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1

Definition: Reactive Power | Open Energy Information  

Open Energy Info (EERE)

Reactive Power Reactive Power Jump to: navigation, search Dictionary.png Reactive Power The portion of electricity that establishes and sustains the electric and magnetic fields of alternating-current equipment. Reactive power must be supplied to most types of magnetic equipment, such as motors and transformers. It also must supply the reactive losses on transmission facilities. Reactive power is provided by generators, synchronous condensers, or electrostatic equipment such as capacitors and directly influences electric system voltage. It is usually expressed in kilovars (kvar) or megavars (Mvar).[1] View on Wikipedia Wikipedia Definition In electric power transmission and distribution, volt-ampere reactive (var) is a unit used to measure reactive power in an AC electric

2

Chevrolet Volt Vehicle Demonstration  

Broader source: Energy.gov (indexed) [DOE]

Volt Vehicle Demonstration Fleet Summary Report Reporting period: January 2013 through March 2013 Number of vehicles: 146 Number of vehicle days driven: 6,680 4292013 2:38:13 PM...

3

Definition: Ampere | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Ampere Jump to: navigation, search Dictionary.png Ampere A unit of measure for electric current that refers to the amount of electric charge passing a point per unit of time; frequently abbreviated to "amp".[1][2] View on Wikipedia Wikipedia Definition The ampere, often shortened to amp, is the SI unit of electric current and is one of the seven SI base units. It is named after André-Marie Ampère (1775-1836), French mathematician and physicist, considered the father of electrodynamics. In practical terms, the ampere is a measure of the amount of electric charge passing a point in an electric circuit per unit time with 6.241 × 10 electrons, or one coulomb per second constituting one ampere. The practical definition may lead to

4

4160 Volt .pdf  

Broader source: Energy.gov (indexed) [DOE]

" " ~, U.S. Department of Energy Naval Reactors laboratory Field Office Knolls Laboratory National Environmental Policy Act (NEPA) Categorical Exclusion (CX) Determination Summary Form 4160 Volt Upgrade Project REFERENCE: 10 CFR Part 1021 , Department of Energy National Environmental Policy Act Implementation Procedures, Subpart 0 , Typical Classes of Actions PROJECT SCOPE DISCUSSION The scope of 4160 Volt Upgrade Project is to make significant improvements to the 4160 Volt power distribution system at the Knolls Laboratory by replacing antiquated (60 year old) switchgear and cabling located in the Z4 high yard with new state-of-the-art equipment. The new switch gear will be located in the NW corner of the existing Z8 High Yard. In addition to

5

Load Impedance as a Function of Power Input in 70-Volt, 100-Volt, and 25-Volt Distribution Systems  

Science Journals Connector (OSTI)

Distributed loudspeaker systems often make use of 70-volt or 100-volt distribution methods. In a 70-volt system, the full power of the amplifier, whatever it might be, is always available at 70 volts rms. By m...

John M. Eargle

2002-01-01T23:59:59.000Z

6

Sky Volt | Open Energy Information  

Open Energy Info (EERE)

Volt Volt Jump to: navigation, search Name Sky Volt Facility Sky Volt Sector Wind energy Facility Type Community Wind Facility Status In Service Owner Sky Volt LLC (community owned) Energy Purchaser City of Greenfield - excess to Central Iowa Power Cooperative Location Greenfield IA Coordinates 41.29038343°, -94.48851585° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.29038343,"lon":-94.48851585,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

7

Clock for and CAMAC hardware for measurement of volt-amphere characteristic of thermionic converter  

SciTech Connect (OSTI)

This paper describes a clock that is controlled by a computer through a CAMAC output-register module. The clock trigger the load of a thermionic converter for measurement of the volt-ampere charecteristic for 10 msec and synchronizes the start of measurement with the phase of the applied voltage. A schemitic diagram of the clock is shown. The clock increases the data-acquisition speed in successive measurement of several VACs with a limited amount of buffer memory.

DZHASHIASHVILI, Yu.N.

1986-09-01T23:59:59.000Z

8

Conservation of reactive electromagnetic energy in reactive time  

E-Print Network [OSTI]

The complex Poynting theorem (CPT) is extended to a canonical time-scale domain $(t,s)$. Time-harmonic phasors are replaced by the positive-frequency parts of general fields, which extend analytically to complex time $t+is$, with $s>0$ interpreted as a time resolution scale. The real part of the extended CPT gives conservation in $t$ of a time-averaged field energy, and its imaginary part gives conservation in $s$ of a time-averaged reactive energy. In both cases, the averaging windows are determined by a Cauchy kernel of width $\\Delta t\\sim \\pm s$. This completes the time-harmonic CPT, whose imaginary part is generally supposed to be vaguely `related to' reactive energy without giving a conservation law, or even an expression, for the latter. The interpretation of $s$ as reactive time, tracking the leads and lags associated with stored capacitative and inductive energy, gives a simple explanation of the volt-ampere reactive (var) unit measuring reactive power: a var is simply one Joule per reactive second. T...

Kaiser, Gerald

2015-01-01T23:59:59.000Z

9

Amper Central Solar SA | Open Energy Information  

Open Energy Info (EERE)

Solar SA Place: Moura, Portugal Zip: 7860 231 Sector: Solar Product: Portugal-based solar PV project developer. References: Amper Central Solar SA1 This article is a stub....

10

GreenVolts Inc | Open Energy Information  

Open Energy Info (EERE)

Name: GreenVolts Inc Place: San Francisco, California Zip: 94105 Product: US-based manufacturer of concentrating PV (CPV). References: GreenVolts Inc1 This article is a stub....

11

E-Print Network 3.0 - ampere average current Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

students' difficulties with Ampere's law Colin S. Wallace1, Summary: . In terms of Ampere's law, this course spent five lectures on current distributions, Ampere's...

12

Sandia National Laboratories: HelioVolt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Regional Testing Center (PV RTC), Renewable Energy, Solar, Solar Newsletter, SunShot HelioVolt, Sandia National Laboratories, the National Renewable Energy Laboratory,...

13

Bonneville Power Ampere Annex Z-995 Building  

High Performance Buildings Database

Vancouver, WA The Bonneville Power Administration (BPA), a federal agency headquartered in Portland, Oregon, provides about half of the electricity used in the Pacific Northwest and operates more than three-fourths of the region's high-voltage transmission. Because BPA markets power at cost from 31 federal dams, its rates are among the least expensive electricity in the country. The Ampere Annex project is a renovation of an exisiting 60-year-old standard warehouse building located within the Ross Complex.

14

2011 Chevrolet Volt EREV Accelerated Testing - June 2013  

Broader source: Energy.gov (indexed) [DOE]

Chevrolet Volt EREV Accelerated Testing - June 2013 Two model year 2011 Chevrolet Volt extended range electric vehicles (EREVs) entered Accelerated testing during March 2011 in a...

15

GreenVolts | Open Energy Information  

Open Energy Info (EERE)

GreenVolts GreenVolts Jump to: navigation, search Logo: GreenVolts Name GreenVolts Address 50 First Street Place San Francisco, California Zip 94105 Sector Solar Product PV developer Website http://www.greenvolts.com/ Coordinates 37.790153°, -122.398669° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.790153,"lon":-122.398669,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

16

HydroVolts | Open Energy Information  

Open Energy Info (EERE)

HydroVolts HydroVolts Jump to: navigation, search Name HydroVolts Address 2815 Eastlake Ave E Place Seattle, Washington Zip 98102 Sector Hydro Product Aims to develop renewable energy from canals, waterways, streams, and ocean currents Website http://www.hydrovolts.com/ Coordinates 47.645778°, -122.3257532° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":47.645778,"lon":-122.3257532,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

17

HelioVolt Corporation | Open Energy Information  

Open Energy Info (EERE)

HelioVolt Corporation HelioVolt Corporation Jump to: navigation, search Name HelioVolt Corporation Place Austin, Texas Zip TX 78744 Product Copper indium gallium selenide (CIGS) thin-film PV module manufacturer based in Austin, Texas. Website http://www.heliovolt.net/ Coordinates 30.267605°, -97.742984° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":30.267605,"lon":-97.742984,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

18

Nissan Leafs and Chevrolet Volts Reporting Data in The EV Project  

Broader source: Energy.gov (indexed) [DOE]

Knoxville 88 Leafs 17 Volts DC 7 Leafs 177 Volts San Diego 657 Leafs 153 Volts 300 Smart Electric Drives Tucson 79 Leafs 7 Volts Chattanooga 50 Leafs 11 Volts Copyright: 2009...

19

AVTA: Chevrolet Volt 2013 Testing Results  

Broader source: Energy.gov [DOE]

The Vehicle Technologies Office's Advanced Vehicle Testing Activity carries out testing on a wide range of advanced vehicles and technologies on dynamometers, closed test tracks, and on-the-road. These results provide benchmark data that researchers can use to develop technology models and guide future research and development. The following reports describe results of testing done on a 2013 Chevrolet Volt. Baseline and battery testing data collected at Argonne National Laboratory is available in summary and CSV form on the Argonne Downloadable Dynometer Database site (http://www.transportation.anl.gov/D3/2013_chevy_volt_phev.html). The reports for download here are based on research done at Idaho National Laboratory. Taken together, these reports give an overall view of how this vehicle functions under extensive testing.

20

Chevy Volt Electrifies DOE Headquarters | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Chevy Volt Electrifies DOE Headquarters Chevy Volt Electrifies DOE Headquarters Chevy Volt Electrifies DOE Headquarters December 9, 2010 - 7:05pm Addthis Dennis A. Smith Director, National Clean Cities Yesterday, Department of Energy staff members were able to experience the newest in market-ready vehicle technology when representatives from General Motors brought two Chevy Volts to Department headquarters. Officials and engineers alike, including the Department's Chief Financial Officer, Steve Isakowitz, test drove the Volt, and peppered the GM representatives with questions about the new plug-in hybrid electric vehicle. Unlike an all-electric vehicle (EV), the Volt has a gasoline engine that supplements the electric drive once the battery is depleted. The Chevrolet Volt will reach an estimated 93 mpg-equivalent when running on all-electric

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Nissan Leafs and Chevrolet Volts Reporting Data in The EV Project...  

Broader source: Energy.gov (indexed) [DOE]

898 Leafs 164 Volts Oregon 541 Leafs 133 Volts 30 Smart Electric Drives San Francisco 1708 Leafs Los Angeles 424 Leafs 338 Volts Chicago 26 Leafs 129 Volts Atlanta 153 Leafs 75...

22

HelioVolt Inc | Open Energy Information  

Open Energy Info (EERE)

Inc Inc Jump to: navigation, search Name HelioVolt Inc Address 8201 E. Riverside Dr Place Austin, Texas Zip 78744 Sector Solar Product Thin-film solar panel producer Website http://www.heliovolt.net/ Coordinates 30.216908°, -97.685078° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":30.216908,"lon":-97.685078,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

23

The Department of Energy's Innovation in GM's Chevrolet Volt | Department  

Broader source: Energy.gov (indexed) [DOE]

The Department of Energy's Innovation in GM's Chevrolet Volt The Department of Energy's Innovation in GM's Chevrolet Volt The Department of Energy's Innovation in GM's Chevrolet Volt January 11, 2011 - 11:49am Addthis Chevy Volt and replica battery | Photo Courtesy of Argonne Lab's Flickr Chevy Volt and replica battery | Photo Courtesy of Argonne Lab's Flickr Patrick B. Davis Patrick B. Davis Vehicle Technologies Program Manager Last Thursday was a big day in the world of advanced vehicle batteries. On January 6, the Department of Energy's Argonne National Laboratory announced that General Motors and its battery cell supplier, LG Chem Power Inc., have each signed licensing agreements to use Argonne's breakthrough battery technology. Funded by the Department, scientists at Argonne have developed a unique suite of cathode materials - a 'family' of lithium-rich

24

The Department of Energy's Innovation in GM's Chevrolet Volt | Department  

Broader source: Energy.gov (indexed) [DOE]

Innovation in GM's Chevrolet Volt Innovation in GM's Chevrolet Volt The Department of Energy's Innovation in GM's Chevrolet Volt January 11, 2011 - 11:49am Addthis Chevy Volt and replica battery | Photo Courtesy of Argonne Lab's Flickr Chevy Volt and replica battery | Photo Courtesy of Argonne Lab's Flickr Patrick B. Davis Patrick B. Davis Vehicle Technologies Program Manager Last Thursday was a big day in the world of advanced vehicle batteries. On January 6, the Department of Energy's Argonne National Laboratory announced that General Motors and its battery cell supplier, LG Chem Power Inc., have each signed licensing agreements to use Argonne's breakthrough battery technology. Funded by the Department, scientists at Argonne have developed a unique suite of cathode materials - a 'family' of lithium-rich

25

SeaVolt Technologies formerly Sea Power Associates | Open Energy  

Open Energy Info (EERE)

SeaVolt Technologies formerly Sea Power Associates SeaVolt Technologies formerly Sea Power Associates Jump to: navigation, search Name SeaVolt Technologies (formerly Sea Power & Associates) Place San Francisco, California Zip CA 94111 Sector Ocean Product The company's Wave Rider system, which is still in prototype stages, uses buoys and hydraulic pumps to convert the movement of ocean waves into electricity. References SeaVolt Technologies (formerly Sea Power & Associates)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This company is listed in the Marine and Hydrokinetic Technology Database. This article is a stub. You can help OpenEI by expanding it. SeaVolt Technologies (formerly Sea Power & Associates) is a company located in San Francisco, California .

26

Advances in 3-Volt Lithium Batteries for Electronic Applications  

Science Journals Connector (OSTI)

Significant improvements have been made in recent years in the performance, reliability and operating temperature range of 3-volt primary lithium cell systems. Because of their excellent characteristics, especially their long life, they are not only ...

R. A. Langan; V. Z. Leger; G. R. Tucholski

1985-08-01T23:59:59.000Z

27

A Method for Evaluating Volt-VAR Optimization Field Demonstrations  

SciTech Connect (OSTI)

In a regulated business environment a utility must be able to validate that deployed technologies provide quantifiable benefits to the end-use customers. For traditional technologies there are well established procedures for determining what benefits will be derived from the deployment. But for many emerging technologies procedures for determining benefits are less clear and completely absent in some cases. Volt-VAR Optimization is a technology that is being deployed across the nation, but there are still numerous discussions about potential benefits and how they are achieved. This paper will present a method for the evaluation, and quantification of benefits, for field deployments of Volt-VAR Optimization technologies. In addition to the basic methodology, the paper will present a summary of results, and observations, from two separate Volt-VAR Optimization field evaluations using the proposed method.

Schneider, Kevin P.; Weaver, T. F.

2014-08-31T23:59:59.000Z

28

CyVolt Energy Systems | Open Energy Information  

Open Energy Info (EERE)

CyVolt Energy Systems CyVolt Energy Systems Jump to: navigation, search Name CyVolt Energy Systems Place Seattle, Washington Zip 98104 Product Seattle-based developer fuel cell-powered battery systems for portable, hand-held consumer electronics Coordinates 47.60356°, -122.329439° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":47.60356,"lon":-122.329439,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

29

Measurements of the volt-ampere characteristics and the breakdown voltages of direct-current helium and hydrogen discharges in microgaps  

SciTech Connect (OSTI)

The discharge phenomena for micro meter gap sizes include many interesting problems from engineering and physical perspectives. In this paper, the authors deal with the experimental and theoretical results of the breakdown voltage and current-voltage characteristics of the direct-current helium and hydrogen discharges. The measurements were performed at a constant pressure of around one atmosphere, while varying the gap size between two parallel plane tungsten electrodes between 1??m and 100??m. From the measured breakdown voltage curves, the effective yields and the ionization coefficients were derived for both gases. Present data for the ionization coefficients correlate with the data obtained for the breakdown voltage curves measured for fixed 100??m interelectrode separation. The current-voltage characteristics were plotted for the various gap sizes illustrating the role of the field emission effects in the microgaps. Based on the Fowler-Nordheim theory, the enhancement factors were determined. The gap spacing dependence of the field emission current can be explained by the introduction of two ideas, the first being a space charge effect by emitted electrons, and the second a change in the breakdown mechanism. Experimental results, presented here, demonstrate that Townsend phenomenology breaks down when field emission becomes the key mechanism affecting the breakdown and deforming the left hand side of the breakdown voltage curves.

Klas, M.; Matej?ik, . [Department of Experimental Physics, Comenius University, Mlynskadolina F2, 84248 Bratislava (Slovakia); Radjenovi?, B.; Radmilovi?-Radjenovi?, M. [Institute of Physics, University of Belgrade, P.O. Box 57, 11080 Belgrade (Serbia)

2014-10-15T23:59:59.000Z

30

Capacitor-Less VAR Compensator Based on a Matrix Converter  

E-Print Network [OSTI]

Reactive power, denoted as volt-ampere reactive (VARs), is fundamental to ac power systems and is due to the complex impedance of the loads and transmission lines. It has several undesirable consequences which include increased transmission loss...

Balakrishnan, Divya Rathna

2012-02-14T23:59:59.000Z

31

Nissan Leafs and Chevrolet Volts Reporting Data in The EV Project...  

Broader source: Energy.gov (indexed) [DOE]

December 2012 Washington State 893 Leafs 98 Volts Oregon 549 Leafs 94 Volts 30 Smart Electric Drives San Francisco 1730 Lea fs Los Angeles 497 Lea fs 165 Vo lts Chicago 29...

32

Guidelines for Working at Voltages < 240 Volts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Guidelines for Working at Voltages < 240 Volts Guidelines for Working at Voltages < 240 Volts February 4, 2005---DRAFT NOTE: Working hot is a LAST ALTERNATIVE. Electrical hot work is defined as: Working on or near exposed conducting parts that are or might become energized at 50V or more. Refer to Electrical Safety Flowchart for Working On or Near Live Parts. Engineered methods to prevent exposed sources of 50V and greater are to be implemented wherever practical. Only QUALIFIED PERSONNEL {as defined in NFPA 70E Article 110.6(D) 2004 edition} as authorized by the CAT/supervisor/division can perform such work. Refer to Qualified Electrical Worker Flow Chart. Training requirements: ES&H 114 (LOTO) / ES&H 375 (NFPA 70E) / ES&H 371 (electrical worker) - Observe Electrical Safe Work Practices. Refer to

33

A new approach based on ant colony optimization for daily Volt/Var control in distribution networks considering distributed generators  

Science Journals Connector (OSTI)

This paper presents a new approach to daily Volt/Var control in distribution systems with regard to distributed generators (DGs). Due to the small X/R ratio and radial configuration of distribution systems, \\{DGs\\} have much impact on this problem. A cost-based compensation methodology is proposed as a proper signal to encourage owners of \\{DGs\\} in active and reactive power generation. An evolutionary method based on ant colony optimization (ACO) is used to determine the active and reactive power values of DGs, reactive power values of capacitors and tap positions of transformers for the next day. The results indicate that the proposed encouraging factor has improved the performance of distribution networks on a large scale.

Taher Niknam

2008-01-01T23:59:59.000Z

34

The Breakthrough Behind the Chevy Volt Battery | U.S. DOE Office of Science (SC)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The Breakthrough Behind the Chevy Volt Battery The Breakthrough Behind the Chevy Volt Battery Stories of Discovery & Innovation The Breakthrough Behind the Chevy Volt Battery Enlarge Photo Image courtesy of General Motors The 2011 Chevrolet Volt's 16 kWh battery can be recharged using a 120V or 240V outlet. The car's lithium-ion battery is based on technology developed at Argonne National Laboratory. Enlarge Photo Illustration courtesy Argonne National Laboratory This illustration shows the inner workings of a lithium-ion battery. When delivering energy to a device, the lithium ion moves from the anode to the cathode. The ion moves in reverse when recharging. Compared to other rechargeable 03.28.11 The Breakthrough Behind the Chevy Volt Battery A revolutionary breakthrough cathode for lithium-ion batteries-the kind in your

35

A new HBMO algorithm for multiobjective daily Volt/Var control in distribution systems considering Distributed Generators  

Science Journals Connector (OSTI)

In recent years, Distributed Generators (DGs) connected to the distribution network have received increasing attention. The connection of enormous \\{DGs\\} into existing distribution network changes the operation of distribution systems. Because of the small X/R ratio and radial structure of distribution systems, \\{DGs\\} affect the daily Volt/Var control. This paper presents a new algorithm for multiobjective daily Volt/Var control in distribution systems including Distributed Generators (DGs). The objectives are costs of energy generation by \\{DGs\\} and distribution companies, electrical energy losses and the voltage deviations for the next day. A new optimization algorithm based on a Chaotic Improved Honey Bee Mating Optimization (CIHBMO) is proposed to determine the active power values of DGs, reactive power values of capacitors and tap positions of transformers for the next day. Since objectives are not the same, a fuzzy system is used to calculate the best solution. The plausibility of the proposed algorithm is demonstrated and its performance is compared with other methods on a 69-bus distribution feeder. Simulation results illustrate that the proposed algorithm has better outperforms the other algorithms.

Taher Niknam

2011-01-01T23:59:59.000Z

36

2011 Chevrolet Volt VIN 0815 Plug-In Hybrid Electric Vehicle...  

Broader source: Energy.gov (indexed) [DOE]

2-29678 2011 Chevrolet Volt VIN 0815 Plug-In Hybrid Electric Vehicle Battery Test Results Tyler Gray Jeffrey Wishart Matthew Shirk July 2013 The Idaho National Laboratory is a U.S....

37

Constant residual electrostatic electron plasma mode in Vlasov-Ampere system  

SciTech Connect (OSTI)

In a collisionless Vlasov-Poisson (V-P) electron plasma system, two types of modes for electric field perturbation exist: the exponentially Landau damped electron plasma waves and the initial-value sensitive ballistic modes. Here, the V-P system is modified slightly to a Vlasov-Ampere (V-A) system. A new constant residual mode is revealed. Mathematically, this mode comes from the Laplace transform of an initial electric field perturbation, and physically represents that an initial perturbation (e.g., external electric field perturbation) would not be damped away. Thus, this residual mode is more difficult to be damped than the ballistic mode.

Xie, Hua-sheng [Institute for Fusion Theory and Simulation, Department of Physics, Zhejiang University, Hangzhou 310027 (China)] [Institute for Fusion Theory and Simulation, Department of Physics, Zhejiang University, Hangzhou 310027 (China)

2013-11-15T23:59:59.000Z

38

Actual Versus Estimated Utility Factor of a Large Set of Privately Owned Chevrolet Volts  

SciTech Connect (OSTI)

In order to determine the overall fuel economy of a plug-in hybrid electric vehicle (PHEV), the amount of operation in charge depleting (CD) versus charge sustaining modes must be determined. Mode of operation is predominantly dependent on customer usage of the vehicle and is therefore highly variable. The utility factor (UF) concept was developed to quantify the distance a group of vehicles has traveled or may travel in CD mode. SAE J2841 presents a UF calculation method based on data collected from travel surveys of conventional vehicles. UF estimates have been used in a variety of areas, including the calculation of window sticker fuel economy, policy decisions, and vehicle design determination. The EV Project, a plug-in electric vehicle charging infrastructure demonstration being conducted across the United States, provides the opportunity to determine the real-world UF of a large group of privately owned Chevrolet Volt extended range electric vehicles. Using data collected from Volts enrolled in The EV Project, this paper compares the real-world UF of two groups of Chevrolet Volts to estimated UF's based on J2841. The actual observed fleet utility factors (FUF) for the MY2011/2012 and MY2013 Volt groups studied were observed to be 72% and 74%, respectively. Using the EPA CD ranges, the method prescribed by J2841 estimates a FUF of 65% and 68% for the MY2011/2012 and MY2013 Volt groups, respectively. Volt drivers achieved higher percentages of distance traveled in EV mode for two reasons. First, they had fewer long-distance travel days than drivers in the national travel survey referenced by J2841. Second, they charged more frequently than the J2841 assumption of once per day - drivers of Volts in this study averaged over 1.4 charging events per day. Although actual CD range varied widely as driving conditions varied, the average CD ranges for the two Volt groups studied matched the EPA CD range estimates, so CD range variation did not affect FUF results.

John Smart; Thomas Bradley; Stephen Schey

2014-04-01T23:59:59.000Z

39

How many electric miles do Nissan Leafs and Chevrolet Volts in The EV Project travel?  

SciTech Connect (OSTI)

This paper presents travel statistics and metrics describing the driving behavior of Nissan Leaf and Chevrolet Volt drivers in the EV Project. It specifically quantifies the distance each group of vehicles drives each month. This paper will be published to INL's external website and will be accessible by the general public.

John Smart

2014-05-01T23:59:59.000Z

40

Aerosol-Jet-Printed, 1 Volt HBridge Drive Circuit on Plastic with Integrated Electrochromic Pixel  

E-Print Network [OSTI]

Aerosol-Jet-Printed, 1 Volt HBridge Drive Circuit on Plastic with Integrated Electrochromic Pixel electrochromic (EC) pixel as large as 4 mm2 that is printed on the same substrate. All of the key components, flexible electronics, electrochromic pixel, transistor, capacitor, ion gel 1. INTRODUCTION Printing

Kim, Chris H.

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Generation of mega-electron-volt electron beams by an ultrafast intense laser pulse  

E-Print Network [OSTI]

Generation of mega-electron-volt electron beams by an ultrafast intense laser pulse Xiaofang Wang filamentation and beam breakup. These results suggest an approach for generating a beam of femtosecond, Me-intensity lasers has made it pos- sible to study extreme physics on a tabletop. Among the studies, the generation

Umstadter, Donald

42

Interactive multiobjective daily volt/var control of distribution networks considering wind power and fuel-cell power plants  

Science Journals Connector (OSTI)

This paper deals with a multiobjective daily volt/var control (MDVVC) for radial distribution feeders integrated renewable energy sources (RES) by means of the tap position of the under load tap changer (ULTC) transformers shunt capacitors and active and reactive power of RES. The multiple objective functions to be minimized are the electrical energy losses the voltage deviations and the total emissions of RES and substations. Discrete behavior of equipments in the distribution systems and nonlinear power flow equations change the VVC problem into a mixed integer non-linear programming (MINLP). Hence a new optimization method based upon the shuffled frog leaping algorithm (SFLA) is presented to solve the optimization problem. The SFLA is modified for resolving the disadvantages of the original algorithm. Besides of accurately passing local optima the MSFLA takes less time to achieve the optimal response. Furthermore the tribe-MSFLA is proposed through using the concept of the tribe. Dealing with the multiobjective optimization problem an interactive fuzzy satisfying method is used while the objective functions are formulated by a fuzzy set theory. An 85-bus radial distribution system is used to test and assess the performance of the proposed algorithm.

Taher Niknam; Mohsen Zare; Jamshid Aghaei; Rasoul Azizipanah-Abarghooee

2012-01-01T23:59:59.000Z

43

Engineering Design and Fabrication of an Ampere-Class Superconducting Photocathode Electron Gun  

SciTech Connect (OSTI)

Over the past three years, Advanced Energy Systems and Brookhaven National Laboratory (BNL) have been collaborating on the design of an Ampere- class superconducting photocathode electron gun. BNL performed the physics design of the overall system and RF cavity under prior programs. Advanced Energy Systems (AES) is currently responsible for the engineering design and fabrication of the electron gun under contract to BNL. We will report on the engineering design and fabrication status of the superconducting photocathode electron gun. The overall configuration of the cryomodule will be reviewed. The layout of the hermitic string, space frame, shielding package, and cold mass will be discussed. The engineering design of the gun cavity and removable cathode will be presented in detail and areas of technical risk will be highlighted. Finally, the fabrication sequence and fabrication status of the gun cavity will be discussed.

Ben-Zvi,I.

2008-11-17T23:59:59.000Z

44

A FAMILY OF TWENTY-AMPERES POWER SUPPLIES FOR MULTI-POLE CORRECTORS FOR ACCELERATORS AND STORAGE RINGS  

E-Print Network [OSTI]

A FAMILY OF TWENTY-AMPERES POWER SUPPLIES FOR MULTI- POLE CORRECTORS FOR ACCELERATORS AND STORAGE of accelerator facilities and storage ring complexes in broad range of output power. Some tasks, e.g. powering-150, correspondingly. The power supplies developed meet the requirements of the up-to-date accelerator facilities

Kozak, Victor R.

45

Search for thermonuclear neutrons in a mega-ampere plasma focus  

Science Journals Connector (OSTI)

Plasma focus experiments were carried out at a modified PF-1000 where the cathode disc was added in front of the anode. Experimental results indicated a fraction of thermonuclear neutrons on the mega-ampere current level. In order to prove the thermonuclear mechanism, the time of neutron production and the neutron energy spectrum were measured by time-of-flight (TOF) diagnostics. Neutron TOF signals showed that the neutron production was a multiphase process and more than one mechanism occurred simultaneously. The occurrence of the thermonuclear mechanism was most evident during the plasma stagnation at low deuterium pressures. At low filling pressures, the narrow width of the neutron energy spectra demonstrated an ion temperature of about 1?keV. The possibility of thermonuclear neutrons was studied also after the stagnation, during the main neutron emission. In this case, the thermonuclear mechanism could be verified by calculating the number of deuterons that participate in the fusion process. For the bulk of thermonuclear plasmas, a significant fraction of plasma should participate in fusion. Finally, the basic consideration of the thermonuclear mechanism in Z-pinches showed the reasonableness of the MagLIF concept.

D Klir; P Kubes; M Paduch; T Pisarczyk; T Chodukowski; M Scholz; Z Kalinowska; B Bienkowska; L Karpinski; J Kortanek; J Kravarik; K Rezac; I Ivanova-Stanik; K Tomaszewski; E Zielinska

2012-01-01T23:59:59.000Z

46

Where do Chevrolet Volt drivers in The EV Project charge when they have the opportunity to charge at work?  

SciTech Connect (OSTI)

This paper investigates where Chevy Volt drivers in the EV Project charge when they have the opportunity to charge at work. Do they charge at home, work, or some other location.

John Smart; Don Scoffield

2014-03-01T23:59:59.000Z

47

The Ionization of Neon and Argon by Positive Alkali Ions of Energies from 650 to 2000 Volts  

Science Journals Connector (OSTI)

With an apparatus of new design the study of the ionization of neon and argon by positive alkali ions has been extended to accelerating potentials as high as 2000 volts. The results obtained are in good quantitative agreement with the previous work at the low potentials. In a number of cases the efficiency of ionization reaches a maximum at accelerating potentials less than 2000 volts.

J. Carlisle Mouzon

1932-09-01T23:59:59.000Z

48

Connectivity-Enhanced Route Selection and Adaptive Control for the Chevrolet Volt: Preprint  

SciTech Connect (OSTI)

The National Renewable Energy Laboratory and General Motors evaluated connectivity-enabled efficiency enhancements for the Chevrolet Volt. A high-level model was developed to predict vehicle fuel and electricity consumption based on driving characteristics and vehicle state inputs. These techniques were leveraged to optimize energy efficiency via green routing and intelligent control mode scheduling, which were evaluated using prospective driving routes between tens of thousands of real-world origin/destination pairs. The overall energy savings potential of green routing and intelligent mode scheduling was estimated at 5% and 3% respectively. These represent substantial opportunities considering that they only require software adjustments to implement.

Gonder, J.; Wood, E.; Rajagopalan, S.

2014-09-01T23:59:59.000Z

49

Reactive Maintenance  

Broader source: Energy.gov [DOE]

Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities.

50

Electron-Atom Superelastic Scattering in Magnesium at Millielectron Volt Energies T. Baynard, A. C. Reber, R. F. Niedziela,| S. A. Darveau, B. Prutzman,# and R. S. Berry*,  

E-Print Network [OSTI]

Electron-Atom Superelastic Scattering in Magnesium at Millielectron Volt Energies T. Baynard, A. C energy dependence of magnesium from threshold to 1400 eV10 with an energy resolution of 250 meV. Similar

Berry, R. Stephen

51

Optimization of Solar Cell Design for Use with GreenVolts CPV System: Cooperative Research and Development Final Report, CRADA Number CRD-08-00281  

SciTech Connect (OSTI)

GreenVolts, a Bay area start-up, was developing a CPV system that was based on a unique reflective optical design. They were interested in adapting the inverted GaInP/GaAs/GaInAs cell structure designed at NREL for use in their system. The purpose of this project was to optimize the inverted GaInP/GaAs/GaInAs cell for operation in the GreenVolts optical system.

Ward, S.

2011-05-01T23:59:59.000Z

52

Causal Analysis of the Inadvertent Contact with an Uncontrolled Electrical Hazardous Energy Source (120 Volts AC)  

SciTech Connect (OSTI)

On September 25, 2013, a Health Physics Technician (HPT) was performing preparations to support a pneumatic transfer from the HFEF Decon Cell to the Room 130 Glovebox in HFEF, per HFEF OI 3165 section 3.5, Field Preparations. This activity involves an HPT setting up and climbing a portable ladder to remove the 14-C meter probe from above ball valve HBV-7. The HPT source checks the meter and probe and then replaces the probe above HBV-7, which is located above Hood ID# 130 HP. At approximately 13:20, while reaching past the HBV-7 valve position indicator switches in an attempt to place the 14-C meter probe in the desired location, the HPTs left forearm came in contact with one of the three sets of exposed terminals on the valve position indication switches for HBV 7. This resulted in the HPT receiving an electrical shock from a 120 Volt AC source. Upon moving the arm, following the electrical shock, the HPT noticed two exposed electrical connections on a switch. The HPT then notified the HFEF HPT Supervisor, who in turn notified the MFC Radiological Controls Manager and HFEF Operations Manager of the situation. Work was stopped in the area and the hazard was roped off and posted to prevent access to the hazard. The HPT was escorted by the HPT Supervisor to the MFC Dispensary and then preceded to CFA medical for further evaluation. The individual was evaluated and released without any medical restrictions. Causal Factor (Root Cause) A3B3C01/A5B2C08: - Knowledge based error/Attention was given to wrong issues - Written Communication content LTA, Incomplete/situation not covered The Causal Factor (root cause) was attention being given to the wrong issues during the creation, reviews, verifications, and actual performance of HFEF OI-3165, which covers the need to perform the weekly source check and ensure placement of the probe prior to performing a rabbit transfer. This resulted in the hazard not being identified and mitigated in the procedure. Work activities with in HFEF-OI-3165 placed the HPT in proximity of an unmitigated hazard directly resulting in this event. Contributing Factor A3B3C04/A4B5C04: - Knowledge Based Error, LTA Review Based on Assumption That Process Will Not Change - Change Management LTA, Risks/consequences associated with change not adequately reviewed/assessed Prior to the pneumatic system being out of service, the probe and meter were not being source checked together. The source check issue was identified and addressed during the period of time when the system was out of service. The corrective actions for this issue resulted in the requirement that a meter and probe be source checked together as it is intended to be used. This changed the activity and required an HPT to weekly, when in use, remove and install the probe from above HBV-7 to meet the requirement of LRD 15001 Part 5 Article 551.5. Risks and consequences associated with this change were not adequately reviewed or assessed. Failure to identify the hazard associated with this change directly contributed to this event.

David E. James; Dennis E. Raunig; Sean S. Cunningham

2014-10-01T23:59:59.000Z

53

Implementation of non-intrusive energy saving estimation for Volt/VAr control of smart distribution system  

Science Journals Connector (OSTI)

Abstract There has been a growing interest among power distribution utilities to explore smart grid technologies to improve the operational efficiency and reliability. As electricity distribution grid is evolving to become smart, energy demand reduction is one of the goals for the distribution utilities. In order to obtain this goal, utilities need to commit significant financial resources. Therefore, it became important to assess the benefit of new technologies such as Volt/VAr control (VVC). To compute the energy savings due to VVC implementation, existing algorithms are intrusive, and generally require altering the distribution system control settings and operating points, which is undesirable for system operator. On the other hand, these may require large amount of historical data. In this paper, implementation of a new non-intrusive energy saving estimation algorithm has been presented for integrated Volt/VAr control by Avista Utilities in Northwest USA. Developed algorithm utilizes measurements from smart distribution system. Develop algorithm allows studying the energy saving in long term as it requires no change in control settings of actual distribution system. Satisfactory results have been obtained and validated against field data from experiments on real feeders by Avista Utilities.

S. Chanda; F. Shariatzadeh; A. Srivastava; E. Lee; W. Stone; J. Ham

2014-01-01T23:59:59.000Z

54

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory  

E-Print Network [OSTI]

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory Modifying memory: Selectively enhancing and updating personal memories for a museum; Reactivating personal memory 2 Abstract Memory can be modified when reactivated

Schacter, Daniel

55

Chevrolet Volt Vehicle Demonstration  

Broader source: Energy.gov (indexed) [DOE]

8.2 Overall AC electrical energy consumption (AC Whmi) 157 Average Trip Distance 12.3 Total distance traveled (mi) 407,245 Average Ambient Temperature (deg F) 67.9 Electric...

56

Chevrolet Volt Vehicle Demonstration  

Broader source: Energy.gov (indexed) [DOE]

70.1 Overall AC electrical energy consumption (AC Whmi) 169 Average Trip Distance 12.3 Total distance traveled (mi) 2,817,365 Average Ambient Temperature (deg F) 62.4 Electric...

57

Reactive Power Compensator.  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation. 26 figs.

El-Sharkawi, M.A.; Venkata, S.S.; Chen, M.; Andexler, G.; Huang, T.

1992-07-28T23:59:59.000Z

58

Reactive power compensator  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation.

El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Woodinville, WA); Chen, Mingliang (Kirkland, WA); Andexler, George (Everett, WA); Huang, Tony (Seattle, WA)

1992-01-01T23:59:59.000Z

59

Oxyferryl Heme Reactivity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxyferryl Heme Reactivity Using both Radiation and Photochemical Oxyferryl Heme Reactivity Using both Radiation and Photochemical Techniques A. M. English, T. Fox, G. Tsaprailis, C. W. Fenwick, J. F. Wishart, J. T. Hazzard, and G. Tollin Adv. Chem. Ser. 254, Ch. 6, pp. 81-98 Abstract: Flash photolysis and pulse radiolysis were used to generate reductants in situ to study the electron-transfer (ET) reactivity of the FeIV=O heme centers in myoglobin and cytochrome c peroxidase. Reduction of a5RuIII groups covalently bound to surface histidines allowed intramolecular RuII --> FeIV=O ET rates to be measured. Protonation of the oxene ligand was found to be largely rate determining in myoglobin, consistent with the lack of proton donors in its heme pocket. The large distance (21-23 Å) between surface histidines and the heme in wild-type

60

Reactivity of Acid Generators  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Acid Generators for Chemically Amplified Resists with Reactivity of Acid Generators for Chemically Amplified Resists with Low-Energy Electrons Atsuro Nakano, Takahiro Kozawa, Seiichi Tagawa, Tomasz Szreder, James F. Wishart, Toshiyuki Kai and Tsutomu Shimokawa Jpn. J. Appl. Phys., 45, L197-L200 (2006). [Find paper at the Japanese Journal of Applied Physics] Abstract: In chemically amplified resists for ionizing radiations such as electron beams and extreme ultraviolet (EUV), low-energy electrons play an important role in the pattern formation processes. The reactivity of acid generators with low-energy electrons was evaluated using solvated electrons in tetrahydrofuran, which were generated by a pulsed electron beam. The rate constants of acid generators with the solvated electrons ranged from 0.6 to 1.9 x 1011 M-1s-1

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Transient Signal Analysis is a digital device testing method that is based on the analysis of volt-age transients at multiple test points. In this paper, the power supply transient signals from sim-  

E-Print Network [OSTI]

in 8-bit Multiplier Simulation Experiments Investigating the Use of Power Supply Transient SigAbstract Transient Signal Analysis is a digital device testing method that is based on the analysis of volt- age transients at multiple test points. In this paper, the power supply transient signals from

Plusquellic, James

62

Reactive Power Compensating System.  

DOE Patents [OSTI]

The circuit was designed for the specific application of wind-driven induction generators. It has great potential for application in any situation where a varying reactive power load is present, such as with induction motors or generators, or for transmission network compensation.

Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

1985-01-04T23:59:59.000Z

63

Reactive power compensating system  

DOE Patents [OSTI]

The reactive power of an induction machine is compensated by providing fixed capacitors on each phase line for the minimum compensation required, sensing the current on one line at the time its voltage crosses zero to determine the actual compensation required for each phase, and selecting switched capacitors on each line to provide the balance of the compensation required.

Williams, Timothy J. (Redondo Beach, CA); El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Seattle, WA)

1987-01-01T23:59:59.000Z

64

Reactive Air Aluminization  

SciTech Connect (OSTI)

Ferritic stainless steels and other alloys are of great interest to SOFC developers for applications such as interconnects, cell frames, and balance of plant components. While these alloys offer significant advantages (e.g., low material and manufacturing cost, high thermal conductivity, and high temperature oxidation resistance), there are challenges which can hinder their utilization in SOFC systems; these challenges include Cr volatility and reactivity with glass seals. To overcome these challenges, protective coatings and surface treatments for the alloys are under development. In particular, aluminization of alloy surfaces offers the potential for mitigating both evaporation of Cr from the alloy surface and reaction of alloy constituents with glass seals. Commercial aluminization processes are available to SOFC developers, but they tend to be costly due to their use of exotic raw materials and/or processing conditions. As an alternative, PNNL has developed Reactive Air Aluminization (RAA), which offers a low-cost, simpler alternative to conventional aluminization methods.

