National Library of Energy BETA

Sample records for waste alcohol fuels

  1. Alcohol-fuel symposium

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    A symposium was conducted on the state-of-the-art of ethanol production and use. The following topics were discussed: ethanol as a fuel for internal combustion engines; ethanol production system design; the economics of producing fuel alcohol in form size plants; alternate feedstocks for ethanol stillage as a cattle feed; high energy sorghum, ethanol versus other alternative fuels; alcohol-fuel; legal and policy issues in ethanol production; and small scale fuel alcohol production. (DMC)

  2. Fuel alcohol opportunities for Indiana

    SciTech Connect (OSTI)

    Greenglass, Bert

    1980-08-01

    Prepared at the request of US Senator Birch Bayh, Chairman of the National Alcohol Fuels Commission, this study may be best utilized as a guidebook and resource manual to foster the development of a statewide fuel alcohol plan. It examines sectors in Indiana which will impact or be impacted upon by the fuel alcohol industry. The study describes fuel alcohol technologies that could be pertinent to Indiana and also looks closely at how such a fuel alcohol industry may affect the economic and policy development of the State. Finally, the study presents options for Indiana, taking into account the national context of the developing fuel alcohol industry which, unlike many others, will be highly decentralized and more under the control of the lifeblood of our society - the agricultural community.

  3. Alcohol fuels program technical review

    SciTech Connect (OSTI)

    1981-07-01

    The last issue of the Alcohol Fuels Process R/D Newsletter contained a work breakdown structure (WBS) of the SERI Alcohol Fuels Program that stressed the subcontracted portion of the program and discussed the SERI biotechnology in-house program. This issue shows the WBS for the in-house programs and contains highlights for the remaining in-house tasks, that is, methanol production research, alcohol utilization research, and membrane research. The methanol production research activity consists of two elements: development of a pressurized oxygen gasifier and synthesis of catalytic materials to more efficiently convert synthesis gas to methanol and higher alcohols. A report is included (Finegold et al. 1981) that details the experimental apparatus and recent results obtained from the gasifier. The catalysis research is principally directed toward producing novel organometallic compounds for use as a homogeneous catalyst. The utilization research is directed toward the development of novel engine systems that use pure alcohol for fuel. Reforming methanol and ethanol catalytically to produce H/sub 2/ and CO gas for use as a fuel offers performance and efficiency advantages over burning alcohol directly as fuel in an engine. An application of this approach is also detailed at the end of this section. Another area of utilization is the use of fuel cells in transportation. In-house researchers investigating alternate electrolyte systems are exploring the direct and indirect use of alcohols in fuel cells. A workshop is being organized to explore potential applications of fuel cells in the transportation sector. The membrane research group is equipping to evaluate alcohol/water separation membranes and is also establishing cost estimation and energy utilization figures for use in alcohol plant design.

  4. Alcohol fuel from Ohio farms

    SciTech Connect (OSTI)

    Jones, J.D.

    1984-01-01

    This booklet provides an introduction to technical, marketing, and regulatory issues involved in on-farm alcohol fuel production. Discussed are ethanol production provcesses, investment, potential returns, regulations and permits, and sources of financial and technical assistance. 2 figures. (DMC)

  5. Farmstead production of fuel alcohol

    SciTech Connect (OSTI)

    Badger, P.C.; Pile, R.S.; Waddell, E.L. Jr.

    1981-01-01

    The Tennessee Valley Authority Agricultural Energy Applications Section (Muscle Shoals, AL) has designed and constructed a small-scale fuel alcohol production facility which can produce 10 gph of 190-proof alcohol. Information presented includes some factors relative to facility design, layout, and construction, plus operation and performance experiences.

  6. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Valkenburt, Corinne

    2009-05-01

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). However, biomass is not always available in sufficient quantity at a price compatible with fuels production. Municipal solid waste (MSW) on the other hand is readily available in large quantities in some communities and is considered a partially renewable feedstock. Furthermore, MSW may be available for little or no cost. This report provides a techno-economic analysis of the production of mixed alcohols from MSW and compares it to the costs for a wood based plant. In this analysis, MSW is processed into refuse derived fuel (RDF) and then gasified in a plant co-located with a landfill. The resulting syngas is then catalytically converted to mixed alcohols. At a scale of 2000 metric tons per day of RDF, and using current technology, the minimum ethanol selling price at a 10% rate of return is approximately $1.85/gallon ethanol (early 2008 $). However, favorable economics are dependent upon the toxicity characteristics of the waste streams and that a market exists for the by-product scrap metal recovered from the RDF process.

  7. Alcohol Fuels - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Fuels Alcohol Fuels Goals Advance a multiscale approach to collaborative reaction kinetic model development and validation, by focusing team efforts on particular alcohol fuels. The team's initial focus has been on n-butanol. This has recently broadened to include detailed kinetic modeling of other isomeric butanols, plus some comparisons with smaller alcohols and the corresponding ketones, aldehydes, and enols. In the future we expect to use what we have learned from the butanol study

  8. Pressure dispensable gelled alcohol fuel

    SciTech Connect (OSTI)

    Monick, J.A.

    1982-12-28

    A pressurized fuel gel composition particularly suitable for igniting wood and charcoal consisting essentially of, by weight, 42-90% of at least one c1-c6 monohydric alcohol, 0.5-6% of water-soluble gelling agent, up to about 24% water and a correlated amount of propellant from 0.5% to 30% characterized by a gel structure which forms a shape retaining mass upon contact with wood or charcoal that is maintained during the burning of said composition. Also within the scope of the invention is an aerosol product comprising said pressurized composition enclosed within a pressure-tight container having valve means for expelling the composition.

  9. Third international symposium on alcohol fuels technology

    SciTech Connect (OSTI)

    1980-04-01

    At the opening of the Symposium, Dr. Sharrah, Senior Vice President of Continental Oil Company, addressed the attendees, and his remarks are included in this volume. The Symposium was concluded by workshops which addressed specific topics. The topical titles are as follows: alcohol uses; production; environment and safety; and socio-economic. The workshops reflected a growing confidence among the attendees that the alcohols from coal, remote natural gas and biomass do offer alternatives to petroleum fuels. Further, they may, in the long run, prove to be equal or superior to the petroleum fuels when the aspects of performance, environment, health and safety are combined with the renewable aspect of the biomass derived alcohols. Although considerable activity in the production and use of alcohols is now appearing in many parts of the world, the absence of strong, broad scale assessment and support for these fuels by the United States Federal Government was a noted point of concern by the attendees. The environmental consequence of using alcohols continues to be more benign in general than the petroleum based fuels. The exception is the family of aldehydes. Although the aldehydes are easily suppressed by catalysts, it is important to understand their production in the combustion process. Progress is being made in this regard. Of course, the goal is to burn the alcohols so cleanly that catalytic equipment can be eliminated. Separate abstracts are prepared for the Energy Data Base for individual presentations.

  10. Jilin Fuel Alcohol Company Ltd | Open Energy Information

    Open Energy Info (EERE)

    Alcohol Company Ltd Jump to: navigation, search Name: Jilin Fuel Alcohol Company Ltd Place: Jilin, Jilin Province, China Zip: 132011 Product: One of the four Chinese government...

  11. Vehicle Fuel Economy Improvement through Thermoelectric Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery 2005 Diesel Engine Emissions ...

  12. Farm alcohol fuel project. Final report

    SciTech Connect (OSTI)

    Demmel, D.

    1981-11-15

    The Small Energy Project is a research and demonstration effort designed to assist small farmers in the utilization of energy conservation techniques on their farms. The Farm Alcohol Project was designed to demonstrate the production of alcohol fuels on small farms in order to reduce purchased liquid fuel requirements. The Project considered the use of on-farm raw materials for process heat and the production of fuel grade, low prood ethanol in volumes up to 10,000 gallons per year. The fuel would be used entirely on the farm. The approach considered low-cost systems the farmer could build himself from local resources. Various crops were considered for ethanol production. The interest in farm alcohol production reached a peak in 1980 and then decreased substantially as farmers learned that the process of alcohol production on the farm was much more complicated than earlier anticipated. Details of Alcohol Project experiences in ethanol production, primarily from corn, are included in this report. A one-bushel distillation plant was constructed as a learning tool to demonstrate the production of ethanol. The report discusses the various options in starch conversion, fermentation and distillation that can be utilized. The advantages and disavantages of atmospheric and the more complicated process of vacuum distillation are evaluated. Larger farm plants are considered in the report, although no experience in operating such plants was gained through the Project. Various precautions and other considerations are included for farm plant designs. A larger community portable distillery is also evaluated. Such a plant was considered for servicing farms with limited plant equipment. The farms serviced would perform only fermentation tasks, with the portable device performing distillation and starch conversion.

  13. Fuel alcohol: the road to independence

    SciTech Connect (OSTI)

    Stull, C.B.

    1982-01-01

    This report describes the production of ethanol using an on-farm fuel alcohol still. Directions are given in lay-language, easily understandable to novices in the field of fermentation. Preparation of the mash, fermentation, and distillation are discussed along with some basic background information on these processes. The design and construction of the still is presented. Off-the-shelf equipment was used in the construction. Vats, pumps, and testing equipment used in the processing are described. Diagrams and a glossary are included. The alcohol produced is used for space heating of a house and greenhouse. (DMC)

  14. Alcohol Fuels Program technical review, Spring 1984

    SciTech Connect (OSTI)

    Not Available

    1984-10-01

    The alcohol fuels program consists of in-house and subcontracted research for the conversion of lignocellulosic biomass into fuel alcohols via thermoconversion and bioconversion technologies. In the thermoconversion area, the SERI gasifier has been operated on a one-ton per day scale and produces a clean, medium-Btu gas that can be used to manufacture methanol with a relatively small gas-water shift reaction requirement. Recent research has produced catalysts that make methanol and a mixture of higher alcohols from the biomass-derived synthetic gas. Three hydrolysis processes have emerged as candidates for more focused research. They are: a high-temperature, dilute-acid, plug-flow approach based on the Dartmouth reactor; steam explosion pretreatment followed by hydrolysis using the RUT-C30 fungal organism; and direct microbial conversion of the cellulose to ethanol using bacteria in a single or mixed culture. Modeling studies, including parametric and sensitivity analyses, have recently been completed. The results of these studies will lead to a better definition of the present state-of-the-art for these processes and provide a framework for establishing the research and process engineering issues that still need resolution. In addition to these modeling studies, economic feasibility studies are being carried out by commercial engineering firms. Their results will supplement and add commercial validity to the program results. The feasibility contractors will provide input at two levels: Technical and economic assessment of the current state-of-the-art in alcohol production from lignocellulosic biomass via thermoconversion to produce methanol and higher alcohol mixtures and bioconversion to produce ethanol; and identification of research areas having the potential to significantly reduce the cost of production of alcohols.

  15. Energy-efficient alcohol-fuel production. Technical final report

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The proposed utilization schedule for the alcohol fuel plant and methane generator is to produce 180 proof ethanol during the spring, summer, and fall (April to October). The ethanol will be used in the farm tractors and trucks during the planting, growing, and harvesting seasons. Some alcohol can be stored for use during the winter. The still will not be operated during the winter (November to March) when the methane from the digester will be used to replace fuel oil for heating a swine farrowing building. There are tentative plans to develop a larger methane generator, which will utilize all of the manure (dairy, beef, horses, and swine) produced on the ISU farm. If this project is completed, there will be enough methane to produce all of the alcohol fuel needed to operate all of the farm equipment, heat the buildings, and possibly generate electricity for the farm. The methane generating system developed is working so well that there is a great deal of interest in expanding the project to where it could utilize all of the livestock waste on the farm for methane production.

  16. Demonstration of alcohol as an aviation fuel

    SciTech Connect (OSTI)

    1996-07-01

    A recently funded Southeastern Regional Biomass Energy Program (SERBEP) project with Baylor University will demonstrate the effectiveness of ethanols as an aviation fuel while providing several environmental and economic benefits. Part of this concern is caused by the petroleum industry. The basis for the petroleum industry to find an alternative aviation fuel will be dictated mainly by economic considerations. Three other facts compound the problem. First is the disposal of oil used in engines burning leaded fuel. This oil will contain too much lead to be burned in incinerators and will have to be treated as a toxic waste with relatively high disposal fees. Second, as a result of a greater demand for alkalites to be used in the automotive reformulated fuel, the costs of these components are likely to increase. Third, the Montreal Protocol will ban in 1998 the use of Ethyl-Di-Bromide, a lead scavenger used in leaded aviation fuel. Without a lead scavenger, leaded fuels cannot be used. The search for alternatives to leaded aviation fuels has been underway by different organizations for some time. As part of the search for alternatives, the Renewable Aviation Fuels Development Center (RAFDC) at Baylor University in Waco, Texas, has received a grant from the Federal Aviation Administration (FAA) to improve the efficiencies of ethanol powered aircraft engines and to test other non-petroleum alternatives to aviation fuel.

  17. Fuel Cell Power Plants Renewable and Waste Fuels

    Broader source: Energy.gov [DOE]

    Presentation by Frank Wolak, Fuel Cell Energy, at the Waste-to-Energy using Fuel Cells Workshop held Jan. 13, 2011

  18. On-farm anaerobic digester and fuel alcohol plant

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    An anaerobic digestion system was constructed and set up on a southern Illinois farm. The anaerobic digestion system was designed to be coupled with a fuel alcohol plant constructed by the farm family as part of an integrated farm energy system. The digester heating can be done using waste hot water from the alcohol plant and biogas from the digester can be used as fuel for the alcohol production. The anaerobic digestion system is made up of the following components. A hog finishing house, which already had a slotted floor and manure pit beneath it, was fitted with a system to scrape the manure into a feed slurry pit constructed at one end of the hog house. A solids handling pump feeds the manure from the feed slurry pit into the digester, a 13,000 gallon tank car body which has been insulated with styrofoam and buried underground. Another pump transfers effluent (digested manure) from the digester to a 150,000 gallon storage tank. The digested manure is then applied to cropland at appropriate times of the year. The digester temperature is maintained at the required level by automated hot water circulation through an internal heat exchanger. The biogas produced in the digester is pumped into a 32,000 gallon gas storage tank.

  19. Electrocatalyst for alcohol oxidation in fuel cells

    DOE Patents [OSTI]

    Adzic, Radoslav R.; Marinkovic, Nebojsa S.

    2001-01-01

    Binary and ternary electrocatalysts are provided for oxidizing alcohol in a fuel cell. The binary electrocatalyst includes 1) a substrate selected from the group consisting of NiWO.sub.4 or CoWO.sub.4 or a combination thereof, and 2) Group VIII noble metal catalyst supported on the substrate. The ternary electrocatalyst includes 1) a substrate as described above, and 2) a catalyst comprising Group VIII noble metal, and ruthenium oxide or molybdenum oxide or a combination thereof, said catalyst being supported on said substrate.

  20. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techno-economic Evaluation of the Production of Mixed Alcohols | Department of Energy 2: A Techno-economic Evaluation of the Production of Mixed Alcohols Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S.

  1. Comparing liquid fuel costs: grain alcohol versus sunflower oil

    SciTech Connect (OSTI)

    Reining, R.C.; Tyner, W.E.

    1983-08-01

    This paper compares the technical and economic feasibility of small-scale production of fuel grade grain alcohol with sunflower oil. Three scales of ethanol and sunflower oil production are modeled, and sensitivity analysis is conducted for various operating conditions and costs. The general conclusion is that sunflower oil costs less to produce than alcohol. Government subsidies for alcohol, but not sunflower oil, could cause adoption of more expensive alcohol in place of cheaper sunflower oil. However, neither sunflower oil nor alcohol are competitive with diesel fuel. 7 references.

  2. Office of Alcohol Fuels Program plan, FY 1981

    SciTech Connect (OSTI)

    1980-10-01

    The goal of the Office of Alcohol Fuels is to promote the production, distribution, and use of alcohol fuels. The program objectives are defined and the strategy for implementation is described. An organizational model of the operation is included. The roles of the 3 program offices and various field offices are described. (DMC)

  3. Cold-Start Performance and Emissions Behavior of Alcohol Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Using Transient Hardware-In-Loop Test Meth Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth ...

  4. Proceedings of the alcohol fuel production and utilization conference

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    A conference was held to provide farmers, businesses, industries, and specialty groups with the best available information on current and projected activities related to the production and utilization of biomass for alcohol fuels. All aspects of the alcohol fuel production and utilization process were discussed. From biomass sources, through conversion processes to end-use products and applications were topics discussed by numerous experts. Other experts took this basic information and put it together into total systems. Speakers presented overviews on alcohol fuel related activities on state, regional, and national levels. Finally, commercialization incentives, funding sources, environmental considerations, research developments, safety considerations, and regulatory requirements were discussed as factors which must be addressed when considering the production and utilization of alcohol fuels. Separate abstracts have been prepared for items within the scope of the Energy Data Base.

  5. Use of alcohol in farming applications: alternative fuels utilization program

    SciTech Connect (OSTI)

    Borman, G.L.; Foster, D.E.; Uyehara, O.A.; McCallum, P.W.; Timbario, T.J.

    1980-11-01

    The use of alcohol with diesel fuel has been investigated as a means of extending diesel fuel supplies. The ability to use ethanol in diesel-powered farm equipment could provide the means for increasing the near-term fuels self-sufficiency of the American farmer. In the longer term, the potential availability of methanol (from coal) in large quantities could serve to further decrease the dependency on diesel fuel. This document gives two separate overviews of the use of alcohols in farm equipment. Part I of this document compares alcohol with No. 1 and No. 2 diesel fuels and describes several techniques for using alcohol in farm diesels. Part II of this document discusses the use of aqueous ethanol in diesel engines, spark ignition engines and provides some information on safety and fuel handling of both methanol and ethanol. This document is not intended as a guide for converting equipment to utilize alcohol, but rather to provide information such that the reader can gain insight on the advantages and disadvantages of using alcohol in existing engines currently used in farming applications.

  6. FUEL CYCLE POTENTIAL WASTE FOR DISPOSITION

    SciTech Connect (OSTI)

    Jones, R.; Carter, J.

    2010-10-13

    The United States (U.S.) currently utilizes a once-through fuel cycle where used nuclear fuel (UNF) is stored on-site in either wet pools or in dry storage systems with ultimate disposal in a deep mined geologic repository envisioned. Within the Department of Energy's (DOE) Office of Nuclear Energy (DOE-NE), the Fuel Cycle Research and Development Program (FCR&D) develops options to the current commercial fuel cycle management strategy to enable the safe, secure, economic, and sustainable expansion of nuclear energy while minimizing proliferation risks by conducting research and development of advanced fuel cycles, including modified open and closed cycles. The safe management and disposition of used nuclear fuel and/or nuclear waste is a fundamental aspect of any nuclear fuel cycle. Yet, the routine disposal of used nuclear fuel and radioactive waste remains problematic. Advanced fuel cycles will generate different quantities and forms of waste than the current LWR fleet. This study analyzes the quantities and characteristics of potential waste forms including differing waste matrices, as a function of a variety of potential fuel cycle alternatives including: (1) Commercial UNF generated by uranium fuel light water reactors (LWR). Four once through fuel cycles analyzed in this study differ by varying the assumed expansion/contraction of nuclear power in the U.S; (2) Four alternative LWR used fuel recycling processes analyzed differ in the reprocessing method (aqueous vs. electro-chemical), complexity (Pu only or full transuranic (TRU) recovery) and waste forms generated; (3) Used Mixed Oxide (MOX) fuel derived from the recovered Pu utilizing a single reactor pass; and (4) Potential waste forms generated by the reprocessing of fuels derived from recovered TRU utilizing multiple reactor passes.

  7. FUEL CYCLE POTENTIAL WASTE FOR DISPOSITION

    SciTech Connect (OSTI)

    Carter, J.

    2011-01-03

    The United States (U.S.) currently utilizes a once-through fuel cycle where used nuclear fuel (UNF) is stored on-site in either wet pools or in dry storage systems with ultimate disposal in a deep mined geologic repository envisioned. Within the Department of Energy's (DOE) Office of Nuclear Energy (DOE-NE), the Fuel Cycle Research and Development Program (FCR&D) develops options to the current commercial fuel cycle management strategy to enable the safe, secure, economic, and sustainable expansion of nuclear energy while minimizing proliferation risks by conducting research and development of advanced fuel cycles, including modified open and closed cycles. The safe management and disposition of used nuclear fuel and/or nuclear waste is a fundamental aspect of any nuclear fuel cycle. Yet, the routine disposal of used nuclear fuel and radioactive waste remains problematic. Advanced fuel cycles will generate different quantities and forms of waste than the current LWR fleet. This study analyzes the quantities and characteristics of potential waste forms including differing waste matrices, as a function of a variety of potential fuel cycle alternatives including: (1) Commercial UNF generated by uranium fuel light water reactors (LWR). Four once through fuel cycles analyzed in this study differ by varying the assumed expansion/contraction of nuclear power in the U.S. (2) Four alternative LWR used fuel recycling processes analyzed differ in the reprocessing method (aqueous vs. electro-chemical), complexity (Pu only or full transuranic (TRU) recovery) and waste forms generated. (3) Used Mixed Oxide (MOX) fuel derived from the recovered Pu utilizing a single reactor pass. (4) Potential waste forms generated by the reprocessing of fuels derived from recovered TRU utilizing multiple reactor passes.

  8. Municipal waste to vehicle fuel

    SciTech Connect (OSTI)

    Henrich, R.A.

    1981-01-01

    The use of water as a scrubbing agent for biogas from wastewater treatment plants and landfills is described. The purified gas containing 98% CH/sub 4/ is a viable and potentially cost-effective fuel for traction. A biogas-purification process (the Binax system), delivery of the gas, quality and economics of the purified gas, the Binax design specifications, and a vehicle-conversion system to operate on gasoline or CH/sub 4/ are discussed. Biogas manufacture from wastewater-treatment plants is generally approximately 0.25 -3 cubic ft/capita-day depending on digester design and operating efficiency, solid removal efficiency (primary treatment vs. secondary treatment), and on the amount of industrial and agricultural waste flowing into the facilities. A treatment facility serving a population of 100,000 might produce 50,000-300,000 cubic ft digester gas/day.

  9. On-farm anaerobic digester and fuel-alcohol plant. Final report

    SciTech Connect (OSTI)

    Bengtson, H.H.

    1985-12-01

    An anaerobic-digestion system, coupled with a fuel-alcohol plant, was constructed and set up on a southern Illinois farm as part of an integrated farm-energy system. The digester heating can be done using waste hot water from the alcohol plant and biogas from the digester can be used as fuel for the alcohol production. The anaerobic digestion system is made up of the following components; a hog finishing house with a manure pit; a solids handling pump to feed the manure; and a 13,000-gallon railroad tank car as the main digester vessel and pump to transfer effluent from the digester to a 150,000 gallon storage tank. The digester was operated for sufficient time to demonstrate the use of hot water in an automated digester temperature control system. Sufficient biogas was produced to demonstrate the use of biogas in a converted propane boiler.

  10. Closed Fuel Cycle Waste Treatment Strategy

    SciTech Connect (OSTI)

    Vienna, J. D.; Collins, E. D.; Crum, J. V.; Ebert, W. L.; Frank, S. M.; Garn, T. G.; Gombert, D.; Jones, R.; Jubin, R. T.; Maio, V. C.; Marra, J. C.; Matyas, J.; Nenoff, T. M.; Riley, B. J.; Sevigny, G. J.; Soelberg, N. R.; Strachan, D. M.; Thallapally, P. K.; Westsik, J. H.

    2015-02-01

    This study is aimed at evaluating the existing waste management approaches for nuclear fuel cycle facilities in comparison to the objectives of implementing an advanced fuel cycle in the U.S. under current legal, regulatory, and logistical constructs. The study begins with the Global Nuclear Energy Partnership (GNEP) Integrated Waste Management Strategy (IWMS) (Gombert et al. 2008) as a general strategy and associated Waste Treatment Baseline Study (WTBS) (Gombert et al. 2007). The tenets of the IWMS are equally valid to the current waste management study. However, the flowsheet details have changed significantly from those considered under GNEP. In addition, significant additional waste management technology development has occurred since the GNEP waste management studies were performed. This study updates the information found in the WTBS, summarizes the results of more recent technology development efforts, and describes waste management approaches as they apply to a representative full recycle reprocessing flowsheet. Many of the waste management technologies discussed also apply to other potential flowsheets that involve reprocessing. These applications are occasionally discussed where the data are more readily available. The report summarizes the waste arising from aqueous reprocessing of a typical light-water reactor (LWR) fuel to separate actinides for use in fabricating metal sodium fast reactor (SFR) fuel and from electrochemical reprocessing of the metal SFR fuel to separate actinides for recycle back into the SFR in the form of metal fuel. The primary streams considered and the recommended waste forms include; Tritium in low-water cement in high integrity containers (HICs); Iodine-129: As a reference case, a glass composite material (GCM) formed by the encapsulation of the silver Mordenite (AgZ) getter material in a low-temperature glass is assumed. A number of alternatives with distinct advantages are also considered including a fused silica waste form with encapsulated nano-sized AgI crystals; Carbon-14 immobilized as a CaCO3 in a cement waste form; Krypton-85 stored as a compressed gas; An aqueous reprocessing high-level waste (HLW) raffinate waste immobilized by the vitrification process; An undissolved solids (UDS) fraction from aqueous reprocessing of LWR fuel either included in the borosilicate HLW glass or immobilized in the form of a metal alloy or titanate ceramics; Zirconium-based LWR fuel cladding hulls and stainless steel (SS) fuel assembly hardware super-compacted for disposal or purified for reuse (or disposal as low-level waste, LLW) of Zr by reactive gas separations; Electrochemical process salt HLW incorporated into a glass bonded Sodalite waste form; and Electrochemical process UDS and SS cladding hulls melted into an iron based alloy waste form. Mass and volume estimates for each of the recommended waste forms based on the source terms from a representative flowsheet are reported. In addition to the above listed primary waste streams, a range of secondary process wastes are generated by aqueous reprocessing of LWR fuel, metal SFR fuel fabrication, and electrochemical reprocessing of SFR fuel. These secondary wastes have been summarized and volumes estimated by type and classification. The important waste management data gaps and research needs have been summarized for each primary waste stream and selected waste process.

  11. Electrocatalysts for Alcohol Oxidation in Fuel Cells - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Electrocatalysts for Alcohol Oxidation in Fuel Cells Brookhaven National Laboratory Contact BNL About This Technology <p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the best commercially available catalyst for methanol oxidation.</p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the

  12. Alternative Fuels Data Center: Seattle's Waste Haulers are Going Green

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Seattle's Waste Haulers are Going Green to someone by E-mail Share Alternative Fuels Data Center: Seattle's Waste Haulers are Going Green on Facebook Tweet about Alternative Fuels Data Center: Seattle's Waste Haulers are Going Green on Twitter Bookmark Alternative Fuels Data Center: Seattle's Waste Haulers are Going Green on Google Bookmark Alternative Fuels Data Center: Seattle's Waste Haulers are Going Green on Delicious Rank Alternative Fuels Data Center: Seattle's Waste Haulers are Going

  13. Design report: small-scale fuel alcohol plant

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The objectives of the report are to (a) provide potential alcohol producers with a reference design and (b) provide a complete, demonstrated design of a small-scale fuel alcohol plant. This report describes a small-scale fuel alcohol plant designed and constructed for the DOE by EG and G Idaho, Inc., an operating contractor at the Idaho National Engineering Laboratory. The plant is reasonably complete, having the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention. Where possible, this document follows the design requirements established in the DOE publication Fuel From Farms, which was published in February 1980. For instance, critical requirements such as using corn as the primary feedstock, production of 25 gallons of 190 proof ethanol per hour, and using batch fermentation were taken from Fuel From Farms. One significant deviation is alcohol dehydration. Fuel From Farms recommends the use of a molecular sieve for dehydration, but a preliminary design raised significant questions about the cost effectiveness of this approach. A cost trade-off study is currently under way to establish the best alcohol dehydration method and will be the subject of a later report. Volume one contains background information and a general description of the plant and process.

  14. Feasibility study of fuel grade ethanol plant for Alcohol Fuels of Mississippi, Inc. , Vicksburg, Mississippi

    SciTech Connect (OSTI)

    1981-01-01

    The results are presented of a feasibility study performed to determine the technical and economic viability of constructing an alcohol plant utilizing the N.Y.U. continuous acid hydrolysis process to convert wood wastes to fuel grade alcohol. The following is a summary of the results: (1) The proposed site in the Vicksburg Industrial Foundation Corporation Industrial Park is adequate from all standpoints, for all plant capacities envisioned. (2) Local hardwood sawmills can provide adequate feedstock for the facility. The price per dry ton varies between $5 and $15. (3) Sale of fuel ethanol would be made primarily through local distributors and an adequate market exists for the plant output. (4) With minor modifications to the preparation facilities, other waste cellulose materials can also be utilized. (5) There are no anticipated major environmental, health, safety or socioeconomic risks related to the construction and operation of the proposed facility. (6) The discounted cash flow and rate of return analysis indicated that the smallest capacity unit which should be built is the 16 million gallon per year plant, utilizing cogeneration. This facility has a 3.24 year payback. (7) The 25 million gallon per year plant utilizing cogeneration is an extremely attractive venture, with a zero interest break-even point of 1.87 years, and with a discounted rate of return of 73.6%. (8) While the smaller plant capacities are unattractive from a budgetary viewpoint, a prudent policy would dictate that a one million gallon per year plant be built first, as a demonstration facility. This volume contains process flowsheets and maps of the proposed site.

  15. Modeling and cold start in alcohol-fueled engines

    SciTech Connect (OSTI)

    Markel, A.J.; Bailey, B.K.

    1998-05-01

    Neat alcohol fuels offer several benefits over conventional gasoline in automotive applications. However, their low vapor pressure and high heat of vaporization make it difficult to produce a flammable vapor composition from a neat alcohol fuel during a start under cold ambient conditions. Various methods have been introduced to compensate for this deficiency. In this study, the authors applied computer modeling and simulation to evaluate the potential of four cold-start technologies for engines fueled by near-neat alcohol. The four technologies were a rich combustor device, a partial oxidation reactor, a catalytic reformer, and an enhanced ignition system. The authors ranked the competing technologies by their ability to meet two primary criteria for cold starting an engine at {minus}25 deg C and also by several secondary parameters related to commercialization. Their analysis results suggest that of the four technologies evaluated, the enhanced ignition system is the best option for further development.

  16. Waste Stream Analyses for Nuclear Fuel Cycles

    SciTech Connect (OSTI)

    N. R. Soelberg

    2010-08-01

    A high-level study was performed in Fiscal Year 2009 for the U.S. Department of Energy (DOE) Office of Nuclear Energy (NE) Advanced Fuel Cycle Initiative (AFCI) to provide information for a range of nuclear fuel cycle options (Wigeland 2009). At that time, some fuel cycle options could not be adequately evaluated since they were not well defined and lacked sufficient information. As a result, five families of these fuel cycle options are being studied during Fiscal Year 2010 by the Systems Analysis Campaign for the DOE NE Fuel Cycle Research and Development (FCRD) program. The quality and completeness of data available to date for the fuel cycle options is insufficient to perform quantitative radioactive waste analyses using recommended metrics. This study has been limited thus far to qualitative analyses of waste streams from the candidate fuel cycle options, because quantitative data for wastes from the front end, fuel fabrication, reactor core structure, and used fuel for these options is generally not yet available.

  17. Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels

    Broader source: Energy.gov [DOE]

    Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

  18. Alcohol fuels bibliography, 1901-March 1980

    SciTech Connect (OSTI)

    Not Available

    1981-04-01

    This annotated bibliography is subdivided by subjects, as follows: general; feedstocks-general; feedstocks-sugar; feedstocks-starch; feedstocks-cellulose crops and residues; production; coproducts; economics; use as vehicle fuel; government policies; and environmental effects and safety. (MHR)

  19. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOE Patents [OSTI]

    Adzic, Radoslav; Kowal, Andrzej

    2011-11-02

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  20. DOE Hydrogen and Fuel Cell Overview: 2011 Waste-to-Energy Using Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop | Department of Energy Cell Overview: 2011 Waste-to-Energy Using Fuel Cells Workshop DOE Hydrogen and Fuel Cell Overview: 2011 Waste-to-Energy Using Fuel Cells Workshop Presentation by Sunita Satyapal, DOE Fuel Cell Technologies Program, at the Waste-to-Energy Using Fuel Cells Workshop help January 13, 2011. PDF icon DOE Hydrogen and Fuel Cell Overview More Documents & Publications Fuel Cell Technologies Program - DOD-DOE Workshop: Shipboard APUs Overview DOE Fuel Cell

  1. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology Municipal solid waste (MSW) is a domestic energy resource with the ...

  2. Transuranic Waste Burning Potential of Thorium Fuel in a Fast...

    Office of Scientific and Technical Information (OSTI)

    ... HEALTH HAZARDS; HIGH-LEVEL RADIOACTIVE WASTES; NUCLEAR FUELS; NUCLEAR INDUSTRY; RADIOACTIVE WASTE MANAGEMENT; RISK ASSESSMENT; THORIUM; THORIUM CYCLE; URANIUM 233; URANIUM 235

  3. Mixed waste paper to ethanol fuel

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  4. RADIOACTIVE WASTE STREAMS FROM VARIOUS POTENTIAL NUCLEAR FUEL...

    Office of Scientific and Technical Information (OSTI)

    FROM VARIOUS POTENTIAL NUCLEAR FUEL CYCLE OPTIONS Citation Details In-Document Search Title: RADIOACTIVE WASTE STREAMS FROM VARIOUS POTENTIAL NUCLEAR FUEL CYCLE OPTIONS Five ...

  5. Alcohol-free alkoxide process for containing nuclear waste

    DOE Patents [OSTI]

    Pope, James M.; Lahoda, Edward J.

    1984-01-01

    Disclosed is a method of containing nuclear waste. A composition is first prepared of about 25 to about 80%, calculated as SiO.sub.2, of a partially hydrolyzed silicon compound, up to about 30%, calculated as metal oxide, of a partially hydrolyzed aluminum or calcium compound, about 5 to about 20%, calculated as metal oxide, of a partially hydrolyzed boron or calcium compound, about 3 to about 25%, calculated as metal oxide, of a partially hydrolyzed sodium, potassium or lithium compound, an alcohol in a weight ratio to hydrolyzed alkoxide of about 1.5 to about 3% and sufficient water to remove at least 99% of the alcohol as an azeotrope. The azeotrope is boiled off and up to about 40%, based on solids in the product, of the nuclear waste, is mixed into the composition. The mixture is evaporated to about 25 to about 45% solids and is melted and cooled.

  6. Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa M.; Albrecht, Karl O.; Li, Jinjing; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2013-05-13

    Synthesis gas (syngas) can be used to synthesize a variety of fuels and chemicals. Domestic transportation and military operational interests have driven continued focus on domestic syngas-based fuels production. Liquid transportation fuels may be made from syngas via four basic processes: 1) higher alcohols, 2) Fischer-Tropsch (FT), 3) methanol-to-gasoline (MTG), and 4) methanol-to-olefins (MTO) and olefins-to-gasoline/distillate (MOGD). Compared to FT and higher alcohols, MTG and MTO-MOGD have received less attention in recent years. Due to the high capital cost of these synthetic fuel plants, the production cost of the finished fuel cannot compete with petroleum-derived fuel. Pacific Northwest National Laboratory has recently evaluated one way to potentially reduce capital cost and overall production cost for MTG by combining the methanol and MTG syntheses in a single reactor. The concept consists of mixing the conventional MTG catalyst (i.e. HZSM-5) with an alcohol synthesis catalyst. It was found that a methanol synthesis catalyst, stable at high temperature (i.e. Pd/ZnO/Al2O3) [1], when mixed with ZSM-5, was active for syngas conversion. Relatively high syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed as they are intermediates to the final hydrocarbon product. However, selectivity control was difficult to achieve as formation of undesirable durene and light hydrocarbons was problematic [2]. The objective of the present study was thus to evaluate other potential composite catalyst systems and optimize the reactions conditions for the conversion of syngas to hydrocarbon fuels, through the use of mixed alcohol intermediates. Mixed alcohols are of interest as they have recently been reported to produce higher yields of gasoline compared to methanol [3]. 1. Lebarbier, V.M., Dagle, R.A., Kovarik, L., Lizarazo-Adarme, J.A., King, D.L., Palo, D.R., Catalyst Science & Technology, 2012, 2, 2116-2127. 2. Zhu, Y., Jones, S.B., Biddy, M.J., Dagle, R.A., Palo, D.P., Bioresource Technology, 2012, 117, 341-351. 3. Gujar, A.C., Guda, V.K., Nolan, M., Yan W., Toghiani, H., White, M.G., Applied Catalysis A: General, 2009, 363, 115-121.

  7. Install Waste Heat Recovery Systems for Fuel-Fired Furnaces;...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Install Waste Heat Recovery Systems for Fuel-Fired Furnaces For most fuel-fired heating equipment, a large amount of the heat supplied is wasted as exhaust or flue gases. ...

  8. Design for a small-scale fuel alcohol plant

    SciTech Connect (OSTI)

    Berglund, G.R.; Richardson, J.G.

    1982-08-01

    The paper describes the small-scale fuel alcohol plant (SSFAT) which was designed as a small-scale chemical processing plant. The DOE publication, Fuel from Farms, set forth the basic design requirements. To lower operating costs, it was important that all the processes required to produce alcohol were integrated. Automated control was also an important consideration in the design to reduce the number of operators and operator time, thus reducing operating costs. Automated control also provides better quality control of the final product. The plant is presently operating in a test mode to evaluate operating characteristics. The discussion covers the following topics - design requirements; plan operations; fermentation; distillation; microprocessor control; automatic control; operating experience. 1 ref.

  9. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    SciTech Connect (OSTI)

    Blaser, Richard

    1980-11-01

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  10. Electrocatalyst for Alcohol Oxidation at Fuel Cell Anodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Alcohol Oxidation at Fuel Cell Anodes Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 (2,641 KB) <p> Scanning transmission electron micrograph showing uniform dispersion of the catalyst particles (bright spots) on the carbon support (dark background). The average particle size is about 1.5&nbsp;nm.</p> Scanning transmission electron

  11. Design for a small-scale fuel alcohol plant

    SciTech Connect (OSTI)

    Berglund, G.R.; Richardson, J.G.

    1982-08-01

    The fuel alcohol plant described in this article was designed, constructed and is being operated for the US DOE by EG and G Idaho. The plant can be operated by a single owner and produces 100 L of ethanol per hour and wet stillage for animal feed using corn as the primary feedstock. Existing technology and off-the-shelf equipment have been used whenever possible. The operation of the plant and microprocessor control of the process are described. (Refs. 1).

  12. Economic analysis of small-scale fuel alcohol plants

    SciTech Connect (OSTI)

    Schafer, J.J. Jr.

    1980-01-01

    To plan Department of Energy support programs, it is essential to understand the fundamental economics of both the large industrial size plants and the small on-farm size alcohol plants. EG and G Idaho, Inc., has designed a 25 gallon per hour anhydrous ethanol plant for the Department of Energy's Alcohol Fuels Office. This is a state-of-the-art reference plant, which will demonstrate the cost and performance of currently available equipment. The objective of this report is to examine the economics of the EG and G small-scale alcohol plant design and to determine the conditions under which a farm plant is a financially sound investment. The reference EG and G Small-Scale Plant is estimated to cost $400,000. Given the baseline conditions defined in this report, it is calculated that this plant will provide an annual after-tax of return on equity of 15%, with alcohol selling at $1.62 per gallon. It is concluded that this plant is an excellent investment in today's market, where 200 proof ethanol sells for between $1.80 and $2.00 per gallon. The baseline conditions which have a significant effect on the economics include plant design parameters, cost estimates, financial assumptions and economic forecasts. Uncertainty associated with operational variables will be eliminated when EG and G's reference plant begins operation in the fall of 1980. Plant operation will verify alcohol yield per bushel of corn, labor costs, maintenance costs, plant availability and by-product value.

  13. Fuel alcohol production from agricultural lignocellulosic feedstocks

    SciTech Connect (OSTI)

    Farina, G.E.; Barrier, J.W.; Forsythe, M.L. )

    1988-01-01

    A two-stage, low-temperature, ambient pressure, acid hydrolysis process that utilizes separate unit operations to convert hemicellulose and cellulose in agricultural residues and crops to fermentable sugars is being developed and tested. Based on the results of the bench-scale tests, an acid hydrolysis experimental plant to demonstrate the concepts of low-temperature acid hydrolysis on a much larger scale was built. Plant tests using corn stover have been conducted for more that a year and conversion efficiences have equaled those achieved in the laboratory. Laboratory tests to determine the potential for low-temperature acid hydrolysis of other feedstocks - including red clover, alfalfa, kobe lespedeza, winter rape, and rye grass - are being conducted. Where applicable, process modifications to include extraction before or after hydrolysis also are being studied. This paper describes the experimental plant and process, results obtained in the plant, results of alternative feedstocks testing in the laboratory, and a plan for an integrated system that will produce other fuels, feed, and food from crops grown on marginal land.

  14. Conversion of cellulosic wastes to liquid fuels

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-09-01

    The current status and future plans for a project to convert waste cellulosic (biomass) materials to quality liquid hydrocarbon fuels is described. The basic approach is indirect liquefaction, i.e., thermal gasification followed by catalytic liquefaction. The indirect approach results in separation of the oxygen in the biomass feedstock, i.e., oxygenated compounds do not appear in the liquid hydrocarbon fuel product. The process is capable of accepting a wide variety of feedstocks. Potential products include medium quality gas, normal propanol, diesel fuel and/or high octane gasoline. A fluidized bed pyrolysis system is used for gasification. The pyrolyzer can be fluidized with recycle pyrolysis gas, steam or recycle liquefaction system off gas or some combination thereof. Tars are removed in a wet scrubber. Unseparated pyrolysis gases are utilized as feed to a modified Fischer-Tropsch reactor. The liquid condensate from the reactor consists of a normal propanol-water phase and a paraffinic hydrocarbon phase. The reactor can be operated to optimize for either product. The following tasks were specified in the statement of work for the contract period: (1) feedstock studies; (2) gasification system optimization; (3) waste stream characterization; and (4) liquid fuels synthesis. In addition, several equipment improvements were implemented.

  15. Producing usable fuel from municipal solid waste

    SciTech Connect (OSTI)

    Ohlsson, O.O.

    1995-03-01

    Refuse disposal is a matter of increasing concern for municipalities and state governments. As existing land-fills become filled to capacity, and new landfills become more costly to site, it has become critical to develop alternative disposal methods. Some of the refuse that is presently being landfilled has the potential to provide considerable quantities of energy and thereby replace conventional fossil fuels. Another environmental concern is the problem of the emissions associated with combustion of traditional fossil fuels. The Clean Air Act Amendments of 1990 significantly restrict the level of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions permissible as effluent from combustion facilities. To address both of these concerns, Argonne National Laboratory, under sponsorship of the U.S. Department of Energy (DOE), has developed a means of producing fuel from municipal solid waste that can be co-fired with coal to supplement coal supplies and reduce problematic emissions.

  16. RADIOACTIVE WASTE STREAMS FROM VARIOUS POTENTIAL NUCLEAR FUEL CYCLE OPTIONS

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: RADIOACTIVE WASTE STREAMS FROM VARIOUS POTENTIAL NUCLEAR FUEL CYCLE OPTIONS Citation Details In-Document Search Title: RADIOACTIVE WASTE STREAMS FROM VARIOUS POTENTIAL NUCLEAR FUEL CYCLE OPTIONS Five fuel cycle options, about which little is known compared to more commonly known options, have been studied in the past year for the United States Department of Energy. These fuel cycle options, and their features relative to uranium-fueled light water

  17. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic ... Municipal solid waste (MSW) on the other hand is readily available in large quantities in ...

  18. Addendum: Tenth International Symposium on Alcohol Fuels, The road to commercialization

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    The Tenth International Symposium on ALCOHOL FUELS ``THE ROAD TO COMMERCIALIZATION`` was held at the Broadmoor Hotel, Colorado Springs, Colorado, USA November 7--10, 1993. Twenty-seven papers on the production of alcohol fuels, specifications, their use in automobiles, buses and trucks, emission control, and government policies were presented. Individual papers have been processed separately for entry into the data base.

  19. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Availability of Feedstock and Technology | Department of Energy 1: Availability of Feedstock and Technology Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology Municipal solid waste (MSW) is a domestic energy resource with the potential to provide a significant amount of energy to meet US liquid fuel requirements. MSW is defined as household waste, commercial solid waste, nonhazardous sludge, conditionally exempt, small quantity hazardous

  20. Waste-to-Energy and Fuel Cell Technologies Overview

    Broader source: Energy.gov [DOE]

    Presentation by Robert Remick, NREL, at the DOE-DOD Waste-to-Energy Using Fuel Cells Workshop held Jan. 13, 2011

  1. Automotive Fuel Efficiency Improvement via Exhaust Gas Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Electricity Automotive Fuel Efficiency Improvement via Exhaust Gas Waste Heat Conversion to Electricity Working to expand the usage of thermoelectric technology beyond seat ...

  2. Overview of fuel alcohol from agricultural crops with emphasis on the Tennessee Valley. Bulletin Y-171

    SciTech Connect (OSTI)

    Roetheli, J.C.; Pile, R.S.; Young, H.C.

    1982-02-01

    An overview is presented of the factors and concerns associated with producing fuel alcohol from agricultural crops. Areas covered include: an assessment of energy used in agriculture; a categorization of grain crop production, land suitable for energy crop production, and livestock production in the 201-county TVA region; a summary of technical and economic information on fuel alcohol production; a discussion of acreages required to produce fuel for benchmark farms in the Tennessee Valley and possible erosion impacts; and a discussion of other pertinent advantages and disadvantages of fuel alcohol production from crops.

