produced. Hydrogen did not reach a steady-state pressure at <140 psi. From these results, estimates of pressure in conceptual containers (cylinders 2 feet ID by 10 feet tall, 90% full) of SRP waste concrete were made. During the first 300 years of storage when radiolysis will mainly be from beta-gamma radiation (from /sup 137/Cs and /sup 90/Sr), hydrogen will reach a steady-state pressure of 8 to 28 psi, and oxygen will be partially consumed. These predictions were confirmed by measurement of gas produced over a short time in a container of concrete and actual SRP waste. The tests with simulated waste also indicated that nitrous oxide may form, but because of the low nitrate or nitrite content of the waste, the maximum pressure of nitrous oxide after 300 years will be <60 psi. After decay of these fission products, alpha radiolysis from /sup 238/Pu and /sup 239/Pu will predominate; the hydrogen and oxygen pressures will increase to >200 psi.

Bibler, N.E.

1978-01-01T23:59:59.000Z

84

Effects of Globally Waste Disturbing Activities on Gas Generation, Retention, and Release in Hanford Waste Tanks  

SciTech Connect

Various operations are authorized in Hanford single- and double-shell tanks that disturb all or a large fraction of the waste. These globally waste-disturbing activities have the potential to release a large fraction of the retained flammable gas and to affect future gas generation, retention, and release behavior. This report presents analyses of the expected flammable gas release mechanisms and the potential release rates and volumes resulting from these activities. The background of the flammable gas safety issue at Hanford is summarized, as is the current understanding of gas generation, retention, and release phenomena. Considerations for gas monitoring and assessment of the potential for changes in tank classification and steady-state flammability are given.

Stewart, Charles W.; Fountain, Matthew S.; Huckaby, James L.; Mahoney, Lenna A.; Meyer, Perry A.; Wells, Beric E.

2005-08-02T23:59:59.000Z

85

Factors influencing coke gasification with carbon dioxide.  

E-Print Network (OSTI)

??Of all coke properties the influence of the catalytic mineral matter on reactivity of metallurgical cokes is least understood. There is limited information about the… (more)

Grigore, Mihaela

2007-01-01T23:59:59.000Z

86

Slurry growth, gas retention, and flammable gas generation by Hanford radioactive waste tanks: Synthetic waste studies, FY 1991  

DOE Green Energy (OSTI)

Of 177 high-level waste storage tanks on the Hanford Site, 23 have been placed on a safety watch list because they are suspected of producing flammable gases in flammable or explosive concentrate. One tankin particular, Tank 241-SY-101 (Tank 101-SY), has exhibited slow increases in waste volume followed by a rapid decrease accompanied by venting of large quantities of gases. The purpose of this study is to help determine the processes by which flammable gases are produced, retained, and eventually released from Tank 101-SY. Waste composition data for single- and double-shell waste tanks on the flammable gas watch listare critically reviewed. The results of laboratory studies using synthetic double-shell wastes are summarized, including physical and chemical properties of crusts that are formed, the stoichiometry and rate ofgas generation, and mechanisms responsible for formation of a floating crust.

Bryan, S.A.; Pederson, L.R.; Ryan, J.L.; Scheele, R.D.; Tingey, J.M.

1992-08-01T23:59:59.000Z

87

Coke from coal and petroleum  

DOE Patents (OSTI)

A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

1981-01-01T23:59:59.000Z

88

Converting Petroleum Coke to Electricity  

E-Print Network (OSTI)

Changes in oil refining technology and economics are driving refiners to utilize thermal processes to maximize the conversion of heavy crude oil components to clean products. Since the primary unit operation to accomplish this objective is the coking unit, more cokers are being built, and existing cokers are being operated to maximum capacity utilization. SRI recently completed an assignment for a refiner interested in converting the by-product fluid coke from his unit to electricity. This paper presents the operating history of US based plants converting petroleum coke to electricity, and presents generic economics for the conversion process utilizing three primary technologies available: conventional pulverized coke combustion, atmospheric fluidized bed combustion, and coke gasification combined cycle power production.

Pavone, A.

1992-04-01T23:59:59.000Z

89

Definition: Petroleum coke | Open Energy Information  

Open Energy Info (EERE)

coke coke Jump to: navigation, search Dictionary.png Petroleum coke A residue high in carbon content and low in hydrogen that is the final product of thermal decomposition in the condensation process in cracking (breaking of carbon-carbon bonds). This product is reported as marketable coke or catalyst coke.Coke from petroleum has a heating value of 6.024 million Btu per barrel.[1] View on Wikipedia Wikipedia Definition Petroleum coke (often abbreviated Pet coke or petcoke) is a carbonaceous solid derived from oil refinery coker units or other cracking processes. Other coke has traditionally been derived from coal. This coke can either be fuel grade (high in sulphur and metals) or anode grade (low in sulphur and metals). The raw coke directly out of the coker is often

90

Georgia Refinery Marketable Petroleum Coke Production Capacity ...  

U.S. Energy Information Administration (EIA)

Georgia Refinery Marketable Petroleum Coke Production Capacity as of January 1 (Barrels per Stream Day)

91

Minnesota Refinery Marketable Petroleum Coke Production ...  

U.S. Energy Information Administration (EIA)

Minnesota Refinery Marketable Petroleum Coke Production Capacity as of January 1 (Barrels per Stream Day)

92

Effects of oxygen cover gas and NaOH dilution on gas generation in tank 241-SY-101 waste  

DOE Green Energy (OSTI)

Laboratory studies are reported of gas generation in heated waste from tank 241-SY-101. The rates of gas generation and the compositions of product gas were measured. Three types of tests are compared. The tests use: undiluted waste, waste diluted by a 54% addition of 2.5 M NaOH, and undiluted waste with a reactive cover gas of 30% Oxygen in He. The gas generation rate is reduced by dilution, increased by higher temperatures (which determines activation energies), and increased by reactions of Oxygen (these primarily produce H{sub 2}). Gases are generated as reduction products oxidation of organic carbon species by nitrite and oxygen.

Person, J.C.

1996-05-30T23:59:59.000Z

93

Flammable gas tank waste level reconciliation for 241-S-111  

SciTech Connect

Fluor Daniel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 241-S-111. The trapped gas evaluation document states that Tank S-111 exceeds the 25% of the lower flammable-limit criterion, based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the Welty Report is the basis for this letter report. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unaccounted for surface level rise. From 1973 through 1980, the Welty Report tracked Tank S-111 transfers. This surface level increase is from an unknown source or is unaccounted for. Duke Engineering and Services Hanford and Lockheed Martin Hanford Corporation are interested in determining the validity of the unexplained surface level changes reported in the Welty Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unaccounted for surface level changes as shown in the Welty Report from 1973 through 1980. Tank S-111 initially received waste from REDOX in 1952, and after April 1974, primarily received processed waste slurry from the 242-S Evaporator/Crystallizer and transferred supernatant waste to Tank S-102. From the FDNW review and comparisons of the Welty Report versus other daily records for Tank S-111, FDNW determined that the majority of the time, the Welty Report is consistent with daily records. Surface level decreases that occurred following saltwell pumping were identified as unaccounted for decreases in the Welty Report, however they were probably a continued settlement caused by saltwell pumping of the interstitial liquids. Because the flammable/trapped gas issue is linked to the unexplained increase in the surface level, FDNW recommends that all occurrence reports, concerning tank waste level increases or decreases from 1970 through 1980, be reevaluated for acceptability of the evaluation as to the root cause of the occurrence.

Brevick, C.H.; Gaddis, L.A.

1997-06-23T23:59:59.000Z

94

Radiolytic gas generation in plutonium contaminated waste materials  

DOE Green Energy (OSTI)

Many plutonium contaminated waste materials decompose into gaseous products because of exposure to alpha radiation. The gases generated (usually hydrogen) over long-storage periods may create hazardous conditions. To determine the extent of such hazards, knowing the gas generation yields is necessary. These yields were measured by contacting some common Rocky Flats Plant waste materials with plutonium and monitoring the enclosed atmospheres for extensive periods of time. The materials were Plexiglas, polyvinyl chloride, glove-box gloves, machining oil, carbon tetrachloride, chlorothene VG solvent, Kimwipes (dry and wet), polyethylene, Dowex-1 resin, and surgeon's gloves. Both /sup 239/Pu oxide and /sup 238/Pu oxide were used as radiation sources. The gas analyses were made by mass spectrometry and the results obtained were the total gas generation, the hydrogen generation, the oxygen consumption rate, and the gas composition over the entire storage period. Hydrogen was the major gas produced in most of the materials. The total gas yields varied from 0.71 to 16 cm/sup 3/ (standard temperature pressure) per day per curie of plutonium. The oxygen consumption rates varied from 0.0088 to 0.070 millimoles per day per gram of plutonium oxide-239 and from 0.0014 to 0.0051 millimoles per day per milligram /sup 238/Pu.

Kazanjian, A.R.

1976-10-29T23:59:59.000Z

95

Flammable gas tank waste level reconcilliation for 241-SX-102  

SciTech Connect

Fluoro Dynel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 24 1-S-1 1 1 (S-I 1 1, typical). The trapped gas evaluation document (ref 1) states that Tank SX-102 exceeds the 25% of the lower flammable limit (FL) criterion (ref 2), based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the ``Wallet Report`` is the basis for this letter report (ref 3). The Wallet Report is also a part of the trapped gas evaluation document criteria. The Wallet Report contains various tank information, including: physical information, status, levels, and dry wells, see Appendix A. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unacquainted for surface level rise. From 1973 through 1980, the Wallet Report tracked Tank S- 102 transfers and reported a net cumulative change of 19.95 in. This surface level increase is from an unknown source or is unacquainted for. Duke Engineering and Services Hanford (DASH) and Leached Martin Hanford Corporation (LMHC) are interested in determining the validity of the unexplained surface level changes reported in the 0611e Wallet Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unacquainted for surface level changes as shown in the Wallet Report from 1973 through 1980.

Brevick, C.H.; Gaddie, L.A.

1997-06-23T23:59:59.000Z

96

Coping with the Decline in Coke Quality – Using Onsite Blending ...  

Science Conference Proceedings (OSTI)

... coke (CPC), the blending of non-traditional cokes (NTAC's) has increased. ... Prebaked Anode from Coal - Utilization of Coal Extract as a Coke Feedstock-.

97

New coke-sorting system at OAO Koks  

SciTech Connect

A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

98

Experimental study of elastoplastic mechanical properties of coke drum materials.  

E-Print Network (OSTI)

??Coke drums are vertical pressure vessels used in the delayed coking process in petroleum refineries. Significant temperature variation during the delayed coking process causes the… (more)

Chen, Jie

2010-01-01T23:59:59.000Z

99

Estimating Coke and Pepsi's Price and Advertising Strategies  

E-Print Network (OSTI)

Strategy Distributions for Coke (First Quarter 1977) a)Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISINGEconomics July, 1998 Estimating Coke and Pepsi’s Price and

Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

1998-01-01T23:59:59.000Z

100

Prediction of Calcined Coke Bulk Density - Programmaster.org  

Science Conference Proceedings (OSTI)

Due to changing green coke quality, a reliable forecast of the calcined coke VBD from small green coke samples is required. The VBD can be predicted from ...

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Estimating retained gas volumes in the Hanford tanks using waste level measurements  

SciTech Connect

The Hanford site is home to 177 large, underground nuclear waste storage tanks. Safety and environmental concerns surround these tanks and their contents. One such concern is the propensity for the waste in these tanks to generate and trap flammable gases. This report focuses on understanding and improving the quality of retained gas volume estimates derived from tank waste level measurements. While direct measurements of gas volume are available for a small number of the Hanford tanks, the increasingly wide availability of tank waste level measurements provides an opportunity for less expensive (than direct gas volume measurement) assessment of gas hazard for the Hanford tanks. Retained gas in the tank waste is inferred from level measurements -- either long-term increase in the tank waste level, or fluctuations in tank waste level with atmospheric pressure changes. This report concentrates on the latter phenomena. As atmospheric pressure increases, the pressure on the gas in the tank waste increases, resulting in a level decrease (as long as the tank waste is {open_quotes}soft{close_quotes} enough). Tanks with waste levels exhibiting fluctuations inversely correlated with atmospheric pressure fluctuations were catalogued in an earlier study. Additionally, models incorporating ideal-gas law behavior and waste material properties have been proposed. These models explicitly relate the retained gas volume in the tank with the magnitude of the waste level fluctuations, dL/dP. This report describes how these models compare with the tank waste level measurements.

Whitney, P.D.; Chen, G.; Gauglitz, P.A.; Meyer, P.A.; Miller, N.E.

1997-09-01T23:59:59.000Z

102

Bethlehem Steel announces plans to control coke oven air and water pollution  

Science Conference Proceedings (OSTI)

Bethlehem Steel Corporation and the Maryland Department of the Environment have announced an agreement under which Bethlehem will spend an estimated $92-million at its Sparrows Points, Md., plant for technologically-advanced controls to further reduce air and water pollution, mainly from the plant's coke ovens. The two major systems include one to treat by-product coke oven gas and chemicals, and another to upgrade existing pushing emission controls on two older coke oven batteries. One of the new systems will replace most of the existing equipment that cleans gas and treats chemicals created by the coking process at the plant's three coke oven batteries. Because this system has the potential to greatly reduce sulfur dioxide and other pollutants, the United States Department of Energy (DOE) in September announced that its installation qualified for funding as part of the nationwide Innovative Clean Coal Technology Program.

Not Available

1989-08-01T23:59:59.000Z

103

Process for converting coal into liquid fuel and metallurgical coke  

DOE Patents (OSTI)

A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

1994-01-01T23:59:59.000Z

104

Coke quality for blast furnaces with coal-dust fuel  

SciTech Connect

Recently, plans have been developed for the introduction of pulverized coal injection (PCI) at various Russian metallurgical enterprises. The main incentive for switching to PCI is the recent price rises for Russian natural gas. The paper discusses the quality of coke for PCI into blast furnaces.

Y.A. Zolotukhin; N.S. Andreichikov [Eastern Coal-Chemistry Institute, Yekaterinburg (Russian Federation)

2009-07-01T23:59:59.000Z

105

Coke gasification costs, economics, and commercial applications  

Science Conference Proceedings (OSTI)

The disposition of petroleum coke remains a problem for modern high conversion refineries. Market uncertainty and the price for coke can prevent the implementation of otherwise attractive projects. The commercially proven Texaco Gasification Process remains an excellent option for clean, cost effective coke disposition as demonstrated by the new coke gasification units coming on-line and under design. Previous papers, have discussed the coke market and general economics of coke gasification. This paper updates the current market situation and economics, and provide more details on cost and performance based on recent studies for commercial plants.

Jahnke, F.C.; Falsetti, J.S.; Wilson, R.F. [Texaco, Inc., White Plains, NY (United States)

1996-12-01T23:59:59.000Z

106

Thermal and radiolytic gas generation from Tank 241-S-102 waste  

SciTech Connect

This report summarizes progress in evaluating thermal and radiolytic rate parameters for flammable gas generation in Hanford single-shell tank wastes based on the results of laboratory tests using actual waste from Tank 241-S-102 (S-102). Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support Fluor Daniel Hanford (FDH) and its Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT) under subcontract to PNNL, using simulated wastes, and to studies being performed at Numatec Hanford Corporation (formerly Westinghouse Hanford Company) using actual wastes. The results of gas generation from Tank S-102 waste under thermal and radiolytic conditions are described in this report. The accurate measurement of gas generation rates in actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from Tank S-102, a waste tank listed as high priority by the Flammable Gas Safety Program due to its potential for flammable gas accumulation above the flammability limit.

King, C.M.; Pederson, L.R.; Bryan, S.A.

1997-07-01T23:59:59.000Z

107

U.S. Imports of Petroleum Coke Marketable (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

Marketable Petroleum Coke Supply and Disposition; Petroleum Coke Imports from All Countries; U.S. Imports from All Countries ...

108

Advanced Green Petroleum Coke Calcination In Electrothermal ...  

Science Conference Proceedings (OSTI)

Symposium, Fluidization Technologies for the Mineral, Materials, and Energy Industries. Presentation Title, Advanced Green Petroleum Coke Calcination In ...

109

Evolved Gas Analysis for High-alumina HLW (High Level Waste) Feed  

Science Conference Proceedings (OSTI)

Using the thermogravimetry coupled with gas chromatography-mass spectrometer, ... Tungstic Acid for Sorption of Uranium from Natural and Waste Waters and ...

110

Combination gas producing and waste-water disposal well  

DOE Patents (OSTI)

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Malinchak, Raymond M. (McKeesport, PA)

1984-01-01T23:59:59.000Z

111

Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 2, July 1, 1991--September 30, 1991  

SciTech Connect

The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental Monitoring includes sampling of 27 additional streams that are important to measure operational or environmental performance and impacts of the installation of the new COG treatment facilities.

Not Available

1992-09-21T23:59:59.000Z

112

Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil  

Science Conference Proceedings (OSTI)

In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

2009-05-15T23:59:59.000Z

113

WASTE CHARACTERIZATION OF POLYMERIC COMPONENTS EXPOSED TO TRITIUM GAS  

Science Conference Proceedings (OSTI)

A recent independent review led to uncertainty about the technical basis for characterizing the residual amount of tritium in polymer components used in the Savannah River Site Tritium Facilities that are sent for waste disposal. A review of a paper published in the open literature firmly establishes the basis of the currently used characterization, 10 Ci/cc. Information provided in that paper about exposure experiments performed at the DOE Mound Laboratory allows the calculation of the currently used characterization. These experiments involved exposure of high density polyethylene (HD-PE) to initially 1 atm tritium gas. In addition, a review of recent research at the Savannah River Site not only further substantiates this characterization, but also establishes its use for ultra-high molecular weight polyethylene (UHMW-PE), polytetrafluoroethylene (PTFE, a trade name is Teflon{reg_sign}), and Vespel{reg_sign} polyimide. 10 Ci/cc tritium is a representative characterization for any type of polymer components exposed at ambient temperature and at approximately 1 atm. tritium gas.

Clark, E

2008-02-15T23:59:59.000Z

114

Selecting the optimum coke pushing sequence  

SciTech Connect

The sequence of pushing coke ovens is one of the most important aspects of battery operation. The sequence must satisfy a number of technical and process conditions: (1) achieve maximum heating-wall life by avoiding destructive expansion pressure in freshly charged ovens and during pushing of the finished coke; (2) ensure uniform brickwork temperature and prevent overheating by compensating for the high thermal flux in freshly charged ovens due to accumulated heat in adjacent ovens that are in the second half of the coking cycle; (3) ensure the most favorable working conditions and safety for operating personnel; (4) provide additional opportunities for repair personnel to perform various types of work, such as replacing coke-machine rails, without interrupting coal production; (5) perform the maximum number of coke-machine operations simultaneously: pushing, charging, and cleaning doors, frames, and standpipe elbows; and (6) reduce electricity consumption by minimizing idle travel of coke machines.

V.T. Krivoshein; A.V. Makarov [ZAO Trest Koksokhimmontazh (Russian Federation)

2007-01-15T23:59:59.000Z

115

Study of Modified Semi-Coke on the Advanced Treatment of Coking ...  

Science Conference Proceedings (OSTI)

Mass of absorbent and absorption time had put much on the removal rate of oil in coke wastewater. The removal rate of oil in coke wastewater could be above ...

116

Development of an advanced gas-fired mineral wool melter. Final report, October 1987-December 1990  

SciTech Connect

A gas-fired mineral wool melter was successfully designed and tested. The test results clearly show that the gas-fired melter offers significant advantages over the current state-of-the-art system, the coke-fired cupola. The primary benefits offered are: lower energy costs, fewer airborne pollutant emissions, virtual elimination of solid waste generation and superior control and quality of the resultant melt stream. Specifically, the unit eliminates the emission of carbon monoxide, hydrogen sulfide and hydrocarbons. Emissions of SOx and particulate are substantially reduced as well. The generation of solid wastes is eliminated through the gas-fired melters ability to utilize untreated process wastes as a feedstock.

Vereecke, F.J.; Gardner, K.M.; Thekdi, A.C.; Swift, M.D.

1990-12-01T23:59:59.000Z

117

Cold End Inserts for Process Gas Waste Heat Boilers Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB)  

E-Print Network (OSTI)

Cold End Inserts for Process Gas Waste Heat Boilers Overview Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB) to cool process syngas. The gas enters satisfies all 3 design criteria. · Correlations relating our experimental results to a waste heat boiler

Demirel, Melik C.

118

Entrained Flow Gasification of Oil Sand Coke.  

E-Print Network (OSTI)

??The effect of blending woody biomass material with fluid coke and coal on the co-pyrolysis process was investigated in an entrained flow gasifier. The SEM… (more)

Vejahati, Farshid

2012-01-01T23:59:59.000Z

119

Characterization of Packing Ability of Coke Particles  

Science Conference Proceedings (OSTI)

VBD is conventionally used in anode industry to determine the required amount of pitch and fine coke. VBD may be achieved by dense particles while they do ...

120

Estimating Coke and Pepsi's price and advertising strategies  

E-Print Network (OSTI)

Working Paper No. 789 ESTIMATING COKE AND PEPSI’ PRICE S ANDand Advertising Strategies: Coke and Pepsi) by Amos Golan,Revised, March 1999 Estimating Coke and Pepsi’s Price and

Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Influence of the batch's coke-ore ratio and distribution on the porosity of the melting zone  

SciTech Connect

The variation in gas permeability in the melting zone is considered as a function of the height and configuration of the coke packing and the ore component of the batch.

V.P. Tarasov; L.V. Bykov; P.V. Tarasov [Priazovsk State Technical University, Mariupol (Ukraine)

2008-09-15T23:59:59.000Z

122

Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment  

SciTech Connect

Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost.

Nick Soelberg

2005-09-01T23:59:59.000Z

123

Evolution of Anode Grade Calcined Coke - Programmaster.org  

Science Conference Proceedings (OSTI)

The term "anode grade coke" has been used as a broad definition to describe delayed coke with a sponge structure containing relatively low levels of trace ...

124

Strength of the coke fillers of carbon materials  

Science Conference Proceedings (OSTI)

Relationships between the ultimate compression strengths of coke fillers for carbon materials determined by various techniques and structures, final coke treatment temperatures, etc., are considered.

V.S. Ostrovskii [Research Institute of Structural Graphite Materials, Moscow (Russian Federation)

2008-12-15T23:59:59.000Z

125

New designs in the reconstruction of coke-sorting systems  

Science Conference Proceedings (OSTI)

In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

126

Effect of Coke Particle Size on Sinter Quality  

Science Conference Proceedings (OSTI)

Abstract Scope, The effect of different Coke particle size on sinter quality has been investigated. Eight different coke particle sizes were chosen and sinter ...

127

Improving the Precision and Productivity of Green Coke VCM Analysis  

Science Conference Proceedings (OSTI)

Green cokes with high VCM (>12%) are more difficult to calcine and result in a higher porosity and lower bulk density in calcined coke. The paper will review ...

128

Observations on the Coke Air Reactivity Test - Programmaster.org  

Science Conference Proceedings (OSTI)

Coke air reactivities are strongly dependent on coke calcination levels and it is possible to drive air reactivities lower by increasing calcining temperatures.

129

Improved Hydrogen Gas Getters for TRU Waste -- Final Report  

DOE Green Energy (OSTI)

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB, characterized by the presence of carbon-carbon triple bonds. Carbon may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. In the presence of oxygen, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB has the needed binding rate and capacity for hydrogen that potentially could be generated in the TRUPACT II. Phases 1 and 2 of this project showed that uncoated DEB performed satisfactorily in lab scale tests. Based upon these results, Phase 3, the final project phase, included larger scale testing. Test vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and a payload of seven 55-gallon drums. The tests were run with an atmosphere of air for 63.9 days at ambient temperature (15-27°C) and a scaled hydrogen generation rate of 2.60E-07 moles per second (0.35 cc/min). A second type of getter known as VEI, a proprietary polymer hydrogen getter characterized by carbon-carbon double bonds, was also tested in Phase 3. Hydrogen was successfully “gettered” by both getter systems. Hydrogen concentrations remained below 5 vol% (in air) for the duration of the tests. However, catalytic reaction of hydrogen with carbon triple or double bonds in the getter materials did not take place. Instead, catalytic recombination was the predominant gettering mechanism in both getter materials as evidenced by (1) consumption of oxygen in the belljars, (2) production of free water in the belljars, and (3) absence of chemical changes in both getter materials as shown by nuclear magnetic resonance spectra.

Mark Stone; Michael Benson; Christopher Orme; Thomas Luther; Eric Peterson

2005-09-01T23:59:59.000Z

130

Scaled Testing of Hydrogen Gas Getters for Transuranic Waste  

SciTech Connect

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage and shipment containers. Hydrogen forms a flammable mixture with air over a wide range of concentrations (5% to 75%), and very low energy is needed to ignite hydrogen-air mixtures. For these reasons, the concentration of hydrogen in waste shipment containers (Transuranic Package Transporter-II or TRUPACT-II containers) needs to remain below the lower explosion limit of hydrogen in air (5 vol%). Accident scenarios and the resulting safety analysis require that this limit not be exceeded. The use of 'hydrogen getters' is being investigated as a way to prevent the build up of hydrogen in TRUPACT-II containers. Preferred getters are solid materials that scavenge hydrogen from the gas phase and chemically and irreversibly bind it into the solid state. In this study, two getter systems are evaluated: a) 1,4-bis (phenylethynyl)benzene or DEB, characterized by the presence of carbon-carbon triple bonds; and b) a proprietary polymer hydrogen getter, VEI or TruGetter, characterized by carbon-carbon double bonds. Carbon in both getter types may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. With oxygen present, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB and VEI performed satisfactorily in lab scale tests using small test volumes (ml-scale), high hydrogen generation rates, and short time spans of hours to days. The purpose of this study is to evaluate whether DEB and VEI perform satisfactorily in actual drum-scale tests with realistic hydrogen generation rates and time frames. The two getter systems were evaluated in test vessels comprised of a Gas Generation Test Program-style bell-jar and a drum equipped with a composite drum filter. The vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and volume of a payload of seven 55-gallon drums. The tests were conducted in an atmosphere of air for 60 days at ambient temperature (15 to 27 deg. C) and a scaled hydrogen generation rate of 2.60 E-07 moles hydrogen per second (0.35 cc/min). Hydrogen was successfully 'gettered' by both systems. Hydrogen concentrations remained below 5 vol% (in air) for the duration of the tests. However, catalytic reaction of hydrogen with carbon triple or double bonds in the getter materials did not take place. Instead, catalytic recombination was the predominant mechanism in both getters as evidenced by 1) consumption of oxygen in the bell-jars; 2) production of free water in the bell-jars; and 3) absence of chemical changes in both getters as shown by NMR spectra. (authors)

Kaszuba, J.; Mroz, E.; Haga, M.; Hollis, W. K. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico, 87545 (United States); Peterson, E.; Stone, M.; Orme, C.; Luther, T.; Benson, M. [Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-2208 (United States)

2006-07-01T23:59:59.000Z

131

Mechanism of physical transformations of mineral matter in the blast furnace coke with reference to its reactivity and strength  

SciTech Connect

Examinations of polished and dry cut sections of feed and tuyere coke revealed some possible mechanisms for the physical influence of mineral compounds on the reactivity and strength of coke. It was observed that rounded particles of mineral phases that are exposed to the pore walls and surface of coke at high temperature create an inorganic cover, thus reducing the surface available for gas-solid reactions. The particles of mineral matter that have a low melting point and viscosity can affect the coke at earlier stages in the blast furnace process, acting in the upper parts of the blast furnace (BF). The temperature-driven redistribution of mineral phases within the coke matrix probably leads to the creation of weak spots and in general to anisotropy in its properties, thus reducing its strength. 9 refs., 2 figs., 1 tab.

Stanislav S. Gornostayev; Jouko J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

2006-12-15T23:59:59.000Z

132

Framework for managing wastes from oil and gas exploration and production (E&P) sites.  

Science Conference Proceedings (OSTI)

Oil and gas companies operate in many countries around the world. Their exploration and production (E&P) operations generate many kinds of waste that must be carefully and appropriately managed. Some of these wastes are inherently part of the E&P process; examples are drilling wastes and produced water. Other wastes are generic industrial wastes that are not unique to E&P activities, such as painting wastes and scrap metal. Still other wastes are associated with the presence of workers at the site; these include trash, food waste, and laundry wash water. In some host countries, mature environmental regulatory programs are in place that provide for various waste management options on the basis of the characteristics of the wastes and the environmental settings of the sites. In other countries, the waste management requirements and authorized options are stringent, even though the infrastructure to meet the requirements may not be available yet. In some cases, regulations and/or waste management infrastructure do not exist at all. Companies operating in these countries can be confronted with limited and expensive waste management options.

Veil, J. A.; Puder, M. G.; Environmental Science Division

2007-09-15T23:59:59.000Z

133

Developing and Implementing a Company-Wide Waste Accounting System at Public Service Electric & Gas  

Science Conference Proceedings (OSTI)

Waste accounting systems will enable utilities to track their recycling, reuse, and prevention efforts. This manual describes the implementation of EPRI's waste accounting method in support of Public Service Electric & Gas Company's pollution prevention efforts. This method provided a means for organizing information from many facilities, transmitting regular performance reports to facility personnel and management, and identifying opportunities for improving pollution prevention performance.