Choi, Jung-Pyung; Chou, Y. S.; Stevenson, Jeffry W.

2011-10-28T23:59:59.000Z

65

Reactive Maintenance | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Reactive Maintenance Reactive Maintenance Reactive Maintenance October 7, 2013 - 9:40am Addthis Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities. Advantages Reactive maintenance advantages are a double-edged sword. Federal agencies following a purely reactive maintenance strategy can expect little expenditures for manpower or system upkeep until something breaks. However, systems do break. With new equipment, Federal agencies can expect minimal incidents of failure. However, older equipment often experiences higher failure incidents and costlier repairs. Other advantages of reactive maintenance are:

66

Federal Energy Management Program: Reactive Maintenance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactive Reactive Maintenance to someone by E-mail Share Federal Energy Management Program: Reactive Maintenance on Facebook Tweet about Federal Energy Management Program: Reactive Maintenance on Twitter Bookmark Federal Energy Management Program: Reactive Maintenance on Google Bookmark Federal Energy Management Program: Reactive Maintenance on Delicious Rank Federal Energy Management Program: Reactive Maintenance on Digg Find More places to share Federal Energy Management Program: Reactive Maintenance on AddThis.com... Sustainable Buildings & Campuses Operations & Maintenance Federal Requirements Program Management Commissioning Metering Computerized Maintenance Management Systems Maintenance Types Reactive Preventive Predictive Reliability-Centered Major Equipment Types

67

Metal-based reactive nanomaterials  

Science Journals Connector (OSTI)

Recent developments in materials processing and characterization resulted in the discovery of a new type of reactive materials containing nanoscaled metal components. The well-known high oxidation energies of metallic fuels can now be released very rapidly because of the very high reactive interface areas in such metal-based reactive nanomaterials. Consequently, these materials are currently being examined for an entire range of applications in energetic formulations inappropriate for conventional, micron-sized metal fuels having relatively low reaction rates. New application areas, such as reactive structural materials, are also being explored. Research remains active in manufacturing and characterization of metal-based reactive nanomaterials including elemental metal nanopowders and various nanocomposite material systems. Because of the nanometer scale of the individual particles, or phase domains, and because of the very high enthalpy of reaction between components of the nanocomposite materials, the final phase compositions, morphology, and thermodynamic properties of the reactive nanocomposite materials may be different from those of their micron-scaled counterparts. Ignition mechanisms in such materials can be governed by heterogeneous reactions that are insignificant for materials with less developed reactive interface areas. New combustion regimes are being observed that are affected by very short ignition delays combined with very high metal combustion temperatures. Current progress in this rapidly growing research area is reviewed and some potential directions for the future research are discussed.

Edward L. Dreizin

2009-01-01T23:59:59.000Z

68

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

69

Chemically Reactive Working Fluids | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Chemically Reactive Working Fluids for the Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Chemically Reactive Working Fluids SunShot CSP...

70

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

71

Fuel Temperature Coefficient of Reactivity  

SciTech Connect (OSTI)

A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

Loewe, W.E.

2001-07-31T23:59:59.000Z

72

Joint Energy and Reactive Power Market Considering Coupled Active and Reactive Reserve Market Ensuring System Security  

Science Journals Connector (OSTI)

Reactive power market is usually held as independent from energy and reserved active power markets; however, active and reactive power are ... synchronous generator capacity curve. Therefore, reactive power market

Hamed Ahmadi; Asghar Akbari Foroud

2014-06-01T23:59:59.000Z

73

Triclosan Reactivity in Chloraminated Waters  

Science Journals Connector (OSTI)

Triclosan Reactivity in Chloraminated Waters ... Triclosan, widely employed as an antimicrobial additive in many household personal care products, has recently been detected in wastewater treatment plant effluents and in source waters used for drinking water supplies. ... Chloramines used either as alternative disinfectants in drinking water treatment or formed during chlorination of nonnitrified wastewater effluents have the potential to react with triclosan. ...

Aimee E. Greyshock; Peter J. Vikesland

2006-03-16T23:59:59.000Z

74

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

75

Reactive Power Support Services in Electricity Markets  

E-Print Network [OSTI]

Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Final Project Report Power Systems Engineering Research Center A National Science Foundation Industry Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Project

76

Data:84e2fa36-5dd3-49d9-9563-8f646c3f8450 | Open Energy Information  

Open Energy Info (EERE)

which may interfere with service to other customers, or all transformer-type welding machines larger than 25 kilo-volt amperes, will not be served on this rate. Source or...

77

Data:A563ad4a-6f47-40bd-9bfa-d67a6d66a93d | Open Energy Information  

Open Energy Info (EERE)

which may interfere with service to other customers, or all transformer-type welding machines larger than 25 kilo-volt amperes, will not be served on this rate. Source or...

78

Reactive Ion Benjamin A. Small  

E-Print Network [OSTI]

(torr) plasma etching reactive ion etching ion milling m cm 100µm µm #12;5 Mechanics ~40 mTorrE380 kHz, 13.56 MHz ~30 sccm #12;6 Chemistry X X X X F- F- F-F- X F-F- F- F- F- R++ R++ R++ #12;7 Chemistry before opening · Silanes are explosive in the atmosphere #12;13 Bibliography Campbell, Stephen A

Garmestani, Hamid

79

Reactive composite compositions and mat barriers  

DOE Patents [OSTI]

A hazardous material storage area has a reactive multi-layer composite mat which lines an opening into which a reactive backfill and hazardous material are placed. A water-inhibiting cap may cover the hazardous material storage area. The reactive multi-layer composite mat has a backing onto which is placed an active layer which will neutralize or stabilize hazardous waste and a fronting layer so that the active layer is between the fronting and backing layers. The reactive backfill has a reactive agent which can stabilize or neutralize hazardous material and inhibit the movement of the hazardous material through the hazardous material storage area.

Langton, Christine A. (Aiken, SC); Narasimhan, Rajendran (Evans, GA); Karraker, David G. (Aiken, SC)

2001-01-01T23:59:59.000Z

80

Permeable Reactive Barriers | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barrier Field Projects Durango, Colorado DOE installed a PRB in October 1995 to treat ground water from a uranium mill tailings disposal site at Durango, Colorado Read more Cañon City, Colorado ESL personnel conduct tests and help evaluate performance at other PRB sites, such as Cotter Corporation's Cañon City site in Colorado. Read more Monticello, Utah Installation of a PRB hydraulically downgradient of the Monticello, Utah, millsite was completed June 30, 1999, as an Interim Remedial Action. Read more A permeable reactive barrier (PRB) is a zone of reactive material placed underground to intercept and react with a contaminant plume in ground water. Typically, PRBs are emplaced by replacing soils with reactive

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Reactive capability limits of wind farms  

Science Journals Connector (OSTI)

Wind Energy Conversion Systems (WECS) technology can be classified into two main types: fixed speed and variable speed. Fixed speed WECS use an induction generator connected directly to the grid while variable speed WECS use a power converter to connect the generator to the grid. Fixed speed WECS require shunt capacitors for reactive power compensation, while variable speed WECS have reactive power capability. Under the Spanish grid code, wind farms have to operate in a range of power factor values. This paper determines the reactive power capability of wind farms equipped with both fixed and variable speed WECS. The reactive power capability can be represented as a reactive capability curve. In this paper, the reactive capability curve is used to calculate the additional reactive power compensation needed to meet the requirements of the Spanish grid code.

Alberto Rios Villacorta; Santiago Arnaltes Gomez; Jose Luis Rodriguez-Amenedo

2005-01-01T23:59:59.000Z

82

Umass Lowell, ECE Spring 2014, Tingshu Hu 16.201 Introductory Circuit Theory I  

E-Print Network [OSTI]

-ampere characteristics, energy relations, First-order transients: initial conditions, natural response, and natural frequencies. Network response to unit step function and unit impulse. Second-order transients: RLC circuits circuit elements through terminal descriptions, volt-ampere relationships and energy consumption/storage

Hu, Tingshu

83

Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same  

DOE Patents [OSTI]

An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

Fritz, Gregory M; Knepper, Robert Allen; Weihs, Timothy P; Gash, Alexander E; Sze, John S

2013-04-30T23:59:59.000Z

84

Rejuvenating Permeable Reactive Barriers by Chemical Flushing  

Broader source: Energy.gov [DOE]

Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

85

Exploring the reactivity of bacterial multicomponent monooxygenases  

E-Print Network [OSTI]

Chapter 1. Introduction: The Reactivity of Bacterial Multicomponent Monooxygenases Bacterial multicomponent monooxygenases constitute a remarkable family of enzymes that oxidize small, inert hydrocarbon substrates using ...

Tinberg, Christine Elaine

2010-01-01T23:59:59.000Z

86

Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts  

DOE Patents [OSTI]

A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Anderson, Raymond P. (Idaho Falls, ID)

2008-08-05T23:59:59.000Z

87

Reactivity of calcium sulfate from FBC systems  

Science Journals Connector (OSTI)

A relative estimate of the reactivity of calcium sulfate in a number of coal combustion ash samples was obtained, using the rate of solution in water as a parameter. Measurements were also performed on standard samples of calcium sulfate prepared in different ways, for comparison. The temperature of previous treatment appeared as the most important factor determining the reactivity of CaSO4; the grain size distribution was less important, and the duration of heating (even to 105 days) had very little influence. No correlation between specific surface of ash samples and their reactivity was apparent. Calcium sulfate in FBC ash samples was much more reactive than that contained in high-temperature ashes, and than calcium sulfate heated, alone or with various additions, at 850C for 2 days. Of the six FBC samples tested, five showed similar behaviour, including a sample from a pressurized system; only a deposit from 96 days operation of an industrial CFBC boiler burning petroleum coke showed considerably less reactivity. Surprisingly, CaSO4 from two FBC samples placed in an oven for 60 days under sulfating conditions showed a very similar rate of solution to that of the other FBC samples, while a third sample kept in the oven for 105 days also showed no decrease in reactivity. Only when one of these samples had agglomerated (which occurred between 60 and 105 days) did it show decreased reactivity, suggesting that the agglomeration process rather than duration is significant in promoting sintering and reducing the sulfate reactivity.

Agripanea P. Iribarne; Julio V. Iribarne; Edward J. Anthony

1997-01-01T23:59:59.000Z

88

Definition: Automated Capacitors | Open Energy Information  

Open Energy Info (EERE)

Capacitors Capacitors Jump to: navigation, search Dictionary.png Automated Capacitors Capacitors can increase the voltage on a distribution circuit by providing reactive power (often referred to as volt-amperes-reactive or VArs). Capacitor banks are switched in discrete steps, either manually, or in response to the voltage at the location where they are connected; typically, distribution capacitor banks are switched in a single step. If the voltage falls too far below the set point, the capacitor is switched in to raise the voltage. If the voltage rises too high above the set point, the capacitor is switched out to lower the voltage. Automated capacitors can be switched in coordination with other voltage control devices with signals from local sensors, distribution automation systems, or grid

89

In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and Reactive Landing of Mass Selected Ions. In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and...

90

1/00 Ampere 1/9 THE INTEGRAL FORM OF AMPERE'S LAW  

E-Print Network [OSTI]

is zero. If the closed line integral around a closed path is not zero, you know that there is a net, polygon, etc. If there is no net current passing through the plane of the closed path, the line integral around the path is zero. This does not mean there is no B field present along the path. Rather it means

Glashausser, Charles

91

EV Project Chevrolet Volt Vehicle Summary Report  

Broader source: Energy.gov (indexed) [DOE]

2012 Vehicle Usage Overall fuel economy (mpg) 136 Overall electrical energy consumption (AC Whmi) 222 Number of trips 286,682 Total distance traveled (mi) 2,392,509 Avg...

92

EV Project Chevrolet Volt Vehicle Summary Report  

Broader source: Energy.gov (indexed) [DOE]

December 2011 Vehicle Usage Overall fuel economy (mpg) 131 Overall electrical energy consumption (AC Whmi) 271 Number of trips 13,819 Total distance traveled (mi) 108,115 Avg trip...

93

EV Project Chevrolet Volt Vehicle Summary Report  

Broader source: Energy.gov (indexed) [DOE]

42 Overall electrical energy consumption (AC Whmi) 231 Number of trips 676,414 Total distance traveled (mi) 5,753,009 Avg trip distance (mi) 8.3 Avg distance traveled per day...

94

EV Project Chevrolet Volt Vehicle Summary Report  

Broader source: Energy.gov (indexed) [DOE]

March 2012 Vehicle Usage Overall fuel economy (mpg) 139 Overall electrical energy consumption (AC Whmi) 293 Number of trips 76,425 Total distance traveled (mi) 609,737 Avg...

95

EV Project Chevrolet Volt Vehicle Summary Report  

Broader source: Energy.gov (indexed) [DOE]

fuel economy (mpg) 155 Overall electrical energy consumption (AC Whmi) 242 Number of trips 147,886 Total distance traveled (mi) 1,184,265 Avg trip distance (mi) 8.0 Avg distance...

96

Maintenance Sheet for 2013 Chevrolet Volt  

Broader source: Energy.gov (indexed) [DOE]

0DU103929 Date Mileage Description Cost 342013 4,876 Replaced relay assembly, engine control module, and 12V battery - under warranty NC 342013 4,876 Reflashed parking brake...

97

EV Project Chevrolet Volt Vehicle Summary Report  

Broader source: Energy.gov (indexed) [DOE]

Vehicle Summary Report Region: ALL Number of vehicles: 1766 Reporting period: January 2013 through March 2013 1 A trip is defined as all the driving done between consecutive...

98

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Broader source: Energy.gov (indexed) [DOE]

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical

99

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Broader source: Energy.gov (indexed) [DOE]

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

100

Characterization of Dual-Fuel Reactivity Controlled Compression...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI)...

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

COAL SLAGGING AND REACTIVITY TESTING  

SciTech Connect (OSTI)

Union Fenosa's La Robla I Power Station is a 270-MW Foster Wheeler arch-fired system. The unit is located at the mine that provides a portion of the semianthracitic coal. The remaining coals used are from South Africa, Russia, Australia, and China. The challenges at the La Robla I Station stem from the various fuels used, the characteristics of which differ from the design coal. The University of North Dakota Energy & Environmental Research Center (EERC) and the Lehigh University Energy Research Center (LUERC) undertook a program to assess problematic slagging and unburned carbon issues occurring at the plant. Full-scale combustion tests were performed under baseline conditions, with elevated oxygen level and with redistribution of air during a site visit at the plant. During these tests, operating information, observations and temperature measurements, and coal, slag deposit, and fly ash samples were obtained to assess slagging and unburned carbon. The slagging in almost all cases appeared due to elevated temperatures rather than fuel chemistry. The most severe slagging occurred when the temperature at the sampling port was in excess of 1500 C, with problematic slagging where first-observed temperatures exceeded 1350 C. The presence of anorthite crystals in the bulk of the deposits analyzed indicates that the temperatures were in excess of 1350 C, consistent with temperature measurements during the sampling period. Elevated temperatures and ''hot spots'' are probably the result of poor mill performance, and a poor distribution of the coal from the mills to the specific burners causes elevated temperatures in the regions where the slag samples were extracted. A contributing cause appeared to be poor combustion air mixing and heating, resulting in oxygen stratification and increased temperatures in certain areas. Air preheater plugging was observed and reduces the temperature of the air in the windbox, which leads to poor combustion conditions, resulting in unburned carbon as well as slagging. A second phase of the project involved advanced analysis of the baseline coal along with an Australian coal fired at the plant. These analysis results were used in equilibrium thermodynamic modeling along with a coal quality model developed by the EERC to assess slagging, fouling, and opacity for the coals. Bench-scale carbon conversion testing was performed in a drop-tube furnace to assess the reactivity of the coals. The Australian coal had a higher mineral content with significantly more clay minerals present than the baseline coal. The presence of these clay minerals, which tend to melt at relatively low temperatures, indicated a higher potential for problematic slagging than the baseline coal. However, the pyritic minerals, comprising over 25% of the baseline mineral content, may form sticky iron sulfides, leading to severe slagging in the burner region if local areas with reducing conditions exist. Modeling results indicated that neither would present significant fouling problems. The Australian coal was expected to show slagging behavior much more severe than the baseline coal except at very high furnace temperatures. However, the baseline coal was predicted to exhibit opacity problems, as well as have a higher potential for problematic calcium sulfate-based low-temperature fouling. The baseline coal had a somewhat higher reactivity than the Australian coal, which was consistent with both the lower average activation energy for the baseline coal and the greater carbon conversion at a given temperature and residence time. The activation energy of the baseline coal showed some effect of oxygen on the activation energy, with E{sub a} increasing at the lower oxygen concentration, but may be due to the scatter in the baseline coal kinetic values at the higher oxygen level tested.

Donald P. McCollor; Kurt E. Eylands; Jason D. Laumb

2003-10-01T23:59:59.000Z

102

Consideration of spatial effects in reactivity measurements  

SciTech Connect (OSTI)

Various methods of considering spatial effects in reactivity measurements are presented. These methods are employed both at the critical (mainly fast-neutron) facilities and at the BN-600 reactor.

Matveenko, I. P., E-mail: matveenko@ippe.ru; Lititskii, V. A.; Shokod'ko, A. G. [Institute of Physics and Power Engineering (Russian Federation)

2010-12-15T23:59:59.000Z

103

Systematic approach for chemical reactivity evaluation  

E-Print Network [OSTI]

Screening Tool (RSST) and the Automatic Pressure Tracking Adiabatic Calorimeter (APTAC) were employed to evaluate the reactive systems experimentally. The RSST detected exothermic behavior and measured the overall liberated energy. The APTAC simulated...

Aldeeb, Abdulrehman Ahmed

2004-09-30T23:59:59.000Z

104

Reactivity control assembly for nuclear reactor  

DOE Patents [OSTI]

Reactivity control assembly for nuclear reactor comprises supports stacked above reactor core for holding control rods. Couplers associated with the supports and a vertically movable drive shaft have lugs at their lower ends for engagement with the supports.

Bollinger, Lawrence R. (Schenectady, NY)

1984-01-01T23:59:59.000Z

105

Fossil plant layup and reactivation conference: Proceedings  

SciTech Connect (OSTI)

The Fossil Plant Layup and Reactivation Conference was held in New Orleans, Louisiana on April 14--15, 1992. The Conference was sponsored by EPRI and hosted by Entergy Services, Inc. to bring together representatives from utilities, consulting firms, manufacturers and architectural engineers. Eighteen papers were presented in three sessions. These sessions were devoted to layup procedures and practices, and reactivation case studies. A panel discussion was held on the second day to interactively discuss layup and reactivation issues. More than 80 people attended the Conference. This report contains technical papers and a summary of the panel discussion. Of the eighteen papers, three are related to general, one is related to regulatory issues, three are related to specific equipment, four are related to layup procedures and practices, and seven are layup and reactivation case studies.

Not Available

1992-10-01T23:59:59.000Z

106

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

1998-01-01T23:59:59.000Z

107

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

1998-09-08T23:59:59.000Z

108

A Tariff for Reactive Power - IEEE  

SciTech Connect (OSTI)

This paper describes a suggested tariff or payment for the local supply of reactive power from distributed energy resources. The authors consider four sample customers, and estimate the cost of supply of reactive power for each customer. The power system savings from the local supply of reactive power are also estimated for a hypothetical circuit. It is found that reactive power for local voltage regulation could be supplied to the distribution system economically by customers when new inverters are installed. The inverter would be supplied with a power factor of 0.8, and would be capable of local voltage regulation to a schedule supplied by the utility. Inverters are now installed with photovoltaic systems, fuel cells and microturbines, and adjustable-speed motor drives.

Kueck, John D [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator; Kirby, Brendan J [ORNL

2008-11-01T23:59:59.000Z

109

Reactive Attachment Disorder: Concepts, Treatment, and Research  

E-Print Network [OSTI]

Reactive Attachment Disorder (RAD) is a disorder characterized by controversy, both with respect to its definition and its treatment. By definition, the RAD diagnosis attempts to characterize and explain the origin of ...

Walter, Uta M.; Petr, Chris

2004-06-01T23:59:59.000Z

110

Phase II: Performance Evaluation of Permeable Reactive Barriers and  

Broader source: Energy.gov (indexed) [DOE]

Phase II: Performance Evaluation of Permeable Reactive Barriers and Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing U. S. Environmental Protection Agency Region 8 Support January 2004 Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing

111

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Broader source: Energy.gov (indexed) [DOE]

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

112

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Broader source: Energy.gov (indexed) [DOE]

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

113

Design and synthesis of reactive separation systems  

SciTech Connect (OSTI)

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-01-01T23:59:59.000Z

114

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-11-25T23:59:59.000Z

115

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-01-21T23:59:59.000Z

116

Formation and Reactivity of Biogenic Iron Microminerals  

SciTech Connect (OSTI)

The overall purpose of the project is to explore and quantify the processes that control the formation and reactivity of biogenic iron microminerals and their impact on the solubility of metal contaminants. The research addresses how surface components of bacterial cells, extracellular organic material, and the aqueous geochemistry of the DIRB microenvironment impacts the mineralogy, chemical state and micromorphology of reduced iron phases.

Beveridge, Terrance J.; Glasauer, Susan; Korenevsky, Anton; Ferris, F. Grant

2000-08-08T23:59:59.000Z

117

Controlling uranium reactivity March 18, 2008  

E-Print Network [OSTI]

for the last decade. Most of their work involves depleted uranium, a more common form of uraniumMarch 2008 Controlling uranium reactivity March 18, 2008 Uranium is an often misunderstood metal uranium research. In reality, uranium presents a wealth of possibilities for funda- mental chemistry. Many

Meyer, Karsten

118

Reports on Initial Results of Smart Grid Investment Grant Projects  

Broader source: Energy.gov (indexed) [DOE]

Reports on Initial Results of Smart Grid Investment Grant Projects Reports on Initial Results of Smart Grid Investment Grant Projects (December 2012) Reports on Initial Results of Smart Grid Investment Grant Projects (December 2012) DOE is implementing the Smart Grid Investment Grant (SGIG) program under the American Recovery and Reinvestment Act of 2009. The SGIG program involves 99 projects that are deploying smart grid technologies, tools, and techniques for electric transmission, distribution, advanced metering, and customer systems. These reports present information about the devices and systems being implemented, deployment progress, expected benefits, and initial results for projects improving electric distribution system reliability; implementing advanced metering, customer systems, and time-based rates; adding advanced voltage and volt-ampere reactive (VAR) optimization (VVO)

119

Characteristic Requirements of a Small Scale Squirrel Cage Induction Generator for Effective Electricity Generation from Wind Energy  

Science Journals Connector (OSTI)

Abstract This paper proposes characteristic requirements of a small scale squirrel cage induction generator for effective electricity generation from wind energy. These characteristics are obtained from modeling and testing results. Investigation into comparative performances between Standard and high efficiency induction generators is given in order to find out the characteristic requirements of a suitable induction generator. Performances of various features of the machine structure are given. The suitable design of the induction generator based on empirical rules is also included. The investigation of power loss of the induction machine both in theory using FEM (Finite Element Method) and tests has been made. In addition, static var (Volt-Ampere reactive power) compensator using power electronic control to keep terminal voltage of a self-excited induction generator constant is explained. These results can be guidelines for machine development and control method for effective electricity generation.

V. Kinnares; B. Sawetsakulanond

2013-01-01T23:59:59.000Z

120

STATEMENT OF CONSIDERATIONS REQUEST BY SOUTHERN COMPANY SERVICES, INC. FOR AN ADVANCE WAIVER  

Broader source: Energy.gov (indexed) [DOE]

SOUTHERN COMPANY SERVICES, INC. FOR AN ADVANCE WAIVER SOUTHERN COMPANY SERVICES, INC. FOR AN ADVANCE WAIVER OF DOMESTIC AND FOREIGN PATENT RIGHTS UNDER DOE COOPERATIVE AGREEMENT NO. DE-FC02-05CH11327 ENTITLED "DEVELOPMENT OF THE UPGRADE OF THE GENERATOR VOLT AMPERE REACTIVE RESERVE (GENVARR) SYSTEM;" W(A)-05-051; CH-1338 As set out in the attached waiver petition and in subsequent discussions with DOE Patent Counsel, Southern Company Service, Inc. has requested an advance waiver of domestic and foreign patent rights for all subject inventions made under the above-identified cooperative agreement by its employees and its subawardees' employees, regardless of tier, except inventions made by subawardees eligible to retain title to inventions pursuant to P.L. 96-517, as amended, and National Laboratories.

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Cell Comp't Thermal Reactivity & Improvements | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Comp't Thermal Reactivity & Improvements Cell Comp't Thermal Reactivity & Improvements Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on...

122

Isotope effects in methanol synthesis and the reactivity of copper...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

123

Design of processes with reactive distillation line diagrams  

SciTech Connect (OSTI)

On the basis of the transformation of concentration coordinates, the concept of reactive distillation lines is developed. It is applied to study the feasibility of a reactive distillation with an equilibrium reaction on all trays of a distillation column. The singular points in the distillation line diagrams are characterized in terms of nodes and saddles. Depending on the characterization of the reactive distillation line diagrams, it can be decided whether a column with two feed stages is required. On the basis of the reaction space concept, a procedure for identification of reactive distillation processes is developed, in which the reactive distillation column has to be divided into reactive and nonreactive sections. This can be necessary to overcome the limitations in separation which result from the chemical equilibrium. The concentration profile of this combined reactive/nonreactive distillation column is estimated using combined reactive/nonreactive distillation lines.

Bessling, B. [BASF Ludwigshafen (Germany). Engineering Research and Development] [BASF Ludwigshafen (Germany). Engineering Research and Development; Schembecker, G.; Simmrock, K.H. [Univ. of Dortmund (Germany). Dept. of Chemical Engineering] [Univ. of Dortmund (Germany). Dept. of Chemical Engineering

1997-08-01T23:59:59.000Z

124

(Vg = 2 volts, Fp = 3,7 volts). Dans le circuit  

E-Print Network [OSTI]

the process is incom- plete. But since it is advantageous to have thermionic convertors workingat temperatures and the latter was used simultaneously for the ionization process. In general, when the energy to be converted

Paris-Sud XI, Université de

125

Reactivity control assembly for nuclear reactor. [LMFBR  

DOE Patents [OSTI]

This invention, which resulted from a contact with the United States Department of Energy, relates to a control mechanism for a nuclear reactor and, more particularly, to an assembly for selectively shifting different numbers of reactivity modifying rods into and out of the core of a nuclear reactor. It has been proposed heretofore to control the reactivity of a breeder reactor by varying the depth of insertion of control rods (e.g., rods containing a fertile material such as ThO/sub 2/) in the core of the reactor, thereby varying the amount of neutron-thermalizing coolant and the amount of neutron-capturing material in the core. This invention relates to a mechanism which can advantageously be used in this type of reactor control system.

Bollinger, L.R.

1982-03-17T23:59:59.000Z

126

Mined land reclamation by biological reactivation  

SciTech Connect (OSTI)

A mine reclamation technique, developed in Europe, restores land to full productivity within two years without topsoil replacement. The method deliberately reestablishes within one year following mining, the required biological balance between microbes, enzymes, and trace elements in the rock spoil rather than waiting five or more years for natural processes to restore balance. The technique is called Biological Reactivation (BR). This paper discusses the feasibility of BR reclamation after surface mining operations in the US. Staff of the Ohio Mining and Mineral Resources Research Institute completed an OSM-sponsored research project on BR in which physical and chemical tests characterized 140 spoil samples obtained from 10 surface mining operations. Test results indicated that Biological Reactivation technology could be effectively applied, at least in the test areas sampled within Appalachia. Preliminary estimates make clear that the new technique reduces reclamation costs on prime farmland by approximately 95% compared to topsoil segregation and replacement methods.

Gozon, J.S.; Konya, C.J.; Lukovic, S.S.; Lundquist, R.G.; Olah, J.

1982-12-01T23:59:59.000Z

127

Acronyms, Abbreviations and Definitions, DOE Hydrogen Program FY 2010 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

81 81 FY 2010 Annual Progress Report DOE Hydrogen Program °C Degrees Celsius °F Degrees Fahrenheit α-AlH 3 Alpha polymorph of aluminum hydride Δ Change, delta ΔG Gibbs free energy of reaction ΔH Enthalpy of reaction, enthalpy of hydrogenation ΔH° f standard heat of formation ΔK Stress intensity factor ΔP Pressure drop, pressure change ~ Approximately ≈ Equals approximately > Greater than ≥ Greater than or equal to < Less than ≤ Less than or equal to @ At # Number % Percent ® Registered trademark µA Micro ampere(s) µA/cm 2 Micro ampere(s) per square centimeter μc-Si Microcrystalline silicon µg Microgram(s) µm Micrometer(s); micron(s) µM Micromolar µmol Micromole(s) µΩ-cm 2 Micro-ohm(s)-square centimeter µV Micro volt(s)

128

Reactive sticking coefficients of silane on silicon  

SciTech Connect (OSTI)

Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition rate measurements using molecular beam scattering and a very low pressure cold wall reactor. The RSCs have non-Arrhenius temperature dependences and decreases with increasing flux at low (710/sup 0/) temperatures. A simple model involving dissociative adsorption of silane is consistent with these results. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1988-09-15T23:59:59.000Z

129

Cellular-automaton model for reactive systems  

Science Journals Connector (OSTI)

A method for constructing a variety of probabilistic lattice-gas cellular automata for chemically reacting systems is described. The microscopic reactive dynamics give rise to a general fourth-order polynomial rate law for the average particle density. The reduction of the microdynamical equations to a discrete or continuous Boltzmann equation is presented. Connection between the linearized Boltzmann equations and a reaction-diffusion macroscopic equation is discussed. As an example of the general formalism a set of cellular automata rules that yield the Schlgl phenomenological model is constructed. Simulation results are presented.

David Dab; Anna Lawniczak; Jean-Pierre Boon; Raymond Kapral

1990-05-14T23:59:59.000Z

130

Theoretical and Experimental Evaluation of Chemical Reactivity  

E-Print Network [OSTI]

released and the rate of energy released for a specific reactive chemical. 2.1 DSC DSC is a popular screening tool (safe and fast) and can provide an overall indication of exothermic activity of the chemical being tested. In a DSC, a sample and a... endothermic or exothermic reaction. When the rate of heat generation in the sample exceeds a particular value, the heat supply to the sample is cut off and this additional heat gain is attributed to exothermic activity within the sample.17 From the DSC...

Wang, Qingsheng

2011-10-21T23:59:59.000Z

131

Preparation of reactive beta-dicalcium silicate  

DOE Patents [OSTI]

This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane and hydrogen, at a temperature of about 850.degree.-1000.degree. C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

Shen, Ming-Shing (Laramie, WY, NJ); Chen, James M. (Rahway, NJ); Yang, Ralph T. (Amherst, NY)

1982-01-01T23:59:59.000Z

132

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 ``Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core`` problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-12-01T23:59:59.000Z

133

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core'' problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-01-01T23:59:59.000Z

134

Atmospheric reactivity of gaseous dimethyl sulfate  

SciTech Connect (OSTI)

The atmospheric reactivity of dimethyl sulfate (DMS) with a series of atmospheric species has been investigated. Upper limits to the rate constants for the homogeneous gas-phase reactions of DMS with O{sub 3}, NH{sub 3}, and H{sub 2}O have been determined by using FTIR spectroscopy and are <1.4 {times} 10{sup {minus}21}, <1.5 {times} 10{sup {minus}21}, and <1.1 {times} 10{sup {minus}23} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. The reactivity of DMS toward ON radicals and Cl atoms has been determined by using relative rate techniques, and the rate constants for those reactions are <5 {times} 10{sup {minus}13} and (4.2 {plus minus} 0.5) {times} 10{sup {minus}13} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. These rate constants correspond to atmospheric lifetimes ranging from >23 days with respect to reaction with OH radicals to >33 years with respect to reaction with ozone. With the possible exception of its reaction with water, for which the calculated lifetime of DMS is >2 days, these results indicate that the atmospheric fate of DMS is not determined by its homogeneous gas-phase reactions with any of the atmosphere species studied.

Japar, S.M.; Wallington, T.J.; Andino, J.M.; Ball, J.C. (Ford Motor Co., Dearborn, MI (USA))

1990-03-01T23:59:59.000Z

135

Measurement of VOC reactivities using a photochemical flow reactor  

SciTech Connect (OSTI)

A commercial ambient air monitoring instrument, the Airtrak 2000, has been modified for use as a photochemical flow reactor and used to measure the absolute and incremental reactivity of 18 single test VOCs and the incremental reactivity of six multicomponent VOC mixtures. A flow technique is a useful supplement to traditional static chamber experiments. The static chamber technique involves periodic sampling of an irradiated mixture in a photochemical chamber. Under these conditions, the irradiated mixture is always in transition. Using a flow system, a steady-state condition is established within the flow reactor that is representative, in this case, of the early stages of the smog forming process in the atmosphere. The measurement technique also allows changes in the background chamber reactivity to be monitored and taken into account. The incremental reactivity of 13 of the 18 test compounds measured is compared with previously reported results from a static chamber experiment, and the two data sets are generally in good agreement. The additivity of reactivity was tested by measuring the incremental reactivity of six multicomponent mixtures, the components being compounds measured individually in this study. The measured reactivity of a mixture was compared to that calculated from the sum of the measured reactivity of the mixture`s individual components. The results show that reactivity is additive for the concentration range studied.

Hurley, M.D.; Chang, T.Y.; Japar, S.M.; Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.] [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.

1998-07-01T23:59:59.000Z

136

Reactive Dehydration technology for Production of Fuels and Chemicals...  

Broader source: Energy.gov (indexed) [DOE]

Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based chemicals from complex aqueous mixtures. SeparationPurification of Biomass...

137

Airborne measurement of OH reactivity during INTEX-B  

E-Print Network [OSTI]

plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

2009-01-01T23:59:59.000Z

138

Reactive Landing of Peptide Ions on Self-Assembled Monolayer...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

were characterized ex situ using time of flight-secondary ion mass spectrometry (TOF-SIMS) and infrared reflection absorption spectroscopy (IRRAS). We demonstrate that reactive...

139

Probing the structure and reactivity of gaseous ions.  

E-Print Network [OSTI]

??Studying ions in the gas phase provides the opportunity to observe their intrinsic structure and reactivity without extraneous perturbations such as solvent effects, aggregation or (more)

Meyer, Matthew Michael

2010-01-01T23:59:59.000Z

140

Chemically Reactive Working Fluids for the Capture and Transport...  

Broader source: Energy.gov (indexed) [DOE]

Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working Fluids Low-Cost Light Weigh Thin Film Solar Concentrators...

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Monitoring Single Molecule Reactivity On a Carbon Nanotube  

E-Print Network [OSTI]

LETTERS Monitoring Single-Molecule Reactivity on a Carbondevice directly transduces single-molecule attachments andoptical methods in single-molecule research. Compared to

Collins, Philip G

2008-01-01T23:59:59.000Z

142

Physical Organic Chemistry of Reactive Intermediates | The Ames...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Physical Organic Chemistry of Reactive Intermediates The Jenks group specializes in physical organic chemistry, the "how" of organic reactions. Much of the work has centered on...

143

Chemical Analysis of Complex Organic Mixtures Using Reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mass Spectrometry. Abstract: Reactive nanospray desorption electrospray ionization (nano-DESI) combined with high-resolution mass spectrometry was utilized for the analysis of...

144

Instrumentation @ Catalysis: Reactivity and Structure Group | Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Instrumentation Instrumentation The Catalysis Group at BNL is leading research initiatives into the development of new tools and techniques that focus on the characterization of heterogeneous catalytic reactions and catalysts using imaging, spectroscopy and scattering techniques and integrated combinations of them under reaction conditions to unravel the morphology, chemical and structural properties, of catalysts, respectively. These efforts revolve around the use of synchrotron radiation (NSLS), electrons (CFN) and quantum tunneling tools with particular thrusts into imaging, spectroscopy and scattering. Groups Instrumentation(BNL) Three UHV chambers with diverse instrumentation for surface characterization: LEED, UPS, XPS, AES, TPD, ISS, PM-AP-IRRAS, Reactivity Cell. All the systems include ancillary instrumentation such as sputtering guns and metal evaporators. The IRRAS system was retrofitted with an ambient pressure (AP) cell on top of the UHV system. The sample can be prepared and characterized in UHV and then transfer in vacuum to the AP cell.

145

Review of existing reactive transport software  

SciTech Connect (OSTI)

Simulations of thermal and hydrological evolution following the potential emplacement of a subterranean nuclear waste repository at Yucca Mountain, NV provide data that suggest the inevitability of dependent, simultaneous chemical evolution in this system. These chemical changes will modify significantly both the magnitude and structure of local porosity and permeability; hence, they will have a dynamic feedback effect on the evolving thermal and hydrological regime. Yet, despite this intimate interdependence of transport and chemical processes, a rigorous quantitative analysis of the post- emplacement environment that incorporates this critical feedback mechanism has not been completed to date. As an initial step in this direction, the present document outlines the fundamental chemical and transport processes that must be accounted for in such an analysis, and reviews the inventory of existing software that encodes these processed in explicitly coupled form. A companion report describes the prioritization of specific capabilities that are needed for modeling post-emplacement reactive transport at Yucca Mountain.

Glassley, W., LLNL

1998-02-03T23:59:59.000Z

146

Current and Resistance SI unit for current is ampere  

E-Print Network [OSTI]

Conversely speak of a material's conductivity, SI unit is (�m)-1 J E = 1 = #12;Resistance and Resistivity E , J , and when talk about electrical properties of materials #12;Resistivity of Materials Resistivities for some common materials (at room temperature) Metal (Copper) Semi-conductor (Silicon) (n

Bertulani, Carlos A. - Department of Physics and Astronomy, Texas A&M University

147

A Learning-Based Approach to Reactive Security  

E-Print Network [OSTI]

Terms--Reactive security, risk management, attack graphs, online learning, adversarial learning, game vulnerability is plugged, CISOs typically perform a cost- benefit analysis to identify which risks to address of reactive strategies in an economic model of the CISO's security cost-benefit trade- offs. Unlike previously

Song, Dawn

148

A Reactive Measurement Framework Mark Allman and Vern Paxson  

E-Print Network [OSTI]

A Reactive Measurement Framework Mark Allman and Vern Paxson International Computer Science Institute Abstract. Often when assessing complex network behavior a single measure- ment is not enough for thinking about "measurement" as a process rather than an event. We introduce reactive measurement (REM

Paxson, Vern

149

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network [OSTI]

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

150

A Reactive Control Approach for Pipeline Inspection with an AUV  

E-Print Network [OSTI]

A Reactive Control Approach for Pipeline Inspection with an AUV Pedro K. Paim, Bruno Jouvencel and research activities, performing tasks such as survey, inspection of sub-sea pipelines and object recovery of mission. This paper proposes a reactive control approach for pipeline following by a torpedo- like

Paris-Sud XI, Université de

151

From Teleo-Reactive specifications to architectural components: A model-driven approach  

Science Journals Connector (OSTI)

The Teleo-Reactive approach designed by N.J. Nilsson offers a high-level programming model that permits the development of reactive systems, such as robotic vehicles. Teleo-Reactive programs are written in a manner that allows engineers to define the ... Keywords: Component-based software development, Model-driven software development, Reactive systems, Robotics, Teleo-Reactive programs

Pedro SNchez; Diego Alonso; Jos Miguel Morales; Pedro Javier Navarro

2012-11-01T23:59:59.000Z

152

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect (OSTI)

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

153

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures  

E-Print Network [OSTI]

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures Elodie Salmon a , Adri C.T. van Duin b , François Lorant Brown coal using the ReaxFF reactive force field. We find that these reactive MD simulations

Goddard III, William A.

154

Reactive barriers for {sup 137}Cs retention  

SciTech Connect (OSTI)

{sup 137}Cs was dispersed globally by cold war activities and, more recently, by the Chernobyl accident. Engineered extraction of {sup 137}Cs from soils and groundwaters is exceedingly difficult. Because the half life of {sup 137}Cs is only 30.2 years, remediation might be more effective (and less costly) if {sup 137}Cs bioavailability could be demonstrably limited for even a few decades by use of a reactive barrier. Essentially permanent isolation must be demonstrated in those few settings where high nuclear level wastes contaminated the environment with {sup 135}Cs (half life 2.3x10{sup 6} years) in addition to {sup 137}Cs. Clays are potentially a low-cost barrier to Cs movement, though their long-term effectiveness remains untested. To identify optimal clays for Cs retention Cs resorption was measured for five common clays: Wyoming Montmorillonite (SWy-1), Georgia Kaolinites (KGa-1 and KGa-2), Fithian Illite (F-Ill), and K-Metabentonite (K-Mbt). Exchange sites were pre-saturated with 0.16 M CsCl for 14 days and readily exchangeable Cs was removed by a series of LiNO{sub 3} and LiCl washes. Washed clay were then placed into dialysis bags and the Cs release to the deionized water outside the bags measured. Release rates from 75 to 139 days for SWy-1, K-Mbt and F- 111 were similar; 0.017 to 0.021% sorbed Cs released per day. Both kaolinites released Cs more rapidly (0.12 to 0.05% of the sorbed Cs per day). In a second set of experiments, clays were doped for 110 days and subjected to an extreme and prolonged rinsing process. All the clays exhibited some capacity for irreversible Cs uptake so most soils have some limited ability to act as a natural barrier to Cs migration. However, the residual loading was greatest on K-Mbt ({approximately} 0.33 wt% Cs). Thus, this clay would be the optimal material for constructing artificial reactive barriers.