  3. Fuel Cycle Potential Waste Inventory for Disposition Rev 5

    Broader source: Energy.gov [DOE]

    The United States (U.S.) currently utilizes a once-through fuel cycle where used nuclear fuel is stored onsite in either wet pools or in dry storage systems with ultimate disposal envisioned in a deep mined geologic repository. This report provides an estimate of potential waste inventory and waste form characteristics for the DOE UNF and HLW and a variety of commercial fuel cycle alternatives in order to support subsequent system-level evaluations of disposal system performance.

  4. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Avoidance Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel BiodieselFuelManagementBestPracticesReport.pdf

  5. PRODUCTION OF NEW BIOMASS/WASTE-CONTAINING SOLID FUELS

    SciTech Connect (OSTI)

    David J. Akers; Glenn A. Shirey; Zalman Zitron; Charles Q. Maney

    2001-04-20

    CQ Inc. and its team members (ALSTOM Power Inc., Bliss Industries, McFadden Machine Company, and industry advisors from coal-burning utilities, equipment manufacturers, and the pellet fuels industry) addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that includes both moisture reduction and pelletization or agglomeration for necessary fuel density and ease of handling. Further, this method of fuel production must be applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provide environmental benefits compared with coal. Notable accomplishments from the work performed in Phase I of this project include the development of three standard fuel formulations from mixtures of coal fines, biomass, and waste materials that can be used in existing boilers, evaluation of these composite fuels to determine their applicability to the major combustor types, development of preliminary designs and economic projections for commercial facilities producing up to 200,000 tons per year of biomass/waste-containing fuels, and the development of dewatering technologies to reduce the moisture content of high-moisture biomass and waste materials during the pelletization process.

  6. On-farm production of fuel-alcohol in Mid-America technical and economic potential

    SciTech Connect (OSTI)

    Hohmann, M.A.

    1980-03-01

    Alcohol fuel production is suggested as an alternative to high energy costs for the Mid-American farmer. The steps involved in producing alcohol from biomass are reviewed. Fermentation equipment and procedures are readily available. The utilization of by-products for animal feeds is discussed. Combustion characteristics and chemical properties of ethanol are reviewed. Estimates are made of costs involved in alcohol production in the mid-west region. Regional agricultural consumption of gasoline is estimated and 3 scenarios are developed. Benefits of on-farm fuel production are outlined. (DMC)

  7. Fact #581: July 27, 2009 Fuel Wasted in Traffic Congestion

    Broader source: Energy.gov [DOE]

    The researchers at the Texas Transportation Institute have recently published new estimates of the effects of traffic congestion. Nearly 3 billion gallons of fuel is wasted each year due to traffic...

  8. Waste-to-Energy using Fuel Cells Workshop

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's (DOE) Fuel Cell Technologies Office and the U.S. Department of Defense (DOD) held a workshop on January 13, 2011, in Washington, DC, to discuss waste-to-energy and...

  9. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, C.W.

    1998-11-03

    A method is described for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package. 6 figs.

  10. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, Charles W.

    1998-01-01

    A method for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package.

  11. Huizenga leads safety of spent fuel management, radioactive waste

    National Nuclear Security Administration (NNSA)

    management meeting in Vienna | National Nuclear Security Administration Huizenga leads safety of spent fuel management, radioactive waste management meeting in Vienna Tuesday, May 26, 2015 - 12:10pm NNSA Blog David Huizenga, NNSA's Principal Assistant Deputy Administrator for Defense Nuclear Nonproliferation, recently served as president of the Fifth Review Meeting of the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management at the

  12. Anticipating Potential Waste Acceptance Criteria for Defense Spent Nuclear Fuel

    SciTech Connect (OSTI)

    Rechard, R.P.; Lord, M.E.; Stockman, C.T.; McCurley, R.D.

    1997-12-31

    The Office of Environmental Management of the U.S. Department of Energy is responsible for the safe management and disposal of DOE owned defense spent nuclear fuel and high level waste (DSNF/DHLW). A desirable option, direct disposal of the waste in the potential repository at Yucca Mountain, depends on the final waste acceptance criteria, which will be set by DOE`s Office of Civilian Radioactive Waste Management (OCRWM). However, evolving regulations make it difficult to determine what the final acceptance criteria will be. A method of anticipating waste acceptance criteria is to gain an understanding of the DOE owned waste types and their behavior in a disposal system through a performance assessment and contrast such behavior with characteristics of commercial spent fuel. Preliminary results from such an analysis indicate that releases of 99Tc and 237Np from commercial spent fuel exceed those of the DSNF/DHLW; thus, if commercial spent fuel can meet the waste acceptance criteria, then DSNF can also meet the criteria. In large part, these results are caused by the small percentage of total activity of the DSNF in the repository (1.5%) and regulatory mass (4%), and also because commercial fuel cladding was assumed to provide no protection.

  13. Waste-to-Energy using Fuel Cells Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    using Fuel Cells Workshop Waste-to-Energy using Fuel Cells Workshop Agenda for the DOE-DOD Waste-to-Energy using Fuel Cells Workshop held Jan. 13, 2011 PDF icon ...

  14. DOE Hydrogen and Fuel Cell Overview: 2011 Waste-to-Energy Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Overview: 2011 Waste-to-Energy Using Fuel Cells Workshop DOE Hydrogen and Fuel Cell Overview: 2011 Waste-to-Energy Using Fuel Cells Workshop Presentation by Sunita Satyapal, ...

  15. Install Waste Heat Recovery Systems for Fuel-Fired Furnaces | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Waste Heat Recovery Systems for Fuel-Fired Furnaces Install Waste Heat Recovery Systems for Fuel-Fired Furnaces This tip sheet recommends installing waste heat recovery systems for fuel-fired furnaces to increase the energy efficiency of process heating systems. PROCESS HEATING TIP SHEET #8 PDF icon Install Waste Heat Recovery Systems for Fuel-Fired Furnaces (September 2005) More Documents & Publications Load Preheating Using Flue Gases from a Fuel-Fired Heating System Using Waste

  16. RADIOACTIVE WASTE STREAMS FROM VARIOUS POTENTIAL NUCLEAR FUEL CYCLE OPTIONS

    SciTech Connect (OSTI)

    Nick Soelberg; Steve Piet

    2010-11-01

    Five fuel cycle options, about which little is known compared to more commonly known options, have been studied in the past year for the United States Department of Energy. These fuel cycle options, and their features relative to uranium-fueled light water reactor (LWR)-based fuel cycles, include: Advanced once-through reactor concepts (Advanced Once-Through, or AOT) intended for high uranium utilization and long reactor operating life, use depleted uranium in some cases, and avoid or minimize used fuel reprocessing Fission-fusion hybrid (FFH) reactor concepts potential variations are intended for high uranium or thorium utilization, produce fissile material for use in power generating reactors, or transmute transuranic (TRU) and some radioactive fission product (FP) isotopes High temperature gas reactor (HTGR) concepts - intended for high uranium utilization, high reactor thermal efficiencies; they have unique fuel designs Molten salt reactor (MSR) concepts can breed fissile U-233 from Th fuel and avoid or minimize U fuel enrichment, use on-line reprocessing of the used fuel, produce lesser amounts of long-lived, highly radiotoxic TRU elements, and avoid fuel assembly fabrication Thorium/U-233 fueled LWR (Th/U-233) concepts can breed fissile U-233 from Th fuel and avoid or minimize U fuel enrichment, and produce lesser amounts of long-lived, highly radiotoxic TRU elements. These fuel cycle options could result in widely different types and amounts of used or spent fuels, spent reactor core materials, and waste streams from used fuel reprocessing, such as: Highly radioactive, high-burnup used metal, oxide, or inert matrix U and/or Th fuels, clad in Zr, steel, or composite non-metal cladding or coatings Spent radioactive-contaminated graphite, SiC, carbon-carbon-composite, metal, and Be reactor core materials Li-Be-F salts containing U, TRU, Th, and fission products Ranges of separated or un-separated activation products, fission products, and actinides. Waste forms now used or studied for used LWR fuels can be used for some of these waste streams but some waste forms may need to be developed for unique waste streams.

  17. Municipal solid waste combustion: Fuel testing and characterization

    SciTech Connect (OSTI)

    Bushnell, D.J.; Canova, J.H.; Dadkhah-Nikoo, A.

    1990-10-01

    The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

  18. Design report small-scale fuel alcohol plant. Volume II. Detailed construction information

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    The objectives of the report are to (a) provide potential alcohol producers with a reference design and (b) provide a complete, demonstrated design of a small-scale fuel alcohol plant. This report describes a small-scale fuel alcohol plant designed and constructed for the DOE by EG and G Idaho, Inc., an operating contractor at the Idaho National Engineering Laboratory. The plant is reasonably complete, having the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention. Where possible, this document follows the design requirements established in the DOE publication Fuel From Farms, which was published in February 1980. For instance, critical requirements such as using corn as the primary feedstock, production of 25 gallons of 190 proof ethanol per hour, and using batch fermentation were taken from Fuel From Farms. One significant deviation is alcohol dehydration. Fuel From Farms recommends the use of a molecular sieve for dehydration, but a preliminary design raised significant questions about the cost effectiveness of this approach. A cost trade-off study is currently under way to establish the best alcohol dehydration method and will be the subject of a later report. Volume two includes equipment and instrumentation data sheets, instrument loop wiring diagrams, and vendor lists.

  19. Waste management plan for Hanford spent nuclear fuel characterization activities

    SciTech Connect (OSTI)

    Chastain, S.A. [Westinghouse Hanford Co., Richland, WA (United States); Spinks, R.L. [Pacific Northwest Lab., Richland, WA (United States)

    1994-10-17

    A joint project was initiated between Westinghouse Hanford Company (WHC) and Pacific Northwest Laboratory (PNL) to address critical issues associated with the Spent Nuclear Fuel (SNF) stored at the Hanford Site. Recently, particular attention has been given to remediation of the SNF stored in the K Basins. A waste management plan (WMP) acceptable to both parties is required prior to the movement of selected material to the PNL facilities for examination. N Reactor and Single Pass Reactor (SPR) fuel has been stored for an extended period of time in the N Reactor, PUREX, K-East, and K-West Basins. Characterization plans call for transport of fuel material form the K Basins to the 327 Building Postirradiation Testing Laboratory (PTL) in the 300 Area for examination. However, PNL received a directive stating that no examination work will be started in PNL hot cell laboratories without an approved disposal route for all waste generated related to the activity. Thus, as part of the Characterization Program Management Plan for Hanford Spent Nuclear Fuel, a waste management plan which will ensure that wastes generated as a result of characterization activities conducted at PNL will be accepted by WHC for disposition is required. This document contains the details of the waste handling plan that utilizes, to the greatest extent possible, established waste handling and disposal practices at Hanford between PNL and WHC. Standard practices are sufficient to provides for disposal of most of the waste materials, however, special consideration must be given to the remnants of spent nuclear fuel elements following examination. Fuel element remnants will be repackaged in an acceptable container such as the single element canister and returned to the K Basins for storage.

  20. Small-scale production of alcohol fuel: not feasible for the farmer

    SciTech Connect (OSTI)

    Miles, J.D.

    1980-10-01

    On-farm alcohol fuel production is not too promising at this time because of the present state of small-scale technology and marketing and some problems with utilization. Small-scale production shows a significant decrease in yield and unacceptable water levels, which makes the cost uncompetitive with large producers. The advantages of on-farm production are that farmers can produce homegrown feedstocks and provide a reliable source of fuel for their own needs as well as an alternative market for surplus grain. Engine modifications must be made, however, in order to use either straight alcohol or combinations of alcohol with gasoline or diesel fuel. Production problems include the need for constant monitoring and temperature control, the high cost of intermittent operation, variations in grain prices, and the difficulty for many farmers of selecting appropriate equipment and complying with regulations. Cooperatives may be the answer to some of these problems. 2 tables. (DCK)

  1. Preliminary waste acceptance criteria for the ICPP spent fuel and waste management technology development program

    SciTech Connect (OSTI)

    Taylor, L.L.; Shikashio, R.

    1993-09-01

    The purpose of this document is to identify requirements to be met by the Producer/Shipper of Spent Nuclear Fuel/High-LeveL Waste SNF/HLW in order for DOE to be able to accept the packaged materials. This includes defining both standard and nonstandard waste forms.

  2. DOE-Managed High-Level Radioactive Waste and Spent Nuclear Fuel

    Office of Environmental Management (EM)

    Assessment of Disposal Options for DOE-Managed High-Level Radioactive Waste and Spent ... level radioactive waste and spent nuclear fuel in a single repository or repositories. ...

  3. Nuclear waste actinides as fissile fuel in hybrid blankets

    SciTech Connect (OSTI)

    Sahin, S.; Al-Kusayer, T.A.

    1983-12-01

    The widespread use of the present LWRs produces substantial quantities of nuclear waste materials. Among those, actinide nuclear waste poses a serious problem of stockage because the associated half life times for actinides is measured in terms of geological time periods (several millions of years) so that no waste disposal guarantee over such time intervals can be given, except for space disposal. On the other hand, these nuclear waste actinides are very good fissionable materials for high energetic (D,T) fusion neutrons. It is therefore worthwhile to investigate their quality as potential nuclear fuel in hybrid blankets. The present study investigates the neutronic performance of hybrid blankets containing Np/sup 237/ and Cm/sup 244/ as fissile materials. The isotopic composition of Americium has been adjusted to the spent fuel isotope composition of a LWR. The geometrical design has been made, according to the AYMAN fussion-fission (hybrid) experimental facility, now in the very early phase of planning.

  4. Spent fuel storage and waste management fuel cycle optimization using CAFCA

    SciTech Connect (OSTI)

    Brinton, S.; Kazimi, M.

    2013-07-01

    Spent fuel storage modeling is at the intersection of nuclear fuel cycle system dynamics and waste management policy. A model that captures the economic parameters affecting used nuclear fuel storage location options, which complements fuel cycle economic assessment has been created using CAFCA (Code for Advanced Fuel Cycles Assessment) of MIT. Research has also expanded to the study on dependency of used nuclear fuel storage economics, environmental impact, and proliferation risk. Three options of local, regional, and national storage were studied. The preliminary product of this research is the creation of a system dynamics tool known as the Waste Management Module which provides an easy to use interface for education on fuel cycle waste management economic impacts. Storage options costs can be compared to literature values with simple variation available for sensitivity study. Additionally, a first of a kind optimization scheme for the nuclear fuel cycle analysis is proposed and the applications of such an optimization are discussed. The main tradeoff for fuel cycle optimization was found to be between economics and most of the other identified metrics. (authors)

  5. Use of alcohol fuel: engine-conversion demonstration. Final report

    SciTech Connect (OSTI)

    Marsh, W.K.

    1982-01-01

    The use of ethanol as a fuel extender when mixed with gasoline, and the use of both hydrated and anhydrous ethanol as a fuel in gasoline and diesel engines are discussed. Required engine modifications for efficient use of ethanol are described, and include engine compression alterations, carburetor adjustments, and arrangement for fuel preheating. In 1981 and 1982 a demonstration of ethanol use in spark ignition engines was conducted at a major public park in South Carolina. The demonstration included a controlled road test with a pick-up truck and a demonstration of ethanol use in small, air cooled gasoline engines. One problem that was identified was that of contaminated fuel that clogged the fuel system after a few days' operation. (LEW)

  6. Evaluation of cement kiln laboratories testing hazardous waste derived fuels

    SciTech Connect (OSTI)

    Nichols, R.E.

    1998-12-31

    Cement kiln operators wishing to burn hazardous waste derived fuels in their kilns must submit applications for Resource Conservation Recovery Act permits. One component of each permit application is a site-specific Waste Analysis Plan. These Plans describe the facilities` sampling and analysis procedures for hazardous waste derived fuels prior to receipt and burn. The Environmental Protection Agency has conducted on-site evaluations of several cement kiln facilities that were under consideration for Resource Conservation Recovery Act permits. The purpose of these evaluations was to determine if the on-site sampling and laboratory operations at each facility complied with their site-specific Waste Analysis Plans. These evaluations covered sampling, laboratory, and recordkeeping procedures. Although all the evaluated facilities were generally competent, the results of those evaluations revealed opportunities for improvement at each facility. Many findings were noted for more than one facility. This paper will discuss these findings, particularly those shared by several facilities (specific facilities will not be identified). Among the findings to be discussed are the ways that oxygen bombs were scrubbed and rinsed, the analytical quality control used, Burn Tank sampling, and the analysis of pH in hazardous waste derived fuels.

  7. Design report small-scale fuel alcohol palnt. Volume III. Drawings

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    The objectives of the report are to (a) provide potential alcohol producers with a reference design and (b) provide a complete, demonstrated design of small-scale fuel alcohol plant. This report describes a small-scale fuel alcohol plant designed and constructed for the DOE by EG and G Idaho, Inc., an operating contractor at the Idaho National Engineering Laboratory. The plant is reasonably complete, having the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention. Where possible, this document follows the design requirements established in the DOE publication Fuel From Farms, which was published in February 1980. For instance, critical requirements such as using corn as the primary feedstock, production of 25 gallons of 190 proof ethanol per hour, and using batch fermentation were taken from Fuel From Farms. One significant deviation is alcohol dehydration. Fuel From Farms recommends the use of a molecular sieve for dehydration, but a preliminary design raised significant questions about the cost effectiveness of this approach. A cost trade-off study is currently under way to establish the best alcohol dehydration method and will be the subject of a later report. This volume contains the equipment and construction drawings used to build the small-scale ethanol plant. The design in this volume represents the design at completion of construction and before continuous production began.

  8. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  9. Recycled waste oil: A fuel for medium speed diesel engines?

    SciTech Connect (OSTI)

    Cheng, A.B.L.; Poynton, W.A.; Howard, J.G.

    1996-12-31

    This paper describes the exploratory engine trials that Mirrlees Blackstone has undertaken to investigate the effect of fueling an engine using waste oil derived from used lubricants. The effect on the engine`s mechanical components, and thermal performance are examined, and the steps taken to overcome problems are discussed. The proposed engine is sited within the Research and Development facilities, housed separately from the manufacturing plant. The unit is already capable of operating on two different types of fuel with single engine set up. It is a 3 cylinder, 4-stroke turbocharged direct injection engine mounted on an underbase and it operates at 600 rpm, 15.0 bar B.M.E.P. (Brake Mean Effective Pressure). It is a mature engine, built {approximately} 20 years previously, and used for emergency stand-by duties in the company`s powerhouse. The test engine is coupled to an alternator and the electricity generated is fed to the national grid. Initial samples of treated fuel oil, analyzed by an independent oil analysis consultant, indicated that the fuel oil does not correspond to a normal fuel oil. They contained high concentrations of trace elements (i.e. calcium, phosphorus, lead, aluminum and silicon) which was consistent with sourcing from waste lubricating oils. The fuel oil was considered to be too severe for use in an engine.

  10. Analysis of vehicle fuel release resulting in waste tank fire

    SciTech Connect (OSTI)

    STEPHENS, L.S.

    2003-03-21

    This document reevaluates several aspects of the in-tank vehicle fuel fire/deflagration accident formally documented as an independent accident (representative accident [rep acc] 2). This reevaluation includes frequencies for the accidents and incorporates the behavior of gasoline and diesel fuel in more detail than previous analysis. This reevaluation uses data from RPP-13121, ''Historical Summary of Occurrences from the Tank Farm Safety Analysis Report'', Table B-1, ''Tank Farm Events, Off-Normal and Critiques,'' and B-2, ''Summary of Occurrences,'' and from the River Protection Project--Occurrence Reporting & Processing System (ORPS) reports as a basis for changing some of the conclusions formally reported in HNF-SD-WM-CN-037, ''Frequency Analysis of Vehicle Fuel Releases Resulting in Waste Tank Fire''. This calculation note will demonstrate that the in-tank vehicle fuel fire/deflagration accident event may be relocated to other, more bounding accidents.

  11. Spent Fuel and High-Level Radioactive Waste Transportation Report

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by SSEB in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educated layman with little or no background in nuclear waste Issues. In addition. this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages will be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.

  12. Spent fuel and high-level radioactive waste transportation report

    SciTech Connect (OSTI)

    Not Available

    1989-11-01

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by the Southern States Energy Board (SSEB) in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educated layman with little or no background in nuclear waste issues. In addition, this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages sew be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.

  13. Spent fuel and high-level radioactive waste transportation report

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by the Southern States Energy Board (SSEB) in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educated layman with little or no background in nuclear waste issues. In addition, this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages will be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.

  14. APEX nuclear fuel cycle for production of LWR fuel and elimination of radioactive waste

    SciTech Connect (OSTI)

    Steinberg, M.; Powell, J.R.

    1981-08-01

    The development of a nuclear fission fuel cycle is proposed which eliminates all the radioactive fission product waste effluent and the need for geological-age high level waste storage and provides a long term supply of fissile fuel for an LWR power reactor economy. The fuel cycle consists of reprocessing LWR spent fuel (1 to 2 years old) to remove the stable nonradioactive (NRFP, e.g. lanthanides, etc.) and short-lived fission products (SLFP e.g. half-lives of (1 to 2 years) and returning, in dilute form, the long-lived fission products, ((LLFPs, e.g. 30 y half-life Cs, Sr, and 10 y Kr, and 16 x 10/sup 6/ y I) and the transuranics (TUs, e.g. Pu, Am, Cm, and Np) to be refabricated into fresh fuel elements. Makeup fertile and fissile fuel are to be supplied through the use of a Spallator (linear accelerator spallation-target fuel-producer). The reprocessing of LWR fuel elements is to be performed by means of the Chelox process which consists of Airox treatment (air oxidation and hydrogen reduction) followed by chelation with an organic reagent (..beta..-diketonate) and vapor distillation of the organometallic compounds for separation and partitioning of the fission products.

  15. Apex nuclear fuel cycle for production of light water reactor fuel and elimination of radioactive waste

    SciTech Connect (OSTI)

    Steinberg, M.; Hiroshi, T.; Powell, J.R.

    1982-09-01

    The development of a nuclear fission fuel cycle is proposed that eliminates all the radioactive fission product (FP) waste effluent and the need for geological age high-level waste storage and provides a longterm supply of fissile fuel for a light water reactor (LWR) economy. The fuel cycle consists of reprocessing LWR spent fuel (1 to 2 yr old) to remove the stable nonradioactive FPs (NRFPs) e.g., lanthanides, etc.) and short-lived FPs (SLFP) (e.g., half-lives of less than or equal to 1 to 2 yr) and returning, in dilute form, the long-lived FPs (LLFPs) (e.g., 30-yr half-life cesium and strontium, 10-yr krypton, and 16 X 10/sup 6/-yr iodine) and the transuranics (TUs) (e.g., plutonium, americium, curium, and neptunium) to be refabricated into fresh fuel elements. Makeup fertile and fissile fuel (FF) are to be supplied through the use of the spallator (linear accelerator spallation-target fuel producer). The reprocessing of LWR fuel elements is to be performed by means of the chelox process, which consists of chopping and leaching with an organic chelating reagent (..beta..-diketonate) and distillation of the organometallic compounds formed for purposes of separating and partitioning the FPs. The stable NRFPs and SLFPs are allowed to decay to background in 10 to 20 yr for final disposal to the environment.

  16. Alcohol as a fuel for farm and construction equipment

    SciTech Connect (OSTI)

    Borman, G L; Foster, D E; Meyers, P S; Uyehara, O A

    1982-06-01

    Work in three areas dealing with the utilization of ethanol as fuel for farm and construction diesels is summarized. The first part is a review of what is known about the retrofitting of diesels for use of ethanol and the combustion problems involved. The second part is a discussion of the work that has been done under the contract on the performance of a single-cylinder, open-chamber diesel using solutions and emulsions of diesel fuel with ethanol. Data taken include performance, emissions and cylinder pressure-time for diesel fuel with zero to forty percent ethanol by volume. Analysis of the data includes calculation of heat release rates using a single zone model. The third part is a discussion of work done retrofitting a multicylinder turbocharged farm tractor diesel to use ethanol by fumigation. Three methods of ethanol introduction are discussed; spraying ethanol upstream and downstream of the compressor and prevaporization of the ethanol. Data on performance and emissions are given for the last two methods. A three zone heat release model is described and results from the model are given. A correlation of the ignition delay using prevaporized ethanol fumigation data is also given. Comparisons are made between fumigation in DI and IDI engines.

  17. Process for recovery of palladium from nuclear fuel reprocessing wastes

    DOE Patents [OSTI]

    Campbell, David O.; Buxton, Samuel R.

    1981-01-01

    Palladium is selectively removed from spent nuclear fuel reprocessing waste by adding sugar to a strong nitric acid solution of the waste to partially denitrate the solution and cause formation of an insoluble palladium compound. The process includes the steps of: (a) adjusting the nitric acid content of the starting solution to about 10 M, (b) adding 50% sucrose solution in an amount sufficient to effect the precipitation of the palladium compound, (c) heating the solution at reflux temperature until precipitation is complete, and (d) centrifuging the solution to separate the precipitated palladium compound from the supernatant liquid.

  18. Process for recovery of palladium from nuclear fuel reprocessing wastes

    DOE Patents [OSTI]

    Campbell, D.O.; Buxton, S.R.

    1980-06-16

    Palladium is selectively removed from spent nuclear fuel reprocessing waste by adding sugar to a strong nitric acid solution of the waste to partially denitrate the solution and cause formation of an insoluble palladium compound. The process includes the steps of: (a) adjusting the nitric acid content of the starting solution to about 10 M; (b) adding 50% sucrose solution in an amount sufficient to effect the precipitation of the palladium compound; (c) heating the solution at reflux temperature until precipitation is complete; and (d) centrifuging the solution to separate the precipitated palladium compound from the supernatant liquid.

  19. Turning Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Game | Department of Energy Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean Energy Game Turning Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean Energy Game February 9, 2011 - 1:40pm Addthis Turning Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean Energy Game Paul Bryan Biomass Program Manager, Office of Energy Efficiency & Renewable Energy How does it work? Vegetative and agricultural waste reacts with oxygen to produce synthesis

  20. Municipal solid waste generation in municipalities: Quantifying impacts of household structure, commercial waste and domestic fuel

    SciTech Connect (OSTI)

    Lebersorger, S.; Beigl, P.

    2011-09-15

    Waste management planning requires reliable data concerning waste generation, influencing factors on waste generation and forecasts of waste quantities based on facts. This paper aims at identifying and quantifying differences between different municipalities' municipal solid waste (MSW) collection quantities based on data from waste management and on socio-economic indicators. A large set of 116 indicators from 542 municipalities in the Province of Styria was investigated. The resulting regression model included municipal tax revenue per capita, household size and the percentage of buildings with solid fuel heating systems. The model explains 74.3% of the MSW variation and the model assumptions are met. Other factors such as tourism, home composting or age distribution of the population did not significantly improve the model. According to the model, 21% of MSW collected in Styria was commercial waste and 18% of the generated MSW was burned in domestic heating systems. While the percentage of commercial waste is consistent with literature data, practically no literature data are available for the quantity of MSW burned, which seems to be overestimated by the model. The resulting regression model was used as basis for a waste prognosis model (Beigl and Lebersorger, in preparation).

  1. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, James P.; Scahill, John W.; Chum, Helena L.; Evans, Robert J.; Rejai, Bahman; Bain, Richard L.; Overend, Ralph P.

    1996-01-01

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  2. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

    1996-04-02

    A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

  3. Energy Supply- Production of Fuel from Agricultural and Animal Waste

    SciTech Connect (OSTI)

    Gabriel Miller

    2009-03-25

    The Society for Energy and Environmental Research (SEER) was funded in March 2004 by the Department of Energy, under grant DE-FG-36-04GO14268, to produce a study, and oversee construction and implementation, for the thermo-chemical production of fuel from agricultural and animal waste. The grant focuses on the Changing World Technologies (CWT) of West Hempstead, NY, thermal conversion process (TCP), which converts animal residues and industrial food processing biproducts into fuels, and as an additional product, fertilizers. A commercial plant was designed and built by CWT, partially using grant funds, in Carthage, Missouri, to process animal residues from a nearby turkey processing plant. The DOE sponsored program consisted of four tasks. These were: Task 1 Optimization of the CWT Plant in Carthage - This task focused on advancing and optimizing the process plant operated by CWT that converts organic waste to fuel and energy. Task 2 Characterize and Validate Fuels Produced by CWT - This task focused on testing of bio-derived hydrocarbon fuels from the Carthage plant in power generating equipment to determine the regulatory compliance of emissions and overall performance of the fuel. Task 3 Characterize Mixed Waste Streams - This task focused on studies performed at Princeton University to better characterize mixed waste incoming streams from animal and vegetable residues. Task 4 Fundamental Research in Waste Processing Technologies - This task focused on studies performed at the Massachusetts Institute of Technology (MIT) on the chemical reformation reaction of agricultural biomass compounds in a hydrothermal medium. Many of the challenges to optimize, improve and perfect the technology, equipment and processes in order to provide an economically viable means of creating sustainable energy were identified in the DOE Stage Gate Review, whose summary report was issued on July 30, 2004. This summary report appears herein as Appendix 1, and the findings of the report formed the basis for much of the subsequent work under the grant. An explanation of the process is presented as well as the completed work on the four tasks.

  4. Biogas and alcohol fuels production. Proceedings of the Seminar on Biomass, Energy for City, Farm, and Industry, Chicago, IL, October 25, 26, 1979

    SciTech Connect (OSTI)

    Goldstein, J.

    1980-01-01

    Basic principles of anaerobic digestion are considered along with the status of the Imperial Valley Biogas Project, the Department of Energy program for the recovery of energy and materials from urban waste, the principles of alcohol production from wastes, the mechanical recovery of a refuse-derived cellulosic feedstock for ethanol production, and the production of ethanol from cellulosic biomass. Attention is given to on-farm alcohol fuel production, the current status and future role of gasohol production, methane generation from small scale farms, farmsite installations of energy harvester anaerobic digesters, biogas/composting and landfill recovery, farm-scale composting as an option to anaerobic digestion, designing a high-quality biogas system, and methane as fuel of the future. A description is presented of subjects which are related to landfill gas recovery, biogas purification with permselective membranes, and anaerobic digestion of marine biomass. Other topics studied include the application of biogas technology in India, biogas production in China, biogasification of organic wastes in the Republic of the Philippines, and economics and operational experience of full-scale anaerobic dairy manure digester.

  5. Liquid Fuel From Renewable Electricity and Bacteria: Electro-Autotrophic Synthesis of Higher Alcohols

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: UCLA is utilizing renewable electricity to power direct liquid fuel production in genetically engineered Ralstonia eutropha bacteria. UCLA is using renewable electricity to convert carbon dioxide into formic acid, a liquid soluble compound that delivers both carbon and energy to the bacteria. The bacteriaare genetically engineered to convert the formic acid into liquid fuelin this case alcohols such as butanol. The electricity required for the process can be generated from sunlight, wind, or other renewable energy sources. In fact, UCLAs electricity-to-fuel system could be a more efficient way to utilize these renewable energy sources considering the energy density of liquid fuel is much higher than the energy density of other renewable energy storage options, such as batteries.

  6. National briefing summaries: Nuclear fuel cycle and waste management

    SciTech Connect (OSTI)

    Schneider, K.J.; Bradley, D.J.; Fletcher, J.F.; Konzek, G.J.; Lakey, L.T.; Mitchell, S.J.; Molton, P.M.; Nightingale, R.E.

    1991-04-01

    Since 1976, the International Program Support Office (IPSO) at the Pacific Northwest Laboratory (PNL) has collected and compiled publicly available information concerning foreign and international radioactive waste management programs. This National Briefing Summaries is a printout of an electronic database that has been compiled and is maintained by the IPSO staff. The database contains current information concerning the radioactive waste management programs (with supporting information on nuclear power and the nuclear fuel cycle) of most of the nations (except eastern European countries) that now have or are contemplating nuclear power, and of the multinational agencies that are active in radioactive waste management. Information in this document is included for three additional countries (China, Mexico, and USSR) compared to the prior issue. The database and this document were developed in response to needs of the US Department of Energy.

  7. Small-scale fuel alcohol production. Technical report

    SciTech Connect (OSTI)

    Not Available

    1980-03-01

    This report describes in substantial detail technical and economic aspects of small-scale ethanol production from on-farm units producing up to 360,000 gallons per year and community plants producing up to 2 million gallons per year. The description of feedstock materials is limited to those containing starches and sugars, not cellulosic materials. Factors influencing the introduction of small-scale ethanol production are evaluated, including the availability and technical capabilities of production equipment. Also discussed are the types and sizes of farms and community operations for which ethanol production is appropriate. The report describes the characteristics of ethanol and its use as a motor fuel, the production and use of co-products, and problems typically encountered by small-scale producers. Information on investment, operation, maintenance and feedstock costs is estimated and analyzed. A sensitivity analysis describes changes in the cost of ethanol production resulting from changes in the major cost elements.

  8. TVA application of integrated onfarm fuel alcohol production system. Annual report

    SciTech Connect (OSTI)

    Badger, P C; Pile, R S

    1980-01-01

    This contract has provided for the documentation of the feasibility of fuel alcohol production with small onfarm facilities, and for the design and construction of an efficient and easily constructed production facility. A feasibility study and a preliminary design report have been prepared. A prototype facility has been designed and constructed with a design production rate of 10 gallons per hour of 190-proof ethanol. The components of the facility are readily available through normal equipment supply channels or can be primarily owner-constructed. Energy efficiency was also of prime consideration in the design, and heat recovery equipment is included where practical. A renewable fuel boiler is used for process heat. Applicable safety standards and environmental requirements were also incorporated into the design. Other project activities included modification of a pickup truck to use the hydrous alcohol produced, evaluation of vacuum distillation for onfarm units, and development of a computer program to allow detailed economic analyses of fuel alcohol production. Efforts were also initiated to evaluate nongrain feedstocks, develop a preliminary design for a low-cost wood-fired boiler, and evaluate packed distillation columns constructed of plastic pipe.

  9. Waste-to-Energy using Fuel Cells Webinar | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Webinar Waste-to-Energy using Fuel Cells Webinar The U.S. Department of Energy's (DOE) Fuel Cell Technologies Office and the U.S. Department of Defense (DOD) held a webinar on July 13, 2011, in Washington, DC, to discuss waste-to-energy for fuel cell applications. Presentations DOD-DOE MOU WTE Using Fuel Cells Briefing, Pete Devlin, Market Transformation and Intergovernmental Coordination Manager, Fuel Cell Technologies Office Net Zero Pilot - Training, Stephen Cosper, Environmental Engineer,

  10. Alcohol-fueled vehicles: An alternative fuels vehicle, emissions, and refueling infrastructure technology assessment

    SciTech Connect (OSTI)

    McCoy, G.A.; Kerstetter, J.; Lyons, J.K.

    1993-06-01

    Interest in alternative motor vehicle fuels has grown tremendously over the last few years. The 1990 Clean Air Act Amendments, the National Energy Policy Act of 1992 and the California Clean Air Act are primarily responsible for this resurgence and have spurred both the motor fuels and vehicle manufacturing industries into action. For the first time, all three U.S. auto manufacturers are offering alternative fuel vehicles to the motoring public. At the same time, a small but growing alternative fuels refueling infrastructure is beginning to develop across the country. Although the recent growth in alternative motor fuels use is impressive, their market niche is still being defined. Environmental regulations, a key driver behind alternative fuel use, is forcing both car makers and the petroleum industry to clean up their products. As a result, alternative fuels no longer have a lock on the clean air market and will have to compete with conventional vehicles in meeting stringent future vehicle emission standards. The development of cleaner burning gasoline powered vehicles has signaled a shift in the marketing of alternative fuels. While they will continue to play a major part in the clean vehicle market, alternative fuels are increasingly recognized as a means to reduce oil imports. This new role is clearly defined in the National Energy Policy Act of 1992. The Act identifies alternative fuels as a key strategy for reducing imports of foreign oil and mandates their use for federal and state fleets, while reserving the right to require private and municipal fleet use as well.

  11. Waste Classification based on Waste Form Heat Generation in Advanced Nuclear Fuel Cycles Using the Fuel-Cycle Integration and Tradeoffs (FIT) Model

    SciTech Connect (OSTI)

    Denia Djokic; Steven J. Piet; Layne F. Pincock; Nick R. Soelberg

    2013-02-01

    This study explores the impact of wastes generated from potential future fuel cycles and the issues presented by classifying these under current classification criteria, and discusses the possibility of a comprehensive and consistent characteristics-based classification framework based on new waste streams created from advanced fuel cycles. A static mass flow model, Fuel-Cycle Integration and Tradeoffs (FIT), was used to calculate the composition of waste streams resulting from different nuclear fuel cycle choices. This analysis focuses on the impact of waste form heat load on waste classification practices, although classifying by metrics of radiotoxicity, mass, and volume is also possible. The value of separation of heat-generating fission products and actinides in different fuel cycles is discussed. It was shown that the benefits of reducing the short-term fission-product heat load of waste destined for geologic disposal are neglected under the current source-based radioactive waste classification system , and that it is useful to classify waste streams based on how favorable the impact of interim storage is in increasing repository capacity.

  12. Waste Classification based on Waste Form Heat Generation in Advanced Nuclear Fuel Cycles Using the Fuel-Cycle Integration and Tradeoffs (FIT) Model - 13413

    SciTech Connect (OSTI)

    Djokic, Denia [Department of Nuclear Engineering, University of California - Berkeley, 4149 Etcheverry Hall, Berkeley, CA 94720-1730 (United States)] [Department of Nuclear Engineering, University of California - Berkeley, 4149 Etcheverry Hall, Berkeley, CA 94720-1730 (United States); Piet, Steven J.; Pincock, Layne F.; Soelberg, Nick R. [Idaho National Laboratory - INL, 2525 North Fremont Avenue, Idaho Falls, ID 83415 (United States)] [Idaho National Laboratory - INL, 2525 North Fremont Avenue, Idaho Falls, ID 83415 (United States)

    2013-07-01

    This study explores the impact of wastes generated from potential future fuel cycles and the issues presented by classifying these under current classification criteria, and discusses the possibility of a comprehensive and consistent characteristics-based classification framework based on new waste streams created from advanced fuel cycles. A static mass flow model, Fuel-Cycle Integration and Tradeoffs (FIT), was used to calculate the composition of waste streams resulting from different nuclear fuel cycle choices. This analysis focuses on the impact of waste form heat load on waste classification practices, although classifying by metrics of radiotoxicity, mass, and volume is also possible. The value of separation of heat-generating fission products and actinides in different fuel cycles is discussed. It was shown that the benefits of reducing the short-term fission-product heat load of waste destined for geologic disposal are neglected under the current source-based radioactive waste classification system, and that it is useful to classify waste streams based on how favorable the impact of interim storage is in increasing repository capacity. (authors)

  13. Assessment of spent-fuel waste-form/stabilizer alternatives for geologic disposal

    SciTech Connect (OSTI)

    Einziger, R.E.; Himes, D.A.

    1982-06-01

    The Office of Nuclear Waste Isolation (ONWI) is studying the possibility of burying canisterized unreprocessed spent fuel in a deep geologic repository. One aspect of this study is an assessment of the possible spent fuel waste forms. The fuel performance portion of the Waste Form Assessment was to evaluate five candidate spent fuel waste forms for postemplacement performance with emphasis on their ability to retard the release of radionuclides to the repository geology. Spent fuel waste forms under general consideration were: (1) unaltered fuel assembly; (2) fuel assembly with end fittings removed to shorten the length; (3 rods vented to remove gases and resealed; (4) disassembled fuel bundles to close-pack the rods; and (5) rods chopped and fragments immobilized in a matrix material. Thirteen spent fuel waste forms, classified by generic stabilizer type, were analyzed for relative in-repository performance based on: (1) waste form/stabilizer support against lithostatic pressure; (2) long-term stability for radionuclide retention; (3) minimization of cladding degradation; (4) prevention of canister/repository breach due to pressurization; (5) stabilizer heat transfer; (6) the stabilizer as an independent barrier to radionuclide migration; and (7) prevention of criticality. The waste form candidates were ranked as follows: (1) the best waste form/stabilizer combination is the intact assembly, with or without end bells, vented (and resealed) or unvented, with a solid stabilizer; (2) a suitable alternative is the combination of bundled close-packed rods with a solid stabilizer around the outside of the bundle to resist lithostatic pressure; and (3) the other possible waste forms are of lower ranking with the worst waste form/stabilizer combination being the intact assembly with a gas stabilizer or the chopped fuel.

  14. Fair Oaks Farms and AMP Americas Transform Waste into Fuel | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Fair Oaks Farms and AMP Americas Transform Waste into Fuel Fair Oaks Farms and AMP Americas Transform Waste into Fuel March 7, 2013 - 9:00am Addthis Learn how an Indiana dairy fuels milk delivery trucks with compressed natural gas. Shannon Brescher Shea Communications Manager, Clean Cities Program What are the key facts? An anaerobic digester is helping Fair Oaks Farms and AMP Americas turn agriculture waste into renewable natural gas. The natural gas will be used to fuel the fleet of

  15. A Combined Nonfertile and UO{sub 2} PWR Fuel Assembly for Actinide Waste

    Office of Scientific and Technical Information (OSTI)

    Minimization (Journal Article) | SciTech Connect A Combined Nonfertile and UO{sub 2} PWR Fuel Assembly for Actinide Waste Minimization Citation Details In-Document Search Title: A Combined Nonfertile and UO{sub 2} PWR Fuel Assembly for Actinide Waste Minimization A new COmbined NonFertile and Uranium (CONFU) fuel assembly is proposed to limit the actinides that need long-term high-level waste storage from the pressurized water reactor (PWR) fuel cycle. In the CONFU assembly concept,

  16. NEW SOLID FUELS FROM COAL AND BIOMASS WASTE

    SciTech Connect (OSTI)

    Hamid Farzan

    2001-09-24

    Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable fuel. These fuels will be converted to energy while reducing CO{sub 2} emissions from power generating boilers and mitigating global warming concerns. This report describes the sludge analysis, solid fuel preparation and production, combustion performance, environmental emissions and required equipment.

  17. Transuranic Waste Burning Potential of Thorium Fuel in a Fast Reactor -

    Office of Scientific and Technical Information (OSTI)

    12423 (Conference) | SciTech Connect Transuranic Waste Burning Potential of Thorium Fuel in a Fast Reactor - 12423 Citation Details In-Document Search Title: Transuranic Waste Burning Potential of Thorium Fuel in a Fast Reactor - 12423 Westinghouse Electric Company (referred to as 'Westinghouse' in the rest of this paper) is proposing a 'back-to-front' approach to overcome the stalemate on nuclear waste management in the US. In this approach, requirements to further the societal acceptance

  18. Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation

    DOE Patents [OSTI]

    Tedder, Daniel W.

    1985-05-14

    Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

  19. Acceptance of spent nuclear fuel in multiple element sealed canisters by the Federal Waste Management System

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    This report is one of a series of eight prepared by E.R. Johnson Associates, Inc. (JAI) under ORNL's contract with DOE's OCRWM Systems Integration Program and in support of the Annual Capacity Report (ACR) Issue Resolution Process. The report topics relate specifically to the list of high priority technical waste acceptance issues developed jointly by DOE and a utility-working group. JAI performed various analyses and studies on each topic to serve as starting points for further discussion and analysis leading eventually to finalizing the process by which DOE will accept spent fuel and waste into its waste management system. The eight reports are concerned with the conditions under which spent fuel and high level waste will be accepted in the following categories: (1) failed fuel; (2) consolidated fuel and associated structural parts; (3) non-fuel-assembly hardware; (4) fuel in metal storage casks; (5) fuel in multi-element sealed canisters; (6) inspection and testing requirements for wastes; (7) canister criteria; (8) spent fuel selection for delivery; and (9) defense and commercial high-level waste packages. 14 refs., 27 figs.

  20. Abundance of {sup 14}C in biomass fractions of wastes and solid recovered fuels

    SciTech Connect (OSTI)

    Fellner, Johann Rechberger, Helmut

    2009-05-15

    In recent years thermal utilization of mixed wastes and solid recovered fuels has become of increasing importance in European waste management. Since wastes or solid recovered fuels are generally composed of fossil and biogenic materials, only part of the CO{sub 2} emissions is accounted for in greenhouse gas inventories or emission trading schemes. A promising approach for determining this fraction is the so-called radiocarbon method. It is based on different ratios of the carbon isotopes {sup 14}C and {sup 12}C in fossil and biogenic fuels. Fossil fuels have zero radiocarbon, whereas biogenic materials are enriched in {sup 14}C and reflect the {sup 14}CO{sub 2} abundance of the ambient atmosphere. Due to nuclear weapons tests in the past century, the radiocarbon content in the atmosphere has not been constant, which has resulted in a varying {sup 14}C content of biogenic matter, depending on the period of growth. In the present paper {sup 14}C contents of different biogenic waste fractions (e.g., kitchen waste, paper, wood), as well as mixtures of different wastes (household, bulky waste, and commercial waste), and solid recovered fuels are determined. The calculated {sup 14}C content of the materials investigated ranges between 98 and 135 pMC.

