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Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
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1

Waste gas combustion in a Hanford radioactive waste tank  

SciTech Connect (OSTI)

It has been observed that a high-level radioactive waste tank generates quantities of hydrogen, ammonia, nitrous oxide, and nitrogen that are potentially well within flammability limits. These gases are produced from chemical and nuclear decay reactions in a slurry of radioactive waste materials. Significant amounts of combustible and reactant gases accumulate in the waste over a 110- to 120-d period. The slurry becomes Taylor unstable owing to the buoyancy of the gases trapped in a matrix of sodium nitrate and nitrite salts. As the contents of the tank roll over, the generated waste gases rupture through the waste material surface, allowing the gases to be transported and mixed with air in the cover-gas space in the dome of the tank. An ignition source is postulated in the dome space where the waste gases combust in the presence of air resulting in pressure and temperature loadings on the double-walled waste tank. This analysis is conducted with hydrogen mixing studies HMS, a three-dimensional, time-dependent fluid dynamics code coupled with finite-rate chemical kinetics. The waste tank has a ventilation system designed to maintain a slight negative gage pressure during normal operation. We modeled the ventilation system with the transient reactor analysis code (TRAC), and we coupled these two best-estimate accident analysis computer codes to model the ventilation system response to pressures and temperatures generated by the hydrogen and ammonia combustion.

Travis, J.R.; Fujita, R.K.; Spore, J.W.

1994-07-01T23:59:59.000Z

2

Comparing the greenhouse gas emissions from three alternative waste combustion concepts  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Significant GHG reductions are possible by efficient WtE technologies. Black-Right-Pointing-Pointer CHP and high power-to-heat ratio provide significant GHG savings. Black-Right-Pointing-Pointer N{sub 2}O and coal mine type are important in LCA GHG emissions of FBC co-combustion. Black-Right-Pointing-Pointer Substituting coal and fuel oil by waste is beneficial in electricity and heat production. Black-Right-Pointing-Pointer Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO{sub 2}-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

Vainikka, Pasi, E-mail: pasi.vainikka@vtt.fi [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Tsupari, Eemeli; Sipilae, Kai [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Hupa, Mikko [Aabo Akademi Process Chemistry Centre, Piispankatu 8, FIN 20500 Turku (Finland)

2012-03-15T23:59:59.000Z

3

Municipal Waste Combustion (New Mexico)  

Broader source: Energy.gov [DOE]

This rule establishes requirements for emissions from, and design and operation of, municipal waste combustion units. "Municipal waste" means all materials and substances discarded from residential...

4

Combustion and performance of a diesel engine with preheated Jatropha curcas oil using waste heat from exhaust gas  

Science Journals Connector (OSTI)

Abstract The viscosity and density of CJO (crude Jatropha oil) were reduced by heating it using the heat from exhaust gas of a diesel engine with an appropriately designed helical coil heat exchanger. Experiments were conducted to evaluate the combustion characteristics of a DI (direct injection) diesel engine using PJO (preheated Jatropha oil). It exhibited a marginally higher cylinder gas pressure, rate of pressure rise and heat release rate as compared to HSD (high speed diesel) during the initial stages of combustion for all engine loadings. Ignition delay was shorter for PJO as compared to HSD. The results also indicated that BSFC (brake specific fuel consumption) and EGT (exhaust gas temperature) increased while BTE (brake thermal efficiency) decreased with PJO as compared to HSD for all engine loadings. The reductions in CO2 (carbon dioxide), HC (hydrocarbon) and \\{NOx\\} (nitrous oxide) emissions were observed for PJO along with increased CO (carbon monoxide) emission as compared to those of HSD.

Priyabrata Pradhan; Hifjur Raheman; Debasish Padhee

2014-01-01T23:59:59.000Z

5

Fluid-bed combustion of solid wastes  

SciTech Connect (OSTI)

For over ten years combustion Power Company has been conducting experimental programs and developing fluid bed systems for agencies of the federal government and for private industry and institutions. Many of these activities have involved systems for the combustion of solid waste materials. Discussed here will be three categories of programs, development of Municipal Solid Waste (MSW) fired fluid beds, development of wood waste fired fluid beds, and industrial installations. Research and development work on wood wastes has led to the design and construction of two large industrial fluid bed combustors. In one of these, a fluid bed is used for the generation of steam with a fuel that was previously suited only for landfill. Rocks and inerts are continuously removed from this combustor using a patented system. The second FBC is designed to use a variety of fuels as the source of energy to dry hog fuel for use in a high performance power boiler. Here the FBC burns green hog fuel, log yard debris, fly ash (char) from the boiler, and dried wood fines to produce a hot gas system for the wood dryer. A significant advantage of the fluidized bed reactor over conventional incinerators is its ability to reduce noxious gas emission and, finally, the fluidized bed is unique in its ability to efficiently consume low quality fuels. The relatively high inerts and moisture content of solid wastes pose no serious problem and require no associated additional devices for their removal.

Vander Molen, R.H.

1980-01-01T23:59:59.000Z

6

Estimating heat of combustion for waste materials  

SciTech Connect (OSTI)

Describes a method of estimating the heat of combustion of hydrocarbon waste (containing S,N,Q,C1) in various physical forms (vapor, liquid, solid, or mixtures) when the composition of the waste stream is known or can be estimated. Presents an equation for predicting the heat of combustion of hydrocarbons containing some sulfur. Shows how the method is convenient for estimating the heat of combustion of a waste profile as shown in a sample calculation.

Chang, Y.C.

1982-11-01T23:59:59.000Z

7

Haraldrud Municipal Solid Waste Combustion Plant in Oslo.  

E-Print Network [OSTI]

??This thesis has studied Haraldrud MSW combustion process. Haraldrud is a realcombustion plant burning waste for citizens of Oslo. A thoroughly description ofthe combustion process… (more)

Gudim, Simen Johan

2011-01-01T23:59:59.000Z

8

Nitrogen oxides reduction by staged combustion of LCV gas  

E-Print Network [OSTI]

to the high nitrogen content (1-2%) of the agricultural wastes, burning of the LCV gas derived from them can result in NO?emissions in excess of 2000 ppm. NO?emissions during combustion of LCV gas derived from gasification of cotton gin trash have been.... Wayne A. LePori for serving on my committee and for the advice and time he offer me. His experience on gasification and combustion of LCV gas was an invaluable source. I appreciate Dr. Mario A. Colaluca for serving on my committee and for his help...

Cabrera Sixto, Jose Manuel

2012-06-07T23:59:59.000Z

9

Trash or treasure? Putting coal combustion waste to work  

SciTech Connect (OSTI)

The use of coal combustion wastes from power plants in construction materials, leaching and the impact of regulations are discussed.

Tenenbaum, D.J.

2009-11-15T23:59:59.000Z

10

Gasification characteristics of combustible wastes in a 5 ton/day fixed bed gasifier  

Science Journals Connector (OSTI)

The gasification characteristics of combustible wastes were determined in ... To capture soot or unburned carbon from the gasification reaction, solid/gas separator and water fluidized...2: 10.7%, CH4: 6.0%, CO2:...

See Hoon Lee; Kyong Bin Choi; Jae Goo Lee…

2006-07-01T23:59:59.000Z

11

Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines...  

Broader source: Energy.gov (indexed) [DOE]

Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines Discusses a novel TEG which utilizes a...

12

Gas turbine alternative fuels combustion characteristics  

SciTech Connect (OSTI)

An experimental investigation was conducted to obtain combustion performance and exhaust pollutant concentrations for specific synthetic hydrocarbon fuels. Baseline comparison fuels used were gasoline and diesel fuel number two. Testing was done over a range of fuel to air mass ratios, total mass flow rates, and input combustion air temperatures in a flame-tube-type gas turbine combustor. Test results were obtained in terms of released heat and combustion gas emission values. The results were comparable to those obtained with the base fuels with variations being obtained with changing operating conditions. The release of carbon particles during the tests was minimal. 22 refs., 12 figs., 2 tabs.

Rollbuhler, R.J.

1989-02-01T23:59:59.000Z

13

Combustion of Low-Calorific Waste Biomass Syngas  

Science Journals Connector (OSTI)

The industrial combustion chamber designed for burning low-calorific syngas from gasification of waste biomass is presented. ... chips and turkey feathers the non-premixed turbulent combustion in the chamber is s...

Kamil Kwiatkowski; Marek Dudy?ski; Konrad Bajer

2013-12-01T23:59:59.000Z

14

Nonlinear Model Predictive Control of Municipal Solid Waste Combustion Plants  

E-Print Network [OSTI]

. Also, the energy that results from waste combustion is often used to produce heat and/or electricityNonlinear Model Predictive Control of Municipal Solid Waste Combustion Plants M. Leskens , R.h.Bosgra@tudelft.nl, p.m.j.vandenhof@tudelft.nl Keywords : nonlinear model predictive control, municipal solid waste

Van den Hof, Paul

15

Particulate Waste Product Combustion System  

E-Print Network [OSTI]

. The introduction of fuels with high ash or silica content into burn.ers have produced problems of fly ash in the exhaust stream causing extensive darrage to boilers f1red by th gasification process. For exanple, the contlus ioo of the rice hull pre sents a... manner using underfire and overflre air to support fficient gasification of the by product, which results ln he pro:Juction of a c~ bustible gas mixture characteristic of organic sub- stances. Intro:Juction of the fuel stock into t cQ1mustion chamber...

King, D. R.; Chastain, C. E.

1984-01-01T23:59:59.000Z

16

Computational Fluid Dynamics Evaluation of Good Combustion Performance in Waste Incinerators  

E-Print Network [OSTI]

a legal requirement to minimize pollution in municipal solid waste incinerators. The conditions for in-furnace destruction of pollutants are stated as: good combustion is achieved when 2-second gas residence time at 850 C of potential pollutants. The residence time needs to be carefully determined based on the gas inlet position

Kim, Yong Jung

17

Combustible radioactive waste treatment by incineration and chemical digestion  

SciTech Connect (OSTI)

A review is given of present and planned combustible radioactive waste treatment systems in the US. Advantages and disadvantages of various systems are considered. Design waste streams are discussed in relation to waste composition, radioactive contaminants by amount and type, and special operating problems caused by the waste.

Stretz, L.A.; Crippen, M.D.; Allen, C.R.

1980-05-28T23:59:59.000Z

18

Premixed Combustion of Hydrogen Augmented Natural Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Premixed Combustion of Hydrogen Premixed Combustion of Hydrogen Augmented Natural Gas * Lean premixed combustion * Effective for emission reduction with natural gas * High hydrogen flame speed requires care in premixer design for SGH fuels * UC Irvine study quantifies effectiveness of hydrogen augmentation strategy * Lean stability limit improves linearly with hydrogen augmentation * Emissions reduction can be achieved * Two OEM's and the California Energy Commission have used the results to help guide them on adapting to hydrogen fuel UC Irvine Scott Samuelsen / Vince McDonell Project 98-01-SR062 1200 1300 1400 1500 1600 1700 1800 1900 0 10 20 30 40 50 60 Hydrogen Volume in Main Fuel (%) Adiabatic Flame Temperature (K) P0(3/4) High Stability High Stability Low emission Low emission operational zone operational zone

19

An investigation into the feasibility of an external combustion, steam injected gas turbine  

E-Print Network [OSTI]

output of the turbine without increasing the work required for compression. Second, the steam may be generated with waste 15 heat from the combustion process. In an internal combustion gas turbine, this would result in an increased work output per... which are: 1. Gas Turbine Engine 2. Heat Exchanger Unit 3. Steam Generator Unit 4. Dynamometer 26 A detailed description of the equipment used in the experiment will be presented in the section entitled Ap- paratus since the purpose...

Ford, David Bruce

2012-06-07T23:59:59.000Z

20

Combustion Exhaust Gas Heat to Power usingThermoelectric Engines...  

Broader source: Energy.gov (indexed) [DOE]

Solutions Combustion Exhaust Gas Heat to Power using Thermoelectric Engines John LaGrandeur October 5, 2011 Advanced Thermoelectric Solutions - 1 - Market motivation based on CO 2...

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Coal/waste cofiring: International survey of combustion practices  

SciTech Connect (OSTI)

Coal is an abundant fuel resource worldwide with an historically stable price. The use of coal is expected to increase, particularly in developing countries; and, as industrialization increases, so will the amount of various waste materials and the environmental problems associated with their disposal. Therefore, coal/waste cofiring can offer an environmentally sound, economic approach to both waste remediation and energy production. This paper highlights the results of an international survey of coal/waste cofiring by describing the principal wastes used and the combustion technologies employed. Also provided are examples of cofiring and areas where cofired fuel parameters will have an effect on boiler performance.

Harding, N.S.; Smouse, S.M.; Ekmann, J.M.; Winslow, J.S. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center; Ramezan, M. [Burns and Roe Services Corp., Pittsburgh, PA (United States)

1996-12-31T23:59:59.000Z

22

Process aspects in combustion and gasification Waste-to-Energy (WtE) units  

Science Journals Connector (OSTI)

Abstract The utilisation of energy in waste, Waste to Energy (WtE), has become increasingly important. Waste is a wide concept, and to focus, the feedstock dealt with here is mostly municipal solid waste. It is found that combustion in grate-fired furnaces is by far the most common mode of fuel conversion compared to fluidized beds and rotary furnaces. Combinations of pyrolysis in rotary furnace or gasification in fluidized or fixed bed with high-temperature combustion are applied particularly in Japan in systems whose purpose is to melt ashes and destroy dioxins. Recently, also in Japan more emphasis is put on WtE. In countries with high heat demand, WtE in the form of heat and power can be quite efficient even in simple grate-fired systems, whereas in warm regions only electricity is generated, and for this product the efficiency of boilers (the steam data) is limited by corrosion from the flue gas. However, combination of cleaned gas from gasification with combustion provides a means to enhance the efficiency of electricity production considerably. Finally, the impact of sorting on the properties of the waste to be fed to boilers or gasifiers is discussed. The description intends to be general, but examples are mostly taken from Europe.

Bo Leckner

2014-01-01T23:59:59.000Z

23

Polybrominated diphenyl ethers in combusted residues and soils from an open burning site of electronic wastes  

Science Journals Connector (OSTI)

Polybrominated diphenyl ethers (PBDEs) are ubiquitous environmental contaminants due to their extensive use. Combusted residue from electronic waste (e-waste) combustion is one of the contamination sources ... tr...

Qian Luo; Ming Hong Wong; Zijian Wang; Zongwei Cai

2013-08-01T23:59:59.000Z

24

Understanding and Control of Combustion Dynamics in Gas Turbine Combustors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Control of Combustion Understanding and Control of Combustion Control of Combustion Understanding and Control of Combustion Dynamics in Gas Turbine Combustors Dynamics in Gas Turbine Combustors Georgia Institute of Technology Georgia Institute of Technology Ben T. Zinn, Tim Lieuwen, Yedidia Neumeier, and Ben Bellows SCIES Project 02-01-SR095 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (05/01/2002, 36 Month Duration) $452,695 Total Contract Value CLEMSONPRES.PPT, 10/28/2003, B.T. ZINN, T. LIEUWEN, Y. NEUMEIER Gas Turbine Need Gas Turbine Need * Need: Gas turbine reliability and availability is important factor affecting power plant economics - Problem: Combustion driven oscillations severely reduce part life, requiring substantially more frequent outages

25

Fluid Bed Combustion Applied to Industrial Waste  

E-Print Network [OSTI]

of its relatively recent application to coal fired steam production, fluid beds have been uti lized in industry for over 60 years. Beginning in Germany in the twenties for coal gasification, the technology was applied to catalytic cracking of heavy... system cost), use of minimum excess air required, and maintaining the min"imum reactor temperature neces sary to sustain combustion. For superautogenous fuels, where incineration. only is desired, minimum capital cost is achieved by using direct bed...

Mullen, J. F.; Sneyd, R. J.

26

Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II Title Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II Publication Type Report LBNL Report Number LBNL-6193E Year of Publication 2013 Authors Rapp, Vi H., Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray Date Published 04/2013 Abstract VENT-II is a computer program designed to provide detailed analysis of natural draft and induced draft combustion appliance vent-systems (i.e., furnace or water heater). This program is capable of predicting house depressurization thresholds that lead to backdrafting and spillage of combustion appliances; however, validation reports of the program being applied for this

27

Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same  

DOE Patents [OSTI]

A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste, and method for producing the same, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces.

Burnet, George (Ames, IA); Gokhale, Ashok J. (College Station, TX)

1990-07-10T23:59:59.000Z

28

Electrical Control of Gas Flows in Combustion Processes  

Science Journals Connector (OSTI)

...research-article Electrical Control of Gas Flows in Combustion Processes J. Lawton P. J. Mayo F. J. Weinberg The theory...where they can be used to modify a variety of combustion processes. Theoretical maximum values of the flow parameters...

1968-01-01T23:59:59.000Z

29

GAS TURBINE REHEAT USING IN SITU COMBUSTION  

SciTech Connect (OSTI)

In situ reheat is an alternative to traditional gas turbine reheat design in which fuel is fed through airfoils rather than in a bulky discrete combustor separating HP and LP turbines. The goals are to achieve increased power output and/or efficiency without higher emissions. In this program the scientific basis for achieving burnout with low emissions has been explored. In Task 1, Blade Path Aerodynamics, design options were evaluated using CFD in terms of burnout, increase of power output, and possible hot streaking. It was concluded that Vane 1 injection in a conventional 4-stage turbine was preferred. Vane 2 injection after vane 1 injection was possible, but of marginal benefit. In Task 2, Combustion and Emissions, detailed chemical kinetics modeling, validated by Task 3, Sub-Scale Testing, experiments, resulted in the same conclusions, with the added conclusion that some increase in emissions was expected. In Task 4, Conceptual Design and Development Plan, Siemens Westinghouse power cycle analysis software was used to evaluate alternative in situ reheat design options. Only single stage reheat, via vane 1, was found to have merit, consistent with prior Tasks. Unifying the results of all the tasks, a conceptual design for single stage reheat utilizing 24 holes, 1.8 mm diameter, at the trailing edge of vane 1 is presented. A development plan is presented.

D.M. Bachovchin; T.E. Lippert; R.A. Newby P.G.A. Cizmas

2004-05-17T23:59:59.000Z

30

Emission of nanoparticles during combustion of waste biomass in fireplace  

Science Journals Connector (OSTI)

Contamination of air by solid particles is serious problem for human health and also environment. Small particles in nano-sizes are more dangerous than same weight of larger size. Negative effect namely of the solid particles depends on (i) number (ii) specific surface area (iii) respirability and (iv) bonding of others substances (e.g. PAHs As Cd Zn Cu etc.) which are higher for smaller (nano-sizes) particles compared to larger one. For this reason mentioned above this contribution deals with measuring of amount and distribution of nanoparticles produced form combustion of waste city biomass in small combustion unit with impactor DLPI.

2014-01-01T23:59:59.000Z

31

Simplified method for determining heat of combustion of natural gas  

SciTech Connect (OSTI)

A simplified technique for determination of the heat of combustion of natural gas has been developed. It is a variation of the previously developed technique wherein the carrier air, in which the test sample was burnt, was oxygen enriched to adjust the mole fraction of oxygen in the combustion product gases up to that in the carrier air. The new technique eliminates the need for oxygen enrichment of the experimental mixtures and natural gas samples and has been found to predict their heats of combustion to an uncertainty of the order of 1 percent.

Singh, J.J.; Chegini, H.; Mall, G.H.

1987-04-01T23:59:59.000Z

32

Understanding pulverised coal, biomass and waste combustion – A brief overview  

Science Journals Connector (OSTI)

Abstract Pulverised coal (PC) firing has been the dominant technology for generating power in utility boilers for almost a century. During this period, boiler designs have evolved through an accumulating collection of knowledge that has led to many empirical relationships that still guide current and future design directions to some degree. In the late 1940s the developed nations began to undertake coal research based on scientific principles to ensure the most efficient use of the primary energy resource represented by coal. As the body of scientific knowledge on the physics and chemistry of coal combustion grew, it was used to direct the improvements to efficiency required and, later, the control of pollutants produced during the combustion of coal. This involves not only the control of emissions of particulates, \\{SOx\\} and oxides of nitrogen but also of trace elements, polycyclic aromatic hydrocarbons and, importantly, CO2. There have been a number of significant developments in the coal-fired power generation sector including cofiring with secondary fuels, particularly biomass and waste, and the development of radically different combustion systems (for example, oxyfuel) to meet carbon capture and storage requirements. Each of these developments has impacted upon the way in which PC-fired boilers are configured and operated and further complicated an already complex combustion environment. This paper outlines the developments in PC combustion and the new techniques that have been developed to enhance our understanding of the processes involved. The paper is based on a comprehensive IEA Clean Coal Centre study “Understanding pulverised coal, biomass and waste combustion”. Ian Barnes, CCC/205 ISBN 978-92-9029-525-9, September 2012.

D. Ian Barnes

2014-01-01T23:59:59.000Z

33

Balancing act creating the right regulation for coal combustion waste  

SciTech Connect (OSTI)

The December 2008 collapse of a coal ash pond in Tennessee threw safe management of coal combustion waste (CCW) into the spotlight. Millions of tons of CCW are produced in the United States each year, and a large percentage of that is recycled. The US Environmental Protection Agency is pursuing a host of initiatives that could directly or indirectly affect the disposition of CCW. States, too, are taking a look at how they regulate CCW. Among the options is the possibility of regulating CCW under the Resource Conservation and Recovery Act, a move that could have far-reaching implications for both the recycling and the disposal of this waste.

Manuel, J.

2009-11-15T23:59:59.000Z

34

Large bore natural gas engine performance improvements and combustion stabilization through reformed natural gas precombustion chamber fueling.  

E-Print Network [OSTI]

??Lean combustion is a standard approach used to reduce NOx emissions in large bore natural gas engines. However, at lean operating points, combustion instabilities and… (more)

Ruter, Matthew D.

2010-01-01T23:59:59.000Z

35

A 25 kWe low concentration methane catalytic combustion gas turbine prototype unit  

Science Journals Connector (OSTI)

Abstract Low concentration methane, emitted from various industries e.g. coal mines and landfills into atmosphere, is not only an important greenhouse gas, but also a wasted energy resource if not utilized. In the past decade, we have been developing a novel VAMCAT (ventilation air methane catalytic combustion gas turbine) technology. This turbine technology can be used to mitigate methane emissions for greenhouse gas reduction, and also to utilize the low concentration methane as an energy source. This paper presents our latest research results on the development and demonstration of a 25 kWe lean burn catalytic combustion gas turbine prototype unit. Recent experimental results show that the unit can be operated with 0.8 vol% of methane in air, producing about 19–21 kWe of electricity output.

Shi Su; Xinxiang Yu

2014-01-01T23:59:59.000Z

36

Flashback Detection Sensor for Hydrogen Augmented Natural Gas Combustion  

SciTech Connect (OSTI)

The use of hydrogen augmented fuel is being investigated by various researchers as a method to extend the lean operating limit, and potentially reduce thermal NOx formation in natural gas fired lean premixed (LPM) combustion systems. The resulting increase in flame speed during hydrogen augmentation, however, increases the propensity for flashback in LPM systems. Real-time in-situ monitoring of flashback is important for the development of control strategies for use of hydrogen augmented fuel in state-of-the-art combustion systems, and for the development of advanced hydrogen combustion systems. The National Energy Technology Laboratory (NETL) and Woodward Industrial Controls are developing a combustion control and diagnostics sensor (CCADS), which has already been demonstrated as a useful sensor for in-situ monitoring of natural gas combustion, including detection of important combustion events such as flashback and lean blowoff. Since CCADS is a flame ionization sensor technique, the low ion concentration produced in pure hydrogen combustion raises concerns of whether CCADS can be used to monitor flashback in hydrogen augmented combustion. This paper discusses CCADS tests conducted at 0.2-0.6 MPa (2-6 atm), demonstrating flashback detection with fuel compositions up to 80% hydrogen (by volume) mixed with natural gas. NETL’s Simulation Validation (SimVal) combustor offers full optical access to pressurized combustion during these tests. The CCADS data and high-speed video show the reaction zone moves upstream into the nozzle as the hydrogen fuel concentration increases, as is expected with the increased flame speed of the mixture. The CCADS data and video also demonstrate the opportunity for using CCADS to provide the necessary in-situ monitor to control flashback and lean blowoff in hydrogen augmented combustion applications.

Thornton, J.D.; Chorpening, B.T.; Sidwell, T.; Strakey, P.A.; Huckaby, E.D.; Benson, K.J. (Woodward)

2007-05-01T23:59:59.000Z

37

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Patents [OSTI]

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

38

Solid fuel combustion system for gas turbine engine  

DOE Patents [OSTI]

A solid fuel, pressurized fluidized bed combustion system for a gas turbine engine includes a carbonizer outside of the engine for gasifying coal to a low Btu fuel gas in a first fraction of compressor discharge, a pressurized fluidized bed outside of the engine for combusting the char residue from the carbonizer in a second fraction of compressor discharge to produce low temperature vitiated air, and a fuel-rich, fuel-lean staged topping combustor inside the engine in a compressed air plenum thereof. Diversion of less than 100% of compressor discharge outside the engine minimizes the expense of fabricating and maintaining conduits for transferring high pressure and high temperature gas and incorporation of the topping combustor in the compressed air plenum of the engine minimizes the expense of modifying otherwise conventional gas turbine engines for solid fuel, pressurized fluidized bed combustion.

Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN)

1993-01-01T23:59:59.000Z

39

Toolbox Safety Talk Waste Anesthetic Gas (WAG)  

E-Print Network [OSTI]

Toolbox Safety Talk Waste Anesthetic Gas (WAG) Environmental Health & Safety Facilities Safety-in sheet to Environmental Health & Safety for recordkeeping. Anesthetic gas and vapors that leak into the surrounding room during medical or research procedures are considered waste anesthetic gas (WAG). These gases

Pawlowski, Wojtek

40

Exhaust gas recirculation system for an internal combustion engine  

DOE Patents [OSTI]

An exhaust gas recirculation system for an internal combustion engine comprises an exhaust driven turbocharger having a low pressure turbine outlet in fluid communication with an exhaust gas conduit. The turbocharger also includes a low pressure compressor intake and a high pressure compressor outlet in communication with an intake air conduit. An exhaust gas recirculation conduit fluidly communicates with the exhaust gas conduit to divert a portion of exhaust gas to a low pressure exhaust gas recirculation branch extending between the exhaust gas recirculation conduit and an engine intake system for delivery of exhaust gas thereto. A high pressure exhaust gas recirculation branch extends between the exhaust gas recirculation conduit and the compressor intake and delivers exhaust gas to the compressor for mixing with a compressed intake charge for delivery to the intake system.

Wu, Ko-Jen

2013-05-21T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Cylinder wall waste heat recovery from liquid-cooled internal combustion engines utilizing thermoelectric generators.  

E-Print Network [OSTI]

?? This report is a dissertation proposal that focuses on the energy balance within an internal combustion engine with a unique coolant-based waste heat recovery… (more)

Armstead, John Randall

2012-01-01T23:59:59.000Z

42

Gaseous emissions during concurrent combustion of biomass and non-recyclable municipal solid waste  

Science Journals Connector (OSTI)

Biomass and municipal solid waste offer sustainable sources ... form of combined cooling, heat and power. Combustion of biomass has a lesser impact than solid fossil ... an integrated, sustainable waste managemen...

René Laryea-Goldsmith; John Oakey; Nigel J Simms

2011-02-01T23:59:59.000Z

43

Enhanced Efficiency of Internal Combustion Engines By Employing Spinning Gas  

SciTech Connect (OSTI)

The efficiency of the internal combustion engine might be enhanced by employing spinning gas. A gas spinning at near sonic velocities has an effectively higher heat capacity, which allows practical fuel cycles, which are far from the Carnot efficiency, to approach more closely the Carnot efficiency. A gain in fuel efficiency of several percent is shown to be theoretically possible for the Otto and Diesel cycles. The use of a flywheel, in principle, could produce even greater increases in the efficiency.

Geyko, Vasily; Fisch, Nathaniel

2014-02-27T23:59:59.000Z

44

Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...  

Broader source: Energy.gov (indexed) [DOE]

Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Presents successful...

45

Near-zero Emissions Oxy-combustion Flue Gas Purification  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Near-zero Emissions Oxy-combustion Near-zero Emissions Oxy-combustion Flue Gas Purification Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions & Capture (EPEC) R&D Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D Program portfolio of post- and

46

Combustion of high-sulfur coal and anthracite wastes in a rotary kiln combustor with an advanced internal air distributor  

SciTech Connect (OSTI)

Fluid bed combustors have received extensive testing with both high-sulfur coal and anthracite wastes. Rotary kilns are effective and popular devices for waste combustion. The Angelo Rotary Furnace{trademark} has been developed to improve the operation of rotary pyrolyzer/combustor systems through enhanced air distribution, which in this process is defined as staged, swirled combustion air injection. Fourteen of these new furnaces have been installed worldwide. Two units in Thailand, designed for rice hull feed with occasional lignite feed, have been recently started up. An older unit in Pennsylvania is being upgraded with a new, more advanced air distribution system for a series of tests this fall in which inexpensive high-sulfur coal and anthracite wastes will be fired with limestone. The purposes of these tests are to determine the burning characteristics of these two fuels in this system, to discover the Ca/S ratios necessary for operation of a rotary kiln combusting these fuels, and to observe the gas-borne emissions from the furnace. An extensive preliminary design study will be performed on a commercial installation for combustion of anthracite wastes. 14 refs., 5 figs., 1 tab.

Cobb, J.T. Jr. (Pittsburgh Univ., PA (USA)); Ahn, Y.K. (Gilbert/Commonwealth, Inc., Reading, PA (USA)); Angelo, J.F. (Universal Energy International, Inc., Little Rock, AR (USA))

1990-01-01T23:59:59.000Z

47

Carbon and Hydrogen Analyses of the Components of a Mixture Utilizing Separation-Combustion Gas Chromatography  

Science Journals Connector (OSTI)

......Utilizing Separation-Combustion Gas Chromatography...temperature copper oxide combustion tube which feeds...solution of brominated hydrocarbons (1% v/v) in...was passed into a combustion tube. Following...Wisconsin) was used to heat the combustion tube...indi- cated by the data of Table II. The......

Sam N. Pennington; Harry D. Brown

1968-10-01T23:59:59.000Z

48

Exhaust gas recirculation for advanced diesel combustion cycles  

Science Journals Connector (OSTI)

Abstract Modern diesel engines tend to utilize significantly large quantities of exhaust gas recirculation (EGR) and high intake pressures across the engine load range to meet \\{NOx\\} targets. At such high EGR rates, the combustion process and exhaust emissions tend to exhibit a marked sensitivity to small changes in the EGR quantity, resulting in unintended deviations from the desired engine performance characteristics (energy efficiency, emissions, stability). An accurate estimation of EGR and its effect on the intake dilution are, therefore, necessary to enable its application during transient engine operation or unstable combustion regimes. In this research, a detailed analysis that includes estimation of the transient (cycle-by-cycle) build-up of EGR and the time (engine cycles) required to reach the steady-state EGR operation has been carried out. One-step global equations to calculate the transient and steady-state gas concentrations in the intake and exhaust are proposed. The effects of engine load and intake pressure on EGR have been examined and explained in terms of intake charge dilution and in-cylinder excess-air ratio. The EGR analysis is validated against a wide range of empirical data that include low temperature combustion cycles, intake pressure and load sweeps. This research intends to not only formulate a clear understanding of EGR application for advanced diesel combustion but also to set forth guidelines for transient analysis of EGR.

Usman Asad; Ming Zheng

2014-01-01T23:59:59.000Z

49

Waste-gas C02 feeds algae  

Science Journals Connector (OSTI)

Waste-gas C02 feeds algae ... The new scheme calls for algae found growing on highly alkaline shallow ponds in Central Africa to metabolize carbon dioxide in waste gases to produce highprotein food. ... IFF has been studying the blue-green algae since the beginning of 1963. ...

1966-07-18T23:59:59.000Z

50

New Developments in Closed Loop Combustion Control Using Flue Gas Analysis  

E-Print Network [OSTI]

New developments in closed loop combustion control are causing radical changes in the way combustion control systems are implemented. The recent availability of in line flue gas analyzers and microprocessor technology are teaming up to produce...

Nelson, R. L.

1981-01-01T23:59:59.000Z

51

Development and test of combustion chamber for Stirling engine heated by natural gas  

Science Journals Connector (OSTI)

The combustion chamber is an important component for the Stirling engine heated by natural gas. In the paper ... , we develop a combustion chamber for the Stirling engine which aims to generate 3?5 kWe...electric...

Tie Li; Xiange Song; Xiaohong Gui; Dawei Tang; Zhigang Li…

2014-04-01T23:59:59.000Z

52

Study on HCl removal for medical waste pyrolysis and combustion using a TG-FTIR analyzer  

Science Journals Connector (OSTI)

Under both pyrolysis and combustion condition, HCl removal efficiency for medical waste with Cabased additives was semi-quantitatively studied by means of ... TG-FTIR. Additionally, the difference of HCl removal ...

Hongmei Zhu; Weiying Chen; Xuguang Jiang…

2014-02-01T23:59:59.000Z

53

Water distillation using waste engine heat from an internal combustion engine  

E-Print Network [OSTI]

To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

Mears, Kevin S

2006-01-01T23:59:59.000Z

54

Comparative Health Risks of Domestic Waste Combustion in Urban and Rural Slovakia  

Science Journals Connector (OSTI)

Comparative Health Risks of Domestic Waste Combustion in Urban and Rural Slovakia ... Another dangerous impact of open burning is supported by the premature mortality increases which are attributable to exposures to PM2.5. ...

Jana Kraj?ovi?ová; Alan Q. Eschenroeder

2007-08-28T23:59:59.000Z

55

Toxic oxide deposits from the combustion of landfill gas and biogas  

Science Journals Connector (OSTI)

Oxide deposits found in combustion systems of landfill gas fired power stations contain relatively high concentrations ... They are selectively transported as part of the landfill gas into the gas-burning devices...

Dietmar Glindemann; Peter Morgenstern…

1996-06-01T23:59:59.000Z

56

Evaluation of the residual gas tolerance of homogeneous combustion processes with high exhaust-gas recirculation rates  

Science Journals Connector (OSTI)

The development of concepts with low emissions and fuel consumption for gasoline engines requires an early knowledge of the combustion process’ residual gas tolerance. At the Institute...

Dipl.-Ing. Dr. techn. Thomas Lauer…

2008-02-01T23:59:59.000Z

57

Municipal solid waste combustion: Waste-to-energy technologies, regulations, and modern facilities in USEPA Region V  

SciTech Connect (OSTI)

Table of Contents: Incinerator operations (Waste preprocessing, combustion, emissions characterization and emission control, process monitoring, heat recovery, and residual ash management); Waste-to-energy regulations (Permitting requirements and operating regulations on both state and Federal levels); Case studies of EPA Region V waste-to-energy facilities (Polk County, Minnesota; Jackson County, Michigan; La Crosse, Wisconsin; Kent County, Michigan; Elk River, Minnesota; Indianapolis, Indiana); Evaluation; and Conclusions.

Sullivan, P.M.; Hallenbeck, W.H.; Brenniman, G.R.

1993-08-01T23:59:59.000Z

58

All of Hanford's underground waste tanks generate hydrogen gas...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Hanford's underground waste tanks generate hydrogen gas to some degree since the radioactivity in the waste releases hydrogen from basic nuclear reactions. The routine release...

59

Automotive Fuel Efficiency Improvement via Exhaust Gas Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Waste Heat Conversion to Electricity Automotive Fuel Efficiency Improvement via Exhaust Gas Waste Heat Conversion to Electricity Working to expand the usage of thermoelectric...

60

Advanced combustion technologies for gas turbine power plants  

SciTech Connect (OSTI)

Objectives are to develop actuators for enhancing the mixing between gas streams, increase combustion stability, and develop hgih-temperature materials for actuators and sensors in combustors. Turbulent kinetic energy maps of an excited jet with co-flow in a cavity with a partially closed exhaust end are given with and without a longitudinal or a transverse acoustic field. Dielectric constants and piezoelectric coefficients were determined for Sr{sub 2}(Nb{sub x}Ta{sub 1-x}){sub 2}O{sub 7} ceramics.

Vandsburger, U. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States). Dept. of Mechanical Engineering; Roe, L.A. [Arkansas Univ., Fayetteville, AR (United States). Dept. of Mechanical Engineering; Desu, S.B. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States). Dept. of Materials Science and Engineering

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Energy exploitation of acid gas with high H2S content by means of a chemical looping combustion system  

Science Journals Connector (OSTI)

Abstract In gas and petroleum industry, the waste gas stream from the sweetening process of a sour natural gas stream is commonly referred as acid gas. Chemical Looping Combustion (CLC) technology has the potential to exploit the combustible fraction of acid gas, H2S, to produce energy obtaining a flue gas highly concentrated on CO2 and SO2, which can be cost-effectively separated for subsequent applications, such as sulfuric acid production. At the same time, a concentrated CO2 stream ready for storage is obtained. The resistance of oxygen carriers to sulfur becomes crucial when an acid gas is subjected to a CLC process since the H2S content can be very high. In this work, a total of 41 h of continuous operation with acid gas and H2S concentrations up to 20 vol.% has been carried out in a 500 Wth CLC unit with two oxygen carriers based on Cu (Cu14?Al) and Fe (Fe20?Al). The formation of copper sulfides and the SO2 emissions in the air reactor made the Cu14?Al material not adequate for the process. In contrast, excellent results were obtained during acid gas combustion with the Fe20?Al oxygen carrier. H2S was fully burnt to SO2 in the fuel reactor at all operating conditions, SO2 was never detected in the gas outlet stream of the air reactor, and iron sulfides were never formed even at H2S concentrations as high as 20 vol.%. Furthermore, it was found that a H2S content of 20 vol.% in the acid gas was high enough to turn the CLC process into an auto-thermal process. Based on these results, it can be concluded that the Fe-based materials prepared by impregnation are very adequate to exploit the energy potential of acid gas mixtures with CO2 capture.

F. García-Labiano; L.F. de Diego; P. Gayán; A. Abad; A. Cabello; J. Adánez; G. Sprachmann

2014-01-01T23:59:59.000Z

62

Capturing Waste Gas: Saves Energy, Lower Costs - Case Study,...  

Office of Environmental Management (EM)

Capturing Waste Gas: Saves Energy, Lower Costs - Case Study, 2013 Capturing Waste Gas: Saves Energy, Lower Costs - Case Study, 2013 ArcelorMittal USA, Inc.'s Indiana Harbor steel...

63

Analysis of options for coal combustion waste management in the Pacific Basin  

SciTech Connect (OSTI)

Many Pacific Basin countries rely on oil for electricity production. Alternative fuel sources such as coal, which is available in the Pacific Basin, can help mitigate adverse impacts of sudden price increases or supply disruptions. Coal combustion produces solid and potentially hazardous wastes of concern to environmental regulators and utility managers. This paper identifies issues associated with managing coal combustion wastes in the Pacific Basin, using the state of Hawaii as a case study. Hawaii is typical of many Pacific Basin locations in that it depends on oil, has limited sites, for waste management operations, and is subject to domestic and international waste management regulations. The paper discusses coal-fired utility wastes, environmental impacts of coal combustion waste disposal, and regulatory requirements that impact coal waste management. From this baseline, potential on- and off-island options for coal waste management are identified. Waste management costs are estimated and non-quantifiable issues are addressed for each option. Many options are applicable across the Pacific Rim and may serve as a basis for future fuel-use decisions.

Elcock, D.; Gasper, J.

1993-10-01T23:59:59.000Z

64

Utilization and Mitigation of VAM/CMM Emissions by a Catalytic Combustion Gas Turbine  

Science Journals Connector (OSTI)

A system configured with a catalytic combustion gas turbine generator unit is introduced. The system has ... Heavy Industries, Ltd., such as small gas turbines, recuperators and catalytic combustors, and catalyti...

K. Tanaka; Y. Yoshino; H. Kashihara; S. Kajita

2013-01-01T23:59:59.000Z

65

Pressure pulsations in combustion chambers of large gas turbines  

SciTech Connect (OSTI)

Flame instabilities and pressure pulsations have been measured in three different types of gas turbine combustors. These are the single and twin silo (such as the ABB GT13E and the Siemens V94.2), the annular combustion chamber (ABB GT 13E2, Siemens V84.3A, etc), and the multi-can combustors common on GEC-EGT gas turbines. Pressure pulsations are mostly resonant. They are interpreted with help of an acoustical model. Non-resonant modes at low frequencies (flame flicker) are ascribed to imperfect mixing especially in premix burners. At higher frequencies they are often due to vortices from the burners. Modifications of the burners, changes in the geometry of the liners and the addition of acoustical dampers are means to abate flame instabilities and the associated resonances. Judicious ways to run the gas turbine can help to avoid them. The efficiency of acoustical dampers of the Helmholtz type has been investigated experimentally and with model predictions.

Verhage, A.J.L.; Stevens, P.M.P.

