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1

Remedial actions at the former Vitro Rare Metals plant site, Canonsburg, Washington County, Pennsylvania. Final Environmental Impact Statement. Volume I  

SciTech Connect (OSTI)

The environmental impacts associated with remedial actions in connection with residual radioactive materials remaining at the inactive uranium processing site located in Canonsburg, Washington County, Pennsylvania are evaluated. The Canonsburg site is an 18.5-acre property that was formerly owned by the Vitro Rare Metals Company. The expanded Canonsburg site would be 30-acre property that would include the Canonsburg site (the former Vitro Rare Metals plant), seven adjacent private houses, and the former Georges Pottery property. During the period 1942 through 1957 the Vitro Manufacturing Company and its successor, the Vitro Corporation of America, processed onsite residues and ores, and government-owned ores, concentrates, and scraps to extract uranium and other rare metals. The Canonsburg site is now the Canon Industrial Park. In addition to storing the residual radioactive materials of this process at the Canonsburg site, about 12,000 tons of radioactively contaminated materials were transferred to a railroad landfill in Burrell Township, Indiana County, Pennsylvania. This Canonsburg FEIS evaluates five alternatives for removing the potential public health hazard associated with the radioactively contaminated materials. In addition to no action, these alternatives involve various combinations of stabilization of the radioactively contaminated materials in place or decontamination of the Canonsburg and Burrell sites by removing the radioactively contaminated materials to another location. In addition to the two sites mentioned, a third site located in Hanover Township, Washington County, Pennsylvania has been considered as a disposal site to which the radioactively contaminated materials presently located at either of the other two sites might be moved.

Not Available

1983-07-01T23:59:59.000Z

2

About Rare Earth Metals | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

About Rare Earth Metals What Are Rare Earths? Ames Laboratory's Materials Preparation Center The Ames Process for Purification of Rare Earths USGS Rare Earth Information Rare Earth...

3

Ecotoxicity of rare earth elements Rare earth elements (REEs) or rare earth metals is the  

E-Print Network [OSTI]

Ecotoxicity of rare earth elements Info Sheet Rare earth elements (REEs) or rare earth metals isolated. Actually, most rare earth elements exist in the Earth's crust in higher concentrations than though most people have never heard of rare earth elements, sev- eral of them govern mankind's modern

Wehrli, Bernhard

4

Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction  

DOE Patents [OSTI]

Method of treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation.

Ellis, Timothy W. (Ames, IA); Schmidt, Frederick A. (Ames, IA)

1995-08-01T23:59:59.000Z

5

Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction  

DOE Patents [OSTI]

A method is described for treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation. 2 figs.

Ellis, T.W.; Schmidt, F.A.

1995-08-01T23:59:59.000Z

6

Valuable rare earth metals from old electronics | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Valuable rare earth metals from old electronics Scientists at the Critical Materials Institute have developed a two-step recovery process that makes recycling rare-earth metals...

7

ONDES DE SPIN MAGNETISM IN THE LIGHT RARE EARTH 'METALS  

E-Print Network [OSTI]

ONDES DE SPIN MAGNETISM IN THE LIGHT RARE EARTH 'METALS A. R. MACKINTOSH H. C. Mrsted Institute terres rares Ikgeres. Abstract. -The magnetic properties of the light rare earth metals are reviewed interaction. The discussion is illustrated by recent magnetization and neutron diffraction measurements

Boyer, Edmond

8

The Materials Preparation Center - Making Rare Earth Metals - Part 3  

SciTech Connect (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 3 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

9

The Materials Preparation Center - Making Rare Earth Metals - Part 2  

SciTech Connect (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 2 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

10

The Materials Preparation Center - Making Rare Earth Metals - Part 1  

SciTech Connect (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 1 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

11

The Materials Preparation Center - Making Rare Earth Metals - Part 4  

SciTech Connect (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 4 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

12

The Materials Preparation Center - Making Rare Earth Metals - Part 4  

ScienceCinema (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 4 of 4.

Riedemann, Trevor

2013-03-01T23:59:59.000Z

13

The Materials Preparation Center - Making Rare Earth Metals - Part 1  

ScienceCinema (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 1 of 4.

Riedemann, Trevor

2013-03-01T23:59:59.000Z

14

The Materials Preparation Center - Making Rare Earth Metals - Part 2  

ScienceCinema (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 2 of 4.

Riedemann, Trevor

2013-03-01T23:59:59.000Z

15

The Materials Preparation Center - Making Rare Earth Metals - Part 3  

ScienceCinema (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 3 of 4.

Riedemann, Trevor

2013-03-01T23:59:59.000Z

16

New CMI process recycles valuable rare earth metals from old...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

New CMI process recycles valuable rare earth metals from old electronics Contacts: For release: Feb. 26, 2015 Ryan Ott, Critical Materials Institute, 515-294-3616 Laura Millsaps,...

17

Method for treating rare earth-transition metal scrap  

DOE Patents [OSTI]

Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a prefused, rare earth fluoride-bearing flux of CaF.sub.2, CaCl.sub.2 or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA); Jones, Lawrence L. (Des Moines, IA)

1992-12-29T23:59:59.000Z

18

Method for treating rare earth-transition metal scrap  

DOE Patents [OSTI]

Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a rare earth fluoride-bearing flux of CaF[sub 2], CaCl[sub 2] or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy. 3 figs.

Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.; Jones, L.L.

1992-12-29T23:59:59.000Z

19

RARE-EARTH METALS--1997 61.1 RARE-EARTH METALS  

E-Print Network [OSTI]

million, to thulium and lutetium, the least abundant rare-earth elements at about 0.5 parts per million. Scandium, atomic number 21, is the lightest rare-earth element. It is the 31st most abundant element and is the second most abundant rare earth in the Earth's crust. The lanthanides consist of a group of 15 elements

20

Nuclear orientation studies of rare-earth metals  

SciTech Connect (OSTI)

The angular distributions of gamma rays from /sup 166m/Ho and /sup 160/Tb aligned at low temperatures in, respectively, Ho metal and Tb metal have been measured. Large hyperfine splittings, expected for the rare earths, have been deduced from the temperature dependence of the gamma-ray anisotropies. Both samples show a macroscopic magnetic anisotropy that is not consistent with an interpretation in terms of a randomly oriented polycrystalline structure.

Krane, K.S.; Morgan, G.L.; Moses, J.D.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Rare earth-transition metal scrap treatment method  

DOE Patents [OSTI]

Rare earth-transition metal (e.g. iron) scrap (e.g. Nd-Fe-B scrap) is melted to reduce the levels of tramp oxygen and nitrogen impurities therein. The tramp impurities are reduced in the melt by virtue of the reaction of the tramp impurities and the rare earth to form dross on the melt. The purified melt is separated from the dross for reuse. The oxygen and nitrogen of the melt are reduced to levels acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA); Jones, Lawrence L. (Des Moines, IA); Lincoln, Lanny P. (Woodward, IA)

1992-02-11T23:59:59.000Z

22

Rare earth-transition metal scrap treatment method  

DOE Patents [OSTI]

Rare earth-transition metal (e.g. iron) scrap (e.g. Nd-Fe-B scrap) is melted to reduce the levels of tramp oxygen and nitrogen impurities therein. The tramp impurities are reduced in the melt by virtue of the reaction of the tramp impurities and the rare earth to form dross on the melt. The purified melt is separated from the dross for reuse. The oxygen and nitrogen of the melt are reduced to levels acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. 3 figs.

Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.; Jones, L.L.; Lincoln, L.P.

1992-02-11T23:59:59.000Z

23

DOE Announces RFI on Rare Earth Metals | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power Systems EngineeringDepartmentSmart GridThirdPartnershipDrillingRFI on Rare Earth Metals DOE

24

DOE - Office of Legacy Management -- International Rare Metals Refinery Inc  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou are here HomeGunnison- NY 38 Rare Metals

25

Reduction Chemistry of Rare-Earth Metal Complexes: Toward New Reactivity and Properties  

E-Print Network [OSTI]

Elsner, A. ; Milliken, M. As hybrid cars gobble rare metals,rare-earths are heavily used in fuel-efficient hybrid cars.In a leading model of hybrid car, 1 kilogram of neodymium

Huang, Wenliang

2013-01-01T23:59:59.000Z

26

Solvent extraction of rare-earth metals by carboxylic acids  

SciTech Connect (OSTI)

The solvent extraction of the trivalent lanthanides and yttrium from nitrate media by solutions of carboxylic acids in xylene has been studied. Commercially available carboxylic acids such as Versatic 10 and naphthenic acids were used, as well as model compounds of known structure, such as 2-ethylhexanoic and 3-cyclohexylpropanoic acids. In a few cases, extraction of the metals from sulphate and chloride solutions was also investigated. The dependence of the extraction properties of the carboxylic acids on the atomic number of the lanthanide shows a definite relationship to the steric bulk of the carboxylic acid molecule quantified by means of the steric parameter, E{sub s}{prime} of the substituent alkyl group. The stoichiometries of the extracted complexes for representative light (La), middle (Gd) and heavy (Lu) rare-earth metals were investigated by the slope-analysis technique for a sterically hindered acid (Versatic 10 acid; -E{prime}{sub s} = 3.83) and an acid with low steric hindrance (3-cyclohexylpropanoic acid; -E{prime}{sub s} = 0.28). 14 refs., 13 figs., 3 tabs.

Preez, A.C. du; Preston, J.S. [Mintek, Randburg (South Africa)

1992-04-01T23:59:59.000Z

27

MATERIALS WORLD January 201216 Dr Steve Barrett from the University of Liverpool, UK, has been studying rare earth metals for  

E-Print Network [OSTI]

to the functionality of these scarce elements. S tudies into the properties of rare earth metals have been active since of rare earth metals have been examined since the elements themselves were discovered. Much studying rare earth metals for 20 years. Here he explains how preparation of the surface layer is crucial

Barrett, Steve D.

28

High Pressure Phase Transformations in Heavy Rare Earth Metals and Connections to Actinide Crystal Structures  

SciTech Connect (OSTI)

High-pressure studies have been performed on heavy rare earth metals Terbium (Tb) to 155 GPa and Holmium (Ho) to 134 GPa in a diamond anvil cell at room temperature. The following crystal structure sequence was observed in both metals hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc (hR-24) {yields} monoclinic (C2/m) with increasing pressure. The last transformation to a low symmetry monoclinic phase is accompanied by a volume collapse of 5 % for Tb at 51 GPa and a volume collapse of 3 % for Ho at 103 GPa. This volume collapse under high pressure is reminiscent of f-shell delocalization in light rare earth metal Cerium (Ce), Praseodymium (Pr), and heavy actinide metals Americium (Am) and Curium (Cm). The orthorhombic Pnma phase that has been reported in Am and Cm after f-shell delocalization is not observed in heavy rare earth metals under high pressures. (authors)

Vohra, Yogesh K.; Sangala, Bagvanth Reddy; Stemshorn, Andrew K. [Physics, University of Alabama at Birmingham (UAB), 310 Campbell Hall, 1300 University Boulevard, Birmingham, AL, 35294-1170 (United States); Hope, Kevin M. [Biology, Chemistry, and Mathematics, University of Montevallo, Harman Hall, Station 6480, Montevallo, AL, 35115 (United States)

2008-07-01T23:59:59.000Z

29

Yttrium and rare earth stabilized fast reactor metal fuel  

DOE Patents [OSTI]

To increase the operating temperature of a reactor, the melting point and mechanical properties of the fuel must be increased. For an actinide-rich fuel, yttrium, lanthanum and/or rare earth elements can be added, as stabilizers, to uranium and plutonium and/or a mixture of other actinides to raise the melting point of the fuel and improve its mechanical properties. Since only about 1% of the actinide fuel may be yttrium, lanthanum, or a rare earth element, the neutron penalty is low, the reactor core size can be reduced, the fuel can be burned efficiently, reprocessing requirements are reduced, and the nuclear waste disposal volumes reduced. A further advantage occurs when yttrium, lanthanum, and/or other rare earth elements are exposed to radiation in a reactor, they produce only short half life radioisotopes, which reduce nuclear waste disposal problems through much shorter assured-isolation requirements.

Guon, Jerold (Woodland Hills, CA); Grantham, LeRoy F. (Calabasas, CA); Specht, Eugene R. (Simi Valley, CA)

1992-01-01T23:59:59.000Z

30

Understanding of Rare Earth Metals from Theory | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof2014National Nuclear23, 2014Cell Imaging. |fromof Rare

31

Rare Earth Metals for Science | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromising Science for1Principal InvestigatorsLivingstonNNSARareRare

32

Metallic beam development for the Facility for Rare Isotope Beam  

SciTech Connect (OSTI)

The Facility for Rare Isotope Beams (FRIB) at Michigan State University (MSU) will accelerate a primary ion beam to energies beyond 200 MeV/u using a superconducting RF linac and will reach a maximum beam power of 400 kW on the fragmentation target. The beam intensity needed from the ECR ion source is expected to be between 0.4 and 0.5 emA for most medium mass to heavy mass elements. Adding to the challenge of reaching the required intensity, an expanded list of primary beams of interest has been established based on the production rate and the number of isotope beams that could be produced with FRIB. We report here on the development done for some of the beam in the list including mercury (natural), molybdenum ({sup 98}Mo), and selenium ({sup 82}Ser)

Machicoane, Guillaume, E-mail: machicoa@nscl.msu.edu; Cole, Dallas; Leitner, Daniela; Neben, Derek; Tobos, Larry [Facility for Rare Isotope Beam, Michigan State University, East Lansing, Michigan 48824 (United States)] [Facility for Rare Isotope Beam, Michigan State University, East Lansing, Michigan 48824 (United States)

2014-02-15T23:59:59.000Z

33

Dynamic polarizabilities of rare-earth-metal atoms and dispersion coefficients for their interaction with helium atoms  

E-Print Network [OSTI]

Dynamic polarizabilities of rare-earth-metal atoms and dispersion coefficients for their interaction with helium atoms Xi Chu Department of Chemistry, University of Montana, Missoula, Montana 59812; published 29 March 2007 The dynamic scalar and tensor polarizabilities of the rare-earth-metal atoms

Chu, Xi

34

Ternary rare earth and actinoid transition metal carbides viewed as carbometalates  

SciTech Connect (OSTI)

Ternary carbides A{sub x}T{sub y}C{sub z} (A=rare earth metals and actinoids; T=transition metals) with monoatomic species C{sup 4-} as structural entities are classified according to the criteria (i) metal to carbon ratio, (ii) coordination number of the transition metal by carbon atoms, and (iii) the dimensionality of the anionic network [T{sub y}C{sub z}]{sup n-}. Two groups are clearly distinguishable, depending on the metal to carbon ratio. Those where this ratio is equal to or smaller than 2 may be viewed as carbometalates, thus extending the sequence of complex anions from fluoro-, oxo-, and nitridometalates to carbometalates. The second group, metal-rich carbides with metal to carbon ratios equal to or larger than 4 is better viewed as typical intermetallics (''interstitial carbides''). The chemical bonding properties have been investigated by analyzing the Crystal Orbital Hamilton Population (COHP). The chemical bonding situation with respect to individual T-C bonds is similar in both classes. The main difference is the larger number of metal-metal bonds in the crystal structures of the metal-rich carbides.

Dashjav, Enkhtsetseg [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Kreiner, Guido [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Schnelle, Walter [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Wagner, Frank R. [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Kniep, Ruediger [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany)], E-mail: Kniep@cpfs.mpg.de; Jeitschko, Wolfgang [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster, Wilhelm-Klemm-Strasse 8, D-48149 Muenster (Germany)], E-mail: jeitsch@uni-muenster.de

2007-02-15T23:59:59.000Z

35

Behaviour of zirconium, niobium, yttrium and the rare earth elements in the Thor Lake rare-metal  

E-Print Network [OSTI]

Behaviour of zirconium, niobium, yttrium and the rare earth elements in the Thor Lake rare and the heavy rare earth elements in the world. Much of the potentially economic mineralization was concentrated of Science Department of Earth and Planetary Sciences McGill University, Montreal, QC, Canada February 2010

36

Rare-earth transition-metal intermetallics: Structure-bonding-property relationships  

SciTech Connect (OSTI)

The explorations of rare-earth, transition metal intermetallics have resulted in the synthesis and characterization, and electronic structure investigation, as well as understanding the structure-bonding property relationships. The work has presented the following results: (1) Understanding the relationship between compositions and properties in LaFe{sub 13-x}Si{sub x} system: A detailed structural and theoretical investigation provided the understanding of the role of a third element on stabilizing the structure and controlling the transformation of cubic NaZn{sub 13}-type structures to the tetragonal derivative, as well as the relationship between the structures and properties. (2) Synthesis of new ternary rare-earth iron silicides Re{sub 2-x}Fe{sub 4}Si{sub 14-y} and proposed superstructure: This compound offers complex structural challenges such as fractional occupancies and their ordering in superstructure. (3) Electronic structure calculation of FeSi{sub 2}: This shows that the metal-semiconductor phase transition depends on the structure. The mechanism of band gap opening is described in terms of bonding and structural distortion. This result shows that the electronic structure calculations are an essential tool for understanding the relationship between structure and chemical bonding in these compounds. (4) Synthesis of new ternary rare-earth Zinc aluminides Tb{sub 3}Zn{sub 3.6}Al{sub 7.4}: Partially ordered structure of Tb{sub 3}Zn{sub 3.6}Al{sub 7.4} compound provides new insights into the formation, composition and structure of rare-earth transition-metal intermetallics. Electronic structure calculations attribute the observed composition to optimizing metal-metal bonding in the electronegative (Zn, Al) framework, while the specific ordering is strongly influenced by specific orbital interactions. (5) Synthesis of new structure type of Zn{sub 39}(Cr{sub x}Al{sub 1-x}){sub 81}: These layered structures are similar to icosahedral Mn-Al quasicrystalline compounds. Therefore, this compound may provide new insights into the formation, composition and structure of quasicrystalline materials.

Han, M.K.

2006-05-06T23:59:59.000Z

37

Rare-Earth Transition-Metal Intermetallics: Structure-bonding-Property Relationships  

SciTech Connect (OSTI)

Our explorations of rare-earth, transition metal intermetallics have resulted in the synthesis and characterization, and electronic structure investigation, as well as understanding the structure-bonding-property relationships. Our work has presented the following results: (1) Understanding the relationship between compositions and properties in LaFe{sub 13-x}Si{sub x} system: A detailed structural and theoretical investigation provided the understanding of the role of a third element on stabilizing the structure and controlling the transformation of cubic NaZn{sub 13}-type structures to the tetragonal derivative, as well as the relationship between the structures and properties. (2) Synthesis of new ternary rare-earth iron silicides RE{sub 2-x}Fe{sub 4}Si{sub 14-y} and proposed superstructure: This compound offers complex structural challenges such as fractional occupancies and their ordering in superstructure. (3) Electronic structure calculation of FeSi{sub 2}: This shows that the metal-semiconductor phase transition depends on the structure. The mechanism of band gap opening is described in terms of bonding and structural distortion. This result shows that the electronic structure calculations are an essential tool for understanding the relationship between structure and chemical bonding in these compounds. (4) Synthesis of new ternary rare-earth Zinc aluminides Tb{sub 3}Zn{sub 3.6}Al{sub 7.4}: Partially ordered structure of Tb{sub 3}Zn{sub 3.6}Al{sub 7.4} compound provides new insights into the formation, composition and structure of rare-earth transition-metal intermetallics. Electronic structure calculations attribute the observed composition to optimizing metal-metal bonding in the electronegative (Zn, Al) framework, while the specific ordering is strongly influenced by specific orbital interactions. (5) Synthesis of new structure type of Zn{sub 39}(Cr{sub x}Al{sub 1-x}){sub 81}: These layered structures are similar to icosahedral Mn-Al quasicrystalline compounds. Therefore, this compound may provide new insights into the formation, composition and structure of quasicrystalline materials.

Mi-Kyung Han

2006-05-01T23:59:59.000Z

38

New Rare Earth Element Abundance Distributions for the Sun and Five r-Process-Rich Very Metal-Poor Stars  

E-Print Network [OSTI]

We have derived new abundances of the rare-earth elements Pr, Dy, Tm, Yb, and Lu for the solar photosphere and for five very metal-poor, neutron-capture r-process-rich giant stars. The photospheric values for all five elements are in good agreement with meteoritic abundances. For the low metallicity sample, these abundances have been combined with new Ce abundances from a companion paper, and reconsideration of a few other elements in individual stars, to produce internally-consistent Ba, rare-earth, and Hf (56element distributions. These have been used in a critical comparison between stellar and solar r-process abundance mixes.

Sneden, Christopher; Cowan, John J; Ivans, Inese I; Hartog, Elizabeth A Den

2009-01-01T23:59:59.000Z

39

Metal sulfide and rare-earth phosphate nanostructures and methods of making same  

DOE Patents [OSTI]

The present invention provides a method of producing a crystalline metal sulfide nanostructure. The metal is a transitional metal or a Group IV metal. In the method, a porous membrane is placed between a metal precursor solution and a sulfur precursor solution. The metal cations of the metal precursor solution and sulfur ions of the sulfur precursor solution react, thereby producing a crystalline metal sulfide nanostructure.

Wong, Stanislaus; Zhang, Fen

2014-05-13T23:59:59.000Z

40

Subcell Structure and Two Different Superstructures of the Rare Earth Metal Silicide Carbides Y  

SciTech Connect (OSTI)

The title compounds crystallize with a very pronounced subcell structure that has been determined from single-crystal X-ray diffractometer data of all four compounds. Only subcell (and no superstructure) reflections have been observed for Pr{sub 3}Si{sub 2}C{sub 2}: space group Cmmm, a=396.7(1) pm, b=1645.2(3) pm, c=439.9(1) pm, R=0.019 for 309 structure factors and 20 variable parameters. In this subcell structure there are C{sub 2} pairs with split atomic positions. This structure may be considered the thermodynamically stable forms of these compounds at high temperatures. Two different superstructures with doubled a or c axes, respectively, of the subcell have been observed, where the C{sub 2} pairs have different orientations. In the structure of Tb{sub 3}Si{sub 2}C{sub 2} the a axis of the subcell is doubled. The resulting superstructure in the standard setting has the space group Pbcm: a=423.6(1) pm, b=770.7(1) pm, c=1570.2(3) pm, R=0.031 f or 1437 structure factors and 22 variable parameters. Dy{sub 3}Si{sub 2}C{sub 2} has the same superstructure: a=420.3(1) pm, b=767.5(1) pm, c=1561.1(3) pm, R=0.045, 801 F values, 22 variables. In the structure of Y{sub 3}Si{sub 2}C{sub 2} the c axis of the subcell is doubled, resulting in a body-centered space group with the standard setting Imma: a=842.6(2) pm, b=1563.4(2) pm, c=384.6(1) pm, R=0.035, 681 F values, 15 variables. In all of these structures the rare earth atoms form two-dimensionally infinite sheets of edge-sharing octahedra that contain the C{sub 2} pairs. In between these sheets there are zig-zag chains of silicon atoms with Si-Si distances varying between 246.2(3) and 253.6(3) pm, somewhat longer than the two-electron bonds of 235 pm in elemental silicon, suggesting a bond order of 0.5 for the Si-Si bonds. The C-C distances in the C{sub 2} pairs vary between 127(1) and 131(1) pm, corresponding to a bond order of approximately 2. 5. Hence, using oxidation numbers, the compounds may to a first approximation be represented by the formula (R{sup +3}){sub 3}(Si{sup {minus}3}){sub 2}(C{sub 2}){sup {minus}3}. A more detailed analysis of the interatomic distances showed that the shortest R-R distances are comparable with the R-R distances in the structures of the rare earth elements, thus indicating some R-R bonding. Therefore, the oxidation numbers of the rare earth atoms are slightly lower than +3, in agreement with the metallic conductivity of these compounds. As a consequence, considering the relatively short Si-Si bonds, the absolute value of the oxidation number of the silicon atoms may be lower than 3, resulting in a Si-Si bond order somewhat higher than 0.5.

Jeitschko, Wolfgang; Gerdes, Martin H.; Witte, Anne M.; Rodewald, Ute Ch.

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Electron/phonon coupling in group-IV transition-metal and rare-earth nitrides  

SciTech Connect (OSTI)

Transport electron/phonon coupling parameters and Eliashberg spectral functions ?{sub tr}{sup 2}F(??) are determined for group-IV transition-metal (TM) nitrides TiN, ZrN, and HfN, and the rare-earth (RE) nitride CeN using an inversion procedure based upon temperature-dependent (4 < T < 300 K) resistivity measurements of high-crystalline-quality stoichiometric epitaxial films grown on MgO(001) by magnetically-unbalanced reactive magnetron sputtering. Transport electron/phonon coupling parameters ?{sub tr} vary from 1.11 for ZrN to 0.82 for HfN, 0.73 for TiN, and 0.44 for CeN. The small variation in ?{sub tr} among the TM nitrides and the weak coupling in CeN are consistent with measured superconducting transition temperatures 10.4 (ZrN), 9.18 (HfN), 5.35 (TiN), and <4 K for CeN. The Eliashberg spectral function describes the strength and energy spectrum of electron/phonon coupling in conventional superconductors. Spectral peaks in ?{sup 2}F(??), corresponding to regions in energy-space for which electrons couple to acoustic ??{sub ac} and optical ??{sub op} phonon modes, are centered at ??{sub ac} = 33 and ??{sub op} = 57 meV for TiN, 25 and 60 meV for ZrN, 18 and 64 meV for HfN, and 21 and 39 meV for CeN. The acoustic modes soften with increasing cation mass; optical mode energies remain approximately constant for the TM nitrides, but are significantly lower for the RE nitride due to a lower interatomic force constant. Optical/acoustic peak-intensity ratios are 1.15 ± 0.1 for all four nitrides, indicating similar electron/phonon coupling strengths ?{sub tr}(??) for both modes.

Mei, A. B.; Rockett, A. [Departments of Materials Science, Physics, and the Materials Research Laboratory, University of Illinois, 104 South Goodwin, Urbana, Illinois 61801 (United States)] [Departments of Materials Science, Physics, and the Materials Research Laboratory, University of Illinois, 104 South Goodwin, Urbana, Illinois 61801 (United States); Hultman, L. [Thin Film Physics Division, Department of Physics (IFM), Linköping University, SE-58183 Linköping (Sweden)] [Thin Film Physics Division, Department of Physics (IFM), Linköping University, SE-58183 Linköping (Sweden); Petrov, I.; Greene, J. E. [Departments of Materials Science, Physics, and the Materials Research Laboratory, University of Illinois, 104 South Goodwin, Urbana, Illinois 61801 (United States) [Departments of Materials Science, Physics, and the Materials Research Laboratory, University of Illinois, 104 South Goodwin, Urbana, Illinois 61801 (United States); Thin Film Physics Division, Department of Physics (IFM), Linköping University, SE-58183 Linköping (Sweden)

2013-11-21T23:59:59.000Z

42

EIS-0096: Remedial Actions at the Former Vitro Rare Metals Plant Site, Canonsburg, Washington County, Pennsylvania  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy prepared this statement to evaluate the environmental impacts associated with five potential sets of actions to address the potential public health hazards of residual radioactive materials remaining at the inactive uranium processing site in Canonsburg, Pennsylvania.

43

Magnetism of the rare earth, 3d --Theoretical review Abstract. --Compounds of rare earth and transition metals exhibit unusual and quite different behaviour. In  

E-Print Network [OSTI]

. Introduction. -- Intermetallic compounds bet- ween rare earth and 3d elements have received much attention similarities of rare earth elements allow to substitute themselves one another in a given material. The mainMagnetism of the rare earth, 3d -- Theoretical review Abstract. -- Compounds of rare earth

Paris-Sud XI, Université de

44

Rare-earth neutral metal injection into an electron beam ion trap plasma  

SciTech Connect (OSTI)

We have designed and implemented a neutral metal vapor injector on the SuperEBIT high-energy electron beam ion trap at the Lawrence Livermore National Laboratory. A horizontally directed vapor of a europium metal is created using a thermal evaporation technique. The metal vapor is then spatially collimated prior to injection into the trap. The source's form and quantity constraints are significantly reduced making plasmas out of metal with vapor pressures ?10{sup ?7} Torr at ?1000?°C more obtainable. A long pulsed or constant feed metal vapor injection method adds new flexibility by varying the timing of injection and rate of material being introduced into the trap.

Magee, E. W., E-mail: magee1@llnl.gov; Beiersdorfer, P.; Brown, G. V. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Hell, N. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Dr. Remeis-Sternwarte and ECAP, Universität Erlangen-Nürnberg, 96049 Bamberg (Germany)

2014-11-15T23:59:59.000Z

45

Synchrotron Diffraction Studies of Spontaneous Magnetostriction in Rare Earth Transition Metal Compounds  

SciTech Connect (OSTI)

Thermal expansion anomalies of R{sub 2}Fe{sub 14}B and R{sub 2}Fe{sub 17}C{sub x} (x = 0,2) (R = Y, Nd, Gd, Tb, Er) stoichiometric compounds are studied with high-energy synchrotron X-ray powder diffraction using Debye-Schemer geometry in temperature range 10K to 1000K. Large spontaneous magnetostriction up to their Curie temperatures (T{sub c}) is observed. The a-axes show relatively larger invar effects than c-axes in the R{sub 2}Fe{sub 14}B compounds whereas the R{sub 2}Fe{sub 17}C{sub x} show the contrary anisotropies. The iron sub-lattice is shown to dominate the spontaneous magnetostriction of the compounds. The contribution of the rare earth sublattice is roughly proportional to the spin magnetic moment of the rare earth in the R{sub 2}Fe{sub 14}B compounds but in R{sub 2}Fe{sub 17}C{sub x}, the rare earth sub-lattice contribution appears more likely to be dominated by the local bonding. The calculation of spontaneous magnetostrain of bonds shows that the bonds associated with Fe(j2) sites in R{sub 2}Fe{sub 14}B and the dumbbell sites in R{sub 2}Fe{sub 17}C{sub x} have larger values, which is strongly related to their largest magnetic moment and Wigner-Seitz atomic cell volume. The roles of the carbon atoms in increasing the Curie temperatures of the R{sub 2}Fe{sub 17} compounds are attributed to the increased separation of Fe hexagons. The R{sub 2}Fe{sub 17} and R{sub 2}Fe{sub 14}B phases with magnetic rare earth ions also show anisotropies of thermal expansion above T{sub c}. For R{sub 2}Fe{sub 17} and R{sub 2}Fe{sub 14}B the a{sub a}/a{sub c} > 1 whereas the anisotropy is reversed with the interstitial carbon in R{sub 2}Fe{sub 17}. The average bond magnetostrain is shown to be a possible predictor of the magnetic moment of Fe sites in the compounds. Both of the theoretical and phenomenological models on spontaneous magnetostriction are discussed and a Landau model on the spontaneous magnetostriction is proposed.

Ning Yang

2004-12-19T23:59:59.000Z

46

DOE Announces Second RFI on Rare Earth Metals | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power Systems EngineeringDepartmentSmart GridThirdPartnershipDrillingRFI on Rare Earth

47

Europium-activated phosphors containing oxides of rare-earth and group-IIIB metals and method of making the same  

DOE Patents [OSTI]

Europium-activated phosphors comprise oxides of at least a rare-earth metal selected from the group consisting of gadolinium, yttrium, lanthanum, and combinations thereof and at least a Group-IIIB metal selected from the group consisting of aluminum, gallium, indium, and combinations thereof. A method for making such phosphors comprises adding at least a halide of at least one of the selected Group-IIIB metals in a starting mixture. The method further comprises firing the starting mixture in an oxygen-containing atmosphere. The phosphors produced by such a method exhibit improved absorption in the UV wavelength range and improved quantum efficiency.

Comanzo, Holly Ann; Setlur, Anant Achyut; Srivastava, Alok Mani; Manivannan, Venkatesan

2004-07-13T23:59:59.000Z

48

Europium-activated phosphors containing oxides of rare-earth and group-IIIB metals and method of making the same  

DOE Patents [OSTI]

Europium-activated phosphors comprise oxides of at least a rare-earth metal selected from the group consisting of gadolinium, yttrium, lanthanum, and combinations thereof and at least a Group-IIIB metal selected from the group consisting of aluminum, gallium, indium, and combinations thereof. A method for making such phosphors comprises adding at least a halide of at least one of the selected Group-IIIB metals in a starting mixture. The method further comprises firing the starting mixture in an oxygen-containing atmosphere. The phosphors produced by such a method exhibit improved absorption in the UV wavelength range and improved quantum efficiency.

Comanzo, Holly Ann; Setlur, Anant Achyut; Srivastava, Alok Mani

2006-04-04T23:59:59.000Z

49

IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La)  

SciTech Connect (OSTI)

This work presents an assessment of solubility data for rare earth metal fluorides (generally of trivalent metals and of CeF{sub 4}) in water and in aqueous ternary systems. Compilations of all available experimental data are introduced for each rare earth metal fluoride with a corresponding critical evaluation. Every such evaluation contains a collection of all solubility results in water, a selection of suggested solubility data, and a brief discussion of the multicomponent systems. Because the ternary systems were seldom studied more than once, no critical evaluations of such data were possible. Only simple fluorides (no complexes or binary salts) are treated as the input substances in this report. The literature has been covered through the end of 2013.

