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1

Remedial actions at the former Vitro Rare Metals plant site, Canonsburg, Washington County, Pennsylvania. Final Environmental Impact Statement. Volume I  

SciTech Connect

The environmental impacts associated with remedial actions in connection with residual radioactive materials remaining at the inactive uranium processing site located in Canonsburg, Washington County, Pennsylvania are evaluated. The Canonsburg site is an 18.5-acre property that was formerly owned by the Vitro Rare Metals Company. The expanded Canonsburg site would be 30-acre property that would include the Canonsburg site (the former Vitro Rare Metals plant), seven adjacent private houses, and the former Georges Pottery property. During the period 1942 through 1957 the Vitro Manufacturing Company and its successor, the Vitro Corporation of America, processed onsite residues and ores, and government-owned ores, concentrates, and scraps to extract uranium and other rare metals. The Canonsburg site is now the Canon Industrial Park. In addition to storing the residual radioactive materials of this process at the Canonsburg site, about 12,000 tons of radioactively contaminated materials were transferred to a railroad landfill in Burrell Township, Indiana County, Pennsylvania. This Canonsburg FEIS evaluates five alternatives for removing the potential public health hazard associated with the radioactively contaminated materials. In addition to no action, these alternatives involve various combinations of stabilization of the radioactively contaminated materials in place or decontamination of the Canonsburg and Burrell sites by removing the radioactively contaminated materials to another location. In addition to the two sites mentioned, a third site located in Hanover Township, Washington County, Pennsylvania has been considered as a disposal site to which the radioactively contaminated materials presently located at either of the other two sites might be moved.

Not Available

1983-07-01T23:59:59.000Z

2

Chapter 4 - Recycling Rare Metals  

Science Journals Connector (OSTI)

Abstract The industrial system now utilizes many more elements, especially rare metals, than was the case even a half century ago. Most are not mined for themselves but are obtained as by-products or “hitchhikers” of the more familiar industrial metals, such as iron, aluminum, copper, nickel, and zinc. This imposes a limit on the production of by-product metals. But in some cases, demand may increase much faster than new supply. This suggests a need for recycling. But the uses of these metals are often in products, such as cell phones, that are mass-produced but where the amount in each individual product is very small. Some uses are also inherently dissipative. This makes recycling very difficult in principle. It constitutes a serious challenge for the future economy. Prices will rise.

Robert U. Ayres; Gara Villalba Méndez; Laura Talens Peiró

2014-01-01T23:59:59.000Z

3

Rare Earth Metals and Alloys | Ames Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Mpc » Rare Earth Metals and Alloys Mpc » Rare Earth Metals and Alloys Rare Earth Metals and Alloys Terbium (Tb) and Cerium (Ce) phosphors in your computer screen allow you to see GREEN. Europium (Eu) is the source of the RED light and BLUE emitted by our display. The Ames Laboratory has been actively involved in the preparation of very pure rare earth metals since the early 1940's when Dr. Frank H. Spedding and his group of pioneers developed the ion-exchange process, a technique that separates the "fraternal fifteen" plus yttrium and scandium. As a result of this and subsequent work, high-purity oxides are available from which high-purity rare earth metals can be prepared. In most cases, the rare earth oxides are first converted to their respective fluorides and are then reduced metallothermicaly on a kilogram

4

DOE Science Showcase - Rare Earth Metal Research from DOE Databases |  

Office of Scientific and Technical Information (OSTI)

Rare Earth Metal Research from DOE Databases Rare Earth Metal Research from DOE Databases Information Bridge Energy Citations Database Highlighted documents of Rare Earth Metal research in DOE databases Information Bridge - Corrosion-resistant metal surfaces DOE R&D Project Summaries - Structural and magnetic studies on heavy rare earth metals at high pressures using designer diamonds Energy Citations Database - Intermultiplet transitions in rare-earth metals DOE Green Energy - LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells Science.gov - H.R.4866 - Rare Earths Supply-Chain Technology and Resources Transformation Act of 2010 WorldWideScience.org - China produces most of the world's rare earth metals DOepatents - Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction

5

DOE launches rare earth metals research hub  

NLE Websites -- All DOE Office Websites (Extended Search)

ATL011113_hub ATL011113_hub 01/11/2013 DOE launches rare earth metals research hub Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Printer-friendly Europium, a rare earth element that has the same relative hardness of lead, is used to create fluorescent lightbulbs. With no proven substitutes, europium is considered critical to the clean energy economy. Photo courtesy of the Ames Laboratory. High Resolution Image The Department of Energy has launched a research hub that focuses on solutions to the domestic shortages of rare earth metals and other materials critical for U.S. energy security. Housed at Ames Laboratory in Iowa, Lawrence Livermore has been involved in establishing this Energy Innovation Hub since its conception more than two years ago. In 2010, on behalf of DOE, LLNL hosted the first U.S.-Japan

6

Engineering of microorganisms towards recovery of rare metal ions  

Science Journals Connector (OSTI)

The bioadsorption of metal ions using microorganisms is an attractive technology for the recovery of rare metal ions as well as removal of toxic heavy metal ions from aqueous solution. In initial attempts, microo...

Kouichi Kuroda; Mitsuyoshi Ueda

2010-06-01T23:59:59.000Z

7

Diversity of accessory minerals in rare-metal-rare earth pegmatites  

Science Journals Connector (OSTI)

About 150 accessory minerals have been identified in the rare-metal-rare earth pegmatites, including 36 OH-, F- and H2 O-bearing silicates, 27 volatile-free silicates, 31 complex oxides, and 17 carbonates. Most a...

B. M. Shmakin

2008-12-01T23:59:59.000Z

8

The Materials Preparation Center - Making Rare Earth Metals - Part 3  

SciTech Connect

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 3 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

9

The Materials Preparation Center - Making Rare Earth Metals - Part 2  

SciTech Connect

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 2 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

10

The Materials Preparation Center - Making Rare Earth Metals - Part 1  

SciTech Connect

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 1 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

11

The Materials Preparation Center - Making Rare Earth Metals - Part 4  

SciTech Connect

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 4 of 4.

Riedemann, Trevor

2011-01-01T23:59:59.000Z

12

The Materials Preparation Center - Making Rare Earth Metals - Part 3  

ScienceCinema (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 3 of 4.

Riedemann, Trevor

2013-03-01T23:59:59.000Z

13

The Materials Preparation Center - Making Rare Earth Metals - Part 1  

ScienceCinema (OSTI)

Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 1 of 4.

Riedemann, Trevor

2013-03-01T23:59:59.000Z

14

DOE Announces RFI on Rare Earth Metals | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

RFI on Rare Earth Metals RFI on Rare Earth Metals DOE Announces RFI on Rare Earth Metals May 6, 2010 - 12:00am Addthis Washington, D.C. - The Department of Energy has released a Request for Information (RFI) soliciting information on rare earth metals and other materials used in the energy sector. The request is specifically focused on rare earth metals (e.g., lanthanum, cerium and neodymium) and several other metals including lithium and cobalt, but respondents are welcome to identify other materials of interest. These materials are important to the development and deployment of a variety of clean energy technologies, such as wind turbines, hybrid vehicles, solar panels and energy efficient light bulbs. In a March 17 speech, Assistant Secretary of Energy for Policy & International Affairs David Sandalow announced that DOE is developing its

15

DOE Announces RFI on Rare Earth Metals | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

RFI on Rare Earth Metals RFI on Rare Earth Metals DOE Announces RFI on Rare Earth Metals May 6, 2010 - 12:00am Addthis Washington, D.C. - The Department of Energy has released a Request for Information (RFI) soliciting information on rare earth metals and other materials used in the energy sector. The request is specifically focused on rare earth metals (e.g., lanthanum, cerium and neodymium) and several other metals including lithium and cobalt, but respondents are welcome to identify other materials of interest. These materials are important to the development and deployment of a variety of clean energy technologies, such as wind turbines, hybrid vehicles, solar panels and energy efficient light bulbs. In a March 17 speech, Assistant Secretary of Energy for Policy & International Affairs David Sandalow announced that DOE is developing its

16

DOE - Office of Legacy Management -- International Rare Metals Refinery Inc  

Office of Legacy Management (LM)

Rare Metals Refinery Rare Metals Refinery Inc - NY 38 FUSRAP Considered Sites Site: International Rare Metals Refinery, Inc. (NY.38 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Canadian Radium and Uranium Corporation NY.38-1 Location: 69 Kisko Avenue , Mt. Kisko , New York NY.38-1 NY.38-3 Evaluation Year: 1987 NY.38-4 Site Operations: Manufactured and distributed radium and polonium products. NY.38-5 Site Disposition: Eliminated - No Authority - Site was a commercial operation not under the jurisdiction of DOE predecessor agencies NY.38-2 NY.38-4 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Radium, Plutonium NY.38-5 Radiological Survey(s): Yes NY.38-1 NY.38-5 Site Status: Eliminated from consideration under FUSRAP

17

Metal-Insulator Transition in Metal—Rare-Gas Alloys  

Science Journals Connector (OSTI)

We present the results of electrical resistivity and optical absorption measurements for compositions spanning the metal-insulator transition in RbKr and CsXe alloys. The two transitions are similar and exhibit an apparently percolative character. No marked emergence of excitons accompanies the disappearance of conductivity. Spectral features associated with metallic conduction also persist through the transitions.

D. J. Phelps; R. Avci; C. P. Flynn

1975-01-06T23:59:59.000Z

18

Rare earth-transition metal scrap treatment method  

DOE Patents (OSTI)

Rare earth-transition metal (e.g. iron) scrap (e.g. Nd-Fe-B scrap) is melted to reduce the levels of tramp oxygen and nitrogen impurities therein. The tramp impurities are reduced in the melt by virtue of the reaction of the tramp impurities and the rare earth to form dross on the melt. The purified melt is separated from the dross for reuse. The oxygen and nitrogen of the melt are reduced to levels acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. 3 figs.

Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.; Jones, L.L.; Lincoln, L.P.

1992-02-11T23:59:59.000Z

19

Metal-insulator transition in rare-gas-alkali-metal thin films  

Science Journals Connector (OSTI)

We report measurements of the conductivity and optical absorption in KrRb and XeCs thin films through the composition range spanning the metal-insulator transition. It is argued from chemical properties of the constituents that the conductivity loss must take the form of a percolative transition. In agreement with this assignment, the optical absorption shows no discontinuous or even marked change through the transitions. "Metallic" and "excitonic" features both persist on each side of the observed transitions in the two systems. The resistivity in metal-rich alloys yields residual resistivities for rare-gas impurities close to the values expected of vacancies, and the resistivity transitions at ? 75 at.% rare gas conform rather closely to the prediction of percolation theory.

D. J. Phelps and C. P. Flynn

1976-12-15T23:59:59.000Z

20

Solvent extraction of rare-earth metals by carboxylic acids  

SciTech Connect

The solvent extraction of the trivalent lanthanides and yttrium from nitrate media by solutions of carboxylic acids in xylene has been studied. Commercially available carboxylic acids such as Versatic 10 and naphthenic acids were used, as well as model compounds of known structure, such as 2-ethylhexanoic and 3-cyclohexylpropanoic acids. In a few cases, extraction of the metals from sulphate and chloride solutions was also investigated. The dependence of the extraction properties of the carboxylic acids on the atomic number of the lanthanide shows a definite relationship to the steric bulk of the carboxylic acid molecule quantified by means of the steric parameter, E{sub s}{prime} of the substituent alkyl group. The stoichiometries of the extracted complexes for representative light (La), middle (Gd) and heavy (Lu) rare-earth metals were investigated by the slope-analysis technique for a sterically hindered acid (Versatic 10 acid; -E{prime}{sub s} = 3.83) and an acid with low steric hindrance (3-cyclohexylpropanoic acid; -E{prime}{sub s} = 0.28). 14 refs., 13 figs., 3 tabs.

Preez, A.C. du; Preston, J.S. [Mintek, Randburg (South Africa)

1992-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

DOE Announces Second RFI on Rare Earth Metals | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Second RFI on Rare Earth Metals Second RFI on Rare Earth Metals DOE Announces Second RFI on Rare Earth Metals March 22, 2011 - 12:00am Addthis Washington, D.C. - The Department of Energy today released a Request for Information (RFI) soliciting information from the public on rare earth metals and other materials used in the energy sector. Responses to this RFI will inform an update to DOE's Critical Materials Strategy (pdf - 5.7mb ), released December 15, 2010, that assessed the use of rare earth metals and other materials important to the development and deployment of a variety of clean energy technologies, such as wind turbines, hybrid vehicles, solar panels and energy efficient light bulbs. The updated strategy, expected later this year, will include additional analysis of rapidly-changing market conditions. It will analyze the use

22

Metal-insulator transition in expanded alkali-metal fluids and alkali-metal—rare-gas films  

Science Journals Connector (OSTI)

We have developed a theoretical model for expanded alkali metals and alkali-metal—rare-gas films that is based on a physically realistic picture of the atomic-scale structure of these materials. It emphasizes the disorder in the systems, in particular the random atomic coordination number. Using this model we have calculated the density- and the energy-dependent conductivity as a function of the mean alkali-metal atomic coordination number. Although the theory contains only two parameters, both of which are fixed by the properties of pure materials at normal temperatures, we have been able to explain results measured over a temprature range from 4.2 to >2000 K in a variety of different alkali-metal systems. Conductivity and magnetic-susceptibility measurements, in particular, have been considered in some detail. In addition, the theory provides insight into the nature and location of the metal-insulator transition, the nature of the critical point for the alkali metals, and the thermal instability of the alkali-metal—rare-gas films.

Judy R. Franz

1984-02-15T23:59:59.000Z

23

New data on mineral forms of rare metals in phosphogypsum wastes  

Science Journals Connector (OSTI)

Phosphogypsum is an industrial waste of the processing ... . This is a valuable and promising technogenous rare-metal feedstock. The samples of fresh and old phosphogypsum were studied using precision physical te...

A. E. Samonov

2011-09-01T23:59:59.000Z

24

Crystal Fields in Dilute Rare-Earth Metals Obtained from Magnetization Measurements on Dilute Rare-Earth Alloys  

Science Journals Connector (OSTI)

Crystal field parameters of Tb, Dy, and Er in Sc, Y, and Lu are summarized. These parameters are obtained from magnetization measurements on dilute single crystals, and successfully checked by a number of different methods. The crystal field parameters vary unpredictably with the rare-earth solute. B40, B60, and B66 are similar in Y and Lu. Crystal field parameters for the pure metals Tb, Dy, and Er are estimated from the crystal fields in Y and Lu.

P. Touborg and J. Høg

1974-09-23T23:59:59.000Z

25

High Pressure Phase Transformations in Heavy Rare Earth Metals and Connections to Actinide Crystal Structures  

SciTech Connect

High-pressure studies have been performed on heavy rare earth metals Terbium (Tb) to 155 GPa and Holmium (Ho) to 134 GPa in a diamond anvil cell at room temperature. The following crystal structure sequence was observed in both metals hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc (hR-24) {yields} monoclinic (C2/m) with increasing pressure. The last transformation to a low symmetry monoclinic phase is accompanied by a volume collapse of 5 % for Tb at 51 GPa and a volume collapse of 3 % for Ho at 103 GPa. This volume collapse under high pressure is reminiscent of f-shell delocalization in light rare earth metal Cerium (Ce), Praseodymium (Pr), and heavy actinide metals Americium (Am) and Curium (Cm). The orthorhombic Pnma phase that has been reported in Am and Cm after f-shell delocalization is not observed in heavy rare earth metals under high pressures. (authors)

Vohra, Yogesh K.; Sangala, Bagvanth Reddy; Stemshorn, Andrew K. [Physics, University of Alabama at Birmingham (UAB), 310 Campbell Hall, 1300 University Boulevard, Birmingham, AL, 35294-1170 (United States); Hope, Kevin M. [Biology, Chemistry, and Mathematics, University of Montevallo, Harman Hall, Station 6480, Montevallo, AL, 35115 (United States)

2008-07-01T23:59:59.000Z

26

Ternary rare earth and actinoid transition metal carbides viewed as carbometalates  

SciTech Connect

Ternary carbides A{sub x}T{sub y}C{sub z} (A=rare earth metals and actinoids; T=transition metals) with monoatomic species C{sup 4-} as structural entities are classified according to the criteria (i) metal to carbon ratio, (ii) coordination number of the transition metal by carbon atoms, and (iii) the dimensionality of the anionic network [T{sub y}C{sub z}]{sup n-}. Two groups are clearly distinguishable, depending on the metal to carbon ratio. Those where this ratio is equal to or smaller than 2 may be viewed as carbometalates, thus extending the sequence of complex anions from fluoro-, oxo-, and nitridometalates to carbometalates. The second group, metal-rich carbides with metal to carbon ratios equal to or larger than 4 is better viewed as typical intermetallics (''interstitial carbides''). The chemical bonding properties have been investigated by analyzing the Crystal Orbital Hamilton Population (COHP). The chemical bonding situation with respect to individual T-C bonds is similar in both classes. The main difference is the larger number of metal-metal bonds in the crystal structures of the metal-rich carbides.

Dashjav, Enkhtsetseg [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Kreiner, Guido [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Schnelle, Walter [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Wagner, Frank R. [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Kniep, Ruediger [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, D-01187 Dresden (Germany)], E-mail: Kniep@cpfs.mpg.de; Jeitschko, Wolfgang [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster, Wilhelm-Klemm-Strasse 8, D-48149 Muenster (Germany)], E-mail: jeitsch@uni-muenster.de

2007-02-15T23:59:59.000Z

27

High-temperature desulfurization of gasifier effluents with rare earth and rare earth/transition metal oxides  

SciTech Connect

We have improved the application of mixed rare-earth oxides (REOs) as hot gas desulfurization adsorbents by impregnating them on stable high surface area supports and by the inclusion of certain transition metal oxides. We report comparative desulfurization experiments at high temperature (900 K) using a synthetic biomass gasifier effluent containing 0.1 vol % H{sub 2}S, along with H{sub 2}, CO{sub 2}, and water. More complex REO sorbents outperform the simpler CeO{sub 2}/La{sub 2}O{sub 3} mixtures, in some cases significantly. Supporting REOs on Al{sub 2}O{sub 3} (?20 wt % REO) or ZrO{sub 2} actually increased the sulfur capacities found after several cycles on a total weight basis. Another major increase in sulfur capacity took place when MnO{sub x} or FeO{sub x} is incorporated. Apparently most of the Mn or Fe is dispersed on or near the surface of the mixed REOs because the capacities with REOs greatly exceeded those of Al{sub 2}O{sub 3}-supported MnO{sub x} or FeO{sub x} alone at these conditions. In contrast, incorporating Cu has little effect on sulfur adsorption capacities. Both the REO and transition metal/REO adsorbents could be regenerated completely using air for at least five repetitive cycles.

Dooley, Kerry M.; Kalakota, Vikram; Adusumilli, Sumana

2011-01-01T23:59:59.000Z

28

Tar Reforming in Model Gasifier Effluents: Transition Metal/Rare Earth Oxide Catalysts  

Science Journals Connector (OSTI)

Tar Reforming in Model Gasifier Effluents: Transition Metal/Rare Earth Oxide Catalysts ... So in this work we investigated the action of transition metal oxides (TMOs) other than Ni (e.g., Fe, Mn) mixed with REOs for tar reforming, at a medium temperature range (923–1073 K) and under conditions where direct reforming would dominate. ... The heated gas mixture passed through a 1/2” stainless steel tube containing 0.2–1 g of catalyst (40–60 mesh size) diluted with mullite and positioned between beds of ?-Al2O3. ...

Rui Li; Amitava Roy; Joseph Bridges; Kerry M. Dooley

2014-04-24T23:59:59.000Z

29

Behaviour of zirconium, niobium, yttrium and the rare earth elements in the Thor Lake rare-metal  

E-Print Network (OSTI)

Behaviour of zirconium, niobium, yttrium and the rare earth elements in the Thor Lake rare and the heavy rare earth elements in the world. Much of the potentially economic mineralization was concentrated of Science Department of Earth and Planetary Sciences McGill University, Montreal, QC, Canada February 2010

30

Pseudocrystalline model of the magnetic anisotropy in amorphous rare-earth–transition-metal thin films  

Science Journals Connector (OSTI)

A pseudocrystalline model is proposed to explain the occurrence of perpendicular anisotropy in amorphous rare-earth–transition metal (R-T) thin films. It is based on the central hypothesis that during layer-by-layer growth small planar hexagonal units are formed defining on average a preferential axis perpendicular to the film plane. The units are similar in structure to relaxed crystalline ones and are estimated to typically comprise six rare-earth atoms. They are regarded as an idealized model of the short-range order and are consistent with the known nearest-neighbor R-T and T-T coordination numbers in the amorphous state. This model is able to explain the known experimental results concerning the influence of composition, substrate temperature, annealing, and bombardment effects during sputter deposition on the magnetic anisotropy of thin amorphous rare-earth–transition-metal films of the system (Nd, Tb, Dy) (Fe, Co), as well as the destruction of this anisotropy by additives.

D. Mergel; H. Heitmann; P. Hansen

1993-01-01T23:59:59.000Z

31

Charge screening and magnetic anisotropy in metallic rare-earth systems  

Science Journals Connector (OSTI)

The calculation of magnetic anisotropy constants is performed beyond the point-charge model for a continuous charge-density distribution of screening conduction electrons. An important role of the nonuniform electron density, in particular, of the Friedel oscillations, in the formation of crystal field is demonstrated. Such effects can modify strongly the effective ion (impurity) charge and even change its sign. This enables one to justify the anion model, which is often used for discussing experimental data on hydrogen-containing systems. Possible applications to the pure rare-earth metals and RCo5 (R=rare earth) compounds are discussed. The deformation of magnetic structure near the interstitial positive muon owing to the strong local anisotropy, and the corresponding contribution to the dipole field at the muon are considered.

V. Yu. Irkhin and Yu. P. Irkhin

1998-02-01T23:59:59.000Z

32

New Rare Earth Element Abundance Distributions for the Sun and Five r-Process-Rich Very Metal-Poor Stars  

E-Print Network (OSTI)

We have derived new abundances of the rare-earth elements Pr, Dy, Tm, Yb, and Lu for the solar photosphere and for five very metal-poor, neutron-capture r-process-rich giant stars. The photospheric values for all five elements are in good agreement with meteoritic abundances. For the low metallicity sample, these abundances have been combined with new Ce abundances from a companion paper, and reconsideration of a few other elements in individual stars, to produce internally-consistent Ba, rare-earth, and Hf (56element distributions. These have been used in a critical comparison between stellar and solar r-process abundance mixes.

Sneden, Christopher; Cowan, John J; Ivans, Inese I; Hartog, Elizabeth A Den

2009-01-01T23:59:59.000Z

33

Solid-Liquid and Solid-Solid Transformations in the Rare-Earth Metals at High Pressures  

Science Journals Connector (OSTI)

The fusion behavior and solid-solid transformations in the rare-earth metals have been investigated at pressures in the range 6-65 kbar. The phase diagrams are presented for La, Pr, Nd, Sm, Gd, and Tb. The initial melting slopes of Dy to Lu have been obtained. Since most of the rare-earth (R.E.) metals melt from a bcc structure, they offer a series for comparison. When the initial melting slope is plotted against atomic number they fall into groups according to their valency; the typically divalent metals Eu and Yb in one, and the typically trivalent metals La, Gd, and Lu in another. Samarium and the metals from Tb to Tm have melting slopes which are intermediate between those of the typically divalent and trivalent metals. It is suggested that these metals assume a partial divalent character in the liquid state and possibly also in the bcc phase. This suggestion derives support from the fact that the gaseous neutral atoms of the R.E. elements, with the exception of La, Gd, and Lu, have no 5d electron and are therefore divalent. Cerium exhibits a unique fusion behavior and its negative melting slope has been attributed to the tetravalency (4f?5d electron promotion) of the atoms in the liquid. For the very small melting slope of Pr, it is suggested that the atoms in the liquid have partial tetravalent character due to 4f?5d electron promotion. Comparisons with alkali metals are made and it is deduced that the R.E. metals are quite compressible at high temperatures. Pressure induced transformations in the rare-earth metals are in the sequence hcp?Sm-type?double hcp?fcc. A plausible mechanism based on the variation of ca ratio with pressure is discussed for hcp?Sm-type transformation.

A. Jayaraman

1965-08-02T23:59:59.000Z

34

Metal sulfide and rare-earth phosphate nanostructures and methods of making same  

DOE Patents (OSTI)

The present invention provides a method of producing a crystalline metal sulfide nanostructure. The metal is a transitional metal or a Group IV metal. In the method, a porous membrane is placed between a metal precursor solution and a sulfur precursor solution. The metal cations of the metal precursor solution and sulfur ions of the sulfur precursor solution react, thereby producing a crystalline metal sulfide nanostructure.

Wong, Stanislaus; Zhang, Fen

2014-05-13T23:59:59.000Z

35

Subcell Structure and Two Different Superstructures of the Rare Earth Metal Silicide Carbides Y  

SciTech Connect

The title compounds crystallize with a very pronounced subcell structure that has been determined from single-crystal X-ray diffractometer data of all four compounds. Only subcell (and no superstructure) reflections have been observed for Pr{sub 3}Si{sub 2}C{sub 2}: space group Cmmm, a=396.7(1) pm, b=1645.2(3) pm, c=439.9(1) pm, R=0.019 for 309 structure factors and 20 variable parameters. In this subcell structure there are C{sub 2} pairs with split atomic positions. This structure may be considered the thermodynamically stable forms of these compounds at high temperatures. Two different superstructures with doubled a or c axes, respectively, of the subcell have been observed, where the C{sub 2} pairs have different orientations. In the structure of Tb{sub 3}Si{sub 2}C{sub 2} the a axis of the subcell is doubled. The resulting superstructure in the standard setting has the space group Pbcm: a=423.6(1) pm, b=770.7(1) pm, c=1570.2(3) pm, R=0.031 f or 1437 structure factors and 22 variable parameters. Dy{sub 3}Si{sub 2}C{sub 2} has the same superstructure: a=420.3(1) pm, b=767.5(1) pm, c=1561.1(3) pm, R=0.045, 801 F values, 22 variables. In the structure of Y{sub 3}Si{sub 2}C{sub 2} the c axis of the subcell is doubled, resulting in a body-centered space group with the standard setting Imma: a=842.6(2) pm, b=1563.4(2) pm, c=384.6(1) pm, R=0.035, 681 F values, 15 variables. In all of these structures the rare earth atoms form two-dimensionally infinite sheets of edge-sharing octahedra that contain the C{sub 2} pairs. In between these sheets there are zig-zag chains of silicon atoms with Si-Si distances varying between 246.2(3) and 253.6(3) pm, somewhat longer than the two-electron bonds of 235 pm in elemental silicon, suggesting a bond order of 0.5 for the Si-Si bonds. The C-C distances in the C{sub 2} pairs vary between 127(1) and 131(1) pm, corresponding to a bond order of approximately 2. 5. Hence, using oxidation numbers, the compounds may to a first approximation be represented by the formula (R{sup +3}){sub 3}(Si{sup {minus}3}){sub 2}(C{sub 2}){sup {minus}3}. A more detailed analysis of the interatomic distances showed that the shortest R-R distances are comparable with the R-R distances in the structures of the rare earth elements, thus indicating some R-R bonding. Therefore, the oxidation numbers of the rare earth atoms are slightly lower than +3, in agreement with the metallic conductivity of these compounds. As a consequence, considering the relatively short Si-Si bonds, the absolute value of the oxidation number of the silicon atoms may be lower than 3, resulting in a Si-Si bond order somewhat higher than 0.5.

Jeitschko, Wolfgang; Gerdes, Martin H.; Witte, Anne M.; Rodewald, Ute Ch.

2001-01-01T23:59:59.000Z

36

Rare-earth neutral metal injection into an electron beam ion trap plasma  

SciTech Connect

We have designed and implemented a neutral metal vapor injector on the SuperEBIT high-energy electron beam ion trap at the Lawrence Livermore National Laboratory. A horizontally directed vapor of a europium metal is created using a thermal evaporation technique. The metal vapor is then spatially collimated prior to injection into the trap. The source's form and quantity constraints are significantly reduced making plasmas out of metal with vapor pressures ?10{sup ?7} Torr at ?1000?°C more obtainable. A long pulsed or constant feed metal vapor injection method adds new flexibility by varying the timing of injection and rate of material being introduced into the trap.

Magee, E. W., E-mail: magee1@llnl.gov; Beiersdorfer, P.; Brown, G. V. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Hell, N. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Dr. Remeis-Sternwarte and ECAP, Universität Erlangen-Nürnberg, 96049 Bamberg (Germany)

2014-11-15T23:59:59.000Z

37

Density of states of a semi-infinite rare-earth metal with magnetic structure: A simple model  

Science Journals Connector (OSTI)

Using a simple tight-binding model and the transfer matrix approach, we have calculated the spectral density of states (SDOS) of a rare-earth metal in the presence of a surface for different magnetic arrangements (such as ferromagnetic, antiferromagnetic, and conical orderings). The local density of states (LDOS) has also been calculated for some examples, integrating the SDOS over the Brillouin zone. The main effect observed deals with the absence of Van Hove's singularities in the surface LDOS, a fact that appears to be an intrinsic property of the surface. Finally the relaxation of the overlap parameters at the surface is discussed and some numerical examples are shown.

Bernardo Laks and G. G. Cabrera

1979-09-15T23:59:59.000Z

38

Inelastic exchange scattering in electron-energy-loss spectroscopy: Localized excitations in transition-metal and rare-earth systems  

Science Journals Connector (OSTI)

Cross sections for quasiatomic excitation by exchange scattering of electrons are calculated in the Born-Ochkur approximation for 3p-3d and 3d-3d transitions in transition-metal systems, and for 4d-4f and 4f-4f transitions in rare earths. The energy dependence of the spin polarization of 3p-3d and 4d-4f losses in reflection electron-energy-loss spectroscopy from ferromagnetic surfaces involves a balance of small-angle spin-dependent inelastic processes accompanied by a high-angle elastic scattering, and large-angle spin-flip exchange scattering without the need for elastic scattering. Both 3d-3d excitations, e.g., in transition-metal compounds, and 4f-4f excitations in rare earths involve spin-flip transitions whose scattering amplitudes g fall off with momentum transfer q such that the full width at half maximum q1/2 (in a.u.) is given by q1/2?rnl??2, where ?rnl? is the expectation value of r for the 3d or 4f electron. The angular width of the spin-flip differential cross section is then much greater than for dipole transitions, a pattern that helps to account for how these intra-atomic transitions compete with dipole processes for primary energies in excess of 100 eV.

S. J. Porter; J. A. D. Matthew; R. J. Leggott

1994-07-15T23:59:59.000Z

39

Synchrotron Diffraction Studies of Spontaneous Magnetostriction in Rare Earth Transition Metal Compounds  

SciTech Connect

Thermal expansion anomalies of R{sub 2}Fe{sub 14}B and R{sub 2}Fe{sub 17}C{sub x} (x = 0,2) (R = Y, Nd, Gd, Tb, Er) stoichiometric compounds are studied with high-energy synchrotron X-ray powder diffraction using Debye-Schemer geometry in temperature range 10K to 1000K. Large spontaneous magnetostriction up to their Curie temperatures (T{sub c}) is observed. The a-axes show relatively larger invar effects than c-axes in the R{sub 2}Fe{sub 14}B compounds whereas the R{sub 2}Fe{sub 17}C{sub x} show the contrary anisotropies. The iron sub-lattice is shown to dominate the spontaneous magnetostriction of the compounds. The contribution of the rare earth sublattice is roughly proportional to the spin magnetic moment of the rare earth in the R{sub 2}Fe{sub 14}B compounds but in R{sub 2}Fe{sub 17}C{sub x}, the rare earth sub-lattice contribution appears more likely to be dominated by the local bonding. The calculation of spontaneous magnetostrain of bonds shows that the bonds associated with Fe(j2) sites in R{sub 2}Fe{sub 14}B and the dumbbell sites in R{sub 2}Fe{sub 17}C{sub x} have larger values, which is strongly related to their largest magnetic moment and Wigner-Seitz atomic cell volume. The roles of the carbon atoms in increasing the Curie temperatures of the R{sub 2}Fe{sub 17} compounds are attributed to the increased separation of Fe hexagons. The R{sub 2}Fe{sub 17} and R{sub 2}Fe{sub 14}B phases with magnetic rare earth ions also show anisotropies of thermal expansion above T{sub c}. For R{sub 2}Fe{sub 17} and R{sub 2}Fe{sub 14}B the a{sub a}/a{sub c} > 1 whereas the anisotropy is reversed with the interstitial carbon in R{sub 2}Fe{sub 17}. The average bond magnetostrain is shown to be a possible predictor of the magnetic moment of Fe sites in the compounds. Both of the theoretical and phenomenological models on spontaneous magnetostriction are discussed and a Landau model on the spontaneous magnetostriction is proposed.

Ning Yang

2004-12-19T23:59:59.000Z

40

Model of thermally activated magnetization reversal in thin films of amorphous rare-earth-transition-metal alloys  

Science Journals Connector (OSTI)

Monte Carlo simulations on a two-dimensional lattice of magnetic dipoles have been performed to investigate the magnetic reversal by thermal activation in rare-earth-transition-metal (RE-TM) alloys. Three mechanisms of magnetization reversal were observed: nucleation dominated growth, nucleation followed by the growth of magnetic domains containing no seeds of unreversed magnetization, and nucleation followed by dendritic domain growth by successive branching in the motion of the domain walls. The domain structures are not fractal; however, the fractal dimension of the domain wall was found to be a good measure of the jaggedness of the domain boundary surface during the growth process. The effects of the demagnetizing field on the hysteretic and time-dependent properties of the thin films were studied and some limitations in the application of the Fatuzzo model on magneto-optic media are identified.

A. Lyberatos; J. Earl; R. W. Chantrell

1996-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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41

f-f excitations by resonant electron-exchange collisions in rare-earth metals  

Science Journals Connector (OSTI)

The spin-forbidden f-f multiplet excitations are observed for the first time as the strongest features in the electron-energy-loss spectra of Gd, Dy, and Sm metals at low primary-electron energies. The exchange nature of the excitation process is argued, in analogy with that of spin-flip Stoner excitations in d-band ferromagnets. A resonance enhancement observed for primary-electron energies near the 4d-4f core threshold is found to be consistent with the proposed mechanism.

S. Modesti; G. Paolucci; E. Tosatti

1985-12-30T23:59:59.000Z

42

IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La)  

SciTech Connect

This work presents an assessment of solubility data for rare earth metal fluorides (generally of trivalent metals and of CeF{sub 4}) in water and in aqueous ternary systems. Compilations of all available experimental data are introduced for each rare earth metal fluoride with a corresponding critical evaluation. Every such evaluation contains a collection of all solubility results in water, a selection of suggested solubility data, and a brief discussion of the multicomponent systems. Because the ternary systems were seldom studied more than once, no critical evaluations of such data were possible. Only simple fluorides (no complexes or binary salts) are treated as the input substances in this report. The literature has been covered through the end of 2013.

Mioduski, Tomasz [Institute of Nuclear Chemistry and Technology, 03195 Warsaw (Poland); Gumi?ski, Cezary, E-mail: cegie@chem.uw.edu.pl [Department of Chemistry, University of Warsaw, 02093 Warsaw (Poland); Zeng, Dewen, E-mail: dewen-zeng@hotmail.com [College of Chemistry and Chemical Engineering, Central South University, 410083 Changsha (China)

2014-03-15T23:59:59.000Z

43

Microstructural investigations of rare-earth transition-metal-based magnetocaloric materials for near-room-temperature applications  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

LOGO LOGO Spomenka Kobe, Paul McGuiness, Boris Saje Jožef Stefan Institute Rare-Earth Permanent Magnets in Europe KOLEKTOR *China's Complete Control of Global High-Tech Magnet Industry Rare-earth minerals are used in: rechargeable batteries (in camcorders), cell phones, PDAs, laptop computers and other portable devices.. wind turbines, drinking water filters, petrochemical catalysts, polishing powders, hydrogen storage, fluorescent lighting, flat panels, color televisions, glass, ceramics and automotive catalysts. fiberoptics, dental and surgical lasers, MRI systems, as medical contrast agents, in medical isotopes and in positron emission tomography scintillation detectors. magnetic refrigeration rechargeable batteries used in hybrid vehicles permanent magnets

44

Observation of coherent population transfer in a four-level tripod system with a rare-earth-metal-ion-doped crystal  

Science Journals Connector (OSTI)

Coherent population transfer in a laser-driven four-level system in a tripod configuration is experimentally investigated with a rare-earth-metal-ion-doped crystal (Pr3+:Y2SiO5). The population transfers observed here indicate that a main process inducing them is not optical pumping, which is an incoherent process inducing population transfer. Moreover, numerical simulation, which well reproduces the experimental results, also shows that the process inducing the observed population transfers is similar to stimulated Raman adiabatic passage (STIRAP) in the sense that this process possesses characteristic features of STIRAP.