1998-07-01T23:59:59.000Z

66

ALCF Research Aimed at Safer, Cleaner Combustion for Gas Turbines | Argonne  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Research Aimed at Safer, Cleaner Combustion for Gas Turbines Research Aimed at Safer, Cleaner Combustion for Gas Turbines December 3, 2013 Printer-friendly version Researchers from the Swiss Federal Institute of Technology (ETHZ) and the Argonne Leadership Computing Facility (ALCF) are using supercomputers to advance the development of safer and cleaner gas turbine engines by studying the operating conditions that can lead to a potentially dangerous phenomenon called autoignition. This phenomenon, which involves the spontaneous ignition of a combustible mixture without an external ignition source, can result in a premature combustion event, called flashback, that causes significant damage to the gas turbine. Understanding autoignition is critical to the design of turbines that operate with novel combustion strategies, such as lean

67

Optical backscatter probe for sensing particulate in a combustion gas stream  

DOE Patents [OSTI]

A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

Parks, James E; Partridge, William P

2013-05-28T23:59:59.000Z

68

Advanced Materials for Mercury 50 Gas Turbine Combustion System  

SciTech Connect (OSTI)

Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-0CH11049, has conducted development activities to improve the durability of the Mercury 50 combustion system to 30,000 hours life and reduced life cycle costs. This project is part of Advanced Materials in the Advanced Industrial Gas Turbines program in DOE's Office of Distributed Energy. The targeted development engine was the Mercury{trademark} 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems program (DOE contract number DE-FC21-95MC31173). As a generator set, the Mercury 50 is used for distributed power and combined heat and power generation and is designed to achieve 38.5% electrical efficiency, reduced cost of electricity, and single digit emissions. The original program goal was 20,000 hours life, however, this goal was increased to be consistent with Solar's standard 30,000 hour time before overhaul for production engines. Through changes to the combustor design to incorporate effusion cooling in the Generation 3 Mercury 50 engine, which resulted in a drop in the combustor wall temperature, the current standard thermal barrier coated liner was predicted to have 18,000 hours life. With the addition of the advanced materials technology being evaluated under this program, the combustor life is predicted to be over 30,000 hours. The ultimate goal of the program was to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for a minimum of 4,000 hours. Solar was the Prime Contractor on the program team, which includes participation of other gas turbine manufacturers, various advanced material and coating suppliers, nationally recognized test laboratories, and multiple industrial end-user field demonstration sites. The program focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future gas turbine products. For liner and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics were evaluated before down-selection to the most promising candidate materials for field evaluation. Preliminary, component and sub-scale testing was conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing was used to validated engine performance prior to field evaluation at a Qualcomm Inc. cogeneration site located in San Diego, California. To ensure that the CFCC liners with the EBC proposed under this program would meet the target life, field evaluations of ceramic matrix composite liners in Centaur{reg_sign} 50 gas turbine engines, which had previously been conducted under the DOE sponsored Ceramic Stationary Gas Turbine program (DE-AC02-92CE40960), was continued under this program at commercial end-user sites under Program Subtask 1A - Extended CFCC Materials Durability Testing. The goal of these field demonstrations was to demonstrate significant component life, with milestones of 20,000 and 30,000 hours. Solar personnel monitor the condition of the liners at the field demonstration sites through periodic borescope inspections and emissions measurements. This program was highly successful at evaluating advanced materials and down-selecting promising solutions for use in gas turbine combustions systems. The addition of the advanced materials technology has enabled the predicted life of the Mercury 50 combustion system to reach 30,000 hours, which is Solar's typical time before overhaul for production engines. In particular, a 40 mil thick advanced Thermal Barrier Coating (TBC) system was selected over various other TBC systems, ODS liners and CFCC liners for the 4,000-hour field evaluation under the program. This advanced TBC is now production bill-of-material at various thicknesses up to 40 mils for all of Solar's advanced backside-cooled combustor liners (Centaur 50, Taurus 60, Mars 100, Taurus 70,

Price, Jeffrey

2008-09-30T23:59:59.000Z

69

Modeling and Control of Lean Premixed Combustion Dynamics for Gas Turbines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Virginia Active Combustion Control Group Virginia Active Combustion Control Group Tech Virginia VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY Reacting Flows Laboratory Modeling and Control of Lean Premixed Combustion Dynamics for Gas Turbines Virginia Tech Principal Investigator: Uri Vandsburger SCIES Project 02- 01- SR099 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (05/01/02, 36 Month Duration) $ 756,700 Total Contract Value ($ 603,600 DOE) Virginia Active Combustion Control Group Tech Virginia VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY Reacting Flows Laboratory Gas Turbine Technology Needs DLN/LP Gas Turbines * Improved Combustion Stability * Improved Design Methodology With a focus on: - Thermoacoustics

70

Elevated Trace Element Concentrations in Southern Toads, Bufo terrestris, Exposed to Coal Combustion Waste  

E-Print Network [OSTI]

, and behavioral abnormalities in amphibians to coal combustion wastes (coal ash). Few studies, however, have determined trace element concentrations in amphibians exposed to coal ash. In the current study we compare high levels of selenium and may be useful bioindicators in agricultural and coal ash-impacted habitats

Hopkins, William A.

71

Single-stage conversion of associated petroleum gas and natural gas to syngas in combustion and auto-ignition processes  

Science Journals Connector (OSTI)

Single-stage conversion of alkane mixtures simulating associated petroleum gas (APG) to syngas is studied in a static installation and ... in a flow reactor based on the rocket combustion chamber. Yields of the d...

Yu. A. Kolbanovskii; I. V. Bilera; I. V. Rossikhin…

2011-12-01T23:59:59.000Z

72

Gasification of Mixed Plastic Wastes in a Moving-Grate Gasifier and Application of the Producer Gas to a Power Generation Engine  

Science Journals Connector (OSTI)

Due to the flame-assisted tar reforming with oxy-combustion of natural gas, the hydrogen content was significantly increased, resulting in an increase in the syngas caloric value and a decrease in the gas cleaning load downstream. ... An auxiliary burner was installed in front of each stage for preheating the inside of the gasifier. ... Such waste products include discarded tires, plastic, glass, steel, burnt foundry sand, and coal combustion byproducts (CCBs). ...

Jeung Woo Lee; Tae U Yu; Jae Wook Lee; Ji Hong Moon; Hyo Jae Jeong; Sang Shin Park; Won Yang; Uen Do Lee

2013-03-15T23:59:59.000Z

73

GTZ-Greenhouse Gas Calculator for Waste Management | Open Energy  

Open Energy Info (EERE)

GTZ-Greenhouse Gas Calculator for Waste Management GTZ-Greenhouse Gas Calculator for Waste Management Jump to: navigation, search Tool Summary Name: GTZ-Greenhouse Gas Calculator for Waste Management Agency/Company /Organization: GTZ Sector: Energy Website: www.gtz.de/en/themen/umwelt-infrastruktur/abfall/30026.htm References: GHG Calculator for Waste Management[1] Waste Management - GTZ Website[2] Logo: GTZ-Greenhouse Gas Calculator for Waste Management The necessity to reduce greenhouse gases and thus mitigate climate change is accepted worldwide. Especially in low- and middle-income countries, waste management causes a great part of the national greenhouse gas production, because landfills produce methane which has a particularly strong effect on climate change. Therefore, it is essential to minimize

74

Condition Based Monitoring of Gas Turbine Combustion Components  

SciTech Connect (OSTI)

The objective of this program is to develop sensors that allow condition based monitoring of critical combustion parts of gas turbines. Siemens teamed with innovative, small companies that were developing sensor concepts that could monitor wearing and cracking of hot turbine parts. A magnetic crack monitoring sensor concept developed by JENTEK Sensors, Inc. was evaluated in laboratory tests. Designs for engine application were evaluated. The inability to develop a robust lead wire to transmit the signal long distances resulted in a discontinuation of this concept. An optical wear sensor concept proposed by K Sciences GP, LLC was tested in proof-of concept testing. The sensor concept depended, however, on optical fiber tips wearing with the loaded part. The fiber tip wear resulted in too much optical input variability; the sensor could not provide adequate stability for measurement. Siemens developed an alternative optical wear sensor approach that used a commercial PHILTEC, Inc. optical gap sensor with an optical spacer to remove fibers from the wearing surface. The gap sensor measured the length of the wearing spacer to follow loaded part wear. This optical wear sensor was developed to a Technology Readiness Level (TRL) of 5. It was validated in lab tests and installed on a floating transition seal in an F-Class gas turbine. Laboratory tests indicate that the concept can measure wear on loaded parts at temperatures up to 800{degrees}C with uncertainty of < 0.3 mm. Testing in an F-Class engine installation showed that the optical spacer wore with the wearing part. The electro-optics box located outside the engine enclosure survived the engine enclosure environment. The fiber optic cable and the optical spacer, however, both degraded after about 100 operating hours, impacting the signal analysis.

Ulerich, Nancy; Kidane, Getnet; Spiegelberg, Christine; Tevs, Nikolai

2012-09-30T23:59:59.000Z

75

Gas-phase combustion processes in light of the theory of non-isothermal chain reactions  

Science Journals Connector (OSTI)

The presented experimental and theoretical results demonstrate, in contrast to the concept commonly accepted until recently, the key role of the branching-chain reaction mechanism in gas-phase combustion processes

V. V. Azatyan

2014-02-01T23:59:59.000Z

76

Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines  

E-Print Network [OSTI]

Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines the EL method well suited for gas turbine computations, but RANS with the EE approach may also be found and coupled with the LES solver of the gas phase. The equations used for each phase and the coupling terms

77

Comanagement of coal combustion by-products and low-volume wastes: A midwestern site  

SciTech Connect (OSTI)

This report presents results from a field evaluation of the environmental effects of co-management of high-volume coal combustion residues with low-volume non-combustion wastes at a utility power plant. At the C-site, located in the midwestern United States, fly ash and bottom ash from the combustion of bituminous Indiana coal are co-managed with non-combustion wastes including pyrite rejects from coal cleaning, demineralizer regenerant, runoff water from the plant grounds, and boiler cleaning wastes. These wastes are disposed of in an unlined ash pond on site. The pond discharges primarily to the surrounding shallow groundwater with a limited surface discharge to a nearby river. Hydrological monitoring took place over a nine-month period in 1989 and 1990. Groundwater and soil samples were collected on three occasions during this time. Samples were analyzed to determine the groundwater chemistry, and soil and waste chemistry and geochemistry. Downgradient wells showed an increased concentration of several ash-derived species including boron, calcium, fluoride, potassium, sodium, strontium, and sulfate. The median sulfate concentration in downgradient wells was 350 mg/L, which exceeds the secondary drinking water limit. Statistical comparison of the composition of background groundwater with water from wells downgradient of the ash ponds was limited by a single set of background water samples. Soils beneath the pond appear to have limited attenuative capacity for ash-derived trace metals, and groundwater velocities are high; however, trace metal concentrations in downgradient wells are similar to background levels. No impact uniquely attributable to the co-management of low-volume wastes was detectable at this site.

Holcombe, L.J.; Thompson, C.M.; Weinberg, A. (Radian Corp., Austin, TX (United States)); Erickson, J.R. (GeoTrans, Inc., Sterling, VA (United States)); Fruchter, J.S. (Battelle Pacific Northwest Lab., Richland, WA (United States))

1992-08-01T23:59:59.000Z

78

Gas generation results and venting study for transuranic waste drums  

SciTech Connect (OSTI)

Sixteen waste drums, containing six categories of plutonium-contaminated waste, were monitored for venting and gas generation for six months. The venting devices tested appeared adequate to relieve pressure and prevent hydrogen accumulation. Most of the gas generation, primarily H2 and CO2, was due to radiolytic decomposition of the hydrogenous wastes. Comparison of the gas yields with those obtained previously in laboratory tests showed very reasonable agreement with few exceptions.

Kazanjian, A.R.; Arnold, P.M.; Simmons, W.C.; D'Amico, E.L.

1985-09-23T23:59:59.000Z

79

GEI 41040G - Specification for Fuel Gases for COmbustion in Heavy-Duty Gas Turbines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Turbine Gas Turbine Revised, January 2002 GEI 41040G These instructions do not purport to cover all details or variations in equipment nor to provide for every possible contingency to be met in connection with installation, operation or maintenance. Should further information be desired or should particular problems arise which are not covered sufficiently for the purchaser's purposes the matter should be referred to the GE Company. © 1999 GENERAL ELECTRIC COMPANY Specification for Fuel Gases for Combustion in Heavy-Duty Gas Turbines GEI 41040G Specification for Fuel Gases for Combustion in Heavy-Duty Gas Turbines 2 TABLE OF CONTENTS I. INTRODUCTION 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

80

E-Print Network 3.0 - acid combustion rate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

air flows are established to provide local and overall... content, and the combustion gas heat loss rate. ... Source: Columbia University - Waste-to-Energy Research and Technology...

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Combustion Instability and Blowout Characteristics of Fuel Flexible Gas Turbine Combustors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Instability and Blowout Combustion Instability and Blowout Characteristics of Fuel Flexible Gas Turbine Characteristics of Fuel Flexible Gas Turbine Combustors Combustors Georgia Institute of Technology Georgia Institute of Technology Tim Lieuwen, Ben Zinn Bobby Noble, Qingguo Zhang DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES SCIES Project 03-01-SR111 Project Awarded (07/01/03, 36 Month Duration) Total Contract Value $376,722 . CLEMSON presentation, T.L., B.Z., B.N., Q.Z. Gas Turbine Need Gas Turbine Need * Need: Gas turbines with sufficient flexibility to cleanly and efficiently combust a wide range of fuels, particularly coal-derived gases - Problem: Inherent variability in composition and heating

82

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Final report  

SciTech Connect (OSTI)

The problem addressed by our invention is that of municipal solid waste utilization. The dimensions of the problem can be visualized by the common comparison that the average individual in America creates in five years time an amount of solid waste equivalent in weight to the Statue of Liberty. The combustible portion of the more than 11 billion tons of solid waste (including municipal solid waste) produced in the United States each year, if converted into useful energy, could provide 32 quads per year of badly needed domestic energy, or more than one-third of our annual energy consumption. Conversion efficiency and many other factors make such a production level unrealistic, but it is clear that we are dealing with a very significant potential resource. This report describes research pertaining to the co-combustion of oil shale with solid municipal wastes in a circulating fluidized bed. The oil shale adds significant fuel content and also constituents that can possible produce a useful cementitious ash.

NONE

1996-06-30T23:59:59.000Z

83

Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas  

SciTech Connect (OSTI)

The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: • Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas • Utilizing proven and reliable technology and equipment • Maximizing electrical efficiency • Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill • Maximizing equipment uptime • Minimizing water consumption • Minimizing post-combustion emissions • The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWh’s of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

Galowitz, Stephen

2012-12-31T23:59:59.000Z

84

EIA - Greenhouse Gas Emissions - Methane Emissions  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

credit for renewable energy, including waste-to-energy and landfill gas combustion. Wastewater treatment, including both domestic wastewater (about two-thirds) and industrial...

85

Corrosion and Mechanical Properties of Materials in Combustion and Mixed-Gas Environments  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Corrosion and Mechanical Properties of Corrosion and Mechanical Properties of Materials in Combustion and Mixed-Gas Environments Background A number of advanced technologies are being developed to convert coal to clean fuels for power generation and for use as a feedstock in chemical plants. Coal con- version and combustion processes create by-products that affect the performance of the materials of which the plant components are fabricated, reducing the systems'

86

Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust  

DOE Patents [OSTI]

A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

2012-05-15T23:59:59.000Z

87

Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials  

SciTech Connect (OSTI)

Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing materials. Transportation regulations prohibit shipment of explosives and radioactive materials together. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials (NM), and spent nuclear fuels (SNF) programs within DOE’s Environmental Management (EM) organization to address gas generation concerns. This paper presents a "program level" roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This "program level" roadmapping involves linking technology development (and deployment) efforts to the programs’ needs and requirements for dispositioning the material/waste that generates combustible gas through radiolysis and chemical decomposition. The roadmapping effort focused on needed technical & programmatic support to the baselines (and to alternatives to the baselines) where the probability of success is low (i.e., high uncertainty) and the consequences of failure are relatively high (i.e., high programmatic risk). A second purpose for roadmapping was to provide the basis for coordinating sharing of "lessons learned" from research and development (R&D) efforts across DOE programs to increase efficiency and effectiveness in addressing gas generation issues.

Luke, Dale Elden; Rogers, Adam Zachary; Hamp, S.

2001-03-01T23:59:59.000Z

88

Study of Lean Premixed Methane Combustion with CO2 Dilution under Gas Turbine Conditions  

Science Journals Connector (OSTI)

In gas turbines, high air dilution is used in order to keep the turbine inlet temperature (TIT)(7) below the metallurgical temperature limit of the first turbine stages. ... It was shown that CO2 dilution could be an efficient method for increasing CO2 concentration in exhaust gas, thus making its capture easier. ... Efforts were focused on the impacts on cycle efficiency, combustion, gas turbine components, and cost. ...

Stéphanie de Persis; Gilles Cabot; Laure Pillier; Iskender Gökalp; Abdelakrim Mourad Boukhalfa

2012-12-29T23:59:59.000Z

89

Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines  

SciTech Connect (OSTI)

The purpose of this program was to develop low-emissions, efficient fuel-flexible combustion technology which enables operation of a given gas turbine on a wider range of opportunity fuels that lie outside of current natural gas-centered fuel specifications. The program encompasses a selection of important, representative fuels of opportunity for gas turbines with widely varying fundamental properties of combustion. The research program covers conceptual and detailed combustor design, fabrication, and testing of retrofitable and/or novel fuel-flexible gas turbine combustor hardware, specifically advanced fuel nozzle technology, at full-scale gas turbine combustor conditions. This project was performed over the period of October 2008 through September 2011 under Cooperative Agreement DE-FC26-08NT05868 for the U.S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled "Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines". The overall objective of this program was met with great success. GE was able to successfully demonstrate the operability of two fuel-flexible combustion nozzles over a wide range of opportunity fuels at heavy-duty gas turbine conditions while meeting emissions goals. The GE MS6000B ("6B") gas turbine engine was chosen as the target platform for new fuel-flexible premixer development. Comprehensive conceptual design and analysis of new fuel-flexible premixing nozzles were undertaken. Gas turbine cycle models and detailed flow network models of the combustor provide the premixer conditions (temperature, pressure, pressure drops, velocities, and air flow splits) and illustrate the impact of widely varying fuel flow rates on the combustor. Detailed chemical kinetic mechanisms were employed to compare some fundamental combustion characteristics of the target fuels, including flame speeds and lean blow-out behavior. Perfectly premixed combustion experiments were conducted to provide experimental combustion data of our target fuels at gas turbine conditions. Based on an initial assessment of premixer design requirements and challenges, the most promising sub-scale premixer concepts were evaluated both experimentally and computationally. After comprehensive screening tests, two best performing concepts were scaled up for further development. High pressure single nozzle tests were performed with the scaled premixer concepts at target gas turbine conditions with opportunity fuels. Single-digit NOx emissions were demonstrated for syngas fuels. Plasma-assisted pilot technology was demonstrated to enhance ignition capability and provide additional flame stability margin to a standard premixing fuel nozzle. However, the impact of plasma on NOx emissions was observed to be unacceptable given the goals of this program and difficult to avoid.

Venkatesan, Krishna

2011-11-30T23:59:59.000Z

90

Near-Zero Emissions Oxy-Combustion Flue Gas Purification  

SciTech Connect (OSTI)

The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions

Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

2012-06-30T23:59:59.000Z

91

Reduced and Validated Kinetic Mechanisms for Hydrogen-CO-sir Combustion in Gas Turbines  

SciTech Connect (OSTI)

Rigorous experimental, theoretical, and numerical investigation of various issues relevant to the development of reduced, validated kinetic mechanisms for synthetic gas combustion in gas turbines was carried out - including the construction of new radiation models for combusting flows, improvement of flame speed measurement techniques, measurements and chemical kinetic analysis of H{sub 2}/CO/CO{sub 2}/O{sub 2}/diluent mixtures, revision of the H{sub 2}/O{sub 2} kinetic model to improve flame speed prediction capabilities, and development of a multi-time scale algorithm to improve computational efficiency in reacting flow simulations.

Yiguang Ju; Frederick Dryer

2009-02-07T23:59:59.000Z

92

Performance of an Internal Combustion Engine Operating on Landfill Gas and the Effect of Syngas Addition  

Science Journals Connector (OSTI)

Performance of an Internal Combustion Engine Operating on Landfill Gas and the Effect of Syngas Addition ... The performance of a four-stroke Honda GC160E spark ignition (SI) internal combustion (IC) engine operating on landfill gas (LFG) was investigated, as well as the impact of H2 and CO (syngas) addition on emissions and engine efficiency. ... In addition, variation across both the syngas content (up to 15%) and the ratio of H2 to CO in the syngas (H2/CO = 0.5, 1, and 2) were tested. ...

McKenzie P. Kohn; Jechan Lee; Matthew L. Basinger; Marco J. Castaldi

2011-02-07T23:59:59.000Z

93

Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1  

SciTech Connect (OSTI)

This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

Not Available

1993-05-01T23:59:59.000Z

94

Flue Gas Purification Utilizing SOx/NOx Reactions During Compressin of CO2 Derived from Oxyfuel Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Flue Gas Purification Flue Gas Purification Utilizing SO X /NO X Reactions During Compression of CO 2 Derived from Oxyfuel Combustion Background Oxy-combustion in a pulverized coal-fired power station produces a raw carbon dioxide (CO 2 ) product containing contaminants such as water vapor, oxygen, nitrogen, and argon from impurities in the oxygen used and any air leakage into the system. Acid gases are also produced as combustion products, such as sulfur oxides (SO

95

Recent Development in Oxy-Combustion Technology and Its Applications to Gas Turbine Combustors and ITM Reactors  

Science Journals Connector (OSTI)

Recent Development in Oxy-Combustion Technology and Its Applications to Gas Turbine Combustors and ITM Reactors ... Also, the application of oxy-combustion technology into gas turbines is possible; however, the combustion temperature will be increased tremendously, which needs more control to make safe the turbine blades. ... technologies, a simplified model of a power plant with two forms of CO2 capture was developed. ...

Mohamed A. Habib; Medhat Nemitallah; Rached Ben-Mansour

2012-11-19T23:59:59.000Z

96

Synthesis, droplet combustion, and sooting characteristics of biodiesel produced from waste vegetable oils  

SciTech Connect (OSTI)

In light of the potential of fatty acid methyl ester (FAME, i.e. biodiesel) as a renewable energy source, an innovative acid catalyzed process was developed for the synthesis of biodiesel from waste vegetable oils. The synthesized biodiesels were analytically characterized for their major components, molar fraction and molecular weight of each component, the average molecular weight, and the heat of combustion. Their droplet combustion characteristics in terms of the burning rate, flame size, and sooting tendency were subsequently determined in a high-temperature, freely-falling droplet apparatus. Results show that the biodiesel droplet has higher burning rate, and that biodiesel in general has a lower propensity to soot because its molecular oxygen content promotes the oxidation of the soot precursors.

Li, T. X.; Zhu, D. L.; Akafuah, N.; Saito, K.; Law, C. K.

2011-01-01T23:59:59.000Z

97

Cogeneration system with low NO sub x combustion of fuel gas  

SciTech Connect (OSTI)

This patent describes a cogeneration system for the production of electricity and refrigeration with low NO{sub x} combustion of fuel gas supplied at a high pressure. It comprises a heat exchanger to heat the fuel gas at high pressure; a turbo-expander connected to receive and expand the heated fuel gas from the heat exchanger; a centrifugal compressor driven by the turbo-expander the compressor being the refrigerant compressor of a refrigeration system; a porous fiber burner connected to receive the expanded fuel gas from the turbo-expander together with the requisite combustion air; a high-pressure steam boiler heated by the combustion of the expanded fuel gas on the outer surface of the porous fiber burner, the boiler being connected to pass the resulting flue gas with low NO{sub x} content through the heat exchanger to heat the fuel gas at high pressure; a steam turbine connected to receive and expand highpressure steam from the boiler and to return expanded and condensed steam to the boiler; and an electric generator driven by the steam turbine.

Garbo, P.W.

1991-06-25T23:59:59.000Z

98

Improving a Pre-Combustion CCS Concept in Gas Turbine Combined Cycle for CHP Production  

Science Journals Connector (OSTI)

Abstract This paper describes modifications to improve the feasibility of a pre-combustion CCS concept for a gas turbine combined cycle. A natural gas-fired greenfield combined heat and power (CHP) plant equipped with pre-combustion capture was used as a base case, for which various improvement options were identified, assessed and selected. The base case was modified using the selected improvement options, after which the investment costs were re-evaluated. The results showed that the investment cost can be reduced with 8% by excluding the pre-reformer and the low temperature water-gas-shift reactor from the reforming process. The exclusion of the pre-reformer did not affect the performance of the plant, but the exclusion of the low temperature water-gas-shift reactor led to higher CO2 emissions.

Marjut S. Suomalainen; Antti Arasto; Sebastian Teir; Sari Siitonen

2013-01-01T23:59:59.000Z

99

The effects and characteristics of hydrogen in SNG on gas turbine combustion using a diffusion type combustor  

Science Journals Connector (OSTI)

Abstract Converting coal to natural gas may be one of the alternative solutions for satisfying the demand for natural gas. However, synthetic natural gas (SNG) has not been proven effective in natural gas-fired power plants. In this research, several combustion tests using a diffusion type combustor were conducted to determine the effect of hydrogen content in SNG on gas turbine combustion. Three kinds of SNG with different H2 content up to 3%vol were used for the combustion tests. Even a small amount of hydrogen in SNG affects the flame structure: it shortened the flame length and enlarged the flame angle slightly. However, hydrogen content up to 3% in SNG did not affect the gas turbine combustion characteristics, which are emission performance and combustion efficiency. Due to a similarity with real gas turbine combustor conditions for power generation, a high pressure combustion test helped us verify the ambient pressure combustion tests conducted to determine the effect of hydrogen in SNG. In the high pressure combustion test, the pattern factors were identical even though the hydrogen content was varied from 0% to 3%.

Seik Park; Uisik Kim; Minchul Lee; Sungchul Kim; Dongjin Cha

2013-01-01T23:59:59.000Z

100

Tungsten carbide synthesized by low-temperature combustion as gas diffusion electrode catalyst  

E-Print Network [OSTI]

June 2014 Keywords: Low-temperature combustion syn- thesis Tungsten carbide Electrocatalyst Gas burning on the environment, and reduce dependence on fossil fuels, development of pure electric and fuel of highly efficient low-cost electrode catalysts for the oxygen reduction cathode, metaleair batteries have

Volinsky, Alex A.

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Method for destroying hazardous organics and other combustible materials in a subcritical/supercritical reactor  

DOE Patents [OSTI]

A waste destruction method using a reactor vessel to combust and destroy organic and combustible waste, including the steps of introducing a supply of waste into the reactor vessel, introducing a supply of an oxidant into the reactor vessel to mix with the waste forming a waste and oxidant mixture, introducing a supply of water into the reactor vessel to mix with the waste and oxidant mixture forming a waste, water and oxidant mixture, reciprocatingly compressing the waste, water and oxidant mixture forming a compressed mixture, igniting the compressed mixture forming a exhaust gas, and venting the exhaust gas into the surrounding atmosphere.

Janikowski, Stuart K. (Idaho Falls, ID)

2000-01-01T23:59:59.000Z

102

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network [OSTI]

OXIDES OF NITROGEN Nitrogen Dioxide (N0 2) Nitrous Oxide (NFigure 7. Emissions of nitrogen dioxide from gas turbines (by AiResearch(8)) . Nitrogen dioxide emissions from a

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

103

Capturing Waste Gas: Saves Energy, Lower Costs  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

per hour of steam from about 490 MMBtu per hour of previously wasted BFG. The steam drives existing turbo-generators at the facility to generate electricity. The electricity...

104

The influence of fuel composition on the combustion and emission characteristics of natural gas fueled engines  

Science Journals Connector (OSTI)

Abstract As global energy demand rises, natural gas (NG) plays an important strategic role in energy supply. Natural gas is the cleanest fossil fuel that has been investigated extensively for use in spark-ignition (SI) and compression-ignition (CI) engines. This paper reviews the research on the effects of natural gas composition on combustion and emission characteristics of natural gas fueled internal combustion engines (ICEs) and reports the most achievements obtained by researchers in this field. It has been reported that the engine performance and emission are greatly affected by varying compositions of natural gas. The most important NG fuel property is the Wobbe number (WN). Generally, it was agreed by researchers that the fuels with higher hydrocarbons, higher WN, and higher energy content exhibited better fuel economy and carbon dioxide (CO2) emissions. Nitrogen oxides (NOx) emissions were also increased for gases with higher levels of higher WN, while total hydrocarbons (THCs), carbon monoxide (CO), showed some reductions for these gases. On the other hand, particulate matter (PM) emissions did not show any fuel effects. Moreover, adding of small fractions of higher alkanes, such as ethane and propane, significantly improved ignition qualities of natural gas engines. The results presented provide a good insight for researchers to pursue their future research on natural gas fueled ICEs.

Amir-Hasan Kakaee; Amin Paykani; Mostafa Ghajar

2014-01-01T23:59:59.000Z

105

Energy recovery from municipal solid waste and sewage sludge using multi-solid fluidized bed combustion technology  

SciTech Connect (OSTI)

This study was initiated to investigate the recovery of energy from municipal solid waste (MSW) and domestic sewage sludge (DSS) simultaneously by using Battelle's multi-solid fluidized-bed combustion (MS-FBC) technology. The concept was to recover energy as high and low pressure steam, simultaneously. High pressure steam would be generated from flue gas using a conventional tubular boiler. Low pressure steam would be generated by direct contact drying of DSS (as 4% solids) with hot sand in a fluidized bed that is an integral part of the MS-FBC process. It was proposed that high pressure steam could be used for district heating or electricity generation. The low pressure steam could be used for close proximity building heat. Alternatively, low pressure steam could be used to heat wastewater in a sewage treatment plant to enhance sedimentation and biological activity that would provide a captive market for this part of the recovered energy. The direct contact drying or tubeless steam generation eliminates fouling problems that are common during heat exchange with DSS. The MS-FBC process was originally developed for coal and was chosen for this investigation because its combustion rate is about three times that of conventional fluidized beds and it was projected to have the flexibility needed for accomplishing tubeless steam generation. The results of the investigation show that the MS-FBC process concept for the co-utilization of MSW and DSS is technically feasible and that the thermal efficiency of the process is 76 to 82% based on experiments conducted in a 70 to 85 lb/h pilot plant and calculations on three conceptual cases.

Not Available

1981-07-01T23:59:59.000Z

106

Evaluation of Gas Retention in Waste Simulants: Tall Column Experiments  

SciTech Connect (OSTI)

Gas generation in Hanford’s underground waste storage tanks can lead to gas accumulation within the layer of settled solids (sludge) at the tank bottom. The gas, which typically has hydrogen as the major component together with other flammable species, is formed principally by radiation-driven chemical reactions. Accumulation of these gases within the sludge in a waste tank is undesirable and limits the amount of tank volume for waste storage. Further, accumulation of large amounts of gas in the sludge may potentially result in an unacceptable release of the accumulated gas if the sludge-layer density is reduced to less than that of the overlying sludge or that of the supernatant liquid. Rapid release of large amounts of flammable gases could endanger personnel and equipment near the tank. For this reason, a thorough understanding of the circumstances that can lead to a potentially problematic gas accumulation in sludge layers is needed. To respond to this need, the Deep Sludge Gas Release Event Program (DSGREP) was commissioned to examine gas release behavior in sludges.

Schonewill, Philip P.; Gauglitz, Phillip A.; Shimskey, Rick W.; Denslow, Kayte M.; Powell, Michael R.; Boeringa, Gregory K.; Bontha, Jagannadha R.; Karri, Naveen K.; Fifield, Leonard S.; Tran, Diana N.; Sande, Susan; Heldebrant, David J.; Meacham, Joseph E.; Smet, Dave; Bryan, Wesley E.; Calmus, Ronald B.

2014-05-16T23:59:59.000Z

107

Soil attenuation of leachates from low-rank coal combustion wastes: a literature survey. [116 references  

SciTech Connect (OSTI)

In parallel with pursuing the goal of increased utilization of low-rank solid fuels, the US Department of Energy is investigating various aspects associated with the disposal of coal-combustion solid wastes. Concern has been expressed relative to the potential hazards presented by leachates from fly ash, bottom ash and scrubber wastes. This is of particular interest in some regions where disposal areas overlap aquifer recharge regions. The western regions of the United States are characterized by relatively dry alkaline soils which may effect substantial attenuation of contaminants in the leachates thereby reducing the pollution potential. A project has been initiated to study the contaminant uptake of western soils. This effort consists of two phases: (1) preparation of a state-of-the-art document on soil attenuation; and (2) laboratory experimental studies to characterize attenuation of a western soil. The state-of-the-art document, represented herein, presents the results of studies on the characteristics of selected wastes, reviews the suggested models which account for the uptake, discusses the specialized columnar laboratory studies on the interaction of leachates and soils, and gives an overview of characteristics of Texas and Wyoming soils. 116 references, 10 figures, 29 tables.

Gauntt, R. O.; DeOtte, R. E.; Slowey, J. F.; McFarland, A. R.

1984-01-01T23:59:59.000Z

108

Post-combustion Carbon Capture with a Gas Separation Membrane: Parametric Study, Capture Cost, and Exergy Analysis  

Science Journals Connector (OSTI)

Post-combustion Carbon Capture with a Gas Separation Membrane: Parametric Study, Capture Cost, and Exergy Analysis ... (5) In a post-combustion CO2 capture process, the purity of the captured CO2 in the permeate stream mainly depends upon the selectivity of CO2 over the other gas species, such as N2 and O2. ... Capturing CO2 from flue gases in a power plant is not like traditional gas processing or purification, there are no strict requirements on the decarbonized sweet gas, which means no strict requirement on the CO2 concentration in the sweet gas or CO2 capture ratio. ...

Xiangping Zhang; Xuezhong He; Truls Gundersen

2013-03-04T23:59:59.000Z

109

DETECTION OF ALUMINUM WASTE REACTIONS AND WASTE FIRES Jeffrey W. Martin, M.S., P.G., R.S.  

E-Print Network [OSTI]

-review and possible publication in the ASCE Journal of Hazardous, Toxic, and Radioactive Waste October 24, 2011 #12;[i combustion of the surrounding solid waste. The landfill liner and explosive gas extraction and leachate

110

Lean Catalytic Combustion for Ultra-low Emissions at High Temperature in Gas-Turbine Burners  

Science Journals Connector (OSTI)

This illustrates the weak point of current catalytic combustion technology: the unavailability of catalytic systems stable at the temperature of the gas turbine inlet temperature. ... The possible feeds are methane, gaseous fuels, and gasified biomasses. ... In particular, the paper presents current development status and design challenges being addressed by Siemens Westinghouse Power Corp. for large industrial engines (>200 MW) and by Solar Turbines for smaller engines (Turbine Systems (ATS) program. ...

Fabrizio D’Alessandro; Giovanna Pacchiarotta; Alberto Rubino; Mauro Sperandio; Pierluigi Villa; Arturo Manrique Carrera; Reza Fakhrai; Gianluigi Marra; Annalisa Congiu

2010-12-16T23:59:59.000Z

111

A diffusion-kinetic model for pulverized-coal combustion and heat-and-mass transfer in a gas stream  

Science Journals Connector (OSTI)

A diffusion-kinetic model for pulverized-coal combustion and heat-and-mass transfer in a gas stream is proposed, and the results of numerical simulation of the burnout dynamics of Kansk-Achinsk coals in the pu...

E. A. Boiko; S. V. Pachkovskii

2008-12-01T23:59:59.000Z

112

LASER STABILIZATION FOR NEAR ZERO NO{sub x} GAS TURBINE COMBUSTION SYSTEMS  

SciTech Connect (OSTI)

Historically, the development of new industrial gas turbines has been primarily driven by the intent to achieve higher efficiency, lower operating costs and lower emissions. Higher efficiency and lower cost is obtained through higher turbine operating temperatures, while reduction in emissions is obtained by extending the lean operating limit of the combustor. However reduction in the lean stability limit of operation is limited greatly by the chemistry of the combustion process and by the occurrence of thermo-acoustic instabilities. Solar Turbines, CFD Research Corporation, and Los Alamos National Laboratory have teamed to advance the technology associated with laser-assisted ignition and flame stabilization, to a level where it could be incorporated onto a gas turbine combustor. The system being developed is expected to enhance the lean stability limit of the swirl stabilized combustion process and assist in reducing combustion oscillations. Such a system has the potential to allow operation at the ultra-lean conditions needed to achieve NO{sub x} emissions below 5 ppm without the need of exhaust treatment or catalytic technologies. The research effort was focused on analytically modeling laser-assisted flame stabilization using advanced CFD techniques, and experimentally demonstrating the technology, using a solid-state laser and low-cost durable optics. A pulsed laser beam was used to generate a plasma pool at strategic locations within the combustor flow field such that the energy from the plasma became an ignition source and helped maintain a flame at ultra lean operating conditions. The periodic plasma generation and decay was used to nullify the fluctuations in the heat release from the flame itself, thus decoupling the heat release from the combustor acoustics and effectively reducing the combustion oscillations. The program was built on an existing technology base and includes: extending LANL's existing laser stabilization experience to a sub-scale combustor rig, performing and validating CFD predictions, and ultimately conducting a full system demonstration in a multi-injector combustion system at Solar Turbines.

Vivek Khanna

2002-09-30T23:59:59.000Z

113

Reducing nitrogen oxides emissions from the combustion of LCV gas staged firing  

E-Print Network [OSTI]

with cotton gin tr ash, one of the primary fuels under consider ation, r esulted in flue NO levels ranging from 650-B60 ng/J (1. 5-2. 0 lb/MBtu). The Texas Air Control Board (TACB) will issue a facility a permit to operate only if NOx emissions are within... NO Methods of NOx Control Methods of NOx control may be lumped into two cate- gories: flue gas treatment (FGT) and combustion modifica- tion. The different processes are described below. Flue Gas Tr eatment Most of the research on FGT to date has been...

Finch, Stanley Frank

2012-06-07T23:59:59.000Z

114

Preventing Buoyant Displacement Gas Release Events in Hanford Double-Shell Waste Tanks  

SciTech Connect (OSTI)

This report summarizes the predictive methods used to ensure that waste transfer operations in Hanford waste tanks do not create waste configurations that lead to unsafe gas release events. The gas release behavior of the waste in existing double-shell tanks has been well characterized, and the flammable gas safety issues associated with safe storage of waste in the current configuration are being formally resolved. However, waste is also being transferred between double-shell tanks and from single-shell tanks into double-shell tanks by saltwell pumping and sluicing that create new wastes and waste configurations that have not been studied as well. Additionally, planning is underway for various waste transfer scenarios to support waste feed delivery to the proposed vitrification plant. It is critical that such waste transfers do not create waste conditions with the potential for dangerous gas release events.

Meyer, Perry A.; Stewart, Charles W.

2001-01-01T23:59:59.000Z

115

Erosion-Corrosion of Iron and Nickel Alloys at Elevated Temperature in a Combustion Gas Environment  

SciTech Connect (OSTI)

This paper reports on the results of a study that compares the erosion-corrosion behavior of a variety of alloys (Fe- 2¼Cr 1Mo, 304 SS, 310 SS, Incoloy 800, Haynes 230 and a Fe3Al) in a combustion environment. Advanced coal combustion environments, with higher temperatures, are driving re-examination of traditional and examination of new alloys in these hostile environments. In order to simulate conditions in advanced coal combustion boilers, a special erosion apparatus was used to allow for impingement of particles under a low abrasive flux in a gaseous environment comprised of 20 % CO2, 0.05 % HCl, 77 % N2, 3 % O2, and 0.1 % SO2. Tests were conducted at room temperature and 700 °C with ~ 270 ?m silica, using an impact velocity of 20 m/s in both air and the simulated combustion gas environment. The erosion-corrosion behavior was characterized by gravimetric measurements and by examination of the degraded surfaces optically and by scanning electron microscopy (SEM). At room temperature most of the alloys had similar loss rates. Not surprisingly, at 700 °C the lower chrome-iron alloy had a very high loss rate. The nickel alloys tended to have higher loss rates than the high chrome austenitic alloys.

Tylczak, Joseph [NETL] [NETL

2014-05-02T23:59:59.000Z

116

Syngas production from wood pellet using filtration combustion of lean natural gas–air mixtures  

Science Journals Connector (OSTI)

Abstract A common method for the production of hydrogen and syngas is solid fuel gasification. This paper discusses the experimental results obtained from the combustion of lean natural gas–air mixtures in a porous medium composed of aleatory alumina spheres and wood pellets, called hybrid bed. Temperature, velocity, and chemical products (H2, CO, CO2, CH4) of the combustion waves were recorded experimentally in an inert bed (baseline) and hybrid bed (with a volume wood fraction of 50%), for equivalence ratios (?) from 0.3 to 1.0, and a constant filtration velocity of 15 cm/s. Upstream, downstream and standing combustion waves were observed for inert and hybrid bed. The maximum hydrogen conversion in hybrid filtration combustion is found to be ?99% at ? = 0.3. Results demonstrate that wood gasification process occurs with high temperature (1188 K) and oxygen available, and the lean hybrid filtration process can be used to reform solid fuels into hydrogen and syngas.

Karina Araus; Felipe Reyes; Mario Toledo

2014-01-01T23:59:59.000Z

117

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1  

SciTech Connect (OSTI)

Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1992-06-10T23:59:59.000Z

118

Numerical prediction of interaction between combustion, acoustics and vibration in gas turbines  

Science Journals Connector (OSTI)

The turbulent flame in the lean combustion regime in a gas turbine combustor generates significant thermo?acoustic instabilities. The flame can amplify fluctuations in the released heat and thus in the acoustic field as well. The induced pressure oscillations will drive vibrations of the combustor walls and burner parts. Stronger fluctuating pressure results in stronger fluctuations in the wall structure. Due to fatigue the remaining life time of the hard ware will be reduced significantly. This paper investigates modeling of acoustic oscillations and mechanical vibrations induced by lean premixed natural gascombustion. The mutual interaction of the combustion processes induced oscillating pressure field in the combustion chamber and induced vibration of the liner walls are investigated with numerical techniques. A partitioned procedure is used here: CFX?10 for the CFD analysis and Ansys?10 for the CSD analysis are coupled to give insight into a correlation between acoustic pressure oscillations and liner vibrations. These results will be compared with the available experimental data. The data are gathered in a purpose built 500 kW/5 bar premixed natural gas test rig.

Artur Pozarlik; Jim B. Kok

2008-01-01T23:59:59.000Z

119

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 5. Appendix G. Final report, June 1980-June 1984  

SciTech Connect (OSTI)

This report, Appendix G, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes under laboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Williamson, H.J.; Grimshaw, T.W.; Dunn, J.E.

1985-02-01T23:59:59.000Z

120

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 3. Appendices D and E. Final report, June 1980-June 1984  

SciTech Connect (OSTI)

This report, Appendices D and E, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes under laboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Minear, R.A.; Grimshaw, T.W.; Little, W.M.