Mioduski, Tomasz [Institute of Nuclear Chemistry and Technology, 03195 Warsaw (Poland); Gumi?ski, Cezary, E-mail: cegie@chem.uw.edu.pl [Department of Chemistry, University of Warsaw, 02093 Warsaw (Poland); Zeng, Dewen, E-mail: dewen-zeng@hotmail.com [College of Chemistry and Chemical Engineering, Central South University, 410083 Changsha (China)

2014-03-15T23:59:59.000Z

50

Soluble transition metals cause the pro-inflammatory effects of welding fumes in vitro   

E-Print Network [OSTI]

Epidemiological studies have consistently reported a higher incidence of respiratory illnesses such as bronchitis, metal fume fever (MFF), and chronic pneumonitis among welders exposed to high concentrations of metal-enriched ...

McNeilly, Jane D; Heal, Mathew R; Beverland, Iain J; Howe, Alan; Gibson, Mark D; Hibbs, Leon; MacNee, William; Donaldson, Ken

2004-01-01T23:59:59.000Z

51

Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen  

SciTech Connect (OSTI)

A series of organometallic compounds containing the tris(dimethylsilyl)methyl ligand are described. The potassium carbanions KC(SiHMe{sub 2}){sub 3} and KC(SiHMe{sub 2}){sub 3}TMEDA are synthesized by deprotonation of the hydrocarbon HC(SiHMe{sub 2}){sub 3} with potassium benzyl. KC(SiHMe{sub 2}){sub 3}TMEDA crystallizes as a dimer with two types of three-center-two-electron KH- Si interactions. Homoleptic Ln(III) tris(silylalkyl) complexes containing ?-SiH groups M{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) are synthesized from salt elimination of the corresponding lanthanide halide and 3 equiv. of KC(SiHMe{sub 2}){sub 3}. The related reactions with Sc yield bis(silylalkyl) ate-complexes containing either LiCl or KCl. The divalent calcium and ytterbium compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) are prepared from MI{sub 2} and 2 equiv of KC(SiHMe{sub 2}){sub 3}. The compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and La{C(SiHMe{sub 2}){sub 3}}{sub 3} react with 1 equiv of B(C{sub 6}F{sub 5}){sub 3} to give 1,3- disilacyclobutane {Me2Si-C(SiHMe2)2}2 and MC(SiHMe2)3HB(C6F5)3L, and La{C(SiHMe{sub 2}){sub 3}}{sub 2}HB(C{sub 6}F{sub 5}){sub 3}, respectively. The corresponding reactions of Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu) give the ?-SiH abstraction product [{(Me{sub 2}HSi){sub 3}C}{sub 2}LnC(SiHMe{sub 2}){sub 2}SiMe{sub 2}][HB(C{sub 6}F{sub 5}){sub 3}] (Ln = Y, Lu), but the silene remains associated with the Y or Lu center. The abstraction reactions of M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2 }or TMEDA) and Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) and 2 equiv of B(C{sub 6}F{sub 5}){sub 3} give the expected dicationic M{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and dicationic mono(silylalkyl) LnC(SiHMe{sub 2}){sub 3}{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2} (Ln = Y, Lu, La), respectively. Salt metathesis reactions of Cp{sub 2}(NR{sub 2})ZrX (X = Cl, I, OTf; R = t-Bu, SiHMe{sub 2}) and lithium hydrosilazide ultimately afford hydride products Cp{sub 2}(NR{sub 2})ZrH that suggest unusual ?-hydrogen elimination processes. A likely intermediate in one of these reactions, Cp{sub 2}Zr[N(SiHMe{sub 2})t-Bu][N(SiHMe{sub 2}){sub 2}], is isolated under controlled synthetic conditions. Addition of alkali metal salts to this zirconium hydrosilazide compound produces the corresponding zirconium hydride. However as conditions are varied, a number of other pathways are also accessible, including C-H/Si-H dehydrocoupling, ?-abstraction of a CH, and ?-abstraction of a SiH. Our observations suggest that the conversion of (hydrosilazido)zirconocene to zirconium hydride does not follow the classical four-center ?- elimination mechanism. Elimination and abstraction reactions dominate the chemistry of ligands containing ?- hydrogen. In contrast, Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}H and Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}Me undergo selective ?-CH bond activation to yield the azasilazirconacycle Cp{sub 2Zr}{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}}, even though there are reactive ?-hydrogen available for abstraction. The ?-SiH groups in metallacycle provide access to new pathways for sixteen-electron zirconium alkyl compounds, in which Cp{sub 2}Zr{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}} undergoes a rare ?-bond metathesis reaction with ethylene. The resulting vinyl intermediate undergoes ?-hydrogen abstraction to reform ethylene and a silanimine zirconium species that reacts with ethylene to give a metallacyclopentane as the isolated product. The pendent ?-SiH in metallocycle also reacts with paraformaldehyde through an uncatalyzed hydrosilylation to form an exocyclic methoxysilyl moiety, while the zirconium-carbon bond in metallocycle is surprisingly inert toward formaldehyde. Still, the Zr-C moiety in metallocycle is available for chemistry, and it interacts with the carbon monoxide and strong electrophile B(C{sub 6}F{sub 5}){sub 3} to provide Cp{sub 2}Zr[?{sup 2}- OC(=CH{sub 2})SiMeHN(SiHMe

Yan, Ka King [Ames Laboratory

2013-05-02T23:59:59.000Z

52

Magnesium substitutions in rare-earth metal germanides with the Gd5Si4 type. Synthesis, structure determination and magnetic properties of RE5-xMgxGe4 (RE=Gd-Tm, Lu and Y)  

SciTech Connect (OSTI)

A series of magnesium-substituted rare-earth metal germanides with a general formula RE{sub 5-x}Mg{sub x}Ge{sub 4} (x {approx} 1.0-2.3; RE =Gd-Tm, Lu, Y) have been synthesized by high-temperature reactions and structurally characterized by single-crystal X-ray diffraction. These compounds crystallize with the common Gd{sub 5}Si{sub 4} type in the orthorhombic space group Pnma (No. 62; Z =4; Pearson's code oP36) and do not appear to undergo temperature-induced crystallographic phase transitions down to 120 K. Replacing rare-earth metal atoms with Mg, up to nearly 45 % at., reduces the valence electron count and is clearly expressed in the subtle changes of the Ge-Ge and metal-metal bonding. Magnetization measurements as a function of the temperature and the applied field reveal complex magnetic structures at cryogenic temperatures, and Curie-Weiss paramagnetic behavior at higher temperatures. The observed local moment magnetism is consistent with RE+ ground states in all cases. In the magnetically ordered phases, the magnetization cannot reach saturation in fields up to 50 kOe. The structural trends across the series and the variations of hte magnetic properties as a function of the Mg content are also discussed. KEYWORDS: Rare-earth intermetallics, germanides, crystal structure,Gd{sub 5}Si{sub 4} type.

Sarrao, J L [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Tobash, P H [UNIV. OF DE; Bobev, S [UNIV. OF DE

2009-01-01T23:59:59.000Z

53

Production method for making rare earth compounds  

DOE Patents [OSTI]

A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.

McCallum, R. William (Ames, IA); Ellis, Timothy W. (Ames, IA); Dennis, Kevin W. (Ames, IA); Hofer, Robert J. (Ames, IA); Branagan, Daniel J. (Ames, IA)

1997-11-25T23:59:59.000Z

54

Production method for making rare earth compounds  

DOE Patents [OSTI]

A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g., a transition metal and optional boron), and a carbide-forming element (e.g., a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g., Nd{sub 2}Fe{sub 14}B or LaNi{sub 5}) and a carbide of the carbide-forming element are formed.

McCallum, R.W.; Ellis, T.W.; Dennis, K.W.; Hofer, R.J.; Branagan, D.J.

1997-11-25T23:59:59.000Z

55

Improved method for preparing rare earth sesquichalcogenides  

DOE Patents [OSTI]

An improved method for the preparation of high purity rare earth sesquichalcogenides is described. The rare earth, as one or more pieces of the metal, is sealed under a vacuum with a stoichiometric amount of sulfur or selenium and a small amount of iodine into a quartz reaction vessel. The sealed vessel is then heated to above the vaporization temperature of the chalcogen and below the melting temperature of the rare earth metal and maintained until the product has been formed. The iodine is then vaporized off leaving a pure product. The rare earth sulfides and selenides thus formed are useful as semiconductors and as thermoelectric generators. 3 tables.

Takeshita, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

1982-04-14T23:59:59.000Z

56

In vitro profiling of epigenetic modifications underlying heavy metal toxicity of tungsten-alloy and its components  

SciTech Connect (OSTI)

Tungsten-alloy has carcinogenic potential as demonstrated by cancer development in rats with intramuscular implanted tungsten-alloy pellets. This suggests a potential involvement of epigenetic events previously implicated as environmental triggers of cancer. Here, we tested metal induced cytotoxicity and epigenetic modifications including H3 acetylation, H3-Ser10 phosphorylation and H3-K4 trimethylation. We exposed human embryonic kidney (HEK293), human neuroepithelioma (SKNMC), and mouse myoblast (C2C12) cultures for 1-day and hippocampal primary neuronal cultures for 1-week to 50-200 {mu}g/ml of tungsten-alloy (91% tungsten/6% nickel/3% cobalt), tungsten, nickel, and cobalt. We also examined the potential role of intracellular calcium in metal mediated histone modifications by addition of calcium channel blockers/chelators to the metal solutions. Tungsten and its alloy showed cytotoxicity at concentrations > 50 {mu}g/ml, while we found significant toxicity with cobalt and nickel for most tested concentrations. Diverse cell-specific toxic effects were observed, with C2C12 being relatively resistant to tungsten-alloy mediated toxic impact. Tungsten-alloy, but not tungsten, caused almost complete dephosphorylation of H3-Ser10 in C2C12 and hippocampal primary neuronal cultures with H3-hypoacetylation in C2C12. Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures with a decrease in H3 pan-acetylation in C2C12, SKNMC and HEK293. Trimethylation of H3-K4 was not affected. Both tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation were reversed with BAPTA-AM, highlighting the role of intracellular calcium, confirmed with 2-photon calcium imaging. In summary, our results for the first time reveal epigenetic modifications triggered by tungsten-alloy exposure in C2C12 and hippocampal primary neuronal cultures suggesting the underlying synergistic effects of tungsten, nickel and cobalt mediated by changes in intracellular calcium homeostasis and buffering. - Highlights: > Tungsten-alloy caused H3-Ser10 dephosphorylation in C2C12 and hippocampal primary cultures. > Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures. > C2C12 cultures exposed to tungsten-alloy or cobalt exhibited decrease in H3 pan-acetylation. > Tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation was reversed with BAPTA-AM. > These epigenetic modifications were mediated by changes in calcium homeostasis and buffering.

Verma, Ranjana, E-mail: Ranjana.Verma.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Xu, Xiufen, E-mail: Xiufen.Xu.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Jaiswal, Manoj K., E-mail: Manoj.Jaiswal.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Olsen, Cara, E-mail: colsen@usuhs.mil [Department of Preventive Medicine and Biometrics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Mears, David, E-mail: dmears@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Caretti, Giuseppina, E-mail: giuseppina.caretti@unimi.it [Department of Biomolecular Sciences and Biotechnology, University of Milan (Italy); Galdzicki, Zygmunt, E-mail: zgaldzicki@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States)

2011-06-15T23:59:59.000Z

57

RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted  

E-Print Network [OSTI]

, was as follows: chemical catalysts, 22%; metallurgical applications and alloys, 21%; petroleum refining catalysts, and importer of rare-earth products in 2010. The estimated value of refined rare earths imported by the United) -- -- -- -- -- Rare-earth metals, alloy 867 784 564 188 250 Cerium compounds 2,590 2,680 2,080 1,500 1,400 Mixed REOs

58

RARE EARTHS1 [Data in metric tons of rare-earth oxide (REO) content unless otherwise noted  

E-Print Network [OSTI]

catalytic converters, 9%; glass polishing and ceramics, 6%; permanent magnets, 5%; petroleum refining, and importer of rare-earth products in 2009. The estimated value of refined rare earths imported by the United) -- -- -- -- 20 Rare-earth metals, alloy 880 867 784 679 210 Cerium compounds 2,170 2,590 2,680 2,080 1,190 Mixed

59

Au/MxOy/TiO2 catalysts for CO oxidation: promotional effect of main-group, transition, and rare-earth metal oxide additives.  

SciTech Connect (OSTI)

Au/TiO2 catalysts are active for CO oxidation, but they suffer from high-temperature sintering of the gold particles, and few attempts have been made to promote or stabilize Au/TiO2. Our recent communication addressed these issues by loading gold onto Al2O3/TiO2 prepared via surface-sol-gel processing of Al(sec-OC4H9)3 on TiO2. In our current full paper, Au/Al2O3/TiO2 catalysts were prepared alternatively by thermal decomposition of Al(NO3)3 on TiO2 followed by loading gold, and the influences of the decomposition temperature and Al2O3 content were systematically surveyed. This facile method was subsequently extended to the preparation of a battery of metal oxide-modified Au/TiO2 catalysts virtually not reported. It was found that Au/TiO2 modified by CaO, NiO, ZnO, Ga2O3, Y2O3, ZrO2, La2O3, Pr2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, Dy2O3, Ho2O3, Er2O3, or Yb2O3 could retain significant activity at ambient temperature even after aging in O2-He at 500 C, whereas unmodified Au/TiO2 lost its activity. Moreover, some 200 C-calcined promoted catalysts showed high activity even at about -100 C. The deactivation and regeneration of some of these new catalysts were studied. This work furnished novel catalysts for further fundamental and applied research.

Ma, Zhen [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2007-01-01T23:59:59.000Z

60

RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)  

E-Print Network [OSTI]

of rare earths by end use was as follows: automotive catalytic converters, 25%; petroleum refining, and consumer of rare-earth products in 2007. The estimated value of refined rare earths consumed in the United -- Rare-earth metals, alloy 1,130 804 880 867 831 Cerium compounds 2,630 1,880 2,170 2,590 3,090 Mixed

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Enhanced pinning in mixed rare earth-123 films  

DOE Patents [OSTI]

An superconductive article and method of forming such an article is disclosed, the article including a substrate and a layer of a rare earth barium cuprate film upon the substrate, the rare earth barium cuprate film including two or more rare earth metals capable of yielding a superconductive composition where ion size variance between the two or more rare earth metals is characterized as greater than zero and less than about 10.times.10.sup.-4, and the rare earth barium cuprate film including two or more rare earth metals is further characterized as having an enhanced critical current density in comparison to a standard YBa.sub.2Cu.sub.3O.sub.y composition under identical testing conditions.

Driscoll, Judith L. (Los Alamos, NM); Foltyn, Stephen R. (Los Alamos, NM)

2009-06-16T23:59:59.000Z

62

JOURNAL OF RARE EARTHS, Vol. 27, No. 2, Apr. 2009, p. 270 Foundation item  

E-Print Network [OSTI]

August 2008; revised 12 September 2008 Abstract: Rare earth elements have been used for 30 years; Juglans nigra; rare earths Rare earth elements (REEs) are metallic ions comprising elementsJOURNAL OF RARE EARTHS, Vol. 27, No. 2, Apr. 2009, p. 270 Foundation item: Corresponding author

63

New ternary rare-earth metal boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Y, Gd-Lu) containing BC{sub 2} units: Crystal and electronic structures, magnetic properties  

SciTech Connect (OSTI)

The ternary rare-earth boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Y, Gd-Lu) were prepared from the elements by arc-melting followed by annealing in silica tubes at 1270 K for 1 month. The crystal structures of Tb{sub 15}B{sub 4}C{sub 14} and Er{sub 15}B{sub 4}C{sub 14} were determined from single crystal X-ray diffraction data. They crystallize in a new structure type in space group P4/mnc (Tb{sub 15}B{sub 4}C{sub 14}: a=8.1251(5) A, c=15.861(1) A, Z=2, R{sub 1}=0.041 (wR{sub 2}=0.088) for 1023 reflections with I{sub o}>2{sigma}(I{sub o}); Er{sub 15}B{sub 4}C{sub 14}: a=7.932(1) A, c=15.685(2) A, Z=2, R{sub 1}=0.037 (wR{sub 2}=0.094) for 1022 reflections with I{sub o}>2{sigma}(I{sub o})). The crystal structure contains discrete carbon atoms and bent CBC units in octahedra and distorted bicapped square antiprisms, respectively. In both structures the same type of disorder exists. One R atom position needs to be refined as split atom position with a ratio 9:1 indicative of a 10% substitution of the neighboring C{sup 4-} by C{sub 2}{sup 4-}. The actual composition has then to be described as R{sub 15}B{sub 4}C{sub 14.2}. The isoelectronic substitution does not change the electron partition of R{sub 15}B{sub 4}C{sub 14} which can be written as (R{sup 3+}){sub 15}(C{sup 4-}){sub 6}(CBC{sup 5-}){sub 4{center_dot}}e{sup -}. The electronic structure was studied with the extended Hueckel method. The investigated compounds Tb{sub 15}B{sub 4}C{sub 14}, Dy{sub 15}B{sub 4}C{sub 14} and Er{sub 15}B{sub 4}C{sub 14} are hard ferromagnets with Curie temperatures T{sub C}=145, 120 and 50 K, respectively. The coercive field B{sub C}=3.15 T for Dy{sub 15}B{sub 4}C{sub 14} is quite remarkable. - Graphical abstract: The ternary rare earth boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Y, Gd-Lu) were prepared from the elements by arc-melting followed by annealing in silica tubes at 1270 K for 1 month. Tb{sub 15}B{sub 4}C{sub 14} is a new member of the rare-earth metal boride carbide series in which the finite quasi-molecular CBC entities as well as isolated C atoms are embedded in the voids of the metal atom matrix. The structure of Tb{sub 15}B{sub 4}C{sub 14} contains two types of slabs: one slab contains finite bent CBC units and isolated carbon atoms whereas another is formed only from octahedral coordinated single carbon atoms. The electronic structure for the idealized composition corresponds to an electron partitioning according to (Tb{sup 3+}){sub 15}(C{sup 4-}){sub 6}(CBC{sup 5-}){sub 4{center_dot}}e{sup -} giving rise to a single electron per formula for Tb-Tb framework bonding. The magnetism of the ternary rare earth boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Tb, Dy, Er) is characterized by the onset of ferromagnetic order below T<150 K.

Babizhetskyy, Volodymyr, E-mail: v.babizhetskyy@fkf.mpg.d [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, Postfach 800665, D-70569 Stuttgart (Germany); Simon, Arndt; Mattausch, Hansjuergen [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, Postfach 800665, D-70569 Stuttgart (Germany); Hiebl, Kurt [Arbeitsgruppe Neue Materialien, Universitaet Wien, Waehringerstrasse 42, A-1090 Wien (Austria); Zheng Chong [Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL 60115 (United States)

2010-10-15T23:59:59.000Z

64

Laminated rare earth structure and method of making  

DOE Patents [OSTI]

A laminated structure having two or more layers, wherein at least one layer is a metal substrate and at least one other layer is a coating comprising at least one rare earth element. For structures having more than two layers, the coating and metal substrate layers alternate. In one embodiment of the invention, the structure is a two-layer laminate having a rare earth coating electrospark deposited onto a metal substrate. In another embodiment of the invention, the structure is a three-layer laminate having the rare earth coating electrospark deposited onto a first metal substrate and the coating subsequently abonded to a second metal substrate. The bonding of the coating to the second metal substrate may be accomplished by hot pressing, hot rolling, high deformation rate processing, or combinations thereof. The laminated structure may be used in nuclear components where reactivity control or neutron absorption is desired and in non-nuclear applications such as magnetic and superconducting films.

Senor, David J [West Richland, WA; Johnson, Roger N [Richland, WA; Reid, Bruce D [Pasco, WA; Larson, Sandra [Richland, WA

2002-07-30T23:59:59.000Z

65

AnnaFrebel! metal-poorstars!  

E-Print Network [OSTI]

-process element pattern!! #12;AnnaFrebel! metal-poorstars! New oscillator strengths of rare earth elements!! · Sneden, Lawler et al. 2009: New Rare Earth Element Abundance Distributions for the Sun and Five r-Process-Rich, Metal-Poor Stars, and Rare Earth Lab Data Summary · Lawler, Sneden et al. 2008: Improved Laboratory

66

Rare earth thermoelectrics  

SciTech Connect (OSTI)

A review is presented of the thermoelectric properties of rare earth compounds: A discussion is presented of the prospects for future improvements in the figure of merit.

Mahan, G.D.

1997-07-01T23:59:59.000Z

67

Rare muon processes  

SciTech Connect (OSTI)

The status of rare muon processes as tests of the standard model is reviewed with the emphasis on results that are expected from experiments in the near future.

Cooper, M.D.

1993-01-01T23:59:59.000Z

68

Rare muon processes  

SciTech Connect (OSTI)

The status of rare muon processes as tests of the standard model is reviewed with the emphasis on results that are expected from experiments in the near future.

Cooper, M.D.; The MEGA Collaboration

1993-05-01T23:59:59.000Z

69

Synthesis and luminescence properties of rare earth activated phosphors for near UV-emitting LEDs for efficacious generation of white light  

E-Print Network [OSTI]

of R 2 SiO 5 (R = rare earth elements)?, Mater. Res. Bull.QE Quantum Efficiency RE Rare Earth Elements RGB Red, green,transition metal or rare earth elements. The standard

Han, Jinkyu

2013-01-01T23:59:59.000Z

70

Crystalline rare-earth activated oxyorthosilicate phosphor  

DOE Patents [OSTI]

Crystalline, transparent, rare-earth activated lutetium oxyorthosilicate phosphor. The phosphor consists essentially of lutetium yttrium oxyorthosilicate activated with a rare-earth metal dopant M and having the general formula Lu(.sub.2-x-z)Y.sub.x M.sub.z SiO.sub.5, wherein 0.00.ltoreq.x.ltoreq.1.95, wherein 0.001.ltoreq.z.ltoreq.0.02, and wherein M is selected from Sm, Tb, Tm, Eu, Yb, and Pr. The phosphor also consists essentially of lutetium gadolinium oxyorthosilicate activated with a rare-earth metal dopant M and having the general formula Lu(.sub.2-x-z)Gd.sub.x M.sub.z SiO.sub.5, wherein 0.00.ltoreq.x.ltoreq.1.95, wherein 0.001.ltoreq.z.ltoreq.0.02, and wherein M is selected from Sm, Tb, Tm, Eu, Yb, and Pr. The phosphor also consists essentially of gadolinium yttrium oxyorthosilicate activated with a rare-earth metal dopant M and having the general formula Gd(.sub.2-x-z)Y.sub.x M.sub.z SiO.sub.5, wherein 0.00.ltoreq.x.ltoreq.1.95, wherein 0.001.ltoreq.z.ltoreq.0.02, and wherein M is selected from Sm, Tb, Tm, Eu, Yb, and Pr. The phosphor may be optically coupled to a photodetector to provide a radiation detector.

McClellan, Kenneth J.; Cooke, D. Wayne

2004-02-10T23:59:59.000Z

71

JOURNAL DE PHYSIQUE Colloque C5, supplkment au no 5, Tome 40, Mai 1979, page C5-63 Heat capacity of rare earth metals near the melting point and the vacancy  

E-Print Network [OSTI]

for the difference of the heat capacity of the liquid and solid metal in the neighbourhood of the melting point. From of the atomic heat capacity of solid and liquid metals at the melting point. The basis for this calculationJOURNAL DE PHYSIQUE Colloque C5, supplkment au no 5, Tome 40, Mai 1979, page C5-63 Heat capacity

Paris-Sud XI, Université de

72

Hydrogeochemistry and rare earth element behavior in a volcanically acidified watershed in Patagonia, Argentina  

E-Print Network [OSTI]

Hydrogeochemistry and rare earth element behavior in a volcanically acidified watershed and analyzed for major ions, trace metals, and rare earth elements (REE). The concentrations of REE in the Rio to oxidation of sulfide minerals. D 2005 Elsevier B.V. All rights reserved. Keywords: Rare earth elements

Royer, Dana

73

RARE EARTHS--2000 62.1 RARE EARTHS  

E-Print Network [OSTI]

, and monazite (table 2). The rare earths are a moderately abundant group of 17 elements composed of scandium and lutetium, the least abundant rare-earth elements at about 0.5 ppm. In rock-forming minerals, rare earths, whose atomic number is 21, is the lightest rare- earth element. It is the 31st most abundant element

74

RARE EARTHS--2001 61.1 RARE EARTHS  

E-Print Network [OSTI]

's crust at 60 parts per million (ppm), to thulium and lutetium, the least abundant rare-earth elements number is 21, is the lightest rare- earth element. It is the 31st most abundant element in the EarthRARE EARTHS--2001 61.1 RARE EARTHS By James B. Hedrick Domestic survey data and tables were

75

RARE EARTHS--2002 61.1 RARE EARTHS  

E-Print Network [OSTI]

. 667). Because they have similar chemical structures, the rare-earth elements proved difficultRARE EARTHS--2002 61.1 RARE EARTHS By James B. Hedrick Domestic survey data and tables were in the Earth's crust is 33 ppm and is the second most abundant rare earth in the Earth's crust. Yttrium

76

Rare hadronic B decays  

E-Print Network [OSTI]

Rare hadronic B-meson decays allow us to study CP violation. The class of B decays final states containing two vector mesons provides a rich set of angular correlation observables to study. This article reviews some of the recent experimental results from the BaBar and Belle collaborations.

A. J. Bevan

2006-06-02T23:59:59.000Z

77

Suppression of the phagocytic capabilities of coelomocytes from Lumbricus terrestris following an in-vitro exposure to heavy metals and evaluation of their metabolic activities by flow cytometry  

SciTech Connect (OSTI)

Immunotoxic effects of environmental exposure to chemical contaminants can be evaluated by monitoring cellular and functional parameters of the immune system of sentinel species. In this scope, the earthworm may represent a relevant sentinel species to determine the level of toxicity linked to soil contaminants or to test the efficacy of remediation protocols. In this work, coelomocytes were incubated in vitro for 18 hours with mercury, cadmium, zinc or lead at concentrations ranging from 10{sup {minus}9} to 10{sup {minus}4}M. The analysis of phagocytosis by flow cytometry revealed that this natural response was impaired at non cytotoxic concentrations of mercury, cadmium and zinc. Moreover, the analysis of cells obtained from coelomic fluid, based on the combination of low angle forward scatter (FSC) and side scatter (SSC) allowed to discriminate between two distinct populations of coelomocytes. With the use of fluorescent probes, such as carboxyfluorescin diacetate (CFDA), dichlorofluorescin diacetate (DCFDA) and chloromethyl fluorescin diacetate (CFDA), to study the esterase activity and Fluo-3 to measure free cytoplasmic calcium, the results showed that the first discrimination between the two populations of cells based on size and complexity could be further accentuated on the basis of their metabolic activities. In summary, the data make very attractive the use of flow cytometry to study cellular and functional parameters of the earthworm.

Brousseau, P.; Fugere, N.; Coderre, D.; Flipo, D.; Foumier, M. [Univ. du Quebec a Montreal, Montreal, Quebec (Canada)

1995-12-31T23:59:59.000Z

78

RARE EARTHS--1999 61.1 RARE EARTHS  

E-Print Network [OSTI]

in the Earth's crust at 60 parts per million, to thulium and lutetium, the least abundant rare-earth elements, is the lightest rare-earth element. It is the 31st most abundant element in the Earth's crust with an average. 667). Because they have similar chemical structures, the rare-earth elements proved difficult

79

RARE EARTHS--1998 61.1 RARE EARTHS  

E-Print Network [OSTI]

in the Earth's crust at 60 parts per million, to thulium and lutetium, the least abundant rare-earth elements, is the lightest rare-earth element. It is the 31st most abundant element in the Earth's crust with an average. 667). Because they have similar chemical structures, the rare-earth elements proved difficult

80

RARE EARTHS--2003 60.1 RARE EARTHS  

E-Print Network [OSTI]

, geographic information specialist. The rare earths are a moderately abundant group of 17 elements comprising), to thulium and lutetium, the least abundant rare-earth elements at about 0.5 ppm (Mason and Moore, 1982, p atomic number is 21, is the lightest rare-earth element. It is the 31st most abundant element

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Ames Lab 101: Rare Earths  

ScienceCinema (OSTI)

"Mr. Rare Earth," Ames Laboratory scientist Karl Gschneidner Jr., explains the importance of rare-earth materials in many of the technologies we use today -- ranging from computers to hybrid cars to wind turbines. Gschneidner is a world renowned rare-earths expert at the U.S. Department of Energy's Ames Laboratory.

Gschneidner, Karl

2012-08-29T23:59:59.000Z

82

2006 Minerals Yearbook RARE EARTHS  

E-Print Network [OSTI]

parts per million (ppm), to thulium and lutetium, the least abundant rare-earth elements at about 0 and malleable, similar in density to titanium. The elemental forms of rare earths are iron gray to silvery2006 Minerals Yearbook RARE EARTHS U.S. Department of the Interior U.S. Geological Survey May 2008

83

Rare B Decays  

SciTech Connect (OSTI)

Recent results from Belle and BaBar on rare B decays involving flavor-changing neutral currents or purely leptonic final states are presented. Measurements of the CP asymmetries in B {yields} K*{gamma} and b {yields} s{gamma} are reported. Also reported are updated limits on B{sup +} {yields} K{sup +}{nu}{bar {nu}}, B{sup +} {yields} {tau}{sup +}{nu}, B{sup +} {yields} {mu}{sup +}{nu} and the recent measurement of B {yields} X{sub s}{ell}{sup +}{ell}{sup -}.

Jackson, P.D.; /Victoria U.

2006-02-24T23:59:59.000Z

84

Transition Metal Switchable Mirror  

ScienceCinema (OSTI)

The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

None

2013-05-29T23:59:59.000Z

85

Transition Metal Switchable Mirror  

ScienceCinema (OSTI)

The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

None

2010-01-08T23:59:59.000Z

86

U.S. Rare Earth Magnet Patents Table © 2-4-2015 page 1  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to a temperature equal to or lower than a sintering temperature of the magnet base material, wherein: a) a content of a rare earth in a metallic state in the magnet base...

87

Corrosion-resistant metal surfaces  

DOE Patents [OSTI]

The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.

Sugama, Toshifumi (Wading River, NY)

2009-03-24T23:59:59.000Z

88

EIS-0096: Final Environmental Impact Statement  

Broader source: Energy.gov [DOE]

Remedial Actions at the Former Vitro Rare Metals Plant Site, Canonsburg, Washington County, Pennsylvania

89

The Colorado Rare Plant Technical Committee Rare Plant Symposium  

E-Print Network [OSTI]

The Colorado Rare Plant Technical Committee presents: 4th Annual Rare Plant Symposium Sponsored by: Colorado Native Plant Society University of Colorado Herbarium US Fish and Wildlife Service Colorado: G2G3/S2S3 Global distribution: Colorado (Larimer and Boulder counties). Possibly extending

90

E-Print Network 3.0 - alkali metal alkaline Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with alkali-metals 9, loi, alkaline earth metals l,18 and some of other rare-earth elements 19, 20 have... alkali metals were doped into C60 solids 9 and...

91

Replacing the Rare Earth Intellectual Capital  

SciTech Connect (OSTI)

The rare earth crisis slowly evolved during a 10 to 15 year period beginning in the mid-1980s, when the Chinese began to export mixed rare earth concentrates. In the early 1990s, they started to move up the supply chain and began to export the individual rare earth oxides and metals. By the late 1990s the Chinese exported higher value products, such as magnets, phosphors, polishing compounds, catalysts; and in the 21st century they supplied finished products including electric motors, computers, batteries, liquid-crystal displays (LCDs), TVs and monitors, mobile phones, iPods and compact fluorescent lamp (CFL) light bulbs. As they moved to higher value products, the Chinese slowly drove the various industrial producers and commercial enterprises in the US, Europe and Japan out of business by manipulating the rare earth commodity prices. Because of this, the technically trained rare earth engineers and scientists who worked in areas from mining to separations, to processing to production, to manufacturing of semifinished and final products, were laid-off and moved to other fields or they retired. However, in the past year the Chinese have changed their philosophy of the 1970s and 1980s of forming a rare earth cartel to control the rare earth markets to one in which they will no longer supply the rest of the world (ROW) with their precious rare earths, but instead will use them internally to meet the growing demand as the Chinese standard of living increases. To this end, they have implemented and occasionally increased export restrictions and added an export tariff on many of the high demand rare earth elements. Now the ROW is quickly trying to start up rare earth mines, e.g. Molycorp Minerals in the US and Lynas Corp. in Australia, to cover this shortfall in the worldwide market, but it will take about five years for the supply to meet the demand, even as other mines in the ROW become productive. Unfortunately, today there is a serious lack of technically trained personnel to bring the entire rare earth industry, from mining to original equipment manufacturers (OEM), up to full speed in the next few years. Accompanying this decline in technical expertise, innovation and new products utilizing rare earth elements has slowed dramatically, and it may take a decade or more to recapture America's leading role in technological advancements of rare earth containing products. Before the disruption of the US rare earth industry, about 25,000 people were employed in all aspects of the industry from mining to OEM. Today, only about 1,500 people are employed in these fields. The ratio of non-technically trained persons to those with college degrees in the sciences or engineering varies from about 8 to 1 to about 4 to 1, depending on the particular area of the industry. Assuming an average of 6 to 1, the number of college degree scientists and engineers has decreased from about 4,000 to 250 employed today. In the magnetic industry the approximate numbers are: 6,000 total with 750 technically trained people in the 1980s to 500 totally employed today of which 75 have degrees. The paucity of scientists and engineers with experience and/or training in the various aspects of production and commercialization of the rare earths is a serious limitation to the ability of the US to satisfy its own needs for materials and technologies (1) to maintain our military strength and posture, (2) to assume leadership in critical energy technologies, and (3) to bring new consumer products to the marketplace. The lack of experts is of even greater national importance than the halting in the 1990s and the recent restart of the mining/benification/separation effort in the US; and thus governmental intervention and support for at least five to 10 years will be required to ameliorate this situation. To respond quickly, training programs should be established in conjunction with a national research center at an educational institution with a long tradition in multiple areas of rare earth and other critical elements research and technology. This center should

Gschneidner, Jr., Karl

2011-04-01T23:59:59.000Z

92

Phase stable rare earth garnets  

DOE Patents [OSTI]

A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.

