National Library of Energy BETA

Sample records for voc volatile organic

  1. Quantitative analysis of volatile organic compounds (VOCs) in soil via passive sampling : polyethylene sampler design and optimization

    E-Print Network [OSTI]

    Jensen, David G. (David Gannon)

    2015-01-01

    The potential for the release of volatile organic compounds (VOCs) to our natural environment is pervasive. However, the ability to accurately measure and predict VOC soil vapor concentrations is still limited. A polyethylene ...

  2. ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2006-07-10

    Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

  3. Southern California Edison's (SCE) Research Program for Industrial Volatile Organic Compound (VOC) Emissions Control 

    E-Print Network [OSTI]

    Sung, R. D.; Cascone, R.; Reese, J.

    1990-01-01

    EDISON'S (SCE) RESEARCH PROGRAM FOR INDUSTRIAL VOLATILE ORGANIC COMPOUND (VOC) EMISSIONS CONTROL ROGER D. SUNG RON CASCONE JIM REESE Program Manager Senior Consultant Manager Southern California Edison Chem Systems, Inc. Applied Utility Systems... Rosemead, California Tarrytown, New York Santa Ana, California ABSTRACT SCE has developed and implemented a research program for customer retention through VOC emission control. Following characterization of problematic emission sources, SCE has...

  4. Benchtop testing of polyethylene passive sampling towards a quantitative analysis of volatile organic compounds (VOCs) in soil vapours

    E-Print Network [OSTI]

    Soo, Yu Xiang Jaren

    2015-01-01

    The feasibility of polyethylene (PE) as a passive sampler for quantitative analysis of volatile organic compounds (VOCs) was analysed in this work by means of a benchtop testing. A benchtop physical model was setup, which ...

  5. Characterization of low-VOC latex paints: Volatile organic compound content, VOC and aldehyde emissions, and paint performance. Final report, January 1997--January 1999

    SciTech Connect (OSTI)

    Fortmann, R.; Lao, H.C.; Ng, A.; Roache, N.

    1999-04-01

    The report gives results of laboratory tests to evaluate commercially available latex paints advertised as `low-odor,` `low-VOC (volatile organic compound),` or `no-VOC.` Measurements were performed to quantify the total content of VOCs in the paints and to identify the predominant VOCs and aldehydes in the emissions following application to test substrates. The performance of the paints was evaluated and compared to that of commonly used conventional latex paints by American Society for Testing and Materials (ASTM) standard methods that measured parameters such as scrubbability, cleanability, and hiding power. The report describes the paints that were tested, the test methods, and the experimental data. Results are presented that can be used to evaluate the low-odor/low-VOC paints as alternatives to conventional latex wall paints that contain and emit higher concentrations of VOCs.

  6. Comparisons of diffusive and advective fluxes of gas phase volatile organic compounds (VOCs) in unsaturated zones under natural conditions

    E-Print Network [OSTI]

    Zhan, Hongbin

    is traditionally treated as the dominant mechanism of gas transport in unsaturated zones under natural conditionsComparisons of diffusive and advective fluxes of gas phase volatile organic compounds (VOCs) in unsaturated zones under natural conditions Kehua You a , Hongbin Zhan a,b, a Department of Geology

  7. Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong

    E-Print Network [OSTI]

    2009-01-01

    Chemistry and Physics Vehicular emission of volatile organicY. , and Huang, Y. S. : Emission factors and characteristicslight-duty vehicle emissions, Environ. Sci. Technol. , 30,

  8. Occupational hygiene in terms of volatile organic compounds (VOCs) and bioaerosols at two solid waste management plants in Finland

    SciTech Connect (OSTI)

    Lehtinen, Jenni; Tolvanen, Outi; Nivukoski, Ulla; Veijanen, Anja; Hänninen, Kari

    2013-04-15

    Highlights: ? Odorous VOCs: acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene. ? VOC concentrations did not exceed occupational exposure limit concentrations. ? 2,3-Butanedione as the health effecting compound is discussed. ? Endotoxin concentrations may cause health problems in waste treatment. - Abstract: Factors affecting occupational hygiene were measured at the solid waste transferring plant at Hyvinkää and at the optic separation plant in Hämeenlinna. Measurements consisted of volatile organic compounds (VOCs) and bioaerosols including microbes, dust and endotoxins. The most abundant compounds in both of the plants were aliphatic and aromatic hydrocarbons, esters of carboxylic acids, ketones and terpenes. In terms of odour generation, the most important emissions were acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene due to their low threshold odour concentrations. At the optic waste separation plant, limonene occurred at the highest concentration of all single compounds of identified VOCs. The concentration of any single volatile organic compound did not exceed the occupational exposure limit (OEL) concentration. However, 2,3-butanedione as a health risk compound is discussed based on recent scientific findings linking it to lung disease. Microbe and dust concentrations were low at the waste transferring plant. Only endotoxin concentrations may cause health problems; the average concentration inside the plant was 425 EU/m{sup 3} which clearly exceeded the threshold value of 90 EU/m{sup 3}. In the wheel loader cabin the endotoxin concentrations were below 1 EU/m{sup 3}. High microbial and endotoxin concentrations were measured in the processing hall at the optic waste separation plant. The average concentration of endotoxins was found to be 10,980 EU/m{sup 3}, a concentration which may cause health risks. Concentrations of viable fungi were quite high in few measurements in the control room. The most problematic factor was endotoxins whose average measured concentrations was 4853 EU/m{sup 3}.

  9. Aging of secondary organic aerosol from small aromatic VOCs. Changes in chemical composition, mass yield, volatility and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2014-12-12

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form and transform SOA from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx. The effects of chemical aging on organic aerosol (OA) composition, mass yield, volatility and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state OSC) and mass yield. The OA oxidation state generally increased duringmore »photo-oxidation, and the final OA OS C ranged from -0.29 to 0.45 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  10. Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-

    E-Print Network [OSTI]

    Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

  11. Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong

    E-Print Network [OSTI]

    2009-01-01

    ethene toluene n-butane propane i-pentane i-butane propeneethene, toluene, n-butane, propane and i-pentane. These fiveVOCs emitted. The high propane and n-butane emissions were

  12. Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong

    E-Print Network [OSTI]

    2009-01-01

    a focus on benzene and 1,3- butadiene, Atmos. Environ. , 30,propylbenzene cis-2-butene 1,3-butadiene 2,3-dimethylbutaneVOCs (e.g. benzene and 1,3-butadiene) emitted from vehicles

  13. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, Gregory D. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID); Reagen, William K. (Stillwater, MN)

    1995-01-01

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

  14. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

    1995-08-29

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

  15. Class 2 Permit Modification Request Revise Volatile Organic Compound...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Monitoring Program scfm standard cubic feet per minute (ft 3 min) TCE trichloroethylene TIC tentatively identified compound TRU transuranic VOC volatile organic compound WIPP...

  16. Energy Efficient Removal of Volatile Organic Compounds (VOCs) and Organic Hazardous Air Pollutants (o-HAPs) from Industrial Waste Streams by Direct Electron Oxidation

    SciTech Connect (OSTI)

    Testoni, A. L.

    2011-10-19

    This research program investigated and quantified the capability of direct electron beam destruction of volatile organic compounds and organic hazardous air pollutants in model industrial waste streams and calculated the energy savings that would be realized by the widespread adoption of the technology over traditional pollution control methods. Specifically, this research determined the quantity of electron beam dose required to remove 19 of the most important non-halogenated air pollutants from waste streams and constructed a technical and economic model for the implementation of the technology in key industries including petroleum refining, organic & solvent chemical production, food & beverage production, and forest & paper products manufacturing. Energy savings of 75 - 90% and green house gas reductions of 66 - 95% were calculated for the target market segments.

  17. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    natural gas extraction can lead to signi?cant emissions of methane (CH 4 ), volatile organic compounds (VOCs), and nitrogen

  18. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.; Bomstad, Theresa M.; Sorini-Wong, Susan S.; Wong, Gregory K.

    2011-03-01

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  19. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F. (Laramie, WY); Rovani, Jr., Joseph F. (Laramie, WY); Bomstad, Theresa M. (Laramie, WY); Sorini-Wong, Susan S. (Laramie, WY)

    2009-02-10

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  20. Electrospun Polyurethane Fibers for Absorption of Volatile Organic Compounds from Air

    E-Print Network [OSTI]

    Scholten, Elke

    Electrospun polyurethane fibers for removal of volatile organic compounds (VOC) from air with rapid VOC absorption and desorption have been developed. Polyurethanes based on 4,4-methylenebis(phenylisocyanate) (MDI) and ...

  1. Measurements of Volatile Organic Compounds Using Proton Transfer Reaction - Mass Spectrometry during the MILAGRO 2006 Campaign

    E-Print Network [OSTI]

    Fortner, E. C.

    Volatile organic compounds (VOCs) were measured by proton transfer reaction – mass spectrometry (PTR-MS) on a rooftop in the urban mixed residential and industrial area North Northeast of downtown Mexico City as part of ...

  2. QUANTIFYING NON-POINT SOURCES OF VOLATILE ORGANIC COMPOUNDS IN STORMWATER FROM A PARKING LOT

    E-Print Network [OSTI]

    1 QUANTIFYING NON-POINT SOURCES OF VOLATILE ORGANIC COMPOUNDS IN STORMWATER FROM A PARKING LOT (VOCs) in stormwater from an asphalt parking lot without obvious point sources (e.g. gasoline stations). The parking lot surface and atmosphere are important non-point sources of VOCs, with each being important

  3. Apparatus for sensing volatile organic chemicals in fluids

    DOE Patents [OSTI]

    Hughes, Robert C.; Manginell, Ronald P.; Jenkins, Mark W.; Kottenstette, Richard; Patel, Sanjay V.

    2005-06-07

    A chemical-sensing apparatus is formed from the combination of a chemical preconcentrator which sorbs and concentrates particular volatile organic chemicals (VOCs) and one or more chemiresistors that sense the VOCs after the preconcentrator has been triggered to release them in concentrated form. Use of the preconcentrator and chemiresistor(s) in combination allows the VOCs to be detected at lower concentration than would be possible using the chemiresistor(s) alone and further allows measurements to be made in a variety of fluids, including liquids (e.g. groundwater). Additionally, the apparatus provides a new mode of operation for sensing VOCs based on the measurement of decay time constants, and a method for background correction to improve measurement precision.

  4. Temperature dependence of volatile organic compound evaporative emissions from motor vehicles

    E-Print Network [OSTI]

    Goldstein, Allen

    Temperature dependence of volatile organic compound evaporative emissions from motor vehicles Juli tailpipe sources to motor vehicle volatile organic compound (VOC) emissions. Contributions were determined in a highway tunnel were used to define the composition of running vehicle emissions. The chemical mass balance

  5. Airborne and ground based measurements of volatile organic compounds using proton transfer reaction mass spectrometry in Texas and Mexico City 

    E-Print Network [OSTI]

    Fortner, Edward Charles

    2009-05-15

    Measurements of ambient volatile organic compounds (VOCs) by proton transfer reaction mass spectrometry (PTR-MS) are reported from recent airborne and surface based field campaigns. The Southeast Texas Tetroon Study (SETTS) ...

  6. Advanced heat pump for the recovery of volatile organic compounds

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    Emissions of Volatile Organic Compounds (VOC) from stationary industrial and commercial sources represent a substantial portion of the total US VOC emissions. The Toxic-Release Inventory'' of The US Environmental Protection Agency estimates this to be at about 3 billion pounds per year (1987 estimates). The majority of these VOC emissions are from coating processes, cleaning processes, polymer production, fuel production and distribution, foam blowing,refrigerant production, and wood products production. The US Department of Energy's (DOE) interest in the recovery of VOC stems from the energy embodied in the recovered solvents and the energy required to dispose of them in an environmentally acceptable manner. This Phase I report documents 3M's work in close working relationship with its subcontractor Nuclear Consulting Services (Nucon) for the preliminary conceptual design of an advanced Brayton cycle heat pump for the recovery of VOC. Nucon designed Brayton cycle heat pump for the recovery of methyl ethyl ketone and toluene from coating operations at 3M Weatherford, OK, was used as a base line for the work under cooperative agreement between 3M and ODE. See appendix A and reference (4) by Kovach of Nucon. This cooperative agreement report evaluates and compares an advanced Brayton cycle heat pump for solvent recovery with other competing technologies for solvent recovery and reuse. This advanced Brayton cycle heat pump is simple (very few components), highly reliable (off the shelf components), energy efficient and economically priced.

  7. Real-time monitoring of volatile organic compounds using chemical ionization mass spectrometry

    DOE Patents [OSTI]

    Mowry, Curtis Dale (Albuquerque, NM); Thornberg, Steven Michael (Peralta, NM)

    1999-01-01

    A system for on-line quantitative monitoring of volatile organic compounds (VOCs) includes pressure reduction means for carrying a gaseous sample from a first location to a measuring input location maintained at a low pressure, the system utilizing active feedback to keep both the vapor flow and pressure to a chemical ionization mode mass spectrometer constant. A multiple input manifold for VOC and gas distribution permits a combination of calibration gases or samples to be applied to the spectrometer.

  8. Modeling VOC sorption of building materials and its impact on indoor air quality

    E-Print Network [OSTI]

    Zhang, Jinsong, 1975-

    2001-01-01

    Sorption of volatile organic compounds (VOCs) by building materials can have significant effect on the indoor VOC concentration levels and indoor air quality in buildings. The objective of this study was to investigate ...

  9. THE COST OF REDUCING VOC EMMISSIONS

    E-Print Network [OSTI]

    Bateman, Ian J.

    THE COST OF REDUCING VOC EMMISSIONS FROM 21 INDUSTRIES BY JONATHAN FISHER CSERGE WORKING PAPER WM 97-03 #12;THE COST OF REDUCING VOC EMISSIONS FROM 21 INDUSTRIES by Jonathan Fisher ERM Economics 8 and Industry to estimate the costs of various levels of controls on emissions of Volatile Organic Compounds

  10. 5, 90979126, 2005 VOC emissions from

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 9097­9126, 2005 VOC emissions from vegetation pyrolysis J. P. Greenberg et al. Title Page Discussions Volatile organic emissions from the distillation and pyrolysis of vegetation J. P. Greenberg, H is licensed under a Creative Commons License. 9097 #12;ACPD 5, 9097­9126, 2005 VOC emissions from vegetation

  11. Partitioning of Volatile Organics in Diesel Particulate and Exhaust

    Office of Energy Efficiency and Renewable Energy (EERE)

    Evaluation of how sampling details affect the measurement of volatile organic compounds in diesel exhaust

  12. NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to date 308 to present SR- BCLDP.003.001 Savannah River Site This waste consists of CH Hydraulic Sludge and Debris generated by the BCLDP program during the D&D of the Building...

  13. Energy Saving System to Remove Volatile Organic Compounds (VOCs) from

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansasCommunities EnergyU.S. DOE Office of99Saving Gift Ideas for Dad

  14. ORIGINAL PAPER CFD-based modeling and design for energy-efficient VOC

    E-Print Network [OSTI]

    Huang, Yinlun

    it is applied to the surface of any substrate in paint spray operation, the volatile organic compounds (VOC 2013 Ó Springer-Verlag Berlin Heidelberg 2013 Abstract Volatile organic compounds (VOC's) are among surface coating application system for energy-efficient emission reduction. A case study on paint spray

  15. Implementation of a solvent management program to control paint shop volatile organic compounds

    SciTech Connect (OSTI)

    Floer, M.M.; Hicks, B.H.

    1997-12-31

    The majority of automobile assembly plant volatile organic compound (VOC) emissions are generated from painting operations. Typical paint operations generate more than 90 percent of the total plant emissions and, up to, 50 percent can be released by cleaning sources. Plant practices which contribute to the release of VOC emissions include the cleaning of paint lines and equipment, tanks, spray booths, floors and vehicles. Solvents continue to be the largest contributing source of VOC emissions in an automotive paint shop. To reduce overall VOC emissions, environmental regulations and guidelines were introduced under the Clean Air Act; Pollution Prevention and Waste Minimization programs, Control Techniques, and special air permit conditions. The introduction of these regulations and guidelines has driven industry toward continual refinement of their present cleaning methods while pursuing new techniques and technologies. Industry has also shown a proactive approach by introducing new waterborne and powder coating paint technologies to reduce overall emissions. As new paint technologies are developed and introduced, special attention must be given to the types of materials utilized for cleaning. The development and implementation of a solvent management program allows a facility to standardize a program to properly implement materials, equipment, technologies and work practices to reduce volatile organic compound emissions, meet strict cleaning requirements posed by new paint technologies and produce a vehicle which meets the high quality standards of the customer. This paper will assess the effectiveness of a solvent management program by examining pollution prevention initiatives and data from four different painting operations.

  16. Environmental Impact on Applied Technology- Global Warming CFCs & VOCs 

    E-Print Network [OSTI]

    Gilbert, J. S.

    1989-01-01

    Hardly a day goes by that the threats to our environment are not brought to our attention. Whether you are following oil spills, groundwater contamination, global warming, chlorofluorocarbons (CFCs) or volatile organic compounds (VOCs), you must...

  17. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    SciTech Connect (OSTI)

    Apel, Eric; Emmons, L.; Karl, Thomas G.; Flocke, Frank M.; Hills, A. J.; Madronich, Sasha; Lee-Taylor, J.; Fried, Alan; Weibring, P.; Walega, J.; Richter, Dirk; Tie, X.; Mauldin, L.; Campos, Teresa; Weinheimer, Andrew J.; Knapp, David; Sive, B.; Kleinman, Lawrence I.; Springston, S.; Zaveri, Rahul A.; Ortega, John V.; Voss, Paul B.; Blake, D. R.; Baker, Angela K.; Warneke, Carsten; Welsh-Bon, Daniel; de Gouw, Joost A.; Zheng, J.; Zhang, Renyi; Rudolph, Jochen; Junkermann, W.; Riemer, D.

    2010-01-01

    The volatile organic compound (VOC) distribution in the Mexico City Metropolitan Area (MCMA) and its evolution as it is uplifted and transported out of the MCMA basin was studied during the 2006 MILAGRO/MIRAGE-Mex field campaign. The results show that in the morning hours in the city center, the VOC distribution is dominated by non-methane hydrocarbons (NMHCs) but with a substantial contribution from oxygenated volatile organic compounds (OVOCs), predominantly from primary emissions. Alkanes account for a large part of the NMHC distribution in terms of mixing ratios. In terms of reactivity, NMHCs also dominate overall, especially in the morning hours. However, in the afternoon, as the boundary layer lifts and air is mixed and aged within the basin, the distribution changes as secondary products are formed. The WRF-Chem (Weather Research and Forecasting with Chemistry) model and MOZART (Model for Ozone and Related chemical Tracers) were able to reproduce the general features of the daytime cycle of the VOC OH reactivity distribution showing that NMHCs dominate the distribution except in the afternoon hours and that the VOC OH reactivity peaks in the early morning due to high morning emissions from the city into a shallow boundary layer. The WRF-Chem and MOZART models showed higher reactivity than the experimental data during the nighttime cycle, perhaps indicating problems with the modeled nighttime boundary layer height. In addition, a plume was studied in which air was advected out of the MCMA and intercepted downwind with the DOE G1 on March 18 and the NCAR C130 one day later on March 19. A number of identical species measured aboard each aircraft gave insight into the chemical evolution of the plume as it aged and was transported as far as 1000 km downwind. Ozone and many OVOCs were photochemically produced in the plume. The WRF-Chem and MOZART models were used to examine the spatial and temporal extent of the March 19 plume and to help interpret the OH reactivity in the downwind plume. The model results generally showed good agreement with experimental results for the total VOC OH reactivity downwind and gave insight into the distributions of VOC chemical classes downwind. A box model with detailed gas phase chemistry (NCAR Master Mechanism), initialized with concentrations observed at one of the ground sites in the MCMA, was used to examine the expected evolution of specific VOCs over a 1-2 day period. The models clearly supported the experimental evidence for NMHC oxidation leading to the formation of OVOCs downwind, which then become the primary fuel for ozone production far away from the MCMA.

  18. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    SciTech Connect (OSTI)

    Apel, E.; Springston, S.; Karl, T.; Emmons, L.; Flocke, F.; Hills, A. J.; Madronich, S.; Lee-Taylor, J.; Fried, A.; Weibring, P.; Walega, J.; Richter, D., Tie, X.; Mauldin, L.; Campos, T.; Sive, B.; Kleinman, L.; Springston, S., Zaveri, R.; deGouw, J.; Zheng, J.; Zhang, R.; Rudolph, J.; Junkermann, W.; Riemer, D. D.

    2009-11-01

    The volatile organic compound (VOC) distribution in the Mexico City Metropolitan Area (MCMA) and its evolution as it is uplifted and transported out of the MCMA basin was studied during the 2006 MILAGRO/MIRAGE-Mex field campaign. The results show that in the morning hours in the city center, the VOC distribution is dominated by non-methane hydrocarbons (NMHCs) but with a substantial contribution from oxygenated volatile organic compounds (OVOCs), predominantly from primary emissions. Alkanes account for a large part of the NMHC distribution in terms of mixing ratios. In terms of reactivity, NMHCs also dominate overall, especially in the morning hours. However, in the afternoon, as the boundary layer lifts and air is mixed and aged within the basin, the distribution changes as secondary products are formed. The WRF-Chem (Weather Research and Forecasting with Chemistry) model and MOZART (Model for Ozone and Related chemical Tracers) were able to reproduce the general features of the daytime cycle of the VOC OH reactivity distribution showing that NMHCs dominate the distribution except in the afternoon hours and that the VOC OH reactivity peaks in the early morning due to high morning emissions from the city into a shallow boundary layer. The WRF-Chem and MOZART models showed higher reactivity than the experimental data during the nighttime cycle, perhaps indicating problems with the modeled nighttime boundary layer height. In addition, a plume was studied in which air was advected out of the MCMA and intercepted downwind with the DOE G1 on 18 March and the NCAR C130 one day later on 19 March. A number of identical species measured aboard each aircraft gave insight into the chemical evolution of the plume as it aged and was transported as far as 1000 km downwind. Ozone and many OVOCs were photochemically produced in the plume. The WRF-Chem and MOZART models were used to examine the spatial and temporal extent of the 19 March plume and to help interpret the OH reactivity in the downwind plume. The model results generally showed good agreement with experimental results for the total VOC OH reactivity downwind and gave insight into the distributions of VOC chemical classes downwind. A box model with detailed gas phase chemistry (NCAR Master Mechanism), initialized with concentrations observed at one of the ground sites in the MCMA, was used to examine the expected evolution of specific VOCs over a 1-2 day period. The models clearly supported the experimental evidence for NMHC oxidation leading to the formation of OVOCs downwind, which then become the primary fuel for ozone production far away from the MCMA.

  19. Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, M. J.; Zoerb, M. C.; Campbell, N. R.; Zimmermann, K. J.; Blomquist, B. W.; Huebert, B. J.; Bertram, T. H.

    2015-10-01

    Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory characterization was performed using both a new set of compounds (i.e. DMS, ?-caryophyllene) as well as previously studied VOCs (i.e., isoprene, ?-pinene). Using a field deployable chemical ionization time-of-flight mass spectrometer (CI-ToFMS), benzene cluster cations demonstrated high sensitivity (> 1 ncps ppt?1) to DMS, isoprene, and ?-pinene standards. Parallel measurements conducted using a chemical-ionization quadrupole mass spectrometer, with a weaker electric field, demonstrated that ion-molecule reactions likely proceed through amore »combination of ligand-switching and direct charge transfer mechanisms. Laboratory tests suggest that benzene cluster cations may be suitable for the selective ionization of sesquiterpenes, where minimal fragmentation (R2=0.80) over a wide range of sampling conditions.« less

  20. Volatile organic compound and particulate emission studies of AF (Air Force) paint-booth facilities. Phase 1. Final report, February-December 1987

    SciTech Connect (OSTI)

    Ayer, J.; Wolbach, D.

    1988-07-01

    This study presents the results of volatile organic compound (VOC) and particulate emission surveys performed at three Air Force painting facilities. The three facilities -- one in McClellan AFB buildings 655 and two at Travis AFB in buildings 550 and 1014 -- did not meet local VOC emission standards. The possibility of reducing these emissions with recirculation modifications and various VOC reduction and control strategies is discussed. Although VOC emissions from paint spray booths can be controlled by add-on control systems, control is expensive for present air flow rates. The use of air recirculation within the spray booth can reduce the cost of VOC emission controls by reducing the quantity of air that requires processing. Recirculation systems were designed for two of the painting facilities included in this study. In designing the systems, various criteria such as paint booth VOC concentrations and health and safety standards were considered. Add-on VOC emission-control systems that can be used in conjunction with the recirculation system are evaluated. The devices of interest are a solvent incineration system and an activated-carbon adsorption bed. The VOC removal efficiency, initial capital investment and operating costs for both of these technologies are discussed.

  1. Advanced heat pump for the recovery of volatile organic compounds. Phase 1, Conceptual design of an advanced Brayton cycle heat pump for the recovery of volatile organic compounds: Final report

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    Emissions of Volatile Organic Compounds (VOC) from stationary industrial and commercial sources represent a substantial portion of the total US VOC emissions. The ``Toxic-Release Inventory`` of The US Environmental Protection Agency estimates this to be at about 3 billion pounds per year (1987 estimates). The majority of these VOC emissions are from coating processes, cleaning processes, polymer production, fuel production and distribution, foam blowing,refrigerant production, and wood products production. The US Department of Energy`s (DOE) interest in the recovery of VOC stems from the energy embodied in the recovered solvents and the energy required to dispose of them in an environmentally acceptable manner. This Phase I report documents 3M`s work in close working relationship with its subcontractor Nuclear Consulting Services (Nucon) for the preliminary conceptual design of an advanced Brayton cycle heat pump for the recovery of VOC. Nucon designed Brayton cycle heat pump for the recovery of methyl ethyl ketone and toluene from coating operations at 3M Weatherford, OK, was used as a base line for the work under cooperative agreement between 3M and ODE. See appendix A and reference (4) by Kovach of Nucon. This cooperative agreement report evaluates and compares an advanced Brayton cycle heat pump for solvent recovery with other competing technologies for solvent recovery and reuse. This advanced Brayton cycle heat pump is simple (very few components), highly reliable (off the shelf components), energy efficient and economically priced.

  2. Formation and aging of secondary organic aerosol from toluene: changes in chemical composition, volatility, and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K. M.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2015-07-24

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form secondary organic aerosol (SOA) from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx under different oxidizing conditions. The effects of the oxidizing condition on organic aerosol (OA) composition, mass yield, volatility, and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state (OSc), and mass yield. The OA oxidation state generally increased duringmore »photo-oxidation, and the final OA OSc ranged from -0.29 to 0.16 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have a significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  3. Best available control technology (BACT) equivalent for the control of volatile organic emissions from paint dipping operations

    SciTech Connect (OSTI)

    Blankenship, W.R.; Pugh, C.W. Jr.

    1999-07-01

    This paper provides details of a study conducted to demonstrate an equivalent method of Best Available Control Technology (BACT) compliance for volatile organic emissions from dip coating of certain miscellaneous metal parts. The study was proposed to show that the total volatile organic compound (VOC) emissions from 3.8 lb of VOC/gallon coating formulations were no greater than the total VOC emissions from 3.5 lb/gallon formulations used under the same conditions for coating steel joists. The presumptive BACT standard enforced by the Virginia Department of Environmental Quality (DEQ) for dip coating of steel joists is 3.5 lb/gallon. The requirement of 3.5 lb/gallon was derived from the US Environmental Protection Agency Guideline Series Control of Volatile Organic Emissions from Existing Stationary Sources--Volume 6: Surface Coating of Miscellaneous Metal Parts and Products. On June 5, 1998 the source completed a 12 month, full scale comparison study under a consent order with the Virginia DEQ. During the study period, the source made daily measurements of product produced, paint used, and emissions from the control and test paint tanks, and reported data to EPA and the DEQ every two months. The study concluded that a 26 percent reduction in paint usage and a 20 percent reduction in emissions was achieved in the test tanks using a 3.8 lb/gal coating compared to the control tanks using a 3.5 lb/gal coating. This study enables the source to achieve greater emission reductions than the presumptive BACT level and at the same time reduce painting costs by 34%. This study provides positive results for the environment, the steel joist industry, and the construction industry. This study could impact EPA's current Maximum Achievable Control Technology (MACT) rule development for Miscellaneous Metal Parts and Products and national VOC rules for this source category under Section 183(e) of the Clean Air Act.

  4. Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: Measurement comparison, emission ratios, and source attribution

    SciTech Connect (OSTI)

    Bon, D.M.; Springston, S.; M.Ulbrich, I.; de Gouw, J. A.; Warneke, C.; Kuster, W. C.; Alexander, M. L.; Baker, A.; Beyersdorf, A. J.; Blake, D.; Fall, R.; Jimenez, J. L., Herndon, S. C.; Huey, L. G.; Knighton, W. B.; Ortega, J.; Vargas, O.

    2011-03-16

    Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements and to aid in the identification of unknown VOCs. The VOC measurements are also compared to simultaneous canister samples and to two independent proton-transfer-reaction mass spectrometers (PTR-MS) deployed on a mobile and an airborne platform during MILAGRO. VOC diurnal cycles demonstrate the large influence of vehicle traffic and liquid propane gas (LPG) emissions during the night and photochemical processing during the afternoon. Emission ratios for VOCs and OVOCs relative to CO are derived from early-morning measurements. Average emission ratios for non-oxygenated species relative to CO are on average a factor of {approx}2 higher than measured for US cities. Emission ratios for OVOCs are estimated and compared to literature values the northeastern US and to tunnel studies in California. Positive matrix factorization analysis (PMF) is used to provide insight into VOC sources and processing. Three PMF factors were distinguished by the analysis including the emissions from vehicles, the use of liquid propane gas and the production of secondary VOCs + long-lived species. Emission ratios to CO calculated from the results of PMF analysis are compared to emission ratios calculated directly from measurements. The total PIT-MS signal is summed to estimate the fraction of identified versus unidentified VOC species.

  5. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1998-06-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  6. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers. Revision 1

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1995-08-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering Laboratory (INEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  7. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30F In Vitro Genotoxicity of Particulate...

  8. Online measurements of the emissions of intermediate-volatility and semi-volatile organic compounds from aircraft

    E-Print Network [OSTI]

    Herndon, S. C.

    A detailed understanding of the climate and air quality impacts of aviation requires measurements of the emissions of intermediate-volatility and semi-volatile organic compounds (I/SVOCs) from aircraft. Currently both the ...

  9. Evaluation of low-VOC latex paints

    SciTech Connect (OSTI)

    Chang, J.C.S.; Fortmann, R.C.; Roache, N.F.; Lao, H.C.

    1999-11-01

    The paper gives results of an evaluation of four commercially available low-VOC (volatile organic compound) latex paints as substitutes for conventional latex paints by assessing both their emission characteristics and their performance as coatings. Bulk analysis indicated that the VOC contents of all four paints are considerably lower than those of conventional latex paints. Low-VOC emissions were confirmed by small chamber emission tests. However, sigificant emissions of several aldehydes, especially formaldehyde, were detected from two of the paints. ASTM methods were used to evaluate the hiding power, scrubbability, washability, dry to touch, and yellowing index. The results indicated that one of the low-VOC paints tested showed performance equivalent or superior to that of a widely used conventional latex paint used as a control. It was concluded that low-VOC latex paint can be a viable option to replace conventional latex paints for prevention of indoor air pollution. However, paints marketed as low-VOC may still have significant emissions of some individual VOCs, and some may not have performance characteristics matching those of conventional latex paints.

  10. Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Performance Building

    SciTech Connect (OSTI)

    Ortiz, Anna C.; Russell, Marion; Lee, Wen-Yee; Apte, Michael; Maddalena, Randy

    2010-09-20

    The developers of the Paharpur Business Center (PBC) and Software Technology Incubator Park in New Delhi, India offer an environmentally sustainable building with a strong emphasis on energy conservation, waste minimization and superior indoor air quality (IAQ). To achieve the IAQ goal, the building utilizes a series of air cleaning technologies for treating the air entering the building. These technologies include an initial water wash followed by ultraviolet light treatment and biolfiltration using a greenhouse located on the roof and numerous plants distributed throughout the building. Even with the extensive treatment of makeup air and room air in the PBC, a recent study found that the concentrations of common volatile organic compounds and aldehydes appear to rise incrementally as the air passes through the building from the supply to the exhaust. This finding highlights the need to consider the minimization of chemical sources in buildings in combination with the use of advanced air cleaning technologies when seeking to achieve superior IAQ. The goal of this project was to identify potential source materials for indoor chemicals in the PBC. Samples of building materials, including wood paneling (polished and unpolished), drywall, and plastic from a hydroponic drum that was part of the air cleaning system, were collected from the building for testing. All materials were collected from the PBC building and shipped to the Lawrence Berkeley National Laboratory (LBNL) for testing. The materials were pre-conditioned for two different time periods before measuring material and chemical specific emission factors for a range of VOCs and Aldehydes. Of the six materials tested, we found that the highest emitter of formaldehyde was new plywood paneling. Although polish and paint contribute to some VOC emissions, the main influence of the polish was in altering the capacity of the surface to accumulate formaldehyde. Neither the new nor aged polish contributed significantly to formaldehyde emissions. The VOC emission stream (excluding formaldehyde) was composed of up to 18 different chemicals and the total VOC emissions ranged in magnitude from 7 mu g/m2/h (old wood with old polish) to>500 mu g/m2/h (painted drywall). The formaldehyde emissions from drywall and old wood with either new or old polish were ~;;15 mu g/m2/h while the new wood material emitted>100 mu g/m2/h. However, when the projected surface area of each material in the building was considered, the new wood, old wood and painted drywall material all contributed substantially to the indoor formaldehyde loading while the coatings contributed primarily to the VOCs.

  11. Ventilation Control of Volatile Organic Compounds in New U.S. Homes: Results of a Controlled Field Study in Nine Residential Units

    SciTech Connect (OSTI)

    Willem, Henry; Hult, Erin L.; Hotchi, Toshifumi; Russell, Marion L.; Maddalena, Randy L.; Singer, Brett C.

    2013-01-01

    In order to optimize strategies to remove airborne contaminants in residences, it is necessary to determine how contaminant concentrations respond to changes in the air exchange rate. The impact of air exchange rate on the indoor concentrations of 39 target volatile organic compounds (VOCs) was assessed by measuring air exchange rates and VOC concentrations at three ventilation settings in nine residences. Active sampling methods were used for VOC concentration measurements, and passive perfluorocarbon tracer gas emitters with active sampling were used to determine the overall air exchange rate corresponding to the VOC measurements at each ventilation setting. The concentration levels and emission rates of the target VOCs varied by as much as two orders of magnitude across sites. Aldehyde and terpene compounds were typically the chemical classes with highest concentrations, followed by alkanes, aromatics, and siloxanes. For each home, VOC concentrations tended to decrease as the air exchange rate was increased, however, measurement uncertainty was significant. The indoor concentration was inversely proportional to air exchange rate for most compounds. For a subset of compounds including formaldehyde, however, the indoor concentration exhibited a non-linear dependence on the timescale for air exchange

  12. Final disposal of VOCs from industrial wastewaters

    SciTech Connect (OSTI)

    Ying, W.; Bonk, R.R.; Hannam, S.C. (Occidential Chemical Corp., Grand Island, NY (United States)); Qi-dong Li (Fudan Univ., Shanghai (China))

    1994-08-01

    Vapor phase carbon adsorption followed by spent carbon regeneration and catalytic oxidation were evaluated as methods for disposal of volatile organic compounds (VOCs) released from industrial wastewaters during treatment operations such as aeration, air-stripping and aerobic biodegradation. Adsorptive capacities and breakthrough characteristics for eight VOCs found in many hazardous landfill leachates and contaminated groundwater were compared for selection of the best adsorbent and optimum treatment conditions. Coconut shell-based activated carbons exhibited higher VOC loading capacities than coal-based carbons, fiber carbon, molecular sieve and zeolite. Steam and hot nitrogen were both effective for regeneration of the spent carbon. A small quantity of adsorbates left in the regenerated carbon did not result in immediate VOC breakthrough in the next cycle adsorption treatment. Catalytic oxidation was found to be an attractive alternative for VOC disposal. Using a new commercial catalyst developed for destruction of halogenated organic compounds, even stable VOCs such as trichloroethylene and tetrachloroethylene were completely destroyed at <350[degrees]C when oxidation was conducted at a space velocity of 17000/hr. 25 refs., 10 figs., 10 tabs.