1985-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 6. Appendix H. Final report, June 1980-June 1984  

SciTech Connect (OSTI)

This report, Appendix H, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes underlaboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Williamson, H.J.; Heinrich, D.L.; Grimshaw, T.W.

1985-02-01T23:59:59.000Z

122

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 7. Appendix I. Final report, June 1980-June 1984  

SciTech Connect (OSTI)

This report, Appendix 1, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes under laboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Eklund, A.G.; Grimshaw, T.W.; Minear, R.A.

1985-02-01T23:59:59.000Z

123

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 2. Appendices A through C. Final report, June 1980-June 1984  

SciTech Connect (OSTI)

This report Appendices A through C, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes under laboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Little, W.M.; Gibson, T.S.; Grimshaw, T.W.; Eklund, A.G.

1985-02-01T23:59:59.000Z

124

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 1. Final report. Report for June 1980-June 1984  

SciTech Connect (OSTI)

This report, including 10 appendices, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes under laboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Grimshaw, T.W.; Minear, R.A.; Eklund, A.G.; Little, W.M.; Dunn, J.E.

1985-02-01T23:59:59.000Z

125

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 4. Appendix F. Final report, June 1980-June 1984  

SciTech Connect (OSTI)

This report, Appendix F, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes under laboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Eklund, A.G.; Grimshaw, T.W.

1985-02-01T23:59:59.000Z

126

Assessment of fluidized-bed-combustion solid wastes for land disposal. Volume 8. Appendix J. Final report, June 1980-June 1984  

SciTech Connect (OSTI)

This report, Appendix J, gives results of: (1) an analysis of representative samples of fluidized-bed-combustion (FBC) wastes, (2) an assessment of the characteristics of leachates generated from the wastes under laboratory and field (landfill) conditions, (3) a characterization of the attenuation of the leachates by earth materials that are typical of disposal settings, (4) development of a way to predict the leachate generation behavior of FBC wastes under landfill conditions on the basis of laboratory test results by establishing a rigorous statistical relationship between the laboratory and field-leaching results, and (5) assessment of the compatibility of commonly used landfill-liner materials with FBC waste leachates. FBC is an emerging energy technology that holds promise for both high efficiency of energy conversion and minimization of adverse air-quality impacts. A major advantage of FBC is that high-sulfur coal can be burned without the use of flue-gas desulfurization equipment to meet air-quality standards. The solid residues that are generated in an FBC unit are usually larger in volume and have different properties than the typical bottom ash from a conventional boiler.

Williamson, H.J.; South, R.C.; Grimshaw, T.W.

1985-02-01T23:59:59.000Z

127

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents [OSTI]

The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

1997-01-01T23:59:59.000Z

128

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents [OSTI]

The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

Yang, W.C.; Newby, R.A.; Lippert, T.E.

1997-08-05T23:59:59.000Z

129

NO, Reduction in a Gas Fired Utility Boiler by Combustion Modifications  

E-Print Network [OSTI]

Data on the effect of several combustion modifications on the for-math of nitrogen oxides and on boiler efficiency were acquired and analyzed for a 110 MW gas fired utility boiler. The results from the study showed that decreasing the oxygen in the flue gas from 2.2% to 0.6 % reduced the NO, formation by 33 % and also gave better boiler efficiencies. Flue gas recirculation through the bottom of the fire4mx WBS founb to be Ineffective. Staged combustion was found to reduce the NO, emlssions by as much as 55 % while decreasing the efficiency by about 5%. Adjustment of the burner air registers reduced the NO, formation by about 20 ppm. The lowest NO, emisdons of 42 ppm (at about 3 % 02) in the stack was obtained for air only to one top burner and 0.5 % oxygen in the flue gas. The reduction of nitrogen oxides (NO,) emissions from steam boilers has been under study for several years. The NO, from boilers consist almost entirely of nitric oxide (NO) and nitrogen dioxide (N02) with NO2 usually only l or 2 % of the total. After leaving the stack, the NO eventually combines with atmospheric oxygen to form NOp. The Environmental Protection Agency has sponsored several studies1-I0 on reducing NO, emissions while maintaining thermal efficiency of boilers. Other studies have been sponsored by The Electric Power Research Institute (EPRI) " and Argonne National

Jerry A. Bullin; Dan Wilkerson

1982-01-01T23:59:59.000Z

130

DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS FIRED COMBUSTION SYSTEMS  

SciTech Connect (OSTI)

This report provides results from the second year of this three-year project to develop dilution measurement technology for characterizing PM2.5 (particles with aerodynamic diameter smaller than 2.5 micrometers) and precursor emissions from stationary combustion sources used in oil, gas and power generation operation. Detailed emission rate and chemical speciation tests results for a gas turbine, a process heater, and a commercial oil/gas fired boiler are presented. Tests were performed using a research dilution sampling apparatus and traditional EPA methods. A series of pilot tests were conducted to identify the constraints to reduce the size of current research dilution sampler for future stack emission tests. Based on the test results, a bench prototype compact dilution sampler developed and characterized in GE EER in August 2002.

Glenn England; Oliver Chang; Stephanie Wien

2002-02-14T23:59:59.000Z

131

A Novel High-Heat Transfer Low-NO{sub x} Natural Gas Combustion System. Final Technical Report  

SciTech Connect (OSTI)

A novel high-heat transfer low NO(sub x) natural gas combustion system. The objectives of this program are to research, develop, test, and commercialize a novel high-heat transfer low-NO{sub x} natural gas combustion system for oxygen-, oxygen-enriched air, and air-fired furnaces. This technology will improve the process efficiency (productivity and product quality) and the energy efficiency of high-temperature industrial furnaces by at least 20%. GTI's high-heat transfer burner has applications in high-temperature air, oxygen-enriched air, and oxygen furnaces used in the glass, metals, cement, and other industries. Development work in this program is focused on using this burner to improve the energy efficiency and productivity of glass melting furnaces that are major industrial energy consumers. The following specific project objectives are defined to provide a means of achieving the overall project objectives. (1) Identify topics to be covered, problems requiring attention, equipment to be used in the program, and test plans to be followed in Phase II and Phase III. (2) Use existing codes to develop models of gas combustion and soot nucleation and growth as well as a thermodynamic and parametric description of furnace heat transfer issues. (3) Conduct a parametric study to confirm the increase in process and energy efficiency. (4) Design and fabricate a high-heat transfer low-NOx natural gas burners for laboratory, pilot- and demonstration-scale tests. (5) Test the high-heat transfer burner in one of GTI's laboratory-scale high-temperature furnaces. (6) Design and demonstrate the high-heat transfer burner on GTI's unique pilot-scale glass tank simulator. (7) Complete one long term demonstration test of this burner technology on an Owens Corning full-scale industrial glass melting furnace. (8) Prepare an Industrial Adoption Plan. This Plan will be updated in each program Phase as additional information becomes available. The Plan will include technical and economic analyses, energy savings and waste reduction predictions, evaluation of environmental effects, and outline issues concerning manufacturing, marketing, and financing. Combustion Tec, Owens Corning, and GTI will all take active roles in defining this Plan. During Phase I, the first three objectives were addressed and completed along with the design component of the fourth objective. In Phase II, the fabrication component of the fourth objective was completed along with objectives five and six. Results of the Phase I work were reported in the Phase I Final Report and are summarized in this Final Technical Report. Work for Phase II was divided in four specific Tasks. Results of the Phase II work were reported in the Phase II Final Report and are also summarized in this Final Technical Report. No Phase III Final Report was prepared, so this Final Technical Report presents the results of Phase III commercial demonstration efforts. A description of each Task in Phases I, II, and III is presented in this report.

Abbasi, H.

2004-01-01T23:59:59.000Z

132

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending 31 December 1994  

SciTech Connect (OSTI)

The test plan is designed to demonstrate that oil shale co-combusted with municipal solid waste (MSW) can reduce gaseous pollutants (SO{sub 2}, CO) to acceptable levels (90%+ reduction) and produce a cementitious ash which will, at a minimum, be acceptable in normal land fills. The small-scale combustion testing will be accomplished in a 6-in. circulating fluid bed combustor (CFBC) at Hazen Research Laboratories. This work will be patterned after the study the authors conducted in 1988 when coal and oil shale were co-combusted in a program sponsored by the Electric Power Research Institute. The specific purpose of the test program will be to: determine the required ratio of oil shale to MSW by determining the ratio of absorbent to pollutant (A/P); determine the effect of temperature and resident time in the reactor; and determine if kinetic model developed for coal/oil shale mixture is applicable.

Not Available

1995-01-01T23:59:59.000Z

133

System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines  

SciTech Connect (OSTI)

Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

Shahrokh Etemad; Lance Smith; Kevin Burns

2004-12-01T23:59:59.000Z

134

16 - Ultra-low nitrogen oxides (NOx) emissions combustion in gas turbine systems  

Science Journals Connector (OSTI)

Abstract: The historical development of gas turbine low \\{NOx\\} combustion from the pioneering NASA work in the early 1970s to the present generation of ultra-low \\{NOx\\} industrial gas turbine combustors is reviewed. The principles of operation of single digit ultra-low \\{NOx\\} gas turbine combustion for industrial applications are outlined. The review shows the potential has been demonstrated by several investigators using different flame stabilizers for \\{NOx\\} to be reduced to 1 ppm at 1700 K, 2 ppm at 1800 K and 3–4 ppm at 1900 K with no influence of operating pressure and with a practical operating flame stability margin. Under these conditions it is shown that no thermal \\{NOx\\} should occur and all the \\{NOx\\} is formed by the prompt \\{NOx\\} mechanisms. The elimination of thermal \\{NOx\\} makes the \\{NOx\\} emissions independent of residence time or reference velocity and independent of pressure. Also there is no influence of air inlet temperature for the same flame temperature. Where legislation requires emissions to be as low as can be achieved, emissions below 4 ppm in production engines are current technology and this review shows the potential to get even lower than this in the future.

G.E. Andrews

2013-01-01T23:59:59.000Z

135

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D.; Bourcier, William L.

2014-08-19T23:59:59.000Z

136

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

2010-11-09T23:59:59.000Z

137

Combustion of Illinois coals and chars with natural gas. Final technical report, September 1, 1991--August 31, 1992  

SciTech Connect (OSTI)

Combined combustion of coal and natural gas offers advantages compared to burning coal or natural gas alone. For example, low volatile coals (or chars) derived from treatment or gasification processes can be of limited use due to their poor flammability characteristics. However, the use of natural gas in conjunction with the solid fuel can provide the necessary ``volatiles`` to enhance the combustion. Also, natural gas provides a clean cofiring fuel source which can enhance the usefulness of coals with high sulfur content. Addition of natural gas may reduce SO{sub x} emissions through increased sulfur retention in the ash and reduce NO{sub x} emissions by varying local stoichiometry and temperature levels. This research program addresses the contributions and the mechanisms of cofiring natural gas with Illinois coal through studies of particle ignition, burning rates and ash characterization.

Buckius, R.O.; Peters, J.E.; Krier, H. [Illinois Univ., Urbana-Champaign, IL (United States)

1992-12-31T23:59:59.000Z

138

Oxygen carrier development for chemical looping combustion of coal derived synthesis gas  

SciTech Connect (OSTI)

In the present work, NETL researchers have studied chemical looping combustion (CLC) with an oxygen carrier NiO/bentonite (60 wt.% NiO) for the IGCC systems utilizing simulated synthesis gas. Multi cycle CLC was conducted with NiO/Bentonite in TGA at atmospheric pressure and in a high pressure reactor in a temperature range between 700-900°C. Global reaction rates of reduction and oxidation as a function of conversion were calculated for all oxidation-reduction cycles utilizing the TGA data. The effect of particle size of the oxygen carrier on CLC was studied for the size between 20-200 mesh. The multi cycle CLC tests conducted in a high pressure packed bed flow reactor indicated constant total production of CO2 from fuel gas at 800°C and 900°C and full consumption of hydrogen during the reaction.

Siriwardane, R.V.; Chaudhari, K.; Zinn, A.N.; Simonyi, T.; Robinson, Clark; Poston, J.A.

2006-09-01T23:59:59.000Z

139

Stirling Engine Natural Gas Combustion Demonstration Program. Final report, October 1989-January 1991  

SciTech Connect (OSTI)

Fueled on natural gas, the Stirling engine is an inherently clean, quiet, and efficient engine. With increasing environmental concern for air quality and the increasingly more stringent requirements for low engine exhaust emissions, the Stirling engine may be an attractive alternative to internal combustion (IC) engines. The study has demonstrated that ultra low emissions can be attained with a Stirling-engine-driven electric generator configured to burn natural gas. Combustion parameters were optimized to produce the lowest possible exhaust emissions for a flame-type combustor without compromising overall engine thermal efficiency. A market application survey and manufacturing cost analysis indicate that a market opportunity potentially exists in the volumes needed to economically manufacture a newly designed Stirling engine (Mod III) for stationary applications and hybrid vehicles. The translation of such potential markets into actual markets does, however, pose difficult challenges as substantial investments are required. Also, the general acceptance of a new engine type by purchasers requires a considerable amount of time.

Ernst, W.; Moryl, J.; Riecke, G.

1991-02-01T23:59:59.000Z

140

Heat loss reduction and hydrocarbon combustion in ultra-micro combustors for ultra-micro gas turbines  

Science Journals Connector (OSTI)

For the development of ultra-micro combustors for Ultra-Micro Gas Turbines (UMGT), heat loss reduction and hydrocarbon fuel use are the key issues. An approach for reducing the effect of heat loss in ultra-micro combustors was proposed. The heat loss ratio (HLR), which was defined as the ratio of heat loss rate from a combustor to heat release rate in the combustor, was related to the space heating rate (SHR), and experiments using some flat-flame ultra-micro combustors with hydrogen/air premixture exhibited the relation of HLR ? SHR?0.92/? (?, characteristic length of combustor). From the viewpoint of heat loss reduction, burning at high SHR in compact ultra-micro combustors is essential for a practical UMGT combustor. As for hydrocarbon combustion, the flat-flame burning method with and without catalyst was applied to propane fuel. The flat-flame combustor, having an inner diameter of 18.5 mm, a height of 3.5 mm, and a volume of 0.806 cm3, could form a propane flame successfully in the chamber without a catalyst and achieved an extremely high SHR of 3370 MW/(MPa m3). Flame stable region was wide enough, and the combustion efficiency achieved was more than 99.4% between the equivalence ratios of 0.5 and 0.7 at m ? a = 0.06 g / s . The flat-flame combustor using a Pt-impregnated porous plate showed catalytic combustion, but did not improve the combustion characteristic. On the other hand, the flat-flame combustor using a nozzle whose surface was covered with Pt showed a combination of catalytic and gas-phase combustion with improved combustion efficiency for a wider range of equivalence ratios, due to CO oxidation in the burned gas after gas-phase combustion in the chamber.

Takashi Sakurai; Saburo Yuasa; Taku Honda; Shoko Shimotori

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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141

Thermochemical Gasification of Biomass: Fuel Conversion, Hot Gas Cleanup and Gas Turbine Combustion  

Science Journals Connector (OSTI)

Air-blown fluidized bed biomass gasification integrated with a gas- and steam turbine combined cycle (BIGCC) is a potentially attractive way to convert biomass into electricity and heat with a high efficiency.

J. Andries; W. de Jong; P. D. J. Hoppesteyn…

2002-01-01T23:59:59.000Z

142

Open burning of household waste: Effect of experimental condition on combustion quality and emission of PCDD, PCDF and PCB  

Science Journals Connector (OSTI)

Open burning for waste disposal is, in many countries, the dominant source of polychlorinated dibenzodioxins, dibenzofurans and biphenyls (PCDD/PCDF/PCB) release to the environment. To generate emission factors for open burning, experimental pile burns of about 100 kg of household waste were conducted with emissions sampling. From these experiments and others conducted by the same authors it is found that less compaction of waste or active mixing during the fire – “stirring” – promotes better combustion (as evidenced by lower CO/CO2 ratio) and reduces emissions of PCDD/PCDF/PCB; an intuitive but previously undemonstrated result. These experiments also support previous results suggesting PCDD/PCDF/PCB generation in open burning – while still highly variable – tends to be greater in the later (smoldering) phases of burning when the CO/CO2 ratio increases.

Gustavo Solorzano-Ochoa; David A. de la Rosa; Pablo Maiz-Larralde; Brian K. Gullett; Dennis G. Tabor; Abderrahmane Touati; Barbara Wyrzykowska-Ceradini; Heidelore Fiedler; Todd Abel; William F. Carroll Jr.

2012-01-01T23:59:59.000Z

143

Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery  

SciTech Connect (OSTI)

Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25-207 kg CO{sub 2}-eq t{sup -1} rw. Within all process stages, the emission of fossil CO{sub 2} from the combustion of MSW was the main contributor (111-254 kg CO{sub 2}-eq t{sup -1} rw), while the substitution of electricity reduced the GHG emissions by 150-247 kg CO{sub 2}-eq t{sup -1} rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.

Yang Na [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Zhang Hua, E-mail: zhanghua_tj@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Chen Miao; Shao Liming [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); He Pinjing, E-mail: xhpjk@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China)

2012-12-15T23:59:59.000Z

144

Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, April 1--June 30, 1992  

SciTech Connect (OSTI)

This quarterly technical progress report summarizes work completed during the Seventh Quarter of the First Budget Period, April 1 through June 30, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion will include the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/Pressurized Circulating Fluidized Bed Gas Source; Hot Gas Cleanup Units to mate to all gas streams. Combustion Gas Turbine; Fuel Cell and associated gas treatment; and Externally Fired Gas Turbine/Water Augmented Gas Turbine. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

Not Available

1992-12-01T23:59:59.000Z

145

Impact of thermal barrier coating application on the combustion, performance and emissions of a diesel engine fueled with waste cooking oil biodiesel–diesel blends  

Science Journals Connector (OSTI)

Abstract Biodiesel fuel was produced from waste cooking oil by transesterification process. B20 and B50 blends of biodiesel–petroleum diesel were prepared. These blends and D2 fuels were tested in a single cylinder CI engine. Performance, combustion and emission values of the engine running with the mentioned fuels were recorded. Then the piston and both exhaust and intake valves of the test engine were coated with layers of ceramic materials. The mentioned parts were coated with 100 ?m of NiCrAl as lining layer. Later the same parts were coated with 400 ?m material of coating that was the mixture of 88% of ZrO2, 4% of MgO and 8% of Al2O3. After the engine coating process, the same fuels were tested in the coated engine at the same operation condition. Finally, the same engine out parameters were obtained and compared with those of uncoated engine parameters in order to find out how this modification would change the combustion, performance and emission parameters. Results showed that the modification of the engine with coating process resulted in better performance, especially in considerably lower brake specific fuel consumption (Bsfc) values. Besides, emissions of the engine were lowered both through coating process and biodiesel usage excluding the nitrogen oxides (NOx) emission. In addition, the results of the coated engine are better than the uncoated one in terms of cylinder gas pressure, heat release rate (HRR) and heat release (HR).

Selman Ayd?n; Cenk Say?n

2014-01-01T23:59:59.000Z

146

Waste utilization as an energy source: Municipal wastes. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning the utilization of municipal wastes as an energy source. Articles discuss energy derived from incineration/combustion, refuse-derived fuels, co-firing municipal waste and standard fuels, landfill gas production, sewage combustion, and other waste-to-energy technologies. Citations address economics and efficiencies of various schemes to utilize municipal waste products as energy sources. (Contains a minimum of 130 citations and includes a subject term index and title list.)

Not Available

1994-05-01T23:59:59.000Z

147

Mitigating the effect of siloxanes on internal combustion engines using landfill gasses  

DOE Patents [OSTI]

A waste gas combustion method that includes providing a combustible fuel source, in which the combustible fuel source is composed of at least methane and siloxane gas. A sodium source or magnesium source is mixed with the combustible fuel source. Combustion of the siloxane gas of the combustible fuel source produces a silicon containing product. The sodium source or magnesium source reacts with the silicon containing product to provide a sodium containing glass or sodium containing silicate, or a magnesium containing silicate. By producing the sodium containing glass or sodium containing silicate, or the magnesium containing silicate, or magnesium source for precipitating particulate silica instead of hard coating, the method may reduce or eliminate the formation of silica deposits within the combustion chamber and the exhaust components of the internal combustion engine.

Besmann, Theodore M

2014-01-21T23:59:59.000Z

148

Occurrence of Zinc and Lead in Aerosols and Deposits in the Fluidized-Bed Combustion of Recovered Waste Wood. Part 1: Samples from Boilers  

Science Journals Connector (OSTI)

1.1 Recovered Waste Wood (RWW) as a Fuel ... In recent years, concerns about the environment, depletion of fossil fuel resources, and economic considerations have increased interest in the use of biomass and waste-derived fuels for power production. ... Lundholm et al. found K2ZnCl4 as one of the main components of the aerosol particles in grate combustion of municipal solid waste (MSW). ...

Sonja Enestam; Christoffer Boman; Jere Niemi; Dan Boström; Rainer Backman; Kari Mäkelä; Mikko Hupa

2011-03-07T23:59:59.000Z

149

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

SciTech Connect (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

150

Advanced combustion zone retrofitting Lidkoeping BFB establishes a state-of-the-art design for waste firing  

SciTech Connect (OSTI)

The oil crisis in 1973 gave an impetus to the development of the fluidized bed combustion technology for power and heat generation with local, often low quality, fuels. Kvaerner delivered the first Bubbling Fluidized Bed (BFB) for Municipal Solid Waste (MSW) firing in 1979 and the first waste fired Circulating Fluidized Bed (CFB) in 1984. Since this introduction Kvaerner has delivered 13 fluidized beds based on MSW out of a total of over 60 BFB and CFB delivers (in the range 5--165 MW{sub ht}). The ever more stringent demands on emissions performance, efficiency and availability have induced a continuous series of design enhancements culminating in the state-of-the-art BFB boilers at Lidkoeping BFB (in operation since 1985 on shredded MSW) was induced by new emission standards and need for increased output. The modified design was based on learning experience from Kvaerner Waste To Energy (WTE) BFB installations and an extensive R and D program. The design has fulfilled all expectations and established a third generation design for MSW fueled BFB-boilers. The green field installation at BCH Energy will commence operation in 1995. Design features include the Advanced Combustion Zone with an air swept fuel inlet spout, an asymmetrical overfire air (OFA) system installed in a double arch arrangement and directional bottom air nozzles. Also included are an integrated ash classifier, an improved back pass surface arrangement and a SNCR-system based on NH{sub 3}.

Tellgren, E.; Hagman, U.; Victoren, A.

1995-12-31T23:59:59.000Z

151

Characterization of a gas burner to simulate a propellant flame and evaluate aluminum particle combustion  

SciTech Connect (OSTI)

This study details the characterization and implementation of a burner designed to simulate solid propellant fires. The burner was designed with the ability to introduce particles (particularly aluminum) into a gas flame. The aluminized flame conditions produced by this burner are characterized based on temperature and heat flux measurements. Using these results, flame conditions are quantified in comparison to other well-characterized reactions including hydrocarbon and propellant fires. The aluminized flame is also used to measure the burning rate of the particles. This work describes the application of this burner for re-creating small-scale propellant flame conditions and as a test platform for experiments that contribute to the development of a particle combustion model, particularly in propellant fires. (author)

Jackson, Matt [Engineering Department, West Texas A and M University, Canyon, TX 79016 (United States); Pantoya, Michelle L. [Mechanical Engineering Department, Texas Tech University, Lubbock, TX 79409 (United States); Gill, Walt [Sandia National Laboratories, Albuquerque, NM 87185 (United States)

2008-04-15T23:59:59.000Z

152

A new BML-based RANS modelling for the description of gas turbine typical combustion processes  

Science Journals Connector (OSTI)

The work is concentrated on the formulation and validation of integral models within RANS framework for the numerical prediction of the premixed and partially premixed flames occurring in gas turbine combustors. The premixed combustion modelling is based on the BML approach coupled to the mixing transport providing variable equivalence ratio. Chemistry is described by means of ILDM model solving transport equations for reaction progress variables conditioned on the flame front. Multivariate presumed PDF model is used for the turbulence-chemistry interaction treatment. Turbulence is modelled using the second moment closure (SMC) and the standard ?-? model as well. The influence of non-gradient turbulent transport is investigated comparing the gradient diffusion closure and the solution of the scalar flux transport equations. Different model combinations are assessed simulating several premixed and partially premixed flame configurations and comparing results to the experimental data. The proposed model provides good predictions particularly in combination with SMC.

A. Maltsev; A. Sadiki; J. Janicka

2004-01-01T23:59:59.000Z

153

Effect of fuel gas composition in chemical-looping combustion with Ni-based oxygen carriers. 1. Fate of sulfur  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) has been suggested among the best alternatives to reduce the economic cost of CO{sub 2} capture using fuel gas because CO{sub 2} is inherently separated in the process. For gaseous fuels, natural gas, refinery gas, or syngas from coal gasification can be used. These fuels may contain different amounts of sulfur compounds, such as H{sub 2}S and COS. An experimental investigation of the fate of sulfur during CH{sub 4} combustion in a 500 W{sub th} CLC prototype using a Ni-based oxygen carrier has been carried out. The effect on the oxygen carrier behavior and combustion efficiency of several operating conditions such as temperature and H{sub 2}S concentration has been analyzed. Nickel sulfide, Ni3S{sub 2}, was formed at all operating conditions in the fuel reactor, which produced an oxygen carrier deactivation and lower combustion efficiencies. However, the oxygen carrier recovered their initial reactivity after certain time without sulfur addition. The sulfides were transported to the air reactor where SO{sub 2} was produced as final gas product. Agglomeration problems derived from the sulfides formation were never detected during continuous operation. Considering both operational and environmental aspects, fuels with sulfur contents below 100 vppm H{sub 2}S seem to be adequate to be used in an industrial CLC plant.

Garcia-Labiano, F.; de Diego, L.F.; Gayan, P.; Adanez, J.; Abad, A.; Dueso, C. [CSIC, Zaragoza (Spain)

2009-03-15T23:59:59.000Z

154

Multi-zone modelling of partially premixed low-temperature combustion in pilot-ignited natural-gas engines  

SciTech Connect (OSTI)

Detailed results from a multi-zone phenomenological simulation of partially premixed advanced-injection low-pilot-ignited natural-gas low-temperature combustion are presented with a focus on early injection timings (the beginning of (pilot) injection (BOI)) and very small diesel quantities (2-3 per cent of total fuel energy). Combining several aspects of diesel and spark ignition engine combustion models, the closed-cycle simulation accounted for diesel autoignition, diesel spray combustion, and natural-gas combustion by premixed turbulent flame propagation. The cylinder contents were divided into an unburned zone, several pilot fuel zones (or 'packets') that modelled diesel evaporation and ignition, a flame zone for natural-gas combustion, and a burned zone. The simulation predicted the onset of ignition, cylinder pressures, and heat release rate profiles satisfactorily over a wide range of BOIs (20-60���° before top dead centre (before TDC)) but especially well at early BOIs. Strong coupling was observed between pilot spray combustion in the packets and premixed turbulent combustion in the flame zone and, therefore, the number of ignition centres (packets) profoundly affected flame combustion. The highest local peak temperatures (greater than 2000 K) were observed in the packets, while the flame zone was much cooler (about 1650 K), indicating that pilot diesel spray combustion is probably the dominant source of engine-out emissions of nitrogen oxide (NO x). Further, the 60���° before TDC BOI yielded the lowest average peak packet temperatures (about 1720 K) compared with the 20���° before TDC BOI (about 2480 K) and 40���° before TDC BOI (about 2700 K). These trends support experimental NO x trends, which showed the lowest NO x emissions for the 60���°, 20���°, and 40���° before TDC BOIs in that order. Parametric studies showed that increasing the intake charge temperature, pilot quantity, and natural-gas equivalence ratio all led to higher peak heat release rates and hotter packets but the pilot quantity and intake temperature affected the potential for NO x formation to a greater extent.

Krishnan, S. R.; Srinivasan, K. K.

2010-06-29T23:59:59.000Z

155

Combustion Model for Engine Concept Development | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Model for Engine Concept Development Presentation shows how 1-cylinder testing, 3D combustion CFD and 1D gas exchange with an advanced combustion model are used...

156

Chemical-looping combustion of simulated synthesis gas using nickel oxide oxygen carrier supported on bentonite  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) is a combustion technology for clean and efficient utilization of fossil fuels for energy production. This process which produces sequestration ready CO2 systems is a promising technology to be utilized with coal gasification systems. In the present work, chemical-looping combustion has been studied with an oxygen carrier, NiO/bentonite (60 wt % NiO) for the gasification systems utilizing simulated synthesis gas. Global reaction rates of reduction and oxidation as a function of conversion were calculated for oxidation-reduction cycles utilizing the thermogravimetric analysis (TGA) data on multicycle tests conducted with NiO/bentonite at atmospheric pressure between 700 and 900 °C. The rate of reduction increased slightly with an increase in temperature, while the rate of oxidation decreased at 900 °C. The effect of particle size of the oxygen carrier on CLC was studied for the particle size between 20 and 200 mesh. The rates of reactions depended on the particle size of the oxygen carrier. The smaller the particle size, the higher the reaction rates. The multicycle CLC tests conducted in a high-pressure flow reactor showed stable reactivity for the production of CO2 from fuel gas at 800 and 900 °C and full consumption of hydrogen during the reaction. The data from a one cycle test on the effect of the pressure on the performance with NiO/bentonite utilizing the tapered element oscillating microbalance (TEOM) showed a positive effect of the pressure on the global rates of reduction-oxidation reactions at higher fractional conversions. The X-ray diffraction (XRD) analysis confirmed the presence of the NiO phase in NiO/bentonite with the oxidized sample in the highpressure reactor and Ni phase with the reduced sample. The presence of a small amount of NiO in the reduced sample detected by X-ray photoelectron spectroscopy (XPS) may be due to its exposure to air during sample transfer from the reactor to XPS. Scanning electron microscopy (SEM) analysis showed no significant changes in morphology of NiO/bentonite reacted in the temperature range 700-800 °C in an atmospheric TGA for 10 oxidation-reduction cycles, but some loss of surface area and porosity was observed at 900 °C. This effect was found to be greater with increase in the particle size of the oxygen carrier.

Siriwardane, R.V.; Chaudhari, K.; Poston, J.A.; Zinn, A.; Simonyi, T.; Robinson, C.

2007-05-01T23:59:59.000Z

157

Flame kernel characterization of laser ignition of natural gas–air mixture in a constant volume combustion chamber  

Science Journals Connector (OSTI)

In this paper, laser-induced ignition was investigated for compressed natural gas–air mixtures. Experiments were performed in a constant volume combustion chamber, which simulate end of the compression stroke conditions of a SI engine. This chamber simulates the engine combustion chamber conditions except turbulence of air–fuel mixture. It has four optical windows at diametrically opposite locations, which are used for laser ignition and optical diagnostics simultaneously. All experiments were conducted at 10 bar chamber pressure and 373 K chamber temperature. Initial stage of combustion phenomena was visualized by employing Shadowgraphy technique using a high speed CMOS camera. Flame kernel development of the combustible fuel–air mixture was investigated under different relative air–fuel ratios (?=1.2?1.7) and the images were interrogated for temporal propagation of flame front. Pressure-time history inside the combustion chamber was recorded and analyzed. This data is useful in characterizing the laser ignition of natural gas–air mixture and can be used in developing an appropriate laser ignition system for commercial use in SI engines.

Dhananjay Kumar Srivastava; Kewal Dharamshi; Avinash Kumar Agarwal

2011-01-01T23:59:59.000Z

158

Experimental study on combustion characteristics of a spark-ignition engine fueled with natural gas–hydrogen blends combining with EGR  

Science Journals Connector (OSTI)

An experimental study on the effect of hydrogen fraction and EGR rate on the combustion characteristics of a spark-ignition engine fueled with natural gas–hydrogen blends was investigated. The results show that flame development duration, rapid combustion duration and total combustion duration are increased with the increase of EGR rate and decreased with the increase of hydrogen fraction in the blends. Hydrogen addition shows larger influence on flame development duration than that on rapid combustion duration. The coefficient of variation of the indicated mean effective pressure increases with the increase of EGR rate. And hydrogen addition into natural gas decreases the coefficient of variation of the indicated mean effective pressure, and this effectiveness becomes more obviously at high EGR rate. Engine fueled with natural gas–hydrogen blends combining with proper EGR rate can realize the stable low temperature combustion in gas engine.

Erjiang Hu; Zuohua Huang; Bing Liu; Jianjun Zheng; Xiaolei Gu

2009-01-01T23:59:59.000Z

159

Combustion Timing Control of Natural Gas HCCI Engines Using Physics-Based Modeling and LQR Controller  

E-Print Network [OSTI]

Homogeneous Charge Compression Ignition (HCCI) Engines hold promises of being the next generation of internal combustion engines due to their ability to produce high thermal efficiencies and low emission levels. HCCI combustion is achieved through...

Abdelgawad, Marwa

2012-07-16T23:59:59.000Z

160

Non-adiabatic flamelet modeling for combustion processes of oxy-natural gas flame  

Science Journals Connector (OSTI)

In order to realistically predict the combustion characteristics of the oxy-fuel flame, the present study employs the non-adiabatic flamelet approach. In this combustion model, the detailed equilibrium chemist...

Gunhong Kim; Yongmo Kim

2005-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

PHYSICAL REVIEW E 90, 022139 (2014) Enhanced efficiency of internal combustion engines by employing spinning gas  

E-Print Network [OSTI]

PHYSICAL REVIEW E 90, 022139 (2014) Enhanced efficiency of internal combustion engines by employing; published 28 August 2014) The efficiency of the internal combustion engine might be enhanced by employing Optimizing the internal combustion engine to achieve the highest possible fuel efficiency can be approached

162

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect (OSTI)

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

163

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect (OSTI)

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

164

Chemical-looping combustion of coal-derived synthesis gas over copper oxide oxygen carriers  

SciTech Connect (OSTI)

CuO/bentonite and CuO-BHA nanocomposites were studied as oxygen carriers in chemical-looping combustion (CLC) of simulated synthesis gas. Global reaction rates of reduction and oxidation, as the function of reaction conversion, were calculated from 10-cycle oxidation/reduction tests utilizing thermogravimetric analysis at atmospheric pressure between 700 and 900 °C. It was found that the reduction reactions are always faster than oxidation reactions; reaction temperature and particle size do not significantly affect the reaction performance of CuO/bentonite. Multicycle CLC tests conducted in a high-pressure flow reactor showed stable reactivity for production of CO2 from fuel gas at 800 and 900 °C and full consumption of hydrogen during the reaction. Results of the tapered element oscillating microbalance showed a negative effect of pressure on the global rates of reduction-oxidation reactions at higher fractional conversions. X-ray diffraction patterns confirmed the presence of CuO in the bulk phase of the oxidized sample. Electron microanalysis showed significant morphology changes of reacted CuO/bentonite samples after the 10 oxidation-reduction cycles above 700 °C in an atmospheric thermogravimetric analyzer. The nanostructured CuO-BHA carrier also showed excellent stability and, in comparison to the CuO/bentonite system, slightly accelerated redox kinetics albeit at the expense of significantly increased complexity of manufacturing. Overall, both types of CuO carriers exhibited excellent reaction performance and thermal stability for the CLC process at 700-900 °C.

Tian, H.; Chaudhari, K.; Simonyi, T.; Poston, J.; Liu, T.; Sanders, T.; Veser, G.; Siriwardane, R.

2008-01-01T23:59:59.000Z

165

Chemical-looping combustion of coal-derived synthesis gas over copper oxide oxygen carriers  

SciTech Connect (OSTI)

CuO/bentonite and CuO?BHA nanocomposites were studied as oxygen carriers in chemical-looping combustion (CLC) of simulated synthesis gas. Global reaction rates of reduction and oxidation, as the function of reaction conversion, were calculated from 10-cycle oxidation/reduction tests utilizing thermogravimetric analysis at atmospheric pressure between 700 and 900 °C. It was found that the reduction reactions are always faster than oxidation reactions; reaction temperature and particle size do not significantly affect the reaction performance of CuO/bentonite. Multicycle CLC tests conducted in a high-pressure flow reactor showed stable reactivity for production of CO2 from fuel gas at 800 and 900 °C and full consumption of hydrogen during the reaction. Results of the tapered element oscillating microbalance showed a negative effect of pressure on the global rates of reduction?oxidation reactions at higher fractional conversions. X-ray diffraction patterns confirmed the presence of CuO in the bulk phase of the oxidized sample. Electron microanalysis showed significant morphology changes of reacted CuO/bentonite samples after the 10 oxidation?reduction cycles above 700 °C in an atmospheric thermogravimetric analyzer. The nanostructured CuO?BHA carrier also showed excellent stability and, in comparison to the CuO/bentonite system, slightly accelerated redox kinetics albeit at the expense of significantly increased complexity of manufacturing. Overall, both types of CuO carriers exhibited excellent reaction performance and thermal stability for the CLC process at 700?900 °C.

Tian, Hanjing; Chaudhari, K.P.; Simonyi, Thomas; Poston, J.A.; Liu, Tengfei; Sanders, Tom; Veser, Goetz; Siriwardane, R.V.

2008-11-01T23:59:59.000Z

166

Impact of Municipal Solid Waste (MSW) Quality on the Behavior of Alkali Metals and Trace Elements during Combustion: A Thermodynamic Equilibrium Analysis  

Science Journals Connector (OSTI)

Light, thermal- and bacterial-resistant, and inexpensive leathers, especially in the footwear industry, are obtained by the Cr tanning method. ... The selected waste items are representing the major combustible fractions found in MSW, i.e. paper, plastic, textile, and biogenic materials (both food and biomass), but also the other waste fraction (a mixed and poorly defined fraction). ... Pedersen et al.(6) studies six different waste fractions separately under different operational conditions in a full-scale incinerator: NaCl (road salt), household batteries, automotive shredder waste (rubber and plastics), Cu?Cr?As (CCA)-impregnated wood, PVC, and shoes (leather mainly). ...

Michae?l Becidan; Lars Sørum; Daniel Lindberg

2010-05-21T23:59:59.000Z

167

An Alternative to Performing Remote-Handled Transuranic Waste Container Headspace Gas Sampling and Analysis  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) is operating under a Resource Conservation and Recovery Act (RCRA) Hazardous Waste Facility Permit (HWFP) for contact-handled (CH) transuranic (TRU) waste. The HWFP contains limitations on allowable emissions from waste disposed in the underground. This environmental performance standard imposed on the WIPP consists of limiting volatile organic compound (VOC) emissions from emplaced waste to ensure protection of human health and the environment. The standard is currently met by tracking individual waste container headspace gas concentrations, which are determined by headspace gas sampling and analysis of CH TRU waste containers. The WIPP is seeking a HWFP modification to allow the disposal of remote-handled (RH) TRU waste. Because RH TRU waste is limited to approximately 5% of the waste volume and is emplaced in the disposal room walls, it is possible to bound the potential RH TRU waste contribution to VOC emissions using conservative upper bounds. These conservative upper bounds were developed as an alternative to RH TRU waste canister headspace gas sampling and analysis. The methodology used to perform the calculations used to evaluate VOC emissions from emplaced RH TRU waste canisters applied the same equations as those used to evaluate VOC emissions in the original HWFP application.

Spangler, L. R.; Djordjevic, S. M.; Kehrman, R. F.; Most, W. A.

2002-02-26T23:59:59.000Z

168

Gasification of waste rigid polyurethane foam: optimizing operational conditions  

Science Journals Connector (OSTI)

The influence of temperature and catalyst type on production of combustible gas during the air gasification of waste rigid polyurethane foam has been...16 (43...) of three parameters was employed to optimize the...

Xiaoya Guo; Lixin Wang; Shouguang Li…

2014-07-01T23:59:59.000Z

169

Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator  

SciTech Connect (OSTI)

This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

2006-07-01T23:59:59.000Z

170

Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant  

SciTech Connect (OSTI)

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter (chloride, fluoride, sulfur), will have high ammonia, and will contain carryover particulates of glass-former chemicals. These species have potential to cause corrosion of tanks and equipment, precipitation of solids, release of ammonia gas vapors, and scale in the tank farm evaporator. Routing this stream to the tank farms does not permanently divert it from recycling into the WTP, only temporarily stores it prior to reprocessing. Testing is normally performed to demonstrate acceptable conditions and limits for these compounds in wastes sent to the tank farms. The primary parameter of this phase of the test program was measuring the formation of solids during evaporation in order to assess the compatibility of the stream with the evaporator and transfer and storage equipment. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW facility melter offgas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and, thus, the composition will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. This report discusses results of evaporation testing of the simulant. Two conditions were tested, one with the simulant at near neutral pH, and a second at alkaline pH. The neutral pH test is comparable to the conditions in the Hanford Effluent Treatment Facility (ETF) evaporator, although that evaporator operates at near atmospheric pressure and tests were done under vacuum. For the alkaline test, the target pH was based on the tank farm corrosion control program requirements, and the test protocol and equipment was comparable to that used for routine evaluation of feed compatibility studies for the 242-A evaporator. One of the

Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

2014-01-27T23:59:59.000Z

171

Gas Combustion Appliances: Validating VENT-II Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Predicting Backdrafting and Spillage for Natural-Draft Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray Environmental Energy Technologies Division April 2013 In Press as: Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray. 2013. "Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: A Validation of VENT-II". HVAC&R Research, DOI:10.1080/10789669.2013.771948 LBNL-6193E 2 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof,

172

JV Task 5 - Evaluation of Residual Oil Fly Ash As A Mercury Sorbent For Coal Combustion Flue Gas  

SciTech Connect (OSTI)

The mercury adsorption capacity of a residual oil fly ash (ROFA) sample collected form Florida Power and Light Company's Port Everglades Power Plant was evaluated using a bituminous coal combustion flue gas simulator and fixed-bed testing protocol. A size-segregated (>38 {micro}g) fraction of ROFA was ground to a fine powder and brominated to potentially enhance mercury capture. The ROFA and brominated-ROFA were ineffective in capturing or oxidizing the Hg{sup 0} present in a simulated bituminous coal combustion flue gas. In contrast, a commercially available DARCO{reg_sign} FGD initially adsorbed Hg{sup 0} for about an hour and then catalyzed Hg{sup 0} oxidation to produce Hg{sup 2+}. Apparently, the unburned carbon in ROFA needs to be more rigorously activated in order for it to effectively capture and/or oxidize Hg{sup 0}.