Hayato Goto and Kouichi Ichimura

2007-03-15T23:59:59.000Z

45

JOURNAL DE PHYSIQUE Colloque C5, supplkment au no 5, Tome 40, Mai 1979, page C5-63 Heat capacity of rare earth metals near the melting point and the vacancy  

E-Print Network (OSTI)

of rare earth metals near the melting point and the vacancy mechanism of melting T. Gorecki (*) Max. -The vacancy mechanism of the melting process is utilized as a starting point for deriving the formula point and changes of the same properties of metals due to the creation of vacancies has been

Paris-Sud XI, Université de

46

Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen  

SciTech Connect

A series of organometallic compounds containing the tris(dimethylsilyl)methyl ligand are described. The potassium carbanions KC(SiHMe{sub 2}){sub 3} and KC(SiHMe{sub 2}){sub 3}TMEDA are synthesized by deprotonation of the hydrocarbon HC(SiHMe{sub 2}){sub 3} with potassium benzyl. KC(SiHMe{sub 2}){sub 3}TMEDA crystallizes as a dimer with two types of three-center-two-electron KH- Si interactions. Homoleptic Ln(III) tris(silylalkyl) complexes containing ?-SiH groups M{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) are synthesized from salt elimination of the corresponding lanthanide halide and 3 equiv. of KC(SiHMe{sub 2}){sub 3}. The related reactions with Sc yield bis(silylalkyl) ate-complexes containing either LiCl or KCl. The divalent calcium and ytterbium compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) are prepared from MI{sub 2} and 2 equiv of KC(SiHMe{sub 2}){sub 3}. The compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and La{C(SiHMe{sub 2}){sub 3}}{sub 3} react with 1 equiv of B(C{sub 6}F{sub 5}){sub 3} to give 1,3- disilacyclobutane {Me2Si-C(SiHMe2)2}2 and MC(SiHMe2)3HB(C6F5)3L, and La{C(SiHMe{sub 2}){sub 3}}{sub 2}HB(C{sub 6}F{sub 5}){sub 3}, respectively. The corresponding reactions of Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu) give the ?-SiH abstraction product [{(Me{sub 2}HSi){sub 3}C}{sub 2}LnC(SiHMe{sub 2}){sub 2}SiMe{sub 2}][HB(C{sub 6}F{sub 5}){sub 3}] (Ln = Y, Lu), but the silene remains associated with the Y or Lu center. The abstraction reactions of M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2 }or TMEDA) and Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) and 2 equiv of B(C{sub 6}F{sub 5}){sub 3} give the expected dicationic M{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and dicationic mono(silylalkyl) LnC(SiHMe{sub 2}){sub 3}{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2} (Ln = Y, Lu, La), respectively. Salt metathesis reactions of Cp{sub 2}(NR{sub 2})ZrX (X = Cl, I, OTf; R = t-Bu, SiHMe{sub 2}) and lithium hydrosilazide ultimately afford hydride products Cp{sub 2}(NR{sub 2})ZrH that suggest unusual ?-hydrogen elimination processes. A likely intermediate in one of these reactions, Cp{sub 2}Zr[N(SiHMe{sub 2})t-Bu][N(SiHMe{sub 2}){sub 2}], is isolated under controlled synthetic conditions. Addition of alkali metal salts to this zirconium hydrosilazide compound produces the corresponding zirconium hydride. However as conditions are varied, a number of other pathways are also accessible, including C-H/Si-H dehydrocoupling, ?-abstraction of a CH, and ?-abstraction of a SiH. Our observations suggest that the conversion of (hydrosilazido)zirconocene to zirconium hydride does not follow the classical four-center ?- elimination mechanism. Elimination and abstraction reactions dominate the chemistry of ligands containing ?- hydrogen. In contrast, Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}H and Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}Me undergo selective ?-CH bond activation to yield the azasilazirconacycle Cp{sub 2Zr}{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}}, even though there are reactive ?-hydrogen available for abstraction. The ?-SiH groups in metallacycle provide access to new pathways for sixteen-electron zirconium alkyl compounds, in which Cp{sub 2}Zr{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}} undergoes a rare ?-bond metathesis reaction with ethylene. The resulting vinyl intermediate undergoes ?-hydrogen abstraction to reform ethylene and a silanimine zirconium species that reacts with ethylene to give a metallacyclopentane as the isolated product. The pendent ?-SiH in metallocycle also reacts with paraformaldehyde through an uncatalyzed hydrosilylation to form an exocyclic methoxysilyl moiety, while the zirconium-carbon bond in metallocycle is surprisingly inert toward formaldehyde. Still, the Zr-C moiety in metallocycle is available for chemistry, and it interacts with the carbon monoxide and strong electrophile B(C{sub 6}F{sub 5}){sub 3} to provide Cp{sub 2}Zr[?{sup 2}- OC(=CH{sub 2})SiMeHN(SiHMe

Yan, Ka King [Ames Laboratory

2013-05-02T23:59:59.000Z

47

Superconductivity in Binary Alloy Systems of the Rare Earths and of Thorium with Pt-Group Metals  

Science Journals Connector (OSTI)

Superconductivity has been discovered in many binary systems composed of transition metals having nearly empty and nearly filled d shells. With the exception of the Sc-Pt and Ce-Rh systems, all contain at least one superconducting phase and frequently more. By comparing the transition temperatures of analogous compounds, it is inferred that pure Rh should become superconducting above 10 mdeg and pure Pt at a considerably lower temperature.

T. H. Geballe; B. T. Matthias; V. B. Compton; E. Corenzwit; G. W. Hull; Jr.; L. D. Longinotti

1965-01-04T23:59:59.000Z

48

Ground States of the Ising Model on the Shastry-Sutherland Lattice and the Origin of the Fractional Magnetization Plateaus in Rare-Earth-Metal Tetraborides  

Science Journals Connector (OSTI)

A complete and exact solution of the ground-state problem for the Ising model on the Shastry-Sutherland lattice in an applied magnetic field is found. The magnetization plateau at one third of the saturation value is shown to be the only possible fractional plateau in this model. However, stripe magnetic structures with 1/2 and 1/n (n>3) magnetization, observed in the rare-earth-metal tetraborides RB4, occur at the boundaries of the three-dimensional regions of the ground-state phase diagram. These structures give rise to new magnetization plateaus if interactions of longer range are taken into account. For instance, an additional third-neighbor interaction is shown to produce a 1/2 plateau. The results obtained significantly refine the understanding of the magnetization process in RB4 compounds, especially in TmB4 and ErB4, which are strong Ising magnets.

Yu. I. Dublenych

2012-10-16T23:59:59.000Z

49

Improved method for preparing rare earth sesquichalcogenides  

DOE Patents (OSTI)

An improved method for the preparation of high purity rare earth sesquichalcogenides is described. The rare earth, as one or more pieces of the metal, is sealed under a vacuum with a stoichiometric amount of sulfur or selenium and a small amount of iodine into a quartz reaction vessel. The sealed vessel is then heated to above the vaporization temperature of the chalcogen and below the melting temperature of the rare earth metal and maintained until the product has been formed. The iodine is then vaporized off leaving a pure product. The rare earth sulfides and selenides thus formed are useful as semiconductors and as thermoelectric generators. 3 tables.

Takeshita, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

1982-04-14T23:59:59.000Z

50

Rare Earth Tungsten Bronzes  

Science Journals Connector (OSTI)

Rare Earth Tungsten Bronzes ... Trivalent Rare Earth Ion Conduction in the Rare Earth Tungstates with the Sc2(WO4)3-Type Structure ... Trivalent Rare Earth Ion Conduction in the Rare Earth Tungstates with the Sc2(WO4)3-Type Structure ...

Werner Ostertag

1966-05-01T23:59:59.000Z

51

Au/MxOy/TiO2 catalysts for CO oxidation: promotional effect of main-group, transition, and rare-earth metal oxide additives.  

SciTech Connect

Au/TiO2 catalysts are active for CO oxidation, but they suffer from high-temperature sintering of the gold particles, and few attempts have been made to promote or stabilize Au/TiO2. Our recent communication addressed these issues by loading gold onto Al2O3/TiO2 prepared via surface-sol-gel processing of Al(sec-OC4H9)3 on TiO2. In our current full paper, Au/Al2O3/TiO2 catalysts were prepared alternatively by thermal decomposition of Al(NO3)3 on TiO2 followed by loading gold, and the influences of the decomposition temperature and Al2O3 content were systematically surveyed. This facile method was subsequently extended to the preparation of a battery of metal oxide-modified Au/TiO2 catalysts virtually not reported. It was found that Au/TiO2 modified by CaO, NiO, ZnO, Ga2O3, Y2O3, ZrO2, La2O3, Pr2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, Dy2O3, Ho2O3, Er2O3, or Yb2O3 could retain significant activity at ambient temperature even after aging in O2-He at 500 C, whereas unmodified Au/TiO2 lost its activity. Moreover, some 200 C-calcined promoted catalysts showed high activity even at about -100 C. The deactivation and regeneration of some of these new catalysts were studied. This work furnished novel catalysts for further fundamental and applied research.

Ma, Zhen [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2007-01-01T23:59:59.000Z

52

Material efficiency: rare and critical metals  

Science Journals Connector (OSTI)

...obvious in the case of hydrocarbons. But we do not contemplate the recycling of hydrocarbons except perhaps in terms...destructive uses, such as combustion of hydrocarbons, the service is usually...chemical potential, heat (or light) that is...

2013-01-01T23:59:59.000Z

53

Material efficiency: rare and critical metals  

Science Journals Connector (OSTI)

...PhD thesis, Fakulteit Scheikunde, University of Utrecht, Utrecht, The Netherlands. 12 Karlsson, S , C Azar, G Bernedes...gas emissions. PhD thesis, Fakultgeit Scheikunde, Utrecht University, Utrecht, The Netherlands. 18 Matthews...

2013-01-01T23:59:59.000Z

54

New ternary rare-earth metal boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Y, Gd-Lu) containing BC{sub 2} units: Crystal and electronic structures, magnetic properties  

SciTech Connect

The ternary rare-earth boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Y, Gd-Lu) were prepared from the elements by arc-melting followed by annealing in silica tubes at 1270 K for 1 month. The crystal structures of Tb{sub 15}B{sub 4}C{sub 14} and Er{sub 15}B{sub 4}C{sub 14} were determined from single crystal X-ray diffraction data. They crystallize in a new structure type in space group P4/mnc (Tb{sub 15}B{sub 4}C{sub 14}: a=8.1251(5) A, c=15.861(1) A, Z=2, R{sub 1}=0.041 (wR{sub 2}=0.088) for 1023 reflections with I{sub o}>2{sigma}(I{sub o}); Er{sub 15}B{sub 4}C{sub 14}: a=7.932(1) A, c=15.685(2) A, Z=2, R{sub 1}=0.037 (wR{sub 2}=0.094) for 1022 reflections with I{sub o}>2{sigma}(I{sub o})). The crystal structure contains discrete carbon atoms and bent CBC units in octahedra and distorted bicapped square antiprisms, respectively. In both structures the same type of disorder exists. One R atom position needs to be refined as split atom position with a ratio 9:1 indicative of a 10% substitution of the neighboring C{sup 4-} by C{sub 2}{sup 4-}. The actual composition has then to be described as R{sub 15}B{sub 4}C{sub 14.2}. The isoelectronic substitution does not change the electron partition of R{sub 15}B{sub 4}C{sub 14} which can be written as (R{sup 3+}){sub 15}(C{sup 4-}){sub 6}(CBC{sup 5-}){sub 4{center_dot}}e{sup -}. The electronic structure was studied with the extended Hueckel method. The investigated compounds Tb{sub 15}B{sub 4}C{sub 14}, Dy{sub 15}B{sub 4}C{sub 14} and Er{sub 15}B{sub 4}C{sub 14} are hard ferromagnets with Curie temperatures T{sub C}=145, 120 and 50 K, respectively. The coercive field B{sub C}=3.15 T for Dy{sub 15}B{sub 4}C{sub 14} is quite remarkable. - Graphical abstract: The ternary rare earth boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Y, Gd-Lu) were prepared from the elements by arc-melting followed by annealing in silica tubes at 1270 K for 1 month. Tb{sub 15}B{sub 4}C{sub 14} is a new member of the rare-earth metal boride carbide series in which the finite quasi-molecular CBC entities as well as isolated C atoms are embedded in the voids of the metal atom matrix. The structure of Tb{sub 15}B{sub 4}C{sub 14} contains two types of slabs: one slab contains finite bent CBC units and isolated carbon atoms whereas another is formed only from octahedral coordinated single carbon atoms. The electronic structure for the idealized composition corresponds to an electron partitioning according to (Tb{sup 3+}){sub 15}(C{sup 4-}){sub 6}(CBC{sup 5-}){sub 4{center_dot}}e{sup -} giving rise to a single electron per formula for Tb-Tb framework bonding. The magnetism of the ternary rare earth boride carbides R{sub 15}B{sub 4}C{sub 14} (R=Tb, Dy, Er) is characterized by the onset of ferromagnetic order below T<150 K.

Babizhetskyy, Volodymyr, E-mail: v.babizhetskyy@fkf.mpg.d [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, Postfach 800665, D-70569 Stuttgart (Germany); Simon, Arndt; Mattausch, Hansjuergen [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, Postfach 800665, D-70569 Stuttgart (Germany); Hiebl, Kurt [Arbeitsgruppe Neue Materialien, Universitaet Wien, Waehringerstrasse 42, A-1090 Wien (Austria); Zheng Chong [Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL 60115 (United States)

2010-10-15T23:59:59.000Z

55

Rare muon processes  

SciTech Connect

The status of rare muon processes as tests of the standard model is reviewed with the emphasis on results that are expected from experiments in the near future.

Cooper, M.D.; The MEGA Collaboration

1993-05-01T23:59:59.000Z

56

Rare muon processes  

SciTech Connect

The status of rare muon processes as tests of the standard model is reviewed with the emphasis on results that are expected from experiments in the near future.

Cooper, M.D.

1993-01-01T23:59:59.000Z

57

AnnaFrebel! metal-poorstars!  

E-Print Network (OSTI)

-process element pattern!! #12;AnnaFrebel! metal-poorstars! New oscillator strengths of rare earth elements!! · Sneden, Lawler et al. 2009: New Rare Earth Element Abundance Distributions for the Sun and Five r-Process-Rich, Metal-Poor Stars, and Rare Earth Lab Data Summary · Lawler, Sneden et al. 2008: Improved Laboratory

58

Synthesis and luminescence properties of rare earth activated phosphors for near UV-emitting LEDs for efficacious generation of white light  

E-Print Network (OSTI)

of R 2 SiO 5 (R = rare earth elements)?, Mater. Res. Bull.QE Quantum Efficiency RE Rare Earth Elements RGB Red, green,transition metal or rare earth elements. The standard

Han, Jinkyu

2013-01-01T23:59:59.000Z

59

Critical Materials and Rare Futures: Ames Laboratory Signs a New Agreement  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Critical Materials and Rare Futures: Ames Laboratory Signs a New Critical Materials and Rare Futures: Ames Laboratory Signs a New Agreement on Rare-Earth Research Critical Materials and Rare Futures: Ames Laboratory Signs a New Agreement on Rare-Earth Research June 15, 2011 - 7:07pm Addthis The plasma torch in the Retech plasma furnace is one tool used in Materials Preparation Center to create ultra-high purity metal alloy samples, particularly rare-earth metals, located at the Ames Lab. | Photo Courtesy of the Ames Lab Flickr The plasma torch in the Retech plasma furnace is one tool used in Materials Preparation Center to create ultra-high purity metal alloy samples, particularly rare-earth metals, located at the Ames Lab. | Photo Courtesy of the Ames Lab Flickr Charles Rousseaux Charles Rousseaux Senior Writer, Office of Science

60

DOE - Office of Legacy Management -- Vitro Corp of America - TN 04  

Office of Legacy Management (LM)

TN 04 TN 04 FUSRAP Considered Sites Site: Vitro Corp. of America (TN.04) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Heavy Minerals Company Vitro Chemical Company TN.04-4 TN.04-5 Location: 4000 North Hawthorne Street , Chattanooga , Tennessee TN.04-5 Evaluation Year: 1990 TN.04-1 Site Operations: Processed mineral monazite to produce a thorium-uranium hydroxide and a series of rare earth products. TN.04-4 Site Disposition: Eliminated - Site licensed by AEC and State of Tennessee - No Authority to perform remedial action under FUSRAP TN.04-2 TN.04-3 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Thorium Metal, ThF4, Thorium Oxide TN.04-1 Radiological Survey(s): None Indicated

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Rare Earth Elements:  

Science Journals Connector (OSTI)

...Energy-efficient compact fluorescent lamps (CFLs) use phosphor...LEDs), and compact fluorescent lamps (CFLs) all utilize...conventional incandescent light bulbs with CFLs in numerous...rare earth industry and led to significant price...previous year. This led to significant price...

Gareth P. Hatch

62

Rare hadronic B decays  

E-Print Network (OSTI)

Rare hadronic B-meson decays allow us to study CP violation. The class of B decays final states containing two vector mesons provides a rich set of angular correlation observables to study. This article reviews some of the recent experimental results from the BaBar and Belle collaborations.

A. J. Bevan

2006-06-02T23:59:59.000Z

63

Ames Lab 101: Rare Earths  

ScienceCinema (OSTI)

"Mr. Rare Earth," Ames Laboratory scientist Karl Gschneidner Jr., explains the importance of rare-earth materials in many of the technologies we use today -- ranging from computers to hybrid cars to wind turbines. Gschneidner is a world renowned rare-earths expert at the U.S. Department of Energy's Ames Laboratory.

Gschneidner, Karl

2012-08-29T23:59:59.000Z

64

Rare-Earth Research Meeting  

Science Journals Connector (OSTI)

Rare-Earth Research Meeting ... The 27th Rare Earth Research Conference will take place at the Village at Squaw Valley in Olympic Valley, Calif.—the site of the 1960 Winter Olympic Games—on June 22–26, 2014. ... Rare-earth element research spans several disciplines and brings together chemists, engineers, physicists, and materials scientists. ...

SOPHIE ROVNER

2013-12-23T23:59:59.000Z

65

Rare Earth Elements:  

Science Journals Connector (OSTI)

...aegirine, magnetite and hematite; and (3) a massive central iron oxide facies containing 3 wt% REE2O3 (Chao et al. 1992...for several bivalent metal ions and cerium(III) with the acetylacetonate ion. Journal of Physical Chemistry 59: 235-237 Lehmann...

Anthony E. Williams-Jones; Artashes A. Migdisov; Iain M. Samson

66

The Colorado Rare Plant Technical Committee Rare Plant Symposium  

E-Print Network (OSTI)

The Colorado Rare Plant Technical Committee presents: 4th Annual Rare Plant Symposium Sponsored by: Colorado Native Plant Society University of Colorado Herbarium US Fish and Wildlife Service Colorado: G2G3/S2S3 Global distribution: Colorado (Larimer and Boulder counties). Possibly extending

67

Replacing the Rare Earth Intellectual Capital  

SciTech Connect

The rare earth crisis slowly evolved during a 10 to 15 year period beginning in the mid-1980s, when the Chinese began to export mixed rare earth concentrates. In the early 1990s, they started to move up the supply chain and began to export the individual rare earth oxides and metals. By the late 1990s the Chinese exported higher value products, such as magnets, phosphors, polishing compounds, catalysts; and in the 21st century they supplied finished products including electric motors, computers, batteries, liquid-crystal displays (LCDs), TVs and monitors, mobile phones, iPods and compact fluorescent lamp (CFL) light bulbs. As they moved to higher value products, the Chinese slowly drove the various industrial producers and commercial enterprises in the US, Europe and Japan out of business by manipulating the rare earth commodity prices. Because of this, the technically trained rare earth engineers and scientists who worked in areas from mining to separations, to processing to production, to manufacturing of semifinished and final products, were laid-off and moved to other fields or they retired. However, in the past year the Chinese have changed their philosophy of the 1970s and 1980s of forming a rare earth cartel to control the rare earth markets to one in which they will no longer supply the rest of the world (ROW) with their precious rare earths, but instead will use them internally to meet the growing demand as the Chinese standard of living increases. To this end, they have implemented and occasionally increased export restrictions and added an export tariff on many of the high demand rare earth elements. Now the ROW is quickly trying to start up rare earth mines, e.g. Molycorp Minerals in the US and Lynas Corp. in Australia, to cover this shortfall in the worldwide market, but it will take about five years for the supply to meet the demand, even as other mines in the ROW become productive. Unfortunately, today there is a serious lack of technically trained personnel to bring the entire rare earth industry, from mining to original equipment manufacturers (OEM), up to full speed in the next few years. Accompanying this decline in technical expertise, innovation and new products utilizing rare earth elements has slowed dramatically, and it may take a decade or more to recapture America's leading role in technological advancements of rare earth containing products. Before the disruption of the US rare earth industry, about 25,000 people were employed in all aspects of the industry from mining to OEM. Today, only about 1,500 people are employed in these fields. The ratio of non-technically trained persons to those with college degrees in the sciences or engineering varies from about 8 to 1 to about 4 to 1, depending on the particular area of the industry. Assuming an average of 6 to 1, the number of college degree scientists and engineers has decreased from about 4,000 to 250 employed today. In the magnetic industry the approximate numbers are: 6,000 total with 750 technically trained people in the 1980s to 500 totally employed today of which 75 have degrees. The paucity of scientists and engineers with experience and/or training in the various aspects of production and commercialization of the rare earths is a serious limitation to the ability of the US to satisfy its own needs for materials and technologies (1) to maintain our military strength and posture, (2) to assume leadership in critical energy technologies, and (3) to bring new consumer products to the marketplace. The lack of experts is of even greater national importance than the halting in the 1990s and the recent restart of the mining/benification/separation effort in the US; and thus governmental intervention and support for at least five to 10 years will be required to ameliorate this situation. To respond quickly, training programs should be established in conjunction with a national research center at an educational institution with a long tradition in multiple areas of rare earth and other critical elements research and technology. This center should

Gschneidner, Jr., Karl

2011-04-01T23:59:59.000Z

68

Transition-Metal Hydrides  

NLE Websites -- All DOE Office Websites (Extended Search)

Transition-Metal Hydride Electrochromics Transition-Metal Hydride Electrochromics A new type of electrochromic hydride material has interesting and unusual properties. Thin Ni-Mg films, for example, are mirror-like in appearance and have very low visible transmittance. On exposure to hydrogen gas or on reduction in alkaline electrolyte, the films become transparent. The transition is believed to result from formation of nickel magnesium hydride, Mg2NiH4. Switchable mirrors based on rare earth hydrides were discovered in 1996 at Vrije University in the Netherlands, Rare earth-magnesium alloy films were subsequently found to be superior to the pure lanthanides in maximum transparency and mirror-state reflectivity by Philips Laboratories. The newer transition-metal types which use less expensive and less reactive materials were discovered at LBNL. This has now become a very active area of study with a network of researchers.

69

Change of magnetic and electronic features through subtle substitution in cubic, non-centrosymmetric extended rare-earth metal cluster complexes (TR{sub 3})X{sub 3}  

SciTech Connect

The new compound (IrCe{sub 3})I{sub 3} was synthesized by comproportionation reactions of stoichiometric ratios of CeI{sub 3}, Ce and Ir. Single crystal X-ray diffraction structure determination shows that (IrCe{sub 3})I{sub 3} crystallizes with the cubic variant of the (TR{sub 3})X{sub 3} family (I4{sub 1}32, Z=8, a=12.450(1) Å, V=1930.0(3) Å{sup 3}) and is isostructural with the recently reported (RuLa{sub 3})Br{sub 3}. Octahedral (IrCe{sub 6}) clusters share three common edges forming interpenetrating chains that run along the 4{sub 1} screw axes. Magnetic measurements on pure powder samples of (IrCe{sub 3})I{sub 3} show paramagnetic behavior and, at temperatures below 2 K, a mictomagnetic state. The isostructural (RuLa{sub 3})Br{sub 3} is a Pauli paramagnet suggesting metallic conductivity which is consistent with band structure calculations where the Fermi level is placed below a pseudogap. For (IrCe{sub 3})I{sub 3}, on the contrary, the Fermi level falls in a narrow gap rather than a pseudogap suggesting activated conductivity. - Graphical abstract: The subtle change from (RuLa{sub 3})Br{sub 3} to (IrCe{sub 3})I{sub 3} (IrCe{sub 3})I{sub 3} with the addition of one 5d and one 4f electron changes the magnetic and electronic properties dramatically; (RuLa{sub 3})Br{sub 3} is a Pauli paramagnet, (IrCe{sub 3})I{sub 3} a Langevin paramagnet with mictomagnetic behavior at very low temperatures. Display Omitted.

Steinberg, Simon [Department für Chemie, Institut für Anorganische Chemie, Universität zu Köln, Greinstraße 6, 50939 Köln (Germany); Valldor, Martin [II. Physikalisches Institut, Universität zu Köln, Zülpicher Straße 77, 50937 Köln (Germany); Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Straße 40, 01187 Dresden (Germany); Meyer, Gerd, E-mail: gerd.meyer@uni-koeln.de [Department für Chemie, Institut für Anorganische Chemie, Universität zu Köln, Greinstraße 6, 50939 Köln (Germany)

2013-10-15T23:59:59.000Z

70

E-Print Network 3.0 - alkali metal alkaline Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

with alkali-metals 9, loi, alkaline earth metals l,18 and some of other rare-earth elements 19, 20 have... alkali metals were doped into C60 solids 9 and...

71

Vivapure Metal Chelate Mega spin columns  

E-Print Network (OSTI)

®® Vivapure Metal Chelate Mega spin columns Hisn Technical data and operating instructions. For in vitro use only. #12;2 Handling overview Vivapure Metal Chelate Mega spin columns - for the purification of proteins with poly-histidine tags Storage conditions Vivapure Metal Chelate Mega spin columns can be stored

Lebendiker, Mario

72

UK bridge to rare tongues  

E-Print Network (OSTI)

  THE TELEGRAPH - About Us - Advertise - Feedback - Contact Us     /div> 2 Front Page > Nation > Story UK bridge to rare tongues London, Dec. 12 (PTI): Cambridge University has launched a project to provide public access to languages...

Anon.

2010-12-13T23:59:59.000Z

73

PRESS RELEASE RARE FRUIT CONFERENCE  

E-Print Network (OSTI)

RELEASE RARE FRUIT CONFERENCE July 9 - 13, 2014 Sponsored by the Tropical Fruit & Vegetable Society of the Redland & the Fruit & Spice Park 24801 SW 187th Avenue, Homestead, Florida

Jawitz, James W.

74

A Rare Isolated Trapezoid Fracture  

E-Print Network (OSTI)

wrist in suggested scaphoid fracture. Acta Radiol. 1988;29:Rare isolated trapezoid fracture: a case report. Hand. 2008;suspect and diagnose this fracture. 2,8 REFERENCES 1. Papp

Afifi, Negean; Lu, Jenny J

2011-01-01T23:59:59.000Z

75

Silicon Shovels for Rare-Earth Solutions  

Office of Science (SC) Website

the uses for rare-earths, but the mined and processed totals are falling short. Green energy technology needs rare earth materials for wind turbines, rechargeable...

76

Research on feline in vitro maturation and the cell cycle  

E-Print Network (OSTI)

species. Very little is known about these species; and if they become extinct, we may not have the chance to leam more about them. Tissues from nondomestic cats are not readily available. 'I'herefore, studies are performed on tissues from domestic cats... in the hope that the infomiation gained can be transferred on to the rare species. Reproductive techniques developed for the domestic cat, such as in vitro maturation, in vitro fertilization, and embryo transfer, can potentially be applied to endangered...

Cox, Ashley Michelle

2013-02-22T23:59:59.000Z

77

Self-assembled rare-earth silicide nanowires on Si(001)  

SciTech Connect

This paper presents scanning tunneling microscope images of several rare-earth metal silicides grown on silicon (001). For certain of the metals studied (Dy, Ho), an anisotropy in lattice match with the substrate results in the formation of nanowires. These nanowires have desirable properties such as nanometer lateral dimension, crystalline structure with a low density of defects, and micrometer scale length. Tunneling spectroscopy on the nanowires indicates that they are metallic.

Nogami, J.; Liu, B. Z.; Katkov, M. V.; Ohbuchi, C.; Birge, Norman O.

2001-06-15T23:59:59.000Z

78

Ultracold chemistry with alkali-metal-rare-earth molecules  

E-Print Network (OSTI)

A first principles study of the dynamics of $^6$Li($^{2}$S) + $^6$Li$^{174}$Yb($^2\\Sigma^+$)$ \\to ^6$Li$_2(^1\\Sigma^+$) + $^{174}$Yb($^1$S) reaction is presented at cold and ultracold temperatures. The computations involve determination and analytic fitting of a three-dimensional potential energy surface for the Li$_2$Yb system and quantum dynamics calculations of varying complexities, ranging from exact quantum dynamics within the close-coupling scheme, to statistical quantum treatment, and universal models. It is demonstrated that the two simplified methods yield zero-temperature limiting reaction rate coefficients in reasonable agreement with the full close-coupling calculations. The effect of the three-body term in the interaction potential is explored by comparing quantum dynamics results from a pairwise potential that neglects the three-body term to that derived from the full interaction potential. Inclusion of the three-body term in the close-coupling calculations was found to reduce the limiting rate coefficients by a factor of two. The reaction exoergicity populates vibrational levels as high as $v=19$ of the $^6$Li$_2$ molecule in the limit of zero collision energy. Product vibrational distributions from the close-coupling calculations reveal sensitivity to inclusion of three-body forces in the interaction potential. Overall, the results indicate that a simplified model based on the long-range potential is able to yield reliable values of the total reaction rate coefficient in the ultracold limit but a more rigorous approach based on statistical quantum or quantum close-coupling methods is desirable when product rovibrational distribution is required.

C. Makrides; J. Hazra; G. B. Pradhan; A. Petrov; B. K. Kendrick; T. González-Lezana; N. Balakrishnan; S. Kotochigova

2014-10-28T23:59:59.000Z

79

Ultracold chemistry with alkali-metal-rare-earth molecules  

E-Print Network (OSTI)

A first principles study of the dynamics of $^6$Li($^{2}$S) + $^6$Li$^{174}$Yb($^2\\Sigma^+$)$ \\to ^6$Li$_2(^1\\Sigma^+$) + $^{174}$Yb($^1$S) reaction is presented at cold and ultracold temperatures. The computations involve determination and analytic fitting of a three-dimensional potential energy surface for the Li$_2$Yb system and quantum dynamics calculations of varying complexities, ranging from exact quantum dynamics within the close-coupling scheme, to statistical quantum treatment, and universal models. It is demonstrated that the two simplified methods yield zero-temperature limiting reaction rate coefficients in reasonable agreement with the full close-coupling calculations. The effect of the three-body term in the interaction potential is explored by comparing quantum dynamics results from a pairwise potential that neglects the three-body term to that derived from the full interaction potential. Inclusion of the three-body term in the close-coupling calculations was found to reduce the limiting rate ...

Makrides, C; Pradhan, G B; Petrov, A; Kendrick, B K; González-Lezana, T; Balakrishnan, N; Kotochigova, S

2014-01-01T23:59:59.000Z

80

Stabilization of Electrocatalytic Metal Nanoparticles at Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Metal Aminoboranes  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal Aminoboranes Metal Aminoboranes Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. June 25, 2013 Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Available for thumbnail of Feynman Center (505) 665-9090 Email Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit. U.S. Patent No.: 7,713,506 (DOE S-112,798)

82

Watch a Rare Earth Elements Event Live This Morning | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Watch a Rare Earth Elements Event Live This Morning Watch a Rare Earth Elements Event Live This Morning Watch a Rare Earth Elements Event Live This Morning December 15, 2010 - 9:20am Addthis Ginny Simmons Ginny Simmons Former Managing Editor for Energy.gov, Office of Public Affairs From 9:30am to noon ET today you can tune into a live discussion on "rare earth materials" that are critical to the production of clean energy technologies. Tune in here. The Department of Energy's Assistant Secretary for Policy and International Affairs David Sandalow will give the keynote, speaking to the role of rare earth metals and other materials in the clean energy economy. You can check back to the Energy Blog for more info later today. Ginny Simmons is a New Media Specialist and contractor to the Office of Public Affairs.

83

Watch a Rare Earth Elements Event Live This Morning | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Watch a Rare Earth Elements Event Live This Morning Watch a Rare Earth Elements Event Live This Morning Watch a Rare Earth Elements Event Live This Morning December 15, 2010 - 9:20am Addthis Ginny Simmons Ginny Simmons Former Managing Editor for Energy.gov, Office of Public Affairs From 9:30am to noon ET today you can tune into a live discussion on "rare earth materials" that are critical to the production of clean energy technologies. Tune in here. The Department of Energy's Assistant Secretary for Policy and International Affairs David Sandalow will give the keynote, speaking to the role of rare earth metals and other materials in the clean energy economy. You can check back to the Energy Blog for more info later today. Ginny Simmons is a New Media Specialist and contractor to the Office of Public Affairs.

84

An Equilibrium Model of Rare Event Premia  

E-Print Network (OSTI)

In this paper, we study the asset pricing implication of imprecise knowledge about rare events. Modeling rare events as jumps in the aggregate endowment, we explicitly solve the equilibrium asset prices in a pure-exchange ...

Liu, Jun

2002-08-12T23:59:59.000Z

85

Rare Iron Oxide in Ancient Chinese Pottery  

NLE Websites -- All DOE Office Websites (Extended Search)

Rare Iron Oxide in Ancient Chinese Pottery Rare Iron Oxide in Ancient Chinese Pottery Print Friday, 26 September 2014 14:37 Jian ware (or Tenmoku) ceramic bowls, famous for their...

86

Novel rare earth boron-rich solids  

SciTech Connect

A new series of boron-rich solids ReB{sub 22}C{sub 2}N (Re: Y, Ho, Er, Tm, Lu) was synthesized by traditional solid-state reaction. The crystal structure of the representative compound YB{sub 22}C{sub 2}N was solved by direct method from powder X-ray diffraction (XRD) data and transmission electron microscope (TEM) analysis. The unit cell of the new structure is rhombohedral with space group R-3m (No. 166), lattice constant a = b = 5.623(0) {angstrom} and c = 44.785(3) {angstrom} with six formula units in one unit cell. The atoms of boron in the solids, like most of the boron-rich solids, exist with icosahedral and octahedral clusters, and the whole crystal shows a layered structure. The interconnected nine layers of icosahedron and three layers of octahedron in a unit cell build the whole framework of the new phase and rare earth metal atoms reside in voids of the octahedron layers. The neighboring icosahedral layers link through C-B-C chains besides the direct bonding of B-B. Both experimental and structural analysis indicated that the nitrogen atoms in the new phase can be replaced with carbon.

Zhang, Fuxiang; Leithe-Jasper, Andreas; Xu, Jun; Mori, Takao; Matsui, Yoshio, Tanaka, Takaho; Okada, Shigeru

2001-06-01T23:59:59.000Z

87

The Colorado Rare Plant Technical Committee presents: Colorado Rare Plant Symposium  

E-Print Network (OSTI)

The Colorado Rare Plant Technical Committee presents: 5th Annual Colorado Rare Plant Symposium September 5, 2008 Montrose, Colorado Sponsored by: Colorado Rare Plant Technical CommitteeColorado Rare Plant Technical Committee Colorado Native Plant Society University of Colorado Herbarium US Fish

88

The Colorado Rare Plant Technical Committee presents: 2nd Annual Rare Plant  

E-Print Network (OSTI)

The Colorado Rare Plant Technical Committee presents: 2nd Annual Rare Plant Symposium Friday, September 16th, 2005 8am-noon: 2nd Annual Colorado Rare Plant Symposium (Discuss G1 species) 6:30-7:30pm with the Colorado Native Plant Society's Annual Meeting Sponsored by: #12;The Second Annual Colorado Rare Plant

89

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2009. All  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was not mined in the United States in 2009. All yttrium. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad. Other rare-earth compounds, including yttrium oxide >85% Y2O3, yttrium nitrate, and other individual

90

[Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted] Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2010. All  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was not mined in the United States in 2010. All yttrium. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5.0% ad. Other rare-earth compounds, including yttrium oxide >85% Y2O3, yttrium nitrate, and other individual

91

(Data in metric tons of yttrium oxide (Y2O3) content, unless noted) Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network (OSTI)

Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

92

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2008. All  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was not mined in the United States in 2008. All yttrium 12-31-08 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and compounds containing by weight >19% to rare-earth compounds, including

93

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2006. All  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was not mined in the United States in 2006. All yttrium-31-06 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium and compounds containing by weight >19% to rare-earth compounds, including

94

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2003.  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was not mined in the United States in 2003. Yttrium Relations 12/31/03 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and compounds containing by weight >19% to rare-earth compounds, including

95

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network (OSTI)

Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth.20.0000 Free Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805

96

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2004. Yttrium  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was not mined in the United States in 2004. Yttrium Relations 12-31-04 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and compounds containing by weight >19% to rare-earth compounds, including

97

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite,  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed

98

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral  

E-Print Network (OSTI)

Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5

99

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network (OSTI)

Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth/31/96 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

100

(Data in metric tons of yttrium oxide (Y2O3) content unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was not mined in the United States in 2005. All  

E-Print Network (OSTI)

Production and Use: The rare-earth element yttrium was not mined in the United States in 2005. All yttrium-31-05 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium and compounds containing by weight >19% to rare-earth compounds, including

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite,  

E-Print Network (OSTI)

Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth/31/98 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

102

Mixed Conduction in Rare-Earth Phosphates  

E-Print Network (OSTI)

their  metal  to  phosphorous  ratio  can  be  varied;  materials,   as   the   phosphorous   to   metal   ratio  tetrahedron.    As   the  phosphorous  content  of  the  

Ray, Hannah Leung

2012-01-01T23:59:59.000Z

103

Development of a metal hydride electrode waste treatment process  

SciTech Connect

Manufacturing residues of metal hydride electrodes for nickel - metal hydride batteries were chemically processed to recover the metal part and heat treated for the organic part. Chemical recovery yielded Ni-Co alloy after electrolysis of the solution and hydroxides of other metal, mainly rare earths. The organic part, pyrolyzed at 700 C, led to separation between carbon and fluorinated matter. Infrared coupling at the output of the pyrolysis furnace was used to identify the pyrolysis gases.