  13. Sorption of selected volatile organic constituents of jet fuels and solvents on natural sorbents from gas and solutions phases. Final report, April 1985-September 1987

    SciTech Connect (OSTI)

    Rao, P.S.; Rhue, R.D.; Johnson, C.T.; Oguada, R.A.

    1988-08-01

    Sorption of selected volatile organic constituents (VOC) of jet fuels and solvents on several natural sorbents from the gas and aqueous phases was investigated. The sorbates studied were: trans-1,2-dichloroethylene; 1,2-dichloroethane; trichloroethylene; 1,1,2,2-tetrachloroethane; toluene; ethylbenzene; p-xylene; o-xylene; and cyclohexane. The sorbents used included clays (kaolin, montmorillonite, SAz-1), soils (Webster and Oldsmar), and aquifer materials (Borden and Lula). Sorption from the vapor phase was studied using three techniques; the headspace analysis method, dynamic-flow method, and a gas chromatographic method. Sorption of VOC on anhydrous sorbents and sorbents in equilibrium with water at different relative humidities was examined. The energetics of sorption were characterized by measuring VOC sorption at several temperatures.

  14. Evaluation of emplacement sensors for detecting radiation and volatile organic compounds and for long-term monitoring access tubes for the BWCS

    SciTech Connect (OSTI)

    Lord, D.L.; Averill, R.H.

    1997-10-01

    This document evaluates sensors for detecting contaminants in the excavated waste generated by the Buried Waste Containment System (BWCS). The Barrier Placement Machine (BPM) removes spoils from under a landfill or plume and places it on a conveyor belt on the left and right sides of the BPM. The spoils will travel down the conveyor belts past assay monitors and be deposited on top of the site being worked. The belts are 5 ft wide and transport approximately 15 ft3 /minute of spoils. This corresponds to a 10 ft per hour BPM advance rate. With a 2 in. spoils height the belt speed would be 3.6 in. per second. The spoils being removed are expected to be {open_quotes}clean{close_quotes} (no radiation or volatile organics above background levels). To ensure that the equipment is not digging through a contaminated area, assay equipment will monitor the spoils for mg radiation and volatile organic compounds (VOCs). The radiation monitors will check for gross radiation indication. Upon detection of radiation levels above a predetermined setpoint, further evaluation will be performed to determine the isotopes present and their quantity. This will require hand held monitors and a remote monitoring station. Simultaneously, VOC monitors will monitor for predetermined volatile/semi-volatile organic compounds. A Fourier-Transform Infrared Spectrometer (FTIR) monitor is recommended for this operation. Specific site requirements and regulations will determine setpoints and operation scenarios. If VOCs are detected, the data will be collected and recorded. A flat panel display will be mounted in the BPM operator`s cab showing the radio nuclide and VOC monitoring data. As the BPM advances, a 3-in. diameter PVC tube will be placed on the bottom of the barrier slot in front of the 12 to 16-in. containment barrier being emplaced.

  15. Numerical modeling of VOC emissions from ozone reactions with human-worn clothing in an aircraft cabin

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    300072, China *Tel. (765)496-7562, Fax (765)494-0539, Email: yanchen@purdue.edu Abstract Volatile organic to VOCs, their concentrations in the breathing zones should be used. 1. Introduction Volatile organic). These compounds are emitted as gases from a variety of indoor materials such as paints, furniture, and building

  16. Glossary of Volatile Organic Compounds Ethylbenzene Carbon tetrachloride

    E-Print Network [OSTI]

    Glossary of Volatile Organic Compounds · Ethylbenzene · Carbon tetrachloride · Benzene · 1 and petroleum. It is also found in manufactured products such as inks, insecticides, and paints. Ethylbenzene, carpet glues, varnishes and paints, and use of tobacco. Some people are exposed to ethylbenzene at work

  17. Volatile Organic Compounds in Untreated Ambient Groundwater of

    E-Print Network [OSTI]

    Volatile Organic Compounds in Untreated Ambient Groundwater of the United States, 1985-1995 P A U L, ambient groundwater of the conterminous United States was conducted based on samples collected from 2948-chloropropane, which had a reporting level of 1.0 µg/L. Because ambient groundwater was targeted, areas of known

  18. Improved land cover and emission factors for modeling biogenic volatile organic compounds emissions from Hong Kong

    E-Print Network [OSTI]

    Leung, DYC; Wong, P; Cheung, BKH; Guenther, A

    2010-01-01

    organic compounds emissions in Hong Kong. Atmosphericvolatile organic compounds emission inventory for Beijing.volatile organic compound emissions. Journal of Geophysical

  19. ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS ? FINAL REPORT

    SciTech Connect (OSTI)

    Salazar, Olivia; Maddalena, Randy L.; Russell, Marion; Sullivan, Douglas P.; Apte, Michael G.

    2008-05-04

    Four unoccupied FEMA temporary housing units (THUs) were studied to assess their indoor emissions of volatile organic compounds including formaldehyde. Measurement of whole-THU VOC and aldehyde emission factors (mu g h-1 per m2 of floor area) for each of the four THUs were made at FEMA's Purvis MS staging yard using a mass balance approach. Measurements were made in the morning, and again in the afternoon in each THU. Steady-state indoor formaldehyde concentrations ranged from 378 mu g m-3 (0.31ppm) to 632 mu g m-3 (0.52 ppm) in the AM, and from 433 mu g m-3 (0.35 ppm) to 926 mu g m-3 (0.78 ppm) in the PM. THU air exchange rates ranged from 0.15 h-1 to 0.39 h-1. A total of 45 small (approximately 0.025 m2) samples of surface material, 16 types, were collected directly from the four THUs and shipped to Lawrence Berkeley Laboratory. The material samples were analyzed for VOC and aldehyde emissions in small stainless steel chambers using a standard, accurate mass balance method. Quantification of VOCs was done via gas chromatography -- mass spectrometry and low molecular weight aldehydes via high performance liquid chromatography. Material specific emission factors (mu g h-1 per m2 of material) were quantified. Approximately 80 unique VOCs were tentatively identified in the THU field samples, of which forty-five were quantified either because of their toxicological significance or because their concentrations were high. Whole-trailer and material specific emission factors were calculated for 33 compounds. The THU emission factors and those from their component materials were compared against those measured from other types of housing and the materials used in their construction. Whole THU emission factors for most VOCs were typically similar to those from comparative housing. The three exceptions were exceptionally large emissions of formaldehyde and TMPD-DIB (a common plasticizer in vinyl products), and somewhat elevated for phenol. Of these three compounds, formaldehyde was the only one with toxicological significance at the observed concentrations. Whole THU formaldehyde emissions ranged from 173 to 266 mu g m-2 h 1 in the morning and 257 to 347 mu g m-2 h-1 in the afternoon. Median formaldehyde emissions in previously studied site-built and manufactured homes were 31 and 45 mu g m-2 h-1, respectively. Only one of the composite wood materials that was tested appeared to exceed the HUD formaldehyde emission standard (430 mu g/m2 h-1 for particleboard and 130 mu g/m2 h-1 for plywood). The high loading factor (material surface area divided by THU volume) of composite wood products in the THUs and the low fresh air exchange relative to the material surface area may be responsible for the excessive concentrations observed for some of the VOCs and formaldehyde.

  20. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nick; Farron, Carrie; Foster, David E.; Andrie, Mike; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs) from an aerosol sample. One method is a Dekati Thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented for this project in an engine test cell built around a direct injection spark ignited (DISI) engine. The engine was designed for stoichiometric, homogeneous combustion. Direct injection is of particular interest for improved fuel efficiency but this comes with the production of a significant amount of (PM) and may therefore be subject to the proposed number based regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition. The first interesting observation is that PM number distributions, acquired using a TSI SMPS, have a large accumulation mode (30-294 nm) but a very small nuclei mode (8-30 nm). This is understood to represent a lack of condensation particles meaning that neither the exhaust conditions nor the sample handling conditions are conducive to condensation. This lack of nuclei mode does not, however, represent a lack of VOCs in the sample. It has been observed, using mass spectral analysis (limited to PM>50 nm), that PM from the DISI engine has approximately 40% organic content through varying operating conditions. This begs the question of how effective different sample handling methods are at removing these VOCs. For one specific operating condition, called Cold Start, the un-treated PM was 40% organic. The TD reduced this by 7% while the EvCh reduced it by 13%. For other operating conditions, PM treated for volatile removal actually exhibited an increase in organic fraction on the order of 5%. This addition appears to be sensitive to the gaseous hydrocarbon concentrations in the exhaust although a precise correlation has not yet been derived. It has been concluded that VOCs are tightly bound to the PM carbon core and thus are not effectively removed by either treatment method.

  1. A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution

    E-Print Network [OSTI]

    Donahue, Neil M.

    We discuss the use of a two-dimensional volatility-oxidation space (2-D-VBS) to describe organic-aerosol chemical evolution. The space is built around two coordinates, volatility and the degree of oxidation, both of which ...

  2. Oxidation of atmospheric organic carbon : interconnecting volatile organic compounds, intermediate-volatility organic compounds, and organic aerosol

    E-Print Network [OSTI]

    Hunter, James Freeman

    2015-01-01

    .Organic molecules have many important roles in the atmosphere, acting as climate and biogeochemical forcers, and in some cases as toxic pollutants. The lifecycle of atmospheric organic carbon is extremely complex, with ...

  3. Maximizing Information from Residential Measurements of Volatile Organic Compounds

    SciTech Connect (OSTI)

    Maddalena, Randy; Li, Na; Hodgson, Alfred; Offermann, Francis; Singer, Brett

    2013-02-01

    Continually changing materials used in home construction and finishing can introduce new chemicals or changes in the VOC profile in residential air and the trend towards tighter homes can lead to higher exposure concentrations for many indoor sources. However, the complex mixture of VOCs in residential air makes it difficult to discover emerging contaminants and/or trends in pollutant profiles. The purpose of this study is to prepare a comprehensive library of chemicals found in homes, along with a semi-quantitative approach to maximize the information gained from VOC measurements. We carefully reviewed data from 108 new California homes and identified 238 individual compounds. The majority of the identified VOCs originated indoors. Only 31% were found to have relevant health based exposure guidelines and less than 10% had a chronic reference exposure level (CREL). The finding highlights the importance of extending IAQ studies to include a wider range of VOCs

  4. Impacts of simulated herbivory on volatile organic compound emission profiles from coniferous plants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faiola, C. L.; Jobson, B. T.; VanReken, T. M.

    2015-01-28

    The largest global source of volatile organic compounds (VOCs) in the atmosphere is from biogenic emissions. Plant stressors associated with a changing environment can alter both the quantity and composition of the compounds that are emitted. This study investigated the effects of one global change stressor, increased herbivory, on plant emissions from five different coniferous species: bristlecone pine (Pinus aristata), blue spruce (Picea pungens), western redcedar (Thuja plicata), grand fir (Abies grandis), and Douglas-fir (Pseudotsuga menziesii). Herbivory was simulated in the laboratory via exogenous application of methyl jasmonate (MeJA), a herbivory proxy. Gas-phase species were measured continuously with a gasmore »chromatograph coupled to a mass spectrometer and flame ionization detector (GC–MS–FID). Stress responses varied between the different plant types and even between experiments using the same set of saplings. The compounds most frequently impacted by the stress treatment were alpha-pinene, beta-pinene, 1,8-cineol, beta-myrcene, terpinolene, limonene, and the cymene isomers. Individual compounds within a single experiment often exhibited a different response to the treatment from one another.« less

  5. Field demonstration and transition of SCAPS direct push VOC in-situ sensing technologies

    SciTech Connect (OSTI)

    William M. Davis

    1999-11-03

    This project demonstrated two in-situ volatile organic compound (VOC) samplers in combination with the direct sampling ion trap mass spectrometer (DSITMS). The technologies chosen were the Vadose Sparge and the Membrane Interface Probe (MIP) sensing systems. Tests at two demonstration sites showed the newer VOC technologies capable of providing in situ contaminant measurements at two to four times the rate of the previously demonstrated Hydrosparge sensor. The results of this project provide initial results supporting the utility of these new technologies to provide rapid site characterization of VOC contaminants in the subsurface.

  6. Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong

    E-Print Network [OSTI]

    2009-01-01

    anthropogenic sources on carbonyl sulfide in Beijing City,Measurements of carbonyl sulfide in automotive emissions andThese include CO, CO 2 , carbonyl sulfide (OCS), carbon

  7. Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong

    E-Print Network [OSTI]

    2009-01-01

    7504, 2009 petroleum gas (LPG), gasoline, and diesel are thevehicles, while diesel and LPG fueled vehicles accounted forShing Mun Tunnel, Hong Kong LPG, gasoline, and diesel ethene

  8. Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong

    E-Print Network [OSTI]

    2009-01-01

    LPG, gasoline, and diesel ethene toluene n-butane propane i-pentane i-butane propene benzene ethyne 1,2,4-order, ethene, toluene, n-butane, propane and i-pentane.

  9. Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong

    E-Print Network [OSTI]

    2009-01-01

    1-pentene 2-methylpentane ethane n-pentane 1-butene o-xylenethe ratios of ethene/ethane and m,p-xylene/ethylbenzene wereaverage value of ethene/ethane and m,p-xylene/ethylbenzene

  10. NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on771/6/14 Contact: Janet Lambert4NIEHS7, 2015 NMED Approves3 NMED

  11. Volatile Organic Compound Emissions from Dairy Cows and

    E-Print Network [OSTI]

    Goldstein, Allen

    , California 94720, and Department of Animal Science, University of California, Davis, Davis, California 95616 of California Senate Bill 700. The proposed SJV Air District Rule 4570 intends to reduce VOC emissions from

  12. Quantifying VOC emissions for the strategic petroleum reserve.

    SciTech Connect (OSTI)

    Knowlton, Robert G.; Lord, David L.

    2013-06-01

    A very important aspect of the Department of Energy's (DOE's) Strategic Petroleum Reserve (SPR) program is regulatory compliance. One of the regulatory compliance issues deals with limiting the amount of volatile organic compounds (VOCs) that are emitted into the atmosphere from brine wastes when they are discharged to brine holding ponds. The US Environmental Protection Agency (USEPA) has set limits on the amount of VOCs that can be discharged to the atmosphere. Several attempts have been made to quantify the VOC emissions associated with the brine ponds going back to the late 1970's. There are potential issues associated with each of these quantification efforts. Two efforts were made to quantify VOC emissions by analyzing VOC content of brine samples obtained from wells. Efforts to measure air concentrations were mentioned in historical reports but no data have been located to confirm these assertions. A modeling effort was also performed to quantify the VOC emissions. More recently in 2011- 2013, additional brine sampling has been performed to update the VOC emissions estimate. An analysis of the statistical confidence in these results is presented here. Arguably, there are uncertainties associated with each of these efforts. The analysis herein indicates that the upper confidence limit in VOC emissions based on recent brine sampling is very close to the 0.42 ton/MMB limit used historically on the project. Refining this estimate would require considerable investment in additional sampling, analysis, and monitoring. An analysis of the VOC emissions at each site suggests that additional discharges could be made and stay within current regulatory limits.

  13. ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT

    E-Print Network [OSTI]

    volatile organic compounds (VOCs) and toxic air pollutants emitted from wastewater and solids handling Management District (SC-AQMD). Contaminated air at POTWs contains two major groups of pollutants: reduced the use of microorganisms that convert air pollutants into harmless end-products. Treatment costs

  14. Technical Assistance to Ohio Closure Sites Technologies to Address Excavated VOC Contaminated Soil

    E-Print Network [OSTI]

    Hazen, Terry

    bioremediation, thermal desorption, vacuum desorption, chemical oxidation, incineration, and DNAPL removal Soil from Areas 3A/4A and Plant 6 at Fernald Environmental Management Project, Ohio Technical volatile organic compound (VOC) contaminated soils. The technical assistance team was composed of technical

  15. Control of VOC emissions from ink and paint manufacturing processes. Final report

    SciTech Connect (OSTI)

    McMinn, B.W.; Marsosudiro, P.J.

    1992-04-01

    The document presents the results of a study to collect and report information on processes used to manufacture paint and ink, volatile organic compound (VOC) emissions generated during these operations, emission control techniques and their effectiveness, and costs associated with process changes and emission control options.

  16. Volatile organic acids and microbial processes in the Yegua formation, east-central Texas

    E-Print Network [OSTI]

    Grossman, Ethan L.

    , 1982). Volatile organic acids such as acetic, propionic, iso- butyric, n-butyric, iso-valeric, and n volatile organic acids (VOA) in the Yegua formation. Acetic and propionic acid concentrations in mudstones modeled to estimate acetic acid transport from aquitard to aquifer. Assuming that SRB completely respire

  17. Volatile organic compound emissions from Larrea tridentata (creosotebush)

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    of these and other compounds, branch enclosure air was also analyzed for VOCs using thermal desorption gas chromatography-proton transfer reaction-mass spectrometry (GC-PTR-MS) in the field and thermal desorption gas, Oracle, AZ 85623, USA. [2] University of Arizona, Departments of Chemistry & Biochemistry and Soil, Water

  18. Evaluation of innovative volatile organic compound and hazardous air-pollutant-control technologies for U. S. Air Force paint spray booths. Final report, Aug 88-Aug 89

    SciTech Connect (OSTI)

    Ritts, D.H.; Garretson, C.; Hyde, C.; Lorelli, J.; Wolbach, C.D.

    1990-10-01

    Significant quantities of volatile organic compounds (VOCs) and hazardous air pollutants are released into the atmosphere during USAF maintenance operations. Painting operations conducted in paint spray booths are major sources of these pollutants. Solvent based epoxy primers and solvent-based polyurethane coatings are typically used by the Air Force for painting aircraft and associated equipment. Solvents used in these paints include methyl ethyl ketone (MEK), toluene, lacquer thinner, and other solvents involved in painting and component cleaning. In this report, carbon paper adsorption/catalytic incineration (CPACI) and fluidized-bed catalytic incineration (FBCI) were evaluated as control technologies to destroy VOC emissions from paint spray booths. Simultaneous testing of pilot-scale units was performed to evaluate the technical performance of both technologies. Results showed that each technology maintained greater than 99 percent Destruction and Removal Efficiencies (DREs). Particulate emissions from both pilot-scale units were less than 0.08 grains/dry standard cubic foot. Emissions of the criteria pollutants--sulfur oxides, nitrogen oxides, and carbon monoxide--were also below general regulatory standards for incinerators. Economic evaluations were based on a compilation of manufacturer-supplied data and energy consuption data gathered during the pilot scale testing. CPACM and FBCI technologies are less expensive than standard VOC control technologies when net present costs for a 15-year equipment life are compared.

  19. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  20. Volatile organic acids and microbial processes in the Yegua formation, east-central Texas 

    E-Print Network [OSTI]

    Routh, J.; Grossman, E. L.; Ulrich, G. A.; Suflita, J. M.

    2000-01-01

    Geochemical and microbiological evidence indicates that viable microorganisms produce and consume volatile organic acids (VOA) in the Yegua formation. Acetic and propionic acid concentrations in mudstones range from 200 ...

  1. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul M.; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition.

  2. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition

  3. Mass transfer of volatile organic compounds from drinking water to indoor air: The role of residential dishwashers

    SciTech Connect (OSTI)

    Howard-Reed, C.; Corsi, R.L.; Moya, J.

    1999-07-01

    Contaminated tap water may be a source of volatile organic compounds (VOCs) in residential indoor air. To better understand the extent and impact of chemical emissions from this source, a two-phase mass balance model was developed based on mass transfer kinetics between each phase. Twenty-nine experiments were completed using a residential dishwasher to determine model parameters. During each experiment, inflow water was spiked with a cocktail of chemical tracers with a wide range of physicochemical properties. In each case, the effects of water temperature, detergent, and dish-loading pattern on chemical stripping efficiencies and mass transfer coefficients were determined. Dishwasher headspace ventilation rates were also measured using an isobutylene tracer gas. Chemical stripping efficiencies for a single cycle ranged from 18% to 55% for acetone, from 96% to 98% for toluene, and from 97% to 98% for ethylbenzene and were consistently 100% for cyclohexane. Experimental results indicate that dishwashers have a relatively low but continuous ventilation rate that results in significant chemical storage within the headspace of the dishwasher. In conjunction with relatively high mass transfer coefficients, low ventilation rates generally lead to emissions that are limited by equilibrium conditions after approximately 1--2 min of dishwasher operation.

  4. ARTIFACT FORMATION IN HIGH VOLUME SAMPLING OF VOC's AND SOLID ORGANIC COMPOUNDS.

    E-Print Network [OSTI]

    Boyer, Edmond

    when sampling polluted air. Purified air containing 180 ppbv ozone seems to destroy PAH according Atmospheriques, Boite 7059, UNIVERSITE PARIS 7, 2, place Jussieu, 75251 PARIS Cedex 05 ABSTRACT Pollutants from well äs solid (SOC's) organic compounds. High volume samplers are commonly used m air quality

  5. Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135

    SciTech Connect (OSTI)

    Michalski, Casey C.; DiSalvo, Rick; Boylan, John

    2013-07-01

    DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

  6. LOW TEMPERATURE VOC COMBUSTION OVER MANGANESE, COBALT AND ZINC ALPO4 MOLECULAR SIEVES

    SciTech Connect (OSTI)

    Rosemarie Szostak

    2003-03-06

    The objective of this project was to prepare microporous aluminophosphates containing magnesium, manganese, cobalt and zinc (MeAPOs) and to evaluate their performance as oxidation catalysts for the removal of low levels of volatile organic compounds (VOCs) from gas streams. The tasks to be accomplished were as follows: (1) To develop reliable synthesis methods for metal aluminophosphates containing manganese, cobalt and zinc in their framework; (2) To characterize these materials for crystallinity, phase purity, the location and nature of the incorporated metal in the framework; and (3) To evaluate the materials for their catalytic activities in the oxidation of volatile organic environmental pollutants.

  7. Method and apparatus for regenerating activated carbon containing an adsorbed volatile organic absorbate

    SciTech Connect (OSTI)

    Tiggelbeck, D.D.; Goyak, G.M.

    1993-07-27

    A method is described for regenerating spent activated carbon containing adsorbed volatile organic adsorbate comprising: establishing a confined downwardly moving bed of activated carbon; adding spent carbon to the top of said bed; introducing superheated steam into the bottom of said bed in contact with said carbon; recovering exit gas including predominantly superheated steam and volatilized adsorbate from the top of said bed; circulating a portion of said exit gas through a superheater and compressor to the bottom of said bed; withdrawing a portion of said exit gas through a cooler to condense steam and volatile adsorbate; continuously circulating superheated steam in a closed loop through said downwardly moving bed, said compressor and said superheater; recovering partially regenerated activated carbon containing residual volatile adsorbate from the bottom of said bed.

  8. A pulse combustion-based VOC destruction technique

    SciTech Connect (OSTI)

    Bramlette, T.T.; Keller, J.O.; Allendorf, M.A.; Barr, P.K.

    1992-01-01

    Herein we describe a recently initiated project to develop and demonstrate a novel technique for volatile organic compound (VOC) destruction that relies upon the unique characteristics of pulse combustors to effect a two-stage (thermal and catalytic) destruction process. The concept exploits both the high combustion intensity (energy release rate per unit volume) in the pulse combustor combustion chamber and the acoustic resonance in the pulse combustor tailpipe. High combustion intensity results from rapid fluid dynamic mixing, and will lead to compact, transportable designs; acoustic resonance results in significantly increased mass transport to the catalyst material, leading to high destruction efficiencies. The operation of a pulse combustor and its unique characteristics are described and illustrated with experimental data and theoretical calculations. The new pulse combustion-based VOC destruction system is discussed, and results from a preliminary feasibility study are presented.

  9. A pulse combustion-based VOC destruction technique

    SciTech Connect (OSTI)

    Bramlette, T.T.; Keller, J.O.; Allendorf, M.A.; Barr, P.K.

    1992-06-01

    Herein we describe a recently initiated project to develop and demonstrate a novel technique for volatile organic compound (VOC) destruction that relies upon the unique characteristics of pulse combustors to effect a two-stage (thermal and catalytic) destruction process. The concept exploits both the high combustion intensity (energy release rate per unit volume) in the pulse combustor combustion chamber and the acoustic resonance in the pulse combustor tailpipe. High combustion intensity results from rapid fluid dynamic mixing, and will lead to compact, transportable designs; acoustic resonance results in significantly increased mass transport to the catalyst material, leading to high destruction efficiencies. The operation of a pulse combustor and its unique characteristics are described and illustrated with experimental data and theoretical calculations. The new pulse combustion-based VOC destruction system is discussed, and results from a preliminary feasibility study are presented.

  10. Thermal engine driven heat pump for recovery of volatile organic compounds

    DOE Patents [OSTI]

    Drake, Richard L. (Schenectady, NY)

    1991-01-01

    The present invention relates to a method and apparatus for separating volatile organic compounds from a stream of process gas. An internal combustion engine drives a plurality of refrigeration systems, an electrical generator and an air compressor. The exhaust of the internal combustion engine drives an inert gas subsystem and a heater for the gas. A water jacket captures waste heat from the internal combustion engine and drives a second heater for the gas and possibly an additional refrigeration system for the supply of chilled water. The refrigeration systems mechanically driven by the internal combustion engine effect the precipitation of volatile organic compounds from the stream of gas.

  11. NICS report links VOCs to respiratory problems

    SciTech Connect (OSTI)

    Kirschner, E.

    1992-04-22

    Children who live near the chemical plants of Kanawha Valley, WV, suffer more acute and chronic respiratory aliments than those farther away, says a Harvard University School of Public Health report. In the $1-million, five-year study commissioned by the National Institute for Chemical Studies (NICS:Charleston, WV) and funded by the Environmental Protection Agency, proximity to chemical plants that emit volatile organic compounds (VOCs) was linked to higher incidence of asthma, acute eye irritation, shortness of breath, and chronic cough. The researchers say they adjusted for most other factors, such as parental smoking and petroleum. {open_quotes}The research hypothesis was whether children in the valley had more symptoms,{close_quotes} says NICS president Paul Hill. {open_quotes}Yes, there is a difference.{close_quotes} The study showed that some ailments were up to 28% more prevalent in children in the valley than in other Kanawha County children.

  12. Space-based formaldehyde measurements as constraints on volatile organic compound emissions in east and south Asia and implications

    E-Print Network [OSTI]

    Palmer, Paul

    Space-based formaldehyde measurements as constraints on volatile organic compound emissions in east a continuous 6-year record (1996­2001) of GOME satellite measurements of formaldehyde (HCHO) columns over east (2007), Space-based formaldehyde measurements as constraints on volatile organic compound emissions

  13. Modeling the VOC emissions from interior latex paint applied to gypsum board

    SciTech Connect (OSTI)

    Guo, Z.; Fortmann, R.; Marfiak, S.; Tichenor, B.; Sparks, L.

    1997-09-01

    The paper discusses modeling volatile organic compound (VOC) emissions from indoor latex paint applied to gypsum board. An empirical source model for a porous substrate was developed that takes both the wet- and dry-stage emission into consideration. Tests in the U.S. EPA`s Source Characterization Laboratory showed that common interior surfaces such as gypsum board and carpet could absorb significant amounts of latex paint VOCS from the air, and that they were re-emitted very slowly. An indoor air quality model incorporating the source model, an irreversible sink model, and the air movement data obtained from tracer gas tests made satisfactory predictions for the VOC levels in a test house.

  14. Analysis of the atmospheric distribution, sources, and sinks of oxygenated volatile organic chemicals based on

    E-Print Network [OSTI]

    Jacob, Daniel J.

    chemicals based on measurements over the Pacific during TRACE-P H. B. Singh,1 L. J. Salas,1 R. B. Chatfield measurements of a large number of oxygenated volatile organic chemicals (OVOC) were carried out in the Pacific of OVOC is comparable to that of methane and far exceeds that of NMHC. A comparison of these data

  15. Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds

    E-Print Network [OSTI]

    Ho, Cliff

    1 Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds Hazmat Spill Center, Nevada Test Site September 19-25, 2001 Clifford K. Ho Sandia National Laboratories Albuquerque-filled 55- gallon drum at the Hazmat Spill Center at the Nevada Test Site. Background and Objectives Tens

  16. Effect of moisture on air stripping of non volatile organic contaminants from soil 

    E-Print Network [OSTI]

    Alvarez, Roberto

    1991-01-01

    of the unsaturated soil zone by organic chemicals has been receiving considerable attention recently since it is the major source of ground water pollution. The main objective of this work was to study the viability of air stripping non volatile organic... in the solid phase. Phenol, an EPA priority pollutant which has been identified in ground water supplies, was the model contaminant. Studies involved stripping the contaminant from a column of Norwood/Westwood soil under several moisture conditions. Removal...

  17. Effects of NOx on the volatility of secondary organic aerosol from isoprene photooxidation

    SciTech Connect (OSTI)

    Xu, Lu; Kollman, Matthew S.; Song, Chen; Shilling, John E.; Ng, L. N.

    2014-01-28

    The effects of NOx on the volatility of the secondary organic aerosol (SOA) formed from isoprene photooxidation are investigated in environmental chamber experiments. Two types of experiments are performed. In HO2-dominant experiments, organic peroxy radicals (RO2) primarily react with HO2. In mixed experiments, RO2 reacts through multiple pathways. The volatility and oxidation state of isoprene SOA is sensitive to and displays a non-linear dependence on NOx levels. When initial NO/isoprene ratio is approximately 3 (ppbv:ppbv), SOA are shown to be most oxidized and least volatile, associated with the highest SOA yield. A High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) is applied to characterize the key chemical properties of aerosols. While the composition of SOA in mixed experiments does not change substantially over time, SOA become less volatile and more oxidized as oxidation progresses in HO2-dominant experiments. Analysis of the SOA composition suggests that the further reactions of organic peroxides and alcohols may produce carboxylic acids, which might play a strong role in SOA aging.

  18. Volatile Organic Compound Concentrations and Emission Rates in New Manufactured and Site-Built Houses

    SciTech Connect (OSTI)

    Armin Rudd

    2008-10-30

    This study was conducted with the primary objective of characterizing and comparing the airborne concentrations and the emission rates of total VOCs and selected individual VOCs, including formaldehyde, among a limited number of new manufactured and site-built houses.

  19. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    E-Print Network [OSTI]

    2010-01-01

    methanol, ethanol, formaldehyde, acetaldehyde), while higher VOCs are represented as a lumped alkane (BIGANE), lumped alkene (BIGENE) and lumped aromatic (

  20. VOCs in Non-Arid Soils Integrated Demonstration: Technology summary

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    The Volatile Organic Compounds (VOCs) in Non-Arid Soils Integrated Demonstration (ID) was initiated in 1989. Objectives for the ID were to test the integrated demonstration concept, demonstrate and evaluate innovative technologies/systems for the remediation of VOC contamination in soils and groundwater, and to transfer technologies and systems to internal and external customers for use in fullscale remediation programs. The demonstration brought together technologies from DOE laboratories, other government agencies, and industry for demonstration at a single test bed. The Savannah River Site was chosen as the location for this ID as the result of having soil and groundwater contaminated with VOCS. The primary contaminants, trichlorethylene and tetrachloroethylene, originated from an underground process sewer line servicing a metal fabrication facility at the M-Area. Some of the major technical accomplishments for the ID include the successful demonstration of the following: In situ air stripping coupled with horizontal wells to remediate sites through air injection and vacuum extraction; Crosshole geophysical tomography for mapping moisture content and lithologic properties of the contaminated media; In situ radio frequency and ohmic heating to increase mobility, of the contaminants, thereby speeding recovery and the remedial process; High-energy corona destruction of VOCs in the off-gas of vapor recovery wells; Application of a Brayton cycle heat pump to regenerate carbon adsorption media used to trap VOCs from the offgas of recovery wells; In situ permeable flow sensors and the colloidal borescope to determine groundwater flow; Chemical sensors to rapidly quantify chlorinated solvent contamination in the subsurface; In situ bioremediation through methane/nutrient injection to enhance degradation of contaminants by methanotrophic bateria.

  1. Measurement of surface emission flux rates for volatile organic compounds at Technical Area 54

    SciTech Connect (OSTI)

    Trujillo, V.; Morgenstern, M.; Krier, D. [Los Alamos National Lab., NM (United States); Gilkeson, R. [Weirich and Associates, Albuquerque, NM (United States)

    1998-06-01

    The survey described in this report was conducted to estimate the mass of volatile organic compounds venting to the atmosphere from active and inactive waste disposal sites at Technical Area 54. A large number of nonintrusive passive sample collection devices were placed on the ground surface for 72 hours to characterize an area of approximately 150 acres. Results provided an indication of the boundary location of the known volatile organic plume, plume constituents, and isolated high concentration areas. The data from this survey enhanced existing data from a limited number of monitor wells currently used for plume surveillance. Results indicate that the estimated mass emission to the atmosphere is orders of magnitude lower than what is considered a small flux rate at a spill site or a Resource Conservation and Recovery Act landfill and is far below the threshold limit established by the State of New Mexico as an air quality concern.

  2. Performance specifications for technology development: Application for characterization of volatile organic compounds in the environment

    SciTech Connect (OSTI)

    Carpenter, S.E.; Doskey, P.V.; Erickson, M.D.; Lindahl, P.C.

    1994-07-01

    This report contains information about technology development for the monitoring and remediation of environmental pollution caused by the release of volatile organic compounds. Topics discussed include: performance specification processes, gas chromatography, mass spectrometer, fiber-optic chemical sensors, infrared spectroscopy, Raman spectroscopy, piezoelectric sensors and electrochemical sensors. These methods are analyzed for their cost efficiency, accuracy, and the ability to meet the needs of the customer.

  3. Phase partitioning and volatility of secondary organic aerosol components formed from ?-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore »and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the conversion of lower volatility components into the detected higher volatility compounds.« less

  4. Phase partitioning and volatility of secondary organic aerosol components formed from ?-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A. J.; Daumit, K. E.; Hunter, J. F.; et al

    2015-07-16

    We measured a large suite of gas- and particle-phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gas andmore »particle phases, the latter being detected by temperature-programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO–HR-ToF-CIMS are highly correlated with, and explain at least 25–50 % of, the organic aerosol mass measured by an Aerodyne aerosol mass spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from high molecular weight organics and/or oligomers (i.e., multi-phase accretion reaction products). Approximately 50 % of the HR-ToF-CIMS particle-phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption-temperature-based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas-particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the conversion of lower volatility components into the detected higher volatility compounds.« less

  5. Field evaluation of ground water sampling devices for volatile organic compounds

    SciTech Connect (OSTI)

    Muska, C F; Colven, W P; Jones, V D; Scogin, J T; Looney, B B; Price, V Jr

    1986-01-01

    Previous studies conducted under laboratory conditions demonstrated that the type of device used to sample ground water contaminated with volatile organic compounds can significantly influence and analytical results. The purpose of this study was to evaluate, under field conditions, both commercial and developmental ground water sampling devices as part of an ongoing ground water contamination investigation and remediation program at the Savannah River Plant (SRP). Ground water samples were collected using six types of sampling devices in monitoring wells of different depths and concentrations of volatile organic contaminants (primarily trichloroethylene and tetrachloroethylene). The study matrix was designed to statistically compare the reuslts of each sampling device under the test conditions. Quantitative and qualitative evaluation criteria were used to determine the relative performance of each device. Two categories of sampling devices were evaluated in this field study, positive displacement pumps and grab samplers. The positive displacement pumps consisted of a centrifugal (mechanical) pump and a bladder pump. The grab samples tested were a syringe sampler, a dual-check valve bailer, a surface bomb sampler, and a pressurized bailer. Preliminary studies were conducted to establish the analytical and sampling variability associated with each device. All six devices were then used to collect ground water samples in water table (unconfined), semi-confined aquifer, and confined aquifer monitoring wells. Results were evaluated against a set of criteria that included intrasampling device variability (precision), volatile organic concentration (accuracy), sampling and analytical logistics, and cost. The study showed that, by using careful and reproducible procedures, overall sampling variability is low regardless of sampling device.

