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Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN  

SciTech Connect (OSTI)

Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

MARUSICH, R.M.

2006-07-10T23:59:59.000Z

2

NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

generation and reduction of the Page 3 of 21 VOC borehole due to creep closure of the salt (DOE 1996a), which might result in VOC emissions from the canister into the room. The...

3

Extended Research on Detection of Deception Using Volatile Organic Compound (VOC) Emissions  

SciTech Connect (OSTI)

A system that captures and analyzes volatile organic compound (VOC) emissions from skin surfaces may offer a viable alternative method to the polygraph instrument currently in use for detecting deception in U.S. government settings. Like the involuntary autonomic central nervous system response data gathered during polygraph testing, VOC emissions from the skin may provide data that can be used to detect stress caused by deception. Detecting VOCs, then, may present a noninvasive, non-intrusive method for observing, recording, and quantifying evidence of stress or emotional change.

Center for Human Reliability Studies

2006-06-01T23:59:59.000Z

4

Technology projects for characterization--monitoring of volatile organic compounds (VOCs)  

SciTech Connect (OSTI)

One hundred thirty technology project titles related to the characterization of volatile organic compounds (VOCs) at an arid site are listed alphabetically by first contact person in a master compilation that includes phone numbers, addresses, keywords, and short descriptions. Separate tables are presented for 62 field-demonstrated, 36 laboratory-demonstrated, and 35 developing technology projects. The technology projects in each of these three categories are also prioritized in separate summary tables. Additional tables are presented for a number of other categorizations of the technology projects: In Situ; Fiberoptic; Mass Spectrometer; Optical Spectroscopy; Raman or SERS; Ion Mobility or Acoustic; Associated; and Commercial. Four lists of contact person names are provided so details concerning the projects that deal with sampling, and VOCs in gases, waters, and soils (sediments) can be obtained. Finally, seven wide-ranging conclusions based on observations and experiences during this work are presented.

Junk, G.A.; Haas, W.J. Jr.

1992-07-01T23:59:59.000Z

5

TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS  

SciTech Connect (OSTI)

This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating agent overestimate the value of the VOCs in a sample. By overestimating the VOC content of a sample, we want to minimize false negatives. A false negative is defined as incorrectly estimating the VOC content of the sample to be below programmatic action limits when, in fact, the sample,exceeds the action limits. The disadvantage of overestimating the flammable VOC content of a sample is that additional cost may be incurred because additional sampling and GC-MS analysis may be required to confirm results over programmatic action limits. Therefore, choosing an appropriate calibration standard for the Ar-PDHID is critical to avoid false negatives and to minimize additional analytical costs.

DOUGLAS, J.G.

2006-07-06T23:59:59.000Z

6

Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong  

E-Print Network [OSTI]

Chemistry and Physics Vehicular emission of volatile organicY. , and Huang, Y. S. : Emission factors and characteristicslight-duty vehicle emissions, Environ. Sci. Technol. , 30,

2009-01-01T23:59:59.000Z

7

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

8

Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong  

E-Print Network [OSTI]

ethene toluene n-butane propane i-pentane i-butane propeneethene, toluene, n-butane, propane and i-pentane. These fiveVOCs emitted. The high propane and n-butane emissions were

2009-01-01T23:59:59.000Z

9

Volatile organic compound sensing devices  

DOE Patents [OSTI]

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

1995-08-29T23:59:59.000Z

10

Volatile organic compound sensing devices  

DOE Patents [OSTI]

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

Lancaster, Gregory D. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID); Reagen, William K. (Stillwater, MN)

1995-01-01T23:59:59.000Z

11

Analysis of volatile organic compounds (VOCs) in A/M Area Crouch Branch (Cretaceous) Aquifer characterization samples: 1993  

SciTech Connect (OSTI)

Samples were collected during the A/M Area Crouch Branch (Cretaceous) Aquifer Characterization (Phase I) Program. The samples were analyzed for chlorinated VOCs by the Savannah River Technology Center (SRTC) and MicroSeeps Ltd. All samples were sealed in the field immediately upon retrieval of the core and subsampling. A total of 113 samples locations were selected for analysis. The Environmental Sciences Section (ESS) of SRTC analyzed all locations in duplicate (226 samples). MicroSeeps Ltd was selected as the quality assurance (QA) check laboratory. MicroSeeps Ltd analyzed 40 locations with 4 duplicates (44 samples). The samples were collected from seven boreholes in A/M Area in the interval from 200 feet deep to the total depth of the boring (360 feet deep nominal); samples were collected every 10 feet within this interval. The sampling zone corresponds approximately to the Crouch Branch Aquifer in A/M Area. The overall A/M Area Crouch Branch Aquifer characterization objectives, a brief description of A/M Area geology and hydrology, and the sample locations, field notes, driller lithologic logs, and required procedural documentation are presented in WSRC (1993).

Looney, B.B.; Haselow, J.S.; Keenan, M.A.; Van Pelt, R.; Eddy-Dilek, C.A.; Rossabi, J.; Simmons, J.L.

1993-12-06T23:59:59.000Z

12

Energy Efficient Removal of Volatile Organic Compounds (VOCs) and Organic Hazardous Air Pollutants (o-HAPs) from Industrial Waste Streams by Direct Electron Oxidation  

SciTech Connect (OSTI)

This research program investigated and quantified the capability of direct electron beam destruction of volatile organic compounds and organic hazardous air pollutants in model industrial waste streams and calculated the energy savings that would be realized by the widespread adoption of the technology over traditional pollution control methods. Specifically, this research determined the quantity of electron beam dose required to remove 19 of the most important non-halogenated air pollutants from waste streams and constructed a technical and economic model for the implementation of the technology in key industries including petroleum refining, organic & solvent chemical production, food & beverage production, and forest & paper products manufacturing. Energy savings of 75 - 90% and green house gas reductions of 66 - 95% were calculated for the target market segments.

Testoni, A. L.

2011-10-19T23:59:59.000Z

13

Volatile organic compound sensor system  

DOE Patents [OSTI]

Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

Schabron, John F. (Laramie, WY); Rovani, Jr., Joseph F. (Laramie, WY); Bomstad, Theresa M. (Waxahachie, TX); Sorini-Wong, Susan S. (Laramie, WY); Wong, Gregory K. (Laramie, WY)

2011-03-01T23:59:59.000Z

14

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS  

SciTech Connect (OSTI)

Western Research Institute (WRI) initiated exploratory work towards the development of new field screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of carbon-halogen bonds. Commercially available heated diode and corona discharge leak detectors were procured and evaluated for halogenated VOC response. The units were modified to provide a digital readout of signal related to VOC concentration. Sensor response was evaluated with carbon tetrachloride and tetrachloroethylene (perchloroethylene, PCE), which represent halogenated VOCs with and without double bonds. The response characteristics were determined for the VOCs directly in headspace in Tedlar bag containers. Quantitation limits in air were estimated. Potential interferences from volatile hydrocarbons, such as toluene and heptane, were evaluated. The effect of humidity was studied also. The performance of the new devices was evaluated in the laboratory by spiking soil samples and monitoring headspace for halogenated VOCs. A draft concept of the steps for a new analytical method was outlined. The results of the first year effort show that both devices show potential utility for future analytical method development work towards the goal of developing a portable test kit for screening halogenated VOCs in the field.

John F. Schabron; Joseph F. Rovani Jr.; Theresa M. Bomstad

2002-06-01T23:59:59.000Z

15

Electrospun Polyurethane Fibers for Absorption of Volatile Organic Compounds from Air  

E-Print Network [OSTI]

Electrospun polyurethane fibers for removal of volatile organic compounds (VOC) from air with rapid VOC absorption and desorption have been developed. Polyurethanes based on 4,4-methylenebis(phenylisocyanate) (MDI) and ...

Scholten, Elke

16

Influence of Atmospheric Pressure and Water Table Fluctuations on Gas Phase Flow and Transport of Volatile Organic Compounds (VOCs) in Unsaturated Zones  

E-Print Network [OSTI]

in previous studies. This dissertation systematically investigates their influence on the gas phase flow and transport of VOCs in soil and ground water remediation processes using analytically and numerically mathematical modeling. New semi...

You, Kehua

2013-04-19T23:59:59.000Z

17

TMVOC, simulator for multiple volatile organic chemicals  

SciTech Connect (OSTI)

TMVOC is a numerical simulator for three-phase non-isothermal flow of water, soil gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. It is an extension of the TOUGH2 general-purpose simulation program developed at the Lawrence Berkeley National Laboratory. TMVOC is designed for applications to contamination problems that involve hydrocarbon fuel or organic solvent spills in saturated and unsaturated zones. It can model contaminant behavior under ''natural'' environmental conditions, as well as for engineered systems, such as soil vapor extraction, groundwater pumping, or steam-assisted source remediation. TMVOC is upwards compatible with T2VOC (Falta et al., 1995) and can be initialized from T2VOC-style initial conditions. The main enhancements in TMVOC relative to T2VOC are as follows: a multicomponent mixture of volatile organic chemicals can be modeled; any and all combinations of the three phases water-oil-gas are treated; several non-condensible gases may be present; diffusion is treated in all phases in a manner that is fully coupled with phase partitioning. This paper gives a brief summary of the methodology used in TMVOC as well as highlighting some implementation issues. Simulation of a NAPL spill and subsequent remediation is discussed for a 2-D vertical section of a saturated-unsaturated flow problem.

Pruess, Karsten; Battistelli, Alfredo

2003-03-25T23:59:59.000Z

18

Volatile organic compound losses from sewage sludge-amended soils  

SciTech Connect (OSTI)

Volatile organic compounds (VOCs) applied to soil in sludge have been assumed to disappear quickly and completely. The VOC behavior in sludge-amended soils has been studied previously only in laboratory systems where the sludged soil has been spiked with compounds of interest. Behavior in these systems may not necessarily represent compound behavior in field soils to which contaminated sludge is added. A series of laboratory microcosm experiments were designed therefore to investigate the behavior of toluene, ethyl benzene, o-, m-, and p-xylene applied to soil in contaminated sludge, and factors influencing loss processes. The VOC loss from sludge-amended soil was well described by a simple one step pseudo-first-order model but in certain soils was better described by a two step first-order model. Volatilization was the predominant loss process. Rates of loss depended on sludge application rate, method of sludge application, soil properties, and on compound characteristics. Experiments indicated that spiking sludge-amended soils gave a reasonable indication of VOC loss rates from systems amended with contaminated sludge at least over a period of 23 d. The majority of VOCs applied to soils in sludge volatilizes quickly to the atmosphere over a few to 10s of days with a small fraction lost more slowly. Potential for VOC crop uptake, livestock ingestion, and contamination of ground water is low under routine, managed applications of sewage sludge to agricultural land.

Wilson, S.C.; Jones, K.C.

1999-08-01T23:59:59.000Z

19

Measurements of Volatile Organic Compounds Using Proton Transfer Reaction - Mass Spectrometry during the MILAGRO 2006 Campaign  

E-Print Network [OSTI]

Volatile organic compounds (VOCs) were measured by proton transfer reaction – mass spectrometry (PTR-MS) on a rooftop in the urban mixed residential and industrial area North Northeast of downtown Mexico City as part of ...

Fortner, E. C.

20

Literature review of stabilization/solidification of volatile organic compounds and the implications for Hanford grouts  

SciTech Connect (OSTI)

A literature review was conducted on the stabilization/solidification of volatile organic compounds (VOCs). Based on this literature, it is likely that the limestone-containing grout will not permanently immobilize VOCs and that no presently available additives can guarantee permanent immobilization. The Westinghouse hanford company grout may be fairly effective at retarding aqueous leaching of VOCs, and commercial additives can improve this performance. Significant VOC losses do occur during stabilization/solidification, and the high temperatures of the Westinghouse Hanford Company waste and grout should exacerbate this problem. In fact, these high temperatures raise doubts about the presence of VOCs in the double-shell tanks supernates.

Spence, R.D.; Osborne, S.C.

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS  

SciTech Connect (OSTI)

Western Research Institute (WRI) is continuing work toward the development of new screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of halogens. In prior work, the devices were tested for response to carbon tetrachloride, heptane, toluene, and water vapors. In the current work, sensor response was evaluated with sixteen halogenated VOCs relative to carbon tetrachloride. The results show that the response of the various chlorinated VOCs is within an order of magnitude of the response to carbon tetrachloride for each of the sensors. Thus, for field screening a single response factor can be used. Both types of leak detectors are being further modified to provide an on-board LCD signal readout, which is related to VOC concentration. The units will be fully portable and will operate with 115-V line or battery power. Signal background, noise level, and response data on the Bacharach heated diode detector and the TIF corona discharge detector show that when the response curves are plotted against the log of concentration, the plot is linear to the upper limit for the particular unit, with some curvature at lower levels. When response is plotted directly against concentration, the response is linear at the low end and is curved at the high end. The dynamic ranges for carbon tetrachloride of the two devices from the lower detection limit (S/N=2) to signal saturation are 4-850 vapor parts per million (vppm) for the corona discharge unit and 0.01-70 vppm for the heated diode unit. Additional circuit modifications are being made to lower the detection limit and increase the dynamic response range of the corona discharge unit. The results indicate that both devices show potential utility for future analytical method development work toward the goal of developing a portable test kit for screening halogenated VOCs in the field.

John F. Schabron; Joseph F. Rovani, Jr.; Theresa M. Bomstad

2003-07-01T23:59:59.000Z

22

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2  

E-Print Network [OSTI]

methyl tertiary- butyl ether (MTBE) and its effect on plasmaand three VOCs (propyne, furan, MTBE) remained below their 3Ethanol Acetone MEK MAC MVK MTBE Furan CH 3 OH C 2 H 5 OH C

2010-01-01T23:59:59.000Z

23

Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles  

SciTech Connect (OSTI)

This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

Mohan, S.; Nagarkatti, M. [Trinity Consultants, Inc., Baton Rouge, LA (United States)

1996-12-31T23:59:59.000Z

24

Modeling VOC sorption of building materials and its impact on indoor air quality  

E-Print Network [OSTI]

Sorption of volatile organic compounds (VOCs) by building materials can have significant effect on the indoor VOC concentration levels and indoor air quality in buildings. The objective of this study was to investigate ...

Zhang, Jinsong, 1975-

2001-01-01T23:59:59.000Z

25

Volatile Organic Compound Discrimination using Nanostructured Polythiophene Sensors  

E-Print Network [OSTI]

in determining response to specific VOCs. I. INTRODUCTION A low-cost, low-power, and portable device for volatile selectivity. While there has been limited success in sensor development for greenhouse gases (CO2, CH4, N2O, NO and CO), the technology for detection of VOCs remains weak due to the similarity of chemical composition

Weiss, Lee E.

26

Characteristics of the volatile organic compounds -- Arid Integrated Demonstration Site  

SciTech Connect (OSTI)

The Volatile Organic Compounds -- Arid Integrated Demonstration Program (VOC-Arid ID) is targeted at demonstration and testing of technologies for the evaluation and cleanup of volatile organic compounds and associated contaminants at arid DOE sites. The initial demonstration site is an area of carbon tetrachloride (CCl{sub 4}) contamination located near the center of the Hanford Site. The movement of CCl{sub 4} and other volatile organic contaminants in the subsurface is very complex. The problem at the Hanford Site is further complicated by the concurrent discharge of other waste constituents including acids, lard oil, organic phosphates, and transuranic radionuclides. In addition, the subsurface environment is very complex, with large spatial variabilities in hydraulic properties. A thorough understanding of the problem is essential to the selection of appropriate containment, retrieval, and/or in situ remedial technologies. The effectiveness of remedial technologies depends on knowing where the contaminants are, how they are held up in a given physical and chemical subsurface environment; and knowing the physical, chemical, and microbiological changes that are induced by the various remedial technologies.

Last, G.V.; Lenhard, R.J.; Bjornstad, B.N.; Evans, J.C.; Roberson, K.R.; Spane, F.A.; Amonette, J.E.; Rockhold, M.L.

1991-10-01T23:59:59.000Z

27

5, 90979126, 2005 VOC emissions from  

E-Print Network [OSTI]

ACPD 5, 9097­9126, 2005 VOC emissions from vegetation pyrolysis J. P. Greenberg et al. Title Page Discussions Volatile organic emissions from the distillation and pyrolysis of vegetation J. P. Greenberg, H is licensed under a Creative Commons License. 9097 #12;ACPD 5, 9097­9126, 2005 VOC emissions from vegetation

Paris-Sud XI, Université de

28

Partitioning of Volatile Organics in Diesel Particulate and Exhaust...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Exhaust Partitioning of Volatile Organics in Diesel Particulate and Exhaust Evaluation of how sampling details affect the measurement of volatile organic compounds in...

29

Detection of Low Volatility Organic Analytes on Soils Using Infrared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Low Volatility Organic Analytes on Soils Using Infrared Reflection Spectroscopy. Abstract: Previous work on detection of low-volatility liquid organic (and...

30

Comparative Toxicity of Combined Particle and Semi-Volatile Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions Comparative Toxicity of Combined Particle and Semi-Volatile Organic Fractioins...

31

Diversity of the Volatile Organic Compounds Emitted by 55 Species of Tropical Trees: a Survey in French Guiana  

E-Print Network [OSTI]

in French Guiana Elodie A. Courtois & C. E. Timothy Paine & Pierre-Alain Blandinieres & Didier Stien & Jean, LLC 2009 Abstract Volatile organic compounds (VOCs) are pro- duced by a broad range of organisms, from tropical tree species in a lowland rainforest of French Guiana. We discovered a remarkably high chemical

Chave, JĂ©rĂ´me

32

Energy Saving System to Remove Volatile Organic Compounds (VOCs) from  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecondCareerFebruary 2005Energy Saver 101:SavingP R I

33

ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT  

E-Print Network [OSTI]

ACCEPTED BY WATER ENVIRONMENT RESEARCH _______ ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT of biofilters for sequential removal of H2S and VOCs from wastewater treatment plant waste air. The biofilter volatile organic compounds (VOCs) and toxic air pollutants emitted from wastewater and solids handling

34

VOC transport in vented drums containing simulated waste sludge  

SciTech Connect (OSTI)

A model is developed to estimate the volatile organic compound (VOC) concentration in the headspace of the innermost layer of confinement in a lab-scale vented waste drum containing simulated waste sludge. The VOC transport model estimates the concentration using the measured VOC concentration beneath the drum lid and model parameters defined or estimated from process knowledge of drum contents and waste drum configuration. Model parameters include the VOC diffusion characteristic across the filter vent, VOC diffusivity in air, size of opening in the drum liner lid, the type and number of layers of polymer bags surrounding the waste, VOC permeability across the polymer, and the permeable surface area of the polymer bags. Comparison of model and experimental results indicates that the model can accurately estimate VOC concentration in the headspace of the innermost layer of confinement. The model may be useful in estimating the VOC concentration in actual waste drums.

Liekhus, K.J.; Gresham, G.L.; Rae, C.; Connolly, M.J.

1994-02-01T23:59:59.000Z

35

Real-time monitoring of volatile organic compounds using chemical ionization mass spectroscopy: Final report  

SciTech Connect (OSTI)

Volatile organic compound (VOC) emission to the atmosphere is of great concern to semiconductor manufacturing industries, research laboratories, the public, and regulatory agencies. Some industries are seeking ways to reduce emissions by reducing VOCs at the point of use (or generation). This paper discusses the requirements, design, calibration, and use of a sampling inlet/quadrupole mass spectrometer system for monitoring VOCs in a semiconductor manufacturing production line. The system uses chemical ionization to monitor compounds typically found in the lithography processes used to manufacture semiconductor devices (e.g., acetone, photoresist). The system was designed to be transportable from tool to tool in the production line and to give the operator real-time feedback so the process(es) can be adjusted to minimize VOC emissions. Detection limits ranging from the high ppb range for acetone to the low ppm range fore other lithography chemicals were achieved using chemical ionization mass spectroscopy at a data acquisition rate of approximately 1 mass spectral scan (30 to 200 daltons) per second. A demonstration of exhaust VOC monitoring was performed at a working semiconductor fabrication facility during actual wafer processing.

Thornberg, S.M.; Mowry, C.D.; Keenan, M.R.; Bender, S.F.A. [Sandia National Labs., Albuquerque, NM (United States). Gas Analysis Lab.; Owen, T. [Intel Corp., Rio Rancho, NM (United States)

1997-04-01T23:59:59.000Z

36

Micropatterned Polymeric Gratings as Chemoresponsive Volatile Organic Compound  

E-Print Network [OSTI]

Micropatterned Polymeric Gratings as Chemoresponsive Volatile Organic Compound Sensors, Northwestern University, Evanston, Illinois 60208 Micropatterned polymeric diffraction gratings have been

37

Particulate Matter Sampling and Volatile Organic Compound Removal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization...

38

Thermal treatment for VOC control  

SciTech Connect (OSTI)

Catalytic and thermal oxidation are well-established technologies for controlling volatile organic compounds (VOCs). Oxidation destroys pollutants, rather than capturing them. Oxidation units can destroy nearly 100% of VOC and toxic emissions targeted by the Clean Air Act Amendments of 1990--some systems attain destruction efficiencies over 99.99%. To assist in the design of these systems, an engineer will often look a/t the heat of combustion of the gas stream, along with the type of pollutant, to best determine the correct type of oxidation device to use. The paper discusses catalytic and thermal oxidation, energy recovery, and equipment for these processes.

Cloud, R.A. [Huntington Environmental Systems, Schaumburg, IL (United States)

1998-07-01T23:59:59.000Z

39

aqueous volatile organic: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mirna 1997-01-01 39 Impacts of herbaceous bioenergy crops on atmospheric volatile organic composition and potential consequences Environmental Sciences and Ecology Websites...

40

VOCs and formaldehyde emissions from cleaning products and air Ccilia Solal1,*  

E-Print Network [OSTI]

VOCs and formaldehyde emissions from cleaning products and air fresheners CĂ©cilia Solal1: air fresheners, glass cleaners, furniture polishes, toilet products, carpet and floor cleaning Formaldehyde, Volatile organic compounds, Household products, Exposure INTRODUCTION Most indoor air pollutants

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Origins of volatile organic compounds emerging from tank 241-C-106 during sluicing  

SciTech Connect (OSTI)

Unexpectedly high concentrations of inorganic gases and volatile organic compounds (VOC) were released from the ventilation stack of tank 241-C-106 during sluicing operations on November 18, 1998. Workers experienced serious discomfort. They reported an obnoxious acrid odor and the 450 ppm VOC in ventilation stack 296-C-006 exceeded the level approved in the air discharge permit. Consequently, the operation was terminated. Subsequent analyses of samples collected opportunistically from the stack indicated many organic compounds including heptenes, heptanones, and normal paraffin hydrocarbons (NPH) and their remnants were present. Subsequently, a process test designed to avoid unnecessary worker exposure and enable collection of analytical samples from the stack, the breathing area, and the receiver tank was conducted on December 16, 1998. The samples obtained during that operation, in which the maximum VOC content of the stack was approximately 35 ppm, have been analyzed by teams at Pacific Northwest National Laboratory and Special Analytic Services (SAS). This report examines the results of these investigations. Future revisions of the report will examine the analytical results obtained for samples collected during sluicing operations in March. This report contains the available evidence about the source term for these emissions. Chapter 2 covers characterization work, including historical information about the layers of waste in the tank, the location of organic compounds in these layers, the total organic carbon (TOC) content and the speciation of organic compounds. Chapter 3 covers the data for the samples from the ventilation stack, which has the highest concentrations of organic compounds. Chapter 4 contains an interpretation of the information connecting the composition of the organic emissions with the composition of the original source term. Chapter 5 summarizes the characterization work, the sample data, and the interpretation of the results.

STAUFFER, L.A.

1999-06-02T23:59:59.000Z

42

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: Measurement comparison, emission ratios, and source attribution  

SciTech Connect (OSTI)

Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements and to aid in the identification of unknown VOCs. The VOC measurements are also compared to simultaneous canister samples and to two independent proton-transfer-reaction mass spectrometers (PTR-MS) deployed on a mobile and an airborne platform during MILAGRO. VOC diurnal cycles demonstrate the large influence of vehicle traffic and liquid propane gas (LPG) emissions during the night and photochemical processing during the afternoon. Emission ratios for VOCs and OVOCs relative to CO are derived from early-morning measurements. Average emission ratios for non-oxygenated species relative to CO are on average a factor of {approx}2 higher than measured for US cities. Emission ratios for OVOCs are estimated and compared to literature values the northeastern US and to tunnel studies in California. Positive matrix factorization analysis (PMF) is used to provide insight into VOC sources and processing. Three PMF factors were distinguished by the analysis including the emissions from vehicles, the use of liquid propane gas and the production of secondary VOCs + long-lived species. Emission ratios to CO calculated from the results of PMF analysis are compared to emission ratios calculated directly from measurements. The total PIT-MS signal is summed to estimate the fraction of identified versus unidentified VOC species.

Bon, D.M.; Springston, S.; M.Ulbrich, I.; de Gouw, J. A.; Warneke, C.; Kuster, W. C.; Alexander, M. L.; Baker, A.; Beyersdorf, A. J.; Blake, D.; Fall, R.; Jimenez, J. L., Herndon, S. C.; Huey, L. G.; Knighton, W. B.; Ortega, J.; Vargas, O.

2011-03-16T23:59:59.000Z

43

In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30F In Vitro Genotoxicity of Particulate...

44

Refinement of ptr-ms methodology and application to the measurement of (o)vocs from cattle slurry.   

E-Print Network [OSTI]

Oxygenated volatile organic compounds ((O)VOCs) contribute to ozone formation, affect the oxidising capacity of the troposphere and are sources of growth, and in some cases formation, of aerosols. It is therefore important ...

House, Emily

2009-01-01T23:59:59.000Z

45

Online measurements of the emissions of intermediate-volatility and semi-volatile organic compounds from aircraft  

E-Print Network [OSTI]

A detailed understanding of the climate and air quality impacts of aviation requires measurements of the emissions of intermediate-volatility and semi-volatile organic compounds (I/SVOCs) from aircraft. Currently both the ...

Herndon, S. C.

46

Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Performance Building  

SciTech Connect (OSTI)

The developers of the Paharpur Business Center (PBC) and Software Technology Incubator Park in New Delhi, India offer an environmentally sustainable building with a strong emphasis on energy conservation, waste minimization and superior indoor air quality (IAQ). To achieve the IAQ goal, the building utilizes a series of air cleaning technologies for treating the air entering the building. These technologies include an initial water wash followed by ultraviolet light treatment and biolfiltration using a greenhouse located on the roof and numerous plants distributed throughout the building. Even with the extensive treatment of makeup air and room air in the PBC, a recent study found that the concentrations of common volatile organic compounds and aldehydes appear to rise incrementally as the air passes through the building from the supply to the exhaust. This finding highlights the need to consider the minimization of chemical sources in buildings in combination with the use of advanced air cleaning technologies when seeking to achieve superior IAQ. The goal of this project was to identify potential source materials for indoor chemicals in the PBC. Samples of building materials, including wood paneling (polished and unpolished), drywall, and plastic from a hydroponic drum that was part of the air cleaning system, were collected from the building for testing. All materials were collected from the PBC building and shipped to the Lawrence Berkeley National Laboratory (LBNL) for testing. The materials were pre-conditioned for two different time periods before measuring material and chemical specific emission factors for a range of VOCs and Aldehydes. Of the six materials tested, we found that the highest emitter of formaldehyde was new plywood paneling. Although polish and paint contribute to some VOC emissions, the main influence of the polish was in altering the capacity of the surface to accumulate formaldehyde. Neither the new nor aged polish contributed significantly to formaldehyde emissions. The VOC emission stream (excluding formaldehyde) was composed of up to 18 different chemicals and the total VOC emissions ranged in magnitude from 7 mu g/m2/h (old wood with old polish) to>500 mu g/m2/h (painted drywall). The formaldehyde emissions from drywall and old wood with either new or old polish were ~;;15 mu g/m2/h while the new wood material emitted>100 mu g/m2/h. However, when the projected surface area of each material in the building was considered, the new wood, old wood and painted drywall material all contributed substantially to the indoor formaldehyde loading while the coatings contributed primarily to the VOCs.

Ortiz, Anna C.; Russell, Marion; Lee, Wen-Yee; Apte, Michael; Maddalena, Randy

2010-09-20T23:59:59.000Z

47

Reducing VOC Press Emission from OSB Manufacturing  

SciTech Connect (OSTI)

Current regulations require industry to meet air emission standards with regard to particulates, volatile organic compounds (VOCs), hazardous air pollutants (HAPs) and other gases. One of many industries that will be affected by the new regulations is the wood composites industry. This industry generates VOCs, HAPs, and particulates mainly during the drying and pressing of wood. Current air treatment technologies for the industry are expensive to install and operate. As regulations become more stringent, treatment technologies will need to become more efficient and cost effective. The overall objective of this study is to evaluate the use of process conditions and chemical additives to reduce VOC/HAPs in air emitted from presses and dryers during the production of oriented strand board.

Dr. Gary D. McGinnis; Laura S. WIlliams; Amy E. Monte; Jagdish Rughani: Brett A. Niemi; Thomas M. Flicker

2001-12-31T23:59:59.000Z

48

Cancer risks from soil emissions of volatile organic compounds at the Lawrence Livermore National Laboratory  

SciTech Connect (OSTI)

The emission isolation flux chamber (EIFC) methodology was applied to Superfund investigations at the Lawrence Livermore National Laboratory Site 300 to determine if on-site workers were exposed to VOCs volatilizing from the subsurface and what, if any, health risks could be attributed to the inhalation of the VOCs volatilizing from the subsurface. During July and August of 1996, twenty, eighteen, and twenty six VOC soil vapor flux samples were collected in the Building 830, 832, and 854 areas, respectively using EIFCS. The VOC concentrations in the vapor samples were used to calculate soil flux rates which were used as input into an air dispersion model to calculate ambient air exposure-point concentrations. The exposure-point concentrations were compared to EPA Region IX Preliminary Remediation Goals (PRGs). Buildings 830 and 832 exposure-point concentrations were less then the PRGs therefore no cancer risks were calculated. The cancer risks for Building 854 ranged from 1.6 x 10{sup -7} to 2.1 x 10{sup -6}. The resultant inhalation cancer risks were all within the acceptable range, implying that on-site workers were not exposed to VOC vapors volatilizing from the subsurface soil that could have significant cancer risks. Therefore remediation in these areas would not be necessary.

Dibley, V. R., LLNL

1998-02-01T23:59:59.000Z

49

ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS ? FINAL REPORT  

SciTech Connect (OSTI)

Four unoccupied FEMA temporary housing units (THUs) were studied to assess their indoor emissions of volatile organic compounds including formaldehyde. Measurement of whole-THU VOC and aldehyde emission factors (mu g h-1 per m2 of floor area) for each of the four THUs were made at FEMA's Purvis MS staging yard using a mass balance approach. Measurements were made in the morning, and again in the afternoon in each THU. Steady-state indoor formaldehyde concentrations ranged from 378 mu g m-3 (0.31ppm) to 632 mu g m-3 (0.52 ppm) in the AM, and from 433 mu g m-3 (0.35 ppm) to 926 mu g m-3 (0.78 ppm) in the PM. THU air exchange rates ranged from 0.15 h-1 to 0.39 h-1. A total of 45 small (approximately 0.025 m2) samples of surface material, 16 types, were collected directly from the four THUs and shipped to Lawrence Berkeley Laboratory. The material samples were analyzed for VOC and aldehyde emissions in small stainless steel chambers using a standard, accurate mass balance method. Quantification of VOCs was done via gas chromatography -- mass spectrometry and low molecular weight aldehydes via high performance liquid chromatography. Material specific emission factors (mu g h-1 per m2 of material) were quantified. Approximately 80 unique VOCs were tentatively identified in the THU field samples, of which forty-five were quantified either because of their toxicological significance or because their concentrations were high. Whole-trailer and material specific emission factors were calculated for 33 compounds. The THU emission factors and those from their component materials were compared against those measured from other types of housing and the materials used in their construction. Whole THU emission factors for most VOCs were typically similar to those from comparative housing. The three exceptions were exceptionally large emissions of formaldehyde and TMPD-DIB (a common plasticizer in vinyl products), and somewhat elevated for phenol. Of these three compounds, formaldehyde was the only one with toxicological significance at the observed concentrations. Whole THU formaldehyde emissions ranged from 173 to 266 mu g m-2 h 1 in the morning and 257 to 347 mu g m-2 h-1 in the afternoon. Median formaldehyde emissions in previously studied site-built and manufactured homes were 31 and 45 mu g m-2 h-1, respectively. Only one of the composite wood materials that was tested appeared to exceed the HUD formaldehyde emission standard (430 mu g/m2 h-1 for particleboard and 130 mu g/m2 h-1 for plywood). The high loading factor (material surface area divided by THU volume) of composite wood products in the THUs and the low fresh air exchange relative to the material surface area may be responsible for the excessive concentrations observed for some of the VOCs and formaldehyde.

Salazar, Olivia; Maddalena, Randy L.; Russell, Marion; Sullivan, Douglas P.; Apte, Michael G.

2008-05-04T23:59:59.000Z

50

A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution  

E-Print Network [OSTI]

We discuss the use of a two-dimensional volatility-oxidation space (2-D-VBS) to describe organic-aerosol chemical evolution. The space is built around two coordinates, volatility and the degree of oxidation, both of which ...

Donahue, N. M.

51

Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong  

E-Print Network [OSTI]

2004. Haszpra, L. and Szilagyi, I. : Non-methane hydrocarbonet al. , 1990; Haszpra and Szilagyi, 1994; Gertler et al. ,

2009-01-01T23:59:59.000Z

52

Southern California Edison's (SCE) Research Program for Industrial Volatile Organic Compound (VOC) Emissions Control  

E-Print Network [OSTI]

. Process Descriptions One of the polystyrene foam plants uses pentane as a blowing agent in the manufacturing process. while the other plant uses butane. Under the provisions, of AQMD Rule 1175, these plants will be I required to control 90 percent... by spray painting subject to AQ Rule 1124. Process Descriptions One of the polystyrene foam plants uses pentane as a blowing agent in the manufacturing process, while the other plant uses butane. Under the provisions of AQMD Rule 1175, these plants...

Sung, R. D.; Cascone, R.; Reese, J.

53

NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Opticalhttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gifAEnergy2014 SolidGold foil| Infrastructure

54

Development of new VOC exposure metrics and their relationship to ''Sick Building Syndrome'' symptoms  

SciTech Connect (OSTI)

Volatile organic compounds (VOCs) are suspected to contribute significantly to ''Sick Building Syndrome'' (SBS), a complex of subchronic symptoms that occurs during and in general decreases away from occupancy of the building in question. A new approach takes into account individual VOC potencies, as well as the highly correlated nature of the complex VOC mixtures found indoors. The new VOC metrics are statistically significant predictors of symptom outcomes from the California Healthy Buildings Study data. Multivariate logistic regression analyses were used to test the hypothesis that a summary measure of the VOC mixture, other risk factors, and covariates for each worker will lead to better prediction of symptom outcome. VOC metrics based on animal irritancy measures and principal component analysis had the most influence in the prediction of eye, dermal, and nasal symptoms. After adjustment, a water-based paints and solvents source was found to be associated with dermal and eye irritation. The more typical VOC exposure metrics used in prior analyses were not useful in symptom prediction in the adjusted model (total VOC (TVOC), or sum of individually identified VOCs ({Sigma}VOC{sub i})). Also not useful were three other VOC metrics that took into account potency, but did not adjust for the highly correlated nature of the data set, or the presence of VOCs that were not measured. High TVOC values (2--7 mg m{sup {minus}3}) due to the presence of liquid-process photocopiers observed in several study spaces significantly influenced symptoms. Analyses without the high TVOC values reduced, but did not eliminate the ability of the VOC exposure metric based on irritancy and principal component analysis to explain symptom outcome.

Ten Brinke, JoAnn [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab., Berkeley, CA (United States)

1995-08-01T23:59:59.000Z

55

Understanding complex Earth systems: volatile metabolites as microbial ecosystem proxies and student conceptual model development of coastal eutrophication  

E-Print Network [OSTI]

research strands which contribute to the scientific and pedagogical understanding of complex Earth systems. In the first strand, a method that characterizes volatile organic compounds (VOCs) as ecological proxies of soil microbial ecosystems was validated...

McNeal, Karen Sue

2009-05-15T23:59:59.000Z

56

Quantifying VOC emissions for the strategic petroleum reserve.  

SciTech Connect (OSTI)

A very important aspect of the Department of Energy's (DOE's) Strategic Petroleum Reserve (SPR) program is regulatory compliance. One of the regulatory compliance issues deals with limiting the amount of volatile organic compounds (VOCs) that are emitted into the atmosphere from brine wastes when they are discharged to brine holding ponds. The US Environmental Protection Agency (USEPA) has set limits on the amount of VOCs that can be discharged to the atmosphere. Several attempts have been made to quantify the VOC emissions associated with the brine ponds going back to the late 1970's. There are potential issues associated with each of these quantification efforts. Two efforts were made to quantify VOC emissions by analyzing VOC content of brine samples obtained from wells. Efforts to measure air concentrations were mentioned in historical reports but no data have been located to confirm these assertions. A modeling effort was also performed to quantify the VOC emissions. More recently in 2011- 2013, additional brine sampling has been performed to update the VOC emissions estimate. An analysis of the statistical confidence in these results is presented here. Arguably, there are uncertainties associated with each of these efforts. The analysis herein indicates that the upper confidence limit in VOC emissions based on recent brine sampling is very close to the 0.42 ton/MMB limit used historically on the project. Refining this estimate would require considerable investment in additional sampling, analysis, and monitoring. An analysis of the VOC emissions at each site suggests that additional discharges could be made and stay within current regulatory limits.

Knowlton, Robert G.; Lord, David L.

2013-06-01T23:59:59.000Z

57

Characterization of the Sources and Concentrations of Formaldehyde and other volatile organic compounds in four new manufactured houses  

SciTech Connect (OSTI)

The concentrations of formaldehyde, 52 individual volatile organic compounds (VOCs) and total VOCs (TVOC) were measured in four new manufactured houses on three occasions over a period of approximately nine months following completion of their construction. The houses were furnished, but unoccupied, model homes produced by a single U.S. manufacturer. Several of the houses incorporated interior finish materials with lower VOC emissions than standard materials. One house had a modified ventilation system. Ventilation rates were measured concurrently with the collection of air samples. A steady-state mass-balance model was used to calculate the area-specific emission rates of the target compounds and TVOC. The emissions of formaldehyde and VOCs from a specimen of plywood used as the floor sheeting were additionally quantified. The median formaldehyde concentration in the four houses was 37 parts-per-billion ( ppb). The formaldehyde concentrations were all less than the most restrictive guideline for this compound of 50 ppb. The concentrations of many of the target VOCs were low. Thirty-one of the VOCs had median concentrations that were at or below 1 ppb. Seven of the compounds were among the most abundant VOCs in all four houses. These compounds were alpha-pinene, beta-pinene, 3-carene, ethylene glycol, hexanal, 2-butanone, and acetic acid. The concentrations of the aldehydes, hexanal, octanal and nonanal, in the four houses were either near or exceeded their respective odor thresholds. The concentrations of acetic acid increased with time. In the final sampling period, the odor threshold for acetic acid was exceeded in all of the houses. The range of TVOC concentrations in the four houses was 0.8 to 3 mg m{sup -3}, with a median value of 1.6 mg m{sup -3}. These concentrations were somewhat lower than TVOC concentrations previously measured in several new site-built houses, and the median concentration was only about twice the typical value for existing residences. The house with the modified ventilation system and several lower emitting materials had consistently low TVOC concentrations that were near 1 mg m{sup -3}. There were no large decreases with time in the emission rates of the individual VOCs or TVOC during the course of the study. However, the emission rates were often lowest in the final sampling with the notable exception of the acetic acid emission rate that increased with time. The source of the aldehydes was most likely engineered wood products, such as the plywood floor sheeting and possibly other structural or interior components. The source of the acetic acid was uncertain. The effects of the source substitution treatments were measurable but turned out to be relatively minor due to the predominance of other sources.

Hodgson, A.T.; Beal, D.; Chandra, S.

1998-09-01T23:59:59.000Z

58

E-Print Network 3.0 - airborne volatile organic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

predicting volatile organic concentration levels immediately downwind of wastewater treatment facilities... aeration which is used to increase the purification capacity also...

59

Final Report on Testing of Off-Gas Treatment Technologies for Abatement of Atmospheric Emissions of Chlorinated Volatile Organic Compounds  

SciTech Connect (OSTI)

The purpose of this report is to summarize the results of the program for off-gas treatment of atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program was funded through the Department of Energy Office of Technology Development`s VOC`s in Non-Arid Soils Integrated Demonstration (VNID). The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed (Looney et al., 1991). That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the United States to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate cost effective evaluation of the emerging technologies. Another motivation for the program is that many CVOCs will be regulated under the Clean Air Act Amendments of 1990 and are already regulated by many state regulatory programs. Additionally, compounds such as TCE and PCE are pervasive subsurface environmental contaminants, and, as a result, a small improvement in terms of abatement efficiency or cost will significantly reduce CVOC discharges to the environment as well as costs to United States government and industry.

Jarosch, T.R.; Haselow, J.S.; Rossabi, J.; Burdick, S.A.; Raymond, R.; Young, J.E.; Lombard, K.H.

1995-01-23T23:59:59.000Z

60

MEASUREMENT OF VOC EMISSIONS FROM WOOD REMEDIAL TREATMENT: CHAMBER TESTS AND FIELD EXPERIMENTS  

E-Print Network [OSTI]

products on indoor air quality. The emissions of two wood remedial treatment products (water in real conditions during a roof renovation work in an old building. A petroleum-based solvent product of volatile organic compound (VOC) emissions from building products. Simple models can be applied to emission

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Energy efficient indoor VOC air cleaning with activated carbon fiber (ACF) filters Meera A. Sidheswaran a  

E-Print Network [OSTI]

Energy efficient indoor VOC air cleaning with activated carbon fiber (ACF) filters Meera A Keywords: Activated carbon fiberVolatile organic compoundIndoor pollutantEnergy efficient ventilation a b s t r a c t This study explores the potential environmental and energy benefits of using activated

62

Detection of volatile organic compounds using surface enhanced Raman scattering  

SciTech Connect (OSTI)

The authors present the detection of volatile organic compounds directly in their vapor phase by surface-enhanced Raman scattering (SERS) substrates based on lithographically-defined two-dimensional rectangular array of nanopillars. The type of nanopillars is known as the tapered pillars. For the tapered pillars, SERS enhancement arises from the nanofocusing effect due to the sharp tip on top. SERS experiments were carried out on these substrates using various concentrations of toluene vapor. The results show that SERS signal from a toluene vapor concentration of ppm level can be achieved, and the toluene vapor can be detected within minutes of exposing the SERS substrate to the vapor. A simple adsorption model is developed which gives results matching the experimental data. The results also show promising potential for the use of these substrates in environmental monitoring of gases and vapors.