Kuntz, Joshua D.; Cherepy, Nerine J.; Roberts, Jeffery J.; Payne, Stephen A.

2013-06-11T23:59:59.000Z

93

Rare Earth ? See Rare Earth, by Ward and Brownlee  

E-Print Network [OSTI]

Rare Earth ? See Rare Earth, by Ward and Brownlee #12;N to date N = N* fs fGHZfp nH fl fi fc L/T ·N Earth is "Just Right" Yes, life on Earth has adapted to Earth, but ... Earth has just the right mass to be ·Tectonically-active ·Retain an atmosphere Earth has had a stable climate The Sun is particularly inactive

Walter, Frederick M.

94

Research on feline in vitro maturation and the cell cycle  

E-Print Network [OSTI]

species. Very little is known about these species; and if they become extinct, we may not have the chance to leam more about them. Tissues from nondomestic cats are not readily available. 'I'herefore, studies are performed on tissues from domestic cats... in the hope that the infomiation gained can be transferred on to the rare species. Reproductive techniques developed for the domestic cat, such as in vitro maturation, in vitro fertilization, and embryo transfer, can potentially be applied to endangered...

Cox, Ashley Michelle

2013-02-22T23:59:59.000Z

95

PRESS RELEASE RARE FRUIT CONFERENCE  

E-Print Network [OSTI]

RELEASE RARE FRUIT CONFERENCE July 9 - 13, 2014 Sponsored by the Tropical Fruit & Vegetable Society of the Redland & the Fruit & Spice Park 24801 SW 187th Avenue, Homestead, Florida

Jawitz, James W.

96

A Rare Isolated Trapezoid Fracture  

E-Print Network [OSTI]

wrist in suggested scaphoid fracture. Acta Radiol. 1988;29:Rare isolated trapezoid fracture: a case report. Hand. 2008;suspect and diagnose this fracture. 2,8 REFERENCES 1. Papp

Afifi, Negean; Lu, Jenny J

2011-01-01T23:59:59.000Z

97

Self-assembled rare-earth silicide nanowires on Si(001)  

SciTech Connect (OSTI)

This paper presents scanning tunneling microscope images of several rare-earth metal silicides grown on silicon (001). For certain of the metals studied (Dy, Ho), an anisotropy in lattice match with the substrate results in the formation of nanowires. These nanowires have desirable properties such as nanometer lateral dimension, crystalline structure with a low density of defects, and micrometer scale length. Tunneling spectroscopy on the nanowires indicates that they are metallic.

Nogami, J.; Liu, B. Z.; Katkov, M. V.; Ohbuchi, C.; Birge, Norman O.

2001-06-15T23:59:59.000Z

98

Stabilization of Electrocatalytic Metal Nanoparticles at Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

99

RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)  

E-Print Network [OSTI]

. The approximate distribution in 2002 by end use was as follows: petroleum refining catalysts, 27%; glass polishing. The estimated value of refined rare earths consumed in the United States was more than $1 billion-earth metals, alloy 1,780 2,470 1,420 1,450 1,130 Cerium compounds 3,990 4,310 3,850 2,540 2,630 Mixed REOs 5

100

RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)  

E-Print Network [OSTI]

, televisions, computer monitors, radar, and X-ray intensifying film, 10%; petroleum refining catalysts, 8 continued to be a major exporter and consumer of rare-earth products in 2006. The estimated value of refined-earth metals, alloy 1,450 1,130 804 880 947 Cerium compounds 2,540 2,630 1,880 2,170 2,530 Mixed REOs 1,040 2

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Ultracold chemistry with alkali-metal-rare-earth molecules  

E-Print Network [OSTI]

A first principles study of the dynamics of $^6$Li($^{2}$S) + $^6$Li$^{174}$Yb($^2\\Sigma^+$)$ \\to ^6$Li$_2(^1\\Sigma^+$) + $^{174}$Yb($^1$S) reaction is presented at cold and ultracold temperatures. The computations involve determination and analytic fitting of a three-dimensional potential energy surface for the Li$_2$Yb system and quantum dynamics calculations of varying complexities, ranging from exact quantum dynamics within the close-coupling scheme, to statistical quantum treatment, and universal models. It is demonstrated that the two simplified methods yield zero-temperature limiting reaction rate coefficients in reasonable agreement with the full close-coupling calculations. The effect of the three-body term in the interaction potential is explored by comparing quantum dynamics results from a pairwise potential that neglects the three-body term to that derived from the full interaction potential. Inclusion of the three-body term in the close-coupling calculations was found to reduce the limiting rate coefficients by a factor of two. The reaction exoergicity populates vibrational levels as high as $v=19$ of the $^6$Li$_2$ molecule in the limit of zero collision energy. Product vibrational distributions from the close-coupling calculations reveal sensitivity to inclusion of three-body forces in the interaction potential. Overall, the results indicate that a simplified model based on the long-range potential is able to yield reliable values of the total reaction rate coefficient in the ultracold limit but a more rigorous approach based on statistical quantum or quantum close-coupling methods is desirable when product rovibrational distribution is required.

C. Makrides; J. Hazra; G. B. Pradhan; A. Petrov; B. K. Kendrick; T. González-Lezana; N. Balakrishnan; S. Kotochigova

2014-10-28T23:59:59.000Z

102

Rare Earth Metals & Alloys | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromising Science for1Principal InvestigatorsLivingstonNNSARare

103

DOE Science Showcase - Rare Earth Metal Research from DOE Databases |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct: CrudeOffice of Scientific andEnergy, OfficeOffice ofOSTI,

104

The Ames Process for Rare Earth Metals | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 and NbSe2 .2004 NorthWeek(activeDirectory: Office

105

Electronic structure of rare-earth metals | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles as SelectiveElectronic Structurefunctional theory

106

Metal aminoboranes  

DOE Patents [OSTI]

Metal aminoboranes of the formula M(NH2BH3)n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya; Shrestha, Roshan P.

2010-05-11T23:59:59.000Z

107

Monolithic integration of rare-earth oxides and semiconductors for on-silicon technology  

SciTech Connect (OSTI)

Several concepts of integration of the epitaxial rare-earth oxides into the emerging advanced semiconductor on silicon technology are presented. Germanium grows epitaxially on gadolinium oxide despite lattice mismatch of more than 4%. Additionally, polymorphism of some of the rare-earth oxides allows engineering of their crystal structure from hexagonal to cubic and formation of buffer layers that can be used for growth of germanium on a lattice matched oxide layer. Molecular beam epitaxy and metal organic chemical vapor deposition of gallium nitride on the rare-earth oxide buffer layers on silicon is discussed.

Dargis, Rytis, E-mail: dargis@translucentinc.com; Clark, Andrew; Erdem Arkun, Fevzi [Translucent, Inc., 952 Commercial St., Palo Alto, California 94303 (United States); Grinys, Tomas; Tomasiunas, Rolandas [Institute of Applied Research, Vilnius University, Sauletekio al. 10, LT-10223 Vilnius (Lithuania); O'Hara, Andy; Demkov, Alexander A. [Department of Physics, The University of Texas at Austin, 2515 Speedway, C1600, Austin, Texas 78712 (United States)

2014-07-01T23:59:59.000Z

108

An Equilibrium Model of Rare Event Premia  

E-Print Network [OSTI]

In this paper, we study the asset pricing implication of imprecise knowledge about rare events. Modeling rare events as jumps in the aggregate endowment, we explicitly solve the equilibrium asset prices in a pure-exchange ...

Liu, Jun

2002-08-12T23:59:59.000Z

109

Novel rare earth boron-rich solids  

SciTech Connect (OSTI)

A new series of boron-rich solids ReB{sub 22}C{sub 2}N (Re: Y, Ho, Er, Tm, Lu) was synthesized by traditional solid-state reaction. The crystal structure of the representative compound YB{sub 22}C{sub 2}N was solved by direct method from powder X-ray diffraction (XRD) data and transmission electron microscope (TEM) analysis. The unit cell of the new structure is rhombohedral with space group R-3m (No. 166), lattice constant a = b = 5.623(0) {angstrom} and c = 44.785(3) {angstrom} with six formula units in one unit cell. The atoms of boron in the solids, like most of the boron-rich solids, exist with icosahedral and octahedral clusters, and the whole crystal shows a layered structure. The interconnected nine layers of icosahedron and three layers of octahedron in a unit cell build the whole framework of the new phase and rare earth metal atoms reside in voids of the octahedron layers. The neighboring icosahedral layers link through C-B-C chains besides the direct bonding of B-B. Both experimental and structural analysis indicated that the nitrogen atoms in the new phase can be replaced with carbon.

Zhang, Fuxiang; Leithe-Jasper, Andreas; Xu, Jun; Mori, Takao; Matsui, Yoshio, Tanaka, Takaho; Okada, Shigeru

2001-06-01T23:59:59.000Z

110

Rare Earth Element Mines, Deposits, and Occurrences  

E-Print Network [OSTI]

Rare Earth Element Mines, Deposits, and Occurrences by Greta J. Orris1 and Richard I. Grauch2 Open. For many years, the deposit at Mountain Pass was the world's dominant source of rare earth elements of rare earth element concentration. Many of the occurrences have not been well studied and the economic

Torgersen, Christian

111

Are Earths Rare? Perhaps Not  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone by E-mailRadioimmunotherapyArchiveAre Earths Rare? Perhaps Not

112

The Colorado Rare Plant Technical Committee presents: Colorado Rare Plant Symposium  

E-Print Network [OSTI]

The Colorado Rare Plant Technical Committee presents: 5th Annual Colorado Rare Plant Symposium September 5, 2008 Montrose, Colorado Sponsored by: Colorado Rare Plant Technical CommitteeColorado Rare Plant Technical Committee Colorado Native Plant Society University of Colorado Herbarium US Fish

113

The Colorado Rare Plant Technical Committee presents: 2nd Annual Rare Plant  

E-Print Network [OSTI]

The Colorado Rare Plant Technical Committee presents: 2nd Annual Rare Plant Symposium Friday, September 16th, 2005 8am-noon: 2nd Annual Colorado Rare Plant Symposium (Discuss G1 species) 6:30-7:30pm with the Colorado Native Plant Society's Annual Meeting Sponsored by: #12;The Second Annual Colorado Rare Plant

114

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2009. All  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was not mined in the United States in 2009. All yttrium. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad. Other rare-earth compounds, including yttrium oxide >85% Y2O3, yttrium nitrate, and other individual

115

[Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted] Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2010. All  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was not mined in the United States in 2010. All yttrium. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad. Other rare-earth compounds, including yttrium oxide >85% Y2O3, yttrium nitrate, and other individual

116

(Data in metric tons of yttrium oxide (Y2O3) content, unless noted) Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network [OSTI]

Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

117

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2008. All  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was not mined in the United States in 2008. All yttrium 12-31-08 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and compounds containing by weight >19% to rare-earth compounds, including

118

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2006. All  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was not mined in the United States in 2006. All yttrium-31-06 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium and compounds containing by weight >19% to rare-earth compounds, including

119

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2003.  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was not mined in the United States in 2003. Yttrium Relations 12/31/03 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and compounds containing by weight >19% to rare-earth compounds, including

120

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network [OSTI]

Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth.20.0000 Free Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2004. Yttrium  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was not mined in the United States in 2004. Yttrium Relations 12-31-04 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and compounds containing by weight >19% to rare-earth compounds, including

122

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite,  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed

123

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral  

E-Print Network [OSTI]

Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5

124

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network [OSTI]

Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth/31/96 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

125

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2005. All  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was not mined in the United States in 2005. All yttrium-31-05 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium and compounds containing by weight >19% to rare-earth compounds, including

126

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite,  

E-Print Network [OSTI]

Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth/31/98 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

127

Development of a metal hydride electrode waste treatment process  

SciTech Connect (OSTI)

Manufacturing residues of metal hydride electrodes for nickel - metal hydride batteries were chemically processed to recover the metal part and heat treated for the organic part. Chemical recovery yielded Ni-Co alloy after electrolysis of the solution and hydroxides of other metal, mainly rare earths. The organic part, pyrolyzed at 700 C, led to separation between carbon and fluorinated matter. Infrared coupling at the output of the pyrolysis furnace was used to identify the pyrolysis gases.

Bianco, J.C.; Martin, D.; Ansart, F.; Castillo, S.

1999-12-01T23:59:59.000Z

128

Metal inks  

DOE Patents [OSTI]

Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

2014-02-04T23:59:59.000Z

129

Mixed Conduction in Rare-Earth Phosphates  

E-Print Network [OSTI]

their  metal  to  phosphorous  ratio  can  be  varied;  materials,   as   the   phosphorous   to   metal   ratio  tetrahedron.    As   the  phosphorous  content  of  the  

Ray, Hannah Leung

2012-01-01T23:59:59.000Z

130

Method for preparing high cure temperature rare earth iron compound magnetic material  

DOE Patents [OSTI]

Insertion of light elements such as H,C, or N in the R.sub.2 Fe.sub.17 (R=rare earth metal) series has been found to modify the magnetic properties of these compounds, which thus become prospective candidates for high performance permanent magnets. The most spectacular changes are increases of the Curie temperature, T.sub.c, of the magnetization, M.sub.s, and of coercivity, H.sub.c, upon interstitial insertion. A preliminary product having a component R--Fe--C,N phase is produced by a chemical route. Rare earth metal and iron amides are synthesized followed by pyrolysis and sintering in an inert or reduced atmosphere, as a result of which, the R--Fe--C,N phases are formed. Fabrication of sintered rare earth iron nitride and carbonitride bulk magnet is impossible via conventional process due to the limitation of nitridation method.

Huang, Yuhong (West Hills, CA); Wei, Qiang (West Hills, CA); Zheng, Haixing (Oak Park, CA)

2002-01-01T23:59:59.000Z

131

Exploration of R2XM2 (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge): Structural Motifs, the novel Compound Gd2AlGe2 and Analysis of the U3Si2 and Zr3Al2 Structure Types  

SciTech Connect (OSTI)

In the process of exploring and understanding the influence of crystal structure on the system of compounds with the composition Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} several new compounds were synthesized with different crystal structures, but similar structural features. In Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, the main feature of interest is the magnetocaloric effect (MCE), which allows the material to be useful in magnetic refrigeration applications. The MCE is based on the magnetic interactions of the Gd atoms in the crystal structure, which varies with x (the amount of Si in the compound). The crystal structure of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} can be thought of as being formed from two 3{sup 2}434 nets of Gd atoms, with additional Gd atoms in the cubic voids and Si/Ge atoms in the trigonal prismatic voids. Attempts were made to substitute nonmagnetic atoms for magnetic Gd using In, Mg and Al. Gd{sub 2}MgGe{sub 2} and Gd{sub 2}InGe{sub 2} both possess the same 3{sup 2}434 nets of Gd atoms as Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, but these nets are connected differently, forming the Mo{sub 2}FeB{sub 2} crystal structure. A search of the literature revealed that compounds with the composition R{sub 2}XM{sub 2} (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge) crystallize in one of four crystal structures: the Mo{sub 2}FeB{sub 2}, Zr{sub 3}Al{sub 2}, Mn{sub 2}AlB{sub 2} and W{sub 2}CoB{sub 2} crystal structures. These crystal structures are described, and the relationships between them are highlighted. Gd{sub 2}AlGe{sub 2} forms an entirely new crystal structure, and the details of its synthesis and characterization are given. Electronic structure calculations are performed to understand the nature of bonding in this compound and how electrons can be accounted for. A series of electronic structure calculations were performed on models with the U{sub 3}Si{sub 2} and Zr{sub 3}Al{sub 2} structures, using Zr and A1 as the building blocks. The starting point for these models was the U{sub 3}Si{sub 2} structure, and models were created to simulate the transition from the idealized U{sub 3}Si{sub 2} structure to the distorted Zr{sub 3}Al{sub 2} structure. Analysis of the band structures of the models has shown that the transition from the U{sub 3}Si{sub 2} structure to the Zr{sub 3}Al{sub 2} structure lifts degeneracies along the {Lambda} {yields} Z direction, indicating a Peierls-type mechanism for the displacement occurring in the positions of the Zr atoms.

Sean William McWhorter

2006-05-01T23:59:59.000Z

132

Silicone metalization  

DOE Patents [OSTI]

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2008-12-09T23:59:59.000Z

133

Silicone metalization  

DOE Patents [OSTI]

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2006-12-05T23:59:59.000Z

134

Ecotoxicit des terres rares Les terres rares sont un groupe de mtaux qui  

E-Print Network [OSTI]

'automobile pour dépolluer les gaz d'échappement constituent le principal débouché des terres rares (tout véhicules hybrides, les turbines d'éoliennes ainsi que dans le nucléaire et l'armement. Les terres rares ont

Wehrli, Bernhard

135

Ames Lab 101: Rare-Earth Recycling  

SciTech Connect (OSTI)

Recycling keeps paper, plastics, and even jeans out of landfills. Could recycling rare-earth magnets do the same? Perhaps, if the recycling process can be improved. Scientists at the U.S. Department of Energy's Ames Laboratory are working to more effectively remove the neodymium, a rare earth, from the mix of other materials in a magnet.

Ryan Ott

2012-09-05T23:59:59.000Z

136

Ames Lab 101: Rare-Earth Recycling  

ScienceCinema (OSTI)

Recycling keeps paper, plastics, and even jeans out of landfills. Could recycling rare-earth magnets do the same? Perhaps, if the recycling process can be improved. Scientists at the U.S. Department of Energy's Ames Laboratory are working to more effectively remove the neodymium, a rare earth, from the mix of other materials in a magnet.

Ryan Ott

2013-06-05T23:59:59.000Z

137

Stark spectroscopy on rare gas atoms  

E-Print Network [OSTI]

Stark spectroscopy on rare gas atoms PROEFSCHRIFT ter verkrijging van de graad van doctor aan de-DATA LIBRARY TECHNISCHE UNIVERSITEIT EINDHOVEN Jiang, Tao Stark spectroscopy on rare gas atoms / by Tao Jiang / gasontladingen Subject headings : plasma diagnostics / Stark effect / optogalvanic spectroscopy / atomic emission

Eindhoven, Technische Universiteit

138

The Colorado Rare Plant Technical Committee presents  

E-Print Network [OSTI]

The Colorado Rare Plant Technical Committee presents: 3rd Annual Rare Plant Symposium Sponsored by: Colorado Native Plant Society University of Colorado Herbarium US Fish and Wildlife Service Colorado and Eastern Colorado (Las Animas, Weld, Kit Carson, Huerfano, Pueblo, Otero, Prowers, Fremont, and El Paso

139

Metal electrode for amorphous silicon solar cells  

DOE Patents [OSTI]

An amorphous silicon solar cell having an N-type region wherein the contact to the N-type region is composed of a material having a work function of about 3.7 electron volts or less. Suitable materials include strontium, barium and magnesium and rare earth metals such as gadolinium and yttrium.

Williams, Richard (Princeton, NJ)

1983-01-01T23:59:59.000Z

140

Cadmium and Zinc Thiolate and Selenolate Metal-Organic Frameworks  

SciTech Connect (OSTI)

Metal-organic frameworks based on metal-sulfur or metal-selenium bonds are relatively rare; herein we describe the synthesis and structural characterization of several examples, including, for example, [Cd(en){sub 3}][Cd(SC{sub 6}H{sub 4}S){sub 2}], which contains the anionic two-dimensional square-grid network [Cd(SC{sub 6}H{sub 4}S){sub 2}]{sub n}{sup 2n-}.

Turner, D.; Stone, K; Stephens, P; Vaid, T

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

RARE EARTHS By James B. Hedrick  

E-Print Network [OSTI]

at its separation Domestic mine production of rare earths Uruguay Round of Multilateral Trade plant at Mountain Pass, CA. Rhône-Poulenc increased in 1994. The domestic economy Negotiation. The GATT Uruguay

142

THE INTERACTION OF RARE GAS METASTABLE ATOMS  

E-Print Network [OSTI]

in the study of metastable atom reactions. > 1 it- Fig, laa raetastable rare gas atom, three quantities are necessaryOF iiARE GAS METASTABLF ATOMS Andrew Zun-Foh Wang M a t e r

Wang, A.Z.-F.

2011-01-01T23:59:59.000Z

143

Ames Lab 101: Rare-Earth Magnets  

ScienceCinema (OSTI)

Senior Scientist, Bill McCallum, briefly discusses rare-earth magnets and their uses and how Ames Lab is research new ways to save money and energy using magnets.

McCallum, Bill

2012-08-29T23:59:59.000Z

144

The BNL rare kaon decay program  

SciTech Connect (OSTI)

The rare kaon decay program at Brookhaven National Laboratory is reviewed. Results from the last round of experiments are briefly discussed. The three experiments currently collecting data are described. Prospects for future experiments are discussed.

Littenberg, L.

1996-12-31T23:59:59.000Z

145

Probing QCD with Rare Charmless $B$ Decays  

SciTech Connect (OSTI)

Rare charmless hadronic B decays are a good testing ground for QCD. In this paper we describe a selection of new measurements made by the BABAR and BELLE collaborations.

Gradl, Wolfgang

2006-07-07T23:59:59.000Z

146

Epitaxial growth of rare-earth silicides on (111) Si  

SciTech Connect (OSTI)

Rapid heating with an electron beam has been used to react overlayers of rare-earth (RE) metals with (111) Si, forming epitaxial layers of silicides of Y, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Under conventional furnace annealing, forming such silicides on Si typically leads to rough, pitted surfaces. The use of fast beam heating not only results in a much smoother surface topology but also helps promote epitaxial growth on (111) Si in both solid and liquid phase reactions. These epitaxial silicides have a hexagonal RESi/sub approximately1.7/ structure (defected AlB/sub 2/ type). Their orientation with the Si substrate is (0001)parallel(111), with predicted lattice mismatches ranging from +0.83 to -2.55%.

Knapp, J.A.; Picraux, S.T.

1986-02-17T23:59:59.000Z

147

Metal oxide films on metal  

DOE Patents [OSTI]

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

148

Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors  

E-Print Network [OSTI]

300-500°C. Doping rare earth phosphate glasses with Ce, andRare Earth Phosphate Glass and Glass-Ceramic Protonconductivity of alkaline-earth doped rare earth phosphate

De Jonghe, Lutgard C.

2010-01-01T23:59:59.000Z

149

Preparations of rare earth-iron alloys by thermite reduction  

DOE Patents [OSTI]

An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA)

1986-09-16T23:59:59.000Z

150

Metals 2000  

SciTech Connect (OSTI)

This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

Allison, S.W.; Rogers, L.C.; Slaughter, G. [Oak Ridge National Lab., TN (United States); Boensch, F.D. [6025 Oak Hill Lane, Centerville, OH (United States); Claus, R.O.; de Vries, M. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)

1993-05-01T23:59:59.000Z

151

Dendritic metal nanostructures  

DOE Patents [OSTI]

Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

2010-08-31T23:59:59.000Z

152

RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless noted)  

E-Print Network [OSTI]

rare earths consumed in the United States was more than $500 million. Principal uses were in petroleum and Foreign). Government Stockpile: Stockpile Status--9-30-95 Uncommitted Committed Authorized Disposals was reported in the first half of the year. China remained a major source of separated rare-earth compounds

153

The Colorado Rare Plant Technical Committee presents: Colorado Rare Plant Symposium  

E-Print Network [OSTI]

The Colorado Rare Plant Technical Committee presents: 6th Annual Colorado Rare Plant Symposium September 11, 2009 Loveland, Colorado Sponsored by:Sponsored by: Colorado Native Plant Society University of Colorado Herbarium US Fish and Wildlife Service Colorado Natural Heritage Program USDA Forest Service #12

154

The Colorado Rare Plant Technical Committee presents: Colorado Rare Plant Symposium  

E-Print Network [OSTI]

The Colorado Rare Plant Technical Committee presents: 7th Annual Colorado Rare Plant Symposium September 10, 2010 Denver, Colorado Sponsored by: Colorado Native Plant Society University of Colorado Herbarium US Fish and Wildlife Service Colorado Natural Heritage Program USDA Forest Service #12;#12;Aletes

155

Equine in vitro fertilization  

E-Print Network [OSTI]

-culturing with equine oviductal epithelial cells, 50 embryos obtained by in-vitro fertilization showed some degree of development. Sixteen embryos developed to the 2-cell stage, three to 3-cell, seven to the 4-cell, one to the S-cell, two to the 6-cell, one... to the 7-cell, two to the 8-cell, two to the 16-cell, seven to early morula (between 16 and 32 cells), eight to morulas and one to blastocyst. Some embryos developed excessively rapid and could not be considered fertilized embryos. Probably those fast...

Vasquez C., Juan Carlos

1992-01-01T23:59:59.000Z

156

Rare earth phosphors and phosphor screens  

DOE Patents [OSTI]

This invention relates to rare earth phosphor screens for converting image carrying incident radiation to image carrying visible or near-visible radiation and to the rare earth phosphor materials utilized in such screens. The invention further relates to methods for converting image carrying charged particles to image carrying radiation principally in the blue and near-ultraviolet region of the spectrum and to stabilized rare earth phosphors characterized by having a continuous surface layer of the phosphors of the invention. More particularly, the phosphors of the invention are oxychlorides and oxybromides of yttrium, lanthanum and gadolinium activated with trivalent cerium and the conversion screens are of the type illustratively including x-ray conversion screens, image amplifier tube screens, neutron imaging screens, cathode ray tube screens, high energy gamma ray screens, scintillation detector screens and screens for real-time translation of image carrying high energy radiation to image carrying visible or near-visible radiation.

Buchanan, Robert A. (Palo Alto, CA); Maple, T. Grant (Sunnyvale, CA); Sklensky, Alden F. (Sunnyvale, CA)

1981-01-01T23:59:59.000Z

157

Prospects for Rare Earth Elements From Marine Minerals  

E-Print Network [OSTI]

Prospects for Rare Earth Elements From Marine Minerals Rare earth elements (REEs) compose in the earth's crust. However, because of their geochemical proper es, rare earth elements are typically. Briefing Paper 02/12 Jim Hein | May 2012 www.isa.org.jm Table 1: Rare Earth Elements This paper

158

E-Print Network 3.0 - actinide metal compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

effects in the X-ray photoemission spectra of the actinides Summary: in 3d transition metal compounds and ns (n 4 , 5) levels in rare earth systems, it is clear that ME......

159

E-Print Network 3.0 - alkaline-earth metal uranium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In metamorphic rocks uranium and rare earth metals can form minerals. An example... Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

160

Search for rare and forbidden eta ' decays  

E-Print Network [OSTI]

We have searched for rare and forbidden decays of the eta' meson in hadronic events at the CLEO II detector. The search is conducted on 4.80 fb(-1) of e(+)e(-) collisions at 10.6 GeV center-of-mass energy at the Cornell Electron Storage Ring. We...

Ammar, Raymond G.; Baringer, Philip S.; Bean, Alice; Besson, David Zeke; Coppage, Don; Davis, Robin E. P.; Kotov, S.; Kravchenko, I.; Kwak, Nowhan; Zhou, X.

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Rare Plant Conservation Planning Workshop Results  

E-Print Network [OSTI]

­ one of the most imperiled species in Colorado. The species is at risk of extinction due to its narrowRare Plant Conservation Planning Workshop Results PAGOSA SPRINGS Plant Species of Focus Pagosa............................................................................................................................. 12 Attachment 1. Additional key species and plant communities in the Pagosa Springs area 13

162

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

163

Composite metal membrane  

DOE Patents [OSTI]

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

164

Composite metal membrane  

DOE Patents [OSTI]

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

1998-04-14T23:59:59.000Z

165

Mechanical property, biocorrosion and in vitro biocompatibility evaluations of MgLi(Al)(RE) alloys for future cardiovascular stent  

E-Print Network [OSTI]

February 2013 Keywords: Mg­Li-based alloys Biodegradable Corrosion Biocompatibility In vitro a b s t r a c to the presence of lithium. To improve the mechanical strengths of Mg­Li binary alloys, aluminum and rare earth- corrosion behavior were evaluated by using optical microscopy, X-ray diffraction, scanning electronic

Zheng, Yufeng

166

The Nonlinear Evolution of Rare Events  

E-Print Network [OSTI]

In this paper I consider the nonlinear evolution of a rare density fluctuation in a random density field with Gaussian fluctuations, and I rigorously show that it follows the spherical collapse dynamics applied to its mean initial profile. This result is valid for any cosmological model and is independent of the shape of the power spectrum. In the early stages of the dynamics the density contrast of the fluctuation is seen to follow with a good accuracy the form $$\\delta=(1-\\delta_L/1.5)^{-1.5}-1,$$ where $\\delta_L$ is the linearly extrapolated overdensity. I then investigate the validity domain of the rare event approximation in terms of the parameter $\

F. Bernardeau

1993-11-25T23:59:59.000Z

167

Rare K decays: Challenges and Perspectives  

E-Print Network [OSTI]

At this stage of the LHC program, the prospect for a new physics signal in the very rare K ---> pi nu nu bar decays may be dented, but remains well alive thanks to their intrinsic qualities. First, these decays are among the cleanest observables in the quark flavor sector. When combined with their terrible suppression in the Standard Model, they thus offer uniquely sensitive probes. Second, the LHC capabilities are not ideal for all kinds of new physics, even below the TeV scale. For example, rather elusive scenarios like natural-SUSY-like hierarchical spectrum, baryon number violation, or new very light but very weakly interacting particles may well induce deviations in rare K decays. Even though experimentalists should brace themselves for tiny deviations, these modes thus have a clear role to play in the LHC era.

Christopher Smith

2014-09-22T23:59:59.000Z

168

Metal Hydrides  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of EnergyDevelopmentTechnologies |Charles Page -toMetabolic PathwaysMetal

169

Concerning the Facility for Rare Isotope Beams  

ScienceCinema (OSTI)

James Symons, Nuclear Science Division Director at Lawrence Berkeley Lab, and Daniela Leitner, head of operations at Berkeley Lab's 88-Inch Cyclotron, discuss major contributions to the new Facility for Rare Isotope Beams (FRIB) at Michigan State University, including ion source, which will based on the VENUS source built for the 88-Inch Cyclotron, and the GRETA gamma-ray detector now under construction there.

Symons, James

2013-05-29T23:59:59.000Z

170

Carbo-metallic oil-conversion process and catalysts  

SciTech Connect (OSTI)

This patent describes a continuous process for cracking of a residual hydrocarbon feedstock into lower molecular weight hydrocarbon transportation fuels. The cracking being carried out in the presence of a catalyst having catalyst parameters comprising porosity, metals content, rare earth content, and zeolite content. The residual hydrocarbon feedstock comprising metal contaminants, fractions boiling above 1025{degrees}F. comprising asphaltenes, polynuclear aromatics, naphthenes and prophyrins.

Hettinger, W.P.; Beck, W.

1989-10-31T23:59:59.000Z

171

Preparations of rare earth-iron alloys by thermite reduction  

DOE Patents [OSTI]

Disclosed is an improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.

1985-10-28T23:59:59.000Z

172

Behavior of Rare Earth Elements in Geothermal Systems- A New...  

Open Energy Info (EERE)

of Rare Earth Elements in Geothermal Systems- A New ExplorationExploitation Tool? Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Behavior of Rare Earth...

173

Mechanochemical processing for metals and metal alloys  

DOE Patents [OSTI]

A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)

2001-01-01T23:59:59.000Z

174

2005 Minerals Yearbook RaRe eaRths  

E-Print Network [OSTI]

, and shipped. substantial stocks of lanthanide concentrates and intermediate and refined compounds were for the petroleum industry and processed cerium and zirconia compounds In 2005, world rare-earth production decreased as did imports of individual rare-earth compounds and mixed rare-earth compounds. U.s. imports

175

1 INTRODUCTION The rare earth elements (REE's) form a unique  

E-Print Network [OSTI]

1 INTRODUCTION The rare earth elements (REE's) form a unique chemical set wherein the gradual October 1991 to December 1993. Clean A time series of dissolved rare earth elements in the lower University, State University, AR 72467 ABSTRACT: Dissolved rare earth element (REE) concentrations were

Chen, Zhongxing

176

RARE EARTH ELEMENT SENSITIVITY FACTORS IN CALCIC PLAGIOCLASE (ANORTHITE)  

E-Print Network [OSTI]

RARE EARTH ELEMENT SENSITIVITY FACTORS IN CALCIC PLAGIOCLASE (ANORTHITE) C. Floss and B. Jolliff Mc Brookings Drive, St. Louis, MO 63130 1. Introduction The rare earth elements (REE) are sensitive indicators concentrations for each sample are listed in Table 1 and are shown in Fig. 1. Table 1. Rare Earth Element Data

177

MATERIAL FLOW ANALYSIS FOR IDENTIFYING RARE EARTH ELEMENT  

E-Print Network [OSTI]

MATERIAL FLOW ANALYSIS FOR IDENTIFYING RARE EARTH ELEMENT RECYCLING POTENTIALS IN THE EU-27 D Rochelle (F) SUMMARY: Rare earth elements (REEs) are essential for high-techology industrial sectors earths. Rare earth elements (REEs) are a group of 17 elements comprising the 15 lanthanides, scandium

Paris-Sud XI, Université de

178

Scintillation of rare earth doped fluoride nanoparticles  

SciTech Connect (OSTI)

The scintillation response of rare earth (RE) doped core/undoped (multi-)shell fluoride nanoparticles was investigated under x-ray and alpha particle irradiation. A significant enhancement of the scintillation response was observed with increasing shells due: (i) to the passivation of surface quenching defects together with the activation of the REs on the surface of the core nanoparticle after the growth of a shell, and (ii) to the increase of the volume of the nanoparticles. These results are expected to reflect a general aspect of the scintillation process in nanoparticles, and to impact radiation sensing technologies that make use of nanoparticles.