  6. VOC and HAP recovery using ionic liquids

    SciTech Connect (OSTI)

    Michael R. Milota : Kaichang Li

    2007-05-29

    During the manufacture of wood composites, paper, and to a lesser extent, lumber, large amounts of volatile organic compounds (VOCs) such as terpenes, formaldehyde, and methanol are emitted to air. Some of these compounds are hazardous air pollutants (HAPs). The air pollutants produced in the forest products industry are difficult to manage because the concentrations are very low. Presently, regenerative thermal oxidizers (RTOs and RCOs) are commonly used for the destruction of VOCs and HAPs. RTOs consume large amounts of natural gas to heat air and moisture. The combustion of natural gas generates increased CO2 and NOx, which have negative implications for global warming and air quality. The aforementioned problems are addressed by an absorption system containing a room-temperature ionic liquid (RTIL) as an absorbent. RTILs are salts, but are in liquid states at room temperature. RTILs, an emerging technology, are receiving much attention as replacements for organic solvents in industrial processes with significant cost and environmental benefits. Some of these processes include organic synthesis, extraction, and metal deposition. RTILs would be excellent absorbents for exhausts from wood products facilities because of their unique properties: no measurable vapor pressure, high solubility of wide range of organic compounds, thermal stability to 200°C (almost 400°F), and immisciblity with water. Room temperature ionic liquids were tested as possible absorbents. Four were imidizolium-based and were eight phosphonium-based. The imidizolium-based ionic liquids proved to be unstable at the conditions tested and in the presence of water. The phosphonium-based ionic liquids were stable. Most were good absorbents; however, cleaning the contaminates from the ionic liquids was problematic. This was overcome with a higher temperature (120°C) than originally proposed and a very low pressure (1 kPa. Absorption trials were conducted with tetradecy(trihexyl)phosphonium dicyanamide as the RTIL. It was determined that it has good absorption properties for methanol and ?-pinene, is thermally stable, and is relatively easy to synthesize. It has a density of 0.89 g/mL at 20°C and a molecular weight of 549.9 g/mol. Trials were conducted with a small absorption system and a larger absorption system. Methanol, formaldehyde, and other HAPs were absorbed well, nearly 100%. Acetaldehyde was difficult to capture. Total VOC capture, while satisfactory on methanol and ?-pinene in a lab system, was less than expected in the field, 60-80%. The inability to capture the broad spectrum of total organics is likely due to difficulties in cleaning them from the ionic liquid rather than the ability of the ionic liquid to absorb. It’s likely that a commercial system could be constructed to remove 90 to 100% of the gas contaminates. Selecting the correct ionic liquid would be key to this. Absorption may not be the main selection criterion, but rather how easily the ionic liquid can be cleaned is very important. The ionic liquid absorption system might work very well in a system with a limited spectrum of pollutants, such as a paint spray line, where there are not very high molecular weight, non volatile, compounds in the exhaust.

  7. A non-planar organic molecule with non-volatile electrical bistability for nano-scale data storage{

    E-Print Network [OSTI]

    Gao, Hongjun

    A non-planar organic molecule with non-volatile electrical bistability for nano-scale data storage-planar organic molecule with electron donor and acceptor capabilities was synthesized for nano-scale data storage possesses good electrical bistability. Nano-scale recording dots with an average diameter of 2.5 nm were

  8. Metal-organic molecular device for non-volatile memory storage

    SciTech Connect (OSTI)

    Radha, B., E-mail: radha.boya@manchester.ac.uk, E-mail: kulkarni@jncasr.ac.in; Sagade, Abhay A.; Kulkarni, G. U., E-mail: radha.boya@manchester.ac.uk, E-mail: kulkarni@jncasr.ac.in [Chemistry and Physics of Materials Unit and DST Unit on Nanoscience, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560064 (India)

    2014-08-25

    Non-volatile memory devices have been of immense research interest for their use in active memory storage in powered off-state of electronic chips. In literature, various molecules and metal compounds have been investigated in this regard. Molecular memory devices are particularly attractive as they offer the ease of storing multiple memory states in a unique way and also represent ubiquitous choice for miniaturized devices. However, molecules are fragile and thus the device breakdown at nominal voltages during repeated cycles hinders their practical applicability. Here, in this report, a synergetic combination of an organic molecule and an inorganic metal, i.e., a metal-organic complex, namely, palladium hexadecylthiolate is investigated for memory device characteristics. Palladium hexadecylthiolate following partial thermolysis is converted to a molecular nanocomposite of Pd(II), Pd(0), and long chain hydrocarbons, which is shown to exhibit non-volatile memory characteristics with exceptional stability and retention. The devices are all solution-processed and the memory action stems from filament formation across the pre-formed cracks in the nanocomposite film.

  9. Anthropogenic emissions of highly reactive volatile organic compounds in eastern Texas

    E-Print Network [OSTI]

    Mickley, Loretta J.

    al 2003, Parrish et al 2012) and in an oil/gas field of northern Colorado (Gilman et al 2013 of VOCs, have been used to constrain AHRVOC emissions in East Asia (Fu et al 2007) and Nigeria (Marais et

  10. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  11. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  12. Emission, oxidation, and secondary organic aerosol formation of volatile organic compounds as observed at Chebogue Point,

    E-Print Network [OSTI]

    Goldstein, Allen

    acid, formaldehyde, acetaldehyde, tentatively identified formic acid and hydroxyacetone organic aerosol production. We clearly show these compounds do not originate from local sources. We also show these compounds match the oxidation products of isoprene observed in smog chamber studies, and we

  13. Photochemical aging of volatile organic compounds in the Los Angeles basin: Weekday-weekend effect

    E-Print Network [OSTI]

    Goldstein, Allen

    in ozone, caused by lower NOx emissions due to reduced diesel truck traffic in the weekends, has been nonattainment area. [3] In the LA basin the main emission sources for the ozone precursors VOCs and NOx (NO + NO that in the LA basin in 2008 mobile sources were the dominant emission sources and accounted for 89% of total NOx

  14. Isotopes of Volatile Organic Compounds: An Emerging Approach for Studying Atmospheric Budgets and Chemistry

    E-Print Network [OSTI]

    Goldstein, Allen

    Emissions 5034 4.1.1. Fossil Fuels 5034 4.1.2. Transportation 5036 4.1.3. Industrial Production 5036 4 Isotope Effects 5038 5.1. Chemical and Photochemical Processes 5038 5.1.1. Production 5038 5.1.2. Losses of carbonaceous particles. This technique has since been applied to VOCs such as formaldehyde, other aldehydes, ac

  15. Pulsed Corona Plasma Technology for Treating VOC Emissions from Pulp Mills

    SciTech Connect (OSTI)

    Fridman, Alexander A.; Gutsol, Alexander; Kennedy, Lawrence A.; Saveliev, Alexei V.; Korobtsev, Sergey V.; Shiryaevsky, Valery L.; Medvedev, Dmitry

    2004-07-28

    Under the DOE Office of Industrial Technologies Forest Products program various plasma technologies were evaluated under project FWP 49885 ''Experimental Assessment of Low-Temperature Plasma Technologies for Treating Volatile Organic Compound Emissions from Pulp Mills and Wood Products Plants''. The heterogeneous pulsed corona discharge was chosen as the best non-equilibrium plasma technology for control of the vent emissions from HVLC Brownstock Washers. The technology for removal of Volatile Organic Compounds (VOCs) from gas emissions with conditions typical of the exhausts of the paper industry by means of pulsed corona plasma techniques presented in this work. For the compounds of interest in this study (methanol, acetone, dimethyl sulfide and ? -pinene), high removal efficiencies were obtained with power levels competitive with the present technologies for the VOCs removal. Laboratory experiments were made using installation with the average power up to 20 W. Pilot plant prepared for on-site test has average plasma power up to 6.4 kW. The model of the Pilot Plant operation is presented.

  16. Volatile organic compounds: Comparison of two sample collection and preservation methods

    SciTech Connect (OSTI)

    Liikala, T.L.; Olsen, K.B.; Teel, S.S.; Lanigan, D.C. [Pacific Northwest National Lab., Richland, WA (United States)] [Pacific Northwest National Lab., Richland, WA (United States)

    1996-12-01

    Two soil sample collection and preservation methods for volatile organic compounds, used during site characterization activities, were evaluated using standard U.S. Environmental Protection Agency analytical methods. A conventional bulk method recommends completely filling a sample container with soil; a less commonly used methanol method recommends placing a soil aliquot into methanol. Analytical results showed large negative biases associated with the bulk samples as compared to the methanol samples for aromatic compounds. Order of magnitude differences in concentrations measured between the methods were observed for benzene and toluene. Lesser differences were noted for xylenes and ethylbenzene. Limited data for chlorinated compounds suggest behavior similar to the aromatic species. A limited spike recovery study was conducted using the methanol method on laboratory and field samples. Samples were analyzed 82 days after spike addition. Poorer spike recoveries were noted from spiked methanol vials transported to the field and used for collection of soil samples. Differences between mean recovery values for the laboratory and field samples appear to be the result of losses during sample collection and transport. Despite the 82-day holding time, spike recoveries were within 70% of initial spike concentrations. These results demonstrate the stability of using methanol as a preservative for soil samples. 17 refs., 6 figs., 3 tabs.

  17. Contribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide levels in two areas of the United States

    E-Print Network [OSTI]

    Dabdub, Donald

    - house gas, but also the hydroperoxide radical (HO2). HO2 converts nitric oxide to nitrogen dioxideContribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide. Chen, K. Carmody, S. Vutukuru, and D. Dabdub (2007), Contribution of gas phase oxidation of volatile

  18. Volatilization of selected organic compounds from a creosote-waste land-treatment facility. Master's thesis

    SciTech Connect (OSTI)

    Scott, E.J.

    1989-01-01

    The purpose of this research was to evaluate the emissions of volatile and semi-volatile compounds which are constituents of a complex creosote waste from laboratory simulations of a land treatment system to assess the potential human exposure to hazardous compounds from this source. In addition, the Thibodeaux-Hwang Air Emission Release Rate (AERR) model was evaluated for its use in predicting emission rates of hazardous constituents of creosote wood preservative waste from land treatment facilities. A group of hazardous volatile and semi-volatile constituents present in the creosote waste was selected for evaluation in this study and included a variety of polynuclear aromatic hydrocarbons (PNA's), phenol, and chlorinated and substituted phenols.

  19. Chemiresistor microsensors for in-situ monitoring of volatile organic compounds : final LDRD report.

    SciTech Connect (OSTI)

    Thomas, Michael Loren; Hughes, Robert Clark; Kooser, Ara S.; McGrath, Lucas K.; Ho, Clifford Kuofei; Wright, Jerome L.; Davis, Chad Edward

    2003-09-01

    This report provides a summary of the three-year LDRD (Laboratory Directed Research and Development) project aimed at developing microchemical sensors for continuous, in-situ monitoring of volatile organic compounds. A chemiresistor sensor array was integrated with a unique, waterproof housing that allows the sensors to be operated in a variety of media including air, soil, and water. Numerous tests were performed to evaluate and improve the sensitivity, stability, and discriminatory capabilities of the chemiresistors. Field tests were conducted in California, Nevada, and New Mexico to further test and develop the sensors in actual environments within integrated monitoring systems. The field tests addressed issues regarding data acquisition, telemetry, power requirements, data processing, and other engineering requirements. Significant advances were made in the areas of polymer optimization, packaging, data analysis, discrimination, design, and information dissemination (e.g., real-time web posting of data; see www.sandia.gov/sensor). This project has stimulated significant interest among commercial and academic institutions. A CRADA (Cooperative Research and Development Agreement) was initiated in FY03 to investigate manufacturing methods, and a Work for Others contract was established between Sandia and Edwards Air Force Base for FY02-FY04. Funding was also obtained from DOE as part of their Advanced Monitoring Systems Initiative program from FY01 to FY03, and a DOE EMSP contract was awarded jointly to Sandia and INEEL for FY04-FY06. Contracts were also established for collaborative research with Brigham Young University to further evaluate, understand, and improve the performance of the chemiresistor sensors.

  20. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    emissions from oil and gas production pads using mobileuxes over other oil and gas production regions using eddycompounds (VOCs) from oil and gas production may have large

  1. A large dynamic chamber for characterizing particulate and VOC emissions

    SciTech Connect (OSTI)

    Lawless, P.A.; Smith, D.D.; Ensor, D.S. [Research Triangle Inst., Research Triangle Park, NC (United States); Sparks, L.E. [Environmental Protection Agency, Research Triangle Park, NC (United States). Air and Energy Engineering Research Lab.

    1996-12-31

    A dynamic chamber (8 m{sup 3}) was designed and constructed for the investigation of particulate emissions from appliances and office equipment and their impact on indoor air quality. The supply air incorporated high efficiency particle filters to provide a near-zero particle background in a low turbulence flow. The flow rate could be varied from 2 to 80 m{sup 3}/min. For testing operating appliances, such as vacuum cleaners, the dimensions of the chamber were chosen to allow an operator to use an appliance over a floor area of about 2 m{sup 2}. The need for low particle backgrounds dictated that the chamber be operated in an overpressure mode, so that all leaks were from the inside and would only affect the total flow measurements. The flow converges into an outlet tube 20 cm in diameter where velocity and concentration measurements could be made in multiple ports. The chamber was furnished with interior lights and electrical outlets. Recently, the chamber has been modified with carbon filters on the inlet to allow for sampling of volatile organic compounds (VOCs), such as from floor wax. The filters remove the VOC background to a level below that detectable by the sorbent cartridges/analysis system used for sampling. The chamber has even been pressed into service as a small cleanroom for some operations that required its unique characteristics. The chamber has been successfully operated in both a closed-loop mode and in an open-loop mode. The main advantage of the closed loop mode is that the backgrounds can be reduced to zero more quickly, but the disadvantage is that humidity and carbon dioxide concentrations grow because they are not removed by the filters.

  2. Characterization of volatile organic compounds (VOCs) in Asian and north American pollution plumes during INTEX-B: identification of specific Chinese air mass tracers

    E-Print Network [OSTI]

    2009-01-01

    sources and sinks of carbonyl sulfide and carbon disulfidemass balances of carbonyl sulfide (OCS) and carbon disul-of atmospheric carbonyl sulfide (COS) and some similarities

  3. Influence of Atmospheric Pressure and Water Table Fluctuations on Gas Phase Flow and Transport of Volatile Organic Compounds (VOCs) in Unsaturated Zones 

    E-Print Network [OSTI]

    You, Kehua

    2013-04-19

    solution in a three-layered unsaturated zone in response to field atmospheric pressure fluctuations at the Hanford site in Richland, Washington... ................................................................................................. 92 4.3 Comparison of gas flow rate calculated by the ML solution with measured flow rates in a three-layered unsaturated zone in response to field atmospheric pressure variations at the Hanford site in Richland...

  4. Infrared Spectroscopy of Wild 2 Particle Hypervelocity Tracks in Stardust Aerogel: Evidence for the presence of Volatile Organics in Comet Dust

    SciTech Connect (OSTI)

    Bajt, S; Sandford, S A; Flynn, G J; Matrajt, G; Snead, C J; Westphal, A J; Bradley, J P

    2007-08-28

    Infrared spectroscopy maps of some tracks, made by cometary dust from 81P/Wild 2 impacting Stardust aerogel, reveal an interesting distribution of volatile organic material. Out of six examined tracks three show presence of volatile organic components possibly injected into the aerogel during particle impacts. When particle tracks contained excess volatile organic material, they were found to be -CH{sub 2}-rich. Off-normal particle tracks could indicate impacts by lower velocity particles that could have bounced off the Whipple shield, therefore carry off some contamination from it. However, this theory is not supported by data that show excess organic-rich material in normal and off-normal particle tracks. It is clear that the population of cometary particles impacting the Stardust aerogel collectors also include grains that contained little or none of this volatile organic component. This observation is consistent with the highly heterogeneous nature of the collected grains, as seen by a multitude of other analytical techniques. We propose that at least some of the volatile organic material might be of cometary origin based on supporting data shown in this paper. However, we also acknowledge the presence of carbon (primarily as -CH{sub 3}) in the original aerogel, which complicates interpretation of these results.

  5. Recovery of semi-volatile organic compounds during sample preparation: Compilation for characterization of airborne particulate matter

    SciTech Connect (OSTI)

    Swartz, Erick; Stockburger, Leonard; Gundel, Lara

    2002-05-01

    Semi-volatile compounds present special analytical challenges not met by conventional methods for analysis of ambient particulate matter (PM). Accurate quantification of PM-associated organic compounds requires validation of the laboratory procedures for recovery over a wide volatility and polarity range. To meet these challenges, solutions of n-alkanes (nC{sub 12} to nC{sub 40}) and polycyclic aromatic hydrocarbons PAHs (naphthalene to benzo[ghi]perylene) were reduced in volume from a solvent mixture (equal volumes of hexane, dichloromethane and methanol), to examine recovery after reduction in volume. When the extract solution volume reached 0.5 mL the solvent was entirely methanol, and the recovery averaged 60% for n-alkanes nC{sub 12} to nC{sub 25} and PAHs from naphthalene to chrysene. Recovery of higher MW compounds decreased with MW, because of their insolubility in methanol. When the walls of the flasks were washed with 1 mL of equal parts hexane and dichloromethane (to reconstruct the original solvent composition), the recovery of nC{sub 18} and higher MW compounds increased dramatically, up to 100% for nC{sub 22}-nC{sub 32} and then slowly decreasing with MW due to insolubility. To examine recovery during extraction of the components of the High Capacity Integrated Gas and Particle Sampler, the same standards were used to spike its denuders and filters. For XAD-4 coated denuders and filters, normalized recovery was > 95% after two extractions. Recovery from spiked quartz filters matched the recovery from the coated surfaces for alkanes nC{sub 18} and larger, and for fluoranthene and larger PAHs. Lower MW compounds evaporated from the quartz filter with the spiking solvent. This careful approach allowed quantification of organics by correcting for volatility- and solubility-related sample preparation losses. This method is illustrated for an ambient sample collected with this sampler during the Texas Air Quality Study 2000.

  6. Membranes for Reverse-Organic Air Separations

    Broader source: Energy.gov [DOE]

    New Membranes Use Reverse Separation to Reduce Pollutant Emissions: Many industrial applications need a process to separate pollutants known as volatile organic compounds (VOCs) from air in order to protect the environment and save energy. One such application is the venting of vapor from underground storage tanks (UST) used in gasoline storage and dispensing. These vapors, which can build up and create high pressure within the UST, contribute to ground-level ozone and smog upon release.

  7. Common Indoor Sources of volatile organic compounds: emission rates and techniques for reducing consumer exposures

    E-Print Network [OSTI]

    Hodgson, A.T.

    2011-01-01

    categories. Latex paints contain organic solvents such assemivolatile organic compounds from waterborne paint - Theorganic compounds from PVC flooring, carpet and paint.

  8. Work plan for support to Upper East Fork Poplar Creek east end VOC plumes well installation project at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    1998-03-01

    Under the Resource Conservation and Recovery Act of 1976 guidelines and requirements from the Tennessee Department of Environment and Conservation (TDEC), the Y-12 Plant initiated investigation and monitoring of various sites within its boundaries in the mid-1980s. The entire Oak Ridge Reservation (ORR) was placed on the National Priorities List of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) sites in November 1989. Following CERCLA guidelines, sites within the ORR require a remedial investigation (RI) to define the nature and extent of contamination, evaluate the risks to public health and the environment, and determine the goals for a feasibility study (FS) or an engineering evaluation/cost analysis (EE/CA) of potential remedial actions. Data from monitoring wells at the east end of the Y-12 Plant have identified an area of groundwater contamination dominated by the volatile organic compound (VOC) carbon tetrachloride; other VOCs include chloroform, tetrachloroethene, and trichloroethene.

  9. Stratification of particulate and VOC pollutants in horizontal-flow-paint spray booths. Report for September 1988-October 1989

    SciTech Connect (OSTI)

    Darvin, C.H.

    1990-01-01

    The paper discusses stratification of particulate and volatile organic compound (VOC) pollutants in horizontal flow paint spray booths, as part of a joint U.S. Air Force/EPA research and development program on emissions from paint spray booths. The test program discussed in the paper was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control strategies are being developed. The results of one series of tests indicate that the pollutants, both particulate and VOC, fall to the lower level of the booth or stratify at the level at which they were generated. This might be expected since the densities of typical pollutants found in spray booths are greater than air. The results showed, however, that the concentration of pollutants in the lower level prior to exiting the booth was significantly greater than expected. Data indicated that, for the 16 ft (4.9 m) high booth tested, the concentration at the exit of the booth below the 8 ft (2.4 m) level was 5-25 times greater than the concentration above that level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The concentrated zone could be directed to a proportionally smaller VOC control system of significantly less capital and operating cost.

  10. Test methods for determining short and long term VOC emissions from latex paint

    SciTech Connect (OSTI)

    Krebs, K.; Lao, H.C.; Fortmann, R.; Tichenor, B.

    1998-09-01

    The paper discusses an evaluation of latex paint (interior, water based) as a source of indoor pollution. A major objective of the research is the development of methods for predicting emissions of volatile organic compounds (VOCs) over time. Test specimens of painted gypsumboard are placed in dynamic flow-through test chambers. Samples of the outlet air are collected on Tenax sorbents and thermally desorbed for analysis by gas chromatography/flame ionization detection. These tests produce short- and long-term data for latex paint emissions of Texanol, 2-2(-butoxyethoxy)-ethanol, and glycols. Evaluation of the data shows that most of the Texanol emissions occur within the first few days, and emissions of the glycols occur over several months. This behavior may be described by an evaporative mass transfer process that dominates the short-term emissions, while long-term emissions are limited by diffusion processes within the dry paint-gypsumboard.

  11. Composites for removing metals and volatile organic compounds and method thereof

    SciTech Connect (OSTI)

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Reynolds, John G. (San Ramon, CA)

    2006-12-12

    Functionalized hydrophobic aerogel/solid support structure composites have been developed to remove metals and organic compounds from aqueous and vapor media. The targeted metals and organics are removed by passing the aqueous or vapor phase through the composite which can be in molded, granular, or powder form. The composites adsorb the metals and the organics leaving a purified aqueous or vapor stream. The species-specific adsorption occurs through specific functionalization of the aerogels tailored towards specific metals and/or organics. After adsorption, the composites can be disposed of or the targeted metals and/or organics can be reclaimed or removed and the composites recycled.

  12. Natural volatile organic compound emissions from plants and their roles in oxidant balance and particle formation

    E-Print Network [OSTI]

    Kesselmeier, JC

    2009-01-01

    of Emissions of Gases and Aero- sols from Nature), Atmos.of secondary organic aero­ sol: A global modeling study, J.and M. Razzaghi (1989), Aero­bic ethanol-production by

  13. Hybrid membranes and their use in volatile organic compound/air separations 

    E-Print Network [OSTI]

    Krohn, John Eric

    2001-01-01

    Hybrid organic/inorganic membranes were produced by chemical grafting of octadecyltrichlorosilane onto ?-alumina membranes. Separation factors are presented showing strong evidence of capillary condensation in ungrafted membranes. The grafted...

  14. Evaluation of control strategies for volatile organic compounds in indoor air (journal article)

    SciTech Connect (OSTI)

    Ramanathan, K.; Debler, V.L.

    1988-01-01

    The paper discusses research which evaluates the application of adsorption techniques to the control of indoor organic vapors. The adsorption on activated carbon of three compounds representing three classes of organic species was studied at 30 C in the concentration range zero to 200 ppb using a microbalance. The three were benzene (aromatic), acetaldehyde (oxygenated aliphatic), and 1,1,1-trichloroethane (halogenated aliphatic). Three sorbents (a wood base carbon, a coal base carbon, and a coconut shell base carbon) were examined. Uptakes for all the compounds on all the carbons were low (on the order of 10 to the minus 7th power gmol/g carbon). Simulation of a packed bed of carbon indicated that carbon adsorption may not be practical for continuous removal, but may be applicable to sudden releases (e.g., spills). Potential alternatives to activated carbon adsorption are discussed. Potentially toxic organic vapors are emitted from a wide variety of building materials, consumer products, and human activities. Control of indoor organic vapors generally involves removing the source and/or increasing the ventilation rate. The ubiquitous nature of sources of organic vapors generally makes source removal impractical. Increased ventilation causes increased energy usage with its resultant economic penalties. Therefore, practical removal methods are needed.

  15. Customizing a VOC control technology

    SciTech Connect (OSTI)

    Enneking, J.C.

    1998-12-31

    An extremely important but very difficult element in applying an emission control device to an exhaust stream is to chose the proper technology. Once it has been determined that recovery, rather than destruction, is appropriate, there are still several process choices available. The type of process is generally dictated by the VOC concentration and total air flow rate. Adsorption is usually chosen for low concentrations and high flow rates while refrigeration is usually best for high concentrations and low flow rates. This paper describes six applications. Adsorption was applied to two of them and condensation to the other four. Solvent vapors from a tape coating operation are recovered in an activated carbon adsorption process and reused. VOC`s from soil vapor extraction operations are captured by activated carbon which is regenerated by a mobile unit. VOC`s displaced from filling tank cars at a refinery are condensed at low temperatures in a high pressure system which uses a pressure swing dryer to remove water. Two different processes were installed to prevent VOC emissions from pharmaceutical processing plants. They both use a thermal swing dryer to remove moisture and low temperature condensation to recover the solvent. With very high concentrations of solvent in an inert gas stream, indirect condensation is used to purify the nitrogen and recover the solvent for reuse. Process flow diagrams and operating results are presented.

  16. Ecosystem-scale volatile organic compound fluxes during an extreme drought in a broadleaf temperate forest of the Missouri Ozarks (central USA)

    E-Print Network [OSTI]

    2015-01-01

    usually have lower vapor pressure than the reactant VOCs andtower. Atmospheric vapor pressure deficit (VPD) was computed

  17. The MESERAN Method: Rapid Quantification of Non-Volatile Organic Residue (NVOR)

    SciTech Connect (OSTI)

    Benkovich, M.G.

    2002-06-13

    The precision analytical technique known as MESERAN Analysis permits quantitative measurement of the level of preexisting nonvolatile organic residue (NVOR) on a substrate from <1 nanogram (ng)/cm{sup 2} to > 100 micrograms ({micro}g)/cm{sup 2} in 2 minutes. MESERAN Analysis is also applicable to determining NVOR in solvents and solvent extracts. The MESERAN method is able to quantify organic contamination levels down to and below 1 ng by depositing as little as 10 microliters ({micro}L) of solvent containing a known amount of contamination on a clean substrate, allowing it to evaporate, and measuring the evaporated residue. The method will be described in detail and NVOR measurements determined from MESERAN data will be presented.

  18. Catalytic oxidation of VOC`s and air toxics

    SciTech Connect (OSTI)

    Lassen, M.A.; Chu, W. [Johnson Matthey, Wayne, PA (United States)

    1995-12-31

    Catalytic oxidation for VOC control of stationary sources has been in use since the 1940`s for energy recovery and odor control. Widespread use of catalytic oxidation, as a means for controlling emissions began in earnest in the early 1970`s with the passage of the Clean Air Act of 1970. Since that time, catalytic technology has undergone many improvements and advancements. Some of these include higher destruction efficiencies at lower temperatures, poison resistance, enhanced durability and the ability to effectively control halogenated hydrocarbon compounds. This is particularly important for meeting the Title III requirements, since many of the air toxics regulated under Title III are halogenated VOC`s. This paper will describe catalytic oxidation, how it works, its benefits and limitations, its cost relative to thermal, and describe recent technology advances.

  19. Biogenic volatile emissions from the soil J. Peuelas1,2

    E-Print Network [OSTI]

    Tholl, Dorothea

    Review Biogenic volatile emissions from the soil J. Peñuelas1,2 , D. Asensio1,2 , D. Tholl3 , K emissions to the atmosphere are often 1­2 (0­3) orders of magnitude lower than those from aboveground of microbial and root VOC emissions. Furthermore, VOC profiles are discussed as non-destructive fingerprints

  20. 4, 66916718, 2004 VOC emissions of

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 6691­6718, 2004 VOC emissions of Scots pine V. Tarvainen et al. Title Page Abstract Discussions Temperature and light dependence of the VOC emissions of Scots pine V. Tarvainen 1 , H. Hakola 1.tarvainen@fmi.fi) 6691 #12;ACPD 4, 6691­6718, 2004 VOC emissions of Scots pine V. Tarvainen et al. Title Page Abstract

  1. Stratification of particulate and VOC pollutants in paint spray booths, June 1990. Report for April 1988-April 1989

    SciTech Connect (OSTI)

    Darvin, C.H.; Ayer, J.

    1990-01-01

    The paper discusses flow management as part of a joint EPA/U.S. Air Force program on emissions from paint spray booths. The goal of the program is to identify and develop efficient and economical emissions control concepts for this source. Flow management is one potential solution that reduces the volume of gases that must be processed in a control system. Although it will not itself control pollution, it can influence the economic and technical viability of subsequent control systems. The test program discussed here was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control and flow management strategies are being developed. Study results indicate that both particulate and volatile organic compounds (VOCs) fall to the lower level of the booth or, at most, stratify at the level at which they were generated. Results indicate that the concentration at the lower level of the booth near the exhaust was from 5 to 25 times greater than that at the upper level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The enriched lower zone could then be directed to a proportionately smaller VOC control system, of lower capital and operating costs.

  2. Ecosystem-scale volatile organic compound fluxes during an extreme drought in a broadleaf temperate forest of the Missouri Ozarks (central USA)

    E-Print Network [OSTI]

    2015-01-01

    Atkinson R (2000) Atmospheric chemistry of VOCs and NOx.and ecology. Journal of Atmospheric Chemistry, 33, 23–88.mixed forest. Atmospheric Chemistry and Physics, 12, 577–

  3. Ecosystem-scale volatile organic compound fluxes during an extreme drought in a broadleaf temperate forest of the Missouri Ozarks (central USA)

    E-Print Network [OSTI]

    2015-01-01

    Atkinson R (2000) Atmospheric chemistry of VOCs and NOx.forest. Journal of Atmospheric Chemistry, 56, 165–185. FunkMediterranean oak forest. Atmospheric Chemistry and Physics,

  4. Installation and Operation of Sorbathene Solvent Vapor Recovery Units to Recover and Recycle Volatile Organic Compounds at Operating Sites within the Dow Chemical Company 

    E-Print Network [OSTI]

    Hall, T. L.; Larrinaga, L.

    1994-01-01

    hydrocarbons, chlorofluorocarbons (CFC's), chlorinated solvents, aromatics, and monomers. SORBATHENE units are now meeting air permit requirements for the abatement of VOC's such as benzene, acetone, trichloroethylene, trichlorofluoromethane, carbon...

  5. Biofiltration control of VOC and air toxic emissions: n-Butane and benzene

    SciTech Connect (OSTI)

    Allen, E.R.

    1996-12-31

    n-Butane and benzene vapors are routinely observed in urban atmospheres. Their presence in urban airsheds is of concern because of their ozone production potential as volatile organic compounds (VOCs) and/or potential toxicity. Also, these saturated hydrocarbons are representative of airborne aliphatic and aromatic compounds. Separate laboratory studies have been conducted on the biological elimination of n-butane (n-C{sub 4}H{sub 10}) and benzene (C{sub 6}H{sub 6}) from airstreams using treated compost biofilters. The removal efficiencies were found to exceed 90% for a conditioned biofilter medium and pollutant low concentrations (< 25 ppm) and zeroth order kinetics at higher concentrations (> 100 ppm), whereas benzene vapor elimination followed zeroth order kinetics at concentrations up to 200 ppm. The maximum n-butane and benzene elimination capacities observed for the compost biofilters and conditions employed were 25 and 70 g pollutant m{sup -3} h{sup -1}, respectively. 13 refs., 6 figs., 2 tabs.

  6. Impacts of simulated herbivory on VOC emission profiles from coniferous plants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faiola, C. L.; Jobson, B. T.; VanReken, T. M.

    2014-09-18

    The largest global source of volatile organic compounds (VOCs) in the atmosphere is from biogenic emissions. Plant stressors associated with a changing environment can alter both the quantity and composition of the compounds that are emitted. This study investigated the effects of one global change stressor, increased herbivory, on plant emissions from five different coniferous species: bristlecone pine (Pinus aristata), blue spruce (Picea pungens), western redcedar (Thuja plicata), grand fir (Abies grandis), and Douglas-fir (Pseudotsugas menziesii). Herbivory was simulated in the laboratory via exogenous application of methyl jasmonate, an herbivory proxy. Gas-phase species were measured continuously with a gas chromatographmore »coupled to a mass spectrometer and flame ionization detector (GC-MS-FID). Stress responses varied between the different plant types and even between experiments using the same set of saplings. The compounds most frequently impacted by the stress treatment were alpha-pinene, beta-pinene, 1,8-cineol, beta-myrcene, terpinolene, limonene, and the cymene isomers. Individual compounds within a single experiment often exhibited a different response to the treatment from one another.« less

  7. Reactive processing of formaldehyde and acetaldehyde in aqueous aerosol mimics: Surface tension depression and secondary organic products

    E-Print Network [OSTI]

    Li, Zhi; Sareen, Neha; McNeill, V Faye

    2011-01-01

    The reactive uptake of carbonyl-containing volatile organic compounds (cVOCs) by aqueous atmospheric aerosols is a likely source of particulate organic material. The aqueous-phase secondary organic products of some cVOCs are surface-active. Therefore, cVOC uptake can lead to organic film formation at the gas-aerosol interface and changes in aerosol surface tension. We examined the chemical reactions of two abundant cVOCs, formaldehyde and acetaldehyde, in water and aqueous ammonium sulfate (AS) solutions mimicking tropospheric aerosols. Secondary organic products were identified using Aerosol Chemical Ionization Mass Spectrometry (Aerosol-CIMS), and changes in surface tension were monitored using pendant drop tensiometry. Hemiacetal oligomers and aldol condensation products were identified using Aerosol-CIMS. A hemiacetal sulfate ester was tentatively identified in the formaldehyde-AS system. Acetaldehyde depresses surface tension to 65(\\pm2) dyn/cm in pure water and 62(\\pm1) dyn/cm in AS solutions. Surface t...

  8. Chemical and Nutritional Ecology of Lucilia sericata (Meigen) (Diptera: Calliphoridae) as Related to Volatile Organic Compounds and Associated Essential Amino Acids 

    E-Print Network [OSTI]

    Liu, Wenqi

    2014-08-07

    are the origin of MVOC. Four bacterially produced VOCs, namely DMDS (Dimethyl disulfide), indole, PAA (Phenylacetic acid), and isobutylamine, which are associated with decomposing carrion were used to investigate the olfactory response of L. sericata of different...

  9. Brookhaven National Laboratory - OU VI VOC | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Brookhaven National Laboratory - OU VI VOC Brookhaven National Laboratory - OU VI VOC January 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater...

  10. Brookhaven National Laboratory - OU III VOC | Department of Energy

    Office of Environmental Management (EM)

    III VOC Brookhaven National Laboratory - OU III VOC January 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName,...

  11. Brookhaven National Laboratory - OU I/IV VOC | Department of...

    Office of Environmental Management (EM)

    IIV VOC Brookhaven National Laboratory - OU IIV VOC January 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName,...

  12. Determination of a cost-effective air pollution control technology for the control of VOC and HAP emissions from a steroids processing plant

    SciTech Connect (OSTI)

    Hamel, T.M.

    1997-12-31

    A steroids processing plant located in northeastern Puerto Rico emits a combined average of 342 lb/hr of hazardous air pollutants (HAPs) and volatile organic compounds (VOCs) from various process operations. The approach that this facility used to implement maximum achievable control technology (MACT) may assist others who must contend with MACT for pharmaceutical or related manufacturing facilities. Federal air regulations define MACT standards for stationary sources emitting any of 189 HAPs. The MACT standards detailed in the NESHAPs are characterized by industry and type of emission control system or technology. It is anticipated that the standard will require HAP reductions of approximately 95%. The steroid plant`s emissions include the following pollutant loadings: VOC/HAP Emission Rate (lb/hr): Methanol 92.0; Acetone 35.0; Methylene chloride 126.0; Chloroform 25.0; Ethyl acetate 56.0; Tetrahydrofuran 5.00; and 1,4-Dioxane 3.00. The facility`s existing carbon adsorption control system was nearing the end of its useful life, and the operators sought to install an air pollution control system capable of meeting MACT requirements for the pharmaceutical industry. Several stand-alone and hybrid control technologies were considered for replacement of the carbon adsorption system at the facility. This paper examines the following technologies: carbon adsorption, membrane separation, thermal oxidation, membrane separation-carbon adsorption, and condensation-carbon adsorption. Each control technology is described; the advantages and disadvantages of utilizing each technology for the steroid processing plant are examined; and capital and operating costs associated with the implementation of each technology are presented. The rationale for the technology ultimately chosen to control VOC and HAP emissions is presented.