1998-05-04T23:59:59.000Z

134

Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends  

Science Conference Proceedings (OSTI)

The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

2009-05-15T23:59:59.000Z

135

Comparing the greenhouse gas emissions from three alternative waste combustion concepts  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Significant GHG reductions are possible by efficient WtE technologies. Black-Right-Pointing-Pointer CHP and high power-to-heat ratio provide significant GHG savings. Black-Right-Pointing-Pointer N{sub 2}O and coal mine type are important in LCA GHG emissions of FBC co-combustion. Black-Right-Pointing-Pointer Substituting coal and fuel oil by waste is beneficial in electricity and heat production. Black-Right-Pointing-Pointer Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO{sub 2}-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

Vainikka, Pasi, E-mail: pasi.vainikka@vtt.fi [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Tsupari, Eemeli; Sipilae, Kai [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Hupa, Mikko [Aabo Akademi Process Chemistry Centre, Piispankatu 8, FIN 20500 Turku (Finland)

2012-03-15T23:59:59.000Z

136

Waste drum gas generation sampling program at Rocky Flats during FY 1988  

DOE Green Energy (OSTI)

Rocky Flats Plant Transuranic Waste Drums were sampled for gas composition. Combustibles, plastics, Raschig rings, solidified organic sludge, and solidified inorganic sludge transuranic waste forms were sampled. Plastic bag material and waste samples were also taken from some solidified sludge waste drums. A vacuum system was used to sample each layer of containment inside a waste drum, including individual waste bags. G values (gas generation) were calculated for the waste drums. Analytical results indicate that very low concentrations of potentially flammable or corrosive gas mixtures will be found in vented drums. G(H{sub 2}) was usually below 1.6, while G(Total) was below 4.0. Hydrogen permeability tests on different types of plastic waste bags used at Rocky Flats were also conducted. Polyvinylchloride was slightly more permeable to hydrogen than polyethylene for new or creased material. Permeability of aged material to hydrogen was slightly higher than for new material. Solidified organic and inorganic sludges were sampled for volatile organics. The analytical results from two drums of solidified organic sludges showed concentrations were above detection limits for four of the 36 volatile organics analyzed. The analytical results for four of the five solidified inorganic sludges show that concentrations were below detection limits for all volatile organics analyzed. 3 refs., 5 figs., 2 tabs.

Roggenthen, D.K.; McFeeters, T.L.; Nieweg, R.G.

1991-02-11T23:59:59.000Z

137

Petroleum Coke: A Viable Fuel for Cogeneration  

E-Print Network (OSTI)

Petroleum coke is a by-product of the coking process which upgrades (converts) low-valued residual oils into higher-valued transportation, heating and industrial fuels. Pace forecasts that by the year 2000 petroleum coke production will increase from 36 million to 47 million short tons/year. Because the crude pool will continue to become more sour and refiners treat the coker as the "garbage can" the quality of the petroleum cokes will generally degrade- contain higher sulfur and trace metal levels. The U.S. produces nearly 70% of the total and is expected to maintain this share. Domestic markets consumed less than half of the U.S. production; 80% of the high sulfur fuel grade production from the Gulf coast is exported to Japan or Europe. Increasing environmental concerns could disrupt historic markets and threaten coker operations. This would create opportunities for alternate end-uses such as cogeneration projects. The Pace Consultants Inc. continuously monitors and reports on the petroleum coke industry-production and markets-in its multi-client publication The Pace Petroleum Coke Ouarterly. The information presented in this paper is based on this involvement and Pace's experience in single and multi client consulting activities related to the petroleum refining and petroleum coke industries. The purpose is to provide a review of the existing world petroleum coke industry with particular emphasis on the U.S. production and markets. Forecasted production levels and critical factors which could alter the historic market disposition of petroleum coke are addressed.

Dymond, R. E.

1992-04-01T23:59:59.000Z

138

Control of Gas Emission during Pyrolysis of Waste Printed Wiring ...  

Science Conference Proceedings (OSTI)

Moreover, the possibility of controlling toxic exhaust gases and recovering ... Chemical Changes and Surface Properties of Carbonated Waste Cement ... Flux for Basic Oxygen Steel Making Using Waste Oxides of Steel Plant ... Heat Treatment of Black Dross for the Production of a Value Added Material - A Preliminary Study.

139

Colorado Refinery Marketable Petroleum Coke Production Capacity as ...  

U.S. Energy Information Administration (EIA)

Colorado Refinery Marketable Petroleum Coke Production Capacity as of January 1 (Barrels per Stream Day)

140

Method for the wet quenching of coke  

SciTech Connect

A method and apparatus for the wet quenching of coke is disclosed wherein hot coke is sprayed from above with quenching water, the steam generated by the heat of the coke is condensed by a spray of condensation water from the top of the quenching tower, and the hot condensate-water mixture is collected at the bottom of the quenching tower and recirculated to the top of the tower where it is sprayed between quenching operations to be cooled by a counterflowing stream of air. The cooled condensate water mixture is suitable for reuse as the condensation spray water.

Blase, M.; Flockenhaus, C.; Wagener, D.

1982-03-30T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Heteroatom incorporated coke for electrochemical cell electrode  

DOE Patents (OSTI)

This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

Lewis, Irwin Charles (Strongsville, OH); Greinke, Ronald Alfred (Medina, OH)

1997-01-01T23:59:59.000Z

142

Heteroatom incorporated coke for electrochemical cell electrode  

DOE Patents (OSTI)

This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

Lewis, I.C.; Greinke, R.A.

1997-06-17T23:59:59.000Z

143

Engineering study - alternatives for SHMS high temperature/moisture gas sample conditioners for the aging waste facility  

SciTech Connect

The Standard Hydrogen Monitoring Systems have been experiencing high temperature/moisture problems with gas samples from the Aging Waste Tanks. These moist hot gas samples have stopped the operation of the SHMS units on tanks AZ-101, AZ-102, and AY-102. This study looks at alternatives for gas sample conditioners for the Aging Waste Facility.

THOMPSON, J.F.

1999-06-02T23:59:59.000Z

144

Spatial variation of coke quality in the non-recovery beehive coke ovens.  

E-Print Network (OSTI)

??More than 50% of hot metal production worldwide takes place in blast furnaces. Coke is the most expensive raw material in the blast furnace. It… (more)

Segers, Magrieta

2006-01-01T23:59:59.000Z

145

Mozambique becomes a major coking coal exporter?  

SciTech Connect

In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

Ruffini, A.

2008-06-15T23:59:59.000Z

146

New and revised standards for coke production  

SciTech Connect

The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

147

TREATMENT OF FISSION PRODUCT WASTE  

DOE Patents (OSTI)

A pyrogenic method of separating nuclear reactor waste solutions containing aluminum and fission products as buring petroleum coke in an underground retort, collecting the easily volatile gases resulting as the first fraction, he uminum chloride as the second fraction, permitting the coke bed to cool and ll contain all the longest lived radioactive fission products in greatly reduced volume.

Huff, J.B.

1959-07-28T23:59:59.000Z

148

Comparison of the Potential Impacts of Petroleum Coke and Anthracite Culm Use  

E-Print Network (OSTI)

The primary feedstock for the proposed Gilberton Coal-to-Clean Fuels and Power Project would be low-cost anthracite culm, which is a locally abundant, previously discarded resource that could accommodate fuel requirements during the demonstration period. Culm reserves controlled by WMPI are estimated to be sufficient to supply the proposed facilities for about 15 years, or to supply both the proposed facilities and the existing Gilberton Power Plant for about 11 years. Based on the applicant’s proposal, the facilities would also be capable of using a blend of feedstock containing up to 25% petroleum coke. Petroleum coke is a high-sulfur, high-energy product having the appearance of coal. Oil refineries produce petroleum coke by heating and removing volatile organic compounds (VOCs) from the residue remaining after the refining process. This appendix compares some of the potential impacts of 100 % anthracite culm use with the potential impacts from using a blended feedstock of 75 % anthracite culm and 25 % petroleum coke. Topics considered include carbon dioxide emissions, air emissions of sulfur compounds and toxic substances, solid wastes and byproduct production, and increased truck traffic. Carbon Dioxide (CO2) Emissions Published values for potential CO2 emissions from anthracite and petroleum coke are very similar.

Gilberton Coal-to-clean Fuels

2007-01-01T23:59:59.000Z

149

Réactivité de l'anode et désulfuration : effet du niveau de calcination du coke.  

E-Print Network (OSTI)

??Les propriétés du coke et la performance des anodes sont affectées par le niveau de calcination du coke. Une densité de coke (VBD) élevée implique… (more)

Bergeron-Lagacé, Charles-Luc

2012-01-01T23:59:59.000Z

150

A computer model of gas generation and transport within TRU waste drums  

DOE Green Energy (OSTI)

A computer model has been developed to predict radiolytic gas generation and transport within Transuranic (TRU) waste drums and surrounding enclosures. Gas generation from the radiolytic decomposition of organic material contaminated with plutonium is modeled and the concentrations of gas throughout the waste drum and enclosures are determined using a diffusional transport model. The model accurately reproduces experimentally measured gas concentrations. With polyethylene waste in unvented drums, the model predicts that the concentration of hydrogen gas can exceed 4 mole percent (lower flammable limit) with only about 5 curies of plutonium. If the drum liner is punctured and an unrestricted 0.75-in. carbon composite filter vent is installed in the drum lid, the plutonium loading can be increased to 240 Ci without generating flammable gas mixtures. Larger diameter filters can be used to increase the curie loading. The model has been used to show that shipments of 1000 Ci of plutonium-238 contaminated waste from Savannah River to the WIPP site are feasible using the TRUPACT shipping container. 10 refs., 17 figs., 6 tabs.

Smith, F.G. III

1988-06-01T23:59:59.000Z

151

Waste Heat Recovery from Industrial Smelting Exhaust Gas  

Science Conference Proceedings (OSTI)

For a cost efficient capture of more valuable heat (higher exergy), heat exchangers should operate on the exhaust gases upstream of the gas treatment plants.

152

Prototype demonstration of dual sorbent injection for acid gas control on municipal solid waste combustion units  

SciTech Connect

This report gathered and evaluated emissions and operations data associated with furnace injection of dry hydrated lime and duct injection of dry sodium bicarbonate at a commercial, 1500 ton per day, waste-to-energy facility. The information compiled during the project sheds light on these sorbents to affect acid gas emissions from municipal solid waste combustors. The information assesses the capability of these systems to meet the 1990 Clean Air Act and 1991 EPA Emission Guidelines.

None

1994-05-01T23:59:59.000Z

153

Hydrogen Gas Generation Model for Fuel Based Remote Handled TRU Waste Stored at INEEL  

DOE Green Energy (OSTI)

The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

Soli T. Khericha; Rajiv N. Bhatt; Kevin Liekhus

2003-02-01T23:59:59.000Z

154

Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant  

SciTech Connect

Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

155

Reactive carbon from life support wastes for incinerator flue gas cleanup-System Testing  

DOE Green Energy (OSTI)

This paper presents the results from a joint research initiative between NASA Ames Research Center and Lawrence Berkeley National lab. The objective of the research is to produce activated carbon from life support wastes and to use the activated carbon to adsorb and chemically reduce the NO{sub x} and SO{sub 2} contained in incinerator flue gas. Inedible biomass waste from food production is the primary waste considered for conversion to activated carbon. Results to date show adsorption of both NO{sub x} and SO{sub 2} in activated carbon made from biomass. Conversion of adsorbed NO{sub x} to nitrogen has also been observed.

Fisher, John W.; Pisharody, Suresh; Moran, Mark J.; Wignarajah, Kanapathipillai; Xu, X.H.; Shi, Yao; Chang, Shih-Ger

2002-05-14T23:59:59.000Z

156

Use of flue gas desulphurisation (FGD) waste and rejected fly ash in waste stabilization/solidification systems  

Science Conference Proceedings (OSTI)

Stabilization/solidification (S/S) processes have been used as the final treatment step for hazardous wastes prior to land disposal. Fly ash is a by-product of coal-fired power generation; a significant proportion of this material is low-grade, reject material (rFA) that is unsuitable as a cement replacement due to its high carbon content and large particle size (>45 {mu}m). Flue gas desulphurization (FGD) sludge is a by-product from the air pollution control systems used in coal-fired power plants. The objective of this work was to investigate the performance of S/S waste binder systems containing these two waste materials (rFA and FGD). Strength tests show that cement-based waste forms with rFA and FGD replacement were suitable for disposal in landfills. The addition of an appropriate quantity of Ca(OH){sub 2} and FGD reduces the deleterious effect of heavy metals on strength development. Results of TCLP testing and the progressive TCLP test show that cement-rFA-Ca(OH){sub 2} systems with a range of FGD additions can form an effective S/S binder. The Leachability Index indicates that cement-based waste forms with rFA replacement were effective in reducing the mobility of heavy metals.

Qiao, X.C. [Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong (China); School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070 (China); Poon, C.S. [Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong (China)]. E-mail: cecspoon@polyu.edu.hk; Cheeseman, C. [Department of Civil and Environmental Engineering, Imperial College, London SW7 2BU (United Kingdom)

2006-07-01T23:59:59.000Z

157

Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar  

SciTech Connect

In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

2006-10-15T23:59:59.000Z

158

Gas generation from low-level radioactive waste: Concerns for disposal  

DOE Green Energy (OSTI)

The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

Siskind, B.

1992-01-01T23:59:59.000Z

159

Gas generation from low-level radioactive waste: Concerns for disposal  

DOE Green Energy (OSTI)

The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

Siskind, B.

1992-04-01T23:59:59.000Z

160

Design, construction and start-up of a modern coke plant  

Science Conference Proceedings (OSTI)

The planning and design of a 60-oven, 6m replacement coke battery and associated by-products plant for Republic Steel Corp, Chicago, are described together with the constructional methods used and problems experienced through start-up of the facility. Pushing emission control is achieved with a Mitsubishi-type land-based system and changing emission control with a Nippon Steel combination car and land-based system. A Takahax-Hirohax coke-oven gas desulphurization unit is included in the by-product plant. Construction began in March 1979 with the first push in December 1981.

Williams, A.E.

1983-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Microbial Gas Generation Under Expected Waste Isolation Pilot Plant Repository Conditions: Final Report  

Science Conference Proceedings (OSTI)

Gas generation from the microbial degradation of the organic constituents of transuranic (TRU) waste under conditions expected in the Waste Isolation Pilot Plant (WIPP) was investigated. The biodegradation of mixed cellulosic materials and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, hypalon, leaded hypalon, and neoprene) was examined. We evaluated the effects of environmental variables such as initial atmosphere (air or nitrogen), water content (humid ({approx}70% relative humidity, RH) and brine inundated), and nutrient amendments (nitogen phosphate, yeast extract, and excess nitrate) on microbial gas generation. Total gas production was determined by pressure measurement and carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) were analyzed by gas chromatography; cellulose degradation products in solution were analyzed by high-performance liquid chromatography. Microbial populations in the samples were determined by direct microscopy and molecular analysis. The results of this work are summarized.

Gillow, J.B.; Francis, A.

2011-07-01T23:59:59.000Z

162

Waste tank headspace gas and vapor characterization reference guide  

SciTech Connect

This document is to serve as a reference guide for gas and vapor sample results presented in tank characterization reports. It describes sampling equipment, devices, and protocols, and sample collection and analysis methods common to all vapor samples.

Huckaby, J.L.

1995-06-01T23:59:59.000Z

163

A study of tritium in municipal solid waste leachate and gas  

Science Conference Proceedings (OSTI)

It has become increasingly clear in the last few years that the vast majority of municipal solid waste landfills produce leachate that contains elevated levels of tritium. The authors recently conducted a study of landfills in New York and New Jersey and found that the mean concentration of tritium in the leachate from ten municipal solid waste (MSW) landfills was 33,800 pCi/L with a peak value of 192,000 pCi/L. A 2003 study in California reported a mean tritium concentration of 99,000 pCi/L with a peak value of 304,000 pCi/L. Studies in Pennsylvania and the UK produced similar results. The USEPA MCL for tritium is 20,000 pCi/L. Tritium is also manifesting itself as landfill gas and landfill gas condensate. Landfill gas condensate samples from landfills in the UK and California were found to have tritium concentrations as high as 54,400 and 513,000 pCi/L, respectively. The tritium found in MSW leachate is believed to derive principally from gaseous tritium lighting devices used in some emergency exit signs, compasses, watches, and even novelty items, such as 'glow stick' key chains. This study reports the findings of recent surveys of leachate from a number of municipal solid waste landfills, both open and closed, from throughout the United States and Europe. The study evaluates the human health and ecological risks posed by elevated tritium levels in municipal solid waste leachate and landfill gas and the implications to their safe management. We also assess the potential risks posed to solid waste management facility workers exposed to tritium-containing waste materials in transfer stations and other solid waste management facilities. (authors)

Mutch Jr, R. D. [HydroQual, Inc., 1200 MacArthur Blvd., Mahwah, NJ 07430 (United States); Manhattan College, Riverdale, NY (United States); Columbia Univ., New York, NY (United States); Mahony, J. D. [HydroQual, Inc., 1200 MacArthur Blvd., Mahwah, NJ 07430 (United States); Manhattan College, Riverdale, NY (United States)

2008-07-15T23:59:59.000Z

164

Options and costs for offsite disposal of oil and gas exploration and production wastes.  

Science Conference Proceedings (OSTI)

In the United States, most of the exploration and production (E&P) wastes generated at onshore oil and gas wells are disposed of or otherwise managed at the well site. Certain types of wastes are not suitable for onsite management, and some well locations in sensitive environments cannot be used for onsite management. In these situations, operators must transport the wastes offsite for disposal. In 1997, Argonne National Laboratory (Argonne) prepared a report that identified offsite commercial disposal facilities in the United States. This information has since become outdated. Over the past year, Argonne has updated the study through contacts with state oil and gas agencies and commercial disposal companies. The new report, including an extensive database for more than 200 disposal facilities, provides an excellent reference for information about commercial disposal operations. This paper describes Argonne's report. The national study provides summaries of the types of offsite commercial disposal facilities found in each state. Data are presented by waste type and by disposal method. The categories of E&P wastes in the database include: contaminated soils, naturally occurring radioactive material (NORM), oil-based muds and cuttings, produced water, tank bottoms, and water-based muds and cuttings. The different waste management or disposal methods in the database involve: bioremediation, burial, salt cavern, discharge, evaporation, injection, land application, recycling, thermal treatment, and treatment. The database includes disposal costs for each facility. In the United States, most of the 18 billion barrels (bbl) of produced water, 149 million bbl of drilling wastes, and 21 million bbl of associated wastes generated at onshore oil and gas wells are disposed of or otherwise managed at the well site. However, under certain conditions, operators will seek offsite management options for these E&P wastes. Commercial disposal facilities are offsite businesses that accept and manage E&P wastes for a fee. Their services include waste management and disposal, transportation, cleaning of vehicles and tanks, disposal of wash water, and, in some cases, laboratory analysis. Commercial disposal facilities offer a suite of waste management methods and technologies.

Puder, M. G.; Veil, J. A.; Environmental Science Division

2007-01-01T23:59:59.000Z

165

Test plan for headspace gas sampling of remote-handled transuranic waste containers at Los Alamos National Laboratory  

DOE Green Energy (OSTI)

Seventeen remote-handled (RH) transuranic (TRU) waste canisters currently are stored in vertical, underground shafts at Technical Area (TA)-54, Area G, at Los Alamos National Laboratory (LANL). These 17 RH TRU waste canisters are destined to be shipped to the Waste Isolation Pilot Plant (WIPP) for permanent disposal in the geologic repository. As the RH TRU canister is likely to be the final payload container prior to placement into the 72-B cask and shipment to the WIPP, these waste canisters provide a unique opportunity to ascertain representative flammable gas concentrations in packaged RH-TRU waste. Hydrogen, which is produced by the radiolytic decomposition of hydrogenous constituents in the waste matrix, is the primary flammable gas of concern with RH TRU waste. The primary objectives of the experiment that is described by this test plan are to sample and analyze the waste canister headspace gases to determine the concentration of hydrogen in the headspace gas and to calculate the hydrogen gas generation rate for comparison to the applicable maximum allowable hydrogen generation rate (mole/sec) limits. It is a goal of this experiment to determine the headspace gas concentrations of other gases (e.g., oxygen, nitrogen, carbon dioxide, carbon monoxide, and volatile organic compounds (VOCs) with molecular weights less than 60 g/mole) that are produced by radiolysis or present when the waste was packaged. Additionally, the temperature, pressure, and flow rate of the headspace gas will be measured.

Field, L.R.; Villarreal, R. [Los Alamos National Lab., NM (United States)

1998-02-24T23:59:59.000Z

166

Development of coke strength after reaction (CSR) at Dofasco  

Science Conference Proceedings (OSTI)

In order to prevent coke degradation without detrimentally affecting blast furnace service life, Dofasco initiated a project to improve coke strength after reaction. The results of the program and Dofasco's prediction model are presented. 9 refs., 12 figs., 9 tabs.

T.W. Todoschuk; J.P. Price; J.F. Gransden

2004-03-01T23:59:59.000Z

167

U.S. Refinery Thermal Cracking, Fluid Coking Downstream Charge ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Thermal Cracking, Fluid Coking Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

168

Characterization of Petroleum Coke and Butts Used in Anode ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2013. Symposium, Particulate Composites. Presentation Title, Characterization of Petroleum Coke ...

169

U.S. Refinery Marketable Petroleum Coke Production Capacity as ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Marketable Petroleum Coke Production Capacity as of January 1 (Barrels per Stream Day)

170

Effect of Coke particle size on sinter quality  

Science Conference Proceedings (OSTI)

Meeting, 2011 TMS Annual Meeting & Exhibition. Symposium, EMPMD Technical Division Student Poster Contest. Presentation Title, Effect of Coke particle size ...

171

Gas Releases During Saltcake Dissolution for Retrieval of Single-Shell Tank Waste  

DOE Green Energy (OSTI)

It is possible to retrieve a large fraction of soluble waste from the Hanford single-shell waste tanks (SST) by dissolving it with water. This retrieval method will be demonstrated in U-107 and S-112 in the next few years. If saltcake dissolution proves practical and effective, many of the saltcake SSTs may be retrieved by this method. Many of the SSTs retain a large volume of flammable gas that will be released into the tank headspace as the waste dissolves. This report describes the physical processes that control dissolution and gas release. Calculation results are shown describing the headspace hydrogen concentration transient during dissolution. The observed spontaneous and induced gas releases from SSTs is summarized and the dissolution of the crust layer in SY-101 is discussed as a recent example of full-scale dissolution of saltcake containing a very large volume of retained gas. The report concludes that the dissolution rate is self limiting and gas release rates are relatively low.

Stewart, Charles W

2001-07-31T23:59:59.000Z

172

Gas Releases During Saltcake Dissolution for Retrieval of Single-Shell Tank Waste, Rev. 1  

DOE Green Energy (OSTI)

It is possible to retrieve a large fraction of soluble waste from the Hanford single-shell waste tanks (SSTs) by dissolving it with water. This retrieval method will be demonstrated in Tanks U-107 and S-112 in the next few years. If saltcake dissolution proves practical and effective, many of the saltcake SSTs may be retrieved by this method. Many of the SSTs retain flammable gas that will be released into the tank headspace as the waste dissolves. This report describes the physical processes that control dissolution and gas release. Calculation results are shown and describe how the headspace hydrogen concentration evolves during dissolution. The observed spontaneous and induced gas releases from SSTs are summarized, and the dissolution of the crust layer in SY-101 is discussed as a recent example of full-scale dissolution of saltcake containing a large volume of retained gas. The report concludes that the dissolution rate is self-limiting and that gas release rates are relatively low.

Stewart, Charles W

2001-12-28T23:59:59.000Z

173

Effect of Trace Elements on Anaerobic Digestion of Coking Wastewater  

Science Conference Proceedings (OSTI)

The pretreatment of coking wastewater using ASBR was conducted at 35? in this paper. The addition of trace elements to the anaerobic reactor has positive effect on the anaerobic treatment of coking wastewater, but too much or too little of it will ... Keywords: trace elements, anaerobic digestion, coking wastewater

Yu-ying Li; Bing Li

2009-10-01T23:59:59.000Z

174

Fundamental factors influencing coke strength.  

E-Print Network (OSTI)

??Research Doctorate - Doctor of Philosophy (PhD) In an ironmaking blast furnace solid-gas reactions are important and the rate of iron production is strongly dependent… (more)

Curran, Joel

2009-01-01T23:59:59.000Z

175

Studies Related to Chemical Mechanisms of Gas Formation in Hanford High-Level Nuclear Wastes  

DOE Green Energy (OSTI)

The objective of this work is to develop a more detailed mechanistic understanding of the thermal reactions that lead to gas production in certain high-level waste storage tanks at the Hanford, Washington site. Prediction of the combustion hazard for these wastes and engineering parameters for waste processing depend upon both a knowledge of the composition of stored wastes and the changes that they undergo as a result of thermal and radiolytic decomposition. Since 1980 when Delagard first demonstrated that gas production (H2and N2O initially, later N2 and NH3)in the affected tanks was related to oxidative degradation of metal complexants present in the waste, periodic attempts have been made to develop detailed mechanisms by which the gases were formed. These studies have resulted in the postulation of a series of reactions that account for many of the observed products, but which involve several reactions for which there is limited, or no, precedent. For example, Al(OH)4 has been postulated to function as a Lewis acid to catalyze the reaction of nitrite ion with the metal complexants, NO is proposed as an intermediate, and the ratios of gaseous products may be a result of the partitioning of NO between two or more reactions. These reactions and intermediates have been the focus of this project since its inception in 1996.

E. Kent Barefield; Charles L. Liotta; Henry M. Neumann

2002-04-08T23:59:59.000Z

176

Test container design/fabrication/function for the Waste Isolation Pilot Plant gas generation experiment glovebox  

SciTech Connect

The gas generation experiments (GGE) are being conducted at Argonne National Laboratory-West (ANL0W) with contact handled transuranic (CH-TRU) waste in support of the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. The purpose of the GGE is to determine the different quantities and types of gases that would be produced and the gas-generation rates that would develop if brine were introduced to CH-TRU waste under post-closure WIPP disposal room conditions. The experiment requires that a prescribed matrix of CH-TRU waste be placed in a 7.5 liter test container. After loaded with the CH-TRU waste, brine and inoculum mixtures (consisting of salt and microbes indigenous to the Carlsbad, New Mexico region) are added to the waste. The test will run for an anticipated time period of three to five years. The test container itself is an ASME rated pressure vessel constructed from Hastelloy C276 to eliminate corrosion that might contaminate the experimental results. The test container is required to maintain a maximum 10% head space with a maximum working pressure of 17.25 MPa (2,500 psia). The test container is designed to provide a gas sample of the head space without the removal of brine. Assembly of the test container lid and process valves is performed inside an inert atmosphere glovebox. Glovebox mockup activities were utilized from the beginning of the design phase to ensure the test container and associated process valves were designed for remote handling. In addition, test container processes (including brine addition, sparging, leak detection, and test container pressurization) are conducted inside the glovebox.

Knight, C.J.; Russell, N.E.; Benjamin, W.W.; Rosenberg, K.E.; Michelbacher, J.A.

1997-09-01T23:59:59.000Z

177

Water protection in coke-plant design  

Science Conference Proceedings (OSTI)

Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

178

Compact Ceramic Heat Exchangers for Corrosive Waste Gas Applications  

E-Print Network (OSTI)

The development of large ceramic heat exchangers is described and performance data given for units installed on steel industry soaking pits in the U.K. Operational experience since 1973 confirms that ceramic heat exchangers capable of operating with high airside pressures have long lives and low maintenance even when operating with dirty gases at 1350 deg. C and preheating combustion air to 800 deg. C. The design of compact units suitable for factory assembly is also described. Units have been developed for low temperature corrosive gas situations and have been applied to the pottery industry and are being developed for coal fired air heaters for the food industry.

Laws, W. R.; Reed, G. R.

1982-01-01T23:59:59.000Z

179

Greenhouse gas emissions from home composting of organic household waste  

Science Conference Proceedings (OSTI)

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6-3.5 kg week{sup -1} and the temperature inside the composting units was in all cases only a few degrees (2-10 {sup o}C) higher than the ambient temperature. The emissions of methane (CH{sub 4}) and nitrous oxide (N{sub 2}O) were quantified as 0.4-4.2 kg CH{sub 4} Mg{sup -1} input wet waste (ww) and 0.30-0.55 kg N{sub 2}O Mg{sup -1} ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH{sub 4} and N{sub 2}O emissions) of 100-239 kg CO{sub 2}-eq. Mg{sup -1} ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH{sub 4} during mixing which was estimated to 8-12% of the total CH{sub 4} emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg{sup -1} ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO{sub 2}-eq. Mg{sup -1} ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.

Andersen, J.K., E-mail: jka@env.dtu.d [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark); Boldrin, A.; Christensen, T.H.; Scheutz, C. [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark)

2010-12-15T23:59:59.000Z

180

Reducing dust emissions at OAO Alchevskkoks coke battery 10A  

Science Conference Proceedings (OSTI)

Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

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181

Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles  

SciTech Connect

Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

Haihua Zhao; Per F. Peterson

2012-10-01T23:59:59.000Z

182

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE  

Science Conference Proceedings (OSTI)

Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.

Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

1999-09-01T23:59:59.000Z

183

Corrosion-induced gas generation in a nuclear waste repository: Reactive geochemistry and multiphase flow effect  

DOE Green Energy (OSTI)

Corrosion of steel canisters, stored in a repository for spent fuel and high-level nuclear wastes, leads to the generation and accumulation of hydrogen gas in the backfilled emplacement tunnels, which may significantly affect long-term repository safety. Previous studies used H{sub 2} generation rates based on the volume of the waste or canister material and the stoichiometry of the corrosion reaction. However, iron corrosion and H{sub 2} generation rates vary with time, depending on factors such as amount of iron, water availability, water contact area, and aqueous and solid chemistry. To account for these factors and feedback mechanisms, we developed a chemistry model related to iron corrosion, coupled with two-phase (liquid and gas) flow phenomena that are driven by gas-pressure buildup associated with H{sub 2} generation and water consumption. Results indicate that by dynamically calculating H{sub 2} generation rates based on a simple model of corrosion chemistry, and by coupling this corrosion reaction with two-phase flow processes, the degree and extent of gas pressure buildup could be much smaller compared to a model that neglects the coupling between flow and reactive transport mechanisms. By considering the feedback of corrosion chemistry, the gas pressure increases initially at the canister, but later decreases and eventually returns to a stabilized pressure that is slightly higher than the background pressure. The current study focuses on corrosion under anaerobic conditions for which the coupled hydrogeochemical model was used to examine the role of selected physical parameters on the H{sub 2} gas generation and corresponding pressure buildup in a nuclear waste repository. The developed model can be applied to evaluate the effect of water and mineral chemistry of the buffer and host rock on the corrosion reaction for future site-specific studies.

Xu, T.; Senger, R.; Finsterle, S.

2008-10-15T23:59:59.000Z

184

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials  

DOE Green Energy (OSTI)

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing materials. Transportation regulations prohibit shipment of explosives and radioactive materials together. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials (NM), and spent nuclear fuels (SNF) programs within DOE’s Environmental Management (EM) organization to address gas generation concerns. This paper presents a "program level" roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This "program level" roadmapping involves linking technology development (and deployment) efforts to the programs’ needs and requirements for dispositioning the material/waste that generates combustible gas through radiolysis and chemical decomposition. The roadmapping effort focused on needed technical & programmatic support to the baselines (and to alternatives to the baselines) where the probability of success is low (i.e., high uncertainty) and the consequences of failure are relatively high (i.e., high programmatic risk). A second purpose for roadmapping was to provide the basis for coordinating sharing of "lessons learned" from research and development (R&D) efforts across DOE programs to increase efficiency and effectiveness in addressing gas generation issues.

Luke, Dale Elden; Rogers, Adam Zachary; Hamp, S.

2001-03-01T23:59:59.000Z

185

Offsite commercial disposal of oil and gas exploration and production waste :availability, options, and cost.  

Science Conference Proceedings (OSTI)

A survey conducted in 1995 by the American Petroleum Institute (API) found that the U.S. exploration and production (E&P) segment of the oil and gas industry generated more than 149 million bbl of drilling wastes, almost 18 billion bbl of produced water, and 21 million bbl of associated wastes. The results of that survey, published in 2000, suggested that 3% of drilling wastes, less than 0.5% of produced water, and 15% of associated wastes are sent to offsite commercial facilities for disposal. Argonne National Laboratory (Argonne) collected information on commercial E&P waste disposal companies in different states in 1997. While the information is nearly a decade old, the report has proved useful. In 2005, Argonne began collecting current information to update and expand the data. This report describes the new 2005-2006 database and focuses on the availability of offsite commercial disposal companies, the prevailing disposal methods, and estimated disposal costs. The data were collected in two phases. In the first phase, state oil and gas regulatory officials in 31 states were contacted to determine whether their agency maintained a list of permitted commercial disposal companies dedicated to oil. In the second stage, individual commercial disposal companies were interviewed to determine disposal methods and costs. The availability of offsite commercial disposal companies and facilities falls into three categories. The states with high oil and gas production typically have a dedicated network of offsite commercial disposal companies and facilities in place. In other states, such an infrastructure does not exist and very often, commercial disposal companies focus on produced water services. About half of the states do not have any industry-specific offsite commercial disposal infrastructure. In those states, operators take their wastes to local municipal landfills if permitted or haul the wastes to other states. This report provides state-by-state summaries of the types of offsite commercial disposal facilities that are found in each state. In later sections, data are presented by waste type and then by disposal method.

Puder, M. G.; Veil, J. A.

2006-09-05T23:59:59.000Z

186

GAS-GENERATION EXPERIMENTS FOR LONG-TERM STORAGE OF TRU WASTES AT WIPP  

DOE Green Energy (OSTI)

An experimental investigation was conducted for gas generation in contact-handled transuranic (CH-TRU) wastes subjected for several years to conditions similar to those expected to occur at the Waste Isolation Pilot Plant (WIPP) should the repository eventually become inundated with brine. Various types of actual CH-TRU wastes were placed into 12 corrosion-resistant vessels. The vessels were loosely filled with the wastes, which were submerged in synthetic brine having the same chemical composition as that in the WIPP vicinity. The vessels were also inoculated with microbes found in the Salado Formation at WIPP. The vessels were sealed, purged, and the approximately 750-ml headspace was pressurized with nitrogen gas to approximately 146 atmospheres to create anoxic conditions at the lithostatic pressure expected in the repository were it inundated. The temperature was maintained at the expected 30 C. The test program objective was to measure the quantities and species of gases generate d by metal corrosion, radiolysis, and microbial activity. These data will assist in the specification of the rates at which gases are produced under inundated repository conditions for use in the WIPP Performance Assessment computer models. These experiments were very carefully designed, constructed, instrumented, and performed. Approximately 6-1/2 years of continuous, undisturbed testing were accumulated. Several of the vessels showed significantly elevated levels of generated gases, virtually all of which was hydrogen. One vessel measured over 4.2% hydrogen, by volume. Two other vessels generated well over 1% hydrogen, and another was at nearly 1%. Only small quantities of other gases, principally carbon dioxide, were detected. Gas generation was found to depend strongly on the waste composition. The maximum hydrogen generation occurred in tests containing carbon steel. Average corrosion penetration rates in carbon-steel of up to 2.3 microns per year were deduced. Conversion of carbon to carbon dioxide was calculated to be up to 4.7 {micro}g-mol/yr/g-carbon.

Felicione, F.S.; Carney, K.P.; Dwight, C.C.; Cummings, D.G.; Foulkrod, L.E.

2003-02-27T23:59:59.000Z

187

Analysis of Induced Gas Releases During Retrieval of Hanford Double-Shell Tank Waste  

DOE Green Energy (OSTI)

Checklist for Technical Peer Review for PNNL-13782 Rev. 1 as requested to ensure that software used to support the DSA is compliant with software QA requirements. Radioactive waste is scheduled to be retrieved from Hanford double-shell tanks AN-103, AN-104, AN-105 and AW-101 and transferred to the vitrification plant beginning in about 2009. Retrieval may involve decanting the supernatant liquid and/or mixing the waste with jet pumps. In these four tanks, which contain relatively large volumes of retained gas, both operations are expected to induce buoyant displacement gas releases that can potentially raise the tank headspace hydrogen concentration to a level very near the lower flammability limit. This report describes the theory and detailed physical models for both the supernatant decant and jet mixing processes and presents the results from applying the models to these operations in the four tanks. The technical bases for input parameter distributions are elucidated.

Wells, Beric E.

2003-02-19T23:59:59.000Z

188

Analysis of Induced Gas Released During Retrieval of Hanford Double-Shell Tank Waste  

DOE Green Energy (OSTI)

Radioactive waste is scheduled to be retrieved from Hanford double-shell tanks AN-103, AN-104, AN-105 and AW-101 to the vitrification plant beginning about 2009. Retrieval may involve decanting the supernatant liquid and/or mixing the waste with jet pumps. In these four tanks, which contain relatively large volumes of retained gas, both of these operations are expected to induce buoyant displacement gas releases that can potentially raise the tank headspace hydrogen concentration to very near the lower flammability limit. This report describes the theory and detailed physical models for both the supernate decant and jet mixing processes and presents the results from applying the models to these operations in the four tanks. The technical bases for input parameter distributions are elucidated.

Wells, Beric E. (BATTELLE (PACIFIC NW LAB)); Cuta, Judith M. (BATTELLE (PACIFIC NW LAB)); Hartley, Stacey A. (BATTELLE (PACIFIC NW LAB)); Mahoney, Lenna A. (BATTELLE (PACIFIC NW LAB)); Meyer, Perry A. (BATTELLE (PACIFIC NW LAB)); Stewart, Charles W. (BATTELLE (PACIFIC NW LAB))

2002-03-20T23:59:59.000Z

189

Analysis of Induced Gas Releases During Retrieval of Hanford Double-Shell Tank Waste  

DOE Green Energy (OSTI)

Radioactive waste is scheduled to be retrieved from Hanford double-shell tanks AN-103, AN-104, AN-105, and AW-101 to the vitrification plant beginning about 2009. Retrieval may involve decanting the supernatant liquid and/or mixing the waste with jet pumps. In these four tanks, which contain relatively large volumes of retained gas, both of these operations are expected to induce buoyant displacement gas releases that can potentially raise the tank headspace hydrogen concentration to very near the lower flammability limit. This report describes the theory and detailed physical models for both the supernatant decant and jet mixing processes and presents the results from applying the models to these operations in the four tanks. The technical bases for input parameter distributions are elucidated.

Wells, Beric E. (BATTELLE (PACIFIC NW LAB)); Cuta, Judith M. (BATTELLE (PACIFIC NW LAB)); Hartley, Stacey A. (BATTELLE (PACIFIC NW LAB)); Mahoney, Lenna A. (BATTELLE (PACIFIC NW LAB)); Meyer, Perry A. (BATTELLE (PACIFIC NW LAB)); Stewart, Charles W. (BATTELLE (PACIFIC NW LAB))

2002-09-25T23:59:59.000Z

190

Predicting Peak Hydrogen Concentrations from Spontaneous Gas Releases in Hanford Waste Tanks  

DOE Green Energy (OSTI)

Buoyant displacement gas release events (BDGRE) are spontaneous gas releases that occur in a few of the Hanford radioactive waste storage tanks when gas accumulation makes the sediment layer buoyant with respect to the liquid. BDGREs are assumed to be likely if the ratio of the predicted sediment gas fraction and neutral buoyancy gas fraction, or buoyancy ratio, exceeds unity. Based on the observation that the buoyancy ratio is also an empirical indicator of BDGRE size, a new methodology is derived that formally correlates the buoyancy ratio and the peak headspace hydrogen concentration resulting from BDGREs. The available data on the six historic BDGRE tanks, AN-103, AN-104, AN-105, AW-101, SY-103, and SY-101, are studied in detail to describe both the waste state and the corresponding distribution of BDGREs. The range of applicability of the buoyancy ratio-based models is assessed based on the modeling assumptions and availability of tank data. Recommendations are given for extending the range of the models applicability.

Stewart, Charles W.; Hartley, Stacey A.; Meyer, Perry A.; Wells, Beric E.

2005-07-15T23:59:59.000Z

191

DNAPL Site Characterization for Waste Management at Manufactured Gas Plant (MGP) Sites  

Science Conference Proceedings (OSTI)

Determining the optimal waste management strategy at manufactured gas plant (MGP) sites requires adequate site characterization to provide data for remediation decisions, a task that is particularly challenging when dense nonaqueous phase liquids (DNAPLs) are present. This report discusses development of an appropriate characterization strategy, including parameters that should be characterized, tools for characterization and the relation between characterization goals, a developing site conceptual model...

2004-12-22T23:59:59.000Z

192

Assessment of microbial processes on gas production at radioactive low-level waste disposal sites  

SciTech Connect

Factors controlling gaseous emanations from low level radioactive waste disposal sites are assessed. Importance of gaseous fluxes of methane, carbon dioxide, and possible hydrogen from the site, stems from the inclusion of tritium and/or carbon-14 into the elemental composition of these compounds. In that the primary source of these gases is the biodegradation of organic components of the waste material, primary emphasis of the study involved an examination of the biochemical pathways producing methane, carbon dioxide, and hydrogen, and the environmental parameters controlling the activity of the microbial community involved. Initial examination of the data indicates that the ecosystem is anaerobic. As the result of the complexity of the pathway leading to methane production, factors such as substrate availability, which limit the initial reaction in the sequence, greatly affect the overall rate of methane evolution. Biochemical transformations of methane, hydrogen and carbon dioxide as they pass through the soil profile above the trench are discussed. Results of gas studies performed at three commercial low level radioactive waste disposal sites are reviewed. Methods used to obtain trench and soil gas samples are discussed. Estimates of rates of gas production and amounts released into the atmosphere (by the GASFLOW model) are evaluated. Tritium and carbon-14 gaseous compounds have been measured in these studies; tritiated methane is the major radionuclide species in all disposal trenches studied. The concentration of methane in a typical trench increases with the age of the trench, whereas the concentration of carbon dioxide is similar in all trenches.

Weiss, A.J.; Tate, R.L. III; Colombo, P.

1982-05-01T23:59:59.000Z

193

Improved Hydrogen Gas Getters for TRU Waste Transuranic and Mixed Waste Focus Area - Phase 2 Final Report  

DOE Green Energy (OSTI)

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission (NRC) limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB. It has the needed binding rate and capacity, but some of the chemical species that might be present in the containers could interfere with its ability to remove hydrogen. This project is focused upon developing a protective polymeric membrane coating for the DEB getter material, which comes in the form of small, irregularly shaped particles. This report summarizes the experimental results of the second phase of the development of the materials.

Stone, Mark Lee

2002-04-01T23:59:59.000Z

194

11th North American Waste to Energy Conference Copyright 2003 by ASME  

E-Print Network (OSTI)

flue gas in an intensive contact with Ca(OH)z, open hearth furnace coke, water and recirculated, in the TURBOSORP® FGC process open-hearth oven coke (HOC) is injected in addition to the sorbent containing calcium during the operation of the pilot plant. As already mentioned above open-hearth oven coke is added

Columbia University

195

Syn-Gas Production from Catalytic Steam Gasification of Municipal Solid Wastes in a Combined Fixed Bed Reactor  

Science Conference Proceedings (OSTI)

The catalytic steam gasi?cation of municipal solid wastes (MSW) for syn-gas production was experimentally investigated in a combined fixed bed reactor using the newly developed tri-metallic catalyst. A series of experiments have been performed to explore ... Keywords: Biomass gasification, municipal solid wastes, catalyst, hydrogen production, energy recovery

Jianfen Li; Jianjun Liu; Shiyan Liao; Xiaorong Zhou; Rong Yan

2010-10-01T23:59:59.000Z

196

Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001  

SciTech Connect

This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

2009-09-15T23:59:59.000Z

197

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE  

SciTech Connect

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

NONE

1998-09-01T23:59:59.000Z

198

Method for reducing coke oven carbonization pressure  

SciTech Connect

A method of reducing the carbonization pressure in the coking of coal is provided which comprises randomly dispersing flakes through the coal, said flakes formed of a material that does not pass through a plastic phase such as pressed sawdust wherein the flakes have a thickness of between about 1/8 '' and about 3/4 '' and a length and width of between about 1'' and about 5''.

Perch, M.

1981-04-28T23:59:59.000Z

199

Process for treatment of residual gas  

SciTech Connect

A process is disclosed for the treatment of the residual gases which are produced when hydrogen sulfide is reduced, by combustion, to elementary sulfur by the Claus process. The residual gases are fed through a heated conduit and gas scrubber, wherein the temperature of those residual gases are maintained above the melting point of sulfur. A portion of the raw coke oven gas condensate is admitted to the gas scrubber to be returned to the coke oven battery main from the flushing liquid separator as flushing liquor. The residual gases are then conducted through the coke oven gas purification process equipment along with the raw coke oven gas where the residual gases are intermixed with the raw coke oven gas prior to tar separation.

Nolden, K.

1980-01-01T23:59:59.000Z

200

Table 16. U.S. Coke Exports  

U.S. Energy Information Administration (EIA) Indexed Site

U.S. Coke Exports U.S. Coke Exports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 16. U.S. Coke Exports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Destination April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 162,796 79,217 201,795 242,013 340,944 -29.0 Canada* 73,859 17,837 112,348 91,696 161,596 -43.3 Mexico 88,535 60,517 86,721 149,052 176,163 -15.4 Other** 402 863 2,726 1,265 3,185 -60.3 South America Total 223 217 591 440 1,158 -62.0 Other** 223 217 591 440 1,158 -62.0 Europe Total 48,972 59,197 - 108,169 6 NM Other** 347 11,743 - 12,090 - - United Kingdom 48,625 47,454 - 96,079 6 NM Asia Total 317 553 633 870 4,778

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Table 21. U.S. Coke Imports  

U.S. Energy Information Administration (EIA) Indexed Site

U.S. Coke Imports U.S. Coke Imports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 21. U.S. Coke Imports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Origin April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 10,284 2,293 159,462 12,577 183,712 -93.2 Canada 3,009 2,293 159,462 5,302 183,712 -97.1 Panama 7,275 - - 7,275 - - South America Total 25,267 13,030 88,424 38,297 106,612 -64.1 Brazil - - 78,595 - 78,595 - Colombia 25,267 13,030 9,829 38,297 28,017 36.7 Europe Total 6,044 40,281 165,027 46,325 485,791 -90.5 Czech Republic - 170 - 170 - - Spain 363 - - 363 - - Ukraine 5,681 40,111 5,047 45,792 53,543 -14.5 United Kingdom

202

Price of dwindling supply of better-quality coke will trend upward during this decade  

Science Conference Proceedings (OSTI)

This paper discusses the markets for petroleum coke with particular emphasis on the USA. The factors affecting the price of Green Coke are examined. It is considered that the price of any coke is set by the mix of markets available to the market based on demand. However, refiners producing similar quality cokes, will not necessarily receive the same netback price even if their cokes are sold to the same mix of markets. Calcined coke is used almost exclusively by the Aluminium industry thus green coke prices are indirectly tied to those of Aluminium as green coke is the primary carbon source for the calcined coke market.

Fasullo, P.; Tarrillion, T.; Matson, J.

1982-11-08T23:59:59.000Z

203

Mechanisms of gas retention and release: Experimental results for Hanford waste tanks 241-AW-101 and 241-AN-103  

DOE Green Energy (OSTI)

The 177 storage tanks at Hanford contain a vast array of radioactive waste forms resulting, primarily, from nuclear materials processing. Through radiolytic, thermal, and other decomposition reactions of waste components, gaseous species including hydrogen, ammonia, and the oxidizer nitrous oxide are generated within the waste tanks. Many of these tanks are known to retain and periodically release quantities of these flammable gas mixtures. The primary focus of the Flammable Gas Project is the safe storage of Hanford tank wastes. To this end, we strive to develop an understanding of the mechanisms of flammable gas retention and release in Hanford tanks through laboratory investigations on actual tank wastes. These results support the closure of the Flammable Gas Unreviewed Safety Question (USQ) on the safe storage of waste tanks known to retain flammable gases and support resolution of the broader Flammable Gas Safety Issue. The overall purpose of this ongoing study is to develop a comprehensive and thorough understanding of the mechanisms of flammable gas retention and release. The first objective of the current study was to classify bubble retention and release mechanisms in two previously untested waste materials from Tanks 241-AN-103 (AN-103) and 241-AW-101 (AW-101). Results were obtained for retention mechanisms, release characteristics, and the maximum gas retention. In addition, unique behavior was also documented and compared with previously studied waste samples. The second objective was to lengthen the duration of the experiments to evaluate the role of slowing bubble growth on the retention and release behavior. Results were obtained for experiments lasting from a few hours to a few days.

Rassat, S.D.; Gauglitz, P.A.; Bredt, P.R.; Mahoney, L.A.; Forbes, S.V.; Tingey, S.M.

1997-09-01T23:59:59.000Z

204

Gas bubble retention and its effect on waste properties: Retention mechanisms, viscosity, and tensile and shear strengths  

SciTech Connect

Several of the underground nuclear storage tanks at Hanford have been placed on a flammable gas watch list, because the waste is either known or suspected to generate, store, and episodically release flammable gases. Because retention and episodic release of flammable gases from these tanks containing radioactive waste slurries are critical safety concerns, Pacific Northwest Laboratory (PNL) is studying physical mechanisms and waste properties that contribute to the episodic gas release from these storage tanks. This study is being conducted for Westinghouse Hanford Company as part of the PNL Flammable Gas project. Previous investigations have concluded that gas bubbles are retained by the slurry or sludge that has settled at the bottom of the tanks; however, the mechanisms responsible for the retention of these bubbles are not well understood. Understanding the rheological behavior of the waste, particularly of the settled sludge, is critical to characterizing the tendency of the waste to retain gas bubbles and the dynamics of how these bubbles are released from the waste. The presence of gas bubbles is expected to affect the rheology of the sludge, specifically its viscosity and tensile and shear strengths, but essentially no literature data are available to assess the effect of bubbles. The objectives of this study were to conduct experiments and develop theories to understand better how bubbles are retained by slurries and sludges, to measure the effect of gas bubbles on the viscosity of simulated slurries, and to measure the effect of gas bubbles on the tensile and shear strengths of simulated slurries and sludges. In addition to accomplishing these objectives, this study developed correlations, based on the new experimental data, that can be used in large-scale computations of waste tank physical phenomena.

Gauglitz, P.A.; Rassat, S.D.; Powell, M.R. [and others

1995-08-01T23:59:59.000Z

205

Reducing Power Production Costs by Utilizing Petroleum Coke  

Science Conference Proceedings (OSTI)

Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke. It is most commonly blended with coal in proportions suitable to meet sulfur emission compliance, and is generally less reactive than coal. Therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the comb...

2000-05-05T23:59:59.000Z

206

Design and economics for low pressure delayed coking  

Science Conference Proceedings (OSTI)

The current refining trend is to run heavier crudes with a growing emphasis on bottom of the barrel resid upgrading. In general, a reduction in light crude availability and a corresponding increase in the price differential between light and heavy crudes makes the processing of heavier crudes highly attractive. US Department of Energy data indicate that between 1985 and 1989 the average API gravity of crude being processed in the US dropped from 32.46 to 32.14 degrees while the average sulfur content increased 0.15 wt%. As crudes get heavier and the demand for light, clean fuels increases, expanded resid upgrading capacity is rapidly becoming a necessity for most refiners. The coking process has existed since the early 1900's, and delayed coking is still favored as a relatively low cost resid upgrading option. Consistent with the objective of maximizing resid conversion, recent trends in delayed coking include maximizing liquid yields and reducing the production of petroleum coke by operating coke drums at lower pressures. Typically, the incremental liquid gained at lower pressures is worth significantly more than coke and can be further upgraded to lighter products. In addition, the driving force to minimize coke make has been accelerated by the worsening quality of crude oils. As vacuum resid feedstocks become heavier, contaminants in coke such as sulfur and metals are increased, making the coke less marketable. In the case of an existing coker which is capacity limited by coke make, a reduction in coke yield can be quite valuable. This paper discusses the design features and presents the economics associated with building a low pressure delayed coker with a 15 psig coke drum operating pressure versus a more conventional 25 psig design.

Bansal, B.B.; Moretta, J.C.; Gentry, A.R. (M.W. Kellogg Co., Houston, TX (United States))

1993-01-01T23:59:59.000Z

207

Processing mixed-waste compressed-gas cylinders at the Oak Ridge Reservation  

Science Conference Proceedings (OSTI)

Until recently, several thousand kilograms of compressed gases were stored at the Oak Ridge Reservation (ORR), in Oak Ridge, Tennessee, because these cylinders could not be taken off-site in their state of configuration for disposal. Restrictions on the storage of old compressed-gas cylinders compelled the Waste Management Organization of Lockheed Martin Energy Systems, Inc. (LMES) to dispose of these materials. Furthermore, a milestone in the ORR Site Treatment Plan required repackaging and shipment off-site of 21 cylinders by September 30, 1997. A pilot project, coordinated by the Chemical Technology Division (CTD) at the Oak Ridge National Laboratory (ORNL), was undertaken to evaluate and recontainerize or neutralize these cylinders, which are mixed waste, to meet that milestone. Because the radiological component was considered to be confined to the exterior of the cylinder, the contents (once removed from the cylinder) could be handled as hazardous waste, and the cylinder could be handled as low-level waste (LLW). This pilot project to process 21 cylinders was important because of its potential impact. The successful completion of the project provides a newly demonstrated technology which can now be used to process the thousands of additional cylinders in inventory across the DOE complex. In this paper, many of the various aspects of implementing this project, including hurdles encountered and the lessons learned in overcoming them, are reported.

Morris, M.I.; Conley, T.B.; Osborne-Lee, I.W.

1998-05-01T23:59:59.000Z

208

Vibrated Bulk Density (VBD) of Calcined Petroleum Coke and ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Vibrated bulk density (VBD) is a quantitative measurement used in the aluminum industry to evaluate the density of calcined petroleum coke.

209

Impurity Removal from Petroleum Coke - Programmaster.org  

Science Conference Proceedings (OSTI)

Presentation Title, Impurity Removal from Petroleum Coke. Author(s), Alexandre Gagnon, Hans Darmstadt, Nigel Backhouse, Esme Ryan, Laurence Dyer, David ...

210

Vibrated Bulk Density (VBD) of Calcined Petroleum Coke and ...  

Science Conference Proceedings (OSTI)

Presentation Title, Vibrated Bulk Density (VBD) of Calcined Petroleum Coke and Implications of Changes in the ASTM Method D4292. Author(s), Bill Spencer, ...

211

Influence of Petroleum Coke Sulphur Content on the Sodium ... - TMS  

Science Conference Proceedings (OSTI)

Feb 1, 1993 ... Influence of Petroleum Coke Sulphur Content on the Sodium Sensitivity of Carbon Anodes by S.M. Hume ... TMS Student Member price: 0.00.

212

Coking is a refinery process that produces 19% of finished ...  

U.S. Energy Information Administration (EIA)

Financial market analysis and financial data ... hydraulically cutting the coke using water. ... to a heater as a fluidized solid where some of it is ...

213

Determination of Coke Calcination Level and Anode Baking Level  

Science Conference Proceedings (OSTI)

Presentation Title, Determination of Coke Calcination Level and Anode Baking Level – Application and Reproducibility of Lc Based Methods. Author(s), Stein ...

214

Use of Coal Tar Pitch Coke for Producing Prebaked Electrodes  

Science Conference Proceedings (OSTI)

The study was conducted in order to (1) find an alternative material to petroleum coke due to its high cost and deteriorating properties, and (2) determine the ...

215

Modélisation thermomécanique d'un piédroit de four à coke.  

E-Print Network (OSTI)

??Inscrite dans le cadre du projet européen Coke Oven Operating Limits, cette thèse porte sur la modélisation thermomécanique d'un piédroit de cokerie. Le piédroit est… (more)

Landreau, Matthieu

2009-01-01T23:59:59.000Z

216

Discrete Element Method Applied to the Vibration Process of Coke ...  

Science Conference Proceedings (OSTI)

In the present work, effects of particle shape and size distribution on vibrated bulk density (VBD) of dry coke samples have been investigated. Discrete Element ...

217

Increasing Coke Impurities – Is this Really a Problem for Metal ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Increases in the Vanadium and Nickel content of anode grade coke in recent years have predictably affected smelter metal quality. This has now ...

218

Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas  

SciTech Connect

The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). 3) The Project will annually produce 365,292 MWh?s of clean energy. 4) By destroying the methane in the landfill gas, the Project will generate CO{sub 2} equivalent reductions of 164,938 tons annually. The completed facility produces 28.3 MWnet and operates 24 hours a day, seven days a week.

Galowitz, Stephen

2013-06-30T23:59:59.000Z

219

The utilization of flue gas desulfurization waste by-products in construction brick  

E-Print Network (OSTI)

Millions of tons of waste by-products from Texas coal burning plants are produced each year. Two common byproducts are the fuel ashes and calcium sulfate (gypsum). Fuel ashes result from the burning of coal. Gypsum is a byproduct of the air purification system, called Flue Gas Desulfurization (FGD). Abatement of these waste products is a growing concern, not only for the industry, but the environment as well. It is possible to produce a gypsum brick unit that can meet the engineering properties required by the Americans Society of Testing Materials (ASTM) standards by using these by-products. This can be accomplished at a cost less than the least expensive common fired clay brick that is used in construction operations. The gypsum brick can be manufactured using established methods that are currently in operation.

Berryman, Charles Wayne

1992-01-01T23:59:59.000Z

220

Title I preliminary engineering for: A. S. E. F. solid waste to methane gas  

DOE Green Energy (OSTI)

An assignment to provide preliminary engineering of an Advanced System Experimental Facility for production of methane gas from urban solid waste by anaerobic digestion is documented. The experimental facility will be constructed on a now-existing solid waste shredding and landfill facility in Pompano Beach, Florida. Information is included on: general description of the project; justification of basic need; process design; preliminary drawings; outline specifications; preliminary estimate of cost; and time schedules for design and construction of accomplishment of design and construction. The preliminary cost estimate for the design and construction phases of the experimental program is $2,960,000, based on Dec. 1975 and Jan. 1976 costs. A time schedule of eight months to complete the Detailed Design, Equipment Procurement and the Award of Subcontracts is given.