Jacobsohn, L. G.; McPherson, C. L.; Sprinkle, K. B.; Ballato, J. [Center for Optical Materials Science and Engineering Technologies (COMSET), and School of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States); Yukihara, E. G. [Physics Department, Oklahoma State University, Stillwater, Oklahoma 74078-3072 (United States); DeVol, T. A. [Department of Environmental Engineering and Earth Sciences, Clemson University, Clemson, South Carolina 29634-0905 (United States)

2011-09-12T23:59:59.000Z

179

Rare Iron Oxide in Ancient Chinese Pottery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromising Science for1PrincipalRare Iron Oxide in Ancient Chinese

180

Rapporteur's Report - workshop on rare earth elements  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergy 0611__Joint_DOE_GoJ_AMS_Data_v3.pptx More Documents &DOE.FTrans-Atlantic Workshop on Rare

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Rare b hadron decays at the LHC  

E-Print Network [OSTI]

With the completion of Run~I of the CERN Large Hadron Collider, particle physics has entered a new era. The production of unprecedented numbers of heavy-flavoured hadrons in high energy proton-proton collisions allows detailed studies of flavour-changing processes. The increasingly precise measurements allow to probe the Standard Model with a new level of accuracy. Rare $b$ hadron decays provide some of the most promising approaches for such tests, since there are several observables which can be cleanly interpreted from a theoretical viewpoint. In this article, the status and prospects in this field are reviewed, with a focus on precision measurements and null tests.

Blake, T; Hiller, G

2015-01-01T23:59:59.000Z

182

Rare-Earth-Free Traction Motor: Rare Earth-Free Traction Motor for Electric Vehicle Applications  

SciTech Connect (OSTI)

REACT Project: Baldor will develop a new type of traction motor with the potential to efficiently power future generations of EVs. Unlike today’s large, bulky EV motors which use expensive, imported rare-earth-based magnets, Baldor’s motor could be light, compact, contain no rare earth materials, and have the potential to deliver more torque at a substantially lower cost. Key innovations in this project include the use of a unique motor design, incorporation of an improved cooling system, and the development of advanced materials manufacturing techniques. These innovations could significantly reduce the cost of an electric motor.

None

2012-01-01T23:59:59.000Z

183

Extracting metals directly from metal oxides  

DOE Patents [OSTI]

A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

Wai, C.M.; Smart, N.G.; Phelps, C.

1997-02-25T23:59:59.000Z

184

Extracting metals directly from metal oxides  

DOE Patents [OSTI]

A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

1997-01-01T23:59:59.000Z

185

Note: Portable rare-earth element analyzer using pyroelectric crystal  

SciTech Connect (OSTI)

We report a portable rare-earth element analyzer with a palm-top size chamber including the electron source of a pyroelectric crystal and the sample stage utilizing cathodoluminescence (CL) phenomenon. The portable rare-earth element analyzer utilizing CL phenomenon is the smallest reported so far. The portable rare-earth element analyzer detected the rare-earth elements Dy, Tb, Er, and Sm of ppm order in zircon, which were not detected by scanning electron microscopy-energy dispersive X-ray spectroscopy analysis. We also performed an elemental mapping of rare-earth elements by capturing a CL image using CCD camera.

Imashuku, Susumu, E-mail: imashuku.susumu.2m@kyoto-u.ac.jp; Fuyuno, Naoto; Hanasaki, Kohei; Kawai, Jun [Department of Materials Science and Engineering, Kyoto University, Sakyo, Kyoto 606-8501 (Japan)] [Department of Materials Science and Engineering, Kyoto University, Sakyo, Kyoto 606-8501 (Japan)

2013-12-15T23:59:59.000Z

186

New fission fragment distributions and r-process origin of the rare-earth elements  

E-Print Network [OSTI]

Neutron star (NS) merger ejecta offer a viable site for the production of heavy r-process elements with nuclear mass numbers A > 140. The crucial role of fission recycling is responsible for the robustness of this site against many astrophysical uncertainties, but calculations sensitively depend on nuclear physics. In particular the fission fragment yields determine the creation of 110 rare-earth peak that is nicely compatible with the abundance patterns in the Sun and metal-poor stars. This new finding further strengthens the case of NS mergers as possible dominant origin of r-nuclei with A > 140.

S. Goriely; J. -L. Sida; J. -F. Lemaitre; S. Panebianco; N. Dubray; S. Hilaire; A. Bauswein; H. -Thomas Janka

2013-11-22T23:59:59.000Z

187

Metal-phosphate binders  

DOE Patents [OSTI]

A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

2009-05-12T23:59:59.000Z

188

Searches for very rare decays of kaons  

SciTech Connect (OSTI)

The physics motivation for searches for very rare kaon decays, either forbidden or suppressed within the Standard Model, is briefly discussed. Simple arguments conclude that such searches probe possible new forces at a 200 TeV mass scale or constitute a precision test of the electroweak model. The examples of such process are decays of K{sub L}{sup 0} {yields} {mu} {sup {+-}}e{sup -+}, K{sup +} {yields} {pi}{sup +} {mu}{sup +} e{sup -}, K{sub L}{sup 0} {yields} {mu}{sup +} {mu}{sup -}, and K{sup +} {yields} {pi} {yields} {pi}{sup +}{nu}{bar {nu}}. We present the current experimental status and describe the new efforts to reach sensitivities down to one part in 10{sup 12}. The discussion is focused on the experimental program at the Alternating Gradient Synchrotron at Brookhaven National Laboratory, where intense beams make such studies possible.

Lang, K. [Univ. of Texas, Austin, TX (United States)

1997-01-01T23:59:59.000Z

189

Rare earth doped zinc oxide varistors  

DOE Patents [OSTI]

A varistor includes a Bi-free, essentially homogeneous sintered body of a ceramic composition including, expressed as nominal weight %, 0.2-4.0% oxide of at least one rare earth element, 0.5-4.0% Co.sub.3 O.sub.4, 0.05-0.4% K.sub.2 O, 0.05-0.2% Cr.sub.2 O.sub.3, 0-0.2% CaO, 0.00005-0.01% Al.sub.2 O.sub.3, 0-2% MnO, 0-0.05% MgO, 0-0.5% TiO.sub.3, 0-0.2% SnO.sub.2, 0-0.02% B.sub.2 O.sub.3, balance ZnO.

McMillan, April D. (Knoxville, TN); Modine, Frank A. (Oak Ridge, TN); Lauf, Robert J. (Oak Ridge, TN); Alim, Mohammad A. (Medina, OH); Mahan, Gerald D. (Oak Ridge, TN); Bartkowiak, Miroslaw (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

190

Rare earth doped zinc oxide varistors  

DOE Patents [OSTI]

A varistor includes a Bi-free, essentially homogeneous sintered body of a ceramic composition including, expressed as nominal weight %, 0.2--4.0% oxide of at least one rare earth element, 0.5--4.0% Co{sub 3}O{sub 4}, 0.05--0.4% K{sub 2}O, 0.05--0.2% Cr{sub 2}O{sub 3}, 0--0.2% CaO, 0.00005--0.01% Al{sub 2}O{sub 3}, 0--2% MnO, 0--0.05% MgO, 0--0.5% TiO{sub 3}, 0--0.2% SnO{sub 2}, 0--0.02% B{sub 2}O{sub 3}, balance ZnO. 4 figs.

McMillan, A.D.; Modine, F.A.; Lauf, R.J.; Alim, M.A.; Mahan, G.D.; Bartkowiak, M.

1998-12-29T23:59:59.000Z

191

Metal Hydrides - Science Needs  

Broader source: Energy.gov (indexed) [DOE]

with traditions in metal hydride research Metal and Ceramic Sciences Condensed Matter Physics Materials Chemistry Chemical and Biological Sciences Located on campus of Tier...

192

Magnetic properties of RT2Zn20; R = rare earth, T = Fe, Co, Ru, Os and Ir  

SciTech Connect (OSTI)

It is well known that rare earth intermetallic compounds have versatile, magnetic properties associated with the 4f electrons: a local moment associated with the Hund's rule ground state is formed in general, but a strongly correlated, hybridized state may also appear for specific 4f electronic configuration (eg. for rare earth elements such as Ce or Yb). On the other hand, the conduction electrons in rare earth intermetallic compounds, certainly ones associated with non hybridizing rare earths, usually manifest non-magnetic behavior and can be treated as a normal, non-interacted Fermi liquid, except for some 3d-transition metal rich binary or ternary systems which often manifest strong, itinerant, d electron dominant magnetic behavior. Of particular interest are examples in which the band filling of the conduction electrons puts the system in the vicinity of a Stoner transition: such systems, characterized as nearly or weakly ferromagnet, manifest strongly correlated electronic properties [Moriya, 1985]. For rare earth intermetallic compounds, such systems provide an additional versatility and allow for the study of the behaviors of local moments and hybridized moments which are associated with 4f electron in a correlated conduction electron background.

Jia, Shuang

2008-12-15T23:59:59.000Z

193

The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river sediments  

E-Print Network [OSTI]

The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river were analyzed to characterize their rare earth element (REE) compositions. Although REE concentrations rights reserved. Keywords: rare earths; sediments; Huang He; Yangtze River 1. Introduction Rare earth

Yang, Shouye

194

Anisotropic magnetic properties of light rare-earth diantimonides  

SciTech Connect (OSTI)

Results are presented of anisotropic temperature and field-dependent magnetization M(H,T) and resistivity {rho}(H,T) measurements on high quality single crystals of the light rare-earth diantimonides RSb{sub 2}, R=La-Nd, Sm. All of these, excepting LaSb{sub 2}, magnetically order at low temperatures, and for CeSb{sub 2} and NdSb{sub 2} several magnetically ordered phases were observed in low-field magnetization and zero-field resistivity measurements. For R=Ce-Sm strong anisotropies, associated with crystalline electric field (CEF) splitting of the R{sup 3+} ion, were found in M(T) measurements both below and above magnetic ordering temperatures. Furthermore, for R=Ce-Nd metamagnetic transitions were observed in M(H) and {rho}(H) for H{parallel}(ab) in the magnetically ordered state. In addition, above 15 kG de Haas{endash}van Alphen oscillations are observed for SmSb{sub 2} and Shubnikov{endash}de Haas quantum oscillations are observed above {approximately}120kG for NdSb{sub 2} and SmSb{sub 2}. The zero-field in-plane resistivity {rho}{sub ab} of all of the compounds is metallic (d{rho}/dT{gt}0), with residual resistance ratios ranging from 40 to 750. The c-axis resistivity is also metallic, but appears to be considerably larger than the in-plane value, consistent with the diantimonides being quasi-two-dimensional materials. The magnetoresistance of all members of the series is large, approximately linear in H at moderate fields, and is also dependent on the relative orientation of the applied magnetic fields to the crystallographic axes. The extreme case of SmSb{sub 2} has [{rho}(55kG){minus}{rho}(0)]/{rho}(0){gt}50000{percent} at T=2K and H{parallel}c. {copyright} {ital 1998} {ital The American Physical Society}

Budko, S.L.; Canfield, P.C. [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States)] [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Mielke, C.H.; Lacerda, A.H. [National High Magnetic Field Laboratory, Los Alamos Facility, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [National High Magnetic Field Laboratory, Los Alamos Facility, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

1998-06-01T23:59:59.000Z

195

POWDER METALLURGICAL PROCESSING OF MAGNETOSTRICTIVE MATERIALS BASED ON RARE EARTH-IRON INTERMETALLIC COMPOUNDS  

E-Print Network [OSTI]

R « any of several rare earth elements) was discovered. Toobserved for pure rare earth elements. This and the strong

Malekzadeh, Manoochehr

2011-01-01T23:59:59.000Z

196

Trichofolliculoma: a rare variant of hair follicle hamartoma  

E-Print Network [OSTI]

to the regressing normal hair follicle in its cycle. J Cutanal. Trichofolliculoma: An Uncommon Hair Follicle Hamartoma.Trichofolliculoma: a rare variant of hair follicle hamartoma

Gokalp, Hilal; Gurer, Mehmet Ali; Alan, Saadet

2013-01-01T23:59:59.000Z

197

Photoemission Study of the Rare Earth Intermetallic Compounds: RNi2Ge2 (R=Eu, Gd)  

SciTech Connect (OSTI)

EuNi{sub 2}Ge{sub 2} and GdNi{sub 2}Ge{sub 2} are two members of the RT{sub 2}X{sub 2} (R = rare earth, T = transition metal and X = Si, Ge) family of intermetallic compounds, which has been studied since the early 1980s. These ternary rare-earth intermetallic compounds with the tetragonal ThCr{sub 2}Si{sub 2} structure are known for their wide variety of magnetic properties, Extensive studies of the RT{sub 2}X{sub 2} series can be found in Refs [ 1,2,3]. The magnetic properties of the rare-earth nickel germanides RNi{sub 2}Ge{sub 2} were recently studied in more detail [4]. The purpose of this dissertation is to investigate the electronic structure (both valence band and shallow core levels) of single crystals of EuNi{sub 2}Ge{sub 2} and GdNi{sub 2}Ge{sub 2} and to check the assumptions that the f electrons are non-interacting and, consequently, the rigid-band model for these crystals would work [11], using synchrotron radiation because, to the best of our knowledge, no photoemission measurements on those have been reported. Photoemission spectroscopy has been widely used to study the detailed electronic structure of metals and alloys, and especially angle-resolved photoemission spectroscopy (ARPES) has proven to be a powerful technique for investigating Fermi surfaces (FSs) of single-crystal compounds.

Jongik Park

2004-12-19T23:59:59.000Z

198

Heavy metal biosensor  

SciTech Connect (OSTI)

Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

2014-04-15T23:59:59.000Z

199

RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)  

E-Print Network [OSTI]

%; glass polishing and ceramics, 14%; metallurgical additives and alloys, 13%; petroleum refining catalysts continued to be a major exporter and consumer of rare-earth products in 2004. The estimated value of refined,980 Mixed REOs 2,190 2,040 1,040 2,150 1,540 Rare-earth chlorides 1,330 2,590 1,800 1,890 1,520 Rare

200

RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content unless otherwise noted)  

E-Print Network [OSTI]

, televisions, and x-ray-intensifying film, 14%; chemicals and petroleum refining catalysts, 11%; ceramics, 3, and importer of rare-earth products in 2008. The estimated value of refined rare earths imported by the United,880 2,170 2,590 2,680 2,180 Mixed REOs 1,660 640 1,570 2,570 2,750 Rare-earth chlorides 1,310 2,670 2

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Portraits of some representatives of metal boride carbide and boride silicide compounds  

SciTech Connect (OSTI)

Different ternary alkaline-earth and rare-earth metal boron carbide and silicide compounds are examined using the solid-state language of Zintl-Klemm concept, band structures, and density of states, in order to show that the topology of the non-metal sub-lattice is highly dependent on the electron count. It is also shown that the chemistry of rare-earth metal-boron-silicon does not parallel that of rare-earth metal-boron-carbon. B-C bonds are easily formed in the latter, leading to a large variety of different structural arrangements, whereas Si-B bonds are hardly observed in the former, except in insertion compounds. - Graphical abstract: Some ternary alkaline-earth and rare-earth metal boron carbide and silicide compounds are examined using the solid-state language of Zintl-Klemm concept, band structures, and density of states, in order to show that the topology of the non-metal sub-lattice is highly dependent on the electron count.

Ben Yahia, Mouna [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Roger, Jerome [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Rocquefelte, Xavier [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Gautier, Regis [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Bauer, Joseph [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Guerin, Roland [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Saillard, Jean-Yves [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Halet, Jean-Francois [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France)]. E-mail: halet@univ-rennes1.fr

2006-09-15T23:59:59.000Z

202

Effect of damping on the laser induced ultrafast switching in rare earth-transition metal alloys  

SciTech Connect (OSTI)

In this paper, we present simulations of thermally induced magnetic switching in ferrimagnetic systems performed with a Landau-Lifshitz-Bloch (LLB) equation for damping constant in a wide range of values. We have systematically studied the GdFeCo ferrimagnet with various concentrations of Gd and compared for some values of parameters the LLB results with atomistic simulations. The agreement is remarkably good, which shows that the dynamics described by the ferrimagnetic LLB is a reasonable approximation of this complex physical phenomenon. As an important element, we show that the LLB is able to also describe the intermediate formation of a ferromagnetic state which seems to be essential to understand laser induced ultrafast switching. The study reveals the fundamental role of damping during the switching process.

Oniciuc, Eugen; Stoleriu, Laurentiu; Cimpoesu, Dorin; Stancu, Alexandru, E-mail: alstancu@uaic.ro [Faculty of Physics and CARPATH Center, “Alexandru Ioan Cuza” University, 700506 Iasi (Romania)

2014-06-02T23:59:59.000Z

203

Selecting the suitable dopants: electronic structures of transition metal and rare earth doped thermoelectric sodium cobaltate  

E-Print Network [OSTI]

Engineered Na0.75CoO2 is considered a prime candidate to achieve high efficiency thermoelectric systems to regenerate electricity from waste heat. In this work, three elements with outmost electronic configurations, (1) an open d shell (Ni), (2) a closed d shell (Zn), and (3) an half fill f shell (Eu) with a maximum unpaired electrons, were selected to outline the dopants' effects on electronic and crystallographic structures of Na0.75CoO2. Systematic ab initio density functional calculations showed that the formation energy of these dopants was found to be lowest when residing on sodium layer and ranked as -1.1 eV, 0.44 eV and 3.44 eV for Eu, Ni and Zn respectively. Furthermore Ni was also found to be stable when substituting Co ion. As these results show great harmony with existing experimental data, they provide new insights into the fundamental principle of dopant selection for manipulating the physical properties in the development of high performance sodium cobaltate based thermoelectric materials.

Assadi, M H N; Yu, A B

2012-01-01T23:59:59.000Z

204

Reduction Chemistry of Rare-Earth Metal Complexes: Toward New Reactivity and Properties  

E-Print Network [OSTI]

reactor and was named promethium. Even Nature could onlyrare-earths (except for promethium and europium; ytterbiumeuropium and radioactive promethium) on hand, we synthesized

Huang, Wenliang

2013-01-01T23:59:59.000Z

205

New CMI process recycles valuable rare earth metals from old electronics |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohn CyberNeutrons used to studyThe Ames Laboratory

206

Organic-Inorganic Complexes Containing a Luminescent Rare Earth-Metal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002Optics Group (X-ray

207

Ames Lab, CMI, NEDO hold First Meeting on Rare Metals | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone by E-mail ShareRed Cross Blood Drive Hanford HealthLab, CMI,

208

Modeling the glass forming ability of metals  

E-Print Network [OSTI]

Rare Earth Elements..without the use of rare earth elements” in Bulk Metallicwithout the Use of Rare Earth Elements details the design

Cheney, Justin Lee

2007-01-01T23:59:59.000Z

209

Polymer quenched prealloyed metal powder  

DOE Patents [OSTI]

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Hajaligol, Mohammad R. (Midlothian, VA); Fleischhauer, Grier (Midlothian, VA); German, Randall M. (State College, PA)

2001-01-01T23:59:59.000Z

210

Metal-Air Batteries  

SciTech Connect (OSTI)

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

211

Metal hydrides as electrode/catalyst materials for oxygen evolution/reduction in electrochemical devices  

DOE Patents [OSTI]

An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

Bugga, Ratnakumar V. (Arcadia, CA); Halpert, Gerald (Pasadena, CA); Fultz, Brent (Pasadena, CA); Witham, Charles K. (Pasadena, CA); Bowman, Robert C. (La Mesa, CA); Hightower, Adrian (Whittier, CA)

1997-01-01T23:59:59.000Z

212

In vitro corrosion and cytotoxicity on microcrystalline, nanocrystalline and amorphous NiTi alloy fabricated by high pressure torsion  

E-Print Network [OSTI]

In vitro corrosion and cytotoxicity on microcrystalline, nanocrystalline and amorphous NiTi alloy Amorphous Metals and alloys Corrosion and ion release Cytotoxicity Bulk nanocrystalline and amorphous Ni50 discs by high pressure torsion (HPT) technique. Then their corrosion resistance, surface wettability

Zheng, Yufeng

213

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

Sheng, Lei; Liu, Jing

2014-01-01T23:59:59.000Z

214

Metal phthalocyanine catalysts  

DOE Patents [OSTI]

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1994-01-01T23:59:59.000Z

215

Durable metallized polymer mirror  

DOE Patents [OSTI]

A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

1994-01-01T23:59:59.000Z

216

Durable metallized polymer mirror  

DOE Patents [OSTI]

A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

1994-11-01T23:59:59.000Z

217

Method for in vitro recombination  

SciTech Connect (OSTI)

The present invention relates to an in vitro method, using isolated protein reagents, for joining two double-stranded (ds) DNA molecules of interest, wherein the distal region of the first DNA molecule and the proximal region of the second DNA molecule share a region of sequence identity. The method allows the joining of a number of DNA fragments, in a predetermined order and orientation, without the use of restriction enzymes. It can be used, e.g., to join synthetically produced sub-fragments of a gene or genome of interest.

Gibson, Daniel Glenn; Smith, Hamilton O

2013-05-07T23:59:59.000Z

218

Formation of rare earth carbonates using supercritical carbon dioxide  

DOE Patents [OSTI]

The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

1991-09-03T23:59:59.000Z

219

Ames Lab scientist hopes to improve rare earth purification process...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lab scientist hopes to improve rare earth purification process Using the second fastest supercomputer in the world, a scientist at the U.S. Department of Energy's Ames Laboratory...

220

Thermodynamic Database for Rare Earth Elements Recycling Process...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermodynamic Database for Rare Earth Elements Recycling Process: Energetics of the REE-X Systems (XA;, Mg, Zn, Si, Sn, Mn, Pb, Fe, Co, Ni) Apr 17 2015 11:00 AM - 12:00 PM In-Ho...

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2015, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and Technical Challenges Dr. Georg Bollen Michigan State...

222

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

Lei Sheng; Jie Zhang; Jing Liu

2014-01-30T23:59:59.000Z

223

E-Print Network 3.0 - astronomy-related rare books Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

astronomy-related rare books Search Powered by Explorit Topic List Advanced Search Sample search results for: astronomy-related rare books Page: << < 1 2 3 4 5 > >> 1 Rare Books...

224

U.S. Rare Earth Magnet Patents Table © 11-10-2014 page...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Rare Earth Magnet Patents Table 11-10-2014 page 1 Disclaimer: This U.S. Rare Earth Magnet Patents Table contains a sample of the rare- earth-magnet patents issued by the U.S....

225

Resonant Inelastic X-ray Scattering of Rare-Earth and Copper Systems  

E-Print Network [OSTI]

Introduction The rare earth elements have unique andun?lled f shell of rare earth elements gives them special4d, 4f shells for rare-earth elements. This suggests that

Kvashnina, Kristina

2007-01-01T23:59:59.000Z

226

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents [OSTI]

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, Lamar T. (Knoxville, TN)

1988-01-01T23:59:59.000Z

227

Facility for Rare Isotope Beams: The Journey Has Begun on DOE...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Facility for Rare Isotope Beams: The Journey Has Begun on DOE's latest Scientific User Facility Facility for Rare Isotope Beams: The Journey Has Begun on DOE's latest Scientific...

228

Modeling the electrical resistivity of deformation processed metal-metal composites  

SciTech Connect (OSTI)

Deformation processed metal–metal (matrix–reinforcement) composites (DMMCs) are high-strength, high-conductivity in situ composites produced by severe plastic deformation. The electrical resistivity of DMMCs is rarely investigated mechanistically and tends to be slightly higher than the rule-of-mixtures prediction. In this paper, we analyze several possible physical mechanisms (i.e. phonons, interfaces, mutual solution, grain boundaries, dislocations) responsible for the electrical resistivity of DMMC systems and how these mechanisms could be affected by processing conditions (i.e. temperature, deformation processing). As an innovation, we identified and assembled the major scattering mechanisms for specific DMMC systems and modeled their electrical resistivity in combination. From this analysis, it appears that filament coarsening rather than dislocation annihilation is primarily responsible for the resistivity drop observed in these materials after annealing and that grain boundary scattering contributes to the resistivity at least at the same magnitude as does interface scattering.

Tian, Liang [Ames Laboratory; Anderson, Iver [Ames Laboratory; Riedemann, Trevor [Ames Laboratory; Russell, Alan [Ames Laboratory

2014-09-01T23:59:59.000Z

229

Metal atomization spray nozzle  

DOE Patents [OSTI]

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

Huxford, T.J.

1993-11-16T23:59:59.000Z

230

Carbide/nitride grain refined rare earth-iron-boron permanent magnet and method of making  

DOE Patents [OSTI]

A method of making a permanent magnet wherein 1) a melt is formed having a base alloy composition comprising RE, Fe and/or Co, and B (where RE is one or more rare earth elements) and 2) TR (where TR is a transition metal selected from at least one of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al) and at least one of C and N are provided in the base alloy composition melt in substantially stoichiometric amounts to form a thermodynamically stable compound (e.g. TR carbide, nitride or carbonitride). The melt is rapidly solidified in a manner to form particulates having a substantially amorphous (metallic glass) structure and a dispersion of primary TRC, TRN and/or TRC/N precipitates. The amorphous particulates are heated above the crystallization temperature of the base alloy composition to nucleate and grow a hard magnetic phase to an optimum grain size and to form secondary TRC, TRN and/or TRC/N precipitates dispersed at grain boundaries. The crystallized particulates are consolidated at an elevated temperature to form a shape. During elevated temperature consolidation, the primary and secondary precipitates act to pin the grain boundaries and minimize deleterious grain growth that is harmful to magnetic properties.

McCallum, R. William (Ames, IA); Branagan, Daniel J. (Ames, IA)

1996-01-23T23:59:59.000Z

231

Carbide/nitride grain refined rare earth-iron-boron permanent magnet and method of making  

DOE Patents [OSTI]

A method of making a permanent magnet is disclosed wherein (1) a melt is formed having a base alloy composition comprising RE, Fe and/or Co, and B (where RE is one or more rare earth elements) and (2) TR (where TR is a transition metal selected from at least one of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al) and at least one of C and N are provided in the base alloy composition melt in substantially stoichiometric amounts to form a thermodynamically stable compound (e.g. TR carbide, nitride or carbonitride). The melt is rapidly solidified in a manner to form particulates having a substantially amorphous (metallic glass) structure and a dispersion of primary TRC, TRN and/or TRC/N precipitates. The amorphous particulates are heated above the crystallization temperature of the base alloy composition to nucleate and grow a hard magnetic phase to an optimum grain size and to form secondary TRC, TRN and/or TRC/N precipitates dispersed at grain boundaries. The crystallized particulates are consolidated at an elevated temperature to form a shape. During elevated temperature consolidation, the primary and secondary precipitates act to pin the grain boundaries and minimize deleterious grain growth that is harmful to magnetic properties. 33 figs.

McCallum, R.W.; Branagan, D.J.

1996-01-23T23:59:59.000Z

232

Interlaboratory Evaluation of in Vitro Cytotoxicity and Inflammatory...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Vitro Cytotoxicity and Inflammatory Responses to Engineered Nanomaterials: The NIEHS Nano GO Interlaboratory Evaluation of in Vitro Cytotoxicity and Inflammatory Responses to...

233

High efficiency rare-earth emitter for thermophotovoltaic applications  

SciTech Connect (OSTI)

In this work, we propose a rare-earth-based ceramic thermal emitter design that can boost thermophotovoltaic (TPV) efficiencies significantly without cold-side filters at a temperature of 1573?K (1300?°C). The proposed emitter enhances a naturally occurring rare earth transition using quality-factor matching, with a quarter-wave stack as a highly reflective back mirror, while suppressing parasitic losses via exponential chirping of a multilayer reflector transmitting only at short wavelengths. This allows the emissivity to approach the blackbody limit for wavelengths overlapping with the absorption peak of the rare-earth material, while effectively reducing the losses associated with undesirable long-wavelength emission. We obtain TPV efficiencies of 34% using this layered design, which only requires modest index contrast, making it particularly amenable to fabrication via a wide variety of techniques, including sputtering, spin-coating, and plasma-enhanced chemical vapor deposition.

Sakr, E. S.; Zhou, Z.; Bermel, P., E-mail: pbermel@purdue.edu [Birck Nanotechnology Center, School of Electrical and Computer Engineering, Purdue University, 1205 W. State St., West Lafayette, Indiana 47907 (United States)

2014-09-15T23:59:59.000Z

234

Rare Isotopes in Cosmic Explosions and Accelerators on Earth  

ScienceCinema (OSTI)

Rare isotopes are nature?s stepping stones to produce the heavy elements, and they are produced in large quantities in stellar explosions. Despite their fleeting existence, they shape the composition of the universe and the observable features of stellar explosions. The challenge for nuclear science is to produce and study the very same rare isotopes so as to understand the origin of the elements and a range of astronomical observations. I will review the progress that has been made to date in astronomy and nuclear physics, and the prospects of finally addressing many of the outstanding issues with the future Facility for Rare Isotope Beams (FRIB), which DOE will build at Michigan State University.

Hendrik Schatz

2010-01-08T23:59:59.000Z

235

Silicon metal-semiconductor-metal photodetector  

DOE Patents [OSTI]

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

236

Silicon metal-semiconductor-metal photodetector  

DOE Patents [OSTI]

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

237

The Rare Earth Peak : An Overlooked r-Process Diagnostic  

E-Print Network [OSTI]

The astrophysical site or sites responsible for the r-process of nucleosynthesis still remains an enigma. Since the rare earth region is formed in the latter stages of the r-process it provides a unique probe of the astrophysical conditions during which the r-process takes place. We use features of a successful rare earth region in the context of a high entropy r-process (S>100k_B) and discuss the types of astrophysical conditions that produce abundance patterns that best match meteoritic and observational data. Despite uncertainties in nuclear physics input, this method effectively constrains astrophysical conditions.

M. Mumpower; G. McLaughlin; R. Surman

2012-02-08T23:59:59.000Z

238

Process to remove rare earth from IFR electrolyte  

DOE Patents [OSTI]

The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner. 1 fig.

Ackerman, J.P.; Johnson, T.R.

1994-08-09T23:59:59.000Z

239

Process to remove rare earth from IFR electrolyte  

DOE Patents [OSTI]

The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

Ackerman, J.P.; Johnson, T.R.

1992-01-01T23:59:59.000Z

240

Process to remove rare earth from IFR electrolyte  

DOE Patents [OSTI]

The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

Ackerman, John P. (Downers Grove, IL); Johnson, Terry R. (Wheaton, IL)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Rare Earths Compounds DOI: 10.1002/ange.201002338  

E-Print Network [OSTI]

) characterized by covalent bonds between the transition metals (T) and the highly polarizable (monoatomic) carbon of the transition metals cause high negative charges on the complex carbometalate anions, which have to be balanced a special class of ternary and higher carbides containing complex anions n 1 ðTyCz�m� � � (n = 0, 1, 2, 3

Widom, Michael

242

PRACTICAL APPLICATION OF THE SINGLE-PARAMETER SUBCRITICAL MASS LIMIT FOR PLUTONIUM METAL  

SciTech Connect (OSTI)

According to ANS-8.1, operations with fissile materials can be performed safely by complying with any of the listed single-parameter subcritical limits. For metallic units, when interspersed moderators are present, the mass limits apply to a single piece having no concave surfaces. On a practical level, when has any operation with fissile metal involved a single piece and absolutely no moderating material, e.g., water, oil, plastic, etc.? This would be rare. This paper explores the application of the single-parameter plutonium metal mass limit for realistic operational environments.

MITCHELL, MARK VON [Los Alamos National Laboratory

2007-01-10T23:59:59.000Z

243

PHYTOEXTRACTION OF HEAVY METALS  

E-Print Network [OSTI]

) Type of phytoremediation Cost effective form of environmental remediation (Glass 1999) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al -using hyperaccumulator plant biomass to produce a bio-ore for commercial use -Li et al. look at using Ni

Blouin-Demers, Gabriel

244

Production of magnesium metal  

DOE Patents [OSTI]

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

2010-02-23T23:59:59.000Z

245

Molecular Photodynamics in Rare Gas Solids V. A. Apkarian*  

E-Print Network [OSTI]

Molecular Photodynamics in Rare Gas Solids V. A. Apkarian* Department of Chemistry, University Processes 1490 III. Sample Preparation and Morphology 1492 IV. Photon-Induced Dissociation 1493 V. Perfect I. Introduction A molecular level understanding of dynamics in condensed media is one of the current

Apkarian, V. Ara

246

Rare Isotope Beams for the 21st Century  

ScienceCinema (OSTI)

In a scientific keynote address on Friday, June 12 at Michigan State University (MSU) in East Lansing, James Symons, Director of Berkeley Labs Nuclear Science Division (NSD), discussed the exciting research prospects of the new Facility for Rare Isotope Beams (FRIB) to be built at MSUs National Superconducting Cyclotron Laboratory.

