National Library of Energy BETA

Sample records for walled hollow glass

  1. POROUS WALL, HOLLOW GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Sexton, W.

    2012-06-30

    Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to 'normal glasses of a 1 to 2 order of magnitude, which can result in unique properties in areas such as hydrogen storage, gas transport, gas separations and purifications, sensors, global warming applications, new drug delivery systems and so on. One of the most interesting porous glass products that SRNL has developed and patented is Porous Wall, Hollow Glass Microspheres (PW-HGMs) that are being studied for many different applications. The European Patent Office (EPO) just recently notified SRS that the continuation-in-part patent application for the PW-HGMs has been accepted. The original patent, which was granted by the EPO on June 2, 2010, was validated in France, Germany and the United Kingdom. The microspheres produced are generally in the range of 2 to 100 microns, with a 1 to 2 micron wall. What makes the SRNL microspheres unique from all others is that the team in Figure 1 has found a way to induce and control porosity through the thin walls on a scale of 100 to 3000 {angstrom}. This is what makes the SRNL HW-HGMs one-of-a-kind, and is responsible for many of their unique properties and potential for various applications, including those in tritium storage, gas separations, H-storage for vehicles, and even a variety of new medical applications in the areas of drug delivery and MRI contrast agents. SRNL Hollow Glass Microspheres, and subsequent, Porous Wall, Hollow Glass Microspheres are fabricated using a flame former apparatus. Figure 2 is a schematic of the apparatus.

  2. Hollow porous-wall glass microspheres for hydrogen storage

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC); Schumacher, Ray F. (Aiken, SC); Wicks, George G. (Aiken, SC)

    2010-02-23

    A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

  3. ENCAPSULATION OF PALLADIUM IN POROUS WALL HOLLOW GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Heung, L; George Wicks, G; Ray Schumacher, R

    2008-04-09

    A new encapsulation method was investigated in an attempt to develop an improved palladium packing material for hydrogen isotope separation. Porous wall hollow glass microspheres (PWHGMs) were produced by using a flame former, heat treating and acid leaching. The PWHGMs were then filled with palladium salt using a soak-and-dry process. The palladium salt was reduced at high temperature to leave palladium inside the microspheres.

  4. Porous wall hollow glass microspheres as a medium or substrate for storage and formation of novel materials

    DOE Patents [OSTI]

    Wicks, George G; Serkiz, Steven M.; Zidan, Ragaiy; Heung, Leung K.

    2014-06-24

    Porous wall hollow glass microspheres are provided as a template for formation of nanostructures such as carbon nanotubes, In addition, the carbon nanotubes in combination with the porous wall hollow glass microsphere provides an additional reaction template with respect to carbon nanotubes.

  5. SRNL POROUS WALL GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Wicks, G; Leung Heung, L; Ray Schumacher, R

    2008-04-15

    The Savannah River National Laboratory (SRNL) has developed a new medium for storage of hydrogen and other gases. This involves fabrication of thin, Porous Walled, Hollow Glass Microspheres (PW-HGMs), with diameters generally in the range of 1 to several hundred microns. What is unique about the glass microballons is that porosity has been induced and controlled within the thin, one micron thick walls, on the scale of 10 to several thousand Angstroms. This porosity results in interesting properties including the ability to use these channels to fill the microballons with special absorbents and other materials, thus providing a contained environment even for reactive species. Gases can now enter the microspheres and be retained on the absorbents, resulting in solid-state and contained storage of even reactive species. Also, the porosity can be altered and controlled in various ways, and even used to filter mixed gas streams within a system. SRNL is involved in about a half dozen different programs involving these PW-HGMs and an overview of some of these activities and results emerging are presented.

  6. Hollow clay tile wall program summary report

    SciTech Connect (OSTI)

    Henderson, R.C.; Jones, W.D. [Gilbert/Commonwealth, Inc., Oak Ridge, TN (United States); Beavers, J.E. [MS Technology, Inc. (United States)

    1995-07-30

    Many of the Y-12 Plant buildings, constructed during the 1940s and 1950s, consist of steel ed concrete framing infilled with hollow clay tile (HCT). The infill was intended to provide for building enclosure and was not designed to have vertical or lateral load-carrying capacity. During the late 1970s and early 1980s, seismic and wind evaluations were performed on many of these buildings in conjunction with the preparation of a site-wide safety analysis report. This analytical work, based on the best available methodology, considered lateral load-carrying capacity of the HCT infill on the basis of building code allowable shear values. In parallel with the analysis effort, DOE initiated a program to develop natural phenomena capacity and performance criteria for existing buildings, but these criteria did not specify guidelines for determining the lateral force capacity of frames infilled with HCT. The evaluation of infills was, therefore, based on the provisions for the design of unreinforced masonry as outlined in standard masonry codes. When the results of the seismic and wind evaluations were compared with the new criteria, the projected building capacities fell short of the requirements. Apparently, if the buildings were to meet the new criteria, many millions of dollars would be required for building upgrades. Because the upgrade costs were significant, the assumptions and approaches used in the analyses were reevaluated. Four issues were identified: (1) Once the infilled walls cracked, what capacity (nonlinear response), if any, would the walls have to resist earthquake or wind loads applied in the plane of the infill (in-plane)? (2) Would the infilled walls remain within the steel or reinforced concrete framing when subjected to earthquake or high wind loads applied perpendicular to the infill (out-of-plane)? (3) What was the actual shear capacity of the HCT infill? (4) Was modeling the HCT infill as a shear wall the best approach?

  7. Accepted Manuscript Rational Design and Direct Fabrication of Multi-walled hollow electrospun fi-

    E-Print Network [OSTI]

    Yanikoglu, Berrin

    -shell structures, hollow fibers, multilayers, tri-axial electrospinning Abstract Multi-walled hollow fibers with a novel architecture are fabricated through utilizing a direct, one-step tri-axial electrospinning process an ideal multi-walled hollow electrospun fiber is shown to be producible by tri-axial electrospinning

  8. Apparatus and process to enhance the uniform formation of hollow glass microspheres

    DOE Patents [OSTI]

    Schumacher, Ray F

    2013-10-01

    A process and apparatus is provided for enhancing the formation of a uniform population of hollow glass microspheres. A burner head is used which directs incoming glass particles away from the cooler perimeter of the flame cone of the gas burner and distributes the glass particles in a uniform manner throughout the more evenly heated portions of the flame zone. As a result, as the glass particles are softened and expand by a released nucleating gas so as to form a hollow glass microsphere, the resulting hollow glass microspheres have a more uniform size and property distribution as a result of experiencing a more homogenous heat treatment process.

  9. Improving Glass Walls Thermal Resistance In Air-Conditioned Buildings 

    E-Print Network [OSTI]

    Galal, T.; Kulaib, A. M.; Alajmi, R.; Al-Ansary. A; Abuzaid, M.

    2010-01-01

    walls; as one of envelope surfaces; has an important impact on solar radiation. Design and construction of glass walls have significant effects on building comfort and energy consumption. This paper describes methods of improving glass walls thermal...

  10. Research on Heat Resisting Character of Hollow Building Blocks in Energy Saving Wall 

    E-Print Network [OSTI]

    Zhang, Y.; He, J.; Gao, S.

    2006-01-01

    By establishing a mathematical model with the finite difference method, the three-dimensional temperature fields of a new type of asymmetrical hollow building blocks in an energy saving wall are solved in this paper. The three forms of heat...

  11. Method and apparatus for determining diameter and wall thickness of minute hollow spherical shells

    DOE Patents [OSTI]

    Steinman, D.A.

    1980-05-30

    Method and apparatus for determining diameter and wall thickness of hollow microspheres or shells wherein terminal velocities of shells traveling in fluid-filled conduits of differing diameters are measured. A wall-effect factor is determined as a ratio of the terminal velocities, and shell outside diameter may then be ascertained as a predetermined empirical function of wall-effect factor. For shells of known outside diameter, wall thickness may then be ascertained as a predetermined empirical function of terminal velocity in either conduit.

  12. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  13. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka [Kawasaki Steel Corp., Mizushima, Kurashiki (Japan). Mizushima Works

    1997-12-31

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  14. Quartz antenna with hollow conductor

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Benabou, Elie (Alameda, CA)

    2002-01-01

    A radio frequency (RF) antenna for plasma ion sources is formed of a hollow metal conductor tube disposed within a glass tube. The hollow metal tubular conductor has an internal flow channel so that there will be no coolant leakage if the outer glass tube of the antenna breaks. A portion of the RF antenna is formed into a coil; the antenna is used for inductively coupling RF power to a plasma in an ion source chamber. The antenna is made by first inserting the metal tube inside the glass tube, and then forming the glass/metal composite tube into the desired coil shape.

  15. Method to fabricate hollow microneedle arrays

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Ingersoll, David (Albuquerque, NM); Schmidt, Carrie (Los Lunas, NM); Flemming, Jeb (Albuquerque, NM)

    2006-11-07

    An inexpensive and rapid method for fabricating arrays of hollow microneedles uses a photoetchable glass. Furthermore, the glass hollow microneedle array can be used to form a negative mold for replicating microneedles in biocompatible polymers or metals. These microneedle arrays can be used to extract fluids from plants or animals. Glucose transport through these hollow microneedles arrays has been found to be orders of magnitude more rapid than natural diffusion.

  16. Hollow spherical shell manufacture

    DOE Patents [OSTI]

    O'Holleran, T.P.

    1991-11-26

    A process is disclosed for making a hollow spherical shell of silicate glass composition in which an aqueous suspension of silicate glass particles and an immiscible liquid blowing agent is placed within the hollow spherical cavity of a porous mold. The mold is spun to reduce effective gravity to zero and to center the blowing agent, while being heated so as to vaporize the immiscible liquid and urge the water carrier of the aqueous suspension to migrate into the body of the mold, leaving a green shell compact deposited around the mold cavity. The green shell compact is then removed from the cavity, and is sintered for a time and a temperature sufficient to form a silicate glass shell of substantially homogeneous composition and uniform geometry. 3 figures.

  17. Hollow spherical shell manufacture

    DOE Patents [OSTI]

    O'Holleran, Thomas P. (Belleville, MI)

    1991-01-01

    A process for making a hollow spherical shell of silicate glass composition in which an aqueous suspension of silicate glass particles and an immiscible liquid blowing agent is placed within the hollow spherical cavity of a porous mold. The mold is spun to reduce effective gravity to zero and to center the blowing agent, while being heated so as to vaporize the immiscible liquid and urge the water carrier of the aqueous suspension to migrate into the body of the mold, leaving a green shell compact deposited around the mold cavity. The green shell compact is then removed from the cavity, and is sintered for a time and a temperature sufficient to form a silicate glass shell of substantially homogeneous composition and uniform geometry.

  18. JOM, February 2013, Volume 65, Issue 2, pp 234-245 234 A Review of Thermal Conductivity of Polymer Matrix Syntactic Foams Effect of Hollow Particle Wall

    E-Print Network [OSTI]

    Gupta, Nikhil

    JOM, February 2013, Volume 65, Issue 2, pp 234-245 234 A Review of Thermal Conductivity of Polymer compositions of syntactic foams. Basic understating of the relationship between thermal conductivity Introduction Hollow particle filled polymer matrix composites, called syntactic foams, are used in weight

  19. Review of Synthetic Methods to Form Hollow Polymer Nanocapsules

    SciTech Connect (OSTI)

    Barker, Madeline T.

    2014-03-13

    Syntactic foams have grown in interest due to the widened range of applications because of their mechanical strength and high damage tolerance. In the past, hollow glass or ceramic particles were used to create the pores. This paper reviews literature focused on the controlled synthesis of hollow polymer spheres with diameters ranging from 100 –200 nm. By using hollow polymer spheres, syntactic foams could reach ultra-low densities.

  20. Testing of hollow clay tile masonry prisms

    SciTech Connect (OSTI)

    Jones, W.D.; Butala, M.B.

    1993-10-15

    This paper presents test results of 610-mm wide (24-in.) by 1219-mm high (48-in.) by 203-or 330-mm (8- or 13-in.) thick prisms constructed of hollow clay tiles. Three prisms were extracted fro existing hollow clay title walls and 69 were constructed in laboratories at The University of Tennessee and the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland. Modulus of Elasticity, E, and compressive strength f{prime}{sub m} were calculated from the results.

  1. Domain wall assisted magnetization switching in (111) oriented L1{sub 0} FePt grown on a soft magnetic metallic glass

    SciTech Connect (OSTI)

    Kaushik, Neelam; Sharma, Parmanand; Yubuta, Kunio; Makino, Akihiro; Inoue, Akihisa

    2010-08-16

    We report on growth and magnetic properties of exchange-coupled (111)-L1{sub 0} FePt hard/CoFeTaB soft magnetic metallic glass bilayered structure processed at lower temperature ({approx}400 deg. C). Single phaselike hysteresis loops with tailorable coercivity (<8.2 kOe) in out of plane direction are obtained. The magnetization switching mechanism is identified as domain wall assisted. In views of excellent nanofabrication abilities of metallic glass thin film and the ability to grow preferred oriented L1{sub 0} FePt, the present bilayered structure is very promising for the fabrication of high density bit--patterned magnetic recording media and other spintronic devices.

  2. Hollow nuclear matter

    E-Print Network [OSTI]

    Gao-Chan Yong

    2015-12-18

    It is generally considered that an atomic nucleus is always compact. Based on the isospin-dependent Boltzmann nuclear transport model, here I show that large block nuclear matter or excited nuclear matter may both be hollow. And the size of inner bubble in these matter is affected by the charge number of nuclear matter. Existence of hollow nuclear matter may have many implications in nuclear or atomic physics or astrophysics as well as some practical applications.

  3. Hollow nuclear matter

    E-Print Network [OSTI]

    Yong, Gao-Chan

    2015-01-01

    It is generally considered that an atomic nucleus is always compact. Based on the isospin-dependent Boltzmann nuclear transport model, here I show that large block nuclear matter or excited nuclear matter may both be hollow. And the size of inner bubble in these matter is affected by the charge number of nuclear matter. Existence of hollow nuclear matter may have many implications in nuclear or atomic physics or astrophysics as well as some practical applications.

  4. Hot hollow cathode gun assembly

    DOE Patents [OSTI]

    Zeren, J.D.

    1983-11-22

    A hot hollow cathode deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, the hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

  5. Pattern Alteration: Hollow Chest 

    E-Print Network [OSTI]

    2006-08-04

    Hollow chest is a posture problem characterized by a depression in the upper chest area above the bust line. It causes clothing to fall in horizontal folds across the chest and the grain line to drop at center front. This well...

  6. Glass Production

    E-Print Network [OSTI]

    Shortland, Andrew

    2009-01-01

    40, pp. 162 - 186. Glass Production, Shortland, UEE 2009AINES Short Citation: Shortland 2009, Glass Production. UEE.Andrew, 2009, Glass Production. In Willeke Wendrich (ed. ),

  7. Facile approach to prepare hollow core–shell NiO microspherers for supercapacitor electrodes

    SciTech Connect (OSTI)

    Han, Dandan; Xu, Pengcheng; Jing, Xiaoyan; Wang, Jun; Song, Dalei; Liu, Jingyuan; Zhang, Milin

    2013-07-15

    A facile lamellar template method (see image) has been developed for the preparation of uniform hollow core–shell structure NiO (HCS–NiO) with a nanoarchitectured wall structure. The prepared NiO was found to be highly crystalline in uniform microstructures with high specific surface area and pore volume. The results indicated that ethanol interacted with trisodium citrate played an important role for the formation of hollow core–shell spheres. On the basis of the analysis of the composition and the morphology, a possible formation mechanism was investigated. NiO microspheres with hollow core–shell showed excellent capacitive properties. The exceptional cyclic, structural and electrochemical stability with ?95% coulombic efficiency, and very low ESR value from impedance measurements promised good utility value of hollow core–shell NiO material in fabricating a wide range of high-performance electrochemical supercapacitors. - The hollow core–shell NiO was prepared with a facile lamellar template method. The prepared NiO show higher capacitance, lower ion diffusion resistance and better electroactive surface utilization for Faradaic reactions. - Highlights: • Formation of hollow core–shell NiO via a novel and facile precipitation route. • Exhibited uniform feature sizes and high surface area of hollow core–shell NiO. • Synthesized NiO has high specific capacitance ( 448 F g{sup 1}) and very low ESR value. • Increased 20% of long life cycles capability after 500 charge–discharge cycles.

  8. Open-cell glass crystalline porous material

    DOE Patents [OSTI]

    Anshits, Alexander G.; Sharonova, Olga M.; Vereshchagina, Tatiana A.; Zykova, Irina D.; Revenko, Yurii A.; Tretyakov, Alexander A.; Aloy, Albert S.; Lubtsev, Rem I.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

    2003-12-23

    An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

  9. Open-cell glass crystalline porous material

    DOE Patents [OSTI]

    Anshits, Alexander G. (Krasnoyarsk, RU); Sharonova, Olga M. (Krasnoyarsk, RU); Vereshchagina, Tatiana A. (Krasnoyarsk, RU); Zykova, Irina D. (Krasnoyarsk, RU); Revenko, Yurii A. (Zheleznogorsk, RU); Tretyakov, Alexander A. (Zheleznogorsk, RU); Aloy, Albert S. (Saint-Petersburg, RU); Lubtsev, Rem I. (Saint-Petersburg, RU); Knecht, Dieter A. (Idaho Falls, ID); Tranter, Troy J. (Idaho Falls, ID); Macheret, Yevgeny (Idaho Falls, ID)

    2002-01-01

    An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

  10. Hollow Core Fiber Optics for Mid-Wave and Long-Wave Infrared Spectroscopy

    SciTech Connect (OSTI)

    Kriesel, J.M.; Gat, N.; Bernacki, Bruce E.; Erikson, Rebecca L.; Cannon, Bret D.; Myers, Tanya L.; Bledt, Carlos M.; Harrington, J. A.

    2011-06-01

    The development and testing of hollow core glass waveguides (i.e., fiber optics) for use in Long-Wave Infrared (LWIR) spectroscopy systems is described. LWIR fiber optics are a key enabling technology needed to improve the utility and effectiveness of trace chemical detection systems based in the 8 to 12 micron region. This paper focuses on recent developments in hollow waveguide technology geared specifically for LWIR spectroscopy, including a reduction in both the length dependent loss and the bending loss while maintaining relatively high beam quality. Results will be presented from tests conducted with a Quantum Cascade Laser.

  11. Hollow electrode plasma excitation source

    DOE Patents [OSTI]

    Ballou, Nathan E. (West Richland, WA)

    1992-01-01

    A plasma source incorporates a furnace as a hollow anode, while a coaxial cathode is disposed therewithin. The source is located in a housing provided with an ionizable gas such that a glow discharge is produced between anode and cathode. Radiation or ionic emission from the glow discharge characterizes a sample placed within the furnace and heated to elevated temperatures.

  12. Hollow electrode plasma excitation source

    DOE Patents [OSTI]

    Ballou, N.E.

    1992-04-14

    A plasma source incorporates a furnace as a hollow anode, while a coaxial cathode is disposed therewithin. The source is located in a housing provided with an ionizable gas such that a glow discharge is produced between anode and cathode. Radiation or ionic emission from the glow discharge characterizes a sample placed within the furnace and heated to elevated temperatures. 5 figs.

  13. Hollow Plasma in a Solenoid

    SciTech Connect (OSTI)

    Anders, Andre; Kauffeldt, Marina; Oks, Efim M.; Roy, Prabir K.

    2010-11-30

    A ring cathode for a pulsed, high-current, multi-spot cathodic arc discharge was placed inside a pulsed magnetic solenoid. Photography is used to evaluate the plasma distribution. The plasma appears hollow for cathode positions close the center of the solenoid, and it is guided closer to the axis when the cathode is away from the center.

  14. Glass Production

    E-Print Network [OSTI]

    Shortland, Andrew

    2009-01-01

    Late Bronze Age glasses. Journal of Archaeological Science781 - 789. Turner, W.E.S. 1954 Studies in ancient glassesand glass making processes. Part I: Crucibles and melting

  15. Control of focusing forces and emittances in plasma-based accelerators using near-hollow plasma channels

    SciTech Connect (OSTI)

    Schroeder, C. B.; Esarey, E.; Benedetti, C.; Leemans, W. P.

    2013-08-15

    A near-hollow plasma channel, where the plasma density in the channel is much less than the plasma density in the walls, is proposed to provide independent control over the focusing and accelerating forces in a plasma accelerator. In this geometry the low density in the channel contributes to the focusing forces, while the accelerating fields are determined by the high density in the channel walls. The channel also provides guiding for intense laser pulses used for wakefield excitation. Both electron and positron beams can be accelerated in a nearly symmetric fashion. Near-hollow plasma channels can effectively mitigate emittance growth due to Coulomb scattering for high-energy physics applications.

  16. Process for making hollow carbon spheres

    DOE Patents [OSTI]

    Luhrs, Claudia C.; Phillips, Jonathan; Richard, Monique N.; Knapp, Angela Michelle

    2013-04-16

    A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.

  17. Phase behavior and material properties of hollow nanoparticles

    E-Print Network [OSTI]

    U. S. Schwarz; S. A. Safran

    2000-09-02

    Effective pair potentials for hollow nanoparticles like the ones made from carbon (fullerenes) or metal dichalcogenides (inorganic fullerenes) consist of a hard core repulsion and a deep, but short-ranged, van der Waals attraction. We investigate them for single- and multi-walled nanoparticles and show that in both cases, in the limit of large radii the interaction range scales inversely with the radius, $R$, while the well depth scales linearly with $R$. We predict the values of the radius $R$ and the wall thickness $h$ at which the gas-liquid coexistence disappears from the phase diagram. We also discuss unusual material properties of the solid, which include a large heat of sublimation and a small surface energy.

  18. Debris-less method and apparatus for forming apertures in hollow metallic articles

    DOE Patents [OSTI]

    Jordan, C.L.; Chodelka, E.J.

    1980-06-24

    This invention is a method for forming an aperture in a wall of a hollow metallic article without introducing metallic debris therein. In a typical operation, an annular groove is formed in an exterior portion of the wall. The groove defines an annular wall segment, and the bottom of the groove is shaped to slope downwardly away from the segment to form a tapered annular web which connects the segment to the wall. Any suitable coupling is attached to the outer face of the segment, as by welding. Pull then is applied to the coupling to effect circumferential breakage of the web, thus forming a removable single-piece wall fragment consisting of the web and segment. The fragment and the coupling member attached thereto then are removed from the wall.

  19. Glass balls

    E-Print Network [OSTI]

    There is a building with 100 floors in it, and glass balls, and an integer k with the following property. If one drops a glass ball from the floor number k or higher, ...

  20. Tiny Glass Bubbles With Big Potential

    Broader source: Energy.gov [DOE]

    If these glass microspheres' walls could talk…They would explain how their tiny pores allow the potential for handling, storing and transporting a variety of materials, including drugs that have...

  1. Mechanism of bubble detachment from vibrating walls

    SciTech Connect (OSTI)

    Kim, Dongjun; Park, Jun Kwon Kang, Kwan Hyoung; Kang, In Seok

    2013-11-15

    We discovered a previously unobserved mechanism by which air bubbles detach from vibrating walls in glasses containing water. Chaotic oscillation and subsequent water jets appeared when a wall vibrated at greater than a critical level. Wave forms were developed at water-air interface of the bubble by the wall vibration, and water jets were formed when sufficiently grown wave-curvatures were collapsing. Droplets were pinched off from the tip of jets and fell to the surface of the glass. When the solid-air interface at the bubble-wall attachment point was completely covered with water, the bubble detached from the wall. The water jets were mainly generated by subharmonic waves and were generated most vigorously when the wall vibrated at the volume resonant frequency of the bubble. Bubbles of specific size can be removed by adjusting the frequency of the wall's vibration.

  2. Non-lead hollow point bullet

    DOE Patents [OSTI]

    Vaughn, Norman L. (Knoxville, TN); Lowden, Richard A. (Clinton, TN)

    2003-04-15

    The non-lead hollow point bullet of the instant invention comprises a mixed construction slug further comprising, a monolithic metal insert having a tapered (preferred conical) hollow point tip and a tapered (preferred conical) tail protrusion, and an unsintered powdered metal composite core in tandem alignment with the insert. The core has a hollow tapered (preferred conical) cavity tip portion coupled with the tapered (preferred conical) tail protrusion on the insert. An open tip jacket envelops at least a portion of the insert and the core. The jacket is swaged at the open tip.

  3. Collimation Studies with Hollow Electron Beams

    SciTech Connect (OSTI)

    Stancari, G.; Annala, G.; Johnson, T.R.; Saewert, G.W.; Shiltsev, V.; Still, D.A.; Valishev, A.; /Fermilab

    2011-08-01

    Recent experimental studies at the Fermilab Tevatron collider have shown that magnetically confined hollow electron beams can act as a new kind of collimator for high-intensity beams in storage rings. In a hollow electron beam collimator, electrons enclose the circulating beam. Their electric charge kicks halo particles transversely. If their distribution is axially symmetric, the beam core is unaffected. This device is complementary to conventional two-stage collimation systems: the electron beam can be placed arbitrarily close to the circulating beam; and particle removal is smooth, so that the device is a diffusion enhancer rather than a hard aperture limitation. The concept was tested in the Tevatron collider using a hollow electron gun installed in one of the existing electron lenses. We describe some of the technical aspects of hollow-beam scraping and the results of recent measurements.

  4. Method to produce large, uniform hollow spherical shells

    DOE Patents [OSTI]

    Hendricks, C.D.

    1983-09-26

    The invention is a method to produce large uniform hollow spherical shells by (1) forming uniform size drops of heat decomposable or vaporizable material, (2) evaporating the drops to form dried particles, (3) coating the dried particles with a layer of shell forming material and (4) heating the composite particles to melt the outer layer and to decompose or vaporize the inner particle to form an expanding inner gas bubble. The expanding gas bubble forms the molten outer layer into a shell of relatively large diameter. By cycling the temperature and pressure on the molten shell, nonuniformities in wall thickness can be reduced. The method of the invention is utilized to produce large uniform spherical shells, in the millimeter to centimeter diameter size range, from a variety of materials and of high quality, including sphericity, concentricity and surface smoothness, for use as laser fusion or other inertial confinement fusion targets as well as other applications.

  5. Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2010-01-01

    Phosphate Glass and Glass-Ceramic Proton Conductors Hannah.phosphate glasses and glass-ceramics were investigated. Therare earth phosphate ceramics, glasses, and glass-ceramics

  6. Coating Glass Cells with OTS The glass cells we use to polarize xenon or to store polarized

    E-Print Network [OSTI]

    Walsworth, Ronald L.

    Coating Glass Cells with OTS The glass cells we use to polarize xenon or to store polarized xenon need to be coated. This is because without coating wall collisions of the xenon can bring with a trichlorosilane at one end. In the coating process that group binds to the silicates in the glass, relinquishing

  7. Tamper-indicating device having a glass body

    DOE Patents [OSTI]

    Johnston, Roger G. (Los Alamos, NM); Garcia, Anthony R. E. (Espanola, NM)

    2003-04-29

    A tamper-indicating device is described. The device has a first glass body member and a second glass body member that are attached to each other through a hasp. The glass body members of the device can be tempered. The body members can be configured with hollow volumes into which powders, microparticles, liquids, gels, or combinations thereof are sealed. The choice, the amount, and the location of these materials can produce a visible, band pattern to provide each body member with a unique fingerprint identifier, which makes it extremely difficult to repair or replace once it is damaged in order to avoid tamper detection.

  8. 18-1165-29AA selectingHollow Fiber

    E-Print Network [OSTI]

    Lebendiker, Mario

    18-1165-29AA selectingHollow Fiber Cartridges and Systems #12;#12;introduction About this guide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 chapter 1 - Selecting a hollow fiber cross flow membrane cartridge Introduction . . . . . . . . . . . . . 12 Cartridge selection illustrated with process examples

  9. Method of making a non-lead hollow point bullet

    DOE Patents [OSTI]

    Vaughn, Norman L.; Lowden, Richard A.

    2003-10-07

    The method of making a non-lead hollow point bullet has the steps of a) compressing an unsintered powdered metal composite core into a jacket, b) punching a hollow cavity tip portion into the core, c) seating an insert, the insert having a hollow point tip and a tail protrusion, on top of the core such that the tail protrusion couples with the hollow cavity tip portion, and d) swaging the open tip of the jacket.

  10. Glass Transition in Confined Geometry

    E-Print Network [OSTI]

    Simon Lang; Vitalie Botan; Martin Oettel; David Hajnal; Thomas Franosch; Rolf Schilling

    2010-08-23

    Extending mode-coupling theory, we elaborate a microscopic theory for the glass transition of liquids confined between two parallel flat hard walls. The theory contains the standard MCT equations in bulk and in two dimensions as limiting cases and requires as input solely the equilibrium density profile and the structure factors of the fluid in confinement. We evaluate the phase diagram as a function of the distance of the plates for the case of a hard sphere fluid and obtain an oscillatory behavior of the glass transtion line as a result of the structural changes related to layering.

  11. ITP Glass: Glass Industry of the Future: Energy and Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: A Clear Vision for a Bright Future ITP Glass: Glass Industry Technology Roadmap; April 2002...

  12. Process for manufacturing hollow fused-silica insulator cylinder

    DOE Patents [OSTI]

    Sampayan, Stephen E. (Manteca, CA); Krogh, Michael L. (Lee's Summit, MO); Davis, Steven C. (Lee's Summit, MO); Decker, Derek E. (Discovery Bay, CA); Rosenblum, Ben Z. (Overland Park, KS); Sanders, David M. (Livermore, CA); Elizondo-Decanini, Juan M. (Albuquerque, NM)

    2001-01-01

    A method for building hollow insulator cylinders that can have each end closed off with a high voltage electrode to contain a vacuum. A series of fused-silica round flat plates are fabricated with a large central hole and equal inside and outside diameters. The thickness of each is related to the electron orbit diameter of electrons that escape the material surface, loop, and return back. Electrons in such electron orbits can support avalanche mechanisms that result in surface flashover. For example, the thickness of each of the fused-silica round flat plates is about 0.5 millimeter. In general, the thinner the better. Metal, such as gold, is deposited onto each top and bottom surface of the fused-silica round flat plates using chemical vapor deposition (CVD). Eutectic metals can also be used with one alloy constituent on the top and the other on the bottom. The CVD, or a separate diffusion step, can be used to defuse the deposited metal deep into each fused-silica round flat plate. The conductive layer may also be applied by ion implantation or gas diffusion into the surface. The resulting structure may then be fused together into an insulator stack. The coated plates are aligned and then stacked, head-to-toe. Such stack is heated and pressed together enough to cause the metal interfaces to fuse, e.g., by welding, brazing or eutectic bonding. Such fusing is preferably complete enough to maintain a vacuum within the inner core of the assembled structure. A hollow cylinder structure results that can be used as a core liner in a dielectric wall accelerator and as a vacuum envelope for a vacuum tube device where the voltage gradients exceed 150 kV/cm.

  13. Through a glass darkly

    E-Print Network [OSTI]

    Hall, James E

    2012-01-01

    Closeup Through a glass darklyThrough a glass darkly James E. Hall Keywords: AKAP2; AQP0;Medicine Closeup Through a glass darkly GLUT1 Glucose

  14. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, T.D.

    1993-12-14

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes. 3 figures.

  15. Electrochemical Cell Design With A Hollow Gate

    DOE Patents [OSTI]

    Romero, Antonio (Parkton, MD); Oweis, Salah (Ellicott City, MD); Chagnon, Guy (Columbia, MD); Staniewicz, Robert (Hunt Valley, MD); Briscoe, Douglas (Westminster, MD)

    2000-02-01

    An electrochemical cell having a spiral winding around a central core, wherein the central core is provided with longitudinal grooves on its outer surface to facilitate electrolyte filing and accommodate overpressure. The core itself improves dissipation of heat generated along the center of the cell, and the hollow core design allows the cell core to have a larger radius, permitting the "jelly roll" winding to begin at a larger radius and thereby facilitate the initial turns of the winding by decreasing the amount of bending required of the electrode laminate at the beginning of the winding operation. The hollow core also provides mechanical support end-to-end. A pair of washers are used at each end of the cell to sandwich current collection tabs in a manner that improves electrical and thermal conductivity while also providing structural integrity.

  16. A novel synthesis of micrometer silica hollow sphere

    SciTech Connect (OSTI)

    Pan Wen; Ye Junwei [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Zhongshan Road 158-43, Dalian 116012 (China); Ning Guiling [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Zhongshan Road 158-43, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Lin Yuan; Wang Jing [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Zhongshan Road 158-43, Dalian 116012 (China)

    2009-02-04

    Silica microcapsules (hollow spheres) were synthesized successfully by a novel CTAB-stabilized water/oil emulsion system mediated hydrothermal method. The addition of urea to a solution of aqueous phase was an essential step of the simple synthetic procedure of silica hollow spheres, which leads to the formation of silica hollow spheres with smooth shell during hydrothermal process. The intact hollow spheres were obtained by washing the as-synthesized solid products with distilled water to remove the organic components. A large amount of silanol groups were retained in the hollow spheres by this facile route without calcination. The morphologies and optical properties of the product were characterized by transmission electron microscopy, scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy. Furthermore, on the basis of a series of SEM observations, phenomenological elucidation of a mechanism for the growth of the silica hollow spheres has been presented.

  17. Glass Furnace Combustion and Melting Research Facility.

    SciTech Connect (OSTI)

    Connors, John J.; McConnell, John F.; Henry, Vincent I.; MacDonald, Blake A.; Gallagher, Robert J.; Field, William B.; Walsh, Peter M.; Simmons, Michael C.; Adams, Michael E.; Leadbetter, James M.; Tomasewski, Jack W.; Operacz, Walter J.; Houf, William G.; Davis, James W.; Marvin, Bart G.; Gunner, Bruce E.; Farrell, Rick G.; Bivins, David P.; Curtis, Warren; Harris, James E.

    2004-08-01

    The need for a Combustion and Melting Research Facility focused on the solution of glass manufacturing problems common to all segments of the glass industry was given high priority in the earliest version of the Glass Industry Technology Roadmap (Eisenhauer et al., 1997). Visteon Glass Systems and, later, PPG Industries proposed to meet this requirement, in partnership with the DOE/OIT Glass Program and Sandia National Laboratories, by designing and building a research furnace equipped with state-of-the-art diagnostics in the DOE Combustion Research Facility located at the Sandia site in Livermore, CA. Input on the configuration and objectives of the facility was sought from the entire industry by a variety of routes: (1) through a survey distributed to industry leaders by GMIC, (2) by conducting an open workshop following the OIT Glass Industry Project Review in September 1999, (3) from discussions with numerous glass engineers, scientists, and executives, and (4) during visits to glass manufacturing plants and research centers. The recommendations from industry were that the melting tank be made large enough to reproduce the essential processes and features of industrial furnaces yet flexible enough to be operated in as many as possible of the configurations found in industry as well as in ways never before attempted in practice. Realization of these objectives, while still providing access to the glass bath and combustion space for optical diagnostics and measurements using conventional probes, was the principal challenge in the development of the tank furnace design. The present report describes a facility having the requirements identified as important by members of the glass industry and equipped to do the work that the industry recommended should be the focus of research. The intent is that the laboratory would be available to U.S. glass manufacturers for collaboration with Sandia scientists and engineers on both precompetitive basic research and the solution of proprietary glass production problems. As a consequence of the substantial increase in scale and scope of the initial furnace concept in response to industry recommendations, constraints on funding of industrial programs by DOE, and reorientation of the Department's priorities, the OIT Glass Program is unable to provide the support for construction of such a facility. However, it is the present investigators' hope that a group of industry partners will emerge to carry the project forward, taking advantage of the detailed furnace design presented in this report. The engineering, including complete construction drawings, bill of materials, and equipment specifications, is complete. The project is ready to begin construction as soon as the quotations are updated. The design of the research melter closely follows the most advanced industrial practice, firing by natural gas with oxygen. The melting area is 13 ft x 6 ft, with a glass depth of 3 ft and an average height in the combustion space of 3 ft. The maximum pull rate is 25 tons/day, ranging from 100% batch to 100% cullet, continuously fed, with variable batch composition, particle size distribution, and raft configuration. The tank is equipped with bubblers to control glass circulation. The furnace can be fired in three modes: (1) using a single large burner mounted on the front wall, (2) by six burners in a staggered/opposed arrangement, three in each breast wall, and (3) by down-fired burners mounted in the crown in any combination with the front wall or breast-wall-mounted burners. Horizontal slots are provided between the tank blocks and tuck stones and between the breast wall and skewback blocks, running the entire length of the furnace on both sides, to permit access to the combustion space and the surface of the glass for optical measurements and sampling probes. Vertical slots in the breast walls provide additional access for measurements and sampling. The furnace and tank are to be fully instrumented with standard measuring equipment, such as flow meters, thermocouples, continuous gas composition

  18. HGMS: Glasses and Nanocomposites for Hydrogen Storage.

    SciTech Connect (OSTI)

    Lipinska, Kris; Hemmers, Oliver

    2013-02-17

    The primary goal of this project is to fabricate and investigate different glass systems and glass-derived nanocrystalline composite materials. These glass-based, two-phased materials will contain nanocrystals that can attract hydrogen and be of potential interest as hydrogen storage media. The glass materials with intrinsic void spaces that are able to precipitate functional nanocrystals capable to attract hydrogen are of particular interest. Proposed previously, but never practically implemented, one of promising concepts for storing hydrogen are micro-containers built of glass and shaped into hollow microspheres. The project expanded this concept to the exploration of glass-derived nanocrystalline composites as potential hydrogen storage media. It is known that the most desirable materials for hydrogen storage do not interact chemically with hydrogen and possess a high surface area to host substantial amounts of hydrogen. Glasses are built of disordered networks with ample void spaces that make them permeable to hydrogen even at room temperature. Glass-derived nanocrystalline composites (two-phased materials), combination of glasses (networks with ample voids) and functional nanocrystals (capable to attract hydrogen), appear to be promising candidates for hydrogen storage media. Key advantages of glass materials include simplicity of preparation, flexibility of composition, chemical durability, non-toxicity and mechanical strength, as well as low production costs and environmental friendliness. This project encompasses a fundamental research into physics and chemistry of glasses and nanocrystalline composite materials, derived from glass. Studies are aimed to answer questions essential for considering glass-based materials and composites as potential hydrogen storage media. Of particular interest are two-phased materials that combine glasses with intrinsic voids spaces for physisorption of hydrogen and nanocrystals capable of chemisorption. This project does not directly address any hydrogen storage technical barriers or targets in terms of numbers. Specifically, hydrogen sorption and desorption tests or kinetics measurements were not part of the project scope. However, the insights gained from these studies could help to answer fundamental questions necessary for considering glass-based materials as hydrogen storage media and could be applied indirectly towards the DOE hydrogen storage technical targets such as system weight and volume, system cost and energy density. Such questions are: Can specific macro-crystals, proven to attract hydrogen when in a macroscopic form (bulk), be nucleated in glass matrices as nanocrystals to create two-phased materials? What are suitable compositions that enable to synthetize glass-based, two-phase materials with nanocrystals that can attract hydrogen via surface or bulk interactions? What are the limits of controlling the microstructure of these materials, especially limits for nanocrystals density and size? Finally, from a technological point of view, the fabrication of glass-derived nanocomposites that we explore is a very simple, fast and inexpensive process that does not require costly or specialized equipment which is an important factor for practical applications.

  19. Casting of particle-based hollow shapes

    DOE Patents [OSTI]

    Menchhofer, Paul (Oak Ridge, TN)

    1997-01-01

    A method for the production of hollow articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is coated onto a prewarmed continuous surface in a relatively thin layer so that the slurry is substantially uniformly coated on the surface. The heat of the prewarmed surface conducts to the slurry to initiate a reaction which causes the slurry to set or harden in a shape conforming to the surface. The hardened configurations may then be sintered to consolidate the particles and provide a high density product.

  20. Casting of particle-based hollow shapes

    DOE Patents [OSTI]

    Menchhofer, Paul (Oak Ridge, TN)

    1995-01-01

    A method for the production of hollow articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is coated onto a prewarmed continuous surface in a relatively thin layer so that the slurry is substantially uniformly coated on the surface. The heat of the prewarmed surface conducts to the slurry to initiate a reaction which causes the slurry to set or harden in a shape conforming to the surface. The hardened configurations may then be sintered to consolidate the particles and provide a high density product.

  1. Self-contained hot-hollow cathode gun source assembly

    DOE Patents [OSTI]

    Zeren, J.D.

