National Library of Energy BETA

Sample records for vocs volatile organic

  1. ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2006-07-10

    Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

  2. NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST OTHER CHANGES TO VOC MONITORING PROGRAM Page 1 of 21 VOC 3*1: PMR Section 3, Topic 1, Table 1 Recalculated Waste Matrix Code Group Weighting Factors based on the 2004 Compliance Recertification Contact Handled (CH) Transuranic (TRU) Waste Inventory (m 3 ) The new weighting factors appear to be based on CH TRU waste only and do not include remote handled (RH) TRU waste. There was no discussion in the PMR addressing

  3. Characterization of low-VOC latex paints: Volatile organic compound content, VOC and aldehyde emissions, and paint performance. Final report, January 1997--January 1999

    SciTech Connect (OSTI)

    Fortmann, R.; Lao, H.C.; Ng, A.; Roache, N.

    1999-04-01

    The report gives results of laboratory tests to evaluate commercially available latex paints advertised as `low-odor,` `low-VOC (volatile organic compound),` or `no-VOC.` Measurements were performed to quantify the total content of VOCs in the paints and to identify the predominant VOCs and aldehydes in the emissions following application to test substrates. The performance of the paints was evaluated and compared to that of commonly used conventional latex paints by American Society for Testing and Materials (ASTM) standard methods that measured parameters such as scrubbability, cleanability, and hiding power. The report describes the paints that were tested, the test methods, and the experimental data. Results are presented that can be used to evaluate the low-odor/low-VOC paints as alternatives to conventional latex wall paints that contain and emit higher concentrations of VOCs.

  4. TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2006-07-06

    This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating agent overestimate the value of the VOCs in a sample. By overestimating the VOC content of a sample, we want to minimize false negatives. A false negative is defined as incorrectly estimating the VOC content of the sample to be below programmatic action limits when, in fact, the sample,exceeds the action limits. The disadvantage of overestimating the flammable VOC content of a sample is that additional cost may be incurred because additional sampling and GC-MS analysis may be required to confirm results over programmatic action limits. Therefore, choosing an appropriate calibration standard for the Ar-PDHID is critical to avoid false negatives and to minimize additional analytical costs.

  5. Occupational hygiene in terms of volatile organic compounds (VOCs) and bioaerosols at two solid waste management plants in Finland

    SciTech Connect (OSTI)

    Lehtinen, Jenni; Tolvanen, Outi; Nivukoski, Ulla; Veijanen, Anja; Hnninen, Kari

    2013-04-15

    Highlights: ? Odorous VOCs: acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene. ? VOC concentrations did not exceed occupational exposure limit concentrations. ? 2,3-Butanedione as the health effecting compound is discussed. ? Endotoxin concentrations may cause health problems in waste treatment. - Abstract: Factors affecting occupational hygiene were measured at the solid waste transferring plant at Hyvink and at the optic separation plant in Hmeenlinna. Measurements consisted of volatile organic compounds (VOCs) and bioaerosols including microbes, dust and endotoxins. The most abundant compounds in both of the plants were aliphatic and aromatic hydrocarbons, esters of carboxylic acids, ketones and terpenes. In terms of odour generation, the most important emissions were acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene due to their low threshold odour concentrations. At the optic waste separation plant, limonene occurred at the highest concentration of all single compounds of identified VOCs. The concentration of any single volatile organic compound did not exceed the occupational exposure limit (OEL) concentration. However, 2,3-butanedione as a health risk compound is discussed based on recent scientific findings linking it to lung disease. Microbe and dust concentrations were low at the waste transferring plant. Only endotoxin concentrations may cause health problems; the average concentration inside the plant was 425 EU/m{sup 3} which clearly exceeded the threshold value of 90 EU/m{sup 3}. In the wheel loader cabin the endotoxin concentrations were below 1 EU/m{sup 3}. High microbial and endotoxin concentrations were measured in the processing hall at the optic waste separation plant. The average concentration of endotoxins was found to be 10,980 EU/m{sup 3}, a concentration which may cause health risks. Concentrations of viable fungi were quite high in few measurements in the control room. The most problematic factor was endotoxins whose average measured concentrations was 4853 EU/m{sup 3}.

  6. Aging of secondary organic aerosol from small aromatic VOCs. Changes in chemical composition, mass yield, volatility and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2014-12-12

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form and transform SOA from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx. The effects of chemical aging on organic aerosol (OA) composition, mass yield, volatility and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state OSC) and mass yield. The OA oxidation state generally increased during photo-oxidation, and the final OA OSmore » C ranged from -0.29 to 0.45 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  7. Investigation of key parameters influencing the efficient photocatalytic oxidation of indoor volatile organic compounds (VOCs)

    SciTech Connect (OSTI)

    Quici, Natalia; Kibanova, Daria; Vera, Maria Laura; Choi, Hyeok; Dionysiou, Dionysios D.; Litter, Marta I.; Cervini-Silva, Javiera; Hodgson, Alfred T.; Destaillats, Hugo; Destaillats, Hugo

    2008-06-01

    Photocatalytic oxidation of indoor VOCs has the potential to eliminate pollutants from indoor environments, thus effectively improving and/or maintaining indoor air quality while reducing ventilation energy costs. Design and operation of UV photocatalytic oxidation (UVPCO) air cleaners requires optimization of various parameters to achieve highest pollutant removal efficiencies while avoiding the formation of harmful secondary byproducts and maximizing catalyst lifetime.

  8. Volatile organic compounds (VOCs): Remediation for wastewater. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning wastewater contamination by volatile organic materials and the technology for reclamation. Remediation techniques discussed include use of activated carbon, activated sludge, oxidation, scrubbing, vapor stripping, biodegradation, and other degradative treatments. Articles include remediation of soils contaminated by volatile wastes. The citations examine a variety of compounds, including aromatic hydrocarbons, petroleum wastes, chlorinated organics, and other volatile materials. (Contains a minimum of 215 citations and includes a subject term index and title list.)

  9. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

    1995-08-29

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

  10. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, Gregory D. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID); Reagen, William K. (Stillwater, MN)

    1995-01-01

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

  11. Energy Efficient Removal of Volatile Organic Compounds (VOCs) and Organic Hazardous Air Pollutants (o-HAPs) from Industrial Waste Streams by Direct Electron Oxidation

    SciTech Connect (OSTI)

    Testoni, A. L.

    2011-10-19

    This research program investigated and quantified the capability of direct electron beam destruction of volatile organic compounds and organic hazardous air pollutants in model industrial waste streams and calculated the energy savings that would be realized by the widespread adoption of the technology over traditional pollution control methods. Specifically, this research determined the quantity of electron beam dose required to remove 19 of the most important non-halogenated air pollutants from waste streams and constructed a technical and economic model for the implementation of the technology in key industries including petroleum refining, organic & solvent chemical production, food & beverage production, and forest & paper products manufacturing. Energy savings of 75 - 90% and green house gas reductions of 66 - 95% were calculated for the target market segments.

  12. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.; Bomstad, Theresa M.; Sorini-Wong, Susan S.; Wong, Gregory K.

    2011-03-01

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  13. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F. (Laramie, WY); Rovani, Jr., Joseph F. (Laramie, WY); Bomstad, Theresa M. (Laramie, WY); Sorini-Wong, Susan S. (Laramie, WY)

    2009-02-10

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  14. ARM - Measurement - Volatile organic compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsVolatile organic compounds ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Volatile organic compounds The quantity or concentration measure of volatile organic compounds including both man-made and naturally occurring chemical compounds (this is inclusive of hydrocarbons). Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following

  15. Apparatus for sensing volatile organic chemicals in fluids

    DOE Patents [OSTI]

    Hughes, Robert C.; Manginell, Ronald P.; Jenkins, Mark W.; Kottenstette, Richard; Patel, Sanjay V.

    2005-06-07

    A chemical-sensing apparatus is formed from the combination of a chemical preconcentrator which sorbs and concentrates particular volatile organic chemicals (VOCs) and one or more chemiresistors that sense the VOCs after the preconcentrator has been triggered to release them in concentrated form. Use of the preconcentrator and chemiresistor(s) in combination allows the VOCs to be detected at lower concentration than would be possible using the chemiresistor(s) alone and further allows measurements to be made in a variety of fluids, including liquids (e.g. groundwater). Additionally, the apparatus provides a new mode of operation for sensing VOCs based on the measurement of decay time constants, and a method for background correction to improve measurement precision.

  16. Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles

    SciTech Connect (OSTI)

    Mohan, S.; Nagarkatti, M.

    1996-12-31

    This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

  17. Real-time monitoring of volatile organic compounds using chemical ionization mass spectrometry

    DOE Patents [OSTI]

    Mowry, Curtis Dale; Thornberg, Steven Michael

    1999-01-01

    A system for on-line quantitative monitoring of volatile organic compounds (VOCs) includes pressure reduction means for carrying a gaseous sample from a first location to a measuring input location maintained at a low pressure, the system utilizing active feedback to keep both the vapor flow and pressure to a chemical ionization mode mass spectrometer constant. A multiple input manifold for VOC and gas distribution permits a combination of calibration gases or samples to be applied to the spectrometer.

  18. Volatile organic compound emissions from usaf wastewater treatment plants in ozone nonattainment areas. Master's thesis

    SciTech Connect (OSTI)

    Ouellette, B.A.

    1994-09-01

    In accordance with the 1990 Clean Air Act Amendments (CAAA), this research conducts an evaluation of the potential emission of volatile organic compounds (VOCs) from selected Air Force wastewater treatment plants. Using a conservative mass balance analysis and process specific simulation models, volatile organic emission estimates are calculated for four individual facilities--Edwards AFB, Luke AFB, McGuire AFB, and McClellan AFB--which represent a cross section of the current inventory of USAF wastewater plants in ozone nonattainment areas. From these calculations, maximum facility emissions are determined which represent the upper limit for the potential VOC emissions from these wastewater plants. Based on the calculated emission estimates, each selected wastewater facility is evaluated as a potential major stationary source of volatile organic emissions under both Title I of the 1990 CAAA and the plant's governing Clean Air Act state implementation plan. Next, the potential impact of the specific volatile organics being emitted is discussed in terms of their relative reactivity and individual contribution to tropospheric ozone formation. Finally, a relative comparison is made between the estimated VOC emissions for the selected wastewater facilities and the total VOC emissions for their respective host installations.

  19. Biotic and Abiotic Transformation of a Volatile Organics Plume in a Semi-Arid Vadose Zone

    SciTech Connect (OSTI)

    Studer, J.E.; Singletary, M.A.; Miller, D.R.

    1999-04-08

    An evaluation of biotic and abiotic attenuation processes potentially important to chlorinated and non-chlorinated volatile organic compound (VOC) fate and transport in the 148 meter thick vadose zone beneath the Chemical Waste Landfill (CWL) was conducted. A unique feature of this evaluation is the comparison of two estimates of VOC mass present in the soil gas, pore-water, and solid phases (but not including mass as non-aqueous phase liquid [NAPL]) of the vadose zone in 1993. One estimate, 1,800 kg, was obtained from vadose zone transport modeling that incorporated molecular diffusion and volatilization to the atmosphere, but not biotic or chemical processes. The other estimate, 2,120 kg, was obtained from the sum of VOC mass physically removed during soil vapor extraction and an estimate of VOC mass remaining in the vadose zone in 1998, both adjusted to exclude NAPL mass. This comparison indicates that biogeochemical processes were at best slightly important to historical VOC plume development. Some evidence of aerobic degradation of non-chlorinated VOCs and abiotic transformation of 1,1,1-Trichloroethane was identified. Despite potentially amenable site conditions, no evidence was found of cometabolic and anaerobic transformation pathways. Relying principally on soil-gas analytical results, an upper-bound estimate of 21% mass reduction due to natural biogeochemical processes was developed. Although available information for the CWL indicates that natural attenuation processes other than volatilization to the atmosphere did not effective y enhance groundwater protection, these processes could be important in significantly reducing groundwater contamination and exposure risks at other sites. More laboratory and field research is required to improve our collective ability to characterize and exploit natural VOC attenuation processes, especially with respect to the combination of relatively thick and dry vadose zones and chlorinated VOCs.

  20. Analysis of volatile organic compounds in groundwater samples by gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Bernhardt, J.

    1995-08-23

    The Savannah River Site contains approximately 1500 monitoring wells from which groundwater samples are collected. Many of these samples are sent off-site for various analyses, including the determination of trace volatile organic compounds (VOCs). This report describes accomplishments that have been made during the past year which will ultimately allow VOC analysis to be performed on-site using gas chromatography-mass spectrometry. Through the use of the on-site approach, it is expected that there will be a substantial cost savings. This approach will also provide split-sample analysis capability which can serve as a quality control measure for off-site analysis.

  1. NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such as ventilation airflow, temperature, barometric pressure, etc. and relative humidity, will be obtained to document the sampling conditions. Appendix 3-A Page 3-A-9 of 14...

  2. Energy Saving System to Remove Volatile Organic Compounds (VOCs...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at Berkeley Lab have developed a catalyst and deployment devices to improve indoor air quality and reduce ventilation energy needs.Description The catalyst, a manganese...

  3. Partitioning of Volatile Organics in Diesel Particulate and Exhaust

    Broader source: Energy.gov [DOE]

    Evaluation of how sampling details affect the measurement of volatile organic compounds in diesel exhaust

  4. Implementation of a solvent management program to control paint shop volatile organic compounds

    SciTech Connect (OSTI)

    Floer, M.M.; Hicks, B.H.

    1997-12-31

    The majority of automobile assembly plant volatile organic compound (VOC) emissions are generated from painting operations. Typical paint operations generate more than 90 percent of the total plant emissions and, up to, 50 percent can be released by cleaning sources. Plant practices which contribute to the release of VOC emissions include the cleaning of paint lines and equipment, tanks, spray booths, floors and vehicles. Solvents continue to be the largest contributing source of VOC emissions in an automotive paint shop. To reduce overall VOC emissions, environmental regulations and guidelines were introduced under the Clean Air Act; Pollution Prevention and Waste Minimization programs, Control Techniques, and special air permit conditions. The introduction of these regulations and guidelines has driven industry toward continual refinement of their present cleaning methods while pursuing new techniques and technologies. Industry has also shown a proactive approach by introducing new waterborne and powder coating paint technologies to reduce overall emissions. As new paint technologies are developed and introduced, special attention must be given to the types of materials utilized for cleaning. The development and implementation of a solvent management program allows a facility to standardize a program to properly implement materials, equipment, technologies and work practices to reduce volatile organic compound emissions, meet strict cleaning requirements posed by new paint technologies and produce a vehicle which meets the high quality standards of the customer. This paper will assess the effectiveness of a solvent management program by examining pollution prevention initiatives and data from four different painting operations.

  5. Volatile organic chemical emissions from carpet cushions: Screening measurements. Final report

    SciTech Connect (OSTI)

    Hodgson, A.T.; Phan, T.A.

    1994-05-01

    The US Consumer Product Safety Commission (CPSC) has received complaints from consumers regarding the occurrence of adverse health effects following the installation of new carpeting (Schachter, 1990). Carpet systems are suspected of emitting chemicals which may be the cause of these complaints, as well as objectionable odors. Carpets themselves have been shown to emit a variety of volatile organic compounds (VOCs). The objective of this study was to screen the representative samples of carpet cushions for emissions of individual VOCS, total VOCs (TVOC), formaldehyde, and, for the two types of polyurethane cushions, isomers of toluene diisocyanate (TDI). The measurements of VOCS, TVOC and formaldehyde were made over six-hour periods using small-volume (4-L) dynamic chambers. Sensitive gas chromatography-mass spectrometry (GC-MS) techniques were used to identify many of the VOCs emitted by the cushion samples and to obtain quantitative estimates of the emission rates of selected compounds. Separate screening measurements were conducted for TDI. The data from the screening measurements were used by the CPSC`s Health Sciences Laboratory to help design and conduct week-long measurements of emission rates of selected compounds.

  6. Pulsed Laser Imager for Detecting Hydrocarbon and VOC Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ALPIS is operated at a safe distance of 50 to 150 meters above the inspection site. Once a volatile organic compound (VOC) is detected, the GPS coordinates are recorded and an ...

  7. Volatile Organic Compound Investigation Results, 300 Area, Hanford Site, Washington

    SciTech Connect (OSTI)

    Peterson, Robert E.; Williams, Bruce A.; Smith, Ronald M.

    2008-07-07

    Unexpectedly high concentrations of volatile organic compounds (VOC) were discovered while drilling in the unconfined aquifer beneath the Hanford Site’s 300 Area during 2006. The discovery involved an interval of relatively finer-grained sediment within the unconfined aquifer, an interval that is not sampled by routine groundwater monitoring. Although VOC contamination in the unconfined aquifer has been identified and monitored, the concentrations of newly discovered contamination are much higher than encountered previously, with some new results significantly higher than the drinking water standards. The primary contaminant is trichloroethene, with lesser amounts of tetrachloroethene. Both chemicals were used extensively as degreasing agents during the fuels fabrication process. A biological degradation product of these chemicals, 1,2-dichloroethene, was also detected. To further define the nature and extent of this contamination, additional characterization drilling was undertaken during 2007. Four locations were drilled to supplement the information obtained at four locations drilled during the earlier investigation in 2006. The results of the combined drilling indicate that the newly discovered contamination is limited to a relatively finer-grained interval of Ringold Formation sediment within the unconfined aquifer. The extent of this contamination appears to be the area immediately east and south of the former South Process Pond. Samples collected from the finer-grained sediment at locations along the shoreline confirm the presence of the contamination near the groundwater/river interface. Contamination was not detected in river water that flows over the area where the river channel potentially incises the finer-grained interval of aquifer sediment. The source for this contamination is not readily apparent. A search of historical documents and the Hanford Waste Information Data System did not provide definitive clues as to waste disposal operations and/or spills that might have resulted in groundwater contamination in this sediment, although several relatively small accidental releases of VOCs have occurred in the past in the northern portion of the 300 Area. It is likely that large quantities of degreasing solutions were disposed to the North and South Process Ponds during the 1950s and 1960s, and that evidence for them in the upper portion of the unconfined aquifer has been removed because of groundwater movement through the much more transmissive sediment. Also, investigations to date have revealed no evidence to suggest that a dense, non-aqueous phase liquid remains undetected in the subsurface. Potential pathways for contamination to migrate from this finer-grained sediment include groundwater movement through the interval to offshore locations in the Columbia River channel, dispersion out of the finer-grained interval into the overlying transmissive sediment (again, with transport to the riverbed), and potential future withdrawal via water supply wells.

  8. Estimating emissions of 20 VOCs. 2: Diffused aeration (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Estimating emissions of 20 VOCs. 2: Diffused aeration Citation Details In-Document Search Title: Estimating emissions of 20 VOCs. 2: Diffused aeration A relationship developed in a companion paper to estimate emissions from surface-aerated reactors that accounts for both gas- and liquid-phase mass-transfer resistances is extended to reactors with diffused-aeration systems. The method accurately predicts the observed stripping rate of 20 volatile organic compounds (VOCs) with

  9. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    SciTech Connect (OSTI)

    Apel, Eric; Emmons, L.; Karl, Thomas G.; Flocke, Frank M.; Hills, A. J.; Madronich, Sasha; Lee-Taylor, J.; Fried, Alan; Weibring, P.; Walega, J.; Richter, Dirk; Tie, X.; Mauldin, L.; Campos, Teresa; Weinheimer, Andrew J.; Knapp, David; Sive, B.; Kleinman, Lawrence I.; Springston, S.; Zaveri, Rahul A.; Ortega, John V.; Voss, Paul B.; Blake, D. R.; Baker, Angela K.; Warneke, Carsten; Welsh-Bon, Daniel; de Gouw, Joost A.; Zheng, J.; Zhang, Renyi; Rudolph, Jochen; Junkermann, W.; Riemer, D.

    2010-01-01

    The volatile organic compound (VOC) distribution in the Mexico City Metropolitan Area (MCMA) and its evolution as it is uplifted and transported out of the MCMA basin was studied during the 2006 MILAGRO/MIRAGE-Mex field campaign. The results show that in the morning hours in the city center, the VOC distribution is dominated by non-methane hydrocarbons (NMHCs) but with a substantial contribution from oxygenated volatile organic compounds (OVOCs), predominantly from primary emissions. Alkanes account for a large part of the NMHC distribution in terms of mixing ratios. In terms of reactivity, NMHCs also dominate overall, especially in the morning hours. However, in the afternoon, as the boundary layer lifts and air is mixed and aged within the basin, the distribution changes as secondary products are formed. The WRF-Chem (Weather Research and Forecasting with Chemistry) model and MOZART (Model for Ozone and Related chemical Tracers) were able to reproduce the general features of the daytime cycle of the VOC OH reactivity distribution showing that NMHCs dominate the distribution except in the afternoon hours and that the VOC OH reactivity peaks in the early morning due to high morning emissions from the city into a shallow boundary layer. The WRF-Chem and MOZART models showed higher reactivity than the experimental data during the nighttime cycle, perhaps indicating problems with the modeled nighttime boundary layer height. In addition, a plume was studied in which air was advected out of the MCMA and intercepted downwind with the DOE G1 on March 18 and the NCAR C130 one day later on March 19. A number of identical species measured aboard each aircraft gave insight into the chemical evolution of the plume as it aged and was transported as far as 1000 km downwind. Ozone and many OVOCs were photochemically produced in the plume. The WRF-Chem and MOZART models were used to examine the spatial and temporal extent of the March 19 plume and to help interpret the OH reactivity in the downwind plume. The model results generally showed good agreement with experimental results for the total VOC OH reactivity downwind and gave insight into the distributions of VOC chemical classes downwind. A box model with detailed gas phase chemistry (NCAR Master Mechanism), initialized with concentrations observed at one of the ground sites in the MCMA, was used to examine the expected evolution of specific VOCs over a 1-2 day period. The models clearly supported the experimental evidence for NMHC oxidation leading to the formation of OVOCs downwind, which then become the primary fuel for ozone production far away from the MCMA.

  10. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    SciTech Connect (OSTI)

    Apel, E.; Springston, S.; Karl, T.; Emmons, L.; Flocke, F.; Hills, A. J.; Madronich, S.; Lee-Taylor, J.; Fried, A.; Weibring, P.; Walega, J.; Richter, D., Tie, X.; Mauldin, L.; Campos, T.; Sive, B.; Kleinman, L.; Springston, S., Zaveri, R.; deGouw, J.; Zheng, J.; Zhang, R.; Rudolph, J.; Junkermann, W.; Riemer, D. D.

    2009-11-01

    The volatile organic compound (VOC) distribution in the Mexico City Metropolitan Area (MCMA) and its evolution as it is uplifted and transported out of the MCMA basin was studied during the 2006 MILAGRO/MIRAGE-Mex field campaign. The results show that in the morning hours in the city center, the VOC distribution is dominated by non-methane hydrocarbons (NMHCs) but with a substantial contribution from oxygenated volatile organic compounds (OVOCs), predominantly from primary emissions. Alkanes account for a large part of the NMHC distribution in terms of mixing ratios. In terms of reactivity, NMHCs also dominate overall, especially in the morning hours. However, in the afternoon, as the boundary layer lifts and air is mixed and aged within the basin, the distribution changes as secondary products are formed. The WRF-Chem (Weather Research and Forecasting with Chemistry) model and MOZART (Model for Ozone and Related chemical Tracers) were able to reproduce the general features of the daytime cycle of the VOC OH reactivity distribution showing that NMHCs dominate the distribution except in the afternoon hours and that the VOC OH reactivity peaks in the early morning due to high morning emissions from the city into a shallow boundary layer. The WRF-Chem and MOZART models showed higher reactivity than the experimental data during the nighttime cycle, perhaps indicating problems with the modeled nighttime boundary layer height. In addition, a plume was studied in which air was advected out of the MCMA and intercepted downwind with the DOE G1 on 18 March and the NCAR C130 one day later on 19 March. A number of identical species measured aboard each aircraft gave insight into the chemical evolution of the plume as it aged and was transported as far as 1000 km downwind. Ozone and many OVOCs were photochemically produced in the plume. The WRF-Chem and MOZART models were used to examine the spatial and temporal extent of the 19 March plume and to help interpret the OH reactivity in the downwind plume. The model results generally showed good agreement with experimental results for the total VOC OH reactivity downwind and gave insight into the distributions of VOC chemical classes downwind. A box model with detailed gas phase chemistry (NCAR Master Mechanism), initialized with concentrations observed at one of the ground sites in the MCMA, was used to examine the expected evolution of specific VOCs over a 1-2 day period. The models clearly supported the experimental evidence for NMHC oxidation leading to the formation of OVOCs downwind, which then become the primary fuel for ozone production far away from the MCMA.

  11. Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, M. J.; Zoerb, M. C.; Campbell, N. R.; Zimmermann, K. J.; Blomquist, B. W.; Huebert, B. J.; Bertram, T. H.

    2015-10-01

    Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory characterization was performed using both a new set of compounds (i.e. DMS, ?-caryophyllene) as well as previously studied VOCs (i.e., isoprene, ?-pinene). Using a field deployable chemical ionization time-of-flight mass spectrometer (CI-ToFMS), benzene cluster cations demonstrated high sensitivity (> 1 ncps ppt?1) to DMS, isoprene, and ?-pinene standards. Parallel measurements conducted using a chemical-ionization quadrupole mass spectrometer, with a weaker electric field, demonstrated that ion-molecule reactions likely proceed through amorecombination of ligand-switching and direct charge transfer mechanisms. Laboratory tests suggest that benzene cluster cations may be suitable for the selective ionization of sesquiterpenes, where minimal fragmentation (R2=0.80) over a wide range of sampling conditions.less

  12. Partitioning of Volatile Organics in Diesel Particulate and Exhaust...

    Broader source: Energy.gov (indexed) [DOE]

    Evaluation of how sampling details affect the measurement of volatile organic compounds in diesel exhaust PDF icon deer08strzelec.pdf More Documents & Publications Trends in ...

  13. Volatile organic compound and particulate emission studies of AF (Air Force) paint-booth facilities. Phase 1. Final report, February-December 1987

    SciTech Connect (OSTI)

    Ayer, J.; Wolbach, D.

    1988-07-01

    This study presents the results of volatile organic compound (VOC) and particulate emission surveys performed at three Air Force painting facilities. The three facilities -- one in McClellan AFB buildings 655 and two at Travis AFB in buildings 550 and 1014 -- did not meet local VOC emission standards. The possibility of reducing these emissions with recirculation modifications and various VOC reduction and control strategies is discussed. Although VOC emissions from paint spray booths can be controlled by add-on control systems, control is expensive for present air flow rates. The use of air recirculation within the spray booth can reduce the cost of VOC emission controls by reducing the quantity of air that requires processing. Recirculation systems were designed for two of the painting facilities included in this study. In designing the systems, various criteria such as paint booth VOC concentrations and health and safety standards were considered. Add-on VOC emission-control systems that can be used in conjunction with the recirculation system are evaluated. The devices of interest are a solvent incineration system and an activated-carbon adsorption bed. The VOC removal efficiency, initial capital investment and operating costs for both of these technologies are discussed.

  14. EPA proposes to control automotive VOC emissions

    SciTech Connect (OSTI)

    Not Available

    1987-09-01

    US Environmental Protection Agency has proposed a vehicle control system for reducing gasoline vapors that can escape into the environment during refueling of motor vehicles. It has also has been proposed that gasoline refiners lower the volatility of commercial fuels in summer to reduce vehicle evaporative emissions. EPA said nationwide emissions of volatile organic compounds (VOC), a major contributor to the formation of urban ozone, could be reduced as much as 10% under the proposed pollution-control measures.

  15. Formation and aging of secondary organic aerosol from toluene: changes in chemical composition, volatility, and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K. M.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2015-07-24

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form secondary organic aerosol (SOA) from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx under different oxidizing conditions. The effects of the oxidizing condition on organic aerosol (OA) composition, mass yield, volatility, and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state (OSc), and mass yield. The OA oxidation state generally increased duringmore » photo-oxidation, and the final OA OSc ranged from -0.29 to 0.16 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have a significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  16. Best available control technology (BACT) equivalent for the control of volatile organic emissions from paint dipping operations

    SciTech Connect (OSTI)

    Blankenship, W.R.; Pugh, C.W. Jr.

    1999-07-01

    This paper provides details of a study conducted to demonstrate an equivalent method of Best Available Control Technology (BACT) compliance for volatile organic emissions from dip coating of certain miscellaneous metal parts. The study was proposed to show that the total volatile organic compound (VOC) emissions from 3.8 lb of VOC/gallon coating formulations were no greater than the total VOC emissions from 3.5 lb/gallon formulations used under the same conditions for coating steel joists. The presumptive BACT standard enforced by the Virginia Department of Environmental Quality (DEQ) for dip coating of steel joists is 3.5 lb/gallon. The requirement of 3.5 lb/gallon was derived from the US Environmental Protection Agency Guideline Series Control of Volatile Organic Emissions from Existing Stationary Sources--Volume 6: Surface Coating of Miscellaneous Metal Parts and Products. On June 5, 1998 the source completed a 12 month, full scale comparison study under a consent order with the Virginia DEQ. During the study period, the source made daily measurements of product produced, paint used, and emissions from the control and test paint tanks, and reported data to EPA and the DEQ every two months. The study concluded that a 26 percent reduction in paint usage and a 20 percent reduction in emissions was achieved in the test tanks using a 3.8 lb/gal coating compared to the control tanks using a 3.5 lb/gal coating. This study enables the source to achieve greater emission reductions than the presumptive BACT level and at the same time reduce painting costs by 34%. This study provides positive results for the environment, the steel joist industry, and the construction industry. This study could impact EPA's current Maximum Achievable Control Technology (MACT) rule development for Miscellaneous Metal Parts and Products and national VOC rules for this source category under Section 183(e) of the Clean Air Act.

  17. Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: Measurement comparison, emission ratios, and source attribution

    SciTech Connect (OSTI)

    Bon, D.M.; Springston, S.; M.Ulbrich, I.; de Gouw, J. A.; Warneke, C.; Kuster, W. C.; Alexander, M. L.; Baker, A.; Beyersdorf, A. J.; Blake, D.; Fall, R.; Jimenez, J. L., Herndon, S. C.; Huey, L. G.; Knighton, W. B.; Ortega, J.; Vargas, O.

    2011-03-16

    Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements and to aid in the identification of unknown VOCs. The VOC measurements are also compared to simultaneous canister samples and to two independent proton-transfer-reaction mass spectrometers (PTR-MS) deployed on a mobile and an airborne platform during MILAGRO. VOC diurnal cycles demonstrate the large influence of vehicle traffic and liquid propane gas (LPG) emissions during the night and photochemical processing during the afternoon. Emission ratios for VOCs and OVOCs relative to CO are derived from early-morning measurements. Average emission ratios for non-oxygenated species relative to CO are on average a factor of {approx}2 higher than measured for US cities. Emission ratios for OVOCs are estimated and compared to literature values the northeastern US and to tunnel studies in California. Positive matrix factorization analysis (PMF) is used to provide insight into VOC sources and processing. Three PMF factors were distinguished by the analysis including the emissions from vehicles, the use of liquid propane gas and the production of secondary VOCs + long-lived species. Emission ratios to CO calculated from the results of PMF analysis are compared to emission ratios calculated directly from measurements. The total PIT-MS signal is summed to estimate the fraction of identified versus unidentified VOC species.

  18. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1998-06-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  19. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers. Revision 1

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1995-08-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering Laboratory (INEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  20. Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications

    SciTech Connect (OSTI)

    Jokinen, Tuija; Berndt, Torsten; Makkonen, Risto; Kerminen, Veli-Matti; Junninen, Heikki; Paasonen, Pauli; Stratmann, Frank; Herrmann, Hartmut; Guenther, Alex B.; Worsnop, Douglas R.; Kulmala, M.; Ehn, Mikael K.; Sipila, Mikko

    2015-06-09

    Extremely low volatility organic compounds (ELVOC) are suggested to promote aerosol particle formation and cloud condensation nuclei (CCN) production in the atmosphere. We show that the capability of biogenic VOC (BVOC) to produce ELVOC depends strongly on their chemical structure and relative oxidant levels. BVOC with an endocyclic double bond, representative emissions from, e.g., boreal forests, efficiently produce ELVOC from ozonolysis. Compounds with exocyclic double bonds or acyclic compounds including isoprene, emission representative of the tropics, produce minor quantities of ELVOC, and the role of OH radical oxidation is relatively larger. Implementing these findings into a global modeling framework shows that detailed assessment of ELVOC production pathways is crucial for understanding biogenic secondary organic aerosol and atmospheric CCN formation.

  1. Comparative Toxicity of Combined Particle and Semi-Volatile Organic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fractioins of Gasoline and Diesel Emissions | Department of Energy Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions Comparative Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions 2002 DEER Conference Presentation: Lovelace Respiratory Research Institute PDF icon 2002_deer_mauderly.pdf More Documents & Publications Relationship Between Composition and Toxicity of Engine Emission Samples

  2. Evaluation of low-VOC latex paints

    SciTech Connect (OSTI)

    Chang, J.C.S.; Fortmann, R.C.; Roache, N.F.; Lao, H.C.

    1999-11-01

    The paper gives results of an evaluation of four commercially available low-VOC (volatile organic compound) latex paints as substitutes for conventional latex paints by assessing both their emission characteristics and their performance as coatings. Bulk analysis indicated that the VOC contents of all four paints are considerably lower than those of conventional latex paints. Low-VOC emissions were confirmed by small chamber emission tests. However, sigificant emissions of several aldehydes, especially formaldehyde, were detected from two of the paints. ASTM methods were used to evaluate the hiding power, scrubbability, washability, dry to touch, and yellowing index. The results indicated that one of the low-VOC paints tested showed performance equivalent or superior to that of a widely used conventional latex paint used as a control. It was concluded that low-VOC latex paint can be a viable option to replace conventional latex paints for prevention of indoor air pollution. However, paints marketed as low-VOC may still have significant emissions of some individual VOCs, and some may not have performance characteristics matching those of conventional latex paints.

  3. Exploratory Research - Using Volatile Organic Compounds to Separate Heterotrophic and Autotrophic Forest Soil Respiration

    SciTech Connect (OSTI)

    Roberts, Scott D; Hatten, Jeffrey A

    2015-02-09

    The initial focus of this project was to develop a method to partition soil respiration into its components (autotrophic, heterotrophic etc.) using the fingerprint of volatile organic compounds (VOCs) from soils. We were able to identify 63 different VOCs in our study; however, due to technical difficulties we were unable to take reliable measurements in order to test our hypotheses and develop this method. In the end, we changed the objectives of the project. Our new objectives were to characterize the effects of species and soil moisture regime on the composition of soil organic matter. We utilized the soils from the greenhouse experiment we had established for the soil VOC study and determined the lignin biomarker profiles of each of the treatments. We found that moisture had a significant effect on the carbon content of the soils with the low moisture treatments having higher carbon content than the high moisture treatments. We found that the relative yield of syringyl phenols (SP), ligin (Lig), and substituted fatty acids (SFA) were elevated in deciduous planted pots and reduced in conifer planted pots relative to plant-free treatments. Our results suggest nuttall oak preserved lignin and SFA, while loblolly pine lost lignin and SFA similarly to the plant free treatments. Since we did not find that the carbon concentrations of the soils were different between the species, nuttall oak probably replaced more native soil carbon than loblolly pine. This suggests that relative to loblolly pine, nuttall oak is a priming species. Since priming may impact soil carbon pools more than temperature or moisture, determining which species are priming species may facilitate an understanding of the interaction that land use and climate change may have on soil carbon pools.

  4. Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Performance Building

    SciTech Connect (OSTI)

    Ortiz, Anna C.; Russell, Marion; Lee, Wen-Yee; Apte, Michael; Maddalena, Randy

    2010-09-20

    The developers of the Paharpur Business Center (PBC) and Software Technology Incubator Park in New Delhi, India offer an environmentally sustainable building with a strong emphasis on energy conservation, waste minimization and superior indoor air quality (IAQ). To achieve the IAQ goal, the building utilizes a series of air cleaning technologies for treating the air entering the building. These technologies include an initial water wash followed by ultraviolet light treatment and biolfiltration using a greenhouse located on the roof and numerous plants distributed throughout the building. Even with the extensive treatment of makeup air and room air in the PBC, a recent study found that the concentrations of common volatile organic compounds and aldehydes appear to rise incrementally as the air passes through the building from the supply to the exhaust. This finding highlights the need to consider the minimization of chemical sources in buildings in combination with the use of advanced air cleaning technologies when seeking to achieve superior IAQ. The goal of this project was to identify potential source materials for indoor chemicals in the PBC. Samples of building materials, including wood paneling (polished and unpolished), drywall, and plastic from a hydroponic drum that was part of the air cleaning system, were collected from the building for testing. All materials were collected from the PBC building and shipped to the Lawrence Berkeley National Laboratory (LBNL) for testing. The materials were pre-conditioned for two different time periods before measuring material and chemical specific emission factors for a range of VOCs and Aldehydes. Of the six materials tested, we found that the highest emitter of formaldehyde was new plywood paneling. Although polish and paint contribute to some VOC emissions, the main influence of the polish was in altering the capacity of the surface to accumulate formaldehyde. Neither the new nor aged polish contributed significantly to formaldehyde emissions. The VOC emission stream (excluding formaldehyde) was composed of up to 18 different chemicals and the total VOC emissions ranged in magnitude from 7 mu g/m2/h (old wood with old polish) to>500 mu g/m2/h (painted drywall). The formaldehyde emissions from drywall and old wood with either new or old polish were ~;;15 mu g/m2/h while the new wood material emitted>100 mu g/m2/h. However, when the projected surface area of each material in the building was considered, the new wood, old wood and painted drywall material all contributed substantially to the indoor formaldehyde loading while the coatings contributed primarily to the VOCs.

  5. Ventilation Control of Volatile Organic Compounds in New U.S. Homes: Results of a Controlled Field Study in Nine Residential Units

    SciTech Connect (OSTI)

    Willem, Henry; Hult, Erin L.; Hotchi, Toshifumi; Russell, Marion L.; Maddalena, Randy L.; Singer, Brett C.

    2013-01-01

    In order to optimize strategies to remove airborne contaminants in residences, it is necessary to determine how contaminant concentrations respond to changes in the air exchange rate. The impact of air exchange rate on the indoor concentrations of 39 target volatile organic compounds (VOCs) was assessed by measuring air exchange rates and VOC concentrations at three ventilation settings in nine residences. Active sampling methods were used for VOC concentration measurements, and passive perfluorocarbon tracer gas emitters with active sampling were used to determine the overall air exchange rate corresponding to the VOC measurements at each ventilation setting. The concentration levels and emission rates of the target VOCs varied by as much as two orders of magnitude across sites. Aldehyde and terpene compounds were typically the chemical classes with highest concentrations, followed by alkanes, aromatics, and siloxanes. For each home, VOC concentrations tended to decrease as the air exchange rate was increased, however, measurement uncertainty was significant. The indoor concentration was inversely proportional to air exchange rate for most compounds. For a subset of compounds including formaldehyde, however, the indoor concentration exhibited a non-linear dependence on the timescale for air exchange

  6. Reducing VOC Press Emission from OSB Manufacturing

    SciTech Connect (OSTI)

    Dr. Gary D. McGinnis; Laura S. WIlliams; Amy E. Monte; Jagdish Rughani: Brett A. Niemi; Thomas M. Flicker

    2001-12-31

    Current regulations require industry to meet air emission standards with regard to particulates, volatile organic compounds (VOCs), hazardous air pollutants (HAPs) and other gases. One of many industries that will be affected by the new regulations is the wood composites industry. This industry generates VOCs, HAPs, and particulates mainly during the drying and pressing of wood. Current air treatment technologies for the industry are expensive to install and operate. As regulations become more stringent, treatment technologies will need to become more efficient and cost effective. The overall objective of this study is to evaluate the use of process conditions and chemical additives to reduce VOC/HAPs in air emitted from presses and dryers during the production of oriented strand board.

  7. ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS ? FINAL REPORT

    SciTech Connect (OSTI)

    Salazar, Olivia; Maddalena, Randy L.; Russell, Marion; Sullivan, Douglas P.; Apte, Michael G.

    2008-05-04

    Four unoccupied FEMA temporary housing units (THUs) were studied to assess their indoor emissions of volatile organic compounds including formaldehyde. Measurement of whole-THU VOC and aldehyde emission factors (mu g h-1 per m2 of floor area) for each of the four THUs were made at FEMA's Purvis MS staging yard using a mass balance approach. Measurements were made in the morning, and again in the afternoon in each THU. Steady-state indoor formaldehyde concentrations ranged from 378 mu g m-3 (0.31ppm) to 632 mu g m-3 (0.52 ppm) in the AM, and from 433 mu g m-3 (0.35 ppm) to 926 mu g m-3 (0.78 ppm) in the PM. THU air exchange rates ranged from 0.15 h-1 to 0.39 h-1. A total of 45 small (approximately 0.025 m2) samples of surface material, 16 types, were collected directly from the four THUs and shipped to Lawrence Berkeley Laboratory. The material samples were analyzed for VOC and aldehyde emissions in small stainless steel chambers using a standard, accurate mass balance method. Quantification of VOCs was done via gas chromatography -- mass spectrometry and low molecular weight aldehydes via high performance liquid chromatography. Material specific emission factors (mu g h-1 per m2 of material) were quantified. Approximately 80 unique VOCs were tentatively identified in the THU field samples, of which forty-five were quantified either because of their toxicological significance or because their concentrations were high. Whole-trailer and material specific emission factors were calculated for 33 compounds. The THU emission factors and those from their component materials were compared against those measured from other types of housing and the materials used in their construction. Whole THU emission factors for most VOCs were typically similar to those from comparative housing. The three exceptions were exceptionally large emissions of formaldehyde and TMPD-DIB (a common plasticizer in vinyl products), and somewhat elevated for phenol. Of these three compounds, formaldehyde was the only one with toxicological significance at the observed concentrations. Whole THU formaldehyde emissions ranged from 173 to 266 mu g m-2 h 1 in the morning and 257 to 347 mu g m-2 h-1 in the afternoon. Median formaldehyde emissions in previously studied site-built and manufactured homes were 31 and 45 mu g m-2 h-1, respectively. Only one of the composite wood materials that was tested appeared to exceed the HUD formaldehyde emission standard (430 mu g/m2 h-1 for particleboard and 130 mu g/m2 h-1 for plywood). The high loading factor (material surface area divided by THU volume) of composite wood products in the THUs and the low fresh air exchange relative to the material surface area may be responsible for the excessive concentrations observed for some of the VOCs and formaldehyde.

  8. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nick; Farron, Carrie; Foster, David E.; Andrie, Mike; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs) from an aerosol sample. One method is a Dekati Thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented for this project in an engine test cell built around a direct injection spark ignited (DISI) engine. The engine was designed for stoichiometric, homogeneous combustion. Direct injection is of particular interest for improved fuel efficiency but this comes with the production of a significant amount of (PM) and may therefore be subject to the proposed number based regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition. The first interesting observation is that PM number distributions, acquired using a TSI SMPS, have a large accumulation mode (30-294 nm) but a very small nuclei mode (8-30 nm). This is understood to represent a lack of condensation particles meaning that neither the exhaust conditions nor the sample handling conditions are conducive to condensation. This lack of nuclei mode does not, however, represent a lack of VOCs in the sample. It has been observed, using mass spectral analysis (limited to PM>50 nm), that PM from the DISI engine has approximately 40% organic content through varying operating conditions. This begs the question of how effective different sample handling methods are at removing these VOCs. For one specific operating condition, called Cold Start, the un-treated PM was 40% organic. The TD reduced this by 7% while the EvCh reduced it by 13%. For other operating conditions, PM treated for volatile removal actually exhibited an increase in organic fraction on the order of 5%. This addition appears to be sensitive to the gaseous hydrocarbon concentrations in the exhaust although a precise correlation has not yet been derived. It has been concluded that VOCs are tightly bound to the PM carbon core and thus are not effectively removed by either treatment method.

  9. Maximizing Information from Residential Measurements of Volatile Organic Compounds

    SciTech Connect (OSTI)

    Maddalena, Randy; Li, Na; Hodgson, Alfred; Offermann, Francis; Singer, Brett

    2013-02-01

    Continually changing materials used in home construction and finishing can introduce new chemicals or changes in the VOC profile in residential air and the trend towards tighter homes can lead to higher exposure concentrations for many indoor sources. However, the complex mixture of VOCs in residential air makes it difficult to discover emerging contaminants and/or trends in pollutant profiles. The purpose of this study is to prepare a comprehensive library of chemicals found in homes, along with a semi-quantitative approach to maximize the information gained from VOC measurements. We carefully reviewed data from 108 new California homes and identified 238 individual compounds. The majority of the identified VOCs originated indoors. Only 31% were found to have relevant health based exposure guidelines and less than 10% had a chronic reference exposure level (CREL). The finding highlights the importance of extending IAQ studies to include a wider range of VOCs

  10. Impacts of simulated herbivory on volatile organic compound emission profiles from coniferous plants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faiola, C. L.; Jobson, B. T.; VanReken, T. M.