Robert Patton

2006-12-31T23:59:59.000Z

173

SILICON CARBIDE MICRO-DEVICES FOR COMBUSTION GAS SENSING UNDER HARSH CONDITIONS  

SciTech Connect (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen containing species in chemically reactive, high temperature environments. For these capacitive sensors we have determined that the optimum sensor operating point in terms of sensor lifetime and response time is at midgap. Detailed measurements of the oxide leakage current as a function of temperature were performed to investigate the high temperature reliability of the devices. In addition, robust metallization and electrical contacting techniques have been developed for device operation at elevated temperatures. To characterize the time response of the sensor responses in the millisecond range, a conceptually new apparatus has been built. Using laser induced fluorescence imaging techniques we have shown that the gas underneath the sensor can be completely exchanged with a time constant under 1 millisecond. Ultrahigh vacuum studies of the surface chemistry of the platinum gate have shown that sensor deactivation by adsorbed sulfur is a possible problem. Investigations on the chemical removal of sulfur by catalytic oxidation or reduction are continuing.

Ruby N. Ghosh; Peter Tobias; Roger G. Tobin

2004-10-01T23:59:59.000Z

174

Chemical-looping combustion of coal-derived synthesis gas over copper oxide oxygen carriers  

SciTech Connect (OSTI)

CuO/bentonite and CuO-BHA nanocomposites were studied as oxygen carriers in chemical-looping combustion (CLC) of simulated synthesis gas. Global reaction rates of reduction and oxidation, as the function of reaction conversion, were calculated from 10-cycle oxidation/reduction tests utilizing thermogravimetric analysis at atmospheric pressure between 700 and 900{degree}C. It was found that the reduction reactions are always faster than oxidation reactions; reaction temperature and particle size do not significantly affect the reaction performance of CuO/bentonite. Multicycle CLC tests conducted in a high-pressure flow reactor showed stable reactivity for production of CO{sub 2} from fuel gas at 800 and 900{degree}C and full consumption of hydrogen during the reaction. Results of the tapered element oscillating microbalance showed a negative effect of pressure on the global rates of reduction-oxidation reactions at higher fractional conversions. X-ray diffraction patterns confirmed the presence of CuO in the bulk phase of the oxidized sample. Electron microanalysis showed significant morphology changes of reacted CuO/bentonite samples after the 10 oxidation-reduction cycles above 700{degree}C in an atmospheric thermogravimetric analyzer. The nanostructured CuO-BHA carrier also showed excellent stability and, in comparison to the CuO/bentonite system, slightly accelerated redox kinetics albeit at the expense of significantly increased complexity of manufacturing. Overall, both types of CuO carriers exhibited excellent reaction performance and thermal stability for the CLC process at 700-900{degree}C. 48 refs., 12 figs., 8 tabs.

Hanjing Tian; Karuna Chaudhari; Thomas Simonyi; James Poston; Tengfei Liu; Tom Sanders; Goetz Veser; Ranjani Siriwardane [U.S. Department of Energy, Morgantown, WV (United States). National Energy Technology Laboratory

2008-11-15T23:59:59.000Z

175

Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion Project. Quarterly report, April--June 1996  

SciTech Connect (OSTI)

The objective of this project is to evaluate hot gas particle control technologies using coal-derived as streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed Include the integration of the particulate control devices into coal utilization systems, on-line cleaning, techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing, Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: 1 . Carbonizer/Pressurized Circulating, Fluidized Bed Gas Source; 2. Hot Gas Cleanup Units to mate to all gas streams; 3. Combustion Gas Turbine; 4. Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during, this reporting period was continuing, the detailed design of the FW portion of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel is complete and the construction of steel for the coal preparation structure is complete.

NONE

1996-12-31T23:59:59.000Z

176

Vehicle Technologies Office: Advanced Combustion Engines | Department...  

Broader source: Energy.gov (indexed) [DOE]

Batteries Fuel Efficiency & Emissions Combustion Engines Fuel Effects on Combustion Idle Reduction Emissions Waste Heat Recovery Lightweighting Parasitic Loss Reduction Lubricants...

177

Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation  

SciTech Connect (OSTI)

The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

Rue, David

2013-09-30T23:59:59.000Z

178

Effect of ignition location on the in-process removal of combustion deposits from the output window of a gas turbine laser ignition system  

Science Journals Connector (OSTI)

The effect of ignition location on the effectiveness of combustion deposit removal from the reverse side of an optical window in a laser ignition system for use in gas turbines is presented. Such deposits consist of carbon and other by-products which accumulate on the walls of the chamber as a result of incomplete combustion. In laser based ignition systems this accumulation of combustion deposits has the potential to reduce the transmissive properties of the output window required for transmission of the laser radiation into the combustion chamber, adversely affecting the likelihood of successful ignition. In this work, a full empirical study into the in-process removal of combustion deposits from the reverse side of the optical window in a laser ignition system using a Q-switched Nd:YAG laser is presented, with an emphasis on the effect of ignition location on the effectiveness of combustion deposit removal. In addition, the mechanism of deposit removal is discussed.

J. Griffiths; J. Lawrence; P. Fitzsimons

2013-01-01T23:59:59.000Z

179

Silicon Carbide Micro-devices for Combustion Gas Sensing under Harsh Conditions  

SciTech Connect (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen-containing species in chemically reactive, high temperature environments. For fast and stable sensor response measurements, a gate activation process is required. Activation of all sensors took place by switching back and forth between oxidizing (1.0% oxygen in nitrogen) and reducing (10% hydrogen in nitrogen) gases for several hours at a sensor temperature {ge}620 C. All 52 devices on the sensor chip were activated simultaneously by flooding the entire chip with gas. The effects of activation on surface morphology and structure of Pt gates before and after activation were investigated. The optical images obtained from Pt gates demonstrated a clear transition from a smooth and shiny surface to a grainy and cloudy surface morphology. XRD scans collected from Pt gates suggest the presence of an amorphous layer and species other than Pt (111) after activation. The reliability of the gate insulator of our metal-oxide-SiC sensors for long-term device operation at 630 C was studied. We find that the dielectric is stable against breakdown due to electron injection from the substrate with gate leakage current densities as low at 5nA/cm{sup 2} at 630 C. We also designed and constructed a new nano-reactor capable of high gas flow rates at elevated pressure. Our reactor, which is a miniature version of an industrial reactor, is designed to heat the flowing gas up to 700 C. Measurements in ultrahigh vacuum demonstrated that hydrogen sulfide readily deposits sulfur on the gate surface, even at the very high hydrogen/hydrogen sulfide ratios (10{sup 3}-10{sup 5}) expected in applications. Once deposited, the sulfur adversely affects sensor response, and could not be removed by exposure to hydrogen at the temperatures and pressures accessible in the ultrahigh vacuum experiments. Oxygen exposures, however, were very effective at removing sulfur, and the device performance after sulfur removal was indistinguishable from performance before exposure to H{sub 2}S.

Ruby N. Ghosh; Reza Loloee; Roger G. Tobin; Yung Ho Kahng

2006-04-01T23:59:59.000Z

180

Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, January 1--March 31, 1992  

SciTech Connect (OSTI)

This quarterly technical progress report summarizes work completed during the Sixth Quarter of the First Budget Period, January 1 through March 31, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. The major emphasis during this reporting period was expanding the test facility to address system integration issues of hot particulate removal in advanced power generation systems. The conceptual design of the facility was extended to include additional modules for the expansion of the test facility, which is referred to as the Power Systems Development Facility (PSOF). A letter agreement was negotiated between Southern Company Services (SCS) and Foster Wheeler (FW) for the conceptual design of the Advanced Pressurized Fluid-Bed Combustion (APFBC)/Topping Combustor/Gas Turbine System to be added to the facility. The expanded conceptual design also included modifications to the existing conceptual design for the Hot Gas Cleanup Test Facility (HGCTF), facility layout and balance of plant design for the PSOF. Southern Research Institute (SRI) began investigating the sampling requirements for the expanded facility and assisted SCS in contacting Particulate Control Device (PCD) vendors for additional information. SCS also contacted the Electric Power Research Institute (EPRI) and two molten carbonate fuel cell vendors for input on the fuel cell module for the PSDF.

Not Available

1992-12-01T23:59:59.000Z

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181

Leaching behavior and possible resource recovery from air pollution control residues of fluidized bed combustion of municipal solid waste  

SciTech Connect (OSTI)

Ash residues are generated at several points during combustion of municipal solid waste (MSW), i.e., in cyclones, electrostatic precipitators and fabric filters. Such residues are of a complex physical and chemical nature and are often enriched in soluble salts and heavy metals such as Pb, Cd and Zn. Fluidized bed combustion (FBC) of MSW is a relatively new technique and very little information is available about the leaching behavior of its residues. In this study, the total elemental composition, mineralogy and leaching behavior of cyclone and bag-house filter ashes from a bubbling fluidized bed (BFB) boiler fired with municipal solid waste have been investigated. In addition, the possibilities of recovery heavy metals from these ashes were studied. The long-term leaching behavior of the ash constituents was evaluated using a two-step batch leaching test known as the CEN-test, whereas short and medium term leaching behavior was evaluated using a Column test. The extraction of elements from cyclone and filter ashes with various acidic solutions was also investigated. The leaching behavior of acid washed ashes was evaluated using the CEN test. The cyclone ash was mainly composed of aluminosilicate minerals, whereas the filter ash consisted of chlorides and hydroxides of alkali and alkaline earth metals. The concentration of heavy metals such as Zn, Cu, Cd and Pb was higher in the filter ash than in the cyclone ash. The leached amounts of sulfates and Pb from the cyclone ash decreased with leaching test contact time, indicating the formation of secondary mineral phases. Large amounts of chlorides, sulfates, Ca, Cu and Pb were leached from the filter ash. Acid extraction removed large amounts ({gt}50%) of Zn, Pb and Cu from the filter ash and approximately 56% of the total amount of Zn present in the cyclone ash. An efficient removal of heavy metal species from these types of ashes can probably be achieved by application of a recycling or multi-step process.

Abbas, Z.; Andersson, B.A.; Steenari, B.M.

1999-07-01T23:59:59.000Z

182

Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion  

SciTech Connect (OSTI)

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Fogash, Kevin

2010-09-30T23:59:59.000Z

183

Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion  

SciTech Connect (OSTI)

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Kevin Fogash

2010-09-30T23:59:59.000Z

184

A Multimedia Study of Hazardous Waste Landfill Gas Migration  

Science Journals Connector (OSTI)

Hazardous waste landfills pose uniquely challenging environmental problems which arise as a result of the chemical complexity of waste sites, their involvement of many environmental media, and their very size ...

Robert D. Stephens; Nancy B. Ball; Danny M. Mar

1986-01-01T23:59:59.000Z

185

Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...  

Broader source: Energy.gov (indexed) [DOE]

Generator (Waste Heat 1) - TEG 1 (preliminary assembly and testing) - TEG 2 (Bi-Te modules) - TEG 3 (Skutterudite and Bi-Te modules) * Develop Cost-Effective TEG (Waste Heat...

186

An acoustic energy framework for predicting combustion- driven acoustic instabilities in premixed gas-turbines  

E-Print Network [OSTI]

of Engineering for Gas Turbines and Power, 2000. Vol. 122:of Engineering for Gas Turbines and Power, 2000. Vol. 122:in Lean Premixed Gas Turbine Combustors," Journal of

Ibrahim, Zuhair M. A.

2007-01-01T23:59:59.000Z

187

Process system evaluation-consolidated letters. Volume 1. Alternatives for the off-gas treatment system for the low-level waste vitrification process  

SciTech Connect (OSTI)

This report provides an evaluation of alternatives for treating off-gas from the low-level waste (LLW) melter. The study used expertise obtained from the commercial nonradioactive off-gas treatment industry. It was assumed that contact maintenance is possible, although the subsequent risk to maintenance personnel was qualitatively considered in selecting equipment. Some adaptations to the alternatives described may be required, depending on the extent of contact maintenance that can be achieved. This evaluation identified key issues for the off-gas system design. To provide background information, technology reviews were assembled for various classifications of off-gas treatment equipment, including off-gas cooling, particulate control, acid gas control, mist elimination, NO{sub x} reduction, and SO{sub 2} removal. An order-of-magnitude cost estimate for one of the off-gas systems considered is provided using both the off-gas characteristics associated with the Joule-heated and combustion-fired melters. The key issues identified and a description of the preferred off-gas system options are provided below. Five candidate treatment systems were evaluated. All of the systems are appropriate for the different melting/feed preparations currently being considered. The lowest technical risk is achieved using option 1, which is similar to designs for high-level waste (HLW) vitrification in the Hanford Waste Vitrification Project (HWVP) and the West Valley. Demonstration Project. Option 1 uses a film cooler, submerged bed scrubber (SBS), and high-efficiency mist eliminator (HEME) prior to NO{sub x} reduction and high-efficiency particulate air (HEPA) filtration. However, several advantages were identified for option 2, which uses high-temperature filtration. Based on the evaluation, option 2 was identified as the preferred alternative. The characteristics of this option are described below.

Peurrung, L.M.; Deforest, T.J; Richards, J.R.

1996-03-01T23:59:59.000Z

188

Using Large Eddy Simulations to Understand Combustion Instabilities in Gas Turbines  

Science Journals Connector (OSTI)

This paper presents a study of the stability of a swirled premixed combustion chamber both with and without reaction using Large Eddy Simulation and a numerical solver able to handle complex geometries. It is ...

Thierry Poinsot; Jörg Schlüter…

2002-01-01T23:59:59.000Z

189

Thermochemical conversion of fuels into hydrogen-containing gas using recuperative heat of internal combustion engines  

Science Journals Connector (OSTI)

The problem of the thermochemical recuperation of heat from the exhaust gases of internal combustion engines (ICEs) as a method of ... the steam conversion of oxygen-containing fuels into syngas were developed, a...

V. A. Kirillov; A. B. Shigarov; N. A. Kuzin…

2013-09-01T23:59:59.000Z

190

Pressurised Combustion of Biomass-Derived, Low Calorific Value, Fuel Gas  

Science Journals Connector (OSTI)

During a 3 year (1996 – 1998) project, partly funded by the EU as part of their JOULE 3 programme, experimental and theoretical research will be done on the pressurised combustion of biomass-derived, LCV, fuel ga...

J. Andries; P. D. J. Hoppesteyn…

1997-01-01T23:59:59.000Z

191

Conversion of Waste CO2 and Shale Gas to High-Value Chemicals  

Broader source: Energy.gov [DOE]

The project aims to develop, build, operate, and validate a laboratory-scale continuous process that converts waste CO2 from industrial sources from shale gas into commodity chemical intermediates.

192

Advanced Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Systems Systems Advanced Combustion Background Conventional coal-fired power plants utilize steam turbines to generate electricity, which operate at efficiencies of 35-37 percent. Operation at higher temperatures and pressures can lead to higher efficiencies, resulting in reduced fuel consumption and lower greenhouse gas emissions. Higher efficiency also reduces CO2 production for the same amount of energy produced, thereby facilitating a reduction in greenhouse gas emissions. When combined, oxy-combustion comes with an efficiency hit, so it will actually increase the amount of CO2 to be captured. But without so much N2 in the flue gas, it will be easier and perhaps more efficient to capture, utilize and sequester. NETL's Advanced Combustion Project and members of the NETL-Regional University

193

Modelling and Numerical Simulation of Gas Migration in a Nuclear Waste Repository  

E-Print Network [OSTI]

We present a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological radioactive waste repository. This model includes capillary effects and the gas diffusivity. The choice of the main variables in this model, Total or Dissolved Hydrogen Mass Concentration and Liquid Pressure, leads to a unique and consistent formulation of the gas phase appearance and disappearance. After introducing this model, we show computational evidences of its adequacy to simulate gas phase appearance and disappearance in different situations typical of underground radioactive waste repository.

Bourgeat, Alain; Smai, Farid

2010-01-01T23:59:59.000Z

194

Characterization of Landfill Gas Composition at the Fresh Kills Municipal Solid-Waste Landfill  

Science Journals Connector (OSTI)

Characterization of Landfill Gas Composition at the Fresh Kills Municipal Solid-Waste Landfill ... The most common disposal method in the United States for municipal solid waste (MSW) is burial in landfills. ... Under the New Source Performance Standards and Emission Guidelines for MSW landfills, MSW operators are required to determine the nonmethane organic gas generation rate of their landfill through modeling and/or measurements. ...

Bart Eklund; Eric P. Anderson; Barry L. Walker; Don B. Burrows

1998-06-18T23:59:59.000Z

195

Heat-pipe gas-combustion system endurance test for Stirling engine. Final report, May 1990-September 1990  

SciTech Connect (OSTI)

Stirling Thermal Motors, Inc., (STM) has been developing a general purpose Heat Pipe Gas Combustion System (HPGC) suitable for use with the STM4-120 Stirling engine. The HPGC consists of a parallel plate recuperative preheater, a finned heat pipe evaporator and a film cooled gas combustor. A principal component of the HPGC is the heat pipe evaporator which collects and distributes the liquid sodium over the heat transfer surfaces. The liquid sodium evaporates and flows to the condensers where it delivers its latent heat. The report presents test results of endurance tests run on a Gas-Fired Stirling Engine (GFSE). Tests on a dynamometer test stand yielded 67 hours of engine operation at power levels over 10 kW (13.5 hp) with 26 hours at power levels above 15 kW (20 hp). Total testing of the engine, including both motoring tests and engine operation, yielded 245 hours of engine run time.

Mahrle, P.

1990-12-01T23:59:59.000Z

196

Effects of Combustion-Induced Vortex Breakdown on Flashback Limits of Syngas-Fueled Gas Turbine Combustors  

SciTech Connect (OSTI)

Turbine combustors of advanced power systems have goals to achieve very low pollutants emissions, fuel variability, and fuel flexibility. Future generation gas turbine combustors should tolerate fuel compositions ranging from natural gas to a broad range of syngas without sacrificing operational advantages and low emission characteristics. Additionally, current designs of advanced turbine combustors use various degrees of swirl and lean premixing for stabilizing flames and controlling high temperature NOx formation zones. However, issues of fuel variability and NOx control through premixing also bring a number of concerns, especially combustor flashback and flame blowout. Flashback is a combustion condition at which the flame propagates upstream against the gas stream into the burner tube. Flashback is a critical issue for premixed combustor designs, because it not only causes serious hardware damages but also increases pollutant emissions. In swirl stabilized lean premixed turbine combustors onset of flashback may occur due to (i) boundary layer flame propagation (critical velocity gradient), (ii) turbulent flame propagation in core flow, (iii) combustion instabilities, and (iv) upstream flame propagation induced by combustion induced vortex breakdown (CIVB). Flashback due to first two foregoing mechanisms is a topic of classical interest and has been studied extensively. Generally, analytical theories and experimental determinations of laminar and turbulent burning velocities model these mechanisms with sufficient precision for design usages. However, the swirling flow complicates the flashback processes in premixed combustions and the first two mechanisms inadequately describe the flashback propensity of most practical combustor designs. The presence of hydrogen in syngas significantly increases the potential for flashback. Due to high laminar burning velocity and low lean flammability limit, hydrogen tends to shift the combustor operating conditions towards flashback regime. Even a small amount of hydrogen in a fuel blend triggers the onset of flashback by altering the kinetics and thermophysical characteristics of the mixture. Additionally, the presence of hydrogen in the fuel mixture modifies the response of the flame to the global effects of stretch and preferential diffusion. Despite its immense importance in fuel flexible combustor design, little is known about the magnitude of fuel effects on CIVB induced flashback mechanism. Hence, this project investigates the effects of syngas compositions on flashback resulting from combustion induced vortex breakdown. The project uses controlled experiments and parametric modeling to understand the velocity field and flame interaction leading to CIVB driven flashback.

Ahsan Choudhuri

2011-03-31T23:59:59.000Z

197

Vehicle Technologies Office: Combustion Engine Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Engine Combustion Engine Research to someone by E-mail Share Vehicle Technologies Office: Combustion Engine Research on Facebook Tweet about Vehicle Technologies Office: Combustion Engine Research on Twitter Bookmark Vehicle Technologies Office: Combustion Engine Research on Google Bookmark Vehicle Technologies Office: Combustion Engine Research on Delicious Rank Vehicle Technologies Office: Combustion Engine Research on Digg Find More places to share Vehicle Technologies Office: Combustion Engine Research on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Combustion Engines Emission Control Waste Heat Recovery Fuels & Lubricants Materials Technologies Combustion Engine Research

198

Vehicle Technologies Office: Advanced Combustion Engines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Combustion Advanced Combustion Engines to someone by E-mail Share Vehicle Technologies Office: Advanced Combustion Engines on Facebook Tweet about Vehicle Technologies Office: Advanced Combustion Engines on Twitter Bookmark Vehicle Technologies Office: Advanced Combustion Engines on Google Bookmark Vehicle Technologies Office: Advanced Combustion Engines on Delicious Rank Vehicle Technologies Office: Advanced Combustion Engines on Digg Find More places to share Vehicle Technologies Office: Advanced Combustion Engines on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Combustion Engines Emission Control Waste Heat Recovery Fuels & Lubricants Materials Technologies Advanced Combustion Engines

199

CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS  

SciTech Connect (OSTI)

This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

2009-11-30T23:59:59.000Z

200

Combustion Characteristics and Heat Release Analysis of a Spark-Ignited Engine Fueled with Natural Gas?Hydrogen Blends  

Science Journals Connector (OSTI)

It can be seen that the laminar-burning velocity of hydrogen is 5 times that of natural gas and that the quenching distance of hydrogen is one-third that of natural gas, while the latter is beneficial to reduce the unburned hydrocarbons near the wall and from the top-land crevice. ... The signal of cylinder pressure was acquired for every 0.5 deg CA, the acquisition process covered 254 completed cycles, and the averaged value of these 254 cycles was outputted as the pressure data for calculation of the combustion parameters. ... Two factors are considered to influence the cylinder pressure:? one is the increase in flame propagation speed or combustion speed with the increase of the hydrogen fraction in the blends, and this will cause a rapid rising in the cylinder pressure and bring a higher value of the peak cylinder pressure; another is the decrease in the heating value of the fuel blends with the increase of the hydrogen fraction in natural gas?hydrogen blends, and this will decrease the volumetric heat release rate and the cylinder pressure rising, leading to the lower value of the peak cylinder pressure. ...

Zuohua Huang; Bing Liu; Ke Zeng; Yinyu Huang; Deming Jiang; Xibin Wang; Haiyan Miao

2007-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Pulse combustion  

Science Journals Connector (OSTI)

Pulse combustion has been gaining increased interest because of its potential for higher combustion efficiency greater combustion intensity and lower pollutant emissions. Unsteady combustion causes increased mass momentum and heat transfer. As a result reactants mix faster heat release is accelerated and heat transfer is enhanced in unsteady reacting flows. Many of these phenomena were discovered long ago by engineers looking for the cause of often detrimental combustion instabilities. Much more recently some of these enhanced transfer properties have been used to design efficient and compact pulse combustors. Although to date successful commercialization on a large scale has been limited to home heating units (e.g. the Lenox Pulse Furnace) highly efficient pulse spray dryers (Bepex Unison Dryer) pulse calciners and pulse waste incinerators have been designed. Pulsations have also been applied to carbon black fluidized bed gasifiers. Not all these designs will become economically viable. However the development of tunable pulse combustors that can be acoustically matched to the changing resonance frequency of these pulse processes have made many of them more promising. Recent findings that pulsation can enhance burning even in turbulent flows lend further encouragement to the developers of novel pulse combustion devices.

Jechiel I. Jagoda

2000-01-01T23:59:59.000Z

202

E-Print Network 3.0 - advanced wall-fired combustion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biomass and Animal Waste Combustion Energy Engine Emission Fuel Cells... Gasification Internal Combustion Engine Performance Pollutants Formation (NOx, Hg) and...

203

Neat Tallow Combustion in a Large Diesel Engine for Electricity Generation from Waste  

Science Journals Connector (OSTI)

This paper explores how neat tallow can be used as a renewable fuel from waste for electricity generation in a large direct injection (DI) diesel engine capable of burning higher viscosity fuel. ... The fuel supply panel is linked with the main engine control panel, so that any alarm state of the plant (i.e., grid voltage fault, engine overheating) results in automatic change over into diesel mode—system flushing. ... Reforming Mini Reactor ...

Jakub Piaszyk; Perry Leung; Miroslaw L. Wyszynski; Athanasios Tsolakis; Barney Williams; Paul Latham; Andrew P. E. York

2012-10-15T23:59:59.000Z

204

Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending December 31, 1995  

SciTech Connect (OSTI)

The objective of this project is to demonstrate that cocombustion of municipal solid waste and oil shale can reduce emissions of gaseous pollutants (SO{sub 2} and HCl) to acceptable levels. Tests in 6- and 15-inch units showed that the oil shale absorbs acid gas pollutants and produces an ash which could be, at the least, disposed of in a normal landfill. Further analysis of the results are underway to estimate scale-up to commercial size. Additional work will be done to evaluate the cementitious properties of oil shale ash.

NONE

1996-01-01T23:59:59.000Z

205

Gas temperature profiles at different flow rates and heating rates suffice to estimate kinetic parameters for fluidised bed combustion  

SciTech Connect (OSTI)

Experimental work on estimation kinetic parameters for combustion was conducted in a bench-scale fluidised bed (FB: 105x200mm). Combustion medium was obtained by using an electrical heater immersed into the bed. The ratio of heating rate (kJ/s) to molar flow rate of air (mol/s) regulated by a rheostat so that the heat of combustion (kJ/mol) can be synthetically obtained by an electrical power supply for relevant O{sub 2}-feedstock concentration (C{sub 0}). O{sub 2}-restriction ratio ({beta}) was defined by the ratio of O{sub 2}-feedstock concentration to O{sub 2}-air concentration (C{sub O{sub 2}-AIR}) at prevailing heating rates. Compressed air at further atmospheric pressure ({approx_equal}102.7kPa) entered the bed that was alumina particles (250{mu}m). Experiments were carried out at different gas flow rates and heating rates. FB was operated with a single charge of (1300g) particles for obtaining the T/T{sub 0} curves, and than C/C{sub 0} curves. The mathematical relationships between temperature (T) and conversion ratio (X) were expressed by combining total energy balance and mass balance in FB. Observed surface reaction rate constants (k{sub S}) was obtained from the combined balances and proposed model was also tested for these kinetic parameters (frequency factor: k{sub 0}, activation energy: E{sub A}, and reaction order: n) obtained from air temperature measurements. It was found that the model curves allow a good description of the experimental data. Thus, reaction rate for combustion was sufficiently expressed. (author)

Suyadal, Y. [Faculty of Engineering, Department of Chemical Engineering, Ankara University, 06100-Tandogan, Ankara (Turkey)

2006-07-15T23:59:59.000Z

206

Desulfurization of coke oven gas from the coking of coking coal blended with a sorbent and waste plastic  

Science Journals Connector (OSTI)

A new way to implement the simultaneous reutilization of solid waste, the desulfurization of coke oven gas (COG), and even the desulfurization of coke by the co-coking of coking coal (CC) and waste plastic (WP).....

Zhao Rongfang; Ye Shufeng; Xie Yusheng…

2007-03-01T23:59:59.000Z

207

Effects of Steam and CO2 in the Fluidizing Gas when Using Bituminous Coal in Chemical-Looping Combustion  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is a combustion technology where an oxygen carrier is used to transfer oxygen from the combustion air to the fuel in order to...2 is inherently separated from the flue gases with...

H. Leion; A. Lyngfelt; T. Mattisson

2010-01-01T23:59:59.000Z

208

On the dynamic nature of azimuthal thermoacoustic modes in annular gas turbine combustion chambers  

Science Journals Connector (OSTI)

...gas turbine combustor, it has...the dynamic pressure field which...requirements in real gas turbine applications...manner that high-amplitude...in annular gas turbines...bifurcations in gas turbine combustor. Int. J...effects on high-frequency...characteristics of pressure oscillations...

2013-01-01T23:59:59.000Z

209

Development of a dynamic simulator for a natural gas combined cycle (NGCC) power plant with post-combustion carbon capture  

SciTech Connect (OSTI)

The AVESTAR Center located at the U.S. Department of Energy’s National Energy Technology Laboratory and West Virginia University is a world-class research and training environment dedicated to using dynamic process simulation as a tool for advancing the safe, efficient and reliable operation of clean energy plants with CO{sub 2} capture. The AVESTAR Center was launched with a high-fidelity dynamic simulator for an Integrated Gasification Combined Cycle (IGCC) power plant with pre-combustion carbon capture. The IGCC dynamic simulator offers full-scope Operator Training Simulator (OTS) Human Machine Interface (HMI) graphics for realistic, real-time control room operation and is integrated with a 3D virtual Immersive Training Simulator (ITS), thus allowing joint control room and field operator training. The IGCC OTS/ITS solution combines a “gasification with CO{sub 2} capture” process simulator with a “combined cycle” power simulator into a single high-performance dynamic simulation framework. This presentation will describe progress on the development of a natural gas combined cycle (NGCC) dynamic simulator based on the syngas-fired combined cycle portion of AVESTAR’s IGCC dynamic simulator. The 574 MW gross NGCC power plant design consisting of two advanced F-class gas turbines, two heat recovery steam generators (HRSGs), and a steam turbine in a multi-shaft 2x2x1 configuration will be reviewed. Plans for integrating a post-combustion carbon capture system will also be discussed.

Liese, E.; Zitney, S.

2012-01-01T23:59:59.000Z

210

Development of thermoelectric power generation system utilizing heat of combustible solid waste  

SciTech Connect (OSTI)

The paper presents the development of thermoelectric power generation system utilizing heat of municipal solid waste. The systematic classification and design guideline are proposed in consideration of the characteristics of solid waste processing system. The conceptual design of thermoelectric power generation system is carried out for a typical middle scale incinerator system (200 ton/day) by the local model. Totally the recovered electricity is 926.5 kWe by 445 units (569,600 couples). In order to achieve detailed design, one dimensional steady state model taking account of temperature dependency of the heat transfer performance and thermoelectric properties is developed. Moreover, small scale on-site experiment on 60 W class module installed in the real incinerator is carried out to extract various levels of technological problems. In parallel with the system development, high temperature thermoelectric elements such as Mn-Si and so on are developed aiming the optimization of ternary compound and high performance due to controlled fine-grain boundary effect. The manganese silicide made by shrinking-rate controlled sintering method performs 5 ({mu}W/cm K{cflx 2}) in power factor at 800 K. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

Kajikawa, T.; Ito, M.; Katsube, I. [Shonan Institute of Technology, Fujisawa, Kanagawa, 251 (Japan); Shibuya, E. [NKK Corporation, Yokohama, Kanagawa, 230 (Japan)

1994-08-10T23:59:59.000Z

211

The effect of dilution on the gas retention behavior of Tank 241-SY- 103 waste  

SciTech Connect (OSTI)

Twenty-five of the 177 underground waste storage tanks on the Hanford Site have been placed on the Flammable Gas watch list. These 25 tanks, containing high-level waste generated during plutonium and uranium processing, have been identified as potentially capable of accumulating flammable gases above the lower flammability limit (Babad et al. 1991). In the case of Tanks 241-SY-101 and 241-SY-103, it has been proposed that diluting the tank waste may mitigate this hazard (Hudson et al. 1995; Stewart et al. 1994). The effect of dilution on the ability of waste from Tank 241-SY-103 to accumulate gas was studied at Pacific Northwest National Laboratory. A similar study has been completed for waste from Tank 241-SY-101 (Bredt et al. 1995). Because of the additional waste-storage volume available in Tank 241-SY-103 and because the waste is assumed to be similar to that currently in Tank 241-SY-101, Tank 241-SY-103 became the target for a demonstration of passive mitigation through in-tank dilution. In 1994, plans for the in-tank dilution demonstration were deferred pending a decision on whether to pursue dilution as a mitigation strategy. However, because Tank 241-SY-103 is an early retrieval target, determination of how waste properties vary with dilution will still be required.

Bredt, P.R.; Tingey, S.M.

1996-01-01T23:59:59.000Z

212

An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors  

SciTech Connect (OSTI)

This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

Townsend, Aaron K., E-mail: aarontownsend@utexas.edu [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States); Webber, Michael E. [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States)

2012-07-15T23:59:59.000Z

213

Compact Ceramic Heat Exchangers for Corrosive Waste Gas Applications  

E-Print Network [OSTI]

developed for low temperature corrosive gas situations and have been applied to the pottery industry and are being developed for coal fired air heaters for the food industry....

Laws, W. R.; Reed, G. R.

1982-01-01T23:59:59.000Z

214

Hot corrosion tests on corrosion resistant coatings developed for gas turbines burning biomass and waste derived fuel gases  

Science Journals Connector (OSTI)

Abstract This paper reports on results of hot corrosion tests carried out on silicon–aluminide coatings developed for hot components of gas turbines burning biomass and waste derived fuel gases. The corrosion tests of the silicon–aluminide coatings, applied to superalloys IN738LC and CMSX-4, each consisted of five 100 h periods; at 700 °C for the type II tests and at 900 °C for the type I tests. Deposits of Cd + alkali and Pb + alkali were applied before each exposure. These deposits had been previously identified as being trace species produced from gasification of biomass containing fuels which after combustion had the potential to initiate hot corrosion in a gas turbine. Additionally, gases were supplied to the furnace to simulate the atmosphere anticipated post-combustion of these biomass derived fuel gases. Results of the type I hot corrosion tests showed that these novel coatings remained in the incubation stage for at least 300 h, after which some of the coating entered propagation. Mass change results for the first 100 h confirmed this early incubation stage. For the type II hot corrosion tests, differences occurred in oxidation and sulphidation rates between the two substrates; the incubation stages for CMSX-4 samples continued for all but the Cd + alkali high salt flux samples, whereas, for IN738LC, all samples exhibited consistent incubation rates. Following both the type I and type II corrosion tests, assessments using BSE/EDX results and XRD analysis confirmed that there has to be remnant coating, sufficient to grow a protective scale. In this study, the novel silicon–aluminide coating development was based on coating technology originally evolved for gas turbines burning natural gas and fossil fuel oils. So in this paper comparisons of performance have been made with three commercially available coatings; a CoCrAlY overlay, a platinum-aluminide diffusion, and triple layer nickel–aluminide/silicon–aluminide-diffusion coatings. These comparisons showed that the novel single-step silicon–aluminide coatings provide equal or superior type II hot corrosion resistance to the best of the commercial coatings.

A. Bradshaw; N.J. Simms; J.R. Nicholls

2013-01-01T23:59:59.000Z

215

An overview of the sustainability of solid waste management at military installations  

E-Print Network [OSTI]

in conventional incinerators. Burning waste substantiallycontrolled burning or combustion of various types of waste.

Borglin, S.

2010-01-01T23:59:59.000Z

216

LABORATORY OPTIMIZATION TESTS OF TECHNETIUM DECONTAMINATION OF HANFORD WASTE TREATMENT PLANT LOW ACTIVITY WASTE OFF-GAS CONDENSATE SIMULANT  

SciTech Connect (OSTI)

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in greatest abundance in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are low but are also expected to be in measurable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, {sup 241}Pu, and {sup 241}Am. These are present due to their partial volatility and some entrainment in the off-gas system. This report discusses results of optimized {sup 99}Tc decontamination testing of the simulant. Testing examined use of inorganic reducing agents for {sup 99}Tc. Testing focused on minimizing the quantity of sorbents/reactants added, and minimizing mixing time to reach the decontamination targets in this simulant formulation. Stannous chloride and ferrous sulfate were tested as reducing agents to determine the minimum needed to convert soluble pertechnetate to the insoluble technetium dioxide. The reducing agents were tried with and without sorbents.

Taylor-Pashow, K.; Nash, C.; McCabe, D.

2014-09-29T23:59:59.000Z

217

Performance of a spark ignition, lean burn, natural gas internal combustion engine .  

E-Print Network [OSTI]

??Relative to gasoline and diesel, use of natural gas as a transport fuel can produce significantly lower emissions of particulate matter and greenhouse gases. Future… (more)

ABBASI ATIBEH, PAYMAN

2012-01-01T23:59:59.000Z

218

Hanford Low-Activity Waste Processing: Demonstration of the Off-Gas Recycle Flowsheet - 13443  

SciTech Connect (OSTI)

Vitrification of Hanford Low-Activity Waste (LAW) is nominally the thermal conversion and incorporation of sodium salts and radionuclides into borosilicate glass. One key radionuclide present in LAW is technetium-99. Technetium-99 is a low energy, long-lived beta emitting radionuclide present in the waste feed in concentrations on the order of 1-10 ppm. The long half-life combined with a high solubility in groundwater results in technetium-99 having considerable impact on performance modeling (as potential release to the environment) of both the waste glass and associated secondary waste products. The current Hanford Tank Waste Treatment and Immobilization Plant (WTP) process flowsheet calls for the recycle of vitrification process off-gas condensates to maximize the portion of technetium ultimately immobilized in the waste glass. This is required as technetium acts as a semi-volatile specie, i.e. considerable loss of the radionuclide to the process off-gas stream can occur during the vitrification process. To test the process flowsheet assumptions, a prototypic off-gas system with recycle capability was added to a laboratory melter (on the order of 1/200 scale) and testing performed. Key test goals included determination of the process mass balance for technetium, a non-radioactive surrogate (rhenium), and other soluble species (sulfate, halides, etc.) which are concentrated by recycling off-gas condensates. The studies performed are the initial demonstrations of process recycle for this type of liquid-fed melter system. This paper describes the process recycle system, the waste feeds processed, and experimental results. Comparisons between data gathered using process recycle and previous single pass melter testing as well as mathematical modeling simulations are also provided. (authors)

Ramsey, William G.; Esparza, Brian P. [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)] [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)

2013-07-01T23:59:59.000Z

219

Microbial Gas Generation Under Expected Waste Isolation Pilot Plant Repository Conditions: Final Report  

SciTech Connect (OSTI)

Gas generation from the microbial degradation of the organic constituents of transuranic (TRU) waste under conditions expected in the Waste Isolation Pilot Plant (WIPP) was investigated. The biodegradation of mixed cellulosic materials and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, hypalon, leaded hypalon, and neoprene) was examined. We evaluated the effects of environmental variables such as initial atmosphere (air or nitrogen), water content (humid ({approx}70% relative humidity, RH) and brine inundated), and nutrient amendments (nitogen phosphate, yeast extract, and excess nitrate) on microbial gas generation. Total gas production was determined by pressure measurement and carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) were analyzed by gas chromatography; cellulose degradation products in solution were analyzed by high-performance liquid chromatography. Microbial populations in the samples were determined by direct microscopy and molecular analysis. The results of this work are summarized.

Gillow, J.B.; Francis, A.

2011-07-01T23:59:59.000Z

220

Experimental investigation of wood combustion in a fixed bed with hot air  

SciTech Connect (OSTI)

Highlights: • Upward combustion is a new combustion concept with ignition by hot primary air. • Upward combustion has three stages: short drying, rapid devolatilization and char combustion. • Variation of fuel moisture and inert content have little influence on the combustion. • Experimental comparison between conventional and upward combustion is presented. - Abstract: Waste combustion on a grate with energy recovery is an important pillar of municipal solid waste (MSW) management in the Netherlands. In MSW incinerators fresh waste stacked on a grate enters the combustion chamber, heats up by radiation from the flame above the layer and ignition occurs. Typically, the reaction zone starts at the top of the waste layer and propagates downwards, producing heat for drying and devolatilization of the fresh waste below it until the ignition front reaches the grate. The control of this process is mainly based on empiricism. MSW is a highly inhomogeneous fuel with continuous fluctuating moisture content, heating value and chemical composition. The resulting process fluctuations may cause process control difficulties, fouling and corrosion issues, extra maintenance, and unplanned stops. In the new concept the fuel layer is ignited by means of preheated air (T > 220 °C) from below without any external ignition source. As a result a combustion front will be formed close to the grate and will propagate upwards. That is why this approach is denoted by upward combustion. Experimental research has been carried out in a batch reactor with height of 4.55 m, an inner diameter of 200 mm and a fuel layer height up to 1 m. Due to a high quality two-layer insulation adiabatic conditions can be assumed. The primary air can be preheated up to 350 °C, and the secondary air is distributed via nozzles above the waste layer. During the experiments, temperatures along the height of the reactor, gas composition and total weight decrease are continuously monitored. The influence of the primary air speed, fuel moisture and inert content on the combustion characteristics (ignition rate, combustion rate, ignition front speed and temperature of the reaction zone) is evaluated. The upward combustion concept decouples the drying, devolatilization and burnout phase. In this way the moisture and inert content of the waste have almost no influence on the combustion process. In this paper an experimental comparison between conventional and reversed combustion is presented.

Markovic, Miladin, E-mail: m.markovic@utwente.nl; Bramer, Eddy A.; Brem, Gerrit

2014-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Natural Gas Variability In California: Environmental Impacts And Device Performance Combustion Modeling of Pollutant Emissions From a Residential Cooking Range  

SciTech Connect (OSTI)

As part of a larger study of liquefied natural gas impacts on device performance and pollutant emissions for existing equipment in California, this report describes a cmoputer modeling study of a partially premixed flame issueing from a single cooktop burner port. The model consisted of a reactive computational fluid dynamics three-dimensional spatial grid and a 71-species chemical mechanism with propane combustion capability. Simulations were conducted with a simplified fuel mixture containing methane, ethane, and propane in proportions that yield properties similar to fuels distributed throughout much of California now and in recent years (baseline fuel), as well as with two variations of simulated liquefied natural gas blends. A variety of simulations were conducted with baseline fuel to explore the effect of several key parameters on pollutant formation and other flame characteristics. Simulations started with fuel and air issuing through the burner port, igniting, and continuing until the flame was steady with time. Conditions at this point were analyzed to understand fuel, secondary air and reaction product flows, regions of pollutant formation, and exhaust concentrations of carbon monoxide, nitric oxide and formaldehyde. A sensitivity study was conducted, varying the inflow parameters of this baseline gs about real-world operating conditions. Flame properties responded as expected from reactive flow theory. In the simulation, carbon monoxide levels were influenced more by the mixture's inflow velocity than by the gas-to-air ratio in the mixture issuing from the inflow port. Additional simulations were executed at two inflow conditions - high heat release and medium heat release - to examine the impact of replacing the baseline gas with two mixtures representative of liquefied natural gas. Flame properties and pollutant generation rates were very similar among the three fuel mixtures.