None

1976-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Support and control system of the Waste Isolation Pilot Plant gas generation experiment glovebox  

SciTech Connect

A glovebox was designed and fabricated to house test containers loaded with contact handled transuranic (CH-TRU) waste. The test containers were designed to simulate the environmental characteristics of the caverns at the Waste Isolation Pilot Plant (WIPP). The support and control systems used to operate and maintain the Gas Generation Experiment (GGE) include the following: glovebox atmosphere and pressure control, test container support, glovebox operation support, and gas supply and exhaust systems. The glovebox atmosphere and pressure control systems consist of various components used to control both the pressure and quality of the argon atmosphere inside the glovebox. The glovebox pressure is maintained by three separate pressure control systems. The primary pressure control system is designed to maintain the glovebox at a negative pressure with the other two control systems serving as redundant safety backups. The quality of the argon atmosphere is controlled using a purifying bed system that removes oxygen and moisture. Glovebox atmosphere contaminants that are monitored on a continuous or periodic basis include moisture, oxygen, and nitrogen. The gas generation experiment requires the test containers to be filled with brine, leak tested, maintained at a constant temperature, and the gas head space of the test container sampled on a periodic basis. Test container support systems consisting of a brine addition system, leak test system, heating system, and gas sampling system were designed and implemented. A rupture disk system was constructed to provide pressure relief to the test containers. Operational requirements stipulated that test container temperature and pressure be monitored and collected on a continuous basis. A data acquisition system (DAS) was specifically designed to meet these requirements.

Benjamin, W.W.; Knight, C.J.; Michelbacher, J.A.; Rosenberg, K.E.

1997-09-01T23:59:59.000Z

222

Uncertainty and sensitivity analyses for gas and brine migration at the Waste Isolation Pilot Plant, May 1992  

SciTech Connect

Uncertainty and sensitivity analysis techniques based on Latin hypercube sampling, partial correlation analysis, stepwise regression analysis and examination of scatterplots are used in conjunction with the BRAGFLO model to examine two phase flow (i.e., gas and brine) at the Waste Isolation Pilot Plant (WIPP), which is being developed by the US Department of Energy as a disposal facility for transuranic waste. The analyses consider either a single waste panel or the entire repository in conjunction with the following cases: (1) fully consolidated shaft, (2) system of shaft seals with panel seals, and (3) single shaft seal without panel seals. The purpose of this analysis is to develop insights on factors that are potentially important in showing compliance with applicable regulations of the US Environmental Protection Agency (i.e., 40 CFR 191, Subpart B; 40 CFR 268). The primary topics investigated are (1) gas production due to corrosion of steel, (2) gas production due to microbial degradation of cellulosics, (3) gas migration into anhydrite marker beds in the Salado Formation, (4) gas migration through a system of shaft seals to overlying strata, and (5) gas migration through a single shaft seal to overlying strata. Important variables identified in the analyses include initial brine saturation of the waste, stoichiometric terms for corrosion of steel and microbial degradation of cellulosics, gas barrier pressure in the anhydrite marker beds, shaft seal permeability, and panel seal permeability.

Helton, J.C. [Arizona State Univ., Tempe, AZ (United States); Bean, J.E. [New Mexico Engineering Research Inst., Albuquerque, NM (United States); Butcher, B.M. [Sandia National Labs., Albuquerque, NM (United States); Garner, J.W.; Vaughn, P. [Applied Physics, Inc., Albuquerque, NM (United States); Schreiber, J.D. [Science Applications International Corp., Albuquerque, NM (United States); Swift, P.N. [Tech Reps, Inc., Albuquerque, NM (United States)

1993-08-01T23:59:59.000Z

223

Dry purification of aspirational air in coke-sorting systems with wet slaking of coke  

Science Conference Proceedings (OSTI)

Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

224

SNG or syn-gas from wet solid waste and low grade fuels  

SciTech Connect

The substitute natural gas (SNG) or a synthesis gas (syngas) is prepared by partly oxidizing wastes and low-grade fuels (peat, lignite, many forms of biomass) containing 0.5-30 times as much water as the dry solids with O or air at 240-300/sup 0/C and 70-100 atmospheres. Sulfur in high S coal is oxidized selectively to SO/sub 4//sup -2/, and the heat to bring the combustible to the necessary temperature is supplied by burning part of the combustible itself. The residual solids (now 70-95% of the original fuel) are mechanically separated from all but 0.5-2 lb water. These solids come from the dewatering unit at a high pressure and may be passed, without loss of pressure or temperature to be gasified in conventional processes and gasifiers by partial oxidation.

Othmer, D.F.

1981-02-17T23:59:59.000Z

225

Adsorptive removal of nitrogen from coal-based needle coke feedstocks using activated carbon.  

E-Print Network (OSTI)

??A low percentage of nitrogen in needle coke feedstocks is desired for the reduction of puffing during the process of graphitization of needle coke. The… (more)

Madala, Sreeja.

2009-01-01T23:59:59.000Z

226

Prediction of Coke Quality in Ironmaking Process: A Data Mining Approach.  

E-Print Network (OSTI)

??Coke is an indispensable material in Ironmaking process by blast furnace. To provide good and constant quality coke for stable and efficient blast furance operation… (more)

Hsieh, Hsu-huang

2006-01-01T23:59:59.000Z

227

Combination gas-producing and waste-water disposal well. [DOE patent application  

DOE Patents (OSTI)

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Malinchak, R.M.

1981-09-03T23:59:59.000Z

228

Hydrogen Gas Generation Model for Fuel-Based Remote-Handled Transuranic Waste Stored at the INEEL  

DOE Green Energy (OSTI)

The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

Khericha, S.; Bhatt, R.; Liekhus, K.

2003-01-14T23:59:59.000Z

229

Hydrogen production from food wastes and gas post-treatment by CO{sub 2} adsorption  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer The dark fermentation process of food wastes was studied over an extended period. Black-Right-Pointing-Pointer Decreasing the HRT of the process negatively affected the specific gas production. Black-Right-Pointing-Pointer Adsorption of CO{sub 2} was successfully attained using a biomass type activated carbon. Black-Right-Pointing-Pointer H{sub 2} concentration in the range of 85-95% was obtained for the treated gas-stream. - Abstract: The production of H{sub 2} by biological means, although still far from being a commercially viable proposition, offers great promise for the future. Purification of the biogas obtained may lead to the production of highly concentrated H{sub 2} streams appropriate for industrial application. This research work evaluates the dark fermentation of food wastes and assesses the possibility of adsorbing CO{sub 2} from the gas stream by means of a low cost biomass-based adsorbent. The reactor used was a completely stirred tank reactor run at different hydraulic retention times (HRTs) while the concentration of solids of the feeding stream was kept constant. The results obtained demonstrate that the H{sub 2} yields from the fermentation of food wastes were affected by modifications in the hydraulic retention time (HRT) due to incomplete hydrolysis. The decrease in the duration of fermentation had a negative effect on the conversion of the substrate into soluble products. This resulted in a lower amount of soluble substrate being available for metabolisation by H{sub 2} producing microflora leading to a reduction in specific H{sub 2} production. Adsorption of CO{sub 2} from a gas stream generated from the dark fermentation process was successfully carried out. The data obtained demonstrate that the column filled with biomass-derived activated carbon resulted in a high degree of hydrogen purification. Co-adsorption of H{sub 2}S onto the activated carbon also took place, there being no evidence of H{sub 2}S present in the bio-H{sub 2} exiting the column. Nevertheless, the concentration of H{sub 2}S was very low, and this co-adsorption did not affect the CO{sub 2} capture capacity of the activated carbon.

Redondas, V. [Chemical Engineering Department, University of Leon, IRENA-ESTIA, Avda. de Portugal 41, Leon 24071 (Spain); Gomez, X., E-mail: xagomb@unileon.es [Chemical Engineering Department, University of Leon, IRENA-ESTIA, Avda. de Portugal 41, Leon 24071 (Spain); Garcia, S.; Pevida, C.; Rubiera, F. [Instituto Nacional del Carbon, CSIC, Apartado 73, 33080 Oviedo (Spain); Moran, A. [Chemical Engineering Department, University of Leon, IRENA-ESTIA, Avda. de Portugal 41, Leon 24071 (Spain); Pis, J.J. [Instituto Nacional del Carbon, CSIC, Apartado 73, 33080 Oviedo (Spain)

2012-01-15T23:59:59.000Z

230

Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery  

Science Conference Proceedings (OSTI)

Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25-207 kg CO{sub 2}-eq t{sup -1} rw. Within all process stages, the emission of fossil CO{sub 2} from the combustion of MSW was the main contributor (111-254 kg CO{sub 2}-eq t{sup -1} rw), while the substitution of electricity reduced the GHG emissions by 150-247 kg CO{sub 2}-eq t{sup -1} rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.

Yang Na [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Zhang Hua, E-mail: zhanghua_tj@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Chen Miao; Shao Liming [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); He Pinjing, E-mail: xhpjk@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China)

2012-12-15T23:59:59.000Z

231

Two phase partially miscible flow and transport modeling in porous media: application to gas migration in a nuclear waste repository  

E-Print Network (OSTI)

We derive a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological repository for radioactive waste. This model includes capillary effects and the gas high diffusivity. Moreover, it is written in variables (total hydrogen mass density and liquid pressure) chosen in order to be consistent with gas appearance or disappearance. We discuss the well possedness of this model and give some computational evidences of its adequacy to simulate gas generation in a water saturated repository.

Alain Bourgeat; Mladen Jurak; Farid Smaï

2008-02-29T23:59:59.000Z

232

A literature review of radiolytic gas generation as a result of the decomposition of sodium nitrate wastes  

DOE Green Energy (OSTI)

The objective of this literature review is to determine expected chemical reactions and the gas generation associated with radiolytic decomposition of radioactive sodium nitrate wastes such as the wastes stored in the Melton Valley Storage Tanks (MVST) at Oak Ridge National Laboratory (ORNL). The literature survey summarizes expected chemical reactions and identifies the gases expected to be generated as a result of the radiolytic decomposition. The literature survey also identifies G values, which are the expression for radiation chemical yields as molecules of gas formed per 100 eV of absorbed energy, obtained from experimental studies of the radiolytic decomposition of water and sodium nitrate. 2 tabs., 32 refs.

Kasten, J.L.

1991-01-01T23:59:59.000Z

233

Coke profile and effect on methane/ethylene conversion process  

E-Print Network (OSTI)

The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were conducted using the Engelhard catalyst with fixed operating conditions. The only variable was the time on stream of each run. Six experiments were conducted starting with one hour time on stream up to six hours with an increment of one hour. In each experiment data on product flow rate, reactor temperature, and product distribution were collected. And at the end of each run, the amount of coke deposited on the catalyst was measured. Hydrogen concentration in the product distribution decreased as a function of time on stream. On the other hand, low and high end hydrocarbons increased with time on stream. The coke deposition kinetics for the catalyst at the process operating conditions can be estimated using Voorhies' empirical formula. The coke profile inside the reactor showed that the coke reaction follows a parallel mechanism to the main reaction. Ethylene was found to be the main coke precursor; however, the participation of methane in the coke reaction could not be neglected.

Al-Solami, Bandar

2002-01-01T23:59:59.000Z

234

Coke mineral transformations in the experimental blast furnace  

SciTech Connect

Blast furnace efficiency may be improved by optimizing coke reactivity. Some but not all forms of mineral matter in the coke modify its reactivity, but changes in mineral matter that occur within coke while in the blast furnace have not been fully quantified. To determine changes in mineral matter forms in the blast furnace, coke samples from a dissection study in the LKAB experimental blast furnace (EBF) were characterized using SEM/EDS analysis, EPMA (microprobe), and low-temperature ashing/quantitative XRD analysis. Variations in alkali concentration, particularly potassium, dominated the compositional changes. At high concentrations of potassium, the mineral matter was largely potassium-bearing but even more potassium was diffused throughout the coke and not associated with mineral matter. There was little difference in potassium concentration between the core and surface of the coke pieces, suggesting that potassium diffused rapidly through the whole coke. Iron, calcium, silicon, and aluminum concentrations were relatively constant in comparison, although the mineralogy of all elements changed significantly with changing temperature. 23 refs., 20 figs., 9 tabs.

Kelli Kazuberns; Sushil Gupta; Mihaela Grigore; David French; Richard Sakurovs; Mats Hallin; Bo Lindblom; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Cooperative Research Centre for Coal in Sustainable Development (CCSD)

2008-09-15T23:59:59.000Z

235

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE [SEC 1 & 2  

DOE Green Energy (OSTI)

Flammable gases such as hydrogen, ammonia, and methane are observed in the tank dome space of the Hanford Site high-level waste tanks. This report assesses the steady-state flammability level under normal and off-normal ventilation conditions in the tank dome space for 177 double-shell tanks and single-shell tanks at the Hanford Site. The steady-state flammability level was estimated from the gas concentration of the mixture in the dome space using estimated gas release rates, Le Chatelier's rule and lower flammability limits of fuels in an air mixture. A time-dependent equation of gas concentration, which is a function of the gas release and ventilation rates in the dome space, has been developed for both soluble and insoluble gases. With this dynamic model, the time required to reach the specified flammability level at a given ventilation condition can be calculated. In the evaluation, hydrogen generation rates can be calculated for a given tank waste composition and its physical condition (e.g., waste density, waste volume, temperature, etc.) using the empirical rate equation model provided in Empirical Rate Equation Model and Rate Calculations of Hydrogen Generation for Hanford Tank Waste, HNF-3851. The release rate of other insoluble gases and the mass transport properties of the soluble gas can be derived from the observed steady-state gas concentration under normal ventilation conditions. The off-normal ventilation rate is assumed to be natural barometric breathing only. A large body of data is required to do both the hydrogen generation rate calculation and the flammability level evaluation. For tank waste that does not have sample-based data, a statistical-based value from probability distribution regression was used based on data from tanks belonging to a similar waste group. This report (Revision 3) updates the input data of hydrogen generation rates calculation for 177 tanks using the waste composition information in the Best-Basis Inventory Detail Report in the Tank Waste Information Network System, and the waste temperature data in the Surveillance Analysis Computer System (SACS) (dated July 2003). However, the release rate of methane, ammonia, and nitrous oxide is based on the input data (dated October 1999) as stated in Revision 0 of this report. Scenarios for adding waste to existing waste levels (dated July 2003) have been studied to determine the gas generation rates and the effect of smaller dome space on the flammability limits to address the issues of routine water additions and other possible waste transfer operations. In the flammability evaluation with zero ventilation, the sensitivity to waste temperature and to water addition was calculated for double-shell tanks 241-AY-102, 241-AN-102,241-AZ-101,241-AN-107,241-AY-101 and 241-AZ-101. These six have the least margin to flammable conditions among 28 double-shell tanks.

HU, T.A.

2003-09-30T23:59:59.000Z

236

U.S. Exports to Saudi Arabia of Petroleum Coke (Thousand ...  

U.S. Energy Information Administration (EIA)

Petroleum Coke Exports by Destination; Saudi Arabia Exports of Crude Oil and Petroleum Products by Destination ...

237

U.S. Exports to South Africa of Petroleum Coke (Thousand ...  

U.S. Energy Information Administration (EIA)

Petroleum Coke Exports by Destination; South Africa Exports of Crude Oil and Petroleum Products by Destination ...

238

Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, and nitrogen in the gas phase; comparison of gas generation rates in supernate and solid fractions of Tank 241-SY-101 simulated waste  

DOE Green Energy (OSTI)

This report summarizes progress made in evaluating me by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using simulated waste mixtures. Work described in this report. was conducted at Pacific Northwest Laboratory (PNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT), under subcontract to PNL, using simulated wastes, and to studies being performed at VMC using actual wastes.

Bryan, S.A.; Pederson, L.R.

1995-03-01T23:59:59.000Z

239

Variation in coke properties within the blast-furnace shop  

SciTech Connect

In active production at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), samples of melt materials were taken during shutdown and during planned repairs at furnaces 1 and 8. In particular, coke was taken from the tuyere zone at different distances from the tuyere tip. The mass of the point samples was 2-15 kg, depending on the sampling zone. The material extracted from each zone underwent magnetic separation and screening by size class. The resulting coke sample was averaged out and divided into parts: one for determining the granulometric composition and mechanical strength; and the other for technical analysis and determination of the physicochemical properties of the coke.

E.N. Stepanov; I.I. Mel'nikov; V.P. Gridasov; A.A. Stepanova [OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), Magnitogorsk, (Russian Federation)

2009-04-15T23:59:59.000Z

240

Recycle/reuse of boiler chemical cleaning wastes in wet limestone flue gas desulfurization (FGD) systems  

Science Conference Proceedings (OSTI)

Boiler chemical cleaning wastes (BCCW) are generated by the periodic waterside cleaning of utility boilers to remove metallic deposits from boiler tube surfaces. Depending on boiler metallurgy, BCCW generally contain high concentrations of iron and copper or both, as well as other heavy metals such as chromium, lead, nickel, and zinc. BCCW treatment and disposal methods include precipitation, coponding in an ash pond, evaporation in the fireside of an operating boiler (for organic solvents), and contracted off-site disposal. Depending on the type of BCCW chemical treatment methods achieve varying degrees of success. BCCW which contain organic chelating agents can be especially difficult to treat to national pollutant discharge elimination system (NPDES) limits (1 mg/L for both iron and copper) with conventional lime precipitation.Research is being done to evaluate different BCCW treatment and disposal methods. One waste management option under consideration is reuse of BCCW in utility wet flue gas desulfurization (FGD) systems. To investigate this option, a series of laboratory tests were performed in which five different types of BCCW were added to the reaction tank of EPRI's bench-scale wet limestone FGD system. This paper presents the results and conclusions from this study.

Stohs, M.; Owens, D.R. (Radian Corp. (US)); Micheletti, W. (Electric Power Research Inst., Palo Alto, CA (USA))

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Methanation of gas streams containing carbon monoxide and hydrogen  

DOE Patents (OSTI)

Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

Frost, Albert C. (Congers, NY)

1983-01-01T23:59:59.000Z

242

Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel  

E-Print Network (OSTI)

Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel Digital upside in view of the power generation growth potential in Asia and the environmental friendly, cost's energy and farming centers in North America as an alternative to coal-fired power plants and a solution

Columbia University

243

Interim On-Site Storage of Low-Level Waste: Volume 4, Part 3: Waste Container Closures, Seals, and Gas Vents  

Science Conference Proceedings (OSTI)

This volume of the Interim On-Site Storage report series supplements Volume 4, Part 1, which includes an extensive methodology and detailed information on the types and availability of low-level waste (LLW) containers and container coatings for extended storage. Part 2, soon to be published, addresses monitoring and inspection requirements for stored LLW containers. Part 3 continues the series by providing detailed guidance on container closures, seals, and gas vents, including performance goals and key ...

1993-11-11T23:59:59.000Z

244

Mechanisms of gas retention and release: Experimental results for Hanford single-shell waste tanks 241-A-101, 241-S-106, and 241-U-103  

Science Conference Proceedings (OSTI)

The 177 underground waste storage tanks at the Hanford Site contain millions of gallons of radioactive waste resulting from the purification of nuclear materials and related processes. Through various mechanisms, flammable gas mixtures of hydrogen, ammonia, methane, and nitrous oxide are generated and retained in significant quantities within the waste in many ({approximately}25) of these tanks. The potential for large releases of retained gas from these wastes creates a flammability hazard. It is a critical component of the effort to understand the flammability hazard and a primary goal of this laboratory investigation to establish an understanding of the mechanisms of gas retention and release in these wastes. The results of bubble retention experimental studies using waste samples from several waste tanks and a variety of waste types support resolution of the Flammable Gas Safety Issue. Gas bubble retention information gained in the pursuit of safe storage will, in turn, benefit future waste operations including salt-well pumping, waste transfers, and sluicing/retrieval.

Rassat, S.D.; Caley, S.M.; Bredt, P.R.; Gauglitz, P.A.; Rinehart, D.E.; Forbes, S.V.

1998-09-01T23:59:59.000Z

245

Table 38. Coal Stocks at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Coal Stocks at Coke Plants by Census Division Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 38. Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Census Division June 30, 2013 March 31, 2013 June 30, 2012 Percent Change (June 30) 2013 versus 2012 Middle Atlantic w w w w East North Central 1,313 1,177 1,326 -1.0 South Atlantic w w w w East South Central w w w w U.S. Total 2,500 2,207 2,295 8.9 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants.'

246

Gulf Coast (PADD 3) Catalyst Petroleum Coke Consumed at ...  

U.S. Energy Information Administration (EIA)

Gulf Coast (PADD 3) Catalyst Petroleum Coke Consumed at Refineries (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 ...

247

Comprehensive Effect of Coke Breeze and Limestone Particle Size ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy · Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

248

U.S. Ending Stocks of Petroleum Coke (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Ending Stocks of Petroleum Coke (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9; 1980's: 4,502: ...

249

U.S. Exports of Petroleum Coke (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Exports of Petroleum Coke (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9; 1980's: 50,292: ...

250

U.S. Petroleum Coke Consumed at Refineries (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Petroleum Coke Consumed at Refineries (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9; 1980's: ...

251

U.S. Exports of Petroleum Coke (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Exports of Petroleum Coke (Thousand Barrels) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 1981: 2,754: 4,394: 3,722: 3,995: 5,211: ...

252

U.S. Petroleum Coke Stocks at Refineries (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Petroleum Coke Stocks at Refineries (Thousand Barrels) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 1993: 10,747: 11,072: 11,444: ...

253

Nippon Coke and Engineering Sumitomo Corp JV | Open Energy Information  

Open Energy Info (EERE)

and Engineering Sumitomo Corp JV Jump to: navigation, search Name Nippon Coke and Engineering & Sumitomo Corp JV Place Tokyo, Japan Zip 135-6007 Product Japan-based natural...

254

An approximate-reasoning-based method for screening high-level waste tanks for flammable gas  

DOE Green Energy (OSTI)

The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at Hanford have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop an improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. AR models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. The authors performed a pilot study to investigate the utility of AR for flammable gas screening. They found that the effort to implement such a model was acceptable and that computational requirements were reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts.

Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

1998-07-01T23:59:59.000Z

255

Flammable Gas Release Estimates for Modified Sluicing Retrieval of Waste from Selected Hanford Single-Shell Tanks  

DOE Green Energy (OSTI)

The high-level radioactive wastes in many single-shell tanks (SSTs) at the Hanford Site are to be retrieved by a modified sluicing method that uses water jets to dissolve the water-soluble waste and mobilize the water-insoluble waste. Retrieval operations will liberate any waste gases trapped in the wetted solid waste matrix, and these gases will be released into the tank headspaces. Because the trapped gases include the flammable species hydrogen, methane, and ammonia, a concern exists that a flammable mixture could be formed in the tank headspaces. This report combines conservative retained gas inventory estimates and tank data with anticipated waste retrieval rates to estimate the potential headspace flammability of selected SSTs during modified sluicing waste retrieval operations. Considered here are nine of the 12 tanks from the 241-S tank farm (241-S-107, 241-S-111, and 241-S 112 are not considered) and Tank 241-U-107. This report is intended to support the specification of process controls that ensure flammable conditions do not develop in the tank headspaces. Consequently, the physical scenarios considered, the models developed to estimate retained gas releases and the tank headspace compositions under these scenarios, and the model input data are intended to conservatively assess the potential to reach headspace flammability. The analyses are intended to address worst-case conditions and establish reasonable upper bounds on the achievable flammability of the tank headspaces. Flammable retained gas inventories, for example, are based on the 95th percentile developed by Barker and Hedengren (2003), giving 95% confidence that actual inventories are smaller than those used in the calculations. Gas releases and headspace flammability were evaluated for three general scenarios: a very aggressive dissolution and erosion of saltcake waste by water jets impinging on the waste surface, the drainage of interstitial liquids from saltcake during a shutdown of the retrieval process, and the dissolution of saltcake by unsaturated liquids during a shutdown of the retrieval process. The simple model of waste retrieval using the modified sluicing approach indicated that the flammable gas headspace concentrations can rapidly approach the action level of 25% of the lower flammability limit (LFL) when the tank is passively ventilated. While it is not necessary to use the portable exhauster to maintain the headspace hydrogen concentration below this action level, retrieval rates would probably be limited by the slow removal of flammable gases by passive ventilation. It was determined that using a portable exhauster anywhere in the assumed operating range of 270 to 475 cfm would prevent the headspaces from reaching the 25% of LFL action level even if the water jets are very effective at eroding the saltcake. Specific guidelines are developed to ensure that, in the event of a catastrophic loss of the retrieval pump and portable exhauster, headspace flammability will not reach the LFL. This report is Revision 1 of PNNL-14271. This revision expands the analysis of interstitial liquid drainage-induced gas releases to address a general retrieval scenario (the previous version of this report assumed a center-out retrieval approach and conditions). Tank waste conditions (waste volumes, interstitial liquid levels, temperatures, retained gas void fractions, etc.) have also been updated from the previous version.

Huckaby, James L.; Wells, Beric E.

2004-03-05T23:59:59.000Z

256

Flammable Gas Release Estimates for Modified Sluicing Retrieval of Waste from Selected Hanford Single-Shell Tanks  

DOE Green Energy (OSTI)

The high-level radioactive wastes in many single-shell tanks (SSTs) at the Hanford Site are to be retrieved by a modified sluicing method. Retrieval operations will hydraulically erode and dissolve the saltcake waste, and the resulting brine will then be pumped to a double-shell tank (DST). Waste gases residing in the solid waste matrix will be released into the tank headspace when the matrix is eroded or dissolved. These retained waste gases include the flammable species hydrogen, methane, and ammonia, and there is a concern that these flammable gases could produce a flammable mixture in the tank headspaces during the retrieval operations. This report combines conservative retained gas inventory estimates and tank data with anticipated waste retrieval rates to estimate the potential headspace flammability of selected SSTs during waste retrieval operations. The SSTs considered here are ten of the twelve 241-S farm tanks (tanks 241-S-107 and 241-S-111 are excluded from consideration here) and tank 241-U-107 (U-107).

Huckaby, James L.; Wells, Beric E.

2003-05-13T23:59:59.000Z

257

NEW TRENDS IN FLUE GAS CLEANING TECHNOLOGIES FOR EUROPEAN AND ASIAN WASTE INCINERATION FACILITIES  

E-Print Network (OSTI)

Organic Compound TCLP EPA Toxicity Characteristic Leaching Procedure TRU Transuranic Waste VOC Volatile

Columbia University

258

Clostridium stain which produces acetic acid from waste gases  

DOE Patents (OSTI)

A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

1997-01-01T23:59:59.000Z

259

Clostridium strain which produces acetic acid from waste gases  

DOE Patents (OSTI)

A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

Gaddy, J.L.

1997-01-14T23:59:59.000Z

260

An example of alkalization of SiO{sub 2} in a blast furnace coke  

SciTech Connect

Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

2007-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Waste tank 241-SY-101 dome airspace and ventilation system response to a flammable gas plume burn  

SciTech Connect

A series of flammable gas plume burn and transient pressure analyses have been completed for a nuclear waste tank (241-SY-101) and associated tank farm ventilation system at the U.S. Department of Energy`s Hanford facility. The subject analyses were performed to address issues concerning the effects of transient pressures resulting from igniting a small volume of concentrated flammable gas just released from the surface of the waste as a plume and before the flammable gas concentration could be reduced by mixing with the dome airspace by local convection and turbulent diffusion. Such a condition may exist as part of an in progress episode gas release (EGR) or gas plume event. The analysis goal was to determine the volume of flammable gas that if burned within the dome airspace would result in a differential pressure, after propagating through the ventilation system, greater than the current High Efficiency Particulate Filter (HEPA) limit of 2.49 KPa (10 inches of water or 0. 36 psi). Such a pressure wave could rupture the tank ventilation system inlet and outlet HEPA filters leading to a potential release of contaminants to the environment

Heard, F.J.

1995-11-01T23:59:59.000Z

262

Wetland treatment of oil and gas well waste waters. Final report  

SciTech Connect

Constructed wetlands are small on-site systems that possess three of the most desirable components of an industrial waste water treatment scheme: low cost, low maintenance and upset resistance. The main objective of the present study is to extend the knowledge base of wetland treatment systems to include processes and substances of particular importance to small, on-site systems receiving oil and gas well wastewaters. A list of the most relevant and comprehensive publications on the design of wetlands for water quality improvement was compiled and critically reviewed. Based on our literature search and conversations with researchers in the private sector, toxic organics such as Phenolics and b-naphthoic acid, (NA), and metals such as CU(II) and CR(VI) were selected as target adsorbates. A total of 90 lysimeters equivalent to a laboratory-scale wetland were designed and built to monitor the uptake and transformation of toxic organics and the immobilization of metal ions. Studies on the uptake of toxic organics such as phenol and b-naphthoic acid (NA) and heavy metals such as Cu(II) and Cr(VI), the latter two singly or as non-stoichiometric mixtures by laboratory-type wetlands (LWs) were conducted. These LWs were designed and built during the first year of this study. A road map and guidelines for a field-scale implementation of a wetland system for the treatment of oil and gas wastewaters have been suggested. Two types of wetlands, surface flow (SF) and sub surface flow (SSF), have been considered, and the relative merits of each configuration have been reviewed.

Kadlec, R.; Srinivasan, K.

1995-08-01T23:59:59.000Z

263

Prediction of metallurgical coke strength from the petrographic composition of coal blends  

Science Conference Proceedings (OSTI)

Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

2009-07-01T23:59:59.000Z

264

The potential for buoyant displacement gas release events in Tank 241-SY-102 after waste transfer from Tank 241-SY-101  

DOE Green Energy (OSTI)

Tank 241-SY-101 (SY-101) is a double-shell, radioactive waste storage tank with waste that, before the recent transfer and water back-dilution operations, was capable of retaining gas and producing buoyant displacement (BD) gas release events (GREs). Some BD GREs caused gas concentrations in the tank headspace to exceed the lower flammability limit (LFL). A BD GRE occurs when a portion of the nonconvective layer retains enough gas to become buoyant, rises to the waste surface, breaks up, and releases some of its stored gas. The installation of a mixer pump in 1993 successfully mitigated gas retention in the settled solids layer in SY-101 and has since prevented BD GREs. However, operation of the mixer pump over the years caused gas retention in the floating crust layer and a corresponding accelerated waste level growth. The accelerating crust growth trend observed in 1997--98 led to initiation of sequences of waste removal and water back-dilutions in December 1999. Waste is removed from the mixed slurry layer in Tank SY-101 and transferred into Tank 241-Sy-102 (SY-102). Water is then added back to dissolve soluble solids that retain gas. The initial transfer of 89,500 gallons of SY-101 waste, diluted in-line at 0.94:1 by volume with water, to SY-102 was conducted in December 1999. The second transfer of 230,000 gallons of original SY-101 waste, diluted approximately 0.9:1, was completed in January 2000, and the third transfer of 205,500 gallons of original SY-101 waste diluted at 0.9:1 was completed in March 2000.