    2015-01-28

    The largest global source of volatile organic compounds (VOCs) in the atmosphere is from biogenic emissions. Plant stressors associated with a changing environment can alter both the quantity and composition of the compounds that are emitted. This study investigated the effects of one global change stressor, increased herbivory, on plant emissions from five different coniferous species: bristlecone pine (Pinus aristata), blue spruce (Picea pungens), western redcedar (Thuja plicata), grand fir (Abies grandis), and Douglas-fir (Pseudotsuga menziesii). Herbivory was simulated in the laboratory via exogenous application of methyl jasmonate (MeJA), a herbivory proxy. Gas-phase species were measured continuously with a gasmore » chromatograph coupled to a mass spectrometer and flame ionization detector (GC–MS–FID). Stress responses varied between the different plant types and even between experiments using the same set of saplings. The compounds most frequently impacted by the stress treatment were alpha-pinene, beta-pinene, 1,8-cineol, beta-myrcene, terpinolene, limonene, and the cymene isomers. Individual compounds within a single experiment often exhibited a different response to the treatment from one another.« less

  11. Emerging site characterization technologies for volatile organic compounds

    SciTech Connect (OSTI)

    Rohay, V.J.; Last, G.V.

    1992-05-01

    A Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) expedited response action (ERA) has been initiated at Hanford Site`s 200 West Area for the removal of carbon tetrachloride from the unsaturated soils. In coordination with the ERA, innovative technology demonstrations are being conducted as part of DOE`s Volatile Organic Compounds -- Arid Integrated Demonstration in an effort to improve upon baseline technologies. Improved methods for accessing, sampling, and analyzing soil and soil-vapor contaminants is a high priority. Sonic drilling is being evaluated as an alternative to cable-tool drilling, while still providing the advantages of reliability, containment, and waste minimization. Applied Research Associates, Inc. used their cone penetrometer in the 200 West Area to install a permanent soil-gas monitoring probe and to collect soil-gas profile data. However, successful application of this technology will require the development of an improved ability to penetrate coarse gravel units. A Science and Engineering Associates Membrane Instrumentation and Sampling Technique (SEAMIST) system designed for collecting in situ soil samples and air permeability data in between drilling runs at variable depths is being tested in 200 West Area boreholes. Analytical technologies scheduled for testing include supercritical fluid extraction and analysis for non- and semi-volatile organic co-contaminants and an unsaturated flow apparatus developed by Washington State University for the measurement of transport parameters.

  12. Emerging site characterization technologies for volatile organic compounds

    SciTech Connect (OSTI)

    Rohay, V.J.; Last, G.V.

    1992-05-01

    A Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) expedited response action (ERA) has been initiated at Hanford Site's 200 West Area for the removal of carbon tetrachloride from the unsaturated soils. In coordination with the ERA, innovative technology demonstrations are being conducted as part of DOE's Volatile Organic Compounds -- Arid Integrated Demonstration in an effort to improve upon baseline technologies. Improved methods for accessing, sampling, and analyzing soil and soil-vapor contaminants is a high priority. Sonic drilling is being evaluated as an alternative to cable-tool drilling, while still providing the advantages of reliability, containment, and waste minimization. Applied Research Associates, Inc. used their cone penetrometer in the 200 West Area to install a permanent soil-gas monitoring probe and to collect soil-gas profile data. However, successful application of this technology will require the development of an improved ability to penetrate coarse gravel units. A Science and Engineering Associates Membrane Instrumentation and Sampling Technique (SEAMIST) system designed for collecting in situ soil samples and air permeability data in between drilling runs at variable depths is being tested in 200 West Area boreholes. Analytical technologies scheduled for testing include supercritical fluid extraction and analysis for non- and semi-volatile organic co-contaminants and an unsaturated flow apparatus developed by Washington State University for the measurement of transport parameters.

  13. Development of new VOC exposure metrics and their relationship to ''Sick Building Syndrome'' symptoms

    SciTech Connect (OSTI)

    Ten Brinke, JoAnn

    1995-08-01

    Volatile organic compounds (VOCs) are suspected to contribute significantly to ''Sick Building Syndrome'' (SBS), a complex of subchronic symptoms that occurs during and in general decreases away from occupancy of the building in question. A new approach takes into account individual VOC potencies, as well as the highly correlated nature of the complex VOC mixtures found indoors. The new VOC metrics are statistically significant predictors of symptom outcomes from the California Healthy Buildings Study data. Multivariate logistic regression analyses were used to test the hypothesis that a summary measure of the VOC mixture, other risk factors, and covariates for each worker will lead to better prediction of symptom outcome. VOC metrics based on animal irritancy measures and principal component analysis had the most influence in the prediction of eye, dermal, and nasal symptoms. After adjustment, a water-based paints and solvents source was found to be associated with dermal and eye irritation. The more typical VOC exposure metrics used in prior analyses were not useful in symptom prediction in the adjusted model (total VOC (TVOC), or sum of individually identified VOCs ({Sigma}VOC{sub i})). Also not useful were three other VOC metrics that took into account potency, but did not adjust for the highly correlated nature of the data set, or the presence of VOCs that were not measured. High TVOC values (2--7 mg m{sup {minus}3}) due to the presence of liquid-process photocopiers observed in several study spaces significantly influenced symptoms. Analyses without the high TVOC values reduced, but did not eliminate the ability of the VOC exposure metric based on irritancy and principal component analysis to explain symptom outcome.

  14. Field demonstration and transition of SCAPS direct push VOC in-situ sensing technologies

    SciTech Connect (OSTI)

    William M. Davis

    1999-11-03

    This project demonstrated two in-situ volatile organic compound (VOC) samplers in combination with the direct sampling ion trap mass spectrometer (DSITMS). The technologies chosen were the Vadose Sparge and the Membrane Interface Probe (MIP) sensing systems. Tests at two demonstration sites showed the newer VOC technologies capable of providing in situ contaminant measurements at two to four times the rate of the previously demonstrated Hydrosparge sensor. The results of this project provide initial results supporting the utility of these new technologies to provide rapid site characterization of VOC contaminants in the subsurface.

  15. Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units

    SciTech Connect (OSTI)

    Parthasarathy, Srinandini; Maddalena, Randy L.; Russell, Marion L.; Apte, Michael G.

    2010-10-01

    Sixteen previously occupied temporary housing units (THUs) were studied to assess emissions of volatile organic compounds. The whole trailer emission factors wereevaluated for 36 VOCs including formaldehyde. Indoor sampling was carried out in the THUs located in Purvis staging yard in Mississippi, USA. Indoor temperature andrelative humidity (RH) were also measured in all the trailers during sampling. Indoor temperatures were varied (increased or decreased) in a selection of THUs using theheating, ventilation and air conditioning (HVAC) systems. Indoor temperatures during sampling ranged from 14o C to 33o C, and relative humidity (RH) varied between 35percentand 74percent. Ventilation rates were increased in some trailers using bathroom fans and vents during some of the sampling events. Ventilation rates measured during some aselection of sampling events varied from 0.14 to 4.3 h-1. Steady state indoor formaldehyde concentrations ranged from 10 mu g-m-3 to 1000 mu g-m-3. The formaldehyde concentrations in the trailers were of toxicological significance. The effects of temperature, humidity and ventilation rates were also studied. A linearregression model was built using log of percentage relative humidity, inverse of temperature (in K-1), and inverse log ACH as continuous independent variables, trailermanufacturer as a categorical independent variable, and log of the chemical emission factors as the dependent variable. The coefficients of inverse temperature, log relativehumidity, log inverse ACH with log emission factor were found to be statistically significant for all the samples at the 95percent confidence level. The regression model wasfound to explain about 84percent of the variation in the dependent variable. Most VOC concentrations measured indoors in the Purvis THUs were mostly found to be belowvalues reported in earlier studies by Maddalena et al.,1,2 Hodgson et al.,3 and Hippelein4. Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found to be higher than values reported in comparable housing by Hodgson et al.,3. Emissions of phenol were also found to be slightly higher than values reported in earlier studies1,2,3. This study can assist in retrospective formaldehyde exposure assessments of THUs where estimates of the occupants indoor formaldehyde exposures are needed.

  16. Control of VOC emissions from ink and paint manufacturing processes. Final report

    SciTech Connect (OSTI)

    McMinn, B.W.; Marsosudiro, P.J.

    1992-04-01

    The document presents the results of a study to collect and report information on processes used to manufacture paint and ink, volatile organic compound (VOC) emissions generated during these operations, emission control techniques and their effectiveness, and costs associated with process changes and emission control options.

  17. Evaluation of innovative volatile organic compound and hazardous air-pollutant-control technologies for U. S. Air Force paint spray booths. Final report, Aug 88-Aug 89

    SciTech Connect (OSTI)

    Ritts, D.H.; Garretson, C.; Hyde, C.; Lorelli, J.; Wolbach, C.D.

    1990-10-01

    Significant quantities of volatile organic compounds (VOCs) and hazardous air pollutants are released into the atmosphere during USAF maintenance operations. Painting operations conducted in paint spray booths are major sources of these pollutants. Solvent based epoxy primers and solvent-based polyurethane coatings are typically used by the Air Force for painting aircraft and associated equipment. Solvents used in these paints include methyl ethyl ketone (MEK), toluene, lacquer thinner, and other solvents involved in painting and component cleaning. In this report, carbon paper adsorption/catalytic incineration (CPACI) and fluidized-bed catalytic incineration (FBCI) were evaluated as control technologies to destroy VOC emissions from paint spray booths. Simultaneous testing of pilot-scale units was performed to evaluate the technical performance of both technologies. Results showed that each technology maintained greater than 99 percent Destruction and Removal Efficiencies (DREs). Particulate emissions from both pilot-scale units were less than 0.08 grains/dry standard cubic foot. Emissions of the criteria pollutants--sulfur oxides, nitrogen oxides, and carbon monoxide--were also below general regulatory standards for incinerators. Economic evaluations were based on a compilation of manufacturer-supplied data and energy consuption data gathered during the pilot scale testing. CPACM and FBCI technologies are less expensive than standard VOC control technologies when net present costs for a 15-year equipment life are compared.

  18. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  19. Treatment of VOCs in high strength wastes using an anaerobic expanded-bed GAC reactor

    SciTech Connect (OSTI)

    Narayanian, B.; Suidan, M.T.; Gelderloos, A.B.; Brenner, R.C.

    1993-01-01

    The potential of the expanded-bed granular activated carbon (GAC) anaerobic reactor in treating a high strength waste containing RCRA volatile organic compounds (VOCs) was studied. A total of six VOCs, methylene chloride, chlorobenzene, carbon tetrachloride, chloroform, toluene and tetrachloroethylene, were fed to the reactor in a high strength matrix of background solvents. Performance was evaluated. The reactor was found to effect excellent removal of all VOCs (97%). Chloroform, while itself removed at levels in excess of 97%, was found to inhibit the degradation of acetate and acetone, two of the background solvents. Without any source of chloroform in the feed, excellent COD removals were obtained in addition to near-complete removal of all the VOCs.

  20. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul M.; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition.

  1. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition

  2. Mass transfer of volatile organic compounds from drinking water to indoor air: The role of residential dishwashers

    SciTech Connect (OSTI)

    Howard-Reed, C.; Corsi, R.L.; Moya, J.

    1999-07-01

    Contaminated tap water may be a source of volatile organic compounds (VOCs) in residential indoor air. To better understand the extent and impact of chemical emissions from this source, a two-phase mass balance model was developed based on mass transfer kinetics between each phase. Twenty-nine experiments were completed using a residential dishwasher to determine model parameters. During each experiment, inflow water was spiked with a cocktail of chemical tracers with a wide range of physicochemical properties. In each case, the effects of water temperature, detergent, and dish-loading pattern on chemical stripping efficiencies and mass transfer coefficients were determined. Dishwasher headspace ventilation rates were also measured using an isobutylene tracer gas. Chemical stripping efficiencies for a single cycle ranged from 18% to 55% for acetone, from 96% to 98% for toluene, and from 97% to 98% for ethylbenzene and were consistently 100% for cyclohexane. Experimental results indicate that dishwashers have a relatively low but continuous ventilation rate that results in significant chemical storage within the headspace of the dishwasher. In conjunction with relatively high mass transfer coefficients, low ventilation rates generally lead to emissions that are limited by equilibrium conditions after approximately 1--2 min of dishwasher operation.

  3. Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135

    SciTech Connect (OSTI)

    Michalski, Casey C.; DiSalvo, Rick; Boylan, John

    2013-07-01

    DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

  4. LOW TEMPERATURE VOC COMBUSTION OVER MANGANESE, COBALT AND ZINC ALPO4 MOLECULAR SIEVES

    SciTech Connect (OSTI)

    Rosemarie Szostak

    2003-03-06

    The objective of this project was to prepare microporous aluminophosphates containing magnesium, manganese, cobalt and zinc (MeAPOs) and to evaluate their performance as oxidation catalysts for the removal of low levels of volatile organic compounds (VOCs) from gas streams. The tasks to be accomplished were as follows: (1) To develop reliable synthesis methods for metal aluminophosphates containing manganese, cobalt and zinc in their framework; (2) To characterize these materials for crystallinity, phase purity, the location and nature of the incorporated metal in the framework; and (3) To evaluate the materials for their catalytic activities in the oxidation of volatile organic environmental pollutants.

  5. Method and apparatus for regenerating activated carbon containing an adsorbed volatile organic absorbate

    SciTech Connect (OSTI)

    Tiggelbeck, D.D.; Goyak, G.M.

    1993-07-27

    A method is described for regenerating spent activated carbon containing adsorbed volatile organic adsorbate comprising: establishing a confined downwardly moving bed of activated carbon; adding spent carbon to the top of said bed; introducing superheated steam into the bottom of said bed in contact with said carbon; recovering exit gas including predominantly superheated steam and volatilized adsorbate from the top of said bed; circulating a portion of said exit gas through a superheater and compressor to the bottom of said bed; withdrawing a portion of said exit gas through a cooler to condense steam and volatile adsorbate; continuously circulating superheated steam in a closed loop through said downwardly moving bed, said compressor and said superheater; recovering partially regenerated activated carbon containing residual volatile adsorbate from the bottom of said bed.

  6. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F | Department of Energy Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F 2003 DEER Conference Presentation: Centers for Disease Control and

  7. Thermal engine driven heat pump for recovery of volatile organic compounds

    DOE Patents [OSTI]

    Drake, Richard L. (Schenectady, NY)

    1991-01-01

    The present invention relates to a method and apparatus for separating volatile organic compounds from a stream of process gas. An internal combustion engine drives a plurality of refrigeration systems, an electrical generator and an air compressor. The exhaust of the internal combustion engine drives an inert gas subsystem and a heater for the gas. A water jacket captures waste heat from the internal combustion engine and drives a second heater for the gas and possibly an additional refrigeration system for the supply of chilled water. The refrigeration systems mechanically driven by the internal combustion engine effect the precipitation of volatile organic compounds from the stream of gas.

  8. NICS report links VOCs to respiratory problems

    SciTech Connect (OSTI)

    Kirschner, E.

    1992-04-22

    Children who live near the chemical plants of Kanawha Valley, WV, suffer more acute and chronic respiratory aliments than those farther away, says a Harvard University School of Public Health report. In the $1-million, five-year study commissioned by the National Institute for Chemical Studies (NICS:Charleston, WV) and funded by the Environmental Protection Agency, proximity to chemical plants that emit volatile organic compounds (VOCs) was linked to higher incidence of asthma, acute eye irritation, shortness of breath, and chronic cough. The researchers say they adjusted for most other factors, such as parental smoking and petroleum. {open_quotes}The research hypothesis was whether children in the valley had more symptoms,{close_quotes} says NICS president Paul Hill. {open_quotes}Yes, there is a difference.{close_quotes} The study showed that some ailments were up to 28% more prevalent in children in the valley than in other Kanawha County children.

  9. Volatile Organic Compound Concentrations and Emission Rates in New Manufactured and Site-Built Houses

    SciTech Connect (OSTI)

    Armin Rudd

    2008-10-30

    This study was conducted with the primary objective of characterizing and comparing the airborne concentrations and the emission rates of total VOCs and selected individual VOCs, including formaldehyde, among a limited number of new manufactured and site-built houses.

  10. Modeling the VOC emissions from interior latex paint applied to gypsum board

    SciTech Connect (OSTI)

    Guo, Z.; Fortmann, R.; Marfiak, S.; Tichenor, B.; Sparks, L.

    1997-09-01

    The paper discusses modeling volatile organic compound (VOC) emissions from indoor latex paint applied to gypsum board. An empirical source model for a porous substrate was developed that takes both the wet- and dry-stage emission into consideration. Tests in the U.S. EPA`s Source Characterization Laboratory showed that common interior surfaces such as gypsum board and carpet could absorb significant amounts of latex paint VOCS from the air, and that they were re-emitted very slowly. An indoor air quality model incorporating the source model, an irreversible sink model, and the air movement data obtained from tracer gas tests made satisfactory predictions for the VOC levels in a test house.

  11. Performance specifications for technology development: Application for characterization of volatile organic compounds in the environment

    SciTech Connect (OSTI)

    Carpenter, S.E.; Doskey, P.V.; Erickson, M.D.; Lindahl, P.C.

    1994-07-01

    This report contains information about technology development for the monitoring and remediation of environmental pollution caused by the release of volatile organic compounds. Topics discussed include: performance specification processes, gas chromatography, mass spectrometer, fiber-optic chemical sensors, infrared spectroscopy, Raman spectroscopy, piezoelectric sensors and electrochemical sensors. These methods are analyzed for their cost efficiency, accuracy, and the ability to meet the needs of the customer.

  12. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore » and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the conversion of lower volatility components into the detected higher volatility compounds.« less

  13. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A. J.; Daumit, K. E.; Hunter, J. F.; et al

    2015-07-16

    We measured a large suite of gas- and particle-phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gas andmore » particle phases, the latter being detected by temperature-programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO–HR-ToF-CIMS are highly correlated with, and explain at least 25–50 % of, the organic aerosol mass measured by an Aerodyne aerosol mass spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from high molecular weight organics and/or oligomers (i.e., multi-phase accretion reaction products). Approximately 50 % of the HR-ToF-CIMS particle-phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption-temperature-based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas-particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the conversion of lower volatility components into the detected higher volatility compounds.« less

  14. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore »and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the conversion of lower volatility components into the detected higher volatility compounds.« less

  15. VOC and HAP recovery using ionic liquids

    SciTech Connect (OSTI)

    Michael R. Milota : Kaichang Li

    2007-05-29

    During the manufacture of wood composites, paper, and to a lesser extent, lumber, large amounts of volatile organic compounds (VOCs) such as terpenes, formaldehyde, and methanol are emitted to air. Some of these compounds are hazardous air pollutants (HAPs). The air pollutants produced in the forest products industry are difficult to manage because the concentrations are very low. Presently, regenerative thermal oxidizers (RTOs and RCOs) are commonly used for the destruction of VOCs and HAPs. RTOs consume large amounts of natural gas to heat air and moisture. The combustion of natural gas generates increased CO2 and NOx, which have negative implications for global warming and air quality. The aforementioned problems are addressed by an absorption system containing a room-temperature ionic liquid (RTIL) as an absorbent. RTILs are salts, but are in liquid states at room temperature. RTILs, an emerging technology, are receiving much attention as replacements for organic solvents in industrial processes with significant cost and environmental benefits. Some of these processes include organic synthesis, extraction, and metal deposition. RTILs would be excellent absorbents for exhausts from wood products facilities because of their unique properties: no measurable vapor pressure, high solubility of wide range of organic compounds, thermal stability to 200C (almost 400F), and immisciblity with water. Room temperature ionic liquids were tested as possible absorbents. Four were imidizolium-based and were eight phosphonium-based. The imidizolium-based ionic liquids proved to be unstable at the conditions tested and in the presence of water. The phosphonium-based ionic liquids were stable. Most were good absorbents; however, cleaning the contaminates from the ionic liquids was problematic. This was overcome with a higher temperature (120C) than originally proposed and a very low pressure (1 kPa. Absorption trials were conducted with tetradecy(trihexyl)phosphonium dicyanamide as the RTIL. It was determined that it has good absorption properties for methanol and ?-pinene, is thermally stable, and is relatively easy to synthesize. It has a density of 0.89 g/mL at 20C and a molecular weight of 549.9 g/mol. Trials were conducted with a small absorption system and a larger absorption system. Methanol, formaldehyde, and other HAPs were absorbed well, nearly 100%. Acetaldehyde was difficult to capture. Total VOC capture, while satisfactory on methanol and ?-pinene in a lab system, was less than expected in the field, 60-80%. The inability to capture the broad spectrum of total organics is likely due to difficulties in cleaning them from the ionic liquid rather than the ability of the ionic liquid to absorb. Its likely that a commercial system could be constructed to remove 90 to 100% of the gas contaminates. Selecting the correct ionic liquid would be key to this. Absorption may not be the main selection criterion, but rather how easily the ionic liquid can be cleaned is very important. The ionic liquid absorption system might work very well in a system with a limited spectrum of pollutants, such as a paint spray line, where there are not very high molecular weight, non volatile, compounds in the exhaust.

  16. Metal-organic molecular device for non-volatile memory storage

    SciTech Connect (OSTI)

    Radha, B., E-mail: radha.boya@manchester.ac.uk, E-mail: kulkarni@jncasr.ac.in; Sagade, Abhay A.; Kulkarni, G. U., E-mail: radha.boya@manchester.ac.uk, E-mail: kulkarni@jncasr.ac.in [Chemistry and Physics of Materials Unit and DST Unit on Nanoscience, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560064 (India)

    2014-08-25

    Non-volatile memory devices have been of immense research interest for their use in active memory storage in powered off-state of electronic chips. In literature, various molecules and metal compounds have been investigated in this regard. Molecular memory devices are particularly attractive as they offer the ease of storing multiple memory states in a unique way and also represent ubiquitous choice for miniaturized devices. However, molecules are fragile and thus the device breakdown at nominal voltages during repeated cycles hinders their practical applicability. Here, in this report, a synergetic combination of an organic molecule and an inorganic metal, i.e., a metal-organic complex, namely, palladium hexadecylthiolate is investigated for memory device characteristics. Palladium hexadecylthiolate following partial thermolysis is converted to a molecular nanocomposite of Pd(II), Pd(0), and long chain hydrocarbons, which is shown to exhibit non-volatile memory characteristics with exceptional stability and retention. The devices are all solution-processed and the memory action stems from filament formation across the pre-formed cracks in the nanocomposite film.

  17. Arid sites stakeholder participation in evaluating innovative technologies: VOC-Arid Site Integrated Demonstration

    SciTech Connect (OSTI)

    Peterson, T.S.; McCabe, G.H.; Brockbank, B.R.

    1995-05-01

    Developing and deploying innovative environmental cleanup technologies is an important goal for the U.S. Department of Energy (DOE), which faces challenging remediation problems at contaminated sites throughout the United States. Achieving meaningful, constructive stakeholder involvement in cleanup programs, with the aim of ultimate acceptance of remediation decisions, is critical to meeting those challenges. DOE`s Office of Technology Development sponsors research and demonstration of new technologies, including, in the past, the Volatile Organic Compounds Arid Site Integrated Demonstration (VOC-Arid ID), hosted at the Hanford Site in Washington State. The purpose of the VOC-Arid ID has been to develop and demonstrate new technologies for remediating carbon tetrachloride and other VOC contamination in soils and ground water. In October 1994 the VOC-Arid ID became a part of the Contaminant Plume Containment and Remediation Focus Area (Plume Focus Area). The VOC Arid ID`s purpose of involving stakeholders in evaluating innovative technologies will now be carried on in the Plume Focus Area in cooperation with Site Technology Coordination Groups and Site Specific Advisory Boards. DOE`s goal is to demonstrate promising technologies once and deploy those that are successful across the DOE complex. Achieving that goal requires that the technologies be acceptable to the groups and individuals with a stake in DOE facility cleanup. Such stakeholders include groups and individuals with an interest in cleanup, including regulatory agencies, Native American tribes, environmental and civic interest groups, public officials, environmental technology users, and private citizens. This report documents the results of the stakeholder involvement program, which is an integral part of the VOC-Arid ID.

  18. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  19. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  20. Modeling ambient air concentrations of volatile organic compounds via digitally filtered FTIR spectra

    SciTech Connect (OSTI)

    Kaltenbach, T.

    1994-12-31

    As part of an agreement with the New York State Department of Environmental Conservation, Eastman Kodak Company has a program to monitor ambient air concentrations of volatile organic compounds at its fence lines. Currently, canister-based point sensors are used to collect a time-averaged sample every sixth day. The staff required to position, retrieve, and analyze these canisters makes this procedure expensive. Alternative methods are being investigated that can provide similar results in real time, while also saving costs. One such method is Fourier transform infrared (FTIR) spectroscopy. Radian Corporation performed a series of FTIR fence-line monitoring experiments at Kodak about one year ago. The spectra collected during this experiment are complicated by the presence of water vapor bands. Digital filtering techniques utilizing the Fourier transform are being explored as a means of removing the interference due to water vapor. When a digital filter is used as a spectral preprocessor, partial least squares (PLS) techniques can be employed to provide a powerful prediction pool. This seminar will describe the operation of the Fourier filters and present some encouraging preliminary results from PLS models.

  1. Volatilization of selected organic compounds from a creosote-waste land-treatment facility. Master's thesis

    SciTech Connect (OSTI)

    Scott, E.J.

    1989-01-01

    The purpose of this research was to evaluate the emissions of volatile and semi-volatile compounds which are constituents of a complex creosote waste from laboratory simulations of a land treatment system to assess the potential human exposure to hazardous compounds from this source. In addition, the Thibodeaux-Hwang Air Emission Release Rate (AERR) model was evaluated for its use in predicting emission rates of hazardous constituents of creosote wood preservative waste from land treatment facilities. A group of hazardous volatile and semi-volatile constituents present in the creosote waste was selected for evaluation in this study and included a variety of polynuclear aromatic hydrocarbons (PNA's), phenol, and chlorinated and substituted phenols.

  2. Solutions for VOC and HAPS control on natural gas fired internal combustion engines

    SciTech Connect (OSTI)

    Marcus, J.Z.; Sleigh, S.; Cotherman, R.

    1996-12-31

    Natural gas fired stationary internal combustion engines (IC engines) emit volatile organic compounds (VOC) and hazardous air pollutants (HAP) as part of their normal operations. VOC and HAP emissions are coming under increased scrutiny with the advent of such Clean Air Act Amendments of 1990 regulations as Title I`s Reasonably Available Control Technology (RACT), Title III`s Maximum Achievable Control Technology (MACT) and Title V`s Operating Permit Program (Title V). In addition, many states are imposing more stringent emission limits on these sources. These emissions may also contribute to the reportable chemicals from the total facility under SARA Title III. Numerous facilities nationwide are interested in reducing these emissions in order to comply with current requirements, to opt out of requirements or to reduce reportable chemicals. This paper will examine the source of these emissions, and discuss combustion control technologies and system operating flexibility, end-of-pipe control technologies, and system tuning opportunities which have the potential to reduce VOC and HAP emissions from IC engines. Data will be presented on potential emission reduction efficiencies achievable using the various control options. 7 refs., 4 tabs.

  3. Chemiresistor microsensors for in-situ monitoring of volatile organic compounds : final LDRD report.

    SciTech Connect (OSTI)

    Thomas, Michael Loren; Hughes, Robert Clark; Kooser, Ara S.; McGrath, Lucas K.; Ho, Clifford Kuofei; Wright, Jerome L.; Davis, Chad Edward

    2003-09-01

    This report provides a summary of the three-year LDRD (Laboratory Directed Research and Development) project aimed at developing microchemical sensors for continuous, in-situ monitoring of volatile organic compounds. A chemiresistor sensor array was integrated with a unique, waterproof housing that allows the sensors to be operated in a variety of media including air, soil, and water. Numerous tests were performed to evaluate and improve the sensitivity, stability, and discriminatory capabilities of the chemiresistors. Field tests were conducted in California, Nevada, and New Mexico to further test and develop the sensors in actual environments within integrated monitoring systems. The field tests addressed issues regarding data acquisition, telemetry, power requirements, data processing, and other engineering requirements. Significant advances were made in the areas of polymer optimization, packaging, data analysis, discrimination, design, and information dissemination (e.g., real-time web posting of data; see www.sandia.gov/sensor). This project has stimulated significant interest among commercial and academic institutions. A CRADA (Cooperative Research and Development Agreement) was initiated in FY03 to investigate manufacturing methods, and a Work for Others contract was established between Sandia and Edwards Air Force Base for FY02-FY04. Funding was also obtained from DOE as part of their Advanced Monitoring Systems Initiative program from FY01 to FY03, and a DOE EMSP contract was awarded jointly to Sandia and INEEL for FY04-FY06. Contracts were also established for collaborative research with Brigham Young University to further evaluate, understand, and improve the performance of the chemiresistor sensors.

  4. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    SciTech Connect (OSTI)

    Borden, R. E.; Cherry, Robert Stephen

    2000-09-01

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced ~7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The system was tested in a petroleum contaminated aquifer near Rocky Point, NC. The contaminant plume there is approximately 10 m deep, 50 m wide and contains up to 4 g/L total BTEX and 75 g/L dissolved iron. An extensive pilot test was first performed to estimate the zone of influence for a single well. At this site an air injection rate of 1.2 L/min resulted in a water flow rate of 1 to 2 L/min based on bromide dilution tests in the GCW. The GCW increased the dissolved oxygen concentration in the discharge water to between 6 and 8 g/L and reduced contaminant concentrations to less than 20 g/L total BTEX. Monitoring results from a 73 day pilot test were then used to define the zone of influence for a single DP-GCW and to design a full scale barrier system.

  5. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    SciTech Connect (OSTI)

    Borden, R.C.; Cherry, R.S.

    2000-09-30

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced {approximately}7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe{reg_sign} rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The system was tested in a petroleum contaminated aquifer near Rocky Point, NC. The contaminant plume there is approximately 10 m deep, 50 m wide and contains up to 4 {micro}g/L total BTEX and 75 {micro}g/L dissolved iron. An extensive pilot test was first performed to estimate the zone of influence for a single well. At this site an air injection rate of 1.2 L/min resulted in a water flow rate of 1 to 2 L/min based on bromide dilution tests in the GCW. The GCW increased the dissolved oxygen concentration in the discharge water to between 6 and 8 {micro}g/L and reduced contaminant concentrations to less than 20 {micro}g/L total BTEX. Monitoring results from a 73 day pilot test were then used to define the zone of influence for a single DP-GCW and to design a full scale barrier system.

  6. Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 4, Organic methods

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    This interim notice covers the following: extractable organic halides in solids, total organic halides, analysis by gas chromatography/Fourier transform-infrared spectroscopy, hexadecane extracts for volatile organic compounds, GC/MS analysis of VOCs, GC/MS analysis of methanol extracts of cryogenic vapor samples, screening of semivolatile organic extracts, GPC cleanup for semivolatiles, sample preparation for GC/MS for semi-VOCs, analysis for pesticides/PCBs by GC with electron capture detection, sample preparation for pesticides/PCBs in water and soil sediment, report preparation, Florisil column cleanup for pesticide/PCBs, silica gel and acid-base partition cleanup of samples for semi-VOCs, concentrate acid wash cleanup, carbon determination in solids using Coulometrics` CO{sub 2} coulometer, determination of total carbon/total organic carbon/total inorganic carbon in radioactive liquids/soils/sludges by hot persulfate method, analysis of solids for carbonates using Coulometrics` Model 5011 coulometer, and soxhlet extraction.

  7. Membranes for Reverse-Organic Air Separations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Membranes for Reverse-Organic Air Separations Membranes for Reverse-Organic Air Separations New Membranes Use Reverse Separation to Reduce Pollutant Emissions Many industrial applications need a process to separate pollutants known as volatile organic compounds (VOCs) from air in order to protect the environment and save energy. One such application is the venting of vapor from underground storage tanks (UST) used in gasoline storage and dispensing. These vapors, which can build up and create

  8. Infrared Spectroscopy of Wild 2 Particle Hypervelocity Tracks in Stardust Aerogel: Evidence for the presence of Volatile Organics in Comet Dust

    SciTech Connect (OSTI)

    Bajt, S; Sandford, S A; Flynn, G J; Matrajt, G; Snead, C J; Westphal, A J; Bradley, J P

    2007-08-28

    Infrared spectroscopy maps of some tracks, made by cometary dust from 81P/Wild 2 impacting Stardust aerogel, reveal an interesting distribution of volatile organic material. Out of six examined tracks three show presence of volatile organic components possibly injected into the aerogel during particle impacts. When particle tracks contained excess volatile organic material, they were found to be -CH{sub 2}-rich. Off-normal particle tracks could indicate impacts by lower velocity particles that could have bounced off the Whipple shield, therefore carry off some contamination from it. However, this theory is not supported by data that show excess organic-rich material in normal and off-normal particle tracks. It is clear that the population of cometary particles impacting the Stardust aerogel collectors also include grains that contained little or none of this volatile organic component. This observation is consistent with the highly heterogeneous nature of the collected grains, as seen by a multitude of other analytical techniques. We propose that at least some of the volatile organic material might be of cometary origin based on supporting data shown in this paper. However, we also acknowledge the presence of carbon (primarily as -CH{sub 3}) in the original aerogel, which complicates interpretation of these results.

  9. VOC Public Notice (9-8-15)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    prevents unnecessary risk to VOC sampling personnel and provides a more practical value for determining the risk from VOC exposure to the non-waste handling surface worker....

  10. Work plan for support to Upper East Fork Poplar Creek east end VOC plumes well installation project at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    1998-03-01

    Under the Resource Conservation and Recovery Act of 1976 guidelines and requirements from the Tennessee Department of Environment and Conservation (TDEC), the Y-12 Plant initiated investigation and monitoring of various sites within its boundaries in the mid-1980s. The entire Oak Ridge Reservation (ORR) was placed on the National Priorities List of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) sites in November 1989. Following CERCLA guidelines, sites within the ORR require a remedial investigation (RI) to define the nature and extent of contamination, evaluate the risks to public health and the environment, and determine the goals for a feasibility study (FS) or an engineering evaluation/cost analysis (EE/CA) of potential remedial actions. Data from monitoring wells at the east end of the Y-12 Plant have identified an area of groundwater contamination dominated by the volatile organic compound (VOC) carbon tetrachloride; other VOCs include chloroform, tetrachloroethene, and trichloroethene.

  11. Stratification of particulate and VOC pollutants in horizontal-flow-paint spray booths. Report for September 1988-October 1989

    SciTech Connect (OSTI)

    Darvin, C.H.

    1990-01-01

    The paper discusses stratification of particulate and volatile organic compound (VOC) pollutants in horizontal flow paint spray booths, as part of a joint U.S. Air Force/EPA research and development program on emissions from paint spray booths. The test program discussed in the paper was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control strategies are being developed. The results of one series of tests indicate that the pollutants, both particulate and VOC, fall to the lower level of the booth or stratify at the level at which they were generated. This might be expected since the densities of typical pollutants found in spray booths are greater than air. The results showed, however, that the concentration of pollutants in the lower level prior to exiting the booth was significantly greater than expected. Data indicated that, for the 16 ft (4.9 m) high booth tested, the concentration at the exit of the booth below the 8 ft (2.4 m) level was 5-25 times greater than the concentration above that level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The concentrated zone could be directed to a proportionally smaller VOC control system of significantly less capital and operating cost.

  12. Composites for removing metals and volatile organic compounds and method thereof

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Reynolds, John G. (San Ramon, CA)

    2006-12-12

    Functionalized hydrophobic aerogel/solid support structure composites have been developed to remove metals and organic compounds from aqueous and vapor media. The targeted metals and organics are removed by passing the aqueous or vapor phase through the composite which can be in molded, granular, or powder form. The composites adsorb the metals and the organics leaving a purified aqueous or vapor stream. The species-specific adsorption occurs through specific functionalization of the aerogels tailored towards specific metals and/or organics. After adsorption, the composites can be disposed of or the targeted metals and/or organics can be reclaimed or removed and the composites recycled.

  13. Test methods for determining short and long term VOC emissions from latex paint

    SciTech Connect (OSTI)

    Krebs, K.; Lao, H.C.; Fortmann, R.; Tichenor, B.

    1998-09-01

    The paper discusses an evaluation of latex paint (interior, water based) as a source of indoor pollution. A major objective of the research is the development of methods for predicting emissions of volatile organic compounds (VOCs) over time. Test specimens of painted gypsumboard are placed in dynamic flow-through test chambers. Samples of the outlet air are collected on Tenax sorbents and thermally desorbed for analysis by gas chromatography/flame ionization detection. These tests produce short- and long-term data for latex paint emissions of Texanol, 2-2(-butoxyethoxy)-ethanol, and glycols. Evaluation of the data shows that most of the Texanol emissions occur within the first few days, and emissions of the glycols occur over several months. This behavior may be described by an evaporative mass transfer process that dominates the short-term emissions, while long-term emissions are limited by diffusion processes within the dry paint-gypsumboard.

  14. Customizing a VOC control technology

    SciTech Connect (OSTI)

    Enneking, J.C.

    1998-12-31

    An extremely important but very difficult element in applying an emission control device to an exhaust stream is to chose the proper technology. Once it has been determined that recovery, rather than destruction, is appropriate, there are still several process choices available. The type of process is generally dictated by the VOC concentration and total air flow rate. Adsorption is usually chosen for low concentrations and high flow rates while refrigeration is usually best for high concentrations and low flow rates. This paper describes six applications. Adsorption was applied to two of them and condensation to the other four. Solvent vapors from a tape coating operation are recovered in an activated carbon adsorption process and reused. VOC`s from soil vapor extraction operations are captured by activated carbon which is regenerated by a mobile unit. VOC`s displaced from filling tank cars at a refinery are condensed at low temperatures in a high pressure system which uses a pressure swing dryer to remove water. Two different processes were installed to prevent VOC emissions from pharmaceutical processing plants. They both use a thermal swing dryer to remove moisture and low temperature condensation to recover the solvent. With very high concentrations of solvent in an inert gas stream, indirect condensation is used to purify the nitrogen and recover the solvent for reuse. Process flow diagrams and operating results are presented.

  15. Study of the VOC emissions from a municipal solid waste storage pilot-scale cell: Comparison with biogases from municipal waste landfill site

    SciTech Connect (OSTI)

    Chiriac, R.; De Araujos Morais, J.; Carre, J.; Bayard, R.; Chovelon, J.M.; Gourdon, R.

    2011-11-15

    Highlights: > Follow-up of the emission of VOCs in a municipal waste pilot-scale cell during the acidogenesis and acetogenesis phases. > Study from the very start of waste storage leading to a better understanding of the decomposition/degradation of waste. > Comparison of the results obtained on the pilot-scale cell with those from 3 biogases coming from the same landfill site. > A methodology of characterization for the progression of the stabilization/maturation of waste is finally proposed. - Abstract: The emission of volatile organic compounds (VOCs) from municipal solid waste stored in a pilot-scale cell containing 6.4 tonnes of waste (storage facility which is left open during the first period (40 days) and then closed with recirculation of leachates during a second period (100 days)) was followed by dynamic sampling on activated carbon and analysed by GC-MS after solvent extraction. This was done in order to know the VOC emissions before the installation of a methanogenesis process for the entire waste mass. The results, expressed in reference to toluene, were exploited during the whole study on all the analyzable VOCs: alcohols, ketones and esters, alkanes, benzenic and cyclic compounds, chlorinated compounds, terpene, and organic sulphides. The results of this study on the pilot-scale cell are then compared with those concerning three biogases from a municipal waste landfill: biogas (1) coming from waste cells being filled or recently closed, biogas (2) from all the waste storage cells on site, and biogas (3) which is a residual gas from old storage cells without aspiration of the gas. The analysis of the results obtained revealed: (i) a high emission of VOCs, principally alcohols, ketones and esters during the acidogenesis; (ii) a decrease in the alkane content and an increase in the terpene content were observed in the VOCs emitted during the production of methane; (iii) the production of heavier alkanes and an increase in the average number of carbon atoms per molecule of alkane with the progression of the stabilisation/maturation process were also observed. Previous studies have concentrated almost on the analysis of biogases from landfills. Our research aimed at gaining a more complete understanding of the decomposition/degradation of municipal solid waste by measuring the VOCs emitted from the very start of the landfill process i.e. during the acidogenesis and acetogenesis phases.

  16. 2010-05 "Interim Measure for Volatile Organic Constituent Contaminant Source Removal in MAD-L and MDA-G"

    Broader source: Energy.gov [DOE]

    Approved March 31, 2010 The intent of this recommendation is to remove large volumes of liquid waste VOCs from the ground and to prevent these contaminants from moving into the groundwater or to the atmosphere. The NNMCAB recognizes it will take additional time and studies for the NMED and DOE to develop final remedies for these MDAs. Therefore, an Interim Measure will provide immediate treatment and removal of source material to reduce further contamination of the site.

  17. Stratification of particulate and VOC pollutants in paint spray booths, June 1990. Report for April 1988-April 1989

    SciTech Connect (OSTI)

    Darvin, C.H.; Ayer, J.

    1990-01-01

    The paper discusses flow management as part of a joint EPA/U.S. Air Force program on emissions from paint spray booths. The goal of the program is to identify and develop efficient and economical emissions control concepts for this source. Flow management is one potential solution that reduces the volume of gases that must be processed in a control system. Although it will not itself control pollution, it can influence the economic and technical viability of subsequent control systems. The test program discussed here was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control and flow management strategies are being developed. Study results indicate that both particulate and volatile organic compounds (VOCs) fall to the lower level of the booth or, at most, stratify at the level at which they were generated. Results indicate that the concentration at the lower level of the booth near the exhaust was from 5 to 25 times greater than that at the upper level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The enriched lower zone could then be directed to a proportionately smaller VOC control system, of lower capital and operating costs.

  18. Biofiltration control of VOC and air toxic emissions: n-Butane and benzene

    SciTech Connect (OSTI)

    Allen, E.R.

    1996-12-31

    n-Butane and benzene vapors are routinely observed in urban atmospheres. Their presence in urban airsheds is of concern because of their ozone production potential as volatile organic compounds (VOCs) and/or potential toxicity. Also, these saturated hydrocarbons are representative of airborne aliphatic and aromatic compounds. Separate laboratory studies have been conducted on the biological elimination of n-butane (n-C{sub 4}H{sub 10}) and benzene (C{sub 6}H{sub 6}) from airstreams using treated compost biofilters. The removal efficiencies were found to exceed 90% for a conditioned biofilter medium and pollutant low concentrations (< 25 ppm) and zeroth order kinetics at higher concentrations (> 100 ppm), whereas benzene vapor elimination followed zeroth order kinetics at concentrations up to 200 ppm. The maximum n-butane and benzene elimination capacities observed for the compost biofilters and conditions employed were 25 and 70 g pollutant m{sup -3} h{sup -1}, respectively. 13 refs., 6 figs., 2 tabs.

  19. Impacts of simulated herbivory on VOC emission profiles from coniferous plants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faiola, C. L.; Jobson, B. T.; VanReken, T. M.

    2014-09-18

    The largest global source of volatile organic compounds (VOCs) in the atmosphere is from biogenic emissions. Plant stressors associated with a changing environment can alter both the quantity and composition of the compounds that are emitted. This study investigated the effects of one global change stressor, increased herbivory, on plant emissions from five different coniferous species: bristlecone pine (Pinus aristata), blue spruce (Picea pungens), western redcedar (Thuja plicata), grand fir (Abies grandis), and Douglas-fir (Pseudotsugas menziesii). Herbivory was simulated in the laboratory via exogenous application of methyl jasmonate, an herbivory proxy. Gas-phase species were measured continuously with a gas chromatographmore » coupled to a mass spectrometer and flame ionization detector (GC-MS-FID). Stress responses varied between the different plant types and even between experiments using the same set of saplings. The compounds most frequently impacted by the stress treatment were alpha-pinene, beta-pinene, 1,8-cineol, beta-myrcene, terpinolene, limonene, and the cymene isomers. Individual compounds within a single experiment often exhibited a different response to the treatment from one another.« less

  20. Determination of a cost-effective air pollution control technology for the control of VOC and HAP emissions from a steroids processing plant

    SciTech Connect (OSTI)

    Hamel, T.M.