Bianco, J.C.; Martin, D.; Ansart, F.; Castillo, S.

1999-12-01T23:59:59.000Z

104

Exploration of R2XM2 (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge): Structural Motifs, the novel Compound Gd2AlGe2 and Analysis of the U3Si2 and Zr3Al2 Structure Types  

SciTech Connect

In the process of exploring and understanding the influence of crystal structure on the system of compounds with the composition Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} several new compounds were synthesized with different crystal structures, but similar structural features. In Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, the main feature of interest is the magnetocaloric effect (MCE), which allows the material to be useful in magnetic refrigeration applications. The MCE is based on the magnetic interactions of the Gd atoms in the crystal structure, which varies with x (the amount of Si in the compound). The crystal structure of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} can be thought of as being formed from two 3{sup 2}434 nets of Gd atoms, with additional Gd atoms in the cubic voids and Si/Ge atoms in the trigonal prismatic voids. Attempts were made to substitute nonmagnetic atoms for magnetic Gd using In, Mg and Al. Gd{sub 2}MgGe{sub 2} and Gd{sub 2}InGe{sub 2} both possess the same 3{sup 2}434 nets of Gd atoms as Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, but these nets are connected differently, forming the Mo{sub 2}FeB{sub 2} crystal structure. A search of the literature revealed that compounds with the composition R{sub 2}XM{sub 2} (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge) crystallize in one of four crystal structures: the Mo{sub 2}FeB{sub 2}, Zr{sub 3}Al{sub 2}, Mn{sub 2}AlB{sub 2} and W{sub 2}CoB{sub 2} crystal structures. These crystal structures are described, and the relationships between them are highlighted. Gd{sub 2}AlGe{sub 2} forms an entirely new crystal structure, and the details of its synthesis and characterization are given. Electronic structure calculations are performed to understand the nature of bonding in this compound and how electrons can be accounted for. A series of electronic structure calculations were performed on models with the U{sub 3}Si{sub 2} and Zr{sub 3}Al{sub 2} structures, using Zr and A1 as the building blocks. The starting point for these models was the U{sub 3}Si{sub 2} structure, and models were created to simulate the transition from the idealized U{sub 3}Si{sub 2} structure to the distorted Zr{sub 3}Al{sub 2} structure. Analysis of the band structures of the models has shown that the transition from the U{sub 3}Si{sub 2} structure to the Zr{sub 3}Al{sub 2} structure lifts degeneracies along the {Lambda} {yields} Z direction, indicating a Peierls-type mechanism for the displacement occurring in the positions of the Zr atoms.

Sean William McWhorter

2006-05-01T23:59:59.000Z

105

Metal inks  

DOE Patents (OSTI)

Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

2014-02-04T23:59:59.000Z

106

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

107

DOE - Office of Legacy Management -- Ferro Metal and Chemical...  

Office of Legacy Management (LM)

- Ferro Metal & Chemical Corp. Letter; Schloss to the Vitro Mfg. Co.; Request for Price Quote; November 15, 1944 NY.42-2 - DOE MemorandumChecklist; Wallo to File; Subject:...

108

Rare is frequent and frequent is costly: rare diseases as a challenge for health care systems  

Science Journals Connector (OSTI)

Of 30,000 known diseases about 6,000–7,000 are defined as rare diseases, also commonly known as orphan diseases [1]. Within the European Union (EU), rare diseases are specified as indications with a prevalence of...

J.-Matthias Graf von der Schulenburg…

2014-10-01T23:59:59.000Z

109

Silicone metalization  

DOE Patents (OSTI)

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2006-12-05T23:59:59.000Z

110

The Colorado Rare Plant Technical Committee presents  

E-Print Network (OSTI)

The Colorado Rare Plant Technical Committee presents: 3rd Annual Rare Plant Symposium Sponsored by: Colorado Native Plant Society University of Colorado Herbarium US Fish and Wildlife Service Colorado and Eastern Colorado (Las Animas, Weld, Kit Carson, Huerfano, Pueblo, Otero, Prowers, Fremont, and El Paso

111

Ames Lab 101: Rare-Earth Recycling  

SciTech Connect

Recycling keeps paper, plastics, and even jeans out of landfills. Could recycling rare-earth magnets do the same? Perhaps, if the recycling process can be improved. Scientists at the U.S. Department of Energy's Ames Laboratory are working to more effectively remove the neodymium, a rare earth, from the mix of other materials in a magnet.

Ryan Ott

2012-09-05T23:59:59.000Z

112

Stark spectroscopy on rare gas atoms  

E-Print Network (OSTI)

Stark spectroscopy on rare gas atoms PROEFSCHRIFT ter verkrijging van de graad van doctor aan de-DATA LIBRARY TECHNISCHE UNIVERSITEIT EINDHOVEN Jiang, Tao Stark spectroscopy on rare gas atoms / by Tao Jiang / gasontladingen Subject headings : plasma diagnostics / Stark effect / optogalvanic spectroscopy / atomic emission

Eindhoven, Technische Universiteit

113

Chemical Properties of the Rare Gases  

Science Journals Connector (OSTI)

... of argon of about 100 atm. I have already shown by an independent method1 that radon, too, forms a hydrate which is much more stable than those of other rare ... , forms a hydrate which is much more stable than those of other rare gases. Radon is easily held by crystals of sulphur dioxide hydrates, when they are formed from ...

B. A. NIKITIN

1937-10-09T23:59:59.000Z

114

The Use of Rare Earths in Photovoltaics  

Science Journals Connector (OSTI)

The metal-insulator semiconductor (MIS) junction used as an alternative solar cell is reviewed. The properties of the new solar cell barrier metals Sc, Y, Lu and Yb are discussed and compared with other barrie...

P. Munz; E. Bucher

1982-01-01T23:59:59.000Z

115

Probing QCD with Rare Charmless $B$ Decays  

SciTech Connect

Rare charmless hadronic B decays are a good testing ground for QCD. In this paper we describe a selection of new measurements made by the BABAR and BELLE collaborations.

Gradl, Wolfgang

2006-07-07T23:59:59.000Z

116

Ames Lab 101: Rare-Earth Magnets  

ScienceCinema (OSTI)

Senior Scientist, Bill McCallum, briefly discusses rare-earth magnets and their uses and how Ames Lab is research new ways to save money and energy using magnets.

McCallum, Bill

2012-08-29T23:59:59.000Z

117

Nuclear Astrophysics in Rare Isotope Facilities  

E-Print Network (OSTI)

Nuclear reactions in stars are difficult to measure directly in the laboratory at the small astrophysical energies. In recent years indirect methods with rare isotopes have been developed and applied to extract low-energy astrophysical cross sections.

C. A. Bertulani

2009-11-02T23:59:59.000Z

118

THE INTERACTION OF RARE GAS METASTABLE ATOMS  

E-Print Network (OSTI)

in the study of metastable atom reactions. > 1 it- Fig, laa raetastable rare gas atom, three quantities are necessaryOF iiARE GAS METASTABLF ATOMS Andrew Zun-Foh Wang M a t e r

Wang, A.Z.-F.

2011-01-01T23:59:59.000Z

119

Rare decays at the LHCb experiment  

E-Print Network (OSTI)

Rare decays of beauty and charm hadrons offer a rich playground to make precise tests of the Standard Model and look for New Physics at the level of quantum corrections. A review of recent LHCb results will be presented.

Luca Pescatore

2014-10-09T23:59:59.000Z

120

Microsoft Word - rare earth speech 3-18 6am  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

REMARKS PREPARED FOR DELIVERY REMARKS PREPARED FOR DELIVERY TECHNOLOGY AND RARE EARTH METALS CONFERENCE 2010 KEYNOTE ADDRESS DAVID SANDALOW ASSISTANT SECRETARY FOR POLICY & INTERNATIONAL AFFAIRS U.S. DEPARTMENT OF ENERGY WASHINGTON, D.C. MARCH 17, 2010 [Acknowledgements.] 1. INTRODUCTION Thank you for the invitation to speak at this important conference. At energy conferences today, no topic is hotter than shale gas. The story is striking: recoverable reserves of shale gas have increased six-fold in the past few years, thanks to new drilling technologies. This increase has been transformational, with U.S. natural gas imports now predicted to drop steadily in the next decade and beyond, whereas just a few years ago imports were projected to climb for the foreseeable future. Large shale gas reserves are believed to exist

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors  

E-Print Network (OSTI)

300-500°C. Doping rare earth phosphate glasses with Ce, andRare Earth Phosphate Glass and Glass-Ceramic Protonconductivity of alkaline-earth doped rare earth phosphate

De Jonghe, Lutgard C.

2010-01-01T23:59:59.000Z

122

Ames Laboratory to Lead New Research Effort to Address Shortages in Rare  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Laboratory to Lead New Research Effort to Address Shortages in Laboratory to Lead New Research Effort to Address Shortages in Rare Earth and Other Critical Materials Ames Laboratory to Lead New Research Effort to Address Shortages in Rare Earth and Other Critical Materials January 9, 2013 - 12:13pm Addthis NEWS MEDIA CONTACT (202) 586-4940 WASHINGTON - The U.S. Department of Energy announced today that a team led by Ames Laboratory in Ames, Iowa, has been selected for an award of up to $120 million over five years to establish an Energy Innovation Hub that will develop solutions to the domestic shortages of rare earth metals and other materials critical for U.S. energy security. The new research center, which will be named the Critical Materials Institute (CMI), will bring together leading researchers from academia, four Department of Energy

123

RARE KAON DECAYS: IL BUONO, IL BRUTTO, IL CATTIVO.  

SciTech Connect

The author briefly reviews recent progress in rare kaon decays, where he takes ''rare'' to mean those with {Beta} < {Omicron}(10{sup -7}).

REDLINGER,G.

2004-06-07T23:59:59.000Z

124

Using Rare Gas Permeation to Probe Methanol Diffusion near the...  

NLE Websites -- All DOE Office Websites (Extended Search)

Rare Gas Permeation to Probe Methanol Diffusion near the Glass Transition Temperature. Using Rare Gas Permeation to Probe Methanol Diffusion near the Glass Transition Temperature....

125

Metal oxide films on metal  

DOE Patents (OSTI)

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

126

Rapporteur's Report - workshop on rare earth elements  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Trans-Atlantic Workshop on Rare Earth Elements and Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Materials for a Clean Energy Future Hosted by the MIT Energy Initiative, cambridge, Massachusetts december 3, 2010 Introduction The objective of the workshop was to exchange views and information on the material security challenges of rare earths and other elements critical for clean energy generation and use. This includes the description of current research topics around the supply chain and end uses, and to identify opportunities for Trans-Atlantic research cooperation. The workshop consisted of a series of brief presentations by researchers in the US and Europe, followed by a discussion of possible areas of collaboration proposed by the co-chairs. A list of the presentations and the agenda for the day is appended with this document.

127

Metal Toxicity  

Science Journals Connector (OSTI)

Problems posed to plants by metal toxicity in the soils of the world are basically of two kinds. The first kind are of natural origin. These arise either as a consequence of the nature of the parent material f...

T. McNeilly

1994-01-01T23:59:59.000Z

128

Dendritic metal nanostructures  

DOE Patents (OSTI)

Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

2010-08-31T23:59:59.000Z

129

Metals on graphene: correlation between adatom adsorption behavior and growth morphology  

SciTech Connect

We present a systematic study of metal adatom adsorption on graphene by ab initio calculations. The calculations cover alkali metals, sp-simple metals, 3d and group 10 transition metals, noble metals, as well as rare earth metals. The correlation between the adatom adsorption properties and the growth morphology of the metals on graphene is also investigated. We show that the growth morphology is related to the ratio of the metal adsorption energy to its bulk cohesive energy (E(a)/E(c)) and the diffusion barrier (?E) of the metal adatom on graphene. Charge transfer, electric dipole and magnetic moments, and graphene lattice distortion induced by metal adsorption would also affect the growth morphologies of the metal islands. We also show that most of the metal nanostructures on graphene would be thermally stable against coarsening.

Liu, Xiaojie; Wang, Cai-Zhuang; Hupalo, Myron; Lu, Wencai; Tringides, Michael C.; Yao, Yongxin; Ho, Kai-Ming

2012-05-19T23:59:59.000Z

130

Complexes of niobium and tantalum containing metal-metal bonds  

SciTech Connect

A new entry into the area of low valent niobium and tantalum complexes containing metal-metal bonds is described. M/sub 2/X/sub 6/ (..mu..-THT)(THF)/sub 2/ complexes, where M = Nb or Ta, X = Cl or Br and THT - tetrahydrothiophene, are conveniently synthesized via the reaction of M/sub 2/M/sub 6/(THT)/sub 3/ with THF (THF = tetrahydrofuran). Unlike M/sub 2/X/sub 6/(THT)/sub 3/, M/sub 2/X/sub 6/(..mu..-THT)(THF)/sub 2/ can be easily reduced by sodium amalgam. In THF and in the presence of THT, complexes of the type M/sub 2/X/sub 6/(..mu..-THT)/sub 3//sup 2 -/ form. Salts of these compounds can also be synthesized directly from the metal pentahalides in a two step, one pot reaction in which M/sub 2/X/sub 6/(THT)/sub 3/ is an intermediate. The M/sub 2/X/sub 6/(..mu..-THT)/sub 3//sup 2 -/ complexes have a face-sharing bioctahedral structure with metal-metal triple bonds, the first reported for niobium or tantalum. These compounds are relatively inert, but (Nb/sub 2/Cl/sub 6/(..mu..-THT)/sub 3//sup 2 -/ does reach with pyridine and with a solution of acetic acid/acetic anhydride. These reactions and those of some of the sodium salts are described. In general, trinuclear complexes of niobium and tantalum are rare, and this type of discrete trinuclear complex, which contains one capping, three bridging and nine terminal ligands, has been seen only once before for the group 5 metals, although many examples of similar group 6 metal complexes are known. Full details of the synthesis and characterization of these complexes are described and an interpretation of their electronic structures is given.

Diebold, M.P.

1987-01-01T23:59:59.000Z

131

Effect of the militarily-relevant heavy metals, depleted uranium and heavy metal tungsten-alloy on gene expression in human liver carcinoma cells (HepG2)  

Science Journals Connector (OSTI)

Depleted uranium (DU) and heavy-metal tungsten alloys ... in military applications. Chemically similar to natural uranium, but depleted of the higher activity 235U and 234U...in vitro. Using insoluble DU-UO2 and ...

Alexandra C. Miller; Kia Brooks; Jan Smith…

2004-01-01T23:59:59.000Z

132

Search for rare and forbidden eta ' decays  

E-Print Network (OSTI)

We have searched for rare and forbidden decays of the eta' meson in hadronic events at the CLEO II detector. The search is conducted on 4.80 fb(-1) of e(+)e(-) collisions at 10.6 GeV center-of-mass energy at the Cornell Electron Storage Ring. We...

Ammar, Raymond G.; Baringer, Philip S.; Bean, Alice; Besson, David Zeke; Coppage, Don; Davis, Robin E. P.; Kotov, S.; Kravchenko, I.; Kwak, Nowhan; Zhou, X.

2000-01-01T23:59:59.000Z

133

Mikhail Avilov Facility for Rare Isotope Beams  

E-Print Network (OSTI)

Challenges Chemical Challenges Radiation Challenges Summary #12; World-leading heavy ion accelerator facility for rare isotope science · Nuclear Structure · Nuclear Astrophysics · Fundamental Interactions Target vacuum vessel M. Avilov, May 2014 5th HP Targetry Workshop, FNAL, Slide 4 Target Beam dump Beam

McDonald, Kirk

134

Equine in vitro fertilization  

E-Print Network (OSTI)

-culturing with equine oviductal epithelial cells, 50 embryos obtained by in-vitro fertilization showed some degree of development. Sixteen embryos developed to the 2-cell stage, three to 3-cell, seven to the 4-cell, one to the S-cell, two to the 6-cell, one... to the 7-cell, two to the 8-cell, two to the 16-cell, seven to early morula (between 16 and 32 cells), eight to morulas and one to blastocyst. Some embryos developed excessively rapid and could not be considered fertilized embryos. Probably those fast...

Vasquez C., Juan Carlos

1992-01-01T23:59:59.000Z

135

Metal-insulator transition in dilute alkali-metal systems  

Science Journals Connector (OSTI)

The metal-insulator transition is studied for dilute systems of alkali metals. Using a spin-split self-consistent band-structure approach, we find the transition density, a strikingly enhanced magnetic susceptibility, and the electron effective mass. The critical density nc is found to be given by the simple relation rsc=r0+2.8. Here rsc=[3(4?nc)]13 and r0 is the model potential radius which is roughly the radius of the neutral atom. The Mott criterion of nc13aB?0.25 (where aB is the appropriate Bohr orbit) is found to be inadequate for describing these systems. The predicted effective mass and magnetic susceptibility enhancements are largest for Li and become systematically smaller for the heavier alkalis. We compare our results for the transition density with two sets of experiments, namely the gas-liquid critical density and the metal-insulator transition for codeposited thick films of alkali-metal and rare-gas atoms. Good agreement is found in both cases.

J. H. Rose

1981-01-15T23:59:59.000Z

136

Composite metal membrane  

DOE Patents (OSTI)

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

137

Composite metal membrane  

DOE Patents (OSTI)

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

1998-04-14T23:59:59.000Z

138

Rare K decays: Challenges and Perspectives  

E-Print Network (OSTI)

At this stage of the LHC program, the prospect for a new physics signal in the very rare K ---> pi nu nu bar decays may be dented, but remains well alive thanks to their intrinsic qualities. First, these decays are among the cleanest observables in the quark flavor sector. When combined with their terrible suppression in the Standard Model, they thus offer uniquely sensitive probes. Second, the LHC capabilities are not ideal for all kinds of new physics, even below the TeV scale. For example, rather elusive scenarios like natural-SUSY-like hierarchical spectrum, baryon number violation, or new very light but very weakly interacting particles may well induce deviations in rare K decays. Even though experimentalists should brace themselves for tiny deviations, these modes thus have a clear role to play in the LHC era.

Christopher Smith

2014-09-22T23:59:59.000Z

139

Concerning the Facility for Rare Isotope Beams  

ScienceCinema (OSTI)

James Symons, Nuclear Science Division Director at Lawrence Berkeley Lab, and Daniela Leitner, head of operations at Berkeley Lab's 88-Inch Cyclotron, discuss major contributions to the new Facility for Rare Isotope Beams (FRIB) at Michigan State University, including ion source, which will based on the VENUS source built for the 88-Inch Cyclotron, and the GRETA gamma-ray detector now under construction there.

Symons, James

2013-05-29T23:59:59.000Z

140

PRELIMINARY SURVEY OF VITRO CORPORATION  

Office of Legacy Management (LM)

PRELIMINARY SURVEY OF VITRO CORPORATION (VITRO LABORATORIES) WEST ORANGE, NEW JERSEY Work performed by the Health and Safety Research Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37830 March 1980 OAK RIDGE NATIONAL LABORATORY operated by UNION CARBIDE CORPORATION for the DEPARTMENT OF ENERGY as part of the Formerly Utilized Sites-- Remedial Actton Program VITRO CORPORATION (VITRO LABORATORIES) WEST ORANGE, NEW JERSEY At the request of the Department of Energy (DOE), a preliminary survey was performed at the former Vitro Corporation Laboratory in West Orange, New Jersey (see Fig 1), on November 30, 1977, to assess the radiological status of those facilities utilized under Atomic Energy Commission (AEC) contract during the late 1950s and early 1960s. This

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Spomenka Kobe, Jozef Stefan Institut, Rare Earth Magnets in Europe...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Spomenka Kobe, Jozef Stefan Institut, Rare Earth Magnets in Europe Spomenka Kobe, Jozef Stefan Institut, Rare Earth Magnets in Europe SessionB4Kobe-JosefStefanInstitut.pdf...

142

Method for removal of heavy metal from molten salt in IFR fuel pyroprocessing  

SciTech Connect

This report details the pyrometallurgical process for recycling spent metal fuels from the Integral Fast Reactor (IFR) which involves electrorefining spent fuel in a molten salt electrolyte (LiCl-KCI-U/PuCl{sub 3}) at 500{degree}C. The total heavy metal chloride concentration in the salt will be about 2 mol %. At some point, the concentrations of alkali, alkaline earth, and rare earth fission products in the salt must be reduced to lower the amount of heat generated in the electrorefiner. The heavy metal concentration in the salt must be reduced before removing the fission products from the salt. The operation uses a lithium-cadmium alloy anode that is solid at 500{degree}C, a solid mandrel cathode with a ceramic catch crucible below to collect heavy metal that falls off it, and a liquid cadmium cathode. The design criteria that had to be met by this equipment included the following: (1) control of the reduction rate by lithium, (2) good separation between heavy metal and rare earths, and (3) the capability to collect heavy metal and rare earths over a wide range of salt compositions. In tests conducted in an engineering-scale electrorefiner (10 kg uranium per cathode), good separation was achieved while removing uranium and rare earths from the salt. Only 13% of the rare earths was removed, while 99.9% of the uranium in the salt was removed; subsequently, the rare earths were also reduced to low concentrations. The uranium concentration in the salt was reduced to 0.05 ppm after uranium and rare earths were transferred from the salt to a solid mandrel cathode with a catch crucible. Rare earth concentrations in the salt were reduced to less than 0.01 wt % in these operations. Similar tests are planned to remove plutonium from the salt in a laboratory-scale (100--300 g heavy metal) electrorefiner.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1994-02-01T23:59:59.000Z

143

RARE EARTH ELEMENT SENSITIVITY FACTORS IN CALCIC PLAGIOCLASE (ANORTHITE)  

E-Print Network (OSTI)

RARE EARTH ELEMENT SENSITIVITY FACTORS IN CALCIC PLAGIOCLASE (ANORTHITE) C. Floss and B. Jolliff Mc Brookings Drive, St. Louis, MO 63130 1. Introduction The rare earth elements (REE) are sensitive indicators concentrations for each sample are listed in Table 1 and are shown in Fig. 1. Table 1. Rare Earth Element Data

144

New model for the mixed-valence phenomenon in rare-earth materials  

Science Journals Connector (OSTI)

A model of a single rare-earth atom in a transition metal is derived, and terms describing screening of charge fluctuations in the resonant l=3 scattering channels by the l=2 channels are included. Using the Tomonaga approximation, in which charge fluctuations are represented by bosons, the screening channels are replaced by a boson field, and the model takes on a particularly simple form, the Anderson model of a magnetic impurity, now coupled to the boson field. The mean-field theory of this model suggests that, unlike in the original Anderson model, the impurity can be in a state of slowly fluctuating valence, which we identify with the mixed-valence phenomenon in certain rare-earth materials. These results suggest that the mixed-valence effect may be purely electronic in origin.

F. D. M. Haldane

1977-03-01T23:59:59.000Z

145

Marathon/Vitro to seek uranium  

Science Journals Connector (OSTI)

Marathon/Vitro to seek uranium ... Last week, Marathon Oil agreed with Vitro Corp. of America to explore jointly for uranium in North America. ...

1967-03-13T23:59:59.000Z

146

Scintillation of rare earth doped fluoride nanoparticles  

SciTech Connect

The scintillation response of rare earth (RE) doped core/undoped (multi-)shell fluoride nanoparticles was investigated under x-ray and alpha particle irradiation. A significant enhancement of the scintillation response was observed with increasing shells due: (i) to the passivation of surface quenching defects together with the activation of the REs on the surface of the core nanoparticle after the growth of a shell, and (ii) to the increase of the volume of the nanoparticles. These results are expected to reflect a general aspect of the scintillation process in nanoparticles, and to impact radiation sensing technologies that make use of nanoparticles.

Jacobsohn, L. G.; McPherson, C. L.; Sprinkle, K. B.; Ballato, J. [Center for Optical Materials Science and Engineering Technologies (COMSET), and School of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States); Yukihara, E. G. [Physics Department, Oklahoma State University, Stillwater, Oklahoma 74078-3072 (United States); DeVol, T. A. [Department of Environmental Engineering and Earth Sciences, Clemson University, Clemson, South Carolina 29634-0905 (United States)

2011-09-12T23:59:59.000Z

147

Rare b hadron decays at the LHC  

E-Print Network (OSTI)

With the completion of Run~I of the CERN Large Hadron Collider, particle physics has entered a new era. The production of unprecedented numbers of heavy-flavoured hadrons in high energy proton-proton collisions allows detailed studies of flavour-changing processes. The increasingly precise measurements allow to probe the Standard Model with a new level of accuracy. Rare $b$ hadron decays provide some of the most promising approaches for such tests, since there are several observables which can be cleanly interpreted from a theoretical viewpoint. In this article, the status and prospects in this field are reviewed, with a focus on precision measurements and null tests.

Blake, T; Hiller, G

2015-01-01T23:59:59.000Z

148

Final Report "Structure of Rare Isotopes"  

SciTech Connect

The Junior Investigator grant 'Structure of Rare Isotopes' (DE-FG02-07ER41529) supported research in low-energy nuclear theory from September 1, 2007 to August 31, 2010. It was the main goal of the proposed research to develop and optimize an occupation-number-based energy functional for the computation of nuclear masses, and this aim has been reached. Furthermore, progress was made in linking two and three-body forces from low-momentum interactions to pairing properties in nuclear density functionals, and in the description of deformed nuclei within an effective theory.

Papenbrock, Thomas

2012-05-09T23:59:59.000Z

149

Rare-Earth-Free Traction Motor: Rare Earth-Free Traction Motor for Electric Vehicle Applications  

SciTech Connect

REACT Project: Baldor will develop a new type of traction motor with the potential to efficiently power future generations of EVs. Unlike today’s large, bulky EV motors which use expensive, imported rare-earth-based magnets, Baldor’s motor could be light, compact, contain no rare earth materials, and have the potential to deliver more torque at a substantially lower cost. Key innovations in this project include the use of a unique motor design, incorporation of an improved cooling system, and the development of advanced materials manufacturing techniques. These innovations could significantly reduce the cost of an electric motor.

None

2012-01-01T23:59:59.000Z

150

Note: Portable rare-earth element analyzer using pyroelectric crystal  

SciTech Connect

We report a portable rare-earth element analyzer with a palm-top size chamber including the electron source of a pyroelectric crystal and the sample stage utilizing cathodoluminescence (CL) phenomenon. The portable rare-earth element analyzer utilizing CL phenomenon is the smallest reported so far. The portable rare-earth element analyzer detected the rare-earth elements Dy, Tb, Er, and Sm of ppm order in zircon, which were not detected by scanning electron microscopy-energy dispersive X-ray spectroscopy analysis. We also performed an elemental mapping of rare-earth elements by capturing a CL image using CCD camera.

Imashuku, Susumu, E-mail: imashuku.susumu.2m@kyoto-u.ac.jp; Fuyuno, Naoto; Hanasaki, Kohei; Kawai, Jun [Department of Materials Science and Engineering, Kyoto University, Sakyo, Kyoto 606-8501 (Japan)] [Department of Materials Science and Engineering, Kyoto University, Sakyo, Kyoto 606-8501 (Japan)

2013-12-15T23:59:59.000Z

151

Mechanochemical processing for metals and metal alloys  

DOE Patents (OSTI)

A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)

2001-01-01T23:59:59.000Z

152

Adenovirus DNA replication in vitro  

Science Journals Connector (OSTI)

...During the course of the in vitro reaction, branched molecules wit structural features identical to in vivo replication intermediates...for expert technical assistance and Drs. Gary Ketner, Sharon Price, and Daniel Nathans for helpful discussions. This work was...

M D Challberg; T J Kelly; Jr

1979-01-01T23:59:59.000Z

153

Searches for very rare decays of kaons  

SciTech Connect

The physics motivation for searches for very rare kaon decays, either forbidden or suppressed within the Standard Model, is briefly discussed. Simple arguments conclude that such searches probe possible new forces at a 200 TeV mass scale or constitute a precision test of the electroweak model. The examples of such process are decays of K{sub L}{sup 0} {yields} {mu} {sup {+-}}e{sup -+}, K{sup +} {yields} {pi}{sup +} {mu}{sup +} e{sup -}, K{sub L}{sup 0} {yields} {mu}{sup +} {mu}{sup -}, and K{sup +} {yields} {pi} {yields} {pi}{sup +}{nu}{bar {nu}}. We present the current experimental status and describe the new efforts to reach sensitivities down to one part in 10{sup 12}. The discussion is focused on the experimental program at the Alternating Gradient Synchrotron at Brookhaven National Laboratory, where intense beams make such studies possible.

Lang, K. [Univ. of Texas, Austin, TX (United States)

1997-01-01T23:59:59.000Z

154

Anisotropic magnetic properties of light rare-earth diantimonides  

SciTech Connect

Results are presented of anisotropic temperature and field-dependent magnetization M(H,T) and resistivity {rho}(H,T) measurements on high quality single crystals of the light rare-earth diantimonides RSb{sub 2}, R=La-Nd, Sm. All of these, excepting LaSb{sub 2}, magnetically order at low temperatures, and for CeSb{sub 2} and NdSb{sub 2} several magnetically ordered phases were observed in low-field magnetization and zero-field resistivity measurements. For R=Ce-Sm strong anisotropies, associated with crystalline electric field (CEF) splitting of the R{sup 3+} ion, were found in M(T) measurements both below and above magnetic ordering temperatures. Furthermore, for R=Ce-Nd metamagnetic transitions were observed in M(H) and {rho}(H) for H{parallel}(ab) in the magnetically ordered state. In addition, above 15 kG de Haas{endash}van Alphen oscillations are observed for SmSb{sub 2} and Shubnikov{endash}de Haas quantum oscillations are observed above {approximately}120kG for NdSb{sub 2} and SmSb{sub 2}. The zero-field in-plane resistivity {rho}{sub ab} of all of the compounds is metallic (d{rho}/dT{gt}0), with residual resistance ratios ranging from 40 to 750. The c-axis resistivity is also metallic, but appears to be considerably larger than the in-plane value, consistent with the diantimonides being quasi-two-dimensional materials. The magnetoresistance of all members of the series is large, approximately linear in H at moderate fields, and is also dependent on the relative orientation of the applied magnetic fields to the crystallographic axes. The extreme case of SmSb{sub 2} has [{rho}(55kG){minus}{rho}(0)]/{rho}(0){gt}50000{percent} at T=2K and H{parallel}c. {copyright} {ital 1998} {ital The American Physical Society}

Budko, S.L.; Canfield, P.C. [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States)] [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Mielke, C.H.; Lacerda, A.H. [National High Magnetic Field Laboratory, Los Alamos Facility, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [National High Magnetic Field Laboratory, Los Alamos Facility, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

1998-06-01T23:59:59.000Z

155

Good Earths and Rare Earths | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Good Earths and Rare Earths Good Earths and Rare Earths Good Earths and Rare Earths April 20, 2011 - 6:17pm Addthis Charles Rousseaux Charles Rousseaux Senior Writer, Office of Science What does this mean for me? Rare earth elements -- dysprosium, neodymium, terbium, europium and yttrium -- are essential to a wide range of green energy technologies ranging from windmills to electric vehicles One of their primary uses is in permanent magnets, which amount to over a $4 billion global industry Ames Laboratory recently discovered a way to make these magnets cheaper and greener and signed a cooperative research and development agreement with Molycorp Inc. -- the Western hemisphere's only producer of rare-earth oxides. China holds about 36 percent of world's rare-earth reserves, (compared to 13 percent in the U.S.), but it currently produces 95 percent

156

Metal-phosphate binders  

DOE Patents (OSTI)

A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

2009-05-12T23:59:59.000Z

157

POWDER METALLURGICAL PROCESSING OF MAGNETOSTRICTIVE MATERIALS BASED ON RARE EARTH-IRON INTERMETALLIC COMPOUNDS  

E-Print Network (OSTI)

R « any of several rare earth elements) was discovered. Toobserved for pure rare earth elements. This and the strong

Malekzadeh, Manoochehr

2011-01-01T23:59:59.000Z

158

Classical spin model of the relaxation dynamics of rare-earth doped permalloy  

Science Journals Connector (OSTI)

In this paper, the ultrafast dynamic behavior of rare-earth doped permalloy is investigated using an atomistic spin model with Langevin dynamics. In line with experimental work, the effective Gilbert damping is calculated from transverse relaxation simulations, which shows that rare-earth doping causes an increase in the damping. Analytic theory suggests that this increase in damping would lead to a decrease in the demagnetization time. However, longitudinal relaxation calculations show an increase with doping concentration instead. The simulations are in a good agreement with previous experimental work of Radu et al. [Radu et al., Phys. Rev. Lett. 102, 117201 (2009)]. The longitudinal relaxation time of the magnetization is shown to be driven by the interaction between the transition metal and the laser-excited conduction electrons, whereas the effective damping is predominantly determined by the slower interaction between the rare-earth elements and the phonon heat bath. We conclude that for complex materials, it is evidently important not to expect a single damping parameter but to consider the energy transfer channel relevant to the technique and time scale of the measurement.

M. O. A. Ellis; T. A. Ostler; R. W. Chantrell

2012-11-19T23:59:59.000Z

159

18F-Labeled Magnetic-Upconversion Nanophosphors via Rare-Earth Cation-Assisted Ligand Assembly  

Science Journals Connector (OSTI)

18F-Labeled Magnetic-Upconversion Nanophosphors via Rare-Earth Cation-Assisted Ligand Assembly ... The inset of Figure S7 shows the bright-field photo of AA-Gd-UCNPs dispersed in PBS for 0 and 48 h. ... To determine whether UCNPs coated with folic acid and aminocaproic acid (FA-AA-Gd-UCNPs, FA:AA = 1:9) could be used for cellular targeted imaging, we performed in vitro cellular studies using FR-positive [FR(+)] KB cell lines and FR-negative [FR(?)] MCF-7 cell lines. ...

Qian Liu; Yun Sun; Chenguang Li; Jing Zhou; Chunyan Li; Tianshe Yang; Xianzhong Zhang; Tao Yi; Dongmei Wu; Fuyou Li

2011-03-08T23:59:59.000Z

160

Jefferson Lab Laser Twinkles in Rare Color | Jefferson Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

Laser Twinkles in Rare Color NEWPORT NEWS, VA, Dec. 21 - December is a time for twinkling lights, and scientists at the Department of Energy's Thomas Jefferson National Accelerator...

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Rare earth element transport in the Yucca Mountain region.  

E-Print Network (OSTI)

??In sync with environmental pollution of solutes in nature, from source, process to consequence, geochemical processes (leaching and sorption) and hydraulic transportation of the rare… (more)

Zhang, Liqiong

2010-01-01T23:59:59.000Z

162

News about Rare Earths, New or Critical Materials, and Their...  

NLE Websites -- All DOE Office Websites (Extended Search)

14, 2014 Could magnets in helmets reduce football concussions?, November 2014 The Rare-Earth Elements -- Vital to Modern Technologies and Lifestyles, November 2014 Energy Report:...

163

Metal Hydrides - Science Needs  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Storage Grand Challenge Pre-Solicitation Meeting, June 19, 2003 1 Metal Hydrides - Science Needs TRADITIONAL METALLIC HYDRIDES: 1.5 to 2 wt.% H. Well studied. COMPLEX...

164

Probing metal solidification nondestructively  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting and...

165

Probing metal solidification nondestructively  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting...

166

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

167

Allele age and a test for selection on rare alleles  

Science Journals Connector (OSTI)

...Charlesworth and P. H. Harvey Allele age and a test for selection on rare alleles Montgomery...recombination, leads to a statistical test of whether a rare allele has experienced natural selection. The test is based on finding whether there is too...

2000-01-01T23:59:59.000Z

168

Kinetic roughening during rare-gas homoepitaxy E. Nabighian,1  

E-Print Network (OSTI)

Kinetic roughening during rare-gas homoepitaxy E. Nabighian,1 M. C. Bartelt,2 and X. D. Zhu1,* 1 roughening, which accounts for deviations from layer- by-layer growth, is generally very sensitive substrates; see e.g., Ref. 3. A quantitative assessment of the way in which rare-gas multilayer films roughen

Zhu, Xiangdong

169

FARVAT: a family-based rare variant association test  

Science Journals Connector (OSTI)

......family-based rare variant association test Sungkyoung Choi 1 Sungyoung Lee 1 Sven...FAmily-based Rare Variant Association Test (FARVAT). FARVAT is based on the quasi-likelihood...working matrix, our method could be a burden test or a variance component test, and could......