    1984-08-01

    A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

  2. Self-contained hot-hollow cathode gun source assembly

    DOE Patents [OSTI]

    Zeren, Joseph D. (Boulder, CO)

    1986-01-01

    A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

  3. The Blue Wall

    E-Print Network [OSTI]

    Milano, Michael

    2015-01-01

    The  Blue  Wall   A  Documentary  Film  by     Michael  talking   about,  The  Blue  Wall.   Your  Honor,  as  the  

  4. Formation of hollow nanocrystals through the nanoscale kirkendall effect

    SciTech Connect (OSTI)

    Yin, Yadong; Rioux, Robert M.; Erdonmez, Can K.; Hughes, Steven; Somorjai, Gabor A.; Alivisatos, A. Paul

    2004-03-11

    We demonstrate that hollow nanocrystals can be synthesized through a mechanism analogous to the Kirkendall Effect, in which pores form due to the difference in diffusion rates between two components in a diffusion couple. Cobalt nanocrystals are chosen as a primary example to show that their reaction in solution with oxygen, sulfur or selenium leads to the formation of hollow nanocrystals of the resulting oxide and chalcogenides. This process provides a general route to the synthesis of hollow nanostructures of large numbers of compounds. A simple extension of this process yields platinum-cobalt oxide yolk-shell nanostructures which may serve as nanoscale reactors in catalytic applications.

  5. Development of hollow electron beams for proton and ion collimation

    SciTech Connect (OSTI)

    Stancari, G.; Drozhdin, A.I.; Kuznetsov, G.; Shiltsev, V.; Still, D.A.; Valishev, A.; Vorobiev, L.G.; Assmann, R.; Kabantsev, A.

    2010-06-01

    Magnetically confined hollow electron beams for controlled halo removal in high-energy colliders such as the Tevatron or the LHC may extend traditional collimation systems beyond the intensity limits imposed by tolerable material damage. They may also improve collimation performance by suppressing loss spikes due to beam jitter and by increasing capture efficiency. A hollow electron gun was designed and built. Its performance and stability were measured at the Fermilab test stand. The gun will be installed in one of the existing Tevatron electron lenses for preliminary tests of the hollow-beam collimator concept, addressing critical issues such as alignment and instabilities of the overlapping proton and electron beams.

  6. Fabrication of AlN/BN bishell hollow nanofibers by electrospinning and atomic layer deposition

    SciTech Connect (OSTI)

    Haider, Ali; Kayaci, Fatma; Uyar, Tamer; Biyikli, Necmi; Ozgit-Akgun, Cagla; Okyay, Ali Kemal

    2014-09-01

    Aluminum nitride (AlN)/boron nitride (BN) bishell hollow nanofibers (HNFs) have been fabricated by successive atomic layer deposition (ALD) of AlN and sequential chemical vapor deposition (CVD) of BN on electrospun polymeric nanofibrous template. A four-step fabrication process was utilized: (i) fabrication of polymeric (nylon 6,6) nanofibers via electrospinning, (ii) hollow cathode plasma-assisted ALD of AlN at 100?°C onto electrospun polymeric nanofibers, (iii) calcination at 500?°C for 2 h in order to remove the polymeric template, and (iv) sequential CVD growth of BN at 450?°C. AlN/BN HNFs have been characterized for their chemical composition, surface morphology, crystal structure, and internal nanostructure using X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, and selected area electron diffraction. Measurements confirmed the presence of crystalline hexagonal BN and AlN within the three dimensional (3D) network of bishell HNFs with relatively low impurity content. In contrast to the smooth surface of the inner AlN layer, outer BN coating showed a highly rough 3D morphology in the form of BN nano-needle crystallites. It is shown that the combination of electrospinning and plasma-assisted low-temperature ALD/CVD can produce highly controlled multi-layered bishell nitride ceramic hollow nanostructures. While electrospinning enables easy fabrication of nanofibrous template, self-limiting reactions of plasma-assisted ALD and sequential CVD provide control over the wall thicknesses of AlN and BN layers with sub-nanometer accuracy.

  7. NEWS & VIEWS Glass dynamics

    E-Print Network [OSTI]

    Weeks, Eric R.

    NEWS & VIEWS Glass dynamics Diverging views on glass transition Gregory B. mc.mckenna@ttu.edu T he glass transition is one of the most intriguing phenomena in the world of soft condensed matter. Despite decades of study, many aspects of the behaviour of glass-forming liquids remain elusive

  8. Glass-silicon column

    DOE Patents [OSTI]

    Yu, Conrad M.

    2003-12-30

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  9. Hollow-Fiber Membrane Compressed Air Drying System

    Broader source: Energy.gov [DOE]

    With the support of a NICE3 grant, a new hollow-fiber membrane for dehydrating gases has been developed by Air Products and Chemicals, Inc. The membrane has 5 times higher water vapor permeation...

  10. Loading rubidium atoms into a hollow core fiber

    E-Print Network [OSTI]

    Chu, Yiwen

    2007-01-01

    We demonstrate a procedure for cooling, trapping, and transferring rubidium atoms into a hollow core photonic band gap fiber. The atoms are first collected in a magneto-optical trap (MOT) and then cooled using polarization ...

  11. Colloidal Glass Transition Observed in Confinement Carolyn R. Nugent,* Kazem V. Edmond, Hetal N. Patel, and Eric R. Weeks

    E-Print Network [OSTI]

    Weeks, Eric R.

    Colloidal Glass Transition Observed in Confinement Carolyn R. Nugent,* Kazem V. Edmond, Hetal N suspension confined between two quasiparallel walls as a model system for glass transitions in confined. For higher volume fraction samples (closer to the glass transition), the onset of confinement effects occurs

  12. ITP Glass: Industrial Glass Bandwidth Analysis Final Report,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 industrialbandwidth.pdf More Documents &...

  13. Resistance heater for use in a glass melter

    DOE Patents [OSTI]

    Routt, K.R.; Porter, M.A.

    1984-01-01

    A resistance heating element that includes: a resistance heating medium of a mixture of electrically conductive and insulative particles in powdered form mixed together in predetermined proportions to achieve a given resistivity; a hollow outer electrode surrounding the resistance heating medium; and an inner electrode coaxially disposed within said outer electrode. In its preferred embodiments, the electrically conductive powder is selected from the group consisting essentially of graphite, Inconel alloy, molybdenum, nichrome alloy and stainless steel, while the insulator powder is silicon dioxide or alumina. The resistance heating element, being resistant to damage from mechanical shock and corrosion at elevated temperatures, is used in a glass melter.

  14. Glass Working, Use and Discard

    E-Print Network [OSTI]

    Nicholson, Paul

    2011-01-01

    Beck, Horace C. 1934 Glass before 1500 BC. Ancient Egypt7 - 21. Cooney, John 1960 Glass sculpture in ancient Egypt.Journal of Glass Studies 2, pp. 10 - 43. 1976 Glass.

  15. Stained glass : an investigation into the design potentials of an architectural material

    E-Print Network [OSTI]

    Ransom, Shirley Anne

    1986-01-01

    Colored glass is a building material usually associated with churches or days of bygone glory. Yet the material would apparently have much to offer in window openings, curtain walls, even as structural block in the creating ...

  16. Daylight photocatalysis performance of biomorphic CeO{sub 2} hollow fibers prepared with lens cleaning paper as biotemplate

    SciTech Connect (OSTI)

    Qian, Junchao; Chen, Feng [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China)] [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Wang, Fang; Zhao, Xiaobing [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China)] [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China); Chen, Zhigang, E-mail: ziyou1900@gmail.com [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China) [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Jiangsu Key Laboratory for Environment Functional Materials, 215009 Suzhou University of Science and Technology, Suzhou (China); State Key laboratory of Crystal Material, Shandong University, 250100 Jinan (China)

    2012-08-15

    Highlights: ? A novel, simple and eco-friendly approach for hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls is presented by using paper as template. ? The biomorphic CeO{sub 2} fibers was composed of nanosheets with bimodal pore-size mesoporous distribution and exhibited high light-harvesting under sunlight irradiation. ? The CeO{sub 2} microfibers biomimicking the natural plant structures have promising application for photodegradation of organic pollutants in water. -- Abstract: Hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls have been fabricated using lens cleaning paper as biotemplates. After sintered at 550 °C in air, the cellulosic fibers of paper were converted into micro-tubes composing of CeO{sub 2} crystallites with grain size about 8 nm. The photocatalytic activity of the CeO{sub 2} fibers was evaluated by photodegradation efficiency of methylene blue in aqueous solution under daylight irradiation. The characterized results show that the CeO{sub 2} fibers faithfully replicated micro-fibrous structure derived from original template and possessed dramatic enhanced photocatalytic activity compared with bulk CeO{sub 2}. This simple biotemplate method provides a cost-effective and eco-friendly route to obtain high performance photocatalysts.

  17. MECS 2006- Glass

    Broader source: Energy.gov [DOE]

    Manufacturing Energy and Carbon Footprint for Glass (NAICS 3272, 327993) Sector with Total Energy Input, October 2012 (MECS 2006)

  18. Hollow proppants and a process for their manufacture

    DOE Patents [OSTI]

    Jones, Arfon H. (Salt Lake City, UT); Cutler, Raymond A. (Salt Lake City, UT)

    1985-01-01

    Hollow, fine-grained ceramic proppants are less expensive and improve fracture control when compared to conventional proppants (dense alumina, mullite, bauxite, zirconia, etc.). Hollow proppants of the present invention have been fabricated by spray drying, followed by sintering in order to obtain a dense case and a hollow core. These proppants generally have high sphericity and roundness (Krumbein sphericity and roundness greater than 0.8), have diameters on average between 2250 and 125 .mu.m, depending on proppant size required, and have strength equal to or greater than that of sand. The hollow core, the size of which can be controlled, permits better fracture control in hydraulic fracturing treatments since the proppant can be transported in lower viscosity fluids. Hollow proppants produced at the same cost/weight as conventional proppants also provide for lower costs, since less weight is required to fill the same volume. The fine-grained (preferably less than 5 .mu.m in diameter) ceramic case provides the strength necessary to withstand closure stresses and prevent crushing.

  19. Hollow proppants and a process for their manufacture

    DOE Patents [OSTI]

    Jones, A.H.; Cutler, R.A.

    1985-10-15

    Hollow, fine-grained ceramic proppants are less expensive and improve fracture control when compared to conventional proppants (dense alumina, mullite, bauxite, zirconia, etc.). Hollow proppants of the present invention have been fabricated by spray drying, followed by sintering in order to obtain a dense case and a hollow core. These proppants generally have high sphericity and roundness (Krumbein sphericity and roundness greater than 0.8), have diameters on average between 2,250 and 125 [mu]m, depending on proppant size required, and have strength equal to or greater than that of sand. The hollow core, the size of which can be controlled, permits better fracture control in hydraulic fracturing treatments since the proppant can be transported in lower viscosity fluids. Hollow proppants produced at the same cost/weight as conventional proppants also provide for lower costs, since less weight is required to fill the same volume. The fine-grained (preferably less than 5 [mu]m in diameter) ceramic case provides the strength necessary to withstand closure stresses and prevent crushing. 6 figs.

  20. Wall surveyor project report

    SciTech Connect (OSTI)

    Mullenhoff, D.J.; Johnston, B.C.; Azevedo, S.G.

    1996-02-22

    A report is made on the demonstration of a first-generation Wall Surveyor that is capable of surveying the interior and thickness of a stone, brick, or cement wall. LLNL`s Micropower Impulse Radar is used, based on emitting and detecting very low amplitude and short microwave impulses (MIR rangefinder). Six test walls were used. While the demonstrator MIR Wall Surveyor is not fieldable yet, it has successfully scanned the test walls and produced real-time images identifying the walls. It is planned to optimize and package the evaluation wall surveyor into a hand held unit.

  1. Analysis and Research on the Thermal Properties of Energy-efficient Building Glass: A Case Study in PVB Laminated Glass 

    E-Print Network [OSTI]

    Chen, Z.; Meng, Q.

    2006-01-01

    the end of 2001, 42,000,000 square meters of glass curtain wall are set up in our country. The style of glazing units has developed from simple ones in the past days to variety nowadays, LOW-E glasses, PVB glasses, double or triple-glazing insulated... million tons of standard coal in China, 27.8% of the total social energy consumption and around 1/3 of the value of the developed countries. The level of Guangzhou, 30%, is a little higher than the average level of the country. [2,3]Therefore, glazing...

  2. Oxynitride glass production procedure

    DOE Patents [OSTI]

    Weidner, Jerry R. (Idaho Falls, ID); Schuetz, Stanley T. (Idaho Falls, ID); O'Brien, Michael H. (Idaho Falls, ID)

    1991-01-01

    The invention is a process for the preparation of high quality oxynitride glasses without resorting to high pressures. Nitrogen-containing compounds such as Si.sub.3 N.sub.4 are first encapsulated in a low melting temperature glass. Particles of the encapsulated nitrogen-containing compound are mixed with other oxide glass-formers and melted in an atmosphere of flowing nitrogen and in the presence of buffering gas to form the oxynitride glass. Glasses containing up to 15 at % nitrogen have been prepared by this method.

  3. A hollow sphere as a detector of gravitational radiation

    E-Print Network [OSTI]

    E. Coccia; V. Fafone; G. Frossati; J. A. Lobo; J. A. Ortega

    1997-07-30

    The most important features of the proposed spherical gravitational wave detectors are closely linked with their symmetry. Hollow spheres share this property with solid ones, considered in the literature so far, and constitute an interesting alternative for the realization of an omnidirectional gravitational wave detector. In this paper we address the problem of how a hollow elastic sphere interacts with an incoming gravitational wave and find an analytical solution for its normal mode spectrum and response, as well as for its energy absorption cross sections. It appears that this shape can be designed having relatively low resonance frequencies (about 200 Hz) yet keeping a large cross section, so its frequency range overlaps with the projected large interferometers. We also apply the obtained results to discuss the performance of a hollow sphere as a detector for a variety of gravitational wave signals.

  4. Scanning optical pyrometer for measuring temperatures in hollow cathodes

    SciTech Connect (OSTI)

    Polk, J. E.; Marrese-Reading, C. M.; Thornber, B.; Dang, L.; Johnson, L. K.; Katz, I.

    2007-09-15

    Life-limiting processes in hollow cathodes are determined largely by the temperature of the electron emitter. To support cathode life assessment, a noncontact temperature measurement technique which employs a stepper motor-driven fiber optic probe was developed. The probe is driven inside the hollow cathode and collects light radiated by the hot interior surface of the emitter. Ratio pyrometry is used to determine the axial temperature profile. Thermocouples on the orifice plate provide measurements of the external temperature during cathode operation and are used to calibrate the pyrometer system in situ with a small oven enclosing the externally heated cathode. The diagnostic method and initial measurements of the temperature distribution in a hollow cathode are discussed.

  5. Synthesis of hollow porous nanospheres of hydroxyl titanium oxalate and their topotactic conversion to anatase titania

    E-Print Network [OSTI]

    Synthesis of hollow porous nanospheres of hydroxyl titanium oxalate and their topotactic conversion-step wet chemistry route has been explored to synthesize hollow hydroxyl titanium oxalate nanoscale spheres hydroxyl titanium oxalate nano- spheres and their corresponding non-hollow porous anatase TiO2 nanospheres

  6. The Hydrogen-Based Hollow-Fiber Membrane Biofilm Reactor (HFMBfR) for Removing Oxidized

    E-Print Network [OSTI]

    Nerenberg, Robert

    The Hydrogen-Based Hollow-Fiber Membrane Biofilm Reactor (HFMBfR) for Removing Oxidized documents that the hydrogen-based hollow-fiber membrane-biofilm reactor (HFMBfR) is technically. The hydrogen pressure to the hollow fibers is a key control parameter that can be adjusted rapidly and easily

  7. Deposition and characterization of metal sulfide dielectric coatings for hollow glass waveguides

    E-Print Network [OSTI]

    and G. Ghosh, Handbook of optical constants of solids, (Academic, London, 1998). 2. Sopra database for n. T Ayala, O Gomezdaza, A Sanchez, J Compos, H Hu, R Suarez, and M. E. Rincon, "Semiconductor thin films

  8. Investigation of metal sulfide optical thin film growth in low-loss IR hollow glass waveguides

    E-Print Network [OSTI]

    ­103 (2003). 4. E. D. Palik and G. Ghosh, Handbook of Optical Constants of Solids (Academic, 1998). 5. M of Semiconductor Films (Marcel Dekker, Inc., 2003). 11. R. Ortega-Borges and D. Lincot, "Mechanism of chemical bath

  9. Diamond turning of glass

    SciTech Connect (OSTI)

    Blackley, W.S.; Scattergood, R.O.

    1988-12-01

    A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

  10. Potential use of hollow spheres in dual gradient drilling 

    E-Print Network [OSTI]

    Vera Vera, Liliana

    2002-01-01

    even when the concentration of spheres injected is smaller than that required to reduce the mud density to seawater density. If the base mud is the carrier fluid, the hollow spheres DGD systems do not require equipment at the seafloor. Additionally...

  11. Evaluation of Plasma Resistant Hollow Fiber Membranes For Artificial Lungs

    E-Print Network [OSTI]

    Federspiel, William J.

    Evaluation of Plasma Resistant Hollow Fiber Membranes For Artificial Lungs HEIDE J. EASH,* HEATHER in artificial lungs (ox- ygenators) undergo plasma leakage (or wetting) in which blood plasma slowly fills2 gas permeance of a plasma resistant fiber imposes the greatest constraint upon artificial lung

  12. HLW Glass Waste Loadings

    Office of Environmental Management (EM)

    HLW Glass Waste Loadings Ian L. Pegg Vitreous State Laboratory The Catholic University of America Washington, DC Overview Overview Vitrification - general background Joule...

  13. ITP Glass: Glass Industry Technology Roadmap; April 2002

    Office of Energy Efficiency and Renewable Energy (EERE)

    Glass is a unique material that has been produced for thousands of years. The glass industry's products are an integral part of the American economy and everyday life. Glass products are used in food and beverage packaging, lighting, communications, etc.

  14. Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2010-01-01

    300-500°C. Doping rare earth phosphate glasses with Ce, andRare Earth Phosphate Glass and Glass-Ceramic Protonconductivity of alkaline-earth doped rare earth phosphate

  15. Plasma processes inside dispenser hollow cathodes

    SciTech Connect (OSTI)

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.; Jameson, Kristina K.

    2006-06-15

    A two-dimensional fluid model of the plasma and neutral gas inside dispenser orificed hollow cathodes has been developed to quantify plasma processes that ultimately determine the life of the porous emitters inserted in these devices. The model self-consistently accounts for electron emission from the insert as well as for electron and ion flux losses from the plasma. Two cathodes, which are distinctively different in size and operating conditions, have been simulated numerically. It is found that the larger cathode, with outer tube diameter of 1.5 cm and orifice diameter of 0.3 cm, establishes an effective emission zone that spans approximately the full length of the emitter when operated at a discharge current of 25 A and a flow rate of 5.5 sccm. The net heating of the emitter is caused by ions that are produced by ionization of the neutral gas inside the tube and are then accelerated by the sheath along the emitter. The smaller cathode, with an outer diameter of 0.635 cm and an orifice diameter of 0.1 cm, does not exhibit the same operational characteristics. At a flow rate of 4.25 sccm and discharge current of 12 A, the smaller cathode requires 4.5 times the current density near the orifice and operates with more than 6 times the neutral particle density compared to the large cathode. As a result, the plasma particle density is almost one order of magnitude higher compared to the large cathode. The plasma density in this small cathode is high enough such that the Debye length is sufficiently small to allow 'sheath funneling' into the pores of the emitter. By accessing areas deeper into the insert material, it is postulated that the overall emission of electrons is significantly enhanced. The maximum emission current density is found to be about 1 A/mm{sup 2} in the small cathode, which is about one order of magnitude higher than attained in the large cathode. The effective emission zone in the small cathode extends to about 15% of the emitter length only, and the power deposited at the emitter surface by returning electrons is found to be twice that deposited by ions. A previous study suggested that the computed particle flux and energy of ions to the emitter of the 1.5 cm cathode were not high enough to change the barium evaporation rate compared to thermally induced evaporation. The same suggestion is made here for the 0.635 cm cathode. The peak ion flux to the emitter is found to be 1.2 A/cm{sup 2} (7.6x10{sup 18}/s cm{sup 2}), and the corresponding peak sheath drop is 2.9 V. Consequently, once the emitter operating temperature is known it is possible to determine directly the barium depletion-limited life of these cathodes using existing vacuum-cathode data.

  16. Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors

    SciTech Connect (OSTI)

    De Jonghe, Lutgard C.; Ray, Hannah L.; Wang, Ruigang

    2008-12-03

    The structure and conductivity of cerium and lanthanum phosphate glasses and glass-ceramics were investigated. The effects of varying the metal to phosphate ratio in the glasses, doping LaP3O9 glasses with Ce, and recrystallization of CeP3O9 glasses, on the glasses' microstructure and total conductivity were investigated using XRD, SEM, and AC impedance techniques. Strong increases in conductivity occurred when the glasses were recrystallized: the conductivity of a cerium metaphosphate glass increased conductivity after recrystallization from 10-7.5 S/cm to 10-6 S/cm at 400oC.

  17. The art of glass blowing

    E-Print Network [OSTI]

    Dugan, David; Macfarlane, Alan

    2004-08-23

    Alan Macfarlane talks to Tony Cummins, one of the last traditional glass blowers, as he demonstrates his art and the making of a flat glass object in an old glass house near Birmingham....

  18. Fluidized wall for protecting fusion chamber walls

    DOE Patents [OSTI]

    Maniscalco, James A. (Danville, CA); Meier, Wayne R. (Livermore, CA)

    1982-01-01

    Apparatus for protecting the inner wall of a fusion chamber from microexplosion debris, x-rays, neutrons, etc. produced by deuterium-tritium (DT) targets imploded within the fusion chamber. The apparatus utilizes a fluidized wall similar to a waterfall comprising liquid lithium or solid pellets of lithium-ceramic, the waterfall forming a blanket to prevent damage of the structural materials of the chamber.

  19. Defense HLW Glass Degradation Model

    SciTech Connect (OSTI)

    D. Strachan

    2004-10-20

    The purpose of this report is to document the development of a model for calculating the release rate for radionuclides and other key elements from high-level radioactive waste (HLW) glasses under exposure conditions relevant to the performance of the repository. Several glass compositions are planned for the repository, some of which have yet to be identified (i.e., glasses from Hanford and Idaho National Engineering and Environmental Laboratory). The mechanism for glass dissolution is the same for these glasses and the glasses yet to be developed for the disposal of DOE wastes. All of these glasses will be of a quality consistent with the glasses used to develop this report.

  20. Glass, Brian 1 BRIAN DANIEL GLASS, M.A.

    E-Print Network [OSTI]

    Maddox, W. Todd

    Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Texas at Austin Austin, TX 78712 (512) 232-2883 e-mail: glass@mail.utexas.edu EDUCATION 2006 ­ Cognitive include: Designing and constructing experiments, statistical #12;Glass, Brian 2 analysis, manuscript

  1. Glass, Brian 1 BRIAN DANIEL GLASS, M.A.

    E-Print Network [OSTI]

    Maddox, W. Todd

    Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Designing and constructing, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D., Chotibut, T

  2. Glass, Brian 1 BRIAN DANIEL GLASS, M.A.

    E-Print Network [OSTI]

    Maddox, W. Todd

    Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Categorization and Decision Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Programming, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D

  3. Room-temperature Formation of Hollow Cu2O Nanoparticles

    SciTech Connect (OSTI)

    Hung, Ling-I; Tsung, Chia-Kuang; Huang, Wenyu; Yang, Peidong

    2010-01-18

    Monodisperse Cu and Cu2O nanoparticles (NPs) are synthesized using tetradecylphosphonic acid as a capping agent. Dispersing the NPs in chloroform and hexane at room temperature results in the formation of hollow Cu2O NPs and Cu@Cu2O core/shell NPs, respectively. The monodisperse Cu2O NPs are used to fabricate hybrid solar cells with efficiency of 0.14percent under AM 1.5 and 1 Sun illumination.

  4. Negative ion source with hollow cathode discharge plasma

    DOE Patents [OSTI]

    Hershcovitch, A.; Prelec, K.

    1980-12-12

    A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface is described. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

  5. Glass electrolyte composition

    DOE Patents [OSTI]

    Kucera, G.H.; Roche, M.F.

    1985-01-08

    An ionically conductive glass is disclosed for use as electrolyte in a high temperature electrochemical cell, particularly a cell with sodium anode and sulfur cathode. The glass includes the constituents Na/sub 2/O, ZrO/sub 2/, Al/sub 2/O/sub 3/ and SiO/sub 2/ in selected proportions to be a single phase solid solution substantially free of crystalline regions and undissolved constituents. Other advantageous properties are an ionic conductivity in excess of 2 x 10/sup -3/ (ohm-cm)/sup -1/ at 300/sup 0/C and a glass transition temperature in excess of 500/sup 0/C.

  6. EXELFS of Metallic Glasses

    SciTech Connect (OSTI)

    Ito, Y.; Alamgir, F.M.; Schwarz, R.B.; Jain, H.; Williams, D.B.

    1999-11-30

    The feasibility of using extended energy-loss fine structure (EXELFS) obtained from {approximately}1 nm regions of metallic glasses to study their short-range order has been examined. Ionization edges of the metallic glasses in the electron energy-loss spectrum (EELS) have been obtained from PdNiP bulk metallic glass and Ni{sub 2}P polycrystalline powder in a transmission electron microscope. The complexity of EXELFS analysis of L- and M-ionization edges of heavy elements (Z>22, i.e. Ni and Pd) is addressed by theoretical calculations using an ab initio computer code, and its results are compared with the experimental data.

  7. Photonic bandgap narrowing in conical hollow core Bragg fibers

    SciTech Connect (OSTI)

    Ozturk, Fahri Emre; Yildirim, Adem; Kanik, Mehmet; Bayindir, Mehmet

    2014-08-18

    We report the photonic bandgap engineering of Bragg fibers by controlling the thickness profile of the fiber during the thermal drawing. Conical hollow core Bragg fibers were produced by thermal drawing under a rapidly alternating load, which was applied by introducing steep changes to the fiber drawing speed. In conventional cylindrical Bragg fibers, light is guided by omnidirectional reflections from interior dielectric mirrors with a single quarter wave stack period. In conical fibers, the diameter reduction introduced a gradient of the quarter wave stack period along the length of the fiber. Therefore, the light guided within the fiber encountered slightly smaller dielectric layer thicknesses at each reflection, resulting in a progressive blueshift of the reflectance spectrum. As the reflectance spectrum shifts, longer wavelengths of the initial bandgap cease to be omnidirectionally reflected and exit through the cladding, which narrows the photonic bandgap. A narrow transmission bandwidth is particularly desirable in hollow waveguide mid-infrared sensing schemes, where broadband light is coupled to the fiber and the analyte vapor is introduced into the hollow core to measure infrared absorption. We carried out sensing simulations using the absorption spectrum of isopropyl alcohol vapor to demonstrate the importance of narrow bandgap fibers in chemical sensing applications.

  8. Tokamak reactor first wall

    DOE Patents [OSTI]

    Creedon, R.L.; Levine, H.E.; Wong, C.; Battaglia, J.

    1984-11-20

    This invention relates to an improved first wall construction for a tokamak fusion reactor vessel, or other vessels subjected to similar pressure and thermal stresses.

  9. Baseline LAW Glass Formulation Testing

    SciTech Connect (OSTI)

    Kruger, Albert A. [USDOE Office of River Protection, Richland, WA (United States); Mooers, Cavin [The Catholic University of America, Washington, DC (United States). Vitreous State Lab.; Bazemore, Gina [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Pegg, Ian L. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Hight, Kenneth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Lai, Shan Tao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Buechele, Andrew [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Rielley, Elizabeth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Gan, Hao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Muller, Isabelle S. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Cecil, Richard [The Catholic University of America, Washington, DC (United States). Vitreous State Lab

    2013-06-13

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  10. Super ionic conductive glass

    DOE Patents [OSTI]

    Susman, Sherman (Park Forest, IL); Volin, Kenneth J. (Fort Collins, CO)

    1984-01-01

    An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  11. Broad-band robustly single-mode hollow-core PCF by resonant filtering of higher order modes

    E-Print Network [OSTI]

    Günendi, Mehmet C; Frosz, Michael H; Russell, Philip St J

    2015-01-01

    We propose and theoretically analyse a novel hollow-core photonic crystal fibre (PCF) that is engineered so as to strongly suppress higher order modes, i.e., to provide robust LP$_{01}$ single-mode guidance in all the wavelength ranges where the fibre guides with low loss. Encircling the core is a single ring of non-touching glass elements whose modes are tailored to ensure resonant phase-matched coupling to higher-order core modes, causing them to leak at a very high rate into the supporting solid glass sheath. Using a model based on coupled capillary waveguides, as well as full vectorial finite element modelling, we show that this modal filtering effect depends on only one dimensionless geometrical parameter, akin to the well-known $d/{\\Lambda}$ parameter for endlessly single-mode solid-core PCF. The design is scalable up to large core sizes and is predicted to deliver LP$_{01}$ mode losses of some $10$s of dB/km in multiple transmission windows, the broadest of which spans more than an octave. At the same ...

  12. DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION

    SciTech Connect (OSTI)

    Adamson, D; Bradley Pickenheim, B

    2008-11-24

    DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point that the test apparatus had to be disassembled to dislodge the plugs created in the system.

  13. The Seduction of the Glass Box

    E-Print Network [OSTI]

    Ackerly, Katie

    2013-01-01

    Visual, and Spatial Effects of Glass, New York: PrincetonBauten, Perspektiven (Glass Architects: Concepts, Buildings,Taking a Second Look: Glass Pavilion at Broadfield House in

  14. Glass blowing on a wafer level

    E-Print Network [OSTI]

    Eklund, E. Jesper; Shkel, Andrei M.

    2007-01-01

    E. Shelby, Introduction to Glass Science and Technology. :Properties of Corning Glasses [Online]. Available: http://1981. [15] R. H. Doremus, Glass Science. New York: Wiley,

  15. Eddy current system for inspection of train hollow axles

    SciTech Connect (OSTI)

    Chady, Tomasz; Psuj, Grzegorz; Sikora, Ryszard; Kowalczyk, Jacek; Spychalski, Ireneusz [Department of Electrical and Computer Engineering, Faculty of Electrical Engineering, West Pomeranian University of Technology, Szczecin (Poland)

    2014-02-18

    The structural integrity of wheelsets used in rolling stock is of great importance to the safety. In this paper, electromagnetic system with an eddy current transducer suitable for the inspection of hollow axles have been presented. The transducer was developed to detect surface braking defects having depth not smaller than 0.5 mm. Ultrasound technique can be utilized to inspect the whole axle, but it is not sufficiently sensitive to shallow defects located close to the surface. Therefore, the electromagnetic technique is proposed to detect surface breaking cracks that cannot be detected by ultrasonic technique.

  16. Baiting Hollow, New York: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAandAmminex AAustriaBiofuels Brasil Jump to:BabetteBaileyBaiting Hollow,

  17. Driving laser pulse evolution in a hollow channel laser wakefield accelerator

    E-Print Network [OSTI]

    Wurtele, Jonathan

    Driving laser pulse evolution in a hollow channel laser wakefield accelerator P. Volfbeyn, P. B of the coupling between a high-intensity laser pulse and a plasma wake is presented, in the context of laser wakefield acceleration in a hollow channel. Laser wavelength reddening and pulse length shortening

  18. Hydrogen-based, hollow-fiber membrane biofilm reactor for reduction of perchlorate and other oxidized

    E-Print Network [OSTI]

    Nerenberg, Robert

    Hydrogen-based, hollow-fiber membrane biofilm reactor for reduction of perchlorate and other. For drinking water treatment, an electron donor must be added. Hydrogen is an ideal electron donor, as it is non-toxic, inexpensive, and sparsely soluble. We tested a hydrogen-based, hollow-fiber membrane

  19. Consecutive Solvent Evaporation and Co-Rolling Techniques for Polymer Multilayer Hollow Fiber

    E-Print Network [OSTI]

    Skorobogatiy, Maksim

    Consecutive Solvent Evaporation and Co-Rolling Techniques for Polymer Multilayer Hollow Fiber, "Consecutive solvent evaporation and co-rolling techniques for polymer multilayer hollow fiber preform Layer-by-Layer Solvent Evaporation Process Polymer tube (cladding) Polymer 1 Polymer 2 Drawing Fiber #12

  20. Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga

    E-Print Network [OSTI]

    1 Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga.O. Box 451, Princeton, NJ 08543 May 31, 1999 Abstract Energy distributions of N atoms in a hollow, University of Illinois c Varian Associates, Inc. #12;2 atom energy distributions for atomic ions

  1. Glass | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,Executive CompensationEnergyGet Current: Switch onDepartment2GlassGlass

  2. Quasi-static energy absorption of hollow microlattice structures

    SciTech Connect (OSTI)

    Liu, YL; Schaedler, TA; Jacobsen, AJ; Chen, X

    2014-12-01

    We present a comprehensive modeling and numerical study focusing on the energy quasi-static crushing behavior and energy absorption characteristics of hollow tube microlattice structures. The peak stress and effective plateau stress of the hollow microlattice structures are deduced for different geometrical parameters which gives volume and mass densities of energy absorption, D-v and D-m, scale with the relative density, (rho) over bar, as D-v similar to (rho) over bar (1) (5) and D-m similar to (rho) over bar (0 5), respectively, fitting very well to the experimental results of both 60 degrees inclined and 90 degrees predominately microlattices. Then the strategies for energy absorption enhancement are proposed for the engineering design of microlattice structures. By introducing a gradient in the thickness or radius of the lattice members, the buckle propagation can be modulated resulting in an increase in energy absorption density that can exceed 40%. Liquid filler is another approach to improve energy absorption by strengthening the microtruss via circumference expansion, and the gain may be over 100% in terms of volume density. Insight into the correlations between microlattice architecture and energy absorption performance combined with the high degree of architecture control paves the way for designing high performance microlattice structures for a range of impact and impulse mitigation applications for vehicles and structures. (C) 2014 Elsevier Ltd. All rights reserved.

  3. The Color Glass Condensate

    E-Print Network [OSTI]

    F. Gelis; E. Iancu; J. Jalilian-Marian; R. Venugopalan

    2010-02-01

    We provide a broad overview of the theoretical status and phenomenological applications of the Color Glass Condensate effective field theory describing universal properties of saturated gluons in hadron wavefunctions that are extracted from deeply inelastic scattering and hadron-hadron collision experiments at high energies.

  4. Intrinsic Dosimetry: Elemental Composition Effects on the Thermoluminescence of Commercial Borosilicate Glass

    SciTech Connect (OSTI)

    Richard A. Clark; J. David Robertson; Jon M. Schwantes

    2013-12-01

    Intrinsic dosimetry is the method of measuring total absorbed dose received by the walls of a container holding radioactive material. By considering this dose in tandem with the physical characteristics of the radioactive material housed within the container, this method can provide enhanced pathway information for interdicted radioactive samples. Thermoluminescence (TL) dosimetry was used to measure ionizing radiation dose effects on stock borosilicate glass. Differences in TL glow curve shape and intensity were observed for glasses from different geographical origins. The different TL signatures strongly correlated with the concentration of alkaline earth metals and the ratio of sodium to the total amount of alkali metal present in the borosilicate glass.

  5. Incorporation and distribution of rhenium in a borosilicate glass melt heat treated in a sealed ampoule

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, Michael J.

    2013-07-25

    We investigated a mass balance of rhenium (used as a surrogate for technetium-99) in a borosilicate glass that was mixed with excess Re source (KReO4) beyond its solubility and heat treated in a vacuum-sealed fused silica ampoule. Distribution of Re in the bulk of the glass, in a salt phase formed on the melt surface, and in condensate material deposited on the ampoule wall was evaluated to understand the Re migration into different phases during the reaction between the molten glass and KReO4. The information gained from this study will contribute to an effort to understand the mechanism of technetium retention in or escape from glass melt during early stages of glass batch melting, which is a goal of the present series of studies.

  6. Production of glass or glass-ceramic to metal seals with the application of pressure

    DOE Patents [OSTI]

    Kelly, M.D.; Kramer, D.P.

    1985-01-04

    In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

  7. Transformation from hollow carbon octahedra to compressed octahedra and their use in lithium-ion batteries

    SciTech Connect (OSTI)

    Mei, Tao; Li, Na; Li, Qianwen; Xing, Zheng; Tang, Kaibin; Zhu, Yongchun [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China)] [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China); Qian, Yitai, E-mail: ytqian@ustc.edu.cn [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China) [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China); School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100 (China); Shen, Xiaoyan [Jiangsu Highstar Battery Manufacturing CO., LTD (China)] [Jiangsu Highstar Battery Manufacturing CO., LTD (China)

    2012-06-15

    Graphical abstract: Schematic illustration of the transformation process from hollow carbon octahedra into deflated balloon-like compressed hollow carbon octahedra ?. Highlights: ? We demonstrate the in situ template synthesis of hollow carbon octahedra. ? The shell thickness of hollow carbon octahedra is only 2.5 nm. ? Morphology transformation could be realized by extending of reaction time. ? The hollow structures show reversible capacity as 353 mAh g{sup ?1} after 100 cycles. -- Abstract: Hollow carbon octahedra with an average size of 300 nm and a shell thickness of 2.5 nm were prepared by a reaction starting from ferrocene and Mg(CH{sub 3}COO){sub 2}·4H{sub 2}O at 700 °C for 10 h. They became compressed and turned into deflated balloon-like octahedra when the reaction time was increased to 16 h. It was proposed that the gas pressure generated during the reaction process induced the transformation from broken carbon hollow octahedra into deflated balloon-like compressed octahedra. X-ray powder diffraction and Raman spectroscopy indicate that the as-obtained carbon products possess a graphitic structure and high-resolution transmission electron microscopy images indicate that they have low crystallinity. Their application as an electrode shows reversible capacity of 353 mAh g{sup ?1} after 100 cycles in the charge/discharge experiments of secondary lithium ion batteries.

  8. Thermal treatment wall

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Newmark, Robin L. (Livermore, CA); Knauss, Kevin G. (Livermore, CA)

    2000-01-01

    A thermal treatment wall emplaced to perform in-situ destruction of contaminants in groundwater. Thermal destruction of specific contaminants occurs by hydrous pyrolysis/oxidation at temperatures achievable by existing thermal remediation techniques (electrical heating or steam injection) in the presence of oxygen or soil mineral oxidants, such as MnO.sub.2. The thermal treatment wall can be installed in a variety of configurations depending on the specific objectives, and can be used for groundwater cleanup, wherein in-situ destruction of contaminants is carried out rather than extracting contaminated fluids to the surface, where they are to be cleaned. In addition, the thermal treatment wall can be used for both plume interdiction and near-wellhead in-situ groundwater treatment. Thus, this technique can be utilized for a variety of groundwater contamination problems.

  9. Covering Walls With Fabrics. 

    E-Print Network [OSTI]

    Anonymous,

    1979-01-01

    , grasscloth and many other textures and weaves are available in this type of wall covering. When selecting fabrics to apply to interior walls, consider pattern, color, amount of shrink age and weight. Check to see if the design is printed with the grain... several times over a 12-inch length until fabric is cut through and can be pulled away easily (see Figure 5) . Figure 5 To cover raw edges at top or bottom when . there is no molding, attach an attractive gimp, flat braid or decorative molding...

  10. Angular output of hollow, metal-lined, waveguide Raman sensors

    SciTech Connect (OSTI)

    Biedrzycki, Stephen; Buric, Michael P.; Falk, Joel; Woodruff, Steven D.

    2012-04-20

    Hollow, metal-lined waveguides used as gas sensors based on spontaneous Raman scattering are capable of large angular collection. The collection of light from a large solid angle implies the collection of a large number of waveguide modes. An accurate estimation of the propagation losses for these modes is required to predict the total collected Raman power. We report a theory/experimental comparison of the Raman power collected as a function of the solid angle and waveguide length. New theoretical observations are compared with previous theory appropriate only for low-order modes. A cutback experiment is demonstrated to verify the validity of either theory. The angular distribution of Raman light is measured using aluminum and silver-lined waveguides of varying lengths.

  11. Moisture Research - Optimizing Wall Assemblies

    SciTech Connect (OSTI)

    Arena, Lois; Mantha, Pallavi

    2013-05-01

    In this project, the Consortium for Advanced Residential Buildings (CARB) team evaluated several different configurations of wall assemblies to determine the accuracy of moisture modeling and make recommendations to ensure durable, efficient assemblies. WUFI and THERM were used to model the hygrothermal and heat transfer characteristics of these walls. Wall assemblies evaluated included code minimum walls using spray foam insulation and fiberglass batts, high R-value walls at least 12 in. thick (R-40 and R-60 assemblies), and brick walls with interior insulation.