James Symons

2010-01-08T23:59:59.000Z

247

September 23, 1997 Rare Events in Stochastic Dynamical Systems and  

E-Print Network [OSTI]

September 23, 1997 Rare Events in Stochastic Dynamical Systems and Failures in Ultra­Reliable reliable is the system, the sharper is the approximation. In this model, we consider two types of failures that the distribution of a failure time can be approximated by an exponen­ tial law is not new in software reliability

248

Potential synergy: the thorium fuel cycle and rare earths processing  

SciTech Connect (OSTI)

The use of thorium in nuclear power programs has been evaluated on a recurring basis. A concern often raised is the lack of 'thorium infrastructure'; however, for at least a part of a potential thorium fuel cycle, this may less of a problem than previously thought. Thorium is frequently encountered in association with rare earth elements and, since the U.S. last systematically evaluated the large-scale use of thorium (the 1970's,) the use of rare earth elements has increased ten-fold to approximately 200,000 metric tons per year. Integration of thorium extraction with rare earth processing has been previously described and top-level estimates have been done on thorium resource availability; however, since ores and mining operations differ markedly, what is needed is process flowsheet analysis to determine whether a specific mining operation can feasibly produce thorium as a by-product. Also, the collocation of thorium with rare earths means that, even if a thorium product stream is not developed, its presence in mining waste streams needs to be addressed and there are previous instances where this has caused issues. This study analyzes several operational mines, estimates the mines' ability to produce a thorium by-product stream, and discusses some waste management implications of recovering thorium. (authors)

Ault, T.; Wymer, R.; Croff, A.; Krahn, S. [Vanderbilt University: 2301 Vanderbilt Place/PMB 351831, Nashville, TN 37235 (United States)

2013-07-01T23:59:59.000Z

249

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1992-01-01T23:59:59.000Z

250

Actinide metal processing  

DOE Patents [OSTI]

A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

1992-01-01T23:59:59.000Z

251

Actinide metal processing  

DOE Patents [OSTI]

A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

Sauer, N.N.; Watkin, J.G.

1992-03-24T23:59:59.000Z

252

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

253

Rules for understanding rare-earth magnetic compounds  

E-Print Network [OSTI]

. Using fragments based on structures of metal-rich lanthanide compounds, we have investigated molecular and low-dimensional extended structures, and have shown that open-d-shell clusters facilitate strong ferromagnetic coupling whereas closed...

Roy, Lindsay Elizabeth

2009-06-02T23:59:59.000Z

254

Functional Metal Phosphonates  

E-Print Network [OSTI]

functional groups. In some cases, these ligands undergo reactions during the solvothermal syntheses which can impart new chemical reactivity. Another method used to introduce functionality was to partially or completely substitute metal atoms within...

Perry, Houston Phillipp

2012-02-14T23:59:59.000Z

255

Production of magnesium metal  

DOE Patents [OSTI]

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

2012-04-10T23:59:59.000Z

256

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents [OSTI]

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

257

Metallic glass composition  

DOE Patents [OSTI]

A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

1986-01-01T23:59:59.000Z

258

Molten metal reactors  

DOE Patents [OSTI]

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

2013-11-05T23:59:59.000Z

259

Thermally tolerant multilayer metal membrane  

DOE Patents [OSTI]

A composite metal membrane including a first metal layer of a Group IVB or Group VB metal sandwiched between two layers of a Group VIIIB metal selected from the group consisting of palladium, platinum, nickel, rhodium, iridium, cobalt, and alloys thereof, and a non-continuous layer of a metal chalcogenide upon one layer of the Group VIIIB metal is disclosed together with a process for the recovery of hydrogen from a gaseous mixture using such a composite membrane and a process for forming such a composite metal membrane.

Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM)

2001-01-01T23:59:59.000Z

260

TOWARD AN ACCURATE MODEL OF METAL SORPTION IN SOILS  

E-Print Network [OSTI]

Radionuclide transport in soils and groundwaters is routinely evaluated in performance assessment (PA) using simplified conceptual models (e.g., KD method) to describe radionuclide sorption. However, the KD approach with linear and reversible sorption of metal cations is rarely observed in the field. Inaccuracies of this model are typically addressed by conservativeness in the use of the chemical partitioning parameters, and often result in failed transport predictions or in increased costs for the cleanup of a site. Realistic assessments of radionuclide transport over a wide range of environmental conditions can proceed only from accurate and mechanistic models of the metal sorption process. Our research has recently examined the sorption mechanisms and partition coefficients for Ba2+ (analog for 226Ra2+) onto soil minerals (iron oxides and clay phases) using a combination of isothermal sorption/desorption measurements, synchrotron spectroscopic analyses of metal sorbed substrates, and computer molecular modeling simulations. Research goals include 1) evaluation and quantification of the critical mechanisms and geochemical parameters that control the retardation of radionuclides on the sorbing phases in near-field soils, 2) use of atomistic computer simulations to predict radionuclide KD values based on the partitioning of the metal cations between the solution and mineral surface, and 3) identification of the general trends in metal plume length associated with field sites. Results should improve our ability to estimate radionuclide migration at contaminated sites.

All T. Cygan; Howard L. Anderson; Sara E. Arthur; Patrick V. Brady; Carlos F. Jove; Jian-jie Liang; Eric R. Lindgren; Malcolm D. Siegel; David M. Teter; Henry R. Westrich; Pengchu Zhang

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Higher order antibunching is not a rare phenomenon  

E-Print Network [OSTI]

Since the introduction of higher order nonclassical effects, higher order squeezing has been reported in a number of different physical systems but higher order antibunching is predicted only in three particular cases. In the present work, we have shown that the higher order antibunching is not a rare phenomenon rather it can be seen in many simple optical processes. To establish our claim, we have shown it in six wave mixing process, four wave mixing process and in second harmonic generation process.

Prakash Gupta; Pratap Narayan Pandey; Anirban Pathak

2005-08-08T23:59:59.000Z

262

Physics and Outlook for Rare, All-neutral Eta Decays  

SciTech Connect (OSTI)

The $\\eta$ meson provides a laboratory to study isospin violation and search for new flavor-conserving sources of C and CP violation with a sensitivity approaching $10^{-6}$ of the isospin-conserving strong amplitude. Some of the most interesting rare $\\eta$ decays are the neutral modes, yet the effective loss of photons from the relatively common decay $\\eta \\rightarrow 3\\pi^0 \\rightarrow 6\\gamma$ (33$\\%$) has largely limited the sensitivity for decays producing 3-5$\\gamma$'s. Particularly important relevant branches include the highly suppressed $\\eta \\rightarrow \\pi^0 2\\gamma \\rightarrow 4\\gamma$, which provides a rare window on testing models of $O(p^6)$ contributions in ChPTh, and $\\eta \\rightarrow 3\\gamma$ and $\\eta \\rightarrow 2\\pi^0 \\gamma \\rightarrow 5\\gamma$ which provide direct constraints on C violation in flavor-conserving processes. The substitution of lead tungstate in the forward calorimeter of the GluEx setup in Jefferson Lab's new Hall D would allow dramatically improved measurements. The main niche of this facility, which we call the JLab Eta Factory (JEF), would be $\\eta$ decay neutral modes. However, this could likely be expanded to rare $\\eta'(958)$ decays for low energy QCD studies as well as $\\eta$ decays involving muons for new physics searches.

Mack, David J. [JLAB

2014-06-01T23:59:59.000Z

263

Liquid metal thermal electric converter  

DOE Patents [OSTI]

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

264

Method for forming metal contacts  

DOE Patents [OSTI]

Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

2013-09-17T23:59:59.000Z

265

High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

266

RARE EARTHS1 (Data in metric tons of rare-earth oxide (REO) content, unless otherwise noted)  

E-Print Network [OSTI]

%; permanent magnets, 16%; petroleum refining catalysts, 12%; metallurgical additives and alloys, 9%; rare-earth products. Domestic ore production was valued at an estimated $28 million. The estimated value of refined, alloy 529 953 1,780 2,470 1,670 Cerium compounds 1,810 4,940 3,990 4,310 4,940 Mixed REOs 974 2,530 5

267

Statistics of amplitude and fluid velocity of large and rare waves in the ocean  

E-Print Network [OSTI]

The understanding of large and rare waves in the ocean is becoming more important as these rare events are turning into more common observances. In order to design a marine structure or vehicle to withstand such a potentially ...

Suh, Il Ho

2007-01-01T23:59:59.000Z

268

Rare-earth tantalates and niobates suitable for use as nanophosphors  

DOE Patents [OSTI]

A family of rare-earth Group 5 oxides, where the Group 5 oxide is a niobate or tantalate. The rare-earth Group 5 oxides can be doped with suitable emitter ions to form nanophosphors.

Nyman, May D; Rohwer, Lauren E.S& gt

2013-11-19T23:59:59.000Z

269

COLLISIONS OF HALOGEN (2P) AND RARE GAS (1S) ATOMS  

E-Print Network [OSTI]

involving 2p excited states of alkali atoms, with groundstate rare gas atoms (RG), though other systems have been2p ) AND RARE GAS (IS) ATOMS Christopher Hank Becker (Ph. D.

Becker, Christopher Hank

2011-01-01T23:59:59.000Z

270

E-Print Network 3.0 - anhydrous rare earth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rare earth Search Powered by Explorit Topic List Advanced Search Sample search results for: anhydrous rare earth Page: << < 1 2 3 4 5 > >> 1 An assessment of the amount and types...

271

E-Print Network 3.0 - alloyed rare earth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rare earth Search Powered by Explorit Topic List Advanced Search Sample search results for: alloyed rare earth Page: << < 1 2 3 4 5 > >> 1 the machinist mar 2007 agnesium is 36 per...

272

DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements...  

Broader source: Energy.gov (indexed) [DOE]

Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal Byproducts DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal...

273

E-Print Network 3.0 - aqueous rare earth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rare earth Search Powered by Explorit Topic List Advanced Search Sample search results for: aqueous rare earth Page: << < 1 2 3 4 5 > >> 1 EES 420 -Geochemistry Course Description...

274

E-Print Network 3.0 - aqueous rare-earth electrolyte Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rare-earth electrolyte Search Powered by Explorit Topic List Advanced Search Sample search results for: aqueous rare-earth electrolyte Page: << < 1 2 3 4 5 > >> 1 SUSTAINABILITY...

275

E-Print Network 3.0 - amorphous rare earth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rare earth Search Powered by Explorit Topic List Advanced Search Sample search results for: amorphous rare earth Page: << < 1 2 3 4 5 > >> 1 JOURNAL DE PHYSIQUE Colloque C8,...

276

Method for locating metallic nitride inclusions in metallic alloy ingots  

DOE Patents [OSTI]

A method of determining the location and history of metallic nitride and/or oxynitride inclusions in metallic melts. The method includes the steps of labeling metallic nitride and/or oxynitride inclusions by making a coreduced metallic-hafnium sponge from a mixture of hafnium chloride and the chloride of a metal, reducing the mixed chlorides with magnesium, nitriding the hafnium-labeled metallic-hafnium sponge, and seeding the sponge to be melted with hafnium-labeled nitride inclusions. The ingots are neutron activated and the hafnium is located by radiometric means. Hafnium possesses exactly the proper metallurgical and radiochemical properties for this use.

White, Jack C. (Albany, OR); Traut, Davis E. (Corvallis, OR); Oden, Laurance L. (Albany, OR); Schmitt, Roman A. (Corvallis, OR)

1992-01-01T23:59:59.000Z

277

190 IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 30, NO. 1, FEBRUARY 2002 Gap Closure in a Cold Metal Halide Lamp  

E-Print Network [OSTI]

lamp has been investigated using a two-dimensional, plasma transport model. Im- ages are presented- charge devices, lighting, plasma applications. METAL halide high-intensity-discharge (HID) lamps op- erate as high-pressure thermal arcs [1]. The cold fills of HID lamps are typically 50­100 torr of a rare

Kushner, Mark

278

Nitrided Metallic Bipolar Plates  

SciTech Connect (OSTI)

The objectives are: (1) Develop and optimize stainless steel alloys amenable to formation of a protective Cr-nitride surface by gas nitridation, at a sufficiently low cost to meet DOE targets and with sufficient ductility to permit manufacture by stamping. (2) Demonstrate capability of nitridation to yield high-quality stainless steel bipolar plates from thin stamped alloy foils (no significant stamped foil warping or embrittlement). (3) Demonstrate single-cell fuel cell performance of stamped and nitrided alloy foils equivalent to that of machined graphite plates of the same flow-field design ({approx}750-1,000 h, cyclic conditions, to include quantification of metal ion contamination of the membrane electrode assembly [MEA] and contact resistance increase attributable to the bipolar plates). (4) Demonstrate potential for adoption in automotive fuel cell stacks. Thin stamped metallic bipolar plates offer the potential for (1) significantly lower cost than currently-used machined graphite bipolar plates, (2) reduced weight/volume, and (3) better performance and amenability to high volume manufacture than developmental polymer/carbon fiber and graphite composite bipolar plates. However, most metals exhibit inadequate corrosion resistance in proton exchange membrane fuel cell (PEMFC) environments. This behavior leads to high electrical resistance due to the formation of surface oxides and/or contamination of the MEA by metallic ions, both of which can significantly degrade fuel cell performance. Metal nitrides offer electrical conductivities up to an order of magnitude greater than that of graphite and are highly corrosion resistant. Unfortunately, most conventional coating methods (for metal nitrides) are too expensive for PEMFC stack commercialization or tend to leave pinhole defects, which result in accelerated local corrosion and unacceptable performance.

Brady, Michael P [ORNL; Tortorelli, Peter F [ORNL; Pihl, Josh A [ORNL; Toops, Todd J [ORNL; More, Karren Leslie [ORNL; Meyer III, Harry M [ORNL; Vitek, John Michael [ORNL; Wang, Heli [National Renewable Energy Laboratory (NREL); Turner, John [National Renewable Energy Laboratory (NREL); Wilson, Mahlon [Los Alamos National Laboratory (LANL); Garzon, Fernando [Los Alamos National Laboratory (LANL); Rockward, Tommy [Los Alamos National Laboratory (LANL); Connors, Dan [GenCell Corp; Rakowski, Jim [Allegheny Ludlum; Gervasio, Don [Arizona State University

2008-01-01T23:59:59.000Z

279

Hard metal composition  

DOE Patents [OSTI]

A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

Sheinberg, H.

1983-07-26T23:59:59.000Z

280

Hard metal composition  

DOE Patents [OSTI]

A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

Sheinberg, Haskell (Los Alamos, NM)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Metal alloy identifier  

DOE Patents [OSTI]

To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

1987-01-01T23:59:59.000Z

282

Metallic coating of microspheres  

SciTech Connect (OSTI)

Extremely smooth, uniform metal coatings of micrometer thicknesses on microscopic glass spheres (microspheres) are often needed as targets for inertial confinement fusion (ICF) experiments. The first part of this paper reviews those methods used successfully to provide metal coated microspheres for ICF targets, including magnetron sputtering, electro- and electroless plating, and chemical vapor pyrolysis. The second part of this paper discusses some of the critical aspects of magnetron sputter coating of microspheres, including substrate requirements, the sticking of microspheres during coating (preventing a uniform coating), and the difficulties in growing the desired dense, smooth, uniform microstructure on continuously moving spherical substrates.

Meyer, S.F.

1980-08-15T23:59:59.000Z

283

Metal Mechanisms | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell Batteries & Fuel Cells In ThisMetal Mechanisms Metal

284

Formation Of The Rare Earth Peak: Gaining Insight Into Late-Time r-Process Dynamics  

E-Print Network [OSTI]

We study the formation and final structure of the rare earth peak ($A\\sim160$) of the $r$-process nucleosynthesis. The rare earth peak forms at late times in the $r$-process after neutron exhaustion (neutron-to-seed ratio unity or R=1) as matter decays back to stability. Since rare earth peak formation does not occur during \

Matthew Mumpower; Gail McLaughlin; Rebecca Surman

2011-09-16T23:59:59.000Z

285

Rare earth elements activate endocytosis in plant cells Lihong Wanga,b,1  

E-Print Network [OSTI]

Rare earth elements activate endocytosis in plant cells Lihong Wanga,b,1 , Jigang Lic,d,1 , Qing (sent for review May 15, 2014) It has long been observed that rare earth elements (REEs) regulate, such as rare earth elements (REEs), have been observed for a long time to be beneficial to plant growth (1, 2

Deng, Xing-Wang

286

Revisiting the rare earth elements in foraminiferal tests Brian A. Haley a,*, Gary P. Klinkhammer b  

E-Print Network [OSTI]

Revisiting the rare earth elements in foraminiferal tests Brian A. Haley a,*, Gary P. Klinkhammer b: E. Boyle Abstract Are the rare earth elements (REEs) in foraminifera a valuable proxy for use sediments. Over twenty years ago the rare earth elements (REEs) were recognized for having potential

Kurapov, Alexander

287

VISIBLE AND INFRARED RARE-EARTH ACTIVATED ELECTROLUMINESCENCE FROM ERBIUM DOPED GaN  

E-Print Network [OSTI]

. At the same time novel work is being conducted using rare earth elements as sources of light emission. Results. III-V semiconductors doped with rare-earth elements have also been used10VISIBLE AND INFRARED RARE-EARTH ACTIVATED ELECTROLUMINESCENCE FROM ERBIUM DOPED GaN M. Garter*, R

Steckl, Andrew J.

288

Rare earth elements in the sediments of Lake Baikal Lawrence M. Och a  

E-Print Network [OSTI]

Rare earth elements in the sediments of Lake Baikal Lawrence M. Och a , Beat Müller a, , Adrian Available online 3 April 2014 Editor: Carla M. Koretsky Keywords: Rare earth elements Cerium anomaly Lake to complex and cryptic redox cycles. The mobility of rare earth elements (REEs) is influenced

Wehrli, Bernhard

289

Constraints on Hadean zircon protoliths from oxygen isotopes, Ti-thermometry, and rare earth elements  

E-Print Network [OSTI]

, and analysis of zircon/melt partitioning of rare earth elements (REEs) provide mutually consistent lines, 3 tables. Keywords: Hadean; crust; ion microprobe; oxygen; zircon thermometry; rare earth elements oxygen isotopes, Ti-thermometry, and rare earth elements, Geochem. Geophys. Geosyst., 8, Q06014, doi:10

290

PHOSPHORIC ACID EXTRACTION AND RARE EARTH RECOVERY FROM APATITES OF THE BRAZILIAN PHOSPHATIC ORES  

E-Print Network [OSTI]

so as to precipitate the rare earth elements as a phosphate concentrate. The application, fertilizer industry, rare earth elements recovery, phosphate rock, hydrochloric acid route. 1. Introduction: impossibility to recover high commercial value by-products such as the rare earth elements, existence of severe

Paris-Sud XI, Université de

291

From the subtropics to the central equatorial Pacific Ocean: Neodymium isotopic composition and rare earth element  

E-Print Network [OSTI]

and rare earth element concentration variations Mélanie Grenier,1 Catherine Jeandel,1 François Lacan,1 compositions (eNd) and rare earth element (REE) concentrations were measured for filtered surface to deep composition and rare earth element concentration variations, J. Geophys. Res. Oceans, 118, 592­618, doi:10

Boyer, Edmond

292

Speciation of adsorbed yttrium and rare earth elements on oxide surfaces  

E-Print Network [OSTI]

Speciation of adsorbed yttrium and rare earth elements on oxide surfaces Wojciech Piasecki, Dimitri 10 June 2008 Abstract The distribution of yttrium and the rare earth elements (YREE) between natural investigate the applicability of the X-ray results to rare earth elements and to several oxides in addition

Sverjensky, Dimitri A.

293

Rare Earth Elements--End Use and Recyclability Scientific Investigations Report 20115094  

E-Print Network [OSTI]

Rare Earth Elements--End Use and Recyclability Scientific Investigations Report 2011­5094 U outside of China. Photograph by Dan Cordier, U.S. Geological Survey. #12;Rare Earth Elements--End Use materials contained within this report. Suggested citation: Goonan, T.G., 2011, Rare earth elements--End use

294

Growth and characterization of rare-earth monosulfides for cold cathode applications  

E-Print Network [OSTI]

of chalco- genides of the rare-earth elements.4,5 The possibility was analyzed theoretically basedGrowth and characterization of rare-earth monosulfides for cold cathode applications Y. Modukuru, J phonons at 261 284 and 100 92 cm 1 with LaS NdS , respectively. These rare-earth monosulfides offer

Boolchand, Punit

295

Source and mobility of Rare Earth Elements in a sedimentary aquifer system: Aquitaine basin (Southern France)  

E-Print Network [OSTI]

Source and mobility of Rare Earth Elements in a sedimentary aquifer system: Aquitaine basin Geological Survey Service, Bordeaux, France, e.malcuit@brgm.fr The study of rare earth elements (REEs such as rivers and lakes and groundwaters. Rare earth elements) are of great interest because of their unique

Paris-Sud XI, Université de

296

High field strength element/rare earth element fractionation during partial melting in the presence  

E-Print Network [OSTI]

High field strength element/rare earth element fractionation during partial melting in the presence the amount of fractionation between the two decreases. In contrast, the heavy rare earth element partition field strength element/rare earth element fractionation during partial melting in the presence of garnet

van Westrenen, Wim

297

Rare Earth Elements--Critical Resources for High Technology U.S. Department of the Interior  

E-Print Network [OSTI]

Rare Earth Elements--Critical Resources for High Technology U.S. Department of the Interior U H The rare earth elements (REE) form the largest chemically coherent group in the periodic table of hydrogen for a post-hydro- carbon economy). Some Applications of the Rare Earth Elements Many applications

298

Use of rare earth elements as external markers for mean retention time measurements in ruminants  

E-Print Network [OSTI]

Review Use of rare earth elements as external markers for mean retention time measurements -- The present review deals with the utilisation of rare earth (RE) elements as particulate markers for ruminant earth / retention time / feedstuff / methodology / ruminant Résumé -- Utilisation des terres rares comme

Paris-Sud XI, Université de

299

Hydrothermal transport and deposition of the rare earth elements by fluorine-bearing aqueous liquids  

E-Print Network [OSTI]

ARTICLE Hydrothermal transport and deposition of the rare earth elements by fluorine environmental concerns, have created a great demand for the rare earth elements (REE), and focused considerable Hydrothermal concentration of the rare earth elements (REE) to economic and potentially economic levels has

300

Wick for metal vapor laser  

DOE Patents [OSTI]

An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

Duncan, David B. (Livermore, CA)

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

PROTOLYSE TRYPSIQUE IN VITRO DE DIVERS ALIMENTS  

E-Print Network [OSTI]

PROT�OLYSE TRYPSIQUE IN VITRO DE DIVERS ALIMENTS Marie-Claire CAMUS, J.-C. LAPORTE C. SAUTIER Unité protéolyse pepsique (CAMUS et SAUTIER, 1972) avait montré des différences surtout pendant la phase initiale

Boyer, Edmond

302

Rare Decays And Exotic States With BaBar  

SciTech Connect (OSTI)

Results from the BABAR experiment are presented for searches for several rare FCNC B and D meson decays, including the modes B{sup 0} {yields} {ell}{sup +}{ell}{sup -} and D{sup 0} {yields} {ell}{sup +}{ell}{sup -}, B {yields} ({rho},{omega}){gamma} and B{sup +} {yields} (K,{pi}){sup +}{nu}{bar {nu}}. Limits on lepton flavor violation in neutrino-less {tau} decays are also discussed. Finally, results of BABAR searches for the strange pentaquark states {Theta}{sup +}(1540), {Xi}{sup --}(1860) and {Xi}{sup 0}(1860) are summarized.

Robertson, S.H.; /McGill U.

2006-08-28T23:59:59.000Z

303

Search for New Physics in Rare Top Decays  

E-Print Network [OSTI]

Top physics provides a fertile ground for new-physics searches. At present, most top observables appear to be in good agreement with the respective Standard Model predictions. However, in the case of decay modes that are suppressed in the Standard Model, new-physics contributions of comparable magnitude may exist and yet go unnoticed because their impact on the total decay width is small. Hence it is interesting to probe rare top decays. This analysis focuses on the decay $t \\to b \\bar b c$. Useful observables are identified and prospects for measuring new-physics parameters are examined.

Pratishruti Saha

2014-11-27T23:59:59.000Z

304

Summary of the CKM 2014 working group on rare decays  

E-Print Network [OSTI]

Rare flavour changing neutral current decays of strange, charm and beauty hadrons have been instrumental in building up a picture of flavour in the Standard Model. Increasingly precise measurements of these decays allow to search for deviations from predictions of the Standard Model that would be associated to contributions from new particles that might arise in extensions of the Standard Model. In this summary, an overview of recent experimental results and theoretical predictions is given. The new physics sensitivity and prospects for the different observables is also addressed.

Blake, Thomas; Straub, David M

2015-01-01T23:59:59.000Z

305

Summary of the CKM 2014 working group on rare decays  

E-Print Network [OSTI]

Rare flavour changing neutral current decays of strange, charm and beauty hadrons have been instrumental in building up a picture of flavour in the Standard Model. Increasingly precise measurements of these decays allow to search for deviations from predictions of the Standard Model that would be associated to contributions from new particles that might arise in extensions of the Standard Model. In this summary, an overview of recent experimental results and theoretical predictions is given. The new physics sensitivity and prospects for the different observables is also addressed.

Thomas Blake; Akimasa Ishikawa; David M. Straub

2015-01-20T23:59:59.000Z

306

US-Japan rare elements meeting | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomenthe House Committee on EnergyEnergyTheUnited States andUS-Japan rare earth

307

Jefferson Lab Laser Twinkles in Rare Color | Jefferson Lab  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfraredJefferson Lab Click onLaser Twinkles in Rare Color NEWPORT NEWS,

308

Serpentine metal gasket  

DOE Patents [OSTI]

A metallic seal or gasket for use in the joining of cryogenic fluid conduits, the seal or gasket having a generally planar and serpentine periphery defining a central aperture. According to a preferred embodiment, the periphery has at least two opposing elongated serpentine sides and two opposing arcuate ends joining the opposing elongated serpentine sides and is of a hexagonal cross-section.

Rothgeb, Timothy Moore (Norfolk, VA); Reece, Charles Edwin (Yorktown, VA)

2009-06-02T23:59:59.000Z

309

Ductile transplutonium metal alloys  

DOE Patents [OSTI]

Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as souces of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

Conner, W.V.

1981-10-09T23:59:59.000Z

310

Iron Isotope and Rare Earth Element Patterns of the Neoproterozoic Fulu Formation, South China: Implications for Late Proterozoic Ocean Chemistry  

E-Print Network [OSTI]

13 3.5. Rare Earth Element Analysis…………………………………………. ……15 4.21 b. 5.2. Rare Earth Element Patterns……………………………………………24 6.Piper, D. Z. (1974). Rare earth elements in the sedimentary

Goldbaum, Elizabeth

2014-01-01T23:59:59.000Z

311

Method of producing adherent metal oxide coatings on metallic surfaces  

DOE Patents [OSTI]

Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

Lane, Michael H. (Clifton Park, NY); Varrin, Jr., Robert D. (McLean, VA)

2001-01-01T23:59:59.000Z

312

Speed of Sound in metal Speed of Sound in metal  

E-Print Network [OSTI]

the metal rod and metal bar. 2. Acquire a metal bar or rod and measure its mass. Use the meter stick and measure and record the length in meters. Use the vernier calipers and measure the other dimensionBar Select the Smart Tool. Position the Smart tool so that the vertical line bisects the pulse. The (x

Yu, Jaehoon

313

LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells  

DOE Patents [OSTI]

An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

1999-03-30T23:59:59.000Z

314

Purification of alkali metal nitrates  

DOE Patents [OSTI]

A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Gregory, Kevin M. (Woodridge, IL)

1985-05-14T23:59:59.000Z

315

Coherent properties of single rare-earth spin qubits  

E-Print Network [OSTI]

Rare-earth-doped crystals are excellent hardware for quantum storage of optical information. Additional functionality of these materials is added by their waveguiding properties allowing for on-chip photonic networks. However, detection and coherent properties of rare-earth single-spin qubits have not been demonstrated so far. Here, we present experimental results on high-fidelity optical initialization, effcient coherent manipulation, and optical readout of a single electron spin of Ce$^{3+}$ ion in a YAG crystal. Under dynamic decoupling, spin coherence lifetime reaches $T_2$=2 ms and is almost limited by the measured spin-lattice relaxation time $T_1$=3.8 ms. Strong hyperfine coupling to aluminium nuclear spins suggests that cerium electron spins can be exploited as an interface between photons and long-lived nuclear spin memory. Combined with high brightness of Ce$^{3+}$ emission and a possibility of creating photonic circuits out of the host material, this makes cerium spins an interesting option for integrated quantum photonics.

P. Siyushev; K. Xia; R. Reuter; M. Jamali; N. Zhao; N. Yang; C. Duan; N. Kukharchyk; A. D. Wieck; R. Kolesov; J. Wrachtrup

2014-05-20T23:59:59.000Z

316

Sublattice Magnetic Relaxation in Rare Earth Iron Garnets  

SciTech Connect (OSTI)

The magnetic properties of rare earth garnets make them attractive materials for applications ranging from optical communications to magnetic refrigeration. The purpose of this research was to determine the AC magnetic properties of several rare earth garnets, in order to ascertain the contributions of various sublattices. Gd3Fe5O¬12, Gd3Ga5O12, Tb3Fe5O12, Tb3Ga5O12, and Y3Fe5O12 were synthesized by a solid state reaction of their oxides and verified by x-ray diffraction. Frequency-dependent AC susceptibility and DC magnetization were measured versus temperature (10 – 340 K). Field cooling had little effect on AC susceptibility, but large effect on DC magnetization, increasing magnetization at the lowest temperature and shifting the compensation point to lower temperatures. Data suggest that interaction of the two iron lattices results in the two frequency dependent magnetic relaxations in the iron garnets, which were fit using the Vogel-Fulcher and Arrhenius laws.

McCloy, John S.; Walsh, Brian

2013-07-08T23:59:59.000Z

317

Ab Initio Nuclear Structure and Reaction Calculations for Rare Isotopes  

SciTech Connect (OSTI)

We have developed a novel ab initio symmetry-adapted no-core shell model (SA-NCSM), which has opened the intermediate-mass region for ab initio investigations, thereby providing an opportunity for first-principle symmetry-guided applications to nuclear structure and reactions for nuclear isotopes from the lightest p-shell systems to intermediate-mass nuclei. This includes short-lived proton-rich nuclei on the path of X-ray burst nucleosynthesis and rare neutron-rich isotopes to be produced by the Facility for Rare Isotope Beams (FRIB). We have provided ab initio descriptions of high accuracy for low-lying (including collectivity-driven) states of isotopes of Li, He, Be, C, O, Ne, Mg, Al, and Si, and studied related strong- and weak-interaction driven reactions that are important, in astrophysics, for further understanding stellar evolution, X-ray bursts and triggering of s, p, and rp processes, and in applied physics, for electron and neutrino-nucleus scattering experiments as well as for fusion ignition at the National Ignition Facility (NIF).

Draayer, Jerry P [Louisiana State University

2014-09-28T23:59:59.000Z

318

Upgrading platform using alkali metals  

DOE Patents [OSTI]

A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

Gordon, John Howard

2014-09-09T23:59:59.000Z

319

Electroless metal plating of plastics  

DOE Patents [OSTI]

Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

Krause, Lawrence J. (Chicago, IL)

1986-01-01T23:59:59.000Z

320

Electroless metal plating of plastics  

DOE Patents [OSTI]

Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

Krause, L.J.

1982-09-20T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Electroless metal plating of plastics  

DOE Patents [OSTI]

Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

Krause, Lawrence J. (Chicago, IL)

1984-01-01T23:59:59.000Z

322

Methods of recovering alkali metals  

DOE Patents [OSTI]

Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

Krumhansl, James L; Rigali, Mark J

2014-03-04T23:59:59.000Z

323

Metals processing control by counting molten metal droplets  

DOE Patents [OSTI]

Apparatus and method for controlling metals processing (e.g., ESR) by melting a metal ingot and counting molten metal droplets during melting. An approximate amount of metal in each droplet is determined, and a melt rate is computed therefrom. Impedance of the melting circuit is monitored, such as by calculating by root mean square a voltage and current of the circuit and dividing the calculated current into the calculated voltage. Analysis of the impedance signal is performed to look for a trace characteristic of formation of a molten metal droplet, such as by examining skew rate, curvature, or a higher moment.

Schlienger, Eric (Albuquerque, NM); Robertson, Joanna M. (Safford, AZ); Melgaard, David (Albuquerque, NM); Shelmidine, Gregory J. (Tijeras, NM); Van Den Avyle, James A. (Corrales, NM)

2000-01-01T23:59:59.000Z

324

Inert electrode containing metal oxides, copper and noble metal  

DOE Patents [OSTI]

A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

2001-01-01T23:59:59.000Z

325

Inert electrode containing metal oxides, copper and noble metal  

DOE Patents [OSTI]

A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

2000-01-01T23:59:59.000Z

326

Fabrication of metallic glass structures  

DOE Patents [OSTI]

Amorphous metal powders or ribbons are fabricated into solid shapes of appreciable thickness by the application of compaction energy. The temperature regime wherein the amorphous metal deforms by viscous flow is measured. The metal powders or ribbons are compacted within the temperature regime.

Cline, C.F.

1983-10-20T23:59:59.000Z

327

Integrated decontamination process for metals  

DOE Patents [OSTI]

An integrated process for decontamination of metals, particularly metals that are used in the nuclear energy industry contaminated with radioactive material. The process combines the processes of electrorefining and melt refining to purify metals that can be decontaminated using either electrorefining or melt refining processes.

Snyder, Thomas S. (Oakmont, PA); Whitlow, Graham A. (Murrysville, PA)

1991-01-01T23:59:59.000Z

328

FLUIDIC: Metal Air Recharged  

ScienceCinema (OSTI)

Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

Friesen, Cody

2014-04-02T23:59:59.000Z

329

FLUIDIC: Metal Air Recharged  

SciTech Connect (OSTI)

Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

Friesen, Cody

2014-03-07T23:59:59.000Z

330

Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)  

E-Print Network [OSTI]

vapor deposition polycrystalline diamond ?lms. Diamonddoped (B- doped) polycrystalline diamond thin ?lms (MR?