Sungkyoung Choi; Sungyoung Lee; Sven Cichon; Markus M. Nöthen; Christoph Lange; Taesung Park; Sungho Won

2014-11-15T23:59:59.000Z

170

Heavy metal biosensor  

DOE Patents (OSTI)

Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

2014-04-15T23:59:59.000Z

171

Ames Lab, CMI, NEDO hold First Meeting on Rare Metals | The Ames...  

NLE Websites -- All DOE Office Websites (Extended Search)

Director Thomas Lograsso and CMI Director Alex King in CMI attended this meeting with ad hoc Japanese members including members in NEDO to exchange information about supply...

172

Parity nonconservation in Fr-like actinide and Cs-like rare-earth-metal ions  

Science Journals Connector (OSTI)

Parity-nonconservation (PNC) amplitudes are calculated for the 7s-6d3/2 transitions of the francium isoelectronic sequence (Fr, Ra+, Ac2+, Th3+, Pa4+, U5+, and Np6+) and for the 6s-5d3/2 transitions of the cesium isoelectronic sequence (Cs, Ba+, La2+, Ce3+, and Pr4+). We show in particular that isotopes of La2+, Ac2+, and Th3+ ions have strong potential in the search for new physics beyond the standard model: The PNC amplitudes are large, the calculations are accurate, and the nuclei are practically stable. In addition, 232Th3+ ions have recently been trapped and cooled [Campbell et al., Phys. Rev. Lett. 102, 233004 (2009)]. We also extend previous works by calculating the s-s PNC transitions in Ra+ and Ba+ and provide calculations of several energy levels, and electric dipole and quadrupole transition amplitudes for the Fr-like actinide ions.

B. M. Roberts; V. A. Dzuba; V. V. Flambaum

2013-07-15T23:59:59.000Z

173

Reduction Chemistry of Rare-Earth Metal Complexes: Toward New Reactivity and Properties  

E-Print Network (OSTI)

reactor and was named promethium. Even Nature could onlyrare-earths (except for promethium and europium; ytterbiumeuropium and radioactive promethium) on hand, we synthesized

Huang, Wenliang

2013-01-01T23:59:59.000Z

174

Behavior of Rare Earth Elements in Geothermal Systems- A New  

Open Energy Info (EERE)

Behavior of Rare Earth Elements in Geothermal Systems- A New Behavior of Rare Earth Elements in Geothermal Systems- A New Exploration/Exploitation Tool? Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Behavior of Rare Earth Elements in Geothermal Systems- A New Exploration/Exploitation Tool? Abstract N/A Author Department of Geology and Geological Engineering niversity of Idaho Published Publisher Not Provided, 2001 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Behavior of Rare Earth Elements in Geothermal Systems- A New Exploration/Exploitation Tool? Citation Department of Geology and Geological Engineering niversity of Idaho. 2001. Behavior of Rare Earth Elements in Geothermal Systems- A New Exploration/Exploitation Tool?. (!) : (!) . Retrieved from

175

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

176

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

177

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

178

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

179

Pyroprocessing of IFR Metal Fuel  

SciTech Connect

The Integral Fast Reactor (IFR) fuel cycle features the use of an innovative reprocessing method, known as {open_quotes}pyroprocessing{close_quotes} featuring fused-salt electrofining of the spent fuel. Electrofining of IFR spent fuel involves uranium recovery by electro-transport to a solid steel cathode. The thermodynamics of the system preclude plutonium recovery in the same way, so a liquid cadmium cathode located in the electrolyte salt phase is utilized. The deposition of Pu, Am, Np, and Cm takes place at the liquid cadmium cathode in the form of cadmium intermetallic compounds (e.g, PuCd{sub 6}), and uranium deposits as the pure metal when cadmium saturation is reached. A small amount of rare earth fission products deposit together with the heavy metals at both the solid and liquid cadmium cathodes, providing a significant degree of self-protection. A full scope demonstration of the IFR fuel cycle will begin in 1993, using fuel irradiated in EBR-II.

Laidler, J.J. [Argonne National Laboratory, IL (United States)

1993-12-31T23:59:59.000Z

180

Portraits of some representatives of metal boride carbide and boride silicide compounds  

SciTech Connect

Different ternary alkaline-earth and rare-earth metal boron carbide and silicide compounds are examined using the solid-state language of Zintl-Klemm concept, band structures, and density of states, in order to show that the topology of the non-metal sub-lattice is highly dependent on the electron count. It is also shown that the chemistry of rare-earth metal-boron-silicon does not parallel that of rare-earth metal-boron-carbon. B-C bonds are easily formed in the latter, leading to a large variety of different structural arrangements, whereas Si-B bonds are hardly observed in the former, except in insertion compounds. - Graphical abstract: Some ternary alkaline-earth and rare-earth metal boron carbide and silicide compounds are examined using the solid-state language of Zintl-Klemm concept, band structures, and density of states, in order to show that the topology of the non-metal sub-lattice is highly dependent on the electron count.

Ben Yahia, Mouna [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Roger, Jerome [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Rocquefelte, Xavier [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Gautier, Regis [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Bauer, Joseph [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Guerin, Roland [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Saillard, Jean-Yves [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France); Halet, Jean-Francois [Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR 6511 CNRS-Universite de Rennes 1-ENSC Rennes, Institut de Chimie de Rennes, F-35042 Rennes (France)]. E-mail: halet@univ-rennes1.fr

2006-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Modeling the glass forming ability of metals  

E-Print Network (OSTI)

Rare Earth Elements..without the use of rare earth elements” in Bulk Metallicwithout the Use of Rare Earth Elements details the design

Cheney, Justin Lee

2007-01-01T23:59:59.000Z

182

Polymer quenched prealloyed metal powder  

DOE Patents (OSTI)

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Hajaligol, Mohammad R. (Midlothian, VA); Fleischhauer, Grier (Midlothian, VA); German, Randall M. (State College, PA)

2001-01-01T23:59:59.000Z

183

Metal-Air Batteries  

SciTech Connect

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

184

Synthesis Of Fluorescent Metal Nanoclusters  

NLE Websites -- All DOE Office Websites (Extended Search)

Synthesis Of Fluorescent Metal Nanoclusters Synthesis Of Fluorescent Metal Nanoclusters Fluorescent metal nanoclusters were prepared. Available for thumbnail of Feynman Center...

185

4f-derived photoemission and 4f-ligand hybridization in light rare-earth halides  

Science Journals Connector (OSTI)

We have studied the 4f-derived photoemission spectra of insulating Ce, Pr, and Nd trihalides by resonant photoemission spectroscopy. A double-peak structure is observed in every f spectrum as in metallic Ce, Pr, and Nd compounds and is successfully analyzed in terms of the cluster model. This confirms that the two peaks arise from hybridization between the 4f and ligand p orbitals rather than from two different screening channels of the f hole. The f-ligand hybridization strength is found to decrease on going from the Ce to Pr to Nd compounds, but appears to remain significantly large for heavier rare earths, suggesting the importance of hybridization effects in heavy rare-earth compounds.

A. Fujimori; T. Miyahara; T. Koide; T. Shidara; H. Kato; H. Fukutani; S. Sato

1988-10-15T23:59:59.000Z

186

Fact Sheet: Facility For Rare Isotope Beams (FRIB) Applicant Selection |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Facility For Rare Isotope Beams (FRIB) Applicant Facility For Rare Isotope Beams (FRIB) Applicant Selection Fact Sheet: Facility For Rare Isotope Beams (FRIB) Applicant Selection December 11, 2008 - 8:51am Addthis Based on the analyses and recommendations over the last decade, the U.S. Department of Energy (DOE) Office of Science determined that the establishment of a Facility for Rare Isotope Beams (FRIB) is a high priority for the future of U.S. nuclear science research. This determination and supporting rationale are reflected in the DOE/ National Science Foundation Nuclear Science Advisory Committee's 2007 Long Range Plan and the 2003 DOE report, "Facilities for the Future of Science: A Twenty-Year Outlook." A Funding Opportunity Announcement (FOA) was used to solicit applications for the conceptual design and establishment of FRIB in order

187

COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities...  

NLE Websites -- All DOE Office Websites (Extended Search)

2015, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and Technical Challenges Dr. Georg Bollen Michigan State...

188

Behavior Of Rare Earth Element In Geothermal Systems, A New  

Open Energy Info (EERE)

Behavior Of Rare Earth Element In Geothermal Systems, A New Behavior Of Rare Earth Element In Geothermal Systems, A New Exploration-Exploitation Tool Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Report: Behavior Of Rare Earth Element In Geothermal Systems, A New Exploration-Exploitation Tool Details Activities (32) Areas (17) Regions (0) Abstract: The goal of this four-year project was to provide a database by which to judge the utility of the rare earth elements (REE) in the exploration for and exploitation of geothermal fields in the United States. Geothermal fluids from hot springs and wells have been sampled from a number of locations, including: (1) the North Island of New Zealand (1 set of samples); (2) the Cascades of Oregon; (3) the Harney, Alvord Desert and Owyhee geothermal areas of Oregon; (4) the Dixie Valley and Beowawe fields

189

Metal phthalocyanine catalysts  

DOE Patents (OSTI)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1994-01-01T23:59:59.000Z

190

MECS 2006- Fabricated Metals  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Fabricated Metals (NAICS 332) Sector with Total Energy Input, October 2012 (MECS 2006)

191

Deposition of Contiguous Metal Adlayer on Transition Metal Nanostructu...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Abstract Primary Lab Date Application 20100099012 Application 20100099012 Electrocatalyst Synthesized by Depositing a Contiguous Metal Adlayer on Transition Metal...

192

E-Print Network 3.0 - astronomy-related rare books Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

astronomy-related rare books Search Powered by Explorit Topic List Advanced Search Sample search results for: astronomy-related rare books Page: << < 1 2 3 4 5 > >> 1 Rare Books...

193

U.S. Rare Earth Magnet Patents Table © 11-10-2014 page...  

NLE Websites -- All DOE Office Websites (Extended Search)

Rare Earth Magnet Patents Table 11-10-2014 page 1 Disclaimer: This U.S. Rare Earth Magnet Patents Table contains a sample of the rare- earth-magnet patents issued by the U.S....

194

Resonant Inelastic X-ray Scattering of Rare-Earth and Copper Systems  

E-Print Network (OSTI)

Introduction The rare earth elements have unique andun?lled f shell of rare earth elements gives them special4d, 4f shells for rare-earth elements. This suggests that

Kvashnina, Kristina

2007-01-01T23:59:59.000Z

195

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents (OSTI)

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, L.T.

1987-03-20T23:59:59.000Z

196

Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Information  

Open Energy Info (EERE)

Sumitomo Metal Industries Ltd Sumitomo Metals Sumitomo Metal Industries Ltd Sumitomo Metals Jump to: navigation, search Name Sumitomo Metal Industries Ltd (Sumitomo Metals) Place Osaka-shi, Osaka, Japan Zip 540-0041 Sector Solar Product Engaged in the steel, engineering, and electronics businesses; works on fuel cell component technology and manufactures silicon wafers for the solar sector. References Sumitomo Metal Industries Ltd (Sumitomo Metals)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Sumitomo Metal Industries Ltd (Sumitomo Metals) is a company located in Osaka-shi, Osaka, Japan . References ↑ "Sumitomo Metal Industries Ltd (Sumitomo Metals)" Retrieved from "http://en.openei.org/w/index.php?title=Sumitomo_Metal_Industries_Ltd_Sumitomo_Metals&oldid=351744"

197

PEROXOTITANATE- AND MONOSODIUM METAL-TITANATE COMPOUNDS AS INHIBITORS OF BACTERIAL GROWTH  

SciTech Connect

Sodium titanates are ion-exchange materials that effectively bind a variety of metal ions over a wide pH range. Sodium titanates alone have no known adverse biological effects but metal-exchanged titanates (or metal titanates) can deliver metal ions to mammalian cells to alter cell processes in vitro. In this work, we test a hypothesis that metal-titanate compounds inhibit bacterial growth; demonstration of this principle is one prerequisite to developing metal-based, titanate-delivered antibacterial agents. Focusing initially on oral diseases, we exposed five species of oral bacteria to titanates for 24 h, with or without loading of Au(III), Pd(II), Pt(II), and Pt(IV), and measuring bacterial growth in planktonic assays through increases in optical density. In each experiment, bacterial growth was compared with control cultures of titanates or bacteria alone. We observed no suppression of bacterial growth by the sodium titanates alone, but significant (p < 0.05, two-sided t-tests) suppression was observed with metal-titanate compounds, particularly Au(III)-titanates, but with other metal titanates as well. Growth inhibition ranged from 15 to 100% depending on the metal ion and bacterial species involved. Furthermore, in specific cases, the titanates inhibited bacterial growth 5- to 375-fold versus metal ions alone, suggesting that titanates enhanced metal-bacteria interactions. This work supports further development of metal titanates as a novel class of antibacterials.

Hobbs, D.

2011-01-19T23:59:59.000Z

198

Carbide/nitride grain refined rare earth-iron-boron permanent magnet and method of making  

DOE Patents (OSTI)

A method of making a permanent magnet is disclosed wherein (1) a melt is formed having a base alloy composition comprising RE, Fe and/or Co, and B (where RE is one or more rare earth elements) and (2) TR (where TR is a transition metal selected from at least one of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al) and at least one of C and N are provided in the base alloy composition melt in substantially stoichiometric amounts to form a thermodynamically stable compound (e.g. TR carbide, nitride or carbonitride). The melt is rapidly solidified in a manner to form particulates having a substantially amorphous (metallic glass) structure and a dispersion of primary TRC, TRN and/or TRC/N precipitates. The amorphous particulates are heated above the crystallization temperature of the base alloy composition to nucleate and grow a hard magnetic phase to an optimum grain size and to form secondary TRC, TRN and/or TRC/N precipitates dispersed at grain boundaries. The crystallized particulates are consolidated at an elevated temperature to form a shape. During elevated temperature consolidation, the primary and secondary precipitates act to pin the grain boundaries and minimize deleterious grain growth that is harmful to magnetic properties. 33 figs.

McCallum, R.W.; Branagan, D.J.

1996-01-23T23:59:59.000Z

199

Fact Sheet: Facility for Rare Isotope Beams (FRIB) Applicant Selection |  

Office of Science (SC) Website

Fact Sheet: Fact Sheet: Facility for Rare Isotope Beams (FRIB) Applicant Selection News Featured Articles Science Headlines 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 Presentations & Testimony News Archives Contact Information Office of Science U.S. Department of Energy 1000 Independence Ave., SW Washington, DC 20585 P: (202) 586-5430 12.11.08 Fact Sheet: Facility for Rare Isotope Beams (FRIB) Applicant Selection Print Text Size: A A A Subscribe FeedbackShare Page Based on the analyses and recommendations over the last decade, the U.S. Department of Energy (DOE) Office of Science determined that the establishment of a Facility for Rare Isotope Beams (FRIB) is a high priority for the future of U.S. nuclear science research. This determination and supporting rationale are reflected in the DOE/ National

200

High efficiency rare-earth emitter for thermophotovoltaic applications  

SciTech Connect

In this work, we propose a rare-earth-based ceramic thermal emitter design that can boost thermophotovoltaic (TPV) efficiencies significantly without cold-side filters at a temperature of 1573?K (1300?°C). The proposed emitter enhances a naturally occurring rare earth transition using quality-factor matching, with a quarter-wave stack as a highly reflective back mirror, while suppressing parasitic losses via exponential chirping of a multilayer reflector transmitting only at short wavelengths. This allows the emissivity to approach the blackbody limit for wavelengths overlapping with the absorption peak of the rare-earth material, while effectively reducing the losses associated with undesirable long-wavelength emission. We obtain TPV efficiencies of 34% using this layered design, which only requires modest index contrast, making it particularly amenable to fabrication via a wide variety of techniques, including sputtering, spin-coating, and plasma-enhanced chemical vapor deposition.

Sakr, E. S.; Zhou, Z.; Bermel, P., E-mail: pbermel@purdue.edu [Birck Nanotechnology Center, School of Electrical and Computer Engineering, Purdue University, 1205 W. State St., West Lafayette, Indiana 47907 (United States)

2014-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Rare Isotopes in Cosmic Explosions and Accelerators on Earth  

ScienceCinema (OSTI)

Rare isotopes are nature?s stepping stones to produce the heavy elements, and they are produced in large quantities in stellar explosions. Despite their fleeting existence, they shape the composition of the universe and the observable features of stellar explosions. The challenge for nuclear science is to produce and study the very same rare isotopes so as to understand the origin of the elements and a range of astronomical observations. I will review the progress that has been made to date in astronomy and nuclear physics, and the prospects of finally addressing many of the outstanding issues with the future Facility for Rare Isotope Beams (FRIB), which DOE will build at Michigan State University.

Hendrik Schatz

2010-01-08T23:59:59.000Z

202

Photoactivated metal removal  

SciTech Connect

The authors propose the use of photochromic dyes as light activated switches to bind and release metal ions. This process, which can be driven by solar energy, can be used in environmental and industrial processes to remove metals from organic and aqueous solutions. Because the metals can be released from the ligands when irradiated with visible light, regeneration of the ligands and concentration of the metals may be easier than with conventional ion exchange resins. Thus, the process has the potential to be less expensive than currently used metal extraction techniques. In this paper, the authors report on their studies of the metal binding of spirogyran dyes and the hydrolytic stability of these dyes. They have prepared a number of spirogyrans and measured their binding constants for calcium and magnesium. They discuss the relationship of the structure of the dyes to their binding strengths. These studies are necessary towards determining the viability of this technique.

Nimlos, M.R.; Filley, J.; Ibrahim, M.A.; Watt, A.S.; Blake, D.M.

1999-07-01T23:59:59.000Z

203

Process to remove rare earth from IFR electrolyte  

DOE Patents (OSTI)

The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

Ackerman, J.P.; Johnson, T.R.

1992-01-01T23:59:59.000Z

204

Process to remove rare earth from IFR electrolyte  

DOE Patents (OSTI)

The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner. 1 fig.

Ackerman, J.P.; Johnson, T.R.

1994-08-09T23:59:59.000Z

205

Metal atomization spray nozzle  

DOE Patents (OSTI)

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

Huxford, T.J.

1993-11-16T23:59:59.000Z

206

Rare Earths Compounds DOI: 10.1002/ange.201002338  

E-Print Network (OSTI)

) characterized by covalent bonds between the transition metals (T) and the highly polarizable (monoatomic) carbon of the transition metals cause high negative charges on the complex carbometalate anions, which have to be balanced a special class of ternary and higher carbides containing complex anions n 1 ðTyCz�m� � � (n = 0, 1, 2, 3

Widom, Michael

207

Fabricated Metals (2010 MECS)  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Fabricated Metals Sector (NAICS 332) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014

208

EMSL - trace metals  

NLE Websites -- All DOE Office Websites (Extended Search)

trace-metals en Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments. http:www.emsl.pnl.govemslwebpublications...

209

Silicon metal-semiconductor-metal photodetector  

DOE Patents (OSTI)

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

210

Silicon metal-semiconductor-metal photodetector  

DOE Patents (OSTI)

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

211

Symmetry reduction of metal phthalocyanines on metals  

Science Journals Connector (OSTI)

The temperature-dependent adsorption behavior of fourfold symmetric metal phthalocyanines (MPcs) on metals with commensurate and incommensurate symmetries was investigated by scanning tunneling microscopy. On the fourfold symmetric Cu(100) surface, planar and fourfold molecular structures in two equivalent orientations were found for MPcs when prepared at room temperature. In addition, two metastable orientations were identified when prepared at low temperature, which can be depopulated upon annealing. MPcs adsorbed on the sixfold symmetric Cu(111) surface showed a disturbed molecular appearance. The symmetry of molecular structures changed from fourfold to twofold, which is discussed in terms of molecule-substrate interaction.

Shih-Hsin Chang; Stefan Kuck; Jens Brede; Leonid Lichtenstein; Germar Hoffmann; Roland Wiesendanger

2008-12-29T23:59:59.000Z

212

Dynamic Effective-Field Scheme for Rare-Earth Systems  

Science Journals Connector (OSTI)

We demonstrate the importance of including the dynamical exchange-interaction term in the Hamiltonian of a rare-earth system. The probability distribution of the dynamic exchange field is derived in the molecular field approximation. The result is exemplified for the zero-field magnetization and crystal field spectroscopy of NdSb.

Albert Furrer and Heinz Heer

1973-11-26T23:59:59.000Z

213

Rare Isotope Beams for the 21st Century  

ScienceCinema (OSTI)

In a scientific keynote address on Friday, June 12 at Michigan State University (MSU) in East Lansing, James Symons, Director of Berkeley Labs Nuclear Science Division (NSD), discussed the exciting research prospects of the new Facility for Rare Isotope Beams (FRIB) to be built at MSUs National Superconducting Cyclotron Laboratory.

James Symons

2010-01-08T23:59:59.000Z

214

Molecular Photodynamics in Rare Gas Solids V. A. Apkarian*  

E-Print Network (OSTI)

Molecular Photodynamics in Rare Gas Solids V. A. Apkarian* Department of Chemistry, University Processes 1490 III. Sample Preparation and Morphology 1492 IV. Photon-Induced Dissociation 1493 V. Perfect I. Introduction A molecular level understanding of dynamics in condensed media is one of the current

Apkarian, V. Ara

215

Cathode-Luminescence of Rare Earths in Coal Ash  

Science Journals Connector (OSTI)

... Samples of a number of Indian coals (from Darjeeling, Assam, Raniganj, Jharia and Hyderabad) were incinerated in thin layers ... in an electric furnace at 400° C. The presence of rare earths in the ashes so obtained could not be detected by arc spectrographic analysis with a current of 10 ...

BIBHUTI MUKHERJEE

1949-03-12T23:59:59.000Z

216

Status of Rare Kaon Decay Experiments at BNL  

E-Print Network (OSTI)

Status of Rare Kaon Decay Experiments at BNL Toshio Numao TRIUMF June 9, at CAP2003 K #12;s d z;#12;#12;Improvements RS chamber Z resolution Energy resolution 2002 1998 #12;#12;L0- Previous search: 5.9 Ã? 10-7 KOPIO is waiting for us. #12;

217

HYDROLOGY AND GEOMORPHOLOGY OF A RARE FLOOD, BLACKBURN FORK,  

E-Print Network (OSTI)

-prediction. � Discharge measurements based on boulder size appear to give more reasonable estimates of flood dischargeHYDROLOGY AND GEOMORPHOLOGY OF A RARE FLOOD, BLACKBURN FORK, PUTNAM-JACKSON COUNTIES 18 AUGUST 2010) #12;Source: NOAA 17-18 Aug 2010 #12;#12;FLOOD DAMAGE #12;#12;#12;#12;#12;#12;#12;#12;#12;4 bridges

Hart, Evan

218

PRACTICAL APPLICATION OF THE SINGLE-PARAMETER SUBCRITICAL MASS LIMIT FOR PLUTONIUM METAL  

SciTech Connect

According to ANS-8.1, operations with fissile materials can be performed safely by complying with any of the listed single-parameter subcritical limits. For metallic units, when interspersed moderators are present, the mass limits apply to a single piece having no concave surfaces. On a practical level, when has any operation with fissile metal involved a single piece and absolutely no moderating material, e.g., water, oil, plastic, etc.? This would be rare. This paper explores the application of the single-parameter plutonium metal mass limit for realistic operational environments.

MITCHELL, MARK VON [Los Alamos National Laboratory

2007-01-10T23:59:59.000Z

219

Synthesizing Membrane Proteins Using In Vitro Methodology | Argonne...  

NLE Websites -- All DOE Office Websites (Extended Search)

Proteins Using In Vitro Methodology Technology available for licensing: in vitro, cell-free expression system that caters to the production of protein types that are challenging...

220

Interlaboratory Evaluation of in Vitro Cytotoxicity and Inflammatory...  

NLE Websites -- All DOE Office Websites (Extended Search)

in Vitro Cytotoxicity and Inflammatory Responses to Engineered Nanomaterials: The NIEHS Nano GO Interlaboratory Evaluation of in Vitro Cytotoxicity and Inflammatory Responses to...

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

PHYTOEXTRACTION OF HEAVY METALS  

E-Print Network (OSTI)

) Type of phytoremediation Cost effective form of environmental remediation (Glass 1999) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al -using hyperaccumulator plant biomass to produce a bio-ore for commercial use -Li et al. look at using Ni

Blouin-Demers, Gabriel

222

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

223

Electroreflectance in Metals  

Science Journals Connector (OSTI)

Calculations have been made which suggest that the prominent maximum in the electroreflectance spectra of metals observed by Feinleib is not due to modulation of the optical constants of the electrolyte, but to modulation of the optical constants of the metal.

Arnold Prostak and Wilford N. Hansen

1967-08-15T23:59:59.000Z

224

Production of magnesium metal  

SciTech Connect

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

2010-02-23T23:59:59.000Z

225

Metal-Nonmetal Transition in Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

A review is given of the properties of metal-ammonia solutions together with a summary of the evidence for the existence of a metal-nonmetal transition.

J. C. THOMPSON

1968-10-01T23:59:59.000Z

226

Liquid metal electric pump  

DOE Patents (OSTI)

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

227

Influence of mechanoactivation on rare earths leaching from phosphogypsum  

Science Journals Connector (OSTI)

The influence of mechanoactivation on the overall solubility of CaSO4 · 2H2O and of phosphogypsum in water and in diluted acids (10% HCl, 7% H2SO4) as well as on the leaching of rare earths from phosphogypsum have been studied. The mechanoactivation is performed in a centrifugal ball mill in air and in suspension with the acids mentioned above. Part of the experimental results are qualitatively explained considering the partial dehydration of the CaSO4 · 2H2O during the activation in air as well as considering the crystal structure disrupted by mechanoactivation. A dissolved fraction, considerably enriched in rare earths (compared to the initial phosphogypsum) is obtained as a result of H2SO4 treatment of the samples activated in water solution.

D. Todorovsky; A. Terziev; M. Milanova

1997-01-01T23:59:59.000Z

228

Magnetic Symmetry of Rare-Earth Orthochromites and Orthoferrites  

Science Journals Connector (OSTI)

A new magnetic symmetry of the rare-earth orthochromites and orthoferrites (RMO3) below the second Néel temperature due to the reordering of the rare-earth spins is proposed. It is shown that the magnetic symmetry group is lowered to the subgroup of index two, thereby keeping the unit cell invariant. The proposed symmetry is shown to be consistent with the previously observed spin configuration of RMO3 such as GdCrO3, DyFeO3, and DyCrO3, and would also be consistent with those of other RMO3. Although symmetry arguments and the calculation of the free energy show that two spin configurations are stable, in GdCrO3, a future measurement of the magnetoelectric tensor would determine which configuration GdCrO3 has. It is further predicted that the magnetoelectric effect should be observed in any RMO3 below the second Néel temperature.

Tsuyoshi Yamaguchi and Kunirô Tsushima

1973-12-01T23:59:59.000Z

229

New physics in CP asymmetries and rare B decays  

Science Journals Connector (OSTI)

We review and update the effects of physics beyond the standard model on CP asymmetries in B decays. These asymmetries can be significantly altered if there are important new-physics contributions to Bq0-Bq0¯ mixing. This same new physics will, therefore, also contribute to rare, flavor-changing B decays. Through a study of such decays, we show that it is possible to partially distinguish the different models of new physics.

Michael Gronau and David London

1997-03-01T23:59:59.000Z

230

Physics and Outlook for Rare, All-neutral Eta Decays  

SciTech Connect

The $\\eta$ meson provides a laboratory to study isospin violation and search for new flavor-conserving sources of C and CP violation with a sensitivity approaching $10^{-6}$ of the isospin-conserving strong amplitude. Some of the most interesting rare $\\eta$ decays are the neutral modes, yet the effective loss of photons from the relatively common decay $\\eta \\rightarrow 3\\pi^0 \\rightarrow 6\\gamma$ (33$\\%$) has largely limited the sensitivity for decays producing 3-5$\\gamma$'s. Particularly important relevant branches include the highly suppressed $\\eta \\rightarrow \\pi^0 2\\gamma \\rightarrow 4\\gamma$, which provides a rare window on testing models of $O(p^6)$ contributions in ChPTh, and $\\eta \\rightarrow 3\\gamma$ and $\\eta \\rightarrow 2\\pi^0 \\gamma \\rightarrow 5\\gamma$ which provide direct constraints on C violation in flavor-conserving processes. The substitution of lead tungstate in the forward calorimeter of the GluEx setup in Jefferson Lab's new Hall D would allow dramatically improved measurements. The main niche of this facility, which we call the JLab Eta Factory (JEF), would be $\\eta$ decay neutral modes. However, this could likely be expanded to rare $\\eta'(958)$ decays for low energy QCD studies as well as $\\eta$ decays involving muons for new physics searches.

Mack, David J. [JLAB

2014-06-01T23:59:59.000Z

231

Divalent metal nanoparticles  

E-Print Network (OSTI)

Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

DeVries, Gretchen Anne

2008-01-01T23:59:59.000Z

232

Nitrided Metallic Bipolar Plates  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

to meet 5000 h automotive durability goal at cost < 5kW Year 1 Goals: Single-cell fuel cell test performance for 25 cm 2 stamped and nitrided metallic bipolar plates...

233

Metal stocks and sustainability  

Science Journals Connector (OSTI)

...dissipated through corrosion and wear, and some enters waste repositories...landfills. Dissipation from wear and corrosion is generally small...dispersion of metals from wear and corrosion is an important...transportation (railroad, marine, aircraft, and aerospace equipment...

R. B. Gordon; M. Bertram; T. E. Graedel

2006-01-01T23:59:59.000Z

234

Oligocyclopentadienyl transition metal complexes  

SciTech Connect

Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

de Azevedo, Cristina G.; Vollhardt, K. Peter C.

2002-01-18T23:59:59.000Z

235

Excitons in Metals  

Science Journals Connector (OSTI)

It is shown that exciton states exist in metals, occurring near the interband threshold in optical absorption and substantially altering the shape and strength of the absorption edge. Their relation to the corresponding donor states is discussed.

G. D. Mahan

1967-03-20T23:59:59.000Z

236

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents (OSTI)

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

237

Metallic glass composition  

DOE Patents (OSTI)

A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

1986-01-01T23:59:59.000Z

238

Molten metal reactors  

DOE Patents (OSTI)

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

2013-11-05T23:59:59.000Z

239

Functionalized Silicone Nanospheres: Synthesis, Transition Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

240

COLLISIONS OF HALOGEN (2P) AND RARE GAS (1S) ATOMS  

E-Print Network (OSTI)

involving 2p excited states of alkali atoms, with groundstate rare gas atoms (RG), though other systems have been2p ) AND RARE GAS (IS) ATOMS Christopher Hank Becker (Ph. D.

Becker, Christopher Hank

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal Byproducts DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal...

242

Crystal Fields and the Effective-Point-Charge Model in the Rare-Earth Pnictides  

Science Journals Connector (OSTI)

Neutron scattering and specific-heat studies of the crystal fields in the rare-earth monophosphides are reported. It is found that the fourth-order crystal-field parameters for the phosphides and for other rare-earth pnictides fall on a universal curve which is close to that predicted by an effective-point-charge model for the light rare earths but deviates markedly for the heavy rare earths.

R. J. Birgeneau; E. Bucher; J. P. Maita; L. Passell; K. C. Turberfield

1973-12-15T23:59:59.000Z

243

Liquid metal thermal electric converter  

DOE Patents (OSTI)

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

244

Rare earth elements activate endocytosis in plant cells Lihong Wanga,b,1  

E-Print Network (OSTI)

Rare earth elements activate endocytosis in plant cells Lihong Wanga,b,1 , Jigang Lic,d,1 , Qing (sent for review May 15, 2014) It has long been observed that rare earth elements (REEs) regulate, such as rare earth elements (REEs), have been observed for a long time to be beneficial to plant growth (1, 2

Deng, Xing-Wang

245

VISIBLE AND INFRARED RARE-EARTH ACTIVATED ELECTROLUMINESCENCE FROM ERBIUM DOPED GaN  

E-Print Network (OSTI)

. At the same time novel work is being conducted using rare earth elements as sources of light emission. Results. III-V semiconductors doped with rare-earth elements have also been used10VISIBLE AND INFRARED RARE-EARTH ACTIVATED ELECTROLUMINESCENCE FROM ERBIUM DOPED GaN M. Garter*, R

Steckl, Andrew J.

246

Rare earth elements in the sediments of Lake Baikal Lawrence M. Och a  

E-Print Network (OSTI)

Rare earth elements in the sediments of Lake Baikal Lawrence M. Och a , Beat Müller a, , Adrian Available online 3 April 2014 Editor: Carla M. Koretsky Keywords: Rare earth elements Cerium anomaly Lake to complex and cryptic redox cycles. The mobility of rare earth elements (REEs) is influenced

Wehrli, Bernhard

247

Speciation of adsorbed yttrium and rare earth elements on oxide surfaces  

E-Print Network (OSTI)

Speciation of adsorbed yttrium and rare earth elements on oxide surfaces Wojciech Piasecki, Dimitri 10 June 2008 Abstract The distribution of yttrium and the rare earth elements (YREE) between natural investigate the applicability of the X-ray results to rare earth elements and to several oxides in addition

Sverjensky, Dimitri A.

248

Growth and characterization of rare-earth monosulfides for cold cathode applications  

E-Print Network (OSTI)

of chalco- genides of the rare-earth elements.4,5 The possibility was analyzed theoretically basedGrowth and characterization of rare-earth monosulfides for cold cathode applications Y. Modukuru, J phonons at 261 284 and 100 92 cm 1 with LaS NdS , respectively. These rare-earth monosulfides offer

Boolchand, Punit

249

Source and mobility of Rare Earth Elements in a sedimentary aquifer system: Aquitaine basin (Southern France)  

E-Print Network (OSTI)

Source and mobility of Rare Earth Elements in a sedimentary aquifer system: Aquitaine basin Geological Survey Service, Bordeaux, France, e.malcuit@brgm.fr The study of rare earth elements (REEs such as rivers and lakes and groundwaters. Rare earth elements) are of great interest because of their unique

Paris-Sud XI, Université de

250

Use of rare earth elements as external markers for mean retention time measurements in ruminants  

E-Print Network (OSTI)

Review Use of rare earth elements as external markers for mean retention time measurements -- The present review deals with the utilisation of rare earth (RE) elements as particulate markers for ruminant earth / retention time / feedstuff / methodology / ruminant Résumé -- Utilisation des terres rares comme

Paris-Sud XI, Université de

251

Hydrothermal transport and deposition of the rare earth elements by fluorine-bearing aqueous liquids  

E-Print Network (OSTI)

ARTICLE Hydrothermal transport and deposition of the rare earth elements by fluorine environmental concerns, have created a great demand for the rare earth elements (REE), and focused considerable Hydrothermal concentration of the rare earth elements (REE) to economic and potentially economic levels has

252

As China's Rare Earth R&D Becomes Ever More Rarefied, Others Tremble  

Science Journals Connector (OSTI)

...production and slap export tariffs on some rare...paper last month, China's Ministry of Industry...idea of prohibiting export of three scarcer rare earths...company in London. China has a “natural monopoly...complex hydrocarbons in petroleum refining. Military...which forced China to import processed rare earths...

Richard Stone

2009-09-11T23:59:59.000Z

253

High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

254

Theory of Rayleigh waves on paramagnetic rare-earth systems  

Science Journals Connector (OSTI)

We present calculations of the velocity changes of Rayleigh waves in cubic, paramagnetic rare-earth systems due to magnetoelastic interactions. These interactions describe the coupling of the strain and rotational part of the deformation tensor to the incomplete 4f shell. They can be influenced by applying a magnetic field. An equation is obtained which generalizes that of Stoneley for cubic systems without magnetoelastic interactions. Special attention is paid to effects resulting from the rotational interactions. The theory is applied to CeAl2 for which experiments are available.

Robert Camley and Peter Fulde

1981-03-15T23:59:59.000Z

255

Search for New Physics in Rare Top Decays  

E-Print Network (OSTI)

Top physics provides a fertile ground for new-physics searches. At present, most top observables appear to be in good agreement with the respective Standard Model predictions. However, in the case of decay modes that are suppressed in the Standard Model, new-physics contributions of comparable magnitude may exist and yet go unnoticed because their impact on the total decay width is small. Hence it is interesting to probe rare top decays. This analysis focuses on the decay $t \\to b \\bar b c$. Useful observables are identified and prospects for measuring new-physics parameters are examined.

Pratishruti Saha

2014-11-27T23:59:59.000Z

256

Summary of the CKM 2014 working group on rare decays  

E-Print Network (OSTI)

Rare flavour changing neutral current decays of strange, charm and beauty hadrons have been instrumental in building up a picture of flavour in the Standard Model. Increasingly precise measurements of these decays allow to search for deviations from predictions of the Standard Model that would be associated to contributions from new particles that might arise in extensions of the Standard Model. In this summary, an overview of recent experimental results and theoretical predictions is given. The new physics sensitivity and prospects for the different observables is also addressed.