  13. 8, 1182111851, 2008 VOCs during 2006

    E-Print Network [OSTI]

    Boyer, Edmond

    the campaign and many species were quantified including methanol, acetaldehyde, toluene, the sum of C2 benzenes patterns and their origins. Diurnal profiles of weekday10 and weekend/holiday aromatic VOC concentrations

  14. FORMATION CONDITIONS OF ICY MATERIALS IN COMET C/2004 Q2 (MACHHOLZ). I. MIXING RATIOS OF ORGANIC VOLATILES

    SciTech Connect (OSTI)

    Kobayashi, Hitomi; Kawakita, Hideyo, E-mail: h_kobayashi@cc.kyoto-su.ac.j [Department of Physics, Faculty of Science, Kyoto Sangyo University, Motoyama, Kamigamo, Kita-ku, Kyoto 603-8555 (Japan)

    2009-09-20

    We observed comet C/2004 Q2 (Machholz) with the Keck II telescope in late 2005 January and we obtained the spectra of C/2004 Q2 including many emission lines of volatile species such as H{sub 2}O, HCN, C{sub 2}H{sub 2}, NH{sub 3}, CH{sub 4}, C{sub 2}H{sub 6}, CH{sub 3}OH, and H{sub 2}CO with high-signal-to-noise ratios. Based on our observations, we determined the mixing ratios of the molecules relative to H{sub 2}O in C/2004 Q2. Since C/2004 Q2 is one of Oort Cloud comets, it is interesting to compare our results with other Oort Cloud comets. The mixing ratios of C{sub 2}H{sub 2}/H{sub 2}O and C{sub 2}H{sub 6}/H{sub 2}O in C/2004 Q2 are lower than typical Oort Cloud comets. Especially, C{sub 2}H{sub 2}/H{sub 2}O ratio in C/2004 Q2 is as lower as Jupiter Family comets. However, mixing ratios of other molecules in C/2004 Q2 are similar to typical Oort Cloud comets. C/2004 Q2 might be the intermediate type between Oort Cloud and Jupiter Family comets. To investigate the formation conditions of such intermediate type comet, we focused on the (C{sub 2}H{sub 2}+C{sub 2}H{sub 6})/H{sub 2}O ratios and C{sub 2}H{sub 6}/(C{sub 2}H{sub 6}+C{sub 2}H{sub 2}) ratios in comets from the viewpoint of conversion from C{sub 2}H{sub 2} to C{sub 2}H{sub 6} in the precometary ices. We found that (C{sub 2}H{sub 2}+C{sub 2}H{sub 6})/H{sub 2}O ratio in C/2004 Q2 is lower than the ratio in typical Oort Cloud comets while C{sub 2}H{sub 6}/(C{sub 2}H{sub 6}+C{sub 2}H{sub 2}) ratio in C/2004 Q2 is consistent with the ratio of the typical Oort Cloud comets and Jupiter family comets. If we assume that the cometary volatiles such as H{sub 2}O, CH{sub 4}, and C{sub 2}H{sub 2} formed similar environment, the C{sub 2}H{sub 6}/(C{sub 2}H{sub 6}+C{sub 2}H{sub 2}) ratio might not be sensitive in the temperature range where hydrogen-addition reactions occurred and cometesimals formed ({approx}30 K). We employed the dynamical-evolutional model and the chemical-evolutional model to determine the formation region of C/2004 Q2 more precisely. We found that comet C/2004 Q2 might have formed in relatively inner region of the solar nebula than the typical Oort Cloud comet (but slightly further than 5 AU from the proto-Sun).

  15. Volatility basis-set approach simulation of organic aerosol formation in East Asia: implications for anthropogenic-biogenic interaction and controllable amounts

    SciTech Connect (OSTI)

    Matsui, H.; Koike, Makoto; Kondo, Yutaka; Takami, A.; Fast, Jerome D.; Kanaya, Y.; Takigawa, M.

    2014-09-16

    Organic aerosol (OA) simulations using the volatility basis-set approach were made for East Asia and its outflow region. Model simulations were evaluated through comparisons with OA measured by aerosol mass spectrometers in and around Tokyo (at Komaba and Kisai in summer 2003 and 2004) and over the outflow region in East Asia (at Fukue and Hedo in spring 2009). The simulations with aging processes of organic vapors reasonably well reproduced mass concentrations, temporal variations, and formation efficiency of observed OA at all sites. As OA mass was severely underestimated in the simulations without the aging processes, the oxidations of organic vapors are essential for reasonable OA simulations over East Asia. By considering the aging processes, simulated OA concentrations considerably increased from 0.24 to 1.28 µg m-3 in the boundary layer over the whole of East Asia. OA formed from the interaction of anthropogenic and biogenic sources was also enhanced by the aging processes. The fraction of controllable OA was estimated to be 87 % of total OA over the whole of East Asia, showing that most of the OA in our simulations formed anthropogenically (controllable). A large portion of biogenic secondary OA (78 % of biogenic secondary OA) formed through the influence of anthropogenic sources. The high fraction of controllable OA in our simulations is likely because anthropogenic emissions are dominant over East Asia and OA formation is enhanced by anthropogenic sources and their aging processes. Both the amounts (from 0.18 to 1.12 µg m-3) and the fraction (from 75 % to 87 %) of controllable OA were increased by aging processes of organic vapors over East Asia.

  16. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    containing compounds carbonyl sulfide (OCS) and dimethyl1,2-Dichloroethane Carbonyl sulfide Dimethyl sulfide

  17. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    control of atmospheric carbonyl sulfide during the growingof atmospheric carbonyl sulfide (COS) and some similaritiesF. : The mass budgets of carbonyl sulfide, dimethyl sulfide,

  18. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    and particles from savanna fires in southern Africa, J.from Canadian boreal forest fires, Can. J. For. Res. , 39(pattern on interannual forest fire vari- ability in Central

  19. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    in situ PTR-MS mea- n-Butane 0 surements in fresh biomassHydrogen cyanide Acetonitrile Ethane Propane i-Butanen-Butane i-Pentane n-Pentane n-Hexane 2+3-Methylpentane n-

  20. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    to methanogenic tailings pond emissions. Published byand no need for tailings ponds (www.oilsands.alberta.ca).the Syncrude Mildred Lake tailings pond contains about 200

  1. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    and Fehsenfeld, F. C. : Emission sources and ocean uptake ofand No- vakov, T. : Emissions of trace gases and particlesGroot, W. J. : Future emissions from Canadian boreal forest

  2. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    gases measured over Alberta oil sands mining operations: 76Canadian plumes Alberta oil sands 1-Butene ARCTAS 1-ButeneCanadian plumes Alberta oil sands y = -358 + 1.29x R = 0.599

  3. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    measured over Alberta oil sands mining operations Soc. , 81(reducing bacteria in oil sands fine tail- ings waste, Can.fine tailings from oil sands processing harbour diverse

  4. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    during ARCTAS-B (H. Singh, 1,3-Butadiene m+p-Xylene personal2-Butene trans-2-Butene 1,3-Butadiene Methacrolein Methyl

  5. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    oxidation of iso- prene and 1,3-butadiene in the presence of2-Butene trans-2-Butene 1,3-Butadiene Isoprene C 2 H 6 C 3 HButene t-2-Butene 1,3-Butadiene Isoprene Ethyne Cyclopentane

  6. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    propene, acetone, benzene, propane and ?-pinene (Table 1).cyanide Acetonitrile Ethane Propane i-Butane n-Butane i-= Ethane Ethane Ethane Ethane Propane Propane Propane ARCTAS

  7. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    ppbv), methanol, ethene, ethane, ethyne, propene, acetone,ethene, ?-pinene, ?-pinene, ethane, benzene, propene, ace-CO), methane (CH 4 ) and ethane (C 2 H 6 ) (Kasis- chke et

  8. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    For example the catalytic hydrocracking of Athabasca bitumenpossibly from fuel gas and/or hydrocracking. The butanes areerations. Similarly, hydrocracking operations do not appear

  9. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    Methanol Ethanol Acetone MEK MAC MVK CHCl 3 C 2 Cl 4 OCS DMS With the exception of the C 9 aromatics,

  10. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    A. : The Tropical Forest and Fire Emis- sions Experiment:W. M. : The Trop- ical Forest and Fire Emissions Experiment:A. : The tropical forest and fire emissions experiment:

  11. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    gases measured over Alberta oil sands mining operationsand Lee, P. : Does the Alberta tar sands industry pollute?gases measured over Alberta oil sands mining operations: 76

  12. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    of fuel composition on a heavy-duty, natural-gas direct-are not aware of the composition of the natural gas that isgas. The composition of commercial- grade natural gas is

  13. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01

    West, C. : Highlighting heavy oil, Oilfield Rev. , 34–53,and enhancement of Mo-heavy oil interaction, Fuel, 83,sticky extra-heavy crude oil that is “unconventional”,

  14. BLUNDEN, JESSICA. Characterization of Non-Methane Volatile Organic Compounds at Swine Facilities in Eastern North Carolina. (Under the direction of Dr. Viney P. Aneja)

    E-Print Network [OSTI]

    Aneja, Viney P.

    other VOCs. Carbonyl sulfide and carbon disulfide were positively identified by GC/MS analysis but were hydrocarbons, phenols, and sulfides were identified and quantified by Gas Chromatographic/Flame Ionization) including methyl mercaptan, dimethyl sulfide, dimethyl disulfide, and dimethyl trisulfide as well as many

  15. Brookhaven National Laboratory - OU I VOC | Department of Energy

    Office of Environmental Management (EM)

    I VOC Brookhaven National Laboratory - OU I VOC January 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State:...

  16. Brookhaven National Laboratory - OU V VOC | Department of Energy

    Office of Environmental Management (EM)

    V VOC Brookhaven National Laboratory - OU V VOC January 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State:...

  17. Sorption of organic gases in residential bedrooms andbathrooms

    SciTech Connect (OSTI)

    Singer, B.C.; Hodgson, A.T.; Hotchi, T.; Ming, K.Y.; Sextro,R.G.; Wood, E.E.; Brown, N.J.

    2005-01-05

    Experiments were conducted to characterize organic gas sorption in residential bedrooms (n=4), bathrooms (n=2), and a furnished test chamber. Rooms were studied ''as-is'' with material surfaces and furnishings unaltered. Surface materials were characterized and areas quantified. Experiments included rapid volatilization of a volatile organic compound (VOC) mixture with the room closed and sealed for a 5-h Adsorb phase, followed by 30-min Flush and 2-h closed-room Desorb phases. The mixture included n-alkanes, aromatics, glycol ethers, 2-ethyl-1-hexanol, dichlorobenzene, and organophosphorus compounds. Measured gas-phase concentrations were fit to three variations of a mathematical model that considers sorption occurring at one surface sink and one potential embedded sink. The 2-parameter sink model tracked measurements for most compounds, but improved fits were obtained for some VOCs with a 3-parameter sink-diffusion or a 4-parameter two-sink model. Sorptive partitioning and initial adsorption rates increased with decreasing vapor pressure within each chemical class.

  18. Brayton Cycle Heat Pump for VOC Control 

    E-Print Network [OSTI]

    Kovach, J. L.

    1990-01-01

    The first full size continuous operation Brayton Cycle Heat Pump (1)(2)(3) application for VOC recovery occurred in 1988. The mixed solvent recovery system was designed and supplied by NUCON for the 3M facility in Weatherford, OK (4). This first...

  19. Volatile Organic Emissions from Carpets

    E-Print Network [OSTI]

    Hodgson, A.T.

    2008-01-01

    of styrene and 1,3-butadiene. The 4- ethenylcyclohexeneof two molecules of 1,3-butadiene. Styrene is present in themonomer. No unreacted 1,3- butadiene was detected in the

  20. Volatile Organic Emissions from Carpets

    E-Print Network [OSTI]

    Hodgson, A.T.

    2008-01-01

    Field-study Carpet o o Styrene 4-Phenylcyclohexene o o o o om-,p-Xylene· Styrene o-Xylene 4-Phenylcyclohexene 4-m-,p-Xylene· Styrene o-Xylene 4- Phenylcyclohexene 4-

  1. Volatile Organic Emissions from Carpets

    E-Print Network [OSTI]

    Hodgson, A.T.

    2008-01-01

    two carpets with styrene-butadiene rubber latex adhesive.two with a styrene-butadiene rubber (SBR) latex adhesive onpresent in the styrene-butadiene rubber (SBR) latex which is

  2. ARM - Measurement - Volatile organic compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska Outreach Homepolarization ARMtotalgovMeasurementsVisibility ARM

  3. Decomposing VOCs with an electron-beam plasma reactor

    SciTech Connect (OSTI)

    Vitale, S.A.; Hadidi, K.; Cohn, D.R.; Bromberg, L.; Falkos, P.

    1996-04-01

    Several emerging technologies are being tested for decomposing VOCs. Among these are bioreactors, catalytic oxidation, photoinduced decomposition, thermal plasma processes, and nonequilibrium plasma processes. For a new technology to be successfully offered for commercial use, it must be reliable, economically competitive, and ready for use on an industrial scale. The authors have been working on an electron-beam-generated plasma reactor that now meets these prerequisites. The reactor can decompose halogenated organic compounds in dilute concentrations 1--3,000 ppm in airstreams at atmospheric pressure. The technology is more energy efficient than thermal technologies and thus represents lower electricity costs for the overall process. The reactor can easily be scaled to industrial needs and was tested successfully in Hanford, WA, to treat the offgas from the remediation of soils contaminated with CCl{sub 4}.

  4. Observations of Diurnal to Weekly Variations of Monoterpene-Dominated Fluxes of Volatile Organic Compounds from Mediterranean Forests: Implications for Regional Modeling

    SciTech Connect (OSTI)

    Fares, Silvano; Schnitzhofer, Ralf; Xiaoyan, Jiang; Guenther, Alex B.; Hansel, Armin; Loreto, Francesco

    2013-09-04

    Most vascular plants species, especially trees, emit biogenic volatile organic compounds (BVOC). Global estimates of BVOC emissions from plants range from 1 to 1.5 Pg C yr?1.1 Mediterranean forest trees have been described as high BVOC emitters, with emission depending primarily on light and temperature, and therefore being promoted by the warm Mediterranean climate. In the presence of sufficient sunlight and nitrogen oxides (NOx), the oxidation of BVOCs can lead to the formation of tropospheric ozone, a greenhouse gas with detrimental effects on plant health, crop yields, and human health. BVOCs are also precursors for aerosol formation, accounting for a significant fraction of secondary organic aerosol (SOA) produced in the atmosphere. The presidential Estate of Castelporziano covers an area of about 6000 ha located 25 km SW from the center of Rome, Italy (Figure 1) and hosts representative forest ecosystems typical of Mediterranean areas: holm oak forests, pine forests, dune vegetation, mixed oak and pine forests. Between 1995 and 2011, three intensive field campaigns were carried out on Mediterranean-type ecosystems inside the Estate. These campaigns were aimed at measuring BVOC emissions and environmental parameters, to improve formulation of basal emission factors (BEFs), that is, standardized emissions at 30 °C and 1000 ?mol m?2s?1 of photosynthetic active radiation (PAR). BEFs are key input parameters of emission models. The first campaign in Castelporziano was a pioneering integrated study on biogenic emissions (1993? 19964). BVOC fluxes from different forest ecosystems were mainly investigated using plant- and leaf enclosures connected to adsorption tubes followed by GC?MS analysis in the laboratory. This allowed a first screening of Mediterranean species with respect to their BVOC emission potential, environmental control, and emission algorithms. In particular, deciduous oak species revealed high isoprene emissions (Quercus f rainetto, Quercus petrea, Quercus pubescens), while evergreen oaks emitted monoterpenes only, for example, Quercus ilex = holm oak. Differences in constitutive emission patterns discovered in Castelporziano supplied basic information to discriminate oak biodiversity in following studies.Ten years later, a second experimental campaign took place in spring and summer 2007 on a dune-shrubland experimental site. In this campaign, the use of a proton transfer reaction mass spectrometer (PTR-MS14) provided the fast BVOC observations necessary for quasi-real-time flux measurements using Disjunct Eddy Covariance. This allowed for the first time continuous measurements and BEFs calculation at canopy level. Finally, in September 2011 a third campaign was performed with the aim of further characterizing and improving estimates of BVOC fluxes from mixed Mediterranean forests dominated by a mixed holm oak and stone pine forest, using for the first time a proton transfer reaction?time-of-flight?mass spectrometer (PTR-TOF-MS). In contrast to the standard quadrupole PTR-MS, which can only measure one m/z ratio at a discrete time, thus being inadequate to quantify fluxes of more than a handful of compounds simultaneously, PTR-TOF-MS allowed simultaneous measurements (10 Hz) of fluxes of all BVOCs at the canopy level by Eddy Covariance.17?20, 50 In this work, we reviewed BEFs from previous campaigns in Castelporziano and calculated new BEFs from the campaign based on PTR-TOF-MS analysis. The new BEFs were used to parametrize the model of emissions of gases and aerosols from nature (MEGAN v2.11).

  5. Using a flame ionization detector (FID) to continuously measure toxic organic vapors in a paint spray booth. Rept. for Jul 91-Jan 92

    SciTech Connect (OSTI)

    Whitfield, J.K.; Howe, G.B.; Pate, B.A.; Wander, J.D.

    1992-01-01

    The paper reports the demonstration of linear and similar responses of a Ratfisch RS-55CA flame ionization detector (FID) to a solvent mixture identical to the volatile organic compounds (VOCs) in the coating and catalyst (NSN 8010-01-336-3036) and to the calibrating gas (propane) used in field calibrations of the FID. Sensitivity and linearity have been shown to extend from 715 to 45 mg/cu m, which brackets the calculated short-term exposure limit (STEL) and lower action thresholds. Monitoring is maintained constantly and, under field conditions, equilibration occurs rapidly (analysis and output transpire in milliseconds). As a trigger for fail-safe conversion from recirculation mode to a straight-through paint spray booth configuration, the FID may confidently be expected to initiate a corrective response before a transient elevation of VOC concentrations overexposes area personnel.

  6. Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

    2014-05-06

    Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

  7. HYDROGEN AND VOC RETENTION IN WASTE BOXES

    SciTech Connect (OSTI)

    PACE ME; MARUSICH RM

    2008-11-21

    The Hanford Waste Management Project Master Documented Safety Analysis (MDSA) (HNF-14741, 2003) identifies derived safety controls to prevent or mitigate the risks of a single-container deflagration during operations requiring moving, venting or opening transuranic (TRU)-waste containers. The issue is whether these safety controls are necessary for operations involving TRU-waste boxes that are being retrieved from burial at the Hanford Site. This paper investigates the potential for a deflagration hazard within these boxes and whether safety controls identified for drum deflagration hazards should be applied to operations involving these boxes. The study evaluates the accumulation of hydrogen and VOCs within the waste box and the transport of these gases and vapors out of the waste box. To perform the analysis, there were numerous and major assumptions made regarding the generation rate and the transport pathway dimensions and their number. Since there is little actual data with regards to these assumptions, analyses of three potential configurations were performed to obtain some indication of the bounds of the issue (the concentration of hydrogen or flammable VOCs within a waste box). A brief description of each of the three cases along with the results of the analysis is summarized.

  8. Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants/Hygroscopicity and CCN Activity of Secondary & Processed Primary Organic Aerosols

    SciTech Connect (OSTI)

    Ziemann, P.J.; Arey, J.; Atkinson, R.; Kreidenweis, S.M.; Petters, M.D.

    2012-06-13

    The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was to carry out reactions of representative anthropogenic and biogenic VOCs and organic particles with ozone (O3), and hydroxyl (OH), nitrate (NO3), and chlorine (Cl) radicals, which are the major atmospheric oxidants, under simulated atmospheric conditions in large-volume environmental chambers. A combination of on-line and off-line analytical techniques were used to monitor the chemical and physical properties of the particles including their hygroscopicity and CCN activity. The results of the studies were used to (1) improve scientific understanding of the relationships between the chemical composition of organic particles and their hygroscopicity and CCN activity, (2) develop an improved molecular level theoretical framework for describing these relationships, and (3) establish a large database that is being used to develop parameterizations relating organic aerosol chemical properties and SOA sources to particle hygroscopicity and CCN activity for use in regional and global atmospheric air quality and climate models.

  9. Environmental Technology Vol. 32, No. 6, April 2011, 617623

    E-Print Network [OSTI]

    ; air pollution control; toluene; n-hexane; VOC mixtures Introduction Volatile organic compounds (VOCs plants, process- ing facilities, paint shops and a wide range of industries. The impacts of VOCs on human

  10. Volatility and commodity price dynamics

    E-Print Network [OSTI]

    Pindyck, Robert S.

    2001-01-01

    Commodity prices tend to be volatile, and volatility itself varies over time. changes in volatility can affect market variables by directly affecting the marginal value of storage, and by affecting a component of the total ...

  11. Associations of indoor carbon dioxide concentrations, VOCS, environmental susceptibilities with mucous membrane and lower respiratory sick building syndrome symptoms in the BASE study: Analyses of the 100 building dataset

    SciTech Connect (OSTI)

    Apte, M.G.; Erdmann, C.A.

    2002-10-01

    Using the 100 office-building Building Assessment Survey and Evaluation (BASE) Study dataset, we performed multivariate logistic regression analyses to quantify the associations between indoor minus outdoor CO{sub 2} (dCO{sub 2}) concentrations and mucous membrane (MM) and lower respiratory system (Lresp) Sick Building Syndrome (SBS) symptoms, adjusting for age, sex, smoking status, presence of carpet in workspace, thermal exposure, relative humidity, and a marker for entrained automobile exhaust. Using principal components analysis we identified a number of possible sources of 73 measured volatile organic compounds in the office buildings, and assessed the impact of these VOCs on the probability of presenting the SBS symptoms. Additionally we included analysis adjusting for the risks for predisposition of having SBS symptoms associated with the allergic, asthmatic, and environmentally sensitive subpopulations within the office buildings. Adjusted odds ratios (ORs) for statistically significant, dose-dependant associations (p<0.05) for dry eyes, sore throat, nose/sinus congestion, and wheeze symptoms with 100-ppm increases in dCO{sub 2} ranged from 1.1 to 1.2. These results suggest that increases in the ventilation rates per person among typical office buildings will, on average significantly reduce the prevalence of several SBS symptoms, up to 80%, even when these buildings meet the existing ASHRAE ventilation standards for office buildings. VOC sources were observed to play an role in direct association with mucous membrane and lower respiratory irritation, and possibly to be indirectly involved in indoor chemical reactions with ozone that produce irritating compounds associated with SBS symptoms. O-xylene, possibly emitted from furniture coatings was associated with shortness of breath (OR at the maximum concentration = 8, p < 0.05). The environmental sensitivities of a large subset of the office building population add to the overall risk of SBS symptoms (ORs ranging from 2 to above 11) within the buildings.

  12. Ecosystem-scale volatile organic compound fluxes during an extreme drought in a broadleaf temperate forest of the Missouri Ozarks (central USA)

    E-Print Network [OSTI]

    2015-01-01

    Environmental Protection Agency, National Risk Management Research Laboratory, Research Triangle Park, NC 27711, USA, 8 Atmospheric Chemistryenvironmental factors on organic compounds from oil palms in South-East Asia. Atmospheric Chemistry

  13. Evaluation of the volatility basis-set approach for the simulation of organic aerosol formation in the Mexico City metropolitan area

    E-Print Network [OSTI]

    Tsimpidi, A. P.

    New primary and secondary organic aerosol modules have been added to PMCAMx, a three dimensional chemical transport model (CTM), for use with the SAPRC99 chemistry mechanism based on recent smog chamber studies. The new ...

  14. Co-treatment of VOCs in low-pH sulfide biofilters

    SciTech Connect (OSTI)

    Devinny, J.S.; Chitwood, D.E.; Choi, D.S.

    1999-07-01

    Biofiltration of off-gases from wastewater treatment plants requires removal of sulfides and volatile organic compounds. Sulfides are readily removed in low-pH biofilters filled with inorganic media. If the same biofilter could simultaneously remove the volatile organic compounds, an efficient single-step system would be possible. Laboratory work on co-treatment of toluene and sulfides, and fieldwork on several volatile compounds indicate that this is possible. Removals of over 90% of toluene, xylene, acetone, methanol, and ethylbenzene should be possible with an empty bed contact time of 60 s. Methyl tert-butyl ether, isopentane, chloroform and methylene chloride were removed with lower but still substantial efficiencies. Biofilters operated at steady state but non-neutral pHs represent a promising avenue of research.

  15. APPLICATION OF STIR BAR SORPTIVE EXTRACTION TO ANALYSIS OF VOLATILE AND SEMIVOLATILE ORGANIC CHEMICALS OF POTENTIAL CONCERN IN SOLIDS AND AQUEOUS SAMPLES FROM THE HANFORD SITE

    SciTech Connect (OSTI)

    FRYE JM; KUNKEL JM

    2009-03-05

    Stir bar sorptive extraction was applied to aqueous and solid samples for the extraction and analysis of organic compounds from the Hanford chemicals of potential concern list, as identified in the vapor data quality objectives. The 222-S Laboratory analyzed these compounds from vapor samples on thermal desorption tubes as part of the Hanford Site industrial hygiene vapor sampling effort.

  16. Analysis of C1, C2, and C10 through C33 particle-phase and semi-volatile organic compound emissions from heavy-duty diesel engines

    E-Print Network [OSTI]

    Wu, Mingshen

    from heavy-duty diesel engines Z. Gerald Liu a,*, Devin R. Berg a , Victoria N. Vasys a , Melissa E 18 November 2009 Keywords: Organic compound emissions Particulate matter emissions Heavy-duty diesel engines Aftertreatment technology Diesel particulate filter Chemical speciation a b s t r a c t To meet

  17. Zero discharge organic coatings, powder paint - UV curable paint - E-coat. Volume 1. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Leal, J.; Martin, D.R.; Spadafora, S.J.; Eng, A.T.; Stark, H.

    1995-06-01

    Zero Discharge Organic Coatings project developed powder paint, Ultraviolet (UV) curable paint, and electro- coating (E-coat) paint for military Applications. These technologies offer potential for high performance coatings with little or no volatile organic compound (VOC) emissions or hazardous waste generation. The ZDOC project focused on formulating non-toxic corrosion inhibitors into these coating technologies, and the applications development of powder coatings. Non-toxic replacements for traditional lead and chromate inhibitors were selected based on a previous NAWCADWAR investigation. Once incorporated, the performance of the coatings with and without inhibitors was compared. Also, the protective mechanisms of these inhibitors were studied. The applications development for powder coatings analyzed technologies to allow powder coating of non-conductive substrates and evaluated the use of IR energy to cure powder coatings. Inhibitors were successfully incorporated into electrocoatings and powder coatings, however corrosion performance results varied with coating formulation.

  18. In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palm, B. B.; Campuzano-Jost, P.; Ortega, A. M.; Day, D. A.; Kaser, L.; Jud, W.; Karl, T.; Hansel, A.; Hunter, J. F.; Cross, E. S.; et al

    2015-11-04

    Ambient air was oxidized by OH radicals in an oxidation flow reactor (OFR) located in a montane pine forest during the BEACHON-RoMBAS campaign to study biogenic secondary organic aerosol (SOA) formation and aging. High OH concentrations and short residence times allowed for semi-continuous cycling through a large range of OH exposures ranging from hours to weeks of equivalent (eq.) atmospheric aging. A simple model is derived and used to account for the relative time scales of condensation of low volatility organic compounds (LVOCs) onto particles, condensational loss to the walls, and further reaction to produce volatile, non-condensing fragmentation products. Moremore »SOA production was observed in the OFR at nighttime (average 4 ?g m-3 when LVOC fate corrected) compared to daytime (average 1 ?g m-3 when LVOC fate corrected), with maximum formation observed at 0.4–1.5 eq. days of photochemical aging. SOA formation followed a similar diurnal pattern to monoterpenes, sesquiterpenes, and toluene + p-cymene concentrations, including a substantial increase just after sunrise at 07:00 LT. Higher photochemical aging (> 10 eq. days) led to a decrease in new SOA formation and a loss of preexisting OA due to heterogeneous oxidation followed by fragmentation and volatilization. When comparing two different commonly used methods of OH production in OFRs (OFR185 and OFR254), similar amounts of SOA formation were observed. We recommend the OFR185 mode for future forest studies. Concurrent gas-phase measurements of air after OH oxidation illustrate the decay of primary VOCs, production of small oxidized organic compounds, and net production at lower ages followed by net consumption of terpenoid oxidation products as photochemical age increased. New particle formation was observed in the reactor after oxidation, especially during times when precursor gas concentrations and SOA formation were largest. Approximately 6 times more SOA was formed in the reactor from OH oxidation than could be explained by the VOCs measured in ambient air. Several recently-developed instruments quantified ambient semi- and intermediate-volatility organic compounds (S/IVOCs) that were not detected by a PTR-TOF-MS. An SOA yield of 24–80 % from those compounds can explain the observed SOA, suggesting that these typically unmeasured S/IVOCs play a substantial role in ambient SOA formation. Our results allow ruling out condensation sticking coefficients much lower than 1. Our measurements help clarify the magnitude of SOA formation in forested environments, and demonstrate methods for interpretation of ambient OFR measurements.« less

  19. Volatiles in protoplanetary disks

    E-Print Network [OSTI]

    Pontoppidan, Klaus M; Bergin, Edwin A; Brittain, Sean; Marty, Bernard; Mousis, Olvier; Oberg, Karin L

    2014-01-01

    Volatiles are compounds with low sublimation temperatures, and they make up most of the condensible mass in typical planet-forming environments. They consist of relatively small, often hydrogenated, molecules based on the abundant elements carbon, nitrogen and oxygen. Volatiles are central to the process of planet formation, forming the backbone of a rich chemistry that sets the initial conditions for the formation of planetary atmospheres, and act as a solid mass reservoir catalyzing the formation of planets and planetesimals. This growth has been driven by rapid advances in observations and models of protoplanetary disks, and by a deepening understanding of the cosmochemistry of the solar system. Indeed, it is only in the past few years that representative samples of molecules have been discovered in great abundance throughout protoplanetary disks - enough to begin building a complete budget for the most abundant elements after hydrogen and helium. The spatial distributions of key volatiles are being mapped...

  20. Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions -...

  1. VOCs, Pesticides, Nitrate, and Their Mixtures in Groundwater Used for

    E-Print Network [OSTI]

    VOCs, Pesticides, Nitrate, and Their Mixtures in Groundwater Used for Drinking Water in the United, Rapid City, South Dakota 57702 Samples of untreated groundwater from 1255 domestic drinking-water wells of the groundwater resource and, thus, were distributed geographically across large aquifers, primarily in rural

  2. VOC Emission Control with the Brayton Cycle Pilot Plant Operations 

    E-Print Network [OSTI]

    Enneking, J. C.

    1992-01-01

    A mobile pilot plant capable of removing VOC emissions from exhaust air streams was cooperatively funded by SCE, EPRI, 3M, and NUCON. Valuable information about the process and the recovery operation has been gained by performing tests at a number...

  3. Recent VOC Control Test Data for a Reactive VOC Converter- Scrubber System for Non-Thermal Control of VOCs 

    E-Print Network [OSTI]

    McGinness, M.

    2003-01-01

    plug and blind off the media or kill the microorganisms if the emissions carry metals or organics that act as biocides at elevated concentrations (Webster, 1999). Bio-trickling filters and stationary air biofilters use fixed microorganisms... but the bio-trickling filters use a flowing water phase. Bio-scrubbers use a suspended biomass and a flowing water phase. Biofilters do not produce CO, NOx, and only produce small amounts of C02. Incineration They typically oxidize VOHAPs to C02...

  4. Red Balloon, Green Balloon, Sensors in the Sky Stacey Kuznetsov1

    E-Print Network [OSTI]

    Paulos, Eric

    engines [9]; and VOC's (volatile organic compounds) originate from paints, pesticides, or certain types color based on input from attached air quality sensors (exhaust, diesel, or volatile organic compounds). The balloons change color in response to one of exhaust gas, diesel, or VOC's (volatile organic compounds

  5. Volatile Organic Compound Detection Using Nanostructured Copolymers

    E-Print Network [OSTI]

    Weiss, Lee E.

    conductivity of these copolymers increased or decreased depending upon the polymer composition and the specific,3-6 conductive poly- mers (CPs),7-12 and carbon black-polymer composites.13,14 Metal oxide materials Carbon black-polymer composites have also attracted a lot of research interest as a promising sensing

  6. Metal price volatility : a study of informative metrics and the volatility mitigating effects of recycling

    E-Print Network [OSTI]

    Fleming, Nathan Richard

    2011-01-01

    Metal price volatility is undesirable for firms that use metals as raw materials, because price volatility can translate into volatility of material costs. Volatile material costs and can erode the profitability of the ...

  7. Realized Stock Volatility 2.1 Introduction

    E-Print Network [OSTI]

    Niebur, Ernst

    Chapter 2 Realized Stock Volatility 2.1 Introduction Financial market volatility is indispensable for asset and derivative pricing, asset allocation, and risk management. As volatility is not a directly is to calculate the daily volatility from the sample variance of intraday returns, the `realized' volatility

  8. Limited effect of anthropogenic nitrogen oxides on secondary organic aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-12-08

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but it can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR (National Center for Atmospheric Research) Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product volatility basis set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. Small differences are found for themore »no-aging VBS and 2-product schemes; large increases in SOA production and the SOA-to-OA ratio are found for the aging scheme. The predicted organic aerosol amounts capture both the magnitude and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of 2 compared to aerosol mass spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different regions and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9–5.6, 6.4–12.0 and 0.9–2.8 % for global, southeast US and Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to a limited shift in chemical regime, to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  9. Limited effect of anthropogenic nitrogen oxides on Secondary Organic Aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-08-28

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product Volatility Basis Set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. The predicted organic aerosol amounts capture both the magnitude and distribution ofmore »US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of two compared to Aerosol Mass Spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different region and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9 to 5.6, 6.4 to 12.0 and 0.9 to 2.8 % for global, the southeast US and the Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  10. VOLATILITY TIME AND PROPERTIES OF OPTION PRICES

    E-Print Network [OSTI]

    Janson, Svante

    VOLATILITY TIME AND PROPERTIES OF OPTION PRICES volatility time, to show convexity of option prices in the underlying asset if the contract function is convex as well as continuity and monotonicity of the option price in the volatility

  11. Available online at www.sciencedirect.com Metabolic engineering of plant volatiles

    E-Print Network [OSTI]

    Pichersky, Eran

    for plant improvement because of the great contribution of volatile secondary metabolites to reproduction organic compounds known as secondary or specialized metabolites [1]. More than 1% of these metabolitesAvailable online at www.sciencedirect.com Metabolic engineering of plant volatiles Natalia Dudareva

  12. Services Initiatives | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and is very low in Volatile Organic Compounds (VOCs) which evaporate little and cause no air pollution, whereas petroleum-based inks are high in VOCs and cause air pollution when...

  13. An Introduction to Texas Senate Bill 5 

    E-Print Network [OSTI]

    Haberl, J. S.; Culp, C.; Yazdani, B.; Fitzpatrick, T.; Turner, W. D.

    2002-01-01

    ), volatile organic compounds (VOCs), and oxygen (O2) combine in the presence of strong sunlight. In response to this effort the Texas Natural Resource Conservation Commission (TNRCC) developed a strategy with the EPA that reduced VOCs from large regulated...

  14. An investigation of the thermal degradation mechanisms of a waste tire through chemical analysis including hydrocarbons, benzene derivatives, and Polycyclic

    E-Print Network [OSTI]

    Columbia University

    including hydrocarbons, benzene derivatives, and Polycyclic Aromatic Hydrocarbons (PAHs) at high temperature a GC/MS. Significant Volatile Organic Carbons (VOCs) including benzene derivatives, PAHs, and Hetero

  15. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TBD ECOS Washington, D.C. FESCNGO Anthony Zammerilli Methane and Volatile Organic Carbon (VOC) Emissions Best Practices Database... The Environmental Council of States, Shale Gas...

  16. Long Wavelength Catalytic Infrared Drying System | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 20' to 30' rotating drum while tumbling the wood product. Product scorching and air emission problems, particularly with carbon, NOx, and volatile organic compounds (VOCs),...

  17. Biological Air Emissions Control

    Office of Energy Efficiency and Renewable Energy (EERE)

    Air quality standards are becoming more stringent for the U.S. wood products industry. Emissions of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) (including methanol,...