  12. Analytical Plan for Roman Glasses

    SciTech Connect (OSTI)

    Strachan, Denis M.; Buck, Edgar C.; Mueller, Karl T.; Schwantes, Jon M.; Olszta, Matthew J.; Thevuthasan, Suntharampillai; Heeren, Ronald M.

    2011-01-01

    Roman glasses that have been in the sea or underground for about 1800 years can serve as the independent “experiment” that is needed for validation of codes and models that are used in performance assessment. Two sets of Roman-era glasses have been obtained for this purpose. One set comes from the sunken vessel the Iulia Felix; the second from recently excavated glasses from a Roman villa in Aquileia, Italy. The specimens contain glass artifacts and attached sediment or soil. In the case of the Iulia Felix glasses quite a lot of analytical work has been completed at the University of Padova, but from an archaeological perspective. The glasses from Aquileia have not been so carefully analyzed, but they are similar to other Roman glasses. Both glass and sediment or soil need to be analyzed and are the subject of this analytical plan. The glasses need to be analyzed with the goal of validating the model used to describe glass dissolution. The sediment and soil need to be analyzed to determine the profile of elements released from the glass. This latter need represents a significant analytical challenge because of the trace quantities that need to be analyzed. Both pieces of information will yield important information useful in the validation of the glass dissolution model and the chemical transport code(s) used to determine the migration of elements once released from the glass. In this plan, we outline the analytical techniques that should be useful in obtaining the needed information and suggest a useful starting point for this analytical effort.

  13. Hollow-fiber gas-membrane process for removal of NH{sub 3} from solution of NH{sub 3} and CO{sub 2}

    SciTech Connect (OSTI)

    Qin, Y.; Cabral, J.M.S.; Wang, S.

    1996-07-01

    A hollow-fiber supported gas membrane process for the separation of NH{sub 3} from aqueous solutions containing both NH{sub 3} and CO{sub 2} was investigated theoretically and experimentally. A lumen laminar flow and radial diffusion model was applied to calculate the membrane wall transfer coefficient from the data stripping a single volatile component, NH{sub 3} or CO{sub 2}, from their individual aqueous solutions. Influence of the type of membranes and operating conditions on mass-transfer rate were discussed, especially the influence of the membrane transfer coefficient on the film mass-transfer coefficient in the lumen. Appropriate configurations of the hollow-fiber modules for stripping of a single component were analyzed to optimize mass transfer. To predict the stripping of NH{sub 3} from a solution containing NH{sub 3} and CO{sub 2}, a mathematical model incorporating local chemical equilibria and Nernst-Planck diffusion was developed to describe the mass transport. The models described the experimental data fairly well. The experimental results showed that the supported gas membrane process can be used to remove NH{sub 3} effectively from aqueous media containing NH{sub 3} and CO{sub 2}.

  14. Glass Property Models and Constraints for Estimating the Glass...

    Office of Scientific and Technical Information (OSTI)

    increases in waste loading in HLW and LAW glasses are possible over current system planning estimates. The data (although limited in some cases) were evaluated to determine a...

  15. Mixed polyanion glass cathodes: Iron phosphate vanadate glasses

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

    2014-01-01

    Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

  16. ITP Glass: Glass Industry of the Future: Energy and Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    remove air pollutants through the use of aqueous media, filters, and precipitators. Air pollution control technologies used in the glass industry commonly transfer...

  17. Experimental study of a fiber absorber-suppressor modified Trombe wall

    SciTech Connect (OSTI)

    Choudhury, D; Birkebak, R C

    1982-12-01

    An experimental study has been conducted to ascertain the effects of introducing fiber bed absorbers on Trombe wall passive solar collectors. Two identical, Trombe wall passive solar units were constructed that incorporate the basic components of masonry collector-storage walls: glazings, masonry and thermal insulation. Both units were extensively instrumented with thermocouples and heat flux transducers. Ambient temperature, relative humidity, wind speed and insolation are also measured. In the first part of the study the two Trombe wall units were tested with a single glass cover. The thermal performance of both units was found to be virtually identical. In the second part of the study a single cover Trombe wall unit was compared with a double cover unit and the latter was found to have higher air gap and masonry wall temperatures and heat fluxes. In the final phase of the experiment, an absorbing, scattering and emitting fiberglass-like material was placed in the air gap of the single gazed wall. Tests were conducted to compare the solar-thermal performance, heat loss and gain characteristics between the units with and without the fiber absorber-suppressor. This experiment showed that the fiber bed served to decouple the wall at night from its exterior environment and to reduce the heat losses. The modified Trombe wall with the fiber absorber-suppressor out-performed the double glazed Trombe wall system by approximately ten percent gain in useable thermal energy. Also, the fiber bed eliminates one glazing thereby reducing system cost as well.

  18. IMPROVEMENT IN THE SIMULATION OF INJECTION MOLDED SHORT GLASS FIBER THERMOPLASTIC COMPOSITES

    E-Print Network [OSTI]

    Wapperom, Peter

    Page 1 IMPROVEMENT IN THE SIMULATION OF INJECTION MOLDED SHORT GLASS FIBER THERMOPLASTIC COMPOSITES Abstract The mechanical properties of injection molded short-fiber reinforced thermoplastic composite parts to frontal flow and the walls. Introduction This Fiber reinforced thermoplastics made by injection molding

  19. Nanoindentation as a Tool for Understanding Nano-mechanical Properties of Wood Cell Wall and Biocomposites

    E-Print Network [OSTI]

    Wang, Siqun

    alternative fibers with conventional fibers, such as glass, carbon or aramid fibers and talc [1-4]. Natural natural fibers and plastic waste, and for preparing water- resistant natural fiber based materials without National Laboratory, Oak Ridge, Tennessee ABSTRACT Cellulose fibers, cell wall fragments and cellulose

  20. High-R Walls for Remodeling: Wall Cavity Moisture Monitoring

    SciTech Connect (OSTI)

    Wiehagen, J.; Kochkin, V.

    2012-12-01

    The focus of the study is on the performance of wall systems, and in particular, the moisture characteristics inside the wall cavity and in the wood sheathing. Furthermore, while this research will initially address new home construction, the goal is to address potential moisture issues in wall cavities of existing homes when insulation and air sealing improvements are made.

  1. High-R Walls for Remodeling. Wall Cavity Moisture Monitoring

    SciTech Connect (OSTI)

    Wiehagen, J.; Kochkin, V.

    2012-12-01

    The focus of the study is on the performance of wall systems, and in particular, the moisture characteristics inside the wall cavity and in the wood sheathing. Furthermore, while this research will initially address new home construction, the goal is to address potential moisture issues in wall cavities of existing homes when insulation and air sealing improvements are made.

  2. Depolarized guided acoustic wave Brillouin scattering in hollow-core photonic crystal fibers

    E-Print Network [OSTI]

    Zhong, Wenjia Elser née; Elser, Dominique; Heim, Bettina; Marquardt, Christoph; Leuchs, Gerd

    2015-01-01

    By performing quantum-noise-limited optical heterodyne detection, we observe polarization noise in light after propagation through a hollow-core photonic crystal fiber (PCF). We compare the noise spectrum to the one of a standard fiber and find an increase of noise even though the light is mainly transmitted in air in a hollow-core PCF. Combined with our simulation of the acoustic vibrational modes in the hollow-core PCF, we are offering an explanation for the polarization noise with a variation of guided acoustic wave Brillouin scattering (GAWBS). Here, instead of modulating the strain in the fiber core as in a solid core fiber, the acoustic vibrations in hollow-core PCF influence the effective refractive index by modulating the geometry of the photonic crystal structure. This induces polarization noise in the light guided by the photonic crystal structure.

  3. Depolarized guided acoustic wave Brillouin scattering in hollow-core photonic crystal fibers

    E-Print Network [OSTI]

    Wenjia Elser née Zhong; Birgit Stiller; Dominique Elser; Bettina Heim; Christoph Marquardt; Gerd Leuchs

    2015-08-06

    By performing quantum-noise-limited optical heterodyne detection, we observe polarization noise in light after propagation through a hollow-core photonic crystal fiber (PCF). We compare the noise spectrum to the one of a standard fiber and find an increase of noise even though the light is mainly transmitted in air in a hollow-core PCF. Combined with our simulation of the acoustic vibrational modes in the hollow-core PCF, we are offering an explanation for the polarization noise with a variation of guided acoustic wave Brillouin scattering (GAWBS). Here, instead of modulating the strain in the fiber core as in a solid core fiber, the acoustic vibrations in hollow-core PCF influence the effective refractive index by modulating the geometry of the photonic crystal structure. This induces polarization noise in the light guided by the photonic crystal structure.

  4. New applications of hollow-core components in housing, administrative and public housing

    E-Print Network [OSTI]

    Beroukhim, Farnaz A

    1985-01-01

    Standard prestressed hollow-core slabs have many advantages as construction members while being relatively very low in cost. The principal advantages include the ease of mass production, a small cross-sectional area, light ...

  5. Hollow cylinder dynamic pressurization and radial flow through permeability tests for cementitous materials 

    E-Print Network [OSTI]

    Jones, Christopher Andrew

    2009-05-15

    Saturated permeability is likely a good method for characterizing the susceptibility of portland cement concrete to various forms of degradation; although no widely accepted test exists to measure this property. The hollow ...

  6. HOLLOWS: A Power-aware Task Scheduler for Energy Harvesting Sensor Nodes

    E-Print Network [OSTI]

    Simunic, Tajana

    (WCMA), which we have developed to estimate the solar panel energy income. We have tested HOLLOWS using have led to the development of a whole new set of applications and multi-tasking system designs

  7. Fire performance of unprotected and protected concrete filled steel hollow structural sections 

    E-Print Network [OSTI]

    Rush, David Ian

    2013-11-28

    Concrete filled steel hollow structural (CFS) sections are increasingly used to support large compressive loads in buildings, with the concrete infill and the steel tube working together to yield several benefits both ...

  8. The Use of Hollow Plastic Balls as Energy Conservation Devices in Heated Open Tanks 

    E-Print Network [OSTI]

    Byrne, T. J.

    1983-01-01

    The problem of heat losses from open liquid filled tanks is as old as industry itself. This paper will present the advantages of using an insulating blanket of hollow plastic spheres as a mechanism to conserve this type ...

  9. Glass Ceiling or Glass Elevator: Are Voters Biased in Favor of Women Candidates in California Elections?

    E-Print Network [OSTI]

    Abney, Ronni Marie; Peterson, Rolfe Daus

    2011-01-01

    10.2202/1944-4370.1103 Abney and Peterson: Glass Ceilingor Glass Elevator Table 7A. Positive Gender Bias ModelAbney and Peterson: Glass Ceiling or Glass Elevator Huddy,

  10. Weihai Blue Star Glass Holding Co Ltd aka Shandong Lanxing Glass...

    Open Energy Info (EERE)

    Blue Star Glass Holding Co Ltd aka Shandong Lanxing Glass Group Co Ltd Jump to: navigation, search Name: Weihai Blue Star Glass Holding Co Ltd (aka Shandong Lanxing Glass Group Co...

  11. Prospects for Integrating a Hollow Electron Lens into the LHC Collimation System

    SciTech Connect (OSTI)

    Smith, Jeffrey Claiborne; /SLAC; Assmann, Ralph; Previtali, Valentina; Shiltsev, Vladimir; Valishev, Alexander; /CERN /Fermilab

    2009-08-03

    It has been proposed to use a hollow electron lens with the LHC beam collimation system [1]. The hollow electron beam would be used as a beam scraper and positioned at a closer sigma than the primary collimators to increase the halo particle diffusion rate striking the primaries. In this paper we use multi-turn beam tracking simulations to analyze the effectiveness of such a lens when integrated into the LHC collimation system.

  12. Environment of deposition of the Permian Lyons Sandstone at Black Hollow Field, Weld County, Colorado 

    E-Print Network [OSTI]

    Frank, David Michael

    1984-01-01

    ENVIRONMENT OF DEPOSITION OF THE PERMIAN LYONS SANDSTONE AT BLACK HOLLOW FIELD, WELD COUNTY, COLORADO A Thesis by DAVID MICHAEL FRANK Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER QF SCIENCE August 1984 Major Subject: Geology ENVIRONMENT OF DEPOSITION OF THE PERMIAN LYONS SANDSTONE AT BLACK HOLLOW FIELD, WELD COUNTY, COLORADO A Thesis by DAVID MICHAEL FRANK Approved as to style and content by: R. R. Berg...

  13. Electronic structure of metallic glasses

    SciTech Connect (OSTI)

    Oelhafen, P.; Lapka, R.; Gubler, U.; Krieg, J.; DasGupta, A.; Guentherodt, H.J.; Mizoguchi, T.; Hague, C.; Kuebler, J.; Nagel, S.R.

    1981-01-01

    This paper is organized in six sections and deals with (1) the glassy transition metal alloys, their d-band structure, the d-band shifts on alloying and their relation to the alloy heat of formation (..delta..H) and the glass forming ability, (2) the glass to crystal phase transition viewed by valence band spectroscopy, (3) band structure calculations, (4) metallic glasses prepared by laser glazing, (5) glassy normal metal alloys, and (6) glassy hydrides.

  14. Method for heating a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.

    1998-07-21

    A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed. 5 figs.

  15. The GLASS CHAIR Edited by Manuel Heitor

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    The GLASS CHAIR Edited by Manuel Heitor IST Press, 2000 #12;Collaborative Design of... The GLASS the glass chair, but also for the numerous discussions on glass production processes. And last · Carmo Valente Chapter 4. GLASS: BEAUTY WITH STRENGTH Sushil Kumar Mendiratta Chapter 5. The IDEA

  16. Method for heating a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI)

    1998-01-01

    A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed.

  17. Color Glass Condensate and Glasma

    E-Print Network [OSTI]

    Francois Gelis

    2010-09-06

    In this talk, I review the Color Glass Condensate theory of gluon saturation, and its application to the early stages of heavy ion collisions.

  18. Controllable synthesis of hollow mesoporous silica spheres and application as support of nano-gold

    SciTech Connect (OSTI)

    Wang, Tao; Ma, Weihua Shangguan, Junnan; Jiang, Wei; Zhong, Qin

    2014-07-01

    Hollow silica spheres with mesoporous structure were synthesized by sol–gel/emulsion method. In the process, the surfactant, cetyltrimethylammonium bromide (CTAB) was used to stabilize the oil droplet and also used as structure direct agent. The diameter of the hollow silica spheres, ranging from 895 nm to 157 nm, can be controlled by changing the ratio of ethanol to water and the concentration of the surfactant as well. The shell thickness of the spheres decreased when the ratio of ethanol to water decreased. The proposed mechanism of the formation of silica spheres could elucidate the experimental results well. Furthermore, the resultant hollow mesoporous silica spheres were then employed as support of nano-gold which was used to catalyze the isomerization reaction of propylene oxide to produce allyl alcohol. - Graphical abstract: It is the schematic mechanism for the formation of hollow mesoporous silica spheres. - Highlights: • The formation mechanism of the hollow spheres is proposed. • The isomerization of propylene oxide can be catalyzed by the nano-gold/SiO{sub 2}. • The hollow silica spheres can be prepared controllably.

  19. Aspects of the mechanics of metallic glasses

    E-Print Network [OSTI]

    Henann, David Lee

    2011-01-01

    Metallic glasses are amorphous materials that possess unique mechanical properties, such as high tensile strengths and good fracture toughnesses. Also, since they are amorphous, metallic glasses exhibit a glass transition, ...

  20. Efficient Breach Theory Through the Looking Glass

    E-Print Network [OSTI]

    Adler, Barry E.

    2007-01-01

    in Wonderland and Through the Looking Glass (Signet 1960).Theory Through the Looking Glass such an award a put by theTheory Through the Looking Glass Consider also the hoary

  1. Glass blowing on a wafer level

    E-Print Network [OSTI]

    Eklund, E. Jesper; Shkel, Andrei M.

    2007-01-01

    Wafer-Level Micro-Glass-Blowing UCI Of?ce of Technology176, 2005. [3] ——, Glass Blowing on a Wafer Scale (Expandedmodels. EKLUND AND SHKEL: GLASS BLOWING ON A WAFER LEVEL [5

  2. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, X.; Johnson, W.L.

    1998-04-07

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  3. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1998-01-01

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  4. Laboratory Waste Disposal HAZARDOUS GLASS

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Laboratory Waste Disposal HAZARDOUS GLASS Items that could cut or puncture skin or trash- can without any treatment. Hazardous Glass and Plastic: Items that can puncture, cut or scratch if disposed a significant hazard. Bags of misc. plasticware that has been autoclaved to remove bio contamination. Syringe

  5. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

    1998-12-08

    A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

  6. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, Carol Maryanne (Aiken, SC); Pickett, John Butler (Aiken, SC); Brown, Kevin George (Augusta, GA); Edwards, Thomas Barry (Aiken, SC)

    1998-01-01

    A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

  7. Refractory Glass Seals for SOFC

    SciTech Connect (OSTI)

    Chou, Y. S.; Stevenson, Jeffry W.

    2011-07-01

    One of the critical challenges facing planar solid oxide fuel cell (SOFC) technology is the need for reliable sealing technology. Seals must exhibit long-term stability and mechanical integrity in the high temperature SOFC environment during normal and transient operation. Several different approaches for sealing SOFC stacks are under development, including glass or glass-ceramic seals, metallic brazes, and compressive seals. Among glass seals, rigid glass-ceramics, self-healing glass, and composite glass approaches have been investigated under the SECA Core Technology Program. The U.S. Department of Energy's Pacific Northwest National Laboratory (PNNL) has developed the refractory glass approach in light of the fact that higher sealing temperatures (e.g., 930-1000 degrees C) may enhance the ultimate in-service bulk strength and electrical conductivity of contact materials, as well as the bonding strength between contact materials and adjacent SOFC components, such as interconnect coatings and electrodes. This report summarizes the thermal, chemical, mechanical, and electrical properties of the refractory sealing glass.

  8. Evaluation of the Thermal Performance for a Wire Mesh/Hollow Glass Microsphere Composite Structure as a Conduction Barrier 

    E-Print Network [OSTI]

    Mckenna, Sean

    2010-01-15

    ]. For instance, application of microsphere insulated pressure vessels for hydrogen storage on vehicles showed good thermal performance [15]. In addition, Mueller [16] in examining cryogenic liquefaction and storage, considered critical in a potential human...

  9. Hollow cylindrical plasma filament waveguide with discontinuous finite thickness cladding

    SciTech Connect (OSTI)

    Alshershby, Mostafa; Hao Zuoqiang; Lin Jingquan

    2013-01-15

    We have explored here a hollow cylindrical laser plasma multifilament waveguide with discontinuous finite thickness cladding, in which the separation between individual filaments is in the range of several millimeters and the waveguide cladding thickness is in the order of the microwave penetration depth. Such parameters give a closer representation of a realistic laser filament waveguide sustained by a long stable propagation of femtosecond (fs) laser pulses. We report how the waveguide losses depend on structural parameters like normalized plasma filament spacing, filament to filament distance or pitch, normal spatial frequency, and radius of the plasma filament. We found that for typical plasma parameters, the proposed waveguide can support guided modes of microwaves in extremely high frequency even with a cladding consisting of only one ring of plasma filaments. The loss of the microwave radiation is mainly caused by tunneling through the discontinuous finite cladding, i.e., confinement loss, and is weakly dependent on the plasma absorption. In addition, the analysis indicates that the propagation loss is fairly large compared with the loss of a plasma waveguide with a continuous infinite thickness cladding, while they are comparable when using a cladding contains more than one ring. Compared to free space propagation, this waveguide still presents a superior microwave transmission to some distance in the order of the filamentation length; thus, the laser plasma filaments waveguide may be a potential channel for transporting pulsed-modulated microwaves if ensuring a long and stable propagation of fs laser pulses.

  10. Ignition and extinction phenomena in helium micro hollow cathode discharges

    SciTech Connect (OSTI)

    Kulsreshath, M. K.; Schwaederle, L.; Dufour, T.; Lefaucheux, P.; Dussart, R.; Overzet, L. J.

    2013-12-28

    Micro hollow cathode discharges (MHCD) were produced using 250??m thick dielectric layer of alumina sandwiched between two nickel electrodes of 8??m thickness. A through cavity at the center of the chip was formed by laser drilling technique. MHCD with a diameter of few hundreds of micrometers allowed us to generate direct current discharges in helium at up to atmospheric pressure. A slowly varying ramped voltage generator was used to study the ignition and the extinction periods of the microdischarges. The analysis was performed by using electrical characterisation of the V-I behaviour and the measurement of He*({sup 3}S{sub 1}) metastable atoms density by tunable diode laser spectroscopy. At the ignition of the microdischarges, 2??s long current peak as high as 24?mA was observed, sometimes followed by low amplitude damped oscillations. At helium pressure above 400?Torr, an oscillatory behaviour of the discharge current was observed just before the extinction of the microdischarges. The same type of instability in the extinction period at high pressure also appeared on the density of He*({sup 3}S{sub 1}) metastable atoms, but delayed by a few ?s relative to the current oscillations. Metastable atoms thus cannot be at the origin of the generation of the observed instabilities.

  11. Lead phosphate glass compositions for optical components

    DOE Patents [OSTI]

    Sales, Brian C. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN)

    1987-01-01

    A lead phosphate glass to which has been added indium oxide or scandium oe to improve chemical durability and provide a lead phosphate glass with good optical properties.

  12. Glass Ceramic Formulation Data Package

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Rodriguez, Carmen P.; McCloy, John S.; Vienna, John D.; Chung, Chul-Woo

    2012-06-17

    A glass ceramic waste form is being developed for treatment of secondary waste streams generated by aqueous reprocessing of commercial used nuclear fuel (Crum et al. 2012b). The waste stream contains a mixture of transition metals, alkali, alkaline earths, and lanthanides, several of which exceed the solubility limits of a single phase borosilicate glass (Crum et al. 2009; Caurant et al. 2007). A multi-phase glass ceramic waste form allows incorporation of insoluble components of the waste by designed crystallization into durable heat tolerant phases. The glass ceramic formulation and processing targets the formation of the following three stable crystalline phases: (1) powellite (XMoO4) where X can be (Ca, Sr, Ba, and/or Ln), (2) oxyapatite Yx,Z(10-x)Si6O26 where Y is alkaline earth, Z is Ln, and (3) lanthanide borosilicate (Ln5BSi2O13). These three phases incorporate the waste components that are above the solubility limit of a single-phase borosilicate glass. The glass ceramic is designed to be a single phase melt, just like a borosilicate glass, and then crystallize upon slow cooling to form the targeted phases. The slow cooling schedule is based on the centerline cooling profile of a 2 foot diameter canister such as the Hanford High-Level Waste canister. Up to this point, crucible testing has been used for glass ceramic development, with cold crucible induction melter (CCIM) targeted as the ultimate processing technology for the waste form. Idaho National Laboratory (INL) will conduct a scaled CCIM test in FY2012 with a glass ceramic to demonstrate the processing behavior. This Data Package documents the laboratory studies of the glass ceramic composition to support the CCIM test. Pacific Northwest National Laboratory (PNNL) measured melt viscosity, electrical conductivity, and crystallization behavior upon cooling to identify a processing window (temperature range) for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form.

  13. A Topological Glass

    E-Print Network [OSTI]

    Jean-Pierre Eckmann

    2007-04-07

    We propose and study a model with glassy behavior. The state space of the model is given by all triangulations of a sphere with $n$ nodes, half of which are red and half are blue. Red nodes want to have 5 neighbors while blue ones want 7. Energies of nodes with different numbers of neighbors are supposed to be positive. The dynamics is that of flipping the diagonal of two adjacent triangles, with a temperature dependent probability. We show that this system has an approach to a steady state which is exponentially slow, and show that the stationary state is unordered. We also study the local energy landscape and show that it has the hierarchical structure known from spin glasses. Finally, we show that the evolution can be described as that of a rarefied gas with spontaneous generation of particles and annihilating collisions.

  14. Domain walls in gapped graphene

    E-Print Network [OSTI]

    Semenoff, G W; Zhou, Fei

    2015-01-01

    The electronic properties of a particular class of domain walls in gapped graphene are investigated. We show that they can support mid-gap states which are localized in the vicinity of the domain wall and propagate along its length. With a finite density of domain walls, these states can alter the electronic properties of gapped graphene significantly. If the mid-gap band is partially filled,the domain wall can behave like a one-dimensional metal embedded in a semi-conductor, and could potentially be used as a single-channel quantum wire.

  15. Domain walls in gapped graphene

    E-Print Network [OSTI]

    G. W. Semenoff; V. Semenoff; Fei Zhou

    2008-05-31

    The electronic properties of a particular class of domain walls in gapped graphene are investigated. We show that they can support mid-gap states which are localized in the vicinity of the domain wall and propagate along its length. With a finite density of domain walls, these states can alter the electronic properties of gapped graphene significantly. If the mid-gap band is partially filled,the domain wall can behave like a one-dimensional metal embedded in a semi-conductor, and could potentially be used as a single-channel quantum wire.

  16. Liquid Walls Innovative Concepts for First Walls and Blankets

    E-Print Network [OSTI]

    California at Los Angeles, University of

    for an attractive fusion energy system 2. Lower the cost and time for R&D · APEX was initiated in November 1997Liquid Walls Innovative Concepts for First Walls and Blankets Mohamed Abdou Professor, Mechanical as part of the US Restructured Fusion Program Strategy to enhance innovation · Natural Questions

  17. Reinforced glass beamsReinforced glass beamsg Auteur Dr. Christian LOUTER 1

    E-Print Network [OSTI]

    Reinforced glass beamsReinforced glass beamsg EDCE Auteur Dr. Christian LOUTER 1 ENAC/EDCE 2011In contemporary architecture glass is increasinglyIn contemporary architecture glass is increasingly applied for structural components such as beamsapplied for structural components such as beams. However glass

  18. Oven wall panel construction

    DOE Patents [OSTI]

    Ellison, Kenneth (20 Avondale Cres., Markham, CA); Whike, Alan S. (R.R. #1, Caledon East, both of Ontario, CA)

    1980-04-22

    An oven roof or wall is formed from modular panels, each of which comprises an inner fabric and an outer fabric. Each such fabric is formed with an angle iron framework and somewhat resilient tie-bars or welded at their ends to flanges of the angle irons to maintain the inner and outer frameworks in spaced disposition while minimizing heat transfer by conduction and permitting some degree of relative movement on expansion and contraction of the module components. Suitable thermal insulation is provided within the module. Panels or skins are secured to the fabric frameworks and each such skin is secured to a framework and projects laterally so as slidingly to overlie the adjacent frame member of an adjacent panel in turn to permit relative movement during expansion and contraction.

  19. HYDROGEN-BASED, HOLLOW-FIBER MEMBRANE BIOFILM REACTOR FOR REDUCTION OF PERCHLORATE AND OTHER OXIDIZED CONTAMINANTS

    E-Print Network [OSTI]

    Nerenberg, Robert

    HYDROGEN-BASED, HOLLOW-FIBER MEMBRANE BIOFILM REACTOR FOR REDUCTION OF PERCHLORATE AND OTHER be added. Hydrogen is an ideal electron donor, as it is non-toxic, inexpensive, and sparsely soluble. We tested a hydrogen-based, hollow-fiber membrane biofilm reactor (MBfR) for reduction of perchlorate

  20. Evolution of Hollow TiO2 Nanostructures via the Kirkendall Effect Driven by Cation Exchange with Enhanced Photoelectrochemical

    E-Print Network [OSTI]

    Wang, Xudong

    . The evolution of TiO2 nanotubes from ZnO NW scaffolds was seamlessly integrated with TiO2 NR branch growthEvolution of Hollow TiO2 Nanostructures via the Kirkendall Effect Driven by Cation Exchange. In this paper, we report a discovery of hollow TiO2 nanostructure evolution in a vapor-solid deposition system

  1. J. Adv. Model. Earth Syst., Vol. 2, Art. #8, 19 pp. Adiabatic Rearrangement of Hollow PV Towers

    E-Print Network [OSTI]

    Schubert, Wayne H.

    J. Adv. Model. Earth Syst., Vol. 2, Art. #8, 19 pp. Adiabatic Rearrangement of Hollow PV Towers potential vorticity (PV). is structure has been referred to as a hollow PV tower. e sign reversal of the radial gradient of PV satis es the Charney-Stern necessary condition for combined barotropic

  2. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. The problems might include arching or ratholing in the silo/hopper. In addition, all of the blends may require consideration for their handling.

  3. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. In addition, all of the blends may require consideration for their handling. A number of engineering considerations and recommendations were prepared based on the experimental findings, experience, and other process considerations. Recommendations for future testing are included. In conjunction with future work, it is recommended that a professional consultant be engaged to guide and assist with testing and design input.

  4. Simulation of Hollow Electron Beam Collimation in the Fermilab Tevatron Collider

    SciTech Connect (OSTI)

    Morozov, I.A.; Stancari, G.; Valishev, A.; Shatilov, D.N.; /Novosibirsk, IYF

    2012-05-01

    The concept of augmenting the conventional collimation system of high-energy storage rings with a hollow electron beam was successfully demonstrated in experiments at the Tevatron. A reliable numerical model is required for understanding particle dynamics in the presence of a hollow beam collimator. Several models were developed to describe imperfections of the electron beam profile and alignment. The features of the imperfections are estimated from electron beam profile measurements. Numerical simulations of halo removal rates are compared with experimental data taken at the Tevatron.

  5. Fuel cell components and systems having carbon-containing electrically-conductive hollow fibers

    DOE Patents [OSTI]

    Langry, Kevin C; Farmer, Joseph C

    2015-04-28

    A method, according to one embodiment, includes acquiring a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst along one side thereof, adding an anode that extends along at least part of a length of the structure, and adding a cathode that extends along at least part of the length of the structure, the cathode being on an opposite side of the hollow fiber as the anode.

  6. Moisture Research - Optimizing Wall Assemblies

    SciTech Connect (OSTI)

    Arena, L.; Mantha, P.

    2013-05-01

    The Consortium for Advanced Residential Buildings (CARB) evaluated several different configurations of wall assemblies to determine the accuracy of moisture modeling and make recommendations to ensure durable, efficient assemblies. WUFI and THERM were used to model the hygrothermal and heat transfer characteristics of these walls.

  7. HIGH-LEVEL WASTE GLASS FORMULATION MODEL SENSITIVITY STUDY 2009 GLASS FORMULATION MODEL VERSUS 1996 GLASS FORMULATION MODEL

    SciTech Connect (OSTI)

    BELSHER JD; MEINERT FL

    2009-12-07

    This document presents the differences between two HLW glass formulation models (GFM): The 1996 GFM and 2009 GFM. A glass formulation model is a collection of glass property correlations and associated limits, as well as model validity and solubility constraints; it uses the pretreated HLW feed composition to predict the amount and composition of glass forming additives necessary to produce acceptable HLW glass. The 2009 GFM presented in this report was constructed as a nonlinear optimization calculation based on updated glass property data and solubility limits described in PNNL-18501 (2009). Key mission drivers such as the total mass of HLW glass and waste oxide loading are compared between the two glass formulation models. In addition, a sensitivity study was performed within the 2009 GFM to determine the effect of relaxing various constraints on the predicted mass of the HLW glass.

  8. Introduction and Motivation Structural Model for Laminated Glass Beams Conclusions and Outlook of Laminated Glass Structures

    E-Print Network [OSTI]

    Introduction and Motivation Structural Model for Laminated Glass Beams Conclusions and Outlook 1 #12;Introduction and Motivation Structural Model for Laminated Glass Beams Conclusions and Outlook Outline 1 Introduction and Motivation 2 Structural Model for Laminated Glass Beams 3 Conclusions

  9. The Pair Interaction of Charged Colloidal Spheres near a Charged Wall Sven H. Behrens and David G. Grier

    E-Print Network [OSTI]

    Grier, David

    spheres (#27; = 1:58 #22;m, catalog # 8150, Duke Scienti#12;c, Palo Alto, CA) dispersed in deionized water water are expected to repel each other, an unexplained long-range attraction has consistently been that polystyrene spheres dispersed in deionized water and closely con#12;ned between parallel glass walls

  10. Organic solar cells using few-walled carbon nanotubes electrode controlled by the balance between sheet resistance and the transparency

    E-Print Network [OSTI]

    Liu, Jie

    Technology, Hokuryo-cho, Matsue, Shimane 690-0816, Japan Received 6 January 2009; accepted 24 February 2009 to easy solution-processing fabrication and high flexibility. Single-walled CNTs SWNT films on glass or poly ethylene terephthalate PET were investigated.2,3 Theoretically the work function of SWNT 4.8­5.0 e

  11. Building wall construction

    SciTech Connect (OSTI)

    Mulford, C.E.

    1987-04-21

    A building wall construction is described comprising, in combination: (a) an elongated top plate; (b) an elongated bottom plate extending in spaced, horizontal, parallel relation to the top plate; (c) elongated studs arranged in spaced, vertical, parallel relation and affixed at their upper and lower ends to the top and bottom plates, respectively; (d) each of the studs, top plates and bottom plates comprises a pair of spaced wooden members of equal length having a substantially rectangular groove centrally disposed in one face thereof extending for the entire length of the wooden members, and at least one web member of fire-rated gypsum board having opposite, marginal edge portions secured in the grooves; (e) sheathing layers affixed to both sides of the stud members and extending vertically between the bottom and top plates, and horizontally between the studs to enclose the space therebetween; and (f) at least one panel member of fire-rated gypsum board extending horizontally between each successive pair of studs parallel to and spaced from each of the sheathing layers, thus providing at least two, separated spaces between the sheathing layers.

  12. Nano-structured self-cleaning superhydrophobic glass

    E-Print Network [OSTI]

    Kim, Jin Yeol

    2010-01-01

    5. Optically transparent glass with vertically alignedcomposition of biosoluble glass fiber” Korean ApplicationS. Jin, “Optically Transparent Glass with Vertically Aligned

  13. Micro-Continuum Modeling of Nuclear Waste Glass Corrosion

    E-Print Network [OSTI]

    Steefel, Carl

    2014-01-01

    21. Grambow, B. (2006). Nuclear waste glasses – How durable?Continuum Modeling of Nuclear Waste Glass Corrosion AugustContinuum Modeling of Nuclear Waste Glass Corrosion Prepared

  14. Investigation of Glass Transition Temperature of Binary Tellurite Glasses

    SciTech Connect (OSTI)

    Chippy, L.; Unnithan, C. Harikuttan [Solid State Physics Laboratory, D.B. College, Sasthamcotta, Kollam, Kerala-690 521 (India); Jayakumar, S. [MSM College, Kayamkulam, Kerala (India)

    2011-10-20

    Five series of binary Tellurite glass samples containing Sb{sub 2}O{sub 4}, WO{sub 3}, Fe{sub 2}O{sub 3}, Na{sub 2}O and ZnO{sub 2} are studied in terms of the variation of glass transition temperature (T{sub g}). It is seen that Tg increases as Tellurite concentration decreases in the case of glasses containing metal oxides Sb{sub 2}O{sub 4} WO{sub 3}, and Fe{sub 2}O{sub 3} while T{sub g} shows a decreasing trend with that of Na{sub 2}O and ZnO and the corresponding changes in the network structure are accounted to possible extent. The structural variations are analyzed using the concept of electronegativity.

  15. Hollow-waveguide delivery systems for high-power, industrial CO2 lasers

    E-Print Network [OSTI]

    Hollow-waveguide delivery systems for high-power, industrial CO2 lasers Ricky K. Nubling and James to deliver CO2 laser power for industrial laser applications. The transmission, bending loss, and output, beam delivery, industrial lasers, power delivery, CO2 lasers. r 1996 Optical Society of America 1

  16. Marrying Organic-Inorganic Hybrid Materials with Polymeric Hollow Fibers for Applications in Catalysis and Adsorptive

    E-Print Network [OSTI]

    Lin, Qiao

    scale CO2 capture,6-9 enabling CO2 capture, utilization and storage (CCUS), as well as the first use(ethyleneimine) into Polymer/Silica Hollow Fiber Sorbents for Carbon Dioxide Capture." Y. Labreche, R. P. Lively, F. Rezaei, G Capture from Simulated Flue Gas and Ambient Air using Mesoporous Silica Grafted Amines." M. Alkhabbaz et

  17. Geometrical Aspects of a Hollow-Cathode Magnetron (HCM) Zhehui Wang and Samuel A. Cohen

    E-Print Network [OSTI]

    -sputtering-magnetron (PSM) cathode with a hollow-cathode structure (HCS), see FIG. 1. The HCS is a right cylinder characterized by its length L and inner diameter D. A conventional PSM can be regarded as an extreme of a HCM volume is generated within the HCM than in its PSM counterpart. This feature may allow HCM plasmas

  18. High-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature,

    E-Print Network [OSTI]

    Cui, Yi

    capacity of 849 and 610 mAh/g at 2C and 4C, respectively. lithium sulfur battery | energy storage | long energy storage (1­4). To achieve a quantum leap in the batteries specific energy density, new electrodeHigh-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature

  19. Laser induced fluorescence of the ferroelectric plasma source assisted hollow anode discharge

    E-Print Network [OSTI]

    the plasma sources described in Refs. 4 and 11­13, where either thermionic cathode or magnetron or arc plasmaLaser induced fluorescence of the ferroelectric plasma source assisted hollow anode discharge V online 20 November 2009 Parameters of the plasma produced by a ferroelectric plasma source FPS assisted

  20. BIOENGINEERING, FOOD, AND NATURAL PRODUCTS Gas Permeance Measurement of Hollow Fiber

    E-Print Network [OSTI]

    Federspiel, William J.

    BIOENGINEERING, FOOD, AND NATURAL PRODUCTS Gas Permeance Measurement of Hollow Fiber Membranes in Gas-Liquid Environment Laura W. Lund McGowan Institute for Regenerative Medicine, Dept in a gas-liquid en®ironment. The gas-liquid permeance measurements were compared with measurements made

  1. Ionic liquid assisted hydrothermal fabrication of hierarchically organized ?-AlOOH hollow sphere

    SciTech Connect (OSTI)

    Tang, Zhe; Liu, Yunqi; Li, Guangci; Hu, Xiaofu; Liu, Chenguang

    2012-11-15

    Highlights: ? The ?-AlOOH hollow spheres were synthesized via an ionic liquid-assisted hydrothermal treatment. ? Ionic liquid plays an important role in the morphology of the product. ? Ionic liquid can be easily removed from the product and reused in next experiment. ? A “aggregation–solution–recrystallization” formation mechanism may occur in the system. -- Abstract: Hierarchically organized ?-AlOOH hollow spheres with nanoflake-like porous surface texture have been successfully synthesized via an ionic liquid-assisted hydrothermal synthesis method in citric acid monohydrate (CAMs). It was found that ionic liquid [bmim]{sup +}Cl{sup ?} played an important role in the morphology of the product due to its strong interactions with reaction particles. The samples were characterized by X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscope (SEM) and Transmission Electron Microscopy (TEM). The results show that the product has narrow particle size distribution (500–900 nm particle diameter range), high specific surface area (240.5 m{sup 2}/g) and large pore volume (0.61 cm{sup 3}/g). The corresponding ?-Al{sub 2}O{sub 3} hollow spheres can be obtained by calcining it at 550 °C for 3 h. The proposed formation mechanism and other influencing factors of the ?-AlOOH hollow sphere material, such as reaction temperature, reaction duration, CAMs and urea, have also been investigated.

  2. Consecutive solvent evaporation and co-rolling techniques for polymer multilayer hollow fiber preform fabrication

    E-Print Network [OSTI]

    Skorobogatiy, Maksim

    Consecutive solvent evaporation and co-rolling techniques for polymer multilayer hollow fiber photonic fiber preforms were fabricated using consecutive deposition from a solvent phase of two polymers process involved consecutive film deposition by solvent evaporation of polymer solutions on the inside

  3. Hetero-Epitaxial Anion Exchange Yields Single-Crystalline Hollow Nanoparticles

    SciTech Connect (OSTI)

    Park, Jungwon; Zheng, Haimei; Jun, Young-wook; Alivisatos, A. Paul

    2009-08-26

    Anion exchange with S was performed on ZnO colloidal nanoparticles. The resulting hollow ZnS nanoparticles are crystal whose shape is dictated by the initial ZnO. Crystallographic and elemental analyses provide insight into the mechanism of the anion exchange.