BE Wells; PE Meyer; G Chen

2000-05-10T23:59:59.000Z

265

Water-Steel Canister Interaction and H2 Gas Pressure Buildup in aNuclear Waste Repository  

DOE Green Energy (OSTI)

Corrosion of steel canisters, stored in a repository forspent fuel and high-level waste, leads to hydrogen gas generation in thebackfilled emplacement tunnels, which may significantly affect long-termrepository safety. Previous modeling studies used a constant H2generation rate. However, iron corrosion and H2 generation rates varywith time, depending on factors such as water chemistry, wateravailability, and water contact area. To account for these factors andfeedback mechanisms, we developed a chemistry model related to ironcorrosion, coupled with two-phase (liquid and gas) flow phenomena thatare driven by gas pressure buildup and water consumption. Resultsindicate that if H2 generation rates are dynamically calculated based ona chemistry model, the degree and extent of gas pressure buildup are muchsmaller compared to a simulation in which the coupling between flow andreactive transport mechansism is neglected.

Xu, Tianfu; Senger, Rainer; Finstele, Stefan

2007-01-02T23:59:59.000Z

266

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

Science Conference Proceedings (OSTI)

This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for all 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 11 days for DSTs (i.e., tank 241-AZ-10l) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 10 days for DSTs (i.e., tank 241-AZ-101) and 34 days for SSTs (i.e., tank 241-B-203).

MEACHAM JE

2009-10-26T23:59:59.000Z

267

STEADY-STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The methodology of flammability analysis for Hanford tank waste is developed. The hydrogen generation rate model was applied to calculate the gas generation rate for 177 tanks. Flammability concentrations and the time to reach 25% and 100% of the lower flammability limit, and the minimum ventilation rate to keep from 100 of the LFL are calculated for 177 tanks at various scenarios.

HU TA

2007-10-26T23:59:59.000Z

268

A New Approach to Investigating Coke Reactivity  

Science Conference Proceedings (OSTI)

Decomposition of methane during oxide reduction using Natural gas · DELIVERING ... Reaction mechanism and reaction rate of Sn evaporation from liquid steel.

269

Hydrogen-Rich Gas Production from Steam Gasification of Palm Oil Wastes Using the Supported Nano-NiO/?-Al2O3 Catalyst  

Science Conference Proceedings (OSTI)

The catalytic steam gasification of palm oil wastes for hydrogen-rich gas production was experimentally investigated in a combined fixed bed reactor using the newly developed nano-NiO/?-Al2O3 catalyst. The results indicated that the nano-NiO/?-Al2O3 ... Keywords: Biomass gasification, palm oil waste, catalyst, hydrogen production

Jianfen Li; Yanfang Yin; Jianjun Liu; Rong Yan

2009-10-01T23:59:59.000Z

270

Gas generation and migration studies involving recently generated /sup 238/Pu-contaminated waste for the TRU Waste Sampling Program  

DOE Green Energy (OSTI)

This study is part of the multicontractor TRU Waste Sampling Program. Radiolytically generated gases were vented through a filtering device to determine its effectiveness in maintaining hydrogen concentrations within acceptably safe levels. In the second part of the study measurements were made to determine the ability of these gases, particularly hydrogen, to migrate through a sealed rigid polyethylene drum liner. Void volumes in these drums were found to be generally in excess of 90%. The carbon composite filter was found to satisfactorily vent hydrogen up to moderately high levels of alpha activity in the waste substrate. The sealed 90-mil liner was found to inhibit, but not prevent, the migration of hydrogen and other radiolytically generated gases.

Zerwekh, A.; Warren, J.L.

1986-07-01T23:59:59.000Z

271

Hydrodesulfurization of Fluid Catalytic Cracking Decant Oils for the Production of Low-sulfur Needle Coke Feedstocks.  

E-Print Network (OSTI)

??Needle coke, produced by the delayed coking of fluid catalytic cracking decant oils, is the primary filler used in the production of graphite electrodes. The… (more)

Wincek, Ronald

2013-01-01T23:59:59.000Z

272

Urinary 1-hydroxypyrene in nonsmokers: a biomarker for coke smoke exposure and general urban PAH exposure.  

E-Print Network (OSTI)

??This dissertation research examined the validity of urinary 1-OHP as a biomarker of PAH for coke production workers and non-coke oven workers in Anshan City,… (more)

Han, In-Kyu

2008-01-01T23:59:59.000Z

273

Commercialization of waste gob gas and methane produced in conjunction with coal mining operations. Final report, August 1992--December 1993  

Science Conference Proceedings (OSTI)

The primary objectives of the project were to identify and evaluate existing processes for (1) using gas as a feedstock for production of marketable, value-added commodities, and (2) enriching contaminated gas to pipeline quality. The following gas conversion technologies were evaluated: (1) transformation to liquid fuels, (2) manufacture of methanol, (3) synthesis of mixed alcohols, and (4) conversion to ammonia and urea. All of these involved synthesis gas production prior to conversion to the desired end products. Most of the conversion technologies evaluated were found to be mature processes operating at a large scale. A drawback in all of the processes was the need to have a relatively pure feedstock, thereby requiring gas clean-up prior to conversion. Despite this requirement, the conversion technologies were preliminarily found to be marginally economic. However, the prohibitively high investment for a combined gas clean-up/conversion facility required that REI refocus the project to investigation of gas enrichment alternatives. Enrichment of a gas stream with only one contaminant is a relatively straightforward process (depending on the contaminant) using available technology. However, gob gas has a unique nature, being typically composed of from constituents. These components are: methane, nitrogen, oxygen, carbon dioxide and water vapor. Each of the four contaminants may be separated from the methane using existing technologies that have varying degrees of complexity and compatibility. However, the operating and cost effectiveness of the combined system is dependent on careful integration of the clean-up processes. REI is pursuing Phase 2 of this project for demonstration of a waste gas enrichment facility using the approach described above. This is expected to result in the validation of the commercial and technical viability of the facility, and the refinement of design parameters.

Not Available

1993-12-01T23:59:59.000Z

274

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report  

DOE Green Energy (OSTI)

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOE's Environmental Management (EM) organizations to address gas generation concerns. This paper presents a ''program level'' roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

Luke, D.E. (INEEL); Hamp, S. (DOE-Albuquerque Operations Office)

2002-01-04T23:59:59.000Z

275

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report  

SciTech Connect

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOE's Environmental Management (EM) organizations to address gas generation concerns. This paper presents a ''program level'' roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

Luke, D.E. (INEEL); Hamp, S. (DOE-Albuquerque Operations Office)

2002-01-04T23:59:59.000Z

276

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report  

SciTech Connect

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen- containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOE’s Environmental Management (EM) organizations to address gas generation concerns. This paper presents a "program level" roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

Luke, Dale Elden; Hamp, S.

2002-02-01T23:59:59.000Z

277

Role of Anti Foam Agent in Gas Retention and Release in Waste ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The Hanford Tank Waste Treatment and Immobilization Plant ( WTP), which is being designed and constructed for the U.S. Department of Energy ...

278

The Iron Age & Coal-based Coke: A Neglected Case of Fossil-fuel Dependence  

E-Print Network (OSTI)

The Iron Age & Coal-based Coke: A Neglected Case of Fossil-fuel Dependence by Vaclav Smil September share of their primary energies from renewable sources. Steel & Coal-Derived Coke Here is another important: steel's fundamental dependence on coal-derived coke with no practical substitutes on any rational

Smil, Vaclav

279

Co-combustion Character of Oil Shale and Its Semi-coke on CFB Bench  

Science Conference Proceedings (OSTI)

Semi-coke is by-product from oil shale retorts and it is important to burn it in CFB furnace. But limited to the inflammable combustion traits, co-combustion of semi-coke with raw oil shale would be meaningful. Experimental research on co-combustion ... Keywords: combustion, distribution, semi-coke, temperature

Sun Baizhong; Huang Zhirong

2011-08-01T23:59:59.000Z

280

Final Report - Gas Generation Testing of Uranium Metal in Simulated K Basin Sludge and in Grouted Sludge Waste Forms  

DOE Green Energy (OSTI)

The Waste Isolation Pilot Plant (WIPP) is being considered for the disposal of K Basin sludge as RH-TRU. Because the hydrogen gas concentration in the 55-gallon RH-TRU sealed drums to be transported to WIPP is limited by flammability safety, the number of containers and shipments likely will be driven by the rate of hydrogen generated by the uranium metal-water reaction (U + 2 H{sub 2}O {yields} UO{sub 2} + 2 H{sub 2}) in combination with the hydrogen generated from water and organic radiolysis. Gas generation testing was conducted with uranium metal particles of known surface area, in simulated K West (KW) Basin canister sludge and immobilized in candidate grout solidification matrices. This study evaluated potential for Portland cement and magnesium phosphate grouts to inhibit the reaction of water with uranium metal in the sludge and thereby permit higher sludge loading to the disposed waste form. The best of the grouted waste forms decreased the uranium metal-water reaction by a factor of four.

Delegard, Calvin H.; Schmidt, Andrew J.; Sell, Rachel L.; Sinkov, Sergei I.; Bryan, Samuel A.; Gano, Sue; Thornton, Brenda M.

2004-08-19T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Mechanisms of gas bubble retention and release: results for Hanford Waste Tanks 241-S-102 and 241-SY-103 and single-shell tank simulants  

DOE Green Energy (OSTI)

Research at Pacific Northwest National Laboratory (PNNL) has probed the physical mechanisms and waste properties that contribute to the retention and release of flammable gases from radioactive waste stored in underground tanks at Hanford. This study was conducted for Westinghouse Hanford Company as part of the PNNL Flammable Gas Project. The wastes contained in the tanks are mixes of radioactive and chemical products, and some of these wastes are known to generate mixtures of flammable gases, including hydrogen, nitrous oxide, and ammonia. Because these gases are flammable, their retention and episodic release pose a number of safety concerns.

Gauglitz, P.A.; Rassat, S.D.; Bredt, P.R.; Konynenbelt, J.H.; Tingey, S.M.; Mendoza, D.P.

1996-09-01T23:59:59.000Z

282

Table 33. Coal Carbonized at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Coal Carbonized at Coke Plants by Census Division Coal Carbonized at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 33. Coal Carbonized at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Census Division April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change Middle Atlantic w w w w w w East North Central 3,051 2,997 3,092 6,048 6,156 -1.8 South Atlantic w w w w w w East South Central w w w w w w U.S. Total 5,471 5,280 5,296 10,751 10,579 1.6 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants

283

Table 23. Coal Receipts at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Receipts at Coke Plants by Census Division Receipts at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 23. Coal Receipts at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Census Division April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change Middle Atlantic w w w w w w East North Central 3,189 2,679 3,225 5,867 5,993 -2.1 South Atlantic w w w w w w East South Central w w w w w w U.S. Total 5,770 4,962 5,370 10,732 10,440 2.8 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants

284

The development of coke smelting and the industrial revolution  

E-Print Network (OSTI)

Abraham Darby and the origins of the industrial revolution in Britain. Alan Macfarlane talks to John about the reasons for the area near Birmingham becoming the epi-centre of the industrial development, and the development of coke furnaces and iron...

Macfarlane, Alan

2004-08-05T23:59:59.000Z

285

U.S. Refinery Yield of Petroleum Coke (Percent)  

U.S. Energy Information Administration (EIA)

U.S. Refinery Yield of Petroleum Coke (Percent) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9; 1990's: 4.3: 4.3: 4.3: ...

286

U.S. Refinery Yield of Petroleum Coke (Percent)  

U.S. Energy Information Administration (EIA)

U.S. Refinery Yield of Petroleum Coke (Percent) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 1993: 4.4: 4.6: 4.5: 4.3: 4.1: 4.2: 4.4: 4.3: ...

287

Novel selective surface flow (SSF{sup TM}) membranes for the recovery of hydrogren from waste gas streams. Final report  

DOE Green Energy (OSTI)

The waste streams are off-gas streams from various chemical/refinery operations. In Phase I, the architecture of the membrane and the separation device were defined and demonstrated. The system consists of a shell-and-tube separator in which the gas to be separated is fed to the tube side, the product is collected as high pressure effluent and the permeate constitutes the waste/fuel stream. Each tube, which has the membrane coated on the interior, does the separation. A multi- tube separator device containing 1 ft{sup 2} membrane area was built and tested. The engineering data were used for designing a process for hydrogen recovery from a fluid catalytic cracker off-gas stream. First-pass economics showed that overall cost for hydrogen production is reduced by 35% vs on-purpose production of hydrogen by steam- methane reforming. The hydrogen recovery process using the SSF membrane results in at least 15% energy reduction and significant decrease in CO{sub 2} and NO{sub x} emissions.

Anand, M. [USDOE, Washington, DC (United States)

1995-08-01T23:59:59.000Z

288

Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network (OSTI)

to 61% in 1999, petroleum coke (11% in 1999) and wastes (Natural Gas Oil Petcoke Coke Coal Either Dry Process Wet1996) coefficients for coke and breeze. For electricity, the

Worrell, Ernst

2008-01-01T23:59:59.000Z

289

Theoretical and experimental foundations for preparing coke for blast-furnace smelting  

SciTech Connect

This article examines the preparation of coke for blast-furnace smelting by a method that most fully meets the requirements of blast-furnace technology: screening of the -36 mm fraction, the separation of nut coke of the 15-36 mm fraction, and its charging into the furnace in a mixture with the iron-ore-bearing charge components. An analysis is made of trial use of coke of the Premium class on blast furnace No. 5 at the Enakievo Metallurgical Plant. Use of this coke makes it possible to reduce the consumption of skip coke by 3.2-4.1%.

A.L. Podkorytov; A.M. Kuznetsov; E.N. Dymchenko; V.P. Padalka; S.L. Yaroshevskii; A.V. Kuzin [Enakievo Metallurgical Plant, Enakievo (Ukraine)

2009-05-15T23:59:59.000Z

290

Investigation of flammable gas and thermal safety issues for retrieval of waste from Tank 241-AN-105  

SciTech Connect

The primary purpose of this report is to identify and resolve some of the flammable gas and thermal safety issues potentially associated with the retrieval of waste from Tank 241-AN-105 (AN-105), which is the first double-shell tank scheduled for waste retrieval at Hanford. The planned retrieval scenario includes the following steps in AN-105: (1) degas the tank using two submerged mixing pumps, (2) turn off the mixer pump(s) and allow any suspended solids to settle, (3) decant the supernatant to the intermediate feed staging tank(s) (IFSTs) (AP-102 and/or AP-104) using water/caustic dilution at the transfer pump inlet, (4) add the remaining dilution water/caustic to the slurry remaining in AN-105, (5) mix the tank with the mixer pump(s) until the soluble solids dissolve, (6) turn off the mixer pump(s) and let the insoluble solids settle, and (7) decant the new supernatant to the IFST(s), leaving the insoluble solids behind. Three waste retrieval safety issues are addressed in this report. They are (1) the controlled degassing of AN-105 to ensure that the headspace remains <25% of the lower flammability limit (LFL), (2) an assessment of how dissolved gas (mainly ammonia) released during the transfer of the supernatant in AN-105 to the IFSTs and the water/caustic dilution of the remaining slurry in AN-105 will affect the flammability in these tanks; and (3) an assessment of the maximum waste temperatures that might occur in AN-105 during retrieval operations.

Caley, S.M.; Stewart, C.W.; Antoniak, Z.I.; Cuta, J.M.; Mahoney, L.A.; Panisko, F.E.

1998-09-01T23:59:59.000Z

291

Effect of explicit representation of detailed stratigraphy on brine and gas flow at the Waste Isolation Pilot Plant  

Science Conference Proceedings (OSTI)

Stratigraphic units of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) disposal room horizon includes various layers of halite, polyhalitic halite, argillaceous halite, clay, and anhydrite. Current models, including those used in the WIPP Performance Assessment calculations, employ a ``composite stratigraphy`` approach in modeling. This study was initiated to evaluate the impact that an explicit representation of detailed stratigraphy around the repository may have on fluid flow compared to the simplified ``composite stratigraphy`` models currently employed. Sensitivity of model results to intrinsic permeability anisotropy, interbed fracturing, two-phase characteristic curves, and gas-generation rates were studied. The results of this study indicate that explicit representation of the stratigraphy maintains higher pressures and does not allow as much fluid to leave the disposal room as compared to the ``composite stratigraphy`` approach. However, the differences are relatively small. Gas migration distances are also different between the two approaches. However, for the two cases in which explicit layering results were considerably different than the composite model (anisotropic and vapor-limited), the gas-migration distances for both models were negligible. For the cases in which gas migration distances were considerable, van Genuchten/Parker and interbed fracture, the differences between the two models were fairly insignificant. Overall, this study suggests that explicit representation of the stratigraphy in the WIPP PA models is not required for the parameter variations modeled if ``global quantities`` (e.g., disposal room pressures, net brine and gas flux into and out of disposal rooms) are the only concern.

Christian-Frear, T.L.; Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States). Geohydrology Dept.

1996-04-01T23:59:59.000Z

292

Biological production of acetic acid from waste gases with Clostridium ljungdahlii  

DOE Patents (OSTI)

A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

Gaddy, James L. (Fayetteville, AR)

1998-01-01T23:59:59.000Z

293

Biological production of acetic acid from waste gases with Clostridium ljungdahlii  

DOE Patents (OSTI)

A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

Gaddy, J.L.

1998-09-15T23:59:59.000Z

294

Radcalc: A computer program to calculate the radiolytic production of hydrogen gas from radioactive wastes in packages  

DOE Green Energy (OSTI)

Radcalc for Windows` is a menu-driven Microsoft2 Windows-compatible computer code that calculates the radiolytic production of hydrogen gas in high- and low-level radioactive waste. In addition, the code also determines US Department of Transportation (DOT) transportation classifications, calculates the activities of parent and daughter isotopes for a specified period of time, calculates decay heat, and calculates pressure buildup from the production of hydrogen gas in a given package geometry. Radcalc for Windows was developed by Packaging Engineering, Transportation and Packaging, Westinghouse Hanford Company, Richland, Washington, for the US Department of Energy (DOE). It is available from Packaging Engineering and is issued with a user`s manual and a technical manual. The code has been verified and validated.

Green, J.R.; Schwarz, R.A.; Hillesland, K.E.; Roetman, V.E.; Field, J.G.

1995-11-01T23:59:59.000Z

295

Numerical modeling of gas migration at a proposed repository for low and intermediate level nuclear wastes at Oberbauenstock, Switzerland  

Science Conference Proceedings (OSTI)

Hydrologic impacts of corrosive gas release from a hypothetical L/ILW nuclear waste repository at Oberbauenstock are explored by means of numerical simulation. A schematic two dimensional vertical section through the mountain is modeled with the simulator TOUGH, which describes two-phase flow of water and gas in porous and fractured media. Two reference cases are considered which represent the formations as a porous and as a fractured-porous (dual permeability) medium, respectively. Both cases predict similar and rather modest pressure increases, from ambient 10 bars to near 25 bars at the repository level. These results are to be considered preliminary because important parameters affecting two-phase flow, such as relative permeabilities of a fractured medium, are not well known at present. 24 refs., 15 figs., 5 tabs.

Pruess, K.

1990-03-01T23:59:59.000Z

296

ESTIMATION OF RADIOLYTIC GAS GENERATION RATE FOR CYLINDRICAL RADIOACTIVE WASTE PACKAGES - APPLICATION TO SPENT ION EXCHANGE RESIN CONTAINERS  

DOE Green Energy (OSTI)

Radioactive waste packages containing water and/or organic substances have the potential to radiolytically generate hydrogen and other combustible gases. Typically, the radiolytic gas generation rate is estimated from the energy deposition rate and the radiolytic gas yield. Estimation of the energy deposition rate must take into account the contributions from all radionuclides. While the contributions from non-gamma emitting radionuclides are relatively easy to estimate, an average geometry factor must be computed to determine the contribution from gamma emitters. Hitherto, no satisfactory method existed for estimating the geometry factors for a cylindrical package. In the present study, a formulation was developed taking into account the effect of photon buildup. A prototype code, called PC-CAGE, was developed to numerically solve the integrals involved. Based on the selected dimensions for a cylinder, the specified waste material, the photon energy of interest and a value for either the absorption or attenuation coefficient, the code outputs values for point and average geometry factors. These can then be used to estimate the internal dose rate to the material in the cylinder and hence to calculate the radiolytic gas generation rate. Besides the ability to estimate the rates of radiolytic gas generation, PC-CAGE can also estimate the dose received by the container material. This is based on values for the point geometry factors at the surface of the cylinder. PC-CAGE was used to calculate geometry factors for a number of cylindrical geometries. Estimates for the absorbed dose rate in container material were also obtained. The results for Ontario Power Generation's 3 m3 resin containers indicate that about 80% of the source gamma energy is deposited internally. In general, the fraction of gamma energy deposited internally depends on the dimensions of the cylinder, the material within it and the photon energy; the fraction deposited increases with increasing dimensions of the cylinder and decreases with increasing photon energy.

Husain, A.; Lewis, Brent J.

2003-02-27T23:59:59.000Z

297

Off-gas characteristics of defense waste vitrification using liquid-fed Joule-heated ceramic melters  

DOE Green Energy (OSTI)

Off-gas and effluent characterization studies have been established as part of a PNL Liquid-Fed Ceramic Melter development program supporting the Savannah River Laboratory Defense Waste Processing Facility (SRL-DWPF). The objectives of these studies were to characterize the gaseous and airborne emission properties of liquid-fed joule-heated melters as a function of melter operational parameters and feed composition. All areas of off-gas interest and concern including effluent characterization, emission control, flow rate behavior and corrosion effects have been studied using alkaline and formic-acid based feed compositions. In addition, the behavioral patterns of gaseous emissions, the characteristics of melter-generated aerosols and the nature and magnitude of melter effluent losses have been established under a variety of feeding conditions with and without the use of auxiliary plenum heaters. The results of these studies have shown that particulate emissions are responsible for most radiologically important melter effluent losses. Melter-generated gases have been found to be potentially flammable as well as corrosive. Hydrogen and carbon monoxide present the greatest flammability hazard of the combustibles produced. Melter emissions of acidic volatile compounds of sulfur and the halogens have been responsible for extensive corrosion observed in melter plenums and in associated off-gas lines and processing equipment. The use of auxiliary plenum heating has had little effect upon melter off-gas characteristics other than reducing the concentrations of combustibles.

Goles, R.W.; Sevigny, G.J.

1983-09-01T23:59:59.000Z

298

Gas Permeation Testing Results from the Mixed Waste Focus Area Improved Hydrogen Getter Program  

Science Conference Proceedings (OSTI)

The gas permeabilities of more than 20 polymers were measured using pure and mixed gas techniques. The motivation was to determine potential materials that could be used to protect hydrogen getter particles from poisons while permitting sufficient hydrogen rates to enable the getters use in TRUPACT types of containers. A rate of five barrers or larger is needed. Of the materials screened in the pure gas tests, more than 15 qualified. Nine materials qualified in the mixed gas tests, but of the nine only three had high CCl4 rejection rates and four others would greatly reduce the transport of the CCl4.

Mark Stone; Christopher Orme; Eric Peterson; Michael Benson; John Kaszuba; Eugene Mroz; Marc Haga

2005-02-01T23:59:59.000Z

299

Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases  

SciTech Connect

Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

Laufhutte, D.

1985-04-30T23:59:59.000Z

300

Eco-efficiency for greenhouse gas emissions mitigation of municipal solid waste management: A case study of Tianjin, China  

Science Conference Proceedings (OSTI)

The issue of municipal solid waste (MSW) management has been highlighted in China due to the continually increasing MSW volumes being generated and the limited capacity of waste treatment facilities. This article presents a quantitative eco-efficiency (E/E) analysis on MSW management in terms of greenhouse gas (GHG) mitigation. A methodology for E/E analysis has been proposed, with an emphasis on the consistent integration of life cycle assessment (LCA) and life cycle costing (LCC). The environmental and economic impacts derived from LCA and LCC have been normalized and defined as a quantitative E/E indicator. The proposed method was applied in a case study of Tianjin, China. The study assessed the current MSW management system, as well as a set of alternative scenarios, to investigate trade-offs between economy and GHG emissions mitigation. Additionally, contribution analysis was conducted on both LCA and LCC to identify key issues driving environmental and economic impacts. The results show that the current Tianjin's MSW management system emits the highest GHG and costs the least, whereas the situation reverses in the integrated scenario. The key issues identified by the contribution analysis show no linear relationship between the global warming impact and the cost impact in MSW management system. The landfill gas utilization scenario is indicated as a potential optimum scenario by the proposed E/E analysis, given the characteristics of MSW, technology levels, and chosen methodologies. The E/E analysis provides an attractive direction towards sustainable waste management, though some questions with respect to uncertainty need to be discussed further.

Zhao Wei, E-mail: zhaowei.tju@gmail.com [College of Civil Engineering and Architecture, Liaoning University of Technology, 121000 Jinzhou (China); Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands); Huppes, Gjalt, E-mail: huppes@cml.leidenuniv.nl [Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands); Voet, Ester van der, E-mail: Voet@cml.leidenuniv.nl [Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands)

2011-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Coke County, Texas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Coke County, Texas: Energy Resources Coke County, Texas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 31.8277663°, -100.5296115° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":31.8277663,"lon":-100.5296115,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

302

Integrated coke, asphalt and jet fuel production process and apparatus  

DOE Patents (OSTI)

A process and apparatus for the production of coke, asphalt and jet fuel from a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products, removing at least some coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. The process provides a useful method of mass producing these products from materials such as coal, oil shale and tar sands. 1 fig.

Shang, Jer Yu.

1989-10-17T23:59:59.000Z

303

Integrated coke, asphalt and jet fuel production process and apparatus  

DOE Patents (OSTI)

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

Shang, Jer Y. (McLean, VA)

1991-01-01T23:59:59.000Z

304

Development of Load Tap Changer Monitoring Technique: Mechanism of Coking  

Science Conference Proceedings (OSTI)

Load tap changers (LTCs) play a major role in the reliable delivery of electric power. They are the single biggest contributors to transformer outages. To improve reliability and extend their service interval, utilities are adopting proactive maintenance practices using monitoring devices and seeking new diagnostic techniques. As part of an ongoing EPRI project, EPRI and cosponsor Consolidated Edison Co. of New York, Inc. engaged in a study of contact coking, one of the biggest problems in LTCs. This EPR...

2001-11-27T23:59:59.000Z

305

New environmental concepts in the chemical and coke industries  

Science Conference Proceedings (OSTI)

We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

2007-05-15T23:59:59.000Z

306

Table 22. Average Price of U.S. Coke Imports  

U.S. Energy Information Administration (EIA) Indexed Site

Average Price of U.S. Coke Imports Average Price of U.S. Coke Imports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 22. Average Price of U.S. Coke Imports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Origin April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 263.21 252.66 353.05 261.29 356.01 -26.6 Canada 263.51 252.66 353.05 258.82 356.01 -27.3 Panama 263.09 - - 263.09 - - South America Total 196.86 194.14 175.88 195.94 181.01 8.2 Brazil - - 157.60 - 157.60 - Colombia 196.86 194.14 322.06 195.94 246.68 -20.6 Europe Total 181.55 232.13 385.65 225.53 384.96 -41.4 Czech Republic - 475.91 - 475.91 - - Spain 360.51

307

Table 17. Average Price of U.S. Coke Exports  

U.S. Energy Information Administration (EIA) Indexed Site

Average Price of U.S. Coke Exports Average Price of U.S. Coke Exports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 17. Average Price of U.S. Coke Exports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Destination April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 240.59 241.38 218.40 240.85 225.80 6.7 Canada* 147.49 330.47 243.04 183.08 286.56 -36.1 Mexico 316.57 211.63 189.12 273.97 171.71 59.6 Other** 612.42 485.63 134.48 525.92 135.04 289.5 South America Total 140.65 156.15 322.70 148.29 250.36 -40.8 Other** 140.65 156.15 322.70 148.29 250.36 -40.8 Europe Total 259.26 255.24 - 257.06 427.83 -39.9 Other**

308

The impact of municipal solid waste treatment methods on greenhouse gas emissions in Lahore, Pakistan  

Science Conference Proceedings (OSTI)

The contribution of existing municipal solid waste management to emission of greenhouse gases and the alternative scenarios to reduce emissions were analyzed for Data Ganj Bukhsh Town (DGBT) in Lahore, Pakistan using the life cycle assessment methodology. DGBT has a population of 1,624,169 people living in 232,024 dwellings. Total waste generated is 500,000 tons per year with an average per capita rate of 0.84 kg per day. Alternative scenarios were developed and evaluated according to the environmental, economic, and social atmosphere of the study area. Solid waste management options considered include the collection and transportation of waste, collection of recyclables with single and mixed material bank container systems (SMBCS, MMBCS), material recovery facilities (MRF), composting, biogasification and landfilling. A life cycle inventory (LCI) of the six scenarios along with the baseline scenario was completed; this helped to quantify the CO{sub 2} equivalents, emitted and avoided, for energy consumption, production, fuel consumption, and methane (CH{sub 4}) emissions. LCI results showed that the contribution of the baseline scenario to the global warming potential as CO{sub 2} equivalents was a maximum of 838,116 tons. The sixth scenario had a maximum reduction of GHG emissions in terms of CO{sub 2} equivalents of -33,773 tons, but the most workable scenario for the current situation in the study area is scenario 5. It saves 25% in CO{sub 2} equivalents compared to the baseline scenario.