Chang, A S; Maiti, A; Ileri, N; Bora, M; Larson, C C; Britten, J A; Bond, T C

2012-03-22T23:59:59.000Z

63

Chemical oxidation of volatile and semi-volatile organic compounds in soil  

SciTech Connect (OSTI)

Subsurface contamination with fuel hydrocarbons or chlorinated hydrocarbons is prevalent throughout the Department of Energy (DOE) complex and in many sites managed by the Environmental Protection Agency (EPA) Superfund program. The most commonly reported chlorinated hydrocarbons (occurring > 50% of DOE contaminated sites) were trichloroethylene (TCE), 1, 1, 1,-trichloroethane (TCA), and tetrachloroethylene (PCE) with concentrations in the range of 0.2 {mu}g/kg to 12,000 mg/kg. The fuel hydrocarbons most frequently reported as being present at DOE sites include aromatic compounds and polyaromatic compounds such as phenanthrene, pyrene, and naphthalene. The primary sources of these semi-volatile organic compounds (SVOCs) are coal waste from coal fired electric power plants used at many of these facilities in the past and gasoline spills and leaks. Dense non-aqueous phase liquids (DNAPLs) can migrate within the subsurface for long periods of time along a variety of pathways including fractures, macropores, and micropores. Diffusion of contaminants in the non-aqueous, aqueous, and vapor phase can occur from the fractures and macropores into the matrix of fine-textured media. As a result of these contamination processes, removal of contaminants from the subsurface and the delivery of treatment agents into and throughout contaminated regions are often hindered, making rapid and extensive remediation difficult.

Gates, D.D.; Siegrist, R.L.; Cline, S.R.

1995-06-01T23:59:59.000Z

64

Volatile Organic Compounds in Untreated Ambient Groundwater of  

E-Print Network [OSTI]

, 1608 Mt. View Road, Rapid City, South Dakota 57702 As part of the National Water-Quality Assessment from this ambient groundwater is uncertain because the quality of the finished drinking water with the largest releases to the environment are VOCs and that the total release for these 10 compounds was almost

65

Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction  

SciTech Connect (OSTI)

Evidence is mounting that the majority of the climatically active aerosols are produced through the growth of smaller particles via secondary organic aerosol (SOA) formation from gas-to-particle conversion of anthropogenic and biogenic volatile organic compounds (VOCs). The timescale of SOA partitioning and the associated size distribution dynamics are expected to depend on the gas-phase oxidation of the precursor VOCs and their products, volatility of these organic solutes, composition and phase state of the pre-existing particles, and diffusivity and reactivity of the solute within the particle phase. This paper describes a new framework for modeling kinetic gas-particle partitioning of SOA, with an analytical treatment for the diffusion-reaction process within the particle phase. The formulation is amenable for eventual use in regional and global climate models, although it currently awaits implementation of the actual particle-phase reactions that are important for SOA formation. In the present work, the model is applied to investigate the competitive growth dynamics of the Aitken and accumulation mode particles while the Kelvin effect and coagulation are neglected for simplicity. The timescale of SOA partitioning and evolution of number and composition size distributions are evaluated for a range of solute volatilities (C*), particle-phase bulk diffusivities (Db), and particle-phase reactivity, as exemplified by a pseudo-first-order rate constant (kc). Results show that irreversible condensation of non-volatile organic vapors (equivalent to ) produces significant narrowing of the size distribution. At the other extreme, non-reactive partitioning of semi-volatile organic vapors is volume-controlled in which the final (equilibrium) size distribution simply shifts to the right on the diameter axis while its shape remains unchanged. However, appreciable narrowing of the size distribution may occur when the pre-existing particles are highly viscous semi-solids such that small particles reach quasi-equilibrium much faster than the large ones. In the case of reactive partitioning (finite ), the size distribution experiences permanent narrowing, which is especially pronounced for Db < 10-13 cm2 s-1 and kc > 0.01 s-1. As a result, both number and composition size distributions are needed to effectively constrain and evaluate the next generation of SOA models that treat phase state thermodynamics, particle-phase diffusion and particle-phase chemical reactions.

Zaveri, Rahul A.; Easter, Richard C.; Shilling, John E.; Seinfeld, J. H.

2014-05-27T23:59:59.000Z

66

Volatile organic chemical emissions from carpets. Final report  

SciTech Connect (OSTI)

The primary objective of this research, was to measure the emission rates of selected individual VOC, including low molecular-weight aldehydes, released by samples of four new carpets that are typical of the major types of carpets used in residences, schools and offices. The carpet samples were collected directly from the manufacturers` mills and packaged to preserve their chemical integrity. The measurements of the concentrations and emission rates of these compounds were made under simulated indoor conditions in a 20-M{sup 3} environmental chamber designed specifically for investigations of VOC. The measurements were conducted over a period of one week following the installation of the carpet samples in the chamber. Duplicate experiments were conducted for one carpet. In addition, the concentrations and emission rates of VOC resulting from the installation of a new carpet in a residence were measured over a period of seven weeks. The stabilities of the week-long ventilation rates and temperatures were one percent relative standard deviation. The four carpets emitted a variety of VOC, 40 of which were positively identified. Eight of these were considered to be dominant. They were (in order of chromatographic retention time) formaldehyde, vinyl acetate, 2,2,4-trimethylpentane (isooctane), 1,2-propanediol (propylene glycol), styrene, 2-ethyl-l-hexanol, 4-phenylcyclohexene (4-PCH), and 2,6 di-tert-butyl-4-methylphenol (BHT). With the exception of formaldehyde, only limited data are available on the toxicity and irritancy of these compounds at low concentrations. Therefore, it is difficult to determine at this time the potential magnitude of the health and comfort effects that may occur among the population from exposures to emissions from new carpets. The concentrations and emission rates of most compounds decreased rapidly over the first 12 h of the experiments.

Hodgson, A.T.; Wooley, J.D.; Daisey, J.M.

1992-04-01T23:59:59.000Z

67

The mechanisms and relative importance of abiotic and biological processes for VOC loss from sludge amended soils  

SciTech Connect (OSTI)

The presence of volatile organic compounds (VOCs) in sewage sludge has been a cause of increasing concern due to the possible risk to human health and the environment when sludge is applied to agricultural soils. Sludge application to agricultural land in the UK is expected to increase as a result of restrictions on alternative disposal routes and also increasingly stringent wastewater treatment requirements. Few studies have examined the fate and behavior of VOCs in sewage sludge amended soils and those reported have used spiked sludge rather than investigating the behavior of VOCs resident in the sludge itself. This study was designed to evaluate the behavior of aromatic VOCs (namely toluene, xylene and ethyl benzene) in unspiked sewage sludge amended soils and assess the relative importance and mechanisms of abiotic and biological loss processes. This was undertaken by adding sewage sludge to sterilized and unsterilized soil in closed and open systems. Results indicated that abiotic loss processes, primarily volatilization, were most important for the removal of VOCs. Initial rate of VOC loss was similar in all systems. After 65 days a residual VOC soil concentration remained which was apparently dependent on the conditions within the system.

Wilson, S.C.; Jones, K.C. [Lancaster Univ. (United Kingdom). Inst. of Environmental and Biological Sciences

1994-12-31T23:59:59.000Z

68

CAN SORBENT-BASED GAS PHASE AIR CLEANING FOR VOCS SUBSTITUTE FOR VENTILATION IN COMMERCIAL BUILDINGS?  

SciTech Connect (OSTI)

This paper reviews current knowledge about the suitability of sorbent-based air cleaning for removing volatile organic compounds (VOCs) from the air in commercial buildings, as needed to enable reductions in ventilation rates and associated energy savings. The principles of sorbent air cleaning are introduced, criteria are suggested for sorbent systems that can counteract indoor VOC concentration increases from reduced ventilation, major findings from research on sorbent performance for this application are summarized, and related priority research needs are identified. Major conclusions include: sorbent systems can remove a broad range of VOCs with moderate to high efficiency, sorbent technologies perform effectively when challenged with VOCs at the low concentrations present indoors, and there is a large uncertainty about the lifetime and associated costs of sorbent air cleaning systems when used in commercial buildings for indoor VOC control. Suggested priority research includes: experiments to determine sorbent system VOC removal efficiencies and lifetimes considering the broad range and low concentration of VOCs indoors; evaluations of in-situ regeneration of sorbents; and an updated analysis of the cost of sorbent air cleaning relative to the cost of ventilation.

Fisk, William; Fisk, William J.

2007-08-01T23:59:59.000Z

69

Sorbent-Based Gas Phase Air Cleaning for VOCs in CommercialBuildings  

SciTech Connect (OSTI)

This paper provides a review of current knowledge about the suitability of sorbent-based air cleaning for removing volatile organic compounds (VOCs) from the air in commercial buildings as needed to enable reductions in ventilation rates and associated energy savings. The fundamental principles of sorbent air cleaning are introduced, criteria are suggested for sorbent systems that can counteract indoor VOC concentration increases from reduced ventilation, major findings from research on sorbent performance for this application are summarized, novel sorbent technologies are described, and related priority research needs are identified. Major conclusions include: sorbent systems can remove a broad range of VOCs with moderate to high efficiency, sorbent technologies perform effectively when challenged with VOCs at the low concentrations present indoors, and there is a large uncertainty about the lifetime and associated costs of sorbent air cleaning systems when used in commercial buildings for indoor VOC control. Suggested priority research includes: experiments to determine sorbent system VOC removal efficiencies and lifetimes considering the broad range and low concentration of VOCs indoors; evaluations of in-situ regeneration of sorbents; and an updated analysis of the cost of sorbent air cleaning relative to the cost of ventilation.

Fisk, William J.

2006-05-01T23:59:59.000Z

70

ARTIFACT FORMATION IN HIGH VOLUME SAMPLING OF VOC's AND SOLID ORGANIC COMPOUNDS.  

E-Print Network [OSTI]

when sampling polluted air. Purified air containing 180 ppbv ozone seems to destroy PAH according Atmospheriques, Boite 7059, UNIVERSITE PARIS 7, 2, place Jussieu, 75251 PARIS Cedex 05 ABSTRACT Pollutants from well äs solid (SOC's) organic compounds. High volume samplers are commonly used m air quality

Boyer, Edmond

71

Double Diffusion in Enclosure Bounded by Massive and Volatilizing Walls  

E-Print Network [OSTI]

ICEBO2006, Shenzhen, China Maximize Comfort: Temperature, Humidity and IAQ Vol.I-6-5 Double Diffusion in Enclosure Bounded by Massive and Volatilizing Walls Di Liu Guangfa Tang Fuyun Zhao Doctoral Professor.... INTRODUCTION It has become evident that building products are major contributors to the pollution of the indoor air environment with volatile organic compounds (VOCs) [1]. The indoor airflow and temperature distributions also have influence on the emission...

Liu, D.; Tang, G.; Zhao, F.

2006-01-01T23:59:59.000Z

72

LOW TEMPERATURE VOC COMBUSTION OVER MANGANESE, COBALT AND ZINC ALPO4 MOLECULAR SIEVES  

SciTech Connect (OSTI)

The objective of this project was to prepare microporous aluminophosphates containing magnesium, manganese, cobalt and zinc (MeAPOs) and to evaluate their performance as oxidation catalysts for the removal of low levels of volatile organic compounds (VOCs) from gas streams. The tasks to be accomplished were as follows: (1) To develop reliable synthesis methods for metal aluminophosphates containing manganese, cobalt and zinc in their framework; (2) To characterize these materials for crystallinity, phase purity, the location and nature of the incorporated metal in the framework; and (3) To evaluate the materials for their catalytic activities in the oxidation of volatile organic environmental pollutants.

Rosemarie Szostak

2003-03-06T23:59:59.000Z

73

Refined conceptual model for the Volatile Organic Compounds-Arid Integrated Demonstration and 200 West Area Carbon Tetrachloride Expedited Response Action  

SciTech Connect (OSTI)

This report presents a refined geohydrologic and geochemical conceptual model of the host site (Hanford Reservation) for the Volatile Organic Compounds -- Arid Integrated Demonstration (VOC-Arid ID) and 200 West Area Carbon Tetrachloride (CCl{sub 4}) Expedited Response Action (ERA), based on the results from fiscal year 1992 site characterization activities. The ERA was initiated in December 1990 to minimize or stabilize CCl{sub 4} migration within the unsaturated (vadose) zone in the vicinity of three CCl{sub 4} disposal sites in the 200 West Area (216-Z-1A tile field, 216-Z-9 trench, and 216-Z-18 crib). Implementation of this ERA was based on concerns that CCl{sub 4} residing in the soils was continuing to spread to the groundwater and, if left unchecked, would significantly increase the area of groundwater contamination. A soil-vapor-extraction system began operating at the site in February 1992.

Last, G.V. [Pacific Northwest Lab., Richland, WA (United States); Rohay, V.J. [Westinghouse Hanford Co., Richland, WA (United States)

1993-03-01T23:59:59.000Z

74

Potential VOC Deflagrations in a Vented TRU Drum  

SciTech Connect (OSTI)

The objective of the analysis is to examine the potential for lid ejection from a vented transuranic (TRU) waste drum due to pressure buildup caused by the deflagration of hydrogen and volatile organic compounds (VOCs) inside the drum. In this analysis, the AICC pressure for a stoichiometric mixture of VOCs is calculated and then compared against the experimental peak pressure of stoichiometric combustion of propane and hexane in a combustion chamber. The experimental peak pressures of propane and hexane are about 12 percent lower than the calculated AICC pressure. Additional losses in the drum are calculated due to venting of the gases, drum bulging, waste compaction, and heat losses from the presence of waste in the drum. After accounting for these losses, the final pressures are compared to the minimum observed pressure that ejects the lid from a TRU drum. The ejection pressure of 105 psig is derived from data that was recorded for a series of tests where hydrogen-air mixtures were ignited inside sealed TRU drums. Since the calculated pressures are below the minimum lid ejection pressure, none of the VOCs and the hydrogen (up to 4 percent) mixtures present in the TRU waste drum is expected to cause lid ejection if ignited. The analysis of potential VOC deflagrations in a vented TRU drum can be applied across the DOE-Complex since TRU waste is stored in drums throughout the complex.

Mukesh, GUPTA

2005-04-07T23:59:59.000Z

75

NICS report links VOCs to respiratory problems  

SciTech Connect (OSTI)

Children who live near the chemical plants of Kanawha Valley, WV, suffer more acute and chronic respiratory aliments than those farther away, says a Harvard University School of Public Health report. In the $1-million, five-year study commissioned by the National Institute for Chemical Studies (NICS:Charleston, WV) and funded by the Environmental Protection Agency, proximity to chemical plants that emit volatile organic compounds (VOCs) was linked to higher incidence of asthma, acute eye irritation, shortness of breath, and chronic cough. The researchers say they adjusted for most other factors, such as parental smoking and petroleum. {open_quotes}The research hypothesis was whether children in the valley had more symptoms,{close_quotes} says NICS president Paul Hill. {open_quotes}Yes, there is a difference.{close_quotes} The study showed that some ailments were up to 28% more prevalent in children in the valley than in other Kanawha County children.

Kirschner, E.

1992-04-22T23:59:59.000Z

76

Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135  

SciTech Connect (OSTI)

DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

Michalski, Casey C.; DiSalvo, Rick; Boylan, John [Stoller LMS Team, 11025 Dover Street, Suite 1000, Westminster, CO 80021 (United States)] [Stoller LMS Team, 11025 Dover Street, Suite 1000, Westminster, CO 80021 (United States)

2013-07-01T23:59:59.000Z

77

A Tree's Response to Herbivory: Quantification of Biogenic Volatile Organic Compound Emissions  

E-Print Network [OSTI]

A Tree's Response to Herbivory: Quantification of Biogenic Volatile Organic Compound Emissions an abundant source of Secondary Organic Aerosols (SOA). These emissions are known to vary in quantity and composition due to both biogenic and anthropogenic stressors. In this study, BVOC emissions from bristlecone

Collins, Gary S.

78

Determination of Migration Parameters for Volatile Organic Compounds in Polyethylene Terephthalate and Nylon 6 by Dynamic Permeation Cell Method  

E-Print Network [OSTI]

Determination of Migration Parameters for Volatile Organic Compounds in Polyethylene Terephthalate, such as low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polypropylene (PP); however

Heller, Barbara

79

Thermal engine driven heat pump for recovery of volatile organic compounds  

DOE Patents [OSTI]

The present invention relates to a method and apparatus for separating volatile organic compounds from a stream of process gas. An internal combustion engine drives a plurality of refrigeration systems, an electrical generator and an air compressor. The exhaust of the internal combustion engine drives an inert gas subsystem and a heater for the gas. A water jacket captures waste heat from the internal combustion engine and drives a second heater for the gas and possibly an additional refrigeration system for the supply of chilled water. The refrigeration systems mechanically driven by the internal combustion engine effect the precipitation of volatile organic compounds from the stream of gas.

Drake, Richard L. (Schenectady, NY)

1991-01-01T23:59:59.000Z

80

Comparisons of diffusive and advective fluxes of gas phase volatile organic compounds (VOCs) in unsaturated zones under natural conditions  

E-Print Network [OSTI]

) in unsaturated zones under natural conditions Kehua You a , Hongbin Zhan a,b, a Department of Geology

Zhan, Hongbin

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Volatile organic acids and microbial processes in the Yegua formation, east-central Texas  

E-Print Network [OSTI]

and Geophysics, Texas A&M University, College Station, TX, 77843, USA b Institute for Energy and the EnvironmentVolatile organic acids and microbial processes in the Yegua formation, east-central Texas Joyanto production of VOAs by microorganisms in mudstones, and net consumption of VOAs by SO4 reducing bacteria (SRB

Grossman, Ethan L.

82

Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds  

E-Print Network [OSTI]

1 Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds Hazmat Spill Center, Nevada Test Site September 19-25, 2001 Clifford K. Ho Sandia National Laboratories Albuquerque-filled 55- gallon drum at the Hazmat Spill Center at the Nevada Test Site. Background and Objectives Tens

Ho, Cliff

83

Low-Level Detections of Halogenated Volatile Organic Compounds in Groundwater  

E-Print Network [OSTI]

compounds; Groundwater management; Drinking water. Introduction Approximately one-half of the U and Hitt 2006 , or more complex process-based analyses utilizing groundwater models Eberts et al. 2005Low-Level Detections of Halogenated Volatile Organic Compounds in Groundwater: Use in Vulnerability

84

MEMBRANE INTRODUCTION MASS SPECTROMETRY FOR THE ON-LINE ANALYSIS OF VOLATILE ORGANIC COMPOUNDS IN AQUEOUS SOLUTIONS  

E-Print Network [OSTI]

organic compounds (VOCs) have been detected in urban waters across the United States, including gasoline was partially supported by the NSF-Chemistry CARREER award # CHE-0.34131. #12;v VITA November 4, 1974.S. Pharmaceutical Chemistry, National School of Biological Sciences (Mexico). 2002 ­ 2005

85

Impacts of nitrogen fertilization on volatile organic compound emissions from decomposing plant litter  

E-Print Network [OSTI]

decomposing litter from 12 plant species over 125 days, measuring both CO2 and VOC emissions throughout with C emissions as VOCs ranging from 0% to 88% of C emissions as CO2. Methanol was the dominant VOC was occasionally large enough to account for the increased CO2 emissions on a per unit C basis, suggesting that N

Fierer, Noah

86

Prediction of short-term and long-term VOC emissions from SBR bitumen-backed carpet under different temperatures  

SciTech Connect (OSTI)

This paper presents two models for volatile organic compound (VOC) emissions from carpet. One is a numerical model using the computational fluid dynamics (CFD) technique for short-term predictions, the other an analytical model for long-term predictions. The numerical model can (1) deal with carpets that are not new, (2) calculate the time-dependent VOC distributions in a test chamber or room, and (3) consider the temperature effect on VOC emissions. Based on small-scale chamber data, both models were used to examine the VOC emissions under different temperatures from polypropene styrene-butadiene rubber (SBR) bitumen-backed carpet. The short-term predictions show that the VOC emissions under different temperatures can be modeled solely by changing the carpet diffusion coefficients. A formulation of the Arrhenius relation was used to correlate the dependence of carpet diffusion coefficient with temperature. The long-term predictions show that it would take several years to bake out the VOCs, and temperature would have a major impact on the bake-out time.

Yang, S.; Chen, Q. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Building Technology Program; Bluyssen, P.M. [TNO Building and Construction Research, Delft (Netherlands)

1998-12-31T23:59:59.000Z

87

Monitoring of volatile organic pollutants in groundwater by passive diffusive bags (PDBs) Catherine Berho, Anne Togola, Benjamin  

E-Print Network [OSTI]

on classical water samples. These results highlighted that PDBs allow the measurement of the BTEX and volatileMonitoring of volatile organic pollutants in groundwater by passive diffusive bags (PDBs) Catherine used for groundwater monitoring such as low-flow peristaltic pumps can sample water slowly from wells

Paris-Sud XI, Université de

88

Monitoring Volatile Organic Tank Waste Using Cermet Microsensors  

SciTech Connect (OSTI)

Presently, very few inexpensive technologies exist in the marketplace that can determine the contents of tank waste or monitor the chemistry of tank constituents in near-real time. The research addressed this problem by developing and assessing ceramic-metallic based microsensors for determining the constituents of a liquid organic storage tank by examining the gases in the headspace of the tank. Overall, the WBO and YSZ sensors responded well to the chemicals in this study. Responses to various concentrations were distinguishable visually. This is a clear indication that pattern recognition tools will be effective in resolving the constituents and concentrations. In tests, such as the test with acetophenone, one sensor, the WBO sensor is not extremely effective. However, the other sensor, the YSZ sensor, is effective in resolving the concentrations. This supports the need to use an array of sensors, as one sensor may be reactive to a compound while another may not. In the course of this research, several interesting phenomena surfaced. New sensors, that were fabricated but not used in a contaminant gas, seemed to function more effectively and predictably if a ?conditioning? step was imposed upon them prior to use in square wave voltammetry. A conditioning step consists of running cyclic voltammetry prior to running square wave voltammetry. This step tends to ?cleanse? the sensor surface by providing a full -1.0 V to +1.0V sweep and both oxidizing and reducing compounds on the sensor surface. [Note: squarewave voltammetry will simply oxidize or reduce compounds ? it will not induce both reactions.] This sweep is essential for recovery between samples.

Edward G. Gatliff, Ph.D.; Laura R. Skubal, Ph.D.; Michael C. Vogt, Ph.D.

2006-03-13T23:59:59.000Z

89

Performance specifications for technology development: Application for characterization of volatile organic compounds in the environment  

SciTech Connect (OSTI)

This report contains information about technology development for the monitoring and remediation of environmental pollution caused by the release of volatile organic compounds. Topics discussed include: performance specification processes, gas chromatography, mass spectrometer, fiber-optic chemical sensors, infrared spectroscopy, Raman spectroscopy, piezoelectric sensors and electrochemical sensors. These methods are analyzed for their cost efficiency, accuracy, and the ability to meet the needs of the customer.

Carpenter, S.E.; Doskey, P.V.; Erickson, M.D.; Lindahl, P.C.

1994-07-01T23:59:59.000Z

90

Removal of hydrophobic Volatile Organic Compounds1 in an integrated process coupling Absorption and2  

E-Print Network [OSTI]

technology like photochemical oxidation shows high efficiency70 but is also high energy-consuming; moreover processes involve water as absorbent, they appear not always really efficient for the treatment of24 of the process, hydrophobic VOC27 absorption in a gas-liquid contactor, and biodegradation in the TPPB. VOC

Boyer, Edmond

91

CONTRIBUTION OF SEMI-VOLATILE ORGANIC MATERIAL TO AMBIENT PM2.5  

SciTech Connect (OSTI)

Both annual 24-h average and seasonal diurnal samples collected at NETL during the research program have been analyzed. The fine particulate components determined include PM{sub 2.5} mass, ammonium sulfate, ammonium nitrate, elemental and organic carbonaceous material and trace elements. The analysis of the nitrate and organic material includes both the identification of nonvolatile material retained by the particle collection filter and semi-volatile material lost from the particles during sample collection. The results obtained in these analyses indicate that both the semivolatile and nonvolatile organic material in the fine particles sampled at the NETL site originate from mobile emissions in the local area. However, the majority of the nonvolatile material is associated with primary emissions and the majority of the semi-volatile material is secondary, being formed from photochemical processes in the atmosphere. In contrast, the fine particulate sulfate does not originate from the local area but is transported into the study region, mostly from sources in the Ohio River Valley. These observations have been supported by both detailed meteorological and apportionment analysis of the data.

Delbert J. Eatough; William K. Modey; Rebecca Sizemore; Michael Simpson

2004-04-01T23:59:59.000Z

92

Volatile tritiated organic acids in stack effluents and in air surrounding contaminated materials  

SciTech Connect (OSTI)

A small fraction of the tritium released into the atmosphere from tritium-handling or solid waste storage facilities was shown to be in the form of volatile organic acids. The same compounds were also found, but at a much higher proportion, in the tritium evolved at room temperature from highly contaminated materials placed under air atmospheres. This might be due to the oxidation and labeling of hydrocarbon(s) by mechanisms that are presumably of a radiolytic nature. The new forms could have an impact on operational requirements and waste management strategies within a tritium facility and a fusion reactor hall. Further data are needed to assess the related doses.

Belot, Y.; Camus, H.; Marini, T.; Raviart, S. (Institut de Protection et de Surete Nucleaire (France))

1993-06-01T23:59:59.000Z

93

In situ treatment of VOCs by recirculation technologies  

SciTech Connect (OSTI)

The project described herein was conducted by Oak Ridge National Laboratory (ORNL) to identify processes and technologies developed in Germany that appeared to have near-term potential for enhancing the cleanup of volatile organic compound (VOC) contaminated soil and groundwater at DOE sites. Members of the ORNL research team identified and evaluated selected German technologies developed at or in association with the University of Karlsruhe (UoK) for in situ treatment of VOC contaminated soils and groundwater. Project activities included contacts with researchers within three departments of the UoK (i.e., Applied Geology, Hydromechanics, and Soil and Foundation Engineering) during fall 1991 and subsequent visits to UoK and private industry collaborators during February 1992. Subsequent analyses consisted of engineering computations, groundwater flow modeling, and treatment process modeling. As a result of these project efforts, two processes were identified as having near-term potential for DOE: (1) the vacuum vaporizer well/groundwater recirculation well and (2) the porous pipe/horizontal well. This document was prepared to summarize the methods and results of the assessment activities completed during the initial year of the project. The project is still ongoing, so not all facets of the effort are completely described in this document. Recommendations for laboratory and field experiments are provided.

Siegrist, R.L.; Webb, O.F.; Ally, M.R.; Sanford, W.E. [Oak Ridge National Lab., TN (US); Kearl, P.M.; Zutman, J.L. [Oak Ridge National Lab., Grand Junction, CO (US)

1993-06-01T23:59:59.000Z

94

Subtask 1.15-Passive Diffusion Sample Bags Made from Expanded Polytetrafluorethylene (ePTFE) to Measure VOC Concentrations in Groundwater  

SciTech Connect (OSTI)

With laboratory testing of expanded polytetrafluoroethylene (ePTFE) membranes complete, collected data support that volatile organic compound (VOC) molecules will readily diffuse across ePTFE membranes. Membrane samples, supplied by BHA Technologies (GE Osmonics), were tested to determine diffusion rates for VOCs in groundwater. Tests were conducted using membranes with two different pore sizes, with and without thermally laminated spun bond backing, and multiple concentrations of contaminated groundwater. Results suggest that typical residence times associated with traditional samplers constructed of polyethylene (2 weeks) can be reduced by 1 week using ePTFE membranes (reducing project costs) and that VOCs will diffuse more readily at lower temperatures (2.2-3.3 C) across ePTFE materials.

Barry W. Botnen

2006-08-01T23:59:59.000Z

95

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect (OSTI)

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

96

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect (OSTI)

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

97

Assessment of subsurface VOCs using a chemical microsensor array. Final report  

SciTech Connect (OSTI)

This report describes the results of laboratory investigations of several performance parameters relevant to surface-acoustic-wave (SAW) chemical sensor arrays for the measurement of volatile organic compounds (VOCs) in contaminated soil and groundwater. The small size, low cost, sensitivity and selectivity of such instruments promise improvements in the quality and quantity of data used to guide site assessment and restoration efforts. In this investigation, calibrations were performed for 15 different coated SAW sensors. Each sensor was exposed to six VOCs selected to represent three chemical classes of contaminants that are commonly found at waste sites (i.e., aliphatic, aromatic and chlorinated hydrocarbons). A new pattern recognition method was developed for determining which coated sensors would maximize the selectivity and accuracy of quantitation for a given set of vapor contaminants. Using this method, an optimal subwet of four coated sensors was selected for testing in a prototype microsensor instrument. Additional laboratory experiments were performed with this optimized array to assess the limits of detection and linear response ranges for the representative vapors, as well as the additivity of responses to vapors in binary mixtures, temperature and humidity effects, aging effects, and other performance parameters related to the application of this technology to soil and groundwater VOC monitoring. Results demonstrate that SAW microsensor arrays can identify and quantify specific VOCs at concentrations in the {mu}g/L to mg/L range when present alone or in simple (e.g., binary) mixtures. SAW sensor technology offers a potentially effective alternative to existing field instrumentation for headspace analysis, soil vapor monitoring, and vacuum extraction process monitoring of VOCs in subsurface media.

Batterman, S.A.; Zellers, E.T. [Michigan Univ., Ann Arbor, MI (United States). School of Public Health

1993-06-01T23:59:59.000Z

98

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS: THE NEW X-WAND HVOC SCREENING DEVICE  

SciTech Connect (OSTI)

Western Research Institute (WRI) has developed new methodology and a test kit to screen soil or water samples for halogenated volatile organic compounds (HVOCs) in the field. The technology has been designated the X-Wand{trademark} screening tool. The new device uses a heated diode sensor that is commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. This sensor is selective to halogens. It does not respond to volatile aromatic hydrocarbons, such as those in gasoline, and it is not affected by high humidity. In the current work, the heated diode leak detectors were modified further to provide units with rapid response and enhanced sensitivity. The limit of detection for trichloroethylene TCE in air is 0.1 mg/m{sup 3} (S/N = 2). The response to other HVOCS relative to TCE is similar. Variability between sensors and changes in a particular sensor over time can be compensated for by normalizing sensor readings to a maximum sensor reading at 1,000 mg/m{sup 3} TCE. The soil TCE screening method was expanded to include application to water samples. Assuming complete vaporization, the detection limit for TCE in soil is about 1 ug/kg (ppb) for a 25-g sample in an 8-oz jar. The detection limit for TCE in water is about 1 ug/L (ppb) for a 25-mL sample in an 8-oz jar. This is comparable to quantitation limits of EPA GC/MS laboratory methods. A draft ASTM method for screening TCE contaminated soils using a heated diode sensor was successfully submitted for concurrent main committee and subcommittee balloting in ASTM Committee D 34 on Waste Management. The method was approved as ASTM D 7203-05, Standard Test Method for Screening Trichloroethylene (TCE)-Contaminated Soil Using a Heated Diode Sensor.

John F. Schabron; Susan S. Sorini; Joseph F. Rovani Jr

2006-03-01T23:59:59.000Z

99

Temperature dependence of volatile organic compound evaporative emissions from motor vehicles  

E-Print Network [OSTI]

gasoline samples collected at Sacramento area service stations. Vapor-liquid equilibrium relationships were summer 2001. Additional gasoline- related VOC emissions not shown in Figure 1 occur at service stations gasoline permeation through rubber and plastic components of the fuel system. [3] EMFAC [California Air

Silver, Whendee

100

Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 4, Organic methods  

SciTech Connect (OSTI)

This interim notice covers the following: extractable organic halides in solids, total organic halides, analysis by gas chromatography/Fourier transform-infrared spectroscopy, hexadecane extracts for volatile organic compounds, GC/MS analysis of VOCs, GC/MS analysis of methanol extracts of cryogenic vapor samples, screening of semivolatile organic extracts, GPC cleanup for semivolatiles, sample preparation for GC/MS for semi-VOCs, analysis for pesticides/PCBs by GC with electron capture detection, sample preparation for pesticides/PCBs in water and soil sediment, report preparation, Florisil column cleanup for pesticide/PCBs, silica gel and acid-base partition cleanup of samples for semi-VOCs, concentrate acid wash cleanup, carbon determination in solids using Coulometrics` CO{sub 2} coulometer, determination of total carbon/total organic carbon/total inorganic carbon in radioactive liquids/soils/sludges by hot persulfate method, analysis of solids for carbonates using Coulometrics` Model 5011 coulometer, and soxhlet extraction.

Not Available

1993-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Volatilization of selected organic compounds from a creosote-waste land-treatment facility. Master's thesis  

SciTech Connect (OSTI)

The purpose of this research was to evaluate the emissions of volatile and semi-volatile compounds which are constituents of a complex creosote waste from laboratory simulations of a land treatment system to assess the potential human exposure to hazardous compounds from this source. In addition, the Thibodeaux-Hwang Air Emission Release Rate (AERR) model was evaluated for its use in predicting emission rates of hazardous constituents of creosote wood preservative waste from land treatment facilities. A group of hazardous volatile and semi-volatile constituents present in the creosote waste was selected for evaluation in this study and included a variety of polynuclear aromatic hydrocarbons (PNA's), phenol, and chlorinated and substituted phenols.

Scott, E.J.

1989-01-01T23:59:59.000Z

102

Recent VOC Control Test Data for a Reactive VOC Converter- Scrubber System for Non-Thermal Control of VOCs  

E-Print Network [OSTI]

of real estate. Non-thermal VOHAP (Volatile Organic Hazardous Air Pollutant) emission control devices require additional maintenance. They also require the replacement of costly consumables such as activated carbon or they use large amounts of energy...

McGinness, M.

103

A Pilot Study of the Effectiveness of Indoor Plants for Removal of Volatile Organic Compounds in Indoor Air in a Seven-Story Office Building  

SciTech Connect (OSTI)

The Paharpur Business Centre and Software Technology Incubator Park (PBC) is a 7 story, 50,400 ft{sup 2} office building located near Nehru Place in New Delhi India. The occupancy of the building at full normal operations is about 500 people. The building management philosophy embodies innovation in energy efficiency while providing full service and a comfortable, safe, healthy environment to the occupants. Provision of excellent Indoor Air Quality (IAQ) is an expressed goal of the facility, and the management has gone to great lengths to achieve it. This is particularly challenging in New Delhi, where ambient urban pollution levels rank among the worst on the planet. The approach to provide good IAQ in the building includes a range of technical elements: air washing and filtration of ventilation intake air from rooftop air handler, the use of an enclosed rooftop greenhouse with a high density of potted plants as a bio-filtration system, dedicated secondary HVAC/air handling units on each floor with re-circulating high efficiency filtration and UVC treatment of the heat exchanger coils, additional potted plants for bio-filtration on each floor, and a final exhaust via the restrooms located at each floor. The conditioned building exhaust air is passed through an energy recovery wheel and chemisorbent cartridge, transferring some heat to the incoming air to increase the HVAC energy efficiency. The management uses 'green' cleaning products exclusively in the building. Flooring is a combination of stone, tile and 'zero VOC' carpeting. Wood trim and finish appears to be primarily of solid sawn materials, with very little evidence of composite wood products. Furniture is likewise in large proportion constructed from solid wood materials. The overall impression is that of a very clean and well-kept facility. Surfaces are polished to a high sheen, probably with wax products. There was an odor of urinal cake in the restrooms. Smoking is not allowed in the building. The plants used in the rooftop greenhouse and on the floors were made up of a number of species selected for the following functions: daytime metabolic carbon dioxide (CO{sub 2}) absorption, nighttime metabolic CO{sub 2} absorption, and volatile organic compound (VOC) and inorganic gas absorption/removal for air cleaning. The building contains a reported 910 indoor plants. Daytime metabolic species reported by the PBC include Areca Palm, Oxycardium, Rubber Plant, and Ficus alii totaling 188 plants (21%). The single nighttime metabolic species is the Sansevieria with a total of 28 plants (3%). The 'air cleaning' plant species reported by the PBC include the Money Plant, Aglaonema, Dracaena Warneckii, Bamboo Palm, and Raphis Palm with a total of 694 plants (76%). The plants in the greenhouse (Areca Palm, Rubber Plant, Ficus alii, Bamboo Palm, and Raphis Palm) numbering 161 (18%) of those in the building are grown hydroponically, with the room air blown by fan across the plant root zones. The plants on the building floors are grown in pots and are located on floors 1-6. We conducted a one-day monitoring session in the PBC on January 1, 2010. The date of the study was based on availability of the measurement equipment that the researchers had shipped from Lawrence Berkeley National Lab in the U.S.A. The study date was not optimal because a large proportion of the regular building occupants were not present being New Year's Day. An estimated 40 people were present in the building all day during January 1. This being said, the building systems were in normal operations, including the air handlers and other HVAC components. The study was focused primarily on measurements in the Greenhouse and 3rd and 5th floor environments as well as rooftop outdoors. Measurements included a set of volatile organic compounds (VOCs) and aldehydes, with a more limited set of observations of indoor and outdoor particulate and carbon dioxide concentrations. Continuous measurements of Temperature (T) and relative humidity (RH) were made selected indoor and outdoor locations.

Apte, Michael G.; Apte, Joshua S.

2010-04-27T23:59:59.000Z

104

A theoretical study of discrete air phase migration contaminated with a volatile organic  

E-Print Network [OSTI]

saturated porous media, while the second part presents volatile contaminant transport in bubbly air flow. The first part of the study is developed in order to determine bubble rise velocity in four flow regimes i.e., steady state, quasi-steady state...

Drazenovic, Mirna

1997-01-01T23:59:59.000Z

105

Infrared Spectroscopy of Wild 2 Particle Hypervelocity Tracks in Stardust Aerogel: Evidence for the presence of Volatile Organics in Comet Dust  

SciTech Connect (OSTI)

Infrared spectroscopy maps of some tracks, made by cometary dust from 81P/Wild 2 impacting Stardust aerogel, reveal an interesting distribution of volatile organic material. Out of six examined tracks three show presence of volatile organic components possibly injected into the aerogel during particle impacts. When particle tracks contained excess volatile organic material, they were found to be -CH{sub 2}-rich. Off-normal particle tracks could indicate impacts by lower velocity particles that could have bounced off the Whipple shield, therefore carry off some contamination from it. However, this theory is not supported by data that show excess organic-rich material in normal and off-normal particle tracks. It is clear that the population of cometary particles impacting the Stardust aerogel collectors also include grains that contained little or none of this volatile organic component. This observation is consistent with the highly heterogeneous nature of the collected grains, as seen by a multitude of other analytical techniques. We propose that at least some of the volatile organic material might be of cometary origin based on supporting data shown in this paper. However, we also acknowledge the presence of carbon (primarily as -CH{sub 3}) in the original aerogel, which complicates interpretation of these results.

Bajt, S; Sandford, S A; Flynn, G J; Matrajt, G; Snead, C J; Westphal, A J; Bradley, J P

2007-08-28T23:59:59.000Z

106

In situ treatment of VOCs by recirculation technologies  

SciTech Connect (OSTI)

Confronted with contaminated land from the world wars and the postwar industrialization period, German researchers and practicing professionals have worked to develop processes for effective environmental restoration. This presentation documents efforts by Oak Ridge National Laboratory (ORNL) researchers to (1) identify collaborators and German technologies exhibiting near-term potential for clean-up of volatile organic contaminated soil and groundwater at Department of Energy sites, (2) critically assess performance, and (3) inform interested agencies. The project was limited to identification and preliminary evaluation and included engineering computations, groundwater flow modeling, and treatment process modeling. Two processes were identified: (1) the vacuum vaporizer well/groundwater recirculation well and (2) the porous pipe/horizontal well (PP/HW). Both technologies induce a recirculation flow field in the aquifer and enable simultaneous down hole treatment of the aquifer and vadose zone. University of Karlsruhe researchers have demonstrated the UVB/GZB technology in shallow aquifers with moderately high saturated thickness and hydraulic conductivities. The PP/HW technology offers potential for VOC treatment in sites with thin aquifers or heterogeneities. This paper describes identified German technologies and includes critical evaluations of well performance, associated treatment processes, operating variables, and aquifer-well interactions.

Webb, O.F.; Siegrist, R.L.; Ally, M.R.; Sanford, W.E. [Oak Ridge National Lab., TN (United States); Kearl, P.M.; Zutman, J.L. [Oak Ridge National Lab., Grand Junction, CO (United States). Environmental Science Div.

1994-06-01T23:59:59.000Z

107

Adsorption -capacity data for 283 organic compounds  

SciTech Connect (OSTI)

Adsorption on activated carbon is a widely used method for removing volatile organic compounds (VOCs) from gases and other exhaust streams. This article presents a compilation of adsorption-capacity data as a function of the VOC concentration in the gas. The results are useful in engineering and environmental studies, and in the design of carbon-based adsorption systems to remove unwanted organic pollutants from gases. For vapor control, carbon-based systems typically combine a carbon-adsorption unit with a secondary control method to reclaim or destroy the vapors desorbed during carbon-bed regeneration. To remove organics dissolved in wastewater, air stripping is typically used to transfer the organics to a vapor stream. Carbon adsorption is then used to separate the organics from the stripper exhaust. Collected vapors can be recovered for reuse or destroyed, depending on their value.