  4. Nickel-mediated polyol synthesis of hierarchical V2O5 hollow microspheres with enhanced lithium

    E-Print Network [OSTI]

    Cao, Guozhong

    Nickel-mediated polyol synthesis of hierarchical V2O5 hollow microspheres with enhanced lithium microspheres has been developed, based on a nickel-mediated polyol process and subsequent calcinations, such as one-dimensional structures (nanowires, nanorods, and nanotubes),21­23 nanosheets,5 and nanobers12

  5. Cellular metal lattices with hollow trusses Douglas T. Queheillalt *, Haydn N.G. Wadley

    E-Print Network [OSTI]

    Wadley, Haydn

    Cellular metal lattices with hollow trusses Douglas T. Queheillalt *, Haydn N.G. Wadley Department; accepted 21 September 2004 Available online 22 October 2004 Abstract Cellular metal lattice truss to buckling offsetting the usually rapid drop in strength as the relative density decreases in cellular

  6. Fuel cell components and systems having carbon-containing electrically-conductive hollow fibers

    DOE Patents [OSTI]

    Langry, Kevin C.; Farmer, Joseph C.

    2014-07-08

    According to one embodiment, a system includes a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst coupled to the hollow fiber, an anode extending along at least part of a length of the structure, and a cathode extending along at least part of the length of the structure, the cathode being on an opposite side of the hollow fiber as the anode. In another embodiment, a method includes acquiring a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst along one side thereof, adding an anode that extends along at least part of a length of the structure, and adding a cathode that extends along at least part of the length of the structure on an opposite side as the anode.

  7. HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses

    SciTech Connect (OSTI)

    Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

    2012-04-02

    In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Matyáš et al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

  8. Fabrication of hollow mesoporous NiO hexagonal microspheres via hydrothermal process in ionic liquid

    SciTech Connect (OSTI)

    Zhao, Jinbo; School of Materials Science and Engineering, Shandong University, 250061, Jinan ; Wu, Lili; School of Materials Science and Engineering, Shandong University, 250061, Jinan ; Zou, Ke; School of Materials Science and Engineering, Shandong University, 250061, Jinan

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Ni(OH){sub 2} precursors were synthesized in ionic liquid and water solution by hydrothermal method. Black-Right-Pointing-Pointer NiO hollow microspheres were prepared by thermal treatment of Ni(OH){sub 2} precursors. Black-Right-Pointing-Pointer NiO hollow microspheres were self-assembled by mesoporous cubic and hexagonal nanocrystals with high specific surface area. Black-Right-Pointing-Pointer The mesoporous structure is stable at 773 K. Black-Right-Pointing-Pointer The ionic liquid absorbed on the O-terminate surface of the crystals to form hydrogen bond and played key roles in determining the final shape of the NiO novel microstructure. -- Abstract: The novel NiO hexagonal hollow microspheres have been successfully prepared by annealing Ni(OH){sub 2}, which was synthesized via an ionic liquid-assisted hydrothermal method. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), N{sub 2} adsorption-desorption and Fourier transform infrared spectrometer (FTIR). The results show that the hollow NiO microstructures are self-organized by mesoporous cubic and hexagonal nanocrystals. The mesoporous structure possessed good thermal stability and high specific surface area (ca. 83 m{sup 2}/g). The ionic liquid 1-butyl-3methylimidazolium tetrafluoroborate ([Bmim][BF{sub 4}]) was found to play a key role in controlling the morphology of NiO microstructures during the hydrothermal process. The special hollow mesoporous architectures will have potential applications in many fields, such as catalysts, absorbents, sensors, drug-delivery carriers, acoustic insulators and supercapacitors.

  9. Experimental study of magnetically confined hollow electron beams in the Tevatron as collimators for intense high-energy hadron beams

    SciTech Connect (OSTI)

    Stancari, G.; Annala, G.; Shiltsev, V.; Still, D.; Valishev, A.; Vorobiev, L.; /Fermilab

    2011-03-01

    Magnetically confined hollow electron beams for controlled halo removal in high-energy colliders such as the Tevatron or the LHC may extend traditional collimation systems beyond the intensity limits imposed by tolerable losses. They may also improve collimation performance by suppressing loss spikes due to beam jitter and by increasing capture efficiency. A hollow electron gun was designed and tested at Fermilab for this purpose. It was installed in one of the Tevatron electron lenses in the summer of 2010. We present the results of the first experimental tests of the hollow-beam collimation concept on 980-GeV antiproton bunches in the Tevatron.

  10. Additive Manufacturing of Optically Transparent Glass

    E-Print Network [OSTI]

    Klein, John

    We present a fully functional material extrusion printer for optically transparent glass. The printer is composed of scalable modular elements able to operate at the high temperatures required to process glass from a molten ...

  11. The Huge, Blue, Jesus Glass Statue

    E-Print Network [OSTI]

    Robbins, Joanna

    2013-01-01

    Later, I found a huge, blue, glass statue of Jesus stuffedOF CALIFORNIA RIVERSIDE The Huge, Blue, Jesus Glass Statue Aeyes as RED And wrote down BLUE for your hair. I had to fix

  12. Structure glass technology : systems and applications

    E-Print Network [OSTI]

    Leitch, Katherine K. (Katherine Kristen)

    2005-01-01

    Glass cannot compete with steel in terms of strength or durability, but it is the only structural material that offers the highly sought after qualities of translucency and transparency. The use of glass has evolved from ...

  13. EFFECT OF GLASS-BATCH MAKEUP ON...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rate of heat-transfer from molten glass to the batch blanket and the kinetics of various chemical reactions and phase transitions jointly control the batch- to-glass conversion...

  14. Glass Transition and the Coulomb Gap in Electron Glasses M. Muller and L. B. Ioffe

    E-Print Network [OSTI]

    Müller, Markus

    Glass Transition and the Coulomb Gap in Electron Glasses M. Mu¨ller and L. B. Ioffe Department December 2004) We establish the connection between the presence of a glass phase and the appearance correlations in a systematic way, we show that in the case of strong disorder a continuous glass transition

  15. Heating-induced glass-glass and glass-liquid transformations in computer simulations of water

    SciTech Connect (OSTI)

    Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

    2014-03-21

    Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

  16. Thermal healing of realistic flaws in glass

    E-Print Network [OSTI]

    Zaccaria, Marco; Overend, Mauro

    2015-01-01

    in glass plates.â?ť Proc. Glass processing days, Tampere, Finland. 447 Anunmana, C., Anusavice, K. J., Mecholsky, J.J., (2009). â??Residual stress in glass: 448 indentation crack and fractography approaches.â?ť Dent.Mater., 40(11), 1453-1458. 449 ASTM...

  17. Do cathedral glasses flow? Edgar Dutra Zanottoa)

    E-Print Network [OSTI]

    Levi, Anthony F. J.

    simple concepts of physics to demonstrate that typical window glasses, which contain K2O­Na2O­CaO­MgO­Al2 for glass to flow and deform at ordinary temperatures, using calculated viscosity curves for several modern of Physics Teachers. I. INTRODUCTION Is glass a liquid or is it not? While teaching materials science

  18. Understanding the dynamics of photoionization-induced nonlinear effects and solitons in gas-filled hollow-core photonic crystal fibers

    SciTech Connect (OSTI)

    Saleh, Mohammed F.; Biancalana, Fabio

    2011-12-15

    We present the details of our previously formulated model [Saleh et al., Phys. Rev. Lett. 107, 203902 (2011)] that governs pulse propagation in hollow-core photonic crystal fibers filled by an ionizable gas. By using perturbative methods, we find that the photoionization process induces the opposite phenomenon of the well-known Raman self-frequency redshift of solitons in solid-core glass fibers, as was recently experimentally demonstrated [Hoelzer et al., Phys. Rev. Lett. 107, 203901 (2011)]. This process is only limited by ionization losses, and leads to a constant acceleration of solitons in the time domain with a continuous blueshift in the frequency domain. By applying the Gagnon-Belanger gauge transformation, multipeak ''inverted gravitylike'' solitary waves are predicted. We also demonstrate that the pulse dynamics shows the ejection of solitons during propagation in such fibers, analogous to what happens in conventional solid-core fibers. Moreover, unconventional long-range nonlocal interactions between temporally distant solitons, unique of gas plasma systems, are predicted and studied. Finally, the effects of higher-order dispersion coefficients and the shock operator on the pulse dynamics are investigated, showing that the conversion efficiency of resonant radiation into the deep UV can be improved via plasma formation.

  19. Turbine airfoil with outer wall thickness indicators

    DOE Patents [OSTI]

    Marra, John J; James, Allister W; Merrill, Gary B

    2013-08-06

    A turbine airfoil usable in a turbine engine and including a depth indicator for determining outer wall blade thickness. The airfoil may include an outer wall having a plurality of grooves in the outer surface of the outer wall. The grooves may have a depth that represents a desired outer surface and wall thickness of the outer wall. The material forming an outer surface of the outer wall may be removed to be flush with an innermost point in each groove, thereby reducing the wall thickness and increasing efficiency. The plurality of grooves may be positioned in a radially outer region of the airfoil proximate to the tip.

  20. Effective Supergravity for Supergravity Domain Walls

    E-Print Network [OSTI]

    M. Cvetic; N. D. Lambert

    2002-05-23

    We discuss the low energy effective action for the Bosonic and Fermionic zero-modes of a smooth BPS Randall-Sundrum domain wall, including the induced supergravity on the wall. The result is a pure supergravity in one lower dimension. In particular, and in contrast to non-gravitational domain walls or domain walls in a compact space, the zero-modes representing transverse fluctuations of domain wall have vanishing action.

  1. Green Wall Technologies Objective: Compile a comprehensive and up-to-date assessment of green wall

    E-Print Network [OSTI]

    Wolberg, George

    Green Wall Technologies Objective: Compile a comprehensive and up-to-date assessment of green wall technologies that can be used to jump-start design and engineering proposals for green walls in a variety of urban conditions. Background: Green walls--otherwise referred to as living walls or biowalls

  2. Glass needs for a growing photovoltaics industry

    SciTech Connect (OSTI)

    Burrows, Keith; Fthenakis, Vasilis

    2015-01-01

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industry’s projected needs, to do so will require advance planning and substantial investments.

  3. Glass needs for a growing photovoltaics industry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burrows, Keith; Fthenakis, Vasilis

    2014-10-18

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industry’s projected needs, to do so will require advance planning and substantialmore »investments.« less

  4. Glass needs for a growing photovoltaics industry

    SciTech Connect (OSTI)

    Burrows, Keith; Fthenakis, Vasilis

    2014-10-18

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industry’s projected needs, to do so will require advance planning and substantial investments.

  5. Characterization of Savannah River Plant waste glass

    SciTech Connect (OSTI)

    Plodinec, M J

    1985-01-01

    The objective of the glass characterization programs at the Savannah River Laboratory (SRL) is to ensure that glass containing Savannah River Plant high-level waste can be permanently stored in a federal repository, in an environmentally acceptable manner. To accomplish this objective, SRL is carrying out several experimental programs, including: fundamental studies of the reactions between waste glass and water, particularly repository groundwater; experiments in which candidate repository environments are simulated as accurately as possible; burial tests of simulated waste glass in candidate repository geologies; large-scale tests of glass durability; and determination of the effects of process conditions on glass quality. In this paper, the strategy and current status of each of these programs is discussed. The results indicate that waste packages containing SRP waste glass will satisfy emerging regulatory criteria.

  6. Recirculation bubbler for glass melter apparatus

    DOE Patents [OSTI]

    Guerrero, Hector (Evans, GA); Bickford, Dennis (Folly Beach, SC)

    2007-06-05

    A gas bubbler device provides enhanced recirculation of molten glass within a glass melter apparatus. The bubbler device includes a tube member disposed within a pool of molten glass contained in the melter. The tube member includes a lower opening through which the molten glass enters and upper slots disposed close to (above or below) the upper surface of the pool of molten glass and from which the glass exits. A gas (air) line is disposed within the tube member and extends longitudinally thereof. A gas bubble distribution device, which is located adjacent to the lower end of the tube member and is connected to the lower end of the gas line, releases gas through openings therein so as to produce gas bubbles of a desired size in the molten glass and in a distributed pattern across the tube member.

  7. Pressurized heat treatment of glass ceramic

    DOE Patents [OSTI]

    Kramer, D.P.

    1984-04-19

    A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

  8. Beam loading in a laser-plasma accelerator using a near-hollow plasma channel

    SciTech Connect (OSTI)

    Schroeder, C. B.; Benedetti, C.; Esarey, E.; Leemans, W. P.

    2013-12-15

    Beam loading in laser-plasma accelerators using a near-hollow plasma channel is examined in the linear wake regime. It is shown that, by properly shaping and phasing the witness particle beam, high-gradient acceleration can be achieved with high-efficiency, and without induced energy spread or emittance growth. Both electron and positron beams can be accelerated in this plasma channel geometry. Matched propagation of electron beams can be achieved by the focusing force provided by the channel density. For positron beams, matched propagation can be achieved in a hollow plasma channel with external focusing. The efficiency of energy transfer from the wake to a witness beam is calculated for single ultra-short bunches and bunch trains.

  9. Thermal breaking systems for metal stud walls -- Can metal stud walls perform as well as wood stud walls

    SciTech Connect (OSTI)

    Kosny, J.; Christian, J.E.; Desjarlais, A.O. [Oak Ridge National Lab., TN (United States). Buildings Technology Center

    1997-12-31

    Metal stud wall systems for residential buildings are gaining in popularity. Strong thermal bridges caused by highly conductive metal studs degrade the thermal performance of such walls. Several wall configurations have been developed to improve their thermal performance. The authors tried to evaluate some of these wall systems. The thermal performance of metal stud walls is frequently compared with that of wood stud walls. A reduction of the in-cavity R-value caused by the wood studs is about 10% in wood stud walls. In metal stud walls, thermal bridges generated by the metal components reduce their thermal performance by up to 55%. Today, metal stud walls are believed to be considerably less thermally effective than similar systems made of wood because steel has much higher thermal conductivity than wood. Relatively high R-values may be achieved by installing insulating sheathing, which is now widely recommended as the remedy for weak thermal performance of metal stud walls. A series of promising metal stud wall configurations was analyzed. Some of these walls were designed and tested by the authors, some were tested in other laboratories, and some were developed and forgotten a long time ago. Several types of thermal breaking systems were used in these walls. Two- and three-dimensional finite-difference computer simulations were used to analyze 20 metal stud wall configurations. Also, a series of hot-box tests were conducted on several of these walls. Test results for 22 additional metal stud walls were analyzed. Most of these walls contained conventional metal studs. Commonly used fiberglass and EPS were used as insulation materials. The most promising metal stud wall configurations have reductions in the center-of-cavity R-values of less than 20%.

  10. Energy Saving Method of Manufacturing Ceramic Products from Fiber Glass Waste

    SciTech Connect (OSTI)

    Michael J. Haun

    2005-07-15

    The U.S. fiber glass industry disposes of more than 260,000 tons of industrial fiber glass waste in landfills annually. New technology is needed to reprocess this industrial waste into useful products. A low-cost energy-saving method of manufacturing ceramic tile from fiber glass waste was developed. The technology is based on sintering fiber glass waste at 700-900 degrees C to produce products which traditionally require firing temperatures of >1200 degrees C, or glass-melting temperatures >1500 degrees C. The process also eliminates other energy intensive processing steps, including mining and transportation of raw materials, spray-drying to produce granulated powder, drying pressed tile, and glazing. The technology completely transforms fiber glass waste into a dense ceramic product, so that all future environmental problems in the handling and disposal of the fibers is eliminated. The processing steps were developed and optimized to produce glossy and matte surface finishes for wall and floor tile applications. High-quality prototype tile samples were processed for demonstration and tile standards testing. A Market Assessment confirmed the market potential for tile products produced by the technology. Manufacturing equipment trials were successfully conducted for each step of the process. An industrial demonstration plant was designed, including equipment and operating cost analysis. A fiber glass manufacturer was selected as an industrial partner to commercialize the technology. A technology development and licensing agreement was completed with the industrial partner. Haun labs will continue working to transfer the technology and assist the industrial partner with commercialization beyond the DOE project.

  11. Hollow cathode theory and experiment. II. A two-dimensional theoretical model of the emitter region

    SciTech Connect (OSTI)

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.

    2005-12-01

    Despite their long history and wide range of applicability that includes electric propulsion, detailed understanding of the driving physics inside orificed hollow cathodes remains elusive. The theoretical complexity associated with the multicomponent fluid inside the cathode, and the difficulty of accessing empirically this region, have limited our ability to design cathodes that perform better and last longer. A two-dimensional axisymmetric theoretical model of the multispecies fluid inside an orificed hollow cathode is presented. The level of detail attained by the model is allowed by its extended system of governing equations not solved for in the past within the hollow cathode. Such detail is motivated in part by the need to quantify the effect(s) of the plasma on the emitter life, and by the need to build the foundation for future modeling that will assess erosion of the keeper plate. Results from numerical simulations of a 1.2-cm-diam cathode operating at a discharge current of 25 A and a gas flow rate of 5 SCCM show that approximately 10 A of electron current, and 3.45 A of ion current return back to the emitter surface. The total emitted electron current is 33.8 A and the peak emitter temperature is found to be 1440 K. Comparisons with the measurements suggest that anomalous heating of the plasma is possible near the orifice region. The model predicts heavy species temperatures as high as 2034 K and peak voltage drops near the emitting surface not exceeding 8 V.

  12. Surfactant-assisted solvothermal preparation of submicrometer-sized hollow hematite particles and their photocatalytic activity

    SciTech Connect (OSTI)

    Lian Suoyuan [Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China); Department of Materials Science and Engineering, Dalian Institute of Light Industry, Dalian 116034 (China); Wang Enbo [Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China)]. E-mail: wangenbo@public.cc.jl.cn; Gao Lei [Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China); Wu Di [Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China); Song Yanli [Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China); Xu Lin [Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China)

    2006-06-15

    Submicrometer-sized hollow hematite particles were prepared through a surfactant-assisted solvothermal process. The amount of FeCl{sub 3}.H{sub 2}O and cetyltrimethylammonium bromide, and the acidity of the solution were systematically altered to study their effects on the final results. Hollow hematite particles with shapes from sphere, ellipsoid to peanut were obtained. Their sizes range from 500 nm to 2 {mu}m with shell thickness from 100 to 500 nm. Powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy and selected area electron diffraction were applied to investigate the products' crystallinity, purity, morphology, size and structural features. Finally, the study on the photocatalysis of Fe{sub 2}O{sub 3} for the destruction of diethyl phthalate in water was carried out. The result proved that Fe{sub 2}O{sub 3} hollow particles were effective photocatalysts for the degradation of DEP, with 96.8% destruction ratio being obtained within 60 min.

  13. Melter Glass Removal and Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-31

    The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

  14. Color Glass Condensate and Glasma

    E-Print Network [OSTI]

    F. Gelis

    2012-11-26

    We review the Color Glass Condensate effective theory, that describes the gluon content of a high energy hadron or nucleus, in the saturation regime. The emphasis is put on applications to high energy heavy ion collisions. After describing initial state factorization, we discuss the Glasma phase, that precedes the formation of an equilibrated quark-gluon plasma. We end this review with a presentation of recent developments in the study of the isotropization and thermalization of the quark-gluon plasma.

  15. Steel-framed buildings: Impacts of wall detail configurations on the whole wall thermal performance

    SciTech Connect (OSTI)

    Kosny, J.; Desjarlais, A.O.; Christian, J.E.

    1998-06-01

    The main objective of this paper is the influence of architectural wall details on the whole wall thermal performance. Whole wall thermal performance analysis was performed for six light gage steel-framed wall systems (some with wood components). For each wall system, all wall details were simulated using calibrated 3-D finite difference computer modeling. The thermal performance of the six steel-framed wall systems included various system details and the whole wall system thermal performance for a typical single-story ranch house. Currently, predicted heat losses through building walls are typically based on measurements of the wall system clear wall area using test methods such as ASTM C 236 or are calculated by one of the procedures recommended in the ASHRAE Handbook of Fundamentals that often is carried out for the clear wall area exclusively. In this paper, clear wall area is defined as the part of the wall system that is free of thermal anomalies due to building envelope details or thermally unaffected by intersections with other surfaces of the building envelope. Clear wall experiments or calculations normally do not include the effects of building envelope details such as corners, window and door openings, and structural intersections with roofs, floors, ceilings, and other walls. In steel-framed wall systems, these details typically consist of much more structural components than the clear wall. For this situation, the thermal properties measured or calculated for the clear wall area do not adequately represent the total wall system thermal performance. Factors that would impact the ability of today`s standard practice to accurately predict the total wall system thermal performance are the accuracy of the calculation methods, the area of the total wall that is clear wall, and the quantity and thermal performance of the various wall system details.

  16. Method for heating, forming and tempering a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.; Sitzman, G.W.

    1998-10-27

    A method for heating, forming and tempering a glass sheet is disclosed including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet. 2 figs.

  17. Method for heating, forming and tempering a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI); Sitzman, Gary W. (Walled Lake, MI)

    1998-01-01

    A method for heating, forming and tempering a glass sheet including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet.

  18. Shear wall ultimate drift limits

    SciTech Connect (OSTI)

    Duffey, T.A.; Goldman, A.; Farrar, C.R.

    1994-04-01

    Drift limits for reinforced-concrete shear walls are investigated by reviewing the open literature for appropriate experimental data. Drift values at ultimate are determined for walls with aspect ratios ranging up to a maximum of 3.53 and undergoing different types of lateral loading (cyclic static, monotonic static, and dynamic). Based on the geometry of actual nuclear power plant structures exclusive of containments and concerns regarding their response during seismic (i.e.,cyclic) loading, data are obtained from pertinent references for which the wall aspect ratio is less than or equal to approximately 1, and for which testing is cyclic in nature (typically displacement controlled). In particular, lateral deflections at ultimate load, and at points in the softening region beyond ultimate for which the load has dropped to 90, 80, 70, 60, and 50 percent of its ultimate value, are obtained and converted to drift information. The statistical nature of the data is also investigated. These data are shown to be lognormally distributed, and an analysis of variance is performed. The use of statistics to estimate Probability of Failure for a shear wall structure is illustrated.

  19. Manufacturing laser glass by continuous melting

    SciTech Connect (OSTI)

    Campbell, J H; Suratwala, T; krenitsky, S; Takeuchi, K

    2000-07-01

    A novel, continuous melting process is being used to manufacture meter-sized plates of laser glass at a rate 20-times faster, 5-times cheaper, and with 2-3 times better optical quality than with previous one-at-a-time, ''discontinuous'' technology processes. This new technology for manufacturing laser glass, which is arguably the most difficult continuously-melted optical material ever produced, comes as a result of a $60 million, six-year joint R&D program between government and industry. The glasses manufactured by the new continuous melting process are Nd-doped phosphate-based glasses and are marketed under the product names LG-770 (Schott Glass Technologies) and LHG-8 (Hoya Corporation USA). With this advance in glass manufacturing technology, it is now possible to construct high-energy, high-peak-power lasers for use in fusion energy development, national defense, and basic physics research that would have been impractical to build using the old melting technology. The development of continuously melted laser glass required technological advances that have lead to improvements in the manufacture of other optical glass products as well. For example, advances in forming, annealing, and conditioning steps of the laser glass continuous melting process are now being used in manufacture of other large-size optical glasses.

  20. Bench Scale Thin Film Composite Hollow Fiber Membranes for Post-Combustion Carbon Dioxide Capture

    SciTech Connect (OSTI)

    Glaser, Paul; Bhandari, Dhaval; Narang, Kristi; McCloskey, Pat; Singh, Surinder; Ananthasayanam, Balajee; Howson, Paul; Lee, Julia; Wroczynski, Ron; Stewart, Frederick; Orme, Christopher; Klaehn, John; McNally, Joshua; Rownaghi, Ali; Lu, Liu; Koros, William; Goizueta, Roberto; Sethi, Vijay

    2015-04-01

    GE Global Research, Idaho National Laboratory (INL), Georgia Institute of Technology (Georgia Tech), and Western Research Institute (WRI) proposed to develop high performance thin film polymer composite hollow fiber membranes and advanced processes for economical post-combustion carbon dioxide (CO2) capture from pulverized coal flue gas at temperatures typical of existing flue gas cleanup processes. The project sought to develop and then optimize new gas separations membrane systems at the bench scale, including tuning the properties of a novel polyphosphazene polymer in a coating solution and fabricating highly engineered porous hollow fiber supports. The project also sought to define the processes needed to coat the fiber support to manufacture composite hollow fiber membranes with high performance, ultra-thin separation layers. Physical, chemical, and mechanical stability of the materials (individual and composite) towards coal flue gas components was considered via exposure and performance tests. Preliminary design, technoeconomic, and economic feasibility analyses were conducted to evaluate the overall performance and impact of the process on the cost of electricity (COE) for a coal-fired plant including capture technologies. At the onset of the project, Membranes based on coupling a novel selective material polyphosphazene with an engineered hollow fiber support was found to have the potential to capture greater than 90% of the CO2 in flue gas with less than 35% increase in COE, which would achieve the DOE-targeted performance criteria. While lab-scale results for the polyphosphazene materials were very promising, and the material was incorporated into hollow-fiber modules, difficulties were encountered relating to the performance of these membrane systems over time. Performance, as measured by both flux of and selectivity for CO2 over other flue gas constituents was found to deteriorate over time, suggesting a system that was more dynamic than initially hypothesized. These phenomena are believed to be associated with the physical and mechanical properties of the separation material, rather than chemical degradation by flue gas or one of its constituents. Strategies to improve the composite systems via alternate chemistries and processing techniques were only partially successful in creating a more robust system, but the research provided critical insight into the barriers to engineering sophisticated composite systems for gas separation. Promising concepts, including a re-engineering of the separation material with interpenetrating polymer networks were identified which may prove useful to future efforts in this field.

  1. The sti ness exponent of two-dimensional Ising spin glasses for non-periodic boundary conditions using aspect-ratio scaling

    E-Print Network [OSTI]

    Hartmann, Alexander K.

    The sti#11;ness exponent of two-dimensional Ising spin glasses for non-periodic boundary conditions a sti#11;ness exponent #18; = 0:287(4), which is independent of the boundary conditions in contrast-wall energy scales like M #18; in the thermodynamic limit, where #18; is the sti#11;ness exponent. If #18;

  2. Systems Biology Approaches to Dissecting Plant Cell Wall Biosynthesis Genes in Poplus (JGI Seventh Annual User Meeting 2012: Genomics of Energy and Environment)

    ScienceCinema (OSTI)

    Glass, N Louise [UC Berkeley

    2013-01-25

    N. Louise Glass from the University of California, Berkeley, presents a talk titled "Systems Biology Approaches to Dissecting Plant Cell Wall Biosynthesis Genes in Poplus" at the JGI 7th Annual Users Meeting: Genomics of Energy & Environment Meeting on March 22, 2012 in Walnut Creek, California.

  3. Systems Biology Approaches to Dissecting Plant Cell Wall Biosynthesis Genes in Poplus (JGI Seventh Annual User Meeting 2012: Genomics of Energy and Environment)

    SciTech Connect (OSTI)

    Glass, N Louise [UC Berkeley] [UC Berkeley

    2012-03-22

    N. Louise Glass from the University of California, Berkeley, presents a talk titled "Systems Biology Approaches to Dissecting Plant Cell Wall Biosynthesis Genes in Poplus" at the JGI 7th Annual Users Meeting: Genomics of Energy & Environment Meeting on March 22, 2012 in Walnut Creek, California.

  4. Current status of the GLASS code

    SciTech Connect (OSTI)

    Hootman, H.E. [Westinghouse Savannah River Co., Aiken, SC (United States); Honeck, H.C. [Computer Application Technology, Inc., Aiken, SC (United States)

    1991-12-31

    This paper summarizes the current status of the Generalized Lattice Analysis SubSystem (GLASS) computer code and its supporting cross section libraries. GLASS was developed at the Savannah River Site (SRS) in the early 1970`s. The GLASS code has been instrumental in supporting safe Heavy Water Reactor (HWR) operations and predicting material production at SRS for more than 20 years. The Department of Energy Office of New Production Reactors (ONPR) program has chosen to use the GLASS code for the design of the HWR option of the New Production Reactor (NPR). A substantial body of validation calculations have been performed and additional validation calculations will be performed to qualify the new GLASS multigroup cross section libraries derived from the ENDF/B-5 and 6 nuclear data files. Several improvements to the code are in progress. Many other improvements are planned to bring GLASS up to modern physics and compute technology.

  5. Glass and Glass Products (2010 MECS) | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUseful LinksGlass Stronger than Steel Stories

  6. Glass Property Data and Models for Estimating High-Level Waste Glass Volume

    SciTech Connect (OSTI)

    Vienna, John D.; Fluegel, Alexander; Kim, Dong-Sang; Hrma, Pavel R.

    2009-10-05

    This report describes recent efforts to develop glass property models that can be used to help estimate the volume of high-level waste (HLW) glass that will result from vitrification of Hanford tank waste. The compositions of acceptable and processable HLW glasses need to be optimized to minimize the waste-form volume and, hence, to save cost. A database of properties and associated compositions for simulated waste glasses was collected for developing property-composition models. This database, although not comprehensive, represents a large fraction of data on waste-glass compositions and properties that were available at the time of this report. Glass property-composition models were fit to subsets of the database for several key glass properties. These models apply to a significantly broader composition space than those previously publised. These models should be considered for interim use in calculating properties of Hanford waste glasses.

  7. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, C.Q. Jr.

    1980-01-28

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  8. 68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Glass Technol., 2004, 45, 6870

    E-Print Network [OSTI]

    Sheffield, University of

    68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Glass Technol., 2004, 45, 68­70 The behaviour of a simulant Magnox waste glass

  9. Radiation Characteristics of Glass Containing Gas Bubbles

    E-Print Network [OSTI]

    Pilon, Laurent; Viskanta, Raymond

    2003-01-01

    Optical properties of soda-lime silicate”, Solar Energye?ciency factors of the soda-lime silicate containing gasscattering albedo of soda-lime silicate glass containing

  10. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure....

  11. High-Temperature Viscosity Of Commercial Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R.; See, Clem A.; Lam, Oanh P.; Minister, Kevin B.

    2005-01-01

    Viscosity was measured for six types of commercial glasses: low-expansion-borosilicate glasses, E glasses, fiberglass wool glasses, TV panel glasses, container glasses, and float glasses. Viscosity data were obtained with rotating spindle viscometers within the temperature range between 900°C and 1550°C; the viscosity varied from 1 Pa?s to 750 Pa?s. Arrhenius coefficients were calculated for individual glasses and linear models were applied to relate them to the mass fractions of 11 major components (SiO2, CaO, Na2O, Al2O3, B2O3, BaO, SrO, K2O, MgO, PbO, and ZrO2) and 12 minor components (Fe2O3, ZnO, Li2O, TiO2, CeO2, F, Sb2O3, Cr2O3, As2O3, MnO2, SO3, and Co3O4). The models are recommended for glasses containing 42 to 84 mass% SiO2 to estimate viscosities or temperatures at a constant viscosity for melts within both the temperature range from 1100°C to 1550°C and viscosity range from 10 to 400 Pa?s.

  12. Compliant Glass Seals for SOFC Stacks

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Xu, Wei; Stephens, Elizabeth V.; Koeppel, Brian J.; Stevenson, Jeffry W.; Lara-Curzio, Edgar

    2014-04-01

    This report summarizes results from experimental and modeling studies performed by participants in the Solid-State Energy Conversion Alliance (SECA) Core Technology Program, which indicate that compliant glass-based seals offer a number of potential advantages over conventional seals based on de-vitrifying glasses, including reduced stresses during stack operation and thermal cycling, and the ability to heal micro-damage induced during thermal cycling. The properties and composition of glasses developed and/or investigated in these studies are reported, along with results from long-term (up to 5,800h) evaluations of seals based on a compliant glass containing ceramic particles or ceramic fibers.

  13. Promising Technology: Cool Paints for Exterior Walls

    Broader source: Energy.gov [DOE]

    Cool Paints increase the solar reflectance of exterior walls. By reflecting more sunlight, the wall surface maintains a cooler temperature. This decrease in temperature leads to less heat transfer through the walls into the building. During the cooling season, the addition of cool paints can decrease the cooling load of the building.

  14. Influence of wall thickness on the stability of the resistive wall mode in tokamak Richard Fitzpatrick

    E-Print Network [OSTI]

    Fitzpatrick, Richard

    Influence of wall thickness on the stability of the resistive wall mode in tokamak plasmas Richard.1063/1.2446041 Nonlinear evolution of resistive wall mode in a cylindrical tokamak with poloidal rotation Phys. Plasmas 13); 10.1063/1.1943347 Control of resistive wall modes in a cylindrical tokamak with radial and poloidal

  15. Level-set method used to track the glass-air interface in the blow step of glass containers

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    Level-set method used to track the glass-air interface in the blow step of glass containers C. G-air interface of the blowing of a preform with non-uniform temperature. Keywords: glass forming of the second blowing step of the forming process. As the glass flows towards the mould the glass-air interface

  16. Comparative study of two- and three-dimensional modeling on arc discharge phenomena inside a thermal plasma torch with hollow electrodes

    SciTech Connect (OSTI)

    Kim, Keun Su; Park, Jin Myung; Choi, Sooseok; Kim, Jongin; Hong, Sang Hee

    2008-02-15

    A comparative study between two- and three-dimensional (2D and 3D) modeling is carried out on arc discharge phenomena inside a thermal plasma torch with hollow electrodes, in order to evaluate the effects of arc root configuration characterized by either 2D annular or 3D highly localized attachment on the electrode surface. For this purpose, a more precise 3D transient model has been developed by taking account of 3D arc current distribution and arc root rotation. The 3D simulation results apparently reveal that the 3D arc root attachment brings about the inherent 3D and turbulence nature of plasma fields inside the torch. It is also found that the constricted arc column near the vortex chamber plays an important role in heating and acceleration of injected arc gases by concentrating arc currents on the axis of the hollow electrodes. The inherent 3D nature of arc discharge is well preserved inside the cathode region, while these 3D features slowly diminish behind the vortex chamber where the turbulent flow begins to be developed in the anode region. Based on the present simulation results, it is noted that the mixing effects of the strong turbulent flow on the heat and mass transfer are mainly responsible for the gradual relaxation of the 3D structures of plasma fields into the 2D axisymmetric ones that eventually appear in the anode region near the torch exit. From a detailed comparison of the 3D results with the 2D ones, the arc root configuration seems to have a significant effect on the heat transfer to the electrode surfaces interacting with the turbulent plasma flow. That is, in the 2D simulation based on an axisymmetric stationary model, the turbulence phenomena are fairly underestimated and the amount of heat transferred to the cold anode wall is calculated to be smaller than that obtained in the 3D simulation. For the validation of the numerical simulations, calculated plasma temperatures and axial velocities are compared with experimentally measured ones, and the 3D simulation turns out to be more accurate than the 2D simulation as a result of a relatively precise description of the turbulent phenomena inside the torch using a more realistic model of arc root attachment. Finally, it is suggested that the 3D transient formulation is indeed required for describing the real arc discharge phenomena inside the torch, while the 2D stationary approach is sometimes useful for getting practical information about the time-averaged plasma characteristics outside the torch because of its simplicity and rapidness in computation.

  17. Measurement of Time-Averaged Particle-Wall Collision Properties Using Particle Tracking Velocimetry, CRADA PC93-006, Final Report

    SciTech Connect (OSTI)

    Shaffer, F.; Massah, H.; Sinclair, J.; Shahnam, M.

    1995-04-30

    This paper describes an experimental facility to measure time-averaged properties of particle-wall collisions. A particle tracking velocimetry (PTV) system measures particle rebound angles and velocities and impact angles and velocities for specific particles. From these measured properties, values of normal and tangential coefficient of restitution are derived. The PTV system rapidly measures thousands of particle-wall collisions enabling determination of time-averaged properties. In this initial work we use 191 {micro}m glass particles colliding with a glass plate at a fixed angle of 17.5{degree} and a velocity of 17.07 m/s. Observations are also made of aspherical particles colliding with gross sliding. In the future, this experimental system will be used with particles and wall materials of industrial significance.

  18. Scaling behavior of domain walls at the T =0 ferromagnet to spin-glass transition

    E-Print Network [OSTI]

    Peinke, Joachim

    ) Disordered model systems, governed by Edwards-Anderson Hamiltonian for Ising spins i =±1: H() = - i,j Jijij Quenched disorder: Jij > 0 : Jij -J2 /2 / 2 + (J -1) =0: SG with Gaussian disorder =1: Ferromagnet Ground states (GSs) Spin

  19. Radiative Heat Transfer in Enhanced Hydrogen Outgassing of Glass

    E-Print Network [OSTI]

    Kitamura, Rei; Pilon, Laurent

    2009-01-01

    Photo-induced hydrogen outgassing of glass”, Journal of Non-Photo-induced hydrogen outgassing of glass, PhD thesis,in Enhanced Hydrogen Outgassing of Glass Rei Kitamura and

  20. Nano-structured self-cleaning superhydrophobic glass

    E-Print Network [OSTI]

    Kim, Jin Yeol

    2010-01-01

    images of water droplet on AAO coating on soda lime glass. (a) with as- made AAO on soda lime glass (CA = 54 o ), (b)Al 2 O 3 nanowires on soda lime glass after 65 min pore-

  1. Radiative Heat Transfer in Enhanced Hydrogen Outgassing of Glass

    E-Print Network [OSTI]

    Kitamura, Rei; Pilon, Laurent

    2009-01-01

    transport in a machinable glass-ceramic”, Journal of Non-in soda-lime-silicate glasses by reaction with hydrogen”,1971. [16] I. Fanderlik, Glass Science and Technology, Vol.

  2. Further developments of capillary absorption spectrometers using small hollow-waveguide fibers

    SciTech Connect (OSTI)

    Kelly, James F.; Sams, Robert L.; Blake, Thomas A.; Kriesel, Jason M.

    2014-05-01

    Our objective is to enhance quantification of stable carbon and oxygen isotope ratios to better than 1‰ relative isotope precision for sample sizes < 1 pico-mole. A newer variant Capillary Absorption Spectrometer (CAS) is described using a proprietary linear-taper hollow waveguide in conjunction with wavelength and frequency modulation techniques of tunable laser absorption spectrometry. Previous work used circular capillaries with uniform 1 mm ID to measure 13C/12C ratios with ? 20 pico-mole samples to ? 10 ppm (1‰ precision against standards) [1]. While performing fairly well, it generated residual modal noise due to multipath propagation in the hollow-waveguides (HWGs). This system has been utilized with laser ablation-catalytic combustion techniques to analyze small resolution (~ 25 ?m spot diameter) laser ablation events on solids. Using smaller ID capillary waveguides could improve detection limits and spatial resolutions. Reducing an IR compatible hollow waveguide’s inner diameter (ID) to < 300 ?m, reduces modal noise significantly for mid-IR operation, but feedback noise with high gain semiconductor lasers can become problematic. A proprietary linear-taper small waveguide (mean ID = 0.35 mm, L = 1 m) was tested to understand whether modal noise and optical feedback effects could be simultaneously reduced. We see better mode filtering and, significant reductions of feedback noise under favorable coupling of a multi-spatial mode QC laser to the smaller ID of the linear-tapered HWG. We demonstrate that better modal coupling operation is consistent with Liouville’s theorem, where greater suppression of feedback from spurious scatter within the HWG occurs by injecting the laser into the smaller ID port. Our progress on developing lighter weight, potentially fieldable alternatives to Isotope Ratio Mass Spectrometers (IRMS) with a small volume (? 0.1 cm3) CAS system will be discussed and compared to other competitive systems.

  3. Post-closure permit application for the Kerr Hollow Quarry at the Y-12 plant

    SciTech Connect (OSTI)

    1995-06-01

    The Kerr Hollow Quarry (KHQ) is located on U.S. Department of Energy (DOE) property at the Y-12 Plant, Oak Ridge, Tennessee. The Oak Ridge Y-12 Plant was built by the U.S. Army Corps of Engineers in 1943 as part of the Manhattan Project. Until 1992, the primary mission of the Y-12 Plant was the production and fabrication of nuclear weapons components. Activities associated with these functions included production of lithium compounds, recovery of enriched uranium from scrap material, and fabrication of uranium and other materials into finished parts for assemblies. The Kerr Hollow Quarry was used for waste disposal of a variety of materials including water-reactive and shock-sensitive chemicals and compressed gas cylinders. These materials were packaged in various containers and sank under the water in the quarry due to their great weight. Disposal activities were terminated in November, 1988 due to a determination by the Tennessee Department of Environment and Conservation that the quarry was subject to regulations under the Resource Conservation and Recovery Act of 1993. Methods of closure for the quarry were reviewed, and actions were initiated to close the quarry in accordance with closure requirements for interim status surface impoundments specified in Tennessee Rules 1200-1-11-.05(7) and 1200-1-11-.05(11). As part of these actions, efforts were made to characterize the physical and chemical nature of wastes that had been disposed of in the quarry, and to remove any containers or debris that were put into the quarry during waste disposal activities. Closure certification reports (Fraser et al. 1993 and Dames and Moore 1993) document closure activities in detail. This report contains the post-closure permit application for the Kerr Hollow Quarry site.