KRUMHANSL,JAMES L.; BRADY,PATRICK V.; ANDERSON,HOWARD L.

2000-05-19T23:59:59.000Z

155

Reactive sticking coefficients of silane on silicon  

SciTech Connect (OSTI)

We have investigated the reaction of room-temperature silane and disilane on a hot polycrystalline silicon surface using both a collision-free molecular beam and a very low pressure CVD cell. Reactive sticking coefficients were obtained from deposition rate data over a wide range of temperatures and silane (disilane) fluxes. The RSCs are substantially less than one, ranging from 6 x 10/sup -5/ to 4 x 10/sup -2/. For silane we observed curved Arrhenius plots with slopes decreasing from approx.60 kcal mol/sup -1/ at low temperatures to approx.2 kcal mol/sup -1/ at higher temperatures. The RSCs are independent of flux (pressure) at 1040/sup 0/C, but vary as flux to the approx.-1/2 power at 710/sup 0/C. A model comprised of a dissociative adsorption mechanism with competing associative desorption and reaction was found to give reasonable agreement. For disilane, we observed RSCs that were roughly ten times higher than those for silane. We also observed a curved Arrhenius plot and a flux dependence at 710/sup 0/C for disilane. 22 refs., 5 figs.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1987-01-01T23:59:59.000Z

156

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

157

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally...

158

Metal-Pyrrolide Complexes in Three-fold Symmetry: Synthesis, Structure, Reactivity and Magnetism  

E-Print Network [OSTI]

Structure, Reactivity and Magnetism by William Hill Harman AStructure, Reactivity and Magnetism by William Hill Harmanlost time. Dave taught me magnetism and what it takes to win

Harman, William Hill

2010-01-01T23:59:59.000Z

159

Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene  

E-Print Network [OSTI]

The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement ...

Arizpe, Luis (Luis Alfredo)

2011-01-01T23:59:59.000Z

160

Aging Enhances the Production of Reactive Oxygen Species andBactericid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Photo of the Week: Reactive Ion Etching | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Reactive Ion Etching Reactive Ion Etching Photo of the Week: Reactive Ion Etching October 17, 2013 - 1:26pm Addthis Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material structures. In this photo, the drop-like domes were carved through a process called reactive ion etching, which produced the striped bubbles you see in the Laue lens. The prototype in this image helped scientists perfect the process of creating lenses so precise that scientists are able to focus x-rays to within a single nanometer. | Photo courtesy of Brookhaven National Laboratory. Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material

162

Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquids: Reactivity of Primary Species Liquids: Reactivity of Primary Species James F. Wishart In "Ionic Liquids as Green Solvents: Progress and Prospects" Rogers, R. D. and Seddon, K. R. , Eds.; ACS Symp. Ser. 856, Ch. 31, pp. 381-395, American Chemical Society, Washington, DC, 2003. (ISBN 0-84123-856-1) [Information about the book] Abstract: An understanding of the radiation chemistry of ionic liquids is important for development of their applications in radioactive material processing and for the application of pulse radiolysis techniques to the general study of chemical reactivity in ionic liquids. The distribution of primary radiolytic species and their reactivities determine the yields of ultimate products and the radiation stability of a particular ionic liquid. This chapter introduces some principles of radiation chemistry and the

163

Detoxification of hydrolysate by reactive-extraction for generating biofuels  

Science Journals Connector (OSTI)

We introduce a reactive extraction to detoxify hydrolysate before fermentation to biofuels. In the selection of diluents, n-octanol showed the highest removal yield of 5-hydroxymethylfurfural (5-HMF) and levulini...

Gwi-Taek Jeong; Sung-Koo Kim; Don-Hee Park

2013-02-01T23:59:59.000Z

164

Cooperative Strategies and Reactive Search: A Hybrid Model Proposal  

Science Journals Connector (OSTI)

Cooperative strategies and reactive search are very promising techniques for solving hard optimization problems, since they reduce human intervention required to set up a method when the resolution of an unknown instance is needed. However, as far as ...

Antonio D. Masegosa; Franco Mascia; David Pelta; Mauro Brunato

2009-11-01T23:59:59.000Z

165

Mechanisms of Photochemistry and Reactive Oxygen Production by  

E-Print Network [OSTI]

photosensitizer that produces reactive oxygen species (ROS) in the presence of light; however, its properties medical and environmental contexts as well as the potential applications implied for industrial or water of transferring light energy to chemical oxidation potential in theformof

Alvarez, Pedro J.

166

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network [OSTI]

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

167

The Safe Storage Study for Autocatalytic Reactive Chemicals  

E-Print Network [OSTI]

In the U.S. Chemical Safety and Hazard Investigation Board (CSB) report, Improving Reactive Hazard Management, there are 37 out of 167 accidents, which occurred in a storage tank or a storage area. This fact demonstrates that thermal runaway...

Liu, Lijun

2010-10-12T23:59:59.000Z

168

Reactive Power Compensation Strategy of DGIF Wind Park  

Science Journals Connector (OSTI)

In this chapter, two different wind park reactive power compensation strategies for the DFIG wind park connected to the sub-transmission level are proposed. Except considering DFIG wind turbines as dynamic reacti...

JingJing Zhao; Yang Fu; DongDong Li

2014-01-01T23:59:59.000Z

169

Evolution of Memory in Reactive Artificial Neural Networks  

E-Print Network [OSTI]

in the context of evolution: how reactive agents could have evolved into cognitive ones with internalized memory? This study strives to find an answer to the question by simulating neuroevolution on artificial neural networks, with the hypothesis...

Chung, Ji Ryang

2012-07-16T23:59:59.000Z

170

Reactive Support and Voltage Control Service: Key Issues and Challenges  

E-Print Network [OSTI]

Reactive Support and Voltage Control Service: Key Issues and Challenges George Gross^, Paolo of Illinois at Urbana-Champaign, Urbana, IL 61801, USA, e-mail gross@uiuc.edu ° Dipartimento di Ingegneria

Gross, George

171

Analytical methods for determining the reactivity of pyrochemical salts  

SciTech Connect (OSTI)

Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

Phillips, A.G.; Stakebake, J.L.

1994-05-01T23:59:59.000Z

172

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

173

Local Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the re...

Turitsyn, Konstantin S; Backhaus, Scott; Chertkov, Misha

2010-01-01T23:59:59.000Z

174

Assessing low power reactivity levels in subcritical CANDU reactors  

SciTech Connect (OSTI)

A new technique has been developed for monitoring slow reactivity changes in Canadian deuterium uranium (CANDU) nuclear reactors during low power operation, following a sustained period of high power operation. The power doubling halving worth (PDHW) test tracks slow reactivity changes by evaluating the reactivity perturbation required by the power regulating system to halve and double reactor power over time. During low power operation of a CANDU reactor, the PDHW test is used to monitor the decay of the photoneutron precursors, so that the reactor power can be lowered using a preset amount of reactivity. The PDHW test is described in this paper and is validated by using computer simulations and operating data from a CANDU reactor.

Teare, S.W. [Corporation of the City of Mississauga, Ontario (Canada)] [Corporation of the City of Mississauga, Ontario (Canada); Shanes, F.C. [Ontario Hydro, Toronto, Ontario (Canada)] [Ontario Hydro, Toronto, Ontario (Canada); Hersey, M.W. [Pickering Nuclear Generating Station, Ontario (Canada)] [Pickering Nuclear Generating Station, Ontario (Canada)

1996-08-01T23:59:59.000Z

175

(Electronic structure and reactivities of transition metal clusters)  

SciTech Connect (OSTI)

The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

Not Available

1992-01-01T23:59:59.000Z

176

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive Reactive  

E-Print Network [OSTI]

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition) homogeneous reactions with indoor pollutants. The #12;Proceedings of Healthy Buildings 2009 Paper 336 latter

Siegel, Jeffrey

177

Research on fuzzy logic based dynamic boundary voltage and reactive power integrated control method  

Science Journals Connector (OSTI)

Aiming at the existing problems of conventional substation voltage and reactive power integrated control method, a new fuzzy logic based dynamic reactive power boundary voltage and reactive power integrated control method is proposed. Fuzzy logic control ... Keywords: dynamic boundary, fuzzy logic, reactive power, voltage

Zigang Xu; Fei Wang

2009-06-01T23:59:59.000Z

178

Development and Evaluation of a State-of-the-Science Reactive Plume  

E-Print Network [OSTI]

for plume rise, plume visibility, and stack opacity (5). Examples of other reactive plume models include

Zhang, Yang

179

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah  

Broader source: Energy.gov [DOE]

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

180

Sandia National Laboratories: HelioVolt Modules Installed at...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Exhibition (EU PVSC) EC Top Publications Reference Model 5 (RM5): Oscillating Surge Wave Energy Converter Experimental Wave Tank Test for Reference Model 3 Floating- Point...

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

2013 Chevrolet Volt - VIN 3929 - Advanced Vehicle Testing - Beginning...  

Broader source: Energy.gov (indexed) [DOE]

Voltage 3 : 3.00 V Thermal Management: Active - Liquid cooled BATTERY LABORATORY TEST RESULTS SUMMARY Vehicle Mileage and Testing Date Vehicle Odometer: 4,007 mi Date of...

182

2013 Chevrolte Volt - VIN 3929 - Advanced Vehicle Testing - Baseline...  

Broader source: Energy.gov (indexed) [DOE]

Sheets (MSDS) for all unique hazardous materials the vehicle is equipped with, including Energy Storage System (ESS) batteries or capacitors, and auxiliary batteries. (3)...

183

2011 Chevrolte Volt - VIN 0815 - Advanced Vehicle Testing - Baseline...  

Broader source: Energy.gov (indexed) [DOE]

Sheets (MSDS) for all unique hazardous materials the vehicle is equipped with, including Energy Storage System (ESS) batteries or capacitors, and auxiliary batteries. (3)...

184

Chevrolet Volt for a Smart Planet Video Transcript  

E-Print Network [OSTI]

Gassenfeit, GM: A smarter automotive industry is one that can foresee the future and then bring it to market pla

185

Some operating features of a 100,000-volt transmission  

E-Print Network [OSTI]

of the thesis - - - - - - Page 2. (2) Introductory description of line - - - Page 5* A* Stations in operation, B. Plan and profile of route, C. Mechanical construction. D. Mechanical weakness of line - - - Paige 10. a^ Excessive lengths of spans. b... Superstructure Denver Substation - 7 Profile of the Transmission Line 8a Plan of the Transmission Line - - - - - 8b Transmission Line at Hell Gate - - - - - 11 Sleet on the Argentine Crest Tower 13 Tower Crushed by Snow Slide - - - - - 13 Curve of Sparking...

Jones, Raymond

1914-03-17T23:59:59.000Z

186

Internal structure, hygroscopic and reactive properties of mixed sodium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Internal structure, hygroscopic and Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Print Friday, 13 May 2011 00:00 Scientists recently combined experimental approaches and molecular dynamics modeling to gain new insights into the internal structure of sea salt particles and relate it to their fundamental chemical reactivity in the atmosphere. This research shows that surface enhancement or depletion of chemical components in marine particles can occur because of the difference in the chemical nature of the species. Because the atmospheric chemistry of the salt particles takes place at the gas-particle interface, understanding their complex surfaces provides new insights about their effect on the environment and climate change. Article Link.

187

Ionic Liquids and Ionizing Radiation: Reactivity of Highly Energetic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ionizing Radiation: Reactivity of Highly Energetic Ionizing Radiation: Reactivity of Highly Energetic Species James F. Wishart J. Phys. Chem. Lett. 1, 3225-3231 (2010). [Find paper at ACS Publications] or use ACS Articles on Request View the video on this Perspective article at The Journal of Physical Chemistry Letters (5:03) Selected for the ACS Special Virtual Issue on Ionic Liquids (March 2011). Abstract: Due to their unique properties, ionic liquids present many opportunities for basic research on the interactions of radiation with materials under conditions not previously available. At the same time, there are practical applied reasons for characterizing, understanding, and being able to predict how ionic-liquid-based devices and industrial-scale systems will perform under conditions of extreme reactivity, including radiation. This

188

Environmentally stable reactive alloy powders and method of making same  

DOE Patents [OSTI]

Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

1998-09-22T23:59:59.000Z

189

Options for Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic(PV) generation on an electrical distribution circuit present several challenges and opportunities for distribution utilities. Rapidly varying irradiance conditions may cause voltage sags and swells that cannot be compensated by slowly responding utility equipment resulting in a degradation of power quality. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We discuss and compare via simulation various design options for control systems to manage the reactive power generated by these inverters. An important design de...

Sulc, Petr; Backhaus, Scott; Chertkov, Michael

2010-01-01T23:59:59.000Z

190

Design and synthesis of reactive separation systems. Final report  

SciTech Connect (OSTI)

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-12-31T23:59:59.000Z

191

Non-Energetic Reactive Armor (NERA) and Semi-Energetic Reactive Armor (SERA) FY13 Final Report  

SciTech Connect (OSTI)

INL researchers have proposed prototypes for future lightweight armor systems that reside in a technology gap between explosive reactive armor and passive armor. The targets were designed to react under impact and throw a steel front plate into the path of the projectile, forcing the projectile to engage more of the front plate during its penetration process. These prototypes are intended to exhibit the enhanced efficiency of explosive reactive armor without the collateral damage often associated with explosive reactive armor. One of the prototype systems, Semi Energetic Reactive Armor (SERA), functions similarly to explosive reactive armor, but features a reactive material that reacts much slower than explosive reactive armor. Two different SERA test groups were built and featuring different ratios of aluminum Teflon(copyright) powders pressed into 0.5 in. thick energetic tiles and sandwiched between 0.25 in. thick RHA plates. The other prototype system, Non Energetic Reactive Armor (NERA), utilizes the strain energy in compressed rubber to launch a front flyer plate into the path of an incoming projectile. It is comprised of a 1 in. thick rubber layer sandwiched between two 0.25 in. thick RHA plates with bolt holes around the perimeter. Bolts are inserted through the entire target and tightened to compress the rubber sheet to significant strain levels (approximately 40%). A fourth group of targets was tested as a control group. It featured a 0.5 in. thick rubber sheet sandwiched between two 0.25 in. thick RHA plates, similar to the NERA test articles, but the rubber is uncompressed. The four test groups (uncompressed rubber, compressed rubber, 70/30 Al/PTFE, 50/50 Al/PTFE) were each fabricated with three identical test articles in each group. All twelve targets were subjected to ballistic testing at the National Security Test Range on July 17, 2013. They were tested with 0.5 in. diameter steel rods shot at a consistent velocity at each target. In order to characterize the energetic materials, break wires were embedded in the targets and burn velocities were measured. The residual mass method was used to compare the target performance of each group and final performance data is presented below.

Ben Langhorst; Nikki Rasmussen; Andrew Robinson

2013-08-01T23:59:59.000Z

192

Reactive Search Optimization: Learning while Roberto Battiti and Mauro Brunato  

E-Print Network [OSTI]

Reactive Search Optimization: Learning while Optimizing Roberto Battiti and Mauro Brunato 1, Universit`a di Trento, Italy, e-mail: roberto.battiti@unitn.it Mauro Brunato LION Lab, Universit`a di Trento, Italy, e-mail: mauro.brunato@unitn.it 1 #12;2 Roberto Battiti and Mauro Brunato in the loop between

Battiti, Roberto

193

Toward a new paradigm for reactive flow modeling.  

SciTech Connect (OSTI)

Traditional reactive flow modeling provides a computational representation of shock initiation of energetic materials. Most reactive flow models require ad hoc assumptions to obtain robust simulations, assumptions that result from partitioning energy and volume change between constituents in a reactive mixture. For example, most models assume pressure and/or temperature equilibrium for the mixture. Many mechanical insults to energetic materials violate these approximations. Careful analysis is required to ensure that the model assumptions and limitations are not exceeded. One limitation is that the shock to detonation transition is replicated only for strong planar shocks. Many models require different parameters to match data from thin pulse, ramp wave, or multidimensional loading, an approach that fails for complex loading. To accurately simulate reaction under non-planar shock impact scenarios a new formalism is required. The continuum mixture theory developed by Baer and Nunziato is used to eliminate ad hoc assumptions and limitations of current reactive flow models. This modeling paradigm represents the multiphase nature of reacting condensed/gas mixtures. Comparisons between simulations and data are presented.

Schmitt, Robert Gerard

2005-08-01T23:59:59.000Z

194

Resilient Intrusion Tolerance through Proactive and Reactive Recovery  

E-Print Network [OSTI]

system's correct operation. We design a proactive- reactive recovery service based on a hybrid the resilience of an intrusion-tolerant firewall adequate for the protection of critical infrastructures infras- tructures like the Power grid. One approach that promises to satisfy this requirement

Neves, Nuno

195

Voltage Regulation through Smart Utilization of Potential Reactive Power Resources  

Science Journals Connector (OSTI)

The introduction of demand response concept, in addition to increment of penetration of distributed generation (DG) based on renewable energies, make opportunities for the novel control schemes to be integrated in power system on a smart grid framework. ... Keywords: Demand response, distributed generation, reactive power, renewable energy, smart grid, voltage control

H. Kazari; A. Abbaspour-Tehrani Fard; A. S. Dobakhshari; A. M. Ranjbar

2011-11-01T23:59:59.000Z

196

Substituent Effects on the Reactivity of the Silicon-Carbon  

E-Print Network [OSTI]

Canada L8S 4M1 Received April 28, 2000 ABSTRACT Laser flash photolysis of various organosilicon compounds as a reactive intermediate in the high-temperature pyrolysis of a silacyclobutane deriva- tive.9 Hundreds describes our efforts to employ these techniquess laser flash photolysis methods in particularsto study

Leigh, William J.

197

Surface tension in a reactive binary mixture of incompressible fluids  

E-Print Network [OSTI]

Surface tension in a reactive binary mixture of incompressible fluids Henning Struchtrup Institute with a distributed form of surface tension. The model describes chemistry, diffusion, viscosity and heat transfer tension at the front. Keywords: Binary mixtures, Surface tension, Irreversible thermodynamics, Hele

Struchtrup, Henning

198

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may depend are combined is certainly not arbitrary. For instance, the repetition of one cycle may rely on the repetitionsDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Leue, Stefan

199

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

processes of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may in which cycle executions are combined is certainly not arbitrary. For instance, the repetition of oneDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Reiterer, Harald

200

Effect of Number of Fractionating Trays on Reactive Distillation Performance  

E-Print Network [OSTI]

Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

Al-Arfaj, Muhammad A.

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Reactive materials can quickly form plugs for blowout control  

SciTech Connect (OSTI)

Various types of reactive materials, or gunk, can react directly with produced fluids (oil, condensate, or brine) or with an additionally injected fluid to form a plug to kill blowout wells or shut off large flow paths. Several recent blowouts were successfully controlled with reactive plugs; other conventional methods would have been more difficult operationally and cost more. Several plug mixtures are available on the market and can be made to suit the type of application and any particular environmental concerns. With proper planning and application, reactive plugs should be considered as a prime well control method when injection into the blowout flow path is available. This method of blowout control can save significant time and expense. The paper discusses the two basic methods of using reactive fluids depending on the flow path available, the use of cements, application steps, environmental concerns, and three case histories: a horizontal well in Texas, a high pressure, high temperature well offshore Louisiana, and a gas blowout in Argentina.

Flak, L.H. [Wright Boots and Coots, Houston, TX (United States)

1995-04-17T23:59:59.000Z

202

Neutron economic reactivity control system for light water reactors  

DOE Patents [OSTI]

A neutron reactivity control system for a LWBR incorporating a stationary seed-blanket core arrangement. The core arrangement includes a plurality of contiguous hexagonal shaped regions. Each region has a central and a peripheral blanket area juxapositioned an annular seed area. The blanket areas contain thoria fuel rods while the annular seed area includes seed fuel rods and movable thoria shim control rods.

Luce, Robert G. (Glenville, NY); McCoy, Daniel F. (Latham, NY); Merriman, Floyd C. (Rotterdam, NY); Gregurech, Steve (Scotia, NY)

1989-01-01T23:59:59.000Z

203

Generalized Chemical Reactivity of Curved Surfaces: Carbon Nanotubes  

E-Print Network [OSTI]

. Following the decomposition, the total reaction energy Etotal, which is the index of chemical reactivity, can be divided into three terms: strain energy Estrain, C-X binding energy EC-X, and global relaxation in a CNT can enhance the hydrogenation energy at the location of the excess deformation so

Srivastava, Deepak

204

Local control of reactive power by distributed photovoltaic generators  

SciTech Connect (OSTI)

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the real power generated by the PVs. Using one adjustable parameter per circuit, we balance the requirements on power quality and desire to minimize thermal losses. Numerical analysis of two exemplary systems, with comparable total PV generation albeit a different spatial distribution, show how to adjust the optimization parameter depending on the goal. Overall, this local scheme shows excellent performance; it's capable of guaranteeing acceptable power quality and achieving significant saving in thermal losses in various situations even when the renewable generation in excess of the circuit own load, i.e. feeding power back to the higher-level system.

Chertkov, Michael [Los Alamos National Laboratory; Turitsyn, Konstantin [Los Alamos National Laboratory; Sulc, Petr [Los Alamos National Laboratory; Backhaus, Scott [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

205

Sleep & Memory/Review Memory reactivation and consolidation during sleep  

E-Print Network [OSTI]

Sleep & Memory/Review Memory reactivation and consolidation during sleep Ken A. Paller1 and Joel L, Illinois 60208-2710, USA Do our memories remain static during sleep, or do they change? We argue here that memory change is not only a natural result of sleep cognition, but further, that such change constitutes

Paller, Ken

206

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Broader source: Energy.gov (indexed) [DOE]

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Final Report Phase II: Performance Evaluation of Permeable Reactive

207

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Broader source: Energy.gov (indexed) [DOE]

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Phase II: Performance Evaluation of Permeable Reactive Barriers and

208

Photoluminescent silicon nanocrystals synthesized by reactive laser Daria Riabinina,a  

E-Print Network [OSTI]

Photoluminescent silicon nanocrystals synthesized by reactive laser ablation Daria Riabinina reactive laser ablation in oxygen atmosphere followed by annealing. We observe a strong photoluminescence size, obtained independently by fitting photoluminescence spectra and from x-ray diffraction patterns

209

Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel  

Broader source: Energy.gov [DOE]

This study uses numerical simulations to explore the use of wet ethanol as the low-reactivity fuel and diesel as the high-reactivity fuel for RCCI operation in a heavy-duty diesel engine.

210

Bioinformatic analysis of xenobiotic reactive metabolite target proteins and their interacting partners  

E-Print Network [OSTI]

Background Protein covalent binding by reactive metabolites of drugs, chemicals and natural products can lead to acute cytotoxicity. Recent rapid progress in reactive metabolite target protein identification has shown ...

Hanzlik, Robert P.; Fang, Jianwen; Koen, Yakov M.

2009-06-12T23:59:59.000Z

211

Chemical Reactivity of Reduced TiO2(110): The dominant role of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

212

E-Print Network 3.0 - advected reactive scalars Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

through... reactive scalars that are initially distinct, ... Source: Crimaldi, John P. - Department of Civil, Environmental, and Architectural Engineering, University of...

213

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network [OSTI]

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

214

Abstract This paper reviews specific issues and challenges in reactive power management within the competitive electricity  

E-Print Network [OSTI]

, points out various deficiencies in the reactive power procurement in the US markets and provides recommendations for, and lists a number of challenges in the reactive power supply and usage area. Basically of the same type as active power or active energy. Many reactive power management issues concern the static

Gross, George

215

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure Modes from Reactive Dynamics Simulations  

Science Journals Connector (OSTI)

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure Modes from Reactive Dynamics Simulations ... Ettringite is a hexacalcium aluminate trisulfate hydrate mineral that forms during Portland cement hydration. ... Here, we report on the development of this ReaxFF force field and on its validation and application using reactive molecular dynamics (RMD) simulations to characterize and understand the elastic, plastic, and failure response of ettringite at the atomic scale. ...

Lianchi Liu; Andres Jaramillo-Botero; William A. Goddard; III; Huai Sun

2012-03-13T23:59:59.000Z

216

Engine combustion control at low loads via fuel reactivity stratification  

DOE Patents [OSTI]

A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

2014-10-07T23:59:59.000Z

217

Reactive Membrane Barriers for Containment of Subsurface Contamination  

SciTech Connect (OSTI)

The overall goal of this project was to develop reactive membrane barriers--a new and flexible technique to contain and stabilize subsurface contaminants. Polymer membranes will leak once a contaminant is able to diffuse through the membrane. By incorporating a reactive material in the polymer, however, the contaminant is degraded or immobilized within the membrane. These processes increase the time for contaminants to breakthrough the barrier (i.e. the lag time) and can dramatically extend barrier lifetimes. In this work, reactive barrier membranes containing zero-valent iron (Fe{sup 0}) or crystalline silicotitanate (CST) were developed to prevent the migration of chlorinated solvents and cesium-137, respectively. These studies were complemented by the development of models quantifying the leakage/kill time of reactive membranes and describing the behavior of products produced via the reactions within the membranes. First, poly(vinyl alcohol) (PVA) membranes containing Fe{sup 0} and CST were prepared and tested. Although PVA is not useful in practical applications, it allows experiments to be performed rapidly and the results to be compared to theory. For copper ions (Cu{sup 2+}) and carbon tetrachloride, the barrier was effective, increasing the time to breakthrough over 300 times. Even better performance was expected, and the percentage of the iron used in the reaction with the contaminants was determined. For cesium, the CST laden membranes increased lag times more than 30 times, and performed better than theoretical predictions. A modified theory was developed for ion exchangers in reactive membranes to explain this result. With the PVA membranes, the effect of a groundwater matrix on barrier performance was tested. Using Hanford groundwater, the performance of Fe{sup 0} barriers decreased compared to solutions containing a pH buffer and high levels of chloride (both of which promote iron reactivity). For the CST bearing membrane, performance improved by a factor of three when groundwater was used in place of deionized water. The performance of high density polyethylene (HDPE) membranes containing Fe{sup 0} was then evaluating using carbon tetrachloride as the target contaminant. Only with a hydrophilic additive (glycerol), was the iron able to extend lag times. Lag times were increased by a factor of 15, but only 2-3% of the iron was used, likely due to formation of oxide precipitates on the iron surface, which slowed the reaction. With thicker membranes and lower carbon tetrachloride concentrations, it is expected that performance will improve. Previous models for reactive membranes were also extended. The lag time is a measurement of when the barrier is breached, but contaminants do slowly leak through prior to the lag time. Thus, two parameters, the leakage and the kill time, were developed to determine when a certain amount of pollutant has escaped (the kill time) or when a given exposure (concentration x time) occurs (the leakage). Finally, a model was developed to explain the behavior of mobile reaction products in reactive barrier membranes. Although the goal of the technology is to avoid such products, it is important to be able to predict how these products will behave. Interestingly, calculations show that for any mobile reaction products, one half of the mass will diffuse into the containment area and one half will escape, assuming that the volumes of the containment area and the surrounding environment are much larger than the barrier membrane. These parameters/models will aid in the effective design of barrier membranes.

William A. Arnold; Edward L. Cussler

2007-02-26T23:59:59.000Z

218

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents [OSTI]

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

219

Kinetic azeotropy and design of reactive distillation columns  

SciTech Connect (OSTI)

The reactive fixed points in the distillation maps of a reactive distillation column (RDC) with kinetically controlled reactions are identified and their role in deciding the design feasibility has been elucidated. The fixed points at which both reaction and distillation vectors have zero magnitudes correspond to the equilibrium fixed point. It is known that the relative positions of these points for the rectifying and stripping sections determine the value of the minimum reflux ratio. However, apart from these fixed points, there are certain fixed points in the distillation map at which, though the reaction and distillation vectors have nonzero magnitudes, they nullify the effects of each other. These points correspond to the kinetic fixed points and have a special significance. Their positions have direct influence on the feasible product composition. A simple example of an ideal ternary system undergoing a reaction 2B {longleftrightarrow} A + c has been illustrated to show the importance of kinetic azeotropy in the design aspects of RDC.

Mahajani, S.M. [Monash Univ., Clayton, Victoria (Australia). Dept. of Chemical Engineering] [Monash Univ., Clayton, Victoria (Australia). Dept. of Chemical Engineering

1999-01-01T23:59:59.000Z

220

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide  

SciTech Connect (OSTI)

Cerium oxide is a principal component in many heterogeneous catalytic processes. One of its key characteristics is the ability to provide or remove oxygen in chemical reactions. The different crystallographic faces of ceria present significantly different surface structures and compositions that may alter the catalytic reactivity. The structure and composition determine the number of coordination vacancies surrounding surface atoms, the availability of adsorption sites, the spacing between adsorption sites and the ability to remove O from the surface. To investigate the role of surface orientation on reactivity, CeO2 films were grown with two different orientations. CeO2(100) films were grown ex situ by pulsed laser deposition on Nb-doped SrTiO3(100). CeO2(111) films were grown in situ by thermal deposition of Ce metal onto Ru(0001) in an oxygen atmosphere. The chemical reactivity was characterized by the adsorption and decomposition of various molecules such as alcohols, aldehydes and organic acids. In general the CeO2(100) surface was found to be more active, i.e. molecules adsorbed more readily and reacted to form new products, especially on a fully oxidized substrate. However the CeO2(100) surface was less selective with a greater propensity to produce CO, CO2 and water as products. The differences in chemical reactivity are discussed in light of possible structural terminations of the two surfaces. Recently nanocubes and nano-octahedra have been synthesized that display CeO2(100) and CeO2(111) faces, respectively. These nanoparticles enable us to correlate reactions on high surface area model catalysts at atmospheric pressure with model single crystal films in a UHV environment.

Mullins, David R [ORNL] [ORNL; Albrecht, Peter M [ORNL] [ORNL; Calaza, Florencia C [ORNL] [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Initiation and reactivation of Proterozoic aulacogen, northern Mexico  

SciTech Connect (OSTI)

Geochemical and petrologic affinities of late Proterozoic (approx. 1Ga) bimodal igneous rocks of the Franklin Mountains, west Texas, suggest a rift origin. Scattered occurrences of similar rocks southward into the state of Chihuahua, Mexico, indicate a southerly trend for the feature. The feature is bounded by stable blocks: the stable craton of west Texas to the east and northeast, and the Sierra del Nido block to the west and southwest. Separation of the Sierra del Nido block from the craton occurred about 1 Ga. Gravity gradients mark the boundaries of the blocks, and a northwest-trending Bouger gravity high may mark the axis of the aulacogen. The aulacogen and the Sierra del Nido block are truncated to the south by the Mesozoic Mojave-Sonora discontinuity. The aulacogen was reactivated, at least in part, in the late Paleozoic as the Pedregosa basin and in the Mesozoic as the Chihuahua trough. These reactivations were apparently not full-fledged rifting events, but did result in basin development. The Sierra del Nido block was a paleographic high throughout the Paleozoic, and the Aldama platform developed on this block during the Cretaceous. The most recent reactivation of the aulacogen is as the southern extension of the Rio Grande rift, as evidenced by trends of high heat flow, recent mafic magmatism, and regional extensional faulting.

Goodell, P.C.; Dyer, R.; Keller, G.R.

1985-02-01T23:59:59.000Z

222

Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns  

SciTech Connect (OSTI)

Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs generally have low volatilities and are combustion-resistant, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of primary radiation chemistry, charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of reactions and product distributions. We study these issues by characterization of primary radiolysis products and measurements of their yields and reactivity, quantification of electron solvation dynamics and scavenging of electrons in different states of solvation. From this knowledge we wish to learn how to predict radiolytic mechanisms and control them or mitigate their effects on the properties of materials used in nuclear fuel processing, for example, and to apply IL radiation chemistry to answer questions about general chemical reactivity in ionic liquids that will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that the slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increase the importance of pre-solvated electron reactivity and consequently alter product distributions and subsequent chemistry. This difference from conventional solvents has profound effects on predicting and controlling radiolytic yields, which need to be quantified for the successful use under radiolytic conditions. Electron solvation dynamics in ILs are measured directly when possible and estimated using proxies (e.g. coumarin-153 dynamic emission Stokes shifts or benzophenone anion solvation) in other cases. Electron reactivity is measured using ultrafast kinetics techniques for comparison with the solvation process.

Wishart, J.F.

2011-06-12T23:59:59.000Z

223

Performance of a Permeable Reactive Barrier Using Granular Zero-Valent  

Broader source: Energy.gov (indexed) [DOE]

Performance of a Permeable Reactive Barrier Using Granular Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing

224

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. 1. Reactivity Based Trading and Potential for Ozone Hot Spot Formation  

Science Journals Connector (OSTI)

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. ... (12)?Thompson, T. M.; Wang, L.; Web, A.; McDonald-Buller, E.; Allen, D. T. Photochemical Modeling of the Air Quality Impacts of an Emissions Trading Program for Highly Reactive Volatile Organic Compounds (HRVOCs) in Texas; Air and Waste Management Association Annual Meeting, New Orleans, June, 2006. ...

Linlin Wang; Tammy Thompson; Elena C. McDonald-Buller; Alba Webb; David T. Allen

2007-02-27T23:59:59.000Z

225

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

Many contaminated areas consist of a source area and a plume. In the source area, the contaminant moves vertically downward from a release point through the vadose zone to an underlying saturated region. Where contaminants are organic liquids, NAPL may accumulate on the water table, or it may continue to migrate downward through the saturated region. Early developments of permeable barrier technology have focused on intercepting horizontally moving plumes with vertical structures, such as trenches, filled with reactive material capable of immobilizing or degrading dissolved contaminants. This focus resulted in part from a need to economically treat the potentially large volumes of contaminated water in a plume, and in part from the availability of construction technology to create the vertical structures that could house reactive compounds. Contaminant source areas, however, have thus far remained largely excluded from the application of permeable barrier technology. One reason for this is the lack of conventional construction methods for creating suitable horizontal structures that would place reactive materials in the path of downward-moving contaminants. Methods of hydraulic fracturing have been widely used to create flat-lying to gently dipping layers of granular material in unconsolidated sediments. Most applications thus far have involved filling fractures with coarse-grained sand to create permeable layers that will increase the discharge of wells recovering contaminated water or vapor. However, it is possible to fill fractures with other compounds that alter the chemical composition of the subsurface. One early application involved development and field testing micro-encapsulated sodium percarbonate, a solid compound that releases oxygen and can create aerobic conditions suitable for biodegradation in the subsurface for several months.

Murdoch, L. [FRx Inc., Cincinnati, OH (United States); [Clemson Univ., SC (United States); Siegrist, B. [Oak Ridge National Lab., TN (United States); Vesper, S. [Univ. of Cincinnati, OH (United States)] [and others

1997-12-31T23:59:59.000Z

226

Reactive multilayer synthesis of hard ceramic foils and films  

DOE Patents [OSTI]

A method for synthesizing hard ceramic materials such as carbides, borides nd aluminides, particularly in the form of coatings provided on another material so as to improve the wear and abrasion performance of machine tools, for example. The method involves the sputter deposition of alternating layers of reactive metals with layers of carbon, boron, or aluminum and the subsequent reaction of the multilayered structure to produce a dense crystalline ceramic. The material can be coated on a substrate or formed as a foil which can be coild as a tape for later use.

Makowiecki, Daniel M. (Livermore, CA); Holt, Joseph B. (San Jose, CA)

1996-01-01T23:59:59.000Z

227

Reactive sticking coefficients for silane and disilane on polycrystalline silicon  

SciTech Connect (OSTI)

Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition-rate measurements using molecular beam scattering and a very low-pressure cold-wall reactor. The RSCs have nonlinear Arrhenius temperature dependencies and decrease with increasing flux at low (710 /sup 0/C) temperatures. Several simple models are proposed to explain these observations. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction and low-pressure chemical vapor deposition-rate measurements.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1988-04-15T23:59:59.000Z

228

Modeling biogechemical reactive transport in a fracture zone  

SciTech Connect (OSTI)

A coupled model of groundwater flow, reactive solute transport and microbial processes for a fracture zone of the Aspo site at Sweden is presented. This is the model of the so-called Redox Zone Experiment aimed at evaluating the effects of tunnel construction on the geochemical conditions prevailing in a fracture granite. It is found that a model accounting for microbially-mediated geochemical processes is able to reproduce the unexpected measured increasing trends of dissolved sulfate and bicarbonate. The model is also useful for testing hypotheses regarding the role of microbial processes and evaluating the sensitivity of model results to changes in biochemical parameters.

Molinero, Jorge; Samper, Javier; Yang, Chan Bing, and Zhang, Guoxiang; Guoxiang, Zhang

2005-01-14T23:59:59.000Z

229

Radial space potential measurements in the central cell of the tandem mirror experiment with a heavy-ion-beam probe  

SciTech Connect (OSTI)

Spatial and temporal profiles of the space potential in the central-cell midplane of TMX have been obtained with a heavy-ion-beam probe. The absolute accuracy of measurements is +- 25 volts (with respect to the machine vacuum walls) with a resolution of approx. 2 volts. During moderate fueling with the gas boxes (i/sub gas/ approx. = 1200 Atom-Amperes D/sub 2/), the plasma potential is parabolic to at least 25 cm radius, with phi/sub e/ approx. = phi/sub max/(1-(r/32)/sup 2/) and 300 < phi/sub max/ <450 volts. With puffer-valve fueling, the space potential is relatively flat to at least 27 cm radius, with 250 < phi/sub e/ < 350 volts.

Hallock, G.A.

1983-04-11T23:59:59.000Z

230

Synthesis of belite cement clinker of high hydraulic reactivity  

SciTech Connect (OSTI)

This study is concerned with the increase of the cooling rate of belite clinker, by using the water quenching for the chemical stabilization of reactive belite, which improves the hydraulic properties of this clinker. The addition of adequate mineralizers, as NaF and Fe{sub 2}O{sub 3}, contributes to the improvement of the clinker properties obtained at low burning temperature. X-ray fluorescence spectroscopy, X-ray diffraction analysis and optical microscopy were used to determine the chemical and mineralogical compositions of this clinker. The samples were analyzed by means of a scanning electronic microscope connected with an energy-dispersive X-ray spectrometer to detect the composition of the belite phase and its morphology. Physical and mechanical properties of this clinker cement were determined. The results show that the belite clinker obtained at 1150 {sup o}C, with lime saturation factor 0.67, is characterized by a great hydraulic reactivity, similar to that of the ordinary alite clinker. The addition of 2% of NaF and the water quenching improved the chemical, mineralogical and structural properties, while improving the cement hydraulic properties.

Kacimi, Larbi [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)], E-mail: kacimi20002000@yahoo.fr; Simon-Masseron, Angelique [Laboratoire des Materiaux a Porosite Controlee, CNRS UMR 7016, Universite de Haute-Alsace, 3, rue Alfred-Werner, F-68093 Mulhouse cedex (France)], E-mail: A.Simon@univ-mulhouse.fr; Salem, Souria [Departement d'Architecture, Faculte de Genie Civile, USTO-Oran (Algeria)], E-mail: zinaisalem@yahoo.fr; Ghomari, Abdelhamid [Departement de Chimie, U.A.I.B., Route de Belahcel, Mostaganem (Algeria)], E-mail: belkey@hotmail.com; Derriche, Zoubir [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)

2009-07-15T23:59:59.000Z

231

Interaction phenomena at reactive metal/ceramic interfaces.  

SciTech Connect (OSTI)

The objective of this study was to understand the interface chemical reactions between stable ceramics and reactive liquid metals, and developing microstructure. Experiments were conducted at elevated temperatures where small metal samples of Zr and Zr-alloy were placed on top of selected oxide and non-oxide ceramic substrates (Y{sub 2}O{sub 3}, ZrN, ZrC, and HfC). The sample stage was heated in high-purity argon to about 2000 C, held in most cases for five minutes at the peak temperature, and then cooled to room temperature at {approximately}20 c/min. An external video camera was used to monitor the in-situ wetting and interface reactions. Post-test examinations of the systems were conducted by scanning electron microscopy and energy dispersive spectroscopy. It was determined that the Zr and the Zr-alloy are very active in the wetting of stable ceramics at elevated temperatures. In addition, in some systems, such as Zr/ZrN, a reactive transition phase formed between the ceramic and the metal. In other systems, such as Zr/Y{sub 2}O{sub 3}, Zr/ZrC and Zr/HfC, no reaction products formed, but a continuous and strong joint developed under these circumstances also.

