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Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
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1

Comparing the greenhouse gas emissions from three alternative waste combustion concepts  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Significant GHG reductions are possible by efficient WtE technologies. Black-Right-Pointing-Pointer CHP and high power-to-heat ratio provide significant GHG savings. Black-Right-Pointing-Pointer N{sub 2}O and coal mine type are important in LCA GHG emissions of FBC co-combustion. Black-Right-Pointing-Pointer Substituting coal and fuel oil by waste is beneficial in electricity and heat production. Black-Right-Pointing-Pointer Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO{sub 2}-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

Vainikka, Pasi, E-mail: pasi.vainikka@vtt.fi [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Tsupari, Eemeli; Sipilae, Kai [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Hupa, Mikko [Aabo Akademi Process Chemistry Centre, Piispankatu 8, FIN 20500 Turku (Finland)

2012-03-15T23:59:59.000Z

2

Municipal Waste Combustion (New Mexico)  

Energy.gov (U.S. Department of Energy (DOE))

This rule establishes requirements for emissions from, and design and operation of, municipal waste combustion units. "Municipal waste" means all materials and substances discarded from residential...

3

Prototype demonstration of dual sorbent injection for acid gas control on municipal solid waste combustion units  

SciTech Connect

This report gathered and evaluated emissions and operations data associated with furnace injection of dry hydrated lime and duct injection of dry sodium bicarbonate at a commercial, 1500 ton per day, waste-to-energy facility. The information compiled during the project sheds light on these sorbents to affect acid gas emissions from municipal solid waste combustors. The information assesses the capability of these systems to meet the 1990 Clean Air Act and 1991 EPA Emission Guidelines.

None

1994-05-01T23:59:59.000Z

4

Particulate waste product combustion system  

SciTech Connect

An apparatus is described for incinerating combustion material within a fluidized bed, including the steps of: feeding the material into a fluidizing zone within which the bed is formed; introducing combustion supporting gas to the fluidizing zone in a plurality of inflow streams of different velocities insufficient to fluidize the material; continuously agitating the material to mechanically fluidize the same within the fluidizing zone during combustion and cause displacement of residual ash from the zone; and withdrawing the residual ash from a discharge location in the apparatus outside of the fluidizing zone.

Chastain, C.E.; King, D.R.

1986-05-20T23:59:59.000Z

5

Method for storing radioactive combustible waste  

DOE Patents (OSTI)

A method is described for preventing pressure buildup in sealed containers which contain radioactively contaminated combustible waste material by adding an oxide getter material to the container so as to chemically bind sorbed water and combustion product gases. (Official Gazette)

Godbee, H.W.; Lovelace, R.C.

1973-10-01T23:59:59.000Z

6

Gas turbine combustion instability  

DOE Green Energy (OSTI)

Combustion oscillations are a common problem in development of LPM (lean premix) combustors. Unlike earlier, diffusion style combustors, LPM combustors are especially susceptible to oscillations because acoustic losses are smaller and operation near lean blowoff produces a greater combustion response to disturbances in reactant supply, mixing, etc. In ongoing tests at METC, five instability mechanisms have been identified in subscale and commercial scale nozzle tests. Changes to fuel nozzle geometry showed that it is possible to stabilize combustion by altering the timing of the feedback between acoustic waves and the variation in heat release.

Richards, G.A.; Lee, G.T.

1996-09-01T23:59:59.000Z

7

Chemical Characterization of Fossil Fuel Combustion Wastes  

Science Conference Proceedings (OSTI)

Fossil fuel combustion wastes differ considerably in total composition and in the key chemical characteristics of their extracts, making leachate composition difficult to predict. A new mechanistic approach, however, shows promise for more-accurate prediction.

1987-08-26T23:59:59.000Z

8

COMBUSTION  

E-Print Network (OSTI)

This document presents an overview of combustion as a waste management strategy in relation to the development of material-specific emission factors for EPA’s Waste Reduction Model (WARM). Included are estimates of the net greenhouse gas (GHG) emissions from combustion of most of the materials considered in WARM and several categories of mixed waste. 1. A SUMMARY OF THE GHG IMPLICATIONS OF COMBUSTION Combustion of municipal solid waste (MSW) results in emissions of CO 2 and N2O. Note that CO2 from combustion of biomass (such as paper products and yard trimmings) is not counted because it is biogenic (as explained in the Introduction & Overview chapter). WARM estimates emissions from combustion of MSW in waste-to-energy (WTE) facilities. WARM does not consider any recovery of materials from the MSW stream that may occur before MSW is delivered to the combustor. WTE facilities can be divided into three categories: (1) mass burn, (2) modular and (3) refusederived fuel (RDF). A mass burn facility generates electricity and/or steam from the combustion of

unknown authors

2012-01-01T23:59:59.000Z

9

Premixed Combustion of Hydrogen Augmented Natural Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

premixed combustion * Effective for emission reduction with natural gas * High hydrogen flame speed requires care in premixer design for SGH fuels * UC Irvine study quantifies...

10

Combustion modeling in waste tanks  

DOE Green Energy (OSTI)

This paper has two objectives. The first one is to repeat previous simulations of release and combustion of flammable gases in tank SY-101 at the Hanford reservation with the recently developed code GASFLOW-II. The GASFLOW-II results are compared with the results obtained with the HMS/TRAC code and show good agreement, especially for non-combustion cases. For combustion GASFLOW-II predicts a steeper pressure rise than HMS/TRAC. The second objective is to describe a so-called induction parameter model which was developed and implemented into GASFLOW-II and reassess previous calculations of Bureau of Mines experiments for hydrogen-air combustion. The pressure time history improves compared with the one-step model, and the time rate of pressure change is much closer to the experimental data.

Mueller, C.; Unal, C. [Los Alamos National Lab., NM (United States); Travis, J.R. [Los Alamos National Lab., NM (United States)]|[Forschungszentrum Karlsruhe (Germany). Inst. fuer Reaktorsicherheit

1997-08-01T23:59:59.000Z

11

Particulate Waste Product Combustion System  

E-Print Network (OSTI)

The disposal of low value by-products from the processing of agricultural food crops presents many energy consuming problems to the food producing industry. Consequently, industry has the continuous problem of utilization or disposal of the by-products within the frame work of its economic structure. The system presented here is an approach to an economical way of utilizing waste by-products for an energy source there-by reducing dependency on traditional fuel sources.

King, D. R.; Chastain, C. E.

1984-01-01T23:59:59.000Z

12

Study of abnormal combustion oscillations in gas fired appliances.  

E-Print Network (OSTI)

??The thesis work discusses abnormal combustion noise in gas-fired appliances. An experimental model was made to provide insight into the causes of abnormal combustion noises.… (more)

Kumar, Dasari

2006-01-01T23:59:59.000Z

13

Combustion modeling in advanced gas turbine systems  

DOE Green Energy (OSTI)

Goal of DOE`s Advanced Turbine Systems program is to develop and commercialize ultra-high efficiency, environmentally superior, cost competitive gas turbine systems for base-load applications in utility, independent power producer, and industrial markets. Primary objective of the program here is to develop a comprehensive combustion model for advanced gas turbine combustion systems using natural gas (coal gasification or biomass fuels). The efforts included code evaluation (PCGC-3), coherent anti-Stokes Raman spectroscopy, laser Doppler anemometry, and laser-induced fluorescence.

Smoot, L.D.; Hedman, P.O.; Fletcher, T.H.; Brewster, B.S.; Kramer, S.K. [Brigham Young Univ., Provo, UT (United States). Advanced Combustion Engineering Research Center

1995-12-31T23:59:59.000Z

14

Fuel Interchangeability Considerations for Gas Turbine Combustion  

DOE Green Energy (OSTI)

In recent years domestic natural gas has experienced a considerable growth in demand particularly in the power generation industry. However, the desire for energy security, lower fuel costs and a reduction in carbon emissions has produced an increase in demand for alternative fuel sources. Current strategies for reducing the environmental impact of natural gas combustion in gas turbine engines used for power generation experience such hurdles as flashback, lean blow-off and combustion dynamics. These issues will continue as turbines are presented with coal syngas, gasified coal, biomass, LNG and high hydrogen content fuels. As it may be impractical to physically test a given turbine on all of the possible fuel blends it may experience over its life cycle, the need to predict fuel interchangeability becomes imperative. This study considers a number of historical parameters typically used to determine fuel interchangeability. Also addressed is the need for improved reaction mechanisms capable of accurately modeling the combustion of natural gas alternatives.

Ferguson, D.H.

2007-10-01T23:59:59.000Z

15

Combustion and Inert Gas Fusion Analysis  

Science Conference Proceedings (OSTI)

...high-temperature combustion and inert gas fusion processes is shown in Fig. 8 . Small samples of known weight are heated to very high temperatures. The elements of interest are driven off as either elemental gas or gaseous oxidation products. These gaseous products are then

16

Premixed Combustion of Hydrogen Augmented Natural Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Premixed Combustion of Hydrogen Premixed Combustion of Hydrogen Augmented Natural Gas * Lean premixed combustion * Effective for emission reduction with natural gas * High hydrogen flame speed requires care in premixer design for SGH fuels * UC Irvine study quantifies effectiveness of hydrogen augmentation strategy * Lean stability limit improves linearly with hydrogen augmentation * Emissions reduction can be achieved * Two OEM's and the California Energy Commission have used the results to help guide them on adapting to hydrogen fuel UC Irvine Scott Samuelsen / Vince McDonell Project 98-01-SR062 1200 1300 1400 1500 1600 1700 1800 1900 0 10 20 30 40 50 60 Hydrogen Volume in Main Fuel (%) Adiabatic Flame Temperature (K) P0(3/4) High Stability High Stability Low emission Low emission operational zone operational zone

17

Operational Flexibility Guidelines for Gas Turbine Low NOx Combustion Systems  

Science Conference Proceedings (OSTI)

Gas turbine low-NOx combustion systems can differ in hardware from manufacturer to manufacturer, but the principle is the same. Low-NOx combustors reduce peak flame temperatures by mixing fuel and air before combustion and by keeping the fuel-to-air ratio as low (lean) as possible, while still maintaining combustion stability over the broadest possible operating range. Low-NOx combustion systems are inherently more complex than diffusion combustion systems, a fact that impacts operational flexibility, re...

2011-12-14T23:59:59.000Z

18

GAS TURBINE REHEAT USING IN-SITU COMBUSTION  

NLE Websites -- All DOE Office Websites (Extended Search)

GAS TURBINE REHEAT USING IN-SITU COMBUSTION Topical Report: Task 2 - Combustion and Emissions Cooperative Agreement No. DE-FC26-00NT40913 April 30, 2004 by D.M. Bachovchin T.E....

19

Assessment of Fuel Gas Cleanup Systems for Waste Gas Fueled Power Generation  

Science Conference Proceedings (OSTI)

There are many industrial operations that have waste gas streams that are combustible. Chief among these is biogas produced by anaerobic digestion of organic wastes to produce a methane-rich biogas in landfills and anaerobic digesters. These gas streams are increasingly being used to fuel local power generators. The biogas streams, however, contain traces of a wide variety of contaminants. Removal of these contaminants may be required to either meet the manufacturer's requirements for fuel gas quality to...

2006-12-21T23:59:59.000Z

20

Element associations in ash from waste combustion in fluidized bed  

SciTech Connect

The incineration of MSW in fluidized beds is a commonly applied waste management practice. The composition of the ashes produced in a fluidized bed boiler has important environmental implications as potentially toxic trace elements may be associated with ash particles and it is therefore essential to determine the mechanisms controlling the association of trace elements to ash particles, including the role of major element composition. The research presented here uses micro-analytical techniques to study the distribution of major and trace elements and determine the importance of affinity-based binding mechanisms in separate cyclone ash particles from MSW combustion. Particle size and the occurrence of Ca and Fe were found to be important factors for the binding of trace elements to ash particles, but the binding largely depends on random associations based on the presence of a particle when trace elements condensate in the flue gas.

Karlfeldt Fedje, K., E-mail: karinka@chalmers.s [Department of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers University of Technology, Kemivaegen 10, 412 96 Goeteborg (Sweden); Rauch, S. [Department of Civil and Environmental Engineering, Division of Water Environment Technology, Chalmers University of Technology, Sven Hultins Gata 8, 412 96 Goeteborg (Sweden); Cho, P.; Steenari, B.-M. [Department of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers University of Technology, Kemivaegen 10, 412 96 Goeteborg (Sweden)

2010-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Development of the Flow Sheet for Incinerating Contaminated Combustible Waste  

SciTech Connect

One of the major problems inherent in any work associated with radioactivity is the disposal of material comtaminated with activity by such work. Biological investigations have shown that this material, unless contaminated to an insignificant degree, cannot be indiscriminately discharged to the plant environment without some hazard to humans, either directly or indirectly. These materials may be in the liquid, solid, or gas form. No radioactive material of gaseous nature has been encountered at Mound Laboratory. In regard to liquid wastes, a process has been in service here for several years which satisfactorily decontaminated these wastes at this laboratory and concentrates the activity originally contained therein to a very small percentage of the original volume. Solid wastes, however, accumulate daily in large amount throughout this site, and these, along with the liquid waste concentrates (in solid form), are package and shipped several hundred miles to a national burial ground. Because the amounts of solid waste sent to burial represent large volumes (thousands of cubic feet annually), research was initiated to determine methods for concentrating this material to reduce the quantity requiring burial. The largest percentage of this material by far is combustible, and for this reason an incineration process was fully investigated in this connection. This process involves the incineration of the waste, the decontamination of the flue gas by a wet process, and the transfer of the contaminated incinerator ash, fly-ash, and soot particles in water, to the liquid waste process for further concentration. This investigation and its outcome is covered by this report; the small percentage of noncombustible solid waste presents a separate problem and is not discussed here. This report serves as a recommendation that a full-scale incineration process be installed at Mound Laboratory and provides a complete flow sheet for this process and recommended designs for the critical parts of the processing equipment. It contains a justification for the process, a history of the investigation including early work and pilot plant results, and explanation of the values and information given in the flow sheet, and the reasons for the recommended design features.

McEwen, M.; Schauer, P. J.; Aponyi, T.

1951-05-15T23:59:59.000Z

22

Determining site-specific drum loading criteria for storing combustible {sup 238}Pu waste  

DOE Green Energy (OSTI)

Waste containing hydrogenous-combustible material contaminated with {sup 238}Pu can generate hydrogen gas at appreciable rates through alpha radiolysis. To ensure safe transportation of WIPP drums, the limit for {sup 238}Pu-combustible waste published in the WIPP TRUPACT-11 CONTENT (TRUCON) CODES is 21 milliwafts per 55 gallon drum. This corresponds to about 45 milligrams of {sup 238}PuO{sub 2} used for satellite heat source-electrical generators. The Los Alamos waste storage site adopted a {sup 238}Pu waste storage criteria based on these TRCUCON codes. However, reviews of the content in drums of combustible waste generated during heat source assembly at Los Alamos showed the amount of {sup 238}Pu is typically much greater than 45 milligrams. It is not feasible to appreciably reduce Los Alamos {sup 238}Pu waste drum loadings without significantly increasing waste volumes or introducing unsafe practices. To address this concern, a series of studies were implemented to evaluate the applicability of the TRUCON limits for storage of this specific waste. Addressed in these evaluations were determination of the hydrogen generation rate, hydrogen diffusion rates through confinement layers and vent filters, and packaging requirements specific to Los Alamos generated {sup 238}Pu contaminated combustible waste. These studies also showed that the multiple-layer packaging practices in use at Los Alamos could be relaxed without significantly increasing the risk of contamination. Based on a model developed to predict H{sub 2} concentrations in packages and drum headspace, the site specific effective hydrogen generation rate, and hydrogen-diffusion values, and revising the waste packaging practices, we were able to raise the safe loading limit for {sup 238}Pu waste drums for on site storage to the gram levels typical of currently generated {sup 238}Pu waste.

Marshall, R.S.; Callis, E.L.; Cappis, J.H.; Espinoza, J.M.; Foltyn, E.M.; Reich, B.T. [Los Alamos National Lab., NM (United States); Smith, M.C. [Benchmark Environmental Corp., Albuquerque, NM (United States)

1994-02-01T23:59:59.000Z

23

Gas turbine combustion modeling for a Parametric Emissions Monitoring System.  

E-Print Network (OSTI)

??Oxides of nitrogen (NOx), carbon monoxide (CO) and other combustion by-products of gas turbines have long been identified as harmful atmospheric pollutants to the environment… (more)

Honegger, Ueli

2007-01-01T23:59:59.000Z

24

Process of producing combustible gas and for carbonizing coal  

SciTech Connect

This patent describes a process of producing combustible gas by supporting a column of fuel in a shaft furnace, intermittently blasting a combustion-supporting gas transversely through a mid portion of said column to produce a mid zone of sufficiently high temperature to decompose steam. The steam then circulated upwardly through said column between said blasting operations.

Doherty, H.L.

1922-08-15T23:59:59.000Z

25

Understanding and Control of Combustion Dynamics in Gas Turbine Combustors  

NLE Websites -- All DOE Office Websites (Extended Search)

Control of Combustion Understanding and Control of Combustion Control of Combustion Understanding and Control of Combustion Dynamics in Gas Turbine Combustors Dynamics in Gas Turbine Combustors Georgia Institute of Technology Georgia Institute of Technology Ben T. Zinn, Tim Lieuwen, Yedidia Neumeier, and Ben Bellows SCIES Project 02-01-SR095 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (05/01/2002, 36 Month Duration) $452,695 Total Contract Value CLEMSONPRES.PPT, 10/28/2003, B.T. ZINN, T. LIEUWEN, Y. NEUMEIER Gas Turbine Need Gas Turbine Need * Need: Gas turbine reliability and availability is important factor affecting power plant economics - Problem: Combustion driven oscillations severely reduce part life, requiring substantially more frequent outages

26

Municipal solid waste combustion: Fuel testing and characterization  

DOE Green Energy (OSTI)

The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

Bushnell, D.J.; Canova, J.H.; Dadkhah-Nikoo, A.

1990-10-01T23:59:59.000Z

27

Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II Title Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II Publication Type Report LBNL Report Number LBNL-6193E Year of Publication 2013 Authors Rapp, Vi H., Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray Date Published 04/2013 Abstract VENT-II is a computer program designed to provide detailed analysis of natural draft and induced draft combustion appliance vent-systems (i.e., furnace or water heater). This program is capable of predicting house depressurization thresholds that lead to backdrafting and spillage of combustion appliances; however, validation reports of the program being applied for this

28

Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same  

DOE Patents (OSTI)

A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste, and method for producing the same, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces.

Burnet, George (Ames, IA); Gokhale, Ashok J. (College Station, TX)

1990-07-10T23:59:59.000Z

29

Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same  

DOE Patents (OSTI)

A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste and method for producing the same are disclosed, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces. 3 figs.

Burnet, G.; Gokhale, A.J.

1990-07-10T23:59:59.000Z

30

GAS TURBINE REHEAT USING IN SITU COMBUSTION  

Science Conference Proceedings (OSTI)

In situ reheat is an alternative to traditional gas turbine reheat design in which fuel is fed through airfoils rather than in a bulky discrete combustor separating HP and LP turbines. The goals are to achieve increased power output and/or efficiency without higher emissions. In this program the scientific basis for achieving burnout with low emissions has been explored. In Task 1, Blade Path Aerodynamics, design options were evaluated using CFD in terms of burnout, increase of power output, and possible hot streaking. It was concluded that Vane 1 injection in a conventional 4-stage turbine was preferred. Vane 2 injection after vane 1 injection was possible, but of marginal benefit. In Task 2, Combustion and Emissions, detailed chemical kinetics modeling, validated by Task 3, Sub-Scale Testing, experiments, resulted in the same conclusions, with the added conclusion that some increase in emissions was expected. In Task 4, Conceptual Design and Development Plan, Siemens Westinghouse power cycle analysis software was used to evaluate alternative in situ reheat design options. Only single stage reheat, via vane 1, was found to have merit, consistent with prior Tasks. Unifying the results of all the tasks, a conceptual design for single stage reheat utilizing 24 holes, 1.8 mm diameter, at the trailing edge of vane 1 is presented. A development plan is presented.

D.M. Bachovchin; T.E. Lippert; R.A. Newby P.G.A. Cizmas

2004-05-17T23:59:59.000Z

31

Assessment of Gas Turbine Combustion Dynamics Monitoring Technologies: Interim Report  

Science Conference Proceedings (OSTI)

This report examines commercially available combustion dynamics monitoring systems (CDMS) and monitoring centers for use on gas turbine engines, specifically 7FA, 501F/5000F/8000H engines. The report provides a current review of combustion monitoring issues and methods, details of operation and available features for various CDMS, including, interviews with equipment suppliers and monitoring center providers, and end-user interviews.BackgroundGas turbines are ...

2013-12-18T23:59:59.000Z

32

Large bore natural gas engine performance improvements and combustion stabilization through reformed natural gas precombustion chamber fueling.  

E-Print Network (OSTI)

??Lean combustion is a standard approach used to reduce NOx emissions in large bore natural gas engines. However, at lean operating points, combustion instabilities and… (more)

Ruter, Matthew D.

2010-01-01T23:59:59.000Z

33

Flashback Detection Sensor for Hydrogen Augmented Natural Gas Combustion  

DOE Green Energy (OSTI)

The use of hydrogen augmented fuel is being investigated by various researchers as a method to extend the lean operating limit, and potentially reduce thermal NOx formation in natural gas fired lean premixed (LPM) combustion systems. The resulting increase in flame speed during hydrogen augmentation, however, increases the propensity for flashback in LPM systems. Real-time in-situ monitoring of flashback is important for the development of control strategies for use of hydrogen augmented fuel in state-of-the-art combustion systems, and for the development of advanced hydrogen combustion systems. The National Energy Technology Laboratory (NETL) and Woodward Industrial Controls are developing a combustion control and diagnostics sensor (CCADS), which has already been demonstrated as a useful sensor for in-situ monitoring of natural gas combustion, including detection of important combustion events such as flashback and lean blowoff. Since CCADS is a flame ionization sensor technique, the low ion concentration produced in pure hydrogen combustion raises concerns of whether CCADS can be used to monitor flashback in hydrogen augmented combustion. This paper discusses CCADS tests conducted at 0.2-0.6 MPa (2-6 atm), demonstrating flashback detection with fuel compositions up to 80% hydrogen (by volume) mixed with natural gas. NETL’s Simulation Validation (SimVal) combustor offers full optical access to pressurized combustion during these tests. The CCADS data and high-speed video show the reaction zone moves upstream into the nozzle as the hydrogen fuel concentration increases, as is expected with the increased flame speed of the mixture. The CCADS data and video also demonstrate the opportunity for using CCADS to provide the necessary in-situ monitor to control flashback and lean blowoff in hydrogen augmented combustion applications.

Thornton, J.D.; Chorpening, B.T.; Sidwell, T.; Strakey, P.A.; Huckaby, E.D.; Benson, K.J. (Woodward)

2007-05-01T23:59:59.000Z

34

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Green Energy (OSTI)

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

35

FLAMELESS COMBUSTION APPLICATION FOR GAS TURBINE ENGINES IN THE AEROSPACE INDUSTRY.  

E-Print Network (OSTI)

??The objective of this thesis is to review the potential application of flameless combustion technology in aerospace gas turbine engines. Flameless combustion is a regime… (more)

OVERMAN, NICHOLAS

2006-01-01T23:59:59.000Z

36

Solid fuel combustion system for gas turbine engine  

DOE Patents (OSTI)

A solid fuel, pressurized fluidized bed combustion system for a gas turbine engine includes a carbonizer outside of the engine for gasifying coal to a low Btu fuel gas in a first fraction of compressor discharge, a pressurized fluidized bed outside of the engine for combusting the char residue from the carbonizer in a second fraction of compressor discharge to produce low temperature vitiated air, and a fuel-rich, fuel-lean staged topping combustor inside the engine in a compressed air plenum thereof. Diversion of less than 100% of compressor discharge outside the engine minimizes the expense of fabricating and maintaining conduits for transferring high pressure and high temperature gas and incorporation of the topping combustor in the compressed air plenum of the engine minimizes the expense of modifying otherwise conventional gas turbine engines for solid fuel, pressurized fluidized bed combustion.

Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN)

1993-01-01T23:59:59.000Z

37

Exhaust gas recirculation system for an internal combustion engine  

SciTech Connect

An exhaust gas recirculation system for an internal combustion engine comprises an exhaust driven turbocharger having a low pressure turbine outlet in fluid communication with an exhaust gas conduit. The turbocharger also includes a low pressure compressor intake and a high pressure compressor outlet in communication with an intake air conduit. An exhaust gas recirculation conduit fluidly communicates with the exhaust gas conduit to divert a portion of exhaust gas to a low pressure exhaust gas recirculation branch extending between the exhaust gas recirculation conduit and an engine intake system for delivery of exhaust gas thereto. A high pressure exhaust gas recirculation branch extends between the exhaust gas recirculation conduit and the compressor intake and delivers exhaust gas to the compressor for mixing with a compressed intake charge for delivery to the intake system.

Wu, Ko-Jen

2013-05-21T23:59:59.000Z

38

Gasification Evaluation of Gas Turbine Combustion  

DOE Green Energy (OSTI)

This report provides a preliminary assessment of the potential for use in gas turbines and reciprocating gas engines of gases derived from biomass by pyrolysis or partial oxidation with air. Consideration was given to the use of mixtures of these gases with natural gas as a means of improving heating value and ensuring a steady gas supply. Gas from biomass, and mixtures with natural gas, were compared with natural gas reformates from low temperature partial oxidation or steam reforming. The properties of such reformates were based on computations of gas properties using the ChemCAD computational tools and energy inputs derived from known engine parameters. In general, the biomass derived fuels compare well with reformates, so far as can be judged without engine testing. Mild reforming has potential to produce a more uniform quality of fuel gas from very variable qualities of natural gas, and could possibly be applied to gas from biomass to eliminate organic gases and condensibles other than methane.

Battelle

2003-12-30T23:59:59.000Z

39

Combustible gas sensor interference test report  

DOE Green Energy (OSTI)

Result of Laboratory Interference testing of the Sierra Monitor Corporation Gas Sensor, number model 4101-2, are documented.

Webb, B.J., Westinghouse Hanford

1996-07-30T23:59:59.000Z

40

Combustion gas turbine/steam generator plant  

SciTech Connect

A fired steam generator is described that is interconnected with a gas turbine/steam generator plant having at least one gas turbine group followed by an exhaust-gas steam generator. The exhaust-gas steam generator has a preheater and an evaporator. The inlet of the preheater is connected to a feedwater distribution line which also feeds a preheater in the fired steam generator. The outlet of the preheater is connected to the evaporator of the fired steam generator. The evaporator outlet of the exhaust-gas steam generator is connected to the input of a superheater in the fired steam generator.

Aguet, E.

1975-11-18T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Temperature programmed combustion studies of the co-processing of coal and waste materials  

E-Print Network (OSTI)

Temperature programmed combustion studies of the co-processing of coal and waste materials F) to study the interaction between coal, polyethylene, and dried sewage sludge which are possible components in coal/ waste materials co-processing combustion systems. The TPC studies were carried out on the raw

Thomas, Mark

42

Combustion System Development for Medium-Sized Industrial Gas Turbines: Meeting Tight Emission Regulations while Using  

E-Print Network (OSTI)

Combustion System Development for Medium-Sized Industrial Gas Turbines: Meeting Tight Emission and the oil & gas industries. The combustion system used in Solar's products are discussed along- bility for the introduction of new combustion systems for gas turbine products to enhance fuel

Ponce, V. Miguel

43

Near-zero Emissions Oxy-combustion Flue Gas Purification  

NLE Websites -- All DOE Office Websites (Extended Search)

Near-zero Emissions Oxy-combustion Near-zero Emissions Oxy-combustion Flue Gas Purification Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions & Capture (EPEC) R&D Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D Program portfolio of post- and

44

Combustion Gas Turbine Power Enhancement by Refrigeration of Inlet Air  

E-Print Network (OSTI)

Combustion gas turbines have gained widespread acceptance for mechanical drive and power generation applications. One key drawback of a combustion turbine is that its specific output and thermal efficiency vary quite significantly with variations in the ambient temperature. On hot days, a machine may experience considerable difficulty in meeting its power demand. One concept that has not received much attention is the cooling down of compressor inlet air. This paper will examine the theoretical and practical implications of concept such as evaporative cooling, intercooling, expansion cooling and compression and absorption refrigeration.

Meher-Homji, C. B.; Mani, G.

1983-01-01T23:59:59.000Z

45

Combustion Gas Sensing of CO and NO  

Science Conference Proceedings (OSTI)

Modern laser absorption sensing schemes have successfully monitored important trace gases in atmospheric research and hold promise for gas monitoring in the power industry. Commercial sensors using near-infrared telecommunications lasers are emerging; however, these near-infrared devices are not sensitive enough to detect small concentrations of carbon monoxide (CO) and nitric oxide (NO) in the large background of flue gas moisture (H2O) and carbon dioxide. In working toward continuous spatially resolved...

2009-03-03T23:59:59.000Z

46

FUEL INTERCHANGEABILITY FOR LEAN PREMIXED COMBUSTION IN GAS TURBINE ENGINES  

DOE Green Energy (OSTI)

In response to environmental concerns of NOx emissions, gas turbine manufacturers have developed engines that operate under lean, pre-mixed fuel and air conditions. While this has proven to reduce NOx emissions by lowering peak flame temperatures, it is not without its limitations as engines utilizing this technology are more susceptible to combustion dynamics. Although dependent on a number of mechanisms, changes in fuel composition can alter the dynamic response of a given combustion system. This is of particular interest as increases in demand of domestic natural gas have fueled efforts to utilize alternatives such as coal derived syngas, imported liquefied natural gas and hydrogen or hydrogen augmented fuels. However, prior to changing the fuel supply end-users need to understand how their system will respond. A variety of historical parameters have been utilized to determine fuel interchangeability such as Wobbe and Weaver Indices, however these parameters were never optimized for today’s engines operating under lean pre-mixed combustion. This paper provides a discussion of currently available parameters to describe fuel interchangeability. Through the analysis of the dynamic response of a lab-scale Rijke tube combustor operating on various fuel blends, it is shown that commonly used indices are inadequate for describing combustion specific phenomena.

Don Ferguson; Geo. A. Richard; Doug Straub

2008-06-13T23:59:59.000Z

47

Atmospheric fluidized bed combustion of municipal solid waste: test program results  

DOE Green Energy (OSTI)

Air classified municipal solid waste (MSW) was fired in an atmospheric fluidized bed combustor at low excess air to simulate boiler conditions. The 7 ft/sup 2/ combustor at Combustion Power Company's energy laboratory in Menlo Park, CA, incorporates water tubes for heat extraction and recycles elutriated particles to the bed. System operation was stable while firing processed MSW for the duration of a 300-h test. Low excess air, low exhaust gas emissions, and constant bed temperature demonstrated feasibility of steam generation from fluidized bed combustion of MSW. During the 300-h test, combustion efficiency averaged 99%. Excess air was typically 44% while an average bed temperature of 1400/sup 0/F and an average superficial gas velocity of 4.6 fps were maintained. Typical exhaust emission levels were 30 ppM SO/sub 2/, 160 ppM NO/sub x/, 200 ppM CO, and 25 ppM hydrocarbons. No agglomeration of bed material or detrimental change in fluidization properties was experienced. A conceptual design study of a full scale plant to be located at Stanford University was based on process conditions from the 300-h test. The plant would produce 250,000 lb/hr steam at the maximum firing rate of 1000 tons per day (TPD) processed MSW. The average 800 TPD firing rate would utilize approximately 1200 TPD raw MSW from surrounding communities. The Stanford Solid Waste energy Program was aimed at development of a MSW-fired fluidized bed boiler and cogeneration plant to supply most of the energy needs of Stanford University.

Preuit, L C; Wilson, K B

1980-05-01T23:59:59.000Z

48

Co-combustion of textile residues with cardboard and waste wood in a packed bed  

SciTech Connect

The combustible fraction of the municipal waste is mostly bio-derived. Energy recovery of the wastes that cannot be economically recycled is a key part of sustainable energy policy and waste management. Textile residues have high energy content. When burned alone in a packed bed system, however, their combustion efficiency is low due to the irregular propagation of the ignition front and the low burning rates. In order to achieve more efficient combustion of textile residues, a series of co-combustion tests were carried out for various mixture compositions and air flow rates in a packed bed combustor. The combustion performance of these materials was evaluated by using quantitative measures such as ignition rate, burning rate and equivalence ratio. Co-combustion of textile residues with cardboard for a textile fraction of up to 30% achieved satisfactorily high burning rate and low unburned carbon content in the bottom ash. The mixture was more resistant to convective cooling by air, which significantly expanded the range of air flow rate for combustion at high burning rates. In co-combustion with a material that has a very low ignition front speed such as waste wood, the propagation of the ignition front was governed by textile residues. Therefore, the co-combustion of textile residues can be better performed with a material having similar ignition front speeds, in which the two materials simultaneously burn at the ignition front. (author)

Ryu, Changkook; Phan, Anh N; Sharifi, Vida N; Swithenbank, Jim [Sheffield University Waste Incineration Centre (SUWIC), Department of Chemical and Process Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD (United Kingdom)

2007-11-15T23:59:59.000Z

49

Coal combustion waste management at landfills and surface impoundments 1994-2004.  

SciTech Connect

On May 22, 2000, as required by Congress in its 1980 Amendments to the Resource Conservation and Recovery Act (RCRA), the U.S. Environmental Protection Agency (EPA) issued a Regulatory Determination on Wastes from the Combustion of Fossil Fuels. On the basis of information contained in its 1999 Report to Congress: Wastes from the Combustion of Fossil Fuels, the EPA concluded that coal combustion wastes (CCWs), also known as coal combustion by-products (CCBs), did not warrant regulation under Subtitle C of RCRA, and it retained the existing hazardous waste exemption for these materials under RCRA Section 3001(b)(3)(C). However, the EPA also determined that national regulations under Subtitle D of RCRA were warranted for CCWs that are disposed of in landfills or surface impoundments. The EPA made this determination in part on the basis of its findings that 'present disposal practices are such that, in 1995, these wastes were being managed in 40 percent to 70 percent of landfills and surface impoundments without reasonable controls in place, particularly in the area of groundwater monitoring; and while there have been substantive improvements in state regulatory programs, we have also identified gaps in State oversight' (EPA 2000). The 1999 Report to Congress (RTC), however, may not have reflected the changes in CCW disposal practices that occurred since the cutoff date (1995) of its database and subsequent developments. The U.S. Department of Energy (DOE) and the EPA discussed this issue and decided to conduct a joint DOE/EPA study to collect new information on the recent CCW management practices by the power industry. It was agreed that such information would provide a perspective on the chronological adoption of control measures in CCW units based on State regulations. A team of experts from the EPA, industry, and DOE (with support from Argonne National Laboratory) was established to develop a mutually acceptable approach for collecting and analyzing data on CCW disposal practices and State regulatory requirements at landfills and surface impoundments that were permitted, built, or laterally expanded between January 1, 1994, and December 31, 2004. The scope of the study excluded waste units that manage CCWs in active or abandoned coal mines. The EPA identified the following three areas of interest: (1) Recent and current CCW industry surface disposal management practices, (2) State regulatory requirements for CCW management, and (3) Implementation of State requirements (i.e., the extent to which States grant or deny operator requests to waive or vary regulatory requirements and the rationales for doing so). DOE and the EPA obtained data on recent and current disposal practices from a questionnaire that the Utility Solid Waste Activities Group (USWAG) distributed to its members that own or operate coal-fired power plants. USWAG, formed in 1978, is responsible for addressing solid and hazardous waste issues on behalf of the utility industry. It is an informal consortium of approximately 80 utility operating companies, the Edison Electric Institute (EEI), the National Rural Electric Cooperative Association (NRECA), the American Public Power Association (APPA), and the American Gas Association (AGA). EEI is the principal national association of investor-owned electric power and light companies. NRECA is the national association of rural electric cooperatives. APPA is the national association of publicly owned electric utilities. AGA is the national association of natural gas utilities. Together, USWAG member companies and trade associations represent more than 85% of the total electric generating capacity of the United States and service more than 95% of the nation's consumers of electricity. To verify the survey findings, the EPA also asked State regulators from nine selected States that are leading consumers of coal for electricity generation for information on disposal units that may not have been covered in the USWAG survey. The selected States were Georgia, Illinois, Indiana, Michigan, Missouri, North Carolina, North Da

Elcock, D.; Ranek, N. L.; Environmental Science Division

2006-09-08T23:59:59.000Z

50

Use of ash from municipal solid waste combustion. Final report  

DOE Green Energy (OSTI)

This report details the results of efforts to integrate municipal solid waste combustion ash into a high strength portland cement concrete matrix comprised of multiple waste materials. The material developed by this research was to be used to construct a large underground storage vault to house the Friendly Mobile Barrier, a safety barrier system for use at highway crossings for the high speed rail system. The subcontractor, Environmental Solutions, Inc., of Richmond, Virginia, worked with researchers at Pennsylvania State University and the State University of New York--Stony Brook to develop and test the material. The result of this work is a portland cement concrete matrix which utilizes 80.01% recycled materials, and a field-applicable method for incorporating MSW ash as a component at volumes up to 9.78%. Twenty-eight day strengths of over 4000 psi were achieved, with 315 day strengths of 6500 psi. All structural, chemical and environmental testing showed the material to be competitive with conventional concrete.

NONE

1997-07-01T23:59:59.000Z

51

An Energy Analysis of the Catalytic Combustion Burner  

E-Print Network (OSTI)

The gas boilers of conventional flame always produce varying degrees of combustion products NOx and CO, which pollute the environment and waste energy. As a new way of combustion, catalytic combustion breaks the flammable limits of conventional flame combustion, and realizes the combustion of ultra-natural gas/air mixture under the flammable limits. Its combustion efficiency is higher, which improves the ratio of energy utilization. Applying the catalytic combustion to gas boilers could solve the gas boilers' lower combustion efficiency, and achieve energy savings. On the basis of the catalytic combustion burner, the catalytic combustion burner was designed according to the catalytic combustion and water heaters. In this paper, we analyzed the heat loss and thermal efficiency of the catalytic combustion burner, and compared it to that of flame combustion boilers. The results showed that catalytic combustion burner ?'s heat loss is not so high as originally considered, and its pollutant emissions are lower.

Dong, Q.; Zhang, S.; Duan, Z.; Zhou, Q.

2006-01-01T23:59:59.000Z

52

Water distillation using waste engine heat from an internal combustion engine  

E-Print Network (OSTI)

To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

Mears, Kevin S

2006-01-01T23:59:59.000Z

53

Causes of Combustion Instabilities with Passive and Active Methods of Control for practical application to Gas Turbine Engines.  

E-Print Network (OSTI)

??Combustion at high pressure in applications such as rocket engines and gas turbine engines commonly experience destructive combustion instabilities. These instabilities results from interactions between… (more)

Cornwell, Michael

2011-01-01T23:59:59.000Z

54

Heavy duty gas turbine combustion tests with simulated low BTU coal gas  

DOE Green Energy (OSTI)

This program has the objectives to: A. Parametrically determine the effects of moisture, nitrogen and carbon dioxide as diluents so that the combustion characteristics of many varieties of gasification product gases can be reasonably predicted without physically testing each specific gas composition. B. Determine emissions characteristics including NO, NO{sub x}, CO, levels etc. associated with each of the diluents, and C. Operate with at least two syngas compositions; DOE chosen air-blown and integrated oxygen-blown, to confirm that the combustion characteristics are in line with predictions. As a result of this program: 1. GE Engineering is now confident that the syngas fuels produced by all currently--viable coal gasifiers can be accommodated by the GE advanced (``F`` Technology) combustion system, and 2. For proposed syngas fuels with varying amounts of steam, nitrogen or CO{sub 2} diluent, the combustion and emissions characteristics can be reasonably estimated without undertaking expensive new screening tests for each different fuel.

Ekstrom, T.E.; Battista, R.A.; Belisle, F.H.; Maxwell, G.P.

1993-11-01T23:59:59.000Z

55

Phytostabilization of a landfill containing coal combustion waste.  

SciTech Connect

The establishment of a vegetative cover to enhance evapotranspiration and control runoff and drainage was examined as a method for stabilizing a landfill containing coal combustion waste. Suitable plant species and pretreatment techniques in the form of amendments, tilling, and chemical stabilization were evaluated. A randomized plot design consisting of three subsurface treatments (blocks) and five surface amendments (treatments) was implemented. The three blocks included (1) ripping and compost amended, (2) ripping only, and (3) control. Surface treatments included (1) topsoil, (2) fly ash, (3) compost, (4) apatite, and (5) control. Inoculated loblolly (Pinus taeda) and Virginia (Pinus virginiana) pine trees were planted on each plot. After three growing seasons, certain treatments were shown to be favorable for the establishment of vegetation on the basin. Seedlings located on block A developed a rooting system that penetrated into the basin media without significant adverse effects to the plant. However, seedlings on blocks B and C displayed poor rooting conditions and high mortality, regardless of surface treatment. Pore-water samples from lysimeters in block C were characterized by high acidity, Fe, Mn, Al, sulfate, and traceelement concentrations. Water-quality characteristics of the topsoil plots in block A, however, conformed to regulatory protocols. A decrease in soil-moisture content was observed in the rooting zone of plots that were successfully revegetated, which suggests that the trees, in combination with the surface treatments, influenced the water balance by facilitating water loss through transpiration and thereby reducing the likelihood of unwanted surface runoff and/or drainage effluent.

Barton, Christopher; Marx, Donald; Adriano, Domy; Koo, Bon Jun; Newman, Lee; Czapka, Stephen; Blake, John

2005-12-01T23:59:59.000Z

56

Natural gas-fired combustion turbines are generally used to meet ...  

U.S. Energy Information Administration (EIA)

In 2012, there were 121 gigawatts of operating natural gas combustion turbines that contributed about 3% of overall electricity generation. The average capacity ...

57

NETL: IEP ? Post-Combustion CO2 Emissions Control - Flue Gas...  

NLE Websites -- All DOE Office Websites (Extended Search)

Flue Gas Purification Utilizing SOx NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion Project No.: DE-NT0005309 Air Products and Chemicals Inc. will...

58

Advanced combustion technologies for gas turbine power plants  

DOE Green Energy (OSTI)

Objectives are to develop actuators for enhancing the mixing between gas streams, increase combustion stability, and develop hgih-temperature materials for actuators and sensors in combustors. Turbulent kinetic energy maps of an excited jet with co-flow in a cavity with a partially closed exhaust end are given with and without a longitudinal or a transverse acoustic field. Dielectric constants and piezoelectric coefficients were determined for Sr{sub 2}(Nb{sub x}Ta{sub 1-x}){sub 2}O{sub 7} ceramics.