  4. The effect of cathode geometry on barium transport in hollow cathode plasmas

    SciTech Connect (OSTI)

    Polk, James E. Mikellides, Ioannis G.; Katz, Ira; Capece, Angela M.

    2014-05-14

    The effect of barium transport on the operation of dispenser hollow cathodes was investigated in numerical modeling of a cathode with two different orifice sizes. Despite large differences in cathode emitter temperature, emitted electron current density, internal xenon neutral and plasma densities, and size of the plasma-surface interaction region, the barium transport in the two geometries is qualitatively very similar. Barium is produced in the insert and flows to the surface through the porous structure. A buildup of neutral Ba pressure in the plasma over the emitter surface can suppress the reactions supplying the Ba, restricting the net production rate. Neutral Ba flows into the dense Xe plasma and has a high probability of being ionized at the periphery of this zone. The steady state neutral Ba density distribution is determined by a balance between pressure gradient forces and the drag force associated with collisions between neutral Ba and neutral Xe atoms. A small fraction of the neutral Ba is lost upstream. The majority of the neutral Ba is ionized in the high temperature Xe plasma and is pushed back to the emitter surface by the electric field. The steady state Ba{sup +} ion density distribution results from a balance between electrostatic and pressure forces, neutral Xe drag and Xe{sup +} ion drag with the dominant forces dependent on location in the discharge. These results indicate that hollow cathodes are very effective at recycling Ba within the discharge and therefore maintain a high coverage of Ba on the emitter surface, which reduces the work function and sustains high electron emission current densities at moderate temperatures. Barium recycling is more effective in the cathode with the smaller orifice because the Ba is ionized in the dense Xe plasma concentrated just upstream of the orifice and pushed back into the hollow cathode. Despite a lower emitter temperature, the large orifice cathode has a higher Ba loss rate through the orifice because the Xe plasma density peaks further upstream.

  5. The quantum Biroli-Mézard model: glass transition and superfluidity in a quantum lattice glass model

    E-Print Network [OSTI]

    Laura Foini; Guilhem Semerjian; Francesco Zamponi

    2011-03-12

    We study the quantum version of a lattice model whose classical counterpart captures the physics of structural glasses. We discuss the role of quantum fluctuations in such systems and in particular their interplay with the amorphous order developed in the glass phase. We show that quantum fluctuations might facilitate the formation of the glass at low enough temperature. We also show that the glass transition becomes a first-order transition between a superfluid and an insulating glass at very low temperature, and is therefore accompanied by phase coexistence between superfluid and glassy regions.

  6. Note: Hollow cathode lamp with integral, high optical efficiency isolation valve: A modular vacuum ultraviolet source

    SciTech Connect (OSTI)

    Sloan Roberts, F.; Anderson, Scott L. [Department of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, Utah 84112 (United States)] [Department of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, Utah 84112 (United States)

    2013-12-15

    The design and operating conditions of a hollow cathode discharge lamp for the generation of vacuum ultraviolet radiation, suitable for ultrahigh vacuum (UHV) application, are described in detail. The design is easily constructed, and modular, allowing it to be adapted to different experimental requirements. A thin isolation valve is built into one of the differential pumping stages, isolating the discharge section from the UHV section, both for vacuum safety and to allow lamp maintenance without venting the UHV chamber. The lamp has been used both for ultraviolet photoelectron spectroscopy of surfaces and as a “soft” photoionization source for gas-phase mass spectrometry.

  7. Low loss hollow optical-waveguide connection from atmospheric pressure to ultra-high vacuum

    SciTech Connect (OSTI)

    Ermolov, A.; Mak, K. F.; Tani, F.; Hölzer, P.; Travers, J. C. [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany)] [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany); Russell, P. St. J. [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany) [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany); Department of Physics, University of Erlangen-Nuremberg, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany)

    2013-12-23

    A technique for optically accessing ultra-high vacuum environments, via a photonic-crystal fiber with a long small hollow core, is described. The small core and the long bore enable a pressure ratio of over 10{sup 8} to be maintained between two environments, while permitting efficient and unimpeded delivery of light, including ultrashort optical pulses. This delivery can be either passive or can encompass nonlinear optical processes such as optical pulse compression, deep UV generation, supercontinuum generation, or other useful phenomena.

  8. Integration of a terahertz quantum cascade laser with a hollow waveguide

    DOE Patents [OSTI]

    Wanke, Michael C. (Albuquerque, NM); Nordquist, Christopher D. (Albuquerque, NM)

    2012-07-03

    The present invention is directed to the integration of a quantum cascade laser with a hollow waveguide on a chip to improve both the beam pattern and manufacturability. By coupling the QCL output into a single-mode rectangular waveguide the radiation mode structure can be known and the propagation, manipulation, and broadcast of the QCL radiation can then be entirely controlled by well-established rectangular waveguide techniques. By controlling the impedance of the interface, enhanced functions, such as creating amplifiers, efficient coupling to external cavities, and increasing power output from metal-metal THz QCLs, are also enabled.

  9. Catalytic Templating Approaches for Three-Dimensional Hollow Carbon/Graphene Oxide Nano-Architectures

    SciTech Connect (OSTI)

    Moon, Gun-Hee; Shin, Yongsoon; Choi, Daiwon; Arey, Bruce W.; Exarhos, Gregory J.; Wang, Chong M.; Choi, Wonyong; Liu, Jun

    2013-01-01

    We report a catalytic templating method to synthesize well-controlled, three-dimensional (3D) nano-architectures with graphene oxide sheets. The 3D composites are prepared via self-assembly of carbon, GO, and spherical alumina-coated silica (ACS) templates during a catalytic reaction porcess. By changing the GO content, we can systematically tune the architecture from layered composites to 3D hollow structures to microporous materials. The composites show a synergistic effect with significantly superior properties than either pure carbon or r-GO prepared with a significant enhancement to its capacitance at high current density.

  10. Method for heating and forming a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI)

    1997-01-01

    A method for heating and forming a glass sheet includes the steps of heating a glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, cooling an outer surface of the glass sheet to at least a third predetermined temperature and forming the glass sheet using forming rollers to a predetermined configuration.

  11. Method for heating and forming a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.

    1997-08-12

    A method for heating and forming a glass sheet includes the steps of heating a glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, cooling an outer surface of the glass sheet to at least a third predetermined temperature and forming the glass sheet using forming rollers to a predetermined configuration. 5 figs.

  12. Method and apparatus for melting glass batch

    DOE Patents [OSTI]

    Fassbender, Alexander G. (Kennewick, WA); Walkup, Paul C. (Richland, WA); Mudge, Lyle K. (Richland, WA)

    1988-01-01

    A glass melting system involving preheating, precalcining, and prefluxing of batch materials prior to injection into a glass furnace. The precursors are heated by convection rather than by radiation in present furnaces. Upon injection into the furnace, batch materials are intimately coated with molten flux so as to undergo or at least begin the process of dissolution reaction prior to entering the melt pool.

  13. Monitoring and analyzing waste glass compositions

    DOE Patents [OSTI]

    Schumacher, Ray F. (Aiken, SC)

    1994-01-01

    A device and method for determining the viscosity of a fluid, preferably molten glass. The apparatus and method uses the velocity of rising bubbles, preferably helium bubbles, within the molten glass to determine the viscosity of the molten glass. The bubbles are released from a tube positioned below the surface of the molten glass so that the bubbles pass successively between two sets of electrodes, one above the other, that are continuously monitoring the conductivity of the molten glass. The measured conductivity will change as a bubble passes between the electrodes enabling an accurate determination of when a bubble has passed between the electrodes. The velocity of rising bubbles can be determined from the time interval between a change in conductivity of the first electrode pair and the second, upper electrode pair. The velocity of the rise of the bubbles in the glass melt is used in conjunction with other physical characteristics, obtained by known methods, to determine the viscosity of the glass melt fluid and, hence, glass quality.

  14. Monitoring and analyzing waste glass compositions

    DOE Patents [OSTI]

    Schumacher, R.F.

    1994-03-01

    A device and method are described for determining the viscosity of a fluid, preferably molten glass. The apparatus and method use the velocity of rising bubbles, preferably helium bubbles, within the molten glass to determine the viscosity of the molten glass. The bubbles are released from a tube positioned below the surface of the molten glass so that the bubbles pass successively between two sets of electrodes, one above the other, that are continuously monitoring the conductivity of the molten glass. The measured conductivity will change as a bubble passes between the electrodes enabling an accurate determination of when a bubble has passed between the electrodes. The velocity of rising bubbles can be determined from the time interval between a change in conductivity of the first electrode pair and the second, upper electrode pair. The velocity of the rise of the bubbles in the glass melt is used in conjunction with other physical characteristics, obtained by known methods, to determine the viscosity of the glass melt fluid and, hence, glass quality. 2 figures.

  15. Viscous Glass Sealants for SOFC Applications

    SciTech Connect (OSTI)

    Scott Misture

    2012-09-30

    Two series of silicate glasses that contain gallium as the primary critical component have been identified and optimized for viscous sealing of solid oxide fuel cells operating from 650 to 850°C. Both series of glass sealants crystallize partially upon heat treatment and yield multiphase microstructures that allow viscous flow at temperatures as low as 650°C. A fully amorphous sealant was also developed by isolating, synthesizing and testing a silicate glass of the same composition as the remnant glassy phase in one of the two glass series. Of ~40 glasses tested for longer than 500 hours, a set of 5 glasses has been further tested for up to 1000h in air, wet hydrogen, and against both yttria-stabilized zirconia and aluminized stainless steel. In some cases the testing times reached 2000h. The reactivity testing has provided new insight into the effects of Y, Zr, and Al on bulk and surface crystallization in boro-gallio-silicate glasses, and demonstrated that at least 5 of the newly-developed glasses are viable viscous sealants.

  16. Perceptual Affordances of Wall-Sized Displays for

    E-Print Network [OSTI]

    Isenberg, Petra

    .g., HCI)]: Miscellaneous. Introduction Wall-sized displays (PowerWalls) engulf viewers in very large high

  17. Glass heat pipe evacuated tube solar collector

    DOE Patents [OSTI]

    McConnell, Robert D. (Lakewood, CO); Vansant, James H. (Tracy, CA)

    1984-01-01

    A glass heat pipe is adapted for use as a solar energy absorber in an evacuated tube solar collector and for transferring the absorbed solar energy to a working fluid medium or heat sink for storage or practical use. A capillary wick is formed of granular glass particles fused together by heat on the inside surface of the heat pipe with a water glass binder solution to enhance capillary drive distribution of the thermal transfer fluid in the heat pipe throughout the entire inside surface of the evaporator portion of the heat pipe. Selective coatings are used on the heat pipe surface to maximize solar absorption and minimize energy radiation, and the glass wick can alternatively be fabricated with granular particles of black glass or obsidian.

  18. Low loss laser glass: Final report

    SciTech Connect (OSTI)

    Izumitani, T.; Toratani, H.; Meissner, H.E.

    1987-01-15

    The objective of this work was a process development on making a laser glass with loss coefficient of 10/sup -4/cm/sup -1/ at 1.05..mu... The key issues for making such a low loss glass will be to use pure raw materials, to reduce OH content and to prevent contamination from the melting environment. A sublimation method was tried to prepare pure P/sub 2/O/sub 5/ batch material. In an attempt to distinguish contributions to the overall loss, glasses were melted in furnaces which were controlled in moisture as well as contamination. Evaluation of glass samples at LLNL are expected to provide guidance on the importance of various process parameters. A new 0.5 liter furnace which almost completely prevents contamination by the furnace environment has been constructed to obtain useful information for making a low loss glass on a production scale.

  19. Titanium sealing glasses and seals formed therefrom

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

    1997-01-01

    Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

  20. Titanium sealing glasses and seals formed therefrom

    DOE Patents [OSTI]

    Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

    1997-12-02

    Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La{sub 2}O{sub 3}, B{sub 2}O{sub 3}, TiO{sub 2} and Al{sub 2}O{sub 3} in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 2 figs.

  1. Gaseous Sulfate Solubility in Glass: Experimental Method

    SciTech Connect (OSTI)

    Bliss, Mary

    2013-11-30

    Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

  2. China Glass Solar aka CG Solar formerly Weihai Bluestar Terra...

    Open Energy Info (EERE)

    China Glass Solar aka CG Solar formerly Weihai Bluestar Terra Photovoltaic Co Ltd Jump to: navigation, search Name: China Glass Solar (aka CG Solar, formerly Weihai Bluestar Terra...

  3. Metal and Glass Manufacturers Reduce Costs by Increasing Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in Process Heating Systems Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in...

  4. California: Energy-Efficient Glass Saves Energy Costs, Increases...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy-Efficient Glass Saves Energy Costs, Increases Personal Comfort California: Energy-Efficient Glass Saves Energy Costs, Increases Personal Comfort April 18, 2013 - 12:00am...

  5. Waste Loading Enhancements for Hanford Low-Activity Waste Glasses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WASTE LOADING ENHANCEMENTS FOR HANFORD LOW-ACTIVITY WASTE GLASSES Albert A. Kruger, Glass Scientist DOE-WTP Project Office Engineering Division US Department of Energy Richland,...

  6. Refractive index of glass and its dipersion for visible light.

    SciTech Connect (OSTI)

    Smith, D. Y.; Karstens, W. (Physics); (Univ. of Vermont); (Saint Michael's Coll.)

    2010-01-01

    The classification of optical glass and empirical relations between the refractive index and its dispersion are discussed in terms of moments of the glass's IR and UV absorption spectra. The observed linear dependence of index on dispersion within glass families is shown to arise primarily from the approximately linear superposition of the electronic absorptions of glass former and glass modifiers. The binary classification into crown and flint glasses is also based primarily on electronic spectra: Crown glasses are 'wide-gap' materials with excitation energies greater than {approx}12.4 eV, while flint glasses are their 'narrow-gap' counterpart.

  7. California: Energy-Efficient Glass Saves Energy Costs, Increases...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    California: Energy-Efficient Glass Saves Energy Costs, Increases Personal Comfort California: Energy-Efficient Glass Saves Energy Costs, Increases Personal Comfort April 18, 2013 -...

  8. Glass-like thermal conductivity in high efficiency thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glass-like thermal conductivity in high efficiency thermoelectric materials Glass-like thermal conductivity in high efficiency thermoelectric materials Discusses strategies to...

  9. Comparative Study of High Triangularity H-mode Plasma Performance in JET with Be/W Wall and CFC Wall

    E-Print Network [OSTI]

    Comparative Study of High Triangularity H-mode Plasma Performance in JET with Be/W Wall and CFC Wall

  10. NREL: Energy Analysis - Anna Wall

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on771/6/14 Contact:NewsWebmasterWorking With UsAnna Wall Photo of

  11. Glass for sealing lithium cells

    DOE Patents [OSTI]

    Leedecke, C.J.

    1981-08-28

    Glass compositions resistant to corrosion by lithium cell electrolyte and having an expansion coefficient of 45 to 85 x 10/sup -70/C/sup -1/ have been made with SiO/sub 2/, 25 to 55% by weight; B/sub 2/O/sub 3/, 5 to 12%; Al/sub 2/O/sub 3/, 12 to 35%; CaO, 5 to 15%; MgO, 5 to 15%; SrO, 0 to 10%; and La/sub 2/O/sub 3/, 0 to 5%. Preferred compositions within that range contain 3 to 8% SrO and 0.5 to 2.5% La/sub 2/O/sub 3/.

  12. Optical response of silver clusters and their hollow shells from Linear-Response TDDFT

    E-Print Network [OSTI]

    Koval, Peter; Foerster, Dietrich; Sánchez-Portal, Daniel

    2015-01-01

    We present a study of the optical response of compact and hollow icosahedral clusters containing up to 868 silver atoms by means of time-dependent density functional theory. We have studied the dependence on size and morphology of both the sharp plasmonic resonance at 3--4 eV (originated mainly from $sp$-electrons), and the less studied broader feature appearing in the 6--7 eV range (interband transitions). An analysis of the effect of structural relaxations, as well as the choice of exchange correlation functional (local density versus generalized gradient approximations) both in the ground state and optical response calculations is also presented. We have further analysed the role of the different atom layers (surface versus inner layers) and the different orbital symmetries on the absorption cross-section for energies up to 8 eV. We have also studied the dependence on the number of atom layers in hollow structures. Shells formed by a single layer of atoms show a pronounced red shift of the main plasmon res...

  13. Method of coating the interior surface of hollow objects with a diffusion coating

    DOE Patents [OSTI]

    Knowles, Shawn D.; Senor, David J.; Forbes, Steven V.; Johnson, Roger N.; Hollenberg, Glenn W.

    2005-03-15

    A method for forming a diffusion coating on the interior of surface of a hollow object wherein a filament, extending through a hollow object and adjacent to the interior surface of the object, is provided, with a coating material, in a vacuum. An electrical current is then applied to the filament to resistively heat the filament to a temperature sufficient to transfer the coating material from the filament to the interior surface of the object. The filament is electrically isolated from the object while the filament is being resistively heated. Preferably, the filament is provided as a tungsten filament or molybdenum filament. Preferably, the coating materials are selected from the group consisting of Ag, Al, As, Au, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Dy, Er, Eu, Fe, Ga, Ge, Hg, In, K, Li, Mg, Mn, Na, Ni P, Pb, Pd, Pr, S, Sb, Sc, Se, Si, Sn, Sr, Te, Tl, Y, Yb, Zn, and combinations thereof. The invention additionally allows for the formation of nitrides, hydrides, or carbides of all the possible coating materials, where such compounds exist, by providing a partial pressure of nitrogen, hydrogen, hydrocarbons, or combination thereof, within the vacuum.

  14. Facile Directed Assembly of Hollow Polymer Nanocapsules within Spontaneously Formed Catanionic Surfactant Vesicles

    SciTech Connect (OSTI)

    Kim, Mariya D.; Dergunov, Sergey; Richter, Andrew; Durbin, Jeffrey; Shmakov, Sergey; Jia, Ying; Kenbeilova, Saltanat; Orazbekuly, Yerbolat; Kengpeiil, Aigerim; Lindner, Erno; Pingali, Sai Venkatesh; Urban, Volker S; Weigand, Steven; Pinkhassik, Eugene

    2014-01-01

    Surfactant vesicles containing monomers in the interior of the bilayer were used to template hollow polymer nanocapsules. This study investigated the formation of surfactant/monomer assemblies by two loading methods, concurrent loading and diffusion loading. The assembly process and the resulting aggregates were investigated with dynamic light scattering, small angle neutron scattering, and small-angle X-ray scattering. Acrylic monomers formed vesicles with a mixture of cationic and anionic surfactants in a broad range of surfactant ratios. Regions with predominant formation of vesicles were broader for compositions containing acrylic monomers compared with blank surfactants. This observation supports the stabilization of the vesicular structure by acrylic monomers. Diffusion loading produced monomer-loaded vesicles unless vesicles were composed from surfactants at the ratios close to the boundary of a vesicular phase region on a phase diagram. Both concurrent-loaded and diffusion-loaded surfactant/monomer vesicles produced hollow polymer nanocapsules upon the polymerization of monomers in the bilayer followed by removal of surfactant scaffolds.

  15. Superior Conductive Solid-like Electrolytes: Nanoconfining Liquids within the Hollow Structures

    SciTech Connect (OSTI)

    Zhang, Jinshui [ORNL; Bai, Ying [ORNL; Sun, Xiao-Guang [ORNL; Li, Yunchao [ORNL; Guo, Bingkun [ORNL; Chen, Jihua [ORNL; Veith, Gabriel M [ORNL; Hensley, Dale K [ORNL; Paranthaman, Mariappan Parans [ORNL; Goodenough, John B [University of Texas at Austin; Dai, Sheng [ORNL

    2015-01-01

    The growth and proliferation of lithium (Li) dendrites during cell recharge is unavoidable, which seriously hinders the development and application of rechargeable Li metal batteries. Solid electrolytes with robust mechanical modulus are regarded as a promising approach to overcome the dendrite problems. However, their room-temperature ionic conductivities are usually too low to reach the level required for normal battery operation. Here, a class of novel solid electrolytes with liquid-like room-temperature ionic conductivities (> 1 mS cm-1) has been successfully synthesized by taking advantage of the unique nanoarchitectures of hollow silica (HS) spheres to confine liquid electrolytes in hollow space to afford high conductivities. In a symmetric lithium/lithium cell, such kind of solid-like electrolytes demonstrates a robust performance against Li dendrite problems, well stabilizing the cell system from short circuiting in a long-time operation at current densities ranging from 0.16 to 0.32 mA cm-2. Moreover, the high flexibility and compatibility of HS nanoarchitectures, in principle, enables broad tunability to choose desired liquids for the fabrication of other kinds of solid-like electrolytes, such as those containing Na+, Mg2+ or Al3+ as conductive media, providing a useful alternative strategy for the development of next generation rechargeable batteries.

  16. Solid oxide fuel cell having a glass composite seal

    DOE Patents [OSTI]

    De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

    2013-04-16

    A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

  17. Glass ceramic-to-metal seals

    DOE Patents [OSTI]

    Not Available

    1982-04-19

    A glass ceramic composition prepared by subjecting a glass composition comprising, by weight, 65 to 80% SiO/sub 2/, 8 to 16% Li/sub 2/O, 2 to 8% Al/sub 2/O/sub 3/, 1 to 8% K/sub 2/O, 1 to 5% P/sub 2/O/sub 5/ and 1.5 to 7% B/sub 2/O/sub 3/, to the following processing steps of heating the glass composition to a temperature sufficient to crystallize lithium metasilicate therein, holding the glass composition at a temperature and for a time period sufficient to dissolve the lithium metasilicate therein thereby creating cristobalite nucleii, cooling the glass composition and maintaining the composition at a temperature and for a time period sufficient to recrystallize lithium metasilicate therein, and thermally treating the glass composition at a temperature and for a time period sufficient to caus growth of cristobalite and further crystallization of lithium metasilicate producing a glass ceramic composition having a specific thermal expansion coefficient and products containing said composition.

  18. Quantum Fusion of Domain Walls with Fluxes

    E-Print Network [OSTI]

    S. Bolognesi; M. Shifman; M. B. Voloshin

    2009-07-20

    We study how fluxes on the domain wall world volume modify quantum fusion of two distant parallel domain walls into a composite wall. The elementary wall fluxes can be separated into parallel and antiparallel components. The parallel component affects neither the binding energy nor the process of quantum merger. The antiparallel fluxes, instead, increase the binding energy and, against naive expectations, suppress quantum fusion. In the small flux limit we explicitly find the bounce solution and the fusion rate as a function of the flux. We argue that at large (antiparallel) fluxes there exists a critical value of the flux (versus the difference in the wall tensions), which switches off quantum fusion altogether. This phenomenon of flux-related wall stabilization is rather peculiar: it is unrelated to any conserved quantity. Our consideration of the flux-related all stabilization is based on substantiated arguments that fall short of complete proof.

  19. Textural break foundation wall construction modules

    DOE Patents [OSTI]

    Phillips, Steven J. (Kennewick, WA)

    1990-01-01

    Below-grade, textural-break foundation wall structures are provided for inhibiting diffusion and advection of liquids and gases into and out from a surrounding hydrogeologic environment. The foundation wall structure includes a foundation wall having an interior and exterior surface and a porous medium disposed around a portion of the exterior surface. The structure further includes a modular barrier disposed around a portion of the porous medium. The modular barrier is substantially removable from the hydrogeologic environment.

  20. NEUTRON WALL LOADING OF TOKAMAK REACTORS

    E-Print Network [OSTI]

    California at Los Angeles, University of

    GA­A23223 NEUTRON WALL LOADING OF TOKAMAK REACTORS by C.P.C. WONG OCTOBER 1999 #12;DISCLAIMER Government or any agency thereof. #12;GA­A23223 NEUTRON WALL LOADING OF TOKAMAK REACTORS by C.P.C. WONG by General Atomics IR&D Funds GA PROJECT 4437 OCTOBER 1999 #12;C.P.C. WONG NEUTRON WALL LOADING OF TOKAMAK

  1. First wall for polarized fusion reactors

    DOE Patents [OSTI]

    Greenside, Henry S. (Cranbury, NJ); Budny, Robert V. (Princeton, NJ); Post, Jr., Douglass E. (Buttonwood, CT)

    1988-01-01

    Depolarization mechanisms arising from the recycling of the polarized fuel at the limiter and the first-wall of a fusion reactor are greater than those mechanisms in the plasma. Rapid depolarization of the plasma is prevented by providing a first-wall or first-wall coating formed of a low-Z, non-metallic material having a depolarization rate greater than 1 sec.sup.-1.

  2. Charm physics with Moebius Domain Wall Fermions

    E-Print Network [OSTI]

    Andreas Jüttner; Francesco Sanfilippo; Justus Tobias Tsang; Peter Boyle; Marina Marinkovic; Shoji Hashimoto; Takashi Kaneko; Yong-Gwi Cho

    2015-01-04

    We present results showing that Domain Wall fermions are a suitable discretisation for the simulation of heavy quarks. This is done by a continuum scaling study of charm quarks in a M\\"obius Domain Wall formalism using a quenched set-up. We find that discretisation effects remain well controlled by the choice of Domain Wall parameters preparing the ground work for the ongoing dynamical $2+1f$ charm program of RBC/UKQCD.

  3. Charm physics with Moebius Domain Wall Fermions

    E-Print Network [OSTI]

    Jüttner, Andreas; Tsang, Justus Tobias; Boyle, Peter; Marinkovic, Marina; Hashimoto, Shoji; Kaneko, Takashi; Cho, Yong-Gwi

    2015-01-01

    We present results showing that Domain Wall fermions are a suitable discretisation for the simulation of heavy quarks. This is done by a continuum scaling study of charm quarks in a M\\"obius Domain Wall formalism using a quenched set-up. We find that discretisation effects remain well controlled by the choice of Domain Wall parameters preparing the ground work for the ongoing dynamical $2+1f$ charm program of RBC/UKQCD.

  4. Novel lead-iron phosphate glass

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.

    1989-07-11

    The invention described and claimed in the specification relates to the discovery that effective addition of Fe[sub 2]O[sub 3] to a lead phosphate glass results in a glass having enhanced chemical durability and physical stability, and consists essentially of the glass resulting from melting a mixture consisting essentially of, in weight percent, 40--66 percent PbO, 30--55 percent P[sub 2]O[sub 5] and an effective concentration up to 12 percent Fe[sub 2]O[sub 3].

  5. Spin Glasses: Old and New Complexity

    SciTech Connect (OSTI)

    Stein, D. L.

    2011-09-22

    Spin glasses are disordered magnetic systems that exhibit a variety of properties that are characteristic of 'complex systems'. After a brief review of the systems themselves, I will discuss how spin glass concepts have found use in and, in some cases, further advanced areas such as computer science, biology, and other fields: what one might term 'old complexity'. I will then turn to a discussion of more recent concepts and ideas that have flowed from studies of spin glasses, and using these introduce a proposal for a kind of 'new complexity'.

  6. The Color Glass Condensate and Glasma

    E-Print Network [OSTI]

    Larry McLerran

    2008-04-10

    These two lectures concern the Color Glass Condensate and the Glasma. These are forms of matter which might be studied in high energy hadronic collisions. The Color Glass Condensate is high energy density gluonic matter. It constitutes the part of a hadron wavefunction important for high energy processes. The Glasma is matter produced from the collision of two high energy hadrons. Both types of matter are associated with coherent fields. The Color Glass Condensate is static and related to a hadron wavefunction where the glasma is transient and evolves quickly after a collision. I present the properties of such matter, and some aspects of what is known of their properties.

  7. Stress in shaped glass evacuated collectors

    SciTech Connect (OSTI)

    Garrison, J.D.; Fischer-Cripps, A.

    1997-02-01

    Shaped glass evacuated collectors have the lower vacuum envelope formed with a CPC shape. The internal surface is silvered. This surface concentrates solar radiation onto an internal absorbing tube. The upper part of the vacuum envelope is a window to pass the solar radiation in to the absorbing tube. A computer program using analytical equations is used to design these collectors while keeping the glass tensile stress arising from evacuation below acceptable limits. A finite element computer program is used to test the accuracy of the stress calculated analytically. The calculations agree within about 1 MPa. Wind and thermal stresses in the glass are lower than the stresses caused by evacuation.

  8. Low-rise shear wall failure modes

    SciTech Connect (OSTI)

    Farrar, C.R. (Los Alamos National Lab., NM (USA)); Hashimoto, P.S. (EQE Engineering, Inc., Costa Mesa, CA (USA)); Reed, J.W. (Benjamin (J.R.) and Associates, Inc., Mountain View, CA (USA))

    1991-01-01

    A summary of the data that are available concerning the structural response of low-rise shear walls is presented. This data will be used to address two failure modes associated with the shear wall structures. First, data concerning the seismic capacity of the shear walls with emphasis on excessive deformations that can cause equipment failure are examined. Second, data concerning the dynamic properties of shear walls (stiffness and damping) that are necessary to compute the seismic inputs to attached equipment are summarized. This case addresses the failure of equipment when the structure remains functional. 23 refs.

  9. Multiple moving wall dry coal extrusion pump

    DOE Patents [OSTI]

    Fitzsimmons, Mark Andrew

    2013-05-14

    A pump for transporting particulate material includes a passageway defined on each side between an inlet and an outlet by a moving wall.

  10. Fillability of Thin-Wall Steel Castings

    SciTech Connect (OSTI)

    Robert C. Voigt; Joseph Bertoletti; Andrew Kaley; Sandi Ricotta; Travis Sunday

    2002-07-30

    The use of steel components is being challenged by lighter nonferrous or cast iron components. The development of techniques for enhancing and ensuring the filability of thin-wall mold cavities is most critical for thinner wall cast steel production. The purpose of this research was to develop thin-wall casting techniques that can be used to reliably produce thin-wall castings from traditional gravity poured sand casting processes. The focus of the research was to enhance the filling behavior to prevent misrunds. Experiments were conducted to investigate the influence of various foundry variables on the filling of thin section steel castings. These variables include casting design, heat transfer, gating design, and metal fluidity. Wall thickness and pouring temperature have the greatest effect on casting fill. As wall thickness increases the volume to surface area of the casting increases, which increases the solidification time, allowing the metal to flow further in thicker sect ions. Pouring time is another significant variable affecting casting fill. Increases or decreases of 20% in the pouring time were found to have a significant effect on the filling of thin-wall production castings. Gating variables, including venting, pouring head height, and mold tilting also significantly affected thin-wall casting fill. Filters offer less turbulent, steadier flow, which is appropriate for thicker castings, but they do not enhance thin-wall casting fill.

  11. First wall for polarized fusion reactors

    DOE Patents [OSTI]

    Greenside, H.S.; Budny, R.V.; Post, D.E. Jr.

    1985-01-29

    A first-wall or first-wall coating for use in a fusion reactor having polarized fuel may be formed of a low-Z non-metallic material having slow spin relaxation, i.e., a depolarization rate greater than 1 sec/sup -1/. Materials having these properties include hydrogenated and deuterated amorphous semiconductors. A method for preventing the rapid depolarization of a polarized plasma in a fusion device may comprise the step of providing a first-wall or first-wall coating formed of a low-Z, non-metallic material having a depolarization rate greater than 1 sec/sup -1/.

  12. Supporting information Evolution of Hollow TiO2 Nanostructures via the Kirkendall Effect Driven by Cation

    E-Print Network [OSTI]

    Wang, Xudong

    valve open). The chamber was cooled down naturally under N2 flow after growth. To acquire different 5 cm away from the precursor inlet nozzle. N2 gas with a flow rate of 40 sccm was introduced into the chamber to serve as the carrier gas. The system's base pressure was kept at 3.2 Torr. The hollow TiO2

  13. Hollow waveguides for gas sensing and near-IR applications David J. Haan and James A. Harrington

    E-Print Network [OSTI]

    : Hollow waveguides, gas sensing, bending loss, near-JR 1. ETRODUCTION HGWs have been shown previously reported.3' It is the purpose ofthis paper to help characterize these waveguides at shorter on bending of the waveguides is analyzed at both Er:YAG and CO2 (10.6 tm) wavelengths in order to better

  14. Planning and scheduling of PPG glass production, model and implementation.

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    considering waste glass management x Synchronization of the production and consumption of waste glass with 2Planning and scheduling of PPG glass production, model and implementation. Ricardo Lima Ignacio of the glass production x Capture the essence of the process that is not considered in the Master Production

  15. Community Geothermal Technology Program: Hawaii glass project. Final report

    SciTech Connect (OSTI)

    Miller, N.; Irwin, B.

    1988-01-20

    Objective was to develop a glass utilizing the silica waste material from geothermal energy production, and to supply local artists with this glass to make artistic objects. A glass composed of 93% indigenous Hawaiian materials was developed; 24 artists made 110 objects from this glass. A market was found for art objects made from this material.

  16. Glass/polymer composites and methods of making

    DOE Patents [OSTI]

    Samuels, W.D.; Exarhos, G.J.

    1995-06-06

    The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

  17. Non-photorealistic Rendering of Images as Evolutionary Stained Glass

    E-Print Network [OSTI]

    Ashlock, Dan

    Non-photorealistic Rendering of Images as Evolutionary Stained Glass Daniel Ashlock Mathematics glass. A collection of points that are the centers of weighted Voronoi tilings are evolved to minimize. A fractal model of stained glass is then run to create a stained glass texture with a similar average color

  18. Finding Glass Kenton McHenry, Jean Ponce

    E-Print Network [OSTI]

    Forsyth, David

    Finding Glass Kenton McHenry, Jean Ponce Beckman Institute University of Illinois Urbana, IL 61801. This paper addresses the problem of finding glass ob- jects in images. Visual cues obtained by combining with the strong highlights typical of glass surfaces are used to train a hierarchy of classifiers, identify glass

  19. Optimization of Automated Float Glass Lines Byungsoo Na, Shabbir Ahmed

    E-Print Network [OSTI]

    Ahmed, Shabbir

    Optimization of Automated Float Glass Lines Byungsoo Na, Shabbir Ahmed , George Nemhauser and Joel flat glass products being manufactured on float glass lines. New technologies are allowing float glass manufacturers to increase the level of automation in their plants, but the question of how to effectively use

  20. Beetle Kill Wall at NREL

    ScienceCinema (OSTI)

    None

    2013-05-29

    When it comes to designing an interior decorative feature for one of the most energy efficient office buildings in the world, very few would consider bringing in a beetle to do the job. But thats what happened at the U.S. Department of Energy's (DOE) Research Support Facility (RSF) located on the National Renewable Energy Laboratory (NREL) campus.In June, the RSF will become home to more than 800 workers from DOE and NREL and building visitors will be greeted with a soaring, two-story high wall entirely covered with wood harvested from the bark beetle infestation that has killed millions of pine trees in the Western U.S. But, the use of beetle kill wood is just one example of the resources being leveraged to make the RSF a model for sustainability and one more step toward NRELs goal to be a net zero energy campus.

  1. Virtual gap dielectric wall accelerator

    DOE Patents [OSTI]

    Caporaso, George James; Chen, Yu-Jiuan; Nelson, Scott; Sullivan, Jim; Hawkins, Steven A

    2013-11-05

    A virtual, moving accelerating gap is formed along an insulating tube in a dielectric wall accelerator (DWA) by locally controlling the conductivity of the tube. Localized voltage concentration is thus achieved by sequential activation of a variable resistive tube or stalk down the axis of an inductive voltage adder, producing a "virtual" traveling wave along the tube. The tube conductivity can be controlled at a desired location, which can be moved at a desired rate, by light illumination, or by photoconductive switches, or by other means. As a result, an impressed voltage along the tube appears predominantly over a local region, the virtual gap. By making the length of the tube large in comparison to the virtual gap length, the effective gain of the accelerator can be made very large.

  2. Compositional Models of Glass/Melt Properties and their Use for Glass Formulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D.; USA, Richland Washington

    2014-12-18

    Nuclear waste glasses must simultaneously meet a number of criteria related to their processability, product quality, and cost factors. The properties that must be controlled in glass formulation and waste vitrification plant operation tend to vary smoothly with composition allowing for glass property-composition models to be developed and used. Models have been fit to the key glass properties. The properties are transformed so that simple functions of composition (e.g., linear, polynomial, or component ratios) can be used as model forms. The model forms are fit to experimental data designed statistically to efficiently cover the composition space of interest. Examples ofmore »these models are found in literature. The glass property-composition models, their uncertainty definitions, property constraints, and optimality criteria are combined to formulate optimal glass compositions, control composition in vitrification plants, and to qualify waste glasses for disposal. An overview of current glass property-composition modeling techniques is summarized in this paper along with an example of how those models are applied to glass formulation and product qualification at the planned Hanford high-level waste vitrification plant.« less

  3. Compositional Models of Glass/Melt Properties and their Use for Glass Formulation

    SciTech Connect (OSTI)

    Vienna, John D. [Pacific Northwest National Laboratory; Richland Washington USA

    2014-12-18

    Nuclear waste glasses must simultaneously meet a number of criteria related to their processability, product quality, and cost factors. The properties that must be controlled in glass formulation and waste vitrification plant operation tend to vary smoothly with composition allowing for glass property-composition models to be developed and used. Models have been fit to the key glass properties. The properties are transformed so that simple functions of composition (e.g., linear, polynomial, or component ratios) can be used as model forms. The model forms are fit to experimental data designed statistically to efficiently cover the composition space of interest. Examples of these models are found in literature. The glass property-composition models, their uncertainty definitions, property constraints, and optimality criteria are combined to formulate optimal glass compositions, control composition in vitrification plants, and to qualify waste glasses for disposal. An overview of current glass property-composition modeling techniques is summarized in this paper along with an example of how those models are applied to glass formulation and product qualification at the planned Hanford high-level waste vitrification plant.

  4. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of glass scaffolds, including polymer foam replication, sol-gel, and freeze-casting; however, the low compressive strength of these scaffolds (0.2-28 MPa for porosity of...

  5. Free energy of sheared colloidal glasses

    E-Print Network [OSTI]

    M. T. Dang; V. Chikkadi; R. Zargar; D. M. Miedema; D. Bonn; A. Zaccone; P. Schall

    2015-05-25

    We develop a free energy framework to describe the response of glasses to applied stress. Unlike crystals, for which the free energy increases quadratically with strain due to affine displacements, for glasses, the nonequilibrium free energy decreases due to complex interplay of non-affine displacements and dissipation. We measure this free energy directly in strained colloidal glasses, and use mean-field theory to relate it to affine and nonaffine displacements. Nonaffine displacements grow with applied shear due to shear-induced loss of structural connectivity. Our mean-field model allows for the first time to disentangle the complex contributions of affine and nonaffine displacements and dissipation in the transient deformation of glasses.

  6. Bipolaron Model of Superconductivity in Chalcogenide Glasses

    E-Print Network [OSTI]

    Liang-You Zheng; Bo-Cheng Wang; Shan T. Lai

    2010-10-25

    In this paper we propose a small bipolaron model for the superconductivity in the Chalcogenide glasses (c-As2Te3 and c-GeTe). The results are agree with the experiments.

  7. Demonstration of chalcogenide glass racetrack microresonators

    E-Print Network [OSTI]

    Kimerling, Lionel C.

    We have demonstrated what we believe to be the first chalcogenide glass racetrack microresonator using a complementary metal-oxide semiconductor-compatible lift-off technique with thermally evaporated As[subscript 2]S[subscript ...

  8. Glass blowing on a wafer level

    E-Print Network [OSTI]

    Eklund, E. Jesper; Shkel, Andrei M.

    2007-01-01

    are then heated inside a furnace at a temperature above theof glass curs at 821 is ?rst heated inside a furnace. Thegob is then removed from the furnace and blown into desired

  9. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, B.R.; McBranch, D.W.; Robinson, J.M.; Koskelo, A.C.; Love, S.P.

    1995-05-30

    Synthesis of fullerene/glass composites is described. A direct method for preparing solid solutions of C{sub 60} in silicon dioxide (SiO{sub 2}) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these ``guests`` in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C{sub 60}. Depending upon the preparative procedure, C{sub 60} dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C{sub 60} in a solid glass matrix, is generated by the present method.

  10. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, Benjamin R. (Santa Fe, NM); McBranch, Duncan W. (Santa Fe, NM); Robinson, Jeanne M. (Los Alamos, NM); Koskelo, Aaron C. (Los Alamos, NM); Love, Steven P. (Los Alamos, NM)

    1995-01-01

    Synthesis of fullerene/glass composites. A direct method for preparing solid solutions of C.sub.60 in silicon dioxide (SiO.sub.2) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these "guests" in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C.sub.60. Depending upon the preparative procedure, C.sub.60 dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C.sub.60 in a solid glass matrix, is generated by the present method.