McDeavitt, S. M.; Billings, G. W.; Indacochea, J. E.

2000-11-03T23:59:59.000Z

232

REACTIVITY OF ANIONS IN INTERSTELLAR MEDIA: DETECTABILITY AND APPLICATIONS  

SciTech Connect (OSTI)

We propose a general rule to distinguish between detectable and undetectable astronomical anions. We believe that only few anions live long enough in the interstellar medium and thus can be detected. Our method is based on quantum mechanical calculations capable of describing accurately the evolution of electronic states during chemical processes. The still not fully understood reactivity at low temperatures is discussed considering non-adiabatic effects. The role of excited states has usually been neglected in previous works which basically focused on the ground electronic state for interpretations of experimental observations. Here, we deal with unsaturated carbon chains (e.g., C{sub n} H{sup -}), which show a high density of electronic states close to their corresponding ground electronic states, complex molecular dynamics, and non-adiabatic phenomena. Our general rule shows that it is not sufficient that anions exist in the gas phase (in the laboratory) to be present in media such as astrophysical media, since formation and decomposition reactions of these anions may allow the population of anionic electronic states to autodetach, forming neutrals. For C{sub n} H, reactivity depends strongly on n, where long and short chains behave differently. Formation of linear chains is relevant.

Senent, M. L. [Departamento de Quimica y Fisica Teoricas, Instituto de Estructura de la Materia, IEM-C.S.I.C., Serrano 121, Madrid E-28006 (Spain); Hochlaf, M., E-mail: senent@iem.cfmac.csic.es, E-mail: hochlaf@univ-mlv.fr [Laboratoire de Modelisation et Simulation Multi Echelle, Universite Paris-Est, MSME UMR 8208 CNRS, 5 boulevard Descartes, F-77454 Marne-la-Vallee (France)

2013-05-01T23:59:59.000Z

233

Electrochemical behavior of reactively sputtered iron-doped nickel oxide  

SciTech Connect (OSTI)

Iron-doped nickel oxide films were deposited by reactive sputtering from elemental and alloy targets in a 20% oxygen/argon atmosphere and were characterized for use as oxygen evolution catalysts. The incorporation of iron reduced the overpotential required for oxygen evolution by as much as 300 mV at a current density of 100 mA/cm{sup 2} compared to undoped nickel oxide deposited under similar conditions. Tafel slopes were reduced from 95 mV/dec in undoped NiO{sub x} films to less than 40 mV/dec for films containing 1.6 to 5.6 mole percent (m/o) iron, indicating a change in the rate-limiting step from the primary discharge of OH{sup {minus}} ions to the recombination of oxygen radicals. Resistivity, structural, and compositional measurements indicate that high oxygen content is necessary to gain the full benefit of the iron dopant. Initial tests in KOH indicate excellent long-term stability. A film deposited from the FeNi alloy target, which exhibited low oxygen overpotentials and a Tafel slope of 35 mV/dec, had not degraded appreciably following more than 7,000 h of operation at an anodic current density of 20 mA/cm{sup 2}. Taken together, the low oxygen evolution reaction overpotentials, the excellent stability in KOH, and the relative insensitivity to iron content indicative that reactively sputtered iron-doped nickel oxide is promising as an oxygen catalyst.

Miller, E.L.; Rocheleau, R.E. [Univ. of Hawaii, Honolulu, HI (United States)

1997-09-01T23:59:59.000Z

234

Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.  

SciTech Connect (OSTI)

In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

2012-02-01T23:59:59.000Z

235

Reactive-coupling-induced normal mode splittings in microdisk resonators coupled to waveguides  

SciTech Connect (OSTI)

We study the optomechanical design introduced by M. Li et al. [Phys. Rev. Lett. 103, 223901 (2009)], which is very effective for investigation of the effects of reactive coupling. We show the normal mode splitting that is due solely to reactive coupling rather than due to dispersive coupling. We suggest feeding the waveguide with a pump field along with a probe field and scanning the output probe for evidence of reactive-coupling-induced normal mode splitting.

Huang Sumei; Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)

2010-05-15T23:59:59.000Z

236

Promoting the Reduction Reactivity of Ilmenite by Introducing Foreign Ions in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Promoting the Reduction Reactivity of Ilmenite by Introducing Foreign Ions in Chemical Looping Combustion ... Industrial & Engineering Chemistry Research2014 53 (39), 15157-15166 ...

Jinhua Bao; Zhenshan Li; Ningsheng Cai

2013-04-15T23:59:59.000Z

237

Removal and Recycling of Phosphorus from Wastewater Using Reactive Filter Material Polonite.  

E-Print Network [OSTI]

?? Literature reviews and laboratory work were used to examine the phosphorus removal efficiency of the reactive filter material Polonite. This material is produced from (more)

sterberg, Anna

2012-01-01T23:59:59.000Z

238

Control of nanoparticle size, reactivity and magnetic properties during the bioproduction of magnetite by Geobacter sulfurreducens  

E-Print Network [OSTI]

Control of nanoparticle size, reactivity and magneticbenign route to magnetic nanoparticle synthesis. Here, wed In both thin film and nanoparticle formation, the dominant

Byrne, J. M.

2012-01-01T23:59:59.000Z

239

Natural nanoparticle structure, properties and reactivity from X-ray studies  

E-Print Network [OSTI]

Another important aspect of nanoparticle work relates to theWe thus expect that nanoparticle research will also shedNATURAL NANOPARTICLE STRUCTURE, PROPERTIES AND REACTIVITY

Waychunas, Glenn A.

2010-01-01T23:59:59.000Z

240

E-Print Network 3.0 - administration reduces reactive Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reactive power losses, and increasing line charging and shunt capacitor... Summary Bonneville Power Administration is investigating wide-area stability and voltage...

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Accelerated test methods for evaluating alkali-silica reactivity of recycled concrete aggregates.  

E-Print Network [OSTI]

??This thesis reports the findings of a study carried out to determine the effectiveness of Accelerated Tests in evaluating the Alkali-Silica Reactivity of Recycled Concrete (more)

Johnson, Robert C (Author)

2011-01-01T23:59:59.000Z

242

Moderator displacers for reducing coolant void reactivity in CANDU reactors: a neutronics scoping study.  

E-Print Network [OSTI]

??When the coolant is voided in a CANDU lattice, the net reactivity change is positive, due primarily to the fact that the coolant and moderator (more)

Farkas, Robert

2014-01-01T23:59:59.000Z

243

Use of the electronic differential analyzer in conjunction with passive analog simulators in the investigation of heat conduction in the unsteady state  

E-Print Network [OSTI]

, electrical e R Electrical resistance e C Electrical capacitance i Electrical current Q' Electrical charge FLQ' FLQ' FLQ Q' Q, 2 L-1F-I Ql g Volts Volts Seconds ohms farads ampere s columbs Dimensionless Ratios& e ? e 1 e -e s i R C J (e... the passive analog system was employed to simulate the physical problem of suddenly heating the slab by applying a d-c voltage to the circuit. The value of the electrical resistance and electrical capacitance in this circuit was determined by the value...

Travis, Larry Gene

2012-06-07T23:59:59.000Z

244

Simulations of Deflagration-to-Detonation Transition in Reactive Gases |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

numerically generated pseudo-schlieren image numerically generated pseudo-schlieren image Weak ignition behind a reflected Mach=1.5 shock in a stoichiometric hydrogen-oxygen mixture at 0.1 atm initial pressure. Picture shows a numerically generated pseudo-schlieren image of the onset of a detonation in a turbulent boundary layer. Alexei Khokhlov, University of Chicago; Charles Bacon, Argonne National Laboratory, Joanna Austin, Andrew Knisely, University of Illinois at Urbanna-Champaign Simulations of Deflagration-to-Detonation Transition in Reactive Gases PI Name: Alexei Khokhlov PI Email: ajk@oddjob.uchicago.edu Institution: The University of Chicago Allocation Program: INCITE Allocation Hours at ALCF: 130 Million Year: 2013 Research Domain: Chemistry Hydrogen is an abundant, environmentally friendly fuel with the potential

245

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

246

Anode reactive bleed and injector shift control strategy  

DOE Patents [OSTI]

A system and method for correcting a large fuel cell voltage spread for a split sub-stack fuel cell system. The system includes a hydrogen source that provides hydrogen to each split sub-stack and bleed valves for bleeding the anode side of the sub-stacks. The system also includes a voltage measuring device for measuring the voltage of each cell in the split sub-stacks. The system provides two levels for correcting a large stack voltage spread problem. The first level includes sending fresh hydrogen to the weak sub-stack well before a normal reactive bleed would occur, and the second level includes sending fresh hydrogen to the weak sub-stack and opening the bleed valve of the other sub-stack when the cell voltage spread is close to stack failure.

Cai, Jun [Rochester, NY; Chowdhury, Akbar [Pittsford, NY; Lerner, Seth E [Honeoye Falls, NY; Marley, William S [Rush, NY; Savage, David R [Rochester, NY; Leary, James K [Rochester, NY

2012-01-03T23:59:59.000Z

247

Properties of Reactive Oxygen Species by Quantum Monte Carlo  

E-Print Network [OSTI]

The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of Chemistry, Biology and Atmospheric Science. Nevertheless, the electronic structure of such species is a challenge for ab-initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as $N^3-N^4$, where $N$ is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

Andrea Zen; Bernhardt L. Trout; Leonardo Guidoni

2014-03-11T23:59:59.000Z

248

TRAVELING WAVES IN 2D REACTIVE BOUSSINESQ SYSTEMS WITH NO-SLIP BOUNDARY CONDITIONS  

E-Print Network [OSTI]

TRAVELING WAVES IN 2D REACTIVE BOUSSINESQ SYSTEMS WITH NO-SLIP BOUNDARY systems of reactive Boussinesq equations in two di* *men- sional strips that are not aligned Boussinesq systems with no-slip boundary conditions (the fluid flow vanishes at* * the boundary). Much

Constantin, Peter

249

Computational mapping reveals dramatic effect of Hoogsteen breathing on duplex DNA reactivity  

E-Print Network [OSTI]

Computational mapping reveals dramatic effect of Hoogsteen breathing on duplex DNA reactivity Formaldehyde has long been recognized as a haz- ardous environmental agent highly reactive with DNA. Recently-ray and nuclear magnetic resonance techniques for observing weakly specific interactions of small organic

Vajda, Sandor

250

Multicomponent reactive transport modeling at the Ratones uranium mine, Cceres (Spain)  

E-Print Network [OSTI]

Multicomponent reactive transport modeling at the Ratones uranium mine, Cáceres (Spain) Modelación management. The Ratones uranium mine was abandoned and flooded in 1974. Due to its reducing underground water, uranium, reactive transport, granite hydrochemistry, Ratones mine. Resumen La inundación de minas

Politècnica de Catalunya, Universitat

251

Monaco-A domain-specific language solution for reactive process control programming with hierarchical components  

Science Journals Connector (OSTI)

In this paper, we present Monaco - a domain-specific language for developing event-based, reactive process control programs - and its visual interactive programming environment. The main purpose of the language is to bring process control programming ... Keywords: Automation control, Component-based systems, Domain-specific languages, Reactive programming

Herbert Prhofer; Roland Schatz; Christian Wirth; Dominik Hurnaus; Hanspeter Mssenbck

2013-10-01T23:59:59.000Z

252

General Multiobjective Force Field Optimization Framework, with Application to Reactive Force Fields for Silicon Carbide  

E-Print Network [OSTI]

Fields for Silicon Carbide Andres Jaramillo-Botero,* Saber Naserifar, and William A. Goddard, III: (1) the ReaxFF reactive force field for modeling the adiabatic reactive dynamics of silicon carbide specific force field parameters for tripod metal templates, tripodMO(CO)3, using the root mean square

Goddard III, William A.

253

Intelligent Voltage and Reactive Power Control of Mini-Hydro Power Stations for Maximisation of Real  

E-Print Network [OSTI]

of a Mini-Hydro Power Generator to the Rural Grid The UK distribution network has been significantly exten1 Intelligent Voltage and Reactive Power Control of Mini-Hydro Power Stations for Maximisation Control (APFC) modes. The ability to export active and reactive power from mini-hydro power generators

Harrison, Gareth

254

Reactive Power Operation Analysis of a Single-Phase EV/PHEV Bidirectional Battery Charger  

E-Print Network [OSTI]

--More battery powered electric vehicles (EVs) and plug-in hybrid electric vehicles (PHEVs) will be introduced, charger, electric vehicle, EV, PHEV, reactive power, V2G. I. INTRODUCTION According to the international of the electric grid by supplying ancillary services such as reactive power compensation, voltage regulation

Tolbert, Leon M.

255

Reactive transport model for the ambient unsaturated hydrogeochemical system at Yucca mountain, Nevada  

Science Journals Connector (OSTI)

To assist a technical review of a potential application for a geologic repository, a reactive transport model is presented for the ambient hydrogeochemical system at Yucca Mountain (YM). The model simulates two-phase, nonisothermal, advective and diffusive ... Keywords: Yucca mountain, geochemistry, groundwater chemistry, groundwater flow and transport, hydrology, reactive transport model, unsaturated zone

Lauren Browning; William M. Murphy; Chandrika Manepally; Randall Fedors

2003-04-01T23:59:59.000Z

256

Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column  

E-Print Network [OSTI]

Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column distillation columns have been explored in many papers, very few papers have dealt with closed-loop control. Most of these control papers consider reactive distillation columns in which there is only one product

Al-Arfaj, Muhammad A.

257

Optical fibers by butyl methacrylate reactive extrusion Berthet Romuald, Chalamet Yvan, Taha Mohamed*, Zerroukhi Amar  

E-Print Network [OSTI]

limitations. Reactive extrusion experiments were carried out in a twin-screw extruder and the effect optical fibbers, polymethacrylate. Introduction Twin screw extruders are playing an increasing role of reactive extrusion is explained by the different advantages offered by the use of the twin-screw extruders

Paris-Sud XI, Université de

258

Study of STATCOM on Reactive Power Compensation Strategy of Wind Farm  

Science Journals Connector (OSTI)

For voltage stability problems caused by grid-connected wind farms, a strategy of coordinated reactive power compensation is proposed in this paper. The strategy utilizes static synchronous compensator (STATCOM) and doubly-fed induction generator (DFIG) ... Keywords: Reactive Power Compensation Strategy, STATCOM, DFIG, Wind Farm

Hui Li; Shucai Li; Hao Zhang; Weihua Bao

2013-12-01T23:59:59.000Z

259

Joint optimization algorithm for network reconfiguration and reactive power control of wind farm in distribution system  

Science Journals Connector (OSTI)

In recent years, the number of small size wind farms used as DG sources located within the distribution system are rapidly increasing. Wind farm made up with doubly fed induction generators (DFIG) is proposed in this paper as the continuous reactive ... Keywords: DFIG wind turbine, network reconfiguration, particle swarm optimization, reactive power control, wind farm

Jingjing Zhao; Xin Li; Jiping Lu; Congli Zhang

2009-02-01T23:59:59.000Z

260

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH  

E-Print Network [OSTI]

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH Ojwang' J.G.O.*, Rutger van is the fall in potential energy surface during heating. Keywords: hydrogen storage, reactive force field governing hydrogen desorption in NaH. During the abstraction process of surface molecular hydrogen charge

Goddard III, William A.

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Discovering Regulated Networks During HIV-1 Latency and Reactivation Sourav Bandyopadhyay, Ryan Kelley, and Trey Ideker  

E-Print Network [OSTI]

corresponding to stages of HIV synthesis. In the early stage, fully spliced mRNAs for Rev, Tat and NefDiscovering Regulated Networks During HIV-1 Latency and Reactivation Sourav Bandyopadhyay, Ryan NETWORKS DURING HIV-1 LATENCY AND REACTIVATION SOURAV BANDYOPADHYAY, RYAN KELLEY, TREY IDEKER1,2 1 Program

262

A gas-kinetic scheme for reactive ows Yongsheng Lian, Kun Xu*  

E-Print Network [OSTI]

A gas-kinetic scheme for reactive ¯ows Yongsheng Lian, Kun Xu* Department of Mathematics, Hong Kong in revised form 22 July 1999; accepted 22 July 1999 Abstract In this paper, the gas-kinetic BGK scheme for the compressible ¯ow equations is extended to chemical reactive ¯ow. The mass fraction of the unburnt gas

Xu, Kun

263

Reactivity during bench-scale combustion of biomass fuels for carbon capture and storage applications  

Science Journals Connector (OSTI)

Abstract Reactivities of four biomass samples were investigated in four combustion atmospheres using non-isothermal thermogravimetric analysis (TGA) under two heating rates. The chosen combustion atmospheres reflect carbon capture and storage (CCS) applications and include O 2 and CO 2 -enrichment. Application of the CoatsRedfern method assessed changes in reactivity. Reactivity varied due to heating rate: the reactivity of char oxidation was lower at higher heating rates while devolatilisation reactions were less affected. In general, and particularly at the higher heating rate, increasing [ O 2 ] increased combustion reactivity. A lesser effect was observed when substituting N 2 for CO 2 as the comburent; in unenriched conditions this tended to reduce char oxidation reactivity while in O 2 -enriched conditions the reactivity marginally increased. Combustion in a typical, dry oxyfuel environment (30% O 2 , 70% CO 2 ) was more reactive than in air in TGA experiments. These biomass results should interest researchers seeking to understand phenomena occurring in larger scale CCS-relevant experiments.

S. Pickard; S.S. Daood; M. Pourkashanian; W. Nimmo

2014-01-01T23:59:59.000Z

264

A Tariff for Reactive Power 0 100 200 300 400 500 600 700 800  

E-Print Network [OSTI]

to the distribution system economically by customers when new inverters are installed. The inverter would be supplied, and adjustable-speed motor drives. Index Terms--Inverter, Power Factor, Reactive Power, Tariff, Voltage efficiency. Reactive power is theoretically available from any inverter-based equipment such as photovoltaic

Pennycook, Steve

265

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials  

E-Print Network [OSTI]

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A and unpainted drywall as passive ozone control surfaces in a room-sized laboratory chamber. Mean deposition-50%, resulted in increased reactivity for activated carbon. In our model for a typical house, about 35

Siegel, Jeffrey

266

X-ray microtomography characterization of porosity, permeability and reactive surface changes during dissolution  

E-Print Network [OSTI]

X-ray microtomography characterization of porosity, permeability and reactive surface changes from X-ray microtomography data obtained before and after a set of dissolution experiments of pure.V. All rights reserved. Keywords: Reactive transport Carbon storage Permeability X-ray microtomography 1

Luquot, Linda

267

Compatibility Analysis on Existing Reactivity Devices in CANDU 6 Reactors for DUPIC Fuel Cycle  

SciTech Connect (OSTI)

The performance of reactivity devices for a Canada deuterium uranium (CANDU) 6 reactor loaded with Direct Use of Spent Pressurized Water Reactor Fuel In CANDU reactors (DUPIC) fuel is assessed. The reactivity devices studied are the zone controller units, the adjuster rods, and the mechanical control absorbers. For the zone controller system, the bulk reactivity control, spatial power control, and damping capability for spatial oscillation are investigated. For the adjusters, the xenon override, restart after a poison-out, shim operation, and power step-back capabilities are confirmed. The mechanical control absorber is assessed for the function of compensating temperature reactivity feedback following a power reduction. This study shows that the current reactivity device system of a CANDU 6 reactor is compatible with DUPIC fuel for normal and transient operations.

Jeong, Chang-Joon; Choi, Hangbok [Korea Atomic Energy Research Institute (Korea, Republic of)

2000-03-15T23:59:59.000Z

268

Reactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms  

Science Journals Connector (OSTI)

Reactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms ...

Jane. Browning; Keith R. Dixon; Robert W. Hilts

1989-02-01T23:59:59.000Z

269

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2-  

Open Energy Info (EERE)

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Project Type / Topic 1 Laboratory Call for Submission of Applications for Research, Development and Analysis of Geothermal Technologies Project Type / Topic 2 Tracers and Tracer Interpretation Project Description The concepts and theory behind the use of heat-sensitive tracers to study the thermal evolution of geothermal reservoirs was developed in the late 1980's under the Hot Dry Rock Project. Those studies described-conceptually and mathematically-the application of reactive tracers to tracking thermal fronts and to reservoir sizing. Later mathematical treatments focused on application of a single reactive tracer test to recover the temperature profile of a single streamtube. Previous tracer work has mainly focused on identifying conservative tracers. In these studies, chemicals that degraded at reservoir temperatures were discarded. Benzoic acids and dicarboxylic acids, which were found by Adams to degrade, may be useful as reactive tracers. Organic esters and amide tracers that undergo hydrolysis have been investigated and their use as reactive tracers appears feasible over a temperature range of 100ºC to 275ºC. However their reaction rates are pH dependent and sorption reactions have not been evaluated. While reactive tracer parameters have been measured in the lab, reactive tracers have not been extensively tested in the field. Thus, while reactive tracers appear to be a promising means of monitoring the thermal evolution of a geothermal reservoir, the concept has yet to be tested at the scale necessary for successful implementation, and tools for analyzing results of such tracer tests under the non-ideal conditions of an actual geothermal system have yet to be developed.

270

DOE/EA-1310: Environmental Assessment for Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Couples Fast Reactivity Measurements Facility at the Idaho National Engineering and Environmental Laboratory  

Broader source: Energy.gov (indexed) [DOE]

0 0 March 2000 Environmental Assessment for Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Coupled Fast Reactivity Measurements Facility at the Idaho National Engineering and Environmental Laboratory DOE/EA-1310 Environmental Assessment for Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Coupled Fast Reactivity Measurements Facility at the Idaho National Engineering and Environmental Laboratory Published March 2000 Prepared for the U.S. Department of Energy Idaho Operations Office iii CONTENTS ACRONYMS ............................................................................................................................... v HELPFUL INFORMATION ........................................................................................................

271

Understanding the stability and reactivity of ultrathin tellurium nanowires in solution: An emerging platform for chemical transformation and material design  

Science Journals Connector (OSTI)

The stability and reactivity of nanomaterials are of crucial importance for their application, but the long-term effects of stability and reactivity of nanomaterials under practical conditions are still not well ...

Liang Xu; Hai-Wei Liang; Hui-Hui Li; Kai Wang; Yuan Yang; Lu-Ting Song

2014-11-01T23:59:59.000Z

272

A conceptual design of a Reactive Ion Etch back end system for the direct reuse of process gases  

E-Print Network [OSTI]

The use of Plasma Etching, specifically Reactive Ion Etching (RIE), is a vital tool in manufacturing semiconductor devices. Most gases used in RIE processes were initially chosen because of their relatively low toxicity and reactivity. However, many...

Tiner, Paul Alan

2012-06-07T23:59:59.000Z

273

Final Report- Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support  

Broader source: Energy.gov [DOE]

Final Report - Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

274

Reactive gases evolved during pyrolysis of Devonian oil shale  

SciTech Connect (OSTI)

Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

1986-11-01T23:59:59.000Z

275

LX-17 Corner-Turning and Reactive Flow Failure  

SciTech Connect (OSTI)

We have performed a series of highly-instrumented experiments examining corner-turning of detonation. A TATB booster is inset 15 mm into LX-17 (92.5% TATB, 7.5% kel-F) so that the detonation must turn a right angle around an air well. An optical pin located at the edge of the TATB gives the start time of the corner-turn. The breakout time on the side and back edges is measured with streak cameras. Three high-resolution X-ray images were taken on each experiment to examine the details of the detonation. We have concluded that the detonation cannot turn the corner and subsequently fails, but the shock wave continues to propagate in the unreacted explosive, leaving behind a dead zone. The detonation front farther out from the corner slowly turns and eventually reaches the air well edge 180{sup o} from its original direction. The dead zone is stable and persists 7.7 {micro}s after the corner-turn, although it has drifted into the original air well area. Our regular reactive flow computer models sometimes show temporary failure but they recover quickly and are unable to model the dead zones. We present a failure model that cuts off the reaction rate below certain detonation velocities and reproduces the qualitative features of the corner-turning failure.

Souers, P C; Andreski, H; Cook III, C F; Garza, R; Pastrone, R; Phillips, D; Roeske, F; Vitello, P; Molitoris, J

2004-03-11T23:59:59.000Z

276

Installation of reactive metals groundwater collection and treatment systems  

SciTech Connect (OSTI)

Three groundwater plumes contaminated with volatile organic compounds (VOCs) and radionuclides at the Rocky Flats Environmental Technology Site are scheduled for remediation by 1999 based on the Rocky Flats Cleanup Agreement (RFCA) (DOE, 1996). These three plumes are among the top 20 environmental cleanup sites at Rocky Flats. One of these plumes, the Mound Site Plume, is derived from a previous drum storage area, and daylights as seeps near the South Walnut Creek drainage. Final design for remediation of the Mound Site Plume has been completed based on use of reactive metals to treat the contaminated groundwater, and construction is scheduled for early 1998. The two other plumes, the 903 Pad/Ryan`s Pit and the East Trenches Plumes, are derived from VOCs either from drums that leaked or that were disposed of in trenches. These two plumes are undergoing characterization and conceptual design in 1998 and construction is scheduled in 1999. The contaminants of concern in these plumes are tetrachloroethene, trichloroethene, carbon tetrachloride and low levels of uranium and americium.

Hopkins, J.K.; Primrose, A.L. [Rocky Mountain Remediation Services, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site; Vogan, J. [EnviroMetal Technologies, Inc., Guelph, Ontario (Canada); Uhland, J. [Kaiser-Hill, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site

1998-07-01T23:59:59.000Z

277

Reactivity initiated accident test series Test RIA 1-4  

SciTech Connect (OSTI)

The Reactivity Initiated Accident (RIA) Test RIA 1-4, the first 9-rod fuel rod bundle RIA Test to be performed at BWR hot startup conditions, was completed on April 16, 1980. The test was performed in the Power Burst Facility (PBF). Objective for Test RIA 1-4 was to provide information regarding loss-of-coolable fuel rod geometry following a RIA event for a peak fuel enthalpy equivalent to the present licensing criteria of 280 cal/g. The most severe RIA is the postulated Boiling Water Reactor (BWR) control rod drop during reactor startup. Therefore the test was conducted at BWR hot startup coolant conditions (538 K, 6.45 MPa, 0.8 1/sec). The test sequence began with steady power operation to condition the fuel, establish a short-lived fission product inventory, and calibrate the calorimetric measurements and core power chambers, neutron flux and gamma flux detectors. The test train was removed from the in-pile tube (IPT) to replace one of the fuel rods with a nominally identical irradiated rod and twelve flux wire monitors. A 2.8 ms period power burst was then performed. Coolant flow measurements were made before and after the power burst to characterize the flow blockage that occurred as a result of fuel rod failure.

Martinson, Z.R.; El-Genk, M.S.; Fukuda, S.K.; LaPointe, R.E.; Osetek, D.J.

1980-05-01T23:59:59.000Z

278

Etching radical controlled gas chopped deep reactive ion etching  

DOE Patents [OSTI]

A method for silicon micromachining techniques based on high aspect ratio reactive ion etching with gas chopping has been developed capable of producing essentially scallop-free, smooth, sidewall surfaces. The method uses precisely controlled, alternated (or chopped) gas flow of the etching and deposition gas precursors to produce a controllable sidewall passivation capable of high anisotropy. The dynamic control of sidewall passivation is achieved by carefully controlling fluorine radical presence with moderator gasses, such as CH.sub.4 and controlling the passivation rate and stoichiometry using a CF.sub.2 source. In this manner, sidewall polymer deposition thicknesses are very well controlled, reducing sidewall ripples to very small levels. By combining inductively coupled plasmas with controlled fluorocarbon chemistry, good control of vertical structures with very low sidewall roughness may be produced. Results show silicon features with an aspect ratio of 20:1 for 10 nm features with applicability to nano-applications in the sub-50 nm regime. By comparison, previous traditional gas chopping techniques have produced rippled or scalloped sidewalls in a range of 50 to 100 nm roughness.

Olynick, Deidre; Rangelow, Ivo; Chao, Weilun

2013-10-01T23:59:59.000Z

279

SSC analysis of the GEMs for reactivity control in PRISM  

SciTech Connect (OSTI)

The performance of three Gas Expansion Modules (GEMS) utilized the Advanced Liquid Metal Reactor (ALMR) concept, PRISM, was analyzed using the computer code, SSC. GE has submitted the PRISM design for a Preapplication Safety Evaluation Report (PSER). The draft PSER indicated a potential weakness in the Unscrammed Loss of Flow (ULOF) event, and GE modified the design by adding three GEMs. The PRISM design was analyzed by SSC for two cases. First, the design`s original response to a ULOF where one Electro Magnetic (EM) pump fails to produce a coastdown was analyzed. Then the revised design with the GEMs included was analyzed. The original design had little or no safety margin for this case. The peak fuel temperature in the hot channel was predicted to be 1358K, which is above the solidus temperature of the fuel. However, after the GEMs were added, the loss of one EM pump coastdown became a benign event. The GEM feedback was predicted by SSC to dominate the other reactivity feedbacks and the GEMS, essentially, responded like passive control rods. The fuel temperature quickly dropped below operating temperatures, while the margin to sodium boiling was predicted to be greater than 350K.

Slovik, G.C.; Rodnizki, J.

1992-12-31T23:59:59.000Z

280

SSC analysis of the GEMs for reactivity control in PRISM  

SciTech Connect (OSTI)

The performance of three Gas Expansion Modules (GEMS) utilized the Advanced Liquid Metal Reactor (ALMR) concept, PRISM, was analyzed using the computer code, SSC. GE has submitted the PRISM design for a Preapplication Safety Evaluation Report (PSER). The draft PSER indicated a potential weakness in the Unscrammed Loss of Flow (ULOF) event, and GE modified the design by adding three GEMs. The PRISM design was analyzed by SSC for two cases. First, the design's original response to a ULOF where one Electro Magnetic (EM) pump fails to produce a coastdown was analyzed. Then the revised design with the GEMs included was analyzed. The original design had little or no safety margin for this case. The peak fuel temperature in the hot channel was predicted to be 1358K, which is above the solidus temperature of the fuel. However, after the GEMs were added, the loss of one EM pump coastdown became a benign event. The GEM feedback was predicted by SSC to dominate the other reactivity feedbacks and the GEMS, essentially, responded like passive control rods. The fuel temperature quickly dropped below operating temperatures, while the margin to sodium boiling was predicted to be greater than 350K.

Slovik, G.C.; Rodnizki, J.

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Reactivity of iron-bearing minerals and CO2 sequestration: A multi-disciplinary experimental approach  

SciTech Connect (OSTI)

The reactivity of sandstones was studied under conditions relevant to the injection of supercritical carbon dioxide in the context of carbon geosequestration. The emphasis of the study was on the reactivity of iron-bearing minerals when exposed to supercritical CO2 (scCO2) and scCO2 with commingled aqueous solutions containing H2S and/or SO2. Flow through and batch experiments were conducted. Results indicate that sandstones, irrespective of their mineralogy, are not reactive when exposed to pure scCO2 or scCO2 with commingled aqueous solutions containing H2S and/or SO2 under conditions simulating the environment near the injection point (flow through experiments). However, sandstones are reactive under conditions simulating the edge of the injected CO2 plume or ahead of the plume (batch experiments). Sandstones containing hematite (red sandstone) are particularly reactive. The composition of the reaction products is strongly dependent on the composition of the aqueous phase. The presence of dissolved sulfide leads to the conversion of hematite into pyrite and siderite. The relative amount of the pyrite and siderite is influenced by the ionic strength of the solution. Little reactivity is observed when sulfite is present in the aqueous phase. Sandstones without hematite (grey sandstones) show little reactivity regardless of the solution composition.

Schoonen, Martin A. [Stony Brook University] (ORCID:0000000271331160)

2014-12-22T23:59:59.000Z

282

Reactivity of low-valent nickel-1,3-BIS (o-Diphenylphosphinophenylthio) propane (arom-PSSP) with small molecules  

E-Print Network [OSTI]

The reactivity of NiO(arom-PSSP) with small molecules was studied in comparison to the reactivity of NIO(PSSP) which was studied by previous members of our group. The low-valent nickel atom in this arom-PSSP ligand exhibited reactivity toward small...

Kang, Jeehee

2012-06-07T23:59:59.000Z

283

Mechanical models of fracture reactivation and slip on bedding surfaces during folding of the asymmetric anticline at Sheep Mountain, Wyoming  

E-Print Network [OSTI]

Mechanical models of fracture reactivation and slip on bedding surfaces during folding June 2008 Accepted 5 June 2008 Available online 13 June 2008 Keywords: Fold Fracture reactivation Bed methods to investigate the reactivation of fractures (opening and shearing) and the development of bedding

Borja, Ronaldo I.

284

Reactivation of the HZSM-5 zeolite-based catalyst used in the MTG process  

SciTech Connect (OSTI)

The recovery of the acidic structure and activity during the regeneration step by coke combustion of an HZSM-5 zeolite-based catalyst used in the methanol-to-gasoline (MTG) process in reaction-regeneration cycles was studied. The reactivation kinetics (activity vs. coke combustion time) was determined as a function of temperature and time on stream of the reaction step. The validity of the reactivation kinetic model was proven by using it for the simulation of the cyclic operation under conditions of catalyst partial reactivation, together with the kinetic model for the MTG process.

Gayubo, A.G.; Aguayo, A.T.; Benito, P.L.; Landeta, A.; Castilla, M.; Bilbao, J. [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica] [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica

1997-06-01T23:59:59.000Z

285

Kinetics and mechanisms of reactions involving small aromatic reactive intermediates  

SciTech Connect (OSTI)

Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

Lin, M.C. [Emory Univ., Atlanta, GA (United States)

1993-12-01T23:59:59.000Z

286

Reactive Transport Modeling of Acid Gas Generation and Condensation  

SciTech Connect (OSTI)

Pulvirenti et al. (2004) recently conducted a laboratory evaporation/condensation experiment on a synthetic solution of primarily calcium chloride. This solution represents one potential type of evaporated pore water at Yucca Mountain, Nevada, a site proposed for geologic storage of high-level nuclear waste. These authors reported that boiling this solution to near dryness (a concentration factor >75,000 relative to actual pore waters) leads to the generation of acid condensate (pH 4.5) presumably due to volatilization of HCl (and minor HF and/or HNO{sub 3}). To investigate the various processes taking place, including boiling, gas transport, and condensation, their experiment was simulated by modifying an existing multicomponent and multiphase reactive transport code (TOUGHREACT). This code was extended with a Pitzer ion-interaction model to deal with high ionic strength. The model of the experiment was set-up to capture the observed increase in boiling temperature (143 C at {approx}1 bar) resulting from high concentrations of dissolved salts (up to 8 m CaCl{sub 2}). The computed HCI fugacity ({approx} 10{sup -4} bars) generated by boiling under these conditions is not sufficient to lower the pH of the condensate (cooled to 80 and 25 C) down to observed values unless the H{sub 2}O mass fraction in gas is reduced below {approx}10%. This is because the condensate becomes progressively diluted by H{sub 2}O gas condensation. However, when the system is modeled to remove water vapor, the computed pH of instantaneous condensates decreases to {approx}1.7, consistent with the experiment (Figure 1). The results also show that the HCl fugacity increases, and calcite, gypsum, sylvite, halite, MgCl{sub 2}4H{sub 2}O and CaCl{sub 2} precipitate sequentially with increasing concentration factors.

G. Zhahg; N. Spycher; E. Sonnenthal; C. Steefel

2005-01-25T23:59:59.000Z

287

Assessment of reactivity transient experiments with high burnup fuel  

SciTech Connect (OSTI)

A few recent experiments aimed at determining the response of high-burnup LWR fuel during a reactivity initiated accident (RIA) have raised concerns that existing failure criteria may be inappropriate for such fuel. In particular, three experiments (SPERT CDC-859, NSRR HBO-1 and CABRI REP Na-1) appear to have resulted in fuel failures at only a fraction of the anticipated enthalpy levels. In evaluating the results of such RIA simulation experiments, however, it is necessary that the following two key considerations be taken into account: (1) Are the experiments representative of conditions that LWR fuel would experience during an in-reactor RIA event? (2) Is the fuel that is being utilized in the tests representative of the present (or anticipated) population of LWR fuel? Conducting experiments under conditions that can not occur in-reactor can trigger response modes that could not take place during in-reactor operation. Similarly, using unrepresentative fuel samples for the tests will produce failure information that is of limited relevance to commercial LWR fuel. This is particularly important for high-burnup fuel since the manner under which the test samples are base-irradiated prior to the test will impact the mechanical properties of the cladding and will therefore affect the RIA response. A good example of this effect can be seen in the results of the SPERT CDC-859 test and in the NSRR JM-4 and JM-5 tests. The conditions under which the fuel used for these tests was fabricated and/or base-irradiated prior to the RIA pulse resulted in the formation of multiple cladding defects in the form of hydride blisters. When this fuel was subjected to the RIA power pulse, it failed by developing multiple cracks that were closely correlated with the locations of the pre-existing hydride blisters. In the case of the JM tests, many of the cracks formed within the blisters themselves and did not propagate beyond the heavily hydrided regions.

Ozer, O.; Yang, R.L.; Rashid, Y.R.; Montgomery, R.O.

1996-03-01T23:59:59.000Z

288

Photoconductivity in reactively evaporated copper indium selenide thin films  

SciTech Connect (OSTI)

Copper indium selenide thin films of composition CuInSe{sub 2} with thickness of the order of 130 nm are deposited on glass substrate at a temperature of 423 5 K and pressure of 10{sup ?5} mbar using reactive evaporation, a variant of Gunther's three temperature method with high purity Copper (99.999%), Indium (99.999%) and Selenium (99.99%) as the elemental starting materials. X-ray diffraction (XRD) studies shows that the films are polycrystalline in nature having preferred orientation of grains along the (112) plane. The structural type of the film is found to be tetragonal with particle size of the order of 32 nm. The structural parameters such as lattice constant, particle size, dislocation density, number of crystallites per unit area and strain in the film are also evaluated. The surface morphology of CuInSe{sub 2} films are studied using 2D and 3D atomic force microscopy to estimate the grain size and surface roughness respectively. Analysis of the absorption spectrum of the film recorded using UV-Vis-NIR Spectrophotometer in the wavelength range from 2500 nm to cutoff revealed that the film possess a direct allowed transition with a band gap of 1.05 eV and a high value of absorption coefficient (?) of 10{sup 6} cm{sup ?1} at 570 nm. Photoconductivity at room temperature is measured after illuminating the film with an FSH lamp (82 V, 300 W). Optical absorption studies in conjunction with the good photoconductivity of the prepared p-type CuInSe{sub 2} thin films indicate its suitability in photovoltaic applications.

Urmila, K. S., E-mail: urmilaks7@gmail.com; Asokan, T. Namitha, E-mail: urmilaks7@gmail.com; Pradeep, B., E-mail: urmilaks7@gmail.com [Solid State Physics Laboratory, Cochin University of Science and Technology, Kochi, Kerala (India); Jacob, Rajani; Philip, Rachel Reena [Thin Film Research Laboratory, Union Christian College, Aluva, Kerala (India)

2014-01-28T23:59:59.000Z

289

Detector response in a CANDU low void reactivity core  

SciTech Connect (OSTI)

The response of the in-core flux detectors to the CANFLEX Low-Void-Reactivity Fuel (LVRF) [1] bundles for use in the CANDU reactor at Bruce nuclear generation station has been studied. The study was based on 2 detector types - platinum (Pt)-clad Inconel and pure Inconel detectors, and 2 fuel types - LVRF bundles and natural-uranium (NU) bundles. Both detectors show a decrease of thermal-neutron-flux to total-photon-flux ratio when NU fuel bundles are replaced by LVRF bundles in the reactor core (7% for Inconel and 9% for Pt-clad detectors). The ratio of the prompt component of the net electron current to the total net electron current (PFe) of the detectors however shows a different response. The use of LVRF bundles in place of NU fuel bundles in the reactor core did not change the PFe of the Pt-clad Inconel detector but increased the PFe of the pure Inconel detector by less than 2%. The study shows that the Inconel detector has a larger prompt-detector response than that of the platinum-clad detector; it reacts to the change of fluxes in the reactor core more readily. On the other hand, the Pt-clad detector is less sensitive to perturbations of the neutron-to-gamma ratio. Nevertheless the changes in an absolute sense are minimal; one does not anticipate a change of the flux-monitoring system if the NU fuel bundles are replaced with the CANFLEX LVRF bundles in the core of the Bruce nuclear generating station. (authors)

Tsang, K. T. [Atomic Energy of Canada Limited, 2251 Speakman Drive, Mississauga, Ont. L5K 1B2 (Canada)

2006-07-01T23:59:59.000Z

290

Reactive ion etching: Optimized diamond membrane fabrication for transmission electron microscopy  

E-Print Network [OSTI]

Commonly used preparation method for thin diamond membranes by focused ion beam (FIB) techniques results in surface damage. Here, the authors introduce an alternative method based on reactive ion etching (RIE). To compare ...