    1997-12-31

    A steroids processing plant located in northeastern Puerto Rico emits a combined average of 342 lb/hr of hazardous air pollutants (HAPs) and volatile organic compounds (VOCs) from various process operations. The approach that this facility used to implement maximum achievable control technology (MACT) may assist others who must contend with MACT for pharmaceutical or related manufacturing facilities. Federal air regulations define MACT standards for stationary sources emitting any of 189 HAPs. The MACT standards detailed in the NESHAPs are characterized by industry and type of emission control system or technology. It is anticipated that the standard will require HAP reductions of approximately 95%. The steroid plant`s emissions include the following pollutant loadings: VOC/HAP Emission Rate (lb/hr): Methanol 92.0; Acetone 35.0; Methylene chloride 126.0; Chloroform 25.0; Ethyl acetate 56.0; Tetrahydrofuran 5.00; and 1,4-Dioxane 3.00. The facility`s existing carbon adsorption control system was nearing the end of its useful life, and the operators sought to install an air pollution control system capable of meeting MACT requirements for the pharmaceutical industry. Several stand-alone and hybrid control technologies were considered for replacement of the carbon adsorption system at the facility. This paper examines the following technologies: carbon adsorption, membrane separation, thermal oxidation, membrane separation-carbon adsorption, and condensation-carbon adsorption. Each control technology is described; the advantages and disadvantages of utilizing each technology for the steroid processing plant are examined; and capital and operating costs associated with the implementation of each technology are presented. The rationale for the technology ultimately chosen to control VOC and HAP emissions is presented.

  1. Volatility basis-set approach simulation of organic aerosol formation in East Asia: implications for anthropogenic-biogenic interaction and controllable amounts

    SciTech Connect (OSTI)

    Matsui, H.; Koike, Makoto; Kondo, Yutaka; Takami, A.; Fast, Jerome D.; Kanaya, Y.; Takigawa, M.

    2014-09-16

    Organic aerosol (OA) simulations using the volatility basis-set approach were made for East Asia and its outflow region. Model simulations were evaluated through comparisons with OA measured by aerosol mass spectrometers in and around Tokyo (at Komaba and Kisai in summer 2003 and 2004) and over the outflow region in East Asia (at Fukue and Hedo in spring 2009). The simulations with aging processes of organic vapors reasonably well reproduced mass concentrations, temporal variations, and formation efficiency of observed OA at all sites. As OA mass was severely underestimated in the simulations without the aging processes, the oxidations of organic vapors are essential for reasonable OA simulations over East Asia. By considering the aging processes, simulated OA concentrations considerably increased from 0.24 to 1.28 g m-3 in the boundary layer over the whole of East Asia. OA formed from the interaction of anthropogenic and biogenic sources was also enhanced by the aging processes. The fraction of controllable OA was estimated to be 87 % of total OA over the whole of East Asia, showing that most of the OA in our simulations formed anthropogenically (controllable). A large portion of biogenic secondary OA (78 % of biogenic secondary OA) formed through the influence of anthropogenic sources. The high fraction of controllable OA in our simulations is likely because anthropogenic emissions are dominant over East Asia and OA formation is enhanced by anthropogenic sources and their aging processes. Both the amounts (from 0.18 to 1.12 g m-3) and the fraction (from 75 % to 87 %) of controllable OA were increased by aging processes of organic vapors over East Asia.

  2. Sorption of organic gases in residential bedrooms andbathrooms

    SciTech Connect (OSTI)

    Singer, B.C.; Hodgson, A.T.; Hotchi, T.; Ming, K.Y.; Sextro,R.G.; Wood, E.E.; Brown, N.J.

    2005-01-05

    Experiments were conducted to characterize organic gas sorption in residential bedrooms (n=4), bathrooms (n=2), and a furnished test chamber. Rooms were studied ''as-is'' with material surfaces and furnishings unaltered. Surface materials were characterized and areas quantified. Experiments included rapid volatilization of a volatile organic compound (VOC) mixture with the room closed and sealed for a 5-h Adsorb phase, followed by 30-min Flush and 2-h closed-room Desorb phases. The mixture included n-alkanes, aromatics, glycol ethers, 2-ethyl-1-hexanol, dichlorobenzene, and organophosphorus compounds. Measured gas-phase concentrations were fit to three variations of a mathematical model that considers sorption occurring at one surface sink and one potential embedded sink. The 2-parameter sink model tracked measurements for most compounds, but improved fits were obtained for some VOCs with a 3-parameter sink-diffusion or a 4-parameter two-sink model. Sorptive partitioning and initial adsorption rates increased with decreasing vapor pressure within each chemical class.

  3. Decomposing VOCs with an electron-beam plasma reactor

    SciTech Connect (OSTI)

    Vitale, S.A.; Hadidi, K.; Cohn, D.R.; Bromberg, L.; Falkos, P.

    1996-04-01

    Several emerging technologies are being tested for decomposing VOCs. Among these are bioreactors, catalytic oxidation, photoinduced decomposition, thermal plasma processes, and nonequilibrium plasma processes. For a new technology to be successfully offered for commercial use, it must be reliable, economically competitive, and ready for use on an industrial scale. The authors have been working on an electron-beam-generated plasma reactor that now meets these prerequisites. The reactor can decompose halogenated organic compounds in dilute concentrations 1--3,000 ppm in airstreams at atmospheric pressure. The technology is more energy efficient than thermal technologies and thus represents lower electricity costs for the overall process. The reactor can easily be scaled to industrial needs and was tested successfully in Hanford, WA, to treat the offgas from the remediation of soils contaminated with CCl{sub 4}.

  4. Observations of Diurnal to Weekly Variations of Monoterpene-Dominated Fluxes of Volatile Organic Compounds from Mediterranean Forests: Implications for Regional Modeling

    SciTech Connect (OSTI)

    Fares, Silvano; Schnitzhofer, Ralf; Xiaoyan, Jiang; Guenther, Alex B.; Hansel, Armin; Loreto, Francesco

    2013-09-04

    Most vascular plants species, especially trees, emit biogenic volatile organic compounds (BVOC). Global estimates of BVOC emissions from plants range from 1 to 1.5 Pg C yr?1.1 Mediterranean forest trees have been described as high BVOC emitters, with emission depending primarily on light and temperature, and therefore being promoted by the warm Mediterranean climate. In the presence of sufficient sunlight and nitrogen oxides (NOx), the oxidation of BVOCs can lead to the formation of tropospheric ozone, a greenhouse gas with detrimental effects on plant health, crop yields, and human health. BVOCs are also precursors for aerosol formation, accounting for a significant fraction of secondary organic aerosol (SOA) produced in the atmosphere. The presidential Estate of Castelporziano covers an area of about 6000 ha located 25 km SW from the center of Rome, Italy (Figure 1) and hosts representative forest ecosystems typical of Mediterranean areas: holm oak forests, pine forests, dune vegetation, mixed oak and pine forests. Between 1995 and 2011, three intensive field campaigns were carried out on Mediterranean-type ecosystems inside the Estate. These campaigns were aimed at measuring BVOC emissions and environmental parameters, to improve formulation of basal emission factors (BEFs), that is, standardized emissions at 30 C and 1000 ?mol m?2s?1 of photosynthetic active radiation (PAR). BEFs are key input parameters of emission models. The first campaign in Castelporziano was a pioneering integrated study on biogenic emissions (1993? 19964). BVOC fluxes from different forest ecosystems were mainly investigated using plant- and leaf enclosures connected to adsorption tubes followed by GC?MS analysis in the laboratory. This allowed a first screening of Mediterranean species with respect to their BVOC emission potential, environmental control, and emission algorithms. In particular, deciduous oak species revealed high isoprene emissions (Quercus f rainetto, Quercus petrea, Quercus pubescens), while evergreen oaks emitted monoterpenes only, for example, Quercus ilex = holm oak. Differences in constitutive emission patterns discovered in Castelporziano supplied basic information to discriminate oak biodiversity in following studies.Ten years later, a second experimental campaign took place in spring and summer 2007 on a dune-shrubland experimental site. In this campaign, the use of a proton transfer reaction mass spectrometer (PTR-MS14) provided the fast BVOC observations necessary for quasi-real-time flux measurements using Disjunct Eddy Covariance. This allowed for the first time continuous measurements and BEFs calculation at canopy level. Finally, in September 2011 a third campaign was performed with the aim of further characterizing and improving estimates of BVOC fluxes from mixed Mediterranean forests dominated by a mixed holm oak and stone pine forest, using for the first time a proton transfer reaction?time-of-flight?mass spectrometer (PTR-TOF-MS). In contrast to the standard quadrupole PTR-MS, which can only measure one m/z ratio at a discrete time, thus being inadequate to quantify fluxes of more than a handful of compounds simultaneously, PTR-TOF-MS allowed simultaneous measurements (10 Hz) of fluxes of all BVOCs at the canopy level by Eddy Covariance.17?20, 50 In this work, we reviewed BEFs from previous campaigns in Castelporziano and calculated new BEFs from the campaign based on PTR-TOF-MS analysis. The new BEFs were used to parametrize the model of emissions of gases and aerosols from nature (MEGAN v2.11).

  5. HYDROGEN AND VOC RETENTION IN WASTE BOXES

    SciTech Connect (OSTI)

    PACE ME; MARUSICH RM

    2008-11-21

    The Hanford Waste Management Project Master Documented Safety Analysis (MDSA) (HNF-14741, 2003) identifies derived safety controls to prevent or mitigate the risks of a single-container deflagration during operations requiring moving, venting or opening transuranic (TRU)-waste containers. The issue is whether these safety controls are necessary for operations involving TRU-waste boxes that are being retrieved from burial at the Hanford Site. This paper investigates the potential for a deflagration hazard within these boxes and whether safety controls identified for drum deflagration hazards should be applied to operations involving these boxes. The study evaluates the accumulation of hydrogen and VOCs within the waste box and the transport of these gases and vapors out of the waste box. To perform the analysis, there were numerous and major assumptions made regarding the generation rate and the transport pathway dimensions and their number. Since there is little actual data with regards to these assumptions, analyses of three potential configurations were performed to obtain some indication of the bounds of the issue (the concentration of hydrogen or flammable VOCs within a waste box). A brief description of each of the three cases along with the results of the analysis is summarized.

  6. Using a flame ionization detector (FID) to continuously measure toxic organic vapors in a paint spray booth. Rept. for Jul 91-Jan 92

    SciTech Connect (OSTI)

    Whitfield, J.K.; Howe, G.B.; Pate, B.A.; Wander, J.D.

    1992-01-01

    The paper reports the demonstration of linear and similar responses of a Ratfisch RS-55CA flame ionization detector (FID) to a solvent mixture identical to the volatile organic compounds (VOCs) in the coating and catalyst (NSN 8010-01-336-3036) and to the calibrating gas (propane) used in field calibrations of the FID. Sensitivity and linearity have been shown to extend from 715 to 45 mg/cu m, which brackets the calculated short-term exposure limit (STEL) and lower action thresholds. Monitoring is maintained constantly and, under field conditions, equilibration occurs rapidly (analysis and output transpire in milliseconds). As a trigger for fail-safe conversion from recirculation mode to a straight-through paint spray booth configuration, the FID may confidently be expected to initiate a corrective response before a transient elevation of VOC concentrations overexposes area personnel.

  7. Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

    2014-05-06

    Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

  8. Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants/Hygroscopicity and CCN Activity of Secondary & Processed Primary Organic Aerosols

    SciTech Connect (OSTI)

    Ziemann, P.J.; Arey, J.; Atkinson, R.; Kreidenweis, S.M.; Petters, M.D.

    2012-06-13

    The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was to carry out reactions of representative anthropogenic and biogenic VOCs and organic particles with ozone (O3), and hydroxyl (OH), nitrate (NO3), and chlorine (Cl) radicals, which are the major atmospheric oxidants, under simulated atmospheric conditions in large-volume environmental chambers. A combination of on-line and off-line analytical techniques were used to monitor the chemical and physical properties of the particles including their hygroscopicity and CCN activity. The results of the studies were used to (1) improve scientific understanding of the relationships between the chemical composition of organic particles and their hygroscopicity and CCN activity, (2) develop an improved molecular level theoretical framework for describing these relationships, and (3) establish a large database that is being used to develop parameterizations relating organic aerosol chemical properties and SOA sources to particle hygroscopicity and CCN activity for use in regional and global atmospheric air quality and climate models.

  9. Associations of indoor carbon dioxide concentrations, VOCS, environmental susceptibilities with mucous membrane and lower respiratory sick building syndrome symptoms in the BASE study: Analyses of the 100 building dataset

    SciTech Connect (OSTI)

    Apte, M.G.; Erdmann, C.A.

    2002-10-01

    Using the 100 office-building Building Assessment Survey and Evaluation (BASE) Study dataset, we performed multivariate logistic regression analyses to quantify the associations between indoor minus outdoor CO{sub 2} (dCO{sub 2}) concentrations and mucous membrane (MM) and lower respiratory system (Lresp) Sick Building Syndrome (SBS) symptoms, adjusting for age, sex, smoking status, presence of carpet in workspace, thermal exposure, relative humidity, and a marker for entrained automobile exhaust. Using principal components analysis we identified a number of possible sources of 73 measured volatile organic compounds in the office buildings, and assessed the impact of these VOCs on the probability of presenting the SBS symptoms. Additionally we included analysis adjusting for the risks for predisposition of having SBS symptoms associated with the allergic, asthmatic, and environmentally sensitive subpopulations within the office buildings. Adjusted odds ratios (ORs) for statistically significant, dose-dependant associations (p<0.05) for dry eyes, sore throat, nose/sinus congestion, and wheeze symptoms with 100-ppm increases in dCO{sub 2} ranged from 1.1 to 1.2. These results suggest that increases in the ventilation rates per person among typical office buildings will, on average significantly reduce the prevalence of several SBS symptoms, up to 80%, even when these buildings meet the existing ASHRAE ventilation standards for office buildings. VOC sources were observed to play an role in direct association with mucous membrane and lower respiratory irritation, and possibly to be indirectly involved in indoor chemical reactions with ozone that produce irritating compounds associated with SBS symptoms. O-xylene, possibly emitted from furniture coatings was associated with shortness of breath (OR at the maximum concentration = 8, p < 0.05). The environmental sensitivities of a large subset of the office building population add to the overall risk of SBS symptoms (ORs ranging from 2 to above 11) within the buildings.

  10. APPLICATION OF STIR BAR SORPTIVE EXTRACTION TO ANALYSIS OF VOLATILE AND SEMIVOLATILE ORGANIC CHEMICALS OF POTENTIAL CONCERN IN SOLIDS AND AQUEOUS SAMPLES FROM THE HANFORD SITE

    SciTech Connect (OSTI)

    FRYE JM; KUNKEL JM

    2009-03-05

    Stir bar sorptive extraction was applied to aqueous and solid samples for the extraction and analysis of organic compounds from the Hanford chemicals of potential concern list, as identified in the vapor data quality objectives. The 222-S Laboratory analyzed these compounds from vapor samples on thermal desorption tubes as part of the Hanford Site industrial hygiene vapor sampling effort.

  11. Flexible CHP System with Low NOx, CO and VOC Emissions - Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 Flexible CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 The Gas Technology Institute, in ...

  12. Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions - ...

  13. Zero discharge organic coatings, powder paint - UV curable paint - E-coat. Volume 1. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Leal, J.; Martin, D.R.; Spadafora, S.J.; Eng, A.T.; Stark, H.

    1995-06-01

    Zero Discharge Organic Coatings project developed powder paint, Ultraviolet (UV) curable paint, and electro- coating (E-coat) paint for military Applications. These technologies offer potential for high performance coatings with little or no volatile organic compound (VOC) emissions or hazardous waste generation. The ZDOC project focused on formulating non-toxic corrosion inhibitors into these coating technologies, and the applications development of powder coatings. Non-toxic replacements for traditional lead and chromate inhibitors were selected based on a previous NAWCADWAR investigation. Once incorporated, the performance of the coatings with and without inhibitors was compared. Also, the protective mechanisms of these inhibitors were studied. The applications development for powder coatings analyzed technologies to allow powder coating of non-conductive substrates and evaluated the use of IR energy to cure powder coatings. Inhibitors were successfully incorporated into electrocoatings and powder coatings, however corrosion performance results varied with coating formulation.

  14. In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palm, B. B.; Campuzano-Jost, P.; Ortega, A. M.; Day, D. A.; Kaser, L.; Jud, W.; Karl, T.; Hansel, A.; Hunter, J. F.; Cross, E. S.; et al

    2015-11-04

    Ambient air was oxidized by OH radicals in an oxidation flow reactor (OFR) located in a montane pine forest during the BEACHON-RoMBAS campaign to study biogenic secondary organic aerosol (SOA) formation and aging. High OH concentrations and short residence times allowed for semi-continuous cycling through a large range of OH exposures ranging from hours to weeks of equivalent (eq.) atmospheric aging. A simple model is derived and used to account for the relative time scales of condensation of low volatility organic compounds (LVOCs) onto particles, condensational loss to the walls, and further reaction to produce volatile, non-condensing fragmentation products. MoremoreSOA production was observed in the OFR at nighttime (average 4 ?g m-3 when LVOC fate corrected) compared to daytime (average 1 ?g m-3 when LVOC fate corrected), with maximum formation observed at 0.41.5 eq. days of photochemical aging. SOA formation followed a similar diurnal pattern to monoterpenes, sesquiterpenes, and toluene + p-cymene concentrations, including a substantial increase just after sunrise at 07:00 LT. Higher photochemical aging (> 10 eq. days) led to a decrease in new SOA formation and a loss of preexisting OA due to heterogeneous oxidation followed by fragmentation and volatilization. When comparing two different commonly used methods of OH production in OFRs (OFR185 and OFR254), similar amounts of SOA formation were observed. We recommend the OFR185 mode for future forest studies. Concurrent gas-phase measurements of air after OH oxidation illustrate the decay of primary VOCs, production of small oxidized organic compounds, and net production at lower ages followed by net consumption of terpenoid oxidation products as photochemical age increased. New particle formation was observed in the reactor after oxidation, especially during times when precursor gas concentrations and SOA formation were largest. Approximately 6 times more SOA was formed in the reactor from OH oxidation than could be explained by the VOCs measured in ambient air. Several recently-developed instruments quantified ambient semi- and intermediate-volatility organic compounds (S/IVOCs) that were not detected by a PTR-TOF-MS. An SOA yield of 2480 % from those compounds can explain the observed SOA, suggesting that these typically unmeasured S/IVOCs play a substantial role in ambient SOA formation. Our results allow ruling out condensation sticking coefficients much lower than 1. Our measurements help clarify the magnitude of SOA formation in forested environments, and demonstrate methods for interpretation of ambient OFR measurements.less

  15. Particulate and gaseous organic receptor modeling for the southern California Air Quality Study. Final report

    SciTech Connect (OSTI)

    Watson, J.G.; Chow, J.G.; Lu, Z.; Gertler, A.W.

    1993-11-01

    The Chemical Mass Balance (CMB) receptor model was applied to the chemically-speciated diurnal particulate matter samples and volatile organic compound (VOC) acquired during the summer and fall campaigns of the Southern California Air Quality Study (SCAQS). Source profiles applicable to the Los Angeles area were used to apportion PM[sub (2.5)] and PM[sub (10)] to primary paved road dust, primary construction dust, primary motor vehicle exhaust, primary marine aerosol, secondary ammonium nitrate, and secondary ammonium sulfate. Nonmethane hydrocarbon was apportioned to motor vehicle exhaust, liquid fuel, gasoline vapor, gas leaks, architectural and industrial coatings, and biogenic emissions. Suspended dust was the major contributor to PM(10) during the summer, while secondary ammonium nitrate and primary motor vehicle exhaust contributions were high in the fall. Motor vehicle exhaust was the major contributor to nonmethane hydrocarbons, ranging from 30% to 70% of the total.

  16. Organization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Organization Print A complete ALS organization chart (March 2016) is available in PDF. Appointed and elected members of advisory panels provide guidance to Berkeley Lab and ALS management in developing the ALS scientific and user programs. ALS Staff Photo staff photo thumb Click on the image to see a recent photo of ALS staff in front of the dome. The photo was taken on May 14, 2013. ALS Management and Advisory Team Roger Falcone, Director Steve Kevan, Deputy Division Director,

  17. Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Gas Technology Institute (GTI), June 2011 | Department of Energy Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio

  18. Volatile chemical reagent detector

    DOE Patents [OSTI]

    Chen, Liaohai; McBranch, Duncan; Wang, Rong; Whitten, David

    2004-08-24

    A device for detecting volatile chemical reagents based on fluorescence quenching analysis that is capable of detecting neutral electron acceptor molecules. The device includes a fluorescent material, a contact region, a light source, and an optical detector. The fluorescent material includes at least one polymer-surfactant complex. The polymer-surfactant complex is formed by combining a fluorescent ionic conjugated polymer with an oppositely charged surfactant. The polymer-surfactant complex may be formed in a polar solvent and included in the fluorescent material as a solution. Alternatively, the complex may be included in the fluorescent material as a thin film. The use of a polymer-surfactant complex in the fluorescent material allows the device to detect both neutral and ionic acceptor molecules. The use of a polymer-surfactant complex film allows the device and the fluorescent material to be reusable after exposing the fluorescent material to a vacuum for limited time.

  19. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-11-01

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  20. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-01-01

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  1. Limited effect of anthropogenic nitrogen oxides on secondary organic aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-12-08

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but it can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR (National Center for Atmospheric Research) Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product volatility basis set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. Small differences are found for themore » no-aging VBS and 2-product schemes; large increases in SOA production and the SOA-to-OA ratio are found for the aging scheme. The predicted organic aerosol amounts capture both the magnitude and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of 2 compared to aerosol mass spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different regions and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9–5.6, 6.4–12.0 and 0.9–2.8 % for global, southeast US and Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to a limited shift in chemical regime, to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  2. Limited effect of anthropogenic nitrogen oxides on Secondary Organic Aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-08-28

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product Volatility Basis Set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. The predicted organic aerosol amounts capture both the magnitude and distribution ofmore » US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of two compared to Aerosol Mass Spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different region and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9 to 5.6, 6.4 to 12.0 and 0.9 to 2.8 % for global, the southeast US and the Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  3. Services Initiatives | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Soy ink is renewable and is very low in Volatile Organic Compounds (VOCs) which evaporate little and cause no air pollution, whereas petroleum-based inks are high in VOCs and cause ...

  4. Building America Case Study: Ventilation System Effectiveness...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... particle counts for formaldehyde and other volatile organic compound (VOC) concentrations. ... In House 1, all ventilation systems reduced the formaldehyde concentration compared to the ...

  5. Albany, OR * Anchorage, AK * Morgantown, WV * Pittsburgh, PA...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... via thermal desorption) to measure volatile organic compounds (VOCs); * Air Pollution Instruments gaseous monitors for NO x and O 3 ; * R.M. Young and Davis Instruments ...

  6. Attachment N

    Office of Environmental Management (EM)

    and Recovery Act RPD relative percent difference SOP standard operating procedure TIC tentatively identified compound TRU Transuranic VOC volatile organic compound WIPP...

  7. Quantitative organic vapor-particle sampler

    DOE Patents [OSTI]

    Gundel, Lara; Daisey, Joan M.; Stevens, Robert K.

    1998-01-01

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  8. Flexible CHP System with Low NOx, CO and VOC Emissions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Flexible CHP System with Low NOx, CO and VOC Emissions Flexible CHP System with Low NOx, CO and VOC Emissions Introduction A combined heat and power (CHP) system can be a financially attractive energy option for many industrial and commercial facilities. This is particularly the case in areas of the country with high electricity rates. However, regions with air quality concerns often have strict limits on criteria pollutants, such as nitrogen oxide (NOx), carbon monoxide (CO), and

  9. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2014-12-20

    Four different parameterizations for the formation and evolution of secondary organic aerosol (SOA) are evaluated using a 0-D box model representing the Los Angeles Metropolitan Region during the CalNex 2010 field campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA formed only from the oxidation of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generationmore » oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model-measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model/measurement agreement for mass concentration. When comparing the three parameterizations, the Grieshop et al. (2009) parameterization more accurately reproduces both the SOA mass concentration and oxygen-to-carbon ratio inside the urban area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the parameterizations over-predict urban SOA formation at long photochemical ages (≈ 3 days) compared to observations from multiple sites, which can lead to problems in regional and global modeling. Among the explicitly modeled VOCs, the precursor compounds that contribute the greatest SOA mass are methylbenzenes. Polycyclic aromatic hydrocarbons (PAHs) are less important precursors and contribute less than 4% of the SOA mass. The amounts of SOA mass from diesel vehicles, gasoline vehicles, and cooking emissions are estimated to be 16–27, 35–61, and 19–35%, respectively, depending on the parameterization used, which is consistent with the observed fossil fraction of urban SOA, 71 (±3) %. In-basin biogenic VOCs are predicted to contribute only a few percent to SOA. A regional SOA background of approximately 2.1 μg m−3 is also present due to the long distance transport of highly aged OA. The percentage of SOA from diesel vehicle emissions is the same, within the estimated uncertainty, as reported in previous work that analyzed the weekly cycles in OA concentrations (Bahreini et al., 2012; Hayes et al., 2013). However, the modeling work presented here suggests a strong anthropogenic source of modern carbon in SOA, due to cooking emissions, which was not accounted for in those previous studies. Lastly, this work adapts a simple two-parameter model to predict SOA concentration and O/C from urban emissions. This model successfully predicts SOA concentration, and the optimal parameter combination is very similar to that found for Mexico City. This approach provides a computationally inexpensive method for predicting urban SOA in global and climate models. We estimate pollution SOA to account for 26 Tg yr−1 of SOA globally, or 17% of global SOA, 1/3 of which is likely to be non-fossil.« less

  10. Summary Report for the Development of Materials for Volatile Radionuclides

    SciTech Connect (OSTI)

    Strachan, Denis M.; Chun, Jaehun; Henager, Charles H.; Matyas, Josef; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

    2010-11-22

    The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2010, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogenides. For 85Kr, metal organic framework (MOF) structures were investigated.

  11. Method of measurement of VOCs in the off-gas and wastewater of wastewater treatment plants

    SciTech Connect (OSTI)

    Min Wang; Keener, T.C.; Orton, T.L.; Zhu, H.; Bishop, P.; Pekonen, S.; Siddiqui, K.

    1997-12-31

    VOCs need to be controlled according to Title 3 of the 1990 Clean Air Act Amendments (CAAA), so an accurate estimation of the total VOC emissions must be attained. This paper reports on a study where EPA method 624 was revised so that this method could be used for VOC analysis both in the water and off-gas of wastewater treatment plants. The revised method uses the same approach and equipment as water and soil analyses, thereby providing a great time and cost advantage for anyone needing to perform this type of analysis. Without using a cryogenic preconcentration step, gas samples from Tedlar bags are easily analyzed to concentrations of approximately 20 ppb using scan mode in a GC-MS unit. For the wastewater, scan mode was still used for the identification, but Selected Ion Monitoring (SIM) mode was used for quantitative analysis because of lower VOC concentration in the water. The results show that this method`s detection limit (MDL) was lowered 2--3 orders of magnitude when compared with scan mode. The modified method has been successfully applied to the identification and quantitative analysis of wastewater and off-gas VOCs from a publicly owned treatment works (POTW) aeration basin (120 MGD).

  12. Method for lowering the VOCS emitted during drying of wood products

    DOE Patents [OSTI]

    Banerjee, Sujit (1832 Jacksons Creek Point, Marietta, GA 30068); Boerner, James Robert (154 Junedale Rd., Cincinnati, OH 45218); Su, Wei (2262 Orleans Ave., Marietta, GA 30062)

    2000-01-01

    The present invention is directed to a method for removal of VOCs from wood products prior to drying the wood products. The method of the invention includes the steps of providing a chamber having an opening for receiving wood and loading the chamber with green wood. The wood is loaded to an extent sufficient to provide a limited headspace in the chamber. The chamber is then closed and the wood is heated in the chamber for a time and at a temperature sufficient to saturate the headspace with moisture and to substantially transfer VOCs from the wood product to the moisture in the headspace.

  13. Experiences with a compost biofilter for VOC control from batch chemical manufacturing operations

    SciTech Connect (OSTI)

    Gilmore, G.L.; Briggs, T.G.

    1997-12-31

    The Synthetic Chemicals Division of Eastman Kodak Company makes a large number of complex organic chemicals using batch reactor syntheses. Exhaust gas, resulting from batch reactor operations, typically contains many different volatile organic chemicals with dynamic concentration profiles. Exhaust streams of this type have been considered difficult to treat effectively by biofiltration. Eastman Kodak Company was interested in exploring the applicability of biofiltration to treat these types of off-gas streams as an alternative to more costly control technologies. To this end, a 20,000 cfm capacity BIOTON{reg_sign} biofilter was installed in December 1995 in Kodak Park, Rochester, New York. A study was initiated to determine the overall efficiency of the biofilter, as well as the chemical specific efficiencies for a number of organic compounds. Flame ionization detectors operated continuously on the inlet and outlet of the biofilter to measure total hydrocarbon concentrations. A process mass spectrometer was installed to simultaneously monitor the concentrations of seven organics in the inlet and outlet of the biofilter. In addition, the process control software for the biofilter continuously recorded pressure drop, temperature, and moisture content of the bed. This paper presents operating and performance data for the BIOTON biofilter from start-up through about eleven months of continuous operation. Included are data collected over a wide range of loading conditions, during initial start-up, and during start-up after shutdown periods. Data for total hydrocarbons, methanol, acetone, and heptane are presented. The relationship between organic loading and removal efficiency is discussed in the biofilter, which typically operates significantly below its design loading specification. The overall control efficiency of the biofilter at design loadings exceeds the design control efficiency of 90%.

  14. Modelling of volatility in monetary transmission mechanism

    SciTech Connect (OSTI)

    Dobešová, Anna; Klepáč, Václav; Kolman, Pavel; Bednářová, Petra

    2015-03-10

    The aim of this paper is to compare different approaches to modeling of volatility in monetary transmission mechanism. For this purpose we built time-varying parameter VAR (TVP-VAR) model with stochastic volatility and VAR-DCC-GARCH model with conditional variance. The data from three European countries are included in the analysis: the Czech Republic, Germany and Slovakia. Results show that VAR-DCC-GARCH system captures higher volatility of observed variables but main trends and detected breaks are generally identical in both approaches.

  15. Securing non-volatile memory regions

    DOE Patents [OSTI]

    Faraboschi, Paolo; Ranganathan, Parthasarathy; Muralimanohar, Naveen

    2013-08-20

    Methods, apparatus and articles of manufacture to secure non-volatile memory regions are disclosed. An example method disclosed herein comprises associating a first key pair and a second key pair different than the first key pair with a process, using the first key pair to secure a first region of a non-volatile memory for the process, and using the second key pair to secure a second region of the non-volatile memory for the same process, the second region being different than the first region.

  16. Reactive flash volatilization of fluid fuels

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

    2013-01-08

    The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

  17. Reduction of VOC emissions from metal dip coating applications -- Canam Steel Corporation Point of Rocks, MD case study

    SciTech Connect (OSTI)

    Monfet, J.P.

    1997-12-31

    The reduction of VOC emissions from metal dip coating applications is not an environmental constraint, it is an economic opportunity. This case study shows how the industry can reap economic benefits from VOC reductions while improving air quality. The Canam Steel Corporation plant located in Point of Rocks, MD operates dip tanks for primer application on fabricated steel joists and joist girders. This process is presently subject to a regulation that limits the paint VOC content to 3.5 pounds per gallon of coating less water. As a result of the high paint viscosity associated with that regulation, the paint thickness of the dipped steel is thicker than the customers` specifications. Most of the VOC emissions can therefore be associated with the excess of paint applied to the products rather than to the required thickness of the coating. The higher paint usage rate has more than environmental consequences, it increases the cost of the applied coating. The project is to reduce the paint usage by controlling the viscosity of the coating in the tank. Experimental results as well as actual mass balance calculations show that using a higher VOC content paint would reduce the overall VOC emissions. The author explained the project to the Maryland Department of the Environment (MDE) Air and Radiation Management Administration. First, the MDE agreed to develop a new RACT determination for fabricated steel dipping operations. The new regulation would limit the amount of VOC than can be emitted to dip coat a ton of fabricated steel. Second, the MDE agreed to allow experimentation of the higher VOC content paint as a pilot project for the new regulation. This paper demonstrates the need for a RACT determination specific to fabricated steel dipping operations.

  18. Ecosystem-scale volatile organic compound fluxes during an extreme...

    Office of Scientific and Technical Information (OSTI)

    ... Univ. of California, Irvine, CA (United States) Univ. of Innsbruck (Austria) Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State Univ., Pullman, ...

  19. Comparative Toxicity of Combined Particle and Semi-Volatile Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Components Responsible for the Health Effects of Inhaled Engine Emissions Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles

  20. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicles Operated at 30F 2003 DEER Conference Presentation: Centers for Disease Control and Prevention PDF icon 2003deerwallace.pdf More Documents & Publications In Vitro ...

  1. sc0011884-advanced-cooling | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative, Economical, Ultra-clean Incinerator for Low Heating Value VOC Emissions Last Reviewed 12/11/2015 DE-SC0011884 Goal The project goal is to develop an innovative, non-catalytic high destruction efficiency, and low fuel consumption volatile organic compounds (VOC) incinerator to reduce VOCs from condensate tanks and other low heat value waste gas streams. Performers Advanced Cooling Technologies (ACT), Inc Background VOC emissions from various sources (oil and gas storage tank,

  2. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization Organization

  3. Understanding sources of organic aerosol during CalNex-2010 using the CMAQ-VBS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Woody, M. C.; Baker, K. R.; Hayes, P. L.; Jimenez, J. L.; Koo, B.; Pye, H. O. T.

    2015-10-05

    Community Multiscale Air Quality (CMAQ) model simulations utilizing the volatility basis set (VBS) treatment for organic aerosols (CMAQ-VBS) were evaluated against measurements collected at routine monitoring networks (Chemical Speciation Network (CSN) and Interagency Monitoring of Protected Visual Environments (IMPROVE)) and those collected during the 2010 California at the Nexus of Air Quality and Climate Change (CalNex) field campaign to examine important sources of organic aerosol (OA) in southern California. CMAQ-VBS (OA lumped by volatility, semivolatile POA) underpredicted total organic carbon (OC) at CSN (?25.5 % Normalized Median Bias (NMdnB)) and IMPROVE (?63.9 % NMdnB) locations and total OC wasmoreunderpredicted to a greater degree compared to the CMAQ-AE6 (9.9 and ?55.7 % NMdnB, respectively; semi-explicit OA treatment, SOA lumped by parent hydrocarbon, nonvolatile POA). However, comparisons to aerosol mass spectrometer (AMS) measurements collected at Pasadena, CA indicated that CMAQ-VBS better represented the diurnal profile and the primary/secondary split of OA. CMAQ-VBS secondary organic aerosol (SOA) underpredicted the average measured AMS oxygenated organic aerosol (OOA, a surrogate of SOA) concentration by a factor of 5.2 (4.7 ?g m?3 measured vs. 0.9 ?g m?3 modeled), a considerable improvement to CMAQ-AE6 SOA predictions, which were approximately 24 lower than the average AMS OOA concentration. We use two new methods, based on species ratios and on a simplified SOA parameterization from the observations, to apportion the SOA underprediction for CMAQ-VBS to too slow photochemical oxidation (estimated as 1.5 lower than observed at Pasadena using ? log (NOx: NOy)), low intrinsic SOA formation efficiency (low by 1.6 to 2 for Pasadena), and too low emissions or too high dispersion for the Pasadena site (estimated to be 1.6 to 2.3 too low/high). The first and third factors will be similar for CMAQ-AE6, while the intrinsic SOA formation efficiency for that model is estimated to be too low by about 7. For CMAQ-VBS, 90 % of the anthropogenic SOA mass formed was attributed to aged secondary semivolatile vapors (70 % originating from volatile organic compounds (VOCs) and 20 % from intermediate volatility compounds (IVOCs)). From source-apportioned model results, we found most of the CMAQ-VBS modeled POA at the Pasadena CalNex site was attributable to meat cooking emissions (48 %, and consistent with a substantial fraction of cooking OA in the observations), compared to 18 % from gasoline vehicle emissions, 13 % from biomass burning (in the form of residential wood combustion), and 8 % from diesel vehicle emissions. All "other" inventoried emission sources (e.g. industrial/point sources) comprised the final 13 %. The CMAQ-VBS semivolatile POA treatment underpredicted AMS hydrocarbon-like OA (HOA) + cooking-influenced OA (CIOA) at Pasadena by a factor of 1.8 (1.16 ?g m?3 modeled vs. 2.05 ?g m?3 observed) compared to a factor of 1.4 overprediction of POA in CMAQ-AE6, but did well to capture the AMS diurnal profile of HOA and CIOA, with the exception of the midday peak. We estimated that using the National Emission Inventory (NEI) POA emissions without scaling to represent SVOCs underestimates SVOCs by ~1.7.less

  4. Volatile Species Retention During Metallic Fuel Casting

    SciTech Connect (OSTI)

    Randall S. Fielding; Douglas L. Proter

    2013-10-01

    Metallic nuclear fuels are candidate transmutation fuel forms for advanced fuel cycles. Through the operation of the Experimental Breeder Reactor II metallic nuclear fuels have been shown to be robust and easily manufactured. However, concerns have been raised concerning loss of americium during the casting process because of its high vapor pressure. In order to address these concerns a gaseous diffusion model was developed and a series of experiments using both manganese and samarium as surrogates for americium were conducted. The modeling results showed that volatility losses can be controlled to essentially no losses with a modest overpressure. Experimental results also showed volatile species retention down to no detectable losses through overpressure, although the loss values varied from the model results the same trend was seen. Bases on these results it is very probably that americium losses through volatility can be controlled to no detectable losses through application of a modest overpressure during casting.

  5. Non-volatile memory for checkpoint storage

    DOE Patents [OSTI]

    Blumrich, Matthias A.; Chen, Dong; Cipolla, Thomas M.; Coteus, Paul W.; Gara, Alan; Heidelberger, Philip; Jeanson, Mark J.; Kopcsay, Gerard V.; Ohmacht, Martin; Takken, Todd E.

    2014-07-22

    A system, method and computer program product for supporting system initiated checkpoints in high performance parallel computing systems and storing of checkpoint data to a non-volatile memory storage device. The system and method generates selective control signals to perform checkpointing of system related data in presence of messaging activity associated with a user application running at the node. The checkpointing is initiated by the system such that checkpoint data of a plurality of network nodes may be obtained even in the presence of user applications running on highly parallel computers that include ongoing user messaging activity. In one embodiment, the non-volatile memory is a pluggable flash memory card.

  6. Proboscis extension reflex platform for volatiles and semi-volatiles detection

    DOE Patents [OSTI]

    Wingo, Robert M. (Los Alamos, NM); McCabe, Kirsten J. (Los Alamos, NM); Haarmann, Timothy K. (Jemez Pueblo, NM)

    2010-11-30

    The present invention provides an apparatus for the detection of volatile and semi-volatile chemicals using the olfactory abilities of honey bees that are trained to respond to the presence of a specific chemical in a sample of gas with the proboscis extension reflex (PER). In particular, the geometry and arrangement of the parts of the apparatus are such that the amount of surface area in contact with the sample of gas prior to its introduction to the bees is minimized to improve the detection of particular volatile and semi-volatile that have a tendency to "stick" to contacting surfaces, especially certain chemicals associated with explosives and narcotics. According to another aspect of the present invention, a pre-concentrating means is incorporated with the device to effectively increase the concentration of "sticky" chemicals presented to the insects.

  7. Rocky Flats Site Expands Solar Power for Treating Groundwater

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) recently added a 6 kilowatt solar photovoltaic system to provide power to operate an enhanced treatment system that removes volatile organic compounds (VOC) from contaminated groundwater at the Rocky Flats, Colorado, Site.

  8. Progress Toward Operable Unit 1 Groundwater Cleanup at the Mound, Ohio, Site

    Broader source: Energy.gov [DOE]

    Groundwater in Operable Unit 1 (OU-1) has been impacted by volatile organic compound (VOC)-contaminated materials in the former solid waste landfill. The remedy for controlling contamination from...

  9. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2015-05-26

    Four different literature parameterizations for the formation and evolution of urban secondary organic aerosol (SOA) frequently used in 3-D models are evaluated using a 0-D box model representing the Los Angeles metropolitan region during the California Research at the Nexus of Air Quality and Climate Change (CalNex) 2010 campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle- and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA that formed only from the oxidationmore » of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generation oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model–measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate-volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model–measurement agreement for mass concentration. The results from the three parameterizations show large differences (e.g., a factor of 3 in SOA mass) and are not well constrained, underscoring the current uncertainties in this area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the recent parameterizations overpredict urban SOA formation at long photochemical ages (≈ 3 days) compared to observations from multiple sites, which can lead to problems in regional and especially global modeling. However, reducing IVOC emissions by one-half in the model to better match recent IVOC measurements improves SOA predictions at these long photochemical ages. Among the explicitly modeled VOCs, the precursor compounds that contribute the greatest SOA mass are methylbenzenes. Measured polycyclic aromatic hydrocarbons (naphthalenes) contribute 0.7% of the modeled SOA mass. The amounts of SOA mass from diesel vehicles, gasoline vehicles, and cooking emissions are estimated to be 16–27, 35–61, and 19–35%, respectively, depending on the parameterization used, which is consistent with the observed fossil fraction of urban SOA, 71(±3) %. The relative contribution of each source is uncertain by almost a factor of 2 depending on the parameterization used. In-basin biogenic VOCs are predicted to contribute only a few percent to SOA. A regional SOA background of approximately 2.1 μg m−3 is also present due to the long-distance transport of highly aged OA, likely with a substantial contribution from regional biogenic SOA. The percentage of SOA from diesel vehicle emissions is the same, within the estimated uncertainty, as reported in previous work that analyzed the weekly cycles in OA concentrations (Bahreini et al., 2012; Hayes et al., 2013). However, the modeling work presented here suggests a strong anthropogenic source of modern carbon in SOA, due to cooking emissions, which was not accounted for in those previous studies and which is higher on weekends. Lastly, this work adapts a simple two-parameter model to predict SOA concentration and O/C from urban emissions. This model successfully predicts SOA concentration, and the optimal parameter combination is very similar to that found for Mexico City. This approach provides a computationally inexpensive method for predicting urban SOA in global and climate models. We estimate pollution SOA to account for 26 Tg yr−1 of SOA globally, or 17% of global SOA, one-third of which is likely to be non-fossil.« less

  10. Analysis of Price Volatility in Natural Gas Markets

    Reports and Publications (EIA)

    2007-01-01

    This article presents an analysis of price volatility in the spot natural gas market, with particular emphasis on the Henry Hub in Louisiana.

  11. Volatiles in hydrothermal fluids- A mass spectrometric study...

    Open Energy Info (EERE)

    Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  12. Design of Semiconductor-Based Back Reflectors for High Voc Monolithic Multijunction Solar Cells: Preprint

    SciTech Connect (OSTI)

    Garcia, I.; Geisz, J.; Steiner, M.; Olson, J.; Friedman, D.; Kurtz, S.

    2012-06-01

    State-of-the-art multijunction cell designs have the potential for significant improvement before going to higher number of junctions. For example, the Voc can be substantially increased if the photon recycling taking place in the junctions is enhanced. This has already been demonstrated (by Alta Devices) for a GaAs single-junction cell. For this, the loss of re-emitted photons by absorption in the underlying layers or substrate must be minimized. Selective back surface reflectors are needed for this purpose. In this work, different architectures of semiconductor distributed Bragg reflectors (DBR) are assessed as the appropriate choice for application in monolithic multijunction solar cells. Since the photon re-emission in the photon recycling process is spatially isotropic, the effect of the incident angle on the reflectance spectrum is of central importance. In addition, the DBR structure must be designed taking into account its integration into the monolithic multijunction solar cells, concerning series resistance, growth economics, and other issues. We analyze the tradeoffs in DBR design complexity with all these requirements to determine if such a reflector is suitable to improve multijunction solar cells.

  13. Chemical characterization of biogenic secondary organic aerosol generated from plant emissions under baseline and stressed conditions: inter- and intra-species variability for six coniferous species

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faiola, C. L.; Wen, M.; VanReken, T. M.