Batool, Syeda Adila [Department of Space Science, Punjab University, Lahore 54600 (Pakistan)], E-mail: aadila_batool@yahoo.com; Chuadhry, Muhammad Nawaz [College of Earth and Environmental Sciences, University of the Punjab, Lahore (Pakistan)], E-mail: muhammadnawazchaudhry@yahoo.com

2009-01-15T23:59:59.000Z

309

Development of an advanced gas-fired mineral-wool melter. Annual report, January-December 1988  

SciTech Connect

A gas-fired mineral-wool melter was designed to provide a melting technology option to the existing coke-fired cupola melters used by the mineral wool industry. Over the past few years, mineral-wool producers have been increasingly pressured to reduce their level of pollutant gaseous emissions. Including the fuel consumption for an afterburner required with a cupola melter, the direct production costs for fuel currently range from $32 to $44 per ton of melted product; dependent on the effectiveness of a heat-recovery system. The estimated direct fuel cost for a gas-fired mineral-wool melter could be as low as $16 per ton. The configuration of the prototype melter contributes to the energy savings because waste heat is reclaimed by preheating the feedstock in a counterflow shaft. Besides the beneficial decrease in energy costs, the proposed gas-fired melter will virtually eliminate carbon monoxide and unburned hydrocarbon emissions as well as substantially reduce emissions of hydrogen sulfide. Finally, with an improved capability to process the melted product at a controlled temperature and flow rate, the gas-fired melter should improve the overall quality of the mineral fiber product compared to the state-of-the-art coke-fired cupola melter.

Vereecke, F.J.; Thekdi, A.C.

1989-06-01T23:59:59.000Z

310

Evaluation of high-level nuclear waste tanks having a potential flammable gas hazard  

DOE Green Energy (OSTI)

In 1990 the U.S. Department of Energy declared an unreviewed safety question as a result of the behavior of tank 241-SY-101. This tank exhibited episodic releases of flammable gases that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years a considerable amount of knowledge has been gained about the chemical and physical processes that govern the behavior of tank 241-SY-101 and the other tanks associated with a potential flammable gas hazard. This paper presents an overview of the current understanding of gas generation, retention, and release and covers the results of direct sampling of the tanks to determine the gas composition and the amount of stored gas.

Johnson, G.D.; Barton, W.B.; Hill, R.C.; et al, Fluor Daniel Hanford

1997-02-14T23:59:59.000Z

311

Gas  

Science Conference Proceedings (OSTI)

... Implements a gas based on the ideal gas law. It should be noted that this model of gases is niave (from many perspectives). ...

312

The radiolytic and radiolytically induced gas generation in Hanford waste tanks  

DOE Green Energy (OSTI)

A task force operating in ANL/CHM has been developing a mechanistic understanding of the radiolytic processes that lead to the generation and retention of gases within tanks of radioactive waste at the Hanford site. This chemistry is one of the important factors that must be considered in devising remediation procedures to eliminate the great potential hazard of these tanks. A quantitative description of much of the chemistry involved in the production of H{sub 2} and, to a lesser extent, in the production of N{sub 2}O has been achieved. Direct radiolytic generation was experimentally quantified and this new information was utilized in computer modeling to provide predictive capabilities so that changes of chemical composition of various waste tanks under different remediation procedures could be assessed. Oxygen in the waste solutions is effectively consumed upon irradiation and thus is of no concern. The mechanism of the radiolytic degradation of the chelators was established. The end products are simple organic molecules, in particularly, formaldehyde and glyoxylate, that are very efficient in the thermal generation of H{sub 2}

Jonah, C.D.; Meisel, D.; Sauer, M.C. Jr.

1994-06-01T23:59:59.000Z

313

Process for separating, especially in multiple stages, acid components such as CO/sub 2/, HCN and specifically H/sub 2/S, from gases, especially from coke oven gases, by means of ammonia recirculation scrubbing  

SciTech Connect

A process of separating in multiple stages acid components in coke oven gas such as CO/sub 2/, HCN and particularly H/sub 2/S by ammonia scrubbing wherein the ammonia used in scrubbing is deacidified to remove the acid components and is recirculated to the scrubbing process at least in part as substantially pure liquid ammonia.

Bauer, H.K.; Otte, E.A.W.

1984-10-16T23:59:59.000Z

314

Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy  

Science Conference Proceedings (OSTI)

Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2009-03-15T23:59:59.000Z

315

The Vertical Ball Mill for the Grinding of Calcined Petroleum Coke to ...  

Science Conference Proceedings (OSTI)

A new vertical ball ring mill concept has been developed based on the results of research on the grinding of calcined petroleum coke. Industrial vertical mills are ...

316

Preparation of Activated Carbon from Oil Sands Coke by Chemical and Physical Activation Techniques.  

E-Print Network (OSTI)

??Oil sands coke is a by-product resulting from the upgrading of heavy crude bitumen to light synthetic oil. This research investigates the preparation of activated… (more)

Morshed, Golam

2012-01-01T23:59:59.000Z

317

Simulation of Combustion and Thermal-flow Inside a Petroleum Coke Rotary Calcining Kiln.  

E-Print Network (OSTI)

??Calcined coke is the best material for making carbon anodes for smelting of alumina to aluminum. Calcining is an energy intensive industry and a significant… (more)

Zhang, Zexuan

2007-01-01T23:59:59.000Z

318

Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.  

E-Print Network (OSTI)

??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola… (more)

Lumadue, Matthew

2012-01-01T23:59:59.000Z

319

Coke yield and transport processes in agglomerates of bitumen and solids.  

E-Print Network (OSTI)

??Agglomerate formation is a common phenomenon that can cause operating problems in the fluid coking reactor. When agglomerates form they provide longer diffusion paths of… (more)

Ali, Mohamed Ali Hassan

2010-01-01T23:59:59.000Z

320

The Effect of Coke Particle Size on Thermal Profile of Sintering ...  

Science Conference Proceedings (OSTI)

Baking process and sinter production was performed for different ranges of coke particle size while other parameter like, iron ore, lime and sintering mixture ...

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

MOLECULAR COMPOSITION OF NEEDLE COKE FEEDSTOCKS AND MESOPHASE DEVELOPMENT DURING CARBONIZATION.  

E-Print Network (OSTI)

??This study investigates the molecular composition of fluid catalytic cracking (FCC) decant oil and its derivatives that are used as feedstocks for delayed coking to… (more)

Wang, Guohua

2005-01-01T23:59:59.000Z

322

U.S. Exports to Belarus of Petroleum Coke (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Exports to Belarus of Petroleum Coke (Thousand Barrels) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 2004: 17

323

Effect of Blending HDPE with Coke on the Reduction Behavior of a ...  

Science Conference Proceedings (OSTI)

This has led to the exploration of the possibility of using polymer/coke blends in the production of ferro-alloys, particularly High Carbon Ferromanganese (HC ...

324

Co-gasification of biomass with coal and oil sands coke in a drop tube furnace.  

E-Print Network (OSTI)

??Chars were obtained from individual fuels and blends with different blend ratios of coal, coke and biomass in Drop Tube Furnace at different temperatures. Based… (more)

Gao, Chen

2010-01-01T23:59:59.000Z

325

The effect of diabietic acid on the coking of oxidised solvent-extracted coal.  

E-Print Network (OSTI)

??Refcoal is a refined carbon source obtained by extraction of coal with dimethylformamide (DMF). During the coking process, Refcoal goes through a mesophase (fluid) stage… (more)

Ludere, Margaret Tshimangadzo

2008-01-01T23:59:59.000Z

326

Pyrolysis behavior of coal and petroleum coke at high temperature and high pressure.  

E-Print Network (OSTI)

??While pyrolysis of coal is a well-studied thermal process, little is known about pressurized pyrolysis of coal and petroleum coke. This study aims to interpret… (more)

Wagner, David Ray

2011-01-01T23:59:59.000Z

327

Gas Generation Testing of Uranium Metal in Simulated K Basins Sludge and Grouted Sludge Waste Forms  

DOE Green Energy (OSTI)

The evolving plan for most of the KE and KW Basin sludges is disposition to WIPP as remote handled (RH) TRU. Because the hydrogen gas concentration in the sealed transportation cask destined for WIPP is limited by flammability safety, the number of containers and shipments to WIPP likely will be driven by the rate of hydrogen generated by the contained uranium metals reaction with water. Therefore, gas generation testing with uranium metal particles of known surface area and immobilized in candidate (grout) solidification matrices was used to identify the effectiveness of various candidate solidification matrices to inhibit the rate of the uranium metal-water reaction.

Delegard, Calvin H.; Schmidt, Andrew J.; Sell, Rachel L.; Sinkov, Sergei I.; Bryan, Samuel A.

2004-05-21T23:59:59.000Z

328

Biological production of products from waste gases  

DOE Patents (OSTI)

A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

Gaddy, James L. (Fayetteville, AR)

2002-01-22T23:59:59.000Z

329

Processing of mixed-waste compressed-gas cylinders on the Oak Ridge Reservation  

Science Conference Proceedings (OSTI)

To comply with restrictions on the storage of old compressed gas cylinders, the environmental management organization of Lockheed Martin Energy Systems must dispose of several thousand kilograms of compressed gases stored on the Oak Ridge Reservation (ORR) because the cylinders cannot be taken off-site for disposal in their current configuration. In the ORR Site Treatment Plan, a milestone is cited that requires repackaging and shipment off-site of 21 cylinders by September 30, 1997. A project was undertaken to first evaluate and then either recontainerize or neutralize these cylinders using a transportable compressed gas recontainerization skid (TCGRS), which was developed by Integrated Environmental Services of Atlanta. The transportable system can: (1) sample, analyze, and identify at the site the chemical and radiological content of each cylinder, even those with inoperable valves; (2) breach cylinders, when necessary, to release their contents into a containment chamber; and (3) either neutralize the gas or liquid contents within the containment chamber or transfer the gas or liquids to a new cylinder. The old cylinders and cylinder fragments were disposed of and the gases neutralized or transferred to new cylinders for transportation off-site for disposal. The entire operation to process the 21 cylinders took place in only 5 days once the system was approved for operation. The system performed as expected and can now be used to process the potentially thousands of more cylinders located across the US Department of Energy (DOE) complex that have not yet been declared surplus.

Morris, M.I.; Conley, T.B.; Osborne-Lee, I.W.

1998-01-01T23:59:59.000Z

330

Developing indicators for the assessment and proper management of the different levels of exposure to polycyclic aromatic hydrocarbons (PAH)s generally associated with coke-oven workers.  

E-Print Network (OSTI)

??Coke ovens may occur in the aluminium, steel, graphite, electrical, and construction industries. In the work area coke-oven workers may be exposed to various chemical… (more)

Wang, Tianyuan

2011-01-01T23:59:59.000Z

331

CHARACTERIZATION OF COAL- AND PETROLEUM-DERIVED BINDER PITCHES AND THE INTERACTION OF PITCH/COKE MIXTURES IN PRE-BAKED CARBON ANODES.  

E-Print Network (OSTI)

??Carbon anodes are manufactured from calcined petroleum coke (i.e. sponge coke) and recycled anode butts as fillers, and coal tar pitch (SCTP) as the binder.… (more)

Suriyapraphadilok, Uthaiporn

2008-01-01T23:59:59.000Z

332

The effects of petroleum coke amendments on macrophytes and aquatic invertebrates in northern Alberta, Canada constructed wetlands.  

E-Print Network (OSTI)

??Oil-sands operators of Fort McMurray, Alberta produce six million t/y of petroleum coke. The use of coke to stabilize clay-dominated mine tailings in constructed wetlands… (more)

Baker, Leanne F.

2007-01-01T23:59:59.000Z

333

Analytical input-output and supply chain study of China's coke and steel sectors; Analytical I/O and supply chain study of China's coke and steel sectors.  

E-Print Network (OSTI)

??I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal… (more)

Li, Yu, 1976-

2004-01-01T23:59:59.000Z

334

Short Survey: Intelligent switching expert system for delayed coking unit based on iterative learning strategy  

Science Conference Proceedings (OSTI)

Delayed coking is the most effective process to decarbonize and demetallize heavy petroleum residues. However, it relies much on the field engineers' experiences and expertise in practice for operating the controllers effectively and compatibly in delayed ... Keywords: Delayed coking, Expert system, Intelligent control, Iterative learning

Xiaodong Yu; Yujie Wei; Dexian Huang; Yongheng Jiang; Bo Liu; Yihui Jin

2011-07-01T23:59:59.000Z

335

Study on Further Treatment of Coal Coking Wastewater by Ultrasound Wave, Fenton's Reagent and Coagulation  

Science Conference Proceedings (OSTI)

The study on further treatment of coal coking wastewater by ultrasound wave, Fenton's reagent and coagulation was carried out in this paper at the first time, Furthermore, this paper discussed the optimum cooperative reaction condition of their combined ... Keywords: ultrasound wave, coke plant wastewater, Fenton reagent, coagulation

Jun Shi; Liangbo Zhang

2009-10-01T23:59:59.000Z

336

Analytical input-output and supply chain study of China's coke and steel sectors  

E-Print Network (OSTI)

I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

Li, Yu, 1976-

2004-01-01T23:59:59.000Z

337

Influence of coal on coke properties and blast-furnace operation  

SciTech Connect

With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

2007-07-01T23:59:59.000Z

338

DEVELOPMENT AND FIELD IMPLEMENTATION OF AN IMPROVED METHOD FOR HEADSPACE GAS SAMPLING OF TRANSURANIC WASTE DRUMS  

Science Conference Proceedings (OSTI)

A fast, safe, and cost-effective method for obtaining headspace gas samples has been developed and implemented at Los Alamos National Laboratory (LANL). A sample port is installed directly into a drum lid using a pneumatic driver, allowing sampling with a side-port needle. Testing has shown that the sample port can be installed with no release of radioactive material. Use of this system at LANL has significantly reduced the time required for sampling, and eliminates the need for many safety precautions previously used. The system has significantly improved productivity and lowered radiation exposure and cost.

Polley, M.; Ankrom, J.; Wickland, T.; Warren, J.

2003-02-27T23:59:59.000Z

339

Monitoring gas retention and slurry transport during the transfer of waste from Tank 241-C-106 to Tank 241-AY-102  

SciTech Connect

The retained gas volume can be estimated by several methods. All of these methods have significant uncertainties, but together they form a preponderance of evidence that describes the gas retention behavior of the tank. The methods are (1) an increase in nonconvective layer thickness; (2) a waste surface level rise (surface level effect [SLE] model); (3) the barometric pressure effect (BPE model); (4) direct void measurement; and (5) the consequences of the transfer process. The nonconvective layer thickness can be determined with sufficient accuracy to describe the overall waste configuration by means of temperature profiles or densitometer indications. However, the presence of a nonconvective layer does not necessarily indicate significant gas retention, and small changes in layer thickness that could quantify gas retention cannot be detected reliably with the methods available. The primary value of this measurement is in establishing the actual {open_quotes}fluffing factor{close_quotes} for thermal calculations. Surface level rise is not a useful measure of gas retention in Tank 241-C-106 (C-106) since the waste level fluctuates with regular makeup water additions. In Tank 241-AY-102 (AY-102) with the existing ventilation system it should be possible to determine the gas retention rate within 30-60% uncertainty from the surface level rise, should a significant rise be observed. The planned ventilation system upgrades in AY- 102 will greatly reduce the exhaust flow and the headspace humidity, and the evaporation rate should be significantly lower when transfers begin. This could reduce the uncertainty in gas retention rate estimates to around {+-} 10%.

Stewart, C.W.; Erian, F.F.; Meyer, P.A. [and others

1997-07-01T23:59:59.000Z

340

Numerical modeling of the aerodynamics, heat exchange, and combustion of a polydisperse ensemble of coke-ash particles in ascending axisymmetric two-phase flow  

Science Conference Proceedings (OSTI)

A two-dimensional stationary model of motion, heat and mass exchange, and chemical reaction of polydisperse coke and ash particles in ascending gas-suspension flow has been constructed with allowance for the turbulent and pseudo turbulent mechanisms of transfer in the dispersed phase. The system of equations that describes motion and heat transfer in the solid phase has been closed at the level of the equations for the second moments of velocity and temperature pulsations, whereas the momentum equations of the carrying medium have been closed using the equation for turbulent gas energy, which allows for the influence of the particles and heterogeneous reactions.

B.B. Rokhman [National Academy of Sciences of Ukraine, Kiev (Ukraine). Institute of Coal Power Technologies

2009-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Hydrogen Sulfide, Oil and Gas, and People's Lana Skrtic  

E-Print Network (OSTI)

at sewage treatment plants, manure-handling plants, tanneries, and coke oven plants.5 2 EPA, "Report standard cubic feet)."9 Sour gas is routinely `sweetened' at processing facilities called desulfurization Process for Desulfurizing Ultra-deep Natural Gas Near the Wellhead," presented at Natural Gas Technologies

Kammen, Daniel M.

342

Photocatalytic oxidation of gas-phase BTEX-contaminated waste streams  

Science Conference Proceedings (OSTI)

Researchers at the National Renewable Energy Laboratory (NREL) have been exploring heterogeneous photocatalytic oxidation (PCO) as a remediation technology for air streams contaminated with benzene, toluene, ethyl-benzene, and xylenes (BTEX). This research is a continuation of work performed on chlorinated organics. The photocatalytic oxidation of BTEX has been studied in the aqueous phase, however, a study by Turchi et al. showed a more economical system would involve stripping organic contaminants from the aqueous phase and treating the resulting gas stream. Another recent study by Turchi et al. indicated that PCO is cost competitive with such remediation technologies as activated carbon adsorption and catalytic incineration for some types of contaminated air streams. In this work we have examined the photocatalytic oxidation of benzene using ozone (0{sub 3}) as an additional oxidant. We varied the residence time in the PCO reactor, the initial concentration of the organic pollutant, and the initial ozone concentration in a single-pass reactor. Because aromatic hydrocarbons represent only a small fraction of the total hydrocarbons present in gasoline and other fuels, we also added octane to the reaction mixture to simulate the composition of air streams produced from soil-vapor-extraction or groundwater-stripping of sites contaminated with gasoline.

Gratson, D A; Nimlos, M R; Wolfrum, E J

1995-03-01T23:59:59.000Z

343

Kinetics of Cold-Cap Reactions for Vitrification of Nuclear Waste Glass Based on Simultaneous Differential Scanning Calorimetry - Thermogravimetry (DSC-TGA) and Evolved Gas Analysis (EGA)  

Science Conference Proceedings (OSTI)

For vitrifying nuclear waste glass, the feed, a mixture of waste with glass-forming and modifying additives, is charged onto the cold cap that covers 90?100% of the melt surface. The cold cap consists of a layer of reacting molten glass floating on the surface of the melt in an all-electric, continuous glass melter. As the feed moves through the cold cap, it undergoes chemical reactions and phase transitions through which it is converted to molten glass that moves from the cold cap into the melt pool. The process involves a series of reactions that generate multiple gases and subsequent mass loss and foaming significantly influence the mass and heat transfers. The rate of glass melting, which is greatly influenced by mass and heat transfers, affects the vitrification process and the efficiency of the immobilization of nuclear waste. We studied the cold-cap reactions of a representative waste glass feed using both the simultaneous differential scanning calorimetry-thermogravimetry (DSC-TGA) and the thermogravimetry coupled with gas chromatography-mass spectrometer (TGA-GC-MS) as complementary tools to perform evolved gas analysis (EGA). Analyses from DSC-TGA and EGA on the cold-cap reactions provide a key element for the development of an advanced cold-cap model. It also helps to formulate melter feeds for higher production rate.

Rodriguez, Carmen P.; Pierce, David A.; Schweiger, Michael J.; Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.

2013-12-03T23:59:59.000Z

344

Development and Demonstration of Waste Heat Integration with Solvent Process for More Efficient CO2 Removal from Coal-Fired Flue Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

and Demonstration of and Demonstration of Waste Heat Integration with Solvent Process for More Efficient CO 2 Removal from Coal-Fired Flue Gas Background The mission of the U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) Existing Plants, Emissions, & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-

345

An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors  

SciTech Connect

This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

Townsend, Aaron K., E-mail: aarontownsend@utexas.edu [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States); Webber, Michael E. [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States)

2012-07-15T23:59:59.000Z

346

Energy efficiency of alternative coke-free metallurgical technologies  

SciTech Connect

Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

2009-02-15T23:59:59.000Z

347

Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 1, May 1--August 1, 1998  

Science Conference Proceedings (OSTI)

The overall aim of the project is to demonstrate the performance and practical use of a laser ultrasonic probe for measuring the thickness of coke deposits located within the high temperature tubes of a thermal cracking furnace. This aim will be met by constructing an optical probe that will be tested using simulated coke deposits that are positioned inside of a bench-scale furnace. Successful development of the optical coke detector will provide industry with the only available method for on-line measurement of coke deposits. The optical coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem. The coke detector will particularly benefit the olefins industry where high temperature thermal crackers are used to produce ethylene, propylene, butylene and other important olefin intermediates. The ethylene industry requires development of an on-line method for gauging the thickness of coke deposits in cracking furnaces because the current lack of detailed knowledge of coke deposition profiles introduces the single greatest uncertainty in the simulation and control of modern cracking furnaces. The laser ultrasonic coke detector will provide operators with valuable new information allowing them to better optimize the decoking turnaround schedule and therefore maximize production capacity.

NONE

1998-08-15T23:59:59.000Z

348

Annual book of ASTM Standards 2008. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke  

SciTech Connect

The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

NONE

2008-09-15T23:59:59.000Z

349

Report to Congress: management of wastes from the exploration, development, and production of crude oil, natural gas, and geothermal energy. Volume 3. Appendices. A. Summary of state oil and gas regulations. B. Glossary of terms for Volume 1. C. Damage case summaries  

SciTech Connect

Section 3001(b)(2)(A) of the 1980 Amendments to the Resource Conservation and Recovery Act (RCRA) temporarily exempted several types of solid waste from regulation under the Federal hazardous-waste control program. These exempted wastes included drilling fluids, produced waters, and other wastes associated with the exploration, development, or production of crude oil or natural gas or geothermal energy. Section 8002(m) of the RCRA Amendments requires EPA to study these wastes and submit a final report to Congress. The report responds to those requirements. This is volume 3 of 3 reports to Congress. The volume contains the Appendices which include a summary of: (1) State oil and gas regulatory programs; and (2) the damage cases compiled for the oil and gas industry. A glossary of oil and gas industry terms is also included in the volume.

Not Available

1987-12-01T23:59:59.000Z

350

petroleum coke - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA)

Petroleum & Other Liquids. Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas

351

Coking is a refinery process that produces 19% of finished ...  

U.S. Energy Information Administration (EIA)

Petroleum & Other Liquids. Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas

352

REACTOR FUEL WASTE DISPOSAL PROJECT PRESSURE-TEMPERATURE EFFECT ON SALT CAVITIES AND SURVEY OF LIQUEFIED PETROLEUM GAS STORAGE  

SciTech Connect

It is deemed feasible to store reactor fuel wastes in a salt dome cavity to a depth where the differential in pressure between the soil over-burden pressure and pressure of the fluid inside the cavity does not exceed 3000 psi, and the temperature is less than 400 deg F. Tests at pressure increments of 1000 psi were conducted on a 2" cylindrical cavity contained in a 6-in. long by 6-in. cylindrical salt core. Tests indicate that the cavity exhibited complete stability under pressures to 3000 psi and temperatures to 300 deg F. At temperatures of 100 to 400 deg F and pressures to 5000 psi continuous deformation of the cavity resulted. Initial movement of the salt was observed at all pressures. This was evidenced by vertical deformation and cavity size reduction. It was noted that a point of structural equilibrium was reached at lower temperatures when the pressure did not exceed 5000 psi. A literature study reveals that the most common type of cavity utilized in liquefied petroleum gas storage is either cylindrical or ellipsoidal. A few are pear or inverted cone shaped. There was no indication of leakage for cavities when pressure tested for as long as 72 hr. This indicates that the salt mass is not permeable under conditions of prevailing underground temperature and pressure. Salt specimens tested under atmospheric Pressure and temperature exhibited permeabilities of 0.1 to 0.2 millidarcys. The cost of completing underground storage cavities in salt masses is expected to be approximately 05 per barrel of storage space. (auth)

Brown, K.E.; Jessen, F.W.; Gloyna, E.F.

1959-01-15T23:59:59.000Z

353

TRU Waste Sampling Program: Volume I. Waste characterization  

DOE Green Energy (OSTI)

Volume I of the TRU Waste Sampling Program report presents the waste characterization information obtained from sampling and characterizing various aged transuranic waste retrieved from storage at the Idaho National Engineering Laboratory and the Los Alamos National Laboratory. The data contained in this report include the results of gas sampling and gas generation, radiographic examinations, waste visual examination results, and waste compliance with the Waste Isolation Pilot Plant-Waste Acceptance Criteria (WIPP-WAC). A separate report, Volume II, contains data from the gas generation studies.

Clements, T.L. Jr.; Kudera, D.E.

1985-09-01T23:59:59.000Z

354

Co-Gasification Behavior of Metallurgical Coke with High and Low ...  

Science Conference Proceedings (OSTI)

The co-gasification behavior of highly and lowly reactive coke for blast furnace is investigated. ... Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy .... Thermal Plasma Torches for Metallurgical Applications.

355

Current developments at Giprokoks for coke-battery construction and reconstruction  

Science Conference Proceedings (OSTI)

Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

356

Guide to ASTM test methods for the analysis of coal and coke  

Science Conference Proceedings (OSTI)

The guide includes brief descriptions of all 56 ASTM test methods that cover the physical, chemical, and spectroscopic analytical techniques to qualitatively and quantitatively identify over 40 chemical and physical properties of coal, coke, their products, and by-products.

R.A. Kishore Nadkarni (ed.)

2008-07-01T23:59:59.000Z

357

U.S. Exports to South Africa of Petroleum Coke (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Exports to South Africa of Petroleum Coke (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9; ...

358

Study of ways of reducing coke use at non-integrated metallurgical plants  

SciTech Connect

To reduce the costs of blast-furnace smelting, the Svobodnyi Sokol plant has devised a comprehensive program of organizational-technical measures that include study of ways of reducing coke consumption. To do this, the plant began operating its blast furnaces with schungite when making foundry and conversion pig irons. Using schungite in the charge employed to make foundry iron makes it possible to save a significant (10-15%) amount of coke. The value of the coefficient that characterizes the replacement of coke by schungite varies broadly and can reach 1.0 or more, depending on the grade of iron being made and the furnace operating regime. The same coefficient has a value of 0.57 kg coke/kg schungite when 12-15 kg schungite/ton pig is used to make conversion pig iron.

S.A. Feshchenko; V.I. Pleshkov; I.N. Shishchuk; A.V. Buev [Svobodnyi Sokol (Russian Federation). Lipetsk Metallurgical Plant

2006-03-15T23:59:59.000Z

359

U.S. Exports to Cameroon of Petroleum Coke (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Exports to Cameroon of Petroleum Coke (Thousand Barrels) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 1995: 0: 0: 0: 35: 0: 0: 0: 36: ...

360

Executive summary: Technical and economic feasibility study. Trigeneration project, Shanghai Coking and Chemical Plant. Export trade information  

SciTech Connect

The study, conducted by Bechtel, Inc., was funded by the U.S. Trade and Development Agency. The purpose of the study is to assess the feasibility of establishing a new coal-based Trigeneration Complex as an addition to the existing Shanghai Coking and Chemical Plant. The complex would produce gas for the city of Shanghai, chemicals for domestic consumption and foreign export, and utilities for use within the complex and for export to other facilities. The report presents an in-depth study of the economic and technical aspects of the project, as well as an outline of project implementation phases. The study is divided into the following sections: (1) Introduction; (2) Summary; (3) Study Bases; (4) Process Selection and Rationale; (5) Chemical Selection and Marketing; (6) Definition of Facilities; (7) Site and Plot Plan.

NONE

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

362

Experimental study on the effects of blast-cap configurations and charge patterns on coke descending in CDQ cooling shaft  

SciTech Connect

The coke descending behavior in a CDQ cooling shaft is studied experimentally by means of a tracing method with a digital camera. For three different blast-caps, the law of coke flow is studied under five conditions of coke charge. The experimental results show that, for the sake of the uniformity of the coke burden descending, a blast-cap with elliptical cross-section is a better choice than that with circular cross-section regardless of high or low placement. A coke charge pattern with a flat top burden surface is preferable to that with peak-valley surface, a double-peak superior to a one-peak. Trajectory and average velocity distribution of coke behavior depend weakly on whether the coke is continuously fed or not as the discharging began. The blast-caps have local effects on the descending coke and hardly affect whether the cokes flow smoothly or not in the case of coke burden with enough depth.