Yaws, C.L.; Bu, L.; Nijhawan, S. [Lamar Univ., Beaumont, TX (United States)

1995-05-01T23:59:59.000Z

108

Use of sonication for in-well softening of semivolatile organic compounds. 1997 annual progress report  

SciTech Connect (OSTI)

'This project investigates the in-situ degradation of semivolatile organic compounds (SVOCs) and volatile organic compounds (VOCs) using in-well sonication, in-well vapor stripping, and bioremediation. Pretreating groundwaters with sonication techniques in-situ would form VOCs that can be effectively removed by in-well vapor stripping and bioremediation. The mechanistic studies focus on the coupling of megasonics and ultrasonics to soften (i.e., partially degrade) the SVOCs; oxidative reaction mechanism studies; surface corrosion studies (on the reactor walls/well); enhancement due to addition of oxidants, quantification of the hydroxyl radical formation; identification/quantification of degradation products; volatility/degradability of the treated waters; development of a computer simulation model to describe combined in-well sonication/in-well vapor stripping/bioremediation; systems analysis/economic analysis; large laboratory-scale experiment verification; and field demonstration of the integrated technology. Benefits of this approach include: (1) Remediation is performed in-situ; (2) The treatment systems complement each other; their combination can drastically reduce or remove SVOCs and VOCs; (3) Ability to convert hard-to-degrade organics into more volatile organic compounds; (4) Ability to remove residual VOCs and softened SVOCs through the combined action of in-well vapor stripping and biodegradation; (5) Does not require handling or disposing of water at the ground surface; and (6) Cost-effective and improved efficiency, resulting in shortened clean-up times to remediate a site.'

Peters, R.W.; Manning, J. [Argonne National Lab., IL (US); Hoffman, M.R. [California Inst. of Tech., Pasadena, CA (US); Gorelick, S. [Stanford Univ., CA (US)

1997-01-01T23:59:59.000Z

109

Estimated monthly emissions of sulfur dioxide, oxides of nitrogen, and volatile organic compounds for the 48 contiguous states, 1985-1986: Volume 2, Sectoral emissions by month for states  

SciTech Connect (OSTI)

A listing by source of sulfur dioxide, nitrogen oxides and volatile organic compounds emitted in 48 states of the US is provided. (CBS)

Kohout, E.J.; Knudson, D.A.; Saricks, C.L.; Miller, D.J.

1987-11-01T23:59:59.000Z

110

VOC recovery using microwave regeneration of adsorbents: Pilot-column studies  

SciTech Connect (OSTI)

A pilot-scale column was constructed to evaluate the technical feasibility of microwave (MW) heating as a means of regenerating adsorbents for recovery of volatile organic compounds (VOCs). The 6 inch diameter moving-bed column, which has a throughput capacity of 200 lb/hr of adsorbent, is representative of a full-scale component of a small-capacity recovery system or a single element of a large-capacity system. Regeneration experiments were conducted to study the effects of key process variables, including adsorbent and stripping gas feed rates, initial adsorbent coverage and microwave power input, on column performance. Two adsorbents with contrasting dielectric loss characteristics were studied, Dowex Optipore L502 (low dielectric loss styrene-based) and Rohm and Haas Ambersorb 600 (moderate dielectric loss carbonaceous). Adsorbates included polar and nonpolar compounds: isopropyl alcohol (iPA), methyl ethyl ketone (MEK) and toluene. Solvent recovery rates of 20--30 lbs/hr were achieved. The results of the pilot-column experiments demonstrate that axial temperature and desorption profiles are dependent on the dielectric characteristics of the adsorbent/sorbate pair, and that final regeneration coverage can be correlated with a dimensionless stripping gas ratio and final adsorbent temperature. Implications for design of microwave-regenerated VOC recovery systems are discussed.

Salinas, M.J.; Price, D.W.; Schmidt, P.S.

1999-07-01T23:59:59.000Z

111

Composites for removing metals and volatile organic compounds and method thereof  

SciTech Connect (OSTI)

Functionalized hydrophobic aerogel/solid support structure composites have been developed to remove metals and organic compounds from aqueous and vapor media. The targeted metals and organics are removed by passing the aqueous or vapor phase through the composite which can be in molded, granular, or powder form. The composites adsorb the metals and the organics leaving a purified aqueous or vapor stream. The species-specific adsorption occurs through specific functionalization of the aerogels tailored towards specific metals and/or organics. After adsorption, the composites can be disposed of or the targeted metals and/or organics can be reclaimed or removed and the composites recycled.

Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Reynolds, John G. (San Ramon, CA)

2006-12-12T23:59:59.000Z

112

Observations of nonmethane hydrocarbons and oxygenated volatile organic compounds at a rural site in the southeastern United States  

SciTech Connect (OSTI)

Measurements of an extensive range of nonmethane hydrocarbons (NMHCs) including alkanes, alkenes, and aromatics, and oxygenated volatile organic compounds (OVOCs) including alcohols, ketones, and aldehydes were conducted for several weeks during the summer of 1995 as part of the Southern Oxidants Study (SOS) at a rural experimental site (Youth, Inc.) 32 km southeast of Nashville, Tennessee, in the southeastern United States. These measurements were conducted to (1) determine the absolute magnitude and variability of oxygenated compounds found in a contemporary rural region; (2) assess the importance of the measured ambient levels of OVOCs on a photochemical reactivity basis relative to the more commonly determined NMHCs; and (3) to evaluate our ability to accurately measure oxygenates by the current techniques employed under a field study scenario. Several other physical (temperature, insolation, etc.), meteorological (wind velocity, wind direction, atmospheric structure, and boundary layer height), and chemical (criterion pollutants, NO{sub x}, SO{sub 2}, CO, O{sub 3}, etc.) parameters were measured concurrently with the NMHC and OVOC measurements. During the study period, OVOCs were consistently the dominant compounds present, and methanol and acetone had the highest mixing ratios. Although OVOCs made up the majority of the volatile organic compound component on a mass basis, a substantial sink for OH was isoprene and its immediate oxidation products, methacrolein and methyl vinyl ketone. In combination with CO and formaldehyde, these compounds comprised about 85{percent} of the observed OH reactivity at the site. Acetaldehyde and methanol were responsible for an additional 10{percent}, with the NMHCs and remaining OVOCs making up the final 5{percent} of the measured OH reactivity at the site. These observed patterns reinforce recent studies which find OVOCs to be an important component of the rural troposphere. {copyright} 1998 American Geophysical Union

Riemer, Daniel; Pos, Willer; Milne, Peter; Farmer, Charlesk; Zika, Rod [Division of Marine and Atmospheric Chemistry, Rosenstiel School of Marine and Atmospheric Science, University of Miami, Miami, Florida (United States)] [Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, Colorado (United States)] [Atmospheric Sciences, Tennessee Valley Authority, Muscle Shoals, Alabama (United States)] Apel, Eric [Atmospheric Chemistry Group, Mantech Environmental Research Triangle Park, North Carolina (United States)] Olszyna, Ken [National Environmental Research Laboratory, U.S. EPA. Research Triangle Park, North Carolina (United States)] Kliendienst, Tad [Department of Chemistry, Western Michigan University, Kalamazoo, Michigan (United States)] Lonneman, William [Departments of Chemistry, and Earth and Atmospheric Science, Purdue University, West Lafayette, Indiana (United States); Shepson, Paul; Starn, Tim

1998-11-01T23:59:59.000Z

113

Carbon tetrachloride contamination, 200 West Area, Hanford Site: Arid Site Integrated Demonstration for remediation of volatile organic compounds  

SciTech Connect (OSTI)

The Arid State Integrated Demonstration is a US Department of Energy (DOE) program targeted at the acquisition, development, demonstration, and deployment of technologies for evaluation and cleanup of volatile organic and associated contaminants in soils and ground waters. Several DOE laboratories, universities, and industry will participate in the program. Candidate technologies will be demonstrated in the areas of site characterization; performance prediction, monitoring, and evaluations; contaminant extraction and ex situ treatment; in situ remediations; and site closure and monitoring. The performance of these demonstrated technologies will be compared to baseline technologies and documented to promote the transfer of new technologies to industry for use at DOE facilities. The initial host site is the Hanford Site's 200 West Area. The location of the demonstration contains primarily carbon tetrachloride (CCl{sub 4}), chloroform, and a variety of associated mixed waste contaminants. Chemical processes used to recover and purify plutonium at Hanford's plutonium finishing plant (Z Plant) resulted in the production of actinide-bearing waste liquid. Both aqueous and organic liquid wastes were generated, and were routinely discharged to subsurface disposal facilities. The primary radionuclide in the waste streams was plutonium, and the primary organic was CCl{sub 4}. This paper contains brief descriptions of the principal CCl{sub 4} waste disposal facilities in Hanford's 200 West Area, associated hydrogeology, existing information on the extent of soil and ground-water contamination, and a conceptual outline of suspected subsurface CCl{sub 4} distributions.

Last, G.V. (Pacific Northwest Lab., Richland, WA (United States)); Rohay, V.J. (Westinghouse Hanford Co., Richland, WA (United States))

1991-05-06T23:59:59.000Z

114

Carbon tetrachloride contamination, 200 West Area, Hanford Site: Arid Site Integrated Demonstration for remediation of volatile organic compounds  

SciTech Connect (OSTI)

The Arid State Integrated Demonstration is a US Department of Energy (DOE) program targeted at the acquisition, development, demonstration, and deployment of technologies for evaluation and cleanup of volatile organic and associated contaminants in soils and ground waters. Several DOE laboratories, universities, and industry will participate in the program. Candidate technologies will be demonstrated in the areas of site characterization; performance prediction, monitoring, and evaluations; contaminant extraction and ex situ treatment; in situ remediations; and site closure and monitoring. The performance of these demonstrated technologies will be compared to baseline technologies and documented to promote the transfer of new technologies to industry for use at DOE facilities. The initial host site is the Hanford Site`s 200 West Area. The location of the demonstration contains primarily carbon tetrachloride (CCl{sub 4}), chloroform, and a variety of associated mixed waste contaminants. Chemical processes used to recover and purify plutonium at Hanford`s plutonium finishing plant (Z Plant) resulted in the production of actinide-bearing waste liquid. Both aqueous and organic liquid wastes were generated, and were routinely discharged to subsurface disposal facilities. The primary radionuclide in the waste streams was plutonium, and the primary organic was CCl{sub 4}. This paper contains brief descriptions of the principal CCl{sub 4} waste disposal facilities in Hanford`s 200 West Area, associated hydrogeology, existing information on the extent of soil and ground-water contamination, and a conceptual outline of suspected subsurface CCl{sub 4} distributions.

Last, G.V. [Pacific Northwest Lab., Richland, WA (United States); Rohay, V.J. [Westinghouse Hanford Co., Richland, WA (United States)

1991-05-06T23:59:59.000Z

115

Occurrence and Potential Human-Health Relevance of Volatile Organic Compounds in Drinking Water from Domestic Wells in the United States  

E-Print Network [OSTI]

Occurrence and Potential Human-Health Relevance of Volatile Organic Compounds in Drinking Water from Domestic Wells in the United States *Barbara L. Rowe1 , Patricia L. Toccalino2 , Michael J. Moran1 , John S. Zogorski1 , Curtis V. Price1 1 United States Geological Survey, Road, Rapid City, SD 57702 USA

116

Communication accepte: Healthy Buildings/IAQ'97 Washington DC, septembre 1997Communication accepte: Healthy Buildings/IAQ'97 Washington DC, septembre 1997 DISCRIMINATION OF VOLATILE ORGANIC COMPOUNDS  

E-Print Network [OSTI]

Communication acceptée: Healthy Buildings/IAQ'97 Washington DC, septembre 1997Communication acceptée: Healthy Buildings/IAQ'97 Washington DC, septembre 1997 DISCRIMINATION OF VOLATILE ORGANIC manuscript, published in "4th International Conference on Healthy Buildings'97, Washington : United States

Paris-Sud XI, Université de

117

Effect of moisture on air stripping of non volatile organic contaminants from soil  

E-Print Network [OSTI]

, a fluid phase and a solid phase, similar to the one used for packed bed adsorbers. Mass transfer between the phases was assumed to be controlled by sorption, with first order surface kinetics describing the change of contaminant concentration... . B. Objectives . . Page 1 2 A. Soil Composition and Interaction with Organic Compounds . . B. Effect of Soil Moisture on Contaminant Transport . C. Mathematical Modeling of Contaminant Transport in Soil . D. Air Stripping of Organic...

Alvarez, Roberto

1991-01-01T23:59:59.000Z

118

Volatile organic acids and microbial processes in the Yegua formation, east-central Texas  

E-Print Network [OSTI]

transported into the aquifer (3.2 µmol·l-1·m·a-1), the CO2 production rate in the aquifer sands is 5.3 µmol·l-1·m·a-1. This slow mineralization rate of in situ organic matter is within the range for deep aquifers, and probably accounts for the long...

Routh, J.; Grossman, E. L.; Ulrich, G. A.; Suflita, J. M.

2000-01-01T23:59:59.000Z

119

4, 66916718, 2004 VOC emissions of  

E-Print Network [OSTI]

ACPD 4, 6691­6718, 2004 VOC emissions of Scots pine V. Tarvainen et al. Title Page Abstract Discussions Temperature and light dependence of the VOC emissions of Scots pine V. Tarvainen 1 , H. Hakola 1.tarvainen@fmi.fi) 6691 #12;ACPD 4, 6691­6718, 2004 VOC emissions of Scots pine V. Tarvainen et al. Title Page Abstract

Paris-Sud XI, Université de

120

Emissions of volatile organic compounds from stationary combustion sources: Numerical modeling capabilities  

SciTech Connect (OSTI)

A collaborative research program initiated to study the emissions of a wide variety of chemical species from stationary combustion systems. These product species have been included in the Clean Air act legislation and their emissions must be rigidly controlled, but there is a need for much better understanding of the physical and chemical mechanisms that produce and consume them. We are using numerical modeling study the chemical reactions and fluid mechanical factors that occur in industrial processes: we are examining systems including premixed and diffusion flames, stirred reactors and plug flow reactors in these modeling studies to establish the major factors leading to emissions of these chemicals. In addition, we are applying advanced laser diagnostic techniques to validate the model predictions and to study the possibilities of developing sophisticated sensors to detect emissions of undesirable species in real time. This paper will discuss the organization of this collaborative effort and its results to date.

Seebold, J.G. [Chevron Research and Technology Co., Richmond, CA (United States); Kee, R.J.; Lutz, A.J. [Sandia National Labs., Albuquerque, NM (United States); Pitz, W.J.; Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States); Senkan, S. [California Univ., Los Angeles, CA (United States)

1992-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

A novel Whole Air Sample Profiler (WASP) for the quantification of volatile organic compounds in the boundary layer  

SciTech Connect (OSTI)

The emission and fate of reactive VOCs is of inherent interest to those studying chemical biosphere-atmosphere interactions. In-canopy VOC observations are obtainable using tower-based samplers, but the lack of suitable sampling systems for the full boundary 5 layer has limited the data characterizing the vertical structure of such gases above the canopy height and still in the boundary layer. This is the important region where many reactive VOCs are oxidized or otherwise removed. Here we describe an airborne sampling system designed to collect a vertical profile of air into a 3/800 OD tube 150m in length. The inlet ram air pressure is used to flow sampled air through the 10 tube, which results in a varying flow rate based on aircraft speed and altitude. Since aircraft velocity decreases during ascent, it is necessary to account for the variable flow rate into the tube. This is accomplished using a reference gas that is pulsed into the air stream so that the precise altitude of the collected air can be reconstructed post-collection. The pulsed injections are also used to determine any significant effect 15 from diffusion/mixing within the sampling tube, either during collection or subsequent extraction for gas analysis. This system has been successfully deployed, and we show some measured vertical profiles of isoprene and its oxidation products methacrolein and methyl vinyl ketone from a mixed canopy near Columbia, Missouri.

Mak, J. E.; Su, L.; Guenther, Alex B.; Karl, Thomas G.

2013-10-16T23:59:59.000Z

122

A Novel New Approach to VOC and HAP Emission Control  

E-Print Network [OSTI]

of real estate. Non-thermal VOHAP (Volatile Organic Hazardous Air Pollutant) emission control devices require additional maintenance. They also require the replacement of costly consumables such as activated carbon or they use large amounts of energy...

McGinness, M.

123

Prediction of risk-based screening levels for infiltration of volatile subsurface contaminants into buildings  

SciTech Connect (OSTI)

A Risk-Based Corrective Action (RBCA) approach is increasingly being used for the management of contaminated sites. Fundamental to this approach is the prediction of risk-based screening levels (RBSL) for operable exposure pathways. Screening level models currently used indicate that RBSLs for the indoor inhalation pathway can be significantly lower than other pathways typically considered. This paper presents the results of a screening level spreadsheet model used to predict human health risks resulting from infiltration of volatile organic compounds (VOCs) into buildings. The model was developed to derive RBSLs for soil and groundwater for possible future incorporation into the regulation of contaminated sites in British Columbia. Key features of the semi-analytical VOC infiltration model are steady-state diffusive mass transfer through soil coupled with advective and diffusive mass transfer through a cracked building floor slab or wall, source mass depletion of soil contaminants present using a mass balance approach, and the capability to incorporate multi-component chemical partitioning for soils containing non-aqueous phase liquid (NAPL). The critical factors affecting VOC infiltration and resulting health risks are presented.

Hers, I.; Zapf-Gilje, R.; Petrovic, S. [Golder Associates Ltd., Burnaby, British Columbia (Canada); Macfarlane, M.; McLenehan, R. [British Columbia Ministry of Environment, Lands and Parks, Victoria, British Columbia (Canada)

1997-09-01T23:59:59.000Z

124

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2  

E-Print Network [OSTI]

K. : Atmospheric chemistry of gasoline-related emissions:chemistry. Methyl tert-butyl ether is a solvent and gasoline

2010-01-01T23:59:59.000Z

125

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2  

E-Print Network [OSTI]

Oil sands comprise 30% of the world’s oil reserves andthe crude oil reserves in Canada’s oil sands deposits are30% of total world oil reserves (Alboudwarej et al. , 2006)

2010-01-01T23:59:59.000Z

126

Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN  

E-Print Network [OSTI]

and Fehsenfeld, F. C. : Emission sources and ocean uptake ofand No- vakov, T. : Emissions of trace gases and particlesGroot, W. J. : Future emissions from Canadian boreal forest

2011-01-01T23:59:59.000Z

127

Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN  

E-Print Network [OSTI]

propene, acetone, benzene, propane and ?-pinene (Table 1).cyanide Acetonitrile Ethane Propane i-Butane n-Butane i-= Ethane Ethane Ethane Ethane Propane Propane Propane ARCTAS

2011-01-01T23:59:59.000Z

128

Regeneration of carboxylic acid-laden basic sorbents by leaching with a volatile base in an organic solvent  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent. The acids are freed from the sorbent phase by treating it with an organic solution of alkylamine thus forming an alkylamine/carboxylic acid complex which is decomposed with improved efficiency to the desired carboxylic acid and the alkylamine. Carbon dioxide addition can be used to improve the adsorption or the carboxylic acids by the solid phase sorbent.

King, C. Judson (Kensington, CA); Husson, Scott M. (Berkeley, CA)

1999-01-01T23:59:59.000Z

129

Brayton Cycle Heat Pump for VOC Control  

E-Print Network [OSTI]

The first full size continuous operation Brayton Cycle Heat Pump (1)(2)(3) application for VOC recovery occurred in 1988. The mixed solvent recovery system was designed and supplied by NUCON for the 3M facility in Weatherford, OK (4). This first...

Kovach, J. L.

130

Volatile Organic Emissions from Carpets  

E-Print Network [OSTI]

irritation by airborne allyl acetate, allyl alcohol, andcompounds. For example, allyl acetate (2-propenyl acetate),acetate, was found to be highly irritating as were other allyl

Hodgson, A.T.

2008-01-01T23:59:59.000Z

131

ARM - Measurement - Volatile organic compounds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearch Relatedcontentcharacteristics ARMgovMeasurementsVisibility

132

Three Essays in Business Management, the Natural Environment, and Environmental Policy  

E-Print Network [OSTI]

Supply Chain GHG Emissions -0.762 Controls Water Abstraction General Waste VOCs HeavySupply Chain GHG Emissions Water Abstraction General Waste Volatile Organic Compounds (VOC) Heavy

Nairn-Birch, Nicholas Simon

2012-01-01T23:59:59.000Z

133

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 VOCsVOCs,, PAHsPAHs, soot, tar, CO, soot, tar, CO  

E-Print Network [OSTI]

incinerator EU (2000) Power plant Germany (1999) MSW incinerator Germany (1999) Hazardou s waste incinerator EU (1996) Waste incinerator USA (1995) CO no limit 50 50 250 50 50 76.31 THC no limit 10 10 20 10 10.153 VOC emissions from waste incineration plants,VOC emissions from waste incineration plants, in mg

Zevenhoven, Ron

134

E-Print Network 3.0 - air voc flow Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geosciences 28 ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT Summary: of biofilters for sequential removal of H2S and VOCs from...

135

Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites  

SciTech Connect (OSTI)

Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

2014-05-06T23:59:59.000Z

136

Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants/Hygroscopicity and CCN Activity of Secondary & Processed Primary Organic Aerosols  

SciTech Connect (OSTI)

The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was to carry out reactions of representative anthropogenic and biogenic VOCs and organic particles with ozone (O3), and hydroxyl (OH), nitrate (NO3), and chlorine (Cl) radicals, which are the major atmospheric oxidants, under simulated atmospheric conditions in large-volume environmental chambers. A combination of on-line and off-line analytical techniques were used to monitor the chemical and physical properties of the particles including their hygroscopicity and CCN activity. The results of the studies were used to (1) improve scientific understanding of the relationships between the chemical composition of organic particles and their hygroscopicity and CCN activity, (2) develop an improved molecular level theoretical framework for describing these relationships, and (3) establish a large database that is being used to develop parameterizations relating organic aerosol chemical properties and SOA sources to particle hygroscopicity and CCN activity for use in regional and global atmospheric air quality and climate models.

Ziemann, P.J.; Arey, J.; Atkinson, R.; Kreidenweis, S.M.; Petters, M.D.

2012-06-13T23:59:59.000Z

137

IS THE TAIL WAGGING THE DOG? AN EMPIRICAL ANALYSIS OF CORPORATE CARBON FOOTPRINTS AND FINANCIAL PERFORMANCE  

E-Print Network [OSTI]

Supply Chain GHG Emissions Controls Water Abstraction General Waste VOCs HeavySupply Chain GHG Emissions Controls Water Abstraction General Waste VOCs HeavySupply Chain GHG Emissions Water Abstraction General Waste Volatile Organic Compounds (VOC) Heavy

Delmas, Magali A; Nairn-Birch, Nicholas S.

2011-01-01T23:59:59.000Z

138

Associations of indoor carbon dioxide concentrations, VOCS, environmental susceptibilities with mucous membrane and lower respiratory sick building syndrome symptoms in the BASE study: Analyses of the 100 building dataset  

SciTech Connect (OSTI)

Using the 100 office-building Building Assessment Survey and Evaluation (BASE) Study dataset, we performed multivariate logistic regression analyses to quantify the associations between indoor minus outdoor CO{sub 2} (dCO{sub 2}) concentrations and mucous membrane (MM) and lower respiratory system (Lresp) Sick Building Syndrome (SBS) symptoms, adjusting for age, sex, smoking status, presence of carpet in workspace, thermal exposure, relative humidity, and a marker for entrained automobile exhaust. Using principal components analysis we identified a number of possible sources of 73 measured volatile organic compounds in the office buildings, and assessed the impact of these VOCs on the probability of presenting the SBS symptoms. Additionally we included analysis adjusting for the risks for predisposition of having SBS symptoms associated with the allergic, asthmatic, and environmentally sensitive subpopulations within the office buildings. Adjusted odds ratios (ORs) for statistically significant, dose-dependant associations (p<0.05) for dry eyes, sore throat, nose/sinus congestion, and wheeze symptoms with 100-ppm increases in dCO{sub 2} ranged from 1.1 to 1.2. These results suggest that increases in the ventilation rates per person among typical office buildings will, on average significantly reduce the prevalence of several SBS symptoms, up to 80%, even when these buildings meet the existing ASHRAE ventilation standards for office buildings. VOC sources were observed to play an role in direct association with mucous membrane and lower respiratory irritation, and possibly to be indirectly involved in indoor chemical reactions with ozone that produce irritating compounds associated with SBS symptoms. O-xylene, possibly emitted from furniture coatings was associated with shortness of breath (OR at the maximum concentration = 8, p < 0.05). The environmental sensitivities of a large subset of the office building population add to the overall risk of SBS symptoms (ORs ranging from 2 to above 11) within the buildings.

Apte, M.G.; Erdmann, C.A.

2002-10-01T23:59:59.000Z

139

Volatility and commodity price dynamics  

E-Print Network [OSTI]

Commodity prices tend to be volatile, and volatility itself varies over time. changes in volatility can affect market variables by directly affecting the marginal value of storage, and by affecting a component of the total ...

Pindyck, Robert S.

2001-01-01T23:59:59.000Z

140

Evaluation of the volatility basis-set approach for the simulation of organic aerosol formation in the Mexico City metropolitan area  

E-Print Network [OSTI]

New primary and secondary organic aerosol modules have been added to PMCAMx, a three dimensional chemical transport model (CTM), for use with the SAPRC99 chemistry mechanism based on recent smog chamber studies. The new ...

Tsimpidi, A. P.

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Analysis of C1, C2, and C10 through C33 particle-phase and semi-volatile organic compound emissions from heavy-duty diesel engines  

E-Print Network [OSTI]

from heavy-duty diesel engines Z. Gerald Liu a,*, Devin R. Berg a , Victoria N. Vasys a , Melissa E 18 November 2009 Keywords: Organic compound emissions Particulate matter emissions Heavy-duty diesel engines Aftertreatment technology Diesel particulate filter Chemical speciation a b s t r a c t To meet

Wu, Mingshen

142

APPLICATION OF STIR BAR SORPTIVE EXTRACTION TO ANALYSIS OF VOLATILE AND SEMIVOLATILE ORGANIC CHEMICALS OF POTENTIAL CONCERN IN SOLIDS AND AQUEOUS SAMPLES FROM THE HANFORD SITE  

SciTech Connect (OSTI)

Stir bar sorptive extraction was applied to aqueous and solid samples for the extraction and analysis of organic compounds from the Hanford chemicals of potential concern list, as identified in the vapor data quality objectives. The 222-S Laboratory analyzed these compounds from vapor samples on thermal desorption tubes as part of the Hanford Site industrial hygiene vapor sampling effort.

FRYE JM; KUNKEL JM

2009-03-05T23:59:59.000Z

143

Low VOC drying of lumber and wood panel products. Progress report No. 8  

SciTech Connect (OSTI)

This study was initiated by an Institute of Paper Science and Technology finding that heating softwood in a low-headspace environment removed much of the VOCs without removing the water. This offered the possibility of removing VOCs from wet wood, capturing them as a product, and then drying the VOC-depleted wood conventionally with little or no VOC controls. Two means of low-headspace heating were explored: steam and radiofrequency (RF). It was found in the previous year, that while both steam and RF were able to drive out VOCs, steam was impracticably slow for lumber. Hence the effect of RF or microwave on wood was the principal focus of the work reported here. Finally, in order to understand the mechanism of VOC release, the transport of the VOCs in wood was studied, together with the seasonal effects that influence VOC concentration in trees.

Su, W.; Yan, H.; Hooda, U.; Wild, M.P.; Banerjee, S. [Inst. of Paper Science and Technology, Atlanta, GA (United States)] [Inst. of Paper Science and Technology, Atlanta, GA (United States); Shmulsky, R.; Thompson, A.; Ingram, L.; Conners, T. [Mississippi State Univ., MS (United States)] [Mississippi State Univ., MS (United States)

1998-07-01T23:59:59.000Z

144

VOC Emission Control with the Brayton Cycle Pilot Plant Operations  

E-Print Network [OSTI]

A mobile pilot plant capable of removing VOC emissions from exhaust air streams was cooperatively funded by SCE, EPRI, 3M, and NUCON. Valuable information about the process and the recovery operation has been gained by performing tests at a number...

Enneking, J. C.

145

ORIGINAL PAPER L. Voc adlo K. S. Knight G. D. Price I. G. Wood  

E-Print Network [OSTI]

ORIGINAL PAPER L. VocÏ adlo á K. S. Knight á G. D. Price á I. G. Wood Thermal expansion and crystal discussed by Wood et al. (1996), VocÏ adlo et al. (1999, 2000) and Mattheiss and Hamann (1993002690100202 L. VocÏ adlo (&) á G. D. Price á I. G. Wood Department of Geological Sciences, University College

Vocadlo, Lidunka

146

O3-NOx-VOC sensitivity and NOx-VOC indicators in Paris: Results from models and Atmospheric Pollution Over  

E-Print Network [OSTI]

from the Atmospheric Pollution Over the Paris Area campaign near Paris, with special attention Composition and Structure: Pollution--urban and regional (0305); 0365 Atmospheric Composition and Structure-VOC indicators in Paris: Results from models and Atmospheric Pollution Over the Paris Area (ESQUIF) measurements

Menut, Laurent

147

Volatile Organic Compound Detection Using Nanostructured Copolymers  

E-Print Network [OSTI]

a lot of success in sensor development for greenhouse gases (CO2, CH4, N2O, NO, and CO), technology sensing mechanisms are at play simultaneously, and we briefly discuss some of them. The demand for low-cost, PennsylVania 15213, and National Personal ProtectiVe Technology Laboratory, National Institute

Weiss, Lee E.

148

Flexible CHP System with Low NOx, CO and VOC Emissions - Fact...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sheet, 2014 Flexible CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 The Gas Technology Institute, in collaboration with Cannon Boiler Works, Integrated CHP...

149

Implementation of VOC source reduction practices in a manufactured house and in school classrooms  

SciTech Connect (OSTI)

Detailed studies of a new manufactured house and four new industrialized relocatable school classrooms were conducted to determine the emission sources of formaldehyde and other VOCs and to identify and implement source reduction practices. Procedures were developed to generate VOC emission factors that allowed reasonably accurate predictions of indoor air VOC concentrations. Based on the identified sources of formaldehyde and other aldehydes, practices were developed to reduce the concentrations of these compounds in new house construction. An alternate ceiling panel reduced formaldehyde concentrations in the classrooms. Overall, the classrooms had relatively low VOC concentrations.

Hodgson, A.T.; Apte, M.G.; Shendell, D.G.; Beal, D.; McIlvaine, J.E.R.

2002-01-01T23:59:59.000Z

150

Brookhaven National Laboratory - OU III VOC | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power Systems EngineeringDepartment of4 Federal6Clean Energy | DepartmentBrandonYoungHFBRIII VOC

151

Organization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat CornellInternships,(SC) Laboratories »OrganicOrganization

152

Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces  

E-Print Network [OSTI]

1 Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces Eva Land. This report describes the photocatalytic degradation of formaldehyde and methanol, two common VOC's, by TiO2 to produce measurable gas phase concentrations. The extended UV illumination of the tiles resulted in a 50

Bergin, Mike

153

Emission and Chemistry of Organic Carbon in the Gas and Aerosol Phase at a Sub-Urban Site Near Mexico City in March 2006 During the MILAGRO Study  

SciTech Connect (OSTI)

Volatile organic compounds (VOCs) and carbonaceous aerosol were measured at a sub-urban site near Mexico City in March of 2006 during the MILAGRO study (Megacity Initiative: Local and Global Research Objectives). Diurnal variations of hydrocarbons, elemental carbon (EC) and hydrocarbon-like organic aerosol (HOA) were dominated by a high peak in the early morning when local emissions accumulated in a shallow boundary layer, and a minimum in the afternoon when the emissions were diluted in a significantly expanded boundary layer and, in case of the reactive gases, removed by OH. In comparison, diurnal variations of species with secondary sources such as the aldehydes, ketones, oxygenated organic aerosol (OOA) and water-soluble organic carbon (WSOC) stayed relatively high in the afternoon indicating strong photochemical formation. Emission ratios of many hydrocarbon species relative to CO were higher in Mexico City than in the U.S., but we found similar emission ratios for most oxygenated VOCs and organic aerosol. Secondary formation of acetone may be more efficient in Mexico City than in the U.S., due to higher emissions of alkane precursors from the use of liquefied petroleum gas. Secondary formation of organic aerosol was similar between Mexico City and the U.S. Combining the data for all measured gas and aerosol species, we describe the budget of total observed organic carbon (TOOC), and find that the enhancement ratio of TOOC relative to CO is conserved between the early morning and mid afternoon despite large compositional changes. Finally, the influence of biomass burning is investigated using the measurements of acetonitrile, which was found to correlate with levoglucosan in the particle phase. Diurnal variations of acetonitrile indicate a contribution from local burning sources. Scatter plots of acetonitrile versus CO suggest that the contribution of biomass burning to the enhancement of most gas and aerosol species was not dominant and perhaps not dissimilar from observations in the U.S.

de Gouw, Joost A.; Welsh-Bon, Daniel; Warneke, Carsten; Kuster, W. C.; Alexander, M. L.; Baker, Angela K.; Beyersdorf, Andreas J.; Blake, D. R.; Canagaratna, Manjula R.; Celada, A. T.; Huey, L. G.; Junkermann, W.; Onasch, Timothy B.; Salcido, A.; Sjostedt, S. J.; Sullivan, Amy; Tanner, David J.; Vargas-Ortiz, Leroy; Weber, R. J.; Worsnop, Douglas R.; Yu, Xiao-Ying; Zaveri, Rahul A.

2009-05-28T23:59:59.000Z

154

Services Initiatives | Department of Energy  

Energy Savers [EERE]

and is very low in Volatile Organic Compounds (VOCs) which evaporate little and cause no air pollution, whereas petroleum-based inks are high in VOCs and cause air pollution when...

155

Surface acoustic wave sensing of VOCs in harsh chemical environments  

SciTech Connect (OSTI)

The measurement of VOC concentrations in harsh chemical and physical environments is a formidable task. A surface acoustic wave (SAW) sensor has been designed for this purpose and its construction and testing are described in this paper. Included is a detailed description of the design elements specific to operation in 300{degree}C steam and HCl environments including temperature control, gas handling, and signal processing component descriptions. In addition, laboratory temperature stability was studied and a minimum detection limit was defined for operation in industrial environments. Finally, a description of field tests performed on steam reforming equipment at Synthetica Technologies Inc. of Richmond, CA is given including a report on destruction efficiency of CCl{sub 4} in the Synthetica moving bed evaporator. Design improvements based on the field tests are proposed.

Pfeifer, K.B.; Martin, S.J.; Ricco, A.J.

1993-06-01T23:59:59.000Z

156

Quantitative organic vapor-particle sampler  

DOE Patents [OSTI]

A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

1998-01-01T23:59:59.000Z

157

North Central Texas Alternative Fuel and Advanced Technology...  

Broader source: Energy.gov (indexed) [DOE]

Gas, Electric, Ethanol, and Biodiesel Project Benefits* Pollutant Annual Reductions Nitrogen Oxides (NO x ) 63.7 Tons Volatile Organic Compounds (VOC) 1.6 Tons Particulate...

158

APPENDIX E. AIRNOVA, INC. EMISSION EVALUATION TEST REPORT  

E-Print Network [OSTI]

.6 Specific Volatile Organic Compounds . . . . . . . . . . . . . . . . 27 4.7 Dioxins, Furans, and PCBs)* · Volatile Organic Compounds (VOCs)* · Sulfur Dioxide (SO2)* · Dioxins and Furans · Toxic Metals

Brookhaven National Laboratory

159

The Chicago VOC trading system : the consequences of market design for performance  

E-Print Network [OSTI]

The Chicago cap-and-trade approach to regulating stationary source VOC emissions in the Chicago ozone non-attainment area is a pioneering program that could set a precedent for other urban areas troubled by high ozone ...

Kosobud, Richard F.

2004-01-01T23:59:59.000Z

160

In Search of a Statistically Valid Volatility Risk Factor  

E-Print Network [OSTI]

The cross- section of volatility and expected returns, Theof a Statistically Valid Volatility Risk Factor (revised)of a Statistically Valid Volatility Risk Factor Robert M.

Anderson, Robert M.; Bianchi, Stephen W.; Goldberg, Lisa R.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Volatility in natural gas and oil markets  

E-Print Network [OSTI]

Using daily futures price data, I examine the behavior of natural gas and crude oil price volatility since 1990. I test whether there has been a significant trend in volatility, whether there was a short-term increase in ...

Pindyck, Robert S.

2003-01-01T23:59:59.000Z

162

Characterizing the formation of secondary organic aerosols  

SciTech Connect (OSTI)

Organic aerosol is an important fraction of the fine particulate matter present in the atmosphere. This organic aerosol comes from a variety of sources; primary organic aerosol emitted directly from combustion process, and secondary aerosol formed in the atmosphere from condensable vapors. This secondary organic aerosol (SOA) can result from both anthropogenic and biogenic sources. In rural areas of the United States, organic aerosols can be a significant part of the aerosol load in the atmosphere. However, the extent to which gas-phase biogenic emissions contribute to this organic load is poorly understood. Such an understanding is crucial to properly apportion the effect of anthropogenic emissions in these rural areas that are sometimes dominated by biogenic sources. To help gain insight on the effect of biogenic emissions on particle concentrations in rural areas, we have been conducting a field measurement program at the University of California Blodgett Forest Research Facility. The field location includes has been used to acquire an extensive suite of measurements resulting in a rich data set, containing a combination of aerosol, organic, and nitrogenous species concentration and meteorological data with a long time record. The field location was established in 1997 by Allen Goldstein, a professor in the Department of Environmental Science, Policy and Management at the University of California at Berkeley to study interactions between the biosphere and the atmosphere. The Goldstein group focuses on measurements of concentrations and whole ecosystem biosphere-atmosphere fluxes for volatile organic compounds (VOC's), oxygenated volatile organic compounds (OVOC's), ozone, carbon dioxide, water vapor, and energy. Another important collaborator at the Blodgett field location is Ronald Cohen, a professor in the Chemistry Department at the University of California at Berkeley. At the Blodgett field location, his group his group performs measurements of the concentrations of important gas phase nitrogen compounds. Experiments have been ongoing at the Blodgett field site since the fall of 2000, and have included portions of the summer and fall of 2001, 2002, and 2003. Analysis of both the gas and particle phase data from the year 2000 show that the particle loading at the site correlates with both biogenic precursors emitted in the forest and anthropogenic precursors advected to the site from Sacramento and the Central Valley of California. Thus the particles at the site are affected by biogenic processing of anthropogenic emissions. Size distribution measurements show that the aerosol at the site has a geometric median diameter of approximately 100 nm. On many days, in the early afternoon, growth of nuclei mode particles (<20 nm) is also observed. These growth events tend to occur on days with lower average temperatures, but are observed throughout the summer. Analysis of the size resolved data for these growth events, combined with typical measured terpene emissions, show that the particle mass measured in these nuclei mode particles could come from oxidation products of biogenic emissions, and can serve as a significant route for SOA partitioning into the particle phase. During periods of each year, the effect of emissions for forest fires can be detected at the Blodgett field location. During the summer of 2002 emissions from the Biscuit fire, a large fire located in Southwest Oregon, was detected in the aerosol data. The results show that increases in particle scattering can be directly related to increased black carbon concentration and an appearance of a larger mode in the aerosol size distribution. These results show that emissions from fires can have significant impact on visibility over large distances. The results also reinforce the view that forest fires can be a significant source of black carbon in the atmosphere, which has important climate and visibility. Continuing work with the 2002 data set, particularly the combination of the aerosol and gas phase data, will continue to provide important information o

Lunden, Melissa; Black, Douglas; Brown, Nancy

2004-02-01T23:59:59.000Z

163

Perturbation Expansion for Option Pricing with Stochastic Volatility  

E-Print Network [OSTI]

We fit the volatility fluctuations of the S&P 500 index well by a Chi distribution, and the distribution of log-returns by a corresponding superposition of Gaussian distributions. The Fourier transform of this is, remarkably, of the Tsallis type. An option pricing formula is derived from the same superposition of Black-Scholes expressions. An explicit analytic formula is deduced from a perturbation expansion around a Black-Scholes formula with the mean volatility. The expansion has two parts. The first takes into account the non-Gaussian character of the stock-fluctuations and is organized by powers of the excess kurtosis, the second is contract based, and is organized by the moments of moneyness of the option. With this expansion we show that for the Dow Jones Euro Stoxx 50 option data, a Delta-hedging strategy is close to being optimal.

Petr Jizba; Hagen Kleinert; Patrick Haener

2007-08-22T23:59:59.000Z

164

AEROBIC BIOTRANSFORMATION OF TOXIC ORGANICS IN WASTEWATER  

E-Print Network [OSTI]

#12;AEROBIC BIOTRANSFORMATION OF TOXIC ORGANICS IN WASTEWATER DOE FRAP 1997-15 Prepared for in both domestic and industrial wastewater. The release of these compounds during wastewater treatment to predict the mass of the VOCs in the wastewater treated by biotransformation and the mass stripped

165

Summary Report for the Development of Materials for Volatile Radionuclides  

SciTech Connect (OSTI)

The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2010, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogenides. For 85Kr, metal organic framework (MOF) structures were investigated.

Strachan, Denis M.; Chun, Jaehun; Henager, Charles H.; Matyas, Josef; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

2010-11-22T23:59:59.000Z

166

Method for lowering the VOCS emitted during drying of wood products  

DOE Patents [OSTI]

The present invention is directed to a method for removal of VOCs from wood products prior to drying the wood products. The method of the invention includes the steps of providing a chamber having an opening for receiving wood and loading the chamber with green wood. The wood is loaded to an extent sufficient to provide a limited headspace in the chamber. The chamber is then closed and the wood is heated in the chamber for a time and at a temperature sufficient to saturate the headspace with moisture and to substantially transfer VOCs from the wood product to the moisture in the headspace.