Blake, Thomas; Straub, David M

2015-01-01T23:59:59.000Z

257

Summary of the CKM 2014 working group on rare decays  

E-Print Network (OSTI)

Rare flavour changing neutral current decays of strange, charm and beauty hadrons have been instrumental in building up a picture of flavour in the Standard Model. Increasingly precise measurements of these decays allow to search for deviations from predictions of the Standard Model that would be associated to contributions from new particles that might arise in extensions of the Standard Model. In this summary, an overview of recent experimental results and theoretical predictions is given. The new physics sensitivity and prospects for the different observables is also addressed.

Thomas Blake; Akimasa Ishikawa; David M. Straub

2015-01-20T23:59:59.000Z

258

K Series X-Ray Wavelengths in Rare Earth Elements  

Science Journals Connector (OSTI)

The K-series x-rays in ten rare earth elements have been studied with a two-meter-radius bent-quartz-crystal spectrograph. The 3.7-Mev proton beam of the A-48 accelerator (UCRL, Livermore) was used to produce the atomic excitations. The wavelengths obtained for the K?1, K?2, K?3, and K?1 lines are compared with previous wavelength measurements. Two weaker transitions, K?5 and KOIIOIII, were also observed and the energies are compared with energies obtained from tables of known atomic energy levels.

E. L. Chupp, J. W. M. Du Mond, F. J. Gordon, R. C. Jopson, and Hans Mark

1958-11-15T23:59:59.000Z

259

Multicanonical sampling of rare events in random matrices  

SciTech Connect

A method based on multicanonical Monte Carlo is applied to the calculation of large deviations in the largest eigenvalue of random matrices. The method is successfully tested with the Gaussian orthogonal ensemble, sparse random matrices, and matrices whose components are subject to uniform density. Specifically, the probability that all eigenvalues of a matrix are negative is estimated in these cases down to the values of {approx}10{sup -200}, a region where simple random sampling is ineffective. The method can be applied to any ensemble of matrices and used for sampling rare events characterized by any statistics.

Saito, Nen; Iba, Yukito; Hukushima, Koji [Graduate School of Science and Cybermedia Center, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Institute of Statistical Mathematics, 10-3 Midorimachi, Tachikawa, Tokyo 190-8562 (Japan); Department of Basic Science, University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902 (Japan)

2010-09-15T23:59:59.000Z

260

190 IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 30, NO. 1, FEBRUARY 2002 Gap Closure in a Cold Metal Halide Lamp  

E-Print Network (OSTI)

lamp has been investigated using a two-dimensional, plasma transport model. Im- ages are presented- charge devices, lighting, plasma applications. METAL halide high-intensity-discharge (HID) lamps op- erate as high-pressure thermal arcs [1]. The cold fills of HID lamps are typically 50­100 torr of a rare

Kushner, Mark

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Iron Isotope and Rare Earth Element Patterns of the Neoproterozoic Fulu Formation, South China: Implications for Late Proterozoic Ocean Chemistry  

E-Print Network (OSTI)

13 3.5. Rare Earth Element Analysis…………………………………………. ……15 4.21 b. 5.2. Rare Earth Element Patterns……………………………………………24 6.Piper, D. Z. (1974). Rare earth elements in the sedimentary

Goldbaum, Elizabeth

2014-01-01T23:59:59.000Z

262

Hard metal composition  

DOE Patents (OSTI)

A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

Sheinberg, H.

1983-07-26T23:59:59.000Z

263

Hard metal composition  

DOE Patents (OSTI)

A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

Sheinberg, Haskell (Los Alamos, NM)

1986-01-01T23:59:59.000Z

264

Catalysis Without Precious Metals  

SciTech Connect

Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

Bullock, R. Morris

2010-11-01T23:59:59.000Z

265

Metal alloy identifier  

DOE Patents (OSTI)

To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

1987-01-01T23:59:59.000Z

266

Evolution of Spin-Wave Excitations in Ferromagnetic Metallic Manganites  

SciTech Connect

Neutron scattering results are presented for spin-wave excitations of three ferromagnetic metallic A1xA0xMnO3 manganites (where A and A0 are rare- and alkaline-earth-metal ions), which when combined with previous work elucidate the systematics of the interactions as a function of carrier concentration x, on-site disorder, and strength of the lattice distortion. The long-wavelength spin dynamics show only a very weak dependence across the series. The ratio of fourth to first neighbor exchange (J4=J1) that controls the zone boundary magnon softening changes systematically with x, but does not depend on the other parameters. None of the prevailing models can account for these behaviors.

Ye, Feng [ORNL; Dai, Pengcheng [ORNL; Fernandez-Baca, Jaime A [ORNL; Sha, Hao [Florida International University, Miami; Lynn, J. W. [National Institute of Standards and Technology (NIST); Kawano-Furukawa, H. [Ochanomizu University, Japan; Tomioka, Y. [Correlated Electron Research Center (CERC), Japan; Tokura, Y. [University of Tokyo, Tokyo, Japan; Zhang, Jiandi [Florida International University, Miami

2006-01-01T23:59:59.000Z

267

Evolution of Spin-Wave Excitations in Ferromagnetic Metallic Manganites  

SciTech Connect

Neutron scattering results are presented for spin-wave excitations of three ferromagnetic metallic A{sub 1-x}A{sub x}{sup '}MnO{sub 3} manganites (where A and A{sup '} are rare- and alkaline-earth-metal ions), which when combined with previous work elucidate the systematics of the interactions as a function of carrier concentration x, on-site disorder, and strength of the lattice distortion. The long-wavelength spin dynamics show only a very weak dependence across the series. The ratio of fourth to first neighbor exchange (J{sub 4}/J{sub 1}) that controls the zone boundary magnon softening changes systematically with x, but does not depend on the other parameters. None of the prevailing models can account for these behaviors.

Ye, F. [Center for Neutron Scattering, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6393 (United States); Dai Pengcheng [Department of Physics and Astronomy, University of Tennessee, Knoxville, Tennessee 37996-1200 (United States); Center for Neutron Scattering, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6393 (United States); Fernandez-Baca, J.A. [Center for Neutron Scattering, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6393 (United States); Department of Physics and Astronomy, University of Tennessee, Knoxville, Tennessee 37996-1200 (United States); Sha Hao; Zhang Jiandi [Department of Physics, Florida International University, Miami, Florida 33199 (United States); Lynn, J.W. [NIST Center for Neutron Research, Gaithersburg, Maryland 20899 (United States); Kawano-Furukawa, H. [Department of Physics, Ochanomizu University, Bunkyo-ku, Tokyo 112-8610 (Japan); Tomioka, Y. [Correlated Electron Research Center (CERC), Tsukuba 305-0046 (Japan); Tokura, Y. [Correlated Electron Research Center (CERC), Tsukuba 305-0046 (Japan); Department of Applied Physics, University of Tokyo, Tokyo 113-8656 (Japan)

2006-02-03T23:59:59.000Z

268

ARM facility captures rare tornado data [EVS News]  

NLE Websites -- All DOE Office Websites (Extended Search)

ARM facility captures rare tornado data ARM facility captures rare tornado data June 13, 2013 Every spring, tornadoes thunder across five states, from Kansas to Texas, and alerts are common. However, by Monday, May 20, it was clear that this time the alert had a different urgency to it. The turn of events leading up to the EF-5 tornado that wreaked havoc in Moore, Oklahoma, provided a unique opportunity for scientists to sample the environment preceding a severe weather event. Read more about how EVS scientist, Donna Holdridge, supported the ARM program in the full article. Raw data from the additional radiosonde launches preceding the severe weather events of May 20 in Oklahoma. The blue line identifies the temperature, which decreases with increasing altitude. The red line is the dew point, the temperature at which the air is 100% saturated with its water vapor content. Where the dew point approaches the actual temperature, the air is nearing 100% relative humidity near the ground-ideal conditions for tornado events.

269

Ab Initio Nuclear Structure and Reaction Calculations for Rare Isotopes  

SciTech Connect

We have developed a novel ab initio symmetry-adapted no-core shell model (SA-NCSM), which has opened the intermediate-mass region for ab initio investigations, thereby providing an opportunity for first-principle symmetry-guided applications to nuclear structure and reactions for nuclear isotopes from the lightest p-shell systems to intermediate-mass nuclei. This includes short-lived proton-rich nuclei on the path of X-ray burst nucleosynthesis and rare neutron-rich isotopes to be produced by the Facility for Rare Isotope Beams (FRIB). We have provided ab initio descriptions of high accuracy for low-lying (including collectivity-driven) states of isotopes of Li, He, Be, C, O, Ne, Mg, Al, and Si, and studied related strong- and weak-interaction driven reactions that are important, in astrophysics, for further understanding stellar evolution, X-ray bursts and triggering of s, p, and rp processes, and in applied physics, for electron and neutrino-nucleus scattering experiments as well as for fusion ignition at the National Ignition Facility (NIF).

Draayer, Jerry P [Louisiana State University

2014-09-28T23:59:59.000Z

270

Recent hybrid origin of three rare chinese turtles  

SciTech Connect

Three rare geoemydid turtles described from Chinese tradespecimens in the early 1990s, Ocadia glyphistoma, O. philippeni, andSacalia pseudocellata, are suspected to be hybrids because they are knownonly from their original descriptions and because they have morphologiesintermediate between other, better-known species. We cloned the allelesof a bi-parentally inherited nuclear intron from samples of these threespecies. The two aligned parental alleles of O. glyphistoma, O.philippeni, and S. pseudocellata have 5-11.5 times more heterozygouspositions than do 13 other geoemydid species. Phylogenetic analysis showsthat the two alleles from each turtle are strongly paraphyletic, butcorrectly match sequences of other species that were hypothesized frommorphology to be their parental species. We conclude that these rareturtles represent recent hybrids rather than valid species. Specifically,"O. glyphistoma" is a hybrid of Mauremys sinensis and M. cf. annamensis,"O. philippeni" is a hybrid of M. sinensis and Cuora trifasciata, and "S.pseudocellata" is a hybrid of C. trifasciata and S. quadriocellata.Conservation resources are better directed toward finding and protectingpopulations of other rare Southeast Asian turtles that do representdistinct evolutionary lineages.

Stuart, Bryan L.; Parham, James F.

2006-02-07T23:59:59.000Z

271

Wick for metal vapor laser  

DOE Patents (OSTI)

An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

Duncan, David B. (Livermore, CA)

1992-01-01T23:59:59.000Z

272

Grant Helps Make U.S. Rare Earth Magnets More Common | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grant Helps Make U.S. Rare Earth Magnets More Common Grant Helps Make U.S. Rare Earth Magnets More Common Grant Helps Make U.S. Rare Earth Magnets More Common August 6, 2010 - 12:12pm Addthis With sintered rare earth magnets a $4 billion worldwide market, the U.S. could be a bigger producer of these magnets - which are not actually rare - and are used in hybrid vehicle motors and wind turbine generators. | Illustration Courtesy of of Electron Energy Corporation | With sintered rare earth magnets a $4 billion worldwide market, the U.S. could be a bigger producer of these magnets - which are not actually rare - and are used in hybrid vehicle motors and wind turbine generators. | Illustration Courtesy of of Electron Energy Corporation | Kevin Craft Electron Energy Corporation is one of a kind. According to Peter Dent, vice president of business development for the

273

Grant Helps Make U.S. Rare Earth Magnets More Common | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grant Helps Make U.S. Rare Earth Magnets More Common Grant Helps Make U.S. Rare Earth Magnets More Common Grant Helps Make U.S. Rare Earth Magnets More Common August 6, 2010 - 12:12pm Addthis With sintered rare earth magnets a $4 billion worldwide market, the U.S. could be a bigger producer of these magnets - which are not actually rare - and are used in hybrid vehicle motors and wind turbine generators. | Illustration Courtesy of of Electron Energy Corporation | With sintered rare earth magnets a $4 billion worldwide market, the U.S. could be a bigger producer of these magnets - which are not actually rare - and are used in hybrid vehicle motors and wind turbine generators. | Illustration Courtesy of of Electron Energy Corporation | Kevin Craft Electron Energy Corporation is one of a kind. According to Peter Dent, vice president of business development for the

274

Thermal conductance of metal-metal interfaces  

Science Journals Connector (OSTI)

The thermal conductance of interfaces between Al and Cu is measured in the temperature range 78metal-dielectric interfaces. The magnitude and the linear temperature dependence of the conductance are described well by a diffuse-mismatch model for electron transport at interfaces.

Bryan C. Gundrum; David G. Cahill; Robert S. Averback

2005-12-30T23:59:59.000Z

275

Moving to Metal  

Science Journals Connector (OSTI)

It is possible to 3D print in metal starting with a powder that...sintered...) by a laser or glued with a binder. As of this writing, this remains a very expensive process, and these are not desktop consumer prin...

Joan Horvath

2014-01-01T23:59:59.000Z

276

Mathematics in metal  

Science Journals Connector (OSTI)

...sculptures begin as a piece of computer code that dictates how the metal-printed parts fit together. She’s been using 3D printing for 15 years to forge her work and says the recent surge in popularity of the technology has opened up a few new opportunities...

Stephen Ornes

2013-01-01T23:59:59.000Z

277

Serpentine metal gasket  

DOE Patents (OSTI)

A metallic seal or gasket for use in the joining of cryogenic fluid conduits, the seal or gasket having a generally planar and serpentine periphery defining a central aperture. According to a preferred embodiment, the periphery has at least two opposing elongated serpentine sides and two opposing arcuate ends joining the opposing elongated serpentine sides and is of a hexagonal cross-section.

Rothgeb, Timothy Moore (Norfolk, VA); Reece, Charles Edwin (Yorktown, VA)

2009-06-02T23:59:59.000Z

278

Metal stocks and sustainability  

Science Journals Connector (OSTI)

...1–4). Unlike oil, which is irremediably...relative scarcity (or price) of the material substituted...interior wiring; plumbing, heating, and architectural uses; and...defined in terms of current prices and costs of production; this...cost-effective at current metal prices. Because the real price of copper has remained...

R. B. Gordon; M. Bertram; T. E. Graedel

2006-01-01T23:59:59.000Z

279

Pile on the metal  

Science Journals Connector (OSTI)

Discovering superconductivity above room temperature is a dream for modern science and technology. Now, theorists propose that for certain types of superconductors, contact with a metal layer could greatly increase the transition temperatures of these materials—in some cases by as much as an order of magnitude.

Dung-Hai Lee

2008-09-15T23:59:59.000Z

280

Photomagnetism of metals  

Science Journals Connector (OSTI)

A photoinduced magnetic moment has been observed in Cu and Al samples exposed to unpolarized visible light at low temperatures. It is shown that the light refected from a metal surface transfers some of its quasimomentum to conduction electrons. This mechanism creates surface currents which, for an appropriate geometry, bring about the photomagnetic effect.

V. L. Gurevich; R. Laiho; A. V. Lashkul

1992-07-06T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Lithium Metal Anodes for Rechargeable Batteries. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal Anodes for Rechargeable Batteries. Lithium Metal Anodes for Rechargeable Batteries. Abstract: Rechargeable lithium metal batteries have much higher energy density than those...

282

LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells  

DOE Patents (OSTI)

An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

1999-03-30T23:59:59.000Z

283

Extensive Interstitial Solid Solutions of Metals in Metals  

Science Journals Connector (OSTI)

A new type of metallic solid solution has been prepared in which <~12.5 at.% of comparatively small metal atoms (Cu) fill interstitial sites in a host metal composed of larger atoms (Y). At higher solute concentrations, both interstitial and substitutional sites are occupied. These solid solutions are metastable; they were formed by ultrarapid quenching from the liquid.

B. C. Giessen; R. Ray; S. H. Hahn

1971-03-01T23:59:59.000Z

284

Purification of alkali metal nitrates  

DOE Patents (OSTI)

A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Gregory, Kevin M. (Woodridge, IL)

1985-05-14T23:59:59.000Z

285

Metal Aminoboranes - Energy Innovation Portal  

NLE Websites -- All DOE Office Websites (Extended Search)

of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other...

286

Metal-Ion-Mediated Reactions  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Print Monday, 19 December 2011 18:29 While mononuclear, polynuclear, and polymeric metal complexes are most often synthesized by the reaction of a metal precursor and a presynthesized organic ligand, it is also possible to generate the ligand in situ from an easily available organic compound. This approach allows the reactivity of the metal ion to activate a proligand, transforming it through an in situ reaction, sometimes providing coordination compounds with ligands not accessible by conventional organic synthesis. The intense interest in the reactivity of coordinated ligands is mainly due to the necessity of interpreting the mechanisms of homogeneous metal-catalyzed processes, in which a substrate is activated upon its coordination to one or more metal sites. A coordinated oxime group contains three active sites (C, N, O) for reactivity.

287

PROTOLYSE TRYPSIQUE IN VITRO DE DIVERS ALIMENTS  

E-Print Network (OSTI)

PROT�OLYSE TRYPSIQUE IN VITRO DE DIVERS ALIMENTS Marie-Claire CAMUS, J.-C. LAPORTE C. SAUTIER Unité protéolyse pepsique (CAMUS et SAUTIER, 1972) avait montré des différences surtout pendant la phase initiale

Boyer, Edmond

288

Upgrading platform using alkali metals  

DOE Patents (OSTI)

A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

Gordon, John Howard

2014-09-09T23:59:59.000Z

289

Exchange-excited f-f transitions in the electron-energy-loss spectra of rare-earth metals  

Science Journals Connector (OSTI)

Dipole-forbidden f-f multiplet excitations are found to characterize the electron-energy-loss spectra of Pr, Nd, Sm, Gd, Tb, Dy, Ho, and Er when the primary-electron energy is close to the binding energy of the 4d electrons. In Sm and Gd the f-f transitions are also detected at lower primary energies. The identification of the sharp peaks observed in the spectra as f-f excitations comes from straightforward comparison with the absorption spectra of the trivalent ions. The excitation energies of the f-f transitions are found to depend very weakly on the chemical environment. The exchange nature of the f-f excitation process explains the strong decrease of the intensities of the f-f peaks when the primary energy is raised, and is consistent with the resonant enhancement observed for primary energies near the 4d-4f threshold. A similar resonance is also observed in the primary-energy dependence of the intensity of the plasmon peak.

F. Della Valle and S. Modesti

1989-07-15T23:59:59.000Z

290

Public to have rare opportunity to tour Neutron Science Center  

NLE Websites -- All DOE Office Websites (Extended Search)

Rosenfest: celebrate Louis Rosen, tour LANSCE Rosenfest: celebrate Louis Rosen, tour LANSCE Public to have rare opportunity to tour Neutron Science Center Tour attendees can expect to see many facets of the LANSCE, including areas along the linear accelerator beam line, the control room area, and one or more experimental areas. May 10, 2011 Aerial View of Neutron Science Center Aerial View of Neutron Science Center Contact James Rickman Communicatons Office (505) 665-9203 Email LANL Rosenfest will celebrate life of LANSCE founder Louis Rosen and offer tour LOS ALAMOS, New Mexico, May 10, 2011-Members of the public will have an unusual opportunity to tour the Los Alamos Neutron Science Center from 1 to 5 p.m. on Friday, May 20, 2011, as part of Rosenfest, a celebration of LANSCE founder Louis Rosen and the remarkable facility he conceived. In

291

Microsoft Word - Rare Earth Update for RFI 110523final  

NLE Websites -- All DOE Office Websites (Extended Search)

J. Thijssen, LLC P: 206 229 6882 J. Thijssen, LLC P: 206 229 6882 4910 163 rd Ave NE Redmond, WA 98052 e: jant@jthijssen.com Solid Oxide Fuel Cells and Critical Materials: A Review of Implications J. Thijssen, LLC Report Number: R102 06 04D1 Date: May 10, 2011 Prepared for: National Energy Technology Laboratory, In Sub-Contract to Leonardo Technologies, Inc. Contract Number: DE-FE0004002 (Subcontract: S013-JTH-PPM4002 MOD 00) 2 Summary The US DOE has identified a number of materials that are both used by clean energy technologies and are at risk of supply disruptions in the short term. Several of these materials, especially the rare earth elements (REEs) yttrium, cerium, and lanthanum were identified by DOE as critical (USDOE 2010) and are crucial to the function and performance of solid oxide

292

Shell model Monte Carlo investigation of rare earth nuclei  

Science Journals Connector (OSTI)

We utilize the shell model Monte Carlo method to study the structure of rare earth nuclei. This work demonstrates the first systematic full oscillator shell with intruder calculations in such heavy nuclei. Exact solutions of a pairing plus quadrupole Hamiltonian are compared with the static path approximation in several dysprosium isotopes from A=152 to 162, including the odd mass A=153. Some comparisons are also made with Hartree-Fock-Bogoliubov results from Baranger and Kumar. Basic properties of these nuclei at various temperatures and spin are explored. These include energy, deformation, moments of inertia, pairing channel strengths, band crossing, and evolution of shell model occupation numbers. Exact level densities are also calculated and, in the case of 162Dy, compared with experimental data.

J. A. White; S. E. Koonin; D. J. Dean

2000-02-14T23:59:59.000Z

293

Ab initio correlated calculations of rare-gas dimer quadrupoles  

SciTech Connect

This paper reports ab initio calculations of rare gas (RG=Kr, Ar, Ne, and He) dimer quadrupoles at the second order of Moeller-Plesset perturbation theory (MP2). The study reveals the crucial role of the dispersion contribution to the RG{sub 2} quadrupole in the neighborhood of the equilibrium dimer separation. The magnitude of the dispersion quadrupole is found to be much larger than that predicted by the approximate model of Hunt. As a result, the total MP2 quadrupole moment is significantly smaller than was assumed in virtually all previous related studies. An analytical model for the distance dependence of the RG{sub 2} quadrupole is proposed. The model is based on the effective-electron approach of Jansen, but replaces the original Gaussian approximation to the electron density in an RG atom by an exponential one. The role of the nonadditive contribution in RG{sub 3} quadrupoles is discussed.

Donchev, Alexander G. [Algodign, LLC, Bolshaya Sadovaya 8, Moscow 123001 (Russian Federation)

2007-10-15T23:59:59.000Z

294

New results in rare allowed muon and pion decays  

E-Print Network (OSTI)

Simple dynamics, few available decay channels, and highly controlled radiative and loop corrections, make pion and muon decays a sensitive means of exploring details of the underlying symmetries. We review the current status of the rare decays: pi+ -> e+ nu, pi+ -> e+ nu gamma, pi+ -> pi0 e+ nu, and mu+ -> e+ nu nu-bar gamma. For the latter we report new preliminary values for the branching ratio B(E_gamma >10 MeV, theta_(e-gamma) > 30deg) = 4.365 (9)_stat (42)_syst x 10^{-3}, and the decay parameter eta-bar = 0.006 (17)_stat (18)_syst, both in excellent agreement with standard model predictions. We review recent measurements, particularly by the PIBETA and PEN experiments, and near-term prospects for improvement. These and other similar precise low energy studies complement modern collider results materially.

D. Pocanic; E. Munyangabe; M. Bychkov; V. A. Baranov; W. Bertl; Yu. M. Bystritsky; E. Frlez; V. A. Kalinnikov; N. V. Khomutov; A. S. Korenchenko; S. M. Korenchenko; M. Korolija; T. Kozlowski; N. P. Kravchuk; N. A. Kuchinsky; M. C. Lehman; D. Mekterovic; D. Mzhavia; A. Palladino; P. Robmann; A. M. Rozhdestvensky; I. Supek; P. Truoel; Z. Tsamalaidze; A. van der Schaaf; B. Vandevender; E. P. Velicheva; V. P. Volnykh

2014-03-28T23:59:59.000Z

295

Inert electrode containing metal oxides, copper and noble metal  

DOE Patents (OSTI)

A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

2001-01-01T23:59:59.000Z

296

Inert electrode containing metal oxides, copper and noble metal  

DOE Patents (OSTI)

A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

2000-01-01T23:59:59.000Z

297

Integrated decontamination process for metals  

DOE Patents (OSTI)

An integrated process for decontamination of metals, particularly metals that are used in the nuclear energy industry contaminated with radioactive material. The process combines the processes of electrorefining and melt refining to purify metals that can be decontaminated using either electrorefining or melt refining processes.

Snyder, Thomas S. (Oakmont, PA); Whitlow, Graham A. (Murrysville, PA)

1991-01-01T23:59:59.000Z

298

Metal-binding polymesr as chelating agents  

E-Print Network (OSTI)

Abstract Metal chelating polymers are functional polymers that bear specified chemical groups capable of selectively binding metals. Heavy metal contamination is considered a serious problem because these metals, even at ...

Mohammadi, Zahra

2011-04-11T23:59:59.000Z

299

Observation of Metal-insulator and Metal-Metal Transitions in Hydrogen Iodide under Pressure  

Science Journals Connector (OSTI)

Hydrogen iodide has been studied up to pressures of 70 GPa at low temperatures in a diamondanvil cell. Electrical-conductivity and optical measurements have been used to observe pressure-induced phase transitions which are interpreted as follows: First a metal-insulator transition takes place in the molecular solid; with increased pressure a metal-metal molecular-to-atomic transition occurs. An additional transition due to intrinsic impurities has been observed. Implications for metallic hydrogen are discussed.

J. van Straaten and Isaac F. Silvera

1986-08-11T23:59:59.000Z

300

FLUIDIC: Metal Air Recharged  

SciTech Connect

Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

Friesen, Cody

2014-03-07T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

FLUIDIC: Metal Air Recharged  

ScienceCinema (OSTI)

Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

Friesen, Cody

2014-04-02T23:59:59.000Z

302

Apoferritin Templated Synthesis of Metal Phosphate Nanoparticle...  

NLE Websites -- All DOE Office Websites (Extended Search)

Apoferritin Templated Synthesis of Metal Phosphate Nanoparticle Labels for Electrochemical Immunoassay. Apoferritin Templated Synthesis of Metal Phosphate Nanoparticle Labels for...

303

THE COORDINATION CHEMISTRY OF METAL SURFACES  

E-Print Network (OSTI)

result 7 ' 30 u 31 in metal carbide cluster chemistry willin metal chemistry. Oxidation of the iron carbide cluster

Muetterties, Earl L.

2013-01-01T23:59:59.000Z

304

Hydrothermal alkali metal recovery process  

DOE Patents (OSTI)

In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

Wolfs, Denise Y. (Houston, TX); Clavenna, Le Roy R. (Baytown, TX); Eakman, James M. (Houston, TX); Kalina, Theodore (Morris Plains, NJ)

1980-01-01T23:59:59.000Z

305

Coated metal fiber coalescing cell  

SciTech Connect

A cell is described for coalescing oil droplets dispersed in a water emulsion including an elongated perforated tube core into which the emulsion is injected, layers of oleophilic plastic covered metal mat wound about the core through which the emulsion is forced to pass, the fibers of the metal mat being covered by oleophilic plastic such as vinyl, acrylic, polypropylene, polyethylene, polyvinyl chloride, the metal being in the form of layers of expanded metal or metal fibers, either aluminum or stainless steel. In manufacturing the cell a helix wound wire is formed around the cylindrical plastic coated metal to retain it in place and resist pressure drop of fluid flowing through the metal fibers. In addition, the preferred arrangement includes the use of an outer sleeve formed of a mat of fibrous material such as polyester fibers, acrylic fibers, modacrylic fibers and mixtures thereof.

Rutz, W.D.; Swain, R.J.

1980-12-23T23:59:59.000Z

306

Water supply and sludge metals  

SciTech Connect

Ultimate sludge disposal is one of the major tasks facing wastewater treatment facilities today. Where adequate farmland exists in proximity to the treatment facility and where sludge characteristics are suitable, land application is often the most economical method. In some cases, however, metal concentrations in the sludge either limit the site life or the application rate to the point where land application is not economical. When metals are above regulatory limits, land application may become impossible. The origin of the metals has largely been credited to industrial users and stormwater runoff and have, in fact, often represented significant sources of metals. Another potentially significant source of metals that has been frequently overlooked is the water supply system (including the distribution and home piping systems). Data from some treatment facilities suggest that the water supply system is the major source of metals and is the reason that sewage sludge metal levels are above allowable land application limits.

Brown, W.E. (Wright-Pierce Engineers, Topsham, ME (USA))

1988-04-01T23:59:59.000Z

307

Rare-Earth Surface Alloying: A New Phase for GdAu2 M. J. Verstraete,1,2  

E-Print Network (OSTI)

refrigeration, are made pos- sible by an unusual group of elements: the rare earths (REs). The rare earthsRare-Earth Surface Alloying: A New Phase for GdAu2 M. Corso,1 M. J. Verstraete,1,2 F. Schiller,1 M. Gadolinium is a borderline rare earth, which is naturally ferromagnetic but can easily switch to different

308

Corrosion protective coating for metallic materials  

DOE Patents (OSTI)

Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds.

Buchheit, Rudolph G. (Albuquerque, NM); Martinez, Michael A. (Albuquerque, NM)

1998-01-01T23:59:59.000Z

309

Corrosion protective coating for metallic materials  

DOE Patents (OSTI)

Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides is disclosed. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds. 1 fig.

Buchheit, R.G.; Martinez, M.A.

1998-05-26T23:59:59.000Z

310

Rare earth focused ion beam implantation utilizing Er and Pr liquid alloy ion sources  

E-Print Network (OSTI)

Pr,10,11 Eu,12 Dy,13 Er,13­15 and Tm16 doped GaN. Rare earth elements were added during growthRare earth focused ion beam implantation utilizing Er and Pr liquid alloy ion sources L. C. Chao, B write implantation. © 1999 American Vacuum Society. S0734-211X 99 08306-7 I. INTRODUCTION Rare earth

Steckl, Andrew J.

311

The 5th Annual Colorado Rare Plant Symposium: G2 Plants of Colorado  

E-Print Network (OSTI)

1 The 5th Annual Colorado Rare Plant Symposium: G2 Plants of Colorado September 5, 2008 8 am - 4 pm they shouldn't collect because th

312

ORISE: Helping to Provide Rare Access to World-Class Computing...  

NLE Websites -- All DOE Office Websites (Extended Search)

Supercomputing ORISE peer review services helping to advance, provide rare access to world-class computing resources The Oak Ridge Institute for Science Education (ORISE)...

313

Alternative High-Performance Motors with Non-Rare Earth Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Alternative High-Performance Motors with Non-Rare Earth Materials 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

314

Fabrication and evaluation of rare-earth-bearing fuel slugs for sodium-cooled fast reactors  

Science Journals Connector (OSTI)

Separation of rare-earth (RE) elements from minor actinides is difficult in pyroprocessing, especially for light REs (e.g....

Jong Hwan Kim; Hoon Song; Ki Hwan Kim…

2014-10-01T23:59:59.000Z

315

Laser Spectroscopy of Short Lived Rare Earth Isotopes  

Science Journals Connector (OSTI)

The ISAC facility at TRIUMF is able to produce intense beams of mass?separated radioactive isotopes of the alkali and the rare earth elements with unprecedented intensities. This will allow our laser spectroscopy collaboration to extend the studies of exotic nuclei for these elements further away from the valley of stability into regions so far inaccessible at other facilities thus allowing a more stringent test of the descriptive and predictive power of global nuclear models. Our effort which involves groups and researchers from the U.S. (TAMU) Japan (JAERI) and Canada (TRIUMF McGill and Calgary Universities) is based on collinear laser spectroscopy in a fast beam. In this method atoms or ions are excited by laser light in collinear geometry. In this way measurements of the optical isotope shift yield the nuclear charge radii and measurements of the hyperfine structure the nuclear moments. The excitation can be done by cw?lasers or alternatively by pulsed lasers without a loss in sensitivity if bunched radioactive ion beams are available. In its basic version the resonances of the spectral lines are observed optically at right angles. However the sensitivity will be increased through modifications using particle or nuclear radiation detection. The progress and the plans of our collaboration will be described.

H. A. Schuessler; F. Buchinger; H. Iimura

2003-01-01T23:59:59.000Z

316

Evidence for the Rare Decay B+ to Ds+ pi0  

SciTech Connect

The authors have searched for the rare decay B{sup +} {yields} D{sub s}{sup +}{pi}{sup 0}. The analysis is based on a sample of 232 million {Upsilon}(4S) {yields} B{bar B} decays collected with the BABAR detector at the PEP-II e{sup +}e{sup -} storage ring. They find 19.6 signal events, corresponding to a significance of 4.7 {sigma}. The extracted signal yield including statistical and systematic uncertainties is 20.1{sub -6.0-1.5}{sup +6.8+0.4}, and they measure {Beta}(B{sup +} {yields} D{sub s}{sup +}{pi}{sup 0}) = (1.5{sub -0.4}{sup +0.5} {+-} 0.1 {+-} 0.2) x 10{sup -5}, where the first uncertainty is statistical, the second is systematic, and the last is due to the uncertainty on the D{sub s}{sup +} decay and its daughter decay branching fractions.

Aubert, B.

2006-11-17T23:59:59.000Z

317

ITP Metal Casting: Implementation of Metal Casting Best Practices  

Energy.gov (U.S. Department of Energy (DOE))

The project examined cases where metal casters had implemented ITP research results and detailed the benefits they received due to that implementation.

318

International Recycling of LLW Metals  

SciTech Connect

Melting of radioactive scrap metal has been successfully practiced for more than 15 years, with approximately 60,000 tons of steel being processed into beneficial reuse applications. This process has converted radioactive scrap metal at a licensed facility into useful products such as shield blocks, security barriers and shield containers. These products are used within the nuclear industry, such as nuclear power plants, waste disposal facilities and high-energy physics research facilities. Recycling provides the following benefits by comparison with direct disposal: - Preserving metal resources. - Conserving valuable Low Level Waste (LLW) disposal site resources, thereby extending disposal site life. - Reducing the cost of metal products to end users by using materials less expensive than virgin metals. This paper outlines international metal recycling practices implemented at EnergySolutions' Bear Creek Facility in Oak Ridge, Tennessee. (authors)

Eshleman, T.; Jansen, J. [EnergySolutions (United States); Shinya, Sawada [KEK - High Energy Accelerator Research Organization (Japan)

2008-07-01T23:59:59.000Z

319

Metal to ceramic sealed joint  

DOE Patents (OSTI)

A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system.

Lasecki, John V. (Livonia, MI); Novak, Robert F. (Farmington Hills, MI); McBride, James R. (Ypsilanti, MI)

1991-01-01T23:59:59.000Z

320

Metal to ceramic sealed joint  

DOE Patents (OSTI)

A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system. 11 figures.

Lasecki, J.V.; Novak, R.F.; McBride, J.R.

1991-08-27T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

EIS-0096: Final Environmental Impact Statement | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

096: Final Environmental Impact Statement 096: Final Environmental Impact Statement EIS-0096: Final Environmental Impact Statement Remedial Actions at the Former Vitro Rare Metals Plant Site, Canonsburg, Washington County, Pennsylvania This Canonsburg FEIS evaluates the environmental impacts associated with remedial actions in connection with residual radioactive materials remaining at the inactive uranium processing site located in Canonsburg, Washington county, Pennsylvania. The Canonsburg site is an 18.5-acre property that was formerly owned by the Vitro Rare Metals Company. The expanded Canonsburg site would be an approximately 30-acre property that would include the Canonsburg site (the former Vitro Rare Metals plant), seven adjacent private houses, and the former Georges Pottery property,

322

ITP Metal Casting: A Vision for the U.S. Metal Casting Industry...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

mcvision.pdf More Documents & Publications ITP Metal Casting: Metalcasting Industry Technology Roadmap ITP Metal Casting: Implementation of Metal Casting Best Practices ITP...

323

Metal-ceramic joint assembly  

DOE Patents (OSTI)

A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

Li, Jian (New Milford, CT)

2002-01-01T23:59:59.000Z

324

Method for preparing porous metal hydride compacts  

DOE Patents (OSTI)

A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

1980-01-21T23:59:59.000Z

325

The impact of vegetation on fractionation of rare earth elements (REE) during waterrock interaction  

E-Print Network (OSTI)

The impact of vegetation on fractionation of rare earth elements (REE) during water The fractionation of the rare earth elements (REE) in river water, as well as the immobilization of REE in the river earth elements (REE) principally originate from apatite dissolution during weathering. However, stream

Mailhes, Corinne

326

Clean Metal Casting  

SciTech Connect

The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

Makhlouf M. Makhlouf; Diran Apelian

2002-02-05T23:59:59.000Z

327

``Towards Strange Metallic Holography'  

SciTech Connect

We initiate a holographic model building approach to 'strange metallic' phenomenology. Our model couples a neutral Lifshitz-invariant quantum critical theory, dual to a bulk gravitational background, to a finite density of gapped probe charge carriers, dually described by D-branes. In the physical regime of temperature much lower than the charge density and gap, we exhibit anomalous scalings of the temperature and frequency dependent conductivity. Choosing the dynamical critical exponent z appropriately we can match the non-Fermi liquid scalings, such as linear resistivity, observed in strange metal regimes. As part of our investigation we outline three distinct string theory realizations of Lifshitz geometries: from F theory, from polarized branes, and from a gravitating charged Fermi gas. We also identify general features of renormalization group flow in Lifshitz theories, such as the appearance of relevant charge-charge interactions when z {ge} 2. We outline a program to extend this model building approach to other anomalous observables of interest such as the Hall conductivity.