Zeng, Li

2007-01-01T23:59:59.000Z

331

Microstructural investigations of rare-earth transition-metal-based magnetocaloric materials for near-room-temperature applications  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Careerlumens_placard-green.eps MoreWSRC-STI-2007-00250 Rev. 05 Oak09 U . SThe March 23,

332

Spray casting of metallic preforms  

DOE Patents [OSTI]

A metal alloy is melted in a crucible and ejected from the bottom of the crucible as a descending stream of molten metal. The descending stream is impacted with a plurality of primary inert gas jets surrounding the molten metal stream to produce a plume of atomized molten metal droplets. An inert gas is blown onto a lower portion of the plume with a plurality of auxiliary inert gas jets to deflect the plume into a more restricted pattern of high droplet density, thereby substantially eliminating unwanted overspray and resulting wasted material. The plume is projected onto a moving substrate to form a monolithic metallic product having generally parallel sides.

Flinn, John E. (Idaho Falls, ID); Burch, Joseph V. (Shelley, ID); Sears, James W. (Niskayuna, NY)

2000-01-01T23:59:59.000Z

333

THE COORDINATION CHEMISTRY OF METAL SURFACES  

E-Print Network [OSTI]

result 7 ' 30 u 31 in metal carbide cluster chemistry willin metal chemistry. Oxidation of the iron carbide cluster

Muetterties, Earl L.

2013-01-01T23:59:59.000Z

334

Hydrothermal alkali metal recovery process  

DOE Patents [OSTI]

In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

Wolfs, Denise Y. (Houston, TX); Clavenna, Le Roy R. (Baytown, TX); Eakman, James M. (Houston, TX); Kalina, Theodore (Morris Plains, NJ)

1980-01-01T23:59:59.000Z

335

Water supply and sludge metals  

SciTech Connect (OSTI)

Ultimate sludge disposal is one of the major tasks facing wastewater treatment facilities today. Where adequate farmland exists in proximity to the treatment facility and where sludge characteristics are suitable, land application is often the most economical method. In some cases, however, metal concentrations in the sludge either limit the site life or the application rate to the point where land application is not economical. When metals are above regulatory limits, land application may become impossible. The origin of the metals has largely been credited to industrial users and stormwater runoff and have, in fact, often represented significant sources of metals. Another potentially significant source of metals that has been frequently overlooked is the water supply system (including the distribution and home piping systems). Data from some treatment facilities suggest that the water supply system is the major source of metals and is the reason that sewage sludge metal levels are above allowable land application limits.

Brown, W.E. (Wright-Pierce Engineers, Topsham, ME (USA))

1988-04-01T23:59:59.000Z

336

Coated metal fiber coalescing cell  

SciTech Connect (OSTI)

A cell is described for coalescing oil droplets dispersed in a water emulsion including an elongated perforated tube core into which the emulsion is injected, layers of oleophilic plastic covered metal mat wound about the core through which the emulsion is forced to pass, the fibers of the metal mat being covered by oleophilic plastic such as vinyl, acrylic, polypropylene, polyethylene, polyvinyl chloride, the metal being in the form of layers of expanded metal or metal fibers, either aluminum or stainless steel. In manufacturing the cell a helix wound wire is formed around the cylindrical plastic coated metal to retain it in place and resist pressure drop of fluid flowing through the metal fibers. In addition, the preferred arrangement includes the use of an outer sleeve formed of a mat of fibrous material such as polyester fibers, acrylic fibers, modacrylic fibers and mixtures thereof.

Rutz, W.D.; Swain, R.J.

1980-12-23T23:59:59.000Z

337

Corrosion protective coating for metallic materials  

DOE Patents [OSTI]

Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds.

Buchheit, Rudolph G. (Albuquerque, NM); Martinez, Michael A. (Albuquerque, NM)

1998-01-01T23:59:59.000Z

338

Corrosion protective coating for metallic materials  

DOE Patents [OSTI]

Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides is disclosed. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds. 1 fig.

Buchheit, R.G.; Martinez, M.A.

1998-05-26T23:59:59.000Z

339

Detecting Rare Events in the Time-Domain  

SciTech Connect (OSTI)

One of the biggest challenges in current and future time-domain surveys is to extract the objects of interest from the immense data stream. There are two aspects to achieving this goal: detecting variable sources and classifying them. Difference imaging provides an elegant technique for identifying new transients or changes in source brightness. Much progress has been made in recent years toward refining the process. We discuss a selection of pitfalls that can afflict an automated difference imagine pipeline and describe some solutions. After identifying true astrophysical variables, we are faced with the challenge of classifying them. For rare events, such as supernovae and microlensing, this challenge is magnified because we must balance having selection criteria that select for the largest number of objects of interest against a high contamination rate. We discuss considerations and techniques for developing classification schemes.

Rest, A; Garg, A

2008-10-31T23:59:59.000Z

340

Coupled-channel optical model potential for rare earth nuclei  

E-Print Network [OSTI]

Inspired by the recent work by Dietrich et al., substantiating validity of the adiabatic assumption in coupled-channel calculations, we explore the possibility of generalizing a global spherical optical model potential (OMP) to make it usable in coupled-channel calculations on statically deformed nuclei. The generalization consists in adding the coupling of the ground state rotational band, deforming the potential by introducing appropriate quadrupole and hexadecupole deformation and correcting the OMP radius to preserve volume integral of the spherical OMP. We choose isotopes of three rare-earth elements (W, Ho, Gd), which are known to be nearly perfect rotors, to perform a consistent test of our conjecture on integrated cross sections as well as on angular distributions for elastic and inelastic neutron scattering. When doing this we employ the well-established Koning-Delaroche global spherical potential and experimentally determined deformations without any adjustments. We observe a dramatically improved agreement with experimental data compared to spherical optical model calculations. The effect of changing the OMP radius to preserve volume integral is moderate but visibly improves agreement at lower incident energies. We find that seven collective states need to be considered for the coupled-channel calculations to converge. Our results for total, elastic, inelastic, and capture cross sections, as well as elastic and inelastic angular distributions are in remarkable agreement with experimental data. This result confirms that the adiabatic assumption holds and can extend applicability of the global spherical OMP to rotational nuclei in the rare-earth region, essentially without any free parameter. Thus, quite reliable coupled-channel calculations can be performed on such nuclei even when the experimental data, and consequently a specific coupled-channel potential, are not available.

M. Herman; G. P. A. Nobre; A. Palumbo; F. S. Dietrich; D. Brown; S. Hoblit

2014-02-06T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

[Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted] Domestic Production and Use: Rare earths were mined by one U.S. company in 2013. Bastnasite, a rare-earth  

E-Print Network [OSTI]

to represent 0.12 percent of the rare-earth elements in the Mountain Pass bastnasite ore. The leading end uses Production and Use: Rare earths were mined by one U.S. company in 2013. Bastnasite, a rare-earth fluorocarbonate mineral, was mined as a primary product at Mountain Pass, CA. Domestic production of rare-earth

342

Combinatorial exploration of rare-earth-free permanent magnets: Magnetic and microstructural properties of Fe-Co-W thin films  

E-Print Network [OSTI]

at least one rare earth element such as Nd, Sm, Tb, or Pr.1­3 However, rare-earth elements are increasCombinatorial exploration of rare-earth-free permanent magnets: Magnetic and microstructural://apl.aip.org/about/rights_and_permissions #12;Combinatorial exploration of rare-earth-free permanent magnets: Magnetic and microstructural

Rubloff, Gary W.

343

Rare-Earth Surface Alloying: A New Phase for GdAu2 M. J. Verstraete,1,2  

E-Print Network [OSTI]

refrigeration, are made pos- sible by an unusual group of elements: the rare earths (REs). The rare earthsRare-Earth Surface Alloying: A New Phase for GdAu2 M. Corso,1 M. J. Verstraete,1,2 F. Schiller,1 M. Gadolinium is a borderline rare earth, which is naturally ferromagnetic but can easily switch to different

344

Methods for preparation of nanocrystalline rare earth phosphates for lighting applications  

SciTech Connect (OSTI)

Disclosed here are methods for the preparation of optionally activated nanocrystalline rare earth phosphates. The optionally activated nanocrystalline rare earth phosphates may be used as one or more of quantum-splitting phosphor, visible-light emitting phosphor, vacuum-UV absorbing phosphor, and UV-emitting phosphor. Also disclosed herein are discharge lamps comprising the optionally activated nanocrystalline rare earth phosphates provided by these methods.

Comanzo, Holly Ann; Manoharan, Mohan; Martins Loureiro, Sergio Paulo; Setlur, Anant Achyut; Srivastava, Alok Mani

2013-04-16T23:59:59.000Z

345

Rare earth focused ion beam implantation utilizing Er and Pr liquid alloy ion sources  

E-Print Network [OSTI]

Pr,10,11 Eu,12 Dy,13 Er,13­15 and Tm16 doped GaN. Rare earth elements were added during growthRare earth focused ion beam implantation utilizing Er and Pr liquid alloy ion sources L. C. Chao, B write implantation. © 1999 American Vacuum Society. S0734-211X 99 08306-7 I. INTRODUCTION Rare earth

Steckl, Andrew J.

346

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatusButlerTransportation From modelingTrending: Metal Oxo Bonds

347

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatusButlerTransportation From modelingTrending: Metal Oxo

348

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2TopoPortal Hydrogen and Fuel CellTrending: Metal

349

Comparison of the Bioavailability of Waste Laden Soils Using ''In Vivo'' ''In Vitro'' Analytical Methodology and Bioaccessibility of Radionuclides for Refinement of Exposure/Dose Estimates  

SciTech Connect (OSTI)

The bioavailability of soil contaminants can be measured using in vitro or in vivo techniques. Since there was no standard method for intercomparison among laboratories, we compared two techniques for bioavailability estimation: in vitro dissolution and in vivo rat feeding model for a NIST-traceable soil material. Bioaccessibility was measured using a sequential soil extraction in synthetic analogues of human saliva, gastric and intestinal fluids. Bioavailability was measured in Sprague Dawley rats by determining metal levels in the major organs and urine, feces, and blood. Bioaccessibility was found to be a good indicator of relative metal bioavailability. Results are presented from bioaccessible experiments with Cesium in contaminated DOE soils, and total alpha and beta bioaccessibility. The results indicate that the modified methodology for bioaccessibility can be used for specific radionuclide analysis.

P. J. Lioy; M. Gallo; P. Georgopoulos; R. Tate; B. Buckley

1999-09-15T23:59:59.000Z

350

E-Print Network 3.0 - acidic rare earths Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of acidic geothermal waters from the Taupo Volcanic Zone, New... Concentrations of rare earth elements (REE) in acidic thermal waters from the Taupo Volcanic Zone, New Zealand......

351

Homogeneous blue pattern: A rare presentation in an acral congenital melanocytic nevus  

E-Print Network [OSTI]

Malvehy J. Homogeneous blue pattern in an acral congenitalof a plantar combined blue nevus: a simulator of melanoma.Homogeneous blue pattern: A rare presentation in an acral

2010-01-01T23:59:59.000Z

352

Alternative High-Performance Motors with Non-Rare Earth Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Alternative High-Performance Motors with Non-Rare Earth Materials 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

353

Supported molten-metal catalysts  

DOE Patents [OSTI]

An entirely new class of catalysts called supported molten-metal catalysts, SMMC, which can replace some of the existing precious metal catalysts used in the production of fuels, commodity chemicals, and fine chemicals, as well as in combating pollution. SMMC are based on supporting ultra-thin films or micro-droplets of the relatively low-melting (<600.degree. C.), inexpensive, and abundant metals and semimetals from groups 1, 12, 13, 14, 15 and 16, of the periodic table, or their alloys and intermetallic compounds, on porous refractory supports, much like supported microcrystallites of the traditional solid metal catalysts. It thus provides orders of magnitude higher surface area than is obtainable in conventional reactors containing molten metals in pool form and also avoids corrosion. These have so far been the chief stumbling blocks in the application of molten metal catalysts.

Datta, Ravindra (Iowa City, IA); Singh, Ajeet (Iowa City, IA); Halasz, Istvan (Iowa City, IA); Serban, Manuela (Iowa City, IA)

2001-01-01T23:59:59.000Z

354

Metal to ceramic sealed joint  

DOE Patents [OSTI]

A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system.

Lasecki, John V. (Livonia, MI); Novak, Robert F. (Farmington Hills, MI); McBride, James R. (Ypsilanti, MI)

1991-01-01T23:59:59.000Z

355

Metal to ceramic sealed joint  

DOE Patents [OSTI]

A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system. 11 figures.

Lasecki, J.V.; Novak, R.F.; McBride, J.R.

1991-08-27T23:59:59.000Z

356

Method for preparing porous metal hydride compacts  

DOE Patents [OSTI]

A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

1980-01-21T23:59:59.000Z

357

Method for preparing porous metal hydride compacts  

DOE Patents [OSTI]

A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

Ron, Moshe (Haifa, IL); Gruen, Dieter M. (Downers Grove, IL); Mendelsohn, Marshall H. (Woodridge, IL); Sheft, Irving (Oak Park, IL)

1981-01-01T23:59:59.000Z

358

Metal-ceramic joint assembly  

DOE Patents [OSTI]

A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

Li, Jian (New Milford, CT)

2002-01-01T23:59:59.000Z

359

``Towards Strange Metallic Holography'  

SciTech Connect (OSTI)

We initiate a holographic model building approach to 'strange metallic' phenomenology. Our model couples a neutral Lifshitz-invariant quantum critical theory, dual to a bulk gravitational background, to a finite density of gapped probe charge carriers, dually described by D-branes. In the physical regime of temperature much lower than the charge density and gap, we exhibit anomalous scalings of the temperature and frequency dependent conductivity. Choosing the dynamical critical exponent z appropriately we can match the non-Fermi liquid scalings, such as linear resistivity, observed in strange metal regimes. As part of our investigation we outline three distinct string theory realizations of Lifshitz geometries: from F theory, from polarized branes, and from a gravitating charged Fermi gas. We also identify general features of renormalization group flow in Lifshitz theories, such as the appearance of relevant charge-charge interactions when z {ge} 2. We outline a program to extend this model building approach to other anomalous observables of interest such as the Hall conductivity.

Hartnoll, Sean A.; /Harvard U., Phys. Dept. /Santa Barbara, KITP /UC, Santa Barbara; Polchinski, Joseph; Silverstein, Eva; /Santa Barbara, KITP /UC, Santa Barbara; Tong, David; /Cambridge U., DAMTP /Santa Barbara, KITP /UC, Santa Barbara

2010-08-26T23:59:59.000Z

360

Magnetic metallic multilayers  

SciTech Connect (OSTI)

Utilizing self-consistent Hartree-Fock calculations, several aspects of multilayers and interfaces are explored: enhancement and reduction of the local magnetic moments, magnetic coupling at the interfaces, magnetic arrangements within each film and among non-neighboring films, global symmetry of the systems, frustration, orientation of the various moments with respect to an outside applied field, and magnetic-field induced transitions. Magnetoresistance of ferromagnetic-normal-metal multilayers is found by solving the Boltzmann equation. Results explain the giant negative magnetoresistance encountered in these systems when an initial antiparallel arrangement is changed into a parallel configuration by an external magnetic field. The calculation depends on (1) geometric parameters (thicknesses of layers), (2) intrinsic metal parameters (number of conduction electrons, magnetization, and effective masses in layers), (3) bulk sample properties (conductivity relaxation times), (4) interface scattering properties (diffuse scattering versus potential scattering at the interfaces, and (5) outer surface scattering properties (specular versus diffuse surface scattering). It is found that a large negative magnetoresistance requires considerable asymmetry in interface scattering for the two spin orientations. Features of the interfaces that may produce an asymmetrical spin-dependent scattering are studied: varying interfacial geometric random roughness with no lateral coherence, correlated (quasi-periodic) roughness, and varying chemical composition of the interfaces. The interplay between these aspects of the interfaces may enhance or suppress the magnetoresistance, depending on whether it increases or decreases the asymmetry in the spin-dependent scattering of the conduction electrons.

Hood, R.Q.

1994-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Clean Metal Casting  

SciTech Connect (OSTI)

The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

Makhlouf M. Makhlouf; Diran Apelian

2002-02-05T23:59:59.000Z

362

Metal deposition using seed layers  

DOE Patents [OSTI]

Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

2013-11-12T23:59:59.000Z

363

Field Deployment for In-situ Metal and Radionuclide Stabilization by Microbial Metabolites  

SciTech Connect (OSTI)

A novel biotechnology is reported here that was demonstrated at SRS that facilitates metal and actinide immobilization by incorporating the physiology and ecology of indigenous bacteria. This technology is based on our previous work with pyomelanin-producing bacteria isolated from SRS soils. Through tyrosine supplementation, overproduction of pyomelanin was achieved, which lead ultimately to metal and actinide immobilization, both in-vitro and in-situ. Pyomelanin is a recalcitrant microbial pigment and a humic type compound in the class of melanin pigments. Pyomelanin has electron shuttling and metal chelation capabilities and thus accelerates the bacterial reduction and/or immobilization of metals. Pyomelanin is produced outside the cell and either diffuses away or attaches to the cell surface. In either case, the reduced pyomelanin is capable of transferring electrons to metals as well as chelating metals. Because of its recalcitrance and redox cycling properties, pyomelanin molecules can be used over and over again for metal transformation. When produced in excess, pyomelanin produced by one bacterial species can be used by other species for metal reduction, thereby extending the utility of pyomelanin and further accelerating metal immobilization rates. Soils contaminated with Ni and U were the focus of this study in order to develop in-situ, metal bioimmobilization technologies. We have demonstrated pyomelanin production in soil from the Tims Branch area of SRS as a result of tyrosine amendments. These results were documented in laboratory soil column studies and field deployment studies. The amended soils demonstrated increased redox behavior and sequestration capacity of U and transition metals following pyomelanin production. Treatments incorporating tyrosine and lactate demonstrated the highest levels of pyomelanin production. In order to determine the potential use of this technology at other areas of SRS, pyomelanin producing bacteria were also quantified from metal contaminated soils at TNX and D areas of SRS. A bacterial culture collection from subsurface studies near P Area of SRS were also evaluated for pyomelanin production. Bacterial densities of pyomelanin producers were determined to be >10{sup 6} cells/g soil at TNX and D areas. In addition, approximately 25% of isolates from P area demonstrated pyomelanin production in the presence of tyrosine. Biogeochemical activity is an ongoing and dynamic process due, in part, to bacterial activity in the subsurface. Bacteria contribute significantly to biotransformation of metals and radionuclides. An understanding and application of the mechanisms of metal and radionuclide reduction offers tremendous potential for development into bioremedial processes and technologies. This report demonstrates the application of recent advances in bacterial physiology and soil ecology for future bioremediation activities involving metal and actinide immobilization.

Turick, C. E.; Knox, A. S.; Dixon, K. L.; Roseberry, R. J.; Kritzas, Y. G

2005-09-26T23:59:59.000Z

364

Evidence for the Rare Decay B+ to Ds+ pi0  

SciTech Connect (OSTI)

The authors have searched for the rare decay B{sup +} {yields} D{sub s}{sup +}{pi}{sup 0}. The analysis is based on a sample of 232 million {Upsilon}(4S) {yields} B{bar B} decays collected with the BABAR detector at the PEP-II e{sup +}e{sup -} storage ring. They find 19.6 signal events, corresponding to a significance of 4.7 {sigma}. The extracted signal yield including statistical and systematic uncertainties is 20.1{sub -6.0-1.5}{sup +6.8+0.4}, and they measure {Beta}(B{sup +} {yields} D{sub s}{sup +}{pi}{sup 0}) = (1.5{sub -0.4}{sup +0.5} {+-} 0.1 {+-} 0.2) x 10{sup -5}, where the first uncertainty is statistical, the second is systematic, and the last is due to the uncertainty on the D{sub s}{sup +} decay and its daughter decay branching fractions.

Aubert, B.

2006-11-17T23:59:59.000Z

365

In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Gasoline and Diesel Engine Vehicle Exhaust Particulate and Semi-Volatile Organic Compound Materials In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust Particulate...

366

Metal sulfide initiators for metal oxide sorbent regeneration  

DOE Patents [OSTI]

A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing gas. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream. 1 fig.

Turk, B.S.; Gupta, R.P.

1999-06-22T23:59:59.000Z

367

Band gap tuning in transition metal oxides by site-specific substitution  

DOE Patents [OSTI]

A transition metal oxide insulator composition having a tuned band gap includes a transition metal oxide having a perovskite or a perovskite-like crystalline structure. The transition metal oxide includes at least one first element selected form the group of Bi, Ca, Ba, Sr, Li, Na, Mg, K, Pb, and Pr; and at least one second element selected from the group of Ti, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Nb, Mo, Ru, Rh, Hf, Ta, W, Re, Os, Ir, and Pt. At least one correlated insulator is integrated into the crystalline structure, including REMO.sub.3, wherein RE is at least one Rare Earth element, and wherein M is at least one element selected from the group of Co, V, Cr, Ni, Mn, and Fe. The composition is characterized by a band gap of less of 4.5 eV.

Lee, Ho Nyung; Chisholm, Jr., Matthew F; Jellison, Jr., Gerald Earle; Singh, David J; Choi, Woo Seok

2013-12-24T23:59:59.000Z

368

Hydrothermal method of synthesis of rare-earth tantalates and niobates  

SciTech Connect (OSTI)

A hydrothermal method of synthesis of a family of rare-earth Group 5 oxides, where the Group 5 oxide is a niobate or tantalate. The rare-earth Group 5 oxides can be doped with suitable emitter ions to form nanophosphors.

Nyman, May D; Rohwer, Lauren E.S.; Martin, James E

2012-10-16T23:59:59.000Z

369

Grant Helps Make U.S. Rare Earth Magnets More Common  

Broader source: Energy.gov [DOE]

Sintered rare earth magnets - which are vital components in hybrid vehicle motors and wind turbine generators - are a $4 billion worldwide industry. Landisville, Pa.-based Electron Energy Corporation is hoping to bring a share of that market (and jobs) to the U.S. with their sintered rare earth magnet innovation.

370

The impact of vegetation on fractionation of rare earth elements (REE) during waterrock interaction  

E-Print Network [OSTI]

The impact of vegetation on fractionation of rare earth elements (REE) during water The fractionation of the rare earth elements (REE) in river water, as well as the immobilization of REE in the river earth elements (REE) principally originate from apatite dissolution during weathering. However, stream

Mailhes, Corinne

371

The Effect of Rare Earth Elements, Temperature and Rolling Speed on the Microstructure Evolution of Magnesium  

E-Print Network [OSTI]

The Effect of Rare Earth Elements, Temperature and Rolling Speed on the Microstructure Evolution ·Rare earth elements are the current focus of study due to: Ability to weaken the rolling texture of Aluminum Abundance: 8th most abundant element in Earth's crust (2% by mass) ·These properties can serve

Barthelat, Francois

372

Expanding hollow metal rings  

DOE Patents [OSTI]

A sealing device that may expand more planar dimensions due to internal thermal expansion of a filler material. The sealing material is of a composition such that when desired environment temperatures and internal actuating pressures are reached, the sealing materials undergoes a permanent deformation. For metallic compounds, this permanent deformation occurs when the material enters the plastic deformation phase. Polymers, and other materials, may be using a sealing mechanism depending on the temperatures and corrosivity of the use. Internal pressures are generated by either rapid thermal expansion or material phase change and may include either liquid or solid to gas phase change, or in the gaseous state with significant pressure generation in accordance with the gas laws. Sealing material thickness and material composition may be used to selectively control geometric expansion of the seal such that expansion is limited to a specific facing and or geometric plane.

Peacock, Harold B. (Evans, GA); Imrich, Kenneth J. (Grovetown, GA)

2009-03-17T23:59:59.000Z

373

Creating bulk nanocrystalline metal.  

SciTech Connect (OSTI)

Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties across the feature.

Fredenburg, D. Anthony (Georgia Institute of Technology, Atlanta, GA); Saldana, Christopher J. (Purdue University, West Lafayette, IN); Gill, David D.; Hall, Aaron Christopher; Roemer, Timothy John (Ktech Corporation, Albuquerque, NM); Vogler, Tracy John; Yang, Pin

2008-10-01T23:59:59.000Z

374

Metal recovery from porous materials  

DOE Patents [OSTI]

The present invention relates to recovery of metals. More specifically, the present invention relates to the recovery of plutonium and other metals from porous materials using microwaves. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

Sturcken, E.F.

1991-01-01T23:59:59.000Z

375

Nanostructured metal-polyaniline composites  

SciTech Connect (OSTI)

Metal-polyaniline (PANI) composites are provided together with a process of preparing such composites by an electrodeless process. The metal of the composite can have nanoscale structural features and the composites can be used in applications such as catalysis for hydrogenation reactions and for analytical detection methods employing SERS.

Wang, Hsing-Lin (Los Alamos, NM); Li, Wenguang (Elgin, IL); Bailey, James A. (Los Alamos, NM); Gao, Yuan (Brewer, ME)

2010-08-31T23:59:59.000Z

376

Metal Hydride Hydrogen Storage R and D | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Metal Hydride Hydrogen Storage R and D Metal Hydride Hydrogen Storage R and D DOE's research on complex metal hydrides targets the development of advanced metal hydride materials...

377

Electrorecycling of Critical and Value Metals from Mobile Electronics  

SciTech Connect (OSTI)

Mobile electronic devices such as smart phones and tablets are a significant source of valuable metals that should be recycled. Each year over a billion devices are sold world-wide and the average life is only a couple years. Value metals in phones are gold, palladium, silver, copper, cobalt and nickel. Devices now contain increasing amounts of rare earth elements (REE). In recent years the supply chain for REE has moved almost exclusively to China. They are contained in displays, speakers and vibrators within the devices. By US Department of Energy (DOE) classification, specific REEs (Nd, Dy, Eu, Tb and Y) are considered critical while others (Ce, La and Pr) are deemed near critical. Effective recycling schemes should include the recovery of these critical materials. By including more value materials in a recovery scheme, more value can be obtained by product diversification and less waste metals remains to be disposed of. REEs are mined as a group such that when specific elements become critical significantly more ore must be processed to capture the dilute but valuable critical elements. Targeted recycling of items containing the more of the less available critical materials could address their future criticality. This presentation will describe work in developing aqueous electrochemistry-based schemes for recycling metals from scrap mobile electronics. The electrorecycling process generates oxidizing agents at an anode while reducing dissolved metals at the cathode. E vs pH diagrams and metals dissolution experiments are used to assess effectiveness of various solution chemistries. Although several schemes were envisioned, a two stages process has been the focus of work: 1) initial dissolution of Cu, Sn, Ag and magnet materials using Fe+3 generated in acidic sulfate and 2) final dissolution of Pd and Au using Cl2 generated in an HCl solution. Experiments were performed using simulated metal mixtures. Both Cu and Ag were recovered at ~ 97% using Fe+3 while leaving Au and Ag intact. REE were extracted from the dissolved mixture using conventional methods. A discussion of future research directions will be discussed.

Tedd E. Lister; Peming Wang; Andre Anderko

2014-09-01T23:59:59.000Z

378

Scoping Inventory Calculations for the Rare Isotope Accelerator  

SciTech Connect (OSTI)

This document is a report on our activities in FY03 exploring nuclear safety and hazard analysis issues relevant to the Rare Isotope Accelerator (RIA). It is not clear whether DOE will classify the RIA as an accelerator facility subject to the accelerator-specific safety requirements of DOE Order 420.2A or as a nonreactor nuclear facility subject to the requirements of 10 CFR 830. The final outcome of this issue will have significant impact on the construction and operation of the facility and the quality assurance requirements for items or services that may affect nuclear safety. The resolution of this issue will be an important earlier decision for the RIA project team and will require early consultation with the appropriate DOE authorities. For nuclear facilities, facility hazard classification depends on the inventory of releasable radionuclides; therefore, some simplistic, scoping inventory calculations for some assumed targets and beams are done to estimate the hazard category of RIA if it is declared a nuclear facility. These calculations show that for the scenarios analyzed, RIA would produce sufficient quantities of radionuclides to be classified as a Category 3 nuclear facility. Over the lifetime of RIA operations, it may be possible to build up Category 2 quantities of {sup 227}Ac and {sup 228}Th. A storage building, separate from the driver, target, and experimental buildings, used to store and isolate accumulated targets and other hardware, can mitigate the potential impact on RIA. The more onerous requirements of Category 2 facilities would only be imposed on the storage facility and not on the rest of the RIA facilities. Some of the differences in a category 2 and category 3 facility are discussed in Appendix 1.

Ahle, L E; Boles, J L

2003-07-25T23:59:59.000Z

379

Durability of metals from archaeological objects, metal meteorites, and native metals  

SciTech Connect (OSTI)

Metal durability is an important consideration in the multi-barrier nuclear waste storage concept. This study summarizes the ancient metals, the environments, and factors which appear to have contributed to metal longevity. Archaeological and radiochemical dating suggest that human use of metals began in the period 6000 to 7000 BC. Gold is clearly the most durable, but many objects fashioned from silver, copper, bronze, iron, lead, and tin have survived for several thousand years. Dry environments, such as tombs, appear to be optimum for metal preservation, but some metals have survived in shipwrecks for over a thousand years. The metal meteorites are Fe-base alloys with 5 to 60 wt% Ni and minor amounts of Co, I, and S. Some meteoritic masses with ages estimated to be 5,000 to 20,000 years have weathered very little, while other masses from the same meteorites are in advanced stages of weathering. Native metals are natural metallic ores. Approximately five million tonnes were mined from native copper deposits in Michigan. Copper masses from the Michigan deposits were transported by the Pleistocene glaciers. Areas on the copper surfaces which appear to represent glacial abrasion show minimal corrosion. Dry cooling tower technology has demonstrated that in pollution-free moist environments, metals fare better at temperatures above than below the dewpoint. Thus, in moderate temperature regimes, elevated temperatures may be useful rather than detrimental for exposures of metal to air. In liquid environments, relatively complex radiolysis reactions can occur, particularly where multiple species are present. A dry environment largely obviates radiolysis effects.

Johnson, A.B. Jr.; Francis, B.

1980-01-01T23:59:59.000Z

380

LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells  

DOE Patents [OSTI]

An at least ternary metal alloy of the formula AB.sub.(Z-Y) X.sub.(Y) is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB.sub.5 alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

Bugga, Ratnakumar V. (Arcadia, CA); Fultz, Brent (Pasadena, CA); Bowman, Robert (La Mesa, CA); Surampudi, Subra Rao (Glendora, CA); Witham, Charles K. (Pasadena, CA); Hightower, Adrian (Pasadena, CA)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Method for preparing metal powder, device for preparing metal powder, method for processing spent nuclear fuel  

DOE Patents [OSTI]

A method for producing metal powder is provided the comprising supplying a molten bath containing a reducing agent, contacting a metal oxide with the molten bath for a time and at a temperature sufficient to reduce the metal in the metal oxide to elemental metal and produce free oxygen; and isolating the elemental metal from the molten bath.

Park, Jong-Hee (Clarendon Hills, IL)

2011-11-29T23:59:59.000Z

382

Cosmic metal production and the mean metallicity of the Universe  

E-Print Network [OSTI]

By means of detailed chemo-photometric models for elliptical, spiral and irregular galaxies, we evaluate the cosmic history of the production of chemical elements as well as the metal mass density of the present-day universe. We then calculate the mean metal abundances for galaxies of different morphological types, along with the average metallicity of galactic matter in the universe (stars, gas and intergalactic medium). For the average metallicity of galaxies in the local universe, we find Z_gal= 0.0175, i.e. close to the solar value. We find the main metal production in spheroids (ellipticals and bulges) to occur at very early times, implying an early peak in the metal production and a subsequent decrease. On the other hand, the metal production in spirals and irregulars is always increasing with time. We perform a self-consistent census of the baryons and metals in the local universe finding that, while the vast majority of the baryons lies outside galaxies in the inter-galactic medium (IGM), 52 % of the metals (with the exception of the Fe-peak elements) is locked up in stars and in the interstellar medium. We estimate indirectly the amount of baryons which resides in the IGM and we derive its mean Fe abundance, finding a value of X_Fe,IGM=0.05 X_Fe,sun. We believe that this estimate is uncertain by a factor of 2, owing to the normalization of the local luminosity function. This means that the Fe abundance of 0.3 solar inferred from X-ray observations of the hot intra-cluster medium (ICM) is higher than the average Fe abundance of the inter-galactic gas in the field.

F. Calura; F. Matteucci

2004-03-08T23:59:59.000Z

383

Metal-directed protein self-assembly  

E-Print Network [OSTI]

Metal-Directed Protein Self- Assembly. Acc. Chem. Res. 43,Metal-directed protein self-assembly. Acc. Chem. Res. 43,Metal- mediated self-assembly of protein superstructures:

Salgado. Eric N.

2010-01-01T23:59:59.000Z

384

Superconducting ``metals'' and ``insulators'' Smitha Vishveshwara  

E-Print Network [OSTI]

Superconducting ``metals'' and ``insulators'' Smitha Vishveshwara Department of Physics, University to the distinction between normal metals and insulators: the superconducting ``metal'' with delocalized qua- siparticle excitations and the superconducting ``insulator'' with localized quasiparticles. We describe

385

In vitro fracture toughness of human dentin V. Imbeni,1  

E-Print Network [OSTI]

In vitro fracture toughness of human dentin V. Imbeni,1 R. K. Nalla,1 C. Bosi,1 J. H. Kinney,2 R. O August 2002 Abstract: The in vitro fracture toughness of human dentin has been reported measured crit- ical stress intensity, Kc, for the onset of unstable fracture along an orientation

Ritchie, Robert

386

Method of coating metal surfaces to form protective metal coating thereon  

DOE Patents [OSTI]

A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

Krikorian, O.H.; Curtis, P.G.