Li, Luozhou

291

In-Cylinder Mechanisms of PCI Heat-Release Rate Control by Fuel Reactivity Stratification  

Broader source: Energy.gov [DOE]

Explores in-cylinder mechanisms by which fuel reactivity stratification via a two fuel system affects premixed charge compression ignition heat release rate to achieve diesel-like efficiency

292

E-Print Network 3.0 - automatic reactive power Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

power Page: << < 1 2 3 4 5 > >> 1 Power control of a wind farm with active stall wind turbines and AC grid connection Summary: , reactive power control and automatic voltage...

293

A review of international cases of fault reactivation during mining subsidence and fluid abstraction  

Science Journals Connector (OSTI)

...reactivation, during coal mining subsidence, has been...intrusion at a longwall coal mine in Appalachia. 22nd International...on Ground Control in Mining, Morgantown, West Virginia...Muller, R.A. 1986. Coal mining under gas pipelines...

L.J. Donnelly

294

Integration of reactive polymeric nanofilms into a low-power electromechanical switch for selective chemical sensing  

E-Print Network [OSTI]

This paper presents the fabrication and demonstration of an ultrathin microelectromechanical chemical sensing device. Microcantilevers are etched from 100-nm-thick silicon nitride, and a 75-nm-thick reactive copolymer film ...

Arora, William J.

295

Fuzzy Control on Voltage/Reactive Power in Electric Power Substation  

Science Journals Connector (OSTI)

A fuzzy method using in voltage and reactive power control in electric substation is proposed based on the improved 17 ... times at the tap positions of transformers in substation are much less than usual. So,...

Xiu-hua Wu; Jun-cheng Wang; Ping Yang

2009-01-01T23:59:59.000Z

296

Influence of calcite on uranium(VI) reactive transport in the groundwaterriver mixing zone  

SciTech Connect (OSTI)

Calcite is an important mineral that can affect uranyl reactive transport in subsurface sediments. This study investigated the distribution of calcite and its influence on uranyl adsorption and reactive transport in the groundwater-river mixing zone at US Hanford 300A, Washington State. Simulations using a 2D reactive transport model under field-relevant hydrogeochemical conditions revealed a complex distribution of calcite concentration as a result of dynamic groundwater-river interactions. The calcite concentration distribution in turn affected the spatial and temporal changes in aqueous carbonate, calcium, and pH, which subsequently influenced U(VI) mobility and discharge rates into the river. The results implied that calcite distribution and its concentration dynamics is an important consideration for field characterization, monitoring, and reactive transport prediction.

Ma, Rui; Liu, Chongxuan; Greskowiak, Janek; Prommer, Henning; Zachara, John M.; Zheng, Chunmiao

2014-01-23T23:59:59.000Z

297

The reactive metabolite target protein database (TPDB) a web-accessible resource  

E-Print Network [OSTI]

Background The toxic effects of many simple organic compounds stem from their biotransformation to chemically reactive metabolites which bind covalently to cellular proteins. To understand the mechanisms of cytotoxic ...

Hanzlik, Robert P.; Koen, Yakov M.; Theertham, Bhargav; Dong, Yinghua; Fang, Jianwen

2007-03-16T23:59:59.000Z

298

Using a DFIG-based wind farm for grid node reactive power compensation  

Science Journals Connector (OSTI)

Grid nodes voltages are not allowed to deviate excessively from nominal value. Appropriate measures should be taken to prevent such a deviation. The voltage difference between two nodes is strongly affected by reactive power flow. In contrast to frequency control, node voltage control must be achieved locally. This article investigates the use of a wind farm based on a doubly fed induction generators (DFIG) for reactive power compensation of a grid node. A wind speed variation sample is applied to the model of a wind power unit. The power flow between the stator of the DFIG-based wind power unit and the grid is controlled by using the decoupled active and reactive power vector control method. The limits or capacity of the stator and power converters to consume or provide reactive power are discussed. SIMULINK software has been used for the simulation of the system.

Mohamed Kesraoui; Ahmed Chaib; Abdullah Madri; Bilal Hammani

2013-01-01T23:59:59.000Z

299

Reactive Point Processes: A New Approach to Predicting Power Failures in Underground Electrical Systems  

E-Print Network [OSTI]

Reactive point processes (RPPs) are a new statistical model designed for predicting discrete events, incorporating self-exciting, self-regulating, and saturating components. The self-excitement occurs as a result of a ...

Ertekin, Seyda

2013-09-26T23:59:59.000Z

300

Isolation of tube precipitin antibody-reactive fractions of Coccidioides immitis.  

Science Journals Connector (OSTI)

...humoral response has been detected by tube precipitin (TP) and immunodiffusion (ID)-TP assays of patient sera, which are valuable aids...antigenic fractions which show reactivity with patient TP antibody have been published. However, confusion...

D Kruse; G T Cole

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Hydrogen storage properties of Mg-based mixtures elaborated by reactive mechanical grinding  

Science Journals Connector (OSTI)

The hydrogen sorption properties of Mg + 10 wt% WO3 and Mg + 5 wt% Cr2O3 mixtures made by reactive (under hydrogen) mechanical grinding were studied and compared with those of elemental Mg subjected to a similar ...

J.-L. Bobet; B. Chevalier

2004-08-01T23:59:59.000Z

302

Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel  

DOE Patents [OSTI]

Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

Herrmann, Steven Douglas

2014-05-27T23:59:59.000Z

303

Distribution of dendritic reticulum cells in follicular lymphoma and reactive hyperplasia  

Science Journals Connector (OSTI)

Reactive and neoplastic follicles in lymph nodes showing changes of (1) follicular hyperplasia and (2) follicular lymphoma were examined for the presence of dendritic reticulum cells (DRC). These cells could b...

J. P. J. Peters; L. H. P. M. Rademakers; J. M. M. Roelofs; D. de Jong

1984-01-01T23:59:59.000Z

304

Synthesis, characterization, and reactivity of pentamethylcyclopentadienyl complexes of divalent cobalt and nickel  

SciTech Connect (OSTI)

The thesis is divided into the following 4 chapters: synthesis, characterization, and reactivity of trinuclear pentamethylcyclopentadienyl cobalt and nickel clusters with triply-bridging methylidyne groups; chemical and physical properties of pentamethylcyclopentadienyl acetylacetonate complexes of Co(II) and Ni(II); synthesis, characterization, and reactivity of pentamethylcyclopentadienyl halide complexes of Co and Ni; and crystallographic studies of distortions in metallocenes with C{sub 5}-symmetrical cyclopentadienyl rings.

Smith, M.E.

1993-10-01T23:59:59.000Z

305

Calculation of the reactivity feedback due to core-assembly bowing in LMFBRs  

SciTech Connect (OSTI)

The nonuniformity of the temperature distribution in an LMFBR leads to differential thermal expansion of the walls of an assembly hexcan. These thermal expansion differentials cause the hexcan to distort or bow. Consequentially, the assembly experiences a spatial displacement, which results in a change in reactivity for the core. A computational model to calculate the reactivity feedback due to material displacements induced by assembly bowing effects has been developed.

Not Available

1983-01-01T23:59:59.000Z

306

The effect of pulse reactivity for stochastic neutron point kinetic equation in nuclear reactor dynamics  

Science Journals Connector (OSTI)

In this present analysis, the numerical simulation methods are applied to calculate the solution for Stochastic Neutron Point Kinetic Equations (SNPKE) with pulse reactivity in dynamical system of a nuclear reactor. The resulting systems of differential equations are solved for each time step-size. Using experimental data, the methods are investigated with pulse reactivity. The computational results designate that these numerical approximation methods are straightforward, effective and easy for solving stochastic point kinetic equations.

A. Patra; S. Saha Ray

2014-01-01T23:59:59.000Z

307

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity  

Science Journals Connector (OSTI)

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity ... However, smaller internal rates inside the column that result from lower reboiler and condenser duty could increase the potential risk of flooding in the column and reduce the availability of reactants in the reactive section. ... Column simulations performed using both Pro/II and SpeedUp showed excellent agreement with previously published exptl. ...

Budi H. Bisowarno; Moses O. Tad

2000-05-09T23:59:59.000Z

308

Flash Pyrolysis of Biomass with Reactive and Non-Reactive Gases: Summary Report for Period July 1983 through September 1984  

SciTech Connect (OSTI)

The purpose of this program is to study the conversion of biomass to liquid and gaseous hydrocarbon fuels and chemical feedstocks by a flash or rapid pyrolysis technique. During this period of study pine wood was flash pyrolyzed in atmospheres of methane and helium at a pressure of 50 psi and at temperatures up to 1050 C. The 1-inch I.D. entrained downflow tubular reactor was used in these experiments. Product yields of methane, ethane, ethylene, BTX, carbon monoxide and carbon dioxide were determined as a function of temperature and gas to wood ratio. Of particular interest were the ethylene and BTX yields. These represented as much as 29.6% and 24.6% of the carbon contained in the feed wood respectively when flash pyrolyzing in methane (flash methanolysls) and 14.7% and 9.7% when pyrolyzing in helium. In the case of flash methanolysis of wood the yields of ethylene and benzene increased with increasing methane to wood feed ratios. In the case of flash pyrolysis in helium the yields of ethylene and BTX decreased with increasing helium gas to wood feed ratios. These results indicate a mechanism by which a free radical reactive species originating from the wood interacts with the methane pyrolyzing gas to produce an enhanced yield of ethylene and benzene. The flash methanolysis of lignin extract from wood produced lower yields of ethylene, indicating the yields mainly originate from the cellulosic fractions of the wood. Some work was also performed on substituting wood ash for sillca flour (Cab-O-Sil) to allow free flow of wood particles through the entrained flow reactor. Preliminary process design and analysis indicates an economically competitive process for the flash methanolysis of wood for the production of methanol, benzene and ethylene. Future plans include completing the studies on obtaining the process chemistry of the flash methanolysis of woods, to obtain a better understanding of the enhanced ethylene and benzene yield and to investigate other biomass forms.

Steinberg M.; Fallon, P.T.; Sundaram, M.S.

1984-10-01T23:59:59.000Z

309

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure Modes from Reactive Dynamics  

E-Print Network [OSTI]

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure: Ettringite is a hexacalcium aluminate trisulfate hydrate mineral that forms during Portland cement hydration of ettringite at the atomic scale. The ReaxFF force field was validated by comparing the lattice parameters

Goddard III, William A.

310

AMPERE 2011, Toulouse Modeling -372 An Iterative Routine for Macroscopic Modeling of  

E-Print Network [OSTI]

. The developed approach involves two software packages: QuickWave-3D, a simulator that uses the conformal finite for energy savings and faster processing of ceramic and metallic powders. The main benefit in comparison. This paper addresses the problem of numerical simulation of micro- wave sintering at a macroscopic scale

Yakovlev, Vadim

311

Power-One produces the industry's broadest selection of linear power supplies with output voltages from 5 volts through 250 volts. Rugged  

E-Print Network [OSTI]

-A 5V @ 9A (Note 1,5) N 5V HD5-12/OVP-A 5V @ 12A (Note 1,5) D HE5-18/OVP-A 5V @ 18A (Note 1,5) E F5 regulatory standards, and is CE Marked to the Low Voltage Directive (LVD). INTERNATIONAL SERIES LINEARS marked to Low Voltage Directive · 100% Burn-In · 2 Year Warranty · Overvoltage Protection (OVP) Standard

Berns, Hans-Gerd

312

Reactive power interconnection requirements for PV and wind plants : recommendations to NERC.  

SciTech Connect (OSTI)

Voltage on the North American bulk system is normally regulated by synchronous generators, which typically are provided with voltage schedules by transmission system operators. In the past, variable generation plants were considered very small relative to conventional generating units, and were characteristically either induction generator (wind) or line-commutated inverters (photovoltaic) that have no inherent voltage regulation capability. However, the growing level of penetration of non-traditional renewable generation - especially wind and solar - has led to the need for renewable generation to contribute more significantly to power system voltage control and reactive power capacity. Modern wind-turbine generators, and increasingly PV inverters as well, have considerable dynamic reactive power capability, which can be further enhanced with other reactive support equipment at the plant level to meet interconnection requirements. This report contains a set of recommendations to the North-America Electricity Reliability Corporation (NERC) as part of Task 1-3 (interconnection requirements) of the Integration of Variable Generation Task Force (IVGTF) work plan. The report discusses reactive capability of different generator technologies, reviews existing reactive power standards, and provides specific recommendations to improve existing interconnection standards.

McDowell, Jason (General Electric, Schenectady, NY); Walling, Reigh (General Electric, Schenectady, NY); Peter, William (SunPower, Richmond, CA); Von Engeln, Edi (NV Energy, Reno, NV); Seymour, Eric (AEI, Fort Collins, CO); Nelson, Robert (Siemens Wind Turbines, Orlando, FL); Casey, Leo (Satcon, Boston, MA); Ellis, Abraham; Barker, Chris. (SunPower, Richmond, CA)

2012-02-01T23:59:59.000Z

313

Reactivity measurements of SiC for accident-tolerant fuel  

Science Journals Connector (OSTI)

Abstract Silicon carbide (SiC) is a candidate structural material for application with accident-tolerant fuel for light water reactors, which is expected to decrease heat and hydrogen generation resulting from oxidation reaction with high-temperature steam. Although there are studies on irradiation properties of SiC for fusion reactors and gas-cooled reactors, there are no published reports on critical experiments to validate the nuclear reactivity of SiC. We performed SiC nuclear reactivity measurements. Measured reactivity worths of SiC were analyzed by a continuous-energy Monte Carlo code MCNP4c3. We obtained the neutron spectrum-dependent reactivity worths of SiC samples, which imply that the neutron scattering with SiC plays an important role concerning the reactivity worths as well as neutron absorption with SiC. Comparison of analyses with measurements reveals the possibility of room for improvement in SiC cross-sections mainly related to neutron scattering, whereas thermal neutron absorption cross-sections of SiC can well describe the experimental results.

Hiroshi Matsumiya; Kenichi Yoshioka; Tsukasa Kikuchi; Tsukasa Sugita; Shinichi Higuchi; Noriyuki Yoshida

2014-01-01T23:59:59.000Z

314

The effect of core configuration on temperature coefficient of reactivity in IRR-1  

SciTech Connect (OSTI)

Experiments designed to measure the effect of coolant moderator temperature on core reactivity in an HEU swimming pool type reactor were performed. The moderator temperature coefficient of reactivity ({alpha}{sub {omega}}) was obtained and found to be different in two core loadings. The measured {alpha}{sub {omega}} of one core loading was {minus}13 pcm/{degrees}C at the temperature range of 23-30{degrees}C. This value of {alpha}{sub {omega}} is comparable to the data published by the IAEA. The {alpha}{sub {omega}} measured in the second core loading was found to be {minus}8 pcm/{degrees}C at the same temperature range. Another phenomenon considered in this study is core behavior during reactivity insertion transient. The results were compared to a core simulation using the Dynamic Simulator for Nuclear Power Plants. It was found that in the second core loading factors other than the moderator temperature influence the core reactivity more than expected. These effects proved to be extremely dependent on core configuration and may in certain core loadings render the reactor`s reactivity coefficient undesirable.

Bettan, M.; Silverman, I.; Shapira, M.; Nagler, A. [Soreq Nuclear Research Center, Yavne (Israel)

1997-08-01T23:59:59.000Z

315

Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. This project aims to develop reactive tracer method for monitoring thermal drawdown in enhanced geothermal systems.

316

Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporations Caon City, Colorado, Uranium Mill  

Broader source: Energy.gov [DOE]

Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporations Canon City, Colorado, Uranium Mill (April 2005)

317

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials: Preliminary Results and  

E-Print Network [OSTI]

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials air quality. #12;Proceedings of Healthy Buildings 2009 Paper 141 Removing ozone from indoor

Siegel, Jeffrey

318

ORNL/CP-97155 Instantaneous Reactive Power and Power Factor of  

Office of Scientific and Technical Information (OSTI)

ORNL/CP-97155 ORNL/CP-97155 Instantaneous Reactive Power and Power Factor of Instantaneous Phasor s ' 4 . L;/, Oak Ridge National Laboratory* P f Senior Member &Eb "'ii Lf/ .. John S. Hsu 4- p d Post Office Box 2009, MS 8038 Oak Ridge, Tennessee 3783 1-8038 Key wordr: Instantaneous reactive power, Symmetrical property, Instantaiteous phasors, Phasors of one phase, n r e e phases. Abstract The unique property of instantaneous phasors is that at any instant the instantaneous three-phase currents and voltages can be represented by a set of balanced phasors. The instantaneous reactive power and the concept of instantaneous power factor can be clearly understood from the instantaneous phasors. This provides a theoretical foundation for power quality monitoring, diagnostics,

319

Impact of exhaust gas recirculation (EGR) on the oxidative reactivity of diesel engine soot  

SciTech Connect (OSTI)

This paper expands the consideration of the factors affecting the nanostructure and oxidative reactivity of diesel soot to include the impact of exhaust gas recirculation (EGR). Past work showed that soot derived from oxygenated fuels such as biodiesel carries some surface oxygen functionality and thereby possesses higher reactivity than soot from conventional diesel fuel. In this work, results show that EGR exerts a strong influence on the physical properties of the soot which leads to enhanced oxidation rate. HRTEM images showed a dramatic difference between the burning modes of the soot generated under 0 and 20% EGR. The soot produced under 0% EGR strictly followed an external burning mode with no evidence of internal burning. In contrast, soot generated under 20% EGR exhibited dual burning modes: slow external burning and rapid internal burning. The results demonstrate clearly that highly reactive soot can be achieved by manipulating the physical properties of the soot via EGR. (author)

Al-Qurashi, Khalid; Boehman, Andre L. [The EMS Energy Institute, The Pennsylvania State University, 405 Academic Activities Bldg., University Park, PA 16802 (United States)

2008-12-15T23:59:59.000Z

320

Stability analysis and reactive power compensation issue in a microgrid with a DFIG based WECS  

Science Journals Connector (OSTI)

Abstract This paper presents a novel methodology for compensating reactive power in a microgrid, having a DFIG based winddiesel system, to enhance the voltage stability of the hybrid system. UPFC as a FACTS device is proposed in order to improve the control of reactive power mismatch and the stability of the system. A small signal model of the winddiesel system, DFIG based wind turbine system, UPFC and the controllers are designed for the stability analysis. Further, the voltage variation and reactive power compensation is analysed with the incorporation of proposed ANFIS based UPFC controller. Simulations are performed in MATLAB environment for transient stability analysis in a winddiesel based microgrid with different wind power input and 2% step increase in load demand. Simulation results illustrate the efficiency and effectiveness of the proposed approach and its impact upon transient behaviour of the microgrid.

Asit Mohanty; Meera Viswavandya; Prakash K. Ray; Sandipan Patra

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Validation of ATR SINDA using SPERT-3 reactivity-initiated transient test data  

SciTech Connect (OSTI)

Thermal-hydraulic analyses of Special Power Excursion Reactor Test-3 (SPERT-3) reactivity-initiated accident (RIA) test data are presented to validate ATR SINDA, a three-dimensional thermal-hydraulic computer code used to conduct transient analysis of Advanced Test Reactor (ATR) fuel plates. Because SPERT-3-C core test results are the only existing data of reactivity insertions for plate-type reactors, validating ATR SINDA is important for safety analysis of postulated reactivity initiated accidents (RIAs) for the plate-type ATR operated at the Idaho National Engineering Laboratory (INEL). The SPERT-3 facility was designed to study the kinetic behavior and safety of pressurized, light water-moderated reactors.

Oh, C.H.; Ambrosek, R.G.; Wadkins, R.P. (Idaho National Engineering Lab., Idaho Falls (United States))

1991-01-01T23:59:59.000Z

322

Estimates of axial leakage and void reactivity in a CANDU reactor  

SciTech Connect (OSTI)

Estimating the axial leakage in a Canada deuterium uranium (CANDU) fuel channel has been of ongoing interest because of the perceived significance of this parameter to an accurate calculation of the void effect. To verify the accuracy of such estimates, a benchmark-quality calculation of void reactivity in a standard CANDU fuel channel has been performed using the Monte Carlo code MCNP4. The result of a similar calculation for an infinite lattice of 37-element CANDU fuel bundles has been reported elsewhere. In this paper, estimates of reactivity and reactivity difference for two different arrangements of 37-element fresh CANDU fuel at both operating and voided conditions in the presence of axial leakage are discussed. It is emphasized that these results are valid for a highly idealized reactor model and cannot be directly applied to an operating reactor.

Milgram, M.S. (Atomic Energy of Canada Ltd., Ontario (Canada))

1993-01-01T23:59:59.000Z

323

Reactive Deposition of Silicon Nanowires Templated on a Stepped Nickel Surface Yi Wang and S. J. Sibener*  

E-Print Network [OSTI]

The initial stages of disilane Si2H6 reactive deposition on Ni(977) to form silicon nanowires have been examined using scanning tunneling microscopy. The effects of disilane exposure and dosing rate by reactive deposition of disilane (Si2H6) on Ni(977). At low dosing exposures, Si2H6 decomposes

Sibener, Steven

324

Aggregation and Reactivity of Phenyllithium Solutions Hans J. Reich,* D. Patrick Green, Marco A. Medina, Wayne S. Goldenberg,  

E-Print Network [OSTI]

Aggregation and Reactivity of Phenyllithium Solutions Hans J. Reich,* D. Patrick Green, Marco A of donor solvents in altering the reactivity of organolithium reagents have been empirically useful solvents used for organolithium reagents such as ether and THF, so pure crystalline material can

Reich, Hans J.

325

CHARACTERIZATION OF THE STRUCTURE AND REACTIVITY OF A NICKEL(II)-TRIPEPTIDE MIMIC OF NICKEL SUPEROXIDE DISMUTASE  

E-Print Network [OSTI]

. However, prior to this work, the structure and chemical reactivity of the nickel-peptide complex were undefined. The work presented herein involves structural and reactivity investigations of the MAP-tag bound with NiII in the dianionic complex [Ni-NCC]2...

Glass, Amanda M.

2012-08-31T23:59:59.000Z

326

The Effect of Loading on Reactive Market Power Antonio C. Zambroni de Souza Fernando Alvarado Mevludin Glavic  

E-Print Network [OSTI]

that are supposed to be competing in the deregulated energy market. Reactive power supplies can make some particularThe Effect of Loading on Reactive Market Power Antonio C. Zambroni de Souza Fernando Alvarado@engr.wisc.edu glavic@untz.ba Abstract The degree of market power (more precisely, the potential for market power

327

Spatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic composition of atmospheric nitrate  

E-Print Network [OSTI]

exchange between gas-phase precursors and variability in reactive nitrogen sources. These findings product of NOx in the atmosphere. Due to its exceptionally high solubility in water, nitrate is rapidly deSpatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic

328

Reactive mercury in the troposphere: Model formation and results for Florida, the northeastern United States, and the Atlantic Ocean  

E-Print Network [OSTI]

. Divalent reactive gaseous mercury (RGM) in the atmo- sphere is water-soluble and is efficiently removed is the Community Multiscale Air Quality model (CMAQ) with modifications to include an integrated solution for gas and mercury. Divalent reactive gaseous mercury (RGM) is formed slowly through gas phase reactions and removed

Sillman, Sanford

329

Reactive oxygen species and Udx1 during early sea urchin development Julian L. Wong, Gary M. Wessel*  

E-Print Network [OSTI]

Reactive oxygen species and Udx1 during early sea urchin development Julian L. Wong, Gary M. Wessel Abstract Sea urchin fertilization is marked by a massive conversion of molecular oxygen to hydrogen of these defective embryos. We also report an unequal distribution of reactive oxygen species between sister

Wessel, Gary M.

330

Effect of Microstructural Changes on Gasification Reactivity of Coal Chars during Low Temperature Gasification  

Science Journals Connector (OSTI)

Effect of Microstructural Changes on Gasification Reactivity of Coal Chars during Low Temperature Gasification ... Pocahontas No. 3, Illinois No. 6, and Beulah-Zap coal char samples were gasified in 1% O2 at 500 C or 600 C up to 90% (daf) conversion, and their structure were observed under a high-resolution transmission electron microscope (HRTEM). ...

Atul Sharma; Hayato Kadooka; Takashi Kyotani; Akira Tomita

2001-11-28T23:59:59.000Z

331

RELATION BETWEEN TEXTURE AND REACTIVITY IN METALLURGICAL COKES OBTAINED FROM COAL USING PETROLEUM COKE AS ADDITIVE  

E-Print Network [OSTI]

Reactivity to C O2 is, perhaps, the most importam quality parameter used to evaluate the performance of a metallurgical coke in the blast furnace [ 1]. A lot of effort has been made to study how it is influenced by the

J. J. Pis; J. A. Men~ndez; R. Alvarez; M. A. Diez; J. B. Parra

332

Viscosity of -pinene secondary organic material and implications for particle growth and reactivity  

E-Print Network [OSTI]

Viscosity of -pinene secondary organic material and implications for particle growth and reactivity of secondary organic material (SOM) are abun- dant in the lower troposphere. The viscosity of these particles-mobility" technique and a "poke-flow" technique, in conjunction with simulations of fluid flow, the viscosity

333

Modular Formalization of Reactive Modules in Ming-Hsien Tsai1,2  

E-Print Network [OSTI]

Modular Formalization of Reactive Modules in COQ Ming-Hsien Tsai1,2 and Bow-Yaw Wang1 1 Institute systems in proof assistants consists of several tedious tasks. Firstly, system behavior has, interleaving versus concur- rent semantics need be resolved in behavioral specification. Secondly, system

Wang, Bow-Yaw

334

Specificationbased Testing of Reactive Software: A Case Study in Technology Transfer  

E-Print Network [OSTI]

Specification­based Testing of Reactive Software: A Case Study in Technology Transfer Lalita be effective in practice. The case study illustrates that technology transfer efforts can benefit from that limit formal methods technology transfer. We also found that there is often a tension between the scope

Porter, Adam

335

Issues affecting the prediction of glass reactivity in an unsaturated environment  

Science Journals Connector (OSTI)

Prior to the licensing of a high-level waste repository, the US Department of Energy (DOE) will seek to initiate hot startup of the high-level waste glass processing facilities at Savannah River and West Valley. To provide confidence that issues related to glass reactivity and disposal are evaluated prior to startup, the Environmental Restoration and Waste Management branch of DOE is studying important physical parameters that will affect glass reaction in a repository environment and is developing a modeling approach to predict glass performance. In this report, results are presented comparing the reactivity of fully radioactive glass with simulated glass of the same nominal composition. While differences in elemental releases between the glass types are observed, the differences are moderated with time and can be related to the dominant reaction mechanism. Additionally, the relationship between glass surface area and the volume of leachate (SA/V) is evaluated. The reactivity at differentSA/V is dominated by solution pH and reaction affinity, with an increase in reactivity observed at long reaction times. Finally, data are presented which provide necessary parameters for the application of predictive modeling. In particular, forward reaction rate constants are presented, for a 165-frit based glass and a simple analogue, and a list of secondary phases observed during glass reaction under a variety of conditions is compiled.

J.K. Bates; W.L. Ebert; X. Feng; W.L. Bourcier

1992-01-01T23:59:59.000Z

336

Reactivity and stability of platinum and platinum alloy catalysts toward the oxygen reduction reaction  

E-Print Network [OSTI]

Density functional theory (DFT) is used to study the reactivity of Pt and Pt-M (M: Pd, Co, Ni, V, and Rh) alloy catalysts towards the oxygen reduction reaction (ORR) as a function of the alloy overall composition and surface atomic distribution...

Calvo, Sergio Rafael

2009-05-15T23:59:59.000Z

337

MEASUREMENT OF OXYGEN CONSUMPTION AND DIFFUSION IN EXPOSED AND COVERED REACTIVE MINE TAILINGS1  

E-Print Network [OSTI]

MEASUREMENT OF OXYGEN CONSUMPTION AND DIFFUSION IN EXPOSED AND COVERED REACTIVE MINE TAILINGS1 the in situ oxygen diffusion and consumption in tailings. It provides measured values for the oxygen reaction rate Kr and the effective diffusion De coefficients based on oxygen consumption and diffusion tests

Aubertin, Michel

338

SPACE WEATHER AND THE INCIDENCE OF REACTIVE "OFF-COST" OPERATIONS IN THE PJM POWER GRID  

E-Print Network [OSTI]

SPACE WEATHER AND THE INCIDENCE OF REACTIVE "OFF-COST" OPERATIONS IN THE PJM POWER GRID 7.6 Kevin F the price of electricity in the PJM power grid. In this paper we examine one of the mechanisms by which space weather impacts the electricity market in the PJM power grid. The starting point of this paper

Schrijver, Karel

339

ANALYSIS OF DETONATION STATES WHEN SHOCKING TWO-PHASE REACTIVE SOLIDS*  

E-Print Network [OSTI]

' ANALYSIS OF DETONATION STATES WHEN SHOCKING TWO-PHASE REACTIVE SOLIDS* J. M. Powers, D. S the hypothesis that observed deviations from Chapman-Jouguet detonation states inporous solid propellants for a minimum detonation wave speed analogous to a Chapman-Jouguet detonation for a single phase is given

340

Prototype-Based Tests for Hybrid Reactive Systems G. Hahn, J. Philipps  

E-Print Network [OSTI]

of models fits well with processes that rely on rapid, or evolutionary, proto- typing. The comparativelyPrototype-Based Tests for Hybrid Reactive Systems G. Hahn, J. Philipps Validas Model Validation AG¨unchen Germany Abstract Model-based testing relies on the use of behavior models to automatically generate

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Examination of a PHEV Bidirectional Charger System for V2G Reactive Power Compensation  

E-Print Network [OSTI]

. Keywords - PHEV; charger; V2G; reactive power; battery I. INTRODUCTION Today, hybrid electric vehicles to power the vehicle for a daily commute. PHEVs provide electricity- only drive option up to a specified which is valuable to the electric power grid. The possibility of using battery-powered vehicles

Tolbert, Leon M.

342

Resilient Intrusion Tolerance through Proactive and Reactive Recovery Paulo Sousa Alysson Neves Bessani Miguel Correia  

E-Print Network [OSTI]

critical infrastructures like the Power grid. One approach that promises to satisfy this re- quirement system's correct opera- tion. We design a proactive-reactive recovery service based on a hybrid- silience of an intrusion-tolerant firewall adequate for the pro- tection of critical infrastructures. 1

Neves, Nuno

343

Highly Available Intrusion-Tolerant Services with Proactive-Reactive Recovery  

E-Print Network [OSTI]

on a hybrid distributed system model and show, as a case study, how this service can effectively be used infrastructures. Index Terms--Intrusion tolerance, proactive recovery, reactive recovery, firewall. ? 1 that are employed in mission-critical applications such as the SCADA systems used to manage critical infrastructures

Neves, Nuno

344

Using Agents to Secure the Internet Marketplace Reactive Security and Social Control  

E-Print Network [OSTI]

Using Agents to Secure the Internet Marketplace Reactive Security and Social Control Lars Rasmusson present the idea to let agents handle security issues in Internet markets. The motivation for this is the difficulties in having external or centralized control over a system as open as the Internet. The agents use

345

Using reactive transport modeling to evaluate the source term at Yucca mountain  

Science Journals Connector (OSTI)

The conventional approach of source-term evaluation for performance assessment of nuclear waste repositories uses the dissolution rate of waste form and the solubility of pure phases of radioactive elements to constrain radionuclide concentrations. This ... Keywords: neptunium, nuclear waste, radionuclide solubility, reactive-transport modeling, secondary phases, spent nuclear fuel, uranium

Yueting Chen

2003-04-01T23:59:59.000Z

346

A source of reactive power at a 35-kV substation of the Vankor oilfield  

Science Journals Connector (OSTI)

An SRP-35/10/10 source of reactive power based on a magnetically controlled RTMU-10000/35-UHL1-series shunt reactor and a capacitor bank rated at 10 MV A at voltage 35 kV is described in this work. It was put int...

B. I. Bazylev; M. A. Bryantsev; S. V. Dyagileva

2012-03-01T23:59:59.000Z

347

Nonvisual effects of led coloured ambient lighting on well-being and cardiac reactivity: preliminary findings  

Science Journals Connector (OSTI)

This study examined the immediate nonvisual effects of ambient lighting colours and illuminance on momentary wellbeing and physiology during daytime. As reported in recent literature, the effects of lighting extend beyond comfort and safety issues. Illuminance ... Keywords: LED, cardiac reactivity, colour lighting, illuminance, nonvisual effects, well-being

Michel Varkevisser; Roy J. E. M. Raymann; David V. Keyson

2011-07-01T23:59:59.000Z

348

Distributed control of reactive power flow in a radial distribution circuit with high photovoltaic penetration  

SciTech Connect (OSTI)

We show how distributed control of reactive power can serve to regulate voltage and minimize resistive losses in a distribution circuit that includes a significant level of photovoltaic (PV) generation. To demonstrate the technique, we consider a radial distribution circuit with a single branch consisting of sequentially-arranged residential-scale loads that consume both real and reactive power. In parallel, some loads also have PV generation capability. We postulate that the inverters associated with each PV system are also capable of limited reactive power generation or consumption, and we seek to find the optimal dispatch of each inverter's reactive power to both maintain the voltage within an acceptable range and minimize the resistive losses over the entire circuit. We assume the complex impedance of the distribution circuit links and the instantaneous load and PV generation at each load are known. We compare the results of the optimal dispatch with a suboptimal local scheme that does not require any communication. On our model distribution circuit, we illustrate the feasibility of high levels of PV penetration and a significant (20% or higher) reduction in losses.

Chertkov, Michael [Los Alamos National Laboratory; Turitsyn, Konstantin [Los Alamos National Laboratory; Backhaus, Scott [Los Alamos National Laboratory; Sule, Petr [NEW MEXICO CONSORTIUM

2009-01-01T23:59:59.000Z

349

Hyperbranched Aliphatic Polyesters and Reactive Diluents in Thermally Cured Coil Coatings  

Science Journals Connector (OSTI)

Reactive diluents (35-38) act as solvents in liquid paint, lowering the viscosity, and then chemically react into the film during cure. ... DSC studies were performed using a Mettler Toledo DSC820 equipped with a Mettler Toledo Sample Robot TSO801RO calibrated using standard procedures. ... Air-drying high solids alkyd paints for decorative coatings ...

Katarina Johansson; Tina Bergman; Mats Johansson

2008-12-04T23:59:59.000Z

350

New Strontium-based Bioactive Glasses: Physicochemical Reactivity and Delivering Capability  

E-Print Network [OSTI]

1 New Strontium-based Bioactive Glasses: Physicochemical Reactivity and Delivering Capability, strontium- doped bioactive glasses are of major interest; their key property relies on the increased that closely resembles to the biological apatite present in bones. Compared to strontium-free materials

Boyer, Edmond

351

Self-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy  

E-Print Network [OSTI]

investigated on the epitaxy and self- organization of laterally nanostructured transition metal TM silicideSelf-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy L to be a flexible and a convenient method for the preparation of dense arrays of Co silicide quantum dots

Ortega, Enrique

352

Extracting the Acoustic pressure field from Large Eddy Simulation of confined reactive flows  

E-Print Network [OSTI]

and non-premixed open flames3,4 as well as in more complex cases such as gas turbine combustors must be large enough to include the sources of noise as well as part of the acoustic near field.6 VeryExtracting the Acoustic pressure field from Large Eddy Simulation of confined reactive flows Camilo

Nicoud, Franck

353

Reactive power control of grid-connected wind farm based on adaptive dynamic programming  

E-Print Network [OSTI]

is widely used in the wind power system for its advantages over other two types [5]. The characteristicsReactive power control of grid-connected wind farm based on adaptive dynamic programming Yufei Tang Wind farm Power system Adaptive control a b s t r a c t Optimal control of large-scale wind farm has

He, Haibo

354

Reactive power management of distribution networks with wind generation for improving voltage stability  

E-Print Network [OSTI]

Reactive power management of distribution networks with wind generation for improving voltage February 2013 Available online Keywords: Composite load Distributed generation D-STATCOM Q with distributed wind generation. Firstly, the impact of high wind penetration on the static voltage stability

Pota, Himanshu Roy

355

Voltage Control of Distribution Networks with Distributed Generation using Reactive Power  

E-Print Network [OSTI]

Voltage Control of Distribution Networks with Distributed Generation using Reactive Power. Nasiruzzaman Abstract--Voltage profile of distribution networks with dis- tributed generation are affected significantly due to the integra- tion of distributed generation (DG) on it. This paper presents a way

Pota, Himanshu Roy

356

Green's function for reversible geminate reaction with volume reactivity Svetlana S. Khokhlova and Noam Agmon  

E-Print Network [OSTI]

Green's function for reversible geminate reaction with volume reactivity Svetlana S. Khokhlova OF CHEMICAL PHYSICS 137, 184103 (2012) Green's function for reversible geminate reaction with volume can occur within a finite reaction sphere. We obtain the Green's function solution for the Laplace

Agmon, Noam

357

Discrete sliding mode control strategy for direct real and reactive power regulation of wind driven DFIG  

Science Journals Connector (OSTI)

Abstract This paper investigates a discrete sliding mode control (DSMC) strategy for direct real and reactive power regulation for wind driven doubly fed induction generator (DFIG). The real and reactive power errors are eliminated by directly calculating the rotor control voltages through DSMC. In the stator stationary reference frame, direct real and reactive power control strategy is implemented. Therefore, it does not require the angular information of the stator and rotor currents or voltages. It does not involve any extra current loops which results into simple design. The use of constant converter switching frequency via space vector pulse width modulation eases the AC harmonic filter design and improves the power quality. The use of fast and flexible discrete controller makes the system competent with modern digital world. Detailed simulations have been carried out to validate the method. The simulation results reveal that the real and reactive power references are followed smoothly even in the presence of speed perturbations and performance of the system is robust against parameter variations and system disturbances.

V.N. Pande; U.M. Mate; Shailaja Kurode

2013-01-01T23:59:59.000Z

358

Improving Reactivity Against Target Organothiophosphates via Active-Site Directed Mutagenisis of a Bacterial Phosphotriesterase  

E-Print Network [OSTI]

to investigate the determining factors in enzyme reactivity. Coumaphos is hydrolyzed more efficiently than any other target by the wild type cobalt enzyme (kcat/Km = 2 x 10^7 M^-1s^-1). Coumaphos, fenitrothion and chlorpyrifos had the lowest Km values from...

Githens, Tyler 1986-

2013-01-17T23:59:59.000Z

359

Reactivity of Charcoal-Derived Water Soluble Biomarkers in River Water  

E-Print Network [OSTI]

combusted at 250C. The DOM was incubated with aliquots of filtered water collected from the Trinity River, (TX) for 37 days. We found that the reactivity of levoglucosan was similar to that of freely dissolved lignin-derived phenols in natural water...

Norwood, Matthew 1985-

2011-04-25T23:59:59.000Z

360

High Performance Computations of Subsurface Reactive Transport Processes at the Pore Scale  

E-Print Network [OSTI]

such as carbon sequestration drive the geochemistry of porous media far from equilibrium in relatively short time in reservoir scale models. In the DOE Energy Frontier Research Center for Nanoscale Control of Geologic Carbon such as reactive surface area or reaction rates as they affect CO2 sequestration, with an objective of upscaling

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Characterization of New Pancreatic Cancer-Reactive Monoclonal Antibodies Directed against Purified Mucin  

Science Journals Connector (OSTI)

...10/15(66.7) ND* 2/14(14.3)ND" Reactivity was wit *ND, notdetermin2.0-IIt] CJ3 i.o-in ri ll bronchial...A., Burchell, J., Bramwell, M. E., Griffiths, A.. Price, M., Taylor-Papadimitriou, J., Zanin, D., and Swallow...

Jenny J. L. Ho; Ning Bi; Pei-sha Yan; Mei Yuan; Kristine A. Norton; and Young S. Kim

1991-01-01T23:59:59.000Z

362

CO{sub 2}-gasification reactivity of different carbonaceous materials at elevated temperatures  

SciTech Connect (OSTI)

At the atmospheric pressure and at the temperatures between 1,223 and 1,673 K, the CO{sub 2} gasification reactivity of seven different carbonaceous materials comprising coal tar pitch coke, petroleum coke, natural graphite, carbon black and three coal chars was investigated by using thermogravimetric analysis. Their crystalline structures were analyzed by X-ray diffraction (XRD). It is found that the reactivity of the chars, pitch coke and petroleum coke produced from liquid phase carbonization, is several times poorer than that of the coal chars produced from solid phase carbonization and even lower than that of natural graphite. At the same time, it is obtained that under the condition of the chemical reaction control, the apparent activation energies of the former are in the range of 135.82-174.92 kJ/mol, while those of the latter are between 89.95 kJ/mol and 110.05 kJ/mol. Besides, the reactivity of the sample has a certain correlation with the crystalline structure of the sample, i.e., the larger the fraction of the relatively better crystalline structure is, the poorer the reactivity of the sample is.