Banerjee, Sujit (1832 Jacksons Creek Point, Marietta, GA 30068); Boerner, James Robert (154 Junedale Rd., Cincinnati, OH 45218); Su, Wei (2262 Orleans Ave., Marietta, GA 30062)

2000-01-01T23:59:59.000Z

167

Determination of VOC emissions from French wood products Christophe YRIEIX *, Franois MAUPETIT **, Olivier RAMALHO **  

E-Print Network [OSTI]

building products. Introduction Today, it is well known that building products may influence indoor air1/10 Determination of VOC emissions from French wood products Christophe YRIEIX *, François air quality (IAQ), it appears necessary to have analytical protocol for the measurement and health

Paris-Sud XI, Université de

168

Carbide-Derived Carbons for Adsorptive Removal of VOCs from Air Streams  

E-Print Network [OSTI]

Carbide-Derived Carbons for Adsorptive Removal of VOCs from Air Streams References 1. USEPA Literature Results Carbide-Derived Carbons Motivation Future Research · The effect of pore size and pore size decreasing removal cost is an advancement for the industry and the environment. Carbide-derived carbons (CDCs

Das, Suman

169

Photoconductive Decay Lifetime and Suns-Voc Diagnostics of Efficient Heterojunction Solar Cells: Preprint  

SciTech Connect (OSTI)

We report results of minority carrier lifetime measurements for double-sided p-type Si heterojunction devices and compare Suns-Voc results to Light I-V measurements on 1 cm2 solar cell devices measured on an AM1.5 calibrated XT-10 solar simulator.

Page, M. R.; Iwaniczko, E.; Xu, Y.; Roybal L.; Bauer, R.; Yan, H.-C.; Wang, Q.; Meier, D. L.

2008-05-01T23:59:59.000Z

170

Ambient air measurements related to traffic : volution of VOCs over three years  

E-Print Network [OSTI]

hours. The major VOC are : benzène and toluène, MTBE, 1,3-butadiene, formaldehyde, phénol, naphtalene, but will not be discussed hère. Aromatic hydrocarbons and MTBE are sampled b

Paris-Sud XI, Université de

171

Mapping isoprene emissions over North America using formaldehyde column observations from space  

E-Print Network [OSTI]

Mapping isoprene emissions over North America using formaldehyde column observations from space. [1] We present a methodology for deriving emissions of volatile organic compounds (VOC) using space to local VOC emissions, with a spatial smearing that increases with the VOC lifetime. Isoprene

Chance, Kelly

172

Moment Methods for Exotic Volatility Derivatives  

E-Print Network [OSTI]

The latest generation of volatility derivatives goes beyond variance and volatility swaps and probes our ability to price realized variance and sojourn times along bridges for the underlying stock price process. In this paper, we give an operator algebraic treatment of this problem based on Dyson expansions and moment methods and discuss applications to exotic volatility derivatives. The methods are quite flexible and allow for a specification of the underlying process which is semi-parametric or even non-parametric, including state-dependent local volatility, jumps, stochastic volatility and regime switching. We find that volatility derivatives are particularly well suited to be treated with moment methods, whereby one extrapolates the distribution of the relevant path functionals on the basis of a few moments. We consider a number of exotics such as variance knockouts, conditional corridor variance swaps, gamma swaps and variance swaptions and give valuation formulas in detail.

Albanese, Claudio

2007-01-01T23:59:59.000Z

173

Development and Characterization of a Thermodenuder for Aerosol Volatility Measurements  

SciTech Connect (OSTI)

This SBIR Phase I project addressed the critical need for improved characterization of carbonaceous aerosol species in the atmosphere. The proposed work focused on the development of a thermodenuder (TD) system capable of systematically measuring volatility profiles of primary and secondary organic aerosol species and providing insight into the effects of absorbing and nonabsorbing organic coatings on particle absorption properties. This work provided the fundamental framework for the generation of essential information needed for improved predictions of ambient aerosol loadings and radiative properties by atmospheric chemistry models. As part of this work, Aerodyne Research, Inc. (ARI) continued to develop and test, with the final objective of commercialization, an improved thermodenuder system that can be used in series with any aerosol instrument or suite of instruments (e.g., aerosol mass spectrometers-AMS, scanning mobility particle sizers-SMPS, photoacoustic absorption spectrometers-PAS, etc.) to obtain aerosol chemical, physical, and optical properties as a function of particle volatility. In particular, we provided the proof of concept for the direct coupling of our improved TD design with a full microphysical model to obtain volatility profiles for different organic aerosol components and to allow for meaningful comparisons between different TD-derived aerosol measurements. In a TD, particles are passed through a heated zone and a denuding (activated charcoal) zone to remove semi-volatile material. Changes in particle size, number concentration, optical absorption, and chemical composition are subsequently detected with aerosol instrumentation. The aerosol volatility profiles provided by the TD will strengthen organic aerosol emission inventories, provide further insight into secondary aerosol formation mechanisms, and provide an important measure of particle absorption (including brown carbon contributions and identification, and absorption enhancements due to coatings on soot particles). The successfully completed Phase I project included construction of a prototype design for the TD with detailed physical modeling, testing with laboratory and ambient aerosol particles, and the initiation of a detailed microphysical model of the aerosol particles passing through the TD to extract vapor pressure distributions. The objective of the microphysical model is to derive vapor pressure distributions (i.e. vapor pressure ranges, including single chemical compounds, mixtures of known compounds, and complex ‘real-world’ aerosols, such as SOA, and soot particles with absorbing and nonabsorbing coatings) from TD measurements of changes in particle size, mass, and chemical composition for known TD temperatures and flow rates (i.e. residence times). The proposed Phase II project was designed to optimize several TD systems for different instrument applications and to combine the hardware and modeling into a robust package for commercial sales.

Dr. Timothy Onasch

2009-09-09T23:59:59.000Z

174

Oxidized organic functional groups in aerosol particles from forest emissions measured at mid-mountain and high- elevation mountain sites in Whistler, BC  

E-Print Network [OSTI]

FTIR) and X-ray fluorescence (XRF) techniques for organicPTR-MS SOA SP2 STXM-NEXAFS VOC XRF Aerosol Mass SpectrometerPTR-MS), X-ray fluorescence (XRF), single particle soot

Schwartz, Rachel E.

2010-01-01T23:59:59.000Z

175

Current status of fluoride volatility method development  

SciTech Connect (OSTI)

The Fluoride Volatility Method is based on a separation process, which comes out from the specific property of uranium, neptunium and plutonium to form volatile hexafluorides whereas most of fission products (mainly lanthanides) and higher transplutonium elements (americium, curium) present in irradiated fuel form nonvolatile tri-fluorides. Fluoride Volatility Method itself is based on direct fluorination of the spent fuel, but before the fluorination step, the removal of cladding material and subsequent transformation of the fuel into a powdered form with a suitable grain size have to be done. The fluorination is made with fluorine gas in a flame fluorination reactor, where the volatile fluorides (mostly UF{sub 6}) are separated from the non-volatile ones (trivalent minor actinides and majority of fission products). The subsequent operations necessary for partitioning of volatile fluorides are the condensation and evaporation of volatile fluorides, the thermal decomposition of PuF{sub 6} and the finally distillation and sorption used for the purification of uranium product. The Fluoride Volatility Method is considered to be a promising advanced pyrochemical reprocessing technology, which can mainly be used for the reprocessing of oxide spent fuels coming from future GEN IV fast reactors.

Uhlir, J.; Marecek, M.; Skarohlid, J. [UJV - Nuclear Research Institute, Research Centre Rez, CZ-250 68 Husinec - Rez 130 (Czech Republic)

2013-07-01T23:59:59.000Z

176

ENHANCEMENTS OF NONPOINT-SOURCE MONITORING PROGRAMS TO ASSESS VOLATILE  

E-Print Network [OSTI]

WATER OF THE UNITED STATES Wayne W. Lapham, Michael J. Moran, and John S. Zogorski ABSTRACT The U compounds (VOCs) in ground water of the United States. The data are from Federal, State, and local nonpoint for VOC occurrence and nonoccurrence in ground water of the United States. INTRODUCTION Background In 1991

177

Treatability test of a stacked-tray air stripper for VOC in water  

SciTech Connect (OSTI)

A common strategy for hydraulic containment and mass removal at VOC contaminated sites is `pump and treat (P&T)`. In P&T operations, contaminated ground water is pumped from wells, treated above ground, and discharged. Many P&T remediation systems at VOC sites rely on air stripping technology because VOCs are easily transferred to the vapor phase. In stacked-tray air strippers, contaminated water is aerated while it flows down through a series of trays. System operations at LLNL are strictly regulated by the California and federal Environmental Protection Agencies (Cal/EPA and EPA), the Bay Area Air Quality Management District (BAAQMD), the California Regional Water Quality Control Board (RWQCB) and the Department of Toxic Substances Control (DTSC). These agencies set discharge limits, require performance monitoring, and assess penalties for non-compliance. National laboratories are also subject to scrutiny by the public and other government agencies. This extensive oversight makes it necessary to accurately predict field treatment performance at new extraction locations to ensure compliance with all requirements prior to facility activation. This paper presents treatability test results for a stacked- tray air stripper conducted at LLNL and compares them to the vendor`s modeling software results.

Pico, T., LLNL

1998-04-01T23:59:59.000Z

178

Volatile constituents in a wood pyrolysis oil  

E-Print Network [OSTI]

Science VOLATILE CONSTITUTENTS IN A WOOD PYROLYSIS OIL A Thesis SHIH-CHIEN LIN Appro d as to style and content by: (Chairman of Committee) Head of epa tmen (Member Member Nay 1978 442936 ABSTRACT Volatile Constituents in a Wood Pyrolysis Oil.../120 Supelcoport. Other trace constituents of volatile acid were also 'dentifi="' by trap- ping the substances from the C. C. column into i: n;- 0-sh ped capillary tube and subjecting to mass spectrometry. The corrosivity of pyrolysis oil and it, volati'e acids...

Lin, Shih-Chien

1978-01-01T23:59:59.000Z

179

Securing non-volatile memory regions  

DOE Patents [OSTI]

Methods, apparatus and articles of manufacture to secure non-volatile memory regions are disclosed. An example method disclosed herein comprises associating a first key pair and a second key pair different than the first key pair with a process, using the first key pair to secure a first region of a non-volatile memory for the process, and using the second key pair to secure a second region of the non-volatile memory for the same process, the second region being different than the first region.

Faraboschi, Paolo; Ranganathan, Parthasarathy; Muralimanohar, Naveen

2013-08-20T23:59:59.000Z

180

On the pricing and hedging of volatility derivatives  

E-Print Network [OSTI]

On the pricing and hedging of volatility derivatives SAM HOWISON Mathematical Institute, University a stochastic volatility model as our starting point; we also provide formulae for the case that the volatility follows a jump- diffusion process of the type described in [18]. The fact that stochastic volatility

Howison, Sam

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Reactive flash volatilization of fluid fuels  

DOE Patents [OSTI]

The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

2013-01-08T23:59:59.000Z

182

Pressure maintenance in a volatile oil reservoir  

E-Print Network [OSTI]

PRESSURE MAINTENANCE IN A VOLATILE OIL RESERVOIR A Thesis BRUCE ALAN SCHUSTER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May, 1989 Major... Subject: Petroleum Engineering PRESSURE MAINTENANCE IN A VOLATILE OIL RESERVOIR A Thesis BRUCE ALAN SCHUSTER Approved as to style and content by: S. A. Holditch (Chair of Committee) W. J. Lee (Member) R. R, Berg (Member) , Jz W. D. Von Gonten...

Schuster, Bruce Alan

1989-01-01T23:59:59.000Z

183

1. PRECONCENTRATION, THERMAL DESORPTION & ANALYSIS OF VOLATILE ORGANIC COMPOUNDS  

E-Print Network [OSTI]

: peltier, liq. N?.. Heated transfer line 2) Desorption & transfer by fastheatlng Cooled & heated trap jas trap. The trap is then quickly heated, under a low flow of hélium, to desorb and inject thé compounds. This highly concentrated plug of sample is transferred via a heated transfer line, to a capillary

Boyer, Edmond

184

Glossary of Volatile Organic Compounds Ethylbenzene Carbon tetrachloride  

E-Print Network [OSTI]

;Ethylbenzene Ethylbenzene is a colorless, flammable liquid found in natural products such as coal tar and petroleum. It is also found in manufactured products such as inks, insecticides, and paints. Ethylbenzene in the air. In surface water, ethylbenzene breaks down by reacting with other chemicals found naturally

185

Volatile organic compounds in some urban locations in United States  

E-Print Network [OSTI]

. Air samples were collected and analyzed in accordance with US Environmental Protection Agency, an increased awareness of air pollutants and new potential sources of airborne toxic chemicals have raised to the immune and nervous systems, and other fatal diseases (Singh et al., 1982; Kao, 1994). Recently, a number

Aneja, Viney P.

186

Volatile Organic Compound Emissions from Dairy Cows and  

E-Print Network [OSTI]

, acetone + propanal, dimethylsulfide, and m/z 109 (likely 4-methyl-phenol). The compounds with highest. Agricultural pro- cesses, notably animal operations, are no longer exempt from emission controls as a result with a pro

Goldstein, Allen

187

Three-Dimensional Simulation of Volatile Organic Compound Mass...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

simulations using data from the U.S. Department of Energy’s Hanford Site, where carbon tetrachloride is present in a low permeability zone about 30 m above the...

188

2 Extracting and trapping biogenic 3 volatile organic compounds stored  

E-Print Network [OSTI]

, Subcritical water extraction; UAE, Ultrasound-assisted extraction 36 1. Introduction Plants release

Goldstein, Allen

189

Detection of Low Volatility Organic Analytes on Soils Using Infrared  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesData FilesShape, Density, andagingaboutDrizzlethiol

190

Comparative Toxicity of Combined Particle and Semi-Volatile Organic  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth Codestheat Two

191

Partitioning of Volatile Organics in Diesel Particulate and Exhaust |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSalesOE0000652 Srivastava,Pacific1ofDepartmentb.SensorDepartment

192

Particulate Matter Sampling and Volatile Organic Compound Removal for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 TheSteven Ashby Dr.presentationsParticipantParticles

193

Metal volatilization and separation during incineration  

SciTech Connect (OSTI)

The US Environmental Protection Agency (US EPA) has reported that metals can account for almost all of the identified risks from a thermal treatment process. Fundamental research leading to better understanding of their behavior and improved control of their emissions is greatly needed. This paper reports studies on metal volatilization and separation during incineration. Metal volatilization studies were carried out in two separate experiments. In the first experiment, the dynamic volatilization characteristics of various metals during the combustion of metal-containing wood pellets were investigated in a high-temperature electric furnace. In addition to uncontrolled volatilization, the potential of employing chemical additives to bind metals and prevent them from volatilizing during combustion was also investigated. The second experiment involved the investigation of metal volatilization characteristics during the thermal treatment of metal-contaminated clay in a fluidized bed unit. The metal species tested in both experiments were compounds of lead and cadmium. Metal capture/separation studies were also carried out in two separate experiments. The first involved the use of sorbents in the combustion chamber to capture metals during the fluidized bed incineration of metal-containing wood pellets. The second experiments, however, employed sorbents to absorb metal vapors in a fluidized-bed waste-heat boiler. The objective of both the experiments is to characterize the metal absorption efficiency associated with the processes.

Ho, T.C.; Chu, H.W.; Hopper, J.R. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

1993-01-01T23:59:59.000Z

194

Low VOC drying of lumber and wood panel products. Progress report number 9  

SciTech Connect (OSTI)

This project is based on the finding that brief microwave or RF-treatment of wood under low-headspace conditions leads to the release of VOCs. On occasion the authors have found that prolonged irradiation increases turpentine yield much more than anticipated from a simple mass balance; i.e., more pinene appeared to be released than was present in the wood in the first place. If taken at face value, this suggests that brief low-headspace irradiation removes VOCs, while prolonged exposure creates it. While seemingly improbable, this could follow if dielectric heating exposed regions of wood that were otherwise inaccessible to the solvent used for extraction (unlikely), or if the irradiation induced depolymerization of terpene dimers or higher polymers. In this report the authors attempt to identify the conditions that lead to this apparent enhancement of terpene yield, by constructing relationships between yield and irradiation parameters. The tentative conclusions are that this enhancement only occurs with relatively wet heartwood, and only under prolonged irradiation. An additional conclusion is that continuing analyses of twelve trees in the MSU forest confirm that the absence of a significant seasonal influence on turpentine content. An apparatus for permeability testing has been constructed, and work is underway.

Hooda, U.; Banerjee, S. [Inst. of Paper Science and Technology, Atlanta, GA (United States); Ingram, L.; Conners, T. [Mississippi State Univ., MS (United States)

1998-10-01T23:59:59.000Z

195

Volatile Species Retention During Metallic Fuel Casting  

SciTech Connect (OSTI)

Metallic nuclear fuels are candidate transmutation fuel forms for advanced fuel cycles. Through the operation of the Experimental Breeder Reactor II metallic nuclear fuels have been shown to be robust and easily manufactured. However, concerns have been raised concerning loss of americium during the casting process because of its high vapor pressure. In order to address these concerns a gaseous diffusion model was developed and a series of experiments using both manganese and samarium as surrogates for americium were conducted. The modeling results showed that volatility losses can be controlled to essentially no losses with a modest overpressure. Experimental results also showed volatile species retention down to no detectable losses through overpressure, although the loss values varied from the model results the same trend was seen. Bases on these results it is very probably that americium losses through volatility can be controlled to no detectable losses through application of a modest overpressure during casting.

Randall S. Fielding; Douglas L. Proter

2013-10-01T23:59:59.000Z

196

Non-volatile memory for checkpoint storage  

DOE Patents [OSTI]

A system, method and computer program product for supporting system initiated checkpoints in high performance parallel computing systems and storing of checkpoint data to a non-volatile memory storage device. The system and method generates selective control signals to perform checkpointing of system related data in presence of messaging activity associated with a user application running at the node. The checkpointing is initiated by the system such that checkpoint data of a plurality of network nodes may be obtained even in the presence of user applications running on highly parallel computers that include ongoing user messaging activity. In one embodiment, the non-volatile memory is a pluggable flash memory card.

Blumrich, Matthias A.; Chen, Dong; Cipolla, Thomas M.; Coteus, Paul W.; Gara, Alan; Heidelberger, Philip; Jeanson, Mark J.; Kopcsay, Gerard V.; Ohmacht, Martin; Takken, Todd E.

2014-07-22T23:59:59.000Z

197

Forecasting Volatility in Stock Market Using GARCH Models  

E-Print Network [OSTI]

Forecasting volatility has held the attention of academics and practitioners all over the world. The objective for this master's thesis is to predict the volatility in stock market by using generalized autoregressive conditional heteroscedasticity(GARCH...

Yang, Xiaorong

2008-01-01T23:59:59.000Z

198

Cursed Resources? Political Conditions and Oil Market Volatility*  

E-Print Network [OSTI]

a country's political conditions affect oil production within its borders. We show production, with very democratic regimes exhibiting less volatility in their oil production than more of oil production volatility. Our finding has implications both for understanding world oil markets

Edwards, Paul N.

199

X-ray elemental online analyzer measures volatiles  

SciTech Connect (OSTI)

The use of an online XRF analyser for determining the volatiles content of coal is outlined. 3 figs.

Klein, A.; Pilz, K.; Reich, K. [Indutech Instruments GmbH, Simmersfeld (Germany)

2008-04-15T23:59:59.000Z

200

COMMODITY PRICE VOLATILITY ACROSS EXCHANGE RATE REGIMES  

E-Print Network [OSTI]

1 COMMODITY PRICE VOLATILITY ACROSS EXCHANGE RATE REGIMES John T. Cuddington* and Hong Liang** March 10, 2003 ABSTRACT This paper documents a new "stylized fact" regarding the relative price 1880 to 1996, this key relative price among two categories of tradable goods is shown to exhibit

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Proboscis extension reflex platform for volatiles and semi-volatiles detection  

DOE Patents [OSTI]

The present invention provides an apparatus for the detection of volatile and semi-volatile chemicals using the olfactory abilities of honey bees that are trained to respond to the presence of a specific chemical in a sample of gas with the proboscis extension reflex (PER). In particular, the geometry and arrangement of the parts of the apparatus are such that the amount of surface area in contact with the sample of gas prior to its introduction to the bees is minimized to improve the detection of particular volatile and semi-volatile that have a tendency to "stick" to contacting surfaces, especially certain chemicals associated with explosives and narcotics. According to another aspect of the present invention, a pre-concentrating means is incorporated with the device to effectively increase the concentration of "sticky" chemicals presented to the insects.

Wingo, Robert M. (Los Alamos, NM); McCabe, Kirsten J. (Los Alamos, NM); Haarmann, Timothy K. (Jemez Pueblo, NM)

2010-11-30T23:59:59.000Z

202

Approximate hedging problem with transaction costs in stochastic volatility markets  

E-Print Network [OSTI]

Approximate hedging problem with transaction costs in stochastic volatility markets Thai Huu Nguyen stochastic volatility markets with transaction costs using a new form for enlarged volatility in Leland between the present setting and high frequency markets with transaction costs. Possibilities to improve

Paris-Sud XI, Université de

203

Volatility Persistence in Crude Oil Markets Amlie CHARLES  

E-Print Network [OSTI]

announcements on production reduction or US announcements on crude inventories. We find that the crude oilVolatility Persistence in Crude Oil Markets Amélie CHARLES Audencia Nantes, School of Management on the volatility modelling process improve the understanding of volatility in crude oil markets. Keywords: Crude

Boyer, Edmond

204

Atmos. Chem. Phys., 14, 1097710988, 2014 www.atmos-chem-phys.net/14/10977/2014/  

E-Print Network [OSTI]

side. In addition, there are also about 1000 coal bed methane wells and conventional wells located in emissions of greenhouse gases (mostly methane), volatile organic compounds (VOCs) and nitrogen oxides (NOx

Pierce, Jeffrey

205

North Central Texas Alternative Fuel and Advanced Technology...  

Broader source: Energy.gov (indexed) [DOE]

Sites: Natural Gas, Electric, Ethanol, and Biodiesel Project Benefits* 67.7 Tons Nitrogen Oxides (NO x ) Reduced 4.5 Tons Volatile Organic Compounds (VOC) Reduced 0.8 Tons...

206

Physical and Chemical Characterization of Particulate and Gas phase Emissions from Biomass Burning  

E-Print Network [OSTI]

Base VOC Volatile Organic Compound XRF X-ray Fluorescence ?mFluorescence spectrometry (XRF) (Na through Pb), inorganicby X-ray fluorescence (XRF). The USFS samples were analyzed

Hosseini, Seyedehsan

2012-01-01T23:59:59.000Z

207

EnviroDB: Applied Database Systems Design for the National Environmental Assessment Toolkit (NEAT)  

E-Print Network [OSTI]

(CO 2 ), carbon monoxide (CO), volatile organic compounds (VOC), particulates (PM), air velocity (AIR_VEL), light levels at 3 locations (LGH), and a photometric camera that analyzes brightness/contrast and glare. The sensor outputs are recorded...

Kim, S. H.; Srivastava, V.; Aziz, A.

2005-01-01T23:59:59.000Z

208

Vapor intrusion modeling : limitations, improvements, and value of information analyses  

E-Print Network [OSTI]

Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

Friscia, Jessica M. (Jessica Marie)

2014-01-01T23:59:59.000Z

209

Aerosol optical and hygroscopic properties during TexAQS-GoMACCS 2006 and their impact on aerosol  

E-Print Network [OSTI]

by diesel-fueled mobile sources and from the numerous coal- fired industries and power generation stations and power plants, with emissions rich in reactive volatile organic compounds (VOCs) and NOX [Ryerson et al

210

A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States  

E-Print Network [OSTI]

Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

Sun, Lin, S.M. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

211

Climate change, ambient ozone, and health in 50 US cities Michelle L. Bell & Richard Goldberg & Christian Hogrefe &  

E-Print Network [OSTI]

Climate change, ambient ozone, and health in 50 US cities Michelle L. Bell & Richard Goldberg Haven, CT 06511, USA e-mail: michelle.bell@yale.edu R. Goldberg Center for Climate Systems Research emissions of volatile organic compounds (VOCs),

212

Laboratory simulation of subsurface airflow beneath a building  

E-Print Network [OSTI]

Vapor intrusion is the vapor-phase migration of volatile organic compounds (VOCs) into buildings due to subsurface soil or groundwater contamination. Oxygen replenishment rates beneath a building are significant for ...

Corsello, Joseph William

2014-01-01T23:59:59.000Z

213

Study of building material emissions and indoor air quality  

E-Print Network [OSTI]

Building materials and furnishings emit a wide variety of indoor pollutants, such as volatile organic compounds (VOCs). At present, no accurate models are available to characterize material emissions and sorption under ...

Yang, Xudong, 1966-

1999-01-01T23:59:59.000Z

214

Journal of Catalysis 202, 413420 (2001) doi:10.1006/jcat.2001.3301, available online at http://www.idealibrary.com on  

E-Print Network [OSTI]

Academic Press Key Words: photocatalysis; nanoparticles; titanium dioxide; toluene; volatile organic. The nanostructured TiO2 provides a larger surface area for adsorption and decomposition of VOC. Quantum size effects

215

Nez Perce Tribe Formaldehyde Study 2011 Kayla Warden and Etta Axtell-Northwest Indian College  

E-Print Network [OSTI]

volatile organic compounds (VOC) were measured using a Proton Transfer Reaction Mass Spectrometer (PTR Acknowledgements: This research was funded by EPA/FaST DOE and NSF Research Experience for Undergraduates (REU). I

Collins, Gary S.

216

ABSORPTION DES ACIDES GRAS VOLATILS DANS L'OMASUM DE LA VACHE  

E-Print Network [OSTI]

ABSORPTION DES ACIDES GRAS VOLATILS DANS L'OMASUM DE LA VACHE C. DARDILLAT Station de rôle du feuillet et ses capacités d'absorption sont très mal connus car il est difficile d'accé- der à cet organe sans perturber son fonctionnement. Nous avons fixé par effet ventouse une chambre d'absorption

Boyer, Edmond

217

Sample and Implied Volatility in GARCH Models  

E-Print Network [OSTI]

Sample and Implied Volatility in GARCH Models Lajos Horva´th University of Utah Piotr Kokoszka Utah of various GARCH-type models is a function hðq� of the parameter vector q which is estimated by bq. For most distributions of the differences ^2 � hðq� and ^2 � hðbq� for broad classes of GARCH-type models. Even though

Kokoszka, Piotr

218

Measuring Spatial Variability of Vapor Flux to Characterize Vadose-zone VOC Sources: Flow-cell Experiments  

SciTech Connect (OSTI)

A method termed vapor-phase tomography has recently been proposed to characterize the distribution of volatile organic contaminant mass in vadose-zone source areas, and to measure associated three-dimensional distributions of local contaminant mass discharge. The method is based on measuring the spatial variability of vapor flux, and thus inherent to its effectiveness is the premise that the magnitudes and temporal variability of vapor concentrations measured at different monitoring points within the interrogated area will be a function of the geospatial positions of the points relative to the source location. A series of flow-cell experiments was conducted to evaluate this premise. A well-defined source zone was created by injection and extraction of a non-reactive gas (SF6). Spatial and temporal concentration distributions obtained from the tests were compared to simulations produced with a mathematical model describing advective and diffusive transport. Tests were conducted to characterize both areal and vertical components of the application. Decreases in concentration over time were observed for monitoring points located on the opposite side of the source zone from the local–extraction point, whereas increases were observed for monitoring points located between the local–extraction point and the source zone. The results illustrate that comparison of temporal concentration profiles obtained at various monitoring points gives a general indication of the source location with respect to the extraction and monitoring points.

Mainhagu, Jon; Morrison, C.; Truex, Michael J.; Oostrom, Martinus; Brusseau, Mark

2014-10-20T23:59:59.000Z

219

Ammonia volatilization and nitrogen transformations in high pH soils used for beef manure disposal  

E-Print Network [OSTI]

. The total nitrogen losses in the limed treatments were believed to be caused by the high solubility of organic matter in high pH solutions followed by chemical volatilization of nitrogen as ammonia. Most of this ammonia was believed to have remained... as par t of the soil air and was lost when the soil samples were taken from the columns. Denitrification was believed to be responsible for losses in the unlimed treatments. Comparison of final organic and total inorganic nitrogen concen- trationss...

Peters, Robert Edgar

1972-01-01T23:59:59.000Z

220

WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos  

E-Print Network [OSTI]

are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

Mankoff, Jennifer

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Atmos. Chem. Phys., 14, 58715891, 2014 www.atmos-chem-phys.net/14/5871/2014/  

E-Print Network [OSTI]

inventories by measurements of ambient volatile organic compounds in Beijing, China M. Wang1, M. Shao1, W inventories to eval- uate the spatial distribution, species-specific emissions, and source structure of VOCs, whereas current emission inventories suggested that VOC emissions were concentrated in downtown areas. Com

Pierce, Jeffrey

222

Design of Semiconductor-Based Back Reflectors for High Voc Monolithic Multijunction Solar Cells: Preprint  

SciTech Connect (OSTI)

State-of-the-art multijunction cell designs have the potential for significant improvement before going to higher number of junctions. For example, the Voc can be substantially increased if the photon recycling taking place in the junctions is enhanced. This has already been demonstrated (by Alta Devices) for a GaAs single-junction cell. For this, the loss of re-emitted photons by absorption in the underlying layers or substrate must be minimized. Selective back surface reflectors are needed for this purpose. In this work, different architectures of semiconductor distributed Bragg reflectors (DBR) are assessed as the appropriate choice for application in monolithic multijunction solar cells. Since the photon re-emission in the photon recycling process is spatially isotropic, the effect of the incident angle on the reflectance spectrum is of central importance. In addition, the DBR structure must be designed taking into account its integration into the monolithic multijunction solar cells, concerning series resistance, growth economics, and other issues. We analyze the tradeoffs in DBR design complexity with all these requirements to determine if such a reflector is suitable to improve multijunction solar cells.

Garcia, I.; Geisz, J.; Steiner, M.; Olson, J.; Friedman, D.; Kurtz, S.

2012-06-01T23:59:59.000Z

223

GADOLINIUM SOLUBILITY AND VOLATILITY DURING DWPF PROCESSING  

SciTech Connect (OSTI)

Understanding of gadolinium behavior, as it relates to potential neutron poisoning applications at the DWPF, has increased over the past several years as process specific data have been generated. Of primary importance are phenomena related to gadolinium solubility and volatility, which introduce the potential for gadolinium to be separated from fissile materials during Chemical Process Cell (CPC) and Melter operations. Existing data indicate that gadolinium solubilities under moderately low pH conditions can vary over several orders of magnitude, depending on the quantities of other constituents that are present. With respect to sludge batching processes, the gadolinium solubility appears to be highly affected by iron. In cases where the mass ratio of Fe:Gd is 300 or more, the gadolinium solubility has been observed to be low, one milligram per liter or less. In contrast, when the ratio of Fe:Gd is 20 or less, the gadolinium solubility has been found to be relatively high, several thousands of milligrams per liter. For gadolinium to serve as an effective neutron poison in CPC operations, the solubility needs to be limited to approximately 100 mg/L. Unfortunately, the Fe:Gd ratio that corresponds to this solubility limit has not been identified. Existing data suggest gadolinium and plutonium are not volatile during melter operations. However, the data are subject to inherent uncertainties preventing definitive conclusions on this matter. In order to determine if gadolinium offers a practical means of poisoning waste in DWPF operations, generation of additional data is recommended. This includes: Gd solubility testing under conditions where the Fe:Gd ratio varies from 50 to 150; and Gd and Pu volatility studies tailored to quantifying high temperature partitioning. Additional tests focusing on crystal aging of Gd/Pu precipitates should be pursued if receipt of gadolinium-poisoned waste into the Tank Farm becomes routine.

Reboul, S

2008-01-30T23:59:59.000Z

224

Volatiles as a link between planetary interiors and the environment  

E-Print Network [OSTI]

Volatiles derived from planetary interiors influence magma evolution and environmental processes. Over appropriate timescales, Earth's mantle, crust, ocean, and atmosphere constitute coupled systems. The apparently synchronous ...

Black, Benjamin A. (Benjamin Alexander)

2013-01-01T23:59:59.000Z

225

Volatiles in hydrothermal fluids- A mass spectrometric study...  

Open Energy Info (EERE)

Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search OpenEI Reference LibraryAdd to library...

226

Volatility of Gasoline and Diesel Fuel Blends for Supercritical...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be...

227

Ammonia volatilization from N fertilizers surface applied on bermudagrass  

E-Print Network [OSTI]

. The biological activity was measured by trapping the CO in NaOH (0. 422 N). The NH3 which was volatilized from the urea was trapped in boric acid according to Bremner (1965). Volatilized NH and evolved CO were measured daily by titrating the boric acid and 13... was passed over the soil surface, then bubbled into boric acid to trap volatilized NH (Bremner, 1965). Humidified air was used to prevent rapid soil drying which would retard NH volatilization (Ernst and Massey, 1960). The apparatus is diagrammed in Fig. 1...

Panossian, Jack B.

1980-01-01T23:59:59.000Z

228

Red Balloon, Green Balloon, Sensors in the Sky Stacey Kuznetsov1  

E-Print Network [OSTI]

color based on input from attached air quality sensors (exhaust, diesel, or volatile organic compounds). The balloons change color in response to one of exhaust gas, diesel, or VOC's (volatile organic compounds]. Diesel exhaust consists of fine particulate matter emitted by engines and industrial processes [44

Paulos, Eric

229

Supporting Information:1 Contributions of individual reactive biogenic volatile organic compounds to organic2  

E-Print Network [OSTI]

System Laboratory, National Center for22 Atmospheric Research, Boulder, CO USA23 Now at: Air Pollution 8 Université Lille Nord de France, Lille, France16 9 �cole des Mines de Douai, Douai, France17 10

Meskhidze, Nicholas

230

Global Emissions of Terpenoid VOCs from Terrestrial Vegetation in the Last Millennium  

SciTech Connect (OSTI)

We investigated the millennial variability of global BVOC emissions by using two independent numerical models: The Model of Emissions of Gases and Aerosols from Nature (MEGAN), for isoprene, monoterpene and sesquiterpene and Lund-Potsdam-Jena General Ecosystem Simulator (LPJ8 GUESS), for isoprene and monoterpenes. We found the millennial trends of global isoprene emissions to be mostly affected by land cover and atmospheric carbon dioxide changes, whereas monoterpene and sesquiterpene emission were dominated by temperature change. Isoprene emissions declined substantially in regions with large and rapid land cover change. In addition, isoprene emission sensitivity to drought proved to have signicant short term global effects. By the end of the past millennium MEGAN isoprene emissions were 634 TgC yr-1 (13% and 19% less than during during 1750-1850 and 1000- 15 1200, respectively) and LPJ-GUESS emissions were 323 TgC yr-1 (15% and 20% less than during 1750-1850 and 1000-1200, respectively). Monoterpene emissions were 89 TgC yr-1 (10% and 6% higher than during 1750-1850 and 1000-1200, respectively) in MEGAN, and 24 TgC yr-1 (2% higher and 5% 19 20 less than during 1750-1850 and 1000-1200, respectively) in LPJ-GUESS. MEGAN sesquiterpene emissions were 36 TgC yr-1 (10% and 4% higher than during1750-1850 and 1000-1200, respectively). Although both models capture similar We investigated the millennial variability of global BVOC emissions by using two independent numerical models: The Model of Emissions of Gases and Aerosols from Nature (MEGAN), for isoprene, monoterpene and sesquiterpene and Lund-Potsdam-Jena General Ecosystem Simulator (LPJ8GUESS), for isoprene and monoterpenes. We found the millennial trends ofglobal isoprene emissions to be mostly a*ected by land cover and atmospheric carbon dioxide changes, whereas monoterpene and sesquiterpene emission were dominated by temperature change. Isoprene emissions declined substantially in regions with large and rapid land cover change. In addition, isoprene emission sensitivity to drought proved to have signifcant short term global effects. By the end of the past millennium MEGAN isoprene emissions were 634 TgC yr-1 (13% and 19% less than during during 1750-1850 and 1000- 1200, respectively) and LPJ-GUESS emissions were 323 TgC yr-1 (15% and 16 17 20% less than during 1750-1850 and 1000-1200, respectively). Monoterpene emissions were 89 TgC yr-1 (10% and 6% higher than during 1750-1850 and 18 1000-1200, respectively) in MEGAN, and 24 TgC yr-1 (2% higher and 5% less than during 1750-1850 and 1000-1200, respectively) in LPJ-GUESS. MEGAN sesquiterpene emissions were 36 TgC yr-1 (10% and 4% higher than during1750-1850 and 1000-1200, respectively). Although both models capture similar emission trends, the magnitude of the emissions are different. This highlights the importance of building better constraints on VOC emissions from terrestrial vegetation.emission trends, the magnitude of the emissions are different. This highlights the importance of building better constraints on VOC emissions from terrestrial vegetation.

Acosta Navarro, J. C.; Smolander, S.; Struthers, H.; Zorita, E.; Ekman, A. M.; Kaplan, J. O.; Guenther, Alex B.; Arneth, A.; Riipinen, I.

2014-06-16T23:59:59.000Z

231

A Comment on \\The Cross-Section of Volatility and Expected Returns": The Statistical Signi  

E-Print Network [OSTI]

on "The Cross-Section of Volatility and Expected Returns":on “The Cross-Section of Volatility and Expected Returns”:the pricing of aggregate volatility risk and idiosyncratic

Anderson, Robert M.; Bianchi, Stephen W.; Goldberg, Lisa R.

2012-01-01T23:59:59.000Z

232

PSERC 98-22 "Market Power and Price Volatility in  

E-Print Network [OSTI]

PSERC 98-22 "Market Power and Price Volatility in Restructured Markets for Electricity" Tim Mount-562-3966. #12;MARKET POWER AND PRICE VOLATILITY IN RESTRUCTURED MARKETS FOR ELECTRICITY Tim Mount School.edu Abstract The restructured market for electricity in the UK has experienced a systematic pattern of price

233

CEC-500-2010-FS-017 Volatility of Ultrafine Particulate  

E-Print Network [OSTI]

. Limited research has been done to characterize compressed natural gas mass emissions and practically-volatile and semi-volatile fractions of ultrafine particulate matter emissions from compressed natural gas vehicles compressed natural gas, and emission control technologies that will best protect human health

234

Method and apparatus for destroying organic contaminants in aqueous liquids  

DOE Patents [OSTI]

A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

Donaldson, T.L.; Wilson, J.H.

1993-09-21T23:59:59.000Z

235

Essays on Resource Allocation and Management, Price Volatility and Applied Nonparametrics  

E-Print Network [OSTI]

85 3.4.4 Comparing GARCH and MRS VolatilityMRS and GARCH Conditional Standard Deviation for (a) CCXF. (2002). Improving GARCH Volatility Forecasts with Regime-

Nigatu, Getchew Sisay

2012-01-01T23:59:59.000Z

236

CSTB / CTBA Wood Preservation -Cannes 2001 MEASUREMENT OF VOC EMISSIONS FROM CURATIVE TREATED WOOD  

E-Print Network [OSTI]

Committee for Standardization (CEN) and the International Organization for Standardization (ISO of International Organization for Standardization (ISO) has prepared the draft international standard ISO/DIS 16000 analytical methods are needed. The aim of this paper is to present the new standards prepared by the European

Paris-Sud XI, Université de

237

Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies  

SciTech Connect (OSTI)

This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

2011-09-28T23:59:59.000Z

238

The price fluctuations of the stock market display fascinating properties. The volatility is around one order of magnitude too large than what is predicted  

E-Print Network [OSTI]

Abstract The price fluctuations of the stock market display fascinating properties. The volatility decisions. We also study the price formation and the microstructure of financial markets, at the level of the order book which organizes transactions. We explain why the price is diffusive despite the fact

Paris-Sud XI, Université de

239

Financial distortions and the distribution of global volatility  

E-Print Network [OSTI]

In this thesis, I study the interactions between various aspects of the financial system and macroeconomic volatility in a globally integrated environment. In Chapter 1, I illustrate that an efficient allocation of liquidity ...

Eden, Maya Rachel

2011-01-01T23:59:59.000Z

240

Bootstrap Prediction for Returns and Volatilities in GARCH Models  

E-Print Network [OSTI]

Bootstrap Prediction for Returns and Volatilities in GARCH Models Lorenzo Pascuala , Juan Romob of GARCH processes is proposed. Financial market participants have shown an increasing interest Autoregressive Conditionally Heteroscedastic (GARCH) models, originally introduced by Bollerslev (1986), provide

Ortega, Esther Ruiz

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Forecasting Returns and Volatilities in GARCH Processes Using the Bootstrap  

E-Print Network [OSTI]

Forecasting Returns and Volatilities in GARCH Processes Using the Bootstrap Lorenzo Pascual, Juan generated by GARCH processes. The main advantage over other bootstrap methods previously proposed for GARCH by having conditional heteroscedasticity. Generalized Autoregressive Conditionally Heteroscedastic (GARCH

Romo, Juan

242

Temporal Geochemical Variations In Volatile Emissions From Mount...  

Open Energy Info (EERE)

Temporal Geochemical Variations In Volatile Emissions From Mount St Helens, Usa, 1980-1994 Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

243

Growth History Of Kilauea Inferred From Volatile Concentrations...  

Open Energy Info (EERE)

Concentrations In Submarine-Collected Basalts Abstract Major-element and volatile (H2O, CO2, S) compositions of glasses from the submarine flanks of Kilauea Volcano record its...

244

The impact of fuel price volatility on transportation mode choice  

E-Print Network [OSTI]

In recent years, the price of oil has driven large fluctuations in the price of diesel fuel, which is an important cost component in freight logistics. This thesis explores the impact of fuel price volatility on supply ...

Kim, Eun Hie

2009-01-01T23:59:59.000Z

245

New Air Cleaning Strategies for Reduced Commercial Building Ventilation Energy ? FY11 Final Report  

SciTech Connect (OSTI)

The research carried out in this project focuses on developing novel volatile organic compounds (VOCs) air cleaning technologies needed to enable energy-saving reductions in ventilation rates. we targeted a VOC air cleaning system that could enable a 50% reduction in ventilation rates. In a typical commercial HVAC system that provides a mixture of recirculated and outdoor air, a VOC air cleaner in the supply airstream must have a 15% to 20% VOC removal efficiency to counteract a 50% reduction in outdoor air supply.

Sidheswaran, Meera; Destaillats, Hugo; Cohn, Sebastian; Sullivan, Douglas P.; Fisk, William J.