Tonse, S. R.; Singer, B. C.

2011-07-01T23:59:59.000Z

222

Sensitivity studies for gas release from the Waste Isolation Pilot Plant (WIPP)  

SciTech Connect (OSTI)

Sensitivity studies have been conducted for the gas release from the Waste Isolation Pilot Plant (WIPP) using the TOUGH2 computer code with performance measures of peak repository pressure and gas migration distance at 1000 years. The effect of formation permeabilities including impermeable halite, two-phase characteristic curves including different models and residual saturations, and other variations was studied to determine their impact on the performance of the WIPP repository. 15 refs., 7 figs., 2 tabs.

Webb, S.W.

1991-01-01T23:59:59.000Z

223

Options and costs for offsite disposal of oil and gas exploration and production wastes.  

SciTech Connect (OSTI)

In the United States, most of the exploration and production (E&P) wastes generated at onshore oil and gas wells are disposed of or otherwise managed at the well site. Certain types of wastes are not suitable for onsite management, and some well locations in sensitive environments cannot be used for onsite management. In these situations, operators must transport the wastes offsite for disposal. In 1997, Argonne National Laboratory (Argonne) prepared a report that identified offsite commercial disposal facilities in the United States. This information has since become outdated. Over the past year, Argonne has updated the study through contacts with state oil and gas agencies and commercial disposal companies. The new report, including an extensive database for more than 200 disposal facilities, provides an excellent reference for information about commercial disposal operations. This paper describes Argonne's report. The national study provides summaries of the types of offsite commercial disposal facilities found in each state. Data are presented by waste type and by disposal method. The categories of E&P wastes in the database include: contaminated soils, naturally occurring radioactive material (NORM), oil-based muds and cuttings, produced water, tank bottoms, and water-based muds and cuttings. The different waste management or disposal methods in the database involve: bioremediation, burial, salt cavern, discharge, evaporation, injection, land application, recycling, thermal treatment, and treatment. The database includes disposal costs for each facility. In the United States, most of the 18 billion barrels (bbl) of produced water, 149 million bbl of drilling wastes, and 21 million bbl of associated wastes generated at onshore oil and gas wells are disposed of or otherwise managed at the well site. However, under certain conditions, operators will seek offsite management options for these E&P wastes. Commercial disposal facilities are offsite businesses that accept and manage E&P wastes for a fee. Their services include waste management and disposal, transportation, cleaning of vehicles and tanks, disposal of wash water, and, in some cases, laboratory analysis. Commercial disposal facilities offer a suite of waste management methods and technologies.

Puder, M. G.; Veil, J. A.; Environmental Science Division

2007-01-01T23:59:59.000Z

224

Nanocomposite oxygen carriers for chemical-looping combustion of sulfur-contaminated synthesis gas  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) is an emerging technology for clean combustion. We have previously demonstrated that the embedding of metal nanoparticles into a nanostructured ceramic matrix can result in unusually active and sinter-resistant nanocomposite oxygen carrier materials for CLC, which combine the high reactivity of metals with the high-temperature stability of ceramics. In the present study, we investigate the effect of H{sub 2}S in a typical coal-derived syngas on the stability and redox kinetics of Ni- and Cu-based nanostructured oxygen carriers. Both carriers show excellent structural stability and only mildly changed redox kinetics upon exposure to H{sub 2}S, despite a significant degree of sulfide formation. Surprisingly, partial sulfidation of the support results in a strong increase in oxygen carrier capacity in both cases because of the addition of a sulfide-sulfate cycle. Overall, the carriers show great potential for use in CLC of high-sulfur fuels. 21 refs., 13 figs. 1 tab.

Rahul D. Solunke; Goetz Veser [United States Department of Energy, Pittsburgh, PA (United States). National Energy Technology Laboratory

2009-09-15T23:59:59.000Z

225

Turbulent combustion  

SciTech Connect (OSTI)

Turbulent combustion is the dominant process in heat and power generating systems. Its most significant aspect is to enhance the burning rate and volumetric power density. Turbulent mixing, however, also influences the chemical rates and has a direct effect on the formation of pollutants, flame ignition and extinction. Therefore, research and development of modern combustion systems for power generation, waste incineration and material synthesis must rely on a fundamental understanding of the physical effect of turbulence on combustion to develop theoretical models that can be used as design tools. The overall objective of this program is to investigate, primarily experimentally, the interaction and coupling between turbulence and combustion. These processes are complex and are characterized by scalar and velocity fluctuations with time and length scales spanning several orders of magnitude. They are also influenced by the so-called {open_quotes}field{close_quotes} effects associated with the characteristics of the flow and burner geometries. The authors` approach is to gain a fundamental understanding by investigating idealized laboratory flames. Laboratory flames are amenable to detailed interrogation by laser diagnostics and their flow geometries are chosen to simplify numerical modeling and simulations and to facilitate comparison between experiments and theory.

Talbot, L.; Cheng, R.K. [Lawrence Berkeley Laboratory, CA (United States)

1993-12-01T23:59:59.000Z

226

Winery waste makes fuel Electricity, bacteria break organics in wastewater into hydrogen gas  

E-Print Network [OSTI]

MSNBC.com Winery waste makes fuel Electricity, bacteria break organics in wastewater into hydrogen method for generating hydrogen fuel from wastewater is now operating at a California winery material in the wastewater into hydrogen gas. There is a lot more energy locked in the wastewater than

227

Simultaneous Gas Chromatographic Determination of Four Toxic Gases Generally Present in Combustion Atmospheres  

Science Journals Connector (OSTI)

......determining these gases in mixtures...dioxide, nitrogen, water vapor, and...determining these gases in mixtures...dioxide, nitrogen, water vapor, and...to the solubility of A HCN in water, which was...thevariationin gas con- centrations......

Boyd R. Endecott; Donald C. Sanders; Arvind K. Chaturvedi

1996-01-01T23:59:59.000Z

228

COMBUSTIVE APPROACH FOR MEASURING TOTAL VOLATILE PHOSPHORUS CONTENT IN LANDFILL GAS  

Science Journals Connector (OSTI)

A technique was developed to measure the total gaseous phosphorus content in biogas. The amount of air needed for a neutral to oxidising flame was mixed with the biogas. The gas mixture was burnt in a closed quar...

JORIS ROELS; FRANK VANHAECKE; WILLY VERSTRAETE

2005-02-01T23:59:59.000Z

229

Ignition of a combustible gas mixture by a laser spark excited in the reactor volume  

Science Journals Connector (OSTI)

Ignition of a stoichiometric CH4: O2 mixture by a laser spark excited in the reactor volume is ... which indicates fast (involving branching chain reactions) ignition of the gas mixture. A conclusion is ... regar...

S. Yu. Kazantsev; I. G. Kononov; I. A. Kossyi; N. M. Tarasova…

2009-03-01T23:59:59.000Z

230

SILICON CARBIDE MICRO-DEVICES FOR COMBUSTION GAS SENSING UNDER HARSH CONDITIONS  

SciTech Connect (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen containing species in chemically reactive, high temperature environments. Robust metallization and electrical contacting techniques have been developed for device operation at elevated temperatures. To characterize the time response of the sensor responses in the millisecond range, a conceptually new apparatus has been built. Software has been developed to cope with the requirements of fast sensor control and data recording. In addition user friendly software has been developed to facilitate use of the SiC sensors for industrial process control applications.

Ruby N. Ghosh; Peter Tobias; Roger G. Tobin

2004-04-01T23:59:59.000Z

231

Combustion Control  

E-Print Network [OSTI]

using a liquid fuel. The air and fuel valve designs are vastly different, with different flow characteristics. These factors make the initial adjustment of the system difficult, and proper maintenance of ratio accuracy unlikely. Linked valves... casing of the fuel control regulator with the combustion air piping. The upstream pressure on the burner air orifice is applied to the main diaphragm of the pressure balanced regulator. Assuming sufficient gas pressure at the regulator inlet...

Riccardi, R. C.

1984-01-01T23:59:59.000Z

232

Trigeneration scheme for energy efficiency enhancement in a natural gas processing plant through turbine exhaust gas waste heat utilization  

Science Journals Connector (OSTI)

The performance of Natural Gas Processing Plants (NGPPs) can be enhanced with the integration of Combined Cooling, Heating and Power (CCHP) generation schemes. This paper analyzes the integration of a trigeneration scheme within a NGPP, that utilizes waste heat from gas turbine exhaust gases to generate process steam in a Waste Heat Recovery Steam Generator (WHRSG). Part of the steam generated is used to power double-effect water–lithium bromide (H2O–LiBr) absorption chillers that provide gas turbine compressor inlet air-cooling. Another portion of the steam is utilized to meet part furnace heating load, and supplement plant electrical power in a combined regenerative Rankine cycle. A detailed techno-economic analysis of scheme performance is presented based on thermodynamic predictions obtained using Engineering Equation Solver (EES). The results indicate that the trigeneration system could recover 79.7 MW of gas turbine waste heat, 37.1 MW of which could be utilized by three steam-fired H2O–LiBr absorption chillers to provide 45 MW of cooling at 5 °C. This could save approximately 9 MW of electric energy required by a typical compression chiller, while providing the same amount of cooling. In addition, the combined cycle generates 22.6 MW of additional electrical energy for the plant, while process heating reduces furnace oil consumption by 0.23 MSCM per annum. Overall, the trigeneration scheme would result in annual natural gas fuel savings of approximately 1879 MSCM, and annual operating cost savings of approximately US$ 20.9 million, with a payback period of 1 year. This study highlights the significant economical and environmental benefits that could be achieved through implementation of the proposed integrated cogeneration scheme in NGPPs, particularly in elevated ambient temperature and humidity conditions such as encountered in Middle East facilities.

Sahil Popli; Peter Rodgers; Valerie Eveloy

2012-01-01T23:59:59.000Z

233

Waste Package Neutron Absorber, Thermal Shunt, and Fill Gas Selection Report  

SciTech Connect (OSTI)

Materials for neutron absorber, thermal shunt, and fill gas for use in the waste package were selected using a qualitative approach. For each component, selection criteria were identified; candidate materials were selected; and candidates were evaluated against these criteria. The neutron absorber materials evaluated were essentially boron-containing stainless steels. Two candidates were evaluated for the thermal shunt material. The fill gas candidates were common gases such as helium, argon, nitrogen, carbon dioxide, and dry air. Based on the performance of each candidate against the criteria, the following selections were made: Neutron absorber--Neutronit A978; Thermal shunt--Aluminum 6061 or 6063; and Fill gas--Helium.

V. Pasupathi

2000-01-28T23:59:59.000Z

234

Chapter 8 - Coal Combustion Residue Disposal Options  

Science Journals Connector (OSTI)

Abstract Coal combustion residues (CCRs) are presently regulated as solid waste (Subtitle D) under the Resource Conservation Recovery Act. Such classification promotes beneficial use by end-users i.e. mitigating excessive liability. According to the US Environmental Protection agency (USEPA), about 131 million tons of coal combustion residuals—including 71 million tons of fly ash, 20 million tons of bottom ash and boiler slag, and 40 million tons of flue gas desulfurization (FGD) material—were generated in the US in 2007. Of this, approximately 36% was disposed of in landfills, 21% was disposed of in surface impoundments, 38% was beneficially reused, and 5% was used as minefill. Stringent regulation, as Subtitle C (hazardous waste), would impose a perceived liability upon end-users; greatly reducing beneficial use opportunities. Mandatory use of synthetic liners—would not have prevented dike wall failure and fails to consider inherent engineering characteristics of CCRs.

Richard W. Goodwin

2014-01-01T23:59:59.000Z

235

Gas retention and release behavior in Hanford single-shell waste tanks  

SciTech Connect (OSTI)

This report describes the current understanding of flammable gas retention and release in Hanford single-shell waste tanks based on theory, experimental results, and observations of tank behavior. The single-shell tanks likely to pose a flammable gas hazard are listed and described, and photographs of core extrusions and the waste surface are included. The credible mechanisms for significant flammable gas releases are described, and release volumes and rates are quantified as much as possible. The only mechanism demonstrably capable of producing large ({approximately}100 m{sup 3}) spontaneous gas releases is the buoyant displacement, which occurs only in tanks with a relatively deep layer of supernatant liquid. Only the double-shell tanks currently satisfy this condition. All release mechanisms believed plausible in single-shell tanks have been investigated, and none have the potential for large spontaneous gas releases. Only small spontaneous gas releases of several cubic meters are likely by these mechanisms. The reasons several other postulated gas release mechanisms are implausible or incredible are also given.

Stewart, C.W.; Brewster, M.E.; Gauglitz, P.A.; Mahoney, L.A.; Meyer, P.A.; Recknagle, K.P.; Reid, H.C.

1996-12-01T23:59:59.000Z

236

Some recent advances in droplet combustion  

Science Journals Connector (OSTI)

This paper reviews the theoretical and experimental advances in droplet combustion since the 1982 Second International Colloquium on Drops and Bubbles. Specific topics discussed include multicomponent droplet combustion and microexplosion convection droplet combustion the combustion of slurries propellants and hazardous wastes soot formation in droplet burning and several miscellaneous subjects. Areas of further research are suggested.

C. K. Law

1990-01-01T23:59:59.000Z

237

US National Technical Meeting of the Combustion Institute  

E-Print Network [OSTI]

potential to enhance combustion performance in gas turbines and scramjet engines. Extensive efforts have

Ju, Yiguang

238

Greenhouse gas emissions from home composting of organic household waste  

SciTech Connect (OSTI)

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6-3.5 kg week{sup -1} and the temperature inside the composting units was in all cases only a few degrees (2-10 {sup o}C) higher than the ambient temperature. The emissions of methane (CH{sub 4}) and nitrous oxide (N{sub 2}O) were quantified as 0.4-4.2 kg CH{sub 4} Mg{sup -1} input wet waste (ww) and 0.30-0.55 kg N{sub 2}O Mg{sup -1} ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH{sub 4} and N{sub 2}O emissions) of 100-239 kg CO{sub 2}-eq. Mg{sup -1} ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH{sub 4} during mixing which was estimated to 8-12% of the total CH{sub 4} emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg{sup -1} ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO{sub 2}-eq. Mg{sup -1} ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.

Andersen, J.K., E-mail: jka@env.dtu.d [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark); Boldrin, A.; Christensen, T.H.; Scheutz, C. [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark)

2010-12-15T23:59:59.000Z

239

Initiation of ignition of a combustible gas mixture in a closed volume by the radiation of a high-power pulsed CO{sub 2} laser  

SciTech Connect (OSTI)

The results of experiments on initiating the ignition of a CH{sub 4} - O{sub 2} - SF{sub 6} triple gas mixture in a closed volume by the radiation of a high-power CO{sub 2} laser are presented. It is shown that spatially nonuniform (in the direction of the laser beam) gas heating by the laser radiation leads to formation of a fast combustion wave, propagating along the chamber axis and giving rise to 'instantaneous' ignition. At the threshold value 16.5 J of the laser radiation energy the fast combustion wave is transformed into a detonation wave, which causes an explosion and destruction of the reaction chamber.

Kazantsev, S Yu; Kononov, I G; Kossyi, I A; Popov, N A; Tarasova, N M; Firsov, K N

2012-01-31T23:59:59.000Z

240

Handbook of industrial and hazardous wastes treatment. 2nd ed.  

SciTech Connect (OSTI)

This expanded Second Edition offers 32 chapters of industry- and waste-specific analyses and treatment methods for industrial and hazardous waste materials - from explosive wastes to landfill leachate to wastes produced by the pharmaceutical and food industries. Key additional chapters cover means of monitoring waste on site, pollution prevention, and site remediation. Including a timely evaluation of the role of biotechnology in contemporary industrial waste management, the Handbook reveals sound approaches and sophisticated technologies for treating: textile, rubber, and timber wastes; dairy, meat, and seafood industry wastes; bakery and soft drink wastes; palm and olive oil wastes; pesticide and livestock wastes; pulp and paper wastes; phosphate wastes; detergent wastes; photographic wastes; refinery and metal plating wastes; and power industry wastes. This final chapter, entitled 'Treatment of power industry wastes' by Lawrence K. Wang, analyses the stream electric power generation industry, where combustion of fossil fuels coal, oil, gas, supplies heat to produce stream, used then to generate mechanical energy in turbines, subsequently converted to electricity. Wastes include waste waters from cooling water systems, ash handling systems, wet-scrubber air pollution control systems, and boiler blowdown. Wastewaters are characterized and waste treatment by physical and chemical systems to remove pollutants is presented. Plant-specific examples are provided.

Lawrence Wang; Yung-Tse Hung; Howard Lo; Constantine Yapijakis (eds.)

2004-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance  

SciTech Connect (OSTI)

A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

Andrew Seltzer; Zhen Fan

2011-03-01T23:59:59.000Z

242

Variability in natural gas fuel composition and its effects on the performance of catalytic combustion systems. Final report for period September 18, 1998 - September 17, 2000  

SciTech Connect (OSTI)

Natural gas is composed primarily of methane with small amounts of higher hydrocarbons and diluents, which vary by region and over time. Compositions of natural gas from domestic and worldwide sources were surveyed with respect to content of higher hydrocarbons and diluents. The survey showed slight compositional variability between most of the gases, with a small fraction of them containing significantly larger contents of higher hydrocarbons than the mean. As gas-fired turbines will be used for power generation all over the world, they will need to tolerate operation with fuels with a wide variety of compositions, particularly with respect to the concentration of higher hydrocarbons and diluents. Subscale catalytic combustion modules typical of those used in gas turbine power generation with ultra low emissions of pollutants were tested in a subscale test system with natural gas alone and with added known levels of hydrocarbon compounds and diluents. The range of compositions tested contained the range observed in the survey. Test results were used to calculate the effect of composition on catalyst performance. The compositional variability is of little consequence to the catalyst for most of the gases in the survey, including nearly all of the gases delivered in the U.S. To accommodate the remaining gases, the catalyst inlet temperature must be lowered to maintain combustor durability. These results support commercial acceptance of catalytic combustion systems for use in natural gas fired turbines in distributed power generation with ultra low NO{sub x} emissions.

Ginter, David; Simchick, Chuck; Schlatter, Jim

2002-03-01T23:59:59.000Z

243

Air bottoming cycle: Use of gas turbine waste heat for power generation  

SciTech Connect (OSTI)

This paper presents a thermodynamic analysis of the Air Bottoming Cycle (ABC) as well as the results of a feasibility study for using the Air Bottoming Cycle for gas turbine waste heat recovery/power generation on oil/gas platforms in the North Sea. The basis for the feasibility study was to utilize the exhaust gas heat from an LM2500PE gas turbine. Installation of the ABC on both a new and an existing platform have been considered. A design reference case is presented, and the recommended ABC is a two-shaft engine with two compressor intercoolers. The compression pressure ratio was found optimal at 8:1. The combined gas turbine and ABC shaft efficiency wa/s calculated to 46.6 percent. The LM2500PE gas turbine contributes with 36.1 percent while the ABC adds 10.5 percent points to the gas turbine efficiency. The ABC shaft power output is 6.6 MW when utilizing the waste heat of an LM2500PE gas turbine. A preliminary thermal and hydraulic design of the ABC main components (compressor, turbine, intercoolers, and recuperator) was carried out. The recuperator is the largest and heaviest component (45 tons). A weight and cost breakdown of the ABC is presented. The total weight of the ABC package was calculated to 154 metric tons, and the ABC package cost to 9.4 million US$. An economical examination for three different cases was carried out. The results show that the ABC alternative (LM2500PE + ABC) is economical, with a rather good margin, compared to the other alternatives. The conclusion is that the Air Bottoming Cycle is an economical alternative for power generation on both new platforms and on existing platforms with demand for more power.

Bolland, O.; Foerde, M. [Norwegian Univ. of Science and Technology, Trondheim (Norway). Div. of Thermal Energy and Hydropower; Haande, B. [Oil Engineering Consultants, Sandvika (Norway)

1996-04-01T23:59:59.000Z

244

Coal combustion system  

DOE Patents [OSTI]

In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

1988-01-01T23:59:59.000Z

245

Coal combustion by-products: State regulatory overview  

SciTech Connect (OSTI)

Coal combustion by-products (CCBs) are generated from the combustion of coal for energy production. Approximately 82 million tons of CCBs are produced each year by electric utilities. (1991 Coal Combustion By-Product Production and Use, American Coal Ash Association, 1992.) There are several common types of CCBs produced by coal combustion--fly ash, bottom ash, boiler slag, flue gas desulfurization material (FGD) and fluidized bed combustion byproducts (FBC). Some CCBs, such as fly ash, have pozzolanic properties and may have cementitious properties, both of which are advantageous for engineering, construction and waste remediation applications. The American Society for Testing Materials (ASTM) in ASTM C-618 has created two classifications of useful and quality coal ash, Class F ash and Class C ash. Each class of coal ash has different pozzolanic and cementitious characteristics. Coal ash can be utilized in many manufacturing, mining, agricultural, engineering, construction and waste remediation applications. This is a review by state of regulations concerning coal combustion by-products.

Jagiella, D. [Howard and Howard Attorneys, Peoria, IL (United States)

1996-11-01T23:59:59.000Z

246

Experimental investigation of the thermal and diluent effects of EGR components on combustion and \\{NOx\\} emissions of a turbocharged natural gas SI engine  

Science Journals Connector (OSTI)

Abstract Exhaust gas recirculation (EGR) is one of effective measures used in natural gas (NG) engines to reduce nitrogen oxides (NOx) emissions. Each component of EGR gases can exert different effects on NG combustion and \\{NOx\\} formation rates, such as thermal effect, diluent effect, and chemical effect. In this study, the thermal and diluent effects of the main components of EGR gases, including carbon dioxide (CO2) and nitrogen (N2), were experimentally investigated. The experiments were arranged based on an electronically controlled heavy-duty natural gas spark-ignition (SI) engine with multi-point injection and 6-cylinder. In order to define the diluent effect of EGR components, argon (Ar) was introduced to the test, for its low and unchangeable specific heat capacity under different temperatures. The results showed that the contribution of the diluent effect on \\{NOx\\} reductions was 50–60% and 41–53% for N2 and CO2 respectively, and the relevant contribution of the thermal effect was 40–50% and 47–59% respectively. CO2 had greater effects on NG combustion and \\{NOx\\} formation rates than N2 at the same dilution ratio. Increasing Ar improved the thermal efficiency due to the higher specific heat ratio provided. Meanwhile, \\{NOx\\} emissions were found to be decreased with increasing DR as a result of the diluent effect of Ar on combustion and \\{NOx\\} formations.

Weifeng Li; Zhongchang Liu; Zhongshu Wang; Yun Xu

2014-01-01T23:59:59.000Z

247

Assessment of microbial processes on gas production at radioactive low-level waste disposal sites  

SciTech Connect (OSTI)

Factors controlling gaseous emanations from low level radioactive waste disposal sites are assessed. Importance of gaseous fluxes of methane, carbon dioxide, and possible hydrogen from the site, stems from the inclusion of tritium and/or carbon-14 into the elemental composition of these compounds. In that the primary source of these gases is the biodegradation of organic components of the waste material, primary emphasis of the study involved an examination of the biochemical pathways producing methane, carbon dioxide, and hydrogen, and the environmental parameters controlling the activity of the microbial community involved. Initial examination of the data indicates that the ecosystem is anaerobic. As the result of the complexity of the pathway leading to methane production, factors such as substrate availability, which limit the initial reaction in the sequence, greatly affect the overall rate of methane evolution. Biochemical transformations of methane, hydrogen and carbon dioxide as they pass through the soil profile above the trench are discussed. Results of gas studies performed at three commercial low level radioactive waste disposal sites are reviewed. Methods used to obtain trench and soil gas samples are discussed. Estimates of rates of gas production and amounts released into the atmosphere (by the GASFLOW model) are evaluated. Tritium and carbon-14 gaseous compounds have been measured in these studies; tritiated methane is the major radionuclide species in all disposal trenches studied. The concentration of methane in a typical trench increases with the age of the trench, whereas the concentration of carbon dioxide is similar in all trenches.

Weiss, A.J.; Tate, R.L. III; Colombo, P.

1982-05-01T23:59:59.000Z

248

Polycyclic Aromatic Hydrocarbon Emissions from the Combustion of Alternative Fuels in a Gas Turbine Engine  

Science Journals Connector (OSTI)

? Centre of Excellence for Aerospace Particulate Emissions Reduction Research, Missouri University of Science and Technology, Rolla, Missouri 65409, United States ... Within the aviation sector, the development and certification of alternative drop-in fuels are progressing at a rapid pace: a standard specification for aviation fuel containing synthesized hydrocarbons was approved by ASTM in 2009,(4) Hydrogenated esters and fatty acids (HEFA), also often referred to as hydrotreated renewable jet (HRJ), qualified as a 50/50 blend with petroleum Jet A-1 in 2011,(4) and the Commercial Aviation Alternative Fuels Initiative (CAAFI) anticipate fully synthetic Fischer–Tropsch (FT) fuel to qualify in 2012. ... Impact of Alternative Fuels on Emissions Characteristics of a Gas Turbine Engine – Part 1: Gaseous and Particulate Matter Emissions ...

Simon Christie; David Raper; David S. Lee; Paul I. Williams; Lucas Rye; Simon Blakey; Chris W. Wilson; Prem Lobo; Donald Hagen; Philip D. Whitefield

2012-04-25T23:59:59.000Z

249

Laboratory Scoping Tests Of Decontamination Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant  

SciTech Connect (OSTI)

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task seeks to examine the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are also expected to be in appreciable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, and {sup 241}Am. This report discusses results of preliminary radionuclide decontamination testing of the simulant. Testing examined use of Monosodium Titanate (MST) to remove {sup 90}Sr and actinides, inorganic reducing agents for {sup 99}Tc, and zeolites for {sup 137}Cs. Test results indicate that excellent removal of {sup 99}Tc was achieved using Sn(II)Cl{sub 2} as a reductant, coupled with sorption onto hydroxyapatite, even in the presence of air and at room temperature. This process was very effective at neutral pH, with a Decontamination Factor (DF) >577 in two hours. It was less effective at alkaline pH. Conversely, removal of the cesium was more effective at alka

Taylor-Pashow, Kathryn M.; Nash, Charles A.; Crawford, Charles L.; McCabe, Daniel J.; Wilmarth, William R.

2014-01-21T23:59:59.000Z

250

DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS  

SciTech Connect (OSTI)

In 1997, the United States Environmental Protection Agency (EPA) promulgated new National Ambient Air Quality Standards (NAAQS) for particulate matter, including for the first time particles with aerodynamic diameter smaller than 2.5 micrometers ({micro}m) referred to as PM2.5. PM2.5 in the atmosphere also contributes to reduced atmospheric visibility, which is the subject of existing rules for siting emission sources near Class 1 areas and new Regional Haze rules. There are few existing data regarding emissions and characteristics of fine aerosols from oil, gas and power generation industry combustion sources, and the information that is available is generally outdated and incomplete. Traditional stationary source air emission sampling methods tend to underestimate or overestimate the contribution of the source to ambient aerosols because they do not properly account for primary aerosol formation, which occurs after the gases leave the stack. Primary aerosol includes both filterable particles that are solid or liquid aerosols at stack temperature plus those that form as the stack gases cool through mixing and dilution processes in the plume downwind of the source. These deficiencies in the current methods can have significant impacts on regulatory decision-making. PM2.5 measurement issues were extensively reviewed by the American Petroleum Institute (API) (England et al., 1998), and it was concluded that dilution sampling techniques are more appropriate for obtaining a representative particulate matter sample from combustion systems for determining PM2.5 emission rate and chemical speciation. Dilution sampling is intended to collect aerosols including those that condense and/or react to form solid or liquid aerosols as the exhaust plume mixes and cools to near-ambient temperature immediately after the stack discharge. These techniques have been widely used in recent research studies. For example, Hildemann et al. (1994) and McDonald et al. (1998) used filtered ambient air to dilute the stack gas sample followed by 80-90 seconds residence time to allow aerosol formation and growth to stabilize prior to sample collection and analysis. More accurate and complete emissions data generated using the methods developed in this program will enable more accurate source-receptor and source apportionment analysis for PM2.5 National Ambient Air Quality Standards (NAAQS) implementation and streamline the environmental assessment of oil, gas and power production facilities. The overall goals of this program were to: (1) Develop improved dilution sampling technology and test methods for PM2.5 mass emissions and speciation measurements, and compare results obtained with dilution and traditional stationary source sampling methods. (2) Develop emission factors and speciation profiles for emissions of fine particulate matter, especially organic aerosols, for use in source-receptor and source apportionment analyses. (3) Identify and characterize PM2.5 precursor compound emissions that can be used in source-receptor and source apportionment analyses.

Glenn C. England

2004-10-20T23:59:59.000Z

251

Proceedings: EPRI Workshop on Condition and Remaining Life Assessment of Hot Gas Path Components of Combustion Turbines  

SciTech Connect (OSTI)

The severity of modern combustion turbine operation is a reflection of industry competition to achieve higher thermal efficiency. This competitive stance has resulted in new turbine designs and material systems that have at times outpaced condition and remaining life assessment (CARLA) technology. These proceedings summarize a two-day workshop on CARLA technology for hot section components of large combustion turbines.

None

2000-05-01T23:59:59.000Z

252

Coal Combustion Science  

SciTech Connect (OSTI)

The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

1991-08-01T23:59:59.000Z

253

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

254

Mechanisms of gas retention and release: Experimental results for Hanford waste tanks 241-AW-101 and 241-AN-103  

SciTech Connect (OSTI)

The 177 storage tanks at Hanford contain a vast array of radioactive waste forms resulting, primarily, from nuclear materials processing. Through radiolytic, thermal, and other decomposition reactions of waste components, gaseous species including hydrogen, ammonia, and the oxidizer nitrous oxide are generated within the waste tanks. Many of these tanks are known to retain and periodically release quantities of these flammable gas mixtures. The primary focus of the Flammable Gas Project is the safe storage of Hanford tank wastes. To this end, we strive to develop an understanding of the mechanisms of flammable gas retention and release in Hanford tanks through laboratory investigations on actual tank wastes. These results support the closure of the Flammable Gas Unreviewed Safety Question (USQ) on the safe storage of waste tanks known to retain flammable gases and support resolution of the broader Flammable Gas Safety Issue. The overall purpose of this ongoing study is to develop a comprehensive and thorough understanding of the mechanisms of flammable gas retention and release. The first objective of the current study was to classify bubble retention and release mechanisms in two previously untested waste materials from Tanks 241-AN-103 (AN-103) and 241-AW-101 (AW-101). Results were obtained for retention mechanisms, release characteristics, and the maximum gas retention. In addition, unique behavior was also documented and compared with previously studied waste samples. The second objective was to lengthen the duration of the experiments to evaluate the role of slowing bubble growth on the retention and release behavior. Results were obtained for experiments lasting from a few hours to a few days.

Rassat, S.D.; Gauglitz, P.A.; Bredt, P.R.; Mahoney, L.A.; Forbes, S.V.; Tingey, S.M.

1997-09-01T23:59:59.000Z

255

Development of Fuel-Flexible Combustion Systems Utilizing Opportunity...  

Office of Environmental Management (EM)

Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines - Fact Sheet, May 2014 Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in...

256

Oxy-combustion Boiler Material Development  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxy-combustion Boiler Material Oxy-combustion Boiler Material Development Background In an oxy-combustion system, combustion air (79 percent nitrogen, 21 percent oxygen) is replaced by oxygen and recycled flue gas (carbon dioxide [CO 2 ] and water), eliminating nitrogen in the flue gas stream. When applied to an existing boiler, the flue gas recirculation rate is adjusted to enable the boiler to maintain its original air-fired heat absorption performance, eliminating the need to derate the boiler

257

Vehicle Technologies Office: Waste Heat Recovery | Department...  

Broader source: Energy.gov (indexed) [DOE]

Batteries Fuel Efficiency & Emissions Combustion Engines Fuel Effects on Combustion Idle Reduction Emissions Waste Heat Recovery Lightweighting Parasitic Loss Reduction Lubricants...

258

Combustion Safety Overview  

Broader source: Energy.gov (indexed) [DOE]

March 1-2, 2012 March 1-2, 2012 Building America Stakeholders Meeting Austin, Texas Combustion Safety in the Codes Larry Brand Gas Technology Institute Acknowledgement to Paul Cabot - American Gas Association 2 | Building America Program www.buildingamerica.gov Combustion Safety in the Codes Widely adopted fuel gas codes: * National Fuel Gas Code - ANSI Z223.1/NFPA 54, published by AGA and NFPA (NFGC) * International Fuel Gas Code - published by the International Code Council (IFGC) * Uniform Plumbing Code published by IAPMO (UPC) Safety codes become requirements when adopted by the Authority Having Jurisdiction (governments or fire safety authorities) 3 | Building America Program www.buildingamerica.gov Combustion Safety in the Codes Formal Relationships Between these codes: - The IFGC extracts many safety

259

Microwave off-gas treatment apparatus and process  

DOE Patents [OSTI]

The invention discloses a microwave off-gas system in which microwave energy is used to treat gaseous waste. A treatment chamber is used to remediate off-gases from an emission source by passing the off-gases through a susceptor matrix, the matrix being exposed to microwave radiation. The microwave radiation and elevated temperatures within the combustion chamber provide for significant reductions in the qualitative and quantitative emissions of the gas waste stream.

Schulz, Rebecca L. (Aiken, SC); Clark, David E. (Gainesville, FL); Wicks, George G. (North Aiken, SC)

2003-01-01T23:59:59.000Z

260

Equipment design guidance document for flammable gas waste storage tank new equipment  

SciTech Connect (OSTI)

This document is intended to be used as guidance for design engineers who are involved in design of new equipment slated for use in Flammable Gas Waste Storage Tanks. The purpose of this document is to provide design guidance for all new equipment intended for application into those Hanford storage tanks in which flammable gas controls are required to be addressed as part of the equipment design. These design criteria are to be used as guidance. The design of each specific piece of new equipment shall be required, as a minimum to be reviewed by qualified Unreviewed Safety Question evaluators as an integral part of the final design approval. Further Safety Assessment may be also needed. This guidance is intended to be used in conjunction with the Operating Specifications Documents (OSDs) established for defining work controls in the waste storage tanks. The criteria set forth should be reviewed for applicability if the equipment will be required to operate in locations containing unacceptable concentrations of flammable gas.

Smet, D.B.

1996-04-11T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Proceedings of the ASME Heat Transfer Division. Volume 4: Natural convection within a horizontal circular cylinder heated from below and cooled from above; Numerical methods for coupled fluid-thermal-structural interaction; Thermal analysis in waste processing and disposal; Heat transfer in fire and combustion systems; HTD-Volume 335  

SciTech Connect (OSTI)

The first two sections as listed in the title contain 7 papers. The third section on thermal analysis contains 18 papers arranged into the following topical areas: Thermal treatment and municipal wastes; Thermal hydraulics in hazardous and nuclear waste processing and disposal; and Waste processing. Heat transfer in fire and combustion systems contains 17 papers arranged into the following topical sections: Soot/radiation; Combustion systems; Multiphase combustion; and Flames and fires. Most papers have been processed separately for inclusion on the data base.

Pepper, D.W. [ed.] [Univ. of Nevada, Las Vegas, NV (United States); Douglass, R.W. [ed.] [Idaho National Engineering Lab., Idaho Falls, ID (United States); Heinrich, J.C. [ed.] [Univ. of Arizona, Tucson, AZ (United States)] [and others

1996-12-31T23:59:59.000Z

262

Composition, preparation, and gas generation results from simulated wastes of Tank 241-SY-101  

SciTech Connect (OSTI)

This document reviews the preparation and composition of simulants that have been developed to mimic the wastes temporarily stored in Tank 241-SY-101 at Hanford. The kinetics and stoichiometry of gases that are generated using these simulants are also compared, considering the roles of hydroxide, chloride, and transition metal ions; the identities of organic constituents; and the effects of dilution, radiation, and temperature. Work described in this report was conducted for the Flammable Gas Safety Program at Pacific Northwest Laboratory, (a) whose purpose is to develop information that is necessary to mitigate potential safety hazards associated with waste tanks at the Hanford Site. The goal of this research and of related efforts at the Georgia Institute of Technology (GIT), Argonne National Laboratory (ANL), and Westinghouse Hanford Company (WHC) is to determine the thermal and thermal/radiolytic mechanisms by which flammable and other gases are produced in Hanford wastes, emphasizing those stored in Tank 241-SY-101. A variety of Tank 241-SY-101 simulants have been developed to date. The use of simulants in laboratory testing activities provides a number of advantages, including elimination of radiological risks to researchers, lower costs associated with experimentation, and the ability to systematically alter simulant compositions to study the chemical mechanisms of reactions responsible for gas generation. The earliest simulants contained the principal inorganic components of the actual waste and generally a single complexant such as N-(2-hydroxyethyl) ethylenediaminetriacetic acid (HEDTA) or ethylenediaminetriacetic acid (EDTA). Both homogeneous and heterogeneous compositional forms were developed. Aggressive core sampling and analysis activities conducted during Windows C and E provided information that was used to design new simulants that more accurately reflected major and minor inorganic components.

Bryan, S.A.; Pederson, L.R.

1994-08-01T23:59:59.000Z

263

Life cycle greenhouse gas impacts of ethanol, biomethane and limonene production from citrus waste  

Science Journals Connector (OSTI)

The production of biofuel from cellulosic residues can have both environmental and financial benefits. A particular benefit is that it can alleviate competition for land conventionally used for food and feed production. In this research, we investigate greenhouse gas (GHG) emissions associated with the production of ethanol, biomethane, limonene and digestate from citrus waste, a byproduct of the citrus processing industry. The study represents the first life cycle-based evaluations of citrus waste biorefineries. Two biorefinery configurations are studied—a large biorefinery that converts citrus waste into ethanol, biomethane, limonene and digestate, and a small biorefinery that converts citrus waste into biomethane, limonene and digestate. Ethanol is assumed to be used as E85, displacing gasoline as a light-duty vehicle fuel; biomethane displaces natural gas for electricity generation, limonene displaces acetone in solvents, and digestate from the anaerobic digestion process displaces synthetic fertilizer. System expansion and two allocation methods (energy, market value) are considered to determine emissions of co-products. Considerable GHG reductions would be achieved by producing and utilizing the citrus waste-based products in place of the petroleum-based or other non-renewable products. For the large biorefinery, ethanol used as E85 in light-duty vehicles results in a 134% reduction in GHG emissions compared to gasoline-fueled vehicles when applying a system expansion approach. For the small biorefinery, when electricity is generated from biomethane rather than natural gas, GHG emissions are reduced by 77% when applying system expansion. The life cycle GHG emissions vary substantially depending upon biomethane leakage rate, feedstock GHG emissions and the method to determine emissions assigned to co-products. Among the process design parameters, the biomethane leakage rate is critical, and the ethanol produced in the large biorefinery would not meet EISA's requirements for cellulosic biofuel if the leakage rate is higher than 9.7%. For the small biorefinery, there are no GHG emission benefits in the production of biomethane if the leakage rate is higher than 11.5%. Compared to system expansion, the use of energy and market value allocation methods generally results in higher estimates of GHG emissions for the primary biorefinery products (i.e., smaller reductions in emissions compared to reference systems).

Mohammad Pourbafrani; Jon McKechnie; Heather L MacLean; Bradley A Saville

2013-01-01T23:59:59.000Z

264

Cold End Inserts for Process Gas Waste Heat Boilers Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB)  

E-Print Network [OSTI]

Cold End Inserts for Process Gas Waste Heat Boilers Overview Air Products, operates hydrogen walls. Air Products tasked our team to design an insert to place in the tubes of the WHB to increase flow velocity, thereby reducing fouling of the WHB. Objectives Air Products wishes that our team

Demirel, Melik C.

265

Development of hot corrosion resistant coatings for gas turbines burning biomass and waste derived fuel gases  

Science Journals Connector (OSTI)

Carbon dioxide emission reductions are being sought worldwide to mitigate climate change. These need to proceed in parallel with optimisation of thermal efficiency in energy conversion systems on economic grounds to achieve overall sustainability. The use of renewable energy is one strategy being adopted to achieve these needs; with one route being the burning of biomass and waste derived fuels in the gas turbines of highly efficient, integrated gasification combined cycle (IGCC) electricity generating units. A major factor to be taken into account with gas turbines using such fuels, compared with natural gas, is the potentially higher rates of hot corrosion caused by molten trace species which can be deposited on hot gas path components. This paper describes the development of hot corrosion protective coatings for such applications. Diffusion coatings were the basis for coating development, which consisted of chemical vapour deposition (CVD) trials, using aluminising and single step silicon-aluminising processes to develop new coating structures on two nickel-based superalloys, one conventionally cast and one single crystal (IN738LC and CMSX-4). These coatings were characterised using SEM/EDX analysis and their performance evaluated in oxidation and hot corrosion screening tests. A variant of the single step silicon-aluminide coating was identified as having sufficient oxidation/hot corrosion resistance and microstructural stability to form the basis for future coating optimisation.

A. Bradshaw; N.J. Simms; J.R. Nicholls

2013-01-01T23:59:59.000Z

266

Combination gas-producing and waste-water disposal well. [DOE patent application  

DOE Patents [OSTI]

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Malinchak, R.M.