Vandsburger, U. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States). Dept. of Mechanical Engineering; Roe, L.A. [Arkansas Univ., Fayetteville, AR (United States). Dept. of Mechanical Engineering; Desu, S.B. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States). Dept. of Materials Science and Engineering

1995-12-31T23:59:59.000Z

59

Computational study of homogeneous and stratified combustion in a compressed natural gas direct injection engine  

Science Conference Proceedings (OSTI)

In recent years, the type of combustion occurred within engine cylinder plays an important role determining the performance and emissions. In the present study, the computational investigation was performed in order to compare characteristics of homogeneous ... Keywords: compressed natural gas, direct injection, exhaust emissions, homogeneous combustion, stratified combustion

S. Abdullah; W. H. Kurniawan; M. A. Al-Rawi; Y. Ali; T. I. Mohamad

2009-02-01T23:59:59.000Z

60

Combustion chamber for gas turbines and the like having a fluidized burner bed  

SciTech Connect

A combustion chamber with a fluidized burner bed preferably for gas turbines is described. It contains means for controlling the supply of fuel, combustion air and a cooling medium for the fluidized bed to maintain a predetermined proportional relationship between combustion air and cooling air under varying load conditions.

Harboe, H.

1975-12-09T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Method for increasing the calorific value of gas produced by the in situ combustion of coal  

DOE Patents (OSTI)

The present invention relates to the production of relatively high Btu gas by the in situ combustion of subterranean coal. The coal bed is penetrated with a horizontally-extending borehole and combustion is initiated in the coal bed contiguous to the borehole. The absolute pressure within the resulting combustion zone is then regulated at a desired value near the pore pressure within the coal bed so that selected quantities of water naturally present in the coal will flow into the combustion zone to effect a hydrogen and carbon monoxide-producing steam-carbon reaction with the hot carbon in the combustion zone for increasing the calorific value of the product gas.

Shuck, Lowell Z. (Morgantown, WV)

1978-01-01T23:59:59.000Z

62

MCO combustible gas management leak test acceptance criteria  

DOE Green Energy (OSTI)

Existing leak test acceptance criteria for mechanically sealed and weld sealed multi-canister overpacks (MCO) were evaluated to ensure that MCOs can be handled and stored in stagnant air without compromising the Spent Nuclear Fuel Project's overall strategy to prevent accumulation of combustible gas mixtures within MCO's or within their surroundings. The document concludes that the integrated leak test acceptance criteria for mechanically sealed and weld sealed MCOs (1 x 10{sup -5} std cc/sec and 1 x 10{sup -7} std cc/sec, respectively) are adequate to meet all current and foreseeable needs of the project, including capability to demonstrate compliance with the NFPA 60 Paragraph 3-3 requirement to maintain hydrogen concentrations [within the air atmosphere CSB tubes] t or below 1 vol% (i.e., at or below 25% of the LFL).

SHERRELL, D.L.

1999-05-11T23:59:59.000Z

63

Axially staged combustion system for a gas turbine engine  

DOE Patents (OSTI)

An axially staged combustion system is provided for a gas turbine engine comprising a main body structure having a plurality of first and second injectors. First structure provides fuel to at least one of the first injectors. The fuel provided to the one first injector is adapted to mix with air and ignite to produce a flame such that the flame associated with the one first injector defines a flame front having an average length when measured from a reference surface of the main body structure. Each of the second injectors comprising a section extending from the reference surface of the main body structure through the flame front and having a length greater than the average length of the flame front. Second structure provides fuel to at least one of the second injectors. The fuel passes through the one second injector and exits the one second injector at a location axially spaced from the flame front.

Bland, Robert J. (Oviedo, FL)

2009-12-15T23:59:59.000Z

64

Heavy duty gas turbine combustion tests with simulated low BTU coal gas  

SciTech Connect

There is an increasing industry interest in integrated gas turbine combined cycle plants in which coal gasifiers provide the fuel for the gas turbines. Some gasifier plant designs, including the air-blown processes, some integrated oxygen blown processes and some oxygen-blown processes followed by heavy moisturization, produce fuel gases which have lower heating values ranging from 130 to below 100 BTU/scf for which there is little gas turbine combustion experience. This program has the objectives to: Parametrically determine the effects of moisture, nitrogen and carbon dioxide as diluents so that the combustion characteristics of many varieties of gasification product gases can be reasonably predicted without physically testing each specific gas composition; determine emissions characteristics including NO[sub x], CO, levels etc. associated with each of the diluents; operate with two syngas compositions; DOE chosen air-blown and integrated oxygen-blown, to confirm that the combustion characteristics are in line with predictions; determine if logical'' refinements to the fuel nozzle will yield improved performance for LBTU fuels; determine the conversion rate of ammonia to NO[sub x]; determine the effects of methane inclusion in the fuel.

Ekstrom, T.E.; Battista, R.A.; Maxwell, G.P.

1992-01-01T23:59:59.000Z

65

Heavy duty gas turbine combustion tests with simulated low BTU coal gas  

DOE Green Energy (OSTI)

There is an increasing industry interest in integrated gas turbine combined cycle plants in which coal gasifiers provide the fuel for the gas turbines. Some gasifier plant designs, including the air-blown processes, some integrated oxygen blown processes and some oxygen-blown processes followed by heavy moisturization, produce fuel gases which have lower heating values ranging from 130 to below 100 BTU/scf for which there is little gas turbine combustion experience. This program has the objectives to: Parametrically determine the effects of moisture, nitrogen and carbon dioxide as diluents so that the combustion characteristics of many varieties of gasification product gases can be reasonably predicted without physically testing each specific gas composition; determine emissions characteristics including NO{sub x}, CO, levels etc. associated with each of the diluents; operate with two syngas compositions; DOE chosen air-blown and integrated oxygen-blown, to confirm that the combustion characteristics are in line with predictions; determine if ``logical`` refinements to the fuel nozzle will yield improved performance for LBTU fuels; determine the conversion rate of ammonia to NO{sub x}; determine the effects of methane inclusion in the fuel.

Ekstrom, T.E.; Battista, R.A.; Maxwell, G.P.

1992-12-31T23:59:59.000Z

66

Heavy duty gas turbine combustion tests with simulated low BTU coal gas  

DOE Green Energy (OSTI)

There is an increasing industry interest in integrated gas turbine combined cycle plants in which coal gasifiers provide the fuel for the gas turbines. Some gasifier plant designs, including the air-blown processes, some integrated oxygen blown processes and some oxygen-blown processes followed by heavy moisturization, produce fuel gases which have lower heating values ranging from 130 to below 100 BTU/scf for which there is little gas turbine combustion experience. This program has the objectives to: Parametrically determine the effects of moisture, nitrogen and carbon dioxide as diluents so that the combustion characteristics of many varieties of gasification product gases can be reasonably predicted without physically testing each specific gas composition; determine emissions characteristics including NO[sub x], CO, levels etc. associated with each of the diluents; operate with two syngas compositions; DOE chosen air-blown and integrated oxygen-blown, to confirm that the combustion characteristics are in line with predictions; determine if logical'' refinements to the fuel nozzle will yield improved performance for LBTU fuels; determine the conversion rate of ammonia to NO[sub x]; determine the effects of methane inclusion in the fuel.

Ekstrom, T.E.; Battista, R.A.; Maxwell, G.P.

1992-01-01T23:59:59.000Z

67

ALCF Research Aimed at Safer, Cleaner Combustion for Gas Turbines | Argonne  

NLE Websites -- All DOE Office Websites (Extended Search)

Research Aimed at Safer, Cleaner Combustion for Gas Turbines Research Aimed at Safer, Cleaner Combustion for Gas Turbines December 3, 2013 Printer-friendly version Researchers from the Swiss Federal Institute of Technology (ETHZ) and the Argonne Leadership Computing Facility (ALCF) are using supercomputers to advance the development of safer and cleaner gas turbine engines by studying the operating conditions that can lead to a potentially dangerous phenomenon called autoignition. This phenomenon, which involves the spontaneous ignition of a combustible mixture without an external ignition source, can result in a premature combustion event, called flashback, that causes significant damage to the gas turbine. Understanding autoignition is critical to the design of turbines that operate with novel combustion strategies, such as lean

68

Greenhouse gas emissions, waste and recycling policy Kaylee Acuff  

E-Print Network (OSTI)

Greenhouse gas emissions, waste and recycling policy Kaylee Acuff and Daniel T. Kaffine We thank@mines.edu.) 1 #12;Greenhouse gas emissions, waste and recycling policy Abstract This paper examines least-cost policies for waste reduction, incorporating upstream greenhouse gas externalities associated

69

Fuel Nozzle Flow Testing Guideline for Gas Turbine Low-NOx Combustion Systems  

Science Conference Proceedings (OSTI)

The evolution of dry low-NOx (DLN) gas turbine combustion systems capable of achieving single-digit emission levels requires precise control of the fuel/air ratio within each combustor. The primary means of maintaining the required fuel/air ratio control is through flow testing designed to ensure even distribution of fuel to both individual fuel nozzles and combustion chambers around the gas turbine. This report provides fuel nozzle flow testing guidelines for advanced gas turbine ...

2012-12-31T23:59:59.000Z

70

Optical backscatter probe for sensing particulate in a combustion gas stream  

SciTech Connect

A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

Parks, James E; Partridge, William P

2013-05-28T23:59:59.000Z

71

Advanced Materials for Mercury 50 Gas Turbine Combustion System  

SciTech Connect

Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-0CH11049, has conducted development activities to improve the durability of the Mercury 50 combustion system to 30,000 hours life and reduced life cycle costs. This project is part of Advanced Materials in the Advanced Industrial Gas Turbines program in DOE's Office of Distributed Energy. The targeted development engine was the Mercury{trademark} 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems program (DOE contract number DE-FC21-95MC31173). As a generator set, the Mercury 50 is used for distributed power and combined heat and power generation and is designed to achieve 38.5% electrical efficiency, reduced cost of electricity, and single digit emissions. The original program goal was 20,000 hours life, however, this goal was increased to be consistent with Solar's standard 30,000 hour time before overhaul for production engines. Through changes to the combustor design to incorporate effusion cooling in the Generation 3 Mercury 50 engine, which resulted in a drop in the combustor wall temperature, the current standard thermal barrier coated liner was predicted to have 18,000 hours life. With the addition of the advanced materials technology being evaluated under this program, the combustor life is predicted to be over 30,000 hours. The ultimate goal of the program was to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for a minimum of 4,000 hours. Solar was the Prime Contractor on the program team, which includes participation of other gas turbine manufacturers, various advanced material and coating suppliers, nationally recognized test laboratories, and multiple industrial end-user field demonstration sites. The program focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future gas turbine products. For liner and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics were evaluated before down-selection to the most promising candidate materials for field evaluation. Preliminary, component and sub-scale testing was conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing was used to validated engine performance prior to field evaluation at a Qualcomm Inc. cogeneration site located in San Diego, California. To ensure that the CFCC liners with the EBC proposed under this program would meet the target life, field evaluations of ceramic matrix composite liners in Centaur{reg_sign} 50 gas turbine engines, which had previously been conducted under the DOE sponsored Ceramic Stationary Gas Turbine program (DE-AC02-92CE40960), was continued under this program at commercial end-user sites under Program Subtask 1A - Extended CFCC Materials Durability Testing. The goal of these field demonstrations was to demonstrate significant component life, with milestones of 20,000 and 30,000 hours. Solar personnel monitor the condition of the liners at the field demonstration sites through periodic borescope inspections and emissions measurements. This program was highly successful at evaluating advanced materials and down-selecting promising solutions for use in gas turbine combustions systems. The addition of the advanced materials technology has enabled the predicted life of the Mercury 50 combustion system to reach 30,000 hours, which is Solar's typical time before overhaul for production engines. In particular, a 40 mil thick advanced Thermal Barrier Coating (TBC) system was selected over various other TBC systems, ODS liners and CFCC liners for the 4,000-hour field evaluation under the program. This advanced TBC is now production bill-of-material at various thicknesses up to 40 mils for all of Solar's advanced backside-cooled combustor liners (Centaur 50, Taurus 60,

Price, Jeffrey

2008-09-30T23:59:59.000Z

72

Advanced Materials for Mercury 50 Gas Turbine Combustion System  

DOE Green Energy (OSTI)

Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-0CH11049, has conducted development activities to improve the durability of the Mercury 50 combustion system to 30,000 hours life and reduced life cycle costs. This project is part of Advanced Materials in the Advanced Industrial Gas Turbines program in DOE's Office of Distributed Energy. The targeted development engine was the Mercury{trademark} 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems program (DOE contract number DE-FC21-95MC31173). As a generator set, the Mercury 50 is used for distributed power and combined heat and power generation and is designed to achieve 38.5% electrical efficiency, reduced cost of electricity, and single digit emissions. The original program goal was 20,000 hours life, however, this goal was increased to be consistent with Solar's standard 30,000 hour time before overhaul for production engines. Through changes to the combustor design to incorporate effusion cooling in the Generation 3 Mercury 50 engine, which resulted in a drop in the combustor wall temperature, the current standard thermal barrier coated liner was predicted to have 18,000 hours life. With the addition of the advanced materials technology being evaluated under this program, the combustor life is predicted to be over 30,000 hours. The ultimate goal of the program was to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for a minimum of 4,000 hours. Solar was the Prime Contractor on the program team, which includes participation of other gas turbine manufacturers, various advanced material and coating suppliers, nationally recognized test laboratories, and multiple industrial end-user field demonstration sites. The program focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future gas turbine products. For liner and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics were evaluated before down-selection to the most promising candidate materials for field evaluation. Preliminary, component and sub-scale testing was conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing was used to validated engine performance prior to field evaluation at a Qualcomm Inc. cogeneration site located in San Diego, California. To ensure that the CFCC liners with the EBC proposed under this program would meet the target life, field evaluations of ceramic matrix composite liners in Centaur{reg_sign} 50 gas turbine engines, which had previously been conducted under the DOE sponsored Ceramic Stationary Gas Turbine program (DE-AC02-92CE40960), was continued under this program at commercial end-user sites under Program Subtask 1A - Extended CFCC Materials Durability Testing. The goal of these field demonstrations was to demonstrate significant component life, with milestones of 20,000 and 30,000 hours. Solar personnel monitor the condition of the liners at the field demonstration sites through periodic borescope inspections and emissions measurements. This program was highly successful at evaluating advanced materials and down-selecting promising solutions for use in gas turbine combustions systems. The addition of the advanced materials technology has enabled the predicted life of the Mercury 50 combustion system to reach 30,000 hours, which is Solar's typical time before overhaul for production engines. In particular, a 40 mil thick advanced Thermal Barrier Coating (TBC) system was selected over various other TBC systems, ODS liners and CFCC liners for the 4,000-hour field evaluation under the program. This advanced TBC is now production bill-of-material at various thicknesses up to 40 mils for all of Solar's advanced backside-cooled combustor liners (Centaur 50, Taurus 60, Mars 100, Taurus 70,

Price, Jeffrey

2008-09-30T23:59:59.000Z

73

Program on Technology Innovation: Evaluation of Mid-Infrared Lasers for Combustion Gas Sensing Applications  

Science Conference Proceedings (OSTI)

Carbon monoxide (CO) and nitric oxide (NO) are important trace species in combustion exhaust, with absorption spectrum features that overlap with the absorption by water vaporan interference that increases with gas temperature. This situation is exacerbated by the need to monitor ppm levels of CO and NO in combustion product gases, which typically have in excess of 10% water. Therefore, the development of sensitive sensors for absorption detection of CO and NO in combustion gases requires evaluation of t...

2009-12-14T23:59:59.000Z

74

Development and Validation of Catalytic Combustion for Gas Turbines, Final Report  

Science Conference Proceedings (OSTI)

Combustion turbines (CTs) have become the preferred customer choice for new power generation capacity. However, some challenges have arisen. While exhaust emissions from natural gas-fueled and distillate-fueled CTs are lower than most other power generation options, continued environmental pressure has led to permitted emission limits below what is commonly achievable -- even with advanced dry low-NOx (DLN) combustors. An advanced combustion approach, catalytic combustion, offers the potential to achieve...

2000-12-05T23:59:59.000Z

75

Comanagement of Coal Combustion By-Products and Low-Volume Wastes: A Midwestern Site  

Science Conference Proceedings (OSTI)

An insufficient database on the environmental effects of comanagement of power plant by-products and wastes could hamper regulatory decisions regarding this practice. This report presents an environmental assessment of comanagement of high-volume coal combustion by-products with low-volume wastes at a steam electric power plant in the midwestern United States. It complements a similar assessment at a southeastern site.

1992-09-03T23:59:59.000Z

76

Modeling and Control of Lean Premixed Combustion Dynamics for Gas Turbines  

NLE Websites -- All DOE Office Websites (Extended Search)

Virginia Active Combustion Control Group Virginia Active Combustion Control Group Tech Virginia VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY Reacting Flows Laboratory Modeling and Control of Lean Premixed Combustion Dynamics for Gas Turbines Virginia Tech Principal Investigator: Uri Vandsburger SCIES Project 02- 01- SR099 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (05/01/02, 36 Month Duration) $ 756,700 Total Contract Value ($ 603,600 DOE) Virginia Active Combustion Control Group Tech Virginia VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY Reacting Flows Laboratory Gas Turbine Technology Needs DLN/LP Gas Turbines * Improved Combustion Stability * Improved Design Methodology With a focus on: - Thermoacoustics

77

Waste drum gas generation sampling program at Rocky Flats during FY 1988  

DOE Green Energy (OSTI)

Rocky Flats Plant Transuranic Waste Drums were sampled for gas composition. Combustibles, plastics, Raschig rings, solidified organic sludge, and solidified inorganic sludge transuranic waste forms were sampled. Plastic bag material and waste samples were also taken from some solidified sludge waste drums. A vacuum system was used to sample each layer of containment inside a waste drum, including individual waste bags. G values (gas generation) were calculated for the waste drums. Analytical results indicate that very low concentrations of potentially flammable or corrosive gas mixtures will be found in vented drums. G(H{sub 2}) was usually below 1.6, while G(Total) was below 4.0. Hydrogen permeability tests on different types of plastic waste bags used at Rocky Flats were also conducted. Polyvinylchloride was slightly more permeable to hydrogen than polyethylene for new or creased material. Permeability of aged material to hydrogen was slightly higher than for new material. Solidified organic and inorganic sludges were sampled for volatile organics. The analytical results from two drums of solidified organic sludges showed concentrations were above detection limits for four of the 36 volatile organics analyzed. The analytical results for four of the five solidified inorganic sludges show that concentrations were below detection limits for all volatile organics analyzed. 3 refs., 5 figs., 2 tabs.

Roggenthen, D.K.; McFeeters, T.L.; Nieweg, R.G.

1991-02-11T23:59:59.000Z

78

Elevated Trace Element Concentrations in Southern Toads, Bufo terrestris, Exposed to Coal Combustion Waste  

E-Print Network (OSTI)

Elevated Trace Element Concentrations in Southern Toads, Bufo terrestris, Exposed to Coal, and behavioral abnormalities in amphibians to coal combustion wastes (coal ash). Few studies, however, have determined trace element concentrations in amphibians exposed to coal ash. In the current study we compare

Hopkins, William A.

79

Advanced Combustion Systems for Next Generation Gas Turbines  

SciTech Connect

Next generation turbine power plants will require high efficiency gas turbines with higher pressure ratios and turbine inlet temperatures than currently available. These increases in gas turbine cycle conditions will tend to increase NOx emissions. As the desire for higher efficiency drives pressure ratios and turbine inlet temperatures ever higher, gas turbines equipped with both lean premixed combustors and selective catalytic reduction after treatment eventually will be unable to meet the new emission goals of sub-3 ppm NOx. New gas turbine combustors are needed with lower emissions than the current state-of-the-art lean premixed combustors. In this program an advanced combustion system for the next generation of gas turbines is being developed with the goal of reducing combustor NOx emissions by 50% below the state-of-the-art. Dry Low NOx (DLN) technology is the current leader in NOx emission technology, guaranteeing 9 ppm NOx emissions for heavy duty F class gas turbines. This development program is directed at exploring advanced concepts which hold promise for meeting the low emissions targets. The trapped vortex combustor is an advanced concept in combustor design. It has been studied widely for aircraft engine applications because it has demonstrated the ability to maintain a stable flame over a wide range of fuel flow rates. Additionally, it has shown significantly lower NOx emission than a typical aircraft engine combustor and with low CO at the same time. The rapid CO burnout and low NOx production of this combustor made it a strong candidate for investigation. Incremental improvements to the DLN technology have not brought the dramatic improvements that are targeted in this program. A revolutionary combustor design is being explored because it captures many of the critical features needed to significantly reduce emissions. Experimental measurements of the combustor performance at atmospheric conditions were completed in the first phase of the program. Emissions measurements were obtained over a variety of operating conditions. A kinetics model is formulated to describe the emissions performance. The model is a tool for determining the conditions for low emission performance. The flow field was also modeled using CFD. A first prototype was developed for low emission performance on natural gas. The design utilized the tools anchored to the atmospheric prototype performance. The 1/6 scale combustor was designed for low emission performance in GE's FA+e gas turbine. A second prototype was developed to evaluate changes in the design approach. The prototype was developed at a 1/10 scale for low emission performance in GE's FA+e gas turbine. The performance of the first two prototypes gave a strong indication of the best design approach. Review of the emission results led to the development of a 3rd prototype to further reduce the combustor emissions. The original plan to produce a scaled-up prototype was pushed out beyond the scope of the current program. The 3rd prototype was designed at 1/10 scale and targeted further reductions in the full-speed full-load emissions.

Joel Haynes; Jonathan Janssen; Craig Russell; Marcus Huffman

2006-01-01T23:59:59.000Z

80

Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine  

E-Print Network (OSTI)

As part of the MIT micro-gas turbine engine project, the development of a hydrocarbon-fueled catalytic micro-combustion system is presented. A conventionally-machined catalytic flow reactor was built to simulate the ...

Peck, Jhongwoo, 1976-

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Repowering oil-fired boilers with combustion turbines fired with gas from coal. Final report  

Science Conference Proceedings (OSTI)

The results of a study on repowering of oil fired reheat steam plants using combustion turbines and coal gas from the Texaco oxygen blown gasifier are presented. The steam plant utilizes combustion turbine exhaust gas as its combustion air supply. In some examples coal gas is fired in both the combustion turbines and the main boiler, while, in other cases, oil firing is retained in the boiler. Plant configurations, equipment changes, and performance are determined for three basic forms: (1) repowering based on coal gas supplied by pipeline (remote source); (2) repowering based on complete integration of the gasification system with the power plant; and (3) repowering based on partial integration of the gasification system wherein the boiler retains oil firing.

Garland, R.V.

1981-07-01T23:59:59.000Z

82

Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines  

E-Print Network (OSTI)

Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines the EL method well suited for gas turbine computations, but RANS with the EE approach may also be found and coupled with the LES solver of the gas phase. The equations used for each phase and the coupling terms

83

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS  

E-Print Network (OSTI)

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS ABSTRACf CRAIG A series, injection of up to 15% (HHV basis) natural gas reduced NOx by 50-70% while maintain ing, Illinois DAVID G. LINZ Gas Research Institute Chicago, Illinois ducing NOx emISSIons from municipal solid

Columbia University

84

Combustion research related to utilization of coal as a gas turbine fuel  

SciTech Connect

A nominal 293 kw (1 MBtu/hr) atmospheric pressure, refractory-lined combustor has been used to investigate the effects of a number of combustor and fuel dependent variables on combustion efficiency and flue gas characteristics for minimally cleaned, coal-derived gas (MCG) and coal water mixtures. The variables which have been evaluated include: percent excess air, air distribution, combustion air preheat temperature, swirl number, fuel feedrate, coal particle size, coal loading in slurry, and slurry viscosity. Characterization of the flue gas included major/minor gas species, alkali levels, and particulate loading, size, and composition. These atmospheric pressure combustion studies accompanied by data from planned pressurized studies on coal-water slurries and hot, minimally cleaned, coal-derived gas will aid in the determination of the potential of these fuels for use in gas turbines.

Davis-Waltermine, D.M.; Anderson, R.J.

1984-06-01T23:59:59.000Z

85

Table 8.5a Consumption of Combustible Fuels for Electricity ...  

U.S. Energy Information Administration (EIA)

Wood 8: Waste 9: Short Tons: Barrels: Short Tons: Barrels: Thousand Cubic Feet: ... For 1949–1979, data are for gas turbine and internal combustion plant use of ...

86

Table 8.5b Consumption of Combustible Fuels for Electricity ...  

U.S. Energy Information Administration (EIA)

Wood 8: Waste 9: Thousand Short Tons: Thousand Barrels: Thousand Short Tons: ... For 1949-1979, data are for gas turbine and internal combustion plant use of petroleum.

87

Table 8.5a Consumption of Combustible Fuels for Electricity ...  

U.S. Energy Information Administration (EIA)

Wood 8: Waste 9: Thousand Short Tons: Thousand Barrels: Thousand Short Tons: ... For 1949-1979, data are for gas turbine and internal combustion plant use of petroleum.

88

GEI 41040G - Specification for Fuel Gases for COmbustion in Heavy-Duty Gas Turbines  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Turbine Gas Turbine Revised, January 2002 GEI 41040G These instructions do not purport to cover all details or variations in equipment nor to provide for every possible contingency to be met in connection with installation, operation or maintenance. Should further information be desired or should particular problems arise which are not covered sufficiently for the purchaser's purposes the matter should be referred to the GE Company. © 1999 GENERAL ELECTRIC COMPANY Specification for Fuel Gases for Combustion in Heavy-Duty Gas Turbines GEI 41040G Specification for Fuel Gases for Combustion in Heavy-Duty Gas Turbines 2 TABLE OF CONTENTS I. INTRODUCTION 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

89

GTZ-Greenhouse Gas Calculator for Waste Management | Open Energy  

Open Energy Info (EERE)

GTZ-Greenhouse Gas Calculator for Waste Management GTZ-Greenhouse Gas Calculator for Waste Management Jump to: navigation, search Tool Summary Name: GTZ-Greenhouse Gas Calculator for Waste Management Agency/Company /Organization: GTZ Sector: Energy Website: www.gtz.de/en/themen/umwelt-infrastruktur/abfall/30026.htm References: GHG Calculator for Waste Management[1] Waste Management - GTZ Website[2] Logo: GTZ-Greenhouse Gas Calculator for Waste Management The necessity to reduce greenhouse gases and thus mitigate climate change is accepted worldwide. Especially in low- and middle-income countries, waste management causes a great part of the national greenhouse gas production, because landfills produce methane which has a particularly strong effect on climate change. Therefore, it is essential to minimize

90

Combustion Instability and Blowout Characteristics of Fuel Flexible Gas Turbine Combustors  

NLE Websites -- All DOE Office Websites (Extended Search)

Combustion Instability and Blowout Combustion Instability and Blowout Characteristics of Fuel Flexible Gas Turbine Characteristics of Fuel Flexible Gas Turbine Combustors Combustors Georgia Institute of Technology Georgia Institute of Technology Tim Lieuwen, Ben Zinn Bobby Noble, Qingguo Zhang DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES SCIES Project 03-01-SR111 Project Awarded (07/01/03, 36 Month Duration) Total Contract Value $376,722 . CLEMSON presentation, T.L., B.Z., B.N., Q.Z. Gas Turbine Need Gas Turbine Need * Need: Gas turbines with sufficient flexibility to cleanly and efficiently combust a wide range of fuels, particularly coal-derived gases - Problem: Inherent variability in composition and heating

91

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network (OSTI)

Nitrogeneous Species in Gas Turbine Exhaust, from Conkle, et82) Percent of Organic Gas Turbine Emissions which containnitrogen dioxide from gas turbines (from the data presented

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

92

Gas generation results and venting study for transuranic waste drums  

DOE Green Energy (OSTI)

Sixteen waste drums, containing six categories of plutonium-contaminated waste, were monitored for venting and gas generation for six months. The venting devices tested appeared adequate to relieve pressure and prevent hydrogen accumulation. Most of the gas generation, primarily H2 and CO2, was due to radiolytic decomposition of the hydrogenous wastes. Comparison of the gas yields with those obtained previously in laboratory tests showed very reasonable agreement with few exceptions.

Kazanjian, A.R.; Arnold, P.M.; Simmons, W.C.; D'Amico, E.L.

1985-09-23T23:59:59.000Z

93

Palladium-catalyzed combustion of methane: Simulated gas turbine combustion at atmospheric pressure  

Science Conference Proceedings (OSTI)

Atmospheric pressure tests were performed in which a palladium catalyst ignites and stabilizes the homogeneous combustion of methane. Palladium exhibited a reversible deactivation at temperatures above 750 C, which acted to ``self-regulate`` its operating temperature. A properly treated palladium catalyst could be employed to preheat a methane/air mixture to temperatures required for ignition of gaseous combustion (ca. 800 C) without itself being exposed to the mixture adiabatic flame temperature. The operating temperature of the palladium was found to be relatively insensitive to the methane fuel concentration or catalyst inlet temperature over a wide range of conditions. Thus, palladium is well suited for application in the ignition and stabilization of methane combustion.

Griffin, T.; Weisenstein, W. [ABB Corporate Research Center, Daettwill (Switzerland); Scherer, V. [ABB Kraftwerke, Mannheim (Germany); Fowles, M. [ICI Katalco, Cleveland (United Kingdom)

1995-04-01T23:59:59.000Z

94

Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment  

Science Conference Proceedings (OSTI)

Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energy release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.

Chen, C.C.; Lee, W.J.; Shih, S.I.; Mou, J.L. [National Cheng Kung University, Tainan (Taiwan). Dept. of Environmental Engineering

2009-07-01T23:59:59.000Z

95

SNG or syn-gas from wet solid waste and low grade fuels  

SciTech Connect

The substitute natural gas (SNG) or a synthesis gas (syngas) is prepared by partly oxidizing wastes and low-grade fuels (peat, lignite, many forms of biomass) containing 0.5-30 times as much water as the dry solids with O or air at 240-300/sup 0/C and 70-100 atmospheres. Sulfur in high S coal is oxidized selectively to SO/sub 4//sup -2/, and the heat to bring the combustible to the necessary temperature is supplied by burning part of the combustible itself. The residual solids (now 70-95% of the original fuel) are mechanically separated from all but 0.5-2 lb water. These solids come from the dewatering unit at a high pressure and may be passed, without loss of pressure or temperature to be gasified in conventional processes and gasifiers by partial oxidation.

Othmer, D.F.

1981-02-17T23:59:59.000Z

96

Low-Volume Wastes With High-Volume Coal Combustion By-Products: P4 Site  

Science Conference Proceedings (OSTI)

Historically, utilities have comanaged some or all of their low-volume wastes with their high-volume by-products in disposal facilities. This report presents the results of a field study of comanagement of coal combustion by-products at a utility-owned dry landfill in the midwestern United States. The findings from this research provide technical information for use in an ongoing study of comanagement by the U.S. Environmental Protection Agency (EPA).

1998-12-30T23:59:59.000Z

97

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Final report  

DOE Green Energy (OSTI)

The problem addressed by our invention is that of municipal solid waste utilization. The dimensions of the problem can be visualized by the common comparison that the average individual in America creates in five years time an amount of solid waste equivalent in weight to the Statue of Liberty. The combustible portion of the more than 11 billion tons of solid waste (including municipal solid waste) produced in the United States each year, if converted into useful energy, could provide 32 quads per year of badly needed domestic energy, or more than one-third of our annual energy consumption. Conversion efficiency and many other factors make such a production level unrealistic, but it is clear that we are dealing with a very significant potential resource. This report describes research pertaining to the co-combustion of oil shale with solid municipal wastes in a circulating fluidized bed. The oil shale adds significant fuel content and also constituents that can possible produce a useful cementitious ash.

NONE

1996-06-30T23:59:59.000Z

98

Corrosion and Mechanical Properties of Materials in Combustion and Mixed-Gas Environments  

NLE Websites -- All DOE Office Websites (Extended Search)

Corrosion and Mechanical Properties of Corrosion and Mechanical Properties of Materials in Combustion and Mixed-Gas Environments Background A number of advanced technologies are being developed to convert coal to clean fuels for power generation and for use as a feedstock in chemical plants. Coal con- version and combustion processes create by-products that affect the performance of the materials of which the plant components are fabricated, reducing the systems'

99

Online elemental analysis of process gases with ICP-OES: A case study on waste wood combustion  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Simultaneous measurements of 23 elements in process gases of a waste wood combustor. Black-Right-Pointing-Pointer Mobile ICP spectrometer allows measurements of high quality at industrial plants. Black-Right-Pointing-Pointer Continuous online measurements with high temporal resolution. Black-Right-Pointing-Pointer Linear correlations among element concentrations in the raw flue gas were detected. Black-Right-Pointing-Pointer Novel sampling and calibration methods for ICP-OES analysis of process gases. - Abstract: A mobile sampling and measurement system for the analysis of gaseous and liquid samples in the field was developed. An inductively coupled plasma optical emission spectrometer (ICP-OES), which is built into a van, was used as detector. The analytical system was calibrated with liquid and/or gaseous standards. It was shown that identical mass flows of either gaseous or liquid standards resulted in identical ICP-OES signal intensities. In a field measurement campaign trace and minor elements in the raw flue gas of a waste wood combustor were monitored. Sampling was performed with a highly transport efficient liquid quench system, which allowed to observe temporal variations in the elemental process gas composition. After a change in feedstock an immediate change of the element concentrations in the flue gas was detected. A comparison of the average element concentrations during the combustion of the two feedstocks showed a high reproducibility for matrix elements that are expected to be present in similar concentrations. On the other hand elements that showed strong differences in their concentration in the feedstock were also represented by a higher concentration in the flue gas. Following the temporal variations of different elements revealed strong correlations between a number of elements, such as chlorine with sodium, potassium and zinc, as well as arsenic with lead, and calcium with strontium.

Wellinger, Marco, E-mail: marco.wellinger@gmail.com [General Energy Research Department, Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland); Ecole Polytechnique Federale de Lausanne (EPFL), School of Architecture, Civil and Environmental Engineering (ENAC-IIE), CH-1015 Lausanne (Switzerland); Wochele, Joerg; Biollaz, Serge M.A. [General Energy Research Department, Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland); Ludwig, Christian, E-mail: christian.ludwig@psi.ch [General Energy Research Department, Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland); Ecole Polytechnique Federale de Lausanne (EPFL), School of Architecture, Civil and Environmental Engineering (ENAC-IIE), CH-1015 Lausanne (Switzerland)

2012-10-15T23:59:59.000Z

100

Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust  

DOE Patents (OSTI)

A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

2012-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network (OSTI)

of two power plants operating on natural gas. The N ofindings in a natural fired power of gas plant consisting of

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

102

Slurry growth and gas retention in synthetic Hanford waste  

DOE Green Energy (OSTI)

This work seeks to establish chemical and physical processes responsible for the generation and retention of gases within waste from a particular high-level waste tank on the Hanford Site, Tank 101-SY, through the use of synthetic wastes on a laboratory scale. The goal of these activities is to support the development of mitigation/remediation strategies for Tank 101-SY. Laboratory studies of aged synthetic waste have shown that gas generation occurs thermally at a significant level at current tank temperatures. Gas compositions include the same gases produced in actual tank waste, primarily N{sub 2}, N{sub 2}O, and H{sub 2}. Gas stoichiometries have been shown to be greatly influenced by several organic and inorganic constituents within the synthetic waste. Retention of gases in the synthetic waste is in the form of bubble attachment to solid particles.

Bryan, S.A.; Pederson, L.R.; Scheele, R.D.

1992-09-01T23:59:59.000Z

103

Slurry growth and gas retention in synthetic Hanford waste  

DOE Green Energy (OSTI)

This work seeks to establish chemical and physical processes responsible for the generation and retention of gases within waste from a particular high-level waste tank on the Hanford Site, Tank 101-SY, through the use of synthetic wastes on a laboratory scale. The goal of these activities is to support the development of mitigation/remediation strategies for Tank 101-SY. Laboratory studies of aged synthetic waste have shown that gas generation occurs thermally at a significant level at current tank temperatures. Gas compositions include the same gases produced in actual tank waste, primarily N[sub 2], N[sub 2]O, and H[sub 2]. Gas stoichiometries have been shown to be greatly influenced by several organic and inorganic constituents within the synthetic waste. Retention of gases in the synthetic waste is in the form of bubble attachment to solid particles.

Bryan, S.A.; Pederson, L.R.; Scheele, R.D.

1992-09-01T23:59:59.000Z

104

Detoxification and generation of useful products from coal combustion wastes  

Science Conference Proceedings (OSTI)

Electric utilities are on the brink of a new era in waste disposal problems. This research project addresses the issue of how to effectively dispose of flyash, bottom ash, desulfurization sludge through the generation of chemically-hardened material that could potentially be used as a cement or as a synthetic aggregate. The specific goals of this study were: (1) to study the hardness of mixtures of flyash, bottom ash, and DSG treated with lime and other hardening agents; (2) to determine the optimum solids content, setting time, moisture content, and post setting treatments that will yield the greatest strength and hardness out of these mixtures; and (3) to determine the leachability of the synthetic material as a measure of its ability to retain absorbed and/or entrained toxic metals. 50 refs., 15 figs., 8 tabs.

Not Available

1990-11-21T23:59:59.000Z

105

Emissions from small-scale energy production using co-combustion of biofuel and the dry fraction of household waste  

SciTech Connect

In sparsely populated rural areas, recycling of household waste might not always be the most environmentally advantageous solution due to the total amount of transport involved. In this study, an alternative approach to recycling has been tested using efficient small-scale biofuel boilers for co-combustion of biofuel and high-energy waste. The dry combustible fraction of source-sorted household waste was mixed with the energy crop reed canary-grass (Phalaris Arundinacea L.), and combusted in both a 5-kW pilot scale reactor and a biofuel boiler with 140-180 kW output capacity, in the form of pellets and briquettes, respectively. The chlorine content of the waste fraction was 0.2%, most of which originated from plastics. The HCl emissions exceeded levels stipulated in new EU-directives, but levels of equal magnitude were also generated from combustion of the pure biofuel. Addition of waste to the biofuel did not give any apparent increase in emissions of organic compounds. Dioxin levels were close to stipulated limits. With further refinement of combustion equipment, small-scale co-combustion systems have the potential to comply with emission regulations.

Hedman, Bjoern [Chemistry Department, Environmental Chemistry, Umeaa University, SE-901 87 Umeaa (Sweden)]. E-mail: bjorn.hedman@chem.umu.se; Burvall, Jan [Unit for Biomass Technology and Chemistry, Swedish University of Agricultural Sciences, Box 4097, SE-904 03 Umeaa (Sweden); Nilsson, Calle [NBC Defence, NBC Analysis, The Swedish Defence Research Agency, SE-901 82 Umeaa (Sweden); Marklund, Stellan [Chemistry Department, Environmental Chemistry, Umeaa University, SE-901 87 Umeaa (Sweden)

2005-07-01T23:59:59.000Z

106

Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines  

SciTech Connect

The purpose of this program was to develop low-emissions, efficient fuel-flexible combustion technology which enables operation of a given gas turbine on a wider range of opportunity fuels that lie outside of current natural gas-centered fuel specifications. The program encompasses a selection of important, representative fuels of opportunity for gas turbines with widely varying fundamental properties of combustion. The research program covers conceptual and detailed combustor design, fabrication, and testing of retrofitable and/or novel fuel-flexible gas turbine combustor hardware, specifically advanced fuel nozzle technology, at full-scale gas turbine combustor conditions. This project was performed over the period of October 2008 through September 2011 under Cooperative Agreement DE-FC26-08NT05868 for the U.S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled "Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines". The overall objective of this program was met with great success. GE was able to successfully demonstrate the operability of two fuel-flexible combustion nozzles over a wide range of opportunity fuels at heavy-duty gas turbine conditions while meeting emissions goals. The GE MS6000B ("6B") gas turbine engine was chosen as the target platform for new fuel-flexible premixer development. Comprehensive conceptual design and analysis of new fuel-flexible premixing nozzles were undertaken. Gas turbine cycle models and detailed flow network models of the combustor provide the premixer conditions (temperature, pressure, pressure drops, velocities, and air flow splits) and illustrate the impact of widely varying fuel flow rates on the combustor. Detailed chemical kinetic mechanisms were employed to compare some fundamental combustion characteristics of the target fuels, including flame speeds and lean blow-out behavior. Perfectly premixed combustion experiments were conducted to provide experimental combustion data of our target fuels at gas turbine conditions. Based on an initial assessment of premixer design requirements and challenges, the most promising sub-scale premixer concepts were evaluated both experimentally and computationally. After comprehensive screening tests, two best performing concepts were scaled up for further development. High pressure single nozzle tests were performed with the scaled premixer concepts at target gas turbine conditions with opportunity fuels. Single-digit NOx emissions were demonstrated for syngas fuels. Plasma-assisted pilot technology was demonstrated to enhance ignition capability and provide additional flame stability margin to a standard premixing fuel nozzle. However, the impact of plasma on NOx emissions was observed to be unacceptable given the goals of this program and difficult to avoid.

Venkatesan, Krishna

2011-11-30T23:59:59.000Z

107

Gas generation from Tank 241-SY-103 waste  

DOE Green Energy (OSTI)

This report summarizes progress made in evaluating mechanisms by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using actual waste from Tank 241-SY-103. The objective of this work is to establish the identity and stoichiometry of degradation products formed in actual tank wastes by thermal and radiolytic processes as a function of temperature. The focus of the gas generation tests on Tank 241-SY-103 samples is first the effect of temperature on gas generation (volume and composition). Secondly, gas generation from irradiation of Tank 241-SY-103 samples at the corresponding temperatures as the thermal-only treatments will be measured in the presence of an external radiation source (using a {sup 137}Cs capsule). The organic content will be measured on a representative sample prior to gas generation experiments and again at the termination of heating and irradiation. The gas generation will be related to the extent of organic species consumption during heating. Described in this report are experimental methods used for producing and measuring gases generated at various temperatures from highly radioactive actual tank waste, and results of gas generation from Tank 241-SY-103 waste taken from its convective layer. The accurate measurement of gas generation rates from actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from the convective layer of Tank 241-SY-103, a waste tank listed on the Flammable Gas Watch List due to its potential for flammable gas accumulation above the flammability limit.

Bryan, S.A.; King, C.M.; Pederson, L.R.; Forbes, S.V.; Sell, R.L.