    2015-04-01

    The largest global source of secondary organic aerosol (SOA) in the atmosphere is derived from the oxidation of biogenic emissions. Plant stressors associated with a changing environment can alter both the quantity and composition of the compounds that are emitted. Alterations to the biogenic volatile organic compound (BVOC) profile could impact the characteristics of the SOA formed from those emissions. This study investigated the impacts of one global change stressor, increased herbivory, on the composition of SOA derived from real plant emissions. Herbivory was simulated via application of methyl jasmonate (MeJA), a proxy compound. Experiments were repeated under pre- andmore » post-treatment conditions for six different coniferous plant types. Volatile organic compounds (VOCs) emitted from the plants were oxidized to form SOA via dark ozone-initiated chemistry. The SOA chemical composition was measured using a Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-AMS). The aerosol mass spectra of pre-treatment biogenic SOA from all plant types tended to be similar with correlations usually greater than or equal to 0.90. The presence of a stressor produced characteristic differences in the SOA mass spectra. Specifically, the following m/z were identified as a possible biogenic stress AMS marker with the corresponding HR ion(s) shown in parentheses: m/z 31 (CH3O+), m/z 58 (C2H2O2+, C3H6O+), m/z 29 (C2H5+), m/z 57 (C3H5O+), m/z 59 (C2H3O2+, C3H7O+), m/z 71 (C3H3O2+, C4H7O+), and m/z 83 (C5H7O+). The first aerosol mass spectrum of SOA generated from the oxidation of the plant stress hormone, MeJA, is also presented. Elemental analysis results demonstrated an O : C range of baseline biogenic SOA between 0.3 and 0.47. The O : C of standard MeJA SOA was 0.52. Results presented here could be used to help identify a biogenic plant stress marker in ambient data sets collected in forest environments.« less

  14. Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

    2011-09-28

    This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

  15. Evaluation of Models for Solubility and Volatility of Copper Compounds

    Office of Scientific and Technical Information (OSTI)

    Under Steam Generation Conditions (Conference) | SciTech Connect Evaluation of Models for Solubility and Volatility of Copper Compounds Under Steam Generation Conditions Citation Details In-Document Search Title: Evaluation of Models for Solubility and Volatility of Copper Compounds Under Steam Generation Conditions The loss in efficiency of power plants with mixed metallurgy, due to transport and deposition of copper and its oxides in HP turbines, has been recognized as one of the key

  16. Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon | Department of Energy Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-14_strzelec.pdf More Documents & Publications Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies Vehicle Technologies Office: 2010 Fuel

  17. LANL organic analysis detection capabilities for chemical and biological warfare agents

    SciTech Connect (OSTI)

    Ansell, G.B.; Cournoyer, M.E.; Hollis, K.W.; Monagle, M.

    1996-12-31

    Organic analysis is the analytical arm for several Los Alamos National Laboratory (LANL) research programs and nuclear materials processes, including characterization and certification of nuclear and nonnuclear materials used in weapons, radioactive waste treatment and waste certification programs. Organic Analysis has an extensive repertoire of analytical technique within the group including headspace gas, PCBs/pesticides, volatile organics and semivolatile organic analysis. In addition organic analysis has mobile labs with analytic capabilities that include volatile organics, total petroleum hydrocarbon, PCBs, pesticides, polyaromatic hydrocarbons and high explosive screening. A natural extension of these capabilities can be applied to the detection of chemical and biological agents,

  18. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, Terrence L. (Lenior City, TN); Wilson, James H. (Oak Ridge, TN)

    1993-01-01

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing.

  19. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, T.L.; Wilson, J.H.

    1993-09-21

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

  20. Fermilab | About | Organization | Fermilab Organization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Fermilab Organization Fermilab Org Chart Fermilab Org Chart Fermilab Org Chart Download pdf of Fermilab Organization Chart Download other organization charts:...

  1. Method of increasing biodegradation of sparingly soluble vapors

    DOE Patents [OSTI]

    Cherry, Robert S. (Idaho Falls, ID)

    2000-01-01

    A method for increasing biodegradation of sparingly soluble volatile organic compounds (VOCs) in a bioreactor is disclosed. The method comprises dissolving in the aqueous phase of the bioreactor a water soluble, nontoxic, non-biodegradable polymer having a molecular weight of at least 500 and operable for decreasing the distribution coefficient of the VOCs. Polyoxyalkylene alkanols are preferred polymers. A method of increasing the growth rate of VOC-degrading microorganisms in the bioreactor and a method of increasing the solubility of sparingly soluble VOCs in aqueous solution are also disclosed.

  2. New Air Cleaning Strategies for Reduced Commercial Building Ventilation Energy ? FY11 Final Report

    SciTech Connect (OSTI)

    Sidheswaran, Meera; Destaillats, Hugo; Cohn, Sebastian; Sullivan, Douglas P.; Fisk, William J.

    2011-10-31

    The research carried out in this project focuses on developing novel volatile organic compounds (VOCs) air cleaning technologies needed to enable energy-saving reductions in ventilation rates. we targeted a VOC air cleaning system that could enable a 50% reduction in ventilation rates. In a typical commercial HVAC system that provides a mixture of recirculated and outdoor air, a VOC air cleaner in the supply airstream must have a 15% to 20% VOC removal efficiency to counteract a 50% reduction in outdoor air supply.

  3. Volatility literature of chlorine, iodine, cesium, strontium, technetium, and rhenium; technetium and rhenium volatility testing

    SciTech Connect (OSTI)

    Langowski, M.H.; Darab, J.G.; Smith, P.A.

    1996-03-01

    A literature review pertaining to the volatilization of Sr, Cs, Tc (and its surrogate Re), Cl, I and other related species during the vitrification of Hanford Low Level Waste (LLW) streams has been performed and the relevant information summarized. For many of these species, the chemistry which occurs in solution prior to the waste stream entering the melter is important in dictating their loss at higher temperatures. In addition, the interactive effects between the species being lost was found to be important. A review of the chemistries of Tc and Re was also performed. It was suggested that Re would indeed act as an excellent surrogate for Tc in non-radioactive materials testing. Experimental results on Tc and Re loss from sodium aluminoborosilicate melts of temperatures ranging from 900--1350{degrees}C performed at PNL are reported and confirm that Re behaves in a nearly identical manner to that of technetium.

  4. Recovery of manganese oxides from spent alkaline and zinccarbon batteries. An application as catalysts for VOCs elimination

    SciTech Connect (OSTI)

    Gallegos, Mara V.; Falco, Lorena R.; Peluso, Miguel A.; Sambeth, Jorge E.; Thomas, Horacio J.

    2013-06-15

    Highlights: Manganese oxides were synthesized using spent batteries as raw materials. Spent alkaline and zinccarbon size AA batteries were used. A biohydrometallurgical process was employed to bio-lixiviate batteries. Manganese oxides were active in the oxidation of VOCs (ethanol and heptane). - Abstract: Manganese, in the form of oxide, was recovered from spent alkaline and zinccarbon batteries employing a biohydrometallurgy process, using a pilot plant consisting in: an air-lift bioreactor (containing an acid-reducing medium produced by an Acidithiobacillus thiooxidans bacteria immobilized on elemental sulfur); a leaching reactor (were battery powder is mixed with the acid-reducing medium) and a recovery reactor. Two different manganese oxides were recovered from the leachate liquor: one of them by electrolysis (EMO) and the other by a chemical precipitation with KMnO{sub 4} solution (CMO). The non-leached solid residue was also studied (RMO). The solids were compared with a MnO{sub x} synthesized in our laboratory. The characterization by XRD, FTIR and XPS reveal the presence of Mn{sub 2}O{sub 3} in the EMO and the CMO samples, together with some Mn{sup 4+} cations. In the solid not extracted by acidic leaching (RMO) the main phase detected was Mn{sub 3}O{sub 4}. The catalytic performance of the oxides was studied in the complete oxidation of ethanol and heptane. Complete conversion of ethanol occurs at 200 C, while heptane requires more than 400 C. The CMO has the highest oxide selectivity to CO{sub 2}. The results show that manganese oxides obtained using spent alkaline and zinccarbon batteries as raw materials, have an interesting performance as catalysts for elimination of VOCs.

  5. An advanced hybrid reprocessing system based on UF{sub 6} volatilization and chromatographic separation

    SciTech Connect (OSTI)

    Wei, Yuezhou; Liu, Ruiqin; Wu, Yan; Zu, Jianhua; Zhao, Long; Mimura, Hitoshi; Shi, Weiqun; Chai, Zhifang; Yang, Jinling; Ding, Youqian

    2013-07-01

    To recover U, Pu, MA (Np, Am, Cm) and some specific fission products FPs (Cs, Sr, Tc, etc.) from various spent nuclear fuels (LWR/FBR: Oxide, Metal Fuels), we are studying an advanced hybrid reprocessing system based on UF6 volatilization (Pyro) and chromatographic separation (Aqueous). Spent fuels are de-cladded by means of thermal and mechanical methods and then applied to the fluorination/volatilization process, which selectively recovers the most amount of U. Then, the remained fuel components are converted to oxides and dissolved by HNO{sub 3} solution. Compared to U, since Pu, MA and FPs are significantly less abundant in spent fuels, the scale of the aqueous separation process could become reasonably small and result in less waste. For the chromatographic separation processes, we have prepared different types of porous silica-based organic/inorganic adsorbents with fast diffusion kinetics, improved chemical stability and low pressure drop in a packed column. So they are advantageously applicable to efficient separation of the actinides and FP elements from the fuel dissolved solution. In this work, adsorption and separation behavior of representative actinides and FP elements was studied. Small scale separation tests using simulated and genuine fuel dissolved solutions were carried out to verify the feasibility of the proposed process. (authors)

  6. High-G testing of MEMS mechanical non-volatile memory and silicon...

    Office of Scientific and Technical Information (OSTI)

    High-G testing of MEMS mechanical non-volatile memory and silicon re-entry switch. Citation Details In-Document Search Title: High-G testing of MEMS mechanical non-volatile memory...

  7. Integrated system for the destruction of organics by hydrolysis and oxidation with peroxydisulfate

    DOE Patents [OSTI]

    Cooper, John F.; Balazs, G. Bryan; Hsu, Peter; Lewis, Patricia R.; Adamson, Martyn G.

    2000-01-01

    An integrated system for destruction of organic waste comprises a hydrolysis step at moderate temperature and pressure, followed by direct chemical oxidation using peroxydisulfate. This system can be used to quantitatively destroy volatile or water-insoluble halogenated organic solvents, contaminated soils and sludges, and the organic component of mixed waste. The hydrolysis step results in a substantially single phase of less volatile, more water soluble hydrolysis products, thus enabling the oxidation step to proceed rapidly and with minimal loss of organic substrate in the off-gas.

  8. Wintertime aerosol chemical composition, volatility, and spatial variability in the greater London area

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, L.; Williams, L. R.; Young, D. E.; Allan, J. D.; Coe, H.; Massoli, P.; Fortner, E.; Chhabra, P.; Herndon, S.; Brooks, W. A.; et al

    2015-08-28

    The composition of PM1 (particulate matter with diameter less than 1 ?m) in the greater London area was characterized during the Clean Air for London (ClearfLo) project in winter 2012. Two High-Resolution Time-of-Flight Aerosol Mass Spectrometers (HR-ToF-AMS) were deployed at a rural site (Detling, Kent) and an urban site (North Kensington, London). The simultaneous and high-temporal resolution measurements at the two sites provide a unique opportunity to investigate the spatial distribution of PM1. We find that the organic aerosol (OA) concentration is comparable between the rural and urban sites, but the sources of OA are distinctly different. The concentration ofmoresolid fuel OA at the urban site is about twice as high as at the rural site, due to elevated domestic heating in the urban area. While the concentrations of oxygenated OA (OOA) are well-correlated between the two sites, the OOA concentration at the rural site is almost twice that of the urban site. At the rural site, more than 70 % of the carbon in OOA is estimated to be non-fossil, which suggests that OOA is likely related to aged biomass burning considering the small amount of biogenic SOA in winter. Thus, it is possible that the biomass burning OA contributes a larger fraction of ambient OA in wintertime than what previous field studies have suggested. A suite of instruments was deployed downstream of a thermal denuder (TD) to investigate the volatility of PM1 species at the rural Detling site. After heating at 250 C in the TD, 40 % of the residual mass is OA, indicating the presence of non-volatile organics in the aerosol. Although the OA associated with refractory black carbon (rBC, measured by a soot-particle aerosol mass spectrometer) only accounts for less

  9. High Efficiency Organic Solar Cells: December 16, 2009 - February 2, 2011

    SciTech Connect (OSTI)

    Walker, K.; Joslin, S.

    2011-05-01

    Details on the development of novel organic solar cells incorporating Trimetasphere based acceptors are presented including: baseline performance for Lu-PCBEH acceptor blended with P3HT demonstrated at 4.89% PCE exceeding the 4.5% PCE goal; an increase of over 250mV in Voc was demonstrated for Lu-PCBEH blended with low band gap polymers compared to a comparable C60-PCBM device. The actual Voc was certified at 260mV higher for a low band gap polymer device using the Lu-PCBEH acceptor; and the majority of the effort was focused on development of a device with over 7% PCE. While low current and fill factors suppressed overall device performance for the low band gap polymers tested, significant discoveries were made that point the way for future development of these novel acceptor materials.

  10. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee R. Todd Anderson Program Manager, BER Climate and Environmental Sciences Anjuli Barnzai Program Manager, BER Climate and Environmental...

  11. Method for refreshing a non-volatile memory

    DOE Patents [OSTI]

    Riekels, James E.; Schlesinger, Samuel

    2008-11-04

    A non-volatile memory and a method of refreshing a memory are described. The method includes allowing an external system to control refreshing operations within the memory. The memory may generate a refresh request signal and transmit the refresh request signal to the external system. When the external system finds an available time to process the refresh request, the external system acknowledges the refresh request and transmits a refresh acknowledge signal to the memory. The memory may also comprise a page register for reading and rewriting a data state back to the memory. The page register may comprise latches in lieu of supplemental non-volatile storage elements, thereby conserving real estate within the memory.

  12. Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection | Department of Energy Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be used in diesel engines having efficient fuel systems and combustion chamber designs that decrease fuel consumption and mitigate emissions. PDF icon p-02_anitescu.pdf More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of Biodiesel

  13. Highly efficient inverted organic solar cells using amino acid modified indium tin oxide as cathode

    SciTech Connect (OSTI)

    Li, Aiyuan; Nie, Riming; Deng, Xianyu; Wei, Huaixin; Li, Yanqing; Tang, Jianxin; Zheng, Shizhao; Wong, King-Young

    2014-03-24

    In this paper, we report that highly efficient inverted organic solar cells were achieved by modifying the surface of indium tin oxide (ITO) using an amino acid, Serine (Ser). With the modification of the ITO surface, device efficiency was significantly enhanced from 0.63% to 4.17%, accompanied with an open circuit voltage (Voc) that was enhanced from 0.30?V to 0.55?V. Ultraviolet and X-ray photoelectron spectroscopy studies indicate that the work function reduction induced by the amino acid modification resulting in the decreased barrier height at the ITO/organic interface played a crucial role in the enhanced performances.

  14. Air stripping of volatile organic chlorocarbons: System development, performance, and lessons learned

    SciTech Connect (OSTI)

    McKillip, S.T.; Sibley, K.L.; Horvath, J.G.

    1991-12-31

    The Savannah River Site, which has been in operation since the 1950`s, is a 780-square kilometer reservation that produces tritium for the national defense program. As a result of past waste handling practices, the ground water at several locations on the Site has become contaminated with solvents, metals, and radionuclides. In 1981, the ground water located under the Site`s fuel and target rod fabrication area (M-Area) was found to be contaminated with degreasing solvents, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE). In 1983, a program was started to evaluate air stripping and determine its applicability to cleanup of M-Area contamination. Lessons learned regarding the efficiency and effectiveness of air stripping technology are presented.

  15. Air stripping of volatile organic chlorocarbons: System development, performance, and lessons learned

    SciTech Connect (OSTI)

    McKillip, S.T.; Sibley, K.L.; Horvath, J.G.

    1991-01-01

    The Savannah River Site, which has been in operation since the 1950's, is a 780-square kilometer reservation that produces tritium for the national defense program. As a result of past waste handling practices, the ground water at several locations on the Site has become contaminated with solvents, metals, and radionuclides. In 1981, the ground water located under the Site's fuel and target rod fabrication area (M-Area) was found to be contaminated with degreasing solvents, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE). In 1983, a program was started to evaluate air stripping and determine its applicability to cleanup of M-Area contamination. Lessons learned regarding the efficiency and effectiveness of air stripping technology are presented.

  16. In-situ remediation system for volatile organic compounds with deep recharge mechanism

    DOE Patents [OSTI]

    Jackson, Jr., Dennis G. (Augusta, GA); Looney, Brian B. (Aiken, SC); Nichols, Ralph L. (Augusta, SC); Phifer, Mark A. (Augusta, SC)

    2001-01-01

    A method and apparatus for the treatment and remediation of a contaminated aquifer in the presence of an uncontaminated aquifer at a different hydraulic potential. The apparatus consists of a wellbore inserted through a first aquifer and into a second aquifer, an inner cylinder within the wellbore is supported and sealed to the wellbore to prevent communication between the two aquifers. Air injection is used to sparge the liquid having the higher static water level and, to airlift it to a height whereby it spills into the inner cylinder. The second treatment area provides treatment in the form of aeration or treatment with a material. Vapor stripped in sparging is vented to the atmosphere. Treated water is returned to the aquifer having the lower hydraulic potential.

  17. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization Organization Download Printable PDF PDF icon Organization Chart - Dated: 07/12/2015

  18. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    About Us » Organization Organization Organization Printable PDF News & Blog CIO Leadership Organization Contact Us

  19. Position Paper on Practicable Performance Criteria for the Removal Efficiency of Volatile Radionuclides

    SciTech Connect (OSTI)

    R. T. Jubin; N. Soelberg; D. M. Strachan

    2012-03-01

    As a result of fuel reprocessing, volatile radionuclides may be released from the facility stack if no processes are put in place to remove them. The radionuclides that are of concern in this document are 3H, 14C, 85Kr, and 129I. The question we attempted to answer is how efficient must this removal process be for each of these radionuclides? To answer this question, we examined the three regulations that may impact the degree to which these radionuclides must be reduced before process gases can be released from the facility. These regulations are 40 CFR 61 (EPA 2010a), 40 CFR 190(EPA 2010b), and 10 CFR 20 (NRC 2012). These regulations apply to the total radionuclide release and to a particular organ - the thyroid. Because these doses can be divided amongst all the radionuclides in different ways and even within the four radionuclides in question, we provided several cases. We first looked at the inventories for these radionuclides for three fuel types (PWR UOX, PWR MOX, and AHTGR), several burn-up values, and time out of reactor extending to 200 y. We calculated doses to the maximum exposed individual (MEI) with the EPA code CAP-88 (Rosnick 1992). Finally, we looked at two dose cases. Allocating all of the allowable dose to be used by the volatile radionuclides is one case, but, perhaps, unrealistic. In lieu of this, we arbitrarily selected a value of 10% of the allowable dose to be assigned to the volatile radionuclides. We calculated the required decontamination factors (DFs) for both of these cases, including the case for the thyroid dose for which 14C and 129I were the main contributors. With respect to 129I doses, we found that the highest dose was calculated with iodine as a fine particulate. The dose scaled as the fraction of the total 129I that was particulate. Therefore, we assumed for all of our calculations that 100% of the 129I was particulate and allow the user of the results given here to scale our calculated doses to their needs.

  20. Biological Air Emissions Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Air Emissions Control Biological Air Emissions Control Innovative Technology Enables Low-Cost, Energy-Efficient Treatment of Industrial Exhaust Streams Air quality standards are becoming more stringent for the U.S. wood products industry. Emissions of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) (including methanol, formaldehyde, acetylaldehyde, and acrolein) during production of wood products must be tightly controlled. Conventional VOCs and HAPs emission

  1. Reactive Flash Volatilization of Solid, Nonvolatile Fuel - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Reactive Flash Volatilization of Solid, Nonvolatile Fuel DOE Grant Recipients University of Minnesota Contact University of Minnesota About This Technology <span id="Caption"><span id="ctl00_MainContentHolder_zoomimage_defaultCaption">Syngas or Synthesis Gas</span></span> Syngas or Synthesis Gas <span id="Caption"><span

  2. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, M.P.; Overmyer, D.L.; Dominguez, F.

    1998-12-22

    A system is disclosed for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source. 3 figs.

  3. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, Michael P. (Albuquerque, NM); Overmyer, Donald L. (Albuquerque, NM); Dominguez, Frank (Albuquerque, NM)

    1998-01-01

    A system for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source.

  4. Method for removing organic liquids from aqueous solutions and mixtures

    DOE Patents [OSTI]

    Hrubesh, Lawrence W.; Coronado, Paul R.; Dow, Jerome P.

    2004-03-23

    A method for removing organic liquids from aqueous solutions and mixtures. The method employs any porous material preferably in granular form and having small pores and a large specific surface area, that is hydrophobic so that liquid water does not readily wet its surface. In this method, organics, especially organic solvents that mix with and are more volatile than water, are separated from aqueous solution by preferentially evaporating across the liquid/solid boundary formed at the surfaces of the hydrophobic porous materials. Also, organic solvents that are immiscible with water, preferentially wet the surfaces of the hydrophobic material and are drawn within the porous materials by capillary action.

  5. Final Technical Report: A Paradigm Shift in Chemical Processing: New Sustainable Chemistries for Low-VOC Coatings

    SciTech Connect (OSTI)

    Smith, Kenneth F.

    2006-07-26

    The project employed new processes to make emulsion polymers from reduced levels of petroleum-derived chemical feedstocks. Most waterborne paints contain spherical, emulsion polymer particles that serve as the film-forming binder phase. Our goal was to make emulsion polymer particles containing 30 percent feedstock that would function as effectively as commercial emulsions made from higher level feedstock. The processes developed yielded particles maintained their film formation capability and binding capacity while preserving the structural integrity of the particles after film formation. Rohm and Haas Company (ROH) and Archer Daniels Midland Company (ADM) worked together to employ novel polymer binders (ROH) and new, non-volatile, biomass-derived coalescing agents (ADM). The University of Minnesota Department of Chemical Engineering and Material Science utilized its unique microscopy capabilities to characterize films made from the New Emulsion Polymers (NEP).

  6. Mr. John Kieling, Acting Chief Hazardous Waste Bureau

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P O. Box 3090 Carlsbad, New Mexico 88221 JUl 2 0 2011 New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 Santa Fe, NM 87505-6303 Subject: Notification of Exceedance of a Disposal Room Volatile Organic Compound Monitoring Action Level for Carbon Tetrachloride Dear Mr. Kieling: The purpose of this letter is to notify you of the receipt of validated analytical results for a volatile organic compound (VOC), carbon tetrachloride, which exceeded the 50 percent action level listed

  7. Cyclic membrane separation process

    DOE Patents [OSTI]

    Nemser, Stuart M.

    2005-05-03

    A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In the first part of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the second part, the membrane is inoperative while gas pressure rises in the ullage. In one aspect of this invention, a vacuum is drawn in the membrane separation unit thus reducing overall VOC emissions.

  8. Buildings Energy Data Book: 1.4 Environmental Data

    Buildings Energy Data Book [EERE]

    0 2010 Emissions Summary Table for U.S. Buildings Energy Consumption (Thousand Short Tons) (1) Buildings Buildings Percent Wood/SiteFossil Electricity Total U.S. Total of U.S. Total SO2 (2) 54% NOx 17% CO 5% VOCs 2% PM-2.5 15% PM-10 7% Note(s): Source(s): 1) VOCs = volatile organic compounds; PM-10 = particulate matter less than 10 micrometers in aerodynamic diameter. PM-2.5 = particulate matter less than 2.5 micrometers in aerodynamic diameter. CO and VOCs site fossil emissions mostly from wood

  9. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Nuclear Physics May 26-27, 2011 Ted Barnes DOE Office of Nuclear Physics Yukiko Sekine NERSC Program Manager, DOE Office of Advanced Computational Research Kathy Yelick NERSC Director Richard Gerber NERSC User Services Harvey Wasserman NERSC User Services Last edited: 2016-02-01 08:07:45

  10. An Innovative Reactor Technology to Improve Indoor Air Quality

    SciTech Connect (OSTI)

    Rempel, Jane

    2013-03-30

    As residential buildings achieve tighter envelopes in order to minimize energy used for space heating and cooling, accumulation of indoor air pollutants such as volatile organic compounds (VOCs), becomes a major concern causing poor air quality and increased health risks. Current VOC removal methods include sorbents, ultraviolet photocatalytic oxidation (UVPCO), and increased ventilation, but these methods do not capture or destroy all VOCs or are prohibitively expensive to implement. TIAX's objective in this program was to develop a new VOC removal technology for residential buildings. This novel air purification technology is based on an innovative reactor and light source design along with UVPCO properties of the chosen catalyst to purify indoor air and enhance indoor air quality (IAQ). During the program we designed, fabricated and tested a prototype air purifier to demonstrate its feasibility and effectiveness. We also measured kinetics of VOC destruction on photocatalysts, providing deep insight into reactor design.

  11. Fermilab | About | Organization | Fermilab Organization | Explanation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Symbols Line Organization: sectors, divisions, sections Line Organization Matrix Organization: centers, projects and programs utilizing resources spanning the entire...

  12. In-Situ Containment and Extraction of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  13. In-Situ Contained And Of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  14. System for loading executable code into volatile memory in a downhole tool

    DOE Patents [OSTI]

    Hall, David R.; Bartholomew, David B.; Johnson, Monte L.

    2007-09-25

    A system for loading an executable code into volatile memory in a downhole tool string component comprises a surface control unit comprising executable code. An integrated downhole network comprises data transmission elements in communication with the surface control unit and the volatile memory. The executable code, stored in the surface control unit, is not permanently stored in the downhole tool string component. In a preferred embodiment of the present invention, the downhole tool string component comprises boot memory. In another embodiment, the executable code is an operating system executable code. Preferably, the volatile memory comprises random access memory (RAM). A method for loading executable code to volatile memory in a downhole tool string component comprises sending the code from the surface control unit to a processor in the downhole tool string component over the network. A central processing unit writes the executable code in the volatile memory.

  15. A Big Data Approach to Analyzing Market Volatility

    SciTech Connect (OSTI)

    Wu, Kesheng; Bethel, E. Wes; Gu, Ming; Leinweber, David; Ruebel, Oliver

    2013-06-05

    Understanding the microstructure of the financial market requires the processing of a vast amount of data related to individual trades, and sometimes even multiple levels of quotes. Analyzing such a large volume of data requires tremendous computing power that is not easily available to financial academics and regulators. Fortunately, public funded High Performance Computing (HPC) power is widely available at the National Laboratories in the US. In this paper we demonstrate that the HPC resource and the techniques for data-intensive sciences can be used to greatly accelerate the computation of an early warning indicator called Volume-synchronized Probability of Informed trading (VPIN). The test data used in this study contains five and a half year?s worth of trading data for about 100 most liquid futures contracts, includes about 3 billion trades, and takes 140GB as text files. By using (1) a more efficient file format for storing the trading records, (2) more effective data structures and algorithms, and (3) parallelizing the computations, we are able to explore 16,000 different ways of computing VPIN in less than 20 hours on a 32-core IBM DataPlex machine. Our test demonstrates that a modest computer is sufficient to monitor a vast number of trading activities in real-time ? an ability that could be valuable to regulators. Our test results also confirm that VPIN is a strong predictor of liquidity-induced volatility. With appropriate parameter choices, the false positive rates are about 7percent averaged over all the futures contracts in the test data set. More specifically, when VPIN values rise above a threshold (CDF > 0.99), the volatility in the subsequent time windows is higher than the average in 93percent of the cases.

  16. Summary Report on the Volatile Radionuclide and Immobilization Research for FY2011 at PNNL

    SciTech Connect (OSTI)

    Strachan, Denis M.; Chun, Jaehun; Matyas, Josef; Lepry, William C.; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

    2011-09-01

    The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2011, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogen-based aerogels (i.e., chalcogels). A silica aerogel was tested at ORNL for total I2 sorption capacity. It was determined to have 48 mass% capacity while having little physisorbed I2 (I2 not taken up in the aerogel pores). For 85Kr, metal organic framework (MOF) structures were investigated and a new MOF with about 8 mass% capacity for Xe and Kr. The selectivity can be changed from Xe > Kr to Xe < Kr simply by lowering the temperature below 0 C. A patent disclosure has been filed. Lastly, silicon carbide (SiC) was loaded with Kr. The diffusion of Kr in SiC was found to be less than detectable at 500 C.

  17. Organic Superconductors

    SciTech Connect (OSTI)

    Charles Mielke

    2009-02-27

    Intense magnetic fields are an essential tool for understanding layered superconductors. Fundamental electronic properties of organic superconductors are revealed in intense (60 tesla) magnetic fields. Properties such as the topology of the Fermi surface and the nature of the superconducting order parameter are revealed. With modest maximum critical temperatures~13K the charge transfer salt organic superconductors prove to be incredibly valuable materials as their electronically clean nature and layered (highly anisotropic) structures yield insights to the high temperature superconductors. Observation of de Haas-van Alphen and Shubnikov-de Haas quantum oscillatory phenomena, magnetic field induced superconductivity and re-entrant superconductivity are some of the physical phenomena observed in the charge transfer organic superconductors. In this talk, I will discuss the nature of organic superconductors and give an overview of the generation of intense magnetic fields; from the 60 tesla millisecond duration to the extreme 1000 tesla microsecond pulsed magnetic fields.

  18. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Advanced Scientific Computing Research An ASCR / NERSC Workshop January 5-6, 2011 Dr. Karen Pao ASCR Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services John Shalf NERSC Advanced Technologies Group Harvey Wasserman NERSC User Services Last edited: 2016-02-01 08:07:45

  19. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee R. Todd Anderson Program Manager, BER Climate and Environmental Sciences Anjuli Barnzai Program Manager, BER Climate and Environmental Sciences Susan Gregurick Program Manager, BER Biological Systems Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services Harvey Wasserman NERSC System Architecture Last edited: 2016-02-01 08:07:43

  20. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Fusion Energy Science August 3-4, 2010 Dr. John Mandrekas Advanced Fusion Simulations; FES HPC Allocations Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services Alice Koniges NERSC Advanced Technologies Harvey Wasserman NERSC User Services Last edited: 2016-02-01 08:07:45

  1. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for High Energy Physics November 12-13, 2009 Amber Boehnlein Division Scientist, Fermi National Accelerator Laboratory, on assignment to DOE Office of HEP. Glen Crawford Program Manager, Research and Technology Division, DOE Office of HEP. Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services Harvey

  2. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Basic Energy Sciences An ASCR / BES / NERSC Workshop February 9-10, 2010 Jim Davenport Program Manager for Theoretical Condensed Material Physics Mark R. Pederson Program Manager for Theoretical and Computational Chemistry Nicholas B. Woodward Program Manager, Geosciences Research Program Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for

  3. Organization Chart | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Chart Organization Chart Organization Chart Printable PDF Mission Leadership

  4. Reduce air, reduce compliance cost new patented spray booth technology

    SciTech Connect (OSTI)

    McGinnis, F.

    1997-12-31

    A New Paint Spray Booth System that dramatically reduces air volumes normally required for capturing and controlling paint overspray that contains either Volatile Organic Compounds (VOC) or Hazardous Air Pollutants (HAP), or both. In turn, a substantial reduction in capital equipment expenditures for air abatement systems and air make-up heaters as well as related annual operating expenses is realized.

  5. CX-011446: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Measurements and Modeling to Quantify Emissions of Methane and Volatile Organic Compounds (VOCs) from Shale Gas Operations CX(s) Applied: B3.1 Date: 11/13/2013 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory

  6. Estimation of stochastic volatility with long memory for index prices of FTSE Bursa Malaysia KLCI

    SciTech Connect (OSTI)

    Chen, Kho Chia; Kane, Ibrahim Lawal; Rahman, Haliza Abd; Bahar, Arifah; Ting, Chee-Ming

    2015-02-03

    In recent years, modeling in long memory properties or fractionally integrated processes in stochastic volatility has been applied in the financial time series. A time series with structural breaks can generate a strong persistence in the autocorrelation function, which is an observed behaviour of a long memory process. This paper considers the structural break of data in order to determine true long memory time series data. Unlike usual short memory models for log volatility, the fractional Ornstein-Uhlenbeck process is neither a Markovian process nor can it be easily transformed into a Markovian process. This makes the likelihood evaluation and parameter estimation for the long memory stochastic volatility (LMSV) model challenging tasks. The drift and volatility parameters of the fractional Ornstein-Unlenbeck model are estimated separately using the least square estimator (lse) and quadratic generalized variations (qgv) method respectively. Finally, the empirical distribution of unobserved volatility is estimated using the particle filtering with sequential important sampling-resampling (SIR) method. The mean square error (MSE) between the estimated and empirical volatility indicates that the performance of the model towards the index prices of FTSE Bursa Malaysia KLCI is fairly well.

  7. Combustion of volatile matter during the initial stages of coal combustion

    SciTech Connect (OSTI)

    Marlow, D.; Niksa, S.; Kruger, C.H.

    1990-08-01

    Both the secondary pyrolysis and combustion of the volatiles from a bituminous coal will be studied. Devolatilization and secondary pyrolysis experiments will be conducted in a novel flow reactor in which secondary pyrolysis of the volatiles occurs after devolatilization is complete. This allows unambiguous measurements of the yields from both processes. Measurements will be made for reactor temperatures from 1500 to 1700 K, and a nominal residence time of 200 msec. These conditions are typical of coal combustion. Yields of tar, soot, H{sub 2}, CO, CH{sub 4}, and C{sub 2} and C{sub 3} hydrocarbons will be determined as a function of reactor temperature. The yields will be reported as a function of the temperature of the reactor. The instrumentation for temperature measurements will be developed during future studies. Combustion studies will be conducted in a constant volume bomb, which will be designed and constructed for this study. Tar and soot will be removed before introducing the volatiles to the bomb, so that only the combustion of the light gas volatiles will be considered. The burning velocities of light gas volatiles will be determined both as functions of mixture stoichiometry and the temperature at which the volatiles are pyrolysed. 90 refs., 70 figs., 13 tabs.

  8. A Literature Survey to Identify Potentially Volatile Iodine-Bearing Species Present in Off-Gas Streams

    SciTech Connect (OSTI)

    Bruffey, S. H.; Spencer, B. B.; Strachan, D. M.; Jubin, R. T.; Soelberg, N. R.; Riley, B. J.

    2015-06-30

    Four radionuclides have been identified as being sufficiently volatile in the reprocessing of nuclear fuel that their gaseous release needs to be controlled to meet regulatory requirements (Jubin et al. 2011, 2012). These radionuclides are 3H, 14C, 85Kr, and 129I. Of these, 129I has the longest half-life and potentially high biological impact. Accordingly, control of the release of 129I is most critical with respect to the regulations for the release of radioactive material in stack emissions. It is estimated that current EPA regulations (EPA 2010) would require any reprocessing plant in the United States to limit 129I release to less than 0.05 Ci/MTIHM for a typical fuel burnup of 55 gigawatt days per metric tonne (GWd/t) (Jubin 2011). The study of inorganic iodide in off-gas systems has been almost exclusively limited to I2 and the focus of organic iodide studies has been CH3I. In this document, we provide the results of an examination of publically available literature that is relevant to the presence and sources of both inorganic and organic iodine-bearing species in reprocessing plants. We especially focus on those that have the potential to be poorly sequestered with traditional capture methodologies. Based on the results of the literature survey and some limited thermodynamic modeling, the inorganic iodine species hypoiodous acid (HOI) and iodine monochloride (ICl) were identified as potentially low-sorbing iodine species that could present in off-gas systems. Organic species of interest included both short chain alkyl iodides such as methyl iodide (CH3I) and longer alkyl iodides up to iodododecane (C10H21I). It was found that fuel dissolution may provide conditions conducive to HOI formation and has been shown to result in volatile long-chain alkyl iodides, though these may not volatilize until later in the reprocessing sequence. Solvent extraction processes were found to be significant sources of various organic iodine-bearing species; formation of these was facilitated by the presence of radiolytic decomposition products resulting from radiolysis of tri-n-butyl phosphate and dodecane. Primarily inorganic iodine compounds were expected from waste management processes, including chlorinated species such as ICl. Critical knowledge gaps that must still be addressed include confirmation of the existence and quantification of low-sorbing species in the off-gas of reprocessing facilities. The contributions from penetrating forms of iodine to the plant DF are largely unknown and highly dependent on the magnitude of their presence. These species are likely to be more difficult to remove and it is likely that their sequestration could be improved through the use of different sorbents, through design modifications of the off-gas capture system, or through chemical conversion prior to iodine abatement that would produce more easily captured forms.

  9. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, Joseph P.; Marek, James C.

    1989-01-01

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper (II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the orginal organic compounds, is subsequently blended with high level radioactive sludge and transferred to a virtrification facility for processing into borosilicate glass for long-term storage.

  10. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, J.P.; Marek, J.C.

    1987-02-25

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper(II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the original organic compounds, is subsequently blended with high level radioactive sludge land transferred to a vitrification facility for processing into borosilicate glass for long-term storage. 2 figs., 3 tabs.

  11. Organization Chart - Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LSD Logo About Us People & Organization Research News & Events Safety Internal Resources Organization Chart Departments Scientific Staff Directory Committees Organization Chart...

  12. High-G testing of MEMS mechanical non-volatile memory and silicon re-entry

    Office of Scientific and Technical Information (OSTI)

    switch. (Technical Report) | SciTech Connect Technical Report: High-G testing of MEMS mechanical non-volatile memory and silicon re-entry switch. Citation Details In-Document Search Title: High-G testing of MEMS mechanical non-volatile memory and silicon re-entry switch. Two different Sandia MEMS devices have been tested in a high-g environment to determine their performance and survivability. The first test was performed using a drop-table to produce a peak acceleration load of 1792 g's

  13. Volatiles combustion in fluidized beds. [Quarterly] technical progress report, 4 December 1994--4 March 1995

    SciTech Connect (OSTI)

    Pendergrass II, R.A.; Mansker, L.D.; Hesketh, R.P.

    1995-08-01

    The goal of this project is to investigate the conditions in which volatiles will bum within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 December, 1994 through, 3 March 1995 is presented in this technical progress report. The research consists of the application of a detailed chemical kinetics model for propane combustion and planned improvements in the experimental system.

  14. Volatiles combustion in fluidized beds. Technical progress report, 4 March 1993--3 June 1993

    SciTech Connect (OSTI)

    Hesketh, R.P.

    1993-09-01

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization will be performed to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 March, 1993 through 3 June, 1993 is reported in this technical progress report. The work during this time period consists primarily of the startup and trouble shooting of the fluidized bed reactor and gas phase modeling of methane and propane.

  15. Method For Removing Volatile Components From A Gel-Cast Ceramic Article

    DOE Patents [OSTI]

    Klug, Frederic Joseph (Schenectady, NY); DeCarr, Sylvia Marie (Schenectady, NY)

    2004-09-07

    A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

  16. Method for removing volatile components from a ceramic article, and related processes

    DOE Patents [OSTI]

    Klug, Frederic Joseph (Schenectady, NY); DeCarr, Sylvia Marie (Waterford, NY)

    2002-01-01

    A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

  17. Henry's law constants for paint solvents and their implications on volatile organic compound emissions from automotive painting

    SciTech Connect (OSTI)

    Kim, B.R.; Kalis, E.M.; DeWulf, T.; Andrews, K.M.

    2000-02-01

    This paper describes experimental results of equilibrium partitioning of several significant paint solvents and formaldehyde between air and water to quantify the potential for capturing and retaining the constituents in spraybooth scrubber water during automotive painting. The compounds studied are toluene, n-butanol, methyl ethyl ketone methyl propyl ketone, methyl isobutyl ketone, methyl amyl ketone, butyl cellosolve, butyl cellosolve acetate, butyl carbitol, and n-methyl-2-pyrrolidinone. A set of field data collected at a Ford Motor Company assembly plant was also analyzed to determine whether data were consistent with the equilibrium phenomenon. The primary findings include: (a) There were more than six orders of magnitude difference in the Henry's law constants among the solvents studied. A solvent with a smaller constant is less easily stripped from water. The Henry's law constants decrease in the following order: toluene and xylenes > methyl ethyl ketone > n-butanol > butyl cellosolve acetate > butyl cellosolve > formaldehyde > butyl carbitol > n-methyl-2-pyrrolidinone. (b) Field data showed accumulation of n-methyl-2-pyrrolidinone and stable concentrations of butyl carbitol, butyl cellosolve, and n-butanol in the paint-sludge pit water during a 2-month period. Stable concentrations indicate a continuous, balanced capture and stripping of the solvents. Data were consistent with measured Henry's law constants. (c) The low Henry's law constant for formaldehyde is the result of the fact that it is hydrated when dissolved in water.

  18. Final Report - Glass Formulation Testing to Increase Sulfate Volatilization from Melter, VSL-04R4970-1, Rev. 0, dated 2/24/05

    SciTech Connect (OSTI)

    Kruger, Albert A.; Matlack, K. A.; Pegg, I. L.; Gong, W.

    2013-11-13

    The principal objectives of the DM100 and DM10 tests were to determine the impact of four different organics and one inorganic feed additive on sulfate volatilization and to determine the sulfur partitioning between the glass and the off-gas system. The tests provided information on melter processing characteristics and off-gas data including sulfur incorporation and partitioning. A series of DM10 and DM100 melter tests were conducted using a LAW Envelope A feed. The testing was divided into three parts. The first part involved a series of DM10 melter tests with four different organic feed additives: sugar, polyethylene glycol (PEG), starch, and urea. The second part involved two confirmatory 50-hour melter tests on the DM100 using the best combination of reductants and conditions based on the DM10 results. The third part was performed on the DM100 with feeds containing vanadium oxide (V{sub 2}O{sub 5}) as an inorganic additive to increase sulfur partitioning to the off-gas. Although vanadium oxide is not a reductant, previous testing has shown that vanadium shows promise for partitioning sulfur to the melter exhaust, presumably through its known catalytic effect on the SO{sub 2}/SO{sub 3} reaction. Crucible-scale tests were conducted prior to the melter tests to confirm that the glasses and feeds would be processable in the melter and that the glasses would meet the waste form (ILAW) performance requirements. Thus, the major objectives of these tests were to: ? Perform screening tests on the DM10 followed by tests on the DM100-WV system using a LAW -Envelope A feed with four organic additives to assess their impact on sulfur volatilization. ? Perform tests on the DM100-WV system using a LAW -Envelope A feed containing vanadium oxide to assess its impact on sulfur volatilization. ? Determine feed processability and product quality with the above additives. ? Collect melter emissions data to determine the effect of additives on sulfur partitioning and melter emissions. ? Collect and analyze discharged glass to determine sulfur retention in the glass. ? Prepare and characterize feeds and glasses with the additives to confirm that the feeds and the glass melts are suitable for processing in the DM100 melter. ? Prepare and characterize glasses with the additives to confirm that the glasses meet the waste form (ILAW) performance requirements.

  19. Kinetics of coal combustion: Part 2, Mechanisms and kinetics of coal volatiles combustion

    SciTech Connect (OSTI)

    Essenhigh, R.H.; Bailey, E.G.; Shaw, D.W. )

    1988-12-01

    Values of global kinetic constants for the combustion of coal volatiles have been determined for the first time for volatiles from three coals (two bituminous coals and a Texas lignite). Global kinetic constants for methane and propane were also measured in the same apparatus to allow comparison with reference gases. Comparisons have also been made with values of global kinetics for pure hydrocarbons from a range of experiments as found in the literature. The volatiles were pyrolyzed from crushed coal drawn on weighed trays through a gas-fired muffle furnace, and they were burned at the top of a tube in an intense back-mix volume treated theoretically as a stirred reactor. Two types of experiment were carried out: partial combustion measurements near the stoichiometric for all coals from which the global kinetics were determined; and extinction limits for the Pittsburgh {number sign}8 coal volatiles to determine the extinction loop. The near stoichiometric generated kinetic data were used to predict the extinction limits with substantial agreement. Extinction loops for methane, propane and carbon monoxide were also measured for comparison.

  20. Experimental studies of actinide volatilities with application to mixed waste oxidation processors

    SciTech Connect (OSTI)

    Krikorian, O.H.; Ebbinghaus, B.B.; Condit, R.H.; Adamson, M.G.; Fontes, A.S. Jr.; Fleming, D.L.

    1993-04-30

    The transpiration technique is used to measure volatilities of U from U{sub 3}O{sub 8}(s), Pu from PuO{sub 2}(s) and Pu and Am from PuO{sub 2}/2%AmO{sub 2}(s) in the presence of steam and oxygen at temperatures ranging from 900 to 1300{degree}C.