2011-10-31T23:59:59.000Z

246

Method of increasing biodegradation of sparingly soluble vapors  

DOE Patents [OSTI]

A method for increasing biodegradation of sparingly soluble volatile organic compounds (VOCs) in a bioreactor is disclosed. The method comprises dissolving in the aqueous phase of the bioreactor a water soluble, nontoxic, non-biodegradable polymer having a molecular weight of at least 500 and operable for decreasing the distribution coefficient of the VOCs. Polyoxyalkylene alkanols are preferred polymers. A method of increasing the growth rate of VOC-degrading microorganisms in the bioreactor and a method of increasing the solubility of sparingly soluble VOCs in aqueous solution are also disclosed.

Cherry, Robert S. (Idaho Falls, ID)

2000-01-01T23:59:59.000Z

247

Estimating monthly and state-level NO sub x , SO sub 2 , VOC and CO sub 2 emissions using the MSCET database  

SciTech Connect (OSTI)

This paper describes the Month and State Current Emission Trends (MSCET) database. It describes the methodology used to estimate NO{sub x}, SO{sub 2}, VOC, and CO{sub 2} emissions and the data sources used by the methodology. Selected emissions results from the database are presented. 2 refs., 6 figs.

Cilek, C.M.; Kohout, E.

1992-01-01T23:59:59.000Z

248

Estimating monthly and state-level NO{sub x}, SO{sub 2}, VOC and CO{sub 2} emissions using the MSCET database  

SciTech Connect (OSTI)

This paper describes the Month and State Current Emission Trends (MSCET) database. It describes the methodology used to estimate NO{sub x}, SO{sub 2}, VOC, and CO{sub 2} emissions and the data sources used by the methodology. Selected emissions results from the database are presented. 2 refs., 6 figs.

Cilek, C.M.; Kohout, E.

1992-07-01T23:59:59.000Z

249

Recovery of manganese oxides from spent alkaline and zinc–carbon batteries. An application as catalysts for VOCs elimination  

SciTech Connect (OSTI)

Highlights: • Manganese oxides were synthesized using spent batteries as raw materials. • Spent alkaline and zinc–carbon size AA batteries were used. • A biohydrometallurgical process was employed to bio-lixiviate batteries. • Manganese oxides were active in the oxidation of VOCs (ethanol and heptane). - Abstract: Manganese, in the form of oxide, was recovered from spent alkaline and zinc–carbon batteries employing a biohydrometallurgy process, using a pilot plant consisting in: an air-lift bioreactor (containing an acid-reducing medium produced by an Acidithiobacillus thiooxidans bacteria immobilized on elemental sulfur); a leaching reactor (were battery powder is mixed with the acid-reducing medium) and a recovery reactor. Two different manganese oxides were recovered from the leachate liquor: one of them by electrolysis (EMO) and the other by a chemical precipitation with KMnO{sub 4} solution (CMO). The non-leached solid residue was also studied (RMO). The solids were compared with a MnO{sub x} synthesized in our laboratory. The characterization by XRD, FTIR and XPS reveal the presence of Mn{sub 2}O{sub 3} in the EMO and the CMO samples, together with some Mn{sup 4+} cations. In the solid not extracted by acidic leaching (RMO) the main phase detected was Mn{sub 3}O{sub 4}. The catalytic performance of the oxides was studied in the complete oxidation of ethanol and heptane. Complete conversion of ethanol occurs at 200 °C, while heptane requires more than 400 °C. The CMO has the highest oxide selectivity to CO{sub 2}. The results show that manganese oxides obtained using spent alkaline and zinc–carbon batteries as raw materials, have an interesting performance as catalysts for elimination of VOCs.

Gallegos, María V., E-mail: plapimu@yahoo.com.ar [Pla.Pi.Mu-Planta Piloto Multipropósito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Falco, Lorena R., E-mail: mlfalco@quimica.unlp.edu.ar [Pla.Pi.Mu-Planta Piloto Multipropósito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Peluso, Miguel A., E-mail: apelu@quimica.unlp.edu.ar [Centro de Investigación y Desarrollo en Ciencias Aplicadas, “Dr. J. Ronco” CINDECA (CONICET CCT La Plata), 47 N°257, La Plata, Buenos Aires (Argentina); Sambeth, Jorge E., E-mail: sambeth@quimica.unlp.edu.ar [Centro de Investigación y Desarrollo en Ciencias Aplicadas, “Dr. J. Ronco” CINDECA (CONICET CCT La Plata), 47 N°257, La Plata, Buenos Aires (Argentina); Thomas, Horacio J. [Pla.Pi.Mu-Planta Piloto Multipropósito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina)

2013-06-15T23:59:59.000Z

250

Improved Predictions of Carbon Tetrachloride Contaminant Flow and Transport: Implementation of Kinetic Volatilization and Multicomponent NAPL Behavior  

SciTech Connect (OSTI)

Carbon tetrachloride (CT) was discharged to waste sites that are included in the 200-PW-1 Operable Unit in Hanford 200 West Area. Fluor Hanford, Inc. is conducting a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remedial investigation/feasibility study (RI/FS) for the 200-PW-1 Operable Unit. The RI/FS process and remedial investigations for the 200-PW-1, 200 PW-3, and 200-PW-6 Operable Units are described in the Plutonium/Organic-Rich Process Condensate/Process Waste Groups Operable Unit RI/FS Work Plan. As part of this overall effort, Pacific Northwest National Laboratory (PNNL) was contracted to improve the STOMP simulator (White and Oostrom, 2006) by incorporating kinetic volatilization of nonaqueous phase liquids (NAPL) and multicomponent flow and transport. This work supports the U.S. Department of Energy's (DOE's) efforts to characterize the nature and distribution of CT in the 200 West Area and subsequently select an appropriate final remedy. Previous numerical simulation results with the STOMP simulator have overestimated the effect of soil vapor extraction (SVE) on subsurface CT, showing rapid removal of considerably more CT than has actually been recovered so far. These previous multiphase simulations modeled CT mass transfer between phases based on equilibrium partitioning. Equilibrium volatilization can overestimate volatilization because mass transfer limitations present in the field are not considered. Previous simulations were also conducted by modeling the NAPL as a single component, CT. In reality, however, the NAPL mixture disposed of at the Hanford site contained several non-volatile and nearly insoluble organic components, resulting in time-variant fluid properties as the CT component volatilized or dissolved over time. Simulation of CT removal from a DNAPL mixture using single-component DNAPL properties typically leads to an overestimation of CT removal. Other possible reasons for the discrepancy between observed and simulated CT mass removal during SVE are differences between the actual and simulated (1) SVE flow rates, (2) fluid-media properties, and (3) disposal history (volumes, rates, and timing). In this report, numerical implementation of kinetic volatilization and multicomponent DNAPL flow and transport into the STOMP simulator (White and Oostrom, 2006) is described. The results of several test cases are presented and explained. The addition of these two major code enhancements increases the ability of the STOMP simulator to model complex subsurface flow and transport processes involving CT at the Hanford site.

Oostrom, Martinus; Zhang, Z. F.; Freedman, Vicky L.; Tartakovsky, Guzel D.

2008-09-29T23:59:59.000Z

251

Volatility literature of chlorine, iodine, cesium, strontium, technetium, and rhenium; technetium and rhenium volatility testing  

SciTech Connect (OSTI)

A literature review pertaining to the volatilization of Sr, Cs, Tc (and its surrogate Re), Cl, I and other related species during the vitrification of Hanford Low Level Waste (LLW) streams has been performed and the relevant information summarized. For many of these species, the chemistry which occurs in solution prior to the waste stream entering the melter is important in dictating their loss at higher temperatures. In addition, the interactive effects between the species being lost was found to be important. A review of the chemistries of Tc and Re was also performed. It was suggested that Re would indeed act as an excellent surrogate for Tc in non-radioactive materials testing. Experimental results on Tc and Re loss from sodium aluminoborosilicate melts of temperatures ranging from 900--1350{degrees}C performed at PNL are reported and confirm that Re behaves in a nearly identical manner to that of technetium.

Langowski, M.H.; Darab, J.G.; Smith, P.A.

1996-03-01T23:59:59.000Z

252

Pilot-scale study of the solar detoxification of VOC-contaminated groundwater  

SciTech Connect (OSTI)

The Solar Detoxification Field Experiment was designed to investigate the photocatalytic decomposition of organic contaminants in groundwater at a Superfund site at Lawrence Livermore National Laboratory (LLNL). The process uses ultraviolet (UV) energy, available in sunlight, in conjunction with the photocatalyst, titanium dioxide, to decompose organic chemicals into nontoxic compounds. The field experiment was developed by three federal laboratories: the National Renewable Energy Laboratory (NREL), Sandia National Laboratory (SNLA), and LLNL. The US Department of Energy funded the experiment. The objectives of the pilot-scale study included the advancement of the solar technology into a nonlaboratory waste-remediation environment the compilation of test data to help guide laboratory research and future demonstrations and the development of safe operational procedures. Results of the pilot study are discussed, emphasizing the effect of several process variables on the system performance. These variables include alkalinity, catalyst loading, flow velocity through the reactor, and incident solar UV radiation. The performance of the solar detoxification process are discussed as it relates to concentrating and nonconcentrating collectors.

Mehos, M.; Turchi, C. [National Renewable Energy Lab., Golden, CO (United States)] [National Renewable Energy Lab., Golden, CO (United States); Pacheco, J. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); Boegel, A.J.; Merrill, T.; Stanley, R. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States)

1992-08-01T23:59:59.000Z

253

An advanced hybrid reprocessing system based on UF{sub 6} volatilization and chromatographic separation  

SciTech Connect (OSTI)

To recover U, Pu, MA (Np, Am, Cm) and some specific fission products FPs (Cs, Sr, Tc, etc.) from various spent nuclear fuels (LWR/FBR: Oxide, Metal Fuels), we are studying an advanced hybrid reprocessing system based on UF6 volatilization (Pyro) and chromatographic separation (Aqueous). Spent fuels are de-cladded by means of thermal and mechanical methods and then applied to the fluorination/volatilization process, which selectively recovers the most amount of U. Then, the remained fuel components are converted to oxides and dissolved by HNO{sub 3} solution. Compared to U, since Pu, MA and FPs are significantly less abundant in spent fuels, the scale of the aqueous separation process could become reasonably small and result in less waste. For the chromatographic separation processes, we have prepared different types of porous silica-based organic/inorganic adsorbents with fast diffusion kinetics, improved chemical stability and low pressure drop in a packed column. So they are advantageously applicable to efficient separation of the actinides and FP elements from the fuel dissolved solution. In this work, adsorption and separation behavior of representative actinides and FP elements was studied. Small scale separation tests using simulated and genuine fuel dissolved solutions were carried out to verify the feasibility of the proposed process. (authors)

Wei, Yuezhou [Shanghai Jiao Tong University, 800 Dongchuan Rd., Shanghai 200240 (China); Tohoku University, Aoba-ku, Sendai 980-8578 (Japan); Liu, Ruiqin; Wu, Yan; Zu, Jianhua; Zhao, Long [Shanghai Jiao Tong University, 800 Dongchuan Rd., Shanghai 200240 (China); Mimura, Hitoshi [Tohoku University, Aoba-ku, Sendai 980-8578 (Japan); Shi, Weiqun; Chai, Zhifang [Institute of High Energy Physics, Chinese Academy of Science, Beijing 100049 (China); Yang, Jinling; Ding, Youqian [China Institute of Atomic Energy, Beijing 102413 (China)

2013-07-01T23:59:59.000Z

254

Freeway Short-Term Traffic Flow Forecasting by Considering Traffic Volatility Dynamics and Missing Data Situations  

E-Print Network [OSTI]

, assuming constant variance when perform forecasting. This method does not consider the volatility nature of traffic flow data. This paper demonstrated that the variance part of traffic flow data is not constant, and dependency exists. A volatility model...

Zhang, Yanru

2012-10-19T23:59:59.000Z

255

Quantifying the value that wind power provides as a hedge against volatile natural gas prices  

E-Print Network [OSTI]

Gas Pricing by Regulated Natural Gas Utilities, Docket No.A HEDGE AGAINST VOLATILE NATURAL GAS PRICES Mark Bolinger,A HEDGE AGAINST VOLATILE NATURAL GAS PRICES Mark Bolinger,

Bolinger, Mark; Wiser, Ryan; Golove, William

2002-01-01T23:59:59.000Z

256

Integration of Micro Patterning Techniques into Volatile Functional Materials and Advanced Devices  

E-Print Network [OSTI]

Novel micro patterning techniques have been developed for the patterning of volatile functional materials which cannot be conducted by conventional photolithography. First, in order to create micro patterns of volatile materials (such as bio...

Hong, Jung M.

2010-07-14T23:59:59.000Z

257

Biogenic Potassium Salt Particles as Seeds for Secondary Organic  

E-Print Network [OSTI]

for the condensation of low- or semi-volatile organic compounds from the atmospheric gas phase or multiphase oxidation is most relevant to the activation of cloud condensation nuclei (6). The aerosol samples were collected The fine particles serving as cloud condensation nuclei in pristine Amazonian rainforest air consist mostly

258

Ammonia volatilization from surface application of ammonium sulfate to carbonate systems  

E-Print Network [OSTI]

from surface application of' ammonium fertilizers to calcareous soils 7 Ammonia Volatilization from Limed, Acid Soil Comparison of ammonia vole, tilization from different ammonium fertilizers Other factors affecting ammonia volatilization 10...-Newman-Keul's multiple range analysis of ammonia volatilization from a limed, acid soil supporting Coastal bermudagrass as affected by calcium carbonate . 58 Student-Newman-Keul's multiple range analysis of ammonia volatilization i'rom a limed. , acid soil supporting...

Feagley, Sam Edward

1976-01-01T23:59:59.000Z

259

Organizational Adaptation in Volatile Environments Kathleen M. Carley  

E-Print Network [OSTI]

by environmental volatility. This paper uses a computational model of organizational learning to theorize about within an ecology of learning in which change is occurring at many levels -- individual, organizational organizational adaptation as resulting from strategic maneuvering in a learning ecology will be illustrated using

Sadeh, Norman M.

260

Neuropeptide alterations in the tree shrew hypothalamus during volatile anesthesia  

E-Print Network [OSTI]

Neuropeptide alterations in the tree shrew hypothalamus during volatile anesthesia Laetitia perception and brain cognitive state. Prolonged general anesthesia has an impact on many of these processes anesthesia administered accompanying a neurosurgical procedure. Using a predicted-peptide database and hybrid

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

A Class of Stochastic Volatility Models for Environmental Applications  

E-Print Network [OSTI]

Pharmaceuticals Inc. Ke Wang, Pfizer Inc. F. Jay Breidt, Colorado State University Richard A. Davis, Columbia stochastic volatility modeling to this context, resulting in a stochastic heteroscedastic process (SHP), which is unconditionally stationary and non-Gaussian. Conditional on a latent GP, the SHP

Breidt, F. Jay

262

Ammonia volatilization from soils with surface rice straw residue  

E-Print Network [OSTI]

rice residue and related factors on NH3 volatilization from an acid Beaumont clay (pH 5.4) and an alkaline Lake Charles clay (pH 7.4). The treatments in the greenhouse and lab consisted of all possible combinations of the following variables: surface...

Barghassa, Peyam

1995-01-01T23:59:59.000Z

263

Quantifying the value that energy efficiency and renewable energy provide as a hedge against volatile natural gas prices  

E-Print Network [OSTI]

Gas Pricing by Regulated Natural Gas Utilities, Docket No.a Hedge Against Volatile Natural Gas Prices Mark Bolinger,wake of unprecedented natural gas price volatility during

Bolinger, Mark; Wiser, Ryan; Bachrach, Devra; Golove, William

2002-01-01T23:59:59.000Z

264

Correct quantitative determination of ethanol and volatile compounds in alcohol products  

E-Print Network [OSTI]

Determination of the volume content of ethanol in the alcohol products in practice is usually determined by pycnometry, electronic densimetry, or densimetry using a hydrostatic balance in accordance with Commission Regulation No 2870/2000. However, these methods determine directly only density of the tested liquid sample and does not take into account the effects of other volatile components such as aldehydes, esters and higher alcohols. So they are appropriate only for binary water-ethanol solutions in accordance with international table adopted by the International Legal Metrology Organization in its Recommendation No 22. Availability notable concentrations of the higher alcohols and ethers in different alcohol-based products, e. g. in whisky, cognac, brandy, wine as well as in waste alcohol and alcohol beverage production, leads to the significant contribution of these compounds in the value of the density of tested alcohol-containing sample. As a result, determination of the volume of ethanol content for ...

Charapitsa, Siarhei; Sytova, Svetlana; Yakuba, Yurii

2014-01-01T23:59:59.000Z

265

Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years  

SciTech Connect (OSTI)

The Model of Emissions of Gases and Aerosols from Nature (MEGANv2.1) together with the Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields were used to create a global emission dataset of biogenic VOCs available on a monthly basis for the time period of 1980 - 2010. This dataset is called MEGAN-MACC. The model estimated mean annual total BVOC emission of 760 Tg(C) yr1 consisting of isoprene (70%), monoterpenes (11%), methanol (6%), acetone (3%), sesquiterpenes (2.5%) and other BVOC species each contributing less than 2 %. Several sensitivity model runs were performed to study the impact of different model input and model settings on isoprene estimates and resulted in differences of * 17% of the reference isoprene total. A greater impact was observed for sensitivity run applying parameterization of soil moisture deficit that led to a 50% reduction of isoprene emissions on a global scale, most significantly in specific regions of Africa, South America and Australia. MEGAN-MACC estimates are comparable to results of previous studies. More detailed comparison with other isoprene in ventories indicated significant spatial and temporal differences between the datasets especially for Australia, Southeast Asia and South America. MEGAN-MACC estimates of isoprene and*-pinene showed a reasonable agreement with surface flux measurements in the Amazon andthe model was able to capture the seasonal variation of emissions in this region.

Sindelarova, K.; Granier, Claire; Bouarar, I.; Guenther, Alex B.; Tilmes, S.; Stavrakou, T.; Muller, J. F.; Kuhn, U.; Stefani, P.; Knorr, W.

2014-09-09T23:59:59.000Z

266

MAGNESIUM ABSORPTION IN THE CCUM OF RATS RELATED TO VOLATILE FATTY ACIDS PRODUCTION  

E-Print Network [OSTI]

MAGNESIUM ABSORPTION IN THE C�CUM OF RATS RELATED TO VOLATILE FATTY ACIDS PRODUCTION Y. RAYSSIGUIER RELATIONS ENTRE L'ABSORPTION C,4ECALE DE MAGNESIUM CHEZ LE RAT ET LA PRODUCTION D'ACIDES GRAS VOLATILS du caecum, pH, acides gras volatils, activité microbienne. Introduction The mode of magnesium

Paris-Sud XI, Université de

267

Flameless thermal oxidation. Innovative technology summary report  

SciTech Connect (OSTI)

The Flameless Thermal Oxidizer (FTO) is a commercial technology offered by Thermatrix, Inc. The FTO has been demonstrated to be an effective destructive technology for process and waste stream off-gas treatment of volatile organic compounds (VOCs), and in the treatment of VOC and chlorinated volatile organic compounds (CVOCs) off-gases generated during site remediation using either baseline or innovative in situ environmental technologies. The FTO process efficiently converts VOCs and CVOCs to carbon dioxide, water, and hydrogen chloride. When FTO is coupled with a baseline technology, such as soil vapor extraction (SVE), an efficient in situ soil remediation system is produced. The innovation is in using a simple, reliable, scalable, and robust technology for the destruction of VOC and CVOC off-gases based on a design that generates a uniform thermal reaction zone that prevents flame propagation and efficiently oxidizes off-gases without forming products of incomplete combustion (PICs).

NONE

1995-09-01T23:59:59.000Z

268

Flameless Thermal Oxidation. Innovative Technology Summary Report  

SciTech Connect (OSTI)

The Flameless Thermal Oxidizer (FTO) is a commercial technology offered by Thermatrix, Inc. The FTO has been demonstrated to be an effective destructive technology for process and waste stream off-gas treatment of volatile organic compounds (VOCs), and in the treatment of VOC and chlorinated volatile organic compounds (CVOCs) off-gases generated during site remediation using either baseline or innovative in situ environmental technologies. The FTO process efficiently converts VOCs and CVOCs to carbon dioxide, water, and hydrogen chloride. When FTO is coupled with a baseline technology, such as soil vapor extraction (SVE), an efficient in situ soil remediation system is produced. The innovation is in using a simple, reliable, scalable, and robust technology for the destruction of VOC and CVOC off-gases based on a design that generates a uniform thermal reaction zone that prevents flame propagation and efficiently oxidizes off-gases without forming products of incomplete combustion (Plcs ).

None

1995-09-01T23:59:59.000Z

269

Highly efficient inverted organic solar cells using amino acid modified indium tin oxide as cathode  

SciTech Connect (OSTI)

In this paper, we report that highly efficient inverted organic solar cells were achieved by modifying the surface of indium tin oxide (ITO) using an amino acid, Serine (Ser). With the modification of the ITO surface, device efficiency was significantly enhanced from 0.63% to 4.17%, accompanied with an open circuit voltage (Voc) that was enhanced from 0.30?V to 0.55?V. Ultraviolet and X-ray photoelectron spectroscopy studies indicate that the work function reduction induced by the amino acid modification resulting in the decreased barrier height at the ITO/organic interface played a crucial role in the enhanced performances.

Li, Aiyuan; Nie, Riming; Deng, Xianyu, E-mail: xydeng@hitsz.edu.cn [Research Center for Advanced Functional Materials and Devices, Shenzhen Key Laboratory of Advanced Materials, School of Materials Science and Engineering, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055 (China); Wei, Huaixin; Li, Yanqing; Tang, Jianxin [Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123 (China); Zheng, Shizhao; Wong, King-Young [Department of Physics, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong (China)

2014-03-24T23:59:59.000Z

270

Temperature-driven decoupling of key phases of organic matter degradation in marine sediments  

E-Print Network [OSTI]

organic matter is further hydrolyzed and fermented to LMW-DOC, such as volatile fatty acids (VFAs) (2 (9­12). The organic carbon consumed by sulfate- reducing bacteria is often VFAs, such as acetic acid is recycled or buried. A diverse consor- tium of microorganisms that hydrolyze, ferment, and terminally

Weston, Nathaniel B.

271

Final Report for Organic Partitioning Resulting from Operation of an INTEC Double-needle Sampler  

SciTech Connect (OSTI)

The double needle sampler testing is a continuation of previous test series that investigated the fate of organic species in the Process Equipment Waste Evaporator (PEWE) system at the Idaho Nuclear Technology and Engineering Center (INTEC). This test series was designed to investigate the effects of operation of the double needle sampling systems on volatile organic constituents in an acidic feed matrix.

Michael B. Heiser

2003-09-01T23:59:59.000Z

272

Method for refreshing a non-volatile memory  

DOE Patents [OSTI]

A non-volatile memory and a method of refreshing a memory are described. The method includes allowing an external system to control refreshing operations within the memory. The memory may generate a refresh request signal and transmit the refresh request signal to the external system. When the external system finds an available time to process the refresh request, the external system acknowledges the refresh request and transmits a refresh acknowledge signal to the memory. The memory may also comprise a page register for reading and rewriting a data state back to the memory. The page register may comprise latches in lieu of supplemental non-volatile storage elements, thereby conserving real estate within the memory.

Riekels, James E. (New Hope, MN); Schlesinger, Samuel (Aventura, FL)

2008-11-04T23:59:59.000Z

273

Comments on Americium Volatilization during Fuel Fabrication for Fast Reactors  

SciTech Connect (OSTI)

The physical processes relevant to the fabrication of metallic and ceramic nuclear fuels are analyzed, with attention to recycling of fuels containing U, Pu, and minor volatile actinides for the use in fast reactors. This analysis is relevant to the development of a process model that can be used for the numerical simulation and prediction of the spatial distribution of composition in the fuel, an important factor in fuel performance.

Sabau, Adrian S [ORNL; Ohriner, Evan Keith [ORNL

2008-01-01T23:59:59.000Z

274

New, improved equation solves for volatile oil, condensate reserves  

SciTech Connect (OSTI)

A new generalized material-balance equation (GMBE) can be applied to the full range of reservoir fluids, including volatile oil and gas condensate. The GMBE replaces the nearly 60-year-old conventional material-balance equation (CMBE). Material balance methods are routinely used by petroleum engineers to estimate reserves. The so-called straight-line methods are the most common. Two of the most popular are: P/z-plot for estimating gas reserves in a dry-gas reservoir; and Havlena and Odeh method for estimating original oil-in-place (N) and original gas-in-place (G) in a black-oil reservoir. A major shortcoming of these and other straight-line methods is that none apply to the full range of reservoir fluids and very few, if any, deal satisfactorily with volatile oil and rich gas condensate. Also, the limits of the methods are not well defined. As drilling goes deeper and more volatile oil and gas-condensate reservoirs are discovered, there is a growing need for a general straight-line method to estimate N and G. For the GMBE, no restrictions are placed on the initial fluid compositions.

Walsh, M.P. (Petroleum Recovery Research Inst., Austin, TX (United States))

1994-08-22T23:59:59.000Z

275

Position Paper on Practicable Performance Criteria for the Removal Efficiency of Volatile Radionuclides  

SciTech Connect (OSTI)

As a result of fuel reprocessing, volatile radionuclides may be released from the facility stack if no processes are put in place to remove them. The radionuclides that are of concern in this document are 3H, 14C, 85Kr, and 129I. The question we attempted to answer is how efficient must this removal process be for each of these radionuclides? To answer this question, we examined the three regulations that may impact the degree to which these radionuclides must be reduced before process gases can be released from the facility. These regulations are 40 CFR 61 (EPA 2010a), 40 CFR 190(EPA 2010b), and 10 CFR 20 (NRC 2012). These regulations apply to the total radionuclide release and to a particular organ - the thyroid. Because these doses can be divided amongst all the radionuclides in different ways and even within the four radionuclides in question, we provided several cases. We first looked at the inventories for these radionuclides for three fuel types (PWR UOX, PWR MOX, and AHTGR), several burn-up values, and time out of reactor extending to 200 y. We calculated doses to the maximum exposed individual (MEI) with the EPA code CAP-88 (Rosnick 1992). Finally, we looked at two dose cases. Allocating all of the allowable dose to be used by the volatile radionuclides is one case, but, perhaps, unrealistic. In lieu of this, we arbitrarily selected a value of 10% of the allowable dose to be assigned to the volatile radionuclides. We calculated the required decontamination factors (DFs) for both of these cases, including the case for the thyroid dose for which 14C and 129I were the main contributors. With respect to 129I doses, we found that the highest dose was calculated with iodine as a fine particulate. The dose scaled as the fraction of the total 129I that was particulate. Therefore, we assumed for all of our calculations that 100% of the 129I was particulate and allow the user of the results given here to scale our calculated doses to their needs.

R. T. Jubin; N. Soelberg; D. M. Strachan

2012-03-01T23:59:59.000Z

276

ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS – FINAL REPORT  

E-Print Network [OSTI]

Composite Wood Products, California Air Resources Board.in Air and Emission Rates from Wood Products Using a LargeComposite Wood Products, California Air Resources Board.

Maddalena, Randy L.

2008-01-01T23:59:59.000Z

277

Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Performance Building  

E-Print Network [OSTI]

Efficiency and Renewable Energy, Building Technologiesand Renewable Energy, Office of Building Technology, State,

Ortiz, Anna C.

2010-01-01T23:59:59.000Z

278

In-situ remediation system for volatile organic compounds with deep recharge mechanism  

DOE Patents [OSTI]

A method and apparatus for the treatment and remediation of a contaminated aquifer in the presence of an uncontaminated aquifer at a different hydraulic potential. The apparatus consists of a wellbore inserted through a first aquifer and into a second aquifer, an inner cylinder within the wellbore is supported and sealed to the wellbore to prevent communication between the two aquifers. Air injection is used to sparge the liquid having the higher static water level and, to airlift it to a height whereby it spills into the inner cylinder. The second treatment area provides treatment in the form of aeration or treatment with a material. Vapor stripped in sparging is vented to the atmosphere. Treated water is returned to the aquifer having the lower hydraulic potential.

Jackson, Jr., Dennis G. (Augusta, GA); Looney, Brian B. (Aiken, SC); Nichols, Ralph L. (Augusta, SC); Phifer, Mark A. (Augusta, SC)

2001-01-01T23:59:59.000Z

279

Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform  

E-Print Network [OSTI]

) and observe an integrated effect from what is called an upwind footprint area. Previous such studies have been limited to a few cities: Nemitz et al. (2002) and Dorsey et al. (2002) measured particle and CO 2 fluxes above the city of Edinburgh, UK, while M... intercomparison tests ..................................... 28 2.5.2. Quantification............................................................................. 30 2.5.3. Footprint analysis...

Park, Chang Hyoun

2011-08-08T23:59:59.000Z

280

Impacts of herbaceous bioenergy crops on atmospheric volatile organic composition and potential consequences  

E-Print Network [OSTI]

mandate, and bioenergy is at the center of attention as a viable alternative for fossil fuels. However of atmospheric particulates, and interactions between plants and arthropods. Our data and projections indicate

DeLucia, Evan H.

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Hybrid membranes and their use in volatile organic compound/air separations  

E-Print Network [OSTI]

of membrane. This housing is equipped with a gasket seal between the high and low pressure sides ol tbe membrane. While the feed/retentate side of the membrane is held at 20-30 in HtO above atmospheric pressure, the permeate side is held at approximately...

Krohn, John Eric

2001-01-01T23:59:59.000Z

282

A study of the tropospheric oxidation of volatile organic compounds using chemical ionization mass spectrometry  

E-Print Network [OSTI]

The mechanisms and kinetics of reactions important to the troposphere have been investigated using a high pressure, turbulent, discharge-flow technique coupled to a chemical ionization mass spectrometer. The ability to ...

Broekhuizen, Keith Edward, 1974-

2002-01-01T23:59:59.000Z

283

Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area  

E-Print Network [OSTI]

and dispersion of a Mexico City pollution out- flow eventon air pollution in the Mexico City Metropolitan Area,pollution transport during the MILAGRO-2006 campaign: a case study of a major Mexico

2010-01-01T23:59:59.000Z

284

Adsorption and desorption of binary mixtures of volatile organic contaminants on soil  

E-Print Network [OSTI]

, the potential theory and the ideal adsorbed solution theory for mixture adsorption were also evaluated for prediction of the experimental results for binary adsorption. All models failed for prediction of the BET type III isotherms when methanol was present...

Guo, Yang

1995-01-01T23:59:59.000Z

285

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity  

E-Print Network [OSTI]

methyl-tertiary-butyl- ether (MTBE) and the biomass burningfrom all source categories. MTBE is a gasoline additive andwith the fuel tracer MTBE (e.g. 0.82 for MTBE/benzene).

Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

2009-01-01T23:59:59.000Z

286

Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area  

E-Print Network [OSTI]

Methanol Ethanol Acetone MEK MTBE CO Methane UCI UCI TOGA/methyl tertiary butyl ether (MTBE), and toluene all ratioedthe observed decay. For MTBE, also a species that is not

2010-01-01T23:59:59.000Z

287

Sampling Throughout The Hydrologic Cycle To Characterize Sources Of Volatile Organic  

E-Print Network [OSTI]

ether (MTBE) are sufficiently high to cause detection in ground water, whereas atmospheric that point sources of MTBE, such as spills or infiltration of urban runoff, are also prevalent are widespread. MTBE is detected less frequently in observation wells that tap 10- to 15-year-old ground water

Torgersen, Christian

288

QUANTIFYING NON-POINT SOURCES OF VOLATILE ORGANIC COMPOUNDS IN STORMWATER FROM A PARKING LOT  

E-Print Network [OSTI]

-butyl ether (MTBE) on urban particles indicates a site- specific interaction between MTBE and a particulate is a possible source only for the gasoline oxygenate methyl tert-butyl ether (MTBE). Lopes and Bender (1998

289

Removal of volatile organic compounds from polluted air in a reverse flow reactor: An experimental study  

SciTech Connect (OSTI)

An experimental study of the reverse flow reactor for the purification of contaminated air has been carried out. An experimental reactor with an inner diameter of 0.145 m has been constructed. It almost completely reached the goal of an adiabatically operating system. The influence of several operating parameters such as gas velocity, cycle period, chemical character, and concentration of the pollutants and reactor pressure are discussed. The reactor could be operated autothermally provided that the inlet concentrations were sufficiently high. If a mixture of contaminants is fed to the reactor, it might be necessary to increase the total hydrocarbon concentration to assure an autothermal process. Increasing the reactor pressure will hardly change the axial temperature profiles, if the mass flux is kept constant. Increasing the mass flow rate will lead to a higher plateau temperature. Not only the reactor behavior at fixed operating conditions, but also the response of the reactor toward variations in inlet conditions is reported.

Beld, B. van de; Borman, R.A.; Derkx, O.R.; Woezik, B.A.A. van; Westerterp, K.R. (Univ. of Twente, Enschede (Netherlands). Dept. of Chemical Engineering)

1994-12-01T23:59:59.000Z

290

Methyl halide and biogenic volatile organic compound fluxes from perennial bioenergy crops and annual arable crops   

E-Print Network [OSTI]

The depletion of fossil fuel resources, pollution concerns and the challenge of energy security are driving the search for renewable energy sources. The use of lignocellulosic plant biomass as an energy source is increasing ...

Morrison, Eilidh Christina

2013-11-28T23:59:59.000Z

291

Impact of California Reformulated Gasoline on Motor Vehicle Emissions. 2. Volatile Organic Compound Speciation and Reactivity  

E-Print Network [OSTI]

California Reformulated Gasoline On Motor Vehicle EmissionsCalifornia Reformulated Gasoline on Motor Vehicle EmmissionsBerkeley Environ. ScLTechnoL gasoline Impact California of

Kirchstetter, Thomas; Singer, Brett; Harley, Robert

1999-01-01T23:59:59.000Z

292

Factors Affecting Indoor Air Concentrations of Volatile Organic Compounds at a Site of Subsurface Gasoline Contamination  

E-Print Network [OSTI]

AT A SITE OF SUBSURFACE GASOLINE CONTAMINATION Marc L.A T A SITE OF SUBSURFACE GASOLINE CONTAMINATION Marc L.a site contaminated with gasoline. Although the high V O C

Fischer, M.L.

2011-01-01T23:59:59.000Z

293

E-Print Network 3.0 - ambient volatile organic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- Department of Chemistry and Biochemistry, University of Colorado at Boulder Collection: Chemistry ; Environmental Sciences and Ecology 55 Generating Methane Gas From Manure...

294

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity  

E-Print Network [OSTI]

mixing ratios and vertical wind speed plotted as a functionPanel: De-trended vertical wind speed (blue) and toluene (between toluene and vertical wind speed. Dashed curve

Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

2009-01-01T23:59:59.000Z

295

Quantitative and qualitative sensing techniques for biogenic volatile organic compounds and their oxidation products  

E-Print Network [OSTI]

M. Porter, H. Fuelberg, J. Halland and D. B. Millet, J.Porter, H. Fuelberg, J. Halland, T. H. Bertram, R. C. Cohen,

Kim, Saewung; Guenther, Alex; Apel, Eric

2013-01-01T23:59:59.000Z

296

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity  

E-Print Network [OSTI]

P. R. , and Hao, W. M. : Emissions from forest fires nearM. O. and Merlet, P. : Emission of trace gases and aerosolsW. : Automo- bile Emissions of Acetonitrile: Assessment of

Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

2009-01-01T23:59:59.000Z

297

In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Improving Fan System Performance aEnginesInEnergyExhaust

298

Three-Dimensional Simulation of Volatile Organic Compound Mass Flux from  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1A: HandlingJefferson Lab ThreeMonkeysthe

299

Detecting Volatile Organic Compounds from Orbit J. J. Harrison & P. F. Bernath  

E-Print Network [OSTI]

ethane retrievals are currently being optimised by updating and improving the microwindow set. Propane cross sections have also been determined from spectra recorded at the MSF. Propane 215 K Propane Q

300

Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area  

E-Print Network [OSTI]

C-130 T0 T1 G1 Ethane Propane i-Butane n-Butane i-Pentane n-ppbv) Ethane Ethene Ethyne Propane Propene i-Butane n-Butanee.g. , ethane, ethene, propane, propane, methanol, ethanol,

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Cyclic membrane separation process  

DOE Patents [OSTI]

A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In the first part of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the second part, the membrane is inoperative while gas pressure rises in the ullage. In one aspect of this invention, a vacuum is drawn in the membrane separation unit thus reducing overall VOC emissions.

Nemser, Stuart M.

2005-05-03T23:59:59.000Z

302

Quarterly sampling of the wetlands along the old F-Area effluent ditch, Revision 1  

SciTech Connect (OSTI)

In May 1994, well point water and bucket samples were collected for tritium and volatile organic compounds in the wetlands along the old F-Area effluent ditch south of 643-E (old burial ground). The well point samples were collected from seven locations and the bucket samples from four locations. Results support that T and VOCs originating from 643-E are outcropping in the wetlands near this ditch. Based on differences in tritium contents at each location, it was determined that the sampling devices intercepted different groundwater flow paths; however, when VOCs were normalized, based on differences in T, resulting well point and bucket VOCs were comparable in most cases.

Dixon, K.L.; cummins, C.L.

1994-05-01T23:59:59.000Z

303

Equation calculates activated carbon's capacity for adsorbing pollutants  

SciTech Connect (OSTI)

Adsorption on activated carbon is an effective method for removing volatile organic compound (VOC) contaminants from gases. A new, simple equation has been developed for calculating activated carbon's adsorption capacity as a function of the VOC concentration in the gas. The correlation shows good agreement with experimental results. Results from the equation are applicable for conditions commonly encountered in air pollution control techniques (25 C, 1 atm). The only input parameters needed are VOC concentrations and a table of correlation coefficients for 292 C[sub 8]-C[sub 14] compounds. The table is suitable for rapid engineering usage with a personal computer or hand calculator.

Yaws, C.L.; Bu, L.; Nijhawan, S. (Lamar Univ., Beaumont, TX (United States))

1995-02-13T23:59:59.000Z

304

Improvement of SOFC Electrodes through Catalyst Infiltration & Control of Cr Volatilization from FeCr Components  

SciTech Connect (OSTI)

This presentation discusses the improvement of SOFC electrodes through catalyst infiltration and control of Cr volatilization from FeCr components.

Visco, S.J.; Jacobson, C.; Kurokawa, H.; Sholklapper, T.; Lu, C.; De Jonghe, L.

2005-01-28T23:59:59.000Z

305

Oil consumption, pollutant emission, oil proce volatility and economic activities in selected Asian Developing Economies.  

E-Print Network [OSTI]

??It is now well established in the literature that oil consumption, oil price shocks, and oil price volatility may impact the economic activities negatively. Studies… (more)

Rafiq, Shuddhasattwa

2009-01-01T23:59:59.000Z

306

Stochastic volatility models with persistent latent factors: theory and its applications to asset prices  

E-Print Network [OSTI]

consider the nonlinear nonstationary state-space model given by yt = radicalbig f(xt,?) ut, xt+1 = ?xt +vt+1,(2.1) where I make the following assumptions: Assumption 1: The volatility function is given by (2.2) f(xt,?) = µ+ ?1+exp(??(x t ??)) , where ? = (µ.... Assumption 2: (xt) is a scalar latent volatility factor and |?| ? 1, I describe the volatility factor, (xt) explicitly in the transition equation because I am interested in the linkage between it and macro economic fundamentals. I assume that this volatility...

Lee, Hyoung Il

2008-10-10T23:59:59.000Z

307

E-Print Network 3.0 - acidos grasos volatiles Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

signal that triggers the release of plant volatiles; one or more elicitors from the oral secretion allow Source: Par, Paul W. - Department of Chemistry and Biochemistry, Texas...

308

Volatilities of Actinide and Lanthanide N,NDimethylaminodiboranate Chemical Vapor Deposition  

E-Print Network [OSTI]

,§ Gregory S. Girolami,*,§ Christopher J. Cramer, and Laura Gagliardi*, Department of Chemistry volatile forms during sublimation. INTRODUCTION Lanthanide-containing materials, such as lanthanide oxides

Girolami, Gregory S.

309

1 Emerging versus developed volatility indexes. The comparison of VIW20 and VIX index.1  

E-Print Network [OSTI]

Modeling of financial markets volatility is one of the most significant issues of contemporary finance, especially while analyzing high-frequency data. Accurate quantification and forecast of volatility are of immense importance in risk management (VaR models, stress testing and worst case scenario), models of capital market and options valuation techniques. What we show in this paper is the methodology for calculating volatility index for Polish capital market (VIW20 – index anticipating expected volatility of WIG20 index). The methods presented are based on VIX index (VIX White Paper, 2003) and enriched with necessary modifications corresponding with the character of Polish options market. Quoted on CBOE, VIX index is currently known as the best measure of capital investment risk perfectly illustrating the level of fear and emotions of market participants. The conception of volatility index is based on combination of realized volatility and implied volatility which, using methodology of Derman et al. (1999) and reconstructing volatility surface, reflects both volatility smile as well as its term structure. The research is carried out using high-frequency data (i.e. tick data) for index options on WIG20 index for the period November 2003- May 2007, in other words, starting with the introduction of options by Warsaw Stock

Robert ?lepaczuk; Grzegorz Zakrzewski

310

Field measurements of ammonia volatilization from surface applications of nitrogen fertilizers to a calcareous soil  

E-Print Network [OSTI]

to measure volatilized NH3 in the labora- tory. A) Vacuum pump, B) Boric acid trap to collect volatilized NH ~ C) NH3 volatilization chamber, D) Trkp to re- move NH3 from incoming air . . . . . . . . . . . 21 A schematic of the apparatus used to make... direct measurements of NH losses in the field. A) Vacuum pum), B) Boric acid trap, C) NH volatilization chamber, consisting of metal cylinder and plexi- glass top The cumulative NH losses over time for four rates of' a)plication of urea...