Y.H. Feng; X.X. Zhang; M.L. Wu [University of Science & Technology, Beijing (China). School of Mechanical Engineering

2008-08-15T23:59:59.000Z

363

Northern Illinois Gas Co IL  

Gasoline and Diesel Fuel Update (EIA)

Northern Northern Illinois Gas Co ............................ IL 254,574,988 4.60 Southern California Gas Co ...................... CA 233,632,354 6.89 Columbia Gas Dist Co............................... OH,KY,PA,MD 196,322,935 6.64 Pacific Gas and Elec Co............................ CA 190,864,262 5.83 Consumers Pwr Co ................................... MI 188,587,672 4.81 Michigan Consol Gas Co........................... MI 160,809,168 5.16 East Ohio Gas Co ..................................... OH 146,802,045 5.44 Pub Svc Elec and Gas Co......................... NJ 140,712,209 6.62 Peoples Gas Lt and Coke Co.................... IL 126,356,925 6.40 Brooklyn Union Gas Co............................. NY 106,349,594 9.43 Atlanta Gas Lt Co ...................................... GA 106,075,815 6.66 Lone Star Gas Co......................................

364

Composition and quantities of retained gas measured in Hanford waste tanks 241-U-103, S-106, BY-101, and BY-109  

DOE Green Energy (OSTI)

This report provides the results obtained for the single-shell tanks (SSTs) sampled with the Retained Gas Sampler (RGS) during 1997: Tanks 241-U-103, 241-S-106, 241-BY-101, and 241-BY-109. The RGS is a modified version of the core sampler used at Hanford. It is designed specifically to be used in concert with the gas extraction equipment in the hot cell to capture and extrude a gas-containing waste sample in a hermetically sealed system. The four tanks represent several different types of flammable gas SSTs. Tank U-103 is on the Flammable Gas Watch List (FGWL) and is one of the highest-priority group of SSTs that show evidence of significant gas retention. Tank S-106, though not a FGWL tank, has a uniquely high barometric pressure response and continuing rapid surface level rise, indicating a large and increasing volume of retained gas. Tanks BY-101 and BY-109 are not on the FGWL but were chosen to test the effect of recent salt-well pumping on gas retention. Section 2 of this report provides an overview of the process by which retained gases in the Hanford tanks are sampled and analyzed. A detailed description of the procedure used to reduce and analyze the data is provided in Section 3. Tank-by-tank results are covered in Section 4 (with the data presented in the order in which the tanks were sampled), and an RGS system performance overview is given in Section 5. Section 6 presents conclusions from these analyses and recommendations for further research. The cited references are listed in Section 7. Appendix A describes the procedures used to extract gas and ammonia from the samples, Appendix B contains detailed laboratory data from each of the tanks, and Appendix C gives field sampling data.

Mahoney, L.A.; Antoniak, Z.I.; Bates, J.M.

1997-12-01T23:59:59.000Z

365

Coke gasification: the influence and behavior of inherent catalytic mineral matter  

Science Conference Proceedings (OSTI)

Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

2009-04-15T23:59:59.000Z

366

Biological production of ethanol from waste gases with Clostridium ljungdahlii  

DOE Patents (OSTI)

A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

Gaddy, James L. (Fayetteville, AR)

2000-01-01T23:59:59.000Z

367

Evaluation of fly ash from co-combustion of coal and petroleum coke for use in concrete  

Science Conference Proceedings (OSTI)

An investigation of fly ash (FA) produced from various blends of coal and petroleum coke (pet coke) fired at Belledune Generating Station, New Brunswick, Canada, was conducted to establish its performance relative to FA derived from coal-only combustion and its compliance with CSA A3000. The FA samples were beneficiated by an electrostatic separation process to produce samples for testing with a range of loss-on-ignition (LOI) values. The results of these studies indicate that the combustion of pet coke results in very little inorganic residue (for example, typically less than 0.5% ash) and the main impact on FA resulting from the co-combustion of coal and up to 25% pet coke is an increase in the unburned carbon content and LOI values. The testing of FA after beneficiation indicates that FA produced from fuels with up to 25% pet coke performs as good as FA produced from the same coal without pet coke.

Scott, A.N.; Thomas, M.D.A.

2007-01-15T23:59:59.000Z

368

Assessment of General Atomics accelerator transmutation of waste concept based on gas-turbine-modular helium cooled reactor technology.  

Science Conference Proceedings (OSTI)

An assessment has been performed for an Accelerator Transmutation of Waste (ATW) concept based on the use of the high temperature gas reactor technology. The concept has been proposed by General Atomics for the ATW system. The assessment was jointly conducted at Argonne National Laboratory (ANL) and Los Alamos national laboratory to assess and to define the potential candidates for the ATW system. This report represents the assessment work performed at ANL. The concept uses recycled light water reactor (LWR)-discharge-transuranic extracted from irradiated oxide fuel in a critical and sub-critical accelerator driven gas-cooled transmuter. In this concept, the transmuter operates at 600 MWt first in the critical mode for three cycles and then operates in a subcritical accelerator-driven mode for a single cycle. The transmuter contains both thermal and fast spectrum transmutation zones. The thermal zone is fueled with the TRU oxide material in the form of coated particles, which are mixed with graphite powder, packed into cylindrical compacts, and loaded in hexagonal graphite blocks with cylindrical channels; the fast zone is fueled with TRU-oxide material in the form of coated particles without the graphite powder and the graphite blocks that has been burned in the thermal region for three critical cycles and one additional accelerator-driven cycle. The fuel loaded into the fast zone is irradiated for four additional cycles. This fuel management scheme is intended to achieve a high Pu isotopes consumption in the thermal spectrum zone, and to consume the minor actinides in the fast-spectrum zone. Monte Carlo and deterministic codes have been used to assess the system performance and to determine the feasibility of achieving high TRU consumption levels. The studies revealed the potential for high consumption of Pu-239 (97%), total Pu (71%) and total TRU (64%) in the system. The analyses confirmed the need for burnable absorber for both suppressing the initial excess reactivity and ensuring a negative temperature coefficient under all operating conditions. Additionally, current results suggest that it may be preferable to use a double strata thermal critical system and fast subcritical system to achieve nearly complete destruction of the TRU oxide fuel. The report gives a general description of the system proposed by General Atomics. The major design parameters (degrees of freedom), which can be altered to optimize the system design, and the constraints, which guide the design and the optimization studies are described. The deterministic and the Monte Carlo neutronics codes and models used for the neutronics analysis and assessment are presented. The results of fuel block and whole-core parametric studies performed to understand the physics are given including the effect of various fuel management schemes on the system performance. A point design is described including the system performance results for a single-batch and three-batch loading schemes. The major design issues, which need to be addressed during further studies, are discussed.

Gohar, Y.; Taiwo, T. A.; Cahalan, J. E.; Finck, P. J.

2001-05-08T23:59:59.000Z

369

Innovative coal gas cleaning at Sparrows Point Coal Chemical Plant, Maryland for Bethlehem Steel Corporation  

SciTech Connect

In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the disposal problems associated with an unmarketable ammonium sulfate by-product. Significant reduction in benzene and hydrogen cyanide emissions are also obtained.

Antrobus, K.; Platts, M. (Davy/Still Otto, Pittsburgh, PA (US)); Harbold, L. (Bethlehem Steel Corp., PA (USA)); Kornosky, R. (Office of Clean Coal Technology, US DOE, Pittsburgh, PA (US))

1990-01-01T23:59:59.000Z

370

Fuel gas production from animal waste: Phase I. Quarterly progress report (2nd), September 1, 1976--December 1, 1976. Dynatech report No. 1556  

DOE Green Energy (OSTI)

During this second quarter, meetings were held with contractors on the ERDA Fuel Gas from Animal Waste Program to discuss project planning and review. Site visits were made to groups involved in anaerobic digestion. An engineering and economic analysis of a process for the anaerobic digestion of animal residue was completed; the results can be used for the design of a pilot plant unit. A comprehensive engineering report of this analysis was completed, and a first draft was submitted to ERDA. Several proposals were received from ERDA and reviewed.

Ashare, E.; Wentworth, R.L.; Wise, D.L.; Augenstein, D.C.

1976-12-08T23:59:59.000Z

371

Characterization of tuyere-level core-drill coke samples from blast furnace operation  

SciTech Connect

A suite of tuyere-level coke samples have been withdrawn from a working blast furnace during coal injection, using the core-drilling technique. The samples have been characterized by size exclusion chromatography (SEC), Fourier transform Raman spectroscopy (FT-RS), and X-ray powder diffraction (XRD) spectroscopy. The 1-methyl-2-pyrrolidinone (NMP) extracts of the cokes sampled from the 'bosh', the rear of the 'bird's nest', and the 'dead man' zones were found by SEC to contain heavy soot-like materials (ca. 10{sup 7}-10{sup 8} apparent mass units). In contrast, NMP extracts of cokes taken from the raceway and the front of the 'bird's nest' only contained a small amount of material of relatively lower apparent molecular mass (up to ca. 10{sup 5} u). Since the feed coke contained no materials extractable by the present method, the soot-like materials are thought to have formed during the reactions of volatile matter released from the injectant coal, probably via dehydrogenation and repolymerization of the tars. The Raman spectra of the NMP-extracted core-drilled coke samples showed variations reflecting their temperature histories. Area ratios of D-band to G-band decreased as the exposure temperature increased, while intensity ratios of D to G band and those of 2D to G bands increased with temperature. The graphitic (G), defect (D), and random (R) fractions of the carbon structure of the cokes were also derived from the Raman spectra. The R fractions decreased with increasing temperature, whereas G fractions increased, while the D fractions showed a more complex variation with temperature. These data appear to give clues regarding the graphitization mechanism of tuyere-level cokes in the blast furnace. 41 refs., 9 figs., 6 tabs.

S. Dong; N. Paterson; S.G. Kazarian; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2007-12-15T23:59:59.000Z

372

Development of an impedance-based sensor for the detection of catalyst coking in fuel-reforming systems.  

E-Print Network (OSTI)

??A novel sensor for detecting the early stages of catalyst coking in fuel reforming systems has been developed. The sensor was manufactured by inkjet printing… (more)

Wheeler, Jeffrey L.

2013-01-01T23:59:59.000Z

373

Dale Coke: Coke Farm  

E-Print Network (OSTI)

to Alice Waters’ Chez Panisse Restaurant in Berkeley, andlater other high-end restaurants across the country. Cokemostly geared toward the restaurant trade, because that’s

Farmer, Ellen

2010-01-01T23:59:59.000Z

374

Dale Coke: Coke Farm  

E-Print Network (OSTI)

the right place to get compost, or how you get the beststerilized or pasteurized our compost before we put it out.

Farmer, Ellen

2010-01-01T23:59:59.000Z

375

Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Observation of Waste Treatment and Immobilization Plant LAW Melter and Melter Off-gas Process System Hazards Analysis _Oct 21-31  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HSS Independent Activity Report - HSS Independent Activity Report - Rev. 0 Report Number: HIAR-WTP-2013-10-21 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Observation of Waste Treatment and Immobilization Plant Low Activity Waste Melter and Melter Off-gas Process System Hazards Analysis Activities Dates of Activity : 10/21/13 - 10/31/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS), Office of Safety and Emergency Management Evaluations (Independent Oversight) reviewed the Insight software hazard evaluation (HE) tables for hazard analysis (HA) generated to date for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter and Off-gas systems, observed a

376

Reduction of phosphogypsum with high-sulfur petroleum coke  

Science Conference Proceedings (OSTI)

Production of concentrated simple and complex fertilizers which contain P/sub 2/O/sub 5/ in water-soluble form is accomplished on the basis of wet-process phosphoric acid, which is produced by sulfuric acid decomposition of phosphate raw materials. A waste product of production of wet-process phosphoric acid is phosphogypsum (4.2-5.6 t dry dihydrate per t P/sub 2/O/sub 5/ in the phosphoric acid). Solving the problems related to utilization of phosphogypsum often becomes the limiting factor in the construction of new enterprises and the expansion of existing ones. Utilizing phosphogypsum is a basic requirement for the creation of zero-waste technology for production of phosphorus-containing fertilizers. This article discusses the production of sulfuric acid and calcium oxide (cement) by reductive decomposition of this large-tonnage waste.

Smolenskaya, E.A.; Koshkarov, V.Y.; Prokhorov, A.G.

1983-03-01T23:59:59.000Z

377

Issues Impacting Refractory Service Life in Biomass/Waste Gasification  

Science Conference Proceedings (OSTI)

Different carbon sources are used, or are being considered, as feedstock for gasifiers; including natural gas, coal, petroleum coke, and biomass. Biomass has been used with limited success because of issues such as ash impurity interactions with the refractory liner, which will be discussed in this paper.

Bennett, J.P.; Kwong, K.-S.; Powell, C.A.

2007-03-01T23:59:59.000Z

378

Quantification of greenhouse gas emissions from waste management processes for municipalities - A comparative review focusing on Africa  

Science Conference Proceedings (OSTI)

The amount of greenhouse gases (GHG) emitted due to waste management in the cities of developing countries is predicted to rise considerably in the near future; however, these countries have a series of problems in accounting and reporting these gases. Some of these problems are related to the status quo of waste management in the developing world and some to the lack of a coherent framework for accounting and reporting of greenhouse gases from waste at municipal level. This review summarizes and compares GHG emissions from individual waste management processes which make up a municipal waste management system, with an emphasis on developing countries and, in particular, Africa. It should be seen as a first step towards developing a more holistic GHG accounting model for municipalities. The comparison between these emissions from developed and developing countries at process level, reveals that there is agreement on the magnitude of the emissions expected from each process (generation of waste, collection and transport, disposal and recycling). The highest GHG savings are achieved through recycling, and these savings would be even higher in developing countries which rely on coal for energy production (e.g. South Africa, India and China) and where non-motorized collection and transport is used. The highest emissions are due to the methane released by dumpsites and landfills, and these emissions are predicted to increase significantly, unless more of the methane is captured and either flared or used for energy generation. The clean development mechanism (CDM) projects implemented in the developing world have made some progress in this field; however, African countries lag behind.

Friedrich, Elena, E-mail: Friedriche@ukzn.ac.za [CRECHE Centre for Research in Environmental, Coastal and Hydrological Engineering, School of Civil Engineering, Surveying and Construction, University of KwaZulu-Natal, Howard College Campus, Durban (South Africa); Trois, Cristina [CRECHE Centre for Research in Environmental, Coastal and Hydrological Engineering, School of Civil Engineering, Surveying and Construction, University of KwaZulu-Natal, Howard College Campus, Durban (South Africa)

2011-07-15T23:59:59.000Z

379

What's Happening to Our Body after Drinking Coke? The Characteristic of the Blood Pressure Wave in Radial Artery  

Science Conference Proceedings (OSTI)

Previous literature has suggested that psychological state may be changed via drinking coke, however, studies empirically documenting the link between coke and blood pressure wave (BPW) are scant. Therefore, the current article attempts to explore how ... Keywords: Blood pressure wave (BPW), spectrum analysis, Sphygmogram, Traditional Chinese medicine (TCM)

Sheng-Chieh Huang; Yung-Pin Lee; Min-Hua Hsieh; Hui-Min Wang; Mark C. Hou; Shih-Chun Chao; Cheng-Lung Tseng; Wei-Ta Hsiao; Chung-Hung Hong; Kai-Yu Shao; Shi-Han Luo; Wei-Chun Chiu; Wei-Yu Chen

2011-12-01T23:59:59.000Z

380

An active carbon catalyst prevents coke formation from asphaltenes during the hydrocracking of vacuum residue  

SciTech Connect

Active carbons were prepared by the steam activation of a brown coal char. The active carbon with mesopores showed greater adsorption selectivity for asphaltenes. The active carbon was effective at suppressing coke formation, even with the high hydrocracking conversion of vacuum residue. The analysis of the change in the composition of saturates, aromatics, resins, and asphaltenes in the cracked residue with conversion demonstrated the ability of active carbon to restrict the transformation of asphaltenes to coke. The active carbon that was richer in mesopores was presumably more effective at providing adsorption sites for the hydrocarbon free-radicals generated initially during thermal cracking to prevent them from coupling and polycondensing.

Fukuyama, H.; Terai, S. [Toyo Engineering Corp., Chiba (Japan). Technological Research Center

2007-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

GAS TURBINES  

E-Print Network (OSTI)

In the age of volatile and ever increasing natural gas fuel prices, strict new emission regulations and technological advancements, modern IGCC plants are the answer to growing market demands for efficient and environmentally friendly power generation. IGCC technology allows the use of low cost opportunity fuels, such as coal, of which there is a more than a 200-year supply in the U.S., and refinery residues, such as petroleum coke and residual oil. Future IGCC plants are expected to be more efficient and have a potential to be a lower cost solution to future CO2 and mercury regulations compared to the direct coal fired steam plants. Siemens has more than 300,000 hours of successful IGCC plant operational experience on a variety of heavy duty gas turbine models in Europe and the U.S. The gas turbines involved range from SGT5-2000E to SGT6-3000E (former designations are shown on Table 1). Future IGCC applications will extend this experience to the SGT5-4000F and SGT6-4000F/5000F/6000G gas turbines. In the currently operating Siemens ’ 60 Hz fleet, the SGT6-5000F gas turbine has the most operating engines and the most cumulative operating hours. Over the years, advancements have increased its performance and decreased its emissions and life cycle costs without impacting reliability. Development has been initiated to verify its readiness for future IGCC application including syngas combustion system testing. Similar efforts are planned for the SGT6-6000G and SGT5-4000F/SGT6-4000F models. This paper discusses the extensive development programs that have been carried out to demonstrate that target emissions and engine operability can be achieved on syngas operation in advanced F-class 50 Hz and 60 Hz gas turbine based IGCC applications.

Power For L; Satish Gadde; Jianfan Wu; Anil Gulati; Gerry Mcquiggan; Berthold Koestlin; Bernd Prade

2006-01-01T23:59:59.000Z

382

Mitigation of Hydrogen Gas Generation from the Reaction of Uranium Metal with Water in K Basin Sludge and Sludge Waste Forms  

DOE Green Energy (OSTI)

Prior laboratory testing identified sodium nitrate and nitrite to be the most promising agents to minimize hydrogen generation from uranium metal aqueous corrosion in Hanford Site K Basin sludge. Of the two, nitrate was determined to be better because of higher chemical capacity, lower toxicity, more reliable efficacy, and fewer side reactions than nitrite. The present lab tests were run to determine if nitrate’s beneficial effects to lower H2 generation in simulated and genuine sludge continued for simulated sludge mixed with agents to immobilize water to help meet the Waste Isolation Pilot Plant (WIPP) waste acceptance drainable liquid criterion. Tests were run at ~60°C, 80°C, and 95°C using near spherical high-purity uranium metal beads and simulated sludge to emulate uranium-rich KW containerized sludge currently residing in engineered containers KW-210 and KW-220. Immobilization agents tested were Portland cement (PC), a commercial blend of PC with sepiolite clay (Aquaset II H), granulated sepiolite clay (Aquaset II G), and sepiolite clay powder (Aquaset II). In all cases except tests with Aquaset II G, the simulated sludge was mixed intimately with the immobilization agent before testing commenced. For the granulated Aquaset II G clay was added to the top of the settled sludge/solution mixture according to manufacturer application directions. The gas volumes and compositions, uranium metal corrosion mass losses, and nitrite, ammonia, and hydroxide concentrations in the interstitial solutions were measured. Uranium metal corrosion rates were compared with rates forecast from the known uranium metal anoxic water corrosion rate law. The ratios of the forecast to the observed rates were calculated to find the corrosion rate attenuation factors. Hydrogen quantities also were measured and compared with quantities expected based on non-attenuated H2 generation at the full forecast anoxic corrosion rate to arrive at H2 attenuation factors. The uranium metal corrosion rates in water alone and in simulated sludge were near or slightly below the metal-in-water rate while nitrate-free sludge/Aquaset II decreased rates by about a factor of 3. Addition of 1 M nitrate to simulated sludge decreased the corrosion rate by a factor of ~5 while 1 M nitrate in sludge/Aquaset II mixtures decreased the corrosion rate by ~2.5 compared with the nitrate-free analogues. Mixtures of simulated sludge with Aquaset II treated with 1 M nitrate had uranium corrosion rates about a factor of 8 to 10 lower than the water-only rate law. Nitrate was found to provide substantial hydrogen mitigation for immobilized simulant sludge waste forms containing Aquaset II or Aquaset II G clay. Hydrogen attenuation factors of 1000 or greater were determined at 60°C for sludge-clay mixtures at 1 M nitrate. Hydrogen mitigation for tests with PC and Aquaset II H (which contains PC) were inconclusive because of suspected failure to overcome induction times and fully enter into anoxic corrosion. Lessening of hydrogen attenuation at ~80°C and ~95°C for simulated sludge and Aquaset II was observed with attenuation factors around 100 to 200 at 1 M nitrate. Valuable additional information has been obtained on the ability of nitrate to attenuate hydrogen gas generation from solution, simulant K Basin sludge, and simulant sludge with immobilization agents. Details on characteristics of the associated reactions were also obtained. The present testing confirms prior work which indicates that nitrate is an effective agent to attenuate hydrogen from uranium metal corrosion in water and simulated K Basin sludge to show that it is also effective in potential candidate solidified K Basin waste forms for WIPP disposal. The hydrogen mitigation afforded by nitrate appears to be sufficient to meet the hydrogen generation limits for shipping various sludge waste streams based on uranium metal concentrations and assumed waste form loadings.

Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

2011-06-08T23:59:59.000Z

383

Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis  

SciTech Connect

Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. (Harvard Center for Risk Analysis, Boston, MA (United States))

1999-04-01T23:59:59.000Z

384

Coal flow aids reduce coke plant operating costs and improve production rates  

Science Conference Proceedings (OSTI)

Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

2005-06-01T23:59:59.000Z

385

Does EIA publish coking coal prices? - FAQ - U.S. Energy ...  

U.S. Energy Information Administration (EIA)

Search EIA.gov. A-Z Index; A-Z Index A B C D E F G H I J K L M N O P Q R S T U V W XYZ. Frequently Asked Questions. Does EIA publish coking coal ...

386

Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector  

E-Print Network (OSTI)

constant heating of the coke ovens ensures optimization ofheating - coke plant Variable speed drive coke oven gasheating - coke plant Variable speed drive coke oven gas

Xu, T.T.

2011-01-01T23:59:59.000Z

387

Life-Cycle Evaluation of Concrete Building Construction as a Strategy for Sustainable Cities  

E-Print Network (OSTI)

coking represents a modern coke plant using standardto produce a ton of coke). The inclusion of parameterconversion of coal feedstock to coke and coke oven gas, for

Stadel, Alexander

2013-01-01T23:59:59.000Z

388

Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst: Final Report, 24 February 2004 -- 23 February 2006  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Heavy-Duty Waste Hauler with Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst Final Report February 24, 2004 - February 23, 2006 T. Reppert Mack Trucks, Inc. Allentown, Pennsylvania J. Chiu Southwest Research Institute San Antonio, Texas Subcontract Report NREL/SR-540-38222 September 2005 Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst Final Report February 24, 2004 - February 23, 2006 T. Reppert Mack Trucks, Inc. Allentown, Pennsylvania J. Chiu Southwest Research Institute San Antonio, Texas NREL Technical Monitor: R. Parish Prepared under Subcontract No. ZCI-4-32049-01 Subcontract Report NREL/SR-540-38222 September 2005 National Renewable Energy Laboratory

389

Production of ethanol from refinery waste gases. Phase 2, technology development, annual report  

DOE Green Energy (OSTI)

Oil refineries discharge large volumes of H{sub 2}, CO, and CO{sub 2} from cracking, coking, and hydrotreating operations. This program seeks to develop a biological process for converting these waste gases into ethanol, which can be blended with gasoline to reduce emissions. Production of ethanol from all 194 US refineries would save 450 billion BTU annually, would reduce crude oil imports by 110 million barrels/year and emissions by 19 million tons/year. Phase II efforts has yielded at least 3 cultures (Clostridium ljungdahlii, Isolate O-52, Isolate C-01) which are able to produce commercially viable concentrations of ethanol from CO, CO{sub 2}, and H{sub 2} in petroleum waste gas. Single continuous stirred tank reactor studies have shown that 15-20 g/L of ethanol can be produced, with less than 5 g/L acetic acid byproduct. Culture and reactor optimization in Phase III should yield even higher ethanol concentrations and minimal acetic acid. Product recovery studies showed that ethanol is best recovered in a multi-step process involving solvent extraction/distillation to azeotrope/azeotropic distillation or pervaporation, or direct distillation to the azeotrope/azeotropic distillation or pervaporation. Projections show that the ethanol facility for a typical refinery would require an investment of about $30 million, which would be returned in less than 2 years.

Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C.; Gaddy, J.L.

1995-07-01T23:59:59.000Z

390

Morphological and Microstructural Characterization of Bio-coke as ...  

Science Conference Proceedings (OSTI)

Alumina-titanium Composites with Improved Fracture Toughness and Electrical Conductivity · Aluminized .... Mechanical and Gas Transport Properties of Hollow Fibers Containing Ionic Liquids for CO2/H2 Separation · Mechanical ... Microstructural Investigation of Nano-Calcium Phosphates Doped with Fluoride Ions.

391

Key China Energy Statistics 2011  

E-Print Network (OSTI)

Gas Works Gas Works - Coke input Briquettes Losses incoal, washed coal, briquettes) and derived fuels (coke,coke oven gas, and other coking products). Crude oil

Levine, Mark

2013-01-01T23:59:59.000Z

392

Challenges and methodology for safety analysis of a high-level waste tank with large periodic releases of flammable gas  

SciTech Connect

Tank 241-SY-101, located at the Department of Energy Hanford Site, has periodically released up to 10,000 ft{sup 3} of flammable gas. This release has been one of the highest-priority DOE operational safety problems. The gases include hydrogen and ammonia (fuels) and nitrous oxide (oxidizer). There have been many opinions regarding the controlling mechanisms for these releases, but demonstrating an adequate understanding of the problem, selecting a mitigation methodology, and preparing the safety analysis have presented numerous new challenges. The mitigation method selected for the tank was to install a pump that would mix the tank contents and eliminate the sludge layer believed to be responsible for the gas retention and periodic releases. This report will describe the principal analysis methodologies used to prepare the safety assessment for the installation and operation of the pump, and because this activity has been completed, it will describe the results of pump operation.

Edwards, J.N.; Pasamehmetoglu, K.O.; White, J.R. [Los Alamos National Lab., NM (United States); Stewart, C.W. [Pacific Northwest Lab., Richland, WA (United States)

1994-07-01T23:59:59.000Z

393

NETL: News Release - Energy Department Selects First Eight Teams...  

NLE Websites -- All DOE Office Websites (Extended Search)

that produce ultra-clean fuels from a variety of energy resources - conventional crude oil, petroleum coke, refinery wastes, natural gas or coal - and verify the performance of...

394

Microsoft Word - 2006FactSR114.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

of burning a variety of fuels such as coal, natural gas, biomass, petroleum, coke, and municipal waste. Similar complications related to fuel composition variations are...

395

Activity Report for Waste Treatment and Immobilizationi Plant...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Waste Treatment and Immobilization Plant Low Activity Waste Melter Off-gas Process...

396

Electrochemical degradation characteristics of refractory organic pollutants in coking wastewater on multiwall carbon nanotube-modified electrode  

Science Conference Proceedings (OSTI)

The multiwall carbon nanotube-mollified electrode (MWCNT-ME) was fabricated and its electrocatalytic activity of refractory organic pollutants of coking wastewater was investigated. The surface morphology, absorption properties, and the electrochemical ...

Yan Wang; Shujing Sun; Guifu Ding; Hong Wang

2012-01-01T23:59:59.000Z

397

Spectroscopic studies on the formation of coke on individual Fluid Catalytic Cracking particles: the effect of poisoning metal compounds.  

E-Print Network (OSTI)

??The formation of coke on individual Fluid Catalytic Cracking (FCC) catalyst particles was studied using UV/Vis microspectroscopy and confocal fluorescence microscopy, with n-hexane cracking as… (more)

Goetze, J.G.

2013-01-01T23:59:59.000Z

398

Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries  

SciTech Connect

A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti [Technical University of Bari, Bari (Italy). Department of Environmental Engineering and Sustainable Development

2006-03-15T23:59:59.000Z

399

Gas Mileage Tips - Driving More Efficiently  

NLE Websites -- All DOE Office Websites (Extended Search)

Driving More Efficiently Drive Sensibly frustrated driver Aggressive driving (speeding, rapid acceleration and braking) wastes gas. It can lower your gas mileage by 33 percent at...

400

The determination of PCBs in Rocky Flats Type IV waste sludge by gas chromatography/electron capture detection. Part 2  

SciTech Connect

Before disposal, radioactive sludge (Type IV) from Rocky Flats Plant (RFP) must be evaluated for polychlorinated biphenyl (PCB) content. The Type IV sludge consists of organic solvents, degreasers, cutting oils, and transuranic (TRU) waste mixed with calcium silicate (MicroCel E{reg_sign} and Oil Dri{reg_sign} to form a grease or paste-like material. For laboratory testing, a nonradioactive simulated Type 17V RFP sludge was prepared at Argonne National Laboratory-East (ANL-E). This sludge has a composition similar to that expected from field samples. In an earlier effort, a simplified method was developed for extraction, cleanup of extract, and determination of PCBs in samples of simulated sludge spiked with Aroclors 1254 and 1260. The simplified method has now been used to determine the presence and quantities of other Aroclors in the simulated sludge, namely, Aroclors 10 1 6, 1221, 1232, 1242, and 1248. The accuracy and precision of the data for these Aroclors were found to be similar to the data for sludges spiked with Aroclors 1254 and 1260. Since actual sludges may vary in composition, the method was also verified by analyzing another source of Type IV simulated sludge, prepared by Argonne National Laboratory-West (ANL-W).