1996-04-01T23:59:59.000Z

108

Reduced and Validated Kinetic Mechanisms for Hydrogen-CO-sir Combustion in Gas Turbines  

DOE Green Energy (OSTI)

Rigorous experimental, theoretical, and numerical investigation of various issues relevant to the development of reduced, validated kinetic mechanisms for synthetic gas combustion in gas turbines was carried out - including the construction of new radiation models for combusting flows, improvement of flame speed measurement techniques, measurements and chemical kinetic analysis of H{sub 2}/CO/CO{sub 2}/O{sub 2}/diluent mixtures, revision of the H{sub 2}/O{sub 2} kinetic model to improve flame speed prediction capabilities, and development of a multi-time scale algorithm to improve computational efficiency in reacting flow simulations.

Yiguang Ju; Frederick Dryer

2009-02-07T23:59:59.000Z

109

Near-Zero Emissions Oxy-Combustion Flue Gas Purification  

Science Conference Proceedings (OSTI)

The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions

Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

2012-06-30T23:59:59.000Z

110

Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas  

SciTech Connect

The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). 3) The Project will annually produce 365,292 MWh?s of clean energy. 4) By destroying the methane in the landfill gas, the Project will generate CO{sub 2} equivalent reductions of 164,938 tons annually. The completed facility produces 28.3 MWnet and operates 24 hours a day, seven days a week.

Galowitz, Stephen

2013-06-30T23:59:59.000Z

111

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials  

DOE Green Energy (OSTI)

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing materials. Transportation regulations prohibit shipment of explosives and radioactive materials together. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials (NM), and spent nuclear fuels (SNF) programs within DOE’s Environmental Management (EM) organization to address gas generation concerns. This paper presents a "program level" roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This "program level" roadmapping involves linking technology development (and deployment) efforts to the programs’ needs and requirements for dispositioning the material/waste that generates combustible gas through radiolysis and chemical decomposition. The roadmapping effort focused on needed technical & programmatic support to the baselines (and to alternatives to the baselines) where the probability of success is low (i.e., high uncertainty) and the consequences of failure are relatively high (i.e., high programmatic risk). A second purpose for roadmapping was to provide the basis for coordinating sharing of "lessons learned" from research and development (R&D) efforts across DOE programs to increase efficiency and effectiveness in addressing gas generation issues.

Luke, Dale Elden; Rogers, Adam Zachary; Hamp, S.

2001-03-01T23:59:59.000Z

112

Dynamic instabilities in spark-ignited combustion engines with high exhaust gas recirculation  

DOE Green Energy (OSTI)

We propose a cycle-resolved dynamic model for combustion instabilities in spark-ignition engines operating with high levels of exhaust gas recirculation (EGR). High EGR is important for increasing fuel efficiency and implementing advanced low-emission combustion modes such as homogenous charge compression ignition (HCCI). We account for the complex combustion response to cycle-to-cycle feedback by utilizing a global probability distribution that describes the pre-spark state of in-cylinder fuel mixing. The proposed model does a good job of simulating combustion instabilities observed in both lean-fueling engine experiments and in experiments where nitrogen dilution is used to simulate some of the combustion inhibition of EGR. When used to simulate high internal EGR operation, the model exhibits a range of global bifurcations and chaos that appear to be very robust. We use the model to show that it should be possible to reduce high EGR combustion instabilities by switching from internal to external EGR. We also explain why it might be helpful to deliberately stratify the fuel in the pre-spark gas mixture. It might be possible to extend the simple approach used in this model to other chemical reaction systems with spatial inhomogeneity.

Daw, C Stuart [ORNL; FINNEY, Charles E A [ORNL

2011-01-01T23:59:59.000Z

113

Flue Gas Purification Utilizing SOx/NOx Reactions During Compressin of CO2 Derived from Oxyfuel Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Flue Gas Purification Flue Gas Purification Utilizing SO X /NO X Reactions During Compression of CO 2 Derived from Oxyfuel Combustion Background Oxy-combustion in a pulverized coal-fired power station produces a raw carbon dioxide (CO 2 ) product containing contaminants such as water vapor, oxygen, nitrogen, and argon from impurities in the oxygen used and any air leakage into the system. Acid gases are also produced as combustion products, such as sulfur oxides (SO

114

Gas Turbine Reheat Using In-Situ Combustion  

SciTech Connect

Siemens Westinghouse Power Corporation (SWPC) is developing in-situ reheat (fuel injection via airfoil injection) as a means for increasing cycle efficiency and power output, with possibly reduced emissions. In addition to kinetic modeling and experimental task, CFD modeling (by Texas A&M) of airfoil injection and its effects on blade aerodynamics and turbine performance. This report discusses validation of the model against single-vane combustion test data from Siemens Westinghouse, and parametric studies of injection reheat in a modern turbine. The best location for injection is at the trailing edge of the inlet guide vane. Combustion is incomplete at trailing edges of subsequent vanes. Recommendations for further development are presented.

T.E. Lippert; D.M. Bachovchin

2004-03-31T23:59:59.000Z

115

A low NO/sub x/ combustion system and a ceramic cross flow heat exchanger for small gas turbines  

SciTech Connect

A new low NO/sub x/ oil-combustion system with superheated steam fuel evaporation prior to combustion has been found especially feasible for open cycle gas turbines with high turbine inlet temperatures and ceramic cross flow heat exchanger. The actual state of development of both the low NO/sub x/ light fuel-oil combustion system and ceramic heat exchanger elements, especially the cross flow type, is outlined in this paper. The use of this combustion system results in considerably lower combustion temperatures in the primary combustion zone, reducing the NO/sub x/-production even at high air temperatures when the air is preheated in the heat exchanger. The water vapour used for the evaporation of the fuel oil before combustion has an improving effect on the cycle efficiency comparable to the Cheng-dual-fluid-cycle. Illustrative evaluations for a gas turbine cycle for a shaft power of 70 kW are given.

Forster, S.; Quell, P.

1987-01-01T23:59:59.000Z

116

Radiolytic gas generation from cement-based waste hosts for DOE low-level radioactive wastes  

DOE Green Energy (OSTI)

Using cement-based immobilization binders with simulated radioactive waste containing sulfate, nitrate, nitrite, phosphate, and fluoride anions, the gamma- and alpha-radiolytic gas generation factors (G/sub t/, molecules/100 eV) and gas compositions were measured on specimens of cured grouts. These tests studied the effects of; (1) waste composition; (2) the sample surface-to-volume ratio; (3) the waste slurry particle size; and (4) the water content of the waste host formula. The radiolysis test vessels were designed to minimize the ''dead'' volume and to simulate the configuration of waste packages.

Dole, L.R.; Friedman, H.A.

1986-01-01T23:59:59.000Z

117

A Testing and Controlling System for the Combustion Test Rig of Gas Turbine Combustor  

Science Conference Proceedings (OSTI)

In this paper, a testing and controlling system is designed for the test rig of gas turbine combustor by using VXi bus and PLC technology. The system is composed of two subsystems: the data acquisition subsystem and the control subsystem. The data acquisition ... Keywords: combustion test rig, VXi bus, PLC control, Modbus agreement, data acquisition

Nihui Xie; Hua Song; Hongzhuan Qiu

2011-10-01T23:59:59.000Z

118

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS  

E-Print Network (OSTI)

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS Discussion by CRAIG's increased turbulent mixing is on the CO profile and what the incremental NOx reduction experienced was from that this alone would contribute to a significant reduction in the NO", generated. The authors are careful

Columbia University

119

Gas Turbines of the Future: Hydrogen and Oxy-Combustion ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Materials issues related to higher efficiency power plants, like hydrogen or oxy-fuel fired gas turbines, require materials with higher temperature  ...

120

Gas Turbines for Advanced Pressurized Fluidized Bed Combustion...  

NLE Websites -- All DOE Office Websites (Extended Search)

APFBC uses a circulating pressurized fluidized bed combustor (PFBC) with a fluid bed heat exchanger to develop hot vitiated air for the gas turbine' s topping combustor and...

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

System for recovering methane gas from liquid waste  

SciTech Connect

A system for and method of recovering methane gas from liquid waste which is stored within a pit is disclosed herein. The methane gas is produced by causing the liquid waste to undergo anaerobic fermentation. Therefore, it is necessary to close the pit in an air tight fashion. This is carried out using a cover sheet which is fixedly disposed over the pit in an air tight but readily disengagable fashion. The liquid waste within this air tight pit is preferably agitated intermittently during its storage therein whereby to increase the amount of methane gas produced.

Grabis, D.W.

1983-07-19T23:59:59.000Z

122

Generation Maintenance Application Center: Fuel Gas System for Combustion Turbine Combined Cycle Plant Maintenance Guide  

Science Conference Proceedings (OSTI)

This guide provides information to assist personnel involved with the maintenance of the fuel gas system at a gas turbine combined cycle facility, including good maintenance practices, preventive maintenance techniques and troubleshooting guidance. BackgroundCombustion turbine combined cycle (CTCC) facilities utilize various components that can be unique to this particular type of power plant. As such, owners and operators of CTCC facilities may find ...

2013-05-15T23:59:59.000Z

123

Studies Related to Chemical Mechanisms of Gas Formation in Hanford High-Level Nuclear Wastes  

DOE Green Energy (OSTI)

The objective of this work is to develop a more detailed mechanistic understanding of the thermal reactions that lead to gas production in certain high-level waste storage tanks at the Hanford, Washington site. Prediction of the combustion hazard for these wastes and engineering parameters for waste processing depend upon both a knowledge of the composition of stored wastes and the changes that they undergo as a result of thermal and radiolytic decomposition. Since 1980 when Delagard first demonstrated that gas production (H2and N2O initially, later N2 and NH3)in the affected tanks was related to oxidative degradation of metal complexants present in the waste, periodic attempts have been made to develop detailed mechanisms by which the gases were formed. These studies have resulted in the postulation of a series of reactions that account for many of the observed products, but which involve several reactions for which there is limited, or no, precedent. For example, Al(OH)4 has been postulated to function as a Lewis acid to catalyze the reaction of nitrite ion with the metal complexants, NO is proposed as an intermediate, and the ratios of gaseous products may be a result of the partitioning of NO between two or more reactions. These reactions and intermediates have been the focus of this project since its inception in 1996.

E. Kent Barefield; Charles L. Liotta; Henry M. Neumann

2002-04-08T23:59:59.000Z

124

TRU Waste Sampling Program: Volume II. Gas generation studies  

DOE Green Energy (OSTI)

Volume II of the TRU Waste Sampling Program report contains the data generated from evaluating the adequacy of venting/filtering devices for maintaining safe hydrogen levels in plutonium contaminated waste drums. Additional studies reported in this volume include gas generation rates, selected waste form monitoring, and evaluation of hydrogen migration from sealed 90-mil rigid polyethylene drum liners containing /sup 238/Pu-contaminated wastes. All wastes used in the studies were newly-generated, and the waste drums were under controlled, experimental conditions. Studies using /sup 239/Pu-contaminated wastes were conducted at the Rocky Flats Plant. Studies using /sup 238/Pu-contaminated wastes were conducted at the Los Alamos National Laboratory.

Clements, T.L. Jr.; Kudera, D.E.

1985-09-01T23:59:59.000Z

125

Control of waste gas from a thermal EOR operation  

SciTech Connect

This paper summarizes a waste-gas treatment system designed to control emissions from thermal EOR wells. This case study discusses the need, design, installation, and operation of the system.

Peavy, M.A.; Braun, J.E. (Oryx Energy Co. (US))

1991-06-01T23:59:59.000Z

126

The effects of spark ignition parameters on the lean burn limit of natural gas combustion in an internal combustion engine  

E-Print Network (OSTI)

A full factorial experiment was conducted to determine the effects of internal combustion engine ignition parameters on the air-fuel ratio (A/F) lean limit of combustion with compressed natural gas (CNG). Spark electrical characteristics (voltage, current, power, energy and duration), electrode design, electrode gap and compression ratio were the control variables and A/F lean limit, fuel consumption and hydrocarbon and oxides of nitrogen emission concentrations were the response variables. Experiments were performed on a General Motors' 2.2 liter four cylinder engine. Spark electrical characteristics were varied by applying various primary voltages and secondary resistances to the production inductive ignition system, with the engine operating at two operating conditions, a light load and a road load, and with two compression ratios. Cylinder pressure data was acquired to quantify load and combustion stability. Spark electrical characteristics were acquired with a digital oscilloscope to quantify secondary spark electrical characteristics. The results indicated that the response variables were generally insensitive to all the control variables, except for compression ratio. However, contrary to the literature, the A/F lean limit and fuel efficiency degraded with a higher compression ratio. Single and multi-variant linear regressions were studied between the A/F lean limit and the spark electrical characteristics. The only statistically significant and notable finding was a multi-variant linear regression of the A/F lean limit to increasing spark duration and decreasing spark energy at the road load operating condition. Statistical significance of the effect of the ignition system control variables on the response variables was higher at the road load than the light load operating condition. Emissions responded as expected with the higher compression ratio.

Chlubiski, Vincent Daniel

1997-01-01T23:59:59.000Z

127

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network (OSTI)

of amines from coal and oil fired power plants. estimateof 100 ppm from coal, oil, and gas fired stationary powerin the which used fuel oil. Craig emissions from confirmed a

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

128

Reduction of NO[sub x] emissions coke oven gas combustion process  

SciTech Connect

The paper describes by-product processing at Clairton Works which uses a unique cryogenic technology. Modifications to the desulfurization facility, nitrogen oxide formation in combustion processes (both thermal and fuel NO[sub x]), and the boilers plants are described. Boilers were used to study the contribution of fuel NO[sub x] formation during the combustion of coke oven gas. Results are summarized. The modifications made to the desulfurization facility resulted in the overall H[sub 2]S emission being reduced by 2-4 grains/100scf and the NO[sub x] emission being reduced by 21-42% in the boiler stacks.

Terza, R.R. (USS Clairton Works, PA (United States)); Sardesai, U.V. (Westfield Engineering and Services, Inc., Houston, TX (United States))

1993-01-01T23:59:59.000Z

129

Design and construction of a thermophotovoltaic generator using turbine combustion gas  

SciTech Connect

This US Naval Academy project involves the development of a prototype thermophotovoltaic (TPV) generator that uses a General Electric T-58 helicopter gas turbine as the heat source. The goals of this project were to demonstrate the viability of using TPV and external combustion gases to generate electricity, and develop a system which could also be used for materials testing. The generator was modularly designed so that different materials could be tested at a later date. The combustion gas was tapped from the T-58`s combustor through one of the two igniter ports and extracted through a silicon carbide matrix ceramic composite tube into a similarly constructed ceramic composite radiant emitter. The ceramic radiant emitters is heated by the combustion gas via convection, and then serves the TPV generator by radiating the heat outwards where it can be absorbed by thermophotovoltaic cells and converted directly into electricity. The gas turbine and generator module are monitored by a data acquisition system that performs both data collection and control functions. This paper details the design of the TPV generator. It also gives results of initial tests with the gas turbine.

Erickson, T.A.; Lindler, K.W.; Harper, M.J. [Naval Academy, Annapolis, MD (United States). Dept. of Naval Architecture, Ocean, and Marine Engineering

1997-07-01T23:59:59.000Z

130

Process for the elimination of waste water produced upon the desulfurization of coking oven gas by means of wash solution containing organic oxygen-carrier, with simultaneous recovery of elemental sulfur  

Science Conference Proceedings (OSTI)

A process is disclosed for the elimination of waste water falling out with the desulfurization of coking oven gas by means of an organic oxygen carrier-containing washing solution with simultaneous recovery of elemental sulfur. The waste water is decomposed in a combustion chamber in a reducing atmosphere at temperatures between about 1000/sup 0/ and 1100/sup 0/ C. under such conditions that the mole ratio of H/sub 2/S:SO/sub 2/ in the exhaust gas of the combustion chamber amounts to at least 2:1. Sulfur falling out is separated and the sensible heat of the exhaust gas is utilized for steam generation. The cooled and desulfurized exhaust gas is added to the coking oven gas before the pre-cooling. Sulfur falling out from the washing solution in the oxidizer is separated out and lead into the combustion chamber together with the part of the washing solution discharged as waste water from the washing solution circulation. Preferred embodiments include that the sulfur loading of the waste water can amount to up to about 370 kg sulfur per m/sup 3/ waste water; having the cooling of sulfur-containing exhaust gas leaving the combustion chamber follow in a waste heat boiler and a sulfur condenser heated by pre-heated boiler feed water, from which condenser sulfur is discharged in liquid state.

Diemer, P.; Brake, W.; Dittmer, R.

1985-04-16T23:59:59.000Z

131

Study of physical properties, gas generation and gas retention in simulated Hanford waste  

DOE Green Energy (OSTI)

The purpose of this study was to establish the chemical and physical processes responsible for the generation and retention of gases within high-level waste from Tank 101-SY on the Hanford Site. This research, conducted using simulated waste on a laboratory scale, supports the development of mitigation/remediation strategies for Tank 101-SY. Simulated waste formulations are based on actual waste compositions. Selected physical properties of the simulated waste are compared to properties of actual Tank 101-SY waste samples. Laboratory studies using aged simulated waste show that significant gas generation occurs thermally at current tank temperatures ({approximately}60{degrees}C). Gas compositions include the same gases produced in actual tank waste, primarily N{sub 2}, N{sub 2}O, and H{sub 2}. Gas stoichiometries have been shown to be greatly influenced by several organic and inorganic constituents within the simulated waste. Retention of gases in the simulated waste is in the form of bubble attachment to solid particles. This attachment phenomenon is related to the presence of organic constituents (HEDTA, EDTA, and citrate) of the simulated waste. A mechanism is discussed that relates the gas bubble/particle interactions to the partially hydrophobic surface produced on the solids by the organic constituents.

Bryan, S.A.; Pederson, L.R.; Scheele, R.D.

1993-04-01T23:59:59.000Z

132

Municipal Solid Waste Combustion : Fuel Testing and Characterization : Task 1 Report, May 30, 1990-October 1, 1990.  

DOE Green Energy (OSTI)

The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

Bushnell, Dwight J.; Canova, Joseph H.; Dadkhah-Nikoo, Abbas.

1990-10-01T23:59:59.000Z

133

Combustion of ultrafine coal/water mixtures and their application in gas turbines: Final report  

Science Conference Proceedings (OSTI)

The feasibility of using coal-water fuels (CWF) in gas turbine combustors has been demonstrated in recent pilot plant experiments. The demands of burning coal-water fuels with high flame stability, complete combustion, low NO/sub x/ emission and a resulting fly ash particle size that will not erode turbine blades represent a significant challenge to combustion scientists and engineers. The satisfactory solution of these problems requires that the variation of the structure of CWF flames, i.e., the fields of flow, temperature and chemical species concentration in the flame, with operating conditions is known. Detailed in-flame measurements are difficult at elevated pressures and it has been proposed to carry out such experiments at atmospheric pressure and interpret the data by means of models for gas turbine combustor conditions. The research was carried out in five sequential tasks: cold flow studies; studies of conventional fine-grind CWF; combustion studies with ultrafine CWF fuel; reduction of NO/sub x/ emission by staged combustion; and data interpretation-ignition and radiation aspects. 37 refs., 61 figs., 9 tabs.

Toqan, M.A.; Srinivasachar, S.; Staudt, J.; Varela, F.; Beer, J.M.

1987-10-01T23:59:59.000Z

134

Radiogenic gas accumulation in TRU waste storage drums  

DOE Green Energy (OSTI)

A field experiment was conducted over a four-year time span to determine the effect of high-activity transuranic (TRU) waste on the atmosphere within TRU waste storage drums typical of those generated in Savannah River Plant operation. Routine gas composition analyses showed that a significant amount of hydrogen can accumulate in drums that contain high alpha activity, and that flammable gas mixtures could form in such drums in spite of the radiolytic consumption of oxygen. According to this study, gas pressure accumulation does not pose a threat to the integrity of the TRU waste containers that are now being stored at the Savannah River Plant. Therefore, the 20-year storage criterion is still viable. However, the continued avoidance of a perfectly gas-tight drum seal (e.g., epoxy, metal welding) is recommended. The test drums will continue to be monitored.

Ryan, J.P.

1982-01-01T23:59:59.000Z

135

Program on Technology Innovation: Combustion Exhaust Gas Monitoring with Laser Absorption Sensors  

Science Conference Proceedings (OSTI)

In current plant practice, the operator of a coal-fired boiler must typically rely on a limited number of point measurements of exhaust-gas oxygen and nitric oxides (NOX) to support combustion and selective catalytic reduction (SCR) control efforts with the goal of meeting emissions reduction mandates. As a possible alternative, tunable diode laser technology offers the potential for enabling a much richer set of measurements to be obtained using in situ, species-specific laser absorption sensors. This t...

2012-07-11T23:59:59.000Z

136

Development and validation of a combustion model for a fuel cell off-gas burner  

E-Print Network (OSTI)

and environmentally clean power generation has never been so important. The increasing cost of fossil fuels and more stringent regulations on emissions (particularly CO2 and NOx), together with increasing demand for electricity, make the provision of cost... Development and Validation of a Combustion Model for a Fuel Cell Off-Gas Burner W. Tristan Collins Magdalene College University of Cambridge A dissertation submitted to the University of Cambridge for the degree of Doctor of Philosophy June 2008...

Collins, William Tristan

2008-10-14T23:59:59.000Z

137

Hot Gas Cleanup Test Facility for gasification and pressurized combustion. Quarterly report, October--December 1994  

Science Conference Proceedings (OSTI)

The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. The major emphasis during this reporting period was continuing the detailed design of the facility and integrating the particulate control devices (PCDs) into structural and process designs. Substantial progress in underground construction activities was achieved during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. MWK equipment at the grade level and the first tier are being set in the structure.

NONE

1995-02-01T23:59:59.000Z

138

Combined catalysts for the combustion of fuel in gas turbines  

Science Conference Proceedings (OSTI)

A catalytic oxidation module for a catalytic combustor of a gas turbine engine is provided. The catalytic oxidation module comprises a plurality of spaced apart catalytic elements for receiving a fuel-air mixture over a surface of the catalytic elements. The plurality of catalytic elements includes at least one primary catalytic element comprising a monometallic catalyst and secondary catalytic elements adjacent the primary catalytic element comprising a multi-component catalyst. Ignition of the monometallic catalyst of the primary catalytic element is effective to rapidly increase a temperature within the catalytic oxidation module to a degree sufficient to ignite the multi-component catalyst.

Anoshkina, Elvira V.; Laster, Walter R.

2012-11-13T23:59:59.000Z

139

A method and apparatus for destroying hazardous organics and other combustible materials in a subcritical/supercritical reactor  

DOE Patents (OSTI)

A waste destruction method is described using a reactor vessel to combust and destroy organic and combustible waste, including the steps of introducing a supply of waste into the reactor vessel, introducing a supply of an oxidant into the reactor vessel to mix with the waste forming a waste and oxidant mixture, introducing a supply of water into the reactor vessel to mix with the waste and oxidant mixture forming a waste, water and oxidant mixture, reciprocatingly compressing the waste, water and oxidant mixture forming a compressed mixture, igniting the compressed mixture forming a exhaust gas, and venting the exhaust gas into the surrounding atmosphere.

Janikowski, Stuart K.

1997-12-01T23:59:59.000Z

140

Optimization of Combustion Efficiency for Supplementally Fired Gas Turbine Cogenerator Exhaust Heat Receptors  

E-Print Network (OSTI)

A broad range of unique cogeneration schemes are being installed or considered for application in the process industries involving gas turbines with heat recovery from the exhaust gas. Depending on the turbine design, exhaust gases will range from 800 to 1000 F with roughly 15 to 18 percent remaining oxygen. The overall heat utilization efficiency and the net effective heat rate of the cogenerating facility varies widely with the degree of supplemental firing of the heat receptor. This effect is explained and its economic significance defined. Other effects are also explored, such as adiabatic and equilibrium combustion temperatures; and variations in radiant versus convection heat transfer in the heat receptor furnace or boiler.

Waterland, A. F.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Radiolytic gas production from concrete containing Savannah River Plant waste  

DOE Green Energy (OSTI)

To determine the extent of gas production from radiolysis of concrete containing radioactive Savannah River Plant waste, samples of concrete and simulated waste were irradiated by /sup 60/Co gamma rays and /sup 244/Cm alpha particles. Gamma radiolysis simulated radiolysis by beta particles from fission products in the waste. Alpha radiolysis indicated the effect of alpha particles from transuranic isotopes in the waste. With gamma radiolysis, hydrogen was the only significant product; hydrogen reached a steady-state pressure that increased with increasing radiation intensity. Hydrogen was produced faster, and a higher steady-state pressure resulted when an organic set retarder was present. Oxygen that was sealed with the wastes was depleted. Gamma radiolysis also produced nitrous oxide gas when nitrate or nitrite was present in the concrete. With alpha radiolysis, hydrogen and oxygen were produced. Hydrogen did not reach a steady-state pressure at <140 psi. From these results, estimates of pressure in conceptual containers (cylinders 2 feet ID by 10 feet tall, 90% full) of SRP waste concrete were made. During the first 300 years of storage when radiolysis will mainly be from beta-gamma radiation (from /sup 137/Cs and /sup 90/Sr), hydrogen will reach a steady-state pressure of 8 to 28 psi, and oxygen will be partially consumed. These predictions were confirmed by measurement of gas produced over a short time in a container of concrete and actual SRP waste. The tests with simulated waste also indicated that nitrous oxide may form, but because of the low nitrate or nitrite content of the waste, the maximum pressure of nitrous oxide after 300 years will be <60 psi. After decay of these fission products, alpha radiolysis from /sup 238/Pu and /sup 239/Pu will predominate; the hydrogen and oxygen pressures will increase to >200 psi.

Bibler, N.E.

1978-01-01T23:59:59.000Z

142

Effects of Globally Waste Disturbing Activities on Gas Generation, Retention, and Release in Hanford Waste Tanks  

SciTech Connect

Various operations are authorized in Hanford single- and double-shell tanks that disturb all or a large fraction of the waste. These globally waste-disturbing activities have the potential to release a large fraction of the retained flammable gas and to affect future gas generation, retention, and release behavior. This report presents analyses of the expected flammable gas release mechanisms and the potential release rates and volumes resulting from these activities. The background of the flammable gas safety issue at Hanford is summarized, as is the current understanding of gas generation, retention, and release phenomena. Considerations for gas monitoring and assessment of the potential for changes in tank classification and steady-state flammability are given.

Stewart, Charles W.; Fountain, Matthew S.; Huckaby, James L.; Mahoney, Lenna A.; Meyer, Perry A.; Wells, Beric E.

2005-08-02T23:59:59.000Z

143

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents (OSTI)

The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

Yang, W.C.; Newby, R.A.; Lippert, T.E.

1997-08-05T23:59:59.000Z

144

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents (OSTI)

The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

1997-01-01T23:59:59.000Z

145

Slurry growth, gas retention, and flammable gas generation by Hanford radioactive waste tanks: Synthetic waste studies, FY 1991  

DOE Green Energy (OSTI)

Of 177 high-level waste storage tanks on the Hanford Site, 23 have been placed on a safety watch list because they are suspected of producing flammable gases in flammable or explosive concentrate. One tankin particular, Tank 241-SY-101 (Tank 101-SY), has exhibited slow increases in waste volume followed by a rapid decrease accompanied by venting of large quantities of gases. The purpose of this study is to help determine the processes by which flammable gases are produced, retained, and eventually released from Tank 101-SY. Waste composition data for single- and double-shell waste tanks on the flammable gas watch listare critically reviewed. The results of laboratory studies using synthetic double-shell wastes are summarized, including physical and chemical properties of crusts that are formed, the stoichiometry and rate ofgas generation, and mechanisms responsible for formation of a floating crust.

Bryan, S.A.; Pederson, L.R.; Ryan, J.L.; Scheele, R.D.; Tingey, J.M.

1992-08-01T23:59:59.000Z

146

DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS FIRED COMBUSTION SYSTEMS  

SciTech Connect

This report provides results from the second year of this three-year project to develop dilution measurement technology for characterizing PM2.5 (particles with aerodynamic diameter smaller than 2.5 micrometers) and precursor emissions from stationary combustion sources used in oil, gas and power generation operation. Detailed emission rate and chemical speciation tests results for a gas turbine, a process heater, and a commercial oil/gas fired boiler are presented. Tests were performed using a research dilution sampling apparatus and traditional EPA methods. A series of pilot tests were conducted to identify the constraints to reduce the size of current research dilution sampler for future stack emission tests. Based on the test results, a bench prototype compact dilution sampler developed and characterized in GE EER in August 2002.

Glenn England; Oliver Chang; Stephanie Wien

2002-02-14T23:59:59.000Z

147

A Novel High-Heat Transfer Low-NO{sub x} Natural Gas Combustion System. Final Technical Report  

Science Conference Proceedings (OSTI)

A novel high-heat transfer low NO(sub x) natural gas combustion system. The objectives of this program are to research, develop, test, and commercialize a novel high-heat transfer low-NO{sub x} natural gas combustion system for oxygen-, oxygen-enriched air, and air-fired furnaces. This technology will improve the process efficiency (productivity and product quality) and the energy efficiency of high-temperature industrial furnaces by at least 20%. GTI's high-heat transfer burner has applications in high-temperature air, oxygen-enriched air, and oxygen furnaces used in the glass, metals, cement, and other industries. Development work in this program is focused on using this burner to improve the energy efficiency and productivity of glass melting furnaces that are major industrial energy consumers. The following specific project objectives are defined to provide a means of achieving the overall project objectives. (1) Identify topics to be covered, problems requiring attention, equipment to be used in the program, and test plans to be followed in Phase II and Phase III. (2) Use existing codes to develop models of gas combustion and soot nucleation and growth as well as a thermodynamic and parametric description of furnace heat transfer issues. (3) Conduct a parametric study to confirm the increase in process and energy efficiency. (4) Design and fabricate a high-heat transfer low-NOx natural gas burners for laboratory, pilot- and demonstration-scale tests. (5) Test the high-heat transfer burner in one of GTI's laboratory-scale high-temperature furnaces. (6) Design and demonstrate the high-heat transfer burner on GTI's unique pilot-scale glass tank simulator. (7) Complete one long term demonstration test of this burner technology on an Owens Corning full-scale industrial glass melting furnace. (8) Prepare an Industrial Adoption Plan. This Plan will be updated in each program Phase as additional information becomes available. The Plan will include technical and economic analyses, energy savings and waste reduction predictions, evaluation of environmental effects, and outline issues concerning manufacturing, marketing, and financing. Combustion Tec, Owens Corning, and GTI will all take active roles in defining this Plan. During Phase I, the first three objectives were addressed and completed along with the design component of the fourth objective. In Phase II, the fabrication component of the fourth objective was completed along with objectives five and six. Results of the Phase I work were reported in the Phase I Final Report and are summarized in this Final Technical Report. Work for Phase II was divided in four specific Tasks. Results of the Phase II work were reported in the Phase II Final Report and are also summarized in this Final Technical Report. No Phase III Final Report was prepared, so this Final Technical Report presents the results of Phase III commercial demonstration efforts. A description of each Task in Phases I, II, and III is presented in this report.

Abbasi, H.

2004-01-01T23:59:59.000Z

148

System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines  

SciTech Connect

Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

Shahrokh Etemad; Lance Smith; Kevin Burns

2004-12-01T23:59:59.000Z

149

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending 31 December 1994  

DOE Green Energy (OSTI)

The test plan is designed to demonstrate that oil shale co-combusted with municipal solid waste (MSW) can reduce gaseous pollutants (SO{sub 2}, CO) to acceptable levels (90%+ reduction) and produce a cementitious ash which will, at a minimum, be acceptable in normal land fills. The small-scale combustion testing will be accomplished in a 6-in. circulating fluid bed combustor (CFBC) at Hazen Research Laboratories. This work will be patterned after the study the authors conducted in 1988 when coal and oil shale were co-combusted in a program sponsored by the Electric Power Research Institute. The specific purpose of the test program will be to: determine the required ratio of oil shale to MSW by determining the ratio of absorbent to pollutant (A/P); determine the effect of temperature and resident time in the reactor; and determine if kinetic model developed for coal/oil shale mixture is applicable.

Not Available

1995-01-01T23:59:59.000Z

150

THE EFFECTS OF HYDROGEN ADDITION AND INTAKE-INDUCED SWIRL ON THE CHARACTERISTICS OF NATURAL GAS COMBUSTION IN A SINGLE-CYLINDER SPARK-IGNITED ENGINE.  

E-Print Network (OSTI)

??Compressed natural gas (CNG) is an alternative fuel of interest for internal combustion engines (ICEs) in the mass transit and vocational applications. Increasingly, due to… (more)

Corrigan, Melanie

2011-01-01T23:59:59.000Z

151

Combustion Turbine Combined Cycle Technology Developments, Reliability Issues, and Related Market Conditions: EPRI Gas Turbine Exper ience and Intelligence Report  

Science Conference Proceedings (OSTI)

Deregulating power generation markets worldwide present both business opportunities and challenges for combustion turbine (CT) plant owners, operators, and project developers. The "EPRI Gas Turbine Experience and Intelligence Report" (GTE&IR) provides concise, well-organized, up-to-date technical, strategic, and business information for combustion turbine (CT) power producers. This technical report assembles all of the content from the most recent three years of GTE&IR (seven editions) into a single docu...

2001-12-04T23:59:59.000Z

152

Apparatus for dusting off gas by filtration and aspiration cleaning of filter, and application to combustion gases  

SciTech Connect

Method and apparatus for dusting off gases by filtration and cleaning of filter by aspiration and application thereof to combustion gases are disclosed. This invention relates to the filtration of dust loaded gases, and, in particular, combustion gases in the hot state. It consists of passing gases to be dusted off from top to bottom over a bed of pulverulent material, in particular, a sand bed and cleaning the upper layer of said bed by aspiration of dusts deposited thereon. This invention is particularly adapted for dusting off combustion gases from boilers or thermal power stations or gases to be supplied to gas turbines.

Merry, J.

1982-07-06T23:59:59.000Z

153

The Modeling of a Laboratory Natural GasFired Furnace with a HigherOrder Projection Method for Unsteady Combustion \\Lambda  

E-Print Network (OSTI)

for Unsteady Combustion \\Lambda R.B. Pember, P. Colella, L.H. Howell, A.S. Almgren, J.B. Bell, W.Y. Crutchfield method for axisymmetric, unsteady, low­ Mach number combustion is used to model a natural gas flame from axisymmetric reacting flow code in order to evaluate the combustion model and the numerical method. The results

154

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report ending March 31, 1996  

SciTech Connect

This document contains a progress report for the Project Description of Grant No. DE-FG01-94CE15612, {open_quotes}Develop a Combustion of Municipal Solid Waste with Oil Shale in Circulating Fluidized Bed{close_quotes}, dated September 2, 1994. The Project Description lists and describes six tasks, four of which are complete, and two others nearing completion. A summary of progress on each task is presented in this report.

1996-04-01T23:59:59.000Z

155

Mixtures of a Coal Combustion By-Product and Composted Yard Wastes for Use as Soil Substitutes and Amendments  

Science Conference Proceedings (OSTI)

Under certain conditions, the physical and chemical properties of coal combustion by-products (CCBPs) can be conducive to plant growth. As one means of increasing use rates, EPRI and several utilities have studied CCBP applications as a soil amendment and soil substitute when mixed with varying proportions of yard waste compost, sand, and soil. This report presents the results of green-house studies on the use of CCBP mixtures in growing shrubs, trees, and ground cover plants.

1996-10-26T23:59:59.000Z

156

LASER STABILIZATION FOR NEAR ZERO NO{sub x} GAS TURBINE COMBUSTION SYSTEMS  

SciTech Connect

Historically, the development of new industrial gas turbines has been primarily driven by the intent to achieve higher efficiency, lower operating costs and lower emissions. Higher efficiency and lower cost is obtained through higher turbine operating temperatures, while reduction in emissions is obtained by extending the lean operating limit of the combustor. However reduction in the lean stability limit of operation is limited greatly by the chemistry of the combustion process and by the occurrence of thermo-acoustic instabilities. Solar Turbines, CFD Research Corporation, and Los Alamos National Laboratory have teamed to advance the technology associated with laser-assisted ignition and flame stabilization, to a level where it could be incorporated onto a gas turbine combustor. The system being developed is expected to enhance the lean stability limit of the swirl stabilized combustion process and assist in reducing combustion oscillations. Such a system has the potential to allow operation at the ultra-lean conditions needed to achieve NO{sub x} emissions below 5 ppm without the need of exhaust treatment or catalytic technologies. The research effort was focused on analytically modeling laser-assisted flame stabilization using advanced CFD techniques, and experimentally demonstrating the technology, using a solid-state laser and low-cost durable optics. A pulsed laser beam was used to generate a plasma pool at strategic locations within the combustor flow field such that the energy from the plasma became an ignition source and helped maintain a flame at ultra lean operating conditions. The periodic plasma generation and decay was used to nullify the fluctuations in the heat release from the flame itself, thus decoupling the heat release from the combustor acoustics and effectively reducing the combustion oscillations. The program was built on an existing technology base and includes: extending LANL's existing laser stabilization experience to a sub-scale combustor rig, performing and validating CFD predictions, and ultimately conducting a full system demonstration in a multi-injector combustion system at Solar Turbines.

Vivek Khanna

2002-09-30T23:59:59.000Z

157

Compact Ceramic Heat Exchangers for Corrosive Waste Gas Applications  

E-Print Network (OSTI)

The development of large ceramic heat exchangers is described and performance data given for units installed on steel industry soaking pits in the U.K. Operational experience since 1973 confirms that ceramic heat exchangers capable of operating with high airside pressures have long lives and low maintenance even when operating with dirty gases at 1350 deg. C and preheating combustion air to 800 deg. C. The design of compact units suitable for factory assembly is also described. Units have been developed for low temperature corrosive gas situations and have been applied to the pottery industry and are being developed for coal fired air heaters for the food industry.

Laws, W. R.; Reed, G. R.

1982-01-01T23:59:59.000Z

158

Effects of oxygen cover gas and NaOH dilution on gas generation in tank 241-SY-101 waste  

DOE Green Energy (OSTI)

Laboratory studies are reported of gas generation in heated waste from tank 241-SY-101. The rates of gas generation and the compositions of product gas were measured. Three types of tests are compared. The tests use: undiluted waste, waste diluted by a 54% addition of 2.5 M NaOH, and undiluted waste with a reactive cover gas of 30% Oxygen in He. The gas generation rate is reduced by dilution, increased by higher temperatures (which determines activation energies), and increased by reactions of Oxygen (these primarily produce H{sub 2}). Gases are generated as reduction products oxidation of organic carbon species by nitrite and oxygen.

Person, J.C.

1996-05-30T23:59:59.000Z

159

Near-Zero NOx Combustion Technology for ATS Mercury 50 Gas Turbine  

SciTech Connect

A project to demonstrate a near-zero NOx, catalytic combustion technology for natural gas-fired, industrial gas turbines is described. In a cooperative effort between Solar Turbines Incorporated and Precision Combustion Incorporated (PCI), proof-of-concept rig testing of PCI's fuel-rich catalytic combustion technology has been completed successfully. The primary technical goal of the project was to demonstrate NOx and CO emissions below 5ppm and 10 ppm, respectively, (corrected to 15% O{sub 2}) at realistic gas turbine operating conditions. The program consisted of two tasks. In the first task, a single prototype RCL{trademark} (Rich Catalytic Lean Burn) module was demonstrated at Taurus 70 (7.5 Mw) operating conditions (1.6 MPa, 16 atm) in a test rig. For a Taurus 70 engine, eight to twelve RCL modules will be required, depending on the final system design. In the second task, four modules of a similar design were adapted to a Saturn engine (1 Mw) test rig (600 kPa, 6 atm) to demonstrate gas turbine light-off and operation with an RCL combustion system. This project was initially focused on combustion technology for the Mercury 50 engine. However, early in the program, the Taurus 70 replaced the Mercury. This substitution was motivated by the larger commercial market for an ultra-low NOx Taurus 70 in the near-term. Rig tests using a single prototype RCL module at Taurus 70 conditions achieved NOx emissions as low as 0.75 ppm. A combustor turndown of approximately 110C (200F) was achieved with NOx and CO emissions below 3 ppm and 10 ppm, respectively. Catalyst light-off occurred at an inlet temperature of 310C (590F). Once lit the module remained active at inlet air temperatures as low as 204C (400F). Combustor pressure oscillations were acceptably low during module testing. Single module rig tests were also conducted with the Taurus 70 module reconfigured with a central pilot fuel injector. Such a pilot will be required in a commercial RCL system for turbine light-off and transient operation. At and near simulated full load engine conditions, the pilot operated at low pilot fueling rates without degrading overall system emissions. In the second project task, a set of four Taurus 70 modules was tested in an existing Saturn engine rig. The combustion system allowed smooth engine startup and load variation. At steady state conditions (between 82% and 89.7% engine speed; 32% and 61% load), NOx and CO emissions were below 3ppm and 10ppm, respectively. Rig limitations unrelated to the RCL technology prevented low emissions operation outside of this speed range. Combustor pressure oscillations were low, below 0.25 % (peak-to-peak) of the mean combustor pressure.

Kenneth Smith

2004-12-31T23:59:59.000Z

160

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents (OSTI)

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

2010-11-09T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Flammable gas tank waste level reconciliation for 241-S-111  

SciTech Connect

Fluor Daniel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 241-S-111. The trapped gas evaluation document states that Tank S-111 exceeds the 25% of the lower flammable-limit criterion, based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the Welty Report is the basis for this letter report. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unaccounted for surface level rise. From 1973 through 1980, the Welty Report tracked Tank S-111 transfers. This surface level increase is from an unknown source or is unaccounted for. Duke Engineering and Services Hanford and Lockheed Martin Hanford Corporation are interested in determining the validity of the unexplained surface level changes reported in the Welty Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unaccounted for surface level changes as shown in the Welty Report from 1973 through 1980. Tank S-111 initially received waste from REDOX in 1952, and after April 1974, primarily received processed waste slurry from the 242-S Evaporator/Crystallizer and transferred supernatant waste to Tank S-102. From the FDNW review and comparisons of the Welty Report versus other daily records for Tank S-111, FDNW determined that the majority of the time, the Welty Report is consistent with daily records. Surface level decreases that occurred following saltwell pumping were identified as unaccounted for decreases in the Welty Report, however they were probably a continued settlement caused by saltwell pumping of the interstitial liquids. Because the flammable/trapped gas issue is linked to the unexplained increase in the surface level, FDNW recommends that all occurrence reports, concerning tank waste level increases or decreases from 1970 through 1980, be reevaluated for acceptability of the evaluation as to the root cause of the occurrence.