  18. An investigation of the thermal degradation mechanisms of a waste tire through chemical analysis including hydrocarbons, benzene derivatives, and Polycyclic

    E-Print Network [OSTI]

    including hydrocarbons, benzene derivatives, and Polycyclic Aromatic Hydrocarbons (PAHs) at high temperature-to-Energy, Volatile Organic Carbons (VOCs), Polycyclic Aromatic Hydrocarbons (PAHs), Hetero-N containing PAH

  19. A Case for Safer Building Materials: Lifecycle Concerns, Data Gaps, and

    E-Print Network [OSTI]

    Lee, Seung-Wuk

    ;Conventional Building Materials · Wood · Stone · Cement · Metal · Glass · Straw · Ceramics #12;Synthetic;Volatile organic compounds (VOCs) · Aliphatic hydrocarbons, aromatic hydrocarbons, halogenated hydrocarbons

  20. Quantitative organic vapor-particle sampler

    DOE Patents [OSTI]

    Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

    1998-01-01

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  1. DOAS measurement of glyoxal as an indicator for fast VOC chemistry in urban air

    E-Print Network [OSTI]

    DOAS measurement of glyoxal as an indicator for fast VOC chemistry in urban air Rainer Volkamer (2005), DOAS measurement of glyoxal as an indicator for fast VOC chemistry in urban air, Geophys. Res for a better quality of life are offset by a severe degradation of air quality caused by photochemical smog

  2. WAT ENVIRON RESEARCH (in press, final version may have small changes) ODOR AND VOC TREATMENT BY BIOTRICKLING FILTERS: PILOT SCALE

    E-Print Network [OSTI]

    in Los Angeles to study H2S/odor and VOC removal from the Headworks' waste air. The performance to the efficiency of removal of H2S as the major pollutant. VOCs were present at concentrations up to 150 ppb. Low Biotrickling filter, biological waste air treatment, hydrogen sulfide, odor, VOCs. #12;INTRODUCTION

  3. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2014-12-20

    Four different parameterizations for the formation and evolution of secondary organic aerosol (SOA) are evaluated using a 0-D box model representing the Los Angeles Metropolitan Region during the CalNex 2010 field campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA formed only from the oxidation of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generationmore »oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model-measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model/measurement agreement for mass concentration. When comparing the three parameterizations, the Grieshop et al. (2009) parameterization more accurately reproduces both the SOA mass concentration and oxygen-to-carbon ratio inside the urban area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the parameterizations over-predict urban SOA formation at long photochemical ages (≈ 3 days) compared to observations from multiple sites, which can lead to problems in regional and global modeling. Among the explicitly modeled VOCs, the precursor compounds that contribute the greatest SOA mass are methylbenzenes. Polycyclic aromatic hydrocarbons (PAHs) are less important precursors and contribute less than 4% of the SOA mass. The amounts of SOA mass from diesel vehicles, gasoline vehicles, and cooking emissions are estimated to be 16–27, 35–61, and 19–35%, respectively, depending on the parameterization used, which is consistent with the observed fossil fraction of urban SOA, 71 (±3) %. In-basin biogenic VOCs are predicted to contribute only a few percent to SOA. A regional SOA background of approximately 2.1 ?g m?3 is also present due to the long distance transport of highly aged OA. The percentage of SOA from diesel vehicle emissions is the same, within the estimated uncertainty, as reported in previous work that analyzed the weekly cycles in OA concentrations (Bahreini et al., 2012; Hayes et al., 2013). However, the modeling work presented here suggests a strong anthropogenic source of modern carbon in SOA, due to cooking emissions, which was not accounted for in those previous studies. Lastly, this work adapts a simple two-parameter model to predict SOA concentration and O/C from urban emissions. This model successfully predicts SOA concentration, and the optimal parameter combination is very similar to that found for Mexico City. This approach provides a computationally inexpensive method for predicting urban SOA in global and climate models. We estimate pollution SOA to account for 26 Tg yr?1 of SOA globally, or 17% of global SOA, 1/3 of which is likely to be non-fossil.« less

  4. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2015-05-26

    Four different literature parameterizations for the formation and evolution of urban secondary organic aerosol (SOA) frequently used in 3-D models are evaluated using a 0-D box model representing the Los Angeles metropolitan region during the California Research at the Nexus of Air Quality and Climate Change (CalNex) 2010 campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle- and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA that formed only from the oxidationmore »of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generation oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model–measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate-volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model–measurement agreement for mass concentration. The results from the three parameterizations show large differences (e.g., a factor of 3 in SOA mass) and are not well constrained, underscoring the current uncertainties in this area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the recent parameterizations overpredict urban SOA formation at long photochemical ages (? 3 days) compared to observations from multiple sites, which can lead to problems in regional and especially global modeling. However, reducing IVOC emissions by one-half in the model to better match recent IVOC measurements improves SOA predictions at these long photochemical ages. Among the explicitly modeled VOCs, the precursor compounds that contribute the greatest SOA mass are methylbenzenes. Measured polycyclic aromatic hydrocarbons (naphthalenes) contribute 0.7% of the modeled SOA mass. The amounts of SOA mass from diesel vehicles, gasoline vehicles, and cooking emissions are estimated to be 16–27, 35–61, and 19–35%, respectively, depending on the parameterization used, which is consistent with the observed fossil fraction of urban SOA, 71(±3) %. The relative contribution of each source is uncertain by almost a factor of 2 depending on the parameterization used. In-basin biogenic VOCs are predicted to contribute only a few percent to SOA. A regional SOA background of approximately 2.1 ?g m?3 is also present due to the long-distance transport of highly aged OA, likely with a substantial contribution from regional biogenic SOA. The percentage of SOA from diesel vehicle emissions is the same, within the estimated uncertainty, as reported in previous work that analyzed the weekly cycles in OA concentrations (Bahreini et al., 2012; Hayes et al., 2013). However, the modeling work presented here suggests a strong anthropogenic source of modern carbon in SOA, due to cooking emissions, which was not accounted for in those previous studies and which is higher on weekends. Lastly, this work adapts a simple two-parameter model to predict SOA concentration and O/C from urban emissions. This model successfully predicts SOA concentration, and the optimal parameter combination is very similar to that found for Mexico City. This approach provides a computationally inexpensive method for predicting urban SOA in global

  5. Volatility in natural gas and oil markets

    E-Print Network [OSTI]

    Pindyck, Robert S.

    2003-01-01

    Using daily futures price data, I examine the behavior of natural gas and crude oil price volatility since 1990. I test whether there has been a significant trend in volatility, whether there was a short-term increase in ...

  6. Global comparison of VOC and CO observations in urban areas Erika von Schneidemesser a

    E-Print Network [OSTI]

    sources, such as industry and LPG-related sources in non- Annex I countries. Yearly benzene to ethyne of air quality. Certain VOCs are very reactive in the atmosphere (e.g., xylenes and benzene compounds

  7. The Chicago VOC trading system : the consequences of market design for performance

    E-Print Network [OSTI]

    Kosobud, Richard F.

    2004-01-01

    The Chicago cap-and-trade approach to regulating stationary source VOC emissions in the Chicago ozone non-attainment area is a pioneering program that could set a precedent for other urban areas troubled by high ozone ...

  8. Target Volatility Option Pricing Giuseppe Di Graziano

    E-Print Network [OSTI]

    Macrina, Andrea

    for the pricing of Target Volatility Options (TVOs), a recent market innovation in the eld of volatility are lower than the target volatility, the pay-o of the former is higher than the pay-o of the corresponding experi- enced a steep increase, with a signicant impact on option (long vega) costs. The generalized

  9. Summary Report for the Development of Materials for Volatile Radionuclides

    SciTech Connect (OSTI)

    Strachan, Denis M.; Chun, Jaehun; Henager, Charles H.; Matyas, Josef; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

    2010-11-22

    The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2010, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogenides. For 85Kr, metal organic framework (MOF) structures were investigated.

  10. Maintaining Indoor Air Quality During Construction and Renovation Projects

    E-Print Network [OSTI]

    Huang, Jianyu

    / Hazards Volatile Organic Compounds (VOCs) Volatile organic compounds (VOCs) are compounds that are readily Flooring Caulks Fuels, Cleaners Wall Coverings Sealants Adhesives Composite Wood Products Paints Carpeting be implemented. Hazardous Particulates which are subject to special regulation include lead paint dust which

  11. Development and Characterization of a Thermodenuder for Aerosol Volatility Measurements

    SciTech Connect (OSTI)

    Dr. Timothy Onasch

    2009-09-09

    This SBIR Phase I project addressed the critical need for improved characterization of carbonaceous aerosol species in the atmosphere. The proposed work focused on the development of a thermodenuder (TD) system capable of systematically measuring volatility profiles of primary and secondary organic aerosol species and providing insight into the effects of absorbing and nonabsorbing organic coatings on particle absorption properties. This work provided the fundamental framework for the generation of essential information needed for improved predictions of ambient aerosol loadings and radiative properties by atmospheric chemistry models. As part of this work, Aerodyne Research, Inc. (ARI) continued to develop and test, with the final objective of commercialization, an improved thermodenuder system that can be used in series with any aerosol instrument or suite of instruments (e.g., aerosol mass spectrometers-AMS, scanning mobility particle sizers-SMPS, photoacoustic absorption spectrometers-PAS, etc.) to obtain aerosol chemical, physical, and optical properties as a function of particle volatility. In particular, we provided the proof of concept for the direct coupling of our improved TD design with a full microphysical model to obtain volatility profiles for different organic aerosol components and to allow for meaningful comparisons between different TD-derived aerosol measurements. In a TD, particles are passed through a heated zone and a denuding (activated charcoal) zone to remove semi-volatile material. Changes in particle size, number concentration, optical absorption, and chemical composition are subsequently detected with aerosol instrumentation. The aerosol volatility profiles provided by the TD will strengthen organic aerosol emission inventories, provide further insight into secondary aerosol formation mechanisms, and provide an important measure of particle absorption (including brown carbon contributions and identification, and absorption enhancements due to coatings on soot particles). The successfully completed Phase I project included construction of a prototype design for the TD with detailed physical modeling, testing with laboratory and ambient aerosol particles, and the initiation of a detailed microphysical model of the aerosol particles passing through the TD to extract vapor pressure distributions. The objective of the microphysical model is to derive vapor pressure distributions (i.e. vapor pressure ranges, including single chemical compounds, mixtures of known compounds, and complex ‘real-world’ aerosols, such as SOA, and soot particles with absorbing and nonabsorbing coatings) from TD measurements of changes in particle size, mass, and chemical composition for known TD temperatures and flow rates (i.e. residence times). The proposed Phase II project was designed to optimize several TD systems for different instrument applications and to combine the hardware and modeling into a robust package for commercial sales.

  12. Mapping isoprene emissions over North America using formaldehyde column observations from space

    E-Print Network [OSTI]

    Palmer, Paul

    Mapping isoprene emissions over North America using formaldehyde column observations from space. [1] We present a methodology for deriving emissions of volatile organic compounds (VOC) using space to local VOC emissions, with a spatial smearing that increases with the VOC lifetime. Isoprene

  13. Update on Biochemistry of Plant Volatiles Biochemistry of Plant Volatiles1

    E-Print Network [OSTI]

    Pichersky, Eran

    to be emitted from plants, al- though a comprehensive list is available only for floral volatiles (Knudsen et alUpdate on Biochemistry of Plant Volatiles Biochemistry of Plant Volatiles1 Natalia Dudareva*, Eran, Beutenberg Campus, D­007745 Jena, Germany (J.G.) Plants have a penchant for perfuming the atmo- sphere around

  14. Method for lowering the VOCS emitted during drying of wood products

    DOE Patents [OSTI]

    Banerjee, Sujit (1832 Jacksons Creek Point, Marietta, GA 30068); Boerner, James Robert (154 Junedale Rd., Cincinnati, OH 45218); Su, Wei (2262 Orleans Ave., Marietta, GA 30062)

    2000-01-01

    The present invention is directed to a method for removal of VOCs from wood products prior to drying the wood products. The method of the invention includes the steps of providing a chamber having an opening for receiving wood and loading the chamber with green wood. The wood is loaded to an extent sufficient to provide a limited headspace in the chamber. The chamber is then closed and the wood is heated in the chamber for a time and at a temperature sufficient to saturate the headspace with moisture and to substantially transfer VOCs from the wood product to the moisture in the headspace.

  15. Zevenhoven & Kilpinen VOCs, PAHs, soot, tar, CO 17.6.2001 6-1 Chapter 6 VOCs, PAHs,

    E-Print Network [OSTI]

    Zevenhoven, Ron

    17.6.2001 6-2 Table 6.2 Organic hazardous air pollutants (HAPs) of interest for thermal power) hazardous air pollutant POHC (USA) principle organic hazardous constituents, selected on the basis of difficulties with their incineration (LaGrega et al., 1994) Hazardous air pollutants (HAPs) as defined

  16. VOLATILITY TIME AND PROPERTIES OF OPTION PRICES: A SUMMARY

    E-Print Network [OSTI]

    Janson, Svante

    VOLATILITY TIME AND PROPERTIES OF OPTION PRICES: A SUMMARY volatility time, to show convexity of option prices in the underlying asset if the contract function is convex as well as continuity and monotonicity of the option price in the volatility

  17. Noise Reduced Realized Volatility: A Kalman Filter Approach

    E-Print Network [OSTI]

    Owens, John; Steigerwald, Douglas G

    2009-01-01

    F. , 2004. Microstructure Noise, Realized Volatility, andof Market Microstructure Noise. Working Paper w9611, NBER.Noise Reduced Realized Volatility: A Kalman Filter Approach

  18. RESEARCH PAPER Identification of loci affecting flavour volatile emissions in

    E-Print Network [OSTI]

    Klee, Harry J.

    RESEARCH PAPER Identification of loci affecting flavour volatile emissions in tomato fruits Denise shown that emissions of carotenoid-derived volatiles were directly correlated with the fruit carotenoid

  19. An In-Situ Ion Mobility Spectrometer Sensor System for Detecting Gaseous VOCs in Unsaturated Soils

    E-Print Network [OSTI]

    Baker, R. Jacob

    . The IMS system will be packaged in a probe housing for deployment using direct push methods methods for sampling and analyzing soil gas samples fall into two classes: passive sampling and active sampling. Passive sampling methods involve the shallow burial of a sorbent collector, which adsorbs the VOC

  20. A Novel New Approach to VOC and HAP Emission Control 

    E-Print Network [OSTI]

    McGinness, M.

    2000-01-01

    if the emissions carry metals or organics that act as biocides at elevated concentrations (Webster, 1999). Bio-trickling filters and stationary air biofilters use fixed microorganisms but the bio-trickling filters use a flowing water phase. Bio-scrubbers use a...&D EFFORTS The Navy has been investigating a pilot scale bio trickling filter (Webster, 1999) for treating off gases from spray paint booths. The project was funded by the Navy's Small Business Innovative Research (SBIR) Program. Test results indicated...

  1. Securing non-volatile memory regions

    DOE Patents [OSTI]

    Faraboschi, Paolo; Ranganathan, Parthasarathy; Muralimanohar, Naveen

    2013-08-20

    Methods, apparatus and articles of manufacture to secure non-volatile memory regions are disclosed. An example method disclosed herein comprises associating a first key pair and a second key pair different than the first key pair with a process, using the first key pair to secure a first region of a non-volatile memory for the process, and using the second key pair to secure a second region of the non-volatile memory for the same process, the second region being different than the first region.

  2. Volatile fatty acid fermentation of AFEX-treated newspaper and bagasse by rumen microorganisms 

    E-Print Network [OSTI]

    Blasig, Jorge Dari?o

    1991-01-01

    production vatied between 6. 6 and 8. 2 mmoles/g volatile solids (VS) digested and biogas (approximately 40% methane ranged from 0. 18 and 0. 29 L/g VS digested for organic waste materials of various origin and composition. The loading rates varied between...

  3. The profitability of trading volatility using realvalued and symbolic models

    E-Print Network [OSTI]

    Tino, Peter

    implied volatility models . 1 Acknowledgements: This work was supported by the Austrian Science Fund (FWF

  4. Reactive flash volatilization of fluid fuels

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

    2013-01-08

    The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

  5. Understanding sources of organic aerosol during CalNex-2010 using the CMAQ-VBS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Woody, M. C.; Baker, K. R.; Hayes, P. L.; Jimenez, J. L.; Koo, B.; Pye, H. O. T.

    2015-10-05

    Community Multiscale Air Quality (CMAQ) model simulations utilizing the volatility basis set (VBS) treatment for organic aerosols (CMAQ-VBS) were evaluated against measurements collected at routine monitoring networks (Chemical Speciation Network (CSN) and Interagency Monitoring of Protected Visual Environments (IMPROVE)) and those collected during the 2010 California at the Nexus of Air Quality and Climate Change (CalNex) field campaign to examine important sources of organic aerosol (OA) in southern California. CMAQ-VBS (OA lumped by volatility, semivolatile POA) underpredicted total organic carbon (OC) at CSN (?25.5 % Normalized Median Bias (NMdnB)) and IMPROVE (?63.9 % NMdnB) locations and total OC wasmore »underpredicted to a greater degree compared to the CMAQ-AE6 (9.9 and ?55.7 % NMdnB, respectively; semi-explicit OA treatment, SOA lumped by parent hydrocarbon, nonvolatile POA). However, comparisons to aerosol mass spectrometer (AMS) measurements collected at Pasadena, CA indicated that CMAQ-VBS better represented the diurnal profile and the primary/secondary split of OA. CMAQ-VBS secondary organic aerosol (SOA) underpredicted the average measured AMS oxygenated organic aerosol (OOA, a surrogate of SOA) concentration by a factor of 5.2 (4.7 ?g m?3 measured vs. 0.9 ?g m?3 modeled), a considerable improvement to CMAQ-AE6 SOA predictions, which were approximately 24× lower than the average AMS OOA concentration. We use two new methods, based on species ratios and on a simplified SOA parameterization from the observations, to apportion the SOA underprediction for CMAQ-VBS to too slow photochemical oxidation (estimated as 1.5× lower than observed at Pasadena using ? log (NOx: NOy)), low intrinsic SOA formation efficiency (low by 1.6 to 2× for Pasadena), and too low emissions or too high dispersion for the Pasadena site (estimated to be 1.6 to 2.3× too low/high). The first and third factors will be similar for CMAQ-AE6, while the intrinsic SOA formation efficiency for that model is estimated to be too low by about 7×. For CMAQ-VBS, 90 % of the anthropogenic SOA mass formed was attributed to aged secondary semivolatile vapors (70 % originating from volatile organic compounds (VOCs) and 20 % from intermediate volatility compounds (IVOCs)). From source-apportioned model results, we found most of the CMAQ-VBS modeled POA at the Pasadena CalNex site was attributable to meat cooking emissions (48 %, and consistent with a substantial fraction of cooking OA in the observations), compared to 18 % from gasoline vehicle emissions, 13 % from biomass burning (in the form of residential wood combustion), and 8 % from diesel vehicle emissions. All "other" inventoried emission sources (e.g. industrial/point sources) comprised the final 13 %. The CMAQ-VBS semivolatile POA treatment underpredicted AMS hydrocarbon-like OA (HOA) + cooking-influenced OA (CIOA) at Pasadena by a factor of 1.8 (1.16 ?g m?3 modeled vs. 2.05 ?g m?3 observed) compared to a factor of 1.4 overprediction of POA in CMAQ-AE6, but did well to capture the AMS diurnal profile of HOA and CIOA, with the exception of the midday peak. We estimated that using the National Emission Inventory (NEI) POA emissions without scaling to represent SVOCs underestimates SVOCs by ~1.7×.« less

  6. Pressure maintenance in a volatile oil reservoir 

    E-Print Network [OSTI]

    Schuster, Bruce Alan

    1989-01-01

    PRESSURE MAINTENANCE IN A VOLATILE OIL RESERVOIR A Thesis BRUCE ALAN SCHUSTER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May, 1989 Major... Subject: Petroleum Engineering PRESSURE MAINTENANCE IN A VOLATILE OIL RESERVOIR A Thesis BRUCE ALAN SCHUSTER Approved as to style and content by: S. A. Holditch (Chair of Committee) W. J. Lee (Member) R. R, Berg (Member) , Jz W. D. Von Gonten...

  7. Reduction of VOC emissions from metal dip coating applications -- Canam Steel Corporation Point of Rocks, MD case study

    SciTech Connect (OSTI)

    Monfet, J.P.

    1997-12-31

    The reduction of VOC emissions from metal dip coating applications is not an environmental constraint, it is an economic opportunity. This case study shows how the industry can reap economic benefits from VOC reductions while improving air quality. The Canam Steel Corporation plant located in Point of Rocks, MD operates dip tanks for primer application on fabricated steel joists and joist girders. This process is presently subject to a regulation that limits the paint VOC content to 3.5 pounds per gallon of coating less water. As a result of the high paint viscosity associated with that regulation, the paint thickness of the dipped steel is thicker than the customers` specifications. Most of the VOC emissions can therefore be associated with the excess of paint applied to the products rather than to the required thickness of the coating. The higher paint usage rate has more than environmental consequences, it increases the cost of the applied coating. The project is to reduce the paint usage by controlling the viscosity of the coating in the tank. Experimental results as well as actual mass balance calculations show that using a higher VOC content paint would reduce the overall VOC emissions. The author explained the project to the Maryland Department of the Environment (MDE) Air and Radiation Management Administration. First, the MDE agreed to develop a new RACT determination for fabricated steel dipping operations. The new regulation would limit the amount of VOC than can be emitted to dip coat a ton of fabricated steel. Second, the MDE agreed to allow experimentation of the higher VOC content paint as a pilot project for the new regulation. This paper demonstrates the need for a RACT determination specific to fabricated steel dipping operations.

  8. Volatile organic compound emissions from Larrea tridentata (creosotebush)

    E-Print Network [OSTI]

    Jardine, K; Abrell, L; Kurc, SA; Huxman, T; Ortega, J; Guenther, A

    2010-01-01

    S. : Uptake of carbonyl sulfide (cos) and emission ofF. : The mass budgets of carbonyl sulfide, dimethyl sulfide,M. , and Mu, Y. J. : Carbonyl sulfide and dimethyl sulfide

  9. Volatile organic emissions from the distillation and pyrolysis of vegetation

    E-Print Network [OSTI]

    Greenberg, T

    2006-01-01

    D. W. T. : Emissions from smoldering combustion of biomassthe combustion process. Emission factors for biomass burning

  10. Volatile organic emissions from the distillation and pyrolysis of vegetation

    E-Print Network [OSTI]

    Greenberg, T

    2006-01-01

    emissions from vegetation pyrolysis Comprehensive laboratoryfrom the distillation and pyrolysis of vegetation J. P.J. Anal. and Appl. Pyrolysis, 60, 123–130, 2000. Fall, R. :

  11. A biogenic volatile organic compound emission inventory for Hong Kong

    E-Print Network [OSTI]

    Tsui, JK-Y; Guenther, A; Yip, W-K; Chen, F

    2009-01-01

    isoprene emissions from 15 Eucalyptus species in Australia.Cinnamomum camphora Cyclobalanopsis edithiae Eucalyptuscitriodora Eucalyptus robusta Eucalyptus torelliana Ficus

  12. Volatile organic emissions from the distillation and pyrolysis of vegetation

    E-Print Network [OSTI]

    Greenberg, T

    2006-01-01

    Pinus ponderosa, Eucalyptus saligna, Quercus gambelli,chem-phys.org/acp/6/81/ Eucalyptus J. P. Greenberg et al. :from vegetation pyrolysis Eucalyptus wood µ gC emission/gC/

  13. Modeling Emissions of Volatile Organic Compounds from New Carpets

    E-Print Network [OSTI]

    Little, J.C.

    2008-01-01

    BPt Name (abbreviation) Styrene (STY) Ethylbenzene andthe study carpets that have a styrene-butadiene rubber (SBR)coefficient, polymer backing, styrene-butadiene rubber,

  14. Comparative Toxicity of Combined Particle and Semi-Volatile Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Components Responsible for the Health Effects of Inhaled Engine Emissions Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles...

  15. Modeling Emissions of Volatile Organic Compounds from New Carpets

    E-Print Network [OSTI]

    Little, J.C.

    2008-01-01

    carpets that have a styrene-butadiene rubber (SBR) backing,polymer backing, styrene-butadiene rubber, environmentalbacking with styrene-butadiene rubber (SBR) latex adhesive.

  16. Effects of additional nonmethane volatile organic compounds, organic nitrates, and direct emissions of oxygenated organic

    E-Print Network [OSTI]

    Sillman, Sanford

    mechanism. The model was then extended by adding emissions and photochemical reactions for aromatic isoprene. Emissions of methanol, phenol, acetic acid and formic acid associated with biomass burning were. The extended model shows improved agreement with measurements for methanol, acetic acid and peroxypropional

  17. Quantifying the value that wind power provides as a hedge against volatile natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2002-01-01

    AGAINST VOLATILE NATURAL GAS PRICES Mark Bolinger, RyanAGAINST VOLATILE NATURAL GAS PRICES Mark Bolinger, Ryanwake of unprecedented natural gas price volatility during

  18. Volatile Species Retention During Metallic Fuel Casting

    SciTech Connect (OSTI)

    Randall S. Fielding; Douglas L. Proter

    2013-10-01

    Metallic nuclear fuels are candidate transmutation fuel forms for advanced fuel cycles. Through the operation of the Experimental Breeder Reactor II metallic nuclear fuels have been shown to be robust and easily manufactured. However, concerns have been raised concerning loss of americium during the casting process because of its high vapor pressure. In order to address these concerns a gaseous diffusion model was developed and a series of experiments using both manganese and samarium as surrogates for americium were conducted. The modeling results showed that volatility losses can be controlled to essentially no losses with a modest overpressure. Experimental results also showed volatile species retention down to no detectable losses through overpressure, although the loss values varied from the model results the same trend was seen. Bases on these results it is very probably that americium losses through volatility can be controlled to no detectable losses through application of a modest overpressure during casting.

  19. Non-volatile memory for checkpoint storage

    DOE Patents [OSTI]

    Blumrich, Matthias A.; Chen, Dong; Cipolla, Thomas M.; Coteus, Paul W.; Gara, Alan; Heidelberger, Philip; Jeanson, Mark J.; Kopcsay, Gerard V.; Ohmacht, Martin; Takken, Todd E.

    2014-07-22

    A system, method and computer program product for supporting system initiated checkpoints in high performance parallel computing systems and storing of checkpoint data to a non-volatile memory storage device. The system and method generates selective control signals to perform checkpointing of system related data in presence of messaging activity associated with a user application running at the node. The checkpointing is initiated by the system such that checkpoint data of a plurality of network nodes may be obtained even in the presence of user applications running on highly parallel computers that include ongoing user messaging activity. In one embodiment, the non-volatile memory is a pluggable flash memory card.

  20. Institutions and the Volatility Curse

    E-Print Network [OSTI]

    Leong, Weishu; Mohaddes, Kamiar

    2011-07-10

    and 12 can be found in the Middle East and North Africa (MENA) region. Our sample also includes 32 out of the 34 OECD countries and 8 out of the 12 of the Organization of the Petroleum Exporting Countries (OPEC). Thus our sample is very comprehensive... -Bissau Netherlands Tanzania Cameroon Guyana New Zealand Thailand Canada Haiti Nicaragua Togo Central African Rep. Honduras Niger Trinidad and Tobago Chad Hungary Nigeria Tunisia Chile India Norway Turkey China, People?s Rep. of Indonesia Oman Uganda Colombia Iran, I...

  1. Integration of Non-volatile Memory into Storage Hierarchy 

    E-Print Network [OSTI]

    Qiu, Sheng

    2013-12-04

    In this dissertation, we present novel approaches for integrating non-volatile memory devices into storage hierarchy of a computer system. There are several types of non- volatile memory devices, such as flash memory, Phase ...

  2. Cursed Resources? Political Conditions and Oil Market Volatility*

    E-Print Network [OSTI]

    Edwards, Paul N.

    a country's political conditions affect oil production within its borders. We show production, with very democratic regimes exhibiting less volatility in their oil production than more of oil production volatility. Our finding has implications both for understanding world oil markets

  3. CEC-500-2010-FS-017 Volatility of Ultrafine Particulate

    E-Print Network [OSTI]

    Gas Vehicles TRANSPORTATION ENERGY RESEARCH PIER Transportation Research www. Limited research has been done to characterize compressed natural gas mass emissions and practically-volatile and semi-volatile fractions of ultrafine particulate matter emissions from compressed natural gas vehicles

  4. Storage Systems for Non-volatile Memory Devices 

    E-Print Network [OSTI]

    Wu, Xiaojian

    2011-10-21

    This dissertation presents novel approaches to the use of non-volatile memory devices in building storage systems. There are many types of non-volatile memory devices, and they usually have better performance than regular magnetic hard disks...

  5. Ultra High Frequency Volatility Estimation with Dependent Microstructure Noise

    E-Print Network [OSTI]

    Ultra High Frequency Volatility Estimation with Dependent Microstructure Noise Yacine Aït sampled at frequencies high enough for that noise to be a dominant consideration. We show that combining; Serial dependence; High frequency data; Realized volatility; Sub- sampling; Two Scales Realized

  6. Forecasting Stock Market Volatility: Evidence from Fourteen Countries. 

    E-Print Network [OSTI]

    Balaban, Ercan; Bayar, Asli; Faff, Robert

    2002-01-01

    This paper evaluates the out-of-sample forecasting accuracy of eleven models for weekly and monthly volatility in fourteen stock markets. Volatility is defined as within-week (within-month) standard deviation of continuously ...

  7. Essays on Financial Market Volatility and Real Economic Activity

    E-Print Network [OSTI]

    Choi, Sang Yup

    2015-01-01

    we add the volatility of crude oil prices (West Texas Inter-Federal Funds Rate Corr w/ changes in Crude oil price Corrw/ Crude oil price volatility* Corr w/ changes in Baa-Aaa

  8. X-ray elemental online analyzer measures volatiles

    SciTech Connect (OSTI)

    Klein, A.; Pilz, K.; Reich, K. [Indutech Instruments GmbH, Simmersfeld (Germany)

    2008-04-15

    The use of an online XRF analyser for determining the volatiles content of coal is outlined. 3 figs.

  9. Volatility Persistence in Crude Oil Markets Amlie CHARLES

    E-Print Network [OSTI]

    Boyer, Edmond

    Volatility Persistence in Crude Oil Markets Amélie CHARLES Audencia Nantes, School of Management announcements on production reduction or US announcements on crude inventories. We find that the crude oil on the volatility modelling process improve the understanding of volatility in crude oil markets. Keywords: Crude

  10. Robust Replication of Volatility Derivatives and Roger Lee

    E-Print Network [OSTI]

    Lee, Roger

    The tradeoff between risk and return is a central theme of finance, and volatility and variance of returns are standard measures of risk. The volatility of a stock is revealed by the market price of an option, allow us to replicate volatility derivatives, by dynamic trading in standard options and the underlying

  11. Study of building material emissions and indoor air quality

    E-Print Network [OSTI]

    Yang, Xudong, 1966-

    1999-01-01

    Building materials and furnishings emit a wide variety of indoor pollutants, such as volatile organic compounds (VOCs). At present, no accurate models are available to characterize material emissions and sorption under ...

  12. Computational Study of Chain Transfer to Monomer Reactions in High-Temperature Polymerization of Alkyl Acrylates

    E-Print Network [OSTI]

    Rappe, Andrew M.

    paint and coatings, adhesives, and functional additives.1-5 The basic nature of acrylic resins limits on allowable volatile organic contents (VOCs) of resins.6-8 High temperature (>100 °C

  13. NAQSAT National Air Quality Site Assessment Tool NAQSAT National Air Quality Site Assessment Tool

    E-Print Network [OSTI]

    of diet and feed management, animal housing, manure collec- tion, transfer and storage, land application minimize odor, ammonia, hydrogen sulfide, methane, dust and volatile organic com- pound (VOC) emissions

  14. Laboratory simulation of subsurface airflow beneath a building

    E-Print Network [OSTI]

    Corsello, Joseph William

    2014-01-01

    Vapor intrusion is the vapor-phase migration of volatile organic compounds (VOCs) into buildings due to subsurface soil or groundwater contamination. Oxygen replenishment rates beneath a building are significant for ...

  15. Vapor intrusion modeling : limitations, improvements, and value of information analyses

    E-Print Network [OSTI]

    Friscia, Jessica M. (Jessica Marie)

    2014-01-01

    Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

  16. Evaluation of the pathways of tropospheric nitrophenol formation from benzene and phenol using a multiphase model 

    E-Print Network [OSTI]

    Heal, Mathew R; Harrison, Mark A J; Cape, Neil

    2005-01-01

    Phenols are a major class of volatile organic compounds (VOC) whose reaction within, and partitioning between, the gas and liquid phases affects their lifetime within the atmosphere, the local oxidising capacity, and the ...

  17. DOE/CBFO-11-3479 Panel Closure System Design

    E-Print Network [OSTI]

    of View Attachment B: Effective Permeability of the Redesigned Panel Closure System Attachment C: Summary Concrete TRU Transuranic VOC Volatile Organic Compound WIPP Waste Isolation Pilot Plant #12;iii Glossary

  18. PDID: Pulsed-Discharge Ionization Detector A new detector for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DE-AC04-94AL85000. SAND2015-1387C Sandia's Volatile Organic Compound (VOC) Biomarker Detection Technology 0.25" grid Photons emitted from a miniaturized helium plasma source...

  19. Ground-level ozone in eastern North America : its formation and transport

    E-Print Network [OSTI]

    Zemba, Stephen G.

    1990-01-01

    Ozone (Os), a natural component of the troposphere, is augmented by photochemical processes involving manmade emissions of nitrogen oxides (NOx) and volatile organic compounds (VOCs). Sufficiently high concentrations of ...

  20. Environmental Control of Isoprene Emission: from Leaf to Canopy Scale 

    E-Print Network [OSTI]

    Pegoraro, Emiliano

    Isoprene is the most abundant volatile organic compound (VOC) emitted from vegetation, mainly trees. Because it plays an important role in tropospheric chemistry leading to formation of pollutants and enhancing the lifetime ...

  1. A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States

    E-Print Network [OSTI]

    Sun, Lin, S.M. Massachusetts Institute of Technology

    2009-01-01

    Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

  2. Source Contributions to VOC's to Ozone Formation in Southeast Texas Using a Source-oriented Air Quality Model 

    E-Print Network [OSTI]

    Krishnan, Anupama

    2011-08-08

    and petrochemical industries to ozone formation in the atmosphere. Source-oriented emissions needed to drive the model were generated using a revised Sparse Matrix Operator Kernel Emissions (SMOKE) model version 2.4. VOC/NOx ratios are found to be a critical factor...

  3. Flexible CHP System with Low NOx, CO, and VOC Emissions- Presentation by the Gas Technology Institute (GTI), June 2011

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio Review Meeting in Washington, D.C. on June 1-2, 2011.

  4. Behavior of Field-Scale Biotrickling Filter under Nonsteady State Conditions

    E-Print Network [OSTI]

    , because conditions nutrient feeding in biotrickling fil- ters promote biomass growth, clogging of volatile organic com- pound VOC degrading biotrickling filters by excess biomass has been reported in a number,b . This has been a major obstacle to the deployment of biotrickling filtration for VOC control in the field

  5. Planta (2007) 226:839851 DOI 10.1007/s00425-007-0530-2

    E-Print Network [OSTI]

    Paré, Paul W.

    2007-01-01

    / Published online: 12 May 2007 © Springer-Verlag 2007 Abstract Certain plant growth-promoting rhizobacteria (PGPR), in the absence of physical contact with a plant stimulate growth via volatile organic compound (VOC) emissions, through largely unknown mechanisms. To probe how PGPR VOCs trigger growth in plants

  6. WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos

    E-Print Network [OSTI]

    Paulos, Eric

    and health from people who are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide

  7. WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos

    E-Print Network [OSTI]

    Chen, Yiling

    are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

  8. Role of ethylene on surface oxidation of TiO2(110) Y. Murata, V. Petrova, I. Petrov, C. V. Ciobanu, and S. Kodambaka

    E-Print Network [OSTI]

    Ciobanu, Cristian

    ,6 and photo-assisted purification of volatile organic compounds (VOCs),7 as a support for metal catalysts,8 all of the above-mentioned applications, TiO2 is well-known for its photo-assisted oxidation of VOCs understanding of the factors controlling the surface stoichiometry is critical for rational design of high

  9. Atmos. Chem. Phys., 9, 16471664, 2009 www.atmos-chem-phys.net/9/1647/2009/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    and Physics SCIAMACHY formaldehyde observations: constraint for isoprene emission estimates over Europe? G. Formaldehyde (HCHO) is an important interme- diate compound in the degradation of volatile organic com- pounds (VOCs) in the troposphere. Sources of HCHO are largely dominated by its secondary production from VOC

  10. Volatiles as a link between planetary interiors and the environment

    E-Print Network [OSTI]

    Black, Benjamin A. (Benjamin Alexander)

    2013-01-01

    Volatiles derived from planetary interiors influence magma evolution and environmental processes. Over appropriate timescales, Earth's mantle, crust, ocean, and atmosphere constitute coupled systems. The apparently synchronous ...

  11. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be...