  1. Integrated data base report - 1994: US spent nuclear fuel and radioactive waste inventories, projections, and characteristics

    SciTech Connect (OSTI)

    1995-09-01

    The Integrated Data Base Program has compiled historic data on inventories and characteristics of both commercial and U.S. Department of Energy (DOE) spent nuclear fuel and commercial and U.S. government-owned radioactive wastes. Except for transuranic wastes, inventories of these materials are reported as of December 31, 1994. Transuranic waste inventories are reported as of December 31, 1993. All spent nuclear fuel and radioactive waste data reported are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest DOE/Energy Information Administration (EIA) projections of U.S. commercial nuclear power growth and the expected DOE-related and private industrial and institutional activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste, transuranic waste, low-level waste, commercial uranium mill tailings, DOE Environmental Restoration Program contaminated environmental media, commercial reactor and fuel-cycle facility decommissioning wastes, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given through the calendar-year 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions.

  2. Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste

    Broader source: Energy.gov [DOE]

    The Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste is a framework for moving toward a sustainable program to deploy an integrated system capable of...

  3. Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste

    Broader source: Energy.gov [DOE]

    Issued on January 11, 2013, the Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste is a framework for moving toward a sustainable program to deploy an...

  4. Geek-Up[5.20.2011]: Electricity from Waste Heat, Fuel from Sunlight

    Broader source: Energy.gov [DOE]

    Did you know 50 percent of the energy generated annually from all sources is lost as waste heat? What scientists are doing to take advantage of this opportunity to save money and new developments in harvesting fuel through photosynthesis.

  5. EM Prepares Report for Convention on Safety of Spent Fuel and Radioactive Waste Management

    Broader source: Energy.gov [DOE]

    WASHINGTON, D.C. – EM supported DOE in its role as the lead technical agency to produce a report recently for the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management.

  6. Energy balances in the production and end use of alcohols derived from biomass. A fuels-specific comparative analysis of alternate ethanol production cycles

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    Considerable public interest and debate have been focused on the so-called energy balance issue involved in the conversion of biomass materials into ethanol for fuel use. This report addresses questions of net gains in premium fuels that can be derived from the production and use of ethanol from biomass, and shows that for the US alcohol fuel program, energy balance need not be a concern. Three categories of fuel gain are discussed in the report: (1) Net petroleum gain; (2) Net premium fuel gain (petroleum and natural gas); and (3) Net energy gain (for all fuels). In this study the investment of energy (in the form of premium fuels) in alcohol production includes all investment from cultivating, harvesting, or gathering the feedstock and raw materials, through conversion of the feedstock to alcohol, to the delivery to the end-user. To determine the fuel gains in ethanol production, six cases, encompassing three feedstocks, five process fuels, and three process variations, have been examined. For each case, two end-uses (automotive fuel use and replacement of petrochemical feedstocks) were scrutinized. The end-uses were further divided into three variations in fuel economy and two different routes for production of ethanol from petrochemicals. Energy requirements calculated for the six process cycles accounted for fuels used directly and indirectly in all stages of alcohol production, from agriculture through distribution of product to the end-user. Energy credits were computed for byproducts according to the most appropriate current use.

  7. Nuclear Solid Waste Processing Design at the Idaho Spent Fuels Facility

    SciTech Connect (OSTI)

    Dippre, M. A.

    2003-02-25

    A spent nuclear fuels (SNF) repackaging and storage facility was designed for the Idaho National Engineering and Environmental Laboratory (INEEL), with nuclear solid waste processing capability. Nuclear solid waste included contaminated or potentially contaminated spent fuel containers, associated hardware, machinery parts, light bulbs, tools, PPE, rags, swabs, tarps, weld rod, and HEPA filters. Design of the nuclear solid waste processing facilities included consideration of contractual, regulatory, ALARA (as low as reasonably achievable) exposure, economic, logistical, and space availability requirements. The design also included non-attended transfer methods between the fuel packaging area (FPA) (hot cell) and the waste processing area. A monitoring system was designed for use within the FPA of the facility, to pre-screen the most potentially contaminated fuel canister waste materials, according to contact- or non-contact-handled capability. Fuel canister waste materials which are not able to be contact-handled after attempted decontamination will be processed remotely and packaged within the FPA. Noncontact- handled materials processing includes size-reduction, as required to fit into INEEL permitted containers which will provide sufficient additional shielding to allow contact handling within the waste areas of the facility. The current design, which satisfied all of the requirements, employs mostly simple equipment and requires minimal use of customized components. The waste processing operation also minimizes operator exposure and operator attendance for equipment maintenance. Recently, discussions with the INEEL indicate that large canister waste materials can possibly be shipped to the burial facility without size-reduction. New waste containers would have to be designed to meet the drop tests required for transportation packages. The SNF waste processing facilities could then be highly simplified, resulting in capital equipment cost savings, operational time savings, and significantly improved ALARA exposure.

  8. The EU Approach for Responsible and Safe Management of Spent Fuel and Radioactive Waste - 12118

    SciTech Connect (OSTI)

    Blohm-Hieber, Ute; Necheva, Christina [European Commission, Directorate-General for Energy, Luxembourg L-2920 (Luxembourg)

    2012-07-01

    In July 2011 legislation on responsible and safe management of spent fuel and radioactive waste was adopted in the European Union (EU). It aims at ensuring a high level of safety, avoiding undue burdens on future generations and enhancing transparency. EU Member States are responsible for the management of their spent fuel and/or radioactive waste. Each Member State remains free to define its fuel cycle policy. The spent fuel can be regarded either as a valuable resource that may be reprocessed or as radioactive waste that is destined for direct disposal. Whatever option is chosen, the disposal of high level waste, separated at reprocessing, or of spent fuel regarded as waste should be considered. The storage of radioactive waste, including long-term storage, is an interim solution, but not an alternative to disposal. To this end, each Member State has to establish, maintain and implement national policy, framework and programme for management of spent fuel and/or radioactive waste in the long term. Member States will invite international peer reviews to ensure that high safety standards are achieved. The EU approach is anchored in internationally endorsed principles and requirements of the IAEA safety standards and the Joint Convention and in this context makes them legally binding and enforceable in the EU. The EU approach of regulating the management of spent fuel and radioactive waste is anchored in the competence of the national regulatory authorities and in the internationally endorsed principles and requirements of the IAEA Safety Standards and the Joint Convention. Member States have to report to the Commission on the implementation of Directive 2011/70/Euratom for the first time by 23 August 2015, and every 3 years thereafter, taking advantage of the review and reporting under the Joint Convention. On the basis of the Member States' reports, the Commission will submit to the European Parliament and the Council a report on progress made and an inventory of radioactive waste and spent fuel present in the EU territory and the future prospects. Directive 2011/70/Euratom is a logical next step after the Council Directive 2009/71/Euratom on the nuclear safety of nuclear installations. The EU is the first major regional actor providing a binding legal framework on nuclear safety and on responsible and safe management of spent fuel and radioactive waste, and thus is a real model to progress spent fuel and waste management in a safe and responsible manner. (authors)

  9. Process Knowledge Summary Report for Materials and Fuels Complex Contact-Handled Transuranic Debris Waste

    SciTech Connect (OSTI)

    R. P. Grant; P. J. Crane; S. Butler; M. A. Henry

    2010-02-01

    This Process Knowledge Summary Report summarizes the information collected to satisfy the transportation and waste acceptance requirements for the transfer of transuranic (TRU) waste between the Materials and Fuels Complex (MFC) and the Advanced Mixed Waste Treatment Project (AMWTP). The information collected includes documentation that addresses the requirements for AMWTP and the applicable portion of their Resource Conservation and Recovery Act permits for receipt and treatment of TRU debris waste in AMWTP. This report has been prepared for contact-handled TRU debris waste generated by the Idaho National Laboratory at MFC. The TRU debris waste will be shipped to AMWTP for purposes of supercompaction. This Process Knowledge Summary Report includes information regarding, but not limited to, the generation process, the physical form, radiological characteristics, and chemical contaminants of the TRU debris waste, prohibited items, and packaging configuration. This report, along with the referenced supporting documents, will create a defensible and auditable record for waste originating from MFC.

  10. Method for recovering palladium and technetium values from nuclear fuel reprocessing waste solutions

    DOE Patents [OSTI]

    Horwitz, E. Philip; Delphin, Walter H.

    1979-07-24

    A method for recovering palladium and technetium values from nuclear fuel reprocessing waste solutions containing these and other values by contacting the waste solution with an extractant of tricaprylmethylammonium nitrate in an inert hydrocarbon diluent which extracts the palladium and technetium values from the waste solution. The palladium and technetium values are recovered from the extractant and from any other coextracted values with a strong nitric acid strip solution.

  11. Maximim Accelerations On The Fuel Assemblies Of a 21-PWR Waste Package During End Impacts 

    SciTech Connect (OSTI)

    V. DeLa Brosse

    2003-03-27

    The objective of this calculation is to determine the acceleration of the fuel assemblies contained in a 21-Pressurized Water Reactor (PWR) spent nuclear fuel waste package impacting an unyielding surface. A range of initial velocities of the waste package is studied. The scope of this calculation is limited to estimating the acceleration of the fuel assemblies during the impact.

  12. Maximim Accelerations On The Fuel Assemblies Of a 21-PWR Waste Package During End Impacts 

    SciTech Connect (OSTI)

    T. Schmitt

    2005-08-17

    The objective of this calculation is to determine the acceleration of the fuel assemblies contained in a 21-Pressurized Water Reactor (PWR) spent nuclear fuel waste package impacting an unyielding surface. A range of initial velocities of the waste package is studied. The scope of this calculation is limited to estimating the acceleration of the fuel assemblies during the impact.

  13. Summary of non-US national and international fuel cycle and radioactive waste management programs 1982

    SciTech Connect (OSTI)

    Harmon, K.M.; Kelman, J.A.

    1982-08-01

    Brief program overviews of fuel cycle, spent fuel, and waste management activities in the following countries are provided: Argentina, Australia, Austria, Belgium, Brazil, Canada, China, Denmark, Finland, France, German Federal Republic, India, Italy, Japan, Republic of Korea, Mexico, Netherlands, Pakistan, South Africa, Spain, Sweden, Switzerland, Taiwan, USSR, and the United Kingdom. International nonproliferation activities, multilateral agreements and projects, and the international agencies specifically involved in the nuclear fuel cycle are also described.

  14. Analyzing Losses: Transuranics into Waste and Fission Products into Recycled Fuel

    SciTech Connect (OSTI)

    Steven J. Piet; Nick R. Soelberg; Samuel E. Bays; Robert E. Cherry; Layne F. Pincock; Eric L. Shaber; Melissa C. Teague; Gregory M. Teske; Kurt G. Vedros; Candido Pereira; Denia Djokic

    2010-11-01

    All mass streams from separations and fuel fabrication are products that must meet criteria. Those headed for disposal must meet waste acceptance criteria (WAC) for the eventual disposal sites corresponding to their waste classification. Those headed for reuse must meet fuel or target impurity limits. A loss is any material that ends up where it is undesired. The various types of losses are linked in the sense that as the loss of transuranic (TRU) material into waste is reduced, often the loss or carryover of waste into TRU or uranium is increased. We have analyzed four separation options and two fuel fabrication options in a generic fuel cycle. The separation options are aqueous uranium extraction plus (UREX+1), electrochemical, Atomics International reduction oxidation separation (AIROX), and melt refining. UREX+1 and electrochemical are traditional, full separation techniques. AIROX and melt refining are taken as examples of limited separations, also known as minimum fuel treatment. The fuels are oxide and metal. To define a generic fuel cycle, a fuel recycling loop is fed from used light water reactor (LWR) uranium oxide fuel (UOX) at 51 MWth-day/kg-iHM burnup. The recycling loop uses a fast reactor with TRU conversion ratio (CR) of 0.50. Excess recovered uranium is put into storage. Only waste, not used fuel, is disposed unless the impurities accumulate to a level so that it is impossible to make new fuel for the fast reactor. Impurities accumulate as dictated by separation removal and fission product generation. Our model approximates adjustment to fast reactor fuel stream blending of TRU and U products from incoming LWR UOX and recycling FR fuel to compensate for impurity accumulation by adjusting TRU:U ratios. Our mass flow model ignores postulated fuel impurity limits; we compare the calculated impurity values with those limits to identify elements of concern. AIROX and melt refining cannot be used to separate used LWR UOX-51 because they cannot separate U from TRU, it is then impossible to make X% TRU for fast reactors with UOX-51 used fuel with 1.3% TRU. AIROX and melt refining can serve in the recycle loop for about 3 recycles, at which point the accumulated impurities displace fertile uranium and the fuel can no longer be as critical as the original fast reactor fuel recipe. UREX+1 and electrochemical can serve in either capacity; key impurities appear to be lanthanides and several transition metals.

  15. A Novel Fuel/Reactor Cycle to Implement the 300 Years Nuclear Waste Policy Approach - 12377

    SciTech Connect (OSTI)

    Carelli, M.D.; Franceschini, F.; Lahoda, E.J.; Petrovic, B.

    2012-07-01

    A thorium-based fuel cycle system can effectively burn the currently accumulated commercial used nuclear fuel and move to a sustainable equilibrium where the actinide levels in the high level waste are low enough to yield a radiotoxicity after 300 years lower than that of the equivalent uranium ore. The second step of the Westinghouse approach to solving the waste 'problem' has been completed. The thorium fuel cycle has indeed the potential of burning the legacy TRU and achieve the waste objective proposed. Initial evaluations have been started for the third step, development and selection of appropriate reactors. Indications are that the probability of show-stoppers is rather remote. It is, therefore, believed that development of the thorium cycle and associated technologies will provide a permanent solution to the waste management. Westinghouse is open to the widest collaboration to make this a reality. (authors)

  16. Fuel from Waste Helps Power Two Tribes | Department of Energy

    Energy Savers [EERE]

    Department of Energy Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower This page contains information on the recently released BioPower engines. PDF icon analysis_saab2007.pdf More Documents & Publications Enabling High Efficiency Ethanol Engines Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) The Impact of Low Octane Hydrocarbon Blending

  17. Trends in characteristics of hazardous waste-derived fuel burned for energy recovery in cement kilns

    SciTech Connect (OSTI)

    Lusk, M.G.; Campbell, C.S.

    1996-12-31

    The Cement Kiln Recycling Coalition (CKRC) is a national trade association representing virtually all the U.S. cement companies involved in the use of waste-derived fuel in the cement manufacturing process as well as those companies involved in the collection, processing, managing, and marketing of such fuel. CKRC, in conjunction with the National Association of Chemical Recyclers (NACR), completed several data collection activities over the past two years to provide the Environmental Protection Agency (EPA) and other interested parties with industry-wide trend analyses. The analyses evaluated the content of specific metals in waste fuels utilized by cement kilns, average Btu value of substitute fuels used by kilns, and provides insight into the trends of these properties. With the exception of the data collected by NACR, the study did not evaluate materials sent to hazardous waste incinerators or materials that are combusted at {open_quotes}on-site{close_quotes} facilities.

  18. Management of Salt Waste from Electrochemical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    Michael F. Simpson; Michael N. Patterson; Joon Lee; Yifeng Wang; Joshua Versey; Ammon Williams; Supathorn Phongikaroon; James Allensworth; Man-Sung Yim

    2013-10-01

    Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electrorefiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form.

  19. Management of salt waste from electrochemical processing of used nuclear fuel

    SciTech Connect (OSTI)

    Simpson, M.F.; Patterson, M.N.; Lee, J.; Wang, Y.; Versey, J.; Phongikaroon, S.

    2013-07-01

    Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electro-refiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form. (authors)

  20. Graphical and tabular summaries of decay characteristics for once-through PWR, LMFBR, and FFTF fuel cycle materials. [Spent fuel, high-level waste fuel can scrap

    SciTech Connect (OSTI)

    Croff, A.G.; Liberman, M.S.; Morrison, G.W.

    1982-01-01

    Based on the results of ORIGEN2 and a newly developed code called ORMANG, graphical and summary tabular characteristics of spent fuel, high-level waste, and fuel assembly structural material (cladding) waste are presented for a generic pressurized-water reactor (PWR), a liquid-metal fast breeder reactor (LMFBR), and the Fast Flux Test Facility (FFTF). The characteristics include radioactivity, thermal power, and toxicity (water dilution volume). Given are graphs and summary tables containing characteristic totals and the principal nuclide contributors as well as graphs comparing the three reactors for a single material and the three materials for a single reactor.

  1. Materials and Fuels Complex Facilities Radioactive Waste Management Basis and DOE Manual 435.1-1 Compliance Tables

    SciTech Connect (OSTI)

    Lisa Harvego; Brion Bennett

    2011-09-01

    Department of Energy Order 435.1, 'Radioactive Waste Management,' along with its associated manual and guidance, requires development and maintenance of a radioactive waste management basis for each radioactive waste management facility, operation, and activity. This document presents a radioactive waste management basis for Idaho National Laboratory's Materials and Fuels Complex facilities that manage radioactive waste. The radioactive waste management basis for a facility comprises existing laboratory-wide and facility-specific documents. Department of Energy Manual 435.1-1, 'Radioactive Waste Management Manual,' facility compliance tables also are presented for the facilities. The tables serve as a tool for developing the radioactive waste management basis.

  2. Recent Developments in the Management of Cameco Corporation's Fuel Services Division Waste - 13144

    SciTech Connect (OSTI)

    Smith, Thomas P.

    2013-07-01

    Cameco Corporation is a world leader in uranium production. Headquartered in Saskatoon, Saskatchewan our operations provide 16% of the world uranium mine production and we have approximately 435 million pounds of proven and probable uranium reserves. Cameco mining operations are located in Saskatchewan, Wyoming, Nebraska and Kazakhstan. Cameco is also a major supplier of uranium processing services required to produce fuel for the generation of clean energy. These operations are based in Blind River, Cobourg and Port Hope, Ontario and are collectively referred to as the Fuel Services Division. The Fuel Services Division produces uranium trioxide from uranium ore concentrate at the Blind River Refinery. Cameco produces uranium hexafluoride and uranium dioxide at the Port Hope Conversion Facility. Cameco operates a fuel manufacturing facility in Port Hope, Ontario and a metal fabrication facility located in Cobourg, Ontario. The company manufactures fuel bundles utilized in the Candu reactors. Cameco's Fuel Services Division produces several types of low-level radioactively contaminated wastes. Internal processing capabilities at both the Blind River Refinery and Port Hope Conversion Facility are extensive and allow for the recycling of several types of waste. Notwithstanding these capabilities there are certain wastes that are not amenable to the internal processing capabilities and must be disposed of appropriately. Disposal options for low-level radioactively contaminated wastes in Canada are limited primarily due to cost considerations. In recent years, Cameco has started to ship marginally contaminated wastes (<500 ppm uranium) to the United States for disposal in an appropriate landfill. The landfill is owned by US Ecology Incorporated and is located near Grand View, Idaho 70 miles southeast of Boise in the Owyhee Desert. The facility treats and disposes hazardous waste, non-hazardous industrial waste and low-activity radioactive material. The site's arid climate, deep groundwater and favourable geology help ensure permanent waste isolation. Combined with a state of the art multi-layer landfill liner system, the Grand View facility represents an ideal choice to minimize environmental liability. Marginally contaminated wastes from operations within the Fuel Services Division are typically loaded into PacTec IP-2 rated Intermediary Bulk Containers and then transported by road to a nearby rail siding. The Intermediary Bulk Containers are then loaded in US Ecology owned gondola rail-cars. The gondolas are then transported via Canadian Pacific and Union Pacific railroads to the US Ecology Rail Transfer facility located in Mayfield, Idaho. The Intermediary Bulk Containers are unloaded into trucks for transport to the disposal facility located approximately 32 miles away. (authors)

  3. Mixed waste paper to ethanol fuel. A technology, market, and economic assessment for Washington

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  4. Plant That Makes Fuel Out Of Garbage and Waste Called A Success

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plant That Makes Fuel Out Of Garbage and Waste Called A Success For more information contact: e:mail: Public Affairs Golden, Colo., May 5, 1999 — The final report on a demonstration of a technology for turning organic wastes into fuel, energy and other products calls the project a success and concludes there are no major issues standing in the way of the technology being commercialized on a larger scale. The report is on the operation of the high solids anaerobic digester (HSAD) in Stanton,

  5. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology

    SciTech Connect (OSTI)

    Valkenburt, Corinne; Walton, Christie W.; Thompson, Becky L.; Gerber, Mark A.; Jones, Susanne B.; Stevens, Don J.

    2008-12-01

    This report investigated the potential of using municipal solid waste (MSW) to make synthesis gas (syngas) suitable for production of liquid fuels. Issues examined include: MSW physical and chemical properties affecting its suitability as a gasifier feedstock and for liquid fuels synthesis expected process scale required for favorable economics the availability of MSW in quantities sufficient to meet process scale requirements the state-of-the-art of MSW gasification technology.

  6. Comparison of emissions from landfills, municipal waste combustors, and fossil fuel-fired utilities

    SciTech Connect (OSTI)

    1996-11-01

    Landfilling is the most popular disposal method for managing municipal solid waste (MSW). However, air emissions from MSW landfills have generally been unregulated until recently. Instead, EPA has focused on emissions from municipal waste combustors (MWCs), even though they only manage 15% of MSW generated in the United States. In the past, little data have been available comparing landfill and MWC air emissions. Such information is provided by this paper. It also compares emissions from waste-to-energy MWCs and fossil fuel-fired utilities with equivalent electrical generation capacity. 1 refs., 6 tabs.

  7. Municipal solid waste fueled power generation in China: a case study of waste-to-energy in Changchun city

    SciTech Connect (OSTI)

    Hefa Cheng; Yanguo Zhang; Aihong Meng; Qinghai Li

    2007-11-01

    With rapid economic growth and massive urbanization in China, many cities face the problem of municipal solid waste (MSW) disposal. With the lack of space for new landfills, waste-to-energy incineration is playing an increasingly important role in waste management. Incineration of MSW from Chinese cities presents some unique challenges because of its low calorific value (3000-6700 kJ/kg) and high water content (about 50%). This study reports a novel waste-to-energy incineration technology based on co-firing of MSW with coal in a grate-circulating fluidized bed (CFB) incinerator, which was implemented in the Changchun MSW power plant. In 2006, two 260 ton/day incinerators incinerated 137,325 tons, or approximately one/sixth of the MSW generated in Changchun, saving more than 0.2 million m{sup 3} landfill space. A total of 46.2 million kWh electricity was generated (38,473 tons lignite was also burned as supplementary fuel), with an overall fuel-to-electricity efficiency of 14.6%. Emission of air pollutants including particulate matters, acidic gases, heavy metals, and dioxins was low and met the emission standards for incinerators. As compared to imported incineration systems, this new technology has much lower capital and operating costs and is expected to play a role in meeting China's demands for MSW disposal and alternative energy. 34 refs., 1 fig., 4 tabs.

  8. Waste fuel, EMS may save plant $1M yearly

    SciTech Connect (OSTI)

    Barber, J.

    1982-05-24

    A mixture of paper trash and coal ash fueling an Erie, Pa. General Electric plant and a Network 90 microprocessor-based energy-management system (EMS) to optimize boiler efficiency will cost about $3 million and have a three-to-four-year payback. Over half the savings will come from the avoided costs of burning plant-generated trash. The EMS system will monitor fuel requirements in the boiler and compensate for changes in steam demand. It will also monitor plant electrical needs and control the steam diverted for cogeneration. (DCK)

  9. Annotated bibliography for the design of waste packages for geologic disposal of spent fuel and high-level waste

    SciTech Connect (OSTI)

    Wurm, K.J.; Miller, N.E.

    1982-11-01

    This bibliography identifies documents that are pertinent to the design of waste packages for geologic disposal of nuclear waste. The bibliography is divided into fourteen subject categories so that anyone wishing to review the subject of leaching, for example, can turn to the leaching section and review the abstracts of reports which are concerned primarily with leaching. Abstracts are also cross referenced according to secondary subject matter so that one can get a complete list of abstracts for any of the fourteen subject categories. All documents which by their title alone appear to deal with the design of waste packages for the geologic disposal of spent fuel or high-level waste were obtained and reviewed. Only those documents which truly appear to be of interest to a waste package designer were abstracted. The documents not abstracted are listed in a separate section. There was no beginning date for consideration of a document for review. About 1100 documents were reviewed and about 450 documents were abstracted.

  10. Comparison of selected foreign plans and practices for spent fuel and high-level waste management

    SciTech Connect (OSTI)

    Schneider, K.J.; Mitchell, S.J.; Lakey, L.T.; Johnson, A.B. Jr.; Hazelton, R.F.; Bradley, D.J.

    1990-04-01

    This report describes the major parameters for management of spent nuclear fuel and high-level radioactive wastes in selected foreign countries as of December 1989 and compares them with those in the United States. The foreign countries included in this study are Belgium, Canada, France, the Federal Republic of Germany, Japan, Sweden, Switzerland, and the United Kingdom. All the countries are planning for disposal of spent fuel and/or high-level wastes in deep geologic repositories. Most countries (except Canada and Sweden) plan to reprocess their spent fuel and vitrify the resultant high-level liquid wastes; in comparison, the US plans direct disposal of spent fuel. The US is planning to use a container for spent fuel as the primary engineered barrier. The US has the most developed repository concept and has one of the earliest scheduled repository startup dates. The repository environment presently being considered in the US is unique, being located in tuff above the water table. The US also has the most prescriptive regulations and performance requirements for the repository system and its components. 135 refs., 8 tabs.

  11. Geologic repository design and disposal: GNEP spent fuel processing-waste volume

    SciTech Connect (OSTI)

    Bauer, T.H.; Wigeland, R.A.

    2007-07-01

    Previous work has shown that removal of key heat generating elements from spent fuel would allow greater utilization of space in a geologic repository such as Yucca Mountain by factors of 100 or more without increasing the estimated peak dose rate to an exposed individual. However, achieving such utilization increases within a repository storage drift requires the density of the remaining fission products, actinide elements, etc. to be increased by roughly the same factor as the utilization increase, itself. This paper analyzes several alternative drift configurations possible within a designated repository area that could: (1) allow greater volume for waste storage and (2) maintain significant utilization benefit. For a representative range of GNEP-generated waste streams, computed results show that increase in repository area space utilization by a factor {approx}100 can be maintained with such configurations as long as waste stream volume can be reduced from that of the original spent fuel by a factor of {approx}10. (authors)

  12. Steam gasification of tyre waste, poplar, and refuse-derived fuel: A comparative analysis

    SciTech Connect (OSTI)

    Galvagno, S. Casciaro, G.; Casu, S.; Martino, M.; Mingazzini, C.; Russo, A.; Portofino, S.

    2009-02-15

    In the field of waste management, thermal disposal is a treatment option able to recover resources from 'end of life' products. Pyrolysis and gasification are emerging thermal treatments that work under less drastic conditions in comparison with classic direct combustion, providing for reduced gaseous emissions of heavy metals. Moreover, they allow better recovery efficiency since the process by-products can be used as fuels (gas, oils), for both conventional (classic engines and heaters) and high efficiency apparatus (gas turbines and fuel cells), or alternatively as chemical sources or as raw materials for other processes. This paper presents a comparative study of a steam gasification process applied to three different waste types (refuse-derived fuel, poplar wood and scrap tyres), with the aim of comparing the corresponding yields and product compositions and exploring the most valuable uses of the by-products.

  13. Transuranic Waste Burning Potential of Thorium Fuel in a Fast Reactor - 12423

    SciTech Connect (OSTI)

    Wenner, Michael; Franceschini, Fausto; Ferroni, Paolo; Sartori, Alberto; Ricotti, Marco

    2012-07-01

    Westinghouse Electric Company (referred to as 'Westinghouse' in the rest of this paper) is proposing a 'back-to-front' approach to overcome the stalemate on nuclear waste management in the US. In this approach, requirements to further the societal acceptance of nuclear waste are such that the ultimate health hazard resulting from the waste package is 'as low as reasonably achievable'. Societal acceptability of nuclear waste can be enhanced by reducing the long-term radiotoxicity of the waste, which is currently driven primarily by the protracted radiotoxicity of the transuranic (TRU) isotopes. Therefore, a transition to a more benign radioactive waste can be accomplished by a fuel cycle capable of consuming the stockpile of TRU 'legacy' waste contained in the LWR Used Nuclear Fuel (UNF) while generating waste which is significantly less radio-toxic than that produced by the current open U-based fuel cycle (once through and variations thereof). Investigation of a fast reactor (FR) operating on a thorium-based fuel cycle, as opposed to the traditional uranium-based is performed. Due to a combination between its neutronic properties and its low position in the actinide chain, thorium not only burns the legacy TRU waste, but it does so with a minimal production of 'new' TRUs. The effectiveness of a thorium-based fast reactor to burn legacy TRU and its flexibility to incorporate various fuels and recycle schemes according to the evolving needs of the transmutation scenario have been investigated. Specifically, the potential for a high TRU burning rate, high U-233 generation rate if so desired and low concurrent production of TRU have been used as metrics for the examined cycles. Core physics simulations of a fast reactor core running on thorium-based fuels and burning an external TRU feed supply have been carried out over multiple cycles of irradiation, separation and reprocessing. The TRU burning capability as well as the core isotopic content have been characterized. Results will be presented showing the potential for thorium to reach a high TRU transmutation rate over a wide variety of fuel types (oxide, metal, nitride and carbide) and transmutation schemes (recycle or partition of in-bred U-233). In addition, a sustainable scheme has been devised to burn the TRU accumulated in the core inventory once the legacy TRU supply has been exhausted, thereby achieving long-term virtually TRU-free. A comprehensive 'back-to-front' approach to the fuel cycle has recently been proposed by Westinghouse which emphasizes achieving 'acceptable', low-radiotoxicity, high-level waste, with the intent not only to satisfy all technical constraints but also to improve public acceptance of nuclear energy. Following this approach, the thorium fuel cycle, due to its low radiotoxicity and high potential for TRU transmutation has been selected as a promising solution. Additional studies not shown here have shown significant reduction of decay heat. The TRU burning potential of the Th-based fuel cycle has been illustrated with a variety of fuel types, using the Toshiba ARR to perform the analysis, including scenarios with continued LWR operation of either uranium fueled or thorium fueled LWRs. These scenarios will afford overall reduction in actinide radiotoxicity, however when the TRU supply is exhausted, a continued U- 235 LWR operation must be assumed to provide TRU makeup feed. This scenario will never reach the characteristically low TRU content of a closed thorium fuel cycle with its associated potential benefits on waste radiotoxicity, as exemplified by the transition scenario studied. At present, the cases studied indicate ThC as a potential fuel for maximizing TRU burning, while ThN with nitrogen enriched to 95% N-15 shows the highest breeding potential. As a result, a transition scenario with ThN was developed to show that a sustainable, closed Th-cycle can be achieved starting from burning the legacy TRU stock and completing the transmutation of the residual TRU remaining in the core inventory after the legacy TRU external supply has been exhausted. The radiotoxicity of the actinide waste during the various phases has been characterized, showing the beneficial effect of the decreasing content of TRU in the recycled fuel as the transition to a closed Th-based fuel cycle is undertaken. Due to the back-to-front nature of the proposed methodology, detailed designs are not the first step taken when assessing a fuel cycle scenario potential. As a result, design refinement is still required and should be expected in future studies. Moreover, significant safety assessment, including determination of associated reactivity coefficients, fuel and reprocessing feasibility studies and economic assessments will still be needed for a more comprehensive and meaningful comparison against other potential solutions. With the above considerations in mind, the potential advantages of thorium fuelled reactors on HLW management optimization lead us to believe that thorium fuelled reactor systems can play a significant role in the future and deserve further consideration. (authors)

  14. Install Waste Heat Recovery Systems for Fuel-Fired Furnaces (English/Chinese) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    Chinese translation of ITP fact sheet about installing Waste Heat Recovery Systems for Fuel-Fired Furnaces. For most fuel-fired heating equipment, a large amount of the heat supplied is wasted as exhaust or flue gases. In furnaces, air and fuel are mixed and burned to generate heat, some of which is transferred to the heating device and its load. When the heat transfer reaches its practical limit, the spent combustion gases are removed from the furnace via a flue or stack. At this point, these gases still hold considerable thermal energy. In many systems, this is the greatest single heat loss. The energy efficiency can often be increased by using waste heat gas recovery systems to capture and use some of the energy in the flue gas. For natural gas-based systems, the amount of heat contained in the flue gases as a percentage of the heat input in a heating system can be estimated by using Figure 1. Exhaust gas loss or waste heat depends on flue gas temperature and its mass flow, or in practical terms, excess air resulting from combustion air supply and air leakage into the furnace. The excess air can be estimated by measuring oxygen percentage in the flue gases.

  15. Characterization of Irradiated Metal Waste from the Pyrometallurgical Treatment of Used EBR-II Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; K.C. Marsden; W.M. McCartin; S.M. Frank; D.D. Keiser, Jr.; T.S. Yoo; D. Vaden; D.G. Cummings; K.J. Bateman; J. J. Giglio; T. P. O'Holleran; P. A. Hahn; M. N. Patterson

    2013-03-01

    As part of the pyrometallurgical treatment of used Experimental Breeder Reactor-II fuel, a metal waste stream is generated consisting primarily of cladding hulls laden with fission products noble to the electrorefining process. Consolidation by melting at high temperature [1873 K (1600 degrees C)] has been developed to sequester the noble metal fission products (Zr, Mo, Tc, Ru, Rh, Te, and Pd) which remain in the iron-based cladding hulls. Zirconium from the uranium fuel alloy (U-10Zr) is also deposited on the hulls and forms Fe-Zr intermetallics which incorporate the noble metals as well as residual actinides during processing. Hence, Zr has been chosen as the primary indicator for consistency of the metal waste. Recently, the first production-scale metal waste ingot was generated and sampled to monitor Zr content for Fe-Zr intermetallic phase formation and validation of processing conditions. Chemical assay of the metal waste ingot revealed a homogeneous distribution of the noble metal fission products as well as the primary fuel constituents U and Zr. Microstructural characterization of the ingot confirmed the immobilization of the noble metals in the Fe-Zr intermetallic phase.

  16. Design Case Summary. Production of Mixed Alcohols from Municipal Solid Waste via Gasification

    SciTech Connect (OSTI)

    Valkenburg, C.; Zhu, Y.; Walton, C. W.; Thompson, B. L.; Gerber, M. A.; Jones, S. B.; Stevens, D. J.

    2010-03-01

    The Biomass Program develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case establishes cost targets for converting MSW to ethanol and other mixed alcohols via gasification.

  17. Waste stream to energy source: What if America's next big fuel source is

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its trash? | The Ames Laboratory Waste stream to energy source: What if America's next big fuel source is its trash? According to the U.S. Environmental Protection Agency, the United States produced 254 million tons of municipal solid waste in 2013. And though 87 million tons of that material from the landfill was diverted through recycling and composting, what if the nation could do better? What if landfills could become local sources of clean energy production? Better yet, what if all

  18. Integrated data base report--1995: US spent nuclear fuel and radioactive waste inventories, projections, and characteristics

    SciTech Connect (OSTI)

    1996-12-01

    The information in this report summarizes the U.S. Department of Energy (DOE) data base for inventories, projections, and characteristics of domestic spent nuclear fuel and radioactive waste. This report is updated annually to keep abreast of continual waste inventory and projection changes in both the government and commercial sectors. Baseline information is provided for DOE program planning purposes and to support DOE program decisions. Although the primary purpose of this document is to provide background information for program planning within the DOE community, it has also been found useful by state and local governments, the academic community, and some private citizens.

  19. Design Case Summary: Production of Mixed Alcohols from Municipal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via ...

  20. Literature review of intrinsic actinide colloids related to spent fuel waste package release rates

    SciTech Connect (OSTI)

    Zhao, P.; Steward, S.A.

    1997-01-01

    Existence of actinide colloids provides an important mechanism in the migration of radionuclides and will be important in performance of a geologic repository for high-level nuclear waste. Actinide colloids have been formed during long-term unsaturated dissolution of spent fuel by groundwater. This article summarizes a literature search of actinide colloids. This report emphasizes the formation of intrinsic actinide colloids, because they would have the opportunity to form soon after groundwater contact with the spent fuel and before actinide-bearing groundwater reaches the surrounding geologic formations.

  1. Fact #775: April 15, 2013 Top Ten Urban Areas for Fuel Wasted due to Traffic Congestion, 2011

    Broader source: Energy.gov [DOE]

    The top ten urban areas across the U.S. accounted for nearly 40% of the total fuel wasted due to traffic congestion in 2011. Highway congestion caused vehicles in the combined urban areas of New...

  2. Integrated data base report--1996: US spent nuclear fuel and radioactive waste inventories, projections, and characteristics

    SciTech Connect (OSTI)

    1997-12-01

    The Integrated Data Base Program has compiled historic data on inventories and characteristics of both commercial and U.S. Department of Energy (DOE) spent nuclear fuel (SNF) and commercial and U.S. government-owned radioactive wastes. Inventories of most of these materials are reported as of the end of fiscal year (FY) 1996, which is September 30, 1996. Commercial SNF and commercial uranium mill tailings inventories are reported on an end-of-calendar year (CY) basis. All SNF and radioactive waste data reported are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest DOE/Energy Information Administration (EIA) projections of U.S. commercial nuclear power growth and the expected DOE-related and private industrial and institutional activities. The radioactive materials considered, on a chapter-by-chapter basis, are SNF, high-level waste, transuranic waste, low-level waste, uranium mill tailings, DOE Environmental Restoration Program contaminated environmental media, naturally occurring and accelerator-produced radioactive material, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given through FY 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions.

  3. Epsilon Metal Waste Form for Immobilization of Noble Metals from Used Nuclear Fuel

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Strachan, Denis M.; Rohatgi, Aashish; Zumhoff, Mac R.

    2013-10-01

    Epsilon metal (?-metal), an alloy of Mo, Pd, Rh, Ru, and Tc, is being developed as a waste form to treat and immobilize the undissolved solids and dissolved noble metals from aqueous reprocessing of commercial used nuclear fuel. Epsilon metal is an attractive waste form for several reasons: increased durability relative to borosilicate glass, it can be fabricated without additives (100% waste loading), and in addition it also benefits borosilicate glass waste loading by eliminating noble metals from the glass and thus the processing problems related there insolubility in glass. This work focused on the processing aspects of the epsilon metal waste form development. Epsilon metal is comprised of refractory metals resulting in high reaction temperatures to form the alloy, expected to be 1500 - 2000C making it a non-trivial phase to fabricate by traditional methods. Three commercially available advanced technologies were identified: spark-plasma sintering, microwave sintering, and hot isostatic pressing, and investigated as potential methods to fabricate this waste form. Results of these investigations are reported and compared in terms of bulk density, phase assemblage (X-ray diffraction and elemental analysis), and microstructure (scanning electron microscopy).

  4. Waste tires as auxiliary fuel for cement kilns

    SciTech Connect (OSTI)

    Dodds, J.

    1987-01-01

    The subject I have been asked to speak about is the utilization of scrap tires as an auxiliary fuel for cement kilns. My experience with scrap tires began five years ago when we performed a technical and economic evaluation for tire pyrolysis. I work for the Idaho National Engineering Laboratory which is supported by the Department of Energy. My interest in scrap tires continued; in 1984 the Department of Energy and the Portland Cement Association jointly sponsored a conference on the utilization of scrap tires in cement kilns. Most of my remarks today are based upon that conference along with some current information in the US. Mr. Sladek requested that I speak on the combustion process, the progress to date, and the factors that impede or encourage implementation of using scrap tires in cement kilns. For discussion purposes it would help if we had a common understanding of the cement manufacturing process. Cement is made by heating a mixture of finely ground limestone and silica from clay or sand to about 1450/degree/C in a large rotating kiln. The heat causes the limestone to decarbonate and subsequently react with the silica to form calcium silicates. 5 figs.

  5. Overview of mineral waste form development for the electrometallurgical treatment of spent nuclear fuel

    SciTech Connect (OSTI)

    Pereira, C.; Lewis, M.A.; Ackerman, J.P.

    1996-05-01

    Argonne is developing a method to treat spent nuclear fuel in a molten salt electrorefiner. Wastes from this treatment will be converted into metal and mineral forms for geologic disposal. A glass-bonded zeolite is being developed to serve as the mineral waste form that will contain the fission products that accumulate in the electrorefiner salt. Fission products are ion exchanged from the salt into the zeolite A structure. The crystal structure of the zeolite after ion exchange is filled with salt ions. The salt-loaded zeolite A is mixed with glass frit and hot pressed. During hot pressing, the zeolite A may be converted to sodalite which also retains the waste salt. The glass-bonded zeolite is leach resistant. MCC-1 testing has shown that it has a release rate below 1 g/(m{sup 2}day) for all elements.

  6. The need for a characteristics-based approach to radioactive waste classification as informed by advanced nuclear fuel cycles using the fuel-cycle integration and tradeoffs (FIT) model

    SciTech Connect (OSTI)

    Djokic, D. [Department of Nuclear Engineering, University of California, Berkeley, 3115B Etcheverry Hall, Berkeley, CA 94720-1730 (United States); Piet, S.; Pincock, L.; Soelberg, N. [Idaho National Laboratory - INL, 2525 North Fremont Avenue, Idaho Falls, ID 83415 (United States)

    2013-07-01

    This study explores the impact of wastes generated from potential future fuel cycles and the issues presented by classifying these under current classification criteria, and discusses the possibility of a comprehensive and consistent characteristics-based classification framework based on new waste streams created from advanced fuel cycles. A static mass flow model, Fuel-Cycle Integration and Tradeoffs (FIT), was used to calculate the composition of waste streams resulting from different nuclear fuel cycle choices. Because heat generation is generally the most important factor limiting geological repository areal loading, this analysis focuses on the impact of waste form heat load on waste classification practices, although classifying by metrics of radiotoxicity, mass, and volume is also possible. Waste streams generated in different fuel cycles and their possible classification based on the current U.S. framework and international standards are discussed. It is shown that the effects of separating waste streams are neglected under a source-based radioactive waste classification system. (authors)

  7. Processing and properties of a solid energy fuel from municipal solid waste (MSW) and recycled plastics

    SciTech Connect (OSTI)

    Gug, JeongIn Cacciola, David Sobkowicz, Margaret J.

    2015-01-15

    Highlights: • Briquetting was used to produce solid fuels from municipal solid waste and recycled plastics. • Optimal drying, processing temperature and pressure were found to produce stable briquettes. • Addition of waste plastics yielded heating values comparable with typical coal feedstocks. • This processing method improves utilization of paper and plastic diverted from landfills. - Abstract: Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW) is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in higher heating value. Analysis of the post-processing water uptake and compressive strength showed a correlation between density and stability to both mechanical stress and humid environment. Proximate analysis indicated heating values comparable to coal. The results showed that mechanical and moisture uptake stability were improved when the moisture and air contents were optimized. Moreover, the briquette sample composition was similar to biomass fuels but had significant advantages due to addition of waste plastics that have high energy content compared to other waste types. Addition of PP and HDPE presented better benefits than addition of PET due to lower softening temperature and lower oxygen content. It should be noted that while harmful emissions such as dioxins, furans and mercury can result from burning plastics, WTE facilities have been able to control these emissions to meet US EPA standards. This research provides a drop-in coal replacement that reduces demand on landfill space and replaces a significant fraction of fossil-derived fuel with a renewable alternative.

  8. Proceedings: 1989 conference on municipal solid waste as a utility fuel

    SciTech Connect (OSTI)

    Not Available

    1991-02-01

    This volume contains papers presented at the 1989 Electric Power Research Institute (EPRI) Conference on Municipal Solid Waste as a Utility Fuel. The subject areas included are: Utility cofiring experience, refuse-derived fuel production, firing 100% refuse-derived fuel, mass burn technology, fluidized bed combustion, research reports, environmental control technology, and papers on permitting, environmental risk assessment, and the impact of recycling. The conference was held on October 10--12, 1989, and was proceeded by similar conferences held 11/85 (EPRI publication CS-4900-SR, 1986); 1/82 (EPRI publication CS-2723, 1982) and 1/80 (EPRI Publication WS-79-225, 1980). Individual projects are processed separately for on the databases. (MHB)

  9. Evaluation of Options for Permanent Geologic Disposal of Spent NuclearFuel and High-Level Radioactive Waste

    Broader source: Energy.gov [DOE]

    [In Support of a Comprehensive National Nuclear Fuel Cycle Strategy, Volumes I and II (Appendices)] This study provides a technical basis for informing policy decisions regarding strategies for the management and permanent disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) in the United States requiring geologic isolation.

  10. Truck and rail charges for shipping spent fuel and nuclear waste

    SciTech Connect (OSTI)

    McNair, G.W.; Cole, B.M.; Cross, R.E.; Votaw, E.F.

    1986-06-01

    The Pacific Northwest Laboratory developed techniques for calculating estimates of nuclear-waste shipping costs and compiled a listing of representative data that facilitate incorporation of reference shipping costs into varius logistics analyses. The formulas that were developed can be used to estimate costs that will be incurred for shipping spent fuel or nuclear waste by either legal-weight truck or general-freight rail. The basic data for this study were obtained from tariffs of a truck carrier licensed to serve the 48 contiguous states and from various rail freight tariff guides. Also, current transportation regulations as issued by the US Department of Transportation and the Nuclear Regulatory Commission were investigated. The costs that will be incurred for shipping spent fuel and/or nuclear waste, as addressed by the tariff guides, are based on a complex set of conditions involving the shipment origin, route, destination, weight, size, and volume and the frequency of shipments, existing competition, and the length of contracts. While the complexity of these conditions is an important factor in arriving at a ''correct'' cost, deregulation of the transportation industry means that costs are much more subject to negotiation and, thus, the actual fee that will be charged will not be determined until a shipping contract is actually signed. This study is designed to provide the baseline data necessary for making comparisons of the estimated costs of shipping spent fuel and/or nuclear wastes by truck and rail transportation modes. The scope of the work presented in this document is limited to the costs incurred for shipping, and does not include packaging, cask purchase/lease costs, or local fees placed on shipments of radioactive materials.