Brevick, C.H.; Gaddis, L.A.

1997-06-23T23:59:59.000Z

162

Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study  

SciTech Connect

Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

1992-07-01T23:59:59.000Z

163

Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study  

SciTech Connect

Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

1992-07-01T23:59:59.000Z

164

Stirling Engine Natural Gas Combustion Demonstration Program. Final report, October 1989-January 1991  

Science Conference Proceedings (OSTI)

Fueled on natural gas, the Stirling engine is an inherently clean, quiet, and efficient engine. With increasing environmental concern for air quality and the increasingly more stringent requirements for low engine exhaust emissions, the Stirling engine may be an attractive alternative to internal combustion (IC) engines. The study has demonstrated that ultra low emissions can be attained with a Stirling-engine-driven electric generator configured to burn natural gas. Combustion parameters were optimized to produce the lowest possible exhaust emissions for a flame-type combustor without compromising overall engine thermal efficiency. A market application survey and manufacturing cost analysis indicate that a market opportunity potentially exists in the volumes needed to economically manufacture a newly designed Stirling engine (Mod III) for stationary applications and hybrid vehicles. The translation of such potential markets into actual markets does, however, pose difficult challenges as substantial investments are required. Also, the general acceptance of a new engine type by purchasers requires a considerable amount of time.

Ernst, W.; Moryl, J.; Riecke, G.

1991-02-01T23:59:59.000Z

165

Radiolytic gas generation in plutonium contaminated waste materials  

DOE Green Energy (OSTI)

Many plutonium contaminated waste materials decompose into gaseous products because of exposure to alpha radiation. The gases generated (usually hydrogen) over long-storage periods may create hazardous conditions. To determine the extent of such hazards, knowing the gas generation yields is necessary. These yields were measured by contacting some common Rocky Flats Plant waste materials with plutonium and monitoring the enclosed atmospheres for extensive periods of time. The materials were Plexiglas, polyvinyl chloride, glove-box gloves, machining oil, carbon tetrachloride, chlorothene VG solvent, Kimwipes (dry and wet), polyethylene, Dowex-1 resin, and surgeon's gloves. Both /sup 239/Pu oxide and /sup 238/Pu oxide were used as radiation sources. The gas analyses were made by mass spectrometry and the results obtained were the total gas generation, the hydrogen generation, the oxygen consumption rate, and the gas composition over the entire storage period. Hydrogen was the major gas produced in most of the materials. The total gas yields varied from 0.71 to 16 cm/sup 3/ (standard temperature pressure) per day per curie of plutonium. The oxygen consumption rates varied from 0.0088 to 0.070 millimoles per day per gram of plutonium oxide-239 and from 0.0014 to 0.0051 millimoles per day per milligram /sup 238/Pu.

Kazanjian, A.R.

1976-10-29T23:59:59.000Z

166

Co-combustion of pellets from Soma lignite and waste dusts of furniture works  

Science Conference Proceedings (OSTI)

In this work, volatiles and char combustion behaviors of the fuel pellets prepared from a low quality lignite and the dusts of furniture works and their various blends were investigated in an experimental fixed bed combustion system through which air flowed by natural convection. Combustion data obtained for varied bed temperatures, mass of pellets, and blend compositions has showed that ignition times of the pellets decreased and volatiles combustion rates tended to increase with the burning temperature. It was concluded that some synergy had existed between lignite and lower ratios of furniture work dusts, which was indicated by a prompt effect on the volatiles combustion rates. Char combustion rates of blend pellets have depended predominantly on the amount of lignite in the blend. The amounts of combustion residues of the pellets were considerably higher than those calculated from individual ash contents of the raw materials and related to lignite ratio in the blends.

Deveci, N.D.; Yilgin, M.; Pehlivan, D. [Firat University, Elazig (Turkey). Faculty of Engineering

2008-07-01T23:59:59.000Z

167

Reducing Mercury Emissions from Municipal Solid Waste Combustion (Results of Investigations and Testing at the Camden Resource Recovery Facility)  

E-Print Network (OSTI)

technologies for mercury control for flue gases of Municipal Waste Combustors (MWCs) not only ecological hydrochloric acid (HCl) and elemental mercury (Hg") under oxidizing conditions of the off-gases downstream to the decreasing gas temperature, the elemental mercury is able to react with other flue gas components. The main

Columbia University

168

Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, April 1--June 30, 1992  

SciTech Connect

This quarterly technical progress report summarizes work completed during the Seventh Quarter of the First Budget Period, April 1 through June 30, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion will include the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/Pressurized Circulating Fluidized Bed Gas Source; Hot Gas Cleanup Units to mate to all gas streams. Combustion Gas Turbine; Fuel Cell and associated gas treatment; and Externally Fired Gas Turbine/Water Augmented Gas Turbine. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

Not Available

1992-12-01T23:59:59.000Z

169

Estimating retained gas volumes in the Hanford tanks using waste level measurements  

SciTech Connect

The Hanford site is home to 177 large, underground nuclear waste storage tanks. Safety and environmental concerns surround these tanks and their contents. One such concern is the propensity for the waste in these tanks to generate and trap flammable gases. This report focuses on understanding and improving the quality of retained gas volume estimates derived from tank waste level measurements. While direct measurements of gas volume are available for a small number of the Hanford tanks, the increasingly wide availability of tank waste level measurements provides an opportunity for less expensive (than direct gas volume measurement) assessment of gas hazard for the Hanford tanks. Retained gas in the tank waste is inferred from level measurements -- either long-term increase in the tank waste level, or fluctuations in tank waste level with atmospheric pressure changes. This report concentrates on the latter phenomena. As atmospheric pressure increases, the pressure on the gas in the tank waste increases, resulting in a level decrease (as long as the tank waste is {open_quotes}soft{close_quotes} enough). Tanks with waste levels exhibiting fluctuations inversely correlated with atmospheric pressure fluctuations were catalogued in an earlier study. Additionally, models incorporating ideal-gas law behavior and waste material properties have been proposed. These models explicitly relate the retained gas volume in the tank with the magnitude of the waste level fluctuations, dL/dP. This report describes how these models compare with the tank waste level measurements.

Whitney, P.D.; Chen, G.; Gauglitz, P.A.; Meyer, P.A.; Miller, N.E.

1997-09-01T23:59:59.000Z

170

Flammable gas tank waste level reconcilliation for 241-SX-102  

SciTech Connect

Fluoro Dynel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 24 1-S-1 1 1 (S-I 1 1, typical). The trapped gas evaluation document (ref 1) states that Tank SX-102 exceeds the 25% of the lower flammable limit (FL) criterion (ref 2), based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the ``Wallet Report`` is the basis for this letter report (ref 3). The Wallet Report is also a part of the trapped gas evaluation document criteria. The Wallet Report contains various tank information, including: physical information, status, levels, and dry wells, see Appendix A. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unacquainted for surface level rise. From 1973 through 1980, the Wallet Report tracked Tank S- 102 transfers and reported a net cumulative change of 19.95 in. This surface level increase is from an unknown source or is unacquainted for. Duke Engineering and Services Hanford (DASH) and Leached Martin Hanford Corporation (LMHC) are interested in determining the validity of the unexplained surface level changes reported in the 0611e Wallet Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unacquainted for surface level changes as shown in the Wallet Report from 1973 through 1980.

Brevick, C.H.; Gaddie, L.A.

1997-06-23T23:59:59.000Z

171

Plant growth response in experimental soilless mixes prepared from coal combustion products and organic waste materials  

Science Conference Proceedings (OSTI)

Large quantities of organic materials such as animal manures, yard trimmings, and biosolids are produced each year. Beneficial use options for them are often limited, and composting has been proposed as a way to better manage these organic materials. Similarly, burning of coal created 125 million tons of coal combustion products (CCP) in the United States in 2006. An estimated 53 million tons of CCP were reused, whereas the remainder was deposited in landfills. By combining CCP and composted organic materials (COM), we were able to create soilless plant growth mixes with physicochemical conditions that can support excellent plant growth. An additional benefit is the conservation of natural raw materials, such as peat, which is generally used for making soilless mixes. Experimental mixes were formulated by combining CCP and COM at ratios ranging from 2:8 to 8:2 (vol/vol), respectively. Water content at saturation for the created mixes was 63% to 72%, whereas for the commercial control, it was 77%. pH values for the best performing mixes ranged between 5.9 and 6.8. Electrical conductivity and concentrations of required plant nutrient were also within plant growth recommendations for container media. Significantly (P < 0.0001) higher plant biomass growth (7%-130%) was observed in the experimental mixes compared with a commercial mix. No additional fertilizers were provided during the experiment, and reduced fertilization costs can thus accrue as an added benefit to the grower. In summary, combining CCP and COM, derived from source materials often viewed as wastes, can create highly productive plant growth mixes.

Bardhan, S.; Watson, M.; Dick, W.A. [Ohio State University, Wooster, OH (United States)

2008-07-15T23:59:59.000Z

172

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

Science Conference Proceedings (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

173

Apparatus for incinerating hazardous waste  

DOE Patents (OSTI)

An apparatus is described for incinerating wastes, including an incinerator having a combustion chamber, a fluid-tight shell enclosing the combustion chamber, an afterburner, an off-gas particulate removal system and an emergency off-gas cooling system. The region between the inner surface of the shell and the outer surface of the combustion chamber forms a cavity. Air is supplied to the cavity and heated as it passes over the outer surface of the combustion chamber. Heated air is drawn from the cavity and mixed with fuel for input into the combustion chamber. The pressure in the cavity is maintained at least approximately 2.5 cm WC higher than the pressure in the combustion chamber. Gases cannot leak from the combustion chamber since the pressure outside the chamber (inside the cavity) is higher than the pressure inside the chamber. The apparatus can be used to treat any combustible wastes, including biological wastes, toxic materials, low level radioactive wastes, and mixed hazardous and low level transuranic wastes. 1 figure.

Chang, R.C.W.

1994-12-20T23:59:59.000Z

174

Apparatus for incinerating hazardous waste  

DOE Patents (OSTI)

An apparatus for incinerating wastes, including an incinerator having a combustion chamber, a fluidtight shell enclosing the combustion chamber, an afterburner, an off-gas particulate removal system and an emergency off-gas cooling system. The region between the inner surface of the shell and the outer surface of the combustion chamber forms a cavity. Air is supplied to the cavity and heated as it passes over the outer surface of the combustion chamber. Heated air is drawn from the cavity and mixed with fuel for input into the combustion chamber. The pressure in the cavity is maintained at least approximately 2.5 cm WC (about 1" WC) higher than the pressure in the combustion chamber. Gases cannot leak from the combustion chamber since the pressure outside the chamber (inside the cavity) is higher than the pressure inside the chamber. The apparatus can be used to treat any combustible wastes, including biological wastes, toxic materials, low level radioactive wastes, and mixed hazardous and low level transuranic wastes.

Chang, Robert C. W. (Martinez, GA)

1994-01-01T23:59:59.000Z

175

Off-gas characteristics of defense waste vitrification using liquid-fed Joule-heated ceramic melters  

DOE Green Energy (OSTI)

Off-gas and effluent characterization studies have been established as part of a PNL Liquid-Fed Ceramic Melter development program supporting the Savannah River Laboratory Defense Waste Processing Facility (SRL-DWPF). The objectives of these studies were to characterize the gaseous and airborne emission properties of liquid-fed joule-heated melters as a function of melter operational parameters and feed composition. All areas of off-gas interest and concern including effluent characterization, emission control, flow rate behavior and corrosion effects have been studied using alkaline and formic-acid based feed compositions. In addition, the behavioral patterns of gaseous emissions, the characteristics of melter-generated aerosols and the nature and magnitude of melter effluent losses have been established under a variety of feeding conditions with and without the use of auxiliary plenum heaters. The results of these studies have shown that particulate emissions are responsible for most radiologically important melter effluent losses. Melter-generated gases have been found to be potentially flammable as well as corrosive. Hydrogen and carbon monoxide present the greatest flammability hazard of the combustibles produced. Melter emissions of acidic volatile compounds of sulfur and the halogens have been responsible for extensive corrosion observed in melter plenums and in associated off-gas lines and processing equipment. The use of auxiliary plenum heating has had little effect upon melter off-gas characteristics other than reducing the concentrations of combustibles.

Goles, R.W.; Sevigny, G.J.

1983-09-01T23:59:59.000Z

176

Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery  

Science Conference Proceedings (OSTI)

Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25-207 kg CO{sub 2}-eq t{sup -1} rw. Within all process stages, the emission of fossil CO{sub 2} from the combustion of MSW was the main contributor (111-254 kg CO{sub 2}-eq t{sup -1} rw), while the substitution of electricity reduced the GHG emissions by 150-247 kg CO{sub 2}-eq t{sup -1} rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.

Yang Na [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Zhang Hua, E-mail: zhanghua_tj@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Chen Miao; Shao Liming [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); He Pinjing, E-mail: xhpjk@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China)

2012-12-15T23:59:59.000Z

177

Activation of catalyst for gas-phase combustion by electrochemical pretreatment  

SciTech Connect

The catalytic activity of an IrO{sub 2} catalyst used as an electrode on a YSZ solid electrolyte cell for the gas-phase combustion of ethylene can be increased by electrochemical pretreatment. Thus, the polarization of the IrO{sub 2} electrode during 90 min at 300 {micro}A, relative to a gold electrode, both deposited on YSZ, increases the activity of the IrO{sub 2} catalyst after current interruption by a factor of 3. In situ catalyst work function measurements showed that after the electrochemical pretreatment the IrO{sub 2} catalyst obtains higher work function. The activation of the catalyst is explained through the formation of a higher oxide, IrO{sub 2+{delta}}.

Nicole, J.; Wodiunig, S.; Comninellis, C. [Swiss Federal Inst. of Tech., Lausanne (Switzerland). Inst. of Chemical Engineering; Tsiplakides, D. [Univ. of Patras (Greece). Dept. of Chemical Engineering

1997-12-01T23:59:59.000Z

178

Air extraction and LBTU coal gas combustion in gas turbines for IGCC systems  

SciTech Connect

The primary objective of the cold flow experiments is to study the effects of air extraction from two sites in a heavy-frame gas turbine: (1) the engine wrapper or manholes and (2) the compressor/combustor prediffuser inlet. The experiments involve a scale model of components of a state-of-the-art, US made gas turbine between the compressor exit and the turbine inlet Specifically, the purpose is to observe and measure how air extraction affects the flow distribution around the combustor cans and the impingement cooling flow rates on transition pieces of the combustor. The experimental data should provide turbine manufacturers the information needed to determine their preferred air extraction site. The secondary objectives for the experiments are as follows: (1) to identify regions with high-pressure losses, (2) to develop a dam base which will validate computational fluid dynamic calculations, and (3) to establish an experimental facility which may be used to assist the US industry in improving the aerodynamic design of nonrotating components of a heavy-frame gas turbine.

Yang, Tah-teh; Agrawal, A.K.; Kapat, J.S.

1992-01-01T23:59:59.000Z

179

Thermal and radiolytic gas generation from Tank 241-S-102 waste  

SciTech Connect

This report summarizes progress in evaluating thermal and radiolytic rate parameters for flammable gas generation in Hanford single-shell tank wastes based on the results of laboratory tests using actual waste from Tank 241-S-102 (S-102). Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support Fluor Daniel Hanford (FDH) and its Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT) under subcontract to PNNL, using simulated wastes, and to studies being performed at Numatec Hanford Corporation (formerly Westinghouse Hanford Company) using actual wastes. The results of gas generation from Tank S-102 waste under thermal and radiolytic conditions are described in this report. The accurate measurement of gas generation rates in actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from Tank S-102, a waste tank listed as high priority by the Flammable Gas Safety Program due to its potential for flammable gas accumulation above the flammability limit.

King, C.M.; Pederson, L.R.; Bryan, S.A.

1997-07-01T23:59:59.000Z

180

In-Situ Oil Combustion: Processes Perpendicular to the Main Gas Flow Direction.  

E-Print Network (OSTI)

??Since most easy oil has been produced, there is an increased interest in enhanced oil recovery methods, e.g., in-situ oil combustion. Oil combustion in its… (more)

Achterbergh, C.P.W.N.

2009-01-01T23:59:59.000Z

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181

Computational Combustion  

DOE Green Energy (OSTI)

Progress in the field of computational combustion over the past 50 years is reviewed. Particular attention is given to those classes of models that are common to most system modeling efforts, including fluid dynamics, chemical kinetics, liquid sprays, and turbulent flame models. The developments in combustion modeling are placed into the time-dependent context of the accompanying exponential growth in computer capabilities and Moore's Law. Superimposed on this steady growth, the occasional sudden advances in modeling capabilities are identified and their impacts are discussed. Integration of submodels into system models for spark ignition, diesel and homogeneous charge, compression ignition engines, surface and catalytic combustion, pulse combustion, and detonations are described. Finally, the current state of combustion modeling is illustrated by descriptions of a very large jet lifted 3D turbulent hydrogen flame with direct numerical simulation and 3D large eddy simulations of practical gas burner combustion devices.

Westbrook, C K; Mizobuchi, Y; Poinsot, T J; Smith, P J; Warnatz, J

2004-08-26T23:59:59.000Z

182

Assessment of combustion and related issues in the DWPF and ITP waste tanks  

Science Conference Proceedings (OSTI)

This report presents a review of the safety analyses described in the DWPF Safety Analysis Report, the combustion analysis of the ITP Tanks 48 and 49, and presents conclusions drawn from interviews staff on issues related to accident analysis, in particular on issues related to combustion phenomena. The major objectives of this report are to clarify the issues related to the modes of combustion and expected loads on process vessels and structures and, in addition, to offer recommendations which would improve the defense-in-depth posture of the DWPF.

Ginsberg, T.

1994-04-01T23:59:59.000Z

183

Assessment of RANS-based turbulent combustion models for prediction of gas turbine emissions: turbulence model and reaction mechanism effects  

DOE Green Energy (OSTI)

The goal of this study is to assess current, commonly applied turbulence and combustion models with respect to their performance in gas-turbine combustion (GTC). Reynolds Averaged Navier-Stokes (RANS)-based turbulence and chemistry models are two primary factors influencing the uncertainty in predicting turbulent combustion characteristics, especially for GTC. RANS-based methods are the design tools of choice in the gas turbine industry due to the high computational costs of LES (Large Eddy Simulation). In this study, lean premixed combustion of methane was simulated using two different reduced mechanisms (ARM9 and ARM19) along with the Eddy Dissipation Concept (EDC) turbulent chemistry interaction model to calculate the CO and NOx emissions. The effect of turbulence models was assessed by considering two different models. Both of the models tested performed well in the prediction of temperature and major species profiles. Predicted values of NO emission profiles showed an average difference of ±5 ppm compared to experimental values. Computed intermediate species profiles showed large qualitative and quantitative errors when compared with the experimental data. These discrepancies, especially the intermediate species hydrogen, indicate the challenges these reduced mechanisms and turbulence models can present when modeling pollutant emissions from gas turbine combustors.

Nanduri, J.R.; Celik, I.B.; Strakey, P.A.; Parsons, D.R.

2007-10-01T23:59:59.000Z

184

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report  

DOE Green Energy (OSTI)

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOE's Environmental Management (EM) organizations to address gas generation concerns. This paper presents a ''program level'' roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

Luke, D.E. (INEEL); Hamp, S. (DOE-Albuquerque Operations Office)

2002-01-04T23:59:59.000Z

185

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report  

SciTech Connect

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOE's Environmental Management (EM) organizations to address gas generation concerns. This paper presents a ''program level'' roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

Luke, D.E. (INEEL); Hamp, S. (DOE-Albuquerque Operations Office)

2002-01-04T23:59:59.000Z

186

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report  

SciTech Connect

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen- containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOE’s Environmental Management (EM) organizations to address gas generation concerns. This paper presents a "program level" roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

Luke, Dale Elden; Hamp, S.

2002-02-01T23:59:59.000Z

187

Evolved Gas Analysis for High-alumina HLW (High Level Waste) Feed  

Science Conference Proceedings (OSTI)

Using the thermogravimetry coupled with gas chromatography-mass spectrometer, ... Tungstic Acid for Sorption of Uranium from Natural and Waste Waters and ...

188

Organic and Inorganic Hazardous Waste Stabilization Using Coal Combustion By-Product Materials  

Science Conference Proceedings (OSTI)

This report describes a laboratory investigation of four clean-coal by-products to stabilize organic and inorganic constituents of hazardous waste stream materials. The wastes included API separator sludge, metal oxide-hydroxide waste, metal plating sludge, and creosote-contaminated soil. Overall, the investigation showed that the high alkalinity of the by-products may cost-effectively stabilize the acidic components of hazardous waste.

1994-10-08T23:59:59.000Z

189

Annual Transuranic Waste Inventory Report - 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

contain both combustible and noncombustible waste items. Combustible waste may include wood, plastics, paper, and rags. Noncombustible waste items may include metals, glass,...

190

Combination gas producing and waste-water disposal well  

DOE Patents (OSTI)

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Malinchak, Raymond M. (McKeesport, PA)

1984-01-01T23:59:59.000Z

191

On use of CO{sub 2} chemiluminescence for combustion metrics in natural gas fired reciprocating engines.  

DOE Green Energy (OSTI)

Flame chemiluminescence is widely acknowledged to be an indicator of heat release rate in premixed turbulent flames that are representative of gas turbine combustion. Though heat release rate is an important metric for evaluating combustion strategies in reciprocating engine systems, its correlation with flame chemiluminescence is not well studied. To address this gap an experimental study was carried out in a single-cylinder natural gas fired reciprocating engine that could simulate turbocharged conditions with exhaust gas recirculation. Crank angle resolved spectra (266-795 nm) of flame luminosity were measured for various operational conditions by varying the ignition timing for MBT conditions and by holding the speed at 1800 rpm and Brake Mean effective Pressure (BMEP) at 12 bar. The effect of dilution on CO*{sub 2}chemiluminescence intensities was studied, by varying the global equivalence ratio (0.6-1.0) and by varying the exhaust gas recirculation rate. It was attempted to relate the measured chemiluminescence intensities to thermodynamic metrics of importance to engine research -- in-cylinder bulk gas temperature and heat release rate (HRR) calculated from measured cylinder pressure signals. The peak of the measured CO*{sub 2} chemiluminescence intensities coincided with peak pressures within {+-}2 CAD for all test conditions. For each combustion cycle, the peaks of heat release rate, spectral intensity and temperature occurred in that sequence, well separated temporally. The peak heat release rates preceded the peak chemiluminescent emissions by 3.8-9.5 CAD, whereas the peak temperatures trailed by 5.8-15.6 CAD. Such a temporal separation precludes correlations on a crank-angle resolved basis. However, the peak cycle heat release rates and to a lesser extent the peak cycle temperatures correlated well with the chemiluminescent emission from CO*{sub 2}. Such observations point towards the potential use of flame chemiluminescence to monitor peak bulk gas temperatures as well as peak heat release rates in natural gas fired reciprocating engines.

Gupta, S. B.; Bihari, B.; Biruduganti, M.; Sekar, R.; Zigan, J. (Energy Systems); (Cummins Technical Center)

2011-01-01T23:59:59.000Z

192

Gas Combustion Appliances: Validating VENT-II Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and  

NLE Websites -- All DOE Office Websites (Extended Search)

Predicting Backdrafting and Spillage for Natural-Draft Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray Environmental Energy Technologies Division April 2013 In Press as: Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray. 2013. "Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: A Validation of VENT-II". HVAC&R Research, DOI:10.1080/10789669.2013.771948 LBNL-6193E 2 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof,

193

JV Task 5 - Evaluation of Residual Oil Fly Ash As A Mercury Sorbent For Coal Combustion Flue Gas  

SciTech Connect

The mercury adsorption capacity of a residual oil fly ash (ROFA) sample collected form Florida Power and Light Company's Port Everglades Power Plant was evaluated using a bituminous coal combustion flue gas simulator and fixed-bed testing protocol. A size-segregated (>38 {micro}g) fraction of ROFA was ground to a fine powder and brominated to potentially enhance mercury capture. The ROFA and brominated-ROFA were ineffective in capturing or oxidizing the Hg{sup 0} present in a simulated bituminous coal combustion flue gas. In contrast, a commercially available DARCO{reg_sign} FGD initially adsorbed Hg{sup 0} for about an hour and then catalyzed Hg{sup 0} oxidation to produce Hg{sup 2+}. Apparently, the unburned carbon in ROFA needs to be more rigorously activated in order for it to effectively capture and/or oxidize Hg{sup 0}.

Robert Patton

2006-12-31T23:59:59.000Z

194

JV Task 5 - Evaluation of Residual Oil Fly Ash As A Mercury Sorbent For Coal Combustion Flue Gas  

SciTech Connect

The mercury adsorption capacity of a residual oil fly ash (ROFA) sample collected form Florida Power and Light Company's Port Everglades Power Plant was evaluated using a bituminous coal combustion flue gas simulator and fixed-bed testing protocol. A size-segregated (>38 {micro}g) fraction of ROFA was ground to a fine powder and brominated to potentially enhance mercury capture. The ROFA and brominated-ROFA were ineffective in capturing or oxidizing the Hg{sup 0} present in a simulated bituminous coal combustion flue gas. In contrast, a commercially available DARCO{reg_sign} FGD initially adsorbed Hg{sup 0} for about an hour and then catalyzed Hg{sup 0} oxidation to produce Hg{sup 2+}. Apparently, the unburned carbon in ROFA needs to be more rigorously activated in order for it to effectively capture and/or oxidize Hg{sup 0}.

Robert Patton

2006-12-31T23:59:59.000Z

195

Combustion of Illinois coals and chars with natural gas. [Quarterly] technical report, March 1, 1992--May 31, 1992  

Science Conference Proceedings (OSTI)

Combined combustion of coal and natural gas offers advantages compared to burning coal or natural gas alone. For example, low volatile coals or low volatile chars derived from treatment or gasification processes can be of limited use due to their poor flammability characteristics. However, the use of natural gas in conjunction with the solid fuel can provide the necessary ``volatiles`` to enhance the combustion. Additionally, natural gas provides a clean cofiring fuel source which can enhance the usefulness of coals with high sulfur content. Addition of natural gas may reduce SO{sub x} emissions through increased sulfur retention in the ash and reduce NO{sub x} emissions by varying local stoichiometry and temperature levels. This research program seeks to clarify the contributions and to identify the controlling mechanisms of coining natural gas with Illinois coal through studies of particle ignition, burning rates and ash characterization. The first two quarters focused on the ignition delay measurements and their analysis, along with the incorporation of particle porosity into the burning rate model. The emphasis of the third quarter was on a more detailed understanding of the burning rate process, as well as understanding of cofiring`s effects on sulfur retention. The contributions of particle burning area to the quantification of the particle burning mechanisms have been shown to be important and continue to be investigated. Ash samples for various methane concentrations under similar other conditions have shown positive trends in reducing S0{sub 2} emission through increased sulfur capture in the ash.

Buckius, R.O.; Peters, J.E.; Krier, H.

1992-10-01T23:59:59.000Z

196

A diffusion-kinetic model for pulverized-coal combustion and heat-and-mass transfer in a gas stream  

SciTech Connect

A diffusion-kinetic model for pulverized-coal combustion and heat-and-mass transfer in a gas stream is proposed, and the results of numerical simulation of the burnout dynamics of Kansk-Achinsk coals in the pulverized state at different treatment conditions and different model parameters are presented. The mathematical model describes the dynamics of thermochemical conversion of solid organic fuels with allowance for complex physicochemical phenomena of heat-and-mass exchange between coal particles and the gaseous environment.

E.A. Boiko; S.V. Pachkovskii [Polytechnic Institute, Federal University of Siberia, Krasnoyarsk (Russian Federation)

2008-12-15T23:59:59.000Z

197

SILICON CARBIDE MICRO-DEVICES FOR COMBUSTION GAS SENSING UNDER HARSH CONDITIONS  

DOE Green Energy (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen containing species in chemically reactive, high temperature environments. For these capacitive sensors we have determined that the optimum sensor operating point in terms of sensor lifetime and response time is at midgap. Detailed measurements of the oxide leakage current as a function of temperature were performed to investigate the high temperature reliability of the devices. In addition, robust metallization and electrical contacting techniques have been developed for device operation at elevated temperatures. To characterize the time response of the sensor responses in the millisecond range, a conceptually new apparatus has been built. Using laser induced fluorescence imaging techniques we have shown that the gas underneath the sensor can be completely exchanged with a time constant under 1 millisecond. Ultrahigh vacuum studies of the surface chemistry of the platinum gate have shown that sensor deactivation by adsorbed sulfur is a possible problem. Investigations on the chemical removal of sulfur by catalytic oxidation or reduction are continuing.

Ruby N. Ghosh; Peter Tobias; Roger G. Tobin

2004-10-01T23:59:59.000Z

198

Natural gas-fired combustion turbines are generally used to meet ...  

U.S. Energy Information Administration (EIA)

Combustion turbines in this article do not include combined-cycle units that operate at higher ... to operate than other types of power plants but can ...

199

Silicon Carbide Micro-devices for Combustion Gas Sensing under Harsh Conditions  

DOE Green Energy (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen-containing species in chemically reactive, high temperature environments. For fast and stable sensor response measurements, a gate activation process is required. Activation of all sensors took place by switching back and forth between oxidizing (1.0% oxygen in nitrogen) and reducing (10% hydrogen in nitrogen) gases for several hours at a sensor temperature {ge}620 C. All 52 devices on the sensor chip were activated simultaneously by flooding the entire chip with gas. The effects of activation on surface morphology and structure of Pt gates before and after activation were investigated. The optical images obtained from Pt gates demonstrated a clear transition from a smooth and shiny surface to a grainy and cloudy surface morphology. XRD scans collected from Pt gates suggest the presence of an amorphous layer and species other than Pt (111) after activation. The reliability of the gate insulator of our metal-oxide-SiC sensors for long-term device operation at 630 C was studied. We find that the dielectric is stable against breakdown due to electron injection from the substrate with gate leakage current densities as low at 5nA/cm{sup 2} at 630 C. We also designed and constructed a new nano-reactor capable of high gas flow rates at elevated pressure. Our reactor, which is a miniature version of an industrial reactor, is designed to heat the flowing gas up to 700 C. Measurements in ultrahigh vacuum demonstrated that hydrogen sulfide readily deposits sulfur on the gate surface, even at the very high hydrogen/hydrogen sulfide ratios (10{sup 3}-10{sup 5}) expected in applications. Once deposited, the sulfur adversely affects sensor response, and could not be removed by exposure to hydrogen at the temperatures and pressures accessible in the ultrahigh vacuum experiments. Oxygen exposures, however, were very effective at removing sulfur, and the device performance after sulfur removal was indistinguishable from performance before exposure to H{sub 2}S.

Ruby N. Ghosh; Reza Loloee; Roger G. Tobin; Yung Ho Kahng

2006-04-01T23:59:59.000Z

200

DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS  

SciTech Connect

This report provides results from the first year of this three-year project to develop dilution measurement technology for characterizing PM2.5 (particles with aerodynamic diameter smaller than 2.5 micrometers) and precursor emissions from stationary combustion sources used in oil, gas and power generation operations. Detailed emission rate and chemical speciation test results for a refinery gas-fired process heater and plans for cogeneration gas turbine tests and pilot-scale tests are presented. Tests were performed using a research dilution sampling apparatus and traditional EPA methods to compare PM2.5 mass and chemical speciation. Test plans are presented for a gas turbine facility that will be tested in the fourth quarter of 2002. A preliminary approach for pilot-scale tests is presented that will help define design constraints for a new dilution sampler design that is smaller, lighter, and less costly to use.

Glenn C. England; Stephanie Wien; Mingchih O. Chang

2002-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion  

SciTech Connect

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Fogash, Kevin

2010-09-30T23:59:59.000Z

202

Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion  

SciTech Connect

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Kevin Fogash

2010-09-30T23:59:59.000Z

203

Disposal Site Economic Model for Coal Combustion Residuals Under Proposed Federal Non-Hazardous Waste Regulations  

Science Conference Proceedings (OSTI)

Proposed federal coal combustion residual (CCR) disposal rules, along with anticipated regulations governing steam electric effluent guidelines, are expected to result in closure of many existing wet disposal facilities and construction of new landfills. Although each CCR project and each project site is unique, many of the major cost items associated with these projects should be reasonably consistent. This report provides baseline costs for four major CCR projects: existing impoundment closure, existin...

2012-08-06T23:59:59.000Z

204

Advanced Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Systems Systems Advanced Combustion Background Conventional coal-fired power plants utilize steam turbines to generate electricity, which operate at efficiencies of 35-37 percent. Operation at higher temperatures and pressures can lead to higher efficiencies, resulting in reduced fuel consumption and lower greenhouse gas emissions. Higher efficiency also reduces CO2 production for the same amount of energy produced, thereby facilitating a reduction in greenhouse gas emissions. When combined, oxy-combustion comes with an efficiency hit, so it will actually increase the amount of CO2 to be captured. But without so much N2 in the flue gas, it will be easier and perhaps more efficient to capture, utilize and sequester. NETL's Advanced Combustion Project and members of the NETL-Regional University

205

WASTE CHARACTERIZATION OF POLYMERIC COMPONENTS EXPOSED TO TRITIUM GAS  

Science Conference Proceedings (OSTI)

A recent independent review led to uncertainty about the technical basis for characterizing the residual amount of tritium in polymer components used in the Savannah River Site Tritium Facilities that are sent for waste disposal. A review of a paper published in the open literature firmly establishes the basis of the currently used characterization, 10 Ci/cc. Information provided in that paper about exposure experiments performed at the DOE Mound Laboratory allows the calculation of the currently used characterization. These experiments involved exposure of high density polyethylene (HD-PE) to initially 1 atm tritium gas. In addition, a review of recent research at the Savannah River Site not only further substantiates this characterization, but also establishes its use for ultra-high molecular weight polyethylene (UHMW-PE), polytetrafluoroethylene (PTFE, a trade name is Teflon{reg_sign}), and Vespel{reg_sign} polyimide. 10 Ci/cc tritium is a representative characterization for any type of polymer components exposed at ambient temperature and at approximately 1 atm. tritium gas.

Clark, E

2008-02-15T23:59:59.000Z

206

Cold End Inserts for Process Gas Waste Heat Boilers Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB)  

E-Print Network (OSTI)

Cold End Inserts for Process Gas Waste Heat Boilers Overview Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB) to cool process syngas. The gas enters satisfies all 3 design criteria. · Correlations relating our experimental results to a waste heat boiler

Demirel, Melik C.

207

An acoustic energy framework for predicting combustion- driven acoustic instabilities in premixed gas-turbines  

E-Print Network (OSTI)

of Engineering for Gas Turbines and Power, 2000. Vol. 122:of Engineering for Gas Turbines and Power, 2000. Vol. 122:in Lean Premixed Gas Turbine Combustors," Journal of

Ibrahim, Zuhair M. A.

2007-01-01T23:59:59.000Z

208

In situ parametric study of alkali release in pulverized coal combustion: Effects of operating conditions and gas composition  

Science Conference Proceedings (OSTI)

This work concerns a parametric study of alkali release in a lab-scale, pulverized coal combustor (drop tube reactor) at atmospheric pressure. Measurements were made at steady reactor conditions using excimer laser fragmentation fluorescence (ELIF) and with direct optical access to the flue gas pipe. In this way, absolute gas-phase alkali species could be determined in situ, continuously, with sub-ppb sensitivity, directly in the flue gas. A hard coal was fired in the range 1000-1300{sup o}C, for residence times in the range 3-5 s and for air numbers {lambda} (air/fuel ratios) from 1.15 to 1.50. In addition, the amount of chlorine, water vapor and sulfur, respectively, was increased in known amounts by controlled dosing of HCl, H{sub 2}O and SO{sub 2} into the combustion gas to determine effects of these components on release or capture of the alkali species. The experimental results are also compared with values calculated using ash/fuel analyses and sequential extraction to obtain a fuller picture of alkali release in pulverized fuel combustion. 27 refs., 7 figs., 1 tab.

H. Schuermann; P.B. Monkhouse; S. Unterberger; K.R.G. Hein [Universitaet Stuttgart, Stuttgart (Germany). Institut fuer Verfahrenstechnik und Dampfkesselwesen

2007-07-01T23:59:59.000Z

209

Silicon Carbide Micro-devices for Combustion Gas Sensing under Harsh Conditions  

DOE Green Energy (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device, Pt/SiO{sub 2}/SiC that can detect hydrogen-containing species in chemically reactive, high temperature (600 C) environments. We demonstrate that the device can be used as a hydrogen monitor in syngas applications of common interferants as well as sulfur and water vapor. These measurements were made in the Catalyst Screening Unit at NETL, Morgantown under atmospheric conditions. The sensor response to hydrogen gas at 350 C is 240 mV/decade, this is significantly higher than the device response to room temperature gas or that predicted from vacuum chamber studies. The enhanced catalytic activity of the platinum sensing film under energy plant operating conditions was investigated via AFM, x-ray diffraction, TEM and x-ray photoelectron spectroscopy. Our characterization indicated that exposure to high temperature gases significantly modifies the morphology of the Pt catalytic film and the Pt/SiO{sub 2} interfacial region, which we tentatively attribute to the enhanced hydrogen sensitivity of the sensing film. A model for the hydrogen/oxygen response of the SiC device under atmospheric conditions was developed. It is based on two independent phenomena: a chemically induced shift in the metal-semiconductor work function difference and the passivation/creation of charged states at the SiO{sub 2}-SiC interface. The optimum operating set point for the SiC sensor with respect to response time and long term reliability was determined to be close to mid-gap. Ultrahigh vacuum (UHV) techniques were used to investigate the effects of sulfur contamination on the Pt gate. Exposure to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20-600 times greater than the H2S level, rapidly coated the gate with a monolayer of sulfur. Although hydrogen exposure could not remove the adsorbed sulfur, oxygen was effective at removing sulfur with no evidence of irreversible changes in device behavior. The role of oxygen in the functioning of the SiC sensors was also investigated. All of the results are consistent with oxygen acting through its surface reactions with hydrogen, including the need for oxygen to reset the device to a fully hydrogen-depleted state and competition between hydrogen oxidation and hydrogen diffusion to metal/oxide interface sites. A strong sensor response to the unsaturated linear hydrocarbon propene (C{sub 3}H{sub 6}) was observed.

Ruby Ghosh; Reza Loloee; Roger Tobin

2008-09-30T23:59:59.000Z

210

Application of Laser Techniques in Combustion Environments of Relevance for Gas Turbine Studies.  

E-Print Network (OSTI)

??In the work presented in this thesis, different laser-based techniques were employed for measurements in different combustion devices. Laser-based techniques enable non-intrusive and in-situ measurements… (more)

Lantz, Andreas

2012-01-01T23:59:59.000Z

211

Utilization of coal mine ventilation exhaust as combustion air in gas-fired turbines for electric and/or mechanical power generation. Semi-annual topical report, June 1995--August 1995  

SciTech Connect

Methane emitted during underground coal mining operations is a hazard that is dealt with by diluting the methane with fresh air and exhausting the contaminated air to the atmosphere. Unfortunately this waste stream may contain more than 60% of the methane resource from the coal, and in the atmosphere the methane acts as a greenhouse gas with an effect about 24.5 times greater than CO{sub 2}. Though the waste stream is too dilute for normal recovery processes, it can be used as combustion air for a turbine-generator, thereby reducing the turbine fuel requirements while reducing emissions. Preliminary analysis indicates that such a system, built using standard equipment, is economically and environmentally attractive, and has potential for worldwide application.

1995-12-01T23:59:59.000Z

212

Development and Validation of Catalytic Combustion for Gas Turbines, Interim Report  

Science Conference Proceedings (OSTI)

The application of combustion turbines (CTs) for stationary power generation has grown considerably over the past decade and is projected to continue to grow in the future. Strong CT demand is based on several key product attributes associated with combustion turbines -- high efficiency in combined-cycle configurations; low capital, operating, and maintenance costs; high reliability and availability; shortened lead time for permitting and construction; and low emissions. While exhaust emissions from natu...

2000-11-11T23:59:59.000Z

213

Vehicle Technologies Office: Advanced Combustion Engines  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Combustion Advanced Combustion Engines to someone by E-mail Share Vehicle Technologies Office: Advanced Combustion Engines on Facebook Tweet about Vehicle Technologies Office: Advanced Combustion Engines on Twitter Bookmark Vehicle Technologies Office: Advanced Combustion Engines on Google Bookmark Vehicle Technologies Office: Advanced Combustion Engines on Delicious Rank Vehicle Technologies Office: Advanced Combustion Engines on Digg Find More places to share Vehicle Technologies Office: Advanced Combustion Engines on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Combustion Engines Emission Control Waste Heat Recovery Fuels & Lubricants Materials Technologies Advanced Combustion Engines

214

Vehicle Technologies Office: Combustion Engine Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Combustion Engine Combustion Engine Research to someone by E-mail Share Vehicle Technologies Office: Combustion Engine Research on Facebook Tweet about Vehicle Technologies Office: Combustion Engine Research on Twitter Bookmark Vehicle Technologies Office: Combustion Engine Research on Google Bookmark Vehicle Technologies Office: Combustion Engine Research on Delicious Rank Vehicle Technologies Office: Combustion Engine Research on Digg Find More places to share Vehicle Technologies Office: Combustion Engine Research on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Combustion Engines Emission Control Waste Heat Recovery Fuels & Lubricants Materials Technologies Combustion Engine Research

215

Combustion of EDS mid-distillate and refined shale-oil residual fuel in a gas turbine with large single-combustion chamber  

DOE Green Energy (OSTI)

The test fuels included a coal derived mid distillate recycle liquid from the EDS coal liquefaction process, produced by Exxon, and a hydroprocessed residual Paraho shale oil fraction originating from a US Government sponsored program. A BBC (Brown Boveri Co.) type 9 fully equipped 35 MW capacity gas turbine, located at BBC's test facilities near Basel, Switzerland, was utilized. The objective of the combustion test was to establish whether these alternate fuels can be fired in large single combustor turbines without deleterious effects to the turbine or environment. Nitrogen in the shale oil was on the order of 0.4 wt% while the EDS distillate contained slightly less than 10 wt% hydrogen. The test program entailed the firing of 600 barrels of each test fuel at varying turbine loads and a comparison of the results with those from a base case petroleum diesel fuel. Fuel bound nitrogen was not found to contribute significantly to NO/sub x/ emissions in contrast to other work reported earlier in subscale gas turbine tests. Water injection at 0.6 to 0.7 water-fo-fuel mass ratios was effective in meeting EPA requirements for NO/sub x/ emissions from the diesel, shale and coal derived fuels at full turbine load. Low fuel hydrogen content did not cause any operational or emission problems. Combustor wall temperature, the major problem with low hydrogen fuels, rose only slightly within acceptable limits.