  12. Evaluation of Models for Solubility and Volatility of Copper...

    Office of Scientific and Technical Information (OSTI)

    Title: Evaluation of Models for Solubility and Volatility of Copper Compounds Under Steam Generation Conditions The loss in efficiency of power plants with mixed metallurgy,...

  13. A Big Data Approach to Analyzing Market Volatility

    E-Print Network [OSTI]

    Wu, Kesheng

    2014-01-01

    A Big Data Approach to Analyzing Market Volatility KeshengUniversity of California. A Big Data Approach to Analyzingefforts to handle the big data problem. However, the

  14. Volatiles in hydrothermal fluids- A mass spectrometric study...

    Open Energy Info (EERE)

    Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  15. Guava leaf volatiles and dimethyl disulphide inhibit response of Diaphorina citri Kuwayama to host plant volatiles

    E-Print Network [OSTI]

    Burns, Jacqueline K.

    bacteria in the genus Liberibacter, which are the causal agents of huang- longbing (HLB) (Tsai et al. 1988 citrus with guava, Psidium guajava L., was reported to reduce D. citri populations and incidence of HLB conducted to compare sulphur volatile profiles of citrus and guava, used in our behavioural assays

  16. Atmos. Chem. Phys., 12, 1179511817, 2012 www.atmos-chem-phys.net/12/11795/2012/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    the atmospheric oxidation of volatile organic compounds (VOCs) leads to low volatility products that partition- acterize SOA. Laboratory chamber studies are essential to understand the lifecycle of organics involved of the complete suite of compounds involved in SOA formation is generally not feasible, key observations can

  17. PSERC 98-22 "Market Power and Price Volatility in

    E-Print Network [OSTI]

    PSERC 98-22 "Market Power and Price Volatility in Restructured Markets for Electricity" Tim Mount/IEEE Service Center/445 Hoes Lane/P.O. Box 1331/Piscataway, NJ 08855-1331, USA. Telephone: + Intl. 908-562-3966. #12;MARKET POWER AND PRICE VOLATILITY IN RESTRUCTURED MARKETS FOR ELECTRICITY Tim Mount School

  18. Multivariate High-Frequency-Based Volatility (HEAVY) Models Diaa Noureldin

    E-Print Network [OSTI]

    Wolfe, Patrick J.

    Multivariate High-Frequency-Based Volatility (HEAVY) Models Diaa Noureldin Department of Economics.sheppard@economics.ox.ac.uk February 18, 2011 Abstract This paper introduces a new class of multivariate volatility models multivariate GARCH models. We also discuss their covariance targeting speci...cation and provide closed

  19. MARKET VOLATILITY AND FEEDBACK EFFECTS FROM DYNAMIC HEDGING1

    E-Print Network [OSTI]

    Frey, Rüdiger

    expression for the transformation of market volatility under the impact of such strategies. It turns outMARKET VOLATILITY AND FEEDBACK EFFECTS FROM DYNAMIC HEDGING1 Rudiger Frey Department of Statistics, University of Bonn, D-53113 Bonn, Germany Alexander Stremme Financial Markets Group, London School

  20. Scaling and memory in volatility return intervals in financial markets

    E-Print Network [OSTI]

    Stanley, H. Eugene

    markets, we study the return intervals between the daily volatilities of the price changes that are above.federal- reserve.gov releases H10 hist. We choose to study daily data records because there are intraday trendsScaling and memory in volatility return intervals in financial markets Kazuko Yamasaki* , Lev

  1. Numerical Convergence Properties of Option Pricing PDEs with Uncertain Volatility

    E-Print Network [OSTI]

    Forsyth, Peter A.

    is then simply the cost of this hedge. The principal source of risk is the price of the underlying assetNumerical Convergence Properties of Option Pricing PDEs with Uncertain Volatility D. M. Pooley , P, 2001 Abstract The pricing equations derived from uncertain volatility models in finance are often cast

  2. IMPLICIT SOLUTION OF UNCERTAIN VOLATILITY/TRANSACTION COST

    E-Print Network [OSTI]

    Forsyth, Peter A.

    IMPLICIT SOLUTION OF UNCERTAIN VOLATILITY/TRANSACTION COST OPTION PRICING MODELS WITH DISCRETELY OBSERVED BARRIERS P.A. FORSYTH \\Lambda AND K.R. VETZAL y Abstract. Option pricing models with uncertain volatility/transaction costs give rise to a nonlinear PDE. Previous work has focussed on explicit methods

  3. Mechanisms of Organic-inorganic Interactions in Soils and Aqueous Environments Elucidated using Calorimetric Techniques 

    E-Print Network [OSTI]

    Harvey, Omar R.

    2011-08-08

    : bacteria, viruses and spores; roads, tire and brake abrasions; and fine soil particles [20]. Secondary organic aerosols (SOAs) are formed through condensation of VOCs in the atmosphere [20]. Estimates of atmospheric organic matter production are very... of the biochar formed during pyrolysis is dependent on combustion conditions (eg. temperature, combustion duration and oxygen supply) and the chemistry of the original plant tissues. As combustion temperature increases transformation of plant tissues occur via...

  4. Moving contact line of a volatile fluid

    E-Print Network [OSTI]

    V. Janecek; B. Andreotti; D. Prazak; T. Barta; V. S. Nikolayev

    2012-12-15

    Interfacial flows close to a moving contact line are inherently multi-scale. The shape of the interface and the flow at meso- and macroscopic scales inherit an apparent interface slope and a regularization length, both called after Voinov, from the dynamical processes at work at the microscopic level. Here, we solve this inner problem in the case of a volatile fluid at equilibrium with its vapor. The evaporative/condensation flux is then controlled by the dependence of the saturation temperature on interface curvature -- the so-called Kelvin effect. We derive the dependencies of the Voinov angle and of the Voinov length as functions of the substrate temperature. The relevance of the predictions for experimental problems is finally discussed.

  5. Moving contact line of a volatile fluid

    E-Print Network [OSTI]

    Janecek, V; Prazak, D; Barta, T; Nikolayev, V S

    2012-01-01

    Interfacial flows close to a moving contact line are inherently multi-scale. The shape of the interface and the flow at meso- and macroscopic scales inherit an apparent interface slope and a regularization length, both called after Voinov, from the dynamical processes at work at the microscopic level. Here, we solve this inner problem in the case of a volatile fluid at equilibrium with its vapor. The evaporative/condensation flux is then controlled by the dependence of the saturation temperature on interface curvature -- the so-called Kelvin effect. We derive the dependencies of the Voinov angle and of the Voinov length as functions of the substrate temperature. The relevance of the predictions for experimental problems is finally discussed.

  6. Design of Semiconductor-Based Back Reflectors for High Voc Monolithic Multijunction Solar Cells: Preprint

    SciTech Connect (OSTI)

    Garcia, I.; Geisz, J.; Steiner, M.; Olson, J.; Friedman, D.; Kurtz, S.

    2012-06-01

    State-of-the-art multijunction cell designs have the potential for significant improvement before going to higher number of junctions. For example, the Voc can be substantially increased if the photon recycling taking place in the junctions is enhanced. This has already been demonstrated (by Alta Devices) for a GaAs single-junction cell. For this, the loss of re-emitted photons by absorption in the underlying layers or substrate must be minimized. Selective back surface reflectors are needed for this purpose. In this work, different architectures of semiconductor distributed Bragg reflectors (DBR) are assessed as the appropriate choice for application in monolithic multijunction solar cells. Since the photon re-emission in the photon recycling process is spatially isotropic, the effect of the incident angle on the reflectance spectrum is of central importance. In addition, the DBR structure must be designed taking into account its integration into the monolithic multijunction solar cells, concerning series resistance, growth economics, and other issues. We analyze the tradeoffs in DBR design complexity with all these requirements to determine if such a reflector is suitable to improve multijunction solar cells.

  7. LANL organic analysis detection capabilities for chemical and biological warfare agents

    SciTech Connect (OSTI)

    Ansell, G.B.; Cournoyer, M.E.; Hollis, K.W.; Monagle, M.

    1996-12-31

    Organic analysis is the analytical arm for several Los Alamos National Laboratory (LANL) research programs and nuclear materials processes, including characterization and certification of nuclear and nonnuclear materials used in weapons, radioactive waste treatment and waste certification programs. Organic Analysis has an extensive repertoire of analytical technique within the group including headspace gas, PCBs/pesticides, volatile organics and semivolatile organic analysis. In addition organic analysis has mobile labs with analytic capabilities that include volatile organics, total petroleum hydrocarbon, PCBs, pesticides, polyaromatic hydrocarbons and high explosive screening. A natural extension of these capabilities can be applied to the detection of chemical and biological agents,

  8. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, Terrence L. (Lenior City, TN); Wilson, James H. (Oak Ridge, TN)

    1993-01-01

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing.

  9. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, T.L.; Wilson, J.H.

    1993-09-21

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

  10. Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

    2011-09-28

    This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

  11. Measurement of fragmentation and functionalization pathways in the heterogeneous oxidation of oxidized organic aerosol

    E-Print Network [OSTI]

    Kroll, Jesse

    The competition between the addition of polar, oxygen-containing functional groups (functionalization) and the cleavage of C–C bonds (fragmentation) has a governing influence on the change in volatility of organic species ...

  12. Bond Price Volatility c2012 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 75

    E-Print Network [OSTI]

    Lyuu, Yuh-Dauh

    Bond Price Volatility c2012 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 75 #12;"Well Taiwan University Page 76 #12;Price Volatility · Volatility measures how bond prices respond to interest-coupon bonds here. c2012 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 77 #12;Price Volatility

  13. Bond Price Volatility c 2008 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 71

    E-Print Network [OSTI]

    Lyuu, Yuh-Dauh

    Bond Price Volatility c 2008 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 71 #12;"Well Taiwan University Page 72 #12;Price Volatility · Volatility measures how bond prices respond to interest-coupon bonds throughout. c 2008 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 73 #12;Price Volatility

  14. Bond Price Volatility c 2011 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 74

    E-Print Network [OSTI]

    Lyuu, Yuh-Dauh

    Bond Price Volatility c 2011 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 74 #12;"Well Taiwan University Page 75 #12;Price Volatility · Volatility measures how bond prices respond to interest-coupon bonds throughout. c 2011 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 76 #12;Price Volatility

  15. Volatility and Growth: Credit Constraints and the Composition of Investment

    E-Print Network [OSTI]

    Aghion, Philippe

    How does uncertainty and credit constraints affect the cyclical composition of investment and thereby volatility and growth? This paper addresses this question within a model where firms engage in two types of investment: ...

  16. Temporal Geochemical Variations In Volatile Emissions From Mount...

    Open Energy Info (EERE)

    Temporal Geochemical Variations In Volatile Emissions From Mount St Helens, Usa, 1980-1994 Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  17. The impact of fuel price volatility on transportation mode choice

    E-Print Network [OSTI]

    Kim, Eun Hie

    2009-01-01

    In recent years, the price of oil has driven large fluctuations in the price of diesel fuel, which is an important cost component in freight logistics. This thesis explores the impact of fuel price volatility on supply ...

  18. Neuropeptide alterations in the tree shrew hypothalamus during volatile anesthesia

    E-Print Network [OSTI]

    Neuropeptide alterations in the tree shrew hypothalamus during volatile anesthesia Laetitia spectral analysis, we first identified 85 peptides from the tree shrew hypothalamus. Differential analysis Tree shrew Neuropeptide Hypothalamus Anesthesia 1. Introduction General anesthesia is characterized

  19. Essays on Return and Volatility on World Stock Markets

    E-Print Network [OSTI]

    Liu, Jia

    2013-08-31

    sizes and etc. Those questions are addressed in this dissertation research. In Chapter 2, co-movements across worldwide stock markets are investigated. A dynamic factor model is designed to decompose stock return volatility into three orthogonal factors...

  20. Bulls, Bears and Excess Volatility: can currency intervention help?

    E-Print Network [OSTI]

    Corrado, Luisa; Miller, Marcus; Zhang, Lei

    and exit of currency 'bulls' and 'bears' with switches driven by 'draw-down' trading rules. We argue that non-sterilised intervention - in support of 'monitoring band' - can reduce excess volatility by coordinating beliefs in line with policy. Strategic...

  1. Financial distortions and the distribution of global volatility

    E-Print Network [OSTI]

    Eden, Maya Rachel

    2011-01-01

    In this thesis, I study the interactions between various aspects of the financial system and macroeconomic volatility in a globally integrated environment. In Chapter 1, I illustrate that an efficient allocation of liquidity ...

  2. Double Diffusion in Enclosure Bounded by Massive and Volatilizing Walls 

    E-Print Network [OSTI]

    Liu, D.; Tang, G.; Zhao, F.

    2006-01-01

    Hazard volatilization emitted from walls enters into airflow in the room, making the indoor air quality worse. An exterior wall of some thickness is affected on its surface by the outdoor air environment. In this paper, ...

  3. Volatility of Vanadia from Vanadia-Based SCR Catalysts under...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions TiO2-supported...

  4. Using Pre-Modeled Scenarios to Estimate Groundwater VOC Concentrations Resulting from Vadose Zone Sources

    SciTech Connect (OSTI)

    Oostrom, Martinus; Truex, Michael J.; Rice, Amy K.; Johnson, Christian D.; Carroll, Kenneth C.; Becker, Dave; Simon, Michelle A.

    2014-04-28

    Soil vapor extraction (SVE) is a prevalent remediation approach for volatile contaminants in the vadose zone. To support selection of an appropriate endpoint for the SVE remedy, an evaluation is needed to determine whether vadose zone contamination has been diminished sufficiently to protect groundwater. When vapor-phase transport is an important component of the overall contaminant fate and transport from a vadose zone source, the contaminant concentration expected in groundwater is controlled by a limited set of parameters, including specific site dimensions, vadose zone properties, and source characteristics. An approach was developed for estimating the contaminant concentration in groundwater resulting from a contaminant source in the vadose zone based on pre-modeling contaminant transport for a matrix of parameter value combinations covering a range of potential site conditions. An interpolation and scaling process are then applied to estimate groundwater impact for site-specific conditions.

  5. Detecting Contagion with Correlation: Volatility and Timing Matter

    E-Print Network [OSTI]

    Dungey, Mardi; Yalama, Abdullah

    , volatility spillover JEL Classi?cation: G01, C22, G15, C51. ?Yalama acknowledges support from an Eskisehir Osmangazi University Research Grant (200817046).The authors contact details are: Dungey; Mardi.Dungey@utas.edu.au, Yalama; Abdul- lah... countries during times of ?nancial crisis by comparing the results of the Forbes and Rigobon test with those of the Hong (2001) volatility spillover test. The second potentially important determinant of contagion outcomes is in the tim- ing of the collected...

  6. Gasoline volatility: Environmental interactions with blending and processing

    SciTech Connect (OSTI)

    Unzelman, G.H. [ed.

    1996-05-01

    Gasoline volatility has long been an economic consideration for petroleum refiners. Although front-end volatility and Rvp (Reid vapor pressure) are primary factors, volatility can impact any part of the distillation range. Specifications, whether in-house, exchange or pipeline, require flexibility to optimize the bottom line with respect to marketed composition. Utilizing lower-value butanes, within Rvp and ASTM distillation limits, to maximize gasoline volume has been traditional. Also, optimizing the T{sub 90} (ASTM distillation temperature at 90% distilled), raises the end point and has been used to extend the gasoline barrel. In most refining situations, controlling back-end gasoline volatility is a function of gasoline vs. distillate volume, the latter generally the lower-value product. Recently, the concept of gasoline reformulation collide with the less complex approach of simply reducing vapor pressure to improve air quality. Reducing Rvp of gasoline shifts front-end composition, while reformulation, especially under future Complex Model rules, shifts volatility and composition over the entire boiling range. While low Rvp vs. RFG is a recent issue, gasoline volatility has always been an economic factor in petroleum refining and a performance factor for the auto maker.

  7. New Air Cleaning Strategies for Reduced Commercial Building Ventilation Energy ? FY11 Final Report

    SciTech Connect (OSTI)

    Sidheswaran, Meera; Destaillats, Hugo; Cohn, Sebastian; Sullivan, Douglas P.; Fisk, William J.

    2011-10-31

    The research carried out in this project focuses on developing novel volatile organic compounds (VOCs) air cleaning technologies needed to enable energy-saving reductions in ventilation rates. we targeted a VOC air cleaning system that could enable a 50% reduction in ventilation rates. In a typical commercial HVAC system that provides a mixture of recirculated and outdoor air, a VOC air cleaner in the supply airstream must have a 15% to 20% VOC removal efficiency to counteract a 50% reduction in outdoor air supply.

  8. Method of increasing biodegradation of sparingly soluble vapors

    DOE Patents [OSTI]

    Cherry, Robert S. (Idaho Falls, ID)

    2000-01-01

    A method for increasing biodegradation of sparingly soluble volatile organic compounds (VOCs) in a bioreactor is disclosed. The method comprises dissolving in the aqueous phase of the bioreactor a water soluble, nontoxic, non-biodegradable polymer having a molecular weight of at least 500 and operable for decreasing the distribution coefficient of the VOCs. Polyoxyalkylene alkanols are preferred polymers. A method of increasing the growth rate of VOC-degrading microorganisms in the bioreactor and a method of increasing the solubility of sparingly soluble VOCs in aqueous solution are also disclosed.

  9. Volatility literature of chlorine, iodine, cesium, strontium, technetium, and rhenium; technetium and rhenium volatility testing

    SciTech Connect (OSTI)

    Langowski, M.H.; Darab, J.G.; Smith, P.A.

    1996-03-01

    A literature review pertaining to the volatilization of Sr, Cs, Tc (and its surrogate Re), Cl, I and other related species during the vitrification of Hanford Low Level Waste (LLW) streams has been performed and the relevant information summarized. For many of these species, the chemistry which occurs in solution prior to the waste stream entering the melter is important in dictating their loss at higher temperatures. In addition, the interactive effects between the species being lost was found to be important. A review of the chemistries of Tc and Re was also performed. It was suggested that Re would indeed act as an excellent surrogate for Tc in non-radioactive materials testing. Experimental results on Tc and Re loss from sodium aluminoborosilicate melts of temperatures ranging from 900--1350{degrees}C performed at PNL are reported and confirm that Re behaves in a nearly identical manner to that of technetium.

  10. Oxidation of volatiles in residential wood burning equipment. Final technical report, September 1980-February 1984

    SciTech Connect (OSTI)

    Malte, P.C.; Thornton, M.M.; Kamber, P.D.

    1984-04-01

    The objectives of this project are to measure, through the use of laboratory combustors, those conditions which promote complete combustion of wood volatiles in residential wood burning equipment. The conditions of interest are combustion temperature, residence time, stoichiometry, and air mixing. The project objectives are met through two laboratory approaches: (1) model compound studies: in order to measure the overall rates of oxidative pyrolysis of biomass volatiles, and to determine the types of intermediate organic species which are likely to form as part of this process, model compounds have been reacted in a specialized jet-stirred reactor, which has been developed as part of this research. (2) high-intensity wood combustion: in order to study the clean combustion of wood, that is, to investigate the conceptual design features required for clean burning, and to ascertain the levels and types of pollutant and condensible species which are most difficult to oxidize, a high-intensity, research wood combustor has been developed and examined for the different phases of the wood burning cycle. Although the objectives of the project have been met, it has not been possible, because of support limitations, to thoroughly explore several interesting aspects which have arisen because of this research. For example, a third laboratory system in which wood pyrolysis gas is injected directly into the a well characterized reactor, so that the kinetics and mechanisms of the gas-phase reaction of the actual biomass volatiles can be studied, could not be thoroughly developed. Refinements in the high-intensity wood combustor, which would bring its design features closer to practicality for the industry, could not be considered. 32 references, 37 figures, 10 tables.

  11. Integrated system for the destruction of organics by hydrolysis and oxidation with peroxydisulfate

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Balazs, G. Bryan (Livermore, CA); Hsu, Peter (Pleasanton, CA); Lewis, Patricia R. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2000-01-01

    An integrated system for destruction of organic waste comprises a hydrolysis step at moderate temperature and pressure, followed by direct chemical oxidation using peroxydisulfate. This system can be used to quantitatively destroy volatile or water-insoluble halogenated organic solvents, contaminated soils and sludges, and the organic component of mixed waste. The hydrolysis step results in a substantially single phase of less volatile, more water soluble hydrolysis products, thus enabling the oxidation step to proceed rapidly and with minimal loss of organic substrate in the off-gas.

  12. An advanced hybrid reprocessing system based on UF{sub 6} volatilization and chromatographic separation

    SciTech Connect (OSTI)

    Wei, Yuezhou; Liu, Ruiqin; Wu, Yan; Zu, Jianhua; Zhao, Long; Mimura, Hitoshi; Shi, Weiqun; Chai, Zhifang; Yang, Jinling; Ding, Youqian

    2013-07-01

    To recover U, Pu, MA (Np, Am, Cm) and some specific fission products FPs (Cs, Sr, Tc, etc.) from various spent nuclear fuels (LWR/FBR: Oxide, Metal Fuels), we are studying an advanced hybrid reprocessing system based on UF6 volatilization (Pyro) and chromatographic separation (Aqueous). Spent fuels are de-cladded by means of thermal and mechanical methods and then applied to the fluorination/volatilization process, which selectively recovers the most amount of U. Then, the remained fuel components are converted to oxides and dissolved by HNO{sub 3} solution. Compared to U, since Pu, MA and FPs are significantly less abundant in spent fuels, the scale of the aqueous separation process could become reasonably small and result in less waste. For the chromatographic separation processes, we have prepared different types of porous silica-based organic/inorganic adsorbents with fast diffusion kinetics, improved chemical stability and low pressure drop in a packed column. So they are advantageously applicable to efficient separation of the actinides and FP elements from the fuel dissolved solution. In this work, adsorption and separation behavior of representative actinides and FP elements was studied. Small scale separation tests using simulated and genuine fuel dissolved solutions were carried out to verify the feasibility of the proposed process. (authors)

  13. Quantifying the value that wind power provides as a hedge against volatile natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2002-01-01

    Gas Pricing by Regulated Natural Gas Utilities, Docket No.A HEDGE AGAINST VOLATILE NATURAL GAS PRICES Mark Bolinger,A HEDGE AGAINST VOLATILE NATURAL GAS PRICES Mark Bolinger,

  14. Recovery of manganese oxides from spent alkaline and zinc–carbon batteries. An application as catalysts for VOCs elimination

    SciTech Connect (OSTI)

    Gallegos, María V.; Falco, Lorena R.; Peluso, Miguel A.; Sambeth, Jorge E.; Thomas, Horacio J.

    2013-06-15

    Highlights: • Manganese oxides were synthesized using spent batteries as raw materials. • Spent alkaline and zinc–carbon size AA batteries were used. • A biohydrometallurgical process was employed to bio-lixiviate batteries. • Manganese oxides were active in the oxidation of VOCs (ethanol and heptane). - Abstract: Manganese, in the form of oxide, was recovered from spent alkaline and zinc–carbon batteries employing a biohydrometallurgy process, using a pilot plant consisting in: an air-lift bioreactor (containing an acid-reducing medium produced by an Acidithiobacillus thiooxidans bacteria immobilized on elemental sulfur); a leaching reactor (were battery powder is mixed with the acid-reducing medium) and a recovery reactor. Two different manganese oxides were recovered from the leachate liquor: one of them by electrolysis (EMO) and the other by a chemical precipitation with KMnO{sub 4} solution (CMO). The non-leached solid residue was also studied (RMO). The solids were compared with a MnO{sub x} synthesized in our laboratory. The characterization by XRD, FTIR and XPS reveal the presence of Mn{sub 2}O{sub 3} in the EMO and the CMO samples, together with some Mn{sup 4+} cations. In the solid not extracted by acidic leaching (RMO) the main phase detected was Mn{sub 3}O{sub 4}. The catalytic performance of the oxides was studied in the complete oxidation of ethanol and heptane. Complete conversion of ethanol occurs at 200 °C, while heptane requires more than 400 °C. The CMO has the highest oxide selectivity to CO{sub 2}. The results show that manganese oxides obtained using spent alkaline and zinc–carbon batteries as raw materials, have an interesting performance as catalysts for elimination of VOCs.

  15. Quantifying the value that energy efficiency and renewable energy provide as a hedge against volatile natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Bachrach, Devra; Golove, William

    2002-01-01

    Gas Pricing by Regulated Natural Gas Utilities, Docket No.a Hedge Against Volatile Natural Gas Prices Mark Bolinger,wake of unprecedented natural gas price volatility during

  16. Quantifying the value that energy efficiency and renewable energy provide as a hedge against volatile natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Bachrach, Devra; Golove, William

    2002-01-01

    Against Volatile Natural Gas Prices Mark Bolinger, Ryanwake of unprecedented natural gas price volatility duringyears) to a 10-year natural gas price forecast (i.e. , what

  17. The Volatility of Liquidity and Expected Stock Returns 

    E-Print Network [OSTI]

    Akbas, Ferhat 1981-

    2011-07-29

    The pricing of total liquidity risk is studied in the cross-section of stock returns. The study suggests that there is a positive relation between total volatility of liquidity and expected returns. Our measure of liquidity is based on Amihud...

  18. Enhanced phytoremediation of volatile environmental pollutants with transgenic trees

    E-Print Network [OSTI]

    Brown, Sally

    , and approved September 12, 2007 (received for review April 9, 2007) Small, volatile hydrocarbons, including systems, these transgenic poplars may provide the means to effectively remediate sites contaminated-and-treat systems as they take up water-soluble contam- inants through their roots and transport/translocate them

  19. Predicting Market-Volatility from Federal Reserve Board Meeting Minutes

    E-Print Network [OSTI]

    Gordon, Geoffrey J.

    been applied to predict intra-day stock market returns, e.g. by (Pui Cheong Fung et al., 2003Predicting Market-Volatility from Federal Reserve Board Meeting Minutes NLP for Finance Reza Bosagh Zadeh, Andreas Zollmann 1 Introduction Predicting markets has always had a certain appeal to researchers

  20. Correct quantitative determination of ethanol and volatile compounds in alcohol products

    E-Print Network [OSTI]

    Charapitsa, Siarhei; Sytova, Svetlana; Yakuba, Yurii

    2014-01-01

    Determination of the volume content of ethanol in the alcohol products in practice is usually determined by pycnometry, electronic densimetry, or densimetry using a hydrostatic balance in accordance with Commission Regulation No 2870/2000. However, these methods determine directly only density of the tested liquid sample and does not take into account the effects of other volatile components such as aldehydes, esters and higher alcohols. So they are appropriate only for binary water-ethanol solutions in accordance with international table adopted by the International Legal Metrology Organization in its Recommendation No 22. Availability notable concentrations of the higher alcohols and ethers in different alcohol-based products, e. g. in whisky, cognac, brandy, wine as well as in waste alcohol and alcohol beverage production, leads to the significant contribution of these compounds in the value of the density of tested alcohol-containing sample. As a result, determination of the volume of ethanol content for ...

  1. Gasoline price volatility and the elasticity of demand for gasoline1 C.-Y. Cynthia Lina

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    - 1 - Gasoline price volatility and the elasticity of demand for gasoline1 C.-Y. Cynthia Lina, California Abstract We examine how gasoline price volatility impacts consumers' price elasticity of demand for gasoline. Results show that volatility in prices decreases consumer demand for gasoline in the intermediate

  2. Statistics and Its Interface Volume 1 (2008) 279288 Spot volatility estimation for high-frequency data

    E-Print Network [OSTI]

    Fan, Jianqing

    2008-01-01

    Statistics and Its Interface Volume 1 (2008) 279­288 Spot volatility estimation for high-frequency data Jianqing Fan and Yazhen Wang The availability of high-frequency intraday data allows us and volatility of an asset and investigates kernel type estimators of spot volatility based on high-frequency

  3. Volatility and Risk Estimation with Linear and Nonlinear Methods Based on High Frequency

    E-Print Network [OSTI]

    Buehlmann, Peter

    Volatility and Risk Estimation with Linear and Nonlinear Methods Based on High Frequency Data of risk management. The use of high frequency data approximately renders volatility from a latent: (i) to select an accurate forecasting procedure for predicting volatilities based on high frequency

  4. ELSEVIER Physica A 245 (1997) 441445 Volatility distribution in the S&P500 stock index

    E-Print Network [OSTI]

    1997-01-01

    Cizeau a, Yanhui Liu a, Martin Meyer a, C.-K. Peng b,a, H. Eugene Stanley a,. aCenter Jbr Polymer Studies Deaconess Medical Center, Boston, MA 02215, USA Received 15 August 1997 Abstract We study the volatility; Volatility; S&P500; Multiplicative processes The volatility is a measure of the mean fluctuation of a market

  5. Wintertime aerosol chemical composition, volatility, and spatial variability in the greater London area

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, L.; Williams, L. R.; Young, D. E.; Allan, J. D.; Coe, H.; Massoli, P.; Fortner, E.; Chhabra, P.; Herndon, S.; Brooks, W. A.; et al

    2015-08-28

    The composition of PM1 (particulate matter with diameter less than 1 ?m) in the greater London area was characterized during the Clean Air for London (ClearfLo) project in winter 2012. Two High-Resolution Time-of-Flight Aerosol Mass Spectrometers (HR-ToF-AMS) were deployed at a rural site (Detling, Kent) and an urban site (North Kensington, London). The simultaneous and high-temporal resolution measurements at the two sites provide a unique opportunity to investigate the spatial distribution of PM1. We find that the organic aerosol (OA) concentration is comparable between the rural and urban sites, but the sources of OA are distinctly different. The concentration ofmore »solid fuel OA at the urban site is about twice as high as at the rural site, due to elevated domestic heating in the urban area. While the concentrations of oxygenated OA (OOA) are well-correlated between the two sites, the OOA concentration at the rural site is almost twice that of the urban site. At the rural site, more than 70 % of the carbon in OOA is estimated to be non-fossil, which suggests that OOA is likely related to aged biomass burning considering the small amount of biogenic SOA in winter. Thus, it is possible that the biomass burning OA contributes a larger fraction of ambient OA in wintertime than what previous field studies have suggested. A suite of instruments was deployed downstream of a thermal denuder (TD) to investigate the volatility of PM1 species at the rural Detling site. After heating at 250 °C in the TD, 40 % of the residual mass is OA, indicating the presence of non-volatile organics in the aerosol. Although the OA associated with refractory black carbon (rBC, measured by a soot-particle aerosol mass spectrometer) only accounts for « less

  6. Concentration of light organic compounds from dilute aqueous solutions by adsorption on bound silicalite 

    E-Print Network [OSTI]

    Flores, Kathryn Louise

    1989-01-01

    azeotrope, the solvent can enhance the volatility of either water or ethanol. Gasoline, when used as a solvent in the extractive distillation of azeotropic ethanol, enhances the volatility of water. The water and the lower boiling components... of the gasoline are taken ofF at the top of the column. The ethanol and the remaining components of the gasoline are collected at the bottom. The ethanol and organic compounds are separated from the water in the distillate from the extractive distillation...

  7. High Efficiency Organic Solar Cells: December 16, 2009 - February 2, 2011

    SciTech Connect (OSTI)

    Walker, K.; Joslin, S.

    2011-05-01

    Details on the development of novel organic solar cells incorporating Trimetasphere based acceptors are presented including: baseline performance for Lu-PCBEH acceptor blended with P3HT demonstrated at 4.89% PCE exceeding the 4.5% PCE goal; an increase of over 250mV in Voc was demonstrated for Lu-PCBEH blended with low band gap polymers compared to a comparable C60-PCBM device. The actual Voc was certified at 260mV higher for a low band gap polymer device using the Lu-PCBEH acceptor; and the majority of the effort was focused on development of a device with over 7% PCE. While low current and fill factors suppressed overall device performance for the low band gap polymers tested, significant discoveries were made that point the way for future development of these novel acceptor materials.

  8. Highly efficient inverted organic solar cells using amino acid modified indium tin oxide as cathode

    SciTech Connect (OSTI)

    Li, Aiyuan; Nie, Riming; Deng, Xianyu; Wei, Huaixin; Li, Yanqing; Tang, Jianxin; Zheng, Shizhao; Wong, King-Young

    2014-03-24

    In this paper, we report that highly efficient inverted organic solar cells were achieved by modifying the surface of indium tin oxide (ITO) using an amino acid, Serine (Ser). With the modification of the ITO surface, device efficiency was significantly enhanced from 0.63% to 4.17%, accompanied with an open circuit voltage (Voc) that was enhanced from 0.30?V to 0.55?V. Ultraviolet and X-ray photoelectron spectroscopy studies indicate that the work function reduction induced by the amino acid modification resulting in the decreased barrier height at the ITO/organic interface played a crucial role in the enhanced performances.

  9. Method for refreshing a non-volatile memory

    DOE Patents [OSTI]

    Riekels, James E. (New Hope, MN); Schlesinger, Samuel (Aventura, FL)

    2008-11-04

    A non-volatile memory and a method of refreshing a memory are described. The method includes allowing an external system to control refreshing operations within the memory. The memory may generate a refresh request signal and transmit the refresh request signal to the external system. When the external system finds an available time to process the refresh request, the external system acknowledges the refresh request and transmits a refresh acknowledge signal to the memory. The memory may also comprise a page register for reading and rewriting a data state back to the memory. The page register may comprise latches in lieu of supplemental non-volatile storage elements, thereby conserving real estate within the memory.

  10. Innovative technology summary report: in situ air stripping using horizontal wells

    SciTech Connect (OSTI)

    NONE

    1995-04-01

    In situ air stripping (ISAS) technology was developed to remediate soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISAS employs horizontal wells to inject (sparge) air into the ground water and vacuum extract VOCs from vadose zone soils. The innovation is creation of a system that combines two somewhat innovative technologies, air sparging and horizontal wells, with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

  11. Method for removing organic liquids from aqueous solutions and mixtures

    DOE Patents [OSTI]

    Hrubesh, Lawrence W.; Coronado, Paul R.; Dow, Jerome P.

    2004-03-23

    A method for removing organic liquids from aqueous solutions and mixtures. The method employs any porous material preferably in granular form and having small pores and a large specific surface area, that is hydrophobic so that liquid water does not readily wet its surface. In this method, organics, especially organic solvents that mix with and are more volatile than water, are separated from aqueous solution by preferentially evaporating across the liquid/solid boundary formed at the surfaces of the hydrophobic porous materials. Also, organic solvents that are immiscible with water, preferentially wet the surfaces of the hydrophobic material and are drawn within the porous materials by capillary action.

  12. Volatility of Power Grids under Real-Time Pricing

    E-Print Network [OSTI]

    Roozbehani, Mardavij; Mitter, Sanjoy K

    2011-01-01

    The paper proposes a framework for modeling and analysis of the dynamics of supply, demand, and clearing prices in power system with real-time retail pricing and information asymmetry. Real-time retail pricing is characterized by passing on the real-time wholesale electricity prices to the end consumers, and is shown to create a closed-loop feedback system between the physical layer and the market layer of the power system. In the absence of a carefully designed control law, such direct feedback between the two layers could increase volatility and lower the system's robustness to uncertainty in demand and generation. A new notion of generalized price-elasticity is introduced, and it is shown that price volatility can be characterized in terms of the system's maximal relative price elasticity, defined as the maximal ratio of the generalized price-elasticity of consumers to that of the producers. As this ratio increases, the system becomes more volatile, and eventually, unstable. As new demand response technolo...

  13. ATOC 3500/CHEM 3151 Spring 2014 Particulate Mass and Visibility

    E-Print Network [OSTI]

    Toohey, Darin W.

    atmosphere, volatile organic (VOCs) released from activities such as barbeques, fast-food restaurants, gas-powered lawn mowers, paint, etc., react photochemically to produce more oxidized compounds that tend'll see how much particulate a similar amount of hypothetical organic molecule can produce. (a) Assume

  14. Position Paper on Practicable Performance Criteria for the Removal Efficiency of Volatile Radionuclides

    SciTech Connect (OSTI)

    R. T. Jubin; N. Soelberg; D. M. Strachan

    2012-03-01

    As a result of fuel reprocessing, volatile radionuclides may be released from the facility stack if no processes are put in place to remove them. The radionuclides that are of concern in this document are 3H, 14C, 85Kr, and 129I. The question we attempted to answer is how efficient must this removal process be for each of these radionuclides? To answer this question, we examined the three regulations that may impact the degree to which these radionuclides must be reduced before process gases can be released from the facility. These regulations are 40 CFR 61 (EPA 2010a), 40 CFR 190(EPA 2010b), and 10 CFR 20 (NRC 2012). These regulations apply to the total radionuclide release and to a particular organ - the thyroid. Because these doses can be divided amongst all the radionuclides in different ways and even within the four radionuclides in question, we provided several cases. We first looked at the inventories for these radionuclides for three fuel types (PWR UOX, PWR MOX, and AHTGR), several burn-up values, and time out of reactor extending to 200 y. We calculated doses to the maximum exposed individual (MEI) with the EPA code CAP-88 (Rosnick 1992). Finally, we looked at two dose cases. Allocating all of the allowable dose to be used by the volatile radionuclides is one case, but, perhaps, unrealistic. In lieu of this, we arbitrarily selected a value of 10% of the allowable dose to be assigned to the volatile radionuclides. We calculated the required decontamination factors (DFs) for both of these cases, including the case for the thyroid dose for which 14C and 129I were the main contributors. With respect to 129I doses, we found that the highest dose was calculated with iodine as a fine particulate. The dose scaled as the fraction of the total 129I that was particulate. Therefore, we assumed for all of our calculations that 100% of the 129I was particulate and allow the user of the results given here to scale our calculated doses to their needs.