  11. Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, Task 17208: Final report

    SciTech Connect (OSTI)

    Amoroso, J. W.; Marra, J. C.

    2015-08-26

    A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics) over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).

  12. Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, task 17208: Final report

    SciTech Connect (OSTI)

    Amoroso, J. W.; Marra, J. C.

    2015-08-26

    A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics) over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).

  13. Municipal Solid Waste Combustion : Fuel Testing and Characterization : Task 1 Report, May 30, 1990-October 1, 1990.

    SciTech Connect (OSTI)

    Bushnell, Dwight J.; Canova, Joseph H.; Dadkhah-Nikoo, Abbas.

    1990-10-01

    The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

  14. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  15. Assessment of degradation concerns for spent fuel, high-level wastes, and transuranic wastes in monitored retrievalbe storage

    SciTech Connect (OSTI)

    Guenther, R.J.; Gilbert, E.R.; Slate, S.C.; Partain, W.L.; Divine, J.R.; Kreid, D.K.

    1984-01-01

    It has been concluded that there are no significant degradation mechanisms that could prevent the design, construction, and safe operation of monitored retrievable storage (MRS) facilities. However, there are some long-term degradation mechanisms that could affect the ability to maintain or readily retrieve spent fuel (SF), high-level wastes (HLW), and transuranic wastes (TRUW) several decades after emplacement. Although catastrophic failures are not anticipated, long-term degradation mechanisms have been identified that could, under certain conditions, cause failure of the SF cladding and/or failure of TRUW storage containers. Stress rupture limits for Zircaloy-clad SF in MRS range from 300 to 440/sup 0/C, based on limited data. Additional tests on irradiated Zircaloy (3- to 5-year duration) are needed to narrow this uncertainty. Cladding defect sizes could increase in air as a result of fuel density decreases due to oxidation. Oxidation tests (3- to 5-year duration) on SF are also needed to verify oxidation rates in air and to determine temperatures below which monitoring of an inert cover gas would not be required. Few, if any, changes in the physical state of HLW glass or canisters or their performance would occur under projected MRS conditions. The major uncertainty for HLW is in the heat transfer through cracked glass and glass devitrification above 500/sup 0/C. Additional study of TRUW is required. Some fraction of present TRUW containers would probably fail within the first 100 years of MRS, and some TRUW would be highly degraded upon retrieval, even in unfailed containers. One possible solution is the design of a 100-year container. 93 references, 28 figures, 17 tables.

  16. Radioactive Waste Management at the New Conversion Facility of 'TVEL'{sup R} Fuel Company - 13474

    SciTech Connect (OSTI)

    Indyk, S.I.; Volodenko, A.V.; Tvilenev, K.A.; Tinin, V.V.; Fateeva, E.V.

    2013-07-01

    The project on the new conversion facility construction is being implemented by Joint Stock Company (JSC) 'Siberian Group of Chemical Enterprises' (SGChE) within TVEL{sup R} Fuel Company. The objective is to construct the up-to-date facility ensuring the industrial and environmental safety with the reduced impact on the community and environment in compliance with the Russian new regulatory framework on radioactive waste (RW) management. The history of the SGChE development, as well as the concepts and approaches to RW management implemented by now are shown. The SGChE future image is outlined, together with its objectives and concept on RW management in compliance with the new act 'On radioactive waste management' adopted in Russia in 2011. Possible areas of cooperation with international companies are discussed in the field of RW management with the purpose of deploying the best Russian and world practices on RW management at the new conversion facility. (authors)

  17. Steam-reforming of fossil fuels and wastes to produce energy and chemicals without greenhouse gases

    SciTech Connect (OSTI)

    Galloway, T.R.

    1998-07-01

    Worldwide concern has demanded a re-examination of the energy- and chemical-producing plants that use fossil fuel sources and release large quantities of greenhouse gases. Plant retrofits with steam-reformer/gasifiers will increase plant efficiencies, improve economics and avoid releasing troublesome amounts of greenhouse gases, such as carbon dioxide. In this paper, the authors describe and illustrate the several new steam-reforming/gasification plants that are processing waste streams and fossil fuels. These plants range in size from 1 ton/day to 2,000 tons/day. They are commercial and economically successful. These new concepts can be used to both upgrade fossil plants for improved economics while eliminating the release of greenhouse gases. By aggressively retrofitting old coal plants and sequestering CO{sub 2}, a 15% reduction in 1990 CO{sub 2} emissions can be met by the US by 2010.

  18. Performance assessment of the direct disposal in unsaturated tuff or spent nuclear fuel and high-level waste owned by USDOE: Volume 2, Methodology and results

    SciTech Connect (OSTI)

    Rechard, R.P.

    1995-03-01

    This assessment studied the performance of high-level radioactive waste and spent nuclear fuel in a hypothetical repository in unsaturated tuff. The results of this 10-month study are intended to help guide the Office of Environment Management of the US Department of Energy (DOE) on how to prepare its wastes for eventual permanent disposal. The waste forms comprised spent fuel and high-level waste currently stored at the Idaho National Engineering Laboratory (INEL) and the Hanford reservations. About 700 metric tons heavy metal (MTHM) of the waste under study is stored at INEL, including graphite spent nuclear fuel, highly enriched uranium spent fuel, low enriched uranium spent fuel, and calcined high-level waste. About 2100 MTHM of weapons production fuel, currently stored on the Hanford reservation, was also included. The behavior of the waste was analyzed by waste form and also as a group of waste forms in the hypothetical tuff repository. When the waste forms were studied together, the repository was assumed also to contain about 9200 MTHM high-level waste in borosilicate glass from three DOE sites. The addition of the borosilicate glass, which has already been proposed as a final waste form, brought the total to about 12,000 MTHM.

  19. Initial performance assessment of the disposal of spent nuclear fuel and high-level waste stored at Idaho National Engineering Laboratory. Volume 2: Appendices

    SciTech Connect (OSTI)

    Rechard, R.P.

    1993-12-01

    This performance assessment characterized plausible treatment options conceived by the Idaho National Engineering Laboratory (INEL) for its spent fuel and high-level radioactive waste and then modeled the performance of the resulting waste forms in two hypothetical, deep, geologic repositories: one in bedded salt and the other in granite. The results of the performance assessment are intended to help guide INEL in its study of how to prepare wastes and spent fuel for eventual permanent disposal. This assessment was part of the Waste Management Technology Development Program designed to help the US Department of Energy develop and demonstrate the capability to dispose of its nuclear waste, as mandated by the Nuclear Waste Policy Act of 1982. The waste forms comprised about 700 metric tons of initial heavy metal (or equivalent units) stored at the INEL: graphite spent fuel, experimental low enriched and highly enriched spent fuel, and high-level waste generated during reprocessing of some spent fuel. Five different waste treatment options were studied; in the analysis, the options and resulting waste forms were analyzed separately and in combination as five waste disposal groups. When the waste forms were studied in combination, the repository was assumed to also contain vitrified high-level waste from three DOE sites for a common basis of comparison and to simulate the impact of the INEL waste forms on a moderate-sized repository, The performance of the waste form was assessed within the context of a whole disposal system, using the U.S. Environmental Protection Agency`s Environmental Radiation Protection Standards for Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes, 40 CFR 191, promulgated in 1985. Though the waste form behavior depended upon the repository type, all current and proposed waste forms provided acceptable behavior in the salt and granite repositories.

  20. Integrated Data Base for 1992: US spent fuel and radioactive waste inventories, projections, and characteristics. Revision 8

    SciTech Connect (OSTI)

    Payton, M. L.; Williams, J. T.; Tolbert-Smith, M.; Klein, J. A.

    1992-10-01

    The Integrated Data Base (IDB) Program has compiled current data on inventories and characteristics of commercial spent fuel and both commercial and US government-owned radioactive wastes through December 31, 1991. These data are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest US Department of Energy/Energy Information Administration (DOE/EIA) projections of US commercial nuclear power growth and the expected DOE-related and private industrial and institutional (I/I) activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste, transuranic waste, low-level waste, commercial uranium mill tailings, environmental restoration wastes, commercial reactor and fuel cycle facility decommissioning wastes, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given through the year 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions. In addition, characteristics and current inventories are reported for miscellaneous radioactive materials that may require geologic disposal.

  1. Integrated Data Base report--1993: U.S. spent nuclear fuel and radioactive waste inventories, projections, and characteristics. Revision 10

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The Integrated Data Base Program has compiled historic data on inventories and characteristics of both commercial and DOE spent nuclear fuel; also, commercial and US government-owned radioactive wastes through December 31, 1993. These data are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest US Department of Energy/Energy Information Administration projections of US commercial nuclear power growth and the expected DOE-related and private industrial and institutional activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste, transuranic waste, low-level waste, commercial uranium mill tailings, DOE Environmental Restoration Program wastes, commercial reactor and fuel-cycle facility decommissioning wastes, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given the calendar-year 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions. In addition, characteristics and current inventories are reported for miscellaneous radioactive materials that may require geologic disposal. 256 refs., 38 figs., 141 tabs.

  2. PRELIMINARY STUDY OF CERAMICS FOR IMMOBILIZATION OF ADVANCED FUEL CYCLE REPROCESSING WASTES

    SciTech Connect (OSTI)

    Fox, K.; Billings, A.; Brinkman, K.; Marra, J.

    2010-09-22

    The Savannah River National Laboratory (SRNL) developed a series of ceramic waste forms for the immobilization of Cesium/Lanthanide (CS/LN) and Cesium/Lanthanide/Transition Metal (CS/LN/TM) waste streams anticipated to result from nuclear fuel reprocessing. Simple raw materials, including Al{sub 2}O{sub 3}, CaO, and TiO{sub 2} were combined with simulated waste components to produce multiphase ceramics containing hollandite-type phases, perovskites (particularly BaTiO{sub 3}), pyrochlores, zirconolite, and other minor metal titanate phases. Identification of excess Al{sub 2}O{sub 3} via X-ray Diffraction (XRD) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS) in the first series of compositions led to a Phase II study, with significantly reduced Al{sub 2}O{sub 3} concentrations and increased waste loadings. Three fabrication methodologies were used, including melting and crystallizing, pressing and sintering, and Spark Plasma Sintering (SPS), with the intent of studying phase evolution under various sintering conditions. XRD and SEM/EDS results showed that the partitioning of the waste elements in the sintered materials was very similar, despite varying stoichiometry of the phases formed. The Phase II compositions generally contained a reduced amount of unreacted Al{sub 2}O{sub 3} as identified by XRD, and had phase assemblages that were closer to the initial targets. Chemical composition measurements showed no significant issues with meeting the target compositions. However, volatilization of Cs and Mo was identified, particularly during melting, since sintering of the pressed pellets and SPS were performed at lower temperatures. Partitioning of some of the waste components was difficult to determine via XRD. SEM/EDS mapping showed that those elements, which were generally present in small concentrations, were well distributed throughout the waste forms. Initial studies of radiation damage tolerance using ion beam irradiation at Los Alamos National Laboratory (LANL) showed little if any modification of the material after irradiation. Additional study in this area is needed. Chemical durability was briefly studied using the Product Consistency Test (PCT). Most of the elements measured were retained by the ceramic waste forms, indicating good chemical durability. Cs, Mo, and Rb were released at somewhat higher rates as compared to the matrix components, although benchmark compositions and additional characterization are needed in order to qualify the PCT results.

  3. The economical production of alcohol fuels from coal-derived synthesis gas. Seventh quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    An analysis of the current base cases has been undertaken to determine if the economic status of the proposed alcohol fuels may benefit from economies of scale. This analysis was based on a literature review which suggested that plants of capacities substantially below 5000 metric tons/day are unlikely to be competitive for the bulk production of alcohols for fuel consumption or chemicals manufacture. The preliminary results of this scale up procedure would indicate that the capacity of the current base cases be increased by a factor of eight. This would yield annual production of 4.1 million metric tons and essentially reduce the plant gate cost by approximately 41 percent in both cases. A facility of this size would be the equivalent of a medium sized oil refinery and would be capable of sustaining local market demands for fuel oxygenates. The actual competitiveness of this product with current oxygenates such as MTBE remains to be determined. The alcohol synthesis loop is being used to evaluate optimization procedures which will eventually be used to optimize the entire process. A more detailed design of the synthesis reactor is required, and a preliminary design of this reactor has been completed.

  4. H.R. 5299: A Bill to amend the Internal Revenue Code of 1986 to phase out the tax subsidies for alcohol fuels involving alcohol produced from feedstocks eligible to receive Federal agricultural subsidies. Introduced in the House of Representatives, One Hundred Third Congress, Second Session, November 29, 1994

    SciTech Connect (OSTI)

    1994-12-31

    The report H.R. 5299 is a bill to amend the Internal Revenue Code of 1986 to phase out the tax subsidies of alcohol fuels involving alcohol produced from feedstocks eligible to receive Federal agriculture subsidies. The proposed legislative text is included.

  5. Recycled Water Reuse Permit Renewal Application for the Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

    SciTech Connect (OSTI)

    No Name

    2014-10-01

    ABSTRACT This renewal application for the Industrial Wastewater Reuse Permit (IWRP) WRU-I-0160-01 at Idaho National Laboratory (INL), Materials and Fuels Complex (MFC) Industrial Waste Ditch (IWD) and Industrial Waste Pond (IWP) is being submitted to the State of Idaho, Department of Environmental Quality (DEQ). This application has been prepared in compliance with the requirements in IDAPA 58.01.17, Recycled Water Rules. Information in this application is consistent with the IDAPA 58.01.17 rules, pre-application meeting, and the Guidance for Reclamation and Reuse of Municipal and Industrial Wastewater (September 2007). This application is being submitted using much of the same information contained in the initial permit application, submitted in 2007, and modification, in 2012. There have been no significant changes to the information and operations covered in the existing IWRP. Summary of the monitoring results and operation activity that has occurred since the issuance of the WRP has been included. MFC has operated the IWP and IWD as regulated wastewater land treatment facilities in compliance with the IDAPA 58.01.17 regulations and the IWRP. Industrial wastewater, consisting primarily of continuous discharges of nonhazardous, nonradioactive, routinely discharged noncontact cooling water and steam condensate, periodic discharges of industrial wastewater from the MFC facility process holdup tanks, and precipitation runoff, are discharged to the IWP and IWD system from various MFC facilities. Wastewater goes to the IWP and IWD with a permitted annual flow of up to 17 million gallons/year. All requirements of the IWRP are being met. The Operations and Maintenance Manual for the Industrial Wastewater System will be updated to include any new requirements.

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of 85% or more of alcohol with gasoline; natural gas and liquid fuels domestically produced from natural gas; liquefied petroleum gas (propane); coal-derived liquid fuels; hydrogen; electricity; pure biodiesel (B100); fuels, other than alcohol, derived from biological materials; and P-Series fuels. In addition, the U.S.

  7. Heterogeneous catalytic process for alcohol fuels from syngas. Final technical report

    SciTech Connect (OSTI)

    Dombek, B.D.

    1996-03-01

    The primary objective of this project has been the pursuit of a catalyst system which would allow the selective production from syngas of methanol and isobutanol. It is desirable to develop a process in which the methanol to isobutanol weight ratio could be varied from 70/30 to 30/70. The 70/30 mixture could be used directly as a fuel additive, while, with the appropriate downstream processing, the 30/70 mixture could be utilized for methyl tertiary-butyl ether (MTBE) synthesis. The indirect manufacture of MTBE from a coal derived syngas to methanol and isobutanol process would appear to be a viable solution to MTBE feedstock limitations. To become economically attractive, a process fro producing oxygenates from coal-derived syngas must form these products with high selectivity and good rates, and must be capable of operating with a low-hydrogen-content syngas. This was to be accomplished through extensions of known catalyst systems and by the rational design of novel catalyst systems.

  8. Integrated data base for 1993: US spent fuel and radioactive waste inventories, projections, and characteristics. Revision 9

    SciTech Connect (OSTI)

    Klein, J.A.; Storch, S.N.; Ashline, R.C.

    1994-03-01

    The Integrated Data Base (IDB) Program has compiled historic data on inventories and characteristics of both commercial and DOE spent fuel; also, commercial and U.S. government-owned radioactive wastes through December 31, 1992. These data are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest U.S. Department of Energy/Energy Information Administration (DOE/EIA) projections of U.S. commercial nuclear power growth and the expected DOE-related and private industrial and institutional (I/I) activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste (HLW), transuranic (TRU), waste, low-level waste (LLW), commercial uranium mill tailings, environmental restoration wastes, commercial reactor and fuel-cycle facility decommissioning wastes, and mixed (hazardous and radioactive) LLW. For most of these categories, current and projected inventories are given through the calendar-year (CY) 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions. In addition, characteristics and current inventories are reported for miscellaneous radioactive materials that may require geologic disposal.

  9. Report of the DOD-DOE Workshop on Converting Waste to Energy Using Fuel Cells: Workshop Summary and Action Plan

    Broader source: Energy.gov [DOE]

    This report discusses the results of a January 13, 2011, workshop that focused on utilizing biowaste as an energy feedstock and converting this feedstock into heat and/or power using fuel cells. DOD and DOE are collaborating under a Memorandum of Understanding (MOU) to pursue technology-driven solutions that reduce petroleum use, among other objectives. One of the solutions being explored under the MOU is leveraging waste as feedstock for fuel cell applications in fixed and deployed military operations.

  10. US Department of Energy Storage of Spent Fuel and High Level Waste

    SciTech Connect (OSTI)

    Sandra M Birk

    2010-10-01

    ABSTRACT This paper provides an overview of the Department of Energy's (DOE) spent nuclear fuel (SNF) and high level waste (HLW) storage management. Like commercial reactor fuel, DOE's SNF and HLW were destined for the Yucca Mountain repository. In March 2010, the DOE filed a motion with the Nuclear Regulatory Commission (NRC) to withdraw the license application for the repository at Yucca Mountain. A new repository is now decades away. The default for the commercial and DOE research reactor fuel and HLW is on-site storage for the foreseeable future. Though the motion to withdraw the license application and delay opening of a repository signals extended storage, DOE's immediate plans for management of its SNF and HLW remain the same as before Yucca Mountain was designated as the repository, though it has expanded its research and development efforts to ensure safe extended storage. This paper outlines some of the proposed research that DOE is conducting and will use to enhance its storage systems and facilities.

  11. Radioactive waste shipments to Hanford retrievable storage from Westinghouse Advanced Reactors and Nuclear Fuels Divisions, Cheswick, Pennsylvania

    SciTech Connect (OSTI)

    Duncan, D.; Pottmeyer, J.A.; Weyns, M.I.; Dicenso, K.D.; DeLorenzo, D.S.

    1994-04-01

    During the next two decades the transuranic (TRU) waste now stored in the burial trenches and storage facilities at the Hanford Sits in southeastern Washington State is to be retrieved, processed at the Waste Receiving and Processing Facility, and shipped to the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico for final disposal. Approximately 5.7 percent of the TRU waste to be retrieved for shipment to WIPP was generated by the decontamination and decommissioning (D&D) of the Westinghouse Advanced Reactors Division (WARD) and the Westinghouse Nuclear Fuels Division (WNFD) in Cheswick, Pennsylvania and shipped to the Hanford Sits for storage. This report characterizes these radioactive solid wastes using process knowledge, existing records, and oral history interviews.

  12. Management of Legacy Spent Nuclear Fuel Wastes at the Chalk River Laboratories: The Challenges and Innovative Solutions Implemented - 13301

    SciTech Connect (OSTI)

    Schruder, Kristan; Goodwin, Derek

    2013-07-01

    AECL's Fuel Packaging and Storage (FPS) Project was initiated in 2004 to retrieve, transfer, and stabilize an identified inventory of degraded research reactor fuel that had been emplaced within in-ground 'Tile Hole' structures in Chalk River Laboratories' Waste Management Area in the 1950's and 60's. Ongoing monitoring of the legacy fuel storage conditions had identified that moisture present in the storage structures had contributed to corrosion of both the fuel and the storage containers. This prompted the initiation of the FPS Project which has as its objective to design, construct, and commission equipment and systems that would allow for the ongoing safe storage of this fuel until a final long-term management, or disposition, pathway was available. The FPS Project provides systems and technologies to retrieve and transfer the fuel from the Waste Management Area to a new facility that will repackage, dry, safely store and monitor the fuel for a period of 50 years. All equipment and the new storage facility are designed and constructed to meet the requirements for Class 1 Nuclear Facilities in Canada. (authors)

  13. Thermal performance of a buried nuclear waste storage container storing a hybrid mix of PWR and BWR spent fuel rods

    SciTech Connect (OSTI)

    Johnson, G.L.

    1988-09-01

    Lawrence Livermore National Laboratory will design, model, and test nuclear waste packages for use at the Nevada Nuclear Waste Storage Repository at Yucca Mountain, Nevada. One such package would store lightly packed spent fuel rods from both pressurized and boiling water reactors. The storage container provides the primary containment of the nuclear waste and the spent fuel rod cladding provides secondary containment. A series of transient conduction and radiation heat transfer analyses was run to determine for the first 1000 yr of storage if the temperature of the tuff at the borehole wall ever falls below 97{degree}C and whether the cladding of the stored spent fuel ever exceeds 350{degree}C. Limiting the borehole to temperatures of 97{degree}C or greater helps minimize corrosion by assuring that no condensed water collects on the container. The 350{degree}C cladding limit minimizes the possibility of creep-related failure in the spent fuel rod cladding. For a series of packages stored in a 8 x 30 m borehole grid where each package contains 10-yr-old spent fuel rods generating 4.74 kW or more, the borehole wall stays above 97{degree}C for the full 1000-yr analysis period.

  14. Molecular Breeding Algae For Improved Traits For The Conversion Of Waste To Fuels And Commodities.

    SciTech Connect (OSTI)

    Bagwell, C.

    2015-10-14

    This Exploratory LDRD aimed to develop molecular breeding methodology for biofuel algal strain improvement for applications in waste to energy / commodity conversion technologies. Genome shuffling technologies, specifically protoplast fusion, are readily available for the rapid production of genetic hybrids for trait improvement and have been used successfully in bacteria, yeast, plants and animals. However, genome fusion has not been developed for exploiting the remarkable untapped potential of eukaryotic microalgae for large scale integrated bio-conversion and upgrading of waste components to valued commodities, fuel and energy. The proposed molecular breeding technology is effectively sexual reproduction in algae; though compared to traditional breeding, the molecular route is rapid, high-throughput and permits selection / improvement of complex traits which cannot be accomplished by traditional genetics. Genome fusion technologies are the cutting edge of applied biotechnology. The goals of this Exploratory LDRD were to 1) establish reliable methodology for protoplast production among diverse microalgal strains, and 2) demonstrate genome fusion for hybrid strain production using a single gene encoded trait as a proof of the concept.

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol and Methanol Tax Ethyl alcohol and methyl alcohol motor fuels are taxed at a rate of $0.14 per gallon when used as a motor fuel. Ethyl alcohol is defined as a motor fuel that is typically derived from agricultural products that have been denatured. Methyl alcohol is a motor fuel that is most commonly derived from wood products. (Reference South Dakota Statutes 10-47B-3 and 10-47B-4

  16. 2011 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

    SciTech Connect (OSTI)

    David Frederick

    2012-02-01

    This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (LA-000160-01), for the wastewater reuse site at the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from November 1, 2010 through October 31, 2011. The report contains the following information: (1) Facility and system description; (2) Permit required effluent monitoring data and loading rates; (3) Groundwater monitoring data; (4) Status of special compliance conditions; and (5) Discussion of the facility's environmental impacts. During the 2011 reporting year, an estimated 6.99 million gallons of wastewater were discharged to the Industrial Waste Ditch and Pond which is well below the permit limit of 13 million gallons per year. Using the dissolved iron data, the concentrations of all permit-required analytes in the samples from the down gradient monitoring wells were below the Ground Water Quality Rule Primary and Secondary Constituent Standards.

  17. 2014 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

    SciTech Connect (OSTI)

    Lewis, Mike

    2015-02-01

    This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (WRU-I-0160-01, formerly LA 000160 01), for the wastewater reuse site at the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from November 1, 2013 through October 31, 2014. The report contains the following information; Facility and system description; Permit required effluent monitoring data and loading rates; Groundwater monitoring data; Status of special compliance conditions; Noncompliance issues; and Discussion of the facility’s environmental impacts During the 2014 reporting year, an estimated 10.11 million gallons of wastewater were discharged to the Industrial Waste Ditch and Pond which is well below the permit limit of 17 million gallons per year. The concentrations of all permit-required analytes in the samples from the down gradient monitoring wells were below the applicable Idaho Department of Environmental Quality’s groundwater quality standard levels.

  18. 2012 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

    SciTech Connect (OSTI)

    Mike Lewis

    2013-02-01

    This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (WRU-I-0160-01, formerly LA 000160 01), for the wastewater reuse site at the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from November 1, 2011 through October 31, 2012. The report contains the following information: • Facility and system description • Permit required effluent monitoring data and loading rates • Groundwater monitoring data • Status of special compliance conditions • Discussion of the facility’s environmental impacts During the 2012 reporting year, an estimated 11.84 million gallons of wastewater were discharged to the Industrial Waste Ditch and Pond which is well below the permit limit of 17 million gallons per year. The concentrations of all permit-required analytes in the samples from the down gradient monitoring wells were below the Ground Water Quality Rule Primary and Secondary Constituent Standards.

  19. 2010 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

    SciTech Connect (OSTI)

    David B. Frederick

    2011-02-01

    This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (#LA 000160 01), for the wastewater reuse site at the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from May 1, 2010 through October 31, 2010. The report contains the following information: • Facility and system description • Permit required effluent monitoring data and loading rates • Groundwater monitoring data • Status of special compliance conditions • Discussion of the facility’s environmental impacts During the 2010 partial reporting year, an estimated 3.646 million gallons of wastewater were discharged to the Industrial Waste Ditch and Pond which is well below the permit limit of 13 million gallons per year. The concentrations of all permit-required analytes in the samples from the down gradient monitoring wells were below the Ground Water Quality Rule Primary and Secondary Constituent Standards.

  20. Recovery of solid fuel from municipal solid waste by hydrothermal treatment using subcritical water

    SciTech Connect (OSTI)

    Hwang, In-Hee; Aoyama, Hiroya; Matsuto, Toshihiko; Nakagishi, Tatsuhiro; Matsuo, Takayuki

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Hydrothermal treatment using subcritical water was studied to recover solid fuel from MSW. Black-Right-Pointing-Pointer More than 75% of carbon in MSW was recovered as char. Black-Right-Pointing-Pointer Heating value of char was comparable to that of brown coal and lignite. Black-Right-Pointing-Pointer Polyvinyl chloride was decomposed at 295 Degree-Sign C and 8 MPa and was removed by washing. - Abstract: Hydrothermal treatments using subcritical water (HTSW) such as that at 234 Degree-Sign C and 3 MPa (LT condition) and 295 Degree-Sign C and 8 MPa (HT condition) were investigated to recover solid fuel from municipal solid waste (MSW). Printing paper, dog food (DF), wooden chopsticks, and mixed plastic film and sheets of polyethylene, polypropylene, and polystyrene were prepared as model MSW components, in which polyvinylchloride (PVC) powder and sodium chloride were used to simulate Cl sources. While more than 75% of carbon in paper, DF, and wood was recovered as char under both LT and HT conditions, plastics did not degrade under either LT or HT conditions. The heating value (HV) of obtained char was 13,886-27,544 kJ/kg and was comparable to that of brown coal and lignite. Higher formation of fixed carbon and greater oxygen dissociation during HTSW were thought to improve the HV of char. Cl atoms added as PVC powder and sodium chloride to raw material remained in char after HTSW. However, most Cl originating from PVC was found to converse into soluble Cl compounds during HTSW under the HT condition and could be removed by washing. From these results, the merit of HTSW as a method of recovering solid fuel from MSW is considered to produce char with minimal carbon loss without a drying process prior to HTSW. In addition, Cl originating from PVC decomposes into soluble Cl compound under the HT condition. The combination of HTSW under the HT condition and char washing might improve the quality of char as alternative fuel.

  1. Hazards and scenarios examined for the Yucca Mountain disposal system for spent nuclear fuel and high-level radioactive waste

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hazards and scenarios examined for the Yucca Mountain disposal system for spent nuclear fuel and high-level radioactive waste Rob P. Rechard a,n , Geoff A. Freeze b , Frank V. Perry c a Nuclear Waste Disposal Research & Analysis, Sandia National Laboratories, P.O. Box 5800, Albuquerque 87185-0747, NM, USA b Applied Systems Analysis & Research, Sandia National Laboratories, P.O. Box 5800, Albuquerque 87185-0747, NM, USA c Earth and Environmental Sciences Division, Los Alamos National

  2. A Review and Analysis of European Industrial Experience in Handling LWR Spent Fuel and Vitrified High-Level Waste

    SciTech Connect (OSTI)

    Blomeke, J.O.

    2001-07-10

    The industrial facilities that have been built or are under construction in France, the United Kingdom, Sweden, and West Germany to handle light-water reactor (LWR) spent fuel and canisters of vitrified high-level waste before ultimate disposal are described and illustrated with drawings and photographs. Published information on the operating performance of these facilities is also given. This information was assembled for consideration in planning and design of similar equipment and facilities needed for the Federal Waste Management System in the United States.

  3. Initial performance assessment of the disposal of spent nuclear fuel and high-level waste stored at Idaho National Engineering Laboratory. Volume 1, Methodology and results

    SciTech Connect (OSTI)

    Rechard, R.P.

    1993-12-01

    This performance assessment characterized plausible treatment options conceived by the Idaho National Engineering Laboratory (INEL) for its spent fuel and high-level radioactive waste and then modeled the performance of the resulting waste forms in two hypothetical, deep, geologic repositories: one in bedded salt and the other in granite. The results of the performance assessment are intended to help guide INEL in its study of how to prepare wastes and spent fuel for eventual permanent disposal. This assessment was part of the Waste Management Technology Development Program designed to help the US Department of Energy develop and demonstrate the capability to dispose of its nuclear waste. Although numerous caveats must be placed on the results, the general findings were as follows: Though the waste form behavior depended upon the repository type, all current and proposed waste forms provided acceptable behavior in the salt and granite repositories.

  4. Expected environments in high-level nuclear waste and spent fuel repositories in salt

    SciTech Connect (OSTI)

    Claiborne, H.C.; Rickertsen, L.D., Graham, R.F.

    1980-08-01

    The purpose of this report is to describe the expected environments associated with high-level waste (HLW) and spent fuel (SF) repositories in salt formations. These environments include the thermal, fluid, pressure, brine chemistry, and radiation fields predicted for the repository conceptual designs. In this study, it is assumed that the repository will be a room and pillar mine in a rock-salt formation, with the disposal horizon located approx. 2000 ft (610 m) below the surface of the earth. Canistered waste packages containing HLW in a solid matrix or SF elements are emplaced in vertical holes in the floor of the rooms. The emplacement holes are backfilled with crushed salt or other material and sealed at some later time. Sensitivity studies are presented to show the effect of changing the areal heat load, the canister heat load, the barrier material and thickness, ventilation of the storage room, and adding a second row to the emplacement configuration. The calculated thermal environment is used as input for brine migration calculations. The vapor and gas pressure will gradually attain the lithostatic pressure in a sealed repository. In the unlikely event that an emplacement hole will become sealed in relatively early years, the vapor space pressure was calculated for three scenarios (i.e., no hole closure - no backfill, no hole closure - backfill, and hole closure - no backfill). It was assumed that the gas in the system consisted of air and water vapor in equilibrium with brine. A computer code (REPRESS) was developed assuming that these changes occur slowly (equilibrium conditions). The brine chemical environment is outlined in terms of brine chemistry, corrosion, and compositions. The nuclear radiation environment emphasized in this report is the stored energy that can be released as a result of radiation damage or crystal dislocations within crystal lattices.

  5. REGIONAL BINNING FOR CONTINUED STORAGE OF SPENT NUCLEAR FUEL AND HIGH-LEVEL WASTES

    SciTech Connect (OSTI)

    W. Lee Poe, Jr

    1998-10-01

    In the Continued Storage Analysis Report (CSAR) (Reference 1), DOE decided to analyze the environmental consequences of continuing to store the commercial spent nuclear fuel (SNF) at 72 commercial nuclear power sites and DOE-owned spent nuclear fuel and high-level waste at five Department of Energy sites by region rather than by individual site. This analysis assumes that three commercial facilities pairs--Salem and Hope Creek, Fitzpatrick and Nine-Mile Point, and Dresden and Moms--share common storage due to their proximity to each other. The five regions selected for this analysis are shown on Figure 1. Regions 1, 2, and 3 are the same as those used by the Nuclear Regulatory Commission in their regulatory oversight of commercial power reactors. NRC Region 4 was subdivided into two regions to more appropriately define the two different climates that exist in NRC Region 4. A single hypothetical site in each region was assumed to store all the SNF and HLW in that region. Such a site does not exist and has no geographic location but is a mathematical construct for analytical purposes. To ensure that the calculated results for the regional analyses reflect appropriate inventory, facility and material degradation, and radionuclide transport, the waste inventories, engineered barriers, and environmental conditions for the hypothetical sites were developed from data for each of the existing sites within the given region. Weighting criteria to account for the amount and types of SNF and HLW at each site were used in the development of the environmental data for the regional site, such that the results of the analyses for the hypothetical site were representative of the sum of the results of each actual site if they had been modeled independently. This report defines the actual site data used in development of this hypothetical site, shows how the individual site data was weighted to develop the regional site, and provides the weighted data used in the CSAR analysis. It is divided into Part 1 that defines time-dependent releases from each regional site, Part 2 that defines transport conditions through the groundwater, and Part 3 that defines transport through surface water and populations using the surface waters for drinking.

  6. Functionalized ultra-porous titania nanofiber membranes as nuclear waste separation and sequestration scaffolds for nuclear fuels recycle.

    SciTech Connect (OSTI)

    Liu, Haiqing; Bell, Nelson Simmons; Cipiti, Benjamin B.; Lewis, Tom Goslee,; Sava, Dorina Florentina; Nenoff, Tina Maria

    2012-09-01

    Advanced nuclear fuel cycle concept is interested in reducing separations to a simplified, one-step process if possible. This will benefit from the development of a one-step universal getter and sequestration material so as a simplified, universal waste form was proposed in this project. We have developed a technique combining a modified sol-gel chemistry and electrospinning for producing ultra-porous ceramic nanofiber membranes with controllable diameters and porous structures as the separation/sequestration materials. These ceramic nanofiber materials have been determined to have high porosity, permeability, loading capacity, and stability in extreme conditions. These porous fiber membranes were functionalized with silver nanoparticles and nanocrystal metal organic frameworks (MOFs) to introduce specific sites to capture gas species that are released during spent nuclear fuel reprocessing. Encapsulation into a durable waste form of ceramic composition was also demonstrated.

  7. Assessment of Disposal Options for DOE-Managed High-Level Radioactive Waste and Spent Nuclear Fuel

    Broader source: Energy.gov [DOE]

    The Assessment of Disposal Options for DOE-Managed High-Level Radioactive Waste and Spent Nuclear Fuel report assesses the technical options for the safe and permanent disposal of high-level radioactive waste (HLW) and spent nuclear fuel (SNF) managed by the Department of Energy. Specifically, it considers whether DOE-managed HLW and SNF should be disposed of with commercial SNF and HLW in one geologic repository or whether there are advantages to developing separate geologic disposal pathways for some DOE-managed HLW and SNF. The report recommends that the Department begin implementation of a phased, adaptive, and consent-based strategy with development of a separate mined repository for some DOE-managed HLW and cooler DOE-managed SNF.

  8. Methodology for modeling the devolatilization of refuse-derived fuel from thermogravimetric analysis of municipal solid waste components

    SciTech Connect (OSTI)

    Fritsky, K.J.; Miller, D.L.; Cernansky, N.P.

    1994-09-01

    A methodology was introduced for modeling the devolatilization characteristics of refuse-derived fuel (RFD) in terms of temperature-dependent weight loss. The basic premise of the methodology is that RDF is modeled as a combination of select municipal solid waste (MSW) components. Kinetic parameters are derived for each component from thermogravimetric analyzer (TGA) data measured at a specific set of conditions. These experimentally derived parameters, along with user-derived parameters, are inputted to model equations for the purpose of calculating thermograms for the components. The component thermograms are summed to create a composite thermogram that is an estimate of the devolatilization for the as-modeled RFD. The methodology has several attractive features as a thermal analysis tool for waste fuels. 7 refs., 10 figs., 3 tabs.

  9. Depleted uranium oxides and silicates as spent nuclear fuel waste package fill materials

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1996-09-10

    A new repository waste package (WP) concept for spent nuclear fuel (SNF) is being investigated that uses depleted uranium (DU) to improve performance and reduce the uncertainties of geological disposal of SNF. The WP would be filled with SNF and then filled with depleted uranium (DU) ({approximately}0.2 wt % {sup 235}U) dioxide (UO{sub 2}) or DU silicate-glass beads. Fission products and actinides can not escape the SNF UO{sub 2} crystals until the UO{sub 2} dissolves or is transformed into other chemical species. After WP failure, the DU fill material slows dissolution by three mechanisms: (1) saturation of AT groundwater with DU and suppression of SNF dissolution, (2) maintenance of chemically reducing conditions in the WP that minimize SNF solubility by sacrificial oxidation of DU from the +4 valence state, and (3) evolution of DU to lower-density hydrated uranium silicates. The fill expansion seals the WP from water flow. The DU also isotopically exchanges with SNF uranium as the SNF degrades to reduce long-term nuclear-criticality concerns.

  10. Premium Fuel Production From Mining and Timber Waste Using Advanced Separation and Pelletizing Technologies

    SciTech Connect (OSTI)

    Honaker, R. Q.; Taulbee, D.; Parekh, B. K.; Tao, D.

    2005-12-05

    The Commonwealth of Kentucky is one of the leading states in the production of both coal and timber. As a result of mining and processing coal, an estimated 3 million tons of fine coal are disposed annually to waste-slurry impoundments with an additional 500 million tons stored at a number of disposal sites around the state due to past practices. Likewise, the Kentucky timber industry discards nearly 35,000 tons of sawdust on the production site due to unfavorable economics of transporting the material to industrial boilers for use as a fuel. With an average heating value of 6,700 Btu/lb, the monetary value of the energy disposed in the form of sawdust is approximately $490,000 annually. Since the two industries are typically in close proximity, one promising avenue is to selectively recover and dewater the fine-coal particles and then briquette them with sawdust to produce a high-value fuel. The benefits are i) a premium fuel product that is low in moisture and can be handled, transported, and utilized in existing infrastructure, thereby avoiding significant additional capital investment and ii) a reduction in the amount of fine-waste material produced by the two industries that must now be disposed at a significant financial and environmental price. As such, the goal of this project was to evaluate the feasibility of producing a premium fuel with a heating value greater than 10,000 Btu/lb from waste materials generated by the coal and timber industries. Laboratory and pilot-scale testing of the briquetting process indicated that the goal was successfully achieved. Low-ash briquettes containing 5% to 10% sawdust were produced with energy values that were well in excess of 12,000 Btu/lb. A major economic hurdle associated with commercially briquetting coal is binder cost. Approximately fifty binder formulations, both with and without lime, were subjected to an extensive laboratory evaluation to assess their relative technical and economical effectiveness as binding agents for the briquetting of 90% coal and 10% sawdust blends. Guar gum, wheat starch, and a multi-component formulation were identified as most cost-effective for the production of briquettes targeted for the pulverized-coal market with costs being around $8 per ton of the coal-sawdust blend. REAX/lime and a second multi-component formulation were identified as the most cost-effective for the production of briquettes targeted for the stoker-coal market. Various sources of sawdust generated from different wood types were also investigated to determine their chemical properties and to evaluate their relative performance when briquetted with clean coal to form a premium fuel. The highest heating values, approaching 7,000 Btu/lb, were obtained from oak. Sawdusts from higher-density, red oak, white oak, hickory, and beech trees provided higher quality briquettes relative to their lower-density counterparts. In addition to sawdust type, a number of other parameters were evaluated to characterize their impact on briquette properties. The parameters that exhibited the greatest impact on briquette performance were binder concentration; sawdust concentration and particle size; cure temperature; and ash content. Parameters that had the least impact on briquette properties, at least over the ranges studied, were moisture content, briquetting force, and briquetting dwell time. The continuous production of briquettes from a blend of coal and sawdust was evaluated using a 200 lbs/hr Komarek Model B-100 briquetter. The heating values of briquettes produced by the unit exceeded the goal of the project by a large margin. A significant observation was the role of feed moisture on the stability of the mass flow rate through the briquetter and on briquette strength. Excessive feed moisture levels caused inconsistent or stoppage of material flow through the feed hopper and resulted in the production of variable-quality briquettes. Obviously, the limit on feed moisture content has a significant impact on the economics of coal-sawdust briquetting since it will ultimately dictate dewatering costs. Interestingly, the maximum feed moisture was found to be dependent to some extent on the binder type with molasses-containing blends being difficult to feed when the moisture content approached 12% while guar gum blends flowed consistently at moisture levels as high as 15% by weight. Due to the low ash and moisture contents of the coal-sawdust briquettes, a production increase of about 50 tons/hr would potentially be realized at a 1,400 ton/hr preparation plant. The overall capital cost of a 50 ton/hr flotation and briquetting addition was estimated to be around $8 million. Based on a conservative briquetting operating cost of $12/ton, the annual profit before taxes was approximated to be $4 million thereby indicating a return on investment in about 2 years. The internal rate of return based on a 10 year life was an attractive 43%.

  11. Use of depleted uranium silicate glass to minimize release of radionuclides from spent nuclear fuel waste packages

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1996-01-20

    A Depleted Uranium Silicate Container Backfill System (DUSCOBS) is proposed that would use small, isotopically-depleted uranium silicate glass beads as a backfill material inside repository waste packages containing spent nuclear fuel (SNF). The uranium silicate glass beads would fill the void space inside the package including the coolant channels inside SNF assemblies. Based on preliminary analysis, the following benefits have been identified. DUSCOBS improves repository waste package performance by three mechanisms. First, it reduces the radionuclide releases from SNF when water enters the waste package by creating a local uranium silicate saturated groundwater environment that suppresses (a) the dissolution and/or transformation of uranium dioxide fuel pellets and, hence, (b) the release of radionuclides incorporated into the SNF pellets. Second, the potential for long-term nuclear criticality is reduced by isotopic exchange of enriched uranium in SNF with the depleted uranium (DU) in the glass. Third, the backfill reduces radiation interactions between SNF and the local environment (package and local geology) and thus reduces generation of hydrogen, acids, and other chemicals that degrade the waste package system. Finally, DUSCOBS provides a potential method to dispose of significant quantities of excess DU from uranium enrichment plants at potential economic savings. DUSCOBS is a new concept. Consequently, the concept has not been optimized or demonstrated in laboratory experiments.

  12. The Potential Role of the Thorium Fuel Cycle in Reducing the Radiotoxicity of Long-Lived Waste - 13477

    SciTech Connect (OSTI)

    Hesketh, Kevin; Thomas, Mike

    2013-07-01

    The thorium (or more accurately the Th-232/U-233) fuel cycle is attracting growing interest world wide and one reason for this is the reduced radiotoxicity of long-lived waste, with the Th- 232/U-233 fuel cycle often being justified partly on the grounds of low radiotoxicity for long cooling times. This paper considers the evolution of heavy metal radiotoxicity in a Molten Salt Fast Reactor (MSFR) operating a closed Th-232/U-233 cycle during different operational phases. The paper shows that even in the MSFR core, the equilibrium radiotoxicity of the thorium fuel cycle is only reached after almost 100 years of operation. MSFR was chosen because it has many theoretical advantages that favour the Th-232/U-233 fuel cycle. Conventional solid fuel systems would be expected to behave similarly, but with even longer timescales and therefore the MSFR cycle can be used to define the limits of what is practically achievable. The results are used to argue the case that a fair approach to justifying the Th-232/U-233 breeder cycle should not quote the long term equilibrium radiotoxicity, but rather the somewhat less favourable radiotoxicity that could be achieved within the operational lifetime of the first generation of Th-232/U-233 breeder reactors. (authors)

  13. Report on interim storage of spent nuclear fuel. Midwestern high-level radioactive waste transportation project

    SciTech Connect (OSTI)

    Not Available

    1993-04-01

    The report on interim storage of spent nuclear fuel discusses the technical, regulatory, and economic aspects of spent-fuel storage at nuclear reactors. The report is intended to provide legislators state officials and citizens in the Midwest with information on spent-fuel inventories, current and projected additional storage requirements, licensing, storage technologies, and actions taken by various utilities in the Midwest to augment their capacity to store spent nuclear fuel on site.

  14. Stationary Fuel Cell System Composite Data Products: Data through...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Equipment, Waste Heat Recovery Costs, ... Fuel Cell CHP Fuel Cell Electric Gas Turbine Internal Combustion ... Equipment, Waste Heat Recovery Costs, ...

  15. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  16. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  17. 2013 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

    SciTech Connect (OSTI)

    Mike Lewis

    2014-02-01

    This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (WRU-I-0160-01, formerly LA 000160 01), for the wastewater reuse site at the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from November 1, 2012 through October 31, 2013. The report contains the following information: • Facility and system description • Permit required effluent monitoring data and loading rates • Groundwater monitoring data • Status of special compliance conditions • Discussion of the facility’s environmental impacts During the 2013 reporting year, an estimated 9.64 million gallons of wastewater were discharged to the Industrial Waste Ditch and Pond which is well below the permit limit of 17 million gallons per year. The concentrations of all permit-required analytes in the samples from the down gradient monitoring wells were below the applicable Idaho Department of Environmental Quality’s groundwater quality standard levels.