1981-09-03T23:59:59.000Z

267

Fluidized-Bed Waste-Heat Recovery System development. Semiannual report, February 1-July 31, 1982  

SciTech Connect (OSTI)

The Fluidized-Bed Waste-Heat Recovery (FBWHR) System is designed to preheat this combustion air using the heat available in dirty flue gas streams. In this system, a recirculating medium is heated by the flue gas in a fluidized bed. The hot medium is then removed from the bed and placed in a second fluidized bed where it is fluidized by the combustion air. Through this process, the combustion air is heated. The cooled medium is then returned to the first bed. Initial development of this concept is for the aluminum smelting industry.

Cole, W. E.; DeSaro, R.; Griffith, J.; Joshi, C.

1982-08-01T23:59:59.000Z

268

Two phase partially miscible flow and transport modeling in porous media: application to gas migration in a nuclear waste repository  

E-Print Network [OSTI]

We derive a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological repository for radioactive waste. This model includes capillary effects and the gas high diffusivity. Moreover, it is written in variables (total hydrogen mass density and liquid pressure) chosen in order to be consistent with gas appearance or disappearance. We discuss the well possedness of this model and give some computational evidences of its adequacy to simulate gas generation in a water saturated repository.

Alain Bourgeat; Mladen Jurak; Farid Smaï

2008-02-29T23:59:59.000Z

269

Two phase partially miscible flow and transport modeling in porous media: application to gas migration in a nuclear waste repository  

E-Print Network [OSTI]

We derive a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological repository for radioactive waste. This model includes capillary effects and the gas high diffusivity. Moreover, it is written in variables (total hydrogen mass density and liquid pressure) chosen in order to be consistent with gas appearance or disappearance. We discuss the well possedness of this model and give some computational evidences of its adequacy to simulate gas generation in a water saturated repository.

Bourgeat, Alain; Smaï, Farid

2008-01-01T23:59:59.000Z

270

Use of Combusted Natural Gas to Cultivate the Anaerobic Bacterial Flora from the Cecum Contents of Mice  

Science Journals Connector (OSTI)

...of an inert gas generator, the gas-to-air...of the inert gas generator. A small compressor...pressure of 250 mm water gauge (WG). By...of changes in the atmospheric pressure. With...temperature ofthe cooling water in the cooling jacket...of the inert gas generator. Parts: 1, stopcock...

J. P. Koopman; J. P. Van Oeveren; F. G. J. Janssen

1973-10-01T23:59:59.000Z

271

METC ceramic corrosion/erosion studies: turbine-material screening tests in high-temperature, low-Btu, coal-derived-gas combustion products  

SciTech Connect (OSTI)

The Morgantown Energy Technology Center, through its Ceramics Corrosion/Erosion Studies, has participated in the United States Department of Energy's High-Temperature Turbine Technology Program, Ceramic Technology Readiness. The program's overall objective is to advance the turbine firing temperature to a range of 2600/sup 0/ to 3000/sup 0/F (1700 to 1922K) with a reasonable service life using coal or coal-derived fuel. The Ceramics Corrosion/Erosion Studies' major objective was to conduct a screening test for several ceramic materials to assess their probability of survival in turbine applications. The materials were exposed to combustion products from low heating value coal-derived gas and air at several high temperatures and velocities. The combustion product composition and temperatures simulated actual environment that may be found in stationary power generating gas turbines except for the pressure levels. The results of approximately 1000 hours of accumulative exposure time of material at the specific test conditions are presented in this report.

Nakaishi, C.V.; Waltermire, D.M.; Hawkins, L.W.; Jarrett, T.L.

1982-05-01T23:59:59.000Z

272

In-cylinder investigations and analysis of a SI gas engine fuelled with H2 and CO rich syngas fuel: Sensitivity analysis of combustion descriptors for engine diagnostics and control  

Science Journals Connector (OSTI)

Abstract The sensitivity of combustion phasing and combustion descriptors to ignition timing, load and mixture quality on fuelling a multi-cylinder natural gas engine with bio-derived H2 and CO rich syngas is addressed. While the descriptors for conventional fuels are well established and are in use for closed loop engine control, presence of H2 in syngas potentially alters the mixture properties and hence combustion phasing, necessitating the current study. The ability of the descriptors to predict abnormal combustion, hitherto missing in the literature, is also addressed. Results from experiments using multi-cylinder engines and numerical studies using zero dimensional Wiebe function based simulation models are reported. For syngas with 20% H2 and CO and 2% CH4 (producer gas), an ignition retard of 5 ± 1 degrees was required compared to natural gas ignition timing to achieve peak load of 72.8 kWe. It is found that, for syngas, whose flammability limits are 0.42–1.93, the optimal engine operation was at an equivalence ratio of 1.12. The same methodology is extended to a two cylinder engine towards addressing the influence of syngas composition, especially H2 fraction (varying from 13% to 37%), on the combustion phasing. The study confirms the utility of pressure trace derived combustion descriptors, except for the pressure trace first derivative, in describing the MBT operating condition of the engine when fuelled with an alternative fuel. Both experiments and analysis suggest most of the combustion descriptors to be independent of the engine load and mixture quality. A near linear relationship with ignition angle is observed. The general trend(s) of the combustion descriptors for syngas fuelled operation are similar to those of conventional fuels; the differences in sensitivity of the descriptors for syngas fuelled engine operation requires re-calibration of control logic for MBT conditions.

Anand M. Shivapuji; S. Dasappa

2014-01-01T23:59:59.000Z

273

Chapter 8 - Natural Gas  

Science Journals Connector (OSTI)

Although natural gas is a nonrenewable resource, it is included for discussion because its sudden growth from fracking will impact the development and use of renewable fuels. Firms who are engaged in the development of processes that employ synthesis gas as an intermediate have concluded that the synthesis gas is more economically obtainable by steam reforming of natural gas than by gasification of waste cellulose. In some instances, firms have largely abandoned the effort to produce a renewable fuel as such, and in others firms are developing hybrid processes that employ natural gas in combination with a fermentation system. Moreover, natural gas itself is an attractive fuel for internal combustion engines since it can be the least expensive option on a cost per joule basis. It is also aided by its high octane number of 130.

Arthur M. Brownstein

2015-01-01T23:59:59.000Z

274

Characteristics of biomass in flameless combustion: A review  

Science Journals Connector (OSTI)

Abstract The demands of energy and pollutant emissions reduction have motivated the combustion researchers to work on combustion improvement. Flameless combustion or high temperature air combustion has many features such as flame stability, low pollutant emission and uniform profiles of temperature compared to the other modes of combustion. Combustion of solid fuels likes biomass and wastes in flameless combustion conditions has not been investigated as comprehensive as combustion of gaseous fuels. The aim of using biomass in combustion is to reduce the pollutant emissions and to decrease the rate of fossil fuel consumption. In this review, combustion characteristics of biomass in flameless combustion are explained. The paper summarizes the research on the mass loss, ignition time, and \\{NOx\\} emissions during biomass flameless combustion. These summaries show that biomass under flameless combustion gives low pollutant emissions, low mass loss and it decreases the ignition time.

A.A.A. Abuelnuor; M.A. Wahid; Seyed Ehsan Hosseini; A. Saat; Khalid M. Saqr; Hani H. Sait; M. Osman

2014-01-01T23:59:59.000Z

275

Coupled multiphase flow and closure analysis of repository response to waste-generated gas at the Waste Isolation Pilot Plant (WIPP)  

SciTech Connect (OSTI)

A long-term assessment of the Waste Isolation Pilot Plant (WIPP) repository performance must consider the impact of gas generation resulting from the corrosion and microbial degradation of the emplaced waste. A multiphase fluid flow code, TOUGH2/EOS8, was adapted to model the processes of gas generation, disposal room creep closure, and multiphase (brine and gas) fluid flow, as well as the coupling between the three processes. System response to gas generation was simulated with a single, isolated disposal room surrounded by homogeneous halite containing two anhydrite interbeds, one above and one below the room. The interbeds were assumed to have flow connections to the room through high-permeability, excavation-induced fractures. System behavior was evaluated by tracking four performance measures: (1) peak room pressure; (2) maximum brine volume in the room; (3) total mass of gas expelled from the room; and (4) the maximum gas migration distance in an interbed. Baseline simulations used current best estimates of system parameters, selected through an evaluation of available data, to predict system response to gas generation under best-estimate conditions. Sensitivity simulations quantified the effects of parameter uncertainty by evaluating the change in the performance measures in response to parameter variations. In the sensitivity simulations, a single parameter value was varied to its minimum and maximum values, representative of the extreme expected values, with all other parameters held at best-estimate values. Sensitivity simulations identified the following parameters as important to gas expulsion and migration away from a disposal room: interbed porosity; interbed permeability; gas-generation potential; halite permeability; and interbed threshold pressure. Simulations also showed that the inclusion of interbed fracturing and a disturbed rock zone had a significant impact on system performance.

Freeze, G.A.; Larson, K.W. [INTERA Inc., Austin, TX (United States); Davies, P.B. [Sandia National Laboratories, Albuquerque, NM (United States)

1995-10-01T23:59:59.000Z

276

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE [SEC 1 & 2  

SciTech Connect (OSTI)

Flammable gases such as hydrogen, ammonia, and methane are observed in the tank dome space of the Hanford Site high-level waste tanks. This report assesses the steady-state flammability level under normal and off-normal ventilation conditions in the tank dome space for 177 double-shell tanks and single-shell tanks at the Hanford Site. The steady-state flammability level was estimated from the gas concentration of the mixture in the dome space using estimated gas release rates, Le Chatelier's rule and lower flammability limits of fuels in an air mixture. A time-dependent equation of gas concentration, which is a function of the gas release and ventilation rates in the dome space, has been developed for both soluble and insoluble gases. With this dynamic model, the time required to reach the specified flammability level at a given ventilation condition can be calculated. In the evaluation, hydrogen generation rates can be calculated for a given tank waste composition and its physical condition (e.g., waste density, waste volume, temperature, etc.) using the empirical rate equation model provided in Empirical Rate Equation Model and Rate Calculations of Hydrogen Generation for Hanford Tank Waste, HNF-3851. The release rate of other insoluble gases and the mass transport properties of the soluble gas can be derived from the observed steady-state gas concentration under normal ventilation conditions. The off-normal ventilation rate is assumed to be natural barometric breathing only. A large body of data is required to do both the hydrogen generation rate calculation and the flammability level evaluation. For tank waste that does not have sample-based data, a statistical-based value from probability distribution regression was used based on data from tanks belonging to a similar waste group. This report (Revision 3) updates the input data of hydrogen generation rates calculation for 177 tanks using the waste composition information in the Best-Basis Inventory Detail Report in the Tank Waste Information Network System, and the waste temperature data in the Surveillance Analysis Computer System (SACS) (dated July 2003). However, the release rate of methane, ammonia, and nitrous oxide is based on the input data (dated October 1999) as stated in Revision 0 of this report. Scenarios for adding waste to existing waste levels (dated July 2003) have been studied to determine the gas generation rates and the effect of smaller dome space on the flammability limits to address the issues of routine water additions and other possible waste transfer operations. In the flammability evaluation with zero ventilation, the sensitivity to waste temperature and to water addition was calculated for double-shell tanks 241-AY-102, 241-AN-102,241-AZ-101,241-AN-107,241-AY-101 and 241-AZ-101. These six have the least margin to flammable conditions among 28 double-shell tanks.

HU, T.A.

2003-09-30T23:59:59.000Z

277

Alternative fuels for industrial gas turbines (AFTUR)  

Science Journals Connector (OSTI)

Environmentally friendly, gas turbine driven co-generation plants can be located close to energy consumption sites, which can produce their own fuel such as waste process gas or biomass derived fuels. Since gas turbines are available in a large power range, they are well suited for this application. Current gas turbine systems that are capable of burning such fuels are normally developed for a single specific fuel (such as natural gas or domestic fuel oil) and use conventional diffusion flame technology with relatively high levels of \\{NOx\\} and partially unburned species emissions. Recently, great progress has been made in the clean combustion of natural gas and other fossil fuels through the use of dry low emission technologies based on lean premixed combustion, particularly with respect of \\{NOx\\} emissions. The objective of the AFTUR project is to extend this capability to a wider range of potentially commercial fuel types, including those of lower calorific value produced by gasification of biomass (LHV gas in line with the European Union targets) and hydrogen enriched fuels. The paper reports preliminary progress in the selection and characterisation of potential, liquid and gas, alternative fuels for industrial gas turbines. The combustion and emission characteristics of the selected fuels will be assessed, in the later phases of the project, both in laboratory and industrial combustion chambers.

Iskender Gökalp; Etienne Lebas

2004-01-01T23:59:59.000Z

278

A new type of self-organization in combustion  

Science Journals Connector (OSTI)

... a solid-phase gasless combustion3 which proceeds with the formation of a melt or a flameless gas3'4. ... gas3'4. Flameless combustion has recently been described for several tetrazole compounds5.

A. I. Lesnikovich; V. V. Sviridov; G. V. Printsev; O. A. Ivashkevich; P. N. Gaponik

1986-10-23T23:59:59.000Z

279

MILD combustion for hydrogen and syngas at elevated pressures  

Science Journals Connector (OSTI)

As gas recirculation constitutes a fundamental condition for the realization of MILD combustion, it is necessary to determine gas recirculation ratio before designing MILD combustor. MILD combustion model with ga...

Mingming Huang; Zhedian Zhang; Weiwei Shao; Yan Xiong…

2014-02-01T23:59:59.000Z

280

Evaluation of Gas Retention in Waste Simulants: Intermediate-Scale Column and Open-Channel-Depth Tests  

SciTech Connect (OSTI)

Gas generation in Hanford’s radioactive waste storage tanks can lead to gas accumulation within the layer of settled solids (sludge) at the tank bottom. The gas, which may be hazardous and/or flammable, is formed principally by radiation-driven chemical reactions. Accumulation of these gases within the sludge increases the sludge-layer volume, which decreases the available tank volume for waste storage. Further, accumulation of large amounts of gas in the sludge can potentially result in a relatively rapid release of the accumulated gas if the sludge-layer density is reduced to less than that of the overlying sludge or that of the supernatant liquid. The potential for rapid release of large amounts of hazardous and/or flammable gases is a safety hazard that needs to be managed. Accordingly, a thorough understanding is needed of the circumstances that can lead to problematic gas accumulation in sludge layers. The Deep-Sludge Gas Release Event Project (DSGREP) is tasked with developing an improved understanding of these gas release events.

Powell, Michael R.; Gauglitz, Phillip A.; Denslow, Kayte M.; Fischer, Christopher M.; Heldebrant, David J.; Prowant, Matthew S.; Sande, Susan; Davis, James M.; Telander, Monty R.

2014-02-14T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Numerical and Experimental Analysis of Combustion and Exhaust Emissions in a Dual-Fuel Diesel/Natural Gas Engine  

Science Journals Connector (OSTI)

Department of Mechanical Engineering, UTV, University of Rome Tor Vergata, Rome, Italy, and IM-CNR, Istituto Motori of Italian National Research Council, Naples, Italy ... Accordingly, the use of NG as primary fuel allows the same compression ratio of the conventional diesel engine; thus, existing diesel engines can be easily converted to dual-fuel operation. ... Thus, a more general combustion model (G-equation or EDC) could be considered to represent flame propagation. ...

Stefano Cordiner; Michele Gambino; Sabato Iannaccone; Vittorio Rocco; Riccardo Scarcelli

2008-02-21T23:59:59.000Z

282

Mechanisms of gas retention and release: Experimental results for Hanford single-shell waste tanks 241-A-101, 241-S-106, and 241-U-103  

SciTech Connect (OSTI)

The 177 underground waste storage tanks at the Hanford Site contain millions of gallons of radioactive waste resulting from the purification of nuclear materials and related processes. Through various mechanisms, flammable gas mixtures of hydrogen, ammonia, methane, and nitrous oxide are generated and retained in significant quantities within the waste in many ({approximately}25) of these tanks. The potential for large releases of retained gas from these wastes creates a flammability hazard. It is a critical component of the effort to understand the flammability hazard and a primary goal of this laboratory investigation to establish an understanding of the mechanisms of gas retention and release in these wastes. The results of bubble retention experimental studies using waste samples from several waste tanks and a variety of waste types support resolution of the Flammable Gas Safety Issue. Gas bubble retention information gained in the pursuit of safe storage will, in turn, benefit future waste operations including salt-well pumping, waste transfers, and sluicing/retrieval.

Rassat, S.D.; Caley, S.M.; Bredt, P.R.; Gauglitz, P.A.; Rinehart, D.E.; Forbes, S.V.

1998-09-01T23:59:59.000Z

283

Co-management of coal combustion by-products and low-volume wastes: A Southeastern Site  

SciTech Connect (OSTI)

The Electric Power Research Institute initiated this study to provide environmental data on the co-management of utility high volume and low volume residues. This report presents results from a field investigation at an ash pond located at a 400 MW, coal-fired power plant in the southeastern US. The pond receives wet-sluiced fly ash and bottom ash from the generating station as well as low volume wastes from coal preparation, demineralizer regeneration, and boiler cleaning. A detailed hydrogeochemical characterization of the primary ash disposal pond and surrounding groundwater system was performed. A total of 25 monitoring wells were installed to characterize groundwater flow directions, rates and chemistry. Ash and soil cores were also collected for hydrogeochemical characterization.

Holcombe, L.J.; Thompson, C.M.; Rehage, J.A. (Radian Corp., Austin, TX (United States)); Erickson, J.R. (GeoTrans, Inc., Sterling, VA (United States)); Fruchter, J.S. (Battelle Pacific Northwest Lab., Richland, WA (United States))

1991-11-01T23:59:59.000Z

284

Fluidized-Bed Waste-Heat Recovery System development. Semiannual report, 1 August 1982-31 January 1983  

SciTech Connect (OSTI)

The Fluidized-Bed Waste-Heat Recovery (FBWHR) System is designed to preheat this combustion air using the heat available in dirty flue gas streams. In this system, a recirculating medium is heated by the flue gas in a fluidized bed. The hot medium is then removed from the bed and placed in a second fluidized bed where it is fluidized by the combustion air. Through this process, the combustion air is heated. The cooled medium is then returned to the first bed. Initial development of this concept is for the aluminum smelting industry.

Cole, W.E.; DeSaro, R.; Joshi, C.

1983-02-01T23:59:59.000Z

285

Fluidized-Bed Waste-Heat Recovery System development. Semiannual report, 1 August 1981-31 January 1982  

SciTech Connect (OSTI)

The Fluidized-Bed Waste-Heat Recovery (FBWHR) System is designed to preheat this combustion air using the heat available in dirty flue gas streams. In this system, a recirculating medium is heated by the flue gas in a fluidized bed. The hot medium is then removed from the bed and placed in a second fluidized bed where it is fluidized by the combustion air. Through this process, the combustion air is heated. The cooled medium is then returned to the first bed. Initial development of this concept is for the aluminum smelting industry.

Cole, W. E.; DeSaro, R.; Joshi, C.

1982-02-01T23:59:59.000Z

286

Scalable, Efficient Solid Waste Burner System - Energy Innovation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

combustion experts at CSU, the device is superior to other systems and achieves improved gasification and combustion of biomass and waste through novel chassis design and process....

287

Life cycle greenhouse gas (GHG) impacts of a novel process for converting food waste to ethanol and co-products  

Science Journals Connector (OSTI)

Abstract Waste-to-ethanol conversion is a promising technology to provide renewable transportation fuel while mitigating feedstock risks and land use conflicts. It also has the potential to reduce environmental impacts from waste management such as greenhouse gas (GHG) emissions that contribute to climate change. This paper analyzes the life cycle GHG emissions associated with a novel process for the conversion of food processing waste into ethanol (EtOH) and the co-products of compost and animal feed. Data are based on a pilot plant co-fermenting retail food waste with a sugary industrial wastewater, using a simultaneous saccharification and fermentation (SSF) process at room temperature with a grinding pretreatment. The process produced 295 L EtOH/dry t feedstock. Lifecycle GHG emissions associated with the ethanol production process were 1458 gCO2e/L EtOH. When the impact of avoided landfill emissions from diverting food waste to use as feedstock are considered, the process results in net negative GHG emissions and approximately 500% improvement relative to corn ethanol or gasoline production. This finding illustrates how feedstock and alternative waste disposal options have important implications in life cycle GHG results for waste-to-energy pathways.

Jacqueline Ebner; Callie Babbitt; Martin Winer; Brian Hilton; Anahita Williamson

2014-01-01T23:59:59.000Z

288

Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification  

SciTech Connect (OSTI)

In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. We employed the thermogravimetry-gas chromatography-mass spectrometry (TGA-GC-MS) combination to perform evolved gas analysis (EGA). Apart from identifying the gases evolved, we performed quantitative analysis relating the weighed sum of intensities of individual gases linearly proportional with the differential themogravimetry. The proportionality coefficients were obtained by three methods based on the stoichiometry, least squares, and calibration. The linearity was shown to be a good first-order approximation, in spite of the complicated overlapping reactions.

Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.; Rodriguez, Carmen P.; Schweiger, Michael J.

2014-04-30T23:59:59.000Z

289

Microbial gas generation under expected Waste Isolation Pilot Plant repository conditions  

SciTech Connect (OSTI)

Gas generation from the microbial degradation of the organic constituents of transuranic waste under conditions expected at the Waste Isolation Pilot Plant (WIPP) repository was investigated at Brookhaven National Laboratory. The biodegradation of mixed cellulosics (various types of paper) and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, neoprene, hypalon, and leaded hypalon) was examined. The rate of gas production from cellulose biodegradation in inundated samples incubated for 1,228 days at 30 C was biphasic, with an initial rapid rate up to approximately 600 days incubation, followed by a slower rate. The rate of total gas production in anaerobic samples containing mixed inoculum was as follows: 0.002 mL/g cellulose/day without nutrients; 0.004 mL/g cellulose/day with nutrients; and 0.01 mL/g cellulose/day in the presence of excess nitrate. Carbon dioxide production proceeded at a rate of 0.009 {micro}mol/g cellulose/day in anaerobic samples without nutrients, 0.05 {micro}mol/g cellulose/day in the presence of nutrients, and 0.2 {micro}mol/g cellulose/day with excess nitrate. Adding nutrients and excess nitrate stimulated denitrification, as evidenced by the accumulation of N{sub 2}O in the headspace (200 {micro}mol/g cellulose). The addition of the potential backfill bentonite increased the rate of CO{sub 2} production to 0.3 {micro}mol/g cellulose/day in anaerobic samples with excess nitrate. Analysis of the solution showed that lactic, acetic, propionic, butyric, and valeric acids were produced due to cellulose degradation. Samples incubated under anaerobic humid conditions for 415 days produced CO{sub 2} at a rate of 0.2 {micro}mol/g cellulose/day in the absence of nutrients, and 1 {micro}mol/g cellulose/day in the presence of bentonite and nutrients. There was no evidence of biodegradation of electron-beam irradiated plastic and rubber.

Francis, A.J.; Gillow, J.B.; Giles, M.R. [Brookhaven National Lab., Upton, NY (United States). Dept. of Applied Science

1997-03-01T23:59:59.000Z

290

Polymer combustion: effects of flame emissivity  

Science Journals Connector (OSTI)

...gas phase. Polymer combustion chemistry is modelled...investigating polymer combustion it has proven advantageous...properties and treat the heat flux from the ignition...luminous flames from hydrocarbon fuels, it is common...A (1999) Polymer combustion: effects of flame emissivity...

1999-01-01T23:59:59.000Z

291

Staged Combustion of Pulverized Coal  

Science Journals Connector (OSTI)

The emissions of nitrogen oxides are much higher with the combustion of fossil fuels containing organic bound nitrogen compounds than with clean fuels like natural gas and light distillate oil. During combusti...

H. Kremer; R. Mechenbier; W. Schulz

1987-01-01T23:59:59.000Z

292

Third millenium ideal gas and condensed phase thermochemical database for combustion (with update from active thermochemical tables).  

SciTech Connect (OSTI)

The thermochemical database of species involved in combustion processes is and has been available for free use for over 25 years. It was first published in print in 1984, approximately 8 years after it was first assembled, and contained 215 species at the time. This is the 7th printed edition and most likely will be the last one in print in the present format, which involves substantial manual labor. The database currently contains more than 1300 species, specifically organic molecules and radicals, but also inorganic species connected to combustion and air pollution. Since 1991 this database is freely available on the internet, at the Technion-IIT ftp server, and it is continuously expanded and corrected. The database is mirrored daily at an official mirror site, and at random at about a dozen unofficial mirror and 'finger' sites. The present edition contains numerous corrections and many recalculations of data of provisory type by the G3//B3LYP method, a high-accuracy composite ab initio calculation. About 300 species are newly calculated and are not yet published elsewhere. In anticipation of the full coupling, which is under development, the database started incorporating the available (as yet unpublished) values from Active Thermochemical Tables. The electronic version now also contains an XML file of the main database to allow transfer to other formats and ease finding specific information of interest. The database is used by scientists, educators, engineers and students at all levels, dealing primarily with combustion and air pollution, jet engines, rocket propulsion, fireworks, but also by researchers involved in upper atmosphere kinetics, astrophysics, abrasion metallurgy, etc. This introductory article contains explanations of the database and the means to use it, its sources, ways of calculation, and assessments of the accuracy of data.

Burcat, A.; Ruscic, B.; Chemistry; Technion - Israel Inst. of Tech.

2005-07-29T23:59:59.000Z

293

Steam Reactivation and Separation of Limestone Sorbents for High Temperature Post-combustion CO2 Capture from Flue Gas.  

E-Print Network [OSTI]

?? Increasing global population and demand for energy has raised concerns of excessive anthropogenic greenhouse gas emissions from consumption of fossil fuels. Coal, in particular,… (more)

Wang, Alan Yao

2012-01-01T23:59:59.000Z

294

Performance and emission characteristics of natural gas combined cycle power generation system with steam injection and oxyfuel combustion.  

E-Print Network [OSTI]

??Natural gas combined cycle power generation systems are gaining popularity due to their high power generation efficiency and reduced emission. In the present work, combined… (more)

Varia, Nitin

2014-01-01T23:59:59.000Z

295

The effect of stratigraphic dip on brine inflow and gas migration at the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

The natural dip of the Salado Formation at the Waste Isolation Pilot Plant (WIPP), although regionally only about 111, has the potential to affect brine inflow and gas-migration distances due to buoyancy forces. Current models, including those in WIPP Performance Assessment calculations, assume a perfectly horizontal repository and stratigraphy. With the addition of buoyancy forces due to the dip, brine and gas flow patterns can be affected. Brine inflow may increase due to countercurrent flow, and gas may preferentially migrate up dip. This scoping study has used analytical and numerical modeling to evaluate the impact of the dip on brine inflow and gas-migration distances at the WIPP in one, two, and three dimensions. Sensitivities to interbed permeabilities, two-phase curves, gas-generation rates, and interbed fracturing were studied.

Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); Larson, K.W. [INTERA, Inc., Albuquerque, NM (United States)] [INTERA, Inc., Albuquerque, NM (United States)

1996-02-01T23:59:59.000Z

296

Demonstration of an on-site PAFC cogeneration system with waste heat utilization by a new gas absorption chiller  

SciTech Connect (OSTI)

Analysis and cost reduction of fuel cells is being promoted to achieve commercial on-site phosphoric acid fuel cells (on-site FC). However, for such cells to be effectively utilized, a cogeneration system designed to use the heat generated must be developed at low cost. Room heating and hot-water supply are the most simple and efficient uses of the waste heat of fuel cells. However, due to the short room-heating period of about 4 months in most areas in Japan, the sites having demand for waste heat of fuel cells throughout the year will be limited to hotels and hospitals Tokyo Gas has therefore been developing an on-site FC and the technology to utilize tile waste heat of fuel cells for room cooling by means of an absorption refrigerator. The paper describes the results of fuel cell cogeneration tests conducted on a double effect gas absorption chiller heater with auxiliary waste heat recovery (WGAR) that Tokyo Gas developed in its Energy Technology Research Laboratory.

Urata, Tatsuo [Tokyo Gas Company, LTD, Tokyo (Japan)

1996-12-31T23:59:59.000Z

297

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

298

Effect of temperature on reduction of CaSO{sub 4} oxygen carrier in chemical-looping combustion of simulated coal gas in a fluidized bed reactor  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) is a promising combustion technology for gaseous and solid fuel with efficient use of energy and inherent separation of CO{sub 2}. The concept of a coal-fueled CLC system using, calcium sulfate (CaSO{sub 4}) as oxygen carrier is proposed in this study. Reduction tests of CaSO{sub 4} oxygen carrier with simulated coal gas were performed in a laboratory-scale fluidized bed reactor in the temperature range of 890-950{degree}C. A high concentration of CO{sub 2} was obtained at the initial reduction period. CaSO{sub 4} oxygen carrier exhibited high reactivity initially and decreased gradually at the late period of reduction. The sulfur release during the reduction of CaSO{sub 4} as oxygen carrier was also observed and analyzed. H{sub 2} and CO{sub 2} conversions were greatly influenced by reduction temperature. The oxygen carrier conversion and mass-based reaction rates during the reduction at typical temperatures were compared. Higher temperatures would enhance reaction rates and result in high conversion of oxygen carrier. An XRD patterns study indicated that CaS was the dominant product of reduction and the variation of relative intensity with temperature is in agreement with the solid conversion. ESEM analysis indicated that the surface structure of oxygen carrier particles changed significantly from impervious to porous after reduction. EDS analysis also demonstrated the transfer of oxygen from the oxygen carrier to the fuel gas and a certain amount of sulfur loss and CaO formation on the surface at higher temperatures. The reduction kinetics of CaSO{sub 4} oxygen carrier was explored with the shrinking unreacted-core model. The apparent kinetic parameters were obtained, and the kinetic equation well predicted the experimental data. Finally, some basic considerations on the use of CaSO{sub 4} oxygen carrier in a CLC system for solid fuels were discussed.

Song, Q.L.; Xiao, R.; Deng, Z.Y.; Shen, L.H.; Xiao, J.; Zhang, M.Y. [Southeast University, Nanjing (China)

2008-12-15T23:59:59.000Z

299

Zevenhoven & Kilpinen CROSS EFFECTS, TOTAL SYSTEM LAY-OUT 13.6.2001 10-1 Figure 10.1 Typical pulverised coal combustion and gas clean-up system: dry scrubber +  

E-Print Network [OSTI]

pulverised coal combustion and gas clean-up system: dry scrubber + baghouse filter for SO2 and particulate For a conventional pulverised coal-fired power plant a set-up is shown in Figure 10.1, with a gas clean-up system scrubber (pH ~ 6) 60 - 70 7 Re-heater 350 - 400 8 SCR DeNOx 300 - 400 9 Active coke bed 100 - 150 Figure 10

Zevenhoven, Ron

300

Prediction of formation of gas-phase bubbles correlated by vortices in the fuel reactor of chemical looping combustion  

Science Journals Connector (OSTI)

Abstract Chemical looping combustion (CLC) as a potential CO2 capture technology has been considered as a promising and likely alternative to traditional combustion technology to mitigate the CO2 emission due to its prosecution of CO2 sequestration at a low cost. Although a number of studies on the hydrodynamic behaviours of the CLC process in fuel reactor have been documented in the open literature, there have been rare studies on the correlation between the bubble formation and the local particulate volume fraction. This paper aims to investigate the CLC process in a fuel reactor using the CFD modelling, coupled with the heterogeneous reactions, the hydrodynamics and reaction kinetics occurring in the fuel reactor. A parameter correlating the occurrence of bubble and dynamic properties is proposed. The parameter may be acted as an indicator of time-dependent bubble evolution with a potential to be adopted in the CLC for controlling the bubbling phenomena since the occurrence of the bubbles at specific positions is highly correlated with the local large eddies embedded in the flow. The results obtained clearly indicate that the CFD model developed in the current study reasonably forecasts the hydrodynamic behaviours and important phenomena observed in the fuel reactor.

Luming Chen; Xiaogang Yang; Xia Li; Guang Li; Colin Snape

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Geotechnical/geochemical characterization of advanced coal process waste streams: Task 2  

SciTech Connect (OSTI)

Successful disposal practices for solid wastes produced from advanced coal combustion and coal conversion processes must provide for efficient management of relatively large volumes of wastes in a cost-effective and environmentally safe manner. At present, most coal-utilization solid wastes are disposed of using various types of land-based systems, and it is probable that this disposal mode will continue to be widely used in the future for advanced process wastes. Proper design and operation of land-based disposal systems for coal combustion wastes normally require appropriate waste transfer, storage, and conditioning subsystems at the plant to prepare the waste for transport to an ultimate disposal site. Further, the overall waste management plan should include a by-product marketing program to minimize the amount of waste that will require disposal. In order to properly design and operate waste management systems for advanced coal-utilization processes, a fundamental understanding of the physical properties, chemical and mineral compositions, and leaching behaviors of the wastes is required. In order to gain information about the wastes produced by advanced coal-utilization processes, 55 waste samples from 16 different coal gasification, fluidized-bed coal combustion (FBC), and advanced flue gas scrubbing processes were collected. Thirty-four of these wastes were analyzed for their bulk chemical and mineral compositions and tested for a detailed set of disposal-related physical properties. The results of these waste characterizations are presented in this report. In addition to the waste characterization data, this report contains a discussion of potentially useful waste management practices for advanced coal utilization processes.

Moretti, C.J.; Olson, E.S.

1992-09-01T23:59:59.000Z

302

Measurement and simulation of swirling coal combustion  

Science Journals Connector (OSTI)

Particle image velocimetry (PIV), thermocouples and flue gas analyzer are used to study swirling coal combustion and NO formation under different secondary-air ratios. Eulerian–Lagrangian large-eddy simulation (LES) using the Smagorinsky–Lilly sub-grid scale stress model, presumed-PDF fast chemistry and eddy-break-up (EBU) gas combustion models, particle devolatilization and particle combustion models, are simultaneously used to simulate swirling coal combustion. Statistical LES results are validated by measurement results. Instantaneous LES results show that the coherent structures for swirling coal combustion are stronger than those for swirling gas combustion. Particles are shown to concentrate along the periphery of the coherent structures. Combustion flame is located in the high vorticity and high particle concentration zones. Measurement shows that secondary-air ratios have little effect on final NO formation at the exit of the combustor.

Liyuan Hu; Lixing Zhou; Yonghao Luo; Caisong Xu

2013-01-01T23:59:59.000Z

303

Comparative environmental analysis of waste brominated plastic thermal treatments  

SciTech Connect (OSTI)

The aim of this research activity is to investigate the environmental impact of different thermal treatments of waste electric and electronic equipment (WEEE), applying a life cycle assessment methodology. Two scenarios were assessed, which both allow the recovery of bromine: (A) the co-combustion of WEEE and green waste in a municipal solid waste combustion plant, and (B) the staged-gasification of WEEE and combustion of produced syngas in gas turbines. Mass and energy balances on the two scenarios were set and the analysis of the life cycle inventory and the life cycle impact assessment were conducted. Two impact assessment methods (Ecoindicator 99 and Impact 2002+) were slightly modified and then used with both scenarios. The results showed that scenario B (staged-gasification) had a potentially smaller environmental impact than scenario A (co-combustion). In particular, the thermal treatment of staged-gasification was more energy efficient than co-combustion, and therefore scenario B performed better than scenario A, mainly in the impact categories of 'fossil fuels' and 'climate change'. Moreover, the results showed that scenario B allows a higher recovery of bromine than scenario A; however, Br recovery leads to environmental benefits for both the scenarios. Finally the study demonstrates that WEEE thermal treatment for energy and matter recovery is an eco-efficient way to dispose of this kind of waste.

Bientinesi, M. [Department of Chemical Engineering, Industrial Chemistry and Materials Science (DICCISM), University of Pisa, Via Diotisalvi 2, 56126 Pisa (Italy)], E-mail: matteo.bientinesi@ing.unipi.it; Petarca, L. [Department of Chemical Engineering, Industrial Chemistry and Materials Science (DICCISM), University of Pisa, Via Diotisalvi 2, 56126 Pisa (Italy)

2009-03-15T23:59:59.000Z

304

Use of Fe2O3-Containing Industrial Wastes As the Oxygen Carrier for Chemical-Looping Combustion of Coal: Effects of Pressure and Cycles  

Science Journals Connector (OSTI)

Industrial & Engineering Chemistry Research (2006), 45 (17), 6075-6080 CODEN: IECRED; ISSN:0888-5885. ... Chemical-Looping Combustion with NiO and Fe2O3 in a Thermobalance and Circulating Fluidized Bed Reactor with Double Loops ... Shen, L. H.; Wu, J. H.; Gao, Z. P.; Xiao, J. Combust. ...

Shuai Zhang; Chiranjib Saha; Yichao Yang; Sankar Bhattacharya; Rui Xiao

2011-09-13T23:59:59.000Z

305

Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications  

Broader source: Energy.gov [DOE]

Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 450 operational projects in 43 states. These projects convert a large source of greenhouse gases into a fuel that...

306

E-Print Network 3.0 - advanced combustion systems Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of these include pulverized coal combustion... combustion in gas turbines and coal gasification-fuel cell systems hold out ... Source: Kammen, Daniel M. - Renewable and...

307

Advanced Combustion  

SciTech Connect (OSTI)

Topics covered in this presentation include: the continued importance of coal; related materials challenges; combining oxy-combustion & A-USC steam; and casting large superalloy turbine components.

Holcomb, Gordon R. [NETL

2013-03-05T23:59:59.000Z

308

Fuel Gas Production from Organic Wastes by Low Capital Cost Batch Digestion  

Science Journals Connector (OSTI)

The technical background is reviewed on energy recovery from biomass--i.e., all organic wastes, especially municipal solid wastes, but also including agricultural residues and crops grown specifically for ener...

Donald L. Wise; Alfred P. Leuschner…

1986-01-01T23:59:59.000Z

309

Energy from Waste UK Joint Statement on Energy from Waste  

E-Print Network [OSTI]

Energy from Waste UK Joint Statement on Energy from Waste Read more overleaf Introduction Energy from waste provides us with an opportunity for a waste solution and a local source of energy rolled,itcan onlyaddressaportionofthewastestream andisnotsufficientonitsown. Energy obtained from the combustion of residual waste (Energy from

310

WASTE HYDROGEN PIPELINES MONITORING IN MODERN POWER PLANT Pawel Gsior, Jerzy Kaleta  

E-Print Network [OSTI]

for combustion generators (leading technology), and the second one use purified hydrogen for fuel cells of four supply gas pipelines (one with pure hydrogen to the fuel cell and three others with waste hydrogen and constructed. Two energetic technologies were applied. First use hydrogen and hydrocarbons as a fuel

Boyer, Edmond

311

Kinetic determination of a highly reactive impregnated Fe2O3/Al2O3 oxygen carrier for use in gas-fueled Chemical Looping Combustion  

Science Journals Connector (OSTI)

Abstract The objective of this work was to determine the kinetic parameters for reduction and oxidation reactions of a highly reactive Fe-based oxygen carrier for use in Chemical Looping Combustion (CLC) of gaseous fuels containing CH4, CO and/or H2, e.g. natural gas, syngas and PSA-off gas. The oxygen carrier was prepared by impregnation of iron on alumina. The effect of both the temperature and gas concentration was analyzed in a thermogravimetric analyzer (TGA). The grain model with uniform conversion in the particle and reaction in grains following the shrinking core model (SCM) was used for kinetics determination. It was assumed that the reduction reactions were controlled by two different resistances: the reaction rate was controlled by chemical reaction in a first step, whereas the mechanism that controlled the reactions at higher conversion values was diffusion through the product layer around the grains. Furthermore, it was found that the reduction reaction mechanism was based on the interaction of Fe2O3 with Al2O3 in presence of the reacting gases to form FeAl2O4 as the only stable Fe-based phase. The reaction order values found for the reducing gases were 0.25, 0.3 and 0.6 for CH4, H2 and CO, respectively, and the activation energy took values of between 8 kJ mol?1 (for H2) and 66 kJ mol?1 (for CH4). With regard to oxidation kinetics, the reacting model assumed a reaction rate that was only controlled by chemical reaction. Values of 0.9 and 23 kJ mol?1 were found for reaction order and activation energy, respectively. Finally, the solids inventory needed in a CLC system was also estimated by considering kinetic parameters. The total solids inventory in the CLC unit took a minimum value of 150 kg MW?1 for CH4 combustion, which is a low value when compared to those of other Fe-based materials found in the literature.

A. Cabello; A. Abad; F. García-Labiano; P. Gayán; L.F. de Diego; J. Adánez

2014-01-01T23:59:59.000Z

312

Comparative investigation on chemical looping combustion of coal-derived synthesis gas containing H2S over supported NiO oxygen carriers  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) of simulated coal-derived synthesis gas was conducted with NiO oxygen carriers supported on SiO2, ZrO2, TiO2, and sepiolite. The effect of H2S on the performance of these samples for the CLC process was also evaluated. Five-cycle thermogravimetric analysis (TGA) tests at 800 #1;C indicated that all oxygen carriers had a stable performance at 800 #1;C, except NiO/SiO2. Full reduction/oxidation reactions of the oxygen carrier were obtained during the five-cycle test. It was found that support had a significant effect on reaction performance of NiO both in reduction and oxidation rates. The reduction reaction was significantly faster than the oxidation reaction for all oxygen carriers, while the oxidation reaction is fairly slow due to oxygen diffusion on NiO layers. The reaction profile was greatly affected by the presence of H2S, but there was no effect on the capacity due to the presence of H2S in synthesis gas. The presence of H2S decreased reduction reaction rates significantly, but oxidation rates of reduced samples increased. X-ray diffraction (XRD) data of the oxidized samples after a five-cycle test showed stable crystalline phases without any formation of sulfides or sulfites/sulfates. Increase in reaction temperature to 900 #1;C had a positive effect on the performance.

Ksepko, E.; Siriwardane, R.; Tian, H.; Simonyi, T.; Sciazko, M.