  15. Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years

    SciTech Connect (OSTI)

    Sindelarova, K.; Granier, Claire; Bouarar, I.; Guenther, Alex B.; Tilmes, S.; Stavrakou, T.; Muller, J. F.; Kuhn, U.; Stefani, P.; Knorr, W.

    2014-09-09

    The Model of Emissions of Gases and Aerosols from Nature (MEGANv2.1) together with the Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields were used to create a global emission dataset of biogenic VOCs available on a monthly basis for the time period of 1980 - 2010. This dataset is called MEGAN-MACC. The model estimated mean annual total BVOC emission of 760 Tg(C) yr1 consisting of isoprene (70%), monoterpenes (11%), methanol (6%), acetone (3%), sesquiterpenes (2.5%) and other BVOC species each contributing less than 2 %. Several sensitivity model runs were performed to study the impact of different model input and model settings on isoprene estimates and resulted in differences of * 17% of the reference isoprene total. A greater impact was observed for sensitivity run applying parameterization of soil moisture deficit that led to a 50% reduction of isoprene emissions on a global scale, most significantly in specific regions of Africa, South America and Australia. MEGAN-MACC estimates are comparable to results of previous studies. More detailed comparison with other isoprene in ventories indicated significant spatial and temporal differences between the datasets especially for Australia, Southeast Asia and South America. MEGAN-MACC estimates of isoprene and*-pinene showed a reasonable agreement with surface flux measurements in the Amazon andthe model was able to capture the seasonal variation of emissions in this region.

  16. A study of the tropospheric oxidation of volatile organic compounds using chemical ionization mass spectrometry

    E-Print Network [OSTI]

    Broekhuizen, Keith Edward, 1974-

    2002-01-01

    The mechanisms and kinetics of reactions important to the troposphere have been investigated using a high pressure, turbulent, discharge-flow technique coupled to a chemical ionization mass spectrometer. The ability to ...

  17. Concentrations and fluxes of atmospheric biogenic volatile organic compounds by proton transfer reaction mass spectrometry 

    E-Print Network [OSTI]

    Misztal, Pawel K.

    2010-01-01

    will be of value to the wider flux measurement community. A novel approach to determining the lag time between the vertical wind measurement and the air concentration measurement has been developed that will greatly reduce the uncertainty in the derived flux...

  18. Measurements and receptor modeling of volatile organic compounds in Southeastern Mexico City, 2000 2007

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    paint (VINPA), liquefied petroleum gas (LPG), hot soak (HOTS), vehicle exhaust (EXHTI and EXHTN) from Instituto Nacional de Ecologia, unpublished. SOLVENT LPG HOTSOAK EXHAUST _________________ ______ _______ ____________________________________ VINPA VARNISH LPG HOTS EXHTI EXHTN EXHTG1 EXHTG2 Ethane 0.000 0.000 0.011 0.004 0.033 0.017 0.029 0

  19. Impact of California Reformulated Gasoline on Motor Vehicle Emissions. 2. Volatile Organic Compound Speciation and Reactivity

    E-Print Network [OSTI]

    Kirchstetter, Thomas; Singer, Brett; Harley, Robert

    1999-01-01

    California Reformulated Gasoline On Motor Vehicle EmissionsCalifornia Reformulated Gasoline on Motor Vehicle EmmissionsBerkeley Environ. ScLTechnoL gasoline Impact California of

  20. Factors Affecting Indoor Air Concentrations of Volatile Organic Compounds at a Site of Subsurface Gasoline Contamination

    E-Print Network [OSTI]

    Fischer, M.L.

    2011-01-01

    AT A SITE OF SUBSURFACE GASOLINE CONTAMINATION Marc L.A T A SITE OF SUBSURFACE GASOLINE CONTAMINATION Marc L.a site contaminated with gasoline. Although the high V O C

  1. Tethered balloon measurements of biogenic volatile organic compounds at a Boreal forest site

    E-Print Network [OSTI]

    Spirig, VC

    2004-01-01

    the distance upwind where the crosswind-integrated footprintand the maximum of the crosswind- integrated footprint

  2. Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity

    E-Print Network [OSTI]

    Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

    2009-01-01

    ethane, ethene, propane, propene, acetylene, i- butane,n-butane, 1-butene, trans-2-butene, cis-2-butene, i-pentane,some alkanes (e.g. propane, i-butane, n-butane) (Blake and

  3. Regional Analysis of Nonmethane Volatile Organic Compounds in the Lower Troposphere of the Southeast

    E-Print Network [OSTI]

    Aneja, Viney P.

    , acetylene, propane, i-butane, and n-butane with a winter maximum and a summer minimum. An analysis

  4. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    E-Print Network [OSTI]

    2010-01-01

    MEX 1 . Compound C-130 T0 T1 G1 Ethane Propane i-Butanen-Butane i-Pentane n-Pentane n-Hexane n-Heptane n-OctaneEthyne Propane Propene i-Butane n-Butane 1-Butene + i-Butene

  5. Source characteristics of volatile organic compounds during high ozone episodes in Hong Kong, Southern China

    E-Print Network [OSTI]

    Zhang, J.; Wang, T.; Chameides, W. L; Cardelino, C.; Blake, D. R; Streets, D. G

    2008-01-01

    Kong. Species TO EPD sites Methane Ethane Propane n-butanei-butane n-pentane i-pentane n-hexane 2,2-dimethybutane 2,3-Species Ethane Propane n-butane i-butane n-pentane i-pentane

  6. Factors Affecting Indoor Air Concentrations of Volatile Organic Compounds at a Site of Subsurface Gasoline Contamination

    E-Print Network [OSTI]

    Fischer, M.L.

    2011-01-01

    OF SUBSURFACE GASOLINE CONTAMINATION Marc L. Fischer, AbraOF SUBSURFACE GASOLINE CONTAMINATION Marc L. Fischer, Abrareporting indoor air contamination (6,7). Estimation of

  7. Source characteristics of volatile organic compounds during high ozone episodes in Hong Kong, Southern China

    E-Print Network [OSTI]

    Zhang, J.; Wang, T.; Chameides, W. L; Cardelino, C.; Blake, D. R; Streets, D. G

    2008-01-01

    2-butene trans-2-butene 1,3-butadiene Y Y Y Y Y Y Y Y Y Y Y1-butene 1-pentene 1,3-butadiene Isoprene Cis-2-butene

  8. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    E-Print Network [OSTI]

    2010-01-01

    Butene cis-2-Butene 1,3-Butadiene 1-Pentene trans-2-Pentenei-Pentane n-Pentane 1,3-Butadiene 1-Pentene Isoprene trans-i-Pentane n-Pentane 1,3-Butadiene 1-Pentene Isoprene trans-

  9. Development of the colorimetric sensor array for detection of explosives and volatile organic compounds in air

    E-Print Network [OSTI]

    of Denmark, Ørsteds Plads 345 East, DK-2800, Kgs. Lyngby, Denmark b Department of Informatics and Mathematical Modelling, Technical University of Denmark, Richard Petersens Plads 321, 2800 Kgs. Lyngby, Denmark c Department of Physics and Chemistry, University of Southern Denmark, Campusvej 55, DK-5230, Odense

  10. Air stripping of volatile organic chlorocarbons: System development, performance, and lessons learned

    SciTech Connect (OSTI)

    McKillip, S.T.; Sibley, K.L.; Horvath, J.G.

    1991-12-31

    The Savannah River Site, which has been in operation since the 1950`s, is a 780-square kilometer reservation that produces tritium for the national defense program. As a result of past waste handling practices, the ground water at several locations on the Site has become contaminated with solvents, metals, and radionuclides. In 1981, the ground water located under the Site`s fuel and target rod fabrication area (M-Area) was found to be contaminated with degreasing solvents, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE). In 1983, a program was started to evaluate air stripping and determine its applicability to cleanup of M-Area contamination. Lessons learned regarding the efficiency and effectiveness of air stripping technology are presented.

  11. Air stripping of volatile organic chlorocarbons: System development, performance, and lessons learned

    SciTech Connect (OSTI)

    McKillip, S.T.; Sibley, K.L.; Horvath, J.G.

    1991-01-01

    The Savannah River Site, which has been in operation since the 1950's, is a 780-square kilometer reservation that produces tritium for the national defense program. As a result of past waste handling practices, the ground water at several locations on the Site has become contaminated with solvents, metals, and radionuclides. In 1981, the ground water located under the Site's fuel and target rod fabrication area (M-Area) was found to be contaminated with degreasing solvents, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE). In 1983, a program was started to evaluate air stripping and determine its applicability to cleanup of M-Area contamination. Lessons learned regarding the efficiency and effectiveness of air stripping technology are presented.

  12. Source characteristics of volatile organic compounds during high ozone episodes in Hong Kong, Southern China

    E-Print Network [OSTI]

    Zhang, J.; Wang, T.; Chameides, W. L; Cardelino, C.; Blake, D. R; Streets, D. G

    2008-01-01

    TO EPD sites Methane Ethane Propane n-butane i-butane n-to Source Category Species Ethane Propane n-butane i-butane9. Ratios of n-butane-to-ethane vs. propane-to-ethane from

  13. Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity

    E-Print Network [OSTI]

    Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

    2009-01-01

    A. M. , Onasch, T. B. , Peltier, R. E. , Quinn, P. K. ,J. , Sullivan, A. P. , Peltier, R. E. , Russell, A. , Yan,

  14. In-situ remediation system for volatile organic compounds with deep recharge mechanism

    DOE Patents [OSTI]

    Jackson, Jr., Dennis G. (Augusta, GA); Looney, Brian B. (Aiken, SC); Nichols, Ralph L. (Augusta, SC); Phifer, Mark A. (Augusta, SC)

    2001-01-01

    A method and apparatus for the treatment and remediation of a contaminated aquifer in the presence of an uncontaminated aquifer at a different hydraulic potential. The apparatus consists of a wellbore inserted through a first aquifer and into a second aquifer, an inner cylinder within the wellbore is supported and sealed to the wellbore to prevent communication between the two aquifers. Air injection is used to sparge the liquid having the higher static water level and, to airlift it to a height whereby it spills into the inner cylinder. The second treatment area provides treatment in the form of aeration or treatment with a material. Vapor stripped in sparging is vented to the atmosphere. Treated water is returned to the aquifer having the lower hydraulic potential.

  15. ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS – FINAL REPORT

    E-Print Network [OSTI]

    Maddalena, Randy L.

    2008-01-01

    lost their homes in Louisiana and Mississippi during the Hurricanelost their homes in Louisiana and Mississippi during the Hurricane

  16. SUPPLEMENTARY MATERIAL OF THE ARTICLE: Volatile Organic Compounds in the Western Mediterranean Basin

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    and no correlation with solar radiation. On the contrary, monoterpenes and aromatics had no correlation acid Acetone Ethanol Metha- nol Isoprene MVK/ MACR Mono- terpenes Benzene Toluene C8- aromatics Aceto.60 0.74 0.77 ns 0.30 0.32, -0.33 Ethanol 0.94 0.91 0.85 - - - - - - - - - - - - - - - Methanol 0.80 0

  17. INSTRUMENTATION AND METHODS FOR THE EXAMINATION OF VOLATILE ORGANIC HALOCARBONS IN AQUEOUS ENVIRONMENTAL SAMPLES

    E-Print Network [OSTI]

    liquid media into a commercial preconcentration system connected to a gas chromatograph. The gas. Methods were developed for the detection of these analytes in ice core samples as well as natural liquid uncovered problems in sample handling and storage that confounded the analytical results. The natural liquid

  18. IMPACT OF BIOGENIC VOLATILE ORGANIC COMPOUND EMISSIONS ON EUROPEAN SURFACE OZONE

    E-Print Network [OSTI]

    Curci, Gabriele

    (IMK-IFU), Forschungszentrum, Karlsruhe (4) Institut für Energiewirtschaft und Rationelle (IMK-IFU), Forschungszentrum, Karlsruhe (4) Institut für Energiewirtschaft und Rationelle

  19. ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS – FINAL REPORT

    E-Print Network [OSTI]

    Maddalena, Randy L.

    2008-01-01

    Indoor Air, 14, 135-144. HUD. 2006. Manufactured Homeand Urban Development (HUD) formaldehyde emission standardCARB CDC CPSC CV FEMA GM GSD HUD HWPW LBNL NCEH NIOSH NIST

  20. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    E-Print Network [OSTI]

    2010-01-01

    C-130 T0 T1 G1 Ethane Propane i-Butane n-Butane i-Pentane n-ppbv) Ethane Ethene Ethyne Propane Propene i-Butane n-Butanee.g. , ethane, ethene, propane, propane, methanol, ethanol,

  1. Atmospheric volatile organic compound measurements during the Pittsburgh Air Quality Study: Results, interpretation, and

    E-Print Network [OSTI]

    Goldstein, Allen

    source types in the region for both seasons. Local automotive emissions were the strongest contributor included in the factor analysis. We conclude that longer-range transport and industrial emissions were more

  2. Biogenic volatile organic compound emissions from a lowland tropical wet forest in Costa Rica

    E-Print Network [OSTI]

    Geron, C; Guenther, A; Greenberg, J; Loescher, HW; Clark, D; Baker, B

    2002-01-01

    Geophysical Research 103 (D1), Kuck, L.R. , Smith Jr. , T. ,basin (Grace et al. , 1995; Kuck et al. , 2000) but is ca. a

  3. Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units

    E-Print Network [OSTI]

    Parthasarathy, Srinandini

    2011-01-01

    Terpenes Benzene p-Xylene Styrene Toluene TMPD-DIB TMPD-MIBpentadecane Hexadecane Styrene Benzene Toluene m/p-xylene o-pentadecane hexadecane styrene benzene toluene m/p-xylene o-

  4. ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS – FINAL REPORT

    E-Print Network [OSTI]

    Maddalena, Randy L.

    2008-01-01

    of four chemicals (styrene, tetradecane, pentadecane and theTwo of the compounds (styrene and acetaldehyde) had similarToluene Ethylbenzene p-Xylene Styrene Propyl-benzene 1,3,5-

  5. Common Indoor Sources of volatile organic compounds: emission rates and techniques for reducing consumer exposures

    E-Print Network [OSTI]

    Hodgson, A.T.

    2011-01-01

    x // ///////////;/7:/1 Styrene Expt. A-2 IZZZl Expt. A-Aromatic Hydrocarbons Toluene Styrene 1,2,4-Trimethylbenzenecompounds included styrene, 4-PCH, 4-ethenylcycohexene, n-

  6. Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units

    E-Print Network [OSTI]

    Parthasarathy, Srinandini

    2011-01-01

    Figure 4b - Comparison of mean formaldehyde and acetic acidJ.A. Carcinogenicity of formaldehyde in rats and mice afterrat induced by gaseous formaldehyde and hydrogen chloride.

  7. A Tree's Response to Herbivory: Quantification of Biogenic Volatile Organic Compound Emissions

    E-Print Network [OSTI]

    Collins, Gary S.

    Giuliana Viglione, Celia Faiola, Tim VanReken Laboratory for Atmospheric Research, Washington State-MS-FID). The data collected were used to calculate the mixing ratios of different BVOCs in the chamber in the same way. Experimental Setup Calculations · Moles of air were calculated using the ideal gas law

  8. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    E-Print Network [OSTI]

    2010-01-01

    results in bar graphs and pie charts. The bar graphs show03:00 p.m. Shown in the first pie chart to the right of eachof each bar graph is a pie chart showing the breakdown of

  9. Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity

    E-Print Network [OSTI]

    Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

    2009-01-01

    P. R. , and Hao, W. M. : Emissions from forest fires nearM. O. and Merlet, P. : Emission of trace gases and aerosolsW. : Automo- bile Emissions of Acetonitrile: Assessment of

  10. Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform 

    E-Print Network [OSTI]

    Park, Chang Hyoun

    2011-08-08

    tall platform must be found that does not influence the wind itself while allowing a measurement setup. The system should be located at minimally twice the urban canopy height and ideally higher to avoid the urban roughness layer (Roth, 2000... of an urban area, we used the median isoprene flux to compare with the isoprene model 8 result. As in other studies, we used the normalization condition of 30?C of leaf temperature and 1000 ?mol m-2 s-1 of PAR to determine basal emission rate (on...

  11. Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units

    E-Print Network [OSTI]

    Parthasarathy, Srinandini

    2011-01-01

    River 3 Gulfstream Cavalier 1 Gulfstream Cavalier 2 Keystone1 Keystone2 Keystone 3 Pilgrim 1 Pilgrim 2 Manufacturer Fleetwood

  12. Methyl halide and biogenic volatile organic compound fluxes from perennial bioenergy crops and annual arable crops 

    E-Print Network [OSTI]

    Morrison, Eilidh Christina

    2013-11-28

    The depletion of fossil fuel resources, pollution concerns and the challenge of energy security are driving the search for renewable energy sources. The use of lignocellulosic plant biomass as an energy source is increasing ...

  13. Improved land cover and emission factors for modeling biogenic volatile organic compounds emissions from Hong Kong

    E-Print Network [OSTI]

    Leung, DYC; Wong, P; Cheung, BKH; Guenther, A

    2010-01-01

    c Yearly Variation of Solar Radiation Data Solar Radiation (data Hourly averages of air temperature and solar radiationof temperature data. c. Annual variation of solar radiation

  14. 2010-05 "Interim Measure for Volatile Organic Constituent Contaminant

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s s i s t a nsecond report released

  15. Wastewater treatment -- New regs add emissions control to managers' duties

    SciTech Connect (OSTI)

    Gorman, P.M. (Environmental Process Technologies Inc., Munster, IN (United States)); Forrest, C.J. (Equinox Environmental Consultants Ltd., Wheaton, IL (United States))

    1994-06-01

    Wastewater treatment facilities traditionally were regulated primarily from the standpoint of effluent criteria and solid waste disposal requirements. However, since passage of the Clean Air Act (CAA) Amendments, wastewater treatment facility operators must be concerned with air emissions, especially of volatile organic compounds (VOCs), generated by their processes. Three basic approaches are used to manage VOC emissions from wastewater treatment systems--pollution prevention activities, wastewater treatment control methods and emissions control methods. These approaches may be used in combination to minimize VOCs in industrial and municipal wastewater streams.

  16. In situ bioremediation using horizontal wells

    SciTech Connect (OSTI)

    NONE

    1995-04-01

    In Situ Bioremediation (ISB), which is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation, remediates soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISB involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove .VOCs from the vadose zone concomitant with biodegradation of VOCs. The innovation is in the combination of 3 emerging technologies, air stripping, horizontal wells, and bioremediation via gaseous nutrient injection with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

  17. Cyclic membrane separation process

    DOE Patents [OSTI]

    Nemser, Stuart M.

    2005-05-03

    A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In the first part of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the second part, the membrane is inoperative while gas pressure rises in the ullage. In one aspect of this invention, a vacuum is drawn in the membrane separation unit thus reducing overall VOC emissions.

  18. Characterization of Persistent Volatile Contaminant Sources in the Vadose Zone

    SciTech Connect (OSTI)

    Carroll, Kenneth C.; Truex, Michael J.; Brusseau, Mark L.; Parker, Kyle R.; Mackley, Rob D.; Rohay, Virginia J.

    2013-05-01

    Remediation activities over time will alter the subsurface distribution of contaminants and likely create significant changes in the source-zone architecture. A field method was demonstrated for use of data collected from multiple individual soil vapor extraction (SVE) system well tests to locate and characterize the distribution of persistent VOC sources in the vadose zone. Operational data collected at the Department of Energy’s Hanford site were used to examine source zone alteration over time due to SVE operation and to illustrate the source-zone characterization approach. Individual well test results confirmed a heterogeneous distribution of permeability and contaminant mass discharge throughout the vadose zone. The trends in mass discharge and concentration were analyzed to determine the location and extent of the primary source zone within a lower-permeability unit at the site. This information is useful to evaluate the performance of SVE operations, and support decisions concerning system alteration or closure based on risk assessments of the impact of vadose-zone sources on groundwater contamination or vapor intrusion.

  19. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, Michael P. (Albuquerque, NM); Overmyer, Donald L. (Albuquerque, NM); Dominguez, Frank (Albuquerque, NM)

    1998-01-01

    A system for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source.

  20. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, M.P.; Overmyer, D.L.; Dominguez, F.

    1998-12-22

    A system is disclosed for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source. 3 figs.

  1. Process Development for High Voc CdTe Solar Cells: Phase I, Annual Technical Report, October 2005 - September 2006

    SciTech Connect (OSTI)

    Ferekides, C. S.; Morel, D. L.

    2007-04-01

    The focus of this project is the open-circuit voltage of the CdTe thin-film solar cell. CdTe continues to be one of the leading materials for large-scale cost-effective production of photovoltaics, but the efficiency of the CdTe solar cell has been stagnant for the last few years. At the manufacturing front, the CdTe technology is fast paced and moving forward with U.S.-based First Solar LLC leading the world in CdTe module production. To support the industry efforts and continue the advancement of this technology, it will be necessary to continue improvements in solar cell efficiency. A closer look at the state-of-the-art performance levels puts the three solar cell efficiency parameters of short-circuit current density (JSC), open-circuit voltage (VOC), and fill factor (FF) in the 24-26 mA/cm2, 844?850 mV, and 74%-76% ranges respectively. During the late 1090s, efforts to improve cell efficiency were primarily concerned with increasing JSC, simply by using thinner CdS window layers to enhance the blue response (<510 nm) of the CdTe cell. These efforts led to underscoring the important role 'buffers' (or high-resistivity transparent films) play in CdTe cells. The use of transparent bi-layers (low-p/high-p) as the front contact is becoming a 'standard' feature of the CdTe cell.

  2. An Innovative Reactor Technology to Improve Indoor Air Quality

    SciTech Connect (OSTI)

    Rempel, Jane [TIAX LLC., Lexington, MA (United States)

    2013-03-30

    As residential buildings achieve tighter envelopes in order to minimize energy used for space heating and cooling, accumulation of indoor air pollutants such as volatile organic compounds (VOCs), becomes a major concern causing poor air quality and increased health risks. Current VOC removal methods include sorbents, ultraviolet photocatalytic oxidation (UVPCO), and increased ventilation, but these methods do not capture or destroy all VOCs or are prohibitively expensive to implement. TIAX's objective in this program was to develop a new VOC removal technology for residential buildings. This novel air purification technology is based on an innovative reactor and light source design along with UVPCO properties of the chosen catalyst to purify indoor air and enhance indoor air quality (IAQ). During the program we designed, fabricated and tested a prototype air purifier to demonstrate its feasibility and effectiveness. We also measured kinetics of VOC destruction on photocatalysts, providing deep insight into reactor design.

  3. Evaluation of a robust, diimide-based, porous organic polymer (POP) as a high-capacity sorbent for representative chemical

    E-Print Network [OSTI]

    Evaluation of a robust, diimide-based, porous organic polymer (POP) as a high-capacity sorbent A previously described porous organic polymer (NU-POP-1) was evaluated against four representative chemical an activated, impregnated carbon. The ability to remove the highly volatile toxic chemicals ammonia

  4. Fermilab | About | Organization | Fermilab Organization | Explanation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Symbols Line Organization: sectors, divisions, sections Line Organization Matrix Organization: centers, projects and programs utilizing resources spanning the entire...

  5. Volatile Loss and Classification of Kuiper Belt Objects

    E-Print Network [OSTI]

    Johnson, R E; Young, L A; Volkov, A N; Schmidt, C

    2015-01-01

    Observations indicate that some of the largest Kuiper Belt Objects (KBOs) have retained volatiles in the gas phase, which implies the presence of an atmosphere that can affect their reflectance spectra and thermal balance. Volatile escape rates driven by solar heating of the surface were estimated by Schaller and Brown (2007) (SB) and Levi and Podolak (2009)(LP) using Jeans escape from the surface and a hydrodynamic model respectively. Based on recent molecular kinetic simulations these rates can be hugely in error (e.g., a factor of $\\sim 10^{16}$ for the SB estimate for Pluto). In this paper we estimate the loss of primordial N$_2$ for several large KBOs guided by recent molecular kinetic simulations of escape due to solar heating of the surface and due to UV/EUV heating of the upper atmosphere. For the latter we extrapolate simulations of escape from Pluto (Erwin et al. 2013) using the energy limited escape model recently validated for the KBOs of interest by molecular kinetic simulations (Johnson et al. 2...

  6. Volatile snowlines in embedded disks around low-mass protostars

    E-Print Network [OSTI]

    Harsono, Daniel; van Dishoeck, Ewine

    2015-01-01

    (Abridged*) Models of the young solar nebula assume a hot initial disk with most volatiles are in the gas phase. The question remains whether an actively accreting disk is warm enough to have gas-phase water up to 50 AU radius. No detailed studies have yet been performed on the extent of snowlines in an embedded accreting disk (Stage 0). Quantify the location of gas-phase volatiles in embedded actively accreting disk system. Two-dimensional physical and radiative transfer models have been used to calculate the temperature structure of embedded protostellar systems. Gas and ice abundances of H$_2$O, CO$_2$, and CO are calculated using the density-dependent thermal desorption formulation. The midplane water snowline increases from 3 to 55 AU for accretion rates through the disk onto the star between $10^{-9}$-$10^{-4} \\ M_{\\odot} \\ {\\rm yr^{-1}}$. CO$_2$ can remain in the solid phase within the disk for $\\dot{M} \\leq 10^{-5} \\ M_{\\odot} \\ {\\rm yr^{-1}}$ down to $\\sim 20$ AU. Most of the CO is in the gas phase w...

  7. Final Technical Report: A Paradigm Shift in Chemical Processing: New Sustainable Chemistries for Low-VOC Coatings

    SciTech Connect (OSTI)

    Smith, Kenneth F.

    2006-07-26

    The project employed new processes to make emulsion polymers from reduced levels of petroleum-derived chemical feedstocks. Most waterborne paints contain spherical, emulsion polymer particles that serve as the film-forming binder phase. Our goal was to make emulsion polymer particles containing 30 percent feedstock that would function as effectively as commercial emulsions made from higher level feedstock. The processes developed yielded particles maintained their film formation capability and binding capacity while preserving the structural integrity of the particles after film formation. Rohm and Haas Company (ROH) and Archer Daniels Midland Company (ADM) worked together to employ novel polymer binders (ROH) and new, non-volatile, biomass-derived coalescing agents (ADM). The University of Minnesota Department of Chemical Engineering and Material Science utilized its unique microscopy capabilities to characterize films made from the New Emulsion Polymers (NEP).

  8. Risk Management Based on Stochastic Volatility Ernst Eberlein, Jan Kallsen, Jrn Kristen

    E-Print Network [OSTI]

    Kallsen, Jan

    Risk Management Based on Stochastic Volatility Ernst Eberlein, Jan Kallsen, Jörn Kristen University of Freiburg Abstract Risk management approaches that do not incorporate randomly changing volatility tend (1995) can be applied quite easily for risk management purposes. Moreover, we compare their relative

  9. LETTER Volatile communication between plants that affects herbivory: a meta-analysis

    E-Print Network [OSTI]

    Ishida, Yuko

    LETTER Volatile communication between plants that affects herbivory: a meta-analysis Richard Karban,1 * Louie H. Yang,1 and Kyle F. Edwards2 Abstract Volatile communication between plants causing of habitat and plant growth form were undetectable. In most cases, the mechanisms of resistance

  10. House Flies andPigManureVolatiles: Wind TunnelBehavioral Studiesand

    E-Print Network [OSTI]

    House Flies andPigManureVolatiles: Wind TunnelBehavioral Studiesand Electrophysiological pig manure were identified as electrophysiologically active on virgin female house fly (Muscadomstica of standards, and wind tunnel behavioral studies The pig manure volatiles eliciting responses from female

  11. RECONSTRUCTING THE UNKNOWN LOCAL VOLATILITY FUNCTION THOMAS F. COLEMAN, YUYING LI, AND ARUN VERMA

    E-Print Network [OSTI]

    Li, Yuying

    Abstract. Using market European option prices, a method for computing a smooth local volatility function, and pricing exotic options. A spline functional approach is used: the local volatility function is represented. Accuracy of pricing and hedging is also illustrated. Moreover, it is demonstrated that, using different

  12. Determining the Volatility of Ultrafine (UF) PM Emissions from CNG Vehicles

    E-Print Network [OSTI]

    Determining the Volatility of Ultrafine (UF) PM Emissions from CNG Vehicles Contract#: 500. Limited research has been done to characterize compressed natural gas (CNG) mass emissions and practically no work focused on the determination of the size- segregated volatility of UF particles from CNG engines

  13. Scaling and memory of intraday volatility return intervals in stock markets Fengzhong Wang,1

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Scaling and memory of intraday volatility return intervals in stock markets Fengzhong Wang,1 Kazuko interval between price volatilities that are above a certain threshold q for 31 intraday data sets Yamasaki,1,2 Shlomo Havlin,1,3 and H. Eugene Stanley1 1 Center for Polymer Studies and Department

  14. A comparison of option prices under different pricing measures in a stochastic volatility model

    E-Print Network [OSTI]

    A comparison of option prices under different pricing measures in a stochastic volatility model option prices in an incomplete stochastic volatility model with correlation. In a general setting, we prove an ordering result which says that prices for European options with convex payoffs are decreasing

  15. Using futures prices to filter short-term volatility and recover a latent, long-term price series for oil

    E-Print Network [OSTI]

    Herce, Miguel Angel

    2006-01-01

    Oil prices are very volatile. But much of this volatility seems to reflect short-term,transitory factors that may have little or no influence on the price in the long run. Many major investment decisions should be guided ...

  16. Analysis of volatile contaminants in US Navy fleet soda lime. Technical report, August 1992-May 1995

    SciTech Connect (OSTI)

    Lillo, R.S.; Ruby, R.; Gummin, D.D.; Porter, W.R.; Caldwell, J.M.

    1995-06-01

    Contamination was suspected of U.S. Navy Fleet soda lime (High Performance Sodasorb(R)) when an ammonia-like odor was reported during its use in August 1992. This material contained indicator dye and was used for carbon dioxide absorption during diving. This incident had a major impact on the U.S Navy diving program when the Navy temporarily banned use of Sodasorb(R) and authorized Sofnolime(R) as an interim replacement. The Naval Medical Research Institute was immediately assigned to investigate. Testing involved sampling from the headspace (gas space) inside closed buckets and from an apparatus simulating conditions during operational diving. Volatile organic compounds were analyzed by gas chromatography and mass spectrometry; ammonia and amines were measured by infrared spectroscopy. Significant amounts of ammonia (up to 30 ppm), ethyl and diethyl amines (up to several ppm), and various aliphatic hydrocarbons (up to 60 ppm) were detected during testing of both Sodasorb(R) and Sofnolime(R). Contaminants were slowly removed by gas flow and did not return. The source(s) of the ammonia and amines are unknown, although they may result from the breakdown of the indicator dye. Hydrocarbon contamination appeared to result from the materials of which the bucket is constructed. Based on these findings, the U.S. Navy is expected to phase in non-indicating soda lime that will be required to meet defined contaminant limits.

  17. Summary Report on the Volatile Radionuclide and Immobilization Research for FY2011 at PNNL

    SciTech Connect (OSTI)

    Strachan, Denis M.; Chun, Jaehun; Matyas, Josef; Lepry, William C.; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

    2011-09-01

    The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2011, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogen-based aerogels (i.e., chalcogels). A silica aerogel was tested at ORNL for total I2 sorption capacity. It was determined to have 48 mass% capacity while having little physisorbed I2 (I2 not taken up in the aerogel pores). For 85Kr, metal organic framework (MOF) structures were investigated and a new MOF with about 8 mass% capacity for Xe and Kr. The selectivity can be changed from Xe > Kr to Xe < Kr simply by lowering the temperature below 0 C. A patent disclosure has been filed. Lastly, silicon carbide (SiC) was loaded with Kr. The diffusion of Kr in SiC was found to be less than detectable at 500 C.

  18. Standard test method for total mass loss and collected volatile condensable materials from outgassing in a vacuum environment

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2007-01-01

    Standard test method for total mass loss and collected volatile condensable materials from outgassing in a vacuum environment

  19. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams for Large-scaleOrganizationAboutOrganizingOrganizing

  20. In-Situ Contained And Of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell (Idaho Falls, ID)

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  1. Volatility return intervals analysis of the Japanese market

    E-Print Network [OSTI]

    Jung, Woo-Sung; Havlin, Shlomo; Kaizoji, Taisei; Moon, Hie-Tae; Stanley, H Eugene

    2007-01-01

    We investigate scaling and memory effects in return intervals between price volatilities above a certain threshold $q$ for the Japanese stock market using daily and intraday data sets. We find that the distribution of return intervals can be approximated by a scaling function that depends only on the ratio between the return interval $\\tau$ and its mean $$. We also find memory effects such that a large (or small) return interval follows a large (or small) interval by investigating the conditional distribution and mean return interval. The results are similar to previous studies of other markets and indicate that similar statistical features appear in different financial markets. We also compare our results between the period before and after the big crash at the end of 1989. We find that scaling and memory effects of the return intervals show similar features although the statistical properties of the returns are different.

  2. In-Situ Containment and Extraction of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  3. A Big Data Approach to Analyzing Market Volatility

    SciTech Connect (OSTI)

    Wu, Kesheng; Bethel, E. Wes; Gu, Ming; Leinweber, David; Ruebel, Oliver

    2013-06-05

    Understanding the microstructure of the financial market requires the processing of a vast amount of data related to individual trades, and sometimes even multiple levels of quotes. Analyzing such a large volume of data requires tremendous computing power that is not easily available to financial academics and regulators. Fortunately, public funded High Performance Computing (HPC) power is widely available at the National Laboratories in the US. In this paper we demonstrate that the HPC resource and the techniques for data-intensive sciences can be used to greatly accelerate the computation of an early warning indicator called Volume-synchronized Probability of Informed trading (VPIN). The test data used in this study contains five and a half year?s worth of trading data for about 100 most liquid futures contracts, includes about 3 billion trades, and takes 140GB as text files. By using (1) a more efficient file format for storing the trading records, (2) more effective data structures and algorithms, and (3) parallelizing the computations, we are able to explore 16,000 different ways of computing VPIN in less than 20 hours on a 32-core IBM DataPlex machine. Our test demonstrates that a modest computer is sufficient to monitor a vast number of trading activities in real-time ? an ability that could be valuable to regulators. Our test results also confirm that VPIN is a strong predictor of liquidity-induced volatility. With appropriate parameter choices, the false positive rates are about 7percent averaged over all the futures contracts in the test data set. More specifically, when VPIN values rise above a threshold (CDF > 0.99), the volatility in the subsequent time windows is higher than the average in 93percent of the cases.

  4. Reduce air, reduce compliance cost new patented spray booth technology

    SciTech Connect (OSTI)

    McGinnis, F.

    1997-12-31

    A New Paint Spray Booth System that dramatically reduces air volumes normally required for capturing and controlling paint overspray that contains either Volatile Organic Compounds (VOC) or Hazardous Air Pollutants (HAP), or both. In turn, a substantial reduction in capital equipment expenditures for air abatement systems and air make-up heaters as well as related annual operating expenses is realized.