  18. Department of Energy Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs draft environmental impact statement. Volume 1, Appendix B: Idaho National Engineering Laboratory Spent Nuclear Fuel Management Program

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    The US Department of Energy (DOE) has prepared this report to assist its management in making two decisions. The first decision, which is programmatic, is to determine the management program for DOE spent nuclear fuel. The second decision is on the future direction of environmental restoration, waste management, and spent nuclear fuel management activities at the Idaho National Engineering Laboratory. Volume 1 of the EIS, which supports the programmatic decision, considers the effects of spent nuclear fuel management on the quality of the human and natural environment for planning years 1995 through 2035. DOE has derived the information and analysis results in Volume 1 from several site-specific appendixes. Volume 2 of the EIS, which supports the INEL-specific decision, describes environmental impacts for various environmental restoration, waste management, and spent nuclear fuel management alternatives for planning years 1995 through 2005. This Appendix B to Volume 1 considers the impacts on the INEL environment of the implementation of various DOE-wide spent nuclear fuel management alternatives. The Naval Nuclear Propulsion Program, which is a joint Navy/DOE program, is responsible for spent naval nuclear fuel examination at the INEL. For this appendix, naval fuel that has been examined at the Naval Reactors Facility and turned over to DOE for storage is termed naval-type fuel. This appendix evaluates the management of DOE spent nuclear fuel including naval-type fuel.

  19. Public acceptability of the use of gamma rays from spent nuclear fuel as a hazardous waste treatment process

    SciTech Connect (OSTI)

    Mincher, B.J.; Wells, R.P.; Reilly, H.J.

    1992-01-01

    Three methods were used to estimate public reaction to the use of gamma irradiation of hazardous wastes as a hazardous waste treatment process. The gamma source of interest is spent nuclear fuel. The first method is Benefit-Risk Decision Making, where the benefits of the proposed technology are compared to its risks. The second analysis compares the proposed technology to the other, currently used nuclear technologies and estimates public reaction based on that comparison. The third analysis is called Analysis of Public Consent, and is based on the professional methods of the Institute for Participatory Management and Planning. The conclusion of all three methods is that the proposed technology should not result in negative public reaction sufficient to prevent implementation.

  20. Fuel Options

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cycle Research & Development Fuel Cycle Research & Development Fuel Cycle Research & Development The mission of the Fuel Cycle Research and Development (FCRD) program is to conduct research and development to help develop sustainable fuel cycles, as described in the Nuclear Energy Research and Development Roadmap. Sustainable fuel cycle options are those that improve uranium resource utilization, maximize energy generation, minimize waste generation, improve safety, and limit

  1. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

    SciTech Connect (OSTI)

    1999-03-01

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

  2. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fueling the Next Generation of Vehicle Technology Fueling the Next Generation of Vehicle Technology February 6, 2013 - 11:20am Addthis Professor Jack Brouwer, Associate Director and Chief Technology Officer of the National Fuel Cell Research Center, points out the tri-generation facility that uses biogas from Orange County Sanitation District’s wastewater treatment plant to produce hydrogen, heat and power. | Photo courtesy of the Energy Department. Professor Jack Brouwer, Associate

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blend Requirement Suppliers that import gasoline for sale in North Carolina must offer fuel that is not pre-blended with fuel alcohol but that is suitable for future blending. Future contract provisions that restrict distributors or retailers from blending gasoline with fuel alcohol are void. (Reference North Carolina General Statutes 75-90, 105-449.60

  4. Municipal waste combustion assessment: Fossil fuel co-firing. Final report, October 1988-July 1989

    SciTech Connect (OSTI)

    Landrum, V.J.; Barton, R.G.

    1989-07-01

    The report identifies refuse derived fuel (RDF) processing operations and various RDF types; describes such fossil fuel co-firing techniques as coal fired spreader stokers, pulverized coal wall fired boilers, pulverized coal tangentially fired boilers, and cyclone fired boilers; and describes the population of coal fired boilers that currently co-fire RDF, have previously co-fired RDF but have ceased to do so, and have been used in RDF co-firing demonstrations. (Fossil fuel co-firing, defined as the combustion of RDF with another fuel (usually coal) in a device designed primarily to burn the other fuel, is generally confined to commercial and utility boilers.) Model plants are developed and good combustion practices are recommended.

  5. Hydrogen Gas Generation Model for Fuel Based Remote Handled TRU Waste Stored at INEEL

    SciTech Connect (OSTI)

    Soli T. Khericha; Rajiv N. Bhatt; Kevin Liekhus

    2003-02-01

    The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

  6. Progression of performance assessment modeling for the Yucca Mountain disposal system for spent nuclear fuel and high-level radioactive waste

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Progression of performance assessment modeling for the Yucca Mountain disposal system for spent nuclear fuel and high-level radioactive waste Rob P. Rechard a,n , Michael L. Wilson b , S. David Sevougian c a Nuclear Waste Disposal Research & Analysis, Sandia National Laboratories, Albuquerque, NM 87185-0747, USA b Systems Analysis/Operations Research, Sandia National Laboratories, Albuquerque, NM 87185-1138, USA c Applied Systems Analysis & Research, Sandia National Laboratories,

  7. Intact and Degraded Criticality Calculations for the Codisposal of Shippingport LWBR Spent Nuclear Fuel in a Waste Package

    SciTech Connect (OSTI)

    L.M. Montierth

    2000-09-15

    The objective of this calculation is to characterize the nuclear criticality safety concerns associated with the codisposal of the U.S. Department of Energy's (DOE) Shippingport Light Water Breeder Reactor (SP LWBR) Spent Nuclear Fuel (SNF) in a 5-Defense High-Level Waste (5-DHLW) Waste Package (WP), which is to be placed in a Monitored Geologic Repository (MGR). The scope of this calculation is limited to the determination of the effective neutron multiplication factor (K{sub eff}) for intact- and degraded-mode internal configurations of the codisposal WP containing Shippingport LWBR seed-type assemblies. The results of this calculation will be used to evaluate criticality issues and support the analysis that is planed to be performed to demonstrate the viability of the codisposal concept for the MGR. This calculation is associated with the waste package design and was performed in accordance with the DOE SNF Analysis Plan for FY 2000 (See Ref. 22). The document has been prepared in accordance with the Administrative Procedure AP-3.12Q, Calculations (Ref. 23).

  8. A review of Title V operating permit application requirements caused by the use of waste-derived fuel at cement plants

    SciTech Connect (OSTI)

    Yarmac, R.F.

    1994-12-31

    The Clean Air Act Amendments of 1990 required the USEPA to establish a comprehensive operating permit program which is being administered by the states. Most major air pollution sources will be required to submit operating permit applications by November 15, 1995 or earlier. Portland cement plants that burn waste-derived fuel face some special permitting problems that need to be addressed during the permit application process. This paper presents a brief summary of the Title V application with special emphasis on the permitting requirements incurred by the utilization of waste fuel at cement plants.

  9. International fuel cycle and waste management technology exchange activities sponsored by the United States Department of Energy: FY 1982 evaluation report

    SciTech Connect (OSTI)

    Lakey, L.T.; Harmon, K.M.

    1983-02-01

    In FY 1982, DOE and DOE contractor personnel attended 40 international symposia and conferences on fuel reprocessing and waste management subjects. The treatment of high-level waste was the topic most often covered in the visits, with geologic disposal and general waste management also being covered in numerous visits. Topics discussed less frequently inlcude TRU/LLW treatment, airborne waste treatment, D and D, spent fuel handling, and transportation. The benefits accuring to the US from technology exchange activities with other countries are both tangible, e.g., design of equipment, and intangible, e.g., improved foreign relations. New concepts initiated in other countries, particularly those with sizable nuclear programs, are beginning to appear in US efforts in growing numbers. The spent fuel dry storage concept originating in the FRG is being considered at numerous sites. Similarly, the German handling and draining concepts for the joule-heated ceramic melter used to vitrify wastes are being incorporated in US designs. Other foreigh technologies applicable in the US include the slagging incinerator (Belgium), the SYNROC waste form (Australia), the decontamination experience gained in decommissioning the Eurochemic reprocessing plant (Belgium), the engineered surface storage of low- and intermediate-level waste (Belgium, FRG, France), the air-cooled storage of vitrified high-level waste (France, UK), waste packaging (Canada, FRG, Sweden), disposal in salt (FRG), disposal in granite (Canada, Sweden), and sea dumping (UK, Belgium, The Netherlands, Switzerland). These technologies did not necessarily originated or have been tried in the US but for various reasons are now being applied and extended in other countries. This growing nuclear technological base in other countires reduces the number of technology avenues the US need follow to develop a solid nuclear power program.

  10. Minimally refined biomass fuel

    DOE Patents [OSTI]

    Pearson, Richard K.; Hirschfeld, Tomas B.

    1984-01-01

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  11. Alcohol injection cuts diesel consumption on turbocharged tractors

    SciTech Connect (OSTI)

    Edson, D.V.

    1980-07-21

    M and W Gear Co. of Gibson City, IL, are marketing a new alcohol- injection system that permits turbocharged diesel engines to burn alcohol and claims to cut diesel consumption by 30% and more. The alcohol fuel, a blend of alcohol and water, does not meet the diesel fuel until the alcohol has been atomized and sprayed through the intake manifold into the cylinders. It permits farmers to use home- still-produced ethanol without the added expense of refining to anhydrous composition.

  12. DEVELOPMENT OF CRYSTALLINE CERAMICS FOR IMMOBILIZATION OF ADVANCED FUEL CYCLE REPROCESSING WASTES

    SciTech Connect (OSTI)

    Fox, K.; Brinkman, K.

    2011-09-22

    The Savannah River National Laboratory (SRNL) is developing crystalline ceramic waste forms to incorporate CS/LN/TM high Mo waste streams consisting of perovskite, hollandite, pyrochlore, zirconolite, and powellite phase assemblages. Simple raw materials, including Al{sub 2}O{sub 3}, CaO, and TiO{sub 2} were combined with simulated waste components to produce multiphase crystalline ceramics. Fiscal Year 2011 (FY11) activities included (i) expanding the compositional range by varying waste loading and fabrication of compositions rich in TiO{sub 2}, (ii) exploring the processing parameters of ceramics produced by the melt and crystallize process, (iii) synthesis and characterization of select individual phases of powellite and hollandite that are the target hosts for radionuclides of Mo, Cs, and Rb, and (iv) evaluating the durability and radiation stability of single and multi-phase ceramic waste forms. Two fabrication methods, including melting and crystallizing, and pressing and sintering, were used with the intent of studying phase evolution under various sintering conditions. An analysis of the XRD and SEM/EDS results indicates that the targeted crystalline phases of the FY11 compositions consisting of pyrochlore, perovskite, hollandite, zirconolite, and powellite were formed by both press and sinter and melt and crystallize processing methods. An evaluation of crystalline phase formation versus melt processing conditions revealed that hollandite, perovskite, zirconolite, and residual TiO{sub 2} phases formed regardless of cooling rate, demonstrating the robust nature of this process for crystalline phase development. The multiphase ceramic composition CSLNTM-06 demonstrated good resistance to proton beam irradiation. Electron irradiation studies on the single phase CaMoO{sub 4} (a component of the multiphase waste form) suggested that this material exhibits stability to 1000 years at anticipated self-irradiation doses (2 x 10{sup 10}-2 x 10{sup 11} Gy), but that its stability may be rate dependent, therefore limiting the activity of the waste for which it can be employed. Overall, these preliminary results indicate good radiation damage tolerance for the crystalline ceramic materials. The PCT results showed that, for all of the waste forms tested, the normalized release values for most of the elements measured, including all of the lanthanides and noble metals, were either very small or below the instrument detection limits. Elevated normalized release values were measured only for Cs, Mo, and Rb. It is difficult to draw further conclusions from these data until a benchmark material is developed for the PCT with this type of waste form. Calcined, simulated CS/LN/TM High Mo waste without additives had relatively low normalized release values for Cs, Mo, and Rb. A review of the chemical composition data for this sample showed that these elements were well retained after the calcination. Therefore, it will be useful to further characterize the calcined material to determine what form these elements are in after calcining. This, along with single phase studies on Cs containing crystal structures such as hollandite, should provide insight into the most ideal phases to incorporate these elements to produce a durable waste form.

  13. In Situ Grouting of Liquid Waste Disposal Trenches and Experimental Reactor Fuel Disposal Wells at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Johnson, Ch.; Cange, J.; Lambert, R. [Bechtel Jacobs Company, LLC, Oak Ridge, TN (United States); Trujillo, E. [BWXT Pantex, LLC, Amarillo, TX (United States); Julius, J. [U.S. DOE, Oak Ridge Operations Office, Oak Ridge, TN (United States)

    2008-07-01

    In the early to mid-1960's, liquid low-level wastes (LLLW) generated at Oak Ridge National Laboratory were disposed of in specially-constructed, gravel-filled trenches within the Melton Valley watershed at the lab. The initial selected remedy for Trenches 5 and 7 was in situ vitrification; however, an amendment to the record of decision changed the remedy to in situ grouting of the trenches. The work was accomplished by filling the void space within the crushed stone section of each trench with cementitious grout. The contaminated soil surrounding the trenches (1-m perimeter) was then grouted with acrylamide grout. At the HRE fuel wells, a 1-m ring of soil surrounding the fuel wells was grouted with acrylamide. The results of the hydraulic conductivity tests ranged from 4.74 x 10{sup -6} to 3.60 x 10{sup -7} cm/sec, values that were well below the 1 x 10{sup -5} cm/sec design criterion. In summary: The ISG Project was conducted to decrease hydraulic conductivity and thereby decrease water flow and contaminate migration from the area of the trenches. The initial remedy for Trenches 5 and 7 in the Melton Valley ROD was for in situ vitrification of the trench matrix. The remedy was changed to in situ grouting of the trenches and HRE fuel wells through an amendment to the ROD after moisture was found in the trenches. The grouting of the trenches was accomplished by filling the void space within the crushed stone section of each trench with cementitious grout. The contaminated soil surrounding the trenches (1-m perimeter) was then grouted with acrylamide grout to further reduce water infiltration. Soil backfill above each of the seven HRE fuel wells was removed to a depth of approximately 1 m by augering, and the soils were replaced with a cement plug to prevent water infiltration from migrating down the original borehole. Soil surrounding the fuel wells was then grouted with acrylamide to ensure water infiltration through the HRE fuel wells is prevented. A summary of the quantities used is shown. After completion of grouting, in-situ hydraulic conductivities of the grouted materials were measured to verify attainment of the design objective. The areas were then covered with multi-layer caps as part of the MV hydrologic isolation project. (authors)

  14. Recovery of cesium and palladium from nuclear reactor fuel processing waste

    DOE Patents [OSTI]

    Campbell, David O.

    1976-01-01

    A method of recovering cesium and palladium values from nuclear reactor fission product waste solution involves contacting the solution with a source of chloride ions and oxidizing palladium ions present in the solution to precipitate cesium and palladium as Cs.sub.2 PdCl.sub.6.

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Labeling Requirements Alternative fuel dispensers must be labeled with information to help consumers make informed decisions about fueling a vehicle, including the name of the fuel and the minimum percentage of the main component of the fuel. Labels may also list the percentage of other fuel components. This requirement applies to, but is not limited to, the following fuel types: methanol, denatured ethanol, and/or other alcohols; mixtures containing 85% or more by volume of

  16. Department of Energy Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs Draft Environmental Impact Statement. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This document analyzes at a pregrammatic level the potential environmental consequences over the next 40 years of alternatives related to the transportation, receipt, processing, and storage of spent nuclear fuel under the responsibility of the US Department of Energy. It also analyzes the site-specific consequences of the Idaho National Engineering Laboratory sitewide actions anticipated over the next 10 years for waste and spent nuclear fuel management and environmental restoration. For pregrammatic spent nuclear fuel management, this document analyzes alternatives of no action, decentralization, regionalization, centralization and the use of the plans that existed in 1992/1993 for the management of these materials. For the Idaho National Engineering Laboratory, this document analyzes alternatives of no action, ten-year plan, minimum and maximum treatment, storage, and disposal of US Department of Energy wastes.

  17. Department of Energy Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs Draft Environmental Impact Statement. Volume 2, Part A

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This document analyzes at a programmatic level the potential environmental consequences over the next 40 years of alternatives related to the transportation, receipt, processing, and storage of spent nuclear fuel under the responsibility of the US Department of Energy. It also analyzes the site-specific consequences of the Idaho National Engineering Laboratory sitewide actions anticipated over the next 10 years for waste and spent nuclear fuel management and environmental restoration. For programmatic spent nuclear fuel management this document analyzes alternatives of no action, decentralization, regionalization, centralization and the use of the plans that existed in 1992/1993 for the management of these materials. For the Idaho National Engineering Laboratory, this document analyzes alternatives of no action, ten-year plan, minimum and maximum and maximum treatment, storage, and disposal of US Department of Energy wastes.

  18. Summary of results from the Series 2 and Series 3 NNWSI [Nevada Nuclear Waste Storage Investigations] bare fuel dissolution tests

    SciTech Connect (OSTI)

    Wilson, C.N.

    1987-11-01

    The Nevada Nuclear Waste Storage Investigations (NNWSI) Project is studying dissolution and radionuclide release behavior of spent nuclear fuel in Nevada Test Site groundwater. Specimens were tested for multiple cycles in J-13 well water. The Series 2 tests were run in unsealed silica vessels under ambient hot cell air (25{sup 0}C) for five cycles for a total of 34 months. The Series 3 tests were run in sealed stainless steel vessels at 25{sup 0}C and 85{sup 0}C for three cycles for a total of 15 months. Selected summary results from Series 2 and Series 3 tests with bare fuel specimens are reported. Uranium concentrations in later test cycles ranged from 1 to 2 {mu}g/ml in the Series 2 Tests versus about 0.1 to 0.4 {mu}g/ml in Series 3 with the lowest concentrations occurring in the 85{sup 0}C tests. Preferential release of fission products Cs, I, Sr and Tc, and activation product C-14, was indicated relative to the actinides. Tc-99 and Cs-137 activities measured in solution after Cycle 1 increased linearly with time, with the rate of increase greater at 85{sup 0}C than at 25{sup 0}C. 8 refs., 8 figs., 3 tabs.

  19. Systems simulation of cotton gin waste as a supplemental fuel in a coal powered generating plant

    SciTech Connect (OSTI)

    Parnell, C.B.; Grubaugh, E.K.; Johnston, M.T.; Ladd, K.L.

    1981-01-01

    A systems simulation model of gin trash use at a Lamb County, Texas, power plant was developed. The model is being used to study gin trash supply, both quantity and transportation, fixed and variable cost, and economic benefit/costs of gin trash utilization. Preliminary results indicate the positive feasibility of using gin trash as a supplemental fuel in a coal fired power plant. (MHR)

  20. Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth

    Broader source: Energy.gov [DOE]

    Discusses results of cold- and hot-start transient tests using gasoline and 3 alcohol-gasoline blends (50% and 85% ethanol, and 83% iso-butanol)

  1. Nuclear Waste Challenge | Department of Energy

    Office of Environmental Management (EM)

    Consent-Based Siting Nuclear Waste Challenge Nuclear Waste Challenge Approximate locations of the current sites where spent nuclear fuel and high-level radioactive waste are ...

  2. Briquetting today`s waste for tomorrow`s fuel and resources

    SciTech Connect (OSTI)

    Ford, G.W. Jr.; Lambert, R.C.; Young, K.M.

    1995-09-01

    Environmental Technologies Group International (ETG) has developed technology that appears to allow revert materials to be successfully recycled in the steelmaking process. ETG has presented research indicating revert materials can be processed to maintain thermal integrity, thus enabling them to be reduced in the steelmaking process. Additional research has been undertaken to define briquetted revert material performance in an electric arc furnace environment. Briquettes made from several revert materials with a variety of component spectrums were introduced into an experimental arc furnace to determine reduction rates and iron recovery. It was found that the iron recovery was dependent on the iron content of the revert, but all reverts yielded between 70 to 80% of the iron units present. Coke was used in the briquettes as a fuel and a carbon source for reduction. It was found that a minimum level of coke at approximately 20% was required to provide sufficient fuel and carbon to recover the available iron units. Iron recovered form the revert materials ranged from 92 to 96% with varying amounts of carbon and other materials present.

  3. Locations of spent nuclear fuel and high-level radioactive waste ultimately destined for geologic disposal

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    Since the late 1950s, Americans have come to rely more and more on energy generated from nuclear reactors. Today, 109 commercial nuclear reactors supply over one-fifth of the electricity used to run our homes, schools, factories, and farms. When the nuclear fuel can no longer sustain a fission reaction in these reactors it becomes `spent` or `used` and is removed from the reactors and stored onsite. Most of our Nation`s spent nuclear fuel is currently being stored in specially designed deep pools of water at reactor sites; some is being stored aboveground in heavy thick-walled metal or concrete structures. Sites currently using aboveground dry storage systems include Virginia Power`s Surry Plant, Carolina Power and Light`s H.B. Robinson Plant, Duke Power`s Oconee Nuclear Station, Colorado Public Service Company`s shutdown reactor at Fort St. Vrain, Baltimore Gas and Electric`s Calvert Cliffs Plant, and Michigan`s Consumer Power Palisades Plant.

  4. Materials and Fuels Complex Hazardous Waste Management Act/Resource Conservation and Recovery Act Storage and Treatment Permit Reapplication, Environmental Protection Agency Number ID4890008952

    SciTech Connect (OSTI)

    Holzemer, Michael J.; Hart, Edward

    2015-04-01

    Hazardous Waste Management Act/Resource Conservation and Recovery Act Storage and Treatment Permit Reapplication for the Idaho National Laboratory Materials and Fuels Complex Hazardous Waste Management Act/Resource Conservation and Recovery Act Partial Permit, PER-116. This Permit Reapplication is required by the PER-116 Permit Conditions I.G. and I.H., and must be submitted to the Idaho Department of Environmental Quality in accordance with IDAPA 58.01.05.012 [40 CFR §§ 270.10 and 270.13 through 270.29].

  5. The production of fuels and chemicals from food processing wastes using a novel fermenter separator

    SciTech Connect (OSTI)

    Dale, M.C.; Venkatesh, K.V.; Choi, Hojoon; Moelhman, M.; Saliceti, L.; Okos, M.R.; Wankat, P.C.

    1991-12-01

    During 1991, considerable progress was made on the waste utilization project. Two small Wisconsin companies have expressed an interest in promoting and developing the ICRS technology. Pilot plant sites at (1) Hopkinton, IA, for a sweet whey plant, and Beaver Dam WI, for an acid whey site have been under development siting ICRS operations. The Hopkinton, IA site is owned and operated by Permeate Refining Inc., who have built a batch ethanol plant across the street from Swiss Valley Farms cheddar cheese operations. Permeate from Swiss Valley is piped across to PRI. PRI has signed a contract to site a 300--500,000 gallon/yr to ICRS pilot plant. They feel that the lower labor, lower energy, continuous process offered by the ICRS will substantially improve their profitability. Catalytics, Inc, is involved with converting whey from a Kraft cream cheese operation to ethanol and yeast. A complete project including whey concentration, sterilization, and yeast growth has been designed for this site. Process design improvements with the ICRS focussed on ethanol recovery techniques during this year's project. A solvent absorption/extractive distillation (SAED) process has been developed which offers the capability of obtaining an anhydrous ethanol product from vapors off 3 to 9% ethanol solutions using very little energy for distillation. Work on products from waste streams was also performed. a. Diacetyl as a high value flavor compound was very successfully produced in a Stirred Tank Reactor w/Separation. b. Yeast production from secondary carbohydrates in the whey, lactic acid, and glycerol was studied. c. Lactic acid production from cellulose and lactose studies continued. d. Production of anti-fungal reagents by immobilized plant cells; Gossypol has antifungal properties and is produced by G. arboretum.

  6. Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2012-12-31

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: • Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas • Utilizing proven and reliable technology and equipment • Maximizing electrical efficiency • Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill • Maximizing equipment uptime • Minimizing water consumption • Minimizing post-combustion emissions • The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWh’s of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

  7. DOCUMENTATION OF NATIONAL WEATHER CONDITIONS AFFECTING LONG-TERM DEGRADATION OF COMMERCIAL SPENT NUCLEAR FUEL AND DOE SPENT NUCLEAR FUEL AND HIGH-LEVEL WASTE

    SciTech Connect (OSTI)

    W. L. Poe, Jr.; P.F. Wise

    1998-11-01

    The U.S. Department of Energy (DOE) is preparing a proposal to construct, operate 2nd monitor, and eventually close a repository at Yucca Mountain in Nye County, Nevada, for the geologic disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW). As part of this effort, DOE has prepared a viability assessment and an assessment of potential consequences that may exist if the repository is not constructed. The assessment of potential consequences if the repository is not constructed assumes that all SNF and HLW would be left at the generator sites. These include 72 commercial generator sites (three commercial facility pairs--Salem and Hope Creek, Fitzpatrick and Nine Mile Point, and Dresden and Morris--would share common storage due to their close proximity to each other) and five DOE sites across the country. DOE analyzed the environmental consequences of the effects of the continued storage of these materials at these sites in a report titled Continued Storage Analysis Report (CSAR; Reference 1 ) . The CSAR analysis includes a discussion of the degradation of these materials when exposed to the environment. This document describes the environmental parameters that influence the degradation analyzed in the CSAR. These include temperature, relative humidity, precipitation chemistry (pH and chemical composition), annual precipitation rates, annual number of rain-days, and annual freeze/thaw cycles. The document also tabulates weather conditions for each storage site, evaluates the degradation of concrete storage modules and vaults in different regions of the country, and provides a thermal analysis of commercial SNF in storage.

  8. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1996-12-31

    The paper consists of viewgraphs from a conference presentation. A comparison is made of opportunity fuels, defined as fuels that can be converted to other forms of energy at lower cost than standard fossil fuels. Types of fuels for which some limited technical data is provided include petroleum coke, garbage, wood waste, and tires. Power plant economics and pollution concerns are listed for each fuel, and compared to coal and natural gas power plant costs. A detailed cost breakdown for different plant types is provided for use in base fuel pricing.

  9. Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2013-06-30

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). 3) The Project will annually produce 365,292 MWh�s of clean energy. 4) By destroying the methane in the landfill gas, the Project will generate CO{sub 2} equivalent reductions of 164,938 tons annually. The completed facility produces 28.3 MWnet and operates 24 hours a day, seven days a week.

  10. Decreased PCDD/F formation when co-firing a waste fuel and biomass in a CFB boiler by addition of sulphates or municipal sewage sludge

    SciTech Connect (OSTI)

    mand, Lars-Erik; Kassman, Hkan

    2013-08-15

    Highlights: Two strategies to reduce PCDD/F formation when co-firing solid recovered fuel (SRF) and biomass. They were co-combustion with municipal sewage sludge (MSS) and addition of ammonium sulphate. PCDD/Fs were significantly reduced for a biomass rich in chlorine when adding ammonium sulphate. MSS had a suppressing effect on PCDD/F formation during co-combustion with SRF. A link is presented between gaseous alkali chlorides, chlorine in deposits and PCDD/F formation. - Abstract: Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are formed during waste incineration and in waste-to-energy boilers. Incomplete combustion, too short residence times at low combustion temperatures (<700 C), incineration of electronic waste and plastic waste containing chlorine are all factors influencing the formation of PCDD/Fs in boilers. The impact of chlorine and catalysing metals (such as copper and iron) in the fuel on PCDD/F formation was studied in a 12 MW{sub th} circulating fluidised bed (CFB) boiler. The PCDD/F concentrations in the raw gas after the convection pass of the boiler and in the fly ashes were compared. The fuel types were a so-called clean biomass with low content of chlorine, biomass with enhanced content of chlorine from supply of PVC, and solid recovered fuel (SRF) which is a waste fuel containing higher concentrations of both chlorine, and catalysing metals. The PCDD/F formation increased for the biomass with enhanced chlorine content and it was significantly reduced in the raw gas as well as in the fly ashes by injection of ammonium sulphate. A link, the alkali chloride track, is demonstrated between the level of alkali chlorides in the gas phase, the chlorine content in the deposits in the convection pass and finally the PCDD/F formation. The formation of PCDD/Fs was also significantly reduced during co-combustion of SRF with municipal sewage sludge (MSS) compared to when SRF was fired without MSS as additional fuel.

  11. Reproductive and developmental health risk from dioxin-like compounds: Insignificant risk from cement kilns burning waste-derived fuels

    SciTech Connect (OSTI)

    Holcomb, L.C.; Pedelty, J.F.

    1994-12-31

    Cement kilns burning waste-derived fuels emit low levels of dibenzodioxins and dibenzofurans and little or no PCB`s. Concern about possible effects on reproduction and development has prompted an evaluation of the research literature especially with regard to the reproductive and developmental effects of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). In sufficient doses, dioxins, furans, and PCB can cause adverse health effects in some animals or humans. Calculated doses of TCDD-EQ (dioxin equivalents) are dependent on many assumptions, but where human effects have been demonstrated, doses were 100--1,000 times higher than the usual background environmental doses. This would include those environmental doses that would be received by the most-exposed individual living near cement kilns burning WDF. There is evidence to suggest that PCB`s have had an adverse impact on some wildlife although there is no evidence that these PCB`s are associated with cement kiln emissions. There is no evidence to suggest that dioxins, at environmental levels or associated with emissions from WDF-burning cement kilns, have caused adverse effects in either wildlife or humans. 63 refs., 3 tabs.

  12. Transportation of Spent Nuclear Fuel and High Level Waste to Yucca Mountain: The Next Step in Nevada

    SciTech Connect (OSTI)

    Sweeney, Robin L,; Lechel, David J.

    2003-02-25

    In the U.S. Department of Energy's ''Final Environmental Impact Statement for a Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, Nevada,'' the Department states that certain broad transportation-related decisions can be made. These include the choice of a mode of transportation nationally (mostly legal-weight truck or mostly rail) and in Nevada (mostly rail, mostly legal-weight truck, or mostly heavy-haul truck with use of an associated intermodal transfer station), as well as the choice among alternative rail corridors or heavy-haul truck routes with use of an associated intermodal transfer station in Nevada. Although a rail line does not service the Yucca Mountain site, the Department has identified mostly rail as its preferred mode of transportation, both nationally and in the State of Nevada. If mostly rail is selected for Nevada, the Department would then identify a preference for one of the rail corridors in consultation with affected stakeholders, particularly the State of Nevada. DOE would then select the rail corridor and initiate a process to select a specific rail alignment within the corridor for the construction of a rail line. Five proposed rail corridors were analyzed in the Final Environmental Impact Statement. The assessment considered the impacts of constructing a branch rail line in the five 400-meter (0.25mile) wide corridors. Each corridor connects the Yucca Mountain site with an existing mainline railroad in Nevada.

  13. Waste/By-Product Hydrogen

    Broader source: Energy.gov [DOE]

    Presentation by Ruth Cox, Fuel Cell and Hydrogen Energy Association, at the DOE-DOD Waste-to-Energy using Fuel Cells Workshop held Jan. 13, 2011

  14. Alcohol fuel from Ohio farms

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Brief descriptions of on-farm ethanol production methods including feedstock preparation, cooking, fermentation, and distillation are presented. Safety conditions are described. Investment in on-farm ethanol production facilities and their potential returns are addressed. The market for ethanol and ethanol blends as well as for by-products is encouraging. Legal aspects for permitting and environmental regulations both for Ohio and federal agencies are discussed. (DMC)

  15. Liquidyne Fuels | Open Energy Information

    Open Energy Info (EERE)

    search Name: Liquidyne Fuels Place: Washington, DC Zip: 20015 Product: Focused on waste-to-energy hybrid approach for bioethanol production. References: Liquidyne Fuels1...

  16. Extracting alcohols from aqueous solutions. [USDOE patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1981-12-02

    The objective is to provide an efficient process for extracting alcohols in aqueous solutions into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. This is done by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5-18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is then mixed with one or more of a group of polyoxyalkylene polymers to extract the alcohol into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  17. Using recycled wood waste as a fuel in the northeast: A handbook for prospective urban wood waste producers, suppliers and consumers

    SciTech Connect (OSTI)

    Prast, W.G.; Donovan, C.T.

    1988-03-01

    This report provides a comprehensive analysis of existing and future markets for recycled wood wastes in the eleven-state northeast region. The purpose of the report is to estimate the availability of wood and woody materials in the solid waste stream and to determine the technical and economic viability of separating and recycling them for other uses. The topics discussed include: current and future markets for recycled wood wastes; key components of successful wood waste processing facilities; decisionmaking process used to determine technical and economic viability of a proposed processing facility; environmental regulations and the permitting process required for recycled wood waste processors and users; case studies and annotated listings of existing wood waste processors and uses; detailed assessments of market opportunities in three metropolitan areas including Boston, New York, and Philadelphia; and a proposed action plan to stimulate and facilitate future market development.

  18. Department of Energy Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs Draft Environmental Impact Statement. Volume 2, Part B

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    Two types of projects in the spent nuclear fuel and environmental restoration and waste management activities at the Idaho National Engineering Laboratory (INEL) are described. These are: foreseeable proposed projects where some funding for preliminary planning and/or conceptual design may already be authorized, but detailed design or planning will not begin until the Department of Energy (DOE) has determined that the requirements of the National Environmental Policy Act process for the project have been completed; planned or ongoing projects not yet completed but whose National Environmental Policy Act documentation is already completed or is expected to be completed before the Record of Decision for this Envirorunental Impact Statement (EIS) is issued. The section on project summaries describe the projects (both foreseeable proposed and ongoing).They provide specific information necessary to analyze the environmental impacts of these projects. Chapter 3 describes which alternative(s) each project supports. Summaries are included for (a) spent nuclear fuel projects, (b) environmental remediation projects, (c) the decontamination and decommissioning of surplus INEL facilities, (d) the construction, upgrade, or replacement of existing waste management facilities, (e) infrastructure projects supporting waste management activities, and (f) research and development projects supporting waste management activities.

  19. Radiological Monitoring Results For Groundwater Samples Associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Pond: May 1, 2010-October 31, 2010

    SciTech Connect (OSTI)

    David B. Frederick

    2011-02-01

    This report summarizes radiological monitoring performed on samples from specific groundwater monitoring wells associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond (#LA-000160-01). The radiological monitoring was performed to fulfill Department of Energy requirements under the Atomic Energy Act.

  20. Radiological Monitoring Results for Groundwater Samples Associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Pond: November 1, 2011-October 31, 2012

    SciTech Connect (OSTI)

    Mike lewis

    2013-02-01

    This report summarizes radiological monitoring performed on samples from specific groundwater monitoring wells associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond WRU-I-0160-01, Modification 1 (formerly LA-000160-01). The radiological monitoring was performed to fulfill Department of Energy requirements under the Atomic Energy Act.

  1. Radiological Monitoring Results For Groundwater Samples Associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Pond: November 1, 2010-October 31, 2011

    SciTech Connect (OSTI)

    David Frederick

    2012-02-01

    This report summarizes radiological monitoring performed on samples from specific groundwater monitoring wells associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond (No.LA-000160-01). The radiological monitoring was performed to fulfill Department of Energy requirements under the Atomic Energy Act.

  2. Radiological Monitoring Results for Groundwater Samples Associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Pond: November 1, 2012-October 31, 2013

    SciTech Connect (OSTI)

    Mike Lewis

    2014-02-01

    This report summarizes radiological monitoring performed on samples from specific groundwater monitoring wells associated with the Industrial Wastewater Reuse Permit for the Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond WRU-I-0160-01, Modification 1 (formerly LA-000160-01). The radiological monitoring was performed to fulfill Department of Energy requirements under the Atomic Energy Act.

  3. Engineered fuel: Renewable fuel of the future?

    SciTech Connect (OSTI)

    Tomczyk, L.

    1997-01-01

    The power generation and municipal solid waste management industries share an interest in the use of process engineered fuel (PEF) comprised mainly of paper and plastics as a supplement to conventional fuels. PEF is often burned in existing boilers, making PEF an alternative to traditional refuse derived fuels (RDF). This paper describes PEF facilities and makes a comparison of PEF and RDF fuels.

  4. Expected near-field thermal environments in a sequentially loaded spent-fuel or high-level waste repository in salt

    SciTech Connect (OSTI)

    Rickertsen, L.D.; Arbital, J.G.; Claiborne, H.C.

    1982-01-01

    This report describes the effect of realistic waste emplacement schedules on repository thermal environments. Virtually all estimates to date have been based on instantaneous loading of wastes having uniform properties throughout the repository. However, more realistic scenarios involving sequential emplacement of wastes reflect the gradual filling of the repository over its lifetime. These cases provide temperatures that can be less extreme than with the simple approximation. At isolated locations in the repository, the temperatures approach the instantaneous-loading limit. However, for most of the repository, temperature rises in the near-field are 10 to 40 years behind the conservative estimates depending on the waste type and the location in the repository. Results are presented for both spent-fuel and high-level reprocessing waste repositories in salt, for a regional repository concept, and for a single national repository concept. The national repository is filled sooner and therefore more closely approximates the instantaneously loaded repository. However, temperatures in the near-field are still 20/sup 0/C or more below the values in the simple model for 40 years after startup of repository emplacement operations. The results suggest that current repository design concepts based on the instantaneous-loading predictions are very conservative. Therefore, experiments to monitor temperatures in a test and evaluation facility, for example, will need to take into account the reduced temperatures in order to provide data used in predicting repository performance.

  5. An assessment of potential environmental impacts of cement kiln dust produced in kilns co-fired with hazardous waste fuels

    SciTech Connect (OSTI)

    Goad, P.T.; Millner, G.C.; Nye, A.C.

    1998-12-31

    The Keystone Cement Company (Keystone), located in Bath, Pennsylvania, produces cement in two kilns that are co-fired with hazardous waste-derived fuels. Beginning in the late 1970`s Keystone began storing cement kiln dust (CKD) in an aboveground storage pile located on company property adjacent to the cement kilns. Storm water runoff from the CKD pile is channeled into a storm water settling pond which in turn discharges into Monocacy Creek, a stream running along the eastern property boundary. Monocacy Creek sustains a thriving trout fishery and is routinely fished during the open recreational fishing season in pennsylvania. The CKD pile has a surface area of approximately 12 acres, with an average height of approximately 35 feet. The southern edge of the pile is contiguous with an adjacent company-owned field in which field corn is grown for cattle feed. Some of the corn on the edges of the field is actually grown in direct contact with CKD that comprises the edge of the storage pile. The CKD pile is located approximately 150 yards to the west of Monocacy Creek. In 1995--1996 water, sediment and fish (trout) samples were obtained from Monocacy Creek sampling stations upstream and downstream of the point of discharge of storm water runoff from the CKD pile. In addition, corn samples were obtained from the field contiguous with the CKD pile and from a control field located distant to the site. The sediment, water, fish, and corn samples were analyzed for various chemicals previously identified as chemicals of potential concern in CKD. These data indicate that chemical constituents of CKD are not contaminating surface water or sediment in the stream, and that bioaccumulation of organic chemicals and/or metals has not occurred in field corn grown in direct contact with undiluted CKD, or in fish living in the waters that receive CKD pile runoff.

  6. Alcohol conversion

    DOE Patents [OSTI]

    Wachs, Israel E.; Cai, Yeping

    2002-01-01

    Preparing an aldehyde from an alcohol by contacting the alcohol in the presence of oxygen with a catalyst prepared by contacting an intimate mixture containing metal oxide support particles and particles of a catalytically active metal oxide from Groups VA, VIA, or VIIA, with a gaseous stream containing an alcohol to cause metal oxide from the discrete catalytically active metal oxide particles to migrate to the metal oxide support particles and to form a monolayer of catalytically active metal oxide on said metal oxide support particles.

  7. Waste Package Lifting Calculation

    SciTech Connect (OSTI)

    H. Marr

    2000-05-11

    The objective of this calculation is to evaluate the structural response of the waste package during the horizontal and vertical lifting operations in order to support the waste package lifting feature design. The scope of this calculation includes the evaluation of the 21 PWR UCF (pressurized water reactor uncanistered fuel) waste package, naval waste package, 5 DHLW/DOE SNF (defense high-level waste/Department of Energy spent nuclear fuel)--short waste package, and 44 BWR (boiling water reactor) UCF waste package. Procedure AP-3.12Q, Revision 0, ICN 0, calculations, is used to develop and document this calculation.

  8. Testing to evaluate the suitability of waste forms developed for electrometallurgically treated spent sodium-bonded nuclear fuel for disposal in the Yucca Mountain reporsitory.

    SciTech Connect (OSTI)

    Ebert, W. E.

    2006-01-31

    The results of laboratory testing and modeling activities conducted to support the development of waste forms to immobilize wastes generated during the electrometallurgical treatment of spent sodium-bonded nuclear fuel and their qualification for disposal in the federal high-level radioactive waste repository are summarized in this report. Tests and analyses were conducted to address issues related to the chemical, physical, and radiological properties of the waste forms relevant to qualification. These include the effects of composition and thermal treatments on the phase stability, radiation effects, and methods for monitoring product consistency. Other tests were conducted to characterize the degradation and radionuclide release behaviors of the ceramic waste form (CWF) used to immobilize waste salt and the metallic waste form (MWF) used to immobilize metallic wastes and to develop models for calculating the release of radionuclides over long times under repository-relevant conditions. Most radionuclides are contained in the binder glass phase of the CWF and in the intermetallic phase of the MWF. The release of radionuclides from the CWF is controlled by the dissolution rate of the binder glass, which can be tracked using the same degradation model that is used for high-level radioactive waste (HLW) glass. Model parameters measured for the aqueous dissolution of the binder glass are used to model the release of radionuclides from a CWF under all water-contact conditions. The release of radionuclides from the MWF is element-specific, but the release of U occurs the fastest under most test conditions. The fastest released constituent was used to represent all radionuclides in model development. An empirical aqueous degradation model was developed to describe the dependence of the radionuclide release rate from a MWF on time, pH, temperature, and the Cl{sup -} concentration. The models for radionuclide release from the CWF and MWF are both bounded by the HLW glass degradation model developed for use in repository licensing, and HLW glass can be used as a surrogate for both CWF and MWF in performance assessment calculations. Test results indicate that the radionuclide release from CWF and MWF is adequately described by other relevant performance assessment models, such as the models for the solution chemistries in breached waste packages, dissolved concentration limits, and the formation of radionuclide-bearing colloids.

  9. End of FY10 report - used fuel disposition technical bases and lessons learned : legal and regulatory framework for high-level waste disposition in the United States.

    SciTech Connect (OSTI)

    Weiner, Ruth F.; Blink, James A.; Rechard, Robert Paul; Perry, Frank; Jenkins-Smith, Hank C.; Carter, Joe; Nutt, Mark; Cotton, Tom

    2010-09-01

    This report examines the current policy, legal, and regulatory framework pertaining to used nuclear fuel and high level waste management in the United States. The goal is to identify potential changes that if made could add flexibility and possibly improve the chances of successfully implementing technical aspects of a nuclear waste policy. Experience suggests that the regulatory framework should be established prior to initiating future repository development. Concerning specifics of the regulatory framework, reasonable expectation as the standard of proof was successfully implemented and could be retained in the future; yet, the current classification system for radioactive waste, including hazardous constituents, warrants reexamination. Whether or not consideration of multiple sites are considered simultaneously in the future, inclusion of mechanisms such as deliberate use of performance assessment to manage site characterization would be wise. Because of experience gained here and abroad, diversity of geologic media is not particularly necessary as a criterion in site selection guidelines for multiple sites. Stepwise development of the repository program that includes flexibility also warrants serious consideration. Furthermore, integration of the waste management system from storage, transportation, and disposition, should be examined and would be facilitated by integration of the legal and regulatory framework. Finally, in order to enhance acceptability of future repository development, the national policy should be cognizant of those policy and technical attributes that enhance initial acceptance, and those policy and technical attributes that maintain and broaden credibility.

  10. Examining Hot Fuels

    SciTech Connect (OSTI)

    Jon Carmack

    2009-10-02

    Nuclear Engineer Jon Carmack talks about his nuclear fuels research at the Idaho National Laboratory, and how it may lead to solutions for nuclear waste.

  11. Examining Hot Fuels

    ScienceCinema (OSTI)

    Jon Carmack

    2010-01-08

    Nuclear Engineer Jon Carmack talks about his nuclear fuels research at the Idaho National Laboratory, and how it may lead to solutions for nuclear waste.

  12. Underground Storage Tanks: New Fuels and Compatibility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... 1980 1984 1990 1995 1981 1985 1988 2005 Prior to Oct. 1980: No single or double wall tanks are warrantied for any alcohol or alcohol blended fuels. Oct. 1980 to Jun. 1984: ...

  13. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  14. EIS-0203: Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs

    Broader source: Energy.gov [DOE]

    This EIS considers programmatic (DOE-wide) alternative approaches to safely, efficiently, and responsibly manage existing and projected quantities of spent nuclear fuel until the year 2035. This amount of time may be required to make and implement a decision on the ultimate disposition of spent nuclear fuel. DOE's spent nuclear fuel responsibilities include fuel generated by DOE production, research, and development reactors; naval reactors; university and foreign research reactors; domestic non-DOE reactors such as those at the National Institute of Standards and Technology and the Armed Forces Radiobiology Research Institute; and special-case commercial reactors such as Fort St. Vrain and the Lynchburg Technology Center.