  11. Initial Conditions from Color Glass Condensate 

    E-Print Network [OSTI]

    Chen, Guangyao

    2013-08-06

    Nuclei at very high energy, characterized by a saturation scale, can be described by an e?ective theory of Quantum ChromoDynamics (QCD) called Color Glass Condensates. The earliest phase of the collision of two nuclei is ...

  12. The Thermal Collector With Varied Glass Covers

    SciTech Connect (OSTI)

    Luminosu, I.; Pop, N.

    2010-08-04

    The thermal collector with varied glass covers represents an innovation realized in order to build a collector able to reach the desired temperature by collecting the solar radiation from the smallest surface, with the highest efficiency. In the case of the thermal collector with variable cover glasses, the number of the glass plates covering the absorber increases together with the length of the circulation pipe for the working fluid. The thermal collector with varied glass covers compared to the conventional collector better meet user requirements because: for the same temperature increase, has the collecting area smaller; for the same collection area, realizes the highest temperature increase and has the highest efficiency. This works is addressed to researchers in the solar energy and to engineers responsible with air-conditioning systems design or industrial and agricultural products drying.

  13. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali; Orler, Bruce; Tornga, Stephanie; Welch, Cindy

    2011-01-26

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

  14. 7/1/08 14:51Chemical & Engineering News | Reel Science --WALL-E Page 1 of 2http://pubs.acs.org/cen/reelscience/reviews/walle/

    E-Print Network [OSTI]

    Arizona, University of

    that WALL-E and EVE show are the holy grails for robotics researchers, he adds. Living on Axiom may seem

  15. Influence of preparation conditions of hollow titania–nickel composite spheres on their catalytic activity for hydrolytic dehydrogenation of ammonia borane

    SciTech Connect (OSTI)

    Umegaki, Tetsuo, E-mail: umegaki.tetsuo@nihon-u.ac.jp [Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, 1-8-14, Kanda-Surugadai, Chiyoda-Ku, Tokyo 101-8308 (Japan); Ohashi, Takato [Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, 1-8-14, Kanda-Surugadai, Chiyoda-Ku, Tokyo 101-8308 (Japan); Xu, Qiang [National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577 (Japan); Kojima, Yoshiyuki [Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, 1-8-14, Kanda-Surugadai, Chiyoda-Ku, Tokyo 101-8308 (Japan)

    2014-04-01

    Highlights: • We study influence of preparation conditions on activity of hollow titania–nickel composite spheres. • The activity for hydrolytic dehydrogenation of NH{sub 3}BH{sub 3} increases with increase of Ti + Ni content. • The activity depends on the amount of PS residue in the hollow spheres. - Abstract: The present work reports influence of preparation conditions of hollow titania–nickel composite spheres on their morphology and catalytic activity for hydrolytic dehydrogenation of ammonia borane (NH{sub 3}BH{sub 3}). The as-prepared hollow titania–nickel composite spheres were characterized by transmission electron microscopy (TEM). Catalytic activities of the hollow spheres for hydrolytic dehydrogenation of aqueous NaBH{sub 4}/NH{sub 3}BH{sub 3} solution improve with the decrease of Ti + Ni content. From the results of FTIR spectra and elemental analysis, the amount of residual polystyrene (PS) templates is able to be reduced by increasing aging time for the preparation, and the catalytic activity of the hollow spheres increases when the amount of residual PS templates decreases. The carbon content in the hollow spheres prepared with aging time = 24 h is 17.3 wt.%, and the evolution of 62 mL hydrogen is finished in about 22 min in the presence of the hollow spheres from aqueous NaBH{sub 4}/NH{sub 3}BH{sub 3} solution. The molar ratio of the hydrolytically generated hydrogen to the initial NH{sub 3}BH{sub 3} in the presence of the hollow spheres is 2.7.

  16. THE COLOUR GLASS CONDENSATE: AN INTRODUCTION

    SciTech Connect (OSTI)

    IANCU,E.; LEONIDOV,A.; MCLERRAN,L.

    2001-08-06

    In these lectures, the authors develop the theory of the Colour Glass Condensate. This is the matter made of gluons in the high density environment characteristic of deep inelastic scattering or hadron-hadron collisions at very high energy. The lectures are self contained and comprehensive. They start with a phenomenological introduction, develop the theory of classical gluon fields appropriate for the Colour Glass, and end with a derivation and discussion of the renormalization group equations which determine this effective theory.

  17. High expansion, lithium corrosion resistant sealing glasses

    DOE Patents [OSTI]

    Brow, R.K.; Watkins, R.D.

    1991-06-04

    Glass compositions containing CaO, Al[sub 2]O[sub 3], B[sub 2]O[sub 3], SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

  18. High expansion, lithium corrosion resistant sealing glasses

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

    1991-01-01

    Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

  19. Equivalence of Glass Transition and Colloidal Glass Transition in the Hard-Sphere Limit Thomas K. Haxton,2

    E-Print Network [OSTI]

    Weeks, Eric R.

    Equivalence of Glass Transition and Colloidal Glass Transition in the Hard-Sphere Limit Ning Xu,1 that the slowing of the dynamics in simulations of several model glass-forming liquids is equivalent to the hard-sphere glass transition in the low-pressure limit. In this limit, we find universal behavior of the relaxation

  20. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

    1995-01-01

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

  1. Hysteretic Optimization For Spin Glasses

    E-Print Network [OSTI]

    B. Goncalves; S. Boettcher

    2007-12-10

    The recently proposed Hysteretic Optimization (HO) procedure is applied to the 1D Ising spin chain with long range interactions. To study its effectiveness, the quality of ground state energies found as a function of the distance dependence exponent, $\\sigma$, is assessed. It is found that the transition from an infinite-range to a long-range interaction at $\\sigma=0.5$ is accompanied by a sharp decrease in the performance . The transition is signaled by a change in the scaling behavior of the average avalanche size observed during the hysteresis process. This indicates that HO requires the system to be infinite-range, with a high degree of interconnectivity between variables leading to large avalanches, in order to function properly. An analysis of the way auto-correlations evolve during the optimization procedure confirm that the search of phase space is less efficient, with the system becoming effectively stuck in suboptimal configurations much earlier. These observations explain the poor performance that HO obtained for the Edwards-Anderson spin glass on finite-dimensional lattices, and suggest that its usefulness might be limited in many combinatorial optimization problems.

  2. High thermal expansion, sealing glass

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); Kovacic, Larry (Albuquerque, NM)

    1993-01-01

    A glass composition for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na.sub.2 O, between about 10 and about 25 mole percent K.sub.2 O, between about 5 and about 15 mole percent Al.sub.2 O.sub.3, between about 35 and about 50 mole percent P.sub.2 O.sub.5 and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe.sub.2 O.sub.3 and between 0 and about 10 mole percent B.sub.2 O.sub.3, has a thermal expansion coefficient in a range of between about 160 and 210.times.10-7/.degree.C. and a dissolution rate in a range of between about 2.times.10.sup.- 7 and 2.times.10.sup.-9 g/cm.sup.2 -min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  3. High thermal expansion, sealing glass

    DOE Patents [OSTI]

    Brow, R.K.; Kovacic, L.

    1993-11-16

    A glass composition is described for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na[sub 2]O, between about 10 and about 25 mole percent K[sub 2]O, between about 5 and about 15 mole percent Al[sub 2]O[sub 3], between about 35 and about 50 mole percent P[sub 2]O[sub 5] and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe[sub 2]O[sub 3] and between 0 and about 10 mole percent B[sub 2]O[sub 3], has a thermal expansion coefficient in a range of between about 160 and 210[times]10[sup [minus]7]/C and a dissolution rate in a range of between about 2[times]10[sup [minus]7] and 2[times]10[sup [minus]9]g/cm[sup 2]-min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  4. Near-wall serpentine cooled turbine airfoil

    DOE Patents [OSTI]

    Lee, Ching-Pang

    2014-10-28

    A serpentine coolant flow path is formed by inner walls in a cavity between pressure and suction side walls of a turbine airfoil, the cavity partitioned by one or more transverse partitions into a plurality of continuous serpentine cooling flow streams each having a respective coolant inlet.

  5. How wood waters down wall insulation

    SciTech Connect (OSTI)

    Lunde, P.J.

    1984-02-01

    Wood framing in walls can lower the actual insulating values, since the R-value of wood is only one per inch of thickness. A chart is presented that shows how wood in the stud space reduces insulating values. Several wall systems and the nominal R-value of insulation for each is presented.

  6. Risk Assessment of Energy-Efficient Walls

    SciTech Connect (OSTI)

    Pallin, Simon B.; Hun, Diana E.; Jackson, Roderick K.; Kehrer, Manfred

    2014-12-01

    This multi-year project aims to provide the residential construction industry with energy-efficient wall designs that are moisture durable. The present work focused on the initial step of this project, which is to develop a moisture durability protocol that identifies energy efficient wall designs that have a low probability of experiencing moisture problems.

  7. Metal stud wall systems -- Thermal disaster, or modern wall systems with highly efficient thermal insulation?

    SciTech Connect (OSTI)

    Kosny, J.; Christian, J.E.; Desjarlais, A.O. [Oak Ridge National Lab., TN (United States). Buildings Technology Center

    1997-11-01

    Because steel has higher thermal conductivity than wood and intense heat transfer occurs through the metal wall components, thermal performances of a metal stud wall are significantly lower than for similar wood stud walls. A reduction of the in-cavity R-value caused by the wood studs is about 10% in wood stud walls. That is why metal stud walls are believed to be considerably less thermally effective than similar made of wood. However, properly designed metal stud walls can be as thermally effective as wood stud walls. Relatively high R-values may be achieved by installing insulating sheathing, which is widely used as a remedy for a weak thermal performance of metal stud walls. A series of the promising metal stud wall configurations is analyzed using results of finite difference computer modeling and guarded hotbox tests. Some of these walls were designed and tested in the ORNL Building Technology Center, some were tested in other laboratories, and some walls were developed and forgotten long time ago. Also, a novel concept of combined foam-metal studs is considered. The main aim of the present paper is to prove that it is possible to build metal stud walls which perform as well as wood stud walls. The key lies in designing; metal stud wall systems have to be treated in a special way with particular consideration to the high thermal conduction of metal components. In the discussed collection of the efficient metal stud wall configurations, reductions of the in-cavity R-value caused by metal studs are between 10 and 20%.

  8. Super-resolution deep imaging with hollow Bessel beam STED microscopy

    E-Print Network [OSTI]

    Yu, Wentao; Dong, Dashan; Yang, Xusan; Xiao, Yunfeng; Gong, Qihuang; Xi, Peng; Shi, Kebin

    2015-01-01

    Stimulated emission depletion (STED) microscopy has become a powerful imaging and localized excitation method beating the diffraction barrier for improved lateral spatial resolution in cellular imaging, lithography, etc. Due to specimen-induced aberrations and scattering distortion, it has been a great challenge for STED to maintain consistent lateral resolution deeply inside the specimens. Here we report on a deep imaging STED microscopy by using Gaussian beam for excitation and hollow Bessel beam for depletion (GB-STED). The proposed scheme shows the improved imaging depth up to ~155{\\mu}m in solid agarose sample, ~115{\\mu}m in PDMS and ~100{\\mu}m in phantom of gray matter in brain tissue with consistent super resolution, while the standard STED microscopy shown a significantly reduced lateral resolution at the same imaging depth. The results indicate the excellent imaging penetration capability of GB-STED, making it a promising tool for deep 3D imaging optical nanoscopy and laser fabrication.

  9. Investigation of a high impedance magnetically insulated transmission line oscillator with hollow load

    SciTech Connect (OSTI)

    Zhou Heng; Shu Ting; Li Zhiqiang [College of Opto-electric Science and Engineering, National University of Defense Technology, Hunan 410073 (China)

    2012-09-15

    A novel high-impedance magnetically insulated transmission line oscillator (MILO) with greatly restrained power deposition on the anode has been investigated. Methods to increase the MILO impedance and decrease the anode current are discussed. A MILO with impedance of 30 {Omega} and power conversion efficiency of 25% is presented by particle-in-cell simulations. Compared with the previous MILO in our lab, the anode current of the proposed MILO is reduced about 50%, the power conversion efficiency doubles, and the power deposition on anode is reduced nearly one half. Furthermore, considerations for reducing the power deposition on load have also been carried out in MILO design, and the load current is reduced to 4.6 kA, only 17% of the total anode current. Finally, a hollow load was introduced to reduce the power deposition density on the load, without decreasing the power conversion efficiency.

  10. Differential high-resolution stimulated CW Raman spectroscopy of hydrogen in a hollow-core fiber

    E-Print Network [OSTI]

    Westergaard, Philip G; Petersen, Jan C

    2015-01-01

    We demonstrate sensitive high-resolution stimulated Raman measurements of hydrogen using a hollow-core photonic crystal fiber (HC-PCF). The Raman transition is pumped by a narrow linewidth (laser. The probe light is produced by a homebuilt CW optical parametric oscillator (OPO), tunable from around 800 nm to 1300 nm (linewidth ~ 5 MHz). These narrow linewidth lasers allow for an excellent spectral resolution of approximately 10^-4 cm^(-1). The setup employs a differential measurement technique for noise rejection in the probe beam, which also eliminates background signals from the fiber. With the high sensitivity obtained, Raman signals were observed with only a few mW of optical power in both the pump and probe beams. This demonstration allows for high resolution Raman identification of molecules and quantification of Raman signal strengths.

  11. Natural glass analogues to alteration of nuclear waste glass: A review and recommendations for further study

    SciTech Connect (OSTI)

    McKenzie, W.F.

    1990-01-01

    The purpose of this report is to review previous work on the weathering of natural glasses; and to make recommendations for further work with respect to studying the alteration of natural glasses as it relates quantifying rates of dissolution. the first task was greatly simplified by the published papers of Jercinovic and Ewing (1987) and Byers, Jercinovic, and Ewing (1987). The second task is obviously the more difficult of the two and the author makes no claim of completeness in this regard. Glasses weather in the natural environment by reacting with aqueous solutions producing a rind of secondary solid phases. It had been proposed by some workers that the thickness of this rind is a function of the age of the glass and thus could be used to estimate glass dissolution rates. However, Jercinovic and Ewing (1987) point out that in general the rind thickness does not correlate with the age of the glass owing to the differences in time of contact with the solution compared to the actual age of the sample. It should be noted that the rate of glass dissolution is also a function of the composition of both the glass and the solution, and the temperature. Quantification of the effects of these parameters (as well as time of contact with the aqueous phase and flow rates) would thus permit a prediction of the consequences of glass-fluid interactions under varying environmental conditions. Defense high- level nuclear waste (DHLW), consisting primarily of liquid and sludge, will be encapsulated by and dispersed in a borosilicate glass before permanent storage in a HLW repository. This glass containing the DHLW serves to dilute the radionuclides and to retard their dispersion into the environment. 318 refs.

  12. Automotion of domain walls for spintronic interconnects

    SciTech Connect (OSTI)

    Nikonov, Dmitri E.; Manipatruni, Sasikanth; Young, Ian A.

    2014-06-07

    We simulate “automotion,” the transport of a magnetic domain wall under the influence of demagnetization and magnetic anisotropy, in nanoscale spintronic interconnects. In contrast to spin transfer driven magnetic domain wall motion, the proposed interconnects operate without longitudinal charge current transfer, with only a transient current pulse at domain wall creation and have favorable scaling down to the 20?nm dimension. Cases of both in-plane and out-of-plane magnetization are considered. Analytical dependence of the velocity of domain walls on the angle of magnetization are compared with full micromagnetic simulations. Deceleration, attenuation and disappearance, and reflection of domain walls are demonstrated through simulation. Dependences of the magnetization angle on the current pulse parameters are studied. The energy and delay analysis suggests that automotion is an attractive option for spintronic logic interconnects.

  13. Gravitational Effects in Supersymmetric Domain Wall Backgrounds

    E-Print Network [OSTI]

    M. Cvetic; S. Griffies

    1992-04-13

    A recent study of supersymmetric domain walls in $N=1$ supergravity theories revealed a new class of domain walls interpolating between supersymmetric vacua with different non-positive cosmological constants. We classify three classes of domain wall configurations and study the geodesic structure of the induced space-time. Motion of massive test particles in such space-times shows that these walls are always repulsive from the anti-deSitter (AdS) side, while on the Minkowski side test particles feel no force. Freely falling particles far away from a wall in an AdS vacuum experience a constant proper acceleration, \\ie\\ they are Rindler particles. A new coordinate system for discussing AdS space-time is presented which eliminates the use of a periodic time-like coordinate.

  14. External Insulation of Masonry Walls and Wood Framed Walls

    SciTech Connect (OSTI)

    Baker, P.

    2013-01-01

    The use of exterior insulation on a building is an accepted and effective means to increase the overall thermal resistance of the assembly that also has other advantages of improved water management and often increased air tightness of building assemblies. For thin layers of insulation (1" to 1 1/2"), the cladding can typically be attached directly through the insulation back to the structure. For thicker insulation layers, furring strips have been added as a cladding attachment location. This approach has been used in the past on numerous Building America test homes and communities (both new and retrofit applications), and has been proven to be an effective and durable means to provide cladding attachment. However, the lack of engineering data has been a problem for many designers, contractors, and code officials. This research project developed baseline engineering analysis to support the installation of thick layers of exterior insulation on existing masonry and frame walls. Furthermore, water management details necessary to integrate windows, doors, decks, balconies and roofs were created to provide guidance on the integration of exterior insulation strategies with other enclosure elements.

  15. External Insulation of Masonry Walls and Wood Framed Walls

    SciTech Connect (OSTI)

    Baker, P.

    2013-01-01

    The use of exterior insulation on a building is an accepted and effective means to increase the overall thermal resistance of the assembly that also has other advantages of improved water management and often increased air tightness of building assemblies. For thin layers of insulation (1” to 1 ˝”), the cladding can typically be attached directly through the insulation back to the structure. For thicker insulation layers, furring strips have been added as a cladding attachment location. This approach has been used in the past on numerous Building America test homes and communities (both new and retrofit applications), and has been proven to be an effective and durable means to provide cladding attachment. However, the lack of engineering data has been a problem for many designers, contractors, and code officials. This research project developed baseline engineering analysis to support the installation of thick layers of exterior insulation on existing masonry and frame walls. Furthermore, water management details necessary to integrate windows, doors, decks, balconies and roofs were created to provide guidance on the integration of exterior insulation strategies with other enclosure elements.

  16. Final Report for "Stabilization of resistive wall modes using moving metal walls"

    SciTech Connect (OSTI)

    Forest, Cary B.

    2014-02-05

    The UW experiment used a linear pinch experiment to study the stabilization of MHD by moving metal walls. The methodology of the experiment had three steps. (1) Identify and understand the no-wall MHD instability limits and character, (2) identify and understand the thin-wall MHD instabilities (re- sistive wall mode), and then (3) add the spinning wall and understand its impact on stability properties. During the duration of the grant we accomplished all 3 of these goals, discovered new physics, and completed the experiment as proposed.

  17. The development of design factors for heat-strengthened and tempered glass based on the glass failure prediction model 

    E-Print Network [OSTI]

    Oakes, Timothy Andrew

    1991-01-01

    - strengthened and tempered glass are then used for determining the design load after the annealed glass design load is calculated. The widely accepted design factors for heat-strengthened and tempered glass are 2. 0 and 4. 0 respectively. The traditional...-STRENGTHENED AND TEMPERED GLASS DESIGN FACTOR TABLES LOWEST FACTOR WITHIN ASPECT RATIO CHARTS . . . . . . . ~ . ~ . ~ 193 VITA 212 LIST OF FIGURES Page Figure 1 Typical stress profile of tempered and heat-strengthened glass Figure 2 Expected wind velocities on a 50...

  18. An Insulating Glass Knowledge Base

    SciTech Connect (OSTI)

    Michael L. Doll; Gerald Hendrickson; Gerard Lagos; Russell Pylkki; Chris Christensen; Charlie Cureija

    2005-08-01

    This report will discuss issues relevant to Insulating Glass (IG) durability performance by presenting the observations and developed conclusions in a logical sequential format. This concluding effort discusses Phase II activities and focuses on beginning to quantifying IG durability issues while continuing the approach presented in the Phase I activities (Appendix 1) which discuss a qualitative assessment of durability issues. Phase II developed a focus around two specific IG design classes previously presented in Phase I of this project. The typical box spacer and thermoplastic spacer design including their Failure Modes and Effect Analysis (FMEA) and Fault Tree diagrams were chosen to address two currently used IG design options with varying components and failure modes. The system failures occur due to failures of components or their interfaces. Efforts to begin quantifying the durability issues focused on the development and delivery of an included computer based IG durability simulation program. The focus/effort to deliver the foundation for a comprehensive IG durability simulation tool is necessary to address advancements needed to meet current and future building envelope energy performance goals. This need is based upon the current lack of IG field failure data and the lengthy field observation time necessary for this data collection. Ultimately, the simulation program is intended to be used by designers throughout the current and future industry supply chain. Its use is intended to advance IG durability as expectations grow around energy conservation and with the growth of embedded technologies as required to meet energy needs. In addition the tool has the immediate benefit of providing insight for research and improvement prioritization. Included in the simulation model presentation are elements and/or methods to address IG materials, design, process, quality, induced stress (environmental and other factors), validation, etc. In addition, acquired data is presented in support of project and model assumptions. Finally, current and suggested testing protocol and procedure for future model validation and IG physical testing are discussed.

  19. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    SciTech Connect (OSTI)

    Kruger, A.A.

    1995-01-01

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

  20. Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics

    SciTech Connect (OSTI)

    Sathish, M.; Eraiah, B.

    2014-04-24

    Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400°C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

  1. INTRINSIC DOSIMETRY: PROPERTIES AND MECHANISMS OF THERMOLUMINESCENCE IN COMMERCIAL BOROSILICATE GLASS

    SciTech Connect (OSTI)

    Clark, Richard A.

    2012-10-24

    Intrinsic dosimetry is the method of measuring total absorbed dose received by the walls of a container holding radioactive material. By considering the total absorbed dose received by a container in tandem with the physical characteristics of the radioactive material housed within that container, this method has the potential to provide enhanced pathway information regarding the history of the container and its radioactive contents. The latest in a series of experiments designed to validate and demonstrate this newly developed tool are reported. Thermoluminescence (TL) dosimetry was used to measure dose effects on raw stock borosilicate container glass up to 70 days after gamma ray, x-ray, beta particle or ultraviolet irradiations at doses from 0.15 to 20 Gy. The TL glow curve when irradiated with 60Co was separated into five peaks: two relatively unstable peaks centered near 120 and 165°C, and three relatively stable peaks centered near 225, 285, and 360°C. Depending on the borosilicate glass source, the minimum measurable dose using this technique is 0.15-0.5 Gy, which is roughly equivalent to a 24 hr irradiation at 1 cm from a 50-165 ng source of 60Co. Differences in TL glow curve shape and intensity were observed for the glasses from different geographical origins. These differences can be explained by changes in the intensities of the five peaks. Electron paramagnetic resonance (EPR) and multivariate statistical methods were used to relate the TL intensity and peaks to electron/hole traps and compositional variations.

  2. Why Walls Don't Work, by Michael Dear

    E-Print Network [OSTI]

    De Leo, Daniela

    2013-01-01

    the role of the wall as a power device does not allow for anat that. Walls work by serving as devices of power—devicessense, the wall can be understood as a device of power that

  3. Seismic design, testing and analysis of reinforced concrete wall buildings

    E-Print Network [OSTI]

    Panagiotou, Marios

    2008-01-01

    In Phase II the main load bearing wall was reconfigured as aIn Phase II the main load bearing wall was reconfigured as aa rectangular load bearing wall acting as the main lateral

  4. Generation of Bright, Spatially Coherent Soft X-Ray High Harmonics in a Hollow Waveguide Using Two-Color Synthesized Laser Pulses

    E-Print Network [OSTI]

    Jin, Cheng

    We investigate the efficient generation of low-divergence high-order harmonics driven by waveform-optimized laser pulses in a gas-filled hollow waveguide. The drive waveform is obtained by synthesizing two-color laser ...

  5. GLASS AND GLASS-DERIVATIVE SEALS FOR USE IN ENERGY-EFFICIENT FUEL CELLS AND LAMPS

    SciTech Connect (OSTI)

    Scott Misture; Arun Varshneya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

    2004-08-15

    As the project approaches the end of the first year, the materials screening components of the work are ahead of schedule, while all other tasks are on schedule. For solid oxide fuel cells (SOFC), a series of 16 sealing glasses have been prepared and characterized. Traditional melting was used to prepare all of the glasses, and the sol-gel approach has been used to prepare some of the glasses as well as other compositions that might be viable because of the low processing temperatures afforded by the sol-gel method. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. Room temperature leak testing has been completed for all sealants, and experiments are in progress to determine the DC electrochemical degradation and degradation in wet hydrogen. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria--alumina--silica system at various silica levels. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. High temperature diffraction and annealing studies have clarified the phase relations for the samples studies, although additional work remains. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase. Functional testing of lamps are on on-going and will be analyzed during year 2 of the contract.

  6. Measurement and Control of Glass Feedstocks

    SciTech Connect (OSTI)

    Arel Weisberg

    2007-04-26

    ERCo has developed a laser-based technology for rapid compositional measurements of batch, real-time sorting of cullet, and in-situ measurements of molten glass. This technology, termed LIBS (Laser Induced Breakdown Spectroscopy) can determine whether or not the batch was formulated accurately in order to control glass quality. It can also be used to determine if individual batch ingredients are within specifications. In the case of cullet feedstocks, the sensor can serve as part of a system to sort cullet by color and ensure that it is free of contaminants. In-situ compositional measurements of molten glass are achieved through immersing a LIBS probe directly into the melt in a glass furnace. This technology has been successfully demonstrated in ERCo’s LIBS laboratory for batch analysis, cullet sorting, and glass melt measurements. A commercial batch analyzer has been operating in a PPG fiberglass plant since August 2004. LIBS utilizes a highly concentrated laser pulse to rapidly vaporize and ionize nanograms of the material being studied. As this vapor cools, it radiates light at specific wavelengths corresponding to the elemental constituents (e.g. silicon, aluminum, iron) of the material. The strengths of the emissions correlate to the concentrations of each of the elemental constituents. By collecting the radiated light with a spectrometer capable of resolving and measuring these wavelengths, the elemental composition of the sample is found.

  7. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

    1997-01-01

    Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

  8. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  9. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2000-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  10. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

    1997-07-15

    Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B{sub 2}O{sub 3}), barium oxide (BaO), lanthanum oxide (La{sub 2}O{sub 3}), and at least one other oxide selected from the group consisting of aluminum oxide (Al{sub 2}O{sub 3}), calcium oxide (CaO), lithium oxide (Li{sub 2}O), sodium oxide (Na{sub 2}O), silicon dioxide (SiO{sub 2}), or titanium dioxide (TiO{sub 2}). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900 C, and generally about 700--800 C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 1 fig.

  11. GLASS FORMULATION FOR INEEL SODIUM BEARING WASTE

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Peeler, David K.

    2002-10-31

    Studies were performed to develop and test a glass formulation for immobilization of sodium-bearing waste (SBW), which is a high soda, acidic, high-activity waste stored at the Idaho National Engineering and Environmental Laboratory (INEEL) in 10 underground tanks. It was determined in previous studies that SBW?s sulfur content dictates its loading in borosilicate glasses to be melted by currently assumed processes. If the sulfur content (which is ~4.5 mass% SO3 on a non-volatile oxide basis in SBW) of the melter feed is too high, then a molten, alkali-sulfate-containing salt phase accumulates on the melt surface. The avoidance of salt accumulation during the melter process and the maximization of sulfur incorporation into the glass melt were the main focus of this development work. A glass was developed for 20 mass% SBW (on a non-volatile oxide basis), which contained 0.91 mass% SO3, that met all the processing and product-quality constraints determined for SBW vitrification at a planned INEEL treatment plant?SBW-22-20. This paper summarizes the formulation efforts and presents the data developed on a series of glasses with simulated SBW.

  12. Mathematical modeling of liquid/liquid hollow fiber membrane contactor accounting for interfacial transport phenomena: Extraction of lanthanides as a surrogate for actinides

    SciTech Connect (OSTI)

    Rogers, J.D.

    1994-08-04

    This report is divided into two parts. The second part is divided into the following sections: experimental protocol; modeling the hollow fiber extractor using film theory; Graetz model of the hollow fiber membrane process; fundamental diffusive-kinetic model; and diffusive liquid membrane device-a rigorous model. The first part is divided into: membrane and membrane process-a concept; metal extraction; kinetics of metal extraction; modeling the membrane contactor; and interfacial phenomenon-boundary conditions-applied to membrane transport.

  13. Research and development of new ultraphosphate laser glasses

    SciTech Connect (OSTI)

    Izumitani, T.; Toratani, H.; Matsukawa, T.; Kanamori, C.; Miyade, H.

    1985-01-30

    Requirements for Zeus laser glass and HAP laser glass were small {sigma}, low water, low concentration quenching and high mechanical and thermal strength in the former and high {sigma}, low water, low concentration quenching and high mechanical, thermal shock resistance in the later. In order to get a high mechanical and thermal shock resistance, we introduced SiO{sub 2} into phosphate glass, because SiO{sub 2} gives a low expansion coefficient. In this report, we discuss the research and development of the laser glass. Chemical durability, water content, lasing properties, mechanical and thermo-mechanical properties, glass composition and glass structures are discussed.

  14. Advanced High Porosity Ceramic Honeycomb Wall Flow Filters |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Porosity Ceramic Honeycomb Wall Flow Filters Advanced High Porosity Ceramic Honeycomb Wall Flow Filters 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

  15. Building America Special Research Project: High-R Walls Case...

    Office of Environmental Management (EM)

    Building America Special Research Project: High-R Walls Case Study Analysis Building America Special Research Project: High-R Walls Case Study Analysis This report considers a...

  16. Transglucosylation of cell wall polysaccharides in equisetum fluviatile. 

    E-Print Network [OSTI]

    Mohler, Kyle Edward

    2012-06-22

    Plant cell walls determine cellular shape and provide structural support for the entire plant. Polysaccharides, comprising the major components of the wall, are actively remodelled throughout development. Xyloglucan ...

  17. Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells Home > Research > ANSER Research Highlights > Sorted Single-Walled Carbon Nanotube...

  18. Kirkendall-effect-based growth of dendrite-shaped CuO hollow micro/nanostructures for lithium-ion battery anodes

    SciTech Connect (OSTI)

    Hu Yingying, E-mail: yyhu@phy.ccnu.edu.c [Center for Nanoscience and Nanotechnology, Huazhong Normal University, Wuhan 430079, Hubei (China); Huang Xintang, E-mail: xthuang@phy.ccnu.edu.c [Center for Nanoscience and Nanotechnology, Huazhong Normal University, Wuhan 430079, Hubei (China); Wang Kai; Liu Jinping; Jiang Jian; Ding Ruimin; Ji Xiaoxu; Li Xin [Center for Nanoscience and Nanotechnology, Huazhong Normal University, Wuhan 430079, Hubei (China)

    2010-03-15

    Three-dimensional (3D) dendrite-shaped CuO hollow micro/nanostructures have been prepared via a Kirkendall-effect-based approach for the first time and have been demonstrated as a high-performance anode material for lithium-ion batteries. The as-prepared hollow structures were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and electrochemical properties. A CuO hollow structure composed of nanocubes outside and a dense film inside was selected as a typical example of the optimized design; it exhibited significantly improved cyclability at a current rate of 0.5 C, with the average Coulombic efficiency of {approx}97.0% and 57.9% retention of the discharge capacity of the second cycle after 50 cycles. The correlation between the structure features of the hollow CuO and their electrochemical behavior was discussed in detail. Smaller size of primary structure and larger internal space of electrode materials are crucial to better electrochemical performance. This work represents that Kirkendall effect is a promising method to fabricate excellent hollow electrode materials for Li-ion batteries. - Graphical abstract: SEM images of 3D dendrite-shaped CuO hollow micro/nanostructures prepared via a Kirkendall-effect-based approach have been shown. The as-prepared CuO electrode exhibited significantly improved cyclability for Li-ion batteries.

  19. Glass/ceramic coatings for implants

    DOE Patents [OSTI]

    Tomsia, Antoni P. (Pinole, CA); Saiz, Eduardo (Berkeley, CA); Gomez-Vega, Jose M. (Nagoya, JP); Marshall, Sally J. (Larkspur, CA); Marshall, Grayson W. (Larkspur, CA)

    2011-09-06

    Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

  20. Opal photonic crystals infiltrated with chalcogenide glasses

    SciTech Connect (OSTI)

    Astratov, V. N.; Adawi, A. M.; Skolnick, M. S.; Tikhomirov, V. K.; Lyubin, V.; Lidzey, D. G.; Ariu, M.; Reynolds, A. L.

    2001-06-25

    Composite opal structures for nonlinear applications are obtained by infiltration with chalcogenide glasses As{sub 2}S{sub 3} and AsSe by precipitation from solution. Analysis of spatially resolved optical spectra reveals that the glass aggregates into submillimeter areas inside the opal. These areas exhibit large shifts in the optical stop bands by up to 80 nm, and by comparison with modelling are shown to have uniform glass filling factors of opal pores up to 40%. Characterization of the domain structure of the opals prior to infiltration by large area angle-resolved spectroscopy is an important step in the analysis of the properties of the infiltrated regions. {copyright} 2001 American Institute of Physics.

  1. Glass Frit Clumping And Dusting

    SciTech Connect (OSTI)

    Steimke, J. L.

    2013-09-26

    DWPF mixes a slurry of glass frit (Frit 418) and dilute (1.5 wt%) formic acid solution with high level waste in the Slurry Mix Evaporator (SME). There would be advantages to introducing the frit in a non-slurry form to minimize water addition to the SME, however, adding completely dry frit has the potential to generate dust which could clog filters or condensers. Prior testing with another type of frit, Frit 320, and using a minimal amount of water reduced dust generation, however, the formation of hard clumps was observed. To examine options and behavior, a TTQAP [McCabe and Stone, 2013] was written to initiate tests that would address these concerns. Tests were conducted with four types of glass frit; Frit 320, DWPF Frit 418, Bekeson Frit 418 and Multi-Aspirator Frit 418. The last two frits are chemically identical to DWPF Frit 418 but smaller particles were removed by the respective vendors. Test results on Frit Clumping and Dusting are provided in this report. This report addresses the following seven questions. Short answers are provided below with more detailed answers to follow. 1. Will the addition of a small amount of water, 1.5 wt%, to dry DWPF Frit 418 greatly reduce the dust generation during handling at DWPF? a. Yes, a small scale test showed that adding a little water to the frit greatly reduced dust generation during handling. 2. Will the addition of small amounts of water to the frit cause clumping that will impair frit handling at DWPF? a. No, not with Frit 418. Although clumps were observed to form when 1.5 wt% water was mixed with DWPF Frit 418, then compressed and air-dried overnight, the clumps were easily crushed and did not form the hardened material noted when Frit 320 was tested. 3. What is the measured size distribution of dust generated when dry frit is handled? (This affects the feasibility and choice of processing equipment for removing the dust generating fraction of the frit before it is added to the SME.) a. The size distribution for the dust removed from fresh DWPF Frit 418 while it was being shaken in a small scale LabRAM test was measured. The median size on a volume basis was 7.6 ?m and 90% of the frit particles were between 1.6 and 28 ?m. The mass of dust collected using this test protocol was much less than 1% of the original frit. 4. Can the dust be removed in a small number of processing steps and without the larger frit particles continuing to spall additional dust sized particles? a. Test results using a LabRAM were inconclusive. The LaRAM performs less efficient particle size separation than the equipment used by Bekeson and Multi-Aspirator. 5. What particle size of frit is expected to create a dust problem? a. The original criterion for creating a dusting problem was those particle sizes that were readily suspended when being shaken. For that criterion calculations and Microtrac size analyses indicated that particles smaller than 37 ?m are likely dust generators. Subsequently a more sophisticated criterion for dust problem was considered, particle sizes that would become suspended in the air flow patterns inside the SME and possibly plug the condenser. That size may be larger than 37 ?m but has not yet been determined. 6. If particles smaller than 37 ?m are removed will bulk dust generation be eliminated? a. Video-taped tests were performed using three gallons each of three types of frit 418, DWPF frit, Bekeson frit and Multi-Aspirator frit. Frit was poured through air from a height of approximately eight feet into a container half filled with water. Pouring Bekeson frit or Multi-Aspirator frit generated markedly less visible dust, but there was still a significant amount, which still has the potential of causing a dust problem. 7. Can completely dry frit be poured into the SME without having dust plug the condenser at the top of the vessel? a. Because of the complexity of air currents inside the SME and the difficulty of defensible size scaling a more prototypical test will be required to answer this question. We recommend construction of a full scale

  2. Dual wall reverse circulation drilling with multi-level groundwater sampling for groundwater contaminant plume delineation at Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Smuin, D.R.; Morti, E.E.; Zutman, J.L.; Pickering, D.A.

    1995-08-01

    Dual wall reverse circulation (DWRC) drilling was used to drill 48 borings during a groundwater contaminant investigation at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky. This method was selected as an alternative to conventional hollow stem auger drilling for a number of reasons, including the expectation of minimizing waste, increasing the drilling rate, and reducing the potential for cross contamination of aquifers. Groundwater samples were collected from several water-bearing zones during drilling of each borehole. The samples were analyzed for volatile organic compounds using a field gas chromatograph. This approach allowed the investigation to be directed using near-real-time data. Use of downhole geophysical logging, in conjunction with lithologic descriptions of borehole cuttings, resulted in excellent correlation of the geology in the vicinity of the contaminant plume. The total volume of cuttings generated using the DWRC drilling method was less than half of what would have been produced by hollow stem augering; however, the cuttings were recovered in slurry form and had to be dewatered prior to disposal. The drilling rate was very rapid, often approaching 10 ft/min; however, frequent breaks to perform groundwater sampling resulted in an average drilling rate of < 1 ft/min. The time required for groundwater sampling could be shortened by changing the sampling methodology. Analytical results indicated that the drilling method successfully isolated the various water bearing zones and no cross contamination resulted from the investigation.

  3. GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE GLASS FOR PLUTONIUM DISPOSITION

    SciTech Connect (OSTI)

    Crawford, C; James Marra, J; Ned Bibler, N

    2007-02-12

    The Department of Energy Office of Environmental Management (DOE/EM) plans to conduct the Plutonium Disposition Project at the Savannah River Site (SRS) in Aiken, SC, to disposition excess weapons-usable plutonium. A plutonium glass waste form is a leading candidate for immobilization of the plutonium for subsequent disposition in a geologic repository. The objectives of this present task were to fabricate plutonium-loaded lanthanide borosilicate (LaBS) Frit B glass and perform testing to provide near-term data that will increase confidence that LaBS glass product is suitable for disposal in the proposed Federal Repository. Specifically, testing was conducted in an effort to provide data to Yucca Mountain Project (YMP) personnel for use in performance assessment calculations. Plutonium containing LaBS glass with the Frit B composition with a 9.5 wt% PuO{sub 2} loading was prepared for testing. Glass was prepared to support glass durability testing via the ASTM Product Consistency Testing (PCT) at Savannah River National Laboratory (SRNL). The glass was characterized with X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) prior to performance testing. This characterization revealed some crystalline PuO{sub 2} inclusions with disk-like morphology present in the as fabricated, quench-cooled glass. A series of PCTs was conducted at SRNL with varying exposed surface area and test durations. Filtered leachates from these tests were analyzed to determine the dissolved concentrations of key elements. The leachate solutions were also ultrafiltered to quantify colloid formation. Leached solids from select PCTs were examined in an attempt to evaluate the Pu and neutron absorber release behavior from the glass and to investigate formation of alteration phases on the glass surface. A series of PCTs was conducted at 90 C in ASTM Type 1 water to compare the Pu LaBS Frit B glass durability to current requirements for High Level Waste (HLW) glass in a geologic repository. The PCT (7-day static test with powdered glass) results on the Pu-containing LaBS Frit B glass at SA/V of {approx} 2000 m{sup -1} showed that the glass was very durable with an average normalized elemental release value for boron of 0.013 g/m{sup 2}. This boron release value is {approx} 640X lower than normalized boron release from current Environmental Assessment (EA) glass used for repository acceptance. The PCT-B (7, 14, 28 and 56-day, static test with powdered glass) normalized elemental releases were similar to the normalized elemental release values from PCT-A testing, indicating that the LaBS Frit B glass is very durable as measured by the PCT. Normalized plutonium releases were essentially the same within the analytical uncertainty of the ICP-MS methods used to quantify plutonium in the 0.45 {micro}m-filtered leachates and ultra-filtered leachates, indicating that colloidal plutonium species do not form under the PCT conditions used in this study.