Hartnoll, Sean A.; /Harvard U., Phys. Dept. /Santa Barbara, KITP /UC, Santa Barbara; Polchinski, Joseph; Silverstein, Eva; /Santa Barbara, KITP /UC, Santa Barbara; Tong, David; /Cambridge U., DAMTP /Santa Barbara, KITP /UC, Santa Barbara

2010-08-26T23:59:59.000Z

328

Comparison of the Bioavailability of Waste Laden Soils Using ''In Vivo'' ''In Vitro'' Analytical Methodology and Bioaccessibility of Radionuclides for Refinement of Exposure/Dose Estimates  

SciTech Connect

The bioavailability of soil contaminants can be measured using in vitro or in vivo techniques. Since there was no standard method for intercomparison among laboratories, we compared two techniques for bioavailability estimation: in vitro dissolution and in vivo rat feeding model for a NIST-traceable soil material. Bioaccessibility was measured using a sequential soil extraction in synthetic analogues of human saliva, gastric and intestinal fluids. Bioavailability was measured in Sprague Dawley rats by determining metal levels in the major organs and urine, feces, and blood. Bioaccessibility was found to be a good indicator of relative metal bioavailability. Results are presented from bioaccessible experiments with Cesium in contaminated DOE soils, and total alpha and beta bioaccessibility. The results indicate that the modified methodology for bioaccessibility can be used for specific radionuclide analysis.

P. J. Lioy; M. Gallo; P. Georgopoulos; R. Tate; B. Buckley

1999-09-15T23:59:59.000Z

329

Metal deposition using seed layers  

DOE Patents (OSTI)

Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

2013-11-12T23:59:59.000Z

330

A Forward Look into Rare Earth Supply and Demand: A Role for Sedimentary Phosphate Deposits?  

Science Journals Connector (OSTI)

Abstract Rare earth elements, key to many high-technology applications, are regularly making headlines, even in general public newspapers. Will the word run short of rare earth elements and of the many applications that rest on their use? In support to French and European Union policy making, as well as in support to industrial clients, BRGM is monitoring rare earth markets from the supply and the demand sides, as well as for technological shifts that drive them. Not every rare earth element is effectively rare and there are well over 400 ongoing rare earth exploration projects worldwide. Nevertheless, some rare earth elements such as dysprosium, europium and terbium are rare, in high and fast growing demand; as they either are indispensable to the production of Fe-B-Nd (Dy) permanent magnets, the highest performance magnetic material currently being available at industrial scale, or to the production of phosphors essential to the production of fluorescent compact, energy saving, light bulbs and video displays. At the current 10% compound annual growth rate of the demand for these elements, the question arises of their the future availability. Among the many rare-earth bearing minerals apatite is of particular interest as a potential source of rare earth elements, as it is a widespread mineral, forming huge deposits such as the sedimentary and magmatic phosphate deposits. An overview of the potential of sedimentary phosphate deposits as an important source for future rare earth production is presented and discussed. In addition to knowledge about the distribution and concentration of individual rare earth elements in sedimentary phosphate deposits, it is also necessary to understand the partitioning of the individual elements between phosphogypsum and phosphoric acid in the fertilizer production process, as well as available technologies to recover and separate individual rare earth elements from these materials. This could pave the way to the generation of extra added-value for phosphate producers, and to the broadening of the international production base of rare earth elements in high demand by the global economy.

Patrice Christmann

2014-01-01T23:59:59.000Z

331

Effects of metals on {alpha}-amylase activity in the digestive gland of the green mussel, Perna viridis L.  

SciTech Connect

A number of digestive enzymes in the green mussel, Perna viridis L., have been reported, and {alpha}-amylase is believed to have a higher activity than the others. Small plankton, on which the green mussel feeds, may supply plenty of starch and glycogen. They may be an important source of nutrients for the green mussel and the ability of the latter to make good use of them depends mainly on the activities of amylase. The effect of heavy metals on amylase activity is also important as the ability of the mussel`s digestive gland to accumulate these metals is well known. High concentrations of heavy metals, especially lead, have been observed in the water around Singapore. The in vitro inhibition of some metals on the activities of digestive enzymes from the green mussel has been observed, but kinetic properties of the inhibition and the in vivo inhibition of the heavy metals on digestive enzymes are little understood. In the present study, in vitro inhibition of four metals (Pb, Cd, Zn and Hg) on the activity of {alpha}-amylase from the digestive gland of the green mussel will be compared. Their effects on the K{sub M} and V{sub max} values of {alpha}-amylase will also be compared. Finally, lead is either added to the food or water, to see how it affects the activity of {alpha}-amylase and how this effect acts in combination with starvation. 12 refs., 3 figs., 3 tabs.

Yan, T.; Teo, L.H.; Sin, Y.M. [National Univ. of Singapore (Singapore)] [National Univ. of Singapore (Singapore)

1996-04-01T23:59:59.000Z

332

Scoping Inventory Calculations for the Rare Isotope Accelerator  

SciTech Connect

This document is a report on our activities in FY03 exploring nuclear safety and hazard analysis issues relevant to the Rare Isotope Accelerator (RIA). It is not clear whether DOE will classify the RIA as an accelerator facility subject to the accelerator-specific safety requirements of DOE Order 420.2A or as a nonreactor nuclear facility subject to the requirements of 10 CFR 830. The final outcome of this issue will have significant impact on the construction and operation of the facility and the quality assurance requirements for items or services that may affect nuclear safety. The resolution of this issue will be an important earlier decision for the RIA project team and will require early consultation with the appropriate DOE authorities. For nuclear facilities, facility hazard classification depends on the inventory of releasable radionuclides; therefore, some simplistic, scoping inventory calculations for some assumed targets and beams are done to estimate the hazard category of RIA if it is declared a nuclear facility. These calculations show that for the scenarios analyzed, RIA would produce sufficient quantities of radionuclides to be classified as a Category 3 nuclear facility. Over the lifetime of RIA operations, it may be possible to build up Category 2 quantities of {sup 227}Ac and {sup 228}Th. A storage building, separate from the driver, target, and experimental buildings, used to store and isolate accumulated targets and other hardware, can mitigate the potential impact on RIA. The more onerous requirements of Category 2 facilities would only be imposed on the storage facility and not on the rest of the RIA facilities. Some of the differences in a category 2 and category 3 facility are discussed in Appendix 1.

Ahle, L E; Boles, J L

2003-07-25T23:59:59.000Z

333

Nonequilibrium electron tunneling in metal-insulator-metal junctions  

Science Journals Connector (OSTI)

The small structure in the conductance curve near zero bias of metal-insulator-metal tunnel junctions has been studied extensively. These experiments are analyzed in detail in a nonequilibrium model. It is shown that this type of zero-bias anomaly can be accounted for entirely by an electron bottleneck arising from the blocking of tunneling states due to nonzero electron relaxation times.

J. G. Adler; H. J. Kreuzer; J. Straus

1975-04-15T23:59:59.000Z

334

Theory of bonding of transition metals to nontransition metals  

Science Journals Connector (OSTI)

We present a theory of the chemical bond in compounds consisting of both transition metals and nontransition metals. Chemical trends in the bonding properties are established by directly comparing the total energies of a large number of such compounds with the total energies of their constituents. These chemical trends are analyzed in terms of the s-, p-, and d-like state densities of the compounds and the constituents. Rather different types of bonding are shown to result when the atomic s and p levels of the nontransition metal lie above, below, and near the energy of the transition-metal d level. The heat of compound formation is shown to result from a competition between two simple physical effects: (1) the weakening of the transition-metal bonds by the lattice dilatation required for the accommodation of the nontransition metal, and (2) the increased bonding which results from the occupation of the bonding members of the hybrid states formed from the interaction between the transition-metal d states and the s-p states on the nontransition metal. Our theoretical values for the heats of formation of these compounds are generally similar to those given by Miedema's empirical formula. Distinctive aspects of the variation of the heat of formation with the number of valence electrons reveal, however, that the microscopic picture on which the empirical formula is based is quite different from that given by our self-consistent energy-band theory.

C. D. Gelatt; Jr.; A. R. Williams; V. L. Moruzzi

1983-02-15T23:59:59.000Z

335

Catalytic production of metal carbonyls from metal oxides  

DOE Patents (OSTI)

This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

1984-01-06T23:59:59.000Z

336

Creating bulk nanocrystalline metal.  

SciTech Connect

Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties across the feature.

Fredenburg, D. Anthony (Georgia Institute of Technology, Atlanta, GA); Saldana, Christopher J. (Purdue University, West Lafayette, IN); Gill, David D.; Hall, Aaron Christopher; Roemer, Timothy John (Ktech Corporation, Albuquerque, NM); Vogler, Tracy John; Yang, Pin

2008-10-01T23:59:59.000Z

337

Metal recovery from porous materials  

DOE Patents (OSTI)

The present invention relates to recovery of metals. More specifically, the present invention relates to the recovery of plutonium and other metals from porous materials using microwaves. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

Sturcken, E.F.

1991-01-01T23:59:59.000Z

338

PHYSICAL PROPERTIES OF METALS1  

Science Journals Connector (OSTI)

... the application of pressing and shaping force is afforded by the processes in use for "teapot spinning,"i.e. the production of a Britannia-metal ... spinning,"i.e. the production of a Britannia-metal teapot by a process technically termed spinning. The alloy being rolled into sheets of convenient ...

1878-05-16T23:59:59.000Z

339

Formation of zirconium metallic glass  

Science Journals Connector (OSTI)

... Bulk metallic glasses are commonly produced by the rapid cooling of liquid alloys. They have emerged over ... a novel class of materials, with attractive properties and technological promise. The bulk metallic glasses so far produced contain three or more component elements. These complex compositions are necessary ...

Jianzhong Zhang; Yusheng Zhao

2004-07-15T23:59:59.000Z

340

In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Gasoline and Diesel Engine Vehicle Exhaust Particulate and Semi-Volatile Organic Compound Materials In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust Particulate...

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Metal binding in an aluminum based metal-organic framework for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal binding in an aluminum based metal-organic framework for carbon dioxide capture Link to article...

342

Durability of metals from archaeological objects, metal meteorites, and native metals  

SciTech Connect

Metal durability is an important consideration in the multi-barrier nuclear waste storage concept. This study summarizes the ancient metals, the environments, and factors which appear to have contributed to metal longevity. Archaeological and radiochemical dating suggest that human use of metals began in the period 6000 to 7000 BC. Gold is clearly the most durable, but many objects fashioned from silver, copper, bronze, iron, lead, and tin have survived for several thousand years. Dry environments, such as tombs, appear to be optimum for metal preservation, but some metals have survived in shipwrecks for over a thousand years. The metal meteorites are Fe-base alloys with 5 to 60 wt% Ni and minor amounts of Co, I, and S. Some meteoritic masses with ages estimated to be 5,000 to 20,000 years have weathered very little, while other masses from the same meteorites are in advanced stages of weathering. Native metals are natural metallic ores. Approximately five million tonnes were mined from native copper deposits in Michigan. Copper masses from the Michigan deposits were transported by the Pleistocene glaciers. Areas on the copper surfaces which appear to represent glacial abrasion show minimal corrosion. Dry cooling tower technology has demonstrated that in pollution-free moist environments, metals fare better at temperatures above than below the dewpoint. Thus, in moderate temperature regimes, elevated temperatures may be useful rather than detrimental for exposures of metal to air. In liquid environments, relatively complex radiolysis reactions can occur, particularly where multiple species are present. A dry environment largely obviates radiolysis effects.

Johnson, A.B. Jr.; Francis, B.

1980-01-01T23:59:59.000Z

343

Method for preparing metal powder, device for preparing metal powder, method for processing spent nuclear fuel  

DOE Patents (OSTI)

A method for producing metal powder is provided the comprising supplying a molten bath containing a reducing agent, contacting a metal oxide with the molten bath for a time and at a temperature sufficient to reduce the metal in the metal oxide to elemental metal and produce free oxygen; and isolating the elemental metal from the molten bath.

Park, Jong-Hee (Clarendon Hills, IL)

2011-11-29T23:59:59.000Z

344

Microbial controls on metal ion mobility  

E-Print Network (OSTI)

In this dissertation, the biogeochemical controls on metal mobility in the subsurface are examined; specifically, the release of metals from buried mineralization, the transport of metals through overburden, and the ...

Leslie, Karla Louise

2012-12-31T23:59:59.000Z

345

Metal-directed protein self-assembly  

E-Print Network (OSTI)

Metal-Directed Protein Self- Assembly. Acc. Chem. Res. 43,Metal-directed protein self-assembly. Acc. Chem. Res. 43,Metal- mediated self-assembly of protein superstructures:

Salgado. Eric N.

2010-01-01T23:59:59.000Z

346

Bad Metals Made with Good-Metal Components  

Science Journals Connector (OSTI)

We have grown thin stable films of a good metal, Ag, that have characteristics of bad metals: high resistivity, strong temperature dependence of resistivity, and lack of resistive saturation. For films of different thickness, the temperature-dependent resistance and the Hall effect resistance provide evidence that the apparent bad metallicity is a consequence of the microstructure of the film rather than the result of new physics. This microstructure, which we characterize with scanning probe techniques, occurs on length scales comparable to the mean free path, thereby changing the sign of the classical magnetoresistance from positive to negative.

S. B. Arnason; S. P. Herschfield; A. F. Hebard

1998-11-02T23:59:59.000Z

347

Global In-Use Stocks of the Rare Earth Elements: A First Estimate  

Science Journals Connector (OSTI)

Since 1990, China has played a dominant role in REE mining production; other countries are almost completely dependent on imports from China with respect to rare earth resources. ... The stages within the system are linked to each other by flows, the system within a particular cycle is associated with other regions by imports and exports at each stage, and all of the rare earth elements are linked through a common processing stage. ... China has traditionally employed rare earths in applications such as metallurgical additives and alloys, petroleum refining, and glass and ceramics, but new applications in China have grown significantly since 2002. ...

Xiaoyue Du; T. E. Graedel

2011-03-25T23:59:59.000Z

348

Metal-based reactive nanomaterials  

Science Journals Connector (OSTI)

Recent developments in materials processing and characterization resulted in the discovery of a new type of reactive materials containing nanoscaled metal components. The well-known high oxidation energies of metallic fuels can now be released very rapidly because of the very high reactive interface areas in such metal-based reactive nanomaterials. Consequently, these materials are currently being examined for an entire range of applications in energetic formulations inappropriate for conventional, micron-sized metal fuels having relatively low reaction rates. New application areas, such as reactive structural materials, are also being explored. Research remains active in manufacturing and characterization of metal-based reactive nanomaterials including elemental metal nanopowders and various nanocomposite material systems. Because of the nanometer scale of the individual particles, or phase domains, and because of the very high enthalpy of reaction between components of the nanocomposite materials, the final phase compositions, morphology, and thermodynamic properties of the reactive nanocomposite materials may be different from those of their micron-scaled counterparts. Ignition mechanisms in such materials can be governed by heterogeneous reactions that are insignificant for materials with less developed reactive interface areas. New combustion regimes are being observed that are affected by very short ignition delays combined with very high metal combustion temperatures. Current progress in this rapidly growing research area is reviewed and some potential directions for the future research are discussed.

Edward L. Dreizin

2009-01-01T23:59:59.000Z

349

Metal-doped organic foam  

DOE Patents (OSTI)

Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

Rinde, James A. (Livermore, CA)

1982-01-01T23:59:59.000Z

350

Metal Hydride Hydrogen Storage R and D  

Energy.gov (U.S. Department of Energy (DOE))

DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

351

Metal-Organic Heat Carrier Nanofluids. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Organic Heat Carrier Nanofluids. Metal-Organic Heat Carrier Nanofluids. Abstract: Nanofluids, dispersions of metal or oxide nanoparticles in a base working fluid, are being...

352

Accelerated Cellulose Depolymerization Catalyzed by Paired Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Depolymerization Catalyzed by Paired Metal Chlorides in Ionic Liquid Solvent. Accelerated Cellulose Depolymerization Catalyzed by Paired Metal Chlorides in Ionic Liquid...

353

Metal Hydride Hydrogen Storage Research and Development  

Energy.gov (U.S. Department of Energy (DOE))

DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

354

Metal Roofing Alliance (MRA) | Open Energy Information  

Open Energy Info (EERE)

Metal Roofing Alliance (MRA) Jump to: navigation, search Name: Metal Roofing Alliance (MRA) Place: Belfair, WA Information About Partnership with NREL Partnership with NREL Yes...

355

Red-Green Emitting and Superparamagnetic Nanomarkers Containing Fe3O4 Functionalized with Calixarene and Rare Earth Complexes  

Science Journals Connector (OSTI)

Red-Green Emitting and Superparamagnetic Nanomarkers Containing Fe3O4 Functionalized with Calixarene and Rare Earth Complexes ... ? Nuclear

Latif U. Khan; Hermi F. Brito; Jorma Hölsä; Kleber R. Pirota; Diego Muraca; Maria C.F.C. Felinto; Ercules E.S. Teotonio; Oscar L. Malta

2014-12-05T23:59:59.000Z

356

METAL NANOPARTICLES FUNCTIONALIZED WITH METAL-LIGAND COVALENT BONDS  

E-Print Network (OSTI)

fundamental and technological perspectives, largely because these nanomaterials show unique optical and electronicelectronic energy structures, which may serve as a fundamentaland electronic characteristics, the metal nanoparticles have been attracting extensive interest in the field of fundamental

Kang, Xiongwu

2012-01-01T23:59:59.000Z

357

Nonmetal-metal transition in metal–molten-salt solutions  

Science Journals Connector (OSTI)

The method of ab initio molecular dynamics, based on finite-temperature density-functional theory, is used to study the nonmetal-metal transition in two different metal–molten-salt solutions, Kx(KCl)1-x and Nax(NaBr)1-x. As the excess metal concentration is increased the electronic density becomes delocalized and percolating conducting paths are formed, making a significant dc electrical conductivity possible. This marks the onset of the metallic regime. By calculating several electronic and structural properties, remarkable differences between the two solutions are observed. The anomalous behavior of Nax(NaBr)1-x, typical of all the Na-NaX solutions, is found to be related to the strong attractive interaction between the sodium ions and the excess electrons. © 1996 The American Physical Society.

Pier Luigi Silvestrelli; Ali Alavi; Michele Parrinello; Daan Frenkel

1996-05-15T23:59:59.000Z

358

Magnetism in Transition Metals  

Science Journals Connector (OSTI)

An attempt is made to distinguish "band-type magnetization" from "alignment-type magnetization" on the basis of whether the local moments associated with the Wannier functions on the atom sites are "induced" or "permanent." In general, the local moment is partially induced and partially permanent, and a criterion is suggested: A local moment is defined to be of the permanent variety if in the presence of magnetic forces (supposed characteristic of the crystal in a given circumstance) tending to produce a moment in one sense (z^, say) of a direction, it can maintain itself (perhaps altered in magnitude, however) in the opposite sense (-z^), as well as in z^. The internal mechanisms tending to produce permanent moments are simplified to just the Hcorr of Anderson, and the external inducing mechanism are the Heisenberg interaction and a magnetic field, Hspin, say. If Hcorr dominates Hspin, then it is shown that a local moment can maintain itself to the polarizing tendencies (whence an alignment type of magnetization calculation is appropriate), but if Hspin dominates Hcorr, then the local moment has only one sense possible in this environment (and a band type of calculation is appropriate). It is suggested that this distinction is relevant to transition metals.

M. Bailyn

1965-09-13T23:59:59.000Z

359

In vitro fracture toughness of human dentin V. Imbeni,1  

E-Print Network (OSTI)

In vitro fracture toughness of human dentin V. Imbeni,1 R. K. Nalla,1 C. Bosi,1 J. H. Kinney,2 R. O August 2002 Abstract: The in vitro fracture toughness of human dentin has been reported measured crit- ical stress intensity, Kc, for the onset of unstable fracture along an orientation

Ritchie, Robert

360

Electromagnetic modes in metal-insulator-metal structures  

Science Journals Connector (OSTI)

Metal-dielectric-metal structures are constructed by depositing Ag films on CaF2 thin films that coat Ag surfaces. The reflectance of such structures was measured for several angles of incidence in the 1–5-eV spectral range. The minima observed in the reflectance are due to the excitation of electromagnetic modes inside an optical cavity. These observed electromagnetic modes are discussed and compared to computed dispersion.

F. Villa; T. Lopez-Rios; L. E. Regalado

2001-04-02T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Contacts Between Metals and Between a Metal and a Semiconductor  

Science Journals Connector (OSTI)

The problem of contacts between metals and between a metal and a semiconductor is treated classically with the help of the results of wave mechanical theory of electron energy states in solids. The potential and electron density distributions in the two bodies near the contact are discussed. The bodies are assumed to be in immediate contact. The problem of a body in vacuum and the problem of two bodies separated by a gap are discussed qualitatively.

H. Y. Fan

1942-10-01T23:59:59.000Z

362

7th Annual Colorado Rare Plant Symposium Conservation Efforts and Status Review of G1 Plants of Colorado  

E-Print Network (OSTI)

7th Annual Colorado Rare Plant Symposium Conservation Efforts and Status Review of G1 Plants of Colorado September 10, 2010; 9:00 am-4:00 pm UC Denver Auraria Campus Denver, Colorado Join members of the Colorado Rare Plant Technical Committee (RPTC) for the 7th Annual Colorado Rare Plant Symposium. The RPTC

363

Portable X-ray fluorescence in the assessment of rare earth element-enriched sedimentary phosphate deposits  

Science Journals Connector (OSTI)

...fluorescence in the assessment of rare earth element-enriched sedimentary...considered as potential sources of rare earth elements (REEs) and...phosphate deposit|pulps|rare earth elements|recalibration...into effluents associated with phosphogypsum stockpiles and could pose a...

G.J. Simandl; R. Fajber; S. Paradis

364

Effect of microstructure, grain size, and rare earth doping on the electrorheological performance of nanosized particle materials  

E-Print Network (OSTI)

and grain sizes were prepared by doping TiO2 or ZrO2 with rare earth (RE) elements, and by changingEffect of microstructure, grain size, and rare earth doping on the electrorheological performance-Hua Zhang,c Shu-Mei Chen,d Rui-Li Huange and Song Gaoa a State Key Laboratory of Rare Earth Materials

Gao, Song

365

PII S0016-7037(02)00888-8 EXAFS study of rare-earth element coordination in calcite  

E-Print Network (OSTI)

PII S0016-7037(02)00888-8 EXAFS study of rare-earth element coordination in calcite E. J. ELZINGA,1-structure (EXAFS) spectroscopy is used to characterize the local coordination of selected rare-earth elements (Nd3 for the increased coordination for the larger rare-earth elements involves bidentate ligation from a CO3 group

Peale, Robert E.

366

Microsoft Word - ARPA-E_RareEarth_Workshop_Overview_v6  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ARPA-E WORKSHOP ARPA-E WORKSHOP Rare Earth and Critical Materials December 6, 2010 in Arlington, VA Background ...................................................................................................................................................................................... 2 Breakout Sessions and Participant Preparation .............................................................................................................. 8 Agenda ................................................................................................................................................................................................ 9 Contact Information ................................................................................................................................................................... 10

367

Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Materials for a Clean Energy Future Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Materials for a Clean Energy Future December 3, 2010 Session A: Setting the Scene - Critical Materials for a Clean Energy Future Diana Bauer, Office of Policy and International Affairs, U.S. Department of Energy, Highlights of the DOE Critical Materials Strategy Antje Wittenberg, Directorate General for Enterprise and Industry, The EU Raw Materials Initiative and the Report of the Ad-hoc Group (tbc) Tom Lograsso, Ames Laboratory (Iowa State University), Future Directions in Rare Earth Research: Critical Materials for 21st Century Industry Derk Bol, Materials Innovation Institute M2i (Netherlands) M2i, Material

368

Development of the Polish wasteless technology of apatite phosphogypsum utilization with recovery of rare earths  

Science Journals Connector (OSTI)

The most promising source of rare earth elements in Poland is apatite phosphogypsum, a waste product obtained in the process of phosphoric acid production from Kola apatite. Depending on the technology used, as the hydration ratio of calcium sulphate is changed from hemihydrate to dihydrate, the content of rare earths varies from 0.6% to 0.3% Ln2O3 respectively. Technological flow charts for recovering the rare earths as a byproduct have been developed. The basic process used in the technology consists of three steps: apatite phosphogypsum leaching with dilute sulphuric acid solution; separation of rare earth concentrates from leaching sulphuric acid by preconcentration via evaporization, liquid-liquid extraction or precipitation method; anhydrite production from purified phosphogypsum by recrystallization in concentrated sulphuric acid solution.

A. Jarosi?ski; J. Kowalczyk; Cz. Mazanek

1993-01-01T23:59:59.000Z

369

Extremal Dependence Indices: Improved Verification Measures for Deterministic Forecasts of Rare Binary Events  

Science Journals Connector (OSTI)

Verifying forecasts of rare events is challenging, in part because traditional performance measures degenerate to trivial values as events become rarer. The extreme dependency score was proposed recently as a nondegenerating measure for the ...

Christopher A. T. Ferro; David B. Stephenson

2011-10-01T23:59:59.000Z

370

Origin of enhanced magnetization in rare earth doped multiferroic bismuth ferrite  

SciTech Connect

We report structural and magnetic properties of rare earth doped Bi{sub 0.95}R{sub 0.05} FeO{sub 3} (R?=?Y, Ho, and Er) submicron particles. Rare earth doping enhances the magnetization and the magnetization shows an increasing trend with decreasing dopant ionic radii. In contrast to the x-ray diffraction pattern, we have seen a strong evidence for the presence of rare earth iron garnets R{sub 3}Fe{sub 5}O{sub 12} in magnetization measured as a function of temperature, in selected area electron diffraction, and in Raman measurements. Our results emphasised the role of secondary phases in the magnetic property of rare earth doped BiFeO{sub 3} compounds along with the structural distortion favoring spin canting by increase in Dzyaloshinskii-Moriya exchange energy.

Nayek, C.; Thirmal, Ch.; Murugavel, P., E-mail: muruga@iitm.ac.in [Department of Physics, Indian Institute of Technology Madras, Chennai 36 (India); Tamilselvan, A.; Balakumar, S. [National Centre for Nanoscience and Nanotechnology, University of Madras, Chennai 25 (India)

2014-02-21T23:59:59.000Z

371

Structure of the rare archaeal biosphere and seasonal dynamics of active ecotypes in surface coastal waters  

Science Journals Connector (OSTI)

...Heidelberg JF Kirchman DL ( 2011 ) Activity of abundant and rare bacteria in a coastal ocean . Proc Natl Acad Sci USA 108 : 12776 – 12781 . 5 Lennon JT Jones SE ( 2011 ) Microbial seed banks: The ecological and evolutionary implications of dormancy...

Mylène Hugoni; Najwa Taib; Didier Debroas; Isabelle Domaizon; Isabelle Jouan Dufournel; Gisèle Bronner; Ian Salter; Hélène Agogué; Isabelle Mary; Pierre E. Galand

2013-01-01T23:59:59.000Z

372

Recycling Rare Earth Elements from Industrial Wastewater with Flowerlike Nano-Mg(OH)2  

Science Journals Connector (OSTI)

Recycling Rare Earth Elements from Industrial Wastewater with Flowerlike Nano-Mg(OH)2 ... The pilot-scale experiment indicated that the self-supported flowerlike nano-Mg(OH)2 had great potential to recycle REEs from industrial wastewater. ...

Chaoran Li; Zanyong Zhuang; Feng Huang; Zhicheng Wu; Yangping Hong; Zhang Lin

2013-09-13T23:59:59.000Z

373

Synthesis, Computations and Characterizations of Low Dimensional Rare-Earth Compounds  

E-Print Network (OSTI)

Reduced rare-earth (Ln, lanthanide elements) compounds with low-dimensional Ln-Ln-bonded structures are promising candidates for magnetic materials because Ln-Ln-bonded molecules and solids have delocalized 5d electrons that make strong magnetic...

Chen, Chun-Yu

2014-04-28T23:59:59.000Z

374

Tricking Iron into Acting like a Rare-earth Element | The Ames...  

NLE Websites -- All DOE Office Websites (Extended Search)

Tricking Iron into Acting like a Rare-earth Element By slipping iron between two nitrogen atoms in a lithium matrix, researchers are able to trick iron into having magnetic...

375

Facility for Rare Isotope Beams: The Journey Has Begun on DOE's latest Scientific User Facility  

Energy.gov (U.S. Department of Energy (DOE))

After many years of planning, ground was officially broken on the Facility for Rare Isotope Beams (FRIB) in a ceremony held at the construction site on Michigan State University’s campus.

376

Geochemistry of dissolved rare earth elements in the Equatorial Pacific Ocean  

Science Journals Connector (OSTI)

Seawater samples were collected from four locations in the Equatorial Pacific Ocean during the MR02-K06 cruise of the R/V Mirai...and analyzed for dissolved rare earth elements (REEs) using inductively coupled pl...

Zhong-Liang Wang; Masatoshi Yamada

2007-04-01T23:59:59.000Z

377

Mutagenic properties of O/sup 6/-methylguanine in DNA in vivo and in vitro  

SciTech Connect

Among the many basic alkylated sites produced in DNA by simple alkylating mutagens, O/sup 6/-alkylguanine is believed to be the major promutagenic lesion. Using O/sup 6/-methyl dGTP as a substrate during in vitro synthesis of biologically active T7 DNA we have shown that the incorporation of the alkylated nucleotide leads to increased reversion of an amber mutation in the phage DNA. We have shown that O/sup 6/-methylguanine has a strong preference for pairing with thymine over cytosine during in vitro replication of synthetic DNA templates with T4 and T5 phage DNA polymerases and E. coli DNA polymerase I. The degree of preference depends not only on the DNA polymerase used but possibly on other factors as well, including the divalent metal ion cofactors. The alkylated base in the template DNA also inhibits chain elongation of the product strand. While O/sup 6/-methyl dGTP can act as a substrate for DNA polymerases, as an analog of dATP, the alkylated nucleotide is incorporated only infrequently and inhibits overall DNA synthesis at the same time. A much higher turnover of the alkylated nucleotide than that of the normal nucleotides suggests that O/sup 6/-methylguanine is not recognized as a normal base by the DNA polymerases in spite of the fact that it is predicted to form a stable base pair with thymine.

Snow, E.T.; Foote, R.S.; Dodson, L.A.; Masker, W.; Mitra, S.

1983-01-01T23:59:59.000Z

378

Safety and core design of large liquid-metal cooled fast breeder reactors  

E-Print Network (OSTI)

Absorption Metal (Zr) Metal (Mo) Carbide Nitride Oxidef /? a k ? Metal (Zr) Metal (Mo) Carbide Nitride Oxide Table? a k ? Metal (Zr) Metal (Mo) Carbide Nitride Oxide CHAPTER

Qvist, Staffan Alexander

2013-01-01T23:59:59.000Z

379

Intracollisional Interference in the Spectrum of HD Mixed with Rare Gases  

Science Journals Connector (OSTI)

We present the first observation and interpretation of an interference effect in the infrared absorption spectrum of HD-rare-gas mixtures. This effect, due to constructive or destructive interference between allowed and collision-induced dipoles during a collision, is referred to as "intracollisional interference." Is is manifested by the appearance of a narrow line at the R1(1) position which increases with rare-gas density. This interference has relevance to the determination of HD abundance in planetary atmospheres.

J. D. Poll; R. H. Tipping; R. D. G. Prasad; S. Paddi Reddy

1976-02-02T23:59:59.000Z

380

Advances in Metallic Nuclear Fuel  

Science Journals Connector (OSTI)

Metallic nuclear fuels have generated renewed interest for advanced ... operations is excellent. Ongoing irradiation tests in Argonne-West’s Idaho-based Experimental Breeder Reactor ... fast reactor (IFR) concept...

B. R. Seidel; L. C. Walters; Y. I. Chang

1987-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Doping Graphene with Metal Contacts  

Science Journals Connector (OSTI)

Making devices with graphene necessarily involves making contacts with metals. We use density functional theory to study how graphene is doped by adsorption on metal substrates and find that weak bonding on Al, Ag, Cu, Au, and Pt, while preserving its unique electronic structure, can still shift the Fermi level with respect to the conical point by ?0.5??eV. At equilibrium separations, the crossover from p-type to n-type doping occurs for a metal work function of ?5.4??eV, a value much larger than the graphene work function of 4.5 eV. The numerical results for the Fermi level shift in graphene are described very well by a simple analytical model which characterizes the metal solely in terms of its work function, greatly extending their applicability.

G. Giovannetti; P. A. Khomyakov; G. Brocks; V. M. Karpan; J. van den Brink; P. J. Kelly

2008-07-10T23:59:59.000Z

382

Electrical Resistance of Ferromagnetic Metals  

Science Journals Connector (OSTI)

......Physics September 1959 research-article Articles Electrical Resistance of Ferromagnetic Metals Isao Mannari Department of Physics...the Physical Society of Japan 81 (2012) 064715 (8 pages) Electric and Magnetic Properties of bcc Fe Based Multicomponent Alloys......

Isao Mannari

1959-09-01T23:59:59.000Z

383

Selenophene transition metal complexes  

SciTech Connect

This research shows that selenophene transition metal complexes have a chemistry that is similar to their thiophene analogs. Selenophene coordination has been demonstrated and confirmed by molecular structure in both the {eta}{sup 5}- and the {eta}{sup 1}(Se)-coordination modes. The reaction chemistry of selenophene complexes closely resembles that of the analogous thiophene complexes. One major difference, however, is that selenophene is a better donor ligand than thiophene making the selenophene complexes more stable than the corresponding thiophene complexes. The {sup 77}Se NMR chemical shift values for selenophene complexes fall within distinct regions primarily depending on the coordination mode of the selenophene ligand. In the final paper, the C-H bond activation of {eta}{sup 1}(S)-bound thiophenes, {eta}{sup 1}(S)-benzothiophene and {eta}{sup 1}(Se)-bound selenophenes has been demonstrated. The deprotonation and rearrangement of the {eta}{sup 1}(E)-bound ligand to the carbon bound L-yl complex readily occurs in the presence of base. Reprotonation with a strong acid gives a carbene complex that is unreactive towards nucleophilic attack at the carbene carbon and is stable towards exposure to air. The molecular structure of [Cp(NO)(PPh{sub 3})Re(2-benzothioenylcarbene)]O{sub 3}SCF{sub 3} was determined and contains a Re-C bond with substantial double bond character. Methyl substitution for the thienylcarbene or selenylcarbene gives a carbene that rearranges thermally to give back the {eta}{sup 1}(E)-bound complex. Based on these model reactions, a new mechanism for the H/D exchange of thiophene over the hydrodesulfurization catalyst has been proposed.

White, C.J.

1994-07-27T23:59:59.000Z

384

Synthesis and characterization of visible emission from rare-earth doped aluminum nitride, gallium nitride and gallium aluminum nitride powders and thin films  

E-Print Network (OSTI)

74 (19) 2821 (1999). F. H. Spedding, Rare-earth Elements, inby the use of rare- earth elements as color emitters inpowders activated with rare-earth elements Eu 3+ , Tb 3+ ,

Tao, Jonathan Huai-Tse

2010-01-01T23:59:59.000Z

385

Titanium metal: extraction to application  

SciTech Connect

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

Gambogi, Joseph (USGS, Reston, VA); Gerdemann, Stephen J.

2002-09-01T23:59:59.000Z

386

Anaerobic microbial remobilization of coprecipitated metals  

DOE Patents (OSTI)

A process is provided for solubilizing coprecipitated metals. Metals in waste streams are concentrated by treatment with an iron oxide coprecipitating agent. The coprecipitated metals are solubilized by contacting the coprecipitate with a bacterial culture of a Clostridium species ATCC 53464. The remobilized metals can then be recovered and recycled. 4 figs.

Francis, A.J.; Dodge, C.J.

1994-10-11T23:59:59.000Z

387

The metal–insulator transition: a perspective  

Science Journals Connector (OSTI)

...transition in condensed phases. Phys. Rev. B...M. J. 1982 The transition to the metallic...metalnon-metal transition in expanded metals...of electrons and ions in condensed matter...The metalnonmetal transition in disordered systems...1996c The changing phase of expanded metals...

1998-01-01T23:59:59.000Z

388

Metal sponge for cryosorption pumping applications  

DOE Patents (OSTI)

A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area. 4 figs.

Myneni, G.R.; Kneisel, P.

1995-12-26T23:59:59.000Z

389

OXFORD BIBLIOGRAPHIES IN ECOLOGY "HEAVY METAL TOLERANCE"  

E-Print Network (OSTI)

cellular mechanisms affected by heavy metals is Bánfalvi 2011. Pollution by heavy metals is an important environmental problem, and sources that focus on heavy metal pollution often contain information about heavyOXFORD BIBLIOGRAPHIES IN ECOLOGY "HEAVY METAL TOLERANCE" By Nishanta Rajakaruna and Robert S. Boyd

Rajakaruna, Nishanta

390

Metal salt catalysts for enhancing hydrogen spillover  

SciTech Connect

A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

Yang, Ralph T; Wang, Yuhe

2013-04-23T23:59:59.000Z

391

Metal sponge for cryosorption pumping applications  

DOE Patents (OSTI)

A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area.