2010-01-01T23:59:59.000Z

313

Effect of hydrogen sulfide on chemical looping combustion of coal-derived synthesis gas over bentonite-supported metal-oxide oxygen carriers  

SciTech Connect (OSTI)

The effect of hydrogen sulfide (H{sub 2}S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxides - such as iron oxide, nickel oxide, manganese oxide, and copper oxide - was investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H{sub 2}S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H{sub 2}S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H{sub 2}S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H{sub 2}S for all four metal oxides.

Tian, H.J.; Simonyi, T.; Poston, J.; Siriwardane, R. [US DOE, Morgantown, WV (United States). National Energy Technology Laboratory

2009-09-15T23:59:59.000Z

314

STEADY-STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect (OSTI)

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The methodology of flammability analysis for Hanford tank waste is developed. The hydrogen generation rate model was applied to calculate the gas generation rate for 177 tanks. Flammability concentrations and the time to reach 25% and 100% of the lower flammability limit, and the minimum ventilation rate to keep from 100 of the LFL are calculated for 177 tanks at various scenarios.

HU TA

2007-10-26T23:59:59.000Z

315

Plasma chemical process for treatment of hazardous wastes  

Science Journals Connector (OSTI)

The conventional methods of combustion are not always effective. One of the new methods for waste treatment is the destruction in plasma jet of chemical reactive gases. An unit with plasmotron power up to 50 kW is constructed for the investigations. Sulphur, chlorine and nitrogen containing organic toxic wastes are subjected to destruction. Water steam, air and their mixture are used as plasma generating gas and chemical reagent. The studies are carried out at a different ratio of plasma generating gasltoxic wastes at temperatures to 2000°C. The products are analysed by gas mass spectroscopy. The released gas is composed of Co, H2 and CO2. There were found no hydrocarbons, dioxine and furan. Gas heat value is good for its burning without environment pollution.

Iv. Georgiev; Zh. Bulgaranova; B. Kumanova

1995-01-01T23:59:59.000Z

316

Commercialization of waste gob gas and methane produced in conjunction with coal mining operations. Final report, August 1992--December 1993  

SciTech Connect (OSTI)

The primary objectives of the project were to identify and evaluate existing processes for (1) using gas as a feedstock for production of marketable, value-added commodities, and (2) enriching contaminated gas to pipeline quality. The following gas conversion technologies were evaluated: (1) transformation to liquid fuels, (2) manufacture of methanol, (3) synthesis of mixed alcohols, and (4) conversion to ammonia and urea. All of these involved synthesis gas production prior to conversion to the desired end products. Most of the conversion technologies evaluated were found to be mature processes operating at a large scale. A drawback in all of the processes was the need to have a relatively pure feedstock, thereby requiring gas clean-up prior to conversion. Despite this requirement, the conversion technologies were preliminarily found to be marginally economic. However, the prohibitively high investment for a combined gas clean-up/conversion facility required that REI refocus the project to investigation of gas enrichment alternatives. Enrichment of a gas stream with only one contaminant is a relatively straightforward process (depending on the contaminant) using available technology. However, gob gas has a unique nature, being typically composed of from constituents. These components are: methane, nitrogen, oxygen, carbon dioxide and water vapor. Each of the four contaminants may be separated from the methane using existing technologies that have varying degrees of complexity and compatibility. However, the operating and cost effectiveness of the combined system is dependent on careful integration of the clean-up processes. REI is pursuing Phase 2 of this project for demonstration of a waste gas enrichment facility using the approach described above. This is expected to result in the validation of the commercial and technical viability of the facility, and the refinement of design parameters.

Not Available

1993-12-01T23:59:59.000Z

317

NETL: Combustion Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abbreviations & Acronyms Abbreviations & Acronyms Reference Shelf Solicitations & Awards Abbreviations & Acronyms The Combustion Technologies Product uses a number of abbreviations and acronyms. This web page gives you a definition of frequently used terms, as follows: 1½-Generation PFBC -- A PFBC plant where the hot (about 1400ºF) PFBC exhaust gases are used as a vitiated air supply for a natural gas combustor supplying high-temperature gas (above 2000ºF) to a combustion turbine expander (synonym for "PFB-NGT"). 1st-Generation PFBC -- Commercial PFBC technology where an unfired low-temperature (below 1650ºF) ruggedized turbine expander expands PFBC exhaust gases (synonym for "PFB-EGT"). 2nd-Generation PFBC (see synonyms: "APFBC," "PFB-CGT") -- Advanced PFBC where a carbonizer (mild gasifier) provides hot (about 1400ºF) coal-derived synthetic fuel gas to a special topping combustor. The carbonizer char is burned in the PFBC, and the PFBC exhaust is used as a hot (about 1400ºF) vitiated air supply for the topping combustor. The syngas and vitiated air are burned in a topping combustor to provide high-temperature gas (above 1700ºF) to a combustion turbine expander.

318

NETL: Combustion Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nebraska Public Power District's Sheldon Station with APFBC Technology Nebraska Public Power District's Sheldon Station with APFBC Technology FBC Repower APFBC AES Greenidge APFBC Dan River FBC, APFBC Four Corners CHIPPS H.F. Lee Products Summary Sheldon Summary APFBC Sheldon GFBCC Sheldon APFBC L.V. Sutton Contents: APFBC Repowering Project Summary Key Features Site Layout Performance Environmental Characteristics Cost Other Combustion Systems Repowering Study Links: A related study is underway that would repower Sheldon Unit 1 and Unit 2 with gasification fluidized-bed combined cycle technology (GFBCC). CLICK HERE to find out more about repowering the Sheldon station with GFBCC instead. APFBC Repowering Project Summary Click on picture to enlarge Advanced circulating pressurized fluidized-bed combustion combined cycle systems (APFBC) are systems with jetting-bed pressurized fluidized-bed (PFB) carbonizer/gasifier and circulating PFBC combustor. The PFB carbonizer and PFBC both operate at elevated pressures (10 to 30 times atmospheric pressure) to provide syngas for operating a gas turbine topping combustor giving high cycle energy efficiency. The remaining char from the PFB carbonizer is burned in the pressurized PFBC. The combustion gas from the PFB also feeds thermal energy to the gas turbine topping combustor. This provides combined cycle plant efficiency on coal by providing the opportunity to generate electricity using both high efficiency gas turbines and steam.

319

The utilization of flue gas desulfurization waste by-products in construction brick.  

E-Print Network [OSTI]

??Millions of tons of waste by-products from Texas coal burning plants are produced each year. Two common byproducts are the fuel ashes and calcium sulfate… (more)

Berryman, Charles Wayne

2012-01-01T23:59:59.000Z

320

Combustion Noise  

E-Print Network [OSTI]

stabilize or destabilize the modes of the system, depending on the configuration of the combustor and the form of the coupling [26, 30]. In contrast to combustion instability, in broad-band combustion noise the unsteadiness in the rate of combustion... from th s in a mod on tempera , entropic a de of indir t frequenci r, open que sical theory assical expe s [14] who it by a spa d a transie le gases. A e bubble si idered as a flame was ent was o ng and dif depended udy it wa ion, ? ?,p r t? : (a...

Dowling, Ann P.; Mahmoudi, Yasser

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

20 - Chemical looping combustion (CLC)  

Science Journals Connector (OSTI)

Abstract: Chemical-looping combustion (CLC) is a new combustion technology with inherent separation of the greenhouse gas CO2. The technology involves the use of a metal oxide as an oxygen carrier which transfers oxygen from combustion air to the fuel, and hence a direct contact between air and fuel is avoided. Two inter-connected fluidized beds, i.e. fuel reactor and air reactor, are used in the process. The outlet gas from the fuel reactor consists ideally of CO2 and H2O, and the latter is easily removed by condensation. This chapter presents the basic principles, gives an overview of oxygen-carrier materials and operational experiences, discusses the application to gaseous, liquid and solid fuels, and the use for combustion as well as for hydrogen production.

A. Lyngfelt

2013-01-01T23:59:59.000Z

322

Mechanisms of gas bubble retention and release: results for Hanford Waste Tanks 241-S-102 and 241-SY-103 and single-shell tank simulants  

SciTech Connect (OSTI)

Research at Pacific Northwest National Laboratory (PNNL) has probed the physical mechanisms and waste properties that contribute to the retention and release of flammable gases from radioactive waste stored in underground tanks at Hanford. This study was conducted for Westinghouse Hanford Company as part of the PNNL Flammable Gas Project. The wastes contained in the tanks are mixes of radioactive and chemical products, and some of these wastes are known to generate mixtures of flammable gases, including hydrogen, nitrous oxide, and ammonia. Because these gases are flammable, their retention and episodic release pose a number of safety concerns.

Gauglitz, P.A.; Rassat, S.D.; Bredt, P.R.; Konynenbelt, J.H.; Tingey, S.M.; Mendoza, D.P.

1996-09-01T23:59:59.000Z

323

Large-Eddy Simulation of Swirling Pulverized-Coal Combustion  

Science Journals Connector (OSTI)

A Eulerian-Lagrangian large-eddy simulation (LES) with a Smagorinsky-Lilly sub-grid scale stress model, presumed-PDF fast chemistry and EBU gas combustion models, particle devolatilization and particle combustion

L. Y. Hu; L. X. Zhou; Y. H. Luo; C. S. Xu

2013-01-01T23:59:59.000Z

324

Combustion Engine  

Broader source: Energy.gov [DOE]

Pictured here is an animation showing the basic mechanics of how an internal combustion engine works. With support from the Energy Department, General Motors researchers developed a new technology ...

325

NETL: Combustion Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Turbines for APFBC Gas Turbines for APFBC FBC Repower Simple Description Detailed Description APFBC Specs GTs for APFBC Suited for Repowering Existing Power Plants with Advanced Pressurized Fluidized-Bed Combined Cycles APFBC combined cycles have high energy efficiency levels because they use modern, high-temperature, high-efficiency gas turbines as the core of a combined power cycle. This web page discusses a current U.S. Department of Energy project that is evaluating combustion turbines suited for repowering existing steam plants. The natural-gas-fueled version of the Siemens Westinghouse Power Corporation W501F. Modified versions of this gas turbine core are suited for operating in APFBC power plants. Contents: Introduction APFBC Repowering Considerations

326

Fuel-Slurry Integrated Gasifier/Gas Turbine (FSIG/GT) Alternative for Power Generation Applied to Municipal Solid Waste (MSW)  

Science Journals Connector (OSTI)

The gas is cleaned to bring the particle content and size as well alkaline concentration within the acceptable limits for injections into standard gas turbines. ... The proper disposal and use of Municipal Solid Wastes (MSW) for power generation remains among the most pressing problems of medium to large cities. ... Bubble sizes and raising velocities through the gasifier bed (Configuration A). ...

Marcio L. de Souza-Santos; Kevin B. Ceribeli

2013-11-22T23:59:59.000Z

327

Recent ORNL experience in site performance prediction: the Gas Centrifuge Enrichment Plant and the Oak Ridge Central Waste Disposal Facility  

SciTech Connect (OSTI)

The suitability of the Portsmouth Gas Centrifuge Enrichment Plant Landfill and the Oak Ridge, Tennessee, Central Waste Disposal Facility for disposal of low-level radioactive waste was evaluated using pathways analyses. For these evaluations, a conservative approach was selected; that is, conservatism was built into the analyses when assumptions concerning future events had to be made or when uncertainties concerning site or waste characteristics existed. Data from comprehensive laboratory and field investigations were used in developing the conceptual and numerical models that served as the basis for the numerical simulations of the long-term transport of contamination to man. However, the analyses relied on conservative scenarios to describe the generation and migration of contamination and the potential human exposure to the waste. Maximum potential doses to man were calculated and compared to the appropriate standards. Even under this conservative framework, the sites were found to provide adequate buffer to persons outside the DOE reservations and conclusions concerning site capacity and site acceptability were drawn. Our experience through these studies has shown that in reaching conclusions in such studies, some consideration must be given to the uncertainties and conservatisms involved in the analyses. Analytical methods to quantitatively assess the probability of future events to occur and to quantitatively determine the sensitivity of the results to data uncertainty may prove useful in relaxing some of the conservatism built into the analyses. The applicability of such methods to pathways analyses is briefly discussed.

Pin, F.G.

1985-01-01T23:59:59.000Z

328

Overview of Hanford Site High-Level Waste Tank Gas and Vapor Dynamics  

SciTech Connect (OSTI)

Hanford Site processes associated with the chemical separation of plutonium from uranium and other fission products produced a variety of volatile, semivolatile, and nonvolatile organic and inorganic waste chemicals that were sent to high-level waste tanks. These chemicals have undergone and continue to undergo radiolytic and thermal reactions in the tanks to produce a wide variety of degradation reaction products. The origins of the organic wastes, the chemical reactions they undergo, and their reaction products have recently been examined by Stock (2004). Stock gives particular attention to explaining the presence of various types of volatile and semivolatile organic species identified in headspace air samples. This report complements the Stock report by examining the storage of volatile and semivolatile species in the waste, their transport through any overburden of waste to the tank headspaces, the physical phenomena affecting their concentrations in the headspaces, and their eventual release into the atmosphere above the tanks.

Huckaby, James L.; Mahoney, Lenna A.; Droppo, James G.; Meacham, Joseph E.

2004-08-31T23:59:59.000Z

329

COMBUSTION RESEARCH - FY-1979  

E-Print Network [OSTI]

deposition due to the heat of combustion. The problem wedimensionless heat of combustion, QpYoxoolhw t transferredfraction of specie i heat of combustion per gram of fuel

,

2012-01-01T23:59:59.000Z

330

Electricity from coal and utilization of coal combustion by-products  

SciTech Connect (OSTI)

Most electricity in the world is conventionally generated using coal, oil, natural gas, nuclear energy, or hydropower. Due to environmental concerns, there is a growing interest in alternative energy sources for heat and electricity production. The major by-products obtained from coal combustion are fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) materials. The solid wastes produced in coal-fired power plants create problems for both power-generating industries and environmentalists. The coal fly ash and bottom ash samples may be used as cementitious materials.

Demirbas, A. [Sila Science, Trabzon (Turkey)

2008-07-01T23:59:59.000Z

331

Laboratory measurements of gas flow along a pressurized grout/membrane/halite interface for the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

A series of laboratory gas-flow tests has been performed on interfaces comprised of concrete, very low-density polyethylene membrane, and halite. These tests were conducted to (1) evaluate whether a meaningful test can be run to quantify the effectiveness of a membrane, and (2) aid in the design of an Alcove Gas Barrier at the Waste Isolation Pilot Plant (WIPP), where membranes of this type are being considered for use at the interface between the concrete or grout of the gas barrier structure and the surrounding halite. Over 400 longitudinal transient-flow and steady-state radial-flow tests have been completed. However, it is not clear from these tests that the test results can be meaningfully applied to the full-scale Alcove Gas Barrier configuration because the measured permeabilities are several orders of magnitude higher than the meter-scale in situ concrete seal tests conducted at the WIPP as part of the Small-Scale Seal Performance Tests. Results show that the membranes decrease gas permeability along the concrete/halite interface by one to two orders of magnitude to below 10{sup {minus}15} m{sup 2} for the simplified test configurations. 28 refs., 11 figs., 16 tabs.

Ucpirti, H.; Daemen, J.J.K. [Univ. of Nevada, Reno, NV (United States); Finley, R.E.; George, J.T. [Sandia National Labs., Albuquerque, NM (United States)

1995-01-01T23:59:59.000Z

332

Effect of explicit representation of detailed stratigraphy on brine and gas flow at the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

Stratigraphic units of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) disposal room horizon includes various layers of halite, polyhalitic halite, argillaceous halite, clay, and anhydrite. Current models, including those used in the WIPP Performance Assessment calculations, employ a ``composite stratigraphy`` approach in modeling. This study was initiated to evaluate the impact that an explicit representation of detailed stratigraphy around the repository may have on fluid flow compared to the simplified ``composite stratigraphy`` models currently employed. Sensitivity of model results to intrinsic permeability anisotropy, interbed fracturing, two-phase characteristic curves, and gas-generation rates were studied. The results of this study indicate that explicit representation of the stratigraphy maintains higher pressures and does not allow as much fluid to leave the disposal room as compared to the ``composite stratigraphy`` approach. However, the differences are relatively small. Gas migration distances are also different between the two approaches. However, for the two cases in which explicit layering results were considerably different than the composite model (anisotropic and vapor-limited), the gas-migration distances for both models were negligible. For the cases in which gas migration distances were considerable, van Genuchten/Parker and interbed fracture, the differences between the two models were fairly insignificant. Overall, this study suggests that explicit representation of the stratigraphy in the WIPP PA models is not required for the parameter variations modeled if ``global quantities`` (e.g., disposal room pressures, net brine and gas flux into and out of disposal rooms) are the only concern.

Christian-Frear, T.L.; Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States). Geohydrology Dept.

1996-04-01T23:59:59.000Z

333

The Beckett System Recovery and Utilization of Low Grade Waste Heat From Flue Gas  

E-Print Network [OSTI]

. During low demand periods, the unit is gas-fired and produces 150 psi steam at high efficiency. In the fall, the heat exchanger is converted to accept flue gas from the large original water tube boilers. The flue gas heats water, which preheats make...

Henderson, W. R.; DeBiase, J. F.

1983-01-01T23:59:59.000Z

334

Generating power with waste wood  

SciTech Connect (OSTI)

Among the biomass renewables, waste wood has great potential with environmental and economic benefits highlighting its resume. The topics of this article include alternate waste wood fuel streams; combustion benefits; waste wood comparisons; waste wood ash; pilot scale tests; full-scale test data; permitting difficulties; and future needs.

Atkins, R.S.

1995-02-01T23:59:59.000Z

335

Turbulent Combustion in SDF Explosions  

SciTech Connect (OSTI)

A heterogeneous continuum model is proposed to describe the dispersion and combustion of an aluminum particle cloud in an explosion. It combines the gas-dynamic conservation laws for the gas phase with a continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models. It incorporates a combustion model based on the mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the C-4 booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Numerical simulations of the explosion fields from 1.5-g Shock-Dispersed-Fuel (SDF) charge in a 6.6 liter calorimeter were used to validate the combustion model. Then the model was applied to 10-kg Al-SDF explosions in a an unconfined height-of-burst explosion. Computed pressure histories are compared with measured waveforms. Differences are caused by physical-chemical kinetic effects of particle combustion which induce ignition delays in the initial reactive blast wave and quenching of reactions at late times. Current simulations give initial insights into such modeling issues.

Kuhl, A L; Bell, J B; Beckner, V E

2009-11-12T23:59:59.000Z

336

NETL: IEP – Post-Combustion CO2 Emissions Control - Oxy-Combustion Boiler  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxy-Combustion Boiler Material Development Oxy-Combustion Boiler Material Development Project No.: DE-NT0005262 CLICK ON IMAGE TO ENLARGE Foster Wheeler Oxy-combustion CFD Graphic The objectives of this Foster Wheeler Corporation-managed program are to assess the corrosion characteristics of oxy-combustion relative to air-fired combustion; identify the corrosion mechanisms involved; and determine the effects of oxy-combustion on conventional boiler tube materials, conventional protective coatings, and alternative materials and coatings when operating with high to low sulfur coals. The program involves the prediction of oxy-combustion gas compositions by computational fluid dynamic calculations, exposure of coupons of boiler materials and coverings coated with coal ash deposit to simulated oxy-combustion gases in electric

337

Co-combustion feasibility study. Final report  

SciTech Connect (OSTI)

This report investigates the technical and economic feasibility of co-combusting municipal sewage sludge produced by the Saratoga County Sewer District No. 1 with paper mill sludge produced by the Cottrell Paper Company, Encore Paper Company, International Paper Company, Mohawk Paper Mills, and TAGSONS Papers at the Saratoga County Sewer District No. 1`s secondary wastewater treatment plant and recovering any available energy products. The co-combustion facility would consist of sludge and wood chip storage and conveying systems, belt filter presses, screw presses, fluidized-bed incinerators, venturi scrubbers and tray cooling systems, ash dewatering facilities, heat recovery steam generators, gas-fired steam superheaters, and a back-pressure steam turbine system. Clean waste wood chips would be used as an auxiliary fuel in the fluidized-bed incinerators. It is recommended that the ash produced by the proposed facility be beneficially used, potentially as a raw material in the manufacture of cement and/or as an interim barrier layer in landfills.

Handcock, D.J. [Clough, Harbour and Associates, Albany, NY (United States)

1995-01-01T23:59:59.000Z

338

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

339

Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333  

SciTech Connect (OSTI)

The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion adsorption chemicals, solid-liquid separation methods, and achievable decontamination factors. Results of the radionuclide removal testing indicate that the radionuclides, including Tc-99, can be removed with inorganic sorbents and precipitating agents. Evaporation test results indicate that the simulant can be evaporated to fairly high concentration prior to formation of appreciable solids, but corrosion has not yet been examined.

McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.; Taylor-Pashow, Kathryn M.; Adamson, Duane J.; Crawford, Charles L.; Morse, Megan M.

2014-01-07T23:59:59.000Z

340

Co-Combustion of Refuse Derived Fuel with Anthracites in a CFB Boiler  

Science Journals Connector (OSTI)

Combustion of Refuse derived fuel (RDF) is considered as a priority solution to energy recovery from municipal solid waste (MSW). The co-combustion characteristics of anthracite coals with RDF were determined in ...

Dong-Won Kim; Jong-Min Lee; Jae-Sung Kim

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Eco-efficiency for greenhouse gas emissions mitigation of municipal solid waste management: A case study of Tianjin, China  

SciTech Connect (OSTI)

The issue of municipal solid waste (MSW) management has been highlighted in China due to the continually increasing MSW volumes being generated and the limited capacity of waste treatment facilities. This article presents a quantitative eco-efficiency (E/E) analysis on MSW management in terms of greenhouse gas (GHG) mitigation. A methodology for E/E analysis has been proposed, with an emphasis on the consistent integration of life cycle assessment (LCA) and life cycle costing (LCC). The environmental and economic impacts derived from LCA and LCC have been normalized and defined as a quantitative E/E indicator. The proposed method was applied in a case study of Tianjin, China. The study assessed the current MSW management system, as well as a set of alternative scenarios, to investigate trade-offs between economy and GHG emissions mitigation. Additionally, contribution analysis was conducted on both LCA and LCC to identify key issues driving environmental and economic impacts. The results show that the current Tianjin's MSW management system emits the highest GHG and costs the least, whereas the situation reverses in the integrated scenario. The key issues identified by the contribution analysis show no linear relationship between the global warming impact and the cost impact in MSW management system. The landfill gas utilization scenario is indicated as a potential optimum scenario by the proposed E/E analysis, given the characteristics of MSW, technology levels, and chosen methodologies. The E/E analysis provides an attractive direction towards sustainable waste management, though some questions with respect to uncertainty need to be discussed further.

Zhao Wei, E-mail: zhaowei.tju@gmail.com [College of Civil Engineering and Architecture, Liaoning University of Technology, 121000 Jinzhou (China); Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands); Huppes, Gjalt, E-mail: huppes@cml.leidenuniv.nl [Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands); Voet, Ester van der, E-mail: Voet@cml.leidenuniv.nl [Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands)

2011-06-15T23:59:59.000Z

342

Towards effective regulation of offshore oil and gas waste management in Nigeria.  

E-Print Network [OSTI]

??The development of the offshore oil and gas industry has been going on for many decades with little thought of the consequences of its activities… (more)

Ofuani, Anwuli Irene

2009-01-01T23:59:59.000Z

343

Heat waste recovery system from exhaust gas of diesel engine to a reciprocal steam engine.  

E-Print Network [OSTI]

??This research project was about the combined organic Rankine cycle which extracted energy from the exhaust gas of a diesel engine. There was a study… (more)

Duong, Tai Anh

2011-01-01T23:59:59.000Z

344

NETL- High-Pressure Combustion Research Facility  

SciTech Connect (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2013-07-08T23:59:59.000Z

345

Generating Resources Combined Cycle Combustion Turbine  

E-Print Network [OSTI]

turbine (s) Heat recovery steam generator (s) - HRSG with or without duct firing Natural gas supply11/17/2014 1 Generating Resources Combined Cycle Combustion Turbine Utility Scale Solar PV Steven doing recently around two key supply-side resource technologies 1. Combined Cycle Combustion Turbine

346

NETL- High-Pressure Combustion Research Facility  

ScienceCinema (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2014-06-26T23:59:59.000Z

347

Combustion & Health  

E-Print Network [OSTI]

FFCOMBUSTION & HEALTH Winifred J. Hamilton, PhD, SM Clear Air Through Energy Efficiency (CATEE) Galveston, TX October 9?11, 2012 FFCOMBUSTION & HEALTH FFCOMBUSTION: THE THREAT ? Biggest threat to world ecosystems (and to human health...) ? Combustion of fossil fuels for ? Electricity ? Industrial processes ? Vehicle propulsion ? Cooking and heat ? Other ? Munitions ? Fireworks ? Light ? Cigarettes, hookahs? FFCOMBUSTION & HEALTH FFCOMBUSTION: THE THREAT ? SCALE (think health...

Hamilton, W.

2012-01-01T23:59:59.000Z

348

Reuse of coal combustion by-products: A new profit center  

SciTech Connect (OSTI)

Coal combustion by-products (CCBs) are generated from the combustion of coal for energy production. Approximately 82 million tons of CCBs are produced each year by electric utilities. There are several common types of CCBs produced by coal combustion--fly ash, bottom ash, boiler slag, flue gas desulfurization material (FGD) and fluidized bed combustion byproducts (FBC). Some CCBs such as fly ash, have pozzolanic properties and may have cementitious properties, both of which are advantageous for engineering, construction and waste remediation applications. The American Society for Testing Materials (ASTM) in ASTM C-618 has created two classifications of useful and quality coal ash, Class F ash and Class C ash. Each class of coal ash has different pozzolanic and cementitious characteristics. Coal ash can be utilized in many manufacturing, mining, agricultural, engineering, construction and waste remediation applications. These potential applications may provide a new revenue source for utilities. The profitability of these applications can, however, be limited by applicable state regulations. Prior to initiating any reuse application, a utility should ensure regulatory approval of the proposed use. Approval may be apparent from a review of state law and regulations. Often times, further regulatory analysis and consultations may be necessary.

Jagiella, D. [Howard and Howard Attorneys, Peoria, IL (United States)

1997-09-01T23:59:59.000Z

349

Adsorption properties of coal from the Ishideiskoe deposit, semicokes, and ash and slag wastes from the combustion of coals from Siberia and Sakhalin  

Science Journals Connector (OSTI)

The results of studying the adsorption properties of black coal, semicoke, and waste coals from a number of coal deposits in Irkutsk oblast and Sakhalin and the Irsha-Borodino deposit are reported. The results...

N. G. Vyazova; V. N. Kryukova; L. P. Shaulina; E. A. Pisar’kova…

2014-05-01T23:59:59.000Z

350

Combustion Characteristics, Emissions and Heat Release Rate Analysis of a Homogeneous Charge Compression Ignition Engine with Exhaust Gas Recirculation Fuelled with Diesel  

Science Journals Connector (OSTI)

The EGR, a very well-known method for NOx reduction in diesel engines, is also a method in HCCI combustion mode, when fuelled with commercial fuel, to improve engine power, mainly because of the increase of the ignition delay. ... Heywood, J. B. “Internal Combustion Engine Fundamentals”, Ed. McGraw-Hill Book Company, Singapur (Singapur), 1988. ... (Mechanical Engineering Laboratory MITI) “Chemical Kinetic Study of a Cetane Number Enhancing Additive for an LGP DI Diesel Engine,” ...

Miguel Torres García; Francisco J. Jiménez-Espadafor Aguilar; Tomás Sánchez Lencero

2009-04-02T23:59:59.000Z

351

Advances in Diode Laser Absorption Sensors for Combustion and Propulsion  

Science Journals Connector (OSTI)

Progress is reported in the evolution of diode laser sensors for combustion and propulsion systems. Applications are diverse, ranging from IC engines and gas turbine combustors to...

Hanson, Ronald K

352

Gas Natural - CNG y GNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Natural Dispensador de Gas Natural Gas Natural Dispensador de Gas Natural El gas natural, un combustible fósil compuesto básicamente de metano, es uno de los combustibles alternativos menos contaminantes. Puede ser usado como gas natural comprimido (GNC) o como gas natural licuado (GNL) para autos y camiones. Existen vehículos diseñados para funcionar exclusivamente con gas natural. Por otra parte hay vehículos de doble combustible o bi-combustibles que también puede funcionar con gasolina o diesel. Los vehículos de doble combustible permiten que el usuario aproveche la gran disponibilidad de gasolina o diesel, pero use la alternativa menos contaminante y más económica cuando el gas natural esté disponible. Ya que el gas natural es almacenado en depósitos de combustible de alta

353

Two-stage thermal/nonthermal waste treatment process  

SciTech Connect (OSTI)

An innovative waste treatment technology is being developed in Los Alamos to address the destruction of hazardous organic wastes. The technology described in this report uses two stages: a packed bed reactor (PBR) in the first stage to volatilize and/or combust liquid organics and a silent discharge plasma (SDP) reactor to remove entrained hazardous compounds in the off-gas to even lower levels. We have constructed pre-pilot-scale PBR-SDP apparatus and tested the two stages separately and in combined modes. These tests are described in the report.

Rosocha, L.A.; Anderson, G.K.; Coogan, J.J.; Kang, M.; Tennant, R.A.; Wantuck, P.J.

1993-05-01T23:59:59.000Z

354

Paper # A02 Topic: Laminar Flames US Combustion Meeting  

E-Print Network [OSTI]

been focused on synthetic fuel gas (syngas) combustion. Syngas is derived from coal throughPaper # A02 Topic: Laminar Flames 1 5th US Combustion Meeting Organized by the Western States Section of the Combustion Institute and Hosted by the University of California at San Diego March 25

Seitzman, Jerry M.

355

Stretch Efficiency for Combustion Engines: Exploiting New Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes 2012 DOE Hydrogen and Fuel...

356

Light Duty Combustion Research: Advanced Light-Duty Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments 2009 DOE Hydrogen Program and...

357

Combustion synthesis continuous flow reactor  

DOE Patents [OSTI]

The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor.

Maupin, Gary D. (Richland, WA); Chick, Lawrence A. (West Richland, WA); Kurosky, Randal P. (Maple Valley, WA)

1998-01-01T23:59:59.000Z

358

Integration of a Process Waste Gas into a Site's Energy Concept  

E-Print Network [OSTI]

In 1996, the BASF Corporation's Geismar, Louisiana site determined that the increased steam demands of their aggressive investment program would require them to expand their steam generation capacity. The site had operated a gas turbine based...

Peterson, J.

359

Evaluation of high-level nuclear waste tanks having a potential flammable gas hazard  

SciTech Connect (OSTI)

In 1990 the U.S. Department of Energy declared an unreviewed safety question as a result of the behavior of tank 241-SY-101. This tank exhibited episodic releases of flammable gases that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years a considerable amount of knowledge has been gained about the chemical and physical processes that govern the behavior of tank 241-SY-101 and the other tanks associated with a potential flammable gas hazard. This paper presents an overview of the current understanding of gas generation, retention, and release and covers the results of direct sampling of the tanks to determine the gas composition and the amount of stored gas.

Johnson, G.D.; Barton, W.B.; Hill, R.C.; et al, Fluor Daniel Hanford

1997-02-14T23:59:59.000Z

360

FEMP Technology Brief: Boiler Combustion Control and Monitoring System |  

Broader source: Energy.gov (indexed) [DOE]

Boiler Combustion Control and Monitoring Boiler Combustion Control and Monitoring System FEMP Technology Brief: Boiler Combustion Control and Monitoring System October 7, 2013 - 9:12am Addthis This composite photo shows technicians observing operation at the monitoring station and making subsequent fine adjustments on combustion system controls Technical staff are making boiler adjustments with the control and monitoring system. Photo courtesy of the Department of Defense's Environmental Security Technology Certification Program. Technology Description A novel combustion control system, along with gas sensors, sets the opening of fuel and air inlets based on flue-gas concentrations. Continuous feedback from measurements of oxygen, carbon monoxide, and nitrogen oxide concentrations enable the control system

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Co-combustion of refuse derived fuel and coal in a cyclone furnace at the Baltimore Gas and Electric Company, C. P. Crane Station  

SciTech Connect (OSTI)

A co-combustion demonstration burn of coal and fluff refuse-derived fuel (RDF) was conducted by Teledyne National and Baltimore Gas and Electric Company. This utility has two B and W cyclone furnaces capable of generating 400 MW. The facility is under a prohibition order to convert from No. 6 oil to coal; as a result, it was desirable to demonstrate that RDF, which has a low sulfur content, can be burned in combination with coals containing up to 2% sulfur, thus reducing overall sulfur emissions without deleterious effects. Each furnace consists of four cyclones capable of generating 1,360,000 pounds per hour steam. The tertiary air inlet of one of the cyclones was modified with an adapter to permit fluff RDF to be pneumatically blown into the cyclone. At the same time, coal was fed into the cyclone furnace through the normal coal feeding duct, where it entered the burning chamber tangentially and mixed with the RDF during the burning process. Secondary shredded fluff RDF was prepared by the Baltimore County Resource Recovery Facility. The RDF was discharged into a receiving station consisting of a belt conveyor discharging into a lump breaker, which in turn, fed the RDF into a pneumatic line through an air-lock feeder. A total of 2316 tons were burned at an average rate of 5.6 tons per hour. The average heat replacement by RDF for the cyclone was 25%, based on Btu input for a period of forty days. The range of RDF burned was from 3 to 10 tons per hour, or 7 to 63% heat replacement. The average analysis of the RDF (39 samples) for moisture, ash, heat (HHV) and sulfur content were 18.9%, 13.4%, 6296 Btu/lb and 0.26% respectively. RDF used in the test was secondary shredded through 1-1/2 inch grates producing the particle size distribution of from 2 inches to .187 inches. Findings to date after inspection of the boiler and superheater indicate satisfactory results with no deleterious effects from the RDF.

Not Available

1982-03-01T23:59:59.000Z

362

Thermal modeling of core sampling in flammable gas waste tanks. Part 2: Rotary-mode sampling  

SciTech Connect (OSTI)

The radioactive waste stored in underground storage tanks at Hanford site includes mixtures of sodium nitrate and sodium nitrite with organic compounds. The waste can produce undesired violent exothermic reactions when heated locally during the rotary-mode sampling. Experiments are performed varying the downward force at a maximum rotational speed of 55 rpm and minimum nitrogen purge flow of 30 scfm. The rotary drill bit teeth-face temperatures are measured. The waste is simulated with a low thermal conductivity hard material, pumice blocks. A torque meter is used to determine the energy provided to the drill string. The exhaust air-chip temperature as well as drill string and drill bit temperatures and other key operating parameters were recorded. A two-dimensional thermal model is developed. The safe operating conditions were determined for normal operating conditions. A downward force of 750 at 55 rpm and 30 scfm nitrogen purge flow was found to yield acceptable substrate temperatures. The model predicted experimental results reasonably well. Therefore, it could be used to simulate abnormal conditions to develop procedures for safe operations.

Unal, C.; Poston, D.; Pasamehmetoglu, K.O. [Los Alamos National Lab., NM (United States). Nuclear Systems Design and Analysis Group; Witwer, K.S. [Westinghouse Hanford Co., Richland, WA (United States). Engineering Testing Lab.

1997-08-01T23:59:59.000Z

363

Argonne TTRDC - Engines - Combustion Visualization - emissions,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Visualization Combustion Visualization Exploring Combustion Using Advanced Imaging Techniques In the photo, the GM diesel test cell is shown with vehicle exhaust aftertreatment hardware (diesel particulate filtration and diesel oxidation catalyst) along with other advanced technology-such as a variable geometry turbocharger, cooled exhaust gas recirculation and a common-rail fuel injection system. Fig. 1. The GM diesel test cell is shown with vehicle exhaust aftertreatment hardware (diesel particulate filtration and diesel oxidation catalyst) along with other advanced technology-such as a variable geometry turbocharger, cooled exhaust gas recirculation and a common-rail fuel injection system. Two-dimensional image of hydrogen combustion OH chemiluminescence. Fig. 2. Two-dimensional image of hydrogen combustion OH chemiluminescence.

364

Rapid Deployment of Rich Catalytic Combustion  

SciTech Connect (OSTI)

The overall objective of this research under the Turbines Program is the deployment of fuel flexible rich catalytic combustion technology into high-pressure ratio industrial gas turbines. The resulting combustion systems will provide fuel flexibility for gas turbines to burn coal derived synthesis gas or natural gas and achieve NO{sub x} emissions of 2 ppmvd or less (at 15 percent O{sub 2}), cost effectively. This advance will signify a major step towards environmentally friendly electric power generation and coal-based energy independence for the United States. Under Phase 1 of the Program, Pratt & Whitney (P&W) performed a system integration study of rich catalytic combustion in a small high-pressure ratio industrial gas turbine with a silo combustion system that is easily scalable to a larger multi-chamber gas turbine system. An implementation plan for this technology also was studied. The principal achievement of the Phase 1 effort was the sizing of the catalytic module in a manner which allowed a single reactor (rather than multiple reactors) to be used by the combustion system, a conclusion regarding the amount of air that should be allocated to the reaction zone to achieve low emissions, definition of a combustion staging strategy to achieve low emissions, and mechanical integration of a Ceramic Matrix Composite (CMC) combustor liner with the catalytic module.

Richard S. Tuthill

2004-06-10T23:59:59.000Z

365

In Situ NMR Spectroscopy of Combustion  

Science Journals Connector (OSTI)

In situ nuclear magnetic resonance spectroscopy (NMR) of high-temperature reactions is of potential value for the investigation of catalytic combustion and other high-temperature applications of catalysts such as partial oxidation of hydrocarbons and steam reforming. ... Two-dimensional (2D) studies of gas exchange within different heat zones of the combustion process provide valuable insights into the gas-phase dynamics. ... This may be the case at the high combustion temperatures, but neither experimental nor theoretical xenon chemical shift data is available in current literature for temperatures above 1000 K. ...

Satyanarayana Anala; Galina E. Pavlovskaya; Prakash Pichumani; Todd J. Dieken; Michael D. Olsen; Thomas Meersmann

2003-10-07T23:59:59.000Z

366

Study of the combustion mechanism of oil shale semicoke in a thermogravimetric analyzer  

Science Journals Connector (OSTI)

Oil shale semicoke, formed in retort furnaces, is ... solid waste. For the industrial application of oil shale semicoke in combustion, this present work focused...

X. X. Han; X. M. Jiang; Z. G. Cui

2008-05-01T23:59:59.000Z

367

E-Print Network 3.0 - alternative fuels combustion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: alternative fuels combustion Page: << < 1 2 3 4 5 > >> 1 14th North American Waste to...

368

E-Print Network 3.0 - abb combustion engineering Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Research Institute Ministry of the Environment . Denmark Summary: combustion; waste incineration; dioxin abatement Layout: Ann-Katrine Holme Christoffersen ISBN: 978... and...

369

High-Temperature Components for Rankine-Cycle-Based Waste Heat...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Components for Rankine-Cycle-Based Waste Heat Recovery Systems on Combustion Engines High-Temperature Components for Rankine-Cycle-Based Waste Heat Recovery Systems on...

370

Nuclear Waste  

Science Journals Connector (OSTI)

Nuclear waste is radioactive material no longer considered valuable...238U, 235U, and 226Ra (where the latter decays to 222Rn gas by emitting an alpha particle) or formed through fission of fissile radioisotopes ...

Rob P. Rechard

2014-01-01T23:59:59.000Z

371

Modeling gas and brine migration for assessing compliance of the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

At the request of the WIPP Project Integration Office (WPIO) of the DOE, the WIPP Performance Assessment (PA) Department of Sandia National Laboratories (SNL) has completed preliminary uncertainty and sensitivity analyses of gas and brine migration away from the undisturbed repository. This paper contains descriptions of the numerical model and simulations, including model geometries and parameter values, and a summary of major conclusions from sensitivity analyses. Because significant transport of contaminants can only occur in a fluid (gas or brine) medium, two-phase flow modeling can provide an estimate of the distance to which contaminants can migrate. Migration of gas or brine beyond the RCRA ``disposal-unit boundary`` or the Standard`s accessible environment constitutes a potential, but not certain, violation and may require additional evaluations of contaminant concentrations.

Vaughn, P. [Applied Physics, Inc., Albuquerque, NM (United States); Butcher, B. [Sandia National Labs., Albuquerque, NM (United States); Helton, J. [Arizona State Univ., Tempe, AZ (United States); Swift, P. [Tech. Reps., Inc., Albuquerque, NM (United States)

1993-10-01T23:59:59.000Z

372

Recovery of Wasted Mechanical Energy from the Reduction of Natural Gas Pressure  

Science Journals Connector (OSTI)

Abstract At the present time in Romania, the transition from the natural gas transportation system to the distribution system is done only thru the use of pressure reducing stations. Here the pressure drop is usually done by using throttle valves or pressure reducing valves, where the gas energy is spent without doing any work. In this article we propose the use of turbo-expanders in the pressure reducing stations, where the natural gas pressure from the transportation grid is high and needs to drop to lower levels to enter the distribution grids, in this way part of the energy consumed in the compression stations are recovered. The plans are made at this time for a pilot project at the pressure reducing station in the city of Onesti, Bacau County.

Iancu Andrei; Tudorache Valentin; Tarean Cristina; Toma Niculae

2014-01-01T23:59:59.000Z

373

Boiler tube failures in municipal waste-to-energy plants  

SciTech Connect (OSTI)

Waste-to-energy plants experienced increased boiler tube failures when the design changed from waste-heat boilers to radiant furnace waterwalls using superheat. Fireside attack by chlorine and sulfur compounds in refuse combustion products caused many forced outages in early European plants operating at high steam temperatures and pressures. Despite conservative steam conditions in the first US plants, failures occurred. As steam temperatures increased, corrosion problems multiplied. The problems have been alleviated by covering the waterwalls with either refractory or weld overlays of nickel-based alloys and using high nickel-chromium alloys for superheater tubes. Changes in furnace design to provide uniform combustion and avoid reducing conditions in the waterwall zone and to lower the gas temperature in the superheater also have helped minimize corrosion.