1992-03-31T23:59:59.000Z

387

Alkaline and alkaline earth metal phosphate halides and phosphors  

DOE Patents [OSTI]

Compounds, phosphor materials and apparatus related to nacaphite family of materials are presented. Potassium and rubidium based nacaphite family compounds and phosphors designed by doping divalent rare earth elements in the sites of alkaline earth metals in the nacaphite material families are descried. An apparatus comprising the phosphors based on the nacaphite family materials are presented herein. The compounds presented is of formula A.sub.2B.sub.1-yR.sub.yPO.sub.4X where the elements A, B, R, X and suffix y are defined such that A is potassium, rubidium, or a combination of potassium and rubidium and B is calcium, strontium, barium, or a combination of any of calcium, strontium and barium. X is fluorine, chlorine, or a combination of fluorine and chlorine, R is europium, samarium, ytterbium, or a combination of any of europium, samarium, and ytterbium, and y ranges from 0 to about 0.1.

Lyons, Robert Joseph; Setlur, Anant Achyut; Cleaver, Robert John

2012-11-13T23:59:59.000Z

388

Non-stoichiometric AB5 alloys for metal hydride electrodes  

DOE Patents [OSTI]

The present invention provides a non-stoichiometric alloy comprising a composition having the formula AB.sub.5+X an atomic ratio wherein A is selected from the group consisting of the rare earth metals, yttrium, mischmetal, or a combination thereof; B is nickel and tin, or nickel and tin and at least a third element selected from the group consisting of the elements in group IVA of the periodic table, aluminum, manganese, iron, cobalt, copper, antimony or a combination thereof; X is greater than 0 and less than or equal to about 2.0; and wherein at least one substituted A site is occupied by at least one of the B elements. An electrode incorporating said alloy and an electrochemical cell incorporating said electrode are also described.

Reilly, James J. (Bellport, NY); Adzic, Gordana D. (Setauket, NY); Johnson, John R. (Calverton, NY); Vogt, Thomas (Cold Spring Harbor, NY); McBreen, James (Bellport, NY)

2001-01-01T23:59:59.000Z

389

Recommendation 221: Recommendation Regarding Recycling of Metals...  

Office of Environmental Management (EM)

221: Recommendation Regarding Recycling of Metals and Materials Recommendation 221: Recommendation Regarding Recycling of Metals and Materials In addition to the DOE making a final...

390

Metal-doped organic foam  

DOE Patents [OSTI]

Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

Rinde, James A. (Livermore, CA)

1982-01-01T23:59:59.000Z

391

Safety and core design of large liquid-metal cooled fast breeder reactors  

E-Print Network [OSTI]

Absorption Metal (Zr) Metal (Mo) Carbide Nitride Oxidef /? a k ? Metal (Zr) Metal (Mo) Carbide Nitride Oxide Table? a k ? Metal (Zr) Metal (Mo) Carbide Nitride Oxide CHAPTER

Qvist, Staffan Alexander

2013-01-01T23:59:59.000Z

392

Nanostructured Metal Oxide Anodes (Presentation)  

SciTech Connect (OSTI)

This summarizes NREL's FY09 battery materials research activity in developing metal oxide nanostructured anodes to enable high-energy, durable and affordable li-ion batteries for HEVs and PHEVs.

Dillon, A. C.; Riley, L. A.; Lee, S.-H.; Kim, Y.-H.; Ban, C.; Gillaspie, D. T.; Pesaran, A.

2009-05-01T23:59:59.000Z

393

Titanium metal: extraction to application  

SciTech Connect (OSTI)

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

Gambogi, Joseph (USGS, Reston, VA); Gerdemann, Stephen J.

2002-09-01T23:59:59.000Z

394

Adsorption of rare earth elements onto bacterial cell walls and its implication for REE sorption onto natural microbial mats  

E-Print Network [OSTI]

Adsorption of rare earth elements onto bacterial cell walls and its implication for REE sorption of rare earth elements (REE) onto the cell walls of Bacillus subtilis (a gram-positive bacterium of the rocks in the geological record. D 2005 Elsevier B.V. All rights reserved. Keywords: Rare earth elements

395

Effect of microstructure, grain size, and rare earth doping on the electrorheological performance of nanosized particle materials  

E-Print Network [OSTI]

and grain sizes were prepared by doping TiO2 or ZrO2 with rare earth (RE) elements, and by changingEffect of microstructure, grain size, and rare earth doping on the electrorheological performance-Hua Zhang,c Shu-Mei Chen,d Rui-Li Huange and Song Gaoa a State Key Laboratory of Rare Earth Materials

Gao, Song

396

Rare earth element concentrations and speciation in organic-rich blackwaters of the Great Dismal Swamp, Virginia, USA  

E-Print Network [OSTI]

Rare earth element concentrations and speciation in organic-rich blackwaters of the Great Dismal Concentrations of rare earth elements (REE), major inorganic solutes, and dissolved organic carbon (DOC) were reserved. Keywords: Rare earth elements; Speciation; Humic substances; Geochemistry; Great Dismal Swamp

Burdige, David

397

PII S0016-7037(02)00888-8 EXAFS study of rare-earth element coordination in calcite  

E-Print Network [OSTI]

PII S0016-7037(02)00888-8 EXAFS study of rare-earth element coordination in calcite E. J. ELZINGA,1-structure (EXAFS) spectroscopy is used to characterize the local coordination of selected rare-earth elements (Nd3 for the increased coordination for the larger rare-earth elements involves bidentate ligation from a CO3 group

Peale, Robert E.

398

Extension of lattice strain theory to mineral/mineral rare-earth element partitioning: An approach for assessing disequilibrium  

E-Print Network [OSTI]

Extension of lattice strain theory to mineral/mineral rare-earth element partitioning: An approach/melt parti- tion coefficients for rare-earth elements (REEs) in olivine and orthopyroxene to better 2006; accepted in revised form 20 September 2006 Abstract Olivine/melt and orthopyroxene/melt rare-earth

Lee, Cin-Ty Aeolus

399

7th Annual Colorado Rare Plant Symposium Conservation Efforts and Status Review of G1 Plants of Colorado  

E-Print Network [OSTI]

7th Annual Colorado Rare Plant Symposium Conservation Efforts and Status Review of G1 Plants of Colorado September 10, 2010; 9:00 am-4:00 pm UC Denver Auraria Campus Denver, Colorado Join members of the Colorado Rare Plant Technical Committee (RPTC) for the 7th Annual Colorado Rare Plant Symposium. The RPTC

400

Fabrication and In Vitro Deployment of a Laser-Activated Shape Memory Polymer Vascular Stent  

SciTech Connect (OSTI)

Vascular stents are small tubular scaffolds used in the treatment of arterial stenosis (narrowing of the vessel). Most vascular stents are metallic and are deployed either by balloon expansion or by self-expansion. A shape memory polymer (SMP) stent may enhance flexibility, compliance, and drug elution compared to its current metallic counterparts. The purpose of this study was to describe the fabrication of a laser-activated SMP stent and demonstrate photothermal expansion of the stent in an in vitro artery model. A novel SMP stent was fabricated from thermoplastic polyurethane. A solid SMP tube formed by dip coating a stainless steel pin was laser-etched to create the mesh pattern of the finished stent. The stent was crimped over a fiber-optic cylindrical light diffuser coupled to an infrared diode laser. Photothermal actuation of the stent was performed in a water-filled mock artery. At a physiological flow rate, the stent did not fully expand at the maximum laser power (8.6 W) due to convective cooling. However, under zero flow, simulating the technique of endovascular flow occlusion, complete laser actuation was achieved in the mock artery at a laser power of {approx}8 W. We have shown the design and fabrication of an SMP stent and a means of light delivery for photothermal actuation. Though further studies are required to optimize the device and assess thermal tissue damage, photothermal actuation of the SMP stent was demonstrated.

Baer, G M; Small IV, W; Wilson, T S; Benett, W J; Matthews, D L; Hartman, J; Maitland, D J

2007-04-25T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Synthesis, Computations and Characterizations of Low Dimensional Rare-Earth Compounds  

E-Print Network [OSTI]

Reduced rare-earth (Ln, lanthanide elements) compounds with low-dimensional Ln-Ln-bonded structures are promising candidates for magnetic materials because Ln-Ln-bonded molecules and solids have delocalized 5d electrons that make strong magnetic...

Chen, Chun-Yu

2014-04-28T23:59:59.000Z

402

Origin of enhanced magnetization in rare earth doped multiferroic bismuth ferrite  

SciTech Connect (OSTI)

We report structural and magnetic properties of rare earth doped Bi{sub 0.95}R{sub 0.05} FeO{sub 3} (R?=?Y, Ho, and Er) submicron particles. Rare earth doping enhances the magnetization and the magnetization shows an increasing trend with decreasing dopant ionic radii. In contrast to the x-ray diffraction pattern, we have seen a strong evidence for the presence of rare earth iron garnets R{sub 3}Fe{sub 5}O{sub 12} in magnetization measured as a function of temperature, in selected area electron diffraction, and in Raman measurements. Our results emphasised the role of secondary phases in the magnetic property of rare earth doped BiFeO{sub 3} compounds along with the structural distortion favoring spin canting by increase in Dzyaloshinskii-Moriya exchange energy.

Nayek, C.; Thirmal, Ch.; Murugavel, P., E-mail: muruga@iitm.ac.in [Department of Physics, Indian Institute of Technology Madras, Chennai 36 (India); Tamilselvan, A.; Balakumar, S. [National Centre for Nanoscience and Nanotechnology, University of Madras, Chennai 25 (India)

2014-02-21T23:59:59.000Z

403

Behavior Of Rare Earth Element In Geothermal Systems, A NewExploratio...  

Open Energy Info (EERE)

Behavior Of Rare Earth Element In Geothermal Systems, A New Exploration-Exploitation Tool Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Behavior Of...

404

Tricking Iron into Acting like a Rare-earth Element | The Ames...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tricking Iron into Acting like a Rare-earth Element By slipping iron between two nitrogen atoms in a lithium matrix, researchers are able to trick iron into having magnetic...

405

OXFORD BIBLIOGRAPHIES IN ECOLOGY "HEAVY METAL TOLERANCE"  

E-Print Network [OSTI]

cellular mechanisms affected by heavy metals is Bánfalvi 2011. Pollution by heavy metals is an important environmental problem, and sources that focus on heavy metal pollution often contain information about heavyOXFORD BIBLIOGRAPHIES IN ECOLOGY "HEAVY METAL TOLERANCE" By Nishanta Rajakaruna and Robert S. Boyd

Rajakaruna, Nishanta

406

Metal sponge for cryosorption pumping applications  

DOE Patents [OSTI]

A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area.

Myneni, Ganapati R. (Yorktown, VA); Kneisel, Peter (Williamsburg, VA)

1995-01-01T23:59:59.000Z

407

Metal oxide nanostructures with hierarchical morphology  

DOE Patents [OSTI]

The present invention relates generally to metal oxide materials with varied symmetrical nanostructure morphologies. In particular, the present invention provides metal oxide materials comprising one or more metallic oxides with three-dimensionally ordered nanostructural morphologies, including hierarchical morphologies. The present invention also provides methods for producing such metal oxide materials.

Ren, Zhifeng (Newton, MA); Lao, Jing Yu (Saline, MI); Banerjee, Debasish (Ann Arbor, MI)

2007-11-13T23:59:59.000Z

408

Metal sponge for cryosorption pumping applications  

DOE Patents [OSTI]

A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area. 4 figs.

Myneni, G.R.; Kneisel, P.

1995-12-26T23:59:59.000Z

409

Anaerobic microbial remobilization of coprecipitated metals  

DOE Patents [OSTI]

A process is provided for solubilizing coprecipitated metals. Metals in waste streams are concentrated by treatment with an iron oxide coprecipitating agent. The coprecipitated metals are solubilized by contacting the coprecipitate with a bacterial culture of a Clostridium species ATCC 53464. The remobilized metals can then be recovered and recycled. 4 figs.

Francis, A.J.; Dodge, C.J.

1994-10-11T23:59:59.000Z

410

Maskless laser writing of microscopic metallic interconnects  

DOE Patents [OSTI]

A method of forming a metal pattern on a substrate. The method includes depositing an insulative nitride film on a substrate and irradiating a laser beam onto the nitride film, thus decomposing the metal nitride into a metal constituent and a gaseous constituent, the metal constituent remaining in the nitride film as a conductive pattern.

Maya, Leon (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

411

Molten metal injector system and method  

DOE Patents [OSTI]

Disclosed is a molten metal injector system including a holder furnace, a casting mold supported above the holder furnace, and a molten metal injector supported from a bottom side of the mold. The holder furnace contains a supply of molten metal having a metal oxide film surface. The bottom side of the mold faces the holder furnace. The mold defines a mold cavity for receiving the molten metal from the holder furnace. The injector projects into the holder furnace and is in fluid communication with the mold cavity. The injector includes a piston positioned within a piston cavity defined by a cylinder for pumping the molten metal upward from the holder furnace and injecting the molten metal into the mold cavity under pressure. The piston and cylinder are at least partially submerged in the molten metal when the holder furnace contains the molten metal. The cylinder further includes a molten metal intake for receiving the molten metal into the piston cavity. The molten metal intake is located below the metal oxide film surface of the molten metal when the holder furnace contains the molten metal. A method of injecting molten metal into a mold cavity of a casting mold is also disclosed.

Meyer, Thomas N. (Murrysville, PA); Kinosz, Michael J. (Apollo, PA); Bigler, Nicolas (Morin Heights, CA); Arnaud, Guy (Riviere-Beaudette, CA)

2003-04-01T23:59:59.000Z

412

Horizontal electromagnetic casting of thin metal sheets  

DOE Patents [OSTI]

Thin metal sheets are cast by magnetically suspending molten metal deposited within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled to form a solid metal sheet. Magnetic flux increases as the molten metal sheet moves downward and decreases as the molten metal sheet moves upward to stabilize the sheet and maintain it in equilibrium as it is linearly displaced and solidified by cooling gases. A conducting shield is electrically coupled to the molten metal sheet by means of either metal sheet engaging rollers or brushes on the solidified metal, and by means of an electrode in the vessel containing the molten metal thereby providing a return path for the eddy currents induced in the metal sheet by the AC coil generated magnetic flux. Variation in the geometry of the conducting shield allows the magnetic flux between the metal sheet and the conducting shield to be varied and the thickness in surface quality of the metal sheet to be controlled. Side guards provide lateral containment for the molten metal sheet and stabilize and shape the magnetic field while a leader sheet having electromagnetic characteristics similar to those of the metal sheet is used to start the casting process and precedes the molten metal sheet through the magnet and forms a continuous sheet therewith. The magnet may be either U-shaped with a single racetrack coil or may be rectangular with a pair of facing bedstead coils.

Hull, John R. (Hinsdale, IL); Lari, Robert J. (Aurora, IL); Praeg, Walter F. (Palos Park, IL); Turner, Larry R. (Naperville, IL)

1987-01-01T23:59:59.000Z

413

Horizontal electromagnetic casting of thin metal sheets  

DOE Patents [OSTI]

Thin metal sheets are cast by magnetically suspending molten metal deposited within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled to form a solid metal sheet. Magnetic flux increases as the molten metal sheet moves downward and decreases as the molten metal sheet moves upward to stabilize the sheet and maintain it in equilibrium as it is linearly displaced and solidified by cooling gases. A conducting shield is electrically coupled to the molten metal sheet by means of either metal sheet engaging rollers or brushes on the solidified metal, and by means of an electrode in the vessel containing the molten metal thereby providing a return path for the eddy currents induced in the metal sheet by the AC coil generated magnetic flux. Variation in the geometry of the conducting shield allows the magnetic flux between the metal sheet and the conducting shield to be varied and the thickness in surface quality of the metal sheet to be controlled. Side guards provide lateral containment for the molten metal sheet and stabilize and shape the magnetic field while a leader sheet having electromagnetic characteristics similar to those of the metal sheet is used to start the casting process and precedes the molten metal sheet through the magnet and forms a continuous sheet therewith. The magnet may be either U-shaped with a single racetrack coil or may be rectangular with a pair of facing bedstead coils.

Hull, John R. (Hinsdale, IL); Lari, Robert J. (Aurora, IL); Praeg, Walter F. (Palos Park, IL); Turner, Larry R. (Naperville, IL)

1988-01-01T23:59:59.000Z

414

Dispersion enhanced metal/zeolite catalysts  

DOE Patents [OSTI]

Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

Sachtler, W.M.H.; Tzou, M.S.; Jiang, H.J.

1987-03-31T23:59:59.000Z

415

Metal salt catalysts for enhancing hydrogen spillover  

DOE Patents [OSTI]

A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

Yang, Ralph T; Wang, Yuhe

2013-04-23T23:59:59.000Z

416

Rare Earth Oxide Fluoride Nanoparticles And Hydrothermal Method For Forming Nanoparticles  

DOE Patents [OSTI]

A hydrothermal method for forming nanoparticles of a rare earth element, oxygen and fluorine has been discovered. Nanoparticles comprising a rare earth element, oxygen and fluorine are also described. These nanoparticles can exhibit excellent refractory properties as well as remarkable stability in hydrothermal conditions. The nanoparticles can exhibit excellent properties for numerous applications including fiber reinforcement of ceramic composites, catalyst supports, and corrosion resistant coatings for high-temperature aqueous solutions.

Fulton, John L. (Richland, WA); Hoffmann, Markus M. (Richland, WA)

2003-12-23T23:59:59.000Z

417

Rare earth oxide fluoride nanoparticles and hydrothermal method for forming nanoparticles  

DOE Patents [OSTI]

A hydrothermal method for forming nanoparticles of a rare earth element, oxygen and fluorine has been discovered. Nanoparticles comprising a rare earth element, oxygen and fluorine are also described. These nanoparticles can exhibit excellent refractory properties as well as remarkable stability in hydrothermal conditions. The nanoparticles can exhibit excellent properties for numerous applications including fiber reinforcement of ceramic composites, catalyst supports, and corrosion resistant coatings for high-temperature aqueous solutions.

Fulton, John L. (Richland, WA) [Richland, WA; Hoffmann, Markus M. (Richland, WA) [Richland, WA

2001-11-13T23:59:59.000Z

418

Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel  

E-Print Network [OSTI]

of adhesion between metals and transition metal carbides/nitrides based on Density Functional Theory(DFT)[14Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel the nature of metal/carbide bonding. Based on the surface and interfacial free energies, we find that both

Adams, James B

419

Bare Metal Stenting for Endovascular Exclusion of Aortic Arch Thrombi  

SciTech Connect (OSTI)

BackgroundAortic thrombi in the ascending aorta or aortic arch are rare but are associated with a relevant risk of major stroke or distal embolization. Although stent grafting is commonly used as a treatment option in the descending aorta, only a few case reports discuss stenting of the aortic arch for the treatment of a thrombus. The use of bare metal stents in this setting has not yet been described.MethodsWe report two cases of ascending and aortic arch thrombus that were treated by covering the thrombus with an uncovered stent. Both procedures were performed under local anesthesia via a femoral approach. A femoral cutdown was used in one case, and a total percutaneous insertion was possible in the second case.ResultsBoth procedures were successfully performed without any periprocedural complications. Postoperative recovery was uneventful. In both cases, no late complications or recurrent embolization occurred at midterm follow-up, and control CT angiography at 1 respectively 10 months revealed no stent migration, freely perfused supra-aortic branches, and no thrombus recurrence.ConclusionTreating symptomatic thrombi in the ascending aorta or aortic arch with a bare metal stent is feasible. This technique could constitute a minimally invasive alternative to a surgical intervention or complex endovascular therapy with fenestrated or branched stent grafts.

Mahnken, Andreas H., E-mail: mahnken@med.uni-marburg.de [University Hospital Giessen and Marburg, Philipps University of Marburg, Department of Diagnostic Radiology (Germany); Hoffman, Andras; Autschbach, Ruediger; Damberg, Anneke L. M., E-mail: anneke.damberg@rwth-aachen.de [University Hospital RWTH Aachen, Department of Thoracic, Cardiac and Vascular Surgery (Germany)

2013-08-01T23:59:59.000Z

420

Method of bonding metals to ceramics  

DOE Patents [OSTI]

A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

Maroni, V.A.

1991-04-23T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Coated metal articles and method of making  

DOE Patents [OSTI]

The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

Boller, Ernest R. (Van Buren Township, IN); Eubank, Lowell D. (Wilmington, DE)

2004-07-06T23:59:59.000Z

422

Reversible photodeposition and dissolution of metal ions  

DOE Patents [OSTI]

A cyclic photocatalytic process for treating waste water containing metal and organic contaminants. In one embodiment of the method, metal ions are photoreduced onto the photocatalyst and the metal concentrated by resolubilization in a smaller volume. In another embodiment of the method, contaminant organics are first oxidized, then metal ions removed by photoreductive deposition. The present invention allows the photocatalyst to be recycled until nearly complete removal of metal ions and organic contaminants is achieved.

Foster, Nancy S. (Boulder, CO); Koval, Carl A. (Golden, CO); Noble, Richard D. (Boulder, CO)

1994-01-01T23:59:59.000Z

423

Coated Metal Articles and Method of Making  

DOE Patents [OSTI]

The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

Boller, Ernest R.; Eubank, Lowell D.

2004-07-06T23:59:59.000Z

424

Synthesis and characterization of visible emission from rare-earth doped aluminum nitride, gallium nitride and gallium aluminum nitride powders and thin films  

E-Print Network [OSTI]

74 (19) 2821 (1999). F. H. Spedding, Rare-earth Elements, inby the use of rare- earth elements as color emitters inpowders activated with rare-earth elements Eu 3+ , Tb 3+ ,

Tao, Jonathan Huai-Tse

2010-01-01T23:59:59.000Z

425

INEL metal recycle radioactive scrap metal survey report  

SciTech Connect (OSTI)

DOE requested that inventory and characterization of radioactive scrap metal (RSM) be conducted across the DOE complex. Past studies have estimated the metal available from unsubstantiated sources. In meetings held in FY-1993, with seven DOE sites represented and several DOE-HQ personnel present, INEL personnel discovered that these numbers were not reliable and that large stockpiles did not exist. INEL proposed doing in-field measurements to ascertain the amount of RSM actually available. This information was necessary to determine the economic viability of recycling and to identify feed stock that could be used to produce containers for radioactive waste. This inventory measured the amount of RSM available at the selected DOE sites. Information gathered included radionuclide content and chemical form, general radiation field, alloy type, and mass of metal.

Funk, D.M.

1994-09-01T23:59:59.000Z

426

In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30F In Vitro Genotoxicity of Particulate...

427

Air Pollution with Heavy Metals and Radionuclides in Slovakia Studied by the Moss Biomonitoring Technique  

E-Print Network [OSTI]

Applying the moss biomonitoring technique to air pollution studies in Slovakia, heavy metals, rare-earth elements, actinides (U and Th) were determined in 86 moss samples from the European moss survey 2000 by means of epithermal neutron activation analysis at the IBR-2 reactor (Dubna). Such elements as In, Cu, Cd, Hg and Pb were determined by AAS in the Forest Research Institute, Zvolen (Slovakia). The results of measurement of the natural radionuclides ^{210}Pb, ^{7}Be, ^{137}Cs and ^{40}K in 11 samples of moss are also reported. A comparison with the results from moss surveys 1991 and 1995 revealed previously unknown tendencies of air pollution in the examined areas.

Florek, M; Mankovska, B; Oprea, K; Pavlov, S S; Steinnes, E; Sykora, I

2001-01-01T23:59:59.000Z

428

Bioavailability of Cadmium and Zin to Two Earthworm Species in High-metal Soils  

E-Print Network [OSTI]

bioavailability of rare earth elements in soils by chemicalavailability of rare earth elements in soil. Communicationsof bioavailability of light rare earth elements to wheat (

Liu, Ying

2012-01-01T23:59:59.000Z

429

Thin films of mixed metal compounds  

DOE Patents [OSTI]

Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

Mickelsen, R.A.; Chen, W.S.

1985-06-11T23:59:59.000Z

430

Metal volatilization and separation during incineration  

SciTech Connect (OSTI)

The US Environmental Protection Agency (US EPA) has reported that metals can account for almost all of the identified risks from a thermal treatment process. Fundamental research leading to better understanding of their behavior and improved control of their emissions is greatly needed. This paper reports studies on metal volatilization and separation during incineration. Metal volatilization studies were carried out in two separate experiments. In the first experiment, the dynamic volatilization characteristics of various metals during the combustion of metal-containing wood pellets were investigated in a high-temperature electric furnace. In addition to uncontrolled volatilization, the potential of employing chemical additives to bind metals and prevent them from volatilizing during combustion was also investigated. The second experiment involved the investigation of metal volatilization characteristics during the thermal treatment of metal-contaminated clay in a fluidized bed unit. The metal species tested in both experiments were compounds of lead and cadmium. Metal capture/separation studies were also carried out in two separate experiments. The first involved the use of sorbents in the combustion chamber to capture metals during the fluidized bed incineration of metal-containing wood pellets. The second experiments, however, employed sorbents to absorb metal vapors in a fluidized-bed waste-heat boiler. The objective of both the experiments is to characterize the metal absorption efficiency associated with the processes.

Ho, T.C.; Chu, H.W.; Hopper, J.R. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

1993-01-01T23:59:59.000Z

431

Photobiomolecular metallic particles and films  

DOE Patents [OSTI]

The method of the invention is based on the unique electron-carrying function of a photocatalytic unit such as the photosynthesis system I (PSI) reaction center of the protein-chlorophyll complex isolated from chloroplasts. The method employs a photo-biomolecular metal deposition technique for precisely controlled nucleation and growth of metallic clusters/particles, e.g., platinum, palladium, and their alloys, etc., as well as for thin-film formation above the surface of a solid substrate. The photochemically mediated technique offers numerous advantages over traditional deposition methods including quantitative atom deposition control, high energy efficiency, and mild operating condition requirements.

Hu, Zhong-Cheng

2003-05-06T23:59:59.000Z

432

Approximating Metal-Insulator Transitions  

E-Print Network [OSTI]

We consider quantum wave propagation in one-dimensional quasiperiodic lattices. We propose an iterative construction of quasiperiodic potentials from sequences of potentials with increasing spatial period. At each finite iteration step the eigenstates reflect the properties of the limiting quasiperiodic potential properties up to a controlled maximum system size. We then observe approximate metal-insulator transitions (MIT) at the finite iteration steps. We also report evidence on mobility edges which are at variance to the celebrated Aubry-Andre model. The dynamics near the MIT shows a critical slowing down of the ballistic group velocity in the metallic phase similar to the divergence of the localization length in the insulating phase.

C. Danieli; K. Rayanov; B. Pavlov; G. Martin; S. Flach

2014-05-06T23:59:59.000Z

433

Metallization and insulization during impact  

SciTech Connect (OSTI)

It is pointed out that the large strains produced by hypervelocity impacts can be expected to produce dramatic changes in the chemical bonding (electronic structures) of materials. This will change the mechanical behavior towards increased ductility when a semiconductor is compressed until it becomes metallic; and towards increased brittleness when a transition metal is expanded so as to localize its d-band electrons. Both isotropic compression (expansion) and shear strains can cause these transformations. Critical deformation criteria are given based on the observed cubic to tetragonal transformations in compressed semiconductors.

Gilman, J.J.

1992-10-01T23:59:59.000Z

434

Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers  

DOE Patents [OSTI]

The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

2001-01-01T23:59:59.000Z

435

Method for producing metal oxide nanoparticles  

DOE Patents [OSTI]

Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.

Phillips, Jonathan (Santa Fe, NM); Mendoza, Daniel (Santa Fe, NM); Chen, Chun-Ku (Albuquerque, NM)

2008-04-15T23:59:59.000Z

436

Synthesis and crystal structure of the isotypic rare earth thioborates Ce[BS{sub 3}], Pr[BS{sub 3}], and Nd[BS{sub 3}  

SciTech Connect (OSTI)

The orthothioborates Ce[BS{sub 3}], Pr[BS{sub 3}] and Nd[BS{sub 3}] were prepared from mixtures of the rare earth (RE) metals together with amorphous boron and sulfur summing up to the compositions CeB{sub 3}S{sub 6}, PrB{sub 5}S{sub 9} and NdB{sub 3}S{sub 6}. The following preparation routes were used: solid state reactions with maximum temperatures of 1323 K and high-pressure high-temperature syntheses at 1173 K and 3 GPa. Pr[BS{sub 3}] and Nd[BS{sub 3}] were also obtained from rare earth chlorides RECl{sub 3} and sodium thioborate Na{sub 2}B{sub 2}S{sub 5} by metathesis type reactions at maximum temperatures of 1073 K. The crystal structure of the title compounds was determined from X-ray powder diffraction data. The thioborates are isotypic and crystallize in the orthorhombic spacegroup Pna2{sub 1} (No. 33; Z=4; Ce: a=7.60738(6)A, b=6.01720(4)A, c=8.93016(6)A; Pr: a=7.56223(4)A, b=6.00876(2)A, c=8.89747(4)A; Nd: a=7.49180(3)A, b=6.00823(2)A, c=8.86197(3)A) . The crystal structures contain isolated [BS{sub 3}]{sup 3-} groups with boron in trigonal-planar coordination. The sulfur atoms form the vertices of undulated kagome nets, which are stacked along [100] according to the sequence ABAB. Within these nets every second triangle is occupied by boron and the large hexagons are centered by rare earth ions, which are surrounded by overall nine sulfur species. - Abstract: Graphical Abstract Legend (TOC Figure): Table of Contents Figure The isotypic orthothioborates Ce[BS{sub 3}], Pr[BS{sub 3}] and Nd[BS{sub 3}] were prepared using different preparation routes. The crystal structure of the title compounds was determined from X-ray powder diffraction data. The crystal structures contain isolated [BS{sub 3}]{sup 3-} groups with boron in trigonal-planar coordination. The sulfur atoms form the vertices of corrugated kagome nets (sketched with blue dotted lines), which are stacked along [100] according to the sequence ABAB. Within these nets every second triangle is occupied by boron and the large hexagons are centered by rare earth ions, which are surrounded by overall nine sulfur species.

Hunger, Jens; Borna, Marija [Max Planck Institute for Chemical Physics of Solids, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Kniep, Ruediger, E-mail: kniep@cpfs.mpg.d [Max Planck Institute for Chemical Physics of Solids, Noethnitzer Strasse 40, D-01187 Dresden (Germany)

2010-03-15T23:59:59.000Z

437

A Better Method for Evaluating Heavy Metal Water Pollution  

E-Print Network [OSTI]

efforts to control heavy metal pollution have focused oncomponent of heavy metal pollution, Dr. Hering found thatthat makes measuring heavy metal pollution a moving target.

Hering, Janet

2002-01-01T23:59:59.000Z

438

SciTech Connect: Metal-Organic Framework Templated Inorganic...  

Office of Scientific and Technical Information (OSTI)

Metal-Organic Framework Templated Inorganic Sorbents for Rapid and Efficient Extraction of Heavy Metals Citation Details In-Document Search Title: Metal-Organic Framework Templated...

439

Corrosion resistant metallic bipolar plate  

DOE Patents [OSTI]

A corrosion resistant, electrically conductive component such as a bipolar plate for a PEM fuel cell includes 20 55% Cr, balance base metal such as Ni, Fe, or Co, the component having thereon a substantially external, continuous layer of chromium nitride.

Brady, Michael P. (Oak Ridge, TN); Schneibel, Joachim H. (Knoxville, TN); Pint, Bruce A. (Knoxville, TN); Maziasz, Philip J. (Oak Ridge, TN)

2007-05-01T23:59:59.000Z

440

Heavy metals in Antarctic organisms  

SciTech Connect (OSTI)

To evaluate levels of essential (zinc and copper) and non-essential (mercury and cadmium) heavy metals, 34 species of organisms from different areas close to the Antarctic Peninsula were analysed. These included algae, filter-feeders, omnivorous invertebrates and vertebrates. Mercury was not detected, while cadmium was found in the majority of organisms analysed (detection limit was 0.05 ppm for both metals). The highest cadmium concentration was observed in the starfish Odontaster validus. Anthozoans, sipunculids and nudibranchs showed maximum levels of zinc, while the highest copper level was found in the gastropod Trophon brevispira. Mercury and cadmium levels in fishes were below the detection limit. Concentrations of essential and non-essential metals in birds were highest in liver followed by muscle and eggs. Cadmium and mercury levels in muscle of southern elephant seals were above the detection limit, whereas in Antarctic fur seals they were below it. The objective of the study was to gather baseline information for metals in Antarctic Ocean biota that may be needed to detect, measure and monitor future environmental changes. 46 refs., 7 figs., 8 tabs.

Moreno, J.E.A. de; Moreno, V.J. [Universidad Nacional de Mar del Plata (Argentina); Gerpe, M.S.; Vodopivez, C. [Instituto Antartico Argentino, Buenos Aires (Argentina)

1997-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Transition metal sulfide loaded catalyst  

DOE Patents [OSTI]

A zeolite based catalyst for activation and conversion of methane. A zeolite support includes a transition metal (Mo, Cr or W) sulfide disposed within the micropores of the zeolite. The catalyst allows activation and conversion of methane to C.sub.2 + hydrocarbons in a reducing atmosphere, thereby avoiding formation of oxides of carbon.