  1. Motor vehicle fuel economy, the forgotten HC control stragegy?

    SciTech Connect (OSTI)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  2. Motor vehicle fuel economy, the forgotten HC control stragegy. [Hydrocarbon (HC)

    SciTech Connect (OSTI)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  3. Investigation into the effect of high concentrations of volatile fatty acids in anaerobic digestion on methanogenic communities

    SciTech Connect (OSTI)

    Franke-Whittle, Ingrid H.; Walter, Andreas; Ebner, Christian; Insam, Heribert

    2014-11-15

    Highlights: • Different methanogenic communities in mesophilic and thermophilic reactors. • High VFA levels do not cause major changes in archaeal communities. • Real-time PCR indicated greater diversity than ANAEROCHIP microarray. - Abstract: A study was conducted to determine whether differences in the levels of volatile fatty acids (VFAs) in anaerobic digester plants could result in variations in the indigenous methanogenic communities. Two digesters (one operated under mesophilic conditions, the other under thermophilic conditions) were monitored, and sampled at points where VFA levels were high, as well as when VFA levels were low. Physical and chemical parameters were measured, and the methanogenic diversity was screened using the phylogenetic microarray ANAEROCHIP. In addition, real-time PCR was used to quantify the presence of the different methanogenic genera in the sludge samples. Array results indicated that the archaeal communities in the different reactors were stable, and that changes in the VFA levels of the anaerobic digesters did not greatly alter the dominating methanogenic organisms. In contrast, the two digesters were found to harbour different dominating methanogenic communities, which appeared to remain stable over time. Real-time PCR results were inline with those of microarray analysis indicating only minimal changes in methanogen numbers during periods of high VFAs, however, revealed a greater diversity in methanogens than found with the array.

  4. Fiber optic spectrochemical emission sensor: Detection of volatile chlorinated compounds in air and water using ultra-thin membranes

    SciTech Connect (OSTI)

    Anheier, N.C. Jr.; Olsen, K.B.; Osantowski, R.E.; Evans, J.C. Jr.; Griffin, J.W.

    1993-05-01

    Prior work on the fiber optic spectrochemical emission sensor called HaloSnif{trademark} has been extended to include an ultra-thin membrane which allows passage of volatile organic chlorinated compounds (VOCl). The membrane has been demonstrated to exclude H{sub 2}O during VOCl monitoring. The system is capable of measuring VOCl in gas-phase samples or aqueous solutions over a wide linear dynamic range. The lower limit of detection for trichloroethylene (TCE), perchloroethylene (PCE), carbon tetrachloride (CCl{sub 4}), and other related compounds in the gas-phase is 1 to 5 ppm{sub v/v}, and in the aqueous-phase is 5 to 10 mg/L. Waste site characterization and remediation activities often require chemical analysis in the vadose zone and in groundwater. These analyses are typically performed in analytical laboratories using widely accepted standardized methods such as gas chromatography, gas chromatography/mass spectrometry. The new developments with HaloSnif provide rapid field screening which can augment the standardized methods.

  5. Application of high-resolution time-of-flight chemical ionization mass spectrometry measurements to estimate volatility distributions of α-pinene and naphthalene oxidation products

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chhabra, P. S.; Lambe, A. T.; Canagaratna, M. R.; Stark, H.; Jayne, J. T.; Onasch, T. B.; Davidovits, P.; Kimmel, J. R.; Worsnop, D. R.

    2015-01-05

    Recent developments in high-resolution time-of-flight chemical ionization mass spectrometry (HR-ToF-CIMS) have made it possible to directly detect atmospheric organic compounds in real time with high sensitivity and with little or no fragmentation, including low-volatility, highly oxygenated organic vapors that are precursors to secondary organic aerosol formation. Here, using ions identified by high-resolution spectra from an HR-ToF-CIMS with acetate reagent ion chemistry, we develop an algorithm to estimate the vapor pressures of measured organic acids. The algorithm uses identified ion formulas and calculated double bond equivalencies, information unavailable in quadrupole CIMS technology, as constraints for the number of possible oxygen-containing functionalmore » groups. The algorithm is tested with acetate chemical ionization mass spectrometry (acetate-CIMS) spectra of O3 and OH oxidation products of α-pinene and naphthalene formed in a flow reactor with integrated OH exposures ranged from 1.2 × 1011 to 9.7 × 1011 molec s cm−3, corresponding to approximately 1.0 to 7.5 days of equivalent atmospheric oxidation. Measured gas-phase organic acids are similar to those previously observed in environmental chamber studies. For both precursors, we find that acetate-CIMS spectra capture both functionalization (oxygen addition) and fragmentation (carbon loss) as a function of OH exposure. The level of fragmentation is observed to increase with increased oxidation. The predicted condensed-phase secondary organic aerosol (SOA) average acid yields and O/C and H/C ratios agree within uncertainties with previous chamber and flow reactor measurements and ambient CIMS results. While acetate reagent ion chemistry is used to selectively measure organic acids, in principle this method can be applied to additional reagent ion chemistries depending on the application.« less

  6. Ordered organic-organic multilayer growth

    DOE Patents [OSTI]

    Forrest, Stephen R; Lunt, Richard R

    2015-01-13

    An ordered multilayer crystalline organic thin film structure is formed by depositing at least two layers of thin film crystalline organic materials successively wherein the at least two thin film layers are selected to have their surface energies within .+-.50% of each other, and preferably within .+-.15% of each other, whereby every thin film layer within the multilayer crystalline organic thin film structure exhibit a quasi-epitaxial relationship with the adjacent crystalline organic thin film.

  7. Photocatalyst activation in a pulsed low pressure discharge

    SciTech Connect (OSTI)

    Rousseau, A.; Guaitella, O.; Gatilova, L.; Thevenet, F.; Guillard, C.; Roepcke, J.; Stancu, G.D.

    2005-11-28

    The effect of combining plasma and photocatalyst for Volatile Organic Compounds (VOC) removal was investigated in a pulsed low-pressure dc discharge. The photocatalyst was TiO{sub 2} while the VOC was acetylene (1000 ppm) diluted in dry air. The temporal evolution of C{sub 2}H{sub 2} concentration was measured by Tunable Diode Laser Absorption Spectroscopy (TDLAS) in the mid-infrared region during the plasma pulse (one second). The contribution of external ultraviolet radiation and plasma exposure were quantified, both with and without a photocatalyst. The synergetic effect was clearly demonstrated.

  8. Cyclic membrane separation process

    DOE Patents [OSTI]

    Bowser, John

    2004-04-13

    A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In one of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the other part, the membrane is inoperative while gas pressure rises in the ullage. Ambient air is charged to the membrane separation unit during the latter part of the cycle.

  9. The role of non-volatile memory from an application perspective

    SciTech Connect (OSTI)

    Kettering, Brett M; Nunez, James A

    2010-09-16

    Current, emerging, and future NVM (non-volatile memory) technologies give us hope that we will be able to architect HPC (high performance computing) systems that initially use them in a memory and storage hierarchy, and eventually use them as the memory and storage for the system, complete with ownership and protections as a HDD-based (hard-disk-drive-based) file system provides today.

  10. Princeton and PPPL launch center to study volatile space weather and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    violent solar storms | Princeton Plasma Physics Lab Princeton and PPPL launch center to study volatile space weather and violent solar storms By John Greenwald December 12, 2013 Tweet Widget Google Plus One Share on Facebook Computer simulation of the solar wind in contact with the Earth's magnetosphere. The streaming wind compresses the magnetosphere on the side of the Earth that is nearest the sun, and stretches the magnetosphere into a long "tail" as the wind blows past the

  11. Electron impact and chemical ionization mass spectral analysis of a volatile uranyl derivative

    SciTech Connect (OSTI)

    Reutter, D.J.; Hardy, D.R.

    1981-01-01

    Quadrupole mass spectral analysis of the volatile uranium ligand complex bis (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato) dioxouranium-di-n-butyl sulfoxide is described utilizing electron impact (EI) and methane chemical ionization (CI) ion sources. All major ions are tentatively identified and the potential usefulness of this complex for determining uranium isotope /sup 235/U//sup 238/U abundance is demonstrated.

  12. Nanoporous Al2O3 as a "Getter" for Volatile Radionuclides into

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanostructued Glass-Ceramic Waste Forms - Energy Innovation Portal Nanoporous Al2O3 as a "Getter" for Volatile Radionuclides into Nanostructued Glass-Ceramic Waste Forms Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (738 KB) Technology Marketing SummaryThe first phase of this project is capture and encapsulation which is achieved by using nanoporous alumina to confine gaseous iodine, for example, from fission or

  13. Implications of changing correlations between WTI and other commodities, asset classes, and implied volatility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Implications of changing correlations between WTI and other commodities, asset classes, and implied volatility James Preciado October 2012 Independent Statistics & Analysis www.eia.gov U.S. Energy Information Administration Washington, DC 20585 This paper is released to encourage discussion and critical comment. The analysis and conclusions expressed here are those of the authors and not necessarily those of the U.S. Energy Information Administration. WORKING PAPER SERIES October 2012 James

  14. Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aging Conditions | Department of Energy Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions TiO2-supported vanadia (and tungsta) can be stabillized by optimization of the catalyst support PDF icon p-03_chapman.pdf More Documents & Publications The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application New Developments in Titania-Based Catalysts

  15. Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review

    SciTech Connect (OSTI)

    Burant, Aniela; Lowry, Gregory V.; Karamalidis, Athanasios K.

    2013-01-13

    Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oilbrinesc-CO{sub 2} system under carbon storage conditions. The solubility of pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by cosolvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oilbrinesc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and cosolvency, which will require more experimental data from key classes of organic compounds.

  16. Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review

    SciTech Connect (OSTI)

    Burant, Aniela; Lowry, Gregory V.; Karamalidis, Athanasios K.

    2013-01-01

    Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oilbrinesc-CO{sub 2} system under carbon storage conditions. The solubility of pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by co-solvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oil-brine-sc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and co-solvency, which will require more experimental data from key classes of organic compounds.

  17. Departmental Organization and Management

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1993-06-10

    Effective immediately, the Departmental organization structure reflected in the chart at Attachment 1 has been approved.

  18. Transportation Organization and Functions

    Broader source: Energy.gov [DOE]

    Office of Packaging and Transportation list of organizations and functions, with a list of acronyms.

  19. Coupled Physical/Chemical and Biofiltration Technologies to Reduce Air Emissions from Forest Products Industries

    SciTech Connect (OSTI)

    Gary D. McGinnis

    2001-12-31

    The research is a laboratory and bench-scale investigation of a system to concentrate and destroy volatile organic compounds (VOCs), including hazardous air pollutants, formed from the drying of wood and the manufacture of wood board products (e.g., particle board and oriented strandboard). The approach that was investigated involved concentrating the dilute VOCs (<500 ppmv) with a physical/chemical adsorption unit, followed by the treatment of the concentrated voc stream (2,000 to 2,500 ppmv) with a biofiltration unit. The research program lasted three years, and involved three research organizations. Michigan Technological University was the primary recipient of the financial assistance, the USDA Forest Products Laboratory (FPL) and Mississippi State University (MSU) were subcontractors to MTU. The ultimate objective of this research was to develop a pilot-scale demonstration of the technology with sufficient data to provide for the design of an industrial system. No commercialization activities were included in this project.

  20. Mixed crystal organic scintillators

    DOE Patents [OSTI]

    Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

    2014-09-16

    A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

  1. Effects of uncertainty in SAPRC90 rate constants and selected product yields on reactivity adjustment factors for alternative fuel vehicle emissions. Final report

    SciTech Connect (OSTI)

    Bergin, M.S.; Russell, A.G.; Yang, Y.J.; Milford, J.B.; Kirchner, F.; Stockwell, W.R.

    1996-07-01

    Tropospheric ozone is formed in the atmosphere by a series of reactions involving volatile organic compounds (VOCs) and nitrogen oxides (NO{sub x}). While NOx emissions are primarily composed of only two compounds, nitrogen oxide (NO) and nitrogen dioxide (NO{sub 2}), there are hundreds of different VOCs being emitted. In general, VOCs promote ozone formation, however, the rate and extent of ozone produced by the individual VOCs varies considerably. For example, it is widely acknowledged that formaldehyde (HCHO) is a very reactive VOC, and produces ozone rapidly and efficiently under most conditions. On the other hand, VOCs such as methane, ethane, propane, and methanol do not react as quickly, and are likely to form less urban ozone than a comparable mass of HCHO. The difference in ozone forming potential is one of the bases for the use of alternative fuels. The fuels considered in this study included compressed natural gas, LPG, mixtures of methanol and gasoline, ethanol and gasoline, and a reformulated gasoline.

  2. Uncorrelated volatile behavior during the 2011 apparition of comet C/2009 P1 Garradd

    SciTech Connect (OSTI)

    Feaga, Lori M.; A'Hearn, Michael F.; Farnham, Tony L.; Bodewits, Dennis; Sunshine, Jessica M.; Gersch, Alan M.; Protopapa, Silvia [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Yang, Bin [Institute for Astronomy, University of Hawaii, Honolulu, HI 96822 (United States); Drahus, Michal [Division of Physics, Mathematics and Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Schleicher, David G., E-mail: feaga@astro.umd.edu [Lowell Observatory, Flagstaff, AZ 86001 (United States)

    2014-01-01

    The High Resolution Instrument Infrared Spectrometer (HRI-IR) on board the Deep Impact Flyby spacecraft detected H{sub 2}O, CO{sub 2}, and CO in the coma of the dynamically young Oort Cloud comet C/2009 P1 (Garradd) post-perihelion at a heliocentric distance of 2 AU. Production rates were derived for the parent volatiles, Q {sub H2O} = 4.6 0.8 10{sup 28}, Q {sub CO2} = 3.9 0.7 10{sup 27}, and Q {sub CO} = 2.9 0.8 10{sup 28} molecules s{sup 1}, and are consistent with the trends seen by other observers and within the error bars of measurements acquired during a similar time period. When compiled with other observations of Garradd's dominant volatiles, unexpected behavior was seen in the release of CO. Garradd's H{sub 2}O outgassing, increasing and peaking pre-perihelion and then steadily decreasing, is more typical than that of CO, which monotonically increased throughout the entire apparition. Due to the temporal asymmetry in volatile release, Garradd exhibited the highest CO to H{sub 2}O abundance ratio ever observed for any comet inside the water snow line at ?60% during the HRI-IR observations. Also, the HRI-IR made the only direct measurement of CO{sub 2}, giving a typical cometary abundance ratio of CO{sub 2} to H{sub 2}O of 8% but, with only one measurement, no sense of how it varied with orbital position.

  3. Photo-activated luminescence sensor and method of detecting trichloroethylene and related volatile organochloride compounds

    DOE Patents [OSTI]

    Dinh, T.V.

    1996-06-11

    A sensor for detecting trichloroethylene and related volatile organochloride compounds uses a photo-activator that produces a photo-product complex with the contaminant. Characteristics of the light emitted from the complex will indicate the presence of the contaminant. A probe containing the photo-activator has an excitation light interface and a contaminant interface. One particular embodiment uses a porous membrane as the contaminant interface, so that the contaminant can migrate there through to the photo-activator and thereby form the complex. 23 figs.

  4. Spatial resolution and the geologic interpretation of Martian morphology - implications for subsurface volatiles

    SciTech Connect (OSTI)

    Zimbelman, J.R.

    1987-08-01

    Viking Orbiter images of the Acheron Fossae on Mars are presented and analyzed, with an emphasis on the impact of image resolution on the interpretation. High-resolution (less than 10 m/pixel) images reveal small mounds which can be interpreted as aeolian dunes, but these features are not evident on images with resolution of 50 m/pixel or greater. Also reported are the results of a visual inspection of 527 usable high-resolution images: it is found that all of the morphological features identified can arise in the absence of subsurface volatiles. 21 references.

  5. Photo-activated luminescence sensor and method of detecting trichloroethylene and related volatile organochloride compounds

    DOE Patents [OSTI]

    Dinh, Tuan V. (Knoxville, TN)

    1996-01-01

    A sensor for detecting trichloroethylene and related volatile organochloride compounds uses a photo-activator that produces a photo-product complex with the contaminant. Characteristics of the light emitted from the complex will indicate the presence of the contaminant. A probe containing the photo-activator has an excitation light interface and a contaminant interface. One particular embodiment uses a porous membrane as the contaminant interface, so that the contaminant can migrate therethrough to the photo-activator and thereby form the complex.

  6. Organizations | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility Biosciences Division Environmental Science Division Mathematics and Computer Science Division Organizations Integrating research in the computing sciences,...

  7. Public Affairs Organization Chart

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Public Affairs Organization Chart Public Affairs Communications Community Public Affairs Org Chart Education Creative Services Navigate Section Public Affairs Communications...

  8. Application and results of whole-body autoradiography in distribution studies of organic solvents

    SciTech Connect (OSTI)

    Bergman, K.

    1983-01-01

    With the growing concern for the health hazards of occupational exposure to toxic substances attention has been focused on the organic solvents, which are associated with both deleterious nervous system effects and specific tissue injuries. Relatively little is known about the distribution of organic solvents and their metabolites in the living organism. Knowledge of the specific tissue localizations and retention of solvents and solvent metabolites is of great value in revealing and understanding the sites and mechanisms of organic solvent toxicity. Whole-body autoradiography has been modified and applied to distribution studies of benzene, toluene, m-xylene, styrene, methylene chloride, chloroform, carbon tetrachloride, trichloroethylene and carbon disulfide. The high volatility of these substances has led to the development of cryo-techniques. Whole-body autoradiographic techniques applicable to the study of volatile substances are reviewed. The localizations of nonvolatile solvent metabolites and firmly bound metabolites have also been examined. The obtained results are discussed in relation to toxic effects and evaluated by comparison with other techniques used in distribution studies of organic solvents and their metabolites.

  9. Organic photosensitive devices

    DOE Patents [OSTI]

    Rand, Barry P; Forrest, Stephen R

    2013-11-26

    The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photosensitive optoelectronic devices having a photoactive organic region containing encapsulated nanoparticles that exhibit plasmon resonances. An enhancement of the incident optical field is achieved via surface plasmon polariton resonances. This enhancement increases the absorption of incident light, leading to a more efficient device.

  10. PDID: Pulsed-Discharge Ionization Detector A new detector for medical analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PDID: Pulsed-Discharge Ionization Detector A New Detector for Medical Diagnosis Matthew Moorman mmoorma@sandia.gov MicroSystems Enabled Detection Department 01716 Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2015-1387C Sandia's Volatile Organic Compound (VOC) Biomarker

  11. Indirect-Fired Kiln Conserves Scrap Aluminum and Cuts Costs

    Broader source: Energy.gov [DOE]

    This case study examines a succesful process heating technology improvement implemented by Wabash Alloys at its East Syracuse, New York, facility. A demonstration project conducted at this plant by Energy Research Company (ERCo), of Staten Island, New York, involves a new energy-efficient kiln that heats scrap aluminum for reuse. This kiln has enabled Wabash to reduce metal loss and emissions of volatile organic compounds (VOCs) and, in addition, has reduced kiln energy use by more than half.

  12. Categorical Exclusion Determination Form Project Title: Program or Program Office:

    Office of Environmental Management (EM)

    task to characterize the volatile organic compound (VOC) concentration in the headspace of a closed container with dried DeconGel 1101 (MSDS 38502). The tests described here are designed to simulate the disposal of this decontamination agent in a waste package after some predetermined drying time and packaging time. Non-radiological samples will be made by spreading decon gel on stainless steel substrates. The gel will be allowed to dry for 24 hours in the lab adjacent to the chemical hood.

  13. Vehicle Emission Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of internal combustion engine vehicles. These vehicles can run on gasoline, diesel, natural gas, or propane. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs) particulate matter (PM) A

  14. Combustion rates of chars from high-volatile fuels for FBC application

    SciTech Connect (OSTI)

    Masi, S.; Salatino, P.; Senneca, O.

    1997-12-31

    The fluidized bed combustion of high volatile fuels is often associated with huge occurrence of comminution phenomena. These result into in-bed generation of substantial amounts of carbon fines which further undergo competitive processes of combustion and elutriation. The small size of carbon fines generated by comminution is such that their further combustion is largely controlled by the intrinsic kinetics of carbon oxidation, alone or in combination with intraparticle diffusion. The competition between fine combustion and elutriation strongly affects the efficiency of fixed carbon conversion and calls for thorough characterization of the combustion kinetics and of residence times of fines in a fluidized bed of coarse solids. In this paper a collection of intrinsic combustion kinetic and porosimetric data for chars from three high-volatile fuels suitable for FBC application is presented. Chars from a Refuse Derived Fuel (RDF), a Tyre Derived Fuel (TDF) and a biomass (Robinia Pseudoacacia) are obtained from devolatilization, in fluidized bed, of fuel samples. Thermogravimetric analysis, mercury porosimetry and helium pycnometry are used to characterize the reactivity and the pore structure of the chars. Combustion rates are characterized over a wide range of temperatures (320--850 C) and oxygen partial pressures, covering the entire range of interest in fluidized bed combustion. Analysis of thermogravimetric and porosimetric data is directed to obtaining the parameters (pre-exponential factors, reaction orders, activation energies, intraparticle diffusivities) of combustion kinetic submodels for application in fluidized bed combustor modeling.

  15. Volatiles combustion in fluidized beds. Final technical report, 4 September 1992--4 June 1995

    SciTech Connect (OSTI)

    Pendergrass, R.A. II; Raffensperger, C.; Hesketh, R.P.

    1996-02-29

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. A review of the work conducted under this grant is presented in this Final Technical Report. Both experimental and theoretical work have been conducted to examine the inhibition of the combustion by the fluidized bed material, sand. It has been shown that particulate phase at incipient fluidization inhibits the combustion of propane by free radical destruction at the surface of sand particles within the particulate phase. The implications of these findings is that at bed temperatures lower than the critical temperatures, gas combustion can only occur in the bubble phase or at the top surface of a bubbling fluidized bed. In modeling fluidized bed combustion this inhibition by the particulate phase should be included.

  16. EMFLUX{reg_sign} soil-gas survey of Technical Area 54, Los Alamos National Laboratory, New Mexico

    SciTech Connect (OSTI)

    1993-09-30

    This EMFLUXR Soil-Gas Survey was conducted on Material Disposal Areas (MDAS) G, J, and L in Technical Area 54 at Los Alamos National Laboratory (LANL), New Mexico. MDA L has been used for disposal of volatile organic compounds (VOCs) and MDA G (comprising sub-areas G-1 through G-8) for disposal of both VOCs and radioactive waste; MDA I has reportedly been used for disposal of waste without either of these contaminants. All three of the sites are currently active. Figure 1 shows the location of the three MDAs within Technical Area 54 of operable Unit 1148. The purpose of the EMFLUX{reg_sign} Soil-Gas Survey was to determine the presence, identities, and relative strengths of contaminants within the three areas of LANL investigated. Quadrel understands that this information will be used in Phase-I assessment of these areas to determine flux rates of -- VOCs emanating from the ground.

  17. Comparison of coating alternatives for US Coast Guard aircraft. Final report for April 1993-August 1994

    SciTech Connect (OSTI)

    Hirst, D.J.; Spadafora, S.J.

    1994-12-12

    Current coatings used on U.S. Coast Guard aircraft contain high volatile organic compound (VOC) contents. Federal, state, and local environmental agencies restrict the amount of VOCs from the use of these materials through legislation such as the Clean Air Act and local Air Quality Management District Rules. At the request of the Coast Guard, the Naval Air Warfare Center Aircraft Division Warminster investigated several low VOC candidate replacements to the current paint scheme. The physical performance properties of these materials (i.e. corrosion resistance, adhesion, etc.) were characterized using standard coatings tests. The results of this program show that there are several acceptable alternatives. Replacement of current coating systems would reduce the total amount of hazardous materials emitted from Coast Guard painting operations and eliminate the need for expensive control equipment which will be required by the Clean Air Act (resulting in substantial future cost savings).

  18. Organic photosensitive devices

    DOE Patents [OSTI]

    Peumans, Peter; Forrest, Stephen R.

    2013-01-22

    A photoactive device is provided. The device includes a first electrode, a second electrode, and a photoactive region disposed between and electrically connected to the first and second electrodes. The photoactive region further includes an organic donor layer and an organic acceptor layer that form a donor-acceptor heterojunction. The mobility of holes in the organic donor region and the mobility of electrons in the organic acceptor region are different by a factor of at least 100, and more preferably a factor of at least 1000. At least one of the mobility of holes in the organic donor region and the mobility of electrons in the organic acceptor region is greater than 0.001 cm.sup.2/V-sec, and more preferably greater than 1 cm.sup.2/V-sec. The heterojunction may be of various types, including a planar heterojunction, a bulk heterojunction, a mixed heterojunction, and a hybrid planar-mixed heterojunction.

  19. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, Peter (Los Alamos, NM); Hemberger, Barbara J. (Los Alamos, NM)

    1991-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a polyolefin tube having an internal diameter of from about 0.01 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the tube, (b) passing a solvent through the tube, said solvent capable of separating the adhered organic contaminant from the tube. Further, a chromatographic apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a polyolefin tube having an internal diameter of from about 0.01 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the tube is disclosed.

  20. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization Office of Indian Energy Organizational Structure As a program office at DOE responsible for implementing energy programs, the Office of Indian Energy is structurally organized under the Office of the Under Secretary. This programmatic structure also focuses and facilitates the coordination between the Office of Indian Energy and the other companion program offices such as the Office of Fossil Energy, Office of Electricity and Energy Reliability and Office of Energy

  1. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization View Office of Management Organization Chart in PDF format. Office of Resource Management and Planning The Office of Resource Management and Planning provides the leadership and centralized management and direction of the Office of Management (MA) planning, budgeting, financial, human resources, and program execution processes; ensures that these processes are effective, and fully integrated and consistent with the Department-wide processes and requirements.

  2. Astatinated organic compounds

    DOE Patents [OSTI]

    Milius, Richard A.; Lambrecht, Richard M.; Bloomer, William D.

    1989-05-02

    Methods and kits for incorporating a radioactive astatine isotope (particularly .sup.211 At) into an organic compound by electrophilic astatodestannylation of organostannanes.

  3. Astatinated organic compounds

    DOE Patents [OSTI]

    Milius, R.A.; Lambrecht, R.M.; Bloomer, W.D.

    1989-05-02

    Methods and kits for incorporating a radioactive astatine isotope (particularly [sup 211]At) into an organic compound by electrophilic astatodestannylation of organostannanes. 3 figs.

  4. Bisfuel links - Professional organizations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Professional organizations http://portal.acs.org/portal/acs/corg/content" target="_blank">American Chemical Society

  5. The Use of Positive Matrix Factorization with Conditional Probability Functions in Air Quality Studies: An Application to Hydrocarbon Emissions in Houston, Texas

    SciTech Connect (OSTI)

    Xie, YuLong; Berkowitz, Carl M.

    2006-06-01

    As part of a study to identify groups of compounds (source categories) associated with different processing facilities, a multivariate receptor model called Positive Matrix Factorization (PMF) was applied to hourly average concentrations of volatile organic compounds (VOCs) measured at five Photochemical Assessment Monitoring Stations (PAMS) located near the Ship Channel in Houston, Texas. The observations were made between June and October, 2003, and limited to nighttime measurements (21:00 pm 6:00 am) in order to remove the complexity of photochemical processing and associated changes in the concentrations of primary and secondary VOCs. Six to eight volatile organic compounds source categories were identified for the five Ship Channel sites. The dominant source categories were found to be those associated with petrochemical, chemical industries and fuel evaporation. In contrast, source categories associated with on-road vehicles were found to be relatively insignificant. Although evidence of biogenic emissions was found at almost all the sites, this broad category was significant only at the Wallisville site, which was also the site furthest away from the Ship Channels area and closest to the northeast forest of Texas. Natural gas, accumulation and fuel evaporation sources were found to contribute most to the ambient VOCs, followed by the petrochemical emission of highly reactive ethene and propylene. Solvent / paint industry and fuel evaporation and emission from refineries were next in importance while the on-road vehicle exhaust generally contributed less than 10% of the total ambient VOCs. Specific geographic areas associated with each source category were identified through the use of a Conditional Probability Function (CPF) analysis that related elevated concentrations of key VOCs in each category to a network of grids superimposed on the source inventories of the VOCs.

  6. Carlsbad Field Office P. O. Box 3090 Carlsbad, New Mexico 88221

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AUG 1 1 2011 Mr. John Kieling , Acli ng Bureau Chief Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive Eas!, Building 1 Santa Fe, NM 87505-6303 Subject: Notification of Exceedance of a Disposal Room Volatile Orga nic Compound Monitoring Action Level for Carbon Tetrachloride Dear Me. Kieling: The purpose of th is letter is to notify you of the re ce ipt of validaled analytical resu lts for a volatile organic compound (VOC), carbon tetra chloride, which exceeded Ihe 50

  7. In-well vapor stripping drilling and characterization work plan

    SciTech Connect (OSTI)

    Koegler, K.J.

    1994-03-13

    This work plan provides the information necessary for drilling, sampling, and hydrologic testing of wells to be completed in support of a demonstration of the in-well vapor stripping system. The in-well vapor stripping system is a remediation technology designed to preferentially extract volatile organic compounds (VOCs) from contaminated groundwater by converting them to a vapor phase. Air-lift pumping is used to lift and aerate groundwater within the well. The volatiles escaping the aerated water are drawn off by a slight vacuum and treated at the surface while the water is allowed to infiltrate the vadose zone back to the watertable.

  8. Applicant Organization: | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Abengoa Bioenergy Biomass of Kansas, LLC Applicant Organization: Broin Companies

  9. Department of Energy Idaho - Organization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Chart Last Updated: 11/14/2011

  10. VOLATILE TRANSPORT INSIDE SUPER-EARTHS BY ENTRAPMENT IN THE WATER-ICE MATRIX

    SciTech Connect (OSTI)

    Levi, A.; Podolak, M.; Sasselov, D.

    2013-05-20

    Whether volatiles can be entrapped in a background matrix composing planetary envelopes and be dragged via convection to the surface is a key question in understanding atmospheric fluxes, cycles, and composition. In this paper, we consider super-Earths with an extensive water mantle (i.e., water planets), and the possibility of entrapment of methane in their extensive water-ice envelopes. We adopt the theory developed by van der Waals and Platteeuw for modeling solid solutions, often used for modeling clathrate hydrates, and modify it in order to estimate the thermodynamic stability field of a new phase called methane filled ice Ih. We find that in comparison to water ice VII the filled ice Ih structure may be stable not only at the high pressures but also at the high temperatures expected at the core-water mantle transition boundary of water planets.

  11. VOLATILE-RICH CIRCUMSTELLAR GAS IN THE UNUSUAL 49 CETI DEBRIS DISK

    SciTech Connect (OSTI)

    Roberge, Aki; Grady, Carol A.; Welsh, Barry Y.; Kamp, Inga; Weinberger, Alycia J.

    2014-11-20

    We present Hubble Space Telescope Space Telescope Imaging Spectrograph far-UV spectra of the edge-on disk around 49 Ceti, one of the very few debris disks showing submillimeter CO emission. Many atomic absorption lines are present in the spectra, most of which arise from circumstellar gas lying along the line-of-sight to the central star. We determined the line-of-sight C I column density, estimated the total carbon column density, and set limits on the O I column density. Surprisingly, no line-of-sight CO absorption was seen. We discuss possible explanations for this non-detection, and present preliminary estimates of the carbon abundances in the line-of-sight gas. The C/Fe ratio is much greater than the solar value, suggesting that 49 Cet harbors a volatile-rich gas disk similar to that of ? Pictoris.

  12. Modeling Volatile Species Retention Experiments: Interim Progress Report (M3FT-12LA0202053)

    SciTech Connect (OSTI)

    Carlson, Neil N. [Los Alamos National Laboratory

    2012-07-06

    Metal nuclear fuel is a candidate transmutation fuel form for advanced fuel cycles. One constituent of the fuel, americium, has a high vapor pressure, and there is a concern that excessive volatility losses of americium will occur during casting of the metal. A number of experiments have been performed using americium and surrogate metals, including experiments slated for FY12, to address the concern. The present task is to model and numerically simulate these experiments. This report describes a system-level model of the relevant experiments that has been developed together with some results. It also describes some initial 3D, full-physics simulations of portions of the experiments that have been performed.

  13. Methods for characterizing subsurface volatile contaminants using in-situ sensors

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2006-02-21

    An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.

  14. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization The Office of Economic Impact and Diversity is comprised of: The Office of the Director- contact us Office of Minority Business and Economic Development - contact us Office of Minority Education and Community Development - contact us Office of Civil Rights - contact us Office of Diversity and Inclusion - contact us Stay in Touch Get email updates from our office. Subscribe

  15. Emission of volatile sulfur compounds during composting of municipal solid waste (MSW)

    SciTech Connect (OSTI)

    Zhang, Hongyu; Schuchardt, Frank; Li, Guoxue; Yang, Jinbing; Yang, Qingyuan

    2013-04-15

    Highlights: ? We compare the volatile sulfur compounds (VSCs) emissions during three types of municipal solid wastes (MSWs) composting. ? The VSCs released from the kitchen waste composting was significantly higher than that from 1580 mm fraction of MSW. ? Among the five VSCs, H{sub 2}S was the most abundant compound with 39.043.0% of total VSCs released. ? Addition of 20% cornstalks could significantly reduce the VSCs emissions during kitchen waste composting. - Abstract: Volatile sulfur compounds (VSCs) are the main source for malodor from composting plants. In this study, the VSCs generated from composting of 1580 mm municipal solid waste (T0), kitchen waste (T1) and kitchen waste mixed dry cornstalks (T2) were measured in 60 L reactors with forced aeration for a period of 30 days. The VSCs detected in all treatments were hydrogen sulfide (H{sub 2}S), methyl mercaptan (MM), dimethyl sulfide (DMS), carbon bisulfide (CS{sub 2}) and dimethyl disulfide (DMDS). Over 90% of the VSCs emissions occurred during the first 15 days, and reached their peak values at days 47. The emission profiles of five VSCs species were significantly correlated with internal materials temperature and outlet O{sub 2} concentration (p < 0.05). Total emissions of the VSCs were 216.1, 379.3 and 126.0 mg kg{sup ?1} (dry matter) for T0, T1 and T2, respectively. Among the five VSCs, H{sub 2}S was the most abundant compound with 39.043.0% of total VSCs released. Composting of kitchen waste from separate collection posed a negative influence on the VSC and leachate production because of its high moisture content. An addition of dry cornstalks at a mixing ratio of 4:1 (wet weight) could significantly reduce the VSCs emissions and avoid leachate. Compared to pure kitchen waste, VSCs were reduced 66.8%.

  16. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  17. Center Organization | Center for Energy Efficient Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Organization People People Scientific Advisory Board Center Organization

  18. Field-usable portable analyzer for chlorinated organic compounds

    SciTech Connect (OSTI)

    Buttner, W.J.; Penrose, W.R.; Stetter, J.R.; Williams, R.D.

    1996-12-31

    In 1992, a chemical sensor was developed which showed almost perfect selectivity to vapors of chlorinated solvents. When interfaced to an instrument, a chemical analyzer will be produced that has near- absolute selectivity to vapors of volatile chlorinated organic compounds. TRI has just completed the second of a 2-phase program to develop this new instrument system, which is called the RCL MONITOR. In Phase II, this instrument was deployed in 5 EM40 operations. Phase II applications covered clean-up process monitoring, environmental modeling, routine monitoring, health and safety, and technology validation. Vapor levels between 0 and 100 ppM can be determined in 90 s with a lower detection limit of 0.5 ppM using the hand-portable instrument. Based on the favorable performance of the RCL MONITOR, the commercial instrument was released for commercial sales on Sept. 20, 1996.

  19. Evaluating anaerobic digestion for reduction of organic wastes

    SciTech Connect (OSTI)

    Hartung, H.A.

    1994-12-31

    A small-scale anaerobic digestion test has been developed for monitoring start-up work with inoperative digesters. The test is described and variables critical to its consistent operation are detailed. The method has been used in many anaerobic digestion studies, including evaluation of the digestibility of various municipal solid wastes like grass and hedge clippings, garbage and newspapers. Digestion rates are expressed in terms of the rate of production of combustible gas and the retention time needed for a fixed degree of volatile solids destruction. An example shows the advantage of digesting selected combined charges, and it is suggested that this approach might be fruitful with many toxic organic materials. Application of this test to find the digestion rates of some high-yield biomass crops is also described.

  20. Development and Application of A Membrane-Based Thermodenuder for Measurement of Volatile Particles Emitted by A Jet Turbine Engine

    SciTech Connect (OSTI)

    Cheng, Mengdawn

    2010-01-01

    Measurement of volatile particles emitted by modern jet engines is a daunting task. Besides the complexity in sampling jet aircraft exhaust, the main difficulty lies at how to faithfully capture the phase-partition dynamics of volatile particles as they travel downstream from the engine exhaust nozzle. As a result, the physico-chemical properties of the exhaust are also transformed. We have developed a sampling instrument that aims at enabling study of the phase-partition dynamics. The objective of this research project was to design and evaluate a new thermodenuder for performing phase separation of the engine-emitted volatile particles. The backbone of the new thermodenuder is a thin metallic membrane. The membrane enables extraction of molecules that can be thermally desorbed from the condensed particulate phases and collected for subsequent chemical analysis. Toward realization of the technique in the future field aircraft emissions measurement we tested this new thermo-denuding device using laboratory-generated particles that were made of non-volatile or semi-volatile chemicals. The particle penetration efficiency, a measure of the device performance, of this thermodenuder was found to be better than 99%. Results obtained from the tests executed at a number of operating temperature conditions show reasonably good thermal separation. We have scheduled to apply this new device to characterize emissions from a T63 turboshaft engine in the spring of 2010 and are expecting to show the engine results at the conference. The test results based on the laboratory-generated particles were encouraging for the intended application. With excellent particle transmission efficiency and an ability to simultaneously measure the composition in the gas and particle phases of the engine particles, we believe the new technology will make a great contribution to measurement research of engine emissions.

  1. Organic Separation Test Results

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

    2014-09-22

    Separable organics have been defined as “those organic compounds of very limited solubility in the bulk waste and that can form a separate liquid phase or layer” (Smalley and Nguyen 2013), and result from three main solvent extraction processes: U Plant Uranium Recovery Process, B Plant Waste Fractionation Process, and Plutonium Uranium Extraction (PUREX) Process. The primary organic solvents associated with tank solids are TBP, D2EHPA, and NPH. There is concern that, while this organic material is bound to the sludge particles as it is stored in the tanks, waste feed delivery activities, specifically transfer pump and mixer pump operations, could cause the organics to form a separated layer in the tank farms feed tank. Therefore, Washington River Protection Solutions (WRPS) is experimentally evaluating the potential of organic solvents separating from the tank solids (sludge) during waste feed delivery activities, specifically the waste mixing and transfer processes. Given the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria per the Waste Feed Acceptance Criteria document (24590-WTP-RPT-MGT-11-014) that there is to be “no visible layer” of separable organics in the waste feed, this would result in the batch being unacceptable to transfer to WTP. This study is of particular importance to WRPS because of these WTP requirements.

  2. Departmental Organization Management System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1996-08-27

    Public Law 95-91, 42 United States Code 7101, Department of Energy Organization Act, Section 642 gives to the Secretary of the Department of Energy the responsibility to approve organization changes affecting the number, designation, or mission of Departmental Elements and to approve the addition, deletion, or transfer of missions and/or functions of or between Departmental Elements. In order to streamline the organizational change process, the Secretary has delegate to the Heads of Departmental Headquarters and Field Elements the authority to approve organization changes. No cancellations.

  3. Inverted organic photosensitive device

    DOE Patents [OSTI]

    Forrest, Stephen R.; Tong, Xiaoran; Lee, Jun Yeob; Cho, Yong Joo

    2015-09-08

    There is disclosed a method for preparing the surface of a metal substrate. The present disclosure also relates to an organic photovoltaic device including a metal substrate made by such method. Also disclosed herein is an inverted photosensitive device including a stainless steel foil reflective electrode, an organic donor-acceptor heterojunction over the reflective electrode, and a transparent electrode over the donor-acceptor heterojunction.

  4. Laboratory Organization Chart

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Organization Chart Director Deputy Director Leadership Team Advisory Board Directorate Staff Org Chart ⇒ Navigate Section Director Deputy Director Leadership Team Advisory Board Directorate Staff Org Chart Berkeley Lab Organization Chart ESnet Protective Services ETA/ESDR ETA/EAEI ETA Chief Operating Officer Laboratory Council RIIO Sustainability Deputy Director Innovation & Partnerships Office Public Affairs Information Technology Office of the Chief Financial Officer Human

  5. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization The organizational structure of the Office of International Affairs (IA) is as follows: Office of Resource Management (IA-10) Office of the Deputy Assistant Secretary for Africa, Middle East, Europe and Eurasia (IA-20) Office of the Deputy Assistant Secretary for Asia and the Americas (IA-30) Office of the Deputy Assistant Secretary for International Climate and Technology (IA-40) IA ORG CHART 1 26 2015 for site.jpg IA's org chart is available for download here. News

  6. Organic containment separator

    DOE Patents [OSTI]

    Del Mar, Peter (Los Alamos, NM)

    1995-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube, said solvent capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube is disclosed.

  7. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, Peter (Los Alamos, NM)

    1993-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube, said solvent capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube is disclosed.

  8. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, Peter (Los Alamos, NM)

    1995-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube, said solvent capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube is disclosed.

  9. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, P.

    1993-12-28

    A process is presented of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube. The solvent is capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus is presented for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium. The apparatus includes a composite tube comprised of a blend of a polyolefin and a polyester. The composite tube has an internal diameter of from about 0.1 to about 2.0 millimeters and has sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube. 2 figures.

  10. Organic contaminant separator

    DOE Patents [OSTI]

    Mar, Peter D. (Los Alamos, NM)

    1994-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube, said solvent capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube is disclosed.

  11. Method for isotopic analysis of chlorinated organic compounds

    DOE Patents [OSTI]

    Holt, B.D.; Sturchio, N.C.

    1999-08-24

    The present invention provides a method for preparing a VOC sample for carbon and chlorine isotope ratio analysis by mass spectrometer. A VOC sample is placed in a combustion tube and reacted with CuO to form CO{sub 2} and CuCl. The CO{sub 2} is then extracted and analyzed for the carbon isotope ratio. The CuCl is separated from the excess CuO and reacted with CH{sub 3}I to form CH{sub 3}Cl, extracted and analyzed for chlorine isotope ratio. 9 figs.

  12. Characterization of Organic Coatings on Hygroscopic Salt Particles and their Atmospheric Impacts

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Ezell, Michael J.; Perraud, Veronique; Johnson, Stanley N.; Bruns, Emily; Yu, Yong; Imre, D.; Alexander, M. L.; Finlayson-Pitts, Barbara J.

    2010-03-30

    The photooxidation of ?-pinene in the presence of NO2, with and without added NaNO3 seed particles, has been studied in a large diameter flow tube. Particles formed by homogeneous nucleation and by condensation on the pre-existing seeds were sampled at various stages of the reaction, dried using four diffusion dryers, size selected at different mobility diameters (dm) using a differential mobility analyzer (DMA), and characterized with a single particle mass spectrometer (SPLAT II). It was found that homogeneously nucleated particles are spherical, have a density (?) of 1.25 0.02 g cm-3 ( 2 ?) and contain a significant amount of organic nitrates. The mass spectra of the low volatility products condensed on the NaNO3 seed particles were found to be virtually the same as in the case of homogeneous nucleation. The data show that the presence of even a submonolayer of organics on the NaNO3 particles causes water retention that leads to a decrease in particle density and that the amount of water retained increases with organic coating thickness. Thicker coatings appear to inhibit water evaporation from the particle seeds altogether. This suggests that in the atmosphere, where low volatility organics are plentiful, some hygroscopic salts will retain water and have different densities and refractive indices than expected in the absence of the organic coating. This water retention combined with the organic shell on the particles can potentially impact light scattering by these particles and activity as cloud condensation nuclei (CCN), as well as heterogeneous chemistry and photochemistry on the particles.

  13. Water-enhanced solvation of organics

    SciTech Connect (OSTI)

    Lee, J.H.