Gu, J.; Wu, S.; Wu, Y.; Gao, J. [East China University of Science and Technology, Shanghai (China)

2009-07-01T23:59:59.000Z

363

Reactive Diffusion in Cu-Nb-Sn Internal Tin Superconducting Wires for the ITER Project  

E-Print Network [OSTI]

project, which investigates the production of electricity by means of nuclear fusion, have been studied and scanning electron microscopy, energy dispersive X-ray spectrometry (EDS) and X-ray Micro-Tomography (XMT density of the superconductor. Further understanding of the reactive diffusion to optimise the heat

Elliott, James

364

SiO2 Nanoparticle Sequestration via Reactive Functionalization in Holographic Polymer-Dispersed  

E-Print Network [OSTI]

SiO2 Nanoparticle Sequestration via Reactive Functionalization in Holographic Polymer addition of nanoparticles. Nanoparticles of many materials can be synthesized in sizes small enough are available to control the chemical interaction of the nanoparticles with the HPDLC system. Previous research

Braun, Paul

365

European Wind Energy Conference 2007 Milan Measurement based analysis of active and reactive power  

E-Print Network [OSTI]

European Wind Energy Conference 2007 ­ Milan 1 Measurement based analysis of active and reactive to the network through distribution systems. Because the production units, the distribution systems units will cover consumption in the vicinity. This can contribute to the reduction of the system losses

366

Synthesis and reactivity of molybdenum organometallic complexes supported by amide ligands  

E-Print Network [OSTI]

Chapter 1. Synthesis and Reactivity of Molybdenum Alkyl Complexes Supported by a Diamidoamine Ligand. The synthesis of a new diamidoamine ligand, CH3N[CH2CH2NH(3-(CF3)C6H4)]2 (H2L) is reported. Molybdenum complexes of the ...

Hock, Adam S. (Adam Scott)

2007-01-01T23:59:59.000Z

367

Reactive barrier technologies for treatment of contaminated groundwater at Rocky Flats  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) Office of Science and Technology Subsurface Contaminants Focus Area is supporting the investigation of reactive barrier technologies to mitigate the risks associated with mixed organic/radioactive waste at several DOE sites. Groundwater from a small contaminated plume at the Rocky Flats Environmental Technology Site (RFETS) is being used to evaluate passive reactive material treatment. Permeable reactive barriers which intercept contaminants and destroy the VOC component while containing radionuclides are attractive for a number of reasons relating to public and regulatory acceptance. In situ treatment keeps contaminants away from the earth`s surface, there is no above-ground treatment equipment that could expose workers and the public and operational costs are expected to be lower than currently used technologies. This paper will present results from preliminary site characterization and in-field small-scale column testing of reactive materials at RFETS. Successful demonstration is expected to lead to full-scale implementation of the technology at several DOE sites, including Rocky Flats.

Marozas, D.C.; Bujewski, G.E. [Sandia National Labs., Albuquerque, NM (United States); Castaneda, N. [Rocky Flats Field Office, Golden, CO (United States)

1997-12-31T23:59:59.000Z

368

IEEE TRANSACTIONS ON POWER SYSTEMS (ACCEPTED NOVEMBER 8, 2014) 1 Stochastic Reactive Power Management  

E-Print Network [OSTI]

response, and electric vehicles. Advances in photovoltaic (PV) inverters offer new opportunitiesIEEE TRANSACTIONS ON POWER SYSTEMS (ACCEPTED NOVEMBER 8, 2014) 1 Stochastic Reactive Power are being challenged by reverse power flows and voltage fluctuations due to renewable generation, demand

Giannakis, Georgios

369

Reactivity Controlled Compression Ignition (RCCI) Combustion on a Multi-Cylinder Light-Duty Diesel Engine  

SciTech Connect (OSTI)

Reactivity controlled compression ignition is a low-temperature combustion technique that has been shown, both in computational fluid dynamics modeling and single-cylinder experiments, to obtain diesel-like efficiency or better with ultra-low nitrogen oxide and soot emissions, while operating primarily on gasoline-like fuels. This paper investigates reactivity controlled compression ignition operation on a four-cylinder light-duty diesel engine with production-viable hardware using conventional gasoline and diesel fuel. Experimental results are presented over a wide speed and load range using a systematic approach for achieving successful steady-state reactivity controlled compression ignition combustion. The results demonstrated diesel-like efficiency or better over the operating range explored with low engine-out nitrogen oxide and soot emissions. A peak brake thermal efficiency of 39.0% was demonstrated for 2600 r/min and 6.9 bar brake mean effective pressure with nitrogen oxide emissions reduced by an order of magnitude compared to conventional diesel combustion operation. Reactivity controlled compression ignition emissions and efficiency results are compared to conventional diesel combustion operation on the same engine.

Curran, Scott [ORNL; Hanson, Reed M [ORNL; Wagner, Robert M [ORNL

2012-01-01T23:59:59.000Z

370

STOMP-ECKEChem: An Engineering Perspective on Reactive Transport in Geologic Media  

SciTech Connect (OSTI)

ECKEChem (Equilibrium, Conservation, Kinetic Equation Chemistry) is a reactive transport module for the STOMP suite of multifluid subsurface flow and transport simulators that was developed from an engineering perspective. STOMP comprises a suite of operational modes that are distinguished by the solved coupled conservation equations with capabilities for a variety of subsurface applications (e.g., environmental remediation and stewardship, geologic sequestration of greenhouse gases, gas hydrate production, and oil shale production). The ECKEChem module was designed to provide integrated reactive transport capabilities across the suite of STOMP simulator operational modes. The initial application for the ECKEChem module was in the simulation of the mineralization reactions that occurred with the injection of supercritical carbon dioxide into deep Columbia River basalt formations, where it was implemented in the STOMP-CO2 simulator. The STOMP-ECKEChem solution approach to modeling reactive transport in multifluid geologic media is founded on an engineering perspective: (1) sequential non-iterative coupling between the flow and reactive transport is sufficient, (2) reactive transport can be modeled by operator splitting with local geochemistry and global transport, (3) geochemistry can be expressed as a system of coupled nonlinear equilibrium, conservation and kinetic equations, (4) a limited number of kinetic equation forms are used in geochemical practice. This chapter describes the conceptual approach to converting a geochemical reaction network into a series of equilibrium, conservation and kinetic equations, the implementation of ECKEChem in STOMP, the numerical solution approach, and a demonstration of the simulator on a complex application involving desorption of uranium from contaminated field-textured sediments.

White, Mark D.; Fang, Yilin

2012-04-04T23:59:59.000Z

371

Dynamics of reverse osmosis in a standalone cogenerative nuclear reactor (Part I: reactivity changes)  

Science Journals Connector (OSTI)

The present study considers the dynamic behaviour of the pressurised water reactor safety features, represented by the integrity of the fuel cladding, under some transient cases. A cosine-shaped heating through the fuel is taken with the corresponding coolant lumps, to simulate realistic cases encountered in nuclear reactors. A mathematical model was developed for the Westinghouse 3411 MWth pressurised water reactor, as an example of a familiar design with predominantly published data design. The model consists of two parts. The first part is concerned with the dynamics of the primary side of the reactor, which is described in this paper. The second part is concerned with the secondary side of the plant, which is described elsewhere in this issue. To study the dynamics of the reactor, a model of 17 lumped parameters was used, consisting of first-order differential equations deduced from the first principles considering six groups of delayed neutrons. A computer program was developed using the Runge-Kutta method to solve these equations and to predict the behaviour of the state variables with time. Two case studies were considered as examples for normal transients. The first case study, which represents Part 1 of this study, considers the effect of primary side transient on the system as the reactivity changes. Reactor reactivity changes, including movements of the reactor control rods, which are taken as an example for the effect of the reactor primary side conditions. These reactivity changes vary from 0.0005 up to 0.003, both for positive and negative reactivity. The results of the developed model, which describe the dynamic response of the reactor primary circuit, have been analysed and verified with the relevant models. These results indicate that the reactor components and the integrity of the fuel cladding were attained during different step changes of reactivity.

Aly Karameldin; M.M. Shamloul; M.R. Shaalan; M.H. Esawy

2007-01-01T23:59:59.000Z

372

Overview on backfill materials and permeable reactive barriers for nuclear waste disposal facilities.  

SciTech Connect (OSTI)

A great deal of money and effort has been spent on environmental restoration during the past several decades. Significant progress has been made on improving air quality, cleaning up and preventing leaching from dumps and landfills, and improving surface water quality. However, significant challenges still exist in all of these areas. Among the more difficult and expensive environmental problems, and often the primary factor limiting closure of contaminated sites following surface restoration, is contamination of ground water. The most common technology used for remediating ground water is surface treatment where the water is pumped to the surface, treated and pumped back into the ground or released at a nearby river or lake. Although still useful for certain remediation scenarios, the limitations of pump-and-treat technologies have recently been recognized, along with the need for innovative solutions to ground-water contamination. Even with the current challenges we face there is a strong need to create geological repository systems for dispose of radioactive wastes containing long-lived radionuclides. The potential contamination of groundwater is a major factor in selection of a radioactive waste disposal site, design of the facility, future scenarios such as human intrusion into the repository and possible need for retrieving the radioactive material, and the use of backfills designed to keep the radionuclides immobile. One of the most promising technologies for remediation of contaminated sites and design of radioactive waste repositories is the use of permeable reactive barriers (PRBs). PRBs are constructed of reactive material(s) to intercept and remove the radionuclides from the water and decontaminate the plumes in situ. The concept of PRBs is relatively simple. The reactive material(s) is placed in the subsurface between the waste or contaminated area and the groundwater. Reactive materials used thus far in practice and research include zero valent iron, hydroxyapatite, magnesium oxide, and others. As the contaminant moves through the reactive material, the contaminant is either sorbed by the reactive material or chemically reacts with the material to form a less harmful substance. Because of the high risk associated with failure of a geological repository for nuclear waste, most nations favor a near-field multibarrier engineered system using backfill materials to prevent release of radionuclides into the surrounding groundwater.

Moore, Robert Charles; Hasan, Ahmed Ali Mohamed; Holt, Kathleen Caroline; Hasan, Mahmoud A. (Egyptian Atomic Energy Authority, Cairo, Egypt)

2003-10-01T23:59:59.000Z

373

Probing Material Reactivity Using X-ray Pair Distribution Function Methods  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Material Reactivity Using X-ray Pair Distribution Material Reactivity Using X-ray Pair Distribution Function Methods Karena W. Chapman X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA Understanding how advanced functional materials react and transform, at an atomic scale, is a characterization challenge with many diverse phenomena possible; components with varying particle size, morphology, and microstructure can evolve from multi-atom clusters to multi-million atom crystals. The pair distribution function (PDF) method shows great promise for providing quantitative insight such reactions. Recent advances in experimental methods, have improved the efficiency of X-ray PDF measurements, to allow time-resolved experiments with sufficient resolution to study reactions in solid

374

Reactivation and operation of the large six-tesla CFFF superconducting magnet  

SciTech Connect (OSTI)

The second MHD superconducting magnet system constructed at the Argonne National Laboratory, originally intended for use in the coal-fired plasma MHD power generation program, has been in storage at Argonne since its assembly and short-term testing a decade ago. At that time it was energized for only a few days and then decommissioned. The magnet, a 6-T dipole having an effective length of 300 cm and a tapered warm bore of 80 to 100 cm, has recently been reactivated and put into service for sea water MHD propulsion research. This report describes the technical aspects of the reactivation process, as well as the operational characterization of the reconstituted system.

Hill, D.; Libera, J.; Petrick, M.

1992-07-01T23:59:59.000Z

375

Reactivation and operation of the large six-tesla CFFF superconducting magnet  

SciTech Connect (OSTI)

The second MHD superconducting magnet system constructed at the Argonne National Laboratory, originally intended for use in the coal-fired plasma MHD power generation program, has been in storage at Argonne since its assembly and short-term testing a decade ago. At that time it was energized for only a few days and then decommissioned. The magnet, a 6-T dipole having an effective length of 300 cm and a tapered warm bore of 80 to 100 cm, has recently been reactivated and put into service for sea water MHD propulsion research. This report describes the technical aspects of the reactivation process, as well as the operational characterization of the reconstituted system.

Hill, D.; Libera, J.; Petrick, M.

1992-01-01T23:59:59.000Z

376

Energy Saving in Conventional and Unconventional Batch Reactive Distillation: Application to Hydrolysis of Methyl Lactate System  

Science Journals Connector (OSTI)

Abstract In this work, energy consumption in a middle vessel batch reactive distillation (MVBRD) column is considered for the production of lactic acid via hydrolysis of methyl lactate. A dynamic optimization problem incorporating a process model is formulated to minimize the batch time which consequently minimizes the total energy consumption. The problem is subject to constraints on the amount and purity of lactic acid. The optimisation variables are reflux ratio and/or reboil ratio which are treated as piecewise constant. The earlier work of the authors on energy consumption in conventional batch reactive distillation column (CBRD) for the same reaction system is used for comparative analysis with the energy consumption in MVBRD. As an example, for a given separation task, the optimization results show that MVBRD is capable of saving over 23% energy compared to energy consumption in CBRD column for the same task.

Elmahboub A. Edreder; Mansour Emtir; Iqbal M. Mujtaba

2014-01-01T23:59:59.000Z

377

Method of extruding and packaging a thin sample of reactive material, including forming the extrusion die  

DOE Patents [OSTI]

This invention teaches a method of cutting a narrow slot in an extrusion die with an electrical discharge machine by first drilling spaced holes at the ends of where the slot will be, whereby the oil can flow through the holes and slot to flush the material eroded away as the slot is being cut. The invention further teaches a method of extruding a very thin ribbon of solid highly reactive material such as lithium or sodium through the die in an inert atmosphere of nitrogen, argon, or the like as in a glovebox. The invention further teaches a method of stamping out sample discs from the ribbon and of packaging each disc by sandwiching it between two aluminum sheets and cold welding the sheets together along an annular seam beyond the outer periphery of the disc. This provides a sample of high purity reactive material that can have a long shelf life.

Lewandowski, E.F.; Peterson, L.L.

1981-11-30T23:59:59.000Z

378

Method of extruding and packaging a thin sample of reactive material including forming the extrusion die  

DOE Patents [OSTI]

This invention teaches a method of cutting a narrow slot in an extrusion die with an electrical discharge machine by first drilling spaced holes at the ends of where the slot will be, whereby the oil can flow through the holes and slot to flush the material eroded away as the slot is being cut. The invention further teaches a method of extruding a very thin ribbon of solid highly reactive material such as lithium or sodium through the die in an inert atmosphere of nitrogen, argon or the like as in a glovebox. The invention further teaches a method of stamping out sample discs from the ribbon and of packaging each disc by sandwiching it between two aluminum sheets and cold welding the sheets together along an annular seam beyond the outer periphery of the disc. This provides a sample of high purity reactive material that can have a long shelf life.

Lewandowski, Edward F. (Westmont, IL); Peterson, Leroy L. (Joliet, IL)

1985-01-01T23:59:59.000Z

379

Lattice Boltzmann simulations of phase separation in chemically reactive binary fluids  

E-Print Network [OSTI]

We use a lattice Boltzmann method to study pattern formation in chemically reactive binary fluids in the regime where hydrodynamic effects are important. The coupled equations solved by the method are a Cahn-Hilliard equation, modified by the inclusion of a reactive source term, and the Navier-Stokes equations for conservation of mass and momentum. The coupling is two-fold, resulting from the advection of the order-parameter by the velocity field and the effect of fluid composition on pressure. We study the the evolution of the system following a critical quench for a linear and for a quadratic reaction source term. Comparison is made between the high and low viscosity regimes to identify the influence of hydrodynamic flows. In both cases hydrodynamics is found to influence the pathways available for domain growth and the eventual steady-states.

K. Furtado; J. M. Yeomans

2006-05-31T23:59:59.000Z

380

Reactivity of surface carbon deposited on supported Rh catalysts by the disproportionation of CO  

SciTech Connect (OSTI)

Recent investigations on hydrocarbon synthesis from CO and H/sub 2/ over Group VIII metals have proposed that the surface carbon formed by the dissociation of CO is an intermediate for hydrocarbon formation. It implies that metals which dissociate CO readily (e.g., Ni, Co, and Ru) are good catalysts for hydrocarbon synthesis unless the surface carbon is bound too strongly. There is a certain controversy in the literature on whether CO undergoes dissociation on Rh surfaces under UHV conditions. In the present work, the authors have investigated the reactivity of surface carbon deposited on TiO/sub 2/- or SiO/sub 2/-supported Rh catalysts in the presence of molecularly adsorbed CO by means of the isotopic tracer technique and have made a direct comparison of the reactivity of adsorbed CO with that of surface carbon. It has been revealed that three forms of carbon are produced by the disproportionation of CO.

Orita, H.; Naito, S.; Tamaru, K.

1988-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

XCHEM-1D: A Heat Transfer/Chemical Kinetics Computer Program for multilayered reactive materials  

SciTech Connect (OSTI)

An eXplosive CHEMical kinetics code, XCHEM, has been developed to solve the reactive diffusion equations associated with thermal ignition of energetic materials. This method-of-lines code uses stiff numerical methods and adaptive meshing to resolve relevant combustion physics. Solution accuracy is maintained between multilayered materials consisting of blends of reactive components and/or inert materials. Phase change and variable properties are included in one-dimensional slab, cylindrical and spherical geometries. Temperature-dependent thermal properties have been incorporated and the modification of thermal conductivities to include decomposition effects are estimated using solid/gas volume fractions determined by species fractions. Gas transport properties, including high pressure corrections, have also been included. Time varying temperature, heat flux, convective and thermal radiation boundary conditions, and layer to layer contact resistances have also been implemented.

Gross, R.J.; Baer, M.R.; Hobbs, M.L.

1993-10-01T23:59:59.000Z

382

ETBE Synthesis via Reactive Distillation. 1. Steady-State Simulation and Design Aspects  

Science Journals Connector (OSTI)

To validate the simulation results without experimental data, Smith's MTBE column was simulated for the case described in his patent application (Smith, 1980) using both Pro/II and SpeedUp. ... The maximum conversion in a 10-stage ETBE reactive distillation column (Figure 5) and a 30-stage ETBE reactive distillation column based on a commercial MTBE column (Simulation Sciences, 1995) (where the co-objective is to essentially eliminate butylenes from the ether product) was determined for varying isobutylene concentrations in the hydrocarbon feed to the primary reactor, by simulations using Pro/II. ... 11.?Determine?column?diameter?from?simulation?data?for?vapor?and?liquid?loadings?and?column?height?from?stage?efficiency? estimates,?including?appropriate?allowances?for?uncertainties?in?flooding?factor?and?stage?efficiency. ...

Martin G. Sneesby; Moses O. Tad; Ravindra Datta; Terence N. Smith

1997-05-05T23:59:59.000Z

383

Impacts of dynamic reactive power compensation devices on the performance of wind power generators  

Science Journals Connector (OSTI)

This paper investigates the main impacts of dynamic reactive power compensation devices on the performance of induction machine-based wind power generators. The dynamic reactive power compensation devices analysed are the SVC (Static Var Compensator) and the DSTATCOM (Distributed Static Synchronous Compensator). The usage of these devices as a power factor regulator or a voltage regulator is investigated. The technical factors analysed are small-signal voltage stability, transient stability and interactions with the anti-islanding protection system. The analyses are carried out by using a wind farm composed of 30 units of 1 MW induction generators. Such wind farm is connected to a 60 Hz, 33 kV distribution system. The results are a useful guideline to evaluate which control strategy and device are suitable for a determined application as well as to understand the dynamic interactions that can occur.

Walmir Freitas; Mauricio B.C. Salles; Jose C.M. Vieira; Andre Morelato; Luiz Carlos Pereira Da Silva; Vivaldo Fernando Da Costa

2005-01-01T23:59:59.000Z

384

Catalytic and reactive polypeptides and methods for their preparation and use  

DOE Patents [OSTI]

Catalytic and reactive polypeptides include a binding site specific for a reactant or reactive intermediate involved in a chemical reaction of interest. The polypeptides further include at least one active functionality proximate the binding site, where the active functionality is capable of catalyzing or chemically participating in the chemical reaction in such a way that the reaction rate is enhanced. Methods for preparing the catalytic peptides include chemical synthesis, site-directed mutagenesis of antibody and enzyme genes, covalent attachment of the functionalities through particular amino acid side chains, and the like. This invention was made with Government support under Grant Contract No. AI-24695, awarded by the Department of health and Human Services, and under Grant Contract No. N 00014-87-K-0256, awarded by the Office of Naval Research. The Government has certain rights in this invention.

Schultz, Peter (Oakland, CA)

1994-01-01T23:59:59.000Z

385

Assessment of sorbent reactivation by water hydration for fluidized bed combustion application  

SciTech Connect (OSTI)

Disposal of fluidized bed combustion (FBC) solid residues currently represents one of the major issues in FBC design and operation, and contributes significantly to its operating cost. This issue has triggered research activities on the enhancement of sorbent utilization for in situ sulfur removal. The present study addresses the effectiveness of the reactivation by liquid water hydration of FB spent sorbents. Two materials are considered in the study, namely the bottom ash from the operation of a full-scale utility FB boiler and the raw commercial limestone used in the same boiler. Hydration-reactivation tests were carried out at temperatures of 40{sup o}C and 80{sup o}C and for curing times ranging from 15 minutes to 2d, depending on the sample. The influence of hydration conditions on the enhancement of sulfur utilization has been assessed. A combination of methods has been used to characterize the properties of liquid water-hydrated materials

Fabio Montagnaro; Piero Salatino; Fabrizio Scala; Yinghai Wu; Edward J. Anthony; Lufei Jia [Universita degli Studi di Napoli Federico II, Complesso Universitario del Monte di Sant'Angelo, Naples (Italy). Dipartimento di Chimica

2006-06-15T23:59:59.000Z

386

Challenges in the Theoretical Description of Nanoparticle Reactivity: Nano Zero-Valent Iron  

E-Print Network [OSTI]

The reactivity of iron atoms, clusters and nanoparticles (nZVI) is of increasing interest owing to their important practical applications, ranging from the steel industry to water remediation technologies. Here, we provide an overview of computational methods and models that can be applied to study nZVI reactions and discuss their benefits and limitations. We also report current progress in calculations through recent examples treating the reactivity of nZVI particles. Finally, we consider the potential use of highly accurate methods with favorable scaling (such as quantum Monte Carlo or random phase approximation), which are currently considered too computationally expensive but are expected to become more amenable in the future as computer power increases.

Karlick, Frantiek

2014-01-01T23:59:59.000Z

387

Study of catalytic effects of mineral matter level on coal reactivity  

SciTech Connect (OSTI)

Coal liquefaction experiments using a 400-lb/day bubble-column reactor tested the catalytic effects of added mineral matter level on coal conversion, desulfurization, and distillate yields in continuous operation under recycle conditions, with specific emphasis on the use of a disposable pyrite catalyst indigenous to the feed coal. Western Kentucky No. 11 run-of-mine (ROM) and washed coals were used as feedstocks to determine the effects of levels of mineral matter, specifically iron compounds. Liquefaction reactivity as characterized by total distillate yield was lower for washed coal, which contained less mineral matter. Liquefaction reactivity was regained when pyrite concentrate was added as a disposable catalyst to the washed coal feed in sufficient quantity to match the feed iron concentration of the run-of-mine coal liquefaction test run.

Mazzocco, Nestor J.; Klunder, Edgar B.; Krastman, Donald

1981-03-01T23:59:59.000Z

388

ANN-based reactive power controller with real-time web monitoring  

Science Journals Connector (OSTI)

This study introduced a real-time reactive power controller based on artificial neural network with web-based monitoring. A feed-forward employing back-propagation was used as training technique. The inputs to the network were the active and reactive power of each load. The targets were to switch on/off the capacitor banks during normal and abnormal conditions. The network was trained using developed MATLAB program and the weights resulted to minimum mean-square-error were fed to the microcontroller unit. The method was then tested in a three-bus radial distribution system model and implemented using Zilog microcontroller. The system actions were monitored using web-based monitoring application. The method was validated in actual operation of the system using the test data and results were satisfactorily obtained.

Carl John O. Salaan; Mark Joseph M. Victoria; Noel R. Estoperez

2013-01-01T23:59:59.000Z

389

The effect of a subcritical lattice on the reactivity of a coupled critical assembly  

E-Print Network [OSTI]

THE INTERACTION BETWEEN A SUBCRITICAL LATTICE COUPLED WITH THE AGN-201 CORE Geometry Assumed for Solution of Plux Equations ~ General Solution of One-group, Three-region Flux Equat'lolls' ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ o ~ ~ ~ ~ ~ ~ ~ ~ Applications of Mathematical... Solution to the Actual Conversion of Induced Buckling Change to Reactivity Worth o + ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ o 10 II ~ BXPERIMENTAL DETERMINATION OF THE INTERACTION BETWEEN THE SUBCRITICAL LATTICE AND THE AGN-201 CORE Description of the Experimental...

Slagle, Henry Roach

1961-01-01T23:59:59.000Z

390

Intrinsic reactivity feedback characteristics for safety analysis of heterogeneous and homogeneous LMFBR core designs  

SciTech Connect (OSTI)

This paper presents a comparison of the intrinsic reactivity feedback characteristics of homogeneous and heterogeneous LMFBR designs. The comparisons are shown for a 1000 MWth LMFBR core design. However, the applicability of the conclusions drawn from these comparisons are generic to larger LMFBRs. Consistent sodium void worth distributions have been calculated for heterogeneous and homogeneous 1000 MWth LMFBR core designs. The basic calculations were performed with three dimensional models using ENDF/B-III cross section data and first order perturbation theory.

Doncals, R.A.; Lake, J.A.

1982-01-01T23:59:59.000Z

391

Increased Blood Glucose is Related to Disturbed Cerebrovascular Pressure Reactivity After Traumatic Brain Injury  

E-Print Network [OSTI]

Joseph Donnelly Division of Neurosurgery, Department of Clinical Neurosciences, Box 167, Cambridge Biomedical Campus, Cambridge, CB2 0QQ, United Kingdom. United Kingdom Email: jd634@cam.ac.uk Phone: +44 (0) 1223 336946 0DQXVFULSW &OLFN#3... glucose concentration impairs endothelial, and smooth muscle cell responses both in the cerebral and peripheral vasculature. Clearly, further investigation on the link between glucose and pressure reactivity in the TBI population is warranted...

Donnelly, Joseph; Sudhan, Nazneen; Varsos, Georgios V.; Nasr, Nathalie; Jalloh, Ibrahim; Liu, Xiuyun; Dias, Celeste; Sekhon, Mypinder; Carpenter, Keri L. H.; Menon, David K.; Hutchinson, Peter J.; Smielewski, Peter; Czosnyka, Marek

2014-08-15T23:59:59.000Z

392

Oxygen Reactivity of Devolatilized Diesel Engine Particulates from Conventional and Biodiesel Fuels  

Science Journals Connector (OSTI)

Oxygen Reactivity of Devolatilized Diesel Engine Particulates from Conventional and Biodiesel Fuels ... Abatement of diesel particulates has led to an overall decrease in the fuel efficiency of diesel engines, and overcoming these losses has been one of the more challenging problems in exhaust aftertreatment. ... (16-18) Establishing a general physical basis for modeling diesel particulate oxidation is especially challenging because of the large variations in microscopic structure that it can have. ...

Andrea Strzelec; Todd J. Toops; C. Stuart Daw

2013-06-10T23:59:59.000Z

393

Set of Acidic Resin Catalysts To Correlate Structure and Reactivity in Fructose Conversion to 5-Hydroxymethylfurfural  

Science Journals Connector (OSTI)

Set of Acidic Resin Catalysts To Correlate Structure and Reactivity in Fructose Conversion to 5-Hydroxymethylfurfural ... With this set of model catalysts, the cross-linker content of the resin was found to be the most influential factor for the liquid phase dehydration of fructose to 5-hydroxymethylfurfural. ... Materials containing either Brnsted(8-10) or Lewis acid sites(11) were proven to be suitable catalysts for the selective dehydration of carbohydrate feedstocks into 5-hydroxymethylfurfural (HMF), a versatile platform molecule. ...

Felix H. Richter; Kristina Pupovac; Regina Palkovits; Ferdi Schth

2012-12-24T23:59:59.000Z

394

DOE/EA-1310: Finding of No Significant Impact for the Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Couples Fast Reactivity Measurements Facility at the Idaho National Engineering and Environmental Laboratory  

Broader source: Energy.gov (indexed) [DOE]

FINDING OF NO SIGNIFICANT IMPACT FOR THE DECONTAMINATION AND FINDING OF NO SIGNIFICANT IMPACT FOR THE DECONTAMINATION AND DISMANTLEMENT OF THE ADVANCED REACTIVITY MEASUREMENT FACILITY AND COUPLED FAST REACTIVITY MEASUREMENTS FACILITY AT THE IDAHO NATIONAL ENGINEERING AND ENVIRONMENTAL LABORATORY Agency: U. S. Department of Energy (DOE) Action: Finding of No Significant Impact (FONSI) Summary: The DOE prepared a Draft Environmental Assessment (EA) for the proposed "Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Coupled Fast Reactivity Measurement Facility at the Idaho National Engineering and Environmental Laboratory" (DOE/EA-1310). The EA was prepared in accordance with the Council on Environmental Quality (CEQ) Regulations for implementing the National Environmental Policy Act (NEPA) (40 CFR 1500-1508), and the

395

EST-CE QU'ON VOlT ATRAVERS UN MICROSCOPE? '  

E-Print Network [OSTI]

speculations philosophiques. *Ian Hacking, «Do we see through a microscope?», P~cifi: Ph~loso phical Quarterly. Texte de Ian Hacking extrait de : Philosophie des sciences - Tome 2 : Naturalismes et réalismes Dirigé par Sandra Laugier , Pierre Wagner Ed. Vrin, Paris #12;240 IAN HACKING LA GRANDE CHAiNE DES ETRES Le

Aubin, David

396

Winery pairs vines with volts, leads the way for solar on BPA...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

vineyard. You'll find productive bugs, not poisons. And now, you'll also find 4,100 solar panels, painstakingly placed on the 1,000 acre estate to harvest the sun's rays. The...

397

Scalable Distributed Automation System: Scalable Real-time Decentralized Volt/VAR Control  

SciTech Connect (OSTI)

GENI Project: Caltech is developing a distributed automation system that allows distributed generatorssolar panels, wind farms, thermal co-generation systemsto effectively manage their own power. To date, the main stumbling block for distributed automation systems has been the inability to develop software that can handle more than 100,000 distributed generators and be implemented in real time. Caltechs software could allow millions of generators to self-manage through local sensing, computation, and communication. Taken together, localized algorithms can support certain global objectives, such as maintaining the balance of energy supply and demand, regulating voltage and frequency, and minimizing cost. An automated, grid-wide power control system would ease the integration of renewable energy sources like solar power into the grid by quickly transmitting power when it is created, eliminating the energy loss associated with the lack of renewable energy storage capacity of the grid.

None

2012-03-01T23:59:59.000Z

398

The characteristics of arcing faults in 480-volt power distribution systems  

E-Print Network [OSTI]

spontaneous arc-over to ground or to another phase. ~ Insulation failure due to surface conduction across conductive dust or contamination, or due to a cracked insulator body. ~ Conductive gases emanating from circuit breakers or fuses during circuit.... ~ Rodents or vermin, especially those returning from a wet outing to the warmth of the equipment. In tropical climates, snakes are known to have caused arcing faults across insulator strings. Since causes of arcing fault cannot always be eliminated in 480...

Shih, Yu?

2012-06-07T23:59:59.000Z

399

Data Analysis and Reporting of the 150 Chevrolet Volt ARRA Demonstration Fleet  

SciTech Connect (OSTI)

This is the final report for the GM Vehicle Demo analysis and reporting. I'd like it to be posted to the AVTA website. It contains no new information than what is in Quarterly reports that were previously approved by GM.

Richard "Barney" Carlson

2014-07-01T23:59:59.000Z

400

Mega-electron-volt ion beam induced anisotropic plasmon resonance of silver nanocrystals in glass  

E-Print Network [OSTI]

, 3508 TA Utrecht, The Netherlands B. J. Kooi Department of Applied Physics, Materials Science Center. Watson Laboratory of Applied Physics, California Institute of Technology, Pasadena, California 91125 A. M. Vredenberg Department of Atomic and Interface Physics, Debye Institute, Utrecht University, P.O. Box 80000

Polman, Albert

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Laboratory testing of Saft SEH-5-200 6 volt traction battery  

SciTech Connect (OSTI)

The purpose of this report is to describe the testing performed on the Saft SEH-5-200 flooded nickel cadmium traction battery by the INEL Electric Vehicle Battery Laboratory, to present the results and conclusions of this testing, and to make appropriate recommendations. 17 figs., 3 tabs.

Hardin, J.E.

1989-12-01T23:59:59.000Z

402

GUINEVERE experiment: Kinetic analysis of some reactivity measurement methods by deterministic and Monte Carlo codes  

SciTech Connect (OSTI)

The GUINEVERE experiment (Generation of Uninterrupted Intense Neutrons at the lead Venus Reactor) is an experimental program in support of the ADS technology presently carried out at SCK-CEN in Mol (Belgium). In the experiment a modified lay-out of the original thermal VENUS critical facility is coupled to an accelerator, built by the French body CNRS in Grenoble, working in both continuous and pulsed mode and delivering 14 MeV neutrons by bombardment of deuterons on a tritium-target. The modified lay-out of the facility consists of a fast subcritical core made of 30% U-235 enriched metallic Uranium in a lead matrix. Several off-line and on-line reactivity measurement techniques will be investigated during the experimental campaign. This report is focused on the simulation by deterministic (ERANOS French code) and Monte Carlo (MCNPX US code) calculations of three reactivity measurement techniques, Slope ({alpha}-fitting), Area-ratio and Source-jerk, applied to a GUINEVERE subcritical configuration (namely SC1). The inferred reactivity, in dollar units, by the Area-ratio method shows an overall agreement between the two deterministic and Monte Carlo computational approaches, whereas the MCNPX Source-jerk results are affected by large uncertainties and allow only partial conclusions about the comparison. Finally, no particular spatial dependence of the results is observed in the case of the GUINEVERE SC1 subcritical configuration. (authors)

Bianchini, G.; Burgio, N.; Carta, M. [ENEA C.R. CASACCIA, via Anguillarese, 301, 00123 S. Maria di Galeria Roma (Italy); Peluso, V. [ENEA C.R. BOLOGNA, Via Martiri di Monte Sole, 4, 40129 Bologna (Italy); Fabrizio, V.; Ricci, L. [Univ. of Rome La Sapienza, C/o ENEA C.R. CASACCIA, via Anguillarese, 301, 00123 S. Maria di Galeria Roma (Italy)

2012-07-01T23:59:59.000Z

403

Treatment of reactive dyes and textile finishing wastewater using Fenton's oxidation for reuse  

Science Journals Connector (OSTI)

Fenton's oxidation (FO) was used to decolourise and degrade some reactive dyes (Remazol Black 5, Remazol Red, Remazol Blue, Remazol Yellow) and raw textile finishing industry effluents (S1, S2, S3) containing mainly reactive dyes. The operational conditions for pH varied between 2.5 and 4.0 while temperature ranged from 30°C to 50°C. The concentrations of FeSO4 and H2O2 varied to a wide range (200??600 mg/l of FeSO4, 300??1000 mg/l of H2O2) depending on the type of the dyes and their mixture and textile additives used in the process. FO is highly effective for colour removal (>99%) for reactive dyes and (87??94%) for textile finishing wastewater. It can be applied as a pretreatment and the remaining total dissolved solids (TDS) can be removed by an additional advanced process, e.g. membrane process.

Sureyya Meric; Giusy Lofrano; Vincenzo Belgiorno

2005-01-01T23:59:59.000Z

404

Flicker mitigation by reactive power control in wind farm with doubly fed induction generators  

Science Journals Connector (OSTI)

Abstract This paper presents a novel wind farm control with the purpose to mitigate the flicker emission of doubly fed induction generators. The presented control strategy is implemented in a wind farm connected to a distribution grid with consumers. The control system is composed by two controllers in cascade, the wind farm control and the local wind turbine controller. The wind farm control adapts itself to the consumptions of the distribution network and generates the minimal reactive power which allows smoothing the fast variations of wind power output. In this sense, the wind farm control facilitates the integration of wind farm into weak power grids by exchanging reactive power with network. Moreover, the wind farm controller has to be stable, fast and robust and the wind farm dispatch function has to guarantees that the local wind turbine controller can exchange the reactive power set point with network. This controller has been developed with the simulation tool DigSilent PowerFactory v14.1.

Francesc Girbau-Llistuella; Andreas Sumper; Francisco Daz-Gonzlez; Samuel Galceran-Arellano

2014-01-01T23:59:59.000Z

405

An overview of permeable reactive barriers for in situ sustainable groundwater remediation  

Science Journals Connector (OSTI)

Abstract Permeable reactive barriers (PRBs) are one of the innovative technologies widely accepted as an alternative to the pump and treat (P&T) for sustainable in situ remediation of contaminated groundwater. The concept of the technology involves the emplacement of a permeable barrier containing reactive materials across the flow path of the contaminated groundwater to intercept and treat the contaminants as the plume flows through it under the influence of the natural hydraulic gradient. Since the invention of \\{PRBs\\} in the early 1990s, a variety of materials has been employed to remove contaminants including heavy metals, chlorinated solvents, aromatic hydrocarbons, and pesticides. Contaminant removal is usually accomplished via processes such as adsorption, precipitation, denitrification and biodegradation. Despite wide acknowledgment, there are still unresolved issues about long term-performance of PRBs, which have somewhat affected their acceptability and full-scale implementation. The current paper presents an overview of the PRB technology, which includes the state of art, the merits and limitations, the reactive media used so far, and the mechanisms employed to transform or immobilize contaminants. The paper also looks at the design, construction and the long-term performance of PRBs.

Franklin Obiri-Nyarko; S. Johana Grajales-Mesa; Grzegorz Malina

2014-01-01T23:59:59.000Z

406

RAFT: A simulator for ReActive Flow and Transport of groundwater contaminants  

SciTech Connect (OSTI)

This report documents the use of the simulator RAFT for the ReActive flow and Transport of groundwater contaminants. RAFT can be used as a predictive tool in the design and analysis of laboratory and field experiments or it can be used for the estimation of model/process parameters from experiments. RAFT simulates the reactive transport of groundwater contaminants in one, two-, or three-dimensions and it can model user specified source/link configurations and arbitrary injection strategies. A suite of solvers for transport, reactions and regression are employed so that a combination of numerical methods best suited for a problem can be chosen. User specified coupled equilibrium and kinetic reaction systems can be incorporated into RAFT. RAFT is integrated with a symbolic computational language MAPLE, to automate code generation for arbitrary reaction systems. RAFT is expected to be used as a simulator for engineering design for field experiments in groundwater remediation including bioremediation, reactive barriers and redox manipulation. As an integrated tool with both the predictive ability and the ability to analyze experimental data, RAFT can help in the development of remediation technologies, from laboratory to field.

Chilakapati, A.

1995-07-01T23:59:59.000Z

407

On the estimation of the unknown reactivity coefficients in a CANDU reactor  

Science Journals Connector (OSTI)

A space-time kinetics based inverse architecture method is suggested to analyze the reactivity variations associated with power excursions in a generic CANDU reactor. It is intended to provide diagnosis tools to gain enhanced control thereby ensuring safe operation of the plant. A methodology for analyzing the data available from the in core flux detectors and extracting the unknown reactivity coefficients is presented. The proposed system uses a reference model in conjunction with an optimal estimator. The reference model is composed of a state space representation of the space-time dynamics of neutron flux in the core, based on modal expansion approximation, and a time domain optimal estimator filter. We investigated three different estimation techniques based on recursive prediction error method (RPEM), dual extended Kalman filter (DEKF), and joint extended Kalman filter (JEKF). We compared their applicability to the estimation of coolant-void dynamic reactivity in loss-of-coolant accident in a CANDU reactor. The state equations also include the characteristics of the detector responses. The thermal hydraulic models were not included in the calculations. Two different types of detectors are considered in this analysis, the over prompt responsive Platinum detector of the reactor shutdown systems, and the under delayed responsive Vanadium detector of the flux mapping system.

Lobat Tayebi; Daryoosh Vashaee

2013-01-01T23:59:59.000Z

408

Data:34a51fea-f6be-4efc-b190-e7cb13fb935a | Open Energy Information  

Open Energy Info (EERE)

a51fea-f6be-4efc-b190-e7cb13fb935a a51fea-f6be-4efc-b190-e7cb13fb935a No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2. Demand 3. Energy << Previous 1 2 3 Next >> Basic Information Utility name: The Potomac Edison Co (West Virginia) Effective date: 2012/04/02 End date if known: Rate name: PP (Large Primary) Sector: Commercial Description: AVAILABLE to single point of delivery for balanced three-phase power loads of not less than 3,000 kilovolt-amperes (1,000 kilovolt-amperes for Customers served here under prior to July 22, 1980) at prevailing voltages as designated by Company but not less than 15,000 volts. Also available at Company standard voltages between 10,000 and 15,000 volts where Company elects to supply service by one transformation from an adjacent transmission line operated at a voltage in excess of 100,000 volts. Service shall not be available for Standby or Maintenance Service such as that required for Alternative Generation Facilities. An Electric Service Agreement shall be executed.