Not Available

1983-01-01T23:59:59.000Z

216

Heat-pipe gas-combustion system endurance test for Stirling engine. Final report, May 1990-September 1990  

SciTech Connect

Stirling Thermal Motors, Inc., (STM) has been developing a general purpose Heat Pipe Gas Combustion System (HPGC) suitable for use with the STM4-120 Stirling engine. The HPGC consists of a parallel plate recuperative preheater, a finned heat pipe evaporator and a film cooled gas combustor. A principal component of the HPGC is the heat pipe evaporator which collects and distributes the liquid sodium over the heat transfer surfaces. The liquid sodium evaporates and flows to the condensers where it delivers its latent heat. The report presents test results of endurance tests run on a Gas-Fired Stirling Engine (GFSE). Tests on a dynamometer test stand yielded 67 hours of engine operation at power levels over 10 kW (13.5 hp) with 26 hours at power levels above 15 kW (20 hp). Total testing of the engine, including both motoring tests and engine operation, yielded 245 hours of engine run time.

Mahrle, P.

1990-12-01T23:59:59.000Z

217

Effects of Combustion-Induced Vortex Breakdown on Flashback Limits of Syngas-Fueled Gas Turbine Combustors  

DOE Green Energy (OSTI)

Turbine combustors of advanced power systems have goals to achieve very low pollutants emissions, fuel variability, and fuel flexibility. Future generation gas turbine combustors should tolerate fuel compositions ranging from natural gas to a broad range of syngas without sacrificing operational advantages and low emission characteristics. Additionally, current designs of advanced turbine combustors use various degrees of swirl and lean premixing for stabilizing flames and controlling high temperature NOx formation zones. However, issues of fuel variability and NOx control through premixing also bring a number of concerns, especially combustor flashback and flame blowout. Flashback is a combustion condition at which the flame propagates upstream against the gas stream into the burner tube. Flashback is a critical issue for premixed combustor designs, because it not only causes serious hardware damages but also increases pollutant emissions. In swirl stabilized lean premixed turbine combustors onset of flashback may occur due to (i) boundary layer flame propagation (critical velocity gradient), (ii) turbulent flame propagation in core flow, (iii) combustion instabilities, and (iv) upstream flame propagation induced by combustion induced vortex breakdown (CIVB). Flashback due to first two foregoing mechanisms is a topic of classical interest and has been studied extensively. Generally, analytical theories and experimental determinations of laminar and turbulent burning velocities model these mechanisms with sufficient precision for design usages. However, the swirling flow complicates the flashback processes in premixed combustions and the first two mechanisms inadequately describe the flashback propensity of most practical combustor designs. The presence of hydrogen in syngas significantly increases the potential for flashback. Due to high laminar burning velocity and low lean flammability limit, hydrogen tends to shift the combustor operating conditions towards flashback regime. Even a small amount of hydrogen in a fuel blend triggers the onset of flashback by altering the kinetics and thermophysical characteristics of the mixture. Additionally, the presence of hydrogen in the fuel mixture modifies the response of the flame to the global effects of stretch and preferential diffusion. Despite its immense importance in fuel flexible combustor design, little is known about the magnitude of fuel effects on CIVB induced flashback mechanism. Hence, this project investigates the effects of syngas compositions on flashback resulting from combustion induced vortex breakdown. The project uses controlled experiments and parametric modeling to understand the velocity field and flame interaction leading to CIVB driven flashback.

Ahsan Choudhuri

2011-03-31T23:59:59.000Z

218

CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS  

SciTech Connect

This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

2009-11-30T23:59:59.000Z

219

Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment  

SciTech Connect

Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost.

Nick Soelberg

2005-09-01T23:59:59.000Z

220

ESTIMATION OF RADIOLYTIC GAS GENERATION RATE FOR CYLINDRICAL RADIOACTIVE WASTE PACKAGES - APPLICATION TO SPENT ION EXCHANGE RESIN CONTAINERS  

DOE Green Energy (OSTI)

Radioactive waste packages containing water and/or organic substances have the potential to radiolytically generate hydrogen and other combustible gases. Typically, the radiolytic gas generation rate is estimated from the energy deposition rate and the radiolytic gas yield. Estimation of the energy deposition rate must take into account the contributions from all radionuclides. While the contributions from non-gamma emitting radionuclides are relatively easy to estimate, an average geometry factor must be computed to determine the contribution from gamma emitters. Hitherto, no satisfactory method existed for estimating the geometry factors for a cylindrical package. In the present study, a formulation was developed taking into account the effect of photon buildup. A prototype code, called PC-CAGE, was developed to numerically solve the integrals involved. Based on the selected dimensions for a cylinder, the specified waste material, the photon energy of interest and a value for either the absorption or attenuation coefficient, the code outputs values for point and average geometry factors. These can then be used to estimate the internal dose rate to the material in the cylinder and hence to calculate the radiolytic gas generation rate. Besides the ability to estimate the rates of radiolytic gas generation, PC-CAGE can also estimate the dose received by the container material. This is based on values for the point geometry factors at the surface of the cylinder. PC-CAGE was used to calculate geometry factors for a number of cylindrical geometries. Estimates for the absorbed dose rate in container material were also obtained. The results for Ontario Power Generation's 3 m3 resin containers indicate that about 80% of the source gamma energy is deposited internally. In general, the fraction of gamma energy deposited internally depends on the dimensions of the cylinder, the material within it and the photon energy; the fraction deposited increases with increasing dimensions of the cylinder and decreases with increasing photon energy.

Husain, A.; Lewis, Brent J.

2003-02-27T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

DISTRICT ENERGY SYSTEMS POWERED THROUGH THE COMBUSTION OF MUNICIPAL SOLID WASTE  

E-Print Network (OSTI)

.assure.org Biography: Mr. Tomberlin has 21 years of experience in the design of power generation facilities having & Brad Moorman Barlow Projects, Inc. 2000 Vermont Drive, Fort Collins, CO 80525 (970) 226-8557 info municipal solid waste (MSW) by 90%-95% creating energy in the form of steam and/or electricity

Columbia University

222

Fluidized bed combustion of pelletized biomass and waste-derived fuels  

SciTech Connect

The fluidized bed combustion of three pelletized biogenic fuels (sewage sludge, wood, and straw) has been investigated with a combination of experimental techniques. The fuels have been characterized from the standpoints of patterns and rates of fuel devolatilization and char burnout, extent of attrition and fragmentation, and their relevance to the fuel particle size distribution and the amount and size distribution of primary ash particles. Results highlight differences and similarities among the three fuels tested. The fuels were all characterized by limited primary fragmentation and relatively long devolatilization times, as compared with the time scale of particle dispersion away from the fuel feeding ports in practical FBC. Both features are favorable to effective lateral distribution of volatile matter across the combustor cross section. The three fuels exhibited distinctively different char conversion patterns. The high-ash pelletized sludge burned according to the shrinking core conversion pattern with negligible occurrence of secondary fragmentation. The low-ash pelletized wood burned according to the shrinking particle conversion pattern with extensive occurrence of secondary fragmentation. The medium-ash pelletized straw yielded char particles with a hollow structure, resembling big cenospheres, characterized by a coherent inorganic outer layer strong enough to prevent particle fragmentation. Inert bed particles were permanently attached to the hollow pellets as they were incorporated into ash melts. Carbon elutriation rates were very small for all the fuels tested. For pelletized sludge and straw, this was mostly due to the shielding effect of the coherent ash skeleton. For the wood pellet, carbon attrition was extensive, but was largely counterbalanced by effective afterburning due to the large intrinsic reactivity of attrited char fines. The impact of carbon attrition on combustion efficiency was negligible for all the fuels tested. The size distribution of primary ash particles liberated upon complete carbon burnoff largely reflected the combustion pattern of each fuel. Primary ash particles of size nearly equal to that of the parent fuel were generated upon complete burnoff of the pelletized sludge. Nonetheless, secondary attrition of primary ash from pelletized sludge is large, to the point where generation of fine ash would be extensive over the typical residence time of bed ash in fluidized bed combustors. Very few and relatively fine primary ash particles were released after complete burnoff of wood pellets. Primary ash particles remaining after complete burnoff of pelletized straw had sizes and shapes that were largely controlled by the occurrence of ash agglomeration phenomena. (author)

Chirone, R.; Scala, F.; Solimene, R. [Istituto di Ricerche sulla Combustione - C.N.R., Piazzale V. Tecchio 80, 80125 Naples (Italy); Salatino, P.; Urciuolo, M. [Dipartimento di Ingegneria Chimica - Universita degli Studi di Napoli Federico II, Piazzale V. Tecchio 80, 80125 Naples (Italy)

2008-10-15T23:59:59.000Z

223

Framework for managing wastes from oil and gas exploration and production (E&P) sites.  

Science Conference Proceedings (OSTI)

Oil and gas companies operate in many countries around the world. Their exploration and production (E&P) operations generate many kinds of waste that must be carefully and appropriately managed. Some of these wastes are inherently part of the E&P process; examples are drilling wastes and produced water. Other wastes are generic industrial wastes that are not unique to E&P activities, such as painting wastes and scrap metal. Still other wastes are associated with the presence of workers at the site; these include trash, food waste, and laundry wash water. In some host countries, mature environmental regulatory programs are in place that provide for various waste management options on the basis of the characteristics of the wastes and the environmental settings of the sites. In other countries, the waste management requirements and authorized options are stringent, even though the infrastructure to meet the requirements may not be available yet. In some cases, regulations and/or waste management infrastructure do not exist at all. Companies operating in these countries can be confronted with limited and expensive waste management options.

Veil, J. A.; Puder, M. G.; Environmental Science Division

2007-09-15T23:59:59.000Z

224

Improved Hydrogen Gas Getters for TRU Waste -- Final Report  

DOE Green Energy (OSTI)

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB, characterized by the presence of carbon-carbon triple bonds. Carbon may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. In the presence of oxygen, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB has the needed binding rate and capacity for hydrogen that potentially could be generated in the TRUPACT II. Phases 1 and 2 of this project showed that uncoated DEB performed satisfactorily in lab scale tests. Based upon these results, Phase 3, the final project phase, included larger scale testing. Test vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and a payload of seven 55-gallon drums. The tests were run with an atmosphere of air for 63.9 days at ambient temperature (15-27°C) and a scaled hydrogen generation rate of 2.60E-07 moles per second (0.35 cc/min). A second type of getter known as VEI, a proprietary polymer hydrogen getter characterized by carbon-carbon double bonds, was also tested in Phase 3. Hydrogen was successfully “gettered” by both getter systems. Hydrogen concentrations remained below 5 vol% (in air) for the duration of the tests. However, catalytic reaction of hydrogen with carbon triple or double bonds in the getter materials did not take place. Instead, catalytic recombination was the predominant gettering mechanism in both getter materials as evidenced by (1) consumption of oxygen in the belljars, (2) production of free water in the belljars, and (3) absence of chemical changes in both getter materials as shown by nuclear magnetic resonance spectra.

Mark Stone; Michael Benson; Christopher Orme; Thomas Luther; Eric Peterson

2005-09-01T23:59:59.000Z

225

Scaled Testing of Hydrogen Gas Getters for Transuranic Waste  

SciTech Connect

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage and shipment containers. Hydrogen forms a flammable mixture with air over a wide range of concentrations (5% to 75%), and very low energy is needed to ignite hydrogen-air mixtures. For these reasons, the concentration of hydrogen in waste shipment containers (Transuranic Package Transporter-II or TRUPACT-II containers) needs to remain below the lower explosion limit of hydrogen in air (5 vol%). Accident scenarios and the resulting safety analysis require that this limit not be exceeded. The use of 'hydrogen getters' is being investigated as a way to prevent the build up of hydrogen in TRUPACT-II containers. Preferred getters are solid materials that scavenge hydrogen from the gas phase and chemically and irreversibly bind it into the solid state. In this study, two getter systems are evaluated: a) 1,4-bis (phenylethynyl)benzene or DEB, characterized by the presence of carbon-carbon triple bonds; and b) a proprietary polymer hydrogen getter, VEI or TruGetter, characterized by carbon-carbon double bonds. Carbon in both getter types may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. With oxygen present, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB and VEI performed satisfactorily in lab scale tests using small test volumes (ml-scale), high hydrogen generation rates, and short time spans of hours to days. The purpose of this study is to evaluate whether DEB and VEI perform satisfactorily in actual drum-scale tests with realistic hydrogen generation rates and time frames. The two getter systems were evaluated in test vessels comprised of a Gas Generation Test Program-style bell-jar and a drum equipped with a composite drum filter. The vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and volume of a payload of seven 55-gallon drums. The tests were conducted in an atmosphere of air for 60 days at ambient temperature (15 to 27 deg. C) and a scaled hydrogen generation rate of 2.60 E-07 moles hydrogen per second (0.35 cc/min). Hydrogen was successfully 'gettered' by both systems. Hydrogen concentrations remained below 5 vol% (in air) for the duration of the tests. However, catalytic reaction of hydrogen with carbon triple or double bonds in the getter materials did not take place. Instead, catalytic recombination was the predominant mechanism in both getters as evidenced by 1) consumption of oxygen in the bell-jars; 2) production of free water in the bell-jars; and 3) absence of chemical changes in both getters as shown by NMR spectra. (authors)

Kaszuba, J.; Mroz, E.; Haga, M.; Hollis, W. K. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico, 87545 (United States); Peterson, E.; Stone, M.; Orme, C.; Luther, T.; Benson, M. [Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-2208 (United States)

2006-07-01T23:59:59.000Z

226

Developing and Implementing a Company-Wide Waste Accounting System at Public Service Electric & Gas  

Science Conference Proceedings (OSTI)

Waste accounting systems will enable utilities to track their recycling, reuse, and prevention efforts. This manual describes the implementation of EPRI's waste accounting method in support of Public Service Electric & Gas Company's pollution prevention efforts. This method provided a means for organizing information from many facilities, transmitting regular performance reports to facility personnel and management, and identifying opportunities for improving pollution prevention performance.

1998-05-04T23:59:59.000Z

227

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending December 31, 1995  

DOE Green Energy (OSTI)

The objective of this project is to demonstrate that cocombustion of municipal solid waste and oil shale can reduce emissions of gaseous pollutants (SO{sub 2} and HCl) to acceptable levels. Tests in 6- and 15-inch units showed that the oil shale absorbs acid gas pollutants and produces an ash which could be, at the least, disposed of in a normal landfill. Further analysis of the results are underway to estimate scale-up to commercial size. Additional work will be done to evaluate the cementitious properties of oil shale ash.

NONE

1996-01-01T23:59:59.000Z

228

Field Evaluation of the Comanagement of Utility Low-Volume Wastes With High-Volume Coal Combustion By-Products: LS Site  

Science Conference Proceedings (OSTI)

The electric power industry has historically comanaged low-volume wastes with high-volume by-products as a cost-effective means of disposal. This report documents an investigation into the effects of comanagement of low-volume wastes with high-volume coal combustion by-products at the LS site. This is one of 14 sites investigated by EPRI to provide background information to the Environmental Protection Agency (EPA) for the 2000 Regulatory Determination on comanagement under the Resource Conservation and ...

2007-06-18T23:59:59.000Z

229

Field Evaluation of the Comanagement of Utility Low-Volume Wastes with High-Volume Coal Combustion By-Products: HA Site  

Science Conference Proceedings (OSTI)

Typically, utilities comanage some or all of their low-volume wastes with their high-volume by-products in disposal facilities. This report presents the results of a field study of comanagement of coal combustion by-products at a utility-owned impoundment in the midwestern United States (HA site). The findings from this research provided technical information for use in a study of comanagement practices by the U.S. Environmental Protection Agency (EPA).

2000-10-30T23:59:59.000Z

230

Field Evaluation of the Comanagement of Utility Low-Volume Wastes With High-Volume Coal Combustion By-Products: CL Site  

Science Conference Proceedings (OSTI)

This report presents the results of a field study of comanagement of coal combustion by-products at a utility disposal impoundment in the southeastern United States. The study was part of a multiyear effort by the Electric Power Research Institute (EPRI), in cooperation with the Utility Solid Waste Activities Group (USWAG) and individual utility companies, to characterize utility comanagement practices and collect and analyze a comprehensive set of data pertinent to the environmental effects of those pra...

1997-12-09T23:59:59.000Z

231

Field Evaluation of the Comanagement of Utility Low-Volume Wastes with High-Volume Coal Combustion By-Products: MO Site  

Science Conference Proceedings (OSTI)

This report documents an investigation into the effects of comanagement of low-volume wastes with high-volume coal combustion by-products at the MO site. The MO site is one of 14 investigated by EPRI to provide background information to the United States Environmental Protection Agency (EPA) for the 2000 Regulatory Determination on comanagement under the Resource Conservation and Recovery Act (RCRA).

2003-09-29T23:59:59.000Z

232

Denitrification of combustion gases. [Patent application  

DOE Patents (OSTI)

A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

Yang, R.T.

1980-10-09T23:59:59.000Z

233

THE ECONOMICS OF ENERGY RECOVERY FROM INDUSTRIAL WASTE INCINERATION  

E-Print Network (OSTI)

re covery system or heat exchanger is to lower the gas temperature as a means of extracting energy GAS I IN t system to be responsive. In all probability a pre heated combustion chamber +·· .. ...,. .... + .. . ·- - + + ·· .. J. J. +. ". · · ..l- f. .. , STACK FIG.10 WASTE GAS INCINERATOR WITH HEAT EXCHANGER FOR OIL HEATING

Columbia University

234

Control methods and valve arrangement for start-up and shutdown of pressurized combustion and gasification systems integrated with a gas turbine  

DOE Patents (OSTI)

A power plant having a system for converting coal to power in a gas turbine comprises a coal fed pressurized circulating bed for converting coal to pressurized gases, a gas turbine having a compressor for pressurizing air for the pressurized circulating bed and expander for receiving and expanding hot combustion gases for powering a generator, a first fast acting valve for controlling the pressurized air, a second fast acting valve means for controlling pressurized gas from the compressor to the expander.

Provol, Steve J. (Carlsbad, CA); Russell, David B. (San Diego, CA); Isaksson, Matti J. (Karhula, FI)

1994-01-01T23:59:59.000Z

235

Modeling Gas Phase RDX Combustion with Intrinsic Low Dimensional Manifolds 1 Sandeep Singh2  

E-Print Network (OSTI)

, "Automatically Simplified Chemical Kinetics and Molec- ular Transport and Its Applications in Premixed and Non systematically reduce chemical kinetic models in such a way that consistency with full model equations is 1, "Using CSP to Understand Complex Chemical Kinetics," Combustion Science and Technology, Vol. 89, pp. 375

236

Development of a dynamic simulator for a natural gas combined cycle (NGCC) power plant with post-combustion carbon capture  

Science Conference Proceedings (OSTI)

The AVESTAR Center located at the U.S. Department of Energy’s National Energy Technology Laboratory and West Virginia University is a world-class research and training environment dedicated to using dynamic process simulation as a tool for advancing the safe, efficient and reliable operation of clean energy plants with CO{sub 2} capture. The AVESTAR Center was launched with a high-fidelity dynamic simulator for an Integrated Gasification Combined Cycle (IGCC) power plant with pre-combustion carbon capture. The IGCC dynamic simulator offers full-scope Operator Training Simulator (OTS) Human Machine Interface (HMI) graphics for realistic, real-time control room operation and is integrated with a 3D virtual Immersive Training Simulator (ITS), thus allowing joint control room and field operator training. The IGCC OTS/ITS solution combines a “gasification with CO{sub 2} capture” process simulator with a “combined cycle” power simulator into a single high-performance dynamic simulation framework. This presentation will describe progress on the development of a natural gas combined cycle (NGCC) dynamic simulator based on the syngas-fired combined cycle portion of AVESTAR’s IGCC dynamic simulator. The 574 MW gross NGCC power plant design consisting of two advanced F-class gas turbines, two heat recovery steam generators (HRSGs), and a steam turbine in a multi-shaft 2x2x1 configuration will be reviewed. Plans for integrating a post-combustion carbon capture system will also be discussed.

Liese, E.; Zitney, S.

2012-01-01T23:59:59.000Z

237

Low Temperature Combustion using nitrogen enrichment to mitigate nox from large bore natural gas-filled engines.  

DOE Green Energy (OSTI)

Low Temperature Combustion (LTC) is identified as one of the pathways to meet the mandatory ultra low NOx emissions levels set by regulatory agencies. This phenomenon can be realized by utilizing various advanced combustion control strategies. The present work discusses nitrogen enrichment using an Air Separation Membrane (ASM) as a better alternative to the mature Exhaust Gas Re-circulation (EGR) technique currently in use. A 70% NOx reduction was realized with a moderate 2% nitrogen enrichment while maintaining power density and simultaneously improving Fuel Conversion Efficiency (FCE). The maximum acceptable Nitrogen Enriched Air (NEA) in a single cylinder spark ignited natural gas engine was investigated in this paper. Any enrichment beyond this level degraded engine performance both in terms of power density and FCE, and unburned hydrocarbon (UHC) emissions. The effect of ignition timing was also studied with and without N2 enrichment. Finally, lean burn versus stoichiometric operation utilizing NEA was compared. Analysis showed that lean burn operation along with NEA is one of the effective pathways for realizing better FCE and lower NOx emissions.

Biruduganti, M. S.; Gupta, S. B.; Sekar, R. R. (Energy Systems)

2008-01-01T23:59:59.000Z

238

Sources of heavy metal contamination in Swedish wood waste used for combustion  

SciTech Connect

In this paper, wood waste (RWW) recovered for heat production in Sweden was studied. Previous research has concluded that RWW contains elevated amounts of heavy metals, causing environmental problems during waste management. This study extends previous work on RWW by analysing which pollution sources cause this contamination. Using existing data on the metal contents in various materials, and the amounts of these materials in RWW, the share of the elevated amounts of metals in RWW that these materials explain was quantified. Six different materials occurring in RWW were studied and the results show that they explain from 70% to 100% of the amounts of arsenic, chromium, lead, copper and zinc in RWW. The most important materials contributing to contamination of RWW are surface-treated wood, industrial preservative-treated wood, plastic and galvanised fastening systems. These findings enable the development and evaluation of strategies aiming to decrease pollution and resource loss from handling RWW. It is argued that source separation and measures taken further downstream from the generation site, such as treatment, need to be combined to substantially decrease the amount of heavy metals in RWW.

Krook, J. [Department of Mechanical Engineering, Linkoeping University, SE-581 83 Linkoeping (Sweden)]. E-mail: joakr@ikp.liu.se; Martensson, A. [Department of Mechanical Engineering, Linkoeping University, SE-581 83 Linkoeping (Sweden); Eklund, M. [Department of Mechanical Engineering, Linkoeping University, SE-581 83 Linkoeping (Sweden)

2006-07-01T23:59:59.000Z

239

Engineering study - alternatives for SHMS high temperature/moisture gas sample conditioners for the aging waste facility  

SciTech Connect

The Standard Hydrogen Monitoring Systems have been experiencing high temperature/moisture problems with gas samples from the Aging Waste Tanks. These moist hot gas samples have stopped the operation of the SHMS units on tanks AZ-101, AZ-102, and AY-102. This study looks at alternatives for gas sample conditioners for the Aging Waste Facility.

THOMPSON, J.F.

1999-06-02T23:59:59.000Z

240

Control of Gas Emission during Pyrolysis of Waste Printed Wiring ...  

Science Conference Proceedings (OSTI)

Moreover, the possibility of controlling toxic exhaust gases and recovering ... Chemical Changes and Surface Properties of Carbonated Waste Cement ... Flux for Basic Oxygen Steel Making Using Waste Oxides of Steel Plant ... Heat Treatment of Black Dross for the Production of a Value Added Material - A Preliminary Study.

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Risk analysis of highly combustible gas storage, supply, and distribution systems in PWR plants  

DOE Green Energy (OSTI)

This report presents the evaluation of the potential safety concerns for pressurized water reactors (PWRs) identified in Generic Safety Issue 106, Piping and the Use of Highly Combustible Gases in Vital Areas. A Westinghouse four-loop PWR plant was analyzed for the risk due to the use of combustible gases (predominantly hydrogen) within the plant. The analysis evaluated an actual hydrogen distribution configuration and conducted several sensitivity studies to determine the potential variability among PWRs. The sensitivity studies were based on hydrogen and safety-related equipment configurations observed at other PWRs within the United States. Several options for improving the hydrogen distribution system design were identified and evaluated for their effect on risk and core damage frequency. A cost/benefit analysis was performed to determine whether alternatives considered were justifiable based on the safety improvement and economics of each possible improvement.

Simion, G.P. [Science Applications International Corp., Albuquerque, NM (United States); VanHorn, R.L.; Smith, C.L.; Bickel, J.H.; Sattison, M.B. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Bulmahn, K.D. [SCIENTECH, Inc., Idaho Falls, ID (United States)

1993-06-01T23:59:59.000Z

242

Ultra-low emissions gas turbine combustion system program. Progress report, July 1, 1993--February 28, 1994  

SciTech Connect

The Santa Barbara County Air Pollution Control District (SBCAPCD) has arranged a consortium to develop ultra-low emissions combustor technology applicable to gas turbines. The goal of the program is to develop and demonstrate a safe, efficient, and cost-effective method to meet a 9 ppmv NO{sub x} emission limit for gas turbines. Currently this emission limit can only be met with the selective catalytic reduction (SCR) technology (a post combustion cleanup process that is capital intensive and maintenance intensive). In coordination with a comprehensive technical advisory committee, SBCAPCD has evaluated different potential low emissions technologies and decided upon a lean premix approach to retrofit existing turbines and to integrate with new engines. This technology will provide a low cost alternative to the expensive controls and will substantially reduce NO{sub x} emissions from gas turbines. The design, fabrication and testing of the ultra-low NO{sub x} combustor system is currently being performed by Allison Gas Turbine Division, General Motors Corporation. This project continues to be overseen by a technical advisory committee to ensure timely and cost-effective product delivery.

Talwar, M.

1994-02-01T23:59:59.000Z

243

NETL: Combustion Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Combustion Technology (June 15-16, 1999) Animal Waste Remediation Roundtable PDF-78KB Advanced Coal-Based Power and Environmental Systems '98 Conference (July 21-23, 1998)...

244

An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors  

SciTech Connect

This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

Townsend, Aaron K., E-mail: aarontownsend@utexas.edu [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States); Webber, Michael E. [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States)

2012-07-15T23:59:59.000Z

245

An Engineering and Economic Evaluation of Post-Combustion CO2 Capture for Natural Gas-Fired Combined-Cycle Power Plants  

Science Conference Proceedings (OSTI)

This report presents an Electric Power Research Institute (EPRI) assessment on the technical feasibility, performance, and associated costs of applying post-combustion carbon dioxide (CO2) capture technology to a natural gas–fired combined-cycle (NGCC) power station.

2012-03-23T23:59:59.000Z

246

EXPERIMENTAL EVALUATION OF THE COMBUSTION HAZARD TO THE EXPERIMENTAL GAS- COOLED REACTOR-PRELIMINARY BURNING RIG EXPERIMENTS  

SciTech Connect

>An assembly was constructed which simulated the moderator coolant annulus in the Experimental Gas-Cooled Reactor. This assembly was preheated to various temperatures and air was passed through the coolant annulus. Under certain conditions it was demonstrated that self-sustained combustion of the graphite could occur. Rates of temperature rise were generally less than 1 deg C/ min until the graphite temperature exceeded 700 deg C and then rise rates became very high. In these cxperimcnts, the assembly was not operated in such a manner as to give ignition temperatures eharaeteristic of the EGCR. These tests were designed only to investigate the effects of changing such parameters as the rate of coolant flow, air humidity, prior oxidation on the graphite, and air inlet temperature. A later series of experiments to more closely duplicate the EGCR operating conditions was completed and will be reported in a second report, HW- 71182. (auth)

Dahl, R.E.

1961-11-01T23:59:59.000Z

247

A computer model of gas generation and transport within TRU waste drums  

DOE Green Energy (OSTI)

A computer model has been developed to predict radiolytic gas generation and transport within Transuranic (TRU) waste drums and surrounding enclosures. Gas generation from the radiolytic decomposition of organic material contaminated with plutonium is modeled and the concentrations of gas throughout the waste drum and enclosures are determined using a diffusional transport model. The model accurately reproduces experimentally measured gas concentrations. With polyethylene waste in unvented drums, the model predicts that the concentration of hydrogen gas can exceed 4 mole percent (lower flammable limit) with only about 5 curies of plutonium. If the drum liner is punctured and an unrestricted 0.75-in. carbon composite filter vent is installed in the drum lid, the plutonium loading can be increased to 240 Ci without generating flammable gas mixtures. Larger diameter filters can be used to increase the curie loading. The model has been used to show that shipments of 1000 Ci of plutonium-238 contaminated waste from Savannah River to the WIPP site are feasible using the TRUPACT shipping container. 10 refs., 17 figs., 6 tabs.

Smith, F.G. III

1988-06-01T23:59:59.000Z

248

Natural Gas Variability In California: Environmental Impacts And Device Performance Combustion Modeling of Pollutant Emissions From a Residential Cooking Range  

Science Conference Proceedings (OSTI)

As part of a larger study of liquefied natural gas impacts on device performance and pollutant emissions for existing equipment in California, this report describes a cmoputer modeling study of a partially premixed flame issueing from a single cooktop burner port. The model consisted of a reactive computational fluid dynamics three-dimensional spatial grid and a 71-species chemical mechanism with propane combustion capability. Simulations were conducted with a simplified fuel mixture containing methane, ethane, and propane in proportions that yield properties similar to fuels distributed throughout much of California now and in recent years (baseline fuel), as well as with two variations of simulated liquefied natural gas blends. A variety of simulations were conducted with baseline fuel to explore the effect of several key parameters on pollutant formation and other flame characteristics. Simulations started with fuel and air issuing through the burner port, igniting, and continuing until the flame was steady with time. Conditions at this point were analyzed to understand fuel, secondary air and reaction product flows, regions of pollutant formation, and exhaust concentrations of carbon monoxide, nitric oxide and formaldehyde. A sensitivity study was conducted, varying the inflow parameters of this baseline gs about real-world operating conditions. Flame properties responded as expected from reactive flow theory. In the simulation, carbon monoxide levels were influenced more by the mixture's inflow velocity than by the gas-to-air ratio in the mixture issuing from the inflow port. Additional simulations were executed at two inflow conditions - high heat release and medium heat release - to examine the impact of replacing the baseline gas with two mixtures representative of liquefied natural gas. Flame properties and pollutant generation rates were very similar among the three fuel mixtures.

Tonse, S. R.; Singer, B. C.

2011-07-01T23:59:59.000Z

249

Alternatives for managing wastes from reactors and post-fission operations in the LWR fuel cycle. Volume 2. Alternatives for waste treatment  

DOE Green Energy (OSTI)

Volume II of the five-volume report is devoted to the description of alternatives for waste treatment. The discussion is presented under the following section titles: fuel reprocessing modifications; high-level liquid waste solidification; treatment and immobilization of chop-leach fuel bundle residues; treatment of noncombustible solid wastes; treatment of combustible wastes; treatment of non-high-level liquid wastes; recovery of transuranics from non-high-level wastes; immobilization of miscellaneous non-high-level wastes; volatile radioisotope recovery and off-gas treatment; immobilization of volatile radioisotopes; retired facilities (decontamination and decommissioning); and, modification and use of selected fuel reprocessing wastes. (JGB)

Not Available

1976-05-01T23:59:59.000Z

250

The gas emissions variation of diesel engine from the combustion of used vegetable oils  

Science Conference Proceedings (OSTI)

Air pollution is any gas or particulate that originates from both natural and anthropogenic sources. Anthropogenic sources mostly related to burning different kinds of fuel for energy. Moreover, the exhaust from burning fuels in automobiles, homes and ... Keywords: biofuels, gas emissions, vegetable oil

Charalampos Arapatsakos; Dimitrios Christoforidis; Anastasios Karkanis

2009-02-01T23:59:59.000Z

251

Nanocomposite oxygen carriers for chemical-looping combustion of sulfur-contaminated synthesis gas  

Science Conference Proceedings (OSTI)

Chemical-looping combustion (CLC) is an emerging technology for clean combustion. We have previously demonstrated that the embedding of metal nanoparticles into a nanostructured ceramic matrix can result in unusually active and sinter-resistant nanocomposite oxygen carrier materials for CLC, which combine the high reactivity of metals with the high-temperature stability of ceramics. In the present study, we investigate the effect of H{sub 2}S in a typical coal-derived syngas on the stability and redox kinetics of Ni- and Cu-based nanostructured oxygen carriers. Both carriers show excellent structural stability and only mildly changed redox kinetics upon exposure to H{sub 2}S, despite a significant degree of sulfide formation. Surprisingly, partial sulfidation of the support results in a strong increase in oxygen carrier capacity in both cases because of the addition of a sulfide-sulfate cycle. Overall, the carriers show great potential for use in CLC of high-sulfur fuels. 21 refs., 13 figs. 1 tab.

Rahul D. Solunke; Goetz Veser [United States Department of Energy, Pittsburgh, PA (United States). National Energy Technology Laboratory

2009-09-15T23:59:59.000Z

252

Hydrogen Gas Generation Model for Fuel Based Remote Handled TRU Waste Stored at INEEL  

DOE Green Energy (OSTI)

The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

Soli T. Khericha; Rajiv N. Bhatt; Kevin Liekhus

2003-02-01T23:59:59.000Z

253

Boiler using combustible fluid  

DOE Patents (OSTI)

A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

Baumgartner, H.; Meier, J.G.

1974-07-03T23:59:59.000Z

254

Waste Heat Recovery from Industrial Smelting Exhaust Gas  

Science Conference Proceedings (OSTI)

For a cost efficient capture of more valuable heat (higher exergy), heat exchangers should operate on the exhaust gases upstream of the gas treatment plants.

255

Combustibles Alternativos  

NLE Websites -- All DOE Office Websites (Extended Search)

Combustibles Alternativos Dispensador de Combustible Alternativo Los combustibles alternativos estn derivados de otras fuentes adems del petrleo. Unos son producidos en el...

256

Reactive carbon from life support wastes for incinerator flue gas cleanup-System Testing  

DOE Green Energy (OSTI)

This paper presents the results from a joint research initiative between NASA Ames Research Center and Lawrence Berkeley National lab. The objective of the research is to produce activated carbon from life support wastes and to use the activated carbon to adsorb and chemically reduce the NO{sub x} and SO{sub 2} contained in incinerator flue gas. Inedible biomass waste from food production is the primary waste considered for conversion to activated carbon. Results to date show adsorption of both NO{sub x} and SO{sub 2} in activated carbon made from biomass. Conversion of adsorbed NO{sub x} to nitrogen has also been observed.

Fisher, John W.; Pisharody, Suresh; Moran, Mark J.; Wignarajah, Kanapathipillai; Xu, X.H.; Shi, Yao; Chang, Shih-Ger

2002-05-14T23:59:59.000Z

257

Use of flue gas desulphurisation (FGD) waste and rejected fly ash in waste stabilization/solidification systems  

Science Conference Proceedings (OSTI)

Stabilization/solidification (S/S) processes have been used as the final treatment step for hazardous wastes prior to land disposal. Fly ash is a by-product of coal-fired power generation; a significant proportion of this material is low-grade, reject material (rFA) that is unsuitable as a cement replacement due to its high carbon content and large particle size (>45 {mu}m). Flue gas desulphurization (FGD) sludge is a by-product from the air pollution control systems used in coal-fired power plants. The objective of this work was to investigate the performance of S/S waste binder systems containing these two waste materials (rFA and FGD). Strength tests show that cement-based waste forms with rFA and FGD replacement were suitable for disposal in landfills. The addition of an appropriate quantity of Ca(OH){sub 2} and FGD reduces the deleterious effect of heavy metals on strength development. Results of TCLP testing and the progressive TCLP test show that cement-rFA-Ca(OH){sub 2} systems with a range of FGD additions can form an effective S/S binder. The Leachability Index indicates that cement-based waste forms with rFA replacement were effective in reducing the mobility of heavy metals.

Qiao, X.C. [Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong (China); School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070 (China); Poon, C.S. [Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong (China)]. E-mail: cecspoon@polyu.edu.hk; Cheeseman, C. [Department of Civil and Environmental Engineering, Imperial College, London SW7 2BU (United Kingdom)

2006-07-01T23:59:59.000Z

258

Performance, Efficiency, and Emissions Characterization of Reciprocating Internal Combustion Engines Fueled with Hydrogen/Natural Gas Blends  

Science Conference Proceedings (OSTI)

Hydrogen is an attractive fuel source not only because it is abundant and renewable but also because it produces almost zero regulated emissions. Internal combustion engines fueled by compressed natural gas (CNG) are operated throughout a variety of industries in a number of mobile and stationary applications. While CNG engines offer many advantages over conventional gasoline and diesel combustion engines, CNG engine performance can be substantially improved in the lean operating region. Lean operation has a number of benefits, the most notable of which is reduced emissions. However, the extremely low flame propagation velocities of CNG greatly restrict the lean operating limits of CNG engines. Hydrogen, however, has a high flame speed and a wide operating limit that extends into the lean region. The addition of hydrogen to a CNG engine makes it a viable and economical method to significantly extend the lean operating limit and thereby improve performance and reduce emissions. Drawbacks of hydrogen as a fuel source, however, include lower power density due to a lower heating value per unit volume as compared to CNG, and susceptibility to pre-ignition and engine knock due to wide flammability limits and low minimum ignition energy. Combining hydrogen with CNG, however, overcomes the drawbacks inherent in each fuel type. Objectives of the current study were to evaluate the feasibility of using blends of hydrogen and natural gas as a fuel for conventional natural gas engines. The experiment and data analysis included evaluation of engine performance, efficiency, and emissions along with detailed in-cylinder measurements of key physical parameters. This provided a detailed knowledge base of the impact of using hydrogen/natural gas blends. A four-stroke, 4.2 L, V-6 naturally aspirated natural gas engine coupled to an eddy current dynamometer was used to measure the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions in a reciprocating four stroke cycle engine. The test matrix varied engine load and air-to-fuel ratio at throttle openings of 50% and 100% at equivalence ratios of 1.00 and 0.90 for hydrogen percentages of 10%, 20% and 30% by volume. In addition, tests were performed at 100% throttle opening, with an equivalence ratio of 0.98 and a hydrogen blend of 20% to further investigate CO emission variations. Data analysis indicated that the use of hydrogen/natural gas fuel blend penalizes the engine operation with a 1.5 to 2.0% decrease in torque, but provided up to a 36% reduction in CO, a 30% reduction in NOX, and a 5% increase in brake thermal efficiency. These results concur with previous results published in the open literature. Further reduction in emissions can be obtained by retarding the ignition timing.

Kirby S. Chapman; Amar Patil

2007-06-30T23:59:59.000Z

259

Gas generation from low-level radioactive waste: Concerns for disposal  

DOE Green Energy (OSTI)

The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

Siskind, B.

1992-01-01T23:59:59.000Z

260

Gas generation from low-level radioactive waste: Concerns for disposal  

DOE Green Energy (OSTI)

The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

Siskind, B.

1992-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

SILICON CARBIDE MICRO-DEVICES FOR COMBUSTION GAS SENSING UNDER HARSH CONDITIONS  

DOE Green Energy (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen containing species in chemically reactive, high temperature environments. Robust metallization and electrical contacting techniques have been developed for device operation at elevated temperatures. To characterize the time response of the sensor responses in the millisecond range, a conceptually new apparatus has been built. Software has been developed to cope with the requirements of fast sensor control and data recording. In addition user friendly software has been developed to facilitate use of the SiC sensors for industrial process control applications.

Ruby N. Ghosh; Peter Tobias; Roger G. Tobin

2004-04-01T23:59:59.000Z

262

An investigation of lean combustion in a natural gas-fueled spark-ignited engine  

SciTech Connect

The objective of this work was to investigate the performance and emission characteristics of natural gas in an original equipment manufacturer (OEM), light-duty, spark-ignited engine being operated in the lean fueling regime and compare the operation with gasoline fueling cases. Data were acquired for several operating conditions of speed, throttle position, air-fuel equivalence ratio, and spark timing for both fuels. Results showed that for stoichiometric fueling, with a naturally aspirated engine, a power loss of 10 to 15 percent can be expected for natural gas over gasoline fueling. For lean operation, however, power increases can be expected for equivalence ratios below about {phi} = 0.80 with natural gas fueling as compared to gasoline. Higher brake thermal efficiencies can also be expected with natural gas fueling with maximum brake torque (MBT) timings over the range of equivalence ratios investigated in this work. Coefficient of variation (COV) data based on the indicated mean effective pressure (IMEP) demonstrated that the engine is much less sensitive to equivalence ratio leaning for natural gas fueling as compared to gasoline cases. The lean limit for a COV of 10 percent was about {phi} = 0.72 for gasoline and {phi} = 0.63 for natural gas. Lean fueling resulted in significantly reduced NO{sub x} levels where a lower plateau for NO{sub x} concentrations was reached at {phi} near or below 0.70, which corresponded to about 220 ppm. For natural gas fueling, this corresponded to about 1.21 gm/kW-h. Finally, with MBT timings, relatively short heat release durations were obtained for lean fueling with natural gas compared to gasoline.

Gupta, M.; Bell, S.R.; Tillman, S.T. [Univ. of Alabama, Tuscaloosa, AL (United States). Dept. of Mechanical Engineering

1996-06-01T23:59:59.000Z

263

Microbial Gas Generation Under Expected Waste Isolation Pilot Plant Repository Conditions: Final Report  

Science Conference Proceedings (OSTI)

Gas generation from the microbial degradation of the organic constituents of transuranic (TRU) waste under conditions expected in the Waste Isolation Pilot Plant (WIPP) was investigated. The biodegradation of mixed cellulosic materials and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, hypalon, leaded hypalon, and neoprene) was examined. We evaluated the effects of environmental variables such as initial atmosphere (air or nitrogen), water content (humid ({approx}70% relative humidity, RH) and brine inundated), and nutrient amendments (nitogen phosphate, yeast extract, and excess nitrate) on microbial gas generation. Total gas production was determined by pressure measurement and carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) were analyzed by gas chromatography; cellulose degradation products in solution were analyzed by high-performance liquid chromatography. Microbial populations in the samples were determined by direct microscopy and molecular analysis. The results of this work are summarized.