    1993-07-01

    Water-enhanced solvation (WES) was explored for Lewis acid solutes in Lewis base organic solvents, to develop cheap extract regeneration processes. WES for solid solutes was determined from ratios of solubilities of solutes in water-sat. and low-water solvent; both were determined from solid-liquid equilibrium. Vapor-headspace analysis was used to determine solute activity coefficients as function of organic phase water concentration. WES magnitudes of volatile solutes were normalized, set equal to slope of log {gamma}{sub s} vs x{sub w}/x{sub s} curve. From graph shape {Delta}(log {gamma}{sub s}) represents relative change in solute activity coefficient. Solutes investigated by vapor-headspace analysis were acetic acid, propionic acid, ethanol, 1,2-propylene glycol, 2,3-butylene glycol. Monocarboxylic acids had largest decrease in activity coefficient with water addition followed by glycols and alcohols. Propionic acid in cyclohexanone showed greatest water-enhancement {Delta} (log {gamma}{sub acid})/{Delta}(x{sub w}/x{sub acid}) = {minus}0.25. In methylcyclohexanone, the decrease of the activity coefficient of propionic acid was {minus}0.19. Activity coefficient of propionic acid in methylcyclohexanone stopped decreasing once the water reached a 2:1 water to acid mole ratio, implying a stoichiometric relation between water, ketone, and acid. Except for 2,3-butanediol, activity coefficients of the solutes studied decreased monotonically with water content. Activity coefficient curves of ethanol, 1,2-propanediol and 2,3-butanediol did not level off at large water/solute mole ratio. Solutes investigated by solid-liquid equilibrium were citric acid, gallic acid, phenol, xylenols, 2-naphthol. Saturation concentration of citric acid in anhydrous butyl acetate increased from 0.0009 to 0.087 mol/L after 1.3 % (g/g) water co-dissolved into organic phase. Effect of water-enhanced solvation for citric acid is very large but very small for phenol and its derivatives.

  14. Full body powder antichip. Final report

    SciTech Connect (OSTI)

    1996-04-17

    Chipping is the major paint defect listed for automobile customer dissatisfaction. The improved chip resistance and smoother paint surfaces produced by full body powder antichip will result in greater customer satisfaction and greater demand for US-produced automobiles. Powder antichip contains virtually no solvent, thereby reducing the potential VOC emissions from Newark Assembly by more than 90 tons per year as compared to the solvent-borne material presently applied in most full body applications. Since Newark Assembly Plant is in a severe non-attainment air quality area, which must demonstrate a 15% reduction in emissions by 1996, projects such as this are crucial to the longevity of industry in this region. The liquid paint spray systems include incineration of the oven volatile organic compounds (VOC`s) at 1,500 F. Since there are minimal VOC`s in powder coatings and the only possible releases occur only during polymerization, incineration is not required. The associated annual savings resulting from the elimination of the incinerator utilized on the liquid spray system is 1.44 {times} 10{sup 10} BTU`s per unit installed. The annual cost savings is approximately $388 thousand, far below the original estimates.

  15. Quantifying the value that wind power provides as a hedge against volatile natural gas prices

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2002-05-31

    Advocates of renewable energy have long argued that wind power and other renewable technologies can mitigate fuel price risk within a resource portfolio. Such arguments--made with renewed vigor in the wake of unprecedented natural gas price volatility during the winter of 2000/2001--have mostly been qualitative in nature, however, with few attempts to actually quantify the price stability benefit that wind and other renewables provide. This paper attempts to quantify this benefit by equating it with the cost of achieving price stability through other means, particularly gas-based financial derivatives (futures and swaps). We find that over the past two years, natural gas consumers have had to pay a premium of roughly 0.50 cents/kWh over expected spot prices to lock in natural gas prices for the next 10 years. This incremental cost is potentially large enough to tip the scales away from new investments in natural gasfired generation and in favor of investments in wind power and other renewable technologies.

  16. Method and apparatus for measuring volatile compounds in an aqueous solution

    DOE Patents [OSTI]

    Gilmore, Tyler J [Pasco, WA; Cantrell, Kirk J [West Richland, WA

    2002-07-16

    The present invention is an improvement to the method and apparatus for measuring volatile compounds in an aqueous solution. The apparatus is a chamber with sides and two ends, where the first end is closed. The chamber contains a solution volume of the aqueous solution and a gas that is trapped within the first end of the chamber above the solution volume. The gas defines a head space within the chamber above the solution volume. The chamber may also be a cup with the second end. open and facing down and submerged in the aqueous solution so that the gas defines the head space within the cup above the solution volume. The cup can also be entirely submerged in the aqueous solution. The second end of the. chamber may be closed such that the chamber can be used while resting on a flat surface such as a bench. The improvement is a sparger for mixing the gas with the solution volume. The sparger can be a rotating element such as a propeller on a shaft or a cavitating impeller. The sparger can also be a pump and nozzle where the pump is a liquid pump and the nozzle is a liquid spray nozzle open, to the head space for spraying the solution volume into the head space of gas. The pump could also be a gas pump and the nozzle a gas nozzle submerged in the solution volume for spraying the head space gas into the solution volume.

  17. Organic aerogel microspheres

    DOE Patents [OSTI]

    Mayer, S.T.; Kong, F.M.; Pekala, R.W.; Kaschmitter, J.L.

    1999-06-01

    Organic aerogel microspheres are disclosed which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonstick gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

  18. Organic aerogel microspheres

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kong, Fung-Ming (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1999-01-01

    Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

  19. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively.more » We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.« less

  20. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    SciTech Connect (OSTI)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively. We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.

  1. Water purification using organic salts

    DOE Patents [OSTI]

    Currier, Robert P.

    2004-11-23

    Water purification using organic salts. Feed water is mixed with at least one organic salt at a temperature sufficiently low to form organic salt hydrate crystals and brine. The crystals are separated from the brine, rinsed, and melted to form an aqueous solution of organic salt. Some of the water is removed from the aqueous organic salt solution. The purified water is collected, and the remaining more concentrated aqueous organic salt solution is reused.

  2. Organic metal neutron detector

    DOE Patents [OSTI]

    Butler, M.A.; Ginley, D.S.

    1984-11-21

    A device for detection of neutrons comprises: as an active neutron sensing element, a conductive organic polymer having an electrical conductivity and a cross-section for said neutrons whereby a detectable change in said conductivity is caused by impingement of said neutrons on the conductive organic polymer which is responsive to a property of said polymer which is altered by impingement of said neutrons on the polymer; and means for associating a change in said alterable property with the presence of neutrons at the location of said device.

  3. Organization Chart | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Chart Download Other Organization Charts Computing, Environment, and Life Sciences Energy and Global Security Physical Science and Engineering Photon Sciences PDF icon argonne_org_chart

  4. Reducing volatilization of heavy metals in phosphate-pretreated municipal solid waste incineration fly ash by forming pyromorphite-like minerals

    SciTech Connect (OSTI)

    Sun Ying; Zheng Jianchang; Zou Luquan; Liu Qiang; Zhu Ping; Qian Guangren

    2011-02-15

    This research investigated the feasibility of reducing volatilization of heavy metals (lead, zinc and cadmium) in municipal solid waste incineration (MSWI) fly ash by forming pyromorphite-like minerals via phosphate pre-treatment. To evaluate the evaporation characteristics of three heavy metals from phosphate-pretreated MSWI fly ash, volatilization tests have been performed by means of a dedicated apparatus in the 100-1000 deg. C range. The toxicity characteristic leaching procedure (TCLP) test and BCR sequential extraction procedure were applied to assess phosphate stabilization process. The results showed that the volatilization behavior in phosphate-pretreated MSWI fly ash could be reduced effectively. Pyromorphite-like minerals formed in phosphate-pretreated MSWI fly ash were mainly responsible for the volatilization reduction of heavy metals in MSWI fly ash at higher temperature, due to their chemical fixation and thermal stabilization for heavy metals. The stabilization effects were encouraging for the potential reuse of MSWI fly ash.

  5. Project organizations and schedules

    SciTech Connect (OSTI)

    Briggs, R.J.

    1990-07-01

    The Superconducting Super Collider Laboratory (SSCL) faces the challenge of simultaneously carrying out a large-scale construction project with demanding cost, schedule, and performance goals; and creating a scientific laboratory capable of exploiting this unique scientific instrument. This paper describes the status of the laboratory organization developed to achieve these goals, and the major near-term schedule objectives of the project.

  6. Organic solvent topical report

    SciTech Connect (OSTI)

    Cowley, W.L.

    1998-04-30

    This report is the technical basis for the accident and consequence analyses used in the Hanford Tank Farms Basis for Interim Operation. The report also contains the scientific and engineering information and reference material needed to understand the organic solvent safety issue. This report includes comments received from the Chemical Reactions Subcommittee of the Tank Advisory Panel.

  7. Business Operations Organization Chart

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office of Business Operations Organization Chart Office of Business Operations Michael Budney, Director Project Management Coordination Office Scott Hine, Director Information and Technology Services Office Steve VonVital, Director (Acting) Workforce Management Office Jennifer Blankenheim, Director Golden Field Office Timothy Meeks, Director

  8. Applicant Organization: | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BlueFire Ethanol, Inc. BlueFire Ethanol Applicant Organization:

  9. FUNDING BY ORGANIZATION

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ORGANIZATION FY 2013 FY 2014 FY 2015 Current Enacted Request Department of Energy Budget by Organization National Nuclear Security Administration Weapons Activities 6,966,855 7,781,000 8,314,902 +533,902 +6.9% Defense Nuclear Nonproliferation 2,237,420 1,954,000 1,555,156 -398,844 -20.4% Naval Reactors 994,118 1,095,000 1,377,100 +282,100 +25.8% Federal Salaries and Expenses/1 377,457 377,000 410,842 +33,842 +9.0% Cerro Grande Fire Activities -61 0 0 0 N/A Total, National Nuclear Security

  10. FUNDING BY ORGANIZATION

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ORGANIZATION FY 2014 FY 2014 FY 2015 FY 2016 Enacted Current Enacted Request $ % Department of Energy Budget by Organization National Nuclear Security Administration Weapons Activities 7,781,000 7,790,197 8,180,359 8,846,948 +666,589 +8.1% Defense Nuclear Nonproliferation 1,954,000 1,941,983 1,615,248 1,940,302 +325,054 +20.1% Naval Reactors 1,095,000 1,101,500 1,233,840 1,375,496 +141,656 +11.5% Office of the Administrator 377,000 370,500 0 0 0 N/A Federal Salaries and Expenses 0 0 369,587

  11. Impact of the revised OSHA exposure standard on evaluation and control of benzene and other volatile organic chemicals in the liquid petroleum pipeline industry

    SciTech Connect (OSTI)

    Mercer, D.O.

    1989-01-01

    The primary purpose of this study was to determine the benzene exposure potential of workers in the liquid petroleum pipeline industry and to assess the impact of compliance with the revised standard on this industry. In addition, exposure to ethylene dibromide (EDB), and ethylene dichloride (EDC), which have toxicological profiles similar to that of benzene and are routinely found in this industry, were evaluated and appropriate control protocols were recommended. Exposure potential to benzene in excess of the 0.5 ppm (8-hour TWA) OSHA action level was shown to be limited to three free product handling operations, and that this increased exposure potential was dependent on the length of time necessary to perform the operations. The incidence and magnitude of benzene overexposure was not severe and control could be accomplished with engineering methods, along with work practice controls and personal protective equipment. Through application of a risk assessment model it was shown that 14 excess leukemia deaths per one thousand workers could be expected in the employee population that routinely performs those operation having maximum benzene exposure potential. This compares to less than on excess leukemia death per one thousand workers in the total work population. The evaluation of EDB and EDC indicated that exposure potential to EDB was of greatest concern. Even though exposure could be limited through application of standard industrial hygiene methods, any control protocol short of total elimination of EDB from the product stream may be not sufficient to reduce exposure to accepted levels.

  12. TEC Working Group Member Organizations Representatives | Department...

    Office of Environmental Management (EM)

    Member Organizations Representatives TEC Working Group Member Organizations Representatives PDF icon TEC MEMBER ORGANIZATION REPRESENTATIVES TOPIC GROUP PARTICIPATION February 2006...

  13. Organization and Functions

    Office of Environmental Management (EM)

    Working to Ensure the Safety and Security of Hazardous Material Shipments Organization and Functions Mission Unit EM-30 Deputy Assistant Secretary/ADAS Waste Management Director Office of Packaging and Transportation EM-33 Regulations & Standards Support * ANSI * ASME/ ASTM * DHS * DOD FEMA * FMCSA * FRA * IAEA * ICAO * IMO * NRC * Orders * PHMSA TSA * UN TDG SCOE Packaging Certification * CoCs for Type B/AF Packages * DOE Exemptions * DOT Special Permits & COCA * QA * RAMPAC * SCALE *

  14. ORGANIZATION/GROUP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HANFORD ADVISORY BOARD MEMBERSHIP Page 1 January 22, 2016 ORGANIZATION/GROUP PRIMARY MEMBER ALTERNATE LOCAL GOVERNMENT INTERESTS (7) Benton County Bob Suyama Larry Lockrem Benton-Franklin Council of Governments Dawn Wellman Tony Benegas City of Kennewick Bob Parks Dick Smith City of Pasco Rob Davis Vacant City of Richland Pam Larsen Vince Panesko City of West Richland Jerry Peltier Richard Bloom Grant & Franklin Counties Gary Garnant Mike Korenko LOCAL BUSINESS INTERESTS (1) Tri-Cities

  15. DESTRUCTION TECHNOLOGY DEMONSTRATION FOR ORGANICS IN TRANSURANIC WASTE

    SciTech Connect (OSTI)

    Mike Spritzer

    2003-02-01

    General Atomics (GA) has recently completed a Phase I program for the development of a two-step alternative to incineration for the destruction of organics in transuranic wastes at the Savannah River Site. This process is known as thermal desorption-supercritical water oxidation, or TD-SCWO. The GA TD process uses heat to volatilize and transport organics from the waste material for subsequent treatment by SCWO. SCWO oxidizes organics in a steam medium at elevated temperatures and pressures in a manner that achieves excellent destruction efficiencies and compliance with all environmental requirements without the need for complex pollution-abatement equipment. This application of TD-SCWO is focused on a full-scale batch process for 55-gallon drums of mixed transuranic waste at the Savannah River Site. The Phase I reduced-scale test results show that the process operates as intended on surrogate waste matrices chosen to be representative of Savannah River Site transuranic mixed wastes. It provides a high degree of hydrogen removal and full containment of the radionuclide surrogate, with minimal requirements for pre-treatment and post-treatment. Other test objectives were to verify that the process produces no dioxins or furans, and meets all applicable regulatory criteria for retention of toxic metals, particulate, and criteria pollutants, while meeting WIPP/WAC and TRUPACT-II requirements. Thermal desorption of surrogate SRS mixed wastes at 500 psi and 1000 F met all tested requirements for WIPP/WAC and TRUPACT-II. SCWO of the desorbed surrogate organic materials at 500 psi and 1500 F also appears to meet all requirements for a nonincineration alternative, although >99.99% DRE for chlorinated solvents has not yet been demonstrated.

  16. Organic solvent topical report

    SciTech Connect (OSTI)

    COWLEY, W.L.

    1999-05-13

    This report provides the basis for closing the organic solvent safety issue. Sufficient information is presented to conclude that risk posed by an organic solvent fire is within risk evaluation guidelines. This report updates information contained in Analysis of Consequences of Postulated Solvent Fires in Hanford Site Waste Tanks. WHC-SD-WM-CN-032. Rev. 0A (Cowley et al. 1996). However, this document will not replace Cowley et al (1996) as the primary reference for the Basis for Interim Operation (BIO) until the recently submitted BIO amendment (Hanson 1999) is approved by the US Department of Energy. This conclusion depends on the use of controls for preventing vehicle fuel fires and for limiting the use of flame cutting in areas where hot metal can fall on the waste surface.The required controls are given in the Tank Waste Remediation System Technical Safety Requirements (Noorani 1997b). This is a significant change from the conclusions presented in Revision 0 of this report. Revision 0 of this calcnote concluded that some organic solvent fire scenarios exceeded risk evaluation guidelines, even with controls imposed.

  17. PNNL: Center for Molecular Electrocatalysis - Organization Chart

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enlarge Image | PDF version EFRC Organization Chart

  18. Form:Policy Organization | Open Energy Information

    Open Energy Info (EERE)

    Policy Organization Jump to: navigation, search Add a Policy Organization Input your policy organization name below to add to the registry. If your policy organization is already...

  19. Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling

    SciTech Connect (OSTI)

    Boone, Eric J.; Laskin, Alexander; Laskin, Julia; Wirth, Christopher; Shepson, Paul B.; Stirm, Brian H.; Pratt, Kerri A.

    2015-07-21

    Cloud water and below-cloud atmospheric particle samples were collected onboard a research aircraft during the Southern Oxidant and Aerosol Study (SOAS) over a forested region of Alabama in June 2013. The organic molecular composition of the samples was studied to gain insights into the aqueous-phase processing of organic compounds within cloud droplets. High resolution mass spectrometry with nanospray desorption electrospray ionization and direct infusion electrospray ionization were utilized to compare the organic composition of the particle and cloud water samples, respectively. Isoprene and monoterpene-derived organosulfates and oligomers were identified in both the particles and cloud water, showing the significant influence of biogenic volatile organic compound oxidation above the forested region. While the average O:C ratios of the organic compounds were similar between the atmospheric particle and cloud water samples, the chemical composition of these samples was quite different. Specifically, hydrolysis of organosulfates and formation of nitrogen-containing compounds were observed for the cloud water when compared to the atmospheric particle samples, demonstrating that cloud processing changes the composition of organic aerosol.

  20. Separation of C2 Hydrocarbons by Porous Materials: Metal Organic Frameworks as Platform

    SciTech Connect (OSTI)

    Banerjee, Debasis; Liu, Jun; Thallapally, Praveen K.

    2014-12-22

    The effective separation of small hydrocarbon molecules (C1 C4) is an important process for petroleum industry, determining the end price of many essential commodities in our daily lives. Current technologies for separation of these molecules rely on energy intensive fractional distillation processes at cryogenic temperature, which is particularly difficult because of their similar volatility. In retrospect, adsorptive separation using solid state adsorbents might be a cost effective alternative. Several types of solid state adsorbents (e.g. zeolite molecular sieves) were tested for separation of small hydrocarbon molecules as a function of pressure, temperature or vacuum. Among different types of plausible adsorbents, metal organic frameworks (MOFs), a class of porous, crystalline, inorganic-organic hybrid materials, is particularly promising. In this brief comment article, we discuss the separation properties of different types of solid state adsorbents, with a particular emphasis on MOF based adsorbents for separation of C2 hydrocarbon molecules.

  1. "Green" Replacement for Industrial Applications of Polar Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search "Green" Replacement for Industrial Applications ... The lower volatility can lead to more energy intensive separation of the solvent; however, ...

  2. Recovery of organic acids

    DOE Patents [OSTI]

    Verser, Dan W. (Menlo Park, CA); Eggeman, Timothy J. (Lakewood, CO)

    2011-11-01

    A method is disclosed for the recovery of an organic acid from a dilute salt solution in which the cation of the salt forms an insoluble carbonate salt. A tertiary amine and CO.sub.2 are introduced to the solution to form the insoluble carbonate salt and a complex between the acid and an amine. A water immiscible solvent, such as an alcohol, is added to extract the acid/amine complex from the dilute salt solution to a reaction phase. The reaction phase is continuously dried and a product between the acid and the solvent, such as an ester, is formed.

  3. Recovery of organic acids

    DOE Patents [OSTI]

    Verser, Dan W. (Golden, CO); Eggeman, Timothy J. (Lakewood, CO)

    2009-10-13

    A method is disclosed for the recovery of an organic acid from a dilute salt solution in which the cation of the salt forms an insoluble carbonate salt. A tertiary amine and CO.sub.2 are introduced to the solution to form the insoluble carbonate salt and a complex between the acid and an amine. A water immiscible solvent, such as an alcohol, is added to extract the acid/amine complex from the dilute salt solution to a reaction phase. The reaction phase is continuously dried and a product between the acid and the solvent, such as an ester, is formed.

  4. Organization Amount Volunteer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Amount Volunteer Albuquerque a nd 4 C orners Pipes a nd D rums 75 Rand, C hristine --- 7 5 Albuquerque B aseball Academy T ouch E m A ll Foundation 500 Mang, J acquelyn --- 2 50 Mang, J oseph --- 2 50 Alm, I nc 200 Martz, C arol A nn --- 1 00 Martz, H arry --- 1 00 Alzheimer's A ssociation, N ew Mexico C hapter 100 Heckethorn, S usan --- 1 00 Amarillo H igh S chool 250 Jones, Tommy --- 250 American A ssociation o f University Women --- Los Alamos 275 George, Denise --- 25 Whyte, H

  5. Emissions of Volatile Particulate Components from Turboshaft Engines running JP-8 and Fischer-Tropsch Fuels

    SciTech Connect (OSTI)

    Cheng, Mengdawn; Corporan, E.; DeWitt, M.; Landgraf, Bradley J

    2009-01-01

    Rotating-wing aircraft or helicopters are heavily used by the US military and also a wide range of commercial applications around the world, but emissions data for this class of engines are limited. In this study, we focus on emissions from T700-GE-700 and T700-GE-701C engines; T700 engine was run with military JP-8 and T701C run with both JP-8 and Fischer-Tropsch (FT) fuels. Each engine was run at three engine power settings from the idle to maximum power in sequence. Exhaust particles measured at the engine exhaust plane (EEP) have a peak mobility diameter less than 50nm in all engine power settings. At a 4-m downstream location, sulfate/sulfur measurements indicate all particulate sulfur exists practically as sulfate, and the particulate sulfur and sulfate contents increased as the engine power increased. The conversion of sulfur to sulfate was found not to be dependent on engine power setting. Analysis also showed that conversion of sulfur to sulfate was not by the adsorption of sulfur dioxide gas on the soot particles and then subsequently oxidized to form sulfate, but by gas-phase conversion of SO2 via OH or O then subsequently forming H2SO4 and condensing on soot particles. Without the sulfur and aromatic components, use of the FT fuel led to significant reduction of soot emissions as compared to that of the JP-8 fuel producing less number of particles than that of the JP-8 fuel; however, the FT fuel produced much higher number concentrations of particles smaller than 7nm than that of JP-8 in all engine power settings. This indicates non-aromatics components in the FT fuel could have contributed to the enhancement of emissions of particles smaller than 7nm. These small particles are volatile, not observed at the EEP, and may be important in playing a role for the formation of secondary particles in the atmosphere or serving as a site for effective cloud nuclei condensation to occur.

  6. Reticulated Organic Photovoltaics

    SciTech Connect (OSTI)

    Schiros T.; Yager K.; Mannsfeld S.; Chiu C.-Y.; Ciston J.; Gorodetsky A.; Palma M.; Bullard Z.; Kramer T.; Delongchamp D.; Fischer D.; Kymissis I.; Toney M.F.; Nuckolls C.

    2012-03-21

    This paper shows how the self-assembled interlocking of two nanostructured materials can lead to increased photovoltaic performance. A detailed picture of the reticulated 6-DBTTC/C{sub 60} organic photovoltaic (OPV) heterojunction, which produces devices approaching the theoretical maximum for these materials, is presented from near edge X-ray absorption spectroscopy (NEXAFS), X-ray photoelectron spectroscopy (XPS), Grazing Incidence X-ray diffraction (GIXD) and transmission electron microscopy (TEM). The complementary suite of techniques shows how self-assembly can be exploited to engineer the interface and morphology between the cables of donor (6-DBTTC) material and a polycrystalline acceptor (C{sub 60}) to create an interpenetrating network of pure phases expected to be optimal for OPV device design. Moreover, we find that there is also a structural and electronic interaction between the two materials at the molecular interface. The data show how molecular self-assembly can facilitate 3-D nanostructured photovoltaic cells that are made with the simplicity and control of bilayer device fabrication. The significant improvement in photovoltaic performance of the reticulated heterojunction over the flat analog highlights the potential of these strategies to improve the efficiency of organic solar cells.

  7. FY 2015 Summary Control Table by Organization

    Broader source: Energy.gov (indexed) [DOE]

    Request Discretionary Summary By Organization Department Of Energy By Organization National Nuclear Security Administration Weapons Activities......

  8. Organization | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Careers/ Human Resources Directory Environment, Safety & Health Furth Plasma Physics Library Lab Leadership Organization Chart Technology Transfer Contact Us Business Operations Careers/ Human Resources Directory Environment, Safety & Health Furth Plasma Physics Library Lab Leadership Organization Chart Technology Transfer Organization Careers/ Human Resources Join Princeton's TALENT NETWORK to enhance your job search and the application process for Princeton University and the Plasma

  9. Stacked organic photosensitive devices

    DOE Patents [OSTI]

    Forrest, Stephen; Xue, Jiangeng; Uchida, Soichi; Rand, Barry P.

    2007-03-27

    A device is provided having a first electrode, a second electrode, a first photoactive region having a characteristic absorption wavelength .lamda..sub.1 and a second photoactive region having a characteristic absorption wavelength .lamda..sub.2. The photoactive regions are disposed between the first and second electrodes, and further positioned on the same side of a reflective layer, such that the first photoactive region is closer to the reflective layer than the second photoactive region. The materials comprising the photoactive regions may be selected such that .lamda..sub.1 is at least about 10% different from .lamda..sub.2. The device may further comprise an exciton blocking layer disposed adjacent to and in direct contact with the organic acceptor material of each photoactive region, wherein the LUMO of each exciton blocking layer other than that closest to the cathode is not more than about 0.3 eV greater than the LUMO of the acceptor material.

  10. Microorganisms for producing organic acids

    DOE Patents [OSTI]

    Pfleger, Brian Frederick; Begemann, Matthew Brett

    2014-09-30

    Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

  11. A hybrid magnetic/complementary metal oxide semiconductor three-context memory bit cell for non-volatile circuit design

    SciTech Connect (OSTI)

    Jovanović, B. E-mail: lionel.torres@lirmm.fr; Brum, R. M.; Torres, L.

    2014-04-07

    After decades of continued scaling to the beat of Moore's law, it now appears that conventional silicon based devices are approaching their physical limits. In today's deep-submicron nodes, a number of short-channel and quantum effects are emerging that affect the manufacturing process, as well as, the functionality of the microelectronic systems-on-chip. Spintronics devices that exploit both the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, are promising solutions to circumvent these scaling threats. Being compatible with the CMOS technology, such devices offer a promising synergy of radiation immunity, infinite endurance, non-volatility, increased density, etc. In this paper, we present a hybrid (magnetic/CMOS) cell that is able to store and process data both electrically and magnetically. The cell is based on perpendicular spin-transfer torque magnetic tunnel junctions (STT-MTJs) and is suitable for use in magnetic random access memories and reprogrammable computing (non-volatile registers, processor cache memories, magnetic field-programmable gate arrays, etc). To demonstrate the potential our hybrid cell, we physically implemented a small hybrid memory block using 45 nm × 45 nm round MTJs for the magnetic part and 28 nm fully depleted silicon on insulator (FD-SOI) technology for the CMOS part. We also report the cells measured performances in terms of area, robustness, read/write speed and energy consumption.

  12. Pyrolysis Autoclave Technology Demonstration Program for Treatment of DOE Solidified Organic Wastes

    SciTech Connect (OSTI)

    Roesener, W.S.; Mason, J.B.; Ryan, K.; Bryson, S.; Eldredge, H.B.

    2006-07-01

    In the summer of 2005, MSE Technologies Applications, Inc. (MSE) and THOR Treatment Technologies, LLC (TTT) conducted a demonstration test of the Thermal Organic Reduction (THOR{sup sm}) in-drum pyrolysis autoclave system under contract to the Department of Energy. The purpose of the test was to demonstrate that the THOR{sup sm} pyrolysis autoclave system could successfully treat solidified organic waste to remove organics from the waste drums. The target waste was created at Rocky Flats and currently resides at the Radioactive Waste Management Complex (RWMC) at the Idaho National Laboratory (INL). Removing the organics from these drums would allow them to be shipped to the Waste Isolation Pilot Plant for disposal. Two drums of simulated organic setup waste were successfully treated. The simulated waste was virtually identical to the expected waste except for the absence of radioactive components. The simulated waste included carbon tetrachloride, trichloroethylene, perchloroethylene, Texaco Regal oil, and other organics mixed with calcium silicate and Portland cement stabilization agents. The two-stage process consisted of the THOR{sup sm} electrically heated pyrolysis autoclave followed by the MSE off gas treatment system. The treatment resulted in a final waste composition that meets the requirements for WIPP transportation and disposal. There were no detectable volatile organic compounds in the treated solid residues. The destruction and removal efficiency (DRE) for total organics in the two drums ranged from >99.999% to >99.9999%. The operation of the process proved to be easily controllable using the pyrolysis autoclave heaters. Complete treatment of a fully loaded surrogate waste drum including heat-up and cooldown took place over a two-day period. This paper discusses the results of the successful pyrolysis autoclave demonstration testing. (authors)

  13. Organic rankine cycle fluid

    DOE Patents [OSTI]

    Brasz, Joost J.; Jonsson, Ulf J.

    2006-09-05

    A method of operating an organic rankine cycle system wherein a liquid refrigerant is circulated to an evaporator where heat is introduced to the refrigerant to convert it to vapor. The vapor is then passed through a turbine, with the resulting cooled vapor then passing through a condenser for condensing the vapor to a liquid. The refrigerant is one of CF.sub.3CF.sub.2C(O)CF(CF.sub.3).sub.2, (CF.sub.3).sub.2 CFC(O)CF(CF.sub.3).sub.2, CF.sub.3(CF.sub.2).sub.2C(O)CF(CF.sub.3).sub.2, CF.sub.3(CF.sub.2).sub.3C(O)CF(CG.sub.3).sub.2, CF.sub.3(CF.sub.2).sub.5C(O)CF.sub.3, CF.sub.3CF.sub.2C(O)CF.sub.2CF.sub.2CF.sub.3, CF.sub.3C(O)CF(CF.sub.3).sub.2.

  14. Is spin transport through molecules really occurring in organic spin valves? A combined magnetoresistance and inelastic electron tunnelling spectroscopy study

    SciTech Connect (OSTI)

    Galbiati, Marta; Tatay, Sergio; Delprat, Sophie; Khanh, Hung Le; Deranlot, Cyrile; Collin, Sophie; Seneor, Pierre Mattana, Richard Petroff, Frédéric

    2015-02-23

    Molecular and organic spintronics is an emerging research field which combines the versatility of chemistry with the non-volatility of spintronics. Organic materials have already proved their potential as tunnel barriers (TBs) or spacers in spintronics devices showing sizable spin valve like magnetoresistance effects. In the last years, a large effort has been focused on the optimization of these organic spintronics devices. Insertion of a thin inorganic tunnel barrier (Al{sub 2}O{sub 3} or MgO) at the bottom ferromagnetic metal (FM)/organic interface seems to improve the spin transport efficiency. However, during the top FM electrode deposition, metal atoms are prone to diffuse through the organic layer and potentially short-circuit it. This may lead to the formation of a working but undesired FM/TB/FM magnetic tunnel junction where the organic plays no role. Indeed, establishing a protocol to demonstrate the effective spin dependent transport through the organic layer remains a key issue. Here, we focus on Co/Al{sub 2}O{sub 3}/Alq{sub 3}/Co junctions and show that combining magnetoresistance and inelastic electron tunnelling spectroscopy measurements one can sort out working “organic” and short-circuited junctions fabricated on the same wafer.

  15. Final Report, The Influence of Organic-Aerosol Emissions and Aging on Regional and Global Aerosol Size Distributions and the CCN Number Budget

    SciTech Connect (OSTI)

    Donahue, Neil M.

    2015-12-23

    We conducted laboratory experiments and analyzed data on aging of organic aerosol and analysis of field data on volatility and CCN activity. With supplemental ASR funding we participated in the FLAME-IV campaign in Missoula MT in the Fall of 2012, deploying a two-chamber photochemical aging system to enable experimental exploration of photochemical aging of biomass burning emissions. Results from that campaign will lead to numerous publications, including demonstration of photochemical production of Brown Carbon (BrC) from secondary organic aerosol associated with biomass burning emissions as well as extensive characterization of the effect of photochemical aging on the overall concentrations of biomass burning organic aerosol. Excluding publications arising from the FLAME-IV campaign, project research resulted in 8 papers: [11, 5, 3, 10, 12, 4, 8, 7], including on in Nature Geoscience addressing the role of organic compounds in nanoparticle growth [11

  16. Method of doping organic semiconductors

    DOE Patents [OSTI]

    Kloc,; Christian Leo (Constance, DE); Ramirez; Arthur Penn (Summit, NJ); So, Woo-Young (New Providence, NJ)

    2010-10-26

    An apparatus has a crystalline organic semiconducting region that includes polyaromatic molecules. A source electrode and a drain electrode of a field-effect transistor are both in contact with the crystalline organic semiconducting region. A gate electrode of the field-effect transistor is located to affect the conductivity of the crystalline organic semiconducting region between the source and drain electrodes. A dielectric layer of a first dielectric that is substantially impermeable to oxygen is in contact with the crystalline organic semiconducting region. The crystalline organic semiconducting region is located between the dielectric layer and a substrate. The gate electrode is located on the dielectric layer. A portion of the crystalline organic semiconducting region is in contact with a second dielectric via an opening in the dielectric layer. A physical interface is located between the second dielectric and the first dielectric.

  17. World Health Organization (WHO) | Open Energy Information

    Open Energy Info (EERE)

    Health Organization (WHO) Jump to: navigation, search Logo: World Health Organization (WHO) Name: World Health Organization (WHO) Address: 20, avenue Appia 1211 Geneva, Switzerland...

  18. Form:Financial Organization | Open Energy Information

    Open Energy Info (EERE)

    Financial Organization Jump to: navigation, search Add a Financial Organization Input the name of the finanical organization below to add it to the registry. If the financial...

  19. APS Organization Chart | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    APS Organization Chart The Advanced Photon Source (APS) organization comprises three divisions and one project office. Advanced Photon Source Organization Photon Sciences Overview...

  20. Form:Networking Organization | Open Energy Information

    Open Energy Info (EERE)

    Networking Organization Jump to: navigation, search Add a Networking Organization Input your networking organization name below to add to the registry. If your networking...

  1. Office of Environmental Management (EM) Organization Chart |...

    Office of Environmental Management (EM)

    Environmental Management (EM) Organization Chart Office of Environmental Management (EM) Organization Chart PDF icon Office of Environmental Management (EM) Organization Chart More...

  2. PPPO Organization Chart | Department of Energy

    Office of Environmental Management (EM)

    PPPO Organization Chart PPPO Organization Chart PPPO Organization Chart r011415 PORTSMOUTHPADUCAH PROJECT OFFICE PPPO LOGO-4 4-3.png PPPO Website Directory...

  3. Clean Technology & Sustainable Industries Organization | Open...

    Open Energy Info (EERE)

    leCleanTechnology%26SustainableIndustriesOrganization&oldid765712" Categories: Organizations Networking Organizations Trade Groups Stubs Articles with outstanding TODO tasks...

  4. Our Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Our Organization Our Organization POWER SYSTEMS ENGINEERING RESEARCH & DEVELOPMENT (PSE R&D) NATIONAL ELECTRICITY DELIVERY DIVISION (NEDD) INFRASTRUCTURE SECURITY & ENERGY RESTORATION (ISER) ENERGY INFRASTRUCTURE MODELING AND ANALYSIS (EIMA) ADVANCED GRID INTEGRATION (AGI) The Power Systems Engineering Research and Development Division is responsible for the development and management of projects for "next generation" electricity delivery technologies and

  5. Organic fuels | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Organic fuels Place: Houston, Texas Zip: 77056 Product: Biodiesel producer and distributor Coordinates: 29.76045, -95.369784 Show Map Loading...

  6. Organic Power | Open Energy Information

    Open Energy Info (EERE)

    Power Jump to: navigation, search Name: Organic Power Place: Ireland Sector: Biomass, Hydro, Wind energy Product: Irish project developer active in wind energy, combined heat and...

  7. Chairman, SRS Community Reuse Organization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remarks by David Jameson, Chairman, SRS Community Reuse Organization before the Blue Ribbon Commission on America's Nuclear Future Augusta, GA, January 7, 2011 Today, you are...

  8. Final Technical Report

    SciTech Connect (OSTI)

    Alexander Fridman

    2005-06-01

    This DOE project DE-FC36-04GO14052 ''Plasma Pilot Plant Test for Treating VOC Emissions from Wood Products Plants'' was conducted by Drexel University in cooperation with Georgia-Pacific (G-P) and Kurchatov Institute (KI). The objective of this project was to test the Plasma Pilot Plant capabilities in wood industry. The final goal of the project was to replace the current state-of-the-art, regenerative thermal oxidation (RTO) technology by Low-Temperature Plasma Technology (LTPT) in paper and wood industry for Volatile Organic Components (VOC) destruction in High Volume Low Concentration (HVLC) vent emissions. MetPro Corporation joined the team as an industrial partner from the environmental control business and a potential leader for commercialization. Concurrent Technology Corporation (CTC) has a separate contract with DOE for this technology evaluation. They prepared questionnaires for comparison of this technology and RTO, and made this comparison. These data are presented in this report along with the description of the technology itself. Experiments with the pilot plant were performed with average plasma power up to 3.6 kW. Different design of the laboratory and pilot plant pulsed coronas, as well as different analytical methods revealed many new peculiarities of the VOC abatement process. The work reported herein describes the experimental results for the VOCs removal efficiency with respect to energy consumption, residence time, water effect and initial concentration.

  9. Sample extraction and injection with a microscale preconcentrator.

    SciTech Connect (OSTI)

    Robinson, Alex Lockwood; Chan, Helena Kai Lun

    2007-09-01

    This report details the development of a microfabricated preconcentrator that functions as a fully integrated chemical extractor-injector for a microscale gas chromatograph (GC). The device enables parts-per-billion detection and quantitative analysis of volatile organic compounds (VOCs) in indoor air with size and power advantages over macro-scale systems. The 44 mm{sup 3} preconcentrator extracts VOCs using highly adsorptive, granular forms of graphitized carbon black and carbon molecular sieves. The micron-sized silicon cavities have integrated heating and temperature sensing allowing low power, yet rapid heating to thermally desorb the collected VOCs (GC injection). The keys to device construction are a new adsorbent-solvent filling technique and solvent-tolerant wafer-level silicon-gold eutectic bonding technology. The product is the first granular adsorbent preconcentrator integrated at the wafer level. Other advantages include exhaustive VOC extraction and injection peak widths an order of magnitude narrower than predecessor prototypes. A mass transfer model, the first for any microscale preconcentrator, is developed to describe both adsorption and desorption behaviors. The physically intuitive model uses implicit and explicit finite differences to numerically solve the required partial differential equations. The model is applied to the adsorption and desorption of decane at various concentrations to extract Langmuir adsorption isotherm parameters from effluent curve measurements where properties are unknown a priori.

  10. Passive soil venting at the Chemical Waste Landfill Site at Sandia National Laboratories, Albuquerque, New Mexico

    SciTech Connect (OSTI)

    Phelan, J.M.; Reavis, B.; Cheng, W.C.

    1995-05-01

    Passive Soil Vapor Extraction was tested at the Chemical Waste Landfill (CWL) site at Sandia National Laboratories, New Mexico (SNLIW). Data collected included ambient pressures, differential pressures between soil gas and ambient air, gas flow rates into and out of the soil and concentrations of volatile organic compounds (VOCS) in vented soil gas. From the differential pressure and flow rate data, estimates of permeability were arrived at and compared with estimates from other studies. Flow, differential pressure, and ambient pressure data were collected for nearly 30 days. VOC data were collected for two six-hour periods during this time. Total VOC emissions were calculated and found to be under the limit set by the Resource Conservation and Recovery Act (RCRA). Although a complete process evaluation is not possible with the data gathered, some of the necessary information for designing a passive venting process was determined and the important parameters for designing the process were indicated. More study is required to evaluate long-term VOC removal using passive venting and to establish total remediation costs when passive venting is used as a polishing process following active soil vapor extraction.

  11. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    SciTech Connect (OSTI)

    Jin, Ling; Tonse, Shaheen; Cohan, Daniel S.; Mao, Xiaoling; Harley, Robert A.; Brown, Nancy J.

    2009-05-15

    CMAQ-HDDM is used to determine spatial and temporal variations in ozone limiting reagents and local vs upwind source contributions for an air pollution episode in Central California. We developed a first- and second- order sensitivity analysis approach with the Decoupled Direct Method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a five-day ozone episode (29th July-3rd Aug, 2000). Despite considerable spatial variations, nitrogen oxides (NO{sub x}) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8-hr ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1-hr ozone standard. Inter-basin source contributions of NO{sub x} emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NO{sub x} and AVOC, and the rate coefficient of the OH + NO{sub 2} termination reaction, have the greatest effect on first-order ozone responses to changes in NO{sub x} emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

  12. The effect of planets beyond the ice line on the accretion of volatiles by habitable-zone rocky planets

    SciTech Connect (OSTI)

    Quintana, Elisa V. [SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Lissauer, Jack J., E-mail: elisa.quintana@nasa.gov [Space Science and Astrobiology Division 245-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

    2014-05-01

    Models of planet formation have shown that giant planets have a large impact on the number, masses, and orbits of terrestrial planets that form. In addition, they play an important role in delivering volatiles from material that formed exterior to the snow line (the region in the disk beyond which water ice can condense) to the inner region of the disk where terrestrial planets can maintain liquid water on their surfaces. We present simulations of the late stages of terrestrial planet formation from a disk of protoplanets around a solar-type star and we include a massive planet (from 1 M {sub ?} to 1 M {sub J}) in Jupiter's orbit at ?5.2 AU in all but one set of simulations. Two initial disk models are examined with the same mass distribution and total initial water content, but with different distributions of water content. We compare the accretion rates and final water mass fraction of the planets that form. Remarkably, all of the planets that formed in our simulations without giant planets were water-rich, showing that giant planet companions are not required to deliver volatiles to terrestrial planets in the habitable zone. In contrast, an outer planet at least several times the mass of Earth may be needed to clear distant regions of debris truncating the epoch of frequent large impacts. Observations of exoplanets from radial velocity surveys suggest that outer Jupiter-like planets may be scarce, therefore, the results presented here suggest that there may be more habitable planets residing in our galaxy than previously thought.

  13. Emissions Inventory Report Summary: Reporting Requirements for the New Mexico Administrative code, Title 20, Chapter 2, Part 73 (20 NMAC 2.73) for Calendar Year 1997

    SciTech Connect (OSTI)

    1999-01-01

    Los Alamos National Laboratory (the Laboratory) is subject to emissions reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73, (20 NMAC 2.73), Notice of Intent and Emissions Inventory Requirements. The Laboratory has the potential to emit 100 tons per year of suspended particulate matter (PM), nitrogen oxides (NO{sub x}), carbon monoxide (CO), and volatile organic compounds (VOCs). For 1997, combustion products from the industrial sources contributed the greatest amount of regulated air emissions from the Laboratory. Research and development activities contributed the greatest amount of VOCs. Emissions of beryllium and aluminum were reported for activities permitted under 20 NMAC 2.72, Construction Permits.

  14. An assessment of the flammability and explosion potential of transuranic waste

    SciTech Connect (OSTI)

    Silva, M.

    1991-06-01

    The explosion potential of transuranic (TRU) waste, destined for the Waste Isolation Pilot (WIPP), was recently examined in EEG-45. That investigation focused on the volatile organic compounds (VOCs) in the waste, particularly acetone, and concluded that an explosion due to the VOCs was unlikely. Recent evidence raises serious concerns about drums containing mixed radioactive hazardous waste bound for the WIPP. Static electricity generated by the plastic bags represents a potential ignition source for other fuels, such as methane gas or hydrogen gas, during transportation and during the test phase. The potential danger of explosion due to hydrogen gas or methane gas generation has not yet been resolved. This report investigates that potential hazard and examines documented ignitions, fires, explosions and incidents of overpressurization of containers at generating and storage sites planning to send transuranic waste to the WIPP for disposal. 68 refs., 6 figs.

  15. Workplace Charging Challenge Partner: Organic Valley | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organic Valley is America's largest cooperative of organic farmers and a well-known organic brand. One of Organic Valley's goals is to promote a respect for the diversity, dignity, ...

  16. Renewable Energy Nongovernmental Organization Network (RENOVE...

    Open Energy Info (EERE)

    Nongovernmental Organization Network (RENOVE) Jump to: navigation, search Name: Renewable Energy Nongovernmental Organization Network (RENOVE) Place: Brasilia, Brazil Phone Number:...

  17. Physical Sciences & Engineering Directorate Organization Chart...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Awards and Achievements Organization Chart Contact Us Physical Sciences & Engineering Directorate Organization Chart PDF icon pseorgchart.pdf...

  18. FY 2013 Control Table by Organization

    Energy Savers [EERE]

    Approp. * Request % Discretionary Summary By Organization Department Of Energy By Organization National Nuclear Security Administration Weapons Activities......