Parish, K.J.; Applegate, D.V.; Postlethwait, P.D.; Boparai, A.S.; Reedy, G.T.

1994-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Waste-to-wheel analysis of anaerobic-digestion-based renewable natural gas pathways with the GREET model.  

SciTech Connect

In 2009, manure management accounted for 2,356 Gg or 107 billion standard cubic ft of methane (CH{sub 4}) emissions in the United States, equivalent to 0.5% of U.S. natural gas (NG) consumption. Owing to the high global warming potential of methane, capturing and utilizing this methane source could reduce greenhouse gas (GHG) emissions. The extent of that reduction depends on several factors - most notably, how much of this manure-based methane can be captured, how much GHG is produced in the course of converting it to vehicular fuel, and how much GHG was produced by the fossil fuel it might displace. A life-cycle analysis was conducted to quantify these factors and, in so doing, assess the impact of converting methane from animal manure into renewable NG (RNG) and utilizing the gas in vehicles. Several manure-based RNG pathways were characterized in the GREET (Greenhouse gases, Regulated Emissions, and Energy use in Transportation) model, and their fuel-cycle energy use and GHG emissions were compared to petroleum-based pathways as well as to conventional fossil NG pathways. Results show that despite increased total energy use, both fossil fuel use and GHG emissions decline for most RNG pathways as compared with fossil NG and petroleum. However, GHG emissions for RNG pathways are highly dependent on the specifics of the reference case, as well as on the process energy emissions and methane conversion factors assumed for the RNG pathways. The most critical factors are the share of flared controllable CH{sub 4} and the quantity of CH{sub 4} lost during NG extraction in the reference case, the magnitude of N{sub 2}O lost in the anaerobic digestion (AD) process and in AD residue, and the amount of carbon sequestered in AD residue. In many cases, data for these parameters are limited and uncertain. Therefore, more research is needed to gain a better understanding of the range and magnitude of environmental benefits from converting animal manure to RNG via AD.

Han, J.; Mintz, M.; Wang, M. (Energy Systems)

2011-12-14T23:59:59.000Z

402

In-Situ Measurements of Low Enrichment Uranium Holdup Process Gas Piping at K-25 - Paper for Waste Management Symposia 2010 East Tennessee Technology Park Oak Ridge, Tennessee  

SciTech Connect

This document is the final version of a paper submitted to the Waste Management Symposia, Phoenix, 2010, abstract BJC/OR-3280. The primary document from which this paper was condensed is In-Situ Measurement of Low Enrichment Uranium Holdup in Process Gas Piping at K-25 Using NaI/HMS4 Gamma Detection Systems, BJC/OR-3355. This work explores the sufficiency and limitations of the Holdup Measurement System 4 (HJVIS4) software algorithms applied to measurements of low enriched uranium holdup in gaseous diffusion process gas piping. HMS4 has been used extensively during the decommissioning and demolition project of the K-25 building for U-235 holdup quantification. The HMS4 software is an integral part of one of the primary nondestructive assay (NDA) systems which was successfully tested and qualified for holdup deposit quantification in the process gas piping of the K-25 building. The initial qualification focused on the measurement of highly enriched UO{sub 2}F{sub 2} deposits. The purpose of this work was to determine if that qualification could be extended to include the quantification of holdup in UO{sub 2}F{sub 2} deposits of lower enrichment. Sample field data are presented to provide evidence in support of the theoretical foundation. The HMS4 algorithms were investigated in detail and found to sufficiently compensate for UO{sub 2}F{sub 2} source self-attenuation effects, over the range of expected enrichment (4-40%), in the North and East Wings of the K-25 building. The limitations of the HMS4 algorithms were explored for a described set of conditions with respect to area source measurements of low enriched UO{sub 2}F{sub 2} deposits when used in conjunction with a 1 inch by 1/2 inch sodium iodide (NaI) scintillation detector. The theoretical limitations of HMS4, based on the expected conditions in the process gas system of the K-25 building, are related back to the required data quality objectives (DQO) for the NBA measurement system established for the K-25 demolition project. The combined review of the HMS software algorithms and supporting field measurements lead to the conclusion that the majority of process gas pipe measurements are adequately corrected for source self-attenuation using HMS4. While there will be instances where the UO{sub 2}F{sub 2} holdup mass presents an infinitely thick deposit to the NaI-HMS4 system these situations are expected to be infrequent. This work confirms that the HMS4 system can quantify UO{sub 2}F{sub 2} holdup, in its current configuration (deposition, enrichment, and geometry), below the DQO levels for the K-25 building decommissioning and demolition project. For an area measurement of process gas pipe in the K-25 building, if an infinitely thick UO{sub 2}F{sub 2} deposit is identified in the range of enrichment of {approx}4-40%, the holdup quantity exceeds the corresponding DQO established for the K-25 building demolition project.

Rasmussen B.

2010-01-01T23:59:59.000Z

403

Municipal Waste Planning, Recycling and Waste Reduction Act (Pennsylvania)  

Open Energy Info (EERE)

Waste Planning, Recycling and Waste Reduction Act (Pennsylvania) Waste Planning, Recycling and Waste Reduction Act (Pennsylvania) No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Last modified on February 13, 2013. EZFeed Policy Place Pennsylvania Name Municipal Waste Planning, Recycling and Waste Reduction Act (Pennsylvania) Policy Category Other Policy Policy Type Environmental Regulations Affected Technologies Biomass/Biogas, Coal with CCS, Concentrating Solar Power, Energy Storage, Fuel Cells, Geothermal Electric, Hydroelectric, Hydroelectric (Small), Natural Gas, Nuclear, Solar Photovoltaics, Wind energy Active Policy Yes Implementing Sector State/Province Program Administrator Pennsylvania Department of Environmental Protection

404

Waste-to-Energy Biomass Digester with Decreased Water Consumption  

The enormous amount of biomass waste created by animal feeding operations releases methane, a valuable fuel but also a greenhouse gas, and other pollutants into the environment. Waste digesters reduce this pollution by converting the waste into ...

405

Biomass Gas Cleanup Using a Therminator  

SciTech Connect

The objective of the project is to develop and demonstrate a novel fluidized-bed process module called a �¢����Therminator�¢��� to simultaneously destroy and/or remove tar, NH3 and H2S from raw syngas produced by a fluidized-bed biomass gasifier. The raw syngas contains as much as 10 g/m3 of tar, 4,000 ppmv of NH3 and 100 ppmv of H2S. The goal of the Therminator module would be to use promising regenerable catalysts developed for removing tar, ammonia, and H2S down to low levels (around 10 ppm). Tars are cracked to a non-condensable gas and coke that would deposit on the acid catalyst. We will deposit coke, much like a fluid catalytic cracker (FCC) in a petroleum refinery. The deposited coke fouls the catalyst, much like FCC, but the coke would be burned off in the regenerator and the regenerated catalyst would be returned to the cracker. The rapid circulation between the cracker and regenerator would ensure the availability of the required amount of regenerated catalyst to accomplish our goal. Also, by removing sulfur down to less than 10 ppmv, NH3 decomposition would also be possible in the cracker at 600-700���°C. In the cracker, tar decomposes and lays down coke on the acid sites of the catalyst, NH3 is decomposed using a small amount of metal (e.g., nickel or iron) catalyst incorporated into the catalyst matrix, and H2S is removed by a small amount of a metal oxide (e.g. zinc oxide or zinc titanate) by the H2S-metal oxide reaction to form metal sulfide. After a tolerable decline in activity for these reactions, the catalyst particles (and additives) are transported to the regenerator where they are exposed to air to remove the coke and to regenerate the metal sulfide back to metal oxide. Sulfate formation is avoided by running the regeneration with slightly sub-stoichiometric quantity of oxygen. Following regeneration, the catalyst is transported back to the cracker and the cycling continues. Analogous to an FCC reactor system, rapid cycling will allow the use of very active cracking catalysts that lose activity due to coking within the order of several seconds.

David C. Dayton; Atish Kataria; Rabhubir Gupta

2012-03-06T23:59:59.000Z

406

China Energy Databook -- User Guide and Documentation, Version 7.0  

E-Print Network (OSTI)

is coke produced in industrial coke ovens. This category isinefficient than industrial coke ovens. This category is noFrom Gas Fields (industrial use) Coke Oven Gas (industrial

Fridley, Ed., David

2008-01-01T23:59:59.000Z

407

Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks  

SciTech Connect

Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

408

Clean Cities: National Clean Fleets Partner: Waste Management  

NLE Websites -- All DOE Office Websites (Extended Search)

for Waste Management. WM's fleet of nearly 1,700 CNG and liquefied natural gas (LNG) vehicles is the largest in the North American waste industry. In 2012, natural gas...

409

MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM - PRELIMINARY REPORT  

SciTech Connect

The Defense Waste Processing Facility (DWPF) is currently evaluating an alternative Chemical Process Cell (CPC) flowsheet to increase throughput. It includes removal of the steam-stripping step, which would significantly reduce the CPC processing time and lessen the sampling needs. However, its downside would be to send 100% of the mercury that come in with the sludge straight to the melter. For example, the new mercury content in the Sludge Batch 5 (SB5) melter feed is projected to be 25 times higher than that in the SB4 with nominal steam stripping of mercury. This task was initiated to study the impact of the worst-case scenario of zero-mercury-removal in the CPC on the DWPF melter off-gas system. It is stressed that this study is intended to be scoping in nature, so the results presented in this report are preliminary. In order to study the impact of elevated mercury levels in the feed, it is necessary to be able to predict how mercury would speciate in the melter exhaust under varying melter operating conditions. A homogeneous gas-phase oxidation model of mercury by chloride was developed to do just that. The model contains two critical parameters pertaining to the partitioning of chloride among HCl, Cl, Cl{sub 2}, and chloride salts in the melter vapor space. The values for these parameters were determined at two different melter vapor space temperatures by matching the calculated molar ratio of HgCl (or Hg{sub 2}Cl{sub 2}) to HgCl{sub 2} with those measured during the Experimental-Scale Ceramic Melter (ESCM) tests run at the Pacific Northwest National Laboratory (PNNL). The calibrated model was then applied to the SB5 simulant used in the earlier flowsheet study with an assumed mercury stripping efficiency of zero; the molar ratio of Cl-to-Hg in the resulting melter feed was only 0.4, compared to 12 for the ESCM feeds. The results of the model run at the indicated melter vapor space temperature of 650 C (TI4085D) showed that due to excessive shortage of chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly, there are many process benefits to be gained by removing the steam-stripping step from the CPC c

Zamecnik, J.; Choi, A.

2009-03-25T23:59:59.000Z

410

MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM-PRELIMINARY REPORT  

SciTech Connect

The Defense Waste Processing Facility (DWPF) is currently evaluating an alternative Chemical Process Cell (CPC) flowsheet to increase throughput. It includes removal of the steam-stripping step, which would significantly reduce the CPC processing time and lessen the sampling needs. However, its downside would be to send 100% of the mercury that comes in with the sludge straight to the melter. For example, the new mercury content in the Sludge Batch 5 (SB5) melter feed is projected to be 25 times higher than that in the SB4 with nominal steam stripping of mercury. This task was initiated to study the impact of the worst-case scenario of zero-mercury-removal in the CPC on the DWPF melter offgas system. It is stressed that this study is intended to be scoping in nature, so the results presented in this report are preliminary. In order to study the impact of elevated mercury levels in the feed, it is necessary to be able to predict how mercury would speciate in the melter exhaust under varying melter operating conditions. A homogeneous gas-phase oxidation model of mercury by chloride was developed to do just that. The model contains two critical parameters pertaining to the partitioning of chloride among HCl, Cl, Cl{sub 2}, and chloride salts in the melter vapor space. The values for these parameters were determined at two different melter vapor space temperatures by matching the calculated molar ratio of HgCl (or Hg{sub 2}Cl{sub 2}) to HgCl{sub 2} with those measured during the Experimental-Scale Ceramic Melter (ESCM) tests run at the Pacific Northwest National Laboratory (PNNL). The calibrated model was then applied to the SB5 simulant used in the earlier flowsheet study with an assumed mercury stripping efficiency of zero; the molar ratio of Cl-to-Hg in the resulting melter feed was only 0.4, compared to 12 for the ESCM feeds. The results of the model run at the indicated melter vapor space temperature of 650 C (TI4085D) showed that due to excessive shortage of chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly, there are many process benefits to be gained by removing the steam-stripping step from the CPC c

Zamecnik, J.; Choi, A.

2010-08-18T23:59:59.000Z

411

Shipment and Disposal of Solidified Organic Waste (Waste Type IV) to the Waste Isolation Pilot Plant (WIPP)  

Science Conference Proceedings (OSTI)

In April of 2005, the last shipment of transuranic (TRU) waste from the Rocky Flats Environmental Technology Site to the WIPP was completed. With the completion of this shipment, all transuranic waste generated and stored at Rocky Flats was successfully removed from the site and shipped to and disposed of at the WIPP. Some of the last waste to be shipped and disposed of at the WIPP was waste consisting of solidified organic liquids that is identified as Waste Type IV in the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC) document. Waste Type IV waste typically has a composition, and associated characteristics, that make it significantly more difficult to ship and dispose of than other Waste Types, especially with respect to gas generation. This paper provides an overview of the experience gained at Rocky Flats for management, transportation and disposal of Type IV waste at WIPP, particularly with respect to gas generation testing. (authors)

D'Amico, E. L [Washington TRU Solutions (United States); Edmiston, D. R. [John Hart and Associates (United States); O'Leary, G. A. [CH2M-WG Idaho, LLC (United States); Rivera, M. A. [Aspen Resources Ltd., Inc. (United States); Steward, D. M. [Boulder Research Enterprises, LLC (United States)

2006-07-01T23:59:59.000Z

412

Development of a Filter Using Absorbent Technologies for the Removal of Coking Precursors: Laboratory Evaluation  

Science Conference Proceedings (OSTI)

On-load tap changers (LTC) are the single biggest contributor to transformer problems. Their failure modes may be mechanical, electrical, or related to the quality of the oil and contacts. Utilities are seeking new strategies for LTC maintenance to minimize these problems and, at the same time, reduce maintenance costs. EPRI has initiated several projects with a goal of producing a maintenance-free LTC. One major LTC problem is contact fouling, which can lead to the buildup of coke deposits on contacts a...

2003-11-24T23:59:59.000Z

413

Form EIA-5 Users Manual Quarterly Coal Consumption and Quality - Coke Plants  

U.S. Energy Information Administration (EIA) Indexed Site

5 5 Users Manual Quarterly Coal Consumption and Quality - Coke Plants Document Number: 001 Version: 2.0 June 2011 i June 2011 Document History Number Date Section Description 1 2 June 2011 June 2011 Document initiation Revised screen shots and remove external user references. Primary POC: Tejasvi Raghuveer Phone: (202) 586-8926 Email: Tejasvi.Raghuveer@eia.gov Document Changes/Maintenance POC: Primary POC: Tejasvi Raghuveer Phone: (202) 586-8926 Email: Tejasvi.Raghuveer@eia.gov Project References: Coal Internet Data Collection (CIDC) User's Manual, September 2007 ii June 2011 Content 1. General System Overview ................................................................................. 1

414

Regulation of Natural Gas (Texas)  

Energy.gov (U.S. Department of Energy (DOE))

This legislation provides for the protection of public and private interests with regards to natural gas production, prohibits waste, and compels ratable production to enable owners of gas in a...

415

Secondary Waste Forms and Technetium Management  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

November 18, 2010 What are Secondary Wastes? Process condensates and scrubber andor off-gas treatment liquids from the pretreatment and ILAW melter facilities at the Hanford WTP....

416

Alternative Fuels Data Center: Natural Gas Vehicle (NGV) Rebate  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Natural Gas Vehicle Natural Gas Vehicle (NGV) Rebate to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Vehicle (NGV) Rebate on Facebook Tweet about Alternative Fuels Data Center: Natural Gas Vehicle (NGV) Rebate on Twitter Bookmark Alternative Fuels Data Center: Natural Gas Vehicle (NGV) Rebate on Google Bookmark Alternative Fuels Data Center: Natural Gas Vehicle (NGV) Rebate on Delicious Rank Alternative Fuels Data Center: Natural Gas Vehicle (NGV) Rebate on Digg Find More places to share Alternative Fuels Data Center: Natural Gas Vehicle (NGV) Rebate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Natural Gas Vehicle (NGV) Rebate Citizens Gas & Coke Utility (Citizens) offers rebates for qualified

417

RSE Table 3.5 Relative Standard Errors for Table 3.5  

U.S. Energy Information Administration (EIA) Indexed Site

5 Relative Standard Errors for Table 3.5;" 5 Relative Standard Errors for Table 3.5;" " Unit: Percents." " "," "," "," "," "," "," "," ","Waste",," " " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars" "NAICS"," "," ","Furnace/Coke","Waste","Petroleum","or","Wood Chips,","and Waste" "Code(a)","Subsector and Industry","Total","Oven Gases","Gas","Coke","Black Liquor","Bark","Materials"

418

"RSE Table N5.1. Relative Standard Errors for Table N5.1;"  

U.S. Energy Information Administration (EIA) Indexed Site

1. Relative Standard Errors for Table N5.1;" 1. Relative Standard Errors for Table N5.1;" " Unit: Percents." " "," "," "," "," "," "," "," ","Waste",," " " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars" "NAICS"," "," ","Furnace/Coke"," ","Petroleum","or","Wood Chips,","and Waste" "Code(a)","Subsector and Industry","Total","Oven Gases","Waste Gas","Coke","Black Liquor","Bark","Materials"

419

Mixed waste characterization reference document  

SciTech Connect

Waste characterization and monitoring are major activities in the management of waste from generation through storage and treatment to disposal. Adequate waste characterization is necessary to ensure safe storage, selection of appropriate and effective treatment, and adherence to disposal standards. For some wastes characterization objectives can be difficult and costly to achieve. The purpose of this document is to evaluate costs of characterizing one such waste type, mixed (hazardous and radioactive) waste. For the purpose of this document, waste characterization includes treatment system monitoring, where monitoring is a supplement or substitute for waste characterization. This document establishes a cost baseline for mixed waste characterization and treatment system monitoring requirements from which to evaluate alternatives. The cost baseline established as part of this work includes costs for a thermal treatment technology (i.e., a rotary kiln incinerator), a nonthermal treatment process (i.e., waste sorting, macronencapsulation, and catalytic wet oxidation), and no treatment (i.e., disposal of waste at the Waste Isolation Pilot Plant (WIPP)). The analysis of improvement over the baseline includes assessment of promising areas for technology development in front-end waste characterization, process equipment, off gas controls, and monitoring. Based on this assessment, an ideal characterization and monitoring configuration is described that minimizes costs and optimizes resources required for waste characterization.

1997-09-01T23:59:59.000Z

420

Delayed Coking  

U.S. Energy Information Administration (EIA)

-No Data Reported; --= Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: See Definitions ...

Note: This page contains sample records for the topic "waste gas coke" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Petroleum Coke  

U.S. Energy Information Administration (EIA)

-No Data Reported; --= Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: Includes volumes uses as ...

422

Petroleum Coke  

Annual Energy Outlook 2012 (EIA)

88,015 81,811 82,516 82,971 84,053 85,190 1986-2012 East Coast (PADD 1) 11,973 12,198 10,887 9,316 9,766 9,003 1986-2012 Midwest (PADD 2) 15,701 15,005 15,507 16,480 16,834 17,611...

423

Bioconversion of waste biomass to useful products  

DOE Patents (OSTI)

A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, bacillus smithii ATCC No. 55404.

Grady, James L. (Fayetteville, AR); Chen, Guang Jiong (Fayetteville, AR)

1998-01-01T23:59:59.000Z

424

Bioconversion of waste biomass to useful products  

DOE Patents (OSTI)

A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, Bacillus smithii ATCC No. 55404. 82 figs.

Grady, J.L.; Chen, G.J.

1998-10-13T23:59:59.000Z

425

Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking  

SciTech Connect

1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

2007-09-15T23:59:59.000Z

426

Methodology for flammable gas evaluations  

DOE Green Energy (OSTI)

There are 177 radioactive waste storage tanks at the Hanford Site. The waste generates flammable gases. The waste releases gas continuously, but in some tanks the waste has shown a tendency to trap these flammable gases. When enough gas is trapped in a tank`s waste matrix, it may be released in a way that renders part or all of the tank atmosphere flammable for a period of time. Tanks must be evaluated against previously defined criteria to determine whether they can present a flammable gas hazard. This document presents the methodology for evaluating tanks in two areas of concern in the tank headspace:steady-state flammable-gas concentration resulting from continuous release, and concentration resulting from an episodic gas release.

Hopkins, J.D., Westinghouse Hanford

1996-06-12T23:59:59.000Z

427

ZERO WASTE.  

E-Print Network (OSTI)

??The aim of the thesis was to develop a clear vision on better waste management system. The thesis introduced the sustainable waste management along with… (more)

Upadhyaya, Luv

2013-01-01T23:59:59.000Z

428

Energy from Waste: A good practice guide  

E-Print Network (OSTI)

and regulation of Energy from Waste 16 5. The planning context 18 6. Waste characterisation, composition 9. Processed waste technologies 36 10. Flue gas treatment options 40 11. Residue management 47 12; an approach that focuses on repeatedly benefiting from a materials~ natural attributes before finally

Columbia University

429

Conservation of Oil and Gas (Texas)  

Energy.gov (U.S. Department of Energy (DOE))

This legislation prohibits the production, storage, or transportation of oil or gas in a manner, in an amount, or under conditions that constitute waste. Actions which may lead to the waste of oil...

430

Gas Turbine Manufacturers Perspective  

NLE Websites -- All DOE Office Websites (Extended Search)

are still comparatively high, the low level and stability of petroleum coke, coal, and oiltar residue feedstock prices can be shown to easily overcome this disadvantage when a...

431

Tritium waste package  

DOE Patents (OSTI)

A containment and waste package system for processing and shipping tritium oxide waste received from a process gas includes an outer drum and an inner drum containing a disposable molecular sieve bed (DMSB) seated within outer drum. The DMSB includes an inlet diffuser assembly, an outlet diffuser assembly, and a hydrogen catalytic recombiner. The DMSB adsorbs tritium oxide from the process gas and converts it to a solid form so that the tritium is contained during shipment to a disposal site. The DMSB is filled with type 4A molecular sieve pellets capable of adsorbing up to 1000 curies of tritium. The recombiner contains a sufficient amount of catalyst to cause any hydrogen and oxygen present in the process gas to recombine to form water vapor, which is then adsorbed onto the DMSB.

Rossmassler, R.; Ciebiera, L.; Tulipano, F.J.; Vinson, S.; Walters, R.T.

1994-12-31T23:59:59.000Z

432

Tritium waste package  

DOE Patents (OSTI)

A containment and waste package system for processing and shipping tritium xide waste received from a process gas includes an outer drum and an inner drum containing a disposable molecular sieve bed (DMSB) seated within outer drum. The DMSB includes an inlet diffuser assembly, an outlet diffuser assembly, and a hydrogen catalytic recombiner. The DMSB absorbs tritium oxide from the process gas and converts it to a solid form so that the tritium is contained during shipment to a disposal site. The DMSB is filled with type 4A molecular sieve pellets capable of adsorbing up to 1000 curies of tritium. The recombiner contains a sufficient amount of catalyst to cause any hydrogen add oxygen present in the process gas to recombine to form water vapor, which is then adsorbed onto the DMSB.

Rossmassler, Rich (Cranbury, NJ); Ciebiera, Lloyd (Titusville, NJ); Tulipano, Francis J. (Teaneck, NJ); Vinson, Sylvester (Ewing, NJ); Walters, R. Thomas (Lawrenceville, NJ)

1995-01-01T23:59:59.000Z

433

Tritium waste package  

DOE Patents (OSTI)

A containment and waste package system for processing and shipping tritium oxide waste received from a process gas includes an outer drum and an inner drum containing a disposable molecular sieve bed (DMSB) seated within the outer drum. The DMSB includes an inlet diffuser assembly, an outlet diffuser assembly, and a hydrogen catalytic recombiner. The DMSB absorbs tritium oxide from the process gas and converts it to a solid form so that the tritium is contained during shipment to a disposal site. The DMSB is filled with type 4A molecular sieve pellets capable of adsorbing up to 1000 curies of tritium. The recombiner contains a sufficient amount of catalyst to cause any hydrogen and oxygen present in the process gas to recombine to form water vapor, which is then adsorbed onto the DMSB. 1 fig.

Rossmassler, R.; Ciebiera, L.; Tulipano, F.J.; Vinson, S.; Walters, R.T.

1995-11-07T23:59:59.000Z

434

Estimating Waste Inventory and Waste Tank Characterization |...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Estimating Waste Inventory and Waste Tank Characterization Estimating Waste Inventory and Waste Tank Characterization Summary Notes from 28 May 2008 Generic Technical Issue...

435

Evaluation of the Implementation of Contained Recovery of Oily Waste (CROW(TM)) Enhanced Recovery at a Manufactured Gas Plant Site  

Science Conference Proceedings (OSTI)

This report describes the implementation of an enhanced tar recovery remediation system at a former Manufactured Gas Plant (MGP) site. The project included investigations, treatability and testing, cost analysis, system design, construction, and operations.

1999-11-03T23:59:59.000Z

436

Disposal of NORM waste in salt caverns  

Science Conference Proceedings (OSTI)

Some types of oil and gas production and processing wastes contain naturally occurring radioactive materials (NORM). If NORM is present at concentrations above regulatory levels in oil field waste, the waste requires special disposal practices. The existing disposal options for wastes containing NORM are limited and costly. This paper evaluates the legality, technical feasibility, economics, and human health risk of disposing of NORM-contaminated oil field wastes in salt caverns. Cavern disposal of NORM waste is technically feasible and poses a very low human health risk. From a legal perspective, there are no fatal flaws that would prevent a state regulatory agency from approving cavern disposal of NORM. On the basis of the costs charged by caverns currently used for disposal of nonhazardous oil field waste (NOW), NORM waste disposal caverns could be cost competitive with existing NORM waste disposal methods when regulatory agencies approve the practice.

Veil, J.A.; Smith, K.P.; Tomasko, D.; Elcock, D.; Blunt, D.; Williams, G.P.

1998-07-01T23:59:59.000Z

437

Minor actinide waste disposal in deep geological boreholes  

E-Print Network (OSTI)

The purpose of this investigation was to evaluate a waste canister design suitable for the disposal of vitrified minor actinide waste in deep geological boreholes using conventional oil/gas/geothermal drilling technology. ...

Sizer, Calvin Gregory

2006-01-01T23:59:59.000Z

438

Treatment of halogen-containing waste and other waste materials  

DOE Patents (OSTI)

A process is described for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes. 3 figs.

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

1997-03-18T23:59:59.000Z

439

Treatment of halogen-containing waste and other waste materials  

DOE Patents (OSTI)

A process for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes.

Forsberg, Charles W. (Oak Ridge, TN); Beahm, Edward C. (Oak Ridge, TN); Parker, George W. (Concord, TN)

1997-01-01T23:59:59.000Z

440

Mineral-wool industry: opportunities for natural gas technologies. Topical report, January-July 1987  

SciTech Connect

To quantify the opportunities for natural gas and identify technological advances needed to capture such opportunities, the mineral-wool industry was analyzed with respect to the principal companies, their capabilities, and markets. The mineral-wool industry is stable with a slightly declining market. Of its market segments, only commercial acoustic insulation (which is currently dominant) is likely to be affected by growth in the next ten years. The principal process is based on treatment of blast-furnace slags in a cupola furnace using coke as the fuel and reducing agent. Expanded use of gas, as a substitute for coke, would eliminate environmental problems and expand the latitude of suitable raw materials. The study provides insights into the mineral-wool industry and identifies factors that may constitute bases for future usage of natural gas.

Not Available

1988-05-01T23:59:59.000Z

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441

Idaho Site Launches Corrective Actions Before Restarting Waste Treatment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Corrective Actions Before Restarting Waste Corrective Actions Before Restarting Waste Treatment Facility Idaho Site Launches Corrective Actions Before Restarting Waste Treatment Facility September 13, 2012 - 12:00pm Addthis Pictured here is the Integrated Waste Treatment Unit's off-gas filter following the June incident. Pictured here is the Integrated Waste Treatment Unit's off-gas filter following the June incident. A view of the process piping installations prior to startup of the Integrated Waste Treatment Unit. A view of the process piping installations prior to startup of the Integrated Waste Treatment Unit. Pictured here is the Integrated Waste Treatment Unit's off-gas filter following the June incident. A view of the process piping installations prior to startup of the Integrated Waste Treatment Unit.

442

Key China Energy Statistics 2012  

E-Print Network (OSTI)

coal, washed coal, briquettes) and derived fuels (coke,coke oven gas, and other coking products). Crude oilWashed Coal Mt Briquettes Mt Coke Mt Coke Oven Gas Billion m

Levine, Mark

2013-01-01T23:59:59.000Z

443

Production of ethanol from refinery waste gases. Phase 3. Engineering development. Annual report, April 1, 1995--May 15, 1996  

DOE Green Energy (OSTI)

Refineries discharge large volumes of H2, CO, and CO 2 from cracking, coking, and hydrotreating operations. This R&D program seeks to develop, demonstrate, and commercialize a biological process for converting these waste gases into ethanol for blending with gasoline. A 200,000 BPD refinery could produce up to 38 million gallons ethanol per year. The program is being conducted in 3 phases: II, technology development; III, engineering development; and IV, demonstration. Phase I, exploratory development, has bee