Myneni, Ganapati R. (Yorktown, VA); Kneisel, Peter (Williamsburg, VA)

1995-01-01T23:59:59.000Z

392

Modal analysis and coupling in metal-insulator-metal waveguides  

Science Journals Connector (OSTI)

This paper shows how to analyze plasmonic metal-insulator-metal waveguides using the full modal structure of these guides. The analysis applies to all frequencies, particularly including the near infrared and visible spectrum, and to a wide range of sizes, including nanometallic structures. We use the approach here specifically to analyze waveguide junctions. We show that the full modal structure of the metal-insulator-metal (MIM) waveguides—which consists of real and complex discrete eigenvalue spectra, as well as the continuous spectrum—forms a complete basis set. We provide the derivation of these modes using the techniques developed for Sturm-Liouville and generalized eigenvalue equations. We demonstrate the need to include all parts of the spectrum to have a complete set of basis vectors to describe scattering within MIM waveguides with the mode-matching technique. We numerically compare the mode-matching formulation with finite-difference frequency-domain analysis and find very good agreement between the two for modal scattering at symmetric MIM waveguide junctions. We touch upon the similarities between the underlying mathematical structure of the MIM waveguide and the PT symmetric quantum-mechanical pseudo-Hermitian Hamiltonians. The rich set of modes that the MIM waveguide supports forms a canonical example against which other more complicated geometries can be compared. Our work here encompasses the microwave results but extends also to waveguides with real metals even at infrared and optical frequencies.

?ükrü Ekin Kocaba?; Georgios Veronis; David A. B. Miller; Shanhui Fan

2009-01-26T23:59:59.000Z

393

Electron Spin Resonance in Metals and Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

Electron spin resonance measurements have been made at 300 Mc/sec on frozen metal ammonia solutions, liquid metal ammonia solutions, and liquid metals. The experiments on frozen solutions have shown that the metal is precipitated out in small particles. Nuclear resonance experiments have corroborated this finding. The frozen solutions are used as a convenient source of small particles, and observations have been made of relaxation times in Na, Li, K, and Cs. Resonances in the liquid ammonia solutions of Li, Na, K, Rb, Cs, and Ca, and also in a solution of Li in methylamine were observed. The data are consistent with the theoretical model of Kraus, Ogg, and Kaplan and Kittel. Bulk metal resonances were observed to temperatures above the melting points on lithium and sodium. The results for sodium corroborate the Elliott theory of relaxation, and the lithium results indicate resistivity-dependent relaxation time. No resonance was observed in bulk K, Rb, and Cs carried to temperatures above their melting points.

R. A. Levy

1956-04-01T23:59:59.000Z

394

Alkali-metal-atom chemisorption onto a metal surface  

Science Journals Connector (OSTI)

Recent theoretical and experimental work implies that an alkali-metal atom chemisorbed onto a metal surface can be viewed within a ‘‘dressed-atom’’ picture, i.e., as an atom whose wave functions are perturbed due to its interaction with the surrounding host lattice. This picture is similar to that used for a noble-gas atom physisorbed onto a metal surface. Such an approach utilizes the calculational method of the coupled–Hartree-Fock theory, and it is applied in the present work to the chemisorption of a potassium atom onto a semi-infinite Na(001) substrate. Results for the Hartree-Fock ground state of the chemisorbed K atom, its induced dipole moment, and induced splitting of its p-orbital states are calculated at various substrate-adatom separations. It has been found that the induced dipole moment exhibits a maximum in its absolute value as the metal-adatom separation changes; most of the contribution to the dipole moment is due to the 3s- and 4s-electron states, while the pz states have been found to be counterpolarized, i.e., they polarize toward the vacuum side. On the other hand, the calculated dipole moments of the adatom were found to be too small to account for the observed work-function changes during alkali-metal chemisorption on a mteal surface.

A. N. Andriotis

1990-11-15T23:59:59.000Z

395

Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum  

DOE Patents (OSTI)

An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

2000-01-01T23:59:59.000Z

396

Magnetic preferential orientation of metal oxide superconducting materials  

DOE Patents (OSTI)

A superconductor comprised of a polycrystalline metal oxide such as YBa[sub 2]Cu[sub 3]O[sub 7[minus]X] (where 0 < X < 0.5) exhibits superconducting properties and is capable of conducting very large current densities. By aligning the two-dimensional Cu-O layers which carry the current in the superconducting state in the a- and b-directions, i.e., within the basal plane, a high degree of crystalline axes alignment is provided between adjacent grains permitting the conduction of high current densities. The highly anisotropic diamagnetic susceptibility of the polycrystalline metal oxide material permits the use of an applied magnetic field to orient the individual crystals when in the superconducting state to substantially increase current transport between adjacent grains. In another embodiment, the anisotropic paramagnetic susceptibility of rare-earth ions substituted into the oxide material is made use of as an applied magnetic field orients the particles in a preferential direction. This latter operation can be performed with the material in the normal (non-superconducting) state. 4 figs.

Capone, D.W.; Dunlap, B.D.; Veal, B.W.

1990-07-17T23:59:59.000Z

397

Magnetic preferential orientation of metal oxide superconducting materials  

DOE Patents (OSTI)

A superconductor comprised of a polycrystalline metal oxide such as YBa.sub.2 Cu.sub.3 O.sub.7-X (where 0metal oxide material permits the use of an applied magnetic field to orient the individual crystals when in the superconducting state to substantially increase current transport between adjacent grains. In another embodiment, the anisotropic paramagnetic susceptibility of rare-earth ions substituted into the oxide material is made use of as an applied magnetic field orients the particles in a preferential direction. This latter operation can be performed with the material in the normal (non-superconducting) state.

Capone, Donald W. (Bolingbrook, IL); Dunlap, Bobby D. (Bolingbrook, IL); Veal, Boyd W. (Downers Grove, IL)

1990-01-01T23:59:59.000Z

398

Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel  

E-Print Network (OSTI)

of adhesion between metals and transition metal carbides/nitrides based on Density Functional Theory(DFT)[14Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel the nature of metal/carbide bonding. Based on the surface and interfacial free energies, we find that both

Adams, James B

399

Reversible photodeposition and dissolution of metal ions  

DOE Patents (OSTI)

A cyclic photocatalytic process for treating waste water containing metal and organic contaminants. In one embodiment of the method, metal ions are photoreduced onto the photocatalyst and the metal concentrated by resolubilization in a smaller volume. In another embodiment of the method, contaminant organics are first oxidized, then metal ions removed by photoreductive deposition. The present invention allows the photocatalyst to be recycled until nearly complete removal of metal ions and organic contaminants is achieved.

Foster, Nancy S. (Boulder, CO); Koval, Carl A. (Golden, CO); Noble, Richard D. (Boulder, CO)

1994-01-01T23:59:59.000Z

400

Coated Metal Articles and Method of Making  

DOE Patents (OSTI)

The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

Boller, Ernest R.; Eubank, Lowell D.

2004-07-06T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Semiconductor assisted metal deposition for nanolithography applications  

DOE Patents (OSTI)

An article of manufacture and method of forming nanoparticle sized material components. A semiconductor oxide substrate includes nanoparticles of semiconductor oxide. A modifier is deposited onto the nanoparticles, and a source of metal ions are deposited in association with the semiconductor and the modifier, the modifier enabling electronic hole scavenging and chelation of the metal ions. The metal ions and modifier are illuminated to cause reduction of the metal ions to metal onto the semiconductor nanoparticles.

Rajh, Tijana (Naperville, IL); Meshkov, Natalia (Downers Grove, IL); Nedelijkovic, Jovan M. (Belgrade, YU); Skubal, Laura R. (West Brooklyn, IL); Tiede, David M. (Elmhurst, IL); Thurnauer, Marion (Downers Grove, IL)

2001-01-01T23:59:59.000Z

402

Semiconductor assisted metal deposition for nanolithography applications  

DOE Patents (OSTI)

An article of manufacture and method of forming nanoparticle sized material components. A semiconductor oxide substrate includes nanoparticles of semiconductor oxide. A modifier is deposited onto the nanoparticles, and a source of metal ions are deposited in association with the semiconductor and the modifier, the modifier enabling electronic hole scavenging and chelation of the metal ions. The metal ions and modifier are illuminated to cause reduction of the metal ions to metal onto the semiconductor nanoparticles.

Rajh, Tijana (Naperville, IL); Meshkov, Natalia (Downers Grove, IL); Nedelijkovic, Jovan M. (Belgrade, YU); Skubal, Laura R. (West Brooklyn, IL); Tiede, David M. (Elmhurst, IL); Thurnauer, Marion (Downers Grove, IL)

2002-01-01T23:59:59.000Z

403

Electronic Structure of Noble-Metal-Noble-Metal Alloys  

Science Journals Connector (OSTI)

We describe optical studies of dilute noble-metal-noble-metal alloys. A differential technique compared the reflectance of the alloy with the reflectance of the pure metal and measured a quantity proportional to just the difference in reflectance. The method was particularly sensitive to small changes in reflectances and could be used to study very dilute alloys-the alloys here were between 110- and 3-at.% impurity concentration. The measurements indicated that the noble alloys are of two types. In copper-gold and silver-gold alloys the electron energy bands shift smoothly as the concentration varies. The rates and directions of shifts are determined not only by differences in the host and impurity potentials, but also by the changes in lattice constant, and we emphasize the importance of the latter. In contrast, in copper-silver alloys separate host and impurity d bands are formed.

David Beaglehole and Erich Erlbach

1972-08-15T23:59:59.000Z

404

Electron transport through a metal-molecule-metal junction  

Science Journals Connector (OSTI)

Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been recorded at room temperature. Zero bias conductances were measured in the 10–100 nS range and different kinds of nonlinear I-V curves with steplike features were reproducibly obtained. Switching between different kinds of I-V curves could be induced by varying the distance between the two metallic electrodes. The experimental results are discussed within the framework of tunneling transport models explicitly taking into account the discrete nature of the electronic spectrum of the molecule.

C. Kergueris; J.-P. Bourgoin; S. Palacin; D. Esteve; C. Urbina; M. Magoga; C. Joachim

1999-05-15T23:59:59.000Z

405

Air Pollution with Heavy Metals and Radionuclides in Slovakia Studied by the Moss Biomonitoring Technique  

E-Print Network (OSTI)

Applying the moss biomonitoring technique to air pollution studies in Slovakia, heavy metals, rare-earth elements, actinides (U and Th) were determined in 86 moss samples from the European moss survey 2000 by means of epithermal neutron activation analysis at the IBR-2 reactor (Dubna). Such elements as In, Cu, Cd, Hg and Pb were determined by AAS in the Forest Research Institute, Zvolen (Slovakia). The results of measurement of the natural radionuclides ^{210}Pb, ^{7}Be, ^{137}Cs and ^{40}K in 11 samples of moss are also reported. A comparison with the results from moss surveys 1991 and 1995 revealed previously unknown tendencies of air pollution in the examined areas.

Florek, M; Mankovska, B; Oprea, K; Pavlov, S S; Steinnes, E; Sykora, I

2001-01-01T23:59:59.000Z

406

Cold nuclear fusion in metallic hydrogen and normal metals  

Science Journals Connector (OSTI)

The rate of nuclear fusion from tunneling in very dense metallic hydrogen in the core of Jupiter is calculated to be 10-50 per hydrogen-deuterium pair per second. It is estimated that the width of the fusion barrier for deuterium in palladium or a similar metal must be reduced to, of order, 0.1 A? for the fusion rate to be 10-25 per deuterium per second. If this scale is achieved, the ratios of various nuclear reaction rates will be very different for cold versus thermonuclear fusion.

Charles J. Horowitz

1989-10-01T23:59:59.000Z

407

Electron-electron scattering in metal-insulator-metal sandwiches  

Science Journals Connector (OSTI)

We have studied weak localization and electron-electron interaction effects in samples consisting of two thin metal films separated by an insulating layer of SiO. When the SiO thickness was less than about 200 Å, the electron-electron scattering rate was enhanced with respect to that found in isolated, i.e., well-separated, films. This suggests that in the sandwich structures, electrons in one metal film are able to ‘‘communicate’’ with, i.e., scatter from, electrons in the other film across distances of order 200 Å, and that this process enhances the phase-breaking rate.

N. Giordano and N. R. Dilley

1993-08-15T23:59:59.000Z

408

Semiconductor-To-Metal Transitions in Transition-Metal Compounds  

Science Journals Connector (OSTI)

The theory presented in a previous paper is applied to the transition-metal compounds which are known to exhibit semiconductor-to-metal transitions. In particular, the predictions of the theory are compared with the experimental results of Feinleib and Paul on V2O3. Very good agreement is obtained for the magnitude of the energy gap and for its pressure and stress coefficients. The theory appears to be consistent with the available data on the other oxides of vanadium and titanium as well. Band models for all of these compounds are suggested. The effects of spin-disorder scattering and broadening, polaron formation, and non-stoichiometry are considered quantitatively.

David Adler; Julius Feinleib; Harvey Brooks; William Paul

1967-03-15T23:59:59.000Z

409

Bioavailability of Cadmium and Zin to Two Earthworm Species in High-metal Soils  

E-Print Network (OSTI)

bioavailability of rare earth elements in soils by chemicalavailability of rare earth elements in soil. Communicationsof bioavailability of light rare earth elements to wheat (

Liu, Ying

2012-01-01T23:59:59.000Z

410

Diesel and biodiesel exhaust particle effects on rat alveolar macrophages with in vitro exposure  

Science Journals Connector (OSTI)

Abstract Combustion emissions from diesel engines emit particulate matter which deposits within the lungs. Alveolar macrophages (AMs) encounter the particles and attempt to engulf the particles. Emissions particles from diesel combustion engines have been found to contain diverse biologically active components including metals and polyaromatic hydrocarbons which cause adverse health effects. However little is known about AM response to particles from the incorporation of biodiesel. The objective of this study was to examine the toxicity in Wistar Kyoto rat AM of biodiesel blend (B20) and low sulfur petroleum diesel (PDEP) exhaust particles. Particles were independently suspended in media at a range of 1–500 ?g mL?1. Results indicated B20 and PDEP initiated a dose dependent increase of inflammatory signals from AM after exposure. After 24 h exposure to B20 and PDEP gene expression of cyclooxygenase-2 (COX-2) and macrophage inflammatory protein 2 (MIP-2) increased. B20 exposure resulted in elevated prostaglandin E2 (PGE2) release at lower particle concentrations compared to PDEP. B20 and PDEP demonstrated similar affinity for sequestration of PGE2 at high concentrations, suggesting detection is not impaired. Our data suggests PGE2 release from AM is dependent on the chemical composition of the particles. Particle analysis including measurements of metals and ions indicate B20 contains more of select metals than PDEP. Other particle components generally reduced by 20% with 20% incorporation of biodiesel into original diesel. This study shows AM exposure to B20 results in increased production of PGE2 in vitro relative to diesel.

Laya Bhavaraju; Jonathan Shannahan; Aaron William; Robert McCormick; John McGee; Urmila Kodavanti; Michael Madden

2014-01-01T23:59:59.000Z

411

Useful variation in in vitro digestibility within perennial ryegrass  

Science Journals Connector (OSTI)

In vitro dry matter digestibility (DMD) and dry matter yield (DMY) of herbage from plots sown with three selected perennial ryegrass varieties with similar heading dates (Ba11778, Talbot and Gator) under a range ...

P.W. Wilkins

1997-01-01T23:59:59.000Z

412

DNA synthetic rates among cells of populations in vitro  

Science Journals Connector (OSTI)

In vitro gezüchtete Hühnerembryozellen werden mit3H-Thymidin oder14C-Thymidin «pulse-labeled», wobei «grain counts» und DNS-Gehalt in individuellen Zellen gemessen werden. Für keine der beiden Isotopen wurde eine...

N. S. Cohn

413

Proteolytic Surface Functionalization Enhances in Vitro Magnetic Nanoparticle  

E-Print Network (OSTI)

Proteolytic Surface Functionalization Enhances in Vitro Magnetic Nanoparticle Mobility through interstitial delivery of macromolecular and nanoparticle (NP) based therapeutic agents. Collagenase- linked-functionalized superparamagnetic nanoparticle (SPM NP) vehicle. The magnetic character of the SPM NP provides spatial and temporal

414

In vitro sensitivity of Cryphonectria parasitica to six agrochemicals  

Science Journals Connector (OSTI)

The in vitro effectiveness of six agrochemicals (captan, epoxiconazole, azoxistrobin, folpet in...Cryphonectria parasitica, the causal agent of chestnut blight. Epoxiconazol was the most effective product since i...

G. González-Varela; A. J. González

2007-12-01T23:59:59.000Z

415

In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30F In Vitro Genotoxicity of Particulate...

416

Approximating Metal-Insulator Transitions  

E-Print Network (OSTI)

We consider quantum wave propagation in one-dimensional quasiperiodic lattices. We propose an iterative construction of quasiperiodic potentials from sequences of potentials with increasing spatial period. At each finite iteration step the eigenstates reflect the properties of the limiting quasiperiodic potential properties up to a controlled maximum system size. We then observe approximate metal-insulator transitions (MIT) at the finite iteration steps. We also report evidence on mobility edges which are at variance to the celebrated Aubry-Andre model. The dynamics near the MIT shows a critical slowing down of the ballistic group velocity in the metallic phase similar to the divergence of the localization length in the insulating phase.

C. Danieli; K. Rayanov; B. Pavlov; G. Martin; S. Flach

2014-05-06T23:59:59.000Z

417

Magnetism of nanosized metallic particles  

Science Journals Connector (OSTI)

The magnetism of a small cluster of magnetic atoms at finite temperatures is numerically investigated. The evolution of the system towards thermal equilibrium is studied, and the possibility of occurrence of vortexlike excitations in the arrangement of the magnetic moments within the cluster is pointed out. The magnetization curve as a function of temperature, of a small magnetic particle, suggests that magnetic clusters in granular metals are not saturated even at room temperature. The relevance of the present results to the understanding of the magnetic behavior of granular metals is discussed.

P. Vargas; J. d’Albuquerque e Castro; D. Altbir

1999-09-01T23:59:59.000Z

418

Atomic and electronic structure of simple metal/graphene and complex metal/graphene/metal interfaces  

Science Journals Connector (OSTI)

Structural, electronic, and magnetic properties of simple interfaces (graphene on top of a metallic substrate) and complex interfaces (a single metallic adlayer on a simple graphene/metal system, either on top or between the graphene and metallic substrate) have been studied using density functional theory. Two types of simple interface with strong (Ni/graphene) and weak (Cu/graphene) bonding were considered. In addition to binding energies and interface distances, which are used to quantify the strength of graphene-substrate interactions, the bonding in simple and complex interfaces was analyzed using charge density distributions and bond orders. Substantial enhancement of the metallic substrate/graphene binding was observed in complex interfaces, consisting of a Ni monolayer on top of a simple {Ni or Cu}/graphene interface. The increase of substrate-graphene bonding in such complex interfaces is accompanied by weakening of in-plane C-C bonds in graphene, as quantified by the bond orders. A weak ferrimagnetism in graphene, i.e., unequal magnetic moments ?0.04?B and +0.06?B on the C atoms, is induced by a ferromagnetic Ni substrate. The strength of graphene-substrate interactions is also reflected in simulated scanning tunneling microscopy images.

Lyudmyla Adamska; You Lin; Andrew J. Ross; Matthias Batzill; Ivan I. Oleynik

2012-05-22T23:59:59.000Z

419

10 Questions for a Materials Scientist: Mr. Rare Earth -- Dr. Karl A.  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Materials Scientist: Mr. Rare Earth -- Dr. Karl Materials Scientist: Mr. Rare Earth -- Dr. Karl A. Gschneidner, Jr. 10 Questions for a Materials Scientist: Mr. Rare Earth -- Dr. Karl A. Gschneidner, Jr. April 3, 2013 - 12:59pm Addthis Dr. Karl Gschneidner is holding a neodymium-iron-boron magnet produced using a new, greener process. The process that Dr. Gschneidner helped develop doesn’t produce the environmentally unfriendly byproducts that result from traditional manufacturing methods. | Photo courtesy of Ames Laboratory. Dr. Karl Gschneidner is holding a neodymium-iron-boron magnet produced using a new, greener process. The process that Dr. Gschneidner helped develop doesn't produce the environmentally unfriendly byproducts that result from traditional manufacturing methods. | Photo courtesy of Ames

420

The effect of rare earth elements on the texture and formability of asymmetrically rolled magnesium sheet  

SciTech Connect

The lack of formability is a serious issue when considering magnesium alloys for various applications. Standard symmetric rolling introduces a strong basal texture that decreases the formability; however, asymmetric rolling has been put forward as a possible route to produce sheet with weaker texture and greater ductility. It has also been shown in recent work that weaker textures can be produced through the addition of rare earth elements to magnesium alloys. Therefore, this study has been carried out to investigate the effect of rare earth additions on the texture changes during asymmetric rolling. Two alloys have been used, AZ31B and ZEK100. The effect that the rare earth additions have on the texture of asymmetrically rolled sheet and the subsequent changes in formability will be discussed.

Alderman, Dr. Martyn [Magnesium Elektron North America; Cavin, Odis Burl [ORNL; Davis, Dr. Bruce [Magnesium Elektron North America; Muralidharan, Govindarajan [ORNL; Muth, Thomas R [ORNL; Peter, William H [ORNL; Randman, David [Magnesium Elektron North America; Watkins, Thomas R [ORNL

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Method of forming magnetostrictive rods from rare earth-iron alloys  

DOE Patents (OSTI)

Rods of magnetostrictive alloys of iron with rare earth elements are formed by flowing a body of rare earth-iron alloy in a crucible enclosed in a chamber maintained under an inert gas atmosphere, forcing such molten rare-earth-iron alloy into a hollow mold tube of refractory material positioned with its lower end portion within the molten body by means of a pressure differential between the chamber and mold tube and maintaining a portion of the molten alloy in the crucible extending to a level above the lower end of the mold tube so that solid particles of higher melting impurities present in the alloy collect at the surface of the molten body and remain within the crucible as the rod is formed in the mold tube. 5 figs.

McMasters, O.D.

1986-09-02T23:59:59.000Z

422

Reduced order prediction of rare events in unidirectional nonlinear water waves  

E-Print Network (OSTI)

We consider the problem of short-term prediction of rare, extreme water waves in unidirectional fields, a critical topic for ocean structures and naval operations. One possible mechanism for the occurrence of such rare, unusually-intense waves is nonlinear wave focusing. Recent results have demonstrated that random localizations of energy, induced by the dispersive mixing of different harmonics, can grow significantly due to localized nonlinear focusing. Here we show how the interplay between i) statistical properties captured through linear information such as the waves power spectrum and ii) nonlinear dynamical properties of focusing localized wave groups defines a critical length scale associated with the formation of extreme events. The energy that is locally concentrated over this length scale acts as the "trigger" of nonlinear focusing for wave groups and the formation of subsequent rare events. We use this property to develop inexpensive, short-term predictors of large water waves. Specifically, we sho...

Cousins, Will

2015-01-01T23:59:59.000Z

423

Metal-on-Metal Bonding and Rebonding Revisited  

Science Journals Connector (OSTI)

Density-functional calculations for a wide variety of metals show that, contrary to rebonding theory, ad-dimers do not have notably longer surface bonds than adatoms, do not reside farther above the surface, and do not meet the rebonding arguments for augmented mobility. Rebonding contributes to destabilize ad-dimers, but does not explain inherently weak ad-dimer bonds.

Alexander Bogicevic

1999-06-28T23:59:59.000Z

424

Separation of rare gases and chiral molecules by selective binding in porous organic cages  

SciTech Connect

Abstract: The rare gases krypton, xenon, and radon pose both an economic opportunity and a potential environmental hazard. Xenon is used in commercial lighting, medical imaging, and anesthesia, and can sell for $5,000 per kilogram. Radon, by contrast, Is naturally radioactive and the second largest cause of lung cancer, and radioactive xenon, 133Xe, was a major pollutant released In the Fukushima Daiichi Nuclear Power Plant disaster. We describe an organic cage molecule that can capture xenon and radon with unprecedented selectivity, suggesting new technologies for environmental monitoring, removal of pollutants, or the recovery of rare, valuable elements from air.

Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.; Holden, Daniel; Jelfs, Kim E.; Hasell, Tom; Little, Marc A.; Kewley, Adam; Briggs, Michael E.; Stephenson, Andrew; Thomas, K. M.; Armstrong, Jayne A.; Bell, Jon; Busto, Jose; Noel, Raymond; Liu, Jian; Strachan, Denis M.; Thallapally, Praveen K.; Cooper, Andrew I.

2014-10-31T23:59:59.000Z

425

A programme for electron-impact broadening parameter calculations of ionized rare-earth element lines  

E-Print Network (OSTI)

In order to provide atomic data needed for astrophysical investigations, a set of electron-impact broadening parameters for ionized rare-earth element lines should be calculated. We are going to calculate the electron-impact broadening parameters for more than 50 transitions of ionized rare-earth elements. Taking into account that the spectra of these elements are very complex, for calculation we can use the modified semiempirical approach - MSE or simplified MSE. Also, we can estimate these parameters on the basis of regularities and systematic trends.

L. C. Popovic; M. S. Dimitrijevic

1998-05-15T23:59:59.000Z

426

Heavy metals in Antarctic organisms  

SciTech Connect

To evaluate levels of essential (zinc and copper) and non-essential (mercury and cadmium) heavy metals, 34 species of organisms from different areas close to the Antarctic Peninsula were analysed. These included algae, filter-feeders, omnivorous invertebrates and vertebrates. Mercury was not detected, while cadmium was found in the majority of organisms analysed (detection limit was 0.05 ppm for both metals). The highest cadmium concentration was observed in the starfish Odontaster validus. Anthozoans, sipunculids and nudibranchs showed maximum levels of zinc, while the highest copper level was found in the gastropod Trophon brevispira. Mercury and cadmium levels in fishes were below the detection limit. Concentrations of essential and non-essential metals in birds were highest in liver followed by muscle and eggs. Cadmium and mercury levels in muscle of southern elephant seals were above the detection limit, whereas in Antarctic fur seals they were below it. The objective of the study was to gather baseline information for metals in Antarctic Ocean biota that may be needed to detect, measure and monitor future environmental changes. 46 refs., 7 figs., 8 tabs.

Moreno, J.E.A. de; Moreno, V.J. [Universidad Nacional de Mar del Plata (Argentina); Gerpe, M.S.; Vodopivez, C. [Instituto Antartico Argentino, Buenos Aires (Argentina)

1997-02-01T23:59:59.000Z

427

Magnetism in amorphous transition metals  

Science Journals Connector (OSTI)

Overall features of magnetism in amorphous transition metals have been investigated on the basis of a finite-temperature theory of the local-environment effect. It is shown that the simple ferromagnetism of Fe, Co, and Ni is drastically changed by structural disorder; amorphous transition metals form spin glasses (SG’s) for compositions near amorphous Fe (6.7?N?7.35), ferromagnets for compositions near amorphous Co (7.35?N?9.0), and paramagnetisms for compositions near amorphous Ni (9.0?N?10.0) where N is the number of d electrons. The SG is accompanied by formation of local ferromagnetic clusters for N?7.2, and shows reentrant behavior at the ferromagnetic boundary N?7.35. The ferromagnetism in amorphous transition metals is shown to be well explained by the main-peak position in the noninteracting densities of states. It is found that structural disorder enhances the Curie temperatures (TC) in the range 7.9?N?8.5 as compared with bcc and fcc structures. These results explain recent experimental data for the SG in Fe-rich amorphous alloys and the high TC in amorphous Co-Y alloys, but they are quite different from the early picture obtained for amorphous transition-metal–metalloid alloys.

Y. Kakehashi

1991-05-01T23:59:59.000Z

428

Electrical Resistance of Ferromagnetic Metals  

Science Journals Connector (OSTI)

......calculate the anomalous electrical resistance from the standpoint of s-d...that the anomalous electrical resistance occurs because the exchange...2012) 064715 (8 pages) Electric and Magnetic Properties of...pp. 335-343 Electrical Resistance of Ferromagnetic Metals Isao......

Tadao Kasuya

1956-07-01T23:59:59.000Z

429

Nanoscale Heat Conduction across Metal-Dielectric Interfaces  

E-Print Network (OSTI)

resistance between a metal and a dielectric material assumedresistance of a metallic film bounded by dielectric materials.resistance of a metallic film bounded by dielectric materials.

Ju, Y. Sungtaek

2005-01-01T23:59:59.000Z

430

A Better Method for Evaluating Heavy Metal Water Pollution  

E-Print Network (OSTI)

efforts to control heavy metal pollution have focused oncomponent of heavy metal pollution, Dr. Hering found thatthat makes measuring heavy metal pollution a moving target.

Hering, Janet

2002-01-01T23:59:59.000Z

431

Engineering embedded metal nanoparticles with ion beam technology  

E-Print Network (OSTI)

2002) Engineering embedded metal nanoparticles with ion beam3 Engineering embedded metal nanoparticles with ion beamcompara- Engineering embedded metal nanoparticles with ion

Ren, Feng; Xiao, Xiang Heng; Cai, Guang Xu; Wang, Jian Bo; Jiang, Chang Zhong

2009-01-01T23:59:59.000Z

432

Gas adsorption on metal-organic frameworks  

DOE Patents (OSTI)

The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.

Willis, Richard R. (Cary, IL); Low, John J. (Schaumburg, IL), Faheem, Syed A. (Huntley, IL); Benin, Annabelle I. (Oak Forest, IL); Snurr, Randall Q. (Evanston, IL); Yazaydin, Ahmet Ozgur (Evanston, IL)

2012-07-24T23:59:59.000Z

433

Microstructure of metal-filled carbon nanotubes  

Science Journals Connector (OSTI)

......Microstructure of metal-filled carbon nanotubes Shoichi Toh 1 Kenji Kaneko 2 Yasuhiko...are usually required to produce carbon nanotubes (CNTs) and play important roles during...mechanisms. metal filling|MPCVD|carbon|nanotube|palladium|microstructure| Microstructure......

Shoichi Toh; Kenji Kaneko; Yasuhiko Hayashi; Tomoharu Tokunaga; Won-Jin Moon

2004-04-01T23:59:59.000Z

434

Electrodialysis Treatment of Metal-Cyanide Complexes  

Science Journals Connector (OSTI)

Metal-cyanide complexes have been used for many years as decorative and protective coatings on a variety of metal substrates. The most important method to protect iron and steel against corrosion is the applicati...

Marco Antônio Siqueira Rodrigues; Luciano Marder…

2014-01-01T23:59:59.000Z

435

Transition Metal Ions in the Gas Phase  

Science Journals Connector (OSTI)

For several years we have been studying the chemistry of atomic transition metal ions with simple organic molecules. This research was ... examining the consequences of oxidation and reduction of transition metal...

Douglas P. Ridge

1982-01-01T23:59:59.000Z

436

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network (OSTI)

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Elevated Temperature Corrosion of Oil Shale Retort Component

Bellman Jr., R.

2012-01-01T23:59:59.000Z

437

METAL IONS: Physiological function and Pathological rle  

E-Print Network (OSTI)

disproportion may be dangerous Whether metals are useful or harmful to human health crucially depends contest." #12;Unbalanced metal content may be dangerous abnormally low dietary copper Menkes disease (no

Morante, Silvia

438

NANO - "Green" metal oxides ... | ornl.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

NANO - "Green" metal oxides ... Water and nano-sized particles isolated from trees, plants and algae are the ingredients of a new recipe for low-cost metal oxides that are widely...

439

Time-Resolved XAFS Spectroscopic Studies of B-H and N-H Oxidative Addition to Transition Metal Catalysts Relevant to Hydrogen Storage  

SciTech Connect

Successful catalytic dehydrogenation of aminoborane, H3NBH3, prompted questions as to the potential role of N-H oxidative addition in the mechanisms of these processes. N-H oxidative addition reactions are rare, and in all cases appear to involve initial dative bonding to the metal by the amine lone pairs followed by transfer of a proton to the basic metal. Aminoborane and its trimethylborane derivative block this mechanism and, in principle, should permit authentic N-H oxidative attrition to occur. Extensive experimental work failed to confirm this hypothesis. In all cases either B-H complexation or oxidative addition of solvent C-H bonds dominate the chemistry.

Bitterwolf, Thomas E. [University of Idaho

2014-12-09T23:59:59.000Z

440

Preparation of metal-triazolate frameworks  

DOE Patents (OSTI)

The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.

Yaghi, Omar M; Uribe-Romo, Fernando J; Gandara-Barragan, Felipe; Britt, David K

2014-10-07T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Managing Natural and Reintroduced Rare Plant Populations within a Large Government Reservation  

SciTech Connect

California is home to many large government reservations that have been in existence for decades. Many of these reservations were formed to support various Department of Defense and Department of Energy national defense activities. Often, only a very small percentage of the reservation is actively used for programmatic activities, resulting in large areas of intact habitat. In some cases, this has benefited rare plant populations, as surrounding lands have been developed for residential or industrial use. However, land management activities such as the suppression or active use of fire and other disturbance (such as fire trail grading) can also work to either the detriment or benefit of rare plant populations at these sites. A management regime that is beneficial to the rare plant populations of interest and is at best consistent with existing site programmatic activities, and at a minimum does not impact such activities, has the best potential for a positive outcome. As a result, some species may be 'difficult' while others may be 'easy' to manage in this context, depending on how closely the species biological requirements match the programmatic activities on the reservation. To illustrate, we compare and contrast two rare annual plant species found at Lawrence Livermore National Laboratory's Site 300. Although several populations of Amsinckia grandiflora have been restored on the site, and all populations are intensively managed, this species continues to decline. In contrast, Blepharizonia plumosa appears to take advantage of the annual controlled burns conducted on the site, and is thriving.

Carlsen, T M; Paterson, L E; Alfaro, T M

2009-07-15T23:59:59.000Z

442

Search for supersymmetry using rare B to mumu decays at CDF run II  

E-Print Network (OSTI)

A search for rare B0 s -> µ+µ- and B0d -> µ+µ- decays has been performed in pp collisions at sqroot(s) = 1.96 TeV using 364 pb-1 of data collected by the CDF II experiment at the Fermilab Tevatron Collider. The rate of each decay is sensitive...

Krutelyov, Vyacheslav

2006-04-12T23:59:59.000Z

443

Magnetic properties of rare-earth antiferromagnets studied using a two-ion model  

Science Journals Connector (OSTI)

In this paper, a two-ion model for rare-earth antiferromagnets is proposed and employed to describe the magnetic behavior of HoNi2B2C and DyFe2Si2 at low temperatures. The calculated temperature dependence of the susceptibilities and magnetizations along the hard and easy directions, respectively, shows very good agreement with experimental results.

Z.-S. Liu; M. Diviš; V. Sechovský

2008-12-05T23:59:59.000Z

444

Search for Rare 3 and 4-Body D0 Decays at FNAL E791  

E-Print Network (OSTI)

Limits at the 10**-4 level are reported for rare and forbidden decays of the D0 charm meson to a pair of leptons and either a vector meson or two pseudoscalar mesons. Of these searches, 18 are investigations of decays without previous published results; several others have significantly improved sensitivity over previous results.

Fermilab E791 Collaboration; D. J. Summers

2000-11-21T23:59:59.000Z

445

Conditionally Rare Taxa Disproportionately Contribute to Temporal Changes in Microbial Diversity  

Science Journals Connector (OSTI)

...Kirchman DL. 2011. Activity of abundant and rare bacteria in a coastal ocean. Proc. Natl. Acad. Sci. U. S. A. 108 :12776-12781. doi: 10.1073/pnas.1101405108 . 15. Jones SE and Lennon JT. 2010. Dormancy contributes to the maintenance...

Ashley Shade; Stuart E. Jones; J. Gregory Caporaso; Jo Handelsman; Rob Knight; Noah Fierer; Jack A. Gilbert

2014-08-01T23:59:59.000Z

446

Thermal treatment for increasing magnetostrictive response of rare earth-iron alloy rods  

DOE Patents (OSTI)

Magnetostrictive rods formed from rare earth-iron alloys are subjected to a short time heat treatment to increase their magnetostrictive response under compression. The heat treatment is preferably carried out at a temperature of from 900 to 1,000 C for 20 minutes to six hours.

Verhoeven, J.D.; McMasters, O.D.

1989-07-18T23:59:59.000Z

447

Ternary rare earth-lanthanide sulfides. [Re = Eu, Sm or Yb  

DOE Patents (OSTI)

Disclosed is a new ternary rare earth sulfur compound having the formula La/sub 3-x/M/sub x/S/sub 4/, where M is europium, samarium, or ytterbium, with x = 0.15 to 0.8. The compound has good high-temperature thermoelectric properties and exhibits long-term structural stability up to 1000/sup 0/C.