  19. FY 2012 Control Table by Organization

    Energy Savers [EERE]

    Request CR Request % Discretionary Summary By Organization Department Of Energy By Organization National Nuclear Security Administration Weapons Activities * ...

  20. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOE Patents [OSTI]

    Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

    1998-05-19

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

  1. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOE Patents [OSTI]

    Taylor, Robert T.; Jackson, Kenneth J.; Duba, Alfred G.; Chen, Ching-I

    1998-01-01

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

  2. Metal-Organic Framework Thin Films as Stationary Phases in Microfabricated Gas-Chromatography Columns.

    SciTech Connect (OSTI)

    Read, Douglas; Sillerud, Colin Halliday

    2016-01-01

    The overarching goal of this project is to integrate Sandia's microfabricated gas-chromatography ( GC) columns with a stationary phase material that is capable of retaining high-volatility chemicals and permanent gases. The successful integration of such a material with GCs would dramatically expand the repertoire of detectable compounds for Sandia's various microanalysis systems. One such promising class of candidate materials is metal-organic frameworks (MOFs). In this report we detail our methods for controlled deposition of HKUST-1 MOF stationary phases within GC columns. We demonstrate: the chromatographic separation of natural gas; a method for determining MOF film thickness from chromatography alone; and the first-reported GC x GC separation of natural gas -- in general -- let alone for two disparate MOF stationary phases. In addition we determine the fundamental thermodynamic constant for mass sorption, the partition coefficient, for HKUST-1 and several light hydrocarbons and select toxic industrial chemicals.

  3. Ultrasonic process for remediation of organics-contaminated groundwater/wastewater

    SciTech Connect (OSTI)

    Wu, J.M.; Peters, R.W.

    1995-07-01

    A technology is being developed that employs ultrasonic-wave energy for remediation of groundwater/wastewater contaminated with volatile organic compounds such as carbon tetrachloride (CCl{sub 4}) and trichloroethylene (TCE). This paper presents the updated results of a laboratory investigation of ultrasonic groundwater remediation using synthetic groundwaters prepared with laboratory deionized water. Key process parameters investigated included steady-state temperature, contaminant concentration, solution pH, sonication time, and intensity of the applied ultrasonics-wave energy. High destruction efficiencies of the target contaminants were achieved, and the sonication time required for a given degree of destruction decreased with increasing intensity of the applied ultrasonic energy. The sonication time can be further reduced by adding a chemical oxidant such as hydrogen peroxide.

  4. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    SciTech Connect (OSTI)

    Kim, S.; Kim, S. -Y.; Lee, M.; Shim, H.; Wolfe, G. M.; Guenther, A. B.; He, A.; Hong, Y.; Han, J.

    2015-04-29

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Guangzhou, and Beijing are surrounded by densely forested areas, and recent research has consistently demonstrated the importance of biogenic volatile organic compounds (VOCs) from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical, undermine our ability to assess regional photochemical air pollution problems. We present an observational data set of CO, NOx, SO2, ozone, HONO, and VOCs (anthropogenic and biogenic) from Taehwa research forest (TRF) near the Seoul metropolitan area in early June 2012. The data show that TRF is influenced both by aged pollution and fresh biogenic volatile organic compound emissions. With the data set, we diagnose HOx (OH, HO2, and RO2) distributions calculated using the University of Washington chemical box model (UWCM v2.1) with near-explicit VOC oxidation mechanisms from MCM v3.2 (Master Chemical Mechanism). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that (1) different model simulation scenarios cause systematic differences in HOx distributions, especially OH levels (up to 2.5 times), and (2) radical destruction (HO2 + HO2 or HO2 + RO2) could be more efficient than radical recycling (RO2 + NO), especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozoneVOCNOx sensitivity and VOC oxidation product formation rates. Overall, the NOx limited regime is assessed except for the morning hours (8 a.m. to 12 p.m. local standard time), but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with oxygenated VOCs (OVOCs) production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher-than-expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.

  5. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, Joel M.; Wylie, Allan H.

    1996-01-01

    A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

  6. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, J.M.; Wylie, A.H.

    1996-01-09

    A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

  7. Unsaturated Groundwater and Heat Transport Model.

    Energy Science and Technology Software Center (OSTI)

    2002-05-13

    TMVOC is a simulator for multicomponent, multiphase, nonisothermal flows of water, soil gas, and several volatile organic chemicals (VOCs). It is based on the M2NOTS-code developed by Adeyinka Adenekan as part of his PhD project at UC Berkeley (Adenekan, 1992). TMVOC is written in standard FORTRAN 77 and operates within the framework of TOUGH2, Version 2.0 (T2V2; Pruess et al., 1999). The code consists of two modules (groups of routines) named *t2fm.f* and *emvoc.f* thatmore » must be linked to several standard T2V2 modules.« less

  8. Borehole induction logging for the Dynamic Underground Stripping Project LLNL gasoline spill site

    SciTech Connect (OSTI)

    Boyd, S.; Newmark, R.; Wilt, M.

    1994-01-21

    Borehole induction logs were acquired for the purpose of characterizing subsurface physical properties and monitoring steam clean up activities at the Lawrence Livermore National Laboratory. This work was part of the Dynamic Underground Stripping Project`s demonstrated clean up of a gasoline spin. The site is composed of unconsolidated days, sands and gravels which contain gasoline both above and below the water table. Induction logs were used to characterize lithology, to provide ``ground truth`` resistivity values for electrical resistance tomography (ERT), and to monitor the movement of an underground steam plume used to heat the soil and drive volatile organic compounds (VOCs) to the extraction wells.

  9. Comparison of FTIR and Particle Mass Spectrometry for the Measurement of Paticulate Organic Nitrates

    SciTech Connect (OSTI)

    Bruns, Emily; Perraud, Veronique; Zelenyuk, Alla; Ezell, Michael J.; Johnson, Stanley N.; Yu, Yong; Imre, D.; Finlayson-Pitts, Barbara J.; Alexander, M. L.

    2010-02-01

    While multifunctional organic nitrates are formed during the atmospheric oxidation of volatile organic compounds, relatively little is known about their signatures in particle mass spectrometers. High resolution time-of-flight aerosol mass spectrometry (HR-ToF-AMS) was applied to NH4NO3, NaNO3 and isosorbide 5-mononitrate (IMN) particles, and to secondary organic aerosol (SOA) from NO3 radical reactions at 22 C and 1 atm in air with and pinene, 3-carene, limonene and isoprene. For comparison, single particle laser ablation mass spectra (SPLAT II) were also obtained for IMN and SOA from the pinene reaction. The mass spectra of all particles exhibit significant intensity at m/z 30, and for the SOA, weak peaks corresponding to various organic fragments containing nitrogen [CxHyNzOa]+ were identified using HR-ToF-AMS. The NO+/NO2+ ratios from HR-ToF-AMS were 10-15 for IMN and the SOA from the and pinene, 3-carene and limonene reactions, ~5 for the isoprene reaction, 2.4 for NH4NO3 and 80 for NaNO3. The N/H ratios from HR-ToF-AMS for the SOA were smaller by a factor of 2 to 4 than the -ONO2/C-H ratios measured using FTIR on particles impacted on ZnSe windows. While the NO+/NO2+ ratio may provide a generic indication of organic nitrates under some conditions, specific identification of particulate organic nitrates awaits further development of particle mass spectrometry techniques.

  10. Cycle chemistry guidelines for fossil plants: All-volatile treatment. Final report

    SciTech Connect (OSTI)

    Dooley, R.B.; Aschoff, A.F.; Pocock, F.J.

    1996-04-01

    The Interim Consensus Guidelines (ICG) for Fossil Plant Cycle Chemistry were introduced in 1986 to provide the guidance needed to better control cycle corrosion and deposition. The ICG were considered interim; they would be reviewed over the next several years in the light of subsequent research and operating experience in implementing these Guidelines, and then revised as necessary. The guidelines provide a set of target values and action levels for the critical sample points throughout the water and steam cycle for drum and once-through units, covering a pressure range of 600--3,600 psi. In specific, the guidelines--which are applicable to baseload, startup, cycling, and peaking operation--discuss corrective actions to be taken when the guideline limits are exceeded as well as sampling, instrumentation, and monitoring issues. Moreover, for the first time, the guidelines address conversion of a drum boiler to AVT as well as procedures for reacting to contaminant ingress. The major philosophy changes from the ICG involve relaxing the feedwater oxygen limits for all-ferrous feedwater systems, indicating that at least one ppb of oxygen should be present at the economizer inlet and that perhaps an oxygen scavenger is not required. For units with mixed metallurgy feedwater systems, the optimum treatment involves maintaining a reducing environment with an oxygen scavenger. Wherever possible, the guidelines have been organized in tabular and graphical form to facilitate use and present information logically and clearly. Sample points, monitoring parameters, target values, and action levels have been summarized on the familiar single generic-cycle diagrams used in the ICG; these may be modified, as appropriate, and permanently displayed at key locations in each plant.

  11. No-migration variance petition. Appendix B, Attachments E--Q: Volume 4, Revision 1

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    Volume IV contains the following attachments: TRU mixed waste characterization database; hazardous constituents of Rocky flats transuranic waste; summary of waste components in TRU waste sampling program at INEL; total volatile organic compounds (VOC) analyses at Rocky Flats Plant; total metals analyses from Rocky Flats Plant; results of toxicity characteristic leaching procedure (TCLP) analyses; results of extraction procedure (EP) toxicity data analyses; summary of headspace gas analysis in Rocky Flats Plant (RFP) -- sampling program FY 1988; waste drum gas generation--sampling program at Rocky Flats Plant during FY 1988; TRU waste sampling program -- volume one; TRU waste sampling program -- volume two; and summary of headspace gas analyses in TRU waste sampling program; summary of volatile organic compounds (V0C) -- analyses in TRU waste sampling program.

  12. Genetic control of organ abscission

    DOE Patents [OSTI]

    Liljegren, Sarah J.; Ecker, Joseph R.; Yanofsky, Martin F.

    2007-01-30

    A method for decreasing the rate of organ or floral abscission is described. The method includes modifying the ARF GAP domain of a gene. In one instance the gene is the NEVERSHED gene.

  13. Photochemical dimerization of organic compounds

    DOE Patents [OSTI]

    Crabtree, Robert H. (Bethany, CT); Brown, Stephen H. (Princeton, NJ); Muedas, Cesar A. (New Haven, CT); Ferguson, Richard R. (Branford, CT)

    1992-01-01

    At least one of selectivity and reaction rate of photosensitized vapor phase dimerizations, including dehydrodimerizations, hydrodimerizations and cross-dimerizations of saturated and unsaturated organic compounds is improved by conducting the dimerization in the presence of hydrogen or nitrous oxide.

  14. Management Principles for Nonproliferation Organizations

    SciTech Connect (OSTI)

    Frazar, Sarah L.; Hund, Gretchen

    2012-03-06

    This paper identifies business models and six management principles that can be applied by a nonproliferation organization to maximize the value and effectiveness of its products. The organizations responsible for reducing the nuclear proliferation threat have experienced a substantial growth in responsibility and visibility since the September 11 attacks. Since then, the international community has witnessed revelations of clandestine nuclear facilities, nuclear black markets, periodic nuclear tests, and a resurgence of interest by countries worldwide in developing nuclear capabilities. The security environment will likely continue to evolve in unexpected ways since most of the proliferation threats with which the world will be forced to contend remain unforeseen. To better prepare for and respond to this evolving security environment, many nonproliferation organizations are interested in finding new or better ways to increase the effectiveness and efficiency of their operations. Of course, all organizations, whether they are market driven or non-profit, must operate effectively and efficiently if they are to succeed. Indeed, as this study demonstrates, many of the management principles that this study recommends can help all organizations succeed. However, this study pays particular attention to nonproliferation organizations because of the mission they are responsible for fulfilling. Nonproliferation organizations, including nonproliferation programs that operate within a larger national security organization, are responsible for reducing the threat of nuclear, chemical and biological weapons. These organizations have an enduring mandate from the public and the international community not to fail in the completion of their mission for failure could have detrimental impacts on international security, public health and the environment. Moreover, the public expects nonproliferation organizations and programs to fulfill their mission, even when resources are limited. They are expected to anticipate and react quickly to prevent a potential threat while staying accountable to their public stakeholders, many of whom remain unaware of the very threats the organization is trying to address. When budgets are flush, it is easy to believe that money will solve all problems; but during times of economic hardship, managers must rely on creative and cost-effective management approaches to implement their missions. Fortunately, managers of nonproliferation organizations can draw on a wealth of research on organizational design and culture to help them identify the management strategies most appropriate for them. Such research can help nonproliferation managers think about their own organizational structures and cultures and adapt accepted management principles to their unique organizational mission. This analytical process is not straight forward, as some managers may find themselves taking risks that others might not take, such as making ostensibly risky investments for the common good, or supporting creative thinking to help mission accomplishment. Some management principles that are relatively straightforward for other organizations may be difficult to envision and implement in a nonproliferation organization. Therefore, the goal of this study is to help nonproliferation managers identify management principles that can be implemented in a nonproliferation organization and, in the process, help maximize the value of the organization's products and effectiveness of its mission.

  15. Preferred Provider Organization (PPO) Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preferred Provider Organization (PPO) Plan for non-Medicare retirees is a medical insurance plan with a lower deductible but higher premium than the 2016 High-Deductible Health...

  16. ARM - Measurement - Organic Carbon Concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsOrganic Carbon Concentration ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send...

  17. PROJECT MANGEMENT PLAN EXAMPLES Project Organization Examples

    Office of Environmental Management (EM)

    Organization Examples Example 8 4.0 PROJECT ORGANIZATION Chapter 4.0 describes the principle project organizations, including their responsibilities and relationships. Other organizations, that have an interest in the project, also are described. 4.1 Principal Project Organizations and Responsibilities The management organization for the 324/327 Buildings Stabilization/Deactivation Project represents a partnership between four principal project organizations responsible for the project. The four

  18. Our Organization | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Ames Laboratory is a U.S. Department of Energy research facility operated by Iowa State University. The management of the Laboratory is divided in two main categories, Scientific and Administrative as shown in the organization chart. Below are links to these and other affiliated agencies. Ames Laboratory is not responsible for the content of any offsite pages referenced. The U.S. Department of Energy home page DOE's Office of Science DOE's Chicago Operations Office DOE Pulse

  19. Ambient-pressure organic superconductor

    DOE Patents [OSTI]

    Williams, Jack M. (Downers Grove, IL); Wang, Hsien-Hau (Willowbrook, IL); Beno, Mark A. (Woodridge, IL)

    1986-01-01

    A new class of organic superconductors having the formula (ET).sub.2 MX.sub.2 wherein ET represents bis(ethylenedithio)-tetrathiafulvalene, M is a metal such as Au, Ag, In, Tl, Rb, Pd and the like and X is a halide. The superconductor (ET).sub.2 AuI.sub.2 exhibits a transition temperature of 5 K which is high for organic superconductors.

  20. Helpful Organizations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Affairs » Helpful Organizations Helpful Organizations Council of State Governments Established in 1933, the Council of State Governments is the only multi-branch state association in the nation. It offers leadership training, provides research and information products, and focuses on regional problem-solving in an effort to increase states' efficiency and productivity. It keeps offices across the United States that staff regional associations of legislative and executive officials. Energy

  1. Our Organization and Employees | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization and Employees Our Organization and Employees Our Organization and Employees Our Organization and Employees DOWNLOAD PRINTABLE VERSION Field Organization Charts National Energy Technology Laboratory Stay Connected Fossil Energy on Facebook Fossil Energy on Twitter Sign up for NewsAlerts Fossil Energy RSS Feeds

  2. Business Operations Organization Chart | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Business Operations Organization Chart Business Operations Organization Chart A chart showing how the Office of Energy Efficiency and Renewable Energy's Business Operations office is organized. PDF icon Business Operations org chart More Documents & Publications Office of Energy Efficiency and Renewable Energy Organization Chart Federal Information Technology Acquisition Reform Act (FITARA) Data Resources Office of Management Organization Chart

  3. Dry-thermophilic anaerobic digestion of organic fraction of municipal solid waste: Methane production modeling

    SciTech Connect (OSTI)

    Fdez-Gueelfo, L.A.; Alvarez-Gallego, C.; Sales, D.; Romero Garcia, L.I.

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Methane generation may be modeled by means of modified product generation model of Romero Garcia (1991). Black-Right-Pointing-Pointer Organic matter content and particle size influence the kinetic parameters. Black-Right-Pointing-Pointer Higher organic matter content and lower particle size enhance the biomethanization. - Abstract: The influence of particle size and organic matter content of organic fraction of municipal solid waste (OFMSW) in the overall kinetics of dry (30% total solids) thermophilic (55 Degree-Sign C) anaerobic digestion have been studied in a semi-continuous stirred tank reactor (SSTR). Two types of wastes were used: synthetic OFMSW (average particle size of 1 mm; 0.71 g Volatile Solids/g waste), and OFMSW coming from a composting full scale plant (average particle size of 30 mm; 0.16 g Volatile Solids/g waste). A modification of a widely-validated product-generation kinetic model has been proposed. Results obtained from the modified-model parameterization at steady-state (that include new kinetic parameters as K, Y{sub pMAX} and {theta}{sub MIN}) indicate that the features of the feedstock strongly influence the kinetics of the process. The overall specific growth rate of microorganisms ({mu}{sub max}) with synthetic OFMSW is 43% higher compared to OFMSW coming from a composting full scale plant: 0.238 d{sup -1} (K = 1.391 d{sup -1}; Y{sub pMAX} = 1.167 L CH{sub 4}/gDOC{sub c}; {theta}{sub MIN} = 7.924 days) vs. 0.135 d{sup -1} (K = 1.282 d{sup -1}; Y{sub pMAX} = 1.150 L CH{sub 4}/gDOC{sub c}; {theta}{sub MIN} = 9.997 days) respectively. Finally, it could be emphasized that the validation of proposed modified-model has been performed successfully by means of the simulation of non-steady state data for the different SRTs tested with each waste.

  4. Cycling Endurance of SONOS Non-Volatile Memory Stacks Prepared with Nitrided SiO(2)/Si(100) Intefaces

    SciTech Connect (OSTI)

    Habermehl, S.; Nasby, R.D.; Rightley, M.J.

    1999-01-11

    The effects of nitrided SiO{sub 2}/Si(100) interfaces upon cycling endurance in silicon-oxide-nitride-oxide-silicon (SONOS) non-volatile memory transistors are investigated. Analysis of MOSFET sub-threshold characteristics indicate cycling degradation to be a manifestation of interface state (D{sub it}) generation at the tunnel oxide/silicon interface. After 10{sup 6} write/erase cycles, SONOS film stacks prepared with nitrided tunnel oxides exhibit enhanced cycling endurance with {Delta}D{sub it}=3x10{sup 12} V{sup -1}cm{sup -2}, compared to {Delta}D{sub it}=2x10{sup 13} V{sup -l}cm{sup -2} for non-nitrided tunnel oxides. Additionally, if the capping oxide is formed by steam oxidation, rather than by deposition, SONOS stacks prepared with non-nitrided tunnel oxides exhibit endurance characteristics similar to stacks with nitrided tunnel oxides. From this observation it is concluded that latent nitridation of the tunnel oxidehilicon interface occurs during steam oxide cap formation.

  5. Magnetic Random Access Memory based non-volatile asynchronous Muller cell for ultra-low power autonomous applications

    SciTech Connect (OSTI)

    Di Pendina, G. E-mail: eldar.zianbetov@cea.fr Zianbetov, E. E-mail: eldar.zianbetov@cea.fr; Beigne, E. E-mail: eldar.zianbetov@cea.fr

    2015-05-07

    Micro and nano electronic integrated circuit domain is today mainly driven by the advent of the Internet of Things for which the constraints are strong, especially in terms of power consumption and autonomy, not only during the computing phases but also during the standby or idle phases. In such ultra-low power applications, the circuit has to meet new constraints mainly linked to its changing energetic environment: long idle phases, automatic wake up, data back-up when the circuit is sporadically turned off, and ultra-low voltage power supply operation. Such circuits have to be completely autonomous regarding their unstable environment, while remaining in an optimum energetic configuration. Therefore, we propose in this paper the first MRAM-based non-volatile asynchronous Muller cell. This cell has been simulated and characterized in a very advanced 28?nm CMOS fully depleted silicon-on-insulator technology, presenting good power performance results due to an extremely efficient body biasing control together with ultra-wide supply voltage range from 160?mV up to 920?mV. The leakage current can be reduced to 154?pA thanks to reverse body biasing. We also propose an efficient standard CMOS bulk version of this cell in order to be compatible with different fabrication processes.

  6. Form:Organization | Open Energy Information

    Open Energy Info (EERE)

    Organization Jump to: navigation, search Enter the title of the Organization you would like to add. If the organization page already exists, you will be able to edit it. Add Edit...

  7. Organization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Group is responsible for providing electron beams that produce the desired quantity and quality of photon beams. This group also operates the diagnostic photon beamline, develops...

  8. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford site low-level waste

    SciTech Connect (OSTI)

    Shade, J.W.

    1996-05-03

    Commercially available melter technologies were tested for application to vitrification of Hanford site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW simulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO{sub x} generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented.

  9. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford Site low-level waste

    SciTech Connect (OSTI)

    Whyatt, G.A. [Pacific Northwest National Lab., Richland, WA (United States); Shade, J.W.; Stegen, G.E. [Westinghouse Hanford Co., Richland, WA (United States)

    1996-12-31

    Commercially available melter technologies were tested for application to vitrification of Hanford Site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW stimulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO{sub x} generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented.

  10. Probing Organic Transistors with Infrared Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications...

  11. Clean Technology Sustainable Industries Organization | Open Energy...

    Open Energy Info (EERE)

    Sustainable Industries Organization Jump to: navigation, search Name: Clean Technology & Sustainable Industries Organization Place: Royal Oak, Michigan Zip: 48073 Product: A...

  12. Probing Organic Transistors with Infrared Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood,...

  13. ATHENA surrogate human organ system approaches milestone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liver, heart, lung and kidney. Each organ component is about the size of a smartphone screen, and the whole ATHENA "body" of interconnected organs is designed to fit...

  14. National Renewables Cooperative Organization NRCO | Open Energy...

    Open Energy Info (EERE)

    Renewables Cooperative Organization NRCO Jump to: navigation, search Name: National Renewables Cooperative Organization (NRCO) Place: Carmel, Indiana Zip: 46032 Sector: Renewable...

  15. PI Organization Chart | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Office of Policy and International Affairs Organization Chart Office of International Affairs Organization Chart Microsoft PowerPoint - Nov...

  16. The Bluestone Organization | Open Energy Information

    Open Energy Info (EERE)

    Bluestone Organization Jump to: navigation, search Name: The Bluestone Organization Place: Fresh Meadows, NY Information About Partnership with NREL Partnership with NREL Yes...

  17. Our Organization and Employees | Department of Energy

    Office of Environmental Management (EM)

    Our Organization and Employees Our Organization and Employees PDF icon FE Org Chart Dec 2015.pdf More Documents & Publications Helpful Resources for Open Season 2015 MA-60 Org...

  18. Structural proteomics of minimal organisms: conservation ofprotein...

    Office of Scientific and Technical Information (OSTI)

    of minimal organisms: conservation ofprotein fold usage and evolutionary implications Citation Details In-Document Search Title: Structural proteomics of minimal organisms: ...

  19. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2015-01-06

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOCs) in the gas phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the WRF-Chem regional chemistry transport model, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48 and 63% respectively over the continental US. Dry deposition ofmore » gas-phase SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40 vs. −8% for anthropogenics, and −52 vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas phase (61% for anthropogenics and 76% for biogenics). Results are sensitive to assumptions made in the dry deposition scheme, but gas-phase deposition of SVOCs remains crucial even under conservative estimates. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We consider this a lower bound for the effect of gas-phase SVOC removal on SOA concentrations. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility of SVOCs made in some current modeling systems (H* = H* (CH3COOH); H* = 105 M atm−1; H* = H* (HNO3)) still lead to an overestimation of 35%/25%/10% compared to our best estimate.« less

  20. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2014-05-26

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOC) in the gas-phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the regional chemistry transport model WRF-Chem, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48% and 63% respectively over the continental US Dry deposition of gas-phasemore » SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40% vs. −8% for anthropogenics, −52% vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas-phase (61% for anthropogenics, 76% for biogenics). A number of sensitivity studies shows that this is a robust feature of the modeling system. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility of SVOCs made in some current modeling systems (H* = 105 M atm−1; H* = H* (HNO3)) still lead to an overestimation of 25% / 10% compared to our best estimate. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We consider this a lower bound for the effect of gas-phase SVOC removal on SOA concentrations.« less

  1. Method of doping organic semiconductors

    DOE Patents [OSTI]

    Kloc, Christian Leo (Constance, DE); Ramirez, Arthur Penn (Summit, NJ); So, Woo-Young (New Providence, NJ)

    2012-02-28

    A method includes the steps of forming a contiguous semiconducting region and heating the region. The semiconducting region includes polyaromatic molecules. The heating raises the semiconducting region to a temperature above room temperature. The heating is performed in the presence of a dopant gas and the absence of light to form a doped organic semiconducting region.

  2. Process-scale modeling of elevated wintertime ozone in Wyoming.

    SciTech Connect (OSTI)

    Kotamarthi, V. R.; Holdridge, D. J.; Environmental Science Division

    2007-12-31

    Measurements of meteorological variables and trace gas concentrations, provided by the Wyoming Department of Environmental Quality for Daniel, Jonah, and Boulder Counties in the state of Wyoming, were analyzed for this project. The data indicate that highest ozone concentrations were observed at temperatures of -10 C to 0 C, at low wind speeds of about 5 mph. The median values for nitrogen oxides (NOx) during these episodes ranged between 10 ppbv and 20 ppbv (parts per billion by volume). Measurements of volatile organic compounds (VOCs) during these periods were insufficient for quantitative analysis. The few available VOCs measurements indicated unusually high levels of alkanes and aromatics and low levels of alkenes. In addition, the column ozone concentration during one of the high-ozone episodes was low, on the order of 250 DU (Dobson unit) as compared to a normal column ozone concentration of approximately 300-325 DU during spring for this region. Analysis of this observation was outside the scope of this project. The data analysis reported here was used to establish criteria for making a large number of sensitivity calculations through use of a box photochemical model. Two different VOCs lumping schemes, RACM and SAPRC-98, were used for the calculations. Calculations based on this data analysis indicated that the ozone mixing ratios are sensitive to (a) surface albedo, (b) column ozone, (c) NOx mixing ratios, and (d) available terminal olefins. The RACM model showed a large response to an increase in lumped species containing propane that was not reproduced by the SAPRC scheme, which models propane as a nearly independent species. The rest of the VOCs produced similar changes in ozone in both schemes. In general, if one assumes that measured VOCs are fairly representative of the conditions at these locations, sufficient precursors might be available to produce ozone in the range of 60-80 ppbv under the conditions modeled.

  3. Development of a new generation of waste form for entrapment and immobilization of highly volatile and soluble radionuclides.

    SciTech Connect (OSTI)

    Rodriguez, Mark Andrew; Bencoe, Denise Nora; Brinker, C. Jeffrey; Murphy, Andrew Wilson; Holt, Kathleen Caroline; Turnham, Rigney; Kruichak, Jessica Nicole; Tellez, Hernesto; Miller, Andy; Xiong, Yongliang; Pohl, Phillip Isabio; Ockwig, Nathan W.; Wang, Yifeng; Gao, Huizhen

    2010-09-01

    The United States is now re-assessing its nuclear waste disposal policy and re-evaluating the option of moving away from the current once-through open fuel cycle to a closed fuel cycle. In a closed fuel cycle, used fuels will be reprocessed and useful components such as uranium or transuranics will be recovered for reuse. During this process, a variety of waste streams will be generated. Immobilizing these waste streams into appropriate waste forms for either interim storage or long-term disposal is technically challenging. Highly volatile or soluble radionuclides such as iodine ({sup 129}I) and technetium ({sup 99}Tc) are particularly problematic, because both have long half-lives and can exist as gaseous or anionic species that are highly soluble and poorly sorbed by natural materials. Under the support of Sandia National Laboratories (SNL) Laboratory-Directed Research & Development (LDRD), we have developed a suite of inorganic nanocomposite materials (SNL-NCP) that can effectively entrap various radionuclides, especially for {sup 129}I and {sup 99}Tc. In particular, these materials have high sorption capabilities for iodine gas. After the sorption of radionuclides, these materials can be directly converted into nanostructured waste forms. This new generation of waste forms incorporates radionuclides as nano-scale inclusions in a host matrix and thus effectively relaxes the constraint of crystal structure on waste loadings. Therefore, the new waste forms have an unprecedented flexibility to accommodate a wide range of radionuclides with high waste loadings and low leaching rates. Specifically, we have developed a general route for synthesizing nanoporous metal oxides from inexpensive inorganic precursors. More than 300 materials have been synthesized and characterized with x-ray diffraction (XRD), BET surface area measurements, and transmission electron microscope (TEM). The sorption capabilities of the synthesized materials have been quantified by using stable isotopes I and Re as analogs to {sup 129}I and {sup 99}Tc. The results have confirmed our original finding that nanoporous Al oxide and its derivatives have high I sorption capabilities due to the combined effects of surface chemistry and nanopore confinement. We have developed a suite of techniques for the fixation of radionuclides in metal oxide nanopores. The key to this fixation is to chemically convert a target radionuclide into a less volatile or soluble form. We have developed a technique to convert a radionuclide-loaded nanoporous material into a durable glass-ceramic waste form through calcination. We have shown that mixing a radionuclide-loaded getter material with a Na-silicate solution can effectively seal the nanopores in the material, thus enhancing radionuclide retention during waste form formation. Our leaching tests have demonstrated the existence of an optimal vitrification temperature for the enhancement of waste form durability. Our work also indicates that silver may not be needed for I immobilization and encapsulation.

  4. Differences in volatile methyl siloxane (VMS) profiles in biogas from landfills and anaerobic digesters and energetics of VMS transformations

    SciTech Connect (OSTI)

    Tansel, Berrin Surita, Sharon C.

    2014-11-15

    Highlights: In the digester gas, D4 and D5 comprised the 62% and 27% if siloxanes, respectively. In landfill gas, the bulk of siloxanes were TMSOH (58%) followed by D4 (17%). Methane utilization may be a possible mechanism for TMSOH formation in the landfills. The geometric configurations of D4 and D5 molecules make them very stable. - Abstract: The objectives of this study were to compare the types and levels of volatile methyl siloxanes (VMS) present in biogas generated in the anaerobic digesters and landfills, evaluate the energetics of siloxane transformations under anaerobic conditions, compare the conditions in anaerobic digesters and municipal solid waste (MSW) landfills which result in differences in siloxane compositions. Biogas samples were collected at the South District Wastewater Treatment Plant and South Dade Landfill in Miami, Florida. In the digester gas, D4 and D5 comprised the bulk of total siloxanes (62% and 27%, respectively) whereas in the landfill gas, the bulk of siloxanes were trimethylsilanol (TMSOH) (58%) followed by D4 (17%). Presence of high levels of TMSOH in the landfill gas indicates that methane utilization may be a possible reaction mechanism for TMSOH formation. The free energy change for transformation of D5 and D4 to TMSOH either by hydrogen or methane utilization are thermodynamically favorable. Either hydrogen or methane should be present at relatively high concentrations for TMSOH formation which explains the high levels present in the landfill gas. The high bond energy and bond distance of the SiO bond, in view of the atomic sizes of Si and O atoms, indicate that Si atoms can provide a barrier, making it difficult to break the SiO bonds especially for molecules with specific geometric configurations such as D4 and D5 where oxygen atoms are positioned inside the frame formed by the large Si atoms which are surrounded by the methyl groups.

  5. Quantifying the value that energy efficiency and renewable energy provide as a hedge against volatile natural gas prices

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Bachrach, Devra; Golove, William

    2002-05-15

    Advocates of energy efficiency and renewable energy have long argued that such technologies can mitigate fuel price risk within a resource portfolio. Such arguments--made with renewed vigor in the wake of unprecedented natural gas price volatility during the winter of 2000/2001--have mostly been qualitative in nature, however, with few attempts to actually quantify the price stability benefit that these sources provide. In evaluating this benefit, it is important to recognize that alternative price hedging instruments are available--in particular, gas-based financial derivatives (futures and swaps) and physical, fixed-price gas contracts. Whether energy efficiency and renewable energy can provide price stability at lower cost than these alternative means is therefore a key question for resource acquisition planners. In this paper we evaluate the cost of hedging gas price risk through financial hedging instruments. To do this, we compare the price of a 10-year natural gas swap (i.e., what it costs to lock in prices over the next 10 years) to a 10-year natural gas price forecast (i.e., what the market is expecting spot natural gas prices to be over the next 10 years). We find that over the past two years natural gas users have had to pay a premium as high as $0.76/mmBtu (0.53/242/kWh at an aggressive 7,000 Btu/kWh heat rate) over expected spot prices to lock in natural gas prices for the next 10 years. This incremental cost to hedge gas price risk exposure is potentially large enough - particularly if incorporated by policymakers and regulators into decision-making practices - to tip the scales away from new investments in variable-price, natural gas-fired generation and in favor of fixed-price investments in energy efficiency and renewable energy.

  6. First report on non-thermal plasma reactor scaling criteria and optimization models

    SciTech Connect (OSTI)

    Rosocha, L.A.; Korzekwa, R.A.

    1998-01-13

    The purpose of SERDP project CP-1038 is to evaluate and develop non-thermal plasma (NTP) reactor technology for Department of Defense (DoD) air emissions control applications. The primary focus is on oxides of nitrogen (NO{sub x}) and a secondary focus on hazardous air pollutants (HAPs), especially volatile organic compounds (VOCs). Example NO{sub x} sources are jet engine test cells (JETCs) and diesel engine powered electrical generators. Example VOCs are organic solvents used in painting, paint stripping, and parts cleaning. To design and build NTP reactors that are optimized for particular DoD applications, one must understand the basic decomposition chemistry of the target compound(s) and how the decomposition of a particular chemical species depends on the air emissions stream parameters and the reactor operating parameters. This report is intended to serve as an overview of the subject of reactor scaling and optimization and will discuss the basic decomposition chemistry of nitric oxide (NO) and two representative VOCs, trichloroethylene and carbon tetrachloride, and the connection between the basic plasma chemistry, the target species properties, and the reactor operating parameters (in particular, the operating plasma energy density). System architecture, that is how NTP reactors can be combined or ganged to achieve higher capacity, will also be briefly discussed.

  7. Technology and Commercialization Organization Chart | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Technology and Commercialization Organization Chart PDF icon tdc_org_chart

  8. HC Organization Chart | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HC Organization Chart HC Organization Chart PDF version of the HC Organizational chart PDF icon 10-20-13 HC_Org_Chart.pdf More Documents & Publications Environmental Justice and Tribal Consultation Training OCIO Organization Chart (printable version) DOE Organization Chart - October 22, 2012

  9. HC Organization Chart | Department of Energy

    Energy Savers [EERE]

    HC Organization Chart HC Organization Chart PDF version of the HC Organizational chart PDF icon 10-20-13 HC_Org_Chart.pdf More Documents & Publications Environmental Justice and Tribal Consultation Training OCIO Organization Chart (printable version) DOE Organization Chart - October 22, 2012

  10. FY 2010 Summary Table by Organization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Current Congressional Approp. Approp. Recovery Request % Discretionary Summary By Organization National Security Weapons......

  11. AU Organization Chart | Department of Energy

    Energy Savers [EERE]

    AU Organization Chart AU Organization Chart AU Organization Chart: December 22, 2015 PDF icon AU Organization Chart: December 22, 2015 More Documents & Publications FTCP Senior Technical Safety Manager (STSM) Status Report USW Health Safety and Environment Conference - HSS Workshop Response to several FOIA requests - Renewable Energy.

  12. US Nuclear Regulatory Commission functional organization charts

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This document provides functional organization charts for all NRC Offices and Regions, and their components.

  13. US Nuclear Regulatory Commission functional organization charts

    SciTech Connect (OSTI)

    Not Available

    1986-11-30

    Functional organization charts for the NRC Commission Offices, Divisions, and Branches are presented.

  14. FY 2015 Summary Control Table by Organization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Summary Control Table by Organization (dollars in thousands - OMB Scoring) Summary Control by Organization Page 1 FY 2015 Congressional Request FY 2013 FY 2014 FY 2014 FY 2014 FY 2015 Current Enacted Adjustments Current Congressional Approp. Approp. Approp. Request Discretionary Summary By Organization Department Of Energy By Organization National Nuclear Security Administration Weapons Activities............................................................................. 6,966,855 7,781,000

  15. FY 2015 Statistical Table by Organization

    Energy Savers [EERE]

    Approp. Approp. Request Discretionary Summary By Organization National Nuclear Security Administration Weapons Activities......

  16. Community Organizing and Outreach | Department of Energy

    Office of Environmental Management (EM)

    Community Organizing and Outreach Community Organizing and Outreach Better Buildings Residential Network Peer Exchange Call Series: Community Organizing and Outreach, call slides and discussion summary, April 23, 2015. PDF icon Call Slides and Discussion Summary More Documents & Publications Outreach to Faith--Based Organizations Staged Upgrades - Homeowner-focused Strategies for Encouraging Energy Upgrades over Time Outreach to Multifamily Landlords and Tenants

  17. Megahertz organic/polymer diodes

    DOE Patents [OSTI]

    Katz, Howard Edan; Sun, Jia; Pal, Nath Bhola

    2012-12-11

    Featured is an organic/polymer diode having a first layer composed essentially of one of an organic semiconductor material or a polymeric semiconductor material and a second layer formed on the first layer and being electrically coupled to the first layer such that current flows through the layers in one direction when a voltage is applied in one direction. The second layer is essentially composed of a material whose characteristics and properties are such that when formed on the first layer, the diode is capable of high frequency rectifications on the order of megahertz rectifications such as for example rectifications at one of above 100KHz, 500KhZ, IMHz, or 10 MHz. In further embodiments, the layers are arranged so as to be exposed to atmosphere.

  18. Blackfeet Nation - Energy Organization Development

    Office of Environmental Management (EM)

    Organization Development First Steps to Renewable Energy Grant Awarded by Department of Energy Presented by Jeri Lawrence Blackfeet Renewable Energy Director Introduction Introduction The Blackfeet Reservation is located in Glacier and The Blackfeet Reservation is located in Glacier and Pondera Counties of Montana. Pondera Counties of Montana. Northwestern part of the state at the eastern base Northwestern part of the state at the eastern base of the Rocky Mountains of the Rocky Mountains 1,

  19. Catalysts for the hydrodenitrogenation of organic materials and process for the preparation of the catalysts

    DOE Patents [OSTI]

    Laine, R.M.; Hirschon, A.S.; Wilson, R.B. Jr.

    1987-12-29

    A process is described for the preparation of a multimetallic catalyst for the hydrodenitrogenation of an organic feedstock, which process comprises: (a) forming a precatalyst itself comprising: (1) a first metal compound selected from compounds of nickel, cobalt or mixtures thereof; (2) a second metal compound selected from compounds of chromium, molybdenum, tungsten, or mixtures thereof; and (3) an inorganic support; (b) heating the precatalyst of step (a) with a source of sulfide in a first non-oxidizing gas at a temperature and for a time effective to presulfide the precatalyst; (c) adding in a second non-oxidizing gas to the sulfided precatalyst of step (b) an organometallic transition metal moiety selected from compounds of iridium, rhodium, iron, ruthenium, tungsten or mixtures thereof for a time and at a temperature effective to chemically combine the metal components; and (d) optionally heating the chemically combined catalyst of step (b) in vacuum at a temperature and for a time effective to remove residual volatile organic materials. 12 figs.

  20. Archaeal community composition affects the function of anaerobic co-digesters in response to organic overload

    SciTech Connect (OSTI)

    Lerm, S.; Kleyboecker, A.; Miethling-Graff, R.; Alawi, M.; Kasina, M.; Liebrich, M.; Wuerdemann, H.

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Two types of methanogens are necessary to respond successfully to perturbation. Black-Right-Pointing-Pointer Diversity of methanogens correlates with the VFA concentration and methane yield. Black-Right-Pointing-Pointer Aggregates indicate tight spatial relationship between minerals and microorganisms. - Abstract: Microbial community diversity in two thermophilic laboratory-scale and three full-scale anaerobic co-digesters was analysed by genetic profiling based on PCR-amplified partial 16S rRNA genes. In parallel operated laboratory reactors a stepwise increase of the organic loading rate (OLR) resulted in a decrease of methane production and an accumulation of volatile fatty acids (VFAs). However, almost threefold different OLRs were necessary to inhibit the gas production in the reactors. During stable reactor performance, no significant differences in the bacterial community structures were detected, except for in the archaeal communities. Sequencing of archaeal PCR products revealed a dominance of the acetoclastic methanogen Methanosarcina thermophila, while hydrogenotrophic methanogens were of minor importance and differed additionally in their abundance between reactors. As a consequence of the perturbation, changes in bacterial and archaeal populations were observed. After organic overload, hydrogenotrophic methanogens (Methanospirillum hungatei and Methanoculleus receptaculi) became more dominant, especially in the reactor attributed by a higher OLR capacity. In addition, aggregates composed of mineral and organic layers formed during organic overload and indicated tight spatial relationships between minerals and microbial processes that may support de-acidification processes in over-acidified sludge. Comparative analyses of mesophilic stationary phase full-scale reactors additionally indicated a correlation between the diversity of methanogens and the VFA concentration combined with the methane yield. This study demonstrates that the coexistence of two types of methanogens, i.e. hydrogenotrophic and acetoclastic methanogens is necessary to respond successfully to perturbation and leads to stable process performance.

  1. Preparation of hydrophobic organic aeorgels

    DOE Patents [OSTI]

    Baumann, Theodore F.; Satcher, Jr., Joe H.; Gash, Alexander E.

    2004-10-19

    Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems. These hydrophobic organics aerogels have numerous application potentials in the field of material absorbers and water-proof insulation.

  2. Preparation of hydrophobic organic aeorgels

    DOE Patents [OSTI]

    Baumann, Theodore F.; Satcher, Jr., Joe H.; Gash, Alexander E.

    2007-11-06

    Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems. These hydrophobic organics aerogels have numerous application potentials in the field of material absorbers and water-proof insulation.

  3. The Statistical Evolution of Multiple Generations of Oxidation Products in the Photochemical Aging of Chemically Reduced Organic Aerosol

    SciTech Connect (OSTI)

    Wilson, Kevin R.; Smith, Jared D.; Kessler, Sean; Kroll, Jesse H.

    2011-10-03

    The heterogeneous reaction of hydroxyl radicals (OH) with squalane and bis(2-ethylhexyl) sebacate (BES) particles are used as model systems to examine how distributions of reactionproducts evolve during the oxidation of chemically reduced organic aerosol. A kinetic model of multigenerational chemistry, which is compared to previously measured (squalane) and new(BES) experimental data, reveals that it is the statistical mixtures of different generations of oxidation products that control the average particle mass and elemental composition during thereaction. The model suggests that more highly oxidized reaction products, although initially formed with low probability, play a large role in the production of gas phase reaction products.In general, these results highlight the importance of considering atmospheric oxidation as a statistical process, further suggesting that the underlying distribution of molecules could playimportant roles in aerosol formation as well as in the evolution of key physicochemical properties such as volatility and hygroscopicity.

  4. What Is Price Volatility

    Gasoline and Diesel Fuel Update (EIA)

    heating-degree-days than normal. Also relevant was that the prices of fuel oil and other alternative fuels were relatively high during this period. For example, the average...

  5. Oil Price Volatility

    U.S. Energy Information Administration (EIA) Indexed Site

    ... rale Cross rale Cross - - Asset Asset Research, Multi Research, Multi - - Asset ... petroleum futures markets 3. 3. Methodology Methodology Count number of speculators ...

  6. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, S.; Kim, S. -Y.; Lee, M.; Shim, H.; Wolfe, G. M.; Guenther, A. B.; He, A.; Hong, Y.; Han, J.