  5. Catalytic Reduction of Nitrogen Oxides by Methane over Pd(110) S. M. Vesecky, J. Paul, and D. W. Goodman*

    E-Print Network [OSTI]

    Goodman, Wayne

    the reduction of NOx species and the oxidation of CO and volatile organic compounds (VOC's) produced in mobile involves the selective catalytic reduction (SCR) or NOx with NH3 4 Although this process is efficient concern. If too much methane is oxidized to CO2, the efficiency of the NOx reduction process will suffer

  6. Atmos. Chem. Phys., 13, 56555669, 2013 www.atmos-chem-phys.net/13/5655/2013/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    (version 3 of Weather Research and Forecasting Chemical model ­ WRF-Chemv3) is applied for this study not only in the urban area, but also on a regional scale of the surrounding area of Shanghai. The results (volatile organic compound)-limited condition in the urban area of Shanghai. Moreover, the VOC

  7. Atmos. Chem. Phys., 14, 13851396, 2014 www.atmos-chem-phys.net/14/1385/2014/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    into several regimes asso- ciated with the dominant emission types and relative levels of NOx and volatile organic compounds (VOC). Ozone pro- duction in industrial regions (the main NOx emission source areas) increases in warmer conditions and slightly decreases following an increase in NOx emissions due to NOx

  8. Bayesian Monte Carlo analysis applied to regional-scale inverse emission modeling for reactive trace gases

    E-Print Network [OSTI]

    Menut, Laurent

    the a priori uncertainties in anthropogenic NOx and volatile organic compounds (VOC) emissions: (1) The a posteriori probability density function (pdf) for NOx emissions is not modified in its averageBayesian Monte Carlo analysis applied to regional-scale inverse emission modeling for reactive

  9. Atmos. Chem. Phys., 10, 11711181, 2010 www.atmos-chem-phys.net/10/1171/2010/

    E-Print Network [OSTI]

    Dabdub, Donald

    with respect to changes in NOx emissions for both years. In particular, de- creasing NOx emissions in 2005 when@uci.edu) NOx emissions reductions alone, which has implications for the assessment of future emission control and particulate matter concentrations, varying baseline nitrogen oxides (NOx) and volatile organic compounds (VOC

  10. CX-011446: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Measurements and Modeling to Quantify Emissions of Methane and Volatile Organic Compounds (VOCs) from Shale Gas Operations CX(s) Applied: B3.1 Date: 11/13/2013 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory

  11. Atmos. Chem. Phys., 14, 1097710988, 2014 www.atmos-chem-phys.net/14/10977/2014/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    -10977-2014 © Author(s) 2014. CC Attribution 3.0 License. Volatile organic compound emissions from the oil and natural gas industry in the Uintah Basin, Utah: oil and gas well pad emissions compared to ambient air (VOCs) associated with oil and natural gas production in the Uintah Basin, Utah were measured

  12. Modeling the Oxidative Capacity of the Atmosphere of the South Coast

    E-Print Network [OSTI]

    Dabdub, Donald

    of the complex chemistry involving volatile organic compounds (VOCs) and oxides of nitrogen (NOx ) nitrogen oxide (NO) + nitrogen dioxide (NO2))(1).O3 productionisinitiatedbyreactionsthatgenerate HOx radicals Air Basin of California (SoCAB). P(O3) indicates the rapid nature of O3 formation under peak

  13. Atmos. Chem. Phys., 7, 12931303, 2007 www.atmos-chem-phys.net/7/1293/2007/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ) is the smallest -dicarbonyl and is an oxidation product of numerous volatile organic compounds (VOCs) (Calvert et source apportion- ment of formaldehyde (HCHO) in urban air (Garc´ia et al., 2005). The atmospheric to measure CHOCHO for the first time directly in the open atmosphere, as part of the Mexico City Metropolitan

  14. Organic Superconductors

    SciTech Connect (OSTI)

    Charles Mielke

    2009-02-27

    Intense magnetic fields are an essential tool for understanding layered superconductors. Fundamental electronic properties of organic superconductors are revealed in intense (60 tesla) magnetic fields. Properties such as the topology of the Fermi surface and the nature of the superconducting order parameter are revealed. With modest maximum critical temperatures~13K the charge transfer salt organic superconductors prove to be incredibly valuable materials as their electronically clean nature and layered (highly anisotropic) structures yield insights to the high temperature superconductors. Observation of de Haas-van Alphen and Shubnikov-de Haas quantum oscillatory phenomena, magnetic field induced superconductivity and re-entrant superconductivity are some of the physical phenomena observed in the charge transfer organic superconductors. In this talk, I will discuss the nature of organic superconductors and give an overview of the generation of intense magnetic fields; from the 60 tesla millisecond duration to the extreme 1000 tesla microsecond pulsed magnetic fields.

  15. Ethanol as Internal Standard for Quantitative Determination of Volatile Compounds in Spirit Drinks by Gas Chromatography

    E-Print Network [OSTI]

    Charapitsa, Siarhei V; Kulevich, Nikita V; Makoed, Nicolai M; Mazanik, Arkadzi L; Sytova, Svetlana N

    2012-01-01

    The new methodical approach of using ethanol as internal standard in gas chromatographic analysis of volatile compounds in spirit drinks in daily practice of testing laboratories is proposed. This method provides determination of volatile compounds concentrations in spirit drinks directly expressed in milligrams per liter (mg/L) of absolute alcohol according to official methods without measuring of alcohol strength of analyzed sample. The experimental demonstration of this method for determination of volatile compounds in spirit drinks by gas chromatography is described. Its validation was carried out by comparison with experimental results obtained by internal standard method and external standard method.

  16. Organization Chart

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams for Large-scaleOrganization Chart Organization Charts

  17. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams for Large-scaleOrganizationAbout EventsOrganizing

  18. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams for Large-scaleOrganizationAboutOrganizing Committee

  19. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams for Large-scaleOrganizationAboutOrganizing

  20. Understanding the Impact of Emerging Non-Volatile Memories on High-Performance,

    E-Print Network [OSTI]

    Gupta, Rajesh

    practical solution, but it is expensive and energy-intensive. Non-volatile, solid-state storage technologies to advanced phase-change memories attached to a DDR3 memory bus. We evaluate the impact of these technologies

  1. Exploring volatile fatty acids (VFAs) as a novel substrate for microbial oil production

    E-Print Network [OSTI]

    Chakraborty, Sagar, Ph. D. Massachusetts Institute of Technology

    2015-01-01

    Cost effective production of biofuels depends critically on feedstock cost and availability. As such, volatile fatty acids (VFAs) can play an important role in advancing sustainable biofuel production since they can be ...

  2. A statistical analysis of the natural gas futures market : the interplay of sentiment, volatility and prices

    E-Print Network [OSTI]

    Fazzio, Thomas J. (Thomas Joseph)

    2010-01-01

    This paper attempts to understand the price dynamics of the North American natural gas market through a statistical survey that includes an analysis of the variables influencing the price and volatility of this energy ...

  3. Comparative forecasting performance of symmetric and asymmetric conditional volatility models of an exchange rate. 

    E-Print Network [OSTI]

    Balaban, Ercan

    2002-01-01

    The relative out-of-sample forecasting quality of symmetric and asymmetric conditional volatility models of an exchange rate differs according to the symmetric and asymmetric evaluation criteria as well as a regression-based ...

  4. Natural formation and degradation of chloroacetic acids and volatile organochlorines in forest soil: challenges to understanding 

    E-Print Network [OSTI]

    Laturnus, Frank; Fahimi, Isabelle; Gryndler, Milan; Hartmann, Anton; Heal, Mathew R; Matucha, Miroslav; Schoeler, Heinfried; Schroll, Reiner; Svensson, Teresia

    2005-01-01

    Goal, Scope and Background. The anthropogenic environmental emissions of chloroacetic acids and volatile organochlorines have been under scrutiny in recent years because the two compound groups are suspected to contribute ...

  5. Volatile depletion in the TW Hydrae disk atmosphere

    E-Print Network [OSTI]

    Du, Fujun; Hogerheijde, Michiel R

    2015-01-01

    An abundance decrease in carbon- and oxygen-bearing species relative to dust has been frequently found in planet-forming disks, which can be attributed to an overall reduction of gas mass. However, in the case of TW Hya, the only disk with gas mass measured directly with HD rotational lines, the inferred gas mass ($\\lesssim$0.005 solar mass) is significantly below the directly measured value ($\\gtrsim$0.05 solar mass). We show that this apparent conflict can be resolved if the elemental abundances of carbon and oxygen are reduced in the upper layers of the outer disk but are normal elsewhere (except for a possible enhancement of their abundances in the inner disk). The implication is that in the outer disk, the main reservoir of the volatiles (CO, water, ...) resides close to the midplane, locked up inside solid bodies that are too heavy to be transported back to the atmosphere by turbulence. An enhancement in the carbon and oxygen abundances in the inner disk can be caused by inward migration of these solid ...

  6. Ammonia volatilization and nitrogen transformations in high pH soils used for beef manure disposal 

    E-Print Network [OSTI]

    Peters, Robert Edgar

    1972-01-01

    AMMONIA VOLATILIZATION AND NITROGEN TRANSFORMATIONS IN HIGH pH SOILS USED FOR BEEF MANURE DISPOSAL A Thesis by ROBERT EDGAR PETERS Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1972 Major Subject: Agricultural Engineering AMMONIA VOLATILIZATION AND NITROGEN TRANSFORMATIONS IN HIGH pH SOILS USED FOR BEEF MANURE DISPOSAL A Thesis by ROBERT EDGAR PETERS Approved as to style and content...

  7. Ammonia volatilization from surface application of ammonium sulfate to carbonate systems 

    E-Print Network [OSTI]

    Feagley, Sam Edward

    1976-01-01

    AMMONIA VOLATILIZATION FROM SURFACE APPLICATION OF AMMONIUM SULFATE TO CARBONATE SYSTEMS A Thesis by SAM EDWARD FEAGLEY Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1976 Major Subject; Soil Science AMMONIA VOLATILIZATION FROM SURFACE APPLICATIONS OF AMMONIUM SULFATE TO CARBONATE SYSTEMS A Thesis SAM EDWARD FEAGLEY Approved as to style and content by: Chairman of Committee Head of Dep...

  8. The performance of a volatile oil reservoir overlain by a gas cap 

    E-Print Network [OSTI]

    Ellis, Joseph Ralph, Jr

    1960-01-01

    THE PERFORMANCE OF A VOLATILE OIL RESERVOIR OVERLAIN BY A GAS CAP A Thesis By J. RALPH ELLIS, JR. Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August, 1960 Major Subject: PETROLEUM ENGINEERING THE PERFORMANCE OF A VOLATILE OIL RESERVOIR OVERLAIN BY A GAS CAP A Thesis By J. RALPH ELLIS, JR. Approved as to style and content by: hairxnan of Coxnxnittee) (Head...

  9. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, Joseph P. (Elkton, MD); Marek, James C. (Augusta, GA)

    1989-01-01

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper (II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the orginal organic compounds, is subsequently blended with high level radioactive sludge and transferred to a virtrification facility for processing into borosilicate glass for long-term storage.

  10. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, J.P.; Marek, J.C.

    1987-02-25

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper(II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the original organic compounds, is subsequently blended with high level radioactive sludge land transferred to a vitrification facility for processing into borosilicate glass for long-term storage. 2 figs., 3 tabs.

  11. Combustion of volatile matter during the initial stages of coal combustion

    SciTech Connect (OSTI)

    Marlow, D.; Niksa, S.; Kruger, C.H.

    1990-08-01

    Both the secondary pyrolysis and combustion of the volatiles from a bituminous coal will be studied. Devolatilization and secondary pyrolysis experiments will be conducted in a novel flow reactor in which secondary pyrolysis of the volatiles occurs after devolatilization is complete. This allows unambiguous measurements of the yields from both processes. Measurements will be made for reactor temperatures from 1500 to 1700 K, and a nominal residence time of 200 msec. These conditions are typical of coal combustion. Yields of tar, soot, H{sub 2}, CO, CH{sub 4}, and C{sub 2} and C{sub 3} hydrocarbons will be determined as a function of reactor temperature. The yields will be reported as a function of the temperature of the reactor. The instrumentation for temperature measurements will be developed during future studies. Combustion studies will be conducted in a constant volume bomb, which will be designed and constructed for this study. Tar and soot will be removed before introducing the volatiles to the bomb, so that only the combustion of the light gas volatiles will be considered. The burning velocities of light gas volatiles will be determined both as functions of mixture stoichiometry and the temperature at which the volatiles are pyrolysed. 90 refs., 70 figs., 13 tabs.

  12. Emission and chemistry of organic carbon in the gas and aerosol phase at a sub-urban site near Mexico City in March 2006 during the MILAGRO study

    E-Print Network [OSTI]

    2009-01-01

    C 11 -aromatics naphthalene benzene Oxygenates methanoland aromatics. In the af- oxygenated VOCs (formaldehyde, methanol,

  13. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams for Large-scaleOrganizationAbout Events

  14. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams for Large-scaleOrganizationAbout

  15. DIVISION S-10--WETLAND SOILS Turnover of Detrital Organic Carbon in a Nutrient-Impacted Everglades Marsh

    E-Print Network [OSTI]

    Florida, University of

    of organic C in plant and soil detrital pools along a P enrichment gradient in an Everglades marsh-30 cmdepth)], potential C mineralization decreased down gradient from the source of nutrient loading to WCA-2 metabolism via denitrification, as well as through NH3 volatilization (Reddy and D'Angelo, 1994). In contrast

  16. In situ bioremediation using horizontal wells. Innovative technology summary report

    SciTech Connect (OSTI)

    NONE

    1995-04-01

    In Situ Bioremediation (ISB) is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation. This process (ISB) involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove Volatile Organic Compounds (VOCs) from the vadose zone concomitant with biodegradation of the VOCs. This process is effective for remediation of soils and ground water contaminated with VOCs both above and below the water table. A full-scale demonstration of ISB was conducted as part of the Savannah River Integrated Demonstration: VOCs in Soils and Ground Water at Nonarid Sites. This demonstration was performed at the Savannah River Site from February 1992 to April 1993.

  17. Vapor Transport of a Volatile Solvent for a Multicomponent Aerosol Droplet

    E-Print Network [OSTI]

    Feng, James Q

    2015-01-01

    This work presents analytical formulas derived for evaluating vapor transport of a volatile solvent for an isolated multicomponent droplet in a quiescent environment, based on quasi-steady-state approximation. Among multiple solvent components, only one component is considered to be much more volatile than the rest such that other components are assumed to be nonvolatile remaining unchanged in the droplet during the process of (single-component) volatile solvent evaporation or condensation. For evaporating droplet, the droplet size often initially decreases following the familiar "d^2 law" at an accelerated rate. But toward the end, the rate of droplet size change diminishes due to the presence of nonvolatile cosolvent. Such an acceleration-deceleration reversal behavior is unique for evaporating multicomponent droplet, while the droplet of pure solvent has an accelerated rate of size change all the way through the end. This reversal behavior is also reflected in the droplet surface temperature evolution as "...

  18. Vapor Transport of a Volatile Solvent for a Multicomponent Aerosol Droplet

    E-Print Network [OSTI]

    James Q. Feng

    2015-07-19

    This work presents analytical formulas derived for evaluating vapor transport of a volatile solvent for an isolated multicomponent droplet in a quiescent environment, based on quasi-steady-state approximation. Among multiple solvent components, only one component is considered to be much more volatile than the rest such that other components are assumed to be nonvolatile remaining unchanged in the droplet during the process of (single-component) volatile solvent evaporation or condensation. For evaporating droplet, the droplet size often initially decreases following the familiar "d^2 law" at an accelerated rate. But toward the end, the rate of droplet size change diminishes due to the presence of nonvolatile cosolvent. Such an acceleration-deceleration reversal behavior is unique for evaporating multicomponent droplet, while the droplet of pure solvent has an accelerated rate of size change all the way through the end. This reversal behavior is also reflected in the droplet surface temperature evolution as "S-shaped" curves. However, a closer mathematical examination of conditions for acceleration-deceleration reversal indicates that the acceleration phase may disappear when the amount of nonvolatile cosolvent is relatively small and ambient vapor pressure is relatively high. Because the net effect of adding nonvolatile cosolvent is to reduce the mole fraction of the volatile solvent such that the saturation vapor pressure is lowered, vapor condensation onto the multicomponent droplet is predicted to occur when the ambient vapor pressure is subsaturated with respect to that for the pure volatile solvent. In this case, the droplet will grow asymptotically toward a finite size. But when the ambient vapor pressure becomes supersaturated with respect to that for the pure volatile solvent, the condensation growth of droplet can continue indefinitely without bound.

  19. Method for removing volatile components from a ceramic article, and related processes

    DOE Patents [OSTI]

    Klug, Frederic Joseph (Schenectady, NY); DeCarr, Sylvia Marie (Waterford, NY)

    2002-01-01

    A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

  20. Method For Removing Volatile Components From A Gel-Cast Ceramic Article

    DOE Patents [OSTI]

    Klug, Frederic Joseph (Schenectady, NY); DeCarr, Sylvia Marie (Schenectady, NY)

    2004-09-07

    A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

  1. The effect of chemical dispersants on the solution of volatile liquid hydrocarbons from spilled crude oil 

    E-Print Network [OSTI]

    McDonald, Thomas Joseph

    1982-01-01

    THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1982 Major Subject: Oceanography THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Approved as to style and content by...

  2. Final Report - Glass Formulation Testing to Increase Sulfate Volatilization from Melter, VSL-04R4970-1, Rev. 0, dated 2/24/05

    SciTech Connect (OSTI)

    Kruger, Albert A.; Matlack, K. A.; Pegg, I. L.; Gong, W.

    2013-11-13

    The principal objectives of the DM100 and DM10 tests were to determine the impact of four different organics and one inorganic feed additive on sulfate volatilization and to determine the sulfur partitioning between the glass and the off-gas system. The tests provided information on melter processing characteristics and off-gas data including sulfur incorporation and partitioning. A series of DM10 and DM100 melter tests were conducted using a LAW Envelope A feed. The testing was divided into three parts. The first part involved a series of DM10 melter tests with four different organic feed additives: sugar, polyethylene glycol (PEG), starch, and urea. The second part involved two confirmatory 50-hour melter tests on the DM100 using the best combination of reductants and conditions based on the DM10 results. The third part was performed on the DM100 with feeds containing vanadium oxide (V{sub 2}O{sub 5}) as an inorganic additive to increase sulfur partitioning to the off-gas. Although vanadium oxide is not a reductant, previous testing has shown that vanadium shows promise for partitioning sulfur to the melter exhaust, presumably through its known catalytic effect on the SO{sub 2}/SO{sub 3} reaction. Crucible-scale tests were conducted prior to the melter tests to confirm that the glasses and feeds would be processable in the melter and that the glasses would meet the waste form (ILAW) performance requirements. Thus, the major objectives of these tests were to: ? Perform screening tests on the DM10 followed by tests on the DM100-WV system using a LAW -Envelope A feed with four organic additives to assess their impact on sulfur volatilization. ? Perform tests on the DM100-WV system using a LAW -Envelope A feed containing vanadium oxide to assess its impact on sulfur volatilization. ? Determine feed processability and product quality with the above additives. ? Collect melter emissions data to determine the effect of additives on sulfur partitioning and melter emissions. ? Collect and analyze discharged glass to determine sulfur retention in the glass. ? Prepare and characterize feeds and glasses with the additives to confirm that the feeds and the glass melts are suitable for processing in the DM100 melter. ? Prepare and characterize glasses with the additives to confirm that the glasses meet the waste form (ILAW) performance requirements.

  3. LONG-TERM STABILITY TESTING RESULTS USING SURROGATES AND SORBENTS FOR SAVANNAH RIVER SITE ORGANIC AND AQUEOUS WASTESTREAMS - 10016

    SciTech Connect (OSTI)

    Burns, H.

    2009-11-10

    The U.S. Department of Energy (DOE) has tasked MSE Technology Applications, Inc. (MSE) with evaluating the long-term stability of various commercially available sorbent materials to solidify two organic surrogate wastestreams (both volatile and nonvolatile), a volatile organic surrogate with a residual aqueous phase, an aqueous surrogate, and an aqueous surrogate with a residual organic phase. The Savannah River Site (SRS) Legacy and F-Canyon plutonium/uranium extraction (PUREX) process waste surrogates constituted the volatile organic surrogates, and various oils constituted the nonvolatile organic surrogates. The aqueous surrogates included a rainwater surrogate and an aqueous organic surrogate. MSE also evaluated the PUREX surrogate with a residual aqueous component with and without aqueous type sorbent materials. Solidification of the various surrogate wastestreams listed above was performed from 2004 to 2006 at the MSE Test Facility located in Butte, Montana. This paper summarizes the comparison of the initial liquid release test (LRT) values with LRT results obtained during subsequent sampling events in an attempt to understand and define the long-term stability characteristics for the solidified wastestreams.

  4. Cold-Storage Potential of Four Yellow-Fleshed Peach Cultivars Defined by Their Volatile Compounds Emissions, Standard Quality

    E-Print Network [OSTI]

    Crisosto, Carlos H.

    Cold-Storage Potential of Four Yellow-Fleshed Peach Cultivars Defined by Their Volatile Compounds in firmness during both storage and commercialization periods. In contrast, the SSC, TA, and color remained constant during storage. Ten days of cold storage produced the highest total volatile emissions

  5. Induced Release of a Plant-Defense Volatile `Deceptively' Attracts Insect Vectors to Plants Infected with a Bacterial

    E-Print Network [OSTI]

    Burns, Jacqueline K.

    , and pathogen. Pathogen-induced plant responses can include changes in volatile and nonvolatile secondary metabolites as well as major plant nutrients. Experiments were conducted to understand how a plant pathogenicInduced Release of a Plant-Defense Volatile `Deceptively' Attracts Insect Vectors to Plants

  6. PII S0016-7037(01)00802-X Volatilization kinetics of silicon carbide in reducing gases: An experimental study with

    E-Print Network [OSTI]

    PII S0016-7037(01)00802-X Volatilization kinetics of silicon carbide in reducing gases August 21, 2001) Abstract--The volatilization kinetics of single crystal -SiC, polycrystalline -Si in terrestrial rocks (Bauer et al., 1963; Marshint- sev et al., 1982; Leung, 1990; Filippidis, 1993), although

  7. Motor vehicle fuel economy, the forgotten HC control stragegy. [Hydrocarbon (HC)

    SciTech Connect (OSTI)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  8. Motor vehicle fuel economy, the forgotten HC control stragegy?

    SciTech Connect (OSTI)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  9. Application of high-resolution time-of-flight chemical ionization mass spectrometry measurements to estimate volatility distributions of ?-pinene and naphthalene oxidation products

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chhabra, P. S.; Lambe, A. T.; Canagaratna, M. R.; Stark, H.; Jayne, J. T.; Onasch, T. B.; Davidovits, P.; Kimmel, J. R.; Worsnop, D. R.

    2015-01-05

    Recent developments in high-resolution time-of-flight chemical ionization mass spectrometry (HR-ToF-CIMS) have made it possible to directly detect atmospheric organic compounds in real time with high sensitivity and with little or no fragmentation, including low-volatility, highly oxygenated organic vapors that are precursors to secondary organic aerosol formation. Here, using ions identified by high-resolution spectra from an HR-ToF-CIMS with acetate reagent ion chemistry, we develop an algorithm to estimate the vapor pressures of measured organic acids. The algorithm uses identified ion formulas and calculated double bond equivalencies, information unavailable in quadrupole CIMS technology, as constraints for the number of possible oxygen-containing functionalmore »groups. The algorithm is tested with acetate chemical ionization mass spectrometry (acetate-CIMS) spectra of O3 and OH oxidation products of ?-pinene and naphthalene formed in a flow reactor with integrated OH exposures ranged from 1.2 × 1011 to 9.7 × 1011 molec s cm?3, corresponding to approximately 1.0 to 7.5 days of equivalent atmospheric oxidation. Measured gas-phase organic acids are similar to those previously observed in environmental chamber studies. For both precursors, we find that acetate-CIMS spectra capture both functionalization (oxygen addition) and fragmentation (carbon loss) as a function of OH exposure. The level of fragmentation is observed to increase with increased oxidation. The predicted condensed-phase secondary organic aerosol (SOA) average acid yields and O/C and H/C ratios agree within uncertainties with previous chamber and flow reactor measurements and ambient CIMS results. While acetate reagent ion chemistry is used to selectively measure organic acids, in principle this method can be applied to additional reagent ion chemistries depending on the application.« less

  10. Non-thermal Plasma - Nanometer TiO2 Photocatalysis for Formaldehyde Decomposition 

    E-Print Network [OSTI]

    Yuan, Q.; Feng, G.; Guang, X.

    2006-01-01

    for the carcinogenicity, the allergy source which is commonly recognized, and one of the latent sudden-change leading matters by the World Health Organization. Therefore, indoor pollutant purification is imperative. At present, the indoor pollutant purification... is more promising. Key words: Air cleaning Techonlogy; Non-thermal Plasma; TiO2 Photocatalysis 1. INTRODUCTION The volatile organic matter (VOCs) [ 1 ]is the main pollution source of indoor air, also the toxicity is extremely big, can lead...

  11. Fiber optic spectrochemical emission sensor: Detection of volatile chlorinated compounds in air and water using ultra-thin membranes

    SciTech Connect (OSTI)

    Anheier, N.C. Jr.; Olsen, K.B.; Osantowski, R.E.; Evans, J.C. Jr.; Griffin, J.W.

    1993-05-01

    Prior work on the fiber optic spectrochemical emission sensor called HaloSnif{trademark} has been extended to include an ultra-thin membrane which allows passage of volatile organic chlorinated compounds (VOCl). The membrane has been demonstrated to exclude H{sub 2}O during VOCl monitoring. The system is capable of measuring VOCl in gas-phase samples or aqueous solutions over a wide linear dynamic range. The lower limit of detection for trichloroethylene (TCE), perchloroethylene (PCE), carbon tetrachloride (CCl{sub 4}), and other related compounds in the gas-phase is 1 to 5 ppm{sub v/v}, and in the aqueous-phase is 5 to 10 mg/L. Waste site characterization and remediation activities often require chemical analysis in the vadose zone and in groundwater. These analyses are typically performed in analytical laboratories using widely accepted standardized methods such as gas chromatography, gas chromatography/mass spectrometry. The new developments with HaloSnif provide rapid field screening which can augment the standardized methods.

  12. Risk Management Based on Stochastic Volatility Ernst Eberlein, Jan Kallsen, Jrn Kristen

    E-Print Network [OSTI]

    Kallsen, Jan

    Risk Management Based on Stochastic Volatility Ernst Eberlein, Jan Kallsen, Jörn Kristen #3; University of Freiburg Abstract Risk management approaches that do not incorporate randomly changing and Keller (1995) can be applied quite easily for risk management purposes. Moreover, we compare

  13. Accurate dispensing of volatile reagents on demand for chemical reactions in EWOD chips{

    E-Print Network [OSTI]

    Accurate dispensing of volatile reagents on demand for chemical reactions in EWOD chips{ Huijiang the use of a filler liquid (e.g., oil). These properties pose challenges for delivering controlled volumes are introduced to the chip, independent of time delays between dispensing operations. On-demand dispensing

  14. On the volatile inventory of Titan from isotopic abundances in nitrogen and methane

    E-Print Network [OSTI]

    Lorenz, Ralph D.

    On the volatile inventory of Titan from isotopic abundances in nitrogen and methane Jonathan I enhancement. The enrichment in deuterated methane is now much better determined than it was when Pinto et al dissociation rates of normal and deuterated methane. We utilize the improved data and models to compute initial

  15. Agriculture and Trade Opportunities for Tanzania: Past Volatility and Future Climate Changerode_672 429..447

    E-Print Network [OSTI]

    Agriculture and Trade Opportunities for Tanzania: Past Volatility and Future Climate Changerode_672 global heterogeneity in climate-induced agricultural variability,Tanzania has the potential to substan owing to supply shocks in major exporting regions, Tanzania may be able to export more maize at higher

  16. Bacterial volatiles promote growth in Arabidopsis Choong-Min Ryu*, Mohamed A. Farag

    E-Print Network [OSTI]

    Paré, Paul W.

    Bacterial volatiles promote growth in Arabidopsis Choong-Min Ryu*, Mohamed A. Farag , Chia-Hui Hu of agricultural species for the purposes of growth enhance- ment, including increased seed emergence, plant weight when seeds were coated with PGPR before planting (1), and plant weight of tuber-treated potatoes

  17. An empirical behavioral model of liquidity and volatility Szabolcs Mike and J. Doyne Farmer

    E-Print Network [OSTI]

    develop a behavioral model for liquidity and volatility based on empirical reg- ularities in trading order interesting regularities in the way trading orders are placed and cancelled. The resulting simple model of absolute returns |r| are well described by a power law of the form P(|r| > R) R-r , with a value of r

  18. Detecting Turning Points of Trading Price and Return Volatility for Market Surveillance Agents

    E-Print Network [OSTI]

    Cao, Longbing

    Trading agent concept is very useful for trading strategy design and market mechanism design for trading strategy design and market mechanism design [2]. Besides that, we are also particularly interestedDetecting Turning Points of Trading Price and Return Volatility for Market Surveillance Agents

  19. Seasonal Variation in Volatile Compound Profiles of Preen Gland Secretions of the Dark-eyed Junco

    E-Print Network [OSTI]

    Ketterson, Ellen D.

    (Junco hyemalis) Helena A. Soini & Sara E. Schrock & Kevin E. Bruce & Donald Wiesler & Ellen D. Ketterson (AED) were utilized to analyze seasonal changes in volatile components of preen oil secretions in Junco . Gas chromatography-mass spectrometry J Chem Ecol DOI 10.1007/s10886-006-9210-0 H. A. Soini :K. E

  20. Zero-Carbon Cloud: A Volatile Resource for High-Performance Computing Andrew A. Chien

    E-Print Network [OSTI]

    Krintz, Chandra

    to exploit the volatile power efficiently. Keywords-Data Center; Stranded Power; Green computing; sustainable deployment of renewable power generation creates a growing opportunity in "stranded power", power that is generated a close to zero-cost, but not usable by the power grid. We propose to use this stranded power

  1. Acquisition and analysis of volatile memory from android devices Joe Sylve a

    E-Print Network [OSTI]

    Richard III, Golden G.

    Acquisition and analysis of volatile memory from android devices Joe Sylve a , Andrew Case b 24 October 2011 Keywords: Android Memory forensics Memory analysis Linux Mobile device forensics a b s t r a c t The Android operating system for mobile phones, which is still relatively new, is rapidly

  2. Thursday, March 15, 2007 POSTER SESSION II: MOON: SOILS, POLES, AND VOLATILES

    E-Print Network [OSTI]

    Rathbun, Julie A.

    Thursday, March 15, 2007 POSTER SESSION II: MOON: SOILS, POLES, AND VOLATILES 6:30 p.m. Fitness Center Schultz R. A. Siddharthan R. Strength of Lunar Soil Using the Cam Cap Approach [#1127] We use a standard Cam Cap approach to model the strength of returned Apollo 12 lunar soil. Cohesion, friction

  3. Multi-scale Jump and Volatility Analysis for High-Frequency Financial Data

    E-Print Network [OSTI]

    Fan, Jianqing

    Multi-scale Jump and Volatility Analysis for High-Frequency Financial Data Jianqing Fan and Yazhen Wang Version of May 2007 Abstract The wide availability of high-frequency data for many financial-diffusion processes observed with market microstructure noise are frequently used to model high-frequency financial

  4. Large Volatility Matrix Inference via Combining Low-Frequency and High-Frequency Approaches

    E-Print Network [OSTI]

    Wang, Yazhen

    Large Volatility Matrix Inference via Combining Low-Frequency and High-Frequency Approaches Minjing adequate estimates and forecasts. Furthermore, since high-frequency financial data for different assets applicable. To overcome those difficulties we explore a novel approach that combines high-frequency

  5. ESTIMATING THE VOLATILITY OF SPOT PRICES IN RESTRUCTURED ELECTRICITY MARKETS AND THE IMPLICATIONS FOR OPTION VALUES

    E-Print Network [OSTI]

    Draft 1e ESTIMATING THE VOLATILITY OF SPOT PRICES IN RESTRUCTURED ELECTRICITY MARKETS depends critically on the specification and estimation of the stochastic process that describes the price path. Accurate valuation of claims based on competitive electricity prices has proved problematic

  6. Sulfur Volatiles in Guava (Psidium guajava L.) Leaves: Possible Defense Mechanism

    E-Print Network [OSTI]

    Burns, Jacqueline K.

    dioxide, methanethiol, dimethyl sulfide (DMS), dimethyl disulfide (DMDS), methional, and dimethyl-Wax, and PLOT columns and MS spectra in the case of DMDS and DMS. DMDS is an insect toxic, defensive volatile for the protective effect of guava against the HLB vector. DMDS is formed immediately after crushing, becoming

  7. Experimental studies of actinide volatilities with application to mixed waste oxidation processors

    SciTech Connect (OSTI)

    Krikorian, O.H.; Ebbinghaus, B.B.; Condit, R.H.; Adamson, M.G.; Fontes, A.S. Jr.; Fleming, D.L.

    1993-04-30

    The transpiration technique is used to measure volatilities of U from U{sub 3}O{sub 8}(s), Pu from PuO{sub 2}(s) and Pu and Am from PuO{sub 2}/2%AmO{sub 2}(s) in the presence of steam and oxygen at temperatures ranging from 900 to 1300{degree}C.

  8. Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review

    SciTech Connect (OSTI)

    Burant, Aniela; Lowry, Gregory V.; Karamalidis, Athanasios K.

    2013-01-13

    Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oil–brine–sc-CO{sub 2} system under carbon storage conditions. The solubility of pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by cosolvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oil–brine–sc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and cosolvency, which will require more experimental data from key classes of organic compounds.

  9. Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review

    SciTech Connect (OSTI)

    Burant, Aniela; Lowry, Gregory V.; Karamalidis, Athanasios K.

    2013-01-01

    Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oil–brine–sc-CO{sub 2} system under carbon storage conditions. The solubility of pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by co-solvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oil-brine-sc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and co-solvency, which will require more experimental data from key classes of organic compounds.

  10. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    in the Haynesville Shale, Environ. Sci. Technol. , 44(24),of methane emissions from shale gas development, Proc. Natl.and northeastern Marcellus shale gas production regions, J.

  11. Impact of biogenic volatile organic compounds on ozone production at the Taehwa Research Forest near Seoul, South Korea

    E-Print Network [OSTI]

    2013-01-01

    NASA INTEX-B mission. Atmospheric Chemistry and Physics 9,HaChi summer campaign. Atmospheric Chemistry and Physics 11,aerosols from nature). Atmospheric Chemistry and Physics 6,

  12. In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust Particulate and Semi-Volatile Organic Compound Materials

    Broader source: Energy.gov [DOE]

    2002 DEER Conference Presentation: U.S. Centers for Disease Control and Prevention - National Institute for Occupational Safety and Health

  13. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    Greater focus needed on methane leakage from natural gasAnthropogenic emissions of methane in the United States,A. R. , et al. (2014), Methane leaks from North American

  14. Sources and photochemistry of volatile organic compounds in the remote atmosphere of western China: results from the Mt. Waliguan Observatory

    E-Print Network [OSTI]

    2013-01-01

    sites a . Waliguan b Species Ethane Propane n-butanei-butane n-pentane i-pentane Ethene Propene Isoprene EthyneNorth b CO Ethane Propane n-butane i-butane Ethyne Benzene

  15. Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform in Houston, Texas: Trends and Tracers 

    E-Print Network [OSTI]

    Hale, Martin C

    2014-05-08

    and traffic counts except during variable working hours. To assign measured fluxes to local sources, we tested a bulk flux footprint model (Kormann and Meixner model) designed for uniform emission surface areas in this urban, heterogeneous landscape. Tracer...

  16. Model Estimates of the Contributions of Environmental Tobacco Smoke to Volatile Organic Compound Exposures in Office Buildings

    E-Print Network [OSTI]

    Daisey, J.M.

    2008-01-01

    Acrolein Limonene 1,3-Butadiene Formaldehyde Acetaldehydesuch as aldehydes, 1,3-butadiene and limonene. Consequently,acrolein, acetaldehyde and 1,3-butadiene, particularly under

  17. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    enhancement ratios of CH 4 /benzene (>10 6 ppb/ ppb) [Kim etof CH 4 and Toluene to Benzene From Different Shale PlaysUrban emissions CH 4 /Benzene, ppb/ppb Toluene/Benzene, ppb/

  18. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    of methane emissions from oil and gas production pads using2015), In?uence of oil and gas ?eld operations on spatialux measurements over oil and gas extraction regions •

  19. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    well sites of the Barnett shale gas play [Eastern Researchof well sites in the Barnett shale play accounted for 70% of

  20. A novel Whole Air Sample Profiler (WASP) for the quantification of volatile organic compounds in the boundary layer

    E-Print Network [OSTI]

    Mak, JE; Su, L; Guenther, A; Karl, T

    2013-01-01

    304 stainless steel tubing, PTFE tubing and silco-treatedfield campaigns. For the PTFE tubing, the propene peakbe due to the low friction of PTFE material, therefore, for