  4. Direction of CRT waste glass processing: Electronics recycling industry communication

    SciTech Connect (OSTI)

    Mueller, Julia R., E-mail: mueller.143@osu.edu [Ohio State University, William G. Lowrie Department of Chemical and Biomolecular Engineering, OH (United States) and University of Queensland, School of Chemical Engineering (Australia) and Ohio State University, Materials Science and Engineering, OH (United States); Boehm, Michael W. [University of Queensland, School of Chemical Engineering (Australia); Drummond, Charles [Ohio State University, Materials Science and Engineering, OH (United States)

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer Given a large flow rate of CRT glass {approx}10% of the panel glass stream will be leaded. Black-Right-Pointing-Pointer The supply of CRT waste glass exceeded demand in 2009. Black-Right-Pointing-Pointer Recyclers should use UV-light to detect lead oxide during the separation process. Black-Right-Pointing-Pointer Recycling market analysis techniques and results are given for CRT glass. Black-Right-Pointing-Pointer Academic initiatives and the necessary expansion of novel product markets are discussed. - Abstract: Cathode Ray Tube, CRT, waste glass recycling has plagued glass manufacturers, electronics recyclers and electronics waste policy makers for decades because the total supply of waste glass exceeds demand, and the formulations of CRT glass are ill suited for most reuse options. The solutions are to separate the undesirable components (e.g. lead oxide) in the waste and create demand for new products. Achieving this is no simple feat, however, as there are many obstacles: limited knowledge of waste glass composition; limited automation in the recycling process; transportation of recycled material; and a weak and underdeveloped market. Thus one of the main goals of this paper is to advise electronic glass recyclers on how to best manage a diverse supply of glass waste and successfully market to end users. Further, this paper offers future directions for academic and industry research. To develop the recommendations offered here, a combination of approaches were used: (1) a thorough study of historic trends in CRT glass chemistry; (2) bulk glass collection and analysis of cullet from a large-scale glass recycler; (3) conversations with industry members and a review of potential applications; and (4) evaluation of the economic viability of specific uses for recycled CRT glass. If academia and industry can solve these problems (for example by creating a database of composition organized by manufacturer and glass source) then the reuse of CRT glass can be increased.

  5. Structure of rhenium-containing sodium borosilicate glass

    SciTech Connect (OSTI)

    Goel, Ashutosh; McCloy, John S.; Windisch, Charles F.; Riley, Brian J.; Schweiger, Michael J.; Rodriguez, Carmen P.; Ferreira, Jose M.

    2013-03-01

    A series of sodium borosilicate glasses were synthesized with increasing fractions of KReO4 or Re2O7, to 10000 ppm (1 mass%) target Re in glass, to assess the effects of large concentrations of rhenium on glass structure and to estimate the solubility of technetium, a radioactive component in typical low active waste nuclear waste glasses. Magic angle spinning nuclear magnetic resonance (MAS-NMR), Fourier transform infrared (FTIR) spectroscopy, and Raman spectroscopy were performed to characterize the glasses as a function of Re source additions. In general, silicon was found coordinated in a mixture of Q2 and Q3 structural units, while Al was 4-coordinated and B was largely 3-coordinate and partially 4-coordinated. The rhenium source did not appear to have significant effects on the glass structure. Thus, at the up to the concentrations that remain in dissolved in glass, ~3000 ppm Re by mass maximum. , the Re appeared to be neither a glass-former nor a strong glass modifier., Rhenium likely exists in isolated ReO4- anions in the interstices of the glass network, as evidenced by the polarized Raman spectrum of the Re glass in the absence of sulfate. Analogous to SO42-¬ in similar glasses, ReO4- is likely a network modifier and forms alkali salt phases on the surface and in the bulk glass above solubility.

  6. A SURVEY OF WALL'S FINITENESS OBSTRUCTION 

    E-Print Network [OSTI]

    Ferry, Steve; Ranicki, Andrew

    2000-01-01

    Wall's finiteness obstruction is an algebraic K-theory invariant which decides if a finitely dominated space is homotopy equivalent to a finite CW complex. The invariant was originally formulated in the context of surgery ...

  7. Wall Drying in Hot and Humid Climates 

    E-Print Network [OSTI]

    Boone, K.; Weston, T.; Pascual, X.

    2004-01-01

    's ability to dry is not considered during the design or material selection process. No cladding system or installation is perfect, therefore wall systems should be designed with the assumption that some moisture will enter and then consider the effects...

  8. Perforation of domain wall by point mass

    E-Print Network [OSTI]

    D. V. Gal'tsov; E. Yu. Melkumova; P. A. Spirin

    2013-12-30

    We investigate collision of a point particle and an infinitely thin planar domain wall interacting gravitationally within the linearized gravity in Minkowski space-time of arbitrary dimension. In this setting we are able to describe analytically the perforation of the wall by an impinging particle, showing that it is accompanied by excitation of the spherical shock branon wave propagating outwards with the speed of light. Formally, the shock wave is a free solution of the branon wave equation which has to be added to ensure the validity of the retarded solution at the perforation point. Physically, the domain wall gets excited due to the shake caused by an instantaneous change of sign of the repulsive gravitational force. This effect is shown to hold, in particular, in four space-time dimensions, being applicable to the problem of cosmological domain walls.

  9. Perforation of domain wall by point mass

    E-Print Network [OSTI]

    Gal'tsov, D V; Spirin, P A

    2013-01-01

    We investigate collision of a point particle and an infinitely thin planar domain wall interacting gravitationally within the linearized gravity in Minkowski space-time of arbitrary dimension. In this setting we are able to describe analytically the perforation of the wall by an impinging particle, showing that it is accompanied by excitation of the spherical shock branon wave propagating outwards with the speed of light. Formally, the shock wave is a free solution of the branon wave equation which has to be added to ensure the validity of the retarded solution at the perforation point. Physically, the domain wall gets excited due to the shake caused by an instantaneous change of sign of the repulsive gravitational force. This effect is shown to hold, in particular, in four space-time dimensions, being applicable to the problem of cosmological domain walls.

  10. PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS

    SciTech Connect (OSTI)

    Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

    2011-01-04

    The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The incorporation of 1 wt % Pu in the glass did not adversely impact glass viscosity (as assessed using Hf surrogate) or glass durability. Finally, evaluation of DWPF glass pour samples that had Pu concentrations below the 897 g/m{sup 3} limit showed that Pu concentrations in the glass pour stream were close to targeted compositions in the melter feed indicating that Pu neither volatilized from the melt nor stratified in the melter when processed in the DWPF melter.

  11. Synthesis of Submicrometer-Sized CdS Hollow Spheres in Aqueous Solutions of a Triblock Copolymer

    E-Print Network [OSTI]

    Qi, Limin

    of surfactant and double-hydrophilic block copolymer can be used as effective soft templates for the synthesis copolymer EO20PO70EO20 (P123) at room temperature through the slow release of S2- ions from thioacetamide),UV-visabsorption,andphotoluminescence(PL)spectroscopyhavebeenusedforthecharacterization of the obtained hollow CdS spheres. It has been revealed that a minimum concentration of the polymer P123

  12. Electric and Magnetic Walls on Dielectric Interfaces

    E-Print Network [OSTI]

    Changbiao Wang

    2010-07-20

    Sufficient conditions of the existence of electric or magnetic walls on dielectric interfaces are given for a multizone uniform dielectric waveguiding system. If one of two adjacent dielectric zones supports a TEM field distribution while the other supports a TM (TE) field distribution, then the common dielectric interface behaves as an electric (magnetic) wall, that is, the electric (magnetic) field line is perpendicular to the interface while the magnetic (electric) field line is parallel to the interface.

  13. Thin Wall Cast Iron: Phase II

    SciTech Connect (OSTI)

    Doru M. Stefanescu

    2005-07-21

    The development of thin-wall technology allows the designers of energy consuming equipment to select the most appropriate material based on cost/material properties considerations, and not solely on density. The technology developed in this research project will permit the designers working for the automotive industry to make a better informed choice between competing materials and thin wall cast iron, thus decreasing the overall cost of the automobile.

  14. Thermally Activated Processes in Polymer Glasses

    E-Print Network [OSTI]

    V. Parihar; D. Drosdoff; A. Widom; Y. N. Srivastava

    2005-12-03

    A derivation is given for the Vogel-Fulcher-Tammann thermal activation law for the glassy state of a bulk polymer. Our microscopic considerations involve the entropy of closed polymer molecular chains (i.e. polymer closed strings). For thin film polymer glasses, one obtains open polymer strings in that the boundary surfaces serve as possible string endpoint locations. The Vogel-Fulcher-Tammann thermal activation law thereby holds true for a bulk polymer glass but is modified in the neighborhood of the boundaries of thin film polymers.

  15. Two glass transitions in miscible polymer blends?

    SciTech Connect (OSTI)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-06-28

    In contrast to mixtures of two small molecule fluids, miscible binary polymer blends often exhibit two structural relaxation times and two glass transition temperatures. Qualitative explanations postulate phenomenological models of local concentration enhancements due to chain connectivity in ideal, fully miscible systems. We develop a quantitative theory that explains qualitative trends in the dynamics of real miscible polymer blends which are never ideal mixtures. The theory is a synthesis of the lattice cluster theory of blend thermodynamics, the generalized entropy theory for glass-formation in polymer materials, and the Kirkwood-Buff theory for concentration fluctuations in binary mixtures.

  16. Nonlinear mechanics of thermoreversibly associating dendrimer glasses

    E-Print Network [OSTI]

    Arvind Srikanth; Robert S. Hoy; Berend C. Rinderspacher; Jan W. Andzelm

    2013-08-06

    We model the mechanics of associating trivalent dendrimer network glasses with a focus on their energy dissipation properties. Various combinations of sticky bond (SB) strength and kinetics are employed. The toughness (work-to-fracture) of these systems displays a surprising deformation-protocol dependence; different association parameters optimize different properties. In particular, "strong, slow" SBs optimize strength, while "weak, fast" SBs optimize ductility via self-healing during deformation. We relate these observations to breaking, reformation, and partner-switching of SBs during deformation. These studies point the way to creating associating-polymer network glasses with tailorable mechanical properties.

  17. Energy Assessment Protocol for Glass Furnaces 

    E-Print Network [OSTI]

    Plodinec, M. J.; Kauffman, B. M.; Norton, O. P.; Richards, C.; Connors, J.; Wishnick, D.

    2005-01-01

    of the protocol are implemented, resulting in cost savings of greater than $200,000 per year. PROJECT OVERVIEW The glass industry is a major energy consumer. Depending on the market sector, a glass furnace heated by oxy-fuel burners may use from 3..., the manufacturer of the burners used in the PPG furnace, brought extensive field experience to the team, as well as in-depth knowledge of burner performance. ENERGY ASSESSMENT PROTOCOL The project team developed the protocol based on DIAL, Eclipse and PPG...

  18. Scaling of fluctuations in a colloidal glass

    E-Print Network [OSTI]

    P. Wang; C. Song; H. A. Makse

    2006-11-01

    We report experimental measurements of particle dynamics in a colloidal glass in order to understand the dynamical heterogeneities associated with the cooperative motion of the particles in the glassy regime. We study the local and global fluctuation of correlation and response functions in an aging colloidal glass. The observables display universal scaling behavior following a modified power-law, with a plateau dominating the less heterogeneous short-time regime and a power-law tail dominating the highly heterogeneous long-time regime.

  19. Glass Mountain Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEniaElectric Jump to:GerGlacialGlacialGlass ButtesGlass

  20. Chaotic Transitions in Wall Following Robots

    E-Print Network [OSTI]

    Harry W. Bullen IV; Priya Ranjan

    2009-08-25

    In this paper we examine how simple agents similar to Braitenberg vehicles can exhibit chaotic movement patterns. The agents are wall following robots as described by Steve Mesburger and Alfred Hubler in their paper "Chaos in Wall Following Robots". These agents uses a simple forward facing distance sensor, with a limited field of view "phi" for navigation. An agent drives forward at a constant velocity and uses the sensor to turn right when it is too close to an object and left when it is too far away. For a flat wall the agent stays a fixed distance from the wall and travels along it, regardless of the sensor's capabilities. But, if the wall represents a periodic function, the agent drives on a periodic path when the sensor has a narrow field of view. The agent's trajectory transitions to chaos when the sensor's field of view is increased. Numerical experiments were performed with square, triangle, and sawtooth waves for the wall, to find this pattern. The bifurcations of the agents were analyzed, finding both border collision and period doubling bifurcations. Detailed experimental results will be reported separately.

  1. Direct measurements of growing amorphous order and non-monotonic dynamic correlations in a colloidal glass-former

    E-Print Network [OSTI]

    K. Hima Nagamanasa; Shreyas Gokhale; A. K. Sood; Rajesh Ganapathy

    2014-08-23

    While the transformation of flowing liquids into rigid glasses is omnipresent, a complete understanding of vitrification remains elusive. Of the numerous approaches aimed at solving the glass transition problem, the Random First-Order Theory (RFOT) is the most prominent. However, the existence of the underlying thermodynamic phase transition envisioned by RFOT remains debatable, since its key microscopic predictions concerning the growth of amorphous order and the nature of dynamic correlations lack experimental verification. Here, by using holographic optical tweezers, we freeze a wall of particles in an equilibrium configuration of a 2D colloidal glass-forming liquid and provide direct evidence for growing amorphous order in the form of a static point-to-set length. Most remarkably, we uncover the non-monotonic dependence of dynamic correlations on area fraction and show that this non-monotonicity follows directly from the change in morphology of cooperatively rearranging regions, as predicted by RFOT. Our findings suggest that the glass transition has a thermodynamic origin.

  2. Temperature and number evolution of cold cesium atoms inside a glass cell

    E-Print Network [OSTI]

    Huang, J Q; Wang, S G; Wang, Z B; Wang, L J

    2015-01-01

    We report an experimental study on the temperature and number evolution of the cold cesium atoms diffusively cooled inside a wall-coated glass cell by measuring the absorption profile of the 62S1/2 (F=4)-62P3/2 (F'=5) transition line with a weak probe laser in the evolution process. We found that the temperature of the cold atoms first gradually decreases from 16 mK to 9 mK, and then rapidly increases. A theoretical model of the number evolution is built, which includes the temperature of the cold atoms and the fraction p of the cold cesium atoms elastically reflected by the cell wall. The theoretical model is consistent with the experimental result very well, and the fraction p is obtained to be (0.58 +/- 0.03), which reveals that the cold cesium atoms are not all heated to the ambient temperature by a single collision with the cell wall.

  3. Radiative Heat Transfer in Enhanced Hydrogen Outgassing of Glass

    E-Print Network [OSTI]

    Kitamura, Rei; Pilon, Laurent

    2009-01-01

    reduction of iron in soda-lime-silicate glasses by reactionand solubility [13]. In soda-lime silicate glass, Johnston0.4 and 0.8 µm for soda-lime silicate. Rapp [9] con?rmed

  4. Effect of furnace atmosphere on E-glass foaming

    E-Print Network [OSTI]

    Kim, D. S.; Dutton, Bryan C.; Hrma, Pavel R.; Pilon, Laurent

    2006-01-01

    on soda-silicate or soda-lime- silicate melts [2-5,9], or on6]. However, even for soda- lime glasses and metallurgicalon the foaming of soda-lime glass batch in air atmospheres

  5. Thermal Analysis of Waste Glass Batches: Effect of Batch Makeup...

    Office of Scientific and Technical Information (OSTI)

    Book: Thermal Analysis of Waste Glass Batches: Effect of Batch Makeup on Gas-Evolving Reactions Citation Details In-Document Search Title: Thermal Analysis of Waste Glass Batches:...

  6. Combustion Technology Development for an Advanced Glass Melting System 

    E-Print Network [OSTI]

    Stickler, D. B.; Westra, L.; Woodroffe, J.; Jeong, K. M.; Donaldson, L. W.

    1987-01-01

    Concept feasibility of an innovative technology for glass production has recently been demonstrated. It is based on suspension heating of the glass-forming batch minerals while entrained in a combustion flow of preheated air and natural gas...

  7. A user interface for customizing cane layouts in Virtual Glass

    E-Print Network [OSTI]

    Baldauf, Kimberly (Kimberly B.)

    2013-01-01

    Cane pulling is a technique used in glass blowing to build up intricate patterns which come out in the final piece. Virtual Glass was created to model the cane pulling process from start to finish. There are a variety of ...

  8. Electrical and optical properties of vanadium tellurite glasses 

    E-Print Network [OSTI]

    Flynn, Brian William

    1977-01-01

    Glasses in the system v?o?-Te0? were prepared at intervals throughout the glass-forming composition range. The vanadium valence state was varied for each composition by the addition of elemental tellurium to reduce the ...

  9. ORNL superhydrophobic glass coating offers clear benefits | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interconnected nanoporous nature of our coatings significantly suppresses Fresnel light reflections from glass surfaces, providing enhanced transmission over a wide...

  10. Energy efficient residential new construction: market transformation. Spectral selective glass. Final project report

    SciTech Connect (OSTI)

    Hammon, Robert

    2000-12-18

    This final report describes the following tasks associated with this project: cost and availability of spectrally selective glass (SSG); window labeling problem and field verification of glass; availability of SSG replacement glass and tempered glass; HVAC load reduction due to spectrally selective glass; and comsumer appreciation of spectrally selective glass. Also included in the report are four attachments: builder and HVAC subcontractor presentation, sample advertisements, spectrally selective glass demonstration model, and invitation to SCE Glass mini trade-show.

  11. GLASS TRANSITION SEEN THROUGH ASYMPTOTIC JULIEN OLIVIER AND MICHAEL RENARDY

    E-Print Network [OSTI]

    GLASS TRANSITION SEEN THROUGH ASYMPTOTIC EXPANSIONS JULIEN OLIVIER AND MICHAEL RENARDY Abstract of the model at low shear rate changes when a certain parameter (which we call the glass parameter) crosses´ebraud-Lequeux model, a Fokker-Planck-like description of soft glassy material, exhibits such a glass transition

  12. Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics

    E-Print Network [OSTI]

    Meyer, Christian

    Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics Gregor Vilkner Submitted Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics Gregor Vilkner Thin sheet concrete crushed glass as aggregate, a multitude of different esthetic effects can be produced, which again open up

  13. condmat/9801215 Crossovers in the Two Dimensional Ising Spin Glass

    E-Print Network [OSTI]

    Roma "La Sapienza", Universitŕ di

    cond­mat/9801215 v2 26 Jan 1998 Crossovers in the Two Dimensional Ising Spin Glass of extensive computer simulations we analyze in detail the two dimen­ sional \\SigmaJ Ising spin glass with ferromagnetic next­nearest­neighbor interactions. We found a crossover from ferromagnetic to ``spin glass'' like

  14. Saga of Glass Damage in Urban Environments Continues

    E-Print Network [OSTI]

    Kareem, Ahsan

    Saga of Glass Damage in Urban Environments Continues: Consequences of Aerodynamics and Debris Laboratory University of Notre Dame The Saga of Glass Damage in Urban Environments Continues: Consequences east of the city of Houston. Initial reconnaissance suggested that the observed glass/cladding damage

  15. A new method for solving radiative heat problems in glass

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    RANA 99­06 A new method for solving radiative heat problems in glass B.J. van der Linden --- R, The Netherlands e­mail: linden@win.tue.nl 15th May 2000 #12; Abstract In the production of glass, temperature Conclusion 25 2 #12; Chapter 1 Introduction The production of glass belongs to the oldest forms of human

  16. Calorimetric glass transition explained by hierarchical dynamic facilitation

    E-Print Network [OSTI]

    Garrahan, Juan P.

    Calorimetric glass transition explained by hierarchical dynamic facilitation Aaron S. Keysa Contributed by David Chandler, February 11, 2013 (sent for review November 15, 2012) The glass transition different on cooling than on heating, and the response to melting a glass depends markedly on the cooling

  17. A new method for solving radiative heat problems in glass

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    RANA 99-06 A new method for solving radiative heat problems in glass B.J. van der Linden -- R, The Netherlands e-mail: linden@win.tue.nl 15th May 2000 #12;Abstract In the production of glass, temperature plays Conclusion 25 2 #12;Chapter 1 Introduction The production of glass belongs to the oldest forms of human

  18. 5D Data Storage by Ultrafast Laser Nanostructuring in Glass

    E-Print Network [OSTI]

    Anderson, Jim

    5D Data Storage by Ultrafast Laser Nanostructuring in Glass Jingyu Zhang* , Mindaugas Gecevicius-assembled form birefringence and retrieved in glass opening the era of unlimited lifetime data storage. © 2013 laser writing in glass were proposed for the polarization multiplexed optical memory, where

  19. Rectilinear Glass-Cut Dissections of Rectangles to Squares

    E-Print Network [OSTI]

    Urrutia, Jorge

    Rectilinear Glass-Cut Dissections of Rectangles to Squares Jurek Czyzowicz§ czyzowic is made using only rectilinear glass-cuts, i.e., vertical or horizontal straight-line cuts separating pieces into two. 1 Introduction A glass-cut of a rectangle is a cut by a straight-line segment

  20. Department of Electrical Engineering Spring 2011 Glass Block Solar Collector

    E-Print Network [OSTI]

    Demirel, Melik C.

    PENNSTATE Department of Electrical Engineering Spring 2011 Glass Block Solar Collector Overview of the team to incorporate solar collectors into glass blocks and provide an application for the collected energy. Objectives The team's objective was to deliver a working glass block solar collector

  1. Nanodiamond in tellurite glass Part I: origin of loss in nanodiamond-doped glass

    E-Print Network [OSTI]

    Ebendorff-Heidepriem, Heike; Ji, Hong; Greentree, Andrew D; Gibson, Brant C; Monro, Tanya M

    2014-01-01

    Tellurite glass fibers with embedded nanodiamond are attractive materials for quantum photonic applications. Reducing the loss of these fibers in the 600-800 nm wavelength range of nanodiamond fluorescence is essential to exploit the unique properties of nanodiamond in the new hybrid material. In the first part of this study, we report the effect of interaction of the tellurite glass melt with the embedded nanodiamond on the loss of the glasses. The glass fabrication conditions such as melting temperature and concentration of NDs added to the melt were found to have critical influence on the interaction. Based on this understanding, we identified promising fabrication conditions for decreasing the loss to levels required for practical applications.

  2. Glass Forming Ability and Relaxation Behavior of Zr Based Metallic Glasses 

    E-Print Network [OSTI]

    Kamath, Aravind Miyar

    2012-07-16

    was studied by using thermal techniques to determine important GFA indicators for Zr-based bulk metallic glasses (BMG). The effect of alloying elements, annealing temperature and annealing time on the thermal and structural relaxation of the BMGs was studied...

  3. DWPF Glass Melter Technology Manual: Volume 4

    SciTech Connect (OSTI)

    Iverson, D.C.

    1993-12-31

    This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Plant. Information contained in this document consists solely of a machine drawing and parts list and purchase orders with specifications of equipment used in the development of the melter.

  4. DWPF Glass Melter Technology Manual: Volume 3

    SciTech Connect (OSTI)

    Iverson, D.C.

    1993-12-31

    This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics discussed include: Information collected during testing, equipment, materials, design basis, feed tubes, and an evaluation of the performance of various components. Information is conveyed using many diagrams and photographs.

  5. Modeling Human Foraging Brian D. Glass

    E-Print Network [OSTI]

    Maddox, W. Todd

    Modeling Human Foraging Brian D. Glass Department of Psychology University of Texas at Austin Thanks to W. Todd Maddox Arthur B. Markman Scott Lauritzen Cognition & Perception Group #12;Foraging What from group experiments like these? You learn about group behavior, with little to say about behavior

  6. Equilibrium ultrastable glasses produced by random pinning

    E-Print Network [OSTI]

    Glen M Hocky; Ludovic Berthier; David R. Reichman

    2014-12-08

    Ultrastable glasses have risen to prominence due to their potentially useful material properties and the tantalizing possibility of a general method of preparation via vapor deposition. Despite the importance of this novel class of amorphous materials, numerical studies have been scarce because achieving ultrastability in atomistic simulations is an enormous challenge. Here we bypass this difficulty and establish that randomly pinning the position of a small fraction of particles inside an equilibrated supercooled liquid generates ultrastable configurations at essentially no numerical cost, while avoiding undesired structural changes due to the preparation protocol. Building on the analogy with vapor-deposited ultrastable glasses, we study the melting kinetics of these configurations following a sudden temperature jump into the liquid phase. In homogeneous geometries, we find that enhanced kinetic stability is accompanied by large scale dynamic heterogeneity, while a competition between homogeneous and heterogeneous melting is observed when a liquid boundary invades the glass at constant velocity. Our work demonstrates the feasibility of large-scale, atomistically resolved, and experimentally relevant simulations of the kinetics of ultrastable glasses.

  7. Mössbauer study of conductive oxide glass

    SciTech Connect (OSTI)

    Matsuda, Koken; Kubuki, Shiro [Tokyo Metropolitan University, Hachi-Oji, Tokyo 192-0397 (Japan); Nishida, Tetsuaki, E-mail: nishida@fuk.kindai.ac.jp [Kinki University, Iizuka, Fukuoka 820-8555 (Japan)

    2014-10-27

    Heat treatment of barium iron vanadate glass, BaO?Fe{sub 2}O{sub 3}?V{sub 2}O{sub 5}, at temperatures higher than crystallization temperature causes a marked decrease in resistivity (?) from several M?cm to several ?cm. {sup 57}Fe Mössbauer spectrum of heat-treated vanadate glass shows a marked decrease in quadrupole splitting (?) of Fe{sup III}, reflecting a structural relaxation, i.e., an increased symmetry of 'distorted' FeO{sub 4} and VO{sub 4} tetrahedra which are connected to each other by sharing corner oxygen atoms. Structural relaxation of 3D-network of vanadate glass accompanies a decrease in the activation energy for the conduction, reflecting a decreased energy gap between the donor level and conduction band. A marked increase in the conductivity was observed in CuO- or Cu{sub 2}O-containing barium iron vanadate glass after heat treatment at 450 °C for 30 min or more. 'n-type semiconductor model combined with small polaron hopping theory' was proposed in order to explain the high conductivity.

  8. Overview of Energy Efficiency for Glass Furnace

    E-Print Network [OSTI]

    Banerjee, Rangan

    ,Particulates (Environmental norms) Global competitiveness #12;3 April, 2006 4Source: www.oilnergy.com Crude Oil Price #12, 2006 8 Energy Consumption in Glass Plant Melting 75% Forehearth 7% Anneling 4% Other 10% Printing Energy Consumption Specific Energy Consumption (SEC)­ Energy Consumption per unit of product output Units

  9. 2007,KevinSkadron Implications of the Power Wall

    E-Print Network [OSTI]

    Huang, Wei

    ©2007,KevinSkadron Implications of the Power Wall in a Manycore Era Sustaining Growth in Computing cost #12;5 ©2007,KevinSkadron Barriers to Performance Growth (2) · Power wall, ILP wall, and slow is a paradigm shift for parallel programming · Power wall will eventually constrain multicore too ­ If power per

  10. High Temperature Polybenzimidazole Hollow Fiber Membranes for Hydrogen Separation and Carbon Dioxide Capture from Synthesis Gas

    SciTech Connect (OSTI)

    Singh, Rajinder P.; Dahe, Ganpat J.; Dudeck, Kevin W.; Welch, Cynthia F.; Berchtold, Kathryn A.

    2014-12-31

    Sustainable reliance on hydrocarbon feedstocks for energy generation requires CO? separation technology development for energy efficient carbon capture from industrial mixed gas streams. High temperature H? selective glassy polymer membranes are an attractive option for energy efficient H?/CO? separations in advanced power production schemes with integrated carbon capture. They enable high overall process efficiencies by providing energy efficient CO? separations at process relevant operating conditions and correspondingly, minimized parasitic energy losses. Polybenzimidazole (PBI)-based materials have demonstrated commercially attractive H?/CO? separation characteristics and exceptional tolerance to hydrocarbon fuel derived synthesis (syngas) gas operating conditions and chemical environments. To realize a commercially attractive carbon capture technology based on these PBI materials, development of high performance, robust PBI hollow fiber membranes (HFMs) is required. In this work, we discuss outcomes of our recent efforts to demonstrate and optimize the fabrication and performance of PBI HFMs for use in pre-combustion carbon capture schemes. These efforts have resulted in PBI HFMs with commercially attractive fabrication protocols, defect minimized structures, and commercially attractive permselectivity characteristics at IGCC syngas process relevant conditions. The H?/CO? separation performance of these PBI HFMs presented in this document regarding realistic process conditions is greater than that of any other polymeric system reported to-date.

  11. High Temperature Polybenzimidazole Hollow Fiber Membranes for Hydrogen Separation and Carbon Dioxide Capture from Synthesis Gas

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, Rajinder P.; Dahe, Ganpat J.; Dudeck, Kevin W.; Welch, Cynthia F.; Berchtold, Kathryn A.

    2014-12-31

    Sustainable reliance on hydrocarbon feedstocks for energy generation requires CO? separation technology development for energy efficient carbon capture from industrial mixed gas streams. High temperature H? selective glassy polymer membranes are an attractive option for energy efficient H?/CO? separations in advanced power production schemes with integrated carbon capture. They enable high overall process efficiencies by providing energy efficient CO? separations at process relevant operating conditions and correspondingly, minimized parasitic energy losses. Polybenzimidazole (PBI)-based materials have demonstrated commercially attractive H?/CO? separation characteristics and exceptional tolerance to hydrocarbon fuel derived synthesis (syngas) gas operating conditions and chemical environments. To realize a commerciallymore »attractive carbon capture technology based on these PBI materials, development of high performance, robust PBI hollow fiber membranes (HFMs) is required. In this work, we discuss outcomes of our recent efforts to demonstrate and optimize the fabrication and performance of PBI HFMs for use in pre-combustion carbon capture schemes. These efforts have resulted in PBI HFMs with commercially attractive fabrication protocols, defect minimized structures, and commercially attractive permselectivity characteristics at IGCC syngas process relevant conditions. The H?/CO? separation performance of these PBI HFMs presented in this document regarding realistic process conditions is greater than that of any other polymeric system reported to-date.« less

  12. Theoretical solution for light transmission of a bended hollow light guide

    SciTech Connect (OSTI)

    Kocifaj, Miroslav; Darula, Stanislav; Kittler, Richard [ICA, Slovak Academy of Sciences, 9, Dubravska Road, 845 03 Bratislava (Slovakia); Kundracik, Frantisek [Department of Experimental Physics, FMPI, Comenius University, Mlynska dolina, 842 48 Bratislava (Slovakia)

    2010-08-15

    Hollow light guides with very high reflective inner surfaces are novel daylight systems that collect sunlight and skylight available on the roof of buildings transporting it into deep or windowless interiors in building cores. Thus the better utilization of daylight can result in energy savings and wellbeing in these enclosed indoor spaces. An analytical complex solution of a straight tube system was solved in the HOLIGILM method with a user-friendly tool available on the http://www.holigilm.info. An even more difficult light flow transport is to be determined in bended tubes usually placed on sloped roofs where a bend is necessary to adjust the vertical pass through the ceilings. This paper presents the theoretical derivation of the model with its graphical representation and coordinate system respecting backward ray-tracing bend distortions. To imagine the resulting illuminance on the horizontal plane element in the interior, the virtual ray (i.e. luminance in an elementary solid angle) has to pass the ceiling diffuser interface, the inner mirror like tube with a bend, through a roof cupola attachment to the element of the sky and sun light source. Due to this complexity and the lengthy derivation and explanations more practical applications will be published later in a separate contribution. (author)

  13. Behavior of a hollow core photonic crystal fiber under high radial pressure for downhole application

    SciTech Connect (OSTI)

    Sadeghi, J., E-mail: j-sadeghi@sbu.ac.ir; Chenari, Z.; Ziaee, F. [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Latifi, H., E-mail: latifi@sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Department of Physics, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Santos, J. L., E-mail: josantos@fc.up.pt [INESC Porto—Instituto de Engenharia de Sistemas e Computadores do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Departamento de Física, da Faculdade de Cięncias, da Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal)

    2014-02-17

    Pressure fiber sensors play an important role in downhole high pressure measurements to withstand long term operation. The purpose of this paper is to present an application of hollow core photonic crystal fiber (HC-PCF) as a high pressure sensor head for downhole application based on dispersion variation. We used a high pressure stainless steel unit to exert pressure on the sensor. The experimental results show that different wavelengths based on sagnac loop interferometer have additive sensitivities from 5?×?10{sup ?5}?nm/psi at 1480?nm to 1.3?×?10{sup ?3}?nm/psi at 1680?nm. We developed a simulation to understand the reason for difference in sensitivity of wavelengths and also the relationship between deformation of HC-PCF and dispersion variation under pressure. For this purpose, by using the finite element method, we investigated the effect of structural variation of HC-PCF on spectral transformation of two linear polarizations under 1000?psi pressure. The simulation and experimental results show exponential decay behavior of dispersion variation from ?3.4?×?10{sup ?6} 1/psi to ?1.3?×?10{sup ?6} 1/psi and from ?5?×?10{sup ?6} 1/psi to ?1.8?×?10{sup ?6} 1/psi, respectively, which were in a good accordance with each other.

  14. Hollow-fiber supported liquid membrane (HFSLM) for the separation of lanthanides and actinides

    SciTech Connect (OSTI)

    Mohapatra, P.K.; Ansari, S.A.; Bhattacharyya, A.; Manchanda, V.K.; Patil, C.B.

    2008-07-01

    The transport behavior of Nd(III) was investigated using hollow-fiber supported liquid membranes (HFSLM) from an acidic feed solution using N,N,N',N'-tetraoctyl-diglycolamide (TODGA) in normal paraffinic hydrocarbon (NPH) as the carrier. Near quantitative transport (>99%) of Nd(III) from 500 mL of feed containing 1 g/L Nd in 3.5 M HNO{sub 3} was possible in about 45 minutes. Quantitative transport time increased when the volume or Nd(III ) concentration in the feed was increased. The liquid membrane had excellent stability as indicated by eight consecutive runs that gave consistent transport rates. The HFSLM data using Cyanex- 301 in n-dodecane as carrier extractant for the lanthanide-actinide separation with the feed solution 1 M NaNO{sub 3} at pH 3.5 and stripping solution 0.01 M EDTA at a pH 3.5 were promising. (authors)

  15. Lumen mass transfer in hollow-fiber membrane processes with constant external resistances

    SciTech Connect (OSTI)

    Qin, Y.; Cabral, J.M.S.

    1997-08-01

    Membrane processes have recently become an accepted unit operation for a wide variety of separations in industry and in environmental applications. Hollow-fiber membrane processes with a constant external resistance having a constant or variable shell concentration resulting from an operational mode of cocurrent or countercurrent are studied. By solving numerically the continuity mass-conservation equation with the corresponding boundary conditions, the lumen laminar mass-transfer coefficients for both cases are correlated. The correlations greatly improve the calculating accuracy of the overall mass-transfer coefficient and can be used to obtain the lumen mixed-cup concentration by an algebraic equation substituting the partial differential equation. A separation factor m{prime} is introduced to characterize the effect of the operational mode. Calculation results demonstrate that the lumen mass-transfer coefficient is independent of the real lumen and shell concentrations, but it is greatly influenced by m{prime}. The countercurrent mode, compared to the cocurrent mode, provides not only a higher mean driving force, but a higher lumen mass-transfer coefficient. This conclusion is novel and valid for the tube-shell heat or mass-transfer processes and is supported by the experimental data in the literature and the authors` gas membrane separation experiments.

  16. HIGH ALUMINUM HLW GLASSES FOR HANFORDS WTP

    SciTech Connect (OSTI)

    KRUGER AA; JOSEPH I; BOWMAN BW; GAN H; KOT W; MATLACK KS; PEGG IL

    2009-08-19

    The world's largest radioactive waste vitrification facility is now under construction at the United State Department of Energy's (DOE's) Hanford site. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is designed to treat nearly 53 million gallons of mixed hazardous and radioactive waste now residing in 177 underground storage tanks. This multi-decade processing campaign will be one of the most complex ever undertaken because of the wide chemical and physical variability of the waste compositions generated during the cold war era that are stored at Hanford. The DOE Office of River Protection (ORP) has initiated a program to improve the long-term operating efficiency of the WTP vitrification plants with the objective of reducing the overall cost of tank waste treatment and disposal and shortening the duration of plant operations. Due to the size, complexity and duration of the WTP mission, the lifecycle operating and waste disposal costs are substantial. As a result, gains in High Level Waste (HLW) and Low Activity Waste (LAW) waste loadings, as well as increases in glass production rate, which can reduce mission duration and glass volumes for disposal, can yield substantial overall cost savings. EnergySolutions and its long-term research partner, the Vitreous State Laboratory (VSL) of the Catholic University of America, have been involved in a multi-year ORP program directed at optimizing various aspects of the HLW and LAW vitrification flow sheets. A number of Hanford HLW streams contain high concentrations of aluminum, which is challenging with respect to both waste loading and processing rate. Therefore, a key focus area of the ORP vitrification process optimization program at EnergySolutions and VSL has been development of HLW glass compositions that can accommodate high Al{sub 2}O{sub 3} concentrations while maintaining high processing rates in the Joule Heated Ceramic Melters (JHCMs) used for waste vitrification at the WTP. This paper, reviews the achievements of this program with emphasis on the recent enhancements in Al{sub 2}O{sub 3} loadings in HLW glass and its processing characteristics. Glass formulation development included crucible-scale preparation and characterization of glass samples to assess compliance with all melt processing and product quality requirements, followed by small-scale screening tests to estimate processing rates. These results were used to down-select formulations for subsequent engineering-scale melter testing. Finally, further testing was performed on the DM1200 vitrification system installed at VSL, which is a one-third scale (1.20 m{sup 2}) pilot melter for the WTP HLW melters and which is fitted with a fully prototypical off-gas treatment system. These tests employed glass formulations with high waste loadings and Al{sub 2}O{sub 3} contents of {approx}25 wt%, which represents a near-doubling of the present WTP baseline maximum Al{sub 2}O{sub 3} loading. In addition, these formulations were processed successfully at glass production rates that exceeded the present requirements for WTP HLW vitrification by up to 88%. The higher aluminum loading in the HLW glass has an added benefit in that the aluminum leaching requirements in pretreatment are reduced, thus allowing less sodium addition in pretreatment, which in turn reduces the amount of LAW glass to be produced at the WTP. The impact of the results from this ORP program in reducing the overall cost and schedule for the Hanford waste treatment mission will be discussed.

  17. Blocking effect of crystal–glass interface in lanthanum doped barium strontium titanate glass–ceramics

    SciTech Connect (OSTI)

    Wang, Xiangrong; Zhang, Yong; Baturin, Ivan; Liang, Tongxiang

    2013-10-15

    Graphical abstract: The blocking effect of the crystal–glass interface on the carrier transport behavior in the lanthanum doped barium strontium titanate glass–ceramics: preparation and characterization. - Highlights: • La{sub 2}O{sub 3} addition promotes the crystallization of the major crystalline phase. • The Z? and M? peaks exist a significant mismatch for 0.5 mol% La{sub 2}O{sub 3} addition. • The Z? and M? peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. • Crystallite impedance decreases while crystal–glass interface impedance increases. • La{sub 2}O{sub 3} addition increases blocking factor of the crystal–glass interface. - Abstract: The microstructures and dielectric properties in La{sub 2}O{sub 3}-doped barium strontium titanate glass–ceramics have been investigated by scanning electron microscopy (SEM) and impedance spectroscopy. SEM analysis indicated that La{sub 2}O{sub 3} additive decreases the average crystallite size. Impedance spectroscopy revealed that the positions of Z? and M? peaks are close for undoped samples. When La{sub 2}O{sub 3} concentration is 0.5 mol%, the Z? and M? peaks show a significant mismatch. Furthermore, these peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. With increasing La{sub 2}O{sub 3} concentration, the contribution of the crystallite impedance becomes smaller, while the contribution of the crystal–glass interface impedance becomes larger. More interestingly, it was found that La{sub 2}O{sub 3} additive increases blocking factor of the crystal–glass interface in the temperature range of 250–450 °C. This may be attributed to a decrease of activation energy of the crystallite and an increase of the crystal–glass interface area.