Hargrove, W. L

1977-01-01T23:59:59.000Z

311

Organic geochemistry and organic petrography  

SciTech Connect (OSTI)

The Vermillion Creek coals and shales contain dominantly humic organic matter originating from woody plant tissues except for one shale unit above the coals, which contains hydrogen-rich kerogen that is mostly remains of filamentous algae, of likely lacustrine origin. The coals have two unusual features - very low inertinite content and high sulfur content compared to mined western coals. However, neither of these features points to the limnic setting reported for the Vermillion Creek sequence. The vitrinite reflectance of Vermillion Creek shales is markedly lower than that of the coals and is inversely proportional to the H/C ratio of the shales. Rock-Eval pyrolysis results, analyses of H, C, and N, petrographic observations, isotope composition of organic carbon, and amounts and compositions of the CHCl/sub 3/-extractable organic matter all suggest mixtures of two types of organic matter in the Vermillion Creek coals and clay shales: (1) isotopically heavy, hydrogen-deficient, terrestrial organic matter, as was found in the coals, and (2) isotopically light, hydrogen-rich organic matter similar to that found in one of the clay-shale samples. The different compositions of the Vermillion Creek coal, the unnamed Williams Fork Formation coals, and coals from the Middle Pennsylvanian Marmaton and Cherokee Groups are apparently caused by differences in original plant composition, alteration of organic matter related to different pH conditions of the peat swamps, and slightly different organic maturation levels.

Bostick, N.H.; Hatch, J.R.; Daws, T.A.; Love, A.H.; Lubeck, S.C.M.; Threlkeld, C.N.

1987-01-01T23:59:59.000Z

312

Volatile Loss and Classification of Kuiper Belt Objects  

E-Print Network [OSTI]

Observations indicate that some of the largest Kuiper Belt Objects (KBOs) have retained volatiles in the gas phase, which implies the presence of an atmosphere that can affect their reflectance spectra and thermal balance. Volatile escape rates driven by solar heating of the surface were estimated by Schaller and Brown (2007) (SB) and Levi and Podolak (2009)(LP) using Jeans escape from the surface and a hydrodynamic model respectively. Based on recent molecular kinetic simulations these rates can be hugely in error (e.g., a factor of $\\sim 10^{16}$ for the SB estimate for Pluto). In this paper we estimate the loss of primordial N$_2$ for several large KBOs guided by recent molecular kinetic simulations of escape due to solar heating of the surface and due to UV/EUV heating of the upper atmosphere. For the latter we extrapolate simulations of escape from Pluto (Erwin et al. 2013) using the energy limited escape model recently validated for the KBOs of interest by molecular kinetic simulations (Johnson et al. 2...

Johnson, R E; Young, L A; Volkov, A N; Schmidt, C

2015-01-01T23:59:59.000Z

313

Organic Superconductors  

SciTech Connect (OSTI)

Intense magnetic fields are an essential tool for understanding layered superconductors. Fundamental electronic properties of organic superconductors are revealed in intense (60 tesla) magnetic fields. Properties such as the topology of the Fermi surface and the nature of the superconducting order parameter are revealed. With modest maximum critical temperatures~13K the charge transfer salt organic superconductors prove to be incredibly valuable materials as their electronically clean nature and layered (highly anisotropic) structures yield insights to the high temperature superconductors. Observation of de Haas-van Alphen and Shubnikov-de Haas quantum oscillatory phenomena, magnetic field induced superconductivity and re-entrant superconductivity are some of the physical phenomena observed in the charge transfer organic superconductors. In this talk, I will discuss the nature of organic superconductors and give an overview of the generation of intense magnetic fields; from the 60 tesla millisecond duration to the extreme 1000 tesla microsecond pulsed magnetic fields.

Charles Mielke

2009-02-27T23:59:59.000Z

314

Volatility-- a statistical comparison between the secondary and primary home markets : the lower Cape's volatility and average return compared to three Boston area primary markets  

E-Print Network [OSTI]

This thesis attempts to analyze the long-standing perception that the secondary home market, homes built in and around vacation areas, is more volatile than the primary home market. For the first time, this study measures ...

Knight, Craig, 1971-

2003-01-01T23:59:59.000Z

315

Volatility Forecasts in Financial Time Series with HMM-GARCH Models  

E-Print Network [OSTI]

Volatility Forecasts in Financial Time Series with HMM-GARCH Models Xiong-Fei Zhuang and Lai {xfzhuang,lwchan}@cse.cuhk.edu.hk Abstract. Nowadays many researchers use GARCH models to generate of the two parameters G1 and A1[1], in GARCH models is usually too high. Since volatility forecasts in GARCH

Chen, Yiling

316

Output Growth and Its Volatility: The Gold Standard through the Great Moderation  

E-Print Network [OSTI]

of real GDP growth and some form of a generalized autoregressive conditional heteroskedasticity (GARCH GARCH or exponential GARCH (EGARCH) process, capturing the movement in volatility. The neglect persistence in the conditional volatility or integrated GARCH (IGARCH). That is, typically all persistence

Ahmad, Sajjad

317

Intra-daily variations in volatility and transaction costs in the Credit Default Swap market  

E-Print Network [OSTI]

Intra-daily variations in volatility and transaction costs in the Credit Default Swap market Andras : Credit Default Swap, Intra-daily patterns, Stochastic transaction costs, Volatility, Interdealer market on the Microstructure of Financial Markets in Hong Kong, the 2008 Credit conference in Venice, the Third Annual Risk

Del Moral , Pierre

318

A comparison of option prices under different pricing measures in a stochastic volatility model  

E-Print Network [OSTI]

A comparison of option prices under different pricing measures in a stochastic volatility model with correlation Vicky Henderson Princeton University David Hobson § University of Bath Sam Howison ¶ University option prices in an incomplete stochastic volatility model with correlation. In a general setting, we

Howison, Sam

319

Cross-Section of Option Returns and Volatility Goizueta Business School  

E-Print Network [OSTI]

compute the stock's IV by taking the average of the ATM call and put implied-volatilities. This also-section of stock option returns by constructing decile portfolios of straddles and delta-hedged calls and puts based on sorting stocks on the differ- ence between historical realized volatility and at

320

ORIGINAL ARTICLE Differential volatile emissions and salicylic acid levels from tobacco  

E-Print Network [OSTI]

pv. tabaci (Pstb), with tobacco plants resulted in a different volatile blend, consisting of MeORIGINAL ARTICLE Differential volatile emissions and salicylic acid levels from tobacco plants / Published online: 24 April 2003 Ă? Springer-Verlag 2003 Abstract Pathogen-induced plant responses include

Raina, Ramesh

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

System for loading executable code into volatile memory in a downhole tool  

DOE Patents [OSTI]

A system for loading an executable code into volatile memory in a downhole tool string component comprises a surface control unit comprising executable code. An integrated downhole network comprises data transmission elements in communication with the surface control unit and the volatile memory. The executable code, stored in the surface control unit, is not permanently stored in the downhole tool string component. In a preferred embodiment of the present invention, the downhole tool string component comprises boot memory. In another embodiment, the executable code is an operating system executable code. Preferably, the volatile memory comprises random access memory (RAM). A method for loading executable code to volatile memory in a downhole tool string component comprises sending the code from the surface control unit to a processor in the downhole tool string component over the network. A central processing unit writes the executable code in the volatile memory.

Hall, David R. (Provo, UT); Bartholomew, David B. (Springville, UT); Johnson, Monte L. (Orem, UT)

2007-09-25T23:59:59.000Z

322

Using futures prices to filter short-term volatility and recover a latent, long-term price series for oil  

E-Print Network [OSTI]

Oil prices are very volatile. But much of this volatility seems to reflect short-term,transitory factors that may have little or no influence on the price in the long run. Many major investment decisions should be guided ...

Herce, Miguel Angel

2006-01-01T23:59:59.000Z

323

Summary Report on the Volatile Radionuclide and Immobilization Research for FY2011 at PNNL  

SciTech Connect (OSTI)

The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2011, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogen-based aerogels (i.e., chalcogels). A silica aerogel was tested at ORNL for total I2 sorption capacity. It was determined to have 48 mass% capacity while having little physisorbed I2 (I2 not taken up in the aerogel pores). For 85Kr, metal organic framework (MOF) structures were investigated and a new MOF with about 8 mass% capacity for Xe and Kr. The selectivity can be changed from Xe > Kr to Xe < Kr simply by lowering the temperature below 0 C. A patent disclosure has been filed. Lastly, silicon carbide (SiC) was loaded with Kr. The diffusion of Kr in SiC was found to be less than detectable at 500 C.

Strachan, Denis M.; Chun, Jaehun; Matyas, Josef; Lepry, William C.; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

2011-09-01T23:59:59.000Z

324

Atmos. Chem. Phys., 13, 91419158, 2013 www.atmos-chem-phys.net/13/9141/2013/  

E-Print Network [OSTI]

comprise gas phase volatile organic compounds (VOCs) or condensed phase matter which partitions at least, NEDC) on a chassis dy- namometer in a vehicle test cell. Emissions from the entire NEDC were sampled aging, with aged OA/POA in the range 9­15. A thorough investigation of the composition of the gas phase

Meskhidze, Nicholas

325

CX-011446: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Measurements and Modeling to Quantify Emissions of Methane and Volatile Organic Compounds (VOCs) from Shale Gas Operations CX(s) Applied: B3.1 Date: 11/13/2013 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory

326

Atmos. Chem. Phys., 9, 88838888, 2009 www.atmos-chem-phys.net/9/8883/2009/  

E-Print Network [OSTI]

identified the long range trans- port of pollution associated with Arctic Haze as well as ocean in the lifetime of volatile organic compounds (VOCs) including methane. In addition, summertime concentra- tions of anthropogenic activities in- cluding iron, steel, and ferro-alloy manufacturing; coal com- bustion; oil

327

Air Quality Conformity G.C. Sciara  

E-Print Network [OSTI]

) · Nitrogen Dioxide (NO2) · Ozone (O3) ­ Volatile Organic Compounds (VOC) ­ Oxides of Nitrogen (NOX) · Oxides disease · Contributes to 80,000 premature deaths/year in CA #12;U.S. Sources of Oxides of Nitrogen EPA

Handy, Susan L.

328

Z .Journal of Contaminant Hydrology 43 2000 2544 www.elsevier.comrlocaterjconhyd  

E-Print Network [OSTI]

Abstract The capture and removal of a continuously produced, migrating Volatile Organic Compound Z .VOC the model aquifer. The electrical conduc- tivity of the Kq -spiked water was continuously monitored using by the stripping well, and the lower unaffected by the remediation system. Thereby, the primary factors

Gvirtzman, Haim

329

Atmos. Chem. Phys., 14, 64956510, 2014 www.atmos-chem-phys.net/14/6495/2014/  

E-Print Network [OSTI]

field measurements of volatile organic compounds over a Norway spruce-dominated forest in centralVOC) fluxes from a Norway spruce (Picea abies) tree in central Germany and explored the emission responses emissions from Norway spruce, with monoter- penes and sesquiterpenes accounting for 50.8 ± 7.2 % and 19

Pierce, Jeffrey

330

*Corresponding author. Tel.: #1-510-643-2451; fax: #1-510-643-5098.  

E-Print Network [OSTI]

contributions to acetone mixing ratios in a rural environment Allen H. Goldstein*, Gunnar W. Schade Ecosystem correlated with acetone mixing ratios (r"0.80), suggesting that the quantity of biogenic and anthropogenic of biogenically and anthropogenically emitted volatile organic compounds (VOCs), and biomass burning

Goldstein, Allen

331

A backward-time stochastic Lagrangian air quality model Deyong Wen a,*, John C. Lin a  

E-Print Network [OSTI]

that simulated O3 concentrations usually agree well with observations across sites in rural areas, small towns). Biomass burning from land use change has been accelerating (Setzer et al., 1994), releasing large quantities of NOx (NO ţ NO2) and volatile organic compounds (VOC) to the atmosphere (Chatfield and Delany

Mlllet, Dylan B.

332

In-Situ Contained And Of Volatile Soil Contaminants  

DOE Patents [OSTI]

The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

Varvel, Mark Darrell (Idaho Falls, ID)

2005-12-27T23:59:59.000Z

333

In-Situ Containment and Extraction of Volatile Soil Contaminants  

DOE Patents [OSTI]

The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

Varvel, Mark Darrell

2005-12-27T23:59:59.000Z

334

Relationship between Compost Stability and Extractable Organic Carbon L. Wu and L. Q. Ma*  

E-Print Network [OSTI]

OH-extractable organic carbon (OC) containsfor a better compost quality control and utilization efficiency. The objective found that the OC contentOC concentration was influenced by the total volatile solids and de- of the core HA relative to total dry mass increased whilecreased with curing time for compost with a high

Ma, Lena

335

Organic sponges for cost-effective CVOC abatement. Final report, September 1992--April 1994  

SciTech Connect (OSTI)

Air contaminated with CVOCs (chlorinated volatile organic compounds) arise from air stripping of ground water or from soil and dual phase vapor extraction. A research program was undertaken to develop sorbents better than activated carbon for remediation. Two such sorbents were found: Dow`s XUS polymer and Rohm and Haas` Ambersorb 563 (carbonaceous). Opportunities exist to further develop sorption and biodegradation technologies.

Flanagan, W.P.; Grade, M.M.; Horney, D.P.; Mackenzie, P.D.; Salvo, J.J.; Sivavec, T.M.; Stephens, M.L.

1994-07-01T23:59:59.000Z

336

A Big Data Approach to Analyzing Market Volatility  

SciTech Connect (OSTI)

Understanding the microstructure of the financial market requires the processing of a vast amount of data related to individual trades, and sometimes even multiple levels of quotes. Analyzing such a large volume of data requires tremendous computing power that is not easily available to financial academics and regulators. Fortunately, public funded High Performance Computing (HPC) power is widely available at the National Laboratories in the US. In this paper we demonstrate that the HPC resource and the techniques for data-intensive sciences can be used to greatly accelerate the computation of an early warning indicator called Volume-synchronized Probability of Informed trading (VPIN). The test data used in this study contains five and a half year?s worth of trading data for about 100 most liquid futures contracts, includes about 3 billion trades, and takes 140GB as text files. By using (1) a more efficient file format for storing the trading records, (2) more effective data structures and algorithms, and (3) parallelizing the computations, we are able to explore 16,000 different ways of computing VPIN in less than 20 hours on a 32-core IBM DataPlex machine. Our test demonstrates that a modest computer is sufficient to monitor a vast number of trading activities in real-time ? an ability that could be valuable to regulators. Our test results also confirm that VPIN is a strong predictor of liquidity-induced volatility. With appropriate parameter choices, the false positive rates are about 7percent averaged over all the futures contracts in the test data set. More specifically, when VPIN values rise above a threshold (CDF > 0.99), the volatility in the subsequent time windows is higher than the average in 93percent of the cases.

Wu, Kesheng; Bethel, E. Wes; Gu, Ming; Leinweber, David; Ruebel, Oliver

2013-06-05T23:59:59.000Z

337

Bayesian analysis of GARCH and stochastic volatility: modeling leverage, jumps and heavy-tails for financial time series  

E-Print Network [OSTI]

Bayesian analysis of GARCH and stochastic volatility: modeling leverage, jumps and heavy for two broad major classes of varying volatility model, GARCH and stochastic volatility (SV) models-t errors yields the best performance among the competing models on the return data. Key words: GARCH, Heavy

Wolpert, Robert L

338

Ethanol as Internal Standard for Quantitative Determination of Volatile Compounds in Spirit Drinks by Gas Chromatography  

E-Print Network [OSTI]

The new methodical approach of using ethanol as internal standard in gas chromatographic analysis of volatile compounds in spirit drinks in daily practice of testing laboratories is proposed. This method provides determination of volatile compounds concentrations in spirit drinks directly expressed in milligrams per liter (mg/L) of absolute alcohol according to official methods without measuring of alcohol strength of analyzed sample. The experimental demonstration of this method for determination of volatile compounds in spirit drinks by gas chromatography is described. Its validation was carried out by comparison with experimental results obtained by internal standard method and external standard method.

Charapitsa, Siarhei V; Kulevich, Nikita V; Makoed, Nicolai M; Mazanik, Arkadzi L; Sytova, Svetlana N

2012-01-01T23:59:59.000Z

339

Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries  

DOE Patents [OSTI]

A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper(II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the original organic compounds, is subsequently blended with high level radioactive sludge land transferred to a vitrification facility for processing into borosilicate glass for long-term storage. 2 figs., 3 tabs.

Doherty, J.P.; Marek, J.C.

1987-02-25T23:59:59.000Z

340

Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries  

DOE Patents [OSTI]

A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper (II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the orginal organic compounds, is subsequently blended with high level radioactive sludge and transferred to a virtrification facility for processing into borosilicate glass for long-term storage.

Doherty, Joseph P. (Elkton, MD); Marek, James C. (Augusta, GA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


342

Options introduction and volatility in the EU ETS1 Julien Chevallier 2  

E-Print Network [OSTI]

in the European Union Emissions Trading Scheme (EU ETS), the European Climate Exchange (ECX) has introduced option the introduction of options has increased or decreased volatility in the European Union Emissions Trading Sc

Paris-Sud XI, Université de

343

Volatility of hotel market fundamentals and the determinants of variations between markets  

E-Print Network [OSTI]

How can volatility as well as other dynamics and characteristics in hotel market fundamentals affecting risk be better understood? This paper explores that fundamental question along with other more specific questions that ...

Cason, Brian (Brian Paul)

2010-01-01T23:59:59.000Z

344

HOW TO DISTINGUISH BETWEEN CLOUDY MINI-NEPTUNES AND WATER/VOLATILE-DOMINATED SUPER-EARTHS  

E-Print Network [OSTI]

One of the most profound questions about the newly discovered class of low-density super-Earths is whether these exoplanets are predominately H2-dominated mini-Neptunes or volatile-rich worlds with gas envelopes dominated ...

Benneke, Björn

345

Trapping of volatiles in amorphous water ice. R. M. E. Mastrapa , R. H. Brown  

E-Print Network [OSTI]

were re- leased into the sample chamber at the same pressure as the water, measurements will be taken with a solar system composition gas with the proper ratios of water to volatile. References: [1] Bar-Nun, A., G

Cohen, Barbara Anne

346

Sensitivity of Investor Reaction to Market Direction and Volatility: The Case of Dividend Change Announcements  

E-Print Network [OSTI]

This study examines whether investor reactions are sensitive to the recent direction and/or volatility of underlying market movements. We find dividend change announcements elicit a greater change in stock price when the ...

Koch, Paul D.; Docking, Diane Scott

2004-02-01T23:59:59.000Z

347

A statistical analysis of the natural gas futures market : the interplay of sentiment, volatility and prices  

E-Print Network [OSTI]

This paper attempts to understand the price dynamics of the North American natural gas market through a statistical survey that includes an analysis of the variables influencing the price and volatility of this energy ...

Fazzio, Thomas J. (Thomas Joseph)

2010-01-01T23:59:59.000Z

348

Architectural Techniques For Managing Non-volatile Caches  

SciTech Connect (OSTI)

As chip power dissipation becomes a critical challenge in scaling processor performance, computer architects are forced to fundamentally rethink the design of modern processors and hence, the chip-design industry is now at a major inflection point in its hardware roadmap. The high leakage power and low density of SRAM poses serious obstacles in its use for designing large on-chip caches and for this reason, researchers are exploring non-volatile memory (NVM) devices, such as spin torque transfer RAM, phase change RAM and resistive RAM. However, since NVMs are not strictly superior to SRAM, effective architectural techniques are required for making them a universal memory solution. This book discusses techniques for designing processor caches using NVM devices. It presents algorithms and architectures for improving their energy efficiency, performance and lifetime. It also provides both qualitative and quantitative evaluation to help the reader gain insights and motivate them to explore further. This book will be highly useful for beginners as well as veterans in computer architecture, chip designers, product managers and technical marketing professionals.

Mittal, Sparsh [ORNL] ORNL

2013-01-01T23:59:59.000Z

349

Identification and evaluation of volatile compounds associated with vacuum and modified atmosphere packaged fresh red meats  

E-Print Network [OSTI]

with Lacrobacillus planrarum or Leuconostoc mesenteroides and stored for 28 days at 3'C included acetone, toluene, acetic acid, ethyl acetate, a hydrocarbon and CHCls. The profile of volatiles in packaged sterile loin tissue stored for 28 days was very similar.... , 1979, 1983; Vanderzant et al. , 1986). ~Although many studies have reported these off-odors, very little published information exists relative to the nature of the volatile aroma compounds which result from microbial or enzymatic activity during...

Jackson, Timothy Court

1989-01-01T23:59:59.000Z

350

The performance of a volatile oil reservoir overlain by a gas cap  

E-Print Network [OSTI]

THE PERFORMANCE OF A VOLATILE OIL RESERVOIR OVERLAIN BY A GAS CAP A Thesis By J. RALPH ELLIS, JR. Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August, 1960 Major Subject: PETROLEUM ENGINEERING THE PERFORMANCE OF A VOLATILE OIL RESERVOIR OVERLAIN BY A GAS CAP A Thesis By J. RALPH ELLIS, JR. Approved as to style and content by: hairxnan of Coxnxnittee) (Head...

Ellis, Joseph Ralph, Jr

1960-01-01T23:59:59.000Z

351

Organization Chart - Home  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LSD Logo About Us People & Organization Research News & Events Safety Internal Resources Organization Chart Departments Scientific Staff Directory Committees Organization Chart...

352

Complex Refractive Indices of Thin Films of Secondary Organic Materials by Spectroscopic Ellipsometry from 220 to 1200 nm  

E-Print Network [OSTI]

particles were produced in a flow tube reactor by ozonolysis of volatile organic compounds, including. By comparison, the UV absorption of the monoterpene-derived SOMs was negligible. On the basis of the measured and mode diameter. 1. INTRODUCTION Aerosol particles directly influence Earth's radiative balance

353

Vertical composition gradient effects on original hydrocarbon in place volumes and liquid recovery for volatile oil and gas condensate reservoirs.  

E-Print Network [OSTI]

??Around the world, volatile oil and retrograde gas reservoirs are considered as complex thermodynamic systems and even more when they exhibit vertical composition variations. Those… (more)

Jaramillo Arias, Juan Manuel

2012-01-01T23:59:59.000Z

354

Oxidation and Volatilization from Tungsten Brush High Heat Flux Armor During High Temperature Steam Exposure  

SciTech Connect (OSTI)

Tungsten brush accommodates thermal stresses and high heat flux in fusion reactor components such as plasma facing surfaces or armor. However, inherently higher surface areas are introduced with the brush design. We have tested a specific design of tungsten brush in steam between 500 and 1100°C. Hydrogen generation and tungsten volatilization rates were determined to address fusion safety issues. The brush prepared from 3.2-mm diameter welding rods had a packing density of 85 percent. We found that both hydrogen generation and tungsten volatilization from brush, fixtured to represent a unit within a larger component, were less than projections based upon the total integrated surface area (TSA). Steam access and the escape of hydrogen and volatile oxide from void spaces within the brush are restricted compared to specimens with more direct diffusion pathways to the test environment. Hydrogen generation rates from restrained specimens based on normal surface area (NSA) remain about five times higher than rates based on total surface areas from specimens with direct steam access. Volatilization rates from restrained specimens based upon normal surface area (NSA) were only 50 percent higher than our historic cumulative maximum flux plot (CMFP) for tungsten. This study has shown that hydrogen generation and tungsten volatilization from brush do not scale according to predictions with previously determined rates, but in fact, with higher packing density could approach those from flat surfaces.

Smolik, Galen Richard; Pawelko, Robert James; Anderl, Robert Andrew; Petti, David Andrew

2000-05-01T23:59:59.000Z

355

Erace--an integrated system for treating organic-contaminated sites  

SciTech Connect (OSTI)

The U.S. Department of Energy`s (DOE) Pacific Northwest Laboratory (PNL) is developing a suite of electrical technologies for treating sites contaminated with hazardous organic compounds. These include: (1) Six-Phase Soil Heating (SPSH) to remove volatile and semi-volatile organic compounds from soils; (2) In Situ Corona (ISC) to decompose nonvolatile and bound organic contaminants in soils; (3) High-Energy Corona (HEC) to treat contaminated off-gases; and (4) Liquid Corona (LC) to treat contaminated liquids. These four technologies comprise ERACE (Electrical Remediation at Contaminated Environments), an integrated system for accomplishing site remediation with little or no secondary wastes produced that would require off-site treatment or disposal. Each ERACE technology can be employed individually as a stand-alone treatment process, or combined as a system for total site remediation. For example, an ERACE system for treating sites contaminated with volatile organics would integrate SPSH to remove the contaminants from the soil, LC to continuously treat an aqueous stream condensed out of the soil off-gas, and HEC to treat non-condensibles remaining in the off-gas, before atmospheric release.

Caley, S.M.; Heath, W.O.; Bergsman, T.M.; Gauglitz, P.A.; Pillay, C.; Moss, R.W.; Shah, R.R.; Goheen, S.C.; Camiaoni, D.M.

1994-11-01T23:59:59.000Z

356

LONG-TERM STABILITY TESTING RESULTS USING SURROGATES AND SORBENTS FOR SAVANNAH RIVER SITE ORGANIC AND AQUEOUS WASTESTREAMS - 10016  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) has tasked MSE Technology Applications, Inc. (MSE) with evaluating the long-term stability of various commercially available sorbent materials to solidify two organic surrogate wastestreams (both volatile and nonvolatile), a volatile organic surrogate with a residual aqueous phase, an aqueous surrogate, and an aqueous surrogate with a residual organic phase. The Savannah River Site (SRS) Legacy and F-Canyon plutonium/uranium extraction (PUREX) process waste surrogates constituted the volatile organic surrogates, and various oils constituted the nonvolatile organic surrogates. The aqueous surrogates included a rainwater surrogate and an aqueous organic surrogate. MSE also evaluated the PUREX surrogate with a residual aqueous component with and without aqueous type sorbent materials. Solidification of the various surrogate wastestreams listed above was performed from 2004 to 2006 at the MSE Test Facility located in Butte, Montana. This paper summarizes the comparison of the initial liquid release test (LRT) values with LRT results obtained during subsequent sampling events in an attempt to understand and define the long-term stability characteristics for the solidified wastestreams.

Burns, H.

2009-11-10T23:59:59.000Z

357

A study of the volatile matter of coal as a function of the heating rate  

SciTech Connect (OSTI)

A study of the volatile matter yields as a function of the heating rate was conducted. A suite of 21 coal and coke samples varying in rank from anthracitic to lignitic and heating rates from 10{degrees}C/min to about 450{degrees}C/min were used in the study. Heating rates up to 60{degrees}C per minute, which are typically used in ASTM Test Method 5142 (instrumental Proximate Analysis), were achieved in a macro thermogravimetric analysis (TGA) system. Heating rates of 50-200{degrees}C/min were obtained in a micro TGA system. All measurements were made in a nitrogen atmosphere. The results of the study illustrate the dependence of the volatile matter yield on the heating rate. For most coals and cokes the optimum heating rate for determining volatile matter values that agree with those obtained by ASTM Method D 3175 appears to be in the 100-150{degrees}C range.

Yanes, E.; Wilhite, D.; Riley, J.M. Jr. [Western Kentucky Univ., Bowling Green, KY (United States)] [and others

1996-12-31T23:59:59.000Z

358

Application of Biodegradable Oils (VOS{sup TM}) for Treatment of Chlorinated Ethenes in the Vadose Zone - 12085  

SciTech Connect (OSTI)

Few active remediation alternatives are available to treat residual chlorinated volatile organic compounds (cVOCs) within the vadose zone. Soil vapor extraction (SVE) can be very effective at removing cVOCs in permeable soils; however, recoveries decline substantially in low permeability zones where mass transfer is diffusion-limited. Entrapped cVOCs in these zones represent a slow but continuous source of contamination to underlying groundwater. An ongoing field study was initiated at the Department of Energy's Savannah River Site (SRS) to evaluate an in situ biological treatment technology to address cVOC contamination in the vadose zone. Developed by Savannah River National Laboratory (SRNL), VOS{sup TM} is a thixotropic (shear thinning) formulation of biodegradable oil, water, nutrients, buffers, and de-chlorinating bacteria (Dehalococcoides sp.) that is designed to sequester and biodegrade slow-diffusing cVOCs from unsaturated, low permeable soils. Injection of 871 L (230 gal) of VOS{sup TM} resulted in a rapid and significant decrease in cVOC gas concentration, generation of cVOC daughter products, a decrease in oxygen concentration, and an increase in carbon dioxide and methane production. (authors)

Riha, Brian D.; Noonkester, Jay V.; Looney, Brian B.; Hyde, W. Keith; Walker, Richard W. [Savannah River National Laboratory, Aiken, SC (United States); Richardson, Stephen D.; Elkins, Brad; Beckwith, Walter [EOS Remediation, LLC, Raleigh, NC (United States)

2012-07-01T23:59:59.000Z

359

Method For Removing Volatile Components From A Gel-Cast Ceramic Article  

DOE Patents [OSTI]

A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

Klug, Frederic Joseph (Schenectady, NY); DeCarr, Sylvia Marie (Schenectady, NY)

2004-09-07T23:59:59.000Z

360

Gas-chromatographic identification of volatile products from thermal processing of Bitumen  

SciTech Connect (OSTI)

The variety of bitumen industrial brands is evident in the significant variation of composition and ratio of volatile thermal processing products, which makes their detailed characterization difficult. For that reason, in the authors` opinion a simple and easily reproducible method for gas chromatographic analysis and identification of these substances should be of greater interest than gathering more such results. In this report the authors discuss the selection of an optimal combination of group and individual gas chromatographic methods for identification of volatile thermal processing products in the presence of air, using the example of AP bitumen, the main brand used in Czechoslavakia for production of asphalt. 15 refs., 1 tab.

Zenkevich, I.G.; Ventura, K. [Advanced Chemical Engineering Institute, Pardubice (Czechoslovakia)

1992-03-10T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Method for removing volatile components from a ceramic article, and related processes  

DOE Patents [OSTI]

A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

Klug, Frederic Joseph (Schenectady, NY); DeCarr, Sylvia Marie (Waterford, NY)

2002-01-01T23:59:59.000Z

362

An unexpected journey: experimental insights into magma and volatile transport beneath Erebus volcano, Antarctica  

E-Print Network [OSTI]

fugacity of the volatile component and the concentration of that volatile dissolved in the melt. Because of the poor fit of our CO2 data to a power law regression, the pure-CO2 experiments of Lesne et al. (2011b) were used to create these isobars... /mantle boundary. Seismic and gravitational investigations on and around Ross Island suggest that this boundary is ?20 km deep (Cooper et al., 1994; Finotello et al., 2011; Newhall & Dzurisin, 1989). The evolution of the Erebus cone itself is inferred to have taken...

Iacovino, Kayla

2014-06-10T23:59:59.000Z

363

The effect of chemical dispersants on the solution of volatile liquid hydrocarbons from spilled crude oil  

E-Print Network [OSTI]

THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1982 Major Subject: Oceanography THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Approved as to style and content by...

McDonald, Thomas Joseph

1982-01-01T23:59:59.000Z

364

Final Report - Glass Formulation Testing to Increase Sulfate Volatilization from Melter, VSL-04R4970-1, Rev. 0, dated 2/24/05  

SciTech Connect (OSTI)

The principal objectives of the DM100 and DM10 tests were to determine the impact of four different organics and one inorganic feed additive on sulfate volatilization and to determine the sulfur partitioning between the glass and the off-gas system. The tests provided information on melter processing characteristics and off-gas data including sulfur incorporation and partitioning. A series of DM10 and DM100 melter tests were conducted using a LAW Envelope A feed. The testing was divided into three parts. The first part involved a series of DM10 melter tests with four different organic feed additives: sugar, polyethylene glycol (PEG), starch, and urea. The second part involved two confirmatory 50-hour melter tests on the DM100 using the best combination of reductants and conditions based on the DM10 results. The third part was performed on the DM100 with feeds containing vanadium oxide (V{sub 2}O{sub 5}) as an inorganic additive to increase sulfur partitioning to the off-gas. Although vanadium oxide is not a reductant, previous testing has shown that vanadium shows promise for partitioning sulfur to the melter exhaust, presumably through its known catalytic effect on the SO{sub 2}/SO{sub 3} reaction. Crucible-scale tests were conducted prior to the melter tests to confirm that the glasses and feeds would be processable in the melter and that the glasses would meet the waste form (ILAW) performance requirements. Thus, the major objectives of these tests were to: ? Perform screening tests on the DM10 followed by tests on the DM100-WV system using a LAW -Envelope A feed with four organic additives to assess their impact on sulfur volatilization. ? Perform tests on the DM100-WV system using a LAW -Envelope A feed containing vanadium oxide to assess its impact on sulfur volatilization. ? Determine feed processability and product quality with the above additives. ? Collect melter emissions data to determine the effect of additives on sulfur partitioning and melter emissions. ? Collect and analyze discharged glass to determine sulfur retention in the glass. ? Prepare and characterize feeds and glasses with the additives to confirm that the feeds and the glass melts are suitable for processing in the DM100 melter. ? Prepare and characterize glasses with the additives to confirm that the glasses meet the waste form (ILAW) performance requirements.

Kruger, Albert A.; Matlack, K. A.; Pegg, I. L.; Gong, W.

2013-11-13T23:59:59.000Z

365

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty  

E-Print Network [OSTI]

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty perform research in molecular machines, exotic CHEMISTRY FACULTY RESEARCH INTERESTS Anne M. Andrews, Professor-in-Residence: Understanding how areas of interest include cross- coupling reactions, green chemistry, heterocycle synthesis, and natural

Levine, Alex J.

366

Determination of Henry's law constants of organics in dilute aqueous solutions  

SciTech Connect (OSTI)

Accurate knowledge of Henry's law constants, H, or air/water partitioning coefficients are required to predict the behavior of organic compounds in the environment. In particular, when the compounds are relatively volatile and exhibit low solubility in water, air stripping may be a viable method for above-ground treatment. Henry's law constants of 15 volatile organic compounds in dilute aqueous solutions were measured by the procedure of equilibrium partitioning in a closed system. The method is based upon the measurement of the headspace concentration by gas chromatography. The compounds investigated included six halogenated hydrocarbons, four aromatic hydrocarbons, and five alkanes. The measurements were made at three temperatures between 25 and 45 C. The measured Henry's law constants compared well with the literature data of some liquids. The temperature dependence of Henry's law constant was also studied from the van't Hoff relation.

Hansen, K.C.; Zhou, Zhou; Yaws, C.L.; Aminabhavi, T.M. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemistry)

1993-10-01T23:59:59.000Z

367

An Analysis of Price Volatility in Different Spot Markets for Electricity in the U.S.A.  

E-Print Network [OSTI]

An Analysis of Price Volatility in Different Spot Markets for Electricity in the U.S.A. by Tim important feature. Spot prices for electricity have been very volatile with dramatic price spikes occurring insight into the behavior of spot prices for electricity, and in particular, to model the type

368

Waste Tank Organic Safety Project: Analysis of liquid samples from Hanford waste tank 241-C-103  

SciTech Connect (OSTI)

A suite of physical and chemical analyses has been performed in support of activities directed toward the resolution of an Unreviewed Safety Question concerning the potential for a floating organic layer in Hanford waste tank 241-C-103 to sustain a pool fire. The analysis program was the result of a Data Quality Objectives exercise conducted jointly with staff from Westinghouse Hanford Company and Pacific Northwest Laboratory (PNL). The organic layer has been analyzed for flash point, organic composition including volatile organics, inorganic anions and cations, radionuclides, and other physical and chemical parameters needed for a safety assessment leading to the resolution of the Unreviewed Safety Question. The aqueous layer underlying the floating organic material was also analyzed for inorganic, organic, and radionuclide composition, as well as other physical and chemical properties. This work was conducted to PNL Quality Assurance impact level III standards (Good Laboratory Practices).

Pool, K.H.; Bean, R.M.

1994-03-01T23:59:59.000Z

369

Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review  

SciTech Connect (OSTI)

Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oil–brine–sc-CO{sub 2} system under carbon storage conditions. The solubility of pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by co-solvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oil-brine-sc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and co-solvency, which will require more experimental data from key classes of organic compounds.

Burant, Aniela; Lowry, Gregory V.; Karamalidis, Athanasios K.

2013-01-01T23:59:59.000Z

370

Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform in Houston, Texas: Trends and Tracers  

E-Print Network [OSTI]

and traffic counts except during variable working hours. To assign measured fluxes to local sources, we tested a bulk flux footprint model (Kormann and Meixner model) designed for uniform emission surface areas in this urban, heterogeneous landscape. Tracer...

Hale, Martin C

2014-05-08T23:59:59.000Z

371

Model Estimates of the Contributions of Environmental Tobacco Smoke to Volatile Organic Compound Exposures in Office Buildings  

E-Print Network [OSTI]

vinyl ketone 2,3-Butadione Acrolein Limonene 1,3-Butadieneconcentrations for for acrolein, acetaldehyde and 1,3-

Daisey, J.M.

2008-01-01T23:59:59.000Z

372

The development of a sensitive method to study volatile organic compounds in gaseous emissions of lung cancer cell lines  

E-Print Network [OSTI]

HCO3 producing excess H+ ions in the medium and therefore a fall in pH. This is seen as a color change. 10 When the confluence has reached 90% the cells are ready to be sub-cultured (Fig 2). 50 % cells in media Thawed... patients with no prior treatment for lung cancer. We have used an alternative method for the spectrometric analysis and quantitation of the selected chemical markers. The pre-concentration method involved a Purge and Trap unit with a thermal desorber...

Maroly, Anupam

2005-08-29T23:59:59.000Z

373

French permanent survey on indoor air quality--microenvironmental concentrations of volatile organic compounds in 90 French dwellings  

E-Print Network [OSTI]

-17Apr2012 Author manuscript, published in "7th International Conference, Healthy Buildings 2003, Singapore : Singapore (2003)" #12;350 Proceedings: Healthy Buildings 2003 and time activity diaries

Boyer, Edmond

374

Airborne and ground based measurements of volatile organic compounds using proton transfer reaction mass spectrometry in Texas and Mexico City  

E-Print Network [OSTI]

of toluene elevated as much as 216 parts per billion by volume (ppbv) and ethyl acetate elevated as much as 183 ppbv above background levels were observed during the late night and early morning hours. These plumes indicate the probability of significant...

Fortner, Edward Charles

2009-05-15T23:59:59.000Z

375

ESTIMATING THE VOLATILITY OF SPOT PRICES IN RESTRUCTURED ELECTRICITY MARKETS AND THE IMPLICATIONS FOR OPTION VALUES  

E-Print Network [OSTI]

Draft 1e ESTIMATING THE VOLATILITY OF SPOT PRICES IN RESTRUCTURED ELECTRICITY MARKETS path. Accurate valuation of claims based on competitive electricity prices has proved problematic, as electricity price data are not well represented by traditional commodity price models of Brownian motion

376

Experimental studies of actinide volatilities with application to mixed waste oxidation processors  

SciTech Connect (OSTI)

The transpiration technique is used to measure volatilities of U from U{sub 3}O{sub 8}(s), Pu from PuO{sub 2}(s) and Pu and Am from PuO{sub 2}/2%AmO{sub 2}(s) in the presence of steam and oxygen at temperatures ranging from 900 to 1300{degree}C.

Krikorian, O.H.; Ebbinghaus, B.B.; Condit, R.H.; Adamson, M.G.; Fontes, A.S. Jr.; Fleming, D.L.

1993-04-30T23:59:59.000Z

377

Effects on milk yield and composition of infusions of volatile fatty acids and caseinate into  

E-Print Network [OSTI]

Effects on milk yield and composition of infusions of volatile fatty acids and caseinate isoenergetic infusions of either a low (17 mol/day of 64% acetic, 21% propionic and 15% butyric acids) or high that with infusions, energy and nitrogen needs were met and consisted of 60% maize silage, 10% hay, 21.5% energy

Paris-Sud XI, Université de

378

Fluid saturation and volatile partitioning between melts and hydrous fluids in crustal magmatic systems: The contribution  

E-Print Network [OSTI]

systems, experimental results on the solubility and partitioning of H2O, CO2, S, Cl, F and a few other ......................................................................... 2 Keywords: magmatic volatiles, solubility, water, carbon dioxide, sulfur, halogens 2 1 systems: The contribution of experimental measurements and solubility models Don R. Baker1 and Marina

Boyer, Edmond

379

Separation and Volatility of Locational Marginal Prices in Restructured Wholesale Power Markets  

E-Print Network [OSTI]

1 Separation and Volatility of Locational Marginal Prices in Restructured Wholesale Power Markets (LMPs) in an ISO-managed restructured wholesale power market operating over an AC transmission grid-determining) generation companies induce correlations among neighboring LMPs. Index Terms--Restructured wholesale power

Tesfatsion, Leigh

380

Lunar apatite with terrestrial volatile abundances Jeremy W. Boyce1,2  

E-Print Network [OSTI]

is a high-Al basalt rich in K, rare-earth elements and P (KREEP), consisting dominantly of augite is texturally associated with anhedral apatite having variable Cl and rare-earth-element con- tents is thought to be depleted relative to the Earth in volatile elements such as H, Cl and the alkalis1

Perfect, Ed

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Agriculture and Trade Opportunities for Tanzania: Past Volatility and Future Climate Changerode_672 429..447  

E-Print Network [OSTI]

Agriculture and Trade Opportunities for Tanzania: Past Volatility and Future Climate Changerode_672 global heterogeneity in climate-induced agricultural variability,Tanzania has the potential to substan could thus export grain to countries as climate change increases the likelihood of severe precipitation

Pittendrigh, Barry

382

Accurate dispensing of volatile reagents on demand for chemical reactions in EWOD chips{  

E-Print Network [OSTI]

Accurate dispensing of volatile reagents on demand for chemical reactions in EWOD chips{ Huijiang the use of a filler liquid (e.g., oil). These properties pose challenges for delivering controlled volumes are introduced to the chip, independent of time delays between dispensing operations. On-demand dispensing

383

Integration of Non-volatile Memory into Storage Hierarchy  

E-Print Network [OSTI]

critical dirty blocks in the cache until their subsequent reuse. S et 0 S et 1 S et 3 nor m al cach e S et 1 5 S et 1 3 P ar tition 0 P ar tition 1 P ar tition 2 P ar tition 3 S et 8 S et 9 h ash 1 S et 1 S et 5 S et 4P ar tition cach e S et 2 S et 6... S et 7S et 3 S et 0 h ash 2 h ash 3 h ash 4 1 6 - w ay p er set in nor m al cach e S et 1 0 S et 1 1 S et 1 4 S et 1 2 S et 2 4 - w ay p er set in p ar titioned- cach e Cach e cap acity = 6 4 cach e lines Figure 2.4: The organization...