409

Advancing Reactive Tracer Methods for Measurement of Thermal Evolution in Geothermal Reservoirs: Final Report  

SciTech Connect (OSTI)

The injection of cold fluids into engineered geothermal system (EGS) and conventional geothermal reservoirs may be done to help extract heat from the subsurface or to maintain pressures within the reservoir (e.g., Rose et al., 2001). As these injected fluids move along fractures, they acquire heat from the rock matrix and remove it from the reservoir as they are extracted to the surface. A consequence of such injection is the migration of a cold-fluid front through the reservoir (Figure 1) that could eventually reach the production well and result in the lowering of the temperature of the produced fluids (thermal breakthrough). Efficient operation of an EGS as well as conventional geothermal systems involving cold-fluid injection requires accurate and timely information about thermal depletion of the reservoir in response to operation. In particular, accurate predictions of the time to thermal breakthrough and subsequent rate of thermal drawdown are necessary for reservoir management, design of fracture stimulation and well drilling programs, and forecasting of economic return. A potential method for estimating migration of a cold front between an injection well and a production well is through application of reactive tracer tests, using chemical whose rate of degradation is dependent on the reservoir temperature between the two wells (e.g., Robinson 1985). With repeated tests, the rate of migration of the thermal front can be determined, and the time to thermal breakthrough calculated. While the basic theory behind the concept of thermal tracers has been understood for some time, effective application of the method has yet to be demonstrated. This report describes results of a study that used several methods to investigate application of reactive tracers to monitoring the thermal evolution of a geothermal reservoir. These methods included (1) mathematical investigation of the sensitivity of known and hypothetical reactive tracers, (2) laboratory testing of novel tracers that would improve method sensitivity, (3) development of a software tool for design and interpretation of reactive tracer tests and (4) field testing of the reactive tracer temperature monitoring concept.

Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; Laurence C. Hull; George D. Redden

2011-07-01T23:59:59.000Z

410

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. 2. Incorporation of Chlorine Emissions  

Science Journals Connector (OSTI)

As part of the State Implementation Plan for attaining the National Ambient Air Quality Standard for ozone, the Texas Commission of Environmental Quality has created a Highly Reactive Volatile Organic Compounds (HRVOC) Emissions Cap and Trade Program for ...

Linlin Wang; Tammy Thompson; Elena C. McDonald-Buller; David T. Allen

2007-02-27T23:59:59.000Z

411

Effect of specific surface area on oxygen storage capacity (OSC) and methane steam reforming reactivity of CeO2  

Science Journals Connector (OSTI)

It was found from the work that the specific surface area of ceria presents an important role on the oxygen storage capacity (OSC), the reactivity toward methane steam reforming, and the resistance toward carbon ...

W. Sutthisripok; S. Sattayanurak; L. Sikong

2008-10-01T23:59:59.000Z

412

Characterization of the reactive and dissociative behavior of transition metal oxide cluster ions in the gas phase  

Science Journals Connector (OSTI)

The reactive and dissociative behavior of molybdenum and tungsten oxide cluster ions has been studied in the gas phase using a triple quadrupole mass spectrometer. Cluster ions (MO3) n ...

Simin Maleknia; Jennifer Brodbelt

1991-05-01T23:59:59.000Z

413

Abstract--This paper proposes an effective VAR planning based on reactive power margin for the enhancement of dynamic  

E-Print Network [OSTI]

networks. Distributed generation based on renewable energy sources offers a promising solution1 Abstract-- This paper proposes an effective VAR planning based on reactive power margin for the enhancement of dynamic voltage stability in distribution networks with distributed wind generation

Pota, Himanshu Roy

414

Effect of temperature on reduction reactivity of oxygen carrier particles in a fixed bed chemical-looping combustor  

Science Journals Connector (OSTI)

In a chemical-looping combustor (CLC), gaseous fuel is oxidized...2...is separated from the exhaust gases during the combustion. In this study, NiO/bentonite particle...x formation during oxidation. Reactivity da...

Ho-Jung Ryu; Dal-Hee Bae; Gyoung-Tae Jin

2003-09-01T23:59:59.000Z

415

Comparison of Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI) Combustion in a Light-Duty Engine  

Broader source: Energy.gov [DOE]

CFD modeling was used to compare conventional diesel and dual-fuel Reactivity Controlled Compression Ignition combustion at US Tier 2 Bin 5 NOx levels, while accounting for Diesel Exhaust Fluid needed to meet NOx constraints with aftertreatment.

416

Glutathione-Dependent Generation of Reactive Oxygen Species by the Peroxidase-Catalyzed Redox Cycling of Flavonoids  

Science Journals Connector (OSTI)

They may also be anti-atherosclerotic as they prevent Cu2+-catalyzed low-density lipoprotein (LDL)1 oxidative modification by scavenging reactive oxygen species (ROS) and eliminating LDL peroxyl and alkoxyl radicals (2, 3). ... fisetin ...

Giuseppe Galati; Tom Chan; Bin Wu; Peter J. O'Brien

1999-05-19T23:59:59.000Z

417

Low dose ionizing radiation produces too few reactive oxygen species to directly affect antioxidant concentrations in cells  

Science Journals Connector (OSTI)

...Radiolysis products and internal dose distribution - Calculation of...products and internal distribution of doses Low dose ionizing radiation produces too few reactive oxygen...stress is the mechanism for a wide range of negative impacts on biota living...

2012-01-01T23:59:59.000Z

418

Surface Reactivity and Plasma Energetics of SiH Radicals during Plasma Deposition of Silicon-Based Materials  

Science Journals Connector (OSTI)

The surface reactivity of the SiH radical was measured during plasma deposition of various silicon-based materials using the imaging of radicals interacting with surfaces (IRIS) method. In this technique, spatially resolved laser-induced fluorescence (LIF)...

W. M. M. Kessels; Patrick R. McCurdy; Keri L. Williams; G. R. Barker; Vincent A. Venturo; Ellen R. Fisher

2002-02-09T23:59:59.000Z

419

Elastic properties of B-C-N films grown by N{sub 2}-reactive sputtering from boron carbide targets  

SciTech Connect (OSTI)

Boron-carbon-nitrogen films were grown by RF reactive sputtering from a B{sub 4}C target and N{sub 2} as reactive gas. The films present phase segregation and are mechanically softer than boron carbide films (a factor of more than 2 in Young's modulus). This fact can turn out as an advantage in order to select buffer layers to better anchor boron carbide films on substrates eliminating thermally induced mechanical tensions.

Salas, E.; Jimnez Riobo, R. J.; Jimnez-Villacorta, F.; Prieto, C. [Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientficas, Cantoblanco, 28049 Madrid (Spain)] [Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientficas, Cantoblanco, 28049 Madrid (Spain); Snchez-Marcos, J. [Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientficas, Cantoblanco, 28049 Madrid (Spain) [Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientficas, Cantoblanco, 28049 Madrid (Spain); Dept. Qumica-Fsica Aplicada, Universidad Autnoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Muoz-Martn, A.; Prieto, J. E.; Joco, V. [Centro de Microanlisis de Materiales, Universidad Autnoma de Madrid, Cantoblanco, 28049 Madrid (Spain)] [Centro de Microanlisis de Materiales, Universidad Autnoma de Madrid, Cantoblanco, 28049 Madrid (Spain)

2013-12-07T23:59:59.000Z

420

Numerical solution for stochastic point-kinetics equations with sinusoidal reactivity in dynamical system of nuclear reactor  

Science Journals Connector (OSTI)

In this present analysis, the numerical simulation methods are applied to calculate the solution for stochastic point-kinetic equations with sinusoidal reactivity in dynamical system of nuclear reactor. The resulting system of differential equations is solved for each time step-size. Using experimental data, the methods are investigated over initial conditions and with sinusoidal reactivity. The computational results designate that these numerical approximation methods are straightforward, effective and easy for solving stochastic point-kinetic equations.

S. Saha Ray; A. Patra

2013-01-01T23:59:59.000Z

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We encourage you to perform a real-time search of NLEBeta
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421

Property:OpenEI/UtilityRate/DemandReactivePowerCharge | Open Energy  

Open Energy Info (EERE)

DemandReactivePowerCharge DemandReactivePowerCharge Jump to: navigation, search This is a property of type Number. Pages using the property "OpenEI/UtilityRate/DemandReactivePowerCharge" Showing 25 pages using this property. (previous 25) (next 25) 0 00b7ccdc-c7e0-40d2-907f-acb6ae828292 + 0.25 + 00e0b930-90c6-43c2-971a-91dade33f76a + 0.32 + 00e2a43f-6844-417a-b459-edf32d33b051 + 0.0092 + 00fb7dca-d0a6-4b11-b7de-791c2fb9f2e1 + 2.7 + 01a64840-7edc-4193-8073-ed5604e098ca + 0.83 + 035f3d22-3650-47cc-a427-bb35170db128 + 0.3 + 042f06f4-6a5b-424f-a31f-8e1c5a838700 + 0.27 + 0479cd85-894d-412b-b2ce-3b96912e9014 + 0.2 + 04bab597-fe1e-4507-8d90-144980aeba73 + 0.3 + 05211bd7-b6d3-425c-9f96-0845b7828c3c + 0.27 + 052fbe23-ac02-4195-b76d-e572cc53f669 + 0.68 + 05490683-8158-4d2f-ad96-66d5e4980890 + 0.25 +

422

Reactivity Accountability Attributed to Reflector Poisons in the High Flux Isotope Reactor  

SciTech Connect (OSTI)

The objective of this study is to develop a methodology to predict the reactivity impact as a function of outage time between cycles of 3He, 6Li, and other poisons in the High Flux Isotope Reactor s (HFIR) beryllium reflector. The reactivity worth at startup of the HFIR has been incorrectly predicted in the past after the reactor has been shut-down for long periods of time. The incorrect prediction was postulated to be due to the erroneous calculation of 3He buildup in the beryllium reflector. It is necessary to develop a better estimate of the start-of-cycle symmetric critical control element positions since if the estimated and actual symmetrical critical control element positions differ by more than $1.55 in reactivity (approximately one-half inch in control element startup position), HFIR is to be shutdown and a technical evaluation is performed to resolve the discrepancy prior to restart. 3He is generated and depleted during operation, but during an outage, the depletion of 3He ceases because it is a stable isotope. 3He is born from the radioactive decay of tritium, and thus the concentration of 3He increases during shutdown. SCALE, specifically the TRITON and CSAS5 control modules including the KENO V.A, COUPLE, and ORIGEN functional modules were utilized in this study. An equation relating the down time (td) to the change in symmetric control element position was generated and validated against measurements for approximately 40 HFIR operating cycles. The newly-derived correlation was shown to improve accuracy of predictions for long periods of down time.

Chandler, David [ORNL; Maldonado, G Ivan [ORNL; Primm, Trent [ORNL

2009-12-01T23:59:59.000Z

423

Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas  

DOE Patents [OSTI]

In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

Durai-Swamy, Kandaswamy (Culver City, CA)

1982-01-01T23:59:59.000Z

424

Reactivity of tributyl phosphate degradation products with nitric acid: Relevance to the Tomsk-7 accident  

SciTech Connect (OSTI)

The reaction of a degraded tributyl phosphate (TBP) solvent with nitric acid is thought to have caused the chemical explosion at the Tomsk-7 reprocessing plant at Tomsk, Russia in 1993. The estimated temperature of the organic layer was not high eneough to cause significant reaction of nitric acid with TBP or hydrocarbon diluent compounds. A more reactive organic compound was likely present in the organic layer that reacted with sufficient heat generation to raise the temperature to the point where an autocatalytic oxidation of the organic solvent was initiated. Two of the most likely reactive compounds that are present in degraded TBP solvents are n-butanol and n-butyl nitrate. The reactions of these compounds with nitric acid are the subject of this study. The objective of laboratory-scale tests was to identify chemical reactions that occur when n-butanol and n-butyl nitrate contact heated nitric acid solutions. Reaction products were identified and quantitified, the temperatures at which these reactions occur and heats of reaction were measured, and reaction variables (temperature, nitric acid concentration, organic concentration, and reaction time) were evaluated. Data showed that n-butyl nitrate is less reactive than n-butanol. An essentially complete oxidation reaction of n-butanol at 110-120 C produced four major reaction products. Mass spectrometry identified the major inorganic oxidation products for both n-butanol and n-butyl nitrate as nitric oxide and carbon dioxide. Calculated heats of reaction for n-butanol and n-butyl nitrate to form propionic acid, a major reaction product, are -1860 cal/g n-butanol and -953 cal/g n-butyl nitrate. These heats of reaction are significant and could have raised the temperature of the organic layer in the Tomsk-7 tank to the point where autocatalytic oxidation of other organic compounds present resulted in an explosion.

Barney, G.S.; Cooper, T.D. [Westinghouse Hanford Company, Richland, WA (United States)

1995-12-31T23:59:59.000Z

425

Dynamics of confined reactive water in smectite clay-zeolite composites  

SciTech Connect (OSTI)

The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

Pitman, Michael C. [IBM Watson Research Center, Yorktown Heights, NY; Van Duin, Adri C. T. [Pennsylvania State University, University Park, PA

2012-01-01T23:59:59.000Z

426

Dynamics of confined reactive water in Smectic clay-zeolite composites.  

SciTech Connect (OSTI)

The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

Pitman, Michael C. [IBM Watson Research Center, Yorktown Heights, NY; Van Duin, Adri C. T. [Pennsylvania State University, University Park, PA

2012-01-01T23:59:59.000Z

427

Early Breakthrough of Molybdenum and Uranium in a Permeable Reactive Barrier  

Science Journals Connector (OSTI)

S.M. Stoller Corporation, 2597 B 3/4 Road, Grand Junction, Colorado 81503, U.S. Environmental Protection Agency Region 8, Federal Facilities Program, Office of Environmental Protection and Remediation, 999 18th Street, Suite 300, Denver, Colorado 80202, and Cotter Corporation, 7800 East Dorado Place, Englewood, Colorado 80111 ... A permeable reactive barrier (PRB) using zerovalent iron (ZVI) was installed at a site near Caon City, CO, to treat molybdenum (Mo) and uranium (U) in groundwater. ... Uranium (U) mill tailings in northern Saskatchewan, Canada, contain elevated concentrations of molybdenum (Mo). ...

Stan J. Morrison; Paul S. Mushovic; Preston L. Niesen

2006-02-14T23:59:59.000Z

428

Chemical filters by non-thermal atmospheric pressure plasmas for reactive fields  

Science Journals Connector (OSTI)

Non-thermal plasmas in electrode configurations are designed in this study and investigated at atmospheric pressure for generation of reactive fields. A combination of insulated wire electrodes and bare metal wire electrodes makes it possible to obtain a filter-like assembly of microplasmas, even in ambient air or in aqueous solutions. Oxidation and reduction fields are obtained by controlling the gas supply of hydrogen, oxygen, and water vapor, and these fields benefit various functional processes such as recycling CO2, decomposing organic molecules, and increasing the work function on metal surfaces.

Osamu Sakai; Tadasuke Morita; Yoshihiko Ueda; Noriaki Sano; Kunihide Tachibana

2011-01-01T23:59:59.000Z

429

Reactive Flow Modeling of Liquid Explosives via ALE3D/Cheetah Simulations  

SciTech Connect (OSTI)

We carried out reactive flow simulations of liquid explosives such as nitromethane using the hydrodynamic code ALE3D coupled with equations of state and reaction kinetics modeled by the thermochemical code Cheetah. The simulation set-up was chosen to mimic cylinder experiments. For pure unconfined nitromethane we find that the failure diameter and detonation velocity dependence on charge diameter are in agreement with available experimental results. Such simulations are likely to be useful for determining detonability and failure behavior for a wide range of experimental conditions and explosive compounds.

Kuo, I W; Bastea, S; Fried, L E

2010-03-10T23:59:59.000Z

430

Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance  

DOE Patents [OSTI]

Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.

Gupta, Raghubir P. (Durham, NC); Gangwal, Santosh K. (Durham, NC); Jain, Suresh C. (Morgantown, WV)

1993-01-01T23:59:59.000Z

431

Laboratory Study on Gasification Reactivity of Coals and Petcokes in CO2/Steam at High Temperatures  

Science Journals Connector (OSTI)

A diffusion term associated with the carbon structure may be needed for modelling the gasification behaviors of the petcoke-like materials. ... Gasification technology is used to convert feedstocks, not only coal but also petcoke and other carbonaceous materials, to fuel gas or syngas,(1, 2) which can be used to generate electricity and heat or to synthesize liquid fuel and chemicals. ... It is certain that petcoke, derived from oil refinery coke units or other cracking processes, has a much lower gasification reactivity than coal chars, especially at low temperatures. ...

Liwei Ren; Jianli Yang; Feng Gao; Jinding Yan

2013-07-30T23:59:59.000Z

432

Physical Properties and Composition Effects on the Reactivity of Calcium-Based Sulfur Sorbents  

Science Journals Connector (OSTI)

A detailed comparison between agglomerated pellets of limestone and commercial-grade plaster of Paris was conducted to test the reactivity of the pellets with H2S over three cycles of sulfidation and regeneration. ... 19 The presumed effects from the iron oxide are partially supported by observations made of the limestone pellets after the multicycle tests that revealed small, circular, brown spots on the surface of the pellets, which were thought to be iron oxide deposits consolidating on the surface. ... distribution of an agglomerated powder is discussed with respect to the size of the multiple-particle packing unit, consolidation forces, and phenomena occurring during sintering. ...

D. J. Hasler; T. D. Wheelock; L. K. Doraiswamy; K. P. Constant

2007-08-02T23:59:59.000Z

433

Permanganate Treatment of DNAPLs in Reactive Barriers and Source Zone Flooding Schemes  

SciTech Connect (OSTI)

In situ oxidation with potassium permanganate has been widely evaluated, as a potential remediation method for dissolved or pure DNAPL in groundwater system. The goals of this study are (1) to elucidate the basic mechanisms by which potassium permanganate oxidizes common chlorinated solvents, various constituents in aqueous solution, and porous medium solids, and (2) to assess the potential for chemical oxidation by potassium permanganate to serve as a remedial scheme involving either source zone flooding or reactive barriers. The study is organized with a laboratory component that looks generally at the basic reaction processes and kinetics, and a theoretical component that is developing modeling tools appropriate for designing systems under field conditions.

Schwartz, Frank W.; Zhang, Hubao

2000-06-30T23:59:59.000Z

434

Uptake of Reactive Black 5 by pumice and walnut activated carbon: Chemistry and adsorption mechanisms  

Science Journals Connector (OSTI)

Abstract The potential of using pumice and walnut wood activated carbon as low-cost adsorbents for the removal of the diazo dye Reactive Black 5 (RB5) from aqueous solutions was investigated. The Langmuir isotherm fit to the data specified the presence of two different natures of adsorption sites with different binding energies on the AC-W surface. Kinetic modelling showed that the adsorption behaviour and mechanism of RB5 for both adsorbents is believed to happen via surface adsorption followed by diffusion into the pores of the AC-W and pumice. The main adsorption mechanisms are hydrogen bonding, electrostatic bonding and n? interactions.

Behzad Heibati; Susana Rodriguez-Couto; Abdeltif Amrane; Mohd. Rafatullah; Alaa Hawari; Mohammad A. Al-Ghouti

2014-01-01T23:59:59.000Z

435

Systems and methods for reactive distillation with recirculation of light components  

SciTech Connect (OSTI)

Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

2011-07-26T23:59:59.000Z

436

Ferrocenylketene and Ferrocenyl-1,2-bisketenes:? Direct Observation and Reactivity Measurements  

Science Journals Connector (OSTI)

36050, Mexico ... To evaluate the properties of ferrocenylketene (1), its structure and energy as well as those of phenylketene (10) and the corresponding alkenes were calculated at the B3LYP/6-311G(d,p)//B3LYP/6-311G(d,p) level, using Gaussian 03. ... The greater reactivity of 18 to reform the cyclobutenedione compared to the diphenyl analogue is consistent with the known acceleration of ring closure of aryl-substituted 1,2-bisketenes by electron-donating aryl groups, with a dependence on ?+ of substituents R for RC6H4, which stabilize the electron-deficient cyclobutenediones with ?+ of ?1.10. ...

Angelica Aguilar-Aguilar; Annette D. Allen; Eduardo Pea Cabrera; Andrei Fedorov; Nanyan Fu; Huda Henry-Riyad; Jrg Leuninger; Ulrich Schmid; Thomas T. Tidwell; Rishi Verma

2005-10-12T23:59:59.000Z

437

Fundamental evaluation of LSI`s using anisotropic reactive ion etching  

SciTech Connect (OSTI)

An electrical and physical evaluation of CMOS LSI`s with multiple-metal layers exposed using a reactive ion etcher (RIE), is described. Anisotropic etching is executed using a parallel plate type reactive ion etcher with 3KV/mm sheath voltage grade and a CF4/02 gas mixture. The formation of small vertical protrusions, known as ``RIE grass``, on the Si-surface is prevented by using a Teflon plate and aluminum foil which covers over the cathode plate and LSI package, except for the LSI chip, itself. High density CMOS LSI`s with 0.5{micro}m design rules and three metal layers, each of which is composed of a sandwiched structure of aluminum between refractory metals (Ti, TiN), are used for an electrical and physical evaluation. Three important results, exhibiting no degradation of transistor characteristics, are discussed: a 10% speed up in circuit operation resulting from removing the isolation layer, a complex change of leakage current value resulting from very small RIE grass, and a change of metal line constitution resulting from removal of the upper refractory metal layer. The absence of transistor degradation shows that RIE is an effective tool for exposing multiple layers of metal lines of LSI`s without destroying any of the electrical functionality of a device. This technique is applied to the failure analysis of a CMOS LSI having an underlying pattern defect. By using an electron beam tester, the complete analysis is executed.

Sanada, M.; Suzuki, S.; Numaziri, T.; Omata, T. [NEC Corp., Kanagawa (Japan); Yoshida, N. [NSC Corp., Tokyo (Japan)

1995-12-31T23:59:59.000Z

438

Evaluation of the coolant reactivity coefficient influence on the dynamic response of a small LFR system  

SciTech Connect (OSTI)

An assessment of the coolant reactivity feedback influence on a small Lead-cooled Fast Reactor (LFR) dynamics has been made aimed at providing both qualitative and quantitative insights into the system transient behavior depending on the sign of the above mentioned coefficient. The need of such an investigation has been recognized since fast reactors cooled by heavy liquid metals show to be characterized by a strong coupling between primary and secondary systems. In particular, the coolant density and radial expansion coefficients have been attested to play a major role in determining the core response to any perturbed condition on the Steam Generator (SG) side. The European Lead-cooled System (ELSY)-based demonstrator (DEMO) has been assumed as the reference LFR case study. As a first step, a zero-dimensional dynamics model has been developed and implemented in MATLAB/SIMULINK{sup R} environment; then typical transient scenarios have been simulated by incorporating the actual negative lead density reactivity coefficient and its opposite. In all the examined cases results have shown that the reactor behaves in a completely different way when considering a positive coolant feedback instead of the reference one, the system free dynamics resulting moreover considerably slower due to the core and SG mutually conflicting reactions. The outcomes of the present analysis may represent a useful feedback for both the core and the control system designers. (authors)

Lorenzi, S.; Bortot, S.; Cammi, A.; Ponciroli, R. [Dept. of Energy, Nuclear Engineering Div. - CeSNEF, Politecnico di Milano, Via La Masa 34, 20156 Milano (Italy)

2012-07-01T23:59:59.000Z

439

On RELAP5-simulated High Flux Isotope Reactor reactivity transients: Code change and application  

SciTech Connect (OSTI)

This paper presents a new and innovative application for the RELAP5 code (hereafter referred to as the code''). The code has been used to simulate several transients associated with the (presently) draft version of the High-Flux Isotope Reactor (HFIR) updated safety analysis report (SAR). This paper investigates those thermal-hydraulic transients induced by nuclear reactivity changes. A major goal of the work was to use an existing RELAP5 HFIR model for consistency with other thermal-hydraulic transient analyses of the SAR. To achieve this goal, it was necessary to incorporate a new self-contained point kinetics solver into the code because of a deficiency in the point-kinetics reactivity model of the Mod 2.5 version of the code. The model was benchmarked against previously analyzed (known) transients. Given this new code, four event categories defined by the HFIR probabilistic risk assessment (PRA) were analyzed: (in ascending order of severity) a cold-loop pump start; run-away shim-regulating control cylinder and safety plate withdrawal; control cylinder ejection; and generation of an optimum void in the target region. All transients are discussed. Results of the bounding incredible event transient, the target region optimum void, are shown. Future plans for RELAP5 HFIR applications and recommendations for code improvements are also discussed.

Freels, J.D.

1993-01-01T23:59:59.000Z

440

On RELAP5-simulated High Flux Isotope Reactor reactivity transients: Code change and application  

SciTech Connect (OSTI)

This paper presents a new and innovative application for the RELAP5 code (hereafter referred to as ``the code``). The code has been used to simulate several transients associated with the (presently) draft version of the High-Flux Isotope Reactor (HFIR) updated safety analysis report (SAR). This paper investigates those thermal-hydraulic transients induced by nuclear reactivity changes. A major goal of the work was to use an existing RELAP5 HFIR model for consistency with other thermal-hydraulic transient analyses of the SAR. To achieve this goal, it was necessary to incorporate a new self-contained point kinetics solver into the code because of a deficiency in the point-kinetics reactivity model of the Mod 2.5 version of the code. The model was benchmarked against previously analyzed (known) transients. Given this new code, four event categories defined by the HFIR probabilistic risk assessment (PRA) were analyzed: (in ascending order of severity) a cold-loop pump start; run-away shim-regulating control cylinder and safety plate withdrawal; control cylinder ejection; and generation of an optimum void in the target region. All transients are discussed. Results of the bounding incredible event transient, the target region optimum void, are shown. Future plans for RELAP5 HFIR applications and recommendations for code improvements are also discussed.

Freels, J.D.

1993-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Active and reactive power ripple minimization in direct power control of matrix converter-fed DFIG  

Science Journals Connector (OSTI)

Abstract Despite the advantages of matrix converters (MCs) compared with standard voltage source converters (VSCs), all of the direct power control (DPC) strategies for doubly fed induction generator (DFIG) reported in the literature, only utilize VSCs. In this paper, the influence of MC voltage vectors on active and reactive powers variation is investigated. Compared with VSCs, \\{MCs\\} generate higher number of voltage vectors. Using this inherent advantage of MC, the main contribution of this paper is to reduce large active and reactive power ripples which is one of the main drawbacks of conventional DPC method. Utilizing a wide range of voltage vectors with different amplitudes, a new switching table is derived which using this table, not only large power ripple is compensated but also, a close to unity input power factor for MC can be achieved. In the other word, the presented scheme adds the advantages of MC and DPC together. Moreover, Owing to the operation of MC in direct acac form, the presented scheme effectively eliminates the need for the grid side converter used in conventional DPC, which has a complicated control method is eliminated. Simulation results show the effectiveness of the proposed method and have a reasonable correspondence with theoretical and mathematical analysis.

Arjang Yousefi-Talouki; Edris Pouresmaeil; Bo Nrregaard Jrgensen

2014-01-01T23:59:59.000Z

442

Fe/Si(001) Ferromagnetic Layers: Reactivity, Local Atomic Structure and Magnetism  

SciTech Connect (OSTI)

Ultrathin ferromagnetic Fe layers on Si(001) have recently been synthesized using the molecular beam epitaxy (MBE) technique, and their structural and magnetic properties, as well as their interface reactivity have been investigated. The study was undertaken as function of the amount of Fe deposited and of substrate temperature. The interface reactivity was characterized by Auger electron spectroscopy (AES). The surface structure was characterized by low-energy electron diffraction (LEED). The magnetism was investigated by magneto-optical Kerr effect (MOKE). A higher deposition temperature stabilizes a better surface ordering, but it also enhances Fe and Si interdiffusion and it therefore decreases the magnetism. Despite the rapid disappearance of the long range order with Fe deposition at room temperature, the material exhibits a significant uniaxial in-plane magnetic anisotropy. For the Fe deposition performed at high temperature (500 deg. C), a weak ferromagnetism is still observed, with saturation magnetization of about 10% of the value obtained previously. MOKE studies allowed inferring the main properties of the distinct formed layers.

Lungu, G. A.; Costescu, R. M.; Husanu, M. A.; Gheorghe, N. G. [National Institute of Materials Physics, Atomistilor 105bis, 077125 Magurele-Ilfov (Romania)

2011-10-03T23:59:59.000Z

443

Calcium sulphide in FBC boilers and its fate using liquid water reactivation  

Science Journals Connector (OSTI)

CaSO4 and CaS are the only sulphur compounds found in solid residues from the sulphation process in FBC boilers. Early results indicated very high levels of CaS in ashes from small-scale FBC pilot plant combustors. However, these results were due to the presence of high levels of char carbon in standpipes and cyclones. In commercial-scale FBC boilers, CaS concentrations are normally less than 0.1% although levels of up to 0.6% are seen in some ashes. Sometimes elevated CaS concentrations are found in deposits in CFBC boilers firing high levels of petroleum coke (although this is unusual), and in ashes from stripper coolers. In both cases, this can be minimized by proper design. CaS can also be deliberately introduced into FBC boilers with the char from a topping cycle gasifier. Test work using hydration in a similar manner to a reactivation strategy has been shown to be ineffective for sulphide destruction when used directly with char from a topping cycle gasifier. Instead it is recommended that reactivation be used on ashes from the CFBC boiler receiving the sulphided char residues. This guarantees overall high sorbent utilization and the effective elimination of sulphides in the ashes finally discharged from the CFBC boiler.

E.J. Anthony; L. Jia; A.P. Iribarne; G. Welford; J. Wang; O. Trass

2006-01-01T23:59:59.000Z

444

Gasoline conversion: reactivity towards cracking with equilibrated FCC and ZSM-5 catalysts  

Science Journals Connector (OSTI)

Cracking of a straight-run FCC gasoline using either a steamed ZSM-5 catalyst or a base, FCC equilibrium, catalyst shows that the only significantly reactive components in the gasoline fraction are normal and branched olefins with a carbon number of seven and higher. Overall, the reactivity of gasoline is one to two orders of magnitude smaller than that of a normal FCC feedstock. The ZSM-5 catalyst produces light olefins (LPG-range and some ethene) through cracking of the gasoline-range olefins. The base catalyst produces these light olefins in lower amounts than ZSM-5 does. Further, the base catalyst produces small amounts of paraffins and products that are heavier than the gasoline feedstock. The overall reason for the differences between the two catalysts is a shape-selective mechanism; in the small pores of ZSM-5 only monomolecular cracking reactions take place, while in the larger pores of the FCC base catalyst also a bimolecular reaction mechanism is operative. As a result of the absence of bimolecular reactions, with ZSM-5, the average size of the products and the amount of hydrogen transfer products is smaller than with the base catalyst. On the other hand, because of the relatively small pore size of ZSM-5, the interaction between the catalytic surface of ZSM-5 and the reactants is larger resulting in a higher conversion of linear olefins and a higher production of ethene than with the base catalyst.

M.A. den Hollander; M. Wissink; M. Makkee; J.A. Moulijn

2002-01-01T23:59:59.000Z

445

Effect of burnup on ACR-700 3-D reactivity devices cross sections  

SciTech Connect (OSTI)

Full core analysis of typical power reactors being generally performed using few groups diffusion theory, it is necessary to generate beforehand, using a lattice code, the required few group cross sections and diffusion coefficients associated with each region in the core. For CANDU-type reactors including the Advanced CANDU Reactor (ACR), the problem is more complex because these reactors contain vertical reactivity devices that are located between two horizontal fuel bundles. The usual calculation scheme relies in this case on a 2-D fuel cell calculation to generate the few group fuel properties and on a 3-D supercell calculation for the analysis of the reactivity devices present in the core. Because of its complexity, the supercell calculations are generally performed using simplified fuel geometries. In this paper, the different stages involved in the reactor physics simulations for ACR will be explained focusing particularly on a study of the burnup dependence of the incremental cross section associated with zone control units (ZCU). The use of these incremental cross sections for finite core calculations will also be presented. (authors)

Dahmani, M.; Marleau, G.; Varin, E. [Institut de Genie Nucleaire, Ecole Polytechnique de Montreal, 2900 Boulevard Edouard-Montpetit, Montreal, Que. H3T 1J4 (Canada)

2006-07-01T23:59:59.000Z

446

A reaction-based paradigm to model reactive chemical transport in groundwater with general kinetic and equilibrium reactions  

SciTech Connect (OSTI)

This paper presents a reaction-based water quality transport model in subsurface flow systems. Transport of chemical species with a variety of chemical and physical processes is mathematically described by M partial differential equations (PDEs). Decomposition via Gauss-Jordan column reduction of the reaction network transforms M species reactive transport equations into two sets of equations: a set of thermodynamic equilibrium equations representing NE equilibrium reactions and a set of reactive transport equations of M-NE kinetic-variables involving no equilibrium reactions (a kinetic-variable is a linear combination of species). The elimination of equilibrium reactions from reactive transport equations allows robust and efficient numerical integration. The model solves the PDEs of kinetic-variables rather than individual chemical species, which reduces the number of reactive transport equations and simplifies the reaction terms in the equations. A variety of numerical methods are investigated for solving the coupled transport and reaction equations. Simulation comparisons with exact solutions were performed to verify numerical accuracy and assess the effectiveness of various numerical strategies to deal with different application circumstances. Two validation examples involving simulations of uranium transport in soil columns are presented to evaluate the ability of the model to simulate reactive transport with complex reaction networks involving both kinetic and equilibrium reactions.

Zhang, Fan [ORNL; Yeh, Gour-Tsyh [University of Central Florida, Orlando; Parker, Jack C [ORNL; Brooks, Scott C [ORNL; Pace, Molly [ORNL; Kim, Young Jin [ORNL; Jardine, Philip M [ORNL; Watson, David B [ORNL

2007-01-01T23:59:59.000Z

447

Hybrid high direct current circuit interrupter  

DOE Patents [OSTI]

A device and a method are disclosed for interrupting very high direct currents (greater than 100,000 amperes) and simultaneously blocking high voltages (greater than 600 volts). The device utilizes a mechanical switch to carry very high currents continuously with low loss and a silicon controlled rectifier (SCR) to bypass the current around the mechanical switch while its contacts are separating. A commutation circuit, connected in parallel with the SCR, turns off the SCR by utilizing a resonant circuit to divert the SCR current after the switch opens. 7 figs.

Rockot, J.H.; Mikesell, H.E.; Jha, K.N.

1998-08-11T23:59:59.000Z

448

Hybrid high direct current circuit interrupter  

DOE Patents [OSTI]

A device and a method for interrupting very high direct currents (greater than 100,000 amperes) and simultaneously blocking high voltages (greater than 600 volts). The device utilizes a mechanical switch to carry very high currents continuously with low loss and a silicon controlled rectifier (SCR) to bypass the current around the mechanical switch while its contacts are separating. A commutation circuit, connected in parallel with the SCR, turns off the SCR by utilizing a resonant circuit to divert the SCR current after the switch opens.

Rockot, Joseph H. (N. Huntingdon, PA); Mikesell, Harvey E. (McMurray, PA); Jha, Kamal N. (Bethel Park, PA)

1998-01-01T23:59:59.000Z

449

Note: Switch-Mode Hybrid Current Controllers for Quantum Cascade Lasers  

SciTech Connect (OSTI)

Chemical sensing in the mid-infrared has been revolutionized by the advent of quantum cascade lasers. Their higher current and voltage demands compared to laser diodes however, negatively impact size, weight and power footprint for fieldable systems, particularly in hot environments. This letter presents a switch-mode/linear hybrid controller design, furnishing low-noise drive current up to 2 amperes at compliance voltages up to 15 volts, with noise levels close to the Johnson noise of the internal resistors. Current modulation from near zero to 1.8 Amps is also demonstrated at frequencies up to a kilohertz.

Taubman, Matthew S.

2013-01-07T23:59:59.000Z

450

Algorithm for calculation of characterisitcs of thermionic electricity-generating assemblies  

SciTech Connect (OSTI)

A numerical algorithm has been developed for calculating the kinetic characteristics of electricity-generating coaxial cells and assemblies; it is based on separate solution of the equations describing the thermal and electrical processes with their subsequent coordination by way of the volt-ampere characteristics of an elementary thermionic converter by means of piecewise-linear approximation of the nonlinear characteristics at the operating points. The possibilities and advantages of the proposed calculation algorithm for investigation of the transients occurring in the course of operation of the electricity generating assemblies (EGA) are indicated. Results are reported for sample calculations of several EGA static and kinetic characteristics. 10 refs.

Babushkin, Yu.V.; Mendel'baum, M.A.; Savinov, A.P.; Sinyavskii, V.V.

1981-01-01T23:59:59.000Z

451

High Power, High Voltage FETs in Linear Applications: A User's Perspective  

SciTech Connect (OSTI)

The specifications of the current crop of highpower, high-voltage field-effect transistors (FETs) can lure a designer into employing them in high-voltage DC equipment. Devices with extremely low on-resistance and very high power ratings are available from several manufacturers. However, our experience shows that high-voltage, linear operation of these devices at near-continuous duty can present difficult reliability challenges at stress levels well-below their published specifications. This paper chronicles the design evolution of a 600 volt, 8 ampere shunt regulator for use with megawatt-class radio transmitters, and presents a final design that has met its reliability criteria.

N. Greenough, E. Fredd, S. DePasquale

2009-09-21T23:59:59.000Z

452

Definition: System Operating Limit | Open Energy Information  

Open Energy Info (EERE)

Operating Limit Operating Limit Jump to: navigation, search Dictionary.png System Operating Limit The value (such as MW, MVar, Amperes, Frequency or Volts) that satisfies the most limiting of the prescribed operating criteria for a specified system configuration to ensure operation within acceptable reliability criteria. System Operating Limits are based upon certain operating criteria. These include, but are not limited to: Facility Ratings (Applicable pre- and post- Contingency equipment or facility ratings), Transient Stability Ratings (Applicable pre- and post-Contingency Stability Limits), Voltage Stability Ratings (Applicable pre- and post- Contingency Voltage Stability), System Voltage Limits (Applicable pre- and post- Contingency Voltage Limits)[1] Also Known As SOL

453

Measurement of the atmospheric reactivity of emissions from gasoline and alternative-fueled vehicles: Assessment of available methodologies. Part 1. Indoor smog chamber study of reactivity. Final report for the first year, January 1-December 31, 1993  

SciTech Connect (OSTI)

A set of multiple indoor smog chambers were used to measure the increase in smog formation (smog = NO oxidation + O3 formation) from a series of individual test volatile organic compounds (VOC`s), as well as carbon monoxide (CO), when they were added to a standard urban mixture and irradiated for 10-12 hours with a solar simulator. The chambers and the mixtures were designed to simulate the Carter incremental reactivity concept that is being used in California. The test compounds covered a wide range of mechanistic uncertainties and predicted reactivities (reactivity is the increase in smog divided by the amount of test compound added). Also, the chambers were used to test the recently developed Integrated Empirical Rate (IER) Model which predicts that the smog formation of a mixture is constant and independent of NOx in the so-called light-limited regime.

Kelly, N.A.; Wang, P.; Japar, S.M.; Hurley, M.D.; Wallington, T.J.

1994-06-30T23:59:59.000Z

454

Electronic Structure and Reactivity of Isomeric Oxo-Mn(V) Porphyrins:? Effects of Spin-State Crossing and pKa Modulation  

Science Journals Connector (OSTI)

Filippo De Angelis ,* Ning Jin , Roberto Car , and John T. Groves * ... 1,2 Reactive oxomanganese complexes are thought to participate in the photosynthetic oxidation of water to produce oxygen. ... In recent years, fast kinetic probes of the reactivity of oxometalloporphyrin complexes13,14 and the emerging power of chemical computation in such systems15-25 have begun to provide a new level of understanding of the nature and reactivity of such oxometal species. ...

Filippo De Angelis; Ning Jin; Roberto Car; John T. Groves

2006-04-21T23:59:59.000Z

455

On a Highly Reactive Fe2O3/Al2O3 Oxygen Carrier for in Situ Gasification Chemical Looping Combustion  

Science Journals Connector (OSTI)

On a Highly Reactive Fe2O3/Al2O3 Oxygen Carrier for in Situ Gasification Chemical Looping Combustion ... State

Daofeng Mei; Alberto Abad; Haibo Zhao; Juan Adnez; Chuguang Zheng

2014-10-13T23:59:59.000Z

456

Surface reactivity and oxygen migration in amorphous indium-gallium-zinc oxide films annealed in humid atmosphere  

SciTech Connect (OSTI)

An isotope tracer study, i.e., {sup 18}O/{sup 16}O exchange using {sup 18}O{sub 2} and H{sub 2}{sup 18}O, was performed to determine how post-deposition annealing (PDA) affected surface reactivity and oxygen diffusivity of amorphous indiumgalliumzinc oxide (a-IGZO) films. The oxygen tracer diffusivity was very high in the bulk even at low temperatures, e.g., 200?C, regardless of PDA and exchange conditions. In contrast, the isotope exchange rate, dominated by surface reactivity, was much lower for {sup 18}O{sub 2} than for H{sub 2}{sup 18}O. PDA in a humid atmosphere at 400?C further suppressed the reactivity of O{sub 2} at the a-IGZO film surface, which is attributable to OH-terminated surface formation.