  18. Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses Maxime Merciera, Andrea Di Muroab , Daniele Giordanoc , Nicole Métricha , Priscille Lesned of an accurate analytical procedure for determination of dissolved water in complex alumino-silicate glasses via

  19. Photograph from Ruth Glass Obituary in The Times 9th March 1990. Ruth Adele Glass [ne Lazarus] (1912 1990), sociologist, was born on 30 June 1912 in Berlin,

    E-Print Network [OSTI]

    RUTH GLASS Photograph from Ruth Glass Obituary in The Times 9th March 1990. Ruth Adele Glass [née, published in 1939, established her reputation as a social scientist. From 1940 until 1942 Ruth Glass College London, which remained her academic base for the rest of her life. In 1951 Ruth Glass became

  20. Glass transitions in two-dimensional suspensions of colloidal ellipsoids

    E-Print Network [OSTI]

    Zhongyu Zheng; Feng Wang; Yilong Han

    2011-05-29

    We observed a two-step glass transition in monolayers of colloidal ellipsoids by video microscopy. The glass transition in the rotational degree of freedom was at a lower density than that in the translational degree of freedom. Between the two transitions, ellipsoids formed an orientational glass. Approaching the respective glass transitions, the rotational and translational fastest-moving particles in the supercooled liquid moved cooperatively and formed clusters with power-law size distributions. The mean cluster sizes diverge in power law as approaching the glass transitions. The clusters of translational and rotational fastest-moving ellipsoids formed mainly within pseudo-nematic domains, and around the domain boundaries, respectively.

  1. Rapid process for producing transparent, monolithic porous glass

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA)

    2006-02-14

    A process for making transparent porous glass monoliths from gels. The glass is produced much faster and in much larger sizes than present technology for making porous glass. The process reduces the cost of making large porous glass monoliths because: 1) the process does not require solvent exchange nor additives to the gel to increase the drying rates, 2) only moderate temperatures and pressures are used so relatively inexpensive equipment is needed, an 3) net-shape glass monoliths are possible using this process. The process depends on the use of temperature to control the partial pressure of the gel solvent in a closed vessel, resulting in controlled shrinking during drying.

  2. Fracture Toughness of Metallic Glasses: Ductile-to-Brittle Transition?

    E-Print Network [OSTI]

    Rycroft, Chris H

    2012-01-01

    Quantitative understanding of the fracture toughness of metallic glasses, including the associated ductile-to-brittle transitions, is not yet available. Here we use a simple model of plastic deformation in glasses, coupled to an advanced Eulerian level set formulation for solving complex free boundary problems, to calculate the fracture toughness of metallic glasses as a function of the degree of structural relaxation corresponding to different annealing times near the glass temperature. Our main result indicates the existence of an elasto-plastic crack tip instability for sufficiently relaxed glasses, resulting in a marked drop in the toughness, which we interpret as a ductile-to-brittle transition similar to experimental observations.

  3. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

    1995-05-02

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

  4. DEVELOPMENT OF GLASS MATRICES FOR HLW RADIOACTIVE WASTES

    SciTech Connect (OSTI)

    Jantzen, C.

    2010-03-18

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc{sup 99}, Cs{sup 137}, and I{sup 129}. Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

  5. Domain wall conduction in multiaxial ferroelectrics

    SciTech Connect (OSTI)

    Eliseev, E. A.; Morozovska, A. N.; Svechnikov, S. V.; Maksymovych, Petro; Kalinin, Sergei V

    2012-01-01

    The conductance of domain wall structures consisting of either stripes or cylindrical domains in multiaxial ferroelectric-semiconductors is analyzed. The effects of the flexoelectric coupling, domain size, wall tilt, and curvature on charge accumulation are analyzed using the Landau-Ginsburg Devonshire theory for polarization vector combined with the Poisson equation for charge distributions. The proximity and size effect of the electron and donor accumulation/depletion by thin stripe domains and cylindrical nanodomains are revealed. In contrast to thick domain stripes and wider cylindrical domains, in which the carrier accumulation (and so the static conductivity) sharply increases at the domain walls only, small nanodomains of radii less than 5-10 correlation lengths appeared conducting across the entire cross-section. Implications of such conductive nanosized channels may be promising for nanoelectronics.

  6. Turbine airfoil with a compliant outer wall

    DOE Patents [OSTI]

    Campbell, Christian X. (Oviedo, FL); Morrison, Jay A. (Oviedo, FL)

    2012-04-03

    A turbine airfoil usable in a turbine engine with a cooling system and a compliant dual wall configuration configured to enable thermal expansion between inner and outer layers while eliminating stress formation in the outer layer is disclosed. The compliant dual wall configuration may be formed a dual wall formed from inner and outer layers separated by a support structure. The outer layer may be a compliant layer configured such that the outer layer may thermally expand and thereby reduce the stress within the outer layer. The outer layer may be formed from a nonplanar surface configured to thermally expand. In another embodiment, the outer layer may be planar and include a plurality of slots enabling unrestricted thermal expansion in a direction aligned with the outer layer.

  7. Thermodynamics of free Domain Wall fermions

    E-Print Network [OSTI]

    R. V. Gavai; Sayantan Sharma

    2008-11-19

    Studying various thermodynamic quantities for the free domain wall fermions for both finite and infinite fifth dimensional extent N_5, we find that the lattice corrections are minimum for $N_T\\geq10$ for both energy density and susceptibility, for its irrelevant parameter M in the range 1.45-1.50. The correction terms are, however, quite large for small lattice sizes of $N_T\\leq8$. We propose modifications of the domain wall operator, as well as the overlap operator, to reduce the finite cut-off effects to within 10% of the continuum results of the thermodynamic quantities for the currently used N_T=6-8 lattices. Incorporating chemical potential, we show that \\mu^2 divergences are absent for a large class of such domain wall fermion actions although the chiral symmetry is broken for $\\mu\

  8. Wall thickness measuring method and apparatus

    DOE Patents [OSTI]

    Salzer, L.J.; Bergren, D.A.

    1987-10-06

    An apparatus for measuring the wall thickness of a nonmagnetic article having a housing supporting a magnet and a contiguous supporting surface. The tubular article and the housing are releasably secured to the supporting surface and a support member of an optical comparator, respectively. To determine the wall thickness of the article at a selected point, a magnetically responsive ball is positioned within the tubular article over said point and retained therein by means of a magnetic field produced by the magnet. Thereafter, an optical comparator is employed to project a magnified image of the ball on a screen and the wall thickness at the selected point is calculated by using a ball surface measurement taken with the comparator in conjunction with a previously determined base line measurement.

  9. System and method for glass processing and temperature sensing

    DOE Patents [OSTI]

    Shepard, Chester L.; Cannon, Bret D.; Khaleel, Mohammad A.

    2004-09-28

    Techniques for measuring the temperature at various locations through the thickness of glass products and to control the glass processing operation with the sensed temperature information are disclosed. Fluorescence emission of iron or cerium in glass is excited and imaged onto segmented detectors. Spatially resolved temperature data are obtained through correlation of the detected photoluminescence signal with location within the glass. In one form the detected photoluminescence is compared to detected scattered excitation light to determine temperature. Stress information is obtained from the time history of the temperature profile data and used to evaluate the quality of processed glass. A heating or cooling rate of the glass is also controlled to maintain a predetermined desired temperature profile in the glass.

  10. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2003-09-23

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste uranium oxides The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  11. Ammonia-treated phosphate glasses useful for sealing to metals

    DOE Patents [OSTI]

    Brow, R.K.; Day, D.E.

    1991-09-03

    A method of improving surface-dependent properties of phosphate glass such as durability and wear resistance without significantly affecting its thermal expansion coefficient is provided which comprises annealing the glass in a dry ammonia atmosphere at temperatures approximating the transition temperature of the glass. The ammonia annealing treatment of the present invention is carried out for a time sufficient to allow incorporation of a thin layer of nitrogen into the surface of the phosphate glass, and the treatment improves the durability of the glass without the reduction in the thermal expansion coefficient that has restricted the effectiveness of prior ammonia treatments. The improved phosphate glass resulting from this method is superior in wear resistance, yet maintains suitable thermal expansion properties so that it may be used effectively in a variety of applications requiring hermetic glass-metal seals.

  12. Scalable synthesis of Na3V2(PO4)(3)/C porous hollow spheres as a cathode for Na-ion batteries

    SciTech Connect (OSTI)

    Mao, JF; Luo, C; Gao, T; Fan, XL; Wang, CS

    2015-01-01

    Na3V2(PO4)(3) (NVP) has been considered as a very promising cathode material for sodium-ion batteries (SIBs) due to its typical NASICON structure, which provides an open and three dimensional (3D) framework for Na+ migration. However, the low electronic conductivity of NVP limits its rate capability and cycling ability. In this study, carbon coated hollow structured NVP/C composites are synthesized via a template-free and scalable ultrasonic spray pyrolysis process, where the carbon coated NVP particles are uniformly decorated on the inner and outer surfaces of the porous hollow carbon spheres. When evaluated as a cathode material for SIBs, the unique NVP/C porous hollow sphere cathode delivers an initial discharge capacity of 99.2 mA h g(-1) and retains 89.3 mA h g(-1) after 300 charge/discharge cycles with a very low degradation rate of 0.035% per cycle. For comparison, the NVP/C composite, prepared by the traditional sol-gel method, delivers a lower initial discharge capacity of 97.4 mA h g(-1) and decreases significantly to 71.5 mA h g(-1) after 300 cycles. The superior electrochemical performance of NVP/C porous hollow spheres is attributed to their unique porous, hollow and spherical structures, as well as the carbon-coating layer, which provides a high contact area between electrode/electrolyte, high electronic conductivity, and high mechanical strength.

  13. Facile synthesis and characterization of ZnFe{sub 2}O{sub 4}/{alpha}-Fe{sub 2}O{sub 3} composite hollow nanospheres

    SciTech Connect (OSTI)

    Shen, Yu [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China) [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); School of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028 (China); Li, Xinyong, E-mail: xyli@dlut.edu.cn [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China) [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Zhao, Qidong; Hou, Yang [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Tade, Moses [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Liu, Shaomin, E-mail: Shaomin.Liu@curtin.edu.au [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer ZnFe{sub 2}O{sub 4}/{alpha}-Fe{sub 2}O{sub 3} composite hollow nanospheres were successfully synthesized via a facile method. Black-Right-Pointing-Pointer Detailed structural, morphology and the phase composition were studied. Black-Right-Pointing-Pointer The incorporation of ZnFe{sub 2}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3} gives an appropriate band gap value to utilize solar energy. -- Abstract: ZnFe{sub 2}O{sub 4}/{alpha}-Fe{sub 2}O{sub 3} composite hollow nanospheres were successfully fabricated via a facile one-pot solvothermal method, utilizing polyethylene glycol as soft template. X-ray diffraction and scanning electron microscopy analysis revealed that the prepared nanospheres with cubic spinel and rhombohedra composite structure had a uniform diameter of about 370 nm, and the hollow structure could be further confirmed by transmission electron microscopy. Energy dispersive X-ray, X-ray photoelectron spectroscopy and Fourier transform infrared techniques were also applied to characterize the elemental composition and chemical bonds in the hollow nanospheres. The ZnFe{sub 2}O{sub 4}/{alpha}-Fe{sub 2}O{sub 3} composite hollow nanospheres show attractive light absorption property for potential applications in electronics, optics, and catalysis.

  14. Enhancement of wall jet transport properties

    DOE Patents [OSTI]

    Claunch, S.D.; Farrington, R.B.

    1997-02-04

    By enhancing the natural instabilities in the boundary layer and in the free shear layer of a wall jet, the boundary is minimized thereby increasing the transport of heat and mass. Enhancing the natural instabilities is accomplished by pulsing the flow of air that creates the wall jet. Such pulsing of the flow of air can be accomplished by sequentially occluding and opening a duct that confines and directs the flow of air, such as by rotating a disk on an axis transverse to the flow of air in the duct. 17 figs.

  15. Cell Wall Recipe: A Lesson on Biofuels

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Students will investigate how changes in the DNA sequence that codes for cell wall formation can have a favorable outcome in producing plants that have higher levels of cellulose than the parent plant. The cellulose yield is most important in the production of ethanol: the greater the amount of cellulose within the cell wall, the greater the amount of ethanol that can be produced. To engage students, the first part of this lesson has students participating in a discovery activity where they will extract DNA from wheat germ.

  16. Enhancement of wall jet transport properties

    DOE Patents [OSTI]

    Claunch, Scott D. (Broomfield, CO); Farrington, Robert B. (Golden, CO)

    1997-01-01

    By enhancing the natural instabilities in the boundary layer and in the free shear layer of a wall jet, the boundary is minimized thereby increasing the transport of heat and mass. Enhancing the natural instabilities is accomplished by pulsing the flow of air that creates the wall jet. Such pulsing of the flow of air can be accomplished by sequentially occluding and opening a duct that confines and directs the flow of air, such as by rotating a disk on an axis transverse to the flow of air in the duct.

  17. Standing gravitational waves from domain walls

    E-Print Network [OSTI]

    Merab Gogberashvili; Shynaray Myrzakul; Douglas Singleton

    2009-07-19

    We construct a plane symmetric, standing gravitational wave for a domain wall plus a massless scalar field. The scalar field can be associated with a fluid which has the properties of `stiff' matter, i.e. matter in which the speed of sound equals the speed of light. Although domain walls are observationally ruled out in the present era the solution has interesting features which might shed light on the character of exact non-linear wave solutions to Einstein's equations. Additionally this solution may act as a template for higher dimensional 'brane-world' model standing waves.

  18. Glass transition and crystallization kinetics of a barium borosilicate glass by a non-isothermal method

    SciTech Connect (OSTI)

    Lopes, Andreia A. S.; Soares, Roque S.; Lima, Maria M. A.; Monteiro, Regina C. C., E-mail: rcm@fct.unl.pt [Department of Materials Science, CENIMAT/I3N, Faculty of Sciences and Technology, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal)

    2014-01-28

    The glass transition and crystallization kinetics of a glass with a molar composition 60BaO-30B{sub 2}O{sub 3}-10SiO{sub 2} were investigated by differential scanning calorimetry (DSC) under non-isothermal conditions. DSC curves exhibited an endothermic peak associated with the glass transition and two partially overlapped exothermic peaks associated with the crystallization of the glass. The dependence of the glass transition temperature (T{sub g}) and of the maximum crystallization temperature (T{sub p}) on the heating rate was used to determine the activation energy associated with the glass transition (E{sub g}), the activation energy for crystallization (E{sub c}), and the Avrami exponent (n). X-ray diffraction (XRD) revealed that barium borate (?-BaB{sub 2}O{sub 4}) was the first crystalline phase to be formed followed by the formation of barium silicate (Ba{sub 5}Si{sub 8}O{sub 21}). The variations of activation energy for crystallization and of Avrami exponent with the fraction of crystallization (?) were also examined. When the crystallization fraction (?) increased from 0.1 to 0.9, the value of local activation energy (E{sub c}(?)) decreased from 554 to 458?kJ/mol for the first exothermic peak and from 1104 to 831?kJ/mol for the second exothermic peak. The value determined for the Avrami exponent was near 2 indicating a similar one-dimensional crystallization mechanism for both crystalline phases. This was confirmed by the morphological studies performed by scanning electron microscopy (SEM) on glass samples heat-treated at the first and at the second crystallization temperatures.

  19. Calculation of the transverse kicks generated by the bends of a hollow electron lens

    SciTech Connect (OSTI)

    Stancari, Giulio

    2014-03-25

    Electron lenses are pulsed, magnetically confined electron beams whose current-density profile is shaped to obtain the desired effect on the circulating beam in high-energy accelerators. They were used in the Fermilab Tevatron collider for abort-gap clearing, beam-beam compensation, and halo scraping. A beam-beam compensation scheme based upon electron lenses is currently being implemented in the Relativistic Heavy Ion Collider at Brookhaven National Laboratory. This work is in support of a conceptual design of hollow electron beam scraper for the Large Hadron Collider. It also applies to the implementation of nonlinear integrable optics with electron lenses in the Integrable Optics Test Accelerator at Fermilab. We consider the axial asymmetries of the electron beam caused by the bends that are used to inject electrons into the interaction region and to extract them. A distribution of electron macroparticles is deposited on a discrete grid enclosed in a conducting pipe. The electrostatic potential and electric fields are calculated using numerical Poisson solvers. The kicks experienced by the circulating beam are estimated by integrating the electric fields over straight trajectories. These kicks are also provided in the form of interpolated analytical symplectic maps for numerical tracking simulations, which are needed to estimate the effects of the electron lens imperfections on proton lifetimes, emittance growth, and dynamic aperture. We outline a general procedure to calculate the magnitude of the transverse proton kicks, which can then be generalized, if needed, to include further refinements such as the space-charge evolution of the electron beam, magnetic fields generated by the electron current, and longitudinal proton dynamics.

  20. Glass ceramic toughened with tetragonal zirconia

    DOE Patents [OSTI]

    Keefer, K.D.

    1984-02-10

    A phase transformation-toughened glass ceramic and a process for making it are disclosed. A mixture of particulate network-forming oxide, network-modifying oxide, and zirconium oxide is heated to yield a homogeneous melt, and this melt is then heat treated to precipitate an appreciable quantity of tetragonal zirconia, which is retained at ambient temperature to form a phase transformation-toughened glass ceramic. Nuclearing agents and stabilizing agents may be added to the mixture to facilitate processing and improve the ceramic's properties. Preferably, the mixture is first melted at a temperature from 1200 to 1700/sup 0/C and is then heat-treated at a temperature within the range of 800 to 1200/sup 0/C in order to precipitate tetragonal ZrO/sub 2/. The composition, as well as the length and temperature of the heat treatment, must be carefully controlled to prevent solution of the precipitated tetragonal zirconia and subsequent conversion to the monoclinic phase.

  1. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.more »For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.« less

  2. Hot wire production of single-wall and multi-wall carbon nanotubes

    DOE Patents [OSTI]

    Dillon, Anne C. (Boulder, CO); Mahan, Archie H. (Golden, CO); Alleman, Jeffrey L. (Lakewood, CO)

    2010-10-26

    Apparatus (210) for producing a multi-wall carbon nanotube (213) may comprise a process chamber (216), a furnace (217) operatively associated with the process chamber (216), and at least one filament (218) positioned within the process chamber (216). At least one power supply (220) operatively associated with the at least one filament (218) heats the at least one filament (218) to a process temperature. A gaseous carbon precursor material (214) operatively associated with the process chamber (216) provides carbon for forming the multi-wall carbon nanotube (213). A metal catalyst material (224) operatively associated with the process (216) catalyzes the formation of the multi-wall carbon nanotube (213).

  3. High-Intensity Plasma Glass Melter Final Technical Report

    SciTech Connect (OSTI)

    Gonterman, J. Ronald; Weinstein, Michael A.

    2006-10-27

    The purpose of this project was to demonstrate the energy efficiency and reduced emissions that can be obtained with a dual torch DC plasma transferred arc-melting system. Plasmelt Glass Technologies, LLC was formed to solicit and execute the project, which utilize a full-scale test melter system. The system is similar to the one that was originally constructed by Johns Manville, but Plasmelt has added significant improvements to the torch design and melter system that has extended the original JM short torch lives. The original JM design has been shown to achieve melt rates 5 to 10 times faster than conventional gas or electric melting, with improved energy efficiency and reduced emissions. This project began on 7/28/2003 and ended 7/27/06. A laboratory scale melter was designed, constructed, and operated to conduct multiple experimental melting trials on various glass compositions. Glass quality was assessed. Although the melter design is generic and equally applicable to all sectors within the glass industry, the development of this melter has focused primarily on fiberglass with additional exploratory melting trials of frits, specialty, and minerals-melting applications. Throughput, energy efficiency, and glass quality have been shown to be heavily dependent on the selected glass composition. During this project, Plasmelt completed the proof-of-concept work in our Boulder, CO Lab to show the technical feasibility of this transferred-arc plasma melter. Late in the project, the work was focused on developing the processes and evaluating the economic viability of plasma melting aimed at the specific glasses of interest to specific client companies. Post project work is on going with client companies to address broader non-glass materials such as refractories and industrial minerals. Exploratory melting trials have been conducted on several glasses of commercial interest including: C-glass, E-glass, S-Glass, AR-Glass, B-glass, Lighting Glass, NE-Glass, and various frits. Exploratory melts of non-glassy materials, such as wollastonite, zirconium silicate, and alumino-silicate melts were successfully done indicating that plasma melting has potential application beyond glass. Experimental results were generated that show the high quality of plasma-melted fiberglass compositions, such as E-glass, can result in good fiberizing performance. Fiberizing performance and tensile strength data were achieved during the project to support this conclusion. High seed counts are a feature of the current lab scale melter and must be dealt with via other means, since fining work was outside the scope of this project.

  4. Single-walled carbon nanotube, SWNT(2)

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Technology Roadmap, Journal of the Japan Society of Mechanical Engineers, Vol. 110, No. 1067 (2007). (2 1 c-e 97 % (5) *1 *1 *2 *2 *2 *2 *2 *2 Scattering Process of Transmitted Gas Molecules through process of gas molecules on vertically aligned single-walled carbon nanotube (VA-SWNT) films

  5. 2004 11 -2-(Single-Walled Carbon

    E-Print Network [OSTI]

    Maruyama, Shigeo

    ~~ 2004 11 -2- 1. (Single-Walled Carbon Nanotubes, SWNTs) 13 nm [1] SWNT van Hove [1 SWNT TEM 0.83 nm 2.0 nm SWNT MWNT SWNT 5(a) [11] 5(b) SWNT 1 nm SWNT [12] #12; 2004., Physical Properties of Carbon Nanotubes, Imperial College Press, London, 1998. (2004). [2] S. Maruyama et

  6. Liquid Walls Innovative High Power Density Concepts

    E-Print Network [OSTI]

    California at Los Angeles, University of

    erosion as limiting factors -Results in smaller and lower cost components (chambLiquid Walls Innovative High Power Density Concepts (Based on the APEX Study) http for the Chamber Technology that can: 1. Improve the vision for an attractive fusion energy system 2. Lower

  7. Program Induction: Building a Wall Dan Ashlock

    E-Print Network [OSTI]

    Ashlock, Dan

    moving off of the grid are lost. A s a wall out of blocks that impede progress in one direction across a grid of squares. Specifically, two at a time in a fixed location on the grid. The robot must move the currently presented block to enable

  8. Solitons and Domain Walls in Odd Dimensions

    E-Print Network [OSTI]

    N. D. Lambert; G. W. Gibbons

    2000-07-04

    We discuss the existance of smooth soliton solutions which interpolate between supersymmetric vacua in odd-dimensional theories. In particular we apply this analysis to a wide class of supergravities to argue against the existence of smooth domain walls interpolating between supersymmetric vacua. We find that if the superpotential changes sign then any Goldstino modes will diverge.

  9. CHALLENGE 2015 WALL OF WIND MITIGATION CHALLENGE

    E-Print Network [OSTI]

    Chen, Shu-Ching

    with the development of the building model. Is wind mitigation being addressed by your solution? What is wind science, sociology, and urban planning when discussing wind mitigation and your solution. WrittenW W! CHALLENGE 2015 WALL OF WIND MITIGATION CHALLENGE Competition at FIU's Engineering & Computing

  10. The Spectrum of the Th-Ar Hollow-Cathode Lamp Used with the 2dcoude Spectrograph

    E-Print Network [OSTI]

    Carlos Allende Prieto

    2001-11-08

    We have produced an atlas of the Th-Ar hollow-cathode lamp used with the 2dcoude spectrograph at McDonald Observatory. The atlas covers from 3611.9 to 10596.4 A at a resolving power of 52,000. We have determined the wavelenghts of 1483 emission lines in the spectrum with a median precision of 0.00023 A. A web-based interface is offered for interactive visualization of segments of the atlas or spectral orders.

  11. Influence of electromagnetic radiation on the power balance in a radiofrequency microdischarge with a hollow needle electrode

    SciTech Connect (OSTI)

    Despax, B.; Pascal, O.; Gherardi, N.; Naude, N.; Belinger, A.; Pitchford, L. C.

    2012-10-01

    This study is focused on the power deposition in microplasma jet discharges generated by application of radiofrequency (RF) excitation to a hollow needle electrode. The plasma jet is initiated at atmospheric pressure in open air with a flow of helium through the electrode. We show that in this configuration, a significant part of the injected power is dissipated in electromagnetic radiation. Many recent works have demonstrated the potential of either cold plasma jets or of RF radiation for applications in medicine, and therefore a source that produces both a cold plasma jet and RF radiation could be of interest.

  12. A one-pot synthetic approach to prepare palladium nanoparticles embedded hierarchically porous TiO{sub 2} hollow spheres for hydrogen peroxide sensing

    SciTech Connect (OSTI)

    Kong Lirong; Lu Xiaofeng; Bian Xiujie; Zhang Wanjin; Wang Ce

    2010-10-15

    A simple one-step method to fabricate hierarchically porous TiO{sub 2}/Pd composite hollow spheres without any template was developed by using solvothermal treatment. Pd nanoparticles (2-5 nm) were well dispersed in the mesopores of the TiO{sub 2} hollow spheres via in-situ reduction. In our experiment, polyvinylpyrrolidone played an important role in the synthetic process as the reducing agent and the connective material between TiO{sub 2} and Pd nanoparticles. HF species generated from solvothermal reaction leaded to the formation of TiO{sub 2} hollow spheres and Ostwald ripening was another main factor that affected the size and structure of the hollow spheres. The as-prepared TiO{sub 2}/Pd composite hollow spheres exhibited high electrocatalytic activity towards the reduction of H{sub 2}O{sub 2}. The sensitivity was about 226.72 {mu}A mM{sup -1} cm{sup -2} with a detection limit of 3.81 {mu}M at a signal-to-noise ratio of 3. These results made the hierarchically porous TiO{sub 2}/Pd composite a promising platform for fabricating new nonenzymic biosensors. - Graphical Abstract: A new one-step solvothermal method was developed to prepare Pd nanoparticles embedded hierarchically porous TiO{sub 2} hollow spheres. Due to its unique nanostructure, the prepared TiO{sub 2}/Pd modified GC electrode exhibit a high sensitivity (226.72 {mu}A mM{sup -1} cm{sup -2}), a relatively low reduction potential (-0.2 V), a fast response time (<3 s) and a relatively low detection limit of 3.81 {mu}M (S/N=3) towards H{sub 2}O{sub 2}.

  13. Triple stack glass-to-glass anodic bonding for optogalvanic spectroscopy cells with electrical feedthroughs

    SciTech Connect (OSTI)

    Daschner, R.; Kübler, H.; Löw, R.; Pfau, T., E-mail: t.pfau@physik.uni-stuttgart.de [5. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, 70550 Stuttgart (Germany); Baur, H.; Frühauf, N. [Institut für Großflächige Mikroelektronik, Universität Stuttgart, 70569 Stuttgart (Germany)

    2014-07-28

    We demonstrate the use of an anodic bonding technique for building a vacuum tight vapor cell for the use of Rydberg spectroscopy of alkali atoms with thin film electrodes on the inside of the cell. The cell is fabricated by simultaneous triple stack glass-to-glass anodic bonding at 300?°C. This glue-free, low temperature sealing technique provides the opportunity to include thin film electric feedthroughs. The pressure broadening is only limited by the vapor pressure of rubidium and the lifetime is at least four months with operating temperatures up to 230?°C.

  14. Indentation size effect and the plastic compressibility of glass

    SciTech Connect (OSTI)

    Smedskjaer, Morten M., E-mail: mos@bio.aau.dk [Section of Chemistry, Aalborg University, 9000 Aalborg (Denmark)

    2014-06-23

    Oxide glasses exhibit significant densification under an applied isostatic pressure at the glass transition temperature. The glass compressibility is correlated with the chemical composition and atomic packing density, e.g., borate glasses with planar triangular BO{sub 3} units are more disposed for densification than silicate glasses with tetrahedral units. We here show that there is a direct relation between the plastic compressibility following hot isostatic compression and the extent of the indentation size effect (ISE), which is the decrease of hardness with indentation load exhibited by most materials. This could suggest that the ISE is correlated with indentation-induced shear bands, which should form in greater density when the glass network is more adaptable to volume changes through structural and topological rearrangements under an applied pressure.

  15. Phosphate Glasses for Vitrification of Waste with High Sulfur Content

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.; Hrma, Pavel R.; Cassingham, Nathan J.

    2002-10-31

    The low solubility of sulfate in silicate-based glasses, approximately 1 mass% as SO3, limits the loading of high-level waste (HLW) and low-activity waste (LAW) containing high concentrations of sulfur. Based on crucible melting studies, we have shown that the phosphate glasses may incorporate more than 5 mass% SO3; hence, the waste loading can be increased until another constraint is met, such as glass durability. A high-sulfate HLW glass has been formulated and tested to demonstrate the advantages of phosphate glasses. The effect of waste loading on the chemical durability of quenched and slow-cooled phosphate glasses was determined using the Product Consistency Test.

  16. Interaction between Drilled Shaft and Mechanically Stabilized Earth (MSE) Wall 

    E-Print Network [OSTI]

    Aghahadi Forooshani, Mohammad

    2014-08-28

    Drilled shafts under horizontal loads are being constructed within Mechanically Stabled Earth (MSE) walls in the reinforced zone especially in overpass bridges and traffic signs. The interaction between the drilled shafts and the MSE wall...

  17. Electrical properties of single wall carbon nanotube reinforced polyimide composites

    E-Print Network [OSTI]

    Ounaies, Zoubeida

    Electrical properties of single wall carbon nanotube reinforced polyimide composites Z. Ounaiesa of single wall carbon nanotube (SWNT) reinforced polyimide composites were investigated as a function nanotube; Composites 1. Introduction Polyimides are widely used in applications ranging from

  18. After Exodus : re-occupation of the metropolitan wall

    E-Print Network [OSTI]

    Allison, Jordan Lloyd Norman

    2012-01-01

    The title "Exodus alludes to a restricted exclave encircled by a forbidding wall -- effect, a prison on the scale of a metropolis, and one in which people sought refuge voluntarily. Over the past forty years, similar walls ...

  19. Double Diffusion in Enclosure Bounded by Massive and Volatilizing Walls 

    E-Print Network [OSTI]

    Liu, D.; Tang, G.; Zhao, F.

    2006-01-01

    Hazard volatilization emitted from walls enters into airflow in the room, making the indoor air quality worse. An exterior wall of some thickness is affected on its surface by the outdoor air environment. In this paper, ...

  20. DESIGN OF A TOKAMAK FUSION REACTOR FIRST WALL ARMOR AGAINST NEUTRAL BEAM IMPINGEMENT

    E-Print Network [OSTI]

    Myers, Richard Allen

    2011-01-01

    exceed that of fusion power reactors for wall loadings up toplasma. The vessel wall temperatures in power reactors isfor· the first wall of fusion power reactors. However, for

  1. Progress on a Cavity with Beryllium Walls for Muon Ionization Cooling Channel R&D.

    E-Print Network [OSTI]

    Bowring, D.L.

    2014-01-01

    ON A CAVITY WITH BERYLLIUM WALLS FOR MUON IONIZATION COOLINGFabricating a cavity with beryllium walls would mitigatepillbox RF cavity with beryllium walls, in order to evaluate

  2. Formulation and Characterization of Waste Glasses with Varying Processing Temperature

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, M. J.; Rodriguez, Carmen P.; Lepry, William C.; Lang, Jesse B.; Crum, Jarrod V.; Vienna, John D.; Johnson, Fabienne; Marra, James C.; Peeler, David K.

    2011-10-17

    This report documents the preliminary results of glass formulation and characterization accomplished within the finished scope of the EM-31 technology development tasks for WP-4 and WP-5, including WP-4.1.2: Glass Formulation for Next Generation Melter, WP-5.1.2.3: Systematic Glass Studies, and WP-5.1.2.4: Glass Formulation for Specific Wastes. This report also presents the suggested studies for eventual restart of these tasks. The initial glass formulation efforts for the cold crucible induction melter (CCIM), operating at {approx}1200 C, with selected HLW (AZ-101) and LAW (AN-105) successfully developed glasses with significant increase of waste loading compared to that is likely to be achieved based on expected reference WTP formulations. Three glasses formulated for AZ-101HLW and one glass for AN-105 LAW were selected for the initial CCIM demonstration melter tests. Melter tests were not performed within the finished scope of the WP-4.1.2 task. Glass formulations for CCIM were expanded to cover additional HLWs that have high potential to successfully demonstrate the unique advantages of the CCIM technologies based on projected composition of Hanford wastes. However, only the preliminary scoping tests were completed with selected wastes within the finished scope. Advanced glass formulations for the reference WTP melter, operating at {approx}1200 C, were initiated with selected specific wastes to determine the estimated maximum waste loading. The incomplete results from these initial formulation efforts are summarized. For systematic glass studies, a test matrix of 32 high-aluminum glasses was completed based on a new method developed in this study.

  3. Laser stimulated emission cross sections of Nd glasses

    SciTech Connect (OSTI)

    Tucker, A.W.; Birnbaum, M.; Fincher, C.L.

    1982-01-01

    A laser-comparison method was used to determine the emission cross sections at 1060 nm of Nd glasses used in laser fusion systems. The values obtained for two phosphate glasses (LHG-8) and (Q-88) were 4.0 +- 0.8 x 10/sup -20/ cm/sup 2/ and 1.7 +- 0.5 x 10/sup -20/ cm/sup 2/ for a silicate glass (LG-650).

  4. Using sputter coated glass to stabilize microstrip gas chambers

    DOE Patents [OSTI]

    Gong, Wen G. (Albany, CA)

    1997-01-01

    By sputter coating a thin-layer of low-resistive, electronically-conductive glass on various substrates (including quartz and ceramics, thin-film Pestov glass), microstrip gas chambers (MSGC) of high gain stability, low leakage current, and a high rate capability can be fabricated. This design can make the choice of substrate less important, save the cost of ion-implantation, and use less glass material.

  5. The beryllium hollow-body solar sail: exploration of the Sun's gravitational focus and the inner Oort Cloud

    E-Print Network [OSTI]

    Gregory L. Matloff; Roman Ya. Kezerashvili; Claudio Maccone; Les Johnson

    2008-09-20

    Spacecraft kinematics, peak perihelion temperature and space environment effects during solar-radiation-pressure acceleration for a beryllium hollow-body interstellar solar sail inflated with hydrogen fill gas are investigated. We demonstrate that diffusion is alleviated by an on-board fill gas reserve and electrostatic pressure can be alleviated by increasing perihelion distance. For a 0.1 AU perihelion, a 937 m radius sail with a sail mass of 150 kg and a payload mass of 150 kg, perihelion sail temperature is about 1000 K, peak acceleration is about 0.6 g, and solar-system exit velocity is about 400 km/s. After sail deployments, the craft reaches the 200 AU heliopause in 2.5 years, the Sun's inner gravitational focus at 550 AU in about 6.5 years and 2,550 AU in 30 years. The Be hollow-body sail could be applied in the post 2040 time frame to verify general relativity predictions regarding the Sun's inner gravitational focus and to explore particles and fields in the Sun's inner Oort Comet Cloud.

  6. High Performance Walls in Hot-Dry Climates

    SciTech Connect (OSTI)

    Hoeschele, M.; Springer, D.; Dakin, B.; German, A.

    2015-01-01

    High performance walls represent a high priority measure for moving the next generation of new homes to the Zero Net Energy performance level. The primary goal in improving wall thermal performance revolves around increasing the wall framing from 2x4 to 2x6, adding more cavity and exterior rigid insulation, achieving insulation installation criteria meeting ENERGY STAR's thermal bypass checklist, and reducing the amount of wood penetrating the wall cavity.

  7. Collaboration yields 'The Right Glasses' for observing mystery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observing mystery behavior In electrons Collaboration yields 'The Right Glasses' for observing mystery behavior in electrons The research may lead to a better understanding of...

  8. Piezooptic coefficients of four neodymium-doped laser glasses

    SciTech Connect (OSTI)

    Waxler, R.M.; Feldman, A.

    1980-08-01

    The stress-induced birefringence was measured for the phosphate glasses Q-88, LG-812, E-181, and LHG-10. (AIP)

  9. Welding/sealing glass-enclosed space in a vacuum

    DOE Patents [OSTI]

    Tracy, C.E.; Benson, D.K.

    1996-02-06

    A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbent material, such as FeO, VO{sub 2}, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbent material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbent material melts glass in the portions of both glass sheets that are adjacent the absorbent material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbent material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbent material to source energy power and welding heat needed, the process can be made self-stopping. 8 figs.

  10. Welding/sealing glass-enclosed space in a vacuum

    DOE Patents [OSTI]

    Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

    1996-01-01

    A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbant material, such as FeO, VO.sub.2, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbant material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbant material melts glass in the portions of both glass sheets that are adjacent the absorbant material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbant material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbant material to source energy power and welding heat needed, the process can be made self-stopping.

  11. Graded-Refractive-Index Glass-based Antireflective Coatings:...

    Office of Scientific and Technical Information (OSTI)

    Graded-Refractive-Index Glass-based Antireflective Coatings: BroadbandOmnidirectional Light Harvesting and Self-Cleaning Characteristics Citation Details In-Document Search Title:...

  12. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.; Franco, S.C.S.

    1994-03-29

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications. 6 figures.

  13. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, Lynn A. (Oak Ridge, TN); Sales, Brian C. (Knoxville, TN); Franco, Sofia C. S. (Santafe de Bogota, CO)

    1994-01-01

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications.

  14. Time-Domain Electromagnetics At Glass Mountain Area (Cumming...

    Open Energy Info (EERE)

    Time-Domain Electromagnetics At Glass Mountain Area (Cumming And Mackie, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Time-Domain...

  15. Dynamical heterogeneities in an attraction driven colloidal glass

    E-Print Network [OSTI]

    Antonio M. Puertas; Matthias Fuchs; Michael E. Cates

    2006-01-16

    The dynamical heterogeneities (DH) in non-ergodic states of an attractive colloidal glass are studied, as a function of the waiting time. Whereas the fluid states close to vitrify showed strong DH, the distribution of squared displacements of the glassy states studied here only present a tail of particles with increased mobility for the lower attraction strength at short waiting times. These particles are in the surface of the percolating cluster that comprises all of the particles, reminiscent of the fastest particles in the fluid. The quench deeper into the attractive glass is dynamically more homogeneous, in agreement with repulsive glasses (i.e. Lennard-Jones glass).

  16. Economic manufacturing of bulk metallic glass compositions by microalloying

    DOE Patents [OSTI]

    Liu, Chain T.

    2003-05-13

    A method of making a bulk metallic glass composition includes the steps of:a. providing a starting material suitable for making a bulk metallic glass composition, for example, BAM-11; b. adding at least one impurity-mitigating dopant, for example, Pb, Si, B, Sn, P, to the starting material to form a doped starting material; and c. converting the doped starting material to a bulk metallic glass composition so that the impurity-mitigating dopant reacts with impurities in the starting material to neutralize deleterious effects of the impurities on the formation of the bulk metallic glass composition.

  17. Glass fiber composition. [for use as thermal insulation

    DOE Patents [OSTI]

    Wolf, G.A.; Kupfer, M.J.

    1980-12-19

    The invention relates to a glass fiber composition useful for thermal insulation having a low melting temperature and high chemical durability.

  18. Thermal Predictions of the Cooling of Waste Glass Canisters

    SciTech Connect (OSTI)

    Donna Post Guillen

    2014-11-01

    Radioactive liquid waste from five decades of weapons production is slated for vitrification at the Hanford site. The waste will be mixed with glass forming additives and heated to a high temperature, then poured into canisters within a pour cave where the glass will cool and solidify into a stable waste form for disposal. Computer simulations were performed to predict the heat rejected from the canisters and the temperatures within the glass during cooling. Four different waste glass compositions with different thermophysical properties were evaluated. Canister centerline temperatures and the total amount of heat transfer from the canisters to the surrounding air are reported.

  19. High Waste Loading Glass Formulations for Hanford High-Aluminum...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for...

  20. Method of processing ``BPS`` glass ceramic and seals made therewith

    DOE Patents [OSTI]

    Reed, S.T.; Stone, R.G.; McCollister, H.L.; Wengert, P.R.

    1998-10-13

    A glass ceramic composition, a glass ceramic-to-metal seal, and more specifically a hermetic glass ceramic-to-metal seal prepared by subjecting a glass composition comprising, by weight percent, SiO{sub 2} (65--80%), LiO{sub 2} (8--16%), Al{sub 2}O{sub 3} (2--8%), K{sub 2}O (1--8%), P{sub 2}O{sub 5} (1--5%), B{sub 2}O{sub 3} (0.5--7%), and ZnO (0--5%) to the following processing steps: (1) heating the glass composition in a belt furnace to a temperature sufficient to melt the glass and crystallize lithium phosphate, (2) holding at a temperature and for a time sufficient to create cristobalite nuclei, (3) cooling at a controlled rate and to a temperature to cause crystallization of lithium silicates and growth of cristobalite, and (4) still further cooling in stages to ambient temperature. This process produces a glass ceramic whose high coefficient of thermal expansion (up to 200{times}10{sup {minus}7} in/in/C) permits the fabrication of glass ceramic-to-metal seals, and particularly hermetic glass ceramic seals to nickel-based and stainless steel alloys and copper. 5 figs.