Qiu, Sheng

2013-12-04T23:59:59.000Z

384

Cyclic membrane separation process  

DOE Patents [OSTI]

A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In one of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the other part, the membrane is inoperative while gas pressure rises in the ullage. Ambient air is charged to the membrane separation unit during the latter part of the cycle.

Bowser, John

2004-04-13T23:59:59.000Z

385

Organic Photovoltaics Philip Schulz  

E-Print Network [OSTI]

Field Effect Transistors Organic Light Emitting Diodes Organic Solar Cells .OFET, OTFT .RF-ID tag 1977 ­ Conductivity in polymers 1986 ­ First heterojunction OPV 1987 ­ First organic light emitting diode (OLED) 1993 ­ First OPV from solution processing 2001 ­ First certified organic solar cell with 2

Firestone, Jeremy

386

Departmental Organization and Management  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Effective immediately, the Departmental organization structure reflected in the chart at Attachment 1 has been approved.

1993-06-10T23:59:59.000Z

387

Coupled Physical/Chemical and Biofiltration Technologies to Reduce Air Emissions from Forest Products Industries  

SciTech Connect (OSTI)

The research is a laboratory and bench-scale investigation of a system to concentrate and destroy volatile organic compounds (VOCs), including hazardous air pollutants, formed from the drying of wood and the manufacture of wood board products (e.g., particle board and oriented strandboard). The approach that was investigated involved concentrating the dilute VOCs (<500 ppmv) with a physical/chemical adsorption unit, followed by the treatment of the concentrated voc stream (2,000 to 2,500 ppmv) with a biofiltration unit. The research program lasted three years, and involved three research organizations. Michigan Technological University was the primary recipient of the financial assistance, the USDA Forest Products Laboratory (FPL) and Mississippi State University (MSU) were subcontractors to MTU. The ultimate objective of this research was to develop a pilot-scale demonstration of the technology with sufficient data to provide for the design of an industrial system. No commercialization activities were included in this project.

Gary D. McGinnis

2001-12-31T23:59:59.000Z

388

Mixed crystal organic scintillators  

DOE Patents [OSTI]

A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

2014-09-16T23:59:59.000Z

389

The impact of crude-oil price volatility on agricultural employment in the United States  

SciTech Connect (OSTI)

This study focuses on the impact of fluctuations in the price of crude oil on agricultural employment in the United States. After reviewing previous assessments of the issue, the existence of an empirical relationship between agricultural employment and crude oil price volatility is established using Granger causality. Subsequently, the nature of the relationship is estimated with the results suggesting that at least three full years are required before the measurable impacts of a percentage change in the real price of crude oil on the change in agricultural employment are exhausted. Finally, the structural stability of the functional relationship between the change in agricultural employment and the volatility of the price of crude oil, the percentage changes in expected net farm income, realized technological innovation, and the wage rate is examined.

Uri, N.D. [Dept. of Agriculture, Washington, DC (United States)

1995-12-31T23:59:59.000Z

390

PII S0016-7037(01)00802-X Volatilization kinetics of silicon carbide in reducing gases: An experimental study with  

E-Print Network [OSTI]

PII S0016-7037(01)00802-X Volatilization kinetics of silicon carbide in reducing gases occurring hexagonal sili- con carbide ( -SiC), and -SiC, the cubic form, are occasion- ally reported

Grossman, Lawrence

391

Vertical composition gradient effects on original hydrocarbon in place volumes and liquid recovery for volatile oil and gas condensate reservoirs  

E-Print Network [OSTI]

Around the world, volatile oil and retrograde gas reservoirs are considered as complex thermodynamic systems and even more when they exhibit vertical composition variations. Those systems must be characterized by an equation of state (EOS...

Jaramillo Arias, Juan Manuel

2000-01-01T23:59:59.000Z

392

Comprehensive verification of new method "Ethanol as Internal Standard" for determination of volatile compounds in alcohol products by gas chromatography  

E-Print Network [OSTI]

Recently proposed new method "Ethanol as Internal Standard" for determination of volatile compounds in alcohol products by gas chromatography is investigated from different sides. Results of experimental study from three different laboratories from Belarus and Russian Federation are presented.

Charapitsa, Siarhei V; Markovsky, Mikhail G; Yakuba, Yurii F; Kotov, Yurii N

2014-01-01T23:59:59.000Z

393

DOI: 10.1002/ejic.200600960 Synthesis and Sublimation Kinetics of a Highly Volatile Asymmetric Iron(II)  

E-Print Network [OSTI]

FULL PAPER DOI: 10.1002/ejic.200600960 Synthesis and Sublimation Kinetics of a Highly Volatile: Asymmetric iron(II) amidinate / Bridging ligands / Metathesis / Sublimation kinetics / Thermochemistry properties have been the subject of intense investigations in chemistry, electronics, optics, energy

394

Evaluation of the colossal electroresistance (CER) effect and its application in the non-volatile Resistive Random Access Memory (RRAM)  

E-Print Network [OSTI]

Flash memory, the current leading technology for non-volatile memory (NVM), is projected by many to run obsolete in the face of future miniaturization trend in the semiconductor devices due to some of its technical ...

Wicaksono, Aulia Tegar

2009-01-01T23:59:59.000Z

395

The role of non-volatile memory from an application perspective  

SciTech Connect (OSTI)

Current, emerging, and future NVM (non-volatile memory) technologies give us hope that we will be able to architect HPC (high performance computing) systems that initially use them in a memory and storage hierarchy, and eventually use them as the memory and storage for the system, complete with ownership and protections as a HDD-based (hard-disk-drive-based) file system provides today.

Kettering, Brett M [Los Alamos National Laboratory; Nunez, James A [Los Alamos National Laboratory

2010-09-16T23:59:59.000Z

396

Volatile sulfhydryl compounds produced in Cheddar cheese slurries upon the addition of whey protein and casein  

E-Print Network [OSTI]

. The addition of whey protein, casein or a combination of whey protein plus 7-glutamyl transpeptidase to slurries was studied to determine the effect of these proteins on volatile sulfhydryl compound production. Milk heat treatment decreased (P&0. 05... measurable free sulfhydryl groups are present in native caseins and only limited amounts are generated by high heat treatments. Those proteins remaining in solution after removal of caseins from milk comprise about 0. 6 to 0. 7% of milk and are designated...

Sheffield, Amelia Rose

2012-06-07T23:59:59.000Z

397

The role of microorganisms in the production of volatile sulfhydryl compounds in cheddar cheese slurries  

E-Print Network [OSTI]

the role of lac- tic cultures on the production of volatile sulfhydryl com- pounds in the slurries. Hydrogen sulfide, methanethiol, carbonyl sulfide and dimethyl sulfide were found in the headspace of slurries prepared from curd manufactured.... (39) stated that although the role of hydrogen sulfide in the production of Cheddar flavor is uncertain, its influence should not be discounted. They suggested that dimethyl sulfide does not contribute directly to flavor. Aston and Douglas (1...

Ponce-Trevino, Raul

2012-06-07T23:59:59.000Z

398

Electron impact and chemical ionization mass spectral analysis of a volatile uranyl derivative  

SciTech Connect (OSTI)

Quadrupole mass spectral analysis of the volatile uranium ligand complex bis (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato) dioxouranium-di-n-butyl sulfoxide is described utilizing electron impact (EI) and methane chemical ionization (CI) ion sources. All major ions are tentatively identified and the potential usefulness of this complex for determining uranium isotope /sup 235/U//sup 238/U abundance is demonstrated.

Reutter, D.J.; Hardy, D.R.

1981-01-01T23:59:59.000Z

399

NOTE SUR LES EFFETS DE L'INFUSION PERMANENTE D'UN MLANGE D'ACIDES GRAS VOLATILS DANS LE  

E-Print Network [OSTI]

NOTE SUR LES EFFETS DE L'INFUSION PERMANENTE D'UN M�LANGE D'ACIDES GRAS VOLATILS DANS LE RUMEN DU problèmes techniques : infusion permanente et prolongée, dans le rumen, de quantités d'acides gras volatils début de l'infusion, les veaux étaient âgés d'environ 4 mois et pesaient respectivement 95 et 80 kg

Paris-Sud XI, Université de

400

Organic photovoltaics and concentrators  

E-Print Network [OSTI]

The separation of light harvesting and charge generation offers several advantages in the design of organic photovoltaics and organic solar concentrators for the ultimate end goal of achieving a lower cost solar electric ...

Mapel, Jonathan King

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Organic photosensitive devices  

DOE Patents [OSTI]

The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photosensitive optoelectronic devices having a photoactive organic region containing encapsulated nanoparticles that exhibit plasmon resonances. An enhancement of the incident optical field is achieved via surface plasmon polariton resonances. This enhancement increases the absorption of incident light, leading to a more efficient device.

Rand, Barry P; Forrest, Stephen R

2013-11-26T23:59:59.000Z

402

UV Curable Coatings in Aluminum Can Production  

E-Print Network [OSTI]

printing operations, including those in metal decorative printing, utilize solvent based, or solvent-eontaining, ink and varnishes. As a result, conventional printing technologies produce significant VOC (volatile organic compound) and HAP (hazardous..., warmed slightly above ambient temperature due to the heat evolution from the UV lamps. The UV oven contains between six and eight 10 inch, 300 watt/inch, microwave energized mercury lamps. The lamps are positioned with parabolic reflectors in a...

Donhowe, E. T.

403

Total Organic Carbon Analyzer | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Total Organic Carbon Analyzer Total Organic Carbon Analyzer The carbon analyzer is used to analyze total carbon (TC), inorganic carbon (IC), total organic carbon (TOC), purgeable...

404

Effets d'infusions d'un mlange complet d'acides gras volatils en cours de repas sur la prise alimentaire de vaches taries  

E-Print Network [OSTI]

Effets d'infusions d'un mĂ©lange complet d'acides gras volatils en cours de repas sur la prise-Gilles, 35590 L'Hermitage, France Summary ― Infusions of 3 or 6 mol of a volatile fatty acid mixture dĂ©pressifs des infusions d'acides gras volatils (AGV) dans le rumen sur l'ingestion d'aliments ont Ă©tĂ©

Paris-Sud XI, Université de

405

Photo-activated luminescence sensor and method of detecting trichloroethylene and related volatile organochloride compounds  

DOE Patents [OSTI]

A sensor for detecting trichloroethylene and related volatile organochloride compounds uses a photo-activator that produces a photo-product complex with the contaminant. Characteristics of the light emitted from the complex will indicate the presence of the contaminant. A probe containing the photo-activator has an excitation light interface and a contaminant interface. One particular embodiment uses a porous membrane as the contaminant interface, so that the contaminant can migrate therethrough to the photo-activator and thereby form the complex.

Dinh, Tuan V. (Knoxville, TN)

1996-01-01T23:59:59.000Z

406

Photo-activated luminescence sensor and method of detecting trichloroethylene and related volatile organochloride compounds  

DOE Patents [OSTI]

A sensor for detecting trichloroethylene and related volatile organochloride compounds uses a photo-activator that produces a photo-product complex with the contaminant. Characteristics of the light emitted from the complex will indicate the presence of the contaminant. A probe containing the photo-activator has an excitation light interface and a contaminant interface. One particular embodiment uses a porous membrane as the contaminant interface, so that the contaminant can migrate there through to the photo-activator and thereby form the complex. 23 figs.

Dinh, T.V.

1996-06-11T23:59:59.000Z

407

Organic vapor jet printing system  

DOE Patents [OSTI]

An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

Forrest, Stephen R

2012-10-23T23:59:59.000Z

408

Quarterly sampling of the wetlands along the old F-Area effluent ditch: March 1994  

SciTech Connect (OSTI)

In March 1994, well point water and near surface water (bucket) samples were collected to further characterize tritium and volatile organic compounds (VOC) in the wetlands along the old F-Area effluent ditch south of 643-E (old burial ground). Groundwater flow paths suggest that compounds detected in water table wells around 643-E would migrate towards the old F-Area effluent ditch and Fourmile Branch. Recent analytical results from near surface water sampling in the wetlands that comprise the old F-Area effluent ditch have shown that tritium and small quantities of VOCs are outcropping in the area. Results of the March 1994 sampling event further support findings that tritium and volatile organic compounds originating from 643-E are outcropping in the wetlands near the old F-Area effluent ditch. Six different analytes were detected in the well points at least once at concentrations greater than the method detection limit: d 1,2-dichloroethylene, acetone, methyl ethyl ketone, tetrachloroethylene, trichloroethylene, and tritium. 1,2-dichloroethylene, tetrachloroethylene, trichloroethylene, and tritium were detected at levels above Primary Drinking Water Standards or Maximum Contaminant Levels list. Four analytes, 1,2-dichloroethylene, trichloroethylene, tritium, and vinyl chloride, were detected at least once at concentrations greater than the method detection limit and least once at concentrations above the PDWS or the MCL. Based on differences in tritium concentrations at each location, it was determined that the sampling devices intercepted different groundwater flow paths. This negated direct comparison of analytical results between devices. However, when VOC concentrations measured at each well point and bucket location were normalized, resulting well point and bucket VOC concentrations were comparable in most cases. These results suggest that volatilization losses of VOCs from the buckets were negligible.

Dixon, K.L.; Cummins, C.L.; Rogers, V.A.

1994-05-01T23:59:59.000Z

409

Effective Presentations Organization  

E-Print Network [OSTI]

1 Pericles Effective Presentations · Content · Organization · Delivery · Visual aids and graphics Be brave Graphics · KISS · Powerpoint: ­ Font · Bigger than you'd expect · San serif ­ Lines · Thicker than · Organization · Energy · Clarity · Poise Key: Practice Web Resources · http

Shull, David H.

410

Field-usable portable analyzer for chlorinated organic compounds  

SciTech Connect (OSTI)

In 1992, a chemical sensor was developed which showed almost perfect selectivity to vapors of chlorinated solvents. When interfaced to an instrument, a chemical analyzer will be produced that has near- absolute selectivity to vapors of volatile chlorinated organic compounds. TRI has just completed the second of a 2-phase program to develop this new instrument system, which is called the RCL MONITOR. In Phase II, this instrument was deployed in 5 EM40 operations. Phase II applications covered clean-up process monitoring, environmental modeling, routine monitoring, health and safety, and technology validation. Vapor levels between 0 and 100 ppM can be determined in 90 s with a lower detection limit of 0.5 ppM using the hand-portable instrument. Based on the favorable performance of the RCL MONITOR, the commercial instrument was released for commercial sales on Sept. 20, 1996.

Buttner, W.J.; Penrose, W.R.; Stetter, J.R.; Williams, R.D.

1996-12-31T23:59:59.000Z

411

An assessment of methyl mercury and volatile mercury in land-applied sewage sludge  

SciTech Connect (OSTI)

In 1993, the US Environmental Protection Agency issued regulations covering the land-application of municipal sewage sludge. These regulations established maximum pollutant concentrations and were based upon a risk assessment of human exposure. Mercury, assumed to be inorganic and non-volatile, was one pollutant evaluated. From April, 1995 through February, 1996, the authors studied the species of mercury contaminating municipal sludge applied to land, and the potential for volatilization of mercury from land-applied sludge. Methyl mercury was found at 0.1% of total mercury concentrations and was emitted from land-applied sludge to the atmosphere. Elemental mercury (Hg) was formed in land-applied sludge via the reduction of oxidized mercury and was also emitted to the atmosphere. Hg emission from land-applied sludge was significantly elevated over background soil emission. Methyl mercury is more toxic and more highly bioaccumulated than inorganic mercury, and warrants assessment considering these special criteria. Additionally, mercury emission from sludge-amended soil may lead to the contamination of other environmental media with significant concentrations of the metal. Although these pathways were not evaluated in the regulatory risk assessment, they are an important consideration for evaluating the risks from mercury in land-applied sludge. This presentation will summarize the results of a re-assessment of US EPA regulations regarding the land-application of municipal sewage sludge using data on methyl mercury toxicity and mercury transport in the atmosphere.

Carpi, A. [Cornell Univ., Ithaca, NY (United States); Lindberg, S.E. [Oak Ridge National Lab., TN (United States)

1995-12-31T23:59:59.000Z

412

Volatile abundances in submarine glasses from the North Fiji and Lau back-arc basins  

SciTech Connect (OSTI)

Glasses from submarine lavas of the North Fiji and lau back-arc basins were analyzed by high-temperature mass spectrometry for volatiles. Abundances for H{sub 2}O, Cl, F, S and CO{sub 2} in glasses ranging in composition from depleted, primitive MORB to enriched, transitional tholeiites are reported. The samples divide into three groups based on K{sub 2}O vs. H{sub 2}O, Ba/Zr vs. H{sub 2}O and K{sub 2}O/H{sub 2}O vs. P{sub 2}O{sub 5}/H{sub 2}O variation diagrams. At similar Mg No., the least evolved samples studied are nearly identical to N-type MORB in H{sub 2}O abundances but show Cl contents enriched by a factor of 5. More enriched samples, classified as back-arc basin basalts (BABB) on the basis of major/trace elements and isotopes, are not as hydrous (at similar Mg No.) as those from the Mariana and East Scotia Sea back-arc basins. The data indicate that not all back-arc basins erupt lavas with the distinct volatile and other elemental characteristics of lavas from the Mariana Trough and Scotia Sea.

Aggrey, K.E.; Muenow, D.W.; Sinton, J.M. (Univ. of Hawaii, Honolulu (USA))

1988-10-01T23:59:59.000Z

413

Organic Separation Test Results  

SciTech Connect (OSTI)

Separable organics have been defined as “those organic compounds of very limited solubility in the bulk waste and that can form a separate liquid phase or layer” (Smalley and Nguyen 2013), and result from three main solvent extraction processes: U Plant Uranium Recovery Process, B Plant Waste Fractionation Process, and Plutonium Uranium Extraction (PUREX) Process. The primary organic solvents associated with tank solids are TBP, D2EHPA, and NPH. There is concern that, while this organic material is bound to the sludge particles as it is stored in the tanks, waste feed delivery activities, specifically transfer pump and mixer pump operations, could cause the organics to form a separated layer in the tank farms feed tank. Therefore, Washington River Protection Solutions (WRPS) is experimentally evaluating the potential of organic solvents separating from the tank solids (sludge) during waste feed delivery activities, specifically the waste mixing and transfer processes. Given the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria per the Waste Feed Acceptance Criteria document (24590-WTP-RPT-MGT-11-014) that there is to be “no visible layer” of separable organics in the waste feed, this would result in the batch being unacceptable to transfer to WTP. This study is of particular importance to WRPS because of these WTP requirements.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2014-09-22T23:59:59.000Z

414

Stable isotopic investigations of in situ bioremediation of chlorinated organic solvents. 1997 annual progress report  

SciTech Connect (OSTI)

'The author has made significant progress in developing innovative methods for investigating the mechanism and extent of in situ bioremediation of chlorinated organic solvents. These methods use precise isotopic ratio measurements of chlorine and carbon in reactant and product species in laboratory experiments and in materials from field demonstration sites. Specific tasks completed during FY 1997 include: (1) refinement and publication of a new analytical method for precise determination of chlorine and carbon isotope ratios in chlorinated volatile organic compounds; (2) laboratory experiments involving biological degradation of chlorinated solvents in liquid cultures and soil columns; and (3) use of chlorine and carbon isotope ratios to investigate natural attenuation of trichloroethene at the Paducah Gaseous Diffusion Plant. This work can have immediate impact because it will provide the fundamental basis for a new and cost-effective means of evaluating and monitoring the effectiveness of in situ bioremediation schemes for chlorinated organic solvents in soils, vadose horizons, and groundwater plumes.'

Sturchio, N.C.

1997-01-01T23:59:59.000Z

415

Departmental Organization Management System  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Public Law 95-91, 42 United States Code 7101, Department of Energy Organization Act, Section 642 gives to the Secretary of the Department of Energy the responsibility to approve organization changes affecting the number, designation, or mission of Departmental Elements and to approve the addition, deletion, or transfer of missions and/or functions of or between Departmental Elements. In order to streamline the organizational change process, the Secretary has delegate to the Heads of Departmental Headquarters and Field Elements the authority to approve organization changes. No cancellations.

1996-08-27T23:59:59.000Z

416

Effets sur la digestion et le mtabolisme des vaches laitires d'infusions d'acides gras volatils dans le rumen  

E-Print Network [OSTI]

Effets sur la digestion et le métabolisme des vaches laitières d'infusions d'acides gras volatils.N.R.A., Saint-Gilles, 35590, L'Hermitage, France. Summary. Effects of !uminal infusion of volatile fatty acids and duodenal infusion of caseinate on digestion and metabolism in the dairy cow. II. - General and mammary

Paris-Sud XI, Université de

417

Effets sur la digestion et le mtabolisme des vaches laitires d'infusions d'acides gras volatils dans le rumen  

E-Print Network [OSTI]

Effets sur la digestion et le métabolisme des vaches laitières d'infusions d'acides gras volatils.N.R.A. Saint-Gilles, 35590 L'Hermitage, France Summary. Effects of ruminal infusion of volatile fatty acids and duodenal infusion of casei- nate on digestion and metabolism in the dairy cow. l. - Production

Paris-Sud XI, Université de

418

Organic Photovoltaics Research  

Broader source: Energy.gov [DOE]

DOE funds research and development projects related to organic photovoltaics (OPV) due to the unique benefits it offers. Below are a list of the projects, summary of the benefits, and discussion on...

419

Organization | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehicles »Exchange VisitorsforDepartment ofNoOrganization Organization View

420

Organic contaminant separator  

DOE Patents [OSTI]

A process is presented of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube. The solvent is capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus is presented for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium. The apparatus includes a composite tube comprised of a blend of a polyolefin and a polyester. The composite tube has an internal diameter of from about 0.1 to about 2.0 millimeters and has sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube. 2 figures.

Del Mar, P.

1993-12-28T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Eco-friendly driven remediation of the indoor air environment: the synthesis of novel transition metal doped titania/silica aerogels for degradation of volatile and semi-volatile organic compounds.  

E-Print Network [OSTI]

??Remediation of the indoor environment led to the development of novel catalysts which can absorb light in the visible range. These catalysts were prepared using… (more)

Baker, Schuyler Denton

2012-01-01T23:59:59.000Z

422

Quarterly sampling of the wetlands along the old F Area effluent ditch: August 1994  

SciTech Connect (OSTI)

In August 1994, well point water and near-surface water samples were collected to characterize tritium and volatile organic compounds (VOC) in the wetlands along the old F-Area effluent ditch south of 643-E (old burial ground). The August sampling event was the third in a series of eight events. Groundwater flow paths suggest that compounds detected in water table wells around 643-E migrate towards the old F-Area effluent ditch and Fourmile Branch. Recent analytical results from well point and near-surface water sampling in the wetlands that comprise the old F-Area effluent ditch have shown that tritium and small quantities of VOCs are outcropping in the area. For this study, seven locations along the old F-Area effluent ditch were selected to be sampled. Well point samples were collected from all seven locations and near-surface water samples were collected at four locations. A secondary objective of this project was to compare VOC concentrations between the well points installed to depths of 6 to 8 ft and the near-surface water sampling buckets installed to depths of 1 to 2 ft. Based on differences in tritium concentrations at each location, it was determined that the sampling devices intercepted different groundwater flow paths. This negated direct comparison of analytical results between devices. However, when VOC concentrations measured at each well point and bucket location were normalized, based on the percent differences observed in tritium concentrations at that location, the resulting well point and bucket VOC concentrations were comparable in most cases. These results are consistent with the results from the three previous sampling events, and suggest that volatilization losses of VOCs from the buckets may be negligible. Since the results from the two sampling methodologies are not directly comparable, further sampling of the buckets is not planned.

Cummins, C.L.; Dixon, K.L.

1994-08-01T23:59:59.000Z

423

UniFI: Leveraging Non-Volatile Memories for a Unified Fault Tolerance and Idle Power Management Technique  

E-Print Network [OSTI]

dissipation but also to make power - proportional to performance by managing idle power. The twin challenges noise margins and thermal cycling [42]. Technology scaling and power management both impact systemUniFI: Leveraging Non-Volatile Memories for a Unified Fault Tolerance and Idle Power Management

Wood, David A.

424

Effects of digestive infusions of volatile fatty acids or glucose on food intake in lactating or dry cows  

E-Print Network [OSTI]

Effects of digestive infusions of volatile fatty acids or glucose on food intake in lactating lactating (30 kg of milk/d) and 3 non pregnant dry dairy cows. The effect of each energetic infusion) control solutions of VFA and glucose treatments were infused at the same vol, pH and osmolarity

Paris-Sud XI, Université de

425

Fluid saturation and volatile partitioning between melts and hydrous fluids in crustal magmatic systems: The contribution of experimental measurements and  

E-Print Network [OSTI]

systems, experimental results on the solubility and partitioning of H2O, CO2, S, Cl, F and a few other systems: The contribution of experimental measurements and solubility models Don R. Baker a, , Marina 2012 Keywords: Magmatic volatiles Solubility Water Carbon dioxide Sulfur Halogens This work reviews

Long, Bernard

426

Estimation of Volatility The values of the parameters r, t, St, T, and K used to price a call op-  

E-Print Network [OSTI]

is the price of light sweet crude oil futures traded on the New York Mercantile Exchange (NYMEX), basedChapter 7 Estimation of Volatility The values of the parameters r, t, St, T, and K used to price in the stock price model dSt St = µdt + dBt. A natural estimator for the trend parameter µ can be written as ^µ

Privault, Nicolas

427

Forecasting the conditional volatility of oil spot and futures prices with structural breaks and long memory models  

E-Print Network [OSTI]

Forecasting the conditional volatility of oil spot and futures prices with structural breaks of oil spot and futures prices using three GARCH-type models, i.e., linear GARCH, GARCH with structural that oil price fluctuations influence economic activity and financial sector (e.g., Jones and Kaul, 1996

Paris-Sud XI, Université de

428

The Impact of Tax Shocks and Oil Price Volatility on Risk - A Study of North Sea Oilfield Projects   

E-Print Network [OSTI]

We examine the impact of market volatility and increased fiscal take on risk in strategic natural resource projects. An increase in 2006 UK oilfield taxation is used as a natural experiment for assessing the impact of a fiscal increase on oilfield...

Kretzschmar, Gavin Lee; Moles, Peter

2006-01-01T23:59:59.000Z

429

Phytologia (Oct. 1, 2014) 96(4)252 Comparison of volatile leaf terpenoids from Lippia dulcis (Verbenaceae) obtained by steam  

E-Print Network [OSTI]

(Verbenaceae) obtained by steam distillation and pentane liquid extraction Robert P. Adams Biology Department, Prairie View, TX 77446 ABSTRACT Comparison of pentane extraction and steam distillation of intact leaves to be due to the different effects of pentane solvent on intact leaves (vs. steam volatilization

Adams, Robert P.

430

Manmade organic compounds in the surface waters of the United States: A review of current understanding  

SciTech Connect (OSTI)

On the basis of their aqueous solubilities, nonionic organic compounds partition themselves between water, dissolved organic matter, particulate organic matter, and the lipid reservoirs of aquatic organisms. Ionized organic compounds can be adsorbed to sediments, thereby reducing their aqueous concentrations. Transformation processes of photolysis, hydrolysis, biodegradation, and volatilization can attenuate organic compounds, and attenuation rates commonly follow a first-order kinetic process. Eight groups of manmade organic compounds are discussed: (1) polychlorinated biphenyls and organochlorine insecticides; (2) carbamate and organophosphorus; (3) herbicides; (4) phenols; (5) halogenated aliphatic and monocyclic aromatic hydrocarbons; (6) phthalate esters; (7) polychlorinated dibenzo-p-dioxins, and (8) polycyclic aromatic hydrocarbons. For each compound group, data pertaining to use, production, and properties are presented and discussed. Process that influence the environmental fate of each group, as determined primarily through laboratory studies, are reviewed, and important fate process are identified. Environmental concentrations of compounds from each group in water, biota, and sediment are given to demonstrate representative values for comparison to concentrations determined during ongoing research. Finally, where sufficient data exist, regional and temporal contamination trends in the US are discussed. 699 refs., 26 figs., 47 tabs.

Smith, J.A.; Witkowski, P.J.; Fusillo, T.V.

1990-01-01T23:59:59.000Z

431

Abundance ratios of volatile vs. refractory elements in planet-harbouring stars: hints of pollution?  

E-Print Network [OSTI]

We present the [X/H] trends as function of the elemental condensation temperature Tc in 88 planet host stars and in a volume-limited comparison sample of 33 dwarfs without detected planetary companions. We gathered homogeneous abundance results for many volatile and refractory elements spanning a wide range of Tc, from a few dozens to several hundreds kelvin. We investigate possible anomalous trends of planet hosts with respect to comparison sample stars in order to detect evidence of possible pollution events. No significant differences are found in the behaviour of stars with and without planets. This result is in agreement with a ``primordial'' origin of the metal excess in planet host stars. However, a subgroup of 5 planet host and 1 comparison sample stars stands out for having particularly high [X/H] vs. Tc slopes.

A. Ecuvillon; G. Israelian; N. C. Santos; M. Mayor; G. Gilli

2005-12-08T23:59:59.000Z

432

Thermodynamic modeling of volatile hazardous metal behavior in the Vortec Vitrification System  

SciTech Connect (OSTI)

The thermochemical equilibrium calculations indicate that at the temperature of a propane--air flame, some volatilization of uranium, plutonium, technetium, and cesium will occur. The expected concentrations of plutonium, technetium, and cesium in the flame will be very low because of the small maximum concentration of these elements in the projected feed materials for the first 30-day test. The quantities volatilized can generally be decreased by operating the flame in a fuel-rich mode, although this will lead to greater carbon monoxide production, which may be more objectionable. The concentrations of chlorine and fluorine, at least at the maximum levels in the projected Vortec feed, are not projected to greatly influence the vaporization rates. Therefore, blending to reduce the concentrations of those elements would most likely not be effective in reducing metal vaporization. Most of the elements vaporized condense by the time the gas cools to 2000 F. These elements would condense either on surfaces near the front of the heat recuperator or on entrained particulates or homogeneously as relatively pure submicron particles. Cesium would be expected to condense at the lower temperatures near the rear of the recuperator, although the expected maximum concentration in the Vortec feed material is extremely low so it should be greatly diluted by other particulates. The elements that condense on other entrained particles will form enriched surface coatings. Particles larger than 10{micro}m or so will be collected in the scrubber. Smaller particles, especially the submicron particles formed from homogeneous nucleation, should be largely collected in the HEPA filter. Deposits formed in the heat recuperator can normally be handled via sootblowing. To reduce handling problems, we suggest that the recuperator be oriented vertically so that the deposits blown off of the heat exchanger fall directly into the molten glass. The large size of the deposits should help to reduce the rate of revaporization, allowing the volatile elements to be removed with the glass. The volatile elements that do not deposit on system surfaces will be concentrated in the smaller particles. Therefore, the HEPA ash will be greatly enriched in these elements. If the HEPA filter is itself sent to a melter, the elements may revaporize and multiply the problems related to metal vaporization significantly. Therefore, the HEPA filters should be disposed of without high-temperature processing. Also, to reduce the formation of these very small particles, it is helpful to include in the feed larger particles to act as condensation nuclei that can then be collected in the scrubber. This can be accomplished by using feed materials with a fraction consisting of particles small enough that they will not be collected in the cyclone in the melter, but large enough that they will easily be collected by the scrubber. This is one advantage that firing bituminous coal has over gas firing; it provides a source of ash particles of the right size range to serve as nucleation sites, but large enough (depending on the coal) so that they can usually be collected efficiently in the scrubber system.

Nowok, J.W.; Hurley, J.P.

2000-07-31T23:59:59.000Z

433

Volatile Delivery to Planets from Water-rich Planetesimals around Low Mass Stars  

E-Print Network [OSTI]

Most models of volatile delivery to accreting terrestrial planets assume that the carriers for water are similar in water content to the carbonaceous chondrites in our Solar System. Here we suggest that the water content of primitive bodies in many planetary systems may actually be much higher, as carbonaceous chondrites have lost some of their original water due to heating from short-lived radioisotopes that drove parent body alteration. Using N-body simulations, we explore how planetary accretion would be different if bodies beyond the water line contained a water mass fraction consistent with chemical equilibrium calculations, and more similar to comets, as opposed to the more traditional water-depleted values. We apply this model to consider planet formation around stars of different masses and identify trends in the properties of Habitable Zone planets and planetary system architecture which could be tested by ongoing exoplanet census data collection. Comparison of such data with the model predicted tren...

Ciesla, Fred J; Pascucci, Ilaria; Apai, Daniel

2015-01-01T23:59:59.000Z

434

Methods for characterizing subsurface volatile contaminants using in-situ sensors  

DOE Patents [OSTI]

An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.

Ho, Clifford K. (Albuquerque, NM)

2006-02-21T23:59:59.000Z

435

Modeling Volatile Species Retention Experiments: Interim Progress Report (M3FT-12LA0202053)  

SciTech Connect (OSTI)

Metal nuclear fuel is a candidate transmutation fuel form for advanced fuel cycles. One constituent of the fuel, americium, has a high vapor pressure, and there is a concern that excessive volatility losses of americium will occur during casting of the metal. A number of experiments have been performed using americium and surrogate metals, including experiments slated for FY12, to address the concern. The present task is to model and numerically simulate these experiments. This report describes a system-level model of the relevant experiments that has been developed together with some results. It also describes some initial 3D, full-physics simulations of portions of the experiments that have been performed.

Carlson, Neil N. [Los Alamos National Laboratory

2012-07-06T23:59:59.000Z

436

Methodology for Formulating Diesel Surrogate Fuels with Accurate Compositional, Ignition-Quality, and Volatility Characteristics  

SciTech Connect (OSTI)

In this study, a novel approach was developed to formulate surrogate fuels having characteristics that are representative of diesel fuels produced from real-world refinery streams. Because diesel fuels typically consist of hundreds of compounds, it is difficult to conclusively determine the effects of fuel composition on combustion properties. Surrogate fuels, being simpler representations of these practical fuels, are of interest because they can provide a better understanding of fundamental fuel-composition and property effects on combustion and emissions-formation processes in internal-combustion engines. In addition, the application of surrogate fuels in numerical simulations with accurate vaporization, mixing, and combustion models could revolutionize future engine designs by enabling computational optimization for evolving real fuels. Dependable computational design would not only improve engine function, it would do so at significant cost savings relative to current optimization strategies that rely on physical testing of hardware prototypes. The approach in this study utilized the state-of-the-art techniques of {sup 13}C and {sup 1}H nuclear magnetic resonance spectroscopy and the advanced distillation curve to characterize fuel composition and volatility, respectively. The ignition quality was quantified by the derived cetane number. Two well-characterized, ultra-low-sulfur No.2 diesel reference fuels produced from refinery streams were used as target fuels: a 2007 emissions certification fuel and a Coordinating Research Council (CRC) Fuels for Advanced Combustion Engines (FACE) diesel fuel. A surrogate was created for each target fuel by blending eight pure compounds. The known carbon bond types within the pure compounds, as well as models for the ignition qualities and volatilities of their mixtures, were used in a multiproperty regression algorithm to determine optimal surrogate formulations. The predicted and measured surrogate-fuel properties were quantitatively compared to the measured target-fuel properties, and good agreement was found.

Mueller, C. J.; Cannella, W. J.; Bruno, T. J.; Bunting, B.; Dettman, H. D.; Franz, J. A.; Huber, M. L.; Natarajan, M.; Pitz, W. J.; Ratcliff, M. A.; Wright, K.

2012-06-21T23:59:59.000Z

437

Reformulated gasoline: Costs and refinery impacts  

SciTech Connect (OSTI)

Studies of reformulated gasoline (RFG) costs and refinery impacts have been performed with the Oak Ridge National Laboratory Refinery Yield Model (ORNL-RYM), a linear program which has been updated to blend gasolines to satisfy emissions constraints defined by preliminary complex emissions models. Policy makers may use the reformulation cost knee (the point at which costs start to rise sharply for incremental emissions control) to set emissions reduction targets, giving due consideration to the differences between model representations and actual refining operations. ORNL-RYM estimates that the reformulation cost knee for the US East Coast (PADD I) is about 15.2 cents per gallon with a 30 percent reduction of volatile organic compounds (VOCs). The estimated cost knee for the US Gulf Coast (PADD III) is about 5.5 cents per gallon with a VOC reduction of 35 percent. Reid vapor pressure (RVP) reduction is the dominant VOC reduction mechanism. Even with anti-dumping constraints, conventional gasoline appears to be an important sink which permits RFG to be blended with lower aromatics and sulfur contents in PADD III. In addition to the potentially large sensitivity of RFG production to different emissions models, RFG production is sensitive to the non-exhaust VOC share assumption for a particular VOC model. ORNL-RYM has also been used to estimate the sensitivity of RFG production to the cost of capital; to the RVP requirements for conventional gasoline; and to the percentage of RFG produced in a refining region.

Hadder, G.R.

1994-02-01T23:59:59.000Z

438

Fragranced consumer products: Chemicals emitted, ingredients unlisted  

SciTech Connect (OSTI)

Fragranced consumer products are pervasive in society. Relatively little is known about the composition of these products, due to lack of prior study, complexity of formulations, and limitations and protections on ingredient disclosure in the U.S. We investigated volatile organic compounds (VOCs) emitted from 25 common fragranced consumer products-laundry products, personal care products, cleaning supplies, and air fresheners-using headspace analysis with gas chromatography/mass spectrometry (GC/MS). Our analysis found 133 different VOCs emitted from the 25 products, with an average of 17 VOCs per product. Of these 133 VOCs, 24 are classified as toxic or hazardous under U.S. federal laws, and each product emitted at least one of these compounds. For 'green' products, emissions of these compounds were not significantly different from the other products. Of all VOCs identified across the products, only 1 was listed on any product label, and only 2 were listed on any material safety data sheet (MSDS). While virtually none of the chemicals identified were listed, this nonetheless accords with U.S. regulations, which do not require disclosure of all ingredients in a consumer product, or of any ingredients in a mixture called 'fragrance.' Because the analysis focused on compounds emitted and listed, rather than exposures and effects, it makes no claims regarding possible risks from product use. Results of this study contribute to understanding emissions from common products, and their links with labeling and legislation.

Steinemann, Anne C., E-mail: acstein@u.washington.ed [University of Washington, Department of Civil and Environmental Engineering, and Evans School of Public Affairs, Seattle, WA 98195-2700 (United States); MacGregor, Ian C.; Gordon, Sydney M. [Battelle Memorial Institute (United States); Gallagher, Lisa G.; Davis, Amy L.; Ribeiro, Daniel S. [University of Washington (United States); Wallace, Lance A. [U.S. Environmental Protection Agency (ret.) (United States)

2011-04-15T23:59:59.000Z

439

Organic aerogel microspheres  

DOE Patents [OSTI]

Organic aerogel microspheres are disclosed which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonstick gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

Mayer, S.T.; Kong, F.M.; Pekala, R.W.; Kaschmitter, J.L.

1999-06-01T23:59:59.000Z

440

Organic aerogel microspheres  

DOE Patents [OSTI]

Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

Mayer, Steven T. (San Leandro, CA); Kong, Fung-Ming (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Sludge organics bioavailability  

SciTech Connect (OSTI)

Concern over the bioavailability of toxic organics that can occur in municipal sludges threatens routine land application of sludge. Available data, however, show that concentrations of priority organics in normal sludges are low. Sludges applied at agronomic rates yield chemical concentrations in soil-sludge mixtures 50 to 100 fold lower. Plant uptake at these pollutant concentrations (and at much higher concentrations) is minimal. Chemicals are either (1) accumulated at extremely low levels (PCBs), (2) possibly accumulated, but then rapidly metabolized within plants to extremely low levels (DEHP), or (3) likely degraded so rapidly in soil that only minor contamination occurs (PCP and 2,4-DNP).

Eiceman, G.E.; Bellin, C.A.; Ryan, J.A.; O'Connor, G.A.

1991-01-01T23:59:59.000Z

442

Requestor's Name: Organization  

E-Print Network [OSTI]

Requestor's Name: Organization: Address: (No PO BOX) City, State, Zip: Cell: Phone: Fax: E showing major natural gas pipelines identified by owner and pipe diameter. 6) California Wind Resource Annual Wind Speed, Annual Wind Power, and Seasonal Wind Speed measured at various elevations (meters

443

Organic solvent topical report  

SciTech Connect (OSTI)

This report is the technical basis for the accident and consequence analyses used in the Hanford Tank Farms Basis for Interim Operation. The report also contains the scientific and engineering information and reference material needed to understand the organic solvent safety issue. This report includes comments received from the Chemical Reactions Subcommittee of the Tank Advisory Panel.

Cowley, W.L.

1998-04-30T23:59:59.000Z

444

REPRESENTATIONS & CERTIFICATIONS ORGANIZATION: PHONE  

E-Print Network [OSTI]

or Agreement. 1. Labor Surplus Area: Offeror ___ will ___ will not, perform the work in an area classified labor surplus area; or (3) ___ substantial labor surplus area. 2. Type of Business Organization: Offeror Business Concern", means a small business concern that (1) is at least 51 percent unconditionally owned

Groppi, Christopher

445

CCPPolicyBriefing Organization  

E-Print Network [OSTI]

BACKGROUND · Modern cartels are well-organized with sophisticated organizational structures. Disclosing to confidentiality, details on the organizational form of cracked cartels are rarely disclosed. · Theoretical to facilitating collusion. · Moreover, the efficiency gains of delegation in facilitating collusion can

Feigon, Brooke

446

DESTRUCTION TECHNOLOGY DEMONSTRATION FOR ORGANICS IN TRANSURANIC WASTE  

SciTech Connect (OSTI)

General Atomics (GA) has recently completed a Phase I program for the development of a two-step alternative to incineration for the destruction of organics in transuranic wastes at the Savannah River Site. This process is known as thermal desorption-supercritical water oxidation, or TD-SCWO. The GA TD process uses heat to volatilize and transport organics from the waste material for subsequent treatment by SCWO. SCWO oxidizes organics in a steam medium at elevated temperatures and pressures in a manner that achieves excellent destruction efficiencies and compliance with all environmental requirements without the need for complex pollution-abatement equipment. This application of TD-SCWO is focused on a full-scale batch process for 55-gallon drums of mixed transuranic waste at the Savannah River Site. The Phase I reduced-scale test results show that the process operates as intended on surrogate waste matrices chosen to be representative of Savannah River Site transuranic mixed wastes. It provides a high degree of hydrogen removal and full containment of the radionuclide surrogate, with minimal requirements for pre-treatment and post-treatment. Other test objectives were to verify that the process produces no dioxins or furans, and meets all applicable regulatory criteria for retention of toxic metals, particulate, and criteria pollutants, while meeting WIPP/WAC and TRUPACT-II requirements. Thermal desorption of surrogate SRS mixed wastes at 500 psi and 1000 F met all tested requirements for WIPP/WAC and TRUPACT-II. SCWO of the desorbed surrogate organic materials at 500 psi and 1500 F also appears to meet all requirements for a nonincineration alternative, although >99.99% DRE for chlorinated solvents has not yet been demonstrated.