Takeshita, Takuo; Gschneidner, K.A. Jr.; Beaudry, B.J.

1986-03-06T23:59:59.000Z

448

Selecting Landscape Plants: Rare and Unusual Trees Diane Relf, Extension Specialist, Horticulture, Virginia Tech  

E-Print Network (OSTI)

Selecting Landscape Plants: Rare and Unusual Trees Diane Relf, Extension Specialist, Horticulture, Virginia Tech Bonnie Appleton, Extension Specialist, Horticulture, Virginia Tech There are many tree and smooth, light gray bark make it a very handsome tree. Many unusual cultivars have been elected from

Liskiewicz, Maciej

449

ACCEPTED MANUSCRIPT The behaviour of Rare-Earth Elements, Zr and Hf during biologically-mediated  

E-Print Network (OSTI)

ACCEPTED MANUSCRIPT ACCEPTED MANUSCRIPT 1 The behaviour of Rare-Earth Elements, Zr and Hf during.a,b* , Cangemi M.a , Brusca L.c , Madonia P.c , Saiano F.d , Zuddas P.e a) Department of Earth and Marine at the solid-liquid interface influencing the distribution of trace elements onto microbial surfaces. Since

450

Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds  

E-Print Network (OSTI)

Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds M Abstract. -- The thermal behavior of oxygen-stabilized RjFegO^-hydrogen (R = Y, Dy, Ho) systems was studied decade to the study of the hydrogenation characte- ristics of a variety of intermetallic compounds, our

Paris-Sud XI, Université de

451

Calculation of the electron distribution function of a rare gas nuclear induced plasma  

E-Print Network (OSTI)

1101 Calculation of the electron distribution function of a rare gas nuclear induced plasma A. M of the energy spectrum of the seed electrons. As an example, this calculation is applied to the case of neon ionisantes rapides est calculable, dans sa partie à basse et moyenne énergie, sans la connaissance précise

Paris-Sud XI, Université de

452

Excess of Rare Damaging TUBA4A Variants Suggests Cytoskeletal Defects in ALS  

Science Journals Connector (OSTI)

Identifying disease genes implicated in late-onset neurodegenerative disorders can be challenging due to the lack of DNA samples from multiple affected family members. To overcome this limitation, Smith et al. (2014) report in this issue of Neuron the first exome-wide rare variant analysis in unrelated familial amyotrophic lateral sclerosis (ALS) patients associating TUBA4A with ALS.

Rosa Rademakers; Marka van Blitterswijk

2014-01-01T23:59:59.000Z

453

Power and sample size calculations for designing rare variant sequenc-ing association studies.  

E-Print Network (OSTI)

of the statistical power of SKAT. Required sample size can be computed easily by inverting the power functionPower and sample size calculations for designing rare variant sequenc- ing association studies pow- erful than the collapsing based burden tests under many circumstances [4]. To design new sequence

Lin, Xihong

454

South Florida Sun-Sentinel.com Venus to cross sun in rare celestial event  

E-Print Network (OSTI)

South Florida Sun-Sentinel.com Venus to cross sun in rare celestial event By Robert Nolin, Sun passage across the face of the sun at twilight Tuesday. It's a sight you'll never see again. Called named for the Roman goddess of love will pass between the Earth and the sun for several hours at sunset

Belogay, Eugene A.

455

Rare earth element partitioning between titanite and silicate melts: Henry's law revisited  

E-Print Network (OSTI)

Rare earth element partitioning between titanite and silicate melts: Henry's law revisited Stefan earth elements (REE) between titanite and a range of different silicate melts. Our results show. For geochemical modelling of magmatic processes involving titanite, and indeed other accessory phases

456

Electronic properties of a simple metal-metal interface  

Science Journals Connector (OSTI)

The properties of metal-metal interfaces are of interest in many metallurgical applications. These include grain boundaries, crack growth, friction, and bimetallic adhesion. The present work is a study of the electronic properties of a simple bimetallic junction. The methods employed to investigate the interface are the Green's-function technique and the phase-shift method. We calculate the Green's function of a simple junction within the tight-binding approximation. The conditions for the occurrence of bound states are deduced from the poles of the Green's function. Using the phase-shift method we derive an expression for the change in density of states due to the creation of the interface. From this expression we derive the corresponding single-particle contribution to the interface energy and the interface specific heat.

Avishay Yaniv

1978-05-15T23:59:59.000Z

457

Metal-nonmetal transition in metal-ammonia solutions  

Science Journals Connector (OSTI)

In this paper we present a coherent physical picture of the metal-nonmetal transition in metal-ammonia solutions in the intermediate concentration range. We propose that in Li-NH3 and Na-NH3 solutions the metallic propagation regime is separated from a nonmetallic regime by a microscopically inhomogeneous regime in which the concentration fluctuates locally about either of two well-defined values M0 and M1, M0>M1, the local concentration remaining near M0 or M1 over radii approximately equal to the Debye short correlation length b for concentration fluctuations. Provided that the concentration-fluctuation decay length is much smaller than b, we can define a percolation problem in which a volume fraction C of the material is occupied by metallic regions of concentration M0, the remainder containing the low concentration M1 of dissociated electron-cation complexes. M0 and M1 constitute the upper and the lower bounds of the inhomogeneous regime, respectively, while C exhibits a linear dependence on M. This physical picture is borne out by concentration-fluctuation determinations based on chemical-potential measurements in Li and Na solutions and by small-angle x-ray and neutron scattering in Li solutions. Assuming that the phase-coherence length of the conduction electrons is shorter than b and having demonstrated that tunneling corrections are negligible, we can define local electronic structure and transport properties. The limits of the inhomogeneous regime were determined from a combination of concentration-fluctuation measurements, electrical conductivity, Hall effect, and paramagnetic susceptibility data to be M0=9 mole percent metal (MPM) and M1=2(13) MPM, which yield the C scale, C=[M-2(13)]6(23), for both Li-NH3 at 223°K and for Na-NH3 at 240°K. We have also established the consistency of our picture with the available magnetic data for Na solutions. An analysis of the electronic and the thermal transport properties was carried out in terms of an effective-medium theory, modified to account for scattering from the boundaries of the metallic clusters. For low values of the conductivity ratio (? 10-3) between the nonmetallic and the metallic regions the modified effective-medium theory is valid for C>0.4. In an attempt to mimic the features of continuous percolation, we have carried out numerical simulations of the conductivity in a simple cubic lattice incorporating correlation between metallic bonds. An excellent fit of the experimental conductivity data for Li and Na with the results of the numerical simulations has been obtained over a three order of magnitude variation of the conductivity throughout the entire inhomogeneous regime. A small systematic negative deviation of the conductivity from the predictions of the effective-medium theory for C>0.4 can be properly accounted for in terms of boundary scattering corrections resulting in b?15 Å for Li at 223°K and b?32 Å for Na at 240°K. The overall agreement of the experimental Hall effect, Hall mobility, thermalconductivity, and thermoelectric-power data with the effective-medium theory is good. The proposed inhomogeneous regime in Li and Na solutions resembles a macroscopic mixed phase at a concentration inside a coexistence curve but with mixing on a microscopic scale. The concentration fluctuations in the inhomogeneous state have nothing to do with critical fluctuations; nevertheless, this state seems to be closely associated with the occurrence of a phase separation.

Joshua Jortner and Morrel H. Cohen

1976-02-15T23:59:59.000Z

458

Growth dynamics at a metal-metal interface  

Science Journals Connector (OSTI)

A determination of the sticking coefficient of sputter-deposited metal films on freshly deposited metal surfaces is described in detail. The systems investigated were Mo deposited on Ta and Ta on Mo. Also described is a detailed determination of the structure of Mo-Ta interfaces using Rutherford backscattering spectrometry and a combination of x-ray diffraction techniques. Within a few angstroms of each interface we find that the lattice is stretched in the growth direction and has an excess of defects relative to the ‘‘bulk’’ lattice. We also find that Mo/Ta superlattices fabricated with wavelengths in the range 20 to 120 A? exhibit structural coherence extending over a number of superlattice layers.

Wayne R. Bennett; J. A. Leavitt; Charles M. Falco

1987-03-15T23:59:59.000Z

459

Metal-dielectric-metal surface plasmon-polariton resonators  

Science Journals Connector (OSTI)

A theoretical study of standing-wave resonances of surface plasmon polaritons (SPPs) in finite-length metal-dielectric-metal cavities is presented. A Fabry-Pérot model is constructed to describe the cavity resonances, and the associated optical parameters are calculated analytically. One key parameter is the phase acquired by resonating SPPs upon reflection from cavity end faces. This phase pickup is associated with the near-field energy storage at these end faces, and the imaginary part of the reflection coefficient is shown to be approximately proportional to the stored energy. Using the Fabry-Pérot model, we also calculate the transmission cross section, peak position, as well as the Q factor of the cavity, and we find good agreement with full-field numerical simulations for a wide range of wavelengths and device dimensions.

Anu Chandran; Edward S. Barnard; Justin S. White; Mark L. Brongersma

2012-02-09T23:59:59.000Z

460

Theory of the alkali-metal chemisorption on metal surfaces  

Science Journals Connector (OSTI)

The electronic structure of the alkali-metal adatom on metal surfaces is studied by a first-principles method as a function of adatom coverage (?). We employ ‘‘jellium’’ as a high-density metal substrate to make a continuous change of ? possible. Although the characteristic variation of the work function with ? is reproduced well by the present calculation, its mechanism is different from a widely accepted mechanism in which the adatom electronic structure is assumed to change from ionic to neutral with increasing ? by the depolarization shift. The charge redistribution ??(r,?) that lowers the work function deviates far from the point-charge-transfer model, and the electrostatic potential change at adatom sites due to ??(r,?) depends very little on ?. Accordingly, the adatom valence density of states shows no downward shift with increasing ?. The adatom region is essentially neutral, even at low ?. The bonding-antibonding boundary in the bond-order density of the adatom-substrate bond coincides well with the Fermi level at low ?, indicating a formation of a metallic bond by the maximum use of bonding states even at low ?. The close similarity between the calculated bond-order and dipole densities as a function of the one-electron energy implies that the adatom polarization due to the hybridization of adatom and substrate orbitals plays an important role for the adatom dipole and its ? dependence even at low ?. The decrease of the adatom dipole is explained by a weakening of the adatom-substrate bonding as well as a significant decrease in the dipole matrix elements with increasing ?.

H. Ishida

1988-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Metal Dusting of Heat-Resistant Alloys  

E-Print Network (OSTI)

Metal dusting leads to disintegration of such alloys as iron and nickel-based into a “dust” of particulate metal, metal carbide, carbon, and/or oxide. It occurs in strongly carburising environments at 400-900°C. Literature survey has shown...

Al-Meshari, Abdulaziz I

462

TRANSITION DE MOTT METAL-INSULATOR TRANSITIONS  

E-Print Network (OSTI)

predominantly non-trivalent ions favor the metallicstate. I. Introduction. -Transition metal oxides form a class that such a transition would be dis- continuous as a function of volume [8], and he later proposed a phase diagramTRANSITION DE MOTT METAL-INSULATOR TRANSITIONS IN TRANSITION METAL OXIDES by D. B. McWHAN, A. MENTH

Paris-Sud XI, Université de

463

Process for making transition metal nitride whiskers  

DOE Patents (OSTI)

A process for making metal nitrides, particularly titanium nitride whiskers, using a cyanide salt as a reducing agent for a metal compound in the presence of an alkali metal oxide. Sodium cyanide, various titanates and titanium oxide mixed with sodium oxide react to provide titanium nitride whiskers that can be used as reinforcement to ceramic composites. 1 fig., 1 tab.

Bamberger, C.E.

1988-04-12T23:59:59.000Z

464

Characterization of Metal-Cyanobacteria Sorption  

E-Print Network (OSTI)

Characterization of Metal-Cyanobacteria Sorption Reactions: A Combined Macroscopic and Infrared titration, and metal sorption experiments to characterize metal-cyanobacteria sorption reactions. Infrared.3 and 4.8 ( 0.3, 6.5 ( 0.1, 8.7 ( 0.2, respectively. Finally, Cu2+, Cd2+, and Pb2+ sorption experiments

Benning, Liane G.

465

Cubic rare-earth compounds: Variants of the three-state Potts model  

Science Journals Connector (OSTI)

In appropriate cubic fields rare-earth ions have sixfold degenerate ground states. When the angular momentum of the rare earth is large, the six levels are characterized by states that are directed along the cube edges. Within these states the angular momentum operators Jx, Jy, and Jz have particularly simple matrix representations. The projection of an isotropic pair coupling between the rare earths onto these sixfold degenerate states leads to an interaction Hamiltonian H=-I??ij??i?j?lilj, where ? takes on the values ± 1 and l the values x, y, and z. This interaction is a variant of the three-state Potts model. We add magnetic and quadrupolar anisotropy field terms to the Hamiltonian and determine the symmetry properties of the phase diagram associated with this model. For nonzero quadrupolar anisotropy fields, the model is shown to have the thermodynamic behavior of an Ising model. However, for zero fields we find a new symmetry appears and in the mean-field approximation the model has tricritical-like exponents. This simple model is able to account for the large specific-heat critical exponent ??=12 which has been observed for holmium antimonide in zero external fields. To the extent that the mean-field approximation is an accurate guide, we predict there are many cubic rare-earth compounds which exhibit tricritical-like behavior in zero field. In addition we find that for pure quadrupole coupling between rare earths in the sixfold degenerate states, the interaction Hamiltonian is exactly the three-state Potts model. In the mean-field approximation this system has a first-order phase transition. However, a small quadrupolar anisotropy field is sufficient to drive the system to a wing critical point. The specific heat has a critical exponent of ?=23 or 1 depending on the path taken to approach this critical point.

D. Kim; Peter M. Levy; L. F. Uffer

1975-08-01T23:59:59.000Z

466

Reclaiming metallic material from an article comprising a non-metallic friable substrate  

DOE Patents (OSTI)

A method for reclaiming a metallic material from a article including a non-metallic friable substrate. The method comprising crushing the article into a plurality of pieces. An acidic solution capable of dissolving the metallic material is provided dissolving the metallic material in the acidic material to form an etchant effluent. The etchant effluent is separated from the friable substrate. A precipitation agent, capable of precipitating the metallic material, is added to the etchant effluent to precipitate out the metallic material from the etchant effluent. The metallic material is then recovered.

Bohland, John Raphael (Oregon, OH); Anisimov, Igor Ivanovich (Whitehouse, OH); Dapkus, Todd James (Toledo, OH); Sasala, Richard Anthony (Toledo, OH); Smigielski, Ken Alan (Toledo, OH); Kamm, Kristin Danielle (Swanton, OH)

2000-01-01T23:59:59.000Z

467

Enhanced Bioaccumulation of Heavy Metals by Bacterial Cells Displaying  

E-Print Network (OSTI)

Enhanced Bioaccumulation of Heavy Metals by Bacterial Cells Displaying Synthetic Phytochelatins for enhanced bioaccumulation of toxic metals. Synthetic genes encoding for several metal strategy for develop- ing high-affinity bioadsorbents suitable for heavy metal removal. © 2000 John Wiley

Chen, Wilfred

468

Synthesis of transition metal carbonitrides  

DOE Patents (OSTI)

Transition metal carbonitrides (in particular, titanium carbonitride, TiC.sub.0.5 N.sub.0.5) are synthesized by a self-propagating reaction between the metal (e.g., titanium) and carbon in a nitrogen atmosphere. Complete conversion to the carbonitride phase is achieved with the addition of TiN as diluent and with a nitrogen pressure .gtoreq.0.6 MPa. Thermodynamic phase-stability calculations and experimental characterizations of quenched samples provided revealed that the mechanism of formation of the carbonitride is a two-step process. The first step involves the formation of the nonstoichiometric carbide, TiC.sub.0.5, and is followed by the formation of the product by the incorporation of nitrogen in the defect-structure carbide.

Munir, Zuhair A. R. (Davis, CA); Eslamloo-Grami, Maryam (Davis, CA)

1994-01-01T23:59:59.000Z

469

Magnons in ferromagnetic metallic manganites  

SciTech Connect

Ferromagnetic (FM) manganites, a group of likely half-metallic oxides, are of special interest not only because they are a testing ground for the classical double-exchange interaction mechanism for the colossal magnetoresistance, but also because they exhibit an extraordinary arena of emergent phenomena. These emergent phenomena are related to the complexity associated with strong interplay between charge, spin, orbital, and lattice. In this review, we focus on the use of inelastic neutron scattering to study the spin dynamics, mainly the magnon excitations in this class of FM metallic materials. In particular, we discuss the unusual magnon softening and damping near the Brillouin zone boundary in relatively narrow-band compounds with strong Jahn CTeller lattice distortion and charge Corbital correlations. The anomalous behaviours of magnons in these compounds indicate the likelihood of cooperative excitations involving spin and lattice as well as orbital degrees of freedom.

Zhang, Jiandi [Florida International University, Miami; Ye, Feng [ORNL; Sha, Hao [Florida International University, Miami; Dai, Pengcheng [ORNL; Fernandez-Baca, Jaime A [ORNL; Plummer, E Ward [ORNL

2007-01-01T23:59:59.000Z

470

Dose Rates from Plutonium Metal and Beryllium Metal in a 9975 Shipping Container  

SciTech Connect

A parametric study was performed of the radiation dose rates that might be produced if plutonium metal and beryllium metal were shipped in the 9975 shipping package. These materials consist of heterogeneous combinations plutonium metal and beryllium. The plutonium metal content varies up to 4.4 kilograms while the beryllium metal varies up to 4 kilograms. This paper presents the results of that study.

Nathan, S.J.

2002-02-04T23:59:59.000Z

471

Liquid metal Flow Meter - Final Report  

SciTech Connect

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

472

Direct electrochemical reduction of metal-oxides  

DOE Patents (OSTI)

A method of controlling the direct electrolytic reduction of a metal oxide or mixtures of metal oxides to the corresponding metal or metals. A non-consumable anode and a cathode and a salt electrolyte with a first reference electrode near the non-consumable anode and a second reference electrode near the cathode are used. Oxygen gas is produced and removed from the cell. The anode potential is compared to the first reference electrode to prevent anode dissolution and gas evolution other than oxygen, and the cathode potential is compared to the second reference electrode to prevent production of reductant metal from ions in the electrolyte.

Redey, Laszlo I. (Downers Grove, IL); Gourishankar, Karthick (Downers Grove, IL)

2003-01-01T23:59:59.000Z

473

Biofuel production by in vitro synthetic enzymatic pathway biotransformation  

NLE Websites -- All DOE Office Websites (Extended Search)

49; 49; NO. OF PAGES 7 Please cite this article in press as: Zhang Y-H P., et al. Biofuel production by in vitro synthetic enzymatic pathway biotransformation, Curr Opin Biotechnol (2010), doi:10.1016/j.copbio.2010.05.005 Available online at www.sciencedirect.com Biofuel production by in vitro synthetic enzymatic pathway biotransformation Y-H Percival Zhang 1,2,3 , Jibin Sun 4 and Jian-Jiang Zhong 5 Cell-free synthetic pathway biotransformation (SyPaB) is the implementation of complicated biochemical reactions by in vitro assembling a number of enzymes or their complexes and coenzymes. Assembly of numerous enzymes without cellular membrane, gene regulation, or undesired pathway can circumvent some of the obstacles to modifying living microorganisms. Several synthetic pathways for the production of liquid biofuels - alcohols and hydrocarbon precursors (polyols)

474

Abstract 2227: An automatic pipeline to find and annotate rare subclonal somatic variants in a paired tumor/normal sample  

Science Journals Connector (OSTI)

...5-9, 2014; San Diego, CA Abstract 2227: An automatic pipeline to find and annotate rare subclonal somatic variants in a paired...Thomas Knudsen, Dan Richards, Roald Forsberg. An automatic pipeline to find and annotate rare subclonal somatic variants in a paired...

Anika Joecker; Nathan Pearson; Cecilie Boysen; Naomi Thomson; Anne-Mette Hein; Bodil Oster; Anne Arens; Bjarne Knudsen; Thomas Knudsen; Dan Richards; Roald Forsberg

2014-10-01T23:59:59.000Z

475

PII S0016-7037(00)00772-4 Rare earth element variations resulting from inversion of pigeonite and subsolidus  

E-Print Network (OSTI)

PII S0016-7037(00)00772-4 Rare earth element variations resulting from inversion of pigeonite ion mass spectrometry study of the rare earth elements (REEs) in the minerals of two samples of lunar earth element (REE) composi- tions of the minerals in the subgroups of lunar ferroan anortho- sites

476

Rare Earth Element sorption by basaltic rock: experimental data and modeling results using the "Generalised Composite approach".  

E-Print Network (OSTI)

Rare Earth Element sorption by basaltic rock: experimental data and modeling results using Email address : emmanuel.tertre@univ-poitiers.fr Keywords: sorption, lanthanides, basalt, surface.1016/j.gca.2007.12.015 #12;Abstract Sorption of the 14 Rare Earth Elements (REE) by basaltic rock

Paris-Sud XI, Université de

477

Method for gas-metal arc deposition  

DOE Patents (OSTI)

Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment wiht the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

Buhrmaster, Carol L. (Corning, NY); Clark, Denis E. (Idaho Falls, ID); Smartt, Herschel B. (Idaho Falls, ID)

1990-01-01T23:59:59.000Z

478

Method for gas-metal arc deposition  

DOE Patents (OSTI)

Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites are disclosed. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite. 1 fig.

Buhrmaster, C.L.; Clark, D.E.; Smartt, H.B.

1990-11-13T23:59:59.000Z

479

Apparatus for gas-metal arc deposition  

DOE Patents (OSTI)

Apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspenion of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

Buhrmaster, Carol L. (Corning, NY); Clark, Denis E. (Idaho Falls, ID); Smartt, Herschel B. (Idaho Falls, ID)

1991-01-01T23:59:59.000Z

480

Metal resistance sequences and transgenic plants  

SciTech Connect

The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

1999-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "vitro rare metals" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Ravi Metallics Ltd | Open Energy Information  

Open Energy Info (EERE)

Metallics Ltd Metallics Ltd Jump to: navigation, search Name Ravi Metallics Ltd. Place Rourkela, Orissa, India Zip 769004 Sector Biomass Product Rourkela-based biomass project developer. References Ravi Metallics Ltd.[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Ravi Metallics Ltd. is a company located in Rourkela, Orissa, India . References ↑ "Ravi Metallics Ltd." Retrieved from "http://en.openei.org/w/index.php?title=Ravi_Metallics_Ltd&oldid=350202" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load)

482

Method of nitriding refractory metal articles  

DOE Patents (OSTI)

A method of nitriding a refractory-nitride forming metal or metalloid articles and composite articles. A consolidated metal or metalloid article or composite is placed inside a microwave oven and nitrogen containing gas is introduced into the microwave oven. The metal or metalloid article or composite is heated to a temperature sufficient to react the metal or metalloid with the nitrogen by applying a microwave energy within the microwave oven. The metal or metalloid article or composite is maintained at that temperature for a period of time sufficient to convert the article of metal or metalloid or composite to an article or composite of refractory nitride. In addition, a method of applying a coating, such as a coating of an oxide, a carbide, or a carbo-nitride, to an article of metal or metalloid by microwave heating.

Tiegs, Terry N. (Lenoir City, TN); Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN); Omatete, Ogbemi O. (Lagos, NG); Young, Albert C. (Flushing, NY)

1994-01-01T23:59:59.000Z

483

Method of nitriding refractory metal articles  

DOE Patents (OSTI)

A method of nitriding a refractory-nitride forming metal or metalloid articles and composite articles. A consolidated metal or metalloid article or composite is placed inside a microwave oven and nitrogen containing gas is introduced into the microwave oven. The metal or metalloid article or composite is heated to a temperature sufficient to react the metal or metalloid with the nitrogen by applying a microwave energy within the microwave oven. The metal or metalloid article or composite is maintained at that temperature for a period of time sufficient to convert the article of metal or metalloid or composite to an article or composite of refractory nitride. In addition, a method of applying a coating, such as a coating of an oxide, a carbide, or a carbo-nitride, to an article of metal or metalloid by microwave heating.

Tiegs, T.N.; Holcombe, C.E.; Dykes, N.L.; Omatete, O.O.; Young, A.C.

1994-03-15T23:59:59.000Z

484

Methods of selectively incorporating metals onto substrates  

DOE Patents (OSTI)

A method for forming multi-metallic sites on a substrate is disclosed and described. A substrate including active groups such as hydroxyl can be reacted with a pretarget metal complex. The target metal attached to the active group can then be reacted with a secondary metal complex such that an oxidation-reduction (redox) reaction occurs to form a multi-metallic species. The substrate can be a highly porous material such as aerogels, xerogels, zeolites, and similar materials. Additional metal complexes can be reacted to increase catalyst loading or control co-catalyst content. The resulting compounds can be oxidized to form oxides or reduced to form metals in the ground state which are suitable for practical use.

Ernst; Richard D. (Salt Lake City, UT), Eyring; Edward M. (Salt Lake City, UT), Turpin; Gregory C. (Salt Lake City, UT), Dunn; Brian C. (Salt Lake City, UT)

2008-09-30T23:59:59.000Z

485

REVIEW PAPER How metal-tolerant ecotypes of ectomycorrhizal fungi  

E-Print Network (OSTI)

with open access at Springerlink.com Abstract & Introduction Heavy metal pollution is a strong driver for heavy metal-contaminated soils. Keywords Heavy metal pollution . Heavy metal tolerance . EctomycorrhizalREVIEW PAPER How metal-tolerant ecotypes of ectomycorrhizal fungi protect plants from heavy metal

Boyer, Edmond

486

Measuring Low Dimensional Schottky Barriers of Rare Earth Silicide-Silicon Interfaces.  

E-Print Network (OSTI)

??The focus of this study is the measurement of low dimensional Schottky barrier heights of metal silicide-silicon interfaces and the challenges of current-voltage (I/V) curve… (more)

Vick, Andrew J

2011-01-01T23:59:59.000Z

487

A method for making dendritic metal nanostructures using a surfactant structure template, a metal salt, and electron donor species.  

DOE Patents (OSTI)

A method for making dendritic metal nanostructures using a surfactant structure template, a metal salt, and electron donor species.

Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

2008-05-20T23:59:59.000Z

488

Metal Can and Bottle FabricationMetal Can and Bottle Fabrication ME 4210: Manufacturing Processes and Engineering  

E-Print Network (OSTI)

;Metal BottlesMetal Bottles ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton © GIT 2009

Colton, Jonathan S.

489

Metal-Polymer Interactions in a Polymer/Metal Nanocomposite  

Science Journals Connector (OSTI)

A poly(t-butyl acrylate)/gold nanocomposite sandwich was annealed to induce diffusion of the gold particles, which was monitored using Rutherford backscattering spectrometry. Marker motion experiments were also performed to probe particle and polymer mobilities independently. The experiments revealed that particle mobility was decreased by 2 to 3 orders of magnitude compared with the predictions by Stokes-Einstein theory. Diffusion of polymer molecules through a gold particle layer is decreased by a much smaller extent. These results are attributed to bridging between particles arising from slow exchange kinetics of polymer segments at the polymer/metal interface.

Douglas H. Cole; Kenneth R. Shull; L. E. Rehn; P. Baldo

1997-06-30T23:59:59.000Z

490

Method and apparatus for dissociating metals from metal compounds extracted into supercritical fluids  

DOE Patents (OSTI)

A method for dissociating metal-ligand complexes in a supercritical fluid by treating the metal-ligand complex with heat and/or reducing or oxidizing agents is described. Once the metal-ligand complex is dissociated, the resulting metal and/or metal oxide form fine particles of substantially uniform size. In preferred embodiments, the solvent is supercritical carbon dioxide and the ligand is a .beta.-diketone such as hexafluoroacetylacetone or dibutyldiacetate. In other preferred embodiments, the metals in the metal-ligand complex are copper, silver, gold, tungsten, titanium, tantalum, tin, or mixtures thereof. In preferred embodiments, the reducing agent is hydrogen. The method provides an efficient process for dissociating metal-ligand complexes and produces easily-collected metal particles free from hydrocarbon solvent impurities. The ligand and the supercritical fluid can be regenerated to provide an economic, efficient process.

Wai, Chien M. (Moscow, ID); Hunt, Fred H. (Moscow, ID); Smart, Neil G. (Workington, GB); Lin, Yuehe (Richland, WA)

2000-01-01T23:59:59.000Z

491

Microsoft Word - US-EU WORKSHOP on RARE EARTHS Program 20101206  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Trans-Atlantic Workshop Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Materials for a Clean Energy Future Hosted by the MIT Energy Initiative Massachusetts Institute of Technology 400 Main Street, Building E19-307, Cambridge, Massachusetts December 3, 2010 Workshop Background Rare earth elements and other critical raw materials are essential to our industrial production, particularly for clean energy options like wind turbines, solar cells, electric vehicles, and energy- efficient lighting. Wind turbines are the most rapidly growing source of electricity generation in both Europe and the United States. Solar photovoltaic cells are steadily declining in cost, and their widespread, cost-effective use on power grids is anticipated within the coming decade.

492

High-pressure studies of rare earth material could lead to lighter, cheaper  

NLE Websites -- All DOE Office Websites (Extended Search)

22013_earth 22013_earth 12/20/2013 A Lawrence Livermore researcher prepares a sample at Oak Ridge National Laboratory's Spallation Neutrons and Pressure Diffractometer (SNAP). High-pressure studies of rare earth material could lead to lighter, cheaper magnets Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Sometimes you have to apply a little pressure to get magnetic materials to reveal their secrets. By placing a permanent magnet under high pressures, Lawrence Livermore researchers are exploring how atomic structure enhances magnetic strength and resistance to demagnetization. This fundamental research into magnetic behavior has important implications for engineering stronger, cheaper magnets. Permanent magnets based on rare earth elements are in high demand for

493

Using NERSC Systems, Physcists Close in on a Rare-Particle Decay Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Using NERSC Systems, Using NERSC Systems, Physcists Close in on a Rare-Particle Decay Process Using NERSC Systems, Physicists Close In on a Rare-Particle Decay Process Underground Experiment May Unlock the Mysteries of the Neutrino June 11, 2012 | Tags: Accelerator Science, High Energy Physics (HEP), Hopper NERSC Contact: Linda Vu, lvu@lbl.gov, +1 510 495 2402 exo-1.jpg Located at the Waste Isolation Pilot Plant near Carlsbad, New Mexico, EXO-200 is a 200-kg detector using liquid xenon, enriched in the isotope 136, to detect "neutrino-less double beta decay." With help from supercomputers at the Department of Energy's National Energy Research Scientific Computing Center (NERSC), the Enriched Xenon Observatory experiment (EXO-200) has placed the most stringent constraints

494

Influence of double-electron transitions on the EXAFS L edges of rare-earth systems  

Science Journals Connector (OSTI)

This work presents an x-ray-absorption study at the L edges of several rare-earth compounds. In both L1-edge and L3-edge spectra, anomalous features are clearly detected in the EXAFS region and have been associated with the creation of 2s4d and 2p4d double-core hole states, respectively. Comparison of theoretical calculations with the experiments are carried out using the results of explicit computation of cross sections for the allowed mainline (L edge) and double-electron (LN4,5 edges) which identify the transitions expected to be observable. In addition, the excitation energies of all of these allowed transitions are given. The influence of multielectron transitions on the EXAFS data analysis is discussed for several rare-earth-based systems. An estimate of the error introduced by neglecting the presence of double-electron transitions on coordination numbers and bond distances is given, based on these experimental data.

Jesús Chaboy; Augusto Marcelli; Trevor A. Tyson

1994-05-01T23:59:59.000Z

495

Orbital-resolved spin model for thermal magnetization switching in rare-earth-based ferrimagnets  

Science Journals Connector (OSTI)

The switching of rare-earth-based ferrimagnets triggered by thermal excitation is investigated on the basis of an atomistic spin model beyond the rigid-spin approximation, distinguishing magnetic moments due to electrons in d and f orbitals of the rare earth. It is shown that after excitation of the conduction electrons a transient ferromagneticlike state follows from a dissipationless spin dynamics where energy and angular momentum are distributed between the two sublattices. The final relaxation can then lead to a new state with the magnetization switched with respect to the initial state. The time scale of the switching event is to a large extent determined by the exchange interaction between the two sublattices.

S. Wienholdt; D. Hinzke; K. Carva; P. M. Oppeneer; U. Nowak

2013-07-24T23:59:59.000Z

496

Iron-Nitride Alloy Magnets: Transformation Enabled Nitride Magnets Absent Rare Earths (TEN Mare)  

SciTech Connect

REACT Project: Case Western is developing a highly magnetic iron-nitride alloy to use in the magnets that power electric motors found in EVs and renewable power generators. This would reduce the overall price of the motor by eliminating the expensive imported rare earth minerals typically found in today’s best commercial magnets. The iron-nitride powder is sourced from abundant and inexpensive materials found in the U.S. The ultimate goal of this project is to demonstrate this new magnet system, which contains no rare earths, in a prototype electric motor. This could significantly reduce the amount of greenhouse gases emitted in the U.S. each year by encouraging the use of clean alternatives to oil and coal.

None

2012-01-01T23:59:59.000Z

497

X-ray resonant exchange scattering of rare-earth nickel borocarbides  

SciTech Connect

The purpose of this thesis is to investigate the systematics of the microscopic magnetic order within a series of isostructural compounds and, at the same, to develop the relatively young experimental method of x-ray resonant exchange scattering (XRES). In this thesis, the author presents XRES studies of several rare-earth nickel borocarbides, RNi{sub 2}B{sub 2}C. He shows that XRES, similar to the neutron techniques, allows the determination of the orientation of the magnetic moment by measuring the Q-dependence of the scattered intensity of magnetic Bragg reflections. As samples in this study, he chose the recently discovered family of rare-earth nickel borocarbides, RNi{sub 2}B{sub 2}C, which display a wide variety of magnetic structures. Furthermore, in several of these materials, long range magnetic order coexists with superconductivity over some temperature range.

Detlefs, C.

1997-10-08T23:59:59.000Z

498

Maria Goeppert Mayer's Theoretical Work on Rare-Earth and Transuranic Elements  

E-Print Network (OSTI)

After the discovery of element 93 neptunium by Edwin McMillan and Philip H. Abelson in 1941, Maria Goeppert Mayer applied the Thomas-Fermi model to calculate the electronic configuration of heavy elements and predicted the occurrence of a second rare-earth series in the vicinity of elements 91 or 92 extending to the transuranic elements. Mayer was motivated by Enrico Fermi, who was at the time contemplating military uses of nuclear energy. Historical development of nuclear science research leading to Mayer's publication is outlined. Mayer's method is introduced with the aid of a computer, which enables students to visualize her description of eigenfunctions, particularly the sudden change of spatial distribution and eigenenergy at the beginning of the rare-earth series. The impact of Mayer's work on the periodic table is discussed.

Wang, Frank Y

2008-01-01T23:59:59.000Z

499

Heavy metal removal and recovery using microorganisms  

SciTech Connect

Microorganisms -- bacteria, fungi, and microalgae -- can accumulate relatively large amounts of toxic heavy metals and radionuclides from the environment. These organisms often exhibit specificity for particular metals. The metal content of microbial biomass can be a substantial fraction of total dry weight with concentration factors (metal in dry biomass to metal in solution) exceeding one million in some cases. Both living and inert (dead) microbial biomass can be used to reduce heavy metal concentrations in contaminated waters to very low levels -- parts per billion and even lower. In many respects (e.g. specificity, residual metal concentrations, accumulation factors, and economics) microbial bioremoval processes can be superior to conventional processes, such as ion exchange and caustic (lime or hydroxide) precipitation for heavy metals removal from waste and contaminated waters. Thus, bioremoval could be developed to contribute to the clean-up of wastes at the Savannah River Site (SRS) and other DOE facilities. However, the potential advantages of bioremoval processes must still be developed into practical operating systems. A detailed review of the literature suggests that appropriate bioremoval processes could be developed for the SRS. There is great variability from one biomass source to another in bioremoval capabilities. Bioremoval is affected by pH, other ions, temperature, and many other factors. The biological (living vs. dead) and physical (immobilized vs. dispersed) characteristics of the biomass also greatly affect metal binding. Even subtle differences in the microbial biomass, such as the conditions under which it was cultivated, can have major effects on heavy metal binding.

Wilde, E.W. (Westinghouse Savannah River Co., Aiken, SC (United States)); Benemann, J.R. (Benemann (J.R.), Pinole, CA (United States))

1991-02-01T23:59:59.000Z

500

Rare-earth amorphous alloys: Nonaxial crystal-field model and induced magnetism  

Science Journals Connector (OSTI)

The consequences of the induced magnetism on amorphous rare-earth systems with singlet ground state are analyzed on the basis of the Fert and Campbell Hamiltonian assuming a suitable distribution of the asymmetry parameter. The formal treatment is developed for both the ferromagnetic and antiferromagnetic interaction in the molecular-field approximation. The magnetization, the specific heat, and the magnetic susceptibility of Pr amorphous alloys, in particular, are discussed.

E. Borchi and S. De Gennaro

1982-02-01T23:59:59.000Z