Gillow, J.B.; Francis, A.

2011-07-01T23:59:59.000Z

264

A study of tritium in municipal solid waste leachate and gas  

Science Conference Proceedings (OSTI)

It has become increasingly clear in the last few years that the vast majority of municipal solid waste landfills produce leachate that contains elevated levels of tritium. The authors recently conducted a study of landfills in New York and New Jersey and found that the mean concentration of tritium in the leachate from ten municipal solid waste (MSW) landfills was 33,800 pCi/L with a peak value of 192,000 pCi/L. A 2003 study in California reported a mean tritium concentration of 99,000 pCi/L with a peak value of 304,000 pCi/L. Studies in Pennsylvania and the UK produced similar results. The USEPA MCL for tritium is 20,000 pCi/L. Tritium is also manifesting itself as landfill gas and landfill gas condensate. Landfill gas condensate samples from landfills in the UK and California were found to have tritium concentrations as high as 54,400 and 513,000 pCi/L, respectively. The tritium found in MSW leachate is believed to derive principally from gaseous tritium lighting devices used in some emergency exit signs, compasses, watches, and even novelty items, such as 'glow stick' key chains. This study reports the findings of recent surveys of leachate from a number of municipal solid waste landfills, both open and closed, from throughout the United States and Europe. The study evaluates the human health and ecological risks posed by elevated tritium levels in municipal solid waste leachate and landfill gas and the implications to their safe management. We also assess the potential risks posed to solid waste management facility workers exposed to tritium-containing waste materials in transfer stations and other solid waste management facilities. (authors)

Mutch Jr, R. D. [HydroQual, Inc., 1200 MacArthur Blvd., Mahwah, NJ 07430 (United States); Manhattan College, Riverdale, NY (United States); Columbia Univ., New York, NY (United States); Mahony, J. D. [HydroQual, Inc., 1200 MacArthur Blvd., Mahwah, NJ 07430 (United States); Manhattan College, Riverdale, NY (United States)

2008-07-15T23:59:59.000Z

265

Method and apparatus for reducing mixed waste  

DOE Patents (OSTI)

The present invention is a method and apparatus for in-can waste reduction. The method is mixing waste with combustible material prior to placing the waste into a waste reduction vessel. The combustible portion is ignited, thereby reducing combustible material to ash and non-combustible material to a slag. Further combustion or heating may be used to sinter or melt the ash. The apparatus is a waste reduction vessel having receiving canister connection means on a first end, and a waste/combustible mixture inlet on a second end. An oxygen supply is provided to support combustion of the combustible mixture.

Elliott, Michael L. (Kennewick, WA); Perez, Jr., Joseph M. (Richland, WA); Chapman, Chris C. (Richland, WA); Peters, Richard D. (Pasco, WA)

1995-01-01T23:59:59.000Z

266

Options and costs for offsite disposal of oil and gas exploration and production wastes.  

Science Conference Proceedings (OSTI)

In the United States, most of the exploration and production (E&P) wastes generated at onshore oil and gas wells are disposed of or otherwise managed at the well site. Certain types of wastes are not suitable for onsite management, and some well locations in sensitive environments cannot be used for onsite management. In these situations, operators must transport the wastes offsite for disposal. In 1997, Argonne National Laboratory (Argonne) prepared a report that identified offsite commercial disposal facilities in the United States. This information has since become outdated. Over the past year, Argonne has updated the study through contacts with state oil and gas agencies and commercial disposal companies. The new report, including an extensive database for more than 200 disposal facilities, provides an excellent reference for information about commercial disposal operations. This paper describes Argonne's report. The national study provides summaries of the types of offsite commercial disposal facilities found in each state. Data are presented by waste type and by disposal method. The categories of E&P wastes in the database include: contaminated soils, naturally occurring radioactive material (NORM), oil-based muds and cuttings, produced water, tank bottoms, and water-based muds and cuttings. The different waste management or disposal methods in the database involve: bioremediation, burial, salt cavern, discharge, evaporation, injection, land application, recycling, thermal treatment, and treatment. The database includes disposal costs for each facility. In the United States, most of the 18 billion barrels (bbl) of produced water, 149 million bbl of drilling wastes, and 21 million bbl of associated wastes generated at onshore oil and gas wells are disposed of or otherwise managed at the well site. However, under certain conditions, operators will seek offsite management options for these E&P wastes. Commercial disposal facilities are offsite businesses that accept and manage E&P wastes for a fee. Their services include waste management and disposal, transportation, cleaning of vehicles and tanks, disposal of wash water, and, in some cases, laboratory analysis. Commercial disposal facilities offer a suite of waste management methods and technologies.

Puder, M. G.; Veil, J. A.; Environmental Science Division

2007-01-01T23:59:59.000Z

267

Waste tank headspace gas and vapor characterization reference guide  

SciTech Connect

This document is to serve as a reference guide for gas and vapor sample results presented in tank characterization reports. It describes sampling equipment, devices, and protocols, and sample collection and analysis methods common to all vapor samples.

Huckaby, J.L.

1995-06-01T23:59:59.000Z

268

CATALYZED COMBUSTION IN A FLAT PLATE BOUNDARY LAYER I. EXPERIMENTAL MEASUREMENTS AND COMPARISON WITH NUMERICAL CALCULATIONS  

E-Print Network (OSTI)

l~ Roberts, "Catathermal Combustion: A New Process for Lm'l-significant gas phase combustion is induced by the presenceInternational) on Combustion (to be published), The

Robben, R.

2010-01-01T23:59:59.000Z

269

Test plan for headspace gas sampling of remote-handled transuranic waste containers at Los Alamos National Laboratory  

DOE Green Energy (OSTI)

Seventeen remote-handled (RH) transuranic (TRU) waste canisters currently are stored in vertical, underground shafts at Technical Area (TA)-54, Area G, at Los Alamos National Laboratory (LANL). These 17 RH TRU waste canisters are destined to be shipped to the Waste Isolation Pilot Plant (WIPP) for permanent disposal in the geologic repository. As the RH TRU canister is likely to be the final payload container prior to placement into the 72-B cask and shipment to the WIPP, these waste canisters provide a unique opportunity to ascertain representative flammable gas concentrations in packaged RH-TRU waste. Hydrogen, which is produced by the radiolytic decomposition of hydrogenous constituents in the waste matrix, is the primary flammable gas of concern with RH TRU waste. The primary objectives of the experiment that is described by this test plan are to sample and analyze the waste canister headspace gases to determine the concentration of hydrogen in the headspace gas and to calculate the hydrogen gas generation rate for comparison to the applicable maximum allowable hydrogen generation rate (mole/sec) limits. It is a goal of this experiment to determine the headspace gas concentrations of other gases (e.g., oxygen, nitrogen, carbon dioxide, carbon monoxide, and volatile organic compounds (VOCs) with molecular weights less than 60 g/mole) that are produced by radiolysis or present when the waste was packaged. Additionally, the temperature, pressure, and flow rate of the headspace gas will be measured.

Field, L.R.; Villarreal, R. [Los Alamos National Lab., NM (United States)

1998-02-24T23:59:59.000Z

270

Assessment of chemical vulnerabilities in the Hanford high-level waste tanks  

SciTech Connect

The purpose of this report is to summarize results of relevant data (tank farm and laboratory) and analysis related to potential chemical vulnerabilities of the Hanford Site waste tanks. Potential chemical safety vulnerabilities examined include spontaneous runaway reactions, condensed phase waste combustibility, and tank headspace flammability. The major conclusions of the report are the following: Spontaneous runaway reactions are not credible; condensed phase combustion is not likely; and periodic releases of flammable gas can be mitigated by interim stabilization.

Meacham, J.E. [and others

1996-02-15T23:59:59.000Z

271

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING  

E-Print Network (OSTI)

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

272

Gas Releases During Saltcake Dissolution for Retrieval of Single-Shell Tank Waste  

DOE Green Energy (OSTI)

It is possible to retrieve a large fraction of soluble waste from the Hanford single-shell waste tanks (SST) by dissolving it with water. This retrieval method will be demonstrated in U-107 and S-112 in the next few years. If saltcake dissolution proves practical and effective, many of the saltcake SSTs may be retrieved by this method. Many of the SSTs retain a large volume of flammable gas that will be released into the tank headspace as the waste dissolves. This report describes the physical processes that control dissolution and gas release. Calculation results are shown describing the headspace hydrogen concentration transient during dissolution. The observed spontaneous and induced gas releases from SSTs is summarized and the dissolution of the crust layer in SY-101 is discussed as a recent example of full-scale dissolution of saltcake containing a very large volume of retained gas. The report concludes that the dissolution rate is self limiting and gas release rates are relatively low.

Stewart, Charles W

2001-07-31T23:59:59.000Z

273

Gas Releases During Saltcake Dissolution for Retrieval of Single-Shell Tank Waste, Rev. 1  

DOE Green Energy (OSTI)

It is possible to retrieve a large fraction of soluble waste from the Hanford single-shell waste tanks (SSTs) by dissolving it with water. This retrieval method will be demonstrated in Tanks U-107 and S-112 in the next few years. If saltcake dissolution proves practical and effective, many of the saltcake SSTs may be retrieved by this method. Many of the SSTs retain flammable gas that will be released into the tank headspace as the waste dissolves. This report describes the physical processes that control dissolution and gas release. Calculation results are shown and describe how the headspace hydrogen concentration evolves during dissolution. The observed spontaneous and induced gas releases from SSTs are summarized, and the dissolution of the crust layer in SY-101 is discussed as a recent example of full-scale dissolution of saltcake containing a large volume of retained gas. The report concludes that the dissolution rate is self-limiting and that gas release rates are relatively low.

Stewart, Charles W

2001-12-28T23:59:59.000Z

274

Coal combustion system  

SciTech Connect

In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

1988-01-01T23:59:59.000Z

275

IN SITU COMBUSTION  

NLE Websites -- All DOE Office Websites (Extended Search)

a combustion zone that moves through the formation toward production wells, providing a steam drive and an intense gas drive for the recovery of oil. This process is sometimes...

276

Reducing mode circulating fluid bed combustion  

DOE Patents (OSTI)

A method for combustion of sulfur-containing fuel in a circulating fluid bed combustion system wherein the fuel is burned in a primary combustion zone under reducing conditions and sulfur captured as alkaline sulfide. The reducing gas formed is oxidized to combustion gas which is then separated from solids containing alkaline sulfide. The separated solids are then oxidized and recycled to the primary combustion zone.

Lin, Yung-Yi (Katy, TX); Sadhukhan, Pasupati (Katy, TX); Fraley, Lowell D. (Sugarland, TX); Hsiao, Keh-Hsien (Houston, TX)

1986-01-01T23:59:59.000Z

277

Variability in natural gas fuel composition and its effects on the performance of catalytic combustion systems. Final report for period September 18, 1998 - September 17, 2000  

SciTech Connect

Natural gas is composed primarily of methane with small amounts of higher hydrocarbons and diluents, which vary by region and over time. Compositions of natural gas from domestic and worldwide sources were surveyed with respect to content of higher hydrocarbons and diluents. The survey showed slight compositional variability between most of the gases, with a small fraction of them containing significantly larger contents of higher hydrocarbons than the mean. As gas-fired turbines will be used for power generation all over the world, they will need to tolerate operation with fuels with a wide variety of compositions, particularly with respect to the concentration of higher hydrocarbons and diluents. Subscale catalytic combustion modules typical of those used in gas turbine power generation with ultra low emissions of pollutants were tested in a subscale test system with natural gas alone and with added known levels of hydrocarbon compounds and diluents. The range of compositions tested contained the range observed in the survey. Test results were used to calculate the effect of composition on catalyst performance. The compositional variability is of little consequence to the catalyst for most of the gases in the survey, including nearly all of the gases delivered in the U.S. To accommodate the remaining gases, the catalyst inlet temperature must be lowered to maintain combustor durability. These results support commercial acceptance of catalytic combustion systems for use in natural gas fired turbines in distributed power generation with ultra low NO{sub x} emissions.

Ginter, David; Simchick, Chuck; Schlatter, Jim

2002-03-01T23:59:59.000Z

278

Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance  

SciTech Connect

A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

Andrew Seltzer; Zhen Fan

2011-03-01T23:59:59.000Z

279

Gas Turbine/Combined Cycle Post-Combustion Emission Control Best Maintenance Practices Guideline  

Science Conference Proceedings (OSTI)

Most simple cycle and combined cycle gas turbines installed in the last ten years have been equipped with selective catalytic reduction (SCR) controls for nitrogen oxides (NOx) and are required to maintain outlet NOx emissions as low as 2.5 ppm (at 15 oxygen content). In addition, many of these units are equipped with catalyst to oxidize carbon monoxide (CO) by as much as 90 or more, lowering CO emissions to less than 5 ppm (also at 15 oxygen content). With many of these units having acquired more than 5...

2011-12-13T23:59:59.000Z

280

Test container design/fabrication/function for the Waste Isolation Pilot Plant gas generation experiment glovebox  

SciTech Connect

The gas generation experiments (GGE) are being conducted at Argonne National Laboratory-West (ANL0W) with contact handled transuranic (CH-TRU) waste in support of the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. The purpose of the GGE is to determine the different quantities and types of gases that would be produced and the gas-generation rates that would develop if brine were introduced to CH-TRU waste under post-closure WIPP disposal room conditions. The experiment requires that a prescribed matrix of CH-TRU waste be placed in a 7.5 liter test container. After loaded with the CH-TRU waste, brine and inoculum mixtures (consisting of salt and microbes indigenous to the Carlsbad, New Mexico region) are added to the waste. The test will run for an anticipated time period of three to five years. The test container itself is an ASME rated pressure vessel constructed from Hastelloy C276 to eliminate corrosion that might contaminate the experimental results. The test container is required to maintain a maximum 10% head space with a maximum working pressure of 17.25 MPa (2,500 psia). The test container is designed to provide a gas sample of the head space without the removal of brine. Assembly of the test container lid and process valves is performed inside an inert atmosphere glovebox. Glovebox mockup activities were utilized from the beginning of the design phase to ensure the test container and associated process valves were designed for remote handling. In addition, test container processes (including brine addition, sparging, leak detection, and test container pressurization) are conducted inside the glovebox.

Knight, C.J.; Russell, N.E.; Benjamin, W.W.; Rosenberg, K.E.; Michelbacher, J.A.

1997-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Coal Combustion Science  

SciTech Connect

The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

1991-08-01T23:59:59.000Z

282

METC Combustion Research Facility  

SciTech Connect

The objective of the Morgantown Energy Technology Center (METC) high pressure combustion facility is to provide a mid-scale facility for combustion and cleanup research to support DOE`s advanced gas turbine, pressurized, fluidized-bed combustion, and hot gas cleanup programs. The facility is intended to fill a gap between lab scale facilities typical of universities and large scale combustion/turbine test facilities typical of turbine manufacturers. The facility is now available to industry and university partners through cooperative programs with METC. High pressure combustion research is also important to other DOE programs. Integrated gasification combined cycle (IGCC) systems and second-generation, pressurized, fluidized-bed combustion (PFBC) systems use gas turbines/electric generators as primary power generators. The turbine combustors play an important role in achieving high efficiency and low emissions in these novel systems. These systems use a coal-derived fuel gas as fuel for the turbine combustor. The METC facility is designed to support coal fuel gas-fired combustors as well as the natural gas fired combustor used in the advanced turbine program.

Halow, J.S.; Maloney, D.J.; Richards, G.A.

1993-11-01T23:59:59.000Z

283

Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles  

SciTech Connect

Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

Haihua Zhao; Per F. Peterson

2012-10-01T23:59:59.000Z

284

DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS  

SciTech Connect

In 1997, the United States Environmental Protection Agency (EPA) promulgated new National Ambient Air Quality Standards (NAAQS) for particulate matter, including for the first time particles with aerodynamic diameter smaller than 2.5 micrometers ({micro}m) referred to as PM2.5. PM2.5 in the atmosphere also contributes to reduced atmospheric visibility, which is the subject of existing rules for siting emission sources near Class 1 areas and new Regional Haze rules. There are few existing data regarding emissions and characteristics of fine aerosols from oil, gas and power generation industry combustion sources, and the information that is available is generally outdated and incomplete. Traditional stationary source air emission sampling methods tend to underestimate or overestimate the contribution of the source to ambient aerosols because they do not properly account for primary aerosol formation, which occurs after the gases leave the stack. Primary aerosol includes both filterable particles that are solid or liquid aerosols at stack temperature plus those that form as the stack gases cool through mixing and dilution processes in the plume downwind of the source. These deficiencies in the current methods can have significant impacts on regulatory decision-making. PM2.5 measurement issues were extensively reviewed by the American Petroleum Institute (API) (England et al., 1998), and it was concluded that dilution sampling techniques are more appropriate for obtaining a representative particulate matter sample from combustion systems for determining PM2.5 emission rate and chemical speciation. Dilution sampling is intended to collect aerosols including those that condense and/or react to form solid or liquid aerosols as the exhaust plume mixes and cools to near-ambient temperature immediately after the stack discharge. These techniques have been widely used in recent research studies. For example, Hildemann et al. (1994) and McDonald et al. (1998) used filtered ambient air to dilute the stack gas sample followed by 80-90 seconds residence time to allow aerosol formation and growth to stabilize prior to sample collection and analysis. More accurate and complete emissions data generated using the methods developed in this program will enable more accurate source-receptor and source apportionment analysis for PM2.5 National Ambient Air Quality Standards (NAAQS) implementation and streamline the environmental assessment of oil, gas and power production facilities. The overall goals of this program were to: (1) Develop improved dilution sampling technology and test methods for PM2.5 mass emissions and speciation measurements, and compare results obtained with dilution and traditional stationary source sampling methods. (2) Develop emission factors and speciation profiles for emissions of fine particulate matter, especially organic aerosols, for use in source-receptor and source apportionment analyses. (3) Identify and characterize PM2.5 precursor compound emissions that can be used in source-receptor and source apportionment analyses.

Glenn C. England

2004-10-20T23:59:59.000Z

285

Greenhouse gas emissions from home composting of organic household waste  

Science Conference Proceedings (OSTI)

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6-3.5 kg week{sup -1} and the temperature inside the composting units was in all cases only a few degrees (2-10 {sup o}C) higher than the ambient temperature. The emissions of methane (CH{sub 4}) and nitrous oxide (N{sub 2}O) were quantified as 0.4-4.2 kg CH{sub 4} Mg{sup -1} input wet waste (ww) and 0.30-0.55 kg N{sub 2}O Mg{sup -1} ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH{sub 4} and N{sub 2}O emissions) of 100-239 kg CO{sub 2}-eq. Mg{sup -1} ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH{sub 4} during mixing which was estimated to 8-12% of the total CH{sub 4} emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg{sup -1} ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO{sub 2}-eq. Mg{sup -1} ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.

Andersen, J.K., E-mail: jka@env.dtu.d [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark); Boldrin, A.; Christensen, T.H.; Scheutz, C. [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark)

2010-12-15T23:59:59.000Z

286

Proceedings: EPRI Workshop on Condition and Remaining Life Assessment of Hot Gas Path Components of Combustion Turbines  

Science Conference Proceedings (OSTI)

The severity of modern combustion turbine operation is a reflection of industry competition to achieve higher thermal efficiency. This competitive stance has resulted in new turbine designs and material systems that have at times outpaced condition and remaining life assessment (CARLA) technology. These proceedings summarize a two-day workshop on CARLA technology for hot section components of large combustion turbines.

2000-06-05T23:59:59.000Z

287

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

Science Conference Proceedings (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

288

Method of launching a missile using secondary combustion  

SciTech Connect

A method is described of selectively increasing the energy output of a gas generator utilized to launch a missile from a launch tube without igniting the missile until after it is launched from the tube comprising the steps of: providing combustible products in the products of combustion produced by primary combustion within the gas generator; providing varying quantities of oxidant in the launch tube to burn the combustible products in the products of combustion produced by the gas generator; and controlling the temperature of the products of combustion produced by the gas generator to permit secondary combustion of the combustible products.

Erikson, E.E.

1987-06-09T23:59:59.000Z

289

NETL: Staged, High-Pressure Oxy-Combustion Technology: Development...  

NLE Websites -- All DOE Office Websites (Extended Search)

tool Conducting CFD-aided design of a novel staged combustion vessel and radiative heat exchanger Performing lab-scale experiments of staged combustion without flue gas...

290

NETL: Pre-Combustion Carbon Capture by a Nanoporous, Superhydrophobic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Pre-Combustion Carbon Capture by a Nanoporous, Superhydrophobic Membrane Contactor Process Project No.: DE-FE0000646 The Gas Technology Institute is developing a pre-combustion...

291

Reactive carbon from life support wastes for incinerator flue gas cleanup-System Testing  

E-Print Network (OSTI)

of Utah with the combustion of biomass has shown that thegas, studies of the combustion of biomass by N A S A Ames

2002-01-01T23:59:59.000Z

292

Oxy-combustion Boiler Material Development  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxy-combustion Boiler Material Oxy-combustion Boiler Material Development Background In an oxy-combustion system, combustion air (79 percent nitrogen, 21 percent oxygen) is replaced by oxygen and recycled flue gas (carbon dioxide [CO 2 ] and water), eliminating nitrogen in the flue gas stream. When applied to an existing boiler, the flue gas recirculation rate is adjusted to enable the boiler to maintain its original air-fired heat absorption performance, eliminating the need to derate the boiler

293

Corrosion-induced gas generation in a nuclear waste repository: Reactive geochemistry and multiphase flow effect  

DOE Green Energy (OSTI)

Corrosion of steel canisters, stored in a repository for spent fuel and high-level nuclear wastes, leads to the generation and accumulation of hydrogen gas in the backfilled emplacement tunnels, which may significantly affect long-term repository safety. Previous studies used H{sub 2} generation rates based on the volume of the waste or canister material and the stoichiometry of the corrosion reaction. However, iron corrosion and H{sub 2} generation rates vary with time, depending on factors such as amount of iron, water availability, water contact area, and aqueous and solid chemistry. To account for these factors and feedback mechanisms, we developed a chemistry model related to iron corrosion, coupled with two-phase (liquid and gas) flow phenomena that are driven by gas-pressure buildup associated with H{sub 2} generation and water consumption. Results indicate that by dynamically calculating H{sub 2} generation rates based on a simple model of corrosion chemistry, and by coupling this corrosion reaction with two-phase flow processes, the degree and extent of gas pressure buildup could be much smaller compared to a model that neglects the coupling between flow and reactive transport mechanisms. By considering the feedback of corrosion chemistry, the gas pressure increases initially at the canister, but later decreases and eventually returns to a stabilized pressure that is slightly higher than the background pressure. The current study focuses on corrosion under anaerobic conditions for which the coupled hydrogeochemical model was used to examine the role of selected physical parameters on the H{sub 2} gas generation and corresponding pressure buildup in a nuclear waste repository. The developed model can be applied to evaluate the effect of water and mineral chemistry of the buffer and host rock on the corrosion reaction for future site-specific studies.

Xu, T.; Senger, R.; Finsterle, S.

2008-10-15T23:59:59.000Z

294

COMBUSTION SYNTHESIS OF ADVANCED MATERIALS: PRINCIPLESAND APPLICATIONS  

E-Print Network (OSTI)

COMBUSTION SYNTHESIS OF ADVANCED MATERIALS: PRINCIPLESAND APPLICATIONS Arvind Varma, Alexander S. Gasless Combustion SynthesisFrom Elements B. Combustion Synthesis in Gas-Solid Systems C. Products of Thermite-vpe SHS D. Commercial Aspects IV. Theoretical Considerations A. Combustion Wave Propagation Theory

Mukasyan, Alexander

295

Offsite commercial disposal of oil and gas exploration and production waste :availability, options, and cost.  

Science Conference Proceedings (OSTI)

A survey conducted in 1995 by the American Petroleum Institute (API) found that the U.S. exploration and production (E&P) segment of the oil and gas industry generated more than 149 million bbl of drilling wastes, almost 18 billion bbl of produced water, and 21 million bbl of associated wastes. The results of that survey, published in 2000, suggested that 3% of drilling wastes, less than 0.5% of produced water, and 15% of associated wastes are sent to offsite commercial facilities for disposal. Argonne National Laboratory (Argonne) collected information on commercial E&P waste disposal companies in different states in 1997. While the information is nearly a decade old, the report has proved useful. In 2005, Argonne began collecting current information to update and expand the data. This report describes the new 2005-2006 database and focuses on the availability of offsite commercial disposal companies, the prevailing disposal methods, and estimated disposal costs. The data were collected in two phases. In the first phase, state oil and gas regulatory officials in 31 states were contacted to determine whether their agency maintained a list of permitted commercial disposal companies dedicated to oil. In the second stage, individual commercial disposal companies were interviewed to determine disposal methods and costs. The availability of offsite commercial disposal companies and facilities falls into three categories. The states with high oil and gas production typically have a dedicated network of offsite commercial disposal companies and facilities in place. In other states, such an infrastructure does not exist and very often, commercial disposal companies focus on produced water services. About half of the states do not have any industry-specific offsite commercial disposal infrastructure. In those states, operators take their wastes to local municipal landfills if permitted or haul the wastes to other states. This report provides state-by-state summaries of the types of offsite commercial disposal facilities that are found in each state. In later sections, data are presented by waste type and then by disposal method.

Puder, M. G.; Veil, J. A.

2006-09-05T23:59:59.000Z

296

GAS-GENERATION EXPERIMENTS FOR LONG-TERM STORAGE OF TRU WASTES AT WIPP  

DOE Green Energy (OSTI)

An experimental investigation was conducted for gas generation in contact-handled transuranic (CH-TRU) wastes subjected for several years to conditions similar to those expected to occur at the Waste Isolation Pilot Plant (WIPP) should the repository eventually become inundated with brine. Various types of actual CH-TRU wastes were placed into 12 corrosion-resistant vessels. The vessels were loosely filled with the wastes, which were submerged in synthetic brine having the same chemical composition as that in the WIPP vicinity. The vessels were also inoculated with microbes found in the Salado Formation at WIPP. The vessels were sealed, purged, and the approximately 750-ml headspace was pressurized with nitrogen gas to approximately 146 atmospheres to create anoxic conditions at the lithostatic pressure expected in the repository were it inundated. The temperature was maintained at the expected 30 C. The test program objective was to measure the quantities and species of gases generate d by metal corrosion, radiolysis, and microbial activity. These data will assist in the specification of the rates at which gases are produced under inundated repository conditions for use in the WIPP Performance Assessment computer models. These experiments were very carefully designed, constructed, instrumented, and performed. Approximately 6-1/2 years of continuous, undisturbed testing were accumulated. Several of the vessels showed significantly elevated levels of generated gases, virtually all of which was hydrogen. One vessel measured over 4.2% hydrogen, by volume. Two other vessels generated well over 1% hydrogen, and another was at nearly 1%. Only small quantities of other gases, principally carbon dioxide, were detected. Gas generation was found to depend strongly on the waste composition. The maximum hydrogen generation occurred in tests containing carbon steel. Average corrosion penetration rates in carbon-steel of up to 2.3 microns per year were deduced. Conversion of carbon to carbon dioxide was calculated to be up to 4.7 {micro}g-mol/yr/g-carbon.

Felicione, F.S.; Carney, K.P.; Dwight, C.C.; Cummings, D.G.; Foulkrod, L.E.

2003-02-27T23:59:59.000Z

297

Analysis of Induced Gas Releases During Retrieval of Hanford Double-Shell Tank Waste  

DOE Green Energy (OSTI)

Checklist for Technical Peer Review for PNNL-13782 Rev. 1 as requested to ensure that software used to support the DSA is compliant with software QA requirements. Radioactive waste is scheduled to be retrieved from Hanford double-shell tanks AN-103, AN-104, AN-105 and AW-101 and transferred to the vitrification plant beginning in about 2009. Retrieval may involve decanting the supernatant liquid and/or mixing the waste with jet pumps. In these four tanks, which contain relatively large volumes of retained gas, both operations are expected to induce buoyant displacement gas releases that can potentially raise the tank headspace hydrogen concentration to a level very near the lower flammability limit. This report describes the theory and detailed physical models for both the supernatant decant and jet mixing processes and presents the results from applying the models to these operations in the four tanks. The technical bases for input parameter distributions are elucidated.

Wells, Beric E.

2003-02-19T23:59:59.000Z

298

Analysis of Induced Gas Released During Retrieval of Hanford Double-Shell Tank Waste  

DOE Green Energy (OSTI)

Radioactive waste is scheduled to be retrieved from Hanford double-shell tanks AN-103, AN-104, AN-105 and AW-101 to the vitrification plant beginning about 2009. Retrieval may involve decanting the supernatant liquid and/or mixing the waste with jet pumps. In these four tanks, which contain relatively large volumes of retained gas, both of these operations are expected to induce buoyant displacement gas releases that can potentially raise the tank headspace hydrogen concentration to very near the lower flammability limit. This report describes the theory and detailed physical models for both the supernate decant and jet mixing processes and presents the results from applying the models to these operations in the four tanks. The technical bases for input parameter distributions are elucidated.

Wells, Beric E. (BATTELLE (PACIFIC NW LAB)); Cuta, Judith M. (BATTELLE (PACIFIC NW LAB)); Hartley, Stacey A. (BATTELLE (PACIFIC NW LAB)); Mahoney, Lenna A. (BATTELLE (PACIFIC NW LAB)); Meyer, Perry A. (BATTELLE (PACIFIC NW LAB)); Stewart, Charles W. (BATTELLE (PACIFIC NW LAB))

2002-03-20T23:59:59.000Z

299

Analysis of Induced Gas Releases During Retrieval of Hanford Double-Shell Tank Waste  

DOE Green Energy (OSTI)

Radioactive waste is scheduled to be retrieved from Hanford double-shell tanks AN-103, AN-104, AN-105, and AW-101 to the vitrification plant beginning about 2009. Retrieval may involve decanting the supernatant liquid and/or mixing the waste with jet pumps. In these four tanks, which contain relatively large volumes of retained gas, both of these operations are expected to induce buoyant displacement gas releases that can potentially raise the tank headspace hydrogen concentration to very near the lower flammability limit. This report describes the theory and detailed physical models for both the supernatant decant and jet mixing processes and presents the results from applying the models to these operations in the four tanks. The technical bases for input parameter distributions are elucidated.

Wells, Beric E. (BATTELLE (PACIFIC NW LAB)); Cuta, Judith M. (BATTELLE (PACIFIC NW LAB)); Hartley, Stacey A. (BATTELLE (PACIFIC NW LAB)); Mahoney, Lenna A. (BATTELLE (PACIFIC NW LAB)); Meyer, Perry A. (BATTELLE (PACIFIC NW LAB)); Stewart, Charles W. (BATTELLE (PACIFIC NW LAB))

2002-09-25T23:59:59.000Z

300

Predicting Peak Hydrogen Concentrations from Spontaneous Gas Releases in Hanford Waste Tanks  

DOE Green Energy (OSTI)

Buoyant displacement gas release events (BDGRE) are spontaneous gas releases that occur in a few of the Hanford radioactive waste storage tanks when gas accumulation makes the sediment layer buoyant with respect to the liquid. BDGREs are assumed to be likely if the ratio of the predicted sediment gas fraction and neutral buoyancy gas fraction, or buoyancy ratio, exceeds unity. Based on the observation that the buoyancy ratio is also an empirical indicator of BDGRE size, a new methodology is derived that formally correlates the buoyancy ratio and the peak headspace hydrogen concentration resulting from BDGREs. The available data on the six historic BDGRE tanks, AN-103, AN-104, AN-105, AW-101, SY-103, and SY-101, are studied in detail to describe both the waste state and the corresponding distribution of BDGREs. The range of applicability of the buoyancy ratio-based models is assessed based on the modeling assumptions and availability of tank data. Recommendations are given for extending the range of the models applicability.

Stewart, Charles W.; Hartley, Stacey A.; Meyer, Perry A.; Wells, Beric E.

2005-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Combustion Safety Overview  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

March 1-2, 2012 March 1-2, 2012 Building America Stakeholders Meeting Austin, Texas Combustion Safety in the Codes Larry Brand Gas Technology Institute Acknowledgement to Paul Cabot - American Gas Association 2 | Building America Program www.buildingamerica.gov Combustion Safety in the Codes Widely adopted fuel gas codes: * National Fuel Gas Code - ANSI Z223.1/NFPA 54, published by AGA and NFPA (NFGC) * International Fuel Gas Code - published by the International Code Council (IFGC) * Uniform Plumbing Code published by IAPMO (UPC) Safety codes become requirements when adopted by the Authority Having Jurisdiction (governments or fire safety authorities) 3 | Building America Program www.buildingamerica.gov Combustion Safety in the Codes Formal Relationships Between these codes: - The IFGC extracts many safety

302

DNAPL Site Characterization for Waste Management at Manufactured Gas Plant (MGP) Sites  

Science Conference Proceedings (OSTI)

Determining the optimal waste management strategy at manufactured gas plant (MGP) sites requires adequate site characterization to provide data for remediation decisions, a task that is particularly challenging when dense nonaqueous phase liquids (DNAPLs) are present. This report discusses development of an appropriate characterization strategy, including parameters that should be characterized, tools for characterization and the relation between characterization goals, a developing site conceptual model...

2004-12-22T23:59:59.000Z

303

Assessment of microbial processes on gas production at radioactive low-level waste disposal sites  

SciTech Connect

Factors controlling gaseous emanations from low level radioactive waste disposal sites are assessed. Importance of gaseous fluxes of methane, carbon dioxide, and possible hydrogen from the site, stems from the inclusion of tritium and/or carbon-14 into the elemental composition of these compounds. In that the primary source of these gases is the biodegradation of organic components of the waste material, primary emphasis of the study involved an examination of the biochemical pathways producing methane, carbon dioxide, and hydrogen, and the environmental parameters controlling the activity of the microbial community involved. Initial examination of the data indicates that the ecosystem is anaerobic. As the result of the complexity of the pathway leading to methane production, factors such as substrate availability, which limit the initial reaction in the sequence, greatly affect the overall rate of methane evolution. Biochemical transformations of methane, hydrogen and carbon dioxide as they pass through the soil profile above the trench are discussed. Results of gas studies performed at three commercial low level radioactive waste disposal sites are reviewed. Methods used to obtain trench and soil gas samples are discussed. Estimates of rates of gas production and amounts released into the atmosphere (by the GASFLOW model) are evaluated. Tritium and carbon-14 gaseous compounds have been measured in these studies; tritiated methane is the major radionuclide species in all disposal trenches studied. The concentration of methane in a typical trench increases with the age of the trench, whereas the concentration of carbon dioxide is similar in all trenches.

Weiss, A.J.; Tate, R.L. III; Colombo, P.

1982-05-01T23:59:59.000Z

304

Improved Hydrogen Gas Getters for TRU Waste Transuranic and Mixed Waste Focus Area - Phase 2 Final Report  

DOE Green Energy (OSTI)

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission (NRC) limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB. It has the needed binding rate and capacity, but some of the chemical species that might be present in the containers could interfere with its ability to remove hydrogen. This project is focused upon developing a protective polymeric membrane coating for the DEB getter material, which comes in the form of small, irregularly shaped particles. This report summarizes the experimental results of the second phase of the development of the materials.

Stone, Mark Lee

2002-04-01T23:59:59.000Z

305

Syn-Gas Production from Catalytic Steam Gasification of Municipal Solid Wastes in a Combined Fixed Bed Reactor  

Science Conference Proceedings (OSTI)

The catalytic steam gasi?cation of municipal solid wastes (MSW) for syn-gas production was experimentally investigated in a combined fixed bed reactor using the newly developed tri-metallic catalyst. A series of experiments have been performed to explore ... Keywords: Biomass gasification, municipal solid wastes, catalyst, hydrogen production, energy recovery

Jianfen Li; Jianjun Liu; Shiyan Liao; Xiaorong Zhou; Rong Yan

2010-10-01T23:59:59.000Z

306

Impact of chemical reactions in the gas phase on the in-situ combustion process: an experimental study.  

E-Print Network (OSTI)

??In-Situ Combustion (ISC) is a thermal enhanced oil recovery method. Therefore, air or oxygen-enriched air is injected in the reservoir. The oxygen reacts with part… (more)

Hoekstra, B.E.

2011-01-01T23:59:59.000Z

307

Microwave off-gas treatment apparatus and process  

DOE Patents (OSTI)

The invention discloses a microwave off-gas system in which microwave energy is used to treat gaseous waste. A treatment chamber is used to remediate off-gases from an emission source by passing the off-gases through a susceptor matrix, the matrix being exposed to microwave radiation. The microwave radiation and elevated temperatures within the combustion chamber provide for significant reductions in the qualitative and quantitative emissions of the gas waste stream.

Schulz, Rebecca L. (Aiken, SC); Clark, David E. (Gainesville, FL); Wicks, George G. (North Aiken, SC)

2003-01-01T23:59:59.000Z

308

Mechanisms of gas retention and release: Experimental results for Hanford waste tanks 241-AW-101 and 241-AN-103  

DOE Green Energy (OSTI)

The 177 storage tanks at Hanford contain a vast array of radioactive waste forms resulting, primarily, from nuclear materials processing. Through radiolytic, thermal, and other decomposition reactions of waste components, gaseous species including hydrogen, ammonia, and the oxidizer nitrous oxide are generated within the waste tanks. Many of these tanks are known to retain and periodically release quantities of these flammable gas mixtures. The primary focus of the Flammable Gas Project is the safe storage of Hanford tank wastes. To this end, we strive to develop an understanding of the mechanisms of flammable gas retention and release in Hanford tanks through laboratory investigations on actual tank wastes. These results support the closure of the Flammable Gas Unreviewed Safety Question (USQ) on the safe storage of waste tanks known to retain flammable gases and support resolution of the broader Flammable Gas Safety Issue. The overall purpose of this ongoing study is to develop a comprehensive and thorough understanding of the mechanisms of flammable gas retention and release. The first objective of the current study was to classify bubble retention and release mechanisms in two previously untested waste materials from Tanks 241-AN-103 (AN-103) and 241-AW-101 (AW-101). Results were obtained for retention mechanisms, release characteristics, and the maximum gas retention. In addition, unique behavior was also documented and compared with previously studied waste samples. The second objective was to lengthen the duration of the experiments to evaluate the role of slowing bubble growth on the retention and release behavior. Results were obtained for experiments lasting from a few hours to a few days.

Rassat, S.D.; Gauglitz, P.A.; Bredt, P.R.; Mahoney, L.A.; Forbes, S.V.; Tingey, S.M.

1997-09-01T23:59:59.000Z

309

Gas bubble retention and its effect on waste properties: Retention mechanisms, viscosity, and tensile and shear strengths  

SciTech Connect

Several of the underground nuclear storage tanks at Hanford have been placed on a flammable gas watch list, because the waste is either known or suspected to generate, store, and episodically release flammable gases. Because retention and episodic release of flammable gases from these tanks containing radioactive waste slurries are critical safety concerns, Pacific Northwest Laboratory (PNL) is studying physical mechanisms and waste properties that contribute to the episodic gas release from these storage tanks. This study is being conducted for Westinghouse Hanford Company as part of the PNL Flammable Gas project. Previous investigations have concluded that gas bubbles are retained by the slurry or sludge that has settled at the bottom of the tanks; however, the mechanisms responsible for the retention of these bubbles are not well understood. Understanding the rheological behavior of the waste, particularly of the settled sludge, is critical to characterizing the tendency of the waste to retain gas bubbles and the dynamics of how these bubbles are released from the waste. The presence of gas bubbles is expected to affect the rheology of the sludge, specifically its viscosity and tensile and shear strengths, but essentially no literature data are available to assess the effect of bubbles. The objectives of this study were to conduct experiments and develop theories to understand better how bubbles are retained by slurries and sludges, to measure the effect of gas bubbles on the viscosity of simulated slurries, and to measure the effect of gas bubbles on the tensile and shear strengths of simulated slurries and sludges. In addition to accomplishing these objectives, this study developed correlations, based on the new experimental data, that can be used in large-scale computations of waste tank physical phenomena.

Gauglitz, P.A.; Rassat, S.D.; Powell, M.R. [and others

1995-08-01T23:59:59.000Z

310

FY 1992 Annual report: Mediated electrochemical oxidation treatment for Rocky Flats combustible low-level mixed waste. Final report to Rocky Flats Plant  

SciTech Connect

The Mediated Electrochemical Oxidation (MEO) process was studied for destroying low-level combustible mixed wastes at Rocky Flats (RFP). Tests were performed with nonradioactive surrogate materials: Trimsol for the contaminated oils, and reagent-grade cellulose for the cellulosic wastes. Extensive testing was carried out on Trimsol in both small laboratory-scale apparatus and on a large-scale system incorporating an industrial-size electrochemical cell. Preliminary tests were also carried out in the small-scale system with cellulose. The following operating and system parameters were studied: use of a silver-nitric acid versus a cobalt-sulfuric acid system, effect of electrolyte temperature, effect of acid concentration, effect of current density, and use of ultrasonic agitation. Destruction and coulombic efficiencies were calculated using data obtained from continuous carbon dioxide monitors and total organic carbon (TOC) analysis of electrolyte samples. For Trimsol, the best performance was achieved with the silver-nitrate system at high acid concentrations, temperatures, and current densities. Destruction efficiencies of 98% or greater and coulombic efficiencies close to 50% were obtained in both small- and large-scale systems. For the cellulose, high destruction efficiencies and reasonable coulombic efficiencies were obtained for both silver-nitrate and cobalt-sulfate systems.

Chiba, Z.; Lewis, P.R.; Kahle, R.W.

1993-03-01T23:59:59.000Z

311

Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion  

DOE Green Energy (OSTI)

This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

DeLallo, M.R.; Zaharchuk, R. [Parsons Power Group, Inc., Reading, PA (United States); Reuther, R.B.; Bonk, D.L. [USDOE Morgantown Energy Technology Center, WV (United States)

1996-09-01T23:59:59.000Z

312

Assessment of landfill reclamation and the effects of age on the combustion of recovered municipal solid waste  

DOE Green Energy (OSTI)

This report summarized the Lancaster county Solid Waste Management Authorities`s (LCSWMA)landfill reclamation activities, ongoing since 1991. All aspects have been analyzed from the manpower and equipment requirements at the landfill to the operational impacts felt at the LCSWMA Resource Recovery Facility (RRF) where the material is delivered for processing. Characteristics of the reclaimed refuse and soil recovered from trommeling operations are discussed as are results of air monitoring performed at the landfill excavation site and the RRF. The report also discusses the energy value of the reclaimed material and compares this value with those obtained for significantly older reclaimed waste streams. The effects of waste age on the air emissions and ash residue quality at the RRF are also provided. The report concludes by summarizing the project benefits and provides recommendations for other landfill reclamation operations and areas requiring further research.