  15. Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks | Department of Energy Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Breakout Session 2-B: New/Emerging Pathways Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend

  16. Design Case Summary: Production of Mixed Alcohols from Municipal Solid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste via Gasification | Department of Energy Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification The Bioenergy Technologies Office develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case establishes cost targets for converting MSW to ethanol and

  17. New Design for an HLW Repository (for Spent Fuel and Waste from Reprocessing) in a Salt Formation in Germany - 12213

    SciTech Connect (OSTI)

    Bollingerfehr, Wilhelm; Filbert, Wolfgang; Lerch, Christian; Mueller-Hoeppe, Nina; Charlier, Frank

    2012-07-01

    In autumn 2010, after a 10-year moratorium, exploration was resumed in Gorleben, the potential site for a German HLW repository. At the same time, the Federal Government launched a two-year preliminary safety analysis to assess whether the salt dome at Gorleben is suitable to host all heat-generating radioactive waste generated by German NPPs based on the waste amounts expected at that time. The revised Atomic Energy Act of June 2011 now stipulates a gradual phase-out of nuclear energy production by 2022, which is 13 years earlier than expected in 2010. A repository design was developed which took into account an updated set of data on the amounts and types of expected heat-generating waste, the documented results of the exploration of the Gorleben salt dome, and the new 'Safety Requirements Governing the Final Disposal of Heat-Generating Radioactive Waste' of 30 September, 2010. The latter has a strong influence on the conceptual designs as it requires that retrievability of all waste containers is possible within the repository lifetime. One design considered that all waste containers will be disposed of in horizontal drifts of a geologic repository, while the other design considered that all waste containers will be disposed of in deep vertical boreholes. For both options (emplacement in drifts/emplacement in vertical boreholes), the respective design includes a selection of waste containers, the layout of drifts, respectively lined boreholes, a description of emplacement fields, and backfilling and sealing measures. The design results were described and displayed and the differences between the two main concepts were elaborated and discussed. For the first time in both repository designs the requirement was implemented to retrieve waste canisters during the operational phase. The measures to fulfill this requirement and eventually the consequences were highlighted. It was pointed out that there arises the need to keep transport- and storage casks in adequate numbers and interim storage facilities available until the repository is closed. (authors)

  18. Zero Waste Plc | Open Energy Information

    Open Energy Info (EERE)

    acquired right to waste processing technology, which processes waste into high energy density fuel products. Coordinates: 51.506325, -0.127144 Show Map Loading map......

  19. Development of Thermoelectric Technology for Automotive Waste...

    Broader source: Energy.gov (indexed) [DOE]

    generator for automotive waste heat recovery and achieve at least 10% fuel ... Opportunities and Challenges of Thermoelectrlic Waste Heat Recovery in the Automotive ...

  20. Chemical Engineering Division fuel cycle programs. Quarterly progress report, April-June 1979. [Pyrochemical/dry processing; waste encapsulation in metal; transport in geologic media

    SciTech Connect (OSTI)

    Steindler, M.J.; Ader, M.; Barletta, R.E.

    1980-09-01

    For pyrochemical and dry processing materials development included exposure to molten metal and salt of Mo-0.5% Ti-0.07% Ti-0.01% C, Mo-30% W, SiC, Si/sub 2/ON/sub 2/, ZrB/sub 2/-SiC, MgAl/sub 2/O/sub 4/, Al/sub 2/O/sub 3/, AlN, HfB/sub 2/, Y/sub 2/O/sub 3/, BeO, Si/sub 3/N/sub 4/, nickel nitrate-infiltrated W, W-coated Mo, and W-metallized alumina-yttria. Work on Th-U salt transport processing included solubility of Th in liquid Cd, defining the Cd-Th and Cd-Mg-Th phase diagrams, ThO/sub 2/ reduction experiments, and electrolysis of CaO in molten salt. Work on pyrochemical processes and associated hardware for coprocessing U and Pu in spent FBR fuels included a second-generation computer model of the transport process, turntable transport process design, work on the U-Cu-Mg system, and U and Pu distribution coefficients between molten salt and metal. Refractory metal vessels are being service-life tested. The chloride volatility processing of Th-based fuel was evaluated for its proliferation resistance, and a preliminary ternary phase diagram for the Zn-U-Pu system was computed. Material characterization and process analysis were conducted on the Exportable Pyrochemical process (Pyro-Civex process). Literature data on oxidation of fissile metals to oxides were reviewed. Work was done on chemical bases for the reprocessing of actinide oxides in molten salts. Flowsheets are being developed for the processing of fuel in molten tin. Work on encapsulation of solidified radioactive waste in metal matrix included studies of leach rate of crystalline waste materials and of the impact resistance of metal-matrix waste forms. In work on the transport properties of nuclear waste in geologic media, adsorption of Sr on oolitic limestone was studied, as well as the migration of Cs in basalt. Fitting of data on the adsorption of iodate by hematite to a mathematical model was attempted.

  1. Biogas Technologies and Integration with Fuel Cells

    Broader source: Energy.gov (indexed) [DOE]

    Food waste Packaged food waste Energy crops Manure Feedstocks for Anaerobic Digestion Biogas Utilization Biomethane Production Biogas Utilization Gas grid Bio fuel Biogas plant...

  2. Development, Testing and Validation of a Waste Assay System for the Measurement and Characterisation of Active Spent Fuel Element Debris From UK Magnox Reactors - 12533

    SciTech Connect (OSTI)

    Mason, John A.; Burke, Kevin J.; Looman, Marc R.; Towner, Antony C.N.; Phillips, Martin E.

    2012-07-01

    This paper describes the development, testing and validation of a waste measurement instrument for characterising active remote handled radioactive waste arising from the operation of Magnox reactors in the United Kingdom. Following operation in UK Magnox gas cooled reactors and a subsequent period of cooling, parts of the magnesium-aluminium alloy cladding were removed from spent fuel and the uranium fuel rods with the remaining cladding were removed to Sellafield for treatment. The resultant Magnox based spent fuel element debris (FED), which constitutes active intermediate level waste (ILW) has been stored in concrete vaults at the reactor sites. As part of the decommissioning of the FED vaults the FED must be removed, measured and characterised and placed in intermediate storage containers. The present system was developed for use at the Trawsfynydd nuclear power station (NPS), which is in the decommissioning phase, but the approach is potentially applicable to FED characterisation at all of the Magnox reactors. The measurement system consists of a heavily shielded and collimated high purity Germanium (HPGe) detector with electromechanical cooling and a high count-rate preamplifier and digital multichannel pulse height analyser. The HPGe based detector system is controlled by a software code, which stores the measurement result and allows a comprehensive analysis of the measured FED data. Fuel element debris is removed from the vault and placed on a tray to a uniform depth of typically 10 cm for measurement. The tray is positioned approximately 1.2 meters above the detector which views the FED through a tungsten collimator with an inverted pyramid shape. At other Magnox sites the positions may be reversed with the shielded and collimated HPGe detector located above the tray on which the FED is measured. A comprehensive Monte Carlo modelling and analysis of the measurement process has been performed in order to optimise the measurement geometry and eliminate interferences from radioactive sources and FED in the immediate vicinity of the measurement position. The detector system has been calibrated and high activity radioactive sources of Cs-137, Co-60 and Na-22 have been used to validate the measurement process. The data acquisition and analysis software code has been tested and validated in keeping with the software quality assurance requirements of both ISO:9001-2008 - TICK-IT in the UK and NQA-1. The measurement and analysis system has been comprehensively tested with high activity sources, is flexible and may be applicable to a wide range of remote handled radioactive waste measurement applications. It is due to be installed at Trawsfynydd NPS later this year. This paper describes the Waste Tray Assay System (WTAS) that has been developed for the measurement of Magnox FED waste. The WTAS has been tested with a range of radioactive sources and its operation has been simulated with benchmarked MCNP Monte Carlo calculations. The measurement software has been validated as has the operation of the system for a range of strong radioactive sources. A system based on the design is due for installation and operation in 2012. The system has application to the measurement of Magnox Fuel Element Debris (FED) waste at other Magnox reactor sites. The major design objective of the WTAS that has been achieved is the ability of the assay system to determine the content of Cs-137, and in turn to enable the fissile burden to be assessed using a radionuclide fingerprint, in the presence of higher and highly variable quantities of Co-60, typically from nimonic springs. The approach can be used in other Magnox FED waste configurations where the detector is located above the FED waste sorting tray and where the collimation is fixed below the detector and at a distance above the tray. In this case, which has also been investigated, there are different shielding problems and mechanical support issues. The extensive use of MCNP Monte Carlo modelling to simulate the geometry of the sorting cell and the distribution of radioactive sources has helped to ensure that all of the detector shielding requirements are addressed and suitable Cs-137 and Co-60 discrimination can be achieved. The WTAS in its present form or in other configurations has relevance to the measurement of other active ILW and highly active RH waste. Examples include high activity RH LLW and RH TRU (Transuranic) waste as defined in the United States arising from both commercial nuclear and Department of Energy (DOE) operations. The analysis is able to analyse a range of radionuclides beyong those expected in the Magnox FED cases. (authors)

  3. Hydrogen Gas Generation Model for Fuel-Based Remote-Handled Transuranic Waste Stored at the INEEL

    SciTech Connect (OSTI)

    Khericha, S.; Bhatt, R.; Liekhus, K.

    2003-01-14

    The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

  4. Milestones for Selection, Characterization, and Analysis of the Performance of a Repository for Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain.

    SciTech Connect (OSTI)

    Rechard, Robert P.

    2014-02-01

    This report presents a concise history in tabular form of events leading up to site identification in 1978, site selection in 1987, subsequent characterization, and ongoing analysis through 2008 of the performance of a repository for spent nuclear fuel and high-level radioactive waste at Yucca Mountain in southern Nevada. The tabulated events generally occurred in five periods: (1) commitment to mined geologic disposal and identification of sites; (2) site selection and analysis, based on regional geologic characterization through literature and analogous data; (3) feasibility analysis demonstrating calculation procedures and importance of system components, based on rough measures of performance using surface exploration, waste process knowledge, and general laboratory experiments; (4) suitability analysis demonstrating viability of disposal system, based on environment-specific laboratory experiments, in-situ experiments, and underground disposal system characterization; and (5) compliance analysis, based on completed site-specific characterization. Because the relationship is important to understanding the evolution of the Yucca Mountain Project, the tabulation also shows the interaction between four broad categories of political bodies and government agencies/institutions: (a) technical milestones of the implementing institutions, (b) development of the regulatory requirements and related federal policy in laws and court decisions, (c) Presidential and agency directives and decisions, and (d) critiques of the Yucca Mountain Project and pertinent national and world events related to nuclear energy and radioactive waste.

  5. Waste Management | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Management Waste Management Nuclear Materials Disposition Nuclear Materials Disposition In fulfilling its mission, EM frequently manages and completes disposition of surplus nuclear materials and spent nuclear fuel. These are not waste. They are nuclear materials no longer needed for national security or other purposes, including spent nuclear fuel, special nuclear materials (as defined by the Atomic Energy Act) and other Nuclear Materials. Read more Tank Waste and Waste Processing Tank Waste

  6. AgriFuel Company | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: AgriFuel Company Place: Cranford, New Jersey Sector: Biofuels Product: AgriFuel produces and markets biofuels refined from waste vegetable oil,...

  7. Power Ecalene Fuels Inc | Open Energy Information

    Open Energy Info (EERE)

    Arvada, Colorado Zip: 80007 Region: Rockies Area Sector: Biofuels Product: Mixed alcohol transportation fuel Website: www.powerecalene.com Coordinates: 39.862942,...

  8. Material Recovery and Waste Form Development FY 2014 Accomplishments Report

    SciTech Connect (OSTI)

    Lori Braase

    2014-11-01

    Develop advanced nuclear fuel cycle separation and waste management technologies that improve current fuel cycle performance and enable a sustainable fuel cycle, with minimal processing, waste generation, and potential for material diversion.

  9. Walk the Line: The Development of Route Selection Standards for Spent Nuclear Fuel and High-level Radioactive Waste in the United States - 13519

    SciTech Connect (OSTI)

    Dilger, Fred; Halstead, Robert J.; Ballard, James D.

    2013-07-01

    Although storage facilities for spent nuclear fuel (SNF) and high-level radioactive waste (HLRW) are widely dispersed throughout the United States, these materials are also relatively concentrated in terms of geographic area. That is, the impacts of storage occur in a very small geographic space. Once shipments begin to a national repository or centralized interim storage facility, the impacts of SNF and HLRW will become more geographically distributed, more publicly visible, and almost certainly more contentious. The selection of shipping routes will likely be a major source of controversy. This paper describes the development of procedures, regulations, and standards for the selection of routes used to ship spent nuclear fuel and high-level radioactive waste in the United States. The paper begins by reviewing the circumstances around the development of HM-164 routing guidelines. The paper discusses the significance of New York City versus the Department of Transportation and application of HM-164. The paper describes the methods used to implement those regulations. The paper will also describe the current HM-164 designated routes and will provide a summary data analysis of their characteristics. This analysis will reveal the relatively small spatial scale of the effects of HM 164. The paper will then describe subsequent developments that have affected route selection for these materials. These developments include the use of 'representative routes' found in the Department of Energy (DOE) 2008 Supplemental Environmental Impact Statement for the formerly proposed Yucca Mountain geologic repository. The paper will describe recommendations related to route selection found in the National Academy of Sciences 2006 report Going the Distance, as well as recommendations found in the 2012 Final Report of the Blue Ribbon Commission on America's Nuclear Future. The paper will examine recently promulgated federal regulations (HM-232) for selection of rail routes for hazardous materials transport. The paper concludes that while the HM 164 regime is sufficient for certain applications, it does not provide an adequate basis for a national plan to ship spent nuclear fuel and high-level radioactive waste to centralized storage and disposal facilities over a period of 30 to 50 years. (authors)

  10. US nuclear waste may have temporary home

    SciTech Connect (OSTI)

    Kramer, David

    2015-05-15

    Combined developments could break the logjam over disposition of spent nuclear fuel and defense high-level radioactive waste.

  11. Zirconia Inert Matrix Fuel for Plutonium and Minor Actinides Management in Reactors and as an Ultimate Waste Form

    SciTech Connect (OSTI)

    Degueldre, Claude; Wiesenack, Wolfgang

    2008-07-01

    An yttria stabilised zirconia doped with plutonia and erbia has been selected as inert matrix fuel (IMF) at PSI. The results of experimental irradiation tests on yttria-stabilised zirconia doped with plutonia and erbia pellets in the Halden research reactor as well as a study of zirconia solubility are presented. Zirconia must be stabilised by yttria to form a solid solution such as MAz(Y,Er){sub y}Pu{sub x}Zr{sub 1-y}O{sub 2-{xi}} where minor actinides (MA) oxides are also soluble. (Er,Y,Pu,Zr)O{sub 2-{xi}} (with Pu containing 5% Am) was successfully prepared at PSI and irradiated in the Halden reactor. Emphasis is given on the zirconia- IMF properties under in-pile irradiation, on the fuel material centre temperatures and on the fission gas release. The retention of fission products in zirconia may be stronger at similar temperature, compared to UO{sub 2}. The outstanding behaviour of plutonia-zirconia inert matrix fuel is compared to the classical (U,Pu)O{sub 2} fuels. The properties of the spent fuel pellets are presented focusing on the once-through strategy. For this strategy, low solubility of the inert matrix is required for geological disposal. This parameter was studied in detail for a range of solutions corresponding to groundwater under near field conditions. Under these conditions the IMF solubility is about 109 times smaller than glass, several orders of magnitude lower than UO{sub 2} in oxidising conditions (Yucca Mountain) and comparable in reducing conditions, which makes the zirconia material very attractive for deep geological disposal. The behaviour of plutonia-zirconia inert matrix fuel is discussed within a 'burn and bury' strategy. (authors)

  12. FUELS; 54 ENVIRONMENTAL SCIENCES; RADIOACTIVE EFFLUENTS; EMISSION...

    Office of Scientific and Technical Information (OSTI)

    SRP radioactive waste releases. Startup through 1959 Ashley, C. 05 NUCLEAR FUELS; 54 ENVIRONMENTAL SCIENCES; RADIOACTIVE EFFLUENTS; EMISSION; ENVIRONMENTAL MATERIALS;...

  13. EIS-0250-S1: Final Supplemental Environmental Impact Statement for a Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, Nevada

    Broader source: Energy.gov [DOE]

    The Proposed Action defined in the Yucca Mountain FEIS is to construct, operate, monitor, and eventually close a geologic repository at Yucca Mountain to dispose of spent nuclear fuel and high-level radioactive waste. The Proposed Action includes transportation of these materials from commercial and DOE sites to the repository.

  14. Lesson 7 - Waste from Nuclear Power Plants | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 - Waste from Nuclear Power Plants Lesson 7 - Waste from Nuclear Power Plants This lesson takes a look at the waste from electricity production at nuclear power plants. It considers the different types of waste generated, as well as how we deal with each type of waste. Specific topics covered include: Nuclear Waste Some radioactive Types of radioactive waste Low-level waste High-level waste Disposal and storage Low-level waste disposal Spent fuel storage Waste isolation Reprocessing

  15. Generating power with waste wood

    SciTech Connect (OSTI)

    Atkins, R.S.

    1995-02-01

    Among the biomass renewables, waste wood has great potential with environmental and economic benefits highlighting its resume. The topics of this article include alternate waste wood fuel streams; combustion benefits; waste wood comparisons; waste wood ash; pilot scale tests; full-scale test data; permitting difficulties; and future needs.

  16. System dynamics of the competition of municipal solid waste to landfill, electricity, and liquid fuel in California

    SciTech Connect (OSTI)

    Westbrook, Jessica; Malczynski, Leonard A.; Manley, Dawn Kataoka

    2014-03-01

    A quantitative system dynamics model was created to evaluate the economic and environmental tradeoffs between biomass to electricity and to liquid fuel using MSW biomass in the state of California as a case study. From an environmental perspective, landfilling represents the worst use of MSW over time, generating more greenhouse gas (GHG) emissions compared to converting MSW to liquid fuel or to electricity. MSW to ethanol results in the greatest displacement of GHG emissions per dollar spent compared to MSW to electricity. MSW to ethanol could save the state of California approximately $60 billion in energy costs by 2050 compared to landfilling, while also reducing GHG emissions state-wide by approximately 140 million metric tons during that timeframe. MSW conversion to electricity creates a significant cost within the state's electricity sector, although some conversion technologies are cost competitive with existing renewable generation.

  17. Radioactive Waste Management: Study of Spent Fuel Dissolution Rates in Geological Storage Using Dosimetry Modeling and Experimental Verification

    SciTech Connect (OSTI)

    Hansen, Brady; Miller, William

    2011-10-28

    This research will provide improved predictions into the mechanisms and effects of radiolysis on spent nuclear fuel dissolution in a geological respository through accurate dosimetry modeling of the dose to water, mechanistic chemistry modeling of the resulting radiolytic reactions and confirmatory experimental measurements. This work will combine effort by the Nuclear Science and Engineering Institute (NSEI) and the Missouri University Research Reactor (MURR) at the University of Missouri-Columbia, and the expertise and facilities at the Pacific Northwest National Laboratory (PNNL).

  18. Emissions from US waste collection vehicles

    SciTech Connect (OSTI)

    Maimoun, Mousa A.; Reinhart, Debra R.; Gammoh, Fatina T.; McCauley Bush, Pamela

    2013-05-15

    Highlights: ? Life-cycle emissions for alternative fuel technologies. ? Fuel consumption of alternative fuels for waste collection vehicles. ? Actual driving cycle of waste collection vehicles. ? Diesel-fueled waste collection vehicle emissions. - Abstract: This research is an in-depth environmental analysis of potential alternative fuel technologies for waste collection vehicles. Life-cycle emissions, cost, fuel and energy consumption were evaluated for a wide range of fossil and bio-fuel technologies. Emission factors were calculated for a typical waste collection driving cycle as well as constant speed. In brief, natural gas waste collection vehicles (compressed and liquid) fueled with North-American natural gas had 610% higher well-to-wheel (WTW) greenhouse gas (GHG) emissions relative to diesel-fueled vehicles; however the pump-to-wheel (PTW) GHG emissions of natural gas waste collection vehicles averaged 6% less than diesel-fueled vehicles. Landfill gas had about 80% lower WTW GHG emissions relative to diesel. Biodiesel waste collection vehicles had between 12% and 75% lower WTW GHG emissions relative to diesel depending on the fuel source and the blend. In 2011, natural gas waste collection vehicles had the lowest fuel cost per collection vehicle kilometer travel. Finally, the actual driving cycle of waste collection vehicles consists of repetitive stops and starts during waste collection; this generates more emissions than constant speed driving.

  19. Nuclear Waste Partnership Contract Modifications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Consent-Based Siting » Nuclear Waste Challenge Nuclear Waste Challenge Approximate locations of the current sites where spent nuclear fuel and high-level radioactive waste are stored around the country. Approximate locations of the current sites where spent nuclear fuel and high-level radioactive waste are stored around the country. How We Got Here The United States has used nuclear power for more than 60 years to produce reliable, low-carbon energy and to support national defense activities.

  20. Nuclear Fuel Cycle Options Catalog

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management ...

  1. Energy from biomass and wastes V. Proceedings of the fifth symposium, Lake Buena Vista, FL, January 26-30, 1981

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    Papers are presented in the areas of biomass production and procurement, biomass and waste combustion, gasification processes, liquefaction processes, environmental effects and government programs. Specific topics include a water hyacinth wastewater treatment system with biomass production, the procurement of wood as an industrial fuel, the cofiring of densified refuse-derived fuel and coal, the net energy production in anaerobic digestion, photosynthetic hydrogen production, the steam gasification of manure in a fluidized bed, and biomass hydroconversion to synthetic fuels. Attention is also given to the economics of deriving alcohol for power applications from grain, ethanol fermentation in a yeast-immobilized column fermenter, a solar-fired biomass flash pyrolysis reactor, particulate emissions from controlled-air modular incinerators, and the DOE program for energy recovery from urban wastes.

  2. Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exposition | Department of Energy Update: 2010 Fuel Cell Seminar and Exposition Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Presentation by Sunita Satyapal at the 2010 Fuel Cell Seminar and Exposition on October 19, 2010. PDF icon Hydrogen and Fuel Cell Technologies Update More Documents & Publications DOE Hydrogen and Fuel Cell Overview: 2011 Waste-to-Energy Using Fuel Cells Workshop 2010 Fuel Cell Project Kick-off Welcome DOE Hydrogen and Fuel Cell

  3. Update to Assessment of Direct Disposal in Unsaturated Tuff of Spent Nuclear Fuel and High-Level Waste Owned by U.S. Department of Energy

    SciTech Connect (OSTI)

    P. D. Wheatley; R. P. Rechard

    1998-09-01

    The overall purpose of this study is to provide information and guidance to the Office of Environmental Management of the U.S. Department of Energy (DOE) about the level of characterization necessary to dispose of DOE-owned spent nuclear fuel (SNF). The disposal option modeled was codisposal of DOE SNF with defense high-level waste (DHLW). A specific goal was to demonstrate the influence of DOE SNF, expected to be minor, in a predominately commercial repository using modeling conditions similar to those currently assumed by the Yucca Mountain Project (YMP). A performance assessment (PA) was chosen as the method of analysis. The performance metric for this analysis (referred to as the 1997 PA) was dose to an individual; the time period of interest was 100,000 yr. Results indicated that cumulative releases of 99Tc and 237Np (primary contributors to human dose) from commercial SNF exceed those of DOE SNF both on a per MTHM and per package basis. Thus, if commercial SNF can meet regulatory performance criteria for dose to an individual, then the DOE SNF can also meet the criteria. This result is due in large part to lower burnup of the DOE SNF (less time for irradiation) and to the DOE SNF's small percentage of the total activity (1.5%) and mass (3.8%) of waste in the potential repository. Consistent with the analyses performed for the YMP, the 1997 PA assumed all cladding as failed, which also contributed to the relatively poor performance of commercial SNF compared to DOE SNF.

  4. Thermoelectric Waste Heat Recovery Program for Passenger Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat Recovery Program for Passenger Vehicles Thermoelectric Waste Heat Recovery Program for Passenger Vehicles 2012 DOE Hydrogen and Fuel Cells Program and Vehicle ...

  5. Using Waste Heat for External Processes; Industrial Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Waste Heat for External Processes The temperature of exhaust gases from fuel-fired industrial processes depends mainly on the process temperature and the waste heat recovery ...

  6. Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Mixtures of ethanol, gasoline, and higher alcohols were evaluated to determine if they offer superior performance to ethanol/gasoline blends in meeting the Renewal Fuels Standard II. PDF icon deer12_ickes.pdf More Documents & Publications Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Drop In Fuels: Where the Road Leads

  7. Fuel Cycle Research and Development Presentation Title

    Energy Savers [EERE]

    Materials Recovery and Waste Form Development Campaign Overview Jim Bresee, DOE NE NEET Webinar September 17, 2014 Campaign Objectives  Develop advanced fuel cycle material recovery and waste management technologies that improve current fuel cycle performance and enable a sustainable fuel cycle, with minimal processing, waste generation, and potential for material diversion to provide options for future fuel cycle policy decisions  Campaign strategy is based on developing: - Technologies

  8. EIS-0250-S2: Supplemental EIS for a Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, Nevada- Nevada Rail Transportation Corridor

    Broader source: Energy.gov [DOE]

    This SEIS is to evaluate the potential environmental impacts of constructing and operating a railroad for shipments of spent nuclear fuel and high-level radioactive waste from an existing rail line in Nevada to a geologic repository at Yucca Mountain. The purpose of the evaluation is to assist the Department in deciding whether to construct and operate a railroad in Nevada, and if so, in which corridor and along which specific alignment within the selected corridor.

  9. The Mississippi University Research Consortium for the Utilization of Biomass: Production of Alternative Fuels from Waste Biomass Initiative

    SciTech Connect (OSTI)

    Drs. Mark E. Zapp; Todd French; Lewis Brown; Clifford George; Rafael Hernandez; Marvin Salin; Drs. Huey-Min Hwang, Ken Lee, Yi Zhang; Maria Begonia; Drs. Clint Williford; Al Mikell; Drs. Robert Moore; Roger Hester .

    2009-03-31

    The Mississippi Consortium for the Utilization of Biomass was formed via funding from the US Department of Energy's EPSCoR Program, which is administered by the Office of Basic Science. Funding was approved in July of 1999 and received by participating Mississippi institutions by 2000. The project was funded via two 3-year phases of operation (the second phase was awarded based on the high merits observed from the first 3-year phase), with funding ending in 2007. The mission of the Consortium was to promote the utilization of biomass, both cultured and waste derived, for the production of commodity and specialty chemicals. These scientific efforts, although generally basic in nature, are key to the development of future industries within the Southeastern United States. In this proposal, the majority of the efforts performed under the DOE EPSCoR funding were focused primarily toward the production of ethanol from lignocellulosic feedstocks and biogas from waste products. However, some of the individual projects within this program investigated the production of other products from biomass feeds (i.e. acetic acid and biogas) along with materials to facilitate the more efficient production of chemicals from biomass. Mississippi is a leading state in terms of raw biomass production. Its top industries are timber, poultry production, and row crop agriculture. However, for all of its vast amounts of biomass produced on an annual basis, only a small percentage of the biomass is actually industrially produced into products, with the bulk of the biomass being wasted. This situation is actually quite representative of many Southeastern US states. The research and development efforts performed attempted to further develop promising chemical production techniques that use Mississippi biomass feedstocks. The three processes that were the primary areas of interest for ethanol production were syngas fermentation, acid hydrolysis followed by hydrolyzate fermentation, and enzymatic conversion. All three of these processes are of particular interest to states in the Southeastern US since the agricultural products produced in this region are highly variable in terms of actual crop, production quantity, and the ability of land areas to support a particular type of crop. This greatly differs from the Midwestern US where most of this region's agricultural land supports one to two primary crops, such as corn and soybean. Therefore, developing processes which are relatively flexible in terms of biomass feedstock is key to the southeastern region of the US if this area is going to be a 'player' in the developing biomass to chemicals arena. With regard to the fermentation of syngas, research was directed toward developing improved biocatalysts through organism discovery and optimization, improving ethanol/acetic acid separations, evaluating potential bacterial contaminants, and assessing the use of innovative fermentors that are better suited for supporting syngas fermentation. Acid hydrolysis research was directed toward improved conversion yields and rates, acid recovery using membranes, optimization of fermenting organisms, and hydrolyzate characterization with changing feedstocks. Additionally, a series of development efforts addressed novel separation techniques for the separation of key chemicals from fermentation activities. Biogas related research focused on key factors hindering the widespread use of digester technologies in non-traditional industries. The digestion of acetic acids and other fermentation wastewaters was studied and methods used to optimize the process were undertaken. Additionally, novel laboratory methods were designed along with improved methods of digester operation. A search for better performing digester consortia was initiated coupled with improved methods to initiate their activity within digester environments. The third activity of the consortium generally studied the production of 'other' chemicals from waste biomass materials found in Mississippi. The two primary examples of this activity are production of chemical feedstocks from lignin and the production of high valued lipids from wastewater treatment sludges. Lignin conversion research, done in collaboration with DOE's National Renewable Energy Laboratory (NREL), studied ligninases derived from bacteria found within the gut of wood degrading insects, such as termites and the Betsey beetle. This research attempted to use these enzymes to reduce lignin down to aromatic chemicals capable of chemical conversation for production of value-added chemicals. The biodiesel efforts attempted to development economically viable methods for the separation of lipids from wastewater bacteria (which make up the bulk of sewage sludge) which were then converted to biodisel.

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    for a pilot program to operate Type II school buses that are retrofitted with an auxiliary fuel tank to enable the use of biodiesel, waste vegetable oil, or straight vegetable oil. ...

  11. Integrated Waste Management | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consent-Based Siting » Integrated Waste Management Integrated Waste Management The Department envisions an integrated waste management system with storage, transportation, and disposal capabilities in order to safely and effectively manage our nation's spent nuclear fuel and high-level radioactive waste. The Department envisions an integrated waste management system with storage, transportation, and disposal capabilities in order to safely and effectively manage our nation's spent nuclear fuel

  12. BioGold Fuels Corporation | Open Energy Information

    Open Energy Info (EERE)

    through joint ventures a lower-cost, higher-output system for the production of diesel fuel derived from Municipal Solid Waste ("MSW"). References: BioGold Fuels...

  13. Biological production of liquid fuels from biomass

    SciTech Connect (OSTI)

    1982-01-01

    A scheme for the production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper was investigated. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The construction of a pilot apparatus for solvent delignifying 150 g samples of lignocellulosic feeds was completed. Also, an analysis method for characterizing the delignified product has been selected and tested. This is a method recommended in the Forage Fiber Handbook. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis. Work is continuing on characterizing the cellulase and cellobiase enzyme systems derived from the YX strain of Thermomonospora.

  14. Milestones for Selection Characterization and Analysis of the Performance of a Repository for Spent Nuclear Fuel and HIh-Level Radioactive Waste at Yucca Mountain.

    SciTech Connect (OSTI)

    Rechard, Robert P.

    2015-02-01

    This report presents a concise history in tabular form of events leading up to site identification in 1978, site selection in 1987, subsequent characterization, and ongoing analysis throu gh 2009 of the performance of a repository for spent nuclear fuel and high - level radi oactive waste at Yucca Mou ntain in southern Nevada. The tabulated events generally occurred in five periods: (1) commitment to mined geologic disposal and identification of sites; (2) site selection and analysis, based on regional geologic characterization through literature and an alogous data; (3) feasibility analysis demonstrating calculation procedures and importance of system components, based on rough measures of performance using surface exploration, waste process knowledge, and general laboratory experiments; (4) suitability analysis demonstrating viability of disposal system, based on environment - specific laboratory experiments, in - situ experiments, and underground disposal system characterization; and (5) compliance analysis, based on completed site - specific characterization . The current sixth period beyond 2010 represents a new effort to set waste management policy in the United States. Because the relationship is important to understanding the evolution of the Yucca Mountain Project , the tabulation also shows the interaction between the policy realm and technical realm using four broad categories of events : (a ) R egulatory requirements and related federal policy in laws and court decisions, (c ) Presidential and agency directives, (c) technical milestones of implemen ting institutions, and (d ) critiques of the Yucca Mountai n P roject and pertinent national and world events related to nuclear energy and radioactive waste. Preface The historical progression of technical milestones for the Yucca Mountain Project was originally developed for 10 journal articles in a special issue of Reliability Engineering System Safe ty on the performance assessment for the Yucca Mountain license application [ 1 - 10 ] . The listing of mile stones , a distinct feature of those articles, has been collected and tabulated here. A lthough a brief description is presented here (based on the summaries in the 10 journal articles) , t he emphasis remains on the tab ulation because of its usefulness in pro viding a comprehensive but concise history of the Yucca Mountain Project . T he tabulation presented here is more elaborate than originally presented in that many of the interactions that occurred between the technical realm and policy realm can be depicted in separate columns . The usefulness of the milestones table is due in part to L.A. Connolly, for editorial and reference support, and S.K. Best, Raytheon, and L. May s, Sandia National Laboratories ( SNL ) , for illustration support. Reviewers P.N. Swift, SNL , and K. Gupta, University of Oklahoma, helped improve the discussion. The historical perspective presented is that of the author and is not necessarily held by reviewers, Sandia National Laboratories , and the US Department of Energy. As a historic perspect ive, the author is reporting on the work of others; however, any interpretative erro r s of the documentation are those of the author alone. The characterization and modeling of the Yucca Mountain disposal system required numerous participants with expertise in many areas of science a nd technology, as evident from the extensive reference list. Their d iligent efforts are generally acknowledged here and through the many references to their impressive work , but the 10 journal articles acknowledge by name many of the numerous participants that contributed to the Yucca Mountain Project .

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Production Facility Tax Exemption Any newly constructed or expanded biomass-to-energy facility is exempt from state property taxes for up to 10 taxable years immediately following the taxable year in which construction or installation is completed. A biomass-to-energy facility includes any industrial process plant that uses biomass to produce at least 500,000 gallons of cellulosic alcohol fuel, liquid or gaseous fuel, or other source of energy in a quantity with energy content at least

  16. YUCCA MOUNTAIN WASTE PACKAGE CLOSURE SYSTEM

    SciTech Connect (OSTI)

    G. Housley; C. Shelton-davis; K. Skinner

    2005-08-26

    The method selected for dealing with spent nuclear fuel in the US is to seal the fuel in waste packages and then to place them in an underground repository at the Yucca Mountain Site in Nevada. This article describes the Waste Package Closure System (WPCS) currently being designed for sealing the waste packages.

  17. Fuel flexible fuel injector

    DOE Patents [OSTI]

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  18. Fuel Cycle Technologies Near Term Planning for Storage and Transporta...

    Office of Environmental Management (EM)

    Secretary plans to transport spent nuclear fuel or high-level radioactive waste to an ... for the transportation of used nuclear fuel and high-level radioactive waste. 6 ...

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel-Efficient Tire Program Development The California Energy Commission (CEC) must adopt and implement a state-wide Fuel-Efficient Tire Program that includes a consumer information and education program and minimum tire efficiency standards. The CEC must consult with the California Integrated Waste Management Board on the program's adoption, implementation, and regular review. (Reference California Public Resources Code 25770-2577

  20. Waste to Energy Power Production at DOE and DOD Sites

    Broader source: Energy.gov [DOE]

    Presentation by Joe Price, Ameresco, DOE-DOD Waste to Energy using Fuel Cells Workshop held Jan. 13, 2011

  1. Automotive Waste Heat Conversion to Electric Power using Skutterudites...

    Broader source: Energy.gov (indexed) [DOE]

    Development of a Scalable 10% Efficient Thermoelectric Generator Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Vehicular Applications of ...

  2. DOE small scale fuel alcohol plant design

    SciTech Connect (OSTI)

    LaRue, D.M.; Richardson, J.G.

    1980-01-01

    The Department of Energy, in an effort to facilitate the deployment of rural-based ethanol production capability, has undertaken this effort to develop a basic small-scale plant design capable of producing anhydrous ethanol. The design, when completed, will contain all necessary specifications and diagrams sufficient for the construction of a plant. The design concept is modular; that is, sections of the plant can stand alone or be integrated into other designs with comparable throughput rates. The plant design will be easily scaled up or down from the designed flow rate of 25 gallons of ethanol per hour. Conversion factors will be provided with the final design package to explain scale-up and scale-down procedures. The intent of this program is to provide potential small-scale producers with sound information about the size, engineering requirements, costs and level of effort in building such a system.

  3. Evaluations in support of regulatory and research decisions by the U. S. Environmental Protection Agency for the control of toxic hazards from hazardous wastes, glyphosate, dalapon, and synthetic fuels

    SciTech Connect (OSTI)

    Scofield, R.

    1984-01-01

    This report includes toxicological and regulatory evaluations performed in support of U.S. EPA regulation of toxic materials and hazardous wastes. The first section of the report describes evaluations which support: (a) the regulation of small-volume generators of hazardous wastes, (b) the regulation of hazardous wastes from pesticide manufacturing, and (c) the disposal of the herbicide, silvex. The second section describes the environmental fate, transport, and effect of glyphosate and dalapon. The third section deals with synthetic fuels, including evaluations of synfuel-product toxicity, uncontrolled air emissions, and particular focus on the toxicity of products from several indirect coal liquefaction processes including methanol synthesis, Fischer-Tropsch, Mobil M-Gasoline, and Lurgi gasification technologies. Three direct coal liquefaction processes were examined for product toxicity and air emissions: Solvent Refined Coal (I and II) and the Exxon Donor Solvent Process. Also described in the third section is an evaluation of environmental and health hazards associated with the use of synthetic fuels from indirect coal liquefaction, direct coal liquefaction, and shale oil. Finally, the fourth section discusses some problems associated with performing, on a contractual basis, scientific and technical evaluations in support of U.S. EPA regulatory and research decisions.

  4. Hige Compression Ratio Turbo Gasoline Engine Operation Using Alcohol Enhancement

    SciTech Connect (OSTI)

    Heywood, John; Jo, Young Suk; Lewis, Raymond; Bromberg, Leslie; Heywood, John

    2015-10-31

    The overall objective of this project was to quantify the potential for improving the performance and efficiency of gasoline engine technology by use of alcohols to suppress knock. Knock-free operation is obtained by direct injection of a second “anti-knock” fuel such as ethanol, which suppresses knock when, with gasoline fuel, knock would occur. Suppressing knock enables increased turbocharging, engine downsizing, and use of higher compression ratios throughout the engine’s operating map. This project combined engine testing and simulation to define knock onset conditions, with different mixtures of gasoline and alcohol, and with this information quantify the potential for improving the efficiency of turbocharged gasoline spark-ignition engines, and the on-vehicle fuel consumption reductions that could then be realized. The more focused objectives of this project were therefore to: Determine engine efficiency with aggressive turbocharging and downsizing and high compression ratio (up to a compression ratio of 13.5:1) over the engine’s operating range; Determine the knock limits of a turbocharged and downsized engine as a function of engine speed and load; Determine the amount of the knock-suppressing alcohol fuel consumed, through the use of various alcohol-gasoline and alcohol-water gasoline blends, for different driving cycles, relative to the gasoline consumed; Determine implications of using alcohol-boosted engines, with their higher efficiency operation, in both light-duty and medium-duty vehicle sectors.

  5. radioactive waste | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Home radioactive waste Y-12 completes waste removal project two years ahead of schedule U.S. Leads Fifth International Review Meeting on the Safety of Spent Fuel and Radioactive ...

  6. Canister arrangement for storing radioactive waste

    DOE Patents [OSTI]

    Lorenzo, Donald K.; Van Cleve, Jr., John E.

    1982-01-01

    The subject invention relates to a canister arrangement for jointly storing high level radioactive chemical waste and metallic waste resulting from the reprocessing of nuclear reactor fuel elements. A cylindrical steel canister is provided with an elongated centrally disposed billet of the metallic waste and the chemical waste in vitreous form is disposed in the annulus surrounding the billet.

  7. Canister arrangement for storing radioactive waste

    DOE Patents [OSTI]

    Lorenzo, D.K.; Van Cleve, J.E. Jr.

    1980-04-23

    The subject invention relates to a canister arrangement for jointly storing high level radioactive chemical waste and metallic waste resulting from the reprocessing of nuclear reactor fuel elements. A cylindrical steel canister is provided with an elongated centrally disposed billet of the metallic waste and the chemical waste in vitreous form is disposed in the annulus surrounding the billet.

  8. Nuclear waste management. Quarterly progress report, January-March 1980

    SciTech Connect (OSTI)

    Platt, A.M.; Powell, J.A.

    1980-06-01

    Reported are: high-level waste immobilization, alternative waste forms, nuclear waste materials characterization, TRU waste immobilization, TRU waste decontamination, krypton solidification, thermal outgassing, iodine-129 fixation, unsaturated zone transport, well-logging instrumentation development, mobile organic complexes of fission products, waste management system and safety studies, assessment of effectiveness of geologic isolation systems, waste/rock interactions, engineered barriers, criteria for defining waste isolation, and spent fuel and pool component integrity. (DLC)

  9. Waste-to-Energy Workshop Summary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... conversion of manure and organic substrates (waste) to middle distillate fuels ... with solid feedstocks (biomass, coal, pet coke, etc.) - Catalytic hydrothermal ...

  10. Update of the Used Fuel Disposition Campaign Implementation Plan

    Broader source: Energy.gov [DOE]

    The Used Fuel Disposition Campaign will identify alternatives and conduct scientific research and technology development to enable storage, transportation, and disposal of used nuclear fuel and wastes generated by existing and future nuclear fuel cycles.

  11. Infographic: The Fuel Cell Electric Vehicle (FCEV)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    gas * water (electrolysis) * biomass * waste products Uses Domestic Fuel Reduces Greenhouse Gas Emissions 50% 90% Operates Efficiently FCEV internal combustion 20-30% 60% ...

  12. Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

  13. Developing Engineered Fuel (Briquettes) Using Fly Ash from the Aquila Coal-Fired Power Plant in Canon City and Locally Available Biomass Waste

    SciTech Connect (OSTI)

    H. Carrasco; H. Sarper

    2006-06-30

    The objective of this research is to explore the feasibility of producing engineered fuels from a combination of renewable and non renewable energy sources. The components are flyash (containing coal fines) and locally available biomass waste. The constraints were such that no other binder additives were to be added. Listed below are the main accomplishments of the project: (1) Determination of the carbon content of the flyash sample from the Aquila plant. It was found to be around 43%. (2) Experiments were carried out using a model which simulates the press process of a wood pellet machine, i.e. a bench press machine with a close chamber, to find out the ideal ratio of wood and fly ash to be mixed to get the desired briquette. The ideal ratio was found to have 60% wood and 40% flyash. (3) The moisture content required to produce the briquettes was found to be anything below 5.8%. (4) The most suitable pressure required to extract the lignin form the wood and cause the binding of the mixture was determined to be 3000psi. At this pressure, the briquettes withstood an average of 150psi on its lateral side. (5) An energy content analysis was performed and the BTU content was determined to be approximately 8912 BTU/lb. (6) The environmental analysis was carried out and no abnormalities were noted. (7) Industrial visits were made to pellet manufacturing plants to investigate the most suitable manufacturing process for the briquettes. (8) A simulation model of extrusion process was developed to explore the possibility of using a cattle feed plant operating on extrusion process to produce briquettes. (9) Attempt to produce 2 tons of briquettes was not successful. The research team conducted a trial production run at a Feed Mill in La Junta, CO to produce two (2) tons of briquettes using the extrusion process in place. The goal was to, immediately after producing the briquettes; send them through Aquila's current system to test the ability of the briquettes to flow through the system without requiring any equipment or process changes. (10) Although the above attempt failed, the plant is still interested in producing briquettes. (11) An economic analysis of investing in a production facility manufacturing such briquettes was conducted to determine the economic viability of the project. Such a project is estimated to have an internal rate of return of 14% and net present value of about $400,000. (12) An engineering independent study class (4 students) is now working on selecting a site near the power plant and determining the layout of the future plant that will produce briquettes.

  14. Department of Energy Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs Draft Environmental Impact Statement. Volume 1, Appendix D, Part B: Naval spent nuclear fuel management

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This volume contains the following attachments: transportation of Naval spent nuclear fuel; description of Naval spent nuclear receipt and handling at the Expended Core Facility at the Idaho National Engineering Laboratory; comparison of storage in new water pools versus dry container storage; description of storage of Naval spent nuclear fuel at servicing locations; description of receipt, handling, and examination of Naval spent nuclear fuel at alternate DOE facilities; analysis of normal operations and accident conditions; and comparison of the Naval spent nuclear fuel storage environmental assessment and this environmental impact statement.

  15. Low emissions diesel fuel

    DOE Patents [OSTI]

    Compere, Alicia L.; Griffith, William L.; Dorsey, George F.; West, Brian H.

    1998-01-01

    A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  16. Low emissions diesel fuel

    DOE Patents [OSTI]

    Compere, A.L.; Griffith, W.L.; Dorsey, G.F.; West, B.H.

    1998-05-05

    A method and matter of composition for controlling NO{sub x} emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO{sub x} produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  17. Furfuryl alcohol cellular product

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-05-26

    Self-extinguishing rigid foam products are formed by polymerization of furfuryl alcohol in the presence of a lightweight, particulate, filler, zinc chloride and selected catalysts.