Krause, H.H.; Wright, I.G. [Battelle, Columbus, OH (United States)

1996-01-01T23:59:59.000Z

374

Fluid Bed Waste Heat Boiler Operating Experience in Dirty Gas Streams  

E-Print Network [OSTI]

from 13 to 15 million BTU per hour for fired boiler efficiencies of 80% to 70% respectively. The savings represents 85 to 90% of the energy entering the waste heat boiler. Equiva lent furnace efficiency increases from 25% to over 60% on high fire... Fired Boiler Efficiency 0.70 0.75 0.80 Energy Savings Furnace Efficiency Corresponding Peak Fuel Equivalent at High (1) . Savi ngs Fire on Melt 4453 kw (15.1x10 6 BTU/hr) 69% 4156 kw (14.1x10 6 BTU/hr) 66% 3896 kw (13.3x10 6 BTU/hr) 63% (1...

Kreeger, A. H.

375

Pre-Combustion Carbon Capture Research | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-combustion capture refers to removing CO2 from fossil fuels before combustion is completed. For example, in gasification processes a feedstock (such as coal) is partially oxidized in steam and oxygen/air under high temperature and pressure to form synthesis gas. This synthesis gas, or syngas, is a mixture of hydrogen, carbon monoxide, CO2, and smaller amounts of other gaseous components, such as methane. The syngas can then undergo the water-gas shift reaction to convert CO and water (H2O) to H2 and CO2, producing a H2 and CO2-rich gas mixture. The concentration of CO2 in this mixture can range from 15-50%. The CO2 can then be captured and separated, transported, and ultimately sequestered, and the H2-rich fuel combusted.

376

Install Waste Heat Recovery Systems for Fuel-Fired Furnaces (English/Chinese) (Fact Sheet)  

SciTech Connect (OSTI)

Chinese translation of ITP fact sheet about installing Waste Heat Recovery Systems for Fuel-Fired Furnaces. For most fuel-fired heating equipment, a large amount of the heat supplied is wasted as exhaust or flue gases. In furnaces, air and fuel are mixed and burned to generate heat, some of which is transferred to the heating device and its load. When the heat transfer reaches its practical limit, the spent combustion gases are removed from the furnace via a flue or stack. At this point, these gases still hold considerable thermal energy. In many systems, this is the greatest single heat loss. The energy efficiency can often be increased by using waste heat gas recovery systems to capture and use some of the energy in the flue gas. For natural gas-based systems, the amount of heat contained in the flue gases as a percentage of the heat input in a heating system can be estimated by using Figure 1. Exhaust gas loss or waste heat depends on flue gas temperature and its mass flow, or in practical terms, excess air resulting from combustion air supply and air leakage into the furnace. The excess air can be estimated by measuring oxygen percentage in the flue gases.

Not Available

2011-10-01T23:59:59.000Z

377

Novel Process for Recycling Waste Plastics To Fuel Gas Using a Moving-Bed Reactor  

Science Journals Connector (OSTI)

National Institute of Advanced Industrial Science & Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki 305-8569, Japan ... In Japan, liquefied petroleum (LP) gas containing propane is used for domestic purposes such as cooking and home heating in nearly half of the households. ...

Yoichi Kodera; Yumiko Ishihara; Takeshi Kuroki

2005-12-02T23:59:59.000Z

378

Studies of siloxane decomposition in biomethane combustion.  

E-Print Network [OSTI]

??Biogas, which is produced from sludge biodegradation in wastewater treatment plants (WWTP), and landfill gas (LFG), which is generated from solid waste in landfills, are… (more)

Jalali, Mir Aydin

2013-01-01T23:59:59.000Z

379

Advanced Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

lead to higher efficiencies, resulting in reduced fuel consumption and lower greenhouse gas emissions. Higher efficiency also reduces CO2 production for the same amount of energy...

380

Investigation of chemical looping combustion by solid fuels. 2. redox reaction kinetics and product characterization with coal, biomass, and solid waste as solid fuels and CuO as an oxygen carrier  

SciTech Connect (OSTI)

This paper is the second in a series of two on the investigation of the chemical looping combustion (CLC) of solid fuels. The first paper put forward the concept of the CLC of solid fuels using a circulating fluidized bed as a reactor and Cu-CuO as the oxygen carrier, which was based on an analysis of oxygen transfer capability, reaction enthalpy, and chemical equilibrium. In this second paper, we report the results of the evaluation of the reduction of CuO reduced by solid fuels such as coal and some other 'opportunity' solid fuels. Tests on the reduction of CuO by the selected solid fuels were conducted using simultaneous differential scanning calorimetry and thermogravimetric analysis, which simulates a microreactor. An attached mass spectrometer (MS) was used for the characterization of evolved gaseous products. The X-ray diffractometer (XRD) and scanning electron microscope (SEM) were used for the characterization of the solid residues. Results strongly supported the feasibility of CuO reduction by selected solid fuels. CuO can be fully converted into Cu in a reduction process, either in a direct path by solid fuels, which was verified by MS analysis under a N{sub 2} atmosphere, or in an indirect path by pyrolysis and gasification products of solid fuels in the reducer. No Cu{sub 2}O exists in reducing atmospheres, which was characterized by an XRD analysis and mass balance calculations. No carbon deposit was found on the surface of the reduced Cu, which was characterized by SEM analysis. CuO reduction by solid fuels can start at temperatures as low as approximately 500 C. Tests indicated that the solid fuels with higher reactivity (higher volatile matter) would be desirable for the development of the chemical looping combustion process of solid fuels, such as sub-bituminous Powder River Basin coal and solid waste and biomass. 4 refs., 12 figs., 3 tabs.

Yan Cao; Bianca Casenas; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2006-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Ultrapyrolytic upgrading of plastic wastes and plastics/heavy oil mixtures to valuable light gas products  

SciTech Connect (OSTI)

Viable operating conditions were identified experimentally for maximizing the production of high-value products such as ethylene, propylene, styrene, and benzene, from the ultrapyrolysis of waste plastics. Using both a batch microreactor and a pilot-plant-sized reactor, the key operating variables considered were pyrolysis temperature, product reaction time, and quench time. In the microreactor experiments, polystyrene (PS), a significant component of waste plastics, was pyrolyzed at temperatures ranging from 800 to 965 C, with total reaction times ranging from 500 to 1,000 ms. At a temperature of 965 C and 500 ms, the yields of styrene plus benzene were greater than 95 wt %. In the pilot-plant experiments, the recently patented internally circulating fluidized bed (ICFB) reactor (Milne et al., US Patent Number 5,370,789, 1994b) was used to ultrapyrolyze low-density polyethylene (LDPE) in addition to LDPE (5% by weight)/heavy oil mixtures at a residence time of 600 ms. Both experiments produced light olefin yields greater than 55 wt % at temperatures above 830 C.

Lovett, S.; Berruti, F.; Behie, L.A. [Univ. of Calgary, Alberta (Canada). Dept. of Chemical and Petroleum Engineering] [Univ. of Calgary, Alberta (Canada). Dept. of Chemical and Petroleum Engineering

1997-11-01T23:59:59.000Z

382

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

1983-09-21T23:59:59.000Z

383

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA); Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA)

1985-01-01T23:59:59.000Z

384

Combustion synthesis method and products  

DOE Patents [OSTI]

Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

Holt, J.B.; Kelly, M.

1993-03-30T23:59:59.000Z

385

Combustion synthesis method and products  

DOE Patents [OSTI]

Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

Holt, J. Birch (San Jose, CA); Kelly, Michael (West Alexandria, OH)

1993-01-01T23:59:59.000Z

386

Gas-phase and catalytic combustion in heat-recirculating burners Jeongmin Ahn, Craig Eastwood, Lars Sitzki* and Paul D. Ronney  

E-Print Network [OSTI]

title: Extinction limits in excess enthalpy burners To be published in Proceedings of the Combustion that hydrocarbon fuels contain 100 times more energy per unit mass than lithium-ion batteries, thus devices engines may be impractical. Consequently, many groups have considered heat-recirculating, or "excess

387

GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS  

SciTech Connect (OSTI)

Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require ultimate disposal when it is put to use. Each task three waste was evaluated for utilization potential based on its physical properties, bulk chemical composition, and mineral composition. Only one of the thirteen materials studied might be suitable for use as a pozzolanic concrete additive. However, many wastes appeared to be suitable for other high-volume uses such as blasting grit, fine aggregate for asphalt concrete, road deicer, structural fill material, soil stabilization additives, waste stabilization additives, landfill cover material, and pavement base course construction.

Edwin S. Olson; Charles J. Moretti

1999-11-01T23:59:59.000Z

388

Waste heat recovery system for recapturing energy after engine aftertreatment systems  

SciTech Connect (OSTI)

The disclosure provides a waste heat recovery (WHR) system including a Rankine cycle (RC) subsystem for converting heat of exhaust gas from an internal combustion engine, and an internal combustion engine including the same. The WHR system includes an exhaust gas heat exchanger that is fluidly coupled downstream of an exhaust aftertreatment system and is adapted to transfer heat from the exhaust gas to a working fluid of the RC subsystem. An energy conversion device is fluidly coupled to the exhaust gas heat exchanger and is adapted to receive the vaporized working fluid and convert the energy of the transferred heat. The WHR system includes a control module adapted to control at least one parameter of the RC subsystem based on a detected aftertreatment event of a predetermined thermal management strategy of the aftertreatment system.

Ernst, Timothy C.; Nelson, Christopher R.

2014-06-17T23:59:59.000Z

389

E-Print Network 3.0 - assessing coal combustion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 44 Proceedings of NAWTEC18 18th Annual North American Waste-to-Energy Conference Summary: -to-particle conversions. In coal and waste combustion systems,...

390

COMBUSTION-ASSISTED CO2 CAPTURE USING MECC MEMBRANES  

SciTech Connect (OSTI)

Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO{sub 2} from power plant flue gas. Here a modified MECC CO{sub 2} capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO{sub 2} driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO{sub 2} in the flue gas may be captured, and a compressed CO{sub 2} product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO{sub 2} capture system, and has the potential to meet U.S. DOE's goal that deployment of a CO{sub 2} capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

Brinkman, K.; Gray, J.

2012-03-30T23:59:59.000Z

391

Combustion-Assisted CO2 Capture Using MECC Membranes  

SciTech Connect (OSTI)

Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO2 from power plant flue gas. Here a modified MECC CO2 capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO2 driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO2 in the flue gas may be captured, and a compressed CO2 product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO2 capture system, and has the potential to meet U.S. DOE s goal that deployment of a CO2 capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

Sherman, Steven R [ORNL; Gray, Dr. Joshua R. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Brinkman, Dr. Kyle S. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Huang, Dr. Kevin [University of South Carolina, Columbia

2012-01-01T23:59:59.000Z

392

Sustainable waste management in Africa through CDM projects  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer This is a compendium on GHG reductions via improved waste strategies in Africa. Black-Right-Pointing-Pointer This note provides a strategic framework for Local Authorities in Africa. Black-Right-Pointing-Pointer Assists LAs to select Zero Waste scenarios and achieve sustained GHG reduction. - Abstract: Only few Clean Development Mechanism (CDM) projects (traditionally focussed on landfill gas combustion) have been registered in Africa if compared to similar developing countries. The waste hierarchy adopted by many African countries clearly shows that waste recycling and composting projects are generally the most sustainable. This paper undertakes a sustainability assessment for practical waste treatment and disposal scenarios for Africa and makes recommendations for consideration. The appraisal in this paper demonstrates that mechanical biological treatment of waste becomes more financially attractive if established through the CDM process. Waste will continue to be dumped in Africa with increasing greenhouse gas emissions produced, unless industrialised countries (Annex 1) fund carbon emission reduction schemes through a replacement to the Kyoto Protocol. Such a replacement should calculate all of the direct and indirect carbon emission savings and seek to promote public-private partnerships through a concerted support of the informal sector.

Couth, R. [CRECHE, Centre for Research in Environmental, Coastal and Hydrological Engineering, School of Engineering, University of KwaZulu-Natal, Durban 4041 (South Africa); Trois, C., E-mail: troisc@ukzn.ac.za [CRECHE, Centre for Research in Environmental, Coastal and Hydrological Engineering, School of Engineering, University of KwaZulu-Natal, Durban 4041 (South Africa)

2012-11-15T23:59:59.000Z

393

Bioelectrochemical Integration of Waste Heat Recovery, Waste...  

Broader source: Energy.gov (indexed) [DOE]

and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes Air Products and Chemicals, Inc. - Allentown, PA A microbial reverse electrodialysis...

394

Increase of unit efficiency by improved waste heat recovery  

SciTech Connect (OSTI)

For coal-fired power plants with flue gas desulfurization by wet scrubbing and desulfurized exhaust gas discharge via cooling tower, a further improvement of new power plant efficiency is possible by exhaust gas heat recovery. The waste heat of exhaust gas is extracted in a flue gas cooler before the wet scrubber and recovered for combustion air and/or feedwater heating by either direct or indirect coupling of heat transfer. Different process configurations for heat recovery system are described and evaluated with regard to net unit improvement. For unite firing bituminous coal an increase of net unit efficiency of 0.25 to 0.7 percentage points and for lignite 0.7 to 1.6 percentage points can be realized depending on the process configurations of the heat recovery systems.

Bauer, G.; Lankes, F.

1998-07-01T23:59:59.000Z

395

Electric power generation using a phosphoric acid cell on a municipal solid waste landfill gas stream. Technology verification report, November 1997--July 1998  

SciTech Connect (OSTI)

The report gives results of tests to verify the performance of a landfill gas pretreatment unit (GPU) and a phosphoric acid fuel cell system. The complete system removes contaminants from landfill gas and produces electricity for on-site use or connection to an electric grid. Performance data were collected at two sites determined to be representative of the U.S. landfill market. The Penrose facility, in Los Angeles, CA, was the first test site. The landfill gas at this site represented waste gas recovery from four nearby landfills, consisting primarily of industrial waste material. It produced approximately 3000 scf of gas/minute, and had a higher heating value of 446 Btu/scf at about 44% methane concentration. The second test site, in Groton, CT, was a relatively small landfill, but with greater heat content gas (methane levels were about 57% and the average heating value was 585 Btu/scf). The verification test addressed contaminant removal efficiency, flare destruction efficiency, and the operational capability of the cleanup system, and the power production capability of the fuel cell system.

Masemore, S.; Piccot, S.

1998-08-01T23:59:59.000Z

396

Combustion chemistry  

SciTech Connect (OSTI)

This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

1993-12-01T23:59:59.000Z

397

On-line measurement of heat of combustion. Final report, period ended 30 April 1988  

SciTech Connect (OSTI)

An experimental method for an on-line measurement of heat of combustion of a gaseous hydrocarbon fuel mixture of unknown composition is developed. It involves combustion of a test gas with a known quantity of air to achieve a predetermined oxygen concentration level in the combustion products. This is accomplished by a feedback controller which maintains the gas volumetric flow rate at a level consistent with the desired oxygen concentration in the products. The heat of combustion is determined from a known correlation with the gas volumetric flow rate. An on-line microcomputer accesses the gas volumetric flow data, and displays the heat of combustion values at desired time intervals.

Chaturvedi, S.K.; Chegini, H.

1988-07-01T23:59:59.000Z

398

Use of combined steam-water and organic rankine cycles for achieving better efficiency of gas turbine units and internal combustion engines  

Science Journals Connector (OSTI)

Innovative concepts of recovering waste heat using low-boiling working fluids, due to which the the efficiency can be increased to 28–30%, are presented. If distributed generation of electricity or combined pr...

M. A. Gotovskiy; M. I. Grinman; V. I. Fomin; V. K. Aref’ev…

2012-03-01T23:59:59.000Z

399

Fine Particle Emissions from Combustion Systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fine Particle Emissions from Combustion Systems Fine Particle Emissions from Combustion Systems Speaker(s): Allen Robinson Date: November 11, 2005 - 12:00pm Location: 90-3122 Combustion systems such as motor vehicles and power plants are major sources of fine particulate matter. This talk describes some of the changes in fine particle emissions that occur as exhaust from combustion systems mix with background air. This mixing cools and dilutes the exhaust which influences gas-particle partitioning of semi-volatile species, the aerosol size distribution, and the fine particle mass. Dilution sampling is used to characterize fine particle emissions from combustion systems because it simulates the rapid cooling and dilution that occur as exhaust mixes with the atmosphere. Results from dilution sampler

400

Advanced Combustion Technologies | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Science & Innovation » Clean Coal » Advanced Combustion Science & Innovation » Clean Coal » Advanced Combustion Technologies Advanced Combustion Technologies Joe Yip, a researcher at FE's National Energy Technology Laboratory, uses laser-based Rayleigh light scattering to measure flame density and speed over a flat flame burner. Oxyfuel combustion, using oxygen in place of air with diluents such as steam or carbon dioxide, can reduce pollutant emissions in advanced power cycles using gas turbines. Photo courtesy of NETL Multimedia. Joe Yip, a researcher at FE's National Energy Technology Laboratory, uses laser-based Rayleigh light scattering to measure flame density and speed over a flat flame burner. Oxyfuel combustion, using oxygen in place of air with diluents such as steam or carbon dioxide, can reduce pollutant

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Develop Thermoelectric Technology for Automotive Waste Heat Recovery...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...

402

Modeling the lubrication of the piston ring pack in internal combustion engines using the deterministic method  

E-Print Network [OSTI]

Piston ring packs are used in internal combustion engines to seal both the high pressure gas in the combustion chamber and the lubricant oil in the crank case. The interaction between the piston ring pack and the cylinder ...

Chen, Haijie

2011-01-01T23:59:59.000Z

403

Paradigms in turbulent combustion research R.W. Bilgera,*, S.B. Popeb  

E-Print Network [OSTI]

at a fundamental level with the problems of combustion processes in engines (spark-igni- tion, diesel, gas then in combustion development. He cites the discovery of lead tetraethyl as an anti- knock additive after

404

E-Print Network 3.0 - adiabatic in-situ combustion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Paul D. Ronney Summary: , corresponding to low Re, H can be negative, indicating self-sustaining combustion at highly sub-adiabatic... 1 Gas-phase and catalytic combustion in...

405

Occurrence of Zinc and Lead in Aerosols and Deposits in the Fluidized-Bed Combustion of Recovered Waste Wood. Part 2: Thermodynamic Considerations  

Science Journals Connector (OSTI)

Recovered waste wood (RWW), comprising packaging materials, demolition wood, timber from building sites, and used wood from residential, industrial, and commercial activities,(1) has in recent years become a popular fuel for biofuel boilers. ... The zinc content of the fuels in the studied cases varies between 74 mg/kg of dry solids (ds) (case 2) and 2200 mg/kg of ds (case 3), ranging from minimum to average values in the reference database. ... In case 3, in which the concentration of lead in the fuel was very high and the S/Cl ratio was high (15), a molten phase (salt melt) containing PbSO4 was predicted to occur between 850 and 950 °C, while solid PbO·3(PbSO4) was predicted below 750 °C. ...

Sonja Enestam; Kari Mäkelä; Rainer Backman; Mikko Hupa

2011-04-08T23:59:59.000Z

406

Combustion Byproducts Recycling Consortium  

SciTech Connect (OSTI)

Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

2008-08-31T23:59:59.000Z

407

Combustion Byproducts Recycling Consortium  

SciTech Connect (OSTI)

Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

2008-08-31T23:59:59.000Z

408

Pyrolysis of waste tyres: A review  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Pyrolysis of waste tyres produces oil, gas and char, and recovered steel. • Batch, screw kiln, rotary kiln, vacuum and fluidised-bed are main reactor types. • Product yields are influenced by reactor type, temperature and heating rate. • Pyrolysis oils are complex and can be used as chemical feedstock or fuel. • Research into higher value products from the tyre pyrolysis process is reviewed. - Abstract: Approximately 1.5 billion tyres are produced each year which will eventually enter the waste stream representing a major potential waste and environmental problem. However, there is growing interest in pyrolysis as a technology to treat tyres to produce valuable oil, char and gas products. The most common reactors used are fixed-bed (batch), screw kiln, rotary kiln, vacuum and fluidised-bed. The key influence on the product yield, and gas and oil composition, is the type of reactor used which in turn determines the temperature and heating rate. Tyre pyrolysis oil is chemically very complex containing aliphatic, aromatic, hetero-atom and polar fractions. The fuel characteristics of the tyre oil shows that it is similar to a gas oil or light fuel oil and has been successfully combusted in test furnaces and engines. The main gases produced from the pyrolysis of waste tyres are H{sub 2}, C{sub 1}–C{sub 4} hydrocarbons, CO{sub 2}, CO and H{sub 2}S. Upgrading tyre pyrolysis products to high value products has concentrated on char upgrading to higher quality carbon black and to activated carbon. The use of catalysts to upgrade the oil to a aromatic-rich chemical feedstock or the production of hydrogen from waste tyres has also been reported. Examples of commercial and semi-commercial scale tyre pyrolysis systems show that small scale batch reactors and continuous rotary kiln reactors have been developed to commercial scale.

Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk

2013-08-15T23:59:59.000Z

409

Stretch Efficiency for Combustion Engines: Exploiting New Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

D.C. ace15daw.pdf More Documents & Publications Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes Stretch Efficiency for Combustion Engines:...

410

Fundamental Studies in Syngas Premixed Combustion Dynamics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Studies Studies in Syngas Premixed Combustion Dynamics Ahmed F. Ghoniem, Anuradha M. Annaswamy, Raymond L. Speth, H. Murat Altay Massachusetts Institute of Technology SCIES Project 05-01-SR121 Project Awarded (08/01/2005, 36 Month Duration) Needs & Objectives Gas Turbine Needs Flexibility to operate with variable syngas compositions Ensure stable operation over a wide range of conditions Reduce emissions of CO and NO x Project Objectives Study experimentally lean premixed syngas combustion

411

Development and Demonstration of Waste Heat Integration with Solvent Process for More Efficient CO2 Removal from Coal-Fired Flue Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Demonstration of and Demonstration of Waste Heat Integration with Solvent Process for More Efficient CO 2 Removal from Coal-Fired Flue Gas Background The mission of the U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) Existing Plants, Emissions, & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-

412

Numerical modelling of MILD combustion for coal  

Science Journals Connector (OSTI)

Emissions of nitrogen oxides from coal combustion are a major environmental problem because they have been shown to contribute to the formation of acid rain and photochemical smog. Moderate and Intensive Low oxygen Dilution (MILD) combustion is a promising technology for decreasing pollutant emissions and improving combustion efficiency. A combination of air preheating and fuel dilution with combustion products of low oxygen concentration are the main features of this technique. In the MILD combustion mode, preheated air and fuel are gradually mixed with large amounts of recirculated exhaust gas. The objective of the present work is to investigate the capability of present fuel NO mechanisms for pulverised coal combustion to predict the observed nitrogen oxide levels in MILD combustion mode. For this purpose, knowledge of the fate of coal nitrogen during the combustion process is vital. The interaction between turbulence and chemistry is modelled by an advanced Eddy Dissipation Concept (EDC). The NOx model is used to predict NO profiles that are compared to measurements obtained from semi-industrial scale experiments.

Ju Pyo Kim; U. Schnell; G. Scheffknecht; A.C. Benim

2007-01-01T23:59:59.000Z

413

Transforming trash: reuse as a waste management and climate change mitigation strategy  

E-Print Network [OSTI]

10: GHG emission sensitivity to landfill gas collectionfollowed by incineration, then landfill gas combustion), andthrough increased landfill gas collection; and avoided GHG

Vergara, Sintana Eugenia

2011-01-01T23:59:59.000Z

414

Code Gaps and Future Research Needs of Combustion Safety: Building America Expert Meeting Update  

Broader source: Energy.gov (indexed) [DOE]

Technical Update Meeting April 2013 Technical Update Meeting April 2013 www.buildingamerica.gov Buildings Technologies Program Code Gaps and Future Research Needs for Combustion Safety 2012 Expert Meeting Larry Brand Gas Technology Institute April 29-30, 2013 Building America Technical Update Meeting Denver, Colorado installation, inspection and testing 2. Appliance Installation: clearances to combustible materials, combustion air, and testing 3. Appliance venting: allowed materials, vent type selection, sizing, installation, and testing Fundamental Combustion Safety Related Coverage: 2 | Building America Technical Update Meeting April 2013 www.buildingamerica.gov 1. Gas piping: allowed materials, sizing, Code Coverage Three Key Provisions For Combustion Safety in the Codes 1. Combustion air

415

Comparative experimental evaluation of performance, combustion and emissions of laser ignition with conventional spark plug in a compressed natural gas fuelled single cylinder engine  

Science Journals Connector (OSTI)

Abstract Laser is emerging as a strong concept for alternative ignition in spark ignition engine. Laser ignition has potential advantages over conventional spark plug ignition. Laser ignition system is free from spark electrodes hence there is no loss of spark energy to the electrodes, which are also free from erosion effect. In addition, there is flexibility in choosing spark location and it offers excellent performance under high in-cylinder pressures. In this paper, performances of laser ignition and conventional spark ignition systems are comparatively evaluated in terms of in-cylinder pressure variation, combustion stability, fuel consumption, power output and exhaust emissions at similar operating conditions of the engine.

Dhananjay Kumar Srivastava; Avinash Kumar Agarwal

2014-01-01T23:59:59.000Z

416

Co-combustion of biomass and gaseous fuel in a novel configuration of fluidized bed: Combustion characteristics  

Science Journals Connector (OSTI)

Abstract Experimental study on co-combustion of rice straw and natural gas has been performed in a bubbling fluidized bed. The used combustor allows a novel jetting-fountain configuration and the conventional operation as well. In the jetting-fountain configuration, natural gas premixed with the air sufficient for combustion proceeds through the jet pipe to create a jet-fountain zone. Whereas only the air required for rice straw combustion passes through the gas distributor. The findings of the experiments confirm that smooth combustion of natural gas with rice straw can be performed in the novel jetting-fountain fluidized bed. This avoids acoustic effects and explosions of burning bubbles that occurs in the conventional operation. Natural gas contribution had a major impact on combustion characteristics and the performance of the combustor has been found to be much better when applying the jetting-fountain configuration. There are considerable reductions (up to 64%, 28% and 34%) in CO, \\{NOx\\} and SO2 emissions, respectively. The fixed carbon loss reduces (up to 65%) as well. Combustion efficiency records generally higher values with the jetting-fountain configuration. Combustion efficiency steadily improves with increasing natural gas contribution (up to 99.8%). Increasing bed temperature (up to 900 °C) is beneficial for reducing CO, decreasing fixed carbon loss and improving combustion efficiency. The existence of an optimum bed temperature for sulfur retention has been confirmed. As normal, \\{NOx\\} increases with bed temperature.

F. Okasha; G. Zaater; S. El-Emam; M. Awad; E. Zeidan

2014-01-01T23:59:59.000Z

417

Semi-pilot scale test for production of hydrogen-rich fuel gas from different wastes by means of a gasification and smelting process with oxygen multi-blowing  

Science Journals Connector (OSTI)

In Europe, most wastes are deposited in landfills, but a European Council directive has called for a 30% reduction of the landfill amount. Though the cement industry commonly burns waste as an alternative fuel together with fossil fuel (so-called waste co-incineration), it is necessary to reconsider this co-incineration from the viewpoints of sustainable development and cement quality. Gasification and smelting processes (GSPs) for waste can convert waste to slag and fuel gas, which can be used by the energy sector and industry, so these processes are desirable in that they provide wide social benefit. Considering its low environmental impact and good economic performance, a GSP that uses a one-process furnace and oxygen multi-blowing was tested on a semi-pilot scale (1.7 tons/day) to convert different wastes (municipal waste, plastic waste and refuse of polyvinyl chloride with a chlorine content of 48%) to slag and hydrogen-rich fuel gas. The results show that the techniques applied in this test increase the quality of the produced fuel gas, strictly control pollutants, and prolong the life of the plant. Furthermore, the tested GSP has the potential to be linked with a hydrogen-based system through its production of hydrogen-rich fuel gas.

R. Kikuchi; H. Sato; Y. Matsukura; T. Yamamoto

2005-01-01T23:59:59.000Z

418

Advanced Combustion | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Advanced Combustion Combustion engines drive a large percentage of our nation's transportation vehicles and power generation and manufacturing facilities. Today's...

419

Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings  

SciTech Connect (OSTI)

The motivation and objective of this research is to determine the role of distributed generation (DG) in greenhouse gas reductions by: (1) applying the Distributed Energy Resources Customer Adoption Model (DER-CAM); (2) using the California Commercial End-Use Survey (CEUS) database for commercial buildings; (3) selecting buildings with electric peak loads between 100 kW and 5 MW; (4) considering fuel cells, micro-turbines, internal combustion engines, gas turbines with waste heat utilization, solar thermal, and PV; (5) testing of different policy instruments, e.g. feed-in tariff or investment subsidies.

Marnay, Chris; Stadler, Michael; Lipman, Tim; Lai, Judy; Cardoso, Goncalo; Megel, Olivier

2009-09-01T23:59:59.000Z

420

Risk analysis of a biomass combustion process using MOSAR and FMEA methods  

Science Journals Connector (OSTI)

Thermal and chemical conversion processes that convert in energy the sewage sludge, pasty waste and other pre-processed waste are increasingly common, for economic and ecological reasons. Fluidized bed combustion is currently one of the most promising methods of energy conversion, since it burns biomass very efficiently, and produces only very small quantities of sulphur and nitrogen oxides. The hazards associated with biomass combustion processes are fire, explosion and poisoning from the combustion gases (CO, etc.). The risk analysis presented in this paper uses the MADS–MOSAR methodology, applied to a semi-industrial pilot scheme comprising a fluidization column, a conventional cyclone, two natural gas burners and a continuous supply of biomass. The methodology uses a generic approach, with an initial macroscopic stage where hazard sources are identified, scenarios for undesired events are recognized and ranked using a grid of Severity × Probability and safety barriers suggested. A microscopic stage then analyzes in detail the major risks identified during the first stage. This analysis may use various different tools, such as HAZOP, FMEA, etc.: our analysis is based on FMEA. Using MOSAR, we were able to identify five subsystems: the reactor (fluidized bed and centrifuge), the fuel and biomass supply lines, the operator and the environment. When we drew up scenarios based on these subsystems, we found that malfunction of the gas supply burners was a common trigger in many scenarios. Our subsequent microscopic analysis, therefore, focused on the burners, looking at the ways they failed, and at the effects and criticality of those failures (FMEA). We were, thus, able to identify a number of critical factors such as the incoming gas lines and the ignition electrode.

P.-X. Thivel; Y. Bultel; F. Delpech

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "waste combustible gas" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Brine and Gas Flow Patterns Between Excavated Areas and Disturbed Rock Zone in the 1996 Performance Assessment for the Waste Isolation Pilot Plant for a Single Drilling Intrusion that Penetrates Repository and Castile Brine Reservoir  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP), which is located in southeastern New Mexico, is being developed for the geologic disposal of transuranic (TRU) waste by the U.S. Department of Energy (DOE). Waste disposal will take place in panels excavated in a bedded salt formation approximately 2000 ft (610 m) below the land surface. The BRAGFLO computer program which solves a system of nonlinear partial differential equations for two-phase flow, was used to investigate brine and gas flow patterns in the vicinity of the repository for the 1996 WIPP performance assessment (PA). The present study examines the implications of modeling assumptions used in conjunction with BRAGFLO in the 1996 WIPP PA that affect brine and gas flow patterns involving two waste regions in the repository (i.e., a single waste panel and the remaining nine waste panels), a disturbed rock zone (DRZ) that lies just above and below these two regions, and a borehole that penetrates the single waste panel and a brine pocket below this panel. The two waste regions are separated by a panel closure. The following insights were obtained from this study. First, the impediment to flow between the two waste regions provided by the panel closure model is reduced due to the permeable and areally extensive nature of the DRZ adopted in the 1996 WIPP PA, which results in the DRZ becoming an effective pathway for gas and brine movement around the panel closures and thus between the two waste regions. Brine and gas flow between the two waste regions via the DRZ causes pressures between the two to equilibrate rapidly, with the result that processes in the intruded waste panel are not isolated from the rest of the repository. Second, the connection between intruded and unintruded waste panels provided by the DRZ increases the time required for repository pressures to equilibrate with the overlying and/or underlying units subsequent to a drilling intrusion. Third, the large and areally extensive DRZ void volumes is a significant source of brine to the repository, which is consumed in the corrosion of iron and thus contributes to increased repository pressures. Fourth, the DRZ itself lowers repository pressures by providing storage for gas and access to additional gas storage in areas of the repository. Fifth, given the pathway that the DRZ provides for gas and brine to flow around the panel closures, isolation of the waste panels by the panel closures was not essential to compliance with the U.S. Environment Protection Agency's regulations in the 1996 WIPP PA.

ECONOMY,KATHLEEN M.; HELTON,JON CRAIG; VAUGHN,PALMER

1999-10-01T23:59:59.000Z

422

TRU Waste Sampling Program: Volume I. Waste characterization  

SciTech Connect (OSTI)

Volume I of the TRU Waste Sampling Program report presents the waste characterization information obtained from sampling and characterizing various aged transuranic waste retrieved from storage at the Idaho National Engineering Laboratory and the Los Alamos National Laboratory. The data contained in this report include the results of gas sampling and gas generation, radiographic examinations, waste visual examination results, and waste compliance with the Waste Isolation Pilot Plant-Waste Acceptance Criteria (WIPP-WAC). A separate report, Volume II, contains data from the gas generation studies.

Clements, T.L. Jr.; Kudera, D.E.

1985-09-01T23:59:59.000Z

423

Burning hazardous waste in cement kilns  

SciTech Connect (OSTI)

The cement manufacturing process is one of the oldest in the world, having been in practice for over 2000 years. It is also one of the most energy intensive, with up to 65 percent of the cost of the product attributable to energy consumption. In addition to high energy demand, the process conditions include extremely high temperatures. Cement clinker forms when the correct mixture of raw materials is heated to 2650/sup 0/ F. This requires combustion temperatures exceeding 3000/sup 0/ F. under oxidizing conditions. To accomplish this, gas temperatures above 2000/sup 0/ F. occur for several seconds (typically five seconds), which is much longer than residence times in permitted hazardous waste incinerators. These conditions are extremely favorable to the destruction of organic compounds and have led to extensive investigation into the potential for burning hazardous waste in cement kilns. Cement kilns consuming hazardous wastes have been tested for air emissions under various operating conditions. The substantial body of information on the emissions and handling of hazardous wastes from these studies has demonstrated that effective destruction of wastes can be accomplished with the added benefits of energy conservation and no significant change in air emissions.

Chadbourne, J.F.; Helmsteller, A.J.

1983-06-01T23:59:59.000Z

424

Energy from waste via coal/waste co-firing  

SciTech Connect (OSTI)

The paper reviews the feasibility of waste-to-energy plants using the cocombustion of coal with refuse-derived fuels. The paper discusses the types of wastes available: municipal solid wastes, plastics, tires, biomass, and specialized industrial wastes, such as waste oils, post-consumer carpet, auto shredder residues, and petroleum coke. The five most common combustion systems used in co-firing are briefly described. They are the stoker boiler, suspension-fired boilers, cyclone furnaces, fluidized bed boilers, and cement kilns. The paper also discusses the economic incentives for generating electricity from waste.

Winslow, J.; Ekmann, J.; Smouse, S. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center; Ramezan, M. [Burns and Roe Services Corp., Pittsburgh, PA (United States); Harding, S.

1996-12-31T23:59:59.000Z

425

Mercury Capture on Fly Ash and Sorbents: The Effects of Coal Properties and Combustion Conditions  

Science Journals Connector (OSTI)

The control of mercury from coal combustion is very dependent upon the flue gas chemistry. The flue gas chemistry is a function of the time–temperature ... duct, etc. However, the flue gas chemistry, and thus mer...

Nick D. Hutson

2008-08-01T23:59:59.000Z

426

Experimental investigations on combustion characteristics of syngas composed of CH4, CO, and H2  

Science Journals Connector (OSTI)

The residual gas and remained raw gas in dual gas resources polygeneration system are quite complex in components (mainly CH4, CO, and H2...), and these results to the distinguished differences in combustion reac...

Qingwei Fan; Shien Hui; Qulan Zhou…

2010-12-01T23:59:59.000Z

427

EIA - Greenhouse Gas Emissions Overview  

Gasoline and Diesel Fuel Update (EIA)

Environment Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) Greenhouse Gas Emissions Overview Diagram Notes [a] CO2 emissions related to petroleum consumption (includes 64 MMTCO2 of non-fuel-related emissions). [b] CO2 emissions related to coal consumption (includes 0.3 MMTCO2 of non-fuel-related emissions). [c] CO2 emissions related to natural gas consumption (includes 13 MMTCO2 of non-fuel-related emissions). [d] Excludes carbon sequestered in nonfuel fossil products. [e] CO2 emissions from the plastics portion of municipal solid waste (11 MMTCO2) combusted for electricity generation and very small amounts (0.4 MMTCO2) of geothermal-related emissions.

428

Fuel gas conditioning process  

DOE Patents [OSTI]

A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

Lokhandwala, Kaaeid A. (Union City, CA)

2000-01-01T23:59:59.000Z

429

Combustion of syngas in a pressurized microturbine-like combustor: Experimental results  

Science Journals Connector (OSTI)

The different routes for power production from biomass often lead to an intermediary product such as a synthesis gas or syngas, which is typically rich in hydrogen and carbon monoxide. The simple design, fuel flexibility and size, which often matches the amount of waste energy available in industrial sites, makes microturbines an attractive solution for on-site, decentralized power generation using a limited range of alternative fuels such as synthetic gas. The properties of the synthetic fuel differ from properties of natural gas and a detailed experimental study with a separated microturbine-like pressurized combustor is therefore necessary. The present article reviews the experimental results obtained by gradually switching the fuel feed from natural gas to wet syngas in a pressurized, slightly modified lean premix microturbine combustor. Temperature profiles, pressure, emissions and flame imaging were closely monitored to detect possible problems in operability of the combustor caused by the strong difference in fuel characteristics. No problems regarding auto-ignition, dynamic or static instability were observed throughout the test-run. Temperature profiles stayed well within allowable limits and did not reveal any significant shift in flame anchoring position. The combustion of syngas during full or part load of the combustor produced remarkably low \\{NOx\\} and CO emissions. The microturbine combustor achieved stable full load combustion of syngas at the end of the test-run.

Frank Delattin; Giovanni Di Lorenzo; Sergio Rizzo; Svend Bram; Jacques De Ruyck

2010-01-01T23:59:59.000Z

430

Circulating fluidised-bed combustion  

SciTech Connect (OSTI)

Steam generators with circulating fluidized-bed combustion systems (CFBC) are characterized by a high degree of environmental comparability and a wide acceptance for FBC boiler plants involving a wide fuel spectrum which ranges from dried brown coal to high-ash coal and low-volatile bituminous coal as well as wood waste and bark. These plants incorporate a variety of CFBC systems. The choice in favor of different system options was not motivated by the inherent fuel properties but has evolved from the progressive advancement in power station FBC technology. The article elucidates several FBC system variants.

Rettemeier, W.; von der Kammer, G. (Steinmueller (L.u.C.) GmbH, Gummersbach (Germany, F.R.))

1990-01-01T23:59:59.000Z

431

Preliminary performance assessment for the Waste Isolation Pilot Plant, December 1992. Volume 5, Uncertainty and sensitivity analyses of gas and brine migration for undisturbed performance  

SciTech Connect (OSTI)

Before disposing of transuranic radioactive waste in the Waste Isolation Pilot Plant (WIPP), the United States Department of Energy (DOE) must evaluate compliance with applicable long-term regulations of the United States Environmental Protection Agency (EPA). Sandia National Laboratories is conducting iterative performance assessments (PAs) of the WIPP for the DOE to provide interim guidance while preparing for a final compliance evaluation. This volume of the 1992 PA contains results of uncertainty and sensitivity analyses with respect to migration of gas and brine from the undisturbed repository. Additional information about the 1992 PA is provided in other volumes. Volume 1 contains an overview of WIPP PA and results of a preliminary comparison with 40 CFR 191, Subpart B. Volume 2 describes the technical basis for the performance assessment, including descriptions of the linked computational models used in the Monte Carlo analyses. Volume 3 contains the reference data base and values for input parameters used in consequence and probability modeling. Volume 4 contains uncertainty and sensitivity analyses with respect to the EPA`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes (40 CFR 191, Subpart B). Finally, guidance derived from the entire 1992 PA is presented in Volume 6. Results of the 1992 uncertainty and sensitivity analyses indicate that, conditional on the modeling assumptions and the assigned parameter-value distributions, the most important parameters for which uncertainty has the potential to affect gas and brine migration from the undisturbed repository are: initial liquid saturation in the waste, anhydrite permeability, biodegradation-reaction stoichiometry, gas-generation rates for both corrosion and biodegradation under inundated conditions, and the permeability of the long-term shaft seal.

Not Available

1993-08-01T23:59:59.000Z

432

Production of methane gas from organic fraction municipal solid waste (OFMSW) via anaerobic process: application methodology for the Malaysian condition  

Science Journals Connector (OSTI)

Solid waste management in Malaysia is confronted with many problems, including low collection coverage, irregular collection services, inadequate equipment used for waste collection, crude open dumping and burning without air and water pollution control systems, inadequate legal provisions and resource constraints. These problems have various effects on the development of the solid waste management system in Malaysia. Anaerobic digestion has been suggested as an alternative method for removing high concentrations of organic waste. In this study, two types of anaerobic digesters which are Simulated Landfill Bioreactor (SLBR) and Anaerobic Solid-Liquid (ASL) reactor were proposed. The reactors were operated at a temperature 60°C, analysed for biogas production and volatile fatty acid.

Irnis Azura Zakarya; Ismail Abustan; Norli Ismail; Mohd Suffian Yusoff

2013-01-01T23:59:59.000Z

433

E-Print Network 3.0 - automotive exhaust gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ON INTERNAL COMBUSTION ENGINES 1. F. Obert, Internal Combustion Engines and Air Pollution, Intext Educational Publishers, 1973 Summary: , Critical Topics in Exhaust Gas...