Forster, G.A. [Lancaster Environmental Foundation, PA (United States)] [Lancaster Environmental Foundation, PA (United States)

1995-01-01T23:59:59.000Z

313

Internal combustion engine  

SciTech Connect

An improvement to an internal combustion engine is disclosed that has a fuel system for feeding a fuel-air mixture to the combustion chambers and an electrical generation system, such as an alternator. An electrolytic cell is attached adjacent to the engine to generate hydrogen and oxygen upon the application of a voltage between the cathode and anode of the electrolytic cell. The gas feed connects the electrolytic cell to the engine fuel system for feeding the hydrogen and oxygen to the engine combustion chambers. Improvements include placing the electrolytic cell under a predetermined pressure to prevent the electrolyte from boiling off, a cooling system for the electrolytic cell and safety features.

Valdespino, J.M.

1981-06-09T23:59:59.000Z

314

Test Operation of Oxygen-Enriched Incinerator for Wastes From Nuclear Fuel Fabrication Facility  

SciTech Connect

The oxygen-enriched combustion concept, which can minimize off-gas production, has been applied to the incineration of combustible uranium-containing wastes from a nuclear fuel fabrication facility. A simulation for oxygen combustion shows the off-gas production can be reduced by a factor of 6.7 theoretically, compared with conventional air combustion. The laboratory-scale oxygen enriched incineration (OEI) process with a thermal capacity of 350 MJ/h is composed of an oxygen feeding and control system, a combustion chamber, a quencher, a ceramic filter, an induced draft fan, a condenser, a stack, an off-gas recycle path, and a measurement and control system. Test burning with cleaning paper and office paper in this OEI process shows that the thermal capacity is about 320 MJ/h, 90 % of design value and the off-gas reduces by a factor of 3.5, compared with air combustion. The CO concentration for oxygen combustion is lower than that of air combustion, while the O2 concentration in off-gas is kept above 25 vol % for a simple incineration process without any grate. The NOx concentration in an off-gas stream does not reduce significantly due to air incoming by leakage, and the volume and weight reduction factors are not changed significantly, which suggests a need for an improvement in sealing.

Kim, J.-G.; Yang, H.cC.; Park, G.-I.; Kim, I.-T.; Kim, J.-K.

2002-02-26T23:59:59.000Z

315

Processing mixed-waste compressed-gas cylinders at the Oak Ridge Reservation  

Science Conference Proceedings (OSTI)

Until recently, several thousand kilograms of compressed gases were stored at the Oak Ridge Reservation (ORR), in Oak Ridge, Tennessee, because these cylinders could not be taken off-site in their state of configuration for disposal. Restrictions on the storage of old compressed-gas cylinders compelled the Waste Management Organization of Lockheed Martin Energy Systems, Inc. (LMES) to dispose of these materials. Furthermore, a milestone in the ORR Site Treatment Plan required repackaging and shipment off-site of 21 cylinders by September 30, 1997. A pilot project, coordinated by the Chemical Technology Division (CTD) at the Oak Ridge National Laboratory (ORNL), was undertaken to evaluate and recontainerize or neutralize these cylinders, which are mixed waste, to meet that milestone. Because the radiological component was considered to be confined to the exterior of the cylinder, the contents (once removed from the cylinder) could be handled as hazardous waste, and the cylinder could be handled as low-level waste (LLW). This pilot project to process 21 cylinders was important because of its potential impact. The successful completion of the project provides a newly demonstrated technology which can now be used to process the thousands of additional cylinders in inventory across the DOE complex. In this paper, many of the various aspects of implementing this project, including hurdles encountered and the lessons learned in overcoming them, are reported.

Morris, M.I.; Conley, T.B.; Osborne-Lee, I.W.

1998-05-01T23:59:59.000Z

316

The utilization of flue gas desulfurization waste by-products in construction brick  

E-Print Network (OSTI)

Millions of tons of waste by-products from Texas coal burning plants are produced each year. Two common byproducts are the fuel ashes and calcium sulfate (gypsum). Fuel ashes result from the burning of coal. Gypsum is a byproduct of the air purification system, called Flue Gas Desulfurization (FGD). Abatement of these waste products is a growing concern, not only for the industry, but the environment as well. It is possible to produce a gypsum brick unit that can meet the engineering properties required by the Americans Society of Testing Materials (ASTM) standards by using these by-products. This can be accomplished at a cost less than the least expensive common fired clay brick that is used in construction operations. The gypsum brick can be manufactured using established methods that are currently in operation.

Berryman, Charles Wayne

1992-01-01T23:59:59.000Z

317

Title I preliminary engineering for: A. S. E. F. solid waste to methane gas  

DOE Green Energy (OSTI)

An assignment to provide preliminary engineering of an Advanced System Experimental Facility for production of methane gas from urban solid waste by anaerobic digestion is documented. The experimental facility will be constructed on a now-existing solid waste shredding and landfill facility in Pompano Beach, Florida. Information is included on: general description of the project; justification of basic need; process design; preliminary drawings; outline specifications; preliminary estimate of cost; and time schedules for design and construction of accomplishment of design and construction. The preliminary cost estimate for the design and construction phases of the experimental program is $2,960,000, based on Dec. 1975 and Jan. 1976 costs. A time schedule of eight months to complete the Detailed Design, Equipment Procurement and the Award of Subcontracts is given.

None

1976-01-01T23:59:59.000Z

318

Support and control system of the Waste Isolation Pilot Plant gas generation experiment glovebox  

SciTech Connect

A glovebox was designed and fabricated to house test containers loaded with contact handled transuranic (CH-TRU) waste. The test containers were designed to simulate the environmental characteristics of the caverns at the Waste Isolation Pilot Plant (WIPP). The support and control systems used to operate and maintain the Gas Generation Experiment (GGE) include the following: glovebox atmosphere and pressure control, test container support, glovebox operation support, and gas supply and exhaust systems. The glovebox atmosphere and pressure control systems consist of various components used to control both the pressure and quality of the argon atmosphere inside the glovebox. The glovebox pressure is maintained by three separate pressure control systems. The primary pressure control system is designed to maintain the glovebox at a negative pressure with the other two control systems serving as redundant safety backups. The quality of the argon atmosphere is controlled using a purifying bed system that removes oxygen and moisture. Glovebox atmosphere contaminants that are monitored on a continuous or periodic basis include moisture, oxygen, and nitrogen. The gas generation experiment requires the test containers to be filled with brine, leak tested, maintained at a constant temperature, and the gas head space of the test container sampled on a periodic basis. Test container support systems consisting of a brine addition system, leak test system, heating system, and gas sampling system were designed and implemented. A rupture disk system was constructed to provide pressure relief to the test containers. Operational requirements stipulated that test container temperature and pressure be monitored and collected on a continuous basis. A data acquisition system (DAS) was specifically designed to meet these requirements.

Benjamin, W.W.; Knight, C.J.; Michelbacher, J.A.; Rosenberg, K.E.

1997-09-01T23:59:59.000Z

319

HOW ENVIRONMENTAL RISK FROM LEACH ING OF HEAVY METALS IN ASH RESIDUES FROM COMBUSTION OF MUNIC IPAL SOLID WASTE  

E-Print Network (OSTI)

Laboratories which led to the use of acid tests such as the EP and TCLP tests. [25] 13 #12;CONCLUSIONS and soluble metals in the ash from Waste-to Energy (WTE) facilities has led to a public concern about why has led to the requirement for continuous monitoring of oxygen , carbon monoxide (CO) , and acid gases

Columbia University

320

Uncertainty and sensitivity analyses for gas and brine migration at the Waste Isolation Pilot Plant, May 1992  

SciTech Connect

Uncertainty and sensitivity analysis techniques based on Latin hypercube sampling, partial correlation analysis, stepwise regression analysis and examination of scatterplots are used in conjunction with the BRAGFLO model to examine two phase flow (i.e., gas and brine) at the Waste Isolation Pilot Plant (WIPP), which is being developed by the US Department of Energy as a disposal facility for transuranic waste. The analyses consider either a single waste panel or the entire repository in conjunction with the following cases: (1) fully consolidated shaft, (2) system of shaft seals with panel seals, and (3) single shaft seal without panel seals. The purpose of this analysis is to develop insights on factors that are potentially important in showing compliance with applicable regulations of the US Environmental Protection Agency (i.e., 40 CFR 191, Subpart B; 40 CFR 268). The primary topics investigated are (1) gas production due to corrosion of steel, (2) gas production due to microbial degradation of cellulosics, (3) gas migration into anhydrite marker beds in the Salado Formation, (4) gas migration through a system of shaft seals to overlying strata, and (5) gas migration through a single shaft seal to overlying strata. Important variables identified in the analyses include initial brine saturation of the waste, stoichiometric terms for corrosion of steel and microbial degradation of cellulosics, gas barrier pressure in the anhydrite marker beds, shaft seal permeability, and panel seal permeability.

Helton, J.C. [Arizona State Univ., Tempe, AZ (United States); Bean, J.E. [New Mexico Engineering Research Inst., Albuquerque, NM (United States); Butcher, B.M. [Sandia National Labs., Albuquerque, NM (United States); Garner, J.W.; Vaughn, P. [Applied Physics, Inc., Albuquerque, NM (United States); Schreiber, J.D. [Science Applications International Corp., Albuquerque, NM (United States); Swift, P.N. [Tech Reps, Inc., Albuquerque, NM (United States)

1993-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

BEE 4760. Solid Waste Engineering Spring Semester 2010  

E-Print Network (OSTI)

chemistry, energy balance, environmental impacts & controls Sanitary Landfills: planning & operation, gas characterization and reduction; collection and transport systems; waste-to-energy combustion; sanitary landfills) management. 2. An ability to plan and design MSW disposal facilities ­ landfills and incineration. 3

Walter, M.Todd

322

BEE 476. Solid Waste Engineering Spring Semester 2007  

E-Print Network (OSTI)

chemistry, energy balance, environmental impacts & controls Sanitary Landfills: planning & operation, gas characterization and reduction; collection and transport systems; waste-to-energy combustion; sanitary landfills) management. 2. An ability to plan and design MSW disposal facilities ­ landfills and incineration. 3

Walter, M.Todd

323

BEE 476. Solid Waste Engineering Spring Semester 2008  

E-Print Network (OSTI)

chemistry, energy balance, environmental impacts & controls Sanitary Landfills: planning & operation, gas characterization and reduction; collection and transport systems; waste-to-energy combustion; sanitary landfills) management. 2. An ability to plan and design MSW disposal facilities ­ landfills and incineration. 3

Walter, M.Todd

324

IFRF Combustion Journal Article Number 200303, July 2003  

E-Print Network (OSTI)

IFRF Combustion Journal Article Number 200303, July 2003 ISSN 1562-479X Waste Incineration European-mail: klaus.goerner@uni-essen.den URL: http://www.luat.uni-essen.de #12;IFRF Combustion Journal - 2 - Goerner the lower calorific value of normal municipal waste increased with the consequence of increasing combustion

Columbia University

325

A review of the efficacy of silicon carbide hot-gas filters in coal gasification and pressurized fluidized bed combustion environments  

SciTech Connect

Reviews of relevant literature and interviews with individuals cognizant of the state of the art in ceramic filters for hot-gas cleaning were conducted. Thermodynamic calculations of the stability of various ceramic phases were also made. Based on these calculations, reviews, and interviews, conclusions were reached regarding the use of silicon carbide-based ceramics at hot-gas filter media. Arguments are presented that provide the basis for the conclusion that high-purity silicon carbide is a viable material in the integrated coal gasification combined cycle (IGCC) and pressurized fluidized-bed combustion (PFBC) environments which were examined. Clay-bonded materials are, the authors concluded, suspect for these applications, their extensive use notwithstanding. Operations data reviewed focused primarily on clay-bonded filters, for which a great deal of experience exists. The authors used the clay-bonded filter experience as a point of reference for their review and analysis.

Judkins, R.R.; Stinton, D.P.; DeVan, J.H. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

1996-07-01T23:59:59.000Z

326

Measurement of spray combustion processes  

SciTech Connect

A free jet configuration was chosen for measuring noncombusting spray fields and hydrocarbon-air spray flames in an effort to develop computational models of the dynamic interaction between droplets and the gas phase and to verify and refine numerical models of the entire spray combustion process. The development of a spray combustion facility is described including techniques for laser measurements in spray combustion environments and methods for data acquisition, processing, displaying, and interpretation.

Peters, C.E.; Arman, E.F.; Hornkohl, J.O.; Farmer, W.M.

1984-04-01T23:59:59.000Z

327

Combination gas-producing and waste-water disposal well. [DOE patent application  

DOE Patents (OSTI)

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Malinchak, R.M.

1981-09-03T23:59:59.000Z

328

Hydrogen Gas Generation Model for Fuel-Based Remote-Handled Transuranic Waste Stored at the INEEL  

DOE Green Energy (OSTI)

The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

Khericha, S.; Bhatt, R.; Liekhus, K.

2003-01-14T23:59:59.000Z

329

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Second quarterly report ending March 31, 1995  

DOE Green Energy (OSTI)

The Project Description lists and describes six tasks, three of which are virtually complete, with three others underway. A summary of progress on each task follows. Task 1: Development of a Detailed Test Plan. This task is complete. Task 2: Preparation of Test Equipment. This task is complete. Two test units (a six-inch internal diameter and a fifteen-inch internal diameter unit) were prepared and used as described under Task 4. Task 3: Obtain test materials. The required amounts of oil shale and pelletized municipal solid waste have been obtained, tested, and found to be suitable. We have obtained an adequate quantity of a pelletized ``standard`` MSW from BEPR/BFI, Eden Prairie, MN. For test purposes, we synthesized the desired ``worst probable case`` of MSW by the addition of sulfur and chlorine to reach the sulfur and chlorine levels characteristic of such waste. Task 4: Execute Feasibility Demonstration Program. The fluidized bed tests associated with the program have been completed. Analysis of the results is continuing. Testing of the waste stream material generated from these runs will begin about 6 April to evaluate its possible use as cement for specific applications. Information on the technical feasibility of the invention as indicated by the fluid bed test program is included as Attachment A. The results demonstrate that the process is technically feasible. Task 5: Data Analysis. This task is beginning. Task 6: Project Management, Reporting, and Necessary Liaison Activities. Those portions of this task associated with work done on Tasks 1 through 4 have been completed. This task will continue throughout the period of the study. In summary, work is proceeding within budget. No serious problems in the next scheduled tasks are foreseen.

NONE

1995-04-01T23:59:59.000Z

330

Industrial Wastes as a Fuel  

E-Print Network (OSTI)

With the advent of scarce supplies and rising costs for traditional industrial fuels such as natural gas and fuel oil, a large amount of technical data has been collected and published to encourage their efficient use. This same data is readily available for coal since it was at one time a major industrial fuel and is still used extensively for electric power generation. However, combustion data for other fuels such as wood and solid materials typically generated as industrial wastes can only be found in widely scattered and more obscure sources. Therefore, this information is not always easily accessible to operating personnel at plants where these type fuels are being utilized. The resulting lack of proper information many times leads to poor fuel utilization because of less than optimum combustion efficiencies. Operational and maintenance problems may also be caused by a misunderstanding of combustion characteristics.

Richardson, G.; Hendrix, W.

1980-01-01T23:59:59.000Z

331

Hydrogen production from food wastes and gas post-treatment by CO{sub 2} adsorption  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer The dark fermentation process of food wastes was studied over an extended period. Black-Right-Pointing-Pointer Decreasing the HRT of the process negatively affected the specific gas production. Black-Right-Pointing-Pointer Adsorption of CO{sub 2} was successfully attained using a biomass type activated carbon. Black-Right-Pointing-Pointer H{sub 2} concentration in the range of 85-95% was obtained for the treated gas-stream. - Abstract: The production of H{sub 2} by biological means, although still far from being a commercially viable proposition, offers great promise for the future. Purification of the biogas obtained may lead to the production of highly concentrated H{sub 2} streams appropriate for industrial application. This research work evaluates the dark fermentation of food wastes and assesses the possibility of adsorbing CO{sub 2} from the gas stream by means of a low cost biomass-based adsorbent. The reactor used was a completely stirred tank reactor run at different hydraulic retention times (HRTs) while the concentration of solids of the feeding stream was kept constant. The results obtained demonstrate that the H{sub 2} yields from the fermentation of food wastes were affected by modifications in the hydraulic retention time (HRT) due to incomplete hydrolysis. The decrease in the duration of fermentation had a negative effect on the conversion of the substrate into soluble products. This resulted in a lower amount of soluble substrate being available for metabolisation by H{sub 2} producing microflora leading to a reduction in specific H{sub 2} production. Adsorption of CO{sub 2} from a gas stream generated from the dark fermentation process was successfully carried out. The data obtained demonstrate that the column filled with biomass-derived activated carbon resulted in a high degree of hydrogen purification. Co-adsorption of H{sub 2}S onto the activated carbon also took place, there being no evidence of H{sub 2}S present in the bio-H{sub 2} exiting the column. Nevertheless, the concentration of H{sub 2}S was very low, and this co-adsorption did not affect the CO{sub 2} capture capacity of the activated carbon.

Redondas, V. [Chemical Engineering Department, University of Leon, IRENA-ESTIA, Avda. de Portugal 41, Leon 24071 (Spain); Gomez, X., E-mail: xagomb@unileon.es [Chemical Engineering Department, University of Leon, IRENA-ESTIA, Avda. de Portugal 41, Leon 24071 (Spain); Garcia, S.; Pevida, C.; Rubiera, F. [Instituto Nacional del Carbon, CSIC, Apartado 73, 33080 Oviedo (Spain); Moran, A. [Chemical Engineering Department, University of Leon, IRENA-ESTIA, Avda. de Portugal 41, Leon 24071 (Spain); Pis, J.J. [Instituto Nacional del Carbon, CSIC, Apartado 73, 33080 Oviedo (Spain)

2012-01-15T23:59:59.000Z

332

Two phase partially miscible flow and transport modeling in porous media: application to gas migration in a nuclear waste repository  

E-Print Network (OSTI)

We derive a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological repository for radioactive waste. This model includes capillary effects and the gas high diffusivity. Moreover, it is written in variables (total hydrogen mass density and liquid pressure) chosen in order to be consistent with gas appearance or disappearance. We discuss the well possedness of this model and give some computational evidences of its adequacy to simulate gas generation in a water saturated repository.

Alain Bourgeat; Mladen Jurak; Farid Smaï

2008-02-29T23:59:59.000Z

333

A literature review of radiolytic gas generation as a result of the decomposition of sodium nitrate wastes  

DOE Green Energy (OSTI)

The objective of this literature review is to determine expected chemical reactions and the gas generation associated with radiolytic decomposition of radioactive sodium nitrate wastes such as the wastes stored in the Melton Valley Storage Tanks (MVST) at Oak Ridge National Laboratory (ORNL). The literature survey summarizes expected chemical reactions and identifies the gases expected to be generated as a result of the radiolytic decomposition. The literature survey also identifies G values, which are the expression for radiation chemical yields as molecules of gas formed per 100 eV of absorbed energy, obtained from experimental studies of the radiolytic decomposition of water and sodium nitrate. 2 tabs., 32 refs.

Kasten, J.L.

1991-01-01T23:59:59.000Z

334

High Performance Alloys for Advanced Combustion Systems  

Science Conference Proceedings (OSTI)

For steam turbines, it is necessary to raise temperatures in excess of 700?C. For gas turbines, raising the temperature also works but migrating the combustion ...

335

Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst: Final Report, 24 February 2004 -- 23 February 2006  

DOE Green Energy (OSTI)

This report discusses the development of a E7G 12-liter, lean-burn natural gas engine--using stoichiometric combustion, cooled exhaust gas recirculation, and three-way catalyst technologies--for refuse haulers.

Reppert, T.; Chiu, J.

2005-09-01T23:59:59.000Z

336

Predictive modeling of combustion processes  

E-Print Network (OSTI)

Recently, there has been an increasing interest in improving the efficiency and lowering the emissions from operating combustors, e.g. internal combustion (IC) engines and gas turbines. Different fuels, additives etc. are ...

Sharma, Sandeep, Ph. D. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

337

Table 7.3a Consumption of Combustible Fuels for Electricity ...  

U.S. Energy Information Administration (EIA)

combustion plant use of petroleum. ... and other biomass. Through 2000, also includes non-renewable waste (municipal solid waste from non-biogenic sources, and

338

On the role of external combustion engines for on-site power generation  

SciTech Connect

Stationary external combustion engines are prime movers that have potential for becoming viable power generation machines in both the residential/commercial and industrial sectors. These large engines are being developed with the capability to employ alternative and/or non-scarce fuels. Energy sources under consideration include coal, coal derived liquids and gases, low-grade petroleum residues, biomass, and municipal wastes. Advantages of external combustion engines relative to conventional prime movers are: greater fuel efficiency, reduced environmental impacts (noise and emissions), and a high degree of fuel flexibility. External combustion engines include steam turbines, Stirling cycle engines, and externally-fired Brayton gas turbines. Among the various applications for external combustion engines are: total energy plants, ICES, industrial cogeneration, small municipal generating plants, and pumping stations. It is not necessary for all the heat supplied an external combustion engine to come from a single source. Various non-coal sources that can be used either independently or integrated with others to supply heat to external combustion engines include solar energy, municipal wastes, biomass, and geothermal. Stirling engine based systems are described. The development of the Stirling engine is briefly discussed. (MCW)

Holtz, R.E.; Uherka, K.L.

1979-01-01T23:59:59.000Z

339

SOLOX coke-oven gas desulfurization ppm levels -- No toxic waste  

SciTech Connect

For sulfur removal from coke-oven gas, the reduction/oxidation processes such as Stretford are the most effective, capable of removing the H[sub 2]S down to ppm levels. However, these processes have, in the past, suffered from ecological problems with secondary pollutant formation resulting from side reactions with HCN and O[sub 2]. The SOLOX gas desulfurization system is a development of the Stretford process in which the toxic effluent problems are eliminated by installing a salt decomposition process operating according to the liquid-phase hydrolysis principle. In this process, the gaseous hydrolysis products H[sub 2]S, NH[sub 3] and CO[sub 2] are returned to the untreated gas, and the regenerated solution is recycled to the absorption process. The blowdown from the absorption circuit is fed into a tube reactor where the hydrolysis process takes place. The toxic salts react with water, producing as reaction products the gases H[sub 2]S, NH[sub 3] and CO[sub 2], and the nontoxic salt Na[sub 2]SO[sub 4]. From the hydrolysis reactor the liquid stream flows into a fractionating crystallization plant. This plant produces a recycle stream of regenerated absorption solution and a second stream containing most of the Na[sub 2]SO[sub 4]. This second stream comprises the net plant waste and can be disposed of with the excess ammonia liquor or sprayed onto the coal.

Platts, M. (Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)); Tippmer, K. (Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany))

1994-09-01T23:59:59.000Z

340

Pressurized fluidized-bed combustion  

SciTech Connect

If pressurised fluidised-bed combustion is to be used in combined cycle electricity generation, gas turbines must be made reliable and flue gas emission standards must be met. This report examines the issues of particulate cleaning before the turbine and stack, as well as recent work on the development of advanced gas filters.

Yeager, K.

1983-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Development of the utilization of combustible gas produced in existing sanitary landfills: effects of corrosion at the Mountain View, CA Landfill Gas-Recovery Plant  

DOE Green Energy (OSTI)

Corrosion of equipment has occurred at the Mountain View, California Landfill Gas Recovery Plant. Corrosion is most severe on compressor valve seats and cages, tubes in the first and second stages of the interstage gas cooler, and first and second stage piping and liquid separators. Corrosion occurs because the raw landfill gas contains water, carbon dioxide, and oxygen. Some corrosion may also result from trace concentrations of organic acids present in the landfill gas. Corrosion of the third stage compressor, cooler, and piping does not occur because the gas is dehydrated immediately prior to the third stage. Controlling corrosion is necessary to maintain the mechanical integrity of the plant and to keep the cost of the gas competitive with natural gas. Attempts to reduce corrosion rates by injecting a chemical inhibitor have proved only partially successful. Recommendations for dealing with corrosion include earlier dehydration of the gas, selection of special alloys in critical locations, chemical inhibition, and regular plant inspections.

Not Available

1982-10-01T23:59:59.000Z

342

Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, and nitrogen in the gas phase; comparison of gas generation rates in supernate and solid fractions of Tank 241-SY-101 simulated waste  

DOE Green Energy (OSTI)

This report summarizes progress made in evaluating me by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using simulated waste mixtures. Work described in this report. was conducted at Pacific Northwest Laboratory (PNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT), under subcontract to PNL, using simulated wastes, and to studies being performed at VMC using actual wastes.

Bryan, S.A.; Pederson, L.R.

1995-03-01T23:59:59.000Z

343

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE [SEC 1 & 2  

DOE Green Energy (OSTI)

Flammable gases such as hydrogen, ammonia, and methane are observed in the tank dome space of the Hanford Site high-level waste tanks. This report assesses the steady-state flammability level under normal and off-normal ventilation conditions in the tank dome space for 177 double-shell tanks and single-shell tanks at the Hanford Site. The steady-state flammability level was estimated from the gas concentration of the mixture in the dome space using estimated gas release rates, Le Chatelier's rule and lower flammability limits of fuels in an air mixture. A time-dependent equation of gas concentration, which is a function of the gas release and ventilation rates in the dome space, has been developed for both soluble and insoluble gases. With this dynamic model, the time required to reach the specified flammability level at a given ventilation condition can be calculated. In the evaluation, hydrogen generation rates can be calculated for a given tank waste composition and its physical condition (e.g., waste density, waste volume, temperature, etc.) using the empirical rate equation model provided in Empirical Rate Equation Model and Rate Calculations of Hydrogen Generation for Hanford Tank Waste, HNF-3851. The release rate of other insoluble gases and the mass transport properties of the soluble gas can be derived from the observed steady-state gas concentration under normal ventilation conditions. The off-normal ventilation rate is assumed to be natural barometric breathing only. A large body of data is required to do both the hydrogen generation rate calculation and the flammability level evaluation. For tank waste that does not have sample-based data, a statistical-based value from probability distribution regression was used based on data from tanks belonging to a similar waste group. This report (Revision 3) updates the input data of hydrogen generation rates calculation for 177 tanks using the waste composition information in the Best-Basis Inventory Detail Report in the Tank Waste Information Network System, and the waste temperature data in the Surveillance Analysis Computer System (SACS) (dated July 2003). However, the release rate of methane, ammonia, and nitrous oxide is based on the input data (dated October 1999) as stated in Revision 0 of this report. Scenarios for adding waste to existing waste levels (dated July 2003) have been studied to determine the gas generation rates and the effect of smaller dome space on the flammability limits to address the issues of routine water additions and other possible waste transfer operations. In the flammability evaluation with zero ventilation, the sensitivity to waste temperature and to water addition was calculated for double-shell tanks 241-AY-102, 241-AN-102,241-AZ-101,241-AN-107,241-AY-101 and 241-AZ-101. These six have the least margin to flammable conditions among 28 double-shell tanks.

HU, T.A.

2003-09-30T23:59:59.000Z

344

Combustion Instability and Blowout Characteristics of Fuel Flexible...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Blowout Combustion Instability and Blowout Characteristics of Fuel Flexible Gas Turbine Characteristics of Fuel Flexible Gas Turbine Combustors Combustors Georgia...

345

Carbon ion pump for removal of carbon dioxide from combustion ...  

Biomass and Biofuels; Building Energy Efficiency; ... Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures United States Patent ...

346

Third millenium ideal gas and condensed phase thermochemical database for combustion (with update from active thermochemical tables).  

DOE Green Energy (OSTI)

The thermochemical database of species involved in combustion processes is and has been available for free use for over 25 years. It was first published in print in 1984, approximately 8 years after it was first assembled, and contained 215 species at the time. This is the 7th printed edition and most likely will be the last one in print in the present format, which involves substantial manual labor. The database currently contains more than 1300 species, specifically organic molecules and radicals, but also inorganic species connected to combustion and air pollution. Since 1991 this database is freely available on the internet, at the Technion-IIT ftp server, and it is continuously expanded and corrected. The database is mirrored daily at an official mirror site, and at random at about a dozen unofficial mirror and 'finger' sites. The present edition contains numerous corrections and many recalculations of data of provisory type by the G3//B3LYP method, a high-accuracy composite ab initio calculation. About 300 species are newly calculated and are not yet published elsewhere. In anticipation of the full coupling, which is under development, the database started incorporating the available (as yet unpublished) values from Active Thermochemical Tables. The electronic version now also contains an XML file of the main database to allow transfer to other formats and ease finding specific information of interest. The database is used by scientists, educators, engineers and students at all levels, dealing primarily with combustion and air pollution, jet engines, rocket propulsion, fireworks, but also by researchers involved in upper atmosphere kinetics, astrophysics, abrasion metallurgy, etc. This introductory article contains explanations of the database and the means to use it, its sources, ways of calculation, and assessments of the accuracy of data.

Burcat, A.; Ruscic, B.; Chemistry; Technion - Israel Inst. of Tech.

2005-07-29T23:59:59.000Z

347

Mechanisms of gas retention and release: Experimental results for Hanford single-shell waste tanks 241-A-101, 241-S-106, and 241-U-103  

Science Conference Proceedings (OSTI)

The 177 underground waste storage tanks at the Hanford Site contain millions of gallons of radioactive waste resulting from the purification of nuclear materials and related processes. Through various mechanisms, flammable gas mixtures of hydrogen, ammonia, methane, and nitrous oxide are generated and retained in significant quantities within the waste in many ({approximately}25) of these tanks. The potential for large releases of retained gas from these wastes creates a flammability hazard. It is a critical component of the effort to understand the flammability hazard and a primary goal of this laboratory investigation to establish an understanding of the mechanisms of gas retention and release in these wastes. The results of bubble retention experimental studies using waste samples from several waste tanks and a variety of waste types support resolution of the Flammable Gas Safety Issue. Gas bubble retention information gained in the pursuit of safe storage will, in turn, benefit future waste operations including salt-well pumping, waste transfers, and sluicing/retrieval.

Rassat, S.D.; Caley, S.M.; Bredt, P.R.; Gauglitz, P.A.; Rinehart, D.E.; Forbes, S.V.

1998-09-01T23:59:59.000Z

348

Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel  

E-Print Network (OSTI)

Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel Digital upside in view of the power generation growth potential in Asia and the environmental friendly, cost's energy and farming centers in North America as an alternative to coal-fired power plants and a solution

Columbia University

349

Interim On-Site Storage of Low-Level Waste: Volume 4, Part 3: Waste Container Closures, Seals, and Gas Vents  

Science Conference Proceedings (OSTI)

This volume of the Interim On-Site Storage report series supplements Volume 4, Part 1, which includes an extensive methodology and detailed information on the types and availability of low-level waste (LLW) containers and container coatings for extended storage. Part 2, soon to be published, addresses monitoring and inspection requirements for stored LLW containers. Part 3 continues the series by providing detailed guidance on container closures, seals, and gas vents, including performance goals and key ...

1993-11-11T23:59:59.000Z

350

Recycle/reuse of boiler chemical cleaning wastes in wet limestone flue gas desulfurization (FGD) systems  

Science Conference Proceedings (OSTI)

Boiler chemical cleaning wastes (BCCW) are generated by the periodic waterside cleaning of utility boilers to remove metallic deposits from boiler tube surfaces. Depending on boiler metallurgy, BCCW generally contain high concentrations of iron and copper or both, as well as other heavy metals such as chromium, lead, nickel, and zinc. BCCW treatment and disposal methods include precipitation, coponding in an ash pond, evaporation in the fireside of an operating boiler (for organic solvents), and contracted off-site disposal. Depending on the type of BCCW chemical treatment methods achieve varying degrees of success. BCCW which contain organic chelating agents can be especially difficult to treat to national pollutant discharge elimination system (NPDES) limits (1 mg/L for both iron and copper) with conventional lime precipitation.Research is being done to evaluate different BCCW treatment and disposal methods. One waste management option under consideration is reuse of BCCW in utility wet flue gas desulfurization (FGD) systems. To investigate this option, a series of laboratory tests were performed in which five different types of BCCW were added to the reaction tank of EPRI's bench-scale wet limestone FGD system. This paper presents the results and conclusions from this study.

Stohs, M.; Owens, D.R. (Radian Corp. (US)); Micheletti, W. (Electric Power Research Inst., Palo Alto, CA (USA))

1988-01-01T23:59:59.000Z

351

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

352

Is combustion of plastics desirable?  

Science Conference Proceedings (OSTI)

Managing waste will always entail some tradeoffs. All of the three options--recycling, landfilling and combustion--have some disadvantages. Even landfilling, which produces no emissions, fails to take advantage of the energy value inherent in plastic. Waste combustion, on the other hand, recovers the energy in plastic materials and reduces the volume of disposed solid waste by up to 90% of its initial preburn volumes. However, this management option generates emissions and produces an ash residue that must be managed. As demonstrated by recent test burns, improvements in combustion and air-pollution-control technology have dramatically reduced the health risks from emissions and ash. Recent studies have shown that plastics--in quantities even higher than those normally found in municipal solid waste--do not adversely affect levels of emissions or the quality of ash from waste-to-energy facilities. In addition, waste-to-energy facilities may be a relatively economical source of fuel, and may be a more economic solution to waste management than the other available options. A waste-to-energy plant generally produces electricity that is sold to the electric utilities for approximately six cents per kilowatt-hour, a rate that is competitive with those offered by nuclear power plants and power plants that generate energy by burning fossil fuels.

Piasecki, B.; Rainey, D. [Rensselaer Polytechnic Inst., Troy, NY (United States). Lally School of Management and Technology; Fletcher, K.

1998-07-01T23:59:59.000Z

353

Advanced Combustion  

Science Conference Proceedings (OSTI)

Topics covered in this presentation include: the continued importance of coal; related materials challenges; combining oxy-combustion & A-USC steam; and casting large superalloy turbine components.

Holcomb, Gordon R. [NETL

2013-03-05T23:59:59.000Z

354

Combustion 2000  

SciTech Connect

This report is a presentation of work carried out on Phase II of the HIPPS program under DOE contract DE-AC22-95PC95144 from June 1995 to March 2001. The objective of this report is to emphasize the results and achievements of the program and not to archive every detail of the past six years of effort. These details are already available in the twenty-two quarterly reports previously submitted to DOE and in the final report from Phase I. The report is divided into three major foci, indicative of the three operational groupings of the program as it evolved, was restructured, or overtaken by events. In each of these areas, the results exceeded DOE goals and expectations. HIPPS Systems and Cycles (including thermodynamic cycles, power cycle alternatives, baseline plant costs and new opportunities) HITAF Components and Designs (including design of heat exchangers, materials, ash management and combustor design) Testing Program for Radiative and Convective Air Heaters (including the design and construction of the test furnace and the results of the tests) There are several topics that were part of the original program but whose importance was diminished when the contract was significantly modified. The elimination of the subsystem testing and the Phase III demonstration lessened the relevance of subtasks related to these efforts. For example, the cross flow mixing study, the CFD modeling of the convective air heater and the power island analysis are important to a commercial plant design but not to the R&D product contained in this report. These topics are of course, discussed in the quarterly reports under this contract. The DOE goal for the High Performance Power Plant System ( HIPPS ) is high thermodynamic efficiency and significantly reduced emissions. Specifically, the goal is a 300 MWe plant with > 47% (HHV) overall efficiency and {le} 0.1 NSPS emissions. This plant must fire at least 65% coal with the balance being made up by a premium fuel such as natural gas. To achieve these objectives requires a change from complete reliance of coal-fired systems on steam turbines (Rankine cycles) and moving forward to a combined cycle utilizing gas turbines (Brayton cycles) which offer the possibility of significantly greater efficiency. This is because gas turbine cycles operate at temperatures well beyond current steam cycles, allowing the working fluid (air) temperature to more closely approach that of the major energy source, the combustion of coal. In fact, a good figure of merit for a HIPPS design is just how much of the enthalpy from coal combustion is used by the gas turbine. The efficiency of a power cycle varies directly with the temperature of the working fluid and for contemporary gas turbines the optimal turbine inlet temperature is in the range of 2300-2500 F (1260-1371 C). These temperatures are beyond the working range of currently available alloys and are also in the range of the ash fusion temperature of most coals. These two sets of physical properties combine to produce the major engineering challenges for a HIPPS design. The UTRC team developed a design hierarchy to impose more rigor in our approach. Once the size of the plant had been determined by the choice of gas turbine and the matching steam turbine, the design process of the High Temperature Advanced Furnace (HITAF) moved ineluctably to a down-fired, slagging configuration. This design was based on two air heaters: one a high temperature slagging Radiative Air Heater (RAH) and a lower temperature, dry ash Convective Air Heater (CAH). The specific details of the air heaters are arrived at by an iterative sequence in the following order:-Starting from the overall Cycle requirements which set the limits for the combustion and heat transfer analysis-The available enthalpy determined the range of materials, ceramics or alloys, which could tolerate the temperatures-Structural Analysis of the designs proved to be the major limitation-Finally the commercialization issues of fabrication and reliability, availability and maintenance. The program that has s

A. Levasseur; S. Goodstine; J. Ruby; M. Nawaz; C. Senior; F. Robson; S. Lehman; W. Blecher; W. Fugard; A. Rao; A. Sarofim; P. Smith; D. Pershing; E. Eddings; M. Cremer; J. Hurley; G. Weber; M. Jones; M. Collings; D. Hajicek; A. Henderson; P. Klevan; D. Seery; B. Knight; R. Lessard; J. Sangiovanni; A. Dennis; C. Bird; W. Sutton; N. Bornstein; F. Cogswell; C. Randino; S. Gale; Mike Heap

2001-06-30T23:59:59.000Z

355

Flammable Gas Release Estimates for Modified Sluicing Retrieval of Waste from Selected Hanford Single-Shell Tanks  

DOE Green Energy (OSTI)

The high-level radioactive wastes in many single-shell tanks (SSTs) at the Hanford Site are to be retrieved by a modified sluicing method that uses water jets to dissolve the water-soluble waste and mobilize the water-insoluble waste. Retrieval operations will liberate any waste gases trapped in the wetted solid waste matrix, and these gases will be released into the tank headspaces. Because the trapped gases include the flammable species hydrogen, methane, and ammonia, a concern exists that a flammable mixture could be formed in the tank headspaces. This report combines conservative retained gas inventory estimates and tank data with anticipated waste retrieval rates to estimate the potential headspace flammability of selected SSTs during modified sluicing waste retrieval operations. Considered here are nine of the 12 tanks from the 241-S tank farm (241-S-107, 241-S-111, and 241-S 112 are not considered) and Tank 241-U-107. This report is intended to support the specification of process controls that ensure flammable conditions do not develop in the tank headspaces. Consequently, the physical scenarios considered, the models developed to estimate retained gas releases and the tank headspace compositions under these scenarios, and the model input data are intended to conservatively assess the potential to reach headspace flammability. The analyses are intended to address worst-case conditions and establish reasonable upper bounds on the achievable flammability of the tank headspaces. Flammable retained gas inventories, for example, are based on the 95th percentile developed by Barker and Hedengren (2003), giving 95% confidence that actual inventories are smaller than those used in the calculations. Gas releases and headspace flammability were evaluated for three general scenarios: a very aggressive dissolution and erosion of saltcake waste by water jets impinging on the waste surface, the drainage of interstitial liquids from saltcake during a shutdown of the retrieval process, and the dissolution of saltcake by unsaturated liquids during a shutdown of the retrieval process. The simple model of waste retrieval using the modified sluicing approach indicated that the flammable gas headspace concentrations can rapidly approach the action level of 25% of the lower flammability limit (LFL) when the tank is passively ventilated. While it is not necessary to use the portable exhauster to maintain the headspace hydrogen concentration below this action level, retrieval rates would probably be limited by the slow removal of flammable gases by passive ventilation. It was determined that using a portable exhauster anywhere in the assumed operating range of 270 to 475 cfm would prevent the headspaces from reaching the 25% of LFL action level even if the water jets are very effective at eroding the saltcake. Specific guidelines are developed to ensure that, in the event of a catastrophic loss of the retrieval pump and portable exhauster, headspace flammability will not reach the LFL. This report is Revision 1 of PNNL-14271. This revision expands the analysis of interstitial liquid drainage-induced gas releases to address a general retrieval scenario (the previous version of this report assumed a center-out retrieval approach and conditions). Tank waste conditions (waste volumes, interstitial liquid levels, temperatures, retained gas void fractions, etc.) have also been updated from the previous version.

Huckaby, James L.; Wells, Beric E.

2004-03-05T23:59:59.000Z

356

Flammable Gas Release Estimates for Modified Sluicing Retrieval of Waste from Selected Hanford Single-Shell Tanks  

DOE Green Energy (OSTI)

The high-level radioactive wastes in many single-shell tanks (SSTs) at the Hanford Site are to be retrieved by a modified sluicing method. Retrieval operations will hydraulically erode and dissolve the saltcake waste, and the resulting brine will then be pumped to a double-shell tank (DST). Waste gases residing in the solid waste matrix will be released into the tank headspace when the matrix is eroded or dissolved. These retained waste gases include the flammable species hydrogen, methane, and ammonia, and there is a concern that these flammable gases could produce a flammable mixture in the tank headspaces during the retrieval operations. This report combines conservative retained gas inventory estimates and tank data with anticipated waste retrieval rates to estimate the potential headspace flammability of selected SSTs during waste retrieval operations. The SSTs considered here are ten of the twelve 241-S farm tanks (tanks 241-S-107 and 241-S-111 are excluded from consideration here) and tank 241-U-107 (U-107).

Huckaby, James L.; Wells, Beric E.

2003-05-13T23:59:59.000Z

357

An approximate-reasoning-based method for screening high-level waste tanks for flammable gas  

DOE Green Energy (OSTI)

The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at Hanford have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop an improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. AR models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. The authors performed a pilot study to investigate the utility of AR for flammable gas screening. They found that the effort to implement such a model was acceptable and that computational requirements were reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts.

Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

1998-07-01T23:59:59.000Z

358

International Journal of Engineering & Technology IJET-IJENS Vol: 11 No: 03 7 Co-combustion of Biosolids with Wood Pellets in a  

E-Print Network (OSTI)

Abstract- Co-combustion of biosolids with coal or other biomass fuel can play a significant role in combustion facilities for energy production and waste management policy context. This paper presents the results of an experimental study to investigate the use of biosolids for cocombustion with wood pellets in a wood pellet stove. Fuel property, gas emissions and stove efficiency are compared. In regard to fuel properties, proximate analysis, ultimate analysis and heating values are determined and emissions of carbon monoxide (CO), nitrogen oxides (NOx) and sulphur dioxide (SO2) are measured and compared. Pilot scale combustion tests revealed that cocombustion of 10 % biosolids with 90% wood pellets resulted in successful combustion without any significant degradation of efficiency and emissions. Nitrogen oxides (NOx) emissions were found to be proportional with the N2 content in the fuel. Sulphur dioxide (SO2) emissions were negligible. Index Terms- Biosolids, co-combustion, wood pellet stove, performance and emissions.

Wood Pellet Stove; Murari Mohon Roy; Animesh Dutta; Kenny Corscadden; Peter Havard

2011-01-01T23:59:59.000Z

359

NEW TRENDS IN FLUE GAS CLEANING TECHNOLOGIES FOR EUROPEAN AND ASIAN WASTE INCINERATION FACILITIES  

E-Print Network (OSTI)

Organic Compound TCLP EPA Toxicity Characteristic Leaching Procedure TRU Transuranic Waste VOC Volatile

Columbia University

360

Life cycle assessment of greenhouse gas emissions and non-CO? combustion effects from alternative jet fuels  

E-Print Network (OSTI)

The long-term viability and success of a transportation fuel depends on both economic and environmental sustainability. This thesis focuses specifically on assessing the life cycle greenhouse gas (GHG) emissions and non-CO ...

Stratton, Russell William

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Modules for estimating solid waste from fossil-fuel technologies  

SciTech Connect

Solid waste has become a subject of increasing concern to energy industries for several reasons. Increasingly stringent air and water pollution regulations result in a larger fraction of residuals in the form of solid wastes. Control technologies, particularly flue gas desulfurization, can multiply the amount of waste. With the renewed emphasis on coal utilization and the likelihood of oil shale development, increased amounts of solid waste will be produced. In the past, solid waste residuals used for environmental assessment have tended only to include total quantities generated. To look at environmental impacts, however, data on the composition of the solid wastes are required. Computer modules for calculating the quantities and composition of solid waste from major fossil fuel technologies were therefore developed and are described in this report. Six modules have been produced covering physical coal cleaning, conventional coal combustion with flue gas desulfurization, atmospheric fluidized-bed combustion, coal gasification using the Lurgi process, coal liquefaction using the SRC-II process, and oil shale retorting. Total quantities of each solid waste stream are computed together with the major components and a number of trace elements and radionuclides.

Crowther, M.A.; Thode, H.C. Jr.; Morris, S.C.

1980-10-01T23:59:59.000Z

362

Waste tank 241-SY-101 dome airspace and ventilation system response to a flammable gas plume burn  

SciTech Connect

A series of flammable gas plume burn and transient pressure analyses have been completed for a nuclear waste tank (241-SY-101) and associated tank farm ventilation system at the U.S. Department of Energy`s Hanford facility. The subject analyses were performed to address issues concerning the effects of transient pressures resulting from igniting a small volume of concentrated flammable gas just released from the surface of the waste as a plume and before the flammable gas concentration could be reduced by mixing with the dome airspace by local convection and turbulent diffusion. Such a condition may exist as part of an in progress episode gas release (EGR) or gas plume event. The analysis goal was to determine the volume of flammable gas that if burned within the dome airspace would result in a differential pressure, after propagating through the ventilation system, greater than the current High Efficiency Particulate Filter (HEPA) limit of 2.49 KPa (10 inches of water or 0. 36 psi). Such a pressure wave could rupture the tank ventilation system inlet and outlet HEPA filters leading to a potential release of contaminants to the environment

Heard, F.J.

1995-11-01T23:59:59.000Z

363

Microsoft Word - 41890_PW_Catalytic Combustion_Factsheet_Rev01...  

NLE Websites -- All DOE Office Websites (Extended Search)

Plan and Integration Study for rich catalytic combustion as applied to industrial gas turbines fired on both natural gas and coal derived synthesis gas. The overall goal is...

364

Combustion Analysis of Different Olive Residues  

E-Print Network (OSTI)

Abstract: The Thermogravimetric Analysis (TGA) techniques and concretely the study of the burning profile provide information that can be used to estimate the behaviour of the combustion of carbonous materials. Commonly, these techniques have been used for the study of carbons, but are also interesting for the analysis of biomass wastes, due to the different species present on the wastes affect directly to its thermal properties. In this work, techniques of thermal analysis have been applied to compare the behaviour of different wastes coming from olive oil mills. From these results, it is remarkable that the Concentrated Olive Mill Waste Water (COMWW) presents more unfavourable conditions for its combustion.

Teresa Mir; Alberto Esteban; Sebastián Rojas; Irene Montero; Antonio Ruiz

2008-01-01T23:59:59.000Z

365

Energy from Waste UK Joint Statement on Energy from Waste  

E-Print Network (OSTI)

Energy from Waste UK Joint Statement on Energy from Waste Read more overleaf Introduction Energy from waste provides us with an opportunity for a waste solution and a local source of energy rolled,itcan onlyaddressaportionofthewastestream andisnotsufficientonitsown. Energy obtained from the combustion of residual waste (Energy from

366

NETL: Combustion Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Abbreviations & Acronyms Abbreviations & Acronyms Reference Shelf Solicitations & Awards Abbreviations & Acronyms The Combustion Technologies Product uses a number of abbreviations and acronyms. This web page gives you a definition of frequently used terms, as follows: 1½-Generation PFBC -- A PFBC plant where the hot (about 1400ºF) PFBC exhaust gases are used as a vitiated air supply for a natural gas combustor supplying high-temperature gas (above 2000ºF) to a combustion turbine expander (synonym for "PFB-NGT"). 1st-Generation PFBC -- Commercial PFBC technology where an unfired low-temperature (below 1650ºF) ruggedized turbine expander expands PFBC exhaust gases (synonym for "PFB-EGT"). 2nd-Generation PFBC (see synonyms: "APFBC," "PFB-CGT") -- Advanced PFBC where a carbonizer (mild gasifier) provides hot (about 1400ºF) coal-derived synthetic fuel gas to a special topping combustor. The carbonizer char is burned in the PFBC, and the PFBC exhaust is used as a hot (about 1400ºF) vitiated air supply for the topping combustor. The syngas and vitiated air are burned in a topping combustor to provide high-temperature gas (above 1700ºF) to a combustion turbine expander.

367

NETL: Combustion Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Nebraska Public Power District's Sheldon Station with APFBC Technology Nebraska Public Power District's Sheldon Station with APFBC Technology FBC Repower APFBC AES Greenidge APFBC Dan River FBC, APFBC Four Corners CHIPPS H.F. Lee Products Summary Sheldon Summary APFBC Sheldon GFBCC Sheldon APFBC L.V. Sutton Contents: APFBC Repowering Project Summary Key Features Site Layout Performance Environmental Characteristics Cost Other Combustion Systems Repowering Study Links: A related study is underway that would repower Sheldon Unit 1 and Unit 2 with gasification fluidized-bed combined cycle technology (GFBCC). CLICK HERE to find out more about repowering the Sheldon station with GFBCC instead. APFBC Repowering Project Summary Click on picture to enlarge Advanced circulating pressurized fluidized-bed combustion combined cycle systems (APFBC) are systems with jetting-bed pressurized fluidized-bed (PFB) carbonizer/gasifier and circulating PFBC combustor. The PFB carbonizer and PFBC both operate at elevated pressures (10 to 30 times atmospheric pressure) to provide syngas for operating a gas turbine topping combustor giving high cycle energy efficiency. The remaining char from the PFB carbonizer is burned in the pressurized PFBC. The combustion gas from the PFB also feeds thermal energy to the gas turbine topping combustor. This provides combined cycle plant efficiency on coal by providing the opportunity to generate electricity using both high efficiency gas turbines and steam.

368

The potential for buoyant displacement gas release events in Tank 241-SY-102 after waste transfer from Tank 241-SY-101  

DOE Green Energy (OSTI)

Tank 241-SY-101 (SY-101) is a double-shell, radioactive waste storage tank with waste that, before the recent transfer and water back-dilution operations, was capable of retaining gas and producing buoyant displacement (BD) gas release events (GREs). Some BD GREs caused gas concentrations in the tank headspace to exceed the lower flammability limit (LFL). A BD GRE occurs when a portion of the nonconvective layer retains enough gas to become buoyant, rises to the waste surface, breaks up, and releases some of its stored gas. The installation of a mixer pump in 1993 successfully mitigated gas retention in the settled solids layer in SY-101 and has since prevented BD GREs. However, operation of the mixer pump over the years caused gas retention in the floating crust layer and a corresponding accelerated waste level growth. The accelerating crust growth trend observed in 1997--98 led to initiation of sequences of waste removal and water back-dilutions in December 1999. Waste is removed from the mixed slurry layer in Tank SY-101 and transferred into Tank 241-Sy-102 (SY-102). Water is then added back to dissolve soluble solids that retain gas. The initial transfer of 89,500 gallons of SY-101 waste, diluted in-line at 0.94:1 by volume with water, to SY-102 was conducted in December 1999. The second transfer of 230,000 gallons of original SY-101 waste, diluted approximately 0.9:1, was completed in January 2000, and the third transfer of 205,500 gallons of original SY-101 waste diluted at 0.9:1 was completed in March 2000.

BE Wells; PE Meyer; G Chen

2000-05-10T23:59:59.000Z

369

Controlling fuel and diluent gas flow for a diesel engine operating in the fuel rich low-temperature-combustion mode  

E-Print Network (OSTI)

The flow of a diluent gas supplied to a motoring engine was controlled at a diluent to air mass flow ratios of 10%, 30%, 50%, and 70%. This arrangement was a significant set up for running the engine in the Low-Temperature ...

Lopez, David M

2007-01-01T23:59:59.000Z

370

Wetland treatment of oil and gas well waste waters. Final report  

SciTech Connect

Constructed wetlands are small on-site systems that possess three of the most desirable components of an industrial waste water treatment scheme: low cost, low maintenance and upset resistance. The main objective of the present study is to extend the knowledge base of wetland treatment systems to include processes and substances of particular importance to small, on-site systems receiving oil and gas well wastewaters. A list of the most relevant and comprehensive publications on the design of wetlands for water quality improvement was compiled and critically reviewed. Based on our literature search and conversations with researchers in the private sector, toxic organics such as Phenolics and b-naphthoic acid, (NA), and metals such as CU(II) and CR(VI) were selected as target adsorbates. A total of 90 lysimeters equivalent to a laboratory-scale wetland were designed and built to monitor the uptake and transformation of toxic organics and the immobilization of metal ions. Studies on the uptake of toxic organics such as phenol and b-naphthoic acid (NA) and heavy metals such as Cu(II) and Cr(VI), the latter two singly or as non-stoichiometric mixtures by laboratory-type wetlands (LWs) were conducted. These LWs were designed and built during the first year of this study. A road map and guidelines for a field-scale implementation of a wetland system for the treatment of oil and gas wastewaters have been suggested. Two types of wetlands, surface flow (SF) and sub surface flow (SSF), have been considered, and the relative merits of each configuration have been reviewed.

Kadlec, R.; Srinivasan, K.

1995-08-01T23:59:59.000Z

371

Water-Steel Canister Interaction and H2 Gas Pressure Buildup in aNuclear Waste Repository  

DOE Green Energy (OSTI)

Corrosion of steel canisters, stored in a repository forspent fuel and high-level waste, leads to hydrogen gas generation in thebackfilled emplacement tunnels, which may significantly affect long-termrepository safety. Previous modeling studies used a constant H2generation rate. However, iron corrosion and H2 generation rates varywith time, depending on factors such as water chemistry, wateravailability, and water contact area. To account for these factors andfeedback mechanisms, we developed a chemistry model related to ironcorrosion, coupled with two-phase (liquid and gas) flow phenomena thatare driven by gas pressure buildup and water consumption. Resultsindicate that if H2 generation rates are dynamically calculated based ona chemistry model, the degree and extent of gas pressure buildup are muchsmaller compared to a simulation in which the coupling between flow andreactive transport mechansism is neglected.

Xu, Tianfu; Senger, Rainer; Finstele, Stefan

2007-01-02T23:59:59.000Z

372

SPATIAL AND SEASONAL DISTRIBUTION OF CARBON DIOXIDE EMISSIONS FROM FOSSIL-FUEL COMBUSTION; GLOBAL, REGIONAL, AND NATIONAL POTENTIAL FOR SUSTAINABLE BIOENERGY FROM RESIDUE BIOMASS AND MUNICIPAL SOLID WASTE.  

E-Print Network (OSTI)

??Combustion of fossil fuels releases carbon dioxide (CO2) into the atmosphere, and has led to an increase in the atmospheric concentration of CO2. CO2 is… (more)

Gregg, Jay Sterling

2009-01-01T23:59:59.000Z

373

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

Science Conference Proceedings (OSTI)

This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for all 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 11 days for DSTs (i.e., tank 241-AZ-10l) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 10 days for DSTs (i.e., tank 241-AZ-101) and 34 days for SSTs (i.e., tank 241-B-203).

MEACHAM JE

2009-10-26T23:59:59.000Z

374

STEADY-STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The methodology of flammability analysis for Hanford tank waste is developed. The hydrogen generation rate model was applied to calculate the gas generation rate for 177 tanks. Flammability concentrations and the time to reach 25% and 100% of the lower flammability limit, and the minimum ventilation rate to keep from 100 of the LFL are calculated for 177 tanks at various scenarios.

HU TA

2007-10-26T23:59:59.000Z

375

NETL: Combustion Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Turbines for APFBC Gas Turbines for APFBC FBC Repower Simple Description Detailed Description APFBC Specs GTs for APFBC Suited for Repowering Existing Power Plants with Advanced Pressurized Fluidized-Bed Combined Cycles APFBC combined cycles have high energy efficiency levels because they use modern, high-temperature, high-efficiency gas turbines as the core of a combined power cycle. This web page discusses a current U.S. Department of Energy project that is evaluating combustion turbines suited for repowering existing steam plants. The natural-gas-fueled version of the Siemens Westinghouse Power Corporation W501F. Modified versions of this gas turbine core are suited for operating in APFBC power plants. Contents: Introduction APFBC Repowering Considerations

376

Oxy-Combustion Activities Worldwide  

Science Conference Proceedings (OSTI)

This report reviews oxy-combustion development activities throughout the world. The report opens by reviewing carbon dioxide (CO2) capture technologies and their relative advantages and disadvantages before focusing on oxy-combustion concepts and giving details on potential designs. It then delves into each sub-system (air separation, oxy boiler, gas quality control, and CO2 purification) giving the latest updates on technologies and associated development issues, pulling from work reported at the Second...

2012-06-26T23:59:59.000Z

377

Utilization of ventilation air methane as a supplementary fuel at a circulating fluidized bed combustion boiler  

Science Conference Proceedings (OSTI)

Ventilation air methane (VAM) accounts for 60-80% of the total emissions from underground coal mining activities in China, which is of serious greenhouse gas concerns as well as a waste of valuable fuel sources. This contribution evaluates the use of the VAM utilization methods as a supplementary fuel at a circulating fluidized bed combustion boiler. The paper describes the system design and discusses some potential technical challenges such as methane oxidation rate, corrosion, and efficiency. Laboratory experimentation has shown that the VAM can be burnt completely in circulated fluidized bed furnaces, and the VAM oxidation does not obviously affect the boiler operation when the methane concentration is less than 0.6%. The VAM decreased the incomplete combustion loss for the circulating fluidized bed combustion furnace. The economic benefit from the coal saving insures that the proposed system is more economically feasible. 17 refs., 3 figs., 1 tab.

Changfu You; Xuchang Xu [Tsinghua University, Beijing (China). Key Laboratory for Thermal Science and Power Engineering of Ministry of Education

2008-04-01T23:59:59.000Z

378

Gas turbines fired by solid fuels  

SciTech Connect

Steadily increasing energy requirements have spurred a search for new methods of generating energy from low-cost, abundant fuels. The development of a gas-turbine system equipped for the direct combustion of such fuels is now underway in the U.S. A one-megawatt pilot plant has been operating for over a year, using a fluidized bed to burn coal. The plant has also operated on wood waste and municipal solid waste as fuels. Methods have been developed for the suppression of noxious gases included among the combustion products, but there remain some problems with the removal of particulate matter from the exhaust gas prior to its entry into the turbine. A new high-temperature filter is being installed to alleviate these. A description of the one-megawatt pilot plant is provided, along with a discussion of operational results and mechanical problems and their solutions. A preliminary design for a full-scale plant is included.

Wade, G.L.

1976-01-01T23:59:59.000Z

379

Building materials using binders and solid combustible minerals  

Science Conference Proceedings (OSTI)

Local materials including low-quality solid combustible minerals and their wastes, are being used to cheapen building costs. The author reviews the use of solid combustible minerals and their carbonaceous wastes as nonbaking binders of the lime-pozzolana type in the production of building and other materials.

Gorlov, E.G.

1982-01-01T23:59:59.000Z

380

Hydrogen-Rich Gas Production from Steam Gasification of Palm Oil Wastes Using the Supported Nano-NiO/?-Al2O3 Catalyst  

Science Conference Proceedings (OSTI)

The catalytic steam gasification of palm oil wastes for hydrogen-rich gas production was experimentally investigated in a combined fixed bed reactor using the newly developed nano-NiO/?-Al2O3 catalyst. The results indicated that the nano-NiO/?-Al2O3 ... Keywords: Biomass gasification, palm oil waste, catalyst, hydrogen production

Jianfen Li; Yanfang Yin; Jianjun Liu; Rong Yan

2009-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

NETL: Combustion Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary for the Combustion Program The Combustion Technologies Product promotes the advancement of coal combustion power generation for use in industrial, commercial, and utility...

382

COMBUSTION RESEARCH - FY-1979  

E-Print Network (OSTI)

Optical Measurement of Combustion Products by Zeeman Atomicand T. Hadeishi • . . • . • . • • . • Combustion Sources offrom Pulverized Coal Combustion J. Pennucci, R. Greif, F.

,

2012-01-01T23:59:59.000Z

383

Commercialization of waste gob gas and methane produced in conjunction with coal mining operations. Final report, August 1992--December 1993  

Science Conference Proceedings (OSTI)

The primary objectives of the project were to identify and evaluate existing processes for (1) using gas as a feedstock for production of marketable, value-added commodities, and (2) enriching contaminated gas to pipeline quality. The following gas conversion technologies were evaluated: (1) transformation to liquid fuels, (2) manufacture of methanol, (3) synthesis of mixed alcohols, and (4) conversion to ammonia and urea. All of these involved synthesis gas production prior to conversion to the desired end products. Most of the conversion technologies evaluated were found to be mature processes operating at a large scale. A drawback in all of the processes was the need to have a relatively pure feedstock, thereby requiring gas clean-up prior to conversion. Despite this requirement, the conversion technologies were preliminarily found to be marginally economic. However, the prohibitively high investment for a combined gas clean-up/conversion facility required that REI refocus the project to investigation of gas enrichment alternatives. Enrichment of a gas stream with only one contaminant is a relatively straightforward process (depending on the contaminant) using available technology. However, gob gas has a unique nature, being typically composed of from constituents. These components are: methane, nitrogen, oxygen, carbon dioxide and water vapor. Each of the four contaminants may be separated from the methane using existing technologies that have varying degrees of complexity and compatibility. However, the operating and cost effectiveness of the combined system is dependent on careful integration of the clean-up processes. REI is pursuing Phase 2 of this project for demonstration of a waste gas enrichment facility using the approach described above. This is expected to result in the validation of the commercial and technical viability of the facility, and the refinement of design parameters.

Not Available

1993-12-01T23:59:59.000Z

384

Gas generation and migration studies involving recently generated /sup 238/Pu-contaminated waste for the TRU Waste Sampling Program  

DOE Green Energy (OSTI)

This study is part of the multicontractor TRU Waste Sampling Program. Radiolytically generated gases were vented through a filtering device to determine its effectiveness in maintaining hydrogen concentrations within acceptably safe levels. In the second part of the study measurements were made to determine the ability of these gases, particularly hydrogen, to migrate through a sealed rigid polyethylene drum liner. Void volumes in these drums were found to be generally in excess of 90%. The carbon composite filter was found to satisfactorily vent hydrogen up to moderately high levels of alpha activity in the waste substrate. The sealed 90-mil liner was found to inhibit, but not prevent, the migration of hydrogen and other radiolytically generated gases.

Zerwekh, A.; Warren, J.L.

1986-07-01T23:59:59.000Z

385

Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature range during Coal Combustion  

SciTech Connect

A number basic sorbents based on CaO were synthesized, characterized with novel techniques and tested for sorption of CO{sub 2} and selected gas mixtures simulating flue gas from coal fired boilers. Our studies resulted in highly promising sorbents which demonstrated zero affinity for N{sub 2}, O{sub 2}, SO{sub 2}, and NO very low affinity for water, ultrahigh CO{sub 2} sorption capacities, and rapid sorption characteristics, CO{sub 2} sorption at a very wide temperature range, durability, and low synthesis cost. One of the 'key' characteristics of the proposed materials is the fact that we can control very accurately their basicity (optimum number of basic sites of the appropriate strength) which allows for the selective chemisorption of CO{sub 2} at a wide range of temperatures. These unique characteristics of this family of sorbents offer high promise for development of advanced industrial sorbents for the effective CO{sub 2} removal.

Panagiotis Smirniotis

2002-09-17T23:59:59.000Z

386

Control circuit for combustion systems  

SciTech Connect

A control circuit is described for gas fired burners and the like such as are employed in commercial laundry fabric ironers requiring the energization of a blower motor and the resulting opening of a gas valve and ignition of a gas burner only after an air pressure sensitive switch is actuated through the operation of the blower motor for purging the system of combustible gases.

Kamberg, E.

1981-11-10T23:59:59.000Z

387

1 Copyright 2003 by ASME 17th International Conference on Fluidised Bed Combustion  

E-Print Network (OSTI)

1 Copyright © 2003 by ASME 17th FBC 17th International Conference on Fluidised Bed Combustion May COMBUSTION OF HIGH-PVC SOLID WASTE WITH HCl RECOVERY Loay Saeed, Antti Tohka, Ron Zevenhoven* Helsinki.zevenhoven@hut.fi * Corresponding author ABSTRACT A process for two-stage combustion of high-PVC solid waste with HCl recovery

Zevenhoven, Ron

388

Electricity from coal and utilization of coal combustion by-products  

Science Conference Proceedings (OSTI)

Most electricity in the world is conventionally generated using coal, oil, natural gas, nuclear energy, or hydropower. Due to environmental concerns, there is a growing interest in alternative energy sources for heat and electricity production. The major by-products obtained from coal combustion are fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) materials. The solid wastes produced in coal-fired power plants create problems for both power-generating industries and environmentalists. The coal fly ash and bottom ash samples may be used as cementitious materials.

Demirbas, A. [Sila Science, Trabzon (Turkey)

2008-07-01T23:59:59.000Z

389

Turbulent Combustion in SDF Explosions  

Science Conference Proceedings (OSTI)

A heterogeneous continuum model is proposed to describe the dispersion and combustion of an aluminum particle cloud in an explosion. It combines the gas-dynamic conservation laws for the gas phase with a continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models. It incorporates a combustion model based on the mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the C-4 booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Numerical simulations of the explosion fields from 1.5-g Shock-Dispersed-Fuel (SDF) charge in a 6.6 liter calorimeter were used to validate the combustion model. Then the model was applied to 10-kg Al-SDF explosions in a an unconfined height-of-burst explosion. Computed pressure histories are compared with measured waveforms. Differences are caused by physical-chemical kinetic effects of particle combustion which induce ignition delays in the initial reactive blast wave and quenching of reactions at late times. Current simulations give initial insights into such modeling issues.

Kuhl, A L; Bell, J B; Beckner, V E

2009-11-12T23:59:59.000Z

390

NETL: IEP – Post-Combustion CO2 Emissions Control - Oxy-Combustion Boiler  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxy-Combustion Boiler Material Development Oxy-Combustion Boiler Material Development Project No.: DE-NT0005262 CLICK ON IMAGE TO ENLARGE Foster Wheeler Oxy-combustion CFD Graphic The objectives of this Foster Wheeler Corporation-managed program are to assess the corrosion characteristics of oxy-combustion relative to air-fired combustion; identify the corrosion mechanisms involved; and determine the effects of oxy-combustion on conventional boiler tube materials, conventional protective coatings, and alternative materials and coatings when operating with high to low sulfur coals. The program involves the prediction of oxy-combustion gas compositions by computational fluid dynamic calculations, exposure of coupons of boiler materials and coverings coated with coal ash deposit to simulated oxy-combustion gases in electric

391

Coal Blending for the Reduction of Acid Gas Emissions: A Characterization of the Milling and Combustion Blends of Powder River Basin Coal and Bituminous Coal  

Science Conference Proceedings (OSTI)

This report describes a systematic study of performance and emission parameters from the combustion of Eastern bituminous coal, a Powder River Basin (PRB) coal, and various blends of these two coals. This study also investigated the effects of coal blending on mill performance, combustion, particulate emissions, and various emissions.

2004-09-21T23:59:59.000Z

392

Role of Anti Foam Agent in Gas Retention and Release in Waste ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The Hanford Tank Waste Treatment and Immobilization Plant ( WTP), which is being designed and constructed for the U.S. Department of Energy ...

393

Mechanisms of gas bubble retention and release: results for Hanford Waste Tanks 241-S-102 and 241-SY-103 and single-shell tank simulants  

DOE Green Energy (OSTI)

Research at Pacific Northwest National Laboratory (PNNL) has probed the physical mechanisms and waste properties that contribute to the retention and release of flammable gases from radioactive waste stored in underground tanks at Hanford. This study was conducted for Westinghouse Hanford Company as part of the PNNL Flammable Gas Project. The wastes contained in the tanks are mixes of radioactive and chemical products, and some of these wastes are known to generate mixtures of flammable gases, including hydrogen, nitrous oxide, and ammonia. Because these gases are flammable, their retention and episodic release pose a number of safety concerns.

Gauglitz, P.A.; Rassat, S.D.; Bredt, P.R.; Konynenbelt, J.H.; Tingey, S.M.; Mendoza, D.P.

1996-09-01T23:59:59.000Z

394

Landfill Gas-to-Electricity Demonstration Project  

DOE Green Energy (OSTI)

Medium Btu methane gas is a naturally occurring byproduct of anaerobic digestion of landfilled municipal solid waste. The energy potential of landfill gas in New York State is estimated to be 61 trillion Btu's per year or the equivalent of 10% of the natural gas used annually in the state. The 18-month Landfill Gas-to-Electricity Demonstration Project conducted at the Fresh Kills Landfill in Staten Island, New York conclusively demonstrated that landfill gas is an acceptable fuel for producing electricity using an internal combustion engine/generator set. Landfill gas proved to be a reliable and consistent fuel source during a six-month field test program. Engine exhaust emissions were determined to be comparable to that of natural gas and no unusually high corrosion rates on standard pipeline material were found.

Not Available

1982-10-01T23:59:59.000Z

395

Final Report - Gas Generation Testing of Uranium Metal in Simulated K Basin Sludge and in Grouted Sludge Waste Forms  

DOE Green Energy (OSTI)

The Waste Isolation Pilot Plant (WIPP) is being considered for the disposal of K Basin sludge as RH-TRU. Because the hydrogen gas concentration in the 55-gallon RH-TRU sealed drums to be transported to WIPP is limited by flammability safety, the number of containers and shipments likely will be driven by the rate of hydrogen generated by the uranium metal-water reaction (U + 2 H{sub 2}O {yields} UO{sub 2} + 2 H{sub 2}) in combination with the hydrogen generated from water and organic radiolysis. Gas generation testing was conducted with uranium metal particles of known surface area, in simulated K West (KW) Basin canister sludge and immobilized in candidate grout solidification matrices. This study evaluated potential for Portland cement and magnesium phosphate grouts to inhibit the reaction of water with uranium metal in the sludge and thereby permit higher sludge loading to the disposed waste form. The best of the grouted waste forms decreased the uranium metal-water reaction by a factor of four.

Delegard, Calvin H.; Schmidt, Andrew J.; Sell, Rachel L.; Sinkov, Sergei I.; Bryan, Samuel A.; Gano, Sue; Thornton, Brenda M.

2004-08-19T23:59:59.000Z

396

Coal combustion products: trash or treasure?  

Science Conference Proceedings (OSTI)

Coal combustion by-products can be a valuable resource to various industries. The American Coal Ash Association (ACAA) collects data on production and uses of coal combustion products (CCPs). 122.5 million tons of CCPs were produced in 2004. The article discusses the results of the ACCA's 2004 survey. Fly ash is predominantly used as a substitute for Portland cement; bottom ash for structural fill, embankments and paved road cases. Synthetic gypsum from the FGD process is commonly used in wallboard. Plant owners are only likely to have a buyer for a portion of their CCPs. Although sale of hot water (from Antelope Valley Station) from condensers for use in a fish farm to raise tilapia proved unviable, the Great Plains Synfuels Plant which manufactures natural gas from lignite produces a wide range of products including anhydrous ammonia, phenol, krypton, carbon dioxide (for enhanced oil recovery), tar oils and liquid nitrogen. ACCA's goal is to educate people about CCPs and how to make them into useful products, and market them, in order to reduce waste disposal and enhance revenue. The article lists members of the ACCA. 2 photos., 1 tab.

Hansen, T.

2006-07-15T23:59:59.000Z

397

Co-combustion feasibility study. Final report  

DOE Green Energy (OSTI)

This report investigates the technical and economic feasibility of co-combusting municipal sewage sludge produced by the Saratoga County Sewer District No. 1 with paper mill sludge produced by the Cottrell Paper Company, Encore Paper Company, International Paper Company, Mohawk Paper Mills, and TAGSONS Papers at the Saratoga County Sewer District No. 1`s secondary wastewater treatment plant and recovering any available energy products. The co-combustion facility would consist of sludge and wood chip storage and conveying systems, belt filter presses, screw presses, fluidized-bed incinerators, venturi scrubbers and tray cooling systems, ash dewatering facilities, heat recovery steam generators, gas-fired steam superheaters, and a back-pressure steam turbine system. Clean waste wood chips would be used as an auxiliary fuel in the fluidized-bed incinerators. It is recommended that the ash produced by the proposed facility be beneficially used, potentially as a raw material in the manufacture of cement and/or as an interim barrier layer in landfills.

Handcock, D.J. [Clough, Harbour and Associates, Albany, NY (United States)

1995-01-01T23:59:59.000Z

398

DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION  

SciTech Connect

For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

Panagiotis G. Smirniotis

2005-01-30T23:59:59.000Z

399

Field Test of a Catalytic Combustion System for Non-Ammonia Control of Gas Turbine NOx Emissions  

DOE Green Energy (OSTI)

Under federal Award/Proposal Number DE-FG26-04NT42078, the California Energy Commission (CEC) will subgrant $100,000 to the City of Riverside, California, where the project will be located. In turn, the City of Riverside will subaward the federal funds to Alliance Power and/or Catalytica Energy Systems, Inc. (CESI). Alliance Power will coordinate administrative and management activities associated with this task to ensure compliance with CEC grant requirements. CESI will design and fabricate two Xonon{trademark} modules according to General Electric (GE) specification for operating conditions in the GE-10 gas turbine. CESI will ship the modules to the GE test facility for engine testing. CESI will provide test personnel as required to oversee the installation, testing and removal of the Xonon modules. GE will perform an engine test of the CESI-supplied Xonon modules on a GE-10 test engine in the fall of 2004. GE will record all test data as appropriate to evaluate the emissions and operating performance of the Xonon module. Following the test, GE will provide a letter report of the engine test findings. The letter report shall summarize the testing and provide an assessment of Xonon's ability to ultimately achieve less than 3 ppm NOx emissions on the GE-10. All expenses incurred by GE for this task will be paid by GE; no federal funds will be used. Following the reporting of findings, GE will make a decision whether or not to proceed with the Riverside retrofit project. GE will write a letter to CESI giving their decision. GE and CESI will report of engine test findings and the decision letter to the CEC Project Manager.

James F. Burns

2007-07-31T23:59:59.000Z

400

Field Test of a Catalytic Combustion System for Non-Ammonia Control of Gas Turbine NOx Emissions  

SciTech Connect

Under federal Award/Proposal Number DE-FG26-04NT42078, the California Energy Commission (CEC) will subgrant $100,000 to the City of Riverside, California, where the project will be located. In turn, the City of Riverside will subaward the federal funds to Alliance Power and/or Catalytica Energy Systems, Inc. (CESI). Alliance Power will coordinate administrative and management activities associated with this task to ensure compliance with CEC grant requirements. CESI will design and fabricate two Xonon{trademark} modules according to General Electric (GE) specification for operating conditions in the GE-10 gas turbine. CESI will ship the modules to the GE test facility for engine testing. CESI will provide test personnel as required to oversee the installation, testing and removal of the Xonon modules. GE will perform an engine test of the CESI-supplied Xonon modules on a GE-10 test engine in the fall of 2004. GE will record all test data as appropriate to evaluate the emissions and operating performance of the Xonon module. Following the test, GE will provide a letter report of the engine test findings. The letter report shall summarize the testing and provide an assessment of Xonon's ability to ultimately achieve less than 3 ppm NOx emissions on the GE-10. All expenses incurred by GE for this task will be paid by GE; no federal funds will be used. Following the reporting of findings, GE will make a decision whether or not to proceed with the Riverside retrofit project. GE will write a letter to CESI giving their decision. GE and CESI will report of engine test findings and the decision letter to the CEC Project Manager.

James F. Burns

2007-07-31T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
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401

Novel selective surface flow (SSF{sup TM}) membranes for the recovery of hydrogren from waste gas streams. Final report  

DOE Green Energy (OSTI)

The waste streams are off-gas streams from various chemical/refinery operations. In Phase I, the architecture of the membrane and the separation device were defined and demonstrated. The system consists of a shell-and-tube separator in which the gas to be separated is fed to the tube side, the product is collected as high pressure effluent and the permeate constitutes the waste/fuel stream. Each tube, which has the membrane coated on the interior, does the separation. A multi- tube separator device containing 1 ft{sup 2} membrane area was built and tested. The engineering data were used for designing a process for hydrogen recovery from a fluid catalytic cracker off-gas stream. First-pass economics showed that overall cost for hydrogen production is reduced by 35% vs on-purpose production of hydrogen by steam- methane reforming. The hydrogen recovery process using the SSF membrane results in at least 15% energy reduction and significant decrease in CO{sub 2} and NO{sub x} emissions.

Anand, M. [USDOE, Washington, DC (United States)

1995-08-01T23:59:59.000Z

402

Combustion instability modeling and analysis  

DOE Green Energy (OSTI)

It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors. The present study represents a coordinated effort between industry, government and academia to investigate gas turbine combustion dynamics. Specific study areas include development of advanced diagnostics, definition of controlling phenomena, advancement of analytical and numerical modeling capabilities, and assessment of the current status of our ability to apply these tools to practical gas turbine combustors. The present work involves four tasks which address, respectively, (1) the development of a fiber-optic probe for fuel-air ratio measurements, (2) the study of combustion instability using laser-based diagnostics in a high pressure, high temperature flow reactor, (3) the development of analytical and numerical modeling capabilities for describing combustion instability which will be validated against experimental data, and (4) the preparation of a literature survey and establishment of a data base on practical experience with combustion instability.

Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States); Sheppard, E.J. [Tuskeggee Univ., Tuskegee, AL (United States). Dept. of Aerospace Engineering

1995-12-31T23:59:59.000Z

403

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

Science Conference Proceedings (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

404

The Value of Post-Combustion Carbon Dioxide Capture and Storage Technologies in a World with Uncertain Greenhouse Gas Emissions Constraints  

Science Conference Proceedings (OSTI)

By analyzing how the largest CO2 emitting electricity generating region in the United States, the East Central Area Reliability Coordination Agreement (ECAR), responds to hypothetical constraints on greenhouse gas emissions, the authors demonstrate that there is an enduring role for post combustion CO2 capture technologies. The utilization of pulverized coal with carbon dioxide capture and storage (PC+CCS) technologies is particularly significant in a world where there is significant uncertainty about the future evolution of climate policy and in particular uncertainty about the rate at which the climate policy will become more stringent. The paper’s analysis shows that within this one large, heavily coal-dominated electricity generating region, as much as 20-40 GW of PC+CCS could be in operation before the middle of this century. Depending upon the state of PC+CCS technology development and the evolution of future climate policy, the analysis shows that these CCS systems could be mated to either already existing PC units or PC units that are currently under construction, announced and planned units, as well as PC units that could continue to be built for a number of decades even in the face of a climate policy. In nearly all the cases analyzed here, these PC+CCS generation units are compliments to a much larger deployment of CCS-enabled coal-fired integrated gasification combined cycle (IGCC) power plants. The analysis presented here shows that the combined deployment of PC+CCS and IGCC+CCS units within this one region of the U.S. could result in the potential capture and storage of between 3.2 and 4.9 billion tones of CO2 before the middle of this century in the region’s deep geologic storage formations.

Wise, Marshall A.; Dooley, James J.

2009-01-01T23:59:59.000Z

405

Investigation of flammable gas and thermal safety issues for retrieval of waste from Tank 241-AN-105  

SciTech Connect

The primary purpose of this report is to identify and resolve some of the flammable gas and thermal safety issues potentially associated with the retrieval of waste from Tank 241-AN-105 (AN-105), which is the first double-shell tank scheduled for waste retrieval at Hanford. The planned retrieval scenario includes the following steps in AN-105: (1) degas the tank using two submerged mixing pumps, (2) turn off the mixer pump(s) and allow any suspended solids to settle, (3) decant the supernatant to the intermediate feed staging tank(s) (IFSTs) (AP-102 and/or AP-104) using water/caustic dilution at the transfer pump inlet, (4) add the remaining dilution water/caustic to the slurry remaining in AN-105, (5) mix the tank with the mixer pump(s) until the soluble solids dissolve, (6) turn off the mixer pump(s) and let the insoluble solids settle, and (7) decant the new supernatant to the IFST(s), leaving the insoluble solids behind. Three waste retrieval safety issues are addressed in this report. They are (1) the controlled degassing of AN-105 to ensure that the headspace remains <25% of the lower flammability limit (LFL), (2) an assessment of how dissolved gas (mainly ammonia) released during the transfer of the supernatant in AN-105 to the IFSTs and the water/caustic dilution of the remaining slurry in AN-105 will affect the flammability in these tanks; and (3) an assessment of the maximum waste temperatures that might occur in AN-105 during retrieval operations.

Caley, S.M.; Stewart, C.W.; Antoniak, Z.I.; Cuta, J.M.; Mahoney, L.A.; Panisko, F.E.

1998-09-01T23:59:59.000Z

406

Ma,BonzongoandGao/UniversityofFlorida Characterization and Leachability of Coal Combustion Residues  

E-Print Network (OSTI)

Ma,BonzongoandGao/UniversityofFlorida Characterization and Leachability of Coal Combustion Residues an important solid waste in Florida, i.e., coal combustion residues (CCR) detailed in #2-4 of the current

Ma, Lena

407

Effect of explicit representation of detailed stratigraphy on brine and gas flow at the Waste Isolation Pilot Plant  

Science Conference Proceedings (OSTI)

Stratigraphic units of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) disposal room horizon includes various layers of halite, polyhalitic halite, argillaceous halite, clay, and anhydrite. Current models, including those used in the WIPP Performance Assessment calculations, employ a ``composite stratigraphy`` approach in modeling. This study was initiated to evaluate the impact that an explicit representation of detailed stratigraphy around the repository may have on fluid flow compared to the simplified ``composite stratigraphy`` models currently employed. Sensitivity of model results to intrinsic permeability anisotropy, interbed fracturing, two-phase characteristic curves, and gas-generation rates were studied. The results of this study indicate that explicit representation of the stratigraphy maintains higher pressures and does not allow as much fluid to leave the disposal room as compared to the ``composite stratigraphy`` approach. However, the differences are relatively small. Gas migration distances are also different between the two approaches. However, for the two cases in which explicit layering results were considerably different than the composite model (anisotropic and vapor-limited), the gas-migration distances for both models were negligible. For the cases in which gas migration distances were considerable, van Genuchten/Parker and interbed fracture, the differences between the two models were fairly insignificant. Overall, this study suggests that explicit representation of the stratigraphy in the WIPP PA models is not required for the parameter variations modeled if ``global quantities`` (e.g., disposal room pressures, net brine and gas flux into and out of disposal rooms) are the only concern.

Christian-Frear, T.L.; Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States). Geohydrology Dept.

1996-04-01T23:59:59.000Z

408

Blending of hydrogen in natural gas distribution systems. Volume II. Combustion tests of blends in burners and appliances. Final report, June 1, 1976--August 30, 1977. [8, 11, 14, 20, 22, 25, and 31% hydrogen  

DOE Green Energy (OSTI)

The emerging ''hydrogen economy'' is a strong contender as one method to supplement or extend the domestic natural gas supply. This volume of the subject study ''Blending Hydrogen in Natural Gas Distribution Systems'' describes combustion studies to determine the maximum amount of hydrogen that can be blended in natural gas and utilized satisfactorily in typical appliances with no adjustment or conversion. Eleven pilot burners and twenty-three main burners typical of those in current use were operated on hydrogen-natural gas mixtures containing approximately 8, 11, 14, 20, 22, 25, and 31 percent, by volume, hydrogen. The eleven pilot burners and thirteen main burners were tested outside the appliance they were a part of. Ten main burners were tested in their respective appliances. Performance of the various burners tested are as follows: (1) Gas blends containing more than 6 to 11% hydrogen are the limiting mixtures for target type pilot burners. (2) Gas blends containing more than 20 to 22% hyrogen are the limiting mixtures for main burners operating in the open. (3) Gas blends containing more than 22 to 25% hydrogen are the limiting mixtures for main burners tested in appliances. (4) Modification of the orifice in target pilots or increasing the supply pressure to a minimum of 7 inches water column will permit the use of gas blends with 20% hydrogen.

None

1977-10-01T23:59:59.000Z

409

Microsoft Word - 41776_GE_Fuel Flexible Combustion_Factsheet...  

NLE Websites -- All DOE Office Websites (Extended Search)

A. Objective: Develop a multi-fuel low emission combustor for Vision 21 plant and gas turbine system applications. Combustion system development includes the development of...

410

Combustion Characterization and Modelling of Fuel Blends for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Value (405,990 DOE) COMBUSTION CHARACTERIZATION AND MODELLING OF FUEL BLENDS FOR POWER GENERATION GAS TURBINES University of Central Florida Presentation-Petersen, 1013...

411