  18. Agricultural, industrial and municipal waste management

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    It is right that consideration of the environment is of prime importance when agricultural and industrial processes are being developed. This book compiles the papers presented at the Institution of Mechanical Engineers conference. The contents include: The use of wastes for land reclamation and restoration; landfill, an environmentally acceptable method of waste disposal and an economic source of energy; control of leachate from waste disposal landfill sites using bentonite; landfill gas migration from operational landfill sites, monitoring and prevention; monitoring of emissions from hazardous waste incineration; hazardous wastes management in Hong Kong, a summary of a report and recommendations; the techniques and problems of chemical analysis of waste waters and leachate from waste tips; a small scale waste burning combustor; energy recovery from municipal waste by incineration; anaerobic treatment of industrial waste; a review of developments in the acid hydrolysis of cellulosic wastes; reduction of slag deposits by magnesium hydroxide injection; integrated rural energy centres (for agriculture-based economies); resource recovery; straw as a fuel in the UK; the computer as a tool for predicting the financial implications of future municipal waste disposal and recycling projects; solid wastes as a cement kiln fuel; monitoring and control of landfill gas; the utilization of waste derived fuels; the economics of energy recovery from municipal and industrial wastes; the development and construction of a municipal waste reclamation plant by a local authority.

  19. Global Nuclear Energy Partnership Waste Treatment Baseline

    SciTech Connect (OSTI)

    Dirk Gombert; William Ebert; James Marra; Robert Jubin; John Vienna

    2008-05-01

    The Global Nuclear Energy Partnership program (GNEP) is designed to demonstrate a proliferation-resistant and sustainable integrated nuclear fuel cycle that can be commercialized and used internationally. Alternative stabilization concepts for byproducts and waste streams generated by fuel recycling processes were evaluated and a baseline of waste forms was recommended for the safe disposition of waste streams. Waste forms are recommended based on the demonstrated or expected commercial practicability and technical maturity of the processes needed to make the waste forms, and performance of the waste form materials when disposed. Significant issues remain in developing technologies to process some of the wastes into the recommended waste forms, and a detailed analysis of technology readiness and availability may lead to the choice of a different waste form than what is recommended herein. Evolving regulations could also affect the selection of waste forms.

  20. Department of Energy Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs, Draft Environmental Impact Statement. Volume 1, Appendix D: Part A, Naval Spent Nuclear Fuel Management

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    Volume 1 to the Department of Energy`s Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Management Programs Environmental Impact Statement evaluates a range of alternatives for managing naval spent nuclear fuel expected to be removed from US Navy nuclear-powered vessels and prototype reactors through the year 2035. The Environmental Impact Statement (EIS) considers a range of alternatives for examining and storing naval spent nuclear fuel, including alternatives that terminate examination and involve storage close to the refueling or defueling site. The EIS covers the potential environmental impacts of each alternative, as well as cost impacts and impacts to the Naval Nuclear Propulsion Program mission. This Appendix covers aspects of the alternatives that involve managing naval spent nuclear fuel at four naval shipyards and the Naval Nuclear Propulsion Program Kesselring Site in West Milton, New York. This Appendix also covers the impacts of alternatives that involve examining naval spent nuclear fuel at the Expended Core Facility in Idaho and the potential impacts of constructing and operating an inspection facility at any of the Department of Energy (DOE) facilities considered in the EIS. This Appendix also considers the impacts of the alternative involving limited spent nuclear fuel examinations at Puget Sound Naval Shipyard. This Appendix does not address the impacts associated with storing naval spent nuclear fuel after it has been inspected and transferred to DOE facilities. These impacts are addressed in separate appendices for each DOE site.

  1. A Combined Nonfertile and UO{sub 2} PWR Fuel Assembly for Actinide...

    Office of Scientific and Technical Information (OSTI)

    Assembly for Actinide Waste Minimization Citation Details In-Document Search Title: A Combined Nonfertile and UOsub 2 PWR Fuel Assembly for Actinide Waste Minimization A new ...

  2. Hydrothermal Processing of Wet Wastes

    Broader source: Energy.gov [DOE]

    Breakout Session 3A—Conversion Technologies III: Energy from Our Waste—Will we Be Rich in Fuel or Knee Deep in Trash by 2025? Hydrothermal Processing of Wet Wastes James R. Oyler, President, Genifuel Corporation

  3. Extracting alcohols from aqueous solutions

    DOE Patents [OSTI]

    Compere, Alicia L.; Googin, John M.; Griffith, William L.

    1984-01-01

    Hydrocarbon and surfactants are contacted with a solution of alcohol and water to extract the alcohol into the hydrocarbon-surfactant mixture.

  4. Integrated Waste Treatment Facility Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Management » Tank Waste and Waste Processing » Integrated Waste Treatment Facility Fact Sheet Integrated Waste Treatment Facility Fact Sheet The Integrated Waste Treatment Unit is a newly constructed facility that is designed to treat 900,000 gallons of radioactive liquid waste stored in underground tanks at a former Cold War spent nuclear fuel reprocessing facility located at DOE's Idaho Site. PDF icon IWTU at Idaho Fact Sheet More Documents & Publications Audit Report: OAS-L-10-03

  5. Cold start characteristics of ethanol as an automobile fuel

    DOE Patents [OSTI]

    Greiner, Leonard

    1982-01-01

    An alcohol fuel burner and decomposer in which one stream of fuel is preheated by passing it through an electrically heated conduit to vaporize the fuel, the fuel vapor is mixed with air, the air-fuel mixture is ignited and combusted, and the combustion gases are passed in heat exchange relationship with a conduit carrying a stream of fuel to decompose the fuel forming a fuel stream containing hydrogen gas for starting internal combustion engines, the mass flow of the combustion gas being increased as it flows in heat exchange relationship with the fuel carrying conduit, is disclosed.

  6. EIS-0250: Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, Nevada

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposed action to construct, operate, monitor, and eventually close a geologic repository at Yucca Mountain  for the disposal of spent nuclear fuel and high-level...

  7. Second National Report for the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management

    Broader source: Energy.gov [DOE]

    This second National Report updates the first National Report published on May 3, 2003, under the terms of the Joint Convention on the Safety of Spent Fuel Management and on the Safety of...

  8. Fuel farms: croplands of the future

    SciTech Connect (OSTI)

    Brown, L.R.

    1980-06-01

    A comprehensive report is given of the use of farmlands for the production of fuel, particularly the production of alcohol to produce gasohol (10% alcohol; 90% petroleum products). Brought about by increasing costs of oil, production of gasohol is proceeding on a worldwide basis led by Brazil, USA, South Africa, New Zealand and Australia. Trends are discussed as well as tax incentives for greater use of gasohol. Various crops are compared in terms of efficiency of conversion to alcohol and limits to production of alcohol by farmlands are considered. Worldwide interest and the competition between the affluent minority and the poorly nourished in developing countries for the products of farmlands are discussed (full tanks, empty stomachs). Economics of the alcohol fuel programs are considered as well as the by-products of the modified alcohol production process (which may be used for animal feed). It is concluded that an alcohol fuel industry is desirable, but many factors (economic, topsoil depletion, proper choice of crop, international communication and cooperation, priorities, uses of the fuel produced, political aspects, etc.) must be considered on a global scale. (MJJ)

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel and Advanced Vehicle Career Training The Clean Technology and Renewable Energy Job Training, Career Technical Education, and Dropout Prevention Program provides grant funding to school districts for occupational training programs that focus on employment in clean technology and renewable energy businesses, such as clean vehicle technologies, and cellulosic ethanol, biodiesel, biomass power, green waste, and fuel cell production. This program is subject to funding appropriation.

  10. Heavy Duty Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Specifications Ethanol-blended gasoline must conform to ASTM D4814, E85 must conform to ASTM D4806, and biodiesel-blended fuel containing at least 6%, but no more than 20%, biodiesel must conform to ASTM D7467. Additionally, biobutanol must be an agriculturally derived isobutyl alcohol that meets ASTM D7862 for butanol for blending with gasoline for use as a motor fuel. Gasoline blended with biobutanol must conform to ASTM D4814. The state defers to the U.S. Environmental Protection

  12. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  13. Radioactive waste material disposal

    DOE Patents [OSTI]

    Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.

    1995-01-01

    The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide.

  14. Radioactive waste material disposal

    DOE Patents [OSTI]

    Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

    1995-10-24

    The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide. 3 figs.

  15. Synthetic fuels handbook: properties, process and performance

    SciTech Connect (OSTI)

    Speight, J.

    2008-07-01

    The handbook is a comprehensive guide to the benefits and trade-offs of numerous alternative fuels, presenting expert analyses of the different properties, processes, and performance characteristics of each fuel. It discusses the concept systems and technology involved in the production of fuels on both industrial and individual scales. Chapters 5 and 7 are of special interest to the coal industry. Contents: Chapter 1. Fuel Sources - Conventional and Non-conventional; Chapter 2. Natural Gas; Chapter 3. Fuels From Petroleum and Heavy Oil; Chapter 4. Fuels From Tar Sand Bitumen; Chapter 5. Fuels From Coal; Chapter 6. Fuels From Oil Shale; Chapter 7. Fuels From Synthesis Gas; Chapter 8. Fuels From Biomass; Chapter 9. Fuels From Crops; Chapter 10. Fuels From Wood; Chapter 11. Fuels From Domestic and Industrial Waste; Chapter 12. Landfill Gas. 3 apps.

  16. No Fossils in This Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plan for Environmental Teaching GM Environmental Science Club No Fossils in This Fuel Your PlanET Sixth through Eighth Grades (Can be easily adapted to any elementary/middle school level) Ingredients: Yeast, sugar ... what are you making? Sweet rolls? Not in Science Class! You're blending these ingredients to make an innovative form of fuel! That's right ... when these two simple ingredients are mixed, the yeast  a simple, living organism  breaks the sugar down into ethyl alcohol, or

  17. Vitrification of NORM wastes

    SciTech Connect (OSTI)

    Chapman, C.

    1994-05-01

    Vitrification of wastes is a relatively new application of none of man`s oldest manufacturing processes. During the past 25 years it has been developed and accepted internationally for immobilizing the most highly radioactive wastes from spent nuclear fuel. By the year 2005, there will be nine operating high-level radioactive vitrification plants. Many of the technical ``lessons learned`` from this international program can be applied to much less hazardous materials such as naturally occurring radioactive material (NORM). With the deployment of low capital and operating cost systems, vitrification should become a broadly applied process for treating a large variety of wastes. In many situations, the wastes can be transformed into marketable products. This paper will present a general description of waste vitrification, summarize some of its key advantages, provide some test data for a small sample of one NORM, and suggest how this process may be applied to NORM.

  18. Transuranic waste disposal in the United States

    SciTech Connect (OSTI)

    Hoffman, R.B.

    1986-01-01

    The United States is unique in having created a special class of radioactive waste disposal based on the concentration of transuranic elements in the waste. Since 1970, the US has been placing newly generated transuranic waste in retrievable storage. It is intended that these wastes will be placed in a permanent deep geologic repository, the Waste Isolation Pilot Plant (WIPP). WIPP opening for a demonstration emplacement period is set for October, 1988. Transuranic wastes derive from some of the manufacturing and research activities carried out by DOE. The bulk of this waste is generated in plutonium parts fabrication activities. A variety of plutonium contaminated materials ranging from glove boxes, HEPA filters, and machine tools, to chemical sludges derived from plutonium recovery streams are stored as TRU wastes. Other processes that generate TRU waste are plutonium production operations, preparation for and cleanup from fuel reprocessing, manufacturing of plutonium heat sources, and nuclear fuel cycle research activities.

  19. Long-term management of high-level radioactive waste (HLW) and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Long-term management of high-level radioactive waste (HLW) and spent nuclear fuel (SNF) Long-term management of high-level radioactive waste (HLW) and spent nuclear fuel (SNF) ...

  20. Report of the DOD-DOE Workshop on Converting Waste to Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOD-DOE Workshop on Converting Waste to Energy Using Fuel Cells: Workshop Summary and Action Plan Report of the DOD-DOE Workshop on Converting Waste to Energy Using Fuel Cells: ...

  1. Nuclear waste management. Quarterly progress report, October through December 1980

    SciTech Connect (OSTI)

    Chikalla, T.D.; Powell, J.A.

    1981-03-01

    Progress reports and summaries are presented under the following headings: high-level waste process development; alternative waste forms; nuclear waste materials characterization center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of radionuclides in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; high level waste form preparation; development of backfill material; development of structural engineered barriers; ONWI disposal charge analysis; spent fuel and fuel component integrity program; analysis of spent fuel policy implementation; analysis of postulated criticality events in a storage array of spent LWR fuel; asphalt emulsion sealing of uranium tailings; liner evaluation for uranium mill tailings; multilayer barriers for sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; revegetation of inactive uranium tailing sites; verification instrument development.

  2. 5-Carbon Alcohols for Drop-in Gasoline Replacement - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Vehicles and Fuels Vehicles and Fuels Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search 5-Carbon Alcohols for Drop-in Gasoline Replacement Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryJay Keasling and Howard Chou of Berkeley Lab and the Joint BioEnergy Institute (JBEI) have invented a fermentation process to produce 5-carbon alcohols from genetically modified E. coli host cells regardless of the

  3. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, T.D.; Smith, J.L.

    1986-07-08

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  4. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D.; Smith, James L.

    1987-01-01

    A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  5. Method for aqueous radioactive waste treatment

    DOE Patents [OSTI]

    Bray, Lane A.; Burger, Leland L.

    1994-01-01

    Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions.

  6. Method for aqueous radioactive waste treatment

    DOE Patents [OSTI]

    Bray, L.A.; Burger, L.L.

    1994-03-29

    Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions. 3 figures.

  7. Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication

    SciTech Connect (OSTI)

    Steven Frank; Hwan Seo Park; Yung Zun Cho; William Ebert; Brian Riley

    2015-07-01

    This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea – ROK) and United States of America (US) ‘centric’ in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration between US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.

  8. A metallic fuel cycle concept from spent oxide fuel to metallic fuel

    SciTech Connect (OSTI)

    Fujita, Reiko; Kawashima, Masatoshi; Yamaoka, Mitsuaki; Arie, Kazuo; Koyama, Tadafumi

    2007-07-01

    A Metallic fuel cycle concept for Self-Consistent Nuclear Energy System (SCNES) has been proposed in a companion papers. The ultimate goal of the SCNES is to realize sustainable energy supply without endangering the environment and humans. For future transition period from LWR era to SCNES era, a new metallic fuel recycle concept from LWR spent fuel has been proposed in this paper. Combining the technology for electro-reduction of oxide fuels and zirconium recovery by electrorefining in molten salts in the nuclear recycling schemes, the amount of radioactive waste reduced in a proposed metallic fuel cycle concept. If the recovery ratio of zirconium metal from the spent zirconium waste is 95%, the cost estimation in zirconium recycle to the metallic fuel materials has been estimated to be less than 1/25. (authors)

  9. Correlation of radioactive-waste-treatment costs and the environmental impact of waste effluents in the nuclear fuel cycle: conversion of yellow cake to uranium hexafluoride. Part II. The solvent extraction-fluorination process

    SciTech Connect (OSTI)

    Sears, M.B.; Etnier, E.L.; Hill, G.S.; Patton, B.D.; Witherspoon, J.P.; Yen, S.N.

    1983-03-01

    A cost/benefit study was made to determine the cost and effectiveness of radioactive waste (radwaste) treatment systems for decreasing the release of radioactive materials and chemicals from a model uranium hexafluoride (UF/sub 6/) production plant using the solvent extraction-fluorination process, and to evaluate the radiological impact (dose commitment) of the release materials on the environment. The model plant processes 10,000 metric tons of uranium per year. Base-case waste treatment is the minimum necessary to operate the process. Effluents meet the radiological requirements listed in the Code of Federal Regulations, Title 10, Part 20 (10 CFR 20), Appendix B, Table II, but may not be acceptable chemically at all sites. Additional radwaste treatment techniques are applied to the base-case plant in a series of case studies to decrease the amounts of radioactive materials released and to reduce the amounts of radioactive materials released and to reduce the radiological dose commitment to the population in the surrounding area. The costs for the added waste treatment operations and the corresponding dose committment are correlated with the annual cost for treatment of the radwastes. The status of the radwaste treatment methods used in the case studies is discussed. Much of the technology used in the advanced cases will require development and demonstration, or else is proprietary and unavailable for immediate use. The methodology and assumptions for the radiological doses are found in ORNL-4992.

  10. Spent fuel storage alternatives

    SciTech Connect (OSTI)

    O'Connell, R.H.; Bowidowicz, M.A.

    1983-01-01

    This paper compares a small onsite wet storage pool to a dry cask storage facility in order to determine what type of spent fuel storage alternatives would best serve the utilities in consideration of the Nuclear Waste Policy Act of 1982. The Act allows the DOE to provide a total of 1900 metric tons (MT) of additional spent fuel storage capacity to utilities that cannot reasonably provide such capacity for themselves. Topics considered include the implementation of the Act (DOE away-from reactor storage), the Act's impact on storage needs, and an economic evaluation. The Waste Act mandates schedules for the determination of several sites, the licensing and construction of a high-level waste repository, and the study of a monitored retrievable storage facility. It is determined that a small wet pool storage facility offers a conservative and cost-effective approach for many stations, in comparison to dry cask storage.

  11. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  12. Corrosion mechanisms for metal alloy waste forms: experiment and theory Level 4 Milestone M4FT-14LA0804024 Fuel Cycle Research & Development

    SciTech Connect (OSTI)

    Liu, Xiang-Yang; Taylor, Christopher D.; Kim, Eunja; Goff, George Scott; Kolman, David Gary

    2014-07-31

    This document meets Level 4 Milestone: Corrosion mechanisms for metal alloy waste forms - experiment and theory. A multiphysics model is introduces that will provide the framework for the quantitative prediction of corrosion rates of metallic waste forms incorporating the fission product Tc. The model requires a knowledge of the properties of not only the metallic waste form, but also the passive oxide films that will be generated on the waste form, and the chemistry of the metal/oxide and oxide/environment interfaces. in collaboration with experimental work, the focus of this work is on obtaining these properties from fundamental atomistic models. herein we describe the overall multiphysics model, which is based on MacDonald's point-defect model for passivity. We then present the results of detailed electronic-structure calculations for the determination of the compatibility and properties of Tc when incorporated into intermetallic oxide phases. This work is relevant to the formation of multi-component oxides on metal surfaces that will incorporate Tc, and provide a kinetic barrier to corrosion (i.e. the release of Tc to the environment). Atomistic models that build upon the electronic structure calculations are then described using the modified embedded atom method to simulate metallic dissolution, and Buckingham potentials to perform classical molecular dynamics and statics simulations of the technetium (and, later, iron-technetium) oxide phases. Electrochemical methods were then applied to provide some benchmark information of the corrosion and electrochemical properties of Technetium metal. The results indicate that published information on Tc passivity is not complete and that further investigation is warranted.

  13. Fully ceramic nuclear fuel and related methods

    DOE Patents [OSTI]

    Venneri, Francesco; Katoh, Yutai; Snead, Lance Lewis

    2016-03-29

    Various embodiments of a nuclear fuel for use in various types of nuclear reactors and/or waste disposal systems are disclosed. One exemplary embodiment of a nuclear fuel may include a fuel element having a plurality of tristructural-isotropic fuel particles embedded in a silicon carbide matrix. An exemplary method of manufacturing a nuclear fuel is also disclosed. The method may include providing a plurality of tristructural-isotropic fuel particles, mixing the plurality of tristructural-isotropic fuel particles with silicon carbide powder to form a precursor mixture, and compacting the precursor mixture at a predetermined pressure and temperature.

  14. FACT SHEET: The Path Forward on Nuclear Waste Disposal | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy FACT SHEET: The Path Forward on Nuclear Waste Disposal FACT SHEET: The Path Forward on Nuclear Waste Disposal PDF icon FACT SHEET: The Path Forward on Nuclear Waste Disposal More Documents & Publications Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste Integrated Waste Management and Consent-Based Siting Booklet

  15. Tank Closure and Waste Management Environmental Impact Statement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... tank waste and provide for final disposition of the SSTs. ... 1968 to 1986 to support fuel reprocessing, isotope ... and have a total waste volume that is less than 1 ...

  16. Used Fuel Disposition Campaign International Activities Implementation Plan

    Broader source: Energy.gov [DOE]

    The management of used nuclear fuel and nuclear waste is required for any country using nuclear energy. This includes the storage, transportation, and disposal of low and intermediate level waste ...

  17. New developments in RTR fuel recycling

    SciTech Connect (OSTI)

    Lelievre, F.; Brueziere, J.; Domingo, X.; Valery, J.F.; Leroy, J.F.; Tribout-Maurizi, A.

    2013-07-01

    As most utilities in the world, Research and Test Reactors (RTR) operators are currently facing two challenges regarding the fuel, in order to comply with local safety and waste management requirements as well as global non-proliferation obligation: - How to manage used fuel today, and - How fuel design changes that are currently under development will influence used fuel management. AREVA-La-Hague plant has a large experience in used fuel recycling, including traditional RTR fuel (UAl). Based on that experience and deep knowledge of RTR fuel manufacturing, AREVA is currently examining possible options to cope with both challenges. This paper describes the current experience of AREVA-La-Hague in UAl used fuels recycling and its plan to propose recycling for various types of fuels such as U{sub 3}Si{sub 2} fuel or UMo fuel on an industrial scale. (authors)

  18. Global Nuclear Energy Partnership Fact Sheet - Minimize Nuclear Waste |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Minimize Nuclear Waste Global Nuclear Energy Partnership Fact Sheet - Minimize Nuclear Waste GNEP will increase the efficiency in the management of used nuclear fuel, also known as spent fuel, and defer the need for additional geologic nuclear waste repositories until the next century. PDF icon Global Nuclear Energy Partnership Fact Sheet - Minimize Nuclear Waste More Documents & Publications GNEP Element:Develop Enhanced Nuclear Safeguards Global Nuclear Energy

  19. Chemicals, fuels and electricity from coal. A proposed tri-generation concept for utilization of CO{sub 2} from power plants

    SciTech Connect (OSTI)

    Song, C.

    1999-07-01

    A tri-generation concept is proposed for the 21st century for making liquid fuels and chemicals along with electricity using CO{sub 2} from flue gases of coal-based electric power plants. The CO{sub 2} from flue gas in the power plant can be converted with CH{sub 4} (natural gas) to form synthesis gas (CO and H{sub 2} mixture) using the waste heat in the power plant. The H{sub 2}O and O{sub 2} in the flue gas will be used as co-reactants and need not be separated from the flue gas. The hot synthesis gas can be used as feedstock for fuel cells for electricity generation (such as MCFC and SOFC). The hot synthesis gas can also be used for gas turbines to generate electricity. The synthesis gas at moderate temperature can be converted into chemicals and fuels, e.g., methanol and mixed alcohols for chemical and fuel uses, dimethylether (DME) and mixed ethers for diesel fuel, dimethyl carbonate and acetic acid for chemicals. The fuels thus produced may be used either for conventional IC engines or in fuel cell-driven vehicles. This concept could also be applied, in principle, for natural gas-based power plants and IGCC power plants.

  20. DOD -DOE MOU WTE Using Fuel Cells Briefing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOD -DOE MOU WTE Using Fuel Cells Briefing DOD -DOE MOU WTE Using Fuel Cells Briefing Presentation at Waste-to-Energy using Fuel Cells Webinar, July 13, 2011 PDF icon ...

  1. Fermentative alcohol production

    DOE Patents [OSTI]

    Wilke, Charles R.; Maiorella, Brian L.; Blanch, Harvey W.; Cysewski, Gerald R.

    1982-01-01

    An improved fermentation process for producing alcohol which includes the combination of vacuum fermentation and vacuum distillation. Preferably, the vacuum distillation is carried out in two phases, one a fermentor proper operated at atmospheric pressure and a flash phase operated at reduced pressure with recycle of fermentation brew having a reduced alcohol content to the fermentor, using vapor recompression heating of the flash-pot recycle stream to heat the flash-pot or the distillation step, and using "water load balancing" (i.e., the molar ratio of water in the fermentor feed is the same as the molar ratio of water in the distillation overhead).

  2. Process for immobilizing plutonium into vitreous ceramic waste forms

    DOE Patents [OSTI]

    Feng, X.; Einziger, R.E.

    1997-01-28

    Disclosed is a method for converting spent nuclear fuel and surplus plutonium into a vitreous ceramic final waste form wherein spent nuclear fuel is bound in a crystalline matrix which is in turn bound within glass.

  3. Process for immobilizing plutonium into vitreous ceramic waste forms

    DOE Patents [OSTI]

    Feng, X.; Einziger, R.E.

    1997-08-12

    Disclosed is a method for converting spent nuclear fuel and surplus plutonium into a vitreous ceramic final waste form wherein spent nuclear fuel is bound in a crystalline matrix which is in turn bound within glass.

  4. Process for immobilizing plutonium into vitreous ceramic waste forms

    DOE Patents [OSTI]

    Feng, Xiangdong; Einziger, Robert E.

    1997-01-01

    Disclosed is a method for converting spent nuclear fuel and surplus plutonium into a vitreous ceramic final waste form wherein spent nuclear fuel is bound in a crystalline matrix which is in turn bound within glass.

  5. Challenges and Opportunities for Wet-Waste Feedstocks - Resource...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications "Wet" Waste-to-Energy in the Bioenergy Technologies Office Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling, and Wastewater ...

  6. Use Feedwater Economizers for Waste Heat Recovery, Energy Tips...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Use Feedwater Economizers for Waste Heat Recovery A feedwater economizer reduces steam boiler fuel requirements by transferring heat from the fue gas to incoming feedwater. Boiler ...

  7. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Develop thermoelectric technology for waste heat recovery with a 10% fuel economy ... More Documents & Publications Engineering and Materials for Automotive Thermoelectric ...

  8. Experience in preparing fuel for combustion

    SciTech Connect (OSTI)

    Rude, J.

    1995-09-01

    The key phase seems to be that wood is the ORIGINAL FUEL. Certainly as man discovered fire, it was the most obvious as well as abundantly available fuel and it burned very well because man was smart enough to select the dry wood once he understood the basics of combustion. As the needs started to go beyond the most elementary, designs for burning ideal fuels were pretty well perfected, however, the burning of less ideal fuels still remain a challenge. To provide plant steam requirements by burning waste that must be disposed of anyway can reduce operating cost considerably. For most of us involved in producing steam, the experience we have with fuels such as bark, wood waste, sludge, and miscellaneous forms of solid combustible waste material, are a result of burning these fuels in an existing boiler supposedly designed for wood waste or possibly a combination of wood and other fuels such as coal, oil, or gas. For a supplier of fuel preparation systems, the typical application involves the sizing, cleaning, and drying of wood waste, and sludge from a pulp and/or paper mill. Other forms of combustible waste are dealt with occasionally and after proper preparation fired in the combustion system for the purpose of generating hot gas and/or steam for the plant process.

  9. American Ref Fuel Corporation ARC | Open Energy Information

    Open Energy Info (EERE)

    Ref Fuel Corporation ARC Jump to: navigation, search Name: American Ref-Fuel Corporation (ARC) Place: Montvale, NJ, New Jersey Zip: 76450 Product: Focused on waste-to-energy...

  10. Strategy for the Management and Disposal of Used Nuclear Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level ...

  11. State Level Incentives for Biogas-Fuel Cell Projects

    Broader source: Energy.gov [DOE]

    State policy and legislative outlook for biogas and fuel cells. Presented by Norma McDonald, Organic Waste Systems, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

  12. ESE Alcohol | Open Energy Information

    Open Energy Info (EERE)

    ESE Alcohol Jump to: navigation, search Name: ESE Alcohol Place: Leoti, Kansas Zip: 67861 Product: Owner of a 6.6m litre per year ethanol plant Coordinates: 38.481425,...

  13. Production of hydrogen from alcohols

    DOE Patents [OSTI]

    Deluga, Gregg A.; Schmidt, Lanny D.

    2007-08-14

    A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

  14. National Report Joint Convention on the Safety of Spent Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Report Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management National Report Joint Convention on the Safety of Spent ...

  15. Webinar: Procuring Fuel Cells for Stationary Power: A Guide for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The speaker today is Pete Devlin, the Fuel Cell Technologies Office's Market ... which means the ability to use waste biogas from wastewater treatment plants or landfills. ...

  16. Biogas and Fuel Cells Workshop Summary Report: Proceedings from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to discuss biogas and waste-to-energy technologies for fuel cell applications. The overall objective was to identify opportunities for coupling renewable biomethane with highly ...

  17. Comprehensive Fuel Cycle Research Study Presented to the Savannah...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comprehensive Fuel Cycle Research Study Presented to the Savannah River Site Community Reuse ... In the United States, the Waste Isolation Pilot Plant ("WIPP") located in southeast ...

  18. Microchannel High-Temperature Recuperator for Fuel Cell Systems

    SciTech Connect (OSTI)

    2010-02-01

    This factsheet describes a research project whose goal is to build an efficient, microchannel-based waste heat recuperator for a high-temperature fuel cell system.

  19. Waste utilization as an energy source: Municipal wastes. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    The bibliography contains citations concerning the utilization of municipal wastes as an energy source. Articles discuss energy derived from incineration/combustion, refuse-derived fuels, co-firing municipal waste and standard fuels, landfill gas production, sewage combustion, and other waste-to-energy technologies. Citations address economics and efficiencies of various schemes to utilize municipal waste products as energy sources. (Contains a minimum of 130 citations and includes a subject term index and title list.)

  20. Nuclear waste management. Quarterly progress report, April-June 1980

    SciTech Connect (OSTI)

    Platt, A.M.; Powell, J.A.

    1980-09-01

    The status of the following programs is reported: high-level waste immobilization; alternative waste forms; Nuclear Waste Materials Characterization Center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of fission products in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; systems study on engineered barriers; criteria for defining waste isolation; spent fuel and fuel pool component integrity program; analysis of spent fuel policy implementation; asphalt emulsion sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; and development of backfill material.

  1. Hybrid systems process mixed wastes

    SciTech Connect (OSTI)

    Chertow, M.R.

    1989-10-01

    Some technologies, developed recently in Europe, combine several processes to separate and reuse materials from solid waste. These plants have in common, generally, that they are reasonably small, have a composting component for the organic portion, and often have a refuse-derived fuel component for combustible waste. Many European communities also have very effective drop-off center programs for recyclables such as bottles and cans. By maintaining the integrity of several different fractions of the waste, there is a less to landfill and less to burn. The importance of these hybrid systems is that they introduce in one plant an approach that encompasses the key concept of today's solid waste planning; recover as much as possible and landfill as little as possible. The plants also introduce various risks, particularly of finding secure markets. There are a number of companies offering various combinations of materials recovery, composting, and waste combustion. Four examples are included: multiple materials recovery and refuse-derived fuel production in Eden Prairie, Minnesota; multiple materials recovery, composting and refuse-derived fuel production in Perugia, Italy; composting, refuse-derived fuel, and gasification in Tolmezzo, Italy; and a front-end system on a mass burning waste-to-energy plant in Neuchatel, Switzerland.

  2. Alcoholes Biocarburantes de Extremadura Albiex | Open Energy...

    Open Energy Info (EERE)

    search Name: Alcoholes Biocarburantes de Extremadura (Albiex) Place: Spain Product: Spanish bioethanol producer building a plant in Extremadura. References: Alcoholes...

  3. Geothermal source potential and utilization for alcohol production

    SciTech Connect (OSTI)

    Austin, J.C.

    1981-11-01

    A study was conducted to assess the technical and economic feasibility of using a potential geothermal source to drive a fuel grade alcohol plant. Test data from the well at the site indicated that the water temperature at approximately 8500 feet should approach 275/sup 0/F. However, no flow data was available, and so the volume of hot water that can be expected from a well at this site is unknown. Using the available data, numerous fuel alcohol production processes and various heat utilization schemes were investigated to determine the most cost effective system for using the geothermal resource. The study found the direct application of hot water for alcohol production based on atmospheric processes using low pressure steam to be most cost effective. The geothermal flow rates were determined for various sizes of alcohol production facility using 275/sup 0/F water, 235/sup 0/F maximum processing temperature, 31,000 and 53,000 Btu per gallon energy requirements, and appropriate process approach temperatures. It was determined that a 3 million gpy alcohol plant is the largest facility that can practically be powered by the flow from one large geothermal well. An order-of-magnitude cost estimate was prepared, operating costs were calculated, the economic feasibility of the propsed project was examined, and a sensitivity analysis was performed.

  4. Fuel Cycle Research & Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cycle Research & Development Fuel Cycle Research & Development Fuel Cycle Research & Development The mission of the Fuel Cycle Research and Development (FCRD) program is to conduct research and development to help develop sustainable fuel cycles, as described in the Nuclear Energy Research and Development Roadmap. Sustainable fuel cycle options are those that improve uranium resource utilization, maximize energy generation, minimize waste generation, improve safety, and limit

  5. Alternatives to traditional transportation fuels 1994. Volume 1

    SciTech Connect (OSTI)

    1996-02-01

    In this report, alternative and replacement fuels are defined in accordance with the EPACT. Section 301 of the EPACT defines alternative fuels as: methanol, denatured ethanol, and other alcohols; mixtures containing 85% or more (or such other percentage, but not less than 70%, as determined by the Secretary of Energy, by rule, to provide for requirements relating to cold start, safety, or vehicle functions) by volume of methanol, denatured ethanol, and other alcohols with gasoline or other fuels; natural gas; liquefied petroleum gas; hydrogen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials; electricity (including electricity from solar energy); and any other fuel the Secretary determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. The EPACT defines replacement fuels as the portion of any motor fuel that is methanol, ethanol, or other alcohols, natural gas, liquefied petroleum gas, hydrogen, coal-derived liquid fuels, fuels (other than alcohol) derived from biological materials, electricity (including electricity from solar energy), ethers, or any other fuel the Secretary of Energy determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. This report covers only those alternative and replacement fuels cited in the EPACT that are currently commercially available or produced in significant quantities for vehicle demonstration purposes. Information about other fuels, such as hydrogen and biodiesel, will be included in later reports as those fuels become more widely used. Annual data are presented for 1992 to 1996. Data for 1996 are based on plans or projections for 1996.

  6. Nuclear Fuel Cycle | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cycle Nuclear Fuel Cycle GC-52 provides legal advice to DOE regarding research and development of nuclear fuel and waste management technologies that meet the nation's energy supply, environmental, and energy security needs. GC-52 also advises DOE on issues involving support for international fuel cycle initiatives aimed at advancing a common vision of the necessity of the expansion of nuclear energy for peaceful purposes worldwide in a safe and secure manner. In addition, GC-52 provides

  7. Nuclear Waste Policy Act.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office of Civilian Radioactive Waste Management Washington, D.C. 20585 March 2004 i THE NUCLEAR WASTE POLICY ACT OF 1982 1 An Act to provide for the development of repositories for the disposal of high-level radioactive waste and spent nuclear fuel, to establish a program of research, development, and demonstration regarding the disposal of high-level radioactive waste and spent nuclear fuel, and for other purposes. Be it enacted by the Senate and House of Representatives of the United States of

  8. Waste Determination Equivalency - 12172

    SciTech Connect (OSTI)

    Freeman, Rebecca D.

    2012-07-01

    The Savannah River Site (SRS) is a Department of Energy (DOE) facility encompassing approximately 800 square kilometers near Aiken, South Carolina which began operations in the 1950's with the mission to produce nuclear materials. The SRS contains fifty-one tanks (2 stabilized, 49 yet to be closed) distributed between two liquid radioactive waste storage facilities at SRS containing carbon steel underground tanks with storage capacities ranging from 2,800,000 to 4,900,000 liters. Treatment of the liquid waste from these tanks is essential both to closing older tanks and to maintaining space needed to treat the waste that is eventually vitrified or disposed of onsite. Section 3116 of the Ronald W. Reagan National Defense Authorization Act of Fiscal Year 2005 (NDAA) provides the Secretary of Energy, in consultation with the Nuclear Regulatory Commission (NRC), a methodology to determine that certain waste resulting from prior reprocessing of spent nuclear fuel are not high-level radioactive waste if it can be demonstrated that the waste meets the criteria set forth in Section 3116(a) of the NDAA. The Secretary of Energy, in consultation with the NRC, signed a determination in January 2006, pursuant to Section 3116(a) of the NDAA, for salt waste disposal at the SRS Saltstone Disposal Facility. This determination is based, in part, on the Basis for Section 3116 Determination for Salt Waste Disposal at the Savannah River Site and supporting references, a document that describes the planned methods of liquid waste treatment and the resulting waste streams. The document provides descriptions of the proposed methods for processing salt waste, dividing them into 'Interim Salt Processing' and later processing through the Salt Waste Processing Facility (SWPF). Interim Salt Processing is separated into Deliquification, Dissolution, and Adjustment (DDA) and Actinide Removal Process/Caustic Side Solvent Extraction Unit (ARP/MCU). The Waste Determination was signed by the Secretary of Energy in January of 2006 based on proposed processing techniques with the expectation that it could be revised as new processing capabilities became viable. Once signed, however, it became evident that any changes would require lengthy review and another determination signed by the Secretary of Energy. With the maturation of additional salt removal technologies and the extension of the SWPF start-up date, it becomes necessary to define 'equivalency' to the processes laid out in the original determination. For the purposes of SRS, any waste not processed through Interim Salt Processing must be processed through SWPF or an equivalent process, and therefore a clear statement of the requirements for a process to be equivalent to SWPF becomes necessary. (authors)

  9. Catalyst Activity Comparison of Alcohols over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-01-01

    Alcohol transformation to transportation fuel range hydrocarbon on HZSM-5 (SiO2 / Al2O3 = 30) catalyst was studied at 360oC and 300psig. Product distributions and catalyst life were compared using methanol, ethanol, 1-propanol or 1-butanol as a feed. The catalyst life for 1-propanol and 1-butanol was more than double compared to that for methanol and ethanol. For all the alcohols studied, the product distributions (classified to paraffin, olefin, napthene, aromatic and naphthalene compounds) varied with time on stream (TOS). At 24 hours TOS, liquid product from 1-propanol and 1-butanol transformation primarily contains higher olefin compounds. The alcohol transformation process to higher hydrocarbon involves a complex set of reaction pathways such as dehydration, oligomerization, dehydrocyclization, and hydrogenation. Compared to ethylene generated from methanol and ethanol, oligomerization of propylene and butylene has a lower activation energy and can readily take place on weaker acidic sites. On the other hand, dehydrocyclization of propylene and butylene to form the cyclic compounds requires the sits with stronger acid strength. Combination of the above mentioned reasons are the primary reasons for olefin rich product generated in the later stage of the time on stream and for the extended catalyst life time for 1 propanol and 1 butanol compared to methanol and ethanol conversion over HZSM-5.

  10. The production of fuels and chemicals from food processing wastes using a novel fermenter separator. Annual progress report, January 1991--December 1991

    SciTech Connect (OSTI)

    Dale, M.C.; Venkatesh, K.V.; Choi, Hojoon; Moelhman, M.; Saliceti, L.; Okos, M.R.; Wankat, P.C.

    1991-12-01

    During 1991, considerable progress was made on the waste utilization project. Two small Wisconsin companies have expressed an interest in promoting and developing the ICRS technology. Pilot plant sites at (1) Hopkinton, IA, for a sweet whey plant, and Beaver Dam WI, for an acid whey site have been under development siting ICRS operations. The Hopkinton, IA site is owned and operated by Permeate Refining Inc., who have built a batch ethanol plant across the street from Swiss Valley Farms cheddar cheese operations. Permeate from Swiss Valley is piped across to PRI. PRI has signed a contract to site a 300--500,000 gallon/yr to ICRS pilot plant. They feel that the lower labor, lower energy, continuous process offered by the ICRS will substantially improve their profitability. Catalytics, Inc, is involved with converting whey from a Kraft cream cheese operation to ethanol and yeast. A complete project including whey concentration, sterilization, and yeast growth has been designed for this site. Process design improvements with the ICRS focussed on ethanol recovery techniques during this year`s project. A solvent absorption/extractive distillation (SAED) process has been developed which offers the capability of obtaining an anhydrous ethanol product from vapors off 3 to 9% ethanol solutions using very little energy for distillation. Work on products from waste streams was also performed. a. Diacetyl as a high value flavor compound was very successfully produced in a Stirred Tank Reactor w/Separation. b. Yeast production from secondary carbohydrates in the whey, lactic acid, and glycerol was studied. c. Lactic acid production from cellulose and lactose studies continued. d. Production of anti-fungal reagents by immobilized plant cells; Gossypol has antifungal properties and is produced by G. arboretum.

  11. Advanced Fuel Cycle Cost Basis

    SciTech Connect (OSTI)

    D. E. Shropshire; K. A. Williams; W. B. Boore; J. D. Smith; B. W. Dixon; M. Dunzik-Gougar; R. D. Adams; D. Gombert; E. Schneider

    2009-12-01

    This report, commissioned by the U.S. Department of Energy (DOE), provides a comprehensive set of cost data supporting a cost analysis for the relative economic comparison of options for use in the Advanced Fuel Cycle Initiative (AFCI) Program. The report describes the AFCI cost basis development process, reference information on AFCI cost modules, a procedure for estimating fuel cycle costs, economic evaluation guidelines, and a discussion on the integration of cost data into economic computer models. This report contains reference cost data for 25 cost modules—23 fuel cycle cost modules and 2 reactor modules. The cost modules were developed in the areas of natural uranium mining and milling, conversion, enrichment, depleted uranium disposition, fuel fabrication, interim spent fuel storage, reprocessing, waste conditioning, spent nuclear fuel (SNF) packaging, long-term monitored retrievable storage, near surface disposal of low-level waste (LLW), geologic repository and other disposal concepts, and transportation processes for nuclear fuel, LLW, SNF, transuranic, and high-level waste.

  12. Advanced Fuel Cycle Cost Basis

    SciTech Connect (OSTI)

    D. E. Shropshire; K. A. Williams; W. B. Boore; J. D. Smith; B. W. Dixon; M. Dunzik-Gougar; R. D. Adams; D. Gombert; E. Schneider

    2008-03-01

    This report, commissioned by the U.S. Department of Energy (DOE), provides a comprehensive set of cost data supporting a cost analysis for the relative economic comparison of options for use in the Advanced Fuel Cycle Initiative (AFCI) Program. The report describes the AFCI cost basis development process, reference information on AFCI cost modules, a procedure for estimating fuel cycle costs, economic evaluation guidelines, and a discussion on the integration of cost data into economic computer models. This report contains reference cost data for 25 cost modules—23 fuel cycle cost modules and 2 reactor modules. The cost modules were developed in the areas of natural uranium mining and milling, conversion, enrichment, depleted uranium disposition, fuel fabrication, interim spent fuel storage, reprocessing, waste conditioning, spent nuclear fuel (SNF) packaging, long-term monitored retrievable storage, near surface disposal of low-level waste (LLW), geologic repository and other disposal concepts, and transportation processes for nuclear fuel, LLW, SNF, transuranic, and high-level waste.

  13. Advanced Fuel Cycle Cost Basis

    SciTech Connect (OSTI)

    D. E. Shropshire; K. A. Williams; W. B. Boore; J. D. Smith; B. W. Dixon; M. Dunzik-Gougar; R. D. Adams; D. Gombert

    2007-04-01

    This report, commissioned by the U.S. Department of Energy (DOE), provides a comprehensive set of cost data supporting a cost analysis for the relative economic comparison of options for use in the Advanced Fuel Cycle Initiative (AFCI) Program. The report describes the AFCI cost basis development process, reference information on AFCI cost modules, a procedure for estimating fuel cycle costs, economic evaluation guidelines, and a discussion on the integration of cost data into economic computer models. This report contains reference cost data for 26 cost modules—24 fuel cycle cost modules and 2 reactor modules. The cost modules were developed in the areas of natural uranium mining and milling, conversion, enrichment, depleted uranium disposition, fuel fabrication, interim spent fuel storage, reprocessing, waste conditioning, spent nuclear fuel (SNF) packaging, long-term monitored retrievable storage, near surface disposal of low-level waste (LLW), geologic repository and other disposal concepts, and transportation processes for nuclear fuel, LLW, SNF, and high-level waste.

  14. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L.

    2002-01-22

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  15. National Report Joint Convention on the Safety of Spent Fuel Management and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on the Safety of Radioactive Waste Management | Department of Energy National Report Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management National Report Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management This is the first National Report prepared under the terms of the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Managementi hereafter

  16. Fuel pin

    DOE Patents [OSTI]

    Christiansen, David W. (Kennewick, WA); Karnesky, Richard A. (Richland, WA); Leggett, Robert D. (Richland, WA); Baker, Ronald B. (Richland, WA)

    1989-01-01

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  17. Fuel pin

    DOE Patents [OSTI]

    Christiansen, D.W.; Karnesky, R.A.; Leggett, R.D.; Baker, R.B.

    1987-11-24

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  18. Waste Hoist

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Disposal Waste Disposal Trucks transport debris from Oak Ridge’s cleanup sites to the onsite CERCLA disposal area, the Environmental Management Waste Management Facility. Trucks transport debris from Oak Ridge's cleanup sites to the onsite CERCLA disposal area, the Environmental Management Waste Management Facility. The low-level radiological and hazardous wastes generated from Oak Ridge's cleanup projects are disposed in the Environmental Management Waste Management Facility (EMWMF). The

  19. Growing attraction of refuse-derived fuels

    SciTech Connect (OSTI)

    Singh, R.

    1981-09-08

    A review of Dr. Andrew Porteous' book, Refuse Derived Fuels is presented. The escalating price of fossil fuel, particularily oil, together with the high cost of handling and transporting refuse makes the idea of refuse-derived fuel production an attractive and economic proposition. Refuse-derived fuel production is discussed and the various manufacturing processes in the UK and the USA are described. The pyrolysis of refuse for the production of gas, oil or heat and the production of methane and ethyl alcohol or other possibilities for refuse conversion.