Maroni, Victor A. (Naperville, IL); Iton, Lennox E. (Downers Grove, IL); Pasterczyk, James W. (Westmont, IL); Winterer, Markus (Westmont, IL); Krause, Theodore R. (Lisle, IL)

1994-01-01T23:59:59.000Z

442

Transition metal sulfide loaded catalyst  

DOE Patents [OSTI]

A zeolite-based catalyst is described for activation and conversion of methane. A zeolite support includes a transition metal (Mo, Cr or W) sulfide disposed within the micropores of the zeolite. The catalyst allows activation and conversion of methane to C[sub 2]+ hydrocarbons in a reducing atmosphere, thereby avoiding formation of oxides of carbon.

Maroni, V.A.; Iton, L.E.; Pasterczyk, J.W.; Winterer, M.; Krause, T.R.

1994-04-26T23:59:59.000Z

443

Semiconductor sensor for optically measuring polarization rotation of optical wavefronts using rare earth iron garnets  

DOE Patents [OSTI]

Described are the design of a rare earth iron garnet sensor element, optical methods of interrogating the sensor element, methods of coupling the optical sensor element to a waveguide, and an optical and electrical processing system for monitoring the polarization rotation of a linearly polarized wavefront undergoing external modulation due to magnetic field or electrical current fluctuation. The sensor element uses the Faraday effect, an intrinsic property of certain rare-earth iron garnet materials, to rotate the polarization state of light in the presence of a magnetic field. The sensor element may be coated with a thin-film mirror to effectively double the optical path length, providing twice the sensitivity for a given field strength or temperature change. A semiconductor sensor system using a rare earth iron garnet sensor element is described.

Duncan, Paul G. (8544 Electric Ave., Vienna, VA 22182)

2002-01-01T23:59:59.000Z

444

The effect of rare earth elements on the texture and formability of asymmetrically rolled magnesium sheet  

SciTech Connect (OSTI)

The lack of formability is a serious issue when considering magnesium alloys for various applications. Standard symmetric rolling introduces a strong basal texture that decreases the formability; however, asymmetric rolling has been put forward as a possible route to produce sheet with weaker texture and greater ductility. It has also been shown in recent work that weaker textures can be produced through the addition of rare earth elements to magnesium alloys. Therefore, this study has been carried out to investigate the effect of rare earth additions on the texture changes during asymmetric rolling. Two alloys have been used, AZ31B and ZEK100. The effect that the rare earth additions have on the texture of asymmetrically rolled sheet and the subsequent changes in formability will be discussed.

Alderman, Dr. Martyn [Magnesium Elektron North America; Cavin, Odis Burl [ORNL; Davis, Dr. Bruce [Magnesium Elektron North America; Muralidharan, Govindarajan [ORNL; Muth, Thomas R [ORNL; Peter, William H [ORNL; Randman, David [Magnesium Elektron North America; Watkins, Thomas R [ORNL

2011-01-01T23:59:59.000Z

445

Method of forming magnetostrictive rods from rare earth-iron alloys  

DOE Patents [OSTI]

Rods of magnetostrictive alloys of iron with rare earth elements are formed by flowing a body of rare earth-iron alloy in a crucible enclosed in a chamber maintained under an inert gas atmosphere, forcing such molten rare-earth-iron alloy into a hollow mold tube of refractory material positioned with its lower end portion within the molten body by means of a pressure differential between the chamber and mold tube and maintaining a portion of the molten alloy in the crucible extending to a level above the lower end of the mold tube so that solid particles of higher melting impurities present in the alloy collect at the surface of the molten body and remain within the crucible as the rod is formed in the mold tube. 5 figs.

McMasters, O.D.

1986-09-02T23:59:59.000Z

446

Method of forming magnetostrictive rods from rare earth-iron alloys  

DOE Patents [OSTI]

Rods of magnetrostructive alloys of iron with rare earth elements are formed by flowing a body of rare earth-iron alloy in a crucible enclosed in a chamber maintained under an inert gas atmosphere, forcing such molten rare-earth-iron alloy into a hollow mold tube of refractory material positioned with its lower end portion within the molten body by means of a pressure differential between the chamber and mold tube and maintaining a portion of the molten alloy in the crucible extending to a level above the lower end of the mold tube so that solid particles of higher melting impurities present in the alloy collect at the surface of the molten body and remain within the crucible as the rod is formed in the mold tube.

McMasters, O. Dale (Ames, IA)

1986-09-02T23:59:59.000Z

447

Reduced order prediction of rare events in unidirectional nonlinear water waves  

E-Print Network [OSTI]

We consider the problem of short-term prediction of rare, extreme water waves in unidirectional fields, a critical topic for ocean structures and naval operations. One possible mechanism for the occurrence of such rare, unusually-intense waves is nonlinear wave focusing. Recent results have demonstrated that random localizations of energy, induced by the dispersive mixing of different harmonics, can grow significantly due to localized nonlinear focusing. Here we show how the interplay between i) statistical properties captured through linear information such as the waves power spectrum and ii) nonlinear dynamical properties of focusing localized wave groups defines a critical length scale associated with the formation of extreme events. The energy that is locally concentrated over this length scale acts as the "trigger" of nonlinear focusing for wave groups and the formation of subsequent rare events. We use this property to develop inexpensive, short-term predictors of large water waves. Specifically, we sho...

Cousins, Will

2015-01-01T23:59:59.000Z

448

Synthesis and Characterization of Porous Metal Phosphonates  

E-Print Network [OSTI]

metal phosphonates by investigating both the role of water and template molecules in the solvothermal synthesis. The role of water in solvothermal reactions was found to have a profound influence on the structure of monovalent metal phosphonates...

Kinnibrugh, Tiffany Lewis

2013-07-26T23:59:59.000Z

449

NANO - "Green" metal oxides ... | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

"Green" metal oxides ... Water and nano-sized particles isolated from trees, plants and algae are the ingredients of a new recipe for low-cost metal oxides that are widely used in...

450

Aspects of the mechanics of metallic glasses  

E-Print Network [OSTI]

Metallic glasses are amorphous materials that possess unique mechanical properties, such as high tensile strengths and good fracture toughnesses. Also, since they are amorphous, metallic glasses exhibit a glass transition, ...

Henann, David Lee

2011-01-01T23:59:59.000Z

451

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Corrosion of Oil Shale Retort Component Materials," LBL-

Bellman Jr., R.

2012-01-01T23:59:59.000Z

452

Gas adsorption on metal-organic frameworks  

DOE Patents [OSTI]

The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.

Willis, Richard R. (Cary, IL); Low, John J. (Schaumburg, IL), Faheem, Syed A. (Huntley, IL); Benin, Annabelle I. (Oak Forest, IL); Snurr, Randall Q. (Evanston, IL); Yazaydin, Ahmet Ozgur (Evanston, IL)

2012-07-24T23:59:59.000Z

453

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Elevated Temperature Corrosion of Oil Shale Retort Component

Bellman Jr., R.

2012-01-01T23:59:59.000Z

454

Separation of rare gases and chiral molecules by selective binding in porous organic cages  

SciTech Connect (OSTI)

Abstract: The rare gases krypton, xenon, and radon pose both an economic opportunity and a potential environmental hazard. Xenon is used in commercial lighting, medical imaging, and anesthesia, and can sell for $5,000 per kilogram. Radon, by contrast, Is naturally radioactive and the second largest cause of lung cancer, and radioactive xenon, 133Xe, was a major pollutant released In the Fukushima Daiichi Nuclear Power Plant disaster. We describe an organic cage molecule that can capture xenon and radon with unprecedented selectivity, suggesting new technologies for environmental monitoring, removal of pollutants, or the recovery of rare, valuable elements from air.

Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.; Holden, Daniel; Jelfs, Kim E.; Hasell, Tom; Little, Marc A.; Kewley, Adam; Briggs, Michael E.; Stephenson, Andrew; Thomas, K. M.; Armstrong, Jayne A.; Bell, Jon; Busto, Jose; Noel, Raymond; Liu, Jian; Strachan, Denis M.; Thallapally, Praveen K.; Cooper, Andrew I.

2014-10-31T23:59:59.000Z

455

Interfacing Superconducting Qubits and Telecom Photons via a Rare-Earth Doped Crystal  

E-Print Network [OSTI]

We propose a scheme to couple short single photon pulses to superconducting qubits. An optical photon is first absorbed into an inhomogeneously broadened rare-earth doped crystal using controlled reversible inhomogeneous broadening. The optical excitation is then mapped into a spin state using a series of $\\pi$-pulses and subsequently transferred to a superconducting qubit via a microwave cavity. To overcome the intrinsic and engineered inhomogeneous broadening of the optical and spin transitions in rare earth doped crystals, we make use of a special transfer protocol using staggered $\\pi$-pulses. We predict total transfer efficiencies on the order of 90%.

Christopher O'Brien; Nikolai Lauk; Susanne Blum; Giovanna Morigi; Michael Fleischhauer

2014-07-25T23:59:59.000Z

456

A programme for electron-impact broadening parameter calculations of ionized rare-earth element lines  

E-Print Network [OSTI]

In order to provide atomic data needed for astrophysical investigations, a set of electron-impact broadening parameters for ionized rare-earth element lines should be calculated. We are going to calculate the electron-impact broadening parameters for more than 50 transitions of ionized rare-earth elements. Taking into account that the spectra of these elements are very complex, for calculation we can use the modified semiempirical approach - MSE or simplified MSE. Also, we can estimate these parameters on the basis of regularities and systematic trends.

L. C. Popovic; M. S. Dimitrijevic

1998-05-15T23:59:59.000Z

457

Spectroscopic studies of metal growth on oxides  

E-Print Network [OSTI]

: Chemistry SPECTROSCOPIC STUDIES OF METAL GROWTH ON OXIDES A Thesis by KAI LUO Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style a d content by: avid W. Goodman.... , Jilin University, P. R. China Chair of Advisory Committee: Dr, David W. Goodman Metal/oxide chemistry and metal cluster growth on oxides are fundamental to our understanding of the catalytic activity and selectivity of metal catalysts, thus...

Luo, Kai

2000-01-01T23:59:59.000Z

458

Preparation of metal-triazolate frameworks  

DOE Patents [OSTI]

The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.

Yaghi, Omar M; Uribe-Romo, Fernando J; Gandara-Barragan, Felipe; Britt, David K

2014-10-07T23:59:59.000Z

459

Sintering and ripening resistant noble metal nanostructures  

DOE Patents [OSTI]

Durable porous metal nanostructures comprising thin metal nanosheets that are metastable under some conditions that commonly produce rapid reduction in surface area due to sintering and/or Ostwald ripening. The invention further comprises the method for making such durable porous metal nanostructures. Durable, high-surface area nanostructures result from the formation of persistent durable holes or pores in metal nanosheets formed from dendritic nanosheets.

van Swol, Frank B; Song, Yujiang; Shelnutt, John A; Miller, James E; Challa, Sivakumar R

2013-09-24T23:59:59.000Z

460

Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings  

SciTech Connect (OSTI)

Amorphous metal and ceramic thermal spray coatings have been developed that can be used to enhance the corrosion resistance of containers for the transportation, aging and disposal of spent nuclear fuel and high-level radioactive wastes. Iron-based amorphous metal formulations with chromium, molybdenum and tungsten have shown the corrosion resistance believed to be necessary for such applications. Rare earth additions enable very low critical cooling rates to be achieved. The boron content of these materials, and their stability at high neutron doses, enable them to serve as high efficiency neutron absorbers for criticality control. Ceramic coatings may provide even greater corrosion resistance for container applications, though the boron-containing amorphous metals are still favored for criticality control applications. These amorphous metal and ceramic materials have been produced as gas atomized powders and applied as near full density, non-porous coatings with the high-velocity oxy-fuel process. This paper summarizes the performance of these coatings as corrosion-resistant barriers, and as neutron absorbers. Relevant corrosion models are also discussed, as well as a cost model to quantify the economic benefits possible with these new materials.

Blink, J; Choi, J; Farmer, J

2007-07-09T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Time-Resolved XAFS Spectroscopic Studies of B-H and N-H Oxidative Addition to Transition Metal Catalysts Relevant to Hydrogen Storage  

SciTech Connect (OSTI)

Successful catalytic dehydrogenation of aminoborane, H3NBH3, prompted questions as to the potential role of N-H oxidative addition in the mechanisms of these processes. N-H oxidative addition reactions are rare, and in all cases appear to involve initial dative bonding to the metal by the amine lone pairs followed by transfer of a proton to the basic metal. Aminoborane and its trimethylborane derivative block this mechanism and, in principle, should permit authentic N-H oxidative attrition to occur. Extensive experimental work failed to confirm this hypothesis. In all cases either B-H complexation or oxidative addition of solvent C-H bonds dominate the chemistry.

Bitterwolf, Thomas E. [University of Idaho

2014-12-09T23:59:59.000Z

462

Liquid phase epitaxial growth of InGaAs on InP using rare-earth-treated and Paul R. Bergerb)  

E-Print Network [OSTI]

in a graphite boat. The rare-earth elements studied were Yb, Gd and Er which act as gettering agents measurements reveal no measurable incorporation of rare-earth elements into the grown epilayers. DLTS the rare earth elements or impurities from within the rare-earth elements. Subsequent glow discharge mass

463

13.21 Geochemistry of the Rare-Earth Element, Nb, Ta, Hf, and Zr Deposits RL Linnen, University of Western Ontario, London, ON, Canada  

E-Print Network [OSTI]

13.21 Geochemistry of the Rare-Earth Element, Nb, Ta, Hf, and Zr Deposits RL Linnen, University to Y, the rare- earth elements (REE, La to Lu), Zr, Hf, Nb, and Ta. The rare elements, Canada ã 2014 Elsevier Ltd. All rights reserved. 13.21.1 Introduction 543 13.21.1.1 Uses of Rare Elements

Chakhmouradian, Anton

464

Biotechnology for the decontamination of Metal  

E-Print Network [OSTI]

Laurentian University SNO Science North #12;Problem: Pollution Heavy Metals Aluminium Lead Caesium CalciumBiotechnology for the decontamination of Metal Wastes Professor Vasu D. Appanna PhD Chair Yttrium #12;Accumulation of metals in living systems #12;Biological Effects #12;Adaptation #12;Aluminium

Appanna, Vasu

465

Thin films of mixed metal compounds  

DOE Patents [OSTI]

A compositionally uniform thin film of a mixed metal compound is formed by simultaneously evaporating a first metal compound and a second metal compound from independent sources. The mean free path between the vapor particles is reduced by a gas and the mixed vapors are deposited uniformly. The invention finds particular utility in forming thin film heterojunction solar cells.

Mickelsen, Reid A. (Bellevue, WA); Chen, Wen S. (Seattle, WA)

1985-01-01T23:59:59.000Z

466

Method for decontamination of radioactive metal surfaces  

DOE Patents [OSTI]

Disclosed is a method for removing radioactive contaminants from metal surfaces by applying steam containing an inorganic acid and cerium IV. Cerium IV is applied to contaminated metal surfaces by introducing cerium IV in solution into a steam spray directed at contaminated metal surfaces. Cerium IV solution is converted to an essentially atomized or vapor phase by the steam.

Bray, L.A.

1996-08-13T23:59:59.000Z

467

Metal Dusting of Heat-Resistant Alloys  

E-Print Network [OSTI]

Metal dusting leads to disintegration of such alloys as iron and nickel-based into a “dust” of particulate metal, metal carbide, carbon, and/or oxide. It occurs in strongly carburising environments at 400-900°C. Literature survey has shown...

Al-Meshari, Abdulaziz I

468

Plasticity of Metal Nanowires Christopher R. Weinberger  

E-Print Network [OSTI]

Plasticity of Metal Nanowires Christopher R. Weinberger Sandia National Laboratories, Albuquerque-4040 (Dated: November 24, 2011) Abstract The mechanisms of plasticity in metal naowires with diameters below 100 nm are reviewed. At these length scales, plasticity in face-centered-cubic metals subjected

Cai, Wei

469

subcollector Schottky collector contact & interconnect metals  

E-Print Network [OSTI]

base collector depletion layer subcollector ohmic metal (a) base collector depletion layer Schottky metal base emitter collector collector We emitter base emitter emitter We Wc Wc (b) Schottky collector contact & interconnect metals Emitter & collector Ohmics undoped collector depletion layer base N

Rodwell, Mark J. W.

470

Method for decontamination of radioactive metal surfaces  

DOE Patents [OSTI]

Disclosed is a method for removing radioactive contaminants from metal surfaces by applying steam containing an inorganic acid and cerium IV. Cerium IV is applied to contaminated metal surfaces by introducing cerium IV in solution into a steam spray directed at contaminated metal surfaces. Cerium IV solution is converted to an essentially atomized or vapor phase by the steam.

Bray, Lane A. (Richland, WA)

1996-01-01T23:59:59.000Z

471

Chronic cadmium exposure in vitro induces cancer cell characteristics in human lung cells  

SciTech Connect (OSTI)

Cadmium is a known human lung carcinogen. Here, we attempt to develop an in vitro model of cadmium-induced human lung carcinogenesis by chronically exposing the peripheral lung epithelia cell line, HPL-1D, to a low level of cadmium. Cells were chronically exposed to 5 ?M cadmium, a noncytotoxic level, and monitored for acquired cancer characteristics. By 20 weeks of continuous cadmium exposure, these chronic cadmium treated lung (CCT-LC) cells showed marked increases in secreted MMP-2 activity (3.5-fold), invasion (3.4-fold), and colony formation in soft agar (2-fold). CCT-LC cells were hyperproliferative, grew well in serum-free media, and overexpressed cyclin D1. The CCT-LC cells also showed decreased expression of the tumor suppressor genes p16 and SLC38A3 at the protein levels. Also consistent with an acquired cancer cell phenotype, CCT-LC cells showed increased expression of the oncoproteins K-RAS and N-RAS as well as the epithelial-to-mesenchymal transition marker protein Vimentin. Metallothionein (MT) expression is increased by cadmium, and is typically overexpressed in human lung cancers. The major MT isoforms, MT-1A and MT-2A were elevated in CCT-LC cells. Oxidant adaptive response genes HO-1 and HIF-1A were also activated in CCT-LC cells. Expression of the metal transport genes ZNT-1, ZNT-5, and ZIP-8 increased in CCT-LC cells culminating in reduced cadmium accumulation, suggesting adaptation to the metal. Overall, these data suggest that exposure of human lung epithelial cells to cadmium causes acquisition of cancer cell characteristics. Furthermore, transformation occurs despite the cell's ability to adapt to chronic cadmium exposure. - Highlights: • Chronic cadmium exposure induces cancer cell characteristics in human lung cells. • This provides an in vitro model of cadmium-induced human lung cell transformation. • This occurred with general and lung specific changes typical for cancer cells. • These findings add insight to the relationship between cadmium and lung cancer.

Person, Rachel J.; Tokar, Erik J.; Xu, Yuanyuan; Orihuela, Ruben; Ngalame, Ntube N. Olive; Waalkes, Michael P., E-mail: waalkes@niehs.nih.gov

2013-12-01T23:59:59.000Z

472

Broadening the Statistical Search for Metal Price Super Cycles to Steel and Related Metals  

E-Print Network [OSTI]

Broadening the Statistical Search for Metal Price Super Cycles to Steel and Related Metals in the prices of six metals traded on the London Metal Exchange (the `LME6'). This paper extends the search, and other emerging economies. Some have argued that the world economy has entered the early phases

473

Slag Metal Reactions in Binary CaF2-Metal Oxide Welding Fluxes  

E-Print Network [OSTI]

) Slag Metal Reactions in Binary CaF2-Metal Oxide Welding Fluxes Some otherwise chemically stable fluxes may decompose into suboxides in the presence of welding arcs, thereby providing higher levels of 0 2 in weld metal than those oxides which do not form suboxides ABSTRACT. The stability of metal

Eagar, Thomas W.

474

In Vitro Measurements of Metabolism for Application in Pharmacokinetic Modeling  

SciTech Connect (OSTI)

Abstract Human risk and exposure assessments require dosimetry information. Species-specific tissue dose response will be driven by physiological and biochemical processes. While metabolism and pharmacokinetic data are often not available in humans, they are much more available in laboratory animals; metabolic rate constants can be readily derived in vitro. The physiological differences between laboratory animals and humans are known. Biochemical processes, especially metabolism, can be measured in vitro and extrapolated to account for in vivo metabolism through clearance models or when linked to a physiologically based biological (PBPK) model to describe the physiological processes, such as drug delivery to the metabolic organ. This review focuses on the different organ, cellular, and subcellular systems that can be used to measure in vitro metabolic rate constants and how that data is extrapolated to be used in biokinetic modeling.

Lipscomb, John C.; Poet, Torka S.

2008-04-01T23:59:59.000Z

475

Reclaiming metallic material from an article comprising a non-metallic friable substrate  

DOE Patents [OSTI]

A method for reclaiming a metallic material from a article including a non-metallic friable substrate. The method comprising crushing the article into a plurality of pieces. An acidic solution capable of dissolving the metallic material is provided dissolving the metallic material in the acidic material to form an etchant effluent. The etchant effluent is separated from the friable substrate. A precipitation agent, capable of precipitating the metallic material, is added to the etchant effluent to precipitate out the metallic material from the etchant effluent. The metallic material is then recovered.

Bohland, John Raphael (Oregon, OH); Anisimov, Igor Ivanovich (Whitehouse, OH); Dapkus, Todd James (Toledo, OH); Sasala, Richard Anthony (Toledo, OH); Smigielski, Ken Alan (Toledo, OH); Kamm, Kristin Danielle (Swanton, OH)

2000-01-01T23:59:59.000Z

476

Enhanced Bioaccumulation of Heavy Metals by Bacterial Cells Displaying  

E-Print Network [OSTI]

Enhanced Bioaccumulation of Heavy Metals by Bacterial Cells Displaying Synthetic Phytochelatins for enhanced bioaccumulation of toxic metals. Synthetic genes encoding for several metal strategy for develop- ing high-affinity bioadsorbents suitable for heavy metal removal. © 2000 John Wiley

Chen, Wilfred

477

Stochastic variation in reproductive success of a rare frog, Rana sevosa: implications for conservation and for monitoring amphibian  

E-Print Network [OSTI]

Stochastic variation in reproductive success of a rare frog, Rana sevosa: implications and Sam Noble Oklahoma Museum of Natural History, University of Oklahoma, 2401 Chautauqua, Norman, OK

Richter, Stephen C.

478

Synthesis of transition metal carbonitrides  

DOE Patents [OSTI]

Transition metal carbonitrides (in particular, titanium carbonitride, TiC.sub.0.5 N.sub.0.5) are synthesized by a self-propagating reaction between the metal (e.g., titanium) and carbon in a nitrogen atmosphere. Complete conversion to the carbonitride phase is achieved with the addition of TiN as diluent and with a nitrogen pressure .gtoreq.0.6 MPa. Thermodynamic phase-stability calculations and experimental characterizations of quenched samples provided revealed that the mechanism of formation of the carbonitride is a two-step process. The first step involves the formation of the nonstoichiometric carbide, TiC.sub.0.5, and is followed by the formation of the product by the incorporation of nitrogen in the defect-structure carbide.

Munir, Zuhair A. R. (Davis, CA); Eslamloo-Grami, Maryam (Davis, CA)

1994-01-01T23:59:59.000Z

479

Directly susceptible, noncarbon metal ceramic composite crucible  

DOE Patents [OSTI]

A sintered metal ceramic crucible suitable for high temperature induction melting of reactive metals without appreciable carbon or silicon contamination of the melt. The crucible comprises a cast matrix of a thermally conductive ceramic material; a perforated metal sleeve, which serves as a susceptor for induction heating of the crucible, embedded within the ceramic cast matrix; and a thermal-shock-absorber barrier interposed between the metal sleeve and the ceramic cast matrix to allow for differential thermal expansions between the matrix and the metal sleeve and to act as a thermal-shock-absorber which moderates the effects of rapid changes of sleeve temperature on the matrix.

Holcombe, Jr., Cressie E. (Farragut, TN); Kiggans, Jr., James O. (Oak Ridge, TN); Morrow, S. Marvin (Kingston, TN); Rexford, Donald (Pattersonville, NY)

1999-01-01T23:59:59.000Z

480

Liquid metal Flow Meter - Final Report  

SciTech Connect (OSTI)

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

CVD of refractory amorphous metal alloys  

SciTech Connect (OSTI)

In this work, a novel process is described for the fabrication of multi-metallic amorphous metal alloy coatings using a chemical vapor deposition (CVD) technique. Of special interest in this work are amorphous metal alloys containing Mo and/or Cr which have high crystallization temperatures and readily available low decomposition temperature metal-bearing precursors. The conditions for amorphous alloy formation via CVD are described as well as the chemical properties of these materials. High temperature, aqueous corrosion tests have shown these materials (especially those containing Cr) are among the most corrosion resistant metal alloys known.

Tenhover, M. [The Carborundum Co., Niagara Falls, NY (United States). Technology Div.

1995-08-01T23:59:59.000Z

482

A Better Method for Evaluating Heavy Metal Water Pollution  

E-Print Network [OSTI]

Method for Evaluating Heavy Metal Water Pollution Janetheavy metal contamination would also help communities evaluate their water

Hering, Janet

2002-01-01T23:59:59.000Z

483

Amorphous metal alloy and composite  

DOE Patents [OSTI]

Amorphous metal alloys of the iron-chromium and nickel-chromium type have excellent corrosion resistance and high temperature stability and are suitable for use as a protective coating on less corrosion resistant substrates. The alloys are stabilized in the amorphous state by one or more elements of titanium, zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. The alloy is preferably prepared by sputter deposition.

Wang, Rong (Richland, WA); Merz, Martin D. (Richland, WA)

1985-01-01T23:59:59.000Z

484

Metal-air battery assessment  

SciTech Connect (OSTI)

The objective of this report is to evaluate the present technical status of the zinc-air, aluminum/air and iron/air batteries and assess their potential for use in an electric vehicle. In addition, this report will outline proposed research and development priorities for the successful development of metal-air batteries for electric vehicle application. 39 refs., 25 figs., 11 tabs.

Sen, R.K.; Van Voorhees, S.L.; Ferrel, T.

1988-05-01T23:59:59.000Z

485

B --> rho K* decays and other rare vector-vector modes  

E-Print Network [OSTI]

The recent analyses of the following rare vector-vector decays of the B meson are presented: rho K*, omega K*, omega rho, omega omega, and omega phi charmless final states. The latest results indicate that the fraction of longitudinal polarization is about 0.5 in penguin-dominated modes and close to 1 for tree-dominated modes.

G. Vasseur

2007-04-03T23:59:59.000Z

486

E-Print Network 3.0 - adding rare earths Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

au n04, Tome 24, a v r i l 1989 Summary: obtenus. Les constantes de Verdet de ces aerogels o n t Bt6 determinees. Abstract - Rare-earth s i l i c... a t e s and TMOS. The...

487

E-Print Network 3.0 - aged rare earth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

au n04, Tome 24, a v r i l 1989 Summary: obtenus. Les constantes de Verdet de ces aerogels o n t Bt6 determinees. Abstract - Rare-earth s i l i c... a t e s and TMOS. The...

488

E-Print Network 3.0 - adjustable rare earth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

au n04, Tome 24, a v r i l 1989 Summary: obtenus. Les constantes de Verdet de ces aerogels o n t Bt6 determinees. Abstract - Rare-earth s i l i c... a t e s and TMOS. The...

489

Search for Rare 3 and 4-Body D0 Decays at FNAL E791  

E-Print Network [OSTI]

Limits at the 10**-4 level are reported for rare and forbidden decays of the D0 charm meson to a pair of leptons and either a vector meson or two pseudoscalar mesons. Of these searches, 18 are investigations of decays without previous published results; several others have significantly improved sensitivity over previous results.

Fermilab E791 Collaboration; D. J. Summers

2000-11-21T23:59:59.000Z

490

ACCEPTED MANUSCRIPT The behaviour of Rare-Earth Elements, Zr and Hf during biologically-mediated  

E-Print Network [OSTI]

ACCEPTED MANUSCRIPT ACCEPTED MANUSCRIPT 1 The behaviour of Rare-Earth Elements, Zr and Hf during.a,b* , Cangemi M.a , Brusca L.c , Madonia P.c , Saiano F.d , Zuddas P.e a) Department of Earth and Marine at the solid-liquid interface influencing the distribution of trace elements onto microbial surfaces. Since

491

Prospects for and Status of CUORE ? The Cryogenic Underground Observatory for Rare Events  

SciTech Connect (OSTI)

CUORE (Cryogenic Underground Observatory for Rare Events) is a next generation experiment designed to search for the neutrinoless DBD of {sup 130}Te using a bolometric technique. The present status of the CUORE is presented along with the latest results from its prototype, CUORICINO.

Norman, E B

2009-07-07T23:59:59.000Z

492

Power and sample size calculations for designing rare variant sequenc-ing association studies.  

E-Print Network [OSTI]

of the statistical power of SKAT. Required sample size can be computed easily by inverting the power functionPower and sample size calculations for designing rare variant sequenc- ing association studies pow- erful than the collapsing based burden tests under many circumstances [4]. To design new sequence

Lin, Xihong

493

Managing Natural and Reintroduced Rare Plant Populations within a Large Government Reservation  

SciTech Connect (OSTI)

California is home to many large government reservations that have been in existence for decades. Many of these reservations were formed to support various Department of Defense and Department of Energy national defense activities. Often, only a very small percentage of the reservation is actively used for programmatic activities, resulting in large areas of intact habitat. In some cases, this has benefited rare plant populations, as surrounding lands have been developed for residential or industrial use. However, land management activities such as the suppression or active use of fire and other disturbance (such as fire trail grading) can also work to either the detriment or benefit of rare plant populations at these sites. A management regime that is beneficial to the rare plant populations of interest and is at best consistent with existing site programmatic activities, and at a minimum does not impact such activities, has the best potential for a positive outcome. As a result, some species may be 'difficult' while others may be 'easy' to manage in this context, depending on how closely the species biological requirements match the programmatic activities on the reservation. To illustrate, we compare and contrast two rare annual plant species found at Lawrence Livermore National Laboratory's Site 300. Although several populations of Amsinckia grandiflora have been restored on the site, and all populations are intensively managed, this species continues to decline. In contrast, Blepharizonia plumosa appears to take advantage of the annual controlled burns conducted on the site, and is thriving.

Carlsen, T M; Paterson, L E; Alfaro, T M

2009-07-15T23:59:59.000Z

494

Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds  

E-Print Network [OSTI]

Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds M Abstract. -- The thermal behavior of oxygen-stabilized RjFegO^-hydrogen (R = Y, Dy, Ho) systems was studied decade to the study of the hydrogenation characte- ristics of a variety of intermetallic compounds, our

Paris-Sud XI, Université de

495

South Florida Sun-Sentinel.com Venus to cross sun in rare celestial event  

E-Print Network [OSTI]

South Florida Sun-Sentinel.com Venus to cross sun in rare celestial event By Robert Nolin, Sun passage across the face of the sun at twilight Tuesday. It's a sight you'll never see again. Called named for the Roman goddess of love will pass between the Earth and the sun for several hours at sunset

Belogay, Eugene A.

496

Rare earth element partitioning between titanite and silicate melts: Henry's law revisited  

E-Print Network [OSTI]

Rare earth element partitioning between titanite and silicate melts: Henry's law revisited Stefan earth elements (REE) between titanite and a range of different silicate melts. Our results show. For geochemical modelling of magmatic processes involving titanite, and indeed other accessory phases

497

Rare sulfur and triple oxygen isotope geochemistry of volcanogenic sulfate aerosols  

E-Print Network [OSTI]

Rare sulfur and triple oxygen isotope geochemistry of volcanogenic sulfate aerosols I.N. Bindeman a of Technology, Pasadena, CA, USA c Department of Earth and Planetary Sciences, McGill University, Montreal, Que., Canada d Department of Geology and Earth System Science Interdisciplinary Center, University of Maryland

Bindeman, Ilya N.

498

Metalization of lipid vesicles via electroless plating  

SciTech Connect (OSTI)

The encapsulation of metallic particles and metallic oxides within lipid vesicles has recently been of interest for applications such as catalysis, water splitting, and magnetic control of spin coupling. In this communication the authors introduce the concept and practice of the deposition of metal on vesicles by using electroless plating techniques. Coordination of low valent transition metals to organic functional groups on the surface of the bilayer membrane provides a means of binding metal atoms to vesicles. Chemical reduction produced zero valent atoms which serve as sites for further metal deposition by the chemical reduction techniques of electroless plating. Specifically, this procedure involved the binding of a small amount of tetrachloropalladate to the vesicle bilayer, reduction of the palladium(II) to palladium(0), followed by the deposition of much larger amounts of metal from an electroless plating solution. Electroless plating solutions were used for the deposition of palladium, nickel, cobalt, or copper metal onto the catalytic palladium centers. Since the metallic particles were associated with the vesicles, colloids were formed that were stable in water for much longer periods than the control metal particles formed in water alone. If the vesicles were composed in part of unsaturated lipids, with the olefinic groups on the hydrocarbon chains, the initial evidence suggests the transition metal was directed into the bilayer, rather than staying on the surface.

Ferrar, W.T.; O'Brien, D.F.; Warshawsky, A.; Voycheck, C.L.

1988-01-06T23:59:59.000Z

499

Metal resistance sequences and transgenic plants  

SciTech Connect (OSTI)

The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

1999-10-12T23:59:59.000Z

500

Method For Characterizing Residual Stress In Metals  

DOE Patents [OSTI]

A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

Jacobson, Loren A. (Santa Fe, NM); Michel, David J. (Alexandria, VA); Wyatt, Jeffrey R. (Burke, VA)

2002-12-03T23:59:59.000Z