Watanabe, Ken, E-mail: Watanabe.Ken@nims.go.jp [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan)] [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan); Lee, Dong-Hee [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Sakaguchi, Isao; Haneda, Hajime [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan)] [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Nomura, Kenji [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)] [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Kamiya, Toshio [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Hosono, Hideo [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Ohashi, Naoki, E-mail: Ohashi.Naoki@nims.go.jp [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)

2013-11-11T23:59:59.000Z

457

Tips on Homeowner Education | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Reference In Reference Tips on Homeowner Education November 22, 2013 Figure 16. How will a new homeowner be able to navigate and successfully interact with the advanced systems of a high performance home? Pictured is the Mike and Deborah Overmyer Residence in Golden, Colorado; Designer: Dr. Phil Tabb, Boulder Architect; Style: 3-story mountain contemporary; Year built: 1997, 2480 square feet; Utility: no utility bills, off utility grid. Features: photovoltaic powered house; house is over a mile to the nearest power line; 14 Shell M75 photovoltaic panels; mounting of PV panels provides for changing the tilt angle; power at a nominal 24 volts runs through an Amanda Power Technology charge controller and to the battery bank; twenty 6 volt 220 ampere-hour Trojan T-105 batteries connected 4 in

458

Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior in Complex Interfacial Systems. Final Technical Report  

SciTech Connect (OSTI)

This research program explored the efficacy of using molecular-level manipulation, imaging and scanning tunneling spectroscopy in conjunction with supersonic molecular beam gas-surface scattering to significantly enhance our understanding of chemical processes occurring on well-characterized interfaces. One program focus was on the spatially-resolved emergent behavior of complex reaction systems as a function of the local geometry and density of adsorbate-substrate systems under reaction conditions. Another focus was on elucidating the emergent electronic and related reactivity characteristics of intentionally constructed single and multicomponent atom- and nanoparticle-based materials. We also examined emergent chirality and self-organization in adsorbed molecular systems where collective interactions between adsorbates and the supporting interface lead to spatial symmetry breaking. In many of these studies we combined the advantages of scanning tunneling (STM) and atomic force (AFM) imaging, scanning tunneling local electronic spectroscopy (STS), and reactive supersonic molecular beams to elucidate precise details of interfacial reactivity that had not been observed by more traditional surface science methods. Using these methods, it was possible to examine, for example, the differential reactivity of molecules adsorbed at different bonding sites in conjunction with how reactivity is modified by the local configuration of nearby adsorbates. At the core of this effort was the goal of significantly extending our understanding of interfacial atomic-scale interactions to create, with intent, molecular assemblies and materials with advanced chemical and physical properties. This ambitious program addressed several key topics in DOE Grand Challenge Science, including emergent chemical and physical properties in condensed phase systems, novel uses of chemical imaging, and the development of advanced reactivity concepts in combustion and catalysis including carbon management. These activities directly benefitted national science objectives in the areas of chemical energy production and advanced materials development.

Sibener, Steven J. [University of Chicago, IL (United States)] [University of Chicago, IL (United States)

2014-03-11T23:59:59.000Z

459

Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation  

SciTech Connect (OSTI)

Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH{sub 4}{sup +} production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface.

Wu, Y.; Ajo-Franklin, J.B.; Spycher, N.; Hubbard, S.S.; Zhang, G.; Williams, K.H.; Taylor, J.; Fujita, Y.; Smith, R.

2011-07-15T23:59:59.000Z

460

Modular High-Temperature Gas-Cooled Reactor short term thermal response to flow and reactivity transients  

SciTech Connect (OSTI)

The analyses reported here have been conducted at the Oak Ridge National Laboratory (ORNL) for the US Nuclear Regulatory Commission's (NRC's) Division of Regulatory Applications of the Office of Nuclear Regulatory Research. The short-term thermal response of the Modular High-Temperature Gas-Cooled Reactor (MHTGR) is analyzed for a range of flow and reactivity transients. These include loss of forced circulation (LOFC) without scram, moisture ingress, spurious withdrawal of a control rod group, hypothetical large and rapid positive reactivity insertion, and a rapid core cooling event. The coupled heat transfer-neutron kinetics model is also described.

Cleveland, J.C.

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
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461

Internal neutronics-temperature coupling in Serpent 2 - Reactivity differences resulting from choice of material property correlations  

SciTech Connect (OSTI)

This paper describes the unique way of simultaneously solving the power and temperature distributions of a nuclear system with the Monte Carlo neutron transport code Serpent 2. The coupled solution is achieved through the implementation of an internal temperature solver and material property correlations in the code. The program structure is reviewed concerning the temperature solver and the internal correlations as well as the internal coupling between these two and the neutron transport part. To estimate the reactivity differences resulting from correlation choices a simple pin-cell case has been calculated. It is established, that some correlation choices may result in difference in reactivity of approximately 100 pcm. (authors)

Valtavirta, V. [VTT Technical Research Centre of Finland, P.O. Box 1000, FI-02044 VTT (Finland)

2013-07-01T23:59:59.000Z

462

Chombo-Crunch: Modeling Pore-Scale Reactive Transport in Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transient pH on calcite grains in capillary tube experiment. 1 billion grid points computed on 48K cores. 1 micron resolution. Transient pH on calcite grains in capillary tube experiment. 1 billion grid points computed on 48K cores. 1 micron resolution. Transient pH on calcite grains in capillary tube experiment. 1 billion grid points computed on 48K cores. 1 micron resolution. David Trebotich, Lawrence Berkeley National Laboratory Chombo-Crunch: Modeling Pore-Scale Reactive Transport in Carbon Sequestration PI Name: David Trebotich PI Email: treb@lbl.gov Institution: Lawrence Berkeley National Laboratory Allocation Program: INCITE Allocation Hours at ALCF: 80 Million Year: 2014 Research Domain: Earth Science Carbon sequestration, the process of capturing carbon dioxide (CO2) before it enters the atmosphere and transferring it into the earth, is a promising technique to help control greenhouse gas emissions. Researchers from the

463

Reactive solid-state dewetting of Cu-Ni films on silicon  

SciTech Connect (OSTI)

The behavior of a 50 nm Cu-Ni alloy film on Si in a process of reactive solid-state dewetting is presented. The films were annealed at a range of temperatures (300-700 deg. C) in 1%H{sub 2} 99%N{sub 2} reducing atmosphere. The resulting alloy and silicide particles formed by film dewetting and film reaction with the substrate were distinguished by selective wet etching and examined by scanning electron microscopy and spectroscopy. After potassium hydroxide etch, regions that etch slower than silicon substrate have distribution statistics similar to the alloy and silicide particles prior to their removal, indicating strong coupling between mass transport across the interface and along the surface.

Clearfield, Raphael; Railsback, Justin G.; Melechko, Anatoli V. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Pearce, Ryan C. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Hensley, Dale K.; Fowlkes, Jason D.; Fuentes-Cabrera, Miguel [Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Simpson, Michael L.; Rack, Philip D. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2010-12-20T23:59:59.000Z

464

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

465

Bonding and reactivity of clean and chemically-modified semiconductor surfaces probed with STM  

SciTech Connect (OSTI)

Scanning tunneling microscopy has been used to directly study the interrelationships between chemical composition, chemical reactivity, electronic structure, and surface morphology at the atomic level on clean and chemically-modified semiconductor surfaces. Our work has focused recently on understanding the atomic-level interactions of dopants such as phosphorus and boron on the Si(001) surface, and the influence of these atoms on other chemical reactions such as the thermal decomposition of disilane to grow epitaxial silicon. Using STM to study how these atoms modify the surface in combination with tunneling spectroscopy to reveal the occupied and unoccupied molecular orbitals of these structures provides direct insight into the nature of chemical bonding on these surfaces. This talk will discuss the application of STM to understand chemical bonding at silicon surfaces.

Hamers, R.J. [Univ. of Wisconsin, Madison, WI (United States)

1995-12-01T23:59:59.000Z

466

Neutron spectral reactivity comparison of /sup 235/U, /sup 233/U, /sup 239/Pu  

SciTech Connect (OSTI)

In the process of storing fuel from reactors capable of breeding fissile material, it is possible that the beginning-of-life fissile loadings are not the most reactive for the fuel. In this context, it is necessary to consider the bred fissile isotopes to ensure conservative safety margins on storage of these fuels. Of particular interest for the Idaho Chemical Processing Plant were fuels consisting primarily of /sup 235/U as the fissile isotope, such as those for the Experimental Breeder Reactor (EBR-I and -II) and some light water breeder reactor (LWBR) test elements. This study examines the relative worth of additions of the isotopes /sup 239/Pu, /sup 233/U, and /sup 235/U to a /sup 235/U-fueled critical system. The equivalence relationship between fissile isotopes depends in a complex fashion on the neutron spectrum and the relative abundance of the isotopic species.

McBroom, R.C.

1987-01-01T23:59:59.000Z

467

Lattice Boltzmann simulations on the role of channel structure for reactive capillary infiltration  

E-Print Network [OSTI]

It is widely recognized that the structure of porous media is of relevance for a variety of mechanical and physical phenomena. The focus of the present work is on capillarity, a pore-scale process occurring at the micron scale. We attempt to characterize the influence of pore shape for capillary infiltration by means of Lattice Boltzmann simulations in 2D. This problem is far from being trivial since, for example, round shapes tend to minimize the surface, but solid edges are subjected to pinning, altering strongly capillary infiltration. Another source of complexity comes into play by considering reactive boundaries leading to surface growth and ultimately to pore closure. The systems under investigation consist of single channels with different simplified morphologies: namely, periodic profiles with sinusoidal, step-shaped and zig-zag walls, as well as constrictions and expansions with rectangular, convex and concave steps. The simulations show that the optimal configuration for the pore structure arises fr...

Sergi, Danilo; Leidi, Tiziano; Ortona, Alberto

2014-01-01T23:59:59.000Z

468

Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier  

DOE Patents [OSTI]

Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

Harrup, Mason K. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID)

2007-05-15T23:59:59.000Z

469

Liquid junctions for characterization of electronic materials. III. Modulation spectroscopies of reactive ion etching of Si  

Science Journals Connector (OSTI)

Photoreflectance electrolyte photoreflectance and electrolyte electroreflectance (EER) were measured for various reactive ion etching (RIE) treatments of ?100? n?Si that include CHF3/Ar CF4 CClF3/H2 CClF3/H2 followed by O2 ash. For all the RIE?treated samples we observe a shift of the transition energy and splitting or broadening of the peaks. These spectral changes were interpreted in terms of tensile strain of the order of 1% caused by the surface damage. In all the cases except for CClF3/H2 the strain is two dimensional. The potential dependence of the EER shows that the CHF3/Ar and the CF4 treatments result in an accumulation of slow surface states that pin the dc potential but not the ac modulation. The CClF3/H2 results in a much smaller pinning that can be removed by O2 ash.

Wu?mian Shen; M. C. A. Fantini; Fred H. Pollak; Micha Tomkiewicz; Herbert J. Leary; J. P. Gambino

1989-01-01T23:59:59.000Z

470

Effects of reactive element additions and sulfur removal on the oxidation behavior of FECRAL alloys  

SciTech Connect (OSTI)

The results of this study have shown that desulfurization of FeCrAl alloys by hydrogen annealing can result in improvements in cyclic oxidation comparable to that achieved by doping with reactive elements. Moreover, specimens of substantial thicknesses can be effectively desulfurized because of the high diffusivity of sulfur in bcc iron alloys. The results have also shown that there is less stress generation during the cyclic oxidation of Y-doped FeCrAl compared to Ti-doped or desulfurized FeCrAl. This indicates that the growth mechanism, as well as the strength of the oxide/alloy interface, influences the ultimate oxidation morphology and stress state which will certainly affect the length of time the alumina remains protective.

Stasik, M.C.; Pettit, F.S.; Meier, G.H. (Univ. of Pittsburgh, PA (United States). Dept. of Materials Science and Engineering); Ashary, A. (Praxair, Indianapolis, IN (United States)); Smialek, J.L. (NASA Lewis Research Center, Cleveland, OH (United States))

1994-12-15T23:59:59.000Z

471

Characterization of the reactive flow field dynamics in a gas turbine injector using high frequency PIV  

E-Print Network [OSTI]

The present work details the analysis of the aerodynamics of an experimental swirl stabilized burner representative of gas turbine combustors. This analysis is carried out using High Frequency PIV (HFPIV) measurements in a reactive situation. While this information is usually available at a rather low rate, temporally resolved PIV measurements are necessary to better understand highly turbulent swirled flows, which are unsteady by nature. Thanks to recent technical improvements, a PIV system working at 12 kHz has been developed to study this experimental combustor flow field. Statistical quantities of the burner are first obtained and analyzed, and the measurement quality is checked, then a temporal analysis of the velocity field is carried out, indicating that large coherent structures periodically appear in the combustion chamber. The frequency of these structures is very close to the quarter wave mode of the chamber, giving a possible explanation for combustion instability coupling.

Barbosa, Sverine; Ducruix, Sbastien

2008-01-01T23:59:59.000Z

472

Utility of reactively sputtered CuN{sub x} films in spintronics devices  

SciTech Connect (OSTI)

We have studied nitrified copper (CuN{sub x}) thin films grown by reactive sputtering in the context of spintronic devices. The Ar-to-N{sub 2} flow ratio enables tunability of the electrical resistivity and surface roughness of the CuN{sub x} films, with the former increasing to nearly 20 times that of Cu, and the latter reduced to the atomic scale. Incorporating this into a Ta/CuN{sub x}/Ta seed stack for spin valves improves the current-in-plane (CIP) magnetoresistance; maximum magnetoresistance results with CuN{sub x} seed layer and Cu interlayer. Finally, finite element modeling results are presented that suggest the use of CuN{sub x} in nanocontact spin torque oscillators can enhance current densities by limiting the current spread through the device. This may positively impact threshold currents, power requirements, and device reliability.

Fang Yeyu [Physics Department, Goeteborg University, 412 96 Goeteborg (Sweden); Persson, J. [Physics Department, Goeteborg University, 412 96 Goeteborg (Sweden); NanOsc AB, Electrum 205, 164 40 Kista (Sweden); Zha, C. [Materials Physics Department, Royal Institute of Technology, Electrum 229, 164 40 Kista (Sweden); Willman, J.; Miller, Casey W. [Department of Physics, Center for Integrated Functional Materials, University of South Florida, 4202 East Fowler Avenue, Tampa, Florida 33620 (United States); Aakerman, Johan [Physics Department, Goeteborg University, 412 96 Goeteborg (Sweden); NanOsc AB, Electrum 205, 164 40 Kista (Sweden); Materials Physics Department, Royal Institute of Technology, Electrum 229, 164 40 Kista (Sweden)

2012-04-01T23:59:59.000Z

473

Catalytic reactive separation system for energy-efficient production of cumene  

DOE Patents [OSTI]

The present invention relates to an atmospheric pressure, reactive separation column packed with a solid acid zeolite catalyst for producing cumene from the reaction of benzene with propylene. Use of this un-pressurized column, where simultaneous reaction and partial separation occur during cumene production, allow separation of un-reacted, excess benzene from other products as they form. This high-yielding, energy-efficient system allows for one-step processing of cumene, with reduced need for product purification. Reacting propylene and benzene in the presence of beta zeolite catalysts generated a selectivity greater than 85% for catalytic separation reactions at a reaction temperature of 115 degrees C and at ambient pressure. Simultaneously, up to 76% of un-reacted benzene was separated from the product; which could be recycled back to the reactor for re-use.

Buelna, Genoveva (Nuevo Laredo, MX); Nenoff, Tina M. (Albuquerque, NM)

2009-07-28T23:59:59.000Z

474

Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework  

SciTech Connect (OSTI)

Cerium compounds have played vital roles in organic, inorganic, and materials chemistry due to their reversible redox chemistry between trivalent and tetravalent oxidation states. However, attempts to rationally access molecular cerium complexes in both oxidation states have been frustrated by unpredictable reactivity in cerium(III) oxidation chemistry. Such oxidation reactions are limited by steric saturation at the metal ion, which can result in high energy activation barriers for electron transfer. An alternative approach has been realized using a rare earth/alkali metal/1,1'-BINOLate (REMB) heterobimetallic framework, which uses redox-inactive metals within the secondary coordination sphere to control ligand reorganization. The rational syntheses of functionalized cerium(IV) products and a mechanistic examination of the role of ligand reorganization in cerium(III) oxidation are presented.

Robinson, Jerome R.; Gordon, Zachary; Booth, Corwin H.; Carroll, Patrick J.; Walsh, Patrick J.; Schelter, Eric J.

2014-06-24T23:59:59.000Z

475

Vitrification of F006 plating waste sludge by Reactive Additive Stabilization Process (RASP)  

SciTech Connect (OSTI)

Solidification into glass of nickel-on-uranium plating wastewater treatment plant sludge (F006 Mixed Waste) has been demonstrated at the Savannah River She (SRS). Vitrification using high surface area additives, the Reactive Additive Stabilization Process (RASP), greatly enhanced the solubility and retention of heavy metals In glass. The bench-scale tests using RASP achieved 76 wt% waste loading In both soda-lime-silica and borosilicate glasses. The RASP has been Independently verified by a commercial waste management company, and a contract awarded to vitrify the approximately 500,000 gallons of stored waste sludge. The waste volume reduction of 89% will greatly reduce the disposal costs, and delisting of the glass waste is anticipated. This will be the world`s first commercial-scale vitrification system used for environmental cleanup of Mixed Waste. Its stabilization and volume reduction abilities are expected to set standards for the future of the waste management Industry.

Martin, H.L.; Jantzen, C.M.; Pickett, J.B.

1994-06-01T23:59:59.000Z

476

Reactive ion etching-assisted surface-enhanced Raman scattering measurements on the single nanoparticle level  

SciTech Connect (OSTI)

Single-nanoparticle surface-enhanced Raman scattering (SERS) measurement is of essential importance for both fundamental research and practical applications. In this work, we develop a class of single-particle SERS approaches, i.e., reactive ion etching (RIE)-assisted SERS measurements correlated with scanning electron microscopy (SEM) strategy (RIE/SERS/SEM), enabling precise and high-resolution identification of single gold nanoparticle (AuNP) in facile and reliable manners. By using AuNP-coated silicon wafer and quartz glass slide as models, we further employ the developed RIE/SERS/SEM method for interrogating the relationship between SERS substrates and enhancement factor (EF) on the single particle level. Together with theoretical calculation using an established finite-difference-time-domain (FDTD) method, we demonstrate silicon wafer as superior SERS substrates, facilitating improvement of EF values.

Wang, Si-Yi; Jiang, Xiang-Xu; Wei, Xin-Pan; Lee, Shuit-Tong, E-mail: apannale@suda.edu.cn, E-mail: yaohe@suda.edu.cn; He, Yao, E-mail: apannale@suda.edu.cn, E-mail: yaohe@suda.edu.cn [Institute of Functional Nano and Soft Materials - FUNSOM, Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Devices Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Xu, Ting-Ting [Institute of Functional Nano and Soft Materials - FUNSOM, Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Devices Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, Hong Kong, China and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (China)

2014-06-16T23:59:59.000Z

477

Boron-carbide-aluminum and boron-carbide-reactive metal cermets  

DOE Patents [OSTI]

Hard, tough, lightweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidation step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modulus of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi.sqroot.in. These composites and methods can be used to form a variety of structural elements.

Halverson, Danny C. (Manteca, CA); Pyzik, Aleksander J. (Seattle, WA); Aksay, Ilhan A. (Seattle, WA)

1986-01-01T23:59:59.000Z

478

Fuel Cell Manufacturing Diagnostic Techniques: IR Thermography with Reactive Flow through Excitation  

SciTech Connect (OSTI)

While design and material considerations for PEMFCs have a large impact on cost, it is also necessary to consider a transition to high volume production of fuel cell systems, including MEA components, to enable economies of scale and reduce per unit cost. One of the critical manufacturing tasks is developing and deploying techniques to provide in?process measurement of fuel cell components for quality control. This effort requires a subsidiary task: The study of the effect of manufacturing defects on performance and durability with the objective to establish validated manufacturing tolerances for fuel cell components. This work focuses on the development of a potential quality control method for gas diffusion electrodes (GDEs). The method consists of infrared (IR) thermography combined with reactive flow through (RFT) excitation. Detection of catalyst loading reduction defects in GDE catalyst layers will be presented.

Manak, A. J.; Ulsh, M.; Bender, G.

2012-01-01T23:59:59.000Z

479

Physical properties of erbium implanted tungsten oxide filmsdeposited by reactive dual magnetron sputtering  

SciTech Connect (OSTI)

Amorphous and partially crystalline WO3 thin films wereprepared by reactive dual magnetron sputtering and successively implantedby erbium ions with a fluence in the range from 7.7 x 1014 to 5 x 1015ions/cm2. The electrical and optical properties were studied as afunction of the film deposition parameters and the ion fluence. Ionimplantation caused a strong decrease of the resistivity, a moderatedecrease of the index of refraction and a moderate increase of theextinction coefficient in the visible and near infrared, while theoptical band gap remained almost unchanged. These effects could belargely ascribed to ion-induced oxygen deficiency. When annealed in air,the already low resistivities of the implanted samples decreased furtherup to 70oC, whereas oxidation, and hence a strong increase of theresistivity, was observed at higher annealing temperatures.

Mohamed, Sodky H.; Anders, Andre

2006-11-08T23:59:59.000Z

480

Effect of Reactive Sputtering Parameters on TiAlN Nanocoating Structure and Morphology  

SciTech Connect (OSTI)

The effect of substrate bias and nitrogen flow rate on the TiAlN nanocoating structure and morphology has been investigated by using reactive unbalance DC magnetron sputtering. TiAlN nanocoating was deposited on the tungsten carbide insert tool and the structure and morphology were characterized by using XRD and AFM, respectively. The substrate bias was varied between 0 to -221 V and the nitrogen flow rate was varied between 30 to 72 sccm. The results showed that the structure of TiAlN nanocoating consisted of mainly (111) and (200) plane. The structure was significatly influenced by substrate bias in promoting finer crystal size and increased crystal plane spacing while the rms roughness of nanocoating was influenced by substrate bias and nitrogen flow rate.

Budi, Esmar [Jurusan Fisika FMIPA Universitas Negeri Jakarta Jl. Pemuda No. 10 Rawamangun Jakarta 13220 (Indonesia); Razali, M. Mohd.; Nizam, A. R. Md. [Faculty of Manufacturing Engineering Universiti Teknikal Malaysia Melaka (UTeM) Karung Berkunci No 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

2010-10-24T23:59:59.000Z

Note: This page contains sample records for the topic "volt ampere reactive" from the National Library of EnergyBeta (NLEBeta).
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481

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

482

Mechanisms of aldehyde-induced bronchial reactivity: role of airway epithelium  

SciTech Connect (OSTI)

To investigate the relative irritant potencies of inhaled aldehydes, guinea pigs were exposed to formaldehyde or acrolein and specific total pulmonary resistance and bronchial reactivity to intravenous acetylcholine were assessed. The mechanisms associated with these responses were investigated by analyzing morphologic and biochemical changes in airway epithelial cells after in vivo and in vitro exposures. Immediately after exposure to formaldehyde or acrolein, specific resistance increased transiently and returned to control values within 30 to 60 minutes. Bronchial hyperreactivity, assessed by the acetylcholine dose necessary to double resistance, increased and became maximal two to six hours after exposure to at least 9 parts per million2 (ppm) formaldehyde or at least 1 ppm acrolein for two hours. The effect of exposure to 3 ppm formaldehyde for two hours was less than the effect of exposure to 1 ppm formaldehyde for eight hours; thus, extended exposures produced a disproportionate heightening of bronchial reactivity. Bronchial hyperreactivity often persisted for longer than 24 hours. Increases in three bronchoconstrictive eicosanoids, prostaglandin F2 alpha, thromboxane B2, and leukotriene C4, occurred immediately after exposure, whereas an influx of neutrophils into lavage fluid occurred 24 hours later. Histological examination of the tracheal epithelium and lamina propria also demonstrated a lack of inflammatory cell infiltration. Treatment with leukotriene synthesis inhibitors and receptor antagonists inhibited acrolein-induced hyperreactivity, supporting a causal role for these compounds in this response. Acrolein also stimulated eicosanoid release from bovine epithelial cells in culture. However, the profile of metabolites formed differed from that found in lavage fluid after in vivo exposure.

Leikauf, G.D. (Department of Environmental Health, University of Cincinnati Medical Center, OH (United States))

1992-02-01T23:59:59.000Z

483

Bioassays for the detection of chemicals that can form bioactivation-dependent reactive free radicals  

SciTech Connect (OSTI)

In vitro bioassays were developed for the detection of chemicals that can be bioactivated to reactive free radical species in microsomal fractions. Two methods were deployed, a down-scaled spectrophotometric method for the detection of chemicals that can cause lipid peroxidation using the measurement of thiobarbituric acid-reactive substances (TBARS) and a fluorometric method for the detection of chemicals that can undergo redox cycling to generate superoxide radicals based on the detection of hydrogen peroxide. The response of these systems to prototypical and environmentally relevant chemicals, including tetrachloromethane and paraquat, was examined. The detection limit of the lipid peroxidation bioassay, based on the formation of TBARS, was about 1 [micro]M for tetrachloromethane; that of the bioassay for redox cyclers, based on the production of hydrogen peroxide, was about 2 [micro]M for paraquat and about 100-fold lower for the potent redox cycler 2,3,5,6-tetramethylbenzoquinone (TMBQ). Several binary mixtures of chemicals were tested for potential nonadditive effects in both in vitro systems. Some antagonistic effects among halogenated methanes were observed in the lipid peroxidation assay. In the hydrogen peroxide production assay, greater than additive effects were seen between small concentrations of paraquat and TMBQ. A number of surface water concentrates from several locations in The Netherlands, with various levels of chemical contamination, exhibited a weak response in the hydrogen peroxide production assay. Acetone was found to interfere with the response of the bioassay to redox cyclers and, therefore, the water concentrates (originally in acetone) were transferred to ethanol prior to testing. A good correlation was observed between the response of the water concentrates in the hydrogen peroxide production assay and their acute toxicity in Daphnia magna. No correlation was observed between this bioassay response and toxicity in the Microtox[trademark] assay using Photobacterium phosphoreum.

Sanderson, J.T.; Commandeur, J.N.M.; Wezel, A. van; Vermeulen, N.P.E. (Free Univ. of Amsterdam (Netherlands). Div. of Molecular Toxicology National Inst. for Coastal and Marine Management, Den Haag (Netherlands))

1999-06-01T23:59:59.000Z

484

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect (OSTI)

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

485

REACTIVITY MONITORING USING THE AREA METHOD FOR THE SUBCRITICAL VENUS-F CORE WITHIN THE FRAMEWORK OF THE FREYA PROJECT  

E-Print Network [OSTI]

1 REACTIVITY MONITORING USING THE AREA METHOD FOR THE SUBCRITICAL VENUS-F CORE WITHIN THE FRAMEWORK consists of the coupling of a subcritical fast reactor to a particle accelerator via a heavy material). It couples the VENUS-F subcritical fast core with the GENEPI-3C accelerator. The latter delivers a beam

Paris-Sud XI, Université de

486

REACTIVE TRANSPORT MODELING USING A PARALLEL FULLY-COUPLED SIMULATOR BASED ON PRECONDITIONED JACOBIAN-FREE NEWTON-KRYLOV  

SciTech Connect (OSTI)

Systems of multicomponent reactive transport in porous media that are large, highly nonlinear, and tightly coupled due to complex nonlinear reactions and strong solution-media interactions are often described by a system of coupled nonlinear partial differential algebraic equations (PDAEs). A preconditioned Jacobian-Free Newton-Krylov (JFNK) solution approach is applied to solve the PDAEs in a fully coupled, fully implicit manner. The advantage of the JFNK method is that it avoids explicitly computing and storing the Jacobian matrix during Newton nonlinear iterations for computational efficiency considerations. This solution approach is also enhanced by physics-based blocking preconditioning and multigrid algorithm for efficient inversion of preconditioners. Based on the solution approach, we have developed a reactive transport simulator named RAT. Numerical results are presented to demonstrate the efficiency and massive scalability of the simulator for reactive transport problems involving strong solution-mineral interactions and fast kinetics. It has been applied to study the highly nonlinearly coupled reactive transport system of a promising in situ environmental remediation that involves urea hydrolysis and calcium carbonate precipitation.

Luanjing Guo; Chuan Lu; Hai Huang; Derek R. Gaston

2012-06-01T23:59:59.000Z

487

Effects of V2G Reactive Power Compensation on the Component Selection in an EV or PHEV Bidirectional Charger  

E-Print Network [OSTI]

, electric vehicle, EV, PHEV, reactive power, V2G. I. NOMENCLATURE Vde (t) instantaneous dc link voltage, [V electric vehicles throughout this paper. EV power electronics and related control systems are the system vehicles (EVs) and plug-in hybrid electric vehicles (PHEVs) are becoming a part of the electric grid day

Tolbert, Leon M.

488

Three-Dimensional Homogeneous Ferrite-Carbon Aerogel: One Pot Fabrication and Enhanced Electro-Fenton Reactivity  

Science Journals Connector (OSTI)

Three-Dimensional Homogeneous Ferrite-Carbon Aerogel: One Pot Fabrication and Enhanced Electro-Fenton Reactivity ... Before analysis, all samples withdrawn from treated solutions were filtered with 0.45 ?m PTFE filters. ... Doped Carbon Nanotube Networks for Electrochemical Filtration of Aqueous Phenol: Electrolyte Precipitation and Phenol Polymerization ...

Yujing Wang; Guohua Zhao; Shouning Chai; Hongying Zhao; Yanbin Wang

2012-12-31T23:59:59.000Z

489

Title: Improving Jet Engine Turbine Thermal Barrier Coatings via Reactive Element Addition to the Bond Coat Alloy  

E-Print Network [OSTI]

Title: Improving Jet Engine Turbine Thermal Barrier Coatings via Reactive Element Addition engine turbine blades can shield the temperature to which the underlying superalloy is exposed modifications that should inhibit the failure of these jet engine turbine thermal barrier coatings. Research

Carter, Emily A.

490

Sequence-Dependent Variation in the Reactivity of 8-Oxo-7,8-dihydro-2?-deoxyguanosine toward Oxidation  

E-Print Network [OSTI]

The goal of this study was to define the effect of DNA sequence on the reactivity of 8-oxo-7,8-dihydro-2?-deoxyguanosine (8-oxodG) toward oxidation. To this end, we developed a quadrupole/time-of-flight (QTOF) mass ...

Lim, Kok Seong

491

Dynamic modeling of the reactive twin-screw co-rotating extrusion process: experimental validation by using inlet  

E-Print Network [OSTI]

and modification.1 The co-rotating twin-screw extruder is of particular interest due to its modular geometry or removing chemical species.3,4 Furthermore, the co-rotating twin-screw extruder can handle high viscosityDynamic modeling of the reactive twin-screw co-rotating extrusion process: experimental validation

Paris-Sud XI, Université de

492

Modeling the sorption dynamics of NaH using a reactive force field J. G. O. Ojwang,1,a  

E-Print Network [OSTI]

Modeling the sorption dynamics of NaH using a reactive force field J. G. O. Ojwang,1,a Rutger van that the fall in potential energy is associated with either cluster fragmentation or de- sorption of molecular ReaxFFNaAlH4 to study the structural and dynamical details of hydrogen ab de sorption processes in Na

Goddard III, William A.

493

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant  

E-Print Network [OSTI]

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

Gates, Kent. S.

494

Chemical and Molecular Descriptors for the Reactivity of Amines with CO{sub 2}  

SciTech Connect (OSTI)

Amine-based solvents are likely to play an important role in CO{sub 2} capture applications in the future, and the identification of amines with superior performance will facilitate their use in CO{sub 2} capture. While some improvements in performance will be achieved through process modifications, modifying the CO{sub 2} capture performance of an amine also implies in part an ability to modify the reactions between the amine and CO{sub 2} through development of new functionalized amines. We present a computational study of trends in the reactions between CO{sub 2} and functionalized amines with a focus on identifying molecular descriptors that determine trends in reactivity. We examine the formation of bicarbonate and carbamate species on three classes of functionalized amines: alkylamines, alkanolamines, and fluorinated alkylamines including primary, secondary and tertiary amines in each class. These functional groups span electron-withdrawing to donating behavior, hydrogen-bonding, extent of functionalization, and proximity effects of the functional groups. Electron withdrawing groups tend to destabilize CO{sub 2} reaction products, whereas electron-donating groups tend to stabilize CO{sub 2} reaction products. Hydrogen bonding stabilizes CO{sub 2} reaction products. Electronic structure descriptors based on electronegativity were found to describe trends in the bicarbonate formation energy. A chemical correlation was observed between the carbamate formation energy and the carbamic acid formation energy. The local softness on the reacting N in the amine was found to partially explain trends carbamic acid formation energy.

Lee, Anita S.; Kitchin, John R.

2012-10-24T23:59:59.000Z

495

Pyrolysis of polycyclic perhydroarenes. 3: 1-n-decylperhydropyrene and structure-reactivity relations  

SciTech Connect (OSTI)

Naphthenic (perhydroarene) moieties decorated with n-alkyl substituents exist in heavy hydrocarbon resources such as coal, heavy oils, and asphaltenes. 1-n-Decylperhydropyrene (DPP) was pyrolyzed neat at temperatures between 400 and 475 C. DPP disappearance followed first-order kinetics, and the Arrhenius parameters for the first-order rate constant were A (s{sup {minus}1}) = 10{sup 9.55.0} and E = 42.9 {+-} 16.5 kcal/mol, where the uncertainties are the 95% confidence intervals. DPP pyrolysis generated numerous primary products, and the primary products with the highest initial selectivities were, in order of decreasing abundance, perhydropyrene plus 1-decene, methylene perhydropyrene plus n-nonane, tetradecahydropyrene plus n-decane, and methylperhydropyrene plus nonene. This ordering of product pairs is completely analogous to that observed from pyrolysis of an alkylcyclohexane, but it differed from that observed for the pyrolysis of other polycyclic n-alkylnaphthenes. Eight other n-alkylperhydroarenes were pyrolyzed at temperatures between 400 and 450 C. The resulting kinetics data were used to test three structure-reactivity correlations in the literature for the pyrolysis kinetics of saturated cyclic compounds and to update one of these correlations so that it becomes consistent with the kinetics of long-chain n-alkylperhydroarenes.

Savage, P.E.; Ratz, S.; Diaz, J. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

1997-06-01T23:59:59.000Z

496

Electrically insulating films deposited on V-4%Cr-4%Ti by reactive CVD  

SciTech Connect (OSTI)

In the design of liquid-metal blankets for magnetic fusion reactors, corrosion resistance of structural materials and the magnetohydrodynamic forces and their influence on thermal hydraulics and corrosion are major concerns. Electrically insulating CaO films deposited on V-4%Cr-4%Ti exhibit high-ohmic insulator behavior even though a small amount of vanadium from the alloy become incorporated into the film. However, when vanadium concentration in the film is > 15 wt.%, the film becomes conductive. When the vanadium concentration is high in localized areas, a calcium vanadate phase that exhibits semiconductor behavior can form. The objective of this study is to evaluate electrically insulating films that were deposited on V-4%Cr-4%Ti by a reactive chemical vapor deposition (CVD) method. To this end, CaO and Ca-V-O coatings were produced on vanadium alloys by CVD and by a metallic-vapor process to investigate the electrical resistance of the coatings. The authors found that the Ca-V-O films exhibited insulator behavior when the ratio of calcium concentration to vanadium concentration R in the film > 0.9, and semiconductor or conductor behavior when R < 0.8. However, in some cases, semiconductor behavior was observed when CaO-coated samples with R > 0.98 were exposed in liquid lithium. Based on these studies, they conclude that semiconductor behavior occurs if a conductive calcium vanadate phase is present in localized regions in the CaO coating.

Park, J.H.

1998-04-01T23:59:59.000Z

497

Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport  

SciTech Connect (OSTI)

Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided thorough characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, partial pressure of carbon dioxide, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions. In this final report, we provide detailed descriptions of our results from this three-year study, completed in 2012 following a one-year no cost extension.

Chorover, Jon; Perdrial, Nico; Mueller, Karl; Strepka, Caleb; Oƒ ƒ ‚ ¢ƒ ‚ ‚ € ƒ ‚ ‚ ™ Day, Peggy; Rivera, Nelson; Um, Wooyong; Chang, Hyun-Shik; Steefel, Carl; Thompson, Aaron

2012-11-05T23:59:59.000Z

498

A radiant flow reactor for high?temperature reactivity studies of pulverized solids  

Science Journals Connector (OSTI)

Our radiant two?phase flow reactor presents several new possibilities for high?temperature reactivity studies. Most importantly the thermal histories of the suspension and entrainment gas can be independently regulated over wide ranges. At low suspension loadings outlet temperatures can differ by hundreds of degrees and gas temperatures are low enough to inhibit hydrocarbon cracking chemistry so primary products are quenched as soon as they are expelled. With coal suspensions tars were generated with the highest H/C ratio and lowest proton aromaticity ever reported. Alternatively particles and gas can be heated at similar rates to promote secondary chemistry by increasing particle loading. Simply by regulating the furnace temperature arbitrary extents of conversion of coal tar into soot were observed for fixed total mass loss. Under both circumstances heat fluxes are comparable to those in large furnaces so relevant heating rates and reaction times are accessible. Suspensions remain optically thin even for the highest loadings of technological interest because they are only 1 cm wide. Consequently the macroscopic behavior remains firmly connected to single?particle phenomena. Mass and elemental closures are rarely breached by more than 5% in individual runs so interpretations are not subject to inordinate scatter in the data. The reactor is also well suited for combustion studies as demonstrated by extents of carbon and nitrogen burnout from 50% to 100% for various gas?stream oxygen levels.

John C. Chen; Stephen Niksa

1992-01-01T23:59:59.000Z

499

Determination of the transport mechanisms in mixed conduction of reactively sputtered ZnO thin films  

Science Journals Connector (OSTI)

Material grown at highly Zn-rich conditions in reactive sputtering of ZnO thin films resulted in mixed conduction, indicating that stable p-type ZnO can be produced. In n-type conductivity, neutral flaw scattering transport mechanism via centres seems to be dominant due to the existence of oxygen vacancies in high concentrations. An exponential decrease in electron mobility is observed upon cooling from room temperature to 210?K while the concentration of the inactive state increases. This is also a cause of p-type conduction in the low temperature range ( scattering. Quantitative evaluations of VO centres show that fractional distribution of , and charge states are, respectively, around 4%, 95% and 1% of the total [VO] at the room temperature conditions. The energy of phonons interacting with the centre is estimated to be 38.5?meV which is a local phonon mode relaxation, most probably resulting in negative-U behaviour of VO centres.

S Tzemen; Emre Gr; S Do?an

2008-01-01T23:59:59.000Z

500

A transparent Pyrex ?-reactor for combined in situ optical characterization and photocatalytic reactivity measurements  

SciTech Connect (OSTI)

A new Pyrex-based ?-reactor for photocatalytic and optical characterization experiments is presented. The reactor chamber and gas channels are microfabricated in a thin poly-silicon coated Pyrex chip that is sealed with a Pyrex lid by anodic bonding. The device is transparent to light in the UV-vis-near infrared range of wavelengths (photon energies between ?0.4 and ?4.1 eV). The absorbance of a photocatalytic film obtained with a light transmission measurement during a photocatalytic reaction is presented as a proof of concept of a photocatalytic reactivity measurement combined with in situ optical characterization. Diffuse reflectance measurements of highly scattering photocatalytic nanopowders in a sealed Pyrex ?-reactor are also possible using an integrating sphere as shown in this work. These experiments prove that a photocatalyst can be characterized with optical techniques after a photocatalytic reaction without removing the material from the reactor. The catalyst deposited in the cylindrical reactor chamber can be illuminated from both top and bottom sides and an example of application of top and bottom illumination is presented.

Dionigi, F.; Hansen, O. [CINF, Department of Physics, Building 312, Fysikvej, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby (Denmark) [CINF, Department of Physics, Building 312, Fysikvej, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby (Denmark); Department of Micro- and Nanotechnology, Nanotech, Building 345 East, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby (Denmark); Nielsen, M. G.; Chorkendorff, I.; Vesborg, P. C. K. [CINF, Department of Physics, Building 312, Fysikvej, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby (Denmark)] [CINF, Department of Physics, Building 312, Fysikvej, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby (Denmark); Pedersen, T. [Department of Micro- and Nanotechnology, Nanotech, Building 345 East, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby (Denmark)] [Department of Micro- and Nanotechnology, Nanotech, Building 345 East, Technical University of Denmark, DTU, DK-2800 Kgs. Lyngby (Denmark)

2013-10-15T23:59:59.000Z