Mike Spritzer

2003-02-01T23:59:59.000Z

447

Methodology for Formulating Diesel Surrogate Fuels with Accurate Compositional, Ignition-Quality, and Volatility Characteristics  

SciTech Connect (OSTI)

In this study, a novel approach was developed to formulate surrogate fuels having characteristics that are representative of diesel fuels produced from real-world refinery streams. Because diesel fuels typically consist of hundreds of compounds, it is difficult to conclusively determine the effects of fuel composition on combustion properties. Surrogate fuels, being simpler representations of these practical fuels, are of interest because they can provide a better understanding of fundamental fuel-composition and property effects on combustion and emissions-formation processes in internal-combustion engines. In addition, the application of surrogate fuels in numerical simulations with accurate vaporization, mixing, and combustion models could revolutionize future engine designs by enabling computational optimization for evolving real fuels. Dependable computational design would not only improve engine function, it would do so at significant cost savings relative to current optimization strategies that rely on physical testing of hardware prototypes. The approach in this study utilized the stateof- the-art techniques of 13C and 1H nuclear magnetic resonance spectroscopy and the advanced distillation curve to characterize fuel composition and volatility, respectively. The ignition quality was quantified by the derived cetane number. Two wellcharacterized, ultra-low-sulfur #2 diesel reference fuels produced from refinery streams were used as target fuels: a 2007 emissions certification fuel and a Coordinating Research Council (CRC) Fuels for Advanced Combustion Engines (FACE) diesel fuel. A surrogate was created for each target fuel by blending eight pure compounds. The known carbon bond types within the pure compounds, as well as models for the ignition qualities and volatilities of their mixtures, were used in a multiproperty regression algorithm to determine optimal surrogate formulations. The predicted and measured surrogate-fuel properties were quantitatively compared to the measured target-fuel properties, and good agreement was found. This paper is dedicated to the memory of our friend and colleague Jim Franz. Funding for this research was provided by the U.S. Department of Energy (U.S. DOE) Office of Vehicle Technologies, and by the Coordinating Research Council (CRC) and the companies that employ the CRC members. The study was conducted under the auspices of CRC. The authors thank U.S. DOE program manager Kevin Stork for supporting the participation of the U.S. national laboratories in this study.

Mueller, Charles J.; Cannella, William J.; Bruno, Thomas J.; Bunting, Bruce G.; Dettman, Heather; Franz, James A.; Huber, Marcia L.; Natarajan, Mani; Pitz, William J.; Ratcliff, Matthew A.; Wright, Ken

2012-07-26T23:59:59.000Z

448

Organic solvent topical report  

SciTech Connect (OSTI)

This report provides the basis for closing the organic solvent safety issue. Sufficient information is presented to conclude that risk posed by an organic solvent fire is within risk evaluation guidelines. This report updates information contained in Analysis of Consequences of Postulated Solvent Fires in Hanford Site Waste Tanks. WHC-SD-WM-CN-032. Rev. 0A (Cowley et al. 1996). However, this document will not replace Cowley et al (1996) as the primary reference for the Basis for Interim Operation (BIO) until the recently submitted BIO amendment (Hanson 1999) is approved by the US Department of Energy. This conclusion depends on the use of controls for preventing vehicle fuel fires and for limiting the use of flame cutting in areas where hot metal can fall on the waste surface.The required controls are given in the Tank Waste Remediation System Technical Safety Requirements (Noorani 1997b). This is a significant change from the conclusions presented in Revision 0 of this report. Revision 0 of this calcnote concluded that some organic solvent fire scenarios exceeded risk evaluation guidelines, even with controls imposed.

COWLEY, W.L.

1999-05-13T23:59:59.000Z

449

Oligomeric Dithienopyrrole-Thienopyrrolodione (DTP-TPD) Donor-Acceptor Copolymer for Organic Photovoltaics: Preprint  

SciTech Connect (OSTI)

A new donor-acceptor copolymer system based upon a dithienopyrrole (DTP) donor moiety and a thienopyrrolodione (TPD) accepting moiety has been designed and synthesized for organic photovoltaic (OPV) applications. The TPD accepting moiety has recently gained significant attention in the OPV community and is being incorporated into a number of different polymer systems. In contrast, the DTP donor moiety has received only limited attention, likely due in part to synthetic difficulties relating to the monomer. In our hands, the bis(trimethyltin)-DTP monomer was indelibly contaminated with ~5% of the mono-destannylated DTP, which limited the Stille polymerization with the dibromo-TPD monomer (>99% pure) to produce material with Mn ~ 4130 g/mol (PDI = 1.10), corresponding to around eight repeat units. Despite this limitation, UV-visible absorption spectroscopy demonstrates strong absorption for this material with a band gap of ~1.6 eV. Cyclic voltammetry indicates a highest occupied molecular orbital (HOMO) energy level of -5.3 eV, which is much lower than calculations predicted. Initial bulk heterojunction OPV devices fabricated with the fullerene acceptor phenyl C61 butyric acid methyl ester (PCBM) exhibit Voc ~ 700 mV, which supports the deep HOMO value obtained from CV. These results suggest the promise of this copolymer system.

Hammond, S. R.; Braunecker, W.; Garcia, A.; Larsen, R.; Owczarczyk, Z.; Olson, D.; Ginley, D.

2011-07-01T23:59:59.000Z

450

Method and apparatus for measuring volatile compounds in an aqueous solution  

DOE Patents [OSTI]

The present invention is an improvement to the method and apparatus for measuring volatile compounds in an aqueous solution. The apparatus is a chamber with sides and two ends, where the first end is closed. The chamber contains a solution volume of the aqueous solution and a gas that is trapped within the first end of the chamber above the solution volume. The gas defines a head space within the chamber above the solution volume. The chamber may also be a cup with the second end. open and facing down and submerged in the aqueous solution so that the gas defines the head space within the cup above the solution volume. The cup can also be entirely submerged in the aqueous solution. The second end of the. chamber may be closed such that the chamber can be used while resting on a flat surface such as a bench. The improvement is a sparger for mixing the gas with the solution volume. The sparger can be a rotating element such as a propeller on a shaft or a cavitating impeller. The sparger can also be a pump and nozzle where the pump is a liquid pump and the nozzle is a liquid spray nozzle open, to the head space for spraying the solution volume into the head space of gas. The pump could also be a gas pump and the nozzle a gas nozzle submerged in the solution volume for spraying the head space gas into the solution volume.

Gilmore, Tyler J [Pasco, WA; Cantrell, Kirk J [West Richland, WA

2002-07-16T23:59:59.000Z

451

The sublethal effects of the non volatile water soluble fraction of Southern Louisiana crude oil on the growth of Skeletonema costatum (Greve.) Cleve  

E-Print Network [OSTI]

THE SUBLETHAL EFFECTS OF THE NON VOLATILE WATER SOLUBLE FRACTION OF SOUTHERN LOUISIANA CRUDE OIL ON THE GROWTH OF Skeletonema costatum (GREVE. ) CLEVE A Thesis by SUE MYHRE SCHAUFFLER Submitted to the Graduate College of Texas ~I University... in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE December 1979 Major Subject: Oceanography THE SUBLETHAL EFFECTS OF THE NON VOLATILE WATER SOLUBLE FRACTION OF SOUTHERN LOUISIANA CRUDE OIL ON THE GROWTH OF Skeletonema...

Schauffler, Sue Myhre

1979-01-01T23:59:59.000Z

452

Influence of Wetting and Mass Transfer Properties of Organic Chemical Mixtures in Vadose Zone Materials on Groundwater Contamination by Nonaqueous Phase Liquids  

SciTech Connect (OSTI)

Previous studies have found that organic acids, organic bases, and detergent-like chemicals change surface wettability. The wastewater and NAPL mixtures discharged at the Hanford site contain such chemicals, and their proportions likely change over time due to reaction-facilitated aging. The specific objectives of this work were to (1) determine the effect of organic chemical mixtures on surface wettability, (2) determine the effect of organic chemical mixtures on CCl4 volatilization rates from NAPL, and (3) accurately determine the migration, entrapment, and volatilization of organic chemical mixtures. Five tasks were proposed to achieve the project objectives. These are to (1) prepare representative batches of fresh and aged NAPL-wastewater mixtures, (2) to measure interfacial tension, contact angle, and capillary pressure-saturation profiles for the same mixtures, (3) to measure interphase mass transfer rates for the same mixtures using micromodels, (4) to measure multiphase flow and interphase mass transfer in large flow cell experiments, all using the same mixtures, and (5) to modify the multiphase flow simulator STOMP in order to account for updated P-S and interphase mass transfer relationships, and to simulate the impact of CCl4 in the vadose zone on groundwater contamination. Results and findings from these tasks and summarized in the attached final report.

Charles J Werth; Albert J Valocchi, Hongkyu Yoon

2011-05-21T23:59:59.000Z

453

Health assessment for Royal Hardage Industrial Hazardous Waste Land Disposal Facility, Criner, Oklahoma, Region 6. CERCLIS No. OKD000400093. Final report  

SciTech Connect (OSTI)

The Royal Hardage Industrial Hazardous Waste Land Disposal Facility (Hardage/Criner) National Priorities List Site is located in Criner, McClain County, Oklahoma. The site is located in an agricultural area. There are volatile organic compounds (VOCs) and several heavy metals present in the groundwater and soil, and VOCs in surface water and sediment. The Record of Decision signed November 1986 selected several remedial actions which included excavation of the primary source material and separation of the wastes for treatment, solids to be disposed of in an on-site landfill that meets Resource Conservation and Recovery Act requirements, organic liquids to be incinerated, and inorganic liquids to be treated by other means as necessary. The site is currently in the remedial-design phase.

Not Available

1988-12-01T23:59:59.000Z

454

Plan of organization  

E-Print Network [OSTI]

~!lr fund available. By recent enactment the appropriation ib placed at the disposal of tEe screral States, and the station1 are being organized. OBJECT OF THE STATIONS. The purpose for which the Agricultural Experiment 11 mas passed is clearly... in the mails free. THE EXPERIMENT STATIONS were placed under the supervision of the Boards of Directors of the Agricultural and Mechanical Colleges, not for the pur- pose of assisting the colleges, but because it was thought the fund would be most...

McInnis, Louis L. (Louis Lowry); Scott, T. M.; Gulley, F. A. (Frank Arthur)

1888-01-01T23:59:59.000Z

455

Bisfuel links - Professional organizations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien,BiologicalPresentationsProfessional organizations

456

Organizations | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratorySpeedingOptimizing I/O performance onAbout MissionOrganizations

457

Neighborhood Progress Through Organized Action.  

E-Print Network [OSTI]

[Blank Page in Original Bulletin] ~ei~ h borhood Progress Through Organized Action E. C. MARTIN, Administrative Assistant BONNIE COX, Organization Specialist MRS. EULA NEWMAN, Specialist in Home Management TEXAS A. & M. COLLEGE SYSTEM "The... coord: lent r peo plt 1. mmunity organization is successful when all families erested groups participate. Such an organization may inate interest in the community and provide an excel- neans for channeling most programs. The interest...

Newman, Eula; Cox, Bonnie; Martin, E. C.

1955-01-01T23:59:59.000Z

458

Nuclear Organization and Genome Function  

E-Print Network [OSTI]

Nuclear Organization and Genome Function Kevin Van Bortle and Victor G. Corces Department-range interactions and have proposed roles in nuclear organization. In this review, we explore recent findings for the roles of insulators in nuclear organization. 163 Annu.Rev.CellDev.Biol.2012.28:163-187.Downloadedfromwww

Corces, Victor G.

459

Chemical and Nutritional Ecology of Lucilia sericata (Meigen) (Diptera: Calliphoridae) as Related to Volatile Organic Compounds and Associated Essential Amino Acids  

E-Print Network [OSTI]

nutritional resources on blow fly larval performance. One GFP producing Providencia was successfully constructed to be used to visualize bacteria along the alimentary canal of L. sericata larvae to implement investigation of its impact on the physiology...

Liu, Wenqi

2014-08-07T23:59:59.000Z

460

Gas phase photocatalytic degradation on TiO{sub 2} pellets of volatile chlorinated organic compounds from a soil vapor extraction well  

SciTech Connect (OSTI)

The mineralization of trichloroethylene (TCE) and tetrachloroethylene (PCE) in gas stream from a soil vapor extraction (SVE) well was demonstrated with an annular photocatalytic reactor packed with porous TiO{sub 2} pellets in field trials at the Savannah River Site in Aiken, SC. The TiO{sub 2} pellets were prepared using a sol-gel method. The experiments were performed at 55 to 60{degree}C using space times of 10{sup 8} to 10{sup 10} g s/mol for TCE and PCE. Chloroform (CHCl{sub 3}) and carbon tetrachloride (CCl{sub 4}) were detected as minor products from side reactions. On a molar basis, CCl{sub 4} and CHCl{sub 3} produced were about 2% and 0.2 % of the reactants.

Yamazaki-Nishida, S.; Read, H.W.; Nagano, J.K.; Anderson, M.A. [Wisconsin Univ., Madison, WI (United States). Water Chemistry Program; Cervera-March, S. [Barcelona Univ., (Spain). Department of Chemical Engineering; Jarosch, T.R.; Eddy-Dilek, C.A. [Westinghouse Savannah River Co., Aiken, SC (United States)

1993-05-20T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE) at 57 amu has been previouslyby a fragment of MTBE (62%) with minor contributions fromFortner and Knighton, 2008). MTBE also in- terfered (16%)

2011-01-01T23:59:59.000Z

462

Impact of the revised OSHA exposure standard on evaluation and control of benzene and other volatile organic chemicals in the liquid petroleum pipeline industry  

SciTech Connect (OSTI)

The primary purpose of this study was to determine the benzene exposure potential of workers in the liquid petroleum pipeline industry and to assess the impact of compliance with the revised standard on this industry. In addition, exposure to ethylene dibromide (EDB), and ethylene dichloride (EDC), which have toxicological profiles similar to that of benzene and are routinely found in this industry, were evaluated and appropriate control protocols were recommended. Exposure potential to benzene in excess of the 0.5 ppm (8-hour TWA) OSHA action level was shown to be limited to three free product handling operations, and that this increased exposure potential was dependent on the length of time necessary to perform the operations. The incidence and magnitude of benzene overexposure was not severe and control could be accomplished with engineering methods, along with work practice controls and personal protective equipment. Through application of a risk assessment model it was shown that 14 excess leukemia deaths per one thousand workers could be expected in the employee population that routinely performs those operation having maximum benzene exposure potential. This compares to less than on excess leukemia death per one thousand workers in the total work population. The evaluation of EDB and EDC indicated that exposure potential to EDB was of greatest concern. Even though exposure could be limited through application of standard industrial hygiene methods, any control protocol short of total elimination of EDB from the product stream may be not sufficient to reduce exposure to accepted levels.

Mercer, D.O.

1989-01-01T23:59:59.000Z

463

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution  

E-Print Network [OSTI]

versus CO for OVOCs and acetonitrile calculated by linearThis analy- OVOCs and acetonitrile. Because OVOCs have knownwas used to measure acetonitrile, aromatics and oxy- genated

2011-01-01T23:59:59.000Z

464

Real refractive indices and volatility of secondary organic aerosol generated from photooxidation and ozonolysis of limonene, -pinene and toluene upon heating  

E-Print Network [OSTI]

C to approximately 20% at 95 şC due to additional thermophoretic forces [Burtscher et al., 2001]. Above 50 nm

Meskhidze, Nicholas

465

Quantifying the ecosystem-scale emission and deposition fluxes of biogenic volatile organic compounds (BVOC) and their oxidation products above plant canopies  

E-Print Network [OSTI]

covariance plots of vertical wind speed and m/z 127.073 (C 7correlation of vertical wind speed (w) and volume mixingcorrections between vertical wind speed and volume mixing

Park, Jeong-Hoo

2012-01-01T23:59:59.000Z

466

Installation and Operation of Sorbathene Solvent Vapor Recovery Units to Recover and Recycle Volatile Organic Compounds at Operating Sites within the Dow Chemical Company  

E-Print Network [OSTI]

because of the history of fires caused by exothermic heat of adsorption and high flammability when adsorption occurs during a long cycle time'. Three SORBATHENE units utilizing activated carbon with a short cycle time to limit temperature rise have... to the potential presence of oxygen in the vapor phase and the increased reactivity of the chemicals on the catalytic surface of the adsorbent. The extent of temperature rises and pressure swings are critical parameters. The adsorption phenomena is exothermic...

Hall, T. L.; Larrinaga, L.

467

Microorganisms for producing organic acids  

DOE Patents [OSTI]

Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

Pfleger, Brian Frederick; Begemann, Matthew Brett

2014-09-30T23:59:59.000Z

468

Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic Hybrid Thermoelectrics Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic Hybrid Thermoelectrics...

469

Movement of VOCs through the vadose zone  

E-Print Network [OSTI]

were classified into steady-state and transient methods. In the first type, difFusion coefficients were determined under steady state conditions. The second type was categorized into open tube (OTM) and closed tube methods (CTM), both measuring dif...Fusion coeflicient in the transient state. In the OTM, one end of the difFusion chamber was open to the atmosphere or to a continuous source. The CTM had the soil medium open at the end chambers but the whole system was isolated from the atmosphere. CTM gave...

Patel, Pinakin K.

1989-01-01T23:59:59.000Z

470

Pilot tests guide VOC control choice  

SciTech Connect (OSTI)

On-site pilot testing determines proper operating conditions for catalysts of pollution control equipment at optimum performance levels while demonstrating their ability to reduce emissions, odors and opacity from stack gases in manufacturing processes. Examples are provided ofr the catalytic control of emissions from coffee roasting, carbon fiber manufacturing, and can coating. Portable oxidizer units are employed in the pilot testing.

Van Benschoten, D.M. [Johnson Matthey Environmental Products, Wayne, PA (United States)

1993-10-01T23:59:59.000Z

471

8, 1182111851, 2008 VOCs during 2006  

E-Print Network [OSTI]

, Texas 77843, TX, USA 2 Molina Center for Energy and the Environment, La Jolla, California, CA, USA * now Northeast of downtown Mexico City as part of the Megacity Initiative ­ Local and Global Research the probability of significant industrial sources of the two compounds in the15 region. Wind fields during those

Boyer, Edmond

472

Comparison of Agricultural Runoff between Organic  

E-Print Network [OSTI]

Comparison of Agricultural Runoff between Organic Farming and Conventional Chemical Farming Nicole release #12;Organic Walnuts Filter strips Compost Organic pesticides Cover crops Monitoring of insects

473

Chemistry of Organic Electronic Materials 6483-Fall  

E-Print Network [OSTI]

Chemistry of Organic Electronic Materials 6483- Fall Tuesdays organic materials. The discussion will include aspects of synthesis General introduction to the electronic structure of organic materials with connection

Sherrill, David

474

Method of doping organic semiconductors  

DOE Patents [OSTI]

An apparatus has a crystalline organic semiconducting region that includes polyaromatic molecules. A source electrode and a drain electrode of a field-effect transistor are both in contact with the crystalline organic semiconducting region. A gate electrode of the field-effect transistor is located to affect the conductivity of the crystalline organic semiconducting region between the source and drain electrodes. A dielectric layer of a first dielectric that is substantially impermeable to oxygen is in contact with the crystalline organic semiconducting region. The crystalline organic semiconducting region is located between the dielectric layer and a substrate. The gate electrode is located on the dielectric layer. A portion of the crystalline organic semiconducting region is in contact with a second dielectric via an opening in the dielectric layer. A physical interface is located between the second dielectric and the first dielectric.

Kloc,; Christian Leo (Constance, DE); Ramirez; Arthur Penn (Summit, NJ); So, Woo-Young (New Providence, NJ)

2010-10-26T23:59:59.000Z

475

An examination of utility emissions contributions to elevated ozone concentrations in the Chicago area  

SciTech Connect (OSTI)

In order to reduce the pollutant load to the atmosphere and subsequent damaging effects, Titles I and IV of the Clean Air Act Amendments of 1990 (CAAAs) require reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and volatile organic compounds (VOCs). Title IV is aimed at reducing acidic deposition and requires utilities to reduce SO{sub 2} and NO{sub x} emissions to specified levels. As a consequence of this, many utilities will have to install SO{sub 2} and NO{sub x} control technologies. Title I is concerned with bringing regions into compliance with the National Ambient Air Quality Standards (NAAQS) for the criteria pollutants, among which is ozone (O{sub 3}). The NAAQS for O{sub 3} is 120 ppb (parts per billion by volume) hourly average concentration, not to be exceeded four times in three years. O{sub 3} is a secondary pollutant formed in the atmosphere when NO{sub x} and VOCs react together in the presence of sunlight. Utilities are a significant source of NO{sub x} and an unimportant source of VOCs. In the past, O{sub 3} control strategy has focused on reducing VOC emissions because of the possibility that reducing NO{sub x} actually might make O{sub 3} concentrations higher. However, this approach has not worked, perhaps because of underestimation of natural and manmade VOC emissions and transport of O{sub 3} from other regions. Computer modeling has shown that for many highly polluted areas massive NO{sub x} reductions may be necessary in addition to or in place of VOC controls. Utilities are a potential source of these NO{sub x} reductions.

Fernau, M.E.; Guziel, K.A.; South, D.W.

1993-05-01T23:59:59.000Z

476

Digestive System general organization throughout  

E-Print Network [OSTI]

Digestive System general organization throughout: mucosa, submucosa, muscularis externa, serosa digestive glands salivary pancreas liver (lobes: right, left, caudate, quadrate, diaphragmatic surface, bare

Houde, Peter

477

IX. Standards for Student Organizations Standards of all Student Organizations  

E-Print Network [OSTI]

1 of 8 IX. Standards for Student Organizations Standards of all Student Organizations As stated to the same standards of conduct to which students are held on an individual basis. Standards for Fraternities on February 25, 1976 - the University has developed the following standards for fraternity/sorority life

Marsh, David

478

Health and Safety Guide for Home Performance Contractors  

E-Print Network [OSTI]

Organic Compounds (VOCs) Water heater repair/replacementfireplaces Pipe insulation Water heater insulation Asbestosboilers woodstoves water heaters ranges clothes dryers

Stratton, Chris

2014-01-01T23:59:59.000Z

479

The use of auxiliary ignition devices to improve combustion of low centane-high volatility fuels in a diesel engine  

SciTech Connect (OSTI)

The use of auxiliary ignition devices to improve the combustion of low cetane-high volatility fuels in a Diesel engine is described. Previous combustion with a low cetane-high volatility fuel (with a spark plug located at the periphery of the cylinder) resulted in engine knock at heavy loads and poor engine operation at light loads. In the present investigation, several new ignition devices were used to ignite the fuel in the center of the cylinder, to allow combustion to be controlled by rate of injection. The devices used were an extended spark electrode, a fuel spray deflector, a nozzle glow ring, and a nozzle fuel cage. High speed photography and heat release were used to characterize the ignition and combustion process of the low cetane fuel in conjunction with the ignition devices. Combustion with all of the ignition devices was initiated in the center of the cylinder, significantly reducing engine knock. The use of the auxiliary ignition devices to ignite the fuel in the center of the chamber demonstrated extended operation of the Diesel engine for all of the devices tested.

Stroia, B.L.; Abata. D.L.

1988-01-01T23:59:59.000Z

480

A hybrid magnetic/complementary metal oxide semiconductor three-context memory bit cell for non-volatile circuit design  

SciTech Connect (OSTI)

After decades of continued scaling to the beat of Moore's law, it now appears that conventional silicon based devices are approaching their physical limits. In today's deep-submicron nodes, a number of short-channel and quantum effects are emerging that affect the manufacturing process, as well as, the functionality of the microelectronic systems-on-chip. Spintronics devices that exploit both the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, are promising solutions to circumvent these scaling threats. Being compatible with the CMOS technology, such devices offer a promising synergy of radiation immunity, infinite endurance, non-volatility, increased density, etc. In this paper, we present a hybrid (magnetic/CMOS) cell that is able to store and process data both electrically and magnetically. The cell is based on perpendicular spin-transfer torque magnetic tunnel junctions (STT-MTJs) and is suitable for use in magnetic random access memories and reprogrammable computing (non-volatile registers, processor cache memories, magnetic field-programmable gate arrays, etc). To demonstrate the potential our hybrid cell, we physically implemented a small hybrid memory block using 45?nm × 45?nm round MTJs for the magnetic part and 28?nm fully depleted silicon on insulator (FD-SOI) technology for the CMOS part. We also report the cells measured performances in terms of area, robustness, read/write speed and energy consumption.

Jovanovi?, B., E-mail: bojan.jovanovic@lirmm.fr, E-mail: lionel.torres@lirmm.fr; Brum, R. M.; Torres, L. [LIRMM—University of Montpellier 2/UMR CNRS 5506, 161 Rue Ada, 34095 Montpellier (France)

2014-04-07T23:59:59.000Z

Note: This page contains sample records for the topic "voc volatile organic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Sample extraction and injection with a microscale preconcentrator.  

SciTech Connect (OSTI)

This report details the development of a microfabricated preconcentrator that functions as a fully integrated chemical extractor-injector for a microscale gas chromatograph (GC). The device enables parts-per-billion detection and quantitative analysis of volatile organic compounds (VOCs) in indoor air with size and power advantages over macro-scale systems. The 44 mm{sup 3} preconcentrator extracts VOCs using highly adsorptive, granular forms of graphitized carbon black and carbon molecular sieves. The micron-sized silicon cavities have integrated heating and temperature sensing allowing low power, yet rapid heating to thermally desorb the collected VOCs (GC injection). The keys to device construction are a new adsorbent-solvent filling technique and solvent-tolerant wafer-level silicon-gold eutectic bonding technology. The product is the first granular adsorbent preconcentrator integrated at the wafer level. Other advantages include exhaustive VOC extraction and injection peak widths an order of magnitude narrower than predecessor prototypes. A mass transfer model, the first for any microscale preconcentrator, is developed to describe both adsorption and desorption behaviors. The physically intuitive model uses implicit and explicit finite differences to numerically solve the required partial differential equations. The model is applied to the adsorption and desorption of decane at various concentrations to extract Langmuir adsorption isotherm parameters from effluent curve measurements where properties are unknown a priori.

Robinson, Alex Lockwood (Advanced Sensor Technologies, Albuquerque, NM); Chan, Helena Kai Lun

2007-09-01T23:59:59.000Z

482

In situ treatment of mixed contaminants in groundwater: Review of candidate processes  

SciTech Connect (OSTI)

This document describes the screening and preliminary evaluation of candidate treatment for use in treating mixed contaminants volatile organic compounds (VOCs) and radionuclides in groundwater. Treating mixed contaminants presents unusual difficulties. Typically, VOCs are the most abundant contaminants, but the presence of radionuclides results in additional health concerns that must be addressed, usually by a treatment approach different from that used for VOCs. Furthermore, the presence of radionuclides may yield mixed solid wastes if the VOCs are treated by conventional means. These issues were specifically addressed in the evaluation of candidate treatment processes for testing in this program. Moreover, because no research or early development of a particular process would be performed, the technology review also focused on technologies that could be readily adapted and integrated for use with mixed contaminants. The objective is to couple emerging or available processes into treatment modules for use in situ. The three year project, to be completed in September 1996, includes a full-scale field demonstration. The findings reported in this document encompass all activities through the treatment process evaluations.

Korte, N.E. [ed.] [Oak Ridge National Lab., Grand Junction, CO (United States)] [ed.; Oak Ridge National Lab., Grand Junction, CO (United States); Siegrist, R.L. [ed.] [Oak Ridge National Lab., TN (United States)] [ed.; Oak Ridge National Lab., TN (United States); Ally, M. [and others] [and others

1994-10-01T23:59:59.000Z

483

Fast photoreactions of ethanol and MTBE on tropospheric metal oxide particles  

SciTech Connect (OSTI)

Ethanol (EtOH) and tert-Butyl methyl ether (MTBE) are both finding increased use as oxygenated additives to fuels. However, the environmental fate in the troposphere of these species is unclear when they escape as fugitive emissions. In several locations there are reports of human illness in response to MTBE in particular. Volatile organic compounds (VOC`s) such as these are generally thought to react by a variety of homogeneous free-radical mechanisms, usually beginning with attack by OH radical. However, we show by laboratory kinetic studies that the heterogeneous photoreaction on solid suspended metal-oxide particulates such as fly ash proceeds with a comparable rate, especially in urban environments. EtOH reacts to form acetaldehyde, and EtOH forms isobutene, methanol, and formaldehyde. Our work appears to be the first-ever demonstration that VOC`s can react as fast by a heterogeneous mechanism as by a homogeneous one in the atmosphere. Experiments by various optical and kinetic techniques show that the active phases in fly ash are Fe oxides, which are fairly abundant in other atmospheric particulates as well.

Idriss, H.; Seebauer, E.G. [Univ. of Illinois, Urbana, IL (United States)

1995-12-31T23:59:59.000Z

484

Passive soil venting at the Chemical Waste Landfill Site at Sandia National Laboratories, Albuquerque, New Mexico  

SciTech Connect (OSTI)

Passive Soil Vapor Extraction was tested at the Chemical Waste Landfill (CWL) site at Sandia National Laboratories, New Mexico (SNLIW). Data collected included ambient pressures, differential pressures between soil gas and ambient air, gas flow rates into and out of the soil and concentrations of volatile organic compounds (VOCS) in vented soil gas. From the differential pressure and flow rate data, estimates of permeability were arrived at and compared with estimates from other studies. Flow, differential pressure, and ambient pressure data were collected for nearly 30 days. VOC data were collected for two six-hour periods during this time. Total VOC emissions were calculated and found to be under the limit set by the Resource Conservation and Recovery Act (RCRA). Although a complete process evaluation is not possible with the data gathered, some of the necessary information for designing a passive venting process was determined and the important parameters for designing the process were indicated. More study is required to evaluate long-term VOC removal using passive venting and to establish total remediation costs when passive venting is used as a polishing process following active soil vapor extraction.

Phelan, J.M.; Reavis, B.; Cheng, W.C.

1995-05-01T23:59:59.000Z

485

Final Technical Report  

SciTech Connect (OSTI)

This DOE project DE-FC36-04GO14052 ''Plasma Pilot Plant Test for Treating VOC Emissions from Wood Products Plants'' was conducted by Drexel University in cooperation with Georgia-Pacific (G-P) and Kurchatov Institute (KI). The objective of this project was to test the Plasma Pilot Plant capabilities in wood industry. The final goal of the project was to replace the current state-of-the-art, regenerative thermal oxidation (RTO) technology by Low-Temperature Plasma Technology (LTPT) in paper and wood industry for Volatile Organic Components (VOC) destruction in High Volume Low Concentration (HVLC) vent emissions. MetPro Corporation joined the team as an industrial partner from the environmental control business and a potential leader for commercialization. Concurrent Technology Corporation (CTC) has a separate contract with DOE for this technology evaluation. They prepared questionnaires for comparison of this technology and RTO, and made this comparison. These data are presented in this report along with the description of the technology itself. Experiments with the pilot plant were performed with average plasma power up to 3.6 kW. Different design of the laboratory and pilot plant pulsed coronas, as well as different analytical methods revealed many new peculiarities of the VOC abatement process. The work reported herein describes the experimental results for the VOCs removal efficiency with respect to energy consumption, residence time, water effect and initial concentration.

Alexander Fridman

2005-06-01T23:59:59.000Z

486

Optimization of soil mixing technology through metallic iron addition.  

SciTech Connect (OSTI)

Enhanced soil mixing is a process used to remove volatile organic compounds (VOCs) from soil. In this process, also known as soil mixing with thermally enhanced soil vapor extraction, or SM/TESVE, a soil mixing apparatus breaks up and mixes a column of soil up to 9 m (30 ft) deep; simultaneously, hot air is blown through the soil. The hot air carries the VOCs to the surface where they are collected and safely disposed of. This technology is cost effective at high VOC concentrations, but it becomes cost prohibitive at low concentrations. Argonne National Laboratory-East conducted a project to evaluate ways of improving the effectiveness of this system. The project investigated the feasibility of integrating the SM/TESVE process with three soil treatment processes--soil vapor extraction, augmented indigenous biodegradation, and zero-valent iron addition. Each of these technologies was considered a polishing treatment designed to remove the contaminants left behind by enhanced soil mixing. The experiment was designed to determine if the overall VOC removal effectiveness and cost-effectiveness of the SM/TESVE process could be improved by integrating this approach with one of the polishing treatment systems.

Moos, L. P.

1999-01-15T23:59:59.000Z

487

An Alternative to Performing Remote-Handled Transuranic Waste Container Headspace Gas Sampling and Analysis  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) is operating under a Resource Conservation and Recovery Act (RCRA) Hazardous Waste Facility Permit (HWFP) for contact-handled (CH) transuranic (TRU) waste. The HWFP contains limitations on allowable emissions from waste disposed in the underground. This environmental performance standard imposed on the WIPP consists of limiting volatile organic compound (VOC) emissions from emplaced waste to ensure protection of human health and the environment. The standard is currently met by tracking individual waste container headspace gas concentrations, which are determined by headspace gas sampling and analysis of CH TRU waste containers. The WIPP is seeking a HWFP modification to allow the disposal of remote-handled (RH) TRU waste. Because RH TRU waste is limited to approximately 5% of the waste volume and is emplaced in the disposal room walls, it is possible to bound the potential RH TRU waste contribution to VOC emissions using conservative upper bounds. These conservative upper bounds were developed as an alternative to RH TRU waste canister headspace gas sampling and analysis. The methodology used to perform the calculations used to evaluate VOC emissions from emplaced RH TRU waste canisters applied the same equations as those used to evaluate VOC emissions in the original HWFP application.

Spangler, L. R.; Djordjevic, S. M.; Kehrman, R. F.; Most, W. A.

2002-02-26T23:59:59.000Z

488

Acid Catalysis in Modern Organic  

E-Print Network [OSTI]

catalyst for organic synthesis". That is the starting sentence of this book by Yamamoto and Ishihara, which follows their earlier book "Lewis Acids in Organic Synthesis (2000)", and covers the new developments book that should be available in every well-equipped chemistry library. It will certainly be helpful

Snyder, Scott A.

489

The Anaerobic Digestion of Organic  

E-Print Network [OSTI]

and commercialization. Anaerobic digestion (AD) of organic municipal solid waste and subsequent biogas and methaneThe Anaerobic Digestion of Organic Municipal Solid Waste in California. Anaerobic Digestion Technology 2.1. Feedstock Characterization 2.2. Collection & Sorting 2.2.1. Waste

Iglesia, Enrique

490

Public health assessment for Chem-Central, Grand Rapids, Kent County, Michigan, Region 5. Cerclis No. MID980477079. Final report  

SciTech Connect (OSTI)

Chem Chentral, a distributor of bulk chemicals, is located in Wyoming, Michigan. Between 1957 and 1962, a fault in the piping at this facility allowed chemicals to leak into the ground. In 1977, the Michigan Department of Natural Resources (MDNR) discovered that a section of ditch 1,000 feet north of the Chem Central property was contaminated with polychlorinated biphenyls (PCBs) and volatile organic chemicals (VOCs). The MDNR traced this contamination to Chem Central, and identified a plume of VOC contamination in the groundwater between the Chem Central property and the ditch. The site poses an indeterminate public health hazard under present conditions because the possibility of exposure to PCBs from the site through the biota of Cole Drain and Plaster Creek has not been fully investigated. The known completed exposure pathway, through surface soil on the site, poses no significant health hazard. Potential exposure pathways include the possible future use of contaminated groundwater.

Not Available

1994-01-19T23:59:59.000Z

491

Transport characteristics across drum filter vents and polymer bags  

SciTech Connect (OSTI)

The rate at which hydrogen (H {sub 2}) or a volatile organic compound (VOC) exits a layer of confinement in a vented waste drum is proportional to the concentration difference across the layer. The proportionality constant is the gas transport characteristic. A series of transport experiments were conducted to determine H{sub 2} and VOC transport characteristics across different drum filter vents and polymer bags. This report reviews the methods and results of past investigators in defining transport characteristics across filter vents and polymer bags, describes the apparatus and procedures used in these experiments, compares the reported and estimated transport characteristics with earlier results, and discusses the impact of changing the transport characteristic values used in model calculations.

Liekhus, K.J.

1994-08-01T23:59:59.000Z

492

Emissions Inventory Report Summary: Reporting Requirements for the New Mexico Administrative code, Title 20, Chapter 2, Part 73 (20 NMAC 2.73) for Calendar Year 1997  

SciTech Connect (OSTI)

Los Alamos National Laboratory (the Laboratory) is subject to emissions reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73, (20 NMAC 2.73), Notice of Intent and Emissions Inventory Requirements. The Laboratory has the potential to emit 100 tons per year of suspended particulate matter (PM), nitrogen oxides (NO{sub x}), carbon monoxide (CO), and volatile organic compounds (VOCs). For 1997, combustion products from the industrial sources contributed the greatest amount of regulated air emissions from the Laboratory. Research and development activities contributed the greatest amount of VOCs. Emissions of beryllium and aluminum were reported for activities permitted under 20 NMAC 2.72, Construction Permits.

NONE

1999-01-01T23:59:59.000Z

493

An assessment of the flammability and explosion potential of transuranic waste  

SciTech Connect (OSTI)

The explosion potential of transuranic (TRU) waste, destined for the Waste Isolation Pilot (WIPP), was recently examined in EEG-45. That investigation focused on the volatile organic compounds (VOCs) in the waste, particularly acetone, and concluded that an explosion due to the VOCs was unlikely. Recent evidence raises serious concerns about drums containing mixed radioactive hazardous waste bound for the WIPP. Static electricity generated by the plastic bags represents a potential ignition source for other fuels, such as methane gas or hydrogen gas, during transportation and during the test phase. The potential danger of explosion due to hydrogen gas or methane gas generation has not yet been resolved. This report investigates that potential hazard and examines documented ignitions, fires, explosions and incidents of overpressurization of containers at generating and storage sites planning to send transuranic waste to the WIPP for disposal. 68 refs., 6 figs.

Silva, M.

1991-06-01T23:59:59.000Z

494

Modeling morphology evolution during solvent-based fabrication of organic solar cells  

E-Print Network [OSTI]

Solvent-based techniques usually involve preparing dilute blends of electron-donor and electron-acceptor materials dissolved in a volatile solvent. After some form of coating onto a substrate, the solvent evaporates. An initially homogeneous mixture separates into electron-acceptor rich and electron-donor rich regions as the solvent evaporates. Depending on the specifics of the blend and processing conditions different morphologies are typically formed. Experimental evidence consistently confirms that the morphology critically affects device performance. A computational framework that can predict morphology evolution can significantly augment experimental analysis. Such a framework will also allow high throughput analysis of the large phase space of processing parameters, thus yielding insight into the process-structure-property relationships. In this paper, we formulate a computational framework to predict evolution of morphology during solvent-based fabrication of organic thin films. This is accomplished by...

Wodo, Olga

2011-01-01T23:59:59.000Z

495

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents [OSTI]

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

1998-05-19T23:59:59.000Z

496

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents [OSTI]

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

Taylor, Robert T. (Livermore, CA); Jackson, Kenneth J. (San Leandro, CA); Duba, Alfred G. (Livermore, CA); Chen, Ching-I (Danville, CA)

1998-01-01T23:59:59.000Z

497

Vapor port and groundwater sampling well  

DOE Patents [OSTI]

A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

Hubbell, Joel M. (Idaho Falls, ID); Wylie, Allan H. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

498

Vadose Zone Remediation Assessment: M-Area Process Sewer Soil Vapor Extraction Units 782-5M, 782-7M, and 782-8M  

SciTech Connect (OSTI)

This study focuses on the status of the vadose zone remediation along 1600 ft of the process sewer line between the M-Area security fence and the M-Area settling basin. Three soil vapor extraction (SVE) units 782-5M, 782-7M, and 782-8M, connected to 4 vertical wells and 3 horizontal wells have been addressing the vadose zone volatile organic contamination (VOC) since 1995. The specific objectives of this study were to obtain soil gas and sediment samples, evaluate SVE units and vadose zone remediation, and make recommendations to address further remediation needs.

Riha, B.D.

2001-04-20T23:59:59.000Z

499

Vapor port and groundwater sampling well  

DOE Patents [OSTI]

A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

Hubbell, J.M.; Wylie, A.H.

1996-01-09T23:59:59.000Z

500

No-migration variance petition. Appendix B, Attachments E--Q: Volume 4, Revision 1  

SciTech Connect (OSTI)

Volume IV contains the following attachments: TRU mixed waste characterization database; hazardous constituents of Rocky flats transuranic waste; summary of waste components in TRU waste sampling program at INEL; total volatile organic compounds (VOC) analyses at Rocky Flats Plant; total metals analyses from Rocky Flats Plant; results of toxicity characteristic leaching procedure (TCLP) analyses; results of extraction procedure (EP) toxicity data analyses; summary of headspace gas analysis in Rocky Flats Plant (RFP) -- sampling program FY 1988; waste drum gas generation--sampling program at Rocky Flats Plant during FY 1988; TRU waste sampling program -- volume one; TRU waste sampling program -- volume two; and summary of headspace gas analyses in TRU waste sampling program; summary of volatile organic compounds (V0C) -- analyses in TRU waste sampling program.

Not Available

1990-03-01T23:59:59.000Z