    2015-04-29

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Guangzhou, and Beijing are surrounded by densely forested areas, and recent research has consistently demonstrated the importance of biogenic volatile organic compounds (VOCs) from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical, undermine our ability to assess regional photochemical air pollution problems. We present an observational data set of CO, NOx, SO2, ozone, HONO,more » and VOCs (anthropogenic and biogenic) from Taehwa research forest (TRF) near the Seoul metropolitan area in early June 2012. The data show that TRF is influenced both by aged pollution and fresh biogenic volatile organic compound emissions. With the data set, we diagnose HOx (OH, HO2, and RO2) distributions calculated using the University of Washington chemical box model (UWCM v2.1) with near-explicit VOC oxidation mechanisms from MCM v3.2 (Master Chemical Mechanism). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that (1) different model simulation scenarios cause systematic differences in HOx distributions, especially OH levels (up to 2.5 times), and (2) radical destruction (HO2 + HO2 or HO2 + RO2) could be more efficient than radical recycling (RO2 + NO), especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozone–VOC–NOx sensitivity and VOC oxidation product formation rates. Overall, the NOx limited regime is assessed except for the morning hours (8 a.m. to 12 p.m. local standard time), but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with oxygenated VOCs (OVOCs) production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher-than-expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.« less

  7. Absorption of ethanol, acetone, benzene and 1,2-dichloroethane through human skin in vitro: a test of diffusion model predictions

    SciTech Connect (OSTI)

    Gajjar, Rachna M.; Kasting, Gerald B.

    2014-11-15

    The overall goal of this research was to further develop and improve an existing skin diffusion model by experimentally confirming the predicted absorption rates of topically-applied volatile organic compounds (VOCs) based on their physicochemical properties, the skin surface temperature, and the wind velocity. In vitro human skin permeation of two hydrophilic solvents (acetone and ethanol) and two lipophilic solvents (benzene and 1,2-dichloroethane) was studied in Franz cells placed in a fume hood. Four doses of each {sup 14}C-radiolabed compound were tested 5, 10, 20, and 40 ?L cm{sup ?2}, corresponding to specific doses ranging in mass from 5.0 to 63 mg cm{sup ?2}. The maximum percentage of radiolabel absorbed into the receptor solutions for all test conditions was 0.3%. Although the absolute absorption of each solvent increased with dose, percentage absorption decreased. This decrease was consistent with the concept of a stratum corneum deposition region, which traps small amounts of solvent in the upper skin layers, decreasing the evaporation rate. The diffusion model satisfactorily described the cumulative absorption of ethanol; however, values for the other VOCs were underpredicted in a manner related to their ability to disrupt or solubilize skin lipids. In order to more closely describe the permeation data, significant increases in the stratum corneum/water partition coefficients, K{sub sc}, and modest changes to the diffusion coefficients, D{sub sc}, were required. The analysis provided strong evidence for both skin swelling and barrier disruption by VOCs, even by the minute amounts absorbed under these in vitro test conditions. - Highlights: Human skin absorption of small doses of VOCs was measured in vitro in a fume hood. The VOCs tested were ethanol, acetone, benzene and 1,2-dichloroethane. Fraction of dose absorbed for all compounds at all doses tested was less than 0.3%. The more aggressive VOCs absorbed at higher levels than diffusion model predictions. We conclude that even small exposures to VOCs temporarily alter skin permeability.

  8. Custom Organic Electronics Out of the Printer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Custom Organic Electronics Out of the Printer Custom Organic Electronics Out of the Printer Print Thursday, 03 December 2015 12:14 They are thin, light-weight, flexible, and can be...

  9. Submitting Organization Hongyou Fan Sandia National Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... In order to study the siloxane condensation effect on the formation of an ordered ... by organic solvent evaporation is an entropy-driven pro- cess in which NCs organize in ...

  10. Organization-About-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Mission Statement (PDF) Organization Contact Us organization This webpage is provided for legacy archive purposes only, as of 30 April 2015. The day to day operations of the...

  11. Project Management Coordination Office Organization Chart

    Broader source: Energy.gov [DOE]

    Project Management Coordination Office Organization Chart, U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy.

  12. CNM Organization Chart | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Chart Organizational structure of Argonnne's Center for Nanoscale Materials PDF icon CNMOrg Chart_March2016

  13. Probing Organic Transistors with Infrared Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also

  14. Organic Photovoltaics Research | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photovoltaics » Organic Photovoltaics Research Organic Photovoltaics Research Graphic showing the seven layers of an organic PV cell: electrode, donor, acceptor, active layer, PEDOT:PSS, transparent conductive oxide, and glass. DOE funds research and development projects related to organic photovoltaics (OPV) due to the unique benefits of the technology. Below is a list of the projects, summary of the benefits, and discussion on the production and manufacturing of this solar technology.

  15. Method of stripping metals from organic solvents

    DOE Patents [OSTI]

    Todd, Terry A.; Law, Jack D.; Herbst, R. Scott; Romanovskiy, Valeriy N.; Smirnov, Igor V.; Babain, Vasily A.; Esimantovski, Vyatcheslav M.

    2009-02-24

    A new method to strip metals from organic solvents in a manner that allows for the recycle of the stripping agent. The method utilizes carbonate solutions of organic amines with complexants, in low concentrations, to strip metals from organic solvents. The method allows for the distillation and reuse of organic amines. The concentrated metal/complexant fraction from distillation is more amenable to immobilization than solutions resulting from current practice.

  16. Hanford Employee Recreation Organization - HERO - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs HERO Home All HDC Discounts (PDF) For Current and Retired Employees Only Contact Us Hanford Employee Recreation Organization - HERO Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size Travel The Hanford Employee Recreation Organization (HERO) is a nonprofit organization maintained for the employees of the following companies: Mission Support Alliance (MSA), CH2M Hill Plateau

  17. FAA Air Traffic Organization Safety Management

    Broader source: Energy.gov [DOE]

    Presenter: Mark DeNicuolo, Manager Performance and Analyses Air Traffic Organization Safety and Technical Training Federal Aviation Administration

  18. Improved Organic Photovoltaics - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organic Photovoltaics B4 Materials For Organic Semiconductor Applications, Including Molecular Electronics And Organic Photovoltaics University of Colorado Contact CU About This Technology Publications: PDF Document Publication CU2768B (Organic PV) Marketing Summary_1.pdf (146 KB) Technology Marketing Summary Traditionally, photosensitive optoelectronic devices such as solar cells have been constructed of a number of inorganic semiconductors. Purity and crystalline grain size are a large

  19. US Nuclear Regulatory Commission functional organization charts

    SciTech Connect (OSTI)

    Not Available

    1990-08-15

    Functional organization charts for the US Nuclear Regulatory Commission offices, divisions, and branches are presented in this document.

  20. US Nuclear Regulatory Commission functional organization charts

    SciTech Connect (OSTI)

    Not Available

    1990-04-01

    Functional organization charts for the US Nuclear Regulatory Commission offices, divisions, and branches are presented in this document.

  1. Leveraging Partnerships with Faith-Based Organizations

    Broader source: Energy.gov [DOE]

    This webinar, presented May 17, 2011, covered two projects between faith-based organizations and energy efficiency programs.

  2. OSDBU Organization Chart | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    About Us » OSDBU Organization Chart OSDBU Organization Chart The organization chart for the Office of Small and Disadvantaged Business Utilization is being updated and should be available soon. More Documents & Publications Guidance of the Department of Energy Subcontracting Program SubcontractingGuidelines.doc&#0; EIS-0433-S1: Notice of Intent to Prepare a Supplemental Environmental Impact Statement News & Blog Events Organization Chart

  3. Magnetoelectroluminescence of organic heterostructures: Analytical theory

    Office of Scientific and Technical Information (OSTI)

    and spectrally resolved measurements (Journal Article) | DOE PAGES Magnetoelectroluminescence of organic heterostructures: Analytical theory and spectrally resolved measurements « Prev Next » Title: Magnetoelectroluminescence of organic heterostructures: Analytical theory and spectrally resolved measurements The effect of a magnetic field on the electroluminescence of organic light emitting devices originates from the hyperfine interaction between the electron/hole polarons and the

  4. Magnetoelectroluminescence of organic heterostructures: Analytical theory

    Office of Scientific and Technical Information (OSTI)

    and spectrally resolved measurements (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Magnetoelectroluminescence of organic heterostructures: Analytical theory and spectrally resolved measurements Citation Details In-Document Search Title: Magnetoelectroluminescence of organic heterostructures: Analytical theory and spectrally resolved measurements The effect of a magnetic field on the electroluminescence of organic light emitting devices originates from

  5. Fermilab | Tevatron | Tevatron Symposium | Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee: Jeffrey Appel, Fermilab Giorgio Bellettini, INFN and University of Pisa Peter Cooper, Fermilab Roger Dixon, Fermilab Young-Kee Kim, Fermilab Jacobo Konigsberg, University of Florida, Co-Chair Stefan Soldner-Rembold, University of Manchester, Co-Chair Lisa Whitehead, University of Houston Darien Wood, Northeastern University Local Organizers: Marilyn Paul Cynthia Sazama Suzanne Weber Katie Yurkewicz

  6. WIP Organization Chart | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WIP Organization Chart WIP Organization Chart This document contains the organizational chart for WIP. PDF icon WIP Organization Chart More Documents & Publications 2014 Annual Workforce Analysis and Staffing Plan Report - Carlsbad Field Office 2011 Annual Workforce Analysis and Staffing Plan Report - Carlsbad Field Office Voluntary Protection Program Onsite Review, Oak Ridge Associated Universities Oak Ridge Institute for Science and Education - April 2008

  7. Reactivity of liquid and semisolid secondary organic carbon with chloride and nitrate in atmospheric aerosols

    SciTech Connect (OSTI)

    Wang, Bingbing; O'Brien, Rachel E.; Kelly, Stephen T.; Shilling, John E.; Moffet, Ryan C.; Gilles, Mary K.; Laskin, Alexander

    2015-05-14

    Constituents of secondary organic carbon (SOC) in atmospheric aerosols are often mixed with inorganic components and compose a significant mass fraction of fine particulate matter in the atmosphere. Interactions between SOC and other condensed-phase species are not well understood. Here, we investigate the reactions of liquid-like and semi-solid SOC from ozonolysis of limonene (LSOC) and ?-pinene (PSOC) with NaCl using a set of complementary micro-spectroscopic analyses. These reactions result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions attributed to acid displacement by SOC acidic components are driven by the high volatility of HCl. Similar reactions can take place in SOC/NaNO? particles. The results show that an increase in SOC mass fraction in the internally mixed SOC/NaCl particles leads to higher chloride depletion. Glass transition temperatures and viscosity of PSOC were estimated for atmospherically relevant conditions. Data show that the reaction extent depends on SOC composition, particle phase state and viscosity, mixing state, temperature, relative humidity (RH), and reaction time. LSOC shows slightly higher potential to deplete chloride than PSOC. Higher particle viscosity at low temperatures and RH can hinder these acid displacement reactions. Formation of organic salts from these overlooked reactions can alter particle physiochemical properties and may affect their reactivity and ability to act as cloud condensation and ice nuclei. The release and potential recycling of HCl and HNO? from reacted aerosol particles may have important implications for atmospheric chemistry.

  8. METHODOLOGY FOR THE NUMBER OF FILTERS NEEDED IN A WASTE BOX

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2007-05-17

    Waste in large waste boxes can generate volatile organic compounds (VOCs) and hydrogen. These waste boxes may or may not have flow paths out of them (although it is believed that most do). These boxes will be retrieved, sampled, and then coated with polyurea. After coating, filters will be installed in the box to keep the concentration of VOCs and hydrogen acceptably low. The MDSA requires that a vent path must be protected during application of the polyurea coating. If the box has been sampled then it is vented and the vent path must be protected. This report provides a model in which the user inputs the free volume of the waste box, sample concentration (ppm of total VOC or volume fraction hydrogen) along with the number of filters to be placed into the waste box lid. Using this information, the model provides an estimate of concentration vs. time or the number of filters needed to reduce the concentration by a specified fraction. If the equations from this report are placed into spreadsheets which are then used to demonstrate TSR compliance, the spreadsheets must come under the Software QA Plan for such documents. Chapters 2 and 3 present the theory. Chapter 4 presents the method with examples of its use found in Chapter 5. Chapter 6 provides the basis far the use of 1,000 ppm as the concentration below which the method is valid under any condition.

  9. New Air Cleaning Strategies for Reduced Commercial Building Ventilation Energy

    SciTech Connect (OSTI)

    Sidheswaran, Meera; Destaillats, Hugo; Sullivan, Douglas P.; Fisk, William J.

    2010-10-27

    Approximately ten percent of the energy consumed in U.S. commercial buildings is used by HVAC systems to condition outdoor ventilation air. Reducing ventilation rates would be a simple and broadly-applicable energy retrofit option, if practical counter measures were available that maintained acceptable concentrations of indoor-generated air pollutants. The two general categories of countermeasures are: 1) indoor pollutant source control, and 2) air cleaning. Although pollutant source control should be used to the degree possible, source control is complicated by the large number and changing nature of indoor pollutant sources. Particle air cleaning is already routinely applied in commercial buildings. Previous calculations indicate that particle filtration consumes only 10percent to 25percent of the energy that would otherwise be required to achieve an equivalent amount of particle removal with ventilation. If cost-effective air cleaning technologies for volatile organic compounds (VOCs) were also available, outdoor air ventilation rates could be reduced substantially and broadly in the commercial building stock to save energy. The research carried out in this project focuses on developing novel VOC air cleaning technologies needed to enable energy-saving reductions in ventilation rates. The minimum required VOC removal efficiency to counteract a 50percent reduction in ventilation rate for air cleaning systems installed in the HVAC supply airstream is modest (generally 20percent or less).

  10. Simultaneous Energy Savings and IEQ Improvements in Relocatable Classrooms

    SciTech Connect (OSTI)

    Apte, Michael G.; Dibartolomeo, Dennis; Hotchi, Toshi; Hodgson, Alfred T.; Lee, Seung-Min; Liff, Shawna M.; Rainer, Leo I.; Shendell, Derek G.; Sullivan, Doug P.; Fisk, William J.

    2003-05-22

    Relocatable classrooms (RCs) are commonly used by school districts with changing demographics and enrollment sizes. We designed and constructed four energy-efficient RCs for this study to demonstrate technologies with the potential to simultaneously improve energy efficiency and indoor environmental quality (IEQ). Two were installed at each of two school districts, and energy use and IEQ parameters were monitored during occupancy. Two RCs (one per school) were finished with materials selected for reduced emissions of toxic and odorous volatile organic compounds (VOCs). Each had two HVAC systems, operated on alternate weeks, consisting of a standard heat-pump system and an indirect-direct evaporative cooling (IDEC) system with gas-fired hydronic heating. The IDEC system provides continuous outside air ventilation at {sup 3}15 CFM (7.5 L s-1) person-1, efficient particle filtration while using significantly less energy for cooling. School year long measurements included: carbon dioxide (CO2), particles, VOCs, temperature, humidity, thermal comfort, noise, meteorology, and energy use. IEQ monitoring results indicate that important ventilation-relevant indoor CO2 and health-relevant VOC concentration reductions were achieved while average cooling and heating energy costs were simultaneously reduced by 50 percent and 30 percent, respectively.

  11. Recovery and reuse of MEK from paint stripping operation emissions using specialized adsorbents

    SciTech Connect (OSTI)

    Blystone, P.G.; Goltz, H.R.; Springer, J. Jr.

    1994-12-31

    The reduction of volatile organic compound (VOC) emissions is a significant goal of the 1990 Clean Air Act. Industrial operations relating to surface preparation, surface coating and paint striping operations constitute one of the largest industrial sources of VOC emissions. This paper describes a new emission control system offered by Purus, Inc. which captures and recovers VOCs from paint stripping operations. The system is based on an on-site adsorption-desorption process which utilizes a specialized polymeric resin adsorbent. Adsorbent beds are regenerated through a computer controlled pressure-temperature swing process (PTSA). The adsorbent resin offers significant operational advantages over conventional activated carbon adsorbents with respect to treating air laden with methyl ethyl ketone (MEK) vapors. Treatment of MEK with activated carbon can be problematic due to reactivity (degradation) and high heats of adsorption of ketones with carbon. The Purus process was successfully demonstrated at Tinker Air Force Base in or under the EPA`s Waste Reduction Evaluation at Federal Sites program. MEK emissions from a paint stripping booth vent were controlled at greater than 95% reduction levels. The recovered solvent was returned to depainting process and reused with no loss in paint stripping efficiency.

  12. Implementing Strategies for Drying and Pressing Wood Without Emissions Controls

    SciTech Connect (OSTI)

    Sujit Banerjee; Terrance Conners

    2007-09-07

    Drying and pressing wood for the manufacture of lumber, particleboard, oriented strand board (OSB), veneer and medium density fiberboard (MDF) release volatile organic compounds (VOCs) into the atmosphere. These emissions require control equipment that are capital-intensive and consume significant quantities of natural gas and electricity. The objective of our work was to understand the mechanisms through which volatile organic compounds are generated and released and to develop simple control strategies. Of the several strategies developed, two have been implemented for OSB manufacture over the course of this study. First, it was found that increasing final wood moisture by about 2-4 percentage points reduced the dryer emissions of hazardous air pollutants by over 70%. As wood dries, the escaping water evaporatively cools the wood. This cooling tapers off wood when the wood is nearly dry and the wood temperature rises. Thermal breakdown of the wood tissue occurs and VOCs are released. Raising the final wood moisture by only a few percentage points minimizes the temperature rise and reduces emissions. Evaporative cooling also impacts has implications for VOC release from wood fines. Flaking wood for OSB manufacture inevitable generates fines. Fines dry out rapidly because of their high surface area and evaporative cooling is lost more rapidly than for flakes. As a result, fines emit a disproportionate quantity of VOCs. Fines can be reduced in two ways: through screening of the green furnish and through reducing their generation during flaking. The second approach is preferable because it also increased wood yield. A procedure to do this by matching the sharpness angle of the flaker knife to the ambient temperature was also developed. Other findings of practical interests are as follows: Dielectric heating of wood under low-headspace conditions removes terpenes and other extractives from softwood; The monoterpene content in trees depend upon temperature and seasonal effects; Method 25A emissions from lumber drying can be modeled from a knowledge of the airflow through the kiln; A heat transfer model shows that VOCs released during hot-pressing mainly originate from the surface of the board; and Boiler ash can be used to adsorb formaldehyde from air streams.

  13. Assessment and remediation at former manufactured gas plants

    SciTech Connect (OSTI)

    Mehan, D.G.

    1995-12-01

    Over 1,000 former Manufactured Gas Plants (MGP) have been identified in the United States. Gal Plants were used to produce gas for lighting and heating from coal and oil from the mid-1800s until the 1950s. Former MGP sites are typically impacted by a variety of compounds that do not collectively lend themselves to {open_quotes}standard{close_quotes} assessment and remedial solutions. These compounds include the volatile organic compounds (VOCs) benzene, toluene, ethylbenzene, and xylene, a variety of semi-volatile organic compound, and inorganic compounds (iron and cyanide). The assessment of former MGP sites is complicated because many former sites are now located in developed and industrialized areas. MGP wastes and by-products were typically disposed on-site. Many modern buildings are now located over former MGP sites. Standard assessment tools such as augering and drilling tend to encounter former structures, making their use difficult and ineffective. Assessment by excavation and geophysical methods allows the acquisition of only shallow data. The remediation of impacted soils and ground water at former MGP sites poses significant challenges due to the differing characteristics of the typical MGP compounds. For example, soil vapor extraction and ground water treatment may decrease VOC concentrations, yet be ineffective on the inorganic and PAH compounds. Because of the variety of typical MGP associated wastes, risk assessment is a vital tool in assessing and selecting the appropriate remedial strategies. Several states have aggressively adopted clean-up programs that rely on risk assessment to determine the appropriate remedial strategy at former MGP sites. At numerous sites, no further action is employed because of the VOCs have attenuated over time, the PAH and inorganic compounds are relatively immobile, ground water contamination plumes are limited, and risk assessment indicates acceptable risks.

  14. Self-Organizing Mesh Generation

    Energy Science and Technology Software Center (OSTI)

    1991-11-01

    A set of five programs which make up a self organizing mesh generation package. QMESH generates meshes having quadrilateral elements on arbitrarily shaped two-dimensional (planar or axisymmetric) bodies. It is designed for use with two-dimensional finite element analysis applications. A flexible hierarchal input scheme is used to describe bodies to QMESH as collections of regions. A mesh for each region is developed independently, with the final assembly and bandwidth minimization performed by the independent program,more » RENUM or RENUM8. RENUM is applied when four-node elements are desired. Eight node elements (with mid side nodes) may be obtained with RENUM8. QPLOT and QPLOT8 are plot programs for meshes generated by the QMESH/RENUM and QMESH/RENUM8 program pairs respectively. QPLOT and QPLOT8 automatically section the mesh into appropriately-sized sections for legible display of node and element numbers, An overall plot showing the position of the selected plot areas is produced.« less

  15. Micro-scale anaerobic digestion of point source components of organic fraction of municipal solid waste

    SciTech Connect (OSTI)

    Chanakya, H.N. Sharma, Isha; Ramachandra, T.V.

    2009-04-15

    The fermentation characteristics of six specific types of the organic fraction of municipal solid waste (OFMSW) were examined, with an emphasis on properties that are needed when designing plug-flow type anaerobic bioreactors. More specifically, the decomposition patterns of a vegetable (cabbage), fruits (banana and citrus peels), fresh leaf litter of bamboo and teak leaves, and paper (newsprint) waste streams as feedstocks were studied. Individual OFMSW components were placed into nylon mesh bags and subjected to various fermentation periods (solids retention time, SRT) within the inlet of a functioning plug-flow biogas fermentor. These were removed at periodic intervals, and their composition was analyzed to monitor decomposition rates and changes in chemical composition. Components like cabbage waste, banana peels, and orange peels fermented rapidly both in a plug-flow biogas reactor (PFBR) as well as under a biological methane potential (BMP) assay, while other OFMSW components (leaf litter from bamboo and teak leaves and newsprint) fermented slowly with poor process stability and moderate biodegradation. For fruit and vegetable wastes (FVW), a rapid and efficient removal of pectins is the main cause of rapid disintegration of these feedstocks, which left behind very little compost forming residues (2-5%). Teak and bamboo leaves and newsprint decomposed only to 25-50% in 30 d. These results confirm the potential for volatile fatty acids accumulation in a PFBR's inlet and suggest a modification of the inlet zone or operation of a PFBR with the above feedstocks.

  16. Organic spintronic devices and methods for making the same (Patent...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organic spintronic devices and methods for making the same Title: Organic spintronic devices and methods for making the same An organic spintronic photovoltaic device (100) having ...

  17. Organic spintronic devices and methods for making the same (Patent...

    Office of Scientific and Technical Information (OSTI)

    Patent: Organic spintronic devices and methods for making the same Citation Details In-Document Search Title: Organic spintronic devices and methods for making the same An organic ...

  18. DOE Organization Chart - June 25, 2012 | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2012-07.pdf More Documents & Publications DOE Organization Chart - July 15, 2013 DOE Organization Chart - May 2, 2014 DOE Organization Chart - October 2014

  19. DOE Organization Chart - October 6, 2011 | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    NONAMES-2011-10.pdf More Documents & Publications DOE Organization Chart - June 6, 2013 DOE Organization Chart - June 25, 2012 DOE Organization Chart - May 1, 2013

  20. Outreach to Faith--Based Organizations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organizations Outreach to Faith--Based Organizations Better Buildings Residential Network Marketing and Outreach Peer Exchange Call: Outreach to Faith-Based Organizations, call...

  1. Office of Policy and International Affairs Organization Chart...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office of Policy and International Affairs Organization Chart Office of Policy and International Affairs Organization Chart Office of Policy and International Affairs Organization...

  2. Probing Organic Transistors with Infrared Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However,

  3. Probing Organic Transistors with Infrared Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However,

  4. Project ATHENA creates surrogate human organ systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project ATHENA creates surrogate human organ systems Alumni Link: Opportunities, News and Resources for Former Employees Latest Issue:September 2015 all issues All Issues » submit Project ATHENA creates surrogate human organ systems The development of miniature surrogate human organs, coupled with highly sensitive mass spectrometry technologies, could one day revolutionize the way new drugs and toxic agents are studied. July 1, 2015 ATHENA prototype undergoes testing. ATHENA prototype undergoes

  5. Probing Organic Transistors with Infrared Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However,

  6. Project ATHENA creates surrogate human organ systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project ATHENA creates surrogate human organ systems Project ATHENA creates surrogate human organ systems The development of miniature surrogate human organs, coupled with highly sensitive mass spectrometry technologies, could one day revolutionize the way new drugs and toxic agents are studied. June 15, 2015 ATHENA prototype undergoes testing. ATHENA prototype undergoes testing. Contact Los Alamos National Laboratory Kevin Roark Communications Office (505) 665-9202 Email "By developing

  7. Pollution prevention opportunity assessment for organization 1700.

    SciTech Connect (OSTI)

    Gerard, Morgan Evan

    2007-06-01

    This Pollution Prevention Opportunity Assessment (PPOA) was conducted for Sandia National Laboratories/New Mexico Organization 1700 in June, 2006. The primary purpose of this PPOA is to provide recommendations to assist Organization 1700 in reducing the generation of waste and improving the efficiency of their processes and procedures. This report contains a summary of the information collected, analyses performed and recommended options for implementation. The Sandia National Laboratories Pollution Prevention staff will continue to work with Organization 1700 to implement the recommendations.

  8. Design, demonstration and evaluation of a thermal enhanced vapor extraction system

    SciTech Connect (OSTI)

    Phelan, J.; Reavis, B.; Swanson, J.

    1997-08-01

    The Thermal Enhanced Vapor Extraction System (TEVES), which combines powerline frequency heating (PLF) and radio frequency (RF) heating with vacuum soil vapor extraction, was used to effectively remove volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) from a pit in the chemical waste landfill (CWL) at Sandia National Laboratories (SNL) within a two month heating period. Volume average temperatures of 83{degrees}C and 112{degrees}C were reached for the PLF and RF heating periods, respectively, within the 15 ft x 45 ft x 18.5 ft deep treated volume. This resulted in the removal of 243 lb of measured toxic organic compounds (VOCs and SVOCs), 55 gallons of oil, and 11,000 gallons of water from the site. Reductions of up to 99% in total chromatographic organics (TCO) was achieved in the heated zone. Energy balance calculations for the PLF heating period showed that 36.4% of the heat added went to heating the soil, 38.5% went to evaporating water and organics, 4.2% went to sensible heat in the water, 7.1% went to heating the extracted air, and 6.6% was lost. For the RF heating period went to heating the soil, 23.5% went to evaporating water and organics, 2.4% went to sensible heat in the water, 7.5% went to heating extracted air, and 9.7% went to losses. Energy balance closure was 92.8% for the PLF heating and 98% for the RF heating. The energy input requirement per unit soil volume heated per unit temperature increase was 1.63 kWH/yd{sup 3}-{degrees}C for PLF heating and 0.73 kWH/yd{sup 3}{degrees}C for RF heating.

  9. Organizations and Networks | Open Energy Information

    Open Energy Info (EERE)

    Network (CLEAN) CLEAN aims to improve communication and coordination by bringing together national and international organizations that are assisting developing countries with...

  10. International Labor Organization (ILO) | Open Energy Information

    Open Energy Info (EERE)

    Switzerland Year Founded: 1919 References: http:www.ilo.orggloballang--enindex.htma1 Overview "The ILO is the international organization responsible for drawing up and...

  11. Data management system for organic soil

    SciTech Connect (OSTI)

    Stinnette, P.

    1999-07-01

    A Data Management System for Organic Soil (DMSOS) has been developed that enables the acquisition, management and analysis of organic soil data as well as the presentation of results to be conducted effectively through a common interface. This development was in response to the data management needs of research investigating the engineering properties of organic soil and its extension to the stabilization of organic soil through dynamic replacement (DR). It is shown how the above functions are implemented efficiently using Windows-based software to perform comprehensive data management and analysis of data gathered from both laboratory and field tests. When the engineering properties of a given organic soil deposit are needed, a build-in Computer Advisor for Organic Soil Projects (CAOSP) predicts the properties from DMSOS based correlations. A unique and useful feature of the CAOSP is its ability to estimate the anticipated ultimate settlement of an organic soil deposit given the loading conditions and the moisture or organic content. Also incorporated in the DMSOS is a quality control system that utilizes computerized data acquisition/data management techniques in order to evaluate the degree of improvement of an organic soil layer at a given stage of treatment using DR.

  12. International energy: Research organizations, 1986--1990

    SciTech Connect (OSTI)

    Hendricks, P.; Jordan, S. )

    1991-03-01

    The International Energy: Research Organizations publication contains the standardized names of energy research organizations used in energy information databases. Involved in this cooperative task are (1) the technical staff of the USDOE Office of Scientific and Technical Information (OSTI) in cooperation with the member countries of the Energy Technology Data Exchange (ETDE) and (2) the International Nuclear Information System (INIS). This publication identifies current organizations doing research in all energy fields, standardizes the format for recording these organization names in bibliographic citations, assigns a numeric code to facilitate data entry, and identifies report number prefixes assigned by these organizations. These research organization names may be used in searching the databases Energy Science Technology'' on DIALOG and Energy'' on STN International. These organization names are also used in USDOE databases on the Integrated Technical Information System. Research organizations active in the past five years, as indicated by database records, were identified to form this publication. This directory includes approximately 34,000 organizations that reported energy-related literature from 1986 to 1990 and updates the DOE Energy Data Base: Corporate Author Entries.

  13. Process for recovering organic vapors from air

    DOE Patents [OSTI]

    Baker, Richard W. (Mountain View, CA)

    1985-01-01

    A process for recovering and concentrating organic vapor from a feed stream of air having an organic vapor content of no more than 20,000 ppm by volume. A thin semipermeable membrane is provided which has a feed side and a permeate side, a selectivity for organic vapor over air of at least 50, as measured by the ratio of organic vapor permeability to nitrogen permeability, and a permeability of organic vapor of at least 3.times.10.sup.-7 cm.sup.3 (STP) cm/cm.sup.2 sec.cm Hg. The feed stream is passed across the feed side of the thin semipermeable membrane while providing a pressure on the permeate side which is lower than the feed side by creating a partial vacuum on the permeate side so that organic vapor passes preferentially through the membrane to form an organic vapor depleted air stream on the feed side and an organic vapor enriched stream on the permeate side. The organic vapor which has passed through the membrane is compressed and condensed to recover the vapor as a liquid.

  14. Method for catalytic destruction of organic materials

    DOE Patents [OSTI]

    Sealock, L.J. Jr.; Baker, E.G.; Elliott, D.C.

    1997-05-20

    A method is disclosed for converting waste organic materials into an innocuous product gas. The method comprises maintaining, in a pressure vessel, in the absence of oxygen, at a temperature of 250 to 500 C and a pressure of at least 50 atmospheres, a fluid organic waste material, water, and a catalyst consisting essentially of reduced nickel in an amount sufficient to catalyze a reaction of the organic waste material to produce an innocuous product gas composed primarily of methane and carbon dioxide. The methane in the product gas may be burned to preheat the organic materials. 7 figs.

  15. Method for catalytic destruction of organic materials

    DOE Patents [OSTI]

    Sealock, Jr., L. John (Richland, WA); Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1997-01-01

    A method is disclosed for converting waste organic materials into an innocuous product gas. The method comprises maintaining, in a pressure vessel, in the absence of oxygen, at a temperature of 250.degree. C. to 500.degree. C. and a pressure of at least 50 atmospheres, a fluid organic waste material, water, and a catalyst consisting essentially of reduced nickel in an amount sufficient to catalyze a reaction of the organic waste material to produce an innocuous product gas composed primarily of methane and carbon dioxide. The methane in the product gas may be burned to preheat the organic materials.

  16. FY 2006 Summary Table by Organization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Budget by Organization (discretionary dollars in thousands) FY 2004 FY 2005 FY 2006 Comparable Comparable Request to FY 2006 vs. FY 2005 Approp Approp Congress Discretionary...

  17. Energy Ventures Organization Inc | Open Energy Information

    Open Energy Info (EERE)

    search Name: Energy Ventures Organization Inc Place: United States Sector: Hydro, Hydrogen Product: Hydrogen ( Private family-controlled ) References: Energy Ventures...

  18. Probing Organic Transistors with Infrared Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is...

  19. ARM - Evaluation Product - Organic Aerosol Component VAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsOrganic Aerosol Component VAP ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file level. Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : Organic Aerosol Component VAP Organic aerosol (OA, i.e., the organic fraction of particles) accounts for 10-90% of the fine aerosol mass globally and is a key determinant of aerosol radiative forcing. But atmospheric OA

  20. Binding Organic Liquids - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    More Like This Return to Search Binding Organic Liquids Pacific Northwest National Laboratory Contact PNNL About This Technology Technology Marketing Summary Researchers at...

  1. ARM - AMF2 Organization and Contact Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2009-2010 Shouxian, China, 2008 Black Forest, Germany, 2007 Niamey, Niger, 2006 Point Reyes, California, 2005 AMF2 Organization and Contact Information The Argonne AMF2...

  2. Energy Systems Organization Charts | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Systems Organization Charts Charts showing the organizational structure of the Energy Systems Division and the Center for Transportation Research at Argonne. PDF icon...

  3. Nanoscience & Technology Organization Chart | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscience & Technology Organization Chart The Nanoscience and Technology (NST) Division at Argonne National Laboratory hosts a user facility, the Center for Nanoscale Materials,...

  4. FY 2005 Control Table by Organization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization (dollars in thousands - OMB Scoring) Table of Contents Summary...................................................................................................... 1 Mandatory Funding....................................................................................... 2 National Nuclear Security Administration..................................................... 3 Energy Efficiency and Renewable Energy.................................................... 4 Electric Transmission

  5. Organization Chart | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact Us Business Operations Careers Human Resources Directory Environment, Safety & Health Furth Plasma Physics Library Lab Leadership Organization Chart Technology Transfer...

  6. Decontamination Systems Information and Research Program. Quarterly technical progress report, January 1--March 31, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    West Virginia University (WVU) and the US DOE Morgantown Energy Technology Center (METC) entered into a Cooperative Agreement on August 29, 1992 entitled ``Decontamination Systems Information and Research Programs.`` Stipulated within the Agreement is the requirement that WVU submit to METC a series of Technical Progress Reports on a quarterly basis. This report comprises the first Quarterly Technical Progress Report for Year 2 of the Agreement. This report reflects the progress and/or efforts performed on the sixteen (16) technical projects encompassed by the Year 2 Agreement for the period of January 1 through March 31, 1994. In situ bioremediation of chlorinated organic solvents; Microbial enrichment for enhancing in-situ biodegradation of hazardous organic wastes; Treatment of volatile organic compounds (VOCs) using biofilters; Drain-enhanced soil flushing (DESF) for organic contaminants removal; Chemical destruction of chlorinated organic compounds; Remediation of hazardous sites with steam reforming; Soil decontamination with a packed flotation column; Use of granular activated carbon columns for the simultaneous removal of organics, heavy metals, and radionuclides; Monolayer and multilayer self-assembled polyion films for gas-phase chemical sensors; Compact mercuric iodide detector technology development; Evaluation of IR and mass spectrometric techniques for on-site monitoring of volatile organic compounds; A systematic database of the state of hazardous waste clean-up technologies; Dust control methods for insitu nuclear and hazardous waste handling; Winfield Lock and Dam remediation; and Socio-economic assessment of alternative environmental restoration technologies.

  7. High Performance Organic Photovoltaics via Novel Materials Combinations

    SciTech Connect (OSTI)

    Laird, Dr Darin; McGuiness, Dr Christine; Storch, Mark

    2011-01-20

    OPV cell efficiencies have increased significantly over the last decade and verified champion efficiencies are currently at 8.3% for both single and multi-junction device types. These increases in efficiency have been driven through the development and optimization of the donor and acceptor materials in bulk heterojunction active layers. Plextronics and Solarmer Energy Inc. are two of the world leading developers of these donor and acceptor materials. Solarmer Energy has reported NREL certified 6.77% efficiencies using optimized low band gap donor materials in combination with PC61BM and PC71BM acceptors and recently reported a champion NREL certified efficiency of 8.1%. Plextronics has reported Newport certified efficiencies of 6.7% using PC71BM acceptors with low band gap materials. In addition, Plextronics has also demonstrated that OPV efficiency of P3HT based materials can be improved by 50% by improving the Voc using alternative acceptors (indene substituted C60 and C70) to PC61BM and PC71BM. However, performance of these alternative acceptors in combination with low band gap materials has not been investigated and the potential for efficiency improvement is evident. In this collaboration, four low band gap donor materials from Solarmer Energy Inc were combined with Plextronics indene-class acceptors Plextronics indene substituted C60 and C70 acceptors to demonstrate OPV performance greater than 7%. Two main indene class C60 acceptors (codenamed Mono-indene[C60] Mono-indene[C60] , Bis-indene[C60] ) were screened with the Solarmer polymers. These four polymers were screened and optimized with the indene class acceptors at both Plextronics and Solarmer. A combination was identified which produced 6.7% (internal measurement) with a Solarmer polymer and a Plextronics fullerene acceptor. This was accomplished primarily by improving the Voc as well as improving the current (Jsc) and FF.

  8. Contribution from biogenic organic compounds to particle growth during the 2010 BEACHON-ROCS campaign in a Colorado temperate needleleaf forest

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, L.; Gierens, R.; Sogachev, A.; Mogensen, D.; Ortega, J.; Smith, J. N.; Harley, P. C.; Prenni, A. J.; Levin, E. J. T.; Turnipseed, A.; et al

    2015-08-06

    New particle formation (NPF) is an important atmospheric phenomenon. During an NPF event, particles first form by nucleation and then grow further in size. The growth step is crucial because it controls the number of particles that can become cloud condensation nuclei. Among various physical and chemical processes contributing to particle growth, condensation by organic vapors has been suggested as important. In order to better understand the influence of biogenic emissions on particle growth, we carried out modeling studies of NPF events during the BEACHON-ROCS (Bio–hydro–atmosphere interactions of Energy, Aerosol, Carbon, H2O, Organics & Nitrogen – Rocky Mountain Organic Carbonmore » Study) campaign at Manitou Experimental Forest Observatory in Colorado, USA. The site is representative of the semi-arid western USA. With the latest Criegee intermediate reaction rates implemented in the chemistry scheme, the model underestimates sulfuric acid concentration by 50 %, suggesting either missing sources of atmospheric sulfuric acid or an overestimated sink term. The results emphasize the contribution from biogenic volatile organic compound emissions to particle growth by demonstrating the effects of the oxidation products of monoterpenes and 2-Methyl-3-buten-2-ol (MBO). Monoterpene oxidation products are shown to influence the nighttime particle loadings significantly, while their concentrations are insufficient to grow the particles during the day. The growth of ultrafine particles in the daytime appears to be closely related to the OH oxidation products of MBO.« less

  9. Contribution from biogenic organic compounds to particle growth during the 2010 BEACHON-ROCS campaign in a Colorado temperate needleleaf forest

    SciTech Connect (OSTI)

    Zhou, L.; Gierens, R.; Sogachev, A.; Mogensen, D.; Ortega, J.; Smith, J. N.; Harley, P. C.; Prenni, A. J.; Levin, E. J. T.; Turnipseed, A.; Rusanen, A.; Smolander, S.; Guenther, A. B.; Kulmala, M.; Karl, T.; Boy, M.

    2015-08-06

    New particle formation (NPF) is an important atmospheric phenomenon. During an NPF event, particles first form by nucleation and then grow further in size. The growth step is crucial because it controls the number of particles that can become cloud condensation nuclei. Among various physical and chemical processes contributing to particle growth, condensation by organic vapors has been suggested as important. In order to better understand the influence of biogenic emissions on particle growth, we carried out modeling studies of NPF events during the BEACHON-ROCS (Bio–hydro–atmosphere interactions of Energy, Aerosol, Carbon, H2O, Organics & Nitrogen – Rocky Mountain Organic Carbon Study) campaign at Manitou Experimental Forest Observatory in Colorado, USA. The site is representative of the semi-arid western USA. With the latest Criegee intermediate reaction rates implemented in the chemistry scheme, the model underestimates sulfuric acid concentration by 50 %, suggesting either missing sources of atmospheric sulfuric acid or an overestimated sink term. The results emphasize the contribution from biogenic volatile organic compound emissions to particle growth by demonstrating the effects of the oxidation products of monoterpenes and 2-Methyl-3-buten-2-ol (MBO). Monoterpene oxidation products are shown to influence the nighttime particle loadings significantly, while their concentrations are insufficient to grow the particles during the day. The growth of ultrafine particles in the daytime appears to be closely related to the OH oxidation products of MBO.

  10. Apparatus and method for oxidizing organic materials

    DOE Patents [OSTI]

    Surma, Jeffrey E. (Kennewick, WA); Bryan, Garry H. (Kennewick, WA); Geeting, John G. H. (West Richland, WA); Butner, R. Scott (Port Orchard, WA)

    1998-01-01

    The invention is a method and apparatus using high cerium concentration in the anolyte of an electrochemical cell to oxidize organic materials. The method and apparatus further use an ultrasonic mixer to enhance the oxidation rate of the organic material in the electrochemical cell.

  11. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, E.

    1995-05-23

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

  12. Apparatus and method for oxidizing organic materials

    DOE Patents [OSTI]

    Surma, J.E.; Bryan, G.H.; Geeting, J.G.H.; Butner, R.S.

    1998-01-13

    The invention is a method and apparatus using high cerium concentration in the anolyte of an electrochemical cell to oxidize organic materials. The method and apparatus further use an ultrasonic mixer to enhance the oxidation rate of the organic material in the electrochemical cell. 6 figs.

  13. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, Elias (Oak Ridge, TN)

    1995-01-01

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

  14. Human Capital Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Human Capital Organization Human Capital Organization HC Organizational Chart HC Organizational Chart Printable Version The Office of the Chief Human Capital Officer provides leadership to the Department of Energy (DOE) on the impact and use of policies, proposals, programs, and partnerships related to all aspects of Human Capital Management (HCM).

  15. About EIA - Organization - U.S. Energy Information Administration (EIA)

    Gasoline and Diesel Fuel Update (EIA)

    Organization Chart Printer-friendly version Howard Gruenspecht Howard Gruenspecht Stephen Harvey John Conti Gina Pearson EIA Organization chart

  16. Organic photovoltaic cells utilizing ultrathin sensitizing layer

    DOE Patents [OSTI]

    Rand, Barry P.; Forrest, Stephen R.

    2011-05-24

    A photosensitive device includes a series of organic photoactive layers disposed between two electrodes. Each layer in the series is in direct contact with a next layer in the series. The series is arranged to form at least one donor-acceptor heterojunction, and includes a first organic photoactive layer comprising a first host material serving as a donor, a thin second organic photoactive layer comprising a second host material disposed between the first and a third organic photoactive layer, and the third organic photoactive layer comprising a third host material serving as an acceptor. The first, second, and third host materials are different. The thin second layer serves as an acceptor relative to the first layer or as a donor relative to the third layer.

  17. Storing data encoded DNA in living organisms

    DOE Patents [OSTI]

    Wong; Pak C. (Richland, WA), Wong; Kwong K. (Sugar Land, TX), Foote; Harlan P. (Richland, WA)

    2006-06-06

    Current technologies allow the generation of artificial DNA molecules and/or the ability to alter the DNA sequences of existing DNA molecules. With a careful coding scheme and arrangement, it is possible to encode important information as an artificial DNA strand and store it in a living host safely and permanently. This inventive technology can be used to identify origins and protect R&D investments. It can also be used in environmental research to track generations of organisms and observe the ecological impact of pollutants. Today, there are microorganisms that can survive under extreme conditions. As well, it is advantageous to consider multicellular organisms as hosts for stored information. These living organisms can provide as memory housing and protection for stored data or information. The present invention provides well for data storage in a living organism wherein at least one DNA sequence is encoded to represent data and incorporated into a living organism.

  18. DOE Organization Chart - February 2015 | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 2015 DOE Organization Chart - February 2015 The DOE Organization Chart is a diagram of the U.S. Department of Energy's structure along with the relationships and relative ranks of its parts and positions/jobs. PDF icon DOE Organization Chart - February 2015 More Documents & Publications DOE Organization Chart - May 2015 DOE Organization Chart - December 2014 DOE ORGANIZATION CHART - JULY 2015

  19. OCIO Organization Chart (printable version) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OCIO Organization Chart (printable version) OCIO Organization Chart (printable version) Printable PDF version of the OCIO Organization Chart. PDF icon OCIO Org Chart as of 11.13.2015 More Documents & Publications Office of Management Organization Chart OCIO Organization Chart (printable version) Organization FTCP Senior Technical Safety Manager (STSM) Status Report

  20. DOE Organization Chart - May 2015 | Department of Energy

    Office of Environmental Management (EM)

    015 DOE Organization Chart - May 2015 The DOE Organization Chart is a diagram of the U.S. Department of Energy's structure along with the relationships and relative ranks of its parts and positions/jobs. PDF icon DOE Organization Chart - May 2015 More Documents & Publications DOE Organization Chart - February 2015 DOE Organization Chart - December 2014 DOE ORGANIZATION CHART - JULY 2015