  20. Federal Register Notice for the Waste Determination

    Broader source: Energy.gov [DOE]

    Section 3116 of the Ronald W. Reagan National Defense Authorization Act for Fiscal Year 2005 (NDAA) provides that certain waste from reprocessing spent nuclear fuel is not considered high-level...

  1. NDAA Section 3116 Waste Determinations with Related Disposal Performance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessments | Department of Energy NDAA Section 3116 Waste Determinations with Related Disposal Performance Assessments NDAA Section 3116 Waste Determinations with Related Disposal Performance Assessments Section 3116 of the Ronald W. Reagan National Defense Authorization Act for Fiscal Year 2005 authorizes the Secretary of Energy, in consultation with the Nuclear Regulatory Commission, to reclassify certain waste from reprocessing spent nuclear fuel from high-level waste to low-level waste

  2. Nuclear waste management. Quarterly progress report, July-September 1980

    SciTech Connect (OSTI)

    Chikalla, T.D.

    1980-11-01

    Research is reported on: high-level waste immobilization, alternative waste forms, TRU waste immobilization and decontamination, krypton solidification, thermal outgassing, /sup 129/I fixation, unsaturated zone transport, well-logging instrumentation, waste management system and safety studies, effectiveness of geologic isolation systems, waste/rock interactions, engineered barriers, backfill material, spent fuel storage (criticality), barrier sealing and liners for U mill tailings, and revegetation of inactive U tailings sites. (DLC)

  3. Alternative Fuels Data Center: Fuel Prices

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Vehicles Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Prices to someone by E-mail Share Alternative Fuels Data Center: Fuel Prices on Facebook Tweet about Alternative Fuels Data Center: Fuel Prices on Twitter Bookmark Alternative Fuels Data Center: Fuel Prices on Google Bookmark Alternative Fuels Data Center: Fuel Prices on Delicious Rank Alternative Fuels Data Center: Fuel Prices on Digg Find More places to share Alternative Fuels Data Center: Fuel

  4. Naval Waste Package Design Report

    SciTech Connect (OSTI)

    M.M. Lewis

    2004-03-15

    A design methodology for the waste packages and ancillary components, viz., the emplacement pallets and drip shields, has been developed to provide designs that satisfy the safety and operational requirements of the Yucca Mountain Project. This methodology is described in the ''Waste Package Design Methodology Report'' Mecham 2004 [DIRS 166168]. To demonstrate the practicability of this design methodology, four waste package design configurations have been selected to illustrate the application of the methodology. These four design configurations are the 21-pressurized water reactor (PWR) Absorber Plate waste package, the 44-boiling water reactor (BWR) waste package, the 5-defense high-level waste (DHLW)/United States (U.S.) Department of Energy (DOE) spent nuclear fuel (SNF) Co-disposal Short waste package, and the Naval Canistered SNF Long waste package. Also included in this demonstration is the emplacement pallet and continuous drip shield. The purpose of this report is to document how that design methodology has been applied to the waste package design configurations intended to accommodate naval canistered SNF. This demonstrates that the design methodology can be applied successfully to this waste package design configuration and support the License Application for construction of the repository.

  5. Industrial Fuel Flexibility Workshop

    SciTech Connect (OSTI)

    none,

    2006-09-01

    On September 28, 2006, in Washington, DC, ITP and Booz Allen Hamilton conducted a fuel flexibility workshop with attendance from various stakeholder groups. Workshop participants included representatives from the petrochemical, refining, food and beverage, steel and metals, pulp and paper, cement and glass manufacturing industries; as well as representatives from industrial boiler manufacturers, technology providers, energy and waste service providers, the federal government and national laboratories, and developers and financiers.

  6. Handbook of industrial and hazardous wastes treatment. 2nd ed.

    SciTech Connect (OSTI)

    Lawrence Wang; Yung-Tse Hung; Howard Lo; Constantine Yapijakis

    2004-06-15

    This expanded Second Edition offers 32 chapters of industry- and waste-specific analyses and treatment methods for industrial and hazardous waste materials - from explosive wastes to landfill leachate to wastes produced by the pharmaceutical and food industries. Key additional chapters cover means of monitoring waste on site, pollution prevention, and site remediation. Including a timely evaluation of the role of biotechnology in contemporary industrial waste management, the Handbook reveals sound approaches and sophisticated technologies for treating: textile, rubber, and timber wastes; dairy, meat, and seafood industry wastes; bakery and soft drink wastes; palm and olive oil wastes; pesticide and livestock wastes; pulp and paper wastes; phosphate wastes; detergent wastes; photographic wastes; refinery and metal plating wastes; and power industry wastes. This final chapter, entitled 'Treatment of power industry wastes' by Lawrence K. Wang, analyses the stream electric power generation industry, where combustion of fossil fuels coal, oil, gas, supplies heat to produce stream, used then to generate mechanical energy in turbines, subsequently converted to electricity. Wastes include waste waters from cooling water systems, ash handling systems, wet-scrubber air pollution control systems, and boiler blowdown. Wastewaters are characterized and waste treatment by physical and chemical systems to remove pollutants is presented. Plant-specific examples are provided.

  7. Efficacy of a solution-based approach for making sodalite waste forms for an oxide reduction salt utilized in the reprocessing of used uranium oxide fuel

    SciTech Connect (OSTI)

    Riley, Brian J.; Pierce, David A.; Frank, Steven M.; Maty, Josef; Burns, Carolyne A.

    2015-04-01

    This paper describes the various approaches attempted to make solution-derived sodalite with a LiCl-Li2O oxide reduction salt used to dissolve used uranium oxide fuel so the uranium can be recovered and recycled. The approaches include modified sol-gel and solutionbased synthesis processes. As-made products were mixed with 5 and 10 mass% of a Na2O-B2O3- SiO2 glass binder and these, along with product without a binder, were heated using either a cold-press-and-sinter method or hot uniaxial pressing. The results demonstrate the limitation of sodalite yield due to the fast intermediate reactions between Na+ and Cl- to form halite in solution and Li2O and SiO2 to form lithium silicates (e.g., Li2SiO3 or Li2Si2O5) in the calcined and sintered pellets. The results show that pellets can be made with high sodalite fractions in the crystalline product (~92 mass%) and low porosities using a solution-based approach and this LiCl-Li2O salt but that the incorporation of Li into the sodalite is low.

  8. Efficacy of a Solution-Based Approach for Making Sodalite Waste Forms for an Oxide Reduction Salt Utilized in the Reprocessing of Used Uranium Oxide Fuel

    SciTech Connect (OSTI)

    Riley, Brian J.; Pierce, David A.; Frank, Steven M.; Matyas, Josef; Burns, Carolyn A.

    2015-04-01

    This paper describes various approaches for making sodalite with a LiCl-Li2O oxide reduction salt used to recover uranium from used oxide fuel. The approaches include sol-gel and solution-based synthesis processes. As-made products were mixed with 5 and 10 mass% of a Na2O-B2O3-SiO2 glass binder and these, along with product without a binder, were heated using either a cold-press-and-sinter method or hot uniaxial pressing. The results demonstrate the limitation of sodalite yield due to the fast intermediate reactions between Na+ and Cl- to form halite in solution and Li2O and SiO2 to form lithium silicates (e.g., Li2SiO3 or Li2Si2O5) in the calcined and sintered pellets. The results show that pellets can be made with high sodalite fractions (~92 mass%) and low porosities using a solution-based approach and this LiCl-Li2O salt.

  9. Efficacy of a solution-based approach for making sodalite waste forms for an oxide reduction salt utilized in the reprocessing of used uranium oxide fuel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Riley, Brian J.; Pierce, David A.; Frank, Steven M.; Matyáš, Josef; Burns, Carolyne A.

    2015-04-01

    This paper describes the various approaches attempted to make solution-derived sodalite with a LiCl-Li2O oxide reduction salt used to dissolve used uranium oxide fuel so the uranium can be recovered and recycled. The approaches include modified sol-gel and solutionbased synthesis processes. As-made products were mixed with 5 and 10 mass% of a Na2O-B2O3- SiO2 glass binder and these, along with product without a binder, were heated using either a cold-press-and-sinter method or hot uniaxial pressing. The results demonstrate the limitation of sodalite yield due to the fast intermediate reactions between Na+ and Cl- to form halite in solution and Li2Omore » and SiO2 to form lithium silicates (e.g., Li2SiO3 or Li2Si2O5) in the calcined and sintered pellets. The results show that pellets can be made with high sodalite fractions in the crystalline product (~92 mass%) and low porosities using a solution-based approach and this LiCl-Li2O salt but that the incorporation of Li into the sodalite is low.« less

  10. Conversion of cellulosic wastes to liquid hydrocarbon fuels: Vol. 6, The modeling and design of a staged indirect liquefaction reactor: Final report

    SciTech Connect (OSTI)

    Kuester, J.L.

    1986-11-01

    A staged reactor was designed to convert biomass to useful fuels. The reactor consists of three stages. The first stage is a concentric combustor/pyrolyzer system where the biomass is gasified in a fluidized bed at high temperatures in the absence of oxygen. The second stage is a cyclonic scrubber where particulates and condensable materials are removed from the gas stream while the gas is cooled. In the final stage the gas undergoes a Fischer-Tropsch synthesis in a fluidized bed or slurry reactor. Mathematical models of the system were developed and used to create computer programs that would predict the behavior of the bed. The models were based on fundamental phenomena and were used to predict key dimensions of the staged reactor system. A transparent plastic, full-scale, cold flow reactor simulator was built using the models' predictions. The simulator was used to refine the models and determine the operating characteristics of the reactor. The design was determined to be workable and potentially useful. The reactor was, however, difficult to operate and would require extensive automated control systems.

  11. Department of Energy Programmatic Spent Nuclear Fuel Management and Idaho National Engineering Laboratory Environmental Restoration and Waste Management Programs Draft Environmental Impact Statement; Volume 1, Appendix F, Nevada Test Site and Oak Ridge Reservation Spent Nuclear Fuel Management Programs

    SciTech Connect (OSTI)

    1994-06-01

    This volume addresses the interim storage of spent nuclear fuel (SNF) at two US Department of Energy sites, the Nevada Test Site (NTS) and the Oak Ridge Reservation (ORR). These sites are being considered to provide a reasonable range of alternative settings at which future SNF management activities could be conducted. These locations are not currently involved in management of large quantities of SNF; NTS has none, and ORR has only small quantities. But NTS and ORR do offer experience and infrastructure for the handling, processing and storage of radioactive materials, and they do exemplify a broad spectrum of environmental parameters. This broad spectrum of environmental parameters will provide, a perspective on whether and how such location attributes may relate to potential environmental impacts. Consideration of these two sites will permit a programmatic decision to be based upon an assessment of the feasible options without bias, to the current storage sites. This volume is divided into four parts. Part One is the volume introduction. Part Two contains chapters one through five for the NTS, as well as references contained in chapter six. Part Three contains chapters one through five for the ORR, as well as references contained in chapter six. Part Four is summary information including the list of preparers, organizations contacted, acronyms, and abbreviations for both the NTS and the ORR. A Table of Contents, List of Figures, and List of Tables are included in parts Two, Three, and Four. This approach permitted the inclusion of both sites in one volume while maintaining consistent chapter numbering.

  12. Maritime Hydrogen Fuel Cell Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cell Project - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  13. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    2008-12-01

    General Electric Global Research will define, develop, and test new fuel nozzle technology concepts for gas turbine operation on a wide spectrum of opportunity fuels and/or fuel blends. This will enable gas turbine operation on ultra-low Btu fuel streams such as very weak natural gas, highly-diluted industrial process gases, or gasified waste streams that are out of the capability range of current turbine systems.

  14. Tank Waste and Waste Processing | Department of Energy

    Office of Environmental Management (EM)

    Tank Waste and Waste Processing Tank Waste and Waste Processing Tank Waste and Waste Processing The Defense Waste Processing Facility set a record by producing 267 canisters filled ...

  15. Missouri Renewable Fuel Standard Brochure

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    The Missouri Renewable Fuel Standard requires ethanol in most gasoline beginning January 1, 2008. ARE YOU READY? TEN THINGS MISSOURI TANK OWNERS AND OPERATORS NEED TO KNOW ABOUT ETHANOL 1. Ethanol is a type of alcohol made usually from corn in Missouri and other states. 2. E10 is a blend of 10% ethanol and 90% unleaded gasoline. E85 is a blend of 75% to 85% fuel ethanol and 25% to 15% unleaded gasoline. Blends between E10 and E85 are not allowed to be sold at retail. 3. Any vehicle or small

  16. Refuse derived fuel delivery system and distribution conveyors

    SciTech Connect (OSTI)

    Kaminski, D.J.; Frank, E.A.; Grinsteiner, C.S.

    1987-08-18

    This patent describes an apparatus for supplying comminuted combustible solid waste material from a refuse material supply to a combustion apparatus for use as fuel and wherein the combustion apparatus includes at least two fuel charging means each having a hopper for receiving comminuted combustible solid waste material, and the hoppers being positioned in side-by-side relation.

  17. Waste heat: Utilization and management

    SciTech Connect (OSTI)

    Sengupta, S.; Lee, S.S.

    1983-01-01

    This book is a presentation on waste heat management and utilization. Topics covered include cogeneration, recovery technology, low grade heat recovery, heat dispersion models, and ecological effects. The book focuses on the significant fraction of fuel energy that is rejected and expelled into the environment either as industrial waste or as a byproduct of installation/equipment operation. The feasibility of retrieving this heat and energy is covered, including technical aspects and potential applications. Illustrations demonstrate that recovery methods have become economical due to recent refinements. The book includes theory and practice concerning waste heat management and utilization.

  18. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect (OSTI)

    Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

    2008-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber o-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile o-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fuIly synthetic jet fuel in the place of petroleum-derived fueL

  19. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect (OSTI)

    Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

    2009-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber a-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile a-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fully synthetic jet fuel in the place of petroleum-derived fuel.

  20. Combined Heat and Power Market Potential for Opportunity Fuels

    SciTech Connect (OSTI)

    Jones, David; Lemar, Paul

    2015-12-01

    This report estimates the potential for opportunity fuel combined heat and power (CHP) applications in the United States, and provides estimates for the technical and economic market potential compared to those included in an earlier report. An opportunity fuel is any type of fuel that is not widely used when compared to traditional fossil fuels. Opportunity fuels primarily consist of biomass fuels, industrial waste products and fossil fuel derivatives. These fuels have the potential to be an economically viable source of power generation in various CHP applications.

  1. Chemical Kinetic Modeling of Advanced Transportation Fuels

    SciTech Connect (OSTI)

    PItz, W J; Westbrook, C K; Herbinet, O

    2009-01-20

    Development of detailed chemical kinetic models for advanced petroleum-based and nonpetroleum based fuels is a difficult challenge because of the hundreds to thousands of different components in these fuels and because some of these fuels contain components that have not been considered in the past. It is important to develop detailed chemical kinetic models for these fuels since the models can be put into engine simulation codes used for optimizing engine design for maximum efficiency and minimal pollutant emissions. For example, these chemistry-enabled engine codes can be used to optimize combustion chamber shape and fuel injection timing. They also allow insight into how the composition of advanced petroleum-based and non-petroleum based fuels affect engine performance characteristics. Additionally, chemical kinetic models can be used separately to interpret important in-cylinder experimental data and gain insight into advanced engine combustion processes such as HCCI and lean burn engines. The objectives are: (1) Develop detailed chemical kinetic reaction models for components of advanced petroleum-based and non-petroleum based fuels. These fuels models include components from vegetable-oil-derived biodiesel, oil-sand derived fuel, alcohol fuels and other advanced bio-based and alternative fuels. (2) Develop detailed chemical kinetic reaction models for mixtures of non-petroleum and petroleum-based components to represent real fuels and lead to efficient reduced combustion models needed for engine modeling codes. (3) Characterize the role of fuel composition on efficiency and pollutant emissions from practical automotive engines.

  2. Alternative Fuels Data Center: Emerging Fuels

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Emerging Fuels Printable Version Share this resource Send a link to Alternative Fuels Data Center: Emerging Fuels to someone by E-mail Share Alternative Fuels Data Center: Emerging Fuels on Facebook Tweet about Alternative Fuels Data Center: Emerging Fuels on Twitter Bookmark Alternative Fuels Data Center: Emerging Fuels on Google Bookmark Alternative Fuels Data Center: Emerging Fuels on Delicious Rank Alternative Fuels Data Center: Emerging Fuels on Digg Find More places to share Alternative

  3. Alternative Fuels Data Center: Biodiesel Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Basics on AddThis.com... More in

  4. Alternative Fuels Data Center: Electricity Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Electricity Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Electricity Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Electricity Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Google Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Delicious Rank Alternative Fuels Data Center: Electricity Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Electricity Fuel Basics on

  5. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this

  6. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fueling Stations on

  7. Alternative Fuels Data Center: Hydrogen Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Google Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Delicious Rank Alternative Fuels Data Center: Hydrogen Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fueling Stations

  8. Alternative Fuels Data Center: Propane Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Propane Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Propane Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Google Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Delicious Rank Alternative Fuels Data Center: Propane Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Propane Fueling Stations on

  9. Model documentation: Renewable Fuels Module of the National Energy Modeling System

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    This report documents the objectives, analytical approach, and design of the National Energy Modeling System (NEMS) Renewable Fuels Module (RFM) as it related to the production of the 1994 Annual Energy Outlook (AEO94) forecasts. The report catalogues and describes modeling assumptions, computational methodologies, data inputs, and parameter estimation techniques. A number of offline analyses used in lieu of RFM modeling components are also described. This documentation report serves two purposes. First, it is a reference document for model analysts, model users, and the public interested in the construction and application of the RFM. Second, it meets the legal requirement of the Energy Information Administration (EIA) to provide adequate documentation in support of its models. The RFM consists of six analytical submodules that represent each of the major renewable energy resources -- wood, municipal solid waste (MSW), solar energy, wind energy, geothermal energy, and alcohol fuels. Of these six, four are documented in the following chapters: municipal solid waste, wind, solar and biofuels. Geothermal and wood are not currently working components of NEMS. The purpose of the RFM is to define the technological and cost characteristics of renewable energy technologies, and to pass these characteristics to other NEMS modules for the determination of mid-term forecasted renewable energy demand.

  10. Waste Heat Recapture from Supermarket Refrigeration Systems

    SciTech Connect (OSTI)

    Fricke, Brian A

    2011-11-01

    The objective of this project was to determine the potential energy savings associated with improved utilization of waste heat from supermarket refrigeration systems. Existing and advanced strategies for waste heat recovery in supermarkets were analyzed, including options from advanced sources such as combined heat and power (CHP), micro-turbines and fuel cells.

  11. Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications

    SciTech Connect (OSTI)

    Eteman, Shahrokh

    2013-06-30

    Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL®) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL® injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

  12. Syngas Mixed Alcohol Cost Validation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 2013 DOE Bioenergy Technologies Office: Project Peer Review Syngas Mixed Alcohol Cost Validation Abhijit Dutta, NREL This presentation does not contain any proprietary, ...

  13. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  14. Radioactive waste material melter apparatus

    DOE Patents [OSTI]

    Newman, Darrell F.; Ross, Wayne A.

    1990-01-01

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another.

  15. Radioactive waste material melter apparatus

    DOE Patents [OSTI]

    Newman, D.F.; Ross, W.A.

    1990-04-24

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another. 8 figs.

  16. Transportation Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels DOE would invest $52 million to fund a major fleet transformation at Idaho National Laboratory, along with the installation of nine fuel management systems, purchase of additional flex fuel cars and one E85 ethanol fueling station. Transportation projects, such as the acquisition of highly efficient and alternative-fuel vehicles, are not authorized by ESPC legislation. DOE has twice proportion of medium vehicles and three times as many heavy vehicles as compared to the Federal agency

  17. WASTES-II: Waste System Transportation and Economic Simulation--Release 24: User's guide

    SciTech Connect (OSTI)

    Ouderkirk, S.J.

    1988-12-01

    WASTES models each reactor pool and an at-reactor, out-of-pool (ex-pool) storage facility for each reactor site. Spent fuel transfers between pools can be simulated under various constraints controlled by user input. In addition to simulating each pool and ex-pool facility, WASTES can accommodate up to ten other storage facilities of four different types: federal interim storage (FIS), monitored retrievable storage (MRS), auxiliary plants, and repositories. Considerable flexibility is allowed for the user to specify system configuration and priorities for fuel receipts. In addition, the WASTES computer code simulates very detailed (assembly-specific) movements of spent fuel throughout the waste management system. Spent fuel characteristics that are tracked by WASTES for each movement are: discharge year and month, number of assemblies, weight of uranium (MTU), exposure, original enrichment, and heat generation rate (calculated from the preceding characteristics). Data for the WASTES model is based upon the DOE reactor-specific spent fuel data base, which is developed and maintained by the Energy Information Administration (EIA). In addition to the spent fuel characteristics, this data includes reactor location, type, transportation access, and historical and projected discharge data on the number of fuel assemblies. 8 refs., 3 figs., 4 tabs.

  18. Physics Features of TRU-Fueled VHTRs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lewis, Tom G.; Tsvetkov, Pavel V.

    2009-01-01

    The current waste management strategy for spent nuclear fuel (SNF) mandated by the US Congress is the disposal of high-level waste (HLW) in a geological repository at Yucca Mountain. Ongoing efforts on closed-fuel cycle options and difficulties in opening and safeguarding such a repository have led to investigations of alternative waste management strategies. One potential strategy for the US fuel cycle would be to make use of fuel loadings containing high concentrations of transuranic (TRU) nuclides in the next-generation reactors. The use of such fuels would not only increase fuel supply but could also potentially facilitate prolonged operation modes (viamore » fertile additives) on a single fuel loading. The idea is to approach autonomous operation on a single fuel loading that would allow marketing power units as nuclear batteries for worldwide deployment. Studies have already shown that high-temperature gas-cooled reactors (HTGRs) and their Generation IV (GEN IV) extensions, very-high-temperature reactors (VHTRs), have encouraging performance characteristics. This paper is focused on possible physics features of TRU-fueled VHTRs. One of the objectives of a 3-year U.S. DOE NERI project was to show that TRU-fueled VHTRs have the possibility of prolonged operation on a single fuel loading. A 3D temperature distribution was developed based on conceivable operation conditions of the 600 MWth VHTR design. Results of extensive criticality and depletion calculations with varying fuel loadings showed that VHTRs are capable for autonomous operation and HLW waste reduction when loaded with TRU fuel.« less

  19. Fuel-tolerance tests with the Ford PROCO engine

    SciTech Connect (OSTI)

    Choma, M.A.; Havstad, P.H.; Simko, A.O.; Stockhausen, W.F.

    1981-01-01

    A variety of fuel tolerance tests were conducted utilizing Ford's PROCO engine, a direct fuel injection stratified charge engine developed for light duty vehicles. These engine tests were run on the dynamometer and in vehicles. Data indicate an 89 RON octane requirement, relatively low sensitivity to volatility characteristics and good fuel economy, emission control and operability on a certain range of petroleum fuel and alcohol mixes including 100% methanol. Fuels such as JP-4 and Diesel fuel are not at present suitable for this engine. There were no engine modifications tested that might improve the match between the engine and a particular fuel. The 100% methanol test was conducted with a modified fuel injection pump. Durability aspects including compatibility of various fuels with the materials in the fuel system were not addressed.

  20. Recycling of nuclear spent fuel with AIROX processing

    SciTech Connect (OSTI)

    Majumdar, D.; Jahshan, S.N.; Allison, C.M.; Kuan, P.; Thomas, T.R.

    1992-12-01

    This report examines the concept of recycling light water reactor (LWR) fuel through use of a dry-processing technique known as the AIROX (Atomics International Reduction Oxidation) process. In this concept, the volatiles and the cladding from spent LWR fuel are separated from the fuel by the AIROX process. The fuel is then reenriched and made into new fuel pins with new cladding. The feasibility of the concept is studied from a technical and high level waste minimization perspective.

  1. fuel cells | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    fuel cells

  2. Commercial waste treatment program annual progress report for FY 1983

    SciTech Connect (OSTI)

    McElroy, J.L.; Burkholder, H.C. (comps.)

    1984-02-01

    This annual report describes progress during FY 1983 relating to technologies under development by the Commercial Waste Treatment Program, including: development of glass waste form and vitrification equipment for high-level wastes (HLW); waste form development and process selection for transuranic (TRU) wastes; pilot-scale operation of a radioactive liquid-fed ceramic melter (LFCM) system for verifying the reliability of the reference HLW treatment proces technology; evaluation of treatment requirements for spent fuel as a waste form; second-generation waste form development for HLW; and vitrification process control and product quality assurance technologies.

  3. Transuranic waste disposal in the United State

    SciTech Connect (OSTI)

    Thompson, J.D.

    1986-01-01

    The US is unique in having created a special class of radioactive waste disposal based on the concentration of transuranic (TRU) elements in the waste. Since 1970, the US has been placing newly generated TRU waste in retrievable storage. It is intended that these wastes will be placed in a permanent deep geologic repository, the Waste Isolation Pilot Plant (WIPP). The WIPP opening for a demonstration emplacement period is set for October 1988. Transuranic wastes derive from some of the manufacturing and research activities carried out by the US Department of Energy (DOE). The bulk of this waste is generated in plutonium parts fabrication activities. A variety of plutonium-contaminated materials ranging from glove boxes, high-efficiency particulate air filters, and machine tools, to chemical sludges derived from plutonium recovery streams are stored as TRU wastes. Other processes that generate TRU waste are plutonium production operations, preparation for and cleanup from fuel reprocessing, manufacturing of plutonium heat sources, and nuclear fuel cycle research activities. Extensive procedures will be used to examine and prepare waste before it is placed in the WIPP for disposal. After the WIPP opens, certified waste will be transported to it and emplaced in the repository.

  4. Alternative Waste Forms for Electro-Chemical Salt Waste

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Sundaram, S. K.; Riley, Brian J.; Matyas, Josef; Arreguin, Shelly A.; Vienna, John D.

    2009-10-28

    This study was undertaken to examine alternate crystalline (ceramic/mineral) and glass waste forms for immobilizing spent salt from the Advanced Fuel Cycle Initiative (AFCI) electrochemical separations process. The AFCI is a program sponsored by U.S. Department of Energy (DOE) to develop and demonstrate a process for recycling spent nuclear fuel (SNF). The electrochemical process is a molten salt process for the reprocessing of spent nuclear fuel in an electrorefiner and generates spent salt that is contaminated with alkali, alkaline earths, and lanthanide fission products (FP) that must either be cleaned of fission products or eventually replaced with new salt to maintain separations efficiency. Currently, these spent salts are mixed with zeolite to form sodalite in a glass-bonded waste form. The focus of this study was to investigate alternate waste forms to immobilize spent salt. On a mole basis, the spent salt is dominated by alkali and Cl with minor amounts of alkaline earth and lanthanides. In the study reported here, we made an effort to explore glass systems that are more compatible with Cl and have not been previously considered for use as waste forms. In addition, alternate methods were explored with the hope of finding a way to produce a sodalite that is more accepting of as many FP present in the spent salt as possible. This study was done to investigate two different options: (1) alternate glass families that incorporate increased concentrations of Cl; and (2) alternate methods to produce a mineral waste form.

  5. Fuel Cell 101 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    101 Fuel Cell 101 Presented at the DOE-DOD Shipboard APU Workshop on March 29, 2011. PDF icon apu2011_2_hoffman.pdf More Documents & Publications System Design - Lessons Learned, Generic Concepts, Characteristics & Impacts Waste-to-Energy Projects at Army Installations Comparison of Fuel Cell Technologies: Fact Sheet

  6. Flowsheets and source terms for radioactive waste projections

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1985-03-01

    Flowsheets and source terms used to generate radioactive waste projections in the Integrated Data Base (IDB) Program are given. Volumes of each waste type generated per unit product throughput have been determined for the following facilities: uranium mining, UF/sub 6/ conversion, uranium enrichment, fuel fabrication, boiling-water reactors (BWRs), pressurized-water reactors (PWRs), and fuel reprocessing. Source terms for DOE/defense wastes have been developed. Expected wastes from typical decommissioning operations for each facility type have been determined. All wastes are also characterized by isotopic composition at time of generation and by general chemical composition. 70 references, 21 figures, 53 tables.

  7. Proceedings of refuse-derived fuel (RDF)

    SciTech Connect (OSTI)

    Saltiel, C. )

    1991-01-01

    This book contains proceedings of Refuse-Derived Fuel (RDF)-Quality. Standards and Processing. Topics covered include: An Overview of RDF Processing Systems: Current Status, Design Features, and Future Trends. The Impact of Recycling and Pre-Combustion Processing of Municipal Solid Waste on Fuel Properties and Steam Combustion. The Changing Role of Standards in the Marketing of RDF. Refuse Derived Fuel Quality Requirements for Firing in Utility, Industrial or Dedicated Boilers. Refuse-Derived Fuel Moisture Effects on Boiler Performance and Operability. Refuse Derived Fuels: Technology, Processing, Quality and Combustion Experiences.

  8. Alternative Fuels Data Center: Flexible Fuel Vehicles

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Flexible Fuel Vehicles to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicles on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicles on Twitter Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Google Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Delicious Rank Alternative Fuels Data Center: Flexible Fuel Vehicles on Digg

  9. Methanol with dimethyl ether ignition promotor as fuel for compression ignition engines

    SciTech Connect (OSTI)

    Brook, D.L.; Cipolat, D.; Rallis, C.J.

    1984-08-01

    Reduction of the world dependence upon crude oil necessitates the use of long term alternative fuels for internal combustion engines. Alcohols appear to offer a solution as in the short term they can be manufactured from natural gas and coal, while ultimately they may be produced from agricultural products. A fair measure of success has been achieved in using alcohols in spark ignition engines. However the more widely used compression ignition engines cannot utilize unmodified pure alcohols. The current techniques for using alcohol fuels in compression ignition engines all have a number of shortcomings. This paper describes a novel technique where an ignition promotor, dimethyl ether (DME), is used to increase the cetane rating of methanol. The systems particular advantage is that the DME can be catalyzed from the methanol base fuel, in situ. This fuel system matches the performance characteristics of diesel oil fuel.

  10. Long-term management of high-level radioactive waste (HLW) and spent

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    nuclear fuel (SNF) | Department of Energy Long-term management of high-level radioactive waste (HLW) and spent nuclear fuel (SNF) Long-term management of high-level radioactive waste (HLW) and spent nuclear fuel (SNF) GC-52 provides legal advice to DOE regarding the long-term management of high-level radioactive waste (HLW) and spent nuclear fuel (SNF). SNF is nuclear fuel that has been used as fuel in a reactor to generate nuclear energy but that has been removed from the reactor as no

  11. Nuclear-fuel-cycle risk assessment: descriptions of representative non-reactor facilities, Sections 15-19

    SciTech Connect (OSTI)

    Schneider, K.J.

    1982-09-01

    Information is presented under the following section headings: fuel reprocessing; spent fuel and high-level and transuranic waste storage; spent fuel and high-level and transuranic waste disposal; low-level and intermediate-level waste disposal; and, transportation of radioactive materials in the nuclear fuel cycle. In each of the first three sections a description is given on the mainline process, effluent processing and waste management systems, plant layout, and alternative process schemes. Safety information and a summary are also included in each. The section on transport of radioactive materials includes information on the transportation of uranium ore, uranium ore concentrate, UF/sub 6/, PuO/sub 2/ powder, unirradiated uranium and mixed-oxide fuel assemblies, spent fuel, solidified high-level waste, contact-handled transuranic waste, remote-handled transuranic waste, and low and intermediate level nontransuranic waste. A glossary is included. (JGB)

  12. Science, society, and America's nuclear waste: Unit 3, The Nuclear Waste Policy Act

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    This is the 3rd unit, (The Nuclear Waste Policy Act) a four-unit secondary curriculum. It is intended to provide information about scientific and societal issues related to the management of spent nuclear fuel from generation of electricity at nuclear powerplants and high-level radioactive waste from US national defense activities. The curriculum, supporting classroom activities, and teaching materials present a brief discussion of energy and electricity generation, including that produced at nuclear powerplants; information on sources, amounts, location, and characteristics of spent nuclear fuel and high-level radioactive waste; sources, types and effects of radiation; US policy for managing and disposing of spent nuclear fuel and high-level radioactive waste and what other countries are doing; and the components of the nuclear waste management system.

  13. Science, society, and America`s nuclear waste: Unit 3, The Nuclear Waste Policy Act

    SciTech Connect (OSTI)

    Not Available

    1992-11-01

    This is the 3rd unit, (The Nuclear Waste Policy Act) a four-unit secondary curriculum. It is intended to provide information about scientific and societal issues related to the management of spent nuclear fuel from generation of electricity at nuclear powerplants and high-level radioactive waste from US national defense activities. The curriculum, supporting classroom activities, and teaching materials present a brief discussion of energy and electricity generation, including that produced at nuclear powerplants; information on sources, amounts, location, and characteristics of spent nuclear fuel and high-level radioactive waste; sources, types and effects of radiation; US policy for managing and disposing of spent nuclear fuel and high-level radioactive waste and what other countries are doing; and the components of the nuclear waste management system.

  14. Science, society, and America's nuclear waste: Unit 3, The Nuclear Waste Policy Act

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    This teachers guide is unit 3, the nuclear waste policy act, in a four-unit secondary curriculum. It is intended to provide information about scientific and societal issues related to the management of spent nuclear fuel from generation of electricity at nuclear powerplants and high-level radioactive waste from US national defense activities. The curriculum, supporting classroom activities, and teaching materials present a brief discussion of energy and electricity generation, including that produced at nuclear power plants; information on sources, amounts, location, and characteristics of spent nuclear fuel and high-level radioactive waste; sources, types and effects of radiation; US policy for managing and disposing of spent nuclear fuel and high-level radioactive waste and what other countries are doing; and the components of the nuclear waste management system.

  15. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell...

  16. Generic Repository Concepts and Thermal Analysis for Advanced Fuel Cycles -

    Office of Scientific and Technical Information (OSTI)

    12477 (Conference) | SciTech Connect Generic Repository Concepts and Thermal Analysis for Advanced Fuel Cycles - 12477 Citation Details In-Document Search Title: Generic Repository Concepts and Thermal Analysis for Advanced Fuel Cycles - 12477 A geologic disposal concept for spent nuclear fuel (SNF) or high-level waste (HLW) consists of three components: waste inventory, geologic setting, and concept of operations. A set of reference geologic disposal concepts has been developed by the U.S.

  17. Downregulation of Cinnamyl Alcohol Dehydrogenase (CAD) Leads...

    Office of Scientific and Technical Information (OSTI)

    Alcohol Dehydrogenase (CAD) Leads to Improved Saccharification Efficiency in Switchgrass Citation Details In-Document Search Title: Downregulation of Cinnamyl Alcohol Dehydrogenase ...

  18. Electrochemical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    K. M. Goff; J. C. Wass; G. M. Teske

    2011-08-01

    As part of the Department of Energys Fuel Cycle Research and Development Program an electrochemical technology employing molten salts is being developed for recycle of metallic fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. This technology has been deployed for treatment of used fuel from the Experimental Breeder Reactor II (EBR-II) in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory. This process is based on dry (non-aqueous) technologies that have been developed and demonstrated since the 1960s. These technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including preparation of associated high-level waste forms.

  19. VISION: Verifiable Fuel Cycle Simulation Model

    SciTech Connect (OSTI)

    Jacob J. Jacobson; Abdellatif M. Yacout; Gretchen E. Matthern; Steven J. Piet; David E. Shropshire

    2009-04-01

    The nuclear fuel cycle is a very complex system that includes considerable dynamic complexity as well as detail complexity. In the nuclear power realm, there are experts and considerable research and development in nuclear fuel development, separations technology, reactor physics and waste management. What is lacking is an overall understanding of the entire nuclear fuel cycle and how the deployment of new fuel cycle technologies affects the overall performance of the fuel cycle. The Advanced Fuel Cycle Initiatives systems analysis group is developing a dynamic simulation model, VISION, to capture the relationships, timing and delays in and among the fuel cycle components to help develop an understanding of how the overall fuel cycle works and can transition as technologies are changed. This paper is an overview of the philosophy and development strategy behind VISION. The paper includes some descriptions of the model and some examples of how to use VISION.

  20. Straight Vegetable Oil as a Diesel Fuel?

    SciTech Connect (OSTI)

    2014-01-01

    Biodiesel, a renewable fuel produced from animal fats or vegetable oils, is popular among many vehicle owners and fleet managers seeking to reduce emissions and support U.S. energy security. Questions sometimes arise about the viability of fueling vehicles with straight vegetable oil (SVO), or waste oils from cooking and other processes, without intermediate processing. But SVO and waste oils differ from biodiesel (and conventional diesel) in some important ways and are generally not considered acceptable vehicle fuels for large-scale or long-term use.

  1. Electro-autotrophic synthesis of higher alcohols

    DOE Patents [OSTI]

    Liao, James C.; Cho, Kwang Myung

    2015-10-06

    The disclosure provides a process that converts CO.sub.2 to higher alcohols (e.g. isobutanol) using electricity as the energy source. This process stores electricity (e.g. from solar energy, nuclear energy, and the like) in liquid fuels that can be used as high octane number gasoline substitutes. Instead of deriving reducing power from photosynthesis, this process derives reducing power from electrically generated mediators, either H.sub.2 or formate. H.sub.2 can be derived from electrolysis of water. Formate can be generated by electrochemical reduction of CO.sub.2. After delivering the reducing power in the cell, formate becomes CO.sub.2 and recycles back. Therefore, the biological CO.sub.2 fixation process can occur in the dark.

  2. Characteristics of potential repository wastes. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1992-07-01

    The LWR spent fuels discussed in Volume 1 of this report comprise about 99% of all domestic non-reprocessed spent fuel. In this report we discuss other types of spent fuels which, although small in relative quantity, consist of a number of diverse types, sizes, and compositions. Many of these fuels are candidates for repository disposal. Some non-LWR spent fuels are currently reprocessed or are scheduled for reprocessing in DOE facilities at the Savannah River Site, Hanford Site, and the Idaho National Engineering Laboratory. It appears likely that the reprocessing of fuels that have been reprocessed in the past will continue and that the resulting high-level wastes will become part of defense HLW. However, it is not entirely clear in some cases whether a given fuel will be reprocessed, especially in cases where pretreatment may be needed before reprocessing, or where the enrichment is not high enough to make reprocessing attractive. Some fuels may be canistered, while others may require special means of disposal. The major categories covered in this chapter include HTGR spent fuel from the Fort St. Vrain and Peach Bottom-1 reactors, research and test reactor fuels, and miscellaneous fuels, and wastes generated from the decommissioning of facilities.

  3. The Nuclear Waste Policy Act, as amended with appropriations acts appended

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    The Nuclear Waste Policy Act of 1982 provides for the development of repositories for the disposal of high-level radioactive waste and spent nuclear fuel, to establish a program of research, development and demonstration regarding the disposal of high-level radioactive waste and spent nuclear fuel. Titles 1 and 2 cover these subjects. Also included in this Act are: Title 3: Other provisions relating to radioactive waste; Title 4: Nuclear waste negotiation; Title 5: Nuclear waste technical review board; and Title 6: High-level radioactive waste. An appendix contains excerpts from appropriations acts from fiscal year 1984--1994.

  4. Synthetic Fuel

    ScienceCinema (OSTI)

    Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

    2010-01-08

    Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

  5. President Reagan Calls for a National Spent Fuel Storage Facility |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration Reagan Calls for a National Spent Fuel Storage Facility President Reagan Calls for a National Spent Fuel Storage Facility Washington, DC The Reagan Administration announces a nuclear energy policy that anticipates the establishment of a facility for the storage of high-level radioactive waste and lifts the ban on commercial reprocessing of nuclear fuel

  6. Fuel Economy

    Broader source: Energy.gov [DOE]

    The Energy Department is investing in groundbreaking research that will make cars weigh less, drive further and consume less fuel.

  7. Fuels Technologies

    Energy Savers [EERE]

    Fuels Technologies Program Mission To develop more energy efficient and environmentally friendly highway transportation technologies that enable America to use less petroleum. --EERE Strategic Plan, October 2002-- Kevin Stork, Team Leader Fuel Technologies & Technology Deployment Vehicle Technologies Program Energy Efficiency and Renewable Energy U.S. Department of Energy DEER 2008 August 6, 2008 Presentation Outline n Fuel Technologies Research Goals Fuels as enablers for advanced engine

  8. Salt Waste Disposal at the Savannah River Site | Department of Energy

    Energy Savers [EERE]

    Salt Waste Disposal at the Savannah River Site Salt Waste Disposal at the Savannah River Site Section 3116 of the Ronald W. Reagan National Defense Authorization Act for Fiscal Year 2005 authorizes the Secretary of Energy, in consultation with the Nuclear Regulatory Commission, to reclassify certain waste from reprocessing spent nuclear fuel from high-level waste to low-level waste if it meets the criteria set forth in Section 3116. Currently, DOE SRS has prepared one final (salt waste) and is

  9. The Waste Isolation Pilot Plant Hazardous Waste Facility Permit...

    Office of Environmental Management (EM)

    The Waste Isolation Pilot Plant Hazardous Waste Facility Permit, Waste Analysis Plan The Waste Isolation Pilot Plant Hazardous Waste Facility Permit, Waste Analysis Plan This ...

  10. ORNL nuclear waste programs annual progress report for period ending September 30, 1982

    SciTech Connect (OSTI)

    Not Available

    1983-05-01

    Research progress is reported in 20 activities under the headings: spent fuels, defense waste management, commercial waste management, remedial action, and conventional reactors. Separate entries were prepared for each activity.

  11. Waste-to-Energy Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste-to-Energy Workshop Waste-to-Energy Workshop The Bioenergy Technologies Office (BETO) at the Department of Energy aims to identify and address key technical barriers to the commercial deployment of liquid transportation fuels from waste feedstocks. As part of this effort, BETO held a Waste-to-Energy Workshop on November 5, 2014. The participants discussed anaerobic digestion, hydrothermal liquefaction, and other processes that make productive use of wastewater residuals, biosolids,

  12. Read More About Nuclear Waste Management | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consent-Based Siting » Read More About Nuclear Waste Management Read More About Nuclear Waste Management Background Information Integrated Waste Management and Consent-Based Siting Booklet Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste Blue Ribbon Commission on America's Nuclear Future Report to the Secretary of Energy Secretary Moniz's Remarks on "A Look Back on the Blue Ribbon Commission on America's Nuclear Future" FACT SHEET: The

  13. Development of Thermoelectric Technology for Automotive Waste Heat Recovery

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy Overview and status of project to develop thermoelectric generator for automotive waste heat recovery and achieve at least 10% fuel economy improvement. PDF icon deer08_gundlach.pdf More Documents & Publications Opportunities and Challenges of Thermoelectrlic Waste Heat Recovery in the Automotive Industry Develop Thermoelectric Technology for Automotive Waste Heat Recovery Thermoelectric Technology for Automotive Waste Heat Recovery

  14. Nuclear waste management. Quarterly progress report, April-June 1981

    SciTech Connect (OSTI)

    Chikalla, T.D.; Powell, J.A.

    1981-09-01

    Reports and summaries are presented for the following: high-level waste process development; alternative waste forms; TMI zeolite vitrification demonstration program; nuclear waste materials characterization center; TRU waste immobilization; TRU waste decontamination; krypton implantation; thermal outgassing; iodine-129 fixation; NWVP off-gas analysis; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; verification instrument development; mobility of organic complexes of radionuclides in soils; handbook of methods to decrease the generation of low-level waste; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology program; high-level waste form preparation; development of backfill materials; development of structural engineered barriers; disposal charge analysis; and analysis of spent fuel policy implementation.

  15. Bioelectrochemical Integration of Waste Heat Recovery, Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioelectrochemical Integration of Waste Heat Recovery, Waste-to-Energy Conversion, and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes ...

  16. Optimization of Waste Disposal - 13338

    SciTech Connect (OSTI)

    Shephard, E.; Walter, N.; Downey, H.; Collopy, P.; Conant, J.

    2013-07-01

    From 2009 through 2011, remediation of areas of a former fuel cycle facility used for government contract work was conducted. Remediation efforts were focused on building demolition, underground pipeline removal, contaminated soil removal and removal of contaminated sediments from portions of an on-site stream. Prior to conducting the remediation field effort, planning and preparation for remediation (including strategic planning for waste characterization and disposal) was conducted during the design phase. During the remediation field effort, waste characterization and disposal practices were continuously reviewed and refined to optimize waste disposal practices. This paper discusses strategic planning for waste characterization and disposal that was employed in the design phase, and continuously reviewed and refined to optimize efficiency. (authors)

  17. Fuel-cycle facilities: preliminary safety and environmental information document. Volume VII

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Information is presented concerning the mining and milling of uranium and thorium; uranium hexafluoride conversion; enrichment; fuel fabrication; reprocessing; storage options; waste disposal options; transportation; heavy-water-production facilities; and international fuel service centers.

  18. Fact #776: April 22, 2013 Fuel Savings from Attempts to Alleviate Traffic Congestion

    Broader source: Energy.gov [DOE]

    Despite the news that traffic congestion wasted nearly 2.9 billion gallons of fuel in 2011, fuel savings were achieved due to efforts to combat congestion. According to the Texas Transportation...

  19. Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power

    Broader source: Energy.gov [DOE]

    With their clean and quiet operation, fuel cells represent a promising means of implementing small-scale distributed power generation in the future. Waste heat from the fuel cell can be harnessed...

  20. oint Convention on the Safety of Spent Fuel Management and on...

    National Nuclear Security Administration (NNSA)

    oint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management | National Nuclear Security Administration Facebook Twitter Youtube Flickr...